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Sample records for bioclim hierarchical strategy

  1. Bioclim Deliverable D6b: application of statistical down-scaling within the BIOCLIM hierarchical strategy: methods, data requirements and underlying assumptions

    International Nuclear Information System (INIS)

    2004-01-01

    The overall aim of BIOCLIM is to assess the possible long term impacts due to climate change on the safety of radioactive waste repositories in deep formations. The coarse spatial scale of the Earth-system Models of Intermediate Complexity (EMICs) used in BIOCLIM compared with the BIOCLIM study regions and the needs of performance assessment creates a need for down-scaling. Most of the developmental work on down-scaling methodologies undertaken by the international research community has focused on down-scaling from the general circulation model (GCM) scale (with a typical spatial resolution of 400 km by 400 km over Europe in the current generation of models) using dynamical down-scaling (i.e., regional climate models (RCMs), which typically have a spatial resolution of 50 km by 50 km for models whose domain covers the European region) or statistical methods (which can provide information at the point or station scale) in order to construct scenarios of anthropogenic climate change up to 2100. Dynamical down-scaling (with the MAR RCM) is used in BIOCLIM WP2 to down-scale from the GCM (i.e., IPSL C M4 D ) scale. In the original BIOCLIM description of work, it was proposed that UEA would apply statistical down-scaling to IPSL C M4 D output in WP2 as part of the hierarchical strategy. Statistical down-scaling requires the identification of statistical relationships between the observed large-scale and regional/local climate, which are then applied to large-scale GCM output, on the assumption that these relationships remain valid in the future (the assumption of stationarity). Thus it was proposed that UEA would investigate the extent to which it is possible to apply relationships between the present-day large-scale and regional/local climate to the relatively extreme conditions of the BIOCLIM WP2 snapshot simulations. Potential statistical down-scaling methodologies were identified from previous work performed at UEA. Appropriate station data from the case

  2. Bioclim Deliverable D6a: regional climatic characteristics for the European sites at specific times: the dynamical down-scaling

    International Nuclear Information System (INIS)

    2003-01-01

    The overall aim of BIOCLIM is to assess the possible long-term impacts due to climate change on the safety of radioactive waste repositories in deep formations. This aim is addressed through the following specific objectives: - Development of practical and innovative strategies for representing sequential climatic changes to the geosphere-biosphere system for existing sites over central Europe, addressing the timescale of one million years, which is relevant to the geological disposal of radioactive waste. - Exploration and evaluation of the potential effects of climate change on the nature of the biosphere systems used to assess the environmental impact. - Dissemination of information on the new methodologies and the results obtained from the project among the international waste management community for use in performance assessments of potential or planned radioactive waste repositories. The BIOCLIM project is designed to advance the state-of-the-art of biosphere modelling for use in Performance Assessments. Therefore, two strategies are developed for representing sequential climatic changes to geosphere-biosphere systems. The hierarchical strategy successively uses a hierarchy of climate models. These models vary from simple 2-D models, which simulate interactions between a few aspects of the Earth system at a rough surface resolution, through General Circulation Model (GCM) and vegetation model, which simulate in great detail the dynamics and physics of the atmosphere, ocean and biosphere, to regional models, which focus on the European regions and sites of interest. Moreover, rule-based and statistical down-scaling procedures are also considered. Comparisons are provided in terms of climate and vegetation cover at the selected times and for the study regions. The integrated strategy consists of using integrated climate models, representing all the physical mechanisms important for long-term continuous climate variations, to simulate the climate evolution over

  3. Bioclim deliverable D8a: development of the rule-based down-scaling methodology for BIOCLIM Work-package 3

    International Nuclear Information System (INIS)

    2003-01-01

    The BIOCLIM project on modelling sequential Biosphere systems under Climate change for radioactive waste disposal is part of the EURATOM fifth European framework programme. The project was launched in October 2000 for a three-year period. The project aims at providing a scientific basis and practical methodology for assessing the possible long term impacts on the safety of radioactive waste repositories in deep formations due to climate and environmental change. Five work packages (WP) have been identified to fulfill the project objectives. One of the tasks of BIOCLIM WP3 was to develop a rule-based approach for down-scaling from the MoBidiC model of intermediate complexity in order to provide consistent estimates of monthly temperature and precipitation for the specific regions of interest to BIOCLIM (Central Spain, Central England and Northeast France, together with Germany and the Czech Republic). A statistical down-scaling methodology has been developed by Philippe Marbaix of CEA/LSCE for use with the second climate model of intermediate complexity used in BIOCLIM - CLIMBER-GREMLINS. The rule-based methodology assigns climate states or classes to a point on the time continuum of a region according to a combination of simple threshold values which can be determined from the coarse scale climate model. Once climate states or classes have been defined, monthly temperature and precipitation climatologies are constructed using analogue stations identified from a data base of present-day climate observations. The most appropriate climate classification for BIOCLIM purposes is the Koeppen/Trewartha scheme. This scheme has the advantage of being empirical, but only requires monthly averages of temperature and precipitation as input variables. Section 2 of this deliverable (D8a) outline how each of the eight methodological steps have been undertaken for each of the three main BIOCLIM study regions (Central England, Northeast France and Central Spain) using Mo

  4. Quantification of thermal bioclimate for the management of urban design in Mediterranean climate of Barcelona, Spain

    Science.gov (United States)

    Rodríguez Algeciras, José Abel; Matzarakis, Andreas

    2016-08-01

    In order to contribute to the sustainability of the outdoor environment, knowledge about the urban thermal bioclimate should be transferred into climatic guidelines for planning. The general framework of this study responds to the need of analyzing thermal bioclimate in Mediterranean climate regions and its influence as an urban design factor. The paper analyzes the background of the urban climate and thermal bioclimate conditions in Barcelona (Spain), through the effect of shade conditions and wind speed variations. Simulations of shade and wind speed variations were performed to evaluate changes in thermal bioclimate due to modifications in urban morphology. Air temperature, relative humidity, wind speed, and solar radiation for the period from January, 2001 to January, 2015 were used to calculate physiologically equivalent temperature (PET) using the RayMan model. The results demonstrate that shade is the most important strategy to improve urban microclimatic conditions. In Barcelona, human thermal comfort conditions can be improved by shade and wind speed increase in terms of PET above 23 °C and by a wind speed decrease for thresholds of PET below 18 °C. Heat stress situations can be mitigated by shade and wind speed increase in conditions above 35 and 45 °C, respectively. The results of the study are an important contribution for urban planners, due to their possibilities and potential for the description of microclimatic conditions in Mediterranean climate regions. The knowledge is useful for improved human thermal comfort conditions, from the suitable configuration of urban form and architecture.

  5. Bioclim Deliverable D7: continuous climate evolution scenarios over western Europe (1000 km scale)

    International Nuclear Information System (INIS)

    2003-01-01

    The overall aim of BIOCLIM is to assess the possible long term impacts due to climate change on the safety of radioactive waste repositories in deep formations. This aim is addressed through the following specific objectives: - Development of practical and innovative strategies for representing sequential climatic changes to the geosphere-biosphere system for existing sites over central Europe, addressing the timescale of one million years, which is relevant to the geological disposal of radioactive waste. - Exploration and evaluation of the potential effects of climate change on the nature of the biosphere systems used to assess the environmental impact. - Dissemination of information on the new methodologies and the results obtained from the project among the international waste management community for use in performance assessments of potential or planned radioactive waste repositories. A key point of the project is therefore to develop strategies for representing sequential long-term climatic changes by addressing time scales of relevance to geological disposal of solid radioactive wastes. The integrated strategy, which first step is described in this deliverable (D7), consists of building an integrated, dynamic climate model, to represent all the known important mechanisms for long term climatic variations. The time-dependent results will then be interpreted in terms of regional climate using rule-based and statistical down-scaling approaches. Therefore, the continuous simulation of the climate evolution of the next 200 000 years selected for study is a major objective of the BIOCLIM project. This requires models that account for the simultaneous evolution of the atmosphere, biosphere, land-ice and the ocean. To be able to perform several 200 000-yearlong transient climate simulations, the models have to include all these components, but also need to be simple enough to run fast. Therefore, climate models of intermediate complexity have been chosen to

  6. Bioclim Deliverable D1: environmental change analysis

    International Nuclear Information System (INIS)

    2001-01-01

    The BIOCLIM project on modelling sequential Biosphere systems under Climate change for radioactive waste disposal is part of the EURATOM fifth European framework programme. The project was launched in October 2000 for a three-year period. The project aims at providing a scientific basis and practical methodology for assessing the possible long term impacts on the safety of radioactive waste repositories in deep formations due to climate and environmental change. The project brings together a number of representatives from both European radioactive waste management organisations which have national responsibilities for the safe disposal of radioactive waste, either as disposers or regulators, and several highly experienced climate research teams. In particular, BIOCLIM aims to address the important objective of how to represent the development of future biosphere systems by addressing both how to model long-term climate change, the relevant environmental consequences of such changes and the implementation of a sequential approach to such changes. The results from the development of this sophisticated approach will be of great benefit for improving long term radiological impact calculations and the information presented in a safety case. Simulations will be conducted to represent the time series of long-term climate in three European areas within which disposal sites may be established (i.e. Central/Southern Spain, Northeast of France and Central Britain). Two complementary strategies will provide representations of future climate predictions together with associated vegetation patterns using either an analysis of distinct climate states or a continuous climate simulation over at least one glacial-interglacial cycle and possibly for other selected periods over the next 1,000,000 years. These results will be used to derive the characteristics of possible future human environments (i.e. biosphere systems) through which radionuclides, emerging from the repository, may

  7. Interpretación bioclimática de la arquitectura vernácula

    OpenAIRE

    Paniagua Padilla, Diego

    2015-01-01

    La ‘arquitectura vernácula’ desarrolló la primera adecuación entre el clima, las necesidades humanas y la construcción sostenible. En este sentido, la ‘arquitectura bioclimática’ de la que hablamos hoy en día es una interpretación de la arquitectura a efectos del clima sobre el hombre. Podríamos entenderla como una arquitectura popular evolucionada y adaptada. ¿Pero es lo mismo arquitectura vernácula que popular? ¿Y arquitectura bioclimática? ¿Es lo que muchos denominan ‘arquitectura sostenib...

  8. The EC BIOCLIM Project (2000-2003), 5. Euratom Framework Programme - Modelling sequential biosphere systems under climate change for radioactive waste disposal

    International Nuclear Information System (INIS)

    Calvez, Marianne

    2002-01-01

    Marianne Calvez (ANDRA, France) presented the new EC BIOCLIM project that started in 2001. Its main objective is to provide a scientific basis and practical methodology for assessing the possible long-term impacts on the safety of radioactive waste repositories in deep formations due to climate driven changes. She explained that BIOCLIM objective is not to predict what will be the future but will correspond to an illustration of how people could use the knowledge. The BIOCLIM project will use the outcomes from the Biomass project. Where Biomass considered discrete biospheres, the BIOCLIM project will consider the evolution of climate with a focus on the European climate for three regions in the United Kingdom, France and Spain. The consortium of BIOCLIM participants consists of various experts in climate modelling and various experts and organisations in performance assessment. The intent is to build an integrated dynamic climate model that represents all the important mechanisms for long-term climate evolution. The modelling will primarily address the next 200000 years. The final outcome will be an enhancement of the state-of-the-art treatment of biosphere system change over long periods of time through the use of a number of innovative climate modelling approaches and the application of the climate model outputs in performance assessments

  9. Hierarchical MAS based control strategy for microgrid

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Z.; Li, T.; Huang, M.; Shi, J.; Yang, J.; Yu, J. [School of Information Science and Engineering, Yunnan University, Kunming 650091 (China); Xiao, Z. [School of Electrical and Electronic Engineering, Nanyang Technological University, Western Catchment Area, 639798 (Singapore); Wu, W. [Communication Branch of Yunnan Power Grid Corporation, Kunming, Yunnan 650217 (China)

    2010-09-15

    Microgrids have become a hot topic driven by the dual pressures of environmental protection concerns and the energy crisis. In this paper, a challenge for the distributed control of a modern electric grid incorporating clusters of residential microgrids is elaborated and a hierarchical multi-agent system (MAS) is proposed as a solution. The issues of how to realize the hierarchical MAS and how to improve coordination and control strategies are discussed. Based on MATLAB and ZEUS platforms, bilateral switching between grid-connected mode and island mode is performed under control of the proposed MAS to enhance and support its effectiveness. (authors)

  10. Bioclim Deliverable D10 - 12: development and application of a methodology for taking climate-driven environmental change into account in performance assessments

    International Nuclear Information System (INIS)

    2004-01-01

    The BIOCLIM project on modelling sequential Biosphere systems under Climate change for radioactive waste disposal is part of the EURATOM fifth European framework programme. The project was launched in October 2000 for a three-year period. The project aims at providing a scientific basis and practical methodology for assessing the possible long term impacts on the safety of radioactive waste repositories in deep formations due to climate and environmental change. Five work packages have been identified to fulfill the project objectives: - Work package 1 will consolidate the needs of the European agencies of the consortium and summarize how environmental change has been treated to date in performance assessments. - Work packages 2 and 3 will develop two innovative and complementary strategies for representing time series of long term climate change using different methods to analyse extreme climate conditions (the hierarchical strategy) and a continuous climate simulation over more than the next glacial-interglacial cycle (the integrated strategy). - Work package 4 will explore and evaluate the potential effects of climate change on the nature of the biosphere systems. - Work package 5 will disseminate information on the results obtained from the three year project among the international community for further use. The output from the climate models developed and applied in WP2 and WP3 has been interpreted in WP4 ('Biosphere system description') in terms of model requirements for the post-closure radiological performance assessment of deep geological repositories for radioactive wastes, in order to develop a methodology to demonstrate how biosphere systems can be represented in the long-term. The work undertaken in WP4 is described in this report. This report describes the methodology used for identification and characterisation of specific climate states and transitions between those climate states. It also covers the application of those methods in the context of

  11. Adapting forest management to climate change using bioclimate models with topographic drivers

    Science.gov (United States)

    Gerald E. Rehfeldt; James J. Worrall; Suzanne B. Marchetti; Nicholas L. Crookston

    2015-01-01

    Bioclimate models incorporating topographic predictors as surrogates for microclimate effects are developed for Populus tremuloides and Picea engelmannii to provide the fine-grained specificity to local terrain required for adapting management of three Colorado (USA) national forests (1.28 million ha) and their periphery to climate change. Models were built with the...

  12. Bioclimate analysis of Mountain Bjelašnica

    Directory of Open Access Journals (Sweden)

    Šušnjar Sanda

    2014-01-01

    Full Text Available The main task of this paper was to assess weather suitability on Bjelasnica Mountain for optimal function of a human organism. Also, this paper represents weather classification for certain types of recreation and sport's activities. For the purpose of bioclimate analyses it has been used Model “MENEX”. This paper deals with the assessment of heat exchange between man and its environment. Research is based on a meteorological data from 2000 to 2010. The aim of a research was to determine periods in year on mountain Bjelasnica with optimal climate conditions for recreation and living but also to define periods with mostly unsuitable weather conditions, except for healthy and well adapted persons and specific type of activities.

  13. Hierarchical Control Strategy for the Cooperative Braking System of Electric Vehicle

    Science.gov (United States)

    Peng, Jiankun; He, Hongwen; Guo, Hongqiang

    2015-01-01

    This paper provides a hierarchical control strategy for cooperative braking system of an electric vehicle with separated driven axles. Two layers are defined: the top layer is used to optimize the braking stability based on two sliding mode control strategies, namely, the interaxle control mode and signal-axle control strategies; the interaxle control strategy generates the ideal braking force distribution in general braking condition, and the single-axle control strategy can ensure braking safety in emergency braking condition; the bottom layer is used to maximize the regenerative braking energy recovery efficiency with a reallocated braking torque strategy; the reallocated braking torque strategy can recovery braking energy as much as possible in the premise of meeting battery charging power. The simulation results show that the proposed hierarchical control strategy is reasonable and can adapt to different typical road surfaces and load cases; the vehicle braking stability and safety can be guaranteed; furthermore, the regenerative braking energy recovery efficiency can be improved. PMID:26236772

  14. Hierarchical Control Strategy for the Cooperative Braking System of Electric Vehicle.

    Science.gov (United States)

    Peng, Jiankun; He, Hongwen; Liu, Wei; Guo, Hongqiang

    2015-01-01

    This paper provides a hierarchical control strategy for cooperative braking system of an electric vehicle with separated driven axles. Two layers are defined: the top layer is used to optimize the braking stability based on two sliding mode control strategies, namely, the interaxle control mode and signal-axle control strategies; the interaxle control strategy generates the ideal braking force distribution in general braking condition, and the single-axle control strategy can ensure braking safety in emergency braking condition; the bottom layer is used to maximize the regenerative braking energy recovery efficiency with a reallocated braking torque strategy; the reallocated braking torque strategy can recovery braking energy as much as possible in the premise of meeting battery charging power. The simulation results show that the proposed hierarchical control strategy is reasonable and can adapt to different typical road surfaces and load cases; the vehicle braking stability and safety can be guaranteed; furthermore, the regenerative braking energy recovery efficiency can be improved.

  15. Hierarchical Control Strategy for the Cooperative Braking System of Electric Vehicle

    Directory of Open Access Journals (Sweden)

    Jiankun Peng

    2015-01-01

    Full Text Available This paper provides a hierarchical control strategy for cooperative braking system of an electric vehicle with separated driven axles. Two layers are defined: the top layer is used to optimize the braking stability based on two sliding mode control strategies, namely, the interaxle control mode and signal-axle control strategies; the interaxle control strategy generates the ideal braking force distribution in general braking condition, and the single-axle control strategy can ensure braking safety in emergency braking condition; the bottom layer is used to maximize the regenerative braking energy recovery efficiency with a reallocated braking torque strategy; the reallocated braking torque strategy can recovery braking energy as much as possible in the premise of meeting battery charging power. The simulation results show that the proposed hierarchical control strategy is reasonable and can adapt to different typical road surfaces and load cases; the vehicle braking stability and safety can be guaranteed; furthermore, the regenerative braking energy recovery efficiency can be improved.

  16. Hierarchy concepts: classification and preparation strategies for zeolite containing materials with hierarchical porosity.

    Science.gov (United States)

    Schwieger, Wilhelm; Machoke, Albert Gonche; Weissenberger, Tobias; Inayat, Amer; Selvam, Thangaraj; Klumpp, Michael; Inayat, Alexandra

    2016-06-13

    'Hierarchy' is a property which can be attributed to a manifold of different immaterial systems, such as ideas, items and organisations or material ones like biological systems within living organisms or artificial, man-made constructions. The property 'hierarchy' is mainly characterised by a certain ordering of individual elements relative to each other, often in combination with a certain degree of branching. Especially mass-flow related systems in the natural environment feature special hierarchically branched patterns. This review is a survey into the world of hierarchical systems with special focus on hierarchically porous zeolite materials. A classification of hierarchical porosity is proposed based on the flow distribution pattern within the respective pore systems. In addition, this review might serve as a toolbox providing several synthetic and post-synthetic strategies to prepare zeolitic or zeolite containing material with tailored hierarchical porosity. Very often, such strategies with their underlying principles were developed for improving the performance of the final materials in different technical applications like adsorptive or catalytic processes. In the present review, besides on the hierarchically porous all-zeolite material, special focus is laid on the preparation of zeolitic composite materials with hierarchical porosity capable to face the demands of industrial application.

  17. Hierarchical Control Strategy for the Cooperative Braking System of Electric Vehicle

    OpenAIRE

    Peng, Jiankun; He, Hongwen; Liu, Wei; Guo, Hongqiang

    2015-01-01

    This paper provides a hierarchical control strategy for cooperative braking system of an electric vehicle with separated driven axles. Two layers are defined: the top layer is used to optimize the braking stability based on two sliding mode control strategies, namely, the interaxle control mode and signal-axle control strategies; the interaxle control strategy generates the ideal braking force distribution in general braking condition, and the single-axle control strategy can ensure braking s...

  18. Bioclim Deliverable D4/5: global climatic characteristics, including vegetation and seasonal cycles over Europe, for snapshots over the next 200,000 years

    International Nuclear Information System (INIS)

    2003-01-01

    The aim of the BIOCLIM project is to develop and present techniques that can be used to develop self-consistent patterns of possible future climate changes over the next million years (climate scenarios), and to demonstrate how these climate scenarios can be used in assessments of the long-term safety of nuclear waste repository sites. Within the project, two strategies are implemented to predict climate change. The first is the hierarchical strategy, in which a hierarchy of climate models is used to investigate the evolution of climate over the period of interest. These models vary from very simple 2-D and threshold models, which simulate interactions between only a few aspects of the earth system, through general circulation models (GCMs) and vegetation models, which simulate in great detail the dynamics and physics of the atmosphere, ocean, and biosphere, to regional models, which focus in particular on the European region and the specific areas of interest. The second strategy is the integrated strategy, in which intermediate complexity climate models are developed, and used to consecutively simulate the development of the earth system over many millennia. Although these models are relatively simple compared to a GCM, they are more advanced than 2D models, and do include physical descriptions of the biosphere, cryo-sphere, atmosphere and ocean. This deliverable, D4/5, focuses on the hierarchical strategy, and in particular the GCM and vegetation model simulation of possible future climates. Deliverable D3 documented the first step in this strategy. The Louvain-la-Neuve 2-D climate model (LLN-2D) was used to estimate (among other variables) annual mean temperatures and ice volume in the Northern Hemisphere over the next 1 million years. It was driven by the calculated evolution of orbital parameters, and plausible scenarios of CO 2 concentration. From the results, 3 future time periods within the next 200,000 years were identified as being extreme, that is

  19. Multilevel Optimization Framework for Hierarchical Stiffened Shells Accelerated by Adaptive Equivalent Strategy

    Science.gov (United States)

    Wang, Bo; Tian, Kuo; Zhao, Haixin; Hao, Peng; Zhu, Tianyu; Zhang, Ke; Ma, Yunlong

    2017-06-01

    In order to improve the post-buckling optimization efficiency of hierarchical stiffened shells, a multilevel optimization framework accelerated by adaptive equivalent strategy is presented in this paper. Firstly, the Numerical-based Smeared Stiffener Method (NSSM) for hierarchical stiffened shells is derived by means of the numerical implementation of asymptotic homogenization (NIAH) method. Based on the NSSM, a reasonable adaptive equivalent strategy for hierarchical stiffened shells is developed from the concept of hierarchy reduction. Its core idea is to self-adaptively decide which hierarchy of the structure should be equivalent according to the critical buckling mode rapidly predicted by NSSM. Compared with the detailed model, the high prediction accuracy and efficiency of the proposed model is highlighted. On the basis of this adaptive equivalent model, a multilevel optimization framework is then established by decomposing the complex entire optimization process into major-stiffener-level and minor-stiffener-level sub-optimizations, during which Fixed Point Iteration (FPI) is employed to accelerate convergence. Finally, the illustrative examples of the multilevel framework is carried out to demonstrate its efficiency and effectiveness to search for the global optimum result by contrast with the single-level optimization method. Remarkably, the high efficiency and flexibility of the adaptive equivalent strategy is indicated by compared with the single equivalent strategy.

  20. Medellín bioclimático : su edificio de oficinas a través del siglo

    Directory of Open Access Journals (Sweden)

    Marcela Estrada Cano

    1993-09-01

    Full Text Available La situación económica y ecológica actual en Colombia y las condiciones de bienestar psicológico y fisiológico de los habitantes de su arquitectura hacen pensar en la necesidad de implementar Ia arquitectura bioclimática en nuestro medio, como componente arquitectónico fundamental para lograr avances significativos en la obtención de ahorro energético por medio del uso racional de las energías tradicionales y de la utilización de energías alternativas cuyas fuentes sean abundantes, en la conservación de nuestro deteriorado medio ambiente y en el mejoramiento de las condiciones de habitabilidad de nuestras edificaciones. Aunque este texto no discurre exclusivamente sobre arquitectura bioclimática, tiene como propósito interesar al lector en ella y contribuir a la formación de una conciencia colectiva acerca ele la necesidad de incorporarla en el quehacer arquitectónico colombiano.

  1. A bioscaffolding strategy for hierarchical zeolites with a nanotube-trimodal network.

    Science.gov (United States)

    Li, Guannan; Huang, Haibo; Yu, Bowen; Wang, Yun; Tao, Jiawei; Wei, Yingxu; Li, Shougui; Liu, Zhongmin; Xu, Yan; Xu, Ruren

    2016-02-01

    Hierarchical zeolite monoliths with multimodal porosity are of paramount importance as they open up new horizons for advanced applications. So far, hierarchical zeolites based on nanotube scaffolds have never been reported. Inspired by the organization of biominerals, we have developed a novel precursor scaffolding-solid phase crystallization strategy for hierarchical zeolites with a unique nanotube scaffolding architecture and nanotube-trimodal network, where biomolecular self-assembly (BSA) provides a scaffolding blueprint. By vapor-treating Sil-1 seeded precursor scaffolds, zeolite MFI nanotube scaffolds are self-generated, during which evolution phenomena such as segmented voids and solid bridges are observed, in agreement with the Kirkendall effect in a solid-phase crystallization system. The nanotube walls are made of intergrown single crystals rendering good mechanical stability. The inner diameter of the nanotube is tunable between 30 and 90 nm by varying the thickness of the precursor layers. Macropores enclosed by cross-linked nanotubes can be modulated by the choice of BSA. Narrow mesopores are formed by intergrown nanocrystals. Hierarchical ZSM-5 monoliths with nanotube (90 nm), micropore (0.55 nm), mesopore (2 nm) and macropore (700 nm) exhibit superior catalytic performance in the methanol-to-hydrocarbon (MTH) conversion compared to conventional ZSM-5. BSA remains intact after crystallization, allowing a higher level of organization and functionalization of the zeolite nanotube scaffolds. The current work may afford a versatile strategy for hierarchical zeolite monoliths with nanotube scaffolding architectures and a nanotube-multimodal network leading to self-supporting and active zeolite catalysts, and for applications beyond.

  2. Parameter-Invariant Hierarchical Exclusive Alphabet Design for 2-WRC with HDF Strategy

    Directory of Open Access Journals (Sweden)

    T. Uřičář

    2010-01-01

    Full Text Available Hierarchical eXclusive Code (HXC for the Hierarchical Decode and Forward (HDF strategy in the Wireless 2-Way Relay Channel (2-WRC has the achievable rate region extended beyond the classical MAC region. Although direct HXC design is in general highly complex, a layered approach to HXC design is a feasible solution. While the outer layer code of the layered HXC can be any state-of-the-art capacity approaching code, the inner layer must be designed in such a way that the exclusive property of hierarchical symbols (received at the relay will be provided. The simplest case of the inner HXC layer is a simple signal space channel symbol memoryless mapper called Hierarchical eXclusive Alphabet (HXA. The proper design of HXA is important, especially in the case of parametric channels, where channel parametrization (e.g. phase rotation can violate the exclusive property of hierarchical symbols (as seen by the relay, resulting in significant capacity degradation. In this paper we introduce an example of a geometrical approach to Parameter-Invariant HXA design, and we show that the corresponding hierarchical MAC capacity region extends beyond the classical MAC region, irrespective of the channel pametrization.

  3. Solicitant -exciting plain bioclimate / Amara Balneoclimateric Resort, 

    Directory of Open Access Journals (Sweden)

    Munteanu Constantin

    2011-05-01

    Full Text Available Spa and balneotherapy is one of studying medicine and therapy and apply natural factors intherapy: natural mineral water springs and lakes mineralized, therapeuticmineral mud and peat, gas emanations and climate zones,orlocalities developed intosources respective treatment , the spa resort climate.Resources are the mineral spa and climatic treatment ,whose physicochemical properties meet the needs of prevention and health maintenance, strengthening and restoration of health, work capacity and physical and mental comfort of the individual.Climatic is a form of treatment, well-run, have fewer side effects than chemo therapeutictreatment and prolonged effects, because the way treatment is as close to normal activity in a relaxing environment.Bioclimate turn-applicant is characterized by general biological effects resulting from theapplication marked the central nervous system and autonomic and endocrine activity. Bioclimatic conditions, demanding aplain exciting resorts are located in northeasternbalneoclimatice Baragan, on the shores of salt lakes: Amara, Lacul Sarat.

  4. Bioclim Deliverable D8b: development of the physical/statistical down-scaling methodology and application to climate model Climber for BIOCLIM Work-package 3

    International Nuclear Information System (INIS)

    2003-01-01

    The overall aim of BIOCLIM is to assess the possible long term impacts due to climate change on the safety of radioactive waste repositories in deep formations. The main aim of this deliverable is to provide time series of climatic variables at the high resolution as needed by performance assessment (PA) of radioactive waste repositories, on the basis of coarse output from the CLIMBER-GREMLINS climate model. The climatological variables studied here are long-term (monthly) mean temperature and precipitation, as these are the main variables of interest for performance assessment. CLIMBER-GREMLINS is an earth-system model of intermediate complexity (EMIC), designed for long climate simulations (glacial cycles). Thus, this model has a coarse resolution (about 50 degrees in longitude) and other limitations which are sketched in this report. For the purpose of performance assessment, the climatological variables are required at scales pertinent for the knowledge of the conditions at the depository site. In this work, the final resolution is that of the best available global gridded present-day climatology, which is 1/6 degree in both longitude and latitude. To obtain climate-change information at this high resolution on the basis of the climate model outputs, a 2-step down-scaling method is designed. First, physical considerations are used to define variables which are expected to have links which climatological values; secondly a statistical model is used to find the links between these variables and the high-resolution climatology of temperature and precipitation. Thus the method is termed as 'physical/statistical': it involves physically based assumptions to compute predictors from model variables and then relies on statistics to find empirical links between these predictors and the climatology. The simple connection of coarse model results to regional values can not be done on a purely empirical way because the model does not provide enough information - it is both

  5. Present, future, and novel bioclimates of the San Francisco, California region

    Science.gov (United States)

    Torregrosa, Alicia; Taylor, Maxwell D.; Flint, Lorraine E.; Flint, Alan L.

    2013-01-01

    Bioclimates are syntheses of climatic variables into biologically relevant categories that facilitate comparative studies of biotic responses to climate conditions. Isobioclimates, unique combinations of bioclimatic indices (continentality, ombrotype, and thermotype), were constructed for northern California coastal ranges based on the Rivas-Martinez worldwide bioclimatic classification system for the end of the 20th century climatology (1971–2000) and end of the 21st century climatology (2070–2099) using two models, Geophysical Fluid Dynamics Laboratory (GFDL) model and the Parallel Climate Model (PCM), under the medium-high A2 emission scenario. The digitally mapped results were used to 1) assess the relative redistribution of isobioclimates and their magnitude of change, 2) quantify the loss of isobioclimates into the future, 3) identify and locate novel isobioclimates projected to appear, and 4) explore compositional change in vegetation types among analog isobioclimate patches. This study used downscaled climate variables to map the isobioclimates at a fine spatial resolution −270 m grid cells. Common to both models of future climate was a large change in thermotype. Changes in ombrotype differed among the two models. The end of 20th century climatology has 83 isobioclimates covering the 63,000 km2 study area. In both future projections 51 of those isobioclimates disappear over 40,000 km2. The ordination of vegetation-bioclimate relationships shows very strong correlation of Rivas-Martinez indices with vegetation distribution and composition. Comparisons of vegetation composition among analog patches suggest that vegetation change will be a local rearrangement of species already in place rather than one requiring long distance dispersal. The digitally mapped results facilitate comparison with other Mediterranean regions. Major remaining challenges include predicting vegetation composition of novel isobioclimates and developing metrics to compare

  6. Present, future, and novel bioclimates of the San Francisco, California region.

    Directory of Open Access Journals (Sweden)

    Alicia Torregrosa

    Full Text Available Bioclimates are syntheses of climatic variables into biologically relevant categories that facilitate comparative studies of biotic responses to climate conditions. Isobioclimates, unique combinations of bioclimatic indices (continentality, ombrotype, and thermotype, were constructed for northern California coastal ranges based on the Rivas-Martinez worldwide bioclimatic classification system for the end of the 20(th century climatology (1971-2000 and end of the 21(st century climatology (2070-2099 using two models, Geophysical Fluid Dynamics Laboratory (GFDL model and the Parallel Climate Model (PCM, under the medium-high A2 emission scenario. The digitally mapped results were used to 1 assess the relative redistribution of isobioclimates and their magnitude of change, 2 quantify the loss of isobioclimates into the future, 3 identify and locate novel isobioclimates projected to appear, and 4 explore compositional change in vegetation types among analog isobioclimate patches. This study used downscaled climate variables to map the isobioclimates at a fine spatial resolution -270 m grid cells. Common to both models of future climate was a large change in thermotype. Changes in ombrotype differed among the two models. The end of 20(th century climatology has 83 isobioclimates covering the 63,000 km(2 study area. In both future projections 51 of those isobioclimates disappear over 40,000 km(2. The ordination of vegetation-bioclimate relationships shows very strong correlation of Rivas-Martinez indices with vegetation distribution and composition. Comparisons of vegetation composition among analog patches suggest that vegetation change will be a local rearrangement of species already in place rather than one requiring long distance dispersal. The digitally mapped results facilitate comparison with other Mediterranean regions. Major remaining challenges include predicting vegetation composition of novel isobioclimates and developing metrics to

  7. Recent progress in the direct synthesis of hierarchical zeolites: synthetic strategies and characterization methods

    KAUST Repository

    Liu, Zhaohui

    2017-06-16

    Hierarchically structured zeolites combine the merits of microporous zeolites and mesoporous materials to offer enhanced molecular diffusion and mass transfer without compromising the inherent catalytic activities and selectivity of zeolites. This short review gives an introduction to the synthesis strategies for hierarchically structured zeolites with emphasis on the latest progress in the route of ‘direct synthesis’ using various templates. Several characterization methods that allow us to evaluate the ‘quality’ of complex porous structures are also introduced. At the end of this review, an outlook is given to discuss some critical issues and challenges regarding the development of novel hierarchically structured zeolites as well as their applications.

  8. Super-hierarchical porous carbons derived from mixed biomass wastes by a stepwise removal strategy for high-performance supercapacitors

    Science.gov (United States)

    Peng, Lin; Liang, Yeru; Dong, Hanwu; Hu, Hang; Zhao, Xiao; Cai, Yijing; Xiao, Yong; Liu, Yingliang; Zheng, Mingtao

    2018-02-01

    The synthesis and energy storage application of hierarchical porous carbons with size ranging from nano-to micrometres has attracted considerable attention all over the world. Exploring eco-friendly and reliable synthesis of hierarchical porous carbons for supercapacitors with high energy density and high power is still of ongoing challenge. In this work, we report the design and synthesis of super-hierarchical porous carbons with highly developed porosity by a stepwise removal strategy for high-rate supercapacitors. The mixed biomass wastes of coconut shell and sewage sludge are employed as raw material. The as-prepared super-hierarchical porous carbons present high surface areas (3003 m2 g-1), large pore volume (2.04 cm3 g-1), appropriate porosity, and outstanding electrochemical performance. The dependence of electrochemical performance on structural, textural, and functional properties of carbons engineered by various synthesis strategies is investigated in detail. Moreover, the as-assembled symmetrical supercapacitor exhibits high energy density of 25.4 Wh kg-1 at a power density of 225 W kg-1 and retains 20.7 Wh kg-1 even at a very high power of 9000 W kg-1. This work provides an environmentally benign strategy and new insights to efficiently regulate the porosity of hierarchical porous carbons derived from biomass wastes for energy storage applications.

  9. An Efficient, Hierarchical Viewpoint Planning Strategy for Terrestrial Laser Scanner Networks

    Science.gov (United States)

    Jia, F.; Lichti, D. D.

    2018-05-01

    Terrestrial laser scanner (TLS) techniques have been widely adopted in a variety of applications. However, unlike in geodesy or photogrammetry, insufficient attention has been paid to the optimal TLS network design. It is valuable to develop a complete design system that can automatically provide an optimal plan, especially for high-accuracy, large-volume scanning networks. To achieve this goal, one should look at the "optimality" of the solution as well as the computational complexity in reaching it. In this paper, a hierarchical TLS viewpoint planning strategy is developed to solve the optimal scanner placement problems. If one targeted object to be scanned is simplified as discretized wall segments, any possible viewpoint can be evaluated by a score table representing its visible segments under certain scanning geometry constraints. Thus, the design goal is to find a minimum number of viewpoints that achieves complete coverage of all wall segments. The efficiency is improved by densifying viewpoints hierarchically, instead of a "brute force" search within the entire workspace. The experiment environments in this paper were simulated from two buildings located on University of Calgary campus. Compared with the "brute force" strategy in terms of the quality of the solutions and the runtime, it is shown that the proposed strategy can provide a scanning network with a compatible quality but with more than a 70 % time saving.

  10. Estudio climático y bioclimático del Parque Natural Sierra de Grazalema

    OpenAIRE

    Naranjo Barea, Alfonso Jesús

    2016-01-01

    El Parque Natural Sierra de Grazalema, uno de los ámbitos más interesantes desde el punto de vista climático y bioclimático de la península, no está lo suficientemente estudiado. Por ello, en primer lugar, afrontamos un estudio climático de detalle, donde se analizan en profundidad las dos variables climáticas más relevantes (temperatura y precipitación). En vista de que la cartografía climática pública es muy general, hemos elaborado, con los valores térmicos y pluviométricos anuales disponi...

  11. Caracterización de patrones bioclimáticos en tejidos urbanos residenciales

    Directory of Open Access Journals (Sweden)

    Luz Alicia Cárdenas Jirón

    2012-05-01

    Full Text Available El microclima urbano es la resultante de una interacción entre la morfología urbana y el medio ambiente; y su estudio importa porque determina las condiciones de confort térmico en los espacios exteriores a la vivienda y por tanto su uso. Se parte del supuesto que la evaluación energética del entorno urbano no se considera en la actividad proyectual de conjuntos habitacionales. Por ello, el objetivo principal de esta tesis fue investigar el comportamiento energético de tejidos urbanos residenciales contemporáneos, aplicado a dos modelos de habitar: la ciudad jardín y la ciudad de bloque. Se postuló que si a una configuración espacial dada, le corresponde un comportamiento energético singular, entonces sería posible descifrar un patrón morfo-climático. El urbanismo bioclimático enmarca el enfoque teórico de la discusión, y el trabajo de campo se situó en un barrio residencial del pericentro en la metrópolis de Santiago de Chile. El método de caso analizó las dos tipologías de tejidos e integró los parámetros bioclimáticos: temperatura del aire, humedad relativa, radiación solar, y vientos para evaluar su desempeño energético. Los resultados demostraron que el rendimiento energético de los tejidos urbanos variaba según la tipología y con ello fue posible descifrar un patrón bioclimático. Este conocimiento es aplicable a la planificación y al diseño urbano sostenible. Abstract: Urban microclimate is a result of interaction between urban morphology and environment at micro-scale. Its study relevance lies on thermal comfort in outdoor spaces so habitat. It is assumed that energy performance of urban surrounding is not considered at design stage of architectural project. Main purpose of current research was to study energy performance of residential urban fabric applied to two urbanized models: garden city and Corbusier city. Rationale was if spatial configuration influences energy performance then those models would

  12. Real-Time Pricing-Based Scheduling Strategy in Smart Grids: A Hierarchical Game Approach

    Directory of Open Access Journals (Sweden)

    Jie Yang

    2014-01-01

    Full Text Available This paper proposes a scheduling strategy based on real-time pricing in smart grids. A hierarchical game is employed to analyze the decision-making process of generators and consumers. We prove the existence and uniqueness of Nash equilibrium and utilize a backward induction method to obtain the generation and consumption strategies. Then, we propose two dynamic algorithms for the generators and consumers to search for the equilibrium in a distributed fashion. Simulation results demonstrate that the proposed scheduling strategy can match supply with demand and shift load away from peak time.

  13. Strategy Implementation through Hierarchical Couplings in a Management Control Package: An Explorative Case Study

    OpenAIRE

    van der Kolk, Berend; Schokker, Tom

    2016-01-01

    We examine how couplings of management control (MC) elements help to implement an organization’s strategy. Despite prior research stating that couplings between MC elements form fruitful soil for further research, empirical studies in this area are still scarce. We draw on coupling theory to explore three hierarchical relations between MC elements, and examine how these couplings help to implement the organization’s strategy. We conducted a single case study in a medium-sized Dutch municipali...

  14. An enhanced hierarchical control strategy for the Internet of Things-based home scale microgrid

    DEFF Research Database (Denmark)

    Guan, Yajuan; Quintero, Juan Carlos Vasquez; Guerrero, Josep M.

    2017-01-01

    As the intelligent control and detection technology improving, more and more smart devices/sensors can be used to increase the living standard. In order to integrate the Internet of Things (IoT) with microgrid (MG), an enhanced hierarchical control strategy for IoT-based home scale MG is proposed...

  15. Hierarchical Targeting Strategy for Enhanced Tumor Tissue Accumulation/Retention and Cellular Internalization.

    Science.gov (United States)

    Wang, Sheng; Huang, Peng; Chen, Xiaoyuan

    2016-09-01

    Targeted delivery of therapeutic agents is an important way to improve the therapeutic index and reduce side effects. To design nanoparticles for targeted delivery, both enhanced tumor tissue accumulation/retention and enhanced cellular internalization should be considered simultaneously. So far, there have been very few nanoparticles with immutable structures that can achieve this goal efficiently. Hierarchical targeting, a novel targeting strategy based on stimuli responsiveness, shows good potential to enhance both tumor tissue accumulation/retention and cellular internalization. Here, the recent design and development of hierarchical targeting nanoplatforms, based on changeable particle sizes, switchable surface charges and activatable surface ligands, will be introduced. In general, the targeting moieties in these nanoplatforms are not activated during blood circulation for efficient tumor tissue accumulation, but re-activated by certain internal or external stimuli in the tumor microenvironment for enhanced cellular internalization. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. A hypercrosslinking-induced self-assembly strategy for preparation of advanced hierarchical porous polymers with customizable functional components.

    Science.gov (United States)

    Xu, Hongji; Wu, Jinlun; Zheng, Bingna; Mai, Weicong; Xu, Fei; Chen, Luyi; Liu, Hao; Fu, Ruowen; Wu, Dingcai; Matyjaszewski, Krzysztof

    2017-05-09

    The fabrication of advanced hierarchical porous polymers with a unique 3D nanonetwork structure composed of functional core-microporous shell nanoparticles was reported based on the development of a simple and efficient hypercrosslinking-induced self-assembly strategy.

  17. Hierarchical prisoner’s dilemma in hierarchical game for resource competition

    Science.gov (United States)

    Fujimoto, Yuma; Sagawa, Takahiro; Kaneko, Kunihiko

    2017-07-01

    Dilemmas in cooperation are one of the major concerns in game theory. In a public goods game, each individual cooperates by paying a cost or defecting without paying it, and receives a reward from the group out of the collected cost. Thus, defecting is beneficial for each individual, while cooperation is beneficial for the group. Now, groups (say, countries) consisting of individuals also play games. To study such a multi-level game, we introduce a hierarchical game in which multiple groups compete for limited resources by utilizing the collected cost in each group, where the power to appropriate resources increases with the population of the group. Analyzing this hierarchical game, we found a hierarchical prisoner’s dilemma, in which groups choose the defecting policy (say, armament) as a Nash strategy to optimize each group’s benefit, while cooperation optimizes the total benefit. On the other hand, for each individual, refusing to pay the cost (say, tax) is a Nash strategy, which turns out to be a cooperation policy for the group, thus leading to a hierarchical dilemma. Here the group reward increases with the group size. However, we find that there exists an optimal group size that maximizes the individual payoff. Furthermore, when the population asymmetry between two groups is large, the smaller group will choose a cooperation policy (say, disarmament) to avoid excessive response from the larger group, and the prisoner’s dilemma between the groups is resolved. Accordingly, the relevance of this hierarchical game on policy selection in society and the optimal size of human or animal groups are discussed.

  18. Bioclim Deliverable D3: global climatic features over the next million years and recommendation for specific situations to be considered

    International Nuclear Information System (INIS)

    2001-01-01

    The BIOCLIM project aims at assessing the possible long-term impacts of climate change on the safety of waste repositories in deep formations using climate simulations of the long-term climate in various European areas. One of the objectives of the project is to develop two strategies for representing sequential climatic changes to the geosphere-biosphere system for different sites over Europe, addressing the time scale of one million years. The results of this work will be interpreted in terms of global or regional changes of climate and of vegetation. The first strategy (hierarchical strategy) will use the full hierarchy of existing climate models (a climate model is a numerical simplified representation of the climate system behaviour and evolution). Simple models (LLN 2-D NH and threshold models; see the description here after) will simulate the overall long-term evolution of the global climate. Their results will then be used as inputs to more complex models (LMD climate models possibly coupled with vegetation models, either SECHIBA or ORCHIDE) and finally climate and vegetation cover will be determined for specific sites at specific times. A second strategy (integrated strategy) will consist in building an integrated climate model, which represents most of the physical mechanisms for studying long-term climatic variations. The results will then be interpreted on a regional scale. This deliverable is the first step of the hierarchical strategy. The purpose of this deliverable is to identify and justify some specific climatic situations amongst different long-term simulations that are of interest for assessing the safety of radioactive waste repository sites and that will be further studied with GCMs (General Circulation Model). The simple threshold (or multi-state) climate model is a modified version of the model from Paillard. It describes the time evolution of the ice volume and the CO 2 concentration. It has two distinct regimes (interglacial and glacial

  19. Modelling sequential Biosphere systems under Climate change for radioactive waste disposal. Project BIOCLIM

    International Nuclear Information System (INIS)

    Texier, D.; Degnan, P.; Loutre, M.F.; Lemaitre, G.; Paillard, D.; Thorne, M.

    2000-01-01

    The BIOCLIM project (Modelling Sequential Biosphere systems under Climate change for Radioactive Waste Disposal) is part of the EURATOM fifth European framework programme. The project was launched in October 2000 for a three-year period. It is coordinated by ANDRA, the French national radioactive waste management agency. The project brings together a number of European radioactive waste management organisations that have national responsibilities for the safe disposal of radioactive wastes, and several highly experienced climate research teams. Waste management organisations involved are: NIREX (UK), GRS (Germany), ENRESA (Spain), NRI (Czech Republic) and ANDRA (France). Climate research teams involved are: LSCE (CEA/CNRS, France), CIEMAT (Spain), UPMETSIMM (Spain), UCL/ASTR (Belgium) and CRU (UEA, UK). The Environmental Agency for England and Wales provides a regulatory perspective. The consulting company Enviros Consulting (UK) assists ANDRA by contributing to both the administrative and scientific aspects of the project. This paper describes the project and progress to date. (authors)

  20. Hierarchical Control Strategy for Active Hydropneumatic Suspension Vehicles Based on Genetic Algorithms

    Directory of Open Access Journals (Sweden)

    Jinzhi Feng

    2015-02-01

    Full Text Available A new hierarchical control strategy for active hydropneumatic suspension systems is proposed. This strategy considers the dynamic characteristics of the actuator. The top hierarchy controller uses a combined control scheme: a genetic algorithm- (GA- based self-tuning proportional-integral-derivative controller and a fuzzy logic controller. For practical implementations of the proposed control scheme, a GA-based self-learning process is initiated only when the defined performance index of vehicle dynamics exceeds a certain debounce time threshold. The designed control algorithm is implemented on a virtual prototype and cosimulations are performed with different road disturbance inputs. Cosimulation results show that the active hydropneumatic suspension system designed in this study significantly improves riding comfort characteristics of vehicles. The robustness and adaptability of the proposed controller are also examined when the control system is subjected to extremely rough road conditions.

  1. Multiple-Time-Scales Hierarchical Frequency Stability Control Strategy of Medium-Voltage Isolated Microgrid

    DEFF Research Database (Denmark)

    Zhao, Zhuoli; Yang, Ping; Guerrero, Josep M.

    2016-01-01

    In this paper, an islanded medium-voltage (MV) microgrid placed in Dongao Island is presented, which integrates renewable-energy-based distributed generations (DGs), energy storage system (ESS), and local loads. In an isolated microgrid without connection to the main grid to support the frequency......, it is more complex to control and manage. Thus in order to maintain the frequency stability in multiple-time-scales, a hierarchical control strategy is proposed. The proposed control architecture divides the system frequency in three zones: (A) stable zone, (B) precautionary zone and (C) emergency zone...... of Zone B. Theoretical analysis, time-domain simulation and field test results under various conditions and scenarios in the Dongao Island microgrid are presented to prove the validity of the introduced control strategy....

  2. Programmable DNA tile self-assembly using a hierarchical sub-tile strategy.

    Science.gov (United States)

    Shi, Xiaolong; Lu, Wei; Wang, Zhiyu; Pan, Linqiang; Cui, Guangzhao; Xu, Jin; LaBean, Thomas H

    2014-02-21

    DNA tile based self-assembly provides a bottom-up approach to construct desired nanostructures. DNA tiles have been directly constructed from ssDNA and readily self-assembled into 2D lattices and 3D superstructures. However, for more complex lattice designs including algorithmic assemblies requiring larger tile sets, a more modular approach could prove useful. This paper reports a new DNA 'sub-tile' strategy to easily create whole families of programmable tiles. Here, we demonstrate the stability and flexibility of our sub-tile structures by constructing 3-, 4- and 6-arm DNA tiles that are subsequently assembled into 2D lattices and 3D nanotubes according to a hierarchical design. Assembly of sub-tiles, tiles, and superstructures was analyzed using polyacrylamide gel electrophoresis and atomic force microscopy. DNA tile self-assembly methods provide a bottom-up approach to create desired nanostructures; the sub-tile strategy adds a useful new layer to this technique. Complex units can be made from simple parts. The sub-tile approach enables the rapid redesign and prototyping of complex DNA tile sets and tiles with asymmetric designs.

  3. Nearly Cyclic Pursuit and its Hierarchical variant for Multi-agent Systems

    DEFF Research Database (Denmark)

    Iqbal, Muhammad; Leth, John-Josef; Ngo, Trung Dung

    2015-01-01

    The rendezvous problem for multiple agents under nearly cyclic pursuit and hierarchical nearly cyclic pursuit is discussed in this paper. The control law designed under nearly cyclic pursuit strategy enables the agents to converge at a point dictated by a beacon. A hierarchical version of the nea......The rendezvous problem for multiple agents under nearly cyclic pursuit and hierarchical nearly cyclic pursuit is discussed in this paper. The control law designed under nearly cyclic pursuit strategy enables the agents to converge at a point dictated by a beacon. A hierarchical version...

  4. Programmable DNA tile self-assembly using a hierarchical sub-tile strategy

    International Nuclear Information System (INIS)

    Shi, Xiaolong; Lu, Wei; Wang, Zhiyu; Pan, Linqiang; Cui, Guangzhao; Xu, Jin; LaBean, Thomas H

    2014-01-01

    DNA tile based self-assembly provides a bottom-up approach to construct desired nanostructures. DNA tiles have been directly constructed from ssDNA and readily self-assembled into 2D lattices and 3D superstructures. However, for more complex lattice designs including algorithmic assemblies requiring larger tile sets, a more modular approach could prove useful. This paper reports a new DNA ‘sub-tile’ strategy to easily create whole families of programmable tiles. Here, we demonstrate the stability and flexibility of our sub-tile structures by constructing 3-, 4- and 6-arm DNA tiles that are subsequently assembled into 2D lattices and 3D nanotubes according to a hierarchical design. Assembly of sub-tiles, tiles, and superstructures was analyzed using polyacrylamide gel electrophoresis and atomic force microscopy. DNA tile self-assembly methods provide a bottom-up approach to create desired nanostructures; the sub-tile strategy adds a useful new layer to this technique. Complex units can be made from simple parts. The sub-tile approach enables the rapid redesign and prototyping of complex DNA tile sets and tiles with asymmetric designs. (paper)

  5. Thermal bioclimate in idealized urban street canyons in Campinas, Brazil

    Science.gov (United States)

    Abreu-Harbich, Loyde V.; Labaki, Lucila C.; Matzarakis, Andreas

    2014-01-01

    Among several urban design parameters, the height-to-width ratio (H/W) and orientation are important parameters strongly affecting thermal conditions in cities. This paper quantifies changes in thermal comfort due to typical urban canyon configurations in Campinas, Brazil, and presents urban guidelines concerning H/W ratios and green spaces to adapt urban climate change. The study focuses on thermal comfort issues of humans in urban areas and performs evaluation in terms of physiologically equivalent temperature (PET), based on long-term data. Meteorological data of air temperature, relative humidity, wind speed and solar radiation over a 7-year period (2003-2010) were used. A 3D street canyon model was designed with RayMan Pro software to simulate the influence of urban configuration on urban thermal climate. The following configurations and setups were used. The model canyon was 500 m in length, with widths 9, 21, and 44 m. Its height varied in steps of 2.5 m, from 5 to 40 m. The canyon could be rotated in steps of 15°. The results show that urban design parameters such as width, height, and orientation modify thermal conditions within street canyons. A northeast-southwest orientation can reduce PET during daytime more than other scenarios. Forestry management and green areas are recommended to promote shade on pedestrian areas and on façades, and to improve bioclimate thermal stress, in particular for H/W ratio less than 0.5. The method and results can be applied by architects and urban planners interested in developing responsive guidelines for urban climate issues.

  6. Hierarchical control of vehicular fuel cell / battery hybrid powertrain

    OpenAIRE

    Xu, Liangfei; Ouyang, Minggao; Li, Jianqiu; Hua, Jianfeng

    2010-01-01

    In a proton exchange membrane (PEM) fuel cell/battery hybrid vehicle, a fuel cell system fulfills the stationary power demand, and a traction battery provides the accelerating power and recycles braking energy. The entire system is coordinated by a distributed control system, incorporating three key strategies: 1) vehicle control, 2) fuel cell control and 3) battery management. They make up a hierarchical control system. This paper introduces a hierarchical control strategy for a fuel cell / ...

  7. Aporte del diseño bioclimático a la sustentabilidad de áreas urbanas en zonas áridas

    Directory of Open Access Journals (Sweden)

    Mario Cunsulo

    2003-01-01

    Full Text Available Partiendo de la certeza ineludible de que toda estrategia tendiente a la sustentabilidad de los asentamientos humanos requiere indefectiblemente programas sistemáticos de sustitución energética, la aplicación masiva de la oferta climática en la construcción del hábitat regional es un componente esencial en dicha sustitución de recursos energéticos renovables. En ese contexto, el trabajo presenta algunas recomendaciones de diseño urbano bioclimático, producto de investigaciones realizadas por el Area Arquitectura Ambiental de la Facultad de Arquitectura y Diseño sobre la ciudad de San Juan (Argentina, localizada en la Franja Arida de América del Sur.

  8. Review of Active and Reactive Power Sharing Strategies in Hierarchical Controlled Microgrids

    DEFF Research Database (Denmark)

    Han, Yang; Li, Hong; Shen, Pan

    2017-01-01

    Microgrids consist of multiple parallel-connected distributed generation (DG) units with coordinated control strategies, which are able to operate in both grid-connected and islanded mode. Microgrids are attracting more and more attention since they can alleviate the stress of main transmission...... systems, reduce feeder losses, and improve system power quality. When the islanded microgrids are concerned, it is important to maintain system stability and achieve load power sharing among the multiple parallel-connected DG units. However, the poor active and reactive power sharing problems due...... in this paper for active power sharing. Moreover, nonlinear and unbalanced loads could further affect the reactive power sharing when regulating the active power, and it is difficult to share the reactive power accurately only by using the enhanced virtual impedance method. Therefore, the hierarchical control...

  9. Hierarchically Nanostructured Materials for Sustainable Environmental Applications

    Directory of Open Access Journals (Sweden)

    Zheng eRen

    2013-11-01

    Full Text Available This article presents a comprehensive overview of the hierarchical nanostructured materials with either geometry or composition complexity in environmental applications. The hierarchical nanostructures offer advantages of high surface area, synergistic interactions and multiple functionalities towards water remediation, environmental gas sensing and monitoring as well as catalytic gas treatment. Recent advances in synthetic strategies for various hierarchical morphologies such as hollow spheres and urchin-shaped architectures have been reviewed. In addition to the chemical synthesis, the physical mechanisms associated with the materials design and device fabrication have been discussed for each specific application. The development and application of hierarchical complex perovskite oxide nanostructures have also been introduced in photocatalytic water remediation, gas sensing and catalytic converter. Hierarchical nanostructures will open up many possibilities for materials design and device fabrication in environmental chemistry and technology.

  10. La ordenanza bioclimática de Tres Cantos, Madrid. Últimos avances en planificación ambiental y sostenible./ The ordinance bioclimatic Tres Cantos, Madrid. Recent developments in environmental planning and sustainable.

    Directory of Open Access Journals (Sweden)

    Higueras García, Ester

    2009-06-01

    Full Text Available Aunque es de todos reconocida la importancia de planificar con criterios ambientales, son muy pocos los casos en los que estos criterios pasan de los objetivos a las propuestas. En el caso de la localidad de Tres Cantos (Madrid se ha obtenido un importante reto: la aprobación de una ordenanza, denominada Ordenanza Bioclimática, que impulsa el desarrollo urbano equilibrado con su territorio, reduce los consumos de suelo y agua, es respetuosa con el paisaje e incentiva la edificación bioclimática frente a otras convencionales./Despite the well-known relevancy of environmental criteria relating to urban planning, they often remain as objectives and do not become proposals. In the case of Tres Cantos, an important challenge has been proposed: the approval of an ordinance, called Bioclimatic Ordinance, that promotes a proportional urban development relating to the territory, that reduces the use of ground and water, that is respectful towards the landscape and encourages bioclimatic construction against the traditional one.

  11. Incidencia del clima local en los procesos de planificación territorial: Análisis bioclimático de la Costa del Sol Occidental de Málaga (España

    Directory of Open Access Journals (Sweden)

    José Luis Pérez

    2015-01-01

    Full Text Available Frente al excesivo consumo energético en el acondicionamiento térmico residencial, este estudio investiga la implicancia del clima local en las estrategias de expansión urbana, así como su grado de afección a las condiciones de confort, en el contexto mediterráneo español de la Costa del Sol Occidental. Para ello se realiza un análisis bioclimático territorial, identificando los diversos climas locales existentes y las diferentes respuestas biológicas asociadas a cada uno de ellos. Con estos resultados se elabora una clasificación del lugar desde la óptica de la idoneidad bioclimática. Esta herramienta ha permitido evaluar los procesos de planificación territorial, concluyéndose que el 80,6% del suelo urbano y urbanizable no se beneficia de las condiciones climáticas más favorables, las cuales constituyen el 47,3% del territorio analizado. Esta información, puesta al servicio de mejorar las condiciones térmicas de las ciudades, puede ser útil en el diseño y distribución de futuras áreas urbanas.

  12. Optimal risky bidding strategy for a generating company by self-organising hierarchical particle swarm optimisation

    International Nuclear Information System (INIS)

    Boonchuay, Chanwit; Ongsakul, Weerakorn

    2011-01-01

    In this paper, an optimal risky bidding strategy for a generating company (GenCo) by self-organising hierarchical particle swarm optimisation with time-varying acceleration coefficients (SPSO-TVAC) is proposed. A significant risk index based on mean-standard deviation ratio (MSR) is maximised to provide the optimal bid prices and quantities. The Monte Carlo (MC) method is employed to simulate rivals' behaviour in competitive environment. Non-convex operating cost functions of thermal generating units and minimum up/down time constraints are taken into account. The proposed bidding strategy is implemented in a multi-hourly trading in a uniform price spot market and compared to other particle swarm optimisation (PSO). Test results indicate that the proposed SPSO-TVAC approach can provide a higher MSR than the other PSO methods. It is potentially applicable to risk management of profit variation of GenCo in spot market.

  13. Active Power Quality Improvement Strategy for Grid-connected Microgrid Based on Hierarchical Control

    DEFF Research Database (Denmark)

    Wei, Feng; Sun, Kai; Guan, Yajuan

    2018-01-01

    proposes an active, unbalanced, and harmonic GCC suppression strategy based on hierarchical theory. The voltage error between the bus of the DCGC-MG and the grid’s PCC was transformed to the dq frame. On the basis of the grid, an additional compensator, which consists of multiple resonant voltage......When connected to a distorted grid utility, droop-controlled grid-connected microgrids (DCGC-MG) exhibit low equivalent impedance. The harmonic and unbalanced voltage at the point of common coupling (PCC) deteriorates the power quality of the grid-connected current (GCC) of DCGC-MG. This work...... regulators, was then added to the original secondary control to generate the negative fundamental and unbalanced harmonic voltage reference. Proportional integral and multiple resonant controllers were adopted as voltage controller at the original primary level to improve the voltage tracking performance...

  14. A first approach to calculate BIOCLIM variables and climate zones for Antarctica

    Science.gov (United States)

    Wagner, Monika; Trutschnig, Wolfgang; Bathke, Arne C.; Ruprecht, Ulrike

    2018-02-01

    For testing the hypothesis that macroclimatological factors determine the occurrence, biodiversity, and species specificity of both symbiotic partners of Antarctic lecideoid lichens, we present a first approach for the computation of the full set of 19 BIOCLIM variables, as available at http://www.worldclim.org/ for all regions of the world with exception of Antarctica. Annual mean temperature (Bio 1) and annual precipitation (Bio 12) were chosen to define climate zones of the Antarctic continent and adjacent islands as required for ecological niche modeling (ENM). The zones are based on data for the years 2009-2015 which was obtained from the Antarctic Mesoscale Prediction System (AMPS) database of the Ohio State University. For both temperature and precipitation, two separate zonings were specified; temperature values were divided into 12 zones (named 1 to 12) and precipitation values into five (named A to E). By combining these two partitions, we defined climate zonings where each geographical point can be uniquely assigned to exactly one zone, which allows an immediate explicit interpretation. The soundness of the newly calculated climate zones was tested by comparison with already published data, which used only three zones defined on climate information from the literature. The newly defined climate zones result in a more precise assignment of species distribution to the single habitats. This study provides the basis for a more detailed continental-wide ENM using a comprehensive dataset of lichen specimens which are located within 21 different climate regions.

  15. Zoneamento bioclimático para a raça ovina Dorper no Estado de Pernambuco

    Directory of Open Access Journals (Sweden)

    Aline Medeiros de Paula Mendes

    2014-12-01

    Full Text Available O objetivo deste trabalho foi realizar o zoneamento bioclimático para ovinos da raça Dorper, no Estado de Pernambuco. Foram utilizados dados meteorológicos médios diários de 246 postos meteorológicos no estado. As variáveis temperatura do ar e umidade relativa do ar foram utilizadas para o cálculo do índice de temperatura e umidade. Com os valores destas variáveis, traçaram-se as isolinhas por meio do programa Surfer. A região do Agreste pernambucano apresenta melhores condições climáticas para a raça Dorper, durante todo o ano, do que a região que compreende o litoral, a Zona da Mata e o Semiárido. Nos meses mais quentes e nas regiões mais críticas, como o Sertão, é necessária a implementação de manejo, como o provimento de sombra, para amenizar o estresse pelo calor e não comprometer o desempenho produtivo da raça.

  16. Sustainable solid-state strategy to hierarchical core-shell structured Fe 3 O 4 @graphene towards a safer and green sodium ion full battery

    KAUST Repository

    Ding, Xiang; Huang, Xiaobing; Jin, Junling; Ming, Hai; Wang, Limin; Ming, Jun

    2017-01-01

    A sustainable solid-state strategy of SPEX milling is developed to coat metal oxide (e.g., Fe3O4) with tunable layers of graphene, and a new hierarchical core-shell structured Fe3O4@graphene composite is constructed. The presented green process can

  17. Optimization of Hierarchical Modulation for Use of Scalable Media

    Directory of Open Access Journals (Sweden)

    Heneghan Conor

    2010-01-01

    Full Text Available This paper studies the Hierarchical Modulation, a transmission strategy of the approaching scalable multimedia over frequency-selective fading channel for improving the perceptible quality. An optimization strategy for Hierarchical Modulation and convolutional encoding, which can achieve the target bit error rates with minimum global signal-to-noise ratio in a single-user scenario, is suggested. This strategy allows applications to make a free choice of relationship between Higher Priority (HP and Lower Priority (LP stream delivery. The similar optimization can be used in multiuser scenario. An image transport task and a transport task of an H.264/MPEG4 AVC video embedding both QVGA and VGA resolutions are simulated as the implementation example of this optimization strategy, and demonstrate savings in SNR and improvement in Peak Signal-to-Noise Ratio (PSNR for the particular examples shown.

  18. Effects of a GPC-PID control strategy with hierarchical structure for a cooling coil unit

    International Nuclear Information System (INIS)

    Xu Min; Li Shaoyuan; Cai Wenjian; Lu Lu

    2006-01-01

    This paper presents a GPC-PID control strategy for a cooling-coil unit in heating, ventilation and air conditioning systems. By analysis of the cooling towers and chillers, different models in the occupied period are considered in each operating condition. Because of the complication of components, well tuned PID controllers are unsatisfied, and the results are poor over a wide range of operation conditions. To solve this problem, a GPC-PID controller with hierarchical structure is proposed based on minimizing the generalized predictive control criterion to tune conventional PID controller parameters. Simulation and experiments show that the proposed controller is able to deal with a wide range of operating conditions and to achieve better performance than conventional methods

  19. Hierarchical scaffolds enhance osteogenic differentiation of human Wharton’s jelly derived stem cells

    International Nuclear Information System (INIS)

    Canha-Gouveia, Analuce; Rita Costa-Pinto, Ana; Martins, Albino M; Sousa, Rui A; Reis, Rui L; Neves, Nuno M; Silva, Nuno A; Salgado, António J; Sousa, Nuno; Faria, Susana

    2015-01-01

    Hierarchical structures, constituted by polymeric nano and microfibers, have been considered promising scaffolds for tissue engineering strategies, mainly because they mimic, in some way, the complexity and nanoscale detail observed in real organs. The chondrogenic potential of these scaffolds has been previously demonstrated, but their osteogenic potential is not yet corroborated. In order to assess if a hierarchical structure, with nanoscale details incorporated, is an improved scaffold for bone tissue regeneration, we evaluate cell adhesion, proliferation, and osteogenic differentiation of human Wharton’s jelly derived stem cells (hWJSCs), seeded into hierarchical fibrous scaffolds. Biological data corroborates that hierarchical fibrous scaffolds show an enhanced cell entrapment when compared to rapid prototyped scaffolds without nanofibers. Furthermore, upregulation of bone specific genes and calcium phosphate deposition confirms the successful osteogenic differentiation of hWJSCs on these scaffolds. These results support our hypothesis that a scaffold with hierarchical structure, in conjugation with hWJSCs, represents a possible feasible strategy for bone tissue engineering applications. (paper)

  20. A Hierarchical Optimal Operation Strategy of Hybrid Energy Storage System in Distribution Networks with High Photovoltaic Penetration

    Directory of Open Access Journals (Sweden)

    Jian Chen

    2018-02-01

    Full Text Available In this paper, a hierarchical optimal operation strategy for a hybrid energy storage system (HESS is proposed, which is suitable to be utilized in distribution networks (DNs with high photovoltaic (PV penetration to achieve PV power smoothing, voltage regulation and price arbitrage. Firstly, a fuzzy-logic based variable step-size control strategy for an ultracapacitor (UC with the improvement of the lifetime of UC and tracking performance is adopted to smooth PV power fluctuations. The impact of PV forecasting errors is eliminated by adjusting the UC power in real time. Secondly, a coordinated control strategy, which includes centralized and local controls, is proposed for lithium-ion batteries. The centralized control is structured to determine the optimal battery unit for voltage regulation or price arbitrage according to lithium-ion battery performance indices. A modified lithium-ion battery aging model with better accuracy is proposed and the coupling relationship between the lifetime and the effective capacity is also considered. Additionally, the local control of the selected lithium-ion battery unit determines the charging/discharging power. A case study is used to validate the operation strategy and the results show that the lifetime equilibrium among different lithium-ion battery units can be achieved using the proposed strategy.

  1. Searching for continuous gravitational wave signals. The hierarchical Hough transform algorithm

    International Nuclear Information System (INIS)

    Papa, M.; Schutz, B.F.; Sintes, A.M.

    2001-01-01

    It is well known that matched filtering techniques cannot be applied for searching extensive parameter space volumes for continuous gravitational wave signals. This is the reason why alternative strategies are being pursued. Hierarchical strategies are best at investigating a large parameter space when there exist computational power constraints. Algorithms of this kind are being implemented by all the groups that are developing software for analyzing the data of the gravitational wave detectors that will come online in the next years. In this talk I will report about the hierarchical Hough transform method that the GEO 600 data analysis team at the Albert Einstein Institute is developing. The three step hierarchical algorithm has been described elsewhere [8]. In this talk I will focus on some of the implementational aspects we are currently concerned with. (author)

  2. Hierarchical virtual screening approaches in small molecule drug discovery.

    Science.gov (United States)

    Kumar, Ashutosh; Zhang, Kam Y J

    2015-01-01

    Virtual screening has played a significant role in the discovery of small molecule inhibitors of therapeutic targets in last two decades. Various ligand and structure-based virtual screening approaches are employed to identify small molecule ligands for proteins of interest. These approaches are often combined in either hierarchical or parallel manner to take advantage of the strength and avoid the limitations associated with individual methods. Hierarchical combination of ligand and structure-based virtual screening approaches has received noteworthy success in numerous drug discovery campaigns. In hierarchical virtual screening, several filters using ligand and structure-based approaches are sequentially applied to reduce a large screening library to a number small enough for experimental testing. In this review, we focus on different hierarchical virtual screening strategies and their application in the discovery of small molecule modulators of important drug targets. Several virtual screening studies are discussed to demonstrate the successful application of hierarchical virtual screening in small molecule drug discovery. Copyright © 2014 Elsevier Inc. All rights reserved.

  3. An interference cancellation strategy for broadcast in hierarchical cell structure

    KAUST Repository

    Yang, Yuli; Aï ssa, Sonia; Eltawil, Ahmed M.; Salama, Khaled N.

    2014-01-01

    In this paper, a hierarchical cell structure is considered, where public safety broadcasting is fulfilled in a femtocell located within a macrocell. In the femtocell, also known as local cell, an access point broadcasts to each local node (LN) over an orthogonal frequency sub-band independently. Since the local cell shares the spectrum licensed to the macrocell, a given LN is interfered by transmissions of the macrocell user (MU) in the same sub-band. To improve the broadcast performance in the local cell, a novel scheme is proposed to mitigate the interference from the MU to the LN while achieving diversity gain. For the sake of performance evaluation, ergodic capacity of the proposed scheme is quantified and a corresponding closed-form expression is obtained. By comparing with the traditional scheme that suffers from the MU's interference, numerical results substantiate the advantage of the proposed scheme and provide a useful tool for the broadcast design in hierarchical cell systems.

  4. An interference cancellation strategy for broadcast in hierarchical cell structure

    KAUST Repository

    Yang, Yuli

    2014-12-01

    In this paper, a hierarchical cell structure is considered, where public safety broadcasting is fulfilled in a femtocell located within a macrocell. In the femtocell, also known as local cell, an access point broadcasts to each local node (LN) over an orthogonal frequency sub-band independently. Since the local cell shares the spectrum licensed to the macrocell, a given LN is interfered by transmissions of the macrocell user (MU) in the same sub-band. To improve the broadcast performance in the local cell, a novel scheme is proposed to mitigate the interference from the MU to the LN while achieving diversity gain. For the sake of performance evaluation, ergodic capacity of the proposed scheme is quantified and a corresponding closed-form expression is obtained. By comparing with the traditional scheme that suffers from the MU\\'s interference, numerical results substantiate the advantage of the proposed scheme and provide a useful tool for the broadcast design in hierarchical cell systems.

  5. A facile self-template strategy to fabricate three-dimensional nitrogen-doped hierarchical porous carbon/graphene for conductive agent-free supercapacitors with excellent electrochemical performance

    International Nuclear Information System (INIS)

    Yuanyuan, Yin; Ruiyi, Li; Zaijun, Li; Junkang, Liu; Zhiguo, Gu; Guangli, Wang

    2014-01-01

    Graphical abstract: - Highlights: • The paper reported a facile template-free strategy to fabricate three-dimensional nitrogen-doped hierarchical porous carbon/graphene (3D-NHPC/G). • Such a new concept of strategy creates 3D carbon framework, hierarchical pore distribution, moderate graphitization and appropriate nitrogen doping. • The 3D-NHPC/G offers high electric conductivity, mass transfer and specific surface area. • The 3D-NHPC/G electrode displays an largely enhanced electrochemical performance. - Abstract: Carbon materials with large surface area, high conductivity and suitable pore distribution are highly desirable for high-performance supercapacitors. The paper reported a self-template strategy for the fabrication of three-dimensional nitrogen-doped hierarchical porous carbon/graphene (3D-NHPC/G). The mixture of beer yeast cells, graphite oxide, urea, potassium hydroxide and phytic acid was dispersed in water by ultrasonication to form homogeneous slurry, which was then dried by spray drying and finally heated at 850°C in Ar/H 2 environment. The study shows that such a new strategy creates a 3D carbon framework, hierarchical pore distribution, moderate graphitization and appropriate nitrogen doping. The as-prepared 3D-NHPC/G offers excellent dispersion, specific surface area of 3108.7 m 2 g −1 and electronic conductivity of 3096 S m −1 , which is more than six-fold that of 3D-NHPC (494 S m −1 ). Owing to the greatly enchanced electron transfer and mass transport, the 3D-NHPC/G electrode displays the largely enhanced electrochemical performance. In 6 mol l −1 potassium hydroxide aqueous electrolyte, its specific capacitance is 318 F g −1 at the current density of 1 A g −1 , 277 F g −1 at the current density of 10 A g −1 , and 155 F g −1 at the current density of 100 A g −1 that can remain at least 96.5% after 10000 cycles. In 1 mol l −1 tetraethylammonium tetrafluoroborate organic electrolyte, the specific capacitance is 138

  6. A Review on the Fabrication of Hierarchical ZnO Nanostructures for Photocatalysis Application

    Directory of Open Access Journals (Sweden)

    Yi Xia

    2016-11-01

    Full Text Available Semiconductor photocatalysis provides potential solutions for many energy and environmental-related issues. Recently, various semiconductors with hierarchical nanostructures have been fabricated to achieve efficient photocatalysts owing to their multiple advantages, such as high surface area, porous structures, as well as enhanced light harvesting. ZnO has been widely investigated and considered as the most promising alternative photocatalyst to TiO2. Herein, we present a review on the fabrication methods, growth mechanisms and photocatalytic applications of hierarchical ZnO nanostructures. Various synthetic strategies and growth mechanisms, including multistep sequential growth routes, template-based synthesis, template-free self-organization and precursor or self-templating strategies, are highlighted. In addition, the fabrication of multicomponent ZnO-based nanocomposites with hierarchical structures is also included. Finally, the application of hierarchical ZnO nanostructures and nanocomposites in typical photocatalytic reactions, such as pollutant degradation and H2 evolution, is reviewed.

  7. A General Synthesis Strategy for Hierarchical Porous Metal Oxide Hollow Spheres

    Directory of Open Access Journals (Sweden)

    Huadong Fu

    2015-01-01

    Full Text Available The hierarchical porous TiO2 hollow spheres were successfully prepared by using the hydrothermally synthesized colloidal carbon spheres as templates and tetrabutyl titanate as inorganic precursors. The diameter and wall thickness of hollow TiO2 spheres were determined by the hard templates and concentration of tetrabutyl titanate. The particle size, dispersity, homogeneity, and surface state of the carbon spheres can be easily controlled by adjusting the hydrothermal conditions and adding certain amount of the surfactants. The prepared hollow spheres possessed the perfect spherical shape, monodispersity, and hierarchically pore structures, and the further experiment verified that the present approach can be used to prepare other metal oxide hollow spheres, which could be used as catalysis, fuel cells, lithium-air battery, gas sensor, and so on.

  8. Role of Genetics in the Etiology of Autistic Spectrum Disorder: Towards a Hierarchical Diagnostic Strategy.

    Science.gov (United States)

    Robert, Cyrille; Pasquier, Laurent; Cohen, David; Fradin, Mélanie; Canitano, Roberto; Damaj, Léna; Odent, Sylvie; Tordjman, Sylvie

    2017-03-12

    Progress in epidemiological, molecular and clinical genetics with the development of new techniques has improved knowledge on genetic syndromes associated with autism spectrum disorder (ASD). The objective of this article is to show the diversity of genetic disorders associated with ASD (based on an extensive review of single-gene disorders, copy number variants, and other chromosomal disorders), and consequently to propose a hierarchical diagnostic strategy with a stepwise evaluation, helping general practitioners/pediatricians and child psychiatrists to collaborate with geneticists and neuropediatricians, in order to search for genetic disorders associated with ASD. The first step is a clinical investigation involving: (i) a child psychiatric and psychological evaluation confirming autism diagnosis from different observational sources and assessing autism severity; (ii) a neuropediatric evaluation examining neurological symptoms and developmental milestones; and (iii) a genetic evaluation searching for dysmorphic features and malformations. The second step involves laboratory and if necessary neuroimaging and EEG studies oriented by clinical results based on clinical genetic and neuropediatric examinations. The identification of genetic disorders associated with ASD has practical implications for diagnostic strategies, early detection or prevention of co-morbidity, specific treatment and follow up, and genetic counseling.

  9. Role of Genetics in the Etiology of Autistic Spectrum Disorder: Towards a Hierarchical Diagnostic Strategy

    Science.gov (United States)

    Robert, Cyrille; Pasquier, Laurent; Cohen, David; Fradin, Mélanie; Canitano, Roberto; Damaj, Léna; Odent, Sylvie; Tordjman, Sylvie

    2017-01-01

    Progress in epidemiological, molecular and clinical genetics with the development of new techniques has improved knowledge on genetic syndromes associated with autism spectrum disorder (ASD). The objective of this article is to show the diversity of genetic disorders associated with ASD (based on an extensive review of single-gene disorders, copy number variants, and other chromosomal disorders), and consequently to propose a hierarchical diagnostic strategy with a stepwise evaluation, helping general practitioners/pediatricians and child psychiatrists to collaborate with geneticists and neuropediatricians, in order to search for genetic disorders associated with ASD. The first step is a clinical investigation involving: (i) a child psychiatric and psychological evaluation confirming autism diagnosis from different observational sources and assessing autism severity; (ii) a neuropediatric evaluation examining neurological symptoms and developmental milestones; and (iii) a genetic evaluation searching for dysmorphic features and malformations. The second step involves laboratory and if necessary neuroimaging and EEG studies oriented by clinical results based on clinical genetic and neuropediatric examinations. The identification of genetic disorders associated with ASD has practical implications for diagnostic strategies, early detection or prevention of co-morbidity, specific treatment and follow up, and genetic counseling. PMID:28287497

  10. Microfluidic Droplet-Facilitated Hierarchical Assembly for Dual Cargo Loading and Synergistic Delivery.

    Science.gov (United States)

    Yu, Ziyi; Zheng, Yu; Parker, Richard M; Lan, Yang; Wu, Yuchao; Coulston, Roger J; Zhang, Jing; Scherman, Oren A; Abell, Chris

    2016-04-06

    Bottom-up hierarchical assembly has emerged as an elaborate and energy-efficient strategy for the fabrication of smart materials. Herein, we present a hierarchical assembly process, whereby linear amphiphilic block copolymers are self-assembled into micelles, which in turn are accommodated at the interface of microfluidic droplets via cucurbit[8]uril-mediated host-guest chemistry to form supramolecular microcapsules. The monodisperse microcapsules can be used for simultaneous carriage of both organic (Nile Red) and aqueous-soluble (fluorescein isothiocyanate-dextran) cargo. Furthermore, the well-defined compartmentalized structure benefits from the dynamic nature of the supramolecular interaction and offers synergistic delivery of cargos with triggered release or through photocontrolled porosity. This demonstration of premeditated hierarchical assembly, where interactions from the molecular to microscale are designed, illustrates the power of this route toward accessing the next generation of functional materials and encapsulation strategies.

  11. Challenges and Strategies in the Synthesis of Mesoporous Alumina Powders and Hierarchical Alumina Monoliths

    Directory of Open Access Journals (Sweden)

    Anne Galarneau

    2012-02-01

    Full Text Available A new rapid, very simple and one-step sol-gel strategy for the large-scale preparation of highly porous γ-Al2O3 is presented. The resulting mesoporous alumina materials feature high surface areas (400 m2 g−1, large pore volumes (0.8 mL g−1 and the ��-Al2O3 phase is obtained at low temperature (500 °C. The main advantages and drawbacks of different preparations of mesoporous alumina materials exhibiting high specific surface areas and large pore volumes such as surfactant-nanostructured alumina, sol-gel methods and hierarchically macro-/mesoporous alumina monoliths have been analyzed and compared. The most reproducible synthesis of mesoporous alumina are given. Evaporation-Induced Self-Assembly (EISA is the sole method to lead to nanostructured mesoporous alumina by direct templating, but it is a difficult method to scale-up. Alumina featuring macro- and mesoporosity in monolithic shape is a very promising material for in flow applications; an optimized synthesis is described.

  12. Hierarchically Ordered Nanopatterns for Spatial Control of Biomolecules

    Science.gov (United States)

    2015-01-01

    The development and study of a benchtop, high-throughput, and inexpensive fabrication strategy to obtain hierarchical patterns of biomolecules with sub-50 nm resolution is presented. A diblock copolymer of polystyrene-b-poly(ethylene oxide), PS-b-PEO, is synthesized with biotin capping the PEO block and 4-bromostyrene copolymerized within the polystyrene block at 5 wt %. These two handles allow thin films of the block copolymer to be postfunctionalized with biotinylated biomolecules of interest and to obtain micropatterns of nanoscale-ordered films via photolithography. The design of this single polymer further allows access to two distinct superficial nanopatterns (lines and dots), where the PEO cylinders are oriented parallel or perpendicular to the substrate. Moreover, we present a strategy to obtain hierarchical mixed morphologies: a thin-film coating of cylinders both parallel and perpendicular to the substrate can be obtained by tuning the solvent annealing and irradiation conditions. PMID:25363506

  13. A multi-mode operation control strategy for flexible microgrid based on sliding-mode direct voltage and hierarchical controls.

    Science.gov (United States)

    Zhang, Qinjin; Liu, Yancheng; Zhao, Youtao; Wang, Ning

    2016-03-01

    Multi-mode operation and transient stability are two problems that significantly affect flexible microgrid (MG). This paper proposes a multi-mode operation control strategy for flexible MG based on a three-layer hierarchical structure. The proposed structure is composed of autonomous, cooperative, and scheduling controllers. Autonomous controller is utilized to control the performance of the single micro-source inverter. An adaptive sliding-mode direct voltage loop and an improved droop power loop based on virtual negative impedance are presented respectively to enhance the system disturbance-rejection performance and the power sharing accuracy. Cooperative controller, which is composed of secondary voltage/frequency control and phase synchronization control, is designed to eliminate the voltage/frequency deviations produced by the autonomous controller and prepare for grid connection. Scheduling controller manages the power flow between the MG and the grid. The MG with the improved hierarchical control scheme can achieve seamless transitions from islanded to grid-connected mode and have a good transient performance. In addition the presented work can also optimize the power quality issues and improve the load power sharing accuracy between parallel VSIs. Finally, the transient performance and effectiveness of the proposed control scheme are evaluated by theoretical analysis and simulation results. Copyright © 2015 ISA. Published by Elsevier Ltd. All rights reserved.

  14. Time to failure of hierarchical load-transfer models of fracture

    DEFF Research Database (Denmark)

    Vázquez-Prada, M; Gómez, J B; Moreno, Y

    1999-01-01

    The time to failure, T, of dynamical models of fracture for a hierarchical load-transfer geometry is studied. Using a probabilistic strategy and juxtaposing hierarchical structures of height n, we devise an exact method to compute T, for structures of height n+1. Bounding T, for large n, we are a...... are able to deduce that the time to failure tends to a nonzero value when n tends to infinity. This numerical conclusion is deduced for both power law and exponential breakdown rules....

  15. Hierarchical control of a photovoltaic/battery based DC microgrid including electric vehicle wireless charging station

    DEFF Research Database (Denmark)

    Xiao, Zhao xia; Fan, Haodong; Guerrero, Josep M.

    2017-01-01

    In this paper, the hierarchical control strategy of a photovoltaic/battery based dc microgrid is presented for electric vehicle (EV) wireless charging. Considering irradiance variations, battery charging/discharging requirements, wireless power transmission characteristics, and onboard battery...... coils, receiving coils and compensation capacitors, the wireless power transmission system is designed to be resonant when it is operating at the rated power, with the aim to achieve the optimum transmission system efficiency. Simulation and experimental results of the hierarchical control...... charging power change and other factors, the possible operation states are obtained. A hierarchical control strategy is established, which includes central and local controllers. The central controller is responsible for the selection and transfer of operation states and the management of the local...

  16. Hierarchical ordering with partial pairwise hierarchical relationships on the macaque brain data sets.

    Directory of Open Access Journals (Sweden)

    Woosang Lim

    Full Text Available Hierarchical organizations of information processing in the brain networks have been known to exist and widely studied. To find proper hierarchical structures in the macaque brain, the traditional methods need the entire pairwise hierarchical relationships between cortical areas. In this paper, we present a new method that discovers hierarchical structures of macaque brain networks by using partial information of pairwise hierarchical relationships. Our method uses a graph-based manifold learning to exploit inherent relationship, and computes pseudo distances of hierarchical levels for every pair of cortical areas. Then, we compute hierarchy levels of all cortical areas by minimizing the sum of squared hierarchical distance errors with the hierarchical information of few cortical areas. We evaluate our method on the macaque brain data sets whose true hierarchical levels are known as the FV91 model. The experimental results show that hierarchy levels computed by our method are similar to the FV91 model, and its errors are much smaller than the errors of hierarchical clustering approaches.

  17. Hierarchical adaptive experimental design for Gaussian process emulators

    International Nuclear Information System (INIS)

    Busby, Daniel

    2009-01-01

    Large computer simulators have usually complex and nonlinear input output functions. This complicated input output relation can be analyzed by global sensitivity analysis; however, this usually requires massive Monte Carlo simulations. To effectively reduce the number of simulations, statistical techniques such as Gaussian process emulators can be adopted. The accuracy and reliability of these emulators strongly depend on the experimental design where suitable evaluation points are selected. In this paper a new sequential design strategy called hierarchical adaptive design is proposed to obtain an accurate emulator using the least possible number of simulations. The hierarchical design proposed in this paper is tested on various standard analytic functions and on a challenging reservoir forecasting application. Comparisons with standard one-stage designs such as maximin latin hypercube designs show that the hierarchical adaptive design produces a more accurate emulator with the same number of computer experiments. Moreover a stopping criterion is proposed that enables to perform the number of simulations necessary to obtain required approximation accuracy.

  18. Creating 3D Hierarchical Carbon Architectures with Micro-, Meso-, and Macropores via a Simple Self-Blowing Strategy for a Flow-through Deionization Capacitor.

    Science.gov (United States)

    Zhao, Shanshan; Yan, Tingting; Wang, Hui; Zhang, Jianping; Shi, Liyi; Zhang, Dengsong

    2016-07-20

    In this work, 3D hierarchical carbon architectures (3DHCAs) with micro-, meso-, and macropores were prepared via a simple self-blowing strategy as highly efficient electrodes for a flow-through deionization capacitor (FTDC). The obtained 3DHCAs have a hierarchically porous structure, large accessible specific surface area (2061 m(2) g(-1)), and good wettability. The electrochemical tests show that the 3DHCA electrode has a high specific capacitance and good electric conductivity. The deionization experiments demonstrate that the 3DHCA electrodes possess a high deionization capacity of 17.83 mg g(-1) in a 500 mg L(-1) NaCl solution at 1.2 V. Moreover, the 3DHCA electrodes present a fast deionization rate in 100-500 mg L(-1) NaCl solutions at 0.8-1.4 V. The 3DHCA electrodes also present a good regeneration behavior in the reiterative regeneration test. These above factors render the 3DHCAs a promising FTDC electrode material.

  19. Hierarchical optimal control of large-scale nonlinear chemical processes.

    Science.gov (United States)

    Ramezani, Mohammad Hossein; Sadati, Nasser

    2009-01-01

    In this paper, a new approach is presented for optimal control of large-scale chemical processes. In this approach, the chemical process is decomposed into smaller sub-systems at the first level, and a coordinator at the second level, for which a two-level hierarchical control strategy is designed. For this purpose, each sub-system in the first level can be solved separately, by using any conventional optimization algorithm. In the second level, the solutions obtained from the first level are coordinated using a new gradient-type strategy, which is updated by the error of the coordination vector. The proposed algorithm is used to solve the optimal control problem of a complex nonlinear chemical stirred tank reactor (CSTR), where its solution is also compared with the ones obtained using the centralized approach. The simulation results show the efficiency and the capability of the proposed hierarchical approach, in finding the optimal solution, over the centralized method.

  20. Improving Hierarchical Models Using Historical Data with Applications in High-Throughput Genomics Data Analysis.

    Science.gov (United States)

    Li, Ben; Li, Yunxiao; Qin, Zhaohui S

    2017-06-01

    Modern high-throughput biotechnologies such as microarray and next generation sequencing produce a massive amount of information for each sample assayed. However, in a typical high-throughput experiment, only limited amount of data are observed for each individual feature, thus the classical 'large p , small n ' problem. Bayesian hierarchical model, capable of borrowing strength across features within the same dataset, has been recognized as an effective tool in analyzing such data. However, the shrinkage effect, the most prominent feature of hierarchical features, can lead to undesirable over-correction for some features. In this work, we discuss possible causes of the over-correction problem and propose several alternative solutions. Our strategy is rooted in the fact that in the Big Data era, large amount of historical data are available which should be taken advantage of. Our strategy presents a new framework to enhance the Bayesian hierarchical model. Through simulation and real data analysis, we demonstrated superior performance of the proposed strategy. Our new strategy also enables borrowing information across different platforms which could be extremely useful with emergence of new technologies and accumulation of data from different platforms in the Big Data era. Our method has been implemented in R package "adaptiveHM", which is freely available from https://github.com/benliemory/adaptiveHM.

  1. Hierarchical Bayesian sparse image reconstruction with application to MRFM.

    Science.gov (United States)

    Dobigeon, Nicolas; Hero, Alfred O; Tourneret, Jean-Yves

    2009-09-01

    This paper presents a hierarchical Bayesian model to reconstruct sparse images when the observations are obtained from linear transformations and corrupted by an additive white Gaussian noise. Our hierarchical Bayes model is well suited to such naturally sparse image applications as it seamlessly accounts for properties such as sparsity and positivity of the image via appropriate Bayes priors. We propose a prior that is based on a weighted mixture of a positive exponential distribution and a mass at zero. The prior has hyperparameters that are tuned automatically by marginalization over the hierarchical Bayesian model. To overcome the complexity of the posterior distribution, a Gibbs sampling strategy is proposed. The Gibbs samples can be used to estimate the image to be recovered, e.g., by maximizing the estimated posterior distribution. In our fully Bayesian approach, the posteriors of all the parameters are available. Thus, our algorithm provides more information than other previously proposed sparse reconstruction methods that only give a point estimate. The performance of the proposed hierarchical Bayesian sparse reconstruction method is illustrated on synthetic data and real data collected from a tobacco virus sample using a prototype MRFM instrument.

  2. Preparation of disk-like particles with micro/nano hierarchical structures.

    Science.gov (United States)

    Meng, Zhen; Yang, Wenbo; Chen, Pengpeng; Wang, Weina; Jia, Xudong; Xi, Kai

    2013-10-15

    A facile, reproductive method has been successfully developed to produce disk-like microparticles self-assembled from monodispersed hybrid silica nanoparticles under certain circumstance. The disk-like microparticles with micro/nano hierarchical structures could be obtained in large amount under a mild condition and further used to biomimetic design of the superhydrophobic surface of lotus leaf. After traditional surface modification with dodecyltrichlorosiliane, the static contact angle of water on the surface with micro/nano hierarchical structure could reach 168.8°. The method of surface modification could be further simplified by click reaction with the introduction of thiol groups under mild condition. The present strategy for constructing the surface with micro/nano hierarchical structures offers the advantage of simple and large area fabrication, which enables a variety of superhydrophobic applications. Copyright © 2013 Elsevier Inc. All rights reserved.

  3. Novel hierarchical microparticles super-assembled from nanoparticles with the induction of casein micelles

    Energy Technology Data Exchange (ETDEWEB)

    Xiong, Xiaopeng, E-mail: xpxiong@xmu.edu.cn; Duan, Jiangjiang; Wang, Yong; Yu, Zhaoju [Xiamen University, Department of Materials Science and Engineering, College of Materials (China)

    2013-08-15

    We have demonstrated a solution-based synthesis of novel waxberry-like hierarchical ZnO microparticles in the presence casein micelles under mild conditions. The microstructures of the sub-micrometer-sized hierarchical microparticles were characterized, and the synthesis conditions were optimized. The formation mechanism of the hierarchical microparticle was analyzed through control experiments. The hierarchical ZnO microparticles are found to be super-assemblies of 30-70 nm ZnO nanoparticles, which are thought to be based on casein micelle induction followed by Ostwald ripening. In the same manner, copper-based hierarchical microparticles with a similar morphology have also been successfully synthesized. By controlling the synthetic time or temperature, solid or hollow microparticles can be fabricated. The narrowly distributed ZnO microparticles have a high specific surface area, exhibiting great potential application in fields such as photocatalytic and energy conversion. Our findings may meanwhile open a new bottom-up strategy in order to construct structurally sophisticated nanomaterials.

  4. Novel hierarchical microparticles super-assembled from nanoparticles with the induction of casein micelles

    Science.gov (United States)

    Xiong, Xiaopeng; Duan, Jiangjiang; Wang, Yong; Yu, Zhaoju

    2013-08-01

    We have demonstrated a solution-based synthesis of novel waxberry-like hierarchical ZnO microparticles in the presence casein micelles under mild conditions. The microstructures of the sub-micrometer-sized hierarchical microparticles were characterized, and the synthesis conditions were optimized. The formation mechanism of the hierarchical microparticle was analyzed through control experiments. The hierarchical ZnO microparticles are found to be super-assemblies of 30-70 nm ZnO nanoparticles, which are thought to be based on casein micelle induction followed by Ostwald ripening. In the same manner, copper-based hierarchical microparticles with a similar morphology have also been successfully synthesized. By controlling the synthetic time or temperature, solid or hollow microparticles can be fabricated. The narrowly distributed ZnO microparticles have a high specific surface area, exhibiting great potential application in fields such as photocatalytic and energy conversion. Our findings may meanwhile open a new bottom-up strategy in order to construct structurally sophisticated nanomaterials.

  5. Novel hierarchical microparticles super-assembled from nanoparticles with the induction of casein micelles

    International Nuclear Information System (INIS)

    Xiong, Xiaopeng; Duan, Jiangjiang; Wang, Yong; Yu, Zhaoju

    2013-01-01

    We have demonstrated a solution-based synthesis of novel waxberry-like hierarchical ZnO microparticles in the presence casein micelles under mild conditions. The microstructures of the sub-micrometer-sized hierarchical microparticles were characterized, and the synthesis conditions were optimized. The formation mechanism of the hierarchical microparticle was analyzed through control experiments. The hierarchical ZnO microparticles are found to be super-assemblies of 30–70 nm ZnO nanoparticles, which are thought to be based on casein micelle induction followed by Ostwald ripening. In the same manner, copper-based hierarchical microparticles with a similar morphology have also been successfully synthesized. By controlling the synthetic time or temperature, solid or hollow microparticles can be fabricated. The narrowly distributed ZnO microparticles have a high specific surface area, exhibiting great potential application in fields such as photocatalytic and energy conversion. Our findings may meanwhile open a new bottom-up strategy in order to construct structurally sophisticated nanomaterials

  6. The Relationship between Self-Leadership and Personality: A Comparison of Hierarchical Factor Structures

    OpenAIRE

    Houghton, Jeffery D.

    2000-01-01

    This study examined the relationship between self-leadership and personality through an analysis and comparison of hierarchical factor structures. More specifically, this study examined the relationships between the self-leadership dimensions of behavior-focused strategies, natural reward strategies, and constructive thought strategies, and the personality dimensions of extraversion, emotional stability, and conscientiousness. The results of the study provide evidence that the self-leadershi...

  7. A hierarchical anatomical classification schema for prediction of phenotypic side effects.

    Science.gov (United States)

    Wadhwa, Somin; Gupta, Aishwarya; Dokania, Shubham; Kanji, Rakesh; Bagler, Ganesh

    2018-01-01

    Prediction of adverse drug reactions is an important problem in drug discovery endeavors which can be addressed with data-driven strategies. SIDER is one of the most reliable and frequently used datasets for identification of key features as well as building machine learning models for side effects prediction. The inherently unbalanced nature of this data presents with a difficult multi-label multi-class problem towards prediction of drug side effects. We highlight the intrinsic issue with SIDER data and methodological flaws in relying on performance measures such as AUC while attempting to predict side effects.We argue for the use of metrics that are robust to class imbalance for evaluation of classifiers. Importantly, we present a 'hierarchical anatomical classification schema' which aggregates side effects into organs, sub-systems, and systems. With the help of a weighted performance measure, using 5-fold cross-validation we show that this strategy facilitates biologically meaningful side effects prediction at different levels of anatomical hierarchy. By implementing various machine learning classifiers we show that Random Forest model yields best classification accuracy at each level of coarse-graining. The manually curated, hierarchical schema for side effects can also serve as the basis of future studies towards prediction of adverse reactions and identification of key features linked to specific organ systems. Our study provides a strategy for hierarchical classification of side effects rooted in the anatomy and can pave the way for calibrated expert systems for multi-level prediction of side effects.

  8. Biominerals- hierarchical nanocomposites: the example of bone

    Science.gov (United States)

    Beniash, Elia

    2010-01-01

    Many organisms incorporate inorganic solids in their tissues to enhance their functional, primarily mechanical, properties. These mineralized tissues, also called biominerals, are unique organo-mineral nanocomposites, organized at several hierarchical levels, from nano- to macroscale. Unlike man made composite materials, which often are simple physical blends of their components, the organic and inorganic phases in biominerals interface at the molecular level. Although these tissues are made of relatively weak components at ambient conditions, their hierarchical structural organization and intimate interactions between different elements lead to superior mechanical properties. Understanding basic principles of formation, structure and functional properties of these tissues might lead to novel bioinspired strategies for material design and better treatments for diseases of the mineralized tissues. This review focuses on general principles of structural organization, formation and functional properties of biominerals on the example the bone tissues. PMID:20827739

  9. Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal-Organic Frameworks

    KAUST Repository

    Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang; Tan, Kui; Li, Jia-Luo; Kirchon, Angelo; Liu, Ling-Mei; Zhang, Peng; Han, Yu; Chabal, Yves J.; Zhou, Hong-Cai

    2018-01-01

    strate-gy, linker thermolysis, to construct ultra-stable hierarchically porous metal−organic frameworks (HP-MOFs) with tunable pore size distribution. Linker instability, usually an undesirable trait of MOFs, was exploited to create mesopores

  10. Recent progress in the direct synthesis of hierarchical zeolites: synthetic strategies and characterization methods

    KAUST Repository

    Liu, Zhaohui; Hua, Yingjie; Wang, Jianjian; Dong, Xinglong; Tian, Qiwei; Han, Yu

    2017-01-01

    Hierarchically structured zeolites combine the merits of microporous zeolites and mesoporous materials to offer enhanced molecular diffusion and mass transfer without compromising the inherent catalytic activities and selectivity of zeolites

  11. Similarity maps and hierarchical clustering for annotating FT-IR spectral images.

    Science.gov (United States)

    Zhong, Qiaoyong; Yang, Chen; Großerüschkamp, Frederik; Kallenbach-Thieltges, Angela; Serocka, Peter; Gerwert, Klaus; Mosig, Axel

    2013-11-20

    Unsupervised segmentation of multi-spectral images plays an important role in annotating infrared microscopic images and is an essential step in label-free spectral histopathology. In this context, diverse clustering approaches have been utilized and evaluated in order to achieve segmentations of Fourier Transform Infrared (FT-IR) microscopic images that agree with histopathological characterization. We introduce so-called interactive similarity maps as an alternative annotation strategy for annotating infrared microscopic images. We demonstrate that segmentations obtained from interactive similarity maps lead to similarly accurate segmentations as segmentations obtained from conventionally used hierarchical clustering approaches. In order to perform this comparison on quantitative grounds, we provide a scheme that allows to identify non-horizontal cuts in dendrograms. This yields a validation scheme for hierarchical clustering approaches commonly used in infrared microscopy. We demonstrate that interactive similarity maps may identify more accurate segmentations than hierarchical clustering based approaches, and thus are a viable and due to their interactive nature attractive alternative to hierarchical clustering. Our validation scheme furthermore shows that performance of hierarchical two-means is comparable to the traditionally used Ward's clustering. As the former is much more efficient in time and memory, our results suggest another less resource demanding alternative for annotating large spectral images.

  12. Zoneamento bioclimático da ovinocultura no Estado do Paraná

    Directory of Open Access Journals (Sweden)

    Barbosa Orlando Rus

    2001-01-01

    Full Text Available Utilizaram-se 45 fêmeas ovinas adultas (15 Hampshire Down [HD], 15 Texel [TE] e 15 Ile de France [IF], para propor um zoneamento bioclimático da ovinocultura no Estado do Paraná. Mediram-se a temperatura retal (Tr, da epiderme (Te, do interior do velo (Tiv e da superfície do velo (Tsv; a frequência respiratória (Fr; a temperatura do ar (Ta, pressão de vapor (e, velocidade do vento (v e carga térmica radiante (CTR. O Índice de Conforto Térmico utilizado foi ICT= 0,6678Ta + 0,4969e + 0,5444Tg + 0,1038v. A regressão do ICT sobre Tr mostrou efeito quadrático para as três raças. Para ICT=24,3, 27,3 e 20,6, os valores de Tr foram respectivamente: 39,10ºC para a raça HD, 39,05ºC para TE e 39,09ºC para IF, atingindo 40,40; 40,50; e 40,28ºC, respectivamente, para ICT=58. As três raças aumentaram sua Tr a partir de ICT=26, com a TE apresentando menor Tr até o valor ICT=46; neste ponto, as três raças foram semelhantes, tendo a TE apresentado maiores valores. Para ICT igual a 27,6; 29,7; e 27,0, os valores de Fr foram, respectivamente, 89,63; 77,08; e 78,77 resp./min., para as raças HD, TE e IF. A raça TE apresentou menor Fr (77,08 resp./min., para ICT=29,7 e para ICT=48, valores semelhantes aos da IF (181,96 resp./min.; a partir deste índice, passou a ser maior que as demais raças, atingindo valores de 288,66 resp./min. no ICT=56, porém inferior à HD (289,01 resp./min.. Neste índice, a raça IF foi a que apresentou a menor Fr (275,72 resp./min.. Uma extensa faixa ao longo do litoral do Estado, entrando cerca de 200 km para o interior até os limites das cidades de Castro, Telêmaco Borba, Laranjeiras do Sul e Pato Branco, permite a criação das três raças, sem exigir grandes esforços de termorregulação.

  13. TiO2 nanowire-templated hierarchical nanowire network as water-repelling coating

    Science.gov (United States)

    Hang, Tian; Chen, Hui-Jiuan; Xiao, Shuai; Yang, Chengduan; Chen, Meiwan; Tao, Jun; Shieh, Han-ping; Yang, Bo-ru; Liu, Chuan; Xie, Xi

    2017-12-01

    Extraordinary water-repelling properties of superhydrophobic surfaces make them novel candidates for a great variety of potential applications. A general approach to achieve superhydrophobicity requires low-energy coating on the surface and roughness on nano- and micrometre scale. However, typical construction of superhydrophobic surfaces with micro-nano structure through top-down fabrication is restricted by sophisticated fabrication techniques and limited choices of substrate materials. Micro-nanoscale topographies templated by conventional microparticles through surface coating may produce large variations in roughness and uncontrollable defects, resulting in poorly controlled surface morphology and wettability. In this work, micro-nanoscale hierarchical nanowire network was fabricated to construct self-cleaning coating using one-dimensional TiO2 nanowires as microscale templates. Hierarchical structure with homogeneous morphology was achieved by branching ZnO nanowires on the TiO2 nanowire backbones through hydrothermal reaction. The hierarchical nanowire network displayed homogeneous micro/nano-topography, in contrast to hierarchical structure templated by traditional microparticles. This hierarchical nanowire network film exhibited high repellency to both water and cell culture medium after functionalization with fluorinated organic molecules. The hierarchical structure templated by TiO2 nanowire coating significantly increased the surface superhydrophobicity compared to vertical ZnO nanowires with nanotopography alone. Our results demonstrated a promising strategy of using nanowires as microscale templates for the rational design of hierarchical coatings with desired superhydrophobicity that can also be applied to various substrate materials.

  14. iHAT: interactive Hierarchical Aggregation Table for Genetic Association Data

    Directory of Open Access Journals (Sweden)

    Heinrich Julian

    2012-05-01

    Full Text Available Abstract In the search for single-nucleotide polymorphisms which influence the observable phenotype, genome wide association studies have become an important technique for the identification of associations between genotype and phenotype of a diverse set of sequence-based data. We present a methodology for the visual assessment of single-nucleotide polymorphisms using interactive hierarchical aggregation techniques combined with methods known from traditional sequence browsers and cluster heatmaps. Our tool, the interactive Hierarchical Aggregation Table (iHAT, facilitates the visualization of multiple sequence alignments, associated metadata, and hierarchical clusterings. Different color maps and aggregation strategies as well as filtering options support the user in finding correlations between sequences and metadata. Similar to other visualizations such as parallel coordinates or heatmaps, iHAT relies on the human pattern-recognition ability for spotting patterns that might indicate correlation or anticorrelation. We demonstrate iHAT using artificial and real-world datasets for DNA and protein association studies as well as expression Quantitative Trait Locus data.

  15. Hierarchical Network Design

    DEFF Research Database (Denmark)

    Thomadsen, Tommy

    2005-01-01

    Communication networks are immensely important today, since both companies and individuals use numerous services that rely on them. This thesis considers the design of hierarchical (communication) networks. Hierarchical networks consist of layers of networks and are well-suited for coping...... with changing and increasing demands. Two-layer networks consist of one backbone network, which interconnects cluster networks. The clusters consist of nodes and links, which connect the nodes. One node in each cluster is a hub node, and the backbone interconnects the hub nodes of each cluster and thus...... the clusters. The design of hierarchical networks involves clustering of nodes, hub selection, and network design, i.e. selection of links and routing of ows. Hierarchical networks have been in use for decades, but integrated design of these networks has only been considered for very special types of networks...

  16. Strategies of Legitimacy Through Social Media: The Networked Strategy

    DEFF Research Database (Denmark)

    Castelló, Itziar; Etter, Michael; Nielsen, Finn Årup

    2016-01-01

    the concept of a networked legitimacy strategy. With this strategy, legitimacy is gained through participation in non-hierarchical open platforms and the co-construction of agendas. We explore the organizational transition needed to yield this new legitimacy approach. We argue that, in this context......How can corporations develop legitimacy when coping with stakeholders who have multiple, often conflicting sustainable development (SD) agendas? We address this question by conducting an in-depth longitudinal case study of a corporation's stakeholder engagement in social media and propose......, legitimacy gains may increase when firms are able to reduce the control over the engagements and relate non-hierarchically with their publics. We contribute to the extant literature on political corporate social responsibility and legitimacy by providing an understanding of a new context for engagement...

  17. Interference mitigation for broadcast in hierarchical cell structure networks: Transmission strategy and area spectral efficiency

    KAUST Repository

    Yang, Yuli

    2014-10-01

    In this paper, a hierarchical cell structure (HCS) is considered, where an access point (AP) broadcasts to local nodes (LNs) over orthogonal frequency subbands within a local cell located in a macrocell. Since the local cell shares the spectrum licensed to the macrocell, a given LN is interfered with by the macrocell user (MU)\\'s transmissions over the same subband. To improve the performance of the AP\\'s broadcast service, a novel transmission strategy is proposed to mitigate the interference from the MU to the LN while achieving diversity gain. For the purpose of performance evaluation, the ergodic capacity of the proposed scheme is quantified, and the corresponding closed-form expression is obtained. By comparing with the traditional transmission scheme, which suffers from MU\\'s interference, illustrative numerical results substantiate that the proposed scheme achieves better performance than the traditional scheme as the MU-LN mean channel power gain is larger than half of the AP-LN mean channel power gain. Subsequently, we develop an optimized network design by maximizing the area spectral efficiency (ASE) of the AP\\'s broadcast in the local cell.

  18. Nonlinear robust hierarchical control for nonlinear uncertain systems

    Directory of Open Access Journals (Sweden)

    Leonessa Alexander

    1999-01-01

    Full Text Available A nonlinear robust control-system design framework predicated on a hierarchical switching controller architecture parameterized over a set of moving nominal system equilibria is developed. Specifically, using equilibria-dependent Lyapunov functions, a hierarchical nonlinear robust control strategy is developed that robustly stabilizes a given nonlinear system over a prescribed range of system uncertainty by robustly stabilizing a collection of nonlinear controlled uncertain subsystems. The robust switching nonlinear controller architecture is designed based on a generalized (lower semicontinuous Lyapunov function obtained by minimizing a potential function over a given switching set induced by the parameterized nominal system equilibria. The proposed framework robustly stabilizes a compact positively invariant set of a given nonlinear uncertain dynamical system with structured parametric uncertainty. Finally, the efficacy of the proposed approach is demonstrated on a jet engine propulsion control problem with uncertain pressure-flow map data.

  19. Energy-efficient hierarchical processing in the network of wireless intelligent sensors (WISE)

    Science.gov (United States)

    Raskovic, Dejan

    Sensor network nodes have benefited from technological advances in the field of wireless communication, processing, and power sources. However, the processing power of microcontrollers is often not sufficient to perform sophisticated processing, while the power requirements of digital signal processing boards or handheld computers are usually too demanding for prolonged system use. We are matching the intrinsic hierarchical nature of many digital signal-processing applications with the natural hierarchy in distributed wireless networks, and building the hierarchical system of wireless intelligent sensors. Our goal is to build a system that will exploit the hierarchical organization to optimize the power consumption and extend battery life for the given time and memory constraints, while providing real-time processing of sensor signals. In addition, we are designing our system to be able to adapt to the current state of the environment, by dynamically changing the algorithm through procedure replacement. This dissertation presents the analysis of hierarchical environment and methods for energy profiling used to evaluate different system design strategies, and to optimize time-effective and energy-efficient processing.

  20. Ferritic Alloys with Extreme Creep Resistance via Coherent Hierarchical Precipitates.

    Science.gov (United States)

    Song, Gian; Sun, Zhiqian; Li, Lin; Xu, Xiandong; Rawlings, Michael; Liebscher, Christian H; Clausen, Bjørn; Poplawsky, Jonathan; Leonard, Donovan N; Huang, Shenyan; Teng, Zhenke; Liu, Chain T; Asta, Mark D; Gao, Yanfei; Dunand, David C; Ghosh, Gautam; Chen, Mingwei; Fine, Morris E; Liaw, Peter K

    2015-11-09

    There have been numerous efforts to develop creep-resistant materials strengthened by incoherent particles at high temperatures and stresses in response to future energy needs for steam turbines in thermal-power plants. However, the microstructural instability of the incoherent-particle-strengthened ferritic steels limits their application to temperatures below 900 K. Here, we report a novel ferritic alloy with the excellent creep resistance enhanced by coherent hierarchical precipitates, using the integrated experimental (transmission-electron microscopy/scanning-transmission-electron microscopy, in-situ neutron diffraction, and atom-probe tomography) and theoretical (crystal-plasticity finite-element modeling) approaches. This alloy is strengthened by nano-scaled L21-Ni2TiAl (Heusler phase)-based precipitates, which themselves contain coherent nano-scaled B2 zones. These coherent hierarchical precipitates are uniformly distributed within the Fe matrix. Our hierarchical structure material exhibits the superior creep resistance at 973 K in terms of the minimal creep rate, which is four orders of magnitude lower than that of conventional ferritic steels. These results provide a new alloy-design strategy using the novel concept of hierarchical precipitates and the fundamental science for developing creep-resistant ferritic alloys. The present research will broaden the applications of ferritic alloys to higher temperatures.

  1. Automatic thoracic anatomy segmentation on CT images using hierarchical fuzzy models and registration

    Science.gov (United States)

    Sun, Kaioqiong; Udupa, Jayaram K.; Odhner, Dewey; Tong, Yubing; Torigian, Drew A.

    2014-03-01

    This paper proposes a thoracic anatomy segmentation method based on hierarchical recognition and delineation guided by a built fuzzy model. Labeled binary samples for each organ are registered and aligned into a 3D fuzzy set representing the fuzzy shape model for the organ. The gray intensity distributions of the corresponding regions of the organ in the original image are recorded in the model. The hierarchical relation and mean location relation between different organs are also captured in the model. Following the hierarchical structure and location relation, the fuzzy shape model of different organs is registered to the given target image to achieve object recognition. A fuzzy connected delineation method is then used to obtain the final segmentation result of organs with seed points provided by recognition. The hierarchical structure and location relation integrated in the model provide the initial parameters for registration and make the recognition efficient and robust. The 3D fuzzy model combined with hierarchical affine registration ensures that accurate recognition can be obtained for both non-sparse and sparse organs. The results on real images are presented and shown to be better than a recently reported fuzzy model-based anatomy recognition strategy.

  2. Hierarchical spatial point process analysis for a plant community with high biodiversity

    DEFF Research Database (Denmark)

    Illian, Janine B.; Møller, Jesper; Waagepetersen, Rasmus

    2009-01-01

    A complex multivariate spatial point pattern of a plant community with high biodiversity is modelled using a hierarchical multivariate point process model. In the model, interactions between plants with different post-fire regeneration strategies are of key interest. We consider initially a maxim...

  3. Detecting Hierarchical Structure in Networks

    DEFF Research Database (Denmark)

    Herlau, Tue; Mørup, Morten; Schmidt, Mikkel Nørgaard

    2012-01-01

    Many real-world networks exhibit hierarchical organization. Previous models of hierarchies within relational data has focused on binary trees; however, for many networks it is unknown whether there is hierarchical structure, and if there is, a binary tree might not account well for it. We propose...... a generative Bayesian model that is able to infer whether hierarchies are present or not from a hypothesis space encompassing all types of hierarchical tree structures. For efficient inference we propose a collapsed Gibbs sampling procedure that jointly infers a partition and its hierarchical structure....... On synthetic and real data we demonstrate that our model can detect hierarchical structure leading to better link-prediction than competing models. Our model can be used to detect if a network exhibits hierarchical structure, thereby leading to a better comprehension and statistical account the network....

  4. Functional annotation of hierarchical modularity.

    Directory of Open Access Journals (Sweden)

    Kanchana Padmanabhan

    Full Text Available In biological networks of molecular interactions in a cell, network motifs that are biologically relevant are also functionally coherent, or form functional modules. These functionally coherent modules combine in a hierarchical manner into larger, less cohesive subsystems, thus revealing one of the essential design principles of system-level cellular organization and function-hierarchical modularity. Arguably, hierarchical modularity has not been explicitly taken into consideration by most, if not all, functional annotation systems. As a result, the existing methods would often fail to assign a statistically significant functional coherence score to biologically relevant molecular machines. We developed a methodology for hierarchical functional annotation. Given the hierarchical taxonomy of functional concepts (e.g., Gene Ontology and the association of individual genes or proteins with these concepts (e.g., GO terms, our method will assign a Hierarchical Modularity Score (HMS to each node in the hierarchy of functional modules; the HMS score and its p-value measure functional coherence of each module in the hierarchy. While existing methods annotate each module with a set of "enriched" functional terms in a bag of genes, our complementary method provides the hierarchical functional annotation of the modules and their hierarchically organized components. A hierarchical organization of functional modules often comes as a bi-product of cluster analysis of gene expression data or protein interaction data. Otherwise, our method will automatically build such a hierarchy by directly incorporating the functional taxonomy information into the hierarchy search process and by allowing multi-functional genes to be part of more than one component in the hierarchy. In addition, its underlying HMS scoring metric ensures that functional specificity of the terms across different levels of the hierarchical taxonomy is properly treated. We have evaluated our

  5. A note on hierarchical hubbing for a generalization of the VPN problem

    NARCIS (Netherlands)

    N.K. Olver (Neil)

    2016-01-01

    textabstractRobust network design refers to a class of optimization problems that occur when designing networks to efficiently handle variable demands. In this context, Fréchette et al. (2013) recently explored hierarchical hubbing: a routing strategy involving a multiplicity of "hubs" connected to

  6. A note on hierarchical hubbing for a generalization of the VPN problem

    NARCIS (Netherlands)

    Olver, Neil

    2016-01-01

    Robust network design refers to a class of optimization problems that occur when designing networks to efficiently handle variable demands. In this context, Fréchette et al. (2013) recently explored hierarchical hubbing: a routing strategy involving a multiplicity of "hubs" connected to terminals

  7. Catalysis with hierarchical zeolites

    DEFF Research Database (Denmark)

    Holm, Martin Spangsberg; Taarning, Esben; Egeblad, Kresten

    2011-01-01

    Hierarchical (or mesoporous) zeolites have attracted significant attention during the first decade of the 21st century, and so far this interest continues to increase. There have already been several reviews giving detailed accounts of the developments emphasizing different aspects of this research...... topic. Until now, the main reason for developing hierarchical zeolites has been to achieve heterogeneous catalysts with improved performance but this particular facet has not yet been reviewed in detail. Thus, the present paper summaries and categorizes the catalytic studies utilizing hierarchical...... zeolites that have been reported hitherto. Prototypical examples from some of the different categories of catalytic reactions that have been studied using hierarchical zeolite catalysts are highlighted. This clearly illustrates the different ways that improved performance can be achieved with this family...

  8. Parallel hierarchical radiosity rendering

    Energy Technology Data Exchange (ETDEWEB)

    Carter, Michael [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    In this dissertation, the step-by-step development of a scalable parallel hierarchical radiosity renderer is documented. First, a new look is taken at the traditional radiosity equation, and a new form is presented in which the matrix of linear system coefficients is transformed into a symmetric matrix, thereby simplifying the problem and enabling a new solution technique to be applied. Next, the state-of-the-art hierarchical radiosity methods are examined for their suitability to parallel implementation, and scalability. Significant enhancements are also discovered which both improve their theoretical foundations and improve the images they generate. The resultant hierarchical radiosity algorithm is then examined for sources of parallelism, and for an architectural mapping. Several architectural mappings are discussed. A few key algorithmic changes are suggested during the process of making the algorithm parallel. Next, the performance, efficiency, and scalability of the algorithm are analyzed. The dissertation closes with a discussion of several ideas which have the potential to further enhance the hierarchical radiosity method, or provide an entirely new forum for the application of hierarchical methods.

  9. Visual hierarchical processing and lateralization of cognitive functions through domestic chicks' eyes.

    Directory of Open Access Journals (Sweden)

    Cinzia Chiandetti

    Full Text Available Hierarchical stimuli have proven effective for investigating principles of visual organization in humans. A large body of evidence suggests that the analysis of the global forms precedes the analysis of the local forms in our species. Studies on lateralization also indicate that analytic and holistic encoding strategies are separated between the two hemispheres of the brain. This raises the question of whether precedence effects may reflect the activation of lateralized functions within the brain. Non-human animals have perceptual organization and functional lateralization that are comparable to that of humans. Here we trained the domestic chick in a concurrent discrimination task involving hierarchical stimuli. Then, we evaluated the animals for analytic and holistic encoding strategies in a series of transformational tests by relying on a monocular occlusion technique. A local precedence emerged in both the left and the right hemisphere, adding further evidence in favour of analytic processing in non-human animals.

  10. Micromechanics of hierarchical materials

    DEFF Research Database (Denmark)

    Mishnaevsky, Leon, Jr.

    2012-01-01

    A short overview of micromechanical models of hierarchical materials (hybrid composites, biomaterials, fractal materials, etc.) is given. Several examples of the modeling of strength and damage in hierarchical materials are summarized, among them, 3D FE model of hybrid composites...... with nanoengineered matrix, fiber bundle model of UD composites with hierarchically clustered fibers and 3D multilevel model of wood considered as a gradient, cellular material with layered composite cell walls. The main areas of research in micromechanics of hierarchical materials are identified, among them......, the investigations of the effects of load redistribution between reinforcing elements at different scale levels, of the possibilities to control different material properties and to ensure synergy of strengthening effects at different scale levels and using the nanoreinforcement effects. The main future directions...

  11. Implementation of hierarchical control in DC microgrids

    DEFF Research Database (Denmark)

    Jin, Chi; Wang, Peng; Xiao, Jianfang

    2014-01-01

    of Technology, Singapore. The coordination control among multiple dc sources and energy storages is implemented using a novel hierarchical control technique. The bus voltage essentially acts as an indicator of supply-demand balance. A wireless control is implemented for the reliable operation of the grid....... A reasonable compromise between the maximum power harvest and effective battery management is further enhanced using the coordination control based on a central energy management system. The feasibility and effectiveness of the proposed control strategies have been tested by a dc microgrid in WERL....

  12. Applying macromolecular crowding to 3D bioprinting: fabrication of 3D hierarchical porous collagen-based hydrogel constructs.

    Science.gov (United States)

    Ng, Wei Long; Goh, Min Hao; Yeong, Wai Yee; Naing, May Win

    2018-02-27

    Native tissues and/or organs possess complex hierarchical porous structures that confer highly-specific cellular functions. Despite advances in fabrication processes, it is still very challenging to emulate the hierarchical porous collagen architecture found in most native tissues. Hence, the ability to recreate such hierarchical porous structures would result in biomimetic tissue-engineered constructs. Here, a single-step drop-on-demand (DOD) bioprinting strategy is proposed to fabricate hierarchical porous collagen-based hydrogels. Printable macromolecule-based bio-inks (polyvinylpyrrolidone, PVP) have been developed and printed in a DOD manner to manipulate the porosity within the multi-layered collagen-based hydrogels by altering the collagen fibrillogenesis process. The experimental results have indicated that hierarchical porous collagen structures could be achieved by controlling the number of macromolecule-based bio-ink droplets printed on each printed collagen layer. This facile single-step bioprinting process could be useful for the structural design of collagen-based hydrogels for various tissue engineering applications.

  13. Interference mitigation for broadcast in hierarchical cell structure networks: Transmission strategy and area spectral efficiency

    KAUST Repository

    Yang, Yuli; Salama, Khaled N.; Aï ssa, Sonia

    2014-01-01

    In this paper, a hierarchical cell structure (HCS) is considered, where an access point (AP) broadcasts to local nodes (LNs) over orthogonal frequency subbands within a local cell located in a macrocell. Since the local cell shares the spectrum

  14. How hierarchical is language use?

    Science.gov (United States)

    Frank, Stefan L.; Bod, Rens; Christiansen, Morten H.

    2012-01-01

    It is generally assumed that hierarchical phrase structure plays a central role in human language. However, considerations of simplicity and evolutionary continuity suggest that hierarchical structure should not be invoked too hastily. Indeed, recent neurophysiological, behavioural and computational studies show that sequential sentence structure has considerable explanatory power and that hierarchical processing is often not involved. In this paper, we review evidence from the recent literature supporting the hypothesis that sequential structure may be fundamental to the comprehension, production and acquisition of human language. Moreover, we provide a preliminary sketch outlining a non-hierarchical model of language use and discuss its implications and testable predictions. If linguistic phenomena can be explained by sequential rather than hierarchical structure, this will have considerable impact in a wide range of fields, such as linguistics, ethology, cognitive neuroscience, psychology and computer science. PMID:22977157

  15. Hierarchical macroscopic fibrillar adhesives: in situ study of buckling and adhesion mechanisms on wavy substrates.

    Science.gov (United States)

    Bauer, Christina T; Kroner, Elmar; Fleck, Norman A; Arzt, Eduard

    2015-10-23

    Nature uses hierarchical fibrillar structures to mediate temporary adhesion to arbitrary substrates. Such structures provide high compliance such that the flat fibril tips can be better positioned with respect to asperities of a wavy rough substrate. We investigated the buckling and adhesion of hierarchically structured adhesives in contact with flat smooth, flat rough and wavy rough substrates. A macroscopic model for the structural adhesive was fabricated by molding polydimethylsiloxane into pillars of diameter in the range of 0.3-4.8 mm, with up to three different hierarchy levels. Both flat-ended and mushroom-shaped hierarchical samples buckled at preloads one quarter that of the single level structures. We explain this behavior by a change in the buckling mode; buckling leads to a loss of contact and diminishes adhesion. Our results indicate that hierarchical structures can have a strong influence on the degree of adhesion on both flat and wavy substrates. Strategies are discussed that achieve highly compliant substrates which adhere to rough substrates.

  16. Hierarchical architecture of active knits

    International Nuclear Information System (INIS)

    Abel, Julianna; Luntz, Jonathan; Brei, Diann

    2013-01-01

    Nature eloquently utilizes hierarchical structures to form the world around us. Applying the hierarchical architecture paradigm to smart materials can provide a basis for a new genre of actuators which produce complex actuation motions. One promising example of cellular architecture—active knits—provides complex three-dimensional distributed actuation motions with expanded operational performance through a hierarchically organized structure. The hierarchical structure arranges a single fiber of active material, such as shape memory alloys (SMAs), into a cellular network of interlacing adjacent loops according to a knitting grid. This paper defines a four-level hierarchical classification of knit structures: the basic knit loop, knit patterns, grid patterns, and restructured grids. Each level of the hierarchy provides increased architectural complexity, resulting in expanded kinematic actuation motions of active knits. The range of kinematic actuation motions are displayed through experimental examples of different SMA active knits. The results from this paper illustrate and classify the ways in which each level of the hierarchical knit architecture leverages the performance of the base smart material to generate unique actuation motions, providing necessary insight to best exploit this new actuation paradigm. (paper)

  17. Nested and Hierarchical Archimax copulas

    KAUST Repository

    Hofert, Marius

    2017-07-03

    The class of Archimax copulas is generalized to nested and hierarchical Archimax copulas in several ways. First, nested extreme-value copulas or nested stable tail dependence functions are introduced to construct nested Archimax copulas based on a single frailty variable. Second, a hierarchical construction of d-norm generators is presented to construct hierarchical stable tail dependence functions and thus hierarchical extreme-value copulas. Moreover, one can, by itself or additionally, introduce nested frailties to extend Archimax copulas to nested Archimax copulas in a similar way as nested Archimedean copulas extend Archimedean copulas. Further results include a general formula for the density of Archimax copulas.

  18. Nested and Hierarchical Archimax copulas

    KAUST Repository

    Hofert, Marius; Huser, Raphaë l; Prasad, Avinash

    2017-01-01

    The class of Archimax copulas is generalized to nested and hierarchical Archimax copulas in several ways. First, nested extreme-value copulas or nested stable tail dependence functions are introduced to construct nested Archimax copulas based on a single frailty variable. Second, a hierarchical construction of d-norm generators is presented to construct hierarchical stable tail dependence functions and thus hierarchical extreme-value copulas. Moreover, one can, by itself or additionally, introduce nested frailties to extend Archimax copulas to nested Archimax copulas in a similar way as nested Archimedean copulas extend Archimedean copulas. Further results include a general formula for the density of Archimax copulas.

  19. Cenogramas, análisis bioclimático y muestreo en faunas de mamíferos: implicaciones para la aplicación de métodos de análisis paleoecológico

    Directory of Open Access Journals (Sweden)

    Hernández Fernández, M.

    2006-12-01

    Full Text Available In this work we analyzed the problems derived from the potential species loss associated to the taphonomic processes occurring in fossil sites. We seek to resolve the possible utility of cenograms and bioclimatic analysis as methodologies applicable in Paleoecology. Supposedly, if species are deleted in a community, significant changes in its structure might appear, which would make these paleoecological techniques dysfunctional. The analysis has been carried out with the data of two modern mammalian communities, Barrow (Alaska and Jaipur (India, on which we have deleted species randomly. Our results have allowed us to conclude that these methodologies are useful in Paleoecology, since they are functional with a satisfactory level of confidence, as long as the species loss is not excessively elevated (for communities with 20-40% of the original species.En este trabajo hemos analizado la problemática derivada de la posible pérdida de especies asociada a los procesos tafonómicos que se dan en los yacimientos de fósiles, para determinar la posible utilidad de los cenogramas y el análisis bioclimático como metodologías aplicables en Paleoecología. Podría suponerse que si eliminamos especies en una comunidad se podrían producir cambios significativos en su estructura que convertirían en no funcionales a estas metodologías. El análisis se ha llevado a cabo con los datos de dos comunidades de mamíferos actuales, Barrow (Alaska y Jaipur (India, de las que hemos eliminado progresivamente especies de forma aleatoria. Los resultados obtenidos nos han permitido concluir que tanto los cenogramas como el análisis bioclimático son útiles en Paleoecología, ya que son funcionales con un nivel de confianza adecuado, siempre y cuando la pérdida de especies no sea excesivamente elevada (en comunidades con un 20-40% de las especies originales.

  20. A new anisotropic mesh adaptation method based upon hierarchical a posteriori error estimates

    Science.gov (United States)

    Huang, Weizhang; Kamenski, Lennard; Lang, Jens

    2010-03-01

    A new anisotropic mesh adaptation strategy for finite element solution of elliptic differential equations is presented. It generates anisotropic adaptive meshes as quasi-uniform ones in some metric space, with the metric tensor being computed based on hierarchical a posteriori error estimates. A global hierarchical error estimate is employed in this study to obtain reliable directional information of the solution. Instead of solving the global error problem exactly, which is costly in general, we solve it iteratively using the symmetric Gauß-Seidel method. Numerical results show that a few GS iterations are sufficient for obtaining a reasonably good approximation to the error for use in anisotropic mesh adaptation. The new method is compared with several strategies using local error estimators or recovered Hessians. Numerical results are presented for a selection of test examples and a mathematical model for heat conduction in a thermal battery with large orthotropic jumps in the material coefficients.

  1. A Performance-Prediction Model for PIC Applications on Clusters of Symmetric MultiProcessors: Validation with Hierarchical HPF+OpenMP Implementation

    Directory of Open Access Journals (Sweden)

    Sergio Briguglio

    2003-01-01

    Full Text Available A performance-prediction model is presented, which describes different hierarchical workload decomposition strategies for particle in cell (PIC codes on Clusters of Symmetric MultiProcessors. The devised workload decomposition is hierarchically structured: a higher-level decomposition among the computational nodes, and a lower-level one among the processors of each computational node. Several decomposition strategies are evaluated by means of the prediction model, with respect to the memory occupancy, the parallelization efficiency and the required programming effort. Such strategies have been implemented by integrating the high-level languages High Performance Fortran (at the inter-node stage and OpenMP (at the intra-node one. The details of these implementations are presented, and the experimental values of parallelization efficiency are compared with the predicted results.

  2. Hierarchical Co(OH)_2 nanostructures/glassy carbon electrode derived from Co(BTC) metal–organic frameworks for glucose sensing

    International Nuclear Information System (INIS)

    He, Juan; Lu, Xingping; Yu, Jie; Wang, Li; Song, Yonghai

    2016-01-01

    A novel Co(OH)_2/glassy carbon electrode (GCE) has been fabricated via metal–organic framework (MOF)-directed method. In the strategy, the Co(BTC, 1,3,5-benzentricarboxylic acid) MOFs/GCE was firstly prepared by alternately immersing GCE in Co"2"+ and BTC solution based on a layer-by-layer method. And then, the Co(OH)_2 with hierarchical flake nanostructure/GCE was constructed by immersing Co(BTC) MOFs/GCE into 0.1 M NaOH solution at room temperature. Such strategy improves the distribution of hierarchical Co(OH)_2 nanostructures on electrode surface greatly, enhances the stability of nanomaterials on the electrode surface, and increases the use efficiency of the Co(OH)_2 nanostructures. Scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, and Raman spectra were used to characterize the Co(BTC) MOFs/GCE and Co(OH)_2/GCE. Based on the hierarchical Co(OH)_2 nanostructures/GCE, a novel and sensitive nonenzymatic glucose sensor was developed. The good performance of the resulted sensor toward the detection of glucose was ascribed to hierarchical flake nanostructures, good mechanical stability, excellent distribution, and large specific surface area of Co(OH)_2 nanostructures. The proposed preparation method is simple, efficient, and cheap .Graphical Abstract.

  3. Constructing storyboards based on hierarchical clustering analysis

    Science.gov (United States)

    Hasebe, Satoshi; Sami, Mustafa M.; Muramatsu, Shogo; Kikuchi, Hisakazu

    2005-07-01

    There are growing needs for quick preview of video contents for the purpose of improving accessibility of video archives as well as reducing network traffics. In this paper, a storyboard that contains a user-specified number of keyframes is produced from a given video sequence. It is based on hierarchical cluster analysis of feature vectors that are derived from wavelet coefficients of video frames. Consistent use of extracted feature vectors is the key to avoid a repetition of computationally-intensive parsing of the same video sequence. Experimental results suggest that a significant reduction in computational time is gained by this strategy.

  4. Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal-Organic Frameworks.

    Science.gov (United States)

    Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang; Tan, Kui; Li, Jia-Luo; Kirchon, Angelo; Liu, Ling-Mei; Zhang, Peng; Han, Yu; Chabal, Yves J; Zhou, Hong-Cai

    2018-02-14

    Sufficient pore size, appropriate stability, and hierarchical porosity are three prerequisites for open frameworks designed for drug delivery, enzyme immobilization, and catalysis involving large molecules. Herein, we report a powerful and general strategy, linker thermolysis, to construct ultrastable hierarchically porous metal-organic frameworks (HP-MOFs) with tunable pore size distribution. Linker instability, usually an undesirable trait of MOFs, was exploited to create mesopores by generating crystal defects throughout a microporous MOF crystal via thermolysis. The crystallinity and stability of HP-MOFs remain after thermolabile linkers are selectively removed from multivariate metal-organic frameworks (MTV-MOFs) through a decarboxylation process. A domain-based linker spatial distribution was found to be critical for creating hierarchical pores inside MTV-MOFs. Furthermore, linker thermolysis promotes the formation of ultrasmall metal oxide nanoparticles immobilized in an open framework that exhibits high catalytic activity for Lewis acid-catalyzed reactions. Most importantly, this work provides fresh insights into the connection between linker apportionment and vacancy distribution, which may shed light on probing the disordered linker apportionment in multivariate systems, a long-standing challenge in the study of MTV-MOFs.

  5. Hierarchical modeling and inference in ecology: The analysis of data from populations, metapopulations and communities

    Science.gov (United States)

    Royle, J. Andrew; Dorazio, Robert M.

    2008-01-01

    A guide to data collection, modeling and inference strategies for biological survey data using Bayesian and classical statistical methods. This book describes a general and flexible framework for modeling and inference in ecological systems based on hierarchical models, with a strict focus on the use of probability models and parametric inference. Hierarchical models represent a paradigm shift in the application of statistics to ecological inference problems because they combine explicit models of ecological system structure or dynamics with models of how ecological systems are observed. The principles of hierarchical modeling are developed and applied to problems in population, metapopulation, community, and metacommunity systems. The book provides the first synthetic treatment of many recent methodological advances in ecological modeling and unifies disparate methods and procedures. The authors apply principles of hierarchical modeling to ecological problems, including * occurrence or occupancy models for estimating species distribution * abundance models based on many sampling protocols, including distance sampling * capture-recapture models with individual effects * spatial capture-recapture models based on camera trapping and related methods * population and metapopulation dynamic models * models of biodiversity, community structure and dynamics.

  6. Hierarchical CuO hollow microspheres: Controlled synthesis for enhanced lithium storage performance

    International Nuclear Information System (INIS)

    Guan Xiangfeng; Li Liping; Li Guangshe; Fu Zhengwei; Zheng Jing; Yan Tingjiang

    2011-01-01

    Graphical abstract: Hierarchical CuO microspheres with hollow interiors were formed through self-wrapping of a single layer of radically oriented CuO nanorods, and these microspheres showed excellent cycle performance and enhanced lithium storage capacity. Display Omitted Research highlights: → Hierarchical CuO hollow microspheres were prepared by a hydrothermal method. → The CuO hollow microspheres were assembled from radically oriented nanorods. → The growth mechanism was proposed to proceed via self-assembly and Ostwald's ripening. → The microspheres showed good cycle performance and enhanced lithium storage capacity. → Hierarchical microstructures with hollow interiors promote electrochemical property. - Abstract: In this work, hierarchical CuO hollow microspheres were hydrothermally prepared without use of any surfactants or templates. By controlling the formation reaction conditions and monitoring the relevant reaction processes using time-dependent experiments, it is demonstrated that hierarchical CuO microspheres with hollow interiors were formed through self-wrapping of a single layer of radically oriented CuO nanorods, and that hierarchical spheres could be tuned to show different morphologies and microstructures. As a consequence, the formation mechanism was proposed to proceed via a combined process of self-assembly and Ostwald's ripening. Further, these hollow microspheres were initiated as the anode material in lithium ion batteries, which showed excellent cycle performance and enhanced lithium storage capacity, most likely because of the synergetic effect of small diffusion lengths in building blocks of nanorods and proper void space that buffers the volume expansion. The strategy reported in this work is reproducible, which may help to significantly improve the electrochemical performance of transition metal oxide-based anode materials via designing the hollow structures necessary for developing lithium ion batteries and the relevant

  7. Efficient learning strategy of Chinese characters based on network approach.

    Directory of Open Access Journals (Sweden)

    Xiaoyong Yan

    Full Text Available We develop an efficient learning strategy of Chinese characters based on the network of the hierarchical structural relations between Chinese characters. A more efficient strategy is that of learning the same number of useful Chinese characters in less effort or time. We construct a node-weighted network of Chinese characters, where character usage frequencies are used as node weights. Using this hierarchical node-weighted network, we propose a new learning method, the distributed node weight (DNW strategy, which is based on a new measure of nodes' importance that considers both the weight of the nodes and its location in the network hierarchical structure. Chinese character learning strategies, particularly their learning order, are analyzed as dynamical processes over the network. We compare the efficiency of three theoretical learning methods and two commonly used methods from mainstream Chinese textbooks, one for Chinese elementary school students and the other for students learning Chinese as a second language. We find that the DNW method significantly outperforms the others, implying that the efficiency of current learning methods of major textbooks can be greatly improved.

  8. Statistical modelling of railway track geometry degradation using Hierarchical Bayesian models

    International Nuclear Information System (INIS)

    Andrade, A.R.; Teixeira, P.F.

    2015-01-01

    Railway maintenance planners require a predictive model that can assess the railway track geometry degradation. The present paper uses a Hierarchical Bayesian model as a tool to model the main two quality indicators related to railway track geometry degradation: the standard deviation of longitudinal level defects and the standard deviation of horizontal alignment defects. Hierarchical Bayesian Models (HBM) are flexible statistical models that allow specifying different spatially correlated components between consecutive track sections, namely for the deterioration rates and the initial qualities parameters. HBM are developed for both quality indicators, conducting an extensive comparison between candidate models and a sensitivity analysis on prior distributions. HBM is applied to provide an overall assessment of the degradation of railway track geometry, for the main Portuguese railway line Lisbon–Oporto. - Highlights: • Rail track geometry degradation is analysed using Hierarchical Bayesian models. • A Gibbs sampling strategy is put forward to estimate the HBM. • Model comparison and sensitivity analysis find the most suitable model. • We applied the most suitable model to all the segments of the main Portuguese line. • Tackling spatial correlations using CAR structures lead to a better model fit

  9. Hierarchical Co-based Porous Layered Double Hydroxide Arrays Derived via Alkali Etching for High-performance Supercapacitors

    Science.gov (United States)

    Abushrenta, Nasser; Wu, Xiaochao; Wang, Junnan; Liu, Junfeng; Sun, Xiaoming

    2015-08-01

    Hierarchical nanoarchitecture and porous structure can both provide advantages for improving the electrochemical performance in energy storage electrodes. Here we report a novel strategy to synthesize new electrode materials, hierarchical Co-based porous layered double hydroxide (PLDH) arrays derived via alkali etching from Co(OH)2@CoAl LDH nanoarrays. This structure not only has the benefits of hierarchical nanoarrays including short ion diffusion path and good charge transport, but also possesses a large contact surface area owing to its porous structure which lead to a high specific capacitance (23.75 F cm-2 or 1734 F g-1 at 5 mA cm-2) and excellent cycling performance (over 85% after 5000 cycles). The enhanced electrode material is a promising candidate for supercapacitors in future application.

  10. Neutrosophic Hierarchical Clustering Algoritms

    Directory of Open Access Journals (Sweden)

    Rıdvan Şahin

    2014-03-01

    Full Text Available Interval neutrosophic set (INS is a generalization of interval valued intuitionistic fuzzy set (IVIFS, whose the membership and non-membership values of elements consist of fuzzy range, while single valued neutrosophic set (SVNS is regarded as extension of intuitionistic fuzzy set (IFS. In this paper, we extend the hierarchical clustering techniques proposed for IFSs and IVIFSs to SVNSs and INSs respectively. Based on the traditional hierarchical clustering procedure, the single valued neutrosophic aggregation operator, and the basic distance measures between SVNSs, we define a single valued neutrosophic hierarchical clustering algorithm for clustering SVNSs. Then we extend the algorithm to classify an interval neutrosophic data. Finally, we present some numerical examples in order to show the effectiveness and availability of the developed clustering algorithms.

  11. The Hierarchical Perspective

    Directory of Open Access Journals (Sweden)

    Daniel Sofron

    2015-05-01

    Full Text Available This paper is focused on the hierarchical perspective, one of the methods for representing space that was used before the discovery of the Renaissance linear perspective. The hierarchical perspective has a more or less pronounced scientific character and its study offers us a clear image of the way the representatives of the cultures that developed it used to perceive the sensitive reality. This type of perspective is an original method of representing three-dimensional space on a flat surface, which characterises the art of Ancient Egypt and much of the art of the Middle Ages, being identified in the Eastern European Byzantine art, as well as in the Western European Pre-Romanesque and Romanesque art. At the same time, the hierarchical perspective is also present in naive painting and infantile drawing. Reminiscences of this method can be recognised also in the works of some precursors of the Italian Renaissance. The hierarchical perspective can be viewed as a subjective ranking criterion, according to which the elements are visually represented by taking into account their relevance within the image while perception is ignored. This paper aims to show how the main objective of the artists of those times was not to faithfully represent the objective reality, but rather to emphasize the essence of the world and its perennial aspects. This may represent a possible explanation for the refusal of perspective in the Egyptian, Romanesque and Byzantine painting, characterised by a marked two-dimensionality.

  12. Comparisons of Flow Patterns over a Hierarchical and a Non-hierarchical Surface in Relation to Biofouling Control

    Directory of Open Access Journals (Sweden)

    Bin Ahmad Fawzan Mohammed Ridha

    2018-01-01

    Full Text Available Biofouling can be defined as unwanted deposition and development of organisms on submerged surfaces. It is a major problem as it causes water contamination, infrastructures damage and increase in maintenance and operational cost especially in the shipping industry. There are a few methods that can prevent this problem. One of the most effective methods which is using chemicals particularly Tributyltin has been banned due to adverse effects on the environment. One of the non-toxic methods found to be effective is surface modification which involves altering the surface topography so that it becomes a low-fouling or a non-stick surface to biofouling organisms. Current literature suggested that non-hierarchical topographies has lower antifouling performance compared to hierarchical topographies. It is still unclear if the effects of the flow on these topographies could have aided in their antifouling properties. This research will use Computational Fluid Dynamics (CFD simulations to study the flow on these two topographies which also involves comparison study of the topographies used. According to the results obtained, it is shown that hierarchical topography has higher antifouling performance compared to non-hierarchical topography. This is because the fluid characteristics at the hierarchical topography is more favorable in controlling biofouling. In addition, hierarchical topography has higher wall shear stress distribution compared to non-hierarchical topography

  13. Regulatory switches for hierarchical use of carbon sources in E. coli

    Directory of Open Access Journals (Sweden)

    Ruth S. Perez-Alfaro

    2014-09-01

    Full Text Available In this work we study the preferential use of carbon sources in the bacterium Escherichia coli. To that end we engineered transcriptional fusions of the reporter gene gfpmut2, downstream of transcription-factor promoters, and analyzed their activity under several conditions. The chosen transcription factors are known to regulate catabolic operons associated to the consumption of alternative sugars. The obtained results indicate the following hierarchical order of sugar preference in this bacterium: glucose > arabinose > sorbitol > galactose. Further dynamical results allowed us to conjecture that this hierarchical behavior might be operated by at least the following three regulatory strategies: 1 the coordinated activation of the corresponding operons by the global regulator catabolic repressor protein (CRP, 2 their asymmetrical responses to specific and unspecific sugars and, 3 the architecture of the associated gene regulatory networks.

  14. MOF-5 decorated hierarchical ZnO nanorod arrays and its photoluminescence

    Science.gov (United States)

    Zhang, Yinmin; Lan, Ding; Wang, Yuren; Cao, He; Jiang, Heng

    2011-04-01

    The strategy to manipulate nanoscale materials into well-organized hierarchical architectures is very important to both material synthesis and nanodevice applications. Here, nanoscale MOF-5 crystallites were successfully fabricated onto ordered hierarchical ZnO arrays based on aqueous chemical synthesis and molecule self-assembly technology guided room temperature diffusion method, which has the advantages of energy saving and simple operation. The structures and morphologies of the samples were performed by X-ray powder diffraction and field emission scanning electronic microscopy. The MOF-5 crystallites have good quality and bind well to the hexagonal-patterned ZnO arrays. The photoluminescence spectrum shows that the emission of hybrid MOF-5-ZnO films displays a blue shift in green emission and intensity reduction in UV emission. This ordered hybrid semiconductor material is expected to exploit the great potentiality in sensors, micro/nanodevices, and screen displays.

  15. Adaptive hierarchical multi-agent organizations

    NARCIS (Netherlands)

    Ghijsen, M.; Jansweijer, W.N.H.; Wielinga, B.J.; Babuška, R.; Groen, F.C.A.

    2010-01-01

    In this chapter, we discuss the design of adaptive hierarchical organizations for multi-agent systems (MAS). Hierarchical organizations have a number of advantages such as their ability to handle complex problems and their scalability to large organizations. By introducing adaptivity in the

  16. Hierarchical video summarization

    Science.gov (United States)

    Ratakonda, Krishna; Sezan, M. Ibrahim; Crinon, Regis J.

    1998-12-01

    We address the problem of key-frame summarization of vide in the absence of any a priori information about its content. This is a common problem that is encountered in home videos. We propose a hierarchical key-frame summarization algorithm where a coarse-to-fine key-frame summary is generated. A hierarchical key-frame summary facilitates multi-level browsing where the user can quickly discover the content of the video by accessing its coarsest but most compact summary and then view a desired segment of the video with increasingly more detail. At the finest level, the summary is generated on the basis of color features of video frames, using an extension of a recently proposed key-frame extraction algorithm. The finest level key-frames are recursively clustered using a novel pairwise K-means clustering approach with temporal consecutiveness constraint. We also address summarization of MPEG-2 compressed video without fully decoding the bitstream. We also propose efficient mechanisms that facilitate decoding the video when the hierarchical summary is utilized in browsing and playback of video segments starting at selected key-frames.

  17. Two-dimensional hierarchical porous carbon composites derived from corn stalks for electrode materials with high performance

    International Nuclear Information System (INIS)

    Xu, Haitao; Zhang, Huijuan; Ouyang, Ya; Liu, Li; Wang, Yu

    2016-01-01

    Highlights: • Novel 2D porous carbon sheets from cornstalks are obtained for the first time. • The hierarchical porous carbon nansheets are gained by chemical activation. • The porous structure facilitates ion transfer and Li-ion absorption. • The strategy are applied to both cathode and anode electrode materials. • The porous nanocomposites exhibit excellent electrochemical performance. - Abstract: Herein, we propose a novel and green strategy to convert crop stalks waste into hierarchical porous carbon composites for electrode materials of lithium-ion batteries. In the method, the sustainable crop stalks, an abundant agricultural byproduct, is recycled and treated by a simple and clean chemical activation process. Afterwards, the obtained porous template is adopted for large-scale production of high-performance anode and cathode materials for lithium-ion batteries. Due to the large surface area, hierarchical porous structures and subsize of the functional particles, the electrode materials manifest excellent electrochemical performance. In particular, the prepared TiO 2 /C composite presents a reversible specific capacity of 203 mAh g −1 after 200 cycles. Our results demonstrate that the sheetlike composites show remarkable cycling stability, high specific capacity and excellent rate ability, and thus hold promise for commercializing the high-performance electrode materials as the advanced lithium-ion batteries.

  18. A Hierarchical Security Architecture for Cyber-Physical Systems

    Energy Technology Data Exchange (ETDEWEB)

    Quanyan Zhu; Tamer Basar

    2011-08-01

    Security of control systems is becoming a pivotal concern in critical national infrastructures such as the power grid and nuclear plants. In this paper, we adopt a hierarchical viewpoint to these security issues, addressing security concerns at each level and emphasizing a holistic cross-layer philosophy for developing security solutions. We propose a bottom-up framework that establishes a model from the physical and control levels to the supervisory level, incorporating concerns from network and communication levels. We show that the game-theoretical approach can yield cross-layer security strategy solutions to the cyber-physical systems.

  19. Hierarchic modeling of heat exchanger thermal hydraulics

    International Nuclear Information System (INIS)

    Horvat, A.; Koncar, B.

    2002-01-01

    Volume Averaging Technique (VAT) is employed in order to model the heat exchanger cross-flow as a porous media flow. As the averaging of the transport equations lead to a closure problem, separate relations are introduced to model interphase momentum and heat transfer between fluid flow and the solid structure. The hierarchic modeling is used to calculate the local drag coefficient C d as a function of Reynolds number Re h . For that purpose a separate model of REV is built and DNS of flow through REV is performed. The local values of heat transfer coefficient h are obtained from available literature. The geometry of the simulation domain and boundary conditions follow the geometry of the experimental test section used at U.C.L.A. The calculated temperature fields reveal that the geometry with denser pin-fins arrangement (HX1) heats fluid flow faster. The temperature field in the HX2 exhibits the formation of thermal boundary layer between pin-fins, which has a significant role in overall thermal performance of the heat exchanger. Although presented discrepancies of the whole-section drag coefficient C d are large, we believe that hierarchic modeling is an appropriate strategy for calculation of complex transport phenomena in heat exchanger geometries.(author)

  20. Hierarchical porous NiCo2O4 nanowires for high-rate supercapacitors.

    Science.gov (United States)

    Jiang, Hao; Ma, Jan; Li, Chunzhong

    2012-05-11

    We demonstrate a simple and scalable strategy for synthesizing hierarchical porous NiCo(2)O(4) nanowires which exhibit a high specific capacitance of 743 F g(-1) at 1 A g(-1) with excellent rate performance (78.6% capacity retention at 40 A g(-1)) and cycling stability (only 6.2% loss after 3000 cycles). This journal is © The Royal Society of Chemistry 2012

  1. Hierarchical nanostructures assembled from ultrathin Bi2WO6 nanoflakes and their visible-light induced photocatalytic property

    International Nuclear Information System (INIS)

    Wang, Xiong; Tian, Peng; Lin, Ying; Li, Li

    2015-01-01

    Graphical abstract: Hierarchical Bi 2 WO 6 nanostructures assembled from nanoflakes were successfully synthesized by a facile hydrothermal method. The excellent photocatalytic activity and recycling performance might be mainly ascribed to the unique hierarchical nanostructures and are expected to offer the nanostructures promising applications in the field of wastewater treatment. - Highlights: • Hierarchical Bi 2 WO 6 nanostructures assembled from nanoflakes were successfully synthesized by a facile hydrothermal method. • Visible-light-induced photocatalytic efficiency of the obtained nanoarchitectures was enhanced about 6 times. • A possible mechanism was proposed. - Abstract: With the aid of ethylene glycol and sodium dodecylbenzene sulfonate, the hierarchical Bi 2 WO 6 nanoarchitectures assembled from nanoflakes could be attained by a facile solvothermal method. The synthetic strategy is versatile and environmentally friendly and a plausible growth-assembly process was proposed for the formation of the hierarchical nanostructures. The visible-light-irradiated photocatalytic activity was estimated by the degradation of rhodamine B. Compared with the sample prepared by a solid-state reaction, the visible-light-induced photocatalytic efficiency of the nanostructures was enhanced about 6 times. The photocatalysis tests show that the nanostructures exhibit excellent photocatalytic activity and recycling performance, which were mainly ascribed to the unique hierarchical nanostructures and are expected to offer promising applications in the field of wastewater treatment

  2. Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal-Organic Frameworks

    KAUST Repository

    Feng, Liang

    2018-01-18

    Sufficient pore size, appropriate stability and hierarchical porosity are three prerequisites for open frameworks designed for drug delivery, enzyme immobilization and catalysis involving large molecules. Herein, we report a powerful and general strate-gy, linker thermolysis, to construct ultra-stable hierarchically porous metal−organic frameworks (HP-MOFs) with tunable pore size distribution. Linker instability, usually an undesirable trait of MOFs, was exploited to create mesopores by generating crystal defects throughout a microporous MOF crystal via thermolysis. The crystallinity and stability of HP-MOFs remain after thermolabile linkers are selectively removed from multivariate metal-organic frameworks (MTV-MOFs) through a decarboxyla-tion process. A domain-based linker spatial distribution was found to be critical for creating hierarchical pores inside MTV-MOFs. Furthermore, linker thermolysis promotes the formation of ultra-small metal oxide (MO) nanoparticles immobilized in an open framework that exhibits high catalytic activity for Lewis acid catalyzed reactions. Most importantly, this work pro-vides fresh insights into the connection between linker apportionment and vacancy distribution, which may shed light on prob-ing the disordered linker apportionment in multivariate systems, a long-standing challenge in the study of MTV-MOFs.

  3. Hierarchical Co(OH){sub 2} nanostructures/glassy carbon electrode derived from Co(BTC) metal–organic frameworks for glucose sensing

    Energy Technology Data Exchange (ETDEWEB)

    He, Juan; Lu, Xingping; Yu, Jie; Wang, Li; Song, Yonghai, E-mail: yhsonggroup@hotmail.com [Jiangxi Normal University, Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Key Laboratory of Chemical Biology, College of Chemistry and Chemical Engineering (China)

    2016-07-15

    A novel Co(OH){sub 2}/glassy carbon electrode (GCE) has been fabricated via metal–organic framework (MOF)-directed method. In the strategy, the Co(BTC, 1,3,5-benzentricarboxylic acid) MOFs/GCE was firstly prepared by alternately immersing GCE in Co{sup 2+} and BTC solution based on a layer-by-layer method. And then, the Co(OH){sub 2} with hierarchical flake nanostructure/GCE was constructed by immersing Co(BTC) MOFs/GCE into 0.1 M NaOH solution at room temperature. Such strategy improves the distribution of hierarchical Co(OH){sub 2} nanostructures on electrode surface greatly, enhances the stability of nanomaterials on the electrode surface, and increases the use efficiency of the Co(OH){sub 2} nanostructures. Scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, and Raman spectra were used to characterize the Co(BTC) MOFs/GCE and Co(OH){sub 2}/GCE. Based on the hierarchical Co(OH){sub 2} nanostructures/GCE, a novel and sensitive nonenzymatic glucose sensor was developed. The good performance of the resulted sensor toward the detection of glucose was ascribed to hierarchical flake nanostructures, good mechanical stability, excellent distribution, and large specific surface area of Co(OH){sub 2} nanostructures. The proposed preparation method is simple, efficient, and cheap .Graphical Abstract.

  4. Improved Gravitation Field Algorithm and Its Application in Hierarchical Clustering

    Science.gov (United States)

    Zheng, Ming; Sun, Ying; Liu, Gui-xia; Zhou, You; Zhou, Chun-guang

    2012-01-01

    Background Gravitation field algorithm (GFA) is a new optimization algorithm which is based on an imitation of natural phenomena. GFA can do well both for searching global minimum and multi-minima in computational biology. But GFA needs to be improved for increasing efficiency, and modified for applying to some discrete data problems in system biology. Method An improved GFA called IGFA was proposed in this paper. Two parts were improved in IGFA. The first one is the rule of random division, which is a reasonable strategy and makes running time shorter. The other one is rotation factor, which can improve the accuracy of IGFA. And to apply IGFA to the hierarchical clustering, the initial part and the movement operator were modified. Results Two kinds of experiments were used to test IGFA. And IGFA was applied to hierarchical clustering. The global minimum experiment was used with IGFA, GFA, GA (genetic algorithm) and SA (simulated annealing). Multi-minima experiment was used with IGFA and GFA. The two experiments results were compared with each other and proved the efficiency of IGFA. IGFA is better than GFA both in accuracy and running time. For the hierarchical clustering, IGFA is used to optimize the smallest distance of genes pairs, and the results were compared with GA and SA, singular-linkage clustering, UPGMA. The efficiency of IGFA is proved. PMID:23173043

  5. Evaluating Hierarchical Structure in Music Annotations.

    Science.gov (United States)

    McFee, Brian; Nieto, Oriol; Farbood, Morwaread M; Bello, Juan Pablo

    2017-01-01

    Music exhibits structure at multiple scales, ranging from motifs to large-scale functional components. When inferring the structure of a piece, different listeners may attend to different temporal scales, which can result in disagreements when they describe the same piece. In the field of music informatics research (MIR), it is common to use corpora annotated with structural boundaries at different levels. By quantifying disagreements between multiple annotators, previous research has yielded several insights relevant to the study of music cognition. First, annotators tend to agree when structural boundaries are ambiguous. Second, this ambiguity seems to depend on musical features, time scale, and genre. Furthermore, it is possible to tune current annotation evaluation metrics to better align with these perceptual differences. However, previous work has not directly analyzed the effects of hierarchical structure because the existing methods for comparing structural annotations are designed for "flat" descriptions, and do not readily generalize to hierarchical annotations. In this paper, we extend and generalize previous work on the evaluation of hierarchical descriptions of musical structure. We derive an evaluation metric which can compare hierarchical annotations holistically across multiple levels. sing this metric, we investigate inter-annotator agreement on the multilevel annotations of two different music corpora, investigate the influence of acoustic properties on hierarchical annotations, and evaluate existing hierarchical segmentation algorithms against the distribution of inter-annotator agreement.

  6. Evaluating Hierarchical Structure in Music Annotations

    Directory of Open Access Journals (Sweden)

    Brian McFee

    2017-08-01

    Full Text Available Music exhibits structure at multiple scales, ranging from motifs to large-scale functional components. When inferring the structure of a piece, different listeners may attend to different temporal scales, which can result in disagreements when they describe the same piece. In the field of music informatics research (MIR, it is common to use corpora annotated with structural boundaries at different levels. By quantifying disagreements between multiple annotators, previous research has yielded several insights relevant to the study of music cognition. First, annotators tend to agree when structural boundaries are ambiguous. Second, this ambiguity seems to depend on musical features, time scale, and genre. Furthermore, it is possible to tune current annotation evaluation metrics to better align with these perceptual differences. However, previous work has not directly analyzed the effects of hierarchical structure because the existing methods for comparing structural annotations are designed for “flat” descriptions, and do not readily generalize to hierarchical annotations. In this paper, we extend and generalize previous work on the evaluation of hierarchical descriptions of musical structure. We derive an evaluation metric which can compare hierarchical annotations holistically across multiple levels. sing this metric, we investigate inter-annotator agreement on the multilevel annotations of two different music corpora, investigate the influence of acoustic properties on hierarchical annotations, and evaluate existing hierarchical segmentation algorithms against the distribution of inter-annotator agreement.

  7. Selective Template Wetting Routes to Hierarchical Polymer Films: Polymer Nanotubes from Phase-Separated Films via Solvent Annealing.

    Science.gov (United States)

    Ko, Hao-Wen; Cheng, Ming-Hsiang; Chi, Mu-Huan; Chang, Chun-Wei; Chen, Jiun-Tai

    2016-03-01

    We demonstrate a novel wetting method to prepare hierarchical polymer films with polymer nanotubes on selective regions. This strategy is based on the selective wetting abilities of polymer chains, annealed in different solvent vapors, into the nanopores of porous templates. Phase-separated films of polystyrene (PS) and poly(methyl methacrylate) (PMMA), two commonly used polymers, are prepared as a model system. After anodic aluminum oxide (AAO) templates are placed on the films, the samples are annealed in vapors of acetic acid, in which the PMMA chains are swollen and wet the nanopores of the AAO templates selectively. As a result, hierarchical polymer films containing PMMA nanotubes can be obtained after the AAO templates are removed. The distribution of the PMMA nanotubes of the hierarchical polymer films can also be controlled by changing the compositions of the polymer blends. This work not only presents a novel method to fabricate hierarchical polymer films with polymer nanotubes on selective regions, but also gives a deeper understanding in the selective wetting ability of polymer chains in solvent vapors.

  8. How does aging affect recognition-based inference? A hierarchical Bayesian modeling approach.

    Science.gov (United States)

    Horn, Sebastian S; Pachur, Thorsten; Mata, Rui

    2015-01-01

    The recognition heuristic (RH) is a simple strategy for probabilistic inference according to which recognized objects are judged to score higher on a criterion than unrecognized objects. In this article, a hierarchical Bayesian extension of the multinomial r-model is applied to measure use of the RH on the individual participant level and to re-evaluate differences between younger and older adults' strategy reliance across environments. Further, it is explored how individual r-model parameters relate to alternative measures of the use of recognition and other knowledge, such as adherence rates and indices from signal-detection theory (SDT). Both younger and older adults used the RH substantially more often in an environment with high than low recognition validity, reflecting adaptivity in strategy use across environments. In extension of previous analyses (based on adherence rates), hierarchical modeling revealed that in an environment with low recognition validity, (a) older adults had a stronger tendency than younger adults to rely on the RH and (b) variability in RH use between individuals was larger than in an environment with high recognition validity; variability did not differ between age groups. Further, the r-model parameters correlated moderately with an SDT measure expressing how well people can discriminate cases where the RH leads to a correct vs. incorrect inference; this suggests that the r-model and the SDT measures may offer complementary insights into the use of recognition in decision making. In conclusion, younger and older adults are largely adaptive in their application of the RH, but cognitive aging may be associated with an increased tendency to rely on this strategy. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Hierarchically structured, nitrogen-doped carbon membranes

    KAUST Repository

    Wang, Hong; Wu, Tao

    2017-01-01

    The present invention is a structure, method of making and method of use for a novel macroscopic hierarchically structured, nitrogen-doped, nano-porous carbon membrane (HNDCMs) with asymmetric and hierarchical pore architecture that can be produced

  10. Hierarchically organized layout for visualization of biochemical pathways.

    Science.gov (United States)

    Tsay, Jyh-Jong; Wu, Bo-Liang; Jeng, Yu-Sen

    2010-01-01

    Many complex pathways are described as hierarchical structures in which a pathway is recursively partitioned into several sub-pathways, and organized hierarchically as a tree. The hierarchical structure provides a natural way to visualize the global structure of a complex pathway. However, none of the previous research on pathway visualization explores the hierarchical structures provided by many complex pathways. In this paper, we aim to develop algorithms that can take advantages of hierarchical structures, and give layouts that explore the global structures as well as local structures of pathways. We present a new hierarchically organized layout algorithm to produce layouts for hierarchically organized pathways. Our algorithm first decomposes a complex pathway into sub-pathway groups along the hierarchical organization, and then partition each sub-pathway group into basic components. It then applies conventional layout algorithms, such as hierarchical layout and force-directed layout, to compute the layout of each basic component. Finally, component layouts are joined to form a final layout of the pathway. Our main contribution is the development of algorithms for decomposing pathways and joining layouts. Experiment shows that our algorithm is able to give comprehensible visualization for pathways with hierarchies, cycles as well as complex structures. It clearly renders the global component structures as well as the local structure in each component. In addition, it runs very fast, and gives better visualization for many examples from previous related research. 2009 Elsevier B.V. All rights reserved.

  11. One-Pot and Facile Fabrication of Hierarchical Branched Pt-Cu Nanoparticles as Excellent Electrocatalysts for Direct Methanol Fuel Cells.

    Science.gov (United States)

    Cao, Yanqin; Yang, Yong; Shan, Yufeng; Huang, Zhengren

    2016-03-09

    Hierarchical branched nanoparticles are one promising nanostructure with three-dimensional open porous structure composed of integrated branches for superior catalysis. We have successfully synthesized Pt-Cu hierarchical branched nanoparticles (HBNDs) with small size of about 30 nm and composed of integrated ultrathin branches by using a modified polyol process with introduction of poly(vinylpyrrolidone) and HCl. This strategy is expected to be a general strategy to prepare various metallic nanostructures for catalysis. Because of the special open porous structure, the as-prepared Pt-Cu HBNDs exhibit greatly enhanced specific activity toward the methanol oxidation reaction as much as 2.5 and 1.7 times compared with that of the commercial Pt-Ru and Pt-Ru/C catalysts, respectively. Therefore, they are potentially applicable as electrocatalysts for direct methanol fuel cells.

  12. Hierarchical screening for multiple mental disorders.

    Science.gov (United States)

    Batterham, Philip J; Calear, Alison L; Sunderland, Matthew; Carragher, Natacha; Christensen, Helen; Mackinnon, Andrew J

    2013-10-01

    There is a need for brief, accurate screening when assessing multiple mental disorders. Two-stage hierarchical screening, consisting of brief pre-screening followed by a battery of disorder-specific scales for those who meet diagnostic criteria, may increase the efficiency of screening without sacrificing precision. This study tested whether more efficient screening could be gained using two-stage hierarchical screening than by administering multiple separate tests. Two Australian adult samples (N=1990) with high rates of psychopathology were recruited using Facebook advertising to examine four methods of hierarchical screening for four mental disorders: major depressive disorder, generalised anxiety disorder, panic disorder and social phobia. Using K6 scores to determine whether full screening was required did not increase screening efficiency. However, pre-screening based on two decision tree approaches or item gating led to considerable reductions in the mean number of items presented per disorder screened, with estimated item reductions of up to 54%. The sensitivity of these hierarchical methods approached 100% relative to the full screening battery. Further testing of the hierarchical screening approach based on clinical criteria and in other samples is warranted. The results demonstrate that a two-phase hierarchical approach to screening multiple mental disorders leads to considerable increases efficiency gains without reducing accuracy. Screening programs should take advantage of prescreeners based on gating items or decision trees to reduce the burden on respondents. © 2013 Elsevier B.V. All rights reserved.

  13. Testing adaptive toolbox models: a Bayesian hierarchical approach.

    Science.gov (United States)

    Scheibehenne, Benjamin; Rieskamp, Jörg; Wagenmakers, Eric-Jan

    2013-01-01

    Many theories of human cognition postulate that people are equipped with a repertoire of strategies to solve the tasks they face. This theoretical framework of a cognitive toolbox provides a plausible account of intra- and interindividual differences in human behavior. Unfortunately, it is often unclear how to rigorously test the toolbox framework. How can a toolbox model be quantitatively specified? How can the number of toolbox strategies be limited to prevent uncontrolled strategy sprawl? How can a toolbox model be formally tested against alternative theories? The authors show how these challenges can be met by using Bayesian inference techniques. By means of parameter recovery simulations and the analysis of empirical data across a variety of domains (i.e., judgment and decision making, children's cognitive development, function learning, and perceptual categorization), the authors illustrate how Bayesian inference techniques allow toolbox models to be quantitatively specified, strategy sprawl to be contained, and toolbox models to be rigorously tested against competing theories. The authors demonstrate that their approach applies at the individual level but can also be generalized to the group level with hierarchical Bayesian procedures. The suggested Bayesian inference techniques represent a theoretical and methodological advancement for toolbox theories of cognition and behavior.

  14. Self-assembled biomimetic superhydrophobic hierarchical arrays.

    Science.gov (United States)

    Yang, Hongta; Dou, Xuan; Fang, Yin; Jiang, Peng

    2013-09-01

    Here, we report a simple and inexpensive bottom-up technology for fabricating superhydrophobic coatings with hierarchical micro-/nano-structures, which are inspired by the binary periodic structure found on the superhydrophobic compound eyes of some insects (e.g., mosquitoes and moths). Binary colloidal arrays consisting of exemplary large (4 and 30 μm) and small (300 nm) silica spheres are first assembled by a scalable Langmuir-Blodgett (LB) technology in a layer-by-layer manner. After surface modification with fluorosilanes, the self-assembled hierarchical particle arrays become superhydrophobic with an apparent water contact angle (CA) larger than 150°. The throughput of the resulting superhydrophobic coatings with hierarchical structures can be significantly improved by templating the binary periodic structures of the LB-assembled colloidal arrays into UV-curable fluoropolymers by a soft lithography approach. Superhydrophobic perfluoroether acrylate hierarchical arrays with large CAs and small CA hysteresis can be faithfully replicated onto various substrates. Both experiments and theoretical calculations based on the Cassie's dewetting model demonstrate the importance of the hierarchical structure in achieving the final superhydrophobic surface states. Copyright © 2013 Elsevier Inc. All rights reserved.

  15. Hierarchically structured, nitrogen-doped carbon membranes

    KAUST Repository

    Wang, Hong

    2017-08-03

    The present invention is a structure, method of making and method of use for a novel macroscopic hierarchically structured, nitrogen-doped, nano-porous carbon membrane (HNDCMs) with asymmetric and hierarchical pore architecture that can be produced on a large-scale approach. The unique HNDCM holds great promise as components in separation and advanced carbon devices because they could offer unconventional fluidic transport phenomena on the nanoscale. Overall, the invention set forth herein covers a hierarchically structured, nitrogen-doped carbon membranes and methods of making and using such a membranes.

  16. Hierarchical Rhetorical Sentence Categorization for Scientific Papers

    Science.gov (United States)

    Rachman, G. H.; Khodra, M. L.; Widyantoro, D. H.

    2018-03-01

    Important information in scientific papers can be composed of rhetorical sentences that is structured from certain categories. To get this information, text categorization should be conducted. Actually, some works in this task have been completed by employing word frequency, semantic similarity words, hierarchical classification, and the others. Therefore, this paper aims to present the rhetorical sentence categorization from scientific paper by employing TF-IDF and Word2Vec to capture word frequency and semantic similarity words and employing hierarchical classification. Every experiment is tested in two classifiers, namely Naïve Bayes and SVM Linear. This paper shows that hierarchical classifier is better than flat classifier employing either TF-IDF or Word2Vec, although it increases only almost 2% from 27.82% when using flat classifier until 29.61% when using hierarchical classifier. It shows also different learning model for child-category can be built by hierarchical classifier.

  17. Hierarchical Recurrent Neural Hashing for Image Retrieval With Hierarchical Convolutional Features.

    Science.gov (United States)

    Lu, Xiaoqiang; Chen, Yaxiong; Li, Xuelong

    Hashing has been an important and effective technology in image retrieval due to its computational efficiency and fast search speed. The traditional hashing methods usually learn hash functions to obtain binary codes by exploiting hand-crafted features, which cannot optimally represent the information of the sample. Recently, deep learning methods can achieve better performance, since deep learning architectures can learn more effective image representation features. However, these methods only use semantic features to generate hash codes by shallow projection but ignore texture details. In this paper, we proposed a novel hashing method, namely hierarchical recurrent neural hashing (HRNH), to exploit hierarchical recurrent neural network to generate effective hash codes. There are three contributions of this paper. First, a deep hashing method is proposed to extensively exploit both spatial details and semantic information, in which, we leverage hierarchical convolutional features to construct image pyramid representation. Second, our proposed deep network can exploit directly convolutional feature maps as input to preserve the spatial structure of convolutional feature maps. Finally, we propose a new loss function that considers the quantization error of binarizing the continuous embeddings into the discrete binary codes, and simultaneously maintains the semantic similarity and balanceable property of hash codes. Experimental results on four widely used data sets demonstrate that the proposed HRNH can achieve superior performance over other state-of-the-art hashing methods.Hashing has been an important and effective technology in image retrieval due to its computational efficiency and fast search speed. The traditional hashing methods usually learn hash functions to obtain binary codes by exploiting hand-crafted features, which cannot optimally represent the information of the sample. Recently, deep learning methods can achieve better performance, since deep

  18. Hierarchical Artificial Bee Colony Optimizer with Divide-and-Conquer and Crossover for Multilevel Threshold Image Segmentation

    Directory of Open Access Journals (Sweden)

    Maowei He

    2014-01-01

    Full Text Available This paper presents a novel optimization algorithm, namely, hierarchical artificial bee colony optimization (HABC, for multilevel threshold image segmentation, which employs a pool of optimal foraging strategies to extend the classical artificial bee colony framework to a cooperative and hierarchical fashion. In the proposed hierarchical model, the higher-level species incorporates the enhanced information exchange mechanism based on crossover operator to enhance the global search ability between species. In the bottom level, with the divide-and-conquer approach, each subpopulation runs the original ABC method in parallel to part-dimensional optimum, which can be aggregated into a complete solution for the upper level. The experimental results for comparing HABC with several successful EA and SI algorithms on a set of benchmarks demonstrated the effectiveness of the proposed algorithm. Furthermore, we applied the HABC to the multilevel image segmentation problem. Experimental results of the new algorithm on a variety of images demonstrated the performance superiority of the proposed algorithm.

  19. Zeolitic materials with hierarchical porous structures.

    Science.gov (United States)

    Lopez-Orozco, Sofia; Inayat, Amer; Schwab, Andreas; Selvam, Thangaraj; Schwieger, Wilhelm

    2011-06-17

    During the past several years, different kinds of hierarchical structured zeolitic materials have been synthesized due to their highly attractive properties, such as superior mass/heat transfer characteristics, lower restriction of the diffusion of reactants in the mesopores, and low pressure drop. Our contribution provides general information regarding types and preparation methods of hierarchical zeolitic materials and their relative advantages and disadvantages. Thereafter, recent advances in the preparation and characterization of hierarchical zeolitic structures within the crystallites by post-synthetic treatment methods, such as dealumination or desilication; and structured devices by in situ and ex situ zeolite coatings on open-cellular ceramic foams as (non-reactive as well as reactive) supports are highlighted. Specific advantages of using hierarchical zeolitic catalysts/structures in selected catalytic reactions, such as benzene to phenol (BTOP) and methanol to olefins (MTO) are presented. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Processing of hierarchical syntactic structure in music.

    Science.gov (United States)

    Koelsch, Stefan; Rohrmeier, Martin; Torrecuso, Renzo; Jentschke, Sebastian

    2013-09-17

    Hierarchical structure with nested nonlocal dependencies is a key feature of human language and can be identified theoretically in most pieces of tonal music. However, previous studies have argued against the perception of such structures in music. Here, we show processing of nonlocal dependencies in music. We presented chorales by J. S. Bach and modified versions in which the hierarchical structure was rendered irregular whereas the local structure was kept intact. Brain electric responses differed between regular and irregular hierarchical structures, in both musicians and nonmusicians. This finding indicates that, when listening to music, humans apply cognitive processes that are capable of dealing with long-distance dependencies resulting from hierarchically organized syntactic structures. Our results reveal that a brain mechanism fundamental for syntactic processing is engaged during the perception of music, indicating that processing of hierarchical structure with nested nonlocal dependencies is not just a key component of human language, but a multidomain capacity of human cognition.

  1. Hierarchical assembly strategy and multiscale structural origin of exceptional mechanical performance in nacre

    Science.gov (United States)

    Huang, Zaiwang

    Nacre (mother of pearl) is a self-assembled hierarchical nanocomposite in possession of exquisite multiscale architecture and exceptional mechanical properties. Previous work has shown that the highly-ordered brick-mortar-like structure in nacre is assembled via epitaxial growth and the aragonite platelets are pure single-crystals. Our results challenge this conclusion and propose that nacre's individual aragonite platelets are constructed with highly-aligned aragonite nanoparticles mediated by screw dislocation and amorphous aggregation. The underlying physics mechanism why the aragonite nanoparticles choose highly-oriented attachment as its crystallization pathway is rationalized in terms of thermodynamics. The aragonite nanoparticle order-disorder transformation can be triggered by high temperature and mechanical deformation, which in turn confirms that the aragonite nanoparticles are basic building blocks for aragonite platelets. Particularly fascinating is the fracture toughness enhancement of nacre through exquisitely collecting mechanically inferior calcium carbonate (CaCO3) and biomolecules. The sandwich-like microarchitecture with a geometrically staggered arrangement can induce crack deflection along its biopolymer interface, thus significantly enhancing nacre's fracture toughness. Our new findings ambiguously demonstrate that, aside from crack deflection, the advancing crack can invade aragonite platelet, leaving a zigzag crack propagation pathway. These unexpected experimental observations disclose, for the first time, the inevitable structural role of aragonite platelets in enhancing nacre's fracture toughness. Simultaneously, the findings that the crack propagates in a zigzag manner within individual aragonite platelets overturn the previously well-established wisdom that considers aragonite platelets as brittle single-crystals. Moreover, we investigated the dynamical mechanical response of nacre under unixial compression. Our results show that the

  2. Hierarchical porous nitrogen-doped partial graphitized carbon monoliths for supercapacitor

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Yifeng; Du, Juan; Liu, Lei; Wang, Guoxu; Zhang, Hongliang; Chen, Aibing, E-mail: chen-ab@163.com [Hebei University of Science and Technology, College of Chemical and Pharmaceutical Engineering (China)

    2017-03-15

    Porous carbon monoliths have attracted great interest in many fields due to their easy availability, large specific surface area, desirable electronic conductivity, and tunable pore structure. In this work, hierarchical porous nitrogen-doped partial graphitized carbon monoliths (N–MC–Fe) with ordered mesoporous have been successfully synthesized by using resorcinol-formaldehyde as precursors, iron salts as catalyst, and mixed triblock copolymers as templates via a one-step hydrothermal method. In the reactant system, hexamethylenetetramine (HMT) is used as nitrogen source and one of the carbon precursors under hydrothermal conditions instead of using toxic formaldehyde. The N–MC–Fe show hierarchically porous structures, with interconnected macroporous and ordered hexagonally arranged mesoporous. Nitrogen element is in situ doped into carbon through decomposition of HMT. Iron catalyst is helpful to improve the graphitization degree and pore volume of N–MC–Fe. The synthesis strategy is user-friendly, cost-effective, and can be easily scaled up for production. As supercapacitors, the N–MC–Fe show good capacity with high specific capacitance and good electrochemical stability.

  3. Hierarchical Nanoceramics for Industrial Process Sensors

    Energy Technology Data Exchange (ETDEWEB)

    Ruud, James, A.; Brosnan, Kristen, H.; Striker, Todd; Ramaswamy, Vidya; Aceto, Steven, C.; Gao, Yan; Willson, Patrick, D.; Manoharan, Mohan; Armstrong, Eric, N., Wachsman, Eric, D.; Kao, Chi-Chang

    2011-07-15

    This project developed a robust, tunable, hierarchical nanoceramics materials platform for industrial process sensors in harsh-environments. Control of material structure at multiple length scales from nano to macro increased the sensing response of the materials to combustion gases. These materials operated at relatively high temperatures, enabling detection close to the source of combustion. It is anticipated that these materials can form the basis for a new class of sensors enabling widespread use of efficient combustion processes with closed loop feedback control in the energy-intensive industries. The first phase of the project focused on materials selection and process development, leading to hierarchical nanoceramics that were evaluated for sensing performance. The second phase focused on optimizing the materials processes and microstructures, followed by validation of performance of a prototype sensor in a laboratory combustion environment. The objectives of this project were achieved by: (1) synthesizing and optimizing hierarchical nanostructures; (2) synthesizing and optimizing sensing nanomaterials; (3) integrating sensing functionality into hierarchical nanostructures; (4) demonstrating material performance in a sensing element; and (5) validating material performance in a simulated service environment. The project developed hierarchical nanoceramic electrodes for mixed potential zirconia gas sensors with increased surface area and demonstrated tailored electrocatalytic activity operable at high temperatures enabling detection of products of combustion such as NOx close to the source of combustion. Methods were developed for synthesis of hierarchical nanostructures with high, stable surface area, integrated catalytic functionality within the structures for gas sensing, and demonstrated materials performance in harsh lab and combustion gas environments.

  4. Hierarchical Control Architecture for Demand Response in Smart Grid Scenario

    DEFF Research Database (Denmark)

    Bhattarai, Bishnu Prasad; Bak-Jensen, Birgitte; Mahat, Pukar

    2013-01-01

    , a number of issues, including DR enabling technologies, control strategy, and control architecture, are still under discussion. This paper outlines novel control requirements based on the categorization of existing DR techniques. More specifically, the roles and responsibilities of smart grid actors...... effective tool for optimum asset utilization and to avoid or delay the need for new infrastructure investment. Furthermore, most of the power networks are under the process of reconfiguration to realize the concept of smart grid and are at the transforming stage to support various forms of DR. However...... for every DR category are allotted and their mode of interactions to coordinate individual as well as coordinative goals is described. Next, hierarchical control architecture (HCA) is developed for the overall coordination of control strategies for individual DR categories. The involved issues are discussed...

  5. The Case for a Hierarchical Cosmology

    Science.gov (United States)

    Vaucouleurs, G. de

    1970-01-01

    The development of modern theoretical cosmology is presented and some questionable assumptions of orthodox cosmology are pointed out. Suggests that recent observations indicate that hierarchical clustering is a basic factor in cosmology. The implications of hierarchical models of the universe are considered. Bibliography. (LC)

  6. Classification using Hierarchical Naive Bayes models

    DEFF Research Database (Denmark)

    Langseth, Helge; Dyhre Nielsen, Thomas

    2006-01-01

    Classification problems have a long history in the machine learning literature. One of the simplest, and yet most consistently well-performing set of classifiers is the Naïve Bayes models. However, an inherent problem with these classifiers is the assumption that all attributes used to describe......, termed Hierarchical Naïve Bayes models. Hierarchical Naïve Bayes models extend the modeling flexibility of Naïve Bayes models by introducing latent variables to relax some of the independence statements in these models. We propose a simple algorithm for learning Hierarchical Naïve Bayes models...

  7. Improved Adhesion and Compliancy of Hierarchical Fibrillar Adhesives.

    Science.gov (United States)

    Li, Yasong; Gates, Byron D; Menon, Carlo

    2015-08-05

    The gecko relies on van der Waals forces to cling onto surfaces with a variety of topography and composition. The hierarchical fibrillar structures on their climbing feet, ranging from mesoscale to nanoscale, are hypothesized to be key elements for the animal to conquer both smooth and rough surfaces. An epoxy-based artificial hierarchical fibrillar adhesive was prepared to study the influence of the hierarchical structures on the properties of a dry adhesive. The presented experiments highlight the advantages of a hierarchical structure despite a reduction of overall density and aspect ratio of nanofibrils. In contrast to an adhesive containing only nanometer-size fibrils, the hierarchical fibrillar adhesives exhibited a higher adhesion force and better compliancy when tested on an identical substrate.

  8. Immobilization of Bacillus subtilis lipase on a Cu-BTC based hierarchically porous metal-organic framework material: a biocatalyst for esterification.

    Science.gov (United States)

    Cao, Yu; Wu, Zhuofu; Wang, Tao; Xiao, Yu; Huo, Qisheng; Liu, Yunling

    2016-04-28

    Bacillus subtilis lipase (BSL2) has been successfully immobilized into a Cu-BTC based hierarchically porous metal-organic framework material for the first time. The Cu-BTC hierarchically porous MOF material with large mesopore apertures is prepared conveniently by using a template-free strategy under mild conditions. The immobilized BSL2 presents high enzymatic activity and perfect reusability during the esterification reaction. After 10 cycles, the immobilized BSL2 still exhibits 90.7% of its initial enzymatic activity and 99.6% of its initial conversion.

  9. Superhydrophobic SERS substrates based on silicon hierarchical nanostructures

    Science.gov (United States)

    Chen, Xuexian; Wen, Jinxiu; Zhou, Jianhua; Zheng, Zebo; An, Di; Wang, Hao; Xie, Weiguang; Zhan, Runze; Xu, Ningsheng; Chen, Jun; She, Juncong; Chen, Huanjun; Deng, Shaozhi

    2018-02-01

    Silicon nanostructures have been cultivated as promising surface enhanced Raman scattering (SERS) substrates in terms of their low-loss optical resonance modes, facile functionalization, and compatibility with today’s state-of-the-art CMOS techniques. However, unlike their plasmonic counterparts, the electromagnetic field enhancements induced by silicon nanostructures are relatively small, which restrict their SERS sensing limit to around 10-7 M. To tackle this problem, we propose here a strategy for improving the SERS performance of silicon nanostructures by constructing silicon hierarchical nanostructures with a superhydrophobic surface. The hierarchical nanostructures are binary structures consisted of silicon nanowires (NWs) grown on micropyramids (MPs). After being modified with perfluorooctyltriethoxysilane (PFOT), the nanostructure surface shows a stable superhydrophobicity with a high contact angle of ˜160°. The substrate can allow for concentrating diluted analyte solutions into a specific area during the evaporation of the liquid droplet, whereby the analytes are aggregated into a small volume and can be easily detected by the silicon nanostructure SERS substrate. The analyte molecules (methylene blue: MB) enriched from an aqueous solution lower than 10-8 M can be readily detected. Such a detection limit is ˜100-fold lower than the conventional SERS substrates made of silicon nanostructures. Additionally, the detection limit can be further improved by functionalizing gold nanoparticles onto silicon hierarchical nanostructures, whereby the superhydrophobic characteristics and plasmonic field enhancements can be combined synergistically to give a detection limit down to ˜10-11 M. A gold nanoparticle-functionalized superhydrophobic substrate was employed to detect the spiked melamine in liquid milk. The results showed that the detection limit can be as low as 10-5 M, highlighting the potential of the proposed superhydrophobic SERS substrate in

  10. Stackelberg Interdependent Security Game in Distributed and Hierarchical Cyber-Physical Systems

    Directory of Open Access Journals (Sweden)

    Jiajun Shen

    2017-01-01

    Full Text Available With the integration of physical plant and network, cyber-physical systems (CPSs are increasingly vulnerable due to their distributed and hierarchical framework. Stackelberg interdependent security game (SISG is proposed for characterizing the interdependent security in CPSs, that is, the interactions between individual CPSs, which are selfish but nonmalicious with the payoff function being formulated from a cross-layer perspective. The pure-strategy equilibria for two-player symmetric SISG are firstly analyzed with the strategy gap between individual and social optimum being characterized, which is known as negative externalities. Then, the results are further extended to the asymmetric and m-player SISG. At last, a numerical case of practical experiment platform is analyzed for determining the comprehensively optimal security configuration for administrator.

  11. One-step synthesis of hierarchically porous hybrid TiO2 hollow spheres with high photocatalytic activity

    Science.gov (United States)

    Liu, Ruiping; Ren, Feng; Yang, Jinlin; Su, Weiming; Sun, Zhiming; Zhang, Lei; Wang, Chang-an

    2016-03-01

    Hierarchically porous hybrid TiO2 hollow spheres were solvothermally synthesized successfully by using tetrabutyl titanate as titanium precursor and hydrated metal sulfates as soft templates. The as-prepared TiO2 spheres with hierarchically pore structures and high specific surface area and pore volume consisted of highly crystallized anatase TiO2 nanocrystals hybridized with a small amount of metal oxide from the hydrated sulfate. The proposed hydrated-sulfate assisted solvothermal (HAS) synthesis strategy was demonstrated to be widely applicable to various systems. Evaluation of the hybrid TiO2 hollow spheres for the photo-decomposition of methyl orange (MO) under visible-light irradiation revealed that they exhibited excellent photocatalytic activity and durability.

  12. Leadership styles across hierarchical levels in nursing departments.

    Science.gov (United States)

    Stordeur, S; Vandenberghe, C; D'hoore, W

    2000-01-01

    Some researchers have reported on the cascading effect of transformational leadership across hierarchical levels. One study examined this effect in nursing, but it was limited to a single hospital. To examine the cascading effect of leadership styles across hierarchical levels in a sample of nursing departments and to investigate the effect of hierarchical level on the relationships between leadership styles and various work outcomes. Based on a sample of eight hospitals, the cascading effect was tested using correlation analysis. The main sources of variation among leadership scores were determined with analyses of variance (ANOVA), and the interaction effect of hierarchical level and leadership styles on criterion variables was tested with moderated regression analysis. No support was found for a cascading effect of leadership across hierarchical levels. Rather, the variation of leadership scores was explained primarily by the organizational context. Transformational leadership had a stronger impact on criterion variables than transactional leadership. Interaction effects between leadership styles and hierarchical level were observed only for perceived unit effectiveness. The hospital's structure and culture are major determinants of leadership styles.

  13. Hierarchically organized architecture of potassium hydrogen phthalate and poly(acrylic acid): toward a general strategy for biomimetic crystal design.

    Science.gov (United States)

    Oaki, Yuya; Imai, Hiroaki

    2005-12-28

    A hierarchically organized architecture in multiple scales was generated from potassium hydrogen phthalate crystals and poly(acrylic acid) based on our novel biomimetic approach with an exquisite association of polymers on crystallization.

  14. An Improved 6LoWPAN Hierarchical Routing Protocol

    Directory of Open Access Journals (Sweden)

    Xue Li

    2015-10-01

    Full Text Available IETF 6LoWPAN working group is engaged in the IPv6 protocol stack research work based on IEEE802.15.4 standard. In this working group, the routing protocol is one of the important research contents. In the 6LoWPAN, HiLow is a well-known layered routing protocol. This paper puts forward an improved hierarchical routing protocol GHiLow by improving HiLow parent node selection and path restoration strategy. GHiLow improves the parent node selection by increasing the choice of parameters. Simutaneously, it also improves path recovery by analysing different situations to recovery path. Therefore, GHiLow contributes to the ehancement of network performance and the decrease of network energy consumption.

  15. Learning with hierarchical-deep models.

    Science.gov (United States)

    Salakhutdinov, Ruslan; Tenenbaum, Joshua B; Torralba, Antonio

    2013-08-01

    We introduce HD (or “Hierarchical-Deep”) models, a new compositional learning architecture that integrates deep learning models with structured hierarchical Bayesian (HB) models. Specifically, we show how we can learn a hierarchical Dirichlet process (HDP) prior over the activities of the top-level features in a deep Boltzmann machine (DBM). This compound HDP-DBM model learns to learn novel concepts from very few training example by learning low-level generic features, high-level features that capture correlations among low-level features, and a category hierarchy for sharing priors over the high-level features that are typical of different kinds of concepts. We present efficient learning and inference algorithms for the HDP-DBM model and show that it is able to learn new concepts from very few examples on CIFAR-100 object recognition, handwritten character recognition, and human motion capture datasets.

  16. Communication Reducing Algorithms for Distributed Hierarchical N-Body Problems with Boundary Distributions

    KAUST Repository

    AbdulJabbar, Mustafa Abdulmajeed

    2017-05-11

    Reduction of communication and efficient partitioning are key issues for achieving scalability in hierarchical N-Body algorithms like Fast Multipole Method (FMM). In the present work, we propose three independent strategies to improve partitioning and reduce communication. First, we show that the conventional wisdom of using space-filling curve partitioning may not work well for boundary integral problems, which constitute a significant portion of FMM’s application user base. We propose an alternative method that modifies orthogonal recursive bisection to relieve the cell-partition misalignment that has kept it from scaling previously. Secondly, we optimize the granularity of communication to find the optimal balance between a bulk-synchronous collective communication of the local essential tree and an RDMA per task per cell. Finally, we take the dynamic sparse data exchange proposed by Hoefler et al. [1] and extend it to a hierarchical sparse data exchange, which is demonstrated at scale to be faster than the MPI library’s MPI_Alltoallv that is commonly used.

  17. A hybrid deterministic-probabilistic approach to model the mechanical response of helically arranged hierarchical strands

    Science.gov (United States)

    Fraldi, M.; Perrella, G.; Ciervo, M.; Bosia, F.; Pugno, N. M.

    2017-09-01

    Very recently, a Weibull-based probabilistic strategy has been successfully applied to bundles of wires to determine their overall stress-strain behaviour, also capturing previously unpredicted nonlinear and post-elastic features of hierarchical strands. This approach is based on the so-called "Equal Load Sharing (ELS)" hypothesis by virtue of which, when a wire breaks, the load acting on the strand is homogeneously redistributed among the surviving wires. Despite the overall effectiveness of the method, some discrepancies between theoretical predictions and in silico Finite Element-based simulations or experimental findings might arise when more complex structures are analysed, e.g. helically arranged bundles. To overcome these limitations, an enhanced hybrid approach is proposed in which the probability of rupture is combined with a deterministic mechanical model of a strand constituted by helically-arranged and hierarchically-organized wires. The analytical model is validated comparing its predictions with both Finite Element simulations and experimental tests. The results show that generalized stress-strain responses - incorporating tension/torsion coupling - are naturally found and, once one or more elements break, the competition between geometry and mechanics of the strand microstructure, i.e. the different cross sections and helical angles of the wires in the different hierarchical levels of the strand, determines the no longer homogeneous stress redistribution among the surviving wires whose fate is hence governed by a "Hierarchical Load Sharing" criterion.

  18. Hierarchically structured transparent hybrid membranes by in situ growth of mesostructured organosilica in host polymer

    Science.gov (United States)

    Vallé, Karine; Belleville, Philippe; Pereira, Franck; Sanchez, Clément

    2006-02-01

    The elaborate performances characterizing natural materials result from functional hierarchical constructions at scales ranging from nanometres to millimetres, each construction allowing the material to fit the physical or chemical demands occurring at these different levels. Hierarchically structured materials start to demonstrate a high input in numerous promising applied domains such as sensors, catalysis, optics, fuel cells, smart biologic and cosmetic vectors. In particular, hierarchical hybrid materials permit the accommodation of a maximum of elementary functions in a small volume, thereby optimizing complementary possibilities and properties between inorganic and organic components. The reported strategies combine sol-gel chemistry, self-assembly routes using templates that tune the material's architecture and texture with the use of larger inorganic, organic or biological templates such as latex, organogelator-derived fibres, nanolithographic techniques or controlled phase separation. We propose an approach to forming transparent hierarchical hybrid functionalized membranes using in situ generation of mesostructured hybrid phases inside a non-porogenic hydrophobic polymeric host matrix. We demonstrate that the control of the multiple affinities existing between organic and inorganic components allows us to design the length-scale partitioning of hybrid nanomaterials with tuned functionalities and desirable size organization from ångström to centimetre. After functionalization of the mesoporous hybrid silica component, the resulting membranes have good ionic conductivity offering interesting perspectives for the design of solid electrolytes, fuel cells and other ion-transport microdevices.

  19. Flexible fabrication of biomimetic compound eye array via two-step thermal reflow of simply pre-modeled hierarchic microstructures

    Science.gov (United States)

    Huang, Shengzhou; Li, Mujun; Shen, Lianguan; Qiu, Jinfeng; Zhou, Youquan

    2017-06-01

    A flexible fabrication method for the biomimetic compound eye (BCE) array is proposed. In this method, a triple-layer sandwich-like coating configuration was introduced, and the required hierarchic microstructures are formed with a simple single-scan exposure in maskless digital lithography. Taking advantage of the difference of glass transition point (Tg) between photoresists of each layer, the pre-formed hierarchic microstructures are in turn reflowed to the curved substrate and the BCE ommatidia in a two-step thermal reflow process. To avoid affecting the spherical substrate formed in the first thermal reflow, a non-contact strategy was proposed in the second reflow process. The measurement results were in good agreement with the designed BCE profiles. Results also showed that the fabricated BCE had good performances in optical test. The presented method is flexible, convenient, low-cost and can easily adapt to the fabrications of other optical elements with hierarchic microstructures.

  20. A Facile Method to Fabricate Anisotropic Hydrogels with Perfectly Aligned Hierarchical Fibrous Structures.

    Science.gov (United States)

    Mredha, Md Tariful Islam; Guo, Yun Zhou; Nonoyama, Takayuki; Nakajima, Tasuku; Kurokawa, Takayuki; Gong, Jian Ping

    2018-03-01

    Natural structural materials (such as tendons and ligaments) are comprised of multiscale hierarchical architectures, with dimensions ranging from nano- to macroscale, which are difficult to mimic synthetically. Here a bioinspired, facile method to fabricate anisotropic hydrogels with perfectly aligned multiscale hierarchical fibrous structures similar to those of tendons and ligaments is reported. The method includes drying a diluted physical hydrogel in air by confining its length direction. During this process, sufficiently high tensile stress is built along the length direction to align the polymer chains and multiscale fibrous structures (from nano- to submicro- to microscale) are spontaneously formed in the bulk material, which are well-retained in the reswollen gel. The method is useful for relatively rigid polymers (such as alginate and cellulose), which are susceptible to mechanical signal. By controlling the drying with or without prestretching, the degree of alignment, size of superstructures, and the strength of supramolecular interactions can be tuned, which sensitively influence the strength and toughness of the hydrogels. The mechanical properties are comparable with those of natural ligaments. This study provides a general strategy for designing hydrogels with highly ordered hierarchical structures, which opens routes for the development of many functional biomimetic materials for biomedical applications. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Hierarchical Compliance Control of a Soft Ankle Rehabilitation Robot Actuated by Pneumatic Muscles.

    Science.gov (United States)

    Liu, Quan; Liu, Aiming; Meng, Wei; Ai, Qingsong; Xie, Sheng Q

    2017-01-01

    Traditional compliance control of a rehabilitation robot is implemented in task space by using impedance or admittance control algorithms. The soft robot actuated by pneumatic muscle actuators (PMAs) is becoming prominent for patients as it enables the compliance being adjusted in each active link, which, however, has not been reported in the literature. This paper proposes a new compliance control method of a soft ankle rehabilitation robot that is driven by four PMAs configured in parallel to enable three degrees of freedom movement of the ankle joint. A new hierarchical compliance control structure, including a low-level compliance adjustment controller in joint space and a high-level admittance controller in task space, is designed. An adaptive compliance control paradigm is further developed by taking into account patient's active contribution and movement ability during a previous period of time, in order to provide robot assistance only when it is necessarily required. Experiments on healthy and impaired human subjects were conducted to verify the adaptive hierarchical compliance control scheme. The results show that the robot hierarchical compliance can be online adjusted according to the participant's assessment. The robot reduces its assistance output when participants contribute more and vice versa , thus providing a potentially feasible solution to the patient-in-loop cooperative training strategy.

  2. Climate change scenarios for Canada's national parks : a users manual

    International Nuclear Information System (INIS)

    Jones, B.; Wun, N.; Scott, D.; Barrow, E.

    2003-01-01

    A screening level impact assessment has shown that the implications of climate change for Canada's national parks are considerable. Climate change scenarios will be an important component in examining the potential climate change impacts and the implications of adaptation strategies. Most climate change scenarios are based on vulnerability, impact and adaptation research. This user's manual describes the development of 3 types of climate change scenarios including scenarios from global climate models (GCMs), bioclimate scenarios and daily scenarios for use by Parks Canada. The manual offers advice to first-time climate change scenario users in choosing and interpreting climate change, bioclimate and daily scenarios. It also addresses the theoretical and practical foundations of each climate scenario and shows how to access data regarding the various scenarios. Hands-on exercises are included as an interpretive aid. 20 refs., 4 tabs., 19 figs

  3. Hierarchical analysis of acceptable use policies

    Directory of Open Access Journals (Sweden)

    P. A. Laughton

    2008-01-01

    Full Text Available Acceptable use policies (AUPs are vital tools for organizations to protect themselves and their employees from misuse of computer facilities provided. A well structured, thorough AUP is essential for any organization. It is impossible for an effective AUP to deal with every clause and remain readable. For this reason, some sections of an AUP carry more weight than others, denoting importance. The methodology used to develop the hierarchical analysis is a literature review, where various sources were consulted. This hierarchical approach to AUP analysis attempts to highlight important sections and clauses dealt with in an AUP. The emphasis of the hierarchal analysis is to prioritize the objectives of an AUP.

  4. Virtual timers in hierarchical real-time systems

    NARCIS (Netherlands)

    Heuvel, van den M.M.H.P.; Holenderski, M.J.; Cools, W.A.; Bril, R.J.; Lukkien, J.J.; Zhu, D.

    2009-01-01

    Hierarchical scheduling frameworks (HSFs) provide means for composing complex real-time systems from welldefined subsystems. This paper describes an approach to provide hierarchically scheduled real-time applications with virtual event timers, motivated by the need for integrating priority

  5. Hierarchical porous Co3O4 films with size-adjustable pores as Li ion battery anodes with excellent rate performances

    International Nuclear Information System (INIS)

    Zhao, Guangyu; Xu, Zhanming; Zhang, Li; Sun, Kening

    2013-01-01

    Highlights: •Template-free synthesis of hierarchical porous Co 3 O 4 films on Ni foams. •Hierarchical porous Co 3 O 4 films with size-adjustable pores. •Excellent rate performances (650 mAh g −1 at 30 C) as Li ion battery anodes. -- Abstract: Constructing hierarchical porous structures on the current collectors is an attractive strategy for improving the rate performance of the Li ion battery electrodes. However, preparing hierarchical porous structures normally requires hard or soft templates to create hollows or pores in different sizes. Rigorous preparation conditions are needed to control the size (especially nanosize) and size distribution of the pores obtained by conventional methods. Herein, we describe a template-free two-step synthesis process to prepare hierarchical porous Co 3 O 4 films on Ni foam substrates. In this synthesis process, free-standing mesoporous precursor flakes are deposited on Ni foams by an electrochemical method. Subsequently, the meosporous precursor flake arrays are calcined to obtain hierarchical porous Co 3 O 4 films. More strikingly, the size of the mesopores in the flakes can be adjusted by altering the calcination temperature. The structure and morphology of the samples are characterized by scanning electron microscopy, transmission electron microscopy and Brunauer–Emmett–Teller measurements. The relationship of the in-flake-pore size and the calcinations temperature is proposed here. Electrochemical tests have revealed that the hierarchical porous Co 3 O 4 films demonstrate excellent rate performances (650 mAh g −1 at 30 C) as Li ion battery anodes due to the hierarchical porous structure, which endows fast ion transmission

  6. Using Hierarchical Machine Learning to Improve Player Satisfaction in a Soccer Videogame

    OpenAIRE

    Collins, Brian; Rovatsos, Michael

    2006-01-01

    This paper describes an approach to using a hierarchical machine learning model in a two player 3D physics-based soccer video game to improve human player satisfaction. Learning is accomplished at two layers to form a complete game-playing agent such that higher level strategy learning is dependent on lower-level learning of basic behaviors.Supervised learning is used to train neural networks on human data to model the basic behaviors. The reinforcement learning algorithms Sarsa (λ) and Q(λ) ...

  7. Risk Assessment for Mobile Systems Through a Multilayered Hierarchical Bayesian Network.

    Science.gov (United States)

    Li, Shancang; Tryfonas, Theo; Russell, Gordon; Andriotis, Panagiotis

    2016-08-01

    Mobile systems are facing a number of application vulnerabilities that can be combined together and utilized to penetrate systems with devastating impact. When assessing the overall security of a mobile system, it is important to assess the security risks posed by each mobile applications (apps), thus gaining a stronger understanding of any vulnerabilities present. This paper aims at developing a three-layer framework that assesses the potential risks which apps introduce within the Android mobile systems. A Bayesian risk graphical model is proposed to evaluate risk propagation in a layered risk architecture. By integrating static analysis, dynamic analysis, and behavior analysis in a hierarchical framework, the risks and their propagation through each layer are well modeled by the Bayesian risk graph, which can quantitatively analyze risks faced to both apps and mobile systems. The proposed hierarchical Bayesian risk graph model offers a novel way to investigate the security risks in mobile environment and enables users and administrators to evaluate the potential risks. This strategy allows to strengthen both app security as well as the security of the entire system.

  8. Hierarchically Coordinated Power Management for Target Tracking in Wireless Sensor Networks

    Directory of Open Access Journals (Sweden)

    Feng Juan

    2013-10-01

    Full Text Available Energy efficiency is very important for wireless sensor networks (WSNs since sensor nodes have a limited energy supply from a battery. So far, a lot research has focused on this issue, while less emphasis has been placed on the adaptive sleep time for each node with a consideration for the application constraints. In this paper, we propose a hierarchically coordinated power management (HCPM approach, which both addresses the energy conservation problem and reduces the packet forwarding delay for target tracking WSNs based on a virtual-grid-based network structure. We extend the network lifetime by adopting an adaptive sleep scheduling scheme that combines the local power management (PM and the adaptive coordinate PM strategies to schedule the activities of the sensor nodes at the surveillance stage. Furthermore, we propose a hierarchical structure for the tracking stage. Experimental results show that the proposed approach has a greater capability of extending the network lifetime while maintaining a short transmission delay when compared with the protocol which does not consider the application constraints in target tracking sensor networks.

  9. Hierarchical modeling and analysis for spatial data

    CERN Document Server

    Banerjee, Sudipto; Gelfand, Alan E

    2003-01-01

    Among the many uses of hierarchical modeling, their application to the statistical analysis of spatial and spatio-temporal data from areas such as epidemiology And environmental science has proven particularly fruitful. Yet to date, the few books that address the subject have been either too narrowly focused on specific aspects of spatial analysis, or written at a level often inaccessible to those lacking a strong background in mathematical statistics.Hierarchical Modeling and Analysis for Spatial Data is the first accessible, self-contained treatment of hierarchical methods, modeling, and dat

  10. Energy Trading and Pricing in Microgrids with Uncertain Energy Supply: A Three-Stage Hierarchical Game Approach

    Directory of Open Access Journals (Sweden)

    Kai Ma

    2017-05-01

    Full Text Available This paper studies an energy trading and pricing problem for microgrids with uncertain energy supply. The energy provider with the renewable energy (RE generation (wind power determines the energy purchase from the electricity markets and the pricing strategy for consumers to maximize its profit, and then the consumers determine their energy demands to maximize their payoffs. The hierarchical game is established between the energy provider and the consumers. The energy provider is the leader and the consumers are the followers in the hierarchical game. We consider two types of consumers according to their response to the price, i.e., the price-taking consumers and the price-anticipating consumers. We derive the equilibrium point of the hierarchical game through the backward induction method. Comparing the two types of consumers, we study the influence of the types of consumers on the equilibrium point. In particular, the uncertainty of the energy supply from the energy provider is considered. Simulation results show that the energy provider can obtain more profit using the proposed decision-making scheme.

  11. Hierarchical organization versus self-organization

    OpenAIRE

    Busseniers, Evo

    2014-01-01

    In this paper we try to define the difference between hierarchical organization and self-organization. Organization is defined as a structure with a function. So we can define the difference between hierarchical organization and self-organization both on the structure as on the function. In the next two chapters these two definitions are given. For the structure we will use some existing definitions in graph theory, for the function we will use existing theory on (self-)organization. In the t...

  12. A bio-inspired N-doped porous carbon electrocatalyst with hierarchical superstructure for efficient oxygen reduction reaction

    Science.gov (United States)

    Miao, Yue-E.; Yan, Jiajie; Ouyang, Yue; Lu, Hengyi; Lai, Feili; Wu, Yue; Liu, Tianxi

    2018-06-01

    The bio-inspired hierarchical "grape cluster" superstructure provides an effective integration of one-dimensional carbon nanofibers (CNF) with isolated carbonaceous nanoparticles into three-dimensional (3D) conductive frameworks for efficient electron and mass transfer. Herein, a 3D N-doped porous carbon electrocatalyst consisting of carbon nanofibers with grape-like N-doped hollow carbon particles (CNF@NC) has been prepared through a simple electrospinning strategy combined with in-situ growth and carbonization processes. Such a bio-inspired hierarchically organized conductive network largely facilitates both the mass diffusion and electron transfer during the oxygen reduction reactions (ORR). Therefore, the metal-free CNF@NC catalyst demonstrates superior catalytic activity with an absolute four-electron transfer mechanism, strong methanol tolerance and good long-term stability towards ORR in alkaline media.

  13. Efficiently dense hierarchical graphene based aerogel electrode for supercapacitors

    Science.gov (United States)

    Wang, Xin; Lu, Chengxing; Peng, Huifen; Zhang, Xin; Wang, Zhenkun; Wang, Gongkai

    2016-08-01

    Boosting gravimetric and volumetric capacitances simultaneously at a high rate is still a discrepancy in development of graphene based supercapacitors. We report the preparation of dense hierarchical graphene/activated carbon composite aerogels via a reduction induced self-assembly process coupled with a drying post treatment. The compact and porous structures of composite aerogels could be maintained. The drying post treatment has significant effects on increasing the packing density of aerogels. The introduced activated carbons play the key roles of spacers and bridges, mitigating the restacking of adjacent graphene nanosheets and connecting lateral and vertical graphene nanosheets, respectively. The optimized aerogel with a packing density of 0.67 g cm-3 could deliver maximum gravimetric and volumetric capacitances of 128.2 F g-1 and 85.9 F cm-3, respectively, at a current density of 1 A g-1 in aqueous electrolyte, showing no apparent degradation to the specific capacitance at a current density of 10 A g-1 after 20000 cycles. The corresponding gravimetric and volumetric capacitances of 116.6 F g-1 and 78.1 cm-3 with an acceptable cyclic stability are also achieved in ionic liquid electrolyte. The results show a feasible strategy of designing dense hierarchical graphene based aerogels for supercapacitors.

  14. LSTM-Based Hierarchical Denoising Network for Android Malware Detection

    Directory of Open Access Journals (Sweden)

    Jinpei Yan

    2018-01-01

    Full Text Available Mobile security is an important issue on Android platform. Most malware detection methods based on machine learning models heavily rely on expert knowledge for manual feature engineering, which are still difficult to fully describe malwares. In this paper, we present LSTM-based hierarchical denoise network (HDN, a novel static Android malware detection method which uses LSTM to directly learn from the raw opcode sequences extracted from decompiled Android files. However, most opcode sequences are too long for LSTM to train due to the gradient vanishing problem. Hence, HDN uses a hierarchical structure, whose first-level LSTM parallelly computes on opcode subsequences (we called them method blocks to learn the dense representations; then the second-level LSTM can learn and detect malware through method block sequences. Considering that malicious behavior only appears in partial sequence segments, HDN uses method block denoise module (MBDM for data denoising by adaptive gradient scaling strategy based on loss cache. We evaluate and compare HDN with the latest mainstream researches on three datasets. The results show that HDN outperforms these Android malware detection methods,and it is able to capture longer sequence features and has better detection efficiency than N-gram-based malware detection which is similar to our method.

  15. Business strategy versus human resources strategy: the influence of the founder in small business

    Directory of Open Access Journals (Sweden)

    Juliana Popp Barbosa Lima

    2016-12-01

    Full Text Available Small and medium-sized businesses with familiar characteristics have been object of study in recent years, especially about the succession process, considering it is extremely critical to the longevity and sustainability of the organization. However, the figure of the founder and its impact in these organizations is less explored in academia. Thus, this article seeks to fill this gap, addressing the influences of the founder in the dissemination of business and HR strategies in these companies. Through a qualitative and quantitative research, there was a case of a single organization study seeking further analysis of the subject. The collection of qualitative data was given through an interview with semi-structured interview with the founder of the organization and the qualitative by applying a questionnaire with closed questions with officials of various hierarchical levels. It was observed that the personal values and the founding principles are permeated the organization, reflected in the mission and values of the company, as well as how the founder treats topics such as business strategy and the role of people management are decisive for inclusion and driving these topics within family-based organizations. The purpose of analyzing the spread of business strategies and human resources of the Founder has been reached. It was found that, in general, strategies portray the way of the Founder, however, the spread of these to the various hierarchical levels, demonstrates a more complex, as in the HRM.

  16. Deliberate change without hierarchical influence?

    DEFF Research Database (Denmark)

    Nørskov, Sladjana; Kesting, Peter; Ulhøi, John Parm

    2017-01-01

    reveals that deliberate change is indeed achievable in a non-hierarchical collaborative OSS community context. However, it presupposes the presence and active involvement of informal change agents. The paper identifies and specifies four key drivers for change agents’ influence. Originality....../value The findings contribute to organisational analysis by providing a deeper understanding of the importance of leadership in making deliberate change possible in non-hierarchical settings. It points to the importance of “change-by-conviction”, essentially based on voluntary behaviour. This can open the door...

  17. Multiparty hierarchical quantum-information splitting

    International Nuclear Information System (INIS)

    Wang Xinwen; Zhang Dengyu; Tang Shiqing; Xie Lijun

    2011-01-01

    We propose a scheme for multiparty hierarchical quantum-information splitting (QIS) with a multipartite entangled state, where a boss distributes a secret quantum state to two grades of agents asymmetrically. The agents who belong to different grades have different authorities for recovering the boss's secret. Except for the boss's Bell-state measurement, no nonlocal operation is involved. The presented scheme is also shown to be secure against eavesdropping. Such a hierarchical QIS is expected to find useful applications in the field of modern multipartite quantum cryptography.

  18. Biased trapping issue on weighted hierarchical networks

    Indian Academy of Sciences (India)

    archical networks which are based on the classic scale-free hierarchical networks. ... Weighted hierarchical networks; weight-dependent walks; mean first passage ..... The weighted networks can mimic some real-world natural and social systems to ... the Priority Academic Program Development of Jiangsu Higher Education ...

  19. Probabilistic Inference: Task Dependency and Individual Differences of Probability Weighting Revealed by Hierarchical Bayesian Modeling.

    Science.gov (United States)

    Boos, Moritz; Seer, Caroline; Lange, Florian; Kopp, Bruno

    2016-01-01

    Cognitive determinants of probabilistic inference were examined using hierarchical Bayesian modeling techniques. A classic urn-ball paradigm served as experimental strategy, involving a factorial two (prior probabilities) by two (likelihoods) design. Five computational models of cognitive processes were compared with the observed behavior. Parameter-free Bayesian posterior probabilities and parameter-free base rate neglect provided inadequate models of probabilistic inference. The introduction of distorted subjective probabilities yielded more robust and generalizable results. A general class of (inverted) S-shaped probability weighting functions had been proposed; however, the possibility of large differences in probability distortions not only across experimental conditions, but also across individuals, seems critical for the model's success. It also seems advantageous to consider individual differences in parameters of probability weighting as being sampled from weakly informative prior distributions of individual parameter values. Thus, the results from hierarchical Bayesian modeling converge with previous results in revealing that probability weighting parameters show considerable task dependency and individual differences. Methodologically, this work exemplifies the usefulness of hierarchical Bayesian modeling techniques for cognitive psychology. Theoretically, human probabilistic inference might be best described as the application of individualized strategic policies for Bayesian belief revision.

  20. Probabilistic inference: Task dependency and individual differences of probability weighting revealed by hierarchical Bayesian modelling

    Directory of Open Access Journals (Sweden)

    Moritz eBoos

    2016-05-01

    Full Text Available Cognitive determinants of probabilistic inference were examined using hierarchical Bayesian modelling techniques. A classic urn-ball paradigm served as experimental strategy, involving a factorial two (prior probabilities by two (likelihoods design. Five computational models of cognitive processes were compared with the observed behaviour. Parameter-free Bayesian posterior probabilities and parameter-free base rate neglect provided inadequate models of probabilistic inference. The introduction of distorted subjective probabilities yielded more robust and generalizable results. A general class of (inverted S-shaped probability weighting functions had been proposed; however, the possibility of large differences in probability distortions not only across experimental conditions, but also across individuals, seems critical for the model’s success. It also seems advantageous to consider individual differences in parameters of probability weighting as being sampled from weakly informative prior distributions of individual parameter values. Thus, the results from hierarchical Bayesian modelling converge with previous results in revealing that probability weighting parameters show considerable task dependency and individual differences. Methodologically, this work exemplifies the usefulness of hierarchical Bayesian modelling techniques for cognitive psychology. Theoretically, human probabilistic inference might be best described as the application of individualized strategic policies for Bayesian belief revision.

  1. Methanesulfonic acid-assisted synthesis of N/S co-doped hierarchically porous carbon for high performance supercapacitors

    Science.gov (United States)

    Huo, Silu; Liu, Mingquan; Wu, Linlin; Liu, Mingjie; Xu, Min; Ni, Wei; Yan, Yi-Ming

    2018-05-01

    Nitrogen and sulfur co-doped carbons are considered as electrode materials for high performance supercapacitors, while their further development is still limited by complicated synthesis procedure, unsatisfied structure and low energy density. Developing a simple synthetic strategy to obtain rationally structured carbon materials and high supercapacitor performance is remaining a grand challenge. Herein, we describe the synthesis of nitrogen and sulfur co-doped hierarchical porous carbons as high performance supercapacitors electrode by a methanesulfonic acid-assisted one-step carbonization and activation of the freeze-dried precursors mixture. The as-prepared carbon material not only exhibits ideally hierarchical pores, but also realizes uniform nitrogen and sulfur co-doping. In 6.0 M KOH electrolyte, the material can achieve a high specific capacitance of 272 F g-1 at 1.0 A g-1 and a promising rate performance retaining 172 F g-1 even at 100 A g-1. Moreover, a fabricated symmetric supercapacitor based on as-prepared nitrogen and sulfur co-doped hierarchical porous carbon delivers high energy densities of 12.4 W h kg-1 and 8.0 W h kg-1 in 6.0 M KOH liquid and KOH/PVA solid-state electrolytes, respectively. This work presents a simple and effective methanesulfonic acid-assisted approach for mass production of heteroatomic doping hierarchical porous carbons for future energy storage applications.

  2. Anti-hierarchical evolution of the active galactic nucleus space density in a hierarchical universe

    International Nuclear Information System (INIS)

    Enoki, Motohiro; Ishiyama, Tomoaki; Kobayashi, Masakazu A. R.; Nagashima, Masahiro

    2014-01-01

    Recent observations show that the space density of luminous active galactic nuclei (AGNs) peaks at higher redshifts than that of faint AGNs. This downsizing trend in the AGN evolution seems to be contradictory to the hierarchical structure formation scenario. In this study, we present the AGN space density evolution predicted by a semi-analytic model of galaxy and AGN formation based on the hierarchical structure formation scenario. We demonstrate that our model can reproduce the downsizing trend of the AGN space density evolution. The reason for the downsizing trend in our model is a combination of the cold gas depletion as a consequence of star formation, the gas cooling suppression in massive halos, and the AGN lifetime scaling with the dynamical timescale. We assume that a major merger of galaxies causes a starburst, spheroid formation, and cold gas accretion onto a supermassive black hole (SMBH). We also assume that this cold gas accretion triggers AGN activity. Since the cold gas is mainly depleted by star formation and gas cooling is suppressed in massive dark halos, the amount of cold gas accreted onto SMBHs decreases with cosmic time. Moreover, AGN lifetime increases with cosmic time. Thus, at low redshifts, major mergers do not always lead to luminous AGNs. Because the luminosity of AGNs is correlated with the mass of accreted gas onto SMBHs, the space density of luminous AGNs decreases more quickly than that of faint AGNs. We conclude that the anti-hierarchical evolution of the AGN space density is not contradictory to the hierarchical structure formation scenario.

  3. Anti-hierarchical evolution of the active galactic nucleus space density in a hierarchical universe

    Energy Technology Data Exchange (ETDEWEB)

    Enoki, Motohiro [Faculty of Business Administration, Tokyo Keizai University, Kokubunji, Tokyo 185-8502 (Japan); Ishiyama, Tomoaki [Center for Computational Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577 (Japan); Kobayashi, Masakazu A. R. [Research Center for Space and Cosmic Evolution, Ehime University, Matsuyama, Ehime 790-8577 (Japan); Nagashima, Masahiro, E-mail: enokimt@tku.ac.jp [Faculty of Education, Nagasaki University, Nagasaki, Nagasaki 852-8521 (Japan)

    2014-10-10

    Recent observations show that the space density of luminous active galactic nuclei (AGNs) peaks at higher redshifts than that of faint AGNs. This downsizing trend in the AGN evolution seems to be contradictory to the hierarchical structure formation scenario. In this study, we present the AGN space density evolution predicted by a semi-analytic model of galaxy and AGN formation based on the hierarchical structure formation scenario. We demonstrate that our model can reproduce the downsizing trend of the AGN space density evolution. The reason for the downsizing trend in our model is a combination of the cold gas depletion as a consequence of star formation, the gas cooling suppression in massive halos, and the AGN lifetime scaling with the dynamical timescale. We assume that a major merger of galaxies causes a starburst, spheroid formation, and cold gas accretion onto a supermassive black hole (SMBH). We also assume that this cold gas accretion triggers AGN activity. Since the cold gas is mainly depleted by star formation and gas cooling is suppressed in massive dark halos, the amount of cold gas accreted onto SMBHs decreases with cosmic time. Moreover, AGN lifetime increases with cosmic time. Thus, at low redshifts, major mergers do not always lead to luminous AGNs. Because the luminosity of AGNs is correlated with the mass of accreted gas onto SMBHs, the space density of luminous AGNs decreases more quickly than that of faint AGNs. We conclude that the anti-hierarchical evolution of the AGN space density is not contradictory to the hierarchical structure formation scenario.

  4. Discovering hierarchical structure in normal relational data

    DEFF Research Database (Denmark)

    Schmidt, Mikkel Nørgaard; Herlau, Tue; Mørup, Morten

    2014-01-01

    -parametric generative model for hierarchical clustering of similarity based on multifurcating Gibbs fragmentation trees. This allows us to infer and display the posterior distribution of hierarchical structures that comply with the data. We demonstrate the utility of our method on synthetic data and data of functional...

  5. Chitin/clay microspheres with hierarchical architecture for highly efficient removal of organic dyes.

    Science.gov (United States)

    Xu, Rui; Mao, Jie; Peng, Na; Luo, Xiaogang; Chang, Chunyu

    2018-05-15

    Numerous adsorbents have been reported for efficient removal of dye from water, but the high cost raw materials and complicated fabrication process limit their practical applications. Herein, novel nanocomposite microspheres were fabricated from chitin and clay by a simple thermally induced sol-gel transition. Clay nanosheets were uniformly embedded in a nanofiber weaved chitin microsphere matrix, leading to their hierarchical architecture. Benefiting from this unique structure, microspheres could efficiently remove methylene blue (MB) through a spontaneous physic-sorption process which fit well with pseudo-second-order and Langmuir isotherm models. The maximal values of adsorption capability obtained by calculation and experiment were 152.2 and 156.7 mg g -1 , respectively. Chitin/clay microspheres (CCM2) could remove 99.99% MB from its aqueous solution (10 mg g -1 ) within 20 min. These findings provide insight into a new strategy for fabrication of dye adsorbents with hierarchical structure from low cost raw materials. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Road Network Selection Based on Road Hierarchical Structure Control

    Directory of Open Access Journals (Sweden)

    HE Haiwei

    2015-04-01

    Full Text Available A new road network selection method based on hierarchical structure is studied. Firstly, road network is built as strokes which are then classified into hierarchical collections according to the criteria of betweenness centrality value (BC value. Secondly, the hierarchical structure of the strokes is enhanced using structural characteristic identification technique. Thirdly, the importance calculation model was established according to the relationships among the hierarchical structure of the strokes. Finally, the importance values of strokes are got supported with the model's hierarchical calculation, and with which the road network is selected. Tests are done to verify the advantage of this method by comparing it with other common stroke-oriented methods using three kinds of typical road network data. Comparision of the results show that this method had few need to semantic data, and could eliminate the negative influence of edge strokes caused by the criteria of BC value well. So, it is better to maintain the global hierarchical structure of road network, and suitable to meet with the selection of various kinds of road network at the same time.

  7. Hierarchically Structured Electrospun Fibers

    Directory of Open Access Journals (Sweden)

    Nicole E. Zander

    2013-01-01

    Full Text Available Traditional electrospun nanofibers have a myriad of applications ranging from scaffolds for tissue engineering to components of biosensors and energy harvesting devices. The generally smooth one-dimensional structure of the fibers has stood as a limitation to several interesting novel applications. Control of fiber diameter, porosity and collector geometry will be briefly discussed, as will more traditional methods for controlling fiber morphology and fiber mat architecture. The remainder of the review will focus on new techniques to prepare hierarchically structured fibers. Fibers with hierarchical primary structures—including helical, buckled, and beads-on-a-string fibers, as well as fibers with secondary structures, such as nanopores, nanopillars, nanorods, and internally structured fibers and their applications—will be discussed. These new materials with helical/buckled morphology are expected to possess unique optical and mechanical properties with possible applications for negative refractive index materials, highly stretchable/high-tensile-strength materials, and components in microelectromechanical devices. Core-shell type fibers enable a much wider variety of materials to be electrospun and are expected to be widely applied in the sensing, drug delivery/controlled release fields, and in the encapsulation of live cells for biological applications. Materials with a hierarchical secondary structure are expected to provide new superhydrophobic and self-cleaning materials.

  8. Hierarchical control of electron-transfer

    DEFF Research Database (Denmark)

    Westerhoff, Hans V.; Jensen, Peter Ruhdal; Egger, Louis

    1997-01-01

    In this chapter the role of electron transfer in determining the behaviour of the ATP synthesising enzyme in E. coli is analysed. It is concluded that the latter enzyme lacks control because of special properties of the electron transfer components. These properties range from absence of a strong...... back pressure by the protonmotive force on the rate of electron transfer to hierarchical regulation of the expression of the gens that encode the electron transfer proteins as a response to changes in the bioenergetic properties of the cell.The discussion uses Hierarchical Control Analysis...

  9. Multi-objective hierarchical genetic algorithms for multilevel redundancy allocation optimization

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Ranjan [Department of Aeronautics and Astronautics, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)], E-mail: ranjan.k@ks3.ecs.kyoto-u.ac.jp; Izui, Kazuhiro [Department of Aeronautics and Astronautics, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)], E-mail: izui@prec.kyoto-u.ac.jp; Yoshimura, Masataka [Department of Aeronautics and Astronautics, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)], E-mail: yoshimura@prec.kyoto-u.ac.jp; Nishiwaki, Shinji [Department of Aeronautics and Astronautics, Kyoto University, Yoshida-honmachi, Sakyo-ku, Kyoto 606-8501 (Japan)], E-mail: shinji@prec.kyoto-u.ac.jp

    2009-04-15

    Multilevel redundancy allocation optimization problems (MRAOPs) occur frequently when attempting to maximize the system reliability of a hierarchical system, and almost all complex engineering systems are hierarchical. Despite their practical significance, limited research has been done concerning the solving of simple MRAOPs. These problems are not only NP hard but also involve hierarchical design variables. Genetic algorithms (GAs) have been applied in solving MRAOPs, since they are computationally efficient in solving such problems, unlike exact methods, but their applications has been confined to single-objective formulation of MRAOPs. This paper proposes a multi-objective formulation of MRAOPs and a methodology for solving such problems. In this methodology, a hierarchical GA framework for multi-objective optimization is proposed by introducing hierarchical genotype encoding for design variables. In addition, we implement the proposed approach by integrating the hierarchical genotype encoding scheme with two popular multi-objective genetic algorithms (MOGAs)-the strength Pareto evolutionary genetic algorithm (SPEA2) and the non-dominated sorting genetic algorithm (NSGA-II). In the provided numerical examples, the proposed multi-objective hierarchical approach is applied to solve two hierarchical MRAOPs, a 4- and a 3-level problems. The proposed method is compared with a single-objective optimization method that uses a hierarchical genetic algorithm (HGA), also applied to solve the 3- and 4-level problems. The results show that a multi-objective hierarchical GA (MOHGA) that includes elitism and mechanism for diversity preserving performed better than a single-objective GA that only uses elitism, when solving large-scale MRAOPs. Additionally, the experimental results show that the proposed method with NSGA-II outperformed the proposed method with SPEA2 in finding useful Pareto optimal solution sets.

  10. Multi-objective hierarchical genetic algorithms for multilevel redundancy allocation optimization

    International Nuclear Information System (INIS)

    Kumar, Ranjan; Izui, Kazuhiro; Yoshimura, Masataka; Nishiwaki, Shinji

    2009-01-01

    Multilevel redundancy allocation optimization problems (MRAOPs) occur frequently when attempting to maximize the system reliability of a hierarchical system, and almost all complex engineering systems are hierarchical. Despite their practical significance, limited research has been done concerning the solving of simple MRAOPs. These problems are not only NP hard but also involve hierarchical design variables. Genetic algorithms (GAs) have been applied in solving MRAOPs, since they are computationally efficient in solving such problems, unlike exact methods, but their applications has been confined to single-objective formulation of MRAOPs. This paper proposes a multi-objective formulation of MRAOPs and a methodology for solving such problems. In this methodology, a hierarchical GA framework for multi-objective optimization is proposed by introducing hierarchical genotype encoding for design variables. In addition, we implement the proposed approach by integrating the hierarchical genotype encoding scheme with two popular multi-objective genetic algorithms (MOGAs)-the strength Pareto evolutionary genetic algorithm (SPEA2) and the non-dominated sorting genetic algorithm (NSGA-II). In the provided numerical examples, the proposed multi-objective hierarchical approach is applied to solve two hierarchical MRAOPs, a 4- and a 3-level problems. The proposed method is compared with a single-objective optimization method that uses a hierarchical genetic algorithm (HGA), also applied to solve the 3- and 4-level problems. The results show that a multi-objective hierarchical GA (MOHGA) that includes elitism and mechanism for diversity preserving performed better than a single-objective GA that only uses elitism, when solving large-scale MRAOPs. Additionally, the experimental results show that the proposed method with NSGA-II outperformed the proposed method with SPEA2 in finding useful Pareto optimal solution sets

  11. Hierarchical Neural Regression Models for Customer Churn Prediction

    Directory of Open Access Journals (Sweden)

    Golshan Mohammadi

    2013-01-01

    Full Text Available As customers are the main assets of each industry, customer churn prediction is becoming a major task for companies to remain in competition with competitors. In the literature, the better applicability and efficiency of hierarchical data mining techniques has been reported. This paper considers three hierarchical models by combining four different data mining techniques for churn prediction, which are backpropagation artificial neural networks (ANN, self-organizing maps (SOM, alpha-cut fuzzy c-means (α-FCM, and Cox proportional hazards regression model. The hierarchical models are ANN + ANN + Cox, SOM + ANN + Cox, and α-FCM + ANN + Cox. In particular, the first component of the models aims to cluster data in two churner and nonchurner groups and also filter out unrepresentative data or outliers. Then, the clustered data as the outputs are used to assign customers to churner and nonchurner groups by the second technique. Finally, the correctly classified data are used to create Cox proportional hazards model. To evaluate the performance of the hierarchical models, an Iranian mobile dataset is considered. The experimental results show that the hierarchical models outperform the single Cox regression baseline model in terms of prediction accuracy, Types I and II errors, RMSE, and MAD metrics. In addition, the α-FCM + ANN + Cox model significantly performs better than the two other hierarchical models.

  12. An Active Learning Framework for Hyperspectral Image Classification Using Hierarchical Segmentation

    Science.gov (United States)

    Zhang, Zhou; Pasolli, Edoardo; Crawford, Melba M.; Tilton, James C.

    2015-01-01

    Augmenting spectral data with spatial information for image classification has recently gained significant attention, as classification accuracy can often be improved by extracting spatial information from neighboring pixels. In this paper, we propose a new framework in which active learning (AL) and hierarchical segmentation (HSeg) are combined for spectral-spatial classification of hyperspectral images. The spatial information is extracted from a best segmentation obtained by pruning the HSeg tree using a new supervised strategy. The best segmentation is updated at each iteration of the AL process, thus taking advantage of informative labeled samples provided by the user. The proposed strategy incorporates spatial information in two ways: 1) concatenating the extracted spatial features and the original spectral features into a stacked vector and 2) extending the training set using a self-learning-based semi-supervised learning (SSL) approach. Finally, the two strategies are combined within an AL framework. The proposed framework is validated with two benchmark hyperspectral datasets. Higher classification accuracies are obtained by the proposed framework with respect to five other state-of-the-art spectral-spatial classification approaches. Moreover, the effectiveness of the proposed pruning strategy is also demonstrated relative to the approaches based on a fixed segmentation.

  13. Hierarchical Traces for Reduced NSM Memory Requirements

    Science.gov (United States)

    Dahl, Torbjørn S.

    This paper presents work on using hierarchical long term memory to reduce the memory requirements of nearest sequence memory (NSM) learning, a previously published, instance-based reinforcement learning algorithm. A hierarchical memory representation reduces the memory requirements by allowing traces to share common sub-sequences. We present moderated mechanisms for estimating discounted future rewards and for dealing with hidden state using hierarchical memory. We also present an experimental analysis of how the sub-sequence length affects the memory compression achieved and show that the reduced memory requirements do not effect the speed of learning. Finally, we analyse and discuss the persistence of the sub-sequences independent of specific trace instances.

  14. Hierarchical Compliance Control of a Soft Ankle Rehabilitation Robot Actuated by Pneumatic Muscles

    Directory of Open Access Journals (Sweden)

    Quan Liu

    2017-12-01

    Full Text Available Traditional compliance control of a rehabilitation robot is implemented in task space by using impedance or admittance control algorithms. The soft robot actuated by pneumatic muscle actuators (PMAs is becoming prominent for patients as it enables the compliance being adjusted in each active link, which, however, has not been reported in the literature. This paper proposes a new compliance control method of a soft ankle rehabilitation robot that is driven by four PMAs configured in parallel to enable three degrees of freedom movement of the ankle joint. A new hierarchical compliance control structure, including a low-level compliance adjustment controller in joint space and a high-level admittance controller in task space, is designed. An adaptive compliance control paradigm is further developed by taking into account patient’s active contribution and movement ability during a previous period of time, in order to provide robot assistance only when it is necessarily required. Experiments on healthy and impaired human subjects were conducted to verify the adaptive hierarchical compliance control scheme. The results show that the robot hierarchical compliance can be online adjusted according to the participant’s assessment. The robot reduces its assistance output when participants contribute more and vice versa, thus providing a potentially feasible solution to the patient-in-loop cooperative training strategy.

  15. A novel vehicle dynamics stability control algorithm based on the hierarchical strategy with constrain of nonlinear tyre forces

    Science.gov (United States)

    Li, Liang; Jia, Gang; Chen, Jie; Zhu, Hongjun; Cao, Dongpu; Song, Jian

    2015-08-01

    Direct yaw moment control (DYC), which differentially brakes the wheels to produce a yaw moment for the vehicle stability in a steering process, is an important part of electric stability control system. In this field, most control methods utilise the active brake pressure with a feedback controller to adjust the braked wheel. However, the method might lead to a control delay or overshoot because of the lack of a quantitative project relationship between target values from the upper stability controller to the lower pressure controller. Meanwhile, the stability controller usually ignores the implementing ability of the tyre forces, which might be restrained by the combined-slip dynamics of the tyre. Therefore, a novel control algorithm of DYC based on the hierarchical control strategy is brought forward in this paper. As for the upper controller, a correctional linear quadratic regulator, which not only contains feedback control but also contains feed forward control, is introduced to deduce the object of the stability yaw moment in order to guarantee the yaw rate and side-slip angle stability. As for the medium and lower controller, the quantitative relationship between the vehicle stability object and the target tyre forces of controlled wheels is proposed to achieve smooth control performance based on a combined-slip tyre model. The simulations with the hardware-in-the-loop platform validate that the proposed algorithm can improve the stability of the vehicle effectively.

  16. Hierarchical subtask discovery with non-negative matrix factorization

    CSIR Research Space (South Africa)

    Earle, AC

    2018-04-01

    Full Text Available Hierarchical reinforcement learning methods offer a powerful means of planning flexible behavior in complicated domains. However, learning an appropriate hierarchical decomposition of a domain into subtasks remains a substantial challenge. We...

  17. Hierarchical subtask discovery with non-negative matrix factorization

    CSIR Research Space (South Africa)

    Earle, AC

    2017-08-01

    Full Text Available Hierarchical reinforcement learning methods offer a powerful means of planning flexible behavior in complicated domains. However, learning an appropriate hierarchical decomposition of a domain into subtasks remains a substantial challenge. We...

  18. Statistical Significance for Hierarchical Clustering

    Science.gov (United States)

    Kimes, Patrick K.; Liu, Yufeng; Hayes, D. Neil; Marron, J. S.

    2017-01-01

    Summary Cluster analysis has proved to be an invaluable tool for the exploratory and unsupervised analysis of high dimensional datasets. Among methods for clustering, hierarchical approaches have enjoyed substantial popularity in genomics and other fields for their ability to simultaneously uncover multiple layers of clustering structure. A critical and challenging question in cluster analysis is whether the identified clusters represent important underlying structure or are artifacts of natural sampling variation. Few approaches have been proposed for addressing this problem in the context of hierarchical clustering, for which the problem is further complicated by the natural tree structure of the partition, and the multiplicity of tests required to parse the layers of nested clusters. In this paper, we propose a Monte Carlo based approach for testing statistical significance in hierarchical clustering which addresses these issues. The approach is implemented as a sequential testing procedure guaranteeing control of the family-wise error rate. Theoretical justification is provided for our approach, and its power to detect true clustering structure is illustrated through several simulation studies and applications to two cancer gene expression datasets. PMID:28099990

  19. Hierarchically Nanoporous Bioactive Glasses for High Efficiency Immobilization of Enzymes

    DEFF Research Database (Denmark)

    He, W.; Min, D.D.; Zhang, X.D.

    2014-01-01

    Bioactive glasses with hierarchical nanoporosity and structures have been heavily involved in immobilization of enzymes. Because of meticulous design and ingenious hierarchical nanostructuration of porosities from yeast cell biotemplates, hierarchically nanostructured porous bioactive glasses can...... and products of catalytic reactions can freely diffuse through open mesopores (2–40 nm). The formation mechanism of hierarchically structured porous bioactive glasses, the immobilization mechanism of enzyme and the catalysis mechanism of immobilized enzyme are then discussed. The novel nanostructure...

  20. Three Ways to Link Merge with Hierarchical Concept-Combination

    Directory of Open Access Journals (Sweden)

    Chris Thornton

    2016-11-01

    Full Text Available In the Minimalist Program, language competence is seen to stem from a fundamental ability to construct hierarchical structure, an operation dubbed ‘Merge’. This raises the problem of how to view hierarchical concept-combination. This is a conceptual operation which also builds hierarchical structure. We can conceive of a garden that consists of a lawn and a flower-bed, for example, or a salad consisting of lettuce, fennel and rocket, or a crew consisting of a pilot and engineer. In such cases, concepts are put together in a way that makes one the accommodating element with respect to the others taken in combination. The accommodating element becomes the root of a hierarchical unit. Since this unit is itself a concept, the operation is inherently recursive. Does this mean the mind has two independent systems of hierarchical construction? Or is some form of integration more likely? Following a detailed examination of the operations involved, this paper shows there are three main ways in which Merge might be linked to hierarchical concept-combination. Also examined are the architectural implications that arise in each case.

  1. Hierarchical modeling and its numerical implementation for layered thin elastic structures

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Jin-Rae [Hongik University, Sejong (Korea, Republic of)

    2017-05-15

    Thin elastic structures such as beam- and plate-like structures and laminates are characterized by the small thickness, which lead to classical plate and laminate theories in which the displacement fields through the thickness are assumed linear or higher-order polynomials. These classical theories are either insufficient to represent the complex stress variation through the thickness or may encounter the accuracy-computational cost dilemma. In order to overcome the inherent problem of classical theories, the concept of hierarchical modeling has been emerged. In the hierarchical modeling, the hierarchical models with different model levels are selected and combined within a structure domain, in order to make the modeling error be distributed as uniformly as possible throughout the problem domain. The purpose of current study is to explore the potential of hierarchical modeling for the effective numerical analysis of layered structures such as laminated composite. For this goal, the hierarchical models are constructed and the hierarchical modeling is implemented by selectively adjusting the level of hierarchical models. As well, the major characteristics of hierarchical models are investigated through the numerical experiments.

  2. Design strategies for self-assembly of discrete targets

    International Nuclear Information System (INIS)

    Madge, Jim; Miller, Mark A.

    2015-01-01

    Both biological and artificial self-assembly processes can take place by a range of different schemes, from the successive addition of identical building blocks to hierarchical sequences of intermediates, all the way to the fully addressable limit in which each component is unique. In this paper, we introduce an idealized model of cubic particles with patterned faces that allows self-assembly strategies to be compared and tested. We consider a simple octameric target, starting with the minimal requirements for successful self-assembly and comparing the benefits and limitations of more sophisticated hierarchical and addressable schemes. Simulations are performed using a hybrid dynamical Monte Carlo protocol that allows self-assembling clusters to rearrange internally while still providing Stokes-Einstein-like diffusion of aggregates of different sizes. Our simulations explicitly capture the thermodynamic, dynamic, and steric challenges typically faced by self-assembly processes, including competition between multiple partially completed structures. Self-assembly pathways are extracted from the simulation trajectories by a fully extendable scheme for identifying structural fragments, which are then assembled into history diagrams for successfully completed target structures. For the simple target, a one-component assembly scheme is most efficient and robust overall, but hierarchical and addressable strategies can have an advantage under some conditions if high yield is a priority

  3. Hierarchical surfaces for enhanced self-cleaning applications

    Science.gov (United States)

    Fernández, Ariadna; Francone, Achille; Thamdrup, Lasse H.; Johansson, Alicia; Bilenberg, Brian; Nielsen, Theodor; Guttmann, Markus; Sotomayor Torres, Clivia M.; Kehagias, Nikolaos

    2017-04-01

    In this study we present a flexible and adaptable fabrication method to create complex hierarchical structures over inherently hydrophobic resist materials. We have tested these surfaces for their superhydrophobic behaviour and successfully verified their self-cleaning properties. The followed approach allow us to design and produce superhydrophobic surfaces in a reproducible manner. We have analysed different combination of hierarchical micro-nanostructures for their application to self-cleaning surfaces. A static contact angle value of 170° with a hysteresis of 4° was achieved without the need of any additional chemical treatment on the fabricated hierarchical structures. Dynamic effects were analysed on these surfaces, obtaining a remarkable self-cleaning effect as well as a good robustness over impacting droplets.

  4. Hierarchical Aligned Cluster Analysis for Temporal Clustering of Human Motion.

    Science.gov (United States)

    Zhou, Feng; De la Torre, Fernando; Hodgins, Jessica K

    2013-03-01

    Temporal segmentation of human motion into plausible motion primitives is central to understanding and building computational models of human motion. Several issues contribute to the challenge of discovering motion primitives: the exponential nature of all possible movement combinations, the variability in the temporal scale of human actions, and the complexity of representing articulated motion. We pose the problem of learning motion primitives as one of temporal clustering, and derive an unsupervised hierarchical bottom-up framework called hierarchical aligned cluster analysis (HACA). HACA finds a partition of a given multidimensional time series into m disjoint segments such that each segment belongs to one of k clusters. HACA combines kernel k-means with the generalized dynamic time alignment kernel to cluster time series data. Moreover, it provides a natural framework to find a low-dimensional embedding for time series. HACA is efficiently optimized with a coordinate descent strategy and dynamic programming. Experimental results on motion capture and video data demonstrate the effectiveness of HACA for segmenting complex motions and as a visualization tool. We also compare the performance of HACA to state-of-the-art algorithms for temporal clustering on data of a honey bee dance. The HACA code is available online.

  5. Simultaneous modulation of surface composition, oxygen vacancies and assembly in hierarchical Co3O4 mesoporous nanostructures for lithium storage and electrocatalytic oxygen evolution

    DEFF Research Database (Denmark)

    Sun, Hongyu; Zhao, Yanyan; Mølhave, Kristian

    2017-01-01

    in superior electrochemical properties when used as the anode materials for lithium-ion batteries and as an electrocatalyst for the oxygen evolution reaction. The excellent electrochemical performance is attributed to the synergistic effects of novel hierarchical morphology, crystal structure of the active...... materials, the improvement of intrinsic conductivity and inner surface area induced by the oxygen vacancies. The present strategy not only provides a facile method to assemble novel hierarchical architectures, but also paves a way to control surface structures (chemical composition and crystal defects...

  6. Hierarchical Micro-Nano Coatings by Painting

    Science.gov (United States)

    Kirveslahti, Anna; Korhonen, Tuulia; Suvanto, Mika; Pakkanen, Tapani A.

    2016-03-01

    In this paper, the wettability properties of coatings with hierarchical surface structures and low surface energy were studied. Hierarchically structured coatings were produced by using hydrophobic fumed silica nanoparticles and polytetrafluoroethylene (PTFE) microparticles as additives in polyester (PES) and polyvinyldifluoride (PVDF). These particles created hierarchical micro-nano structures on the paint surfaces and lowered or supported the already low surface energy of the paint. Two standard application techniques for paint application were employed and the presented coatings are suitable for mass production and use in large surface areas. By regulating the particle concentrations, it was possible to modify wettability properties gradually. Highly hydrophobic surfaces were achieved with the highest contact angle of 165∘. Dynamic contact angle measurements were carried out for a set of selected samples and low hysteresis was obtained. Produced coatings possessed long lasting durability in the air and in underwater conditions.

  7. Hierarchical electrode architectures for electrical energy storage & conversion.

    Energy Technology Data Exchange (ETDEWEB)

    Zavadil, Kevin Robert; Missert, Nancy A.; Shelnutt, John Allen; van Swol, Frank B.

    2012-01-01

    The integration and stability of electrocatalytic nanostructures, which represent one level of porosity in a hierarchical structural scheme when combined with a three-dimensional support scaffold, has been studied using a combination of synthetic processes, characterization techniques, and computational methods. Dendritic platinum nanostructures have been covalently linked to common electrode surfaces using a newly developed chemical route; a chemical route equally applicable to a range of metals, oxides, and semiconductive materials. Characterization of the resulting bound nanostructure system confirms successful binding, while electrochemistry and microscopy demonstrate the viability of these electroactive particles. Scanning tunneling microscopy has been used to image and validate the short-term stability of several electrode-bound platinum dendritic sheet structures toward Oswald ripening. Kinetic Monte Carlo methods have been applied to develop an understanding of the stability of the basic nano-scale porous platinum sheets as they transform from an initial dendrite to hole containing sheets. Alternate synthetic strategies were pursued to grow dendritic platinum structures directly onto subunits (graphitic particles) of the electrode scaffold. A two-step photocatalytic seeding process proved successful at generating desirable nano-scale porous structures. Growth in-place is an alternate strategy to the covalent linking of the electrocatalytic nanostructures.

  8. Introduction into Hierarchical Matrices

    KAUST Repository

    Litvinenko, Alexander

    2013-01-01

    Hierarchical matrices allow us to reduce computational storage and cost from cubic to almost linear. This technique can be applied for solving PDEs, integral equations, matrix equations and approximation of large covariance and precision matrices.

  9. Introduction into Hierarchical Matrices

    KAUST Repository

    Litvinenko, Alexander

    2013-12-05

    Hierarchical matrices allow us to reduce computational storage and cost from cubic to almost linear. This technique can be applied for solving PDEs, integral equations, matrix equations and approximation of large covariance and precision matrices.

  10. Hierarchical surfaces for enhanced self-cleaning applications

    International Nuclear Information System (INIS)

    Fernández, Ariadna; Francone, Achille; Sotomayor Torres, Clivia M; Kehagias, Nikolaos; Thamdrup, Lasse H; Johansson, Alicia; Bilenberg, Brian; Nielsen, Theodor; Guttmann, Markus

    2017-01-01

    In this study we present a flexible and adaptable fabrication method to create complex hierarchical structures over inherently hydrophobic resist materials. We have tested these surfaces for their superhydrophobic behaviour and successfully verified their self-cleaning properties. The followed approach allow us to design and produce superhydrophobic surfaces in a reproducible manner. We have analysed different combination of hierarchical micro-nanostructures for their application to self-cleaning surfaces. A static contact angle value of 170° with a hysteresis of 4° was achieved without the need of any additional chemical treatment on the fabricated hierarchical structures. Dynamic effects were analysed on these surfaces, obtaining a remarkable self-cleaning effect as well as a good robustness over impacting droplets. (paper)

  11. Hierarchical processing in the prefrontal cortex in a variety of cognitive domains

    Directory of Open Access Journals (Sweden)

    Hyeon-Ae eJeon

    2014-11-01

    Full Text Available This review scrutinizes several findings on human hierarchical processing within the prefrontal cortex (PFC in diverse cognitive domains. Converging evidence from previous studies has shown that the PFC, specifically Brodmann area (BA 44, may function as the essential region for hierarchical processing across the domains. In language fMRI studies, BA 44 was significantly activated for the hierarchical processing of center-embedded sentences and this pattern of activations was also observed in artificial grammar. The same pattern was observed in the visuo-spatial domain where BA44 was actively involved in the processing of hierarchy for the visual symbol. Musical syntax, which is the rule-based arrangement of musical sets, has also been construed as hierarchical processing as in the language domain such that the activation in BA44 was observed in a chord sequence paradigm. P600 ERP was also engendered during the processing of musical hierarchy. Along with a longstanding idea that a human’s number faculty is developed as a by-product of language faculty, BA44 was closely involved in hierarchical processing in mental arithmetic. This review extended its discussion of hierarchical processing to hierarchical behavior, that is, human action which has been referred to as being hierarchically composed. Several lesion and TMS studies supported the involvement of BA44 for hierarchical processing in the action domain. Lastly, the hierarchical organization of cognitive controls was discussed within the PFC, forming a cascade of top-down hierarchical processes operating along a posterior-to-anterior axis of the lateral PFC including BA44 within the network. It is proposed that PFC is actively involved in different forms of hierarchical processing and specifically BA44 may play an integral role in the process. Taking levels of proficiency and subcortical areas into consideration may provide further insight into the functional role of BA44 for hierarchical

  12. A Cloud-Computing-Based Data Placement Strategy in High-Speed Railway

    Directory of Open Access Journals (Sweden)

    Hanning Wang

    2012-01-01

    Full Text Available As an important component of China’s transportation data sharing system, high-speed railway data sharing is a typical application of data-intensive computing. Currently, most high-speed railway data is shared in cloud computing environment. Thus, there is an urgent need for an effective cloud-computing-based data placement strategy in high-speed railway. In this paper, a new data placement strategy named hierarchical structure data placement strategy is proposed. The proposed method combines the semidefinite programming algorithm with the dynamic interval mapping algorithm. The semi-definite programming algorithm is suitable for the placement of files with various replications, ensuring that different replications of a file are placed on different storage devices, while the dynamic interval mapping algorithm ensures better self-adaptability of the data storage system. A hierarchical data placement strategy is proposed for large-scale networks. In this paper, a new theoretical analysis is provided, which is put in comparison with several other previous data placement approaches, showing the efficacy of the new analysis in several experiments.

  13. Hierarchical Ag mesostructures for single particle SERS substrate

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Minwei, E-mail: xuminwei@xjtu.edu.cn; Zhang, Yin

    2017-01-30

    Highlights: • Hierarchical Ag mesostructures with the size of 250, 360 and 500 nm are synthesized via a seed-mediated approach. • The Ag mesostructures present the tailorable size and highly roughened surfaces. • The average enhancement factors for individual Ag mesostructures were estimated to be as high as 10{sup 6}. - Abstract: Hierarchical Ag mesostructures with highly rough surface morphology have been synthesized at room temperature through a simple seed-mediated approach. Electron microscopy characterizations indicate that the obtained Ag mesostructures exhibit a textured surface morphology with the flower-like architecture. Moreover, the particle size can be tailored easily in the range of 250–500 nm. For the growth process of the hierarchical Ag mesostructures, it is believed that the self-assembly mechanism is more reasonable rather than the epitaxial overgrowth of Ag seed. The oriented attachment of nanoparticles is revealed during the formation of Ag mesostructures. Single particle surface enhanced Raman spectra (sp-SERS) of crystal violet adsorbed on the hierarchical Ag mesostructures were measured. Results reveal that the hierarchical Ag mesostructures can be highly sensitive sp-SERS substrates with good reproducibility. The average enhancement factors for individual Ag mesostructures are estimated to be about 10{sup 6}.

  14. Biomass derived nitrogen-doped hierarchical porous carbon sheets for supercapacitors with high performance.

    Science.gov (United States)

    Wang, Cunjing; Wu, Dapeng; Wang, Hongju; Gao, Zhiyong; Xu, Fang; Jiang, Kai

    2018-08-01

    A facile potassium chloride salt-locking technique combined with hydrothermal treatment on precursors was explored to prepare nitrogen-doped hierarchical porous carbon sheets in air from biomass. Benefiting from the effective synthesis strategy, the as-obtained carbon possesses a unique nitrogen-doped thin carbon sheet structure with abundant hierarchical pores and large specific surface areas of 1459 m 2  g -1 . The doped nitrogen in carbon framework has a positive effect on the electrochemical properties of the electrode material, the thin carbon sheet structure benefits for fast ion transfer, the abundant meso-pores provide convenient channels for rapid charge transportation, large specific surface area and lots of micro-pores guarantee sufficient ion-storage sites. Therefore, applied for supercapacitors, the carbon electrode material exhibits an outstanding specific capacitance of 451 F g -1 at 0.5 A g -1 in a three-electrode system. Moreover, the assembled symmetric supercapacitor based on two identical carbon electrodes also displays high specific capacitance of 309 F g -1 at 0.5 A g -1 , excellent rate capacity and remarkable cycling stability with 99.3% of the initial capacitance retention after 10,000 cycles at 5 A -1 . The synthesis strategy avoids expensive inert gas protection and the use of corrosive KOH and toxic ZnCl 2 activated reagents, representing a promising green route to design advanced carbon electrode materials from biomass for high-capacity supercapacitors. Copyright © 2018. Published by Elsevier Inc.

  15. Analysis hierarchical model for discrete event systems

    Science.gov (United States)

    Ciortea, E. M.

    2015-11-01

    The This paper presents the hierarchical model based on discrete event network for robotic systems. Based on the hierarchical approach, Petri network is analysed as a network of the highest conceptual level and the lowest level of local control. For modelling and control of complex robotic systems using extended Petri nets. Such a system is structured, controlled and analysed in this paper by using Visual Object Net ++ package that is relatively simple and easy to use, and the results are shown as representations easy to interpret. The hierarchical structure of the robotic system is implemented on computers analysed using specialized programs. Implementation of hierarchical model discrete event systems, as a real-time operating system on a computer network connected via a serial bus is possible, where each computer is dedicated to local and Petri model of a subsystem global robotic system. Since Petri models are simplified to apply general computers, analysis, modelling, complex manufacturing systems control can be achieved using Petri nets. Discrete event systems is a pragmatic tool for modelling industrial systems. For system modelling using Petri nets because we have our system where discrete event. To highlight the auxiliary time Petri model using transport stream divided into hierarchical levels and sections are analysed successively. Proposed robotic system simulation using timed Petri, offers the opportunity to view the robotic time. Application of goods or robotic and transmission times obtained by measuring spot is obtained graphics showing the average time for transport activity, using the parameters sets of finished products. individually.

  16. Hierarchical effects on target detection and conflict monitoring

    Science.gov (United States)

    Cao, Bihua; Gao, Feng; Ren, Maofang; Li, Fuhong

    2016-01-01

    Previous neuroimaging studies have demonstrated a hierarchical functional structure of the frontal cortices of the human brain, but the temporal course and the electrophysiological signature of the hierarchical representation remains unaddressed. In the present study, twenty-one volunteers were asked to perform a nested cue-target task, while their scalp potentials were recorded. The results showed that: (1) in comparison with the lower-level hierarchical targets, the higher-level targets elicited a larger N2 component (220–350 ms) at the frontal sites, and a smaller P3 component (350–500 ms) across the frontal and parietal sites; (2) conflict-related negativity (non-target minus target) was greater for the lower-level hierarchy than the higher-level, reflecting a more intensive process of conflict monitoring at the final step of target detection. These results imply that decision making, context updating, and conflict monitoring differ among different hierarchical levels of abstraction. PMID:27561989

  17. Programming with Hierarchical Maps

    DEFF Research Database (Denmark)

    Ørbæk, Peter

    This report desribes the hierarchical maps used as a central data structure in the Corundum framework. We describe its most prominent features, ague for its usefulness and briefly describe some of the software prototypes implemented using the technology....

  18. A test sheet generating algorithm based on intelligent genetic algorithm and hierarchical planning

    Science.gov (United States)

    Gu, Peipei; Niu, Zhendong; Chen, Xuting; Chen, Wei

    2013-03-01

    In recent years, computer-based testing has become an effective method to evaluate students' overall learning progress so that appropriate guiding strategies can be recommended. Research has been done to develop intelligent test assembling systems which can automatically generate test sheets based on given parameters of test items. A good multisubject test sheet depends on not only the quality of the test items but also the construction of the sheet. Effective and efficient construction of test sheets according to multiple subjects and criteria is a challenging problem. In this paper, a multi-subject test sheet generation problem is formulated and a test sheet generating approach based on intelligent genetic algorithm and hierarchical planning (GAHP) is proposed to tackle this problem. The proposed approach utilizes hierarchical planning to simplify the multi-subject testing problem and adopts genetic algorithm to process the layered criteria, enabling the construction of good test sheets according to multiple test item requirements. Experiments are conducted and the results show that the proposed approach is capable of effectively generating multi-subject test sheets that meet specified requirements and achieve good performance.

  19. Hierarchical Porous Structures

    Energy Technology Data Exchange (ETDEWEB)

    Grote, Christopher John [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-06-07

    Materials Design is often at the forefront of technological innovation. While there has always been a push to generate increasingly low density materials, such as aero or hydrogels, more recently the idea of bicontinuous structures has gone more into play. This review will cover some of the methods and applications for generating both porous, and hierarchically porous structures.

  20. Analyzing security protocols in hierarchical networks

    DEFF Research Database (Denmark)

    Zhang, Ye; Nielson, Hanne Riis

    2006-01-01

    Validating security protocols is a well-known hard problem even in a simple setting of a single global network. But a real network often consists of, besides the public-accessed part, several sub-networks and thereby forms a hierarchical structure. In this paper we first present a process calculus...... capturing the characteristics of hierarchical networks and describe the behavior of protocols on such networks. We then develop a static analysis to automate the validation. Finally we demonstrate how the technique can benefit the protocol development and the design of network systems by presenting a series...

  1. Hierarchical Analysis of the Omega Ontology

    Energy Technology Data Exchange (ETDEWEB)

    Joslyn, Cliff A.; Paulson, Patrick R.

    2009-12-01

    Initial delivery for mathematical analysis of the Omega Ontology. We provide an analysis of the hierarchical structure of a version of the Omega Ontology currently in use within the US Government. After providing an initial statistical analysis of the distribution of all link types in the ontology, we then provide a detailed order theoretical analysis of each of the four main hierarchical links present. This order theoretical analysis includes the distribution of components and their properties, their parent/child and multiple inheritance structure, and the distribution of their vertical ranks.

  2. Growth and containment of a hierarchical criminal network

    Science.gov (United States)

    Marshak, Charles Z.; Rombach, M. Puck; Bertozzi, Andrea L.; D'Orsogna, Maria R.

    2016-02-01

    We model the hierarchical evolution of an organized criminal network via antagonistic recruitment and pursuit processes. Within the recruitment phase, a criminal kingpin enlists new members into the network, who in turn seek out other affiliates. New recruits are linked to established criminals according to a probability distribution that depends on the current network structure. At the same time, law enforcement agents attempt to dismantle the growing organization using pursuit strategies that initiate on the lower level nodes and that unfold as self-avoiding random walks. The global details of the organization are unknown to law enforcement, who must explore the hierarchy node by node. We halt the pursuit when certain local criteria of the network are uncovered, encoding if and when an arrest is made; the criminal network is assumed to be eradicated if the kingpin is arrested. We first analyze recruitment and study the large scale properties of the growing network; later we add pursuit and use numerical simulations to study the eradication probability in the case of three pursuit strategies, the time to first eradication, and related costs. Within the context of this model, we find that eradication becomes increasingly costly as the network increases in size and that the optimal way of arresting the kingpin is to intervene at the early stages of network formation. We discuss our results in the context of dark network disruption and their implications on possible law enforcement strategies.

  3. Hierarchical composites: Analysis of damage evolution based on fiber bundle model

    DEFF Research Database (Denmark)

    Mishnaevsky, Leon

    2011-01-01

    A computational model of multiscale composites is developed on the basis of the fiber bundle model with the hierarchical load sharing rule, and employed to study the effect of the microstructures of hierarchical composites on their damage resistance. Two types of hierarchical materials were consi...

  4. Sustainable solid-state strategy to hierarchical core-shell structured Fe 3 O 4 @graphene towards a safer and green sodium ion full battery

    KAUST Repository

    Ding, Xiang

    2017-12-11

    A sustainable solid-state strategy of SPEX milling is developed to coat metal oxide (e.g., Fe3O4) with tunable layers of graphene, and a new hierarchical core-shell structured Fe3O4@graphene composite is constructed. The presented green process can preserve the physicochemical properties of metal (oxide) nanocrystals well while conveniently modifying them with graphene carbon, which is unique from the conventional approaches carried out in the solution followed by high temperature calcinations/carbonization. This strategy is environmental-friendly, cost-effective and feasible to extend for preparing more metal (oxide)-graphene materials readily with controllable layers of graphene. In energy storage applications, as-prepared Fe3O4@graphene only modified with 10 wt% of graphene can show greater capacity of 283 mAh g−1 at 100 mA g−1 with capacity retention of 84% over 100 cycles in sodium battery (vs. 17% of pristine Fe3O4). As an appealing nonflammable anode, a completely new full battery of Fe3O4@graphite/Na2.4Fe1.8(SO4)3 is assembled, and an impressive energy density beyond 300 Wh kgcathode−1 with a high working voltage of 3.2 V is attained. Such kind of green battery comprising from the earth-abundant elements (i.e., Na, Fe, S and O) can demonstrate extremely long cycle ability over 500 cycles and robust rate capability even to 10 C (where 1 C define as 108 mA gcathode−1) which are rarely reported before.

  5. Hierarchical cellular designs for load-bearing biocomposite beams and plates

    International Nuclear Information System (INIS)

    Burgueno, Rigoberto; Quagliata, Mario J.; Mohanty, Amar K.; Mehta, Geeta; Drzal, Lawrence T.; Misra, Manjusri

    2005-01-01

    Scrutiny into the composition of natural, or biological materials convincingly reveals that high material and structural efficiency can be attained, even with moderate-quality constituents, by hierarchical topologies, i.e., successively organized material levels or layers. The present study demonstrates that biologically inspired hierarchical designs can help improve the moderate properties of natural fiber polymer composites or biocomposites and allow them to compete with conventional materials for load-bearing applications. An overview of the mechanics concepts that allow hierarchical designs to achieve higher performance is presented, followed by observation and results from flexural tests on periodic and hierarchical cellular beams and plates made from industrial hemp fibers and unsaturated polyester resin biocomposites. The experimental data is shown to agree well with performance indices predicted by mechanics models. A procedure for the multi-scale integrated material/structural analysis of hierarchical cellular biocomposite components is presented and its advantages and limitations are discussed

  6. Hierarchically interconnected porous scaffolds for phase change materials with improved thermal conductivity and efficient solar-to-electric energy conversion.

    Science.gov (United States)

    Yang, Jie; Yu, Peng; Tang, Li-Sheng; Bao, Rui-Ying; Liu, Zheng-Ying; Yang, Ming-Bo; Yang, Wei

    2017-11-23

    An ice-templating self-assembly strategy and a vacuum impregnation method were used to fabricate polyethylene glycol (PEG)/hierarchical porous scaffold composite phase change materials (PCMs). Hierarchically interconnected porous scaffolds of boron nitride (BN), with the aid of a small amount of graphene oxide (GO), endow the composite PCMs with high thermal conductivity, excellent shape-stability and efficient solar-to-electric energy conversion. The formation of a three-dimensional (3D) thermally conductive pathway in the composites contributes to improving the thermal conductivity up to 2.36 W m -1 K -1 at a relatively low content of BN (ca. 23 wt%). This work provides a route for thermally conductive and shape-stabilized composite PCMs used as energy storage materials.

  7. Fabrication of Superhydrophobic Surface with Controlled Wetting Property by Hierarchical Particles.

    Science.gov (United States)

    Xu, Jianxiong; Liu, Weiwei; Du, Jingjing; Tang, Zengmin; Xu, Lijian; Li, Na

    2015-04-01

    Hierarchical particles were prepared by synthetically joining appropriately functionalized polystyrene spheres of poly[styrene-co-(3-(4-vinylphenyl)pentane-2,4-dione)] (PS-co-PVPD) nanoparticles and poly(styrene-co-chloromethylstyrene) (PS-co-PCMS) microparticles. The coupling reaction of nucleophilic substitution of pendent β-diketone groups with benzyl chloride was used to form the hierarchical particles. Since the polymeric nanoparticles and microparticles were synthesized by dispersion polymerization and emulsion polymerization, respectively, both the core microparticles and the surface nanoparticles can be different size and chemical composition. By means of changing the size of the PS-co-PVPD surface nanoparticles, a series of hierarchical particles with different scale ratio of the micro/nano surface structure were successfully prepared. Moreover, by employing the PS-co-PVPD microparticles and PS-co-PCMS nanoparticles as building blocks, hierarchical particles with surface nanoaprticles of different composition were made. These as-prepared hierarchical particles were subsequently assembled on glass substrates to form particulate films. Contact angle measurement shows that superhydrophobic surfaces can be obtained and the contact angle of water on the hierarchically structured surface can be adjusted by the scale ratio of the micro/nano surface structure and surface chemical component of hierarchical particles.

  8. Hierarchical multi-scale classification of nearshore aquatic habitats of the Great Lakes: Western Lake Erie

    Science.gov (United States)

    McKenna, J.E.; Castiglione, C.

    2010-01-01

    Classification is a valuable conservation tool for examining natural resource status and problems and is being developed for coastal aquatic habitats. We present an objective, multi-scale hydrospatial framework for nearshore areas of the Great Lakes. The hydrospatial framework consists of spatial units at eight hierarchical scales from the North American Continent to the individual 270-m spatial cell. Characterization of spatial units based on fish abundance and diversity provides a fish-guided classification of aquatic areas at each spatial scale and demonstrates how classifications may be generated from that framework. Those classification units then provide information about habitat, as well as biotic conditions, which can be compared, contrasted, and hierarchically related spatially. Examples within several representative coastal or open water zones of the Western Lake Erie pilot area highlight potential application of this classification system to management problems. This classification system can assist natural resource managers with planning and establishing priorities for aquatic habitat protection, developing rehabilitation strategies, or identifying special management actions.

  9. Discursive Hierarchical Patterning in Law and Management Cases

    Science.gov (United States)

    Lung, Jane

    2008-01-01

    This paper investigates the differences in the discursive patterning of cases in Law and Management. It examines a corpus of 271 Law and Management cases and discusses the kind of information that these two disciplines call for and how discourses are constructed in discursive hierarchical patterns. A discursive hierarchical pattern is a model…

  10. Hierarchical modularity in human brain functional networks

    Directory of Open Access Journals (Sweden)

    David Meunier

    2009-10-01

    Full Text Available The idea that complex systems have a hierarchical modular organization originates in the early 1960s and has recently attracted fresh support from quantitative studies of large scale, real-life networks. Here we investigate the hierarchical modular (or “modules-within-modules” decomposition of human brain functional networks, measured using functional magnetic resonance imaging (fMRI in 18 healthy volunteers under no-task or resting conditions. We used a customized template to extract networks with more than 1800 regional nodes, and we applied a fast algorithm to identify nested modular structure at several hierarchical levels. We used mutual information, 0 < I < 1, to estimate the similarity of community structure of networks in different subjects, and to identify the individual network that is most representative of the group. Results show that human brain functional networks have a hierarchical modular organization with a fair degree of similarity between subjects, I=0.63. The largest 5 modules at the highest level of the hierarchy were medial occipital, lateral occipital, central, parieto-frontal and fronto-temporal systems; occipital modules demonstrated less sub-modular organization than modules comprising regions of multimodal association cortex. Connector nodes and hubs, with a key role in inter-modular connectivity, were also concentrated in association cortical areas. We conclude that methods are available for hierarchical modular decomposition of large numbers of high resolution brain functional networks using computationally expedient algorithms. This could enable future investigations of Simon's original hypothesis that hierarchy or near-decomposability of physical symbol systems is a critical design feature for their fast adaptivity to changing environmental conditions.

  11. Hierarchical Context Modeling for Video Event Recognition.

    Science.gov (United States)

    Wang, Xiaoyang; Ji, Qiang

    2016-10-11

    Current video event recognition research remains largely target-centered. For real-world surveillance videos, targetcentered event recognition faces great challenges due to large intra-class target variation, limited image resolution, and poor detection and tracking results. To mitigate these challenges, we introduced a context-augmented video event recognition approach. Specifically, we explicitly capture different types of contexts from three levels including image level, semantic level, and prior level. At the image level, we introduce two types of contextual features including the appearance context features and interaction context features to capture the appearance of context objects and their interactions with the target objects. At the semantic level, we propose a deep model based on deep Boltzmann machine to learn event object representations and their interactions. At the prior level, we utilize two types of prior-level contexts including scene priming and dynamic cueing. Finally, we introduce a hierarchical context model that systematically integrates the contextual information at different levels. Through the hierarchical context model, contexts at different levels jointly contribute to the event recognition. We evaluate the hierarchical context model for event recognition on benchmark surveillance video datasets. Results show that incorporating contexts in each level can improve event recognition performance, and jointly integrating three levels of contexts through our hierarchical model achieves the best performance.

  12. Bayesian nonparametric hierarchical modeling.

    Science.gov (United States)

    Dunson, David B

    2009-04-01

    In biomedical research, hierarchical models are very widely used to accommodate dependence in multivariate and longitudinal data and for borrowing of information across data from different sources. A primary concern in hierarchical modeling is sensitivity to parametric assumptions, such as linearity and normality of the random effects. Parametric assumptions on latent variable distributions can be challenging to check and are typically unwarranted, given available prior knowledge. This article reviews some recent developments in Bayesian nonparametric methods motivated by complex, multivariate and functional data collected in biomedical studies. The author provides a brief review of flexible parametric approaches relying on finite mixtures and latent class modeling. Dirichlet process mixture models are motivated by the need to generalize these approaches to avoid assuming a fixed finite number of classes. Focusing on an epidemiology application, the author illustrates the practical utility and potential of nonparametric Bayes methods.

  13. Hierarchical species distribution models

    Science.gov (United States)

    Hefley, Trevor J.; Hooten, Mevin B.

    2016-01-01

    Determining the distribution pattern of a species is important to increase scientific knowledge, inform management decisions, and conserve biodiversity. To infer spatial and temporal patterns, species distribution models have been developed for use with many sampling designs and types of data. Recently, it has been shown that count, presence-absence, and presence-only data can be conceptualized as arising from a point process distribution. Therefore, it is important to understand properties of the point process distribution. We examine how the hierarchical species distribution modeling framework has been used to incorporate a wide array of regression and theory-based components while accounting for the data collection process and making use of auxiliary information. The hierarchical modeling framework allows us to demonstrate how several commonly used species distribution models can be derived from the point process distribution, highlight areas of potential overlap between different models, and suggest areas where further research is needed.

  14. Hierarchical silica particles by dynamic multicomponent assembly

    DEFF Research Database (Denmark)

    Wu, Z. W.; Hu, Q. Y.; Pang, J. B.

    2005-01-01

    Abstract: Aerosol-assisted assembly of mesoporous silica particles with hierarchically controllable pore structure has been prepared using cetyltrimethylammonium bromide (CTAB) and poly(propylene oxide) (PPO, H[OCH(CH3)CH2],OH) as co-templates. Addition of the hydrophobic PPO significantly...... influences the delicate hydrophilic-hydrophobic balance in the well-studied CTAB-silicate co-assembling system, resulting in various mesostructures (such as hexagonal, lamellar, and hierarchical structure). The co-assembly of CTAB, silicate clusters, and a low-molecular-weight PPO (average M-n 425) results...... in a uniform lamellar structure, while the use of a high-molecular-weight PPO (average M-n 2000), which is more hydrophobic, leads to the formation of hierarchical pore structure that contains meso-meso or meso-macro pore structure. The role of PPO additives on the mesostructure evolution in the CTAB...

  15. Using Technology to Support Visual Learning Strategies

    Science.gov (United States)

    O'Bannon, Blanche; Puckett, Kathleen; Rakes, Glenda

    2006-01-01

    Visual learning is a strategy for visually representing the structure of information and for representing the ways in which concepts are related. Based on the work of Ausubel, these hierarchical maps facilitate student learning of unfamiliar information in the K-12 classroom. This paper presents the research base for this Type II computer tool, as…

  16. Hollow Carbon Nanopolyhedra for Enhanced Electrocatalysis via Confined Hierarchical Porosity.

    Science.gov (United States)

    Song, Xiaokai; Guo, Linli; Liao, Xuemei; Liu, Jian; Sun, Jianhua; Li, Xiaopeng

    2017-06-01

    A novel strategy for the fabrication of hollow Co and N-codoped carbon nanopolyhedra (H-CoNC) from metal-organic framework (MOF) using in situ evaporation of ZnO nanosphere templates is proposed. The excess Zn supply during the pyrolysis process is found beneficial in terms of high nitrogen (≈9.75 at%), relatively homogenous CoN bonding, and the electrochemically accessible hierarchical porous system. Compared with other reported "solid" CoNC of identical surface areas, the newly developed H-CoNC shows enhanced kinetic current in 0.1 m KOH electrolyte and elevated oxygen reduction reaction (ORR) performance in 6 m KOH. The latter exceeds results obtained with the benchmark 20 wt% Pt/C, which is related to the strong confinement of O 2 molecules in the H-CoNC hierarchical porous system. Furthermore, the H-CoNC displays great tolerance toward the methanol crossover and KSCN poisoning. Finally, the assembled Zn-air batteries with H-CoNC yield a record open circuit potential (1.59 V vs Zn, stabilized at 1.52 V), high power density (331.0 mW cm -2 ), and promising rate performance. This work provides a new guideline for the design of MOF-derived carbon materials, as well as novel insights into spatial confinement effect toward the ORR activity. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. A Model of Dynamic Strategy-Making

    DEFF Research Database (Denmark)

    Andersen, Torben Juul; Hallin, Carina Antonia; Li, Xin

    The organizational capacity to cope with unexpected changes remains a fundamental challenge in strategy as global competition and technological innovation increase environmental uncertainty. Conventional strategy-making is often conceived as a sequential linear process where we see it as a non......-linear interaction between top-down and bottom-up mechanisms dealing with multiple actions taken throughout the organization over time. It is driven by intension but with a flexible balance between centralized (planned) and decentralized (spontaneous) activities. We adopt the principles of complementary Yin......-Yang elements and Zhong Yong balance to explain the time bound interaction between these opposing yet complementary strategy-making mechanisms where tradeoffs and synergies are balanced across hierarchical levels....

  18. Hierarchical classification with a competitive evolutionary neural tree.

    Science.gov (United States)

    Adams, R G.; Butchart, K; Davey, N

    1999-04-01

    A new, dynamic, tree structured network, the Competitive Evolutionary Neural Tree (CENT) is introduced. The network is able to provide a hierarchical classification of unlabelled data sets. The main advantage that the CENT offers over other hierarchical competitive networks is its ability to self determine the number, and structure, of the competitive nodes in the network, without the need for externally set parameters. The network produces stable classificatory structures by halting its growth using locally calculated heuristics. The results of network simulations are presented over a range of data sets, including Anderson's IRIS data set. The CENT network demonstrates its ability to produce a representative hierarchical structure to classify a broad range of data sets.

  19. Direct hierarchical assembly of nanoparticles

    Science.gov (United States)

    Xu, Ting; Zhao, Yue; Thorkelsson, Kari

    2014-07-22

    The present invention provides hierarchical assemblies of a block copolymer, a bifunctional linking compound and a nanoparticle. The block copolymers form one micro-domain and the nanoparticles another micro-domain.

  20. Band structures of two dimensional solid/air hierarchical phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Y.L.; Tian, X.G. [State Key Laboratory for Mechanical Structure Strength and Vibration, Xi' an Jiaotong University, Xi' an 710049 (China); Chen, C.Q., E-mail: chencq@tsinghua.edu.cn [Department of Engineering Mechanics, AML and CNMM, Tsinghua University, Beijing 100084 (China)

    2012-06-15

    The hierarchical phononic crystals to be considered show a two-order 'hierarchical' feature, which consists of square array arranged macroscopic periodic unit cells with each unit cell itself including four sub-units. Propagation of acoustic wave in such two dimensional solid/air phononic crystals is investigated by the finite element method (FEM) with the Bloch theory. Their band structure, wave filtering property, and the physical mechanism responsible for the broadened band gap are explored. The corresponding ordinary phononic crystal without hierarchical feature is used for comparison. Obtained results show that the solid/air hierarchical phononic crystals possess tunable outstanding band gap features, which are favorable for applications such as sound insulation and vibration attenuation.

  1. Automatic Hierarchical Color Image Classification

    Directory of Open Access Journals (Sweden)

    Jing Huang

    2003-02-01

    Full Text Available Organizing images into semantic categories can be extremely useful for content-based image retrieval and image annotation. Grouping images into semantic classes is a difficult problem, however. Image classification attempts to solve this hard problem by using low-level image features. In this paper, we propose a method for hierarchical classification of images via supervised learning. This scheme relies on using a good low-level feature and subsequently performing feature-space reconfiguration using singular value decomposition to reduce noise and dimensionality. We use the training data to obtain a hierarchical classification tree that can be used to categorize new images. Our experimental results suggest that this scheme not only performs better than standard nearest-neighbor techniques, but also has both storage and computational advantages.

  2. Numerically Optimized Uniformly Most Powerful Alphabets for Hierarchical-Decode-and-Forward Two-Way Relaying

    Directory of Open Access Journals (Sweden)

    M. Hekrdla

    2011-01-01

    Full Text Available We address the issue of the parametric performance of the Hierarchical-Decode-and-Forward (HDF strategy in a wireless 2-way relay channel. Promising HDF, representing the concept of wireless network coding, performs well with a pre-coding strategy that requires Channel State Information (CSI on the transceiver side. Assuming a practical case when CSI is available only on the receiver side and the channel conditions do not allow adaptive strategies, the parametrization causes significant HDF performance degradation for some modulation alphabets. Alphabets that are robust to the parametrization (denoted Uniformly Most Powerful (UMP have already been proposed restricting on the class of non-linear multi-dimensional frequency modulations. In this work, we focus on the general design of unrestricted UMP alphabets. We formulate an optimization problem which is solved by standard non-linear convex constrained optimization algorithms, particularly by Nelder-Mead global optimization search, which is further refined by the local interior-pointsmethod.

  3. Hierarchical clustering using correlation metric and spatial continuity constraint

    Science.gov (United States)

    Stork, Christopher L.; Brewer, Luke N.

    2012-10-02

    Large data sets are analyzed by hierarchical clustering using correlation as a similarity measure. This provides results that are superior to those obtained using a Euclidean distance similarity measure. A spatial continuity constraint may be applied in hierarchical clustering analysis of images.

  4. Static and dynamic friction of hierarchical surfaces.

    Science.gov (United States)

    Costagliola, Gianluca; Bosia, Federico; Pugno, Nicola M

    2016-12-01

    Hierarchical structures are very common in nature, but only recently have they been systematically studied in materials science, in order to understand the specific effects they can have on the mechanical properties of various systems. Structural hierarchy provides a way to tune and optimize macroscopic mechanical properties starting from simple base constituents and new materials are nowadays designed exploiting this possibility. This can be true also in the field of tribology. In this paper we study the effect of hierarchical patterned surfaces on the static and dynamic friction coefficients of an elastic material. Our results are obtained by means of numerical simulations using a one-dimensional spring-block model, which has previously been used to investigate various aspects of friction. Despite the simplicity of the model, we highlight some possible mechanisms that explain how hierarchical structures can significantly modify the friction coefficients of a material, providing a means to achieve tunability.

  5. Hierarchical Bayesian Modeling of Fluid-Induced Seismicity

    Science.gov (United States)

    Broccardo, M.; Mignan, A.; Wiemer, S.; Stojadinovic, B.; Giardini, D.

    2017-11-01

    In this study, we present a Bayesian hierarchical framework to model fluid-induced seismicity. The framework is based on a nonhomogeneous Poisson process with a fluid-induced seismicity rate proportional to the rate of injected fluid. The fluid-induced seismicity rate model depends upon a set of physically meaningful parameters and has been validated for six fluid-induced case studies. In line with the vision of hierarchical Bayesian modeling, the rate parameters are considered as random variables. We develop both the Bayesian inference and updating rules, which are used to develop a probabilistic forecasting model. We tested the Basel 2006 fluid-induced seismic case study to prove that the hierarchical Bayesian model offers a suitable framework to coherently encode both epistemic uncertainty and aleatory variability. Moreover, it provides a robust and consistent short-term seismic forecasting model suitable for online risk quantification and mitigation.

  6. Deep hierarchical attention network for video description

    Science.gov (United States)

    Li, Shuohao; Tang, Min; Zhang, Jun

    2018-03-01

    Pairing video to natural language description remains a challenge in computer vision and machine translation. Inspired by image description, which uses an encoder-decoder model for reducing visual scene into a single sentence, we propose a deep hierarchical attention network for video description. The proposed model uses convolutional neural network (CNN) and bidirectional LSTM network as encoders while a hierarchical attention network is used as the decoder. Compared to encoder-decoder models used in video description, the bidirectional LSTM network can capture the temporal structure among video frames. Moreover, the hierarchical attention network has an advantage over single-layer attention network on global context modeling. To make a fair comparison with other methods, we evaluate the proposed architecture with different types of CNN structures and decoders. Experimental results on the standard datasets show that our model has a more superior performance than the state-of-the-art techniques.

  7. Hierarchical structures of correlations networks among Turkey’s exports and imports by currencies

    Science.gov (United States)

    Kocakaplan, Yusuf; Deviren, Bayram; Keskin, Mustafa

    2012-12-01

    We have examined the hierarchical structures of correlations networks among Turkey’s exports and imports by currencies for the 1996-2010 periods, using the concept of a minimal spanning tree (MST) and hierarchical tree (HT) which depend on the concept of ultrametricity. These trees are useful tools for understanding and detecting the global structure, taxonomy and hierarchy in financial markets. We derived a hierarchical organization and build the MSTs and HTs during the 1996-2001 and 2002-2010 periods. The reason for studying two different sub-periods, namely 1996-2001 and 2002-2010, is that the Euro (EUR) came into use in 2001, and some countries have made their exports and imports with Turkey via the EUR since 2002, and in order to test various time-windows and observe temporal evolution. We have carried out bootstrap analysis to associate a value of the statistical reliability to the links of the MSTs and HTs. We have also used the average linkage cluster analysis (ALCA) to observe the cluster structure more clearly. Moreover, we have obtained the bidimensional minimal spanning tree (BMST) due to economic trade being a bidimensional problem. From the structural topologies of these trees, we have identified different clusters of currencies according to their proximity and economic ties. Our results show that some currencies are more important within the network, due to a tighter connection with other currencies. We have also found that the obtained currencies play a key role for Turkey’s exports and imports and have important implications for the design of portfolio and investment strategies.

  8. Constructing hierarchical porous nanospheres for versatile microwave response approaches: the effect of architectural design.

    Science.gov (United States)

    Quan, Bin; Liang, Xiaohui; Yi, Heng; Gong, He; Ji, Guangbin; Chen, Jiabin; Xu, Guoyue; Du, Youwei

    2017-10-24

    Owing to their immense potential in functionalized applications, tremendous interest has been devoted to the design and synthesis of nanostructures. The introduction of sufficient amount of microwaves into the absorbers on the premise that the dissipation capacity is strong enough remains a key challenge. Pursuing a general methodology to overcome the incompatibility is of great importance. There is widespread interest in designing the materials with specific architectures. Herein, the common absorber candidates were chosen to feature the hierarchical porous Fe 3 O 4 @C@Fe 3 O 4 nanospheres. Due to the reduced skin effect (induced by low-conductivity Fe 3 O 4 outer layer), multiple interfacial polarizations and scattering (due to the ternary hierarchical structures and nanoporous inner core) as well as the improved magnetic dissipation ability (because of multiple magnetic components), the material design enabled a promising microwave absorption performance. This study not only illustrates the primary mechanisms for the improved microwave absorption performance but also underscores the potential in designing the particular architectures as a strategy for achieving the compatibility characteristics.

  9. Models and Methods of Aggregating Linguistic Information in Multi-criteria Hierarchical Quality Assessment Systems

    Science.gov (United States)

    Azarnova, T. V.; Titova, I. A.; Barkalov, S. A.

    2018-03-01

    The article presents an algorithm for obtaining an integral assessment of the quality of an organization from the perspective of customers, based on the method of aggregating linguistic information on a multilevel hierarchical system of quality assessment. The algorithm is of a constructive nature, it provides not only the possibility of obtaining an integral evaluation, but also the development of a quality improvement strategy based on the method of linguistic decomposition, which forms the minimum set of areas of work with clients whose quality change will allow obtaining the required level of integrated quality assessment.

  10. An Integrative Model of Dynamic Strategy-Making

    DEFF Research Database (Denmark)

    Andersen, Torben Juul; Hallin, Carina Antonia; Li, Xin

    . We adopt the frame of complementary Yin-Yang elements and Zhong Yong balance to explain the time bound interaction between these opposing yet complementary strategy-making mechanisms where tradeoffs and synergies are balanced across hierarchical levels. The model outlines how the interaction between......The organizational capacity to cope with unexpected changes remains a fundamental challenge in strategy as global competition and technological innovation increase environmental uncertainty. Whereas conventional strategy-making often is conceived as a sequential linear process, we see it as a non......-linear interaction between top-down and bottom-up mechanisms dealing with multiple actions taken throughout the organization over time. It is driven by intension but with a flexible balance between centralized (planned) and decentralized (spontaneous) activities where strategy formulation and implementation interact...

  11. Epitaxial Growth of Hetero-Ln-MOF Hierarchical Single Crystals for Domain- and Orientation-Controlled Multicolor Luminescence 3D Coding Capability.

    Science.gov (United States)

    Pan, Mei; Zhu, Yi-Xuan; Wu, Kai; Chen, Ling; Hou, Ya-Jun; Yin, Shao-Yun; Wang, Hai-Ping; Fan, Ya-Nan; Su, Cheng-Yong

    2017-11-13

    Core-shell or striped heteroatomic lanthanide metal-organic framework hierarchical single crystals were obtained by liquid-phase anisotropic epitaxial growth, maintaining identical periodic organization while simultaneously exhibiting spatially segregated structure. Different types of domain and orientation-controlled multicolor photophysical models are presented, which show either visually distinguishable or visible/near infrared (NIR) emissive colors. This provides a new bottom-up strategy toward the design of hierarchical molecular systems, offering high-throughput and multiplexed luminescence color tunability and readability. The unique capability of combining spectroscopic coding with 3D (three-dimensional) microscale spatial coding is established, providing potential applications in anti-counterfeiting, color barcoding, and other types of integrated and miniaturized optoelectronic materials and devices. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Epitaxial growth of hetero-Ln-MOF hierarchical single crystals for domain- and orientation-controlled multicolor luminescence 3D coding capability

    International Nuclear Information System (INIS)

    Pan, Mei; Zhu, Yi-Xuan; Wu, Kai; Chen, Ling; Hou, Ya-Jun; Yin, Shao-Yun; Wang, Hai-Ping; Fan, Ya-Nan; Su, Cheng-Yong

    2017-01-01

    Core-shell or striped heteroatomic lanthanide metal-organic framework hierarchical single crystals were obtained by liquid-phase anisotropic epitaxial growth, maintaining identical periodic organization while simultaneously exhibiting spatially segregated structure. Different types of domain and orientation-controlled multicolor photophysical models are presented, which show either visually distinguishable or visible/near infrared (NIR) emissive colors. This provides a new bottom-up strategy toward the design of hierarchical molecular systems, offering high-throughput and multiplexed luminescence color tunability and readability. The unique capability of combining spectroscopic coding with 3D (three-dimensional) microscale spatial coding is established, providing potential applications in anti-counterfeiting, color barcoding, and other types of integrated and miniaturized optoelectronic materials and devices. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  13. Epitaxial growth of hetero-Ln-MOF hierarchical single crystals for domain- and orientation-controlled multicolor luminescence 3D coding capability

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Mei; Zhu, Yi-Xuan; Wu, Kai; Chen, Ling; Hou, Ya-Jun; Yin, Shao-Yun; Wang, Hai-Ping; Fan, Ya-Nan [MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou (China); Su, Cheng-Yong [MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-Sen University, Guangzhou (China); State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou (China)

    2017-11-13

    Core-shell or striped heteroatomic lanthanide metal-organic framework hierarchical single crystals were obtained by liquid-phase anisotropic epitaxial growth, maintaining identical periodic organization while simultaneously exhibiting spatially segregated structure. Different types of domain and orientation-controlled multicolor photophysical models are presented, which show either visually distinguishable or visible/near infrared (NIR) emissive colors. This provides a new bottom-up strategy toward the design of hierarchical molecular systems, offering high-throughput and multiplexed luminescence color tunability and readability. The unique capability of combining spectroscopic coding with 3D (three-dimensional) microscale spatial coding is established, providing potential applications in anti-counterfeiting, color barcoding, and other types of integrated and miniaturized optoelectronic materials and devices. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Hierarchical Sets: Analyzing Pangenome Structure through Scalable Set Visualizations

    DEFF Research Database (Denmark)

    Pedersen, Thomas Lin

    2017-01-01

    of hierarchical sets by applying it to a pangenome based on 113 Escherichia and Shigella genomes and find it provides a powerful addition to pangenome analysis. The described clustering algorithm and visualizations are implemented in the hierarchicalSets R package available from CRAN (https...

  15. Exceptionally stable and hierarchically porous self-standing zeolite monolith based on a solution-mediated and solid-state transformation synergistic mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Do, Manh Huy [Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou 310027, Zhejiang (China); College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang (China); Institute of Chemical Technology, Vietnamese Academy of Science and Technology, 01 Mac Dinh Chi, District 1, Ho Chi Minh (Viet Nam); Cheng, Dang-guo, E-mail: dgcheng@zju.edu.cn [College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang (China); Chen, Fengqiu [Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou 310027, Zhejiang (China); College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang (China); Zhan, Xiaoli [College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang (China)

    2015-11-15

    Although many strategies exist for fabricating hierarchical zeolite monolith, it is still challenging to synthesize pure hierarchical zeolite monolith with intracrystalline meso-/macropores and stability suitable for industrial application in a general and efficient process. Here we describe a simple quasi-solid gel crystallization route to prepare hierarchical self-standing ZSM-5 zeolite monolith via the use of Na{sup +} and OH{sup −} as counterions to modify the breaking and remaking of T–O–T (T = Si or Al) bonds. X-ray diffraction (XRD), scanning electron microcopy (SEM), transmission electron microscopy (TEM), laser scan confocal microscopy (LSCM), N{sub 2} adsorption–desorption, mercury porosimetry, solid-state nuclear magnetic resonance (NMR), and compression mechanical testing were applied to elucidate the structure and mechanical stability of the obtained monolith. The self-standing monolith is composed of self-interconnected meso-/macroporous MFI crystals with tunable intracrystalline meso-/macropores and possesses an unusually mechanical stability with a crushing strength of 5.01 MPa. Combined with controllable structure of the defect-free membrane layer on the monolith top, the self-standing zeolite monolith should widen their potential applications. - Highlights: • Hierarchical self-standing MFI zeolite monoliths were synthesized via a facile method. • Na{sup +} and OH{sup −} are used as counterions for breaking and remaking of T–O–T (T = Si or Al) bonds. • Hierarchical self-standing MFI zeolite monoliths result from zeolite crystal intergrowth. • Self-standing zeolite monolith has an excellent mechanical stability with tunable intracrystalline meso-/macropores.

  16. What are hierarchical models and how do we analyze them?

    Science.gov (United States)

    Royle, Andy

    2016-01-01

    In this chapter we provide a basic definition of hierarchical models and introduce the two canonical hierarchical models in this book: site occupancy and N-mixture models. The former is a hierarchical extension of logistic regression and the latter is a hierarchical extension of Poisson regression. We introduce basic concepts of probability modeling and statistical inference including likelihood and Bayesian perspectives. We go through the mechanics of maximizing the likelihood and characterizing the posterior distribution by Markov chain Monte Carlo (MCMC) methods. We give a general perspective on topics such as model selection and assessment of model fit, although we demonstrate these topics in practice in later chapters (especially Chapters 5, 6, 7, and 10 Chapter 5 Chapter 6 Chapter 7 Chapter 10)

  17. Facile synthesis and photocatalytic activity of zinc oxide hierarchical microcrystals

    KAUST Repository

    Xu, Xinjiang

    2013-04-04

    ZnO microcrystals with hierarchical structure have been synthesized by a simple solvothermal approach. The microcrystals were studied by means of X-ray diffraction, transmission electron microscopy, and scanning electron microscopy. Research on the formation mechanism of the hierarchical microstructure shows that the coordination solvent and precursor concentration have considerable influence on the size and morphology of the microstructures. A possible formation mechanism of the hierarchical structure was suggested. Furthermore, the catalytic activity of the ZnO microcrystals was studied by treating low concentration Rhodamine B (RhB) solution under UV light, and research results show the hierarchical microstructures of ZnO display high catalytic activity in photocatalysis, the catalysis process follows first-order reaction kinetics, and the apparent rate constant k = 0.03195 min-1.

  18. A hierarchical classification approach for recognition of low-density (LDPE) and high-density polyethylene (HDPE) in mixed plastic waste based on short-wave infrared (SWIR) hyperspectral imaging

    Science.gov (United States)

    Bonifazi, Giuseppe; Capobianco, Giuseppe; Serranti, Silvia

    2018-06-01

    The aim of this work was to recognize different polymer flakes from mixed plastic waste through an innovative hierarchical classification strategy based on hyperspectral imaging, with particular reference to low density polyethylene (LDPE) and high-density polyethylene (HDPE). A plastic waste composition assessment, including also LDPE and HDPE identification, may help to define optimal recycling strategies for product quality control. Correct handling of plastic waste is essential for its further "sustainable" recovery, maximizing the sorting performance in particular for plastics with similar characteristics as LDPE and HDPE. Five different plastic waste samples were chosen for the investigation: polypropylene (PP), LDPE, HDPE, polystyrene (PS) and polyvinyl chloride (PVC). A calibration dataset was realized utilizing the corresponding virgin polymers. Hyperspectral imaging in the short-wave infrared range (1000-2500 nm) was thus applied to evaluate the different plastic spectral attributes finalized to perform their recognition/classification. After exploring polymer spectral differences by principal component analysis (PCA), a hierarchical partial least squares discriminant analysis (PLS-DA) model was built allowing the five different polymers to be recognized. The proposed methodology, based on hierarchical classification, is very powerful and fast, allowing to recognize the five different polymers in a single step.

  19. Hierarchical decision making for flood risk reduction

    DEFF Research Database (Denmark)

    Custer, Rocco; Nishijima, Kazuyoshi

    2013-01-01

    . In current practice, structures are often optimized individually without considering benefits of having a hierarchy of protection structures. It is here argued, that the joint consideration of hierarchically integrated protection structures is beneficial. A hierarchical decision model is utilized to analyze...... and compare the benefit of large upstream protection structures and local downstream protection structures in regard to epistemic uncertainty parameters. Results suggest that epistemic uncertainty influences the outcome of the decision model and that, depending on the magnitude of epistemic uncertainty...

  20. THE ESSENCE OF STRATEGY DEVELOPMENT COMPANY IN THE INTEGRATED STRUCTURE

    Directory of Open Access Journals (Sweden)

    A. I. Khorev

    2014-01-01

    Full Text Available Summary. In the beginning of the article is defined a rational sequence of the consideration of the nature of the strategy of a company development, included into an integrated structure. Further the article describes the following items separately: "a strategy", "a development of a company", and "an integrational structure", applying them to companies included to the integrated structure; separating them from a strategy of development of an autonomous company. The article defines functions which such strategy must define, taking into consideration the nature of the strategy of the company development, included into an integrated structure. Next, the article defines six steps which describe a sequence of development of the strategy of the company development, included into an integrated structure. The analysis which is defined in the article allows determining a complete definition of essence of the strategy of the company development, included into an integrated structure. The article also defines a place of the strategy of development into the hierarchical structure of the strategies. The strategy of the company development, included into an integrated structure (as well as the strategy of development of an autonomous company -- is a competition strategy, and it separates "strategy of leadership for costs", “differentiation strategy”, and “strategy of focusing for costs”. Also authors are analyzed the strategy of the cost optimization. According to the complex definition of the strategy, and the strategy's place inside the hierarchical structure, the article defines functions which corporate, competitive, and functional strategies execute during the management of companies inside an integrational structure. The article presents characteristics of applied strategic decisions at different levels of all three types of strategies. The article's researches allow companies included to the integrated structure define their place inside the

  1. Ionothermal synthesis of hierarchical BiOBr microspheres for water treatment

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Dieqing [The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, 100 Guilin Road, Shanghai 200231 (China); Department of Chemistry and Institute of Environment, Energy and Sustainability, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong (China); Wen, Meicheng; Jiang, Bo; Li, Guisheng [The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, 100 Guilin Road, Shanghai 200231 (China); Yu, Jimmy C., E-mail: jimyu@cuhk.edu.hk [Department of Chemistry and Institute of Environment, Energy and Sustainability, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong (China)

    2012-04-15

    Graphical abstract: Hierarchical BiOBr microspheres were prepared from a bromine-containing ionic liquid. The material was found effective for removing heavy metals, degrading organic pollutants and killing bacteria. Highlight: Black-Right-Pointing-Pointer Ionothermal synthesis of BiOBr microspheres with hierarchical structure. Black-Right-Pointing-Pointer Efficient mass transfer and excellent light-harvesting ability. Black-Right-Pointing-Pointer Suitable for removing heavy metals and treatment of organic dyes. Black-Right-Pointing-Pointer Remarkable photocatalytic bactericidal property. - Abstract: Bismuth oxybromide (BiOBr) micropsheres with hierarchical morphologies have been fabricated via an ionothermal synthesis route. Ionic liquid acts as a unique soft material capable of promoting nucleation and in situ growth of 3D hierarchical BiOBr mesocrystals without the help of surfactants. The as-prepared BiOBr nanomaterials can effectively remove heavy metal ions and organic dyes from wastewater. They can also kill Micrococcus lylae, a Gram positive bacterium, in water under fluorescent light irradiation. Their high adaptability in water treatment may be ascribed to their hierarchical structure, allowing them high surface to volume ratio, facile species transportation and excellent light-harvesting ability.

  2. Ionothermal synthesis of hierarchical BiOBr microspheres for water treatment

    International Nuclear Information System (INIS)

    Zhang, Dieqing; Wen, Meicheng; Jiang, Bo; Li, Guisheng; Yu, Jimmy C.

    2012-01-01

    Graphical abstract: Hierarchical BiOBr microspheres were prepared from a bromine-containing ionic liquid. The material was found effective for removing heavy metals, degrading organic pollutants and killing bacteria. Highlight: ► Ionothermal synthesis of BiOBr microspheres with hierarchical structure. ► Efficient mass transfer and excellent light-harvesting ability. ► Suitable for removing heavy metals and treatment of organic dyes. ► Remarkable photocatalytic bactericidal property. - Abstract: Bismuth oxybromide (BiOBr) micropsheres with hierarchical morphologies have been fabricated via an ionothermal synthesis route. Ionic liquid acts as a unique soft material capable of promoting nucleation and in situ growth of 3D hierarchical BiOBr mesocrystals without the help of surfactants. The as-prepared BiOBr nanomaterials can effectively remove heavy metal ions and organic dyes from wastewater. They can also kill Micrococcus lylae, a Gram positive bacterium, in water under fluorescent light irradiation. Their high adaptability in water treatment may be ascribed to their hierarchical structure, allowing them high surface to volume ratio, facile species transportation and excellent light-harvesting ability.

  3. BiOCl nanowire with hierarchical structure and its Raman features

    International Nuclear Information System (INIS)

    Tian Ye; Guo Chuanfei; Guo Yanjun; Wang Qi; Liu Qian

    2012-01-01

    BiOCl is a promising V-VI-VII-compound semiconductor with excellent optical and electrical properties, and has great potential applications in photo-catalysis, photoelectric, etc. We successfully synthesize BiOCl nanowire with a hierarchical structure by combining wet etch (top-down) with liquid phase crystal growth (bottom-up) process, opening a novel method to construct ordered bismuth-based nanostructures. The morphology and lattice structures of Bi nanowires, β-Bi 2 O 3 nanowires and BiOCl nanowires with the hierarchical structure are investigated by scanning electron microscope (SEM) and transition electron microscope (TEM). The formation mechanism of such ordered BiOCl hierarchical structure is considered to mainly originate from the highly preferred growth, which is governed by the lattice match between (1 1 0) facet of BiOCl and (2 2 0) or (0 0 2) facet of β-Bi 2 O 3 . A schematic model is also illustrated to depict the formation process of the ordered BiOCl hierarchical structure. In addition, Raman properties of the BiOCl nanowire with the hierarchical structure are investigated deeply.

  4. Dynamic modeling and hierarchical compound control of a novel 2-DOF flexible parallel manipulator with multiple actuation modes

    Science.gov (United States)

    Liang, Dong; Song, Yimin; Sun, Tao; Jin, Xueying

    2018-03-01

    This paper addresses the problem of rigid-flexible coupling dynamic modeling and active control of a novel flexible parallel manipulator (PM) with multiple actuation modes. Firstly, based on the flexible multi-body dynamics theory, the rigid-flexible coupling dynamic model (RFDM) of system is developed by virtue of the augmented Lagrangian multipliers approach. For completeness, the mathematical models of permanent magnet synchronous motor (PMSM) and piezoelectric transducer (PZT) are further established and integrated with the RFDM of mechanical system to formulate the electromechanical coupling dynamic model (ECDM). To achieve the trajectory tracking and vibration suppression, a hierarchical compound control strategy is presented. Within this control strategy, the proportional-differential (PD) feedback controller is employed to realize the trajectory tracking of end-effector, while the strain and strain rate feedback (SSRF) controller is developed to restrain the vibration of the flexible links using PZT. Furthermore, the stability of the control algorithm is demonstrated based on the Lyapunov stability theory. Finally, two simulation case studies are performed to illustrate the effectiveness of the proposed approach. The results indicate that, under the redundant actuation mode, the hierarchical compound control strategy can guarantee the flexible PM achieves singularity-free motion and vibration attenuation within task workspace simultaneously. The systematic methodology proposed in this study can be conveniently extended for the dynamic modeling and efficient controller design of other flexible PMs, especially the emerging ones with multiple actuation modes.

  5. Template-mediated, Hierarchical Engineering of Ordered Mesoporous Films and Powders

    Science.gov (United States)

    Tian, Zheng

    Hierarchical control over pore size, pore topology, and meso/mictrostructure as well as material morphology (e.g., powders, monoliths, thin films) is crucial for meeting diverse materials needs among applications spanning next generation catalysts, sensors, batteries, sorbents, etc. The overarching goal of this thesis is to establish fundamental mechanistic insight enabling new strategies for realizing such hierarchical textural control for carbon materials that is not currently achievable with sacrificial pore formation by 'one-pot' surfactant-based 'soft'-templating or multi-step inorganic 'hard-templating. While 'hard'-templating is often tacitly discounted based upon its perceived complexity, it offers potential for overcoming key 'soft'-templating challenges, including bolstering pore stability, accommodating a more versatile palette of replica precursors, realizing ordered/spanning porosity in the case of porous thin films, simplifying formation of bi-continuous pore topologies, and inducing microstructure control within porous replica materials. In this thesis, we establish strategies for hard-templating of hierarchically porous and structured carbon powders and tunable thin films by both multi-step hard-templating and a new 'one-pot' template-replica precursor co-assembly process. We first develop a nominal hard-templating technique to successfully prepare three-dimensionally ordered mesoporous (3DOm) and 3DOm-supported microporous carbon thin films by exploiting our ability to synthesize and assemble size-tunable silica nanoparticles into scalable, colloidal crystalline thin film templates of tunable mono- to multi-layer thickness. This robust thin film template accommodates liquid and/or vapor-phase infiltration, polymerization, and pyrolysis of various carbon sources without pore contraction and/or collapse upon template sacrifice. The result is robust, flexible 3DOm or 3DOm-supported ultra-thin microporous films that can be transferred by stamp

  6. On Utmost Multiplicity of Hierarchical Stellar Systems

    Directory of Open Access Journals (Sweden)

    Gebrehiwot Y. M.

    2016-12-01

    Full Text Available According to theoretical considerations, multiplicity of hierarchical stellar systems can reach, depending on masses and orbital parameters, several hundred, while observational data confirm the existence of at most septuple (seven-component systems. In this study, we cross-match the stellar systems of very high multiplicity (six and more components in modern catalogues of visual double and multiple stars to find among them the candidates to hierarchical systems. After cross-matching the catalogues of closer binaries (eclipsing, spectroscopic, etc., some of their components were found to be binary/multiple themselves, what increases the system's degree of multiplicity. Optical pairs, known from literature or filtered by the authors, were flagged and excluded from the statistics. We compiled a list of hierarchical systems with potentially very high multiplicity that contains ten objects. Their multiplicity does not exceed 12, and we discuss a number of ways to explain the lack of extremely high multiplicity systems.

  7. Hierarchical capillary adhesion of microcantilevers or hairs

    International Nuclear Information System (INIS)

    Liu Jianlin; Feng Xiqiao; Xia Re; Zhao Hongping

    2007-01-01

    As a result of capillary forces, animal hairs, carbon nanotubes or nanowires of a periodically or randomly distributed array often assemble into hierarchical structures. In this paper, the energy method is adopted to analyse the capillary adhesion of microsized hairs, which are modelled as clamped microcantilevers wetted by liquids. The critical conditions for capillary adhesion of two hairs, three hairs or two bundles of hairs are derived in terms of Young's contact angle, elastic modulus and geometric sizes of the beams. Then, the hierarchical capillary adhesion of hairs is addressed. It is found that for multiple hairs or microcantilevers, the system tends to take a hierarchical structure as a result of the minimization of the total potential energy of the system. The level number of structural hierarchy increases with the increase in the number of hairs if they are sufficiently long. Additionally, we performed experiments to verify our theoretical solutions for the adhesion of microbeams

  8. An adaptive sampling method for variable-fidelity surrogate models using improved hierarchical kriging

    Science.gov (United States)

    Hu, Jiexiang; Zhou, Qi; Jiang, Ping; Shao, Xinyu; Xie, Tingli

    2018-01-01

    Variable-fidelity (VF) modelling methods have been widely used in complex engineering system design to mitigate the computational burden. Building a VF model generally includes two parts: design of experiments and metamodel construction. In this article, an adaptive sampling method based on improved hierarchical kriging (ASM-IHK) is proposed to refine the improved VF model. First, an improved hierarchical kriging model is developed as the metamodel, in which the low-fidelity model is varied through a polynomial response surface function to capture the characteristics of a high-fidelity model. Secondly, to reduce local approximation errors, an active learning strategy based on a sequential sampling method is introduced to make full use of the already required information on the current sampling points and to guide the sampling process of the high-fidelity model. Finally, two numerical examples and the modelling of the aerodynamic coefficient for an aircraft are provided to demonstrate the approximation capability of the proposed approach, as well as three other metamodelling methods and two sequential sampling methods. The results show that ASM-IHK provides a more accurate metamodel at the same simulation cost, which is very important in metamodel-based engineering design problems.

  9. Digested sludge-derived three-dimensional hierarchical porous carbon for high-performance supercapacitor electrode

    Science.gov (United States)

    Zhang, Jia-Jia; Fan, Hao-Xiang; Dai, Xiao-Hu; Yuan, Shi-Jie

    2018-04-01

    Digested sludge, as the main by-product of the sewage sludge anaerobic digestion process, still contains considerable organic compounds. In this protocol, we report a facile method for preparing digested sludge-derived self-doped porous carbon material for high-performance supercapacitor electrodes via a sustainable pyrolysis/activation process. The obtained digested sludge-derived carbon material (HPDSC) exhibits versatile O-, N-doped hierarchical porous framework, high specific surface area (2103.6 m2 g-1) and partial graphitization phase, which can facilitate ion transport, provide more storage sites for electrolyte ions and enhance the conductivity of active electrode materials. The HPDSC-based supercapacitor electrodes show favourable energy storage performance, with a specific capacitance of 245 F g-1 at 1.0 A g-1 in 0.5 M Na2SO4; outstanding cycling stability, with 98.4% capacitance retention after 2000 cycles; and good rate performance (211 F g-1 at 11 A g-1). This work provides a unique self-doped three-dimensional hierarchical porous carbon material with a favourable charge storage capacity and at the same time finds a high value-added and environment-friendly strategy for disposal and recycling of digested sludge.

  10. Advances in Applications of Hierarchical Bayesian Methods with Hydrological Models

    Science.gov (United States)

    Alexander, R. B.; Schwarz, G. E.; Boyer, E. W.

    2017-12-01

    Mechanistic and empirical watershed models are increasingly used to inform water resource decisions. Growing access to historical stream measurements and data from in-situ sensor technologies has increased the need for improved techniques for coupling models with hydrological measurements. Techniques that account for the intrinsic uncertainties of both models and measurements are especially needed. Hierarchical Bayesian methods provide an efficient modeling tool for quantifying model and prediction uncertainties, including those associated with measurements. Hierarchical methods can also be used to explore spatial and temporal variations in model parameters and uncertainties that are informed by hydrological measurements. We used hierarchical Bayesian methods to develop a hybrid (statistical-mechanistic) SPARROW (SPAtially Referenced Regression On Watershed attributes) model of long-term mean annual streamflow across diverse environmental and climatic drainages in 18 U.S. hydrological regions. Our application illustrates the use of a new generation of Bayesian methods that offer more advanced computational efficiencies than the prior generation. Evaluations of the effects of hierarchical (regional) variations in model coefficients and uncertainties on model accuracy indicates improved prediction accuracies (median of 10-50%) but primarily in humid eastern regions, where model uncertainties are one-third of those in arid western regions. Generally moderate regional variability is observed for most hierarchical coefficients. Accounting for measurement and structural uncertainties, using hierarchical state-space techniques, revealed the effects of spatially-heterogeneous, latent hydrological processes in the "localized" drainages between calibration sites; this improved model precision, with only minor changes in regional coefficients. Our study can inform advances in the use of hierarchical methods with hydrological models to improve their integration with stream

  11. Coordinated Control Strategies of VSC-HVDC-Based Wind Power Systems for Low Voltage Ride Through

    Directory of Open Access Journals (Sweden)

    Xinyin Zhang

    2015-07-01

    Full Text Available The Voltage Source Converter-HVDC (VSC-HVDC system applied to wind power generation can solve large scale wind farm grid-connection and long distance transmission problems. However, the low voltage ride through (LVRT of the VSC-HVDC connected wind farm is a key technology issue that must be solved, and it is currently lacking an economic and effective solution. In this paper, a LVRT coordinated control strategy is proposed for the VSC-HVDC-based wind power system. In this strategy, the operation and control of VSC-HVDC and wind farm during the grid fault period is improved. The VSC-HVDC system not only provides reactive power support to the grid, but also effectively maintains the power balance and DC voltage stability by reducing wind-farm power output, without increasing the equipment investment. Correspondingly, to eliminate the influence on permanent magnet synchronous generator (PMSG-based wind turbine (WT systems, a hierarchical control strategy is designed. The speed and validity of the proposed LVRT coordinated control strategy and hierarchical control strategy were verified by MATLAB/Simulink simulations.

  12. A Hierarchical Dispatch Structure for Distribution Network Pricing

    OpenAIRE

    Yuan, Zhao; Hesamzadeh, Mohammad Reza

    2015-01-01

    This paper presents a hierarchical dispatch structure for efficient distribution network pricing. The dispatch coordination problem in the context of hierarchical network operators are addressed. We formulate decentralized generation dispatch into a bilevel optimization problem in which main network operator and the connected distribution network operator optimize their costs in two levels. By using Karush-Kuhn-Tucker conditions and Fortuny-Amat McCarl linearization, the bilevel optimization ...

  13. Hierarchical materials: Background and perspectives

    DEFF Research Database (Denmark)

    2016-01-01

    Hierarchical design draws inspiration from analysis of biological materials and has opened new possibilities for enhancing performance and enabling new functionalities and extraordinary properties. With the development of nanotechnology, the necessary technological requirements for the manufactur...

  14. Hierarchical Planning Methodology for a Supply Chain Management

    Directory of Open Access Journals (Sweden)

    Virna ORTIZ-ARAYA

    2012-01-01

    Full Text Available Hierarchical production planning is a widely utilized methodology for real world capacitated production planning systems with the aim of establishing different decision–making levels of the planning issues on the time horizon considered. This paper presents a hierarchical approach proposed to a company that produces reusable shopping bags in Chile and Perú, to determine the optimal allocation of resources at the tactical level as well as over the most immediate planning horizon to meet customer demands for the next weeks. Starting from an aggregated production planning model, the aggregated decisions are disaggregated into refined decisions in two levels, using a couple of optimization models that impose appropriate constraints to keep coherence of the plan on the production system. The main features of the hierarchical solution approach are presented.

  15. Hierarchical Factoring Based On Image Analysis And Orthoblique Rotations.

    Science.gov (United States)

    Stankov, L

    1979-07-01

    The procedure for hierarchical factoring suggested by Schmid and Leiman (1957) is applied within the framework of image analysis and orthoblique rotational procedures. It is shown that this approach necessarily leads to correlated higher order factors. Also, one can obtain a smaller number of factors than produced by typical hierarchical procedures.

  16. UNSUPERVISED TRANSIENT LIGHT CURVE ANALYSIS VIA HIERARCHICAL BAYESIAN INFERENCE

    International Nuclear Information System (INIS)

    Sanders, N. E.; Soderberg, A. M.; Betancourt, M.

    2015-01-01

    Historically, light curve studies of supernovae (SNe) and other transient classes have focused on individual objects with copious and high signal-to-noise observations. In the nascent era of wide field transient searches, objects with detailed observations are decreasing as a fraction of the overall known SN population, and this strategy sacrifices the majority of the information contained in the data about the underlying population of transients. A population level modeling approach, simultaneously fitting all available observations of objects in a transient sub-class of interest, fully mines the data to infer the properties of the population and avoids certain systematic biases. We present a novel hierarchical Bayesian statistical model for population level modeling of transient light curves, and discuss its implementation using an efficient Hamiltonian Monte Carlo technique. As a test case, we apply this model to the Type IIP SN sample from the Pan-STARRS1 Medium Deep Survey, consisting of 18,837 photometric observations of 76 SNe, corresponding to a joint posterior distribution with 9176 parameters under our model. Our hierarchical model fits provide improved constraints on light curve parameters relevant to the physical properties of their progenitor stars relative to modeling individual light curves alone. Moreover, we directly evaluate the probability for occurrence rates of unseen light curve characteristics from the model hyperparameters, addressing observational biases in survey methodology. We view this modeling framework as an unsupervised machine learning technique with the ability to maximize scientific returns from data to be collected by future wide field transient searches like LSST

  17. UNSUPERVISED TRANSIENT LIGHT CURVE ANALYSIS VIA HIERARCHICAL BAYESIAN INFERENCE

    Energy Technology Data Exchange (ETDEWEB)

    Sanders, N. E.; Soderberg, A. M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Betancourt, M., E-mail: nsanders@cfa.harvard.edu [Department of Statistics, University of Warwick, Coventry CV4 7AL (United Kingdom)

    2015-02-10

    Historically, light curve studies of supernovae (SNe) and other transient classes have focused on individual objects with copious and high signal-to-noise observations. In the nascent era of wide field transient searches, objects with detailed observations are decreasing as a fraction of the overall known SN population, and this strategy sacrifices the majority of the information contained in the data about the underlying population of transients. A population level modeling approach, simultaneously fitting all available observations of objects in a transient sub-class of interest, fully mines the data to infer the properties of the population and avoids certain systematic biases. We present a novel hierarchical Bayesian statistical model for population level modeling of transient light curves, and discuss its implementation using an efficient Hamiltonian Monte Carlo technique. As a test case, we apply this model to the Type IIP SN sample from the Pan-STARRS1 Medium Deep Survey, consisting of 18,837 photometric observations of 76 SNe, corresponding to a joint posterior distribution with 9176 parameters under our model. Our hierarchical model fits provide improved constraints on light curve parameters relevant to the physical properties of their progenitor stars relative to modeling individual light curves alone. Moreover, we directly evaluate the probability for occurrence rates of unseen light curve characteristics from the model hyperparameters, addressing observational biases in survey methodology. We view this modeling framework as an unsupervised machine learning technique with the ability to maximize scientific returns from data to be collected by future wide field transient searches like LSST.

  18. Ultrafast Hierarchical OTDM/WDM Network

    Directory of Open Access Journals (Sweden)

    Hideyuki Sotobayashi

    2003-12-01

    Full Text Available Ultrafast hierarchical OTDM/WDM network is proposed for the future core-network. We review its enabling technologies: C- and L-wavelength-band generation, OTDM-WDM mutual multiplexing format conversions, and ultrafast OTDM wavelengthband conversions.

  19. Facile fabrication of superhydrophobic surfaces with hierarchical structures.

    Science.gov (United States)

    Lee, Eunyoung; Lee, Kun-Hong

    2018-03-06

    Hierarchical structures were fabricated on the surfaces of SUS304 plates using a one-step process of direct microwave irradiation under a carbon dioxide atmosphere. The surface nanostructures were composed of chrome-doped hematite single crystals. Superhydrophobic surfaces with a water contact angle up to 169° were obtained by chemical modification of the hierarchical structures. The samples maintained superhydrophobicity under NaCl solution up to 2 weeks.

  20. Psychological autonomy and hierarchical relatedness as organizers of developmental pathways.

    Science.gov (United States)

    Keller, Heidi

    2016-01-19

    The definition of self and others can be regarded as embodying the two dimensions of autonomy and relatedness. Autonomy and relatedness are two basic human needs and cultural constructs at the same time. This implies that they may be differently defined yet remain equally important. The respective understanding of autonomy and relatedness is socialized during the everyday experiences of daily life routines from birth on. In this paper, two developmental pathways are portrayed that emphasize different conceptions of autonomy and relatedness that are adaptive in two different environmental contexts with very different affordances and constraints. Western middle-class children are socialized towards psychological autonomy, i.e. the primacy of own intentions, wishes, individual preferences and emotions affording a definition of relatedness as psychological negotiable construct. Non-Western subsistence farmer children are socialized towards hierarchical relatedness, i.e. positioning oneself into the hierarchical structure of a communal system affording a definition of autonomy as action oriented, based on responsibility and obligations. Infancy can be regarded as a cultural lens through which to study the different socialization agendas. Parenting strategies that aim at supporting these different socialization goals in German and Euro-American parents on the one hand and Nso farmers from North Western Cameroon on the other hand are described. It is concluded that different pathways need to be considered in order to understand human psychology from a global perspective. © 2015 The Author(s).

  1. Hierarchical traits distances explain grassland Fabaceae species' ecological niches distances

    Science.gov (United States)

    Fort, Florian; Jouany, Claire; Cruz, Pablo

    2015-01-01

    Fabaceae species play a key role in ecosystem functioning through their capacity to fix atmospheric nitrogen via their symbiosis with Rhizobium bacteria. To increase benefits of using Fabaceae in agricultural systems, it is necessary to find ways to evaluate species or genotypes having potential adaptations to sub-optimal growth conditions. We evaluated the relevance of phylogenetic distance, absolute trait distance and hierarchical trait distance for comparing the adaptation of 13 grassland Fabaceae species to different habitats, i.e., ecological niches. We measured a wide range of functional traits (root traits, leaf traits, and whole plant traits) in these species. Species phylogenetic and ecological distances were assessed from a species-level phylogenetic tree and species' ecological indicator values, respectively. We demonstrated that differences in ecological niches between grassland Fabaceae species were related more to their hierarchical trait distances than to their phylogenetic distances. We showed that grassland Fabaceae functional traits tend to converge among species with the same ecological requirements. Species with acquisitive root strategies (thin roots, shallow root systems) are competitive species adapted to non-stressful meadows, while conservative ones (coarse roots, deep root systems) are able to tolerate stressful continental climates. In contrast, acquisitive species appeared to be able to tolerate low soil-P availability, while conservative ones need high P availability. Finally we highlight that traits converge along the ecological gradient, providing the assumption that species with similar root-trait values are better able to coexist, regardless of their phylogenetic distance. PMID:25741353

  2. A hierarchical community occurrence model for North Carolina stream fish

    Science.gov (United States)

    Midway, S.R.; Wagner, Tyler; Tracy, B.H.

    2016-01-01

    The southeastern USA is home to one of the richest—and most imperiled and threatened—freshwater fish assemblages in North America. For many of these rare and threatened species, conservation efforts are often limited by a lack of data. Drawing on a unique and extensive data set spanning over 20 years, we modeled occurrence probabilities of 126 stream fish species sampled throughout North Carolina, many of which occur more broadly in the southeastern USA. Specifically, we developed species-specific occurrence probabilities from hierarchical Bayesian multispecies models that were based on common land use and land cover covariates. We also used index of biotic integrity tolerance classifications as a second level in the model hierarchy; we identify this level as informative for our work, but it is flexible for future model applications. Based on the partial-pooling property of the models, we were able to generate occurrence probabilities for many imperiled and data-poor species in addition to highlighting a considerable amount of occurrence heterogeneity that supports species-specific investigations whenever possible. Our results provide critical species-level information on many threatened and imperiled species as well as information that may assist with re-evaluation of existing management strategies, such as the use of surrogate species. Finally, we highlight the use of a relatively simple hierarchical model that can easily be generalized for similar situations in which conventional models fail to provide reliable estimates for data-poor groups.

  3. Hierarchical traits distances explain grassland Fabaceae species’ ecological niches distances

    Directory of Open Access Journals (Sweden)

    Florian eFort

    2015-02-01

    Full Text Available Fabaceae species play a key role in ecosystem functioning through their capacity to fix atmospheric nitrogen via their symbiosis with Rhizobium bacteria. To increase benefits of using Fabaceae in agricultural systems, it is necessary to find ways to evaluate species or genotypes having potential adaptations to sub-optimal growth conditions. We evaluated the relevance of phylogenetic distance, absolute trait distance and hierarchical trait distance for comparing the adaptation of 13 grassland Fabaceae species to different habitats, i.e. ecological niches. We measured a wide range of functional traits (root traits, leaf traits and whole plant traits in these species. Species phylogenetic and ecological distances were assessed from a species-level phylogenetic tree and species’ ecological indicator values, respectively. We demonstrated that differences in ecological niches between grassland Fabaceae species were related more to their hierarchical trait distances than to their phylogenetic distances. We showed that grassland Fabaceae functional traits tend to converge among species with the same ecological requirements. Species with acquisitive root strategies (thin roots, shallow root systems are competitive species adapted to non-stressful meadows, while conservative ones (coarse roots, deep root systems are able to tolerate stressful continental climates. In contrast, acquisitive species appeared to be able to tolerate low soil-P availability, while conservative ones need high P availability. Finally we highlight that traits converge along the ecological gradient, providing the assumption that species with similar root-trait values are better able to coexist, regardless of their phylogenetic distance.

  4. Hierarchical Multinomial Processing Tree Models: A Latent-Trait Approach

    Science.gov (United States)

    Klauer, Karl Christoph

    2010-01-01

    Multinomial processing tree models are widely used in many areas of psychology. A hierarchical extension of the model class is proposed, using a multivariate normal distribution of person-level parameters with the mean and covariance matrix to be estimated from the data. The hierarchical model allows one to take variability between persons into…

  5. Hierarchically nanostructured hydroxyapatite: hydrothermal synthesis, morphology control, growth mechanism, and biological activity

    Directory of Open Access Journals (Sweden)

    Ma MG

    2012-04-01

    Full Text Available Ming-Guo MaInstitute of Biomass Chemistry and Technology, College of Materials Science and Technology, Beijing Forestry University, Beijing, People's Republic of ChinaAbstract: Hierarchically nanosized hydroxyapatite (HA with flower-like structure assembled from nanosheets consisting of nanorod building blocks was successfully synthesized by using CaCl2, NaH2PO4, and potassium sodium tartrate via a hydrothermal method at 200°C for 24 hours. The effects of heating time and heating temperature on the products were investigated. As a chelating ligand and template molecule, the potassium sodium tartrate plays a key role in the formation of hierarchically nanostructured HA. On the basis of experimental results, a possible mechanism based on soft-template and self-assembly was proposed for the formation and growth of the hierarchically nanostructured HA. Cytotoxicity experiments indicated that the hierarchically nanostructured HA had good biocompatibility. It was shown by in-vitro experiments that mesenchymal stem cells could attach to the hierarchically nanostructured HA after being cultured for 48 hours.Objective: The purpose of this study was to develop facile and effective methods for the synthesis of novel hydroxyapatite (HA with hierarchical nanostructures assembled from independent and discrete nanobuilding blocks.Methods: A simple hydrothermal approach was applied to synthesize HA by using CaCl2, NaH2PO4, and potassium sodium tartrate at 200°C for 24 hours. The cell cytotoxicity of the hierarchically nanostructured HA was tested by MTT (3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide assay.Results: HA displayed the flower-like structure assembled from nanosheets consisting of nanorod building blocks. The potassium sodium tartrate was used as a chelating ligand, inducing the formation and self-assembly of HA nanorods. The heating time and heating temperature influenced the aggregation and morphology of HA. The cell viability did

  6. Bioinspired Hierarchical Alumina-Graphene Oxide-Poly(vinyl alcohol) Artificial Nacre with Optimized Strength and Toughness.

    Science.gov (United States)

    Wang, Jinrong; Qiao, Jinliang; Wang, Jianfeng; Zhu, Ying; Jiang, Lei

    2015-05-06

    Due to hierarchical organization of micro- and nanostructures, natural nacre exhibits extraordinary strength and toughness, and thus provides a superior model for the design and fabrication of high-performance artificial composite materials. Although great progress has been made in constructing layered composites by alternately stacking hard inorganic platelets and soft polymers, the real issue is that the excellent strength of these composites was obtained at the sacrifice of toughness. In this work, inspired by the layered aragonite microplatelets/chitin nanofibers-protein structure of natural nacre, alumina microplatelets-graphene oxide nanosheets-poly(vinyl alcohol) (Al2O3/GO-PVA) artificial nacre is successfully constructed through layer-by-layer bottom-up assembly, in which Al2O3 and GO-PVA act as "bricks" and "mortar", respectively. The artificial nacre has hierarchical "brick-and-mortar" structure and exhibits excellent strength (143 ± 13 MPa) and toughness (9.2 ± 2.7 MJ/m(3)), which are superior to those of natural nacre (80-135 MPa, 1.8 MJ/m(3)). It was demonstrated that the multiscale hierarchical structure of ultrathin GO nanosheets and submicrometer-thick Al2O3 platelets can deal with the conflict between strength and toughness, thus leading to the excellent mechanical properties that cannot be obtained using only one size of platelet. We strongly believe that the work presented here provides a creative strategy for designing and developing new composites with excellent strength and toughness.

  7. MR-AFS: a global hierarchical file-system

    International Nuclear Information System (INIS)

    Reuter, H.

    2000-01-01

    The next generation of fusion experiments will use object-oriented technology creating the need for world wide sharing of an underlying hierarchical file-system. The Andrew file system (AFS) is a well known and widely spread global distributed file-system. Multiple-resident-AFS (MR-AFS) combines the features of AFS with hierarchical storage management systems. Files in MR-AFS therefore may be migrated on secondary storage, such as roboted tape libraries. MR-AFS is in use at IPP for the current experiments and data originating from super-computer applications. Experiences and scalability issues are discussed

  8. Robust Real-Time Music Transcription with a Compositional Hierarchical Model.

    Science.gov (United States)

    Pesek, Matevž; Leonardis, Aleš; Marolt, Matija

    2017-01-01

    The paper presents a new compositional hierarchical model for robust music transcription. Its main features are unsupervised learning of a hierarchical representation of input data, transparency, which enables insights into the learned representation, as well as robustness and speed which make it suitable for real-world and real-time use. The model consists of multiple layers, each composed of a number of parts. The hierarchical nature of the model corresponds well to hierarchical structures in music. The parts in lower layers correspond to low-level concepts (e.g. tone partials), while the parts in higher layers combine lower-level representations into more complex concepts (tones, chords). The layers are learned in an unsupervised manner from music signals. Parts in each layer are compositions of parts from previous layers based on statistical co-occurrences as the driving force of the learning process. In the paper, we present the model's structure and compare it to other hierarchical approaches in the field of music information retrieval. We evaluate the model's performance for the multiple fundamental frequency estimation. Finally, we elaborate on extensions of the model towards other music information retrieval tasks.

  9. Effects of Preschool Intervention Strategies on School Readiness in Kindergarten

    Science.gov (United States)

    Ma, Xin; Nelson, Regena F.; Shen, Jianping; Krenn, Huilan Y.

    2015-01-01

    Using hierarchical linear modeling, the present study aimed to examine whether targeted intervention strategies implemented individually during a preschool program exhibited any short-term and long-term effects on children's school readiness in kindergarten, utilizing data gathered through the Supporting Partnerships to Assure Ready Kids (SPARK)…

  10. Hierarchical wave functions revisited

    International Nuclear Information System (INIS)

    Li Dingping.

    1997-11-01

    We study the hierarchical wave functions on a sphere and on a torus. We simplify some wave functions on a sphere or a torus using the analytic properties of wave functions. The open question, the construction of the wave function for quasi electron excitation on a torus, is also solved in this paper. (author)

  11. Hierarchically nanostructured hydroxyapatite: hydrothermal synthesis, morphology control, growth mechanism, and biological activity

    Science.gov (United States)

    Ma, Ming-Guo

    2012-01-01

    Hierarchically nanosized hydroxyapatite (HA) with flower-like structure assembled from nanosheets consisting of nanorod building blocks was successfully synthesized by using CaCl2, NaH2PO4, and potassium sodium tartrate via a hydrothermal method at 200°C for 24 hours. The effects of heating time and heating temperature on the products were investigated. As a chelating ligand and template molecule, the potassium sodium tartrate plays a key role in the formation of hierarchically nanostructured HA. On the basis of experimental results, a possible mechanism based on soft-template and self-assembly was proposed for the formation and growth of the hierarchically nanostructured HA. Cytotoxicity experiments indicated that the hierarchically nanostructured HA had good biocompatibility. It was shown by in-vitro experiments that mesenchymal stem cells could attach to the hierarchically nanostructured HA after being cultured for 48 hours. Objective The purpose of this study was to develop facile and effective methods for the synthesis of novel hydroxyapatite (HA) with hierarchical nanostructures assembled from independent and discrete nanobuilding blocks. Methods A simple hydrothermal approach was applied to synthesize HA by using CaCl2, NaH2PO4, and potassium sodium tartrate at 200°C for 24 hours. The cell cytotoxicity of the hierarchically nanostructured HA was tested by MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay. Results HA displayed the flower-like structure assembled from nanosheets consisting of nanorod building blocks. The potassium sodium tartrate was used as a chelating ligand, inducing the formation and self-assembly of HA nanorods. The heating time and heating temperature influenced the aggregation and morphology of HA. The cell viability did not decrease with the increasing concentration of hierarchically nanostructured HA added. Conclusion A novel, simple and reliable hydrothermal route had been developed for the synthesis of

  12. Hierarchical partial order ranking

    International Nuclear Information System (INIS)

    Carlsen, Lars

    2008-01-01

    Assessing the potential impact on environmental and human health from the production and use of chemicals or from polluted sites involves a multi-criteria evaluation scheme. A priori several parameters are to address, e.g., production tonnage, specific release scenarios, geographical and site-specific factors in addition to various substance dependent parameters. Further socio-economic factors may be taken into consideration. The number of parameters to be included may well appear to be prohibitive for developing a sensible model. The study introduces hierarchical partial order ranking (HPOR) that remedies this problem. By HPOR the original parameters are initially grouped based on their mutual connection and a set of meta-descriptors is derived representing the ranking corresponding to the single groups of descriptors, respectively. A second partial order ranking is carried out based on the meta-descriptors, the final ranking being disclosed though average ranks. An illustrative example on the prioritisation of polluted sites is given. - Hierarchical partial order ranking of polluted sites has been developed for prioritization based on a large number of parameters

  13. Hierarchical control of a nuclear reactor using uncertain dynamics techniques

    International Nuclear Information System (INIS)

    Rovere, L.A.; Otaduy, P.J.; Brittain, C.R.; Perez, R.B.

    1988-01-01

    Recent advances in the nonlinear optimal control area are opening new possibilities towards its implementation in process control. Algorithms for multivariate control, hierarchical decomposition, parameter tracking, model uncertainties actuator saturation effects and physical limits to state variables can be implemented on the basis of a consistent mathematical formulation. In this paper, good agreement is shown between a centralized and a hierarchical implementation of a controller for a hypothetical nuclear power plant subject to multiple demands. The performance of the hierarchical distributed system in the presence of localized subsystem failures is analyzed. 4 refs., 13 figs

  14. Analytical and numerical studies of creation probabilities of hierarchical trees

    Directory of Open Access Journals (Sweden)

    S.S. Borysov

    2011-03-01

    Full Text Available We consider the creation conditions of diverse hierarchical trees both analytically and numerically. A connection between the probabilities to create hierarchical levels and the probability to associate these levels into a united structure is studied. We argue that a consistent probabilistic picture requires the use of deformed algebra. Our consideration is based on the study of the main types of hierarchical trees, among which both regular and degenerate ones are studied analytically, while the creation probabilities of Fibonacci, scale-free and arbitrary trees are determined numerically.

  15. Hierarchical drivers of reef-fish metacommunity structure.

    Science.gov (United States)

    MacNeil, M Aaron; Graham, Nicholas A J; Polunin, Nicholas V C; Kulbicki, Michel; Galzin, René; Harmelin-Vivien, Mireille; Rushton, Steven P

    2009-01-01

    Coral reefs are highly complex ecological systems, where multiple processes interact across scales in space and time to create assemblages of exceptionally high biodiversity. Despite the increasing frequency of hierarchically structured sampling programs used in coral-reef science, little progress has been made in quantifying the relative importance of processes operating across multiple scales. The vast majority of reef studies are conducted, or at least analyzed, at a single spatial scale, ignoring the implicitly hierarchical structure of the overall system in favor of small-scale experiments or large-scale observations. Here we demonstrate how alpha (mean local number of species), beta diversity (degree of species dissimilarity among local sites), and gamma diversity (overall species richness) vary with spatial scale, and using a hierarchical, information-theoretic approach, we evaluate the relative importance of site-, reef-, and atoll-level processes driving the fish metacommunity structure among 10 atolls in French Polynesia. Process-based models, representing well-established hypotheses about drivers of reef-fish community structure, were assembled into a candidate set of 12 hierarchical linear models. Variation in fish abundance, biomass, and species richness were unevenly distributed among transect, reef, and atoll levels, establishing the relative contribution of variation at these spatial scales to the structure of the metacommunity. Reef-fish biomass, species richness, and the abundance of most functional-groups corresponded primarily with transect-level habitat diversity and atoll-lagoon size, whereas detritivore and grazer abundances were largely correlated with potential covariates of larval dispersal. Our findings show that (1) within-transect and among-atoll factors primarily drive the relationship between alpha and gamma diversity in this reef-fish metacommunity; (2) habitat is the primary correlate with reef-fish metacommunity structure at

  16. Order from the disorder: hierarchical nanostructures self-assembled from the gas phase (Conference Presentation)

    Science.gov (United States)

    Di Fonzo, Fabio

    2017-02-01

    The assembly of nanoscale building blocks in engineered mesostructures is one of the fundamental goals of nanotechnology. Among the various processes developed to date, self-assembly emerges as one of the most promising, since it relays solely on basic physico-chemical forces. Our research is focused on a new type of self-assembly strategy from the gas-phase: Scattered Ballistic Deposition (SBD). SBD arises from the interaction of a supersonic molecular beam with a static gas and enables the growth of quasi-1D hierarchical mesostructures. Overall, they resemble a forest composed of individual, high aspect-ratio, tree-like structures, assembled from amorphous or crystalline nanoparticles. SBD is a general occurring phenomenon and can be obtained with different vapour or cluster sources. In particular, SBD by Pulsed Laser Deposition is a convenient physical vapor technique that allows the generation of supersonic plasma jets from any inorganic material irrespective of melting temperature, preserving even the most complex stoichiometries. One of the advantages of PLD over other vapour deposition techniques is extremely wide operational pressure range, from UHV to ambient pressure. These characteristics allowed us to develop quasi-1D hierarchical nanostructures from different transition metal oxides, semiconductors and metals. The precise control offered by the SBD-PLD technique over material properties at the nanoscale allowed us to fabricate ultra-thin, high efficiency hierarchical porous photonic crystals with Bragg reflectivity up to 85%. In this communication we will discuss the application of these materials to solar energy harvesting and storage, stimuli responsive photonic crystals and smart surfaces with digital control of their wettability behaviour.

  17. Tunable fabrication of hierarchical hybrids via the incorporation of poly(dopamine) functional interlayer

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Ting; Zhao, Xin; Zhang, Junxian; Dong, Jie; Zhang, Qinghua, E-mail: qhzhang@dhu.edu.cn

    2016-04-30

    Highlights: • PS/PDA with well-defined core/shell structures was prepared in aqueous solution. • Au NPs were coated on PS/PDA by in-situ reduction and self-assembly approach. • PS/PDA/Au had homogeneous and dense Au coatings with different shape. • Hierarchical spheres exhibited a well-defined core/shell structure maintaining the spherical morphology. - Abstract: Two kinds of ternary hybrids were prepared by anchoring different shapes and loadings of Au nanoparticles (NPs) on poly(dopamine) (PDA) functionalized polystyrene (PS) microspheres with two different strategies, i.e., in situ reduction and self-assembly approach. PDA coatings were firstly introduced to functionalize the hydrophobic PS surface with sufficient amino and hydroxyl groups, which enhanced the interaction between Au NPs and the polymer spheres. Thus, Au NPs could be easily immobilized onto the surface of the PDA/PS microspheres, and the hierarchical composite microspheres exhibited a well-defined core/shell structure without sacrificing the spherical PS morphology. PS/PDA/Au-R and PS/PDA/Au-A microspheres fabricated by in situ reduction and self-assembly approach showed different distinct Au nano-shell morphology with the corresponding optical, catalytic and electrochemical properties. Field emission scanning electron microscopy and transmission electronic microscopy verified these hierarchical structures with the ultrathin PDA film incorporating between the inner PS core and the outer Au NPs shell. X-ray diffraction and X-ray photoelectron spectroscopy confirmed the presence of PDA and Au layer on the surface of the composite particles. These green and facile methods with mild experimental conditions can extend to fabricate other polymer or inorganic substrates coated by various noble metals.

  18. Resolution of Singularities Introduced by Hierarchical Structure in Deep Neural Networks.

    Science.gov (United States)

    Nitta, Tohru

    2017-10-01

    We present a theoretical analysis of singular points of artificial deep neural networks, resulting in providing deep neural network models having no critical points introduced by a hierarchical structure. It is considered that such deep neural network models have good nature for gradient-based optimization. First, we show that there exist a large number of critical points introduced by a hierarchical structure in deep neural networks as straight lines, depending on the number of hidden layers and the number of hidden neurons. Second, we derive a sufficient condition for deep neural networks having no critical points introduced by a hierarchical structure, which can be applied to general deep neural networks. It is also shown that the existence of critical points introduced by a hierarchical structure is determined by the rank and the regularity of weight matrices for a specific class of deep neural networks. Finally, two kinds of implementation methods of the sufficient conditions to have no critical points are provided. One is a learning algorithm that can avoid critical points introduced by the hierarchical structure during learning (called avoidant learning algorithm). The other is a neural network that does not have some critical points introduced by the hierarchical structure as an inherent property (called avoidant neural network).

  19. Control Strategies for Islanded Microgrid using Enhanced Hierarchical Control Structure with Multiple Current-Loop Damping Schemes

    DEFF Research Database (Denmark)

    Han, Yang; Shen, Pan; Zhao, Xin

    2017-01-01

    In this paper, the modeling, controller design, and stability analysis of the islanded microgrid (MG) using enhanced hierarchical control structure with multiple current loop damping schemes is proposed. The islanded MG is consisted of the parallel-connected voltage source inverters using LCL...... output filters, and the proposed control structure includes: the primary control with additional phase-shift loop, the secondary control for voltage amplitude and frequency restoration, the virtual impedance loops which contains virtual positive- and negative-sequence impedance loops at fundamental...... frequency, and virtual variable harmonic impedance loop at harmonic frequencies, and the inner voltage and current loop controllers. A small-signal model for the primary and secondary controls with additional phase-shift loop is presented, which shows an over-damped feature from eigenvalue analysis...

  20. Hierarchically structured materials for lithium batteries

    International Nuclear Information System (INIS)

    Xiao, Jie; Zheng, Jianming; Li, Xiaolin; Shao, Yuyan; Zhang, Ji-Guang

    2013-01-01

    The lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles, including solely battery powered vehicles, plug-in hybrid electric vehicles, and hybrid electric vehicles. With the increasing demand for devices of high-energy densities (>500 Wh kg −1 ), new energy storage systems, such as lithium–oxygen (Li–O 2 ) batteries and other emerging systems beyond the conventional LIB, have attracted worldwide interest for both transportation and grid energy storage applications in recent years. It is well known that the electrochemical performance of these energy storage systems depends not only on the composition of the materials, but also on the structure of the electrode materials used in the batteries. Although the desired performance characteristics of batteries often have conflicting requirements with the micro/nano-structure of electrodes, hierarchically designed electrodes can be tailored to satisfy these conflicting requirements. This work will review hierarchically structured materials that have been successfully used in LIB and Li–O 2 batteries. Our goal is to elucidate (1) how to realize the full potential of energy materials through the manipulation of morphologies, and (2) how the hierarchical structure benefits the charge transport, promotes the interfacial properties and prolongs the electrode stability and battery lifetime. (paper)

  1. Hierarchical structure of moral stages assessed by a sorting task

    NARCIS (Netherlands)

    Boom, J.; Brugman, D.; Van der Heijden, P.G.M.

    2001-01-01

    Following criticism of Kohlberg’s theory of moral judgment, an empirical re-examination of hierarchical stage structure was desirable. Utilizing Piaget’s concept of reflective abstraction as a basis, the hierarchical stage structure was investigated using a new method. Study participants (553 Dutch

  2. Structural Group-based Auditing of Missing Hierarchical Relationships in UMLS

    Science.gov (United States)

    Chen, Yan; Gu, Huanying(Helen); Perl, Yehoshua; Geller, James

    2009-01-01

    The Metathesaurus of the UMLS was created by integrating various source terminologies. The inter-concept relationships were either integrated into the UMLS from the source terminologies or specially generated. Due to the extensive size and inherent complexity of the Metathesaurus, the accidental omission of some hierarchical relationships was inevitable. We present a recursive procedure which allows a human expert, with the support of an algorithm, to locate missing hierarchical relationships. The procedure starts with a group of concepts with exactly the same (correct) semantic type assignments. It then partitions the concepts, based on child-of hierarchical relationships, into smaller, singly rooted, hierarchically connected subgroups. The auditor only needs to focus on the subgroups with very few concepts and their concepts with semantic type reassignments. The procedure was evaluated by comparing it with a comprehensive manual audit and it exhibits a perfect error recall. PMID:18824248

  3. Japanese Intercultural Communiccative Strategies in Multinational Companies

    OpenAIRE

    大山, 中勝

    1998-01-01

    The purpose of this study is to describe, from a sociolinguistic perspective, major language functions during which Japanese-American communication occurs in multinational companies in the United States. Comparing communication problems across major language functions and research memos, five major themes emerged: (1)foramlity; (2)social hierarchical distinctons; (3)ambiguous communication strategies; (4)consensus making; and (5)language attitudes. This paper also aims to identify the intercu...

  4. Japanese Intercultural Communication Strategies in Multinational Companies

    OpenAIRE

    大山, 中勝

    1997-01-01

    The purpose of this study is to describe, from a sociolinguistic perspective, major language functions during which Japanese-American communication occurs in multinational companies in the United States. Comparing communication problems across major language functions and research memos, five major themes emerged: (1)foramlity; (2)social hierarchical distinctons; (3)ambiguous communication strategies; (4)consensus making; and (5)language attitudes. This paper also aims to identify the intercu...

  5. Hierarchical video summarization based on context clustering

    Science.gov (United States)

    Tseng, Belle L.; Smith, John R.

    2003-11-01

    A personalized video summary is dynamically generated in our video personalization and summarization system based on user preference and usage environment. The three-tier personalization system adopts the server-middleware-client architecture in order to maintain, select, adapt, and deliver rich media content to the user. The server stores the content sources along with their corresponding MPEG-7 metadata descriptions. In this paper, the metadata includes visual semantic annotations and automatic speech transcriptions. Our personalization and summarization engine in the middleware selects the optimal set of desired video segments by matching shot annotations and sentence transcripts with user preferences. Besides finding the desired contents, the objective is to present a coherent summary. There are diverse methods for creating summaries, and we focus on the challenges of generating a hierarchical video summary based on context information. In our summarization algorithm, three inputs are used to generate the hierarchical video summary output. These inputs are (1) MPEG-7 metadata descriptions of the contents in the server, (2) user preference and usage environment declarations from the user client, and (3) context information including MPEG-7 controlled term list and classification scheme. In a video sequence, descriptions and relevance scores are assigned to each shot. Based on these shot descriptions, context clustering is performed to collect consecutively similar shots to correspond to hierarchical scene representations. The context clustering is based on the available context information, and may be derived from domain knowledge or rules engines. Finally, the selection of structured video segments to generate the hierarchical summary efficiently balances between scene representation and shot selection.

  6. Hierarchical matrices algorithms and analysis

    CERN Document Server

    Hackbusch, Wolfgang

    2015-01-01

    This self-contained monograph presents matrix algorithms and their analysis. The new technique enables not only the solution of linear systems but also the approximation of matrix functions, e.g., the matrix exponential. Other applications include the solution of matrix equations, e.g., the Lyapunov or Riccati equation. The required mathematical background can be found in the appendix. The numerical treatment of fully populated large-scale matrices is usually rather costly. However, the technique of hierarchical matrices makes it possible to store matrices and to perform matrix operations approximately with almost linear cost and a controllable degree of approximation error. For important classes of matrices, the computational cost increases only logarithmically with the approximation error. The operations provided include the matrix inversion and LU decomposition. Since large-scale linear algebra problems are standard in scientific computing, the subject of hierarchical matrices is of interest to scientists ...

  7. Biomass-derived nitrogen-doped porous carbons with tailored hierarchical porosity and high specific surface area for high energy and power density supercapacitors

    Science.gov (United States)

    Sun, Junting; Niu, Jin; Liu, Mengyue; Ji, Jing; Dou, Meiling; Wang, Feng

    2018-01-01

    Porous carbon materials with hierarchical structures attract intense interest for the development of high-performance supercapacitors. Herein, we demonstrate a facile and efficient strategy to synthesize nitrogen-doped hierarchically porous carbons with tailored porous structure combined with high specific surface area (SSA), which involves a pre-carbonization and a subsequent carbonization combined with KOH activation of silkworm cocoon precursors. Through adjusting the mass ratio of the activator (KOH) to pre-carbonized precursor in the activation process, the hierarchically porous carbon prepared at the mass ratio of 2 (referred to as NHPC-2) possesses a high defect density and a high SSA of 3386 m2 g-1 as well as the relatively high volumetric proportion of mesopores and macropores (45.5%). As a result, the energy density and power density of the symmetric supercapacitor based on NHPC-2 electrode are as high as 34.41 Wh kg-1 and 31.25 kW kg-1 in organic-solvent electrolyte, and are further improved to 112.1 Wh kg-1 and 23.91 kW kg-1 in ionic-liquid electrolyte.

  8. Multiscale experimental mechanics of hierarchical carbon-based materials.

    Science.gov (United States)

    Espinosa, Horacio D; Filleter, Tobin; Naraghi, Mohammad

    2012-06-05

    Investigation of the mechanics of natural materials, such as spider silk, abalone shells, and bone, has provided great insight into the design of materials that can simultaneously achieve high specific strength and toughness. Research has shown that their emergent mechanical properties are owed in part to their specific self-organization in hierarchical molecular structures, from nanoscale to macroscale, as well as their mixing and bonding. To apply these findings to manmade materials, researchers have devoted significant efforts in developing a fundamental understanding of multiscale mechanics of materials and its application to the design of novel materials with superior mechanical performance. These efforts included the utilization of some of the most promising carbon-based nanomaterials, such as carbon nanotubes, carbon nanofibers, and graphene, together with a variety of matrix materials. At the core of these efforts lies the need to characterize material mechanical behavior across multiple length scales starting from nanoscale characterization of constituents and their interactions to emerging micro- and macroscale properties. In this report, progress made in experimental tools and methods currently used for material characterization across multiple length scales is reviewed, as well as a discussion of how they have impacted our current understanding of the mechanics of hierarchical carbon-based materials. In addition, insight is provided into strategies for bridging experiments across length scales, which are essential in establishing a multiscale characterization approach. While the focus of this progress report is in experimental methods, their concerted use with theoretical-computational approaches towards the establishment of a robust material by design methodology is also discussed, which can pave the way for the development of novel materials possessing unprecedented mechanical properties. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Final Report of Optimization Algorithms for Hierarchical Problems, with Applications to Nanoporous Materials

    Energy Technology Data Exchange (ETDEWEB)

    Nash, Stephen G.

    2013-11-11

    The research focuses on the modeling and optimization of nanoporous materials. In systems with hierarchical structure that we consider, the physics changes as the scale of the problem is reduced and it can be important to account for physics at the fine level to obtain accurate approximations at coarser levels. For example, nanoporous materials hold promise for energy production and storage. A significant issue is the fabrication of channels within these materials to allow rapid diffusion through the material. One goal of our research is to apply optimization methods to the design of nanoporous materials. Such problems are large and challenging, with hierarchical structure that we believe can be exploited, and with a large range of important scales, down to atomistic. This requires research on large-scale optimization for systems that exhibit different physics at different scales, and the development of algorithms applicable to designing nanoporous materials for many important applications in energy production, storage, distribution, and use. Our research has two major research thrusts. The first is hierarchical modeling. We plan to develop and study hierarchical optimization models for nanoporous materials. The models have hierarchical structure, and attempt to balance the conflicting aims of model fidelity and computational tractability. In addition, we analyze the general hierarchical model, as well as the specific application models, to determine their properties, particularly those properties that are relevant to the hierarchical optimization algorithms. The second thrust was to develop, analyze, and implement a class of hierarchical optimization algorithms, and apply them to the hierarchical models we have developed. We adapted and extended the optimization-based multigrid algorithms of Lewis and Nash to the optimization models exemplified by the hierarchical optimization model. This class of multigrid algorithms has been shown to be a powerful tool for

  10. An adaptive map-matching algorithm based on hierarchical fuzzy system from vehicular GPS data.

    Directory of Open Access Journals (Sweden)

    Jinjun Tang

    Full Text Available An improved hierarchical fuzzy inference method based on C-measure map-matching algorithm is proposed in this paper, in which the C-measure represents the certainty or probability of the vehicle traveling on the actual road. A strategy is firstly introduced to use historical positioning information to employ curve-curve matching between vehicle trajectories and shapes of candidate roads. It improves matching performance by overcoming the disadvantage of traditional map-matching algorithm only considering current information. An average historical distance is used to measure similarity between vehicle trajectories and road shape. The input of system includes three variables: distance between position point and candidate roads, angle between driving heading and road direction, and average distance. As the number of fuzzy rules will increase exponentially when adding average distance as a variable, a hierarchical fuzzy inference system is then applied to reduce fuzzy rules and improve the calculation efficiency. Additionally, a learning process is updated to support the algorithm. Finally, a case study contains four different routes in Beijing city is used to validate the effectiveness and superiority of the proposed method.

  11. Organization of excitable dynamics in hierarchical biological networks.

    Directory of Open Access Journals (Sweden)

    Mark Müller-Linow

    Full Text Available This study investigates the contributions of network topology features to the dynamic behavior of hierarchically organized excitable networks. Representatives of different types of hierarchical networks as well as two biological neural networks are explored with a three-state model of node activation for systematically varying levels of random background network stimulation. The results demonstrate that two principal topological aspects of hierarchical networks, node centrality and network modularity, correlate with the network activity patterns at different levels of spontaneous network activation. The approach also shows that the dynamic behavior of the cerebral cortical systems network in the cat is dominated by the network's modular organization, while the activation behavior of the cellular neuronal network of Caenorhabditis elegans is strongly influenced by hub nodes. These findings indicate the interaction of multiple topological features and dynamic states in the function of complex biological networks.

  12. Hierarchical Control for Multiple DC-Microgrids Clusters

    DEFF Research Database (Denmark)

    Shafiee, Qobad; Dragicevic, Tomislav; Vasquez, Juan Carlos

    2014-01-01

    DC microgrids (MGs) have gained research interest during the recent years because of many potential advantages as compared to the ac system. To ensure reliable operation of a low-voltage dc MG as well as its intelligent operation with the other DC MGs, a hierarchical control is proposed in this p......DC microgrids (MGs) have gained research interest during the recent years because of many potential advantages as compared to the ac system. To ensure reliable operation of a low-voltage dc MG as well as its intelligent operation with the other DC MGs, a hierarchical control is proposed...

  13. Bioclimate of Liberec

    OpenAIRE

    Rubáš, Dominik

    2016-01-01

    The diploma thesis provides special studies from the human bioclimatology sector. Ten year sequences (2001-2010) of many meteorological components are processed here. The meteorological components are as follows: average daily air temperature, average daily wind speed, time of sunshine per day, duration of rainfalls, fogs and fumes and also monthly aggregate rainfall. The main study aims attention to evaluation of complex effects of selected elements on humans. The most and the least suitable...

  14. Efficiency of alternative MCMC strategies illustrated using the reaction norm model

    DEFF Research Database (Denmark)

    Shariati, Mohammad Mahdi; Sørensen, D.

    2008-01-01

    The Markov chain Monte Carlo (MCMC) strategy provides remarkable flexibility for fitting complex hierarchical models. However, when parameters are highly correlated in their posterior distributions and their number is large, a particular MCMC algorithm may perform poorly and the resulting...... in the low correlation scenario where SG was the best strategy. The two LH proposals could not compete with any of the Gibbs sampling algorithms. In this study it was not possible to find an MCMC strategy that performs optimally across the range of target distributions and across all possible values...

  15. Multiperiod Hierarchical Location Problem of Transit Hub in Urban Agglomeration Area

    Directory of Open Access Journals (Sweden)

    Ting-ting Li

    2017-01-01

    Full Text Available With the rapid urbanization in developing countries, urban agglomeration area (UAA forms. Also, transportation demand in UAA grows rapidly and presents hierarchical feature. Therefore, it is imperative to develop models for transit hubs to guide the development of UAA and better meet the time-varying and hierarchical transportation demand. In this paper, the multiperiod hierarchical location problem of transit hub in urban agglomeration area (THUAA is studied. A hierarchical service network of THUAA with a multiflow, nested, and noncoherent structure is described. Then a multiperiod hierarchical mathematical programming model is proposed, aiming at minimizing the total demand weighted travel time. Moreover, an improved adaptive clonal selection algorithm is presented to solve the model. Both the model and algorithm are verified by the application to a real-life problem of Beijing-Tianjin-Hebei Region in China. The results of different scenarios in the case show that urban population migration has a great impact on the THUAA location scheme. Sustained and appropriate urban population migration helps to reduce travel time for urban residents.

  16. Hierarchical Trust Management of COI in Heterogeneous Mobile Networks

    Science.gov (United States)

    2017-08-01

    Report: Hierarchical Trust Management of COI in Heterogeneous Mobile Networks The views, opinions and/or findings contained in this report are those of...Institute & State University Title: Hierarchical Trust Management of COI in Heterogeneous Mobile Networks Report Term: 0-Other Email: irchen@vt.edu...Reconfigurability, Survivability and Intrusion Tolerance for Community of Interest (COI) Applications – Our proposed COI trust management protocol will

  17. Metastable states in the hierarchical Dyson model drive parallel processing in the hierarchical Hopfield network

    International Nuclear Information System (INIS)

    Agliari, Elena; Barra, Adriano; Guerra, Francesco; Galluzzi, Andrea; Tantari, Daniele; Tavani, Flavia

    2015-01-01

    In this paper, we introduce and investigate the statistical mechanics of hierarchical neural networks. First, we approach these systems à la Mattis, by thinking of the Dyson model as a single-pattern hierarchical neural network. We also discuss the stability of different retrievable states as predicted by the related self-consistencies obtained both from a mean-field bound and from a bound that bypasses the mean-field limitation. The latter is worked out by properly reabsorbing the magnetization fluctuations related to higher levels of the hierarchy into effective fields for the lower levels. Remarkably, mixing Amit's ansatz technique for selecting candidate-retrievable states with the interpolation procedure for solving for the free energy of these states, we prove that, due to gauge symmetry, the Dyson model accomplishes both serial and parallel processing. We extend this scenario to multiple stored patterns by implementing the Hebb prescription for learning within the couplings. This results in Hopfield-like networks constrained on a hierarchical topology, for which, by restricting to the low-storage regime where the number of patterns grows at its most logarithmical with the amount of neurons, we prove the existence of the thermodynamic limit for the free energy, and we give an explicit expression of its mean-field bound and of its related improved bound. We studied the resulting self-consistencies for the Mattis magnetizations, which act as order parameters, are studied and the stability of solutions is analyzed to get a picture of the overall retrieval capabilities of the system according to both mean-field and non-mean-field scenarios. Our main finding is that embedding the Hebbian rule on a hierarchical topology allows the network to accomplish both serial and parallel processing. By tuning the level of fast noise affecting it or triggering the decay of the interactions with the distance among neurons, the system may switch from sequential retrieval to

  18. Translating Management Practices in Hierarchical Organizations

    DEFF Research Database (Denmark)

    Wæraas, Arild; Nielsen, Jeppe Agger

    structures affect translators’ approaches taken towards management ideas. This paper reports the findings from a longitudinal case study of the translation of Leadership Pipeline in a Danish fire department and how the translators’ approach changed over time from a modifying to a reproducing mode. The study......This study examines how translators in a hierarchical context approach the translation of management practices. Although current translation theory and research emphasize the importance of contextual factors in translation processes, little research has investigated how strongly hierarchical...... finds that translation does not necessarily imply transformation of the management idea, pointing instead to aspects of exact imitation and copying of an ”original” idea. It also highlights how translation is likely to involve multiple and successive translation modes and, furthermore, that strongly...

  19. Convenient and large-scale synthesis of nitrogen-rich hierarchical porous carbon spheres for supercapacitors and CO_2 capture

    International Nuclear Information System (INIS)

    Chang, Binbin; Zhang, Shouren; Yin, Hang; Yang, Baocheng

    2017-01-01

    Highlights: • Convenient and large-scale synthesis route for N-doped hierarchical porous carbon sphere. • The resultant own spherical morphology, tunable hierarchical porosity, high surface area. • The optimal material exhibits a high CO_2 capture capacity of 4.23 mmol g"−"1. • It shows a large voltage window of 1.8 V for symmetric cell in 0.5 M Na_2SO_4. - Abstract: Herein, considering the great potential of nitrogen-doped hierarchical porous carbons in energy storage and CO_2 capture, we designed a convenient and easily large-scale production strategy for preparing nitrogen-doped hierarchical porous carbon sphere (NHPCS) materials. In this synthesis route, spherical resorcinol-formaldehyde (RF) resins were selected as carbon precursor, and then the ZnCl_2-impregnated RF resin spheres were carbonized in a NH_3 atmosphere at a temperature range of 600–800 °C. During the one-step heat-treatment process, nitrogen atom could be efficiently incorporated into the carbon skeleton, and the interconnected and hierarchical pore structure with different micro/mesopore proportion could be generated and tuned by adjusting the activating agent ZnCl_2 dosage and carbonization temperature. The resultant nitrogen-doped hierarchical porous carbon sphere materials exhibited a satisfactory charge storage capacity, and the optimal sample of NHPCS-2-8 with a high mesopore proportion obtained at 800 °C with a ZnCl_2/RF mass ratio of 2:1 presented a specific capacitance of 273.8 F g"−"1 at a current density of 0.5 A g"−"1. More importantly, the assembled NHPCS-2-8-based symmetric capacitor displayed a high energy density of 17.2 Wh kg"−"1 at a power density of 178.9 W kg"−"1 within a voltage window of 0 ∼ 1.8 V in 0.5 M Na_2SO_4 aqueous electrolyte. In addition, the CO_2 capture application of these NHPCS materials was also explored, and the optimal sample of NHPCS-0-8 with a large micropore proportion prepared at 800 °C exhibited an exceptional CO_2 uptake

  20. Economic–environmental hierarchical frequency management of a droop-controlled islanded microgrid

    International Nuclear Information System (INIS)

    Rezaei, Navid; Kalantar, Mohsen

    2014-01-01

    Highlights: • Modeling the steady-state frequency of the droop-controlled microgrids. • Precise formulation the hierarchical control levels of islanded microgrids. • Economic–environmental frequency management using mixed-integer linear programming. • Proposing a novel objective function based on the microgrid daily frequency profile. • Scheduling primary and secondary control reserves using a stochastic optimization. - Abstract: This paper presents a novel energy management system (EMS) for a microgrid to enhance the power system security in a cost-effective manner. Small size of the islanded microgrids, high levels of intermittency and energy fluctuations, lower inertia potential of inverter-interfaced distributed energy resources (DERs) makes the frequency a vital factor in the microgrid energy management system that should be managed subject to the economic–environmental policies of the microgrid EMS. The proposed model is based on precise energy and reserve scheduling of the DERs in a droop-controlled islanded microgrid to manage the possible microgrid frequency excursions. The expected value of the microgrid frequency excursions stem from system power deviations is employed as a new objective function in this study, which is aimed to be minimized using a two stage stochastic mixed-integer linear programming method. In order to model the hierarchical control structure of the islanded microgrid, the frequency dependent behavior of the droop-controlled inverter-interfaced DERs is formulated thoroughly. The proposed model is applied to a typical microgrid test system. The primary and secondary frequency control reserves are appropriately scheduled over a 24 h period. A methodology based on the Monte-Carlo simulation strategy is adapted to generate some random scenarios corresponding to renewable generation variations, load consumption deviations and contingencies of line/unit outages. The generated scenarios are reduced and applied to the

  1. Carbon fiber reinforced hierarchical orthogrid stiffened cylinder: Fabrication and testing

    Science.gov (United States)

    Wu, Hao; Lai, Changlian; Sun, Fangfang; Li, Ming; Ji, Bin; Wei, Weiyi; Liu, Debo; Zhang, Xi; Fan, Hualin

    2018-04-01

    To get strong, stiff and light cylindrical shell, carbon fiber reinforced hierarchical orthogrid stiffened cylinders are designed and fabricated. The cylinder is stiffened by two-scale orthogrid. The primary orthogrid has thick and high ribs and contains several sub-orthogrid cells whose rib is much thinner and lower. The primary orthogrid stiffens the bending rigidity of the cylinder to resist the global instability while the sub-orthogrid stiffens the bending rigidity of the skin enclosed by the primary orthogrid to resist local buckling. The cylinder is fabricated by filament winding method based on a silicone rubber mandrel with hierarchical grooves. Axial compression tests are performed to reveal the failure modes. With hierarchical stiffeners, the cylinder fails at skin fracture and has high specific strength. The cylinder will fail at end crushing if the end of the cylinder is not thickened. Global instability and local buckling are well restricted by the hierarchical stiffeners.

  2. Coping Strategies for Managing Acculturative Stress among Asian International Students

    Science.gov (United States)

    Ra, Young-An; Trusty, Jerry

    2015-01-01

    This article examines the effects of specific coping strategies on managing acculturative stress and acculturation of Asian international students, based on a sample of 220 Asian international students in the U.S. The data were analyzed with hierarchical multiple regression using Baron and Kenny's (1986) mediation procedure. The results supported…

  3. A polyacrylonitrile copolymer-silica template for three-dimensional hierarchical porous carbon as a Pt catalyst support for the oxygen reduction reaction.

    Science.gov (United States)

    Liu, Minmin; Li, Jian; Cai, Chao; Zhou, Ziwei; Ling, Yun; Liu, Rui

    2017-08-01

    Herein, we report a novel route to construct a hierarchical three-dimensional porous carbon (3DC) through a copolymer-silica assembly. In the synthesis, silica acts as a hard template and leads to the formation of an interconnected 3D macropore, whereas styrene-co-acrylonitrile polymer has been used as both a carbon source and a soft template for micro- and meso-pores. The obtained 3DC materials possess a large surface area (∼550.5 m 2 g -1 ), which facilitates high dispersion of Pt nanoparticles on the carbon support. The 3DC-supported Pt electrocatalyst shows excellent performance in the oxygen reduction reaction (ORR). The easy processing ability along with the characteristics of hierarchical porosity offers a new strategy for the preparation of carbon nanomaterials for energy application.

  4. A hierarchical model predictive voltage control for NPC/H-bridge converters with a reduced computational burden

    DEFF Research Database (Denmark)

    Gong, Zheng; Dai, Peng; Wu, Xiaojie

    2017-01-01

    In recent years, voltage source multilevel converters are very popular in medium/high-voltage industrial applications, among which the NPC/H-Bridge converter is a popular solution to the medium/high-voltage drive systems. The conventional finite control set model predictive control (FCS-MPC) stra......In recent years, voltage source multilevel converters are very popular in medium/high-voltage industrial applications, among which the NPC/H-Bridge converter is a popular solution to the medium/high-voltage drive systems. The conventional finite control set model predictive control (FCS......-MPC) strategy is not practical for multilevel converters due to their substantial calculation requirements, especially under high number of voltage levels. To solve this problem, a hierarchical model predictive voltage control (HMPVC) strategy with referring to the implementation of g-h coordinate space vector...... and experiments with a down-scaled NPC/H-Bridge converter prototype under various conditions, which validate the proposed HMPVC strategy....

  5. HiPS - Hierarchical Progressive Survey Version 1.0

    Science.gov (United States)

    Fernique, Pierre; Allen, Mark; Boch, Thomas; Donaldson, Tom; Durand, Daniel; Ebisawa, Ken; Michel, Laurent; Salgado, Jesus; Stoehr, Felix; Fernique, Pierre

    2017-05-01

    This document presents HiPS, a hierarchical scheme for the description, storage and access of sky survey data. The system is based on hierarchical tiling of sky regions at finer and finer spatial resolution which facilitates a progressive view of a survey, and supports multi-resolution zooming and panning. HiPS uses the HEALPix tessellation of the sky as the basis for the scheme and is implemented as a simple file structure with a direct indexing scheme that leads to practical implementations.

  6. Parallel content-based sub-image retrieval using hierarchical searching.

    Science.gov (United States)

    Yang, Lin; Qi, Xin; Xing, Fuyong; Kurc, Tahsin; Saltz, Joel; Foran, David J

    2014-04-01

    The capacity to systematically search through large image collections and ensembles and detect regions exhibiting similar morphological characteristics is central to pathology diagnosis. Unfortunately, the primary methods used to search digitized, whole-slide histopathology specimens are slow and prone to inter- and intra-observer variability. The central objective of this research was to design, develop, and evaluate a content-based image retrieval system to assist doctors for quick and reliable content-based comparative search of similar prostate image patches. Given a representative image patch (sub-image), the algorithm will return a ranked ensemble of image patches throughout the entire whole-slide histology section which exhibits the most similar morphologic characteristics. This is accomplished by first performing hierarchical searching based on a newly developed hierarchical annular histogram (HAH). The set of candidates is then further refined in the second stage of processing by computing a color histogram from eight equally divided segments within each square annular bin defined in the original HAH. A demand-driven master-worker parallelization approach is employed to speed up the searching procedure. Using this strategy, the query patch is broadcasted to all worker processes. Each worker process is dynamically assigned an image by the master process to search for and return a ranked list of similar patches in the image. The algorithm was tested using digitized hematoxylin and eosin (H&E) stained prostate cancer specimens. We have achieved an excellent image retrieval performance. The recall rate within the first 40 rank retrieved image patches is ∼90%. Both the testing data and source code can be downloaded from http://pleiad.umdnj.edu/CBII/Bioinformatics/.

  7. Digested sludge-derived three-dimensional hierarchical porous carbon for high-performance supercapacitor electrode.

    Science.gov (United States)

    Zhang, Jia-Jia; Fan, Hao-Xiang; Dai, Xiao-Hu; Yuan, Shi-Jie

    2018-04-01

    Digested sludge, as the main by-product of the sewage sludge anaerobic digestion process, still contains considerable organic compounds. In this protocol, we report a facile method for preparing digested sludge-derived self-doped porous carbon material for high-performance supercapacitor electrodes via a sustainable pyrolysis/activation process. The obtained digested sludge-derived carbon material (HPDSC) exhibits versatile O-, N-doped hierarchical porous framework, high specific surface area (2103.6 m 2  g -1 ) and partial graphitization phase, which can facilitate ion transport, provide more storage sites for electrolyte ions and enhance the conductivity of active electrode materials. The HPDSC-based supercapacitor electrodes show favourable energy storage performance, with a specific capacitance of 245 F g -1 at 1.0 A g -1 in 0.5 M Na 2 SO 4 ; outstanding cycling stability, with 98.4% capacitance retention after 2000 cycles; and good rate performance (211 F g -1 at 11 A g -1 ). This work provides a unique self-doped three-dimensional hierarchical porous carbon material with a favourable charge storage capacity and at the same time finds a high value-added and environment-friendly strategy for disposal and recycling of digested sludge.

  8. Multi-objective Optimization Strategies Using Adjoint Method and Game Theory in Aerodynamics

    Science.gov (United States)

    Tang, Zhili

    2006-08-01

    There are currently three different game strategies originated in economics: (1) Cooperative games (Pareto front), (2) Competitive games (Nash game) and (3) Hierarchical games (Stackelberg game). Each game achieves different equilibria with different performance, and their players play different roles in the games. Here, we introduced game concept into aerodynamic design, and combined it with adjoint method to solve multi-criteria aerodynamic optimization problems. The performance distinction of the equilibria of these three game strategies was investigated by numerical experiments. We computed Pareto front, Nash and Stackelberg equilibria of the same optimization problem with two conflicting and hierarchical targets under different parameterizations by using the deterministic optimization method. The numerical results show clearly that all the equilibria solutions are inferior to the Pareto front. Non-dominated Pareto front solutions are obtained, however the CPU cost to capture a set of solutions makes the Pareto front an expensive tool to the designer.

  9. Multi-objective optimization strategies using adjoint method and game theory in aerodynamics

    Institute of Scientific and Technical Information of China (English)

    Zhili Tang

    2006-01-01

    There are currently three different game strategies originated in economics:(1) Cooperative games (Pareto front),(2)Competitive games (Nash game) and (3)Hierarchical games (Stackelberg game).Each game achieves different equilibria with different performance,and their players play different roles in the games.Here,we introduced game concept into aerodynamic design, and combined it with adjoint method to solve multicriteria aerodynamic optimization problems.The performance distinction of the equilibria of these three game strategies was investigated by numerical experiments.We computed Pareto front, Nash and Stackelberg equilibria of the same optimization problem with two conflicting and hierarchical targets under different parameterizations by using the deterministic optimization method.The numerical results show clearly that all the equilibria solutions are inferior to the Pareto front.Non-dominated Pareto front solutions are obtained,however the CPU cost to capture a set of solutions makes the Pareto front an expensive tool to the designer.

  10. Hierarchical sets: analyzing pangenome structure through scalable set visualizations

    Science.gov (United States)

    2017-01-01

    Abstract Motivation: The increase in available microbial genome sequences has resulted in an increase in the size of the pangenomes being analyzed. Current pangenome visualizations are not intended for the pangenome sizes possible today and new approaches are necessary in order to convert the increase in available information to increase in knowledge. As the pangenome data structure is essentially a collection of sets we explore the potential for scalable set visualization as a tool for pangenome analysis. Results: We present a new hierarchical clustering algorithm based on set arithmetics that optimizes the intersection sizes along the branches. The intersection and union sizes along the hierarchy are visualized using a composite dendrogram and icicle plot, which, in pangenome context, shows the evolution of pangenome and core size along the evolutionary hierarchy. Outlying elements, i.e. elements whose presence pattern do not correspond with the hierarchy, can be visualized using hierarchical edge bundles. When applied to pangenome data this plot shows putative horizontal gene transfers between the genomes and can highlight relationships between genomes that is not represented by the hierarchy. We illustrate the utility of hierarchical sets by applying it to a pangenome based on 113 Escherichia and Shigella genomes and find it provides a powerful addition to pangenome analysis. Availability and Implementation: The described clustering algorithm and visualizations are implemented in the hierarchicalSets R package available from CRAN (https://cran.r-project.org/web/packages/hierarchicalSets) Contact: thomasp85@gmail.com Supplementary information: Supplementary data are available at Bioinformatics online. PMID:28130242

  11. Road network safety evaluation using Bayesian hierarchical joint model.

    Science.gov (United States)

    Wang, Jie; Huang, Helai

    2016-05-01

    Safety and efficiency are commonly regarded as two significant performance indicators of transportation systems. In practice, road network planning has focused on road capacity and transport efficiency whereas the safety level of a road network has received little attention in the planning stage. This study develops a Bayesian hierarchical joint model for road network safety evaluation to help planners take traffic safety into account when planning a road network. The proposed model establishes relationships between road network risk and micro-level variables related to road entities and traffic volume, as well as socioeconomic, trip generation and network density variables at macro level which are generally used for long term transportation plans. In addition, network spatial correlation between intersections and their connected road segments is also considered in the model. A road network is elaborately selected in order to compare the proposed hierarchical joint model with a previous joint model and a negative binomial model. According to the results of the model comparison, the hierarchical joint model outperforms the joint model and negative binomial model in terms of the goodness-of-fit and predictive performance, which indicates the reasonableness of considering the hierarchical data structure in crash prediction and analysis. Moreover, both random effects at the TAZ level and the spatial correlation between intersections and their adjacent segments are found to be significant, supporting the employment of the hierarchical joint model as an alternative in road-network-level safety modeling as well. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Hierarchical Microaggressions in Higher Education

    Science.gov (United States)

    Young, Kathryn; Anderson, Myron; Stewart, Saran

    2015-01-01

    Although there has been substantial research examining the effects of microaggressions in the public sphere, there has been little research that examines microaggressions in the workplace. This study explores the types of microaggressions that affect employees at universities. We coin the term "hierarchical microaggression" to represent…

  13. Hierarchical energy management system for stand-alone hybrid system based on generation costs and cascade control

    International Nuclear Information System (INIS)

    Torreglosa, J.P.; García, P.; Fernández, L.M.; Jurado, F.

    2014-01-01

    Highlights: • We present an energy management system for a stand-alone WT/PV/hydrogen/battery hybrid system. • Hierarchical control composed by master and slave control strategies. • Control assures reliable electricity support for stand-alone applications subject to technical and economic criteria. - Abstract: This paper presents an energy management system (EMS) for stand-alone hybrid systems composed by photovoltaic (PV) solar panels and a wind turbine (WT) as primary energy sources and two energy storage systems, which are a hydrogen system and a battery. The hydrogen system is composed of fuel cell (FC), electrolyzer and hydrogen storage tank. The EMS is a hierarchical control composed by a master control strategy and a slave control strategy. On the one hand, the master control generates the reference powers to meet several premises (such as to satisfy the load power demand, and to maintain the hydrogen tank level and the state of charge (SOC) of the battery between their target margins), taking also into account economic aspects to discriminate between using the battery or hydrogen system. On the other hand, the slave control modifies the reference powers generated by the master control according to the energy sources dynamic limitations, and maintains the DC bus voltage at its reference value. The models, implemented in MATLAB-Simulink environment, have been developed from commercially available components. To check the viability of the proposed EMS, two kinds of simulations were carried out: (1) A long-term simulation of 25 years (expected lifetime of the system) with a sample time of one hour to validate the master control of the EMS; and (2) A short-term simulation with sudden net power variations to validate the slave control of the EMS

  14. Stability of glassy hierarchical networks

    Science.gov (United States)

    Zamani, M.; Camargo-Forero, L.; Vicsek, T.

    2018-02-01

    The structure of interactions in most animal and human societies can be best represented by complex hierarchical networks. In order to maintain close-to-optimal function both stability and adaptability are necessary. Here we investigate the stability of hierarchical networks that emerge from the simulations of an organization type with an efficiency function reminiscent of the Hamiltonian of spin glasses. Using this quantitative approach we find a number of expected (from everyday observations) and highly non-trivial results for the obtained locally optimal networks, including, for example: (i) stability increases with growing efficiency and level of hierarchy; (ii) the same perturbation results in a larger change for more efficient states; (iii) networks with a lower level of hierarchy become more efficient after perturbation; (iv) due to the huge number of possible optimal states only a small fraction of them exhibit resilience and, finally, (v) ‘attacks’ targeting the nodes selectively (regarding their position in the hierarchy) can result in paradoxical outcomes.

  15. Hierarchical Semantic Model of Geovideo

    Directory of Open Access Journals (Sweden)

    XIE Xiao

    2015-05-01

    Full Text Available The public security incidents were getting increasingly challenging with regard to their new features, including multi-scale mobility, multistage dynamic evolution, as well as spatiotemporal concurrency and uncertainty in the complex urban environment. However, the existing video models, which were used/designed for independent archive or local analysis of surveillance video, have seriously inhibited emergency response to the urgent requirements.Aiming at the explicit representation of change mechanism in video, the paper proposed a novel hierarchical geovideo semantic model using UML. This model was characterized by the hierarchical representation of both data structure and semantics based on the change-oriented three domains (feature domain, process domain and event domain instead of overall semantic description of video streaming; combining both geographical semantics and video content semantics, in support of global semantic association between multiple geovideo data. The public security incidents by video surveillance are inspected as an example to illustrate the validity of this model.

  16. Hierarchical graphs for rule-based modeling of biochemical systems

    Directory of Open Access Journals (Sweden)

    Hu Bin

    2011-02-01

    Full Text Available Abstract Background In rule-based modeling, graphs are used to represent molecules: a colored vertex represents a component of a molecule, a vertex attribute represents the internal state of a component, and an edge represents a bond between components. Components of a molecule share the same color. Furthermore, graph-rewriting rules are used to represent molecular interactions. A rule that specifies addition (removal of an edge represents a class of association (dissociation reactions, and a rule that specifies a change of a vertex attribute represents a class of reactions that affect the internal state of a molecular component. A set of rules comprises an executable model that can be used to determine, through various means, the system-level dynamics of molecular interactions in a biochemical system. Results For purposes of model annotation, we propose the use of hierarchical graphs to represent structural relationships among components and subcomponents of molecules. We illustrate how hierarchical graphs can be used to naturally document the structural organization of the functional components and subcomponents of two proteins: the protein tyrosine kinase Lck and the T cell receptor (TCR complex. We also show that computational methods developed for regular graphs can be applied to hierarchical graphs. In particular, we describe a generalization of Nauty, a graph isomorphism and canonical labeling algorithm. The generalized version of the Nauty procedure, which we call HNauty, can be used to assign canonical labels to hierarchical graphs or more generally to graphs with multiple edge types. The difference between the Nauty and HNauty procedures is minor, but for completeness, we provide an explanation of the entire HNauty algorithm. Conclusions Hierarchical graphs provide more intuitive formal representations of proteins and other structured molecules with multiple functional components than do the regular graphs of current languages for

  17. Hierarchical Spatial Concept Formation Based on Multimodal Information for Human Support Robots.

    Science.gov (United States)

    Hagiwara, Yoshinobu; Inoue, Masakazu; Kobayashi, Hiroyoshi; Taniguchi, Tadahiro

    2018-01-01

    In this paper, we propose a hierarchical spatial concept formation method based on the Bayesian generative model with multimodal information e.g., vision, position and word information. Since humans have the ability to select an appropriate level of abstraction according to the situation and describe their position linguistically, e.g., "I am in my home" and "I am in front of the table," a hierarchical structure of spatial concepts is necessary in order for human support robots to communicate smoothly with users. The proposed method enables a robot to form hierarchical spatial concepts by categorizing multimodal information using hierarchical multimodal latent Dirichlet allocation (hMLDA). Object recognition results using convolutional neural network (CNN), hierarchical k-means clustering result of self-position estimated by Monte Carlo localization (MCL), and a set of location names are used, respectively, as features in vision, position, and word information. Experiments in forming hierarchical spatial concepts and evaluating how the proposed method can predict unobserved location names and position categories are performed using a robot in the real world. Results verify that, relative to comparable baseline methods, the proposed method enables a robot to predict location names and position categories closer to predictions made by humans. As an application example of the proposed method in a home environment, a demonstration in which a human support robot moves to an instructed place based on human speech instructions is achieved based on the formed hierarchical spatial concept.

  18. Hierarchical Spatial Concept Formation Based on Multimodal Information for Human Support Robots

    Directory of Open Access Journals (Sweden)

    Yoshinobu Hagiwara

    2018-03-01

    Full Text Available In this paper, we propose a hierarchical spatial concept formation method based on the Bayesian generative model with multimodal information e.g., vision, position and word information. Since humans have the ability to select an appropriate level of abstraction according to the situation and describe their position linguistically, e.g., “I am in my home” and “I am in front of the table,” a hierarchical structure of spatial concepts is necessary in order for human support robots to communicate smoothly with users. The proposed method enables a robot to form hierarchical spatial concepts by categorizing multimodal information using hierarchical multimodal latent Dirichlet allocation (hMLDA. Object recognition results using convolutional neural network (CNN, hierarchical k-means clustering result of self-position estimated by Monte Carlo localization (MCL, and a set of location names are used, respectively, as features in vision, position, and word information. Experiments in forming hierarchical spatial concepts and evaluating how the proposed method can predict unobserved location names and position categories are performed using a robot in the real world. Results verify that, relative to comparable baseline methods, the proposed method enables a robot to predict location names and position categories closer to predictions made by humans. As an application example of the proposed method in a home environment, a demonstration in which a human support robot moves to an instructed place based on human speech instructions is achieved based on the formed hierarchical spatial concept.

  19. THE STRATEGY OF RURAL TOURISM DEVELOPMENT (An Eco-economy and Eco-cultural Approach)

    OpenAIRE

    Soeroso, Amiluhur; Susilo, Y. Sri

    2015-01-01

    The research is aimed to analyse the strategy of rural tourism development in Kepuharjo, a village in the foot plain of Merapi Volcano. The data were obtained from 140visitors doing activities surrounding Yogyakarta Special Province with structured questionnaire; the data was then analysed using conjoint analysis and analytic hierarchical process.The finding shows that the strategy of rural tourism development of Kepuharjo village is called “saga”. Within this strategy, its urgent aspect is k...

  20. Hierarchical Mesoporous Organosilica-Silica Core-Shell Nanoparticles Capable of Controlled Fungicide Release.

    Science.gov (United States)

    Luo, Leilei; Liang, Yucang; Erichsen, Egil Severin; Anwander, Reiner

    2018-05-17

    A new class of hierarchically structured mesoporous silica core-shell nanoparticles (HSMSCSNs) with a periodic mesoporous organosilica (PMO) core and a mesoporous silica (MS) shell is reported. The applied one-pot, two-step strategy allows rational control over the core/shell chemical composition, topology, and pore/particle size, simply by adjusting the reaction conditions in the presence of cetyltrimethylammonium bromide (CTAB) as structure-directing agent under basic conditions. The spherical, ethylene- or methylene-bridged PMO cores feature hexagonal (p6mm) or cage-like cubic symmetry (Pm3‾ n) depending on the organosilica precursor. The hexagonal MS shell was obtained by n-hexane-induced controlled hydrolysis of TEOS followed by directional co-assembly/condensation of silicate/CTAB composites at the PMO cores. The HSMSCSNs feature a hierarchical pore structure with pore diameters of about 2.7 and 5.6 nm in the core and shell domains, respectively. The core sizes and shell thicknesses are adjustable in the ranges of 90-275 and 15-50 nm, respectively, and the surface areas (max. 1300 m 2  g -1 ) and pore volumes (max. 1.83 cm 3  g -1 ) are among the highest reported for core-shell nanoparticles. The adsorption and controlled release of the fungicide propiconazole by the HSMSCSNs showed a three-stage release profile. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Exploring hierarchical and overlapping modular structure in the yeast protein interaction network

    Directory of Open Access Journals (Sweden)

    Zhao Yi

    2010-12-01

    Full Text Available Abstract Background Developing effective strategies to reveal modular structures in protein interaction networks is crucial for better understanding of molecular mechanisms of underlying biological processes. In this paper, we propose a new density-based algorithm (ADHOC for clustering vertices of a protein interaction network using a novel subgraph density measurement. Results By statistically evaluating several independent criteria, we found that ADHOC could significantly improve the outcome as compared with five previously reported density-dependent methods. We further applied ADHOC to investigate the hierarchical and overlapping modular structure in the yeast PPI network. Our method could effectively detect both protein modules and the overlaps between them, and thus greatly promote the precise prediction of protein functions. Moreover, by further assaying the intermodule layer of the yeast PPI network, we classified hubs into two types, module hubs and inter-module hubs. Each type presents distinct characteristics both in network topology and biological functions, which could conduce to the better understanding of relationship between network architecture and biological implications. Conclusions Our proposed algorithm based on the novel subgraph density measurement makes it possible to more precisely detect hierarchical and overlapping modular structures in protein interaction networks. In addition, our method also shows a strong robustness against the noise in network, which is quite critical for analyzing such a high noise network.

  2. On hierarchical solutions to the BBGKY hierarchy

    Science.gov (United States)

    Hamilton, A. J. S.

    1988-01-01

    It is thought that the gravitational clustering of galaxies in the universe may approach a scale-invariant, hierarchical form in the small separation, large-clustering regime. Past attempts to solve the Born-Bogoliubov-Green-Kirkwood-Yvon (BBGKY) hierarchy in this regime have assumed a certain separable hierarchical form for the higher order correlation functions of galaxies in phase space. It is shown here that such separable solutions to the BBGKY equations must satisfy the condition that the clustered component of the solution has cluster-cluster correlations equal to galaxy-galaxy correlations to all orders. The solutions also admit the presence of an arbitrary unclustered component, which plays no dyamical role in the large-clustering regime. These results are a particular property of the specific separable model assumed for the correlation functions in phase space, not an intrinsic property of spatially hierarchical solutions to the BBGKY hierarchy. The observed distribution of galaxies does not satisfy the required conditions. The disagreement between theory and observation may be traced, at least in part, to initial conditions which, if Gaussian, already have cluster correlations greater than galaxy correlations.

  3. Statistical dynamics of ultradiffusion in hierarchical systems

    International Nuclear Information System (INIS)

    Gardner, S.

    1987-01-01

    In many types of disordered systems which exhibit frustration and competition, an ultrametric topology is found to exist in the space of allowable states. This ultrametric topology of states is associated with a hierarchical relaxation process called ultradiffusion. Ultradiffusion occurs in hierarchical non-linear (HNL) dynamical systems when constraints cause large scale, slow modes of motion to be subordinated to small scale, fast modes. Examples of ultradiffusion are found throughout condensed matter physics and critical phenomena (e.g. the states of spin glasses), in biophysics (e.g. the states of Hopfield networks) and in many other fields including layered computing based upon nonlinear dynamics. The statistical dynamics of ultradiffusion can be treated as a random walk on an ultrametric space. For reversible bifurcating ultrametric spaces the evolution equation governing the probability of a particle being found at site i at time t has a highly degenerate transition matrix. This transition matrix has a fractal geometry similar to the replica form proposed for spin glasses. The authors invert this fractal matrix using a recursive quad-tree (QT) method. Possible applications of hierarchical systems to communications and symbolic computing are discussed briefly

  4. Hierarchically Structured Electrospun Fibers

    Science.gov (United States)

    2013-01-07

    in the natural lotus and silver ragwort leaves. Figure 4. Examples of electrospun bio-mimics of natural hierarchical structures. (A) Lotus leaf...B) pillared poly(methyl methacrylate) (PMMA) electrospun fiber mimic; (C) silver ragwort leaf; (D) electrospun fiber mimic made from nylon 6 and...domains containing the protein in the surrounding EVA fibers [115]. A wide variety of core-shell fibers have been generated, including PCL/ gelatin

  5. Topology-based hierarchical scheduling using deficit round robin

    DEFF Research Database (Denmark)

    Yu, Hao; Yan, Ying; Berger, Michael Stubert

    2009-01-01

    according to the topology. The mapping process could be completed through the network management plane or by manual configuration. Based on the knowledge of the network, the scheduler can manage the traffic on behalf of other less advanced nodes, avoid potential traffic congestion, and provide flow...... protection and isolation. Comparisons between hierarchical scheduling, flow-based scheduling, and class-based scheduling schemes have been carried out under a symmetric tree topology. Results have shown that the hierarchical scheduling scheme provides better flow protection and isolation from attack...

  6. An Improved Hierarchical Genetic Algorithm for Sheet Cutting Scheduling with Process Constraints

    OpenAIRE

    Yunqing Rao; Dezhong Qi; Jinling Li

    2013-01-01

    For the first time, an improved hierarchical genetic algorithm for sheet cutting problem which involves n cutting patterns for m non-identical parallel machines with process constraints has been proposed in the integrated cutting stock model. The objective of the cutting scheduling problem is minimizing the weighted completed time. A mathematical model for this problem is presented, an improved hierarchical genetic algorithm (ant colony—hierarchical genetic algorithm) is developed for better ...

  7. Molecular simulation of adsorption and transport in hierarchical porous materials.

    Science.gov (United States)

    Coasne, Benoit; Galarneau, Anne; Gerardin, Corine; Fajula, François; Villemot, François

    2013-06-25

    Adsorption and transport in hierarchical porous solids with micro- (~1 nm) and mesoporosities (>2 nm) are investigated by molecular simulation. Two models of hierarchical solids are considered: microporous materials in which mesopores are carved out (model A) and mesoporous materials in which microporous nanoparticles are inserted (model B). Adsorption isotherms for model A can be described as a linear combination of the adsorption isotherms for pure mesoporous and microporous solids. In contrast, adsorption in model B departs from adsorption in pure microporous and mesoporous solids; the inserted microporous particles act as defects, which help nucleate the liquid phase within the mesopore and shift capillary condensation toward lower pressures. As far as transport under a pressure gradient is concerned, the flux in hierarchical materials consisting of microporous solids in which mesopores are carved out obeys the Navier-Stokes equation so that Darcy's law is verified within the mesopore. Moreover, the flow in such materials is larger than in a single mesopore, due to the transfer between micropores and mesopores. This nonzero velocity at the mesopore surface implies that transport in such hierarchical materials involves slippage at the mesopore surface, although the adsorbate has a strong affinity for the surface. In contrast to model A, flux in model B is smaller than in a single mesopore, as the nanoparticles act as constrictions that hinder transport. By a subtle effect arising from fast transport in the mesopores, the presence of mesopores increases the number of molecules in the microporosity in hierarchical materials and, hence, decreases the flow in the micropores (due to mass conservation). As a result, we do not observe faster diffusion in the micropores of hierarchical materials upon flow but slower diffusion, which increases the contact time between the adsorbate and the surface of the microporosity.

  8. Packaging glass with hierarchically nanostructured surface

    KAUST Repository

    He, Jr-Hau; Fu, Hui-Chun

    2017-01-01

    An optical device includes an active region and packaging glass located on top of the active region. A top surface of the packaging glass includes hierarchical nanostructures comprised of honeycombed nanowalls (HNWs) and nanorod (NR) structures

  9. Selective hierarchical patterning of silicon nanostructures via soft nanostencil lithography.

    Science.gov (United States)

    Du, Ke; Ding, Junjun; Wathuthanthri, Ishan; Choi, Chang-Hwan

    2017-11-17

    It is challenging to hierarchically pattern high-aspect-ratio nanostructures on microstructures using conventional lithographic techniques, where photoresist (PR) film is not able to uniformly cover on the microstructures as the aspect ratio increases. Such non-uniformity causes poor definition of nanopatterns over the microstructures. Nanostencil lithography can provide an alternative means to hierarchically construct nanostructures on microstructures via direct deposition or plasma etching through a free-standing nanoporous membrane. In this work, we demonstrate the multiscale hierarchical fabrication of high-aspect-ratio nanostructures on microstructures of silicon using a free-standing nanostencil, which is a nanoporous membrane consisting of metal (Cr), PR, and anti-reflective coating. The nanostencil membrane is used as a deposition mask to define Cr nanodot patterns on the predefined silicon microstructures. Then, deep reactive ion etching is used to hierarchically create nanostructures on the microstructures using the Cr nanodots as an etch mask. With simple modification of the main fabrication processes, high-aspect-ratio nanopillars are selectively defined only on top of the microstructures, on bottom, or on both top and bottom.

  10. Conceptual hierarchical modeling to describe wetland plant community organization

    Science.gov (United States)

    Little, A.M.; Guntenspergen, G.R.; Allen, T.F.H.

    2010-01-01

    Using multivariate analysis, we created a hierarchical modeling process that describes how differently-scaled environmental factors interact to affect wetland-scale plant community organization in a system of small, isolated wetlands on Mount Desert Island, Maine. We followed the procedure: 1) delineate wetland groups using cluster analysis, 2) identify differently scaled environmental gradients using non-metric multidimensional scaling, 3) order gradient hierarchical levels according to spatiotem-poral scale of fluctuation, and 4) assemble hierarchical model using group relationships with ordination axes and post-hoc tests of environmental differences. Using this process, we determined 1) large wetland size and poor surface water chemistry led to the development of shrub fen wetland vegetation, 2) Sphagnum and water chemistry differences affected fen vs. marsh / sedge meadows status within small wetlands, and 3) small-scale hydrologic differences explained transitions between forested vs. non-forested and marsh vs. sedge meadow vegetation. This hierarchical modeling process can help explain how upper level contextual processes constrain biotic community response to lower-level environmental changes. It creates models with more nuanced spatiotemporal complexity than classification and regression tree procedures. Using this process, wetland scientists will be able to generate more generalizable theories of plant community organization, and useful management models. ?? Society of Wetland Scientists 2009.

  11. Band structures of two dimensional solid/air hierarchical phononic crystals

    International Nuclear Information System (INIS)

    Xu, Y.L.; Tian, X.G.; Chen, C.Q.

    2012-01-01

    The hierarchical phononic crystals to be considered show a two-order “hierarchical” feature, which consists of square array arranged macroscopic periodic unit cells with each unit cell itself including four sub-units. Propagation of acoustic wave in such two dimensional solid/air phononic crystals is investigated by the finite element method (FEM) with the Bloch theory. Their band structure, wave filtering property, and the physical mechanism responsible for the broadened band gap are explored. The corresponding ordinary phononic crystal without hierarchical feature is used for comparison. Obtained results show that the solid/air hierarchical phononic crystals possess tunable outstanding band gap features, which are favorable for applications such as sound insulation and vibration attenuation.

  12. Senior Executives' Perceptions of Business-to-Consumer (B2C) Online Marketing Strategies: The Case of Singapore.

    Science.gov (United States)

    Teo, Thompson S. H.; Tan, Jek Swan

    2002-01-01

    Describes a study on Internet marketing strategies of business-to-consumer (B2C) firms in Singapore. Results of a survey and hierarchical regression analyses indicate that strategies to attract customers and to relate to customers have significant positive relationships to online brand equity, which is positively related to financial growth.…

  13. Lattice-Symmetry-Driven Epitaxy of Hierarchical GaN Nanotripods

    KAUST Repository

    Wang, Ping

    2017-01-18

    Lattice-symmetry-driven epitaxy of hierarchical GaN nanotripods is demonstrated. The nanotripods emerge on the top of hexagonal GaN nanowires, which are selectively grown on pillar-patterned GaN templates using molecular beam epitaxy. High-resolution transmission electron microscopy confirms that two kinds of lattice-symmetry, wurtzite (wz) and zinc-blende (zb), coexist in the GaN nanotripods. Periodical transformation between wz and zb drives the epitaxy of the hierarchical nanotripods with N-polarity. The zb-GaN is formed by the poor diffusion of adatoms, and it can be suppressed by improving the ability of the Ga adatoms to migrate as the growth temperature increased. This controllable epitaxy of hierarchical GaN nanotripods allows quantum dots to be located at the phase junctions of the nanotripods and nanowires, suggesting a new recipe for multichannel quantum devices.

  14. Intensity-based hierarchical elastic registration using approximating splines.

    Science.gov (United States)

    Serifovic-Trbalic, Amira; Demirovic, Damir; Cattin, Philippe C

    2014-01-01

    We introduce a new hierarchical approach for elastic medical image registration using approximating splines. In order to obtain the dense deformation field, we employ Gaussian elastic body splines (GEBS) that incorporate anisotropic landmark errors and rotation information. Since the GEBS approach is based on a physical model in form of analytical solutions of the Navier equation, it can very well cope with the local as well as global deformations present in the images by varying the standard deviation of the Gaussian forces. The proposed GEBS approximating model is integrated into the elastic hierarchical image registration framework, which decomposes a nonrigid registration problem into numerous local rigid transformations. The approximating GEBS registration scheme incorporates anisotropic landmark errors as well as rotation information. The anisotropic landmark localization uncertainties can be estimated directly from the image data, and in this case, they represent the minimal stochastic localization error, i.e., the Cramér-Rao bound. The rotation information of each landmark obtained from the hierarchical procedure is transposed in an additional angular landmark, doubling the number of landmarks in the GEBS model. The modified hierarchical registration using the approximating GEBS model is applied to register 161 image pairs from a digital mammogram database. The obtained results are very encouraging, and the proposed approach significantly improved all registrations comparing the mean-square error in relation to approximating TPS with the rotation information. On artificially deformed breast images, the newly proposed method performed better than the state-of-the-art registration algorithm introduced by Rueckert et al. (IEEE Trans Med Imaging 18:712-721, 1999). The average error per breast tissue pixel was less than 2.23 pixels compared to 2.46 pixels for Rueckert's method. The proposed hierarchical elastic image registration approach incorporates the GEBS

  15. Hierarchical Fiber Structures Made by Electrospinning Polymers

    Science.gov (United States)

    Reneker, Darrell H.

    2009-03-01

    A filter for water purification that is very thin, with small interstices and high surface area per unit mass, can be made with nanofibers. The mechanical strength of a very thin sheet of nanofibers is not great enough to withstand the pressure drop of the fluid flowing through. If the sheet of nanofibers is made thicker, the strength will increase, but the flow will be reduced to an impractical level. An optimized filter can be made with nanometer scale structures supported on micron scale structures, which are in turn supported on millimeter scale structures. This leads to a durable hierarchical structure to optimize the filtration efficiency with a minimum amount of material. Buckling coils,ootnotetextTao Han, Darrell H Reneker, Alexander L. Yarin, Polymer, Volume 48, issue 20 (September 21, 2007), p. 6064-6076. electrical bending coilsootnotetextDarrell H. Reneker and Alexander L. Yarin, Polymer, Volume 49, Issue 10 (2008) Pages 2387-2425, DOI:10.1016/j.polymer.2008.02.002. Feature Article. and pendulum coilsootnotetextT. Han, D.H. Reneker, A.L. Yarin, Polymer, Volume 49, (2008) Pages 2160-2169, doi:10.1016/jpolymer.2008.01.0487878. spanning dimensions from a few microns to a few centimeters can be collected from a single jet by controlling the position and motion of a collector. Attractive routes to the design and construction of hierarchical structures for filtration are based on nanofibers supported on small coils that are in turn supported on larger coils, which are supported on even larger overlapping coils. ``Such top-down'' hierarchical structures are easy to make by electrospinning. In one example, a thin hierarchical structure was made, with a high surface area and small interstices, having an open area of over 50%, with the thinnest fibers supported at least every 15 microns.

  16. Application of hierarchical matrices for partial inverse

    KAUST Repository

    Litvinenko, Alexander

    2013-11-26

    In this work we combine hierarchical matrix techniques (Hackbusch, 1999) and domain decomposition methods to obtain fast and efficient algorithms for the solution of multiscale problems. This combination results in the hierarchical domain decomposition (HDD) method, which can be applied for solution multi-scale problems. Multiscale problems are problems that require the use of different length scales. Using only the finest scale is very expensive, if not impossible, in computational time and memory. Domain decomposition methods decompose the complete problem into smaller systems of equations corresponding to boundary value problems in subdomains. Then fast solvers can be applied to each subdomain. Subproblems in subdomains are independent, much smaller and require less computational resources as the initial problem.

  17. Hierarchical control system of advanced robot manipulator

    International Nuclear Information System (INIS)

    Oomichi, Takeo; Okino, Akihisa; Nishihara, Masatoshi; Sakamoto, Taizou; Matsuda, Koichi; Ohnishi, Ken

    1990-01-01

    We introduce a double arm with 4-finger's manipulator system which process the large volume of information at high speed. This is under research/development many type of works in the harsh condition. Namely, hierarchization of instruction unit in which motion control system as real time processing unit, and task planning unit as non-real time processing unit, interface with operation through the task planning unit has been made. Also, high speed processing of large volume information has been realized by decentralizing the motion control unit by function, hierarchizing the high speed processing unit, and developing high speed transmission, IC which does not depend on computer OS to avoid the delay in transmission. (author)

  18. Masking effects of speech and music: does the masker's hierarchical structure matter?

    Science.gov (United States)

    Shi, Lu-Feng; Law, Yvonne

    2010-04-01

    Speech and music are time-varying signals organized by parallel hierarchical rules. Through a series of four experiments, this study compared the masking effects of single-talker speech and instrumental music on speech perception while manipulating the complexity of hierarchical and temporal structures of the maskers. Listeners' word recognition was found to be similar between hierarchically intact and disrupted speech or classical music maskers (Experiment 1). When sentences served as the signal, significantly greater masking effects were observed with disrupted than intact speech or classical music maskers (Experiment 2), although not with jazz or serial music maskers, which differed from the classical music masker in their hierarchical structures (Experiment 3). Removing the classical music masker's temporal dynamics or partially restoring it affected listeners' sentence recognition; yet, differences in performance between intact and disrupted maskers remained robust (Experiment 4). Hence, the effect of structural expectancy was largely present across maskers when comparing them before and after their hierarchical structure was purposefully disrupted. This effect seemed to lend support to the auditory stream segregation theory.

  19. On Hierarchical Extensions of Large-Scale 4-regular Grid Network Structures

    DEFF Research Database (Denmark)

    Pedersen, Jens Myrup; Patel, A.; Knudsen, Thomas Phillip

    2004-01-01

    dependencies between the number of nodes and the distances in the structures. The perfect square mesh is introduced for hierarchies, and it is shown that applying ordered hierarchies in this way results in logarithmic dependencies between the number of nodes and the distances, resulting in better scaling...... structures. For example, in a mesh of 391876 nodes the average distance is reduced from 417.33 to 17.32 by adding hierarchical lines. This is gained by increasing the number of lines by 4.20% compared to the non-hierarchical structure. A similar hierarchical extension of the torus structure also results...

  20. Wetting and Dewetting Transitions on Submerged Superhydrophobic Surfaces with Hierarchical Structures.

    Science.gov (United States)

    Wu, Huaping; Yang, Zhe; Cao, Binbin; Zhang, Zheng; Zhu, Kai; Wu, Bingbing; Jiang, Shaofei; Chai, Guozhong

    2017-01-10

    The wetting transition on submersed superhydrophobic surfaces with hierarchical structures and the influence of trapped air on superhydrophobic stability are predicted based on the thermodynamics and mechanical analyses. The dewetting transition on the hierarchically structured surfaces is investigated, and two necessary thermodynamic conditions and a mechanical balance condition for dewetting transition are proposed. The corresponding thermodynamic phase diagram of reversible transition and the critical reversed pressure well explain the experimental results reported previously. Our theory provides a useful guideline for precise controlling of breaking down and recovering of superhydrophobicity by designing superhydrophobic surfaces with hierarchical structures under water.

  1. Hierarchical DSE for multi-ASIP platforms

    DEFF Research Database (Denmark)

    Micconi, Laura; Corvino, Rosilde; Gangadharan, Deepak

    2013-01-01

    This work proposes a hierarchical Design Space Exploration (DSE) for the design of multi-processor platforms targeted to specific applications with strict timing and area constraints. In particular, it considers platforms integrating multiple Application Specific Instruction Set Processors (ASIPs...

  2. Hierarchical quark mass matrices

    International Nuclear Information System (INIS)

    Rasin, A.

    1998-02-01

    I define a set of conditions that the most general hierarchical Yukawa mass matrices have to satisfy so that the leading rotations in the diagonalization matrix are a pair of (2,3) and (1,2) rotations. In addition to Fritzsch structures, examples of such hierarchical structures include also matrices with (1,3) elements of the same order or even much larger than the (1,2) elements. Such matrices can be obtained in the framework of a flavor theory. To leading order, the values of the angle in the (2,3) plane (s 23 ) and the angle in the (1,2) plane (s 12 ) do not depend on the order in which they are taken when diagonalizing. We find that any of the Cabbibo-Kobayashi-Maskawa matrix parametrizations that consist of at least one (1,2) and one (2,3) rotation may be suitable. In the particular case when the s 13 diagonalization angles are sufficiently small compared to the product s 12 s 23 , two special CKM parametrizations emerge: the R 12 R 23 R 12 parametrization follows with s 23 taken before the s 12 rotation, and vice versa for the R 23 R 12 R 23 parametrization. (author)

  3. A distributed location management strategy for next generation IP-based wireless networks

    Institute of Scientific and Technical Information of China (English)

    SONG Mei; FENG Rui-jun; HUANG Jian-wen; SONG Jun-de

    2006-01-01

    Location management is the most important function in mobility management technology. The hierarchical structure of the proposed hierarchical network-layer mobility management (HNMM) can reduce the signaling cost. The selforganizing topology scheme can enhance the robustness and quality of the mobility management. The information of location of the mobile node is stored in the distributed database,which makes the storage of the location information more reliable and robust, and more flexible strategies can be used.The numeric results show that HNMM can provide better performance than the general structure of mobile IPv6, when the mobile nodes move frequently and when there is high traffic throughput.

  4. Strategies of marine dinoflagellate survival and some rules of assembly

    Science.gov (United States)

    Smayda, Theodore J.; Reynolds, Colin S.

    2003-03-01

    Dinoflagellate ecology is based on multiple adaptive strategies and species having diverse habitat preferences. Nine types of mixing-irradiance-nutrient habitats selecting for specific marine dinoflagellate life-form types are recognised, with five rules of assembly proposed to govern bloom-species selection and community organisation within these habitats. Assembly is moulded around an abiotic template of light energy, nutrient supply and physical mixing in permutative combinations. Species selected will have one of three basic ( C-, S-, R-) strategies: colonist species ( C-) which predominate in chemically disturbed habitats; nutrient stress tolerant species ( S-), and species ( R-) tolerant of shear/stress forces in physically disturbed water masses. This organisational plan of three major habitat variables and three major adaptive strategies is termed the 3-3 plan. The bloom behaviour and habitat specialisation of dinoflagellates and diatoms are compared. Dinoflagellates behave as annual species, bloom soloists, are ecophysiologically diverse, and habitat specialists whose blooms tend to be monospecific. Diatoms behave as perennial species, guild members, are habitat cosmopolites, have a relatively uniform bloom strategy based on species-rich pools and exhibit limited habitat specialisation. Dinoflagellate bloom-species selection follows a taxonomic hierarchical pathway which progresses from phylogenetic to generic to species selection, and in that sequence. Each hierarchical taxonomic level has its own adaptive requirements subject to rules of assembly. Dinoflagellates would appear to be well suited to exploit marine habitats and to be competitive with other phylogenetic groups, yet fail to do so.

  5. Sphere-shaped hierarchical cathode with enhanced growth of nanocrystal planes for high-rate and cycling-stable li-ion batteries.

    Science.gov (United States)

    Zhang, Linjing; Li, Ning; Wu, Borong; Xu, Hongliang; Wang, Lei; Yang, Xiao-Qing; Wu, Feng

    2015-01-14

    High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li(1.2)Ni(0.13)Mn(0.54)Co(0.13)O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li(+) intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achieving around 70% (175 mAh g(-1)) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.

  6. Corticosterone manipulation reveals differences in hierarchical organization of multidimensional reproductive trade-offs in r-strategist and K-strategist females.

    Science.gov (United States)

    Lancaster, L T; Hazard, L C; Clobert, J; Sinervo, B R

    2008-03-01

    Life history trade-offs are often hierarchical with decisions at one level affecting lower level trade-offs. We investigated trade-off structure in female side-blotched lizards (Uta stansburiana), which exhibit two evolved strategies: yellow-throated females are K-strategists and orange-throated are r-strategists. Corticosterone treatment was predicted to differentially organize these females' reproductive decisions. Corticosterone-treated yellow females suppressed reproduction but survived well, and augmented egg mass without decreasing clutch size. Conversely, corticosterone enhanced mortality and reproductive rates in orange females, and increased egg mass only after lengthy exposure. Corticosterone did not affect post-laying condition, suggesting that corticosterone increased egg mass through enhanced energy acquisition (income breeding). Corticosterone enhanced survival of lightweight females, but decreased survival of heavy females, introducing a foraging vs. predation trade-off. We conclude that rather than being a direct, functional relationship, observed trade-offs between offspring size and number represent evolved differences in hierarchical organization of multidimensional trade-offs, particularly in response to stress.

  7. Negative Sequence Droop Method based Hierarchical Control for Low Voltage Ride-Through in Grid-Interactive Microgrids

    DEFF Research Database (Denmark)

    Zhao, Xin; Firoozabadi, Mehdi Savaghebi; Quintero, Juan Carlos Vasquez

    2015-01-01

    . In this paper, a voltage support strategy based on negative sequence droop control, which regulate the positive/negative sequence active and reactive power flow by means of sending proper voltage reference to the inner control loop, is proposed for the grid connected MGs to ride through voltage sags under...... complex line impedance conditions. In this case, the MGs should inject a certain amount of positive and negative sequence power to the grid so that the voltage quality at load side can be maintained at a satisfied level. A two layer hierarchical control strategy is proposed in this paper. The primary...... control loop consists of voltage and current inner loops, conventional droop control and virtual impedance loop while the secondary control loop is based on positive/negative sequence droop control which can achieve power injection under voltage sags. Experimental results with asymmetrical voltage sags...

  8. Catalytic Fast Pyrolysis of Kraft Lignin over Hierarchical HZSM-5 and Hβ Zeolites

    Directory of Open Access Journals (Sweden)

    Yadong Bi

    2018-02-01

    Full Text Available The hierarchical HZSM-5 and Hβ zeolites were prepared by alkaline post-treatment methods adopting Na2CO3, TMAOH/NaOH mixture, and NaOH as desilication sources, respectively. More mesopores are produced over two kinds of zeolites, while the micropores portion is well preserved. The mesopores formed in hierarchical Hβ zeolites were directly related to the basicity of the alkaline solution, indicating that Hβ zeolite is more sensitive to the alkaline post-treatment. The hierarchical HZSM-5 and Hβ zeolites are more active than the parent one for catalytic fast pyrolysis (CFP of Kraft lignin. Hierarchical zeolites retained the function of acid catalysis, while additionally creating larger mesopores to ensure the entry of bulkier reactant molecules. The increase of the condensable volatiles yield can be attributed to the improvement of the mass transfer performance, which correlates well with the change of mesoporous surface area. In particular, the condensable volatiles yield for the optimized hierarchical Hβ reached approximately two times that of the parent Hβ zeolites. In contrast to the parent HZSM-5, the optimized hierarchical HZSM-5 zeolite significantly reduced the selectivity of oxygenates from 27.2% to 3.3%.

  9. Modular networks with hierarchical organization

    Indian Academy of Sciences (India)

    Several networks occurring in real life have modular structures that are arranged in a hierarchical fashion. In this paper, we have proposed a model for such networks, using a stochastic generation method. Using this model we show that, the scaling relation between the clustering and degree of the nodes is not a necessary ...

  10. Hierarchical machining materials and their performance

    DEFF Research Database (Denmark)

    Sidorenko, Daria; Loginov, Pavel; Levashov, Evgeny

    2016-01-01

    as nanoparticles in the binder, or polycrystalline, aggregate-like reinforcements, also at several scale levels). Such materials can ensure better productivity, efficiency, and lower costs of drilling, cutting, grinding, and other technological processes. This article reviews the main groups of hierarchical...

  11. Packaging glass with hierarchically nanostructured surface

    KAUST Repository

    He, Jr-Hau

    2017-08-03

    An optical device includes an active region and packaging glass located on top of the active region. A top surface of the packaging glass includes hierarchical nanostructures comprised of honeycombed nanowalls (HNWs) and nanorod (NR) structures extending from the HNWs.

  12. Hierarchical Multiple Markov Chain Model for Unsupervised Texture Segmentation

    Czech Academy of Sciences Publication Activity Database

    Scarpa, G.; Gaetano, R.; Haindl, Michal; Zerubia, J.

    2009-01-01

    Roč. 18, č. 8 (2009), s. 1830-1843 ISSN 1057-7149 R&D Projects: GA ČR GA102/08/0593 EU Projects: European Commission(XE) 507752 - MUSCLE Institutional research plan: CEZ:AV0Z10750506 Keywords : Classification * texture analysis * segmentation * hierarchical image models * Markov process Subject RIV: BD - Theory of Information Impact factor: 2.848, year: 2009 http://library.utia.cas.cz/separaty/2009/RO/haindl-hierarchical multiple markov chain model for unsupervised texture segmentation.pdf

  13. Loops in hierarchical channel networks

    Science.gov (United States)

    Katifori, Eleni; Magnasco, Marcelo

    2012-02-01

    Nature provides us with many examples of planar distribution and structural networks having dense sets of closed loops. An archetype of this form of network organization is the vasculature of dicotyledonous leaves, which showcases a hierarchically-nested architecture. Although a number of methods have been proposed to measure aspects of the structure of such networks, a robust metric to quantify their hierarchical organization is still lacking. We present an algorithmic framework that allows mapping loopy networks to binary trees, preserving in the connectivity of the trees the architecture of the original graph. We apply this framework to investigate computer generated and natural graphs extracted from digitized images of dicotyledonous leaves and animal vasculature. We calculate various metrics on the corresponding trees and discuss the relationship of these quantities to the architectural organization of the original graphs. This algorithmic framework decouples the geometric information from the metric topology (connectivity and edge weight) and it ultimately allows us to perform a quantitative statistical comparison between predictions of theoretical models and naturally occurring loopy graphs.

  14. Hierarchical modeling of molecular energies using a deep neural network

    Science.gov (United States)

    Lubbers, Nicholas; Smith, Justin S.; Barros, Kipton

    2018-06-01

    We introduce the Hierarchically Interacting Particle Neural Network (HIP-NN) to model molecular properties from datasets of quantum calculations. Inspired by a many-body expansion, HIP-NN decomposes properties, such as energy, as a sum over hierarchical terms. These terms are generated from a neural network—a composition of many nonlinear transformations—acting on a representation of the molecule. HIP-NN achieves the state-of-the-art performance on a dataset of 131k ground state organic molecules and predicts energies with 0.26 kcal/mol mean absolute error. With minimal tuning, our model is also competitive on a dataset of molecular dynamics trajectories. In addition to enabling accurate energy predictions, the hierarchical structure of HIP-NN helps to identify regions of model uncertainty.

  15. A nontransferring dry adhesive with hierarchical polymer nanohairs.

    Science.gov (United States)

    Jeong, Hoon Eui; Lee, Jin-Kwan; Kim, Hong Nam; Moon, Sang Heup; Suh, Kahp Y

    2009-04-07

    We present a simple yet robust method for fabricating angled, hierarchically patterned high-aspect-ratio polymer nanohairs to generate directionally sensitive dry adhesives. The slanted polymeric nanostructures were molded from an etched polySi substrate containing slanted nanoholes. An angled etching technique was developed to fabricate slanted nanoholes with flat tips by inserting an etch-stop layer of silicon dioxide. This unique etching method was equipped with a Faraday cage system to control the ion-incident angles in the conventional plasma etching system. The polymeric nanohairs were fabricated with tailored leaning angles, sizes, tip shapes, and hierarchical structures. As a result of controlled leaning angle and bulged flat top of the nanohairs, the replicated, slanted nanohairs showed excellent directional adhesion, exhibiting strong shear attachment (approximately 26 N/cm(2) in maximum) in the angled direction and easy detachment (approximately 2.2 N/cm(2)) in the opposite direction, with a hysteresis value of approximately 10. In addition to single scale nanohairs, monolithic, micro-nanoscale combined hierarchical hairs were also fabricated by using a 2-step UV-assisted molding technique. These hierarchical nanoscale patterns maintained their adhesive force even on a rough surface (roughness <20 microm) because of an increase in the contact area by the enhanced height of hierarchy, whereas simple nanohairs lost their adhesion strength. To demonstrate the potential applications of the adhesive patch, the dry adhesive was used to transport a large-area glass (47.5 x 37.5 cm(2), second-generation TFT-LCD glass), which could replace the current electrostatic transport/holding system with further optimization.

  16. A nontransferring dry adhesive with hierarchical polymer nanohairs

    KAUST Repository

    Jeong, H. E.

    2009-03-20

    We present a simple yet robust method for fabricating angled, hierarchically patterned high-aspect-ratio polymer nanohairs to generate directionally sensitive dry adhesives. The slanted polymeric nanostructures were molded from an etched polySi substrate containing slanted nanoholes. An angled etching technique was developed to fabricate slanted nanoholes with flat tips by inserting an etch-stop layer of silicon dioxide. This unique etching method was equipped with a Faraday cage system to control the ion-incident angles in the conventional plasma etching system. The polymeric nanohairs were fabricated with tailored leaning angles, sizes, tip shapes, and hierarchical structures. As a result of controlled leaning angle and bulged flat top of the nanohairs, the replicated, slanted nanohairs showed excellent directional adhesion, exhibiting strong shear attachment (approximately 26 N/cm(2) in maximum) in the angled direction and easy detachment (approximately 2.2 N/cm(2)) in the opposite direction, with a hysteresis value of approximately 10. In addition to single scale nanohairs, monolithic, micro-nanoscale combined hierarchical hairs were also fabricated by using a 2-step UV-assisted molding technique. These hierarchical nanoscale patterns maintained their adhesive force even on a rough surface (roughness <20 microm) because of an increase in the contact area by the enhanced height of hierarchy, whereas simple nanohairs lost their adhesion strength. To demonstrate the potential applications of the adhesive patch, the dry adhesive was used to transport a large-area glass (47.5 x 37.5 cm(2), second-generation TFT-LCD glass), which could replace the current electrostatic transport/holding system with further optimization.

  17. Convex Clustering: An Attractive Alternative to Hierarchical Clustering

    Science.gov (United States)

    Chen, Gary K.; Chi, Eric C.; Ranola, John Michael O.; Lange, Kenneth

    2015-01-01

    The primary goal in cluster analysis is to discover natural groupings of objects. The field of cluster analysis is crowded with diverse methods that make special assumptions about data and address different scientific aims. Despite its shortcomings in accuracy, hierarchical clustering is the dominant clustering method in bioinformatics. Biologists find the trees constructed by hierarchical clustering visually appealing and in tune with their evolutionary perspective. Hierarchical clustering operates on multiple scales simultaneously. This is essential, for instance, in transcriptome data, where one may be interested in making qualitative inferences about how lower-order relationships like gene modules lead to higher-order relationships like pathways or biological processes. The recently developed method of convex clustering preserves the visual appeal of hierarchical clustering while ameliorating its propensity to make false inferences in the presence of outliers and noise. The solution paths generated by convex clustering reveal relationships between clusters that are hidden by static methods such as k-means clustering. The current paper derives and tests a novel proximal distance algorithm for minimizing the objective function of convex clustering. The algorithm separates parameters, accommodates missing data, and supports prior information on relationships. Our program CONVEXCLUSTER incorporating the algorithm is implemented on ATI and nVidia graphics processing units (GPUs) for maximal speed. Several biological examples illustrate the strengths of convex clustering and the ability of the proximal distance algorithm to handle high-dimensional problems. CONVEXCLUSTER can be freely downloaded from the UCLA Human Genetics web site at http://www.genetics.ucla.edu/software/ PMID:25965340

  18. Hierarchical structure of stock price fluctuations in financial markets

    International Nuclear Information System (INIS)

    Gao, Ya-Chun; Cai, Shi-Min; Wang, Bing-Hong

    2012-01-01

    The financial market and turbulence have been broadly compared on account of the same quantitative methods and several common stylized facts they share. In this paper, the She–Leveque (SL) hierarchy, proposed to explain the anomalous scaling exponents deviating from Kolmogorov monofractal scaling of the velocity fluctuation in fluid turbulence, is applied to study and quantify the hierarchical structure of stock price fluctuations in financial markets. We therefore observed certain interesting results: (i) the hierarchical structure related to multifractal scaling generally presents in all the stock price fluctuations we investigated. (ii) The quantitatively statistical parameters that describe SL hierarchy are different between developed financial markets and emerging ones, distinctively. (iii) For the high-frequency stock price fluctuation, the hierarchical structure varies with different time periods. All these results provide a novel analogy in turbulence and financial market dynamics and an insight to deeply understand multifractality in financial markets. (paper)

  19. Ways of looking ahead: hierarchical planning in language production.

    Science.gov (United States)

    Lee, Eun-Kyung; Brown-Schmidt, Sarah; Watson, Duane G

    2013-12-01

    It is generally assumed that language production proceeds incrementally, with chunks of linguistic structure planned ahead of speech. Extensive research has examined the scope of language production and suggests that the size of planned chunks varies across contexts (Ferreira & Swets, 2002; Wagner & Jescheniak, 2010). By contrast, relatively little is known about the structure of advance planning, specifically whether planning proceeds incrementally according to the surface structure of the utterance, or whether speakers plan according to the hierarchical relationships between utterance elements. In two experiments, we examine the structure and scope of lexical planning in language production using a picture description task. Analyses of speech onset times and word durations show that speakers engage in hierarchical planning such that structurally dependent lexical items are planned together and that hierarchical planning occurs for both direct and indirect dependencies. Copyright © 2013 Elsevier B.V. All rights reserved.

  20. Synthesis of hierarchical worm-like SnO2@C aggregates and their enhanced lithium storage properties

    International Nuclear Information System (INIS)

    Wu, Zhen-Guo; Li, Jun-Tao; Zhong, Yan-Jun; Liu, Jie; Guo, Xiao-Dong; Huang, Ling; Zhong, Ben-He; Sun, Shi-Gang

    2015-01-01

    Highlights: • The hierarchical worm-like SnO 2 @C aggregates were synthesized. • The hierarchical worm-like SnO 2 @C unit is assembled by nanowires. • The cycling performances of SnO 2 @C aggregates are improved. • A capacity of 477.0 mA h g −1 at 400 mA g −1 could be obtained after 60 cycles. - Abstract: The present paper reports a synthetic strategy of hierarchical worm-like SnO 2 @C aggregates with enhanced electrochemical performances. Specifically, a glucose-assisted hydrothermal treatment of the intermediate Co–Sn alloy nanoparticles, which were formed by carbothermal reduction of mixed commercial SnO 2 and Co 3 O 4 nanoparticles. The SnO 2 @C sample exhibits enhanced cycling performance in comparison with raw commercial SnO 2 nanoparticles and intermediate Co–Sn alloy nanoparticles when used as anode of lithium ion battery. A stable capacity of 533.6 mA h g −1 at 100 mA g −1 and 477.0 mA h g −1 at 400 mA g −1 remains after 60 cycles. When the current density increases to 1600 mA g −1 , the SnO 2 @C sample still deliver a high capacity of 384.2 mA h g −1 . The superior electrochemical performances could be attributed to the synergistic effect of unique worm-like aggregates structure and carbon surface-layer, which facilitate the electron transportation and buffer the large volume change

  1. Multiple simultaneous fault diagnosis via hierarchical and single artificial neural networks

    International Nuclear Information System (INIS)

    Eslamloueyan, R.; Shahrokhi, M.; Bozorgmehri, R.

    2003-01-01

    Process fault diagnosis involves interpreting the current status of the plant given sensor reading and process knowledge. There has been considerable work done in this area with a variety of approaches being proposed for process fault diagnosis. Neural networks have been used to solve process fault diagnosis problems in chemical process, as they are well suited for recognizing multi-dimensional nonlinear patterns. In this work, the use of Hierarchical Artificial Neural Networks in diagnosing the multi-faults of a chemical process are discussed and compared with that of Single Artificial Neural Networks. The lower efficiency of Hierarchical Artificial Neural Networks , in comparison to Single Artificial Neural Networks, in process fault diagnosis is elaborated and analyzed. Also, the concept of a multi-level selection switch is presented and developed to improve the performance of hierarchical artificial neural networks. Simulation results indicate that application of multi-level selection switch increase the performance of the hierarchical artificial neural networks considerably

  2. An Improved Hierarchical Genetic Algorithm for Sheet Cutting Scheduling with Process Constraints

    Directory of Open Access Journals (Sweden)

    Yunqing Rao

    2013-01-01

    Full Text Available For the first time, an improved hierarchical genetic algorithm for sheet cutting problem which involves n cutting patterns for m non-identical parallel machines with process constraints has been proposed in the integrated cutting stock model. The objective of the cutting scheduling problem is minimizing the weighted completed time. A mathematical model for this problem is presented, an improved hierarchical genetic algorithm (ant colony—hierarchical genetic algorithm is developed for better solution, and a hierarchical coding method is used based on the characteristics of the problem. Furthermore, to speed up convergence rates and resolve local convergence issues, a kind of adaptive crossover probability and mutation probability is used in this algorithm. The computational result and comparison prove that the presented approach is quite effective for the considered problem.

  3. An improved hierarchical genetic algorithm for sheet cutting scheduling with process constraints.

    Science.gov (United States)

    Rao, Yunqing; Qi, Dezhong; Li, Jinling

    2013-01-01

    For the first time, an improved hierarchical genetic algorithm for sheet cutting problem which involves n cutting patterns for m non-identical parallel machines with process constraints has been proposed in the integrated cutting stock model. The objective of the cutting scheduling problem is minimizing the weighted completed time. A mathematical model for this problem is presented, an improved hierarchical genetic algorithm (ant colony--hierarchical genetic algorithm) is developed for better solution, and a hierarchical coding method is used based on the characteristics of the problem. Furthermore, to speed up convergence rates and resolve local convergence issues, a kind of adaptive crossover probability and mutation probability is used in this algorithm. The computational result and comparison prove that the presented approach is quite effective for the considered problem.

  4. Convenient and large-scale synthesis of nitrogen-rich hierarchical porous carbon spheres for supercapacitors and CO2 capture

    Science.gov (United States)

    Chang, Binbin; Zhang, Shouren; Yin, Hang; Yang, Baocheng

    2017-08-01

    Herein, considering the great potential of nitrogen-doped hierarchical porous carbons in energy storage and CO2 capture, we designed a convenient and easily large-scale production strategy for preparing nitrogen-doped hierarchical porous carbon sphere (NHPCS) materials. In this synthesis route, spherical resorcinol-formaldehyde (RF) resins were selected as carbon precursor, and then the ZnCl2-impregnated RF resin spheres were carbonized in a NH3 atmosphere at a temperature range of 600-800 °C. During the one-step heat-treatment process, nitrogen atom could be efficiently incorporated into the carbon skeleton, and the interconnected and hierarchical pore structure with different micro/mesopore proportion could be generated and tuned by adjusting the activating agent ZnCl2 dosage and carbonization temperature. The resultant nitrogen-doped hierarchical porous carbon sphere materials exhibited a satisfactory charge storage capacity, and the optimal sample of NHPCS-2-8 with a high mesopore proportion obtained at 800 °C with a ZnCl2/RF mass ratio of 2:1 presented a specific capacitance of 273.8 F g-1 at a current density of 0.5 A g-1. More importantly, the assembled NHPCS-2-8-based symmetric capacitor displayed a high energy density of 17.2 Wh kg-1 at a power density of 178.9 W kg-1 within a voltage window of 0 ∼ 1.8 V in 0.5 M Na2SO4 aqueous electrolyte. In addition, the CO2 capture application of these NHPCS materials was also explored, and the optimal sample of NHPCS-0-8 with a large micropore proportion prepared at 800 °C exhibited an exceptional CO2 uptake capacity at ambient pressures of up to 4.23 mmol g-1 at 0 °C.

  5. Urban pattern: Layout design by hierarchical domain splitting

    KAUST Repository

    Yang, Yongliang; Wang, Jun; Vouga, Etienne; Wonka, Peter

    2013-01-01

    We present a framework for generating street networks and parcel layouts. Our goal is the generation of high-quality layouts that can be used for urban planning and virtual environments. We propose a solution based on hierarchical domain splitting using two splitting types: streamline-based splitting, which splits a region along one or multiple streamlines of a cross field, and template-based splitting, which warps pre-designed templates to a region and uses the interior geometry of the template as the splitting lines. We combine these two splitting approaches into a hierarchical framework, providing automatic and interactive tools to explore the design space.

  6. Urban pattern: Layout design by hierarchical domain splitting

    KAUST Repository

    Yang, Yongliang

    2013-11-06

    We present a framework for generating street networks and parcel layouts. Our goal is the generation of high-quality layouts that can be used for urban planning and virtual environments. We propose a solution based on hierarchical domain splitting using two splitting types: streamline-based splitting, which splits a region along one or multiple streamlines of a cross field, and template-based splitting, which warps pre-designed templates to a region and uses the interior geometry of the template as the splitting lines. We combine these two splitting approaches into a hierarchical framework, providing automatic and interactive tools to explore the design space.

  7. Comparing hierarchical models via the marginalized deviance information criterion.

    Science.gov (United States)

    Quintero, Adrian; Lesaffre, Emmanuel

    2018-07-20

    Hierarchical models are extensively used in pharmacokinetics and longitudinal studies. When the estimation is performed from a Bayesian approach, model comparison is often based on the deviance information criterion (DIC). In hierarchical models with latent variables, there are several versions of this statistic: the conditional DIC (cDIC) that incorporates the latent variables in the focus of the analysis and the marginalized DIC (mDIC) that integrates them out. Regardless of the asymptotic and coherency difficulties of cDIC, this alternative is usually used in Markov chain Monte Carlo (MCMC) methods for hierarchical models because of practical convenience. The mDIC criterion is more appropriate in most cases but requires integration of the likelihood, which is computationally demanding and not implemented in Bayesian software. Therefore, we consider a method to compute mDIC by generating replicate samples of the latent variables that need to be integrated out. This alternative can be easily conducted from the MCMC output of Bayesian packages and is widely applicable to hierarchical models in general. Additionally, we propose some approximations in order to reduce the computational complexity for large-sample situations. The method is illustrated with simulated data sets and 2 medical studies, evidencing that cDIC may be misleading whilst mDIC appears pertinent. Copyright © 2018 John Wiley & Sons, Ltd.

  8. Moisture condensation behavior of hierarchically carbon nanotube-grafted carbon nanofibers.

    Science.gov (United States)

    Park, Kyu-Min; Lee, Byoung-Sun; Youk, Ji Ho; Lee, Jinyong; Yu, Woong-Reol

    2013-11-13

    Hierarchical micro/nanosurfaces with nanoscale roughness on microscale uneven substrates have been the subject of much recent research interest because of phenomena such as superhydrophobicity. However, an understanding of the effect of the difference in the scale of the hierarchical entities, i.e., nanoscale roughness on microscale uneven substrates as opposed to nanoscale roughness on (a larger) nanoscale uneven surface, is still lacking. In this study, we investigated the effect of the difference in scale between the nano- and microscale features. We fabricated carbon nanotube-grafted carbon nanofibers (CNFs) by dispersing a catalyst precursor in poly (acrylonitrile) (PAN) solution, electrospinning the PAN/catalyst precursor solution, carbonization of electrospun PAN nanofibers, and direct growth of carbon nanotubes (CNTs) on the CNFs. We investigated the relationships between the catalyst concentrations, the size of catalyst nanoparticles on CNFs, and the sizes of CNFs and CNTs. Interestingly, the hydrophobic behavior of micro/nano and nano/nano hierarchical surfaces with water droplets was similar; however a significant difference in the water condensation behavior was observed. Water condensed into smaller droplets on the nano/nano hierarchical surface, causing it to dry much faster.

  9. Hierarchical TiN nanoparticles-assembled nanopillars for flexible supercapacitors with high volumetric capacitance.

    Science.gov (United States)

    Qin, Ping; Li, Xingxing; Gao, Biao; Fu, Jijiang; Xia, Lu; Zhang, Xuming; Huo, Kaifu; Shen, Wenli; Chu, Paul K

    2018-05-10

    Titanium nitride (TiN) is an attractive electrode material in fast charging/discharging supercapacitors because of its excellent conductivity. However, the low capacitance and mechanical brittleness of TiN restricts its further application in flexible supercapacitors with high energy density. Thus, it is still a challenge to rationally design TiN electrodes with both high electrochemical and mechanical properties. Herein, the hierarchical TiN nanoparticles-assembled nanopillars (H-TiN NPs) array as binder free electrodes were obtained by nitriding of hierarchical titanium dioxide (TiO2) nanopillars, which was produced by a simple hydrothermal treatment of anodic TiO2 nanotubes (NTs) array in water. The porous TiN nanoparticles connected to each other to form ordered nanopillar arrays, effectively providing larger specific surface area and more active sites for charge storage. The H-TiN NPs delivered a high volumetric capacitance of 120 F cm-3 at 0.83 A cm-3, which is better than that of TiN NTs arrays (69 F cm-3 at 0.83 A cm-3). After assembling into all-solid-state devices, the H-TiN NPs based supercapacitors exhibited outstanding volumetric capacitance of 5.9 F cm-3 at 0.02 A cm-3 and a high energy density of 0.53 mW h cm-3. Our results reveal a new strategy to optimize the supercapacitive performance of metal nitrides.

  10. Construction of a Hierarchical Architecture of Covalent Organic Frameworks via a Postsynthetic Approach.

    Science.gov (United States)

    Zhang, Gen; Tsujimoto, Masahiko; Packwood, Daniel; Duong, Nghia Tuan; Nishiyama, Yusuke; Kadota, Kentaro; Kitagawa, Susumu; Horike, Satoshi

    2018-02-21

    Covalent organic frameworks (COFs) represent an emerging class of crystalline porous materials that are constructed by the assembly of organic building blocks linked via covalent bonds. Several strategies have been developed for the construction of new COF structures; however, a facile approach to fabricate hierarchical COF architectures with controlled domain structures remains a significant challenge, and has not yet been achieved. In this study, a dynamic covalent chemistry (DCC)-based postsynthetic approach was employed at the solid-liquid interface to construct such structures. Two-dimensional imine-bonded COFs having different aromatic groups were prepared, and a homogeneously mixed-linker structure and a heterogeneously core-shell hollow structure were fabricated by controlling the reactivity of the postsynthetic reactions. Solid-state nuclear magnetic resonance (NMR) spectroscopy and transmission electron microscopy (TEM) confirmed the structures. COFs prepared by a postsynthetic approach exhibit several functional advantages compared with their parent phases. Their Brunauer-Emmett-Teller (BET) surface areas are 2-fold greater than those of their parent phases because of the higher crystallinity. In addition, the hydrophilicity of the material and the stepwise adsorption isotherms of H 2 O vapor in the hierarchical frameworks were precisely controlled, which was feasible because of the distribution of various domains of the two COFs by controlling the postsynthetic reaction. The approach opens new routes for constructing COF architectures with functionalities that are not possible in a single phase.

  11. Inferring on the Intentions of Others by Hierarchical Bayesian Learning

    Science.gov (United States)

    Diaconescu, Andreea O.; Mathys, Christoph; Weber, Lilian A. E.; Daunizeau, Jean; Kasper, Lars; Lomakina, Ekaterina I.; Fehr, Ernst; Stephan, Klaas E.

    2014-01-01

    Inferring on others' (potentially time-varying) intentions is a fundamental problem during many social transactions. To investigate the underlying mechanisms, we applied computational modeling to behavioral data from an economic game in which 16 pairs of volunteers (randomly assigned to “player” or “adviser” roles) interacted. The player performed a probabilistic reinforcement learning task, receiving information about a binary lottery from a visual pie chart. The adviser, who received more predictive information, issued an additional recommendation. Critically, the game was structured such that the adviser's incentives to provide helpful or misleading information varied in time. Using a meta-Bayesian modeling framework, we found that the players' behavior was best explained by the deployment of hierarchical learning: they inferred upon the volatility of the advisers' intentions in order to optimize their predictions about the validity of their advice. Beyond learning, volatility estimates also affected the trial-by-trial variability of decisions: participants were more likely to rely on their estimates of advice accuracy for making choices when they believed that the adviser's intentions were presently stable. Finally, our model of the players' inference predicted the players' interpersonal reactivity index (IRI) scores, explicit ratings of the advisers' helpfulness and the advisers' self-reports on their chosen strategy. Overall, our results suggest that humans (i) employ hierarchical generative models to infer on the changing intentions of others, (ii) use volatility estimates to inform decision-making in social interactions, and (iii) integrate estimates of advice accuracy with non-social sources of information. The Bayesian framework presented here can quantify individual differences in these mechanisms from simple behavioral readouts and may prove useful in future clinical studies of maladaptive social cognition. PMID:25187943

  12. Interneuronal Mechanism for Tinbergen’s Hierarchical Model of Behavioral Choice

    Science.gov (United States)

    Pirger, Zsolt; Crossley, Michael; László, Zita; Naskar, Souvik; Kemenes, György; O’Shea, Michael; Benjamin, Paul R.; Kemenes, Ildikó

    2014-01-01

    Summary Recent studies of behavioral choice support the notion that the decision to carry out one behavior rather than another depends on the reconfiguration of shared interneuronal networks [1]. We investigated another decision-making strategy, derived from the classical ethological literature [2, 3], which proposes that behavioral choice depends on competition between autonomous networks. According to this model, behavioral choice depends on inhibitory interactions between incompatible hierarchically organized behaviors. We provide evidence for this by investigating the interneuronal mechanisms mediating behavioral choice between two autonomous circuits that underlie whole-body withdrawal [4, 5] and feeding [6] in the pond snail Lymnaea. Whole-body withdrawal is a defensive reflex that is initiated by tactile contact with predators. As predicted by the hierarchical model, tactile stimuli that evoke whole-body withdrawal responses also inhibit ongoing feeding in the presence of feeding stimuli. By recording neurons from the feeding and withdrawal networks, we found no direct synaptic connections between the interneuronal and motoneuronal elements that generate the two behaviors. Instead, we discovered that behavioral choice depends on the interaction between two unique types of interneurons with asymmetrical synaptic connectivity that allows withdrawal to override feeding. One type of interneuron, the Pleuro-Buccal (PlB), is an extrinsic modulatory neuron of the feeding network that completely inhibits feeding when excited by touch-induced monosynaptic input from the second type of interneuron, Pedal-Dorsal12 (PeD12). PeD12 plays a critical role in behavioral choice by providing a synaptic pathway joining the two behavioral networks that underlies the competitive dominance of whole-body withdrawal over feeding. PMID:25155505

  13. Do pseudo-absence selection strategies influence species distribution models and their predictions? An information-theoretic approach based on simulated data

    Directory of Open Access Journals (Sweden)

    Guisan Antoine

    2009-04-01

    Full Text Available Abstract Background Multiple logistic regression is precluded from many practical applications in ecology that aim to predict the geographic distributions of species because it requires absence data, which are rarely available or are unreliable. In order to use multiple logistic regression, many studies have simulated "pseudo-absences" through a number of strategies, but it is unknown how the choice of strategy influences models and their geographic predictions of species. In this paper we evaluate the effect of several prevailing pseudo-absence strategies on the predictions of the geographic distribution of a virtual species whose "true" distribution and relationship to three environmental predictors was predefined. We evaluated the effect of using a real absences b pseudo-absences selected randomly from the background and c two-step approaches: pseudo-absences selected from low suitability areas predicted by either Ecological Niche Factor Analysis: (ENFA or BIOCLIM. We compared how the choice of pseudo-absence strategy affected model fit, predictive power, and information-theoretic model selection results. Results Models built with true absences had the best predictive power, best discriminatory power, and the "true" model (the one that contained the correct predictors was supported by the data according to AIC, as expected. Models based on random pseudo-absences had among the lowest fit, but yielded the second highest AUC value (0.97, and the "true" model was also supported by the data. Models based on two-step approaches had intermediate fit, the lowest predictive power, and the "true" model was not supported by the data. Conclusion If ecologists wish to build parsimonious GLM models that will allow them to make robust predictions, a reasonable approach is to use a large number of randomly selected pseudo-absences, and perform model selection based on an information theoretic approach. However, the resulting models can be expected to have

  14. The Revised Hierarchical Model: A critical review and assessment

    OpenAIRE

    Kroll, Judith F.; van Hell, Janet G.; Tokowicz, Natasha; Green, David W.

    2010-01-01

    Brysbaert and Duyck (2009) suggest that it is time to abandon the Revised Hierarchical Model (Kroll and Stewart, 1994) in favor of connectionist models such as BIA+ (Dijkstra and Van Heuven, 2002) that more accurately account for the recent evidence on nonselective access in bilingual word recognition. In this brief response, we first review the history of the Revised Hierarchical Model (RHM), consider the set of issues that it was proposed to address, and then evaluate the evidence that supp...

  15. Cluster Based Hierarchical Routing Protocol for Wireless Sensor Network

    OpenAIRE

    Rashed, Md. Golam; Kabir, M. Hasnat; Rahim, Muhammad Sajjadur; Ullah, Shaikh Enayet

    2012-01-01

    The efficient use of energy source in a sensor node is most desirable criteria for prolong the life time of wireless sensor network. In this paper, we propose a two layer hierarchical routing protocol called Cluster Based Hierarchical Routing Protocol (CBHRP). We introduce a new concept called head-set, consists of one active cluster head and some other associate cluster heads within a cluster. The head-set members are responsible for control and management of the network. Results show that t...

  16. Hierarchical structure in the distribution of galaxies

    International Nuclear Information System (INIS)

    Schulman, L.S.; Seiden, P.E.; Technion - Israel Institute of Technology, Haifa; IBM Thomas J. Watson Research Center, Yorktown Heights, NY)

    1986-01-01

    The distribution of galaxies has a hierarchical structure with power-law correlations. This is usually thought to arise from gravity alone acting on an originally uniform distributioon. If, however, the original process of galaxy formation occurs through the stimulated birth of one galaxy due to a nearby recently formed galaxy, and if this process occurs near its percolation threshold, then a hierarchical structure with power-law correlations arises at the time of galaxy formation. If subsequent gravitational evolution within an expanding cosmology is such as to retain power-law correlations, the initial r exp -1 dropoff can steepen to the observed r exp -1.8. The distribution of galaxies obtained by this process produces clustering and voids, as observed. 23 references

  17. Subject-Verb Agreement in Children and Adults: Serial or Hierarchical Processing?

    Science.gov (United States)

    Negro, Isabelle; Chanquoy, Lucile; Fayol, Michel; Louis-Sidney, Maryse

    2005-01-01

    Two processes, serial and hierarchical, are generally opposed to account for grammatical encoding in language production. In a developmental perspective, the question addressed here is whether the subject-verb agreement during writing is computed serially, once the words are linearly ordered in the sentence, or hierarchically, as soon as the…

  18. A hierarchical spatiotemporal analog forecasting model for count data.

    Science.gov (United States)

    McDermott, Patrick L; Wikle, Christopher K; Millspaugh, Joshua

    2018-01-01

    Analog forecasting is a mechanism-free nonlinear method that forecasts a system forward in time by examining how past states deemed similar to the current state moved forward. Previous applications of analog forecasting has been successful at producing robust forecasts for a variety of ecological and physical processes, but it has typically been presented in an empirical or heuristic procedure, rather than as a formal statistical model. The methodology presented here extends the model-based analog method of McDermott and Wikle (Environmetrics, 27, 2016, 70) by placing analog forecasting within a fully hierarchical statistical framework that can accommodate count observations. Using a Bayesian approach, the hierarchical analog model is able to quantify rigorously the uncertainty associated with forecasts. Forecasting waterfowl settling patterns in the northwestern United States and Canada is conducted by applying the hierarchical analog model to a breeding population survey dataset. Sea surface temperature (SST) in the Pacific Ocean is used to help identify potential analogs for the waterfowl settling patterns.

  19. Detecting the overlapping and hierarchical community structure in complex networks

    International Nuclear Information System (INIS)

    Lancichinetti, Andrea; Fortunato, Santo; Kertesz, Janos

    2009-01-01

    Many networks in nature, society and technology are characterized by a mesoscopic level of organization, with groups of nodes forming tightly connected units, called communities or modules, that are only weakly linked to each other. Uncovering this community structure is one of the most important problems in the field of complex networks. Networks often show a hierarchical organization, with communities embedded within other communities; moreover, nodes can be shared between different communities. Here, we present the first algorithm that finds both overlapping communities and the hierarchical structure. The method is based on the local optimization of a fitness function. Community structure is revealed by peaks in the fitness histogram. The resolution can be tuned by a parameter enabling different hierarchical levels of organization to be investigated. Tests on real and artificial networks give excellent results.

  20. New insight in magnetic saturation behavior of nickel hierarchical structures

    Science.gov (United States)

    Ma, Ji; Zhang, Jianxing; Liu, Chunting; Chen, Kezheng

    2017-09-01

    It is unanimously accepted that non-ferromagnetic inclusions in a ferromagnetic system will lower down total saturation magnetization in unit of emu/g. In this study, ;lattice strain; was found to be another key factor to have critical impact on magnetic saturation behavior of the system. The lattice strain determined assembling patterns of primary nanoparticles in hierarchical structures and was intimately related with the formation process of these architectures. Therefore, flower-necklace-like and cauliflower-like nickel hierarchical structures were used as prototype systems to evidence the relationship between assembling patterns of primary nanoparticles and magnetic saturation behaviors of these architectures. It was found that the influence of lattice strain on saturation magnetization outperformed that of non-ferromagnetic inclusions in these hierarchical structures. This will enable new insights into fundamental understanding of related magnetic effects.

  1. Enhanced lithium storage performances of hierarchical hollow MoS₂ nanoparticles assembled from nanosheets.

    Science.gov (United States)

    Wang, Meng; Li, Guangda; Xu, Huayun; Qian, Yitai; Yang, Jian

    2013-02-01

    MoS(2), because of its layered structure and high theoretical capacity, has been regarded as a potential candidate for electrode materials in lithium secondary batteries. But it suffers from the poor cycling stability and low rate capability. Here, hierarchical hollow nanoparticles of MoS(2) nanosheets with an increased interlayer distance are synthesized by a simple solvothermal reaction at a low temperature. The formation of hierarchical hollow nanoparticles is based on the intermediate, K(2)NaMoO(3)F(3), as a self-sacrificed template. These hollow nanoparticles exhibit a reversible capacity of 902 mA h g(-1) at 100 mA g(-1) after 80 cycles, much higher than the solid counterpart. At a current density of 1000 mA g(-1), the reversible capacity of the hierarchical hollow nanoparticles could be still maintained at 780 mAh g(-1). The enhanced lithium storage performances of the hierarchical hollow nanoparticles in reversible capacities, cycling stability and rate performances can be attributed to their hierarchical surface, hollow structure feature and increased layer distance of S-Mo-S. Hierarchical hollow nanoparticles as an ensemble of these features, could be applied to other electrode materials for the superior electrochemical performance.

  2. Runtime Concepts of Hierarchical Software Components

    Czech Academy of Sciences Publication Activity Database

    Bureš, Tomáš; Hnětynka, P.; Plášil, František

    2007-01-01

    Roč. 8, special (2007), s. 454-463 ISSN 1525-9293 R&D Projects: GA AV ČR 1ET400300504 Institutional research plan: CEZ:AV0Z10300504 Keywords : component-based development * hierarchical components * connectors * controlers * runtime environment Subject RIV: JC - Computer Hardware ; Software

  3. Hierarchical production planning for consumer goods

    NARCIS (Netherlands)

    Kok, de A.G.

    1990-01-01

    Abstract In this paper the mathematical logic behind a hierarchical planning procedure is discussed. The planning procedure is used to derive production volumes of consumer products. The essence of the planning procedure is that first a commitment is made concerning the production volume for a

  4. Hierarchically Organized Behavior and Its Neural Foundations: A Reinforcement Learning Perspective

    Science.gov (United States)

    Botvinick, Matthew M.; Niv, Yael; Barto, Andrew C.

    2009-01-01

    Research on human and animal behavior has long emphasized its hierarchical structure--the divisibility of ongoing behavior into discrete tasks, which are comprised of subtask sequences, which in turn are built of simple actions. The hierarchical structure of behavior has also been of enduring interest within neuroscience, where it has been widely…

  5. Hierarchical zeolites from class F coal fly ash

    Science.gov (United States)

    Chitta, Pallavi

    Fly ash, a coal combustion byproduct is classified as types class C and class F. Class C fly ash is traditionally recycled for concrete applications and Class F fly ash often disposed in landfills. Class F poses an environmental hazard due to disposal and leaching of heavy metals into ground water and is important to be recycled in order to mitigate the environmental challenges. A major recycling option is to reuse the fly ash as a low-cost raw material for the production of crystalline zeolites, which serve as catalysts, detergents and adsorbents in the chemical industry. Most of the prior literature of fly ash conversion to zeolites does not focus on creating high zeolite surface area zeolites specifically with hierarchical pore structure, which are very important properties in developing a heterogeneous catalyst for catalysis applications. This research work aids in the development of an economical process for the synthesis of high surface area hierarchical zeolites from class F coal fly ash. In this work, synthesis of zeolites from fly ash using classic hydrothermal treatment approach and fusion pretreatment approach were examined. The fusion pretreatment method led to higher extent of dissolution of silica from quartz and mullite phases, which in turn led to higher surface area and pore size of the zeolite. A qualitative kinetic model developed here attributes the difference in silica content to Si/Al ratio of the beginning fraction of fly ash. At near ambient crystallization temperatures and longer crystallization times, the zeolite formed is a hierarchical faujasite with high surface area of at least 360 m2/g. This work enables the large scale recycling of class F coal fly ash to produce zeolites and mitigate environmental concerns. Design of experiments was used to predict surface area and pore sizes of zeolites - thus obviating the need for intense experimentation. The hierarchical zeolite catalyst supports tested for CO2 conversion, yielded hydrocarbons

  6. Stress generation and hierarchical fracturing in reactive systems

    Science.gov (United States)

    Jamtveit, B.; Iyer, K.; Royne, A.; Malthe-Sorenssen, A.; Mathiesen, J.; Feder, J.

    2007-12-01

    Hierarchical fracture patterns are the result of a slowly driven fracturing process that successively divides the rocks into smaller domains. In quasi-2D systems, such fracture patterns are characterized by four sided domains, and T-junctions where new fractures stop at right angles to pre-existing fractures. We describe fracturing of mm to dm thick enstatite layers in a dunite matrix from the Leka ophiolite complex in Norway. The fracturing process is driven by expansion of the dunite matrix during serpentinization. The cumulative distributions of fracture lengths show a scaling behavior that lies between a log - normal and power law (fractal) distribution. This is consistent with a simple fragmentation model in which domains are divided according to a 'top hat' distribution of new fracture positions within unfractured domains. Reaction-assisted hierarchical fracturing is also likely to be responsible for other (3-D) structures commonly observed in serpentinized ultramafic rocks, including the mesh-textures observed in individual olivine grains, and the high abundance of rectangular domains at a wide range of scales. Spectacular examples of 3-D hierarchical fracture patterns also form during the weathering of basaltic intrusions (dolerites). Incipient chemical weathering of dolerites in the Karoo Basin in South Africa occurs around water- filled fractures, originally produced by thermal contraction or by externally imposed stresses. This chemical weathering causes local expansion of the rock matrix and generates elastic stresses. On a mm to cm scale, these stresses lead to mechanical layer-by-layer spalling, producing the characteristic spheroidal weathering patterns. However, our field observations and computer simulations demonstrate that in confined environments, the spalling process alone is unable to relieve the elastic stresses. In such cases, chemical weathering drives a much larger scale hierarchical fracturing process in which fresh dolerite undergoes a

  7. Effect of Job Autonomy Upon Organizational Commitment of Employees at Different Hierarchical Level

    Directory of Open Access Journals (Sweden)

    Shalini Sisodia

    2013-10-01

    Full Text Available The main aim of the present study was to examine the effect of job autonomy upon organizational commitment of employees at different hierarchical level. A study was made on randomly selected 100 male employees who work in different organizations in Agra, who were administered Organizational Commitment Scale (by Allen & Meyer, 1990 and Job Autonomy Scale (by Das, Arora, & Singhal, 2000. On the basis of median of the job autonomy scores, the sample was divided into two groups (1 high job autonomy group and (2 low job autonomy group and on the basis of hierarchical level, the employees were divided into two groups (1 50 high hierarchical level employees’ including managers, etc. and (2 50 low hierarchical level employees, e.g. clerical staff, etc. The 2x2 factorial design was formed for this purpose and four groups of employees were formed (1 high hierarchy, high autonomy group (2 high hierarchy, low autonomy group(3 low hierarchy, high autonomy group and (4 low hierarchy, low autonomy group. A two-way analysis of variance was employed to compare the level of organizational commitment of each of the four groups. There is a significant difference found between job commitment of employees with high and low job autonomy (F = 4.670, p < .05. There is a significant difference found between job commitment of employees of high hierarchical group and those of low hierarchical group (F = 40.691, p < .01 and significant interaction effect found between job autonomy and hierarchical level upon organizational commitment of employees (F = 6.114, p < .05.

  8. A novel hierarchical ZnO disordered/ordered bilayer nanostructured film for dye sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Yamin, E-mail: yaminfengccnuphy@outlook.com; Wu, Fei; Jiang, Jian; Zhu, Jianhui; Fodjouong, Ghislain Joel; Meng, Gaoxiang; Xing, Yanmin; Wang, Wenwu; Huang, Xintang, E-mail: xthuang@phy.ccnu.edu.cn

    2013-12-25

    Graphical abstract: A novel hierarchical disordered/ordered bilayer ZnO nanostructured film in the length of 18 μm have been successfully synthesized on the FTO substrate; the hierarchical ZnO nanostructured film electrodes applied in DSSCs exhibit photoelectric conversion efficiency as high as 5.16%. Highlights: •A novel hierarchical ZnO structure film was fabricated on a FTO substrate. •Hierarchical ZnO film is applied as the electrodes for dye sensitized solar cells. •The film possess high specific surface area and fast electron transport effect. •The light-scattering effect of the hierarchical film is pronounced. •The energy conversion efficiency of hierarchical ZnO electrode reaches to 5.16%. -- Abstract: A novel hierarchical ZnO nanostructured film is synthesized via a chemical bath deposition (CBD) method followed by a treatment of thermal decomposition onto a fluorine-doped tin oxide (FTO) substrate. This hierarchical film is composed of disordered ZnO nanorods (NRs) (top layer) and ordered ZnO nanowires (NWs) (bottom layer). The products possess the following features such as high specific surface area, fast electron transport, and pronounced light-scattering effect, which are quite suitable for dye sensitized solar cells (DSSCs) applications. A light-to-electricity conversion efficiency of 5.16% is achieved when the hierarchical ZnO nanostructured film is used as the photoanode under 100 mW cm{sup −2} illumination. This efficiency is found to be much higher than that of the DSSCs with pure ordered ZnO NWs (1.45%) and disordered ZnO NRs (3.31%) photoanodes.

  9. A novel hierarchical ZnO disordered/ordered bilayer nanostructured film for dye sensitized solar cells

    International Nuclear Information System (INIS)

    Feng, Yamin; Wu, Fei; Jiang, Jian; Zhu, Jianhui; Fodjouong, Ghislain Joel; Meng, Gaoxiang; Xing, Yanmin; Wang, Wenwu; Huang, Xintang

    2013-01-01

    Graphical abstract: A novel hierarchical disordered/ordered bilayer ZnO nanostructured film in the length of 18 μm have been successfully synthesized on the FTO substrate; the hierarchical ZnO nanostructured film electrodes applied in DSSCs exhibit photoelectric conversion efficiency as high as 5.16%. Highlights: •A novel hierarchical ZnO structure film was fabricated on a FTO substrate. •Hierarchical ZnO film is applied as the electrodes for dye sensitized solar cells. •The film possess high specific surface area and fast electron transport effect. •The light-scattering effect of the hierarchical film is pronounced. •The energy conversion efficiency of hierarchical ZnO electrode reaches to 5.16%. -- Abstract: A novel hierarchical ZnO nanostructured film is synthesized via a chemical bath deposition (CBD) method followed by a treatment of thermal decomposition onto a fluorine-doped tin oxide (FTO) substrate. This hierarchical film is composed of disordered ZnO nanorods (NRs) (top layer) and ordered ZnO nanowires (NWs) (bottom layer). The products possess the following features such as high specific surface area, fast electron transport, and pronounced light-scattering effect, which are quite suitable for dye sensitized solar cells (DSSCs) applications. A light-to-electricity conversion efficiency of 5.16% is achieved when the hierarchical ZnO nanostructured film is used as the photoanode under 100 mW cm −2 illumination. This efficiency is found to be much higher than that of the DSSCs with pure ordered ZnO NWs (1.45%) and disordered ZnO NRs (3.31%) photoanodes

  10. Hierarchical unilamellar vesicles of controlled compositional heterogeneity.

    Directory of Open Access Journals (Sweden)

    Maik Hadorn

    Full Text Available Eukaryotic life contains hierarchical vesicular architectures (i.e. organelles that are crucial for material production and trafficking, information storage and access, as well as energy production. In order to perform specific tasks, these compartments differ among each other in their membrane composition and their internal cargo and also differ from the cell membrane and the cytosol. Man-made structures that reproduce this nested architecture not only offer a deeper understanding of the functionalities and evolution of organelle-bearing eukaryotic life but also allow the engineering of novel biomimetic technologies. Here, we show the newly developed vesicle-in-water-in-oil emulsion transfer preparation technique to result in giant unilamellar vesicles internally compartmentalized by unilamellar vesicles of different membrane composition and internal cargo, i.e. hierarchical unilamellar vesicles of controlled compositional heterogeneity. The compartmentalized giant unilamellar vesicles were subsequently isolated by a separation step exploiting the heterogeneity of the membrane composition and the encapsulated cargo. Due to the controlled, efficient, and technically straightforward character of the new preparation technique, this study allows the hierarchical fabrication of compartmentalized giant unilamellar vesicles of controlled compositional heterogeneity and will ease the development of eukaryotic cell mimics that resemble their natural templates as well as the fabrication of novel multi-agent drug delivery systems for combination therapies and complex artificial microreactors.

  11. Anisotropic and Hierarchical Porosity in Multifunctional Ceramics

    Science.gov (United States)

    Lichtner, Aaron Zev

    The performance of multifunctional porous ceramics is often hindered by the seemingly contradictory effects of porosity on both mechanical and non-structural properties and yet a sufficient body of knowledge linking microstructure to these properties does not exist. Using a combination of tailored anisotropic and hierarchical materials, these disparate effects may be reconciled. In this project, a systematic investigation of the processing, characterization and properties of anisotropic and isotropic hierarchically porous ceramics was conducted. The system chosen was a composite ceramic intended as the cathode for a solid oxide fuel cell (SOFC). Comprehensive processing investigations led to the development of approaches to make hierarchical, anisotropic porous microstructures using directional freeze-casting of well dispersed slurries. The effect of all the important processing parameters was investigated. This resulted in an ability to tailor and control the important microstructural features including the scale of the microstructure, the macropore size and total porosity. Comparable isotropic porous ceramics were also processed using fugitive pore formers. A suite of characterization techniques including x-ray tomography and 3-D sectional scanning electron micrographs (FIB-SEM) was used to characterize and quantify the green and partially sintered microstructures. The effect of sintering temperature on the microstructure was quantified and discrete element simulations (DEM) were used to explain the experimental observations. Finally, the comprehensive mechanical properties, at room temperature, were investigated, experimentally and using DEM, for the different microstructures.

  12. Growth Mechanism of Pumpkin-Shaped Vaterite Hierarchical Structures

    Science.gov (United States)

    Ma, Guobin; Xu, Yifei; Wang, Mu

    2015-03-01

    CaCO3-based biominerals possess sophisticated hierarchical structures and promising mechanical properties. Recent researches imply that vaterite may play an important role in formation of CaCO3-based biominerals. However, as a less common polymorph of CaCO3, the growth mechanism of vaterite remains not very clear. Here we report the growth of a pumpkin-shaped vaterite hierarchical structure with a six-fold symmetrical axis and lamellar microstructure. We demonstrate that the growth is controlled by supersaturation and the intrinsic crystallographic anisotropy of vaterite. For the scenario of high supersaturation, the nucleation rate is higher than the lateral extension rate, favoring the ``double-leaf'' spherulitic growth. Meanwhile, nucleation occurs preferentially in as determined by the crystalline structure of vaterite, modulating the grown products with a hexagonal symmetry. The results are beneficial for an in-depth understanding of the biomineralization of CaCO3. The growth mechanism may also be applicable to interpret the formation of similar hierarchical structures of other materials. The authors gratefully acknowledge the financial support from National Science Foundation of China (Grant Nos. 51172104 and 50972057) and National Key Basic Research Program of China (Grant No. 2010CB630705).

  13. Proposing a Hierarchical Utility Package with Reference to Mobile Advertising

    OpenAIRE

    Shalini N. Tripathi; Masood H. Siddiqui

    2011-01-01

    Mobile advertising is a powerful tool for direct and interactive marketing. However effective marketing requires examining consumers’ psyche. This study proposes a hierarchical utility package (in the consumers’ perception) with reference to mobile advertising, thus enhancing its acceptance. Confirmatory factor analysis revealed four consolidated utility dimensions (with reference to mobile advertising). Binary logistic regression was used to create a hierarchical utility package with res...

  14. The MIL-88A-Derived Fe3O4-Carbon Hierarchical Nanocomposites for Electrochemical Sensing

    Science.gov (United States)

    Wang, Li; Zhang, Yayun; Li, Xia; Xie, Yingzhen; He, Juan; Yu, Jie; Song, Yonghai

    2015-01-01

    Metal or metal oxides/carbon nanocomposites with hierarchical superstructures have become one of the most promising functional materials in sensor, catalysis, energy conversion, etc. In this work, novel hierarchical Fe3O4/carbon superstructures have been fabricated based on metal-organic frameworks (MOFs)-derived method. Three kinds of Fe-MOFs (MIL-88A) with different morphologies were prepared beforehand as templates, and then pyrolyzed to fabricate the corresponding novel hierarchical Fe3O4/carbon superstructures. The systematic studies on the thermal decomposition process of the three kinds of MIL-88A and the effect of template morphology on the products were carried out in detail. Scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy and thermal analysis were employed to investigate the hierarchical Fe3O4/carbon superstructures. Based on these resulted hierarchical Fe3O4/carbon superstructures, a novel and sensitive nonenzymatic N-acetyl cysteine sensor was developed. The porous and hierarchical superstructures and large surface area of the as-formed Fe3O4/carbon superstructures eventually contributed to the good electrocatalytic activity of the prepared sensor towards the oxidation of N-acetyl cysteine. The proposed preparation method of the hierarchical Fe3O4/carbon superstructures is simple, efficient, cheap and easy to mass production. It might open up a new way for hierarchical superstructures preparation. PMID:26387535

  15. Which, When, and How: Hierarchical Clustering with Human–Machine Cooperation

    Directory of Open Access Journals (Sweden)

    Huanyang Zheng

    2016-12-01

    Full Text Available Human–Machine Cooperations (HMCs can balance the advantages and disadvantages of human computation (accurate but costly and machine computation (cheap but inaccurate. This paper studies HMCs in agglomerative hierarchical clusterings, where the machine can ask the human some questions. The human will return the answers to the machine, and the machine will use these answers to correct errors in its current clustering results. We are interested in the machine’s strategy on handling the question operations, in terms of three problems: (1 Which question should the machine ask? (2 When should the machine ask the question (early or late? (3 How does the machine adjust the clustering result, if the machine’s mistake is found by the human? Based on the insights of these problems, an efficient algorithm is proposed with five implementation variations. Experiments on image clusterings show that the proposed algorithm can improve the clustering accuracy with few question operations.

  16. Hierarchical Bayesian modelling of mobility metrics for hazard model input calibration

    Science.gov (United States)

    Calder, Eliza; Ogburn, Sarah; Spiller, Elaine; Rutarindwa, Regis; Berger, Jim

    2015-04-01

    In this work we present a method to constrain flow mobility input parameters for pyroclastic flow models using hierarchical Bayes modeling of standard mobility metrics such as H/L and flow volume etc. The advantage of hierarchical modeling is that it can leverage the information in global dataset for a particular mobility metric in order to reduce the uncertainty in modeling of an individual volcano, especially important where individual volcanoes have only sparse datasets. We use compiled pyroclastic flow runout data from Colima, Merapi, Soufriere Hills, Unzen and Semeru volcanoes, presented in an open-source database FlowDat (https://vhub.org/groups/massflowdatabase). While the exact relationship between flow volume and friction varies somewhat between volcanoes, dome collapse flows originating from the same volcano exhibit similar mobility relationships. Instead of fitting separate regression models for each volcano dataset, we use a variation of the hierarchical linear model (Kass and Steffey, 1989). The model presents a hierarchical structure with two levels; all dome collapse flows and dome collapse flows at specific volcanoes. The hierarchical model allows us to assume that the flows at specific volcanoes share a common distribution of regression slopes, then solves for that distribution. We present comparisons of the 95% confidence intervals on the individual regression lines for the data set from each volcano as well as those obtained from the hierarchical model. The results clearly demonstrate the advantage of considering global datasets using this technique. The technique developed is demonstrated here for mobility metrics, but can be applied to many other global datasets of volcanic parameters. In particular, such methods can provide a means to better contain parameters for volcanoes for which we only have sparse data, a ubiquitous problem in volcanology.

  17. HIERARCHICAL ORGANIZATION OF INFORMATION, IN RELATIONAL DATABASES

    Directory of Open Access Journals (Sweden)

    Demian Horia

    2008-05-01

    Full Text Available In this paper I will present different types of representation, of hierarchical information inside a relational database. I also will compare them to find the best organization for specific scenarios.

  18. A Wireless Power Sharing Control Strategy for Hybrid Energy Storage Systems in DC Microgrids

    DEFF Research Database (Denmark)

    Yang, Jie; Jin, Xinmin; Wu, Xuezhi

    2017-01-01

    In order to compensate multiple time scales power fluctuation resulted from distributed energy resources and loads, hybrid energy storage systems are employed as the buffer unit in DC microgrid. In this paper, a wireless hierarchical control strategy is proposed to realize power sharing between...

  19. Three-Dimensional ZnO Hierarchical Nanostructures: Solution Phase Synthesis and Applications

    Directory of Open Access Journals (Sweden)

    Xiaoliang Wang

    2017-11-01

    Full Text Available Zinc oxide (ZnO nanostructures have been studied extensively in the past 20 years due to their novel electronic, photonic, mechanical and electrochemical properties. Recently, more attention has been paid to assemble nanoscale building blocks into three-dimensional (3D complex hierarchical structures, which not only inherit the excellent properties of the single building blocks but also provide potential applications in the bottom-up fabrication of functional devices. This review article focuses on 3D ZnO hierarchical nanostructures, and summarizes major advances in the solution phase synthesis, applications in environment, and electrical/electrochemical devices. We present the principles and growth mechanisms of ZnO nanostructures via different solution methods, with an emphasis on rational control of the morphology and assembly. We then discuss the applications of 3D ZnO hierarchical nanostructures in photocatalysis, field emission, electrochemical sensor, and lithium ion batteries. Throughout the discussion, the relationship between the device performance and the microstructures of 3D ZnO hierarchical nanostructures will be highlighted. This review concludes with a personal perspective on the current challenges and future research.

  20. Supervisory Control Strategy Development

    International Nuclear Information System (INIS)

    Gary D Storrick; Bojan Petrovic

    2007-01-01

    Task 4 of this collaborative effort between ORNL, Brazil, and Westinghouse for the International Nuclear Energy Research Initiative entitled 'Development of Advanced Instrumentation and Control for an Integrated Primary System Reactor' focused on the design of the hierarchical supervisory control for multiple-module units. The state of the IRIS plant design--specifically, the lack of a detailed secondary system design--made developing a detailed hierarchical control difficult at this time. However, other simultaneous and ongoing efforts have contributed to providing the needed information. This report summarizes the results achieved under Task 4 of this Financial Assistance Award. Section 1.2 describes the scope of this effort. Section 2 discusses the IRIS control functions. Next, it briefly reviews the current control concepts, and then reviews the maneuvering requirements for the IRIS plant. It closes by noting the benefits that automated sequences have in reducing operator workload. Section 3 examines reactor loading in the frequency domain to establish some guidelines for module operation, paying particular attention to strategies for using process steam for desalination and/or district heating. The final subsection discusses the implications for reactor control, and argues that using the envisioned percentage (up to 10%) of the NSSS thermal output for these purposes should not significantly affect the NSSS control strategies. Section 4 uses some very general economic assumptions to suggest how one should approach multi-module operation. It concludes that the well-known algorithms used for economic dispatching could be used to help manage a multi-unit IRIS site. Section 5 addresses the human performance factors of multi-module operation. Section 6 summarizes our conclusions

  1. The reflection of hierarchical cluster analysis of co-occurrence matrices in SPSS

    NARCIS (Netherlands)

    Zhou, Q.; Leng, F.; Leydesdorff, L.

    2015-01-01

    Purpose: To discuss the problems arising from hierarchical cluster analysis of co-occurrence matrices in SPSS, and the corresponding solutions. Design/methodology/approach: We design different methods of using the SPSS hierarchical clustering module for co-occurrence matrices in order to compare

  2. Hierarchical Diagnosis of Vocal Fold Disorders

    Science.gov (United States)

    Nikkhah-Bahrami, Mansour; Ahmadi-Noubari, Hossein; Seyed Aghazadeh, Babak; Khadivi Heris, Hossein

    This paper explores the use of hierarchical structure for diagnosis of vocal fold disorders. The hierarchical structure is initially used to train different second-level classifiers. At the first level normal and pathological signals have been distinguished. Next, pathological signals have been classified into neurogenic and organic vocal fold disorders. At the final level, vocal fold nodules have been distinguished from polyps in organic disorders category. For feature selection at each level of hierarchy, the reconstructed signal at each wavelet packet decomposition sub-band in 5 levels of decomposition with mother wavelet of (db10) is used to extract the nonlinear features of self-similarity and approximate entropy. Also, wavelet packet coefficients are used to measure energy and Shannon entropy features at different spectral sub-bands. Davies-Bouldin criterion has been employed to find the most discriminant features. Finally, support vector machines have been adopted as classifiers at each level of hierarchy resulting in the diagnosis accuracy of 92%.

  3. Quantum Ising model on hierarchical structures

    International Nuclear Information System (INIS)

    Lin Zhifang; Tao Ruibao.

    1989-11-01

    A quantum Ising chain with both the exchange couplings and the transverse fields arranged in a hierarchical way is considered. Exact analytical results for the critical line and energy gap are obtained. It is shown that when R 1 not= R 2 , where R 1 and R 2 are the hierarchical parameters for the exchange couplings and the transverse fields, respectively, the system undergoes a phase transition in a different universality class from the pure quantum Ising chain with R 1 =R 2 =1. On the other hand, when R 1 =R 2 =R, there exists a critical value R c dependent on the furcating number of the hierarchy. In case of R > R c , the system is shown to exhibit as Ising-like critical point with the critical behaviour the same as in the pure case, while for R c the system belongs to another universality class. (author). 19 refs, 2 figs

  4. Detailed Sponge City Planning Based on Hierarchical Fuzzy Decision-Making: A Case Study on Yangchen Lake

    Directory of Open Access Journals (Sweden)

    Junyu Zhang

    2017-11-01

    Full Text Available We proposed a Hierarchical Fuzzy Inference System (HFIS framework to offer better decision supports with fewer user-defined data (uncertainty. The framework consists two parts: a fuzzified Geographic Information System (GIS and a HFIS system. The former provides comprehensive information on the criterion unit and the latter helps in making more robust decisions. The HFIS and the traditional Multi-Criteria Decision Making (MCDM method were applied to a case study and compared. The fuzzified GIS maps maintained a majority of the dominant characteristics of the criterion unit but also revealed some non-significant information according to the surrounding environment. The urban planning map generated by the two methods shares similar strategy choices (6% difference, while the spatial distribution of strategies shares 69.7% in common. The HFIS required fewer subjective decisions than the MCDM (34 user-defined decision rules vs. 141 manual evaluations.

  5. Biomimetic synthesis of hierarchical crystalline hydroxyapatite fibers in large-scale

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Chaogang; Ge, Suxiang; Huang, Baojun; Bo, Yingying [Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan Province 461000 (China); Zhang, Di [State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, 1954 Huashan Road, Shanghai 200030 (China); Zheng, Zhi, E-mail: zhengzhi9999@yahoo.com.cn [Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan Province 461000 (China)

    2012-06-15

    Highlights: ► Crystalline hierarchical hydroxyapatite (HAp) fibers are synthesized. ► We employ a biomimetic route by using cotton cloth as a natural bio-template. ► We study the effects of pH, ultrasonic cleaning time, and calcination temperature. ► We obtain an optimized reaction condition. ► This is a low cost method for production of hierarchical HAp fibers. -- Abstract: Crystalline hierarchical hydroxyapatite [Ca{sub 10}(PO{sub 4}){sub 6}(OH){sub 2}, HAp)] fibers were successfully synthesized via a biomimetic route by using cotton cloth as a natural bio-template. The effects of pH value, aging time, ultrasonic cleaning time, and calcination temperature on the purity and morphology of the resulting hydroxyapatite (HAp) were monitored by scanning election microscope (SEM), X-ray diffraction (XRD), and infrared spectrophotometer (IR) to obtain an optimized reaction condition, namely, pH 9, ultrasonic cleaning for 1 min, aging for 24 h, and calcination at 600 °C for 4 h. We found that the natural cellulose could not only control the morphology of HAp but also lower its phase transformation temperature. The impact of this method lies in its low cost and successful production of large-scale patterning of three-dimensional hierarchical HAp fibers.

  6. Biomimetic synthesis of hierarchical crystalline hydroxyapatite fibers in large-scale

    International Nuclear Information System (INIS)

    Xing, Chaogang; Ge, Suxiang; Huang, Baojun; Bo, Yingying; Zhang, Di; Zheng, Zhi

    2012-01-01

    Highlights: ► Crystalline hierarchical hydroxyapatite (HAp) fibers are synthesized. ► We employ a biomimetic route by using cotton cloth as a natural bio-template. ► We study the effects of pH, ultrasonic cleaning time, and calcination temperature. ► We obtain an optimized reaction condition. ► This is a low cost method for production of hierarchical HAp fibers. -- Abstract: Crystalline hierarchical hydroxyapatite [Ca 10 (PO 4 ) 6 (OH) 2 , HAp)] fibers were successfully synthesized via a biomimetic route by using cotton cloth as a natural bio-template. The effects of pH value, aging time, ultrasonic cleaning time, and calcination temperature on the purity and morphology of the resulting hydroxyapatite (HAp) were monitored by scanning election microscope (SEM), X-ray diffraction (XRD), and infrared spectrophotometer (IR) to obtain an optimized reaction condition, namely, pH 9, ultrasonic cleaning for 1 min, aging for 24 h, and calcination at 600 °C for 4 h. We found that the natural cellulose could not only control the morphology of HAp but also lower its phase transformation temperature. The impact of this method lies in its low cost and successful production of large-scale patterning of three-dimensional hierarchical HAp fibers.

  7. Universal Method for Creating Hierarchical Wrinkles on Thin-Film Surfaces.

    Science.gov (United States)

    Jung, Woo-Bin; Cho, Kyeong Min; Lee, Won-Kyu; Odom, Teri W; Jung, Hee-Tae

    2018-01-10

    One of the most interesting topics in physical science and materials science is the creation of complex wrinkled structures on thin-film surfaces because of their several advantages of high surface area, localized strain, and stress tolerance. In this study, a significant step was taken toward solving limitations imposed by the fabrication of previous artificial wrinkles. A universal method for preparing hierarchical three-dimensional wrinkle structures of thin films on a multiple scale (e.g., nanometers to micrometers) by sequential wrinkling with different skin layers was developed. Notably, this method was not limited to specific materials, and it was applicable to fabricating hierarchical wrinkles on all of the thin-film surfaces tested thus far, including those of metals, two-dimensional and one-dimensional materials, and polymers. The hierarchical wrinkles with multiscale structures were prepared by sequential wrinkling, in which a sacrificial layer was used as the additional skin layer between sequences. For example, a hierarchical MoS 2 wrinkle exhibited highly enhanced catalytic behavior because of the superaerophobicity and effective surface area, which are related to topological effects. As the developed method can be adopted to a majority of thin films, it is thought to be a universal method for enhancing the physical properties of various materials.

  8. Convenient and large-scale synthesis of nitrogen-rich hierarchical porous carbon spheres for supercapacitors and CO{sub 2} capture

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Binbin, E-mail: binbinchang@infm.hhstu.edu.cn [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China); Zhang, Shouren; Yin, Hang [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China); Yang, Baocheng, E-mail: baochengyang@yahoo.com [Institute of Nanostructured Functional Materials, Huanghe Science and Technology College, Zhengzhou, Henan 450006 (China); Henan Provincial Key Laboratory of Nano-composite and Application, Zhengzhou, Henan 450006 (China)

    2017-08-01

    Highlights: • Convenient and large-scale synthesis route for N-doped hierarchical porous carbon sphere. • The resultant own spherical morphology, tunable hierarchical porosity, high surface area. • The optimal material exhibits a high CO{sub 2} capture capacity of 4.23 mmol g{sup −1}. • It shows a large voltage window of 1.8 V for symmetric cell in 0.5 M Na{sub 2}SO{sub 4}. - Abstract: Herein, considering the great potential of nitrogen-doped hierarchical porous carbons in energy storage and CO{sub 2} capture, we designed a convenient and easily large-scale production strategy for preparing nitrogen-doped hierarchical porous carbon sphere (NHPCS) materials. In this synthesis route, spherical resorcinol-formaldehyde (RF) resins were selected as carbon precursor, and then the ZnCl{sub 2}-impregnated RF resin spheres were carbonized in a NH{sub 3} atmosphere at a temperature range of 600–800 °C. During the one-step heat-treatment process, nitrogen atom could be efficiently incorporated into the carbon skeleton, and the interconnected and hierarchical pore structure with different micro/mesopore proportion could be generated and tuned by adjusting the activating agent ZnCl{sub 2} dosage and carbonization temperature. The resultant nitrogen-doped hierarchical porous carbon sphere materials exhibited a satisfactory charge storage capacity, and the optimal sample of NHPCS-2-8 with a high mesopore proportion obtained at 800 °C with a ZnCl{sub 2}/RF mass ratio of 2:1 presented a specific capacitance of 273.8 F g{sup −1} at a current density of 0.5 A g{sup −1}. More importantly, the assembled NHPCS-2-8-based symmetric capacitor displayed a high energy density of 17.2 Wh kg{sup −1} at a power density of 178.9 W kg{sup −1} within a voltage window of 0 ∼ 1.8 V in 0.5 M Na{sub 2}SO{sub 4} aqueous electrolyte. In addition, the CO{sub 2} capture application of these NHPCS materials was also explored, and the optimal sample of NHPCS-0-8 with a large

  9. Hierarchical State Machines as Modular Horn Clauses

    Directory of Open Access Journals (Sweden)

    Pierre-Loïc Garoche

    2016-07-01

    Full Text Available In model based development, embedded systems are modeled using a mix of dataflow formalism, that capture the flow of computation, and hierarchical state machines, that capture the modal behavior of the system. For safety analysis, existing approaches rely on a compilation scheme that transform the original model (dataflow and state machines into a pure dataflow formalism. Such compilation often result in loss of important structural information that capture the modal behaviour of the system. In previous work we have developed a compilation technique from a dataflow formalism into modular Horn clauses. In this paper, we present a novel technique that faithfully compile hierarchical state machines into modular Horn clauses. Our compilation technique preserves the structural and modal behavior of the system, making the safety analysis of such models more tractable.

  10. Potassium vapor assisted preparation of highly graphitized hierarchical porous carbon for high rate performance supercapacitors

    Science.gov (United States)

    Liu, Zheng; Zeng, Ying; Tang, Qunli; Hu, Aiping; Xiao, Kuikui; Zhang, Shiying; Deng, Weina; Fan, Binbin; Zhu, Yanfei; Chen, Xiaohua

    2017-09-01

    Ultrahigh graphitized carbon microspheres with rich hierarchical pores (AGHPCM-1) have been successfully synthesized through the one-step activation-carbonization strategy (OACS) with porous sulfonated poly-divinylbenzene as the carbon precursor, iron as the hard template and catalyst, and potassium hydroxide (KOH) as activation agent. Through the XRD, TEM, Raman and BET analysis, AGHPCM-1 shows very high graphitization degree and rich micro-, meso- and macro-pores. More importantly, the mechanism for KOH to improve the graphitization degree of carbon materials in OACS has been illustrated by the thermodynamical theory. The tremendous heat releasing from the reaction between the catalyst precursor of Fe2O3 and potassium vapor plays a key role in the formation of graphitized carbon. It may provide a general direction to prepare highly graphitized porous carbon at a moderate temperature. Integrating the advantages of high graphitization degree and rich hierarchical porous structure, the AGHPCM-1 exhibits an excellent rate performance with a response to up to the high current density of 150 A g-1 and high scan rate of 2000 mV s-1. No obvious capacitance decay can be observed after 10000 charge/discharge cycles even at the high current density of 20 A g-1.

  11. Hierarchical Mesoporous Lithium-Rich Li[Li0.2Ni0.2Mn0.6]O2 Cathode Material Synthesized via Ice Templating for Lithium-Ion Battery.

    Science.gov (United States)

    Li, Yu; Wu, Chuan; Bai, Ying; Liu, Lu; Wang, Hui; Wu, Feng; Zhang, Na; Zou, Yufeng

    2016-07-27

    Tuning hierarchical micro/nanostructure of electrode materials is a sought-after means to reinforce their electrochemical performance in the energy storage field. Herein, we introduce a type of hierarchical mesoporous Li[Li0.2Ni0.2Mn0.6]O2 microsphere composed of nanoparticles synthesized via an ice templating combined coprecipitation strategy. It is a low-cost, eco-friendly, and easily operated method using ice as a template to control material with homogeneous morphology and rich porous channels. The as-prepared material exhibits remarkably enhanced electrochemical performances with higher capacity, more excellent cycling stability and more superior rate property, compared with the sample prepared by conventional coprecipitation method. It has satisfactory initial discharge capacities of 280.1 mAh g(-1) at 0.1 C, 207.1 mAh g(-1) at 2 C, and 152.4 mAh g(-1) at 5 C, as well as good cycle performance. The enhanced electrochemical performance can be ascribed to the stable hierarchical microsized structure and the improved lithium-ion diffusion kinetics from the highly porous structure.

  12. Construction of Hierarchical CuO/Cu₂O@NiCo₂S₄ Nanowire Arrays on Copper Foam for High Performance Supercapacitor Electrodes.

    Science.gov (United States)

    Zhou, Luoxiao; He, Ying; Jia, Congpu; Pavlinek, Vladimir; Saha, Petr; Cheng, Qilin

    2017-09-15

    Hierarchical copper oxide @ ternary nickel cobalt sulfide (CuO/Cu₂O@NiCo₂S₄) core-shell nanowire arrays on Cu foam have been successfully constructed by a facile two-step strategy. Vertically aligned CuO/Cu₂O nanowire arrays are firstly grown on Cu foam by one-step thermal oxidation of Cu foam, followed by electrodeposition of NiCo₂S₄ nanosheets on the surface of CuO/Cu₂O nanowires to form the CuO/Cu₂O@NiCo₂S₄ core-shell nanostructures. Structural and morphological characterizations indicate that the average thickness of the NiCo₂S₄ nanosheets is ~20 nm and the diameter of CuO/Cu₂O core is ~50 nm. Electrochemical properties of the hierarchical composites as integrated binder-free electrodes for supercapacitor were evaluated by various electrochemical methods. The hierarchical composite electrodes could achieve ultrahigh specific capacitance of 3.186 F cm -2 at 10 mA cm -2 , good rate capability (82.06% capacitance retention at the current density from 2 to 50 mA cm -2 ) and excellent cycling stability, with capacitance retention of 96.73% after 2000 cycles at 10 mA cm -2 . These results demonstrate the significance of optimized design and fabrication of electrode materials with more sufficient electrolyte-electrode interface, robust structural integrity and fast ion/electron transfer.

  13. Hierarchical pre-segmentation without prior knowledge

    NARCIS (Netherlands)

    Kuijper, A.; Florack, L.M.J.

    2001-01-01

    A new method to pre-segment images by means of a hierarchical description is proposed. This description is obtained from an investigation of the deep structure of a scale space image – the input image and the Gaussian filtered ones simultaneously. We concentrate on scale space critical points –

  14. An Evolutionary Approach for Optimizing Hierarchical Multi-Agent System Organization

    OpenAIRE

    Shen, Zhiqi; Yu, Ling; Yu, Han

    2014-01-01

    It has been widely recognized that the performance of a multi-agent system is highly affected by its organization. A large scale system may have billions of possible ways of organization, which makes it impractical to find an optimal choice of organization using exhaustive search methods. In this paper, we propose a genetic algorithm aided optimization scheme for designing hierarchical structures of multi-agent systems. We introduce a novel algorithm, called the hierarchical genetic algorithm...

  15. A mechanical model of biomimetic adhesive pads with tilted and hierarchical structures.

    Science.gov (United States)

    Schargott, M

    2009-06-01

    A 3D model for hierarchical biomimetic adhesive pads is constructed. It is based on the main principles of the adhesive pads of the Tokay gecko and consists of hierarchical layers of vertical or tilted beams, where each layer is constructed in such a way that no cohesion between adjacent beams can occur. The elastic and adhesive properties are calculated analytically and numerically. For the adhesive contact on stochastically rough surfaces, the maximum adhesion force increases with increasing number of hierarchical layers. Additional calculations show that the adhesion force also depends on the height spectrum of the rough surface.

  16. A mechanical model of biomimetic adhesive pads with tilted and hierarchical structures

    Energy Technology Data Exchange (ETDEWEB)

    Schargott, M [Institute of Mechanics, Technische Universitaet Berlin, Strd 17 Juni 135, 10623 Berlin (Germany)], E-mail: martin.schargott@tu-berlin.de

    2009-06-01

    A 3D model for hierarchical biomimetic adhesive pads is constructed. It is based on the main principles of the adhesive pads of the Tokay gecko and consists of hierarchical layers of vertical or tilted beams, where each layer is constructed in such a way that no cohesion between adjacent beams can occur. The elastic and adhesive properties are calculated analytically and numerically. For the adhesive contact on stochastically rough surfaces, the maximum adhesion force increases with increasing number of hierarchical layers. Additional calculations show that the adhesion force also depends on the height spectrum of the rough surface.

  17. A mechanical model of biomimetic adhesive pads with tilted and hierarchical structures

    International Nuclear Information System (INIS)

    Schargott, M

    2009-01-01

    A 3D model for hierarchical biomimetic adhesive pads is constructed. It is based on the main principles of the adhesive pads of the Tokay gecko and consists of hierarchical layers of vertical or tilted beams, where each layer is constructed in such a way that no cohesion between adjacent beams can occur. The elastic and adhesive properties are calculated analytically and numerically. For the adhesive contact on stochastically rough surfaces, the maximum adhesion force increases with increasing number of hierarchical layers. Additional calculations show that the adhesion force also depends on the height spectrum of the rough surface

  18. Copper oxide assisted cysteine hierarchical structures for immunosensor application

    Energy Technology Data Exchange (ETDEWEB)

    Pandey, Chandra Mouli [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221005 (India); Sumana, Gajjala, E-mail: sumanagajjala@gmail.com [Biomedical Instrumentation Section, CSIR-National Physical Laboratory, New Delhi 110012 (India); Tiwari, Ida [Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221005 (India)

    2014-09-08

    The present work describes the promising electrochemical immunosensing strategy based on copper (II) assisted hierarchical cysteine structures (CuCys) varying from star to flower like morphology. The CuCys having average size of 10 μm have been synthesised using L-Cysteine as initial precursor in presence of copper oxide under environmentally friendly conditions in aqueous medium. To delineate the synthesis mechanism, detailed structural investigations have been carried out using characterization techniques such as X-ray diffraction, transmission electron microscopy, and Fourier transform infrared spectroscopy. The electrochemical behaviour of self-assembled CuCys on gold electrode shows surface controlled electrode reaction with an apparent electron transfer rate constant of 3.38 × 10{sup −4 }cm s{sup −1}. This innovative platform has been utilized to fabricate an immunosensor by covalently immobilizing monoclonal antibodies specific for Escherichia coli O157:H7 (E. coli). Under the optimal conditions, the fabricated immunosensor is found to be sensitive and specific for the detection of E. coli with a detection limit of 10 cfu/ml.

  19. Modular Assembly of Hierarchically Structured Polymers

    Science.gov (United States)

    Leophairatana, Porakrit

    The synthesis of macromolecules with complex yet highly controlled molecular architectures has attracted significant attention in the past few decades due to the growing demand for specialty polymers that possess novel properties. Despite recent efforts, current synthetic routes lack the ability to control several important architectural variables while maintaining low polydispersity index. This dissertation explores a new synthetic scheme for the modular assembly of hierarchically structured polymers (MAHP) that allows virtually any complex polymer to be assembled from a few basic molecular building blocks using a single common coupling chemistry. Complex polymer structures can be assembled from a molecular toolkit consisting of (1) copper-catalyzed azide-alkyne cycloaddition (CuAAC), (2) linear heterobifunctional macromonomers, (3) a branching heterotrifunctional molecule, (4) a protection/deprotection strategy, (5) "click" functional solid substrates, and (6) functional and responsive polymers. This work addresses the different challenges that emerged during the development of this synthetic scheme, and presents strategies to overcome those challenges. Chapter 3 investigates the alkyne-alkyne (i.e. Glaser) coupling side reactions associated with the atom transfer radical polymerization (ATRP) synthesis of alkyne-functional macromonomers, as well as with the CuAAC reaction of alkyne functional building blocks. In typical ATRP synthesis of unprotected alkyne functional polymers, Glaser coupling reactions can significantly compromise the polymer functionality and undermine the success of subsequent click reactions in which the polymers are used. Two strategies are reported that effectively eliminate these coupling reactions: (1) maintaining low temperature post-ATRP upon exposure to air, followed by immediate removal of copper catalyst; and (2) adding excess reducing agents post-ATRP, which prevents the oxidation of Cu(I) catalyst required by the Glaser coupling

  20. Fabrication and properties of dual-level hierarchical structures mimicking gecko foot hairs.

    Science.gov (United States)

    Zhang, Peng; Liu, Shiyuan; Lv, Hao

    2013-02-01

    In nature, geckos have extraordinary adhesive capabilities. The multi-scale hierarchical structure of the gecko foot hairs, especially the high-aspect-ratio structure of its micro-scale seta and nano-scale spatulae is the critical factor of the gecko's ability to adopt and stick to any different surface with powerful adhesion force. In this paper, we present a simple and effective approach to fabricate dual-level hierarchical structures mimicking gecko foot hairs. Polydimethyl-siloxane (PDMS) hierarchical arrays were fabricated by demolding from a double stack mold that was composed of an SU-8 mold by thick film photolithography and a silicon mold by inductively coupled plasma (ICP) etching. Top pillars of the fabricated structures have 3 micom diameter and 18 microm in height, while base pillars have 25 microm diameter and 40 microm in height. The water droplet contact angle tests indicate that the hierarchical structures increase the hydrophobic property significantly compared with the single-level arrays and the unstructured polymers, exhibiting superhydrophobicity (154.2 degrees) like the Tokay gecko's (160.9 degrees). The shear force tests show that the top pillars make attachment through side contact with a value of about 0.25 N/cm2, and moreover, the hierarchical structures are demonstrated to be more suitable for contacting with rough surfaces.

  1. Helical self-organization and hierarchical self-assembly of an oligoheterocyclic pyridine-pyridazine strand into extended supramolecular fibers.

    Science.gov (United States)

    Cuccia, Louis A; Ruiz, Eliseo; Lehn, Jean-Marie; Homo, Jean-Claude; Schmutz, Marc

    2002-08-02

    The synthesis and characterization of an alternating pyridine-pyridazine strand comprising thirteen heterocycles are described. Spontaneous folding into a helical secondary structure is based on a general molecular self-organization process enforced by the conformational information encoded within the primary structure of the molecular strand itself. Conformational control based on heterocyclic "helicity codons" illustrates a strategy for designing folding properties into synthetic oligomers (foldamers). Strong intermolecular interactions of the highly ordered lock-washer subunits of compound 3 results in hierarchical supramolecular self-assembly into protofibrils and fibrils. Compound 3 also forms mechanically stable two-dimensional Langmuir-Blodgett and cast thin films.

  2. Scale of association: hierarchical linear models and the measurement of ecological systems

    Science.gov (United States)

    Sean M. McMahon; Jeffrey M. Diez

    2007-01-01

    A fundamental challenge to understanding patterns in ecological systems lies in employing methods that can analyse, test and draw inference from measured associations between variables across scales. Hierarchical linear models (HLM) use advanced estimation algorithms to measure regression relationships and variance-covariance parameters in hierarchically structured...

  3. Simultaneous formation of multiscale hierarchical surface morphologies through sequential wrinkling and folding

    Science.gov (United States)

    Wang, Yu; Sun, Qingyang; Xiao, Jianliang

    2018-02-01

    Highly organized hierarchical surface morphologies possess various intriguing properties that could find important potential applications. In this paper, we demonstrate a facile approach to simultaneously form multiscale hierarchical surface morphologies through sequential wrinkling. This method combines surface wrinkling induced by thermal expansion and mechanical strain on a three-layer structure composed of an aluminum film, a hard Polydimethylsiloxane (PDMS) film, and a soft PDMS substrate. Deposition of the aluminum film on hard PDMS induces biaxial wrinkling due to thermal expansion mismatch, and recovering the prestrain in the soft PDMS substrate leads to wrinkling of the hard PDMS film. In total, three orders of wrinkling patterns form in this process, with wavelength and amplitude spanning 3 orders of magnitude in length scale. By increasing the prestrain in the soft PDMS substrate, a hierarchical wrinkling-folding structure was also obtained. This approach can be easily extended to other thin films for fabrication of multiscale hierarchical surface morphologies with potential applications in different areas.

  4. Criticality of the Potts ferromagnet in Midgal-Kadanoff - like hierarchical lattices

    International Nuclear Information System (INIS)

    Silva, L.R. da; Tsallis, C.

    1987-01-01

    Within the real space renormalisation group framework, we discuss the critical point and exponent υ of the Potts ferromagnet in b-sized Migdal-Kadanoff-like hierarchical lattices. Both b → ∞ and b → 1 limits are exhibited. The important discrepancies that might exist between the exact results for d-dimensional hierarchical lattices and d-dimensional Bravais lattices are illustrated. (Author) [pt

  5. Hierarchical Bayesian Models of Subtask Learning

    Science.gov (United States)

    Anglim, Jeromy; Wynton, Sarah K. A.

    2015-01-01

    The current study used Bayesian hierarchical methods to challenge and extend previous work on subtask learning consistency. A general model of individual-level subtask learning was proposed focusing on power and exponential functions with constraints to test for inconsistency. To study subtask learning, we developed a novel computer-based booking…

  6. Three-Dimensional Nitrogen-Doped Hierarchical Porous Carbon as an Electrode for High-Performance Supercapacitors.

    Science.gov (United States)

    Tang, Jing; Wang, Tao; Salunkhe, Rahul R; Alshehri, Saad M; Malgras, Victor; Yamauchi, Yusuke

    2015-11-23

    A facile and sustainable procedure for the synthesis of nitrogen-doped hierarchical porous carbons with a three-dimensional interconnected framework (NHPC-3D) was developed. The strategy, based on a colloidal crystal-templating method, utilizes nitrogenous dopamine as the precursor due to its unique properties, including self-polymerization under mild alkaline conditions, coating onto various surfaces, a high carbonization yield, and well-preserved nitrogen doping after heat treatment. The obtained NHPC-3D possesses a high surface area of 1056 m(2)  g(-1) , a large pore volume of 2.56 cm(3)  g(-1) , and a high nitrogen content of 8.2 wt %. The NHPC-3D is implemented as the electrode material of a supercapacitor and exhibits a specific capacitance as high as 252 F g(-1) at a current density of 2 A g(-1) . The device also shows a high capacitance retention of 75.7 % at a higher current density of 20 A g(-1) in aqueous electrolyte due to a sufficient surface area for charge accommodation, reversible pseudocapacitance, and minimized ion-transport resistance, as a result of the advantageous interconnected hierarchical porous texture. These results showcase NHPC-3D as a promising candidate for electrode materials in supercapacitors. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Nanoscale Analysis of a Hierarchical Hybrid Solar Cell in 3D.

    Science.gov (United States)

    Divitini, Giorgio; Stenzel, Ole; Ghadirzadeh, Ali; Guarnera, Simone; Russo, Valeria; Casari, Carlo S; Bassi, Andrea Li; Petrozza, Annamaria; Di Fonzo, Fabio; Schmidt, Volker; Ducati, Caterina

    2014-05-01

    A quantitative method for the characterization of nanoscale 3D morphology is applied to the investigation of a hybrid solar cell based on a novel hierarchical nanostructured photoanode. A cross section of the solar cell device is prepared by focused ion beam milling in a micropillar geometry, which allows a detailed 3D reconstruction of the titania photoanode by electron tomography. It is found that the hierarchical titania nanostructure facilitates polymer infiltration, thus favoring intermixing of the two semiconducting phases, essential for charge separation. The 3D nanoparticle network is analyzed with tools from stochastic geometry to extract information related to the charge transport in the hierarchical solar cell. In particular, the experimental dataset allows direct visualization of the percolation pathways that contribute to the photocurrent.

  8. Hierarchically Nanostructured Transition Metal Oxides for Lithium‐Ion Batteries

    Science.gov (United States)

    Zheng, Mingbo; Tang, Hao; Li, Lulu; Hu, Qin; Zhang, Li; Xue, Huaiguo

    2018-01-01

    Abstract Lithium‐ion batteries (LIBs) have been widely used in the field of portable electric devices because of their high energy density and long cycling life. To further improve the performance of LIBs, it is of great importance to develop new electrode materials. Various transition metal oxides (TMOs) have been extensively investigated as electrode materials for LIBs. According to the reaction mechanism, there are mainly two kinds of TMOs, one is based on conversion reaction and the other is based on intercalation/deintercalation reaction. Recently, hierarchically nanostructured TMOs have become a hot research area in the field of LIBs. Hierarchical architecture can provide numerous accessible electroactive sites for redox reactions, shorten the diffusion distance of Li‐ion during the reaction, and accommodate volume expansion during cycling. With rapid research progress in this field, a timely account of this advanced technology is highly necessary. Here, the research progress on the synthesis methods, morphological characteristics, and electrochemical performances of hierarchically nanostructured TMOs for LIBs is summarized and discussed. Some relevant prospects are also proposed. PMID:29593962

  9. Robust Pedestrian Classification Based on Hierarchical Kernel Sparse Representation

    Directory of Open Access Journals (Sweden)

    Rui Sun

    2016-08-01

    Full Text Available Vision-based pedestrian detection has become an active topic in computer vision and autonomous vehicles. It aims at detecting pedestrians appearing ahead of the vehicle using a camera so that autonomous vehicles can assess the danger and take action. Due to varied illumination and appearance, complex background and occlusion pedestrian detection in outdoor environments is a difficult problem. In this paper, we propose a novel hierarchical feature extraction and weighted kernel sparse representation model for pedestrian classification. Initially, hierarchical feature extraction based on a CENTRIST descriptor is used to capture discriminative structures. A max pooling operation is used to enhance the invariance of varying appearance. Then, a kernel sparse representation model is proposed to fully exploit the discrimination information embedded in the hierarchical local features, and a Gaussian weight function as the measure to effectively handle the occlusion in pedestrian images. Extensive experiments are conducted on benchmark databases, including INRIA, Daimler, an artificially generated dataset and a real occluded dataset, demonstrating the more robust performance of the proposed method compared to state-of-the-art pedestrian classification methods.

  10. Hierarchical structure of biological systems: a bioengineering approach.

    Science.gov (United States)

    Alcocer-Cuarón, Carlos; Rivera, Ana L; Castaño, Victor M

    2014-01-01

    A general theory of biological systems, based on few fundamental propositions, allows a generalization of both Wierner and Berthalanffy approaches to theoretical biology. Here, a biological system is defined as a set of self-organized, differentiated elements that interact pair-wise through various networks and media, isolated from other sets by boundaries. Their relation to other systems can be described as a closed loop in a steady-state, which leads to a hierarchical structure and functioning of the biological system. Our thermodynamical approach of hierarchical character can be applied to biological systems of varying sizes through some general principles, based on the exchange of energy information and/or mass from and within the systems.

  11. Mobile Multicast in Hierarchical Proxy Mobile IPV6

    Science.gov (United States)

    Hafizah Mohd Aman, Azana; Hashim, Aisha Hassan A.; Mustafa, Amin; Abdullah, Khaizuran

    2013-12-01

    Mobile Internet Protocol Version 6 (MIPv6) environments have been developing very rapidly. Many challenges arise with the fast progress of MIPv6 technologies and its environment. Therefore the importance of improving the existing architecture and operations increases. One of the many challenges which need to be addressed is the need for performance improvement to support mobile multicast. Numerous approaches have been proposed to improve mobile multicast performance. This includes Context Transfer Protocol (CXTP), Hierarchical Mobile IPv6 (HMIPv6), Fast Mobile IPv6 (FMIPv6) and Proxy Mobile IPv6 (PMIPv6). This document describes multicast context transfer in hierarchical proxy mobile IPv6 (H-PMIPv6) to provide better multicasting performance in PMIPv6 domain.

  12. A novel method for a multi-level hierarchical composite with brick-and-mortar structure.

    Science.gov (United States)

    Brandt, Kristina; Wolff, Michael F H; Salikov, Vitalij; Heinrich, Stefan; Schneider, Gerold A

    2013-01-01

    The fascination for hierarchically structured hard tissues such as enamel or nacre arises from their unique structure-properties-relationship. During the last decades this numerously motivated the synthesis of composites, mimicking the brick-and-mortar structure of nacre. However, there is still a lack in synthetic engineering materials displaying a true hierarchical structure. Here, we present a novel multi-step processing route for anisotropic 2-level hierarchical composites by combining different coating techniques on different length scales. It comprises polymer-encapsulated ceramic particles as building blocks for the first level, followed by spouted bed spray granulation for a second level, and finally directional hot pressing to anisotropically consolidate the composite. The microstructure achieved reveals a brick-and-mortar hierarchical structure with distinct, however not yet optimized mechanical properties on each level. It opens up a completely new processing route for the synthesis of multi-level hierarchically structured composites, giving prospects to multi-functional structure-properties relationships.

  13. A novel method for a multi-level hierarchical composite with brick-and-mortar structure

    Science.gov (United States)

    Brandt, Kristina; Wolff, Michael F. H.; Salikov, Vitalij; Heinrich, Stefan; Schneider, Gerold A.

    2013-07-01

    The fascination for hierarchically structured hard tissues such as enamel or nacre arises from their unique structure-properties-relationship. During the last decades this numerously motivated the synthesis of composites, mimicking the brick-and-mortar structure of nacre. However, there is still a lack in synthetic engineering materials displaying a true hierarchical structure. Here, we present a novel multi-step processing route for anisotropic 2-level hierarchical composites by combining different coating techniques on different length scales. It comprises polymer-encapsulated ceramic particles as building blocks for the first level, followed by spouted bed spray granulation for a second level, and finally directional hot pressing to anisotropically consolidate the composite. The microstructure achieved reveals a brick-and-mortar hierarchical structure with distinct, however not yet optimized mechanical properties on each level. It opens up a completely new processing route for the synthesis of multi-level hierarchically structured composites, giving prospects to multi-functional structure-properties relationships.

  14. Poincaré Embeddings for Learning Hierarchical Representations

    CERN Multimedia

    CERN. Geneva

    2018-01-01

    Abstracts: Representation learning has become an invaluable approach for learning from symbolic data such as text and graphs. However, while complex symbolic datasets often exhibit a latent hierarchical structure, state-of-the-art methods typically do not account for this property. In this talk, I will discuss a new approach for learning hierarchical representations of symbolic data by embedding them into hyperbolic space -- or more precisely into an n-dimensional Poincaré ball. Due to the underlying hyperbolic geometry, this allows us to learn parsimonious representations of symbolic data by simultaneously capturing hierarchy and similarity. We introduce an efficient algorithm to learn the embeddings based on Riemannian optimization and show experimentally that Poincaré embeddings outperform Euclidean embeddings significantly on data with latent hierarchies, both in terms of representation capacity and in terms of generalization ability.      &...

  15. Olympic athletes’ job market entry strategies. A typology

    Directory of Open Access Journals (Sweden)

    Anna Vilanova

    2017-05-01

    Full Text Available The aim of this study was to establish a typology of job market entry strategies among Olympic athletes. Guided by rational choice theory and social reproduction theory, we conducted a telephone survey among 94 athletes (68 men and 26 women. Hierarchical cluster analysis was used to identify four distinct groups, which we called parallel life strategists, freelance strategists, lifetime athletes, and non-strategists: it’s a job. The results show that athletes from families with greater economic and cultural capital implement career transition strategies further in advance and achieve greater career success and satisfaction. These findings can be used to develop support programs tailored to the needs of athletes according to their profile.

  16. Barriers perceived by teachers at work, coping strategies, self-efficacy and burnout.

    Science.gov (United States)

    Doménech Betoret, Fernando; Gómez Artiga, Amparo

    2010-11-01

    This study examines the relationships among stressors, coping strategies, self-efficacy and burnout in a sample of 724 Spanish primary and secondary teachers. We understood stressors as barriers perceived by teachers that interfere with their work meeting learning objectives and which cause them stress and burnout. An analysis of teacher responses using hierarchical regression revealed that pedagogical barriers had significant positive effects on the burnout dimensions. Furthermore, the results show not only the moderator role played by coping strategies in the pedagogical barriers-burnout dimensions relationship, but also the association between self-efficacy and the coping strategies used by teachers. Practical implications are discussed.

  17. Hierarchical porous ZnO microflowers with ultra-high ethanol gas-sensing at low concentration

    Science.gov (United States)

    Song, Liming; Yue, He; Li, Haiying; Liu, Li; Li, Yu; Du, Liting; Duan, Haojie; Klyui, N. I.

    2018-05-01

    Hierarchical porous and non-porous ZnO microflowers have been successfully fabricated by hydrothermal method. Their crystal structure, morphology and gas-sensing properties were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical gas sensing intelligent analysis system (CGS). Compared with hierarchical non-porous ZnO microflowers, hierarchical porous ZnO microflowers exhibited ultra-high sensitivity with 50 ppm ethanol at 260 °C and the response is 110, which is 1.8 times higher than that of non-porous ZnO microflowers. Moreover, the lowest concentration limit of hierarchical porous ZnO microflowers (non-porous ZnO microflowers) to ethanol is 0.1 (1) ppm, the response value is 1.6 (1).

  18. Combustion synthesized hierarchically porous WO{sub 3} for selective acetone sensing

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Chengjun; Liu, Xu; Guan, Hongtao; Chen, Gang; Xiao, Xuechun [Department of Materials Science and Engineering, Yunnan University, 650091, Kunming (China); Djerdj, Igor [Ruđer Bošković Institute, Bijenička 54, 10000, Zagreb (Croatia); Wang, Yude, E-mail: ydwang@ynu.edu.cn [Department of Materials Science and Engineering, Yunnan University, 650091, Kunming (China); Yunnan Province Key Lab of Mico-Nano Materials and Technology, Yunnan University, 650091, Kunming (China)

    2016-12-01

    An easy, inexpensive combustion route was designed to synthesize hierarchically porous WO{sub 3}. The tungsten source was fresh peroxiotungstic acid by dissolving tungsten powder into hydrogen peroxide. To promote the combustion reaction, a combined fuel of both glycine and hydrazine hydrate was used. The microstructure was well-connected pores comprised of subunit nanoparticles. Upon exposing towards acetone gas, the porous WO{sub 3} based sensor exhibits high gas response, rapid response and recovery, and good selectivity in the range of 5–1000 ppm under working temperature of 300 °C. This excellent sensing performance was plausibly attributed to the porous morphology, which hence provides more active sites for the gas molecules' reaction. - Graphical abstract: Hierarchically porous WO{sub 3} synthesized by combustion process exhibits high gas response, rapid response and recovery, and excellent selectivity for acetone, making it to be promising candidates for practical detectors for acetone. - Highlights: • Hierarchically porous WO{sub 3} synthesized by combustion process. • Hierarchically porous WO{sub 3} exhibits high gas response and excellent selectivity for acetone. • The excellent sensing property was plausibly attributed to the porous morphology.

  19. Hierarchical SAPO‐34 Architectures with Tailored Acid Sites using Sustainable Sugar Templates

    Science.gov (United States)

    Miletto, Ivana; Ivaldi, Chiara; Paul, Geo; Chapman, Stephanie; Marchese, Leonardo; Raja, Robert

    2018-01-01

    Abstract In a distinct, bottom‐up synthetic methodology, monosaccharides (fructose and glucose) and disaccharides (sucrose) have been used as mesoporogens to template hierarchical SAPO‐34 catalysts. Detailed materials characterization, which includes solid‐state magic angle spinning NMR and probe‐based FTIR, reveals that, although the mesopore dimensions are modified by the identity of the sugar template, the desirable acid characteristics of the microporous framework are retained. When the activity of the hierarchical SAPO‐34 catalysts was evaluated in the industrially relevant Beckmann rearrangement, under liquid‐phase conditions, the enhanced mass‐transport properties of sucrose‐templated hierarchical SAPO‐34 were found to deliver a superior yield of ϵ‐caprolactam. PMID:29686961

  20. Hierarchical analysis of urban space

    OpenAIRE

    Kataeva, Y.

    2014-01-01

    Multi-level structure of urban space, multitude of subjects of its transformation, which follow asymmetric interests, multilevel system of institutions which regulate interaction in the "population business government -public organizations" system, determine the use of hierarchic approach to the analysis of urban space. The article observes theoretical justification of using this approach to study correlations and peculiarities of interaction in urban space as in an intricately organized syst...

  1. A distributed hierarchical architecture of expert systems for supervisory control of multimodular nuclear reactors

    International Nuclear Information System (INIS)

    Otaduy, P.J.; Brittain, C.R.; Rovere, L.A.; Gove, N.B.

    1991-01-01

    A hierarchical supervisory control architecture has being implemented at ORNL to coordinate the controllers of a multimodular nuclear plant. The supervisory controller form a network of distributed expert system interfaced with a real-time simulation of the plant, the plant's automatic controllers, and the human operator. The main goal of the supervisory controllers is to maintain the plant operating within safety envelopes while optimizing availability, minimizing stress to components and operators, and facilitating operations. Representative rules implementing strategies for situation dependent reassignment of process goals by embedding diagnostics into the control philosophy are discussed. It should noted that the control philosophies here described use the ALMR concept for illustration purposes and are not part of the official ALMR design at this time. 3 refs., 1 fig

  2. Requirements for implementing real-time control functional modules on a hierarchical parallel pipelined system

    Science.gov (United States)

    Wheatley, Thomas E.; Michaloski, John L.; Lumia, Ronald

    1989-01-01

    Analysis of a robot control system leads to a broad range of processing requirements. One fundamental requirement of a robot control system is the necessity of a microcomputer system in order to provide sufficient processing capability.The use of multiple processors in a parallel architecture is beneficial for a number of reasons, including better cost performance, modular growth, increased reliability through replication, and flexibility for testing alternate control strategies via different partitioning. A survey of the progression from low level control synchronizing primitives to higher level communication tools is presented. The system communication and control mechanisms of existing robot control systems are compared to the hierarchical control model. The impact of this design methodology on the current robot control systems is explored.

  3. A DC Microgrid Coordinated Control Strategy Based on Integrator Current-Sharing

    DEFF Research Database (Denmark)

    Gao, Liyuan; Liu, Yao; Ren, Huisong

    2017-01-01

    The DC microgrid has become a new trend for microgrid study with the advantages of high reliability, simple control and low losses. With regard to the drawbacks of the traditional droop control strategies, an improved DC droop control strategy based on integrator current-sharing is introduced....... In the strategy, the principle of eliminating deviation through an integrator is used, constructing the current-sharing term in order to make the power-sharing between different distributed generation (DG) units uniform and reasonable, which can reduce the circulating current between DG units. Furthermore......, at the system coordinated control level, a hierarchical/droop control strategy based on the DC bus voltage is proposed. In the strategy, the operation modes of the AC main network and micro-sources are determined through detecting the DC voltage variation, which can ensure the power balance of the DC microgrid...

  4. Effects of Concept Mapping Strategy on Learning Performance in Business and Economics Statistics

    Science.gov (United States)

    Chiou, Chei-Chang

    2009-01-01

    A concept map (CM) is a hierarchically arranged, graphic representation of the relationships among concepts. Concept mapping (CMING) is the process of constructing a CM. This paper examines whether a CMING strategy can be useful in helping students to improve their learning performance in a business and economics statistics course. A single…

  5. Hierarchical structures of ZnO spherical particles synthesized solvothermally

    Science.gov (United States)

    Saito, Noriko; Haneda, Hajime

    2011-12-01

    We review the solvothermal synthesis, using a mixture of ethylene glycol (EG) and water as the solvent, of zinc oxide (ZnO) particles having spherical and flower-like shapes and hierarchical nanostructures. The preparation conditions of the ZnO particles and the microscopic characterization of the morphology are summarized. We found the following three effects of the ratio of EG to water on the formation of hierarchical structures: (i) EG restricts the growth of ZnO microcrystals, (ii) EG promotes the self-assembly of small crystallites into spheroidal particles and (iii) the high water content of EG results in hollow spheres.

  6. Dynamics and thermodynamics in hierarchically organized systems applications in physics, biology and economics

    CERN Document Server

    Auger, P

    2013-01-01

    One of the most fundamental and efficient ways of conceptualizing complex systems is to organize them hierarchically. A hierarchically organized system is represented by a network of interconnected subsystems, each of which has its own network of subsystems, and so on, until some elementary subsystems are reached that are not further decomposed. This original and important book proposes a general mathematical theory of a hierarchical system and shows how it can be applied to very different topics such as physics (Hamiltonian systems), biology (coupling the molecular and the cellular levels), e

  7. Hierarchical Broadcasting in the Future Mobile Internet

    NARCIS (Netherlands)

    Hesselman, C.E.W.; Eertink, E.H.; Fernandez, Milagros; Crnkovic, Ivica; Fohler, Gerhard; Griwodz, Carsten; Plagemann, Thomas; Gruenbacher, Paul

    2002-01-01

    We describe an architecture for the hierarchical distribution of multimedia broadcasts in the future mobile Internet. The architecture supports network as well as application-layer mobility solutions, and uses stream control functions that are influenced by available network resources, user-defined

  8. Modular networks with hierarchical organization: The dynamical ...

    Indian Academy of Sciences (India)

    Most of the complex systems seen in real life also have associated dynamics [10], and the ... another example, this time a hierarchical structure, viz., the Cayley tree with b ..... natural constraints operating on networks in real life, such as the ...

  9. A metal-organic framework derived hierarchical nickel-cobalt sulfide nanosheet array on Ni foam with enhanced electrochemical performance for supercapacitors.

    Science.gov (United States)

    Tao, Kai; Han, Xue; Ma, Qingxiang; Han, Lei

    2018-03-06

    Metal-organic frameworks (MOFs) have emerged as a new platform for the construction of various functional materials for energy related applications. Here, a facile MOF templating method is developed to fabricate a hierarchical nickel-cobalt sulfide nanosheet array on conductive Ni foam (Ni-Co-S/NF) as a binder-free electrode for supercapacitors. A uniform 2D Co-MOF nanowall array is first grown in situ on Ni foam in aqueous solution at room temperature, and then the Co-MOF nanowalls are converted into hierarchical Ni-Co-S nanoarchitectures via an etching and ion-exchange reaction with Ni(NO 3 ) 2 , and a subsequent solvothermal sulfurization. Taking advantage of the compositional and structural merits of the hierarchical Ni-Co-S nanosheet array and conductive Ni foam, such as fast electron transportation, short ion diffusion path, abundant active sites and rich redox reactions, the obtained Ni-Co-S/NF electrode exhibits excellent electrochemical capacitive performance (1406.9 F g -1 at 0.5 A g -1 , 53.9% retention at 10 A g -1 and 88.6% retention over 1000 cycles), which is superior to control CoS/NF. An asymmetric supercapacitor (ASC) assembled by using the as-fabricated Ni-Co-S/NF as the positive electrode and activated carbon (AC) as the negative electrode delivers a high energy density of 24.8 W h kg -1 at a high power density of 849.5 W kg -1 . Even when the power density is as high as 8.5 kW kg -1 , the ASC still exhibits a high energy density of 12.5 W h kg -1 . This facile synthetic strategy can also be extended to fabricate other hierarchical integrated electrodes for high-efficiency electrochemical energy conversion and storage devices.

  10. Hierarchic levels of a system classification of radiation-contaminated landscapes

    International Nuclear Information System (INIS)

    Dolyin, V.V.; Sushchik, Yu.Ya.; Bondarenko, G.M.; Shramenko, Yi.F.; Dudar, T.V.

    2001-01-01

    Five hierarchic levels of the systematic organization of natural landscapes are determined: substantial-phase, soil-profile, biogeocenotic, landscape, and geosystematic. Systems and subsystems of compounds of chemical elements and natural and man-caused factors that characterized properties and mechanisms of ecological self-organization of biogeocenoses are brought into accordance with each level. A scheme of hierarchic subordination of systems, subsystems, and processes is worked out. Leading links of transformation and migration of radionuclides that define the contamination of tropic chains are determined

  11. Context updates are hierarchical

    Directory of Open Access Journals (Sweden)

    Anton Karl Ingason

    2016-10-01

    Full Text Available This squib studies the order in which elements are added to the shared context of interlocutors in a conversation. It focuses on context updates within one hierarchical structure and argues that structurally higher elements are entered into the context before lower elements, even if the structurally higher elements are pronounced after the lower elements. The crucial data are drawn from a comparison of relative clauses in two head-initial languages, English and Icelandic, and two head-final languages, Korean and Japanese. The findings have consequences for any theory of a dynamic semantics.

  12. Why do some women prefer submissive men? Hierarchically disparate couples reach higher reproductive success in European urban humans.

    Science.gov (United States)

    Jozifkova, Eva; Konvicka, Martin; Flegr, Jaroslav

    2014-01-01

    Equality between partners is considering a feature of the functional partnerships in westernized societies. However, the evolutionary consequences of how in-pair hierarchy influences reproduction are less known. Attraction of some high-ranking women towards low-ranking men represents a puzzle. Young urban adults (120 men, 171 women) filled out a questionnaire focused on their sexual preference for higher or lower ranking partners, their future in-pair hierarchy, and hierarchy between their parents. Human pairs with a hierarchic disparity between partners conceive more offspring than pairs of equally-ranking individuals, who, in turn, conceive more offspring than pairs of two dominating partners. Importantly, the higher reproductive success of hierarchically disparate pairs holds, regardless of which sex, male or female, is the dominant one. In addition, the subjects preferring hierarchy disparity in partnerships were with greater probability sexually aroused by such disparity, suggesting that both the partnership preference and the triggers of sexual arousal may reflect a mating strategy. These results challenge the frequently held belief in within-pair equality as a trademark of functional partnerships. It rather appears that existence of some disparity improves within-pair cohesion, facilitating both cooperation between partners and improving the pairs' ability to face societal challenges. The parallel existence of submissivity-dominance hierarchies within human sexes allows for the parallel existence of alternative reproductive strategies, and may form a background for the diversity of mating systems observed in human societies. Arousal of overemphasized dominance/submissiveness may explain sadomasochistic sex, still little understood from the evolutionary psychology point of view.

  13. Fuzzy hierarchical model for risk assessment principles, concepts, and practical applications

    CERN Document Server

    Chan, Hing Kai

    2013-01-01

    Risk management is often complicated by situational uncertainties and the subjective preferences of decision makers. Fuzzy Hierarchical Model for Risk Assessment introduces a fuzzy-based hierarchical approach to solve risk management problems considering both qualitative and quantitative criteria to tackle imprecise information.   This approach is illustrated through number of case studies using examples from the food, fashion and electronics sectors to cover a range of applications including supply chain management, green product design and green initiatives. These practical examples explore how this method can be adapted and fine tuned to fit other industries as well.   Supported by an extensive literature review, Fuzzy Hierarchical Model for Risk Assessment  comprehensively introduces a new method for project managers across all industries as well as researchers in risk management.

  14. Hierarchical Decompositions for the Computation of High-Dimensional Multivariate Normal Probabilities

    KAUST Repository

    Genton, Marc G.

    2017-09-07

    We present a hierarchical decomposition scheme for computing the n-dimensional integral of multivariate normal probabilities that appear frequently in statistics. The scheme exploits the fact that the formally dense covariance matrix can be approximated by a matrix with a hierarchical low rank structure. It allows the reduction of the computational complexity per Monte Carlo sample from O(n2) to O(mn+knlog(n/m)), where k is the numerical rank of off-diagonal matrix blocks and m is the size of small diagonal blocks in the matrix that are not well-approximated by low rank factorizations and treated as dense submatrices. This hierarchical decomposition leads to substantial efficiencies in multivariate normal probability computations and allows integrations in thousands of dimensions to be practical on modern workstations.

  15. Hierarchical Decompositions for the Computation of High-Dimensional Multivariate Normal Probabilities

    KAUST Repository

    Genton, Marc G.; Keyes, David E.; Turkiyyah, George

    2017-01-01

    We present a hierarchical decomposition scheme for computing the n-dimensional integral of multivariate normal probabilities that appear frequently in statistics. The scheme exploits the fact that the formally dense covariance matrix can be approximated by a matrix with a hierarchical low rank structure. It allows the reduction of the computational complexity per Monte Carlo sample from O(n2) to O(mn+knlog(n/m)), where k is the numerical rank of off-diagonal matrix blocks and m is the size of small diagonal blocks in the matrix that are not well-approximated by low rank factorizations and treated as dense submatrices. This hierarchical decomposition leads to substantial efficiencies in multivariate normal probability computations and allows integrations in thousands of dimensions to be practical on modern workstations.

  16. Hierarchical structure graphitic-like/MoS2 film as superlubricity material

    Science.gov (United States)

    Gong, Zhenbin; Jia, Xiaolong; Ma, Wei; Zhang, Bin; Zhang, Junyan

    2017-08-01

    Friction and wear result in a great amount of energy loss and the invalidation of mechanical parts, thus it is necessary to minimize friction in practical application. In this study, the graphitic-like/MoS2 films with hierarchical structure were synthesized by the combination of pulse current plasma chemical-vapor deposition and medium frequency unbalanced magnetron sputtering in preheated environment. This hierarchical structure composite with multilayer nano sheets endows the films excellent tribological performance, which easily achieves macro superlubricity (friction coefficient ∼0.004) under humid air. Furthermore, it is expected that hierarchical structure of graphitic-like/MoS2 films could match the requirements of large scale, high bear-capacity and wear-resistance of actual working conditions, which could be widely used in the industrial production as a promising superlubricity material.

  17. The concept of a hierarchical cosmos

    Science.gov (United States)

    Grujić, P. V.

    2003-10-01

    The idea of a hierachically structured cosmos can be traced back to the Presocratic Hellada. In the fifth century BC Anaxagoras from Clazomenae developed an idea of a sort of fractal material world, by introducing the concept of seeds (spermata), or homoeomeries as Aristotle dubbed it later (Grujić 2001). Anaxagoras ideas have been grossly neglected during the Middle Ages, to be invoked by a number of post-Renaissance thinkers, like Leibniz, Kant, etc, though neither of them referred to their Greek predecessor. But the real resurrections of the hierarchical paradigm started at the beginning of the last century, with Fournier and Charlier (Grujić 2002). Second half of the 20th century witnessed an intensive development of the theoretical models based on the (multi)fractal paradigm, as well as a considerable body of the observational evidence in favour of the hierarchical cosmos (Saar 1988). We overview the state of the art of the cosmological fractal concept, both within the astrophysical (Sylos Labini et al 1998), methodological (Ribeiro 2001) and epistemological (Ribeiro and Videira 1998) context.

  18. A self-defining hierarchical data system

    Science.gov (United States)

    Bailey, J.

    1992-01-01

    The Self-Defining Data System (SDS) is a system which allows the creation of self-defining hierarchical data structures in a form which allows the data to be moved between different machine architectures. Because the structures are self-defining they can be used for communication between independent modules in a distributed system. Unlike disk-based hierarchical data systems such as Starlink's HDS, SDS works entirely in memory and is very fast. Data structures are created and manipulated as internal dynamic structures in memory managed by SDS itself. A structure may then be exported into a caller supplied memory buffer in a defined external format. This structure can be written as a file or sent as a message to another machine. It remains static in structure until it is reimported into SDS. SDS is written in portable C and has been run on a number of different machine architectures. Structures are portable between machines with SDS looking after conversion of byte order, floating point format, and alignment. A Fortran callable version is also available for some machines.

  19. A Hierarchal Risk Assessment Model Using the Evidential Reasoning Rule

    Directory of Open Access Journals (Sweden)

    Xiaoxiao Ji

    2017-02-01

    Full Text Available This paper aims to develop a hierarchical risk assessment model using the newly-developed evidential reasoning (ER rule, which constitutes a generic conjunctive probabilistic reasoning process. In this paper, we first provide a brief introduction to the basics of the ER rule and emphasize the strengths for representing and aggregating uncertain information from multiple experts and sources. Further, we discuss the key steps of developing the hierarchical risk assessment framework systematically, including (1 formulation of risk assessment hierarchy; (2 representation of both qualitative and quantitative information; (3 elicitation of attribute weights and information reliabilities; (4 aggregation of assessment information using the ER rule and (5 quantification and ranking of risks using utility-based transformation. The proposed hierarchical risk assessment framework can potentially be implemented to various complex and uncertain systems. A case study on the fire/explosion risk assessment of marine vessels demonstrates the applicability of the proposed risk assessment model.

  20. Hierarchical VOOH hollow spheres for symmetrical and asymmetrical supercapacitor devices

    Science.gov (United States)

    Jing, Xuyang; Wang, Cong; Feng, Wenjing; Xing, Na; Jiang, Hanmei; Lu, Xiangyu; Zhang, Yifu; Meng, Changgong

    2018-01-01

    Hierarchical VOOH hollow spheres with low crystallinity composed of nanoparticles were prepared by a facile and template-free method, which involved a precipitation of precursor microspheres in aqueous solution at room temperature and subsequent hydrothermal reaction. Quasi-solid-state symmetric and asymmetric supercapacitor (SSC and ASC) devices were fabricated using hierarchical VOOH hollow spheres as the electrodes, and the electrochemical properties of the VOOH//VOOH SSC device and the VOOH//AC ASC device were studied by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS). Results demonstrated that the electrochemical performance of the VOOH//AC ASC device was better than that of the VOOH//VOOH SSC device. After 3000 cycles, the specific capacitance of the VOOH//AC ASC device retains 83% of the initial capacitance, while the VOOH//VOOH SSC device retains only 7.7%. Findings in this work proved that hierarchical VOOH hollow spheres could be a promising candidate as an ideal electrode material for supercapacitor devices.