WorldWideScience

Sample records for biobased motor fuels

  1. The KFB Program on Biobased Fuels for Vehicles

    International Nuclear Information System (INIS)

    1996-12-01

    KFB supports research and demonstration projects for bio-based transport fuels, alcohols and biogas. The program started in 1991 and will continue through 1997. The program focuses on heavy vehicles, e.g. buses for public transportation. Projects and intermediate results are described in the brochure. Information is also available at the KFB homepage. //www.kfb.se

  2. Life-cycle analysis of bio-based aviation fuels.

    Science.gov (United States)

    Han, Jeongwoo; Elgowainy, Amgad; Cai, Hao; Wang, Michael Q

    2013-12-01

    Well-to-wake (WTWa) analysis of bio-based aviation fuels, including hydroprocessed renewable jet (HRJ) from various oil seeds, Fischer-Tropsch jet (FTJ) from corn-stover and co-feeding of coal and corn-stover, and pyrolysis jet from corn stover, is conducted and compared with petroleum jet. WTWa GHG emission reductions relative to petroleum jet can be 41-63% for HRJ, 68-76% for pyrolysis jet and 89% for FTJ from corn stover. The HRJ production stage dominates WTWa GHG emissions from HRJ pathways. The differences in GHG emissions from HRJ production stage among considered feedstocks are much smaller than those from fertilizer use and N2O emissions related to feedstock collection stage. Sensitivity analyses on FTJ production from coal and corn-stover are also conducted, showing the importance of biomass share in the feedstock, carbon capture and sequestration options, and overall efficiency. For both HRJ and FTJ, co-product handling methods have significant impacts on WTWa results. Copyright © 2013 Elsevier Ltd. All rights reserved.

  3. Motor Fuel Excise Taxes

    Energy Technology Data Exchange (ETDEWEB)

    2015-09-01

    A new report from the National Renewable Energy Laboratory (NREL) explores the role of alternative fuels and energy efficient vehicles in motor fuel taxes. Throughout the United States, it is common practice for federal, state, and local governments to tax motor fuels on a per gallon basis to fund construction and maintenance of our transportation infrastructure. In recent years, however, expenses have outpaced revenues creating substantial funding shortfalls that have required supplemental funding sources. While rising infrastructure costs and the decreasing purchasing power of the gas tax are significant factors contributing to the shortfall, the increased use of alternative fuels and more stringent fuel economy standards are also exacerbating revenue shortfalls. The current dynamic places vehicle efficiency and petroleum use reduction polices at direct odds with policies promoting robust transportation infrastructure. Understanding the energy, transportation, and environmental tradeoffs of motor fuel tax policies can be complicated, but recent experiences at the state level are helping policymakers align their energy and environmental priorities with highway funding requirements.

  4. Stabilizing motor fuels

    Energy Technology Data Exchange (ETDEWEB)

    1935-07-12

    Motor fuel is stabilized by adding less than 2% of a tar fraction from peat, coal, torbanite or shale, said fraction containing sufficient constituents boiling between 200 and 325/sup 0/C, to inhibit gum formation. Low-temperature coal-tar fractions are specified. The preferred boiling ranges are from 225 or 250/sup 0/ to 275/sup 0/C. In examples, the quantity added was 0.01%. The fuel may be a cracked distillate of gasoline boiling-point range or containing gasoline, and may contain relatively large proportions of di- and tri-olefines. The material added to the fuel may be (1) the tar fraction itself; (2) its alkali-soluble constituents; (3) its acid-soluble constituents; (4) a mixture of (2) and (3); (5) a blend of (2), (3) or (4) with a normal tar fraction; (6) the residue after extraction with alkali; (7) the residue after extraction with acid and alkali.

  5. Motor fuel prices in Turkey

    International Nuclear Information System (INIS)

    Erdogdu, Erkan

    2014-01-01

    The world's most expensive motor fuel (gasoline, diesel and LPG) is sold most likely in the Republic of Turkey. This paper investigates the key issues related to the motor fuel prices in Turkey. First of all, the paper analyses the main reason behind high prices, namely motor fuel taxes in Turkey. Then, it estimates the elasticity of motor fuel demand in Turkey using an econometric analysis. The findings indicate that motor fuel demand in Turkey is quite inelastic and, therefore, not responsive to price increases caused by an increase in either pre-tax prices or taxes. Therefore, fuel market in Turkey is open to opportunistic behavior by firms (through excessive profits) and the government (through excessive taxes). Besides, the paper focuses on the impact of high motor fuel prices on road transport associated activities, including the pattern of passenger transportation, motorization rate, fuel use, total kilometers traveled and CO 2 emissions from road transportation. The impact of motor fuel prices on income distribution in Turkey and Turkish public opinion about high motor fuel prices are also among the subjects investigated in the course of the study. - Highlights: • The key issues (e.g. taxes) related to motor fuel prices in Turkey are explored. • Their impact on transport activities and income distribution is also investigated. • An econometric analysis is performed to estimate motor fuel demand in Turkey. • Motor fuel demand in Turkey is found to be quite inelastic. • Turkish fuel market is open to opportunistic behavior by firms and the government

  6. Wet motor geroter fuel pump

    Energy Technology Data Exchange (ETDEWEB)

    Wiernicki, M.V.

    1987-05-05

    This patent describes a wet motor gerotor fuel pump for pumping fuel from a fuel source to an internal combustion which consists of: gerotor pump means comprising an inner pump gear, an outer pump gear, and second tang means located on one of the inner and outer pump gears. The second tang means further extends in a second radial direction radially offset from the first radial direction and forms a driving connection with the first tang means such that the fuel pump pumps fuel from the fuel source into the narrow conduit inlet chamber, through the gerotor pump means past the electric motor means into the outlet housing means substantially along the flow axis to the internal combustion engine.

  7. Comparison of radiocarbon techniques for the assessment of biobase content in fuels

    International Nuclear Information System (INIS)

    Culp, Randy; Cherkinsky, Alex; Ravi Prasad, G.V.

    2014-01-01

    A comparison was made between various radiocarbon measurement techniques for the purpose of quantifying each methods capability for the proper apportionment of biobase-derived additives to gasoline. Measurement techniques include (1) direct liquid scintillation counting, (2) carbon dioxide absorption followed by liquid scintillation counting, (3) conversion to benzene followed by liquid scintillation counting and (4) accelerator mass spectrometry. In addition, stable isotope ratios of carbon and hydrogen were determined to assist in the authentication of a fuels source with regard to petrochemical or biobase origin is required for the confirmation of minimum anti-knock components, consumer awareness and proper assessment for regulatory taxation. Accelerator mass spectrometry was found to be the most precise technique followed by conversion of fuel to benzene with liquid scintillation counting and direct counting by liquid scintillation counting. Finally, liquid scintillation counting of absorbed carbon dioxide was found to be the least precise and should not be used for this analysis. The high to low precisions correlate with the high to low cost of equipment and support required by each of these methods except for direct liquid scintillation counting. Therefore, laboratories interested in developing capability to perform such authentication can use this data to consider the economics of the optimum technique to use for radiocarbon measurement

  8. Comparison of radiocarbon techniques for the assessment of biobase content in fuels.

    Science.gov (United States)

    Culp, Randy; Cherkinsky, Alex; Ravi Prasad, G V

    2014-11-01

    A comparison was made between various radiocarbon measurement techniques for the purpose of quantifying each methods capability for the proper apportionment of biobase-derived additives to gasoline. Measurement techniques include (1) direct liquid scintillation counting, (2) carbon dioxide absorption followed by liquid scintillation counting, (3) conversion to benzene followed by liquid scintillation counting and (4) accelerator mass spectrometry. In addition, stable isotope ratios of carbon and hydrogen were determined to assist in the authentication of a fuels source with regard to petrochemical or biobase origin is required for the confirmation of minimum anti-knock components, consumer awareness and proper assessment for regulatory taxation. Accelerator mass spectrometry was found to be the most precise technique followed by conversion of fuel to benzene with liquid scintillation counting and direct counting by liquid scintillation counting. Finally, liquid scintillation counting of absorbed carbon dioxide was found to be the least precise and should not be used for this analysis. The high to low precisions correlate with the high to low cost of equipment and support required by each of these methods except for direct liquid scintillation counting. Therefore, laboratories interested in developing capability to perform such authentication can use this data to consider the economics of the optimum technique to use for radiocarbon measurement. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials

    NARCIS (Netherlands)

    Weiss, M.|info:eu-repo/dai/nl/156419912; Patel, M.K.|info:eu-repo/dai/nl/18988097X; Heilmeier, H.; Bringezu, S.

    2007-01-01

    The enhanced use of biomass for the production of energy, fuels, and materials is one of the key strategies towards sustainable production and consumption. Various life cycle assessment (LCA) studies demonstrate the great potential of bio-based products to reduce both the consumption of

  10. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Petrik, Michael [Technology Management Inc., Cleveland, OH (United States); Ruhl, Robert [Technology Management Inc., Cleveland, OH (United States)

    2012-05-01

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled Small Scale SOFC Demonstration using Bio-based and Fossil Fuels. Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  11. MOTOR FUEL TAXES AND THE ENVIRONMENTAL PROTECTION

    OpenAIRE

    Michal Ptak

    2011-01-01

    Motor fuel taxes are primarily revenue-raising taxes. However, due to high fuel consumption these taxes can be quite an efficient source of general budget revenue in many countries. It seems that the taxes on motor fuels may also be useful instruments for environmental policy or climate change policy. Environmental objectives can be achieved through change of behavior of drivers. The paper presents theoretical basis for taxes levied on motor fuels. Attention is paid to the problem of external...

  12. Applying distance-to-target weighing methodology to evaluate the environmental performance of bio-based energy, fuels, and materials

    International Nuclear Information System (INIS)

    Weiss, Martin; Patel, Martin; Heilmeier, Hermann; Bringezu, Stefan

    2007-01-01

    The enhanced use of biomass for the production of energy, fuels, and materials is one of the key strategies towards sustainable production and consumption. Various life cycle assessment (LCA) studies demonstrate the great potential of bio-based products to reduce both the consumption of non-renewable energy resources and greenhouse gas emissions. However, the production of biomass requires agricultural land and is often associated with adverse environmental effects such as eutrophication of surface and ground water. Decision making in favor of or against bio-based and conventional fossil product alternatives therefore often requires weighing of environmental impacts. In this article, we apply distance-to-target weighing methodology to aggregate LCA results obtained in four different environmental impact categories (i.e., non-renewable energy consumption, global warming potential, eutrophication potential, and acidification potential) to one environmental index. We include 45 bio- and fossil-based product pairs in our analysis, which we conduct for Germany. The resulting environmental indices for all product pairs analyzed range from -19.7 to +0.2 with negative values indicating overall environmental benefits of bio-based products. Except for three options of packaging materials made from wheat and cornstarch, all bio-based products (including energy, fuels, and materials) score better than their fossil counterparts. Comparing the median values for the three options of biomass utilization reveals that bio-energy (-1.2) and bio-materials (-1.0) offer significantly higher environmental benefits than bio-fuels (-0.3). The results of this study reflect, however, subjective value judgments due to the weighing methodology applied. Given the uncertainties and controversies associated not only with distance-to-target methodologies in particular but also with weighing approaches in general, the authors strongly recommend using weighing for decision finding only as a

  13. Opportunities for Bio-Based Solvents Created as Petrochemical and Fuel Products Transition towards Renewable Resources.

    Science.gov (United States)

    Clark, James H; Farmer, Thomas J; Hunt, Andrew J; Sherwood, James

    2015-07-28

    The global bio-based chemical market is growing in size and importance. Bio-based solvents such as glycerol and 2-methyltetrahydrofuran are often discussed as important introductions to the conventional repertoire of solvents. However adoption of new innovations by industry is typically slow. Therefore it might be anticipated that neoteric solvent systems (e.g., ionic liquids) will remain niche, while renewable routes to historically established solvents will continue to grow in importance. This review discusses bio-based solvents from the perspective of their production, identifying suitable feedstocks, platform molecules, and relevant product streams for the sustainable manufacturing of conventional solvents.

  14. Opportunities for Bio-Based Solvents Created as Petrochemical and Fuel Products Transition towards Renewable Resources

    Science.gov (United States)

    Clark, James H.; Farmer, Thomas J.; Hunt, Andrew J.; Sherwood, James

    2015-01-01

    The global bio-based chemical market is growing in size and importance. Bio-based solvents such as glycerol and 2-methyltetrahydrofuran are often discussed as important introductions to the conventional repertoire of solvents. However adoption of new innovations by industry is typically slow. Therefore it might be anticipated that neoteric solvent systems (e.g., ionic liquids) will remain niche, while renewable routes to historically established solvents will continue to grow in importance. This review discusses bio-based solvents from the perspective of their production, identifying suitable feedstocks, platform molecules, and relevant product streams for the sustainable manufacturing of conventional solvents. PMID:26225963

  15. 40 CFR 79.33 - Motor vehicle diesel fuel.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Motor vehicle diesel fuel. 79.33... diesel fuel. (a) The following fuels commonly or commercially known or sold as motor vehicle diesel fuel are hereby individually designated: (1) Motor vehicle diesel fuel, grade 1-D; (2) Motor vehicle diesel...

  16. High-Throughput Screening of Heterogeneous Catalysts for the Conversion of Furfural to Bio-Based Fuel Components

    Directory of Open Access Journals (Sweden)

    Roberto Pizzi

    2015-12-01

    Full Text Available The one-pot catalytic reductive etherification of furfural to 2-methoxymethylfuran (furfuryl methyl ether, FME, a valuable bio-based chemical or fuel, is reported. A large number of commercially available hydrogenation heterogeneous catalysts based on nickel, copper, cobalt, iridium, palladium and platinum catalysts on various support were evaluated by a high-throughput screening approach. The reaction was carried out in liquid phase with a 10% w/w furfural in methanol solution at 50 bar of hydrogen. Among all the samples tested, carbon-supported noble metal catalysts were found to be the most promising in terms of productivity and selectivity. In particular, palladium on charcoal catalysts show high selectivity (up to 77% to FME. Significant amounts of furfuryl alcohol (FA and 2-methylfuran (2-MF are observed as the major by-products.

  17. Conversion of hydrocarbon oils into motor fuels

    Energy Technology Data Exchange (ETDEWEB)

    1937-11-09

    The abstract describes a process for producing lower boiling hydrocarbon motor fuels with a starting material of wide boiling range composed primarily of hydrocarbon oils boiling substantially above the boiling range of the desired product. Separate catalytic and pyrolytic conversion zones are simultaneously maintained in an interdependent relationship. Higher boiling constituents are separated from residual constituents by fractionation while desirable reaction conditions are maintained. All or at least a portion of the products from the catalytic and pyrolytic conversion zones are blended to yield the desired lower boiling hydrocarbons or motor fuels.

  18. Alternative motor fuels today and tomorrow

    International Nuclear Information System (INIS)

    Bensaid, B.

    2004-01-01

    Today, petroleum products account for 97% of the energy consumed in road transport. The purpose of replacing these products with alternative energies is to reduce oil dependence as well as greenhouse gas emissions. The high price of oil has promoted the use of 'conventional' alternative motor fuels (biofuels, LPG, NGV) and also renewed interest in syn-fuels (GTL, CTL, BTL) that have already given rise to industrial and pilot projects. (author)

  19. 46 CFR 153.1025 - Motor fuel antiknock compounds.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Motor fuel antiknock compounds. 153.1025 Section 153... Cargo Procedures § 153.1025 Motor fuel antiknock compounds. (a) No person may load or carry any other cargo in a containment system approved for motor fuel antiknock compounds containing lead alkyls except...

  20. 46 CFR 151.50-6 - Motor fuel antiknock compounds.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Motor fuel antiknock compounds. 151.50-6 Section 151.50... BARGES CARRYING BULK LIQUID HAZARDOUS MATERIAL CARGOES Special Requirements § 151.50-6 Motor fuel antiknock compounds. When transporting motor fuel antiknock compounds containing tetraethyl lead and...

  1. Extraction of medium chain fatty acids from organic municipal waste and subsequent production of bio-based fuels.

    Science.gov (United States)

    Kannengiesser, Jan; Sakaguchi-Söder, Kaori; Mrukwia, Timo; Jager, Johannes; Schebek, Liselotte

    2016-01-01

    This paper provides an overview on investigations for a new technology to generate bio-based fuel additives from bio-waste. The investigations are taking place at the composting plant in Darmstadt-Kranichstein (Germany). The aim is to explore the potential of bio-waste as feedstock in producing different bio-based products (or bio-based fuels). For this investigation, a facultative anaerobic process is to be integrated into the normal aerobic waste treatment process for composting. The bio-waste is to be treated in four steps to produce biofuels. The first step is the facultative anaerobic treatment of the waste in a rotting box namely percolate to generate a fatty-acid rich liquid fraction. The Hydrolysis takes place in the rotting box during the waste treatment. The organic compounds are then dissolved and transferred into the waste liquid phase. Browne et al. (2013) describes the hydrolysis as an enzymatically degradation of high solid substrates to soluble products which are further degraded to volatile fatty acids (VFA). This is confirmed by analytical tests done on the liquid fraction. After the percolation, volatile and medium chain fatty acids are found in the liquid phase. Concentrations of fatty acids between 8.0 and 31.5 were detected depending on the nature of the input material. In the second step, a fermentation process will be initiated to produce additional fatty acids. Existing microorganism mass is activated to degrade the organic components that are still remaining in the percolate. After fermentation the quantity of fatty acids in four investigated reactors increased 3-5 times. While fermentation mainly non-polar fatty acids (pentanoic to octanoic acid) are build. Next to the fermentation process, a chain-elongation step is arranged by adding ethanol to the fatty acid rich percolate. While these investigations a chain-elongation of mainly fatty acids with pair numbers of carbon atoms (acetate, butanoic and hexanoic acid) are demonstrated. After

  2. Fuel cell usage in motor vehicles

    International Nuclear Information System (INIS)

    Vellone, R.

    1998-01-01

    Much interest has been aroused by fuel cell usage in motor vehicles, since this technology seems to overcome the conventional limits by other kinds of drive, i.e. the high environmental impact of internal-combustion engines and the drawbacks of electric battery vehicles in terms of maximum operating range and battery recharge time. After 2010 its costs are expected to fall in competitive levels with internal-combustion engines [it

  3. Alternative bio-based fuels for aviation: the clean airports program

    International Nuclear Information System (INIS)

    Shauck, M.E.; Zanin, M.G.

    1997-01-01

    The Renewable Aviation Fuels Development Center at Baylor University in Waco, Texas, has been designated as the national coordinator of the Clean Airports Program. The U.S. Dept. of Energy (US DOE) conferred this designation in March 1996. This program, a spin-off of the Clean Cities Program, was initiated to increase the use of alternative fuels in aviation. The two major fuels used in aviation are the current piston engine aviation gasoline and the current turbine engine fuel. The environmental impact of each of these fuels is significant. Aviation gasoline (100LL), currently used in the general aviation piston engine fleet, contributes 100% of the emissions containing lead in the U.S. today. Turbine engine fuel (jet fuel) produces two major environmental impacts: a local one, in the vicinity of the airports, and a global impact on climate change. The Clean Airports Program was established to achieve and maintain clean air at and in the vicinity of airports, through the use of alternative fuel-powered air and ground transportation vehicles. (author)

  4. 40 CFR 69.51 - Motor vehicle diesel fuel.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Motor vehicle diesel fuel. 69.51... (CONTINUED) SPECIAL EXEMPTIONS FROM REQUIREMENTS OF THE CLEAN AIR ACT Alaska § 69.51 Motor vehicle diesel... motor vehicle diesel fuel standards and dye provisions under 40 CFR 80.520 and associated requirements...

  5. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    None

    2015-06-01

    This article investigates upgrading biomass pyrolysis vapors to form hydrocarbon fuels and chemicals using catalysts with different concentrations of acid sites. It shows that greater separation of acid sites makes catalysts more efficient at producing hydrocarbon fuels and chemicals. The conversion of biomass into liquid transportation fuels has attracted significant attention because of depleting fossil fuel reserves and environmental concerns resulting from the use of fossil fuels. Biomass is a renewable resource, which is abundant worldwide and can potentially be exploited to produce transportation fuels that are less damaging to the environment. This renewable resource consists of cellulose (40–50%), hemicellulose (25–35%), and lignin (16–33%) biopolymers in addition to smaller quantities of inorganic materials such as silica and alkali and alkaline earth metals (calcium and potassium). Fast pyrolysis is an attractive thermochemical technology for converting biomass into precursors for hydrocarbon fuels because it produces up to 75 wt% bio-oil,1 which can be upgraded to feedstocks and/or blendstocks for further refining to finished fuels. Bio-oil that has not been upgraded has limited applications because of the presence of oxygen-containing functional groups, derived from cellulose, hemicellulose and lignin, which gives rise to high acidity, high viscosity, low heating value, immiscibility with hydrocarbons and aging during storage. Ex situ catalytic vapor phase upgrading is a promising approach for improving the properties of bio-oil. The goal of this process is to reject oxygen and produce a bio-oil with improved properties for subsequent downstream conversion to hydrocarbons.

  6. Motor fuels by hydrogenation of liquid hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    1938-05-07

    A process is disclosed for the production of knock-stable low-boiling motor fuels by conversion of liquid hydrocarbons which are vaporizable under the reaction conditions, which comprises passing the initial material at a temperature above 380/sup 0/C in a true vapor phase under pressure of more than 40 atmospheres together with hydrogen and gaseous hydrocarbons containing more than 1 carbon atom in the molecule in an amount by volume larger than that of the hydrogen over catalysts stable to poisoning stationarily confined in the reaction vessel.

  7. IEA-Advanced Motor Fuels Annual Report 2010

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-12-02

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes the agreement, activities, and projects for the year. A section on the global situation for Advanced Motor Fuels includes country reports from each participating AMF member. A status report on each active annex for the agreement is also included, as is a message from the AMF Chairman. Final sections include an Outlook for Advanced Motor Fuels, further information, and a glossary of terms.

  8. Conversion of olefins to liquid motor fuels

    Science.gov (United States)

    Rabo, Jule A.; Coughlin, Peter K.

    1988-01-01

    Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

  9. Primer on Motor Fuel Excise Taxes and the Role of Alternative Fuels and Energy Efficient Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, Alex [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2015-08-26

    Motor fuel taxes were established to finance our nation’s transportation infrastructure, yet evolving economic, political, and technological influences are constraining this ability. At the federal level, the Highway Trust Fund (HTF), which is primarily funded by motor fuel taxes, has become increasingly dependent on general fund contributions and short-term reauthorizations to prevent insolvency. As a result, there are discussions at both the federal and state levels in which stakeholders are examining the future of motor fuel excise taxes as well as the role of electric and alternative fuel vehicles in that future. On July 1, 2015, six states increased their motor fuel tax rates.

  10. Motor vehicle fuel economy, the forgotten HC control stragegy?

    Energy Technology Data Exchange (ETDEWEB)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  11. Potential of Coproduction of Energy, Fuels and Chemicals from Biobased Renewable Resources. Transition Path 3. Co-production of Energy, Fuels and Chemicals

    International Nuclear Information System (INIS)

    2006-11-01

    This report shows how in 2030, biobased alternatives can potentially cover up to 30% of the Netherlands' domestic energy and chemicals demand, effectively reducing CO2 emissions. Maximizing the economical potential of biobased alternatives seems the most attractive strategy. The method to compare various routes has been highly simplified and the conclusions of this report are only valid within the limitations of the underlying assumptions. Nevertheless, the Working group WISE BIOMAS of the Platform Biobased Raw Materials feels that the conclusions are valuable for Dutch policy makers and others interested in the use of biobased raw materials. In 2030, biobased alternatives are expected to be sufficiently competitive to fossil-based alternatives, even without subsidies. They are expected to play a significant role in an energy mix comprised of other renewables as well as 'clean' fossil energy sources. Presently, however, the Netherlands needs to step up its stimulation of biobased applications, through substantial investments in R and D programmes, demonstration plants, as well as measures to stimulate implementation. The whole package of tax reductions, local government purchases, etc., as well as direct financial support should amount to approximately 500 million euros per year. The simplified study presented here provides input for more realistic macro-economic scenario analysis taking actual and updated cost-availability relations including second generation biofuels and biochemicals, land use, international trade, etc., into account. Initial discussions with for instance the Netherlands Bureau for Economic Policy Analysis (Centraal Plan Bureau or CPB) have taken place, but are not covered in this report. It is urgently suggested to update macro-economic scenarios for securing the best Netherlands' position among the accelerating global development towards biobased resources

  12. 40 CFR 80.532 - How are motor vehicle diesel fuel credits used and transferred?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How are motor vehicle diesel fuel... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel....532 How are motor vehicle diesel fuel credits used and transferred? (a) Credit use stipulations. Motor...

  13. 40 CFR 80.581 - What are the batch testing and sample retention requirements for motor vehicle diesel fuel, NRLM...

    Science.gov (United States)

    2010-07-01

    ... retention requirements for motor vehicle diesel fuel, NRLM diesel fuel, and ECA marine fuel? 80.581 Section...) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel... requirements for motor vehicle diesel fuel, NRLM diesel fuel, and ECA marine fuel? (a) Beginning on June 1...

  14. 40 CFR 80.531 - How are motor vehicle diesel fuel credits generated?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How are motor vehicle diesel fuel... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel... are motor vehicle diesel fuel credits generated? (a) Generation of credits from June 1, 2006 through...

  15. Possibilities of Using Hydrogen as Motor Vehicle Fuel

    Directory of Open Access Journals (Sweden)

    Zdravko Bukljaš

    2005-03-01

    Full Text Available Hydrogen is the fuel of the future, since it is the element ofwater (H20 whichsun·ounds us and the resources of which areunlimited. First water is divided into hydrogen and oxygen. Thepaper presents the laboratory and industrial methods of obtain·ing hydrogen, types of fuel cells for various purposes, hydrogen-propelled motor vehicles, as well as advantages and drawbacksof hydrogen used as fuel under the conditions that haveto be met in order to use it as propulsion energy for motor vehicles.

  16. Wet motor gerotor fuel pump with self-aligning bearing

    Energy Technology Data Exchange (ETDEWEB)

    Carleton, W.A.

    1987-02-24

    A wet motor gerotor fuel pump is described for pumping fuel from a fuel source to an internal combustion engine comprising: a pump case having one end, an opposite end and a flow axis therethrough, the pump case further comprising an inlet end bore at the one end adapted to communicate with the fuel source; an inlet chamber adjacent to the inlet end bore; a motor chamber located in the opposite end of the pump case; a pump chamber interposed the motor chamber and the inlet chamber; first means for sealing the pump case, the first means for sealing located at the opposite end of the pump case; inlet housing means mounted in the pump chamber, the inlet housing means comprising an annular hub protruding into the inlet chamber. The inlet housing means further comprises a gerotor cavity about a gerotor axis located parallel to and displaced a predetermined distance in an eccentric radial direction from the flow axis.

  17. Inter-organizational collaboration in bio-based business

    NARCIS (Netherlands)

    Nuhoff-Isakhanyan, Gohar

    2016-01-01

    Globally, bio-based business is often perceived as sustainable, because its renewable production can potentially lower carbon and greenhouse emissions by substituting fossil-fuel-based production, reduce environmental sourcing problems, and create turnover and jobs. However, bio-based business

  18. 40 CFR 80.592 - What records must be kept by entities in the motor vehicle diesel fuel and diesel fuel additive...

    Science.gov (United States)

    2010-07-01

    ... in the motor vehicle diesel fuel and diesel fuel additive distribution systems? 80.592 Section 80.592... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA... the motor vehicle diesel fuel and diesel fuel additive distribution systems? (a) Records that must be...

  19. IEA-Advanced Motor Fuels Annual Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes what the agreement is about, how to join, various activities of the agreement, a message from the Chairman, and projects/annexes active for the year. An annual section covers the global situation for the topic of advanced motor fuels. Another section includes highlights coming from each country participating in AMF, and major sections relaying activities on each of the ongoing annexes. Information regarding participating delegations, contact information, publications resulting from AMF, and upcoming meetings rounds out the report.

  20. IEA-Advanced Motor Fuels Annual Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-06-15

    The annual report from the IEA implementing agreement on Advanced Motor Fuels (AMF) describes what the agreement is about, how to join, various activities of the agreement, a message from the Chairman, and projects/annexes active for the year. An annual section covers the global situation for the topic of advanced motor fuels. Another section includes highlights coming from each country participating in AMF, and major sections relaying activities on each of the ongoing annexes. Information regarding participating delegations, contact information, publications resulting from AMF, and upcoming meetings rounds out the report.

  1. Supply of fossil heating and motor fuels

    International Nuclear Information System (INIS)

    Kaegi, W.; Siegrist, S.; Schaefli, M.; Eichenberger, U.

    2003-01-01

    This comprehensive study made for the Swiss Federal Office of Energy (SFOE) within the framework of the Energy Economics Fundamentals research programme examines if it can be guaranteed that Swiss industry can be supplied with fossil fuels for heating and transport purposes over the next few decades. The results of a comprehensive survey of literature on the subject are presented, with a major focus being placed on oil. The study examines both pessimistic and optimistic views and also presents an overview of fossil energy carriers and the possibilities of substituting them. Scenarios and prognoses on the availability of fossil fuels and their reserves for the future are presented. Also, new technologies for exploration and the extraction of fossil fuels are discussed, as are international interdependencies that influence supply. Market and price scenarios are presented that take account of a possible increasing scarcity of fossil fuels. The implications for industry and investment planning are examined

  2. 40 CFR 80.550 - What is the definition of a motor vehicle diesel fuel small refiner or a NRLM diesel fuel small...

    Science.gov (United States)

    2010-07-01

    ...) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel... vehicle diesel fuel small refiner or a NRLM diesel fuel small refiner under this subpart? (a) A motor...-operational between January 1, 1999, and January 1, 2000, may apply for motor vehicle diesel fuel small...

  3. 78 FR 32223 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards

    Science.gov (United States)

    2013-05-29

    ...-OAR-2011-0135; FRL-9818-5] RIN 2060-A0 Control of Air Pollution From Motor Vehicles: Tier 3 Motor... extension of the public comment period for the proposed rule ``Control of Air Pollution from Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards'' (the proposed rule is hereinafter referred to as...

  4. Toxicological and performance aspects of oxygenated motor vehicle fuels

    National Research Council Canada - National Science Library

    National Research Council Staff; Commission on Life Sciences; Division on Earth and Life Studies; National Research Council; National Academy of Sciences

    ... COMMITTEE ON TOXICOLOGICAL PERFORMANCE ASPECTS OXYGENATED MOTOR VEHICLE FUELS ENVIRONMENTAL STUDIES TOXICOLOGY COMMISSION LIFE SCIENCES NATIONAL RESEARCH COUNCIL AND OF BOARD ON AND ON NATIONAL ACADEMY PRESS Washington, D.C. 1996 i Copyrightoriginal retained, the be not from cannot book, paper original however, for version formatting, authoritative the t...

  5. Motor fuel demand analysis - applied modelling in the European union

    International Nuclear Information System (INIS)

    Chorazewiez, S.

    1998-01-01

    Motor fuel demand in Europe amounts to almost half of petroleum products consumption and to thirty percent of total final energy consumption. This study considers, Firstly, the energy policies of different European countries and the ways in which the consumption of motor gasoline and automotive gas oil has developed. Secondly it provides an abstract of demand models in the energy sector, illustrating their specific characteristics. Then it proposes an economic model of automotive fuel consumption, showing motor gasoline and automotive gas oil separately over a period of thirty years (1960-1993) for five main countries in the European Union. Finally, forecasts of consumption of gasoline and diesel up to the year 2020 are given for different scenarios. (author)

  6. 40 CFR 80.524 - What sulfur content standard applies to motor vehicle diesel fuel downstream of the refinery or...

    Science.gov (United States)

    2010-07-01

    ... to motor vehicle diesel fuel downstream of the refinery or importer? 80.524 Section 80.524 Protection... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.524 What sulfur content standard...

  7. 40 CFR 69.52 - Non-motor vehicle diesel fuel.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 15 2010-07-01 2010-07-01 false Non-motor vehicle diesel fuel. 69.52... (CONTINUED) SPECIAL EXEMPTIONS FROM REQUIREMENTS OF THE CLEAN AIR ACT Alaska § 69.52 Non-motor vehicle diesel... NRLM diesel fuel. (5) Exempt NRLM diesel fuel and heating oil must be segregated from motor vehicle...

  8. Challenges in Building a Sustainable Biobased Economy

    DEFF Research Database (Denmark)

    Mussatto, Solange I.

    2017-01-01

    for the production of fuels, chemicals, energy and materials is therefore recognized as a need by numerous industries and policy makers in countries around the world. In addition, a biobased economy has the potential to generate new jobs and even new industries, creating new opportunities for entrepreneurship...

  9. Toxicological properties of emission particles from heavy duty engines powered by conventional and bio-based diesel fuels and compressed natural gas.

    Science.gov (United States)

    Jalava, Pasi I; Aakko-Saksa, Päivi; Murtonen, Timo; Happo, Mikko S; Markkanen, Ari; Yli-Pirilä, Pasi; Hakulinen, Pasi; Hillamo, Risto; Mäki-Paakkanen, Jorma; Salonen, Raimo O; Jokiniemi, Jorma; Hirvonen, Maija-Riitta

    2012-09-29

    One of the major areas for increasing the use of renewable energy is in traffic fuels e.g. bio-based fuels in diesel engines especially in commuter traffic. Exhaust emissions from fossil diesel fuelled engines are known to cause adverse effects on human health, but there is very limited information available on how the new renewable fuels may change the harmfulness of the emissions, especially particles (PM). We evaluated the PM emissions from a heavy-duty EURO IV diesel engine powered by three different fuels; the toxicological properties of the emitted PM were investigated. Conventional diesel fuel (EN590) and two biodiesels were used - rapeseed methyl ester (RME, EN14214) and hydrotreated vegetable oil (HVO) either as such or as 30% blends with EN590. EN590 and 100% HVO were also operated with or without an oxidative catalyst (DOC + POC). A bus powered by compressed natural gas (CNG) was included for comparison with the liquid fuels. However, the results from CNG powered bus cannot be directly compared to the other situations in this study. High volume PM samples were collected on PTFE filters from a constant volume dilution tunnel. The PM mass emission with HVO was smaller and with RME larger than that with EN590, but both biofuels produced lower PAH contents in emission PM. The DOC + POC catalyst greatly reduced the PM emission and PAH content in PM with both HVO and EN590. Dose-dependent TNFα and MIP-2 responses to all PM samples were mostly at the low or moderate level after 24-hour exposure in a mouse macrophage cell line RAW 264.7. Emission PM from situations with the smallest mass emissions (HVO + cat and CNG) displayed the strongest potency in MIP-2 production. The catalyst slightly decreased the PM-induced TNFα responses and somewhat increased the MIP-2 responses with HVO fuel. Emission PM with EN590 and with 30% HVO blended in EN590 induced the strongest genotoxic responses, which were significantly greater than those with EN590

  10. 26 CFR 48.4041-5 - Sales of diesel and special motor fuels and fuel for use in aircraft; rules of general application.

    Science.gov (United States)

    2010-04-01

    ... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Sales of diesel and special motor fuels and fuel... AND RETAILERS EXCISE TAXES Special Fuels § 48.4041-5 Sales of diesel and special motor fuels and fuel... of a diesel-powered highway vehicle, or of special motor fuel to an owner, lessee, or other operator...

  11. Biodiesel as a motor fuel price stabilization mechanism

    International Nuclear Information System (INIS)

    Serra, Teresa; Gil, José M.

    2012-01-01

    This article studies the capacity of biofuels to reduce motor fuel price fluctuations. For this purpose, we study dependence between crude oil and biodiesel blend prices in Spain. Copula models are used for this purpose. Results suggest that the practice of blending biodiesel with diesel can protect consumers against extreme crude oil price increases. - Highlights: ► We study the capacity of biofuels to reduce fuel price fluctuations. ► We focus on Spanish biodiesel market. ► Biodiesel and crude oil price dependence is studied using copula functions. ► Biodiesel can protect consumers against extreme crude oil price increases.

  12. Hydroprocessed Esters and Fatty Acids (HEFA) Bio-Based Jet Fuels: Sensory Irritation Study and Human Health Hazard Assessment

    Science.gov (United States)

    2013-06-30

    animal that is found moribund, or appears to be in intense, unrelievable pain. The carcass of the animal will be placed in a plastic bag along...ol’ Laboratory Animals ," Institute of Laboratory Animal Resources, National Research Council. AFRL-RH.WP-TR.2014- HAS BEEN REVIEWED AND iS APPROVED...also summarizes toxicity data for HEFA fuels, including HEFA-C, HEFA-T and a HEFA fuel with a feedstock of mixed animal fats and oils (HEFA-F

  13. Comparison of the environmental impacts of motor fuels

    International Nuclear Information System (INIS)

    Pedersen, P.

    1995-01-01

    A short comparison of the most significant environmental impacts of of the use of diesel, natural gas and dimethyl ether motor fuels. In Denmark the transport sector is responsible for more than one third of nitrogen oxides emission, for the major part of the total emission of unburnt hydrocarbons, carbon monoxide and soot particles and for ca. 20% of the country's total emission of carbon dioxide. The method of cleaning exhaust gases is more effective but also results in other forms of pollution and an increased consumption of energy. Preventive technical measures involve the combustion of cleaner-burning motor fuels combined with specific motor design. It is concluded that the immediate environment gains by the substitution of diesel with compressed natural gas, liquefied petroleum gas and dimethyl ether. There are indications that, with regard to the global environment liquefied petroleum gas and compressed natural gas pollute to the same extent as diesel fuels and that dimethyl ether pollutes more. When production methods become more effective this situation might improve. In comparison with petrol, dimethyl ether, liquefied petroleum gas and compressed natural gas pollute are less pollutive to the atmosphere. (AB) 18 refs

  14. Motor fuel taxation, energy conservation, and economic development: A regional approach

    International Nuclear Information System (INIS)

    England, Richard W.

    2007-01-01

    Combustion of motor fuels has a variety of environmental impacts on local, regional and global scales. Taxing motor fuels more heavily would mitigate those environmental impacts. However, many governments are reluctant to increase motor fuel taxes because they fear that the tax incidence will be regressive and that economic development will be impeded. Using data for the New England region of the United States, this paper argues that an oil-importing region can conserve energy, avoid regressive impacts and encourage economic development by taxing motor fuels more heavily and rebating the incremental revenues to owners of motor vehicles. (author)

  15. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery motor vehicle diesel... Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes of this subpart, a refinery's motor vehicle diesel fuel volume baseline is calculated using the...

  16. A methodology for assessing the market benefits of alternative motor fuels: The Alternative Fuels Trade Model

    Energy Technology Data Exchange (ETDEWEB)

    Leiby, P.N.

    1993-09-01

    This report describes a modeling methodology for examining the prospective economic benefits of displacing motor gasoline use by alternative fuels. The approach is based on the Alternative Fuels Trade Model (AFTM). AFTM development was undertaken by the US Department of Energy (DOE) as part of a longer term study of alternative fuels issues. The AFTM is intended to assist with evaluating how alternative fuels may be promoted effectively, and what the consequences of substantial alternative fuels use might be. Such an evaluation of policies and consequences of an alternative fuels program is being undertaken by DOE as required by Section 502(b) of the Energy Policy Act of 1992. Interest in alternative fuels is based on the prospective economic, environmental and energy security benefits from the substitution of these fuels for conventional transportation fuels. The transportation sector is heavily dependent on oil. Increased oil use implies increased petroleum imports, with much of the increase coming from OPEC countries. Conversely, displacement of gasoline has the potential to reduce US petroleum imports, thereby reducing reliance on OPEC oil and possibly weakening OPEC`s ability to extract monopoly profits. The magnitude of US petroleum import reduction, the attendant fuel price changes, and the resulting US benefits, depend upon the nature of oil-gas substitution and the supply and demand behavior of other world regions. The methodology applies an integrated model of fuel market interactions to characterize these effects.

  17. 40 CFR 80.552 - What compliance options are available to motor vehicle diesel fuel small refiners?

    Science.gov (United States)

    2010-07-01

    ... to motor vehicle diesel fuel small refiners? 80.552 Section 80.552 Protection of Environment... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Small Refiner Hardship Provisions § 80.552 What compliance options are available to motor vehicle diesel fuel...

  18. 40 CFR 80.593 - What are the reporting requirements for refiners and importers of motor vehicle diesel fuel...

    Science.gov (United States)

    2010-07-01

    ... for refiners and importers of motor vehicle diesel fuel subject to temporary refiner relief standards... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... the reporting requirements for refiners and importers of motor vehicle diesel fuel subject to...

  19. 40 CFR 80.520 - What are the standards and dye requirements for motor vehicle diesel fuel?

    Science.gov (United States)

    2010-07-01

    ... requirements for motor vehicle diesel fuel? 80.520 Section 80.520 Protection of Environment ENVIRONMENTAL... Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.520 What are the standards and dye requirements for motor vehicle diesel...

  20. BPM Magazine : biobased performance materials

    NARCIS (Netherlands)

    Bolck, C.H.; Bos, H.L.; Gennip, van E.; Zee, van der M.

    2011-01-01

    BPM magazine is een uitgave van het Biobased Performance Materials programma. In dit programma werken kennisinstellingen en bedrijven samen aan nieuwe biobased plastics en aan toepassingsgericht onderzoek om de eigenschappen van bestaande biokunststoffen te verbeteren.

  1. 75 FR 59103 - Defense Federal Acquisition Regulation Supplement; Motor Carrier Fuel Surcharge (DFARS Case 2008...

    Science.gov (United States)

    2010-09-27

    ...-AG30 Defense Federal Acquisition Regulation Supplement; Motor Carrier Fuel Surcharge (DFARS Case 2008... comments is provided below: 1. Comment. One respondent stated that it is customary in the motor carrier freight industry to assume a fixed cost of diesel fuel with a cost recovery mechanism (fuel surcharge) for...

  2. Can bio-based attributes upgrade a brand? How partial and full use of bio-based materials affects the purchase intention of brands

    NARCIS (Netherlands)

    Reinders, Machiel J.; Onwezen, Marleen C.; Meeusen, Marieke J.G.

    2017-01-01

    To reduce human dependency on fossil fuels, increasing attempts are being made to substitute synthetic materials in products with bio-based materials. Global brands attempt to differentiate themselves by adding bio-based materials to their products. However, little is known about consumers'

  3. Catalysts for conversion of syngas to liquid motor fuels

    Science.gov (United States)

    Rabo, Jule A.; Coughlin, Peter K.

    1987-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

  4. Guide to Permitting Hydrogen Motor Fuel Dispensing Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Rivkin, Carl [National Renewable Energy Lab. (NREL), Golden, CO (United States); Buttner, William [National Renewable Energy Lab. (NREL), Golden, CO (United States); Burgess, Robert [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-03-28

    The purpose of this guide is to assist project developers, permitting officials, code enforcement officials, and other parties involved in developing permit applications and approving the implementation of hydrogen motor fuel dispensing facilities. The guide facilitates the identification of the elements to be addressed in the permitting of a project as it progresses through the approval process; the specific requirements associated with those elements; and the applicable (or potentially applicable) codes and standards by which to determine whether the specific requirements have been met. The guide attempts to identify all applicable codes and standards relevant to the permitting requirements.

  5. Impact of reformulated fuels on motor vehicle emissions

    Science.gov (United States)

    Kirchstetter, Thomas

    Motor vehicles continue to be an important source of air pollution. Increased vehicle travel and degradation of emission control systems have offset some of the effects of increasingly stringent emission standards and use of control technologies. A relatively new air pollution control strategy is the reformulation of motor vehicle fuels, both gasoline and diesel, to make them cleaner- burning. Field experiments in a heavily traveled northern California roadway tunnel revealed that use of oxygenated gasoline reduced on-road emissions of carbon monoxide (CO) and volatile organic compounds (VOC) by 23 +/- 6% and 19 +/- 8%, respectively, while oxides of nitrogen (NOx) emissions were not significantly affected. The introduction of reformulated gasoline (RFG) in California led to large changes in gasoline composition including decreases in alkene, aromatic, benzene, and sulfur contents, and an increase in oxygen content. The combined effects of RFG and fleet turnover between summers 1994 and 1997 were decreases in on-road vehicle exhaust emissions of CO, non-methane VOC, and NOx by 31 +/- 5, 43 +/- 8, and 18 +/- 4%, respectively. Although it was difficult to separate the fleet turnover and RFG contributions to these changes, it was clear that the effect of RFG was greater for VOC than for NOx. The RFG effect on exhaust emissions of benzene was a 30-40% reduction. Use of RFG reduced the reactivity of liquid gasoline and gasoline headspace vapors by 23 and 19%, respectively. Increased use of methyl tert-butyl ether in gasoline led to increased concentrations of highly reactive formaldehyde and isobutene in vehicle exhaust. As a result, RFG reduced the reactivity of exhaust emissions by only about 5%. Per unit mass of fuel burned, heavy-duty diesel trucks emit about 25 times more fine particle mass and 15-20 times the number of fine particles compared to light-duty vehicles. Exhaust fine particle emissions from heavy-duty diesels contain more black carbon than particulate

  6. 76 FR 54932 - Revisions and Additions to Motor Vehicle Fuel Economy Label; Correction

    Science.gov (United States)

    2011-09-06

    ...-AK73 Revisions and Additions to Motor Vehicle Fuel Economy Label; Correction AGENCY: Environmental... regarding labeling of cars and trucks with fuel economy and environmental information in the Federal...

  7. Bio-based fuels: an analysis of potential, conditions, market, instruments and risks. Opportunities and risks - the BIODRIV project. Final Report; Biobaserade drivmedel: analys av potential, foerutsaettningar, marknad, styrmedel och risker. Moejligheter och risker - projektet BIODRIV. Slutrapport

    Energy Technology Data Exchange (ETDEWEB)

    Rydberg, Tomas (IVL Svenska Miljoeinstitutet, Stockholm (Sweden)); Gaardfeldt, Katarina; Ahlbaeck, Anders (Goeteborgs Miljoevetenskapliga Centrum, Chalmers Tekniska Hoegskola och Goeteborgs Universitet (Sweden)) (and others)

    2010-12-15

    The BIODRIV project is a study of the conditions, opportunities, constraints and risks in the short and long term for the Swedish production of biofuels, with specific focus on the production opportunities offered by the Swedish refineries. The study was conducted at Chalmers Univ. of Technology and IVL Swedish Environmental Research Inst. with support from Preem Environment Foundation and the Foundation of IVL. Researchers in the disciplines of environmental economics, chemical engineering and environmental system analysis have been working collectively to illustrate various technology tracks for bio-based fuel production. A total of six technology tracks for biofuel production have been identified in the long run, in whole or in part, which can replace today's fossil-based fuels in the transport sector. The six technology tracks are: methane from gas networks, decentralized pyrolysis/gasification, different resource bases to fat, hydrogen, methanol, electricity

  8. Serviceability of rod ceramic fuel pins on motoring conditions of FTP or NEMF reactor

    International Nuclear Information System (INIS)

    Deryavko, I.I.

    2004-01-01

    The operation conditions of rod ceramic fuel pins in the running hydrogen-cooled technological canals of FTP or NEMF reactor on the motoring conditions are considered. The available postreactor researches of the fuel pins are presented and the additional postreactor researches of fuel pins, tested on this mode in IVG.1 and IRGIT reactors, are carried out. The fuel pins serviceability on motoring conditions of FTP or NEF reactor operation is concluded. (author)

  9. Biobased Plastics 2012

    NARCIS (Netherlands)

    Bolck, C.H.; Ravenstijn, J.; Molenveld, K.; Harmsen, P.F.H.

    2011-01-01

    Dit boek geeft inzicht in de huidige op de markt verkrijgbare biobased plastics en de te verwachten ontwikkelingen. Er wordt gekeken naar zowel thermoplastische als thermohardende materialen. Het boek biedt inzicht in de productie, verwerking en eigenschappen van de verschillende types. Daarnaast

  10. adaptation of natural gas for motor fuels in nigeria transport system

    African Journals Online (AJOL)

    In recent years, as a result of limiting reserve of crude oil and the clamour for the deregulation of the petroleum sector of the nation's economy, there is need to look beyond liquid fuel (gasoline, diesel) as vehicular fuels. The viability of adapting natural gas for motor fuels had been presented. Natural gas as automobile fuel ...

  11. Acute Dermal Irritation Study of Ten Jet Fuels in New Zealand White Rabbits: Comparison of Synthetic and Bio-Based Jet Fuels with Petroleum JP-8

    Science.gov (United States)

    2014-02-18

    C.A. 2008. Comparative Evaluation of Semi-Synthetic Jet Fuels. Dayton OH: Universal Technology Corporation. http://crcao.org/publications/aviation...Acrobat, PDF) Master Schedule Maintains the master schedule for the company. Metasys DDC Electronic Environmental Control System Controls and

  12. Environmental Comparison of Biobased Chemicals from Glutamic Acid with Their Petrochemical Equivalents

    NARCIS (Netherlands)

    Lammens, T.M.; Potting, J.; Sanders, J.P.M.; Boer, de I.J.M.

    2011-01-01

    Glutamic acid is an important constituent of waste streams from biofuels production. It is an interesting starting material for the synthesis of biobased chemicals, thereby decreasing the dependency on fossil fuels. The objective of this paper was to compare the environmental impact of four biobased

  13. Environmental comparison of biobased chemicals from glutamic acid with their petrochemical equivalents

    NARCIS (Netherlands)

    Lammens, T.M.; Potting, J.; Sanders, J.P.M.; Boer, de I.J.M.

    2012-01-01

    Glutamic acid is an important constituent of waste streams from biofuels production. It is an interesting starting material for the synthesis of biobased chemicals, thereby decreasing the dependency on fossil fuels. The objective of this paper was to compare the environmental impact of four biobased

  14. 48 CFR 970.5223-5 - DOE motor vehicle fleet fuel efficiency.

    Science.gov (United States)

    2010-10-01

    ... and Contract Clauses for Management and Operating Contracts 970.5223-5 DOE motor vehicle fleet fuel..., insert the following clause in contracts providing for Contractor management of the motor vehicle fleet... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false DOE motor vehicle fleet...

  15. Process and catalysts for hydrocarbon conversion. [high antiknock motor fuel

    Energy Technology Data Exchange (ETDEWEB)

    1940-02-14

    High anti-knock motor fuel is produced from hydrocarbons by subjecting it at an elevated temperature to contact with a calcined mixture of hydrated silica, hydrated alumina, and hydrated zirconia, substantially free from alkali metal compounds. The catalyst may be prepared by precipitating silica gel by the acidification of an aqueous solution of an alkali metal silicate, intimately mixing hydrated alumina and hydrated zirconia therewith, drying, purifying the composite to substantially remove alkali metal compounds, again drying, forming the dried material into particles, and finally calcining. The resultant conversion products may be fractionated to produce gasoline, hydrocarbon oil above gasoling boiling point range, and a gaseous fraction of olefins which are polymerized into gasoline boiling range polymers.

  16. Fuel taxes, motor vehicle emission standards and patents related to the fuel-efficiency and emissions of motor vehicles. Joint Meetings of Tax and Environment Experts

    International Nuclear Information System (INIS)

    Vollebergh, H.

    2010-01-01

    Contribution to the project on Taxation, Innovation and the Environment of OECD's Joint Meetings of Tax and Environment Experts. It studies the impacts of motor vehicle fuel taxes and mandatory fuel efficiency standards on relevant car-related innovation activity in selected car-producing countries.

  17. 40 CFR 80.527 - Under what conditions may motor vehicle diesel fuel subject to the 15 ppm sulfur standard be...

    Science.gov (United States)

    2010-07-01

    ... vehicle diesel fuel subject to the 15 ppm sulfur standard be downgraded to motor vehicle diesel fuel... Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor Vehicle Diesel Fuel Standards and Requirements § 80.527 Under what conditions may motor vehicle diesel fuel subject to the 15...

  18. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    Energy Technology Data Exchange (ETDEWEB)

    Blaser, Richard

    1980-11-01

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  19. 40 CFR 80.594 - What are the pre-compliance reporting requirements for motor vehicle diesel fuel?

    Science.gov (United States)

    2010-07-01

    ... requirements for motor vehicle diesel fuel? 80.594 Section 80.594 Protection of Environment ENVIRONMENTAL... Requirements § 80.594 What are the pre-compliance reporting requirements for motor vehicle diesel fuel? (a... June 1, 2005, all refiners and importers planning to produce or import motor vehicle diesel fuel...

  20. My 2030s. Citizens about the Biobased Economy; My 2030s. Burgers over de Biobased Economy

    Energy Technology Data Exchange (ETDEWEB)

    Van den Berg, N.; Hulshof, M.; Van der Veen, M.

    2013-02-15

    My 2030s is the first qualitative study of the needs and concerns of citizens about the Biobased Economy, an economy in which fossil fuels are largely substituted by vegetable alternatives. This final report describes the reason and purpose of My 2030s, the course of the public debates and the results of research into ideas of citizens on the Biobased Economy The report concludes with recommendations on how the stakeholders can actively involve citizens in one of the major transitions of the next century [Dutch] My 2030s is het eerste kwalitatieve onderzoek naar de wensen en zorgen van burgers over de Biobased Economy, een economie waarin fossiele grondstoffen grotendeels zijn vervangen door plantaardige alternatieven. Dit eindrapport beschrijft de aanleiding en opzet van My 2030s, het verloop van de publieksdebatten en de resultaten van het onderzoek naar denkbeelden van burgers over de Biobased Economy. Het rapport eindigt met aanbevelingen over hoe de stakeholders burgers actief kunnen betrekken bij een van de belangrijkste transities van de komende eeuw.

  1. Motor vehicle fuel economy, the forgotten HC control stragegy. [Hydrocarbon (HC)

    Energy Technology Data Exchange (ETDEWEB)

    Deluchi, M.; Wang, Quanlu; Greene, D.L.

    1992-06-01

    Emissions of hydrocarbons from motor vehicles are recognized as major contributors to ozone pollution in urban areas. Petroleum-based motor fuels contain volatile organic compounds (VOC) which, together with oxides of nitrogen, promote the formation of ozone in the troposphere via complex photochemical reactions. VOC emissions from the tailpipe and evaporation from the fuel and engine systems of highway vehicles are believed to account for about 40% of total VOC emissions in any region. But motor fuels also generate emissions throughout the fuel cycle, from crude oil production to refining, storage, transportation, and handling, that can make significant contributions to the total inventory of VOC emissions. Many of these sources of emissions are directly related to the quantity of fuel produced and handled throughout the fuel cycle. It is, therefore, reasonable to expect that a reduction in total fuel throughput might result in a reduction of VOC emissions. In particular, reducing vehicle fuel consumption by increasing vehicle fuel economy should reduce total fuel throughput, thereby cutting total emissions of VOCS. In this report we identify the sources of VOC emissions throughout the motor fuel cycle, quantify them to the extent possible, and describe their dependence on automobile and light truck fuel economy.

  2. Application of multi-criteria material selection techniques to constituent refinement in biobased composites

    International Nuclear Information System (INIS)

    Miller, Sabbie A.; Lepech, Michael D.; Billington, Sarah L.

    2013-01-01

    Highlights: • Biobased composites have the potential to replace certain engineered materials. • Woven reinforcement can provide better material properties in biobased composites. • Short fiber filler can provide lower environmental impact in biobased composites. • Per function, different fibers are desired to lower composite environmental impact. - Abstract: Biobased composites offer a potentially low environmental impact material option for the construction industries. Designing these materials to meet both performance requirements for an application and minimize environmental impacts requires the ability to refine composite constituents based on environmental impact and mechanical properties. In this research, biobased composites with varying natural fiber reinforcement in a poly(β-hydroxybutyrate)-co-(β-hydroxyvalerate) matrix were characterized based on material properties through experiments and environmental impact through life cycle assessments. Using experimental results, these biobased composites were found to have competitive flexural properties and thermal conductivity with certain short-chopped glass fiber reinforced plastics. Multi-criteria material selection techniques were applied to weigh desired material properties with greenhouse gas emissions, fossil fuel demand, and Eco-Indicator ’99 score. The effects of using different reinforcing fibers in biobased composites were analyzed using the developed selection scheme as a tool for choosing constituents. The use of multi-criteria material selection provided the ability to select fiber reinforcement for biobased composites and showed when it would be more appropriate to use a novel biobased composite or a currently available engineered material

  3. 78 FR 20881 - Control of Air Pollution From Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards...

    Science.gov (United States)

    2013-04-08

    ...The EPA is announcing two public hearings to be held for the proposed rule ``Control of Air Pollution from Motor Vehicles: Tier 3 Motor Vehicle Emission and Fuel Standards'' (the proposed rule is hereinafter referred to as ``Tier 3''), which will be published separately in the Federal Register. The hearings will be held in Philadelphia, PA on April 24, 2013 and in Chicago, IL on April 29, 2013. The comment period for the proposed rulemaking will end on June 13, 2013.

  4. BPM Magazine : biobased performance materials

    NARCIS (Netherlands)

    Bolck, C.H.; Bos, H.L.; Gennip, van E.; Zee, van der M.

    2011-01-01

    BPM magazine is a publication of the Biobased Performance Materials programme. In this programme, knowledge institutions and businesses are working together on new bio-based plastics and application-focused research to improve the properties of existing bio-plastics.

  5. Improvement of the environmental and operational characteristics of vehicles through decreasing the motor fuel density.

    Science.gov (United States)

    Magaril, Elena

    2016-04-01

    The environmental and operational characteristics of motor transport, one of the main consumers of motor fuel and source of toxic emissions, soot, and greenhouse gases, are determined to a large extent by the fuel quality which is characterized by many parameters. Fuel density is one of these parameters and it can serve as an indicator of fuel quality. It has been theoretically substantiated that an increased density of motor fuel has a negative impact both on the environmental and operational characteristics of motor transport. The use of fuels with a high density leads to an increase in carbonization within the engine, adversely affecting the vehicle performance and increasing environmental pollution. A program of technological measures targeted at reducing the density of the fuel used was offered. It includes a solution to the problem posed by changes in the refining capacities ratio and the temperature range of gasoline and diesel fuel boiling, by introducing fuel additives and adding butanes to the gasoline. An environmental tax has been developed which allows oil refineries to have a direct impact on the production of fuels with improved environmental performance, taking into account the need to minimize the density of the fuel within a given category of quality.

  6. 40 CFR 80.530 - Under what conditions can 500 ppm motor vehicle diesel fuel be produced or imported after May 31...

    Science.gov (United States)

    2010-07-01

    ... motor vehicle diesel fuel be produced or imported after May 31, 2006? 80.530 Section 80.530 Protection... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Temporary Compliance Option § 80.530 Under what conditions can 500 ppm motor vehicle diesel...

  7. A projection of motor fuel tax revenue and analysis of alternative revenue sources in Georgia.

    Science.gov (United States)

    2012-05-01

    Motor fuel tax revenue currently supplies the majority of funding for : transportation agencies at the state and federal level. Georgia uses excise and sales taxes : to generate revenue for the Georgia Department of Transportation (GDOT). Inflation a...

  8. Second interim report of the Interagency Commission on Alternative Motor Fuels

    International Nuclear Information System (INIS)

    1991-09-01

    This report describes progress the commission and government agencies have made in implementing the provisions of the Alternative Motor Fuels Act of 1988, assessing the role of alternative motor fuels in the US transportation sector, and developing policies to promote the use of alternative fuels. The alternative motor-fuels policies proposed in the National Energy Strategy (NES) are described and shows how they compose an effective long-term plan to encourage the widespread use of alternative motor fuels. The progress to date of the Department of Energy (DOE) and other agencies in implementing the programs required by the AMFA is reported. A detailed scenario of future alternative-fuel use that displaces 2.5 million barrels per day (MMBD) of petroleum and a feasible path of vehicle production and fuel supply leading to that goal is described. An analytical tool for exploring and quantifying the energy market impacts of alternative fuels, the Alternative Fuels Trade Model (AFTM), is described. The AFTM provides a means of investigating the impacts of alternative fuels in interrelated world energy markets for petroleum and natural gas. Several major initiatives have recently been enacted that have important ramifications for alternative-fuels policy. The Clean Air Act Amendments of 1990 contain provisions mandating the use of nonpetroleum oxygenates in reformulated gasoline. Other provisions for much more stringent emissions standards may affect the ability of manufacturers to make and sell conventional-fuel vehicles or, at the very least, affect their cost-effectiveness in comparison to cleaner alternative-fuel vehicles (AFV's). Finally, the key areas in which technological advances could substantially improve the competitiveness of AFV technologies in the marketplace are reviewed

  9. 40 CFR 80.595 - How does a small or GPA refiner apply for a motor vehicle diesel fuel volume baseline for the...

    Science.gov (United States)

    2010-07-01

    ... for a motor vehicle diesel fuel volume baseline for the purpose of extending their gasoline sulfur... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... a small or GPA refiner apply for a motor vehicle diesel fuel volume baseline for the purpose of...

  10. Fluid flow and fuel-air mixing in a motored two-dimensional Wankel rotary engine

    Science.gov (United States)

    Shih, T. I.-P.; Nguyen, H. L.; Stegeman, J.

    1986-01-01

    The implicit-factored method of Beam and Warming was employed to obtain numerical solutions to the conservation equations of mass, species, momentum, and energy to study the unsteady, multidimensional flow and mixing of fuel and air inside the combustion chambers of a two-dimensional Wankel rotary engine under motored conditions. The effects of the following engine design and operating parameters on fluid flow and fuel-air mixing during the intake and compression cycles were studied: engine speed, angle of gaseous fuel injection during compression cycle, and speed of the fuel leaving fuel injector.

  11. The simple economics of motor vehicle pollution: A case for fuel tax

    International Nuclear Information System (INIS)

    Montag, Josef

    2015-01-01

    The volume of pollution produced by an automobile is determined by driver's behavior along three margins: (i) vehicle selection, (ii) kilometers driven, and (iii) on-road fuel economy. The first two margins have been studied extensively, however the third has received scant attention. How significant is this ‘intensive margin’? What would be the optimal policies when it is taken into account? The paper develops and analyzes a simple model of the technical and behavioral mechanisms that determine the volume emissions produced by a car. The results show that an optimal fuel tax would provide drivers with appropriate incentives along all three margins and that only public information is needed for a fuel tax to be set optimally. In contrast, an optimal distance tax would require private information. Lastly, relative to the optimal fuel tax, a simple uniform fuel tax is shown to be progressive. Thus, being already deployed worldwide, a uniform fuel tax is an attractive second-best policy. These findings should be accounted for when designing new mechanisms to alleviate motor vehicle pollution. -- Highlights: •The paper analyzes motor vehicle pollution and optimal policy responses. •The intensive margin of vehicle use (on-road fuel consumption) is modeled explicitly. •An optimal fuel tax requires only public information, unlike an optimal distance tax. •Fuel taxes should remain the core instrument for car pollution control. •Other policies, such as a car tax, may complement fuel taxes but are not substitutes

  12. Development and Characterization of Fast Burning Solid Fuels/Propellants for Hybrid Rocket Motors with High Volumetric Efficiency

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of this proposed work is to develop several fast burning solid fuels/fuel-rich solid propellants for hybrid rocket motor applications. In the...

  13. Fifth annual report to congress. Federal alternative motor fuels programs

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-01

    This report presents the status of the US Department of Energy`s alternative fuel vehicle demonstration and performance tracking programs being conducted in accordance with the Energy Policy and Conservation Act. These programs comprise the most comprehensive data collection effort ever undertaken on alternative transportation fuels and alternative fuel vehicles. The report summarizes tests and results from the fifth year. Electric vehicles are not included in these programs, and the annual report does not include information on them. Since the inception of the programs, great strides have been made in developing commercially viable alternative fuel vehicle technologies. However, as is the case in the commercialization of all new technologies, some performance problems have been experienced on vehicles involved in early demonstration efforts. Substantial improvements have been recorded in vehicle practicality, safety, and performance in real-world demonstrations. An aspect of particular interest is emissions output. Results from light duty alternative fuel vehicles have demonstrated superior inservice emissions performance. Heavy duty alternative fuel vehicles have demonstrated dramatic reductions in particulate emissions. However, emissions results from vehicles converted to run on alternative fuel have not been as promising. Although the technologies available today are commercially viable in some markets, further improvements in infrastructure and economics will result in greater market expansion. Information is included in this report on light and heavy duty vehicles, transit buses, vehicle conversions, safety, infrastructure support, vehicle availability, and information dissemination.

  14. Toxicological and performance aspects of oxygenated motor vehicle fuels

    National Research Council Canada - National Science Library

    National Research Council Staff; Commission on Life Sciences; Division on Earth and Life Studies; National Research Council; National Academy of Sciences

    .... Other questions have been raised about reduced fuel economy and engine performance and pollution of ground water due to the use of MTBE in gasoline. The book provides conclusions and recommendations about each major topic addressed in the government's report.

  15. New technologies in the production of motor fuels from renewable materials

    Directory of Open Access Journals (Sweden)

    Adnađević Borivoj K.

    2012-01-01

    Full Text Available This work presents resources of the Autonomous Province of Vojvodina available for bioethanol and motor fuels (gasoline and diesel fuel from sustainable resources: corn-stalks, straw, sweet sorghum, pork fat. The physicochemical basis for novel processes for motor fuel production is coupling microwave pyrolysis of oil shale and catalytic cracking of purified pyrolysis oil, hydrothermal liquefaction of algae and swine manure. The effects of the degree of purification of crude pyrolysis oil and oil shale on the degree of their conversion to gasoline and diesel fuel, as well as the product distribution are investigated. The effects of the duration and temperature of hydrothermal liquefaction of microalga, Botryoccocus braunii, and swine manure on their degrees of conversion into bio-oil and its thermal properties are investigated. The development of novel strategy of biofuel in the Autonomous Province of Vojvodina is presented.

  16. 40 CFR 80.500 - What are the implementation dates for the motor vehicle diesel fuel sulfur control program?

    Science.gov (United States)

    2010-07-01

    ... Information § 80.500 What are the implementation dates for the motor vehicle diesel fuel sulfur control... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What are the implementation dates for the motor vehicle diesel fuel sulfur control program? 80.500 Section 80.500 Protection of Environment...

  17. 90-Day Inhalation Toxicity Study of Hydroprocessed Esters and Fatty Acids (HEFA) Bio-Based Jet Fuel in Rats (Rattus norvegicus) with Neurotoxicity Testing and Genotoxicity Assay

    Science.gov (United States)

    2013-06-01

    elevated frame to detect vertical rears, as well as differentiate small ( stereotypic ) movements from large movements. Motor activity was measured in a...Laboratory Animals V.3.3.1. Genus / Species Rattus norvegicus V.3.3.2. Strain / Stock 62 Distribution A: Approved for public release...horizontal movement and to differentiate small ( stereotypic ) movements from large movements, and a second frame was elevated above the ground level frame

  18. Bio-based production of fuels and industrial chemicals by repurposing antibiotic-producing type I modular polyketide synthases: opportunities and challenges

    DEFF Research Database (Denmark)

    Yuzawa, Satoshi; Keasling, Jay D.; Katz, Leonard

    2017-01-01

    Complex polyketides comprise a large number of natural products that have broad application in medicine and agriculture. They are produced in bacteria and fungi from large enzyme complexes named type I modular polyketide synthases (PKSs) that are composed of multifunctional polypeptides containin...... have applications as fuels or industrial chemicals....

  19. Fuel-Cell-Powered Electric Motor Drive Analyzed for a Large Airplane

    Science.gov (United States)

    Brown, Gerald V.; Choi, Benjamin B.

    2005-01-01

    Because of its high efficiency, fuel cell technology may be used to launch a new generation of more-electric aeropropulsion and power systems for future aircraft. Electric-motor-driven airplanes using fuel-cell powerplants would be beneficial to the environment because of fuel savings, low noise, and zero carbon-dioxide emissions. In spite of the fuel cell s efficiency benefit, to produce the same shaft drive power, a fuel cell- powered electric-drive system must be definitely heavier than a turbine-drive system. However, the fuel-cell system s overall efficiency from fuel-to-shaft power is higher than for a turbine-drive system. This means that the fuel consumption rate could be lower than for a conventional system. For heavier, fuel-laden planes for longer flights, we might achieve substantial fuel savings. In the airplane industry, in fact, an efficiency gain of even a few percentage points can make a major economic difference in operating costs.

  20. Natural gas -- introduction on the market as a motor fuel without tax reduction

    International Nuclear Information System (INIS)

    Seifert, M.; Weber, J.-C.

    2001-01-01

    This extensive article reviews the history of efforts being made to promote the use of gas as a motor fuel in Switzerland and the work done in various institutions in Europe and Switzerland on natural gas driven vehicles, from small cars up to full sized trucks and hybrid vehicles. The reduction of airborne pollution as a result of using natural gas is looked at and the certification of vehicles according to European and American standards is commented. The motor fuel taxing situation in Switzerland and various parliamentary initiatives calling for the reduction of taxes on more environmentally friendly fuels such as natural gas are discussed. The use of biogas as a tax-exempted motor fuel and the technology necessary for its refinement is examined and its potential assessed. Pilot and demonstration projects in the natural gas fuels area are described and the gas industry's activities in their promotion are discussed. The article is concluded by a look at today's fiscal and technical situation; future trends and developments on the market are also discussed

  1. Estimating Price Elasticity of Demand for Motor Fuel in the Transport Sectors

    Directory of Open Access Journals (Sweden)

    Olga Vasilyevna Mazurova

    2015-03-01

    Full Text Available Modeling of long-term forecasts of prices and demand on regional energy markets requires accounting for the future changes in the interactions between the greater economy and its energy sector, along with the possible emergence of new factors and specific regional features determining those interactions. The proposed approach allows the study of a correlation between demand and prices for motor fuel, taking into account the competition of energy carriers, the dynamics of energy prices, resource constraints, the use of new technologies and the uncertainty of input data. The main feature of the proposed approach is the combined estimation of the price elasticity of demand for motor fuel with optimization of fuel supply in the region. Thus the author determined elasticity of demand based on the comparison of economic efficiency of the use of different fuels. The study includes results of experimental calculations and forecasted price according to demand for motor fuel in freight transportation for the expected development conditions of the Far Eastern federal district

  2. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials, APPENDIX A: Energy Use and Emissions from the Lifecycle of Diesel-Like Fuels Derived From Biomass

    OpenAIRE

    Delucchi, Mark; Lipman, Timothy

    2003-01-01

    An Appendix to the Report, “A Lifecycle Emissions Model (LEM): Lifecycle Emissions From Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materialsâ€

  3. Biofuels policy and the US market for motor fuels: Empirical analysis of ethanol splashing

    Energy Technology Data Exchange (ETDEWEB)

    Walls, W.D., E-mail: wdwalls@ucalgary.ca [Department of Economics, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4 (Canada); Rusco, Frank; Kendix, Michael [US GAO (United States)

    2011-07-15

    Low ethanol prices relative to the price of gasoline blendstock, and tax credits, have resulted in discretionary blending at wholesale terminals of ethanol into fuel supplies above required levels-a practice known as ethanol splashing in industry parlance. No one knows precisely where or in what volume ethanol is being blended with gasoline and this has important implications for motor fuels markets: Because refiners cannot perfectly predict where ethanol will be blended with finished gasoline by wholesalers, they cannot know when to produce and where to ship a blendstock that when mixed with ethanol at 10% would create the most economically efficient finished motor gasoline that meets engine standards and has comparable evaporative emissions as conventional gasoline without ethanol blending. In contrast to previous empirical analyses of biofuels that have relied on highly aggregated data, our analysis is disaggregated to the level of individual wholesale fuel terminals or racks (of which there are about 350 in the US). We incorporate the price of ethanol as well as the blendstock price to model the wholesaler's decision of whether or not to blend additional ethanol into gasoline at any particular wholesale city-terminal. The empirical analysis illustrates how ethanol and gasoline prices affect ethanol usage, controlling for fuel specifications, blend attributes, and city-terminal-specific effects that, among other things, control for differential costs of delivering ethanol from bio-refinery to wholesale rack. - Research Highlights: > Low ethanol prices and tax credits have resulted in discretionary blending of ethanol into fuel supplies above required levels. > This has important implications for motor fuels markets and vehicular emissions. > Our analysis incorporates the price of ethanol as well as the blendstock price to model the wholesaler's decision of whether or not to blend additional ethanol into gasoline at any particular wholesale city

  4. Biofuels policy and the US market for motor fuels: Empirical analysis of ethanol splashing

    International Nuclear Information System (INIS)

    Walls, W.D.; Rusco, Frank; Kendix, Michael

    2011-01-01

    Low ethanol prices relative to the price of gasoline blendstock, and tax credits, have resulted in discretionary blending at wholesale terminals of ethanol into fuel supplies above required levels-a practice known as ethanol splashing in industry parlance. No one knows precisely where or in what volume ethanol is being blended with gasoline and this has important implications for motor fuels markets: Because refiners cannot perfectly predict where ethanol will be blended with finished gasoline by wholesalers, they cannot know when to produce and where to ship a blendstock that when mixed with ethanol at 10% would create the most economically efficient finished motor gasoline that meets engine standards and has comparable evaporative emissions as conventional gasoline without ethanol blending. In contrast to previous empirical analyses of biofuels that have relied on highly aggregated data, our analysis is disaggregated to the level of individual wholesale fuel terminals or racks (of which there are about 350 in the US). We incorporate the price of ethanol as well as the blendstock price to model the wholesaler's decision of whether or not to blend additional ethanol into gasoline at any particular wholesale city-terminal. The empirical analysis illustrates how ethanol and gasoline prices affect ethanol usage, controlling for fuel specifications, blend attributes, and city-terminal-specific effects that, among other things, control for differential costs of delivering ethanol from bio-refinery to wholesale rack. - Research highlights: → Low ethanol prices and tax credits have resulted in discretionary blending of ethanol into fuel supplies above required levels. → This has important implications for motor fuels markets and vehicular emissions. → Our analysis incorporates the price of ethanol as well as the blendstock price to model the wholesaler's decision of whether or not to blend additional ethanol into gasoline at any particular wholesale city-terminal.

  5. Bio-based production of fuels and industrial chemicals by repurposing antibiotic-producing type I modular polyketide synthases: opportunities and challenges.

    Science.gov (United States)

    Yuzawa, Satoshi; Keasling, Jay D; Katz, Leonard

    2017-04-01

    Complex polyketides comprise a large number of natural products that have broad application in medicine and agriculture. They are produced in bacteria and fungi from large enzyme complexes named type I modular polyketide synthases (PKSs) that are composed of multifunctional polypeptides containing discrete enzymatic domains organized into modules. The modular nature of PKSs has enabled a multitude of efforts to engineer the PKS genes to produce novel polyketides of predicted structure. We have repurposed PKSs to produce a number of short-chain mono- and di-carboxylic acids and ketones that could have applications as fuels or industrial chemicals.

  6. Bio-based production of fuels and industrial chemicals by repurposing antibiotic-producing type I modular polyketide synthases: opportunities and challenges

    Energy Technology Data Exchange (ETDEWEB)

    Yuzawa, Satoshi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Biological Systems and Engineering Division; Keasling, Jay D. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Biological Systems and Engineering Division; Univ. of California, Berkeley, CA (United States). QB3 Inst.; Joint BioEnergy Inst. (JBEI), Emeryville, CA (United States); Univ. of California, Berkeley, CA (United States). Dept. of Bioengineering; Univ. of California, Berkeley, CA (United States). Dept. of Chemical and Biomolecular Engineering; Technical Univ. of Denmark, Horsholm (Denmark). Novo Nordisk Foundation Center for Biosustainability; Katz, Leonard [Univ. of California, Berkeley, CA (United States). QB3 Inst.

    2016-11-16

    Complex polyketides comprise a large number of natural products that have broad application in medicine and agriculture. They are produced in bacteria and fungi from large enzyme complexes named type I modular polyketide synthases (PKSs) that are composed of multifunctional polypeptides containing discrete enzymatic domains organized into modules. The modular nature of PKSs has enabled a multitude of efforts to engineer the PKS genes to produce novel polyketides of predicted structure. Finally, we have repurposed PKSs to produce a number of short-chain mono- and di-carboxylic acids and ketones that could have applications as fuels or industrial chemicals.

  7. VOC composition of current motor vehicle fuels and vapors, and collinearity analyses for receptor modeling.

    Science.gov (United States)

    Chin, Jo-Yu; Batterman, Stuart A

    2012-03-01

    The formulation of motor vehicle fuels can alter the magnitude and composition of evaporative and exhaust emissions occurring throughout the fuel cycle. Information regarding the volatile organic compound (VOC) composition of motor fuels other than gasoline is scarce, especially for bioethanol and biodiesel blends. This study examines the liquid and vapor (headspace) composition of four contemporary and commercially available fuels: gasoline (gasoline), ultra-low sulfur diesel (ULSD), and B20 (20% soy-biodiesel and 80% ULSD). The composition of gasoline and E85 in both neat fuel and headspace vapor was dominated by aromatics and n-heptane. Despite its low gasoline content, E85 vapor contained higher concentrations of several VOCs than those in gasoline vapor, likely due to adjustments in its formulation. Temperature changes produced greater changes in the partial pressures of 17 VOCs in E85 than in gasoline, and large shifts in the VOC composition. B20 and ULSD were dominated by C(9) to C(16)n-alkanes and low levels of the aromatics, and the two fuels had similar headspace vapor composition and concentrations. While the headspace composition predicted using vapor-liquid equilibrium theory was closely correlated to measurements, E85 vapor concentrations were underpredicted. Based on variance decomposition analyses, gasoline and diesel fuels and their vapors VOC were distinct, but B20 and ULSD fuels and vapors were highly collinear. These results can be used to estimate fuel related emissions and exposures, particularly in receptor models that apportion emission sources, and the collinearity analysis suggests that gasoline- and diesel-related emissions can be distinguished. Copyright © 2011 Elsevier Ltd. All rights reserved.

  8. Processing biogas to obtain motor fuel - Operational experience

    International Nuclear Information System (INIS)

    Seifert, M.

    2008-01-01

    This article takes a look at how raw biogas can be processed in order to remove carbon dioxide and corrosive substances and thus bring it up to natural gas quality. The ecological advantages of using biogas as a fuel are discussed and the situation in Europe and Switzerland is examined. Also, feeding biogas into the normal natural gas mains is discussed and the technologies necessary for the cleaning and preparation of the biogas are described. These include absorption and adsorption processes as well as membrane systems that are used to remove excessive carbon dioxide. The costs involved are discussed on the basis of experience gained in Sweden and Switzerland. Finally, the environmental aspects of methane losses are discussed.

  9. Impact of methanol and CNG fuels on motor-vehicle toxic emissions

    International Nuclear Information System (INIS)

    Black, F.; Gabele, P.

    1991-01-01

    The 1990 Clean Air Act Amendments require that the Environmental Protection Agency investigate the need for reduction of motor vehicle toxic emissions such as formaldehyde, acetaldehyde, benzene, 1,3-butadiene, and polycyclic organic matter. Toxic organic emissions can be reduced by utilizing the control technologies employed for regulated THC (NMHC) and CO emissions, and by changing fuel composition. The paper examines emissions associated with the use of methanol and compressed natural gas fuels. Both tailpipe and evaporative emissions are examined at varied ambient temperatures ranging from 20 C to 105 F. Tailpipe emissions are also examined over a variety of driving cycles with average speeds ranging from 7 to 48 mph. Results suggest that an equivalent ambient temperatures and average speeds, motor vehicle toxic emissions are generally reduced with methanol and compressed natural gas fuels relative to those with gasoline, except for formaldehyde emissions, which may be elevated. As with gasoline, tailpipe toxic emissions with methanol and compressed natural gas fuels generally increase when ambient temperature or average speed decreases (the sensitivity to these variables is greater with methanol than with compressed natural gas). Evaporative emissions generally increase when fuel volatility or ambient temperature increases (however, the relative contribution of evaporative sources to the aggregate toxic compound emissions is small)

  10. A fuel-based approach to estimating motor vehicle exhaust emissions

    Science.gov (United States)

    Singer, Brett Craig

    Motor vehicles contribute significantly to air pollution problems; accurate motor vehicle emission inventories are therefore essential to air quality planning. Current travel-based inventory models use emission factors measured from potentially biased vehicle samples and predict fleet-average emissions which are often inconsistent with on-road measurements. This thesis presents a fuel-based inventory approach which uses emission factors derived from remote sensing or tunnel-based measurements of on-road vehicles. Vehicle activity is quantified by statewide monthly fuel sales data resolved to the air basin level. Development of the fuel-based approach includes (1) a method for estimating cold start emission factors, (2) an analysis showing that fuel-normalized emission factors are consistent over a range of positive vehicle loads and that most fuel use occurs during loaded-mode driving, (3) scaling factors relating infrared hydrocarbon measurements to total exhaust volatile organic compound (VOC) concentrations, and (4) an analysis showing that economic factors should be considered when selecting on-road sampling sites. The fuel-based approach was applied to estimate carbon monoxide (CO) emissions from warmed-up vehicles in the Los Angeles area in 1991, and CO and VOC exhaust emissions for Los Angeles in 1997. The fuel-based CO estimate for 1991 was higher by a factor of 2.3 +/- 0.5 than emissions predicted by California's MVEI 7F model. Fuel-based inventory estimates for 1997 were higher than those of California's updated MVEI 7G model by factors of 2.4 +/- 0.2 for CO and 3.5 +/- 0.6 for VOC. Fuel-based estimates indicate a 20% decrease in the mass of CO emitted, despite an 8% increase in fuel use between 1991 and 1997; official inventory models predict a 50% decrease in CO mass emissions during the same period. Cold start CO and VOC emission factors derived from parking garage measurements were lower than those predicted by the MVEI 7G model. Current inventories

  11. Study of brushless fuel pump (improvement of pump and motor parts). 2nd Report. Blushless dendo fuel pump no kento. 2

    Energy Technology Data Exchange (ETDEWEB)

    Mine, K; Takada, S; Tatematsu, M; Takeuchi, H [Aisan Industry Co. Ltd., Aichi (Japan)

    1992-10-01

    A methanol use electrically driven fuel pump was developed as reported in the present report. Mixed fuel of gasoline with alcohol can be handled by a brushless fuel pump which was proposed and improved as reported. The flow rate performance was heightened to 25g/sec by heightening in output power of motor, while the high temperature performance was 17% heightened against the conventional ratio of lowering in flow rate by heightening in vapor jet capacity. Against the corrosiveness of methanol, an in-tank type was applied to the pump, and all its electrically conductive and other mechanical parts were made to be both anti-corrosive and anti-abrasive. It is structurally of a two-stage series turbine type of non-volume form. A sensor method was applied to the motor by confining the miniaturized control circuit of brushless motor in the motor so that the transistor is controlled against the heightening in temperature. The motor is a three-phase half-wave driving motor. Also developed was a fuel supply system which is useful for the mixed fuel covering a range of 100% methanol through 100% gasoline. The present pump is dimensionally interchangeable with the conventional gasoline use one. Its operational life is more than 10000 hours. 3 refs., 17 figs., 1 tab.

  12. Towards a carbon-negative sustainable bio-based economy.

    Science.gov (United States)

    Vanholme, Bartel; Desmet, Tom; Ronsse, Frederik; Rabaey, Korneel; Van Breusegem, Frank; De Mey, Marjan; Soetaert, Wim; Boerjan, Wout

    2013-01-01

    The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy toward sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green) and industrial (white) biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy.

  13. Towards a carbon-negative sustainable bio-based economy

    Directory of Open Access Journals (Sweden)

    Bartel eVanholme

    2013-06-01

    Full Text Available The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy towards sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green and industrial (white biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy.

  14. Towards a carbon-negative sustainable bio-based economy

    Science.gov (United States)

    Vanholme, Bartel; Desmet, Tom; Ronsse, Frederik; Rabaey, Korneel; Breusegem, Frank Van; Mey, Marjan De; Soetaert, Wim; Boerjan, Wout

    2013-01-01

    The bio-based economy relies on sustainable, plant-derived resources for fuels, chemicals, materials, food and feed rather than on the evanescent usage of fossil resources. The cornerstone of this economy is the biorefinery, in which renewable resources are intelligently converted to a plethora of products, maximizing the valorization of the feedstocks. Innovation is a prerequisite to move a fossil-based economy toward sustainable alternatives, and the viability of the bio-based economy depends on the integration between plant (green) and industrial (white) biotechnology. Green biotechnology deals with primary production through the improvement of biomass crops, while white biotechnology deals with the conversion of biomass into products and energy. Waste streams are minimized during these processes or partly converted to biogas, which can be used to power the processing pipeline. The sustainability of this economy is guaranteed by a third technology pillar that uses thermochemical conversion to valorize waste streams and fix residual carbon as biochar in the soil, hence creating a carbon-negative cycle. These three different multidisciplinary pillars interact through the value chain of the bio-based economy. PMID:23761802

  15. North America markets for alcohol and alcohol-derived motor fuels and need for tax incentives

    International Nuclear Information System (INIS)

    Haigwood, B.

    1991-01-01

    The U.S. fuel alcohol and ether industry has grown from its infancy in 1979 to approximately 2.9 billion gallons of production capacity in 1991. With the emphasis on clean air, the uncertainties in the Middle East, and fluctuating oil prices, IRI believes the demand for alcohol-derived motor fuels is poised to begin a second phase of expansion. Historically, the two primary alcohol-derived motor fuels sold in the U.S. have been methyl tertiary butyl ether (MTBE) and ethanol. There is also a limited but growing use of methanol as 85% blendstock for gasoline. Since 1978, fuel ethanol has provided the U.S. petroleum industry with an additional source of supply, octane, and profit. Its price was based on the price of wholesale gasoline plus available federal and state tax incentives. These incentives allowed ethanol, with production costs of $1.00 to $1.25 per gallon, to compete with gasoline at prices of 40 to 65 per gallon. Without the federal and state tax incentives, it would not be economically feasible to sell or manufacture fuel ethanol. On the other hand, the largest consumption of methanol has been as a feedstock for the production of MTBE, the world's fastest growing chemical over the past seven years. MTBE prices are based on the cost of raising the octane level of gasoline, and this commodity does not receive subsidies. Beginning in 1992, IRI predicts the price relationship between ethanol, MTBE, and gasoline will change as U.S. refiners and marketers are required to include oxygenated fuels (alcohol-derived) in their gasoline. In total, over 60 billion gallons of gasoline will need to be reformulated by the year 2000. The increased demand for oxygen will result in a 2.5-billion gallon deficit of MTBE and 1.2-billion gallon deficit of ethanol by the year 2000. 2 tabs

  16. Numerical investigation on the regression rate of hybrid rocket motor with star swirl fuel grain

    Science.gov (United States)

    Zhang, Shuai; Hu, Fan; Zhang, Weihua

    2016-10-01

    Although hybrid rocket motor is prospected to have distinct advantages over liquid and solid rocket motor, low regression rate and insufficient efficiency are two major disadvantages which have prevented it from being commercially viable. In recent years, complex fuel grain configurations are attractive in overcoming the disadvantages with the help of Rapid Prototyping technology. In this work, an attempt has been made to numerically investigate the flow field characteristics and local regression rate distribution inside the hybrid rocket motor with complex star swirl grain. A propellant combination with GOX and HTPB has been chosen. The numerical model is established based on the three dimensional Navier-Stokes equations with turbulence, combustion, and coupled gas/solid phase formulations. The calculated fuel regression rate is compared with the experimental data to validate the accuracy of numerical model. The results indicate that, comparing the star swirl grain with the tube grain under the conditions of the same port area and the same grain length, the burning surface area rises about 200%, the spatially averaged regression rate rises as high as about 60%, and the oxidizer can combust sufficiently due to the big vortex around the axis in the aft-mixing chamber. The combustion efficiency of star swirl grain is better and more stable than that of tube grain.

  17. Ethanol as a fuel for road transportation. Main report; Contribution to IEA Implementing Agreement on Advanced Motor Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, Ulrik; Johansen, T.; Schramm, J.

    2009-05-15

    Bioethanol as a motor fuel in the transportation sector, mainly for road transportation, has been subject to many studies and much discussion. Furthermore, the topic involves not only the application and engine technical aspects, but also the understanding of the entire life cycle of the fuel, well-to-wheels, including economical, environmental, and social aspects. It is not, however, the aim of this report to assess every single one of these aspects. The present report aims to address the technical potential and problems as well as the central issues related to the general application of bioethanol as an energy carrier in the near future. In discussions of the advantages and drawbacks of ethanol, the type of application is important. Generalization is not possible, because ethanol can be used in many forms. Furthermore, a wide range of ethanol/gasoline blends has not yet been investigated sufficiently. The most favorable type of application is determined by infrastructural factors, especially vehicle fleet configuration. From a technical point of view, optimal usage involves a high degree of water content in the ethanol, and this excludes low-percentage-ethanol fuels. The benefits seem strongly related to the amount of ethanol in a given blend, that is, the more the better. Both engine efficiencies and emissions improve with more ethanol in the fuel. Wet ethanol constitutes an even cleaner fuel in both the production and application phases. In summary, ethanol application has many possibilities, but with each type of application comes a set of challenges. Nevertheless, technical solutions for each challenge are available. (ln)

  18. [Preface for special issue on bio-based materials (2016)].

    Science.gov (United States)

    Weng, Yunxuan

    2016-06-25

    Bio-based materials are new materials or chemicals with renewable biomass as raw materials such as grain, legume, straw, bamboo and wood powder. This class of materials includes bio-based polymer, biobased fiber, glycotechnology products, biobased rubber and plastics produced by biomass thermoplastic processing and basic biobased chemicals, for instance, bio-alcohols, organic acids, alkanes, and alkenes, obtained by bio-synthesis, bio-processing and bio-refinery. Owing to its environmental friendly and resource conservation, bio-based materials are becoming a new dominant industry taking the lead in the world scientific and technological innovation and economic development. An overview of bio-based materials development is reported in this special issue, and the industrial status and research progress of the following aspects, including biobased fiber, polyhydroxyalkanoates, biodegradable mulching film, bio-based polyamide, protein based biomedical materials, bio-based polyurethane, and modification and processing of poly(lactic acid), are introduced.

  19. [Current status of bio-based materials industry in China].

    Science.gov (United States)

    Diao, Xiaoqian; Weng, Yunxuan; Huang, Zhigang; Yang, Nan; Wang, Xiyuan; Zhang, Min; Jin, Yujuan

    2016-06-25

    In recent years, bio-based materials are becoming a new dominant industry leading the scientific and technological innovation, and economic development of the world. We reviewed the new development of bio-based materials industry in China, analyzed the entire market of bio-based materials products comprehensively, and also stated the industry status of bio-based chemicals, such as lactic acid, 1,3-propanediol, and succinic acid; biodegradable bio-based polymers, such as co-polyester of diacid and diol, polylactic acid, carbon dioxide based copolymer, polyhydroxyalknoates, polycaprolactone, and thermoplastic bio-based plastics; non-biodegradable bio-based polymers, such as bio-based polyamide, polytrimethylene terephthalate, bio-based polyurethane, and bio-based fibers.

  20. Latent Heat Characteristics of Biobased Oleochemical Carbonates as Novel Phase Change Materials

    Science.gov (United States)

    Oleochemical carbonates are biobased materials that were readily prepared through a carbonate interchange reaction between renewable C10-C18 fatty alcohols and dimethyl or diethyl carbonate in the presence of a catalyst. These carbonates have various commercial uses in cosmetic, fuel additive and l...

  1. Induced motor vehicle travel from improved fuel efficiency and road expansion

    Energy Technology Data Exchange (ETDEWEB)

    Su Qing, E-mail: suq1@nku.edu [Department of Marketing, Economics and Sports Business, Northern Kentucky University, AST Center, Office 338, Nunn Drive, Highland Heights, KY 41099 (United States)

    2011-11-15

    This paper investigates the impact of improved fuel efficiency and road network expansion on motor vehicle travel using a system dynamic panel data estimator and panel data at the state level for the 2001-2008 period. Our model accounts for endogenous changes in fuel efficiency, congestion, fuel cost per mile, and vehicle stock. Our regression results suggest that the short run rebound effect is 0.0276 while the long run rebound effect is 0.11. The short run effect of road capacity per capita is 0.066 while the long run effect is 0.26. - Highlights: > We estimate two effects: the rebound effect and induced travel effect at the state level. > System dynamic panel data approach is used to address endogeneity issue. > In the period of 2001-2008, the rebound effect is 0.0276 in the short run and 0.11 in the long run. > Increase in road capacity induces motor vehicle travel. > Induced travel effect is 0. 0.066 in the short run and 0.26 in the long run.

  2. Induced motor vehicle travel from improved fuel efficiency and road expansion

    International Nuclear Information System (INIS)

    Su Qing

    2011-01-01

    This paper investigates the impact of improved fuel efficiency and road network expansion on motor vehicle travel using a system dynamic panel data estimator and panel data at the state level for the 2001-2008 period. Our model accounts for endogenous changes in fuel efficiency, congestion, fuel cost per mile, and vehicle stock. Our regression results suggest that the short run rebound effect is 0.0276 while the long run rebound effect is 0.11. The short run effect of road capacity per capita is 0.066 while the long run effect is 0.26. - Highlights: → We estimate two effects: the rebound effect and induced travel effect at the state level. → System dynamic panel data approach is used to address endogeneity issue. → In the period of 2001-2008, the rebound effect is 0.0276 in the short run and 0.11 in the long run. → Increase in road capacity induces motor vehicle travel. → Induced travel effect is 0. 0.066 in the short run and 0.26 in the long run.

  3. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    Science.gov (United States)

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  4. Biobased chemicals: the convergence of green chemistry with industrial biotechnology.

    Science.gov (United States)

    Philp, Jim C; Ritchie, Rachael J; Allan, Jacqueline E M

    2013-04-01

    Policy issues around biobased chemicals are similar to those for biobased plastics. However, there are significant differences that arise from differences in production volumes and the more specific applications of most chemicals. The drivers for biobased chemicals production are similar to those for biobased plastics, particularly the environmental drivers. However, in Europe, biobased chemical production is further driven by the need to improve the competitiveness of the chemicals industry. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Motor fuels

    Energy Technology Data Exchange (ETDEWEB)

    1937-09-14

    The abstract describes a process for obtaining a maximum quantity of commercial gasoline from a composite hydrocarbon stream containing hydrocarbons within and below the gasoline boiling range including gaseous olefins. The hydrocarbon stream is separated into low vapor pressure gasoline and a gas fraction consisting of the 4 carbon atom group and possibly some of the 3 carbon atom group. The fraction is subjected to a polymerization process utilizing the products of the operation, both liquid polymers and unconverted gases to increase the yield of the gasoline and to adjust the low vapor pressure of the gasoline to the equivalent of that of commercial gasoline. A small fraction of the gaseous products are used for this purpose. The remainder are recycled through the polymerization operation.

  6. Biomass based energy combines with motor fuel production; Biobraenslebaserade energikombinat med tillverkning av drivmedel

    Energy Technology Data Exchange (ETDEWEB)

    Goldschmidt, Barbara

    2005-01-01

    In the report the state of development of production processes for various motor fuels, such as FT diesel, methanol , DME and ethanol, from biomass is reviewed. Biomass and black liquor gasification processes as well as processes for ethanol production from lignocellulosic biomass are discussed. The processes are complicated and still not very well tried in their whole context. The gas cleaning steps, which are necessary to reach acceptable catalyst lifetimes in the motor fuel production processes based on gasification, have been tested in the oil industry and to some extent in coal gasification plants, but not with syngas from biomass or black liquor gasification. For black liquor gasification particularly, also material selection and material lifetime issues remain to be solved. For ethanol production from lignocellulosic biomass process development is needed, to increase the yield in the pre-treatment, hydrolysis and fermentation steps. The energy yields of the processes are dependent on the degree of complexity of the processes, as well as on the integration and balancing of energy demanding steps and steps with energy surplus. This is especially valid for the processes based on gasification, due to high temperatures in the gasifier and some of the catalytic steps, but also for the ethanol process, which benefit from optimal steam integration in the evaporation and distillation steps. Also steam integration with cogeneration plants, or for black liquor gasification with pulp mills, improves the overall energy balance. In addition, the energy yield when motor fuels are produced by gasification is dependent on the usage of the off-gas. The efficiency is improved when the off-gas is burned in a boiler or gas turbine, than when it is flared. In the report examples are given of processes with and without integration.

  7. More chemistry between green and growth. The opportunities and dilemmas of a bio-based economy

    International Nuclear Information System (INIS)

    2010-12-01

    A bio-based economy is one in which enterprises manufacture non-food products from biomass. Such products include fuel for the transport industry, chemicals, materials, and energy. Biomass is the biological material of living or recently living organisms, either animal or vegetable. With technology becoming more sophisticated, it is growing easier to turn plants, trees, crops, and residual animal waste into biomass. Waste and waste streams are increasingly being used as input in production processes, thereby gaining an economic value of their own. They are giving rise to new, sustainable products with considerable added value that replace products based on non-renewable materials. New bio-based products may offer the Netherlands new economic opportunities. The Dutch can already boast a number of distinct advantages in that respect, thanks to the sophistication of their industrial sector, agro-industry, chemicals and energy industries, and transport and logistics sector - all key sectors in a bio-based economy. However, the growing world population and increasing level of prosperity worldwide, and the environmental and climate problems associated with such growth, are adding to the complexity of policy-making aimed at developing a bio-based economy. The shift from fossil-based to bio-based materials must be part of a comprehensive policy aimed at achieving a sustainable economy. [nl

  8. Azolla domestication towards a biobased economy?

    Science.gov (United States)

    Brouwer, Paul; Bräutigam, Andrea; Külahoglu, Canan; Tazelaar, Anne O E; Kurz, Samantha; Nierop, Klaas G J; van der Werf, Adrie; Weber, Andreas P M; Schluepmann, Henriette

    2014-05-01

    Due to its phenomenal growth requiring neither nitrogen fertilizer nor arable land and its biomass composition, the mosquito fern Azolla is a candidate crop to yield food, fuels and chemicals sustainably. To advance Azolla domestication, we research its dissemination, storage and transcriptome. Methods for dissemination, cross-fertilization and cryopreservation of the symbiosis Azolla filiculoides-Nostoc azollae are tested based on the fern spores. To study molecular processes in Azolla including spore induction, a database of 37 649 unigenes from RNAseq of microsporocarps, megasporocarps and sporophytes was assembled, then validated. Spores obtained year-round germinated in vitro within 26 d. In vitro fertilization rates reached 25%. Cryopreservation permitted storage for at least 7 months. The unigene database entirely covered central metabolism and to a large degree covered cellular processes and regulatory networks. Analysis of genes engaged in transition to sexual reproduction revealed a FLOWERING LOCUS T-like protein in ferns with special features induced in sporulating Azolla fronds. Although domestication of a fern-cyanobacteria symbiosis may seem a daunting task, we conclude that the time is ripe and that results generated will serve to more widely access biochemicals in fern biomass for a biobased economy. No claim to original European Union works. New Phytologist © 2014 New Phytologist Trust.

  9. The technologies for heavy vehicles motors and their fuels; Les technologies des moteurs de vehicules lourds et leurs carburants

    Energy Technology Data Exchange (ETDEWEB)

    Plassat, G

    2005-07-01

    The heavy vehicles are those the total weight (charged) is more than 3,5 tons. This document provides a comparative and parametric analysis of the main technologies developed for the future buses. A detailed presentation is done for each technique, as the operating principles and the advantages and disadvantages facing the today solution. More particularly the author presents the evolution of the diesel-fuel motor, the motor optimization for specific fuel as the natural gas and the liquefied petroleum gas, the hybrid thermal-electric motor, the hydrogen fuel cells, the biofuels and the de-pollution systems to eliminate the NO{sub X} and the particles. (A.L.B.)

  10. Power technology complex for production of motor fuel from brown coals with power supply from NPPs

    International Nuclear Information System (INIS)

    Troyanov, M.F.; Poplavskij, V.M.; Sidorov, G.I.; Bondarenko, A.V.; Chebeskov, A.N.; Chushkin, V.N.; Karabash, A.A.; Krichko, A.A.; Maloletnev, A.S.

    1998-01-01

    With the present-day challenge of efficient use of low-grade coals and current restructuring of coal industry in the Russian Federation, it is urgent to organise the motor fuel production by the synthesis from low grade coals and heavy petroleum residues. With this objective in view, the Institute of Physics and Power Engineering of RF Minatom and Combustible Resources Institute of RF Mintopenergo proposed a project of a standard nuclear power technology complex for synthetic liquid fuel (SLF) production using fast neutron reactors for power supply. The proposed project has two main objectives: (1) Engineering and economical optimization of the nuclear power supply for SLF production; and (2) Engineering and economical optimization of the SLF production by hydrogenisation of brown coals and heavy petroleum residues with a complex development of advanced coal chemistry. As a first approach, a scheme is proposed with the use of existing reactor cooling equipment, in particular, steam generators of BN-600, limiting the effect on safety of reactor facility operation at minimum in case of deviations and abnormalities in the operation of technological complex. The possibility to exclude additional requirements to the equipment for nuclear facility cooling was also taken into account. It was proposed to use an intermediate steam-water circuit between the secondary circuit sodium and the coolant to heat the technological equipment. The only change required for the BN-600 equipment will be the replacement of sections of intermediate steam superheaters at the section of main steam superheaters. The economic aspects of synthetic motor fuel production proposed by the joint project depend on the evaluation of integral balances: thermal power engineering, chemical technology, the development of advanced large scale coal chemistry of high profitability; utilisation of ash and precious microelements in waste-free technology; production of valuable isotopes; radical solution of

  11. More chemistry between green and growth. The opportunities and dilemmas of a bio-based economy; Meer chemie tussen groen en groei. De kansen en dilemma's van een biobased economy

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-12-15

    A bio-based economy is one in which enterprises manufacture non-food products from biomass. Such products include fuel for the transport industry, chemicals, materials, and energy. Biomass is the biological material of living or recently living organisms, either animal or vegetable. With technology becoming more sophisticated, it is growing easier to turn plants, trees, crops, and residual animal waste into biomass. Waste and waste streams are increasingly being used as input in production processes, thereby gaining an economic value of their own. They are giving rise to new, sustainable products with considerable added value that replace products based on non-renewable materials. New bio-based products may offer the Netherlands new economic opportunities. The Dutch can already boast a number of distinct advantages in that respect, thanks to the sophistication of their industrial sector, agro-industry, chemicals and energy industries, and transport and logistics sector - all key sectors in a bio-based economy. However, the growing world population and increasing level of prosperity worldwide, and the environmental and climate problems associated with such growth, are adding to the complexity of policy-making aimed at developing a bio-based economy. The shift from fossil-based to bio-based materials must be part of a comprehensive policy aimed at achieving a sustainable economy. [Dutch] In dit advies gaat de SER in op mogelijkheden en knelpunten van de biobased economy. In een biobased economy dienen plantaardige en dierlijke biomassa (zoals gewassen, planten, snijafval, mest) als groene grondstoffen om non-food producten mee te maken (denk aan cosmetica, bioplastics, brandstoffen). De SER vindt dat de rijksoverheid stevig moet inzetten op een biobased economy met meer gesloten kringlopen. Dit draagt immers bij aan economische groei en aan een meer duurzame economie (gesloten kringlopen, gunstige arbeidsomstandigheden)

  12. Transformation of a car diesel engine with direct injection and common rail into a dual fuel engine; Trasformazione di un motore automobilistico diesel ad iniezione diretta dotato di common rail in un motore dual fuel

    Energy Technology Data Exchange (ETDEWEB)

    De Risi, A.; Laforgia, D. [Lecce Univ. (Italy). Dipt. di Scienza dei Materiali

    1999-08-01

    The reduced polluting emissions make natural gas a quite interesting alternative fuel for automotive applications. Therefore a car diesel engine has been transformed into a dual fuel engine with pilot injection via the common rail injection system used to ignite the methane-air charge. Standard injection pumps show a certain instability at low flow rates and high engine speed. On the opposite the new common rail system allows to ignite the fuel in all conditions with an amount of gas oil less than 8% of the entire energy required by the engine was enough to ignite the fuel. Furthermore, a power increase has been obtained, with an overall efficiency equal to or even higher than a conventional engine. The article deals with a series of test carried out on 1929 cm{sup 3} direct injection turbo-charged engine and presents the preliminary results. [Italian] La riduzione delle emissioni inquinanti rende il metano un combustibile alternativo piuttosto interessante per applicazioni automobilistiche. Per quasta ragione e' stata realizzata la trasformazione di un motore automobilitico diesel ad iniezione diretta in un motore dual fuel con iniezione pilota prodotta da un sistema common rail. L'adozione del sistema common rail consente l'accensione in ogni condizione con una quantita' di combustibile inferiore all'8% dell'intera energia richiesta alla potenza nominale del motore risolvendo i problemi di instabilita' che una pompa normale presenta a basse portate e ad alta velocita'. In alcuni casi e' stato sufficiente il 3% dell'energia totale richiesta dal motore per accendere la carica. Inoltre si e' ottenuto un aumento della potenza con un'efficienza globale analoga a qualla del motore tradizionale o addirittura migliore. Si riportano i risultati di una campagna di prove condotta su un motore sovralimentato ad iniezione diretta (1929 cm{sup 3}).

  13. Feasibility study of palm-based fuels for hybrid rocket motor applications

    Science.gov (United States)

    Tarmizi Ahmad, M.; Abidin, Razali; Taha, A. Latif; Anudip, Amzaryi

    2018-02-01

    This paper describes the combined analysis done in pure palm-based wax that can be used as solid fuel in a hybrid rocket engine. The measurement of pure palm wax calorific value was performed using a bomb calorimeter. An experimental rocket engine and static test stand facility were established. After initial measurement and calibration, repeated procedures were performed. Instrumentation supplies carried out allow fuel regression rate measurements, oxidizer mass flow rates and stearic acid rocket motors measurements. Similar tests are also carried out with stearate acid (from palm oil by-products) dissolved with nitrocellulose and bee solution. Calculated data and experiments show that rates and regression thrust can be achieved even in pure-tested palm-based wax. Additionally, palm-based wax is mixed with beeswax characterized by higher nominal melting temperatures to increase moisturizing points to higher temperatures without affecting regression rate values. Calorie measurements and ballistic experiments were performed on this new fuel formulation. This new formulation promises driving applications in a wide range of temperatures.

  14. 48 CFR 52.223-1 - Biobased Product Certification.

    Science.gov (United States)

    2010-10-01

    ....223-1 Biobased Product Certification. As prescribed in 23.406(a), insert the following provision: Biobased Product Certification (DEC 2007) As required by the Farm Security and Rural Investment Act of 2002... 48 Federal Acquisition Regulations System 2 2010-10-01 2010-10-01 false Biobased Product...

  15. Life cycle impact assssment of biobased plastics from sugarcane ethanol

    NARCIS (Netherlands)

    Tsiropoulos, Ioannis; Faaij, André; Lundquist, Lars; Schenker, Urs; Biois, J.F.; Patel, M.K.

    The increasing production of bio-based plastics calls for thorough environmental assessments. Using life cycle assessment, this study compares European supply of fully bio-based high-density polyethylene and partially bio-based polyethylene terephthalate from Brazilian and Indian sugarcane ethanol

  16. Challenges for bio-based products in sustainable value chains

    NARCIS (Netherlands)

    Cardon, L.; Lin, J.W.; De Groote, M.; Ragaert, K.; Kopecka, J.A.; Koster, R.P.

    2011-01-01

    This work concerns studies related to strategic development of products in which bio-based plastics are or will be applied, referred to as bio-based products. The studies cover (1) current and potential benefits of bio-based products in extended value chains including activities after end-of-life of

  17. Sustainable bio-based materials: opportunities and challenges

    NARCIS (Netherlands)

    van der Meer, Yvonne

    2017-01-01

    Research in the area of bio-based materials aims to achieve breakthroughs in bio-based materials development. A novel way is presented to organise bio-based materials research with a value chain approach in which sustainability research is integrated in the research program. This research approach

  18. Bio-based liquid crystalline polyesters

    Science.gov (United States)

    Wilsens, Carolus; Rastogi, Sanjay; Dutch Collaboration

    2013-03-01

    The reported thin-film polymerization has been used as a screening method in order to find bio-based liquid crystalline polyesters with convenient melting temperatures for melt-processing purposes. An in depth study of the structural, morphological and chemical changes occurring during the ongoing polycondensation reactions of these polymers have been performed. Structural and conformational changes during polymerization for different compositions have been followed by time resolved X-ray and Infrared spectroscopy. In this study, bio-based monomers such as vanillic acid and 2,5-furandicarboxylic acid are successfully incorporated in liquid crystalline polyesters and it is shown that bio-based liquid crystalline polymers with high aromatic content and convenient processing temperatures can be synthesized. Special thanks to the Dutch Polymer Institute for financial support

  19. Composites and blends from biobased materials

    Energy Technology Data Exchange (ETDEWEB)

    Kelley, S.S. [National Renewable Energy Laboratory, Golden, CO (United States)

    1995-05-01

    The program is focused on the development of composites and blends from biobased materials to use as membranes, high value plastics, and lightweight composites. Biobased materials include: cellulose derivative microporous materials, cellulose derivative copolymers, and cellulose derivative blends. This year`s research focused on developing an improved understanding of the molecular features that cellulose based materials with improved properties for gas separation applications. Novel cellulose ester membrane composites have been developed and are being evaluated under a collaborative research agreement with Dow Chemicals Company.

  20. Safety Aspects of Bio-Based Nanomaterials.

    Science.gov (United States)

    Catalán, Julia; Norppa, Hannu

    2017-12-01

    Moving towards a bio-based and circular economy implies a major focus on the responsible and sustainable utilization of bio-resources. The emergence of nanotechnology has opened multiple possibilities, not only in the existing industrial sectors, but also for completely novel applications of nanoscale bio-materials, the commercial exploitation of which has only begun during the last few years. Bio-based materials are often assumed not to be toxic. However, this pre-assumption is not necessarily true. Here, we provide a short overview on health and environmental aspects associated with bio-based nanomaterials, and on the relevant regulatory requirements. We also discuss testing strategies that may be used for screening purposes at pre-commercial stages. Although the tests presently used to reveal hazards are still evolving, regarding modifi-cations required for nanomaterials, their application is needed before the upscaling or commercialization of bio-based nanomaterials, to ensure the market potential of the nanomaterials is not delayed by uncertainties about safety issues.

  1. Enzymatic Synthesis of Biobased Polyesters and Polyamides

    Directory of Open Access Journals (Sweden)

    Yi Jiang

    2016-06-01

    Full Text Available Nowadays, “green” is a hot topic almost everywhere, from retailers to universities to industries; and achieving a green status has become a universal aim. However, polymers are commonly considered not to be “green”, being associated with massive energy consumption and severe pollution problems (for example, the “Plastic Soup” as a public stereotype. To achieve green polymers, three elements should be entailed: (1 green raw materials, catalysts and solvents; (2 eco-friendly synthesis processes; and (3 sustainable polymers with a low carbon footprint, for example, (biodegradable polymers or polymers which can be recycled or disposed with a gentle environmental impact. By utilizing biobased monomers in enzymatic polymerizations, many advantageous green aspects can be fulfilled. For example, biobased monomers and enzyme catalysts are renewable materials that are derived from biomass feedstocks; enzymatic polymerizations are clean and energy saving processes; and no toxic residuals contaminate the final products. Therefore, synthesis of renewable polymers via enzymatic polymerizations of biobased monomers provides an opportunity for achieving green polymers and a future sustainable polymer industry, which will eventually play an essential role for realizing and maintaining a biobased and sustainable society.

  2. Potential for Biobased Adhesives in Wood Bonding

    Science.gov (United States)

    Charles R. Frihart

    2016-01-01

    There has been a resurgence of interest and research on using bio-based materials as wood adhesives; however, they have achieved only limited market acceptance. To better understand this low level of replacement, it is important to understand why adhesives work or fail in moisture durability tests. A holistic model for wood adhesives has been developed that clarifies...

  3. Biobased adhesives and non-conventional bonding

    Science.gov (United States)

    Charles Frihart

    2010-01-01

    Biobased adhesives fall into several major classes based upon their chemical structures. Starches are used in large volume, especially in the paper products industries, but cellulosics generally do not have the strength and water resistance needed for most wood products. Several authors have covered cellulosics adhesives (Baumann and Conner 2002, Pizzi 2006). However...

  4. Safety Aspects of Bio-Based Nanomaterials

    Directory of Open Access Journals (Sweden)

    Julia Catalán

    2017-12-01

    Full Text Available Moving towards a bio-based and circular economy implies a major focus on the responsible and sustainable utilization of bio-resources. The emergence of nanotechnology has opened multiple possibilities, not only in the existing industrial sectors, but also for completely novel applications of nanoscale bio-materials, the commercial exploitation of which has only begun during the last few years. Bio-based materials are often assumed not to be toxic. However, this pre-assumption is not necessarily true. Here, we provide a short overview on health and environmental aspects associated with bio-based nanomaterials, and on the relevant regulatory requirements. We also discuss testing strategies that may be used for screening purposes at pre-commercial stages. Although the tests presently used to reveal hazards are still evolving, regarding modifi­cations required for nanomaterials, their application is needed before the upscaling or commercialization of bio-based nanomaterials, to ensure the market potential of the nanomaterials is not delayed by uncertainties about safety issues.

  5. Biobased organic acids production by metabolically engineered microorganisms

    DEFF Research Database (Denmark)

    Chen, Yun; Nielsen, Jens

    2016-01-01

    Bio-based production of organic acids via microbial fermentation has been traditionally used in food industry. With the recent desire to develop more sustainable bioprocesses for production of fuels, chemicals and materials, the market for microbial production of organic acids has been further...... expanded as organic acids constitute a key group among top building block chemicals that can be produced from renewable resources. Here we review the current status for production of citric acid and lactic acid, and we highlight the use of modern metabolic engineering technologies to develop high...... performance microbes for production of succinic acid and 3-hydroxypropionic acid. Also, the key limitations and challenges in microbial organic acids production are discussed...

  6. Production of alcohols and other oxygenates from fossil fuels and renewables : final report for IEA Alternative Motor Fuels Agreement Program of research and development on alternative motor fuels, Annex 4/Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Vancea, L. (comp.) [Natural Resources Canada, Ottawa, ON (Canada)

    1995-07-01

    The objective of the International Energy Agency's (IEA's) Alternative Motor Fuels Agreement Program was to exchange information on the production of alcohols and other oxygenates between 6 participating countries including Canada, Italy, Japan, New Zealand, Sweden and the United States. Various production methods were reviewed in an effort to identify potential areas of cooperative research programs. The original scope was to examine the production of alcohols and other oxygenates from fossil fuels only, but some participants examined their production from renewables. This report provided a brief description of the Annex and the list of participants. It presented the Operating Agent's Report and contained a summary of the contributions submitted by participating countries by topic. In Canada, Iogen of Ottawa, Ontario has conducted a study on the energy, carbon and economic budgets estimated for wheat grain, corn grain, wheat straw, and switchgrass. Iogen has developed a process for fermenting wheat straw and switchgrass into ethanol. Most research has focused on enzymatic hydrolysis processes because of the low yields inherent in dilute acid hydrolysis processes. Enzymes hydrolyze the cellulose to glucose without producing any degradation products, thereby yielding high quantity products with no toxicity. Future bioethanol production will probably be cellulosic-based rather than grain-based. refs., tabs., figs.

  7. Production of alcohols and other oxygenates from fossil fuels and renewables : final report for IEA Alternative Motor Fuels Agreement Program of research and development on alternative motor fuels, Annex 4/Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Vancea, L [Natural Resources Canada, Ottawa, ON (Canada)

    1995-07-01

    The objective of the International Energy Agency's (IEA's) Alternative Motor Fuels Agreement Program was to exchange information on the production of alcohols and other oxygenates between 6 participating countries including Canada, Italy, Japan, New Zealand, Sweden and the United States. Various production methods were reviewed in an effort to identify potential areas of cooperative research programs. The original scope was to examine the production of alcohols and other oxygenates from fossil fuels only, but some participants examined their production from renewables. This report provided a brief description of the Annex and the list of participants. It presented the Operating Agent's Report and contained a summary of the contributions submitted by participating countries by topic. In Canada, Iogen of Ottawa, Ontario has conducted a study on the energy, carbon and economic budgets estimated for wheat grain, corn grain, wheat straw, and switchgrass. Iogen has developed a process for fermenting wheat straw and switchgrass into ethanol. Most research has focused on enzymatic hydrolysis processes because of the low yields inherent in dilute acid hydrolysis processes. Enzymes hydrolyze the cellulose to glucose without producing any degradation products, thereby yielding high quantity products with no toxicity. Future bioethanol production will probably be cellulosic-based rather than grain-based. refs., tabs., figs.

  8. Influence of diffusion of fuel-efficient motor vehicles on gasoline demand for individual user owned passenger cars

    International Nuclear Information System (INIS)

    Sakaguchi, Takahiro

    2000-01-01

    Trends in the demand for petrol in Japan for cars owned by individuals are discussed with reference to expected improvements in fuel efficiency for new models and the results of a survey of user preferences for fuel-efficient vehicles. Demand for petrol in Japan has continued to increase in line with the number of cars used by individual owners. A questionnaire on motor vehicles sent to households found that, while cost and body style were the primary factors in car purchase, three-quarters of respondents would consider buying a low fuel consumption (LFC) version of the model chosen. The influence of LFC vehicles on future demand for petrol was estimated for up to 2015 by combining market timing with consumer preferences. Comparison of the estimated petrol consumption by LFC cars with the Government's requirement for reduced energy use by the transport sector in order to meet its climate change targets indicated a shortfall and a need to increase consumer demand for LFC vehicles. Government measures to reduce energy use in the transport sector, fuel efficiency targets for 2010, major LFC cars, fuel efficiency improvements by major Japanese motor manufacturers and scenarios for assessing the influence of LFC cars are summarised in five tables. Trends in petrol consumption and estimated use by individual user owned passenger cars are shown graphically

  9. Bio-Based Coatings for Paper Applications

    Directory of Open Access Journals (Sweden)

    Vibhore Kumar Rastogi

    2015-11-01

    Full Text Available The barrier resistance and wettability of papers are commonly controlled by the application of petroleum-based derivatives such as polyethylene, waxes and/or fluor- derivatives as coating. While surface hydrophobicity is improved by employing these polymers, they have become disfavored due to limitations in fossil-oil resources, poor recyclability, and environmental concerns on generated waste with lack of biodegradation. Alternatively, biopolymers including polysaccharides, proteins, lipids and polyesters can be used to formulate new pathways for fully bio-based paper coatings. However, difficulties in processing of most biopolymers may arise due to hydrophilicity, crystallization behavior, brittleness or melt instabilities that hinder a full exploitation at industrial scale. Therefore, blending with other biopolymers, plasticizers and compatibilizers is advantageous to improve the coating performance. In this paper, an overview of barrier properties and processing of bio-based polymers and their composites as paper coating will be discussed. In particular, recent technical advances in nanotechnological routes for bio-based nano- composite coatings will be summarized, including the use of biopolymer nanoparticles, or nanofillers such as nanoclay and nanocellulose. The combination of biopolymers along with surface modification of nanofillers can be used to create hierarchical structures that enhance hydrophobicity, complete barrier protection and functionalities of coated papers.

  10. Novel approaches to the creation of alternative motor fuels from renewable raw materials

    Directory of Open Access Journals (Sweden)

    Ольга Олександрівна Гайдай

    2016-06-01

    Full Text Available The paper considers the method of obtaining aliphatic alcohols as components of alternative fuels by catalytic processing of synthesis gas under the conditions of mechanochemical activation of the catalyst without using high pressure.It is established that the introduction of hydrocarbon spherical clusters (onions in the alternative fuel changes physical, chemical and chemmotological characteristics of fuel due to the effect of structure formation. The results of comparative studies of the performance properties of hydrocarbon and alternative fuels are displayed

  11. Fuel cell system economics: comparing the costs of generating power with stationary and motor vehicle PEM fuel cell systems

    International Nuclear Information System (INIS)

    Lipman, Timothy E.; Edwards, Jennifer L.; Kammen, Daniel M.

    2004-01-01

    This investigation examines the economics of producing electricity from proton-exchange membrane (PEM) fuel cell systems under various conditions, including the possibility of using fuel cell vehicles (FCVs) to produce power when they are parked at office buildings and residences. The analysis shows that the economics of both stationary fuel cell and FCV-based power vary significantly with variations in key input variables such as the price of natural gas, electricity prices, fuel cell and reformer system costs, and fuel cell system durability levels. The 'central case' results show that stationary PEM fuel cell systems can supply electricity for offices and homes in California at a net savings when fuel cell system costs reach about $6000 for a 5 kW home system ($1200/kW) and $175,000 for a 250 kW commercial system ($700/kW) and assuming somewhat favorable natural gas costs of $6/GJ at residences and $4/GJ at commercial buildings. Grid-connected FCVs in commercial settings can also potentially supply electricity at competitive rates, in some cases producing significant annual benefits. Particularly attractive is the combination of net metering along with time-of-use electricity rates that allow power to be supplied to the utility grid at the avoided cost of central power plant generation. FCV-based power at individual residences does not appear to be as attractive, at least where FCV power can only be used directly or banked with the utility for net metering and not sold in greater quantity, due to the low load levels at these locations that provide a poor match to automotive fuel cell operation, higher natural gas prices than are available at commercial settings, and other factors

  12. Types, production and assessment of biobased food packaging materials

    Science.gov (United States)

    Food packaging performs an essential function, but packaging materials can have a negative impact on the environment. This book describes the latest advances in bio-based food packaging materials. Book provides a comprehensive review on bio-based, biodegradable and recycled materials and discusses t...

  13. Design and manufacturing of bio-based sandwich structures

    CSIR Research Space (South Africa)

    John, Maya J

    2017-03-01

    Full Text Available The aim of this chapter is to discuss the design and manufacturing of bio-based sandwich structures. As the economic advantages of weight reduction have become mandatory for many advanced industries, bio-based sandwich panels have emerged...

  14. Reduction of motor fuel consumption - Which recipes does the state have at its disposal?; Absenkung des Treibstoffverbrauchs: Welche Rezepte hat der Staat?

    Energy Technology Data Exchange (ETDEWEB)

    Volken, T.

    2008-07-01

    This presentation made at the Swiss 2008 research conference on traffic by Thomas Volken from the Energy Policy Section of the Swiss Federal Office of Energy SFOE takes a look at how motor-fuel consumption can be reduced. First of all, the present situation with regard to heating oil and motor fuels is examined and the gap between actual CO{sub 2} emissions from motor fuels and the target aimed for is discussed. Various legal and economical measures available are examined as are the promotion of technical innovation and motivational measures. The federal energy efficiency action plan and bonus/malus schemes are discussed and the environment label for cars is examined. Further, the situation in the European Union is discussed.

  15. THE POSSIBILITIES OF USING LANDFILL GAS AS A FUEL OF MOTOR VEHICLES IN POLAND

    Directory of Open Access Journals (Sweden)

    Małgorzata Śliwka

    2014-10-01

    Full Text Available Limited energy resources, especially reserves of oil and natural gas and increasing request for fuels, make it necessary to find new energy sources, including from renewable sources. The use of renewable fuels will have the additional benefit to the environment, such as reduction of CO2, SO2, CO and NOx emissions. One of the promising energy sources is biogas produced in agricultural biogas plants and landfills. Biogas landfill should also be used as a fuel for transportation. This paper describes the chain of biomethane (a weel waste, and discussed the possibility of using biomethane as a fuel. The possibilities of using biomethane as a fuel were discussed on Biomaster experiences.

  16. Biodiesel as an alternative motor fuel: Production and policies in the European Union

    International Nuclear Information System (INIS)

    Bozbas, Kahraman

    2008-01-01

    The purpose of this work is to investigate fuel characteristics of biodiesel and its production in European Union. Biodiesel fuel can be made from new or used vegetable oils and animal fats, which are non-toxic, biodegradable, renewable resources. The vegetable oil fuels were not acceptable because they were more expensive than petroleum fuels. Biodiesel has become more attractive recently because of its environmental benefits. With recent increases in petroleum prices and uncertainties concerning petroleum availability, there is renewed interest in vegetable oil fuels for diesel engines. In Europe the most important biofuel is biodiesel. In the European Union biodiesel is the by far biggest biofuel and represents 82% of the biofuel production. Biodiesel production for 2003 in EU-25 was 1,504,000 tons. (author)

  17. Oxidation of Alkane Rich Gasoline Fuels and their Surrogates in a Motored Engine

    KAUST Repository

    Shankar, Vijai S B

    2015-03-30

    The validation of surrogates formulated using a computational framework by Ahmed et al.[1]for two purely paraffinic gasoline fuels labelled FACE A and FACE C was undertaken in this study. The ability of these surrogate mixtures to be used in modelling LTC engines was accessed by comparison of their low temperature oxidation chemistry with that of the respective parent fuel as well as a PRF based on RON. This was done by testing the surrogate mixtures in a modified Cooperative Fuels Research (CFR) engine running in Controlled Autoignition Mode (CAI) mode. The engine was run at a constant speed of 600 rpm at an equivalence ratio of 0.5 with the intake temperature at 150 °C and a pressure of 98 kPa. The low temperature reactivity of the fuels were studied by varying the compression ratio of the engine from the point were very only small low temperature heat release was observed to a point beyond which auto-ignition of the fuel/air mixture occurred. The apparent heat release rates of different fuels was calculated from the pressure histories using first law analysis and the CA 50 times of the low temperature heat release (LTHR) were compared. The surrogates reproduced the cool flame behavior of the parent fuels better than the PRF across all compression ratios.

  18. Oxidation of Alkane Rich Gasoline Fuels and their Surrogates in a Motored Engine

    KAUST Repository

    Shankar, Vijai S B; Al-Qurashi, Khalid; Ahmed, Ahfaz; Atef, Nour; Chung, Suk-Ho; Roberts, William L.; Sarathy, Mani

    2015-01-01

    The validation of surrogates formulated using a computational framework by Ahmed et al.[1]for two purely paraffinic gasoline fuels labelled FACE A and FACE C was undertaken in this study. The ability of these surrogate mixtures to be used in modelling LTC engines was accessed by comparison of their low temperature oxidation chemistry with that of the respective parent fuel as well as a PRF based on RON. This was done by testing the surrogate mixtures in a modified Cooperative Fuels Research (CFR) engine running in Controlled Autoignition Mode (CAI) mode. The engine was run at a constant speed of 600 rpm at an equivalence ratio of 0.5 with the intake temperature at 150 °C and a pressure of 98 kPa. The low temperature reactivity of the fuels were studied by varying the compression ratio of the engine from the point were very only small low temperature heat release was observed to a point beyond which auto-ignition of the fuel/air mixture occurred. The apparent heat release rates of different fuels was calculated from the pressure histories using first law analysis and the CA 50 times of the low temperature heat release (LTHR) were compared. The surrogates reproduced the cool flame behavior of the parent fuels better than the PRF across all compression ratios.

  19. Bio-based Polymer Foam from Soyoil

    Science.gov (United States)

    Bonnaillie, Laetitia M.; Wool, Richard P.

    2006-03-01

    The growing bio-based polymeric foam industry is presently lead by plant oil-based polyols for polyurethanes and starch foams. We developed a new resilient, thermosetting foam system with a bio-based content higher than 80%. The acrylated epoxidized soybean oil and its fatty acid monomers is foamed with pressurized carbon dioxide and cured with free-radical initiators. The foam structure and pore dynamics are highly dependent on the temperature, viscosity and extent of reaction. Low-temperature cure hinds the destructive pore coalescence and the application of a controlled vacuum results in foams with lower densities ˜ 0.1 g/cc, but larger cells. We analyze the physics of foam formation and stability, as well as the structure and mechanical properties of the cured foam using rigidity percolation theory. The parameters studied include temperature, vacuum applied, and cross-link density. Additives bring additional improvements: nucleating agents and surfactants help produce foams with a high concentration of small cells and low bulk density. Hard and soft thermosetting foams with a bio content superior to 80% are successfully produced and tested. Potential applications include foam-core composites for hurricane-resistant housing, structural reinforcement for windmill blades, and tissue scaffolds.

  20. Numerical Simulations of Flow and Fuel Regression Rate Coupling in Hybrid Rocket Motors

    Directory of Open Access Journals (Sweden)

    Marius STOIA-DJESKA

    2017-03-01

    Full Text Available The hybrid propulsion offers some remarkable advantages like high safety and high specific impulse and thus it is considered a promising technology for the next generation launchers and space systems. The purpose of this work is to validate a design tool for hybrid rocket motors (HRM through numerical simulations.

  1. 76 FR 39477 - Revisions and Additions to Motor Vehicle Fuel Economy Label

    Science.gov (United States)

    2011-07-06

    ...The Environmental Protection Agency (EPA) and the National Highway Traffic Safety Administration (NHTSA) are issuing a joint final rule establishing new requirements for the fuel economy and environment label that will be posted on the window sticker of all new automobiles sold in the U.S. The labeling requirements apply for model year 2013 and later vehicles with a voluntary manufacturer option for model year 2012. The labeling requirements apply to passenger cars, light-duty trucks, and medium duty passenger vehicles such as larger sport-utility vehicles and vans. The redesigned label provides expanded information to American consumers about new vehicle fuel economy and fuel consumption, greenhouse gas and smog-forming emissions, and projected fuel costs and savings, and also includes a smartphone interactive code that permits direct access to additional Web resources. Specific label designs are provided for gasoline, diesel, ethanol flexible fuel, compressed natural gas, electric, plug-in hybrid electric, and hydrogen fuel cell vehicles. This rulemaking is in response to provisions in the Energy Independence and Security Act of 2007 that imposed several new labeling requirements and new advanced-technology vehicles entering the market. NHTSA and EPA believe that these changes will help consumers to make more informed vehicle purchase decisions, particularly as the future automotive marketplace provides more diverse vehicle technologies from which consumers may choose. These new label requirements do not affect the methodologies that EPA uses to generate consumer fuel economy estimates, or the automaker compliance values for NHTSA's corporate average fuel economy and EPA's greenhouse gas emissions standards. This action also finalizes a number of technical corrections to EPA's light-duty greenhouse gas emission standards program.

  2. Hydrogen condensation products of Turkmenistan gas fields as motor fuel components

    Energy Technology Data Exchange (ETDEWEB)

    Kul-dzhaev, B.A.; Sergienko, S.R.; Tsibrova, E.G.

    1985-07-01

    Technical data are provided in tabular form on the composition of hydrocarbon condensation products obtained from various gas fields in Turkmenia, with an analysis of their usefulness as gasoline and diesel fuels. For example, high-paraffin condensates are characterized by low octane numbers (30-50) of the gasoline fraction (150-180/sup 0/C). However, lowering the temperature at the end of distillation to 120-130/sup 0/C increased the octane number to 73, one point higher than required by State Standards for automobile gasoline A-72. The cetane number of diesel fuels in general exceed the State Standards, especially in the case of fractions 150/sup 0/C and 180/sup 0/C of the high-paraffin condensates obtained from the Shatlyk site. Summarized data are presented on the suitability of the products obtained from the different site for the different types of fuels. 4 references.

  3. Price elasticity of Swiss motor fuel demand; Elasticite-prix de la demande d'essence en Suisse

    Energy Technology Data Exchange (ETDEWEB)

    Baranzini, A. [Haute Ecole de Gestion de Geneve (HEG-Geneve), Centre de Recherche Appliquee en Gestion (CRAG), Carouge (Switzerland); Neto, D.; Weber, S. [Universite de Geneve, Laboratoire d' Economie Appliquee (LEA), Geneve (Switzerland)

    2009-07-15

    This report for the Swiss Federal Office of Energy (SFOE) by the University of Geneva takes a look at the price elasticity of motor fuel demand in Switzerland. Macro-economic data on petrol and diesel consumption is used to calculate short and long-term price elasticity. Various factors that have an influence on prices are discussed. Data for the period 1970 - 2008 is used. A method developed by Engle and Granger is used to examine short and long-term developments in this area. A large number of variables are used in mathematical models to explain price developments. The methods used are described and the results are presented in tabular form. Various external effects such the oil-price shocks and price developments in neighbouring countries are examined.

  4. Price elasticity of Swiss motor fuel demand; Elasticite-prix de la demande d'essence en Suisse

    Energy Technology Data Exchange (ETDEWEB)

    Baranzini, A. [Haute Ecole de Gestion de Geneve (HEG-Geneve), Centre de Recherche Appliquee en Gestion (CRAG), Carouge (Switzerland); Neto, D.; Weber, S. [Universite de Geneve, Laboratoire d' Economie Appliquee (LEA), Geneve (Switzerland)

    2009-07-15

    This report for the Swiss Federal Office of Energy (SFOE) by the University of Geneva takes a look at the price elasticity of motor fuel demand in Switzerland. Macro-economic data on petrol and diesel consumption is used to calculate short and long-term price elasticity. Various factors that have an influence on prices are discussed. Data for the period 1970 - 2008 is used. A method developed by Engle and Granger is used to examine short and long-term developments in this area. A large number of variables are used in mathematical models to explain price developments. The methods used are described and the results are presented in tabular form. Various external effects such the oil-price shocks and price developments in neighbouring countries are examined.

  5. S.790: This Act may be cited as the Motor Fuel Consumer Protection Act of 1991, introduced in the Senate of the United States, One Hundred Second Congress, First Session, April 9, 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This bill would amend the antitrust laws in order to preserve and promote wholesale and retail competition in the retail gasoline market. The bill describes limits on the ownership and operation of service stations. The main provision is the it shall be unlawful for any producer or refiner to require any retail motor fuel dealer to purchase more than 70% of the monthly retail sales of motor fuel from such refiner or producer. Motor fuel refers to gasoline, diesel fuel, alcohol, or any mixture of these sold for use in automobiles and related vehicles

  6. Prospects for a bio-based succinate industry.

    Science.gov (United States)

    McKinlay, James B; Vieille, C; Zeikus, J Gregory

    2007-09-01

    Bio-based succinate is receiving increasing attention as a potential intermediary feedstock for replacing a large petrochemical-based bulk chemical market. The prospective economical and environmental benefits of a bio-based succinate industry have motivated research and development of succinate-producing organisms. Bio-based succinate is still faced with the challenge of becoming cost competitive against petrochemical-based alternatives. High succinate concentrations must be produced at high rates, with little or no by-products to most efficiently use substrates and to simplify purification procedures. Herein are described the current prospects for a bio-based succinate industry, with emphasis on specific bacteria that show the greatest promise for industrial succinate production. The succinate-producing characteristics and the metabolic pathway used by each bacterial species are described, and the advantages and disadvantages of each bacterial system are discussed.

  7. Synthesis and Verification of Biobased Terephthalic Acid from Furfural

    Science.gov (United States)

    Tachibana, Yuya; Kimura, Saori; Kasuya, Ken-Ichi

    2015-02-01

    Exploiting biomass as an alternative to petrochemicals for the production of commodity plastics is vitally important if we are to become a more sustainable society. Here, we report a synthetic route for the production of terephthalic acid (TPA), the monomer of the widely used thermoplastic polymer poly(ethylene terephthalate) (PET), from the biomass-derived starting material furfural. Biobased furfural was oxidised and dehydrated to give maleic anhydride, which was further reacted with biobased furan to give its Diels-Alder (DA) adduct. The dehydration of the DA adduct gave phthalic anhydride, which was converted via phthalic acid and dipotassium phthalate to TPA. The biobased carbon content of the TPA was measured by accelerator mass spectroscopy and the TPA was found to be made of 100% biobased carbon.

  8. 7 CFR 2902.7 - Determining biobased content.

    Science.gov (United States)

    2010-01-01

    ....7 Determining biobased content. (a) Certification requirements. For any product offered for... the weight (mass) of the total organic carbon in the material or product. (d) Products with the same...

  9. Motor fuel demand analysis - applied modelling in the European union; Modelisation de la demande de carburant appliquee a l`europe

    Energy Technology Data Exchange (ETDEWEB)

    Chorazewiez, S

    1998-01-19

    Motor fuel demand in Europe amounts to almost half of petroleum products consumption and to thirty percent of total final energy consumption. This study considers, Firstly, the energy policies of different European countries and the ways in which the consumption of motor gasoline and automotive gas oil has developed. Secondly it provides an abstract of demand models in the energy sector, illustrating their specific characteristics. Then it proposes an economic model of automotive fuel consumption, showing motor gasoline and automotive gas oil separately over a period of thirty years (1960-1993) for five main countries in the European Union. Finally, forecasts of consumption of gasoline and diesel up to the year 2020 are given for different scenarios. (author) 330 refs.

  10. Biobased Packaging - Application in Meat Industry

    Directory of Open Access Journals (Sweden)

    S. Wilfred Ruban

    2009-04-01

    Full Text Available Because of growing problems of waste disposal and because petroleum is a nonrenewable resource with diminishing quantities, renewed interest in packaging research is underway to develop and promote the use of “bio-plastics.” In general, compared to conventional plastics derived from petroleum, bio-based polymers have more diverse stereochemistry and architecture of side chains which enable research scientists a greater number of opportunities to customize the properties of the final packaging material. The primary challenge facing the food (Meat industry in producing bio-plastic packaging, currently, is to match the durability of the packaging with product shelf-life. Notable advances in biopolymer production, consumer demand for more environmentally-friendly packaging, and technologies that allow packaging to do more than just encompass the food are driving new and novel research and developments in the area of packaging for muscle foods. [Vet. World 2009; 2(2.000: 79-82

  11. 75 FR 58077 - Revisions and Additions to Motor Vehicle Fuel Economy Label

    Science.gov (United States)

    2010-09-23

    ...The Environmental Protection Agency (EPA) and the National Highway Traffic Safety Administration (NHTSA) are conducting a joint rulemaking to redesign and add information to the current fuel economy label that is posted on the window sticker of all new cars and light- duty trucks sold in the U.S. The redesigned label will provide new information to American consumers about the fuel economy and consumption, fuel costs, and environmental impacts associated with purchasing new vehicles beginning with model year 2012 cars and trucks. This action will also develop new labels for certain advanced technology vehicles, which are poised to enter the U.S. market, in particular plug-in hybrid electric vehicles and electric vehicles. NHTSA and EPA are proposing these changes because the Energy Independence and Security Act (EISA) of 2007 imposes several new labeling requirements, because the agencies believe that the current labels can be improved to help consumers make more informed vehicle purchase decisions, and because the time is right to develop new labels for advanced technology vehicles that are being commercialized. This proposal is also consistent with the recent joint rulemaking by EPA and NHTSA that established harmonized federal greenhouse gas (GHG) emissions and corporate average fuel economy (CAFE) standards for new cars, sport utility vehicles, minivans, and pickup trucks for model years 2012-2016.

  12. Opportunities for a bio-based economy in the Netherlands

    International Nuclear Information System (INIS)

    Sanders, J.; Hoeven, D. van der

    2008-01-01

    The shift to a bio-based economy for the Netherlands is not only required because of climate change, but also for industrial strategy reasons. Traditional strongholds of the Dutch economy like the Rotterdam harbour, the agricultural sector (including the greenhouse sector, and food and feed industries) and the petrochemical industry will be affected by the new economic realities, and it is precisely to these sectors that a bio-based economy will offer new opportunities. (author)

  13. Annex 34 : task 1 : analysis of biodiesel options : biomass-derived diesel fuels : final report

    Energy Technology Data Exchange (ETDEWEB)

    McGill, R [Oak Ridge National Laboratory, TN (United States); Aakko-Saksa, P; Nylund, N O [TransEnergy Consulting Ltd., Helsinki (Finland)

    2009-06-15

    Biofuels are derived from woody biomass, non-woody biomass, and organic wastes. The properties of vegetable oil feedstocks can have profound effects on the properties of the finished biodiesel product. However, all biodiesel fuels have beneficial effects on engine emissions. This report discussed the use of biodiesel fuels as replacements for part of the diesel fuel consumed throughout the world. Biodiesel fuels currently being produced from fatty acid esters today were reviewed, as well as some of the more advanced diesel replacement fuels. The report was produced as part of the International Energy Agency (IEA) Advanced Motor Fuels (AMF) Implementing Agreement Annex 34, and was divided into 14 sections: (1) an introduction, (2) biodiesel and biomass, (3) an explanation of biodiesel, (4) properties of finished biodiesel fuels, (5) exhaust emissions of finished biodiesel fuels and blends, (6) life-cycle emissions and energy, (7) international biodiesel (FAME) technical standards and specifications, (8) growth in production and use of biodiesel fuels, (9) biofuel refineries, (10) process technology, (11) development and status of biorefineries, (12) comparison of options to produce biobased diesel fuels, (13) barriers and gaps in knowledge, and (14) references. 113 refs., 37 tabs., 74 figs.

  14. Bio-Based Polymers with Potential for Biodegradability

    Directory of Open Access Journals (Sweden)

    Thomas F. Garrison

    2016-07-01

    Full Text Available A variety of renewable starting materials, such as sugars and polysaccharides, vegetable oils, lignin, pine resin derivatives, and proteins, have so far been investigated for the preparation of bio-based polymers. Among the various sources of bio-based feedstock, vegetable oils are one of the most widely used starting materials in the polymer industry due to their easy availability, low toxicity, and relative low cost. Another bio-based plastic of great interest is poly(lactic acid (PLA, widely used in multiple commercial applications nowadays. There is an intrinsic expectation that bio-based polymers are also biodegradable, but in reality there is no guarantee that polymers prepared from biorenewable feedstock exhibit significant or relevant biodegradability. Biodegradability studies are therefore crucial in order to assess the long-term environmental impact of such materials. This review presents a brief overview of the different classes of bio-based polymers, with a strong focus on vegetable oil-derived resins and PLA. An entire section is dedicated to a discussion of the literature addressing the biodegradability of bio-based polymers.

  15. Green Thermosetting Factory: Novel Star-Shaped Biobased Systems and Their Thermosetting Resins; Synthesis and Characterization

    Science.gov (United States)

    Jahandideh, Arash

    Increasing attentions toward sustainable development, economic and environmental issues have led to many attempts at replacing the petroleum-based materials with renewables. Substitution of petroleum-based platforms with green alternative technologies is beneficiary in different ways. Using bio-renewables reduces the dependency of the national plastic industry to the petroleum resources and substantially promotes the environmental profile and sustainability of the product. It is expected that the emergence of the corn-based thermosetting industry generates substantial profits for the corn production sector. Developments in the emerging biobased thermosets are spectacular from a technological point of view. However, there are still several disadvantages associated with the current biobased thermosetting resins, e.g. low processability, environmental issues, expensive sources and poor thermomechanical properties. Use of natural fibers not only contributes to the production of a more environmentally friendly product, but also has advantages such as low-weight product and low manufacturing costs. The results of this study show a possibility of production of biocomposites made from natural fibers and star-shaped resin, synthesized from corn-based materials (lactic acid and itaconic acid) and different multihydroxyl core molecules. These resins were synthesized via two-steps strategy: polycondensation of the monomers with the core molecules followed by end-functionalization of the branches by methacrylic anhydride or itaconic acid. The results have shown that these resin are capable of competing with or even surpassing fossil fuel based resins in terms of cost and eco-friendliness aspect. Inexpensive biobased raw material, better environmental profile, low viscosity, and better processability of the matrix along with better thermomechanical properties of the produced biocomposites are of advantages expected for these systems.

  16. Aggregate effects of reducing the motor fuels excise tax in the United States

    International Nuclear Information System (INIS)

    Uri, N.D.; Boyd, R.

    1997-01-01

    The analysis in this article examines the impact of reducing the excise tax on gasoline and diesel fuel on the U.S. economy. The analytical approach used consists of a computable general equilibrium model composed of 14 producing sectors, 14 consuming sectors, 6 household categories classified by income, and a government. The effects are examined of a 4.3 cents per gallon reduction in the excise tax on gasoline and diesel fuel on prices and quantities. The results suggest, for example, a decrease in the tax would result in higher output by the producing sectors (by about $2.86 billion), an expansion in the consumption of goods and services (by about $3.48 billion), and an increase in welfare (by about $3.59 billion). The government would realize a decrease in revenue of about $2.37 billion. When subjected to a sensitivity analysis, the results are reasonably robust with regard to the assumption of the values of the substitution elasticities

  17. Life cycle impact assessment of bio-based plastics from sugarcane ethanol

    NARCIS (Netherlands)

    Tsiropoulos, I.; Faaij, A. P C; Lundquist, L.; Schenker, U.; Briois, J. F.; Patel, M. K.

    2015-01-01

    The increasing production of bio-based plastics calls for thorough environmental assessments. Using life cycle assessment, this study compares European supply of fully bio-based high-density polyethylene and partially bio-based polyethylene terephthalate from Brazilian and Indian sugarcane ethanol

  18. Consumer perception of bio-based products-An exploratory study in 5 European countries

    NARCIS (Netherlands)

    Sijtsema, Siet J.; Onwezen, Marleen C.; Reinders, Machiel J.; Dagevos, Hans; Partanen, Asta; Meeusen-van Onna, Marieke

    2016-01-01

    This study explores people's perceptions (i.e., positive and negative associations, mixed feelings) regarding the concept of 'bio-based' in general and specific bio-based products. This exploratory study is one of the first consumer studies in the field of bio-based research. Three focus group

  19. Projections for the Production of Bulk Volume Bio-Based Polymers in Europe and Environmental Implications

    NARCIS (Netherlands)

    Patel, M.K.; Crank, M.

    2007-01-01

    In this paper we provide an overview of the most important emerging groups of bio-based polymers for bulk volume applications and we discuss market projections for these types of bio-based polymers in the EU, thereby distinguishing between three scenarios. Bio-based polymers are projected to reach a

  20. SYNTHESIS AND CHARACTERIZATION OF BIO-BASED POLYESTER POLYOL

    Directory of Open Access Journals (Sweden)

    MİTHAT ÇELEBİ

    2016-11-01

    Full Text Available Polyurethanes are versatile polymeric materials and are usually synthesised by isocyanate reactions with polyols. Due to the variety of isocyanates and polyols, particularly polyols, polyurethanes can be easily tailored for wide applications, such as rigid and flexible foams, coatings, adhesives, and elastomers. Considerable efforts have been recently devoted to developing bio-based substitutes for petroleum-based polyuretahanes due to increasing concerns over the depletion of petroleum resources, environment, and sustainability. Polyester polyols based on aliphatic and aromatic dicarboxylic acids are one of the most important materials in polymer technologies. Large volume of plants oils are used as renewable resources to produce various chemicals which are industrially important to make soaps, cosmetic products, surfactants, lubricants, diluents, plasticizers, inks, agrochemicals, composite materials, food industry. This study introduces synthesis and properties of bio-based polyols from different renewable feedstocks including vegetable oils and derivatives. A comparison of bio-based polyol properties with their petroleum-based analogues were investigated.

  1. Bio-based chemicals - green, but also sustainable?

    DEFF Research Database (Denmark)

    Ögmundarson, Ólafur; Herrgard, Markus; Förster, Jochen

    For almost two decades, the chemical industry has put great effort into developing bio-chemicals,among others to fight global warming caused by greenhouse gas emissions, one of the biggest threats that are faced by our society today. To facilitate a growing and versatile bio-based chemical...... production, the US Department of Energy proposed in 2004 a list of 12 building block chemicals which can either be converged through biological or chemical conversions. Moving toward more bio-based chemicals, the chemical industry does not only claim to reduce climate change impacts, but also...... that they are increasing overall sustainability in chemical production. Whether such claims are justifiable is unclear. When sustainability of bio-based polymer production is assessed, various environmental trade-offs occur that need to be considered. It is not enough to claim that a bio-chemical is sustainable...

  2. Comparing life cycle energy and GHG emissions of bio-based PET, recycled PET, PLA and man-made cellulosics

    NARCIS (Netherlands)

    Shen, L.; Worrell, E.; Patel, M.K.

    2012-01-01

    The purpose of this paper is to review the environmental profiles of petrochemical PET, (partially) bio-based PET, recycled PET, and recycled (partially) bio-based PET, and compare them with other bio-based materials, namely PLA (polylactic acid, a bio-based polyester) and man-made cellulose

  3. Multidisciplinary Graduate Curriculum in Support of the Biobased Products Industry

    Energy Technology Data Exchange (ETDEWEB)

    John R. Dorgan

    2005-07-31

    The project had a dominant education component. The project involved revising curriculum to educate traditional engineering students in the emerging field of industrial biotechnology. New classes were developed and offered. As a result, the curriculum of the Colorado School of Mines was expanded to include new content. Roughly 100 undergraduates and about 10 graduate students each year benefit from this curricular expansion. The research associated with this project consisted of developing new materials and energy sources from renewable resources. Several significant advances were made, most importantly the heat distortion temperature of polylactide (PLA) was increased through the addition of cellulosic nanowhiskers. The resulting ecobionanocomposites have superior properties which enable the use of renewable resource based plastics in a variety of new applications. Significant amounts of petroleum are thereby saved and considerable environmental benefits also result. Effectiveness and economic feasibility of the project proved excellent. The educational activities are continuing in a sustainable fashion, now being supported by tuition revenues and the normal budgeting of the University. The PI will be teaching one of the newly developed classes will next Fall (Fall 2006), after the close of the DOE grant, and again repeatedly into the future. Now established, the curriculum in biobased products and energy will grow and evolve through regular teaching and revision. On the research side, the new plastic materials appear economically feasible and a new collaboration between the PI’s group and Sealed Air, a major food-packaging manufacturer, has been established to bring the new green plastics to market. Public benefits of the project are noteworthy in many respects. These include the development of a better educated workforce and citizenry capable of providing technological innovation as a means of growing the economy and providing jobs. In particular, the

  4. Recent Advances in the Sound Insulation Properties of Bio-based Materials

    Directory of Open Access Journals (Sweden)

    Xiaodong Zhu

    2013-12-01

    Full Text Available Many bio-based materials, which have lower environmental impact than traditional synthetic materials, show good sound absorbing and sound insulation performances. This review highlights progress in sound transmission properties of bio-based materials and provides a comprehensive account of various multiporous bio-based materials and multilayered structures used in sound absorption and insulation products. Furthermore, principal models of sound transmission are discussed in order to aid in an understanding of sound transmission properties of bio-based materials. In addition, the review presents discussions on the composite structure optimization and future research in using co-extruded wood plastic composite for sound insulation control. This review contributes to the body of knowledge on the sound transmission properties of bio-based materials, provides a better understanding of the models of some multiporous bio-based materials and multilayered structures, and contributes to the wider adoption of bio-based materials as sound absorbers.

  5. Opportunities for a Bio-based Economy in the Netherlands

    NARCIS (Netherlands)

    Sanders, J.P.M.; Hoeven, van der D.A.

    2008-01-01

    The shift to a bio-based economy for the Netherlands is not only required because of climate change, but also for industrial strategy reasons. Traditional strongholds of the Dutch economy like the Rotterdam harbour, the agricultural sector (including the greenhouse sector, and food and feed

  6. Biobased economy : state-of-the-art assessment

    NARCIS (Netherlands)

    Nowicki, P.L.; Banse, M.A.H.; Bolck, C.H.; Bos, H.L.; Scott, E.L.

    2008-01-01

    The interest in the biobased economy stems from the possibility to substitute biologically derived materials and processes for the production of goods that will, therefore, result in a reduced use of petroleum and petro-chemistry. Other reasons are the reduction in the energy required in production

  7. Opportunity and development of bio-based composites

    Science.gov (United States)

    Zhiyong Cai; Jerrold E. Winandy

    2005-01-01

    Our forests are a naturally renewable resource that has been used as a principal source of bio-energy and building materials for centuries. The rapid growth of world population has now resulted in substantial increases in demand and in consumption of all raw materials. This now provides a unique opportunity of developing new bio-based composites. The 100-year history...

  8. Synthesis of Biobased Succinonitrile from Glutamic Acid and Glutamine

    NARCIS (Netherlands)

    Lammens, T.M.; Nôtre, Le J.; Franssen, M.C.R.; Scott, E.L.; Sanders, J.P.M.

    2011-01-01

    Succinonitrile is the precursor of 1,4-diaminobutane, which is used for the industrial production of polyamides. This paper describes the synthesis of biobased succinonitrile from glutamic acid and glutamine, amino acids that are abundantly present in many plant proteins. Synthesis of the

  9. Bio-composites : opportunities for value-added biobased materials

    Energy Technology Data Exchange (ETDEWEB)

    Drzal, L.T. [Michigan State Univ., East Lansing, MI (United States). Dept. of Chemical Engineering and Materials Science]|[Michigan State Univ., East Lansing, MI (United States). Composite Materials and Structures Center

    2003-07-01

    In order to reduce dependency on foreign oil, there is a growing need to develop and commercialize new bio-based green materials and technologies that can produce bio-based structural materials that are competitive with current synthetic products. The use of bio-based products would also improve the environment and create new opportunities for the agricultural economy. This paper described ongoing research into bio-based materials and products that replace petroleum-based products. In particular, it examined the use of biocomposites made by embedding natural/biofibers such as kenaf, hemp, flax, jute, henequen, pineapple leaf fiber, corn stalk fibers and native Michigan grasses into petroleum-derived traditional plastics such as polypropylene, unsaturated polyesters and epoxies. It also examines the use of green biocomposites developed by embedding these bio-fibers into renewable resource-based bioplastics such as cellulosic plastics and soy-based plastics. New processing methods that combine biofibers with plastics were needed to produce the biocomposites with desirable mechanical properties. The study showed that biofiber reinforced petroleum-based plastic biocomposites can produce a structural material that offers a balance between ecology, economy and technology. The potential for using these materials for automotive and building materials was also presented. 1 tab., 28 figs.

  10. Biobased step-growth polymers : chemistry, functionality and applicability

    NARCIS (Netherlands)

    Noordover, B.A.J.

    2008-01-01

    Inspired by the opportunity to obtain materials with interesting new properties and further stimulated by the increasing oil prices and the augmenting environmental concerns, renewed interest in biobased polymers has recently arisen. Extensive efforts are being invested in extracting useful starting

  11. Microbial conversion of biomass into bio-based polymers.

    Science.gov (United States)

    Kawaguchi, Hideo; Ogino, Chiaki; Kondo, Akihiko

    2017-12-01

    The worldwide market for plastics is rapidly growing, and plastics polymers are typically produced from petroleum-based chemicals. The overdependence on petroleum-based chemicals for polymer production raises economic and environmental sustainability concerns. Recent progress in metabolic engineering has expanded fermentation products from existing aliphatic acids or alcohols to include aromatic compounds. This diversity provides an opportunity to expand the development and industrial uses of high-performance bio-based polymers. However, most of the biomonomers are produced from edible sugars or starches that compete directly with food and feed uses. The present review focuses on recent progress in the microbial conversion of biomass into bio-based polymers, in which fermentative products from renewable feedstocks serve as biomonomers for the synthesis of bio-based polymers. In particular, the production of biomonomers from inedible lignocellulosic feedstocks by metabolically engineered microorganisms and the synthesis of bio-based engineered plastics from the biological resources are discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Understanding intentions to purchase bio-based products

    NARCIS (Netherlands)

    Onwezen, Marleen C.; Reinders, Machiel J.; Sijtsema, Siet J.

    2017-01-01

    This article aims to explore whether subjective ambivalence increases the understanding of consumers' intentions to buy bio-based products. Subjective ambivalence is the aversive feeling that accompanies evaluations containing both negative and positive elements. Two studies (N = 1851) in six

  13. 76 FR 3789 - Voluntary Labeling Program for Biobased Products

    Science.gov (United States)

    2011-01-20

    ... products is to inform consumers that these new and innovative products are available and that USDA has... violates the consumer advertising rules of the FTC. \\2\\ The definition of ``biobased products'' found in... endorsement. The consumer may also conclude that forestry practices, no matter how sustainable, are less...

  14. Bio-based fillers for environmentally friendly composites

    CSIR Research Space (South Africa)

    Mokhothu, Thabang H

    2017-03-01

    Full Text Available The use of bio-based fillers as alternative replacement for synthetic fillers has been dictated by increasing ecological concerns as well as depleting petroleum resources. The other aspect is a growing need for eco-friendly, renewable...

  15. Biobased Organic Chemistry Laboratories as Sustainable Experiment Alternatives

    Science.gov (United States)

    Silverman, Julian R.

    2016-01-01

    As nonrenewable resources deplete and educators seek relevant interdisciplinary content for organic chemistry instruction, biobased laboratory experiments present themselves as potential alternatives to petroleum-based transformations, which offer themselves as sustainable variations on important themes. Following the principles of green chemistry…

  16. HFRR investigation of biobased and petroleum based oils

    Science.gov (United States)

    Biobased oils come in a wide range of chemical structures as do petroleum based oils. In addition, a distinct structural difference exists between these two broad categories of oils. Previous work has shown that, in spite of the structural differences, these two categories of oils display similar pr...

  17. Bio-based supply chains : risks and institutional arrangements

    NARCIS (Netherlands)

    Peerlings, J.H.M.; Ge, L.; Galen, van M.A.

    2012-01-01

    One of the challenges for the bio-based economy is to achieve production efficiency that can compete with fossil-based products. New scale-efficient product supply chains have to be created, or current supply chains have to be amended to incorporate the biomass supply chain. These new supply chains

  18. Bio-based targeted chemical engineering education : Role and impact of bio-based energy and resourcedevelopment projects

    NARCIS (Netherlands)

    N.M. Márquez Luzardoa; Dr. ir. Jan Venselaar

    2012-01-01

    Avans University of Applied Sciences is redrafting its courses and curricula in view of sustainability. For chemical engineering in particular that implies a focus on 'green' and bio-based processes, products and energy. Avans is situated in the Southwest region of the Netherlands and specifically

  19. 40 CFR 80.590 - What are the product transfer document requirements for motor vehicle diesel fuel, NRLM diesel...

    Science.gov (United States)

    2010-07-01

    ... distillates? 80.590 Section 80.590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... oil, ECA marine fuel, and other distillates? (a) This paragraph (a) applies on each occasion that any... distillates used or intended to be used as MVNRLM diesel fuel, heating oil, or ECA marine fuel) except when...

  20. Catalytic agents; motor fuels

    Energy Technology Data Exchange (ETDEWEB)

    1935-09-16

    The anti-knock qualities of benzines are improved by passing them in the vapor phase and at temperatures below which cracking takes place over catalysts comprising phosphates. A Mexican straight run gasoline (octane no. 55) is passed at 450/sup 0/C over granular boron phosphate. A product having an octane number of 62.5 is obtained without loss due to formation of gases. The boron phosphate was prepared by heating on a steam bath orthophosphoric acid and boric acid in the ratio corresponding to the compound BPO/sub 4/.

  1. Alternative drives for motor cars. Hybrid systems, fuel cells, alternative energy sources. 2. enl. ed.; Alternative Antriebe fuer Automobile. Hybridsysteme, Brennstoffzellen, alternative Energietraeger

    Energy Technology Data Exchange (ETDEWEB)

    Stan, Cornel [Berkeley Univ., CA (United States)]|[Paris Univ. (France)]|[Pisa Univ. (Italy)]|[Perugia Univ. (Italy)]|[Westsaechsischen Hochschule Zwickau (Germany)

    2008-07-01

    The implementation possibilities of future drive concepts - from hybrid systems comprising an electric motor and an internal combustion engine to fuel cells to alternative fuels like hydrogen or alcohol - will depend largely on quality criteria, e.g. power density, rotary momentum, acceleration characteristics, specific energy consumption, emissions of chemical substances, and noise. The boundary criteria for the introduction of realizeable concepts of alternative drives for motor cars will be defined by the availability and storability of the envisaged fuels, technical complexity, cost, safety, infrastructure and service. The book presents and analyzes the processes, drives and energy sources that can be combined in complex energy management systems for motor cars in accordance with the aforementioned criteria. Knowledge about these facts is indispensable for the development of new concepts. The 2nd edition describes many new developments in car propulsion systems as well as their combinations, new energy sources, energy converters and energy stores. All contents and literature reflect the latest state of science and technology. (orig.) [German] Ueber die Realisierungsmoeglichkeiten zukuenftiger Antriebskonzepte - von Hybridsystemen Elektro-/Verbrennungsmotor ueber Brennstoffzellen bis zu alternativen Energietraegern wie Wasserstoff oder Alkohol - werden fundierte Kriterien der Qualitaet eines Antriebs entscheiden. Leistungsdichte, Drehmomentverlauf, Beschleunigungscharakteristik, spezifischer Energieverbrauch sowie Emission chemischer Stoffe und Geraeusche sind dafuer wichtige Merkmale zur Qualitaetsbeurteilung. Die Verfuegbarkeit und die Speicherfaehigkeit vorgesehener Energietraeger, die technische Komplexitaet, Kosten, Sicherheit, Infrastruktur und Service werden die Randbedingungen fuer die Einfuehrung realisierbarer Konzepte alternativer Antriebe fuer Automobile stellen. Die Uebersicht und die Analyse der Prozesse, Antriebsmaschinen und Energietraeger, die

  2. Sustainability of biomass in a bio-based economy. A quick-scan analysis of the biomass demand of a bio-based economy in 2030 compared to the sustainable supply

    Energy Technology Data Exchange (ETDEWEB)

    Ros, J.; Olivier, J.; Notenboom, J. [Netherlands Environmental Assessment Agency PBL, Bilthoven (Netherlands); Croezen, H.; Bergsma, G. [CE Delft, Delft (Netherlands)

    2012-02-15

    The conversion of a fossil fuel-based economy into a bio-based economy will probably be restricted in the European Union (EU) by the limited supply of ecologically sustainable biomass. It appears realistic that, for the EU, the sustainable biomass supply will be enough to meet about 10% of the final energy and feedstock consumption in 2030. Under optimistic assumptions, this supply might increase to 20%. EU Member States, in their Renewable Energy Action Plans for 2020, already aim to apply an amount of biomass that already approaches this 10%. Therefore, from a sustainability perspective, there is an urgent need to guarantee ecologically sustainable biomass production. In considering sustainable biomass production, land use is the most critical issue, especially the indirect land-use impacts on greenhouse gas emissions and biodiversity. The use of waste resources and agricultural and forestry residues, that does not involve additional land use, therefore, would be a sustainable option. Technically, it is possible to use these types of resources for most applications in a bio-based economy. However, it seems unlikely that, by 2030, waste and residue resources will contribute more than three to four per cent to the final energy and feedstock consumption in Europe. Moreover, many waste and residue resources currently already have useful applications; for instance, as feed or soil improvers. These are the main findings of a quick-scan analysis carried out by the PBL Netherlands Environmental Assessment Agency and CE Delft on the sustainability of a bio-based economy. Three priorities can be distinguished in the transition to an ecologically sustainable bio-based economy that aims to reduce the consumption of fossil fuels: (1) develop new technologies, procedures and infrastructure to collect or to produce more biomass without using directly or indirectly valuable natural land; (2) develop technologies to produce hydrocarbons from types of biomass that have potentially

  3. Azolla domestication towards a biobased economy?

    NARCIS (Netherlands)

    Brouwer, Paul; Brautigam, A.; Kulahoglu, C.; Tazelaar, A.O.E.; Kurz, S.; Nierop, K.G.J.; Werf, van der A.K.; Weber, A.P.M.; Schluepmann, H.

    2014-01-01

    Due to its phenomenal growth requiring neither nitrogen fertilizer nor arable land and its biomass composition, the mosquito fern Azolla is a candidate crop to yield food, fuels and chemicals sustainably. To advance Azolla domestication, we research its dissemination, storage and transcriptome.

  4. Azolla domestication towards a biobased economy?

    NARCIS (Netherlands)

    Brouwer, Paul; Bräutigam, A.; Külahoglu, C.; Tazelaar, A.O.E.; Kurz, S.; Nierop, K.G.J.; van der Werf, A.; Weber, A.P.M.; Schlupmann, Henriette

    Due to its phenomenal growth requiring neither nitrogen fertilizer nor arable land and its biomass composition, the mosquito fern Azolla is a candidate crop to yield food, fuels and chemicals sustainably. To advance Azolla domestication, we research its dissemination, storage and transcriptome.

  5. Integrating Social Aspect into Sustainability Assessment of Bio-Based Industries: Towards a Systemic Approach

    OpenAIRE

    Rafiaani, P.; Van Passel, S.; Lebailly, Philippe; Kuppens, T.; Azadi, Hossein; Van Dael, M.

    2016-01-01

    Biobased industries require to be assessed on their positive and negative impacts on sustainable development. However, social factors are usually neglected in the majority of impact assessments of biobased industries: they are mainly focused on environmental performance and (techno)- economic assessments. This review proposes a new systemic approach for assessing and integrating the social dimension into sustainability assessments of biobased industries. First the main methodologies for as...

  6. Bio-Based Polyurethane Containing Isosorbide for Use in Composites and Coatings

    Science.gov (United States)

    2015-04-01

    ARL-TR-7259 ● APR 2015 US Army Research Laboratory Bio-Based Polyurethane Containing Isosorbide for Use in Composites and...copyright notation hereon. ARL-TR-7259 ● APR 2015 US Army Research Laboratory Bio-Based Polyurethane Containing Isosorbide for Use...4. TITLE AND SUBTITLE Bio-Based Polyurethane Containing Isosorbide for Use in Composites and Coatings 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c

  7. 3D Printable Filaments Made of Biobased Polyethylene Biocomposites

    Directory of Open Access Journals (Sweden)

    Daniel Filgueira

    2018-03-01

    Full Text Available Two different series of biobased polyethylene (BioPE were used for the manufacturing of biocomposites, complemented with thermomechanical pulp (TMP fibers. The intrinsic hydrophilic character of the TMP fibers was previously modified by grafting hydrophobic compounds (octyl gallate and lauryl gallate by means of an enzymatic-assisted treatment. BioPE with low melt flow index (MFI yielded filaments with low void fraction and relatively low thickness variation. The water absorption of the biocomposites was remarkably improved when the enzymatically-hydrophobized TMP fibers were used. Importantly, the 3D printing of BioPE was improved by adding 10% and 20% TMP fibers to the composition. Thus, 3D printable biocomposites with low water uptake can be manufactured by using fully biobased materials and environmentally-friendly processes.

  8. Bio-based products from solar energy and carbon dioxide.

    Science.gov (United States)

    Yu, Jian

    2014-01-01

    Producing bio-based products directly from CO₂ and solar energy is a desirable alternative to the conventional biorefining that relies on biomass feedstocks. The production paradigm is based on an artificial photosynthetic system that converts sunlight to electricity and H₂ via water electrolysis. An autotrophic H₂-oxidizing bacterium fixes CO₂ in dark conditions. The assimilated CO₂ is stored in bacterial cells as polyhydroxybutyrate (PHB), from which a range of products can be derived. Compared with natural photosynthesis of a fast-growing cyanobacterium, the artificial photosynthetic system has much higher energy efficiency and productivity of bio-based products. The new technology looks promising because of possible cost reduction in feedstock, equipment, and operation. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Biobased Epoxy Nanocomposites Derived from Lignin-Based Monomers.

    Science.gov (United States)

    Zhao, Shou; Abu-Omar, Mahdi M

    2015-07-13

    Biobased epoxy nanocomposites were synthesized based on 2-methoxy-4-propylphenol (dihydroeugenol, DHE), a molecule that has been obtained from the lignin component of biomass. To increase the content of hydroxyl groups, DHE was o-demethylated using aqueous HBr to yield propylcatechol (DHEO), which was subsequently glycidylated to epoxy monomer. Optimal conditions in terms of yield and epoxy equivalent weight were found to be 60 °C with equal NaOH/phenolic hydroxyl molar ratio. The structural evolution from DHE to cured epoxy was followed by (1)H NMR and Fourier transform infrared spectroscopy. The nano-montmorillonite modified DHEO epoxy exhibited improved storage modulus and thermal stability as determined from dynamic mechanical analysis and thermogravimetric analysis. This study widens the synthesis routes of biobased epoxy thermosets from lignin-based molecules.

  10. Fast-Responding Bio-Based Shape Memory Thermoplastic Polyurethanes.

    Science.gov (United States)

    Petrović, Zoran S; Milić, Jelena; Zhang, Fan; Ilavsky, Jan

    2017-07-14

    Novel fast response shape-memory polyurethanes were prepared from bio-based polyols, diphenyl methane diisocyanate and butane diol for the first time. The bio-based polyester polyols were synthesized from 9-hydroxynonanoic acid, a product obtained by ozonolysis of fatty acids extracted from soy oil and castor oil. The morphology of polyurethanes was investigated by synchrotron ultra-small angle X-ray scattering, which revealed the inter-domain spacing between the hard and soft phases, the degree of phase separation, and the level of intermixing between the hard and soft phases. We also conducted thorough investigations of the thermal, mechanical, and dielectric properties of the polyurethanes, and found that high crystallization rate of the soft segment gives these polyurethanes unique properties suitable for shape-memory applications, such as adjustable transition temperatures, high degree of elastic elongations, and good mechanical strength. These materials are also potentially biodegradable and biocompatible, therefore suitable for biomedical and environmental applications.

  11. Highly Branched Bio-Based Unsaturated Polyesters by Enzymatic Polymerization

    DEFF Research Database (Denmark)

    Nguyen, Hiep Dinh; Löf, David; Hvilsted, Søren

    2016-01-01

    A one-pot, enzyme-catalyzed bulk polymerization method for direct production of highly branched polyesters has been developed as an alternative to currently used industrial procedures. Bio-based feed components in the form of glycerol, pentaerythritol, azelaic acid, and tall oil fatty acid (TOFA)...... stability, very high water contact angles of up to 141° and a glass transition temperature that could be controlled through the feed composition....

  12. Processing and characterization of bio-based composites

    Science.gov (United States)

    Lu, Hong

    Much research has focused on bio-based composites as a potential material to replace petroleum-based plastics. Considering the high price of Polyhydroxyalkanoates (PHAs), PHA/ Distiller's Dried Grains with Solubles (DDGS) composite is a promising economical and high-performance biodegradable material. In this paper, we discuss the effect of DDGS on PHA composites in balancing cost with material performance. Poly (lactic acid) PLA/DDGS composite is another excellent biodegradable composite, although as a bio-based polymer its degradation time is relatively long. The goal of this research is therefore to accelerate the degradation process for this material. Both bio-based composites were extruded through a twin-screw microcompounder, and the two materials were uniformly mixed. The morphology of the samples was examined using a Scanning Electron Microscope (SEM); thermal stability was determined with a Thermal Gravimetric Analyzer (TGA); other thermal properties were studied using Differential Scanning Calorimetry (DSC) and a Dynamic Mechanical Analyzer (DMA). Viscoelastic properties were also evaluated using a Rheometer.

  13. LPG a clean and efficient motor fuel: regulated and non-regulated emissions of a commercial attractive LPG vehicle

    NARCIS (Netherlands)

    Hollemans, B.H.

    1996-01-01

    Excise and other duties measures in Europe, threaten to affect the low price of LPG as a car fuel. As a result, this less polluting fuel would lose position. For this reason the Netherlands LPG industry commissioned TNO to undertake a study which would clearly demonstrate the advantages of LPG. The

  14. Life cycle risks for human health: a comparison of petroleum versus bio-based production of five bulk organic chemicals.

    Science.gov (United States)

    Roes, Alexander L; Patel, Martin K

    2007-10-01

    This article describes the development and application of a generic approach to the comparative assessment of risks related to the production of organic chemicals by petrochemical processes versus white biotechnology. White biotechnology, also referred to as industrial biotechnology, typically uses bio-based feedstocks instead of the fossil raw materials used in the petrochemical sector. The purpose of this study was to investigate whether the production of chemicals by means of white biotechnology has lower conventional risks than their production by petrochemical processes. Conventional risks are the risks of well-established processes, and not those related to genetically modified microorganisms and plants. Our approach combines classical risk assessment methods (largely based on toxicology), as developed by the life cycle assessment (LCA) community, with statistics on technological disasters, accidents, and work-related illnesses. Moreover, it covers the total process chain for both petrochemical and bio-based products from cradle to grave. The approach was applied to five products: the plastics polytrimethylene terephthalate (PTT), polyhydroxyalkanoates (PHA), polyethylene terephthalate (PET), polyethylene (PE), and ethanol. Our results show that the conventional risks related to the white biotechnology products studied are lower than those of the petrochemical products. However, considering the uncertainties with respect to the ranges of input data, the (incomplete) coverage of emissions by the environmental priority strategies (EPS) 2000 method, and the uncertainties of the assumptions made in this study (i.e., large to very large), the differences in results between bio-based and petrochemical products fall into the uncertainty range. Because of this, future research is necessary to decrease the uncertainties before we can conclude that the conventional risks of biotechnologically produced chemicals are lower than those of fossil-fuel-derived chemicals.

  15. Cryogenic Electric Motor Tested

    Science.gov (United States)

    Brown, Gerald V.

    2004-01-01

    Technology for pollution-free "electric flight" is being evaluated in a number of NASA Glenn Research Center programs. One approach is to drive propulsive fans or propellers with electric motors powered by fuel cells running on hydrogen. For large transport aircraft, conventional electric motors are far too heavy to be feasible. However, since hydrogen fuel would almost surely be carried as liquid, a propulsive electric motor could be cooled to near liquid hydrogen temperature (-423 F) by using the fuel for cooling before it goes to the fuel cells. Motor windings could be either superconducting or high purity normal copper or aluminum. The electrical resistance of pure metals can drop to 1/100th or less of their room-temperature resistance at liquid hydrogen temperature. In either case, super or normal, much higher current density is possible in motor windings. This leads to more compact motors that are projected to produce 20 hp/lb or more in large sizes, in comparison to on the order of 2 hp/lb for large conventional motors. High power density is the major goal. To support cryogenic motor development, we have designed and built in-house a small motor (7-in. outside diameter) for operation in liquid nitrogen.

  16. Bio-based Industries Joint Undertaking: The catalyst for sustainable bio-based economic growth in Europe.

    Science.gov (United States)

    Mengal, Philippe; Wubbolts, Marcel; Zika, Eleni; Ruiz, Ana; Brigitta, Dieter; Pieniadz, Agata; Black, Sarah

    2018-01-25

    This article discusses the preparation, structure and objectives of the Bio-based Industries Joint Undertaking (BBI JU). BBI JU is a public-private partnership (PPP) between the European Commission (EC) and the Bio-based Industries Consortium (BIC), the industry-led private not-for-profit organisation representing the private sectors across the bio-based industries. The model of the public-private partnership has been successful as a new approach to supporting research and innovation and de-risking investment in Europe. The BBI JU became a reality in 2014 and represents the largest industrial and economic cooperation endeavour financially ever undertaken in Europe in the area of industrial biotechnologies. It is considered to be one of the most forward-looking initiatives under Horizon 2020 and demonstrates the circular economy in action. The BBI JU will be the catalyst for this strategy to mobilise actors across Europe including large industry, small and medium-sized enterprises (SMEs), all types of research organisations, networks and universities. It will support regions and in doing so, the European Union Member States and associated countries in the implementation of their bioeconomy strategies. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. The sustainable development of transports: the motors and the fuels; Le developpement durable des transports: quels moteurs, quels carburants?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This panorama 2005 between politicians, industrialists and scientists discussed the following topics: exploration-production activities and markets, refining and petrochemistry, the future world gas market, the petroleum supply and demand, the new petroleum and gas reserves, the today and tomorrow alternative fuels, the biofuels in the world, the hybrid vehicles future, the energy consumption in the transport sector, the road fuels in europe and the increase of diesel fuel, the de-pollution techniques of industrial vehicles. The slides of the interventions are provided. The sheets ''le point sur'' of the year 2005 are also provided. (A.L.B.)

  18. Level Recession Of Emissions Release By Motor-And-Tractor Diesel Engines Through The Application Of Water-Fuel Emulsions

    Science.gov (United States)

    Ivanov, A.; Chikishev, E.

    2017-01-01

    The paper is dedicated to a problem of environmental pollution by emissions of hazardous substances with the exhaust gases of internal combustion engines. It is found that application of water-fuel emulsions yields the best results in diesels where production of a qualitative carburetion is the main problem for the organization of working process. During pilot studies the composition of a water-fuel emulsion with the patent held is developed. The developed composition of a water-fuel emulsion provides its stability within 14-18 months depending on mass content of components in it while stability of emulsions’ analogues makes 8-12 months. The mode of operation of pilot unit is described. Methodology and results of pilot study of operation of diesel engine on a water-fuel emulsion are presented. Cutting time of droplet combustion of a water-fuel emulsion improves combustion efficiency and reduces carbon deposition (varnish) on working surfaces. Partial dismantling of the engine after its operating time during 60 engine hours has shown that there is a removal of a carbon deposition in cylinder-piston group which can be observed visually. It is found that for steady operation of the diesel and ensuring decrease in level of emission of hazardous substances the water-fuel emulsion with water concentration of 18-20% is optimal.

  19. Emulsification as an approach to the introduction of methanol/gasoline blends as a motor fuel in Canada

    Energy Technology Data Exchange (ETDEWEB)

    1982-10-29

    This report summarizes the work on a phase of a program which concentrates on the utilization of methanol-gasoline mixtures in spark-ignition engines. A fuel system having components for a 2.5 liter engine equipped with an oxygen sensor controlled carburetor, described in another report, was further developed. Extended cold start tests were carried out and the maximum amount of methanol that could be tolerated by the fuel system , without imparing engine operation, was 30% methanol in gasoline on a volume basis. The engine was installed in an automobile and road tests were conducted concentrating on cold starts and warm-up, fuel system performance, fuel economy and materials compatibility of components exposed to the methanol-gasoline blend. A second phase separation control system was developed for a 2.1 liter displacement engine equipped with a mechanical fuel injection system. The proportioning and pick-up components for the tank were incorporated in the existing fuel system. Cold start tests were performed and 20% methanol was found to be the upper limit. The engine was installed and the vehicle were road tested. Minor shortcomings identified during road testing were corrected. Overall performance and driveability of both vehicles were found acceptable. However, testing under low ambient temperature conditions remains to be done. 2 refs., 37 figs., 8 tabs.

  20. Fostering the Bioeconomic Revolution in Biobased Products and Bioenergy: An Environmental Approach

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2001-01-01

    This document is a product of the Biomass Research and Development Board and presents a high-level summary of the emerging national strategy for biobased products and bioenergy. It provides the first integrated approach to policies and procedures that will promote R&D and demonstration leading to accelerated production of biobased products and bioenergy.

  1. Sulfuric acid as a catalyst for ring-opening of biobased bis-epoxides

    Science.gov (United States)

    Vegetable oils can be relatively and easily transformed into bio-based epoxides. Because of this, the acid-catalyzed epoxide ring-opening has been explored for the preparation of bio-based lubricants and polymers. Detailed model studies are carried out only with mono-epoxide made from methyl oleate,...

  2. REACHing out to the bio-based economy : Perspectives and challenges of EU chemicals legislation

    NARCIS (Netherlands)

    Luit RJ; Waaijers-van der Loop SL; Heugens EHW; ICH; VSP

    2017-01-01

    The Dutch National Institute for Public Health and the Environment (hereafter: RIVM) recently investigated how the bio-based economy, more specifically the bio-based chemistry sector, relates to the EU REACH Regulation on chemicals. From this investigation, RIVM learnt that REACH may actually be an

  3. RIVM ZZS-2-BIO project : the biobased replacement potential of hazardous substances

    NARCIS (Netherlands)

    Es, van D.S.

    2014-01-01

    A quick scan of the ZZS (zeer zorgwekkende stoffen) list of 371 substances of very high concern shows that there is significant potential in biobased replacement of part of the list. It is shown that in many cases easily implementable biobased alternatives are already available or in advanced stages

  4. Novel strategies for biobased feedstock utilization : Efficiency, optimization and production of a platform chemical

    NARCIS (Netherlands)

    Koopman, F.W.

    2010-01-01

    Due to evident environmental, economical and political reasons, it is becoming inevitable to shift society’s dependence away from fossil towards renewable, bio-based resources. However, for efficient implementation of biobased resources, cost effectiveness is key. In this thesis, different

  5. Advanced biomass science and technology for bio-based products: proceedings

    Science.gov (United States)

    Chung Hse; Zehui Jiang; Mon-Lin Kuo

    2009-01-01

    This book was developed from the proceedings of the Advanced Biomass Science and Technology for Bio-Based Products Symposium held in Beijing, China, May 23-25, 2007. The symposium was designed to provide a forum for researchers, producers, and consumers of biomass and bio-based products; to exchange information and ideas; and to stimulate new research and...

  6. Bio-based composite pedestrian bridge. Part 2: materials and production process

    NARCIS (Netherlands)

    Lepelaar, Mark; Hoogendoorn, Alwin; Blok, Rijk; Teuffel, Patrick; Kawaguchi, K.; Ohsaki, M.; Takeuchi, T.

    2016-01-01

    The Bio-based composite bridge is a 3TU project which aims to design and realize a 14m span pedestrian bridge made from fibre-reinforced polymers (FRP) and which is introduced in part 1 of this paper. Part 2 will focus on various studies about bio-based materials, which are suitable for structural

  7. Black Liquor Gasification with Motor Fuel Production - BLGMF II - A techno-economic feasibility study on catalytic Fischer-Tropsch synthesis for synthetic diesel production in comparison with methanol and DME as transport fuels

    Energy Technology Data Exchange (ETDEWEB)

    Ekbom, Tomas; Berglin, Niklas; Loegdberg, Sara [Nykomb Synergetics AB, Stockholm (Sweden)

    2005-06-15

    The present project presents additional results to the former BLGMF project, which investigate Black Liquor Gasification with Motor Fuels (BLGMF) production. The objectives were to investigate, based on the KAM 2 program Ecocyclic Pulp Mill (2,000 ADt/day of pulp) the feasibility of synthetic fuels production. Specifically the route to Fischer-Tropsch diesel fuels is investigated as comparison to earlier work on methanol/DME. As modern kraft pulp mills have a surplus of energy, they could become key suppliers of renewable fuels. It is thus of great interest to convert the spent cooking product 'black liquor' to an energy carrier of high value. The resulting biomass-to-fuel energy efficiency when only biomass is used as an external energy source was 43% for FTD or 65% for FT products compared with 66% for methanol and 67% for DME. The FTD calculation is considerably more complicated and based on assumptions, therefore the uncertainty is higher. Would the diesel be taken out with a T95% of 320 deg C the FTD efficiency would be 45%. FT synthesis also opens up a possibility to produce e.g. lube oils from waxes produced. The total net FT-products output equals 4115 barrels/day. The FTD production cost is calculated as the energy share of the total production cost and assumes an offset of naphtha covering its own costs, where it is essential that it finds a market. Assuming same petrol (methanol) and diesel (DME, FTD) costs for the consumer the payback time were 2.6, 2.9 and 3.4 years with an IRR of 40%, 45% and 30%, respectively. In conclusion, there are necessary resources and potential for large-scale methanol (or DME, FTD) production and substantial economic incentive for making plant investments and achieving competitive product revenues.

  8. Potential food applications of biobased materials. An EU- concerted action project

    DEFF Research Database (Denmark)

    Haugaard, V.K.; Udsen, A.M.; Mortensen, G.

    2001-01-01

    and coatings to food but novel commercial applications of these are scarce. Based on information currently available on the properties of biobased packaging materials the study identified products in the fresh meat, dairy, ready meal, beverage, fruit and vegetable, snack, frozen food and dry food categories......The objective of the study was to ascertain the state of the art with regard to the applicability of biobased packaging materials to foods and to identify potential food applications for biobased materials. The study revealed relatively few examples of biobased materials used as primary, secondary...... or tertiary packaging materials for foods. This is due to the fact that published investigations on the use of biobased materials are still scarce, and results obtained remain unpublished because of commercial pressures. The scientific literature contains numerous reports on applications of edible films...

  9. 40 CFR 80.607 - What are the requirements for obtaining an exemption for diesel fuel or ECA marine fuel used for...

    Science.gov (United States)

    2010-07-01

    ... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... fuel will be segregated from motor vehicle diesel fuel, NRLM diesel fuel, or ECA marine fuel, as... documents associated with research and development motor vehicle diesel fuel must comply with requirements...

  10. Superamphiphobic overhang structured coating on a biobased material

    Energy Technology Data Exchange (ETDEWEB)

    Tuominen, Mikko, E-mail: mikko.tuominen@sp.se [SP Technical Research Institute of Sweden—Chemistry, Materials and Surfaces, Box 5607, SE-114 86 Stockholm (Sweden); Teisala, Hannu [Tampere University of Technology, Paper Converting and Packaging Technology, Department of Materials Science, P.O. Box 589, FI-33101 Tampere (Finland); Haapanen, Janne; Mäkelä, Jyrki M. [Tampere University of Technology, Aerosol Physics Laboratory, Department of Physics, P.O. Box 692, FI-33101 Tampere (Finland); Honkanen, Mari; Vippola, Minnamari [Tampere University of Technology, Material Characterization, Department of Materials Science, P.O. Box 589, FI-33101 Tampere (Finland); Bardage, Stig [SP Technical Research Institute of Sweden, Sustainable Built Environment, Biobased Materials and Products, Box 5609, SE-114 86 Stockholm (Sweden); Wålinder, Magnus E.P. [KTH Royal Institute of Technology, Department of Civil and Architectural Engineering, Building Materials, SE-100 44 Stockholm (Sweden); Swerin, Agne [SP Technical Research Institute of Sweden—Chemistry, Materials and Surfaces, Box 5607, SE-114 86 Stockholm (Sweden); KTH Royal Institute of Technology, Department of Chemistry, Surface and Corrosion Science, SE-100 44 Stockholm (Sweden)

    2016-12-15

    Highlights: • A superamphiphobic coating on a wood shows extreme liquid repellence against water, ethylene glycol, diiodomethane and olive oil. • The coated wood sample can have the required geometrical homogeneity to establish superamphiphobic properties. • To our knowledge, this is the first time superamphiphobicity based on overhang structures has been shown for a renewable bio-based material.A superamphiphobic coating on a wood shows extreme liquid repellence with static contact angles (CA) greater than 150° and roll-off angles less than 10° against water, ethylene glycol, diiodomethane and olive oil. - Abstract: A superamphiphobic coating on a biobased material shows extreme liquid repellency with static contact angles (CA) greater than 150° and roll-off angles less than 10° against water, ethylene glycol, diiodomethane and olive oil, and a CA for hexadecane greater than 130°. The coating consisting of titania nanoparticles deposited by liquid flame spray (LFS) and hydrophobized using plasma-polymerized perfluorohexane was applied to a birch hardwood. Scanning electron microscopy (SEM) imaging after sample preparation by UV laser ablation of coated areas revealed that capped structures were formed and this, together with the geometrically homogeneous wood structure, fulfilled the criteria for overhang structures to occur. The coating showed high hydrophobic durability by still being non-wetted after 500 000 water drop impacts, and this is discussed in relation to geometrical factors and wetting forces. The coating was semi-transparent with no significant coloration. A self-cleaning effect was demonstrated with both water and oil droplets. A self-cleanable, durable and highly transparent superamphiphobic coating based on a capped overhang structure has a great potential for commercial feasibility in a variety of applications, here exemplified for a biobased material.

  11. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials

    OpenAIRE

    Delucchi, Mark

    2003-01-01

    This report documents changes to the methods and data in a recently revised version of the greenhouse-gas emissions model originally documented in Emissions of Greenhouse Gases from the Use of Transportation Fuels and Electricity, ANL/ESD/TM-22, Volumes 1 and 2, Center for Transportation Research, Argonne National Laboratory, Argonne (ANL), Illinois (DeLuchi, 1991, 1993). The revised Lifecycle Emissions Model (LEM) calculates energy use, air-pollutant emissions, and CO2-equivalent emissions o...

  12. Editorial: from plant biotechnology to bio-based products.

    Science.gov (United States)

    Stöger, Eva

    2013-10-01

    From plant biotechnology to bio-based products - this Special Issue of Biotechnology Journal is dedicated to plant biotechnology and is edited by Prof. Eva Stöger (University of Natural Resources and Life Sciences, Vienna, Austria). The Special Issue covers a wide range of topics in plant biotechnology, including metabolic engineering of biosynthesis pathways in plants; taking advantage of the scalability of the plant system for the production of innovative materials; as well as the regulatory challenges and society acceptance of plant biotechnology. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. 40 CFR 79.32 - Motor vehicle gasoline.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false Motor vehicle gasoline. 79.32 Section...) REGISTRATION OF FUELS AND FUEL ADDITIVES Designation of Fuels and Additives § 79.32 Motor vehicle gasoline. (a) The following fuels commonly or commercially known or sold as motor vehicle gasoline are hereby...

  14. Optimisation of the process of fuel gas production for fuel cells in motor vehicles; Verfahrenstechnische Optimierung der Brenngaserzeugung fuer Brennstoffzellen in Kraftfahrzeugen

    Energy Technology Data Exchange (ETDEWEB)

    Colsman, G

    1995-10-01

    There are advanced development programs and demonstration projects worldwide concerning the use of Proton Exchange Membrane Fuel Cells (PEMFC) in passenger cars. The on-board production of a hydrogen-rich fuel gas in particular requires research and development. Based on a comparison of different energy carriers and hydrogen production processes, the methanol steam-reforming system is optimized with respect to criteria such as power density and fuel gas quality. The specific hydrogen production is thereby raised to 10 m{sup 3} (STP) per hour and litre of catalyst at 99.5% methanol conversion rate and 280 C reformer wall temperature. Due to the fact, that the maximum CO concentration in the fuel gas, which is tolerable by the PEMFC with platinum catalyst, is 10 ppm, a separate gas cleaning is necessary after the steam reforming process. Different gas treatment processes are discussed and investigated theoretically as well as experimentally. Pore-free metal membranes allow the separation of ultra pure (>99.9999 vol.-%) hydrogen from the reformer gas while the technical criteria for the use in passenger cars are fulfilled. The investigations are completed by mathematical models of the optimized methanol reformer as well as the gas separation by membranes. The results of this work concerning the optimization of the fuel processing from methanol have made possible the building and testing of a fuel gas production unit on a passenger car scale. Volume and weight of the total unit allow already today the installation in a vehicle without any restrictions. (orig.) [Deutsch] Der Einsatz von PEMFC (Brennstoffzellen mit Protonenaustauschmembran) in Kraftfahrzeugen wird weltweit erforscht und in zahlreichen Prototypen demonstriert. Insbesondere auf dem Gebiet der Erzeugung eines wasserstoffreichen Brenngases im Kraftfahrzeug besteht ein erheblicher Entwicklungsbedarf. Auf der Basis eines Vergleichs verschiedener Energietraeger und Verfahren der Wasserstoffgewinnung wird das

  15. 40 CFR 80.501 - What fuel is subject to the provisions of this subpart?

    Science.gov (United States)

    2010-07-01

    ... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel...) Motor vehicle diesel fuel. (2) Nonroad, locomotive, or marine diesel fuel. (3) Diesel fuel additives. (4... for use as fuel in diesel motor vehicles or nonroad diesel engines or is blended with diesel fuel for...

  16. Center for BioBased Binders and Pollution Reduction Technology

    Energy Technology Data Exchange (ETDEWEB)

    Thiel, Jerry [Univ. of Northern Iowa, Cedar Falls, IA (United States)

    2013-07-01

    Funding will support the continuation of the Center for Advanced Bio-based Binders and Pollution Reduction Technology Center (CABB) in the development of bio-based polymers and emission reduction technologies for the metal casting industry. Since the formation of the center several new polymers based on agricultural materials have been developed. These new materials have show decreases in hazardous air pollutants, phenol and formaldehyde as much as 50 to 80% respectively. The polymers termed bio-polymers show a great potential to utilize current renewable agricultural resources to replace petroleum based products and reduce our dependence on importing of foreign oil. The agricultural technology has shown drastic reductions in the emission of hazardous air pollutants and volatile organic compounds and requires further development to maintain competitive costs and productivity. The project will also research new and improved inorganic binders that promise to eliminate hazardous emissions from foundry casting operations and allow for the beneficial reuse of the materials and avoiding the burdening of overcrowded landfills.

  17. Bio-based polyurethane foams toward applications beyond thermal insulation

    International Nuclear Information System (INIS)

    Gama, Nuno V.; Soares, Belinda; Freire, Carmen S.R.; Silva, Rui; Neto, Carlos P.; Barros-Timmons, Ana; Ferreira, Artur

    2015-01-01

    Highlights: • Coffee grounds wastes were successfully liquefied yielding a bio-based polyol. • Coffee grounds derived foams formulations were optimized by tuning reagents’ contents. • The viscoelastic properties of these foams are promising to expand their applications. - Abstract: In this work the preparation of viscoelastic bio-based polyurethane foams (PUFs) using polyols obtained via acid liquefaction of coffee grounds wastes has been optimized. In a first stage, the effect of different ratios of isocyanate content to hydroxyl number (0.6, 0.7 and 0.8) and of three distinct percentages of catalyst (3%, 5% and 7%) on the extent of the polymerization reaction was studied by infrared spectroscopy. Next, different percentages of surfactant (14%, 16% and 18%) and blowing agent (12%, 14% and 16%) were used to assess their effect on the density, thermal conductivity and mechanical properties of the foams, including their recovery time. The mechanical properties of the ensuing foams proved to be very interesting due to their viscoelastic behavior. PUFs were also characterized by scanning electron microscopy (SEM) revealing a typical cellular structure and by thermogravimetric analysis (TGA) which proved that these materials are thermally stable up to 190 °C. These results suggest other potential applications for these materials beyond heat insulation in areas where damping properties can be an added value

  18. Processing biobased polymers using plasticizers: Numerical simulations versus experiments

    Science.gov (United States)

    Desplentere, Frederik; Cardon, Ludwig; Six, Wim; Erkoç, Mustafa

    2016-03-01

    In polymer processing, the use of biobased products shows lots of possibilities. Considering biobased materials, biodegradability is in most cases the most important issue. Next to this, bio based materials aimed at durable applications, are gaining interest. Within this research, the influence of plasticizers on the processing of the bio based material is investigated. This work is done for an extrusion grade of PLA, Natureworks PLA 2003D. Extrusion through a slit die equipped with pressure sensors is used to compare the experimental pressure values to numerical simulation results. Additional experimental data (temperature and pressure data along the extrusion screw and die are recorded) is generated on a dr. Collin Lab extruder producing a 25mm diameter tube. All these experimental data is used to indicate the appropriate functioning of the numerical simulation tool Virtual Extrusion Laboratory 6.7 for the simulation of both the industrial available extrusion grade PLA and the compound in which 15% of plasticizer is added. Adding the applied plasticizer, resulted in a 40% lower pressure drop over the extrusion die. The combination of different experiments allowed to fit the numerical simulation results closely to the experimental values. Based on this experience, it is shown that numerical simulations also can be used for modified bio based materials if appropriate material and process data are taken into account.

  19. Bio-Based Adhesives and Evaluation for Wood Composites Application

    Directory of Open Access Journals (Sweden)

    Fatemeh Ferdosian

    2017-02-01

    Full Text Available There has been a rapid growth in research and innovation of bio-based adhesives in the engineered wood product industry. This article reviews the recent research published over the last few decades on the synthesis of bio-adhesives derived from such renewable resources as lignin, starch, and plant proteins. The chemical structure of these biopolymers is described and discussed to highlight the active functional groups that are used in the synthesis of bio-adhesives. The potentials and drawbacks of each biomass are then discussed in detail; some methods have been suggested to modify their chemical structures and to improve their properties including water resistance and bonding strength for their ultimate application as wood adhesives. Moreover, this article includes discussion of techniques commonly used for evaluating the petroleum-based wood adhesives in terms of mechanical properties and penetration behavior, which are expected to be more widely applied to bio-based wood adhesives to better evaluate their prospect for wood composites application.

  20. 40 CFR 80.510 - What are the standards and marker requirements for NRLM diesel fuel and ECA marine fuel?

    Science.gov (United States)

    2010-07-01

    ... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel General... of marker solvent yellow 124. (2) All motor vehicle and NRLM diesel fuel shall be free of solvent... yellow 124 shall be considered motor vehicle diesel fuel or NRLM diesel fuel, as appropriate. (5) Any...

  1. Motor fuels made by direct liquefaction of coal, peat and biomass. Drivmedel genom direktfoervaetskning av kol, torv och biomassa

    Energy Technology Data Exchange (ETDEWEB)

    Granath, L; Karlsson, G; Karlsson, G; Nilsson, T

    1981-01-01

    The Department of Chemical Technology at the Royal Institute of Technology has completed a system study concerning direct liquefaction of peat and biomass to produce transportation fuel. A comprehensive survey of coal liquefaction is included. Gasoline produced in Sweden from direct liquefaction of imported coal may compete with regular gasoline at the earliest around 1985. Biomass can become a competitive alternative to black coal at the beginning of the 21st century. Methanol can be produced from wood with a higher efficiency than the transportation fuels which are produced by direct liquefaction. The peat is not good source for liquefaction as wood chips. A continuously working liquefaction plant designed also for peat among other substances is under construction at the Royal Institute of Technology, Stockholm.

  2. The potential of the aquatic water fern Azolla within a biobased economy

    Science.gov (United States)

    Nierop, Klaas G. J.; Jongerius, Anna L.; Bijl, Peter K.; Bruijnincx, Pieter C. A.; Klein Gebbink, Robertus J. M.; Reichart, Gert-Jan

    2014-05-01

    Azolla is a free-floating freshwater fern capable of fixing atmospheric carbon dioxide and nitrogen, the latter of which through its symbiosis with the cyanobacteria Anabaena azollae. It is currently ranked among the fastest growing plants on Earth and occurs in both tropical and temperate freshwater ecosystems. Therefore, it is non-directly competitive with food crops. In addition, Azolla does not require inorganic fertilizers, which makes it a potential and unique source of biomass for the sustainable production of fuels and chemicals that are currently derived from fossil (fuel) sources. The biochemical composition of Azolla allows the production of biofuel or biobased chemicals that are of interest to the chemical industry. Of Azolla, two extractable groups of compounds are of particular interest, i.e. the polyphenols (condensed tannins and ester-bound caffeic acid) and the lipids. The antioxidant property of polyphenols and their application to the treatment of cancer, diabetes and cardiovascular diseases has further contributed to the growth of the polyphenol market. In addition, they can be chemically transformed into aromatic platform and specialty chemicals. The composition of the lipid fraction of Azolla is characterized by highly specific compounds consisting of C26-C36 carbon chains all bearing a ω20-hydroxy group. Such compounds produce an oil fraction upon hydrous pyrolysis, or, alternatively, are well suited to be converted to e.g. various specialty chemicals that are hardly available from both natural sources. Indeed, upon chemical conversion these lipids may yield components for fuels, plastics, cosmetics, and lubricants. Another group of interesting compounds within the lipid group are the polyunsaturated fatty acids (PUFAs). The demand for PUFAs has witnessed a significant increase over the last three years, particularly due to their benefits as cholesterol lowering agents. Here we will present some of the thermal and chemical conversions of the

  3. Feasibility and Environmental Implications of Using Waste Motor Oil as Alternative Supplemental Fuel in Contingency Prime Power Generation

    Science.gov (United States)

    2017-03-23

    50 x Figure 19 - Baldwin Fuel/ Water Separator and Replacement Cartridge Filters ............... 51 Figure 20 - Waste Drained from...15ppm for ULSDa 20,000ppm Catalyst equipped engines will be damaged Sodium Content 0.5ppm maximum 10ppm Water & Sediment Not to exceed 0.05...for further sample collection parameters and number of samples collected for each type. To prevent contamination from sediment , water , or antifreeze

  4. 40 CFR 80.583 - What alternative sampling and testing requirements apply to importers who transport motor vehicle...

    Science.gov (United States)

    2010-07-01

    ... requirements apply to importers who transport motor vehicle diesel fuel, NRLM diesel fuel, or ECA marine fuel... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel... alternative sampling and testing requirements apply to importers who transport motor vehicle diesel fuel, NRLM...

  5. Capability of a SOFC-APU to optimise the fuel consumption of motor vehicles; Potenzial einer SOFC-APU bei der Verbrauchsoptimierung von Kraftfahrzeugen

    Energy Technology Data Exchange (ETDEWEB)

    Diegelmann, Christian B.

    2008-04-28

    While the energy system motor vehicle is analysed in this work different application possibilities of a SOFC-Auxiliary Power Unit for reducing the fuel consumption are identified. Apart from the pure electric power supply the APU can support functions like the engine-stop automatism or electric driving (hybrid vehicle). In addition the SOFC-APU generates waste heat at a high temperature level. The waste heat can be used for heating the passenger cabin or for preheating the combustion engine. Several methods are used for evaluating the conservation potentials. A simple estimate of the fuel consumption by means of medium efficiency and power already suffices to identify and evaluate the major impacts. The conservation potential of a SOFC-APU mainly depends on three factors, the start-up consumption of the APU, the operating period and the required electric power. A cold APU must first be heated-up to an operational temperature between 700 and 800 degrees Celsius. The heat-up process requires energy resulting in an excess consumption first. This excess consumption will only be compensated by the high efficiency of the SOFC-APU after a longer operating period. The operating period strongly depends on the electric power. In case of higher electric power the APU achieves a higher conservation rate. An APU is particularly interesting in standard applications with high energy demand. The APU avoids an operation of the combustion engine in the extreme underload range. In case of an air-conditioning at idling speed lasting for 30 minutes a fuel conservation of approx. 36% can be achieved including the start-up consumption. Conservation potentials in fuel consumption can only be achieved in the driving mode if the APU is operational and in case of a longer operating period. The difference in consumption compared to vehicles without APU was determined at vehicles with different basic operating strategies (current vehicle, vehicle with engine-stop automatism, vehicle with

  6. Active load current sharing in fuel cell and battery fed DC motor drive for electric vehicle application

    International Nuclear Information System (INIS)

    Pany, Premananda; Singh, R.K.; Tripathi, R.K.

    2016-01-01

    Highlights: • Load current sharing in FC and battery fed dc drive. • Active current sharing control using LabVIEW. • Detail hardware implementation. • Controller performance is verified through MATLAB simulation and experimental results. - Abstract: In order to reduce the stress on fuel cell based hybrid source fed electric drive system the controller design is made through active current sharing (ACS) technique. The effectiveness of the proposed ACS technique is tested on a dc drive system fed from fuel cell and battery energy sources which enables both load current sharing and source power management. High efficiency and reliability of the hybrid system can be achieved by proper energy conversion and management of power to meet the load demand in terms of required voltage and current. To overcome the slow dynamics feature of FC, a battery bank of adequate power capacity has to be incorporated as FC voltage drops heavily during fast load demand. The controller allows fuel cell to operate in normal load region and draw the excess power from battery. In order to demonstrate the performance of the drive using ACS control strategy different modes of operation of the hybrid source with the static and dynamic behavior of the control system is verified through simulation and experimental results. This control scheme is implemented digitally in LabVIEW with PCI 6251 DAQ I/O interface card. The efficacy of the controller performance is demonstrated in system changing condition supplemented by experimental validation.

  7. Development of PLA hybrid yarns for biobased self-reinforced polymer composites

    Science.gov (United States)

    Köhler, T.; Gries, T.; Seide, G.

    2017-10-01

    Lightweight materials are a necessity in various industries. Lightweight design is in the key interest of the mobility sector, e.g. the automotive and aerospace industry. This trend applies also for the consumer industries, e.g. sporting goods. In addition, the worldwide demand for replacing fossil-based materials has led to a significant growth of bioplastics. Due to their low mechanical performance and durability, their use is still limited. Therefore, it is necessary to develop biobased, sustainable polymeric materials with high stiffness, high impact and high durability without impairing recyclability at a similar price level of non-biobased solutions. Biobased self-reinforced polymer composites offer these unique properties.

  8. Recent developments and future prospects on bio-based polyesters derived from renewable resources: A review.

    Science.gov (United States)

    Zia, Khalid Mahmood; Noreen, Aqdas; Zuber, Mohammad; Tabasum, Shazia; Mujahid, Mohammad

    2016-01-01

    A significantly growing interest is to design a new strategy for development of bio-polyesters from renewable resources due to limited fossil fuel reserves, rise of petrochemicals price and emission of green house gasses. Therefore, this review aims to present an overview on synthesis of biocompatible, biodegradable and cost effective polyesters from biomass and their prospective in different fields including packaging, coating, tissue engineering, drug delivery system and many more. Isosorbide, 2,4:3,5-di-O-methylene-d-mannitol, bicyclic diacetalyzed galactaric acid, 2,5-furandicarboxylic acid, citric, 2,3-O-methylene l-threitol, dimethyl 2,3-O-methylene l-threarate, betulin, dihydrocarvone, decalactone, pimaric acid, ricinoleic acid and sebacic acid, are some important monomers derived from biomass which are used for bio-based polyester manufacturing, consequently, replacing the petrochemical based polyesters. The last part of this review highlights some recent advances in polyester blends and composites in order to improve their properties for exceptional biomedical applications i.e. skin tissue engineering, guided bone regeneration, bone healing process, wound healing and wound acceleration. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Method for production of fuel oils and diesel motor oils free of sediments and with unlimited miscibility

    Energy Technology Data Exchange (ETDEWEB)

    1942-01-13

    A method is described for the production of fuel and diesel oils free of sediments and with unlimited miscibility by their recovery from substances poor in hydrogen, such as tars of fossil carbon, from lignite, from peat, from schist oils, from wood, or tar oils of corresponding extracts, poorly hydrogenated carbohydrates and the like, characterized by the fact that these substances are being subjected without mixing with selective solvents to a chemical purification and then immediately subjected to a redistillation and the obtained distillates being cut with hydrogen-rich oils to obtain normal diesel oils.

  10. Resource recovery from bio-based production processes: a future necessity?

    DEFF Research Database (Denmark)

    Mansouri, Seyed Soheil; S.B.A. Udugama, Isuru; Cignitti, Stefano

    2017-01-01

    The promise of transforming waste streams with small economic value into valuable products makes resource recovery technologies in bio-based production processes an attractive proposition. However, the use of resource recovery technologies in industrial applications is still minimal, despite its...... technologies to industrial bio-based production processes. The role and importance of economics, technology readiness and socio-environmental impacts of resource recovery in successfully implementing resource recovery technologies in industrial bio-based production processes is also discussed. Finally, based...... wide use in closely related processes such as dairy production. In this paper, a perspective on the role of resource recovery in bio-based production processes is provided through reviewing the past practice and identifying the benefits, opportunities and challenges of introducing resource recovery...

  11. The biobased economy: biofuels, materials and chemicals in the post-oil era

    National Research Council Canada - National Science Library

    Langeveld, Hans; Meeusen, Marieke; Sanders, Johan

    2010-01-01

    .... Starting with a state-of-the-art overview of major biobased technologies, including biorefinery and technologies for the production of biofuels, biogas, biomass feedstocks for chemistry and bio...

  12. Recirculation: A New Concept to Drive Innovation in Sustainable Product Design for Bio-Based Products.

    Science.gov (United States)

    Sherwood, James; Clark, James H; Farmer, Thomas J; Herrero-Davila, Lorenzo; Moity, Laurianne

    2016-12-29

    Bio-based products are made from renewable materials, offering a promising basis for the production of sustainable chemicals, materials, and more complex articles. However, biomass is not a limitless resource or one without environmental and social impacts. Therefore, while it is important to use biomass and grow a bio-based economy, displacing the unsustainable petroleum basis of energy and chemical production, any resource must be used effectively to reduce waste. Standards have been developed to support the bio-based product market in order to achieve this aim. However, the design of bio-based products has not received the same level of attention. Reported here are the first steps towards the development of a framework of understanding which connects product design to resource efficiency. Research and development scientists and engineers are encouraged to think beyond simple functionality and associate value to the potential of materials in their primary use and beyond.

  13. Biodegradability of biobased polymeric materials in natural environments: Structures and Chemistry

    CSIR Research Space (South Africa)

    Muniyasamy, S

    2017-03-01

    Full Text Available The development of biobased polymer materials from renewable resources meets the concept of sustainability, offering the potential of renewability, biodegradation, and a path away from the problems associated with plastic derived from nonrenewable...

  14. Biobased alkylphenols from lignins via a two-step pyrolysis - Hydrodeoxygenation approach

    NARCIS (Netherlands)

    de Wild, P. J.; Huijgen, W.J.J.; Kloekhorst, A.; Chowdari, R. K.; Heeres, H. J.

    Five technical lignins (three organosolv, Kraft and soda lignin) were depolymerised to produce monomeric biobased aromatics, particularly alkylphenols, by a new two-stage thermochemical approach consisting of dedicated pyrolysis followed by catalytic hydrodeoxygenation (HDO) of the resulting

  15. A study of the use of bio-based technologies (lubricant and grease) in rail applications.

    Science.gov (United States)

    2014-05-01

    The objective of the project was to study the efficacy of using bio-based lubricant and grease technologies in railroad applications : (locomotives and maintenance of way equipment). Several commercially available rail curve greases were identified a...

  16. Fully Biobased Unsaturated Aliphatic Polyesters from Renewable Resources : Enzymatic Synthesis, Characterization, and Properties

    NARCIS (Netherlands)

    Jiang, Yi; Alberda van Ekenstein, Gerhard; Woortman, Albert J. J.; Loos, Katja

    2014-01-01

    Fully biobased saturated and unsaturated aliphatic polyesters and oligoesters are successfully prepared by Candida antarctica lipase B (CALB)-catalyzed polycondensations of succinate, itaconate, and 1,4-butanediol. The effects of monomer substrates and polymerization methods on enzymatic

  17. Bio-based alkyds by direct enzymatic bulk polymerization

    DEFF Research Database (Denmark)

    Nguyen, Hiep Dinh

    to a corresponding classical reference. In a further development of the system, it has been found possible to use the esters of pentaerythritol and stearic acid in combination with the penta-aze derivative for the preparation of pseudo alkyds containing only pentaerythritol as polyol with high degree of branching....... Bio-based alkyds prepared from a combination of glycerol, and tall oil fatty acids, and azelaic acid by enzymatic polymerization show improved hydrophobicity and lower glass transition temperatures compared to an alkyd prepared from the same raw materials by a classical boiling method. The enzymatic...... of pentaerythritol derivatized with azelaic acid (or penta-aze) was examined and tested for the production of more branched alkyd systems. A photostability test validated the concept, and the method also resulted in alkyds with improved hydrophobicity and lower glass transition temperatures compared...

  18. Consumer acceptance of fresh blueberries in bio-based packages.

    Science.gov (United States)

    Almenar, Eva; Samsudin, Hayati; Auras, Rafael; Harte, Janice

    2010-05-01

    Instrumental analyses have shown that non-vented bio-based containers made from poly(lactic acid) (PLA) have the capability to enhance blueberry shelf life as compared with commercial vented petroleum-based clamshell containers. However, consumer preference has not been explored so far. In this study, two sensory evaluations, triangle and paired preference tests, were performed after storing fruit in both containers at 3 and 10 degrees C for 7 and 14 days. In addition, physicochemical analyses were performed after each tasting in order to correlate instrumental findings with consumer preference. The results of the triangle test showed the capability of the consumer to differentiate (P consumer preference for flavour, texture, external appearance and overall quality (P Consumers distinguished between blueberries from different packages and preferred those packaged in the PLA containers. The instrumental analyses showed that the usable life of the berries was extended in the PLA containers. A correlation between consumer preference and instrumental evaluations was found.

  19. Bio-based C-3 Platform Chemical: Biotechnological Production and -Conversion of 3-Hydroxypropionaldehyde

    OpenAIRE

    Rezaei, Roya

    2013-01-01

    Demands for efficient, greener, economical and sustainable production of chemicals, materials and energy have led to development of industrial biotechnology as a key technology area to provide such products from bio-based raw materials from agricultural-, forestry- and related industrial residues and by-products. For the bio-based industry, it is essential to develop a number of building blocks or platform chemicals for C2-C6 chemicals and even aromatic chemicals. 3-hydroxypropionaldehyde (3H...

  20. SET-LRP of the Hydrophobic Biobased Menthyl Acrylate.

    Science.gov (United States)

    Bensabeh, Nabil; Ronda, Joan C; Galià, Marina; Cádiz, Virginia; Lligadas, Gerard; Percec, Virgil

    2018-04-09

    Cu(0) wire-catalyzed single electron transfer-living radical polymerization (SET-LRP) of (-)-menthyl acrylate, a biobased hydrophobic monomer, was investigated at 25 °C in ethanol, isopropanol, ethyl lactate, 2,2,2-trifluoroethanol (TFE), and 2,2,3,3-tetrafluoropropanol (TFP). All solvents are known to promote, in the presence of N ligands, the mechanistically required self-regulated disproportionation of Cu(I)Br into Cu(0) and Cu(II)Br 2 . Both fluorinated alcohols brought out their characteristics of universal SET-LRP solvents and showed the proper polarity balance to mediate an efficient polymerization of this bulky and hydrophobic monomer. Together with the secondary alkyl halide initiator, methyl 2-bromopropionate (MBP), and the tris(2-dimethylaminoethyl)amine (Me 6 -TREN) ligand, TFE and TPF mediated an efficient SET-LRP of MnA at room temperature that proceeds through a self-generated biphasic system. The results presented here demonstrate that Cu(0) wire-catalyzed SET-LRP can be used to target polyMnA with different block lengths and narrow molecular weight distribution at room temperature. Indeed, the use of a combination of techniques that include GPC, 1 H NMR, MALDI-TOF MS performed before and after thioetherification of bromine terminus via "thio-bromo" click chemistry, and in situ reinitiation copolymerization experiments supports the near perfect chain end functionality of the synthesized biobased hydrophobic polymers. These results expand the possibilities of SET-LRP into the area of renewable resources where hydrophobic compounds are widespread.

  1. Minimize constraints for a biobased economy. Progress report. Version 1.0; Wegnemen van belemmeringen in de biobased economy. Voortgangsrapportage. Versie 1.0

    Energy Technology Data Exchange (ETDEWEB)

    Bex, P.M.H.H.; Blank, R.E.

    2013-04-15

    In the study 'Conflicting interests in the biobased economy (BBE in Dutch)), an overview is given of constraints, experienced by entrepreneurs, that limit innovations and investments in the BBE and thus hinder the transition towards a biobased economy. In a first inventory 69 constraints were identified. This report summarizes the progress of the BBE Program, and gives an overview of new constraints. The solutions for the constraints can be found at www.biobasedeconomy.nl [Dutch] In het onderzoek 'Botsende belangen in de biobased economy' (BBE) zijn de belemmeringen van ondernemers in kaart gebracht die innovaties en investeringen in de BBE beperken en daarmee de transitie van de BBE in de weg staan. In een eerste inventarisatie zijn 69 belemmeringen geidentificeerd. Deze voortgangsrapportage geeft een overzicht van de voortgang van het BBE Programma, de naar voren gekomen nieuwe belemmeringen. De oplossingen voor de belemmeringen zijn terug te vinden op www.biobasedeconomy.nl.

  2. 40 CFR 80.512 - May an importer treat diesel fuel as blendstock?

    Science.gov (United States)

    2010-07-01

    ... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... fuel under §§ 80.593, 80.601, and 80.604. (4) If previously designated motor vehicle diesel fuel having... redesignate all the diesel fuel as 500 ppm sulfur motor vehicle diesel fuel for purposes of the temporary...

  3. Design of Incremental Conductance Sliding Mode MPPT Control Applied by Integrated Photovoltaic and Proton Exchange Membrane Fuel Cell System under Various Operating Conditions for BLDC Motor

    Directory of Open Access Journals (Sweden)

    Jehun Hahm

    2015-01-01

    Full Text Available This paper proposes an integrated photovoltaic (PV and proton exchange membrane fuel cell (PEMFC system for continuous energy harvesting under various operating conditions for use with a brushless DC motor. The proposed scheme is based on the incremental conductance (IncCond algorithm combined with the sliding mode technique. Under changing atmospheric conditions, the energy conversion efficiency of a PV array is very low, leading to significant power losses. Consequently, increasing efficiency by means of maximum power point tracking (MPPT is particularly important. To manage such a hybrid system, control strategies need to be established to achieve the aim of the distributed system. Firstly, a Matlab/Simulink based model of the PV and PEMFC is developed and validated, as well as the incremental conductance sliding (ICS MPPT technique; then, different MPPT algorithms are employed to control the PV array under nonuniform temperature and insolation conditions, to study these algorithms effectiveness under various operating conditions. Conventional techniques are easy to implement but produce oscillations at MPP. Compared to these techniques, the proposed technique is more efficient; it produces less oscillation at MPP in the steady state and provides more precise tracking.

  4. The analysis of the motor characteristics of D–RME–E fuel blend during on-field tests

    Directory of Open Access Journals (Sweden)

    Ž. Bazaras

    2009-09-01

    Full Text Available A detailed analysis of the characteristics of D–RME–E (diesel-rapeseed methyl ester-ethanol was carefully performed fuelling an 18 kW capacity tractor unit equipped with the four-stroke D21A1 diesel engine (combustion chamber consists of a dished piston. The conducted on-field test demonstrated a positive effect on the dynamic and ecological characteristics of the tractor unit while fuelling the engine with biodiesel blend 70% D+30% RME (hereinafter – B30 admixed with dehydrated ethanol additive (5% (v/v. This compound did not affect a decrease in the diesel engine power, and in the range of experiment error, showed a tendency of ~2% fuel economy compared to pure B30. A dramatic decrease in PM (40%, HC (25% and CO (6% emissions comparing to fossil diesel was observed when operating the tractor unit at maximum traction power which is a characteristic operating mode of the heavy duty transport means of agricultural purpose. NOx emission of the proposed D–RME–E blend showed a tendency to decrease to 4% compared to B30.

  5. Current statuses of international cooperation activities, and research and development activities, based on IEA's Implementing Agreement for a Program on Research and Demonstration of Advanced Motor Fuels; EIA jidoshayo senshin nenryo jisshi kyotei ni motozuku kokusai kyoryoku katsudo oyobi kenkyu kaihatsu no genjo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-09-01

    Described herein are current statuses of international cooperation activities, and R and D activities, based on IEA's Implementing Agreement for a Program on Research and Demonstration of Advanced Motor Fuels. This agreement is aimed at efficient implementation of researches, demonstration tests and information exchanges for advanced motor fuels by promoting international cooperation. It raises future environment-compatible diesel fuels and new fuels for new engines as the major R and D themes, which cover information exchanges for engines/vehicles of heavy- duty vehicles, motor fuel information services, toxicity assessments of bio-diesel fuels, feasibility studies on possibility of dimethyl ether as diesel fuel, surveys on barriers in alternative fuel markets, surveys on biodegradable lubricant oils, and effects of new heavy-duty vehicle techniques on the environments. Some of the results reported in FY 1997 are those for comparison between current motor fuels and dimethyl ether in toxicity, analysis of the failure mode effects of dimethyl ether tank in vehicles, and surveys on barriers in alternative fuel markets. (NEDO)

  6. High Power Density Motors

    Science.gov (United States)

    Kascak, Daniel J.

    2004-01-01

    With the growing concerns of global warming, the need for pollution-free vehicles is ever increasing. Pollution-free flight is one of NASA's goals for the 21" Century. , One method of approaching that goal is hydrogen-fueled aircraft that use fuel cells or turbo- generators to develop electric power that can drive electric motors that turn the aircraft's propulsive fans or propellers. Hydrogen fuel would likely be carried as a liquid, stored in tanks at its boiling point of 20.5 K (-422.5 F). Conventional electric motors, however, are far too heavy (for a given horsepower) to use on aircraft. Fortunately the liquid hydrogen fuel can provide essentially free refrigeration that can be used to cool the windings of motors before the hydrogen is used for fuel. Either High Temperature Superconductors (HTS) or high purity metals such as copper or aluminum may be used in the motor windings. Superconductors have essentially zero electrical resistance to steady current. The electrical resistance of high purity aluminum or copper near liquid hydrogen temperature can be l/lOO* or less of the room temperature resistance. These conductors could provide higher motor efficiency than normal room-temperature motors achieve. But much more importantly, these conductors can carry ten to a hundred times more current than copper conductors do in normal motors operating at room temperature. This is a consequence of the low electrical resistance and of good heat transfer coefficients in boiling LH2. Thus the conductors can produce higher magnetic field strengths and consequently higher motor torque and power. Designs, analysis and actual cryogenic motor tests show that such cryogenic motors could produce three or more times as much power per unit weight as turbine engines can, whereas conventional motors produce only 1/5 as much power per weight as turbine engines. This summer work has been done with Litz wire to maximize the current density. The current is limited by the amount of heat it

  7. Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Sinskey, Anthony J. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Worden, Robert Mark [Michigan State Univ., East Lansing, MI (United States); Brigham, Christopher [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Lu, Jingnan [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Quimby, John Westlake [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Gai, Claudia [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Speth, Daan [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Elliott, Sean [Boston Univ., MA (United States); Fei, John Qiang [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Bernardi, Amanda [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Li, Sophia [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Grunwald, Stephan [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Grousseau, Estelle [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Maiti, Soumen [Michigan State Univ., East Lansing, MI (United States); Liu, Chole [Michigan State Univ., East Lansing, MI (United States)

    2013-12-16

    This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide

  8. Replacing fossil based plastic performance products by bio-based plastic products-Technical feasibility.

    Science.gov (United States)

    van den Oever, Martien; Molenveld, Karin

    2017-07-25

    Larger scale market introduction of new bio-based products requires a clear advantage regarding sustainability, as well as an adequate techno-economic positioning relative to fossil based products. In a previous paper [Broeren et al., 2016], LCA results per kg and per functionality equivalent of bio-based plastics were presented, together with economic considerations. The present paper discusses the mechanical and thermal properties of a range of commercially available bio-based plastics based on polylactic acid (PLA), cellulose esters, starch and polyamides, and the feasibility of replacing fossil-based counterparts based on performance. The evaluation is approached from an end user perspective. First, potentially suitable bio-based plastics are selected based on manufacturers' specifications in technical data sheets, then a first experimental evaluation is performed on injection moulded ISO specimens, and finally a further selection of plastics is tested on large 50×70cm panels. This technical feasibility study indicates that so far bio-based plastics do not completely match the properties of high performance materials like flame retardant V-0 PC/ABS blends used in electronic devices. The performance gap is being decreased by the development of stereocomplex PLA and hybrid PLA blends with polycarbonate, which offer clearly improved properties with respect to maximum usage temperature and toughness. In addition, several materials meet the V-0 flammability requirements needed in specific durable applications. On the other hand, improving these properties so far has negative consequences for the bio-based content. This study also shows that replacement of bulk polymers like PS is feasible using PLA compounds with a bio-based content as high as 85%. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Between mountains of gold and green business. System analysis of a bio-based economy; Tussen gouden bergen en groene business. Systeemverkenning van een bio-based economie

    Energy Technology Data Exchange (ETDEWEB)

    Weterings, R.; Roelofs, E.; Suurs, R.; Van der Zee, F.

    2012-04-15

    The study shows it is possible for the Dutch industry to expand its strong knowledge position to a forceful international competitive position by aiming innovations towards the realization of a biobased economy. The main conclusions of this report are that the biobased economy offers big opportunities for sustainable economic development in the Netherlands and in Europe, but there is no guarantee of success. At a European level a stable and inviting investment climate necessary for biobased economic activity is lacking. In the Netherlands there is a need for a proactive innovation policy to substantially accelerate the development of promising business cases [Dutch] Deze verkenning vertrekt vanuit trends en ontwikkelingen in de wereld en kijkt vervolgens naar de consequenties voor Europa en Nederland. Dit 'van buiten naar binnen' perspectief contrasteert met veel andere analyses die doorgaans vertrekken vanuit de kansen voor bio-based processen en producten en vooral ingaan op de 'gewenste' maatschappelijke context. Gekeken is enerzijds naar globale maatschappelijke trends en anderzijds naar specifieke sleutelactiviteiten binnen het Nederlandse innovatiesysteem. De verkenning gaat met deze benadering niet alleen in op de mondiale en Europese context, maar analyseert ook op systematische wijze de sterkten en zwakten binnen het Nederlandse innovatiesysteem.

  10. Sustainable Systems Analysis of Production and Transportation Scenarios for Conventional and Bio-based Energy Commodities

    Science.gov (United States)

    Doran, E. M.; Golden, J. S.; Nowacek, D. P.

    2013-12-01

    International commerce places unique pressures on the sustainability of water resources and marine environments. System impacts include noise, emissions, and chemical and biological pollutants like introduction of invasive species into key ecosystems. At the same time, maritime trade also enables the sustainability ambition of intragenerational equity in the economy through the global circulation of commodities and manufactured goods, including agricultural, energy and mining resources (UN Trade and Development Board 2013). This paper presents a framework to guide the analysis of the multiple dimensions of the sustainable commerce-ocean nexus. As a demonstration case, we explore the social, economic and environmental aspects of the nexus framework using scenarios for the production and transportation of conventional and bio-based energy commodities. Using coupled LCA and GIS methodologies, we are able to orient the findings spatially for additional insight. Previous work on the sustainable use of marine resources has focused on distinct aspects of the maritime environment. The framework presented here, integrates the anthropogenic use, governance and impacts on the marine and coastal environments with the natural components of the system. A similar framework has been highly effective in progressing the study of land-change science (Turner et al 2007), however modification is required for the unique context of the marine environment. This framework will enable better research integration and planning for sustainability objectives including mitigation and adaptation to climate change, sea level rise, reduced dependence on fossil fuels, protection of critical marine habitat and species, and better management of the ocean as an emerging resource base for the production and transport of commodities and energy across the globe. The framework can also be adapted for vulnerability analysis, resilience studies and to evaluate the trends in production, consumption and

  11. Honda Motor Company's CVCC Engine

    Science.gov (United States)

    1980-01-01

    From 1968 to 1972, Honda Motor Co. of Japan designed, tested, and massproduced a stratified charge engine, the CVCC, which was lower in carbon monoxide, hydrocarbon, and nitrogen oxide emissions and higher in fuel economy than contemporary convention...

  12. The Recent Developments in Biobased Polymers toward General and Engineering Applications: Polymers that Are Upgraded from Biodegradable Polymers, Analogous to Petroleum-Derived Polymers, and Newly Developed

    OpenAIRE

    Nakajima, Hajime; Dijkstra, Peter; Loos, Katja

    2017-01-01

    The main motivation for development of biobased polymers was their biodegradability, which is becoming important due to strong public concern about waste. Reflecting recent changes in the polymer industry, the sustainability of biobased polymers allows them to be used for general and engineering applications. This expansion is driven by the remarkable progress in the processes for refining biomass feedstocks to produce biobased building blocks that allow biobased polymers to have more versati...

  13. Motor Neurons

    DEFF Research Database (Denmark)

    Hounsgaard, Jorn

    2017-01-01

    Motor neurons translate synaptic input from widely distributed premotor networks into patterns of action potentials that orchestrate motor unit force and motor behavior. Intercalated between the CNS and muscles, motor neurons add to and adjust the final motor command. The identity and functional...... in in vitro preparations is far from complete. Nevertheless, a foundation has been provided for pursuing functional significance of intrinsic response properties in motoneurons in vivo during motor behavior at levels from molecules to systems....

  14. Development of Bio-Based Paint by using Methyl Esters from Palm Oil for Corrosion Inhibitor

    International Nuclear Information System (INIS)

    Mohibah Musa; Miradatul Najwa Muhd Rodhi; Najmiddin Yaakob; Ku Halim Ku Hamid; Juferi Idris

    2013-01-01

    Paint is used as a means of protection to prevent surfaces from being corroded over time. This research is focused on the development of a Bio-based paint made from palm oil methyl ester (POME) which originated from crude palm oil (CPO). New formulation paint has been developed to protect the pipeline from corrosion thus reducing the cost of the operation. Bio-based paint is made up of four components which are solvent, binder, additives, and pigment. The solvent in the bio-based paint is POME. The additives used are wetting and dispersing agent. The pigment used in the bio-based paint is TiO 2 . The formulation was developed by using a constant amount of additives and binder but varying the amount of POME at 10 ml, 15 ml, 20 ml, 25 ml and 30 ml with addition of water. The Standard Testing Methods for measuring the corrosion rate (ASTM G5-94(2011)) was carried out for each sample. In conclusion, it is proven that in the making of bio-based paint formulation for better corrosion inhibitor; the best amount of binder, additives and de-foam that should be used is 20 ml, 10 ml and 10 ml, respectively. (author)

  15. Structural Foams of Biobased Isosorbide-Containing Copolycarbonate

    Directory of Open Access Journals (Sweden)

    Stefan Zepnik

    2017-01-01

    Full Text Available Isosorbide-containing copolycarbonate (Bio-PC is a partly biobased alternative to conventional bisphenol A (BPA based polycarbonate (PC. Conventional PC is widely used in polymer processing technologies including thermoplastic foaming such as foam injection molding. At present, no detailed data is available concerning the foam injection molding behavior and foam properties of Bio-PC. This contribution provides first results on injection-molded foams based on isosorbide-containing PC. The structural foams were produced by using an endothermic chemical blowing agent (CBA masterbatch and the low pressure foam injection molding method. The influence of weight reduction and blowing agent concentration on general foam properties such as density, morphology, and mechanical properties was studied. The test specimens consist of a foam core in the center and compact symmetrical shell layers on the sides. The thickness of the foam core increases with increasing weight reduction irrespective of the CBA concentration. The specific (mechanical bending properties are significantly improved and the specific tensile properties can almost be maintained while reducing the density of the injection-molded parts.

  16. Towards a sustainable biobased industry - Highlighting the impact of extremophiles.

    Science.gov (United States)

    Krüger, Anna; Schäfers, Christian; Schröder, Carola; Antranikian, Garabed

    2018-01-25

    The transition of the oil-based economy towards a sustainable economy completely relying on biomass as renewable feedstock requires the concerted action of academia, industry, politics and civil society. An interdisciplinary approach of various fields such as microbiology, molecular biology, chemistry, genetics, chemical engineering and agriculture in addition to cross-sectional technologies such as economy, logistics and digitalization is necessary to meet the future global challenges. The genomic era has contributed significantly to the exploitation of naturés biodiversity also from extreme habitats. By applying modern technologies it is now feasible to deliver robust enzymes (extremozymes) and robust microbial systems that are active at temperatures up to 120°C, at pH 0 and 12 and at 1000bar. In the post-genomic era, different sophisticated "omics" analyses will allow the identification of countless novel enzymes regardless of the lack of cultivability of most microorganisms. Furthermore, elaborate protein-engineering methods are clearing the way towards tailor-made robust biocatalysts. Applying environmentally friendly and efficient biological processes, terrestrial and marine biomass can be converted to high value products e.g. chemicals, building blocks, biomaterials, pharmaceuticals, food, feed and biofuels. Thus, further application of extremophiles has the potential to improve sustainability of existing biotechnological processes towards a greener biobased industry. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Highly Branched Bio-Based Unsaturated Polyesters by Enzymatic Polymerization

    Directory of Open Access Journals (Sweden)

    Hiep Dinh Nguyen

    2016-10-01

    Full Text Available A one-pot, enzyme-catalyzed bulk polymerization method for direct production of highly branched polyesters has been developed as an alternative to currently used industrial procedures. Bio-based feed components in the form of glycerol, pentaerythritol, azelaic acid, and tall oil fatty acid (TOFA were polymerized using an immobilized Candida antarctica lipase B (CALB and the potential for an enzymatic synthesis of alkyds was investigated. The developed method enables the use of both glycerol and also pentaerythritol (for the first time as the alcohol source and was found to be very robust. This allows simple variations in the molar mass and structure of the polyester without premature gelation, thus enabling easy tailoring of the branched polyester structure. The postpolymerization crosslinking of the polyesters illustrates their potential as binders in alkyds. The formed films had good UV stability, very high water contact angles of up to 141° and a glass transition temperature that could be controlled through the feed composition.

  18. {sup 14}C determination in different bio-based products

    Energy Technology Data Exchange (ETDEWEB)

    Santos Arévalo, Francisco-Javier, E-mail: fj.santos@csic.es [Centro Nacional de Aceleradores (Universidad de Sevilla, Consejo Superior de Investigaciones Científicas, Junta de Andalucía), Thomas Alva Edison 7, 41092 Seville (Spain); Gómez Martínez, Isabel; Agulló García, Lidia; Reina Maldonado, María-Teresa [Centro Nacional de Aceleradores (Universidad de Sevilla, Consejo Superior de Investigaciones Científicas, Junta de Andalucía), Thomas Alva Edison 7, 41092 Seville (Spain); García León, Manuel [Centro Nacional de Aceleradores (Universidad de Sevilla, Consejo Superior de Investigaciones Científicas, Junta de Andalucía), Thomas Alva Edison 7, 41092 Seville (Spain); Dpto. de Física Atómica Molecular y Nuclear, Universidad de Sevilla, Reina Mercedes s/n, 41012 Seville (Spain)

    2015-10-15

    Radiocarbon determination can be used as a tool to investigate the presence of biological elements in different bio-based products, such as biodiesel blends. These products may also be produced from fossil materials obtaining the same final molecules, so that composition is chemically indistinguishable. The amount of radiocarbon in these products can reveal how much of these biological elements have been used, usually mixed with petrol derived components, free of {sup 14}C. Some of these products are liquid and thus the handling at the laboratory is not as straightforward as with solid samples. At Centro Nacional de Aceleradores (CNA) we have tested the viability of these samples using a graphitization system coupled to an elemental analyzer used for combustion of the samples, thus avoiding any vacuum process. Samples do not follow any chemical pre-treatment procedure and are directly graphitized. Specific equipment for liquid samples related to the elemental analyzer was tested. Measurement of samples was performed by low-energy AMS at the 1 MV HVEE facility at CNA, paying special attention to background limits and reproducibility during sample preparation.

  19. 40 CFR 80.610 - What acts are prohibited under the diesel fuel sulfur program?

    Science.gov (United States)

    2010-07-01

    ... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel... supply, store or transport motor vehicle diesel fuel, NRLM diesel fuel, ECA marine fuel or heating oil... transport any diesel fuel for use in motor vehicle or nonroad engines that contains greater than 0.10...

  20. 26 CFR 41.4482(a)-1 - Definition of highway motor vehicle.

    Science.gov (United States)

    2010-04-01

    ... of its own motor, whether such motor is powered by gasoline, diesel fuel, special motor fuels... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Definition of highway motor vehicle. 41.4482(a... (CONTINUED) MISCELLANEOUS EXCISE TAXES EXCISE TAX ON USE OF CERTAIN HIGHWAY MOTOR VEHICLES Tax on Use of...

  1. Reciprocating Linear Electric Motor

    Science.gov (United States)

    Goldowsky, M. P.

    1984-01-01

    Features include structural simplicity and good force/displacement characteristics. Reciprocating motor has simple, rugged construction, relatively low reciprocating weight, improved power delivery, and improved force control. Wear reduced by use of magnetic bearings. Intended to provide drivers for long-lived Stirling-cycle cryogenic refrigerators, concept has less exotic applications, such as fuel pumps.

  2. Perspectives on Resource Recovery from Bio-Based Production Processes: From Concept to Implementation

    DEFF Research Database (Denmark)

    S.B.A. Udugama, Isuru; Mansouri, Seyed Soheil; Mitic, Aleksandar

    2017-01-01

    Recovering valuable compounds from waste streams of bio-based production processes is in line with the circular economy paradigm, and is achievable by implementing “simple-to-use” and well-established process separation technologies. Such solutions are acceptable from industrial, economic...... and environmental points of view, implying relatively easy future implementation on pilot- and full-scale levels in the bio-based industry. Reviewing such technologies is therefore the focus here. Considerations about technology readiness level (TRL) and Net Present Value (NPV) are included in the review, since TRL...... and NPV contribute significantly to the techno-economic evaluation of future and promising process solutions. Based on the present review, a qualitative guideline for resource recovery from bio-based production processes is proposed. Finally, future approaches and perspectives toward identification...

  3. A comparative review of petroleum-based and bio-based acrolein production.

    Science.gov (United States)

    Liu, Lu; Ye, X Philip; Bozell, Joseph J

    2012-07-01

    Acrolein is an important chemical intermediate for many common industrial chemicals, leading to an array of useful end products. This paper reviews all the synthetic methods, including the former (aldol condensation) and contemporary (partial oxidation of propylene) manufacturing methods, the partial oxidation of propane, and most importantly, the bio-based glycerol-dehydration route. Emphasis is placed on the petroleum-based route from propylene and the bio-based route from glycerol, an abundantly available and relatively inexpensive raw material available from biodiesel production. This review provides technical details and incentives for industrial proyduction that justify a transition toward bio-based acrolein production. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Thermoset coatings from epoxidized sucrose soyate and blocked, bio-based dicarboxylic acids.

    Science.gov (United States)

    Kovash, Curtiss S; Pavlacky, Erin; Selvakumar, Sermadurai; Sibi, Mukund P; Webster, Dean C

    2014-08-01

    A new 100% bio-based thermosetting coating system was developed from epoxidized sucrose soyate crosslinked with blocked bio-based dicarboxylic acids. A solvent-free, green method was used to block the carboxylic acid groups and render the acids miscible with the epoxy resin. The thermal reversibility of this blocking allowed for the formulation of epoxy-acid thermoset coatings that are 100% bio-based. This was possible due to the volatility of the vinyl ethers under curing conditions. These systems have good adhesion to metal substrates and perform well under chemical and physical stress. Additionally, the hardness of the coating system is dependent on the chain length of the diacid used, making it tunable. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The Rebirth of Waste Cooking Oil to Novel Bio-based Surfactants

    Science.gov (United States)

    Zhang, Qi-Qi; Cai, Bang-Xin; Xu, Wen-Jie; Gang, Hong-Ze; Liu, Jin-Feng; Yang, Shi-Zhong; Mu, Bo-Zhong

    2015-05-01

    Waste cooking oil (WCO) is a kind of non-edible oil with enormous quantities and its unreasonable dispose may generate negative impact on human life and environment. However, WCO is certainly a renewable feedstock of bio-based materials. To get the rebirth of WCO, we have established a facile and high-yield method to convert WCO to bio-based zwitterionic surfactants with excellent surface and interfacial properties. The interfacial tension between crude oil and water could reach ultra-low value as 0.0016 mN m-1 at a low dosage as 0.100 g L-1 of this bio-based surfactant without the aid of extra alkali, which shows a strong interfacial activity and the great potential application in many industrial fields, in particular, the application in enhanced oil recovery in oilfields in place of petroleum-based surfactants.

  6. Production of bio-based materials using photobioreactors with binary cultures

    Science.gov (United States)

    Beliaev, Alex S; Pinchuk, Grigoriy E; Hill, Eric A; Fredrickson, Jim K

    2013-08-27

    A method, device and system for producing preselected products, (either finished products or preselected intermediary products) from biobased precursors or CO.sub.2 and/or bicarbonate. The principal features of the present invention include a method wherein a binary culture is incubated with a biobased precursor in a closed system to transform at least a portion of the biobased precursor to a preselected product. The present invention provides a method of cultivation that does not need sparging of a closed bioreactor to remove or add a gaseous byproduct or nutrient from a liquid medium. This improvement leads to significant savings in energy consumption and allows for the design of photobioreactors of any desired shape. The present invention also allows for the use of a variety of types of waste materials to be used as the organic starting material.

  7. Life-cycle assessment of corn-based butanol as a potential transportation fuel.

    Energy Technology Data Exchange (ETDEWEB)

    Wu, M.; Wang, M.; Liu, J.; Huo, H.; Energy Systems

    2007-12-31

    Butanol produced from bio-sources (such as corn) could have attractive properties as a transportation fuel. Production of butanol through a fermentation process called acetone-butanol-ethanol (ABE) has been the focus of increasing research and development efforts. Advances in ABE process development in recent years have led to drastic increases in ABE productivity and yields, making butanol production worthy of evaluation for use in motor vehicles. Consequently, chemical/fuel industries have announced their intention to produce butanol from bio-based materials. The purpose of this study is to estimate the potential life-cycle energy and emission effects associated with using bio-butanol as a transportation fuel. The study employs a well-to-wheels analysis tool--the Greenhouse Gases, Regulated Emissions and Energy Use in Transportation (GREET) model developed at Argonne National Laboratory--and the Aspen Plus{reg_sign} model developed by AspenTech. The study describes the butanol production from corn, including grain processing, fermentation, gas stripping, distillation, and adsorption for products separation. The Aspen{reg_sign} results that we obtained for the corn-to-butanol production process provide the basis for GREET modeling to estimate life-cycle energy use and greenhouse gas emissions. The GREET model was expanded to simulate the bio-butanol life cycle, from agricultural chemical production to butanol use in motor vehicles. We then compared the results for bio-butanol with those of conventional gasoline. We also analyzed the bio-acetone that is coproduced with bio-butanol as an alternative to petroleum-based acetone. Our study shows that, while the use of corn-based butanol achieves energy benefits and reduces greenhouse gas emissions, the results are affected by the methods used to treat the acetone that is co-produced in butanol plants.

  8. The Biobased Economy. Biofuels, Materials and Chemicals in the Post-oil Era

    International Nuclear Information System (INIS)

    Langeveld, H.; Sanders, J.; Meeusen, M.

    2010-01-01

    The impending threats of catastrophic climate change and peak oil are driving our society towards increased use of biomass for energy, chemical compounds and other materials - the beginnings of a biobased economy. As alternative development models for the biobased economy emerge, we need to determine potential applications, their perspectives and possible impacts as well as policies that can steer technological and market development in such a way that our objectives are met. Currently, it is still far from clear what will be the most sustainable routes to follow, which technologies should be included, and how their development will affect, and be affected by, research, public opinion and policy and market forces. This groundbreaking work, edited by a group of leading researchers originally from Wageningen Agricultural University in the Netherlands, sets out to unpick the complex systems in play. It provides an illuminating framework for how policy and market players could and should drive the development of a biobased economy that is effective, sustainable, fair and cost efficient. Starting with a state-of-the-art overview of major biobased technologies, including biorefinery and technologies for the production of biofuels, biogas, biomass feedstocks for chemistry and bioplastics, it discusses how different actor groups interact through policy and markets. Information from case studies is used to demonstrate how the potential of the biobased economy in different parts of the world, such as North America, Europe, and emerging economies like China and Brazil can be realised using research, debate, policy and commercial development. The result is an essential resource for all those working in or concerned with biobased industries, their policy or research.

  9. 40 CFR 80.602 - What records must be kept by entities in the NRLM diesel fuel, ECA marine fuel, and diesel fuel...

    Science.gov (United States)

    2010-07-01

    ... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Recordkeeping and Reporting Requirements... in the NRLM diesel fuel, ECA marine fuel, and diesel fuel additive production, importation, and...

  10. Novel bio-based and biodegradable polymer blends

    Science.gov (United States)

    Yang, Shengzhe

    Most plastic materials, including high performance thermoplastics and thermosets are produced entirely from petroleum-based products. The volatility of the natural oil markets and the increasing cost of petroleum have led to a push to reduce the dependence on petroleum products. Together with an increase in environmental awareness, this has promoted the use of alternative, biorenewable, environmentally-friendly products, such as biomass. The growing interest in replacing petroleum-based products by inexpensive, renewable, natural materials is important for sustainable development into the future and will have a significant impact on the polymer industry and the environment. This thesis involved characterization and development of two series of novel bio-based polymer blends, namely polyhydroxyalkanoate (PHA)/polyamide (PA) and poly(lactic acid) (PLA)/soy protein. Blends with different concentrations and compatible microstructures were prepared using twin-screw extruder. For PHA/PA blends, the poor mechanical properties of PHA improved significantly with an excellent combination of strength, stiffness and toughness by adding PA. Furthermore, the effect of blending on the viscoelastic properties has been investigated using small-amplitude oscillatory shear flow experiments as a function of blend composition and angular frequency. The elastic shear modulus (G‧) and complex viscosity of the blends increased significantly with increasing the concentration of PHA. Blending PLA with soy protein aims at reducing production cost, as well as accelerating the biodegradation rate in soil medium. In this work, the mechanical, thermal and morphological properties of the blends were investigated using dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile tests.

  11. Hydrogen and fuel cells

    International Nuclear Information System (INIS)

    2006-06-01

    This road-map proposes by the Group Total aims to inform the public on the hydrogen and fuel cells. It presents the hydrogen technology from the production to the distribution and storage, the issues as motor fuel and fuel cells, the challenge for vehicles applications and the Total commitments in the domain. (A.L.B.)

  12. Evaluación de un motor de encendido por chispa trabajando con mezclas etanol-gasolina; Evaluation of the spark-ignition engine fueled with ethanol–gasoline blends

    Directory of Open Access Journals (Sweden)

    Eliezer Ahmed Melo Espinosa

    2012-07-01

    Full Text Available En la presente investigación se realiza un análisis del rendimiento de un motor de encendido por chispa (Lada 1300 al usar como combustible mezclas de etanol con gasolina en un 10%, 20% y 30%. Los parámetros analizados en cada experimento fueron el torque efectivo, la potencia efectiva, el consumo específico de combustible y las emisiones de monóxido de carbono. Los resultados obtenidos se analizaron estadísticamente mediante una comparación de muestras múltiples en el software estadístico Statgraphics Centurion XV.II. Este análisis fue hecho con él con el objetivo de analizar las posibles diferencias entre los parámetros evaluados para cada combustible a una misma rpm. A partir de los resultados obtenidos se pudieron establecer satisfactoriamente dos porcientos adecuados de la mezcla etanol-gasolina para ser utilizado en motores de encendido por chispa (Lada en las condiciones de Cuba y sin hacer modificacionesen el motor. In this investigation an analysis based on the performances of an engine when using blends of anhydrous ethanol with regular gasoline as fuels is carried out. The experiments of the Lada 1300 engine were carriedout for different blends in 10%, 20% and 30% of ethanol in gasoline. The analyzed parameters for each experiment were the effective torque, the effective power, the specific fuel consumption and the carbon monoxide exhausts emissions. The obtained results were statistically analyzed through multiple-sample comparison in the software Statgraphics Centurion XV.II. This analysis was made with the objective of analyzing the possible differences among the evaluated parameters for each fuel to the same rpm. The appropriate percent of the anhydrous ethanol - regular gasoline blends for use in engine (Lada under the Cuba conditions and without making modifications were satisfactorily established.

  13. Diseño y optimización del sistema de renovación de la carga de un motor dual fuel para transporte pesado mediante sobrealimentación en doble etapa

    OpenAIRE

    SIRVENT SANJOSÉ, ROBERTO ANDRÉS

    2016-01-01

    El trabajo consiste en el diseño del sistema de admisión y escape de un motor dual-fuel para transporte pesado. Se deberá seleccionar la arquitectura adecuada para poder conseguir las condiciones de deseadas en el interior del cilindro (sistema de sobrealimentación, producción de EGR). Se deberá también seleccionar la estrategia adecuada para el control de cada uno de los elementos utilizados. Sirvent Sanjosé, RA. (2016). Diseño y optimización del sistema de renovación de la carga de un mo...

  14. Special on the Bio-based Economy. Making money with a green economy; Special Biobased Economy. Geld verdienen met een groene economie

    Energy Technology Data Exchange (ETDEWEB)

    Waterval, R. (ed.)

    2011-12-15

    Bio-based is booming. Increasingly more businesses see a healthy business case in products that are not made with fossil raw materials, but with biomass. But where are the opportunities for the Netherlands? And which roles can the government, trade and industry and science play? This PM special contains interviews with and experiences of pioneering entrepreneurs and agricultural attaches in the Netherlands and abroad [Dutch] Biobased is booming. Steeds meer bedrijven zien een gezonde businesscase in producten die niet gemaakt zijn met fossiele grondstoffen maar met biomassa. Waar liggen de kansen voor Nederland? En welke rol is daarbij weggelegd voor de overheid, het bedrijfsleven en de wetenschap? In deze PM-special onder meer interviews met en ervaringen van pionerende entrepreneurs en landbouwattaches in binnen- en buitenland.

  15. Assessment of possible usages of fuels alternatives to diesel by maritime, road and river freight transport professionals. Gas-based motorizations, strategic investments for the energy transition of road and maritime freight transport companies within the frame of the 2014/94/EU directive of 22 October 2014

    International Nuclear Information System (INIS)

    Erhardt, Jean-Bernard; Maler, Philippe

    2017-05-01

    As the 2014/94/EU directive defines alternative fuels (electric power, natural gas under its gaseous and liquefied form, biofuels, liquefied petrol gas or LPG, hydrogen, synthetic fuels, and paraffinic fuels), and states the obligation for member states to develop distribution infrastructures for these fuels, this report addresses fuels which cannot be mixed with diesel fuel and thus require the modification of transport equipment and the development of a new distribution infrastructure, technically different from that for oil-derived fuels. It describes technical and economic characteristics of French freight transport companies, public policies aimed at an energy transition of these companies, and alternate fuels defined by the European directive. Then, it proposes an overview of the status of perspectives of development of alternative motorizations for four types of equipment used in freight transport: freight transport ships, industrial vehicles, light commercial vehicles, and inland vessels

  16. Quantifying the Impact of Vehicle and Motor Fuel Provisions from the Energy Policy Act on the Sustainability and Resilience of U.S. Cities: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Steward, Darlene; Sears, Ted

    2017-02-01

    The Energy Policy Act (EPAct) of 1992, with later amendments, was enacted with the goal of reducing U.S. petroleum consumption by building a core market for alternative fuels and vehicles. The U.S. Department of Energy manages three federal programs related to EPAct; the Sustainable Federal Fleets Program, the State and Alternative Fuel Provider Program, and Clean Cities. Federal agencies and State and Alternative Fuel Provider Fleets are required to submit annual reports that document their compliance with the legislation. Clean Cities is a voluntary program aimed at building partnerships and providing technical expertise to encourage cities to reduce petroleum use in transportation. This study reviews the evolution of these three programs in relation to alternative fuel and vehicle markets and private sector adoption of alternative fueled vehicles to assess the impact of the programs on reduction in petroleum use and greenhouse gas emissions both within the regulated fleets and through development of alternative fuel and vehicle markets. The increased availability of alternative fuels and use of alternative fuels in regulated fleets is expected to improve cities' ability to respond to and quickly recover from both local disasters and short- and long-term regional or national fuel supply interruptions. Our analysis examines the benefits as well as potential drawbacks of alternative fuel use for the resiliency of U.S. cities.

  17. Socio-economic opportunities of the biobased economy in the south-west of the Netherlands. Estimated employment impact in 2020; Sociaaleconomische kansen van de biobased economy in Zuidwest-Nederland. Inschatting werkgelegenheidseffecten in 2020

    Energy Technology Data Exchange (ETDEWEB)

    Van Lieshout, M.; Warringa, G.; Bergsma, G.; Croezen, H.

    2013-06-15

    This study, commissioned by the Socio-Economic Councils (SER) of the Dutch provinces of Zeeland and Brabant, was carried out in collaboration with a supervisory committee comprising numerous stakeholders in the biobased economy in the south-west of the Netherlands. The motto was 'agro meets chemistry'. Given that it was clear from the outset that the volume of locally available biomass is insufficient for large-scale power generation without inducing serious competition with food production, it was opted to restrict the scope of the 'biobased economy' to production of biobased chemicals and innovative materials. Because of the study's limited scope and duration, gross employment effects were also calculated for Zeeland and West Brabant only. To this end, three factors critical for the growth of the biobased economy and thus for potential employment effects were analysed: the price of fossil feedstocks, the availability of biomass for chemical industry applications, and the availability of capital for investing in innovative biobased processes. To cover the full range of possible developments in the biobased economy, two scenarios were developed: high and low, with in each case employment effects being estimated on the basis of a biomass flow analysis and employment indices [Dutch] Deze studie is uitgevoerd in opdracht van de SER Zeeland en de SER Brabant, in samenwerking met een begeleidingscommissie met brede vertegenwoordiging van stakeholders van de biobased economy in Zuidwest Nederland. De insteek was 'agro meets chemistry'. Aangezien bij aanvang vast stond dat de lokaal beschikbare biomassa onvoldoende is voor grootschalige energieopwekking, zonder ernstige concurrentie met voedselproductie te veroorzaken, is er voor gekozen om de biobased economy te beperken tot de productie van biobased chemie en innovatieve materialen. Verder is gezien de beperkte omvang en doorlooptijd van de studie besloten om

  18. A point at the horizon. Start of an intersectoral Business Plan Biobased Economy

    International Nuclear Information System (INIS)

    2011-06-01

    This document is the starting point of a joint business plan for the transition to a Dutch biobased economy (BBE), in which the 6 top sectors chemistry, agro-food, horticulture and propagation materials, logistics, energy and water want to join forces to give more shape to the leading role of the Netherlands in the transition to a sustainable society. [nl

  19. Securing renewable resource supplies for changing market demands in a bio-based economy

    NARCIS (Netherlands)

    Dam, van J.E.G.; Klerk-Engels, de B.; Struik, P.C.; Rabbinge, R.

    2005-01-01

    Establishment of a bio-based economy has been recognised as one of the key issues for sustainable development For future developments renewable resources will play a key role as CO2 neutral raw material for sustainable industrial production to curb depletion of fossil resources. Options to fully

  20. Acoustic performance and microstructural analysis of bio-based lightweight concrete containing miscanthus

    NARCIS (Netherlands)

    Chen, Yuxuan; Yu, Q. L.; Brouwers, H. J.H.

    2017-01-01

    Miscanthus Giganteus (i.e. Elephant Grass) is a cost-effective and extensively available ecological resource in many agricultural regions. This article aims at a fundamental research on a bio-based lightweight concrete using miscanthus as aggregate, i.e. miscanthus lightweight concrete (MLC), with

  1. Why we need resilience thinking to meet societal challenges in bio-based production systems

    NARCIS (Netherlands)

    Ge, L.; Anten, N.P.R.; Dixhoorn, van I.D.E.; Feindt, P.H.; Kramer, K.; Leemans, H.B.J.; Gielen-Meuwissen, M.P.M.; Spoolder, H.A.M.; Sukkel, W.

    2016-01-01

    The need to feed an increasing world population and to
    respond to the effects of climate change creates
    unprecedented challenges for bio-based production systems.
    Many of these systems have been designed to maximize
    productivity and efficiency under standard

  2. Twisting biomaterials around your little finger: Environmental impacts of bio-based wrappings

    NARCIS (Netherlands)

    Hermann, B.G.; Blok, K.; Patel, M.K.

    2010-01-01

    Background, aim, and scope Packaging uses nearly 40% of all polymers, a substantial share of which is used for sensitive merchandise such as moisture-sensitive food. To find out if bio-based materials are environmentally advantageous for this demanding application, we compared laminated, printed

  3. 77 FR 10939 - Driving Innovation and Creating Jobs in Rural America Through Biobased and Sustainable Product...

    Science.gov (United States)

    2012-02-24

    ... Sustainable Product Procurement Memorandum for the Heads of Executive Departments and Agencies The Bio... economic development, create new jobs, and provide new markets for farm commodities. Biobased and sustainable products help to increase our energy security and independence. The Federal Government, with...

  4. 76 FR 53113 - Guidelines for Designating Biobased Products for Federal Procurement

    Science.gov (United States)

    2011-08-25

    ... Designating Biobased Products for Federal Procurement AGENCY: Office of Procurement and Property Management... that the Department of Agriculture, Office of Procurement and Property Management, is hereby requesting... comments to: Ron Buckhalt, USDA, Office of Procurement and Property Management, Room 361, Reporters...

  5. Thermoplastic poly(urethane urea)s from novel, bio-based amorphous polyester diols

    NARCIS (Netherlands)

    Tang, D.; Noordover, B.A.J.; Sablong, R.J.; Koning, C.E.

    2012-01-01

    In this study, two novel, bio-based, amorphous polyester diols, namely poly(1,2-dimethylethylene adipate) (PDMEA) and poly(1,2-dimethylethylene succinate) (PDMES) are used to prepare thermoplastic poly(urethane urea)s (TPUUs). Interestingly, the TPUUs based on PDMEA show similar thermal and

  6. Bio-based self-healing coatings based on thermo-reversible Diels-Alder reaction

    NARCIS (Netherlands)

    Turkenburg, D.H.; Durant, Y.; Fischer, H.R.

    2017-01-01

    Stimulated by the growing demand for greener and more sustainable polymer systems we have studied thermoreversible polymer networks composed largely (> 83% w/w) of diethylitaconate of bio-based origin. A series of coating materials has been synthesized consisting of linear chains of diethylitaconate

  7. Potential of commodity chemicals to become bio-based according to maximum yields and petrochemical prices

    NARCIS (Netherlands)

    Straathof, Adrie J.J.; Bampouli, A.

    2017-01-01

    Carbohydrates are the prevailing biomass components available for bio-based production. The most direct way to convert carbohydrates into commodity chemicals is by one-step conversion at maximum theoretical yield, such as by anaerobic fermentation without side product formation. Considering these

  8. Polypyrrole Additional functions to bio-based façades

    NARCIS (Netherlands)

    Sailer, M.F. (Michael); Oostra, M.A.R. (Mieke); Eversdijk, J. (Jacco)

    2015-01-01

    AbstractDue to the crisis of 2008 the construction and real estate market became more demand-driven. Architects, builders and developers are looking for high-quality solutions for the realization of sustainable buildings. Supplying SMEs experience an increasing demand for bio-based materials with

  9. Improved natural rubber composites reinforced with a complex filler network of biobased nanoparticles and ionomer

    Science.gov (United States)

    Biobased rubber composites are renewable and sustainable. Significant improvement in modulus of rubber composite reinforced with hydrophilic filler was achieved with the inclusion of ionomers. Soy particles aided with ionomer, carboxylated styrene-butadiene (CSB), formed a strong complex filler netw...

  10. 77 FR 25632 - Guidelines for Designating Biobased Products for Federal Procurement

    Science.gov (United States)

    2012-05-01

    ... section 3201.2 and adding a definition of the term ``relevant stakeholder,'' which is used in the proposed...,'' ``Qualifying biobased product,'' and ``Relevant stakeholder'' to read as follows: Sec. 3201.2 Definitions... current program guidelines, gather input from government, industry, and public stakeholders on different...

  11. Sustainability benefits and challenges of inter-organizational collaboration in bio-based business

    NARCIS (Netherlands)

    Nuhoff-Isakhanyan, Gohar; Wubben, Emiel F.M.; Omta, S.W.F.

    2016-01-01

    Bio-based businesses are often considered to be sustainable. However, they are also linked to sustainability challenges such as deforestation and soil erosion. Encouraged to exploit innovative solutions and enhance sustainability, organizations engaged in bio-based activities extensively explore

  12. Unexpected nitrile formation in bio-based mesoporous materials (Starbons®).

    Science.gov (United States)

    Attard, Jennifer; Milescu, Roxana; Budarin, Vitaliy; Matharu, Avtar S; Clark, James H

    2018-01-16

    The bio-based mesoporous materials made from polysaccharides, Starbons® can be modified by two different routes to give high levels of N-content, unexpectedly including significant quantities of nitrile groups which can improve the materials performance in applications including metal capture.

  13. A bio-based fibre-reinforced plastic pedestrian bridge for Schiphol

    NARCIS (Netherlands)

    Smits, J.E.P.; Gkaidatzis, R.

    2015-01-01

    The present paper investigates Bio-based fibre-reinforced plastics, used as a load-bearing element of a bridge. We aim to increase the renewable content and decreasing the embodied energy of FRP. To achieve that, the consisting raw materials of these plastics which are based on non-renewable

  14. Opportunities for using bio-based fibers for value-added composites

    Science.gov (United States)

    Zhiyong Cai; Jerrold E. Winandy

    2006-01-01

    Efficient and economical utilization of various bio-based materials is an effective way to improve forest management, promote long-term sustainability, and restore native ecosystems. However, the dilemma is how to deal with lesser used, undervalued or no-value bio-resources such as small diameter trees, agricultural residues (wheat straw, rice straw, and corn stalk),...

  15. Techno-economic assessment of the production of bio-based chemicals from glutamic acid

    NARCIS (Netherlands)

    Lammens, T.M.; Gangarapu, S.; Franssen, M.C.R.; Scott, E.L.; Sanders, J.P.M.

    2012-01-01

    In this review, possible process steps for the production of bio-based industrial chemicals from glutamic acid are described, including a techno-economic assessment of all processes. The products under investigation were those that were shown to be synthesized from glutamic acid on lab-scale, namely

  16. Sustainable coatings from bio-based, enzymatically synthesized polyesters with enhanced functionalities

    NARCIS (Netherlands)

    Gustini, L.; Lavilla, C.; Finzel, L.; Noordover, B.A.J.; Hendrix, M.M.R.M.; Koning, C.E.

    2016-01-01

    Bio-based sorbitol-containing polyester polyols were synthesized via enzymatic polycondensation. The selectivity of the biocatalyst for primary vs. secondary hydroxyl groups allowed for the preparation of close to linear renewable polyester polyols with enhanced hydroxyl functionalities, both as

  17. Stabilized and Immobilized Bacillus subtilis Arginase for the Biobased Production of Nitrogen-Containing Chemicals

    NARCIS (Netherlands)

    Könst, P.M.; Turras, P.M.C.C.D.; Franssen, M.C.R.; Scott, E.L.; Sanders, J.P.M.

    2010-01-01

    L-Ornithine could serve as an intermediate in the biobased production of 1,4-diaminobutane from L-arginine. Using the concept of biorefinery, L-arginine could become widely available from biomass waste streams via the nitrogen storage polypeptide cyanophycin. Selective hydrolysis of L-arginine to

  18. Replacing fossil based plastic performance products by bio-based plastic products-Technical feasibility

    NARCIS (Netherlands)

    Oever, van den Martien; Molenveld, Karin

    2017-01-01

    Larger scale market introduction of new bio-based products requires a clear advantage regarding sustainability, as well as an adequate techno-economic positioning relative to fossil based products. In a previous paper [Broeren et al., 2016], LCA results per kg and per functionality equivalent of

  19. Enzymatic polymerization of bio-based monomers for applications in hydrogels and coatings

    DEFF Research Database (Denmark)

    Hoffmann, Christian; Nguyen, Hiep Dinh; Storgaard, Thomas

    of the enzymatic catalysts that can provide control over polymer structure in functional polymers. Lipase catalyzed polymerizations (specifically CALB) has been applied to prepare functional polyesters and to evaluate the possibilities of using less stable bio-based monomers such as itaconic acid or its...

  20. Conversion of polyhydroxybutyrate (PHB) to methyl crotonate for the production of biobased monomers

    NARCIS (Netherlands)

    Spekreijse, J.; Notre, Le J.E.L.; Sanders, J.P.M.; Scott, E.L.

    2015-01-01

    Within the concept of the replacement of fossil with biobased resources, bacterial polyhydroxybutyrate (PHB) can be obtained from volatile fatt y acids (VFAs) from agro-food waste streams and used as an intermediate toward attractive chemicals. Here we address a crucial step in this process, the

  1. Bio-based renewable additives for anti-icing applications (phase one).

    Science.gov (United States)

    2016-09-04

    The performance and impacts of several bio-based anti-icers along with a traditional chloride-based anti-icer (salt brine) were evaluated. : A statistical design of experiments (uniform design) was employed for developing anti-icing liquids consistin...

  2. Impact of Bio-Based Plastics on Current Recycling of Plastics

    Directory of Open Access Journals (Sweden)

    Luc Alaerts

    2018-05-01

    Full Text Available Bio-based plastics are increasingly appearing in a range of consumption products, and after use they often end up in technical recycling chains. Bio-based plastics are different from fossil-based ones and could disturb the current recycling of plastics and hence inhibit the closure of plastic cycles, which is undesirable given the current focus on a transition towards a circular economy. In this paper, this risk has been assessed via three elaborated case studies using data and information retrieved through an extended literature search. No overall risks were revealed for bio-based plastics as a group; rather, every bio-based plastic is to be considered as a potential separate source of contamination in current recycling practices. For PLA (polylactic acid, a severe incompatibility with PET (polyethylene terephthalate recycling is known; hence, future risks are assessed by measuring amounts of PLA ending up in PET waste streams. For PHA (polyhydroxy alkanoate there is no risk currently, but it will be crucial to monitor future application development. For PEF (polyethylene furanoate, a particular approach for contamination-related issues has been included in the upcoming market introduction. With respect to developing policy, it is important that any introduction of novel plastics is well guided from a system perspective and with a particular eye on incompatibilities with current and upcoming practices in the recycling of plastics.

  3. 40 CFR 80.570 - What labeling requirements apply to retailers and wholesale purchaser-consumers of diesel fuel...

    Science.gov (United States)

    2010-07-01

    ... FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA..., motor vehicle diesel fuel subject to the 15 ppm sulfur standard of § 80.520(a)(1), must affix the... dispensing, motor vehicle diesel fuel subject to the 500 ppm sulfur standard of § 80.520(c), must prominently...

  4. 40 CFR 80.617 - How may California diesel fuel be distributed or sold outside of the State of California?

    Science.gov (United States)

    2010-07-01

    ... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Violation... California diesel fuel redesignates it as motor vehicle diesel meeting the 15 ppm sulfur standard; and (vi) The terminal includes the volumes of California diesel fuel redesignated as motor vehicle diesel fuel...

  5. Alternative Bio-Based Solvents for Extraction of Fat and Oils: Solubility Prediction, Global Yield, Extraction Kinetics, Chemical Composition and Cost of Manufacturing

    Directory of Open Access Journals (Sweden)

    Anne-Gaëlle Sicaire

    2015-04-01

    Full Text Available The present study was designed to evaluate the performance of alternative bio-based solvents, more especially 2-methyltetrahydrofuran, obtained from crop’s byproducts for the substitution of petroleum solvents such as hexane in the extraction of fat and oils for food (edible oil and non-food (bio fuel applications. First a solvent selection as well as an evaluation of the performance was made with Hansen Solubility Parameters and the COnductor-like Screening MOdel for Realistic Solvation (COSMO-RS simulations. Experiments were performed on rapeseed oil extraction at laboratory and pilot plant scale for the determination of lipid yields, extraction kinetics, diffusion modeling, and complete lipid composition in term of fatty acids and micronutrients (sterols, tocopherols and tocotrienols. Finally, economic and energetic evaluations of the process were conducted to estimate the cost of manufacturing using 2-methyltetrahydrofuran (MeTHF as alternative solvent compared to hexane as petroleum solvent.

  6. To be, or not to be biodegradable… that is the question for the bio-based plastics

    OpenAIRE

    Prieto, Auxiliadora

    2016-01-01

    Summary Global warming, market and production capacity are being the key drivers for selecting the main players for the next decades in the market of bio?based plastics. The drop?in bio?based polymers such as the bio?based polyethylene terephtalate (PET) or polyethylene (PE), chemically identical to their petrochemical counterparts but having a component of biological origin, are in the top of the list. They are followed by new polymers such as PHA and PLA with a significant market growth rat...

  7. Superconducting DC homopolar motors for ship propulsion

    Energy Technology Data Exchange (ETDEWEB)

    Heiberger, M.; Reed, M.R.; Creedon, W.P.; O' Hea, B.J. [General Atomic (United States)

    2000-07-01

    Superconducting DC homopolar motors have undergone recent advances in technology, warranting serious consideration of their use for ship propulsion. Homopolar motor propulsion is now practical because of two key technology developments: cryogen-free superconducting refrigeration and high performance motor fiber brushes. These compact motors are ideal for podded applications, where reduced drag and fuel consumption are predicted. In addition, the simple DC motor controller is more efficient and reliable compared with AC motor controllers. Military ships also benefit from increased stealth implicit in homopolar DC excitation, which also allows the option for direct hull or pod mounting. (authors)

  8. 40 CFR 80.535 - How are NRLM diesel fuel credits generated?

    Science.gov (United States)

    2010-07-01

    ... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive... the standards of § 80.510(a) or (b). V520 = The total volume of motor vehicle diesel fuel produced or... generated by both a foreign refiner and by an importer for the same motor vehicle diesel fuel. (iii) Credits...

  9. Building a bio-based industry in the Middle East through harnessing the potential of the Red Sea biodiversity

    KAUST Repository

    Nielsen, Jens; Archer, John A.C.; Essack, Magbubah; Bajic, Vladimir B.; Gojobori, Takashi; Mijakovic, Ivan

    2017-01-01

    The incentive for developing microbial cell factories for production of fuels and chemicals comes from the ability of microbes to deliver these valuable compounds at a reduced cost and with a smaller environmental impact compared to the analogous chemical synthesis. Another crucial advantage of microbes is their great biological diversity, which offers a much larger “catalog” of molecules than the one obtainable by chemical synthesis. Adaptation to different environments is one of the important drives behind microbial diversity. We argue that the Red Sea, which is a rather unique marine niche, represents a remarkable source of biodiversity that can be geared towards economical and sustainable bioproduction processes in the local area and can be competitive in the international bio-based economy. Recent bioprospecting studies, conducted by the King Abdullah University of Science and Technology, have established important leads on the Red Sea biological potential, with newly isolated strains of Bacilli and Cyanobacteria. We argue that these two groups of local organisms are currently most promising in terms of developing cell factories, due to their ability to operate in saline conditions, thus reducing the cost of desalination and sterilization. The ability of Cyanobacteria to perform photosynthesis can be fully exploited in this particular environment with one of the highest levels of irradiation on the planet. We highlight the importance of new experimental and in silico methodologies needed to overcome the hurdles of developing efficient cell factories from the Red Sea isolates.

  10. Building a bio-based industry in the Middle East through harnessing the potential of the Red Sea biodiversity.

    Science.gov (United States)

    Nielsen, Jens; Archer, John; Essack, Magbubah; Bajic, Vladimir B; Gojobori, Takashi; Mijakovic, Ivan

    2017-06-01

    The incentive for developing microbial cell factories for production of fuels and chemicals comes from the ability of microbes to deliver these valuable compounds at a reduced cost and with a smaller environmental impact compared to the analogous chemical synthesis. Another crucial advantage of microbes is their great biological diversity, which offers a much larger "catalog" of molecules than the one obtainable by chemical synthesis. Adaptation to different environments is one of the important drives behind microbial diversity. We argue that the Red Sea, which is a rather unique marine niche, represents a remarkable source of biodiversity that can be geared towards economical and sustainable bioproduction processes in the local area and can be competitive in the international bio-based economy. Recent bioprospecting studies, conducted by the King Abdullah University of Science and Technology, have established important leads on the Red Sea biological potential, with newly isolated strains of Bacilli and Cyanobacteria. We argue that these two groups of local organisms are currently most promising in terms of developing cell factories, due to their ability to operate in saline conditions, thus reducing the cost of desalination and sterilization. The ability of Cyanobacteria to perform photosynthesis can be fully exploited in this particular environment with one of the highest levels of irradiation on the planet. We highlight the importance of new experimental and in silico methodologies needed to overcome the hurdles of developing efficient cell factories from the Red Sea isolates.

  11. Building a bio-based industry in the Middle East through harnessing the potential of the Red Sea biodiversity

    KAUST Repository

    Nielsen, Jens

    2017-05-20

    The incentive for developing microbial cell factories for production of fuels and chemicals comes from the ability of microbes to deliver these valuable compounds at a reduced cost and with a smaller environmental impact compared to the analogous chemical synthesis. Another crucial advantage of microbes is their great biological diversity, which offers a much larger “catalog” of molecules than the one obtainable by chemical synthesis. Adaptation to different environments is one of the important drives behind microbial diversity. We argue that the Red Sea, which is a rather unique marine niche, represents a remarkable source of biodiversity that can be geared towards economical and sustainable bioproduction processes in the local area and can be competitive in the international bio-based economy. Recent bioprospecting studies, conducted by the King Abdullah University of Science and Technology, have established important leads on the Red Sea biological potential, with newly isolated strains of Bacilli and Cyanobacteria. We argue that these two groups of local organisms are currently most promising in terms of developing cell factories, due to their ability to operate in saline conditions, thus reducing the cost of desalination and sterilization. The ability of Cyanobacteria to perform photosynthesis can be fully exploited in this particular environment with one of the highest levels of irradiation on the planet. We highlight the importance of new experimental and in silico methodologies needed to overcome the hurdles of developing efficient cell factories from the Red Sea isolates.

  12. Towards a sustainable bio-based economy: Redirecting primary metabolism to new products with plant synthetic biology.

    Science.gov (United States)

    Shih, Patrick M

    2018-08-01

    Humans have domesticated many plant species as indispensable sources of food, materials, and medicines. The dawning era of synthetic biology represents a means to further refine, redesign, and engineer crops to meet various societal and industrial needs. Current and future endeavors will utilize plants as the foundation of a bio-based economy through the photosynthetic production of carbohydrate feedstocks for the microbial fermentation of biofuels and bioproducts, with the end goal of decreasing our dependence on petrochemicals. As our technological capabilities improve, metabolic engineering efforts may expand the utility of plants beyond sugar feedstocks through the direct production of target compounds, including pharmaceuticals, renewable fuels, and commodity chemicals. However, relatively little work has been done to fully realize the potential in redirecting central carbon metabolism in plants for the engineering of novel bioproducts. Although our ability to rationally engineer and manipulate plant metabolism is in its infancy, I highlight some of the opportunities and challenges in applying synthetic biology towards engineering plant primary metabolism. Copyright © 2018 Elsevier B.V. All rights reserved.

  13. Macro-economic Impact Study for Bio-based Malaysia

    NARCIS (Netherlands)

    Meijl, van H.; Smeets, E.M.W.; Dijk, van M.; Powell, J.P.; Tabeau, A.A.

    2012-01-01

    This Macro-economic Impact Study (MES) provides quantitative insights into the macro-economic effects of introducing green, palmbased alternatives for electricity, fuels, chemicals and materials industries in Malaysia between now and 2030.

  14. Hydrogen Fuel Cell Vehicles

    OpenAIRE

    Anton Francesch, Judit

    1992-01-01

    Hydrogen is an especially attractive transportation fuel. It is the least polluting fuel available, and can be produced anywhere there is water and a clean source of electricity. A fuel cycle in which hydrogen is produced by solar-electrolysis of water, or by gasification of renewably grown biomass, and then used in a fuel-cell powered electric-motor vehicle (FCEV), would produce little or no local, regional, or global pollution. Hydrogen FCEVs would combine the best features of bat...

  15. 40 CFR 80.608 - What requirements apply to diesel fuel and ECA marine fuel for use in the Territories?

    Science.gov (United States)

    2010-07-01

    ... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Exemptions... sulfur standards of § 80.520(a)(1) and (c) related to motor vehicle diesel fuel, of § 80.510(a), (b), and... 40 Protection of Environment 16 2010-07-01 2010-07-01 false What requirements apply to diesel fuel...

  16. Feasibility Study for the Use of Green, Bio-Based, Efficient Reactive Sorbent Material to Neutralize Chemical Warfare Agents

    Science.gov (United States)

    2012-08-02

    REPORT Feasibility study for the use of green, bio-based, efficient reactive sorbent material to neutralize chemical warfare agents 14. ABSTRACT 16...way cellulose, lignin and hemicelluloses interact as well as whole wood dissolution occurs in ILs. The present project was conducted to 1. REPORT...Feasibility study for the use of green, bio-based, efficient reactive sorbent material to neutralize chemical warfare agents Report Title ABSTRACT Over the

  17. Proposed Rule for Control of Air Pollution From New Motor Vehicles: Proposed Heavy-Duty Engine and Vehicle Standards and Highway Diesel Fuel Sulfur Control Requirements

    Science.gov (United States)

    Rule summary, CFR citations and additional resources concerning proposed new emission standards that will begin to take effect in 2007 and corresponding diesel fuel requirements that take effect in 2006.

  18. Investigation of the influence of physical and chemical properties of biodiesel in the fuel economy, energy and environmental performance of motor diesel

    Directory of Open Access Journals (Sweden)

    Korpach А.

    2016-08-01

    Full Text Available Due to exhaustion of world energy reserves and significant environmental pollution by harmful substances, current research aimed at determining the effectiveness of alternative fuels. In the article compare two samples of biodiesel and studied their physical and chemical properties accordance with International Standard. Effect of different samples of biodiesel in fuel economy, energy and environmental performance automotive diesel determined by the bench tests of 4CH11,0/12.5 (D-241 diesel. The difference between physical and chemical properties of two biodiesel samples influenced to the fuel efficiency and environmental performance of the diesel. Operation on biodiesel with higher density and kinematic viscosity provide increases of maximum power and torque and increase fuel consumption. It also increases the concentration of nitrogen oxides in exhaust gases and it opacity. The results allow evaluate how the deviation of physical and chemical properties of biodiesel could affect the operational performance of the engine.

  19. Characteristics of a tractor engine using mineral and biodiesel fuels blended with rapeseed oil Características de um motor de trator alimentado com combustíveis mineral e biodisel misturados com óleo de colza

    Directory of Open Access Journals (Sweden)

    Tone Godeša

    2010-10-01

    Full Text Available One of the most unfavourable characteristics of crude vegetable oil when used as the fuel is the high viscosity. To improve this weakness, oil can be blended with mineral diesel or biodiesel fuels. This study was designed to evaluate how the use of mineral diesel or biodiesel blend with cold pressed rapeseed (Brassica napus oil affects the engine power, torque and fuel consumption. A tractor equipped with direct injection, water cooling system and three-cylinder diesel engine was used for the experiment. Fuels used were standard diesel fuel (diesel, rapeseed oil methyl ester - biodiesel (B100 and their mixtures with 10, 30 and 50 vol. % of cold pressed rapeseed oil (RO. Increased portion of RO in diesel fuel blends had almost no effect on the torque measured on the tractor PTO shaft; it however decreased the maximal power. Fuel blends with B100 and rising RO content (up to 50% gave a positive correlation with maximal torque and power. By increasing the portion of RO from 0 to 50%, the minimal specific fuel consumption increased by 6.65% with diesel and decreased by 2.98% with B100 based fuel.Uma das características mais desfavoráveis dos óleos vegetais crus usados como combustível é a alta viscosidade. Para melhorar este ponto fraco, o óleo pode ser misturado com diesel mineral ou biodiesel. Este estudo foi desenvolvido para avaliar como o uso de diesel mineral ou biodiesel misturado a oleo de colza (Brassica napus extraído por pressão a frio afeta a potência do motor, o torque e o consumo de combustível, empregando um trator equipado com injeção direta, sistema de refrigeração de água e um motor de três cilindros. Os combustíveis utilizados foram o diesel padrão (diesel, éster metílico de óleo de sementes de colza - biodiesel (B100 e suas misturas com 10, 30 e 50 % vol. de óleo de semente de colza pressionado a frio (RO. Maiores proporções de RO nas misturas de diesel praticamente não tiveram efeito sobre o torque

  20. Microgeneration of electricity with producer gas in dual fuel mode operation Microgeração de eletricidade com gás de gaseificação num motor gerador dual

    Directory of Open Access Journals (Sweden)

    Marcelo J. Silva

    2011-10-01

    Full Text Available Among the alternatives to meet the increasing of world demand for energy, the use of biomass as energy source is one of the most promising as it contributes to reducing emissions of carbon dioxide in the atmosphere. Gasification is a technological process of biomass energy production of a gaseous biofuel. The fuel gas has a low calorific value that can be used in Diesel engine in dual mode for power generation in isolated communities. This study aimed to evaluate the reduction in the consumption of oil Diesel an engine generator, using gas from gasification of wood. The engine generator brand used was a BRANCO, with direct injection power of 7.36 kW (10 HP coupled to an electric generator 5.5 kW. Diesel oil mixed with intake air was injected, as the oil was injected via an injector of the engine (dual mode. The fuel gas was produced in a downdraft gasifier. The engine generator was put on load system from 0.5 kW to 3.5 kW through a set of electrical resistances. Diesel oil consumption was measured with a precision scale. It was concluded that the engine converted to dual mode when using the gas for the gasification of wood decreased Diesel consumption by up to 57%.Dentre as alternativas à crescente demanda energética mundial, o uso da biomassa como fonte de energia é uma das formas mais promissoras, pois contribui para a redução das emissões de dióxido de carbono na atmosfera. A gaseificação é uma tecnologia de transformação energética da biomassa num biocombustível gasoso. O gás de gaseificação é um combustível de baixo poder calorífico que pode ser utilizado em motor ciclo Diesel no modo dual para geração de energia elétrica em comunidades isoladas. Este trabalho teve por objetivo avaliar a redução no consumo de Diesel num motor gerador, com a utilização de gás da gaseificação da madeira. O motor avaliado foi da marca BRANCO, com injeção direta e potência de 7,36 kW (10 cv acoplado a um gerador elétrico de 5

  1. Project of multiple controller models for the maintenance of air/fuel ratio in natural gas internal combustion motors; Projeto de controladores multiplos modelos para manutencao da relacao ar/combustivel em motores de combustao interna movidos a gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Freitas Junior, Fernando Sousa e; Fleury, Agenor de Toledo [Sao Paulo Univ. SP (Brazil). Escola Politecnica. Dept. de Engenharia Mecanica]. E-mails: ffreitas@usp.br; agfleury@ipt.br

    2006-07-01

    The objective of this work is the study of advanced control techniques for the reduction of pollutant gases generated by internal combustion engines powered by natural gas. In this paper three techniques are applied to control the fuel injection and the ignition timing: the Generalized Predictive Control (GPC), the Linear Quadratic Regulator (LQR) and H{infinity} Control by Linear Matrix Inequalities (LMI). To each one of those techniques were developed a multiple model structure seeking to include the vast operation region of the engine. The controller's performance is measured by the efficiency in maintaining the fuel/air ratio around 1% of maximum deviation in relation to the stoichiometric value. The results show the possibility of controlling pollutant emission generated by this kind of engine to conform to international emission standards, improving life quality. (author)

  2. Characteristic parameters in the measurement of (14)C of biobased diesel fuels by liquid scintillation.

    Science.gov (United States)

    Idoeta, R; Pérez, E; Herranz, M; Legarda, F

    2014-11-01

    The direct method based on the radiocarbon content present in modern-day materials used for the quantification of the renewable origin component in diesel has been analysed in order to establish the best sample preparation and measuring conditions that minimise the limit of detection. The scintillation cocktail and the diesel/cocktail ratio have been optimised. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Comportamento de um motor de ignição por compressão trabalhando com óleo Diesel e gás natural A dual fuel compression ignition engine performance, running with Diesel fuel and natural gas

    Directory of Open Access Journals (Sweden)

    José F. Schlosser

    2004-12-01

    Full Text Available A previsível escassez de petróleo aliada a uma consciência ecológica está levando pesquisadores a procurar novas fontes de energia e processos de combustão mais eficientes e menos poluentes. Entre os combustíveis menos poluentes está o gás natural, cujo consumo aumenta ano a ano. Os motores de combustão interna são transformadores de energia que têm baixa eficiência de conversão. Este trabalho avaliou um motor Diesel, bicombustível, movido a Diesel e gás natural. Nesse motor, a energia provém, basicamente, da combustão do gás natural. O Diesel tem a função de produzir o início da combustão do gás, que é o combustível principal. Assim, haverá uma substituição parcial de óleo Diesel por gás natural, aumentando o rendimento da combustão. Inicialmente, foi feito um ensaio-testemunha, somente com óleo Diesel e após foram feitos ensaios, com três repetições, para variadas proporções de óleo Diesel, gás natural e ângulos de avanço da injeção. O melhor desempenho foi obtido para 22% de óleo Diesel em relação ao máximo débito da bomba injetora e 13 L min-1 de gás natural com ângulo de avanço de injeção original (21º. Nesse caso, a potência média aumentou 14%, e o consumo específico (medido em valores monetários diminuiu 46% em relação ao ensaio-testemunha.The foresight of a petroleum shortage and an ecological conscience is moving scientists to look for new sources of energy and to develop more efficient combustion processes and reduced emissions. Natural gas is a reduced emission fuel, whose consumption increases every year. The present work evaluates a dual fuel compression ignition engine. The major portion of the fuel burned is natural gas. The Diesel fuel acts as combustion starter, which ignites under the compression heat. Diesel fuel is used only as an ignition source. The partial substitution of Diesel fuel by natural gas increases the combustion efficiency and achieves significant

  4. 26 CFR 48.4041-7 - Dual use of taxable liquid fuel.

    Science.gov (United States)

    2010-04-01

    ... taxable liquid fuel. Tax applies to all taxable liquid fuel sold for use or used as a fuel in the motor which is used to propel a diesel-powered vehicle or in the motor used to propel a motor vehicle... vehicle, motorboat, or aircraft. Thus, if the motor of a diesel-powered highway vehicle or a motorboat...

  5. Coupling chemical and biological catalysis: a flexible paradigm for producing biobased chemicals.

    Science.gov (United States)

    Schwartz, Thomas J; Shanks, Brent H; Dumesic, James A

    2016-04-01

    Advances in metabolic engineering have allowed for the development of new biological catalysts capable of selectively de-functionalizing biomass to yield platform molecules that can be upgraded to biobased chemicals using high efficiency continuous processing allowed by heterogeneous chemical catalysis. Coupling these disciplines overcomes the difficulties of selectively activating COH bonds by heterogeneous chemical catalysis and producing petroleum analogues by biological catalysis. We show that carboxylic acids, pyrones, and alcohols are highly flexible platforms that can be used to produce biobased chemicals by this approach. More generally, we suggest that molecules with three distinct functionalities may represent a practical upper limit on the extent of functionality present in the platform molecules that serve as the bridge between biological and chemical catalysis. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Going greener: Synthesis of fully biobased unsaturated polyesters for styrene crosslinked resins with enhanced thermomechanical properties

    Directory of Open Access Journals (Sweden)

    C. S. M. F. Costa

    2017-11-01

    Full Text Available The main goal of this work was the development of fully biobased unsaturated polyesters (UPs that upon crosslinking with unsaturated monomers (UM could lead to greener unsaturated polyester resins (UPRs with similar thermomechanical properties to commercial fossil based UPR. After the successful synthesis of the biobased UPs, those were crosslinked with styrene (Sty, the most commonly used monomer, and the influence of the chemical structure of the UPs on the thermomechanical characteristics of UPRs were evaluated. The properties were compared with those of a commercial resin (Resipur 9837©. The BioUPRs presented high gel contents and contact angles that are similar to the commercial resin. The thermomechanical properties were evaluated by dynamic mechanical thermal analysis (DMTA and it was found that the UPR synthesized using propylene glycol (PG, succinic acid (SuAc and itaconic acid (ItAc presented very close thermomechanical properties compared to the commercial resin.

  7. The Closure of the Cycle: Enzymatic Synthesis and Functionalization of Bio-Based Polyesters.

    Science.gov (United States)

    Pellis, Alessandro; Herrero Acero, Enrique; Ferrario, Valerio; Ribitsch, Doris; Guebitz, Georg M; Gardossi, Lucia

    2016-04-01

    The polymer industry is under pressure to mitigate the environmental cost of petrol-based plastics. Biotechnologies contribute to the gradual replacement of petrol-based chemistry and the development of new renewable products, leading to the closure of carbon circle. An array of bio-based building blocks is already available on an industrial scale and is boosting the development of new generations of sustainable and functionally competitive polymers, such as polylactic acid (PLA). Biocatalysts add higher value to bio-based polymers by catalyzing not only their selective modification, but also their synthesis under mild and controlled conditions. The ultimate aim is the introduction of chemical functionalities on the surface of the polymer while retaining its bulk properties, thus enlarging the spectrum of advanced applications. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. Technological change of the energy innovation system: From oil-based to bio-based energy

    International Nuclear Information System (INIS)

    Wonglimpiyarat, Jarunee

    2010-01-01

    This paper concerns the structural developments and the direction of technological change of the energy innovation system, based on the studies of Kuhn's model of scientific change and Schumpeter's model of technological change. The paper uses the case study of Thai government agencies for understanding the way governments can facilitate technological innovation. The analyses are based on a pre-foresight exercise to examine the potential of the bio-based energy and investigate a set of development policies necessary for the direction of energy system development. The results have shown that bio-based energy is seen as the next new wave for future businesses and one of the solutions to the problem of high oil prices to improve the world's economic security and sustainable development. (author)

  9. Six recommendations for a bio-based economy in the Netherlands

    International Nuclear Information System (INIS)

    Van der Hoeven, D.

    2009-03-01

    The Bio-based Raw Materials Platform (PGG), part of the Energy Transition in The Netherlands, commissioned the Agricultural Economics Research Institute (LEI) and the Copernicus Institute of Utrecht University to conduct research on the macro-economic impact of large scale deployment of biomass for energy and materials in the Netherlands. Two model approaches were applied based on a consistent set of scenario assumptions: a bottom-up study including technoeconomic projections of fossil and bio-based conversion technologies and a topdown study including macro-economic modelling of (global) trade of biomass and fossil resources. The results of the top-down and bottom-up modelling work are reported separately. Based on the results of the studies the platform formulated six recommendations [nl

  10. Biotechnological Perspectives of Pyrolysis Oil for a Bio-Based Economy.

    Science.gov (United States)

    Arnold, Stefanie; Moss, Karin; Henkel, Marius; Hausmann, Rudolf

    2017-10-01

    Lignocellulosic biomass is an important feedstock for a potential future bio-based economy. Owing to its compact structure, suitable decomposition technologies will be necessary to make it accessible for biotechnological conversion. While chemical and enzymatic hydrolysis are currently established methods, a promising alternative is provided by fast pyrolysis. The main resulting product thereof, referred to as pyrolysis oil, is an energy-rich and easily transportable liquid. Many of the identified constituents of pyrolysis oil, however, have previously been reported to display adverse effects on microbial growth. In this Opinion we discuss relevant biological, biotechnological, and technological challenges that need to be addressed to establish pyrolysis oil as a reliable microbial feedstock for a bio-based economy of the future. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. A methodology to assess the contribution of biorefineries to a sustainable bio-based economy

    International Nuclear Information System (INIS)

    Maga, Daniel

    2015-01-01

    Within this thesis for the first time an integrative methodology to assess the sustainability of biorefineries and bio-based products has been developed which is based on a fundamental understanding of sustainability as presented in the Brundtland report. The applied integrative concept of sustainability as developed by the Institute for Technology Assessment and Systems Analysis (ITAS) overcomes the widespread thinking in three pillars of sustainability and opens up new perspectives. The methodology developed addresses innovative life cycle assessment evaluation methods on midpoint level as well as on the area of protection and adopts state-of-the-art assessment procedures e.g. to determine water deprivation. It goes far beyond the scope of conventional LCA studies and examines effects on human health, on the environment, on the development of knowledge and physical capital, and on regional development and acceptance. In order to validate the developed method it was applied to an algae biorefinery currently under development and construction in the south of Spain. For this assessment for the first time extensive process data was collected of a real algae biorefinery which uses municipal waste water as a culture medium for microalgae. The use of waste water allows to reduce the demand for fresh water and avoids additional fertilisation of microalgae. Moreover, the analysed algae biorefinery replaces conventional waste water treatment by a biological purification and produces biogas by an anaerobic pretreatment of waste water as well as by anaerobic digestion of algae. After several purification steps the biogas can be used as automotive fuel and thus contributes to further development and increased use of biofuels. On the one hand the sustainability assessment shows that this way of waste water treatment contributes to climate protection and to the conservation of fossil energy carrier. On the other hand approximately ten times more land is needed and twenty times

  12. A methodology to assess the contribution of biorefineries to a sustainable bio-based economy

    Energy Technology Data Exchange (ETDEWEB)

    Maga, Daniel

    2015-07-01

    Within this thesis for the first time an integrative methodology to assess the sustainability of biorefineries and bio-based products has been developed which is based on a fundamental understanding of sustainability as presented in the Brundtland report. The applied integrative concept of sustainability as developed by the Institute for Technology Assessment and Systems Analysis (ITAS) overcomes the widespread thinking in three pillars of sustainability and opens up new perspectives. The methodology developed addresses innovative life cycle assessment evaluation methods on midpoint level as well as on the area of protection and adopts state-of-the-art assessment procedures e.g. to determine water deprivation. It goes far beyond the scope of conventional LCA studies and examines effects on human health, on the environment, on the development of knowledge and physical capital, and on regional development and acceptance. In order to validate the developed method it was applied to an algae biorefinery currently under development and construction in the south of Spain. For this assessment for the first time extensive process data was collected of a real algae biorefinery which uses municipal waste water as a culture medium for microalgae. The use of waste water allows to reduce the demand for fresh water and avoids additional fertilisation of microalgae. Moreover, the analysed algae biorefinery replaces conventional waste water treatment by a biological purification and produces biogas by an anaerobic pretreatment of waste water as well as by anaerobic digestion of algae. After several purification steps the biogas can be used as automotive fuel and thus contributes to further development and increased use of biofuels. On the one hand the sustainability assessment shows that this way of waste water treatment contributes to climate protection and to the conservation of fossil energy carrier. On the other hand approximately ten times more land is needed and twenty times

  13. Environmental impacts of producing bioethanol and biobased lactic acid from standalone and integrated biorefineries using a consequential and an attributional life cycle assessment approach.

    Science.gov (United States)

    Parajuli, Ranjan; Knudsen, Marie Trydeman; Birkved, Morten; Djomo, Sylvestre Njakou; Corona, Andrea; Dalgaard, Tommy

    2017-11-15

    This study evaluates the environmental impacts of biorefinery products using consequential (CLCA) and attributional (ALCA) life cycle assessment (LCA) approaches. Within ALCA, economic allocation method was used to distribute impacts among the main products and the coproducts, whereas within the CLCA system expansion was adopted to avoid allocation. The study seeks to answer the questions (i) what is the environmental impacts of process integration?, and (ii) do CLCA and ALCA lead to different conclusions when applied to biorefinery?. Three biorefinery systems were evaluated and compared: a standalone system producing bioethanol from winter wheat-straw (system A), a standalone system producing biobased lactic acid from alfalfa (system B), and an integrated biorefinery system (system C) combining the two standalone systems and producing both bioethanol and lactic acid. The synergy of the integration was the exchange of useful energy necessary for biomass processing in the two standalone systems. The systems were compared against a common reference flow: "1MJ EtOH +1kg LA ", which was set on the basis of products delivered by the system C. Function of the reference flow was to provide service of both fuel (bioethanol) at 99.9% concentration (wt. basis) and biochemical (biobased lactic acid) in food industries at 90% purity; both products delivered at biorefinery gate. The environmental impacts of interest were global warming potential (GWP 100 ), eutrophication potential (EP), non-renewable energy (NRE) use and the agricultural land occupation (ALO). Regardless of the LCA approach adopted, system C performed better in most of the impact categories than both standalone systems. The process wise contribution to the obtained environmental impacts also showed similar impact pattern in both approaches. The study also highlighted that the recirculation of intermediate materials, e.g. C 5 sugar to boost bioethanol yield and that the use of residual streams in the energy

  14. Performance of palm oil as a biobased machining lubricant when drilling inconel 718

    OpenAIRE

    Abd Rahim Erween; Sasahara Hiroyuki

    2017-01-01

    Metalworking fluid acts as cooling and lubrication agent at the cutting zone in the machining process. However, conventional Metalworking fluid such mineral oil gives negative impact on the human and environment. Therefore, the manufacture tends to substitute the mineral oil to bio-based oil such as vegetables and synthetic oil. In this paper, the drilling experiment was carried out to evaluate the efficiency of palm oil and compare it with minimal quantity lubrication technique using synthet...

  15. The use of bio-based materials to reduce the environmental impact of construction

    OpenAIRE

    Lawrence, Michael

    2014-01-01

    In the UK, the construction industry is responsible for over 50 % of total carbon emissions. 20% of these carbon emissions are embodied within the construction and materials of buildings and the balance is expended in environmental control (heating, lighting, air conditioning) and other ‘in use’ aspects of occupation of buildings. This is replicated in other countries to a similar extent. This lecture identifies ways in which the use of bio-based construction materials can significantly reduc...

  16. Biodegradable and bio-based polymers: future prospects of eco-friendly plastics.

    Science.gov (United States)

    Iwata, Tadahisa

    2015-03-09

    Currently used plastics are mostly produced from petrochemical products, but there is a growing demand for eco-friendly plastics. The use of bio-based plastics, which are produced from renewable resources, and biodegradable plastics, which are degraded in the environment, will lead to a more sustainable society and help us solve global environmental and waste management problems. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Gallic acid as an oxygen scavenger in bio-based multilayer packaging films

    OpenAIRE

    Pant, Astrid; Sängerlaub, Sven; Müller, Kajetan

    2017-01-01

    Oxygen scavengers are used in food packaging to protect oxygen-sensitive food products. A mixture of gallic acid (GA) and sodium carbonate was used as an oxygen scavenger (OSc) in bio-based multilayer packaging films produced in a three-step process: compounding, flat film extrusion, and lamination. We investigated the film surface color as well as oxygen absorption at different relative humidities (RHs) and temperatures, and compared the oxygen absorption of OSc powder, monolayer films, and ...

  18. Production and 3D printing processing of bio-based thermoplastic filament

    OpenAIRE

    Gkartzou, Eleni; Koumoulos, Elias P.; Charitidis, Costas A.

    2017-01-01

    In this work, an extrusion-based 3D printing technique was employed for processing of biobased blends of Poly(Lactic Acid) (PLA) with low-cost kraft lignin. In Fused Filament Fabrication (FFF) 3D printing process, objects are built in a layer-by-layer fashion by melting, extruding and selectively depositing thermoplastic fibers on a platform. These fibers are used as building blocks for more complex structures with defined microarchitecture, in an automated, cost-effective process, with minim...

  19. Design methodology for bio-based processing: Biodiesel and fatty alcohol production

    DEFF Research Database (Denmark)

    Simasatikul, Lida; Arpornwichanop, Amornchai; Gani, Rafiqul

    2012-01-01

    A systematic design methodology is developed for producing two main products plus side products starting with one or more bio-based renewable source. A superstructure that includes all possible reaction and separation operations is generated through thermodynamic insights and available data. The ....... Economic analysis and net present value are determined to find the best economically and operationally feasible process. The application of the methodology is presented through a case study involving biodiesel and fatty alcohol productions....

  20. Design methodology for bio-based processing: Biodiesel and fatty alcohol production

    DEFF Research Database (Denmark)

    Simasatikul, Lida; Arpornwichanopa, Amornchai; Gani, Rafiqul

    2013-01-01

    A systematic design methodology is developed for producing multiple main products plus side products starting with one or more bio-based renewable source. A superstructure that includes all possible reaction and separation operations is generated through thermodynamic insights and available data........ Economic analysis and net present value are determined to find the best economically and operationally feasible process. The application of the methodology is presented through a case study involving biodiesel and fatty alcohol productions....

  1. Biobased production of alkanes and alkenes through metabolic engineering of microorganisms

    OpenAIRE

    Kang, Min Kyoung; Nielsen, Jens

    2017-01-01

    Advancement in metabolic engineering of microorganisms has enabled bio-based production of a range of chemicals, and such engineered microorganism can be used for sustainable production leading to reduced carbon dioxide emission there. One area that has attained much interest is microbial hydrocarbon biosynthesis, and in particular, alkanes and alkenes are important high-value chemicals as they can be utilized for a broad range of industrial purposes as well as ?drop-in? biofuels. Some microo...

  2. Bio-based composites from stone groundwood applied to new product development

    OpenAIRE

    Julián Pérez, Fernando; Méndez González, José Alberto; Espinach Orús, Xavier; Verdaguer Pujadas, Narcís; Mutjé Pujol, Pere; Vilaseca Morera, Fabiola

    2012-01-01

    This paper deals with the product design, engineering, and material selection intended for the manufacturing of an eco-friendly chair. The final product is expected to combine design attributes with technical and legal feasibility with the implementation of new bio-based materials. Considering the industrial design, a range of objectives and trends were determined after setting the market requirements, and the final concept was proposed and modeled. The product geometry, production technology...

  3. Deep desulfurization of hydrocarbon fuels

    Science.gov (United States)

    Song, Chunshan [State College, PA; Ma, Xiaoliang [State College, PA; Sprague, Michael J [Calgary, CA; Subramani, Velu [State College, PA

    2012-04-17

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  4. Roadmap for Bioenergy and Biobased Products in the United States

    Science.gov (United States)

    2007-10-01

    improved agronomic practices, and the efficient and enviromentally conscious use of chemical and natural inputs. The focus should be primarily on grain and...rapidly growing industry will need over the next 10 years. It will be challenging to produce the scientists, engineers , and technological operations...fueling infrastructure. Target 30 percent of U.S. stations in five years. • Provide policy incentives to drive 50 percent of spark ignition engine

  5. The electric motor handbook

    Energy Technology Data Exchange (ETDEWEB)

    Hurst, R.W.; Feltham, P. (eds.)

    2004-05-01

    This handbook outlines the important role that electric motors play in modern society. It covers the field of motor applications from various motor types to their use and repair. It also presents practical applications of electric motors and methods on motor efficiency. More than half of all electricity generated, and 75 per cent of all industrial electricity consumption is consumed by electric motors. Electrical personnel must be aware of all factors involved in electric motors in order to choose and apply the appropriate size of electric motor. These factors include efficiency, sizing and proper application. The efficient use and maximum life expectancy of electric motors depends on proper motor protection, control and maintenance. This handbook includes articles from leading experts on electric motors in modern electrical systems. The content includes: design considerations; proper electric motor sizing techniques; optimal electric motor application; electric motor protection technology; electric motor control principles; electric motor maintenance and troubleshooting; induction electric motors; electric motor bearing currents; electric motor bearing lubrication; electromagnetism; electric motor enclosures; electric motor testing; electric motor repair; DC electric motor; electric motor starters; electric motor brushes; industrial electric motors; electric motor diagrams; AC electric motors; electric motor wiring; electric motor service; electric motor rewinding; electric motor winding; diagram of electric motor wiring; electric motor kit; and, troubleshooting electric motors. A directory of motor manufacturers and suppliers was also included. refs., tabs., figs.

  6. Bioethanol: fuel or feedstock?

    DEFF Research Database (Denmark)

    Rass-Hansen, Jeppe; Falsig, Hanne; Jørgensen, Betina

    2007-01-01

    Increasing amounts of bioethanol are being produced from fermentation of biomass, mainly to counteract the continuing depletion of fossil resources and the consequential escalation of oil prices. Today, bioethanol is mainly utilized as a fuel or fuel additive in motor vehicles, but it could also...

  7. 3D printing of new biobased unsaturated polyesters by microstereo-thermal-lithography

    International Nuclear Information System (INIS)

    Gonçalves, Filipa A M M; Costa, Cátia S M F; Fabela, Inês G P; Simões, Pedro N; Serra, Arménio C; Coelho, Jorge F J; Farinha, Dina; Faneca, Henrique; Bártolo, Paulo J

    2014-01-01

    New micro three-dimensional (3D) scaffolds using biobased unsaturated polyesters (UPs) were prepared by microstereo-thermal-lithography (μSTLG). This advanced processing technique offers indubitable advantages over traditional printing methods. The accuracy and roughness of the 3D structures were evaluated by scanning electron microscopy and infinite focus microscopy, revealing a suitable roughness for cell attachment. UPs were synthesized by bulk polycondensation between biobased aliphatic diacids (succinic, adipic and sebacic acid) and two different glycols (propylene glycol and diethylene glycol) using fumaric acid as the source of double bonds. The chemical structures of the new oligomers were confirmed by proton nuclear magnetic resonance spectra, attenuated total reflectance Fourier transform infrared spectroscopy and matrix assisted laser desorption/ionization-time of flight mass spectrometry. The thermal and mechanical properties of the UPs were evaluated to determine the influence of the diacid/glycol ratio and the type of diacid in the polyester’s properties. In addition an extensive thermal characterization of the polyesters is reported. The data presented in this work opens the possibility for the use of biobased polyesters in additive manufacturing technologies as a route to prepare biodegradable tailor made scaffolds that have potential applications in a tissue engineering area. (paper)

  8. Computational Methods to Assess the Production Potential of Bio-Based Chemicals.

    Science.gov (United States)

    Campodonico, Miguel A; Sukumara, Sumesh; Feist, Adam M; Herrgård, Markus J

    2018-01-01

    Elevated costs and long implementation times of bio-based processes for producing chemicals represent a bottleneck for moving to a bio-based economy. A prospective analysis able to elucidate economically and technically feasible product targets at early research phases is mandatory. Computational tools can be implemented to explore the biological and technical spectrum of feasibility, while constraining the operational space for desired chemicals. In this chapter, two different computational tools for assessing potential for bio-based production of chemicals from different perspectives are described in detail. The first tool is GEM-Path: an algorithm to compute all structurally possible pathways from one target molecule to the host metabolome. The second tool is a framework for Modeling Sustainable Industrial Chemicals production (MuSIC), which integrates modeling approaches for cellular metabolism, bioreactor design, upstream/downstream processes, and economic impact assessment. Integrating GEM-Path and MuSIC will play a vital role in supporting early phases of research efforts and guide the policy makers with decisions, as we progress toward planning a sustainable chemical industry.

  9. Assessing the Economic Viability of Bio-based Products for Missouri Value-added Crop Production

    Energy Technology Data Exchange (ETDEWEB)

    Nicholas Kalaitzandonakes

    2005-11-30

    While research and development on biobased products has continued strong over the years, parallel attention on the economics and management of such product innovation has been lacking. With the financial support of the Department of Energy, the Economics and Management of Agrobiotechnology Center at the University of Missouri-Columbia has launched a pilot graduate education program that seeks to fill the gap. Within this context, a multi-disciplinary research and teaching program has been structured with an emphasis on new product and innovation economics and management. More specifically, this pilot graduate education program has the following major objectives: (1) To provide students with a strong background in innovation economics, management, and strategy. (2) To diversify the students academic background with coursework in science and technology. (3) To familiarize the student with biobased policy initiatives through interaction with state and national level organizations and policymakers. (4) To facilitate active collaboration with industry involved in the development and production of biobased products. The pilot education program seeks to develop human capital and research output. Although the research is, initially, focused on issues related to the State of Missouri, the results are expected to have national implications for the economy, producers, consumers and environment.

  10. 40 CFR 80.521 - What are the standards and identification requirements for diesel fuel additives?

    Science.gov (United States)

    2010-07-01

    ... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Motor... consumer in diesel motor vehicles or nonroad diesel engines. [69 FR 39171, June 29, 2004] ... identification requirements for diesel fuel additives? 80.521 Section 80.521 Protection of Environment...

  11. 40 CFR 600.206-93 - Calculation and use of fuel economy values for gasoline-fueled, diesel-fueled, electric, alcohol...

    Science.gov (United States)

    2010-07-01

    ... EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1977 and Later Model Year Automobiles-Procedures... equivalent petroleum-based fuel economy value exists for an electric vehicle configuration, all values for... values for gasoline-fueled, diesel-fueled, electric, alcohol-fueled, natural gas-fueled, alcohol dual...

  12. Air pollution from motor vehicle emissions

    International Nuclear Information System (INIS)

    Petrushevska, Ljubica

    1996-01-01

    This paper presents some aspects of air pollution from motor vehicle emissions as: characteristic primary and secondary pollutants, dependence of the motor vehicle emission from the engine type; the relationship of typical engine emission and performance to air-fuel ratio, transport of pollutants from mobile sources of emissions, as well as some world experiences in the control approaches for exhaust emissions. (author)

  13. Motor homopolar

    OpenAIRE

    Martín Muñoz, Agustín

    2007-01-01

    Mostramos la construcción de un modelo de motor homopolar, uno de los más antiguos tipos de motores eléctricos. Se caracterizan porque el campo magnético del imán mantiene siempre la misma polaridad (de ahí su nombre, del griego homos, igual), de modo que, cuando una corriente eléctrica atraviesa el campo magnético, aparece una fuerza que hace girar los elementos no fijados mecánicamente. En el sencillísimo motor homopolar colgado (Schlichting y Ucke 2004), el imán puede girar ...

  14. ENIAK. Development of a non-motor injector coking test facility for alternative fuels; ENIAK. Entwicklung eines nichtmotorischen Injektorverkokungspruefstands fuer alternative Kraftstoffe

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, Hajo; Schloss, Heide vom; Yang, Zhi; Grote, Melanie [OWI Oel-Waerme-Institut GmbH, Aachen (Germany). Gruppe Anwendungstechnik

    2013-10-01

    Poor Biodiesel quality, contamination with copper and zinc as well as undesired reactions between (several) additives and biodiesel components are known causes for nozzle fouling. Therefore, among other things, all additives have to pass a no-harm test. The standard fouling tests are two engine tests: the XUD9-test (CEC F-23-01) and the DW-10-test (CEC DF 98-08). The XUD9 is a cost efficient, fast and proven testing method. It uses, however, an obsolete indirect injection diesel engine. The newer DW10 test is complex, costly and designed for high stress. This reduces the engine life and leads to a fuel consumption of approximately 1,000 l per test, both contributing to the high costs of the test. The main goal of the project ENIAK is the development, assembly, commissioning, and evaluation of a non-engine fuel injector test. It uses four complete common rail systems. The injection takes place in four self-designed reactors instead of an engine, and the fuel is not combusted, but re-condensed and pumped in a circle. If the test method proves to be as reliable as expected, it can be used as an alternative test method for injector fouling with low requirements regarding infrastructure on the testing site and sample volume. The project is funded by the the federal ministry of consumer protection, food and agriculture via FNR (''Fachagentur Nachwachsende Rohstoffe'', Agency for Renewable Resources). (orig.)

  15. Application of stepping motor

    International Nuclear Information System (INIS)

    1980-10-01

    This book is divided into three parts, which is about practical using of stepping motor. The first part has six chapters. The contents of the first part are about stepping motor, classification of stepping motor, basic theory og stepping motor, characteristic and basic words, types and characteristic of stepping motor in hybrid type and basic control of stepping motor. The second part deals with application of stepping motor with hardware of stepping motor control, stepping motor control by microcomputer and software of stepping motor control. The last part mentions choice of stepping motor system, examples of stepping motor, measurement of stepping motor and practical cases of application of stepping motor.

  16. Succinic acid production derived from carbohydrates: An energy and greenhouse gas assessment of a platform chemical toward a bio-based economy

    NARCIS (Netherlands)

    Cok, B.|info:eu-repo/dai/nl/371750679; Tsiropoulos, I.; Roes, A.L.|info:eu-repo/dai/nl/303022388; Patel, M.K.|info:eu-repo/dai/nl/18988097X

    2014-01-01

    Bio-based succinic acid has the potential to become a platform chemical, i.e. a key building block for deriving both commodity and high-value chemicals, which makes it an attractive compound in a bio-based economy. A few companies and industrial consortia have begun to develop its industrial

  17. The Recent Developments in Biobased Polymers toward General and Engineering Applications : Polymers that Are Upgraded from Biodegradable Polymers, Analogous to Petroleum-Derived Polymers, and Newly Developed

    NARCIS (Netherlands)

    Nakajima, Hajime; Dijkstra, Peter; Loos, Katja

    2017-01-01

    The main motivation for development of biobased polymers was their biodegradability, which is becoming important due to strong public concern about waste. Reflecting recent changes in the polymer industry, the sustainability of biobased polymers allows them to be used for general and engineering

  18. Unraveling Dutch citizens' perceptions on the bio-based economy : The case of bioplastics, bio-jetfuels and small-scale bio-refineries

    NARCIS (Netherlands)

    Lynch, Durwin H J; Klaassen, Pim; Broerse, Jacqueline E W

    2017-01-01

    Little is known about how citizens perceive the transition towards a bio-based economy (BBE), despite the fact that they are one of the most important actors in this transition. Citizens' perceptions of bio-based innovations can support policy-makers to improve the quality of decision-making and the

  19. Comparing biobased products from oil crops versus sugar crops with regard to non-renewable energy use, GHG emissions and land use

    NARCIS (Netherlands)

    Bos, Harriëtte L.; Meesters, Koen P.H.; Conijn, Sjaak G.; Corré, Wim J.; Patel, Martin K.

    2016-01-01

    Non-renewable energy use, greenhouse gas emissions and land use of two biobased products and biofuel from oil crops is investigated and compared with products from sugar crops. In a bio-based economy chemicals, materials and energy carriers will be produced from biomass. Next to side streams,

  20. Reactive Distillation for Esterification of Bio-based Organic Acids

    Energy Technology Data Exchange (ETDEWEB)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential

  1. 49 CFR 398.4 - Driving of motor vehicles.

    Science.gov (United States)

    2010-10-01

    .... Lighting devices and reflectors. Tires. Horn. Windshield wiper or wipers. Rear-vision mirror or mirrors.... No driver or any employee of a motor carrier shall: (1) Fuel a motor vehicle with the engine running, except when it is necessary to run the engine to fuel the vehicle; (2) Smoke or expose any open flame in...

  2. Process systems engineering studies for catalytic production of bio-based platform molecules from lignocellulosic biomass

    International Nuclear Information System (INIS)

    Han, Jeehoon

    2017-01-01

    Highlights: • A process-systems engineering study for production of bio-based platform molecules to is presented. • Experimentally verified catalysis studies for biomass conversion are investigated. • New separations for effective recovery of bio-based platform molecules are developed. • Separations are integrated with catalytic biomass conversions. • Proposed process can compete economically with the current production approaches. - Abstract: This work presents a process-system engineering study of an integrated catalytic conversion strategy to produce bio-based platform molecules (levulinic acid (LA), furfural (FF), and propyl guaiacol (PG)) from hemicellulose (C_5), cellulose (C_6), and lignin fractions of lignocellulosic biomass. A commercial-scale process based on the strategy produces high numerical carbon yields (overall yields: 35.2%; C_6-to-LA: 20.4%, C_5-to-FF: 69.2%, and Lignin-to-PG: 13.3%) from a dilute concentration of solute (1.3–30.0 wt.% solids), but a high recovery of these molecules requires an efficient separation system with low energy requirement. A heat exchanger network significantly reduced the total energy requirements of the process. An economic analysis showed that the minimum selling price of LA as the highest value-added product (42.3 × 10"3 t of LA/y using 700 × 10"3 dry t/y of corn stover) is US$1707/t despite using negative economic parameters, and that this system can be cost-competitive with current production approaches.

  3. Bio-based materials with novel characteristics for tissue engineering applications - A review.

    Science.gov (United States)

    Bedian, Luis; Villalba-Rodríguez, Angel M; Hernández-Vargas, Gustavo; Parra-Saldivar, Roberto; Iqbal, Hafiz M N

    2017-05-01

    Recently, a wider spectrum of bio-based materials and materials-based novel constructs and systems has been engineered with high interests. The key objective is to help for an enhanced/better quality of life in a secure way by avoiding/limiting various adverse effects of some in practice traditional therapies. In this context, different methodological approaches including in vitro, in vivo, and ex vivo techniques have been exploited, so far. Among them, bio-based therapeutic constructs are of supreme interests for an enhanced and efficient delivery in the current biomedical sector of the modern world. The development of new types of novel, effective and highly reliable materials-based novel constructs for multipurpose applications is essential and a core demand to tackle many human health related diseases. Bio-based materials possess several complementary functionalities, e.g. unique chemical structure, bioactivity, non-toxicity, biocompatibility, biodegradability, recyclability, etc. that position them well in the modern world's materials sector. In this context, the utilization of biomaterials provides extensive opportunities for experimentation in the field of interdisciplinary and multidisciplinary scientific research. With an aim to address the global dependence on petroleum-based polymers, researchers have been redirecting their interests to the engineering of biological materials for targeted applications in different industries including cosmetics, pharmaceuticals, and other biotechnological or biomedical applications. Herein, we reviewed biotechnological advancements at large and tissue engineering from a biomaterials perspective in particular and envision directions of future developments. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Isolation, Characterization, and Environmental Application of Bio-Based Materials as Auxiliaries in Photocatalytic Processes

    Directory of Open Access Journals (Sweden)

    Davide Palma

    2018-05-01

    Full Text Available Sustainable alternative substrates for advanced applications represent an increasing field of research that attracts the attention of worldwide experts (in accordance with green chemistry principles. In this context, bio-based substances (BBS isolated from urban composted biowaste were purified and characterized. Additionally, these materials were tested as auxiliaries in advanced oxidizing photocatalytic processes for the abatement of organic contaminants in aqueous medium. Results highlighted the capability of these substances to enhance efficiency in water remediation treatments under mild conditions, favoring the entire light-driven photocatalytic process.

  5. Top value platform chemicals: bio-based production of organic acids.

    Science.gov (United States)

    Becker, Judith; Lange, Anna; Fabarius, Jonathan; Wittmann, Christoph

    2015-12-01

    Driven by the quest for sustainability, recent years have seen a tremendous progress in bio-based production routes from renewable raw materials to commercial goods. Particularly, the production of organic acids has crystallized as a competitive and fast-evolving field, related to the broad applicability of organic acids for direct use, as polymer building blocks, and as commodity chemicals. Here, we review recent advances in metabolic engineering and industrial market scenarios with focus on organic acids as top value products from biomass, accessible through fermentation and biotransformation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Renewable fibers and bio-based materials for packaging applications - A review of recent developments

    DEFF Research Database (Denmark)

    Johansson, Caisa; Bras, Julien; Mondragon, Inaki

    2012-01-01

    This review describes the state-of-the-art of material derived from the forest sector with respect to its potential for use in the packaging industry. Some innovative approaches are highlighted. The aim is to cover recent developments and key challenges for successful introduction of renewable...... materials in the packaging market. The covered subjects are renewable fibers and bio-based polymers for use in bioplastics or as coatings for paper-based packaging materials. Current market sizes and forecasts are also presented. Competitive mechanical, thermal, and barrier properties along with material...

  7. Synthetics, mineral oils, and bio-based lubricants chemistry and technology

    CERN Document Server

    Rudnick, Leslie R

    2005-01-01

    As the field of tribology has evolved, the lubrication industry is also progressing at an extraordinary rate. Updating the author's bestselling publication, Synthetic Lubricants and High-Performance Functional Fluids, this book features the contributions of over 60 specialists, ten new chapters, and a new title to reflect the evolving nature of the field: Synthetics, Mineral Oils, and Bio-Based Lubricants: Chemistry and Technology. The book contains chapters on all major lubricant fluids used in a wide range of applications. For each type of lubricant, the authors discuss the historical develo

  8. Towards reinforcement solutions for urban fibre/fabric waste using bio-based biodegradable resins.

    Science.gov (United States)

    Agrawal, Pramod; Hermes, Alina; Bapeer, Solaf; Luiken, Anton; Bouwhuis, Gerrit; Brinks, Ger

    2017-10-01

    The main research question is how to systematically define and characterize urban textile waste and how to effectively utilise it to produce reinforcement(s) with selected bio-based biodegradable resin(s). Several composite samples have been produced utilising predominantly natural and predominantly synthetic fibres by combining loose fibres with PLA, nonwoven fabric with PLA, woven fabric with PLA, two-layer composite & four-layer composite samples. Physio-chemical characterisations according to the established standards have been conducted. The present work is a step toward the circular economy and closing the loop in textile value chain.

  9. Preparation of new biobased coatings from a triglycidyl eugenol derivative through thiol-epoxy click reaction

    OpenAIRE

    Guzman, Dailyn; Ramis Juan, Xavier; Fernández Francos, Xavier; de la Flor1 López, Sílvia; Serra Albet, Àngels

    2018-01-01

    © 2017 Elsevier B.V. A new triglycidyl eugenol derivative (3EPO-EU) was synthesized and characterized by spectroscopic techniques, and used as starting monomer in the preparation of novel bio-based thiol-epoxy thermosets. As thiols, commercially available tetrathiol derived from pentaerythritol (PETMP), a trithiol derived from eugenol (3SH-EU) and the hexathiol derived from squalene (6SH-SQ) were used in the presence of 4-(N,N-dimethylamino)pyridine as the basic catalyst. A flexible diglycidy...

  10. Study on thermal properties of synthetic and bio-based polyurethane

    Directory of Open Access Journals (Sweden)

    Šercer Mladen

    2015-01-01

    Full Text Available Polymers that are created by the chemical polymerization of naturally occurring monomers are attracting considerable commercial interest in the last few years because of their non-toxicity, biodegradability and biocompatibility and use of feedstock that is renewable. The development of specialized lignin compounds, such as electrically conducting polymers, engineering plastics and polyurethane, is an area of highest interest and growth. The paper will present the comparison of the mechanical and thermal properties of conventional polyurethane and bio-based polyurethane, i.e. polyurethane based on polyols produced by liquefaction of waste wood biomass.

  11. Physical and mechanical properties of biobased materials - Starch polylactate and polyhydroxybutyrate

    DEFF Research Database (Denmark)

    Bergenholtz, Karina P.; Nielsen, Per Væggemose; Olsen, M.B.

    2001-01-01

    Commercial and semi-commercial biobased materials (Polylactate, PLA, polyhydroxybutyrate, PHB, wheat starch and corn starch) were investigated. Physical and mechanical characterisation (tensile strength, elongation, tear strength, compression, gas permeability (CO2 and O-2) and water vapour...... permeability (WVP)) was examined. Tests on both films and cups show potential use of these materials for primary food packaging, especially PLA and PHB. An interesting O-2:CO2 permeability ratio (1:7 to 1:12) was seen, which make these materials suitable for packaging of food with high respiration...

  12. 40 CFR 80.511 - What are the per-gallon and marker requirements that apply to NRLM diesel fuel, ECA marine fuel...

    Science.gov (United States)

    2010-07-01

    ... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel General Information § 80.511 What are the per-gallon and... requirements that apply to NRLM diesel fuel, ECA marine fuel, and heating oil downstream of the refiner or...

  13. Study of the production of ethanol from sugar beets for use as a motor fuel. Final report, February 1, 1980-April 30, 1981

    Energy Technology Data Exchange (ETDEWEB)

    Baird, H W

    1981-04-27

    This study was performed to assess the feasibility of producing fuel ethanol from sugar beets. Sugar beets are a major agricultural crop in the area and the beet sugar industry is a major employer. There have been some indications that increasing competition from imported sugar and fructose sugar produced from corn may lead to lower average sugar prices than have prevailed in the past. Fuel ethanol might provide an attractive alternative market for beets and ethanol production would continue to provide an industrial base for labor. Ethanol production from beets would utilize much of the same field and plant equipment as is now used for sugar. It is logical to examine the modification of an existing sugar plant from producing sugar to ethanol. The decision was made to use Great Western Sugar Company's plant at Mitchell as the example plant. This plant was selected primarily on the basis of its independence from other plants and the availability of relatively nearby beet acreage. The potential feedstocks assessed included sugar beets, corn, hybrid beets, and potatoes. Markets were assessed for ethanol and fermentation by-products saleability. Investment and operating costs were determined for each prospective plant. Plants were evaluated using a discounted cash flow technique to obtain data on full production costs. Environmental, health, safety, and socio-economic aspects of potential facilities were examined. Three consulting engineering firms and 3 engineering-construction firms are considered capable of providing the desired turn-key engineering design and construction services. It was concluded that the project is technically feasible. (DMC)

  14. 49 CFR 393.65 - All fuel systems.

    Science.gov (United States)

    2010-10-01

    ... motor vehicles or for the operation of auxiliary equipment installed on, or used in connection with, motor vehicles. (b) Location. Each fuel system must be located on the motor vehicle so that— (1) No part... will not contact any part of the exhaust or electrical systems of the vehicle, except the fuel level...

  15. Determination of the agricultural and process-related boundary conditions for the use of rapeseed oil and its refinery products as motor fuel. Final report; Ermittlung der landwirtschaftlichen, prozesstechnischen und verfahrenstechnischen Rahmenbedingungen fuer die Verwendung von Rapsoel und seiner Umwandlungsprodukte als Kraftstoff. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Schliephake, D; Hacker, C M

    1994-11-01

    The use of rapeseed oil as a motor fuel is viewed from various angles: Production aspects; environmental aspects; marketing aspects in agriculture; business management aspects in the Federal Republic of Germany; production and refining of rapeseed oil; use of rapeseed oil methyl ester as diesel fuel and in mineral oil processing plants; engine performance. (orig./SR) [Deutsch] In dem vorliegenden Bericht wird der Einsatz von Rapsoel als Kraftstoff aus verschiedenen Blickwinkeln betrachtet: Produktionsaspekte, Umweltaspekte, marktwirtschaftliche Aspekte in der Landwirtschaft; betriebswirtschaftliche Aspekte in der Bundesrepublik Deutschland; Herstellung und Raffination von Rapsoel; Einsatz von Rapsoelmethylester als Dieselkraftstoff und in Anlagen der Mineraloelverarbeitung; Motortechnische Untersuchungsergebnisse. (orig./SR)

  16. Bio-Based Nano Composites from Plant Oil and Nano Clay

    Science.gov (United States)

    Lu, Jue; Hong, Chang K.; Wool, Richard P.

    2003-03-01

    We explored the combination of nanoclay with new chemically functionalized, amphiphilic, plant oil resins to form bio-based nanocomposites with improved physical and mechanical properties. These can be used in many new applications, including the development of self-healing nanocomposites through controlled reversible exfoliation/intercalation, and self-assembled nano-structures. Several chemically modified triglyceride monomers of varying polarity, combined with styrene (ca 30include acrylated epoxidized soybean oil (AESO), maleated acrylated epoxidized soybean oil (MAESO) and soybean oil pentaerythritol glyceride maleates (SOPERMA), containing either hydroxyl group or acid functionality or both. The clay used is a natural montmorillonite modified with methyl tallow bis-2-hydroxyethyl quaternary ammonium chloride, which has hydroxyl groups. Both XRD and TEM showed a completely exfoliated structure at 3 wtwhen the clay content is above 5 wtconsidered a mix of intercalated and partially exfoliated structure. The controlled polarity of the monomer has a major effect on the reversible dispersion of clay in the polymer matrix. The bio-based nanocomposites showed a significant increase in flexural modulus and strength. Supported by EPA and DoE

  17. Amplified and in situ detection of redox-active metabolite using a biobased redox capacitor.

    Science.gov (United States)

    Kim, Eunkyoung; Gordonov, Tanya; Bentley, William E; Payne, Gregory F

    2013-02-19

    Redox cycling provides a mechanism to amplify electrochemical signals for analyte detection. Previous studies have shown that diverse mediators/shuttles can engage in redox-cycling reactions with a biobased redox capacitor that is fabricated by grafting redox-active catechols onto a chitosan film. Here, we report that redox cycling with this catechol-chitosan redox capacitor can amplify electrochemical signals for detecting a redox-active bacterial metabolite. Specifically, we studied the redox-active bacterial metabolite pyocyanin that is reported to be a virulence factor and signaling molecule for the opportunistic pathogen P. aeruginosa. We demonstrate that redox cycling can amplify outputs from various electrochemical methods (cyclic voltammetry, chronocoulometry, and differential pulse voltammetry) and can lower the detection limit of pyocyanin to 50 nM. Further, the compatibility of this biobased redox capacitor allows the in situ monitoring of the production of redox-active metabolites (e.g., pyocyanin) during the course of P. aeruginosa cultivation. We anticipate that the amplified output of redox-active virulence factors should permit an earlier detection of life-threatening infections by the opportunistic pathogen P. aeruginosa while the "bio-compatibility" of this measurement approach should facilitate in situ study of the spatiotemporal dynamics of bacterial redox signaling.

  18. Isosorbide as the structural component of bio-based unsaturated polyesters for use as thermosetting resins.

    Science.gov (United States)

    Sadler, Joshua M; Toulan, Faye R; Nguyen, Anh-Phuong T; Kayea, Ronald V; Ziaee, Saeed; Palmese, Giuseppe R; La Scala, John J

    2014-01-16

    In recent years, the development of renewable bio-based resins has gained interest as potential replacements for petroleum based resins. Modified carbohydrate-based derivatives have favorable structural features such as fused bicyclic rings that offer promising candidates for the development of novel renewable polymers with improved thermomechanical properties when compared to early bio-based resins. Isosorbide is one such compound and has been utilized as the stiffness component for the synthesis of novel unsaturated polyesters (UPE) resins. Resin blends of BioUPE systems with styrene were shown to possess viscosities (120-2200 cP) amenable to a variety of liquid molding techniques, and after cure had Tgs (53-107 °C) and storage moduli (430-1650 MPa) that are in the desired range for composite materials. These investigations show that BioUPEs containing isosorbide can be tailored during synthesis of the prepolymer to meet the needs of different property profiles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Steam explosion and its combinatorial pretreatment refining technology of plant biomass to bio-based products.

    Science.gov (United States)

    Chen, Hong-Zhang; Liu, Zhi-Hua

    2015-06-01

    Pretreatment is a key unit operation affecting the refinery efficiency of plant biomass. However, the poor efficiency of pretreatment and the lack of basic theory are the main challenges to the industrial implementation of the plant biomass refinery. The purpose of this work is to review steam explosion and its combinatorial pretreatment as a means of overcoming the intrinsic characteristics of plant biomass, including recalcitrance, heterogeneity, multi-composition, and diversity. The main advantages of the selective use of steam explosion and other combinatorial pretreatments across the diversity of raw materials are introduced. Combinatorial pretreatment integrated with other unit operations is proposed as a means to exploit the high-efficiency production of bio-based products from plant biomass. Finally, several pilot- and demonstration-scale operations of the plant biomass refinery are described. Based on the principle of selective function and structure fractionation, and multi-level and directional composition conversion, an integrated process with the combinatorial pretreatments of steam explosion and other pretreatments as the core should be feasible and conform to the plant biomass refinery concept. Combinatorial pretreatments of steam explosion and other pretreatments should be further exploited based on the type and intrinsic characteristics of the plant biomass used, the bio-based products to be made, and the complementarity of the processes. Copyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Bio-based polyurethane composite foams with inorganic fillers studied by thermogravimetry

    International Nuclear Information System (INIS)

    Hatakeyema, Hyoe; Tanamachi, Noriko; Matsumura, Hiroshi; Hirose, Shigeo; Hatakeyama, Tatsuko

    2005-01-01

    Bio-based polyurethane (PU) composite foams filled with various inorganic fillers, such as barium sulfate (BaSO 4 ), calcium carbonate (CaCO 3 ) and talc were prepared using polyols, such as diethylene glycol, triethylene glycol and polyethylene glycol (molecular weight ca. 200) containing molasses and lignin. Reactive hydroxyl groups in plant components and above polyols were used as reaction sites. Morphological observation of fracture surface of composites was carried out by scanning electron microscopy. Thermal properties of bio-based PU composites were examined by thermogravimetry. It was found that the above composites decompose in two stages reflecting decomposition of organic components. Decomposition temperature increased with increasing filler content, when plant components were homogenously mixed with inorganic fillers. Activation energy calculated by Ozawa-Wall-Flynn method was ca. 150 kJ mol -1 . The durability of composites was predicted using kinetic data. Calculated values indicate that composites with fillers are more durable than that of those without fillers at a moderate temperature region

  1. Eugenol-loaded chitosan nanoparticles: II. Application in bio-based plastics for active packaging.

    Science.gov (United States)

    Woranuch, Sarekha; Yoksan, Rangrong

    2013-07-25

    The aim of the present research was to study the possibility of using eugenol-loaded chitosan nanoparticles as antioxidants for active bio-based packaging material. Eugenol-loaded chitosan nanoparticles were incorporated into thermoplastic flour (TPF) - a model bio-based plastic - through an extrusion process at temperatures above 150°C. The influences of eugenol-loaded chitosan nanoparticles on crystallinity, morphology, thermal properties, radical scavenging activity, reducing power, tensile properties and barrier properties of TPF were investigated. Although the incorporation of 3% (w/w) of eugenol-loaded chitosan nanoparticles significantly reduced the extensibility and the oxygen barrier property of TPF, it provided antioxidant activity and improved the water vapor barrier property. In addition, TPF containing eugenol-loaded chitosan nanoparticles exhibited superior radical scavenging activity and stronger reducing power compared with TPF containing naked eugenol. The results suggest the applicability of TPF containing eugenol-loaded chitosan nanoparticles as an antioxidant active packaging material. Copyright © 2012 Elsevier Ltd. All rights reserved.

  2. Production of Plant Phthalate and its Hydrogenated Derivative from Bio-Based Platform Chemicals.

    Science.gov (United States)

    Lu, Rui; Lu, Fang; Si, Xiaoqin; Jiang, Huifang; Huang, Qianqian; Yu, Weiqiang; Kong, Xiangtao; Xu, Jie

    2018-04-06

    Direct transformation of bio-based platform chemicals into aromatic dicarboxylic acids and their derivatives, which are widely used for the manufacture of polymers, is of significant importance for the sustainable development of the plastics industry. However, limited successful chemical processes have been reported. This study concerns a sustainable route for the production of phthalate and its hydrogenated derivative from bio-based malic acid and erythritol. The key Diels-Alder reaction is applied to build a substituted cyclohexene structure. The dehydration reaction of malic acid affords fumaric acid with 96.6 % yield, which could be used as the dienophile, and 1,3-butadiene generated in situ through erythritol deoxydehydration serves as the diene. Starting from erythritol and dibutyl fumarate, a 74.3 % yield of dibutyl trans-4-cyclohexene-1,2-dicarboxylate is obtained. The palladium-catalyzed dehydrogenation of the cycloadduct gives a 77.8 % yield of dibutyl phthalate. Dibutyl trans-cyclohexane-1,2-dicarboxylate could be formed in nearly 100 % yield under mild conditions by hydrogenation of the cycloadduct. Furthermore, fumaric acid and fumarate, with trans configurations, were found to be better dienophiles for this Diels-Alder reaction than maleic acid and maleate, with cis configuration, based on the experimental and computational results. This new route will pave the way for the production of environmental friendly plastic materials from plants. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Key parameters in testing biodegradation of bio-based materials in soil.

    Science.gov (United States)

    Briassoulis, D; Mistriotis, A

    2018-05-05

    Biodegradation of plastics in soil is currently tested by international standard testing methods (e.g. ISO 17556-12 or ASTM D5988-12). Although these testing methods have been developed for plastics, it has been shown in project KBBPPS that they can be extended also to lubricants with small modifications. Reproducibility is a critical issue regarding biodegradation tests in the laboratory. Among the main testing variables are the soil types and nutrients available (mainly nitrogen). For this reason, the effect of the soil type on the biodegradation rates of various bio-based materials (cellulose and lubricants) was tested for five different natural soil types (loam, loamy sand, clay, clay-loam, and silt-loam organic). It was shown that use of samples containing 1 g of C in a substrate of 300 g of soil with the addition of 0.1 g of N as nutrient strongly improves the reproducibility of the test making the results practically independent of the soil type with the exception of the organic soil. The sandy soil was found to need addition of higher amount of nutrients to exhibit similar biodegradation rates as those achieved with the other soil types. Therefore, natural soils can be used for Standard biodegradation tests of bio-based materials yielding reproducible results with the addition of appropriate nutrients. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Intumescent formulations based on lignin and phosphinates for the bio-based textiles

    Science.gov (United States)

    Mandlekar, N.; Cayla, A.; Rault, F.; Giraud, S.; Salaün, F.; Malucelli, G.; Guan, J.

    2017-10-01

    This study investigates new intumescent formulations based on lignin and phosphinates to improve the flame retardant properties of Polyamide 11, while preserving the bio-based characteristics of this latter. Lignin has the advantage of being a bio-based compound and can be effectively used as carbon source for the design of intumescent systems in combination with other flame retardant additives. Metal phosphinates belong to a novel class of phosphorus flame retardants. Despite their increasing use, there is lack of scientific understanding as far as their fire retardancy mechanism is considered, especially in char forming polymeric materials. In this context, Polyamide 11 was melt blended with lignin and metal phosphinates. The possibility of melt spinning the prepared blends were assessed through melt flow index (MFI) tests; thermogravimetric (TG) analyses and cone calorimetry tests were exploited for investigating the thermal stability and the combustion behaviour of the obtained products, respectively. MFI results indicate that some formulations are suitable for melt spinning processes to generate flame retardant multifilament. Furthermore, the combination of lignin and phosphinates provides charring properties to polyamide 11. Finally, cone calorimetry data confirmed that the designed intumescent formulations could remarkably reduce PHRR through formation of protective char layer, hence slowing down the combustion process.

  5. Bio-Based Polyols from Seed Oils for Water-Blown Rigid Polyurethane Foam Preparation

    Directory of Open Access Journals (Sweden)

    Paweena Ekkaphan

    2016-01-01

    Full Text Available The preparation of water-blown rigid polyurethane (RPUR foams using bio-based polyols from sesame seed oil and pumpkin seed oil has been reported. Polyols synthesis involved two steps, namely, hydroxylation and alcoholysis reaction. FTIR, NMR, and ESI-MS were used to monitor the process of the synthesized polyols and their physicochemical properties were determined. The resulting polyols have OH number in the range of 340–351 mg KOH/g. RPUR foams blown with water were produced from the reaction of biopolyols with commercial polymeric methylene diphenyl diisocyanate (PMDI. The proper PUR formulations can be manipulated to produce the desired material applications. These seed oil-based RPUR foams exhibited relatively high compressive strength (237.7–240.2 kPa with the density in the range of 40–45 kg/m3. Additionally, the cell foam morphology investigated by scanning electron microscope indicated that their cellular structure presented mostly polygonal closed cells. The experimental results demonstrate that these bio-based polyols can be used as an alternative starting material for RPUR production.

  6. Gallic Acid as an Oxygen Scavenger in Bio-Based Multilayer Packaging Films.

    Science.gov (United States)

    Pant, Astrid F; Sängerlaub, Sven; Müller, Kajetan

    2017-05-03

    Oxygen scavengers are used in food packaging to protect oxygen-sensitive food products. A mixture of gallic acid (GA) and sodium carbonate was used as an oxygen scavenger (OSc) in bio-based multilayer packaging films produced in a three-step process: compounding, flat film extrusion, and lamination. We investigated the film surface color as well as oxygen absorption at different relative humidities (RHs) and temperatures, and compared the oxygen absorption of OSc powder, monolayer films, and multilayer films. The films were initially brownish-red in color but changed to greenish-black during oxygen absorption under humid conditions. We observed a maximum absorption capacity of 447 mg O₂/g GA at 21 °C and 100% RH. The incorporation of GA into a polymer matrix reduced the rate of oxygen absorption compared to the GA powder because the polymer acted as a barrier to oxygen and water vapor diffusion. As expected, the temperature had a significant effect on the initial absorption rate of the multilayer films; the corresponding activation energy was 75.4 kJ/mol. Higher RH significantly increased the oxygen absorption rate. These results demonstrate for the first time the production and the properties of a bio-based multilayer packaging film with GA as the oxygen scavenger. Potential applications include the packaging of food products with high water activity (a w > 0.86).

  7. Injection Molding and Mechanical Properties of Bio-Based Polymer Nanocomposites

    Directory of Open Access Journals (Sweden)

    Maria Chiara Mistretta

    2018-04-01

    Full Text Available The use of biodegradable/bio-based polymers is of great importance in addressing several issues related to environmental protection, public health, and new, stricter legislation. Yet some applications require improved properties (such as barrier or mechanical properties, suggesting the use of nanosized fillers in order to obtain bio-based polymer nanocomposites. In this work, bionanocomposites based on two different biodegradable polymers (coming from the Bioflex and MaterBi families and two different nanosized fillers (organo-modified clay and hydrophobic-coated precipitated calcium carbonate were prepared and compared with traditional nanocomposites with high-density polyethylene (HDPE as matrix. In particular, the injection molding processability, as well as the mechanical and rheological properties of the so-obtained bionanocomposites were investigated. It was found that the processability of the two biodegradable polymers and the related nanocomposites can be compared to that of the HDPE-based systems and that, in general, the bio-based systems can be taken into account as suitable alternatives.

  8. Catalyst Influence on Undesired Side Reactions in the Polycondensation of Fully Bio-Based Polyester Itaconates

    Directory of Open Access Journals (Sweden)

    Ina Schoon

    2017-12-01

    Full Text Available Bio-based unsaturated polyester resins derived from itaconic acid can be an alternative to established resins of this type in the field of radical-curing resins. However, one of the challenges of these polyester itaconates is the somewhat more elaborate synthetic process, especially under polycondensation conditions used on an industrial scale. The α,β-unsaturated double bond of the itaconic acid is prone to side reactions that can lead to the gelation of the polyester resin under standard conditions. This is especially true when bio-based diols such as 1,3-propanediol or 1,4-butanediol are used to obtain resins that are 100% derived from renewable resources. It was observed in earlier studies that high amounts of these aliphatic diols in the polyester lead to low conversion and gelation of the resins. In this work, a catalytic study using different diols was performed in order to elucidate the reasons for this behavior. It was shown that the choice of catalyst has a crucial influence on the side reactions occurring during the polycondensation reactions. In addition, the side reactions taking place were identified and suppressed. These results will allow for the synthesis of polyester itaconates on a larger scale, setting the stage for their industrial application.

  9. Micro- and nano bio-based delivery systems for food applications: In vitro behavior.

    Science.gov (United States)

    de Souza Simões, Lívia; Madalena, Daniel A; Pinheiro, Ana C; Teixeira, José A; Vicente, António A; Ramos, Óscar L

    2017-05-01

    Micro- and nanoencapsulation is an emerging technology in the food field that potentially allows the improvement of food quality and human health. Bio-based delivery systems of bioactive compounds have a wide variety of morphologies that influence their stability and functional performance. The incorporation of bioactive compounds in food products using micro- and nano-delivery systems may offer extra health benefits, beyond basic nutrition, once their encapsulation may provide protection against undesired environmental conditions (e.g., heat, light and oxygen) along the food chain (including processing and storage), thus improving their bioavailability, while enabling their controlled release and target delivery. This review provides an overview of the bio-based materials currently used for encapsulation of bioactive compounds intended for food applications, as well as the main production techniques employed in the development of micro- and nanosystems. The behavior of such systems and of bioactive compounds entrapped into, throughout in vitro gastrointestinal systems, is also tracked in a critical manner. Comparisons between various in vitro digestion systems (including the main advantages and disadvantages) currently in use, as well as correlations between the behavior of micro- and nanosystems studied through in vitro and in vivo systems were highlighted and discussed here for the first time. Finally, examples of bioactive micro- and nanosystems added to food simulants or to real food matrices are provided, together with a revision of the main challenges for their safe commercialization, the regulatory issues involved and the main legislation aspects. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. To be, or not to be biodegradable… that is the question for the bio-based plastics.

    Science.gov (United States)

    Prieto, Auxiliadora

    2016-09-01

    Global warming, market and production capacity are being the key drivers for selecting the main players for the next decades in the market of bio-based plastics. The drop-in bio-based polymers such as the bio-based polyethylene terephtalate (PET) or polyethylene (PE), chemically identical to their petrochemical counterparts but having a component of biological origin, are in the top of the list. They are followed by new polymers such as PHA and PLA with a significant market growth rate since 2014 with projections to 2020. Research will provide improved strains designed through synthetic and systems biology approaches; furthermore, the use of low-cost substrates will contribute to the widespread application of these bio- based polymers. The durability of plastics is not considered anymore as a virtue, and interesting bioprospecting strategies to isolate microorganisms for assimilating the recalcitrant plastics will pave the way for in vivo strategies for plastic mineralization. In this context, waste management of bio-based plastic will be one of the most important issues in the near future in terms of the circular economy. There is a clear need for standardized labelling and sorting instructions, which should be regulated in a coordinated way by policymakers and material producers. © 2016 The Author. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  11. Building a bio-based industry in the Middle East through harnessing the potential of the Red Sea biodiversity

    DEFF Research Database (Denmark)

    Nielsen, Jens; Archer, John; Essack, Magbubah

    2017-01-01

    , represents a remarkable source of biodiversity that can be geared towards economical and sustainable bioproduction processes in the local area and can be competitive in the international bio-based economy. Recent bioprospecting studies, conducted by the King Abdullah University of Science and Technology...

  12. Rigid, bio-based polyamides from galactaric acid derivatives with elevated glass transition temperatures and their characterization

    NARCIS (Netherlands)

    Wróblewska, Aleksandra A.; Bernaerts, Katrien; de Wildeman, Stefaan

    2017-01-01

    A comparative study was prepared investigating the synthesis of polyamides using bio-based building blocks derived from sugar beet pulp, namely 2,3:4,5-di-O-methylene-galactarate (GalXH) and 2,3:4,5-di-O-isopropylidene-galactarate (GalXMe) derivatives. Two different approaches towards the synthesis

  13. Synthesis and characterization of poly (lactic acid)/chitosan nanocomposites based on renewable resources as biobased-material

    Science.gov (United States)

    Suryani; Agusnar, H.; Wirjosentono, B.; Rihayat, T.; Salisah, Z.

    2018-01-01

    Biobased becomes one of the new breakthrough in the smart engineering, especially in biomedical applications, such as tissue engineering that serves as a supporting physical structure to trigger the growth of skin tissue. From various studies which had been done, it was known that the optimal Biobased healed wounds or injuries in a relatively short time. In this study, a Biobased natural polymer based e.g Poly(Lactic Acid) (PLA)/Chitosan Nanocomposites was made. PLA was synthesized from saba banana (Musa acuminata) as raw material using Ring-Opening Polymerization (ROP) method. PLA was mixed with Chitosan with Chitosan concentration variations of 1%, 3%, and 5% to form a nanocomposites. The analysis result showed that Chitosan concentration in PLA/Chitosan Nanocomposites sample affected the value of tensile strength. The highest value of tensile strength was obtained on a sample of 100 ml volume with a concentration of 3%, which was 120.396 MPa. The highest percentage of elongation was obtained in 100 ml volume sample with 5% concentration, which was 26.3686%. In the hydrophilicity test, the highest percentage of water absorption was obtained in a 200 ml volume sample with 5% concentration, which was 44.615%. The addition of Chitosan to the sample affected the functional group bonding, where there was a functional group of NH2 at the wave number of 2923.92 cm-1. The sample characteristics based on water absorption indicated that the sample was potentially to be used as Biobased construction material.

  14. Sustainability Benefits and Challenges of Inter-Organizational Collaboration in Bio-Based Business: A Systematic Literature Review

    Directory of Open Access Journals (Sweden)

    Gohar Nuhoff-Isakhanyan

    2016-03-01

    Full Text Available Bio-based businesses are often considered to be sustainable. However, they are also linked to sustainability challenges such as deforestation and soil erosion. Encouraged to exploit innovative solutions and enhance sustainability, organizations engaged in bio-based activities extensively explore collaboration possibilities with external partners. The objective of this paper is to integrate the available knowledge on sustainability of inter-organisational collaborations in bio-based businesses, while considering the three aspects of sustainability: environmental, economic, and social. We collected data from three academic sources—Web of Science, Scopus, and EconLit—and conducted a systematic literature review. The results show the importance of geographical proximity and complementarity in creating sustainability benefits such as reduced emissions, reduced waste, economic synergies, and socio-economic activities. Based on the findings, we have developed a framework that illustrates sustainability benefits and challenges. Interestingly, the studies emphasize sustainability benefits more in emerging than in industrialised economies, especially relating to the social aspects of sustainability. In conclusion, although the scholars have not discussed mitigation of several sustainability challenges in bio-based businesses, such as land use conflicts, they have found evidence of vital sustainability benefits, such as energy availability, lower emissions, improved socio-economic life, and poverty reduction, which are essential in emerging economies.

  15. Secondary Resources in the Bio-Based Economy : A Computer Assisted Survey of Value Pathways in Academic Literature

    NARCIS (Netherlands)

    Davis, Chris B.; Aid, Graham; Zhu, B.

    2017-01-01

    Research on value pathways for organic wastes has been steadily increasing in recent decades. There have been few considerably broad overview studies of such materials and their valuation potential in the bio-based economy in part because of the vast multitude of materials and processes that can

  16. Modelling continuous pharmaceutical and bio-based processes at plant-wide level: A roadmap towards efficient decision-making

    DEFF Research Database (Denmark)

    Ramin, Pedram; Mansouri, Seyed Soheil; Udugama, Isuru A.

    2018-01-01

    The importance of developing simulation models for decision making in pharmaceutical and bio-based production processes is elaborated in this article. The advantages of modelling continuous processes are outlined and certain barriers in this regard are identified. Although there have been some...

  17. Tokyo Motor Show 2003; Tokyo Motor Show 2003

    Energy Technology Data Exchange (ETDEWEB)

    Joly, E.

    2004-01-01

    The text which follows present the different techniques exposed during the 37. Tokyo Motor Show. The report points out the great tendencies of developments of the Japanese automobile industry. The hybrid electric-powered vehicles or those equipped with fuel cells have been highlighted by the Japanese manufacturers which allow considerable budgets in the research of less polluting vehicles. The exposed models, although being all different according to the manufacturer, use always a hybrid system: fuel cell/battery. The manufacturers have stressed too on the intelligent systems for navigation and safety as well as on the design and comfort. (O.M.)

  18. Comparative investigation of conventional and R744 auxiliary heating systems in motor cars with low fuel consumption on the basis of a 1.9 l TDI engine; Vergleich konventioneller Zuheizsysteme mit R744-Zuheizsystemen in Automobilen mit geringem Kraftstoffverbrauch auf Basis eines 1,9 l TDI Motors

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, B.; Feuerecker, G.; Heinle, D.; Strauss, T. [Behr GmbH und Co. KG, Stuttgart (Germany). Entwicklungszentrum

    2003-07-01

    The heat emitted by modern consumption-optimized engines, especially diesel engines, is so low that auxiliary heating systems are required for thermal comfort. With R744 air conditioning systems, the air conditioner can be used as auxiliary heating system. The contribution therefore compares conventional PTC and fuel based auxiliary heating systems with three R744 auxiliary heating systems (air-to-air heat pump, coolant-to-air heat pump, and delta process). Simulations were carried out in order to compare heat-up, fuel consumption, and cost. The simulation models were used for calculating demand-oriented heating at different ambient temperatures with a 1.9 l TDI engine. The BEHR software BISS (Behr Integrierte System Simulation) was used as simulation tool. The performance of the heat pump was significantly lower than the performance of conventional auxiliary heating systems at all temperatures. On the other hand, the additional fuel consumption as referred to performance was 15 percent lower than for conventional heating systems. The PTC system had the best cost/profit ratio. (orig.) [German] Der Anteil verbrauchsoptimierter Verbrennungsmotoren, insbesondere Diesel, ist in Europa in den letzten Jahren rasant gestiegen. Die Waermeabgabe dieser Motoren ist inzwischen so niedrig, dass fuer eine rasche und komfortable Aufheizung der Fahrzeugkabine Zuheizsysteme eingesetzt werden muessen. Beim Einsatz von Kohlendioxid (R744) als Kaeltemittel einer Klimaanlage, ist auch ein Betrieb der Klimaanlage als Zuheizsystem denkbar. In diesem Beitrag werden die konventionellen Zuheizsysteme PTC-Zuheizer und Brennstoffzuheizer mit drei R744-Zuheizsystemen mittels Simulation bezueglich Aufheizverhalten, Kraftstoffverbrauch und Kosten bewertet. Die R744 Zuheizsysteme sind Luft-Luft Waermepumpe, Kuehlmittel-Luft-Waermepumpe und Dreiecksprozess. Mit den Simulationsmodellen wurden Berechnungen einer bedarfsorientierten Aufheizung fuer verschiedene Umgebungstemperaturen auf Basis eines

  19. Jidosha's Motors

    OpenAIRE

    Shirakawa Okuma, Rosely; Calderón Orejuela, Javier

    2016-01-01

    La tesis narra la situación de una empresa concesionaria de vehículos nuevos, Jidosha's Motors, perteneciente a una corporación japonesa que cuenta con una cultura muy arraigada de ética y de cumplimiento. Se plantean respuestas, se identifican problemas y sus alternativas de solución para una toma adecuada de decisiones por parte de los directivos, siguiendo una estructura de análisis de situaciones de negocios (ASN). Tesis

  20. Nuclear fuel pellet loading machine

    International Nuclear Information System (INIS)

    Dazen, J.R.; Denero, J.V.

    1976-01-01

    A nuclear fuel pellet loading machine is described including an inclined rack mounted on a base and having parallel spaced grooves on its upper surface arranged to support fuel rods. A fuel pellet tray is adapted to be placed on a table spaced from the rack, the tray having columns of fuel pellets which are in alignment with the open ends of fuel rods located in the rack grooves. A transition plate is mounted between the fuel rod rack and the fuel pellet tray to receive and guide the pellets into the open ends of the fuel rods. The pellets are pushed into the fuel rods by a number of mechanical fingers mounted on a motor operated block which is moved along the pellet tray length by a drive screw driven by the motor. To facilitate movement of the pellets in the fuel rods the rack is mounted on a number of spaced vibrators which vibrate the fuel rods during fuel pellet insertion. A pellet sensing device movable into an end of each fuel rod indicates to an operator when each rod has been charged with the correct number of pellets

  1. Hydrogen and Gaseous Fuel Safety and Toxicity

    Energy Technology Data Exchange (ETDEWEB)

    Lee C. Cadwallader; J. Sephen Herring

    2007-06-01

    Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

  2. 40 CFR 80.533 - How does a refiner or importer apply for a motor vehicle or non-highway baseline for the...

    Science.gov (United States)

    2010-07-01

    ... compliance with the provisions of § 80.554(d), the baseline volumes of motor vehicle diesel fuel produced..., BMV equals the average annual volume of motor vehicle diesel fuel produced or imported from January 1... annual volume of motor vehicle diesel fuel produced or imported during the period from January 1, 2006...

  3. Finite element based electric motor design optimization

    Science.gov (United States)

    Campbell, C. Warren

    1993-01-01

    The purpose of this effort was to develop a finite element code for the analysis and design of permanent magnet electric motors. These motors would drive electromechanical actuators in advanced rocket engines. The actuators would control fuel valves and thrust vector control systems. Refurbishing the hydraulic systems of the Space Shuttle after each flight is costly and time consuming. Electromechanical actuators could replace hydraulics, improve system reliability, and reduce down time.

  4. Thermal and mechanical properties of bio-based plasticizers mixtures on poly (vinyl chloride

    Directory of Open Access Journals (Sweden)

    Boussaha Bouchoul

    2017-09-01

    Full Text Available Abstract The use of mixtures of nontoxic and biodegradable plasticizers coming from natural resources is a good way to replace conventional phthalates plasticizers. In this study, two secondary plasticizers of epoxidized sunflower oil (ESO and epoxidized sunflower oil methyl ester (ESOME were synthesized and have been used with two commercially available biobased plasticizers; isosorbide diesters (ISB and acetyl tributyl citrate (ATBC in order to produce flexible PVC. Different mixtures of these plasticizers have been introduced in PVC formulations. Thermal, mechanical and morphological properties have been studied by using discoloration, thermogravimetric analysis (TGA, differential scanning calorimetry (DSC, dynamic mechanical thermal analysis (DMTA, tensile - strain and scanning electron microscopy (SEM. Studies have shown that PVC plasticization and stabilization were improved by addition of plasticizers blends containing ISB, ATBC, ESO and ESOME. An increase in the content of ESO or ESOME improved thermal and mechanical properties, whereas ESOME/ATBC formulations exhibited the best properties.

  5. Biobased production of alkanes and alkenes through metabolic engineering of microorganisms

    DEFF Research Database (Denmark)

    Kang, Min Kyoung; Nielsen, Jens

    2017-01-01

    Advancement in metabolic engineering of microorganisms has enabled bio-based production of a range of chemicals, and such engineered microorganism can be used for sustainable production leading to reduced carbon dioxide emission there. One area that has attained much interest is microbial...... hydrocarbon biosynthesis, and in particular, alkanes and alkenes are important high-value chemicals as they can be utilized for a broad range of industrial purposes as well as ‘drop-in’ biofuels. Some microorganisms have the ability to biosynthesize alkanes and alkenes naturally, but their production level...... is extremely low. Therefore, there have been various attempts to recruit other microbial cell factories for production of alkanes and alkenes by applying metabolic engineering strategies. Here we review different pathways and involved enzymes for alkane and alkene production and discuss bottlenecks...

  6. Recent advances in bio-based multi-products of agricultural Jerusalem artichoke resources.

    Science.gov (United States)

    Qiu, Yibin; Lei, Peng; Zhang, Yatao; Sha, Yuanyuan; Zhan, Yijing; Xu, Zongqi; Li, Sha; Xu, Hong; Ouyang, Pingkai

    2018-01-01

    The Jerusalem artichoke is a perennial plant that belongs to the sunflower family. As a non-grain crop, Jerusalem artichoke possesses a number of desirable characteristics that make it a valuable feedstock for biorefinery, such as inulin content, rapid growth, strong adaptability, and high yields. This review provides a comprehensive introduction to renewable Jerusalem artichoke-based biomass resources and recent advances in bio-based product conversion. Furthermore, we discuss the latest in the development of inulinase-producing microorganisms and enhanced inulin hydrolysis capacity of microbes by genetic engineering, which lead to a more cost-effective Jerusalem artichoke biorefinery. The review is aimed at promoting Jerusalem artichoke industry and new prospects for higher value-added production.

  7. Chemoenzymatic Synthesis of Oligo(L-cysteine) for Use as a Thermostable Bio-Based Material.

    Science.gov (United States)

    Ma, Yinan; Sato, Ryota; Li, Zhibo; Numata, Keiji

    2016-01-01

    Oligomerization of thiol-unprotected L-cysteine ethyl ester (Cys-OEt) catalyzed by proteinase K in aqueous solution has been used to synthesize oligo(L-cysteine) (OligoCys) with a well-defined chemical structure and relatively large degree of polymerization (DP) up to 16-17 (average 8.8). By using a high concentration of Cys-OEt, 78.0% free thiol content was achieved. The thermal properties of OligoCys are stable, with no glass transition until 200 °C, and the decomposition temperature could be increased by oxidation. Chemoenzymatically synthesized OligoCys has great potential for use as a thermostable bio-based material with resistance to oxidation. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. N-Alkylated dinitrones from isosorbide as cross-linkers for unsaturated bio-based polyesters

    Directory of Open Access Journals (Sweden)

    Oliver Goerz

    2014-04-01

    Full Text Available Isosorbide was esterified with acryloyl chloride and crotonic acid yielding isosorbide diacrylate (9a and isosorbide dicrotonate (9b, which were reacted with benzaldehyde oxime in the presence of zinc(II iodide and boron triflouride etherate as catalysts to obtain N-alkylated dinitrones 10a/b. Poly(isosorbide itaconite -co- succinate 13 as a bio-based unsaturated polyester was cross-linked by a 1,3-dipolar cycloaddition with the received dinitrones 10a/b. The 1,3-dipolar cycloaddition led to a strong change of the mechanical properties which were investigated by rheological measurements. Nitrones derived from methyl acrylate (3a and methyl crotonate (3b were used as model systems and reacted with dimethyl itaconate to further characterize the 1,3-dipolaric cycloaddition.

  9. Performance of palm oil as a biobased machining lubricant when drilling inconel 718

    Directory of Open Access Journals (Sweden)

    Abd Rahim Erween

    2017-01-01

    Full Text Available Metalworking fluid acts as cooling and lubrication agent at the cutting zone in the machining process. However, conventional Metalworking fluid such mineral oil gives negative impact on the human and environment. Therefore, the manufacture tends to substitute the mineral oil to bio-based oil such as vegetables and synthetic oil. In this paper, the drilling experiment was carried out to evaluate the efficiency of palm oil and compare it with minimal quantity lubrication technique using synthetic ester, flood coolant and air blow with respect to cutting temperature, cutting force, torque and tool life. The experimental results showed that the application of palm oil under minimal quantity lubrication condition as the cutting fluid was more efficient process as it improves the machining performances.

  10. The Future of Polar Organometallic Chemistry Written in Bio-Based Solvents and Water.

    Science.gov (United States)

    García-Álvarez, Joaquín; Hevia, Eva; Capriati, Vito

    2018-06-19

    There is a strong imperative to reduce the release of volatile organic compounds (VOCs) into the environment, and many efforts are currently being made to replace conventional hazardous VOCs in favour of safe, green and bio-renewable reaction media that are not based on crude petroleum. Recent ground-breaking studies from a few laboratories worldwide have shown that both Grignard and (functionalised) organolithium reagents, traditionally handled under strict exclusion of air and humidity and in anhydrous VOCs, can smoothly promote both nucleophilic additions to unsaturated substrates and nucleophilic substitutions in water and other bio-based solvents (glycerol, deep eutectic solvents), competitively with protonolysis, at room temperature and under air. The chemistry of polar organometallics in the above protic media is a complex phenomenon influenced by several factors, and understanding its foundational character is surely stimulating in the perspective of the development of a sustainable organometallic chemistry. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. High renewable content sandwich structures based on flax-basalt hybrids and biobased epoxy polymers

    Science.gov (United States)

    Colomina, S.; Boronat, T.; Fenollar, O.; Sánchez-Nacher, L.; Balart, R.

    2014-05-01

    In the last years, a growing interest in the development of high environmental efficiency materials has been detected and this situation is more accentuated in the field of polymers and polymer composites. In this work, green composite sandwich structures with high renewable content have been developed with core cork materials. The base resin for composites was a biobased epoxy resin derived from epoxidized vegetable oils. Hybrid basalt-flax fabrics have been used as reinforcements for composites and the influence of the stacking sequence has been evaluated in order to optimize the appropriate laminate structure for the sandwich bases. Core cork materials with different thickness have been used to evaluate performance of sandwich structures thus leading to high renewable content composite sandwich structures. Results show that position of basalt fabrics plays a key role in flexural fracture of sandwich structures due to differences in stiffness between flax and basalt fibers.

  12. Assessment of ethanol-fueled IMHEX{reg_sign} fuel cell power plants in distributed generation

    Energy Technology Data Exchange (ETDEWEB)

    Woods, R. [M-C Power Corp., Burr Ridge, IL (United States); Lefeld, J. [PSI Energy, Plainfield, IN (United States)

    1993-12-31

    Ethanol-fueled cell power plants presents several significant opportunities for the power generation industry. The potential exists to reduce pollution, help the nation shift from its dependence on imported fuels, reduce global warming, and strengthen the economy. Two important developments can be merged to create a clean, high-technology, bio-based energy system: the production of ethanol fuels and the application of fuel cell power plants. Utilization of ethanol will be in dual-fueled applications initially, and evolve toward the primary fuel as the need for renewable energy sources increase and the economic competitiveness improves. This assessment addresses the major issues of this proposed concept and outlines the benefits anticipated to the environment, US agriculture, energy supplies, and electric power customers. Economic and technical aspects of the concept are also reviewed. One of PSI Energy`s primary interests is the utilization of renewable fuels supplied by their customer base. The IMHEX{reg_sign} fuel cell is an advanced electric power generation technology currently under development by M-C Power. Commercial applications within the power generation industry are scheduled to begin during the late 1990s.

  13. Facile Fabrication of 100% Bio-based and Degradable Ternary Cellulose/PHBV/PLA Composites

    Directory of Open Access Journals (Sweden)

    Tao Qiang

    2018-02-01

    Full Text Available Modifying bio-based degradable polymers such as polylactide (PLA and poly(hydroxybutyrate-co-hydroxyvalerate (PHBV with non-degradable agents will compromise the 100% degradability of their resultant composites. This work developed a facile and solvent-free route in order to fabricate 100% bio-based and degradable ternary cellulose/PHBV/PLA composite materials. The effects of ball milling on the physicochemical properties of pulp cellulose fibers, and the ball-milled cellulose particles on the morphology and mechanical properties of PHBV/PLA blends, were investigated experimentally and statistically. The results showed that more ball-milling time resulted in a smaller particle size and lower crystallinity by way of mechanical disintegration. Filling PHBV/PLA blends with the ball-milled celluloses dramatically increased the stiffness at all of the levels of particle size and filling content, and improved their elongation at the break and fracture work at certain levels of particle size and filling content. It was also found that the high filling content of the ball-milled cellulose particles was detrimental to the mechanical properties for the resultant composite materials. The ternary cellulose/PHBV/PLA composite materials have some potential applications, such as in packaging materials and automobile inner decoration parts. Furthermore, filling content contributes more to the variations of their mechanical properties than particle size does. Statistical analysis combined with experimental tests provide a new pathway to quantitatively evaluate the effects of multiple variables on a specific property, and figure out the dominant one for the resultant composite materials.

  14. 40 CFR 80.554 - What compliance options are available to NRLM diesel fuel small refiners?

    Science.gov (United States)

    2010-07-01

    ... an approved motor vehicle diesel fuel small refiner under § 80.550(a) but does not qualify as a NRLM... to NRLM diesel fuel small refiners? 80.554 Section 80.554 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle...

  15. 40 CFR 600.006-87 - Data and information requirements for fuel economy vehicles.

    Science.gov (United States)

    2010-07-01

    ..., motor controller, battery configuration, or other components performed within 2,000 miles prior to fuel... fuel economy vehicles. 600.006-87 Section 600.006-87 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel...

  16. Cascade use indicators for selected biopolymers: Are we aiming for the right solutions in the design for recycling of bio-based polymers?

    Science.gov (United States)

    Hildebrandt, Jakob; Bezama, Alberto; Thrän, Daniela

    2017-01-01

    When surveying the trends and criteria for the design for recycling (DfR) of bio-based polymers, priorities appear to lie in energy recovery at the end of the product life of durable products, such as bio-based thermosets. Non-durable products made of thermoplastic polymers exhibit good properties for material recycling. The latter commonly enjoy growing material recycling quotas in countries that enforce a landfill ban. Quantitative and qualitative indicators are needed for characterizing progress in the development towards more recycling friendly bio-based polymers. This would enable the deficits in recycling bio-based plastics to be tracked and improved. The aim of this paper is to analyse the trends in the DfR of bio-based polymers and the constraints posed by the recycling infrastructure on plastic polymers from a systems perspective. This analysis produces recommendations on how life cycle assessment indicators can be introduced into the dialogue between designers and recyclers in order to promote DfR principles to enhance the cascading use of bio-based polymers within the bioeconomy, and to meet circular economy goals. PMID:28097922

  17. Cascade use indicators for selected biopolymers: Are we aiming for the right solutions in the design for recycling of bio-based polymers?

    Science.gov (United States)

    Hildebrandt, Jakob; Bezama, Alberto; Thrän, Daniela

    2017-04-01

    When surveying the trends and criteria for the design for recycling (DfR) of bio-based polymers, priorities appear to lie in energy recovery at the end of the product life of durable products, such as bio-based thermosets. Non-durable products made of thermoplastic polymers exhibit good properties for material recycling. The latter commonly enjoy growing material recycling quotas in countries that enforce a landfill ban. Quantitative and qualitative indicators are needed for characterizing progress in the development towards more recycling friendly bio-based polymers. This would enable the deficits in recycling bio-based plastics to be tracked and improved. The aim of this paper is to analyse the trends in the DfR of bio-based polymers and the constraints posed by the recycling infrastructure on plastic polymers from a systems perspective. This analysis produces recommendations on how life cycle assessment indicators can be introduced into the dialogue between designers and recyclers in order to promote DfR principles to enhance the cascading use of bio-based polymers within the bioeconomy, and to meet circular economy goals.

  18. Montana fuel tax refunds : draft final report.

    Science.gov (United States)

    2011-11-01

    "The primary source of funding for transportation infrastructure is the taxes that are imposed on motor fuels. One aspect of fuel tax collections is the process that requires consumers to apply for refunds of taxes paid on fuels used for tax-exempt p...

  19. Water for energy and fuel production

    CERN Document Server

    Shah, Yatish T

    2014-01-01

    Water, in all its forms, may be the key to an environmentally friendly energy economy. Water is free, there is plenty of it, plus it carries what is generally believed to be the best long-term source of green energy-hydrogen. Water for Energy and Fuel Production explores the many roles of water in the energy and fuel industry. The text not only discusses water's use as a direct source of energy and fuel-such as hydrogen from water dissociation, methane from water-based clathrate molecules, hydroelectric dams, and hydrokinetic energy from tidal waves, off-shore undercurrents, and inland waterways-but also: Describes water's benign application in the production of oil, gas, coal, uranium, biomass, and other raw fuels, and as an energy carrier in the form of hot water and steam Examines water's role as a reactant, reaction medium, and catalyst-as well as steam's role as a reactant-for the conversion of raw fuels to synthetic fuels Explains how supercritical water can be used to convert fossil- and bio-based feed...

  20. Guidance Document for Alternative Diesel Fuels Proposed as Drop-In Fuels to Displace Diesel Fuels as Specified By ASTM Specification D975

    Science.gov (United States)

    2014-07-01

    includes both direct contact with the fuel and inhalation of fuel engine exhaust. The first source of information regarding the hazards associated...maintain its registration. Only gasoline and diesel fuel and fuel additives produced and commercially distributed for use in highway motor

  1. 40 CFR 80.591 - What are the product transfer document requirements for additives to be used in diesel fuel?

    Science.gov (United States)

    2010-07-01

    ... Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel... content requirements for use in diesel motor vehicles and nonroad engines.”; or (2) For those additives... requirements for use in model year 2007 and newer diesel motor vehicles or model year 2011 and newer diesel...

  2. 40 CFR 80.536 - How are NRLM diesel fuel credits used and transferred?

    Science.gov (United States)

    2010-07-01

    ... (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Temporary Compliance Option § 80.536 How... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How are NRLM diesel fuel credits used...

  3. Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts

    Directory of Open Access Journals (Sweden)

    X. Q. Liu

    2012-04-01

    Full Text Available In this paper a bio-based epoxy with outstanding thermal and mechanical properties was synthesized using a rosin-based epoxy monomer and a rosin-based curing agent. The chemical structures of rosin based epoxy monomer and curing agent were confirmed by Nuclear Magnetic Resonance (NMR and Fourier Transform Infrared (FT-IR spectra. The flexural mechanical and dynamic mechanical properties as well as thermal stability of the cured epoxy were investigated. The results showed that the cured epoxy exhibited a glass transition temperature (Tg of 164°C and its flexural strength and modulus were as high as 70 and 2200 MPa, respectively. This indicated that a wholly bio-based epoxy resin possessing high performance was successfully obtained.

  4. Bio-based hyperbranched thermosetting polyurethane/triethanolamine functionalized multi-walled carbon nanotube nanocomposites as shape memory materials.

    Science.gov (United States)

    Kalita, Hemjyoti; Karak, Niranjan

    2014-07-01

    Here, bio-based shape memory polymers have generated immense interest in recent times. Here, Bio-based hyperbranched polyurethane/triethanolamine functionalized multi-walled carbon nanotube (TEA-f-MWCNT) nanocomposites were prepared by in-situ pre-polymerization technique. The Fourier transform infrared spectroscopy and the transmission electron microscopic studies showed the strong interfacial adhesion and the homogeneous distribution of TEA-f-MWCNT in the polyurethane matrix. The prepared epoxy cured thermosetting nanocomposites exhibited enhanced tensile strength (6.5-34.5 MPa), scratch hardness (3.0-7.5 kg) and thermal stability (241-288 degrees C). The nanocomposites showed excellent shape fixity and shape recovery. The shape recovery time decreases (24-10 s) with the increase of TEA-f-MWCNT content in the nanocomposites. Thus the studied nanocomposites have potential to be used as advanced shape memory materials.

  5. Fuel Exhaling Fuel Cell.

    Science.gov (United States)

    Manzoor Bhat, Zahid; Thimmappa, Ravikumar; Devendrachari, Mruthyunjayachari Chattanahalli; Kottaichamy, Alagar Raja; Shafi, Shahid Pottachola; Varhade, Swapnil; Gautam, Manu; Thotiyl, Musthafa Ottakam

    2018-01-18

    State-of-the-art proton exchange membrane fuel cells (PEMFCs) anodically inhale H 2 fuel and cathodically expel water molecules. We show an unprecedented fuel cell concept exhibiting cathodic fuel exhalation capability of anodically inhaled fuel, driven by the neutralization energy on decoupling the direct acid-base chemistry. The fuel exhaling fuel cell delivered a peak power density of 70 mW/cm 2 at a peak current density of 160 mA/cm 2 with a cathodic H 2 output of ∼80 mL in 1 h. We illustrate that the energy benefits from the same fuel stream can at least be doubled by directing it through proposed neutralization electrochemical cell prior to PEMFC in a tandem configuration.

  6. Fuel cells : a viable fossil fuel alternative

    Energy Technology Data Exchange (ETDEWEB)

    Paduada, M.

    2007-02-15

    This article presented a program initiated by Natural Resources Canada (NRCan) to develop proof-of-concept of underground mining vehicles powered by fuel cells in order to eliminate emissions. Recent studies on American and Canadian underground mines provided the basis for estimating the operational cost savings of switching from diesel to fuel cells. For the Canadian mines evaluated, the estimated ventilation system operating cost reductions ranged from 29 per cent to 75 per cent. In order to demonstrate the viability of a fuel cell-powered vehicle, NRCan has designed a modified Caterpillar R1300 loader with a 160 kW hybrid power plant in which 3 stacks of fuel cells deliver up to 90 kW continuously, and a nickel-metal hydride battery provides up to 70 kW. The battery subsystem transiently boosts output to meet peak power requirements and also accommodates regenerative braking. Traction for the loader is provided by a brushless permanent magnet traction motor. The hydraulic pump motor is capable of a 55 kW load continuously. The loader's hydraulic and traction systems are operated independently. Future fuel cell-powered vehicles designed by the program may include a locomotive and a utility vehicle. Future mines running their operations with hydrogen-fueled equipment may also gain advantages by employing fuel cells in the operation of handheld equipment such as radios, flashlights, and headlamps. However, the proton exchange membrane (PEM) fuel cells used in the project are prohibitively expensive. The catalytic content of a fuel cell can add hundreds of dollars per kW of electric output. Production of catalytic precious metals will be strongly connected to the scale of use and acceptance of fuel cells in vehicles. In addition, the efficiency of hydrogen production and delivery is significantly lower than the well-to-tank efficiency of many conventional fuels. It was concluded that an adequate hydrogen infrastructure will be required for the mining industry

  7. Roles of programmable logic controllers in fuel reprocessing plants

    International Nuclear Information System (INIS)

    Mishra, Hrishikesh; Balakrishnan, V.P.; Pandya, G.J.

    1999-01-01

    Fuel charging facility is another application of Programmable Logic Controllers (PLC) in fuel reprocessing plants, that involves automatic operation of fuel cask dolly, charging motor, pneumatic doors, clutches, clamps, stepper motors and rod pushers in a pre-determined sequence. Block diagram of ACF system is given for underlining the scope of control and interlocks requirements involved for automation of the fuel charging system has been provided for the purpose at KARP Plant, Kalpakkam

  8. Fine motor control

    Science.gov (United States)

    ... gross (large, general) motor control. An example of gross motor control is waving an arm in greeting. Problems ... out the child's developmental age. Children develop fine motor skills over time, by practicing and being taught. To ...

  9. Investigation of curing rates of bio-based thiol-ene films from diallyl 2,5-furandicaboxylate

    DEFF Research Database (Denmark)

    Larsen, Daniel Bo; Sønderbæk-Jørgensen, Rene; Duus, Jens Ø.

    2018-01-01

    The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV-crosslinking. In......The bio-based monomer, 2,5-furandicarboxylic acid, has been adapted to classic thiol-ene chemistry by derivatization of the acid with allyl alcohol. This new monomer has allowed for the synthesis of new thermoset systems, capable of forming green, sustainable materials through UV......-crosslinking. In this study, the synthesis of the new monomer along with thorough kinetic studies of the new thermoset systems are presented. In order to determine kinetic values for the systems, all reactions have been followed by real-time FT-IR. Initially, a study of three different photoinitiators is performed...... on a classic TEMPIC-TATATO system, in order to determine the superior initiator for the new systems. The new monomer is crosslinked with five different thiol compounds in both stoichiometric and off-stoichiometric ratios, yielding an array of bio-based thermosets. The properties of these systems are determined...

  10. Biogas for heat, power and motor fuel

    International Nuclear Information System (INIS)

    Nagel, C.; Kilchmann, A.

    2009-01-01

    In this interview with Dr. Serge Biollaz, his work at the Paul Scherrer Institute (PSI) in Switzerland concerning the use of dry biomass as a source of energy for the generation of electrical energy or synthetic natural gas (SNG) is reviewed. In the interview, the following topics are discussed: Work in an International Energy Agency (IEA) bioenergy task, the work being done at the PSI, work also being done by colleagues in the wet biomass area, the gasification of biomass, gas purification, effects on catalytic converters and other critical effects encountered. The possibility of building SNG plants in Switzerland is discussed, as are the costs involved. SNG generation as an alternative to using wood in the form of wood pellets is discussed. Figures are also presented on the theoretical and usable amounts of energy available in biomass in Switzerland. The considerable - but still unused - potential available is commented on

  11. Motor control for a brushless DC motor

    Science.gov (United States)

    Peterson, William J. (Inventor); Faulkner, Dennis T. (Inventor)

    1985-01-01

    This invention relates to a motor control system for a brushless DC motor having an inverter responsively coupled to the motor control system and in power transmitting relationship to the motor. The motor control system includes a motor rotor speed detecting unit that provides a pulsed waveform signal proportional to rotor speed. This pulsed waveform signal is delivered to the inverter to thereby cause an inverter fundamental current waveform output to the motor to be switched at a rate proportional to said rotor speed. In addition, the fundamental current waveform is also pulse width modulated at a rate proportional to the rotor speed. A fundamental current waveform phase advance circuit is controllingly coupled to the inverter. The phase advance circuit is coupled to receive the pulsed waveform signal from the motor rotor speed detecting unit and phase advance the pulsed waveform signal as a predetermined function of motor speed to thereby cause the fundamental current waveform to be advanced and thereby compensate for fundamental current waveform lag due to motor winding reactance which allows the motor to operate at higher speeds than the motor is rated while providing optimal torque and therefore increased efficiency.

  12. Acute Dermal Irritation Study of Six Jet Fuels in New Zealand White Rabbits: Comparison of Four Bio-Based Jet Fuels with Two Petroleum JP-8 Fuels

    Science.gov (United States)

    2014-02-01

    Shafer University of Dayton Research Institute Wright-Patterson AFB OH David R. Mattie Bioeffects Division Molecular Bioeffects Branch February...master schedule for the company. Metasys DDC Electronic Environmental Control System Controls and monitors animal room environmental conditions

  13. 40 CFR 600.113-78 - Fuel economy calculations.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Fuel economy calculations. 600.113-78... FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1978 and Later Model Year Automobiles-Test Procedures § 600.113-78 Fuel economy calculations. The...

  14. 40 CFR 600.113-88 - Fuel economy calculations.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Fuel economy calculations. 600.113-88... FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1978 and Later Model Year Automobiles-Test Procedures § 600.113-88 Fuel economy calculations. The...

  15. 40 CFR 600.113-93 - Fuel economy calculations.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Fuel economy calculations. 600.113-93... FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1978 and Later Model Year Automobiles-Test Procedures § 600.113-93 Fuel economy calculations. The...

  16. Characterization of radiation modified κ-carrageenan oligomers for bio-based materials development

    International Nuclear Information System (INIS)

    Abad, Lucille V.; Relleve, Lorna S.; Aranilla, Charito T.; Racadio, Darwin T.; Dela Rosa, Alumanda M.

    2011-01-01

    κ-carrageenan oligomers are known to have several biological activities such as anti-HIV, anti-herpes, antitumor and antioxidant properties. Recent progress in the development of radiation modified κ-carrageenan has resulted in new applications such as plant growth promoter, radiation dose indicator and hydrogels for wound dressing. This presentation would touch on the changes in chemical structure, gelation and conformational transition behavior and molecular size of κ-carrageenan at doses from 0 to 200 kGy and would be correlated to these functions for the development of bio-based materials. Chemical and spectral analyses were carried out using UV-Vis spectroscopy, FT-IR spectroscopy, NMR spectroscopy, reducing sugar analysis, free sulfate and carboxylic acid analysis. The chemical and spectral analyses of the radiolytic products indicated increasing reducing sugars, carbonyl, carboxylic acids, and sulfates with increasing doses which reached a maximum level at a certain dose depending on the irradiation condition. Values were very much lower in solid irradiation (in vacuum and in air) as compared to aqueous irradiation. NMR data also revealed an intact structure of the oligomer irradiated at 100 kGy in the specific fraction that contains an Mw = (3-10) kDa. κ-carrageenan oligomers exhibited antioxidant properties as determined by hydroxyl radical scavenging activity, reducing power and DPPH radical scavenging capacity assay. The degree of oxidative inhibition increased with increasing dose which can be attributed to higher reducing sugar. Dynamic light scattering (DLS) experiments showed that a dose of up to 50 kGy, sol-gelation transition was still observed. Beyond 50 kGy, no gelation took place, instead appearance of fast relax-carrageenan mode in characteristic decay time function was observed at doses of (75-150) kGy. Optimum peak intensity was found at 100 kGy (mol wt. 5-10 kDa) which coincides with the optimum plant growth promoter effect in κ

  17. High efficiency motors; Motores de alta eficiencia

    Energy Technology Data Exchange (ETDEWEB)

    Uranga Favela, Ivan Jaime [Energia Controlada de Mexico, S. A. de C. V., Mexico, D. F. (Mexico)

    1993-12-31

    This paper is a technical-financial study of the high efficiency and super-premium motors. As it is widely known, more than 60% of the electrical energy generated in the country is used for the operation of motors, in industry as well as in commerce. Therefore the importance that the motors have in the efficient energy use. [Espanol] El presente trabajo es un estudio tecnico-financiero de los motores de alta eficiencia y los motores super premium. Como es ampliamente conocido, mas del 60% de la energia electrica generada en el pais, es utilizada para accionar motores, dentro de la industria y el comercio. De alli la importancia que los motores tienen en el uso eficiente de la energia.

  18. High efficiency motors; Motores de alta eficiencia

    Energy Technology Data Exchange (ETDEWEB)

    Uranga Favela, Ivan Jaime [Energia Controlada de Mexico, S. A. de C. V., Mexico, D. F. (Mexico)

    1992-12-31

    This paper is a technical-financial study of the high efficiency and super-premium motors. As it is widely known, more than 60% of the electrical energy generated in the country is used for the operation of motors, in industry as well as in commerce. Therefore the importance that the motors have in the efficient energy use. [Espanol] El presente trabajo es un estudio tecnico-financiero de los motores de alta eficiencia y los motores super premium. Como es ampliamente conocido, mas del 60% de la energia electrica generada en el pais, es utilizada para accionar motores, dentro de la industria y el comercio. De alli la importancia que los motores tienen en el uso eficiente de la energia.

  19. Sipping fuel and saving lives: increasing fuel economy withoutsacrificing safety

    Energy Technology Data Exchange (ETDEWEB)

    Gordon, Deborah; Greene, David L.; Ross, Marc H.; Wenzel, Tom P.

    2007-06-11

    The public, automakers, and policymakers have long worried about trade-offs between increased fuel economy in motor vehicles and reduced safety. The conclusion of a broad group of experts on safety and fuel economy in the auto sector is that no trade-off is required. There are a wide variety of technologies and approaches available to advance vehicle fuel economy that have no effect on vehicle safety. Conversely, there are many technologies and approaches available to advance vehicle safety that are not detrimental to vehicle fuel economy. Congress is considering new policies to increase the fuel economy of new automobiles in order to reduce oil dependence and reduce greenhouse gas emissions. The findings reported here offer reassurance on an important dimension of that work: It is possible to significantly increase the fuel economy of motor vehicles without compromising their safety. Automobiles on the road today demonstrate that higher fuel economy and greater safety can co-exist. Some of the safest vehicles have higher fuel economy, while some of the least safe vehicles driven today--heavy, large trucks and SUVs--have the lowest fuel economy. At an October 3, 2006 workshop, leading researchers from national laboratories, academia, auto manufacturers, insurance research industry, consumer and environmental groups, material supply industries, and the federal government agreed that vehicles could be designed to simultaneously improve safety and fuel economy. The real question is not whether we can realize this goal, but the best path to get there. The experts' studies reveal important new conclusions about fuel economy and safety, including: (1) Vehicle fuel economy can be increased without affecting safety, and vice versa; (2) Reducing the weight and height of the heaviest SUVs and pickup trucks will simultaneously increase both their fuel economy and overall safety; and (3) Advanced materials can decouple size from mass, creating important new possibilities

  20. 76 FR 80362 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Fuel Quality...

    Science.gov (United States)

    2011-12-23

    ... requirements for motor vehicle diesel fuel and non-road, locomotive and marine diesel fuel. It also includes... the regulations at 40 CFR Part 80, Subpart I--``Motor Vehicle, Non-Road, Locomotive, and Marine Diesel... expiring approval, we had estimated 285,261 hours. Most motor vehicle diesel reporting has now ended, which...

  1. Synthesis and Characterization of Bio-based Nanomaterials from Jabon (Anthocephalus cadamba (Roxb. Miq Wood Bark: an Organic Waste Material from Community Forest

    Directory of Open Access Journals (Sweden)

    Sutrisno

    2015-06-01

    Full Text Available The application of nanotechnology to produce nanomaterials from renewable bio-based materials, like wood bark, has great potential to benefit the wood processing industry. To support this issue, we investigated the production of bio-based nanomaterials using conventional balls milling. Jabon (Anthocephalus cadamba(Roxb. Miq wood bark (JWB, an organic waste material from a community forest was subjected to conventional balls milling for 96 h and was converted into bio-based nanomaterial. The morphology and particle size, chemical components, functional groups and crystallinity of the bio-based nanomaterial were evaluated using scanning electron microscopy (SEM, scanning electron microscopy extended with energy dispersive X-ray spectroscopy (SEM-EDS, Fourier transform infrared spectroscopy (FTIR, and X-ray diffraction (XRD. The particle-sizes obtained for the JWB bio-based nanomaterial were between 43 nm to 469 nm and the functional groups were detected as cellulose. The chemical components found were carbon, oxygen, chloride, potassium and calcium, except for the sample produced from sieve type T14, which did not contain chloride. The crystalline structure was calcium oxalate hydrate (C2CaO4.H2O with crystalline sizes 21 nm and 15 nm, produced from sieve types T14 and T200 respectively.

  2. Advances in Base-Free Oxidation of Bio-Based Compounds on Supported Gold Catalysts

    Directory of Open Access Journals (Sweden)

    Robert Wojcieszak

    2017-11-01

    Full Text Available The oxidation of bio-based molecules in general, and of carbohydrates and furanics in particular, is a highly attractive process. The catalytic conversion of renewable compounds is of high importance. Acids and other chemical intermediates issued from oxidation processes have many applications related, especially, to food and detergents, as well as to pharmaceutics, cosmetics, and the chemical industry. Until now, the oxidation of sugars, furfural, or 5-hydroxymethylfurfural has been mainly conducted through biochemical processes or with strong inorganic oxidants. The use of these processes very often presents many disadvantages, especially regarding products separation and selectivity control. Generally, the oxidation is performed in batch conditions using an appropriate catalyst and a basic aqueous solution (pH 7–9, while bubbling oxygen or air through the slurry. However, there is a renewed interest in working in base-free conditions to avoid the production of salts. Actually, this gives direct access to different acids or diacids without laborious product purification steps. This review focuses on processes applying gold-based catalysts, and on the catalytic properties of these systems in the base-free oxidation of important compounds: C5–C6 sugars, furfural, and 5-hydroxymethylfurfural. A better understanding of the chemical and physical properties of the catalysts and of the operating conditions applied in the oxidation reactions is essential. For this reason, in this review we put emphasis on these most impacting factors.

  3. Polymerization and Structure of Bio-Based Plastics: A Computer Simulation

    Science.gov (United States)

    Khot, Shrikant N.; Wool, Richard P.

    2001-03-01

    We recently examined several hundred chemical pathways to convert chemically functionalized plant oil triglycerides, monoglycerides and reactive diluents into high performance plastics with a broad range of properties (US Patent No. 6,121,398). The resulting polymers had linear, branched, light- and highly-crosslinked chain architectures and could be used as pressure sensitive adhesives, elastomers and high performance rigid thermoset composite resins. To optimize the molecular design and minimize the number of chemical trials in this system with excess degrees of freedom, we developed a computer simulation of the free radical polymerization process. The triglyceride structure, degree of chemical substitution, mole fractions, fatty acid distribution function, and reaction kinetic parameters were used as initial inputs on a 3d lattice simulation. The evolution of the network fractal structure was computed and used to measure crosslink density, dangling ends, degree of reaction and defects in the lattice. The molecular connectivity was used to determine strength via a vector percolation model of fracture. The simulation permitted the optimal design of new bio-based materials with respect to monomer selection, cure reaction conditions and desired properties. Supported by the National Science Foundation

  4. Production and 3D printing processing of bio-based thermoplastic filament

    Directory of Open Access Journals (Sweden)

    Gkartzou Eleni

    2017-01-01

    Full Text Available In this work, an extrusion-based 3D printing technique was employed for processing of biobased blends of Poly(Lactic Acid (PLA with low-cost kraft lignin. In Fused Filament Fabrication (FFF 3D printing process, objects are built in a layer-by-layer fashion by melting, extruding and selectively depositing thermoplastic fibers on a platform. These fibers are used as building blocks for more complex structures with defined microarchitecture, in an automated, cost-effective process, with minimum material waste. A sustainable material consisting of lignin biopolymer blended with poly(lactic acid was examined for its physical properties and for its melt processability during the FFF process. Samples with different PLA/lignin weight ratios were prepared and their mechanical (tensile testing, thermal (Differential Scanning Calorimetry analysis and morphological (optical and scanning electron microscopy, SEM properties were studied. The composition with optimum properties was selected for the production of 3D-printing filament. Three process parameters, which contribute to shear rate and stress imposed on the melt, were examined: extrusion temperature, printing speed and fiber’s width varied and their effect on extrudates’ morphology was evaluated. The mechanical properties of 3D printed specimens were assessed with tensile testing and SEM fractography.

  5. Metabolic engineering of Escherichia coli: a sustainable industrial platform for bio-based chemical production.

    Science.gov (United States)

    Chen, Xianzhong; Zhou, Li; Tian, Kangming; Kumar, Ashwani; Singh, Suren; Prior, Bernard A; Wang, Zhengxiang

    2013-12-01

    In order to decrease carbon emissions and negative environmental impacts of various pollutants, more bulk and/or fine chemicals are produced by bioprocesses, replacing the traditional energy and fossil based intensive route. The Gram-negative rod-shaped bacterium, Escherichia coli has been studied extensively on a fundamental and applied level and has become a predominant host microorganism for industrial applications. Furthermore, metabolic engineering of E. coli for the enhanced biochemical production has been significantly promoted by the integrated use of recent developments in systems biology, synthetic biology and evolutionary engineering. In this review, we focus on recent efforts devoted to the use of genetically engineered E. coli as a sustainable platform for the production of industrially important biochemicals such as biofuels, organic acids, amino acids, sugar alcohols and biopolymers. In addition, representative secondary metabolites produced by E. coli will be systematically discussed and the successful strategies for strain improvements will be highlighted. Moreover, this review presents guidelines for future developments in the bio-based chemical production using E. coli as an industrial platform. Copyright © 2013 Elsevier Inc. All rights reserved.

  6. Recent Developments on Genetic Engineering of Microalgae for Biofuels and Bio-Based Chemicals.

    Science.gov (United States)

    Ng, I-Son; Tan, Shih-I; Kao, Pei-Hsun; Chang, Yu-Kaung; Chang, Jo-Shu

    2017-10-01

    Microalgae serve as a promising source for the production of biofuels and bio-based chemicals. They are superior to terrestrial plants as feedstock in many aspects and their biomass is naturally rich in lipids, carbohydrates, proteins, pigments, and other valuable compounds. Due to the relatively slow growth rate and high cultivation cost of microalgae, to screen efficient and robust microalgal strains as well as genetic modifications of the available strains for further improvement are of urgent demand in the development of microalgae-based biorefinery. In genetic engineering of microalgae, transformation and selection methods are the key steps to accomplish the target gene modification. However, determination of the preferable type and dosage of antibiotics used for transformant selection is usually time-consuming and microalgal-strain-dependent. Therefore, more powerful and efficient techniques should be developed to meet this need. In this review, the conventional and emerging genome-editing tools (e.g., CRISPR-Cas9, TALEN, and ZFN) used in editing the genomes of nuclear, mitochondria, and chloroplast of microalgae are thoroughly surveyed. Although all the techniques mentioned above demonstrate their abilities to perform gene editing and desired phenotype screening, there still need to overcome higher production cost and lower biomass productivity, to achieve efficient production of the desired products in microalgal biorefineries. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Feasibility of bio-based lactate esters as extractant for biobutanol recovery: (Liquid + liquid) equilibria

    International Nuclear Information System (INIS)

    Zheng, Shaohua; Cheng, Hongye; Chen, Lifang; Qi, Zhiwen

    2016-01-01

    Highlights: • Lactate esters were studied as solvent to remove butanol from aqueous media. • (Liquid + liquid) equilibrium data were measured at T = 298.15 K and 1 atm. • Selectivity and 1-butanol partition coefficient were calculated. • COSMO-based study of separation efficiency on solvent structure was conducted. - Abstract: As bio-based solvents, lactate esters can be used as extractant for removing 1-butanol from the aqueous fermentation broths. In order to evaluate the separation efficiency of butyl lactate and 2-ethylhexyl lactate for the extraction of 1-butanol from its mixture with water, the (liquid + liquid) equilibrium for the ternary systems {water (1) + 1-butanol (2) + lactate ester (3)} were measured at T = 298.15 K. The 1-butanol partition coefficient varied in the range of 4.46 to 10.29, and the solvent selectivity within 32.12 to 108.18. For the separation of low-concentration butanol from fermentation broths, butyl lactate exhibits higher partition coefficient and lower selectivity than 2-ethylhexyl lactate. The NRTL model was employed to correlate the experimental data, and the COSMO-RS theory was utilized to predict the (liquid + liquid) equilibria and to analyze the influence of lactate esters on extraction efficiency.

  8. Determining the bio-based content of bio-plastics used in Thailand by radiocarbon analysis

    Science.gov (United States)

    Ploykrathok, T.; Chanyotha, S.

    2017-06-01

    Presently, there is an increased interest in the development of bio-plastic products from agricultural materials which are biodegradable in order to reduce the problem of waste disposal. Since the amount of modern carbon in bio-plastics can indicate how much the amount of agricultural materials are contained in the bio-plastic products, this research aims to determine the modern carbon in bio-plastic using the carbon dioxide absorption method. The radioactivity of carbon-14 contained in the sample is measured by liquid scintillation counter (Tri-carb 3110 TR, PerkinElmer). The percentages of bio-based content in the samples were determined by comparing the observed modern carbon content with the values contained in agricultural raw materials. The experimental results show that only poly(lactic acid) samples have the modern carbon content of 97.4%, which is close to the agricultural materials while other bio-plastics types are found to have less than 50% of the modern carbon content. In other words, most of these bio-plastic samples were mixed with other materials which are not agriculturally originated.

  9. Environmental performance of bio-based and biodegradable plastics: the road ahead.

    Science.gov (United States)

    Lambert, Scott; Wagner, Martin

    2017-11-13

    Future plastic materials will be very different from those that are used today. The increasing importance of sustainability promotes the development of bio-based and biodegradable polymers, sometimes misleadingly referred to as 'bioplastics'. Because both terms imply "green" sources and "clean" removal, this paper aims at critically discussing the sometimes-conflicting terminology as well as renewable sources with a special focus on the degradation of these polymers in natural environments. With regard to the former we review innovations in feedstock development (e.g. microalgae and food wastes). In terms of the latter, we highlight the effects that polymer structure, additives, and environmental variables have on plastic biodegradability. We argue that the 'biodegradable' end-product does not necessarily degrade once emitted to the environment because chemical additives used to make them fit for purpose will increase the longevity. In the future, this trend may continue as the plastics industry also is expected to be a major user of nanocomposites. Overall, there is a need to assess the performance of polymer innovations in terms of their biodegradability especially under realistic waste management and environmental conditions, to avoid the unwanted release of plastic degradation products in receiving environments.

  10. Chemical and enzymatic catalytic routes to polyesters and oligopeptides biobased materials

    Science.gov (United States)

    Zhu, Jianhui

    My Ph.D research focuses on the synthesis and property studies of different biobased materials, including polyesters, polyurethanes and oligopeptides. The first study describes the synthesis, crystal structure and physico-mechanical properties of a bio-based polyester prepared from 2,5-furandicarboxylic acid (FDCA) and 1,4-butanediol. Melt-polycondensation experiments were conducted by a two-stage polymerization using titanium tetraisopropoxide (Ti[OiPr] 4) as catalyst. Polymerization conditions (catalyst concentration, reaction time and 2nd stage reaction temperature) were varied to optimize poly(butylene furan dicarboxylate), PBF, molecular weight. A series of PBFs with different Mw were characterized by Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), Dynamic Mechanical Thermal Analysis (DMTA), X-Ray diffraction and tensile testing. Influence of molecular weight and melting/crystallization enthalpy on PBF material tensile properties was explored. Cold-drawing tensile tests at room temperature for PBF with Mw 16K to 27K showed a brittle-to-ductile transition. When Mw reaches 38K, the Young's Modulus of PBF remains above 900 MPa, and the elongation at break increases to above 1000%. The mechanical properties, thermal properties and crystal structures of PBF were similar to petroleum derived poly(butylenes terephthalate), PBT. Fiber diagrams of uniaxially stretched PBF films were collected, indexed, and the unit cell was determined as triclinic (a=4.78(3) A, b=6.03(5) A, c=12.3(1) A, alpha=110.1(2)°, beta=121.1(3)°, gamma=100.6(2)°). A crystal structure was derived from this data and final atomic coordinates are reported. We concluded that there is a close similarity of the PBF structure to PBT alpha- and beta-forms. In the second study, a biobased long chain polyester polyol (PC14-OH) was synthesized from o-hydroxytetradecanoic acid (o-HOC14) and 1,4-butanediol. The first section about polyester polyurethanes describes the synthesis

  11. Effect of melamine phosphate on the thermal stability and flammability of bio-based polyurethanes

    International Nuclear Information System (INIS)

    Yakushin, Vladimir; Sevastyanova, Irina; Vilsone, Dzintra; Avots, Andris

    2016-01-01

    The effect of melamine phosphate (MP) on the thermal stability of bio-based polyurethane and the flammability parameters of wood samples with polyurethane coatings was studied. Thermogravimetric analysis and cone calorimeter test at a heat flux of 35 kW/m 2 were used for this purpose. The main characteristics of the thermal stability and flammability of the coating with addition of MP were compared with the characteristics of analogous coatings with addition of ammonium polyphosphate (APP), as well as APP in combination with melamine. It was found that the use of MP as an intumescent additive allows a considerable decrease of most of the flammability parameters of the polyurethane based on tall oil fatty acids, like APP. To reach the maximum effect, it is enough to load in the polyurethane 20% of MP. In contrast to APP, MP reduces also the smoke release of the samples. Using MP in combination with APP at definite weight ratios, it is possible to essentially reduce the flammability parameters of polyurethane coatings, such as PHRR, THR and MARHE. (paper)

  12. Determining the bio-based content of bio-plastics used in Thailand by radiocarbon analysis

    International Nuclear Information System (INIS)

    Ploykrathok, T; Chanyotha, S

    2017-01-01

    Presently, there is an increased interest in the development of bio-plastic products from agricultural materials which are biodegradable in order to reduce the problem of waste disposal. Since the amount of modern carbon in bio-plastics can indicate how much the amount of agricultural materials are contained in the bio-plastic products, this research aims to determine the modern carbon in bio-plastic using the carbon dioxide absorption method. The radioactivity of carbon-14 contained in the sample is measured by liquid scintillation counter (Tri-carb 3110 TR, PerkinElmer). The percentages of bio-based content in the samples were determined by comparing the observed modern carbon content with the values contained in agricultural raw materials. The experimental results show that only poly(lactic acid) samples have the modern carbon content of 97.4%, which is close to the agricultural materials while other bio-plastics types are found to have less than 50% of the modern carbon content. In other words, most of these bio-plastic samples were mixed with other materials which are not agriculturally originated. (paper)

  13. Biobased alkylphenols from lignins via a two-step pyrolysis - Hydrodeoxygenation approach.

    Science.gov (United States)

    de Wild, P J; Huijgen, W J J; Kloekhorst, A; Chowdari, R K; Heeres, H J

    2017-04-01

    Five technical lignins (three organosolv, Kraft and soda lignin) were depolymerised to produce monomeric biobased aromatics, particularly alkylphenols, by a new two-stage thermochemical approach consisting of dedicated pyrolysis followed by catalytic hydrodeoxygenation (HDO) of the resulting pyrolysis oils. Pyrolysis yielded a mixture of guaiacols, catechols and, optionally, syringols in addition to alkylphenols. HDO with heterogeneous catalysts (Ru/C, CoMo/alumina, phosphided NiMO/C) effectively directed the product mixture towards alkylphenols by, among others, demethoxylation. Up to 15wt% monomeric aromatics of which 11wt% alkylphenols was obtained (on the lignin intake) with limited solid formation (<3wt% on lignin oil intake). For comparison, solid Kraft lignin was also directly hydrotreated for simultaneous depolymerisation and deoxygenation resulting in two times more alkylphenols. However, the alkylphenols concentration in the product oil is higher for the two-stage approach. Future research should compare direct hydrotreatment and the two-stage approach in more detail by techno-economic assessments. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. The Use of Biodiesel Residues for Heat Insulating Biobased Polyurethane Foams

    Directory of Open Access Journals (Sweden)

    Nihan Özveren

    2017-01-01

    Full Text Available The commercial and biobased polyurethane foams (PUF were produced and characterized in this study. Commercial polyether polyol, crude glycerol, methanol-free crude glycerol, and pure glycerol were used as polyols. Crude glycerol is byproduct of the biodiesel production, and it is a kind of biofuel residue. Polyol blends were prepared by mixing the glycerol types and the commercial polyol with different amounts, 10 wt%, 30 wt%, 50 wt%, and 80 wt%. All types of polyol blends were reacted with polymeric diphenyl methane diisocyanates (PMDI for the production of rigid foams. Thermal properties of polyurethane foams are examined by thermogravimetric analysis (TGA and thermal conductivity tests. The structures of polyurethane foams were examined by Fourier Transformed Infrared Spectroscopy (FTIR. Changes in morphology of foams were investigated by Scanning Electron Microscopy (SEM. Mechanical properties of polyurethane foams were determined by compression tests. This study identifies the critical aspects of polyurethane foam formation by the use of various polyols and furthermore offers new uses of crude glycerol and methanol-free crude glycerol which are byproducts of biodiesel industry.

  15. Development of the University of Washington Biofuels and Biobased Chemicals Process Laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Gustafson, Richard [University of Washington

    2014-02-04

    The funding from this research grant enabled us to design and build a bioconversion steam explosion reactor and ancillary equipment such as a high pressure boiler and a fermenter to support the bioconversion process research. This equipment has been in constant use since its installation in 2012. Following are research projects that it has supported: • Investigation of novel chip production method in biofuels production • Investigation of biomass refining following steam explosion • Several studies on use of different biomass feedstocks • Investigation of biomass moisture content on pretreatment efficacy. • Development of novel instruments for biorefinery process control Having this equipment was also instrumental in the University of Washington receiving a $40 million grant from the US Department of Agriculture for biofuels development as well as several other smaller grants. The research that is being done with the equipment from this grant will facilitate the establishment of a biofuels industry in the Pacific Northwest and enable the University of Washington to launch a substantial biofuels and bio-based product research program.

  16. Plant cell wall sugars: sweeteners for a bio-based economy.

    Science.gov (United States)

    Van de Wouwer, Dorien; Boerjan, Wout; Vanholme, Bartel

    2018-02-12

    Global warming and the consequent climate change is one of the major environmental challenges we are facing today. The driving force behind the rise in temperature is our fossil-based economy, which releases massive amounts of the greenhouse gas carbon dioxide into the atmosphere. In order to reduce greenhouse gas emission, we need to scale down our dependency on fossil resources, implying that we need other sources for energy and chemicals to feed our economy. Here, plants have an important role to play; by means of photosynthesis, plants capture solar energy to split water and fix carbon derived from atmospheric carbon dioxide. A significant fraction of the fixed carbon ends up as polysaccharides in the plant cell wall. Fermentable sugars derived from cell wall polysaccharides form an ideal carbon source for the production of bio-platform molecules. However, a major limiting factor in the use of plant biomass as feedstock for the bio-based economy is the complexity of the plant cell wall and its recalcitrance towards deconstruction. To facilitate the release of fermentable sugars during downstream biomass processing, the composition and structure of the cell wall can be engineered. Different strategies to reduce cell wall recalcitrance will be described in this review. The ultimate goal is to obtain a tailor-made biomass, derived from plants with a cell wall optimized for particular industrial or agricultural applications, without affecting plant growth and development. This article is protected by copyright. All rights reserved.

  17. Bio-based and biodegradable plastics for use in crop production.

    Science.gov (United States)

    Riggi, Ezio; Santagata, Gabriella; Malinconico, Mario

    2011-01-01

    The production and management of crops uses plastics for many applications (e.g., low tunnels, high tunnels, greenhouses, mulching, silage bags, hay bales, pheromone traps, coatings of fertilizers or pesticides or hormones or seeds, and nursery pots and containers for growing transplants). All these applications have led some authors to adopt the term "plasticulture" when discussing the use of plastic materials in agriculture and related industries. Unfortunately, the sustainability of this use of plastics is low, and renewability and degradability have become key words in the debate over sustainable production and utilization of plastic. Recently, researchers and the plastics industry have made strong efforts (i) to identify new biopolymers and natural additives from renewable sources that can be used in plastics production and (ii) to enhance the degradability (biological or physical) of the new ecologically sustainable materials. In the present review, we describe the main research results, current applications, patents that have been applied for in the last two decades, and future perspectives on sustainable use of plastics to support crop production. The article presents some promising patents on bio-based and biodegradable plastics for use in crop production.

  18. A review on electrospun bio-based polymers for water treatment

    Directory of Open Access Journals (Sweden)

    T. C. Mokhena

    2015-10-01

    Full Text Available Over the past decades, electrospinning of biopolymers down to nanoscale garnered much interest to address most of the millennia issues related to water treatment. The fabrication of these nanostructured membranes added a new dimension to the current nanotechnologies where a wide range of materials can be processed to their nanosize. Electrospinning is a simple and versatile technique to fabricate unique nanostructured membranes with fascinating properties for a wide spectrum of applications such as filtration and others. These nanostructured membranes, fabricated by electrospinning, were found to be of a paramount importance because of their advanced inherited properties such as large surface-to-volume ratio, as well as tuneable porosity, stability, and high permeability. The extensive research conducted on these materials extended the success of electrospinning not only to bio-based polymer nanofibres, but to their hybrids and their derivatives. The technique also created avenues for advanced and massive production of nanofibres. This paper reviews the recent developments in the electrospinning technique. Electrospinning of biopolymers, their blends and functionalization using metals/metal oxides, and the potential applications of electrospun nanofibrous membranes in water filtration are discussed.

  19. Experimental Measurements of Journal Bearing Friction Using Mineral, Synthetic, and Bio-Based Lubricants

    Directory of Open Access Journals (Sweden)

    Pantelis G. Nikolakopoulos

    2015-04-01

    Full Text Available The environmental impact of many industrial and naval applications is becoming increasingly important. Journal bearings are crucial components related with the reliable, safe and environmentally friendly operation of rotating machinery in many applications, e.g., in hydroplants, ships, power generation stations. The maintenance activities in certain cases also have considerable environmental impact. Fortunately, it is relatively easy to reduce the impact by changing the way lubricants are being used. Selecting the proper lubricant is important to sharply reduce long-term costs. The best-fit product selection can mean longer lubricant life, reduced machine wear, reduced incipient power losses and improved safety. Suitable basestocks and additives reduce environmental impact. In this paper, three types of lubricants are used in order to examine their effects on the tribological behavior of journal bearings. A mineral oil, a synthetic oil and a bio-based lubricant are experimentally and analytically examined for several configurations of load and journal rotational velocity. The friction forces and the hydrodynamic friction coefficients are calculated and compared. This investigation can assist the correct choice of lubricant in journal bearings with minimized environmental footprint.

  20. Synthesis and characterization of a novel bio-based resin from maleated soybean oil polyols

    Science.gov (United States)

    Li, Y. T.; Yang, L. T.; Zhang, H.

    2017-02-01

    In this paper, a novel bio-based resin was prepared by the radical copolymerization of maleated soybean oil polyols (MSBOP) and styrene (ST). Structure of the product was studied by Fourier transformation infrared spectrometer (FT-IR), and the result was found to be consistent with that of theoretical structure. Swelling experiments indicated that the crosslinking degree increased with the increase of hydroxyl value. Thermal analysis by differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TG) revealed that glass transition temperature (Tg) of the polymer increased with increasing hydroxyl values, and that its thermal stability showed a good correlation with the hydroxyl value. The tensile strength and impact strength were significantly affected by the hydroxyl value of soybean oil polyols. With increasing hydroxyl value, the tensile strength presented an increasing trend, while the impact strength showed a decreasing one. Moreover, the property of the polymer from elastomer to plastic character also depended on the functionality of the hydroxyl value of soybean oil polyols.

  1. Utilization of diesel fuel, anhydrous ethanol and additives blend of a stationary diesel engine with rotatory pump; Utilizacao de mistura ternaria alcool, diesel e aditivo em motores do ciclo diesel com bomba de injecao rotativa

    Energy Technology Data Exchange (ETDEWEB)

    Reyes Cruz, Yordanka; Cavado Osorio, Alberto [Centro de Pesquisas de Petroleo (CEINPET), Havana (Cuba); Belchior, Carlos Rodrigues Pereira; Pereira, Pedro P.; Pinto, Nauberto Rodrigues [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Centro de Tecnologia. Dept. de Engenharia Naval e Mecanica; Aranda, Donato A. Gomes [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica

    2008-07-01

    In this paper is analyzed the performance and fuel consumption of a stationary Diesel engine, with rotary diesel fuel injection pump, using (diesel fuel + anhydrous ethanol + 0.5% additive) blend. The engine performance parameters and fuel consumption tests were performed at the Termic Machine Laboratory, located in Federal University of Rio de Janeiro, and evaluated using a MWM Series 10 model 4.10 TCA. Two test cycles were used for this test program: the tests were carried out starting from the base diesel S-500, used as a reference; the engine operated with (diesel fuel S-500 - 8% anhydrous ethanol - DIOLEFECT additive (0,5% SPAN80 + 0,1% Biomix-D)) blend. The results indicate that: the reduction levels in power and torque of engine are approximately the same which is (2,55{+-}2%), the brake specific fuel consumption increased in 1,8%. (author)

  2. 78 FR 21850 - Federal Motor Vehicle Safety Standards; Matters Incorporated by Reference

    Science.gov (United States)

    2013-04-12

    ... to the 1985 Annual Book of ASTM Standards, Vol. 05.04, ``Test Methods for Rating Motor, Diesel... for Rating Motor, Diesel, Aviation Fuels, A2. Reference Materials and Blending Accessories, (``ASTM... [Docket No. NHTSA-2011-0185] RIN 2127-AL25 Federal Motor Vehicle Safety Standards; Matters Incorporated by...

  3. Fuel cell system blower configuration

    Science.gov (United States)

    Patel, Kirtikumar H.; Saito, Kazuo

    2017-11-28

    An exemplary fuel cell system includes a cell stack assembly having a plurality of cathode components and a plurality of anode components. A first reactant blower has an outlet situated to provide a first reactant to the cathode components. A second reactant blower has an outlet situated to provide a second reactant to the anode components. The second reactant blower includes a fan portion that moves the second reactant through the outlet. The second reactant blower also includes a motor portion that drives the fan portion and a bearing portion associated with the fan portion and the motor portion. The motor portion has a motor coolant inlet coupled with the outlet of the first reactant blower to receive some of the first reactant for cooling the motor portion.

  4. Fuel assemblies

    International Nuclear Information System (INIS)

    Mukai, Hideyuki

    1987-01-01

    Purpose: To prevent bending of fuel rods caused by the difference of irradiation growth between coupling fuel rods and standards fuel rods thereby maintain the fuel rod integrity. Constitution: The f value for a fuel can (the ratio of pole of zirconium crystals in the entire crystals along the axial direction of the fuel can) of a coupling fuel rod secured by upper and lower tie plates is made smaller than the f value for the fuel can of a standard fuel rod not secured by the upper and the lower tie plates. This can make the irradiation growth of the fuel can of the coupling fuel rod greater than the irradiation growth of the fuel can of the standard fuel rod and, accordingly, since the elongation of the standard fuel rod can always by made greater, bending of the standard fuel rod can be prevented. (Yoshihara, M.)

  5. Final Rule for Control of Air Pollution From New Motor Vehicles and New Motor Vehicle Engines: Evaporative and Refueling Emission Regulations for Gasolineand Methanol-Fueled Light-Duty Vehicles and Light-Duty Trucks and Heavy-Duty Vehicles; Technical Amen

    Science.gov (United States)

    On March 24, 1993 EPA finalized a new test procedure to measure evaporative emissions from motor vehicles. The amendments modify several of the test procedure’s tolerances, equipment specifications, and procedural steps.

  6. 40 CFR 80.603 - What are the pre-compliance reporting requirements for NRLM diesel fuel?

    Science.gov (United States)

    2010-07-01

    ... requirements for NRLM diesel fuel? 80.603 Section 80.603 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Motor Vehicle Diesel Fuel; Nonroad, Locomotive, and Marine Diesel Fuel; and ECA Marine Fuel Recordkeeping and Reporting...

  7. A multi-scale, multi-disciplinary approach for assessing the technological, economic and environmental performance of bio-based chemicals.

    Science.gov (United States)

    Herrgård, Markus; Sukumara, Sumesh; Campodonico, Miguel; Zhuang, Kai

    2015-12-01

    In recent years, bio-based chemicals have gained interest as a renewable alternative to petrochemicals. However, there is a significant need to assess the technological, biological, economic and environmental feasibility of bio-based chemicals, particularly during the early research phase. Recently, the Multi-scale framework for Sustainable Industrial Chemicals (MuSIC) was introduced to address this issue by integrating modelling approaches at different scales ranging from cellular to ecological scales. This framework can be further extended by incorporating modelling of the petrochemical value chain and the de novo prediction of metabolic pathways connecting existing host metabolism to desirable chemical products. This multi-scale, multi-disciplinary framework for quantitative assessment of bio-based chemicals will play a vital role in supporting engineering, strategy and policy decisions as we progress towards a sustainable chemical industry. © 2015 Authors; published by Portland Press Limited.

  8. 77 FR 14482 - Petroleum Reduction and Alternative Fuel Consumption Requirements for Federal Fleets

    Science.gov (United States)

    2012-03-12

    ...-road or non-road vehicle. \\2\\ The definition of the term ``low-speed electric vehicle,'' as used... alternative fuel used in Federal fleet motor vehicles. This report also would include the alternative fuel...-- (1) a motor vehicle that operates solely on alternative fuel; or (2) a low-speed electric vehicle. (g...

  9. Desempenho de misturas pré-aquecidas de óleo de soja cru e diesel como combustível para motores agrícolas Performance of preheated crude soybean oil-diesel blends as fuel in agricultural engines

    Directory of Open Access Journals (Sweden)

    José Fernando Schlosser

    2007-10-01

    Full Text Available O óleo de soja é um dos óleos vegetais que têm potencial de uso como combustível para motores diesel, pois é renovável, seguro e de fácil utilização. Em temperatura ambiente, o óleo cru apresenta uma viscosidade cerca de dez vezes maior que a do óleo diesel. Para reduzir a viscosidade do óleo de soja a níveis aceitáveis, é necessária uma temperatura de aquecimento em torno de aproximadamente 60°C ou misturá-lo com óleo diesel. O objetivo deste estudo foi avaliar o desempenho do óleo de soja cru e suas misturas com óleo diesel, pré-aquecidas antes da bomba injetora entre 57°C e 68°C, como combustível para motores diesel. O desempenho das misturas combustíveis foi avaliado num motor monocilíndrico de injeção indireta e comparado com o obtido pelo óleo diesel. Os ensaios de curta duração foram conduzidos entre 1.800 e 2.800rpm, sob condição de plena carga em dinamômetro hidráulico. Ensaios realizados a 68°C apresentaram sempre os melhores valores para torque, potência e consumo específico de combustível do que a 57°C. Uma mistura composta por 70% de óleo de soja e 30% de óleo diesel, aquecida a 68°C, apresentou os melhores resultados.Crude soybean oil is one of the vegetable oils that have potential for use as fuel for diesel engines. Soybean oil is renewable, and is safe and easy to handle. At room temperature crude oil has a viscosity about ten times higher than that of diesel oil. To lower soybean oil's viscosity to the acceptable levels a heating temperature at least 60°C is needed or blending with diesel fuel. The objective of this study was evaluating the soybean oil and blends performance as a fuel for diesel engines. On both crude soybean oil and soybean oil blends were used pre-heating temperature levels on the range between 57°C and 68°C, before fuel pump. The performance of the fuel blends were evaluated in a single cylinder indirect injection diesel engine and compared with the performance

  10. Social Life Cycle Approach as a Tool for Promoting the Market Uptake of Bio-Based Products from a Consumer Perspective

    Directory of Open Access Journals (Sweden)

    Pasquale Marcello Falcone

    2018-03-01

    Full Text Available The sustainability of bio-based products, especially when compared with fossil based products, must be assured. The life cycle approach has proven to be a promising way to analyze the social, economic and environmental impacts of bio-based products along the whole value chain. Until now, however, the social aspects have been under-investigated in comparison to environmental and economic aspects. In this context, the present paper aims to identify the main social impact categories and indicators that should be included in a social sustainability assessment of bio-based products, with a focus on the consumers’ category. To identify which social categories and indicators are most relevant, we carry out a literature review on existing social life cycle studies; this is followed by a focus group with industrial experts and academics. Afterwards, we conduct semi-structured interviews with some consumer representatives to understand which social indicators pertaining to consumers are perceived as relevant. Our findings highlight the necessity for the development and dissemination of improved frameworks capable of exploiting the consumers’ role in the ongoing process of market uptake of bio-based products. More specifically, this need regards the effective inclusion of some social indicators (i.e., end users’ health and safety, feedback mechanisms, transparency, and end-of-life responsibility in the social life cycle assessment scheme for bio-based products. This would allow consumers, where properly communicated, to make more informed and aware purchasing choices, therefore having a flywheel effect on the market diffusion of a bio-based product.

  11. 40 CFR 600.114-08 - Vehicle-specific 5-cycle fuel economy calculations.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 29 2010-07-01 2010-07-01 false Vehicle-specific 5-cycle fuel economy... (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy... fuel economy calculations. This section applies to data used for fuel economy labeling under Subpart D...

  12. Electric motor handbook

    CERN Document Server

    Chalmers, B J

    2013-01-01

    Electric Motor Handbook aims to give practical knowledge in a wide range of capacities such as plant design, equipment specification, commissioning, operation and maintenance. The book covers topics such as the modeling of steady-state motor performance; polyphase induction, synchronous, and a.c. commutator motors; ambient conditions, enclosures, cooling and loss dissipation; and electrical supply systems and motor drives. Also covered are topics such as variable-speed drives and motor control; materials and motor components; insulation types, systems, and techniques; and the installation, sit

  13. System dynamics modelling of the European demand for bio-based plastics: An analysis of scaling and learning effects and framework conditions on price competitiveness and market growth

    OpenAIRE

    Horvat, Djerdj; Wydra, Sven

    2017-01-01

    Bio-based plastics are used as raw materials in a wide range of applications and provide potential for mitigating climate change by lowering CO2 emissions. However, because of the high production costs compared to fossil-based alternative products, they are currently not cost competitive on the market. Moreover, the decrease of oil price as main antecedent of fossil-based plastics has even been diminishing their competiveness. Thus, the future of bio-based plastics on the market depends on th...

  14. Mechanical design of translocating motor proteins.

    Science.gov (United States)

    Hwang, Wonmuk; Lang, Matthew J

    2009-01-01

    Translocating motors generate force and move along a biofilament track to achieve diverse functions including gene transcription, translation, intracellular cargo transport, protein degradation, and muscle contraction. Advances in single molecule manipulation experiments, structural biology, and computational analysis are making it possible to consider common mechanical design principles of these diverse families of motors. Here, we propose a mechanical parts list that include track, energy conversion machinery, and moving parts. Energy is supplied not just by burning of a fuel molecule, but there are other sources or sinks of free energy, by binding and release of a fuel or products, or similarly between the motor and the track. Dynamic conformational changes of the motor domain can be regarded as controlling the flow of free energy to and from the surrounding heat reservoir. Multiple motor domains are organized in distinct ways to achieve motility under imposed physical constraints. Transcending amino acid sequence and structure, physically and functionally similar mechanical parts may have evolved as nature's design strategy for these molecular engines.

  15. Modified Chitosan Nanoparticle by Radiation Synthesis: An Approach to Drug Delivery and Bio-Based Additive for Biomedical Applications

    International Nuclear Information System (INIS)

    Pasanphan, W.; Rimdusit, P.; Rattanawongwiboon, T.; Choofong, S.

    2010-01-01

    Self-assembly chitosan nanoparticle (CsNP) has been synthesized via radiolytic methodology using gamma irradiation. The systematic condition in preparation was studied. Chitosan nanoparticle was modified using hydrophobic core of deoxycholic acid (DC) and stearyl methacrylate (SMA) and the hydrophilic shell of polyethylene glycol monomethacrylate (PEG). The hydrophobic/hydrophilic CsNP was prepared for drug carrier molecule. The SMA-CsNP was also conjugated with pyperidine, hindered amine light stabilizer function, to achieve a bio-based additive for biomedical plastic. (author)

  16. Modified Chitosan Nanoparticle by Radiation Synthesis: An Approach to Drug Delivery and Bio-Based Additive for Biomedical Applications

    Energy Technology Data Exchange (ETDEWEB)

    Pasanphan, W.; Rimdusit, P.; Rattanawongwiboon, T.; Choofong, S., E-mail: sciwvm@ku.ac.th, E-mail: pwanvimol@yahoo.com [Kasetsart University, Faculty of Science, Department of Applied Radiation and Isotopes, 50 Phahonyothin Road, Chatuchak, Bangkok 1090 (Thailand)

    2010-07-01

    Self-assembly chitosan nanoparticle (CsNP) has been synthesized via radiolytic methodology using gamma irradiation. The systematic condition in preparation was studied. Chitosan nanoparticle was modified using hydrophobic core of deoxycholic acid (DC) and stearyl methacrylate (SMA) and the hydrophilic shell of polyethylene glycol monomethacrylate (PEG). The hydrophobic/hydrophilic CsNP was prepared for drug carrier molecule. The SMA-CsNP was also conjugated with pyperidine, hindered amine light stabilizer function, to achieve a bio-based additive for biomedical plastic. (author)

  17. Modelling continuous pharmaceutical and bio-based processes at plant-wide level: A roadmap towards efficient decision-making

    DEFF Research Database (Denmark)

    Ramin, Pedram; Mansouri, Seyed Soheil; Udugama, Isuru A.

    2018-01-01

    The importance of developing simulation models for decision making in pharmaceutical and bio-based production processes is elaborated in this article. The advantages of modelling continuous processes are outlined and certain barriers in this regard are identified. Although there have been some...... advancements in the field, there needs to be a larger international collaboration in this regard for providing reliable data for model validation, for development of generic modelbased frameworks and implementing them in computer-aided platforms in the form of software tools....

  18. Information processing through a bio-based redox capacitor: signatures for redox-cycling.

    Science.gov (United States)

    Liu, Yi; Kim, Eunkyoung; White, Ian M; Bentley, William E; Payne, Gregory F

    2014-08-01

    Redox-cycling compounds can significantly impact biological systems and can be responsible for activities that range from pathogen virulence and contaminant toxicities, to therapeutic drug mechanisms. Current methods to identify redox-cycling activities rely on the generation of reactive oxygen species (ROS), and employ enzymatic or chemical methods to detect ROS. Here, we couple the speed and sensitivity of electrochemistry with the molecular-electronic properties of a bio-based redox-capacitor to generate signatures of redox-cycling. The redox capacitor film is electrochemically-fabricated at the electrode surface and is composed of a polysaccharide hydrogel with grafted catechol moieties. This capacitor film is redox-active but non-conducting and can engage diffusible compounds in either oxidative or reductive redox-cycling. Using standard electrochemical mediators ferrocene dimethanol (Fc) and Ru(NH3)6Cl3 (Ru(3+)) as model redox-cyclers, we observed signal amplifications and rectifications that serve as signatures of redox-cycling. Three bio-relevant compounds were then probed for these signatures: (i) ascorbate, a redox-active compound that does not redox-cycle; (ii) pyocyanin, a virulence factor well-known for its reductive redox-cycling; and (iii) acetaminophen, an analgesic that oxidatively redox-cycles but also undergoes conjugation reactions. These studies demonstrate that the redox-capacitor can enlist the capabilities of electrochemistry to generate rapid and sensitive signatures of biologically-relevant chemical activities (i.e., redox-cycling). Published by Elsevier B.V.

  19. Bio-based biodegradable film to replace the standard polyethylene cover for silage conservation.

    Science.gov (United States)

    Borreani, Giorgio; Tabacco, Ernesto

    2015-01-01

    The research was aimed at studying whether the polyethylene (PE) film currently used to cover maize silage could be replaced with bio-based biodegradable films, and at determining the effects on the fermentative and microbiological quality of the resulting silages in laboratory silo conditions. Biodegradable plastic film made in 2 different formulations, MB1 and MB2, was compared with a conventional 120-μm-thick PE film. A whole maize crop was chopped; ensiled in MB1, MB2, and PE plastic bags, 12.5kg of fresh weight per bag; and opened after 170d of conservation. At silo opening, the microbial and fermentative quality of the silage was analyzed in the uppermost layer (0 to 50mm from the surface) and in the whole mass of the silo. All the silages were well fermented with little differences in fermentative quality between the treatments, although differences in the mold count and aerobic stability were observed in trial 1 for the MB1 silage. These results have shown the possibility of successfully developing a biodegradable cover for silage for up to 6mo after ensiling. The MB2 film allowed a good silage quality to be obtained even in the uppermost part of the silage close to the plastic film up to 170d of conservation, with similar results to those obtained with the PE film. The promising results of this experiment indicate that the development of new degradable materials to cover silage till 6mo after ensiling could be possible. Copyright © 2015 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

  20. Systems-wide metabolic pathway engineering in Corynebacterium glutamicum for bio-based production of diaminopentane.

    Science.gov (United States)

    Kind, Stefanie; Jeong, Weol Kyu; Schröder, Hartwig; Wittmann, Christoph

    2010-07-01

    In the present work the Gram-positive bacterium Corynebacterium glutamicum was engineered into an efficient, tailor-made production strain for diaminopentane (cadaverine), a highly attractive building block for bio-based polyamides. The engineering comprised expression of lysine decarboxylase (ldcC) from Escherichia coli, catalyzing the conversion of lysine into diaminopentane, and systems-wide metabolic engineering of central supporting pathways. Substantially re-designing the metabolism yielded superior strains with desirable properties such as (i) the release from unwanted feedback regulation at the level of aspartokinase and pyruvate carboxylase by introducing the point mutations lysC311 and pycA458, (ii) an optimized supply of the key precursor oxaloacetate by amplifying the anaplerotic enzyme, pyruvate carboxylase, and deleting phosphoenolpyruvate carboxykinase which otherwise removes oxaloacetate, (iii) enhanced biosynthetic flux via combined amplification of aspartokinase, dihydrodipicolinate reductase, diaminopimelate dehydrogenase and diaminopimelate decarboxylase, and (iv) attenuated flux into the threonine pathway competing with production by the leaky mutation hom59 in the homoserine dehydrogenase gene. Lysine decarboxylase proved to be a bottleneck for efficient production, since its in vitro activity and in vivo flux were closely correlated. To achieve an optimal strain having only stable genomic modifications, the combination of the strong constitutive C. glutamicum tuf promoter and optimized codon usage allowed efficient genome-based ldcC expression and resulted in a high diaminopentane yield of 200 mmol mol(-1). By supplementing the medium with 1 mgL(-1) pyridoxal, the cofactor of lysine decarboxylase, the yield was increased to 300 mmol mol(-1). In the production strain obtained, lysine secretion was almost completely abolished. Metabolic analysis, however, revealed substantial formation of an as yet unknown by-product. It was identified as an