WorldWideScience

Sample records for bio-chemical mass-balance model

  1. Modeling and Understanding the Mass Balance of Himalayan Glaciers

    Science.gov (United States)

    Rengaraju, S.; Achutarao, K. M.

    2017-12-01

    Changes in glaciers are among the most visible manifestations of a changing climate. Retreating glaciers have significant impacts on global sea-level rise and stream flow of rivers. Modeling the response of glaciers to climate change is important for many reasons including predicting changes in global sea level and water resources. The mass balance of a glacier provides a robust way of ascertaining whether there has been a net loss or gain of ice from the glacier. The mass balance reflects all of the meteorological forcing of the glacier - from the accumulation of snow and the combined losses from ablation and sublimation. The glaciers in the Himalayan region are considered sensitive to climate change and their fate under climate change is critical to the billions of humans that rely on rivers originating from these glaciers. Owing to complex terrain and harsh climate, Himalayan glaciers have historically been poorly monitored and this makes it harder to understand and predict their fate.In this study we model the observed mass balance of Himalayan glaciers using the methods of Radic and Hock (2011) and analyze the response to future changes in climate based on the model projections from the Coupled Model Intercomparison Project Phase-5 (CMIP5; Taylor et al., 2012). We make use of available observations of mass balance from various sources for 14 glaciers across the Himalayas. These glaciers are located across distinct climatic conditions - from the Karakoram and Hindu Kush in the West that are fed by winter precipitation caused by westerly disturbances to the Eastern Himalayas where the summer monsoon provides the bulk of the precipitation. For the historical observed period, we use the ECMWF Re-Analysis (ERA-40) for temperature and VASClimO (GPCC) data at 2.5°x2.5° resolution to calibrate the mass balance model. We evaluate the CMIP5 model simulations for their fidelity in capturing the distinct climatic conditions across the Himalayas in order to select

  2. Satellite-retrieval and modeling of glacier mass balance

    Science.gov (United States)

    de Ruyter Wildt, Martijn Sybren

    2002-07-01

    In this research project we use satellite measurements to infer the mean specific mass balance (Bm) of glaciers. Vatnajökull, the largest ice cap in Europe, is being used as a test-case because this ice cap has often been studied. Only one aspect of Vatnajökull has not been investigated so far, and that is the relation between its mass balance and climatological conditions. We therefore also construct a mass balance model, the results of which can be compared to the satellite images. On Vatnajökull an extensive meteorological experiment took place in the summer of 1996, and the dataset collected during this experiment can be used for validation of the model. The mass balance model is calibrated with in situ measurements. We find that the incoming longwave radiation is best modeled as a function of meteorological variables in the free atmosphere just above the relatively thin katabatic layer. Also, the ratio of changes in the 2 m temperature to changes in the free atmospheric temperature (the climate sensitivity) is smaller than 1. Horizontal precipitation gradients over Vatnajökull are large, which results in a strongly varying sensitivity to external temperature changes over the ice cap. Local climatic conditions thus highly determine the mass balance and its sensitivity. From the mass balance model we construct a Seasonal Sensitivity Characteristic (SSC) of Vatnajökull, which consists of the sensitivity of Bm to monthly perturbations in temperature and precipitation. Temperature sensitivities are high in summer and nearly zero in winter, while precipitation sensitivities are high in winter and low in summer. With the SSC we reconstruct the mass balance of Vatnajökull since 1825. The results for two Icelandic glaciers correlate very well with mass balance records that are extracted from length records with a linear inverse model. For the south of Vatnajökull we find that after 1900, the length record is well explained by temperature variations alone, while

  3. Modelled climate sensitivity of the mass balance of Morteratschgletscher and its dependence on albedo parameterization

    NARCIS (Netherlands)

    Klok, E.J.; Oerlemans, J.

    2004-01-01

    This paper presents a study of the climate sensitivity of the mass balance of Morteratschgletscher in Switzerland, estimated from a two-dimensional mass balance model. Since the albedo scheme chosen is often the largest error source in mass balance models, we investigated the impact of using

  4. Mass balance model parameter transferability on a tropical glacier

    Science.gov (United States)

    Gurgiser, Wolfgang; Mölg, Thomas; Nicholson, Lindsey; Kaser, Georg

    2013-04-01

    The mass balance and melt water production of glaciers is of particular interest in the Peruvian Andes where glacier melt water has markedly increased water supply during the pronounced dry seasons in recent decades. However, the melt water contribution from glaciers is projected to decrease with appreciable negative impacts on the local society within the coming decades. Understanding mass balance processes on tropical glaciers is a prerequisite for modeling present and future glacier runoff. As a first step towards this aim we applied a process-based surface mass balance model in order to calculate observed ablation at two stakes in the ablation zone of Shallap Glacier (4800 m a.s.l., 9°S) in the Cordillera Blanca, Peru. Under the tropical climate, the snow line migrates very frequently across most of the ablation zone all year round causing large temporal and spatial variations of glacier surface conditions and related ablation. Consequently, pronounced differences between the two chosen stakes and the two years were observed. Hourly records of temperature, humidity, wind speed, short wave incoming radiation, and precipitation are available from an automatic weather station (AWS) on the moraine near the glacier for the hydrological years 2006/07 and 2007/08 while stake readings are available at intervals of between 14 to 64 days. To optimize model parameters, we used 1000 model simulations in which the most sensitive model parameters were varied randomly within their physically meaningful ranges. The modeled surface height change was evaluated against the two stake locations in the lower ablation zone (SH11, 4760m) and in the upper ablation zone (SH22, 4816m), respectively. The optimal parameter set for each point achieved good model skill but if we transfer the best parameter combination from one stake site to the other stake site model errors increases significantly. The same happens if we optimize the model parameters for each year individually and transfer

  5. Mass-balance model for predicting nitrate in ground water

    Science.gov (United States)

    Frimpter, Michael H.; Donohue, John J.; Rapacz, Michael V.

    1990-01-01

    A mass-balance accounting model can be used to guide the management of septic systems and fertilizers to control the degradation of ground-water quality in zones of an aquifer that contribute water to public-supply wells. The nitrate concentration of the mixture in the well can be predicted for steady-state conditions by calculating the concentration that results from the total weight of nitrogen and total volume of water entering the zone of contribution to the well. These calculations will allow water-quality managers to predict the nitrate concentrations that would be produced by different types and levels of development, and to plan development accordingly. Computations for different development schemes provide a technical basis for planners and managers to compare water-quality effects and to select alternatives that limit nitrate concentration in wells.

  6. Gray box modeling of MSW degradation : Revealing its dominant (bio)chemical mechanism

    NARCIS (Netherlands)

    Van Turnhout, A.G.; Heimovaara, T.J.; Kleerebezem, R.

    2013-01-01

    In this paper we present an approach to describe organic degradation within immobile water regions of Municipal Solid Waste (MSW) landfills which is best described by the term “gray box” model. We use a simplified set of dominant (bio)chemical and physical reactions and realistic environmental

  7. Modelled and observed mass balance of Rikha Samba Glacier, Nepal, Central Himalaya

    Science.gov (United States)

    Gurung, T. R.; Kayastha, R. B.; Fujita, K.; Sinisalo, A. K.; Stumm, D.; Joshi, S.; Litt, M.

    2016-12-01

    Glacier mass balance variability has an implication for the regional water resources and it helps to understand the response of glacier to climate change in the Himalayan region. Several mass balance studies have been started in the Himalayan region since 1970s, but they are characterized by frequent temporal gaps and a poor spatial representatively. This study aims at bridging the temporal gaps in a long term mass balance series of the Rikha Samba glacier (5383 - 6475 m a.s.l.), a benchmark glacier located in the Hidden Valley, Mustang, Nepal. The ERA Interim reanalysis data for the period 2011-2015 is calibrated with the observed meteorological variables from an AWS installed near the glacier terminus. We apply an energy mass balance model, validated with the available in-situ measurements for the years 1998 and 2011-2015. The results show that the glacier is shrinking at a moderate negative mass balance rate for the period 1995 to 2015 and the high altitude location of Rikha Samba also prevents a bigger mass loss compared to other small Himalayan glaciers. Precipitation from July to January and the mean air temperature from June to October are the most influential climatic parameters of the annual mass balance variability of Rikha Samba glacier.

  8. Applying an orographic precipitation model to improve mass balance modeling of the Juneau Icefield, AK

    Science.gov (United States)

    Roth, A. C.; Hock, R.; Schuler, T.; Bieniek, P.; Aschwanden, A.

    2017-12-01

    Mass loss from glaciers in Southeast Alaska is expected to alter downstream ecological systems as runoff patterns change. To investigate these potential changes under future climate scenarios, distributed glacier mass balance modeling is required. However, the spatial resolution gap between global or regional climate models and the requirements for glacier mass balance modeling studies must be addressed first. We have used a linear theory of orographic precipitation model to downscale precipitation from both the Weather Research and Forecasting (WRF) model and ERA-Interim to the Juneau Icefield region over the period 1979-2013. This implementation of the LT model is a unique parameterization that relies on the specification of snow fall speed and rain fall speed as tuning parameters to calculate the cloud time delay, τ. We assessed the LT model results by considering winter precipitation so the effect of melt was minimized. The downscaled precipitation pattern produced by the LT model captures the orographic precipitation pattern absent from the coarse resolution WRF and ERA-Interim precipitation fields. Observational data constraints limited our ability to determine a unique parameter combination and calibrate the LT model to glaciological observations. We established a reference run of parameter values based on literature and performed a sensitivity analysis of the LT model parameters, horizontal resolution, and climate input data on the average winter precipitation. The results of the reference run showed reasonable agreement with the available glaciological measurements. The precipitation pattern produced by the LT model was consistent regardless of parameter combination, horizontal resolution, and climate input data, but the precipitation amount varied strongly with these factors. Due to the consistency of the winter precipitation pattern and the uncertainty in precipitation amount, we suggest a precipitation index map approach to be used in combination with

  9. SEMIC: an efficient surface energy and mass balance model applied to the Greenland ice sheet

    Directory of Open Access Journals (Sweden)

    M. Krapp

    2017-07-01

    Full Text Available We present SEMIC, a Surface Energy and Mass balance model of Intermediate Complexity for snow- and ice-covered surfaces such as the Greenland ice sheet. SEMIC is fast enough for glacial cycle applications, making it a suitable replacement for simpler methods such as the positive degree day (PDD method often used in ice sheet modelling. Our model explicitly calculates the main processes involved in the surface energy and mass balance, while maintaining a simple interface and requiring minimal data input to drive it. In this novel approach, we parameterise diurnal temperature variations in order to more realistically capture the daily thaw–freeze cycles that characterise the ice sheet mass balance. We show how to derive optimal model parameters for SEMIC specifically to reproduce surface characteristics and day-to-day variations similar to the regional climate model MAR (Modèle Atmosphérique Régional, version 2 and its incorporated multilayer snowpack model SISVAT (Soil Ice Snow Vegetation Atmosphere Transfer. A validation test shows that SEMIC simulates future changes in surface temperature and surface mass balance in good agreement with the more sophisticated multilayer snowpack model SISVAT included in MAR. With this paper, we present a physically based surface model to the ice sheet modelling community that is general enough to be used with in situ observations, climate model, or reanalysis data, and that is at the same time computationally fast enough for long-term integrations, such as glacial cycles or future climate change scenarios.

  10. Mass balances for a biological life support system simulation model

    Science.gov (United States)

    Volk, Tyler; Rummel, John D.

    1987-01-01

    Design decisions to aid the development of future space based biological life support systems (BLSS) can be made with simulation models. The biochemistry stoichiometry was developed for: (1) protein, carbohydrate, fat, fiber, and lignin production in the edible and inedible parts of plants; (2) food consumption and production of organic solids in urine, feces, and wash water by the humans; and (3) operation of the waste processor. Flux values for all components are derived for a steady state system with wheat as the sole food source. The large scale dynamics of a materially closed (BLSS) computer model is described in a companion paper. An extension of this methodology can explore multifood systems and more complex biochemical dynamics while maintaining whole system closure as a focus.

  11. The influence of changes in glacier extent and surface elevation on modeled mass balance

    Directory of Open Access Journals (Sweden)

    F. Paul

    2010-12-01

    Full Text Available Glaciers are widely recognized as unique demonstration objects for climate change impacts, mostly due to the strong change of glacier length in response to small climatic changes. However, glacier mass balance as the direct response to the annual atmospheric conditions can be better interpreted in meteorological terms. When the climatic signal is deduced from long-term mass balance data, changes in glacier geometry (i.e. surface extent and elevation must be considered as such adjustments form an essential part of the glacier reaction to new climatic conditions. In this study, a set of modelling experiments is performed to assess the influence of changes in glacier geometry on mass balance for constant climatic conditions. The calculations are based on a simplified distributed energy/mass balance model in combination with information on glacier extent and surface elevation for the years 1850 and 1973/1985 for about 60 glaciers in the Swiss Alps. The results reveal that over this period about 50–70% of the glacier reaction to climate change (here a one degree increase in temperature is "hidden" in the geometric adjustment, while only 30–50% can be measured as the long-term mean mass balance. For larger glaciers, the effect of the areal change is partly reduced by a lowered surface elevation, which results in a slightly more negative balance despite a potential increase of topographic shading. In view of several additional reinforcement feedbacks that are observed in periods of strong glacier decline, it seems that the climatic interpretation of long-term mass balance data is rather complex.

  12. Mass Balance Model, A study of contamination effects in AMS 14C sample analysis

    NARCIS (Netherlands)

    Prokopiou, Markella

    2010-01-01

    In this training thesis a background correction analysis, also known as mass balance model, was implemented to study the contamination effects in AMS 14C sample processing. A variety of backgrounds and standards with sizes ranging from 50 μg C to 1500 μg

  13. Higher surface mass balance of the Greenland ice sheet revealed by high-resolution climate modeling

    NARCIS (Netherlands)

    Ettema, J.|info:eu-repo/dai/nl/304831913; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; Bamber, Jonathan L.; Box, J.E.; Bales, R.C.

    2009-01-01

    High-resolution (∼11 km) regional climate modeling shows total annual precipitation on the Greenland ice sheet for 1958–2007 to be up to 24% and surface mass balance up to 63% higher than previously thought. The largest differences occur in coastal southeast Greenland, where the much higher

  14. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    NARCIS (Netherlands)

    Rae, J.G.L.; Aðalgeirsdóttir, G.; Edwards, T.L.; Fettweis, X.; Gregory, J.M.; Hewitt, H.T.; Lowe, J.A.; Lucas-Picher, P.; Mottram, R.H.; Payne, A.J.; Ridley, J.K.; Shannon, S.R.; van de Berg, W.J.|info:eu-repo/dai/nl/304831611; van de Wal, R.S.W.|info:eu-repo/dai/nl/101899556; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643

    2012-01-01

    Four high-resolution regional climate models (RCMs) have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB), and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution

  15. Steady state phosphorus mass balance model during hemodialysis based on a pseudo one-compartment kinetic model.

    Science.gov (United States)

    Leypoldt, John K; Agar, Baris U; Akonur, Alp; Gellens, Mary E; Culleton, Bruce F

    2012-11-01

    Mathematical models of phosphorus kinetics and mass balance during hemodialysis are in early development. We describe a theoretical phosphorus steady state mass balance model during hemodialysis based on a novel pseudo one-compartment kinetic model. The steady state mass balance model accounted for net intestinal absorption of phosphorus and phosphorus removal by both dialysis and residual kidney function. Analytical mathematical solutions were derived to describe time-dependent intradialytic and interdialytic serum phosphorus concentrations assuming hemodialysis treatments were performed symmetrically throughout a week. Results from the steady state phosphorus mass balance model are described for thrice weekly hemodialysis treatment prescriptions only. The analysis predicts 1) a minimal impact of dialyzer phosphorus clearance on predialysis serum phosphorus concentration using modern, conventional hemodialysis technology, 2) variability in the postdialysis-to-predialysis phosphorus concentration ratio due to differences in patient-specific phosphorus mobilization, and 3) the importance of treatment time in determining the predialysis serum phosphorus concentration. We conclude that a steady state phosphorus mass balance model can be developed based on a pseudo one-compartment kinetic model and that predictions from this model are consistent with previous clinical observations. The predictions from this mass balance model are theoretical and hypothesis-generating only; additional prospective clinical studies will be required for model confirmation.

  16. Aquatic Exposure Predictions of Insecticide Field Concentrations Using a Multimedia Mass-Balance Model.

    Science.gov (United States)

    Knäbel, Anja; Scheringer, Martin; Stehle, Sebastian; Schulz, Ralf

    2016-04-05

    Highly complex process-driven mechanistic fate and transport models and multimedia mass balance models can be used for the exposure prediction of pesticides in different environmental compartments. Generally, both types of models differ in spatial and temporal resolution. Process-driven mechanistic fate models are very complex, and calculations are time-intensive. This type of model is currently used within the European regulatory pesticide registration (FOCUS). Multimedia mass-balance models require fewer input parameters to calculate concentration ranges and the partitioning between different environmental media. In this study, we used the fugacity-based small-region model (SRM) to calculate predicted environmental concentrations (PEC) for 466 cases of insecticide field concentrations measured in European surface waters. We were able to show that the PECs of the multimedia model are more protective in comparison to FOCUS. In addition, our results show that the multimedia model results have a higher predictive power to simulate varying field concentrations at a higher level of field relevance. The adaptation of the model scenario to actual field conditions suggests that the performance of the SRM increases when worst-case conditions are replaced by real field data. Therefore, this study shows that a less complex modeling approach than that used in the regulatory risk assessment exhibits a higher level of protectiveness and predictiveness and that there is a need to develop and evaluate new ecologically relevant scenarios in the context of pesticide exposure modeling.

  17. Mathematical modeling of water mass balance for proton exchange membrane fuel cell

    International Nuclear Information System (INIS)

    Wan Ramli Wan Daud; Kamaruzzaman Sopian; Jaafar Sahari; Nik Suhaimi Mat Hassan

    2006-01-01

    Gas and water management are key to achieving good performance from a proton exchange membrane fuel cell (PEMFC) stack. Water plays a critical role in PEMFC. The proton conductivity is increase with the water content. In order to achieve enough hydration, water is normally introduced into the cell externally by a variety of methods such as liquid injection, steam introduction, and humidification of reactants by passing them through humidifiers before entering the cell. In this paper, mathematical modeling of water mass balance for PEMFC at anode and cathode side are proposed by using external humidification and assume that steady state, constant pressure, constant temperature and gases distribution are uniform

  18. Quantification of Submarine Groundwater Discharge Using a Radon (222-Rn) Mass Balance and Hydrogeological Modelling

    Science.gov (United States)

    Petermann, Eric; Stollberg, Reiner; Scholten, Jan; Knöller, Kay; Schubert, Michael

    2016-04-01

    Apart from river and surface water runoff subsurface discharge of groundwater plays a key role in coastal water and matter budgets. Two major forms of submarine groundwater discharge (SGD) can be distinguished: (i) pure freshwater discharge from continental aquifers that are connected to the coastal sea driven by a positive hydraulic gradient (fresh SGD) and (ii) re-circulation of seawater that has penetrated permeable coastal sediments (re-circulated SGD), e.g. driven by tidal pumping. The localization of SGD zones and the quantification of SGD fluxes is of high interest for coastal water management due to potential threats related to SGD, namely (i) the detrimental impact of discharging nutrient- or contaminant-laden groundwater on coastal seawater quality, an aspect that is of relevance along coastlines which are impacted by agriculture, industry or intense urbanization, and (ii) the loss of freshwater to the ocean, an issue that is of major relevance in all coastal areas with (seasonally) limited freshwater availability. In this work, we discuss estimates for the total (fresh + re-circulated) SGD fluxes derived from a mass balance of the radioactive noble gas radon (222-Rn) with estimates of fresh SGD fluxes derived by hydrogeological modelling. The precision of the mass balance results depends on the adequate determination of the mass balance source and sink terms. These terms are calculated based on field observations of environmental tracers (salinity, δ18O, 222-Rn, 223-Ra, 224-Ra, 226-Ra) in seawater and porewater, as well as on meteorological data. The numerical hydrogeological model estimates groundwater flow based on groundwater monitoring data, river flow data, groundwater recharge estimates, tidal dynamics, and density effects along the freshwater/seawater interface. We compare these two independent methodological approaches of SGD flux estimation, discuss results regarding their relevance for the regional water balance and reason the implications of

  19. The potential role of mass balance models for the management of upwelling ecosystems

    DEFF Research Database (Denmark)

    Jarre, Astrid

    1998-01-01

    Upwelling ecosystems are productive fishing grounds, contributing >30% to the world's catch of marine fish. A set of seven trophic mass balance models of productive subsystems of the four largest upwelling areas is used to demonstrate key features of the modeling process and the analysis of the m......Upwelling ecosystems are productive fishing grounds, contributing >30% to the world's catch of marine fish. A set of seven trophic mass balance models of productive subsystems of the four largest upwelling areas is used to demonstrate key features of the modeling process and the analysis...... N), focusing on different biological regimes in the 1970s and 1980s. The straightforwardness of the method is emphasized as a coherent basis for more sophisticated modeling approaches. One major advantage over more traditional assessment methods is that the fishery is explicitly tied into the full...... set of species interactions, and its impact can thus be readily compared to that of other piscivores in the ecosystem. This approach consequently allows us to assess the ecological sustainability of a fishery. It therefore addresses the Code of Conduct for Responsible Fisheries recently published...

  20. Regional Modeling of Dust Mass Balance and Radiative Forcing over East Asia using WRF-Chem

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Siyu; Zhao, Chun; Qian, Yun; Leung, Lai-Yung R.; Huang, J.; Huang, Zhongwei; Bi, Jianrong; Zhang, Wu; Shi, Jinsen; Yang, Lei; Li, Deshuai; Li, Jinxin

    2014-12-01

    The Weather Research and Forecasting model with Chemistry (WRF-Chem) is used to investigate the seasonal and annual variations of mineral dust over East Asia during 2007-2011, with a focus on the dust mass balance and radiative forcing. A variety of measurements from in-stu and satellite observations have been used to evaluate simulation results. Generally, WRF-Chem reproduces not only the column variability but also the vertical profile and size distribution of mineral dust over and near the dust source regions of East Asia. We investigate the dust lifecycle and the factors that control the seasonal and spatial variations of dust mass balance and radiative forcing over the seven sub-regions of East Asia, i.e. source regions, the Tibetan Plateau, Northern China, Southern China, the ocean outflow region, and Korea-Japan regions. Results show that, over the source regions, transport and dry deposition are the two dominant sinks. Transport contributes to ~30% of the dust sink over the source regions. Dust results in a surface cooling of up to -14 and -10 W m-2, atmospheric warming of up to 20 and 15 W m-2, and TOA cooling of -5 and -8 W m-2 over the two major dust source regions of East Asia, respectively. Over the Tibetan Plateau, transport is the dominant source with a peak in summer. Over identified outflow regions, maximum dust mass loading in spring is contributed by the transport. Dry and wet depositions are the comparably dominant sinks, but wet deposition is larger than dry deposition over the Korea-Japan region, particularly in spring (70% versus 30%). The WRF-Chem simulations can generally capture the measured features of dust aerosols and its radaitve properties and dust mass balance over East Asia, which provides confidence for use in further investigation of dust impact on climate over East Asia.

  1. Surface Energy and Mass Balance Model for Greenland Ice Sheet and Future Projections

    Science.gov (United States)

    Liu, Xiaojian

    The Greenland Ice Sheet contains nearly 3 million cubic kilometers of glacial ice. If the entire ice sheet completely melted, sea level would raise by nearly 7 meters. There is thus considerable interest in monitoring the mass balance of the Greenland Ice Sheet. Each year, the ice sheet gains ice from snowfall and loses ice through iceberg calving and surface melting. In this thesis, we develop, validate and apply a physics based numerical model to estimate current and future surface mass balance of the Greenland Ice Sheet. The numerical model consists of a coupled surface energy balance and englacial model that is simple enough that it can be used for long time scale model runs, but unlike previous empirical parameterizations, has a physical basis. The surface energy balance model predicts ice sheet surface temperature and melt production. The englacial model predicts the evolution of temperature and meltwater within the ice sheet. These two models can be combined with estimates of precipitation (snowfall) to estimate the mass balance over the Greenland Ice Sheet. We first compare model performance with in-situ observations to demonstrate that the model works well. We next evaluate how predictions are degraded when we statistically downscale global climate data. We find that a simple, nearest neighbor interpolation scheme with a lapse rate correction is able to adequately reproduce melt patterns on the Greenland Ice Sheet. These results are comparable to those obtained using empirical Positive Degree Day (PDD) methods. Having validated the model, we next drove the ice sheet model using the suite of atmospheric model runs available through the CMIP5 atmospheric model inter-comparison, which in turn built upon the RCP 8.5 (business as usual) scenarios. From this exercise we predict how much surface melt production will increase in the coming century. This results in 4-10 cm sea level equivalent, depending on the CMIP5 models. Finally, we try to bound melt water

  2. Uncertainty analysis on simple mass balance model to calculate critical loads for soil acidity

    International Nuclear Information System (INIS)

    Li Harbin; McNulty, Steven G.

    2007-01-01

    Simple mass balance equations (SMBE) of critical acid loads (CAL) in forest soil were developed to assess potential risks of air pollutants to ecosystems. However, to apply SMBE reliably at large scales, SMBE must be tested for adequacy and uncertainty. Our goal was to provide a detailed analysis of uncertainty in SMBE so that sound strategies for scaling up CAL estimates to the national scale could be developed. Specifically, we wanted to quantify CAL uncertainty under natural variability in 17 model parameters, and determine their relative contributions in predicting CAL. Results indicated that uncertainty in CAL came primarily from components of base cation weathering (BC w ; 49%) and acid neutralizing capacity (46%), whereas the most critical parameters were BC w base rate (62%), soil depth (20%), and soil temperature (11%). Thus, improvements in estimates of these factors are crucial to reducing uncertainty and successfully scaling up SMBE for national assessments of CAL. - A comprehensive uncertainty analysis, with advanced techniques and full list and full value ranges of all individual parameters, was used to examine a simple mass balance model and address questions of error partition and uncertainty reduction in critical acid load estimates that were not fully answered by previous studies

  3. Towards coupling of regional atmosphere models to ice sheet models by mass balance gradients - application to the Greenland Ice Sheet

    NARCIS (Netherlands)

    Helsen, M.M.; van de Wal, R.S.W.; van den Broeke, M.R.; van de Berg, W.J.; Oerlemans, J.

    2012-01-01

    It is notoriously difficult to couple surface mass balance (SMB) results from climate models to the changing geometry of an ice sheet model. This problem is traditionally avoided by using only accumulation from a climate model, and parameterizing the meltwater run-off as a function of temperature,

  4. Gaussian Process Model for Antarctic Surface Mass Balance and Ice Core Site Selection

    Science.gov (United States)

    White, P. A.; Reese, S.; Christensen, W. F.; Rupper, S.

    2017-12-01

    Surface mass balance (SMB) is an important factor in the estimation of sea level change, and data are collected to estimate models for prediction of SMB on the Antarctic ice sheet. Using Favier et al.'s (2013) quality-controlled aggregate data set of SMB field measurements, a fully Bayesian spatial model is posed to estimate Antarctic SMB and propose new field measurement locations. Utilizing Nearest-Neighbor Gaussian process (NNGP) models, SMB is estimated over the Antarctic ice sheet. An Antarctic SMB map is rendered using this model and is compared with previous estimates. A prediction uncertainty map is created to identify regions of high SMB uncertainty. The model estimates net SMB to be 2173 Gton yr-1 with 95% credible interval (2021,2331) Gton yr-1. On average, these results suggest lower Antarctic SMB and higher uncertainty than previously purported [Vaughan et al. (1999); Van de Berg et al. (2006); Arthern, Winebrenner and Vaughan (2006); Bromwich et al. (2004); Lenaerts et al. (2012)], even though this model utilizes significantly more observations than previous models. Using the Gaussian process' uncertainty and model parameters, we propose 15 new measurement locations for field study utilizing a maximin space-filling, error-minimizing design; these potential measurements are identied to minimize future estimation uncertainty. Using currently accepted Antarctic mass balance estimates and our SMB estimate, we estimate net mass loss [Shepherd et al. (2012); Jacob et al. (2012)]. Furthermore, we discuss modeling details for both space-time data and combining field measurement data with output from mathematical models using the NNGP framework.

  5. Biogeochemical mass balances in a turbid tropical reservoir. Field data and modelling approach

    Science.gov (United States)

    Phuong Doan, Thuy Kim; Némery, Julien; Gratiot, Nicolas; Schmid, Martin

    2014-05-01

    The turbid tropical Cointzio reservoir, located in the Trans Mexican Volcanic Belt (TMVB), behaves as a warm monomictic water body (area = 6 km2, capacity 66 Mm3, residence time ~ 1 year). It is strategic for the drinking water supply of the city of Morelia, capital of the state of Michoacán, and for downstream irrigation during the dry season. This reservoir is a perfect example of a human-impacted system since its watershed is mainly composed of degraded volcanic soils and is subjected to high erosion processes and agricultural loss. The reservoir is threatened by sediment accumulation and nutrients originating from untreated waters in the upstream watershed. The high content of very fine clay particles and the lack of water treatment plants lead to serious episodes of eutrophication (up to 70 μg chl. a L-1), high levels of turbidity (Secchi depth water vertical profiles, reservoir inflow and outflow) we determined suspended sediment (SS), carbon (C), nitrogen (N) and phosphorus (P) mass balances. Watershed SS yields were estimated at 35 t km2 y-1 of which 89-92 % were trapped in the Cointzio reservoir. As a consequence the reservoir has already lost 25 % of its initial storage capacity since its construction in 1940. Nutrient mass balances showed that 50 % and 46 % of incoming P and N were retained by sedimentation, and mainly eliminated through denitrification respectively. Removal of C by 30 % was also observed both by sedimentation and through gas emission. To complete field data analyses we examined the ability of vertical one dimensional (1DV) numerical models (Aquasim biogeochemical model coupled with k-ɛ mixing model) to reproduce the main biogeochemical cycles in the Cointzio reservoir. The model can describe all the mineralization processes both in the water column and in the sediment. The values of the entire mass balance of nutrients and of the mineralization rates (denitrification and aerobic benthic mineralization) calculated from the model

  6. Coupled Model of Heat and Mass Balance for Droplet Growth in Wet Steam Non-Equilibrium Homogeneous Condensation Flow

    Directory of Open Access Journals (Sweden)

    Xu Han

    2017-12-01

    Full Text Available Because of the complexity of wet steam two-phase condensation flow, many problems remain to be solved. The important part of condensation theory—the calculation of the water droplet growth model in the transition zone—is not ideal; thus, it is necessary to develop a water droplet growth model with full-scale range. On the basis of the heat and mass transfer equilibrium in droplet growth, a coupled model of heat and mass balance for droplet growth is proposed. To verify the accuracy of this model, the differences and applicable ranges of various models were analysed using the experimental data of Peters and Meyer and two widely used models. In the free molecular flow region, the heat and mass balance model coincides with the Young low-pressure correction model. In the transition region, the heat and mass balance model agrees well with the experimental values of Peters and Meyer. In the continuous flow region, the heat and mass balance model coincides with the Gyarmathy model. Therefore, the heat and mass balance model can be used to accurately describe the growth process of water droplets in the arbitrary range of Knudsen numbers.

  7. 21st century changes in the surface mass balance of the Greenland ice sheet simulated with the global model CESM

    Science.gov (United States)

    Vizcaíno, M.; Lipscomb, W. H.; Van den Broeke, M.

    2012-04-01

    We present here the first projections of 21st century surface mass balance change of the Greenland ice sheet simulated with the Community Earth System Model (CESM). CESM is a fully-coupled, global climate model developed at many research centers and universities, primarily in the U.S. The model calculates the surface mass balance in the land component (the Community Land Model, CLM), at the same resolution as the atmosphere (1 degree), with an energy-balance scheme. The snow physics included in CLM for non-glaciated surfaces (SNiCAR model, Flanner and Zender, 2005) are used over the ice sheet. The surface mass balance is calculated for 10 elevation classes, and then downscaled to the grid of the ice sheet model (5 km in this case) via vertical linear interpolation between elevation classes combined with horizontal bilinear interpolation. The ice sheet topography is fixed at present-day values for the simulations presented here. The use of elevation classes reduces computational costs while giving results that reproduce well the mass balance gradients at the steep margins of the ice sheet. The simulated present-day surface mass balance agrees well with results from regional models. We focus on the regional model RACMO (Ettema et al. 2009) to compare the results on 20th-century surface mass balance evolution and two-dimensional patterns. The surface mass balance of the ice sheet under RCP8.5. forcing becomes negative in the last decades of the 21st century. The equilibrium line becomes ~500 m higher on average. Accumulation changes are positive in the accumulation zone. We examine changes in refreezing, accumulation, albedo, surface fluxes, and the timing of the melt season.

  8. Mass balance of Djankuat Glacier, Central Caucasus: observations, modeling and prediction

    Science.gov (United States)

    Rybak, Oleg; Mariia, Kaminskaia; Stanislav, Kutuzov; Ivan, Lavrentiev; Polina, Morozova; Victor, Popovnin; Elena, Rybak

    2017-04-01

    Djankuat is a typical valley glacier on the northern slope of the main Caucasus chain. Its present day area is approximately 2.5 square km with the characteristic ice thickness of several tens of meters. As well as other glaciers in the region, Djankuat has been shrinking during the last several decades, its cumulative mass balance in 1968-2016 was equal to -13.6 m w.e. In general, Caucasus' glaciers lost approximately one-third of their area and half of the volume. Prediction of further deradation of glaciers in changing environment is a challenging task because rivers fed by glacier melt water provide from 40 to 70% of the total river run-off in the adjacent piedmont territories. Growing demand in fresh water is rather critical for the local economy development and for growing population, motivating elaboration of an effitient instrument for evaluation and forecasting of the glaciation in the Greater Caucasus. Unfortunately, systematic observations are sparse limiting possibilities for proper model development for the most of the glaciers. Under these circumstances, we have to rely on the models developed for the few well-studied ones, like Djankuat, which is probably one of the most explored glaciers in the world. Accumulation and ablation rates have been observed here systematically and uninterruptedly since mid 60-ies using dense stake network. Together with the mass balance components, changes in flow velocity, ice thickness and geometry were regularly evaluated. During the last several ablation seasons, direct meteorological observations were carried out using an AMS. Long series of meteorological observations at the nearest weather station allow making assessment of the glacier response to climate change in the second half of the 20th century. Abundant observation data gave us the opportunity to elaborate, calibrate and validate an efficient mathematical model of surface mass balance of a typical glacier in the region. Since many glaciers in the Caucasus

  9. Does mechanistic modeling of filter strip pesticide mass balance and degradation processes affect environmental exposure assessments?

    Science.gov (United States)

    Muñoz-Carpena, Rafael; Ritter, Amy; Fox, Garey A; Perez-Ovilla, Oscar

    2015-11-01

    Vegetative filter strips (VFS) are a widely adopted practice for limiting pesticide transport from adjacent fields to receiving waterbodies. The efficacy of VFS depends on site-specific input factors. To elucidate the complex and non-linear relationships among these factors requires a process-based modeling framework. Previous research proposed linking existing higher-tier environmental exposure models with a well-tested VFS model (VFSMOD). However, the framework assumed pesticide mass stored in the VFS was not available for transport in subsequent storm events. A new pesticide mass balance component was developed to estimate surface pesticide residue trapped in the VFS and its degradation between consecutive runoff events. The influence and necessity of the updated framework on acute and chronic estimated environmental concentrations (EECs) and percent reductions in EECs were investigated across three, 30-year U.S. EPA scenarios: Illinois corn, California tomato, and Oregon wheat. The updated framework with degradation predicted higher EECs than the existing framework without degradation for scenarios with greater sediment transport, longer VFS lengths, and highly sorbing and persistent pesticides. Global sensitivity analysis (GSA) assessed the relative importance of mass balance and degradation processes in the context of other input factors like VFS length (VL), organic-carbon sorption coefficient (Koc), and soil and water half-lives. Considering VFS pesticide residue and degradation was not important if single, large runoff events controlled transport, as is typical for higher percentiles considered in exposure assessments. Degradation processes become more important when considering percent reductions in acute or chronic EECs, especially under scenarios with lower pesticide losses. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. Real-time nonlinear feedback control of pattern formation in (bio)chemical reaction-diffusion processes: a model study.

    Science.gov (United States)

    Brandt-Pollmann, U; Lebiedz, D; Diehl, M; Sager, S; Schlöder, J

    2005-09-01

    Theoretical and experimental studies related to manipulation of pattern formation in self-organizing reaction-diffusion processes by appropriate control stimuli become increasingly important both in chemical engineering and cellular biochemistry. In a model study, we demonstrate here exemplarily the application of an efficient nonlinear model predictive control (NMPC) algorithm to real-time optimal feedback control of pattern formation in a bacterial chemotaxis system modeled by nonlinear partial differential equations. The corresponding drift-diffusion model type is representative for many (bio)chemical systems involving nonlinear reaction dynamics and nonlinear diffusion. We show how the computed optimal feedback control strategy exploits the system inherent physical property of wave propagation to achieve desired control aims. We discuss various applications of our approach to optimal control of spatiotemporal dynamics.

  11. A Simplified Model of Human Alcohol Metabolism That Integrates Biotechnology and Human Health into a Mass Balance Team Project

    Science.gov (United States)

    Yang, Allen H. J.; Dimiduk, Kathryn; Daniel, Susan

    2011-01-01

    We present a simplified human alcohol metabolism model for a mass balance team project. Students explore aspects of engineering in biotechnology: designing/modeling biological systems, testing the design/model, evaluating new conditions, and exploring cutting-edge "lab-on-a-chip" research. This project highlights chemical engineering's impact on…

  12. Greenland ice sheet surface mass-balance modeling in a 131-Yr perspective, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2010-01-01

    and correct RCM output data before they were used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirmthemodel's robustness. The authors simulated an ~90% increase in end-of-summer surface melt extent (0.483 × 106 km2) from 1950......Fluctuations in the Greenland ice sheet (GrIS) surface mass balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise.Astate-of-the-art snow-evolution modeling system(SnowModel) was used...... to 2080 and a melt index (above 2000-m elevation) increase of 138% (1.96 × 106 km2 × days). The greatest difference in melt extent occurred in the southern part of theGrIS, and the greatest changes in the number of melt dayswere seen in the eastern part of the GrIS (~50%-70%) and were lowest in the west...

  13. Bayesian treatment of a chemical mass balance receptor model with multiplicative error structure

    Science.gov (United States)

    Keats, Andrew; Cheng, Man-Ting; Yee, Eugene; Lien, Fue-Sang

    The chemical mass balance (CMB) receptor model is commonly used in source apportionment studies as a means for attributing measured airborne particulate matter (PM) to its constituent emission sources. Traditionally, error terms (e.g., measurement and source profile uncertainty) associated with the model have been treated in an additive sense. In this work, however, arguments are made for the assumption of multiplicative errors, and the effects of this assumption are realized in a Bayesian probabilistic formulation which incorporates a 'modified' receptor model. One practical, beneficial effect of the multiplicative error assumption is that it automatically precludes the possibility of negative source contributions, without requiring additional constraints on the problem. The present Bayesian treatment further differs from traditional approaches in that the source profiles are inferred alongside the source contributions. Existing knowledge regarding the source profiles is incorporated as prior information to be updated through the Bayesian inferential scheme. Hundreds of parameters are therefore present in the expression for the joint probability of the source contributions and profiles (the posterior probability density function, or PDF), whose domain is explored efficiently using the Hamiltonian Markov chain Monte Carlo method. The overall methodology is evaluated and results compared to the US Environmental Protection Agency's standard CMB model using a test case based on PM data from Fresno, California.

  14. Development of a Water and Enthalpy Budget-based Glacier mass balance Model (WEB-GM) and its preliminary validation

    Science.gov (United States)

    Ding, Baohong; Yang, Kun; Yang, Wei; He, Xiaobo; Chen, Yingying; Lazhu; Guo, Xiaofeng; Wang, Lei; Wu, Hui; Yao, Tandong

    2017-04-01

    This paper presents a new water and energy budget-based glacier mass balance model. Enthalpy, rather than temperature, is used in the energy balance equations to simplify the computation of the energy transfers through the water phase change and the movement of liquid water in the snow. A new parameterization for albedo estimation and state-of-the-art parameterization schemes for rainfall/snowfall type identification and surface turbulent heat flux calculations are implemented in the model. This model was driven with meteorological data and evaluated using mass balance and turbulent flux data collected during a field experiment implemented in the ablation zone of the Parlung No. 4 Glacier on the Southeast Tibetan Plateau during 2009 and 2015-2016. The evaluation shows that the model can reproduce the observed glacier ablation depth, surface albedo, surface temperature, sensible heat flux, and latent heat flux with high accuracy. Comparing with a traditional energy budget-based glacier mass balance model, this enthalpy-based model shows a superior capacity in simulation accuracy. Therefore, this model can reasonably simulate the energy budget and mass balance of glacier melting in this region and be used as a component of land surface models and hydrological models.

  15. Numerical modeling of gas mixing and bio-chemical transformations during underground hydrogen storage within the project H2STORE

    Science.gov (United States)

    Hagemann, B.; Feldmann, F.; Panfilov, M.; Ganzer, L.

    2015-12-01

    The change from fossil to renewable energy sources is demanding an increasing amount of storage capacities for electrical energy. A promising technological solution is the storage of hydrogen in the subsurface. Hydrogen can be produced by electrolysis using excessive electrical energy and subsequently converted back into electricity by fuel cells or engine generators. The development of this technology starts with adding small amounts of hydrogen to the high pressure natural gas grid and continues with the creation of pure underground hydrogen storages. The feasibility of hydrogen storage in depleted gas reservoirs is investigated in the lighthouse project H2STORE financed by the German Ministry for Education and Research. The joint research project has project members from the University of Jena, the Clausthal University of Technology, the GFZ Potsdam and the French National Center for Scientic Research in Nancy. The six sub projects are based on laboratory experiments, numerical simulations and analytical work which cover the investigation of mineralogical, geochemical, physio-chemical, sedimentological, microbiological and gas mixing processes in reservoir and cap rocks. The focus in this presentation is on the numerical modeling of underground hydrogen storage. A mathematical model was developed which describes the involved coupled hydrodynamic and microbiological effects. Thereby, the bio-chemical reaction rates depend on the kinetics of microbial growth which is induced by the injection of hydrogen. The model has been numerically implemented on the basis of the open source code DuMuX. A field case study based on a real German gas reservoir was performed to investigate the mixing of hydrogen with residual gases and to discover the consequences of bio-chemical reactions.

  16. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    NARCIS (Netherlands)

    van Angelen, J.H.|info:eu-repo/dai/nl/325922470; Lenaerts, J.T.M.|info:eu-repo/dai/nl/314850163; Lhermitte, S.; Fettweis, X.; Kuipers Munneke, P.|info:eu-repo/dai/nl/304831891; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Meijgaard, E.; Smeets, C.J.P.P.|info:eu-repo/dai/nl/191522236

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover,

  17. Estimating Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    NARCIS (Netherlands)

    Fettweis, X.; Franco, B.; Tedesco, M.; van Angelen, J.H.; Lenaerts, J.T.M.; van den Broeke, M.R.; Gallee, H

    2012-01-01

    We report future projections of Surface Mass Balance (SMB) over the Greenland ice sheet (GrIS) obtained with the regional climate model MAR, forced by the outputs of three CMIP5 General Circulation Models (GCMs) when considering two different warming scenarios (RCP 4.5 and RCP 8.5). The GCMs

  18. A heuristic simulation model of Lake Ontario circulation and mass balance transport

    Science.gov (United States)

    McKenna, J.E.; Chalupnicki, M.A.

    2011-01-01

    The redistribution of suspended organisms and materials by large-scale currents is part of natural ecological processes in large aquatic systems but can contribute to ecosystem disruption when exotic elements are introduced into the system. Toxic compounds and planktonic organisms spend various lengths of time in suspension before settling to the bottom or otherwise being removed. We constructed a simple physical simulation model, including the influence of major tributaries, to qualitatively examine circulation patterns in Lake Ontario. We used a simple mass balance approach to estimate the relative water input to and export from each of 10 depth regime-specific compartments (nearshore vs. offshore) comprising Lake Ontario. Despite its simplicity, our model produced circulation patterns similar to those reported by more complex studies in the literature. A three-gyre pattern, with the classic large counterclockwise central lake circulation, and a simpler two-gyre system were both observed. These qualitative simulations indicate little offshore transport along the south shore, except near the mouths of the Niagara River and Oswego River. Complex flow structure was evident, particularly near the Niagara River mouth and in offshore waters of the eastern basin. Average Lake Ontario residence time is 8 years, but the fastest model pathway indicated potential transport of plankton through the lake in as little as 60 days. This simulation illustrates potential invasion pathways and provides rough estimates of planktonic larval dispersal or chemical transport among nearshore and offshore areas of Lake Ontario. ?? 2011 Taylor & Francis.

  19. Surface Mass Balance Distributions: Downscaling of Coarse Climates to drive Ice Sheet Models realistically

    Science.gov (United States)

    Rodehacke, Christian; Mottram, Ruth; Langen, Peter; Madsen, Marianne; Yang, Shuting; Boberg, Fredrik; Christensen, Jens

    2017-04-01

    The surface mass balance (SMB) is the most import boundary conditions for the state of glaciers and ice sheets. Hence its representation in numerical model simulations is of highest interest for glacier, ice cap and ice sheet modeling efforts. While descent SMB distributions of the current climate could be interfered with the help of various observation techniques and platforms, its construction for older past and future climates relies on input from spatially coarse resolved global climate models or reconstructions. These coarse SMB estimates with a footprint in the order of 100 km could hardly resolve the marginal ablations zones where the Greenland ice sheets, for instance, loses snow and ice. We present a downscaling method that is based on the physical calculation of the surface mass and energy balance. By the consequent application of universal and computationally cheap parameterizations we get an astonishing good representation of the SMB distribution including its marginal ablation zone. However the method has its limitations; for example wrong accumulation rates due to an insufficient precipitation field leaves its imprint on the SMB distribution. Also the still not satisfactory description of the bare ice albedo, in particular, in parts of Greenland is a challenge. We inspect our Greenland SMB fields' for various forcings and compare them with some widely used reference fields in the community to highlight the weakness and strength of our approach. We use the ERA-Interim reanalyzes period starting in 1979 directly as well as dynamically downscaled by our regional climate model HIRHAM (5 km resolution). Also SMB distributions obtained from the climate model EC-Earth with a resolution of T159 (approx. 125 km resolution in Greenland) are used either directly or downscaled with our regional climate model HIRHAM. Model-based End-of-the-century SMB estimates give an outlook of the future.

  20. Coupling of a Detailed Snow Model to WRF-Hydro for Glacier Mass Balance and Glacier Runoff Studies

    Science.gov (United States)

    Eidhammer, T.; Gochis, D.; Barlage, M. J.; Rasmussen, R.

    2017-12-01

    Studies of mass balance in glaciers in complex terrain show that elevation gradients and complex topography in many glaciated regions lead to large variations in temperature, precipitation, winds (and thereby wind deflection, transport and deposition of dry snow during the accumulation season) and net radiative exchange across the glacier. Therefore, proper simulation of the non-homogenous, non-stationary, evolution of a glacier requires much finer resolution of atmospheric processes than typical global or regional climate models can provide. Furthermore, regional `atmosphere-only' models typically do not have the detailed information about runoff routing processes, which are important components in the hydrological cycle. Glacier melt contributes to discharge especially during summer when the magnitude of the summer peak river flow depends greatly on the contribution of melt water from snow and ice to the total river flow. This contribution from glaciers to total flow plays a key role in the glacier-fed rivers in populated regions where summer flows are crucial for irrigation, human consumption and energy production. We have incorporated the detailed Crocus snow model, as a glacier mass balance model, into the Noah-MP land model, within the Weather and Research Forecasting - Hydro (WRF-Hydro) modelling system. By linking a surface mass balance glacier model to the WRF-Hydro system (WRF-HydroGlac), the interactions between the energy, water and mass balance budgets over glaciated river basins can be better depicted and projected future impacts, better understood. We will demonstrate the WRF-HydroGlac model with a mass balance and snowpack/glacier runoff study of a highly observed Norwegian glacier (Hardangerjokulen).

  1. The mass balance of the Greenland ice sheet: sensitivity to climate change as revealed by energy-balance modelling

    NARCIS (Netherlands)

    Oerlemans, J.

    1991-01-01

    The sensitivity of the mass balance of the Greenland ice sheet to climate change is studied with an energy-balance model of the ice/snow surface, applied at 200 m elevation intervals for four characteristic regions of the ice sheet. Solar radiation, longwave radiation, turbulent heat fluxes

  2. Greenland Surface Mass Balance as Simulated by the Community Earth System Model. Part II: Twenty-First-Century Changes

    NARCIS (Netherlands)

    Vizcaino, M.; Lipscomb, W.H.; Sacks, W.J.; van den Broeke, M.R.

    2014-01-01

    This study presents the first twenty-first-century projections of surface mass balance (SMB) changes for the Greenland Ice Sheet (GIS) with the Community Earth System Model (CESM), which includes a new ice sheet component. For glaciated surfaces, CESM includes a sophisticated calculation of energy

  3. A mass balance model for the Mapleson D anaesthesia breathing system.

    Science.gov (United States)

    Lovich, M A; Simon, B A; Venegas, J G; Sims, N M; Cooper, J B

    1993-06-01

    A mathematical model is described which calculates the alveolar concentration of CO2(FACO2) in a patient breathing through a Mapleson D anaesthesia system. The model is derived using a series of mass balances for CO2 in the alveolar space, dead space, breathing system limb volume and reservoir. The variables included in the model are tidal volume (VT), respiratory rate, fresh gas flow rate (Vf), dead space volume, I:E ratio, and expiratory limb volume (Vl) time constant of lung expiration, and carbon dioxide production rate. The model predictions are compared with measurements made using a mechanical lung simulator in both spontaneous and controlled ventilation. Both the model and the experimental data predict that at high fresh gas flow rates and low respiratory rates, FACO2 is independent of Vf; at low fresh gas flow rates and high respiratory rates, FACO2 is independent of respiratory rate. The model and the data show that the VT influences FACO2, independent of minute ventilation alone, during both partial re-breathing and non-rebreathing operation. Therefore, describing the operation in terms of minute ventilation is ambiguous. It is also shown that Vl influences FACO2 such that, for any combination of patient and breathing-system variables, there is a Vl that minimizes the Vf required to maintain FACO2. In addition, expiratory resistance can increase the fresh gas flow rate required to maintain a given FACO2. The respiratory patterns observed with spontaneous and controlled ventilation are responsible for the difference in Vf required with each mode of ventilation.

  4. Glacier surface mass balance and freshwater runoff modeling for the entire Andes Cordillera

    Science.gov (United States)

    Mernild, Sebastian H.; Liston, Glen E.; Yde, Jacob C.

    2017-04-01

    Glacier surface mass balance (SMB) observations for the Andes Cordillera are limited and, therefore, estimates of the SMB contribution from South America to sea-level rise are highly uncertain. Here, we simulate meteorological, snow, glacier surface, and hydrological runoff conditions and trends for the Andes Cordillera (1979/80-2013/14), covering the tropical latitudes in the north down to the sub-polar latitudes in the far south, including the Northern Patagonia Ice Field (NPI) and Southern Patagonia Ice Field (SPI). SnowModel - a fully integrated energy balance, blowing-snow distribution, multi-layer snowpack, and runoff routing model - was used to simulate glacier SMBs for the Andes Cordillera. The Randolph Glacier Inventory and NASA Modern-Era Retrospective Analysis for Research and Applications products, downscaled in SnowModel, allowed us to conduct relatively high-resolution simulations. The simulated glacier SMBs were verified against independent directly-observed and satellite gravimetry and altimetry-derived SMB, indicating a good statistical agreement. For glaciers in the Andes Cordillera, the 35-year mean annual SMB was found to be -1.13 m water equivalent. For both NPI and SPI, the mean SMB was positive (where calving is the likely reason for explaining why geodetic estimates are negative). Further, the spatio-temporal freshwater river runoff patterns from individual basins, including their runoff magnitude and change, were simulated. For the Andes Cordillera rivers draining to the Pacific Ocean, 86% of the simulated runoff originated from rain, 12% from snowmelt, and 2% from ice melt, whereas, for example, for Chile, the water-source distribution was 69, 24, and 7%, respectively. Along the Andes Cordillera, the 35-year mean basin outlet-specific runoff (L s-1 km-2) showed a characteristic regional hourglass shape pattern with highest runoff in both Colombia and Ecuador and in Patagonia, and lowest runoff in the Atacama Desert area.

  5. Uncertainty analysis on simple mass balance model to calculate critical loads for soil acidity

    Science.gov (United States)

    Harbin Li; Steven G. McNulty

    2007-01-01

    Simple mass balance equations (SMBE) of critical acid loads (CAL) in forest soil were developed to assess potential risks of air pollutants to ecosystems. However, to apply SMBE reliably at large scales, SMBE must be tested for adequacy and uncertainty. Our goal was to provide a detailed analysis of uncertainty in SMBE so that sound strategies for scaling up CAL...

  6. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-11-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual mean near-surface air temperature increase over Greenland of ~ 2°C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice sheet would eventually be eliminated.

  7. E-Area Low-Level Waste Facility Vadose Zone Model: Confirmation of Water Mass Balance for Subsidence Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Dyer, J. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-11-30

    In preparation for the next revision of the E-Area Low-Level Waste Facility (LLWF) Performance Assessment (PA), a mass balance model was developed in Microsoft Excel to confirm correct implementation of intact- and subsided-area infiltration profiles for the proposed closure cap in the PORFLOW vadose-zone model. The infiltration profiles are based on the results of Hydrologic Evaluation of Landfill Performance (HELP) model simulations for both intact and subsided cases.

  8. Greenland ice sheet surface mass-balance modeling in a 131-year perspective, 1950-2080

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.; Hiemstra, Christopher [COLORADO STATE UNIV.; Christensen, Jens [DANISH METEOROLOGICAL INS.

    2009-01-01

    Fluctuations in the Greenland Ice Sheet (GrIS) surface mass-balance (SMB) and freshwater influx to the surrounding oceans closely follow climate fluctuations and are of considerable importance to the global eustatic sea level rise. SnowModel, a state-of-the-art snow-evolution modeling system, was used to simulate variations in the GrIS melt extent, surface water balance components, changes in SMB, and freshwater influx to the ocean. The simulations are based on the IPCC scenario AlB modeled by the HIRHAM4 RCM (using boundary conditions from ECHAM5 AOGCM) from 1950 through 2080. In-situ meteorological station (GC-Net and WMO DMI) observations from inside and outside the GrIS were used to validate and correct RCM output data before it was used as input for SnowModel. Satellite observations and independent SMB studies were used to validate the SnowModel output and confirm the model's robustness. We simulated a {approx}90% increase in end-of-summer surface melt extent (0.483 x 10{sup 6} km{sup 2}) from 1950 to 2080, and a melt index (above 2,000-m elevation) increase of 138% (1.96 x 10{sup 6} km{sup 2} x days). The greatest difference in melt extent occured in the southern part of the GrIS, and the greatest changes in the number of melt days was seen in the eastern part of the GrIS ({approx}50-70%) and was lowest in the west ({approx}20-30%). The rate of SMB loss, largely tied to changes in ablation processes, lead to an enhanced average loss of 331 km{sup 3} from 1950 to 2080, an average 5MB level of -99 km{sup 3} for the period 2070-2080. GrIS surface freshwater runoff yielded an eustatic rise in sea level from 0.8 {+-} 0.1 (1950-1959) to 1.9 {+-} 0.1 mm (2070-2080) sea level equivalent (SLE) y{sup -1}. The accumulated GrIS freshwater runoff contribution from surface melting equaled 160 mm SLE from 1950 through 2080.

  9. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2010-01-01

    in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign...... elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by surface density modelling. The firn compaction and density models are driven by a dynamically downscaled simulation of the HIRHAM5 regional climate model using ERA-Interim reanalysis lateral......ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...

  10. Modelling the contribution of supraglacial ice cliffs to the mass-balance of glaciers in the Langtang catchment, Nepalese Himalaya

    Science.gov (United States)

    Buri, P.; Steiner, J. F.; Miles, E.; Ragettli, S.; Pellicciotti, F.

    2017-12-01

    Supraglacial cliffs are typical surface features of debris-covered glaciers worldwide, affecting surface evolution, and mass balance by providing a direct ice-atmosphere interface where melt rates can be very high. As a result, ice cliffs act as windows of energy transfer from the atmosphere to the ice, and enhance melt and mass losses of otherwise insulated ice. However, their contribution to glacier mass balance has never been quantified at the glacier scale, and all inference has been obtained from upscaling results of point-scale models or observations at select individual cliffs. Here we use a 3D, physically-based backwasting model to estimate the volume losses associated with the melting and backwasting of supraglacial ice cliffs for the entire debris-covered glacier area of the Langtang catchment. We estimate mass losses for the 2014 melt season and compare them to recent values of glacier mass balance determined from geodetic and numerical modelling approached. Cliff outlines and topography are derived from high-resolution stereo SPOT6-imagery from April 2014. Meteorological data to force the model are provided by automatic weather stations on- and off-glacier within the valley. The model simulates ice cliff backwasting by considering the cliff-atmosphere energy-balance, reburial by debris and the effects of adjacent ponds. In the melt season of 2014, cliffs' distribution and patterns of mass losses vary considerably from glacier to glacier, and we relate rates of volume loss to both glaciers' and cliffs' characteristics. Only cliffs with a northerly aspect account for substantial losses. Uncertainty in our estimates is due to the quality of the stereo DEM, uncertainties in the cliff delineation and the fact that we use a conservative approach to cliff delineation and discard very small cliffs and those for which uncertainty in topography is high. Despite these uncertainties, our work presents the first estimate of the importance of supraglacial ice

  11. Estimation of Mass Balance of the Grosser Aletschgletscher, Swiss Alps, from ICESat Laser Altimetry Data and Digital Elevation Models

    Directory of Open Access Journals (Sweden)

    Jan Kropáček

    2014-06-01

    Full Text Available Traditional glaciological mass balance measurements of mountain glaciers are a demanding and cost intensive task. In this study, we combine data from the Ice Cloud and Elevation Satellite (ICESat acquired between 2003 and 2009 with air and space borne Digital Elevation Models (DEMs in order to derive surface elevation changes of the Grosser Aletschgletscher in the Swiss Alps. Three different areas of the glacier are covered by one nominal ICESat track, allowing us to investigate the performance of the approach under different conditions in terms of ICESat data coverage, and surface characteristics. In order to test the sensitivity of the derived trend in surface lowering, several variables were tested. Employing correction for perennial snow accumulation, footprint selection and adequate reference DEM, we estimated a mean mass balance of −0.92 ± 0.18 m w.e. a−1. for the whole glacier in the studied time period. The resulting mass balance was validated by a comparison with another geodetic approach based on the subtraction of two DEMs for the years 1999 and 2009. It appears that the processing parameters need to be selected depending on the amount of available ICESat measurements, quality of the elevation reference and character of the glacier surface.

  12. Multi-year analysis of distributed glacier mass balance modelling and equilibrium line altitude on King George Island, Antarctic Peninsula

    Directory of Open Access Journals (Sweden)

    U. Falk

    2018-04-01

    Full Text Available The South Shetland Islands are located at the northern tip of the Antarctic Peninsula (AP. This region was subject to strong warming trends in the atmospheric surface layer. Surface air temperature increased about 3 K in 50 years, concurrent with retreating glacier fronts, an increase in melt areas, ice surface lowering and rapid break-up and disintegration of ice shelves. The positive trend in surface air temperature has currently come to a halt. Observed surface air temperature lapse rates show a high variability during winter months (standard deviations up to ±1.0 K (100 m−1 and a distinct spatial heterogeneity reflecting the impact of synoptic weather patterns. The increased mesocyclonic activity during the wintertime over the past decades in the study area results in intensified advection of warm, moist air with high temperatures and rain and leads to melt conditions on the ice cap, fixating surface air temperatures to the melting point. Its impact on winter accumulation results in the observed negative mass balance estimates. Six years of continuous glaciological measurements on mass balance stake transects as well as 5 years of climatological data time series are presented and a spatially distributed glacier energy balance melt model adapted and run based on these multi-year data sets. The glaciological surface mass balance model is generally in good agreement with observations, except for atmospheric conditions promoting snow drift by high wind speeds, turbulence-driven snow deposition and snow layer erosion by rain. No drift in the difference between simulated mass balance and mass balance measurements can be seen over the course of the 5-year model run period. The winter accumulation does not suffice to compensate for the high variability in summer ablation. The results are analysed to assess changes in meltwater input to the coastal waters, specific glacier mass balance and the equilibrium line altitude (ELA. The

  13. Sensitivity of a Chemical Mass Balance model for PM2.5 to source profiles for differing styles of cooking

    Science.gov (United States)

    Abdullahi, K. L.; Delgado-Saborit, J. M.; Harrison, Roy M.

    2018-04-01

    Use of a Chemical Mass Balance model is one of the two most commonly used approaches to estimating atmospheric concentrations of cooking aerosol. Such models require the input of chemical profiles for each of the main sources contributing to particulate matter mass and there is appreciable evidence from the literature that not only the mass emission but also the chemical composition of particulate matter varies according to the food being prepared and the style of cooking. In this study, aerosol has been sampled in the laboratory from four different styles of cooking, i.e. Indian, Chinese, Western and African cooking. The chemical profiles of molecular markers have been quantified and are used individually within a Chemical Mass Balance model applied to air samples collected in a multi-ethnic area of Birmingham, UK. The model results give a source contribution estimate for cooking aerosol which is consistent with other comparable UK studies, but also shows a very low sensitivity of the model to the cooking aerosol profile utilised. A survey of local restaurants suggested a wide range of cooking styles taking place which may explain why no one profile gives an appreciably better fit in the CMB model.

  14. Development of an in vivo animal model for skin penetration in hairless rats assessed by mass balance

    DEFF Research Database (Denmark)

    Simonsen, Lene; Petersen, Mads B; Benfeldt, Eva

    2002-01-01

    acid and (14)C-butyl salicylate were topically applied. Rapid and differentiated percutaneous absorption of both compounds were shown by urinary excretion data. For (14)C-salicylic acid the amount on the skin surface, in the stratum corneum and in the viable skin was determined. Total mass balance...... rat and free mobility throughout the test period. By consecutive tape stripping, monitored by measurements of transepidermal water loss and confirmed by histological examination of skin biopsies, 10 tape strippings were found to remove the stratum corneum completely. For assessment of the model, (14)C-salicylic...

  15. Modelling system dynamics and phytoplankton diversity at Ranchi lake using the carbon and nutrient mass balance equations.

    Science.gov (United States)

    Mukherjee, B; Nivedita, M; Mukherjee, D

    2014-05-01

    Modelling system dynamics in a hyper-eutrophic lake is quite complex especially with a constant influx of detergents and sewage material which continually changes the state variables and interferes with the assessment of the chemical rhythm occurring in polluted conditions as compared to unpolluted systems. In this paper, a carbon and nutrient mass balance model for predicting system dynamics in a complex environment was studied. Studies were conducted at Ranchi lake to understand the altered environmental dynamics in hyper-eutrophic conditions, and its impact on the plankton community. The lake was monitored regularly for five years (2007 - 2011) and the data collected on the carbon flux, nitrates, phosphates and silicates was used to design a mass balance model for evaluating and predicting the system. The model was then used to correlate the chemical rhythm with that of the phytoplankton dynamics and diversity. Nitrates and phosphates were not limiting (mean nitrate and phosphate concentrations were 1.74 and 0.83 mgl⁻¹ respectively). Free carbon dioxide was found to control the system and, interacting with other parameters determined the diversity and dynamics of the plankton community. N/P ratio determined which group of phytoplankton dominated the community, above 5 it favoured the growth of chlorophyceae while below 5 cyanobacteria dominates. TOC/TIC ratio determined the abundance. The overall system was controlled by the availability of free carbon dioxide which served as a limiting factor.

  16. On Deriving Requirements for the Surface Mass Balance forcing of a Greenland Ice Sheet Model using Uncertainty Analyses

    Science.gov (United States)

    Schlegel, N.; Larour, E. Y.; Box, J. E.

    2015-12-01

    During July of 2012, the percentage of the Greenland surface exposed to melt was the largest in recorded history. And, even though evidence of increased melt rates had been captured by remote sensing observations throughout the last decade, this particular event took the community by surprise. How Greenland ice flow will respond to such an event or to increased frequencies of extreme melt events in the future is unclear, as it requires detailed comprehension of Greenland surface climate and the ice sheet's sensitivity to associated uncertainties. With established uncertainty quantification (UQ) tools embedded within the Ice Sheet System Model (ISSM), we conduct decadal-scale forward modeling experiments to 1) quantify the spatial resolution needed to effectively force surface mass balance (SMB) in various regions of the ice sheet and 2) determine the dynamic response of Greenland outlet glaciers to variations in SMB. First, we perform sensitivity analyses to determine how perturbations in SMB affect model output; results allow us to investigate the locations where variations most significantly affect ice flow, and on what spatial scales. Next, we apply Monte-Carlo style sampling analyses to determine how errors in SMB propagate through the model as uncertainties in estimates of Greenland ice discharge and regional mass balance. This work is performed at the California Institute of Technology's Jet Propulsion Laboratory under a contract with the National Aeronautics and Space Administration's Cryosphere Program.

  17. Effect of GIA models with 3D composite mantle viscosity on GRACE mass balance estimates for Antarctica

    Science.gov (United States)

    van der Wal, Wouter; Whitehouse, Pippa L.; Schrama, Ernst J. O.

    2015-03-01

    Seismic data indicate that there are large viscosity variations in the mantle beneath Antarctica. Consideration of such variations would affect predictions of models of Glacial Isostatic Adjustment (GIA), which are used to correct satellite measurements of ice mass change. However, most GIA models used for that purpose have assumed the mantle to be uniformly stratified in terms of viscosity. The goal of this study is to estimate the effect of lateral variations in viscosity on Antarctic mass balance estimates derived from the Gravity Recovery and Climate Experiment (GRACE) data. To this end, recently-developed global GIA models based on lateral variations in mantle temperature are tuned to fit constraints in the northern hemisphere and then compared to GPS-derived uplift rates in Antarctica. We find that these models can provide a better fit to GPS uplift rates in Antarctica than existing GIA models with a radially-varying (1D) rheology. When 3D viscosity models in combination with specific ice loading histories are used to correct GRACE measurements, mass loss in Antarctica is smaller than previously found for the same ice loading histories and their preferred 1D viscosity profiles. The variation in mass balance estimates arising from using different plausible realizations of 3D viscosity amounts to 20 Gt/yr for the ICE-5G ice model and 16 Gt/yr for the W12a ice model; these values are larger than the GRACE measurement error, but smaller than the variation arising from unknown ice history. While there exist 1D Earth models that can reproduce the total mass balance estimates derived using 3D Earth models, the spatial pattern of gravity rates can be significantly affected by 3D viscosity in a way that cannot be reproduced by GIA models with 1D viscosity. As an example, models with 1D viscosity always predict maximum gravity rates in the Ross Sea for the ICE-5G ice model, however, for one of the three preferred 3D models the maximum (for the same ice model) is found

  18. The exploration of trophic structure modeling using mass balance Ecopath model of Tangerang coastal waters

    Science.gov (United States)

    Dewi, N. N.; Kamal, M.; Wardiatno, Y.; Rozi

    2018-04-01

    Ecopath model approach was used to describe trophic interaction, energy flows and ecosystem condition of Tangerang coastal waters. This model consists of 42 ecological groups, of which 41 are living groups and one is a detritus group. Trophic levels of these groups vary between 1.0 (for primary producers and detritus) to 4.03 (for tetraodontidae). Groups with trophic levels 2≤TL<3 and 3≤TL<4 have a range of ecotropic efficiency from 0 to 0.9719 and 0 to 0.7520 respectively.The Mean transfer efficiency is 9.43% for phytoplankton and 3.39% for detritus. The Mixed trophic impact analysis indicates that phytoplankton havea positive impact on the majority of pelagic fish, while detritus has a positive impact on the majority of demersal fish. Leiognathidae havea negative impact on phytoplankton, zooplankton and several other groups. System omnivory index for this ecosystem is 0.151. System primary production/respiration (P/R) ratio of Tangerang coastal waters is 1.505. This coastal ecosystem is an immatureecosystem because it hasdegraded. Pedigree index for this model is 0.57. This model describes ecosystem condition affected by overfishing and antropogenic activities. Therefore, through Ecopath model we provide some suggestions about the ecosystem-based fisheries management.

  19. A two-component mass balance model for calibration of solid-phase microextraction fibers for pyrethroids in seawater.

    Science.gov (United States)

    Lao, Wenjian; Maruya, Keith A; Tsukada, David

    2012-11-06

    Determination of the analyte-specific distribution coefficient between the aqueous and sorbing phases is required for estimation of the aqueous-phase concentration of the analyte of interest using polymeric materials. Poly(dimethylsiloxane)-coated solid-phase microextration (PDMS-SPME) fiber-water partition coefficient (K(f)) values for eight common-use pyrethroids were determined using a two-compartment mass balance model and parameters determined in experimental seawater microcosms. Mass balance, epimerization, and aqueous-phase degradation (i.e., hydrolysis) were characterized using gas chromatography-negative chemical ionization mass spectrometry to facilitate K(f) estimation. Of the eight pyrethroids, only bifenthrin exhibited increasing sorption on the SPME fiber over the entire time-series exposure, indicating that its K(f) value could be estimated through a stable-compound model. The remaining pyrethroids were found to be unstable (half-life of 0.98) and the remaining unstable pyrethroids (R(2) > 0.7), leading to estimated values of log K(f) between 5.7 and 6.4, after correcting for residual dissolved organic carbon (DOC) in the experimental seawater. These K(f) values can be used to determine freely dissolved pyrethroid concentrations in the pg/L range using PDMS-SPME in fresh or seawater matrices under equilibrium conditions in laboratory or field applications.

  20. Coupling of climate models and ice sheet models by surface mass balance gradients: application to the Greenland Ice Sheet

    Directory of Open Access Journals (Sweden)

    M. M. Helsen

    2012-03-01

    Full Text Available It is notoriously difficult to couple surface mass balance (SMB results from climate models to the changing geometry of an ice sheet model. This problem is traditionally avoided by using only accumulation from a climate model, and parameterizing the meltwater run-off as a function of temperature, which is often related to surface elevation (Hs. In this study, we propose a new strategy to calculate SMB, to allow a direct adjustment of SMB to a change in ice sheet topography and/or a change in climate forcing. This method is based on elevational gradients in the SMB field as computed by a regional climate model. Separate linear relations are derived for ablation and accumulation, using pairs of Hs and SMB within a minimum search radius. The continuously adjusting SMB forcing is consistent with climate model forcing fields, also for initially non-glaciated areas in the peripheral areas of an ice sheet. When applied to an asynchronous coupled ice sheet – climate model setup, this method circumvents traditional temperature lapse rate assumptions. Here we apply it to the Greenland Ice Sheet (GrIS. Experiments using both steady-state forcing and glacial-interglacial forcing result in realistic ice sheet reconstructions.

  1. Using bioprocess stoichiometry to build a plant-wide mass balance based steady-state WWTP model.

    Science.gov (United States)

    Ekama, G A

    2009-05-01

    Steady-state models are useful for design of wastewater treatment plants (WWTPs) because they allow reactor sizes and interconnecting flows to be simply determined from explicit equations in terms of unit operation performance criteria. Once the overall WWTP scheme is established and the main system defining parameters of the individual unit operations estimated, dynamic models can be applied to the connected unit operations to refine their design and evaluate their performance under dynamic flow and load conditions. To model anaerobic digestion (AD) within plant-wide WWTP models, not only COD and nitrogen (N) but also carbon (C) fluxes entering the AD need to be defined. Current plant-wide models, like benchmark simulation model No 2 (BSM2), impose a C flux at the AD influent. In this paper, the COD and N mass balance steady-state models of activated sludge (AS) organics degradation, nitrification and denitrification (ND) and anaerobic (AD) and aerobic (AerD) digestion of wastewater sludge are extended and linked with bioprocess transformation stoichiometry to form C, H, O, N, chemical oxygen demand (COD) and charge mass balance based models so that also C (and H and O) can be tracked through the whole WWTP. By assigning a stoichiometric composition (x, y, z and a in C(x)H(y)O(z)N(a)) to each of the five main influent wastewater organic fractions and ammonia, these, and the products generated from them via the biological processes, are tracked through the WWTP. The model is applied to two theoretical case study WWTPs treating the same raw wastewater (WW) to the same final sludge residual biodegradable COD. It is demonstrated that much useful information can be generated with the relatively simple steady-state models to aid WWTP layout design and track the different products exiting the WWTP via the solid, liquid and gas streams, such as aerobic versus anaerobic digestion of waste activated sludge, N loads in recycle streams, methane production for energy recovery

  2. Trophic mass-balance model of Alaska's Prince William Sound ecosystem, for the post-spill period 1994-1996

    International Nuclear Information System (INIS)

    Okey, T.A.; Pauly, D.

    1998-01-01

    The Ecopath modelling approach for the Prince William Sound (PWS) ecosystem was described. The area is the site of the 1989 Exxon Valdez oil spill (EVOS), the largest spill in U.S. history. 36,000 tonnes of crude oil spread throughout the central and southwestern PWS into the Gulf of Alaska and along the Kenai and Alaska Peninsula. The initial effects of the oil spill were catastrophic. The Ecopath modelling approach discussed in this report is aimed at providing a cohesive picture of the PWS ecosystem by constructing a mass-balanced model of food-web interactions and trophic flows using information collected since the EVOS. The model includes all biotic components of the ecosystem and provides a quantitative description of food-web interactions and relationships, as well as energy flows among components. The model can provide an understanding of how ecosystems respond to disturbances, such as oil spills. 216 refs., 74 tabs., 13 figs., 8 appendices

  3. Modeling mass balance and volume of Xiao Dongkemadi glacier in the Central Tibetan Plateau from 1989 to 2050

    Science.gov (United States)

    Duan, K.

    2015-12-01

    The Tibetan Plateau (TP) holds ten thousands of alpine glaciers in mid-latitude, which have shrunk with an accelerating retreat rate recently. Here, we applied a temperature-index distributed mass-balance model coupled with a volume-area scaling method to Xiao Dongkemadi Glacier (XDG) in the central TP, to assess its response to climate change. The result shows the simulated mass balance is in a good agreement with observations (R2=0.75, pRegCM4 under the climate scenarios RCP4.5 and RCP8.5 from 2013 to 2050. The simulated terminus elevation of the glacier will rise from 5454m a.s.l. in 2013 to 5533m a.s.l. (RCP4.5) and 5543m a.s.l (RCP8.5) in 2050. XDG will lose its volume with an increasing rate of 600-700m3 a-1 during the period of 1989-2050, indicating the melting water will enhance the river runoff. But for the long term, the contribution to the river runoff will decrease for shrinkage of glacier scale.

  4. Investigating ice cliff evolution and contribution to glacier mass-balance using a physically-based dynamic model

    Science.gov (United States)

    Buri, Pascal; Miles, Evan; Ragettli, Silvan; Brun, Fanny; Steiner, Jakob; Pellicciotti, Francesca

    2016-04-01

    Supraglacial cliffs are a surface feature typical of debris-covered glaciers, affecting surface evolution, glacier downwasting and mass balance by providing a direct ice-atmosphere interface. As a result, melt rates can be very high and ice cliffs may account for a significant portion of the total glacier mass loss. However, their contribution to glacier mass balance has rarely been quantified through physically-based models. Most cliff energy balance models are point scale models which calculate energy fluxes at individual cliff locations. Results from the only grid based model to date accurately reflect energy fluxes and cliff melt, but modelled backwasting patterns are in some cases unrealistic, as the distribution of melt rates would lead to progressive shallowing and disappearance of cliffs. Based on a unique multitemporal dataset of cliff topography and backwasting obtained from high-resolution terrestrial and aerial Structure-from-Motion analysis on Lirung Glacier in Nepal, it is apparent that cliffs exhibit a range of behaviours but most do not rapidly disappear. The patterns of evolution cannot be explained satisfactorily by atmospheric melt alone, and are moderated by the presence of supraglacial ponds at the base of cliffs and by cliff reburial with debris. Here, we document the distinct patterns of evolution including disappearance, growth and stability. We then use these observations to improve the grid-based energy balance model, implementing periodic updates of the cliff geometry resulting from modelled melt perpendicular to the ice surface. Based on a slope threshold, pixels can be reburied by debris or become debris-free. The effect of ponds are taken into account through enhanced melt rates in horizontal direction on pixels selected based on an algorithm considering distance to the water surface, slope and lake level. We use the dynamic model to first study the evolution of selected cliffs for which accurate, high resolution DEMs are available

  5. Application of a mass-balance model to predict PCDD/F turnover in a Baltic coastal estuary

    Science.gov (United States)

    Karlsson, O. Magnus; Malmaeus, J. Mikael; Josefsson, Sarah; Wiberg, Karin; Håkanson, Lars

    2010-06-01

    A dynamical, process-based mass-balance model was applied to quantify the transports of polychlorinated- p-dibenzodioxins and dibenzofurans (PCDD/Fs) to, within and from the Kallrigafjärden Bay, a coastal estuary in the Baltic Sea, and to predict the PCDD/F levels in the water and sediments of the bay. Before the modelling, a one-year sampling programme was implemented in 2007-2008 to measure the flows of PCDD/Fs in tributaries entering the system, the fluxes from the adjacent sea and the levels in water, sediment and fish within the estuary. The collected data set was used as input data to the model and for validation purposes. The model was originally developed and tested for suspended particulate matter and phosphorus in Baltic coastal areas. In this work, it was run monthly without any tuning of the original model variables. The simulation results compared favourably with the field measurements of levels of 15 PCDD/F congeners in the water and sediments of the bay. The dominating fluxes of PCDD/Fs were the exchange with the adjacent sea, followed by riverine input, atmospheric deposition and sediment burial. Although the sediment-water exchange was of minor importance for the overall mass-balance due to the rapid water turnover and limited areas favourable for the long-term deposition of fine sedimentary matter, sensitivity analyses indicated that the model's predictive capability was improved with about 5% by taking the sediment burial and release into account.

  6. Modeling the influence of climate change on the mass balance of polychlorinated biphenyls in the Adriatic Sea.

    Science.gov (United States)

    Lamon, Lara; MacLeod, Matthew; Marcomini, Antonio; Hungerbühler, Konrad

    2012-05-01

    Climate forcing is forecasted to influence the Adriatic Sea region in a variety of ways, including increasing temperature, and affecting wind speeds, marine currents, precipitation and water salinity. The Adriatic Sea is intensively developed with agriculture, industry, and port activities that introduce pollutants to the environment. Here, we developed and applied a Level III fugacity model for the Adriatic Sea to estimate the current mass balance of polychlorinated biphenyls in the Sea, and to examine the effects of a climate change scenario on the distribution of these pollutants. The model's performance was evaluated for three PCB congeners against measured concentrations in the region using environmental parameters estimated from the 20th century climate scenario described in the Special Report on Emission Scenarios (SRES) by the IPCC, and using Monte Carlo uncertainty analysis. We find that modeled fugacities of PCBs in air, water and sediment of the Adriatic are in good agreement with observations. The model indicates that PCBs in the Adriatic Sea are closely coupled with the atmosphere, which acts as a net source to the water column. We used model experiments to assess the influence of changes in temperature, wind speed, precipitation, marine currents, particulate organic carbon and air inflow concentrations forecast in the IPCC A1B climate change scenario on the mass balance of PCBs in the Sea. Assuming an identical PCBs' emission profile (e.g. use pattern, treatment/disposal of stockpiles, mode of entry), modeled fugacities of PCBs in the Adriatic Sea under the A1B climate scenario are higher because higher temperatures reduce the fugacity capacity of air, water and sediments, and because diffusive sources to the air are stronger. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. Development of an in vivo animal model for skin penetration in hairless rats assessed by mass balance

    DEFF Research Database (Denmark)

    Simonsen, Lene; Petersen, Mads B; Benfeldt, Eva

    2002-01-01

    -salicylic acid and (14)C-butyl salicylate were topically applied. Rapid and differentiated percutaneous absorption of both compounds were shown by urinary excretion data. For (14)C-salicylic acid the amount on the skin surface, in the stratum corneum and in the viable skin was determined. Total mass balance......The aim of the study was to develop an in vivo animal model for studies of the penetration of topically applied drugs into the skin of hairless rats. Protective appliances were designed for non-occluded and finite-dose application of topical formulations. The design allowed 2 test sites for each...... rat and free mobility throughout the test period. By consecutive tape stripping, monitored by measurements of transepidermal water loss and confirmed by histological examination of skin biopsies, 10 tape strippings were found to remove the stratum corneum completely. For assessment of the model, (14)C...

  8. Greenland Ice Sheet Mass Balance

    Science.gov (United States)

    Reeh, N.

    1984-01-01

    Mass balance equation for glaciers; areal distribution and ice volumes; estimates of actual mass balance; loss by calving of icebergs; hydrological budget for Greenland; and temporal variations of Greenland mass balance are examined.

  9. High-resolution modeling of coastal freshwater discharge and glacier mass balance in the Gulf of Alaska watershed

    Science.gov (United States)

    Beamer, J. P.; Hill, D. F.; Arendt, A.; Liston, G. E.

    2016-05-01

    A comprehensive study of the Gulf of Alaska (GOA) drainage basin was carried out to improve understanding of the coastal freshwater discharge (FWD) and glacier volume loss (GVL). Hydrologic processes during the period 1980-2014 were modeled using a suite of physically based, spatially distributed weather, energy-balance snow/ice melt, soil water balance, and runoff routing models at a high-resolution (1 km horizontal grid; daily time step). Meteorological forcing was provided by the North American Regional Reanalysis (NARR), Modern Era Retrospective Analysis for Research and Applications (MERRA), and Climate Forecast System Reanalysis (CFSR) data sets. Streamflow and glacier mass balance modeled using MERRA and CFSR compared well with observations in four watersheds used for calibration in the study domain. However, only CFSR produced regional seasonal and long-term trends in water balance that compared favorably with independent Gravity Recovery and Climate Experiment (GRACE) and airborne altimetry data. Mean annual runoff using CFSR was 760 km3 yr-1, 8% of which was derived from the long-term removal of stored water from glaciers (glacier volume loss). The annual runoff from CFSR was partitioned into 63% snowmelt, 17% glacier ice melt, and 20% rainfall. Glacier runoff, taken as the sum of rainfall, snow, and ice melt occurring each season on glacier surfaces, was 38% of the total seasonal runoff, with the remaining runoff sourced from nonglacier surfaces. Our simulations suggests that existing GRACE solutions, previously reported to represent glacier mass balance alone, are actually measuring the full water budget of land and ice surfaces.

  10. A new, high-resolution surface mass balance map of Antarctica (1979-2010) based on regional atmospheric climate modeling

    Science.gov (United States)

    Lenaerts, J. T. M.; van den Broeke, M. R.; van de Berg, W. J.; van Meijgaard, E.; Kuipers Munneke, P.

    2012-02-01

    A new, high resolution (27 km) surface mass balance (SMB) map of the Antarctic ice sheet is presented, based on output of a regional atmospheric climate model that includes snowdrift physics and is forced by the most recent reanalysis data from the European Centre for Medium-Range Weather Forecasts (ECMWF), ERA-Interim (1979-2010). The SMB map confirms high accumulation zones in the western Antarctic Peninsula (>1500 mm y-1) and coastal West Antarctica (>1000 mm y-1), and shows low SMB values in large parts of the interior ice sheet (181 Gt y-1. Snowfall shows modest interannual variability (σ = 114 Gt y-1), but a pronounced seasonal cycle (σ = 30 Gt mo-1), with a winter maximum. The main ablation process is drifting snow sublimation, which also peaks in winter but with little interannual variability (σ = 9 Gt y-1).

  11. Modeling and experimental validation of water mass balance in a PEM fuel cell stack

    DEFF Research Database (Denmark)

    Liso, Vincenzo; Araya, Samuel Simon; Olesen, Anders Christian

    2016-01-01

    incorporates all the essential fundamental physical and electrochemical processes occurring in the membrane electrolyte and considers the water adsorption/desorption phenomena in the membrane. The effect of diffusivity model, surface roughness and water content driving force is considered. The model...... transport when membrane absorption/ desorption is considered in the model. The model becomes useful in system modelling when studying fuel cells in dynamic conditions....

  12. Assessing modeled Greenland surface mass balance in the GISS Model E2 and its sensitivity to surface albedo

    Science.gov (United States)

    Alexander, Patrick; LeGrande, Allegra N.; Koenig, Lora S.; Tedesco, Marco; Moustafa, Samiah E.; Ivanoff, Alvaro; Fischer, Robert P.; Fettweis, Xavier

    2016-04-01

    The surface mass balance (SMB) of the Greenland Ice Sheet (GrIS) plays an important role in global sea level change. Regional Climate Models (RCMs) such as the Modèle Atmosphérique Régionale (MAR) have been employed at high spatial resolution with relatively complex physics to simulate ice sheet SMB. Global climate models (GCMs) incorporate less sophisticated physical schemes and provide outputs at a lower spatial resolution, but have the advantage of modeling the interaction between different components of the earth's oceans, climate, and land surface at a global scale. Improving the ability of GCMs to represent ice sheet SMB is important for making predictions of future changes in global sea level. With the ultimate goal of improving SMB simulated by the Goddard Institute for Space Studies (GISS) Model E2 GCM, we compare simulated GrIS SMB against the outputs of the MAR model and radar-derived estimates of snow accumulation. In order to reproduce present-day climate variability in the Model E2 simulation, winds are constrained to match the reanalysis datasets used to force MAR at the lateral boundaries. We conduct a preliminary assessment of the sensitivity of the simulated Model E2 SMB to surface albedo, a parameter that is known to strongly influence SMB. Model E2 albedo is set to a fixed value of 0.8 over the entire ice sheet in the initial configuration of the model (control case). We adjust this fixed value in an ensemble of simulations over a range of 0.4 to 0.8 (roughly the range of observed summer GrIS albedo values) to examine the sensitivity of ice-sheet-wide SMB to albedo. We prescribe albedo from the Moderate Resolution Imaging Spectroradiometer (MODIS) MCD43A3 v6 to examine the impact of a more realistic spatial and temporal variations in albedo. An age-dependent snow albedo parameterization is applied, and its impact on SMB relative to observations and the RCM is assessed.

  13. A regional mass balance model based on total ammoniacal nitrogen for estimating ammonia emissions from beef cattle in Alberta Canada

    Science.gov (United States)

    Chai, Lilong; Kröbel, Roland; Janzen, H. Henry; Beauchemin, Karen A.; McGinn, Sean M.; Bittman, Shabtai; Atia, Atta; Edeogu, Ike; MacDonald, Douglas; Dong, Ruilan

    2014-08-01

    Animal feeding operations are primary contributors of anthropogenic ammonia (NH3) emissions in North America and Europe. Mathematical modeling of NH3 volatilization from each stage of livestock manure management allows comprehensive quantitative estimates of emission sources and nutrient losses. A regionally-specific mass balance model based on total ammoniacal nitrogen (TAN) content in animal manure was developed for estimating NH3 emissions from beef farming operations in western Canada. Total N excretion in urine and feces was estimated from animal diet composition, feed dry matter intake and N utilization for beef cattle categories and production stages. Mineralization of organic N, immobilization of TAN, nitrification, and denitrification of N compounds in manure, were incorporated into the model to account for quantities of TAN at each stage of manure handling. Ammonia emission factors were specified for different animal housing (feedlots, barns), grazing, manure storage (including composting and stockpiling) and land spreading (tilled and untilled land), and were modified for temperature. The model computed NH3 emissions from all beef cattle sub-classes including cows, calves, breeding bulls, steers for slaughter, and heifers for slaughter and replacement. Estimated NH3 emissions were about 1.11 × 105 Mg NH3 in Alberta in 2006, with a mean of 18.5 kg animal-1 yr-1 (15.2 kg NH3-N animal-1 yr-1) which is 23.5% of the annual N intake of beef cattle (64.7 kg animal-1 yr-1). The percentage of N intake volatilized as NH3-N was 50% for steers and heifers for slaughter, and between 11 and 14% for all other categories. Steers and heifers for slaughter were the two largest contributors (3.5 × 104 and 3.9 × 104 Mg, respectively) at 31.5 and 32.7% of total NH3 emissions because most growing animals were finished in feedlots. Animal housing and grazing contributed roughly 63% of the total NH3 emissions (feedlots, barns and pastures contributed 54.4, 0.2 and 8.1% of

  14. Modelling the climate and surface mass balance of polar ice sheets using RACMO2 - Part 1: Greenland (1958-2016)

    Science.gov (United States)

    Noël, Brice; van de Berg, Willem Jan; Melchior van Wessem, J.; van Meijgaard, Erik; van As, Dirk; Lenaerts, Jan T. M.; Lhermitte, Stef; Kuipers Munneke, Peter; Smeets, C. J. P. Paul; van Ulft, Lambertus H.; van de Wal, Roderik S. W.; van den Broeke, Michiel R.

    2018-03-01

    We evaluate modelled Greenland ice sheet (GrIS) near-surface climate, surface energy balance (SEB) and surface mass balance (SMB) from the updated regional climate model RACMO2 (1958-2016). The new model version, referred to as RACMO2.3p2, incorporates updated glacier outlines, topography and ice albedo fields. Parameters in the cloud scheme governing the conversion of cloud condensate into precipitation have been tuned to correct inland snowfall underestimation: snow properties are modified to reduce drifting snow and melt production in the ice sheet percolation zone. The ice albedo prescribed in the updated model is lower at the ice sheet margins, increasing ice melt locally. RACMO2.3p2 shows good agreement compared to in situ meteorological data and point SEB/SMB measurements, and better resolves the spatial patterns and temporal variability of SMB compared with the previous model version, notably in the north-east, south-east and along the K-transect in south-western Greenland. This new model version provides updated, high-resolution gridded fields of the GrIS present-day climate and SMB, and will be used for projections of the GrIS climate and SMB in response to a future climate scenario in a forthcoming study.

  15. Estimating the Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    NARCIS (Netherlands)

    Fettweis, X.; Franco, B.; Tedesco, M.; van Angelen, J.H.|info:eu-repo/dai/nl/325922470; Lenaerts, J.T.M.|info:eu-repo/dai/nl/314850163; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; Gallée, H.

    2013-01-01

    To estimate the sea level rise (SLR) originating from changes in surface mass balance (SMB) of the Greenland ice sheet (GrIS), we present 21st century climate projections obtained with the regional climate model MAR (Mod`ele Atmosph´erique R´egional), forced by output of three CMIP5 (Coupled Model

  16. A Mass Balance Model for Designing Green Roof Systems that Incorporate a Cistern for Re-Use

    Directory of Open Access Journals (Sweden)

    Manoj Chopra

    2012-11-01

    Full Text Available Green roofs, which have been used for several decades in many parts of the world, offer a unique and sustainable approach to stormwater management. Within this paper, evidence is presented on water retention for an irrigated green roof system. The presented green roof design results in a water retention volume on site. A first principle mass balance computer model is introduced to assist with the design of these green roof systems which incorporate a cistern to capture and reuse runoff waters for irrigation of the green roof. The model is used to estimate yearly stormwater retention volume for different cistern storage volumes. Additionally, the Blaney and Criddle equation is evaluated for estimation of monthly evapotranspiration rates for irrigated systems and incorporated into the model. This is done so evapotranspiration rates can be calculated for regions where historical data does not exist, allowing the model to be used anywhere historical weather data are available. This model is developed and discussed within this paper as well as compared to experimental results.

  17. Comparing Mass Balance and Adjoint-Based 4D-VAR Methods for Inverse Modeling of Nitrogen Dioxide Columns for Nitrogen Oxide Emissions

    Science.gov (United States)

    Cooper, M.; Martin, R.; Henze, D. K.

    2016-12-01

    Nitrogen oxide (NOx ≡ NO + NO2) emission inventories can be improved through top-down constraints provided by inverse modeling of observed nitrogen dioxide (NO2) columns. Here we compare two methods of inverse modeling for emissions of NOx from synthetic NO2 columns generated from known emissions using the GEOS-Chem chemical transport model and its adjoint. We treat the adjoint-based 4D-VAR approach for estimating top-down emissions as a benchmark against which to evaluate variations on the mass balance method. We find that the standard mass balance algorithm can be improved by using an iterative process and using finite difference to calculate the local sensitivity of a change in NO2 columns to a change in emissions, resulting in a factor of two reduction in inversion error. In a simplified case study to recover local emission perturbations, horizontal smearing effects due to NOx transport were better resolved by the adjoint-based approach than by mass balance. For more complex emission changes that reflect real world scenarios, the iterative finite difference mass balance and adjoint methods produce similar top-down inventories when inverting hourly synthetic observations, both reducing the a priori error by factors of 3-4. Inversions of data sets that simulate satellite observations from low Earth and geostationary orbits also indicate that both the mass balance and adjoint inversions produce similar results, reducing a priori error by a factor of 3. As the iterative finite difference mass balance method provides similar accuracy as the adjoint-based 4D-VAR method, it offers the ability to efficiently estimate top-down emissions using models that do not have an adjoint.

  18. A Mass Balance Model of Lyell and Maclure Glaciers in Yosemite National Park

    Science.gov (United States)

    Mendoza, K. A.; Stock, G. M.; Sharping, J. E.

    2015-12-01

    The Lyell and Maclure glaciers, two historically important glaciers of Yosemite National Park, have been rapidly retreating since the late 1800's. I attempted to quantify the water balance of two basins containing these glaciers. Water inputs were calculated by applying snow pillow data and two precipitation vs. elevation slope models. Water outputs consisted of a simplified evapotranspiration model and stream runoff data. Fifty-six linear combinations of precipitation and evaporation were used to develop water balance models. Most of these models predicted melt rates from the two glaciers outside of empirical observations. However, both the Lyell Glacier Basin and the Lyell Fork of the Tuolumne Basin water balance spreads had notable Kolmogorov-Smirnov test statistics: Lyell Glacier with p = 0.34 for 2013 and p = 0.37 for 2014, and Lyell Fork with p = 0.45 for 2009. The basin containing Lyell Glacier had a water balance spread of between -1,105×10^3m^3 and +58×10^3m^3+ (interquartile range) with a mean of -564×10^3m^3 for the 2013 hydrologic year, and between -1,137×10^3m^3 and +21×10^3m^3 (interquartile range) with a mean of-583×10^3m^3 for the 2014 hydrologic year. The Lyell fork of the Tuolumne basin containing both Lyell and Maclure Glaciers had a water balance spread of between-14,350×10^3m^3 and +7,454×10^3m^3 (interquartile range) with a mean of -2,426×10^3m^3 for the 2009 hydrologic year. Variations observed in water balance models for Lyell Glacier in this study are an order of magnitude larger than the expected melt signal, and two orders of magnitude for the Lyell Fork of the Tuolumne water balance models.

  19. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    2006-04-28

    Apr 28, 2006 ... AS activated sludge. ASM1,2,3 Activated Sludge Models No. 1, 2 or 3. BEPR biological excess phosphorus removal. BNR biological nutrient removal ... PS primary sludge. PST primary settling tank. Q flow. R hydraulic retention time or sludge age for anaerobic digester. RBCOD readily biodegradable COD.

  20. Estimating personal exposures based on mass balance material usage rates: validation of a ventilation model in a spray paint booth.

    Science.gov (United States)

    Taylor, Jon R; O'Shaughnessy, Patrick T; Reynolds, Stephen J

    2004-04-01

    The goal of this research was to evaluate an estimating model (box model) with direct measurements of contaminants in an industrial spray painting operation. The research involved a dilution ventilation efficiency experiment that was devised to estimate the effective ventilation rate, sampling for organic compounds (xylene, ethyl benzene, methyl ethyl ketone, and methyl isobutyl ketone) in a paint booth, and simultaneously measuring the mass usage of these compounds during painting operations in order to compare measured with predicted concentrations. The results of the dilution ventilation experiment indicated that channeling of air was occurring due to a high ventilation rate in the painting area. The results of the mass balance usage and air sampling comparisons indicated that predicted concentrations were within the 95% upper/lower confidence interval about the geometric mean in 14 out of 16 area samples taken within the paint booth (87.5%). Correlation analysis between predicted concentrations and area, personal, and exhaust stack concentrations were strongest with exhaust (r = 0.923). Correlations with personal concentrations were not as strong (r = 0.828), and the area concentrations were even less strong (0.757). In conclusion, the box model does appear to be a useful additional tool for estimating worker exposures. However, the characteristics of any particular ventilation system must be understood before modeling is conducted.

  1. A model for the oceanic mass balance of rhenium and implications for the extent of Proterozoic ocean anoxia

    Science.gov (United States)

    Sheen, Alex I.; Kendall, Brian; Reinhard, Christopher T.; Creaser, Robert A.; Lyons, Timothy W.; Bekker, Andrey; Poulton, Simon W.; Anbar, Ariel D.

    2018-04-01

    Emerging geochemical evidence suggests that the atmosphere-ocean system underwent a significant decrease in O2 content following the Great Oxidation Event (GOE), leading to a mid-Proterozoic ocean (ca. 2.0-0.8 Ga) with oxygenated surface waters and predominantly anoxic deep waters. The extent of mid-Proterozoic seafloor anoxia has been recently estimated using mass-balance models based on molybdenum (Mo), uranium (U), and chromium (Cr) enrichments in organic-rich mudrocks (ORM). Here, we use a temporal compilation of concentrations for the redox-sensitive trace metal rhenium (Re) in ORM to provide an independent constraint on the global extent of mid-Proterozoic ocean anoxia and as a tool for more generally exploring how the marine geochemical cycle of Re has changed through time. The compilation reveals that mid-Proterozoic ORM are dominated by low Re concentrations that overall are only mildly higher than those of Archean ORM and significantly lower than many ORM deposited during the ca. 2.22-2.06 Ga Lomagundi Event and during the Phanerozoic Eon. These temporal trends are consistent with a decrease in the oceanic Re inventory in response to an expansion of anoxia after an interval of increased oxygenation during the Lomagundi Event. Mass-balance modeling of the marine Re geochemical cycle indicates that the mid-Proterozoic ORM with low Re enrichments are consistent with extensive seafloor anoxia. Beyond this agreement, these new data bring added value because Re, like the other metals, responds generally to low-oxygen conditions but has its own distinct sensitivity to the varying environmental controls. Thus, we can broaden our capacity to infer nuanced spatiotemporal patterns in ancient redox landscapes. For example, despite the still small number of data, some mid-Proterozoic ORM units have higher Re enrichments that may reflect a larger oceanic Re inventory during transient episodes of ocean oxygenation. An improved understanding of the modern oceanic Re

  2. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    Directory of Open Access Journals (Sweden)

    J. H. van Angelen

    2012-10-01

    Full Text Available We present a sensitivity study of the surface mass balance (SMB of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover, solar zenith angle and black carbon concentration. For the control experiment the overestimation of absorbed shortwave radiation (+6% at the K-transect (west Greenland for the period 2004–2009 is considerably reduced compared to the previous density-dependent albedo scheme (+22%. To simulate realistic snow albedo values, a small concentration of black carbon is needed, which has strongest impact on melt in the accumulation area. A background ice albedo field derived from MODIS imagery improves the agreement between the modeled and observed SMB gradient along the K-transect. The effect of enhanced meltwater retention and refreezing is a decrease of the albedo due to an increase in snow grain size. As a secondary effect of refreezing the snowpack is heated, enhancing melt and further lowering the albedo. Especially in a warmer climate this process is important, since it reduces the refreezing potential of the firn layer that covers the Greenland Ice Sheet.

  3. Evaluation of optimization methods for solving the receptor model for chemical mass balance

    Directory of Open Access Journals (Sweden)

    Anu N.

    2015-01-01

    Full Text Available Balance (CMB model has been extensively used in order to determine source contribution for particulate matters (size diameters less than 10 μm and 2.5 μm in the air quality analysis. A comparison of the source contribution estimated from the three CMB models (CMB 8.2, CMB-fmincon and CMB-GA have been carried out through optimization techniques such as ‘fmincon’ (CMB-fmincon and genetic algorithm (CMB-GA using MATLAB. The proposed approach has been validated using San Joaquin Valley Air Quality Study (SJVAQS California Fresno and Bakersfield PM10 and PM2.5 followed with Oregon PM10 data. The source contribution estimated from CMB-GA was better in source interpretation in comparison with CMB8.2 and CMB-fmincon. The performance accuracy of three CMB approaches were validated using R-square, reduced chi-square and percentage mass tests. The R-square (0.90, 0.67 and 0.81, 0.83, Chi-square (0.36, 0.66 and 0.65, 0.43 and percentage mass (67.36 %, 55.03 % and 94.24 %, 74.85 % of CMB-GA showed high correlation for PM10, PM2.5 Fresno and Bakersfield data respectively. To make a complete decision, the proposed methodology has been bench marked with Portland, Oregon PM10 data with best fit with R2 (0.99, Chi-square (1.6 and percentage mass (94.4 % from CMB-GA. Therefore, the study revealed that CMB with genetic algorithm optimization method holds better stability in determining the source contributions.

  4. Th isotopes in the Santa Monica basin: temporal variation, long-term mass balance and model rate constants

    International Nuclear Information System (INIS)

    Huh, Chih-An

    1995-01-01

    Distribution and flux of 234 Th, 232 Th and 230 Th in the water column of central Santa Monica basin observed over a period of seven years show seasonal and interannual variabilities. A steady-state model is applied to the integrated data to calculate long term average flux and model rate constants of Th isotopes. Mass balance calculations show that the basin acts like a closed system for short-lived 234 Th, but not for the long-lived isotopes 230 Th and 232 Th. Most 230 Th in the basin is transported from elsewhere. Of the incoming Th, 40-55% of the 230 Th and 14-26% of the 232 Th enter the surface water in dissolved form. In the upper 100m, the residence time of dissolved Th with respect to adsorption onto suspended particulates, 70-80 days, is about one order of magnitude higher than the residence time of suspended particles with respect to aggregation into sinking particles, 7-10 days. (author)

  5. A holistic approach combining factor analysis, positive matrix factorization, and chemical mass balance applied to receptor modeling.

    Science.gov (United States)

    Selvaraju, N; Pushpavanam, S; Anu, N

    2013-12-01

    Rapid urbanization and population growth resulted in severe deterioration of air quality in most of the major cities in India. Therefore, it is essential to ascertain the contribution of various sources of air pollution to enable us to determine effective control policies. The present work focuses on the holistic approach of combining factor analysis (FA), positive matrix factorization (PMF), and chemical mass balance (CMB) for receptor modeling in order to identify the sources and their contributions in air quality studies. Insight from the emission inventory was used to remove subjectivity in source identification. Each approach has its own limitations. Factor analysis can identify qualitatively a minimal set of important factors which can account for the variations in the measured data. This step uses information from emission inventory to qualitatively match source profiles with factor loadings. This signifies the identification of dominant sources through factors. PMF gives source profiles and source contributions from the entire receptor data matrix. The data from FA is applied for rank reduction in PMF. Whenever multiple solutions exist, emission inventory identifies source profiles uniquely, so that they have a physical relevance. CMB identifies the source contributions obtained from FA and PMF. The novel approach proposed here overcomes the limitations of the individual methods in a synergistic way. The adopted methodology is found valid for a synthetic data and also the data of field study.

  6. Models for mirror symmetry breaking via β-sheet-controlled copolymerization: (i) mass balance and (ii) probabilistic treatment.

    Science.gov (United States)

    Blanco, Celia; Hochberg, David

    2012-12-06

    Experimental mechanisms that yield the growth of homochiral copolymers over their heterochiral counterparts have been advocated by Lahav and co-workers. These chiral amplification mechanisms proceed through racemic β-sheet-controlled polymerization operative in both surface crystallites as well as in solution. We develop two complementary theoretical models for these template-induced desymmetrization processes leading to multicomponent homochiral copolymers. First, assuming reversible β-sheet formation, the equilibrium between the free monomer pool and the polymer strand within the template is assumed. This yields coupled nonlinear mass balance equations whose solutions are used to calculate enantiomeric excesses and average lengths of the homochiral chains formed. The second approach is a probabilistic treatment based on random polymerization. The occlusion probabilities depend on the polymerization activation energies for each monomer species and are proportional to the concentrations of the monomers in solution in the constant pool approximation. The monomer occlusion probabilities are represented geometrically in terms of unit simplexes from which conditions for maximizing or minimizing the likelihood for mirror symmetry breaking can be determined.

  7. On the Utilization of Ice Flow Models and Uncertainty Quantification to Interpret the Impact of Surface Radiation Budget Errors on Estimates of Greenland Ice Sheet Surface Mass Balance and Regional Estimates of Mass Balance

    Science.gov (United States)

    Schlegel, N.; Larour, E. Y.; Gardner, A. S.; Lang, C.; Miller, C. E.; van den Broeke, M. R.

    2016-12-01

    How Greenland ice flow may respond to future increases in surface runoff and to increases in the frequency of extreme melt events is unclear, as it requires detailed comprehension of Greenland surface climate and the ice sheet's sensitivity to associated uncertainties. With established uncertainty quantification tools run within the framework of Ice Sheet System Model (ISSM), we conduct decadal-scale forward modeling experiments to 1) quantify the spatial resolution needed to effectively force distinct components of the surface radiation budget, and subsequently surface mass balance (SMB), in various regions of the ice sheet and 2) determine the dynamic response of Greenland ice flow to variations in components of the net radiation budget. The Glacier Energy and Mass Balance (GEMB) software is a column surface model (1-D) that has recently been embedded as a module within ISSM. Using the ISSM-GEMB framework, we perform sensitivity analyses to determine how perturbations in various components of the surface radiation budget affect model output; these model experiments allow us predict where and on what spatial scale the ice sheet is likely to dynamically respond to changes in these parameters. Preliminary results suggest that SMB should be forced at at least a resolution of 23 km to properly capture dynamic ice response. In addition, Monte-Carlo style sampling analyses reveals that the areas with the largest uncertainty in mass flux are located near the equilibrium line altitude (ELA), upstream of major outlet glaciers in the North and West of the ice sheet. Sensitivity analysis indicates that these areas are also the most vulnerable on the ice sheet to persistent, far-field shifts in SMB, suggesting that continued warming, and upstream shift in the ELA, are likely to result in increased velocities, and consequentially SMB-induced thinning upstream of major outlet glaciers. Here, we extend our investigation to consider various components of the surface radiation

  8. Modelling the dynamics of fish contamination by Chernobyl radiocaesium: an analytical solution based on potassium mass balance

    International Nuclear Information System (INIS)

    Koulikov, Alexei O.; Meili, Markus

    2003-01-01

    After the sudden fallout from the Chernobyl nuclear accident in 1986, activities and bioaccumulation factors of radiocaesium ( 137 Cs, 134 Cs) fluctuated strongly over several years before reaching quasi-equilibrium, with patterns significantly differing among organisms. To model these dynamic relaxation processes based on ecological mechanisms we developed mass balance equations for 137 Cs in an aquatic food chain on the following basis: (a) potassium acts as a biogeochemical analogue ('carrier') of caesium; (b) the concentration of potassium in fish and other animals is effectively constant; (c) the main source of potassium in freshwater fish is the dietary uptake. The model is applicable to linear food chains of any number of trophic levels, while solutions evaluated here include the following food chain compartments: water, invertebrates (fish food), non-piscivorous fish, and piscivorous fish. The activity concentration in the water, which is considered as the secondary source of 137 Cs, is described by multi-component first-order decay function, although two components (fast and slow) are often sufficient to provide agreement with empirical data. In every compartment the turnover rate of caesium is considered as a constant over time. The analytical solution of the model equations describes the 137 Cs activity concentration in every compartment as a series of exponential functions, of which some are derived from the source pattern, and the others determined by the 137 Cs turnover rate in each food chain compartment. The model was tested with post-Chernobyl data from several long-term studies in lakes and provided a reasonable description of important radioecological aspects

  9. A hybrid source apportionment strategy using positive matrix factorization (PMF) and molecular marker chemical mass balance (MM-CMB) models.

    Science.gov (United States)

    Lu, Zhaojie; Liu, Qingyang; Xiong, Ying; Huang, Fan; Zhou, Jiabin; Schauer, James J

    2018-03-10

    The molecular marker-based chemical mass balance (MM-CMB) method performs well in the source apportionment of organic carbon (OC) but has some difficulty with contributions from primary sources to inorganic secondary ions when apportioning PM 2.5 (particles with aerodynamic diameter of 2.5 μm or less) sources. Positive matrix factorization (PMF) with the input of inorganic and organic tracers can properly estimate the contributions of primary and secondary sources to inorganic secondary ions; however, PMF is unable to apportion several PM 2.5 sources with large fractions of organic carbon and few elemental compositions. In this study regarding data collected in 2011 and 2012 at three sites in Wuhan, China, the MM-CMB model was used to apportion OC in the PM 2.5, and the PMF model was used to apportion the inorganic ions (sulfate, nitrate, and ammonia), dust, and EC. The source contributions of PM 2.5 were estimated by reconstructing masses of bulk chemical components that had been apportioned to real-world sources using suitable source apportionment methods. Good performance of this hybrid source apportionment strategy was observed with ten resolved factors, explaining 70-80% of measured PM 2.5 mass on average. The hybrid strategy takes the advantages of both models in PM 2.5 source apportionment and yields unique source apportionment results for PM 2.5 bulk chemical components, which could provide new information for optimizing air quality regulations for the emission abatement of target PM mass and compositions for countries around the world. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Use of geomorphic, hydrologic, and nitrogen mass balance data to model ecosystem nitrate retention in tidal freshwater wetlands

    Directory of Open Access Journals (Sweden)

    E. D. Seldomridge

    2012-07-01

    Full Text Available Geomorphic characteristics have been used as scaling parameters to predict water and other fluxes in many systems. In this study, we combined geomorphic analysis with in-situ mass balance studies of nitrate retention (NR to evaluate which geomorphic scaling parameters best predicted NR in a tidal freshwater wetland ecosystem. Geomorphic characteristics were measured for 267 individual marshes that constitute the freshwater tidal wetland ecosystem of the Patuxent River, Maryland. Nitrate retention was determined from mass balance measurements conducted at the inlets of marshes of varying size (671, 5705, and 536 873 m2 over a period of several years. Mass balance measurements indicate that NR is proportional to total water flux over the tidal cycle. Relationships between estimated tidal prism (calculated water volume for spring tides and various geomorphic parameters (marsh area, total channel length, and inlet width were defined using measurements from air photos and compared to field data. From these data, NR equations were determined for each geomorphic parameter, and used to estimate NR for all marshes in the ecosystem for a reference spring (high tide. The resulting ecosystem NR estimates were evaluated for (a accuracy and completeness of geomorphic data, (b relationship between the geomorphic parameters and hydrologic flux, and (c the ability to adapt the geomorphic parameter to varying tidal conditions. This analysis indicated that inlet width data were the most complete and provided the best estimate of ecosystem nitrate retention. Predictions based on marsh area were significantly lower than the inlet width-based predictions. Cumulative probability distributions of nitrate retention indicate that the largest 3–4% of the marshes retained half of the total nitrate for the ecosystem.

  11. Moisture and drug solid-state monitoring during a continuous drying process using empirical and mass balance models

    DEFF Research Database (Denmark)

    Fonteyne, Margot; Gildemyn, Delphine; Peeters, Elisabeth

    2014-01-01

    of Process Analytical Technology (PAT) tools (Raman and NIR spectroscopy) and a mass balance approach. The six-segmented fluid bed drying system being part of a fully continuous from-powder-to-tablet production line (ConsiGma™-25) was used for this study. A theophylline:lactose:PVP (30:67.5:2.5) blend......, the different size fractions of the dried granules obtained during different experiments (fines, yield and oversized granules) were compared separately, revealing differences in both solid state of theophylline and moisture content between the different granule size fractions. © 2014 Elsevier B.V. All rights...... reserved...

  12. The effect of adjusting model inputs to achieve mass balance on time-dynamic simulations in a food-web model of Lake Huron

    Science.gov (United States)

    Langseth, Brian J.; Jones, Michael L.; Riley, Stephen C.

    2014-01-01

    Ecopath with Ecosim (EwE) is a widely used modeling tool in fishery research and management. Ecopath requires a mass-balanced snapshot of a food web at a particular point in time, which Ecosim then uses to simulate changes in biomass over time. Initial inputs to Ecopath, including estimates for biomasses, production to biomass ratios, consumption to biomass ratios, and diets, rarely produce mass balance, and thus ad hoc changes to inputs are required to balance the model. There has been little previous research of whether ad hoc changes to achieve mass balance affect Ecosim simulations. We constructed an EwE model for the offshore community of Lake Huron, and balanced the model using four contrasting but realistic methods. The four balancing methods were based on two contrasting approaches; in the first approach, production of unbalanced groups was increased by increasing either biomass or the production to biomass ratio, while in the second approach, consumption of predators on unbalanced groups was decreased by decreasing either biomass or the consumption to biomass ratio. We compared six simulation scenarios based on three alternative assumptions about the extent to which mortality rates of prey can change in response to changes in predator biomass (i.e., vulnerabilities) under perturbations to either fishing mortality or environmental production. Changes in simulated biomass values over time were used in a principal components analysis to assess the comparative effect of balancing method, vulnerabilities, and perturbation types. Vulnerabilities explained the most variation in biomass, followed by the type of perturbation. Choice of balancing method explained little of the overall variation in biomass. Under scenarios where changes in predator biomass caused large changes in mortality rates of prey (i.e., high vulnerabilities), variation in biomass was greater than when changes in predator biomass caused only small changes in mortality rates of prey (i.e., low

  13. Reconstruction of the 1979–2006 Greenland ice sheet surface mass balance using the regional climate model MAR

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2007-10-01

    Full Text Available Results from a 28-year simulation (1979–2006 over the Greenland ice sheet (GrIS reveal an increase of solid precipitation (+0.4±2.5 km3 yr−2 and run-off (+7.9±3.3 km3 yr−2 of surface meltwater. The net effect of these competing factors is a significant Surface Mass Balance (SMB loss of −7.2±5.1 km3 yr−2. The contribution of changes in the net water vapour flux (+0.02±0.09 km3 yr−2 and rainfall (+0.2±0.2 km3 yr−2 to the SMB variability is negligible. The meltwater supply has increased because the GrIS surface has been warming up +2.4°C since 1979. Sensible heat flux, latent heat flux and net solar radiation have not varied significantly over the last three decades. However, the simulated downward infrared flux has increased by 9.3 W m−2 since 1979. The natural climate variability (e.g. the North Atlantic Oscillation does not explain these changes. The recent global warming, due to the greenhouse gas concentration increase induced by human activities, could be a cause of these changes. The doubling of surface meltwater flux into the ocean over the period 1979–2006 suggests that the overall ice sheet mass balance has been increasingly negative, given the likely meltwater-induced acceleration of outlet glaciers. This study suggests that increased melting overshadows over an increased accumulation in a warming scenario and that the GrIS is likely to keep losing mass in the future. An enduring GrIS melting will probably affect in the future an certain effect on the stability of the thermohaline circulation and the global sea level rise.

  14. Relative performance of empirical and physical models in assessing the seasonal and annual glacier surface mass balance of Saint-Sorlin Glacier (French Alps

    Directory of Open Access Journals (Sweden)

    M. Réveillet

    2018-04-01

    Full Text Available This study focuses on simulations of the seasonal and annual surface mass balance (SMB of Saint-Sorlin Glacier (French Alps for the period 1996–2015 using the detailed SURFEX/ISBA-Crocus snowpack model. The model is forced by SAFRAN meteorological reanalysis data, adjusted with automatic weather station (AWS measurements to ensure that simulations of all the energy balance components, in particular turbulent fluxes, are accurately represented with respect to the measured energy balance. Results indicate good model performance for the simulation of summer SMB when using meteorological forcing adjusted with in situ measurements. Model performance however strongly decreases without in situ meteorological measurements. The sensitivity of the model to meteorological forcing indicates a strong sensitivity to wind speed, higher than the sensitivity to ice albedo. Compared to an empirical approach, the model exhibited better performance for simulations of snow and firn melting in the accumulation area and similar performance in the ablation area when forced with meteorological data adjusted with nearby AWS measurements. When such measurements were not available close to the glacier, the empirical model performed better. Our results suggest that simulations of the evolution of future mass balance using an energy balance model require very accurate meteorological data. Given the uncertainties in the temporal evolution of the relevant meteorological variables and glacier surface properties in the future, empirical approaches based on temperature and precipitation could be more appropriate for simulations of glaciers in the future.

  15. Relative performance of empirical and physical models in assessing the seasonal and annual glacier surface mass balance of Saint-Sorlin Glacier (French Alps)

    Science.gov (United States)

    Réveillet, Marion; Six, Delphine; Vincent, Christian; Rabatel, Antoine; Dumont, Marie; Lafaysse, Matthieu; Morin, Samuel; Vionnet, Vincent; Litt, Maxime

    2018-04-01

    This study focuses on simulations of the seasonal and annual surface mass balance (SMB) of Saint-Sorlin Glacier (French Alps) for the period 1996-2015 using the detailed SURFEX/ISBA-Crocus snowpack model. The model is forced by SAFRAN meteorological reanalysis data, adjusted with automatic weather station (AWS) measurements to ensure that simulations of all the energy balance components, in particular turbulent fluxes, are accurately represented with respect to the measured energy balance. Results indicate good model performance for the simulation of summer SMB when using meteorological forcing adjusted with in situ measurements. Model performance however strongly decreases without in situ meteorological measurements. The sensitivity of the model to meteorological forcing indicates a strong sensitivity to wind speed, higher than the sensitivity to ice albedo. Compared to an empirical approach, the model exhibited better performance for simulations of snow and firn melting in the accumulation area and similar performance in the ablation area when forced with meteorological data adjusted with nearby AWS measurements. When such measurements were not available close to the glacier, the empirical model performed better. Our results suggest that simulations of the evolution of future mass balance using an energy balance model require very accurate meteorological data. Given the uncertainties in the temporal evolution of the relevant meteorological variables and glacier surface properties in the future, empirical approaches based on temperature and precipitation could be more appropriate for simulations of glaciers in the future.

  16. Using plot experiments to test the validity of mass balance models employed to estimate soil redistribution rates from 137Cs and 210Pbex measurements

    International Nuclear Information System (INIS)

    Porto, Paolo; Walling, Des E.

    2012-01-01

    Information on rates of soil loss from agricultural land is a key requirement for assessing both on-site soil degradation and potential off-site sediment problems. Many models and prediction procedures have been developed to estimate rates of soil loss and soil redistribution as a function of the local topography, hydrometeorology, soil type and land management, but empirical data remain essential for validating and calibrating such models and prediction procedures. Direct measurements using erosion plots are, however, costly and the results obtained relate to a small enclosed area, which may not be representative of the wider landscape. In recent years, the use of fallout radionuclides and more particularly caesium-137 ( 137 Cs) and excess lead-210 ( 210 Pb ex ) has been shown to provide a very effective means of documenting rates of soil loss and soil and sediment redistribution in the landscape. Several of the assumptions associated with the theoretical conversion models used with such measurements remain essentially unvalidated. This contribution describes the results of a measurement programme involving five experimental plots located in southern Italy, aimed at validating several of the basic assumptions commonly associated with the use of mass balance models for estimating rates of soil redistribution on cultivated land from 137 Cs and 210 Pb ex measurements. Overall, the results confirm the general validity of these assumptions and the importance of taking account of the fate of fresh fallout. However, further work is required to validate the conversion models employed in using fallout radionuclide measurements to document soil redistribution in the landscape and this could usefully direct attention to different environments and to the validation of the final estimates of soil redistribution rate as well as the assumptions of the models employed. - Highlights: ► Soil erosion is an important threat to the long-term sustainability of agriculture.

  17. A mass balance model to estimate the rate of composting, methane oxidation and anaerobic digestion in soil covers and shallow waste layers.

    Science.gov (United States)

    Rafiee, Reza; Obersky, Lizanne; Xie, Sihuang; Clarke, William P

    2017-05-01

    Although CH 4 oxidation in landfill soil covers is widely studied, the extent of composting and CH 4 oxidation in underlying waste layers has been speculated but not measured. The objective of this study was to develop and validate a mass balance model to estimate the simultaneous rates of anaerobic digestion (r AD ), CH 4 oxidation (r OX ) and composting (r COM ) in environments where O 2 penetration is variable and zones of aerobic and anaerobic activity are intermingled. The modelled domain could include, as an example, a soil cover and the underlying shallow waste to a nominated depth. The proposed model was demonstrated on a blend of biogas from three separate known sources of gas representing the three reaction processes: (i) a bottle of laboratory grade 50:50% CH 4 :CO 2 gas representing anaerobic digestion biogas; (ii) an aerated 250mL bottle containing food waste that represented composting activity; and (iii) an aerated 250mL bottle containing non-degradable graphite granules inoculated with methanotrophs and incubated with CH 4 and O 2 to represent methanotrophic activity. CO 2 , CH 4 , O 2 and the stable isotope 13 C-CO 2 were chosen as the components for the mass balance model. The three reaction rates, r (=r AD , r OX , r COM ) were calculated as fitting parameters to the overdetermined set of 4mass balance equations with the net flux of these components from the bottles q (= [Formula: see text] , [Formula: see text] , [Formula: see text] and [Formula: see text] ) as inputs to the model. The coefficient of determination (r 2 ) for observed versus modelled values of r were 1.00, 0.97, 0.98 when the stoichiometry of each reaction was based on gas yields measured in the individual bottles and q was calculated by summing yields from the three bottles. r 2 deteriorated to 0.95, 0.96, 0.87 when using an average stoichiometry from 11 incubations of each of the composting and methane oxidation processes. The significant deterioration in the estimation of r

  18. Model-based calculations of surface mass balance of mountain glaciers for the purpose of water consumption planning: focus on Djankuat Glacier (Central Caucasus)

    Science.gov (United States)

    Rybak, O. O.; Rybak, E. A.

    2018-01-01

    Mountain glaciers act as regulators of run-off in the summer period, which is very crucial for economy especially in dynamically developing regions with rapidly growing population, such as Central Asia or the Northern Caucasus in Russia. In overall, glaciers stabilize water consumption in comparatively arid areas and provide conditions for sustainable development of the economy in mountainous regions and in the surrounding territories. A proper prediction of the glacial run-off is required to elaborate strategies of the regional development. This goal can be achieved by implementation of mathematical modeling methods into planning methodologies. In the paper, we consider one of the first steps in glacier dynamical modeling - surface mass balance simulation. We focus on the Djankuat Glacier in the Central Caucasus, where regular observations have been conducted during the last fifty years providing an exceptional opportunity to calibrate and to validate a mathematical model.

  19. Estimating overall persistence and long-range transport potential of persistent organic pollutants: a comparison of seven multimedia mass balance models and atmospheric transport models.

    Science.gov (United States)

    Hollander, A; Scheringer, M; Shatalov, V; Mantseva, E; Sweetman, A; Roemer, M; Baart, A; Suzuki, N; Wegmann, F; van de Meent, D

    2008-10-01

    Two different approaches to modeling the environmental fate of organic chemicals have been developed in recent years. The first approach is applied in multimedia box models, calculating average concentrations in homogeneous boxes which represent the different environmental media, based on intermedia partitioning, transport, and degradation processes. In the second approach, used in atmospheric transport models, the spatially and temporally variable atmospheric dynamics form the basis for calculating the environmental distribution of chemicals, from which also exchange processes to other environmental media are modeled. The main goal of the present study was to investigate if the multimedia mass balance models CliMoChem, SimpleBox, EVn-BETR, G-CIEMS, OECD Tool and the atmospheric transport models MSCE-POP and ADEPT predict the same rankings of the overall persistence (P(ov)) and long-range transport potential (LRTP) of POPs, and to explain differences and similarities between the rankings by the mass distributions and inter-compartment mass flows. The study was performed for a group of 14 reference chemicals. For P(ov), the models yield consistent results, owing to the large influence of phase partitioning parameters and degradation rate constants, which are used similarly by all models. Concerning LRTP, there are larger differences between the models than for P(ov), due to different LRTP calculation methods and spatial model resolutions. Between atmospheric transport models and multimedia fate models, no large differences in mass distributions and inter-compartment flows can be recognized. Deviations in mass flows are mainly caused by the geometrical design of the models.

  20. Application and Evaluation of a Snow Energy and Mass Balance Distributed Model in the Merced and Tuolumne River Watersheds of the Sierra Nevada, California

    Science.gov (United States)

    Roche, J. W.; Rice, R.; Marks, D. G.

    2015-12-01

    Characterization of snow accumulation and melt in forested environments is a key component of the hydrological cycle in mountainous regions, yet is often over-simplified in hydroecological watershed modeling due to computational limits and paucity of input data. A key first step in addressing this deficiency is to assess potential improvements in predicting snow water equivalent using a land surface model (full energy and mass balance of snow pack) over a sufficiently large geographic area to address societal questions centered on forest change and water yield of river basins. The snow energy and mass balance model ISNOBAL was applied over a 14,300 km2 region encompassing the Merced and Tuolumne River watersheds in the Sierra Nevada at a 1-hour time step and 100-meter spatial resolution for water years 2010-2014. Results show a bias toward a slight over-estimation of snow water equivalent when compared to manual snow course measurements, though cumulative melt was consistent with summed river gage data and independent estimates of evapotranspiration. Ratios of gaged runoff to water available for runoff from the base of the snowpack ranged from 0.45 to 0.59 for three different gages. Modeled results were compared to independently-derived estimates of snow water equivalent from MODIS Snow Covered Area reconstruction and airborne LiDAR estimates of snow depth, highlighting potential deficiency in SCA reconstructions, and the use of LiDAR derived snow surface maps providing snow distribution patterns in physically based models. Further, ISNOBAL highlighted trends in snow distribution patterns and snowmelt timing in an average (2010), above average (2011), and below average (2014) year.

  1. Application of GRACE to the assessment of model-based estimates of monthly Greenland Ice Sheet mass balance (2003–2012

    Directory of Open Access Journals (Sweden)

    N.-J. Schlegel

    2016-09-01

    Full Text Available Quantifying the Greenland Ice Sheet's future contribution to sea level rise is a challenging task that requires accurate estimates of ice sheet sensitivity to climate change. Forward ice sheet models are promising tools for estimating future ice sheet behavior, yet confidence is low because evaluation of historical simulations is challenging due to the scarcity of continental-wide data for model evaluation. Recent advancements in processing of Gravity Recovery and Climate Experiment (GRACE data using Bayesian-constrained mass concentration ("mascon" functions have led to improvements in spatial resolution and noise reduction of monthly global gravity fields. Specifically, the Jet Propulsion Laboratory's JPL RL05M GRACE mascon solution (GRACE_JPL offers an opportunity for the assessment of model-based estimates of ice sheet mass balance (MB at ∼ 300 km spatial scales. Here, we quantify the differences between Greenland monthly observed MB (GRACE_JPL and that estimated by state-of-the-art, high-resolution models, with respect to GRACE_JPL and model uncertainties. To simulate the years 2003–2012, we force the Ice Sheet System Model (ISSM with anomalies from three different surface mass balance (SMB products derived from regional climate models. Resulting MB is compared against GRACE_JPL within individual mascons. Overall, we find agreement in the northeast and southwest where MB is assumed to be primarily controlled by SMB. In the interior, we find a discrepancy in trend, which we presume to be related to millennial-scale dynamic thickening not considered by our model. In the northwest, seasonal amplitudes agree, but modeled mass trends are muted relative to GRACE_JPL. Here, discrepancies are likely controlled by temporal variability in ice discharge and other related processes not represented by our model simulations, i.e., hydrological processes and ice–ocean interaction. In the southeast, GRACE_JPL exhibits larger seasonal

  2. Impact of improved Greenland ice sheet surface representation in the NASA GISS ModelE2 GCM on simulated surface mass balance and regional climate

    Science.gov (United States)

    Alexander, P. M.; LeGrande, A. N.; Fischer, E.; Tedesco, M.; Kelley, M.; Schmidt, G. A.; Fettweis, X.

    2017-12-01

    Towards achieving coupled simulations between the NASA Goddard Institute for Space Studies (GISS) ModelE2 general circulation model (GCM) and ice sheet models (ISMs), improvements have been made to the representation of the ice sheet surface in ModelE2. These include a sub-grid-scale elevation class scheme, a multi-layer snow model, a time-variable surface albedo scheme, and adjustments to parameterization of sublimation/evaporation. These changes improve the spatial resolution and physical representation of the ice sheet surface such that the surface is represented at a level of detail closer to that of Regional Climate Models (RCMs). We assess the impact of these changes on simulated Greenland Ice Sheet (GrIS) surface mass balance (SMB). We also compare ModelE2 simulations in which winds have been nudged to match the European Center for Medium-Range Weather Forecasts (ECMWF) ERA-Interim reanalysis with simulations from the Modèle Atmosphérique Régionale (MAR) RCM forced by the same reanalysis. Adding surface elevation classes results in a much higher spatial resolution representation of the surface necessary for coupling with ISMs, but has a negligible impact on overall SMB. Implementing a variable surface albedo scheme increases melt by 100%, bringing it closer to melt simulated by MAR. Adjustments made to the representation of topography-influenced surface roughness length in ModelE2 reduce a positive bias in evaporation relative to MAR. We also examine the impact of changes to the GrIS surface on regional atmospheric and oceanic climate in coupled ocean-atmosphere simulations with ModelE2, finding a general warming of the Arctic due to a warmer GrIS, and a cooler North Atlantic in scenarios with doubled atmospheric CO2 relative to pre-industrial levels. The substantial influence of changes to the GrIS surface on the oceans and atmosphere highlight the importance of including these processes in the GCM, in view of potential feedbacks between the ice sheet

  3. The use of a numerical mass-balance model to estimate rates of soil redistribution on uncultivated land from 137Cs measurements

    International Nuclear Information System (INIS)

    Owens, P.N.; Walling, D.E.

    1988-01-01

    A numerical mass-balance model is developed which can be used to estimate rates of soil redistribution on uncultivated land from measurements of bombderived 137 Cs inventories. The model uses a budgeting approach, which takes account of temporal variations in atmospheric fallout of 137 Cs, radioactive decay, and net gains or losses of 137 Cs due to erosion and deposition processes, combined with parameters which describe internal 137 Cs redistribution processes, to estimate the 137 Cs content of topsoil and the 137 Cs inventory at specific points, from the start of 137 Cs fallout in the 1950s to the present day. The model is also able to account for potential differences in particle size composition and organic matter content between mobilised soil particles and the original soil, and the effect that these may have on 137 Cs concentrations and inventories. By running the model for a range of soil erosion and deposition rates, a calibration relationship can be constructed which relates the 137 Cs inventory at a sampling point to the average net soil loss or gain at that location. In addition to the magnitude and temporal distribution of the 137 Cs atmospheric fallout flux, the soil redistribution rates estimated by the model are sensitive to parameters which describe the relative texture and organic matter content of the eroded or deposited material, and the ability of the soil to retain 137 Cs in the upper part of the soil profile. (Copyright (c) 1988 Elsevier Science B.V., Amsterdam. All rights reserved.)

  4. Application of mass balance models and the chemical activity concept to facilitate the use of in vitro toxicity data for risk assessment.

    Science.gov (United States)

    Armitage, James M; Wania, Frank; Arnot, Jon A

    2014-08-19

    Practical, financial, and ethical considerations related to conducting extensive animal testing have resulted in various initiatives to promote and expand the use of in vitro testing data for chemical evaluations. Nominal concentrations in the aqueous phase corresponding to an effect (or biological activity) are commonly reported and used to characterize toxicity (or biological response). However, the true concentration in the aqueous phase can be substantially different from the nominal. To support in vitro test design and aid the interpretation of in vitro toxicity data, we developed a mass balance model that can be parametrized and applied to represent typical in vitro test systems. The model calculates the mass distribution, freely dissolved concentrations, and cell/tissue concentrations corresponding to the initial nominal concentration and experimental conditions specified by the user. Chemical activity, a metric which can be used to assess the potential for baseline toxicity to occur, is also calculated. The model is first applied to a set of hypothetical chemicals to illustrate the degree to which test conditions (e.g., presence or absence of serum) influence the distribution of the chemical in the test system. The model is then applied to set of 1194 real substances (predominantly from the ToxCast chemical database) to calculate the potential range of concentrations and chemical activities under assumed test conditions. The model demonstrates how both concentrations and chemical activities can vary by orders of magnitude for the same nominal concentration.

  5. Evaluating recharge to an ephemeral dryland stream using a hydraulic model and water, chloride and isotope mass balance

    Science.gov (United States)

    Dogramaci, Shawan; Firmani, Giovanni; Hedley, Paul; Skrzypek, Grzegorz; Grierson, Pauline F.

    2015-02-01

    Dewatering associated with mining below water table to achieve dry mining conditions may exert significant pressure on water balance in terms of lowering the water table and change in the dynamics of interactions between surface water and groundwater. The discharge of surplus mine water into ephemeral streams may also affect the water balance, by elevating groundwater levels and altering the exchange rate between streams and underlying aquifers. However, it is unclear whether volumes and recharge processes are within the range of natural variability. Here, we present a case study of an ephemeral creek in the semi-arid Hamersley Basin of northwest Australia that has received continuous mine discharge for more than six years. We used a numerical model coupled with repeated measurements of water levels, chloride concentrations and the hydrogen and oxygen stable isotope composition (δ2H and δ18O) to estimate longitudinal evapotranspiration and recharge rates along a 27 km length of Weeli Wolli Creek. We found that chloride increased from 73 to 120 mg/L across this length, while δ18O increased from -8.2‰ to -7.00‰. Groundwater is directly connected to the creek for the first 13 km and recharge rates are negligible. Below this point, the creek flows over a highly permeable aquifer and water loss by recharge increases to a maximum rate of 4.4 mm/d, which accounts for ∼65% of the total water discharged to the creek. Evapotranspiration losses account for the remaining ∼35%. The calculated recharge from continuous flow due to surplus water discharge is similar to that measured for rainfall-driven flood events along the creek. Groundwater under the disconnected section of the creek is characterised by a much lower Cl concentration and more depleted δ18O value than mining discharge water but is similar to flood water generated by large episodic rainfall events. Our results suggest that the impact of recharge from continuous flow on the water balance of the creek

  6. Test and application of a general process-based dynamic coastal mass-balance model for contaminants using data for radionuclides in the Dnieper-Bug estuary

    International Nuclear Information System (INIS)

    Hakanson, Lars; Lindgren, Dan

    2009-01-01

    In this work a general, process-based mass-balance model for water contaminants for coastal areas at the ecosystem scale (CoastMab) is presented and for the first time tested for radionuclides. The model is dynamic, based on ordinary differential equations and gives monthly predictions. Connected to the core model there is also a sub-model for contaminant concentrations in fish. CoastMab calculates sedimentation, resuspension, diffusion, mixing, burial and retention of the given contaminant. The model contains both general algorithms, which apply to all contaminants, and substance-specific parts (such as algorithms for the particulate fraction, diffusion, biouptake and biological half-life). CoastMab and the sub-model for fish are simple to apply in practice since all driving variables may be readily accessed from maps or regular monitoring programs. The separation between the surface-water layer and the deep-water layer is not done as in most traditional models from water temperature data but from sedimentological criteria. Previous versions of the models for phosphorus and suspended particulate matter (in the Baltic Sea) have been validated and shown to predict well. This work presents modifications of the model and tests using two tracers, radiocesium and radiostrontium (from the Chernobyl fallout) in the Dnieper-Bug estuary (the Black Sea). Good correlations are shown between modeled and empirical data, except for the month directly after the fallout. We have, e.g., shown that: 1. The conditions in the sea outside the bay are important for the concentrations of the substances in water, sediments and fish within the bay, 2. We have demonstrated 'biological,' 'chemical' and 'water' dilution, 3. That the water chemical conditions in the bay influence biouptake and concentrations in fish of the radionuclides and 4. That the feeding behaviour of the coastal fish is very important for the biouptake of the radionuclides

  7. A Mass-balance nitrate model for predicting the effects of land use on ground-water quality in municipal wellhead-protection areas

    Science.gov (United States)

    Frimpter, M.H.; Donohue, J.J.; Rapacz, M.V.; Beye, H.G.

    1990-01-01

    A mass-balance accounting model can be used to guide the management of septic systems and fertilizers to control the degradation of groundwater quality in zones of an aquifer that contributes water to public supply wells. The nitrate nitrogen concentration of the mixture in the well can be predicted for steady-state conditions by calculating the concentration that results from the total weight of nitrogen and total volume of water entering the zone of contribution to the well. These calculations will allow water-quality managers to predict the nitrate concentrations that would be produced by different types and levels of development, and to plan development accordingly. Computations for different development schemes provide a technical basis for planners and managers to compare water quality effects and to select alternatives that limit nitrate concentration in wells. Appendix A contains tables of nitrate loads and water volumes from common sources for use with the accounting model. Appendix B describes the preparation of a spreadsheet for the nitrate loading calculations with a software package generally available for desktop computers. (USGS)

  8. Surface mass balance and runoff modeling using HIRHAM4 RCM at Kangerlussuaq (Søndre Strømfjord), West Greenland, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2011-01-01

    Greenland's Kangerlussuaq drainage. Projected changes in the Greenland Ice Sheet (GrIS) surface mass balance (SMB) and runoff are relevant for potential hydropower production and prediction of ecosystem changes in sensitive Kangerlussuaq Fjord systems. Mean annual surface air temperatures and precipitation...... in the Kangerlussuaq area were simulated to increase by 3.4°C and 95 mm water equivalent (w.eq.), respectively, between 1950 and 2080. The local Kangerlussuaq warming was less than the average warming of 4.8°C simulated for the entire GrIS. The Kangerlussuaq SMB loss increased by an average of 0.3 km3 because of a 0.......4 km3 rise in precipitation, 0.1 km3 rise in evaporation and sublimation, and 0.6 km3 gain in runoff (1950-2080). By 2080, the spring runoff season begins approximately three weeks earlier. The average modeled SMB and runoff is approximately -0.1 and 1.2 km3 yr-1, respectively, indicating that ~10...

  9. 14 CFR 29.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 29.659 Section 29.659... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Design and Construction Rotors § 29.659 Mass balance. (a) The rotor... flutter at any speed up to the maximum forward speed. (b) The structural integrity of the mass balance...

  10. 14 CFR 23.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 23.659 Section 23.659 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT AIRWORTHINESS... Surfaces § 23.659 Mass balance. The supporting structure and the attachment of concentrated mass balance...

  11. 14 CFR 27.659 - Mass balance.

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Mass balance. 27.659 Section 27.659... STANDARDS: NORMAL CATEGORY ROTORCRAFT Design and Construction Rotors § 27.659 Mass balance. (a) The rotors... flutter at any speed up to the maximum forward speed. (b) The structural integrity of the mass balance...

  12. Using plot experiments to test the validity of mass balance models employed to estimate soil redistribution rates from 137Cs and 210Pb(ex) measurements.

    Science.gov (United States)

    Porto, Paolo; Walling, Des E

    2012-10-01

    Information on rates of soil loss from agricultural land is a key requirement for assessing both on-site soil degradation and potential off-site sediment problems. Many models and prediction procedures have been developed to estimate rates of soil loss and soil redistribution as a function of the local topography, hydrometeorology, soil type and land management, but empirical data remain essential for validating and calibrating such models and prediction procedures. Direct measurements using erosion plots are, however, costly and the results obtained relate to a small enclosed area, which may not be representative of the wider landscape. In recent years, the use of fallout radionuclides and more particularly caesium-137 ((137)Cs) and excess lead-210 ((210)Pb(ex)) has been shown to provide a very effective means of documenting rates of soil loss and soil and sediment redistribution in the landscape. Several of the assumptions associated with the theoretical conversion models used with such measurements remain essentially unvalidated. This contribution describes the results of a measurement programme involving five experimental plots located in southern Italy, aimed at validating several of the basic assumptions commonly associated with the use of mass balance models for estimating rates of soil redistribution on cultivated land from (137)Cs and (210)Pb(ex) measurements. Overall, the results confirm the general validity of these assumptions and the importance of taking account of the fate of fresh fallout. However, further work is required to validate the conversion models employed in using fallout radionuclide measurements to document soil redistribution in the landscape and this could usefully direct attention to different environments and to the validation of the final estimates of soil redistribution rate as well as the assumptions of the models employed. Copyright © 2012 Elsevier Ltd. All rights reserved.

  13. Estimating the Greenland ice sheet surface mass balance contribution to future sea level rise using the regional atmospheric climate model MAR

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2013-03-01

    Full Text Available To estimate the sea level rise (SLR originating from changes in surface mass balance (SMB of the Greenland ice sheet (GrIS, we present 21st century climate projections obtained with the regional climate model MAR (Modèle Atmosphérique Régional, forced by output of three CMIP5 (Coupled Model Intercomparison Project Phase 5 general circulation models (GCMs. Our results indicate that in a warmer climate, mass gain from increased winter snowfall over the GrIS does not compensate mass loss through increased meltwater run-off in summer. Despite the large spread in the projected near-surface warming, all the MAR projections show similar non-linear increase of GrIS surface melt volume because no change is projected in the general atmospheric circulation over Greenland. By coarsely estimating the GrIS SMB changes from GCM output, we show that the uncertainty from the GCM-based forcing represents about half of the projected SMB changes. In 2100, the CMIP5 ensemble mean projects a GrIS SMB decrease equivalent to a mean SLR of +4 ± 2 cm and +9 ± 4 cm for the RCP (Representative Concentration Pathways 4.5 and RCP 8.5 scenarios respectively. These estimates do not consider the positive melt–elevation feedback, although sensitivity experiments using perturbed ice sheet topographies consistent with the projected SMB changes demonstrate that this is a significant feedback, and highlight the importance of coupling regional climate models to an ice sheet model. Such a coupling will allow the assessment of future response of both surface processes and ice-dynamic changes to rising temperatures, as well as their mutual feedbacks.

  14. Isotopic and hydrologic responses of small, closed lakes to climate variability: Hydroclimate reconstructions from lake sediment oxygen isotope records and mass balance models

    Science.gov (United States)

    Steinman, Byron A.; Abbott, Mark B.

    2013-03-01

    Hydroclimate sensitivity simulations were conducted with a lake-catchment hydrologic and isotope mass balance model adapted to two small, closed lakes (Castor and Scanlon) located in the Pacific Northwest. Model simulations were designed to investigate the combined influences of persistent disequilibrium, reddening, and equifinality on lake water and sediment (i.e., biogenic and endogenic carbonate mineral) oxygen isotope (δ18O) values and to provide a basis for quantitative, probabilistic climate reconstructions using lake sediment δ18O records. Simulation results indicate that within closed-basin lakes changes in long-term (i.e., multi-decadal) precipitation amounts produce inconsistent responses in lake water and sediment δ18O values that are strongly influenced by lake basin outseepage and morphometry. Simulations of variable initial conditions in which randomly generated monthly climate data (i.e., precipitation, temperature, and relative humidity) were used to force the model during the equilibration period (which precedes the application of instrumental climate data) demonstrate that Castor Lake and Scanlon Lake have a somewhat limited isotopic 'memory' of ˜10 years. Additional tests conducted using a Monte Carlo ensemble (in which random climate data were used to force the model) combined with δ18O analyses of water samples collected from 2003 to 2011 AD, indicate that within small, closed lakes in the Pacific Northwest November-February precipitation is the strongest seasonal, climatic control on sediment oxygen-isotope values. Further, a Monte Carlo based reconstruction of 20 year average November-February precipitation amounts strongly correlates (R2 = 0.66) to instrumental values from the 20th century (with all observed values falling within modeled 95% prediction limits), indicating that probabilistic, quantitative paleoclimate interpretations of lake sediment δ18O records are attainable.

  15. Mass balancing of hollow fan blades

    Science.gov (United States)

    Kielb, R. E.

    1986-01-01

    A typical section model is used to analytically investigate the effect of mass balancing as applied to hollow, supersonic fan blades. A procedure to determine the best configuration of an internal balancing mass to provide flutter alleviation is developed. This procedure is applied to a typical supersonic shroudless fan blade which is unstable in both the solid configuration and when it is hollow with no balancing mass. The addition of an optimized balancing mass is shown to stabilize the blade at the design condition.

  16. Application of a hybrid method for downscaling of the global climate model fields for evaluation of future surface mass balance of mountain glaciers

    Science.gov (United States)

    Morozova, Polina; Rybak, Oleg; Kaminskaia, Mariia

    2017-04-01

    Mountain glaciers in the Caucasus have been degrading during the last century. During this time period they lost approximately one-third in area and half of their volume. Prediction of their evolution in changing climate is crucial for the local economy because hydrological regime in the territory north to the Main Caucasus Chain is mainly driven by glacier run-off. For future projections of glaciers' surface mass balance (SMB) we apply a hybrid method of downscaling of GCM-generated meteorological fields from the global scale to the characteristic spatial resolution normally used for modeling of a single mountain glacier SMB. A method consists of two stages. On the first, dynamical stage, we use the results of calculations of regional climate model (RCM) HadRM3P for the Black Sea-Caspian region with a spatial resolution of approximately 25 km. Initial and boundary conditions for HadRM3P are provided by an AO GCM INMCM developed in the Institute of Numerical Mathematics (Moscow, Russia). Calculations were carried out for two time slices: the present (reference) climate (1971-2000 years) and climate in the late 21st century (2071-2100 years) according to scenario of greenhouse gas emissions RCP 8.5. On the second stage of downscaling, further regionalization is achieved by projecting of RCM-generated data to the high-resolution (25 m) digital elevation models in a domain enclosing target glaciers (Marukh in the Western Caucasus and Djankuat in the Central Caucasus, both being typical valley glaciers). Elevation gradient of surface air temperature and precipitation were derived from the model data. Further, results were corrected using data of observations. The incoming shortwave radiation is calculated separately, taking into account slopes, aspects and shade effect. In the end of the current century expected air temperature growth in the Central and Western Caucasus is about 5-6 °C (summer), and 2-3 °C (winter). Reduction in annual precipitation is not

  17. Estimating representative background PM2.5 concentration in heavily polluted areas using baseline separation technique and chemical mass balance model

    Science.gov (United States)

    Gao, Shuang; Yang, Wen; Zhang, Hui; Sun, Yanling; Mao, Jian; Ma, Zhenxing; Cong, Zhiyuan; Zhang, Xian; Tian, Shasha; Azzi, Merched; Chen, Li; Bai, Zhipeng

    2018-02-01

    The determination of background concentration of PM2.5 is important to understand the contribution of local emission sources to total PM2.5 concentration. The purpose of this study was to exam the performance of baseline separation techniques to estimate PM2.5 background concentration. Five separation methods, which included recursive digital filters (Lyne-Hollick, one-parameter algorithm, and Boughton two-parameter algorithm), sliding interval and smoothed minima, were applied to one-year PM2.5 time-series data in two heavily polluted cities, Tianjin and Jinan. To obtain the proper filter parameters and recession constants for the separation techniques, we conducted regression analysis at a background site during the emission reduction period enforced by the Government for the 2014 Asia-Pacific Economic Cooperation (APEC) meeting in Beijing. Background concentrations in Tianjin and Jinan were then estimated by applying the determined filter parameters and recession constants. The chemical mass balance (CMB) model was also applied to ascertain the effectiveness of the new approach. Our results showed that the contribution of background PM concentration to ambient pollution was at a comparable level to the contribution obtained from the previous study. The best performance was achieved using the Boughton two-parameter algorithm. The background concentrations were estimated at (27 ± 2) μg/m3 for the whole year, (34 ± 4) μg/m3 for the heating period (winter), (21 ± 2) μg/m3 for the non-heating period (summer), and (25 ± 2) μg/m3 for the sandstorm period in Tianjin. The corresponding values in Jinan were (30 ± 3) μg/m3, (40 ± 4) μg/m3, (24 ± 5) μg/m3, and (26 ± 2) μg/m3, respectively. The study revealed that these baseline separation techniques are valid for estimating levels of PM2.5 air pollution, and that our proposed method has great potential for estimating the background level of other air pollutants.

  18. Quantifying mass balance processes on the Southern Patagonia Icefield

    DEFF Research Database (Denmark)

    Schaefer, M.; Machguth, Horst; Falvey, M.

    2014-01-01

    measured accumulation of snow as well as the high measured ablation is reproduced by the model. The overall modeled surface mass balance was positive and increasing during 1975–2011. Subtracting the surface mass balance from geodetic balances, calving fluxes were inferred. Mass losses of the SPI due...... to calving were strongly increasing from 1975–2000 to 2000–2011 and higher 10 than losses due to surface melt. Calving fluxes were inferred for the individual glacier catchments and compared to fluxes estimated from velocity data. Measurements of ice thickness and flow velocities at the glaciers’ front...

  19. Quantifying mass balance processes on the Southern Patagonia Icefield

    DEFF Research Database (Denmark)

    Schaefer, M.; Machguth, Horst; Falvey, M.

    2015-01-01

    measured accumulation of snow of up to 15.4m w.e. yr(-1) (meters water equivalent per year) as well as the high measured ablation of up to 11m w.e. yr(-1) is reproduced by the model. The overall modeled surface mass balance was positive and increasing during 1975-2011. Subtracting the surface mass balance...... from geodetic balances, calving fluxes were inferred. Mass losses of the SPI due to calving were strongly increasing from 1975-2000 to 2000-2011 and higher than losses due to surface melt. Calving fluxes were inferred for the individual glacier catchments and compared to fluxes estimated from velocity...

  20. Petrographic features, geochemical trends and mass balance ...

    African Journals Online (AJOL)

    Petrographic features, geochemical trends and mass balance computation, in relation to the evolution of anatectic migmatites in the granulite facies terrain of the Manalur area, Tamil Nadu, south India.

  1. The importance of accurate glacier albedo for estimates of surface mass balance on Vatnajökull: evaluating the surface energy budget in a regional climate model with automatic weather station observations

    Science.gov (United States)

    Steffensen Schmidt, Louise; Aðalgeirsdóttir, Guðfinna; Guðmundsson, Sverrir; Langen, Peter L.; Pálsson, Finnur; Mottram, Ruth; Gascoin, Simon; Björnsson, Helgi

    2017-07-01

    A simulation of the surface climate of Vatnajökull ice cap, Iceland, carried out with the regional climate model HIRHAM5 for the period 1980-2014, is used to estimate the evolution of the glacier surface mass balance (SMB). This simulation uses a new snow albedo parameterization that allows albedo to exponentially decay with time and is surface temperature dependent. The albedo scheme utilizes a new background map of the ice albedo created from observed MODIS data. The simulation is evaluated against observed daily values of weather parameters from five automatic weather stations (AWSs) from the period 2001-2014, as well as in situ SMB measurements from the period 1995-2014. The model agrees well with observations at the AWS sites, albeit with a general underestimation of the net radiation. This is due to an underestimation of the incoming radiation and a general overestimation of the albedo. The average modelled albedo is overestimated in the ablation zone, which we attribute to an overestimation of the thickness of the snow layer and not taking the surface darkening from dirt and volcanic ash deposition during dust storms and volcanic eruptions into account. A comparison with the specific summer, winter, and net mass balance for the whole of Vatnajökull (1995-2014) shows a good overall fit during the summer, with a small mass balance underestimation of 0.04 m w.e. on average, whereas the winter mass balance is overestimated by on average 0.5 m w.e. due to too large precipitation at the highest areas of the ice cap. A simple correction of the accumulation at the highest points of the glacier reduces this to 0.15 m w.e. Here, we use HIRHAM5 to simulate the evolution of the SMB of Vatnajökull for the period 1981-2014 and show that the model provides a reasonable representation of the SMB for this period. However, a major source of uncertainty in the representation of the SMB is the representation of the albedo, and processes currently not accounted for in RCMs

  2. The importance of accurate glacier albedo for estimates of surface mass balance on Vatnajökull: evaluating the surface energy budget in a regional climate model with automatic weather station observations

    Directory of Open Access Journals (Sweden)

    L. S. Schmidt

    2017-07-01

    Full Text Available A simulation of the surface climate of Vatnajökull ice cap, Iceland, carried out with the regional climate model HIRHAM5 for the period 1980–2014, is used to estimate the evolution of the glacier surface mass balance (SMB. This simulation uses a new snow albedo parameterization that allows albedo to exponentially decay with time and is surface temperature dependent. The albedo scheme utilizes a new background map of the ice albedo created from observed MODIS data. The simulation is evaluated against observed daily values of weather parameters from five automatic weather stations (AWSs from the period 2001–2014, as well as in situ SMB measurements from the period 1995–2014. The model agrees well with observations at the AWS sites, albeit with a general underestimation of the net radiation. This is due to an underestimation of the incoming radiation and a general overestimation of the albedo. The average modelled albedo is overestimated in the ablation zone, which we attribute to an overestimation of the thickness of the snow layer and not taking the surface darkening from dirt and volcanic ash deposition during dust storms and volcanic eruptions into account. A comparison with the specific summer, winter, and net mass balance for the whole of Vatnajökull (1995–2014 shows a good overall fit during the summer, with a small mass balance underestimation of 0.04 m w.e. on average, whereas the winter mass balance is overestimated by on average 0.5 m w.e. due to too large precipitation at the highest areas of the ice cap. A simple correction of the accumulation at the highest points of the glacier reduces this to 0.15 m w.e. Here, we use HIRHAM5 to simulate the evolution of the SMB of Vatnajökull for the period 1981–2014 and show that the model provides a reasonable representation of the SMB for this period. However, a major source of uncertainty in the representation of the SMB is the representation of the albedo, and processes

  3. Estimates of Regional Equilibrium Line Altitudes and Net Mass Balance from MODIS Imagery

    Science.gov (United States)

    Shea, J. M.; Menounos, B.; Moore, R. D.

    2011-12-01

    Glacier mass balance is a key variable used to assess the health of glaciers and ice sheets. Estimates of glacier mass balance are required to model the dynamic response of glaciers and ice sheets to climate change, estimate sea-level contribution from surface melt, and document the response of glaciers to climate forcing. Annually resolved estimates of regional mass balance for mountain ranges is often inferred from a sparse network of ground-based measurements of mass balance for individual glaciers. Given that net mass balance is highly correlated with the annual equilibrium line altitude (ELA), we develop an automated approach to estimate the ELA, and by inference net mass balance, on large glaciers and icefields using MODIS 250 m imagery (MOD02QKM). We discriminate areas of bare ice and snow/firn using the product of MODIS' red (0.620 - 0.670 μ m) and near infrared (0.841 - 0.876 μ m) bands. To assess the skill in estimating glacier ELAs, we compare ELAs derived from (1) manual delineation and (2) unsupervised classification of the band product to ground-based observations of ELA and net mass balance at seven long term mass-balance monitoring sites in western North America (Gulkana, Wolverine, Lemon Creek, Taku, Place, Peyto, and South Cascade). Spatial and temporal variations in MODIS-derived ELAs provide an opportunity to validate regional mass-balance models, estimate surface melt contributions to sea-level rise, and examine the cryospheric response to climate change.

  4. Greenland ice sheet mass balance: a review.

    Science.gov (United States)

    Khan, Shfaqat A; Aschwanden, Andy; Bjørk, Anders A; Wahr, John; Kjeldsen, Kristian K; Kjær, Kurt H

    2015-04-01

    Over the past quarter of a century the Arctic has warmed more than any other region on Earth, causing a profound impact on the Greenland ice sheet (GrIS) and its contribution to the rise in global sea level. The loss of ice can be partitioned into processes related to surface mass balance and to ice discharge, which are forced by internal or external (atmospheric/oceanic/basal) fluctuations. Regardless of the measurement method, observations over the last two decades show an increase in ice loss rate, associated with speeding up of glaciers and enhanced melting. However, both ice discharge and melt-induced mass losses exhibit rapid short-term fluctuations that, when extrapolated into the future, could yield erroneous long-term trends. In this paper we review the GrIS mass loss over more than a century by combining satellite altimetry, airborne altimetry, interferometry, aerial photographs and gravimetry data sets together with modelling studies. We revisit the mass loss of different sectors and show that they manifest quite different sensitivities to atmospheric and oceanic forcing. In addition, we discuss recent progress in constructing coupled ice-ocean-atmosphere models required to project realistic future sea-level changes.

  5. Mass-balance modeling of mineral weathering rates and CO2 consumption in the forested, metabasaltic Hauver Branch watershed, Catoctin Mountain, Maryland, USA

    Science.gov (United States)

    Rice, Karen; Price, Jason R.; Szymanski, David W.

    2013-01-01

    Mineral weathering rates and a forest macronutrient uptake stoichiometry were determined for the forested, metabasaltic Hauver Branch watershed in north-central Maryland, USA. Previous studies of Hauver Branch have had an insufficient number of analytes to permit determination of rates of all the minerals involved in chemical weathering, including biomass. More equations in the mass-balance matrix were added using existing mineralogic information. The stoichiometry of a deciduous biomass term was determined using multi-year weekly to biweekly stream-water chemistry for a nearby watershed, which drains relatively unreactive quartzite bedrock.At Hauver Branch, calcite hosts ~38 mol% of the calcium ion (Ca2+) contained in weathering minerals, but its weathering provides ~90% of the stream water Ca2+. This occurs in a landscape with a regolith residence time of more than several Ka (kiloannum). Previous studies indicate that such old regolith does not typically contain dissolving calcite that affects stream Ca2+/Na+ ratios. The relatively high calcite dissolution rate likely reflects dissolution of calcite in fractures of the deep critical zone.Of the carbon dioxide (CO2) consumed by mineral weathering, calcite is responsible for approximately 27%, with the silicate weathering consumption rate far exceeding that of the global average. The chemical weathering of mafic terrains in decaying orogens thus may be capable of influencing global geochemical cycles, and therefore, climate, on geological timescales. Based on carbon-balance calculations, atmospheric-derived sulfuric acid is responsible for approximately 22% of the mineral weathering occurring in the watershed. Our results suggest that rising air temperatures, driven by global warming and resulting in higher precipitation, will cause the rate of chemical weathering in the Hauver Branch watershed to increase until a threshold temperature is reached. Beyond the threshold temperature, increased recharge would

  6. Incorporation of diet information derived from Bayesian stable isotope mixing models into mass-balanced marine ecosystem models: A case study from the Marennes-Oleron Estuary, France

    Science.gov (United States)

    We investigated the use of output from Bayesian stable isotope mixing models as constraints for a linear inverse food web model of a temperate intertidal seagrass system in the Marennes-Oléron Bay, France. Linear inverse modeling (LIM) is a technique that estimates a complete net...

  7. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in g...

  8. Mass balance reconstruction of Rikha Samba Glacier between 1979 and 2016, Nepal Himalaya

    Science.gov (United States)

    Gurung, T. R.; Kayastha, R. B.; Fujita, K.; Sinisalo, A. K.; Litt, M.; Joshi, S.; Stumm, D.

    2017-12-01

    Glacier mass balance variability influences regional water resources and helps to understand the glacier response to climate change. Several mass balance studies have started in the Himalayan region since the 1970s, but a time series remains short or incomplete and spatial representatively remains poor. We run an energy mass balance model in order to bridge the temporal gaps in a long-term mass balance series of the Rikha Samba Glacier, a benchmark glacier located in the Hidden Valley, Mustang, Nepal. We force the model with ERA-Interim reanalysis data, adjusted near the glacier terminus for the period 1979 to 2016, the location of an automatic weather station (AWS), to observed meteorological variables (2011-2015) by a linear regression method. The modelled mass balances are validated with the available in-situ measurements for the mass years 1998-99 and 2011-15 and geodetic mass balance from 1979 to 1995 and 1998 to 2010. Modelled results show the glacier has been shrinking moderately with annual glacier-wide mass balance at -0.44 m w.e. a-1 during the study period. Summer temperature, monsoon and westerlies precipitation are the influential climatic variables of an annual mass balance variability of Rikha Samba Glacier.

  9. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    NARCIS (Netherlands)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker; Ahlstrøm, Andreas P.; Abermann, Jakob; Andersen, Morten L.; Andersen, Signe B.; Bjørk, Anders A.; Box, Jason E.; Braithwaite, Roger J.; Bøggild, Carl E.; Citterio, Michele; Clement, Poul; Colgan, William; Fausto, Robert S.; Gleie, Karin; Gubler, Stefanie; Hasholt, Bent; Hynek, Bernhard; Knudsen, Niels T.; Larsen, Signe H.; Mernild, Sebastian H.; Oerlemans, Johannes; Oerter, Hans; Olesen, Ole B.; Smeets, C. J P Paul; Steffen, Konrad; Stober, Manfred; Sugiyama, Shin; Van As, Dirk; Van Den Broeke, Michiel R.; Van De Wal, Roderik S W

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in

  10. Greenland ice sheet mass balance: a review

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Aschwanden, Andy; Bjørk, Anders A.

    2015-01-01

    Over the past quarter of a century the Arctic has warmed more than any other region on Earth, causing a profound impact on the Greenland ice sheet (GrIS) and its contribution to the rise in global sea level. The loss of ice can be partitioned into processes related to surface mass balance...... realistic future sea-level changes....

  11. On the Mass Balance of Asphaltene Precipitation

    DEFF Research Database (Denmark)

    Andersen, Simon Ivar; Lira-Galeana, C.; Stenby, Erling Halfdan

    2001-01-01

    are performed in order to check the consistency of mass balances within asphaltene precipitation. Asphaltenes are precipitated in two step processes either by changing temperature or by changes in precipitant with increasing precipitation power. This has been performed for three different oils. The data...

  12. Uncertainty analysis using a fugacity-based multimedia mass-balance model: application of the updated EQC model to decamethylcyclopentasiloxane (D5).

    Science.gov (United States)

    Kim, Jaeshin; Powell, David E; Hughes, Lauren; Mackay, Don

    2013-10-01

    The EQuilibrium Criterion (EQC) model developed and published in 1996 was recently revised to include improved treatment of input partitioning and reactivity data, temperature dependence and an easier sensitivity and uncertainty analysis. This New EQC model was used to evaluate the multimedia, fugacity-based fate of decamethylcyclopentasiloxane (D5; CAS No. 541-02-6) in the environment over a temperature range of 1-25°C. In addition, Monte Carlo uncertainty analysis was used to quantitatively determine the influence of temperature and input partitioning and reactivity data on the behavior of D5 under various emission scenarios. Results indicated that emission mode was the most influential factor determining the fate and distribution of D5 in the model environment. When emitted to air and soil, D5 partitioned to and remained in the air compartment where rates of removal from degradation and advection processes were relatively rapid. In contrast, D5 emitted to water resulted in a substantial mass fraction of D5 being accumulated in the sediment compartment, where rates of removal from degradation and advection processes were slow. The mass distributions and fate of D5 in the model environment were strongly influenced by multiple input parameters, including temperature, the mode of emission (especially emission rate to water), KOC and half-life in air. As temperature decreased from 25°C to 1°C, KOC and half-life in air became increasingly more influential such that the mass distribution of D5 increased in air and decreased in sediment, resulting in decreased overall persistence. Copyright © 2012 Elsevier Ltd. All rights reserved.

  13. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...... in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from......-term time series of which there are only two exceeding 20 a. We use the data to analyse uncertainties in point measurements of surface mass balance, as well as to estimate surface mass-balance profiles for most regions of Greenland....

  14. Reversible uptake of molecular oxygen by heteroligand Co(II)-L-α-amino acid-imidazole systems: equilibrium models at full mass balance.

    Science.gov (United States)

    Pająk, Marek; Woźniczka, Magdalena; Vogt, Andrzej; Kufelnicki, Aleksander

    2017-09-19

    The paper examines Co(II)-amino acid-imidazole systems (where amino acid = L-α-amino acid: alanine, asparagine, histidine) which, when in aqueous solutions, activate and reversibly take up dioxygen, while maintaining the structural scheme of the heme group (imidazole as axial ligand and O 2 uptake at the sixth, trans position) thus imitating natural respiratory pigments such as myoglobin and hemoglobin. The oxygenated reaction shows higher reversibility than for Co(II)-amac systems with analogous amino acids without imidazole. Unlike previous investigations of the heteroligand Co(II)-amino acid-imidazole systems, the present study accurately calculates all equilibrium forms present in solution and determines the [Formula: see text]equilibrium constants without using any simplified approximations. The equilibrium concentrations of Co(II), amino acid, imidazole and the formed complex species were calculated using constant data obtained for analogous systems under oxygen-free conditions. Pehametric and volumetric (oxygenation) studies allowed the stoichiometry of O 2 uptake reaction and coordination mode of the central ion in the forming oxygen adduct to be determined. The values of dioxygen uptake equilibrium constants [Formula: see text] were evaluated by applying the full mass balance equations. Investigations of oxygenation of the Co(II)-amino acid-imidazole systems indicated that dioxygen uptake proceeds along with a rise in pH to 9-10. The percentage of reversibility noted after acidification of the solution to the initial pH ranged within ca 30-60% for alanine, 40-70% for asparagine and 50-90% for histidine, with a rising tendency along with the increasing share of amino acid in the Co(II): amino acid: imidazole ratio. Calculations of the share of the free Co(II) ion as well as of the particular complex species existing in solution beside the oxygen adduct (regarding dioxygen bound both reversibly and irreversibly) indicated quite significant values for the

  15. A nitrogen mass balance for California

    Science.gov (United States)

    Liptzin, D.; Dahlgren, R. A.

    2010-12-01

    , requires a net influx of N in feed to the state. In terms of exports, the riverine N loads are smaller than many more mesic climates. Because many of the large population centers are on the coast, N discharged directly from wastewater treatment plants into the ocean is almost four times greater than the N discharge of all of the watersheds in the state combined. Gas losses are estimated through a combination of bottom up approaches using field data, emissions inventories, and numerical models. The largest uncertainties are in emissions of N2 and NH3. Calculated by difference, groundwater N loading represents the largest loss term in the mass balance. Contamination of groundwater with nitrates is a serious concern in many areas of the state. Given the long residence time of groundwater in many aquifers like the Central Valley the current and past N inputs to groundwater pose a hazard to drinking water supplies for decades to come. These calculations along with the analysis of management and policy tools will help elucidate the spatial location or activities that would be best to target to reduce the negative consequences of human alteration of the nitrogen cycle.

  16. Sforzellina Glaciers: Glacial Geomorfology, Mass Balance, Frontal Variations and Dendroglaciology

    Science.gov (United States)

    Diolaiuti, G.; D'Agata, C.; Smiraglia, C.; Santilli, M. Pelfini M.

    The Sforzellina Glacier is a small cirque glacier located in Gavia Valley, in the Lom- bardy side of the Ortles-Cevedale Group (Italy). Although its modest dimensions, it is an important source of glaciological and geomorphological data; it is in fact moni- torated over a long time, more than seventy years, by the Italian Glaciological Com- mitteeSs (CGI) relatively to the frontal variations and so now is available a complete data set that was used in order to calculate the correlation with other alpine italian glaciers. The analysis allowed to estimate that this small cirque glacier is in phase with a large number of alpine glacial bodies. The glacier had a continuous and un- interrupted retreating phase from 1925 to the beginning of the 70s of XXth century when a frontal progress phase started. This new trend culminated in 1985 and finished in 1987. From that year the glacier resumed a continuous and uninterrupted frontal retreat. From 1925 to 2000 the glacier retreated was of 379 m. From 1987 up to now Sforzellina is used as a sample glacier for mass balance measurements and all the data (15 years of mass balance data) were correlated with the other Italian and European mass balance data; this analysis allowed to notice that this glacier was strongly corre- lated with many of the monitorated alpine glaciers located in the same climatic region. This result suggests to continue the monitoring of Sforzellina as important climatic and environmental index and suggests to use the data in order to calcolate matemathi- cal models to create alpine glacier scenaries. From 1987 to 2000 the Sforzellina mass balances were constantly negative. In the hydrological year 2000-2001 there was a change in mass balance trend with a moderately positive mass balance. In 15 years the glacier lost a thickness of about 13 m w.e. In the summers 1999 and 2000 the glacier was studied by means of sysmic and radar geophysical surveys to determinate the thickness, that was resulted of about 40

  17. A reconciled estimate of ice-sheet mass balance

    DEFF Research Database (Denmark)

    Shepherd, Andrew; Ivins, Erik R; A, Geruo

    2012-01-01

    We combined an ensemble of satellite altimetry, interferometry, and gravimetry data sets using common geographical regions, time intervals, and models of surface mass balance and glacial isostatic adjustment to estimate the mass balance of Earth's polar ice sheets. We find that there is good...... agreement between different satellite methods--especially in Greenland and West Antarctica--and that combining satellite data sets leads to greater certainty. Between 1992 and 2011, the ice sheets of Greenland, East Antarctica, West Antarctica, and the Antarctic Peninsula changed in mass by -142 ± 49, +14...... ± 43, -65 ± 26, and -20 ± 14 gigatonnes year(-1), respectively. Since 1992, the polar ice sheets have contributed, on average, 0.59 ± 0.20 millimeter year(-1) to the rate of global sea-level rise....

  18. A Reconciled Estimate of Ice-Sheet Mass Balance

    Science.gov (United States)

    Shepherd, Andrew; Ivins, Erik R.; Geruo, A.; Barletta, Valentia R.; Bentley, Mike J.; Bettadpur, Srinivas; Briggs, Kate H.; Bromwich, David H.; Forsberg, Rene; Galin, Natalia; hide

    2012-01-01

    We combined an ensemble of satellite altimetry, interferometry, and gravimetry data sets using common geographical regions, time intervals, and models of surface mass balance and glacial isostatic adjustment to estimate the mass balance of Earth's polar ice sheets. We find that there is good agreement between different satellite methods-especially in Greenland and West Antarctica-and that combining satellite data sets leads to greater certainty. Between 1992 and 2011, the ice sheets of Greenland, East Antarctica, West Antarctica, and the Antarctic Peninsula changed in mass by -142 plus or minus 49, +14 plus or minus 43, -65 plus or minus 26, and -20 plus or minus 14 gigatonnes year(sup -1), respectively. Since 1992, the polar ice sheets have contributed, on average, 0.59 plus or minus 0.20 millimeter year(sup -1) to the rate of global sea-level rise.

  19. An isotope mass balance model for the correlation of freshwater bivalve shell (Unio pictorum carbonate δ18O to climatic conditions and water δ18O in Lake Balaton (Hungary

    Directory of Open Access Journals (Sweden)

    Gabriella SCHÖLL-BARNA

    2011-08-01

    Full Text Available The oxygen isotope composition of bivalve shells (δ18Oshell can potentially record environmental variability of shallow lakes and therefore it has been extensively used as a proxy in the reconstruction of past climate and environmental conditions. As δ18Oshell reflects - besides the water temperature - the oxygen isotope composition of lake water (δ18OL, it is required to interpret the quality and impact of parameters influencing the δ18OL. Using the isotope mass balance model, I tested the hypothesis that Balaton lake water δ18O variability can be described as a result of the combined effects of three main climatic parameters such as river runoff, precipitation and evaporation. I calculated δ18OL time series for the period 1999-2008 for the whole water body at Siófok (eastern part of Lake Balaton, Hungary based on measured precipitation, inflow and evaporation amount and measured inflow, precipitation δ18O and calculated vapour δ18O data. The comparison of the modelled δ18OL time series to measured surface δ18OL data revealed that δ18O of Balaton water is sensitive for variation of climatic parameters. This variability is most striking at the surface, while according to the results of the model, the whole water body itself is less sensitive. Monthly differences suggest that generally during summer the whole water body is mixed up, while moderate isotope stratification (0.3-0.7‰ difference between surface and whole water body can be assumed in early spring and autumn. Predictions of shell δ18O values were made using the measured surface water δ18O data and the modelled δ18O values for the whole water body. High-resolution sampling was conducted on two Unio pictorum shells covering the period of 2001-2008, and both predictions were compared to measured shell δ18O records. The results showed that the prediction for the whole water body gives a better fit to the measured shell δ18O, suggesting that the whole water body better

  20. Composting: Mass Balances and Product Quality

    DEFF Research Database (Denmark)

    Boldrin, Alessio; Christensen, Thomas Højlund; Körner, I.

    2011-01-01

    While the basic processes involved in composting of waste are described in Chapter 9.1 and the main composting technologies are presented in Chapter 9.2, this chapter focuses on mass balances, environmental emissions, unit process inventories and the quality of the compost produced. Understanding...... these issues and being able to account for them is a prerequisite in compost engineering and for establishing and running a successful composting facility. Of specific importance is the final use of the compost product. Use in agriculture is described in Chapter 9.10 and the use of compost in soil amendment...

  1. Numerical modeling of late Glacial Laurentide advance of ice across Hudson Strait: Insights into terrestrial and marine geology, mass balance, and calving flux

    Science.gov (United States)

    Pfeffer, W.T.; Dyurgerov, M.; Kaplan, M.; Dwyer, J.; Sassolas, C.; Jennings, A.; Raup, B.; Manley, W.

    1997-01-01

    A time-dependent finite element model was used to reconstruct the advance of ice from a late Glacial dome on northern Quebec/Labrador across Hudson Strait to Meta Incognita Peninsula (Baffin Island) and subsequently to the 9.9-9.6 ka 14C Gold Cove position on Hall Peninsula. Terrestrial geological and geophysical information from Quebec and Labrador was used to constrain initial and boundary conditions, and the model results are compared with terrestrial geological information from Baffin Island and considered in the context of the marine event DC-0 and the Younger Dryas cooling. We conclude that advance across Hudson Strait from Ungava Bay to Baffin Island is possible using realistic glacier physics under a variety of reasonable boundary conditions. Production of ice flux from a dome centered on northeastern Quebec and Labrador sufficient to deliver geologically inferred ice thickness at Gold Cove (Hall Peninsula) appears to require extensive penetration of sliding south from Ungava Bay. The discharge of ice into the ocean associated with advance and retreat across Hudson Strait does not peak at a time coincident with the start of the Younger Dryas and is less than minimum values proposed to influence North Atlantic thermohaline circulation; nevertheless, a significant fraction of freshwater input to the North Atlantic may have been provided abruptly and at a critical time by this event.

  2. Haematological and Serum Bio-Chemical Parameters of West ...

    African Journals Online (AJOL)

    Haematological and Serum Bio-Chemical Parameters of West African Dwarf and Kalahari Red Goats in the Humid Tropics. ... Haematological results showed that white blood cell count, haemoglobin concentration, haematocrit, mean corpuscular volume, mean corpuscular haemoglobin and mean corpuscular haemoglobin ...

  3. Study of interfacial phenomena for bio/chemical sensing applications

    Science.gov (United States)

    Min, Hwall

    This work presents the fundamental study of biological and chemical interfacial phenomena and (bio)chemical sensing applications using high frequency resonator arrays. To realize a versatile (bio)chemical sensing system for the fundamental study as well as their practical applications, the following three distinct components were studied and developed: i) detection platforms with high sensitivity, ii) novel innovative sensing materials with high selectivity, iii) analytical model for data interpretation. 8-pixel micromachined quartz crystal resonator (muQCR) arrays with a fundamental resonance frequency of 60 ¡V 90 MHz have been used to provide a reliable detection platform with high sensitivity. Room temperature ionic liquid (RTIL) has been explored and integrated into the sensing system as a smart chemical sensing material. The use of nanoporous gold (np-Au) enables the combination of the resonator and surface-enhanced Raman spectroscopy for both quantitative and qualitative measurement. A statistical model for the characterization of resonator behavior to study the protein adsorption kinetics is developed by random sequential adsorption (RSA) approach with the integration of an effective surface depletion theory. The investigation of the adsorption kinetics of blood proteins is reported as the fundamental study of biological phenomena using the proposed sensing system. The aim of this work is to study different aspects of protein adsorption and kinetics of adsorption process with blood proteins on different surfaces. We specifically focus on surface depletion effect in conjunction with the RSA model to explain the observed adsorption isotherm characteristics. A number of case studies on protein adsorption conducted using the proposed sensing system has been discussed. Effort is specifically made to understand adsorption kinetics, and the effect of surface on the adsorption process as well as the properties of the adsorbed protein layer. The second half of the

  4. Anaerobic Digestion: Mass Balances and Products

    DEFF Research Database (Denmark)

    Møller, Jacob; Christensen, Thomas Højlund; Jansen, Jes la Cour

    2011-01-01

    While the basic processes involved in anaerobic digestion of waste are described in Chapter 9.4 and the main digestion technologies are presented in Chapter 9.5, this chapter focuses on mass balances, gas production and energy aspects, environmental emissions and unit process inventories....... Understanding these issues and being able to account for them is a prerequisite in digestion engineering and for establishing and running a successful anaerobic digestion facility. Of specific importance is the final use of the digestate. Use in agriculture as a fertilizer is described in Chapter 9.10 and use...... after composting of the digestate as a soil amendment product is analogous to issues presented in Chapter 9.9 for compost....

  5. The Ice Sheet Mass Balance Inter-comparison Exercise

    Science.gov (United States)

    Shepherd, A.; Ivins, E. R.

    2015-12-01

    Fluctuations in the mass of ice stored in Antarctica and Greenland are of considerable societal importance. The Ice Sheet Mass Balance Inter-Comparison Exercise (IMBIE) is a joint-initiative of ESA and NASA aimed at producing a single estimate of the global sea level contribution to polar ice sheet losses. Within IMBIE, estimates of ice sheet mass balance are developed from a variety of satellite geodetic techniques using a common spatial and temporal reference frame and a common appreciation of the contributions due to external signals. The project brings together the laboratories and space agencies that have been instrumental in developing independent estimates of ice sheet mass balance to date. In its first phase, IMBIE involved 27 science teams, and delivered a first community assessment of ice sheet mass imbalance to replace 40 individual estimates. The project established that (i) there is good agreement between the three main satellite-based techniques for estimating ice sheet mass balance, (ii) combining satellite data sets leads to significant improvement in certainty, (iii) the polar ice sheets contributed 11 ± 4 mm to global sea levels between 1992 and 2012, and (iv) that combined ice losses from Antarctica and Greenland have increased over time, rising from 10% of the global trend in the early 1990's to 30% in the late 2000's. Demand for an updated assessment has grown, and there are now new satellite missions, new geophysical corrections, new techniques, and new teams producing data. The period of overlap between independent satellite techniques has increased from 5 to 12 years, and the full period of satellite data over which an assessment can be performed has increased from 19 to 40 years. It is also clear that multiple satellite techniques are required to confidently separate mass changes associated with snowfall and ice dynamical imbalance - information that is of critical importance for climate modelling. This presentation outlines the approach

  6. Reconstructing mass balance of Garabashi Glacier (1800–2005 using dendrochronological data

    Directory of Open Access Journals (Sweden)

    E. A. Dolgova

    2013-01-01

    Full Text Available The exploration whether tree-ring data can be effectually applied for the mass balance reconstruction in Caucasus was the main goal of this research. Tree-ring width and maximum density chronologies of pine (Pinus sylvestris L. at seven high-elevation sites in Northern Caucasus were explored for this purpose. As well as in other places of the temperate zone tree- ring width has complex climate signal controlled both temperature and precipitation. Instrumental mass balance records of Garabashi Gglacier started at 1983s. It is well known that Caucasus glaciers intensively retreat in the last decades and according to instrumental data mass balance variations are mostly controlled by the ablation, i.e. summer temperature variations. Maximum density chronology has statistically significant correlation with mass balance due to summer temperature sensitivity and great input of ablation to total mass balance variations. To include in our reconstruction different climatically sensitive parameters, stepwise multiple regression model was used. The strongest relation (r = 0.88; r2 = 0.78; p < 0.05 between two ring-width and one maximum density chronologies was identified. Cross-validation test (r = 0.79; r2 = 0.62; p < 0.05 confirmed model adequacy and it allowed to reconstruct Garabashi Glacier mass balance for 1800–2005ss. Reconstructed and instrumental mass balance values coincide well except the most recent period in 2000s, when the reconstructed mass balance slightly underestimated the real values. However even in this period it remained negative as well as the instrumental records. The bias can be explained by the weak sensitivity of the chronologies to winter precipitation (i.e. accumulation. The tree-ring based mass balance reconstruction was compared with one based on meteorological data (since 1905s. Both reconstructions have good interannual agreement (r = 0.53; p < 0.05 particularly for the period between 1975 and 2005. According to the

  7. Reconstruction of specific mass balance for glaciers in Western ...

    Indian Academy of Sciences (India)

    Vinay Kumar Gaddam

    2017-06-12

    Jun 12, 2017 ... temperatures and precipitation estimates of ERA 20CM ensemble climate reanalysis datasets to reconstruct the specific mass balance for a period of 110 years, between 1900 and 2010. Mass balance estimates suggest that the Shaune Garang, Gor-Garang and Gara glaciers have experienced both ...

  8. Local reduction of decadal glacier thickness loss through mass balance management in ski resorts

    Science.gov (United States)

    Fischer, Andrea; Helfricht, Kay; Stocker-Waldhuber, Martin

    2016-11-01

    For Austrian glacier ski resorts, established in the 1970s and 1980s during a period of glacier advance, negative mass balances with resulting glacier area loss and decrease in surface elevation present an operational challenge. Glacier cover, snow farming, and technical snow production were introduced as adaptation measures based on studies on the effect of these measures on energy and mass balance. After a decade of the application of the various measures, we studied the transition from the proven short-term effects of the measures on mass balance to long-term effects on elevation changes. Based on lidar digital elevation models and differential GPS measurements, decadal surface elevation changes in 15 locations with mass balance management were compared to those without measures (apart from piste grooming) in five Tyrolean ski resorts on seven glaciers. The comparison of surface elevation changes presents clear local differences in mass change, and it shows the potential to retain local ice thickness over 1 decade. Locally up to 21.1 m ± 0.4 m of ice thickness was preserved on mass balance managed areas compared to non-maintained areas over a period of 9 years. In this period, mean annual thickness loss in 15 of the mass balance managed profiles is 0.54 ± 0.04 m yr-1 lower (-0.23 ± 0.04 m yr-1on average) than in the respective reference areas (-0.78 ± 0.04 m yr-1). At two of these profiles the surface elevation was preserved altogether, which is promising for a sustainable maintenance of the infrastructure at glacier ski resorts. In general the results demonstrate the high potential of the combination of mass balance management by snow production and glacier cover, not only in the short term but also for multi-year application to maintain the skiing infrastructure.

  9. Recent Changes in Ices Mass Balance of the Amundsen Sea Sector

    Science.gov (United States)

    Sutterley, T. C.; Velicogna, I.; Rignot, E. J.; Mouginot, J.; Flament, T.; van den Broeke, M. R.; van Wessem, M.; Reijmer, C.

    2014-12-01

    The glaciers flowing into the Amundsen Sea Embayment (ASE) sector of West Antarctica were confirmed in the Ice Sheet Mass Balance Inter-comparison Exercise (IMBIE) to be the dominant contributors to the current Antarctic ice mass loss, and recently recognized to be undergoing marine ice sheet instability. Here, we investigate their regional ice mass balance using a time series of satellite and airborne data combined with model output products from the Regional Atmospheric and Climate Model (RACMO). Our dataset includes laser altimetry from NASA's ICESat-1 satellite mission and from Operation IceBridge (OIB) airborne surveys, satellite radar altimetry data from ESA's Envisat mission, time-variable gravity data from NASA/DLR's GRACE mission, surface mass balance products from RACMO, ice velocity from a combination of international synthetic aperture radar satellites and ice thickness data from OIB. We find a record of ice mass balance for the ASE where all the analyzed techniques agree remarkably in magnitude and temporal variability. The mass loss of the region has been increasing continuously since 1992, with no indication of a slow down. The mass loss during the common period averaged 91 Gt/yr and accelerated 20 Gt/yr2. In 1992-2013, the ASE contributed 4.5 mm global sea level rise. Overall, our results demonstrate the synergy of multiple analysis techniques for examining Antarctic Ice Sheet mass balance at the regional scale. This work was performed at UCI and JPL under a contract with NASA.

  10. Mass balance re-analysis of Findelengletscher, Switzerland; benefits of extensive snow accumulation measurements

    Directory of Open Access Journals (Sweden)

    Leo eSold

    2016-02-01

    Full Text Available A re-analysis is presented here of a 10-year mass balance series at Findelengletscher, a temperate mountain glacier in Switzerland. Calculating glacier-wide mass balance from the set of glaciological point balance observations using conventional approaches, such as the profile or contour method, resulted in significant deviations from the reference value given by the geodetic mass change over a five-year period. This is attributed to the sparsity of observations at high elevations and to the inability of the evaluation schemes to adequately estimate accumulation in unmeasured areas. However, measurements of winter mass balance were available for large parts of the study period from snow probings and density pits. Complementary surveys by helicopter-borne ground-penetrating radar (GPR were conducted in three consecutive years. The complete set of seasonal observations was assimilated using a distributed mass balance model. This model-based extrapolation revealed a substantial mass loss at Findelengletscher of -0.43m w.e. a^-1 between 2004 and 2014, while the loss was less pronounced for its former tributary, Adlergletscher (-0.30m w.e. a^-1. For both glaciers, the resulting time series were within the uncertainty bounds of the geodetic mass change. We show that the model benefited strongly from the ability to integrate seasonal observations. If no winter mass balance measurements were available and snow cover was represented by a linear precipitation gradient, the geodetic mass balance was not matched. If winter balance measurements by snow probings and snow density pits were taken into account, the model performance was substantially improved but still showed a significant bias relative to the geodetic mass change. Thus the excellent agreement of the model-based extrapolation with the geodetic mass change was owed to an adequate representation of winter accumulation distribution by means of extensive GPR measurements.

  11. Estimates of Ice Sheet Mass Balance from Satellite Altimetry: Past and Future

    Science.gov (United States)

    Zwally, H. Jay; Zukor, Dorothy J. (Technical Monitor)

    2001-01-01

    A major uncertainty in predicting sea level rise is the sensitivity of ice sheet mass balance to climate change, as well as the uncertainty in present mass balance. Since the annual water exchange is about 8 mm of global sea level equivalent, the 20% uncertainty in current mass balance corresponds to 1.6 mm/yr in sea level change. Furthermore, estimates of the sensitivity of the mass balance to temperature change range from perhaps as much as - 10% to + 10% per K. A principal purpose of obtaining ice sheet elevation changes from satellite altimetry has been estimation of the current ice sheet mass balance. Limited information on ice sheet elevation change and their implications about mass balance have been reported by several investigators from radar altimetry (Seasat, Geosat, ERS-1&2). Analysis of ERS-1&2 data over Greenland for 7 years from 1992 to 1999 shows mixed patterns of ice elevation increases and decreases that are significant in terms of regional-scale mass balances. Observed seasonal and interannual variations in ice surface elevation are larger than previously expected because of seasonal and interannUal variations in precipitation, melting, and firn compaction. In the accumulation zone, the variations in firn compaction are modeled as a function of temperature leaving variations in precipitation and the mass balance trend. Significant interannual variations in elevation in some locations, in particular the difference in trends from 1992 to 1995 compared to 1995 to 1999, can be explained by changes in precipitation over Greenland. Over the 7 years, trends in elevation are mostly positive at higher elevations and negative at lower elevations. In addition, trends for the winter seasons (from a trend analysis through the average winter elevations) are more positive than the corresponding trends for the summer. At lower elevations, the 7-year trends in some locations are strongly negative for summer and near zero or slightly positive for winter. These

  12. Mass-Balance Constraints on Nutrient Cycling in Tropical Seagrass Beds

    NARCIS (Netherlands)

    Erftemeijer, P.L.A.; Middelburg, J.J.

    1995-01-01

    A relatively simple mass balance model is presented to study the cycling of nutrients (nitrogen and phosphorus) in tropical seagrass beds. The model is based on quantitative data on nutrient availability, seagrass primary production, community oxygen metabolism, seagrass tissue nutrient contents,

  13. Trends in ice sheet mass balance, 1992 to 2017

    Science.gov (United States)

    Shepherd, A.; Ivins, E. R.; Smith, B.; Velicogna, I.; Whitehouse, P. L.; Rignot, E. J.; van den Broeke, M. R.; Briggs, K.; Hogg, A.; Krinner, G.; Joughin, I. R.; Nowicki, S.; Payne, A. J.; Scambos, T.; Schlegel, N.; Moyano, G.; Konrad, H.

    2017-12-01

    The Ice Sheet Mass Balance Inter-Comparison Exercise (IMBIE) is a community effort, jointly supported by ESA and NASA, that aims to provide a consensus estimate of ice sheet mass balance from satellite gravimetry, altimetry and mass budget assessments, on an annual basis. The project has five experiment groups, one for each of the satellite techniques and two others to analyse surface mass balance (SMB) and glacial isostatic adjustment (GIA). The basic premise for the exercise is that individual ice sheet mass balance datasets are generated by project participants using common spatial and temporal domains to allow meaningful inter-comparison, and this controlled comparison in turn supports aggregation of the individual datasets over their full period. Participation is open to the full community, and the quality and consistency of submissions is regulated through a series of data standards and documentation requirements. The second phase of IMBIE commenced in 2015, with participant data submitted in 2016 and a combined estimate due for public release in 2017. Data from 48 participant groups were submitted to one of the three satellite mass balance technique groups or to the ancillary dataset groups. The individual mass balance estimates and ancillary datasets have been compared and combined within the respective groups. Following this, estimates of ice sheet mass balance derived from the individual techniques were then compared and combined. The result is single estimates of ice sheet mass balance for Greenland, East Antarctica, West Antarctica, and the Antarctic Peninsula. The participants, methodology and results of the exercise will be presented in this paper.

  14. Juneau Icefield Mass Balance Program 1946-2011

    Science.gov (United States)

    Pelto, M.; Kavanaugh, J.; McNeil, C.

    2013-11-01

    The annual surface mass balance records of the Lemon Creek Glacier and Taku Glacier observed by the Juneau Icefield Research Program are the longest continuous glacier annual mass balance data sets in North America. Annual surface mass balance (Ba) measured on Taku Glacier averaged +0.40 m a-1 from 1946-1985, and -0.08 m a-1 from 1986-2011. The recent annual mass balance decline has resulted in the cessation of the long-term thickening of the glacier. Mean Ba on Lemon Creek Glacier has declined from -0.30 m a-1 for the 1953-1985 period to -0.60 m a-1 during the 1986-2011 period. The cumulative change in annual surface mass balance is -26.6 m water equivalent, a 29 m of ice thinning over the 55 yr. Snow-pit measurements spanning the accumulation zone, and probing transects above the transient snow line (TSL) on Taku Glacier, indicate a consistent surface mass balance gradient from year to year. Observations of the rate of TSL rise on Lemon Creek Glacier and Taku Glacier indicate a comparatively consistent migration rate of 3.8 to 4.1 m d-1. The relationship between TSL on Lemon Creek Glacier and Taku Glacier to other Juneau Icefield glaciers (Norris, Mendenhall, Herbert, and Eagle) is strong, with correlations exceeding 0.82 in all cases. doi:10.5065/D6NZ85N3

  15. Monthly solutions of ice sheet mass balance at basin scale – and their associated uncertainties

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Barletta, Valentina Roberta; Forsberg, René

    2012-01-01

    There are still discrepancies in published ice sheet mass balance results, even between ones based on the same data sets. It can be difficult to conclude from where the discrepancies arise, and it is therefore important to cross calibrate methods, data and models in order to determine...

  16. A California Nitrogen Mass Balance: Uncertainties and information needs

    Science.gov (United States)

    Liptzin, D.; Dahlgren, R. A.

    2011-12-01

    fixation or do not explicitly specify whether the measured rates are total N fixation or only aboveground fixation. There is medium evidence to estimate how much of the emitted NOx and ammonia is redeposited within California. The Community Multiscale Air Quality model is the standard for modeling atmospheric deposition, but is dependent on the quality of the emissions inventory used. There is less agreement among sources on ammonia emissions which will be increasingly problematic as reduced N emissions will soon outpace oxidized N emissions. There is high evidence for wastewater discharge and riverine discharge. Most wastewater facilities are required monitor their N discharge although they often only measure the N species with the highest concentration (either ammonia or nitrate) depending on the level of treatment. Riverine N concentrations and flow in large watersheds are monitored by the US Geological Survey and there are relatively small uncertainties in the model calculating N discharge from these parameters. We suggest that while the best estimate of a mass balance is important, an evaluation of the major uncertainties can be just as important.

  17. Basin-scale partitioning of Greenland ice sheet mass balance components (2007-2011)

    DEFF Research Database (Denmark)

    Andersen, M.L.; Stenseng, Lars; Skourup, Henriette

    2015-01-01

    The current deficit in Greenland ice sheet mass balance is due to both a decrease in surface mass balance (SMB) input and an increase in ice discharge (D) output. While SMB processes are beginning to be well captured by observationally-constrained climate modeling, insight into D is relatively...... of the gate. Using a 1961-1990 reference climatology SMB field from the MAR regional climate model, we quantify ice sheet mass balance within eighteen basins. We find a 2007-2011 mean D of 515±57 Gtyr-1. We find a 2007-2011 mean total mass balance of -262±21 Gtyr-1, which is equal to a 0.73 mm yr-1 global sea...... limited. We use InSAR-derived velocities, in combination with ice thickness observations, to quantify the mass flux (F) across a flux perimeter around the ice sheet at ~1700 m elevation. To quantify D, we correct F for SMB, as well as changes in volume due to ice dynamics, in the area downstream...

  18. Opportunities and Challenges in Enhancing Value of Annual Glacier Mass Balance Monitoring Examples from Western North America

    Science.gov (United States)

    Pelto, M. S.

    2017-12-01

    Alpine glacier mass balance is the most accurate indicator of glacier response to climate and with retreat of alpine glaciers is one of the clearest signals of global climate change. Completion of long term, representative and homogenous mass balance field measurement of mass balance, compiled by WGMS, is a key climate data record. To ensure a monitoring program remains vital and funded local collaboration and connecting the research to local societal impacts is crucial. Working with local partners in collecting and providing the right data is critical whether their interest is in hydropower, irrigation, municipal supply, hazard reduction and/or aquatic ecosystems. The expansion of remote sensing and modeling capability provides both a challenge to continued relevance and an opportunity for field mass balance programs to expand relevance. In modelling studies of both glacier mass balance and glacier runoff transient balance data has equivalent value with annual balance data, for both calibration runs and as an input variable. This increases the utility of mid-season field observations. Remote sensing provides repeat imagery that often identifies the AAR and transient snowline of a glacier. For runoff assessment understanding the specific percent of glacier surface area that is glacier ice, older firn, and retained snowpack from the previous winter at frequent intervals during the melt season is vital since each region has a different melt factor. A denser field observation network combined with this imagery can provide additional point balance values of ablation that complement the mass balance record. Periodic measurement of mass balance at a denser network using GPR, LIDAR, TLS or probing is required to better understand long term point balance locations and is important at end of the melt season not just beginning, and has value mid-season for modelling. Applications of each of utility of field mass balance observations will be illustrated.

  19. Mass balance at partial run of quartzite carbothermal reduction

    Directory of Open Access Journals (Sweden)

    J. Węgrzyn

    2016-04-01

    Full Text Available Mass balance for the process of incomplete carbothermal reduction of SiO2 to SiC thermogravimetric studies was presented. Tests were performed for the molar ratio of C/SiO2 = 3 at a temperature of 1 500 °C under an argon flow in the range from 0,1 to 3,4 dm3/min. Mass balance includes the loss due to escape of SiO and the mass of reactants C and SiO2 due to stopping the reaction. The weight gain of Al2O3 crucible was found and also the formation of crust layer on the surface of the samples. The crucible weight gain and the weight of crust layer created were taken into account in mass balance.

  20. Differences in mass balance behavior for three glaciers from different climatic regions on the Tibetan Plateau

    Science.gov (United States)

    Zhu, Meilin; Yao, Tandong; Yang, Wei; Xu, Baiqing; Wu, Guanjian; Wang, Xiaojun

    2017-07-01

    Glacier mass balance shows a spatially heterogeneous pattern in response to global warming on the Tibetan Plateau (TP), and the climate mechanisms controlling this pattern require further study. In this study, three glaciers where systematic glaciological and meteorological observations have been carried out were selected, specifically Parlung No. 4 (PL04) and Zhadang (ZD) glaciers on the southern TP and Muztag Ata No. 15 (MZ15) glacier in the eastern Pamir. The characteristics of the mass and energy balances of these three glaciers during the periods between October 1th, 2008 and September 23rd, 2013 were analyzed and compared using the energy and mass balance model. Results show that differences in surface melt, which mainly result from differences in the amounts of incoming longwave radiation (L in ) and outgoing shortwave radiation (S out ), represent the largest source of the observed differences in mass balance changes between PL04 and ZD glaciers and MZ15 glacier, where air temperature, humidity, precipitation and cloudiness are dramatically different. In addition, sensitivity experiments show that mass balance sensitivity to air temperature change is remarkably higher than that associated with precipitation change on PL04 and ZD glaciers, in contrast results from MZ15 glacier. And significantly higher sensitivities to air temperature change are noted for PL04 and ZD glaciers than for MZ15 glacier. These significant differences in the sensitivities to air temperature change are mainly caused by differences in the ratio of snowfall to precipitation during the ablation season, melt energy (L in +S out ) during the ablation season and the seasonality of precipitation among the different regions occupied by glaciers. In turn, these conditions are related to local climatic conditions, especially air temperature. These factors can be used to explain the different patterns of change in Tibetan glacier mass balance under global warming.

  1. Mass balance of the Antarctic ice sheet.

    Science.gov (United States)

    Wingham, D J; Shepherd, A; Muir, A; Marshall, G J

    2006-07-15

    The Antarctic contribution to sea-level rise has long been uncertain. While regional variability in ice dynamics has been revealed, a picture of mass changes throughout the continental ice sheet is lacking. Here, we use satellite radar altimetry to measure the elevation change of 72% of the grounded ice sheet during the period 1992-2003. Depending on the density of the snow giving rise to the observed elevation fluctuations, the ice sheet mass trend falls in the range -5-+85Gtyr-1. We find that data from climate model reanalyses are not able to characterise the contemporary snowfall fluctuation with useful accuracy and our best estimate of the overall mass trend-growth of 27+/-29Gtyr-1-is based on an assessment of the expected snowfall variability. Mass gains from accumulating snow, particularly on the Antarctic Peninsula and within East Antarctica, exceed the ice dynamic mass loss from West Antarctica. The result exacerbates the difficulty of explaining twentieth century sea-level rise.

  2. Reconstruction of specific mass balance for glaciers in Western ...

    Indian Academy of Sciences (India)

    Seasonal sensitivity characteristics (SSCs) were developed for Naradu, Shaune Garang, Gor Garang and Gara glaciers, Western Himalaya to quantify the changes in mean specific mass balance using monthly temperature and precipitation perturbations. The temperature sensitivities were observed high during summer ...

  3. 3D viscosity maps for Greenland and effect on GRACE mass balance estimates

    Science.gov (United States)

    van der Wal, Wouter; Xu, Zheng

    2016-04-01

    The GRACE satellite mission measures mass loss of the Greenland ice sheet. To correct for glacial isostatic adjustment numerical models are used. Although generally found to be a small signal, the full range of possible GIA models has not been explored yet. In particular, low viscosities due to a wet mantle and high temperatures due to the nearby Iceland hotspot could have a significant effect on GIA gravity rates. The goal of this study is to present a range of possible viscosity maps, and investigate the effect on GRACE mass balance estimates. Viscosity is derived using flow laws for olivine. Mantle temperature is computed from global seismology models, based on temperature derivatives for different mantle compositions. An indication for grain sizes is obtained by xenolith findings at a few locations. We also investigate the weakening effect of the presence of melt. To calculate gravity rates, we use a finite-element GIA model with the 3D viscosity maps and the ICE-5G loading history. GRACE mass balances for mascons in Greenland are derived with a least-squares inversion, using separate constraints for the inland and coastal areas in Greenland. Biases in the least-squares inversion are corrected using scale factors estimated from a simulation based on a surface mass balance model (Xu et al., submitted to The Cryosphere). Model results show enhanced gravity rates in the west and south of Greenland with 3D viscosity maps, compared to GIA models with 1D viscosity. The effect on regional mass balance is up to 5 Gt/year. Regional low viscosity can make present-day gravity rates sensitivity to ice thickness changes in the last decades. Therefore, an improved ice loading history for these time scales is needed.

  4. Studying the Effects of Amazonian Land Cover Change on Glacier Mass Balance in the Tropical Andes

    Science.gov (United States)

    Mark, B. G.; Fernandez, A.; Gabrielli, P.; Montenegro, A.; Postigo, J.; Hellstrom, R. A.

    2017-12-01

    Recent research has highlighted several ongoing environmental changes occurring across Tropical South America, including Andean glacier retreat, drought, as well as changes in land-use and land-cover. As the regional climate of the area is mostly characterized by land-ocean interactions, the atmospheric convection in the Amazon, and the effect of the Andes on circulation patterns, it follows that changes in one of those regions may affect the other. Most scholars who have studied the causes of tropical glaciers' fluctuations have not analyzed the linkages with changes in the Amazon with the same attention paid to the influence of Pacific sea surface temperature. Here we study the response of glacier surface mass balance in the Cordillera Blanca, Peru (10°S), to a scenario where the Amazonian rainforest is replaced by savannas. We ran climatic simulations at 2-km spatial resolution utilizing the Weather Research and Forecasting (WRF) model considering two scenarios: (a) control (CRTL), with today's rainforest extent; and (b) land cover change (LCC), where all the rainforest was replaced by savanna. WRF output was in turn ingested into a glacier energy and mass balance (GEMB) model that we validate by reconstructing both the accumulated mass balance from available observations, and the altitudinal distribution of mass balance in the region. Seasonal comparison between CRTL and LCC scenarios indicates that forest replacement by savanna results in more positive glacier mass balance. This shift to more positive mass balance contrasts with a (WRF) modeled rise in the elevation of the freezing line (0°C) between 30 to 120 m for the LCC scenario. Our results are surprising because most previous studies have shown that reducing Amazon forest cover diminishes rainfall and increases temperature, suggesting that glaciers should lose mass. We hypothesize and discuss implications of possible land-atmospheric processes that might drive this tropical glacier response to

  5. Fe and Cu isotope mass balances in the human body

    Science.gov (United States)

    Balter, V.; Albarede, F.; Jaouen, K.

    2011-12-01

    The ranges of the Fe and Cu isotope compositions in the human body are large, i.e. ~3% and ~2%, respectively. Both isotopic fractionations appear to be mainly controlled by redox conditions. The Fe and Cu isotope compositions of the tissues analyzed so far plot on a mixing hyperbolae between a reduced and an oxidized metals pools. The reduced metals pool is composed by erythrocytes, where Fe is bounded to hemoglobin as Fe(II) and Cu to superoxide-dismutase as Cu(I). The oxidized metals pool is composed by hepatocytes, where Fe and Cu are stored as Fe(III) ferritin and as Cu(II) ceruloplasmine, respectively. The position of each biological component in the δ56Fe-δ65Cu diagram therefore reflects the oxidation state of Fe and Cu of the predominant metal carrier protein and allows to quantify Fe and Cu fluxes between organs using mass balance calculations. For instance, serum and clot Fe and Cu isotope compositions show that current biological models of erythropoiesis violates mass conservation requirements, and suggest hidden Fe and Cu pathways during red blood cells synthesis. The results also show that a coupled Fe-Cu strong gender isotopic effect is observed in various organs. The isotopic difference between men and women is unlikely to be due to differential dietary uptake or endometrium loss, but rather reflects the effect of menstrual losses and a correlative solicitation of hepatic stores. We speculate that thorough studies of the metabolism of stable isotopes in normal conditions is a prerequisite for the understanding of the pathological dysregulations.

  6. The impact of Saharan dust and black carbon on albedo and long-term mass balance of an Alpine glacier

    Directory of Open Access Journals (Sweden)

    J. Gabbi

    2015-07-01

    Full Text Available Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e., mineral dust and black carbon (BC, on albedo and glacier mass balance. The analysis was performed over the period 1914–2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100-year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the effects of melt and accumulation processes on the impurity concentration at the surface and thus on albedo and glacier mass balance. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04–0.06 depending on the location on the glacier. Consequently, annual melt was increased by 15–19 %, and the mean annual mass balance was reduced by about 280–490 mm w.e. BC clearly dominated absorption which is about 3 times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust and BC-enriched layers due to frequent years with negative mass balances.

  7. Autonomous Ice Mass Balance Observations for Changing Arctic Sea Ice Conditions

    Science.gov (United States)

    Whitlock, J. D.; Planck, C.; Perovich, D. K.; Richter-Menge, J.; Elder, B. C.; Polashenski, C.

    2016-12-01

    Results from observational data and predictive models agree: the state of the Arctic sea ice cover is in transition with a major shift from thick multiyear ice to thinner seasonal ice. The ice mass-balance represents the integration of all surface and ocean heat fluxes, and frequent temporal measurement can aid in attributing the impact of these forcing fluxes on the ice cover. Autonomous Ice Mass Balance buoys (IMB's) have proved to be important measurement tools allowing in situ, long-term data collection at multiple locations. Seasonal IMB's (SIMB's) are free floating versions of the IMB that allow data collection in thin ice and during times of transition. To accomplish this a custom computer was developed to integrate the scientific instruments, power management, and data communications while providing expanded autonomous functionality. This new design also allows for the easy incorporation of other sensors. Additionally, the latest generation of SIMB includes improvements to make it more stable, longer lasting, easier to deploy, and less expensive. Models can provide important insights as to where to deploy the sea ice mass balance buoys and what measurements are the most important. The resulting dataset from the buoys can be used to inform and assess model results.

  8. A spatially resolved estimate of High Mountain Asia glacier mass balances from 2000 to 2016

    Science.gov (United States)

    Brun, Fanny; Berthier, Etienne; Wagnon, Patrick; Kääb, Andreas; Treichler, Désirée

    2017-09-01

    High Mountain Asia hosts the largest glacier concentration outside the polar regions. These glaciers are important contributors to streamflow in one of the most populated areas of the world. Past studies have used methods that can provide only regionally averaged glacier mass balances to assess the glacier contribution to rivers and sea level rise. Here we compute the mass balance for about 92% of the glacierized area of High Mountain Asia using time series of digital elevation models derived from satellite stereo-imagery. We calculate a total mass change of -16.3 +/- 3.5 Gt yr-1 (-0.18 +/- 0.04 m w.e. yr-1) between 2000 and 2016, which is less negative than most previous estimates. Region-wide mass balances vary from -4.0 +/- 1.5 Gt yr-1 (-0.62 +/- 0.23 m w.e. yr-1) in Nyainqentanglha to +1.4 +/- 0.8 Gt yr-1 (+0.14 +/- 0.08 m w.e. yr-1) in Kunlun, with large intra-regional variability of individual glacier mass balances (standard deviation within a region ~0.20 m w.e. yr-1). Specifically, our results shed light on the Nyainqentanglha and Pamir glacier mass changes, for which contradictory estimates exist in the literature. They provide crucial information for the calibration of the models used for projecting glacier response to climatic change, as these models do not capture the pattern, magnitude and intra-regional variability of glacier changes at present.

  9. Advanced nanoporous materials for micro-gravimetric sensing to trace-level bio/chemical molecules.

    Science.gov (United States)

    Xu, Pengcheng; Li, Xinxin; Yu, Haitao; Xu, Tiegang

    2014-10-13

    Functionalized nanoporous materials have been developed recently as bio/chemical sensing materials. Due to the huge specific surface of the nano-materials for molecular adsorption, high hopes have been placed on gravimetric detection with micro/nano resonant cantilevers for ultra-sensitive sensing of low-concentration bio/chemical substances. In order to enhance selectivity of the gravimetric resonant sensors to the target molecules, it is crucial to modify specific groups onto the pore-surface of the nano-materials. By loading the nanoporous sensing material onto the desired region of the mass-type transducers like resonant cantilevers, the micro-gravimetric bio/chemical sensors can be formed. Recently, such micro-gravimetric bio/chemical sensors have been successfully applied for rapid or on-the-spot detection of various bio/chemical molecules at the trace-concentration level. The applicable nanoporous sensing materials include mesoporous silica, zeolite, nanoporous graphene oxide (GO) and so on. This review article focuses on the recent achievements in design, preparation, functionalization and characterization of advanced nanoporous sensing materials for micro-gravimetric bio/chemical sensing.

  10. Advanced Nanoporous Materials for Micro-Gravimetric Sensing to Trace-Level Bio/Chemical Molecules

    Directory of Open Access Journals (Sweden)

    Pengcheng Xu

    2014-10-01

    Full Text Available Functionalized nanoporous materials have been developed recently as bio/chemical sensing materials. Due to the huge specific surface of the nano-materials for molecular adsorption, high hopes have been placed on gravimetric detection with micro/nano resonant cantilevers for ultra-sensitive sensing of low-concentration bio/chemical substances. In order to enhance selectivity of the gravimetric resonant sensors to the target molecules, it is crucial to modify specific groups onto the pore-surface of the nano-materials. By loading the nanoporous sensing material onto the desired region of the mass-type transducers like resonant cantilevers, the micro-gravimetric bio/chemical sensors can be formed. Recently, such micro-gravimetric bio/chemical sensors have been successfully applied for rapid or on-the-spot detection of various bio/chemical molecules at the trace-concentration level. The applicable nanoporous sensing materials include mesoporous silica, zeolite, nanoporous graphene oxide (GO and so on. This review article focuses on the recent achievements in design, preparation, functionalization and characterization of advanced nanoporous sensing materials for micro-gravimetric bio/chemical sensing.

  11. Mass balance of the Amitsulôq ice cap, West Greenland

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Bøggild, Carl Egede; Olesen, Ole B.

    2007-01-01

    We present detailed mass balance measurements from the Amitsulôq ice cap in West Greenland spanning from 1982 to 1990. The data includes summer and winter balances from 26 stake locations distributed over five transects covering the whole ice cap. The mass balance measurements are combined...... with a recent satellite-derived digital elevation model to calculate the specific balance, which is in turn compared to discharge data from the adjacent Tasersiaq basin. The correlation between specific summer balance and discharge is R2 = 0.93 indicating that the basin discharge is dominated by glacial...... meltwater, linking the hydropower potential of the basin closely to the fate of the adjoining Greenland ice-sheet margin....

  12. Autonomous Ice Mass Balance Buoys for Seasonal Sea Ice

    Science.gov (United States)

    Whitlock, J. D.; Planck, C.; Perovich, D. K.; Parno, J. T.; Elder, B. C.; Richter-Menge, J.; Polashenski, C. M.

    2017-12-01

    The ice mass-balance represents the integration of all surface and ocean heat fluxes and attributing the impact of these forcing fluxes on the ice cover can be accomplished by increasing temporal and spatial measurements. Mass balance information can be used to understand the ongoing changes in the Arctic sea ice cover and to improve predictions of future ice conditions. Thinner seasonal ice in the Arctic necessitates the deployment of Autonomous Ice Mass Balance buoys (IMB's) capable of long-term, in situ data collection in both ice and open ocean. Seasonal IMB's (SIMB's) are free floating IMB's that allow data collection in thick ice, thin ice, during times of transition, and even open water. The newest generation of SIMB aims to increase the number of reliable IMB's in the Arctic by leveraging inexpensive commercial-grade instrumentation when combined with specially developed monitoring hardware. Monitoring tasks are handled by a custom, expandable data logger that provides low-cost flexibility for integrating a large range of instrumentation. The SIMB features ultrasonic sensors for direct measurement of both snow depth and ice thickness and a digital temperature chain (DTC) for temperature measurements every 2cm through both snow and ice. Air temperature and pressure, along with GPS data complete the Arctic picture. Additionally, the new SIMB is more compact to maximize deployment opportunities from multiple types of platforms.

  13. Geodetic Mass Balance of the Northern Patagonian Icefield from 2000 to 2012 Using Two Independent Methods

    Directory of Open Access Journals (Sweden)

    Inés Dussaillant

    2018-02-01

    Full Text Available We compare two independent estimates of the rate of elevation change and geodetic mass balance of the Northern Patagonian Icefield (NPI between 2000 (3,856 km2 and 2012 (3,740 km2 from space-borne data. The first is obtained by differencing the Shuttle Radar Topography Mission (SRTM digital elevation model (DEM from February 2000 and a Satellite pour l'Observation de la Terre 5 (SPOT5 DEM from March 2012. The second is deduced by fitting pixel-based linear elevation trends over 118 DEMs calculated from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER stereo images acquired between 2000 and 2012. Both methods lead to similar and strongly negative icefield-wide mass balance rates of −1.02 ± 0.21 and −1.06 ± 0.14 m w.e. yr−1 respectively, which is in agreement with earlier studies. Contrasting glacier responses are observed, with individual glacier mass balance rates ranging from −0.15 to −2.30 m w.e. yr−1 (standard deviation = 0.49 m w.e. yr−1; N = 38. For individual glaciers, the two methods agree within error bars, except for small glaciers poorly sampled in the SPOT5 DEM due to clouds. Importantly, our study confirms the lack of penetration of the C-band SRTM radar signal into the NPI snow and firn except for a region above 2,900 m a.s.l. covering <1% of the total area. Ignoring penetration would bias the mass balance by only 0.005 m w.e. yr−1. A strong advantage of the ASTER method is that it relies only on freely available data and can thus be extended to other glacierized areas.

  14. Long term mass balance of the Helheim and Kangerdlugssuaq glaciers in

    DEFF Research Database (Denmark)

    Khan, Shfaqat Abbas; Fitzner, Antje; Kjær, Kurt

    2013-01-01

    Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve the projec......Observations over the past decade show huge ice loss associated with speeding up of glaciers in southeast Greenland in 2003, followed by a deceleration in 2006. These short-term episodic dynamic perturbations have a major impact on the mass balance at decadal scale. However, to improve...... the projection of future sea level rise, a long-term data record that reveals the mass balance between episodic events is required. Here, we extend the observational record of marginal thinning of Helheim glacier (HG) and Kangerdlugssuaq glacier (KG) from 7 to 30 years. Our measurements reveal that, although...... in air temperature suggest that both outlet glaciers respond immediately to small fluctuations in both the SST and air temperature. Furthermore, we compare our observations of ice flow speed and elevation changes with predictions based on the The Parallel Ice Sheet Model (PISM) software....

  15. The role of crystallization-driven exsolution on the sulfur mass balance in volcanic arc magmas

    Science.gov (United States)

    Su, Yanqing; Huber, Christian; Bachmann, Olivier; Zajacz, Zoltán; Wright, Heather M.; Vazquez, Jorge A.

    2016-01-01

    The release of large amounts of sulfur to the stratosphere during explosive eruptions affects the radiative balance in the atmosphere and consequentially impacts climate for up to several years after the event. Quantitative estimations of the processes that control the mass balance of sulfur between melt, crystals, and vapor bubbles is needed to better understand the potential sulfur yield of individual eruption events and the conditions that favor large sulfur outputs to the atmosphere. The processes that control sulfur partitioning in magmas are (1) exsolution of volatiles (dominantly H2O) during decompression (first boiling) and during isobaric crystallization (second boiling), (2) the crystallization and breakdown of sulfide or sulfate phases in the magma, and (3) the transport of sulfur-rich vapor (gas influx) from deeper unerupted regions of the magma reservoir. Vapor exsolution and the formation/breakdown of sulfur-rich phases can all be considered as closed-system processes where mass balance arguments are generally easier to constrain, whereas the contribution of sulfur by vapor transport (open system process) is more difficult to quantify. The ubiquitous “excess sulfur” problem, which refers to the much higher sulfur mass released during eruptions than what can be accounted for by amount of sulfur originally dissolved in erupted melt, as estimated from melt inclusion sulfur concentrations (the “petrologic estimate”), reflects the challenges in closing the sulfur mass balance between crystals, melt, and vapor before and during a volcanic eruption. In this work, we try to quantify the relative importance of closed- and open-system processes for silicic arc volcanoes using kinetic models of sulfur partitioning during exsolution. Our calculations show that crystallization-induced exsolution (second boiling) can generate a significant fraction of the excess sulfur observed in crystal-rich arc magmas. This result does not negate the important role of

  16. Ice-sheet mass balance and climate change.

    Science.gov (United States)

    Hanna, Edward; Navarro, Francisco J; Pattyn, Frank; Domingues, Catia M; Fettweis, Xavier; Ivins, Erik R; Nicholls, Robert J; Ritz, Catherine; Smith, Ben; Tulaczyk, Slawek; Whitehouse, Pippa L; Zwally, H Jay

    2013-06-06

    Since the 2007 Intergovernmental Panel on Climate Change Fourth Assessment Report, new observations of ice-sheet mass balance and improved computer simulations of ice-sheet response to continuing climate change have been published. Whereas Greenland is losing ice mass at an increasing pace, current Antarctic ice loss is likely to be less than some recently published estimates. It remains unclear whether East Antarctica has been gaining or losing ice mass over the past 20 years, and uncertainties in ice-mass change for West Antarctica and the Antarctic Peninsula remain large. We discuss the past six years of progress and examine the key problems that remain.

  17. Surface Mass Balance of the Greenland Ice Sheet Derived from Paleoclimate Reanalysis

    Science.gov (United States)

    Badgeley, J.; Steig, E. J.; Hakim, G. J.; Anderson, J.; Tardif, R.

    2017-12-01

    Modeling past ice-sheet behavior requires independent knowledge of past surface mass balance. Though models provide useful insight into ice-sheet response to climate forcing, if past climate is unknown, then ascertaining the rate and extent of past ice-sheet change is limited to geological and geophysical constraints. We use a novel data-assimilation framework developed under the Last Millennium Reanalysis Project (Hakim et al., 2016) to reconstruct past climate over ice sheets with the intent of creating an independent surface mass balance record for paleo ice-sheet modeling. Paleoclimate data assimilation combines the physics of climate models and the time series evidence of proxy records in an offline, ensemble-based approach. This framework allows for the assimilation of numerous proxy records and archive types while maintaining spatial consistency with known climate dynamics and physics captured by the models. In our reconstruction, we use the Community Climate System Model version 4, CMIP5 last millennium simulation (Taylor et al., 2012; Landrum et al., 2013) and a nearly complete database of ice core oxygen isotope records to reconstruct Holocene surface temperature and precipitation over the Greenland Ice Sheet on a decadal timescale. By applying a seasonality to this reconstruction (from the TraCE-21ka simulation; Liu et al., 2009), our reanalysis can be used in seasonally-based surface mass balance models. Here we discuss the methods behind our reanalysis and the performance of our reconstruction through prediction of unassimilated proxy records and comparison to paleoclimate reconstructions and reanalysis products.

  18. Mass Balance of Novaya Zemlya Archipelago from 2002 to Present

    Science.gov (United States)

    Ciraci, E.; Velicogna, I.; Fettweis, X.

    2017-12-01

    We employ satellite gravimetry from NASA's Gravity Recovery and Climate Experiment (GRACE) using a least-squares fit mascon approach to evaluate the mass balance of the glaciers of the Novaya Zemlya Archipelago (NZA) from 2002 to present. Our results reveal a mean mass loss 8±5 Gt/yr (gigatons per year), which makes NZA the largest contributor to sea level rise in the Russian Arctic (total Russian Arctic contributes 16±7Gt/yr). We then use Surface Mass Balance (SMB) estimates from the Modèle Atmosphérique Régional (MAR) and ice elevation change rates from NASA ICESat (2003-2009) and ESA CryoSat-2 (2010-present) altimetry data to gain insight about the physical processes driving the observed mass loss. We find that the inter-annual variability in SMB displays a significant correlation (0.6, p-val sea level rise. Elevation change from satellite altimetry reveals substantial thinning at low altitudes for both marine and land terminating glaciers. This result is consistent with the negative cumulative SMB values found at those sites. Yet, altimetry-derived thinning rates for the marine terminating glaciers are on average two times larger than those for land-terminating glaciers. We conclude that both SMB and ice dynamics play important roles in the regional ice mass loss.

  19. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960-2014

    NARCIS (Netherlands)

    Kuipers Munneke, P.; Ligtenberg, S. R M; Noël, B. P Y; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; Van Den Broeke, M. R.

    2015-01-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes

  20. The mid-cretaceous water bearer: Isotope mass balance quantification of the Albian hydrologic cycle

    Science.gov (United States)

    Ufnar, David F.; Gonzalez, Luis A.; Ludvigson, Greg A.; Brenner, Richard L.; Witzke, B.J.

    2002-01-01

    A latitudinal gradient in meteoric ??18O compositions compiled from paleosol sphaerosiderites throughout the Cretaceous Western Interior Basin (KWIB) (34-75??N paleolatitude) exhibits a steeper, more depleted trend than modern (predicted) values (3.0??? [34??N latitude] to 9.7??? [75??N] lighter). Furthermore, the sphaerosiderite meteoric ??18O latitudinal gradient is significantly steeper and more depleted (5.8??? [34??N] to 13.8??? [75??N] lighter) than a predicted gradient for the warm mid-Cretaceous using modern empirical temperature-??18O precipitation relationships. We have suggested that the steeper and more depleted (relative to the modern theoretical gradient) meteoric sphaerosiderite ??18O latitudinal gradient resulted from increased air mass rainout effects in coastal areas of the KWIB during the mid-Cretaceous. The sphaerosiderite isotopic data have been used to constrain a mass balance model of the hydrologic cycle in the northern hemisphere and to quantify precipitation rates of the equable 'greenhouse' Albian Stage in the KWIB. The mass balance model tracks the evolving isotopic composition of an air mass and its precipitation, and is driven by latitudinal temperature gradients. Our simulations indicate that significant increases in Albian precipitation (34-52%) and evaporation fluxes (76-96%) are required to reproduce the difference between modern and Albian meteoric siderite ??18O latitudinal gradients. Calculations of precipitation rates from model outputs suggest mid-high latitude precipitation rates greatly exceeded modern rates (156-220% greater in mid latitudes [2600-3300 mm/yr], 99% greater at high latitudes [550 mm/yr]). The calculated precipitation rates are significantly different from the precipitation rates predicted by some recent general circulation models (GCMs) for the warm Cretaceous, particularly in the mid to high latitudes. Our mass balance model by no means replaces GCMs. However, it is a simple and effective means of obtaining

  1. Past and future sea-level change from the surface mass balance of glaciers

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-11-01

    Full Text Available We present estimates of sea-level change caused by the global surface mass balance of glaciers, based on the reconstruction and projection of the surface mass balance of all the individual glaciers of the world, excluding the ice sheets in Greenland and Antarctica. The model is validated using a leave-one-glacier-out cross-validation scheme against 3997 observed surface mass balances of 255 glaciers, and against 756 geodetically observed, temporally integrated volume and surface area changes of 341 glaciers. When forced with observed monthly precipitation and temperature data, the glaciers of the world are reconstructed to have lost mass corresponding to 114 ± 5 mm sea-level equivalent (SLE between 1902 and 2009. Using projected temperature and precipitation anomalies from 15 coupled general circulation models from the Coupled Model Intercomparison Project phase 5 (CMIP5 ensemble, they are projected to lose an additional 148 ± 35 mm SLE (scenario RCP26, 166 ± 42 mm SLE (scenario RCP45, 175 ± 40 mm SLE (scenario RCP60, or 217 ± 47 mm SLE (scenario RCP85 during the 21st century. Based on the extended RCP scenarios, glaciers are projected to approach a new equilibrium towards the end of the 23rd century, after having lost either 248 ± 66 mm SLE (scenario RCP26, 313 ± 50 mm SLE (scenario RCP45, or 424 ± 46 mm SLE (scenario RCP85. Up until approximately 2100, ensemble uncertainty within each scenario is the biggest source of uncertainty for the future glacier mass loss; after that, the difference between the scenarios takes over as the biggest source of uncertainty. Ice mass loss rates are projected to peak 2040 ∼ 2050 (RCP26, 2050 ∼ 2060 (RCP45, 2070 ∼ 2090 (RCP60, or 2070 ∼ 2100 (RCP85.

  2. Glacier mass balance and its potential impacts in the Altai Mountains over the period 1990-2011

    Science.gov (United States)

    Zhang, Yong; Enomoto, Hiroyuki; Ohata, Tetsuo; Kitabata, Hideyuki; Kadota, Tsutomu; Hirabayashi, Yukiko

    2017-10-01

    The Altai Mountains contain 1281 glaciers covering an area of 1191 km2. These glaciers have undergone significant changes in glacial length and area over the past decade. However, mass changes of these glaciers and their impacts remain poorly understood. Here we present surface mass balances of all glaciers in the region for the period 1990-2011, using a glacier mass-balance model forced by the outputs of a regional climate model. Our results indicate that the mean specific mass balance for the whole region is about -0.69 m w.e. yr-1 over the entire period, and about 81.3% of these glaciers experience negative net mass balance. We detect an accelerated wastage of these glaciers in recent years, and marked differences in mass change and its sensitivity to climate change for different regions and size classes. In particular, higher mass loss and temperature sensitivity are observed for glaciers smaller than 0.5 km2. In addition to temperature rise, a decrease in precipitation in the western part of the region and an increase in precipitation in the eastern part likely contribute to significant sub-region differences in mass loss. With significant glacier wastage, the contribution of all glaciers to regional water resources and sea-level change becomes larger than before, but may not be a potential threat to human populations through impacts on water availability.

  3. Region-wide glacier mass balances over the Pamir-Karakoram-Himalaya during 1999–2011

    Directory of Open Access Journals (Sweden)

    J. Gardelle

    2013-08-01

    Full Text Available The recent evolution of Pamir-Karakoram-Himalaya (PKH glaciers, widely acknowledged as valuable high-altitude as well as mid-latitude climatic indicators, remains poorly known. To estimate the region-wide glacier mass balance for 9 study sites spread from the Pamir to the Hengduan Shan (eastern Himalaya, we compared the 2000 Shuttle Radar Topography Mission (SRTM digital elevation model (DEM to recent (2008–2011 DEMs derived from SPOT5 stereo imagery. During the last decade, the region-wide glacier mass balances were contrasted with moderate mass losses in the eastern and central Himalaya (−0.22 ± 0.12 m w.e. yr−1 to −0.33 ± 0.14 m w.e. yr−1 and larger losses in the western Himalaya (−0.45 ± 0.13 m w.e. yr−1. Recently reported slight mass gain or balanced mass budget of glaciers in the central Karakoram is confirmed for a larger area (+0.10 ± 0.16 m w.e. yr−1 and also observed for glaciers in the western Pamir (+0.14 ± 0.13 m w.e. yr−1. Thus, the "Karakoram anomaly" should be renamed the "Pamir-Karakoram anomaly", at least for the last decade. The overall mass balance of PKH glaciers, −0.14 ± 0.08 m w.e. yr−1, is two to three times less negative than the global average for glaciers distinct from the Greenland and Antarctic ice sheets. Together with recent studies using ICESat and GRACE data, DEM differencing confirms a contrasted pattern of glacier mass change in the PKH during the first decade of the 21st century.

  4. Antarctic Ice-Sheet Mass Balance from Satellite Altimetry 1992 to 2001

    Science.gov (United States)

    Zwally, H. Jay; Brenner, Anita C.; Cornejo, Helen; Giovinetto, Mario; Saba, Jack L.; Yi, Donghui

    2003-01-01

    A major uncertainty in understanding the causes of the current rate of sea level rise is the potential contributions from mass imbalances of the Greenland and Antarctic ice sheets. Estimates of the current mass balance of the Antarctic ice sheet are derived from surface- elevation changes obtained from 9 years of ERS - 1 & 2 radar altimeter data. Elevation time-series are created from altimeter crossovers among 90-day data periods on a 50 km grid to 81.5 S. The time series are fit with a multivariate linear/sinusoidal function to give the average rate of elevation change (dH/dt). On the major Rome-Filchner, Ross, and Amery ice shelves, the W d t are small or near zero. In contrast, the ice shelves of the Antarctic Peninsula and along the West Antarctic coast appear to be thinning significantly, with a 23 +/- 3 cm per year surface elevation decrease on the Larsen ice shelf and a 65 +/- 4 cm per year decrease on the Dotson ice shelf. On the grounded ice, significant elevation decreases are obtained over most of the drainage basins of the Pine Island and Thwaites glaciers in West Antarctica and inland of Law Dome in East Antarctica. Significant elevation increases are observed within about 200 km of the coast around much of the rest of the ice sheet. Farther inland, the changes are a mixed pattern of increases and decreases with increases of a few centimeters per year at the highest elevations of the East Antarctic plateau. The derived elevation changes are combined with estimates of the bedrock uplift from several models to provide maps of ice thickness change. The ice thickness changes enable estimates of the ice mass balances for the major drainage basins, the overall mass balance, and the current contribution of the ice sheet to global sea level change.

  5. Geodetic mass balance measurements on debris and clean-ice tropical glaciers in Ecuador

    Science.gov (United States)

    La Frenierre, J.; Decker, C. R.; Jordan, E.; Wigmore, O.; Hodge, B. E.; Niederriter, C.; Michels, A.

    2017-12-01

    Glaciers are recognized as highly sensitive indicators of climate change in high altitude, low latitude environments. In the tropical Andes, various analyses of glacier surface area change have helped illuminate the manifestation of climate change in this region, however, information about actual glacier mass balance behavior is much more limited given the relatively small glaciers, difficult access, poor weather, and/or limited local resources common here. Several new technologies, including aerial and terrestrial LIDAR and structure-from-motion photogrammetry using small unmanned aerial vehicles (UAVs), make mass balance measurements using geodetic approaches increasingly feasible in remote mountain locations, which can both further our understanding of changing climatic conditions, and improve our ability to evaluate the downstream hydrologic impacts of ice loss. At Volcán Chimborazo, Ecuador, these new technologies, combined with a unique, 5-meter resolution digital elevation model derived from 1997 aerial imagery, make possible an analysis of the magnitude and spatial patterns of mass balance behavior over the past two decades. Here, we evaluate ice loss between 1997 and 2017 at the tongues of two adjacent glaciers, one debris-covered and detached from its accumulation area (Reschreiter Glacier), and one debris-free and intact (Hans Meyer Glacier). Additionally, we incorporate data from 2012 and 2013 terrestrial LIDAR surveys to evaluate the behavior of the Reschreiter at a finer temporal resolution. We find that on the Hans Meyer, the mean surface deflation rate since 1997 at the present-day tongue has been nearly 3 m yr-1, while on the lower-elevation Reschreiter, the mean deflation rate has been approximately 1 m yr-1. However, the processes by which debris-covered ice becomes exposed results in highly heterogeneous patterns of ice loss, with some areas experiencing surface deflation rates approaching 15 m yr-1 when energy absorption is unimpeded.

  6. Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions. Part II: source contribution assessment using the Chemical Mass Balance (CMB) model.

    Science.gov (United States)

    Badol, Caroline; Locoge, Nadine; Galloo, Jean-Claude

    2008-01-25

    In Part I of this study (Badol C, Locoge N, Leonardis T, Gallo JC. Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions, Part I: Study area description, data set acquisition and qualitative data analysis of the data set. Sci Total Environ 2007; submitted as companion manuscript.) the study area, acquisition of the one-year data set and qualitative analysis of the data set have been described. In Part II a source profile has been established for each activity present in the study area: 6 profiles (urban heating, solvent use, natural gas leakage, biogenic emissions, gasoline evaporation and vehicle exhaust) have been extracted from literature to characterise urban sources, 7 industrial profiles have been established via canister sampling around industrial plants (hydrocarbon cracking, oil refinery, hydrocarbon storage, lubricant storage, lubricant refinery, surface treatment and metallurgy). The CMB model is briefly described and its implementation is discussed through the selection of source profiles and fitting species. Main results of CMB modellings for the Dunkerque area are presented. (1) The daily evolution of source contributions for the urban wind sector shows that the vehicle exhaust source contribution varies between 40 and 55% and its relative increase at traffic rush hours is hardly perceptible. (2) The relative contribution of vehicle exhaust varies from 55% in winter down to 30% in summer. This decrease is due to the increase of the relative contribution of hydrocarbon storage source reaching up to 20% in summer. (3) The evolution of source contributions with wind directions has confirmed that in urban wind sectors the contribution of vehicle exhaust dominate with around 45-55%. For the other wind sectors that include some industrial plants, the contribution of industrial sources is around 60% and could reach 80% for the sector 280-310 degrees , which corresponds to the most dense

  7. Thermal non-equilibrium heat transfer in a porous cavity in the presence of bio-chemical heat source

    Directory of Open Access Journals (Sweden)

    Nazari Mohsen

    2015-01-01

    Full Text Available This paper is concerned with thermal non-equilibrium natural convection in a square cavity filled with a porous medium in the presence of a biomass which is transported in the cavity. The biomass can consume a secondary moving substrate. The physics of the presented problem is related to the analysis of heat and mass transfer in a composting process that controlled by internal heat generation. The intensity of the bio-heat source generated in the cavity is equal to the rate of consumption of the substrate by the biomass. It is assumed that the porous medium is homogeneous and isotropic. A two-field model that represents the fluid and solid phase temperature fields separately is used for energy equation. A simplified Monod model is introduced along with the governing equations to describe the consumption of the substrate by the biomass. In other word, the transient biochemical heat source which is dependent on a solute concentration is considered in the energy equations. Investigation of the biomass activity and bio-chemical heat generation in the case of thermal non-equilibrium assumption has not been considered in the literature and they are open research topics. The effects of thermal non-equilibrium model on heat transfer, flow pattern and biomass transfer are investigated. The effective parameters which have a direct impact on the generated bio-chemical heat source are also presented. The influences of the non-dimensional parameters such as fluid-to-solid conductivity ratio on the temperature distribution are presented.

  8. Sustainability of algae derived biodiesel: a mass balance approach.

    Science.gov (United States)

    Pfromm, Peter H; Amanor-Boadu, Vincent; Nelson, Richard

    2011-01-01

    A rigorous chemical engineering mass balance/unit operations approach is applied here to bio-diesel from algae mass culture. An equivalent of 50,000,000 gallons per year (0.006002 m3/s) of petroleum-based Number 2 fuel oil (US, diesel for compression-ignition engines, about 0.1% of annual US consumption) from oleaginous algae is the target. Methyl algaeate and ethyl algaeate diesel can according to this analysis conceptually be produced largely in a technologically sustainable way albeit at a lower available diesel yield. About 11 square miles of algae ponds would be needed with optimistic assumptions of 50 g biomass yield per day and m2 pond area. CO2 to foster algae growth should be supplied from a sustainable source such as a biomass-based ethanol production. Reliance on fossil-based CO2 from power plants or fertilizer production renders algae diesel non-sustainable in the long term. Copyright © 2010 Elsevier Ltd. All rights reserved.

  9. Closing the Mass Balance on Fluorine on Papers and Textiles.

    Science.gov (United States)

    Robel, Alix E; Marshall, Kristin; Dickinson, Margaret; Lunderberg, David; Butt, Craig; Peaslee, Graham; Stapleton, Heather M; Field, Jennifer A

    2017-08-15

    Papers and textiles that are treated with per- and polyfluoroalkyl substances (PFASs) are sources of human and environmental exposure. Data for individual PFASs, such as perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), are not placed into the context of total fluorine for papers and textiles. Gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-tandem mass spectrometry (LC-MS/MS) were used to quantify volatile and ionic PFASs, respectively, and the total oxidizable precursor (TOP) assay was used to quantify precursors that form perfluoroalkyl carboxylates. Molar sums of PFASs obtained by GC-MS, LC-MS/MS, and precursors were compared to total fluorine (nmol F/cm 2 ) determined by particle-induced gamma ray emission (PIGE) spectroscopy, measured before and after extraction. Volatile and ionic PFASs and unknown precursors accounted for 0-2.2%, 0-0.41%, and 0.021-14%, respectively, of the total nmol F/cm 2 determined by PIGE. After extraction, papers and textiles retained 64 ± 28% to 110 ± 30% of the original nmol F/cm 2 as determined by PIGE, indicating that the majority of fluorine remains associated with the papers and textiles. The sum of PFASs in the volatile, ionic, and precursor fraction, and total fluorine after extraction indicate that mass balance was achieved (within analytical error) of the initial total fluorine measured by PIGE.

  10. Mass balance of the Greenland ice sheet (2003-2008) from ICESat data

    DEFF Research Database (Denmark)

    Sørensen, Louise Sandberg; Simonsen, Sebastian Bjerregaard; Nielsen, Karina

    2011-01-01

    of the Greenland ice sheet. Firn dynamics and surface densities are important factors that contribute to the mass change derived from remote-sensing altimetry. The volume change derived from ICESat data is corrected for changes in firn compaction over the observation period, vertical bedrock movement...... and an intercampaign elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by the application of a simple surface density model, in which some of the ice dynamics are accounted for. The firn compaction and density models are driven by the HIRHAM5 regional climate......ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique dataset for monitoring the changes of the cryosphere. Here, we present a novel method for determining the mass balance of the Greenland ice sheet, derived from ICESat...

  11. A MASS BALANCE OF SURFACE WATER GENOTOXICITY IN PROVIDENCE RIVER (RHODE ISLAND USA)

    Science.gov (United States)

    White and Rasmussen (Mutation Res. 410:223-236) used a mass balance approach to demonstrate that over 85% of the total genotoxic loading to the St. Lawrence River at Montreal is non-industrial. To validate the mass balance approach and investigate the sources of genotoxins in sur...

  12. Uncertainty of solute flux estimation in ungauged small streams: potential implications for input-output nutrient mass balances at stream reach scale

    Directory of Open Access Journals (Sweden)

    A. Butturini

    2005-01-01

    Full Text Available Input-output mass balances within stream reaches provide in situ estimates of stream nutrient retention/release under a wide spectrum of hydrological conditions. Providing good estimates of the mass balances for nutrients depends on precise hydrological monitoring and good chemical characterisation of stream water at the input and output ends of the stream reach. There is a need to optimise the hydrological monitoring and the frequencies of water sampling to yield precise annual mass balances, so as to avoid undue cost - high resolution monitoring and subsequent chemical analysis can be labour intensive and costly. In this paper, simulation exercises were performed using a data set created to represent the instantaneous discharge and solute dynamics at the input and output ends of a model stream reach during a one year period. At the output end, stream discharge and water chemistry were monitored continuously, while the input end was assumed to be ungauged; water sampling frequency was changed arbitrarily. Instantaneous discharge at the ungauged sampling point was estimated with an empirical power model linking the discharge to the catchment area (Hooper, 1986. The model thus substitutes for the additional gauge station. Simulations showed that 10 days was the longest chemical sampling interval which could provide reach annual mass balances of acceptable precision. Presently, the relationship between discharge and catchment area is usually assumed to be linear but simulations indicate that small departures from the linearity of this relationship could cause dramatic changes in the mass balance estimations.

  13. How effective would solar geoengineering be at offsetting surface mass balance losses of the ice-sheets?

    Science.gov (United States)

    Irvine, P. J.; Keith, D.

    2016-12-01

    Studies of the sea-level rise response to solar geoengineering suggest that it could be highly effective at reducing sea-level rise by reducing thermal expansion of ocean waters and reducing the melting of land ice. However, all studies to date have employed simplistic treatments of surface mass balance where melt is a function only of surface air temperature and many have not had explicit treatments of accumulation. Solar geoengineering would counteract the longwave forcing of elevated greenhouse gas concentrations by reducing incoming solar radiation, changing the seasonal, latitudinal and vertical distribution of energy within the climate system. Climate model simulations suggest that solar geoengineering deployed to counter future warming from rising greenhouse gas concentrations could partially offset many climate trends associated with rising greenhouse gas concentrations, however it would lead to a suppression of the hydrological cycle as well as leading to substantial residual regional climate changes. In this study the response of the surface mass balance of the Greenland and Antarctic ice sheets to solar geoengineering will be investigated. Multi-model results from G1, the idealized solar insolation reduction experiment of the Geoengineering Model Intercomparison Project (GeoMIP), will be compared against results from the abrupt4×CO2 and piControl experiment. The energy and mass balance of the ice sheets, as well as the broader climate response in the polar regions will be analysed in the GeoMIP ensemble. This analysis will be complemented by offline surface mass balance simulations, including both those which directly simulate the energy balance and by those which use approximations based on surface air temperatures. This analysis will help to determine whether previous studies have over- or under-estimated the efficacy of solar geoengineering at offsetting future sea-level rise.

  14. Measuring air-water interfacial area for soils using the mass balance surfactant-tracer method.

    Science.gov (United States)

    Araujo, Juliana B; Mainhagu, Jon; Brusseau, Mark L

    2015-09-01

    There are several methods for conducting interfacial partitioning tracer tests to measure air-water interfacial area in porous media. One such approach is the mass balance surfactant tracer method. An advantage of the mass-balance method compared to other tracer-based methods is that a single test can produce multiple interfacial area measurements over a wide range of water saturations. The mass-balance method has been used to date only for glass beads or treated quartz sand. The purpose of this research is to investigate the effectiveness and implementability of the mass-balance method for application to more complex porous media. The results indicate that interfacial areas measured with the mass-balance method are consistent with values obtained with the miscible-displacement method. This includes results for a soil, for which solid-phase adsorption was a significant component of total tracer retention. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Land motion due to 20th century mass balance of the Greenland Ice Sheet

    Science.gov (United States)

    Kjeldsen, K. K.; Khan, S. A.

    2017-12-01

    Quantifying the contribution from ice sheets and glaciers to past sea level change is of great value for understanding sea level projections into the 21st century. However, quantifying and understanding past changes are equally important, in particular understanding the impact in the near-field where the signal is highest. We assess the impact of 20th century mass balance of the Greenland Ice Sheet on land motion using results from Kjeldsen et al, 2015. These results suggest that the ice sheet on average lost a minimum of 75 Gt/yr, but also show that the mass balance was highly spatial- and temporal variable, and moreover that on a centennial time scale changes were driven by a decreasing surface mass balance. Based on preliminary results we discuss land motion during the 20th century due to mass balance changes and the driving components surface mass balance and ice dynamics.

  16. A case-study on the accuracy of mass balances for xenobiotics in full-scale wastewater treatment plants.

    Science.gov (United States)

    Majewsky, Marius; Farlin, Julien; Bayerle, Michael; Gallé, Tom

    2013-04-01

    Removal efficiencies of micropollutants in wastewater treatment plants (WWTPs) are usually evaluated from mass balance calculations using a small number of observations drawn from short sampling campaigns. Since micropollutant loads can vary greatly in both influent and effluent and reactor tanks exhibit specific hydraulic residence times, these short-term approaches are particularly prone to yield erroneous removal values. A detailed investigation of micropollutant transit times at full-scale and on how this affects mass balancing results was still lacking. The present study used hydraulic residence time distributions to scrutinize the match of influent loads to effluent loads of 10 polar micropollutants with different influent dynamics in a full-scale WWTP. Prior hydraulic modeling indicated that a load sampled over one day in the effluent is composed of influent load fractions of five preceding days. Results showed that the error of the mass balance can be reduced with increasing influent sampling duration. The approach presented leads to a more reliable estimation of the removal efficiencies of those micropollutants which can be constantly detected in influents, such as pharmaceuticals, but provides no advantage for pesticides due to their sporadic occurrence. The mismatch between sampled influent and effluent loads was identified as a major error source and an explanation was provided for the occurrence of negative mass balances regularly reported. This study indicates that the accurate determination of global removal values is only feasible in full-scale investigations with sampling durations much longer than 1 day. In any case, the uncertainty of these values needs to be reported when used in removal assessment, model selection or validation.

  17. Re-assessing the influence of glacial-isostatic adjustment on Antarctic ice-mass balance estimated from GRACE

    Science.gov (United States)

    Konrad, H.; Sasgen, I.; Klemann, V.; Ivins, E. R.; Martinec, Z.

    2012-04-01

    Satellite gravimetry observations of the contemporary ice-mass balance in Antarctica are strongly influenced by mass movements in the Earth interior induced by ice-load variations during the last glacial cycle, i.e. the glacial-isostatic adjustment (GIA). Newly available GPS observations collected within the POLENET project (www.polenet.org) represent a valuable constraint on GIA models predicting surface deformation and gravity-field change in Antarctica. Here, we re-assess the influence of GIA on Antarctic ice-mass balance estimated from the Gravity Recovery and Climate Experiment (GRACE). For this, we apply a viscoelastic Earth model, accounting for the rheological differences between East and West Antarctica, to three independent glacial histories ICE-5G (Peltier, 2004), IJ05 (Ivins & James, 2005) and HUY (Huybrechts, 2002). We predict the associated Antarctic GIA signal. With a stochastic approach, the glacial histories are regionally modified to satisfy GPS, GRACE as well as the combination of both observation types. We assess the influence of constraining GIA with GPS/GRACE on the reduction of the error budget of Antarctic ice-mass balances from GRACE.

  18. Elastodynamic Effects of Mass-Balancing: Experimental Investigation of a Four-Bar Linkage

    Directory of Open Access Journals (Sweden)

    Alberto Martini

    2013-01-01

    Full Text Available This paper deals with static balancing of closed-loop mechanisms. The long-term goal of the research is enhancing the performance of parallel robots by means of effective static balancing strategies that take into account the system dynamic behaviour. In this contribution, the influence of mass-balancing on the elastodynamic performance of a four-bar linkage, intended as the simplest example of closed-loop mechanism, is experimentally investigated. The design of the experimental apparatus is discussed and the results of tests on both an unbalanced linkage and its balanced variant are presented. Base-transmitted forces and vibrations are monitored for constant-speed operations and for velocity ramp tests in order to characterize the elastodynamic behaviour of the linkages. The analysis is supported by implementing a flexible multibody model of the experimental apparatus that enhances the interpretation of the experimental data.

  19. Mass balance of Greenland and the Canadian Ice Caps from combined altimetry and GRACE inversion

    DEFF Research Database (Denmark)

    Forsberg, René; Simonsen, Sebastian Bjerregaard; Sørensen, Louise Sandberg

    The combination of GRACE and altimetry data may yield a high resolution mass balance time series of the Greenlandice sheet, highlighting the varying individual mass loss behaviour of major glaciers. By including the Canadian arctic ice caps in the estimation, a more reliable estimate of the mass...... loss of both Greenlandand the Canadian ice caps may be obtained, minimizing the leakage errors otherwise unavoidable by GRACE. Actually, the absolute value of the Greenlandice sheet mass loss is highly dependent on methods and how the effects of Arctic Canadian ice caps are separated in the GRACE...... signal; here altimetry data and firn models may provide important constraints.In the presentation we outline the basis of the joint estimation method, including corrections for firn density and compaction, and use CryoSat and EnviSat data together with GRACE data to provide composite time series of mass...

  20. Mass balance evolution on two glaciers in the ecuadorian Andes (0°28'S) since the mid-20th century

    Science.gov (United States)

    Basantes, Ruben; Rabatel, Antoine; Alvarez, Danilo; Francou, Bernard; Galarraga, Remigio; Maisincho, Luis; Caceres, Bolivar

    2014-05-01

    The glacier mass balance evolution on two glaciers (Antisana Glacier 12 and Antisana Glacier 15α) in the tropical Andes is presented. To this end, photogrammetry technique was applied on aerial images taken at five dates: 1956, 1965, 1979, 1997 and 2009. For each date, digital elevation models (DEMs) were generated with an average vertical accuracy of ±2.2 m. The spatiotemporal volume variation of the glaciers is calculated through the elevations differences between DEMs and a density factor. The outcomes show that after 1970s the glaciers have experimented a strong recession even if a noticeable increase in mass was detected between 1965 and 1979. From 1979 to 1997, the ablation rates have dramatically increased and the average annual mass balance reached very negative values (-1.1 m w.e. yr-1 for Antisana Glacier 15α and -0.8 m w.e. yr-1 for Antisana Glacier 12). In the last study period, from 1997 to 2009, the glaciers average annual mass balances were less negative (-0.6 m w.e. yr-1 for Antisana Glacier 12 and -0.2 m w.e. yr-1 for Antisana Glacier 15α). The later matched with the period of conventional observations allowing compare the results given by both methodologies, i.e. geodetic and glaciological methods. However, some morphological constraints affecting the figures observed in the glaciological mass balance must be considered. Finally, we performed an analysis of the relationship between the glacier changes and the climate conditions over the study periods in order to understand how climate has impacted the glacier retreat in this region. For such an aim, local climate variables, i.e. temperature and precipitation, as well as regional indices, i.e. Pacific Decadal Oscillation (PDO) and Multivariate ENSO Index (MEI) have been used. The outcomes show a high correlation between the climate signals and the glacier behavior at both annual and decadal time scales.

  1. Sea Ice Mass Balance Buoys (IMBs): First Results from a Data Processing Intercomparison Study

    Science.gov (United States)

    Hoppmann, Mario; Tiemann, Louisa; Itkin, Polona

    2017-04-01

    IMBs are autonomous instruments able to continuously monitor the growth and melt of sea ice and its snow cover at a single point on an ice floe. Complementing field expeditions, remote sensing observations and modelling studies, these in-situ data are crucial to assess the mass balance and seasonal evolution of sea ice and snow in the polar oceans. Established subtypes of IMBs combine coarse-resolution temperature profiles through air, snow, ice and ocean with ultrasonic pingers to detect snow accumulation and ice thermodynamic growth. Recent technological advancements enable the use of high-resolution temperature chains, which are also able to identify the surrounding medium through a „heating cycle". The temperature change during this heating cycle provides additional information on the internal properties and processes of the ice. However, a unified data processing technique to reliably and accurately determine sea ice thickness and snow depth from this kind of data is still missing, and an unambiguous interpretation remains a challenge. Following the need to improve techniques for remotely measuring sea ice mass balance, an international IMB working group has recently been established. The main goals are 1) to coordinate IMB deployments, 2) to enhance current IMB data processing and -interpretation techniques, and 3) to provide standardized IMB data products to a broader community. Here we present first results from two different data processing algorithms, applied to selected IMB datasets from the Arctic and Antarctic. Their performance with regard to sea ice thickness and snow depth retrieval is evaluated, and an uncertainty is determined. Although several challenges and caveats in IMB data processing and -interpretation are found, such datasets bear great potential and yield plenty of useful information about sea ice properties and processes. It is planned to include many more algorithms from contributors within the working group, and we explicitly invite

  2. Ranking of factors determining potassium mass balance in bicarbonate haemodialysis.

    Science.gov (United States)

    Basile, Carlo; Libutti, Pasquale; Lisi, Piero; Teutonico, Annalisa; Vernaglione, Luigi; Casucci, Francesco; Lomonte, Carlo

    2015-03-01

    One of the most important pathogenetic factors involved in the onset of intradialysis arrhytmias is the alteration in electrolyte concentration, particularly potassium (K(+)). Two studies were performed: Study A was designed to investigate above all the isolated effect of the factor time t on intradialysis K(+) mass balance (K(+)MB): 11 stable prevalent Caucasian anuric patients underwent one standard (∼4 h) and one long-hour (∼8 h) bicarbonate haemodialysis (HD) session. The latter were pair-matched as far as the dialysate and blood volume processed (90 L) and volume of ultrafiltration are concerned. Study B was designed to identify and rank the other factors determining intradialysis K(+)MB: 63 stable prevalent Caucasian anuric patients underwent one 4-h standard bicarbonate HD session. Dialysate K(+) concentration was 2.0 mmol/L in both studies. Blood samples were obtained from the inlet blood tubing immediately before the onset of dialysis and at t60, t120, t180 min and at end of the 4- and 8-h sessions for the measurement of plasma K(+), blood bicarbonates and blood pH. Additional blood samples were obtained at t360 min for the 8 h sessions. Direct dialysate quantification was utilized for K(+)MBs. Direct potentiometry with an ion-selective electrode was used for K(+) measurements. Study A: mean K(+)MBs were significantly higher in the 8-h sessions (4 h: -88.4 ± 23.2 SD mmol versus 8 h: -101.9 ± 32.2 mmol; P = 0.02). Bivariate linear regression analyses showed that only mean plasma K(+), area under the curve (AUC) of the hourly inlet dialyser diffusion concentration gradient of K(+) (hcgAUCK(+)) and AUC of blood bicarbonates and mean blood bicarbonates were significantly related to K(+)MB in both 4- and 8-h sessions. A multiple linear regression output with K(+)MB as dependent variable showed that only mean plasma K(+), hcgAUCK(+) and duration of HD sessions per se remained statistically significant. Study B: mean K(+)MBs were -86.7 ± 22.6 mmol

  3. Mass balance of the Greenland ice sheet from 1958 to 2007

    OpenAIRE

    Rignot, E; Box, JE; Burgess, E; Hanna, E

    2008-01-01

    We combine estimates of the surface mass balance, SMB, of the Greenland ice sheet for years 1958 to 2007 with measurements of the temporal variability in ice discharge, D, to deduce the total ice sheet mass balance. During that time period, we find a robust correlation (R2 = 0.83) between anomalies in SMB and in D, which we use to reconstruct a continuous series of total ice sheet mass balance. We. find that the ice sheet was losing 110 ± 70 Gt/yr in the 1960s, 30 ± 50 Gt/yr or near balance...

  4. Dual-sensor mapping of mass balance on Russia's northernmost ice caps

    Science.gov (United States)

    Nikolskiy, D.; Malinnikov, V.; Sharov, A.; Ukolova, M.

    2012-04-01

    Mass balance of Russia's northernmost ice caps is poorly known and scarcely mapped. Thorough information about glacier fluctuations in the outer periphery of Russian shelf seas is both lacking and highly desired since it may constitute the relevant benchmark for judging and projecting climate change impacts in the entire Arctic. The present study is focussed on geodetic measurements and medium-scale mapping of the mass balance on a dozen insular ice caps, some large and some smaller, homogeneously situated along the Eurasian boundary of Central Arctic Basin. The study region extends for approx. 2.200 km from Victoria and Arthur islands in the west across Rudolph, Eva-Liv, Ushakova, Schmidt and Komsomolets islands in the north to Bennett and Henrietta islands in the east thereby comprising the most distant and least studied ice caps in the Russian Arctic. The situation of insular ice masses close to the edge of summer minimum sea ice proved helpful in analysing spatial asymmetry of glacier accumulation signal. The overall mapping of glacier elevation changes and quantification of mass balance characteristics in the study region was performed by comparing reference elevation models of study glaciers derived from Russian topographic maps 1:200,000 (CI = 20 or 40 m) representing the glacier state as in the 1950s-1960s with modern elevation data obtained from satellite radar interferometry and lidar altimetry. In total, 14 ERS and 4 TanDEM-X high-quality SAR interferograms of 1995/96 and 2011 were acquired, processed in the standard 2-pass DINSAR manner, geocoded, calibrated, mosaicked and interpreted using reference elevation models and co-located ICESat altimetry data of 2003-2010. The DINSAR analysis revealed the existence of fast-flowing outlet glaciers at Arthur, Rudolph, Eva-Liv and Bennett islands. The calculation of separate mass-balance components is complicated in this case because of generally unknown glacier velocities and ice discharge values for the mid-20

  5. Mass Balance Reconstruction and Volumetric change of Stok Glaicer , Ladak Region, Western Himalyas,India (1969-2015)

    Science.gov (United States)

    Mohd, S.; AL, R.

    2017-12-01

    Understanding mass balance and volumetric change of glaciers are extremely important in areas where the majority of the population depends on cryospheric sources for the livelihood. Ladakh is one of the coldest and the aridest region of India. The majority of the population live in mountain pockets where the only source of water is snow and glacier melt for agriculture and domestic use. Stok village catchment (52 km2) has seven very small glaciers with an area ranging between 0.2-1.05 km2 at an elevation above 5300m a.s.l (GSI 2009). These glaciers contribute to a stream feeding Stok village of 274 ( 1469 individuals) households and a portion of Chuchot village before joining the Indus River. Ironically very limited studies have been carried out so far in this region, making it even more urgent to monitor the health of the glaciers in this region. With the changing climate, booming of the tourism industry and scarcity of water resources during the spring season, there is a shift in the livelihood of the region towards other option leading to a negative impact on the environment and over exploitation of natural resources. In this study we present analysis of measured annual mass balances for the period 2015-2017 and reconstruction of annual mass balances since 1969 to 2015 of Stok glacier located on the north eastern slope of Zanskar range in Ladakh region of western Himalayas. Direct glaciological methods were used to obtain annual mass balance for 2015-2017 and for reconstruction of annual mass balances, Classical Temperature Index model were used with the help of meteorological data from Indian Meteorological Department. The data gaps were filled with the help of several modelled datasets viz. HAR (High Asia Reanalysis), REMO, and Climate Research Unit (CRU) TS2.1 dataset. We also present catchment wide change in volume of the glaciers since 1969 to 2015. Declassified satellite images and Landsat images were used to obtain the change in volume of the glacier with

  6. A mascon approach to assess ice sheet and glacier mass balances and their uncertainties from GRACE data

    Science.gov (United States)

    Schrama, Ernst J. O.; Wouters, Bert; Rietbroek, Roelof

    2014-07-01

    The purpose of this paper is to assess the mass changes of the Greenland Ice Sheet (GrIS), Ice Sheets over Antarctica, and Land glaciers and Ice Caps with a global mascon method that yields monthly mass variations at 10,242 mascons. Input for this method are level 2 data from the Gravity Recovery and Climate Experiment (GRACE) system collected between February 2003 and June 2013 to which a number of corrections are made. With glacial isostatic adjustment (GIA) corrections from an ensemble of models based on different ice histories and rheologic Earth model parameters, we find for Greenland a mass loss of -278 ± 19 Gt/yr. Whereas the mass balances for the GrIS appear to be less sensitive to GIA modeling uncertainties, this is not the case with the mass balance of Antarctica. Ice history models for Antarctica were recently improved, and updated historic ice height data sets and GPS time series have been used to generate new GIA models. We investigated the effect of two new GIA models for Antarctica and found -92 ± 26 Gt/yr which is half of what is obtained with ICE-5G-based GIA models, where the largest GIA model differences occur on East Antarctica. The mass balance of land glaciers and ice caps currently stands at -162 ± 10 Gt/yr. With the help of new GIA models for Antarctica, we assess the mass contribution to the mean sea level at 1.47 ± 0.09 mm/yr or 532 ± 34Gt/yr which is roughly half of the global sea level rise signal obtained from tide gauges and satellite altimetry.

  7. Glacier Mass Balance and Regime Measurements and Analysis, 1945-2003, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of glacier regime parameters observed between 1945 and 2003. Data include annual mass balances, ablation, accumulation, and equilibrium-line...

  8. Quantifying the Mass Balance of Ice Caps on Severnaya Zemlya, Russian High Arctic. I: Climate and Mass Balance of the Vavilov Ice Cap

    NARCIS (Netherlands)

    Bassford, R.P.; Siegert, M.J.; Dowdeswell, J.A.; Oerlemans, J.; Glazovsky, A.F.; Macheret, Y.Y.

    2006-01-01

    Due to their remote location within the Russian High Arctic, little is known about the mass balance of ice caps on Severnaya Zemlya now and in the past. Such information is critical, however, to building a global picture of the cryospheric response to climate change. This paper provides a numerical

  9. Ocean Basalt Simulator version 1 (OBS1): Trace element mass balance in adiabatic melting of a pyroxenite-bearing peridotite

    Science.gov (United States)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2015-01-01

    We present a new numerical trace element mass balance model for adiabatic melting of a pyroxenite-bearing peridotite for estimating mantle potential temperature, depth of melting column, and pyroxenite fraction in the source mantle for a primary ocean basalt/picrite. The Ocean Basalt Simulator version 1 (OBS1) uses a thermodynamic model of adiabatic melting of a pyroxenite-bearing peridotite with experimentally/thermodynamically parameterized liquidus-solidus intervals and source mineralogy. OBS1 can be used to calculate a sequence of adiabatic melting with two melting models, including (1) melting of peridotite and pyroxenite sources with simple mixing of their fractional melts (melt-melt mixing model), and (2) pyroxenite melting, melt metasomatism in the host peridotite, and melting of the metasomatized peridotite (source-metasomatism model). OBS1 can be used to explore (1) the fractions of peridotite and pyroxenite, (2) mantle potential temperature, (3) pressure of termination of melting, (4) degree of melting, and (5) residual mode of the sources. In order to constrain these parameters, the model calculates a mass balance for 26 incompatible trace elements in the sources and in the generated basalt/picrite. OBS1 is coded in an Excel spreadsheet and runs with VBA macros. Using OBS1, we examine the source compositions and conditions of the mid-oceanic ridge basalts, Loihi-Koolau basalts in the Hawaiian hot spot, and Jurassic Shatsky Rise and Mikabu oceanic plateau basalts and picrites. The OBS1 model shows the physical conditions, chemical mass balance, and amount of pyroxenite in the source peridotite, which are keys to global mantle recycling.

  10. Determination of Interannual to Decadal Changes in Ice Sheet Mass Balance from Satellite Altimetry

    Science.gov (United States)

    Zwally, H. Jay; Busalacchi, Antonioa J. (Technical Monitor)

    2001-01-01

    A major uncertainty in predicting sea level rise is the sensitivity of ice sheet mass balance to climate change, as well as the uncertainty in present mass balance. Since the annual water exchange is about 8 mm of global sea level equivalent, the +/- 25% uncertainty in current mass balance corresponds to +/- 2 mm/yr in sea level change. Furthermore, estimates of the sensitivity of the mass balance to temperature change range from perhaps as much as - 10% to + 10% per K. Although the overall ice mass balance and seasonal and inter-annual variations can be derived from time-series of ice surface elevations from satellite altimetry, satellite radar altimeters have been limited in spatial coverage and elevation accuracy. Nevertheless, new data analysis shows mixed patterns of ice elevation increases and decreases that are significant in terms of regional-scale mass balances. In addition, observed seasonal and interannual variations in elevation demonstrate the potential for relating the variability in mass balance to changes in precipitation, temperature, and melting. From 2001, NASA's ICESat laser altimeter mission will provide significantly better elevation accuracy and spatial coverage to 86 deg latitude and to the margins of the ice sheets. During 3 to 5 years of ICESat-1 operation, an estimate of the overall ice sheet mass balance and sea level contribution will be obtained. The importance of continued ice monitoring after the first ICESat is illustrated by the variability in the area of Greenland surface melt observed over 17-years and its correlation with temperature. In addition, measurement of ice sheet changes, along with measurements of sea level change by a series of ocean altimeters, should enable direct detection of ice level and global sea level correlations.

  11. Mass balance and hydrological contribution of glaciers in northern and central Chile

    Science.gov (United States)

    MacDonell, Shelley; Vivero, Sebastian; McPhee, James; Ayala, Alvaro; Pellicciotti, Francesca; Campos, Cristian; Caro, Dennys; Ponce, Rodrigo

    2016-04-01

    Water is a critical resource in the northern and central regions of Chile, as the area supports more than 40% of the country's population, and the regional economy depends on agricultural production and mining, which are two industries that rely heavily on a consistent water supply. Due to relatively low rates of rainfall, meltwater from snow and ice bodies in the highland areas provides a key component of the annual water supply in these areas. Consequently, accurate estimates of the rates of ablation of the cryosphere (i.e. snow and ice) are crucial for predicting current supply rates, and future projections. Whilst snow is generally a larger contributor of freshwater, during periods of drought, glaciers provide a significant source. This study aims to determine the contribution of glaciers to two catchments in northern and central Chile during a 2.5 year period, which largely consisted of extreme dry periods, but also included the recent El Niño event. This study combined field and modelling studies to understand glacier and rock glacier contributions in the Tapado (30°S), Yeso (33°S) catchments. In the field we undertook glaciological mass balance monitoring of three glaciers, monitored albedo and snow line changes using automatic cameras for three glaciers, measured discharge continuously at several points, installed six automatic weather stations and used thermistors to monitor thermal regime changes of two rock glaciers. The combination of these datasets where used to drive energy balance and hydrological models to estimate the contribution of ice bodies to streamflow in the two studied catchments. Over the course of the study all glaciers maintained a negative mass balance, however glaciers in central Chile lost more mass, which is due to the higher melt rates experienced due to lower elevations and higher temperatures. Areas free of debris generally contributed more to streamflow than sediment covered regions, and snow generally contributed more over

  12. Detecting high spatial variability of ice shelf basal mass balance, Roi Baudouin Ice Shelf, Antarctica

    Science.gov (United States)

    Berger, Sophie; Drews, Reinhard; Helm, Veit; Sun, Sainan; Pattyn, Frank

    2017-11-01

    Ice shelves control the dynamic mass loss of ice sheets through buttressing and their integrity depends on the spatial variability of their basal mass balance (BMB), i.e. the difference between refreezing and melting. Here, we present an improved technique - based on satellite observations - to capture the small-scale variability in the BMB of ice shelves. As a case study, we apply the methodology to the Roi Baudouin Ice Shelf, Dronning Maud Land, East Antarctica, and derive its yearly averaged BMB at 10 m horizontal gridding. We use mass conservation in a Lagrangian framework based on high-resolution surface velocities, atmospheric-model surface mass balance and hydrostatic ice-thickness fields (derived from TanDEM-X surface elevation). Spatial derivatives are implemented using the total-variation differentiation, which preserves abrupt changes in flow velocities and their spatial gradients. Such changes may reflect a dynamic response to localized basal melting and should be included in the mass budget. Our BMB field exhibits much spatial detail and ranges from -14.7 to 8.6 m a-1 ice equivalent. Highest melt rates are found close to the grounding line where the pressure melting point is high, and the ice shelf slope is steep. The BMB field agrees well with on-site measurements from phase-sensitive radar, although independent radar profiling indicates unresolved spatial variations in firn density. We show that an elliptical surface depression (10 m deep and with an extent of 0.7 km × 1.3 km) lowers by 0.5 to 1.4 m a-1, which we tentatively attribute to a transient adaptation to hydrostatic equilibrium. We find evidence for elevated melting beneath ice shelf channels (with melting being concentrated on the channel's flanks). However, farther downstream from the grounding line, the majority of ice shelf channels advect passively (i.e. no melting nor refreezing) toward the ice shelf front. Although the absolute, satellite-based BMB values remain uncertain, we have

  13. Detecting high spatial variability of ice shelf basal mass balance, Roi Baudouin Ice Shelf, Antarctica

    Directory of Open Access Journals (Sweden)

    S. Berger

    2017-11-01

    Full Text Available Ice shelves control the dynamic mass loss of ice sheets through buttressing and their integrity depends on the spatial variability of their basal mass balance (BMB, i.e. the difference between refreezing and melting. Here, we present an improved technique – based on satellite observations – to capture the small-scale variability in the BMB of ice shelves. As a case study, we apply the methodology to the Roi Baudouin Ice Shelf, Dronning Maud Land, East Antarctica, and derive its yearly averaged BMB at 10 m horizontal gridding. We use mass conservation in a Lagrangian framework based on high-resolution surface velocities, atmospheric-model surface mass balance and hydrostatic ice-thickness fields (derived from TanDEM-X surface elevation. Spatial derivatives are implemented using the total-variation differentiation, which preserves abrupt changes in flow velocities and their spatial gradients. Such changes may reflect a dynamic response to localized basal melting and should be included in the mass budget. Our BMB field exhibits much spatial detail and ranges from −14.7 to 8.6 m a−1 ice equivalent. Highest melt rates are found close to the grounding line where the pressure melting point is high, and the ice shelf slope is steep. The BMB field agrees well with on-site measurements from phase-sensitive radar, although independent radar profiling indicates unresolved spatial variations in firn density. We show that an elliptical surface depression (10 m deep and with an extent of 0.7 km × 1.3 km lowers by 0.5 to 1.4 m a−1, which we tentatively attribute to a transient adaptation to hydrostatic equilibrium. We find evidence for elevated melting beneath ice shelf channels (with melting being concentrated on the channel's flanks. However, farther downstream from the grounding line, the majority of ice shelf channels advect passively (i.e. no melting nor refreezing toward the ice shelf front. Although the absolute, satellite

  14. Hydrogenation of rapeseed oil for production of liquid bio-chemicals

    International Nuclear Information System (INIS)

    Pinto, F.; Martins, S.; Gonçalves, M.; Costa, P.; Gulyurtlu, I.; Alves, A.; Mendes, B.

    2013-01-01

    Highlights: ► Production of renewable liquid hydrocarbons through rapeseed oil hydrogenation. ► Hydrogenation at lower temperature and lower hydrogen pressures. ► Test of a catalyst commonly employed in petrochemical industry. ► Improve of hydrogenation process viability by decreasing operational costs. ► Analysis of hydrogenated product applications as bio-chemicals. -- Abstract: The main objective of rapeseed oil hydrogenation tests was the production of liquid bio-chemicals to be used as renewable raw material for the production of several chemicals and in chemical synthesis to substitute petroleum derived stuff. As, hydrogenation of vegetable oils is already applied for the production of biofuels, the work done focused in producing aromatic compounds, due to their economic value. The effect of experimental conditions on rapeseed oil hydrogenation was studied, namely, reaction temperature and time with the aim of selecting the most favourable conditions to convert rapeseed oil into liquid valuable bio-chemicals. Rapeseed oil was hydrogenated at a hydrogen initial pressure of 1.10 MPa. Reaction temperature varied in the range from 200 °C to 400 °C, while reaction times between 6 and 180 min were tested. The performance of a commercial cobalt and molybdenum catalyst was also studied. The highest hydrocarbons yields were obtained at the highest temperature and reaction times tested. At a temperature of 400 °C and at the reaction time of 120 min hydrocarbons yield was about 92% in catalyst presence, while in the absence of the catalyst this value decreased to 85%. Hydrocarbons yield was even higher when the reaction time of 180 min was used in the presence of catalyst, as the yield of 97% was observed. At these conditions hydrocarbons formed had a high content of aromatic compounds, around 50%. For this reason, the viscosity values of hydrogenated oils were lower than that established by EN590, which together with hydrogenated liquids composition

  15. Re-assessment of recent (2008–2013 surface mass balance over Dome Argus, Antarctica

    Directory of Open Access Journals (Sweden)

    Minghu Ding

    2016-04-01

    Full Text Available At Dome Argus, East Antarctica, the surface mass balance (SMB from 2008 to 2013 was evaluated using 49 stakes installed across a 30×30 km area. Spatial analysis showed that at least 12 and 20 stakes are needed to obtain reliable estimates of SMB at local scales (a few hundred square metres and regional scales (tens of square kilometres, respectively. The estimated annual mean SMB was 22.9±5.9 kg m−2 yr−1, including a net loss by sublimation of −2.22±0.02 kg m−2 yr−1 and a mass gain by deposition of 1.37±0.01 kg m−2 yr−1. Therefore, ca. 14.3% of precipitation was modified after deposition, which should be considered when interpreting snow or ice core records produced by future drilling projects. The surface snow density and SMB in the western portion of Dome Argus are higher than in other areas, and these differences are likely related to the katabatic wind, which is strengthened by topography in this sector. A new digital elevation model (DEM of Dome Argus was generated, confirming that both peaks of the dome can be considered as the summit of the East Antarctic Ice Sheet. Findings from this study should be valuable for validating SMB estimates obtained from regional climate models and DEMs established using remote-sensing data.

  16. Sugarcane bagasse pretreatment using three imidazolium-based ionic liquids; mass balances and enzyme kinetics

    Directory of Open Access Journals (Sweden)

    Karatzos Sergios

    2012-08-01

    Full Text Available Abstract Background Effective pretreatment is key to achieving high enzymatic saccharification efficiency in processing lignocellulosic biomass to fermentable sugars, biofuels and value-added products. Ionic liquids (ILs, still relatively new class of solvents, are attractive for biomass pretreatment because some demonstrate the rare ability to dissolve all components of lignocellulosic biomass including highly ordered (crystalline cellulose. In the present study, three ILs, 1-butyl-3-methylimidazolium chloride ([C4mim]Cl, 1-ethyl-3-methylimidazolium chloride ([C2mim]Cl, 1-ethyl-3-methylimidazolium acetate ([C2mim]OAc are used to dissolve/pretreat and fractionate sugarcane bagasse. In these IL-based pretreatments the biomass is completely or partially dissolved in ILs at temperatures greater than 130°C and then precipitated by the addition of an antisolvent to the IL biomass mixture. For the first time mass balances of IL-based pretreatments are reported. Such mass balances, along with kinetics data, can be used in process modelling and design. Results Lignin removals of 10% mass of lignin in bagasse with [C4mim]Cl, 50% mass with [C2mim]Cl and 60% mass with [C2mim]OAc, are achieved by limiting the amount of water added as antisolvent to 0.5 water:IL mass ratio thus minimising lignin precipitation. Enzyme saccharification (24 h, 15FPU yields (% cellulose mass in starting bagasse from the recovered solids rank as: [C2mim]OAc(83% > >[C2mim]Cl(53% = [C4mim]Cl(53%. Composition of [C2mim]OAc-treated solids such as low lignin, low acetyl group content and preservation of arabinosyl groups are characteristic of aqueous alkali pretreatments while those of chloride IL-treated solids resemble aqueous acid pretreatments. All ILs are fully recovered after use (100% mass as determined by ion chromatography. Conclusions In all three ILs regulated addition of water as an antisolvent effected a polysaccharide enriched precipitate since some of the lignin

  17. Geodetic mass balance of the Patagonian Icefields from STRM and TanDEM-X DEMs

    Science.gov (United States)

    Abdel Jaber, W.; Floricioiu, D.; Rott, H.

    2016-12-01

    The Northern and Southern Patagonian Icefields (NPI & SPI), represent the largest mid-latitude ice masses in the Southern Hemisphere. They are mostly drained by outlet glaciers with fronts calving into fresh water lakes or Pacific fjords. Both icefields were affected by significant downwasting in the last decades, as confirmed by published mass change trends obtained by means of gravimetric measurements and geodetic methods. Given their unique characteristics and the significant contribution to sea level rise per unit of area, they represent a fundamental barometer for climate research. The Shuttle Radar Topography Mission (SRTM) of 2000 provided the most complete and accurate Digital Elevation Model (DEM) at the time covering the entire globe from 56°S to 60°N. The present TanDEM-X mission shares the same objective aiming at a global coverage with much higher resolution and accuracy. Their combination leads to a unique multitemporal elevation dataset based solely on SAR single pass bistatic interferometry characterized by 11 to 16 year time span: an ideal setup for monitoring long-term large-scale geophysical phenomena. Using this dataset, detailed and extensive ice elevation change maps were obtained for the 12900 km² SPI for the observation period 2000 - 2011/2012 and for the 3900 km² NPI for the period 2000 - 2014. These maps were used to compute the glacier mass balance of the icefields through the geodetic method. Particular emphasis was set on the estimation of the uncertainty of the geodetic mass balance by quantifying all relevant sources of error. Among these, signal penetration into dry ice and snow can affect considerably radar elevation measurements. For this purpose the backscattering coefficient of the acquisitions along with concurrent meteorological data were analyzed to assess the conditions of the icefield surface. Mass change rates of -3.96±0.14 Gt a-1 and of -13.14±0.42 Gt a-1 (excluding subaqueous loss) were obtained for NPI and SPI

  18. Radar Interferometry Studies of the Mass Balance of Polar Ice Sheets

    Science.gov (United States)

    Rignot, Eric (Editor)

    1999-01-01

    The objectives of this work are to determine the current state of mass balance of the Greenland and Antarctic Ice Sheets. Our approach combines different techniques, which include satellite synthetic-aperture radar interferometry (InSAR), radar and laser altimetry, radar ice sounding, and finite-element modeling. In Greenland, we found that 3.5 times more ice flows out of the northern part of the Greenland Ice Sheet than previously accounted for. The discrepancy between current and past estimates is explained by extensive basal melting of the glacier floating sections in the proximity of the grounding line where the glacier detaches from its bed and becomes afloat in the ocean. The inferred basal melt rates are very large, which means that the glaciers are very sensitive to changes in ocean conditions. Currently, it appears that the northern Greenland glaciers discharge more ice than is being accumulated in the deep interior, and hence are thinning. Studies of temporal changes in grounding line position using InSAR confirm the state of retreat of northern glaciers and suggest that thinning is concentrated at the lower elevations. Ongoing work along the coast of East Greenland reveals an even larger mass deficit for eastern Greenland glaciers, with thinning affecting the deep interior of the ice sheet. In Antarctica, we found that glaciers flowing into a large ice shelf system, such as the Ronne Ice Shelf in the Weddell Sea, exhibit an ice discharge in remarkable agreement with mass accumulation in the interior, and the glacier grounding line positions do not migrate with time. Glaciers flowing rapidly into the Amudsen Sea, unrestrained by a major ice shelf, are in contrast discharging more ice than required to maintain a state of mass balance and are thinning quite rapidly near the coast. The grounding line of Pine Island glacier (see diagram) retreated 5 km in 4 years, which corresponds to a glacier thinning rate of 3.5 m/yr. Mass imbalance is even more negative

  19. Mass-balance measurements in Alaska and suggestions for simplified observation programs

    Science.gov (United States)

    Trabant, D.C.; March, R.S.

    1999-01-01

    US Geological Survey glacier fieldwork in Alaska includes repetitious measurements, corrections for leaning or bending stakes, an ability to reliably measure seasonal snow as deep as 10 m, absolute identification of summer surfaces in the accumulation area, and annual evaluation of internal accumulation, internal ablation, and glacier-thickness changes. Prescribed field measurement and note-taking techniques help eliminate field errors and expedite the interpretative process. In the office, field notes are transferred to computerized spread-sheets for analysis, release on the World Wide Web, and archival storage. The spreadsheets have error traps to help eliminate note-taking and transcription errors. Rigorous error analysis ends when mass-balance measurements are extrapolated and integrated with area to determine glacier and basin mass balances. Unassessable errors in the glacier and basin mass-balance data reduce the value of the data set for correlations with climate change indices. The minimum glacier mass-balance program has at least three measurement sites on a glacier and the measurements must include the seasonal components of mass balance as well as the annual balance.

  20. Genomic analysis of thermophilic Bacillus coagulans strains: efficient producers for platform bio-chemicals.

    Science.gov (United States)

    Su, Fei; Xu, Ping

    2014-01-29

    Microbial strains with high substrate efficiency and excellent environmental tolerance are urgently needed for the production of platform bio-chemicals. Bacillus coagulans has these merits; however, little genetic information is available about this species. Here, we determined the genome sequences of five B. coagulans strains, and used a comparative genomic approach to reconstruct the central carbon metabolism of this species to explain their fermentation features. A novel xylose isomerase in the xylose utilization pathway was identified in these strains. Based on a genome-wide positive selection scan, the selection pressure on amino acid metabolism may have played a significant role in the thermal adaptation. We also researched the immune systems of B. coagulans strains, which provide them with acquired resistance to phages and mobile genetic elements. Our genomic analysis provides comprehensive insights into the genetic characteristics of B. coagulans and paves the way for improving and extending the uses of this species.

  1. Bio-chemical properties of sandy calcareous soil treated with rice straw-based hydrogels

    Directory of Open Access Journals (Sweden)

    Houssni El-Saied

    2016-06-01

    The results obtained show that, application of the investigated hydrogels positively affects bio-chemical properties of the soil. These effects are assembled in the following: (a slightly decreasing soil pH, (b increasing cation exchange capacity (CEC of the soil indicating improvement in activating chemical reactions in the soil, (c increasing organic matter (OM, organic carbon, total nitrogen percent in the soil. Because the increase in organic nitrogen surpassed that in organic carbon, a narrower CN ratio of treated soils was obtained. This indicated the mineralization of nitrogen compounds and hence the possibility to save and provide available forms of N to growing plants, (d increasing available N, P and K in treated soil, and (e improving biological activity of the soil expressed as total count of bacteria and counts of Azotobacter sp., phosphate dissolving bacteria (PDB, fungi and actinomycetes/g soil as well as the activity of both dehydrogenase and phosphatase.

  2. G-protein-Coupled Receptors and Their (Bio Chemical Significance Win 2012 Nobel Prize in Chemistry

    Directory of Open Access Journals (Sweden)

    Hsi-Hsien Lin

    2013-06-01

    Full Text Available G-protein-coupled receptors (GPCRs are seven transmembrane cell surface proteins specialized in cellular communication. These receptors represent a major gateway through which cells convert external cues into intracellular signals and respond with appropriate actions. While the effects of hormones, neurotransmitters, and drugs on cells, tissues, organs, and even whole organisms are well described, the molecular identity of the direct targets and the diverse signaling mechanisms of these biological ligands have been slow and hard to define. The Nobel Prize in Chemistry for the year 2012 acknowledges the importance of GPCRs in these processes, especially for the contribution of Profs Robert J. Lefkowitz and Brian K. Kobilka to the studies of GPCRs. In this brief review, the seminal works accomplished by the two GPCR pioneers are summarized and the (bio chemical significance of GPCRs in health and disease is discussed.

  3. G-protein-coupled receptors and their (Bio) chemical significance win 2012 Nobel Prize in Chemistry.

    Science.gov (United States)

    Lin, Hsi-Hsien

    2013-01-01

    G-protein-coupled receptors (GPCRs) are seven transmembrane cell surface proteins specialized in cellular communication. These receptors represent a major gateway through which cells convert external cues into intracellular signals and respond with appropriate actions. While the effects of hormones, neurotransmitters, and drugs on cells, tissues, organs, and even whole organisms are well described, the molecular identity of the direct targets and the diverse signaling mechanisms of these biological ligands have been slow and hard to define. The Nobel Prize in Chemistry for the year 2012 acknowledges the importance of GPCRs in these processes, especially for the contribution of Profs Robert J. Lefkowitz and Brian K. Kobilka to the studies of GPCRs. In this brief review, the seminal works accomplished by the two GPCR pioneers are summarized and the (bio) chemical significance of GPCRs in health and disease is discussed.

  4. Assessment of uncertainties of an aircraft-based mass balance approach for quantifying urban greenhouse gas emissions

    Science.gov (United States)

    Cambaliza, M. O. L.; Shepson, P. B.; Caulton, D. R.; Stirm, B.; Samarov, D.; Gurney, K. R.; Turnbull, J.; Davis, K. J.; Possolo, A.; Karion, A.; Sweeney, C.; Moser, B.; Hendricks, A.; Lauvaux, T.; Mays, K.; Whetstone, J.; Huang, J.; Razlivanov, I.; Miles, N. L.; Richardson, S. J.

    2014-09-01

    Urban environments are the primary contributors to global anthropogenic carbon emissions. Because much of the growth in CO2 emissions will originate from cities, there is a need to develop, assess, and improve measurement and modeling strategies for quantifying and monitoring greenhouse gas emissions from large urban centers. In this study the uncertainties in an aircraft-based mass balance approach for quantifying carbon dioxide and methane emissions from an urban environment, focusing on Indianapolis, IN, USA, are described. The relatively level terrain of Indianapolis facilitated the application of mean wind fields in the mass balance approach. We investigate the uncertainties in our aircraft-based mass balance approach by (1) assessing the sensitivity of the measured flux to important measurement and analysis parameters including wind speed, background CO2 and CH4, boundary layer depth, and interpolation technique, and (2) determining the flux at two or more downwind distances from a point or area source (with relatively large source strengths such as solid waste facilities and a power generating station) in rapid succession, assuming that the emission flux is constant. When we quantify the precision in the approach by comparing the estimated emissions derived from measurements at two or more downwind distances from an area or point source, we find that the minimum and maximum repeatability were 12 and 52%, with an average of 31%. We suggest that improvements in the experimental design can be achieved by careful determination of the background concentration, monitoring the evolution of the boundary layer through the measurement period, and increasing the number of downwind horizontal transect measurements at multiple altitudes within the boundary layer.

  5. Winter mass balance of Drangajökull ice cap (NW Iceland derived from satellite sub-meter stereo images

    Directory of Open Access Journals (Sweden)

    J. M. C. Belart

    2017-06-01

    Full Text Available Sub-meter resolution, stereoscopic satellite images allow for the generation of accurate and high-resolution digital elevation models (DEMs over glaciers and ice caps. Here, repeated stereo images of Drangajökull ice cap (NW Iceland from Pléiades and WorldView2 (WV2 are combined with in situ estimates of snow density and densification of firn and fresh snow to provide the first estimates of the glacier-wide geodetic winter mass balance obtained from satellite imagery. Statistics in snow- and ice-free areas reveal similar vertical relative accuracy ( <  0.5 m with and without ground control points (GCPs, demonstrating the capability for measuring seasonal snow accumulation. The calculated winter (14 October 2014 to 22 May 2015 mass balance of Drangajökull was 3.33 ± 0.23 m w.e. (meter water equivalent, with ∼ 60 % of the accumulation occurring by February, which is in good agreement with nearby ground observations. On average, the repeated DEMs yield 22 % less elevation change than the length of eight winter snow cores due to (1 the time difference between in situ and satellite observations, (2 firn densification and (3 elevation changes due to ice dynamics. The contributions of these three factors were of similar magnitude. This study demonstrates that seasonal geodetic mass balance can, in many areas, be estimated from sub-meter resolution satellite stereo images.

  6. Mass Balance Applied to Brazilian Conventional Broiler Houses during One Production Cycle

    Directory of Open Access Journals (Sweden)

    A Migliavacca

    Full Text Available ABSTRACT Brazil plays an important role in global poultry production as it is the world's largest chicken exporter and the third largest broiler producer. Despite the development achieved by the Brazilian broiler industry as a result of the integrated production system, many obstacles still need to be overcome, in particular, housing environment. In this regard, detailed knowledge of the inputs, outputs, and primary waste generated by broiler production cycles is essential to establish a baseline for energy balance research studies and to develop environmental solutions. This article proposes a mass balance of conventional broiler houses of southern Brazil sheds in order to predict their outputs, but that may also be applicable to other regions with similar climate. Control volumes considered the heating, cooling, and rearing processes. All generated products and wastes were estimated considering litter production and the total production per cycle. Despite the variety of the microclimates, the results were very close to those reported in experiments, indicating that this model is adequate for this kind of estimation.

  7. A sensitivity analysis of the mass balance equation terms in subcooled flow boiling

    International Nuclear Information System (INIS)

    Braz Filho, Francisco A.; Caldeira, Alexandre D.; Borges, Eduardo M.

    2013-01-01

    In a heated vertical channel, the subcooled flow boiling occurs when the fluid temperature reaches the saturation point, actually a small overheating, near the channel wall while the bulk fluid temperature is below this point. In this case, vapor bubbles are generated along the channel resulting in a significant increase in the heat flux between the wall and the fluid. This study is particularly important to the thermal-hydraulics analysis of Pressurized Water Reactors (PWRs). The computational fluid dynamics software FLUENT uses the Eulerian multiphase model to analyze the subcooled flow boiling. In a previous paper, the comparison of the FLUENT results with experimental data for the void fraction presented a good agreement, both at the beginning of boiling as in nucleate boiling at the end of the channel. In the region between these two points the comparison with experimental data was not so good. Thus, a sensitivity analysis of the mass balance equation terms, steam production and condensation, was performed. Factors applied to the terms mentioned above can improve the agreement of the FLUENT results to the experimental data. Void fraction calculations show satisfactory results in relation to the experimental data in pressures values of 15, 30 and 45 bars. (author)

  8. The role of mass balance equations in growth mechanics illustrated in surface and volume dissolutions.

    Science.gov (United States)

    Ateshian, Gerard A

    2011-01-01

    Growth mechanics problems require the solution of mass balance equations that include supply terms and account for mass exchanges among constituents of a mixture. Though growth may often be accompanied by a variety of concomitant phenomena that increase modeling complexity, such as solid matrix deformation, evolving traction-free configurations, cell division, and active cell contraction, it is important to distinguish these accompanying phenomena from the fundamental growth process that consists of deposition or removal of mass from the solid matrix. Therefore, the objective of this study is to present a canonical problem of growth, namely, dissolution of a rigid solid matrix in a solvent. This problem illustrates a case of negative growth (loss of mass) of the solid in a mixture framework that includes three species, a solid, a solvent, and a solute, where the solute is the product of the solid dissolution. By analyzing both volumetric and surface dissolutions, the two fundamental modes of growth are investigated within the unified framework of mixture theory.

  9. Basin Excavation, Lower Crust, Composition, and Bulk Moon Mass balance in Light of a Thin Crust

    Science.gov (United States)

    Jolliff, B. L.; Korotev, R. L.; Ziegler, R. A.

    2013-01-01

    New lunar gravity results from GRAIL have been interpreted to reflect an overall thin and low-density lunar crust. Accordingly, crustal thickness has been modeled as ranging from 0 to 60 km, with thinnest crust at the locations of Crisium and Moscoviense basins and thickest crust in the central farside highlands. The thin crust has cosmochemical significance, namely in terms of implications for the Moon s bulk composition, especially refractory lithophile elements that are strongly concentrated in the crust. Wieczorek et al. concluded that the bulk Moon need not be enriched compared to Earth in refractory lithophile elements such as Al. Less Al in the crust means less Al has been extracted from the mantle, permitting relatively low bulk lunar mantle Al contents and low pre- and post-crust-extraction values for the mantle (or the upper mantle if only the upper mantle underwent LMO melting). Simple mass-balance calculations using the method of [4] suggests that the same conclusion might hold for Th and the entire suite of refractory lithophile elements that are incompatible in olivine and pyroxene, including the KREEP elements, that are likewise concentrated in the crust.

  10. Reconstruction of specific mass balance for glaciers in Western ...

    Indian Academy of Sciences (India)

    Vinay Kumar Gaddam

    2017-06-12

    Jun 12, 2017 ... Press, Birlington, MA, pp. 318–321. Pellicciotti F, Helbing J, Rivera A, Favier V, Corripio J,. Araos J, Sicard J E, and Carenzo M 2008 A study of the energy balance and melt regime on Juncal Norte glacier, semi-arid Andes of Central Chile, using melt models of different complexity; Hydrol. Process. 22 3980–.

  11. Decadal-scale joint inversion of NOx and SO2 using a hybrid 4D-Var / mass balance approach

    Science.gov (United States)

    Qu, Z.; Henze, D. K.; Capps, S.; Wang, Y.; Xu, X.; Wang, J.; Keller, M.

    2016-12-01

    Quantifying the emissions of nitrogen oxides (NOx) and sulfur dioxide (SO2) is important for improving our understanding of acid rain, formation of aerosols, and human health problems. Traditional top-down estimates have provided valuable constraints for NOx and SO2 emission inventories in China, but are either time-consuming (e.g., 4D-Var) or only crudely represent the influence of atmospheric transport and chemistry (e.g., mass balance). We develop an approach combining mass balance and an adjoint-based four-dimensional variational (4D-Var) methods that facilitates decadal-scale emission inversions. This hybrid inversion is first evaluated with a single species inversion using NO2 pseudo observations. In a set of seven-year pseudo observation test, hybrid posterior NOx emissions have smaller normalized mean square error (by 54% to 94%) than that of mass balance when compared to true emissions in most cases, and have slightly better performance in detecting emissions magnitudes and trends. Using this hybrid method, NO2 observations from the Ozone Monitoring Instrument (OMI), and the GEOS-Chem chemical transport model, we have derived monthly top-down NOx emissions for China from 2005 to 2012. Our posterior emissions have the same seasonality as recent bottom-up inventories, and smaller emissions (by 13.4% to 23.5%) as well as emission growth rate (by 0.6% to 4.1%). The hybrid method is further implemented for long-term joint inversion of NOx and SO2 emissions in China using combined observations of OMI NO2 and SO2 column densities. A 4D-Var inversion is first performed to optimize NOx and SO2 emissions in the base year using GEOS-Chem adjoint. Mass balance scaling factor is then applied to these posterior to improve their inter-annual variation. Overall, these studies augment the utility of remote sensing data for evaluating emission control strategies and mitigating the impact of NOx and SO2 on human health and the environment.

  12. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005–2015

    Science.gov (United States)

    Clark, Adam; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, −3.41, and −0.40 m w.e. yr−1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  13. Glaciological measurements and mass balances from Sperry Glacier, Montana, USA, years 2005-2015

    Science.gov (United States)

    Clark, Adam M.; Fagre, Daniel B.; Peitzsch, Erich H.; Reardon, Blase A.; Harper, Joel T.

    2017-01-01

    Glacier mass balance measurements help to provide an understanding of the behavior of glaciers and their response to local and regional climate. In 2005 the United States Geological Survey established a surface mass balance monitoring program on Sperry Glacier, Montana, USA. This project is the first quantitative study of mass changes of a glacier in the US northern Rocky Mountains and continues to the present. The following paper describes the methods used during the first 11 years of measurements and reports the associated results. From 2005 to 2015, Sperry Glacier had a cumulative mean mass balance loss of 4.37 m w.e. (water equivalent). The mean winter, summer, and annual glacier-wide mass balances were 2.92, -3.41, and -0.40 m w.e. yr-1 respectively. We derive these cumulative and mean results from an expansive data set of snow depth, snow density, and ablation measurements taken at selected points on the glacier. These data allow for the determination of mass balance point values and a time series of seasonal and annual glacier-wide mass balances for all 11 measurement years. We also provide measurements of glacier extent and accumulation areas for select years. All data have been submitted to the World Glacier Monitoring Service and are available at fog-2016-08" target="_blank">doi:10.5904/wgms-fog-2016-08. This foundational work provides valuable insight about Sperry Glacier and supplies additional data to the worldwide record of glaciers measured using the glaciological method. Future research will focus on the processes that control accumulation and ablation patterns across the glacier. Also we plan to examine the uncertainties related to our methods and eventually quantify a more robust estimate of error associated with our results.

  14. SU-8 cantilevers for bio/chemical sensing; Fabrication, characterisation and development of novel read-out methods

    DEFF Research Database (Denmark)

    Nordström, M.; Keller, Stephan Urs; Lillemose, Michael

    2008-01-01

    Here, we present the activities within our research group over the last five years with cantilevers fabricated in the polymer SU-8. We believe that SU-8 is an interesting polymer for fabrication of cantilevers for bio/chemical sensing due to its simple processing and low Young's modulus. We show...

  15. Understanding Recent Mass Balance Changes of the Greenland Ice Sheet

    Science.gov (United States)

    vanderVeen, Cornelius

    2003-01-01

    The ultimate goal of this project is to better understand the current transfer of mass between the Greenland Ice Sheet, the world's oceans and the atmosphere, and to identify processes controlling the rate of this transfer, to be able to predict with greater confidence future contributions to global sea level rise. During the first year of this project, we focused on establishing longer-term records of change of selected outlet glaciers, reevaluation of mass input to the ice sheet and analysis of climate records derived from ice cores, and modeling meltwater production and runoff from the margins of the ice sheet.

  16. Evaluation of a mass-balance approach to determine consumptive water use in northeastern Illinois

    Science.gov (United States)

    Mills, Patrick C.; Duncker, James J.; Over, Thomas M.; Marian Domanski,; ,; Engel, Frank

    2014-01-01

    A principal component of evaluating and managing water use is consumptive use. This is the portion of water withdrawn for a particular use, such as residential, which is evaporated, transpired, incorporated into products or crops, consumed by humans or livestock, or otherwise removed from the immediate water environment. The amount of consumptive use may be estimated by a water (mass)-balance approach; however, because of the difficulty of obtaining necessary data, its application typically is restricted to the facility scale. The general governing mass-balance equation is: Consumptive use = Water supplied - Return flows.

  17. The mass balance of a Proton Exchange Membrane Fuel Cell (PEMFC)

    International Nuclear Information System (INIS)

    Miloud, S.; Kamaruzzaman Sopian; Wan Ramli Wan Daud

    2006-01-01

    A Proton Exchange Membrane Fuel Cell (PEMFC), operating at low temperature uses a simple chemical process to combine hydrogen and oxygen into water, producing electric current and heat during the electrochemical reaction. This work concern on the theoretical consideration of the mass balance has been evaluated to predict the mass flow rate of the both gases (hydrogen/oxygen), the water mass balance, and the heat transfer in order to design a single cell PEMFC stack with a better flow field distributor on the performance of Polymer Electrolyte membrane fuel cells

  18. Sensitivity of mountain glacier mass balance to changes in bare-ice albedo

    OpenAIRE

    Naegeli, Kathrin; Huss, Matthias

    2017-01-01

    Albedo is an important parameter in the energy balance of bare-ice surfaces and modulates glacier melt rates. The prolongation of the ablation period enforces the albedo feedback and highlights the need for profound knowledge on impacts of bare-ice albedo on glacier mass balance. In this study, we assess the mass balance sensitivity of 12 Swiss glaciers with abundant long-term in-situ data on changes in bare-ice albedo. We use pixel-based bare-ice albedo derived from Landsat 8. A distributed ...

  19. Can we close the long term mass balance equation for pollutants in highway ponds?

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby; Larsen, Torben; Rasmussen, Michael R.

    2007-01-01

    The paper discusses the prospects of finding the long term mass balance on basis of short term simulations. A step in this process is to see to which degree the mass balance equation can be closed by measurements. Accordingly the total accumulation of heavy metals and PAH's in 8 Danish detention...... ponds only receiving runoff from highways have been measured. The result shows that the incoming mass of heavy metals from short term runoff events is accumulated. This is not observable in the same magnitude for the toxic organic compounds. The results also show that the accumulation rates...

  20. Recharge Estimation Using Water, Chloride and Isotope Mass Balances

    Science.gov (United States)

    Dogramaci, S.; Firmani, G.; Hedley, P.; Skrzypek, G.; Grierson, P. F.

    2014-12-01

    Discharge of surplus mine water into ephemeral streams may elevate groundwater levels and alter the exchange rate between streams and underlying aquifers but it is unclear whether volumes and recharge processes are within the range of natural variability. Here, we present a case study of an ephemeral creek in the semi-arid subtropical Hamersley Basin that has received continuous mine discharge for more than five years. We used a numerical model coupled with repeated measurements of water levels, chloride concentrations and the hydrogen and oxygen stable isotope composition (δ2H and δ18O) to estimate longitudinal evapotranspiration and recharge rates along a 27 km length of Weeli Wolli Creek. We found that chloride increased from 74 to 120 mg/L across this length, while δ18O increased from -8.24‰ to -7.00‰. Groundwater is directly connected to the creek for the first 13 km and recharge rates are negligible. Below this point, the creek flows over a highly permeable aquifer and water loss by recharge increases to a maximum rate of 4.4 mm/d, which accounts for ~ 65% of the total water discharged to the creek. Evapotranspiration losses account for the remaining ~35%. The calculated recharge from continuous flow due to surplus water discharge is similar to that measured for rainfall-driven flood events along the creek. Groundwater under the disconnected section of the creek is characterised by a much lower Cl concentration and more depleted δ18O value than mining discharge water but is similar to flood water generated by large episodic rainfall events. Our results suggest that the impact of recharge from continuous flow on the creek has not extended beyond 27 km from the discharge point. Our approach using a combination of hydrochemical and isotope methods coupled with classical surface flow hydraulic modelling allowed evaluation of components of water budget otherwise not possible in a highly dynamic system that is mainly driven by infrequent but large episodic

  1. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    Energy Technology Data Exchange (ETDEWEB)

    Cooper, Clay A [DRI; Hershey, Ronald L [DRI; Healey, John M [DRI; Lyles, Brad F [DRI

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  2. On the importance of sublimation to an alpine snow mass balance in the Canadian Rocky Mountains

    Directory of Open Access Journals (Sweden)

    M. K. MacDonald

    2010-07-01

    Full Text Available A modelling study was undertaken to evaluate the contribution of sublimation to an alpine snow mass balance in the Canadian Rocky Mountains. Snow redistribution and sublimation by wind, snowpack sublimation and snowmelt were simulated for two winters over an alpine ridge transect located in the Canada Rocky Mountains. The resulting snowcover regimes were compared to those from manual snow surveys. Simulations were performed using physically based blowing snow (PBSM and snowpack ablation (SNOBAL models. A hydrological response unit (HRU-based spatial discretization was used rather than a more computationally expensive fully-distributed one. The HRUs were set up to follow an aerodynamic sequence, whereby eroded snow was transported from windswept, upwind HRUs to drift accumulating, downwind HRUs. That snow redistribution by wind can be adequately simulated in computationally efficient HRUs over this ridge has important implications for representing snow transport in large-scale hydrology models and land surface schemes. Alpine snow sublimation losses, in particular blowing snow sublimation losses, were significant. Snow mass losses to sublimation as a percentage of cumulative snowfall were estimated to be 20–32% with the blowing snow sublimation loss amounting to 17–19% of cumulative snowfall. This estimate is considered to be a conservative estimate of the blowing snow sublimation loss in the Canadian Rocky Mountains because the study transect is located in the low alpine zone where the topography is more moderate than the high alpine zone and windflow separation was not observed. An examination of the suitability of PBSM's sublimation estimates in this environment and of the importance of estimating blowing snow sublimation on the simulated snow accumulation regime was conducted by omitting sublimation calculations. Snow accumulation in HRUs was overestimated by 30% when neglecting blowing snow sublimation calculations.

  3. Mixing-cell boundary conditions and apparent mass balance errors for advective dispersive solute transport

    Science.gov (United States)

    Gimmi, Thomas; Flühler, Hannes

    1998-09-01

    In many field or laboratory situations, well-mixed reservoirs like, for instance, injection or detection wells and gas distribution or sampling chambers define boundaries of transport domains. Exchange of solutes or gases across such boundaries can occur through advective or diffusive processes. First we analyzed situations, where the inlet region consists of a well-mixed reservoir, in a systematic way by interpreting them in terms of injection type. Second, we discussed the mass balance errors that seem to appear in case of resident injections. Mixing cells (MC) can be coupled mathematically in different ways to a domain where advective-dispersive transport occurs: by assuming a continuous solute flux at the interface (flux injection, MC-FI), or by assuming a continuous resident concentration (resident injection). In the latter case, the flux leaving the mixing cell can be defined in two ways: either as the value when the interface is approached from the mixing-cell side (MC-RI-), or as the value when it is approached from the column side (MC-RI+). Solutions of these injection types with constant or—in one case—distance-dependent transport parameters were compared to each other as well as to a solution of a two-layer system, where the first layer was characterized by a large dispersion coefficient. These solutions differ mainly at small Péclet numbers. For most real situations, the model for resident injection MC-RI+ is considered to be relevant. This type of injection was modeled with a constant or with an exponentially varying dispersion coefficient within the porous medium. A constant dispersion coefficient will be appropriate for gases because of the Eulerian nature of the usually dominating gaseous diffusion coefficient, whereas the asymptotically growing dispersion coefficient will be more appropriate for solutes due to the Lagrangian nature of mechanical dispersion, which evolves only with the fluid flow. Assuming a continuous resident concentration at

  4. Mass balance evolution of Black Rapids Glacier, Alaska, 1980-2100, and its implications for surge recurrence

    Science.gov (United States)

    Kienholz, Christian; Hock, Regine; Truffer, Martin; Bieniek, Peter; Lader, Richard

    2017-07-01

    Surge-type Black Rapids Glacier, Alaska, has undergone strong retreat since it last surged in 1936-37. To assess its evolution during the late 20th and 21st centuries and determine potential implications for surge likelihood, we run a simplified glacier model over the periods 1980-2015 (hindcasting) and 2015-2100 (forecasting). The model is forced by daily temperature and precipitation fields, with downscaled reanalysis data used for the hindcasting. A constant climate scenario and an RCP 8.5 scenario based on the GFDL-CM3 climate model are employed for the forecasting. Debris evolution is accounted for by a debris layer time series derived from satellite imagery (hindcasting) and a parametrized debris evolution model (forecasting). A retreat model accounts for the evolution of the glacier geometry. Model calibration, validation and parametrization rely on an extensive set of in situ and remotely sensed observations. To explore uncertainties in our projections, we run the glacier model in a Monte Carlo fashion, varying key model parameters and input data within plausible ranges. Our results for the hindcasting period indicate a negative mass balance trend, caused by atmospheric warming in the summer, precipitation decrease in the winter and surface elevation lowering (climate-elevation feedback), which exceed the moderating effects from increasing debris cover and glacier retreat. Without the 2002 rockslide deposits on Black Rapids' lower reaches, the mass balances would be more negative, by 20% between the 2003 and 2015 mass-balance years. Despite its retreat, Black Rapids Glacier is substantially out of balance with the current climate. By 2100, 8% of Black Rapids' 1980 area are projected to vanish under the constant climate scenario and 73% under the RCP 8.5 scenario. For both scenarios, the remaining glacier portions are out of balance, suggesting continued retreat after 2100. Due to mass starvation, a surge in the 21st century is unlikely. The projected

  5. Effect of enhanced manganese oxidation in the hyporheic zone on basin-scale geochemical mass balance

    Science.gov (United States)

    Harvey, Judson W.; Fuller, Christopher C.

    1998-01-01

    cumulative effect of hyporheic exchange in Pinal Creek basin was to remove approximately 20% of the dissolved manganese flowing out of the drainage basin. Our results illustrate that the cumulative significance of reactive uptake in the hyporheic zone depends on the balance between chemical reaction rates, hyporheic porewater residence time, and turnover of streamflow through hyporheic flow paths. The similarity between the hyporheic reaction timescale (1/λs ≈ 1.3 hours), and the hyporheic porewater residence timescale (ts ≈ 8 min) ensured that there was adequate time for the reaction to progress. Furthermore, it was the similarity between the turnover length for stream water flow through hyporheic flow paths (Ls = stream velocity/storage-zone exchange coefficient ≈ 1.3 km) and the length of Pinal Creek (L ≈ 7 km), which ensured that all stream water passed through hyporheic flow paths several times. As a means to generalize our findings to other sites where similar types of hydrologic and chemical information are available, we suggest a cumulative significance index for hyporheic reactions, Rs = λstsL/Ls (dimensionless); higher values indicate a greater potential for hyporheic reactions to influence geochemical mass balance. Our experience in Pinal Creek basin suggests that values of Rs > 0.2 characterize systems where hyporheic reactions are likely to influence geochemical mass balance at the drainage-basin scale.

  6. The pattern of anthropogenic signal emergence in Greenland Ice Sheet surface mass balance

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.H.

    2014-01-01

    Surface mass balance (SMB) trends influence observed Greenland Ice Sheet (GrIS) mass loss, but the component of these trends related to anthropogenic forcing is unclear. Here we study the simulated spatial pattern of emergence of an anthropogenically derived GrIS SMB signal between 1850 and 2100

  7. Spent Nuclear Fuel (SNF) Project Canister Storage Building (CSB) Process Flow Diagram Mass Balance Calculations

    International Nuclear Information System (INIS)

    KLEM, M.J.

    2000-01-01

    The purpose of these calculations is to develop the material balances for documentation of the Canister Storage Building (CSB) Process Flow Diagram (PFD) and future reference. The attached mass balances were prepared to support revision two of the PFD for the CSB. The calculations refer to diagram H-2-825869

  8. Spent Nuclear Fuel (SNF) Project Multi Canister Overpack (MCO) Process Flow Diagram Mass Balance Calculations

    International Nuclear Information System (INIS)

    KLEM, M.J.

    2000-01-01

    The purpose of this calculation document is to develop the bases for the material balances of the Multi-Canister Overpack (MCO) Level 1 Process Flow Diagram (PFD). The attached mass balances support revision two of the PFD for the MCO and provide future reference

  9. Transdermal administration of radiolabelled [14C]rotigotine by a patch formulation: A mass balance trial

    NARCIS (Netherlands)

    Cawello, W.; Wolff, H.M.; Meuling, W.J.A.; Horstmann, R.; Braun, M.

    2007-01-01

    Background and objective: The dopamine agonist rotigotine has been formulated in a silicone-based transdermal system for once-daily administration. The objective of the present study was to characterise the mass balance of rotigotine in humans after administration of a single transdermal patch

  10. Future climate warming increases Greenland ice sheet surface mass balance variability

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.; Price, S.

    2014-01-01

    The integrated surface mass balance (SMB) of the Greenland ice sheet (GrIS) has large interannual variability. Long-term future changes to this variability will affect GrIS dynamics, freshwater fluxes, regional oceanography, and detection of changes in ice volume trends. Here we analyze a simulated

  11. Microbial transglutaminase production by Streptoverticillium mobaraense: Analysis of amino acid metabolism using mass balances

    NARCIS (Netherlands)

    Zhu, Y.; Rinzema, A.; Bonarius, H.P.J.; Tramper, J.; Bol, J.

    1998-01-01

    Metabolic flows, especially those of amino acids, were determined and analyzed at different stages of a batch fermentation for microbial transglutaminase production by Streptoverticillium mobaraense. The method is mainly based on mass balances and measurements of amino acids and other metabolites.

  12. Geodetic reanalysis of annual glaciological mass balances (2001-2011) of Hintereisferner, Austria

    Science.gov (United States)

    Klug, Christoph; Bollmann, Erik; Galos, Stephan Peter; Nicholson, Lindsey; Prinz, Rainer; Rieg, Lorenzo; Sailer, Rudolf; Stötter, Johann; Kaser, Georg

    2018-03-01

    This study presents a reanalysis of the glaciologically obtained annual glacier mass balances at Hintereisferner, Ötztal Alps, Austria, for the period 2001-2011. The reanalysis is accomplished through a comparison with geodetically derived mass changes, using annual high-resolution airborne laser scanning (ALS). The grid-based adjustments for the method-inherent differences are discussed along with associated uncertainties and discrepancies of the two methods of mass balance measurements. A statistical comparison of the two datasets shows no significant difference for seven annual, as well as the cumulative, mass changes over the 10-year record. Yet, the statistical view hides significant differences in the mass balance years 2002/03 (glaciological minus geodetic records = +0.92 m w.e.), 2005/06 (+0.60 m w.e.), and 2006/07 (-0.45 m w.e.). We conclude that exceptional meteorological conditions can render the usual glaciological observational network inadequate. Furthermore, we consider that ALS data reliably reproduce the annual mass balance and can be seen as validation or calibration tools for the glaciological method.

  13. Study of Annual Mass Balance (2011-2013) of Rikha Samba Glacier, Hidden Valley, Mustang, Nepal

    Science.gov (United States)

    Gurung, S.; Bhattrai, B. C.; Kayastha, R. B.; Stumm, D.; Joshi, S.; Mool, P. K.

    2016-12-01

    lthough Himalayan glaciers are of particular interest interms of future water supplies, regional climate changes, and sea-level rises, little is known about them due to lack of reliable and consistent data. There is a need for monitoring these glaciers to bridge this knowledge gap and to provide field measurements necessary to calibrate and validate the results from different remote sensing operations. Therefore, glaciological observations have been carried out by the Cryosphere Monitoring Project (CMP) since September 2011 on Rikha Samba Glacier in Hidden valley, Mustang district in western Nepal in order to study its annual mass balance. This paper presents the first results of that study. There are 10 glaciers in Hidden Valley, named G1, G2, G3, up to G10. Of these, G5 is the Rikha Samba Glacier, which has the largest area (5.37 km2) in this valley and the highest and lowest altitudes (6,476 and 5,392 m a.s.l., respectively). The glacier mass balance discussed in this paper was calculated using the glaciological method and the equilibrium line altitude (ELA).The glacier showed a negative annual point mass balance along the longitudinal profile of its lower part from September 10, 2011 to October 3, 2012. Stake measurements from October 4, 2012 to September 30, 2013 indicated a negative areal average of annual mass balance -0.088±0.019 m w.e. for the whole glacier. Based on these observations, the ELA of the Rikha Samba Glacier is estimated at 5,800 m a.s.l. in 2013. This negative balance may be due to rising air temperatures in the region, which have been incrementally rising since 1980 accompanied by little or no significant increase in precipitation in that period. The negative mass balance confirms the general shrinking trend of the glacier.

  14. Overview and Assessment of Antarctic Ice-Sheet Mass Balance Estimates: 1992-2009

    Science.gov (United States)

    Zwally, H. Jay; Giovinetto, Mario B.

    2011-01-01

    Mass balance estimates for the Antarctic Ice Sheet (AIS) in the 2007 report by the Intergovernmental Panel on Climate Change and in more recent reports lie between approximately ?50 to -250 Gt/year for 1992 to 2009. The 300 Gt/year range is approximately 15% of the annual mass input and 0.8 mm/year Sea Level Equivalent (SLE). Two estimates from radar altimeter measurements of elevation change by European Remote-sensing Satellites (ERS) (?28 and -31 Gt/year) lie in the upper part, whereas estimates from the Input-minus-Output Method (IOM) and the Gravity Recovery and Climate Experiment (GRACE) lie in the lower part (-40 to -246 Gt/year). We compare the various estimates, discuss the methodology used, and critically assess the results. We also modify the IOM estimate using (1) an alternate extrapolation to estimate the discharge from the non-observed 15% of the periphery, and (2) substitution of input from a field data compilation for input from an atmospheric model in 6% of area. The modified IOM estimate reduces the loss from 136 Gt/year to 13 Gt/year. Two ERS-based estimates, the modified IOM, and a GRACE-based estimate for observations within 1992 2005 lie in a narrowed range of ?27 to -40 Gt/year, which is about 3% of the annual mass input and only 0.2 mm/year SLE. Our preferred estimate for 1992 2001 is -47 Gt/year for West Antarctica, ?16 Gt/year for East Antarctica, and -31 Gt/year overall (?0.1 mm/year SLE), not including part of the Antarctic Peninsula (1.07% of the AIS area). Although recent reports of large and increasing rates of mass loss with time from GRACE-based studies cite agreement with IOM results, our evaluation does not support that conclusion

  15. Stabilization of heavy oil-water emulsions using a bio/chemical emulsifier mixture

    Energy Technology Data Exchange (ETDEWEB)

    Farahbakhsh, A.; Taghizadeh, M.; Movagharnejad, K. [Chemical Engineering Department, Babol University of Technology, Babol (Iran, Islamic Republic of); Yakhchali, B. [National Institute of Genetic Engineering and Biotechnology, Tehran (Iran, Islamic Republic of)

    2011-11-15

    In this study, the viscosity reduction of heavy oil has been investigated through the formation of oil-water emulsion using a bio/chemical emulsifier mixture. Four bioemulsifiers from indigenous Rhodococcus ergthropolis and Bacillus licheniformis strains were used to stabilize a highly-viscous oil-in-water emulsion. The Taguchi method with an L{sub 9} orthogonal array design was used to investigate the effect of various control factors on the formation of the oil/water emulsions. An emulsion with lowest viscosity was formed using ACO4 strain. The substantial stability of the oil-in-water emulsion allows the heavy oil to be transported practically over long distances or remain stationary for a considerable period of time prior to utilization. As the result of Taguchi analysis, the temperature and concentration of the emulsifier had a significant influence on viscosity reduction of the emulsion. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. An array of field-effect nanoplate SOI capacitors for (bio-)chemical sensing.

    Science.gov (United States)

    Abouzar, M H; Poghossian, A; Pedraza, A M; Gandhi, D; Ingebrandt, S; Moritz, W; Schöning, M J

    2011-02-15

    An array of individually addressable nanoplate field-effect capacitive (bio-)chemical sensors based on an SOI (silicon-on-insulator) structure has been developed. The isolation of the individual capacitors was achieved by forming a trench in the top Si layer with a thickness of 350 nm. The realized sensor array allows addressable biasing and electrical readout of multiple nanoplate EISOI (electrolyte-insulator-silicon-on-insulator) capacitive biosensors on the same SOI chip as well as differential-mode measurements. The feasibility of the proposed approach has been demonstrated by realizing sensors for the pH and penicillin concentration detection as well as for the label-free electrical monitoring of polyelectrolyte multilayers formation and DNA (deoxyribonucleic acid)-hybridization event. A potential change of ∼ 120 mV has been registered after the DNA hybridization for the sensor immobilized with perfectly matched single-strand DNA, while practically no signal changes have been observed for a sensor with fully mismatched DNA. The realized examples demonstrate the potential of the nanoplate SOI capacitors as a new basic structural element for the development of different types of field-effect biosensors. Copyright © 2010 Elsevier B.V. All rights reserved.

  17. Flow Type Bio-Chemical Calorimeter with Micro Differential Thermopile Sensor.

    Science.gov (United States)

    Saito, Masataka; Nakabeppu, Osamu

    2015-04-01

    Bio-chemical calorimeters with a MEMS (Micro-Electro-Mechanical Systems) thermopile sensor have been studied for monitoring detailed processes of the biochemical reactions of a minute sample with a high temporal resolution. The bio-calorimeters are generally divided into a batch-type and a flow-type. We developed a highly sensitive batch-type calorimeter which can detect a 100 nW level thermal reaction. However it shows a long settling time of 2 hours because of the heat capacity of a whole calorimeter. Thus, the flow-type calorimeters in passive and active mode have been studied for measuring the thermal reactions in an early stage after starting an analysis. The flow-type calorimeter consists of the MEMS differential thermopile sensor, a pair of micro channel reactor in a PDMS (polydimethylsiloxane) sheet in a three-fold thermostat chamber. The calorimeter in the passive mode was tested with dilution reactions of ethanol to water and NaCl aqueous solution to water. It was shown that the calorimeter detects exo- and endothermic reaction over 250 nW at solution flow rate of 0.05 ~ 1 µl/min with a settling time of about 4 minutes. In the active mode, a response test was conducted by using heat removal by water flow from the reactor channel. The active calorimetry enhances the response time about three to four times faster.

  18. Big (Bio)Chemical Data Mining Using Chemometric Methods: A Need for Chemists.

    Science.gov (United States)

    Tauler, Roma; Parastar, Hadi

    2018-03-23

    This review aims to demonstrate abilities to analyze Big (Bio)Chemical Data (BBCD) with multivariate chemometric methods and to show some of the more important challenges of modern analytical researches. In this review, the capabilities and versatility of chemometric methods will be discussed in light of the BBCD challenges that are being encountered in chromatographic, spectroscopic and hyperspectral imaging measurements, with an emphasis on their application to omics sciences. In addition, insights and perspectives on how to address the analysis of BBCD are provided along with a discussion of the procedures necessary to obtain more reliable qualitative and quantitative results. In this review, the importance of Big Data and of their relevance to (bio)chemistry are first discussed. Then, analytical tools which can produce BBCD are presented as well as some basics needed to understand prospects and limitations of chemometric techniques when they are applied to BBCD are given. Finally, the significance of the combination of chemometric approaches with BBCD analysis in different chemical disciplines is highlighted with some examples. In this paper, we have tried to cover some of the applications of big data analysis in the (bio)chemistry field. However, this coverage is not extensive covering everything done in the field. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Elevation change and remote-sensing mass-balance methods on the Greenland ice sheet

    DEFF Research Database (Denmark)

    Ahlstrøm, Andreas P.; Reeh, Niels; Christensen, Erik Lintz

    The mass balance of the Greenland Ice Sheet is virtually impossible to obtain with traditional ground-based methods alone due to its vast size. It is thus desirable to develop mass-balance methods depending on remote sensing instead and this field has experienced a dramatic development within...... the last decade. Large amounts of data have been collected from satellite and airborne platforms, yielding surface elevation changes and surface velocity fields. Here we present data from the Greenland Ice-Sheet margin acquired with a new small-scale airborne system, designed for regional high......-density coverage. During campaigns in 2000, 2003 and 2005, we have collected and processed ice-sheet surface elevation and ice-thickness data, acquired with a laser altimeter and a 60~MHz ice-penetrating radar. Both instruments were mounted on a small Twin-Otter aircraft which were positioned using three onboard...

  20. High-resolution DEMs for High-mountain Asia: A systematic, region-wide assessment of geodetic glacier mass balance and dynamics

    Science.gov (United States)

    Shean, D. E.; Arendt, A. A.; Osmanoglu, B.; Montesano, P.

    2017-12-01

    High Mountain Asia (HMA) constitutes the largest glacierized region outside of the Earth's polar regions. Although available observations are limited, long-term records indicate sustained regional glacier mass loss since 1850, with increased loss in recent decades. Recent satellite data (e.g., GRACE, ICESat-1) show spatially variable glacier mass balance, with significant mass loss in the Himalaya and Hindu Kush and slight mass gain in the Karakoram. We generated 4000 high-resolution digital elevation models (DEMs) from sub-meter commercial stereo imagery (DigitalGlobe WorldView/GeoEye) acquired over glaciers in High-mountain Asia from 2002-present (mostly 2013-present). We produced a regional 8-m DEM mosaic for 2015 and estimated 15-year geodetic mass balance for 40000 glaciers larger than 0.1 km2. We are combining with other regional DEM sources to systematically document the spatiotemporal evolution of glacier mass balance for the entire HMA region. We also generated monthly to interannual DEM and velocity time series for high-priority sites distributed across the region, with >15-20 DEMs available for some locations from 2010-present. These records document glacier dynamics, seasonal snow accumulation/redistribution, and processes that affect glacier mass balance (e.g., ice-cliff retreat, debris cover evolution). These efforts will provide basin-scale assessments of snow/ice melt runoff contributions for model cal/val and downstream water resources applications. We will continue processing all archived and newly available commercial stereo imagery for HMA, and will release all DEMs through the HiMAT DAAC.

  1. Precision Flow and Salinity Mass Balance Assessments Across the Merced-San Joaquin River Confluence Zone

    Science.gov (United States)

    Fisher, J. C.; Pai, H.; Amaya, S. V.; Butler, C.; Harmon, T. C.

    2008-12-01

    Net surface water-groundwater losses and gains may be estimated from flow gauges if they are adequately spaced such that flow differences are discernible. However, mapping of losses/gains on increasingly smaller scale river reaches is becoming important from the perspective of assessing non-point source pollution, ecological restoration efforts, and related issues. This work describes the deployment and testing of the tethered robotic system known as NIMS RD which can be used for precise determination of coupled flow and solute distributions and mass balances in complex flow regimes. The system is demonstrated at the confluence of the relatively high salinity San Joaquin River and its tributary, the relatively low salinity Merced River. Two upstream and one downstream transects are scanned repeatedly using a NIMS RD system. The resulting two-dimensional velocity and salinity distributions are integrated to provide estimates for flow and salt loads, which are then used to perform mass balances over the confluence zone. The resulting flow mass balance resulted in a best-estimate of 0.15 m3/s groundwater input over the confluence zone, which was reasonable in comparison to a previous investigation. Sensitivity analysis on the key flow adjustment needed to perform the mass balance indicated that changes ranging from a loss of 0.2 m3/s to a gain of 0.5 m3/s were possible. The quantitative nature of the salinity balance was compromised by the lack of NIMS RD data for the key transect at the optimal time for the calculation, and resulted in an unrealistically high estimate of salt input from groundwater. The precision of the NIMS RD results for a given transect at specific times points to the usefulness of this approach to obtain high resolution flow and pollutant loading estimates in complex flow regimes. The uncertainty of the results points to the need to perform the measurements under stationary conditions or synchronously using additional equipment.

  2. Antarctic and Greenland ice sheet mass balance products from satellite gravimetry

    Science.gov (United States)

    Horwath, Martin; Groh, Andreas; Horvath, Alexander; Forsberg, René; Meister, Rakia; Barletta, Valentina R.; Shepherd, Andrew

    2017-04-01

    Because of their important role in the Earth's climate system, ESA's Climate Change Initiative (CCI) has identified both the Antarctic Ice Sheet (AIS) and the Greenland Ice Sheet (GIS) as Essential Climate Variables (ECV). Since respondents of a user survey indicated that the ice sheet mass balance is one of the most important ECV data products needed to better understand climate change, the AIS_cci and the GIS_cci project provide Gravimetric Mass Balance (GMB) products based on satellite gravimetry data. The GMB products are derived from GRACE (Gravity Recovery and Climate Experiment) monthly solutions of release ITSG-Grace2016 produced at TU Graz. GMB basin products (i.e. time series of monthly mass changes for the entire ice sheets and selected drainage basins) and GMB gridded products (e.g. mass balance estimates with a formal resolution of about 50km, covering the entire ice sheets) are generated for the period from 2002 until present. The first GMB product was released in mid 2016. Here we present an extended and updated version of the ESA CCI GMB products, which are freely available through data portals hosted by the projects (https://data1.geo.tu-dresden.de/ais_gmb, http://products.esa-icesheets-cci.org/products/downloadlist/GMB). Since the initial product release, the applied processing strategies have been improved in order to further reduce GRACE errors and to enhance the separation of signals super-imposed to the ice mass changes. While a regional integration approach is used by the AIS_cci project, the GMB products of the GIS_cci project are derived using a point mass inversion. The differences between both approaches are investigated through the example of the GIS, where an alternative GMB product was generated using the regional integration approach implemented by the AIS_cci. Finally, we present the latest mass balance estimates for both ice sheets as well as their corresponding contributions to global sea level rise.

  3. A semi-automated approach to derive elevation time-series and calculate glacier mass balance from historical aerial imagery

    Science.gov (United States)

    Whorton, E.; Headman, A.; Shean, D. E.; McCann, E.

    2017-12-01

    Understanding the implications of glacier recession on water resources in the western U.S. requires quantifying glacier mass change across large regions over several decades. Very few glaciers in North America have long-term continuous field measurements of glacier mass balance. However, systematic aerial photography campaigns began in 1957 on many glaciers in the western U.S. and Alaska. These historical, vertical aerial stereo-photographs documenting glacier evolution have recently become publically available. Digital elevation models (DEM) of the transient glacier surface preserved in each imagery timestamp can be derived, then differenced to calculate glacier volume and mass change to improve regional geodetic solutions of glacier mass balance. In order to batch process these data, we use Python-based algorithms and Agisoft Photoscan structure from motion (SfM) photogrammetry software to semi-automate DEM creation, and orthorectify and co-register historical aerial imagery in a high-performance computing environment. Scanned photographs are rotated to reduce scaling issues, cropped to the same size to remove fiducials, and batch histogram equalization is applied to improve image quality and aid pixel-matching algorithms using the Python library OpenCV. Processed photographs are then passed to Photoscan through the Photoscan Python library to create DEMs and orthoimagery. To extend the period of record, the elevation products are co-registered to each other, airborne LiDAR data, and DEMs derived from sub-meter commercial satellite imagery. With the exception of the placement of ground control points, the process is entirely automated with Python. Current research is focused on: one, applying these algorithms to create geodetic mass balance time series for the 90 photographed glaciers in Washington State and two, evaluating the minimal amount of positional information required in Photoscan to prevent distortion effects that cannot be addressed during co

  4. Predicting unsaturated zone nitrogen mass balances in agricultural settings of the United States

    Science.gov (United States)

    Nolan, Bernard T.; Puckett, Larry J.; Ma, Liwang; Green, Christopher T.; Bayless, E. Randall; Malone, Robert W.

    2009-01-01

    Unsaturated zone N fate and transport were evaluated at four sites to identify the predominant pathways of N cycling: an almond [Prunus dulcis (Mill.) D.A. Webb] orchard and cornfield (Zea mays L.) in the lower Merced River study basin, California; and corn–soybean [Glycine max (L.) Merr.] rotations in study basins at Maple Creek, Nebraska, and at Morgan Creek, Maryland. We used inverse modeling with a new version of the Root Zone Water Quality Model (RZWQM2) to estimate soil hydraulic and nitrogen transformation parameters throughout the unsaturated zone; previous versions were limited to 3-m depth and relied on manual calibration. The overall goal of the modeling was to derive unsaturated zone N mass balances for the four sites. RZWQM2 showed promise for deeper simulation profiles. Relative root mean square error (RRMSE) values for predicted and observed nitrate concentrations in lysimeters were 0.40 and 0.52 for California (6.5 m depth) and Nebraska (10 m), respectively, and index of agreement (d) values were 0.60 and 0.71 (d varies between 0 and 1, with higher values indicating better agreement). For the shallow simulation profile (1 m) in Maryland, RRMSE and d for nitrate were 0.22 and 0.86, respectively. Except for Nebraska, predictions of average nitrate concentration at the bottom of the simulation profile agreed reasonably well with measured concentrations in monitoring wells. The largest additions of N were predicted to come from inorganic fertilizer (153–195 kg N ha−1 yr−1 in California) and N fixation (99 and 131 kg N ha−1 yr−1 in Maryland and Nebraska, respectively). Predicted N losses occurred primarily through plant uptake (144–237 kg N ha−1 yr−1) and deep seepage out of the profile (56–102 kg N ha−1 yr−1). Large reservoirs of organic N (up to 17,500 kg N ha−1 m−1 at Nebraska) were predicted to reside in the unsaturated zone, which has implications for potential future transfer of nitrate to groundwater.

  5. Response of glacier mass balance to regional warming, deduced by remote sensing on three glaciers in S-Iceland

    Science.gov (United States)

    Gudmundsson, S.; Björnsson, H.; Magnússon, E.; Berthier, E.; Pálsson, F.; Gudmundsson, M. T.; Dall, J.

    2009-04-01

    We assess the mass balance changes of three ice caps in South Iceland, for two periods, 1980 to 1998 and 1998 to 2004, by comparing digital elevation models (DEMs) covering the entire glaciers; Eyjafjallajökull (81 km2), Tindfjallajökull (15 km2) and Torfajökull (14 km2). The DEMs were compiled by i) using aerial photographs taken between 1979 to 1984 by the American Defense Map Agency (DMA) and the Icelandic Geodetic Survey, ii) using airborne EMISAR radar images obtained in 1998 by the Electromagnetic system (EMI) of the Technical University of Denmark, and iii) using two image pairs from the SPOT5 high resolution stereoscopic (HRS) instrument from 2004. The ice-free part of the EMISAR-DEM (5x5 m spatial resolution with accuracy

  6. Bio-Chemicals Derived from Waste: Building on the Concept of a Bio-Refinery

    International Nuclear Information System (INIS)

    Habib, M.; Habib, U.; Khan, A.U.; Rehman, Z.U.; Zeb, A.; Moeed, A.; Pasha, M.K.; Memon, A.R.

    2013-01-01

    The work presented here has looked into the thermal-conversion of wheat and barley spent grains (SG). Wheat fermentation was carried in the laboratory to get a mashed product while barley grain residues were sourced from a local brewing company. Pyrolysis carried at 460, 520 and 540 Degree C at ambient conditions of pressure in a bench scale fluidized bed reactor resulted in producing bio-oil, charcoal and non-condensable gases. These products were characterized by using the Gas Chromatography Mass Spectrometry (GC-MS), Differential Thermo-glavemetric Analysis (DTG), Elemental Analyzer (E.A) and a Bomb Calorimeter. The final pyrolysis product analysis revealed that the bio-oil production yields and Higher Heating Value (HHV) largely depended on the pyrolysis temperature and the sample type. In comparison with original raw grain samples, the analysis of thermally treated (pyrolysis) spent grains revealed the presence of high carbon and low oxygen contents. Results gathered in this work have shown that high bio-crude-oil production yields can be obtained at 520 Degree C (53 and 37wt percentage bio-oil from wheat and barley SG). Pyrolysis of wheat and barley SG resulted in giving a Higher Heating Value (HHV) of 21.80 and 21.86 MJ/kg at 540 and 460 Degree C, which is considerably more in comparison to their virgin counterparts. This suggested route thus has a potential for further up-gradation of waste bio-mass for use as an intermediate fuel or as a raw material source for producing other bio-chemicals. (author)

  7. Bio-Chemicals Derived from Waste: Building on the Concept of a Bio-Refinery

    Directory of Open Access Journals (Sweden)

    Muddasar Habib

    2013-12-01

    Full Text Available The work presented here has looked into the thermal-conversion of wheat and barley spent grains (SG. Wheat fermentation was carried in the laboratory to get a mashed product while barley grain residues were sourced from a local brewing company. Pyrolysis carried at 460, 520 and 540 oC at ambient conditions of pressure in a bench scale fluidized bed reactor resulted in producing bio-oil, charcoal and non-condensable gases. These products were characterized by using the Gas Chromatography Mass Spectrometry (GC-MS, Differential Thermo-glavemetric Analysis (DTG, Elemental Analyzer (E.A and a Bomb Calorimeter. The final pyrolysis product analysis revealed that the bio-oil production yields and Higher Heating Value (HHV largely depended on the pyrolysis temperature and the sample type. In comparison with original raw grain samples, the analysis of thermally treated (pyrolysis spent grains revealed the presence of high carbon and low oxygen contents. Results gathered in this work have shown that high bio-crude-oil production yields can be obtained at 520 oC (53 and 37wt% bio-oil from wheat and barley SG. Pyrolysis of wheat and barley SG resulted in giving a Higher Heating Value (HHV of 21.80 and 21.86 MJ/kg at 540 and 460oC, which is considerably more in comparison to their virgin counterparts. This suggested route thus has a potential for further up-gradation of waste bio-mass for use as an intermediate fuel or as a raw material source for producing other bio-chemicals.

  8. Soil Physico-Bio-Chemical Properties under Poplar + Indian Mustard Inter Cropping System

    Directory of Open Access Journals (Sweden)

    Tara Bahadur Ghimire

    2015-12-01

    Full Text Available A field experiment was conducted during the winter seasons of 2008-10 at Agroforestry Research Centre, Pantnagar, India with aim to examine the effect of different levels of recommended Nitrogen (N: Phosphorus (P: Potassium (K (NPK on soil physico-bio-chemical properties under varying poplar tree densities with mustard introcropping. Lower soil bulk density was recorded under 1000 trees/ha density compared to sole crop in both the year. Soil bulk density (BD decreased underneath trees. However, soil pH, available N and K were not influenced by tree density in both the years. Electrical conductivity (EC and soil organic carbon (SOC increased underneath trees of either tree density compared to sole crop in both the years. Significantly (P<0.05 higher available P was recorded under 1000 trees/ha density compared to 250 and 500 trees/ha densities including sole crop in 2008-09. Similarly, soil microbial biomass carbon (SMBC increased with increasing the tree density and significantly (P<0.01 higher value was recorded under 1000 trees/ha density compared to sole crop and sparse density both the years except 2009-10, where 500 and 1000 trees/ha densities remain statistically at par. On the other hand, dehydrogenase activity (DA was maximum under 500 trees/ha density compared to sole crop and 1000 trees/ha density in both the years. Among the fertility levels, the maximum SOC and available N were recorded with 75% compared to 50, 100 and 125% of recommended NPK in 2008-09, except available N with 100% of recommended NPK. But, available P was more with 100% of recommended NPK in 2008-09. Similarly, maximum SMBC were recorded with 75 % compared to higher doses of recommended NPK in both the years. Similarly, BD, EC, SOC, available N, P and K were recorded maximum and soil pH minimum in 0-15 cm soil layers compared deeper layers.

  9. A range correction for ICESat and its potential impact on ice-sheet mass balance studies

    Science.gov (United States)

    Borsa, A. A.; Moholdt, G.; Fricker, H. A.; Brunt, K. M.

    2014-03-01

    We report on a previously undocumented range error in NASA's Ice, Cloud and land Elevation Satellite (ICESat) that degrades elevation precision and introduces a small but significant elevation trend over the ICESat mission period. This range error (the Gaussian-Centroid or "G-C" offset) varies on a shot-to-shot basis and exhibits increasing scatter when laser transmit energies fall below 20 mJ. Although the G-C offset is uncorrelated over periods ≤ 1 day, it evolves over the life of each of ICESat's three lasers in a series of ramps and jumps that give rise to spurious elevation trends of -0.92 to -1.90 cm yr-1, depending on the time period considered. Using ICESat data over the Ross and Filchner-Ronne ice shelves we show that (1) the G-C offset introduces significant biases in ice-shelf mass balance estimates, and (2) the mass balance bias can vary between regions because of different temporal samplings of ICESat. We can reproduce the effect of the G-C offset over these two ice shelves by fitting trends to sample-weighted mean G-C offsets for each campaign, suggesting that it may not be necessary to fully repeat earlier ICESat studies to determine the impact of the G-C offset on ice-sheet mass balance estimates.

  10. A range correction for ICESat and its potential impact on ice sheet mass balance studies

    Science.gov (United States)

    Borsa, A. A.; Moholdt, G.; Fricker, H. A.; Brunt, K. M.

    2013-08-01

    We report on a range error in NASA's Ice, Cloud and land Elevation Satellite (ICESat) that degrades elevation precision and introduces a small but significant elevation trend over the ICESat mission period. This range error (the Gaussian-Centroid or "G-C" offset) varies on a shot-to-shot basis and increases in magnitude as laser transmit energies decline. Although the G-C offset is uncorrelated over periods ≤1 day, it evolves over the life of each of ICESat's three lasers in a series of ramps and jumps that give rise to spurious elevation trends of 0.92 to 1.90 cm yr-1, depending on the time period considered. Using data over the Ross and Filchner-Ronne ice shelves we show that (1) the G-C offset introduces significant biases in ice-shelf mass balance estimates, and (2) the mass balance bias can vary between regions because of different temporal sampling of ICESat. We can accurately reproduce the impact of the G-C offset on these two ice shelves by fitting trends to sample-weighted global mean G-C offsets for each campaign, suggesting that it may not be necessary to fully repeat earlier ICESat studies to determine the impact of the G-C offset on ice sheet mass balance estimates.

  11. Morphometric Controls on Glacier Mass Balance of the Puruogangri Ice Field, Central Tibetan Plateau

    Directory of Open Access Journals (Sweden)

    Lin Liu

    2016-11-01

    Full Text Available Evaluating the impacts of climatic changes and morphometric features on glacier mass balance is crucial to providing insight into glacier changes and their effects on regional water resources and ecosystems. Here, we presented an evaluation of morphometric effects on the glacier mass balances of the Puruogangri ice field (PIF on the Tibetan Plateau. A clear spatial variability of glacier mass balances, ranging from −0.035 to +0.019 m·w.e.·year−1, was estimated by comparing the TanDEM-X DEM (2012 with the SRTM-X DEM (2000. In general, the observed glacier mass changes were consistent with our fieldwork investigations. Furthermore, by applying the method of linear regression analysis, we found that the mass changes of individual glaciers on the PIF were mainly dominated by the mean altitude (R = 0.84, p < 0.001, however, they were statistically independent of glacier size, aspect, and surface velocity. At a local scale (grid size of 10 × 10 pixels, apart from the factor of altitude, surface velocity was correlated with glacier mass change.

  12. Hybrid inventory, gravimetry and altimetry (HIGA) mass balance product for Greenland and the Canadian Arctic

    DEFF Research Database (Denmark)

    Colgan, W.; Abdalati, W.; Citterio, M.

    2015-01-01

    We present a novel inversion algorithm that generates a mass balance field that is simultaneously consistent with independent observations of glacier inventory derived from optical imagery, cryosphere-attributed mass trends derived from satellite gravimetry, and ice surface elevation trends derived...... from airborne and satellite altimetry. We use this algorithm to assess mass balance across Greenland and the Canadian Arctic over the Sep-2003 to Oct-2009 period at 26 km resolution. We evaluate local algorithm-inferred mass balance against forty in situ point observations. This evaluation yields...... an RMSE of 0.15 mWE/a, and highlights a paucity of in situ observations from regions of high dynamic mass loss and peripheral glaciers. We assess mass losses of 212 ± 67 Gt/a to the Greenland ice sheet proper, 38 ± 11 Gt/a to peripheral glaciers in Greenland, and 42 ± 11 Gt/a to glaciers in the Canadian...

  13. A Range Correction for Icesat and Its Potential Impact on Ice-sheet Mass Balance Studies

    Science.gov (United States)

    Borsa, A. A.; Moholdt, G.; Fricker, H. A.; Brunt, Kelly M.

    2014-01-01

    We report on a previously undocumented range error in NASA's Ice, Cloud and land Elevation Satellite (ICESat) that degrades elevation precision and introduces a small but significant elevation trend over the ICESat mission period. This range error (the Gaussian-Centroid or 'G-C'offset) varies on a shot-to-shot basis and exhibits increasing scatter when laser transmit energies fall below 20 mJ. Although the G-C offset is uncorrelated over periods less than1 day, it evolves over the life of each of ICESat's three lasers in a series of ramps and jumps that give rise to spurious elevation trends of -0.92 to -1.90 cm yr(exp -1), depending on the time period considered. Using ICESat data over the Ross and Filchner-Ronne ice shelves we show that (1) the G-C offset introduces significant biases in ice-shelf mass balance estimates, and (2) the mass balance bias can vary between regions because of different temporal samplings of ICESat.We can reproduce the effect of the G-C offset over these two ice shelves by fitting trends to sample-weighted mean G-C offsets for each campaign, suggesting that it may not be necessary to fully repeat earlier ICESat studies to determine the impact of the G-C offset on ice-sheet mass balance estimates.

  14. Mass Balance of Perfluorinated Alkyl Acids in a Pristine Boreal Catchment.

    Science.gov (United States)

    Filipovic, Marko; Laudon, Hjalmar; McLachlan, Michael S; Berger, Urs

    2015-10-20

    Mass balances of ten individual perfluorinated alkyl acids (PFAAs) in two nested pristine catchments in Northern Sweden with different sizes and hydrological functions were assembled for 2011-2012. Concentrations of PFAAs in rain and snowmelt, as well as in streamwater at the outlet of the two watersheds were measured and used to calculate PFAA atmospheric inputs to and riverine outputs from the catchments. The results generally showed a great excess of PFAA inputs for both catchments over the whole study year. However, during the spring flood period, the inputs and outputs were within a factor of 2 for several PFAAs and the streamwater showed PFAA patterns resembling the patterns in rain (as opposed to snowmelt), suggesting that snowmelt water infiltrating the ground had displaced water from the previous summer. Comparison of PFAA mass balances between the two catchments further suggested that atmospheric inputs of short-chain (replacement) perfluoroalkyl carboxylic acids had increased in the years before sampling, while inputs of the legacy perfluorooctane sulfonic acid had decreased. Overall, the mass balances indicate that a considerable portion of the PFAAs deposited from the atmosphere are stored in soil and may be released to surface and marine water environments in the future.

  15. Gulkana Glacier, Alaska-Mass balance, meteorology, and water measurements, 1997-2001

    Science.gov (United States)

    March, Rod S.; O'Neel, Shad

    2011-01-01

    The measured winter snow, maximum winter snow, net, and annual balances for 1997-2001 in the Gulkana Glacier basin are determined at specific points and over the entire glacier area using the meteorological, hydrological, and glaciological data. We provide descriptions of glacier geometry to aid in estimation of conventional and reference surface mass balances and descriptions of ice motion to aid in the understanding of the glacier's response to its changing geometry. These data provide annual estimates for area altitude distribution, equilibrium line altitude, and accumulation area ratio during the study interval. New determinations of historical area altitude distributions are given for 1900 and annually from 1966 to 2001. As original weather instrumentation is nearing the end of its deployment lifespan, we provide new estimates of overlap comparisons and precipitation catch efficiency. During 1997-2001, Gulkana Glacier showed a continued and accelerated negative mass balance trend, especially below the equilibrium line altitude where thinning was pronounced. Ice motion also slowed, which combined with the negative mass balance, resulted in glacier retreat under a warming climate. Average annual runoff augmentation by glacier shrinkage for 1997-2001 was 25 percent compared to the previous average of 13 percent, in accordance with the measured glacier volume reductions.

  16. The changing impact of snow conditions and refreezing on the mass balance of an idealized Svalbard glacier

    Directory of Open Access Journals (Sweden)

    Ward Van Pelt

    2016-11-01

    Full Text Available Glacier surface melt and runoff depend strongly on seasonal and perennial snow (firn conditions. Not only does the presence of snow and firn directly affect melt rates by reflecting solar radiation, it may also act as a buffer against mass loss by storing melt water in refrozen or liquid form. In Svalbard, ongoing and projected amplified climate change with respect to the global mean change has severe implications for the state of snow and firn and its impact on glacier mass loss. Model experiments with a coupled surface energy balance - firn model were done to investigate the surface mass balance and the changing role of snow and firn conditions for an idealized Svalbard glacier. A climate forcing for the past, present and future (1984-2104 is constructed, based on observational data from Svalbard Airport and a seasonally dependent projection scenario. Results illustrate ongoing and future firn degradation in response to an elevational retreat of the equilibrium line altitude (ELA of 31 m decade−1. The temperate firn zone is found to retreat and expand, while cold ice in the ablation zone warms considerably. In response to pronounced winter warming and an associated increase in winter rainfall, the current prevalence of refreezing during the melt season gradually shifts to the winter season in a future climate. Sensitivity tests reveal that in a present and future climate the density and thermodynamic structure of Svalbard glaciers are heavily influenced by refreezing. Refreezing acts as a net buffer against mass loss. However, the net mass balance change after refreezing is substantially smaller than the amount of refreezing itself, which can be ascribed to melt-enhancing effects after refreezing, which partly offset the primary mass-retaining effect of refreezing.

  17. Properties of the surface snow in Princess Elizabeth Land, East Antarctica - climate and non-climate dependent variability of the surface mass balance and stable water isotopic composition

    Science.gov (United States)

    Vladimirova, D.; Ekaykin, A.; Lipenkov, V.; Popov, S. V.; Petit, J. R.; Masson-Delmotte, V.

    2017-12-01

    Glaciological and meteorological observations conducted during the past four decades in Princess Elizabeth Land, East Antarctica, are compiled. The database is used to investigate spatial patterns of surface snow isotopic composition and surface mass balance, including detailed information near subglacial lake Vostok. We show diverse relationships between snow isotopic composition and surface temperature. In the most inland part (elevation 3200-3400 m a.s.l.), surface snow isotopic composition varies independently from surface temperature, and is closely related to the distance to the open water source (with a slope of 0.98±0.17 ‰ per 100 km). Surface mass balance values are higher along the ice sheet slope, and relatively evenly distributed inland. The minimum values of snow isotopic composition and surface mass balance are identified in an area XX km southwestward from Vostok station. The spatial distribution of deuterium excess delineates regions influenced by the Indian Ocean and Pacific Ocean air masses, with Vostok area being situated close to their boundary. Anomalously high deuterium excess values are observed near Dome A, suggesting high kinetic fractionation for its moisture source, or specifically high post-deposition artifacts. The dataset is available for further studies such as the assessment of skills of general circulation or regional atmospheric models, and the search for the oldest ice.

  18. Mechanism and rate of denitrification in an agricultural watershed: Electron and mass balance along groundwater flow paths

    Science.gov (United States)

    Tesoriero, Anthony J.; Liebscher, Hugh; Cox, Stephen E.

    2000-01-01

    The rate and mechanism of nitrate removal along and between groundwater flow paths were investigated using a series of well nests screened in an unconfined sand and gravel aquifer. Intensive agricultural activity in this area has resulted in nitrate concentrations in groundwater often exceeding drinking water standards. Both the extent and rate of denitrification varied depending on the groundwater flow path. While little or no denitrification occurred in much of the upland portions of the aquifer, a gradual redox gradient is observed as aerobic upland groundwater moves deeper in the aquifer. In contrast, a sharp shallow redox gradient is observed adjacent to a third‐order stream as aerobic groundwater enters reduced sediments. An essentially complete loss of nitrate concurrent with increases in excess N2 provide evidence that denitrification occurs as groundwater enters this zone. Electron and mass balance calculations suggest that iron sulfide (e.g., pyrite) oxidation is the primary source of electrons for denitrification. Denitrification rate estimates were based on mass balance calculations using nitrate and excess N2 coupled with groundwater travel times. Travel times were determined using a groundwater flow model and were constrained by chlorofluorocarbon‐based age dates. Denitrification rates were found to vary considerably between the two areas where denitrification occurs. Denitrification rates in the deep, upland portions of the aquifer were found to range from from 1.0 to 2.7 mM of N per year. Potential denitrification rates in groundwater adjacent to the stream may be much faster, with rates up to 140 mM per year based on an in situ experiment conducted in this zone.

  19. Atmospheric river impacts on Greenland Ice Sheet surface melt and mass balance

    Science.gov (United States)

    Mattingly, K.; Mote, T. L.

    2017-12-01

    Mass loss from the Greenland Ice Sheet (GrIS) has accelerated during the early part of the 21st Century. Several episodes of widespread GrIS melt in recent years have coincided with intense poleward moisture transport by atmospheric rivers (ARs), suggesting that variability in the frequency and intensity of these events may be an important driver of the surface mass balance (SMB) of the GrIS. ARs may contribute to GrIS surface melt through the greenhouse effect of water vapor, the radiative effects of clouds, condensational latent heating within poleward-advected air masses, and the energy provided by liquid precipitation. However, ARs may also provide significant positive contributions to GrIS SMB through enhanced snow accumulation. Prior research on the role of ARs in Arctic climate has consisted of case studies of ARs associated with major GrIS melt events or examined the effects of poleward moisture flux on Arctic sea ice. In this study, a long-term (1979-2016) record of intense moisture transport events affecting Greenland is compiled using a conventional AR identification algorithm as well as a self-organizing map (SOM) classification applied to integrated water vapor transport (IVT) data from several atmospheric reanalysis datasets. An analysis of AR effects on GrIS melt and SMB is then performed with GrIS surface melt data from passive microwave satellite observations and the Modèle Atmosphérique Régional (MAR) regional climate model. Results show that meltwater production is above normal during and after AR impact days throughout the GrIS during all seasons, with surface melt enhanced most by strong (> 85th percentile IVT) and extreme (> 95th percentile IVT) ARs. This relationship holds at the seasonal scale, as the total amount of water vapor transported to the GrIS by ARs is significantly greater during above-normal melt seasons. ARs exert a more complex influence on SMB. Normal (< 85th percentile IVT) ARs generally do not have a substantial impact on

  20. Observationally constrained surface mass balance of Larsen C ice shelf, Antarctica

    Directory of Open Access Journals (Sweden)

    P. Kuipers Munneke

    2017-11-01

    Full Text Available The surface mass balance (SMB of the Larsen C ice shelf (LCIS, Antarctica, is poorly constrained due to a dearth of in situ observations. Combining several geophysical techniques, we reconstruct spatial and temporal patterns of SMB over the LCIS. Continuous time series of snow height (2.5–6 years at five locations allow for multi-year estimates of seasonal and annual SMB over the LCIS. There is high interannual variability in SMB as well as spatial variability: in the north, SMB is 0.40 ± 0.06 to 0.41 ± 0.04 m w.e. year−1, while farther south, SMB is up to 0.50 ± 0.05 m w.e. year−1. This difference between north and south is corroborated by winter snow accumulation derived from an airborne radar survey from 2009, which showed an average snow thickness of 0.34 m w.e. north of 66° S, and 0.40 m w.e. south of 68° S. Analysis of ground-penetrating radar from several field campaigns allows for a longer-term perspective of spatial variations in SMB: a particularly strong and coherent reflection horizon below 25–44 m of water-equivalent ice and firn is observed in radargrams collected across the shelf. We propose that this horizon was formed synchronously across the ice shelf. Combining snow height observations, ground and airborne radar, and SMB output from a regional climate model yields a gridded estimate of SMB over the LCIS. It confirms that SMB increases from north to south, overprinted by a gradient of increasing SMB to the west, modulated in the west by föhn-induced sublimation. Previous observations show a strong decrease in firn air content toward the west, which we attribute to spatial patterns of melt, refreezing, and densification rather than SMB.

  1. Assessment of Antarctic Ice-Sheet Mass Balance Estimates: 1992 - 2009

    Science.gov (United States)

    Zwally, H. Jay; Giovinetto, Mario B.

    2011-01-01

    Published mass balance estimates for the Antarctic Ice Sheet (AIS) lie between approximately +50 to -250 Gt/year for 1992 to 2009, which span a range equivalent to 15% of the annual mass input and 0.8 mm/year Sea Level Equivalent (SLE). Two estimates from radar-altimeter measurements of elevation change by European Remote-sensing Satellites (ERS) (+28 and -31 Gt/year) lie in the upper part, whereas estimates from the Input-minus-Output Method (IOM) and the Gravity Recovery and Climate Experiment (GRACE) lie in the lower part (-40 to -246 Gt/year). We compare the various estimates, discuss the methodology used, and critically assess the results. Although recent reports of large and accelerating rates of mass loss from GRACE=based studies cite agreement with IOM results, our evaluation does not support that conclusion. We find that the extrapolation used in the published IOM estimates for the 15 % of the periphery for which discharge velocities are not observed gives twice the rate of discharge per unit of associated ice-sheet area than the 85% faster-moving parts. Our calculations show that the published extrapolation overestimates the ice discharge by 282 Gt/yr compared to our assumption that the slower moving areas have 70% as much discharge per area as the faster moving parts. Also, published data on the time-series of discharge velocities and accumulation/precipitation do not support mass output increases or input decreases with time, respectively. Our modified IOM estimate, using the 70% discharge assumption and substituting input from a field-data compilation for input from an atmospheric model over 6% of area, gives a loss of only 13 Gt/year (versus 136 Gt/year) for the period around 2000. Two ERS-based estimates, our modified IOM, and a GRACE-based estimate for observations within 1992 to 2005 lie in a narrowed range of +27 to - 40 Gt/year, which is about 3% of the annual mass input and only 0.2 mm/year SLE. Our preferred estimate for 1992-2001 is - 47 Gt

  2. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  3. Optimal hydrograph separation using a recursive digital filter constrained by chemical mass balance, with application to selected Chesapeake Bay watersheds

    Science.gov (United States)

    Raffensperger, Jeff P.; Baker, Anna C.; Blomquist, Joel D.; Hopple, Jessica A.

    2017-06-26

    Quantitative estimates of base flow are necessary to address questions concerning the vulnerability and response of the Nation’s water supply to natural and human-induced change in environmental conditions. An objective of the U.S. Geological Survey National Water-Quality Assessment Project is to determine how hydrologic systems are affected by watershed characteristics, including land use, land cover, water use, climate, and natural characteristics (geology, soil type, and topography). An important component of any hydrologic system is base flow, generally described as the part of streamflow that is sustained between precipitation events, fed to stream channels by delayed (usually subsurface) pathways, and more specifically as the volumetric discharge of water, estimated at a measurement site or gage at the watershed scale, which represents groundwater that discharges directly or indirectly to stream reaches and is then routed to the measurement point.Hydrograph separation using a recursive digital filter was applied to 225 sites in the Chesapeake Bay watershed. The recursive digital filter was chosen for the following reasons: it is based in part on the assumption that groundwater acts as a linear reservoir, and so has a physical basis; it has only two adjustable parameters (alpha, obtained directly from recession analysis, and beta, the maximum value of the base-flow index that can be modeled by the filter), which can be determined objectively and with the same physical basis of groundwater reservoir linearity, or that can be optimized by applying a chemical-mass-balance constraint. Base-flow estimates from the recursive digital filter were compared with those from five other hydrograph-separation methods with respect to two metrics: the long-term average fraction of streamflow that is base flow, or base-flow index, and the fraction of days where streamflow is entirely base flow. There was generally good correlation between the methods, with some biased

  4. Overview of Ice-Sheet Mass Balance and Dynamics from ICESat Measurements

    Science.gov (United States)

    Zwally, H. Jay

    2010-01-01

    The primary purpose of the ICESat mission was to determine the present-day mass balance of the Greenland and Antarctic ice sheets, identify changes that may be occurring in the surface-mass flux and ice dynamics, and estimate their contributions to global sea-level rise. Although ICESat's three lasers were planned to make continuous measurements for 3 to 5 years, the mission was re-planned to operate in 33-day campaigns 2 to 3 times each year following failure of the first laser after 36 days. Seventeen campaigns were conducted with the last one in the Fall of 2009. Mass balance maps derived from measured ice-sheet elevation changes show that the mass loss from Greenland has increased significantly to about 170 Gt/yr for 2003 to 2007 from a state of near balance in the 1990's. Increased losses (189 Gt/yr) from melting and dynamic thinning are over seven times larger'than increased gains (25 gt/yr) from precipitation. Parts of the West Antarctic ice sheet and the Antarctic Peninsula are losing mass at an increasing rate, but other parts of West Antarctica and the East Antarctic ice sheet are gaining mass at an increasing rate. Increased losses of 35 Gt/yr in Pine Island, Thwaites-Smith, and Marie-Bryd.Coast are more than balanced by gains in base of Peninsula and ice stream C, D, & E systems. From the 1992-2002 to 2003-2007 period, the overall mass balance for Antarctica changed from a loss of about 60 Gt/yr to near balance or slightly positive.

  5. Evaporation and NARS Nitric Acid Mass Balance Summary: 2000--2005

    International Nuclear Information System (INIS)

    Kreutzberg, B.D.; Ames, R.L.; Hansel, K.M.

    2005-01-01

    A compilation of the historical nitric acid processing data for the evaporation and nitric acid recycle system (NARS) in TA-55 has provided general acid mass balance trends, as well as the location of missing information in both the evaporation system and NARS data logs. The data were accumulated during the calendar years 2000 to 2005. After making a number of processing assumptions, the empirical system information was used to create an interactive spreadsheet that predicts, with moderate accuracy, some of the various stream variables for the combined evaporation and acid recycle processes. Empirical data and interactive calculations were compared to an Aspen Plus(trademark) simulation of the process

  6. Glacier albedo decrease in the European Alps: potential causes and links with mass balances

    Science.gov (United States)

    Di Mauro, Biagio; Julitta, Tommaso; Colombo, Roberto

    2016-04-01

    Both mountain glaciers and polar ice sheets are losing mass all over the Earth. They are highly sensitive to climate variation, and the widespread reduction of glaciers has been ascribed to the atmospheric temperature increase. Beside this driver, also ice albedo plays a fundamental role in defining mass balance of glaciers. In fact, dark ice absorbs more energy causing faster glacier melting, and this can drive to more negative balances. Previous studies showed that the albedo of Himalayan glaciers and the Greenland Ice Sheet is decreasing with important rates. In this contribution, we tested the hypothesis that also glaciers in the European Alps are getting darker. We analyzed 16-year time series of MODIS (MODerate resolution Imaging Spectrometer) snow albedo from Terra (MOD13A1, 2000-2015) and Aqua (MYD13A1, 2002-2015) satellites. These data feature a spatial resolution of 500m and a daily temporal resolution. We evaluated the existence of a negative linear and nonlinear trend of the summer albedo values both at pixel and at glacier level. We also calculated the correlation between MODIS summer albedo and glacier mass balances (from the World Glaciological Monitoring Service, WGMS database), for all the glaciers with available mass balance during the considered period. In order to estimate the percentage of the summer albedo that can be explained by atmospheric temperature, we correlated MODIS albedo and monthly air temperature extracted from the ERA-Interim reanalysis dataset. Results show that decreasing trends exist with a strong spatial variability in the whole Alpine chain. In large glaciers, such as the Aletch (Swiss Alps), the trend varies significantly also within the glacier, showing that the trend is higher in the area across the accumulation and ablation zone. Over the 17 glaciers with mass balance available in the WGMS data set, 11 gave significant relationship with the MODIS summer albedo. Moreover, the comparison between ERA-Interim temperature

  7. Reconstructing the mass balance of Brewster Glacier, New Zealand, using MODIS-derived glacier-wide albedo

    Directory of Open Access Journals (Sweden)

    P. Sirguey

    2016-10-01

    Full Text Available In New Zealand, direct measurements of mass balance are sparse due to the inaccessibility of glaciers in the Southern Alps and the logistical difficulties associated with maintaining a mass balance record. In order to explore the benefit of remotely sensed imaging to monitor mass balance in the Southern Alps, this research assesses the relationship between measurements of glacier surface albedo derived from Moderate Resolution Imaging Spectroradiometer (MODIS and mass balance observations using the glaciological method on Brewster Glacier over the 2005–2013 period. We confirm that minimum glacier-wide albedo is a reliable predictor for annual mass balance in this maritime environment (R2 = 0.93. Furthermore, we show that regular monitoring of glacier-wide albedo enables a new metric of winter accumulation to be derived, namely the cumulative winter albedo, which is found to correlate strongly with winter mass balance (R2 = 0.88, thus enabling the reconstruction of separate winter and summer mass balance records. This allows the mass balance record for Brewster Glacier to be extended back to the start of MODIS observations in 2000 and to confirm that the annual balance of Brewster Glacier is largely controlled by summer balance (R2  =  92 %. An application of the extended record is proposed whereby the relationship between mass balance and the photographic record of the end-of-summer snowline altitude is assessed. This allowed the annual balance record of Brewster Glacier to be reconstructed over the period 1977–2013, thus providing the longest record of mass balance for a glacier in New Zealand. Over the 37-year period, our results show that Brewster Glacier gained a significant mass of up to 14.5 ± 2.7 m w.e. by 2007. This gain was offset by a marked shift toward negative balances after 2008, yielding a loss of 5.1 ± 1.2 m w.e., or 35 % of the gain accumulated over the previous 30 years. The good

  8. GLACIOCLIM-SAMBA: A Terre Adelie / Wilkes Land Antarctic surface mass balance observatory

    Science.gov (United States)

    Genthon, C.; Frezzotti, M.; Le Meur, E.; Magand, O.; Six, D.; Wagnon, P.

    2005-12-01

    While local measurements at hundreds of sites are now available (although sometimes questionable, e.g. Magand et al., this volume) to verify how large-scale models reproduce the spatial distribution of the surface mass balance (SMB) of Antarctica, few field observations yet make it possible to verify current intra- and inter-annual variability and trends of the SMB in the models, and to evaluate the processes that relate this variability with that of climate. It is a major aim of the GLACIOCLIM-SAMBA observatory (http://lgge.obs.ujf-grenoble.fr/~christo/glacioclim/samba/), initiated in 2004, to provide such observations in the Terre Adelie and Wilkes Land area. Recognizing that the largest absolute changes (and thus contribution to sea-level) of Antarctic SMB are expected where the current mean SMB is largest, that is in the coastal regions, SAMBA is largely focused on ice sheet margin. To sample spatial scales compatible with the scales resolved by models used to predict climate and SMB changes, a 150 km accumulation stakes line is being set up from the coast near the French Dumont d'Urville station, towards to Antarctic plateau in the general direction of the Italy/France Concordia station. Ground penetrating radar survey will provide snap-shot SMB interpolation along the stakes line. A blue ice stretch at the coast is being monitored by a 50-stake ablation network. Three 50-stakes networks are being set up near Concordia station to relate coastal and plateau SMB variability and change. An automatic weather station (AWS, including radiation) deployed at the coast, and the D-10, D-47 and DCII Antarctic Meteorological Research Center (http://amrc.ssec.wisc.edu/) AWSs, provide meteorological information to relate observed SMB and climate. Italian meteorology and radiation programs at Concordia, planned micrometeorology special campaigns at the margin, and precipitation monitoring at both sites, should help decipher the processes that relate SMB and climate

  9. Spatial Variability in Basal Mass Balance of the Roi Baudouin Ice Shelf, East Antarctica

    Science.gov (United States)

    Berger, Sophie; Drews, Reinhard; Helm, Veit; Sun, Sainan; Pattyn, Frank

    2017-04-01

    Ice-shelf buttressing is an important component controlling the dynamic mass loss of ice sheets. The basal mass balance (BMB, i.e. the sum of melting/refreezing beneath ice shelves), and spatio-temporal variations thereof, critically impact the ice-shelf buttressing strength. Therefore, it is important to pinpoint BMB area-wide from space which is challenging because many input parameters are typically not well resolved. Here, we present the BMB field of the Roi Baudouin Ice Shelf, Dronning Maud Land, East Antarctica at 10 m gridding, based on mass conservation in a Lagrangian framework using interferometric elevations and surface velocities along with atmospheric modelling. We apply the total variation differentiation to account for noisy input data, which circumnavigates spatial averaging with corresponding loss of spatial resolution. At the core of our analysis is a high-resolution surface elevation model from the TandDEM-X satellites (consisting out of 43 scenes), from which we derive the hydrostatic ice thickness in 2013 and 2014. This dataset clearly resolves small-scale features such as ice-shelf channels, resulting in a yearly-averaged BMB field revealing much detail. Our satellite-based BMB field shows good agreement with on-site measurements from phase-sensitive radar over a two-week time period, and we compare the hydrostatic thickness with measurements from ground-penetrating radar highlighting unresolved spatial variations of firn density. Our BMB field ranges from -14.8 to 8.6 m/yr, with an average of -0.8 m/yr. Highest melting is found close to the grounding line, where ice thickness changes are most prominent. As an example for the small-scale variability in the BMB field, we investigate a previously identified englacial lake at 30 m depth extending over an area of 0.7 by 1.3 km. Using the TanDEM-X DEMs and kinematic GNSS we find localized surface lowering of 5 to 10 m/yr which we tentatively attribute to a transient adaptation to hydrostatic

  10. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  11. Inter-comparison of ice sheet mass balance products from GRACE: ESA CCI Round Robin results

    DEFF Research Database (Denmark)

    Groth, A.; Horwath, M.; Horvath, A.

    Both the Antarctic Ice Sheet (AIS) and the Greenland Ice Sheet (GIS) have been identified as key parameters, so called Essential Climate Variables (ECV), in the climate system. Within the framework of the Climate Change Initiative (CCI) of the European Space Agency (ESA), reliable long-term satel......Both the Antarctic Ice Sheet (AIS) and the Greenland Ice Sheet (GIS) have been identified as key parameters, so called Essential Climate Variables (ECV), in the climate system. Within the framework of the Climate Change Initiative (CCI) of the European Space Agency (ESA), reliable long......-term satellite-based data products are generated for selected ECVs. Since ice sheet mass balance is an ECV parameter of highest interest, both the AIS_cci and the GIS_cci project will provide mass balance products based on satellite gravimetry data: (a) time series of monthly mass changes for individual drainage...... spatial resolution and complex error structures place particular demands on the applied processing strategy. To choose the most suitable algorithm which minimizes the impact of GRACE errors and signal leakage errors on GMB products, an open Round Robin experiment was set up. Participants were asked...

  12. A mass balance study on nitrification and deammonification in vertical flow constructed wetlands treating landfill leachate.

    Science.gov (United States)

    Sun, G; Austin, D

    2007-01-01

    A laboratory-scale, mass-balance study was carried out on the transformation of nitrogenous pollutants in four vertical flow wetland columns. Landfill leachate containing low organic matter, but a high concentration of ammoniacal-nitrogen, was treated under dissolved oxygen concentrations close to saturation. Influent total nitrogen (TN) comprised ammoniacal-nitrogen with less than 1% nitrate and nitrite, negligible organic nitrogen, and very low BOD. Nitrification occurred in three of the four columns. There was a substantial loss of total nitrogen (52%) in one column, whereas other columns exhibited zero to minor losses (Nitrogen loss under study conditions was unexpected. Two hypotheses are proposed to account for it: (1) either the loss of TN is attributed to nitrogen transformation into a form (provisionally termed alpha-nitrogen) that is undetectable by the analytical methods used; or (2) the loss is caused by microbial denitrification or deammonification. By elimination and stoichiometric mass balance calculations, completely autotrophic nitrogen-removal over nitrite (CANON) deammonification is confirmed as responsible for nitrogen loss in one column. This result reveals that CANON can be native to aerobic engineered wetland systems treating high ammonia, low organic content wastewater.

  13. Transfer of arsenic from poultry feed to poultry litter: A mass balance study.

    Science.gov (United States)

    Gupta, Sanjay K; Le, X Chris; Kachanosky, Gary; Zuidhof, Martin J; Siddique, Tariq

    2018-02-22

    Roxarsone (rox), an arsenic (As) containing organic compound, is a common feed additive used in poultry production. To determine if As present in rox is excreted into the poultry litter without any retention in chicken meat for safe human consumption, the transference of As from the feed to poultry excreta was assessed using two commercial chicken strains fed with and without dietary rox. The results revealed that both the strains had similar behaviour in growth (chicken weight; 2.17-2.25kg), feed consumption (282-300kgpen -1 initially containing 102 chicken) and poultry litter production (73-81kgpen -1 ) during the growth phase of 35days. Our mass balance calculations showed that chickens ingested 2669-2730mg As with the feed and excreted out 2362-2896mg As in poultry litter during the growth period of 28days when As containing feed was used, yielding As recovery between 86 and 108%. Though our complementary studies show that residual arsenic species in rox-fed chicken meat may have relevance to human exposure, insignificant retention of total As in the chicken meat substantiates our mass balance results. The results are important in evaluating the fate of feed additive used in poultry production and its potential environmental implications if As containing poultry litter is applied to soil for crop production. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Climate dependent contrast in surface mass balance in East Antarctica over the past 216 ka

    Science.gov (United States)

    Parrenin, Frédéric; Fujita, Shuji; Abe-Ouchi, Ayako; Kawamura, Kenji; Masson-Delmotte, Valérie; Motoyama, Hideaki; Saito, Fuyuki; Severi, Mirko; Stenni, Barbara; Uemura, Ryu; Wolff, Eric

    2017-04-01

    Documenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice-sheet contribution to global mean sea-level change. Here we reconstruct past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronization of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 a, this SMB ratio, denoted SMB EDC /SMB DF , varied between 0.7 and 1.1, being small during cold periods and large during warm periods. Our results therefore reveal larger amplitudes of changes in SMB at EDC compared with DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared with DF. Within the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 0.2 from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends.

  15. Changes in ice dynamics and mass balance of the Antarctic ice sheet.

    Science.gov (United States)

    Rignot, Eric

    2006-07-15

    The concept that the Antarctic ice sheet changes with eternal slowness has been challenged by recent observations from satellites. Pronounced regional warming in the Antarctic Peninsula triggered ice shelf collapse, which led to a 10-fold increase in glacier flow and rapid ice sheet retreat. This chain of events illustrated the vulnerability of ice shelves to climate warming and their buffering role on the mass balance of Antarctica. In West Antarctica, the Pine Island Bay sector is draining far more ice into the ocean than is stored upstream from snow accumulation. This sector could raise sea level by 1m and trigger widespread retreat of ice in West Antarctica. Pine Island Glacier accelerated 38% since 1975, and most of the speed up took place over the last decade. Its neighbour Thwaites Glacier is widening up and may double its width when its weakened eastern ice shelf breaks up. Widespread acceleration in this sector may be caused by glacier ungrounding from ice shelf melting by an ocean that has recently warmed by 0.3 degrees C. In contrast, glaciers buffered from oceanic change by large ice shelves have only small contributions to sea level. In East Antarctica, many glaciers are close to a state of mass balance, but sectors grounded well below sea level, such as Cook Ice Shelf, Ninnis/Mertz, Frost and Totten glaciers, are thinning and losing mass. Hence, East Antarctica is not immune to changes.

  16. Purity determination and uncertainty evaluation of folic acid by mass balance method.

    Science.gov (United States)

    Gong, Hui; Huang, Ting; Yang, Yi; Wang, Haifeng

    2012-11-15

    Folic acid is one of the most important nutrient substances for human beings, especially for the pregnant women and infants. Therefore the purity determination of folic acid is particularly important. The mass balance method was employed to determine the purity of folic acid, by using the measures of high performance liquid chromatography (HPLC), Karl Fischer titration and other conventional approach. The moisture quantification of folic acid was a major problem since it is a thermally unstable substance and it is apt to contain crystal water. Therefore, a novel improved Karl Fischer method was established for accurate determination of the water content in folic acid, whose repeatability (RSD=2.9%) was significantly better than that of the original direct injection method (RSD=12%). The purity of folic acid certified reference material (CRM) determined by mass balance method was 90.9% with an expanded uncertainty of 0.35%, and the content of water (the major impurity) was 8.5%, with an expanded uncertainty of 0.32%. Copyright © 2012 Elsevier B.V. All rights reserved.

  17. A metabolism perspective on alternative urban water servicing options using water mass balance.

    Science.gov (United States)

    Farooqui, Tauheed A; Renouf, Marguerite A; Kenway, Steven J

    2016-12-01

    Urban areas will need to pursue new water servicing options to ensure local supply security. Decisions about how best to employ them are not straightforward due to multiple considerations and the potential for problem shifting among them. We hypothesise that urban water metabolism evaluation based a water mass balance can help address this, and explore the utility of this perspective and the new insights it provides about water servicing options. Using a water mass balance evaluation framework, which considers direct urban water flows (both 'natural' hydrological and 'anthropogenic' flows), as well as water-related energy, we evaluated how the use of alternative water sources (stormwater/rainwater harvesting, wastewater/greywater recycling) at different scales influences the 'local water metabolism' of a case study urban development. New indicators were devised to represent the water-related 'resource efficiency' and 'hydrological performance' of the urban area. The new insights gained were the extent to which alternative water supplies influence the water efficiency and hydrological performance of the urban area, and the potential energy trade-offs. The novel contribution is the development of new indicators of urban water resource performance that bring together considerations of both the 'anthropogenic' and 'natural' water cycles, and the interactions between them. These are used for the first time to test alternative water servicing scenarios, and to provide a new perspective to complement broader sustainability assessments of urban water. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Dual-core mass-balance approach for evaluating mercury and 210Pb atmospheric fallout and focusing to lakes.

    Science.gov (United States)

    Van Metre, Peter C; Fuller, Christopher C

    2009-01-01

    Determining atmospheric deposition rates of mercury and other contaminants using lake sediment cores requires a quantitative understanding of sediment focusing. Here we present a novel approach that solves mass-balance equations fortwo cores algebraicallyto estimate contaminant contributions to sediment from direct atmospheric fallout and from watershed and in-lake focusing. The model is applied to excess 210Pb and Hg in coresfrom Hobbs Lake, a high-altitude lake in Wyoming. Model results for excess 210Pb are consistent with estimates of fallout and focusing factors computed using excess 210Pb burdens in lake cores and soil cores from the watershed and model results for Hg fallout are consistent with fallout estimated using the soil-core-based 210Pb focusing factors. The lake cores indicate small increases in mercury deposition beginning in the late 1800s and large increases after 1940, with the maximum at the tops of the cores of 16-20 microg/m2 x year. These results suggest that global Hg emissions and possibly regional emissions in the western United States are affecting the north-central Rocky Mountains. Hg fallout estimates are generally consistent with fallout reported from an ice core from the nearby Upper Fremont Glacier, but with several notable differences. The model might not work for lakes with complex geometries and multiple sediment inputs, but for lakes with simple geometries, like Hobbs, it can provide a quantitative approach for evaluating sediment focusing and estimating contaminant fallout.

  19. Survey on bio-chemical complex harmonized with global environment. 3; Kankyo chowagata seibutsu kagaku konbinato ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of bio-chemical complex harmonized with the global environment for the purpose of constructing the material production process harmonized with the environment by the process fusion between biological conversion and chemical reaction. Palm oil was taken up as renewable raw material plant resource. The process utilizing bio-chemical reaction advances at normal temperature and pressure and is high in reaction specificity and selectivity. This is a recycling, circulation and environmental harmony type production technology which brings high yield, energy conservation, resource conservation, and low environmental loads. Waste water treatment and production of useful substances from sludge were thought as elementary technology. A possibility was studied of enzyme production by culturing solid waste, and the enzyme was applied to the hydrolysis process. The paper indicated trace components in the palm oil and the extraction method and proposed the production process of new derivatives for adding value to hydrolysate. A study was also made of the overall process flow which integrated these new processes and the material balance. The comprehensive evaluation of this new process was made from the aspect of the product structure, the market, construction cost, economical efficiency, and the environment. 133 refs., 65 figs., 56 tabs.

  20. 21st century projections of surface mass balance changes for major drainage systems of the Greenland ice sheet

    International Nuclear Information System (INIS)

    Tedesco, M; Fettweis, X

    2012-01-01

    Outputs from the regional climate model Modèle Atmosphérique Régionale at a spatial resolution of 25 km are used to study 21st century projected surface mass balance (SMB) over six major drainage basins of the Greenland ice sheet (GrIS). The regional model is forced with the outputs of three different Earth System Models (CanESM2, NorESM1 and MIROC5) obtained when considering two greenhouse gas future scenarios with levels of CO 2 equivalent of, respectively, 850 and >1370 ppm by 2100. Results indicate that the increase in runoff due to warming will exceed the increased precipitation deriving from the increase in evaporation for all basins, with the amount of net loss of mass at the surface varying spatially. Basins along the southwest and north coast are projected to have the highest sensitivity of SMB to increasing temperatures. For these basins, the global temperature anomaly corresponding to a decrease of the SMB below the 1980–99 average (when the ice sheet was near the equilibrium) ranges between +0.60 and +2.16 °C. For the basins along the northwest and northeast, these values range between +1.50 and +3.40 °C. Our results are conservative as they do not account for ice dynamics and changes in the ice sheet topography. (letter)

  1. Mass balance of the Greenland ice sheet (2003–2008 from ICESat data – the impact of interpolation, sampling and firn density

    Directory of Open Access Journals (Sweden)

    L. S. Sørensen

    2011-03-01

    Full Text Available ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique dataset for monitoring the changes of the cryosphere. Here, we present a novel method for determining the mass balance of the Greenland ice sheet, derived from ICESat altimetry data.

    Three different methods for deriving elevation changes from the ICESat altimetry dataset are used. This multi-method approach provides a method to assess the complexity of deriving elevation changes from this dataset.

    The altimetry alone can not provide an estimate of the mass balance of the Greenland ice sheet. Firn dynamics and surface densities are important factors that contribute to the mass change derived from remote-sensing altimetry. The volume change derived from ICESat data is corrected for changes in firn compaction over the observation period, vertical bedrock movement and an intercampaign elevation bias in the ICESat data. Subsequently, the corrected volume change is converted into mass change by the application of a simple surface density model, in which some of the ice dynamics are accounted for. The firn compaction and density models are driven by the HIRHAM5 regional climate model, forced by the ERA-Interim re-analysis product, at the lateral boundaries.

    We find annual mass loss estimates of the Greenland ice sheet in the range of 191 ± 23 Gt yr−1 to 240 ± 28 Gt yr−1 for the period October 2003 to March 2008. These results are in good agreement with several other studies of the Greenland ice sheet mass balance, based on different remote-sensing techniques.

  2. Mass balance approaches for estimating the intestinal absorption and metabolism of peptides and analogues: theoretical development and applications

    Science.gov (United States)

    Sinko, P. J.; Leesman, G. D.; Amidon, G. L.

    1993-01-01

    A theoretical analysis for estimating the extent of intestinal peptide and peptide analogue absorption was developed on the basis of a mass balance approach that incorporates convection, permeability, and reaction. The macroscopic mass balance analysis (MMBA) was extended to include chemical and enzymatic degradation. A microscopic mass balance analysis, a numerical approach, was also developed and the results compared to the MMBA. The mass balance equations for the fraction of a drug absorbed and reacted in the tube were derived from the general steady state mass balance in a tube: [formula: see text] where M is mass, z is the length of the tube, R is the tube radius, Pw is the intestinal wall permeability, kr is the reaction rate constant, C is the concentration of drug in the volume element over which the mass balance is taken, VL is the volume of the tube, and vz is the axial velocity of drug. The theory was first applied to the oral absorption of two tripeptide analogues, cefaclor (CCL) and cefatrizine (CZN), which degrade and dimerize in the intestine. Simulations using the mass balance equations, the experimental absorption parameters, and the literature stability rate constants yielded a mean estimated extent of CCL (250-mg dose) and CZN (1000-mg dose) absorption of 89 and 51%, respectively, which was similar to the mean extent of absorption reported in humans (90 and 50%). It was proposed previously that 15% of the CCL dose spontaneously degraded systematically; however, our simulations suggest that significant CCL degradation occurs (8 to 17%) presystemically in the intestinal lumen.(ABSTRACT TRUNCATED AT 250 WORDS).

  3. Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

    Science.gov (United States)

    Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

    2018-01-01

    Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5) are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

  4. Linking glacier annual mass balance and glacier albedo retrieved from MODIS data

    Directory of Open Access Journals (Sweden)

    M. Dumont

    2012-12-01

    Full Text Available Albedo is one of the variables controlling the mass balance of temperate glaciers. Multispectral imagers, such as MODerate Imaging Spectroradiometer (MODIS on board the TERRA and AQUA satellites, provide a means to monitor glacier surface albedo. In this study, different methods to retrieve broadband glacier surface albedo from MODIS data are compared. The effect of multiple reflections due to the rugged topography and of the anisotropic reflection of snow and ice are particularly investigated. The methods are tested on the Saint Sorlin Glacier (Grandes Rousses area, French Alps. The accuracy of the retrieved albedo is estimated using both field measurements, at two automatic weather stations located on the glacier, and albedo values derived from terrestrial photographs. For summers 2008 and 2009, the root mean square deviation (RMSD between field measurements and the broadband albedo retrieved from MODIS data at 250 m spatial resolution was found to be 0.052 or about 10% relative error. The RMSD estimated for the MOD10 daily albedo product is about three times higher. One decade (2000–2009 of MODIS data were then processed to create a time series of albedo maps of Saint Sorlin Glacier during the ablation season. The annual mass balance of Saint Sorlin Glacier was compared with the minimum albedo value (average over the whole glacier surface observed with MODIS during the ablation season. A strong linear correlation exists between the two variables. Furthermore, the date when the average albedo of the whole glacier reaches a minimum closely corresponds to the period when the snow line is located at its highest elevation, thus when the snow line is a good indicator of the glacier equilibrium line. This indicates that this strong correlation results from the fact that the minimal average albedo values of the glacier contains considerable information regarding the relative share of areal surfaces between the ablation zone (i.e. ice with generally

  5. Recycled Uranium Mass Balance Project Y-12 National Security Complex Site Report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-12-01

    This report has been prepared to summarize the findings of the Y-12 National Security Complex (Y-12 Complex) Mass Balance Project and to support preparation of associated U. S. Department of Energy (DOE) site reports. The project was conducted in support of DOE efforts to assess the potential for health and environmental issues resulting from the presence of transuranic (TRU) elements and fission products in recycled uranium (RU) processed by DOE and its predecessor agencies. The United States government used uranium in fission reactors to produce plutonium and tritium for nuclear weapons production. Because uranium was considered scarce relative to demand when these operations began almost 50 years ago, the spent fuel from U.S. fission reactors was processed to recover uranium for recycling. The estimated mass balance for highly enriched RU, which is of most concern for worker exposure and is the primary focus of this project, is summarized in a table. A discrepancy in the mass balance between receipts and shipments (plus inventory and waste) reflects an inability to precisely distinguish between RU and non-RU shipments and receipts involving the Y-12 Complex and Savannah River. Shipments of fresh fuel (non-RU) and sweetener (also non-RU) were made from the Y-12 Complex to Savannah River along with RU shipments. The only way to distinguish between these RU and non-RU streams using available records is by enrichment level. Shipments of {le}90% enrichment were assumed to be RU. Shipments of >90% enrichment were assumed to be non-RU fresh fuel or sweetener. This methodology using enrichment level to distinguish between RU and non-RU results in good estimates of RU flows that are reasonably consistent with Savannah River estimates. Although this is the best available means of distinguishing RU streams, this method does leave a difference of approximately 17.3 MTU between receipts and shipments. Slightly depleted RU streams received by the Y-12 Complex from ORGDP and

  6. Estimation of the Greenland ice sheet surface mass balance for the 20th and 21st centuries

    Directory of Open Access Journals (Sweden)

    X. Fettweis

    2008-09-01

    Full Text Available Results from a regional climate simulation (1970–2006 over the Greenland ice sheet (GrIS reveals that more than 97% of the interannual variability of the modelled Surface Mass Balance (SMB can be explained by the GrIS summer temperature anomaly and the GrIS annual precipitation anomaly. This multiple regression is then used to empirically estimate the GrIS SMB since 1900 from climatological time series. The projected SMB changes in the 21st century are investigated with the set of simulations performed with atmosphere-ocean general circulation models (AOGCMs of the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR4. These estimates show that the high surface mass loss rates of recent years are not unprecedented in the GrIS history of the last hundred years. The minimum SMB rate seems to have occurred earlier in the 1930s and corresponds to a zero SMB rate. The AOGCMs project that the SMB rate of the 1930s would be common at the end of 2100. The temperature would be higher than in the 1930s but the increase of accumulation in the 21st century would partly offset the acceleration of surface melt due to the temperature increase. However, these assumptions are based on an empirical multiple regression only validated for recent/current climatic conditions, and the accuracy and time homogeneity of the data sets and AOGCM results used in these estimations constitute a large uncertainty.

  7. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy)

    International Nuclear Information System (INIS)

    Biganzoli, L.; Falbo, A.; Forte, F.; Grosso, M.; Rigamonti, L.

    2015-01-01

    Lombardia Region in 2011 was analysed in an LCA study. • Primary data were collected to model the WEEE treatment. • A detailed mass balance for each WEEE category was determined. • Results show the good environmental performance of the system. • The recovery of metals, plastic and glass gives the main benefits

  8. Evaluation of Primary Production in the Lower Amazon River Based on a Dissolved Oxygen Stable Isotopic Mass Balance

    Energy Technology Data Exchange (ETDEWEB)

    Gagne-Maynard, William C.; Ward, Nicholas D.; Keil, Richard G.; Sawakuchi, Henrique O.; Da Cunha, Alan C.; Neu, Vania; Brito, Daimio C.; Da Silva Less, Diani F.; Diniz, Joel E. M.; De Matos Valerio, Aline; Kampel, Milton; Krusche, Alex V.; Richey, Jeffrey E.

    2017-02-07

    The Amazon River outgasses nearly an equivalent amount of CO2 as the rainforest sequesters on an annual basis due to microbial decomposition of terrigenous and aquatic organic matter. Most research performed in the Amazon has been focused on unraveling the mechanisms driving CO2 production since the recognition of a persistent state of CO2 supersaturation. However, although the river system is clearly net heterotrophic, the interplay between primary production and respiration is an essential aspect to understanding the overall metabolism of the ecosystem and potential transfer of energy up trophic levels. For example, an efficient ecosystem is capable of both decomposing high amounts of organic matter at lower trophic levels, driving CO2 emissions, and accumulating energy/biomass in higher trophic levels, stimulating fisheries production. Early studies found minimal evidence for primary production in the Amazon River mainstem and it has since been assumed that photosynthesis is strongly limited by low light penetration attributed to the high sediment load. Here, we test this assumption by measuring the stable isotopic composition of O218O-O2) and O2 saturation levels in the lower Amazon River from Óbidos to the river mouth and its major tributaries, the Xingu and Tapajós rivers, during high and low water periods. An oxygen mass balance model was developed to estimate the input of photosynthetic oxygen in the discrete reach from Óbidos to Almeirim, midway to the river mouth. Based on the oxygen mass balance we estimate that primary production occurred at a rate of 0.39 ± 0.24 g O m3 d-1 at high water and 1.02 ± 0.55 g O m3 d-1 at low water. This translates to 41 ± 24% of the rate of O2 drawdown via respiration during high water and 67 ± 33% during low water. These primary production rates are 2-7 times higher than

  9. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Biganzoli, L., E-mail: laura.biganzoli@mail.polimi.it; Falbo, A.; Forte, F.; Grosso, M.; Rigamonti, L.

    2015-08-15

    Lombardia Region in 2011 was analysed in an LCA study. • Primary data were collected to model the WEEE treatment. • A detailed mass balance for each WEEE category was determined. • Results show the good environmental performance of the system. • The recovery of metals, plastic and glass gives the main benefits.

  10. Changes in the Mass Balance of the Greenland Ice Sheet in a Warming Climate During 2003-2009

    Science.gov (United States)

    Zwally, H. Jay; Luthcke, Scott

    2010-01-01

    Mass changes of the Greenland ice sheet (GIS) derived from ICESat and GRACE data both show that the net mass loss from GIS during 2003-2009 is about 175 Gt/year, which contributes 0.5mm/yr global sea-level rise. The rate of mass loss has increased significantly since the 1990's when the GIS was close to mass balance. Even though the GIS was close to mass balance during the 1990's, it was already showing characteristics of responding to8 warmer climate, specifically thinning at the margins and thickening inland at higher elevations. During 2003-2009, increased ice thinning due to increases in melting and acceleration of outlet glaciers began to strongly exceed the inland thickening from increases in accumulation. Over the entire GIS, the mass loss between the two periods, from increased melting and ice dynamics, increased by about 190 Gt/year while the mass gain, from increased precipitation and accumulation, increased by only about 15Gt/year. These ice changes occurred during a time when the temperature on GIS changed at rate of about 2K/decade. The distribution of elevation and mass changes derived from ICESat have high spatial resolution showing details over outlet glaciers, by drainage systems, and by elevation. However, information on the seasonal cycle of changes from ICESat data is limited, because the ICESat lasers were only operated during two to three campaigns per year of about 35 days duration each. In contrast, the temporal resolution of GRACE data, provided by the continuous data collection, is much better showing details of the seasonal cycle and the inter-annual variability. The differing sensitivity of the ICESat altimetry and the GRACE gravity methods to motion of the underlying bedrock from glacial isostatic adjustment (GIA) is used to evaluate the GIA corrections provided by models. The two data types are also combined to make estimates of the partitioning of the mass gains and losses among accumulation, melting, and ice discharge from outlet

  11. Norway and adjacent sedimentary basins during Cenozoic times - sediment fluxes, accumulation rates and mass balance

    DEFF Research Database (Denmark)

    Gołędowski, Bartosz; Nielsen, S.B.; Clausen, O.R.

    2011-01-01

    The objective of this study is to investigate varying sediment fluxes from the Scandinavian landmass during Cenozoic times and to calculate a mass balance from the observed accumulation rates. As the onshore area provides little data to quantify erosion rates and vertical movements of rock mass, we...... use offshore data from adjacent sedimentary basins (the North Sea and the Norwegian shelf) to calculate the amount of erosion. We have used a broad dataset of seismic 2D lines to map depositional units and a well dataset for the stratigraphic control and the velocity distribution in the sediments. We...... have therefore obtained accumulation rates in meters per million years for 5 depositional units in three areas - Southern North Sea, Central and Northern North Sea and the Norwegian shelf. Furthermore, taking into account the decay of porosity in sediments with burial depth, we have estimated...

  12. Incorrect interpretation of carbon mass balance biases global vegetation fire emission estimates.

    Science.gov (United States)

    Surawski, N C; Sullivan, A L; Roxburgh, S H; Meyer, C P Mick; Polglase, P J

    2016-05-05

    Vegetation fires are a complex phenomenon in the Earth system with many global impacts, including influences on global climate. Estimating carbon emissions from vegetation fires relies on a carbon mass balance technique that has evolved with two different interpretations. Databases of global vegetation fire emissions use an approach based on 'consumed biomass', which is an approximation to the biogeochemically correct 'burnt carbon' approach. Here we show that applying the 'consumed biomass' approach to global emissions from vegetation fires leads to annual overestimates of carbon emitted to the atmosphere by 4.0% or 100 Tg compared with the 'burnt carbon' approach. The required correction is significant and represents ∼9% of the net global forest carbon sink estimated annually. Vegetation fire emission studies should use the 'burnt carbon' approach to quantify and understand the role of this burnt carbon, which is not emitted to the atmosphere, as a sink enriched in carbon.

  13. Improving Surface Mass Balance Over Ice Sheets and Snow Depth on Sea Ice

    Science.gov (United States)

    Koenig, Lora Suzanne; Box, Jason; Kurtz, Nathan

    2013-01-01

    Surface mass balance (SMB) over ice sheets and snow on sea ice (SOSI) are important components of the cryosphere. Large knowledge gaps remain in scientists' abilities to monitor SMB and SOSI, including insufficient measurements and difficulties with satellite retrievals. On ice sheets, snow accumulation is the sole mass gain to SMB, and meltwater runoff can be the dominant single loss factor in extremely warm years such as 2012. SOSI affects the growth and melt cycle of the Earth's polar sea ice cover. The summer of 2012 saw the largest satellite-recorded melt area over the Greenland ice sheet and the smallest satellite-recorded Arctic sea ice extent, making this meeting both timely and relevant.

  14. Mass balance and surface movement of the Greenland Ice Sheet at Summit, Central Greenland

    DEFF Research Database (Denmark)

    Hvidberg, C.S.; Keller, K.; Gundestrup, N.S.

    1997-01-01

    During the GRIP deep drilling in Central Greenland, the ice sheet topography and surface movement at Summit has been mapped with GPS. Measurements of the surface velocity are presented for a strain net consisting of 13 poles at distances of 25-60 km from the GRIP site. Some results are: The GRIP...... site is located approximately 2 km NW of the topographic summit; the surface velocity at the GISP 2 site is 1.7 m/yr in the W direction. The present mass balance at Summit is calculated to be -0.03+/-0.04 m/yr, i.e. close to steady state. This result is the best now available for Summit. A small...... thinning rate might be a transient response of the Greenland Ice Sheet due to the temperature increase at the Wisconsin-Holocene transition....

  15. Mass balance investigation of perfluorooctanoic acid PFOA environmental levels, emissions and sinks in the northern hemisphere

    Energy Technology Data Exchange (ETDEWEB)

    Cousins, I.T.; Prevedouros, K. [Stockholm Univ., Stockholm (Sweden); Buck, R.C.; Korzeniowski, S.H. [Dupont Chemical Solutions, Wilmington, DE (United States)

    2005-07-01

    Perfluoroalkyl sulfonic acids (PFAS) and perfluoroalkyl carboxylic acids (PFCAs) and their precursors are found in a wide array of environmental samples, and have no known degradation mechanisms. PFCAs have been used for over 50 years as processing aids in the manufacture of fluoropolymers. PFASs and fluorotelomer products are used in a wide variety of products and industrial processes. This study provided a detailed account of direct and indirect sources of perfluorooctanoic acid (PFOA) in the environment. A mass balance investigation between sources and amounts residing in the northern hemisphere was conducted, and the magnitude of historical removal processes was estimated. It was hypothesized that the majority of historical PFOA production use, and emissions occurred in the northern hemisphere. The study considered both direct and indirect sources. Production and emissions were calculated from a number of published and unpublished chemical industry data. A mass balance computation was performed to estimate historical PFOA emissions with existing environmental levels and historical losses. A literature search was used to estimate representative PFOA levels in sediments and biota. The study confirmed the importance of surface water compartments for PFOA storage. Important sink processes included physical mixing and sedimentation to the deep oceans and sediment burial. Maximum and minimum ranges of the sum of the total environmental inventory and historical sink processes overlapped the ranges of emission estimates. It was concluded that a quantitative comparison of the atmospheric transport of PFOA precursors and the aquatic transport of the substances showed that ocean transport is the most significant transport routes of PFOAs. 13 refs., 1 tab., 1 fig.

  16. Persistent organic pollutants (POPs) in the conventional activated sludge treatment process: fate and mass balance

    International Nuclear Information System (INIS)

    Katsoyiannis, Athanasios; Samara, Constantini

    2005-01-01

    The fate and the mass balance of persistent organic pollutants (POPs) during the conventional activated sludge treatment process were investigated in the wastewater treatment plant of the city of Thessaloniki, northern Greece. The POPs of interest were 7 polychlorinated biphenyls and 19 organochlorine pesticides. Target compounds were determined at six different points across the treatment system: the influent, the effluent of the primary sedimentation tank, the effluent of the secondary sedimentation tank, the primary sludge, the activated sludge from the recirculation stream, and the digested/dewatered sludge. The distribution of POPs between the dissolved and the adsorbed phases of wastewater and sludge was investigated. A good linear relationship between the distribution coefficients, K d , and the octanol-water partition coefficients, K ow , of the solutes was observed only in raw wastewater, suggesting that other factors affect the phase distribution of organic compounds in treated wastewater. For all POPs, a significant increase in partitioning with a decreasing solids concentration was observed, revealing an effect from non-settling microparticles remaining in the 'dissolved' phase during the separation procedure. A good linear relationship was also revealed between logK d and the dissolved organic carbon (DOC) content of wastewater, suggesting that DOC favors the advective transport of POPs in the dissolved phase. Almost all POPs showed good mass balance agreements at both the primary and the secondary treatment. The losses observed for some species could be attributed to biodegradation/biotransformation rather than volatilization. The relative distribution between the treated effluent and the waste sludge streams varied largely among different compounds, with p-p'-DDE being highly accumulated in the waste sludge (98%) but almost 60% of α-HCH remaining in the treated effluent

  17. Mass Balance of the West Antarctic Ice-Sheet from ICESat Measurements

    Science.gov (United States)

    Zwally, H. Jay; Li, Jun; Robins, John; Saba, Jack L.; Yi, Donghui

    2011-01-01

    Mass balance estimates for 2003-2008 are derived from ICESat laser altimetry and compared with estimates for 1992-2002 derived from ERS radar altimetry. The net mass balance of 3 drainage systems (Pine Island, Thwaites/Smith, and the coast of Marie Bryd) for 2003-2008 is a loss of 100 Gt/yr, which increased from a loss of 70 Gt/yr for the earlier period. The DS including the Bindschadler and MacAyeal ice streams draining into the Ross Ice Shelf has a mass gain of 11 Gt/yr for 2003-2008, compared to an earlier loss of 70 Gt/yr. The DS including the Whillans and Kamb ice streams has a mass gain of 12 Gt/yr, including a significant thickening on the upper part of the Kamb DS, compared to a earlier gain of 6 Gt/yr (includes interpolation for a large portion of the DS). The other two DS discharging into the Ronne Ice Shelf and the northern Ellsworth Coast have a mass gain of 39 Gt/yr, compared to a gain of 4 Gt/yr for the earlier period. Overall, the increased losses of 30 Gt/yr in the Pine Island, Thwaites/Smith, and the coast of Marie Bryd DSs are exceeded by increased gains of 59 Gt/yr in the other 4 DS. Overall, the mass loss from the West Antarctic ice sheet has decreased to 38 Gt/yr from the earlier loss of 67 Gt/yr, reducing the contribution to sea level rise to 0.11 mm/yr from 0.19 mm/yr

  18. Source identification and mass balance studies of mercury in Lake An-dong, S. Korea

    Science.gov (United States)

    Han, J.; Byeon, M.; Yoon, J.; Park, J.; Lee, M.; Huh, I.; Na, E.; Chung, D.; Shin, S.; Kim, Y.

    2009-12-01

    In this study, mercury and methylmercury were measured in atmospheric, tributary, open-lake water column, sediment, planktons and fish samples in the catchments area of Lake An-dong, S. Korea. Lake An-dong, an artificial freshwater lake is located on the upstream of River Nak-dong. It has 51.5 km2 of open surface water and 1.33 year of hydraulic residence time. It is a source of drinking water for 0.3 million S. Koreans. Recently, the possibilities of its mercury contamination became an issue since current studies showed that the lake had much higher mercury level in sediment and certain freshwater fish species than any other lakes in S. Korea. This catchments area has the possibilities of historical mercury pollution by the location of more than 50 abandoned gold mines and Young-poong zinc smelter. The objective of this study was to develop a mercury mass balance and identify possible mercury sources in the lake. The results of this study are thus expected to offer valuable insights for the sources of mercury loading through the watershed. In order to estimate the mercury flux, TGM, RGM and particulate mercury were measured using TEKRAN 2537 at the five sites surrounding Lake An-dong from May, 2009 with wet and dry deposition. The fate and transport of mercury in water body were predicted by using EFDC (Environmental Dynamic Fluid Code) and Mercury module in WASP7 (Water quality analysis program) after subsequent distribution into water body, sediments, followed by bioaccumulation and ultimate uptake by humans. The mercury mass balance in Young-poong zinc smelter was also pre-estimated by measuring mercury content in zinc ores, emission gases, sludge, wastewater and products.

  19. Occurrence and simulation of trihalomethanes in swimming pool water: A simple prediction method based on DOC and mass balance.

    Science.gov (United States)

    Peng, Di; Saravia, Florencia; Abbt-Braun, Gudrun; Horn, Harald

    2016-01-01

    Trihalomethanes (THM) are the most typical disinfection by-products (DBPs) found in public swimming pool water. DBPs are produced when organic and inorganic matter in water reacts with chemical disinfectants. The irregular contribution of substances from pool visitors and long contact time with disinfectant make the forecast of THM in pool water a challenge. In this work occurrence of THM in a public indoor swimming pool was investigated and correlated with the dissolved organic carbon (DOC). Daily sampling of pool water for 26 days showed a positive correlation between DOC and THM with a time delay of about two days, while THM and DOC didn't directly correlate with the number of visitors. Based on the results and mass-balance in the pool water, a simple simulation model for estimating THM concentration in indoor swimming pool water was proposed. Formation of THM from DOC, volatilization into air and elimination by pool water treatment were included in the simulation. Formation ratio of THM gained from laboratory analysis using native pool water and information from field study in an indoor swimming pool reduced the uncertainty of the simulation. The simulation was validated by measurements in the swimming pool for 50 days. The simulated results were in good compliance with measured results. This work provides a useful and simple method for predicting THM concentration and its accumulation trend for long term in indoor swimming pool water. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Estimation of groundwater recharge using the chloride mass-balance method, Pingtung Plain, Taiwan

    Science.gov (United States)

    Ting, Cheh-Shyh; Kerh, Tienfuan; Liao, Chiu-Jung

    Due to rapid economic growth in the Pingtung Plain of Taiwan, the use of groundwater resources has changed dramatically. Over-pumping of the groundwater reservoir, which lowers hydraulic heads in the aquifers, is not only affecting the coastal area negatively but has serious consequences for agriculture throughout the plain. In order to determine the safe yield of the aquifer underlying the plain, a reliable estimate of groundwater recharge is desirable. In the present study, for the first time, the chloride mass-balance method is adopted to estimate groundwater recharge in the plain. Four sites in the central part were chosen to facilitate the estimations using the ion-chromatograph and Thiessen polygon-weighting methods. Based on the measured and calculated results, in all sites, including the mountain and river boundaries, recharge to the groundwater is probably 15% of the annual rainfall, excluding recharge from additional irrigation water. This information can improve the accuracy of future groundwater-simulation and management models in the plain. Résumé Du fait de la croissance économique rapide de la plaine de Pingtung à Taiwan, l'utilisation des ressources en eau souterraine s'est considérablement modifié. La surexploitation des aquifères, qui a abaissé le niveau des nappes, n'affecte pas seulement la région côtière, mais a de sérieuses répercutions sur l'agriculture dans toute la plaine. Afin de déterminer les ressources renouvelables de l'aquifère sous la plaine, une estimation précise de la recharge de la nappe est nécessaire. Dans cette étude, le taux de recharge de la nappe a d'abord été estimé au moyen d'un bilan de matière de chlorure. Quatre sites de la partie centrale ont été sélectionnés pour réaliser ces estimations, à l'aide d'un chromatographe ionique et de la méthode des polygones de Thiessen. A partir des résultats mesurés et calculés, à chaque site, et en prenant comme limites les montagnes et les rivi

  1. On the importance of the albedo parameterization for the mass balance of the Greenland ice sheet in EC-Earth

    Directory of Open Access Journals (Sweden)

    M. M. Helsen

    2017-08-01

    Full Text Available The albedo of the surface of ice sheets changes as a function of time due to the effects of deposition of new snow, ageing of dry snow, bare ice exposure, melting and run-off. Currently, the calculation of the albedo of ice sheets is highly parameterized within the earth system model EC-Earth by taking a constant value for areas with thick perennial snow cover. This is an important reason why the surface mass balance (SMB of the Greenland ice sheet (GrIS is poorly resolved in the model. The purpose of this study is to improve the SMB forcing of the GrIS by evaluating different parameter settings within a snow albedo scheme. By allowing ice-sheet albedo to vary as a function of wet and dry conditions, the spatial distribution of albedo and melt rate improves. Nevertheless, the spatial distribution of SMB in EC-Earth is not significantly improved. As a reason for this, we identify omissions in the current snow albedo scheme, such as separate treatment of snow and ice and the effect of refreezing. The resulting SMB is downscaled from the lower-resolution global climate model topography to the higher-resolution ice-sheet topography of the GrIS, such that the influence of these different SMB climatologies on the long-term evolution of the GrIS is tested by ice-sheet model simulations. From these ice-sheet simulations we conclude that an albedo scheme with a short response time of decaying albedo during wet conditions performs best with respect to long-term simulated ice-sheet volume. This results in an optimized albedo parameterization that can be used in future EC-Earth simulations with an interactive ice-sheet component.

  2. On the importance of the albedo parameterization for the mass balance of the Greenland ice sheet in EC-Earth

    Science.gov (United States)

    Helsen, Michiel M.; van de Wal, Roderik S. W.; Reerink, Thomas J.; Bintanja, Richard; Madsen, Marianne S.; Yang, Shuting; Li, Qiang; Zhang, Qiong

    2017-08-01

    The albedo of the surface of ice sheets changes as a function of time due to the effects of deposition of new snow, ageing of dry snow, bare ice exposure, melting and run-off. Currently, the calculation of the albedo of ice sheets is highly parameterized within the earth system model EC-Earth by taking a constant value for areas with thick perennial snow cover. This is an important reason why the surface mass balance (SMB) of the Greenland ice sheet (GrIS) is poorly resolved in the model. The purpose of this study is to improve the SMB forcing of the GrIS by evaluating different parameter settings within a snow albedo scheme. By allowing ice-sheet albedo to vary as a function of wet and dry conditions, the spatial distribution of albedo and melt rate improves. Nevertheless, the spatial distribution of SMB in EC-Earth is not significantly improved. As a reason for this, we identify omissions in the current snow albedo scheme, such as separate treatment of snow and ice and the effect of refreezing. The resulting SMB is downscaled from the lower-resolution global climate model topography to the higher-resolution ice-sheet topography of the GrIS, such that the influence of these different SMB climatologies on the long-term evolution of the GrIS is tested by ice-sheet model simulations. From these ice-sheet simulations we conclude that an albedo scheme with a short response time of decaying albedo during wet conditions performs best with respect to long-term simulated ice-sheet volume. This results in an optimized albedo parameterization that can be used in future EC-Earth simulations with an interactive ice-sheet component.

  3. Linking Morphodynamic Response with Sediment Mass Balance: Issues of Scale, Geomorphic Setting, and Sampling Design

    Science.gov (United States)

    Grams, P. E.; Topping, D. J.; Schmidt, J. C.; Kaplinski, M. A.; Hazel, J. E.

    2011-12-01

    The sediment mass balance, or budget, is one of the most powerful and frequently used conceptual frameworks in fluvial geomorphology. Sediment budgets are used to evaluate the effects of streamflow regulation, inform the design of stream restoration projects, and anticipate the outcomes of dam removal, among other applications. In almost every case, the primary interest is the interaction between changes in the sediment budget and the morphodynamics of specific channel features that make up the components of the sediment budget. However, linkages between changes in specific morphologic features and changes in the sediment budget are not necessarily straightforward and are often poorly understood. In order for the sediment budget to be used as an effective tool, these linkages must be better quantified. A complete understanding of these linkages is usually hampered by sparse data. Measurements of morphologic change typically consist of some type of sampling scheme that requires extrapolation to the reach scale and adequate measurements of both sediment influx and efflux are rarely available. Our attempts to develop a monitoring program for the Colorado River in Grand Canyon that tracks changes in specific morphologic features, transfers in sediment storage among channel features, and changes in the sediment budget have yielded several insights: (1) changes in sediment storage can be highly localized with as much as 80% of changes in storage occurring within as little as 1% of a reach; (2) areas where large storage changes are likely may be predictable in the sense that the largest changes tend to occur in specific geomorphic settings; (3) magnitudes of changes are unpredictable because nearby features of the same general geomorphic type often respond differently due to differences in local hydraulics; (4) the morphology of a set of features at the time of measurement may be strongly affected by the antecedent flow regime, thereby confounding attempts to make

  4. A century of variation in the dependence of Greenland iceberg calving on ice sheet surface mass balance and regional climate change.

    Science.gov (United States)

    Bigg, G R; Wei, H L; Wilton, D J; Zhao, Y; Billings, S A; Hanna, E; Kadirkamanathan, V

    2014-06-08

    Iceberg calving is a major component of the total mass balance of the Greenland ice sheet (GrIS). A century-long record of Greenland icebergs comes from the International Ice Patrol's record of icebergs (I48N) passing latitude 48° N, off Newfoundland. I48N exhibits strong interannual variability, with a significant increase in amplitude over recent decades. In this study, we show, through a combination of nonlinear system identification and coupled ocean-iceberg modelling, that I48N's variability is predominantly caused by fluctuation in GrIS calving discharge rather than open ocean iceberg melting. We also demonstrate that the episodic variation in iceberg discharge is strongly linked to a nonlinear combination of recent changes in the surface mass balance (SMB) of the GrIS and regional atmospheric and oceanic climate variability, on the scale of the previous 1-3 years, with the dominant causal mechanism shifting between glaciological (SMB) and climatic (ocean temperature) over time. We suggest that this is a change in whether glacial run-off or under-ice melting is dominant, respectively. We also suggest that GrIS calving discharge is episodic on at least a regional scale and has recently been increasing significantly, largely as a result of west Greenland sources.

  5. Mass balance and long-term fate of PCDD/Fs in a lagoon sediment and paddy soil, Niigata, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Mizuki [National Institute for Agro-Environmental Science, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan)], E-mail: mizukis@affrc.go.jp; Seike, Nobuyasu [National Institute for Agro-Environmental Science, 3-1-3 Kannondai, Tsukuba, Ibaraki 305-8604 (Japan)], E-mail: seike@niaes.affrc.go.jp; Kobayashi, Jun [National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305-8506 (Japan)], E-mail: kobayashi.jun@nies.go.jp; Kajihara, Hideo [National Institute of Advanced Industrial Science and Technology, 16-1 Tsukuba, Ibaraki 305-8569 (Japan)], E-mail: kajihara.hideo@aist.go.jp; Takahashi, Yukio [Academic Assembly Institute of Science and Technology, Niigata University, 2-8050 Ikarashi, Niigata City 950-2181 (Japan)], E-mail: yukitak@eng.niigata-u.ac.jp

    2008-12-15

    Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) in a sediment core and in samples of surface sediment and paddy soil collected from the Toyano lagoon and Kameda basin in Niigata, Japan, were analyzed to elucidate the temporal trends of their concentrations in the lagoon sediment and the relationship between the sediment and the paddy soil. The mass balance of these pollutants was also estimated to determine their long-term fate in surface waters. An analysis by chemical mass balance identified the agrochemicals pentachlorophenol and 2,4,6-trichlorophenyl 4-nitrophenyl ether as the major sources of PCDD/Fs. On the basis of the findings regarding the mass balance in the Kameda basin over the last 40 years, we estimate that more than half the input of PCDD/Fs to the Kameda basin has disappeared. We suggest that the PCDD/Fs that flowed out from the paddy fields have been transferred to the lower basin. - The long-term mass balance of PCDD/Fs in sediments from paddy soil is elucidated.

  6. Assessment of the surface mass balance along the K-transect (Greenland ice sheet) from satellite-derived albedos

    NARCIS (Netherlands)

    Oerlemans, J.; Greuell, W.

    This paper explores the potential of using satellite-derived albedos to estimate the surface mass balance of the Kangerlussuaq transect (K-transect; Greenland ice sheet). We first retrieved surface albedos from Advanced Very High Resolution Radar data by using, among other techniques, a new

  7. Very fast isotopic and mass balance calculations used for strategic planing of the nuclear fuel cycle

    International Nuclear Information System (INIS)

    Marguet, S.D.

    1993-01-01

    Owing to the prevalence in France of nuclear generated electricity, the french utility, EDF focuses much research on fuel cycle strategy. In this context, analysis of scenarios combining problems related to planning and economics, but also reactor physics, necessitate a relatively thorough understanding of fuel response to irradiation. The main purpose of the fuel strategy program codes is to predict mass balance modifications with time for the main actinides involved in the cycle, including the minor actinides associated with the current back end fuel cycle key issues. Considering the large number of calculations performed by a strategy code in an iterative process covering a range of about a hundred years, it was important to develop basic computation modules for both the ''reactor'' and ''fabrication'' items. These had to be high speed routines, but on an accuracy level compatible with the strategy code efficiency. At the end of 1992, the EDF Research and Development Division (EDF/DER) developed a very simple, extremely fast method of calculating transuranian isotope masses. This approach, which resulted in the STRAPONTIN software, considerably increased the scope of the EDF/DER fuel strategy code TIRELIRE without undue impairment of machine time requirements for a scenario. (author). 2 figs., 2 tabs., 3 refs

  8. Mass balance of biogeochemically active materials (C, N, P) in a hypersaline gulf

    Science.gov (United States)

    Smith, S. V.; Veeh, H. H.

    1989-09-01

    Inverse estuaries tend to have long water residence time and little hydrographic input of materials. Yet such systems can support apparently normal marine communities. Slow net fluxes over long timespans substantially alter water composition, so such systems provide an opportunity to study system-scale characteristics of net material fluxes. We have examined the mass balance of water, salt, C, N, and P in Spencer Gulf, a large inverse estuary in South Australia. Dissolved inorganic C is taken up in Spencer Gulf by biogenic CaCO 3 precipitation and organic production. Input of C includes both hydrographic processes and gas flux across the air-sea interface. Most of the C uptake is exported as particulate organic matter; some is exported as dissolved organic matter; relatively little organic C is buried in the sediments. Virtually all dissolved inorganic P delivered to the gulf is taken up and apparently largely exported as particulate material. The major source of N appears to be the atmosphere, and dissolved organic N export exceeds dissolved inorganic N import. The fluxes of C, N, and P are biologically mediated, and we look for a plausible interaction among these fluxes. The CO 2 system appears remarkably 'balanced' by its fluxes—to relatively constant pH, PCO 2, and calcite saturation state. We conclude that supply of PO 43- largely controls characteristics of C and N flux. The controls postulated for P include CaCO 3 precipitation, CO 2 gas flux, organic C production, and N fixation.

  9. Sediment source apportionment in Laurel Hill Creek, PA, using Bayesian chemical mass balance and isotope fingerprinting

    Science.gov (United States)

    Stewart, Heather; Massoudieh, Arash; Gellis, Allen C.

    2015-01-01

    A Bayesian chemical mass balance (CMB) approach was used to assess the contribution of potential sources for fluvial samples from Laurel Hill Creek in southwest Pennsylvania. The Bayesian approach provides joint probability density functions of the sources' contributions considering the uncertainties due to source and fluvial sample heterogeneity and measurement error. Both elemental profiles of sources and fluvial samples and 13C and 15N isotopes were used for source apportionment. The sources considered include stream bank erosion, forest, roads and agriculture (pasture and cropland). Agriculture was found to have the largest contribution, followed by stream bank erosion. Also, road erosion was found to have a significant contribution in three of the samples collected during lower-intensity rain events. The source apportionment was performed with and without isotopes. The results were largely consistent; however, the use of isotopes was found to slightly increase the uncertainty in most of the cases. The correlation analysis between the contributions of sources shows strong correlations between stream bank and agriculture, whereas roads and forest seem to be less correlated to other sources. Thus, the method was better able to estimate road and forest contributions independently. The hypothesis that the contributions of sources are not seasonally changing was tested by assuming that all ten fluvial samples had the same source contributions. This hypothesis was rejected, demonstrating a significant seasonal variation in the sources of sediments in the stream.

  10. Fluxes and the mass balance of mercury in Augusta Bay (Sicily, southern Italy)

    Science.gov (United States)

    Salvagio Manta, Daniela; Bonsignore, Maria; Oliveri, Elvira; Barra, Marco; Tranchida, Giorgio; Giaramita, Luigi; Mazzola, Salvatore; Sprovieri, Mario

    2016-11-01

    The flux (Φ) of mercury (Hg) at the sediment-seawater interface was investigated in Augusta Bay (southern Italy) where uncontrolled industrial discharge from one of the most important chlor-alkali plant in Europe has caused significant negative effects on the environment. Hg fluxes were measured by the deployment of in-situ benthic chamber. The obtained value of 1.3 kmol y-1 clearly emphasizes the role of the sediments as source of Hg for the overlying water column. Moreover, Hg concentrations in the outflowing bottom waters were measured to estimate the export of this pollutant from Augusta Bay to the open sea. The calculated value of 0.54 kmol y-1, corresponding to ∼4% of the anthropogenic input of Hg from coastal point/diffuse sources to the Mediterranean Sea (12.5 kmol y-1; Rajar et al., 2007; UNEP-MAP, 2001), assigns this area a crucial role in the Hg inventory of the entire Mediterranean basin. Finally, a consistent and robust mass balance for Hg in Augusta Bay was provided by combining the obtained data with Hg fluxes at seawater-atmosphere interface.

  11. Quantifying in-stream retention of nitrate at catchment scales using a practical mass balance approach.

    Science.gov (United States)

    Schwientek, Marc; Selle, Benny

    2016-02-01

    As field data on in-stream nitrate retention is scarce at catchment scales, this study aimed at quantifying net retention of nitrate within the entire river network of a fourth-order stream. For this purpose, a practical mass balance approach combined with a Lagrangian sampling scheme was applied and seasonally repeated to estimate daily in-stream net retention of nitrate for a 17.4 km long, agriculturally influenced, segment of the Steinlach River in southwestern Germany. This river segment represents approximately 70% of the length of the main stem and about 32% of the streambed area of the entire river network. Sampling days in spring and summer were biogeochemically more active than in autumn and winter. Results obtained for the main stem of Steinlach River were subsequently extrapolated to the stream network in the catchment. It was demonstrated that, for baseflow conditions in spring and summer, in-stream nitrate retention could sum up to a relevant term of the catchment's nitrogen balance if the entire stream network was considered.

  12. Mass balance of decabromodiphenyl ethane and decabromodiphenyl ether in a WWTP.

    Science.gov (United States)

    Ricklund, Niklas; Kierkegaard, Amelie; McLachlan, Michael S; Wahlberg, Cajsa

    2009-01-01

    The additive flame retardant decabromodiphenyl ethane (deBDethane) has been identified in the environment, but little is known about its environmental behaviour. It is structurally similar to decabromodiphenyl ether (decaBDE), making it conceivable that it may also become an environmental contaminant of concern. In this study a mass balance of deBDethane and decaBDE was undertaken in a modern WWTP in Stockholm serving 7.05x10(5) inhabitants. Flow proportional samples of plant influent and effluent as well as daily grab samples of digested sludge were collected during two 7-day periods. All samples were analyzed with GC/HRMS using isotope labelled internal standards. The mean mass flows of deBDethane and decaBDE to the WWTP were 6.0 g per day and 55 g per day, respectively. Of this, less than 1% of both BFRs left the WWTP via the effluent, while the bulk was sequestered into the digested sludge, where the mean concentrations of deBDethane and decaBDE were 81 and 800 ng g(-1)d.wt., respectively. It is concluded that the transfer efficiency of deBDethane from the technosphere to the environment via WWTPs is similar to that of decaBDE.

  13. Performance of the Fuel Conditioning Facility electronic in-cell mass balances

    International Nuclear Information System (INIS)

    Orechwa, Y.; Bucher, R.G.

    1996-01-01

    An approach to error estimation and measurement control in the analysis of the balance measurements of mass standards on the in-cell electronic mass balances of the Fuel Conditioning Facility is presented. In light of measurement data from one year of operation, the algorithms proposed are evaluated. The need to take into account the effects of facility operations on the estimates of measurement uncertainty is demonstrated. In the case of a newly installed balance, where no historical data exists, an ad hoc procedure of adding a term which takes into account the operational variability is proposed. This procedure allows a sufficiently long operation so as to collect data for the estimate of the contribution of operational effects to the uncertainty estimate. An algorithm for systematically taking into account historical data is developed and demonstrated for two balances over two calibration periods. The algorithm, both asymptotically and in the two samples cases, has the necessary desirable properties for estimating the uncertainty in the measurements of the balances

  14. Challenges for Greenland-wide mass balance from Cryosat-2 radar-altimetry

    DEFF Research Database (Denmark)

    Simonsen, Sebastian Bjerregaard; Forsberg, René; Sørensen, Louise Sandberg

    As the Greenland ice sheet warms, a change in the structure of the upper snow/firn occurs. This change further induces changes in the reflective properties of the firn seen from satellite radar altimetry. If not identified as changes in the reflective properties of the firn, these may be interpre......As the Greenland ice sheet warms, a change in the structure of the upper snow/firn occurs. This change further induces changes in the reflective properties of the firn seen from satellite radar altimetry. If not identified as changes in the reflective properties of the firn, these may...... be interpreted as actual surface elevation changes seen from the satellite radar altimetry (Nilsson et al., 2015).Here, we investigate how to correct the elevation change observed from the ESA Cryosat-2 radar altimetry mission to derive elevation change of the air/snow interface of the Greenland ice sheet....... The elevation change of this “real” physical surface is crucial, if the goal is to derive Greenland mass balance as done for LiDAR missions.The investigations look into waveform parameters to correct for the observed bias between Radar and LiDAR observations when using Croysat-2 level-2 data. Based...

  15. The impact of a seasonally ice free Arctic Ocean on the temperature, precipitation and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2012-01-01

    Full Text Available The observed decline in summer sea ice extent since the 1970s is predicted to continue until the Arctic Ocean is seasonally ice free during the 21st Century. This will lead to a much perturbed Arctic climate with large changes in ocean surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers and is expected to experience rapid warming over the 21st Century. The total sea level rise if all the land ice on Svalbard were to melt completely is 0.02 m.

    The purpose of this study is to quantify the impact of climate change on Svalbard's surface mass balance (SMB and to determine, in particular, what proportion of the projected changes in precipitation and SMB are a result of changes to the Arctic sea ice cover. To investigate this a regional climate model was forced with monthly mean climatologies of sea surface temperature (SST and sea ice concentration for the periods 1961–1990 and 2061–2090 under two emission scenarios. In a novel forcing experiment, 20th Century SSTs and 21st Century sea ice were used to force one simulation to investigate the role of sea ice forcing. This experiment results in a 3.5 m water equivalent increase in Svalbard's SMB compared to the present day. This is because over 50 % of the projected increase in winter precipitation over Svalbard under the A1B emissions scenario is due to an increase in lower atmosphere moisture content associated with evaporation from the ice free ocean. These results indicate that increases in precipitation due to sea ice decline may act to moderate mass loss from Svalbard's glaciers due to future Arctic warming.

  16. Quantification of Dialytic Removal and Extracellular Calcium Mass Balance during a Weekly Cycle of Hemodialysis.

    Directory of Open Access Journals (Sweden)

    Jacek Waniewski

    Full Text Available The removal of calcium during hemodialysis with low calcium concentration in dialysis fluid is generally slow, and the net absorption of calcium from dialysis fluid is often reported. The details of the calcium transport process during dialysis and calcium mass balance in the extracellular fluid, however, have not been fully studied.Weekly cycle of three dialysis sessions with interdialytic breaks of 2-2-3 days was monitored in 25 stable patients on maintenance hemodialysis with calcium concentration in dialysis fluid of 1.35 mmol/L. Total and ionic calcium were frequently measured in blood and dialysate. The volume of fluid compartments was measured by bioimpedance.Weekly dialytic removal of 12.79 ± 8.71 mmol calcium was found in 17 patients, whereas 9.48 ± 8.07 mmol calcium was absorbed per week from dialysis fluid in 8 patients. Ionic calcium was generally absorbed from dialysis fluid, whereas complexed calcium (the difference of total and ionic calcium in dialysis fluid was removed from the body. The concentration of total calcium in plasma increased slightly during dialysis. The mass of total and ionic calcium in extracellular fluid decreased during dialysis in patients with the dialytic removal of calcium from the body and did not change in patients with the absorption of calcium from dialysis fluid.We conclude that about one third of patients on dialysis with calcium 1.35 mmol/L in dialysis fluid may absorb calcium from dialysis fluid and therefore individual prescriptions of calcium concentration in dialysis fluid should be considered for such patients.

  17. Denudation rates from mass balance on alluvial fans in the chinese Tian Shan

    Science.gov (United States)

    Guerit, Laure; Barrier, Laurie; Métivier, François; Jolivet, Marc; Fu, Bihong

    2015-04-01

    Denudation is a key process for mountain ranges evolution as it is an essential parameter to study the mass transfer over the Earth surface, the evolution of reliefs, or the complex relationships between climate, erosion and landscape changes. Several methods have been develop to quantify denudation such as the estimation of paleo-sediment fluxes from mass budget. In fact, markers of erosion within drainage areas are often scarce, temporary and difficult to reach. At the outlet of mountain belts, more continuous and perennial records of deposition can be found in sedimentary basins. Sediment budget is thus a powerful approach, generally used at the scale of sedimentary basins. However, this method can also be applied on smaller sedimentary systems, such as alluvial fans. Yet, it is seldom used on these systems, and consequently, its accuracy is barely questioned. We propose to implement such a method on several alluvial fan systems in the Chinese part of the Tian Shan Range, where estimations of denudation rates have already been proposed. Based on the reconstruction of two generations of alluvial fans, we estimate the volume of sediment exported out of the drainage system of the range for the Middle- Late Pleistocene (300 000 to ~11 000 y) and for the Holocene (~11 000 y to present). From these volumes, we derive denudation rates of ~135 m/My at maximum for these two periods, in good agreement with previous mass balance studies. Despite a strong change in the morphology of the piedmont at the onset of the Holocene, denudation rate seems quite stable within the hinterland mountains. This value is quite low for such a range. Based on a comparison of denudation rates observed in other areas over the world with comparable shortening or precipitation rates, we suggest that the low denudation rate observed in the chinese Tian Shan is related to the limited amount of precipitation.

  18. Mass balance analyses of nutrients on California dairies to evaluate data quality for regulatory review.

    Science.gov (United States)

    Miller, Christine M F; Price, Patricia L; Meyer, Deanne

    2017-02-01

    Effective regulations may help reduce nitrate contamination of groundwater from agriculture. Dairy farmers in California must maintain a ratio below 1.4 of total nitrogen (N) applied to total N-removed (N-Ratio) on cropland receiving manure application. In annual reports to the regulatory agency, farmers detail nutrients applied to cropland, removed in harvests, and exported off farm. Data were extracted from all available annual reports for 62 dairies from 2011, 2012, and 2013. Excretions of N, phosphorus (P), and potassium (K) were calculated using reported herd demographics and standard excretion equations from the American Society of Agricultural and Biological Engineers. Calculated nutrient excretion values were compared to the reported values of manure nutrients applied to cropland and exported off farm. Reported N-Ratios were compared to mass balance simulations exploring variable crop yields and alfalfa management. In the nutrient excretion balance, the distribution of the percent of N and P recovered in manures applied or exported peaked at 24% (median=31%) and 26% (median=53%) of excreted, respectively. The distribution of recovered K was fairly uniform from 0% to 300% (median=146%) of excreted K. In N-ratio simulations, 62% and 66% of all reported N-ratios were lower than their respective simulated N-ratio, assuming alfalfa crops received no N fertilization and minimal fertilization (26% of N-removed in harvest) respectively. When simulated crop yields were normally (sd=0.25) or Student's t distributed (df=154) around expected crop yields, 28% and 57% of all reported ratios fell within the 95% confidence interval of the simulations, respectively. Low and erratic recovery rates of excreted P and K existed. Additionally, reported N-Ratios were generally lower and more varied than necessary for farmers to maintain crop yields while complying with regulations. Greater understanding of low recovery rates is needed before data are used to assess the impact of

  19. Precursors predicted by artificial neural networks for mass balance calculations: Quantifying hydrothermal alteration in volcanic rocks

    Science.gov (United States)

    Trépanier, Sylvain; Mathieu, Lucie; Daigneault, Réal; Faure, Stéphane

    2016-04-01

    This study proposes an artificial neural networks-based method for predicting the unaltered (precursor) chemical compositions of hydrothermally altered volcanic rock. The method aims at predicting precursor's major components contents (SiO2, FeOT, MgO, CaO, Na2O, and K2O). The prediction is based on ratios of elements generally immobile during alteration processes; i.e. Zr, TiO2, Al2O3, Y, Nb, Th, and Cr, which are provided as inputs to the neural networks. Multi-layer perceptron neural networks were trained on a large dataset of least-altered volcanic rock samples that document a wide range of volcanic rock types, tectonic settings and ages. The precursors thus predicted are then used to perform mass balance calculations. Various statistics were calculated to validate the predictions of precursors' major components, which indicate that, overall, the predictions are precise and accurate. For example, rank-based correlation coefficients were calculated to compare predicted and analysed values from a least-altered test dataset that had not been used to train the networks. Coefficients over 0.87 were obtained for all components, except for Na2O (0.77), indicating that predictions for alkali might be less performant. Also, predictions are performant for most volcanic rock compositions, except for ultra-K rocks. The proposed method provides an easy and rapid solution to the often difficult task of determining appropriate volcanic precursor compositions to rocks modified by hydrothermal alteration. It is intended for large volcanic rock databases and is most useful, for example, to mineral exploration performed in complex or poorly known volcanic settings. The method is implemented as a simple C++ console program.

  20. Nitrogen losses from dairy manure estimated through nitrogen mass balance and chemical markers

    Science.gov (United States)

    Hristov, Alexander N.; Zaman, S.; Vander Pol, M.; Ndegwa, P.; Campbell, L.; Silva, S.

    2009-01-01

    Ammonia is an important air and water pollutant, but the spatial variation in its concentrations presents technical difficulties in accurate determination of ammonia emissions from animal feeding operations. The objectives of this study were to investigate the relationship between ammonia volatilization and ??15N of dairy manure and the feasibility of estimating ammonia losses from a dairy facility using chemical markers. In Exp. 1, the N/P ratio in manure decreased by 30% in 14 d as cumulative ammonia losses increased exponentially. Delta 15N of manure increased throughout the course of the experiment and ??15N of emitted ammonia increased (p < 0.001) quadratically from -31??? to -15 ???. The relationship between cumulative ammonia losses and ??15N of manure was highly significant (p < 0.001; r2 = 0.76). In Exp. 2, using a mass balance approach, approximately half of the N excreted by dairy cows (Bos taurus) could not be accounted for in 24 h. Using N/P and N/K ratios in fresh and 24-h manure, an estimated 0.55 and 0.34 (respectively) of the N excreted with feces and urine could not be accounted for. This study demonstrated that chemical markers (P, K) can be successfully used to estimate ammonia losses from cattle manure. The relationship between manure ??15N and cumulative ammonia loss may also be useful for estimating ammonia losses. Although promising, the latter approach needs to be further studied and verified in various experimental conditions and in the field. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

  1. A mass balance approach to investigate arsenic cycling in a petroleum plume.

    Science.gov (United States)

    Ziegler, Brady A; Schreiber, Madeline E; Cozzarelli, Isabelle M; Crystal Ng, G-H

    2017-12-01

    Natural attenuation of organic contaminants in groundwater can give rise to a series of complex biogeochemical reactions that release secondary contaminants to groundwater. In a crude oil contaminated aquifer, biodegradation of petroleum hydrocarbons is coupled with the reduction of ferric iron (Fe(III)) hydroxides in aquifer sediments. As a result, naturally occurring arsenic (As) adsorbed to Fe(III) hydroxides in the aquifer sediment is mobilized from sediment into groundwater. However, Fe(III) in sediment of other zones of the aquifer has the capacity to attenuate dissolved As via resorption. In order to better evaluate how long-term biodegradation coupled with Fe-reduction and As mobilization can redistribute As mass in contaminated aquifer, we quantified mass partitioning of Fe and As in the aquifer based on field observation data. Results show that Fe and As are spatially correlated in both groundwater and aquifer sediments. Mass partitioning calculations demonstrate that 99.9% of Fe and 99.5% of As are associated with aquifer sediment. The sediments act as both sources and sinks for As, depending on the redox conditions in the aquifer. Calculations reveal that at least 78% of the original As in sediment near the oil has been mobilized into groundwater over the 35-year lifespan of the plume. However, the calculations also show that only a small percentage of As (∼0.5%) remains in groundwater, due to resorption onto sediment. At the leading edge of the plume, where groundwater is suboxic, sediments sequester Fe and As, causing As to accumulate to concentrations 5.6 times greater than background concentrations. Current As sinks can serve as future sources of As as the plume evolves over time. The mass balance approach used in this study can be applied to As cycling in other aquifers where groundwater As results from biodegradation of an organic carbon point source coupled with Fe reduction. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Chloride-mass-balance for predicting increased recharge after land-use change

    Energy Technology Data Exchange (ETDEWEB)

    Gee, G.W.; Zhang, Z.F.; Tyler, S.W.; Albright, W.H.; Singleton, M.J.

    2004-02-23

    The chloride-mass-balance (CMB) method has been used extensively to estimate recharge in arid and semi-arid environments. Required data include estimates of annual precipitation, total chloride input (from dry fallout and precipitation), and pore-water chloride concentrations. Typically, CMB has been used to estimate ancient recharge but recharge from recent land-use change has also been documented. Recharge rates below a few mm/yr are reliably detected with CMB; however, estimates above a few mm/yr appear to be less reliable. We tested the CMB method against 26 years of drainage from a 7.6-m-deep lysimeter at a simulated waste-burial ground, located on the Department of Energy s Hanford Site in southeastern Washington State, USA where land-use change has increased recharge rates. Measured drainage from the lysimeter for the past 26 years averaged 62 mm/yr. Precipitation averaged 190 mm/yr with an estimated chloride input of 0.225 mg/L. Initial pore-water chloride concentration was 88 mg/L and decreased to about 6 mg/L after 26 years, while the drainage water decreased to less than 1 mg/L. A recharge estimate made using chloride concentrations in drain water was within 20 percent of the measured drainage rate. In contrast, recharge estimates using 1:1 (water: soil) extracts were lower than actual by factors ranging from 2 to 8 or more. The results suggest that when recharge is above a few mm/yr, soil water extracts can lead to unreliable estimates of recharge. For conditions of elevated recharge, direct sampling of pore water is the preferred method, because chloride concentrations are often 20 to 50 times higher in directly-sampled pore water than in pore-water extracts.

  3. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    2006-07-03

    Jul 3, 2006 ... WW wastewater. WWTP wastewater treatment plant. List of symbols. bH, b'H. OHO endogenous respiration and death rates (/d). Additional subscripts T and 20 denote rates at T and 20oC fav, fat. OHO fraction of AS with respect to VSS and TSS. Additional subscripts i or e denote aerobic digester influent or ...

  4. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    From an experimental and theoretical investigation of the continuity of influent inorganic suspended solids (ISS) along the links connecting the primary settling tank, fully aerobic or N removal activated sludge and anaerobic and aerobic digestion unit operations, it was found that the influent wastewater (fixed) ISS ...

  5. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    From an experimental and theoretical investigation of the continuity of activated sludge organic (COD), inorganic and N compounds along the link between the fully aerobic or N removal activated sludge (AS) and anaerobic digestion unit operations, it was found that the unbiodegradable particulate organics originating from ...

  6. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    From a theoretical investigation of the continuity of wastewater organic (COD) and N compounds along the links connecting the primary settling tank (PST), fully aerobic or N removal activated sludge (AS) treating raw and settled wastewater and aerobic digestion unit operations, it was found that the PS characteristics, viz.

  7. Mass balance-based plant-wide wastewater treatment plant models ...

    African Journals Online (AJOL)

    From an experimental and theoretical investigation of the continuity of wastewater organic chemical oxygen demand (COD) and nitrogen (N) compounds along the link connecting the primary settling tank (PST) and anaerobic digester (AD), it was found that the primary sludge (PS) characteristics, viz. the biodegradable and ...

  8. Impacts of invasive earthworms on soil mercury cycling: Two mass balance approaches to an earthworm invasion in a northern Minnesota forest

    Science.gov (United States)

    Sona Psarska; Edward A. Nater; Randy Kolka

    2016-01-01

    Invasive earthworms perturb natural forest ecosystems that initially developed without them, mainly by consuming the forest floor (an organic rich surficial soil horizon) and by mixing the upper parts of the soil. The fate of mercury (Hg) formerly contained in the forest floor is largely unknown. We used two mass balance approaches (simple mass balance and geochemical...

  9. Evaluation of the effect of conventionally prepared swarna makshika bhasma on different bio-chemical parameters in experimental animals.

    Science.gov (United States)

    Mohapatra, Sudhaldev; Jha, C B

    2011-10-01

    Swarna makshika (chalcopyrite) bhasma (SMB) has been used for different therapeutic purposes since long in Ayurveda. The present study is conducted to evaluate the effect of conventionally prepared SMB on different bio-chemical parameters in experimental animals, for providing scientific data base for its logical use in clinical practice. The genuine SMB was prepared by following classical techniques of shodhana and marana most commonly used by different Ayurvedic drug manufacturers. Shodhana was done by roasting raw swarna makshika with lemon juice for three days and marana was performed by 11 putas. The experimental animals (rats) were divided into two groups. SMB mixed with diluted honey was administered orally in therapeutic dose to Group SMB and diluted honey only was administered to vehicle control Group, for 30 days. The blood samples were collected twice, after 15 days and after 30 days of drug administration and different biochemical investigations were done. Biochemical parameters were chosen based on references from Ayurvedic classics and contemporary medicine. It was observed that Hb% was found significantly increased and LDL and VLDL were found significantly decreased in Group SMB when compared with vehicle control group. This experimental data will help the clinician for the logical use of SMB in different disease conditions with findings like low Hb% and high LDL, VLDL levels.

  10. Evaluation of the effect of conventionally prepared swarna makshika bhasma on different bio-chemical parameters in experimental animals

    Directory of Open Access Journals (Sweden)

    Sudhaldev Mohapatra

    2011-01-01

    Full Text Available Swarna makshika (chalcopyrite bhasma (SMB has been used for different therapeutic purposes since long in Ayurveda. The present study is conducted to evaluate the effect of conventionally prepared SMB on different bio-chemical parameters in experimental animals, for providing scientific data base for its logical use in clinical practice. The genuine SMB was prepared by following classical techniques of shodhana and marana most commonly used by different Ayurvedic drug manufacturers. Shodhana was done by roasting raw swarna makshika with lemon juice for three days and marana was performed by 11 putas . The experimental animals (rats were divided into two groups. SMB mixed with diluted honey was administered orally in therapeutic dose to Group SMB and diluted honey only was administered to vehicle control Group, for 30 days. The blood samples were collected twice, after 15 days and after 30 days of drug administration and different biochemical investigations were done. Biochemical parameters were chosen based on references from Ayurvedic classics and contemporary medicine. It was observed that Hb% was found significantly increased and LDL and VLDL were found significantly decreased in Group SMB when compared with vehicle control group. This experimental data will help the clinician for the logical use of SMB in different disease conditions with findings like low Hb% and high LDL, VLDL levels.

  11. Sensitivity and detection limit analysis of silicon nanowire bio(chemical) sensors

    NARCIS (Netherlands)

    Chen, S.; van den Berg, Albert; Carlen, Edwin

    2015-01-01

    This paper presents an analysis of the sensitivity and detection limit of silicon nanowire biosensors using an analytical model in combination with I-V and current noise measurements. The analysis shows that the limit of detection (LOD) and signal to noise ratio (SNR) can be optimized by determining

  12. A systematic synthesis and design methodology to achieve process intensification in (bio) chemical processes

    DEFF Research Database (Denmark)

    Lutze, Philip; Roman Martinez, Alicia; Woodley, John

    2012-01-01

    be intensified for the biggest improvement is difficult to identify. In this paper the development of a systematic computer aided model-based synthesis and design methodology incorporating PI is presented. In order to manage the complexities involved, the methodology employs a decomposition-based solution...... the chemo-enzymatic synthesis of N-acetyl-d-neuraminic acid (Neu5Ac)....

  13. Application of a contaminant mass balance method at an old landfill to assess the impact on water resources

    DEFF Research Database (Denmark)

    Thomsen, Nanna Isbak; Milosevic, Nemanja; Bjerg, Poul Løgstrup

    2012-01-01

    linking soil and groundwater contamination to surface water pollution are required. This paper presents a method which provides an estimate of the contaminant mass discharge, using a combination of a historical investigation and contaminant mass balance approach. The method works at the screening level...... and could be part of a risk assessment. The study site was Risby Landfill, an old unlined landfill located in a clay till setting on central Zealand, Denmark. The contaminant mass discharge was determined for three common leachate indicators: chloride, dissolved organic carbon and ammonium. For instance...... of chloride to the small Risby Stream down gradient of the landfill was approximately 31kg/year. The contaminant mass balance method worked well for chloride and dissolved organic carbon, but the uncertainties were elevated for ammonium due to substantial spatial variability in the source composition...

  14. Characterization of methane oxidation in a simulated landfill cover system by comparing molecular and stable isotope mass balances.

    Science.gov (United States)

    Schulte, Marcel; Jochmann, Maik A; Gehrke, Tobias; Thom, Andrea; Ricken, Tim; Denecke, Martin; Schmidt, Torsten C

    2017-11-01

    Biological methane oxidation may be regarded as a method of aftercare treatment for landfills to reduce climate relevant methane emissions. It is of social and economic interest to estimate the behavior of bacterial methane oxidation in aged landfill covers due to an adequate long-term treatment of the gas emissions. Different approaches assessing methane oxidation in laboratory column studies have been investigated by other authors recently. However, this work represents the first study in which three independent approaches, ((i) mass balance, (ii) stable isotope analysis, and (iii) stoichiometric balance of product (CO 2 ) and reactant (CH 4 ) by CO 2 /CH 4 -ratio) have been compared for the estimation of the biodegradation by a robust statistical validation on a rectangular, wide soil column. Additionally, an evaluation by thermal imaging as a potential technique for the localization of the active zone of bacterial methane oxidation has been addressed in connection with stable isotope analysis and CO 2 /CH 4 -ratios. Although landfills can be considered as open systems the results for stable isotope analysis based on a closed system correlated better with the mass balance than calculations based on an open system. CO 2 /CH 4 -ratios were also in good agreement with mass balance. In general, highest values for biodegradation were determined from mass balance, followed by CO 2 /CH 4 -ratio, and stable isotope analysis. The investigated topsoil proved to be very suitable as a potential cover layer by removing up to 99% of methane for CH 4 loads of 35-65gm -2 d -1 that are typical in the aftercare phase of landfills. Finally, data from stable isotope analysis and the CO 2 /CH 4 -ratios were used to trace microbial activity within the reactor system. It was shown that methane consumption and temperature increase, as a cause of high microbial activity, correlated very well. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Hopanes Degradation: New Observational Evidence and Their Incorporation into Chemical Mass Balance Source Apportionment of PM2.5

    Science.gov (United States)

    Wong, Yee Ka; Huang, Xiao Hui Hilda; Zhen Yu, Jian

    2017-04-01

    The chemically unstable and semi-volatile nature of molecular markers is among the major concerns in receptor model source apportionment of airborne fine particulates (PM2.5). This hampers our way towards a more reliable estimation of source contributions, which is crucial for optimized air quality control in polluted areas. Vehicular exhaust (VE) is an important factor contributing to PM2.5 pollution in urbanized areas. Quantifying its source contribution estimate by receptor modelling has so far been relying mainly on hopanes, a group of molecular markers for fossil fuel combustion sources. Evidence for their atmospheric instability from both ambient measurements and chamber studies has been emerging. Overlooking atmospheric degradation would unarguably underestimate the source contribution, but studies about determining the bias has hitherto been scarce. We will share some findings from analysing PM2.5 chemical speciation data, particularly C27-C31 hopanes and elemental carbon (EC), in two urban sites of the Pearl River Delta, a polluted co-urbanized region in China. Evidence for atmospheric hopanes degradation through investigating ratio-ratio plot normalized against EC will be shown. We will also present the first result of investigating the ratios between hopanes abundance normalized by the least reactive homologue in ambient PM2.5 and that in representative VE source profiles, to further corroborate hopanes degradation. This method could potentially be used in other regions to determine whether hopanes degradation exists. We deployed the effective variance-chemical mass balance (CMB) model to apportion organic carbon (OC) in PM2.5 and subsequently total PM2.5, with special emphasis on determining the bias arising from hopanes degradation. The effect was incorporated by applying degradation factors derived from pseudo-first-order atmospheric oxidation to ambient hopanes concentrations. The extent of degradation was individually determined for each sample

  16. Phosphorus mass balance in a highly eutrophic semi-enclosed inlet near a big metropolis: a small inlet can contribute towards particulate organic matter production.

    Science.gov (United States)

    Asaoka, Satoshi; Yamamoto, Tamiji

    2011-01-01

    Terrigenous loading into enclosed water bodies has been blamed for eutrophic conditions marked by massive algal growth and subsequent hypoxia due to decomposition of dead algal cells. This study aims to describe the eutrophication and hypoxia processes in a semi-enclosed water body lying near a big metropolis. Phosphorus mass balance in a small inlet, Ohko Inlet, located at the head of Hiroshima Bay, Japan, was quantified using a numerical model. Dissolved inorganic phosphorous inflow from Kaita Bay next to the inlet was five times higher than that from terrigenous load, which may cause an enhancement of primary production. Therefore, it was concluded that not only the reduction of material load from the land and the suppression of benthic flux are needed, but also reducing the inflow of high phosphorus and oxygen depleted water from Kaita Bay will form a collective alternative measure to remediate the environmental condition of the inlet. Copyright © 2011 Elsevier Ltd. All rights reserved.

  17. After the Earthquake: Impacts of Seismic Snow and Ice Redistribution in Langtang Valley, Nepal, on Glacier Mass Balances and Hydrological Regimes

    Science.gov (United States)

    Shea, J. M.; Ragettli, S.; Immerzeel, W.; Pellicciotti, F.; Miles, E. S.; Steiner, J. F.; Buri, P.; Kraaijenbrink, P. D. A.

    2015-12-01

    The magnitude 7.8 Gorkha Earthquake that struck Nepal on 25 April 2015 resulted in a catastrophic loss of life and property, and had major impacts in high mountain areas. The earthquake resulted in a number of massive ice avalanches in Langtang Valley that destroyed entire villages and killed over 300 people. We first conduct a remote sensing analysis of the entire catchment, and attempt to quantify the volumes of snow and ice redistributed through high-resolution optical imagery, thermal imagery, and DEM differencing. Where data are available we examine the impact on the surface mass balances of four major glaciers (Lirung, Shalbachaum, Langtang and Langshisha). Finally, we use the physically-based and fully distributed TOPKAPI model to simulate the impacts of the co-seismic snow and ice redistribution on the hydrology of the Langtang River.

  18. Nutrient digestibility and mass balance in laying hens fed a commercial or acidifying diet.

    Science.gov (United States)

    Wu-Haan, W; Powers, W J; Angel, C R; Hale, C E; Applegate, T J

    2007-04-01

    The objectives of the current study were to evaluate the effect of an acidifying diet (gypsum) combined with zeolite and slightly reduced crude protein (R) vs. a control diet (C) on nutrient retention in laying hens and compare 3 approaches to estimating nutrient excretion from hens: 1) mass balance calculation (feed nutrients - egg nutrient), 2) use of an indigestible marker with analyzed feed and excreta nutrient content, and 3) an environmental chamber that allowed for capturing all excreted and volatilized nutrients. Hens (n = 640) were allocated randomly to 8 environmental chambers for 3-wk periods. Excreta samples were collected at the end of each trial to estimate apparent retention of N, S, P, and Ca. No diet effects on apparent retention of N were observed (53.44%, P > 0.05). Apparent retention of S, P, and Ca decreased in hens fed R diet (18.7, - 11.4, and 22.6%, respectively) compared with hens fed the C diet (40.7, 0.3, and 28.6%, respectively; P < 0.05). Total N excretion from hens fed the C and R diet was not different (1.16 g/hen/d); however, mass of chamber N remaining in excreta following the 3-wk period was less from hens fed the C diet (1.27 kg) than from hens fed the R diet (1.43 kg). Gaseous emissions of NH(3) over the 3-wk period from hens fed the C diet (0.74 kg per chamber) were greater than emissions from hens fed the R diet (0.45 kg). The 3-wk S excretion mass (estimated using the calculation, indigestible marker, and environmental chamber methods, respectively) was greater from hens fed the R diet (1.85, 1.54, and 1.27 kg, respectively) compared with hens fed the C diet (0.24, 0.20, and 0.14 kg, respectively). The 3-wk P excretion was similar between diets (0.68 kg). Results demonstrate that feeding the acidified diet resulted in decreased N emissions, but because of the acidulant fed, greatly increased S excretion and emissions.

  19. Pharmacokinetics, tissue distribution and mass balance of radiolabeled dihydroartemisinin in male rats

    Directory of Open Access Journals (Sweden)

    Weina Peter J

    2009-05-01

    Full Text Available Abstract Background Dihydroartemisinin (DHA, a powerful anti-malarial drug, has been used as monotherapy and artemisinin-based combination therapy (ACT for more than decades. So far, however, the tissue distribution and metabolic profile of DHA data are not available from animal and humans. Methods Pharmacokinetics, tissue distribution, mass balance, and elimination of [14C] DHA have been studieded in rats following a single intravenous administration. Protein binding was performed with rat and human plasma. Drug concentrations were obtained up to 192 hr from measurements of total radioactivity and drug concentration to determine the contribution by the parent and metabolites to the total dose of drug injected from whole blood, plasma, urine and faecal samples. Results Drug was widely distributed after 1 hr and rapidly declined at 24 hr in all tissues except spleen until 96 hrs. Only 0.81% of the total radioactivity was detected in rat brain tissue. DHA revealed a high binding capacity with both rat and human plasma proteins (76–82%. The concentration of total radioactivity in the plasma fraction was less than 25% of that in blood total. Metabolism of DHA was observed with high excretion via bile into intestines and approximately 89–95% dose of all conjugations were accounted for in blood, urine and faeces. However, the majority of elimination of [14C] DHA was through urinary excretion (52% dose. The mean terminal half-lives of plasma and blood radioactivity (75.57–122.13 h were significantly prolonged compared with that of unchanged DHA (1.03 h. Conclusion In rat brain, the total concentration of [14C] was 2-fold higher than that in plasma, indicating the radioactivity could easily penetrate the brain-blood barrier. Total radioactivity distributed in RBC was about three- to four-fold higher than that in plasma, suggesting that the powerful anti-malarial potency of DHA in the treatment of blood stage malaria may relate to the high RBC

  20. A mass balance mercury budget for a mine-dominated lake: Clear Lake, California

    Science.gov (United States)

    Suchanek, T.H.; Cooke, J.; Keller, K.; Jorgensen, S.; Richerson, P.J.; Eagles-Smith, Collin A.; Harner, E.J.; Adam, D.P.

    2009-01-01

    The Sulphur Bank Mercury Mine (SBMM), active intermittently from 1873–1957 and now a USEPA Superfund site, was previously estimated to have contributed at least 100 metric tons (105 kg) of mercury (Hg) into the Clear Lake aquatic ecosystem. We have confirmed this minimum estimate. To better quantify the contribution of the mine in relation to other sources of Hg loading into Clear Lake and provide data that might help reduce that loading, we analyzed Inputs and Outputs of Hg to Clear Lake and Storage of Hg in lakebed sediments using a mass balance approach. We evaluated Inputs from (1) wet and dry atmospheric deposition from both global/regional and local sources, (2) watershed tributaries, (3) groundwater inflows, (4) lakebed springs and (5) the mine. Outputs were quantified from (1) efflux (volatilization) of Hg from the lake surface to the atmosphere, (2) municipal and agricultural water diversions, (3) losses from out-flowing drainage of Cache Creek that feeds into the California Central Valley and (4) biotic Hg removal by humans and wildlife. Storage estimates include (1) sediment burial from historic and prehistoric periods (over the past 150–3,000 years) from sediment cores to ca. 2.5m depth dated using dichloro diphenyl dichloroethane (DDD), 210Pb and 14C and (2) recent Hg deposition in surficial sediments. Surficial sediments collected in October 2003 (11 years after mine site remediation) indicate no reduction (but a possible increase) in sediment Hg concentrations over that time and suggest that remediation has not significantly reduced overall Hg loading to the lake. Currently, the mine is believed to contribute ca. 322–331 kg of Hg annually to Clear Lake, which represents ca. 86–99% of the total Hg loading to the lake. We estimate that natural sedimentation would cover the existing contaminated sediments within ca. 150–300 years.

  1. Efficient Characterization of Parametric Uncertainty of Complex (Bio)chemical Networks.

    Science.gov (United States)

    Schillings, Claudia; Sunnåker, Mikael; Stelling, Jörg; Schwab, Christoph

    2015-08-01

    Parametric uncertainty is a particularly challenging and relevant aspect of systems analysis in domains such as systems biology where, both for inference and for assessing prediction uncertainties, it is essential to characterize the system behavior globally in the parameter space. However, current methods based on local approximations or on Monte-Carlo sampling cope only insufficiently with high-dimensional parameter spaces associated with complex network models. Here, we propose an alternative deterministic methodology that relies on sparse polynomial approximations. We propose a deterministic computational interpolation scheme which identifies most significant expansion coefficients adaptively. We present its performance in kinetic model equations from computational systems biology with several hundred parameters and state variables, leading to numerical approximations of the parametric solution on the entire parameter space. The scheme is based on adaptive Smolyak interpolation of the parametric solution at judiciously and adaptively chosen points in parameter space. As Monte-Carlo sampling, it is "non-intrusive" and well-suited for massively parallel implementation, but affords higher convergence rates. This opens up new avenues for large-scale dynamic network analysis by enabling scaling for many applications, including parameter estimation, uncertainty quantification, and systems design.

  2. Glaciological settings and recent mass balance of Blåskimen Island in Dronning Maud Land, Antarctica

    Directory of Open Access Journals (Sweden)

    V. Goel

    2017-12-01

    Full Text Available The ice-shelf-fringed coast of Dronning Maud Land in East Antarctica contains numerous ice rises that influence the dynamics and mass balance of the region. However, only a few of these ice rises have been investigated in detail. Here, we present field measurements of Blåskimen Island, an isle-type ice rise adjacent to Fimbul Ice Shelf. This ice rise is largely dome shaped, with a pronounced ridge extending to the south-west from its summit (410 m a.s.l.. Its bed is mostly flat and about 100 m below the current sea level. Shallow radar-detected isochrones dated with a firn core reveal that the surface mass balance is higher on the south-eastern (upwind slope than on the north-western (downwind slope by ∼ 37 %, and this pattern has persisted for at least the past decade. Moreover, arches in radar stratigraphy suggest that the summit of the ice rise has been stable for ∼ 600 years. Ensemble estimates of the mass balance using the input–output method show that this ice rise has thickened by 0.12–0.37 m ice equivalent per year over the past decade.

  3. Glaciological settings and recent mass balance of Blåskimen Island in Dronning Maud Land, Antarctica

    Science.gov (United States)

    Goel, Vikram; Brown, Joel; Matsuoka, Kenichi

    2017-12-01

    The ice-shelf-fringed coast of Dronning Maud Land in East Antarctica contains numerous ice rises that influence the dynamics and mass balance of the region. However, only a few of these ice rises have been investigated in detail. Here, we present field measurements of Blåskimen Island, an isle-type ice rise adjacent to Fimbul Ice Shelf. This ice rise is largely dome shaped, with a pronounced ridge extending to the south-west from its summit (410 m a.s.l.). Its bed is mostly flat and about 100 m below the current sea level. Shallow radar-detected isochrones dated with a firn core reveal that the surface mass balance is higher on the south-eastern (upwind) slope than on the north-western (downwind) slope by ˜ 37 %, and this pattern has persisted for at least the past decade. Moreover, arches in radar stratigraphy suggest that the summit of the ice rise has been stable for ˜ 600 years. Ensemble estimates of the mass balance using the input-output method show that this ice rise has thickened by 0.12-0.37 m ice equivalent per year over the past decade.

  4. Estimation of air-water gas exchange coefficient in a shallow lagoon based on 222Rn mass balance.

    Science.gov (United States)

    Cockenpot, S; Claude, C; Radakovitch, O

    2015-05-01

    The radon-222 mass balance is now commonly used to quantify water fluxes due to Submarine Groundwater Discharge (SGD) in coastal areas. One of the main loss terms of this mass balance, the radon evasion to the atmosphere, is based on empirical equations. This term is generally estimated using one among the many empirical equations describing the gas transfer velocity as a function of wind speed that have been proposed in the literature. These equations were, however, mainly obtained from areas of deep water and may be less appropriate for shallow areas. Here, we calculate the radon mass balance for a windy shallow coastal lagoon (mean depth of 6m and surface area of 1.55*10(8) m(2)) and use these data to estimate the radon loss to the atmosphere and the corresponding gas transfer velocity. We present new equations, adapted to our shallow water body, to express the gas transfer velocity as a function of wind speed at 10 m height (wind range from 2 to 12.5 m/s). When compared with those from the literature, these equations fit particularly well with the one of Kremer et al. (2003). Finally, we emphasize that some gas transfer exchange may always occur, even for conditions without wind. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. A mass balance approach to investigating geochemical controls on secondary water quality impacts at a crude oil spill site near Bemidji, MN

    Science.gov (United States)

    Ng, Gene-Hua Crystal; Bekins, Barbara A.; Cozzarelli, Isabelle M.; Baedecker, Mary Jo; Bennett, Philip C.; Amos, Richard T.

    2014-01-01

    Secondary water quality impacts can result from a broad range of coupled reactions triggered by primary groundwater contaminants. Data from a crude-oil spill research site near Bemidji, MN provide an ideal test case for investigating the complex interactions controlling secondary impacts, including depleted dissolved oxygen and elevated organic carbon, inorganic carbon, CH4, Mn, Fe, and other dissolved ions. To better understand these secondary impacts, this study began with an extensive data compilation of various data types, comprising aqueous, sediment, gas, and oil phases, covering a 260 m cross-sectional domain over 30 years. Mass balance calculations are used to quantify pathways that control secondary components, by using the data to constrain the sources and sinks for the important redox processes. The results show that oil constituents other than BTEX (benzene, toluene, ethylbenzene, o-, m- and p-xylenes), including n-alkanes and other aromatic compounds, play significant roles in plume evolution and secondary water quality impacts. The analysis underscores previous results on the importance of non-aqueous phases. Over 99.9% of the Fe2+ plume is attenuated by immobilization on sediments as Fe(II) and 85–95% of the carbon biodegradation products are outgassed. Gaps identified in carbon and Fe mass balances and in pH buffering mechanisms are used to formulate a new conceptual model. This new model includes direct out-gassing of CH4 and CO2 from organic carbon biodegradation, dissolution of directly produced CO2, and sorption with H+ exchange to improve pH buffering. The identification of these mechanisms extends understanding of natural attenuation of potential secondary impacts at enhanced reductive dechlorination sites, particularly for reduced Fe plumes, produced CH4, and pH perturbations.

  6. Physico-chemical and Bio-chemical Controls on Soil C Saturation Behavior

    Energy Technology Data Exchange (ETDEWEB)

    Six, Johan [Univ. of California, Davis, CA (United States); Plante, Alain F. [Univ. of Pennsylvania, Philadelphia, PA (United States)

    2011-05-31

    In this project, we tested through a multitude of lab and field experiments the concept of soil C stabilization and determined metrics for the level of C saturation across soils and soil organic matter fractions. The basic premise of the soil C saturation concept is that there is a maximum amount of C that can be stabilized within a soil, even when C input is further increased. In a first analysis, our results showed that linear regression models do not adequately predict maximal organic C stabilization by fine soil particles. Soil physical and chemical properties associated with soil clay mineralogy, such as specific surface area and organic C loading, should be incorporated into models for predicting maximal organic C stabilization. In a second analysis, we found significantly greater maximal C stabilization in the microaggregate-protected versus the non-microaggregate protected mineral fractions, which provides independent validation that microaggregation plays an important role in increasing the protection and stabilization of soil C leading to greater total soil C accumulation in these pools. In a third study, our results question the role of biochemical preference in mineral C stabilization and of the chemical recalcitrance of specific plant-derived compounds in non-protected soil C accumulation. Because C biochemical composition of slowly turning over mineral protected C pools does not change with C saturation, input C composition is unlikely to affect long-term C stabilization. Rather, C saturation and stabilization in soil is controlled only by the quantity of C input to the soil and the physical and chemical protection mechanisms at play in long-term C stabilization. In conclusion, we have further corroborated the concept of soil C saturation and elucidated several mechanisms underlying this soil C saturation.

  7. Earthworms and nutrient availability: the ecosystem engineer as (bio)chemical engineer

    Science.gov (United States)

    van Groenigen, Jan Willem; Ros, Mart; Vos, Hannah; De Deyn, Gerlinde; Hiemstra, Tjisse; Oenema, Oene; Koopmans, Gerwin

    2017-04-01

    The ability of earthworms to increase plant production has long been recognized. However, the pathways through which they do so, and the magnitude of this effect, have not been conclusively addressed. In two studies we address these issues for nitrogen (N) and phosphorus (P) availability to plants. In the first study, a meta-analysis, we concluded that earthworm presence increases crop yield on average with 26% and aboveground biomass with 24%. The positive effects of earthworms increase when more residue is returned to the soil, but disappear when soil N availability is high. This suggests that earthworms stimulate plant growth predominantly through N mineralization from soil organic matter or crop residue. In a second study, we tested the effect of earthworms on plant P uptake from inorganic sources. In a greenhouse experiment on a soil with low P availability we showed that presence of the anecic earthworm Lumbricus terrestris resulted in increased aboveground biomass (from 164 to 188 g dry matter m-2) and P uptake (from 0.21 to 0.27 g m-2). Concentrations of total dissolved P and dissolved inorganic P in water extractions of earthworm casts were 7-9 times higher than in those of bulk soil. Using advanced surface complexation modelling, we showed that these effects were primarily related to desorption of inorganic P due to competition with organic carbon for binding sites. We conclude that earthworms can alter nutrient cycling and increase N and P uptake by plants through a combination of biochemical and chemical pathways. Earthworms are most likely to stimulate N uptake in organic farming systems and tropical subsistence farming, which largely rely on nutrient mineralization. Additional benefits of earthworms might be expected in conventional farming systems with low levels of available P.

  8. Seasonal changes in surface albedo of Himalayan glaciers from MODIS data and links with the annual mass balance

    Directory of Open Access Journals (Sweden)

    F. Brun

    2015-02-01

    Full Text Available Few glaciological field data are available on glaciers in the Hindu Kush–Karakoram–Himalayan (HKH region, and remote sensing data are thus critical for glacier studies in this region. The main objectives of this study are to document, using satellite images, the seasonal changes of surface albedo for two Himalayan glaciers, Chhota Shigri Glacier (Himachal Pradesh, India and Mera Glacier (Everest region, Nepal, and to reconstruct the annual mass balance of these glaciers based on the albedo data. Albedo is retrieved from Moderate Resolution Imaging Spectroradiometer (MODIS images, and evaluated using ground based measurements. At both sites, we find high coefficients of determination between annual minimum albedo averaged over the glacier (AMAAG and glacier-wide annual mass balance (Ba measured with the glaciological method (R2 = 0.75. At Chhota Shigri Glacier, the relation between AMAAG found at the end of the ablation season and Ba suggests that AMAAG can be used as a proxy for the maximum snow line altitude or equilibrium line altitude (ELA on winter-accumulation-type glaciers in the Himalayas. However, for the summer-accumulation-type Mera Glacier, our approach relied on the hypothesis that ELA information is preserved during the monsoon. At Mera Glacier, cloud obscuration and snow accumulation limits the detection of albedo during the monsoon, but snow redistribution and sublimation in the post-monsoon period allows for the calculation of AMAAG. Reconstructed Ba at Chhota Shigri Glacier agrees with mass balances previously reconstructed using a positive degree-day method. Reconstructed Ba at Mera Glacier is affected by heavy cloud cover during the monsoon, which systematically limited our ability to observe AMAAG at the end of the melting period. In addition, the relation between AMAAG and Ba is constrained over a shorter time period for Mera Glacier (6 years than for Chhota Shigri Glacier (11 years. Thus the mass balance reconstruction

  9. The Mass Balance of Glacier No. 1 at the Headwaters of the Urumqi River in Relation to Northern Hemisphere Teleconnection Patterns

    Directory of Open Access Journals (Sweden)

    Feifei Yuan

    2016-03-01

    Full Text Available Most small glaciers in the world have significantly decreased their volume during the last century, which has caused water shortage problems. Glacier No. 1, at the headwaters of the Urumqi River, Tianshan, China, has been monitored since 1959 and similarly has experienced significant mass and volume losses over the last few decades. Thus, we examined the trend and potential abrupt changes of the mass balance of Glacier No. 1. Principal component analysis and singular value decomposition were used to find significant relations between the mass balance of Glacier No. 1 and Northern Hemisphere teleconnection patterns using climate indices. It was found that the mass balance of Glacier No. 1 had a significantly decreasing trend corresponding to −14.5 mm/year from 1959 to 2010. A change point was detected in 1997 with 99% confidence level. Two time periods with different mass balances were identified as 1959–1996 and 1997–2010. The mass balance for the first period was −136.4 mm/year and up to −663.9 mm/year for the second period. The mass balance of Glacier No. 1 is positively related to the Scandinavian Pattern (SCA, and negatively related to the East Atlantic Pattern (EA. These relationships are useful in better understanding the interaction between glacier mass balance and climate variability.

  10. Lithophile Trace Element Mass Balance in Spinel Lherzolites from Borée, Massif Central, France: the Effects of Melt Impregnation on Variably Depleted Peridotites

    Science.gov (United States)

    Barnett, C. J.; Harvey, J.; Morgan, D. J.; Hammond, S.; Walshaw, R.

    2014-12-01

    Isotopic and elemental investigations of peridotite xenoliths can be used to model the timing and degree of melt extraction in the mantle. However, the primary melt depletion signature preserved in these xenoliths can be overprinted by subsequent metasomatism and melt-rock interactions, which tend to obscure the degree of original melt depletion either through the crystallisation of secondary phases or through the pervasive addition of lithophile element-rich basalt or its derivatives. Anhydrous spinel lherzolite xenoliths from the volcanic Maar de Borée in the French Massif Central have textures that vary from equigranular to protogranular. There is clear evidence of melt infiltration of up to several modal per cent in an anastomosing network of veins and stringers. Bulk-rock major elements and compatible trace element concentrations suggest that the Borée peridotites are genetically related by differing degrees of melt extraction, but the influence of melt infiltration, clearly visible at the thin section scale, and likely comprising several modal percent of the rock, makes this melt depletion difficult to quantify accurately. Some incompatible trace element concentrations in clinopyroxenes are consistent with melt depletion, while elevated (La/Yb)Nratios in others are clearly indicative of cryptic metasomatism and suggest yet another style of metasomatism. Furthermore, infiltrated melt along grain boundaries and in interstitial pockets disturbs the incompatible element mass balance, further obscuring the true nature of the prior melt depletion event(s). Quantitative lithophile element mass balance calculations will allow the effects of melt infiltration to be determined and stripped away from bulk-rock xenolith compositions, permitting a more realistic appraisal of the original melt depletion event.

  11. Carbon dioxide degassing at the groundwater-stream-atmosphere interface: isotopic equilibration and hydrological mass balance in a sandy watershed

    Science.gov (United States)

    Deirmendjian, Loris; Abril, Gwenaël

    2018-03-01

    Streams and rivers emit significant amounts of CO2 and constitute a preferential pathway of carbon transport from terrestrial ecosystems to the atmosphere. However, the estimation of CO2 degassing based on the water-air CO2 gradient, gas transfer velocity and stream surface area is subject to large uncertainties. Furthermore, the stable isotope signature of dissolved inorganic carbon (δ13C-DIC) in streams is strongly impacted by gas exchange, which makes it a useful tracer of CO2 degassing under specific conditions. For this study, we characterized the annual transfers of dissolved inorganic carbon (DIC) along the groundwater-stream-river continuum based on DIC concentrations, stable isotope composition and measurements of stream discharges. We selected a homogeneous, forested and sandy lowland watershed as a study site, where the hydrology occurs almost exclusively through drainage of shallow groundwater (no surface runoff). We observed the first general spatial pattern of decreases in pCO2 and DIC and an increase in δ13C-DIC from groundwater to stream orders 1 and 2, which was due to the experimentally verified faster degassing of groundwater 12C-DIC compared to 13C-DIC. This downstream enrichment in 13C-DIC could be modelled by simply considering the isotopic equilibration of groundwater-derived DIC with the atmosphere during CO2 degassing. A second spatial pattern occurred between stream orders 2 and 4, consisting of an increase in the proportion of carbonate alkalinity to the DIC accompanied by the enrichment of 13C in the stream DIC, which was due to the occurrence of carbonate rock weathering downstream. We could separate the contribution of these two processes (gas exchange and carbonate weathering) in the stable isotope budget of the river network. Thereafter, we built a hydrological mass balance based on drainages and the relative contribution of groundwater in streams of increasing order. After combining with the dissolved CO2 concentrations, we

  12. Imaging spectroscopy to assess the composition of ice surface materials and their impact on glacier mass balance

    Science.gov (United States)

    Naegeli, Kathrin; Huss, Matthias; Damm, Alexander; de Jong, Rogier; Schaepman, Michael; Hoelzle, Martin

    2014-05-01

    The ice-albedo feedback plays a crucial role in various glaciological processes, but especially influences ice melt. Glacier surface albedo is one of the most important variables in the energy balance of snow and ice, but depends in a complicated way on many factors, such as cryoconite concentration, impurities due to mineral dust, soot or organic matter, grain size or ice surface morphology. Our understanding on how these various factors influence glacier albedo is still limited hindering a spatially and temporally explicit parameterization of energy balance models and requiring strongly simplified assumptions on actual albedo values. Over the last two decades, several studies have focused on glacier surface albedo using automatic in-situ weather stations in combination with radiation measurement setups or satellite images. Due to limitations of both approaches in matching either the spatial or the temporal length scale of glacier albedo, still fairly little is known about the state, changes and impact of glacier surface albedo in the Swiss Alps, although there are obvious changes in surface characteristics on most alpine glaciers over the last years. With use of the APEX (Airborne Prism EXperiment) image spectrometer, measurements of reflected radiation were acquired in high spatial and spectral resolution on Glacier de la Plaine Morte, Switzerland, to explicitly analyse the ice surface. In-situ radiometric measurements were acquired with an ASD field spectrometer in parallel to APEX overflights. These data are intended to be used for validation purposes as well as input data for the linear spectral unmixing analysis of the APEX data. Seasonal glacier mass balance is monitored since five years using the direct glaciological method. This contribution presents a first evaluation of the data collected in summer 2013. The obtained in-situ and airborne reflectance measurements were used in combination with a spectral mixture analysis (SMA) approach to assess the

  13. A newly isolated Bacillus licheniformis strain thermophilically produces 2,3-butanediol, a platform and fuel bio-chemical.

    Science.gov (United States)

    Li, Lixiang; Zhang, Lijie; Li, Kun; Wang, Yu; Gao, Chao; Han, Binbin; Ma, Cuiqing; Xu, Ping

    2013-08-28

    2,3-Butanediol (2,3-BD), a platform and fuel bio-chemical, can be efficiently produced by Klebsiella pneumonia, K. oxytoca, and Serratia marcescens. However, these strains are opportunistic pathogens and not favorable for industrial application. Although some generally regarded as safe (GRAS) microorganisms have been isolated in recent years, there is still a demand for safe 2,3-BD producing strains with high productivity and yield under thermophilic fermentation. Bacillus licheniformis strain 10-1-A was newly isolated for 2,3-BD production. The optimum temperature and medium pH were 50°C and pH 7.0 for 2,3-BD production by strain 10-1-A. The medium composition was optimized through Plackett-Burman design and response surface methodology techniques. With a two-stage agitation speed control strategy, 115.7 g/L of 2,3-BD was obtained from glucose by fed-batch fermentation in a 5-L bioreactor with a high productivity (2.4 g/L·h) and yield (94% of its theoretical value). The 2,3-BD produced by strain 10-1-A comprises (2R,3R)-2,3-BD and meso-2,3-BD with a ratio of nearly 1:1. The bdh and gdh genes encoding meso-2,3-butanediol dehydrogenase (meso-BDH) and glycerol dehydrogenase (GDH) of strain 10-1-A were expressed in Escherichia coli and the proteins were purified. meso-2,3-BD and (2R,3R)-2,3-BD were transformed from racemic acetoin by meso-BDH and GDH with NADH, respectively. Compared with the reported GRAS 2,3-BD producers, B. licheniformis 10-1-A could thermophilically produce 2,3-BD with a high concentration, productivity and yield. Thus, the newly isolated GRAS strain 10-1-A might be a promising strain for industrial production of 2,3-BD. Two key enzymes for meso-2,3-BD and (2R,3R)-2,3-BD production were purified and further studied, and this might be helpful to understand the mechanism for 2,3-BD stereoisomers forming in B. licheniformis.

  14. Systematic metabolic engineering of Escherichia coli for high-yield production of fuel bio-chemical 2,3-butanediol.

    Science.gov (United States)

    Xu, Youqiang; Chu, Haipei; Gao, Chao; Tao, Fei; Zhou, Zikang; Li, Kun; Li, Lixiang; Ma, Cuiqing; Xu, Ping

    2014-05-01

    The production of biofuels by recombinant Escherichia coli is restricted by the toxicity of the products. 2,3-Butanediol (2,3-BD), a platform and fuel bio-chemical with low toxicity to microbes, could be a promising alternative for biofuel production. However, the yield and productivity of 2,3-BD produced by recombinant E. coli strains are not sufficient for industrial scale fermentation. In this work, the production of 2,3-BD by recombinant E. coli strains was optimized by applying a systematic approach. 2,3-BD biosynthesis gene clusters were cloned from several native 2,3-BD producers, including Bacillus subtilis, Bacillus licheniformis, Klebsiella pneumoniae, Serratia marcescens, and Enterobacter cloacae, inserted into the expression vector pET28a, and compared for 2,3-BD synthesis. The recombinant strain E. coli BL21/pETPT7-EcABC, carrying the 2,3-BD pathway gene cluster from Enterobacter cloacae, showed the best ability to synthesize 2,3-BD. Thereafter, expression of the most efficient gene cluster was optimized by using different promoters, including PT7, Ptac, Pc, and Pabc. E. coli BL21/pET-RABC with Pabc as promoter was superior in 2,3-BD synthesis. On the basis of the results of biomass and extracellular metabolite profiling analyses, fermentation conditions, including pH, agitation speed, and aeration rate, were optimized for the efficient production of 2,3-BD. After fed-batch fermentation under the optimized conditions, 73.8g/L of 2,3-BD was produced by using E. coli BL21/pET-RABC within 62h. The values of both yield and productivity of 2,3-BD obtained with the optimized biological system are the highest ever achieved with an engineered E. coli strain. In addition to the 2,3-BD production, the systematic approach might also be used in the production of other important chemicals through recombinant E. coli strains. Copyright © 2014 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved.

  15. Development of a new certified reference material of diosgenin using mass balance approach and Coulometric titration method.

    Science.gov (United States)

    Gong, Ningbo; Zhang, Baoxi; Hu, Fan; Du, Hui; Du, Guanhua; Gao, Zhaolin; Lu, Yang

    2014-12-01

    Certified reference materials (CRMs) can be used as a valuable tool to validate the trueness of measurement methods and to establish metrological traceability of analytical results. Diosgenin has been selected as a candidate reference material. Characterization of the material relied on two different methods, mass balance method and Coulometric titration method (CT). The certified value of diosgenin CRM is 99.80% with an expanded uncertainty of 0.37% (k=2). The new CRM of diosgenin can be used to validate analytical methods, improve the accuracy of measurement data and control the quality of diosgenin in relevant pharmaceutical formulations. Copyright © 2014 Elsevier Inc. All rights reserved.

  16. The Suitability and the Bio-chemical Characteristics of Soils from the Northwest Region of Development from Romania, for Blueberry Crop

    Directory of Open Access Journals (Sweden)

    Amalia Ioana BOȚ

    2017-11-01

    Full Text Available We conducted several bio-chemical analyses on soil samples collected from eight blueberry plantations from Northwest Region of Development, using such as Kjeldahl method for total N, Perucci, Krawczyński, Hoffman and Teicher methodology for determine soil enzyme. The bio-chemical analyses conducted provide a better qualitative characterization of soils, providing significant information regarding their fertility degree and favourability for blueberries. For instance, the higher amount of total organic carbon found in four of the eight studied plantation, can be correlated with the same higher amount of enzyme present in soil which have an influence on them, xanthine oxidase and peroxidase activity. Taking into account the requirements needed for a blueberry plantation, we demonstrate that organic soils have also had the highest amount of bio-chemical compounds, such as cambisoil, met in Galații Bistriței, where were also found the highest amounts of different forms of nitrogen (1.755 g/kg total N; 0.0189 g/kg NH4 + and 0.0231g/kg NO3 in Galații Bistriței, comparing to 1.344 g/kg of total nitrogen; 0.0126 g/kg NH4+ and 0.0119 g/kg NO3- in Ulmeni, different forms of carbon and the enzymes that influence this compounds in soil, xanthine oxidase activity, peroxidase activity and nitrate reductase activity.

  17. Barrow real-time sea ice mass balance data: ingestion, processing, dissemination and archival of multi-sensor data

    Science.gov (United States)

    Grimes, J.; Mahoney, A. R.; Heinrichs, T. A.; Eicken, H.

    2012-12-01

    Sensor data can be highly variable in nature and also varied depending on the physical quantity being observed, sensor hardware and sampling parameters. The sea ice mass balance site (MBS) operated in Barrow by the University of Alaska Fairbanks (http://seaice.alaska.edu/gi/observatories/barrow_sealevel) is a multisensor platform consisting of a thermistor string, air and water temperature sensors, acoustic altimeters above and below the ice and a humidity sensor. Each sensor has a unique specification and configuration. The data from multiple sensors are combined to generate sea ice data products. For example, ice thickness is calculated from the positions of the upper and lower ice surfaces, which are determined using data from downward-looking and upward-looking acoustic altimeters above and below the ice, respectively. As a data clearinghouse, the Geographic Information Network of Alaska (GINA) processes real time data from many sources, including the Barrow MBS. Doing so requires a system that is easy to use, yet also offers the flexibility to handle data from multisensor observing platforms. In the case of the Barrow MBS, the metadata system needs to accommodate the addition of new and retirement of old sensors from year to year as well as instrument configuration changes caused by, for example, spring melt or inquisitive polar bears. We also require ease of use for both administrators and end users. Here we present the data and processing steps of using sensor data system powered by the NoSQL storage engine, MongoDB. The system has been developed to ingest, process, disseminate and archive data from the Barrow MBS. Storing sensor data in a generalized format, from many different sources, is a challenging task, especially for traditional SQL databases with a set schema. MongoDB is a NoSQL (not only SQL) database that does not require a fixed schema. There are several advantages using this model over the traditional relational database management system (RDBMS

  18. Electrode Mass Balancing as an Inexpensive and Simple Method to Increase the Capacitance of Electric Double-Layer Capacitors.

    Science.gov (United States)

    Andres, Britta; Engström, Ann-Christine; Blomquist, Nicklas; Forsberg, Sven; Dahlström, Christina; Olin, Håkan

    Symmetric electric double-layer capacitors (EDLCs) have equal masses of the same active material in both electrodes. However, having equal electrode masses may prevent the EDLC to have the largest possible specific capacitance if the sizes of the hydrated anions and cations in the electrolyte differ because the electrodes and the electrolyte may not be completely utilized. Here we demonstrate how this issue can be resolved by mass balancing. If the electrode masses are adjusted according to the size of the ions, one can easily increase an EDLC's specific capacitance. To that end, we performed galvanostatic cycling to measure the capacitances of symmetric EDLCs with different electrode mass ratios using four aqueous electrolytes- Na2SO4, H2SO4, NaOH, and KOH (all with a concentration of 1 M)-and compared these to the theoretical optimal electrode mass ratio that we calculated using the sizes of the hydrated ions. Both the theoretical and experimental values revealed lower-than-1 optimal electrode ratios for all electrolytes except KOH. The largest increase in capacitance was obtained for EDLCs with NaOH as electrolyte. Specifically, we demonstrate an increase of the specific capacitance by 8.6% by adjusting the electrode mass ratio from 1 to 0.86. Our findings demonstrate that electrode mass balancing is a simple and inexpensive method to increase the capacitance of EDLCs. Furthermore, our results imply that one can reduce the amount of unused material in EDLCs and thus decrease their weight, volume and cost.

  19. A mass balance approach to the fate of viruses in a municipal wastewater treatment plant during summer and winter seasons.

    Science.gov (United States)

    Ulbricht, Katharina; Selinka, Hans-Christoph; Wolter, Stefanie; Rosenwinkel, Karl-Heinz; Nogueira, Regina

    2014-01-01

    In contrast to previous discussion on general virus removal efficiency and identifying surrogates for human pathogenic viruses, this study focuses on virus retention within each step of a wastewater treatment plant (WWTP). Additionally, the influence of weather conditions on virus removal was addressed. To account for the virus retention, this study describes a mass balance of somatic coliphages (bacterial viruses) in a municipal WWTP, performed in the winter and summer seasons of 2011. In the winter season, the concentration of coliphages entering the WWTP was about 1 log lower than in summer. The mass balance in winter revealed a virus inactivation of 85.12 ± 13.97%. During the summer season, virus inactivation was significantly higher (95.25 ± 3.69%, p-value virus removal in the secondary clarifier by insolation. Thus, a total removal of coliphages of about 2.78 log units was obtained in summer compared to 1.95 log units in winter. Rainfall events did not statistically correlate with the concentrations of coliphages entering the WWTP in summer.

  20. Mass balance and sliding velocity of the Puget lobe of the cordilleran ice sheet during the last glaciation

    Science.gov (United States)

    Booth, D.B.

    1986-01-01

    An estimate of the sliding velocity and basal meltwater discharge of the Puget lobe of the Cordilleran ice sheet can be calculated from its reconstructed extent, altitude, and mass balance. Lobe dimensions and surface altitudes are inferred from ice limits and flow-direction indicators. Net annual mass balance and total ablation are calculated from relations empirically derived from modern maritime glaciers. An equilibrium-line altitude between 1200 and 1250 m is calculated for the maximum glacial advance (ca. 15,000 yr B.P.) during the Vashon Stade of the Fraser Glaciation. This estimate is in accord with geologic data and is insensitive to plausible variability in the parameters used in the reconstruction. Resultant sliding velocities are as much as 650 m/a at the equilibrium line, decreasing both up- and downglacier. Such velocities for an ice sheet of this size are consistent with nonsurging behavior. Average meltwater discharge increases monotonically downglacier to 3000 m3/sec at the terminus and is of a comparable magnitude to ice discharge over much of the glacier's ablation area. Palcoclimatic inferences derived from this reconstruction are consistent with previous, independently derived studies of late Pleistocene temperature and precipitation in the Pacific Northwest. ?? 1986.

  1. Data requirements for using combined conductivity mass balance and recursive digital filter method to estimate groundwater recharge in a small watershed, New Brunswick, Canada

    Science.gov (United States)

    Li, Qiang; Xing, Zisheng; Danielescu, Serban; Li, Sheng; Jiang, Yefang; Meng, Fan-Rui

    2014-04-01

    Estimation of baseflow and groundwater recharge rates is important for hydrological analysis and modelling. A new approach which combines recursive digital filter (RDF) model with conductivity mass balance (CMB) method was considered to be reliable for baseflow separation because the combined method takes advantages of the reduced data requirement for RDF method and the reliability of CMB method. However, it is not clear what the minimum data requirements for producing acceptable estimates of the RDF model parameters are. In this study, 19-year record of stream discharge and water conductivity collected from the Black Brook Watershed (BBW), NB, Canada were used to test the combined baseflow separation method and assess the variability of parameters in the model over seasons. The data requirements and potential bias in estimated baseflow index (BFI) were evaluated using conductivity data for different seasons and/or resampled data segments at various sampling durations. Results indicated that the data collected during ground-frozen season are more suitable to estimate baseflow conductivity (Cbf) and data during snow-melting period are more suitable to estimate runoff conductivity (Cro). Relative errors of baseflow estimation were inversely proportional to the number of conductivity data records. A minimum of six-month discharge and conductivity data is required to obtain reliable parameters for current method with acceptable errors. We further found that the average annual recharge rate for the BBW was 322 mm in the past twenty years.

  2. A daily, 1 km resolution data set of downscaled Greenland ice sheet surface mass balance (1958–2015

    Directory of Open Access Journals (Sweden)

    B. Noël

    2016-10-01

    Full Text Available This study presents a data set of daily, 1 km resolution Greenland ice sheet (GrIS surface mass balance (SMB covering the period 1958–2015. Applying corrections for elevation, bare ice albedo and accumulation bias, the high-resolution product is statistically downscaled from the native daily output of the polar regional climate model RACMO2.3 at 11 km. The data set includes all individual SMB components projected to a down-sampled version of the Greenland Ice Mapping Project (GIMP digital elevation model and ice mask. The 1 km mask better resolves narrow ablation zones, valley glaciers, fjords and disconnected ice caps. Relative to the 11 km product, the more detailed representation of isolated glaciated areas leads to increased precipitation over the southeastern GrIS. In addition, the downscaled product shows a significant increase in runoff owing to better resolved low-lying marginal glaciated regions. The combined corrections for elevation and bare ice albedo markedly improve model agreement with a newly compiled data set of ablation measurements.

  3. Assessing the optimized precision of the aircraft mass balance method for measurement of urban greenhouse gas emission rates through averaging

    Directory of Open Access Journals (Sweden)

    Alexie M. F. Heimburger

    2017-06-01

    Full Text Available To effectively address climate change, aggressive mitigation policies need to be implemented to reduce greenhouse gas emissions. Anthropogenic carbon emissions are mostly generated from urban environments, where human activities are spatially concentrated. Improvements in uncertainty determinations and precision of measurement techniques are critical to permit accurate and precise tracking of emissions changes relative to the reduction targets. As part of the INFLUX project, we quantified carbon dioxide (CO2, carbon monoxide (CO and methane (CH4 emission rates for the city of Indianapolis by averaging results from nine aircraft-based mass balance experiments performed in November-December 2014. Our goal was to assess the achievable precision of the aircraft-based mass balance method through averaging, assuming constant CO2, CH4 and CO emissions during a three-week field campaign in late fall. The averaging method leads to an emission rate of 14,600 mol/s for CO2, assumed to be largely fossil-derived for this period of the year, and 108 mol/s for CO. The relative standard error of the mean is 17% and 16%, for CO2 and CO, respectively, at the 95% confidence level (CL, i.e. a more than 2-fold improvement from the previous estimate of ~40% for single-flight measurements for Indianapolis. For CH4, the averaged emission rate is 67 mol/s, while the standard error of the mean at 95% CL is large, i.e. ±60%. Given the results for CO2 and CO for the same flight data, we conclude that this much larger scatter in the observed CH4 emission rate is most likely due to variability of CH4 emissions, suggesting that the assumption of constant daily emissions is not correct for CH4 sources. This work shows that repeated measurements using aircraft-based mass balance methods can yield sufficient precision of the mean to inform emissions reduction efforts by detecting changes over time in urban emissions.

  4. Basin-Wide Mass Balance of Jakobshavn Isbræ (West Greenland) during 1880-2100

    DEFF Research Database (Denmark)

    Muresan, Ioana Stefania; Khan, Shfaqat Abbas; Aschwanden, Andy

    the contribution between 1997 to 2014 represents 27 %. By the end of the century contributions to SLR as high as ~11 mm (~4000 Gt under RCP 8.5 and almost 300% increase relative to 1880-2014) can be expected from Jakobshavn Isbræ only. Our choice of ice sheet model comprises the Parallel Ice Sheet Model (PISM)....

  5. Troughs on Martian Ice Sheets: Analysis of Their Closure and Mass Balance

    Science.gov (United States)

    Fountain, A.; Kargel, J.; Lewis, K.; MacAyeal, D.; Pfeffer, T.; Zwally, J.

    2000-01-01

    At the Copenhagen workshop on Martian polar processes, Ralf Greve commented that the flow regime surrounding scarps and troughs of the Martian polar ice sheets cannot be modeled using traditional "plan view" ice-sheet models. Such models are inadequate because they typically use reduced equations that embody certain simplifications applicable only to terrestrial ice sheets where the upper ice sheet surface is smooth. In response to this suggestion, we have constructed a 2-dimensional, time dependent "side view" (two spatial dimensions: one horizontal, one vertical) model of scarp closure that is designed to overcome the difficulties described by Greve. The purpose of the model is to evaluate the scales of stress variation and styles of flow closure so as to estimate errors that may be encountered by "plan view" models. We show that there may be avenues whereby the complications associated with scarp closure can be overcome in "plan view" models through appropriate parameterizations of 3-dimensional effects. Following this, we apply the flow model to simulate the evolution of a typical scarp on the North Polar Cap of Mars. Our simulations investigate: (a) the role of "radiation trapping" (see our companion abstract) in creating and maintaining "spiral-like" scarps on the ice sheet, (b) the consequences of different flowlaws and ice compositions on scarp evolution and, in particular, scarp age, and (c) the role of dust and debris in scarp evolution.

  6. Greenland Ice Sheet Mass Balance Reconstruction. Part I: Net Snow Accumulation (1600–2009)

    NARCIS (Netherlands)

    Box, J.E.; Cressie, N.; Bromwich, D.H.; Jung, J.-H.; van den Broeke, M.R.|info:eu-repo/dai/nl/073765643; van Angelen, J.H.|info:eu-repo/dai/nl/325922470; Forster, R.R.; Miège, C.; Mosley-Thompson, E.; Vinther, B.; McConnell, J.R.

    2013-01-01

    Ice core data are combined with Regional Atmospheric Climate Model version 2 (RACMO2) output (1958–2010) to develop a reconstruction of Greenland ice sheet net snow accumulation rate, ^At(G), spanning the years 1600–2009. Regression parameters from regional climate model (RCM) output regressed on 86

  7. Contents and mass balances of cadmium and arsenic in a wastewater-fed fish pond of Hoang Mai, Hanoi, Vietnam.

    Science.gov (United States)

    Marcussen, Helle; Ha, Le Thai; Polprasert, Chongrak; Holm, Peter E

    2012-01-01

    Wastewater-fed aquatic production has been practiced since the 1960s in peri-urban Hanoi. Wastewater is used as a cheap and reliable source of both water and nutrients but there is a risk that it may lead to accumulation of potentially toxic elements (PTEs) in the production systems and produce and thereby constitute a food safety risk. This study investigates the cadmium (Cd) and arsenic (As) concentrations in water, sediment, plant and fish of a wastewater fed-fish pond in Hoang Mai district, Hanoi, Vietnam. Cd concentrations in the water were lower than the Vietnamese quality guidelines (0.8-1.8 μg Cd/L) for protection of aquatic life but As concentrations in inlet and outlet water of 44.3 and 21.3 μg/L, respectively both were higher that the guidelines (20 μg As/L) and may cause toxicity to fish in the pond and the surrounding vegetable farms using the outlet water for irrigation. The concentrations of Cd and As in fish and Cd in water spinach did not constitute a food safety risk. However, As concentrations in water spinach may be of concern. A mass balance estimate for the fish pond showed that about 12% of the incoming As accumulate in suspended particular matters, 40% settle down to the sediment, less than 0.1% accumulate in the fish and water spinach and 48% overflow with the pond effluent. The concentrations of Cd were too low to make a mass balance for the fish pond.

  8. Satellite-derived submarine melt rates and mass balance (2011-2015) for Greenland's largest remaining ice tongues

    Science.gov (United States)

    Wilson, Nat; Straneo, Fiammetta; Heimbach, Patrick

    2017-12-01

    Ice-shelf-like floating extensions at the termini of Greenland glaciers are undergoing rapid changes with potential implications for the stability of upstream glaciers and the ice sheet as a whole. While submarine melting is recognized as a major contributor to mass loss, the spatial distribution of submarine melting and its contribution to the total mass balance of these floating extensions is incompletely known and understood. Here, we use high-resolution WorldView satellite imagery collected between 2011 and 2015 to infer the magnitude and spatial variability of melt rates under Greenland's largest remaining ice tongues - Nioghalvfjerdsbræ (79 North Glacier, 79N), Ryder Glacier (RG), and Petermann Glacier (PG). Submarine melt rates under the ice tongues vary considerably, exceeding 50 m a-1 near the grounding zone and decaying rapidly downstream. Channels, likely originating from upstream subglacial channels, give rise to large melt variations across the ice tongues. We compare the total melt rates to the influx of ice to the ice tongue to assess their contribution to the current mass balance. At Petermann Glacier and Ryder Glacier, we find that the combined submarine and aerial melt approximately balances the ice flux from the grounded ice sheet. At Nioghalvfjerdsbræ the total melt flux (14.2 ± 0.96 km3 a-1 w.e., water equivalent) exceeds the inflow of ice (10.2 ± 0.59 km3 a-1 w.e.), indicating present thinning of the ice tongue.

  9. Cross check of the new economic and mass balance feature of the fuel cycle scenario code TR-EVOL

    International Nuclear Information System (INIS)

    Merino-Rodriguez, I.; Garcia-Martinez, M.; Alvarez-Velarde, F.; Lopez, D.

    2016-01-01

    Versatile computational tools with up to date capabilities are needed to assess current nuclear fuel cycles or the transition from the current status of the fuel cycle to the more advanced and sustainable ones. The TR-EVOL module, that is devoted to fuel cycle mass balance, simulates diverse nuclear power plants (PWR, SFR, ADS, etc.), having possibly different types of fuels (UO 2 , MOX, etc.), and the associated fuel cycle facilities (enrichment, fuel fabrication, processing, interim storage, waste storage, geological disposal). This work is intended to cross check the new capabilities of the fuel cycle scenario code TR-EVOL.This process has been divided in 2 stages. The first stage is dedicated to check the improvements in the nuclear fuel mass balance estimation using the available data for the Spanish nuclear fuel cycle. The second stage has been focused in verifying the validity of the TR-EVOL economic module, comparing results to data published by the ARCAS EU project. A specific analysis was required to evaluate the back-end cost. Data published by the waste management responsible institutions was used for the validation of the methodology. Results were highly satisfactory for both stages. In particular, the economic assessment provides a difference smaller than 3% regarding results published by the ARCAS project (NRG estimations). Furthermore, concerning the back-end cost, results are highly acceptable (7% difference for a final disposal in a once-through scenario and around 11% for a final disposal in a reprocessing strategy) given the significant uncertainties involved in design concepts and related unit costs. (authors)

  10. Boundary-layer isotope dilution/mass balance methods for measurement of nocturnal methane emissions from grazing sheep

    Science.gov (United States)

    Harvey, M. J.; Brailsford, G. W.; Bromley, A. M.; Lassey, K. R.; Mei, Z.; Kristament, I. S.; Reisinger, A. R.; Walker, C. F.; Kelliher, F. M.

    Following advances with methods for 13C/ 12C isotopic analysis of methane in small (⩽4 L) air samples, new isotope dilution techniques are proposed for measurement of methane emissions at the paddock scale from grazing ruminant animals. These techniques combine measurement of the isotopic δ13CH 4 composition of air samples with a non-intrusive mass balance method applied in the nocturnal boundary layer. Flux estimates from trials using the isotope dilution techniques are compared with estimates based on scaling up individual animal emission measurements using a rumen gas tracer technique. The methane flux assessed by the latter technique ranged from 35 to 70 mg (CH 4) m -2 d -1 with a stocking density between 10 and 20 sheep ha -1. The isotope dilution based nocturnal boundary-layer estimates generally agreed to better than a factor of 2 and usually to within 20% of the average of individual animal emission rate per unit area of paddock. Both static and advecting mass balance methods are developed. In the advecting case, the upwind/downwind contrast in δ13C was typically 0.2-0.5‰. Care was necessary with air sampling to avoid error in this small contrast contributing to error in the flux. Agreement between concentration- and isotope-based nocturnal boundary layer methods and the sheep breath measurements indicated that sample representativeness was generally good. Factors which affect the accuracy of the method are examined and include variability in nocturnal mixing height, the assumed δ13CH 4 composition of the source sheep breath and diurnal patterns in sheep emission. This paper establishes new techniques useful in the paddock to landscape scale although widespread application awaits further development of technology for rapid and repeatable field analysis of δ13CH 4 in small samples.

  11. Calculating carbon mass balance from unsaturated soil columns treated with CaSO₄₋minerals: test of soil carbon sequestration.

    Science.gov (United States)

    Han, Young-Soo; Tokunaga, Tetsu K

    2014-12-01

    Renewed interest in managing C balance in soils is motivated by increasing atmospheric concentrations of CO2 and consequent climate change. Here, experiments were conducted in soil columns to determine C mass balances with and without addition of CaSO4-minerals (anhydrite and gypsum), which were hypothesized to promote soil organic carbon (SOC) retention and soil inorganic carbon (SIC) precipitation as calcite under slightly alkaline conditions. Changes in C contents in three phases (gas, liquid and solid) were measured in unsaturated soil columns tested for one year and comprehensive C mass balances were determined. The tested soil columns had no C inputs, and only C utilization by microbial activity and C transformations were assumed in the C chemistry. The measurements showed that changes in C inventories occurred through two processes, SOC loss and SIC gain. However, the measured SOC losses in the treated columns were lower than their corresponding control columns, indicating that the amendments promoted SOC retention. The SOC losses resulted mostly from microbial respiration and loss of CO2 to the atmosphere rather than from chemical leaching. Microbial oxidation of SOC appears to have been suppressed by increased Ca(2+) and SO4(2)(-) from dissolution of CaSO4 minerals. For the conditions tested, SIC accumulation per m(2) soil area under CaSO4-treatment ranged from 130 to 260 g C m(-1) infiltrated water (20-120 g C m(-1) infiltrated water as net C benefit). These results demonstrate the potential for increasing C sequestration in slightly alkaline soils via CaSO4-treatment. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Estimate of regional groundwater recharge rate in the Central Haouz Plain, Morocco, using the chloride mass balance method and a geographical information system

    Science.gov (United States)

    Ait El Mekki, Ouassil; Laftouhi, Nour-Eddine; Hanich, Lahoucine

    2017-07-01

    Located in the extreme northwest of Africa, the Kingdom of Morocco is increasingly affected by drought. Much of the country is characterised by an arid to semi-arid climate and the demand for water is considerably higher than the supply, particularly on the Haouz Plain in the centre of the country. The expansion of agriculture and tourism, in addition to industrial development and mining, have exacerbated the stress on water supplies resulting in drought. It is therefore necessary to adopt careful management practices to preserve the sustainability of the water resources in this region. The aquifer recharge rate in the piedmont region that links the High Atlas and the Central Haouz Plain was estimated using the chloride mass balance hydrochemical method, which is based on the relationship between the chloride concentrations in groundwater and rainwater. The addition of a geographical information system made it possible to estimate the recharge rate over the whole 400 km2 of the study area. The results are presented in the form of a map showing the spatialized recharge rate, which ranges from 13 to 100 mm/year and the recharge percentage of the total rainfall varies from 3 to 25 % for the hydrological year 2011-2012. This approach will enable the validation of empirical models covering areas >6200 km2, such as the Haouz nappe.

  13. Chemical mass balance source apportionment of PM10 and TSP in residential and industrial sites of an urban region of Kolkata, India.

    Science.gov (United States)

    Gupta, A K; Karar, Kakoli; Srivastava, Anjali

    2007-04-02

    Daily average PM(10) (particulate matter which passes through a size selective impactor inlet with a 50% efficiency cut-off at 10 microm aerodynamic diameter), TSP (total suspended particulate matter) and their chemical species mass concentrations were measured at residential and industrial sites of an urban region of Kolkata during November 2003-November 2004. Source apportionment using chemical mass balance model revealed that the most dominant source throughout the study period at residential site was coal combustion (42%), while vehicular emission (47%) dominates at industrial site to PM(10). Paved road, field burning and wood combustion contributed 21%, 7% and 1% at residential site, while coal combustion, metal industry and soil dust contributed 34%, 1% and 1% at industrial site, respectively, to PM(10) during the study period. The contributors to TSP included coal combustion (37%), soil dust (19%), road dust (17%) and diesel combustion (15%) at residential site, while soil dust (36%), coal combustion (17%), solid waste (17%), road dust (16%) and tyre wear (7%) at industrial site. Significant seasonal variations of the particulate matters have been observed during the study period. In the monitoring sites total carbon, organic carbon and iron were found to be the marker species of road dust, while organic carbon, total carbon, chloride and sulfate have been observed as the marker species of soil dust in TSP.

  14. Sea level changes from monthly solutions of ice sheet mass balance

    DEFF Research Database (Denmark)

    Barletta, Valentina Roberta; Sørensen, Louise Sandberg; Forsberg, René

    We present mass change time series at basin scale for both Greenland and Antarctica, de-rived from GRACE data, and use these data to find the associated global sea level changes. We use two independent methods for GRACE ice mass loss estimation, including use of different GIA models and estimatio...

  15. Annual and Seasonal Glacier-Wide Surface Mass Balance Quantified from Changes in Glacier Surface State: A Review on Existing Methods Using Optical Satellite Imagery

    Directory of Open Access Journals (Sweden)

    Antoine Rabatel

    2017-05-01

    Full Text Available Glaciers are one of the terrestrial essential climate variables (ECVs as they respond very sensitively to climate change. A key driver of their response is the glacier surface mass balance that is typically derived from field measurements. It deserves to be quantified over long time scales to better understand the accumulation and ablation processes at the glacier surface and their relationships with inter-annual changes in meteorological conditions and long-term climate changes. Glaciers with in situ monitoring of surface mass balance are scarce at the global scale, and satellite remote sensing provides a powerful tool to increase the number of monitored glaciers. In this study, we present a review of three optical remote sensing methods developed to quantify seasonal and annual glacier surface mass balances. These methodologies rely on the multitemporal monitoring of the end-of-summer snow line for the equilibrium-line altitude (ELA method, the annual cycle of glacier surface albedo for the albedo method and the mapping of the regional snow cover at the seasonal scale for the snow-map method. Together with a presentation of each method, an application is illustrated. The ELA method shows promising results to quantify annual surface mass balance and to reconstruct multi-decadal time series. The other two methods currently need a calibration on the basis of existing in situ data; however, a generalization of these methods (without calibration could be achieved. The two latter methods show satisfying results at the annual and seasonal scales, particularly for the summer surface mass balance in the case of the albedo method and for the winter surface mass balance in the case of the snow-map method. The limits of each method (e.g., cloud coverage, debris-covered glaciers, monsoon-regime and cold glaciers, their complementarities and the future challenges (e.g., automating of the satellite images processing, generalization of the methods needing

  16. Wind drifted snow influence on the water and mass balance in the mountainous catchment "Modry potok", the Giant Mountains, Czech Republic.

    Science.gov (United States)

    Dvorak, I. J.; Fottova, D.; Tesar, M.; Kocianova, M.; Harcarik, J.

    2009-04-01

    There are very specific components of the water balance in the mountain headwater regions. Beside the point of cloud- and fog-water deposition it is mainly accumulation of water in the snow cover drifted into the watershed by the wind. Uneven distribution of the snow cover over the mountainous terrain is a well known phenomenon in all alpine and arctic areas. The result of this uneveness is a mosaic of microhabitats with various snow depths, different melting dates and snow free periods. Wire probes can be reliably used up to snow depths of 3 m only. To get more realistic data, two digital models using kinematic carrier phase-based GPS measurements were developed: (1) a model for snow surface data, applied at the end of winter seasons from 2000 to 2008, and (2) a model for the underlying snow free ground surface, applied after the snow melting in August 2000. These two models, overlaid in the GIS environment, have identified snow depths. For the creation of digital elevation models (DEMs), the TOPOGRID command in ArcInfo was used, which generated a grid of elevations from 3-D point, line, and polygon data. The snow depths were obtained and snow maps constructed accordingly. These "snow" results can be used for more realistic estimation of water content of snow in the watershed, distribution of snow depth during the winter seasons and define the water and mass balance more precisely. The objectives of this study were to highlight water storage in the snow-beds and show the GPS kinematic measurements as a contribution to understand more the snow accumulating and melting processes in the Modry potok catchment (2,62 km2, 1010 - 1554 m a.s.l.) in the Giant Mts. The research is supported by the Ministry of the Environment of the Czech Republic (SP/1a6/151/07) and by the Krkonose National Park Administration in Vrchlabi.

  17. Paleohydrology on Mars constrained by mass balance and mineralogy of pre-Amazonian sodium chloride lakes

    Science.gov (United States)

    Melwani Daswani, M.; Kite, E. S.

    2017-09-01

    Chloride-bearing deposits on Mars record high-elevation lakes during the waning stages of Mars' wet era (mid-Noachian to late Hesperian). The water source pathways, seasonality, salinity, depth, lifetime, and paleoclimatic drivers of these widespread lakes are all unknown. Here we combine reaction-transport modeling, orbital spectroscopy, and new volume estimates from high-resolution digital terrain models, in order to constrain the hydrologic boundary conditions for forming the chlorides. Considering a T = 0°C system, we find that (1) individual lakes were >100 m deep and lasted decades or longer; (2) if volcanic degassing was the source of chlorine, then the water-to-rock ratio or the total water volume were probably low, consistent with brief excursions above the melting point and/or arid climate; (3) if the chlorine source was igneous chlorapatite, then Cl-leaching events would require a (cumulative) time of >10 years at the melting point; and (4) Cl masses, divided by catchment area, give column densities 0.1-50 kg Cl/m2, and these column densities bracket the expected chlorapatite-Cl content for a seasonally warm active layer. Deep groundwater was not required. Taken together, our results are consistent with Mars having a usually cold, horizontally segregated hydrosphere by the time chlorides formed.

  18. The heat source of Ruapehu crater lake; deductions from the energy and mass balances

    Science.gov (United States)

    Hurst, A. W.; Bibby, H. M.; Scott, B. J.; McGuinness, M. J.

    1991-05-01

    Regular observations of temperature, outflow rates and water chemistry of Crater Lake, Mt. Ruapehu, New Zealand have been made for the last 25 years. These data have been used to derive a model of the dynamics of the lake, and determine the input of energy, mass, and chloride from the volcano to the Crater Lake. The recent, relatively quiescent state of the volcano, when virtually no heat has been input to the lake, has also enabled an assessment to be made of the surface heat loss characteristics, which play an important role in the model of the lake. The modelling suggests that since about 1982 the ratio of the volcanic heat to mass added to the base of the lake is about 6 MJ/kg, which is not compatible with heating of the lake by magmatic steam alone. Thus, only about 50% of the heating has been by magmatic steam. It is suggested that heat could be transferred from a magmatic source to the region below the lake by a heat-pipe mechanism, commonly associated with geothermal systems. The simultaneous upward movement of vapour phase, and downward movement of liquid phase from condensed vapour allows efficient heat transfer without overall mass transfer. The permeability necessary to supply the required heat is of the order of 10 darcy, and is consistent with a rubble filled vent. For at least the last five years, there has been a characteristic pattern in the Crater Lake temperature record, with alternate heating and cooling phases. The heating phase generally lasts for one or two months, while the cooling phase lasts for six months to a year. A possible explanation for this cyclic behaviour is the presence of a layer of liquid sulphur under Crater Lake, acting as a partial barrier between the heat-pipe and the lake. The unusual variations of the viscosity of liquid sulphur with temperature will mean that at temperatures greater than 160°C, the layer of sulphur becomes highly viscous and would block any upwards steam flow and hence stop the heat input to Crater

  19. Katabatic winds diminish precipitation contribution to the Antarctic ice mass balance

    Science.gov (United States)

    Grazioli, Jacopo; Madeleine, Jean-Baptiste; Gallée, Hubert; Forbes, Richard M.; Genthon, Christophe; Krinner, Gerhard; Berne, Alexis

    2017-10-01

    Snowfall in Antarctica is a key term of the ice sheet mass budget that influences the sea level at global scale. Over the continental margins, persistent katabatic winds blow all year long and supply the lower troposphere with unsaturated air. We show that this dry air leads to significant low-level sublimation of snowfall. We found using unprecedented data collected over 1 year on the coast of Adélie Land and simulations from different atmospheric models that low-level sublimation accounts for a 17% reduction of total snowfall over the continent and up to 35% on the margins of East Antarctica, significantly affecting satellite-based estimations close to the ground. Our findings suggest that, as climate warming progresses, this process will be enhanced and will limit expected precipitation increases at the ground level.

  20. Katabatic winds diminish precipitation contribution to the Antarctic ice mass balance.

    Science.gov (United States)

    Grazioli, Jacopo; Madeleine, Jean-Baptiste; Gallée, Hubert; Forbes, Richard M; Genthon, Christophe; Krinner, Gerhard; Berne, Alexis

    2017-10-10

    Snowfall in Antarctica is a key term of the ice sheet mass budget that influences the sea level at global scale. Over the continental margins, persistent katabatic winds blow all year long and supply the lower troposphere with unsaturated air. We show that this dry air leads to significant low-level sublimation of snowfall. We found using unprecedented data collected over 1 year on the coast of Adélie Land and simulations from different atmospheric models that low-level sublimation accounts for a 17% reduction of total snowfall over the continent and up to 35% on the margins of East Antarctica, significantly affecting satellite-based estimations close to the ground. Our findings suggest that, as climate warming progresses, this process will be enhanced and will limit expected precipitation increases at the ground level.

  1. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    Energy Technology Data Exchange (ETDEWEB)

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  2. Bioaccumulation potential of air contaminants: Combining biological allometry, chemical equilibrium and mass-balances to predict accumulation of air pollutants in various mammals

    International Nuclear Information System (INIS)

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-01-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity for lipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (K ba ) and tissue-air partition coefficients (K ta ) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 68% of the modeled inhalation and exhalation rate constants are within a factor of 2.1 from independent empirical values for humans, rats and mice, and 87% of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  3. Mass balances and energy flows, reference concept. (Spent Fuel - Copper-Iron - Bentonite - Granite)

    International Nuclear Information System (INIS)

    Nordman, H.; Lehikoinen, J.

    2008-12-01

    In this work, a semi-quantitative analysis of mass and energy flows and balances in a deep repository of the KBS-3V type subject to a glacial cycle has been carried out. The energy flows and temperatures show the maximum temperature at the canister surface not to exceed the design temperature of 100 deg C. If the measures taken to limit the water flow into the underground facilities are appropriate, the lifetime of the calcite buffer in the hydraulically conductive fracture zones was calculated to extend well beyond the operational phase of the repository. The results from hydrogeochemical model calculations in the backfill imply a long-term exchange of sodium for calcium in the clay component, if MX-80 bentonite is used. As this constitutes a potential threat to the swelling pressure of backfill in saline water environments, the physicochemical properties of a backfill should be carefully adjusted to meet its preplanned function. Despite short-lived episodes of oxygen-rich glacial water intrusion, the corrosion of the copper canister will likely be minor in the long term. (orig.)

  4. THERMODYNAMIC AND MASS BALANCE ANALYSIS OF EXPANSIVE PHASE PRECIPITATION IN SALTSTONE

    Energy Technology Data Exchange (ETDEWEB)

    Fletcher, D

    2008-05-01

    This report assesses the potential for future precipitation of expansive phases that could cause fracturing in saltstone. It examines the equilibrium case using The Geochemist's Workbench{reg_sign} reaction path model. The scenarios simulated examine the effects of different possible infiltrating fluids, different saltstone formulations, and different amounts of minerals available for reaction. Mineralogy of the vault cement and saltstone were estimated using reported chemical compositions of each. The infiltrating fluid was assumed to be either rainwater equilibrated with vault cement or rainwater itself. The simulations assumed that minerals were homogeneously distributed in saltstone and that each pore volume of infiltration reached equilibrium with the mineral assemblage. Fracturing that initiates in pores by expansive phase precipitation is unlikely to occur in saltstone because the maximum amount of porosity filled is 34%. If less than 100% of the saltstone minerals are available for reaction, less porosity will be lost to expansive phases. Likewise, the formulation of saltstone used will affect the amount of porosity filled by expansive phases.

  5. THERMODYNAMIC AND MASS BALANCE ANALYSIS OF EXPANSIVE PHASE PRECIPITATION IN SALTSTONE

    Energy Technology Data Exchange (ETDEWEB)

    Denham, M

    2008-05-06

    This report assesses the potential for future precipitation of expansive phases that could cause fracturing in saltstone. It examines the equilibrium case using The Geochemist's Workbench{reg_sign} reaction path model. The scenarios simulated examine the effects of different possible infiltrating fluids, different saltstone formulations, and different amounts of minerals available for reaction. Mineralogy of the vault cement and saltstone were estimated using reported chemical compositions of each. The infiltrating fluid was assumed to be either rainwater equilibrated with vault cement or rainwater itself. The simulations assumed that minerals were homogeneously distributed in saltstone and that each pore volume of infiltration reached equilibrium with the mineral assemblage. Fracturing that initiates in pores by expansive phase precipitation is unlikely to occur in saltstone because the maximum amount of porosity filled is 34%. If less than 100% of the saltstone minerals are available for reaction, less porosity will be lost to expansive phases. Likewise, the formulation of saltstone used will affect the amount of porosity filled by expansive phases.

  6. Elliptic Cylinder Airborne Sampling and Geostatistical Mass Balance Approach for Quantifying Local Greenhouse Gas Emissions.

    Science.gov (United States)

    Tadić, Jovan M; Michalak, Anna M; Iraci, Laura; Ilić, Velibor; Biraud, Sébastien C; Feldman, Daniel R; Bui, Thaopaul; Johnson, Matthew S; Loewenstein, Max; Jeong, Seongeun; Fischer, Marc L; Yates, Emma L; Ryoo, Ju-Mee

    2017-09-05

    In this study, we explore observational, experimental, methodological, and practical aspects of the flux quantification of greenhouse gases from local point sources by using in situ airborne observations, and suggest a series of conceptual changes to improve flux estimates. We address the major sources of uncertainty reported in previous studies by modifying (1) the shape of the typical flight path, (2) the modeling of covariance and anisotropy, and (3) the type of interpolation tools used. We show that a cylindrical flight profile offers considerable advantages compared to traditional profiles collected as curtains, although this new approach brings with it the need for a more comprehensive subsequent analysis. The proposed flight pattern design does not require prior knowledge of wind direction and allows for the derivation of an ad hoc empirical correction factor to partially alleviate errors resulting from interpolation and measurement inaccuracies. The modified approach is applied to a use-case for quantifying CH 4 emission from an oil field south of San Ardo, CA, and compared to a bottom-up CH 4 emission estimate.

  7. Analysis of Antarctic Ice-Sheet Mass Balance from ICESat Measurements

    Science.gov (United States)

    Zwally, H. Jay; Li, Jun; Robbins, John; Saba, Jack L.; Yi, Donghui

    2011-01-01

    If protoplanets formed from 10 to 20 kilometer diameter planetesimals in a runaway accretion process prior to their oligarchic growth into the terrestrial planets, it is only logical to ask where these planetesimals may have formed in order to assess the initial composition of the Earth. We have used Weidenschilling's model for the formation of comets (1997) to calculate an efficiency factor for the formation of planetesimals from the solar nebula, then used this factor to calculate the feeding zones that contribute to material contained within 10, 15 and 20 kilometer diameter planetesimals at 1 A.V. as a function of nebular mass. We find that for all reasonable nebular masses, these planetesimals contain a minimum of 3% water as ice by mass. The fraction of ice increases as the planetesimals increase in size and as the nebular mass decreases, since both factors increase the feeding zones from which solids in the final planetesimals are drawn. Is there really a problem with the current accretion scenario that makes the Earth too dry, or is it possible that the nascent Earth lost significant quantities of water in the final stages of accretion?

  8. Meso-scale testing and development of test procedures to maintain mass balance.

    Science.gov (United States)

    Bonner, James; Page, Cheryl; Fuller, Chris

    2003-01-01

    The Conrad Blucher Institute for Surveying and Science (Texas A&M University--Corpus Christi) has conducted numerous petroleum experiments at the Shoreline Environmental Research Facility (Corpus Christi, Texas, USA). The meso-scale facility has multiple wave tanks, permitting some control in experimental design of the investigations, but allowing for real-world conditions. This paper outlines the evolution of a materials balance approach in conducting petroleum experiments at the facility. The first attempt at a materials balance was during a 1998 study on the fate/effects of dispersant use on crude oil. Both water column and beach sediment samples were collected. For the materials balance, the defined environmental compartments for oil accumulation were sediments, water column, and the water surface, while the discharge from the tanks was presumed to be the primary sink. The "lessons learned" included a need to quantify oil adhesion to the tank surfaces. This was resolved by adhering strips of the polymer tank lining to the tank sides that could be later removed and extracted for oil. Also, a protocol was needed to quantify any floating oil on the water surface. A water surface (oil slick) quantification protocol was developed, involving the use of solid-phase extraction disks. This protocol was first tested during a shoreline cleaner experiment, and later refined in subsequent dispersant effectiveness studies. The effectiveness tests were designed to simulate shallow embayments which created the need for additional adjustments in the tanks. Since dispersant efficacy is largely affected by hydrodynamics, it was necessary to scale the hydrodynamic conditions of the tanks to those expected in our prototype system (Corpus Christi Bay, Texas). The use of a scaled model permits the experiment to be reproduced and/or evaluated under different conditions. To minimize wave reflection in the tank, a parabolic wave dissipater was built. In terms of materials balance, this

  9. Implications of elevated CO2 on pelagic carbon fluxes in an Arctic mesocosm study – an elemental mass balance approach

    Directory of Open Access Journals (Sweden)

    J. Czerny

    2013-05-01

    Full Text Available Recent studies on the impacts of ocean acidification on pelagic communities have identified changes in carbon to nutrient dynamics with related shifts in elemental stoichiometry. In principle, mesocosm experiments provide the opportunity of determining temporal dynamics of all relevant carbon and nutrient pools and, thus, calculating elemental budgets. In practice, attempts to budget mesocosm enclosures are often hampered by uncertainties in some of the measured pools and fluxes, in particular due to uncertainties in constraining air–sea gas exchange, particle sinking, and wall growth. In an Arctic mesocosm study on ocean acidification applying KOSMOS (Kiel Off-Shore Mesocosms for future Ocean Simulation, all relevant element pools and fluxes of carbon, nitrogen and phosphorus were measured, using an improved experimental design intended to narrow down the mentioned uncertainties. Water-column concentrations of particulate and dissolved organic and inorganic matter were determined daily. New approaches for quantitative estimates of material sinking to the bottom of the mesocosms and gas exchange in 48 h temporal resolution as well as estimates of wall growth were developed to close the gaps in element budgets. However, losses elements from the budgets into a sum of insufficiently determined pools were detected, and are principally unavoidable in mesocosm investigation. The comparison of variability patterns of all single measured datasets revealed analytic precision to be the main issue in determination of budgets. Uncertainties in dissolved organic carbon (DOC, nitrogen (DON and particulate organic phosphorus (POP were much higher than the summed error in determination of the same elements in all other pools. With estimates provided for all other major elemental pools, mass balance calculations could be used to infer the temporal development of DOC, DON and POP pools. Future elevated pCO2 was found to enhance net autotrophic community carbon

  10. Indoor and outdoor urban atmospheric CO2: Stable carbon isotope constraints on mixing and mass balance

    International Nuclear Information System (INIS)

    Yanes, Yurena; Yapp, Crayton J.

    2010-01-01

    Research highlights: → 13 C of indoor CO 2 indicates proportion of C 4 -derived carbon in occupants' diet. → Flux balance model for ventilated rooms shows rapid approach to CO 2 steady-state. → From extant indoor CO 2 data more dietary C 4 carbon in American than European diets. → Local outdoor urban CO 2 increase of 17 ppm in ten years, no change in average 13 C. - Abstract: From July to November 2009, concentrations of CO 2 in 78 samples of ambient air collected in 18 different interior spaces on a university campus in Dallas, Texas (USA) ranged from 386 to 1980 ppm. Corresponding δ 13 C values varied from -8.9 per mille to -19.4 per mille. The CO 2 from 22 samples of outdoor air (also collected on campus) had a more limited range of concentrations from 385 to 447 ppm (avg. = 408 ppm), while δ 13 C values varied from -10.1 per mille to -8.4 per mille (avg.=-9.0 per mille). In contrast to ambient indoor and outdoor air, the concentrations of CO 2 exhaled by 38 different individuals ranged from 38,300 to 76,200 ppm (avg. = 55,100 ppm), while δ 13 C values ranged from -24.8 per mille to -17.7 per mille (avg. = -21.8 per mille). The residence times of the total air in the interior spaces of this study appear to have been on the order of 10 min with relatively rapid approaches (∼30 min) to steady-state concentrations of ambient CO 2 gas. Collectively, the δ 13 C values of the indoor CO 2 samples were linearly correlated with the reciprocal of CO 2 concentration, exhibiting an intercept of -21.8 per mille, with r 2 = 0.99 and p 2 data representing 18 interior spaces (with varying numbers of occupants), and the coincidence of the intercept (-21.8 per mille) with the average δ 13 C value for human-exhaled CO 2 demonstrates simple mixing between two inputs: (1) outdoor CO 2 introduced to the interior spaces by ventilation systems, and (2) CO 2 exhaled by human occupants of those spaces. If such simple binary mixing is a common feature of interior spaces, it

  11. Volume changes of Vatnajökull ice cap, Iceland, due to surface mass balance, ice flow, and subglacial melting at geothermal areas

    DEFF Research Database (Denmark)

    Magnússon, Eyjólfur; Björnson, Helgi; Dall, Jørgen

    2005-01-01

    We present observed changes in the geometry of western Vatnajökull over a period of about ten years which are caused by the surface mass balance, ice flow (both during surges and quiescent periods), and basal melting due to geothermal and volcanic activity. Comparison of two digital elevation...

  12. Mass balance of the Greenland ice sheet (2003-2008) from ICESat data - the impact of interpolation, sampling and firn density

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2011-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique dataset for monitoring the changes of the cryosphere. Here, we present a novel method for determining the mass balance of the Greenland ice sheet, derived from ICESat altim...

  13. Biomethanation of vegetable market waste in an anaerobic baffled reactor: Effect of effluent recirculation and carbon mass balance analysis.

    Science.gov (United States)

    Gulhane, Madhuri; Khardenavis, Anshuman A; Karia, Sneha; Pandit, Prabhakar; Kanade, Gajanan S; Lokhande, Satish; Vaidya, Atul N; Purohit, Hemant J

    2016-09-01

    In the present study, feasibility of biomethanation of vegetable market waste in a 4-chambered anaerobic baffled reactor (ABR) was investigated at 30d hydraulic retention time and organic loading rate of 0.5gVS/L/d for one year. Indicators of process stability viz., butyrate/acetate and propionate/acetate ratios were consistent with phase separation in the different chambers, which remained unaltered even during recirculation of effluent. Chemical oxygen demand (COD) and volatile solids (VS) removal efficiencies were observed to be consistently high (above 90%). Corresponding biogas and methane yields of 0.7-0.8L/g VS added/d and 0.42-52L/g VS added/d respectively were among the highest reported in case of AD of vegetable waste in an ABR. Process efficiency of the ABR for vegetable waste methanation, which is indicated by carbon recovery factor showed that, nearly 96.7% of the input carbon considered for mass balance was accounted for in the product. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Previously hidden low-energy ions: a better map of near-Earth space and the terrestrial mass balance

    International Nuclear Information System (INIS)

    André, Mats

    2015-01-01

    This is a review of the mass balance of planet Earth, intended also for scientists not usually working with space physics or geophysics. The discussion includes both outflow of ions and neutrals from the ionosphere and upper atmosphere, and the inflow of meteoroids and larger objects. The focus is on ions with energies less than tens of eV originating from the ionosphere. Positive low-energy ions are complicated to detect onboard sunlit spacecraft at higher altitudes, which often become positively charged to several tens of volts. We have invented a technique to observe low-energy ions based on the detection of the wake behind a charged spacecraft in a supersonic ion flow. We find that low-energy ions usually dominate the ion density and the outward flux in large volumes in the magnetosphere. The global outflow is of the order of 10 26 ions s –1 . This is a significant fraction of the total number outflow of particles from Earth, and changes plasma processes in near-Earth space. We compare order of magnitude estimates of the mass outflow and inflow for planet Earth and find that they are similar, at around 1 kg s −1 (30 000 ton yr −1 ). We briefly discuss atmospheric and ionospheric outflow from other planets and the connection to evolution of extraterrestrial life. (invited comment)

  15. Recent mass balance of the Purogangri Ice Cap, central Tibetan Plateau, by means of differential X-band SAR interferometry

    Directory of Open Access Journals (Sweden)

    N. Neckel

    2013-10-01

    Full Text Available Due to their remoteness, altitude and harsh climatic conditions, little is known about the glaciological parameters of ice caps on the Tibetan Plateau. This study presents a geodetic mass balance estimate of the Purogangri Ice Cap, Tibet's largest ice field between 2000 and 2012. We utilized data from the actual TerraSAR-X mission and its add-on for digital elevation measurements and compared it with elevation data from the Shuttle Radar Topography Mission. The employed data sets are ideal for this approach as both data sets were acquired at X-band at nearly the same time of the year and are available at a fine grid spacing. In order to derive surface elevation changes we employed two different methods. The first method is based on differential synthetic radar interferometry while the second method uses common DEM differencing. Both approaches revealed a slightly negative mass budget of −44 ± 15 and −38 ± 23 mm w.eq. a−1 (millimeter water equivalent respectively. A slightly negative trend of −0.15 ± 0.01 km2 a−1 in glacier extent was found for the same time period employing a time series of Landsat data. Overall, our results show an almost balanced mass budget for the studied time period. Additionally, we detected one continuously advancing glacier tongue in the eastern part of the ice cap.

  16. The Alteration History of Clovis Class Rocks in Gusev Crater as Determined by Ti-Normalzed Mass Balance Analysis

    Science.gov (United States)

    Sutter, Brat; Ming, Douglas W.; Niles, P. B.; Golden, D. C.

    2012-01-01

    The West Spur Clovis class rocks in Gusev Crater are some of the most altered rocks in Gusev Crater and likely contain a mixed sulfate and phyllosilicate mineralogy [1,2]. The high S and Cl content of the Clovis rocks suggests that acidic vapors or fluids of H2SO4 and HCl reacted with the Clovis parent rock to form Ca, Mg,- sulfates, iron-oxyhydroxides and secondary aluminosilicates (approx.60 wt.%) of a poorly crystalline nature (e.g., allophane) [1]. Up to 14-17 wt.% phyllosilicates (e.g., kaolinite, chlorite, serpentine) are hypothesized to exist in the Clovis materials suggesting that Clovis parent materials while possibly exposed to acidic pHs were likely neutralized by basalt dissolution which resulted in mildly acidic pHs (4-6) [1, 2]. This work proposes that subsequent to the alteration of the Clovis rocks, alteration fluids became concentrated in ions resulting in the addition of silicate and salts. The objective of this work is to utilize Ti-normalized mass balance analysis to evaluate (1) mineral gains and losses and (2) elemental gains and losses in the Clovis rocks. Results of this work will be used evaluate the nature of geochemical conditions that affect phyllosilicate and sulfate formation at Gusev crater.

  17. Titanium Mass-balance Analysis of Paso Robles Soils: Elemental Gains and Losses as Affected by Acid Alteration Fluids

    Science.gov (United States)

    Sutter, Brad; Ming, Douglas W.

    2010-01-01

    The Columbia Hills soils have been exposed to aqueous alteration in alkaline [1] as well as acid conditions [2,3]. The Paso Robles class soils are bright soils that possess the highest S concentration of any soil measured on Mars [2]. Ferric-sulfate detection by Moessbauer analysis indicated that acid solutions were involved in forming these soils [4]. These soils are proposed to have formed by alteration of nearby rock by volcanic hydrothermal or fumarolic activity. The Paso Robles soils consist of the original Paso Robles-disturbed-Pasadena (PR-dist), Paso Robles- PasoLight (PR-PL), Arad-Samra, Arad-Hula, Tyrone- Berker Island1 and Tyrone-MountDarwin [2 ,3. ]Chemical characteristics indicate that the PR-dist and PR-PL soils could be derived from acid weathering of local Wishstone rocks while the Samra and Hula soils are likely derived from local Algonquin-Iroquet rock [3]. The Paso Robles soils were exposed to acidic sulfur bearing fluids; however, little else is known about the chemistry of the alteration fluid and its effects on the alteration of the proposed parent materials. The objectives of this work are to conduct titanium normalized mass-balance analysis to1) assess elemental gains and losses from the parent materials in the formation of the Paso Robles soils and 2) utilize this information to indicate the chemical nature of the alteration fluids.

  18. Evaluating the potential for environmental pollution from chromated copper arsenate (CCA)-treated wood waste: a new mass balance approach.

    Science.gov (United States)

    Mercer, T G; Frostick, L E

    2014-07-15

    The potential for pollution from arsenic, chromium and copper in chromated copper arsenate (CCA) treated wood waste was assessed using two lysimeter studies. The first utilised lysimeters containing soil and CCA wood waste mulch exposed to natural conditions over a five month period. The second study used the same lysimeter setup in a regulated greenhouse setting with a manual watering regime. Woodchip, soil and leachate samples were evaluated for arsenic, chromium and copper concentrations. Resultant concentration data were used to produce mass balances, an approach thus far unused in such studies. This novel analysis revealed new patterns of mobility and distribution of the elements in the system. The results suggest that CCA wood waste tends to leach on initial exposure to a leachant and during weathering of the wood. When in contact with soil, metal(loid) transport is reduced due to complexation reactions. With higher water application or where the adsorption capacity of the soil is exceeded, the metal(loid)s are transported through the soil column as leachate. Overall, there was an unexplained loss of metal(loid)s from the system that might be attributed to volatilisation of arsenic and plant uptake. This suggests a hitherto unidentified risk to both the environment and human health. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Climate change threatens archaeologically significant ice patches: insights into their age, internal structure, mass balance and climate sensitivity

    Science.gov (United States)

    Strand Ødegård, Rune; Nesje, Atle; Isaksen, Ketil; Andreassen, Liss Marie; Eiken, Trond; Schwikowski, Margit; Uglietti, Chiara

    2017-04-01

    Despite numerous spectacular archaeological discoveries worldwide related to melting ice patches and the emerging field of glacial archaeology, governing processes related to ice patch development during the Holocene and their sensitivity to climate change are still largely unexplored. Here we present new results from an extensive 6-year (2009-2015) field experiment at the Juvfonne ice patch in Jotunheimen in central southern Norway. Our results show that the ice patch has existed continuously since the late Mesolithic period. Organic-rich layers and carbonaceous aerosols embedded in clear ice show ages spanning from modern at the surface to ca. 7600 cal years BP at the bottom. This is the oldest dating of ice in mainland Norway. The expanding ice patch covered moss mats appearing along the margin of Juvfonne about 2000 years ago. During the study period, the mass balance record showed a strong negative balance, and the annual balance is highly asymmetric over short distances. Snow accumulation is poorly correlated with estimated winter precipitation, and single storm events may contribute significantly to the total winter balance. Snow accumulation is approx. 20% higher in the frontal area compared to the upper central part of the ice patch. There is sufficient meltwater to bring the permeable snowpack to an isothermal state within a few weeks in early summer. Below the seasonal snowpack, ice temperatures are between -2 and -4 °C. Juvfonne has clear ice stratification of isochronic origin. Reference: The Cryosphere, 11, 17-32, 2017.

  20. Sensitivity analysis of lake mass balance in discontinuous permafrost: the example of disappearing Twelvemile Lake, Yukon Flats, Alaska (USA)

    Science.gov (United States)

    Jepsen, S.M.; Voss, C.I.; Walvoord, Michelle Ann; Rose, J.R.; Minsley, B.J.; Smith, B.D.

    2013-01-01

    Many lakes in northern high latitudes have undergone substantial changes in surface area over the last four decades, possibly as a result of climate warming. In the discontinuous permafrost of Yukon Flats, interior Alaska (USA), these changes have been non-uniform across adjacent watersheds, suggesting local controls on lake water budgets. Mechanisms that could explain the decreasing mass of one lake in Yukon Flats since the early 1980s, Twelvemile Lake, are identified via a scoping analysis that considers plausible changes in snowmelt mass and infiltration, permafrost distribution, and climate warming. Because predicted changes in evaporation (2 cmyr-1) are inadequate to explain the observed 17.5 cmyr-1 reduction in mass balance, other mechanisms are required. The most important potential mechanisms are found to involve: (1) changes in shallow, lateral groundwater flow to the lake possibly facilitated by vertical freeze-thaw migration of the permafrost table in gravel; (2) increased loss of lake water as downward groundwater flow through an open talik to a permeable subpermafrost flowpath; and (3) reduced snow meltwater inputs due to decreased snowpack mass and increased infiltration of snowmelt into, and subsequent evaporation from, fine-grained sediment mantling the permafrost-free lake basin.

  1. Kinetic rates and mass balance of COD, TKN, and TP using SBR treating domestic and industrial wastewater.

    Science.gov (United States)

    Warodomrungsimun, Chaowalit; Fongsatitkul, Prayoon

    2009-12-01

    To assess the performance of SBR to treat three different types of wastewater from domestic, hospital, slaughterhouse and investigate the kinetic rates of active biomass. Mass balance calculation of COD, TKN and TP was further performed to explain the mechanisms of the biological nutrient removals processed in the SBR system. The measured kinetic rates were in turn used to evaluate the process performances under different types of wastewater. Experimental research involving 3 similar SBR lab-scales were installed and operated at the Sanitary Engineering Laboratory. The reactors were seeded with sludge biomass obtained from the Sri-Phraya Domestic Wastewater Treatment Plant in Bangkok. The slaughterhouse, hospital and domestic wastewaters were treated by SBR system for biological organic carbon (COD), nitrogen (TKN) and phosphorus removals. Biological methods for kinetic rates evaluation were conducted in five replicated batch tests. The removal efficiencies of COD and TKN were greater than 90% for all three types of wastewater while the biological phosphorus removal for domestic and hospital wastewaters were less than 60% and phosphorus removal for slaughterhouse exceeded 95%. The kinetic rates of nitrification and denitrification of hospital wastewater was lower than those the domestic and slaughterhouse wastewaters. Phosphorus release and uptake rates of slaughterhouse wastewater were high but domestic and hospital wastewaters were very low. The result of system removal efficiency and batch test for kinetic rates confirmed that the domestic and hospital wastewaters were in deficiency of organic carbon with respect to its ability to support successful biological phosphorus removal.

  2. chloride mass balance

    African Journals Online (AJOL)

    Agadaga

    in the unsaturated profiles (Mbeubeuss, F22, Pikine and. P2-6) make the CMB not applicable in this area. Qualitative estimation of recharge using environmental isotopic data (18O, 2H and 3H). Groundwater samples have δ18O values ranging between. –5.1 and –1.5‰, with a mean of –3.8‰ and δ2H values from –38.1 to ...

  3. Mass Balance, Metabolite Profile, and In Vitro-In Vivo Comparison of Clearance Pathways of Deleobuvir, a Hepatitis C Virus Polymerase Inhibitor

    Science.gov (United States)

    Chen, Lin-Zhi; Sabo, John P.; Philip, Elsy; Rowland, Lois; Mao, Yan; Latli, Bachir; Ramsden, Diane; Mandarino, Debra A.

    2014-01-01

    The pharmacokinetics, mass balance, and metabolism of deleobuvir, a hepatitis C virus (HCV) polymerase inhibitor, were assessed in healthy subjects following a single oral dose of 800 mg of [14C]deleobuvir (100 μCi). The overall recovery of radioactivity was 95.2%, with 95.1% recovered from feces. Deleobuvir had moderate to high clearance, and the half-life of deleobuvir and radioactivity in plasma were ∼3 h, indicating that there were no metabolites with half-lives significantly longer than that of the parent. The most frequently reported adverse events (in 6 of 12 subjects) were gastrointestinal disorders. Two major metabolites of deleobuvir were identified in plasma: an acyl glucuronide and an alkene reduction metabolite formed in the gastrointestinal (GI) tract by gut bacteria (CD 6168), representing ∼20% and 15% of the total drug-related material, respectively. Deleobuvir and CD 6168 were the main components in the fecal samples, each representing ∼30 to 35% of the dose. The majority of the remaining radioactivity found in the fecal samples (∼21% of the dose) was accounted for by three metabolites in which deleobuvir underwent both alkene reduction and monohydroxylation. In fresh human hepatocytes that form biliary canaliculi in sandwich cultures, the biliary excretion for these excretory metabolites was markedly higher than that for deleobuvir and CD 6168, implying that rapid biliary elimination upon hepatic formation may underlie the absence of these metabolites in circulation. The low in vitro clearance was not predictive of the observed in vivo clearance, likely because major deleobuvir biotransformation occurred by non-CYP450-mediated enzymes that are not well represented in hepatocyte-based in vitro models. PMID:25313217

  4. Methane mass balance at three landfill sites: What is the efficiency of capture by gas collection systems?

    International Nuclear Information System (INIS)

    Spokas, K.; Bogner, J.; Chanton, J.P.; Morcet, M.; Aran, C.; Graff, C.; Golvan, Y. Moreau-Le; Hebe, I.

    2006-01-01

    Many developed countries have targeted landfill methane recovery among greenhouse gas mitigation strategies, since methane is the second most important greenhouse gas after carbon dioxide. Major questions remain with respect to actual methane production rates in field settings and the relative mass of methane that is recovered, emitted, oxidized by methanotrophic bacteria, laterally migrated, or temporarily stored within the landfill volume. This paper presents the results of extensive field campaigns at three landfill sites to elucidate the total methane balance and provide field measurements to quantify these pathways. We assessed the overall methane mass balance in field cells with a variety of designs, cover materials, and gas management strategies. Sites included different cell configurations, including temporary clay cover, final clay cover, geosynthetic clay liners, and geomembrane composite covers, and cells with and without gas collection systems. Methane emission rates ranged from -2.2 to >10,000 mg CH 4 m -2 d -1 . Total methane oxidation rates ranged from 4% to 50% of the methane flux through the cover at sites with positive emissions. Oxidation of atmospheric methane was occurring in vegetated soils above a geomembrane. The results of these studies were used as the basis for guidelines by the French environment agency (ADEME) for default values for percent recovery: 35% for an operating cell with an active landfill gas (LFG) recovery system, 65% for a temporary covered cell with an active LFG recovery system, 85% for a cell with clay final cover and active LFG recovery, and 90% for a cell with a geomembrane final cover and active LFG recovery

  5. Bioanalysis works in the IAA AMS facility: Comparison of AMS analytical method with LSC method in human mass balance study

    International Nuclear Information System (INIS)

    Miyaoka, Teiji; Isono, Yoshimi; Setani, Kaoru; Sakai, Kumiko; Yamada, Ichimaro; Sato, Yoshiaki; Gunji, Shinobu; Matsui, Takao

    2007-01-01

    Institute of Accelerator Analysis Ltd. (IAA) is the first Contract Research Organization in Japan providing Accelerator Mass Spectrometry (AMS) analysis services for carbon dating and bioanalysis works. The 3 MV AMS machines are maintained by validated analysis methods using multiple control compounds. It is confirmed that these AMS systems have reliabilities and sensitivities enough for each objective. The graphitization of samples for bioanalysis is prepared by our own purification lines including the measurement of total carbon content in the sample automatically. In this paper, we present the use of AMS analysis in human mass balance and metabolism profiling studies with IAA 3 MV AMS, comparing results obtained from the same samples with liquid scintillation counting (LSC). Human samples such as plasma, urine and feces were obtained from four healthy volunteers orally administered a 14 C-labeled drug Y-700, a novel xanthine oxidase inhibitor, of which radioactivity was about 3 MBq (85 μCi). For AMS measurement, these samples were diluted 100-10,000-fold with pure-water or blank samples. The results indicated that AMS method had a good correlation with LSC method (e.g. plasma: r = 0.998, urine: r = 0.997, feces: r = 0.997), and that the drug recovery in the excreta exceeded 92%. The metabolite profiles of plasma, urine and feces obtained with HPLC-AMS corresponded to radio-HPLC results measured at much higher radioactivity level. These results revealed that AMS analysis at IAA is useful to measure 14 C-concentration in bioanalysis studies at very low radioactivity level

  6. Life cycle inventory and mass-balance of municipal food waste management systems: Decision support methods beyond the waste hierarchy.

    Science.gov (United States)

    Edwards, Joel; Othman, Maazuza; Crossin, Enda; Burn, Stewart

    2017-11-01

    When assessing the environmental and human health impact of a municipal food waste (FW) management system waste managers typically rely on the principles of the waste hierarchy; using metrics such as the mass or rate of waste that is 'prepared for recycling,' 'recovered for energy,' or 'sent to landfill.' These metrics measure the collection and sorting efficiency of a waste system but are incapable of determining the efficiency of a system to turn waste into a valuable resource. In this study a life cycle approach was employed using a system boundary that includes the entire waste service provision from collection to safe end-use or disposal. A life cycle inventory of seven waste management systems was calculated, including the first service wide inventory of FW management through kitchen in-sink disposal (food waste disposer). Results describe the mass, energy and water balance of each system along with key emissions profile. It was demonstrated that the energy balance can differ significantly from its' energy generation, exemplified by mechanical biological treatment, which was the best system for generating energy from waste but only 5 th best for net-energy generation. Furthermore, the energy balance of kitchen in-sink disposal was shown to be reduced because 31% of volatile solids were lost in pre-treatment. The study also confirmed that higher FW landfill diversion rates were critical for reducing many harmful emissions to air and water. Although, mass-balance analysis showed that the alternative end-use of the FW material may still contain high impact pollutants. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

  7. Mass balance and life cycle assessment of the waste electrical and electronic equipment management system implemented in Lombardia Region (Italy).

    Science.gov (United States)

    Biganzoli, L; Falbo, A; Forte, F; Grosso, M; Rigamonti, L

    2015-08-15

    Waste electrical and electronic equipment (WEEE) is one of the fastest growing waste streams in Europe, whose content of hazardous substances as well as of valuable materials makes the study of the different management options particularly interesting. The present study investigates the WEEE management system in Lombardia Region (Italy) in the year 2011 by applying the life cycle assessment (LCA) methodology. An extensive collection of primary data was carried out to describe the main outputs and the energy consumptions of the treatment plants. Afterwards, the benefits and burdens associated with the treatment and recovery of each of the five categories in which WEEE is classified according to the Italian legislation (heaters and refrigerators - R1, large household appliances - R2, TV and monitors - R3, small household appliances - R4 and lighting equipment - R5) were evaluated. The mass balance of the treatment and recovery system of each of the five WEEE categories showed that steel and glass are the predominant streams of materials arising from the treatment; a non-negligible amount of plastic is also recovered, together with small amounts of precious metals. The LCA of the regional WEEE management system showed that the benefits associated with materials and energy recovery balance the burdens of the treatment processes, with the sole exception of two impact categories (human toxicity-cancer effects and freshwater ecotoxicity). The WEEE categories whose treatment and recovery resulted more beneficial for the environment and the human health are R3 and R5. The contribution analysis showed that overall the main benefits are associated with the recovery of metals, as well as of plastic and glass. Some suggestions for improving the performance of the system are given, as well as an indication for a more-in-depth analysis for the toxicity categories and a proposal for a new characterisation method for WEEE. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. Mass balance, metabolic disposition, and pharmacokinetics of a single oral dose of regorafenib in healthy human subjects.

    Science.gov (United States)

    Gerisch, Michael; Hafner, Frank-Thorsten; Lang, Dieter; Radtke, Martin; Diefenbach, Konstanze; Cleton, Adriaan; Lettieri, John

    2018-01-01

    To evaluate the mass balance, metabolic disposition, and pharmacokinetics of a single dose of regorafenib in healthy volunteers. In addition, in vitro metabolism of regorafenib in human hepatocytes was investigated. Four healthy male subjects received one 120 mg oral dose of regorafenib containing approximately 100 µCi (3.7 MBq) [ 14 C]regorafenib. Plasma concentrations of parent drug were derived from HPLC-MS/MS analysis and total radioactivity from liquid scintillation counting (LSC). Radiocarbon analyses used HPLC with fraction collection followed by LSC for all urine samples, plasma, and fecal homogenate extracts. For the in vitro study, [ 14 C]regorafenib was incubated with human hepatocytes and analyzed using HPLC-LSC and HPLC-HRMS/MS. Regorafenib was the major component in plasma, while metabolite M-2 (pyridine N-oxide) was the most prominent metabolite. Metabolites M-5 (demethylated pyridine N-oxide) and M-7 (N-glucuronide) were identified as minor plasma components. The mean concentration of total radioactivity in plasma/whole blood appeared to plateau at 1-4 h and again at 6-24 h post-dose. In total, 90.5% of administered radioactivity was recovered in the excreta within a collection interval of 12 days, most of which (71.2%) was eliminated in feces, while excretion via urine accounted for 19.3%. Regorafenib (47.2%) was the most prominent component in feces and was not excreted into urine. Excreted metabolites resulted from oxidative metabolism and glucuronidation. Regorafenib was eliminated predominantly in feces as well as by hepatic biotransformation. The multiple biotransformation pathways of regorafenib decrease the risk of pharmacokinetic drug-drug interactions.

  9. Bioanalysis works in the IAA AMS facility: Comparison of AMS analytical method with LSC method in human mass balance study

    Energy Technology Data Exchange (ETDEWEB)

    Miyaoka, Teiji [Institute of Accelerator Analysis Ltd., 129-1 Noborito-Shinmachi, Tama-Ku Kawasaki, Kanagawa 214-0013 (Japan)]. E-mail: miyaoka@iaa-ams.co.jp; Isono, Yoshimi [Institute of Accelerator Analysis Ltd., 129-1 Noborito-Shinmachi, Tama-Ku Kawasaki, Kanagawa 214-0013 (Japan); Setani, Kaoru [Institute of Accelerator Analysis Ltd., 129-1 Noborito-Shinmachi, Tama-Ku Kawasaki, Kanagawa 214-0013 (Japan); Sakai, Kumiko [Institute of Accelerator Analysis Ltd., 129-1 Noborito-Shinmachi, Tama-Ku Kawasaki, Kanagawa 214-0013 (Japan); Yamada, Ichimaro [Mitsubishi Pharma Co., 2-2-6 Nihombashi-Honcho, Chuo-Ku, Tokyo 103-8405 (Japan); Sato, Yoshiaki [Daiichi Pure Chemicals, Co., Ltd., 2117 Muramatsu, Tokai, Naka-Gun, Ibaraki 319-1132 (Japan); Gunji, Shinobu [Daiichi Pure Chemicals, Co., Ltd., 2117 Muramatsu, Tokai, Naka-Gun, Ibaraki 319-1132 (Japan); Matsui, Takao [Institute of Accelerator Analysis Ltd., 129-1 Noborito-Shinmachi, Tama-Ku Kawasaki, Kanagawa 214-0013 (Japan)

    2007-06-15

    Institute of Accelerator Analysis Ltd. (IAA) is the first Contract Research Organization in Japan providing Accelerator Mass Spectrometry (AMS) analysis services for carbon dating and bioanalysis works. The 3 MV AMS machines are maintained by validated analysis methods using multiple control compounds. It is confirmed that these AMS systems have reliabilities and sensitivities enough for each objective. The graphitization of samples for bioanalysis is prepared by our own purification lines including the measurement of total carbon content in the sample automatically. In this paper, we present the use of AMS analysis in human mass balance and metabolism profiling studies with IAA 3 MV AMS, comparing results obtained from the same samples with liquid scintillation counting (LSC). Human samples such as plasma, urine and feces were obtained from four healthy volunteers orally administered a {sup 14}C-labeled drug Y-700, a novel xanthine oxidase inhibitor, of which radioactivity was about 3 MBq (85 {mu}Ci). For AMS measurement, these samples were diluted 100-10,000-fold with pure-water or blank samples. The results indicated that AMS method had a good correlation with LSC method (e.g. plasma: r = 0.998, urine: r = 0.997, feces: r = 0.997), and that the drug recovery in the excreta exceeded 92%. The metabolite profiles of plasma, urine and feces obtained with HPLC-AMS corresponded to radio-HPLC results measured at much higher radioactivity level. These results revealed that AMS analysis at IAA is useful to measure {sup 14}C-concentration in bioanalysis studies at very low radioactivity level.

  10. Outline of surface mass balance at Dome Fuji, East Antarctica, by the stake method from 1995 to 2006

    Directory of Open Access Journals (Sweden)

    Takao Kameda

    2008-06-01

    Full Text Available This paper describes observational results of surface mass balance (SMB at Dome Fuji (77°19'01″S, 39°42'11″E; 3810m a.s.l., East Antarctica from 1995 to 2006. The SMB was estimated using 36 bamboo stakes (grid of 6×6, placed at 20m intervals. The heights of the stake tops from the snow surface were measured at 0.5cm resolution twice monthly in 1995, 1996, 1997, and 2003, and once a year for the rest of the study period. The annual SMB from 1995 to 2006 at Dome Fuji was 27.3±1.5kgm^a^. This result agrees well with the annual SMB from AD 1260 to 1993 (26.4kgm^a^, estimated from volcanic signals in the Dome Fuji ice core. From 1995 to 2006, there were 37 incidences of negative or zero annual SMB, which was 8.6%. Compared with similar studies at Vostok, South Pole and Dome C, we found that a site with SMB over 190kgm^a^ is expected to have annual snow accumulation at the 95% confidence level. Sites from 1500 to 2500m above sea level fit the criteria on the Antarctic ice sheet. According to stake and snow pit observations at Vostok, we estimated that the probability of an annual layer missing (hiatus at Dome Fuji under present-day and glacial conditions are 9.4% and 11.4%, respectively. Variations of SMB measured by 36-stakes for 12 years were also analyzed.

  11. Using a mass balance to understand the geology and geochemistry of a reservoir receiving and discharging acid mine drainage

    International Nuclear Information System (INIS)

    Turney, D.C.; Edwards, K.

    1996-01-01

    Howard-Williams Lake is a 14.5 acre reservoir located in an abandoned coal mine in Perry County, Ohio. With a pH of 3.0 and acidity values of 300--400 mg/L, the reservoir has no plants or fish currently surviving in the lake. Reclamation of spoil piles adjacent to the lake to the north in the late 1980s was not successful in reducing the acidity of the lake. Currently, papermill sludge is being used on the reclaimed area to the north to promote vegetation, but the reservoir has shown no signs of improving. The goal of this project is to transform the lake into a fishable and swimmable one. The reservoir is receiving about 175 gallons per minute of acid mine drainage, not including seepage into the lake, from eight different sources. Three of the sources account for about 165 gallons per minute of the surface water that enters the lake. These inflows have relatively low acidity readings, which range from 66 mg/L to 568 mg/L. The other five sources of acid mine drainage have much lower flowrates, but have acidity values as high as 3,000 mg/L. Samples of all of the surface inflows and the outflow of the lake were taken and sent to a laboratory and tested for the following parameters: total acidity as CaCO 3 , total alkalinity as CaCO 2 , specific conductivity, total suspended solids, sulfate, chloride calcium, magnesium, sodium, potassium, total iron, total manganese, aluminum, and hardness. During sampling of the surface inflows, volumetric flowrates were measured for each inflow. Once the flowrates and the concentrations of the various parameters were known, a mass balance could be constructed which would show how much of each parameter was entering the lake each day. These data were then used to gain an understanding of the geochemistry and geology of the site

  12. Mass balance of emerging contaminants in the water cycle of a highly urbanized and industrialized area of Italy.

    Science.gov (United States)

    Castiglioni, Sara; Davoli, Enrico; Riva, Francesco; Palmiotto, Marinella; Camporini, Paolo; Manenti, Angela; Zuccato, Ettore

    2017-12-22

    The occurrence of several classes of emerging contaminants (ECs) was assessed in the River Lambro basin, one of the most urbanized and industrialized areas of Italy. The study aims were to identify the main sources of ECs, quantify their amounts circulating in the water cycle, and study their fate in the aquatic environment. More than 80 ECs were selected among pharmaceuticals (PHARM), personal care products (PCPs), disinfectants (DIS), illicit drugs (IDs), perfluorinated compounds (PERF), alkylphenols and bisphenol A (Alk-BPA), and anthropogenic markers (AM). Specific analytical methods were developed for quantitative analysis based on solid phase extraction and liquid chromatography tandem mass spectrometry. ECs were measured in rivers upstream and downstream of the main city (Milan), and in untreated and treated wastewater from Milan to assess the contribution to river contamination, and in superficial and deep groundwater in the city area to study the relationship between river and groundwater contamination. Samples were collected in a two-year monitoring campaign. Almost all ECs were ubiquitous in untreated wastewater, at concentrations up to the μg/L range, and the most abundant classes were PHARM and AM. Removals during different wastewater treatment processes were studied and the most stable substances were PHARM, PCPs and PERF. The mass loads increased for all the classes of ECs along the River Lambro basin. A mass balance was done in the river basin and allowed to identify the main sources of contamination, which were domestic, from treated or untreated wastewater, for PHARM, PCPs and IDs, mainly industrial for PERF, and both industrial and domestic for Alk-BPA. The study of AM helped to identify direct discharges of untreated wastewater. A substantial contribution of surface water to groundwater contamination was observed. This study improves the knowledge on occurrence, sources and fate of multiple classes of ECs in a highly urbanized area providing

  13. Localized Surface Plasmon Resonance with Five-Branched Gold Nanostars in a Plastic Optical Fiber for Bio-Chemical Sensor Implementation

    Directory of Open Access Journals (Sweden)

    Luigi Zeni

    2013-10-01

    Full Text Available In this paper a refractive index sensor based on localized surface plasmon resonance (LSPR in a Plastic Optical Fiber (POF, is presented and experimentally tested. LSPR is achieved exploiting five-branched gold nanostars (GNS obtained using Triton X-100 in a seed-growth synthesis. They have the uncommon feature of three localized surface plasmon resonances. The strongest LSPRs fall in two ranges, one in the 600–900 nm range (LSPR 2 and the other one in the 1,100–1,600 nm range (LSPR 3, both sensible to refractive index changes. Anyway, due to the extremely strong attenuation (>102 dB/m of the employed POF in the 1,100–1,600 nm range, only LSPR 2 will be exploited for refractive index change measurements, useful for bio-chemical sensing applications, as a proof of principle of the possibility of realizing a compact, low cost and easy-to-use GNS based device.

  14. Enhanced electricity generation by triclosan and iron anodes in the three-chambered membrane bio-chemical reactor (TC-MBCR).

    Science.gov (United States)

    Song, Jing; Liu, Lifen; Yang, Fenglin; Ren, Nanqi; Crittenden, John

    2013-11-01

    A three-chambered membrane bio-chemical reactor (TC-MBCR) was developed. The stainless steel membrane modules were used as cathodes and iron plates in the middle chamber served as the anode. The TC-MBCR was able to reduce fouling, remove triclosan (TCS) from a synthetic wastewater treatment and enhance electricity generation by ~60% compared with the cell voltage before TCS addition. The TC-MBCR system generated a relatively stable power output (cell voltage ~0.2V) and the corrosion of iron plates contributed to electricity generation together with microbes on iron anode. The permeation flow from anode to cathode chamber was considered important in electricity generation. In addition, the negatively charged cathode membrane and Fe(2+)/Fe(3+) released by iron plates mitigated membrane fouling by approximately 30%, as compared with the control. The removal of COD and total phosphorus was approximately 99% and 90%. The highest triclosan removal rate reached 97.9%. Copyright © 2013. Published by Elsevier Ltd.

  15. Origin of CaCl2 brines by basalt-seawater interaction: Insights provided by some simple mass balance calculations

    Science.gov (United States)

    Hardie, Lawrence A.

    1983-06-01

    Modern rift zone hydrothermal brines are typically CaCl2-bearing brines, an unusual chemical signature they share with certain oil field brines, fluid inclusions in ore minerals and a few uncommon saline lakes. Many origins have been suggested for such CaCl2 brines but in the Reykjanes, Iceland, geothermal system a strong empirical case can be made for a basalt-seawater interaction origin. To examine this mechanism of CaCl2 brine evolution some simple mass balance calculations were carried out. Average Reykjanes olivine tholeiite was “reacted” with average North Atlantic seawater to make an albite-chlorite-epidotesphene rock using Al2O3 as the conservative rock component and Cl as the conservative fluid component. The excess components released by the basalt to the fluid were “precipitated” at 275° C as quartz, calcite, anhydrite, magnetite and pyrite to complete the conversion to greenstone. The resulting fluid was a CaCl2 brine of seawater chlorinity with a composition remarkably similar to the actual Reykjanes brine at 1750 m depth. Thus, the calculations strongly support the idea that the Reykjanes CaCl2 brines result from “closed system” oceanic basalt-seawater interaction (albitization — chloritization mechanism) at greenschist facies temperatures. The calculation gives a seawater: basalt mass ratio of 3∶1 to 4∶1 (vol. ratio of 9∶1 to 12∶1), in keeping with experimental results, submarine vent data and with ocean crust cooling calculations. The brine becomes anoxic because there is insufficient dissolved or combined oxygen to balance all the Fe released from the basalt during alteration. Large excesses of Ca are released to the fluid and precipitate out in the form of anhydrite which essentially sweeps the brine free of sulfate leaving an elevated Ca concentration. The calculated rock-water interaction basically involves Na + Mg + SO4 ⇌ Ca + K, simulating chemical differences observed between oceanic basalts and greenstones from many

  16. Greenland ice sheet surface mass-balance modelling and freshwater flux for 2007, and in a 1995-2007 perspective

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2009-01-01

    % occurs from iceberg calving and geothermal bottom melting. The average annual GrIS freshwater flux equals 2.1 ± 0.2 mm w.eq. y-1 in eustatic sea level rise, indicating a cumulative flux of 28 mm w.eq. from 1995 through 2007. The average GrIS net loss contributes to a net sea level rise of 0.7 ± 0.2 mm w...

  17. Precipitation Modeling over the Greenland and Antarctic Ice Sheets and the Relationship to the Surface Mass Balance and Climate

    Science.gov (United States)

    Bromwich, David H.; Chen, Qui-Shi

    2005-01-01

    Atmospheric numerical simulation and dynamic retrieval method with atmospheric numerical analyses are used to assess the spatial and temporal variability of Antarctic precipitation for the last two decades. First, the Polar MM5 has been run over Antarctica to study the Antarctic precipitation. With a horizontal resolution of 60km, the Polar MM5 has been run for the period of July 1996 through June 1999 in a series of short-term forecasts from initial and boundary conditions provided by the ECMWF operational analyses. In comparison with climatological maps, the major features of the spatial distribution of Antarctic precipitation are well captured by the Polar MM5. Drift snow effects on redistribution of surface accumulation over Antarctica are also assessed with surface wind fields from Polar MM5 in this study. There are complex divergence and convergence patterns of drift snow transport over Antarctica, especially along the coast. It is found that areas with large drift snow transport convergence and divergence are located around escarpment areas where there is large katabatic wind acceleration. In addition, areas with large snow transport divergence are generally accompanied by areas with large snow transport convergence nearby, indicating that drift snow transport is of local importance for the redistribution of the snowfall

  18. Modelling the surface mass balance of the Greenland ice sheet and neighbouring ice caps : A dynamical and statistical downscaling approach

    NARCIS (Netherlands)

    Noël, B.P.Y.|info:eu-repo/dai/nl/370612345

    2018-01-01

    The Greenland ice sheet (GrIS) is the world’s second largest ice mass, storing about one tenth of the Earth’s freshwater. If totally melted, global sea level would rise by 7.4 m, affecting low-lying regions worldwide. Since the mid-1990s, increased atmospheric and oceanic temperatures have

  19. The contribution of groundwater discharge to the overall water budget of two typical Boreal lakes in Alberta/Canada estimated from a radon mass balance

    Directory of Open Access Journals (Sweden)

    A. Schmidt

    2010-01-01

    Full Text Available Radon-222, a naturally-occurring radioisotope with a half-life of 3.8 days, was used to estimate groundwater discharge to small lakes in wetland-dominated basins in the vicinity of Fort McMurray, Canada. This region is under significant water development pressure including both oil sands mining and in situ extraction. Field investigations were carried out in March and July 2008 to measure radon-222 distributions in the water column of two lakes as a tracer of groundwater discharge. Radon concentrations in these lakes ranged from 0.5 to 72 Bq/m3, while radon concentrations in groundwaters ranged between 2000 and 8000 Bq/m3. A radon mass balance, used in comparison with stable isotope mass balance, suggested that the two lakes under investigation had quite different proportions of annual groundwater inflow (from 0.5% to about 14% of the total annual water inflow. Lower discharge rates were attributed to a larger drainage area/lake area ratio which promotes greater surface connectivity. Interannual variability in groundwater proportions is expected despite an implied seasonal constancy in groundwater discharge rates. Our results demonstrate that a combination of stable isotope and radon mass balance approaches provides information on flowpath partitioning that is useful for evaluating surface-groundwater connectivity and acid sensitivity of individual water bodies of interest in the Alberta Oil Sands Region.

  20. The origin and crust/mantle mass balance of Central Andean ignimbrite magmatism constrained by oxygen and strontium isotopes and erupted volumes

    Science.gov (United States)

    Freymuth, Heye; Brandmeier, Melanie; Wörner, Gerhard

    2015-06-01

    Volcanism during the Neogene in the Central Volcanic Zone (CVZ) of the Andes produced (1) stratovolcanoes, (2) rhyodacitic to rhyolitic ignimbrites which reach volumes of generally less than 300 km3 and (3) large-volume monotonous dacitic ignimbrites of up to several thousand cubic kilometres. We present models for the origin of these magma types using O and Sr isotopes to constrain crust/mantle proportions for the large-volume ignimbrites and explore the relationship to the evolution of the Andean crust. Oxygen isotope ratios were measured on phenocrysts in order to avoid the effects of secondary alteration. Our results show a complete overlap in the Sr-O isotope compositions of lavas from stratovolcanoes and low-volume rhyolitic ignimbrites as well as older (>9 Ma) large-volume dacitic ignimbrites. This suggests that the mass balance of crustal and mantle components are largely similar. By contrast, younger (de Pica ignimbrites) and 70 km3 Ma-1 km-1 (assuming plutonic/volcanic ratios of 1:5) which are additional to, but within the order of, the arc background magmatic flux. Comparing our results to average shortening rates observed in the Andes, we observe a "lag-time" with large-volume eruptions occurring after accelerated shortening. A similar delay exists between the ignimbrite pulses and the subduction of the Juan Fernandez ridge. This is consistent with the idea that large-volume ignimbrite eruptions occurred in the wake of the N-S passage of the ridge after slab steepening has allowed hot asthenospheric mantle to ascend into and cause the melting of the mantle wedge. In our model, the older large-volume dacitic ignimbrites in the northern part of the CVZ have lower (15-37 %) crustal contributions because they were produced at times when the Central Andean crust was thinner and colder, and large-scale melting in the middle crust could not be achieved. Younger ignimbrite flare-ups further south (22°S) formed with a significantly higher crustal contribution

  1. In-situ GPS records of surface mass balance, firn compaction rates, and ice-shelf basal melt rates for Pine Island Glacier, Antarctica

    Science.gov (United States)

    Shean, D. E.; Christianson, K.; Larson, K. M.; Ligtenberg, S.; Joughin, I. R.; Smith, B.; Stevens, C.

    2016-12-01

    In recent decades, Pine Island Glacier (PIG) has experienced marked retreat, speedup and thinning due to ice-shelf basal melt, internal ice-stream instability and feedbacks between these processes. In an effort to constrain recent ice-stream dynamics and evaluate potential causes of retreat, we analyzed 2008-2010 and 2012-2014 GPS records for PIG. We computed time series of horizontal velocity, strain rate, multipath-based antenna height, surface elevation, and Lagrangian elevation change (Dh/Dt). These data provide validation for complementary high-resolution WorldView stereo digital elevation model (DEM) records, with sampled DEM vertical error of 0.7 m. The GPS antenna height time series document a relative surface elevation increase of 0.7-1.0 m/yr, which is consistent with estimated surface mass balance (SMB) of 0.7-0.9 m.w.e./yr from RACMO2.3 and firn compaction rates from the IMAU-FDM dynamic firn model. An abrupt 0.2-0.3 m surface elevation decrease due to surface melt and/or greater near-surface firn compaction is observed during a period of warm atmospheric temperatures from December 2012 to January 2013. Observed surface Dh/Dt for all PIG shelf sites is highly linear with trends of -1 to -4 m/yr and PIG shelf and 4 m/yr for the South shelf. These melt rates are similar to those derived from ice-bottom acoustic ranging, phase-sensitive ice-penetrating radar, and high-resolution stereo DEM records. The GPS/DEM records document higher melt rates within and near transverse surface depressions and rifts associated with longitudinal extension. Basal melt rates for the 2012-2014 period show limited temporal variability, despite significant change in ocean heat content. This suggests that sub-shelf melt rates are less sensitive to ocean heat content than previously reported, at least for these locations and time periods.

  2. Alternate strategies to obtain mass balance without the use of radiolabeled compounds: application of quantitative fluorine (19F) nuclear magnetic resonance (NMR) spectroscopy in metabolism studies.

    Science.gov (United States)

    Mutlib, Abdul; Espina, Robert; Atherton, James; Wang, Jianyao; Talaat, Rasmy; Scatina, JoAnn; Chandrasekaran, Appavu

    2012-03-19

    Nuclear magnetic resonance (NMR) spectroscopy is playing an increasingly important role in the quantitation of small and large molecules. Recently, we demonstrated that (1)H NMR could be used to quantitate drug metabolites isolated in submilligram quantities from biological sources. It was shown that these metabolites, once quantitated by NMR, were suitable to be used as reference standards in quantitative LC/MS-based assays, hence circumventing the need for radiolabeled material or synthetic standards to obtain plasma exposure estimates in humans and preclinical species. The quantitative capabilities of high-field NMR is further demonstrated in the current study by obtaining the mass balance of fluorinated compounds using (19)F-NMR. Two fluorinated compounds which were radio-labeled with carbon-14 on metabolically stable positions were dosed in rats and urine and feces collected. The mass balance of the compounds was obtained initially by counting the radioactivity present in each sample. Subsequently, the same sets of samples were analyzed by (19)F-NMR, and the concentrations determined by this method were compared with data obtained using radioactivity counting. It was shown that the two methods produced comparable values. To demonstrate the value of this analytical technique in drug discovery, a fluorinated compound was dosed intravenously in dogs and feces and urine collected. Initial profiling of samples showed that this compound was excreted mainly unchanged in feces, and hence, an estimate of mass balance was obtained using (19)F-NMR. The data obtained by this method was confirmed by additional quantitative studies using mass spectrometry. Hence cross-validations of the quantitative (19)F-NMR method by radioactivity counting and mass spectrometric analysis were demonstrated in this study. A strategy outlining the use of fluorinated compounds in conjunction with (19)F-NMR to understand their routes of excretion or mass balance in animals is proposed. These

  3. Differences in the energy and mass balance between a low- and a high-altitude glacial site in the Ortles-Cevedale (Italy), during the warm summer 2012

    Science.gov (United States)

    Carturan, Luca; Avvenuti, Marco; Cazorzi, Federico; Dalla Fontana, Giancarlo; Dinale, Roberto; Gabrielli, Paolo; Mair, Volkmar; Seppi, Roberto; Zanoner, Thomas

    2013-04-01

    Like in most of the European Alps, the glaciers of the Ortles-Cevedale (Eastern Italian Alps) are rapidly shrinking under the current warm climatic conditions. Different glaciers of this mountain group were found to react in different ways. The main control of their individual response appears to be the hypsometric distribution of area vs. altitude. In fact, the elevation affects the spatial distribution of the energy and mass balance through the atmospheric temperature and precipitation lapse rates, that determine the amount and frequency of ablation and accumulation. However, other processes and feedbacks take place during periods of rapid climatic change, which still need to be investigated and fully understood, in particular at high elevation. Two Automatic Weather Stations (AWS), operating on glacial sites at different altitudes in the Ortles-Cevedale, enabled a first comparative analysis for the warm summer of 2012. The lower AWS was placed in the ablation area of La Mare glacier, at 2970 m a.s.l., on temperate ice. The upper AWS worked on the high-altitude accumulation area of Alto dell'Ortles glacier, at 3840 m a.s.l., over temperate firn overlying cold ice. The two AWSs, located 10 km away from each other, monitor air temperature and relative humidity, wind speed and direction, incoming and outgoing shortwave and longwave radiation, surface temperature and snow height, and record mean values at time intervals of 15 minutes. The upper AWS also measures the temperature profile below the surface to a depth of 15 m. Direct mass balance measurements were carried out in the proximity of the two AWSs at the end of the accumulation and ablation seasons, by means of snow depth soundings, density measurements into snow pits and ablation measurements through ablation stakes. A strongly negative mass balance was measured in 2012 at the lowest AWS, which lost early in the summer the 110 cm thick snowpack accumulated during winter and underwent a net ablation of 350 cm

  4. Chemical mass balance (CMB) source apportionment and organic speciation of PM(2.5) in Missoula, Montana including the 2000 wildfire season

    Science.gov (United States)

    Ward, Tony J.

    A yearlong sampling program for PM2.5, Semi- Volatile Organic Compounds (SVOCs), and Volatile Organic Compounds (VOCs) was conducted in 2000/2001. The data were used in a Chemical Mass Balance (CMB) Source Apportionment Model (Version 8.0) to apportion the sources of PM2.5 in the Missoula Valley. Results showed that wood combustion contributed an average of 41% to the fine fraction throughout the year. The second largest source of PM 2.5 was diesel (19%), followed by ammonium nitrate (17%), the kraft recovery boilers from Smurfit-Stone Container (14%), other hog fuel boilers (6%), and street sand (5%). Results also showed that PM2.5 levels and contributions from sources were consistent on both sides of the Missoula Valley, but VOCs were twice as high in Missoula compared to Frenchtown. Another aspect of this program was to investigate the organic fraction of the Missoula Valley PM2.5 by evaluating a modified Federal Reference Method (FRM) PM2.5 sampler. A method comparison was also made between sampling for SVOCs using the modified PM2.5 sampler and in using a Hi-volume Polyurethane Foam (PUF) sampler. Results showed that the PM 2.5 PUF measured more of the lighter SVOCs compared to the Hi-vol PUF sampler. This is most likely the result of the higher flows through the Hi-vol PUF which ``strip'' the lighter organics from the surface of the filter. The wildland fires of summer 2000 comprised one of the most severe fire seasons is U.S. history, and had a direct impact on the city of Missoula. Sampling in Missoula was already in progress when the fires began and smoke started rolling into the Missoula Valley. Samples were collected before, during, and after the 2000 fire season, and a detailed characterization of particulate and gaseous emissions from extensive wildland fires was obtained. The 2000/2001 CMB Sampling Program data collected during the 2000 fire season suggest that the main health impacts to downwind populations reside in the fine particulate exposures

  5. Investigation of thallium fluxes from subaerial volcanism-Implications for the present and past mass balance of thallium in the oceans

    Science.gov (United States)

    Baker, R.G.A.; Rehkamper, M.; Hinkley, T.K.; Nielsen, S.G.; Toutain, J.P.

    2009-01-01

    A suite of 34 volcanic gas condensates and particulates from Kilauea (Hawaii), Mt. Etna and Vulcano (Italy), Mt. Merapi (Indonesia), White Island and Mt. Nguaruhoe (New Zealand) were analysed for both Tl isotope compositions and Tl/Pb ratios. When considered together with published Tl-Pb abundance data, the measurements provide globally representative best estimates of Tl/Pb = 0.46 ?? 0.25 and ??205Tl = -1.7 ?? 2.0 for the emissions of subaerial volcanism to the atmosphere and oceans (??205Tl is the deviation of the 205Tl/203Tl isotope ratio from NIST SRM 997 isotope standard in parts per 10,000). Compared to igneous rocks of the crust and mantle, volcanic gases were found to have (i) Tl/Pb ratios that are typically about an order of magnitude higher, and (ii) significantly more variable Tl isotope compositions but a mean ??205Tl value that is indistinguishable from estimates for the Earth's mantle and continental crust. The first observation can be explained by the more volatile nature of Tl compared to Pb during the production of volcanic gases, whilst the second reflects the contrasting and approximately balanced isotope fractionation effects that are generated by partial evaporation of Tl during magma degassing and partial Tl condensation as a result of the cooling and differentiation of volcanic gases. Mass balance calculations, based on results from this and other recent Tl isotope studies, were carried out to investigate whether temporal changes in the volcanic Tl fluxes could be responsible for the dramatic shift in the ??205Tl value of the oceans at ???55 Ma, which has been inferred from Tl isotope time series data for ferromanganese crusts. The calculations demonstrate that even large changes in the marine Tl input fluxes from volcanism and other sources are unable to significantly alter the Tl isotope composition of the oceans. Based on modelling, it is shown that the large inferred change in the ??205Tl value of seawater is best explained if the oceans

  6. Constitutive mass balance relations between chemical composition, volume, density, porosity, and strain in metasomatic hydrochemical systems: Results on weathering and pedogenesis

    Science.gov (United States)

    Brimhall, George H.; Dietrich, William E.

    1987-03-01

    Relations characterizing the chemical, physical, and mechanical changes resulting from metasomatic hydrochemical processes are developed using mass balance models which formally link chemical composition to bulk density, mineral density, volumetric properties, porosity, and amount of deformation (strain). Rigorous analysis of aqueous solute transport effects is then made possible in a variety of porous media flow environments including chemical weathering, pedogenesis (soil formation), diagenesis, ore deposition and enrichment, and metamorphism. Application of these linear constitutive relations to chemical weathering profiles shows that immobile and locally mobile chemical elements, with masses conserved on the scale of soil profiles, can be accurately identified from analysis of appropriate data arrays and then used as natural geochemical tracers to infer the nature and extent of hydrochemical weathering processes and volume changes during pedogenesis. Assumptions commonly made in the past about the supposed immobility of certain elements, e.g., Ti and Zr, become unnecessary. Quantitative differentiation between the effects of residual and supergene fractionation is then easily made. These methods are applied to Ni-rich laterites developed by weathering of ultramafic rocks, showing that during ordinary residual enrichment, Ni is concentrated by as much as 4× protolith peridotite concentrations. This occurs simply by silicate mineral dissolution and removal of chemical elements other than Ni ( e.g., Mg) with a corresponding reduction in saprolite density and increase in bulk porosity without significant deformation. In contrast, laterites with mineable concentrations of Ni which are similarly undeformed (such as the Nickel Mountain Mine in Riddle, Oregon) have experienced, in addition to residual enrichment, strong supergene enrichment by fractionation of ore elements between a leached zone from which Ni is extracted and a complementary enriched zone positioned

  7. Quantifying canal leakage rates using a mass-balance approach and heat-based hydraulic conductivity estimates in selected irrigation canals, western Nebraska, 2007 through 2009

    Science.gov (United States)

    Hobza, Christopher M.; Andersen, Michael J.

    2010-01-01

    The water supply in areas of the North Platte River Basin in the Nebraska Panhandle has been designated as fully appropriated or overappropriated by the Nebraska Department of Natural Resources (NDNR). Enacted legislation (Legislative Bill 962) requires the North Platte Natural Resources District (NPNRD) and the NDNR to develop an Integrated Management Plan (IMP) to balance groundwater and surface-water supply and demand in the NPNRD. A clear understanding of the groundwater and surface-water systems is critical for the development of a successful IMP. The primary source of groundwater recharge in parts of the NPNRD is from irrigation canal leakage. Because canal leakage constitutes a large part of the hydrologic budget, spatially distributing canal leakage to the groundwater system is important to any management strategy. Surface geophysical data collected along selected reaches of irrigation canals has allowed for the spatial distribution of leakage on a relative basis; however, the actual magnitude of leakage remains poorly defined. To address this need, the U.S. Geological Survey, in cooperation with the NPNRD, established streamflow-gaging stations at upstream and downstream ends from two selected canal reaches to allow a mass-balance approach to be used to calculate daily leakage rates. Water-level and sediment temperature data were collected and simulated at three temperature monitoring sites to allow the use of heat as a tracer to estimate the hydraulic conductivity of canal bed sediment. Canal-leakage rates were estimated by applying Darcy's Law to modeled vertical hydraulic conductivity and either the estimated or measured hydraulic gradient. This approach will improve the understanding of the spatial and temporal variability of canal leakage in varying geologic settings identified in capacitively coupled resistivity surveys. The high-leakage potential study reach of the Tri-State Canal had two streamflow-gaging stations and two temperature monitoring

  8. Perennial water stratification and the role of freshwater in the mass balance of Arctic ice shelves and multiyear landfast sea ice

    International Nuclear Information System (INIS)

    Jeffries, M.O.

    1991-01-01

    A number of the ice shelves of northern Ellesmere Island in the Canadian High Arctic owe their origin to multiyear landfast sea ice (MLSI) growth during the post-Hypsithermal cooling ca. 3,000-4,000 BP. Since they grew in response to an arctic-wide climatic deterioration and contain evidence of occasional post-4,000 BP climatic ameliorations, they may be expected to be sensitive to future global climate changes manifested in the High Arctic. The purpose of this paper is to examine ice-ocean interactions and feedbacks, and the response of the ice shelves and the MLSI to the improved summer climate of the last ca. 100 years, and implications for the future. There is good evidence that there has been a negative surface mass balance since the turn of the century. Mass balance measurements on the Ward Hunt Ice Shelf between 1966 and 1985 indicate a total ice loss of 1.371 m at a mean annual rate of 68.5 mm. The interannual pattern of accumulation and ablation and the long-term losses on the ice shelf are similar to other Canadian High Arctic glacier mass balance records. It is evident from water and ice core records of salinity, δ 18 0 and tritium, that perennial water stratification is common below and behind the ice shelves and MLSI. The coastal waters are highly stratified, with anything from 0.5 m to 41.0 m of freshwater interposed between the overlying ice and underlying seawater. The primary source of the freshwater is summer run-off of snow-meltwater from the adjacent land and from the ice itself. There is minimal mixing between the influent freshwater and seawater, and the freshwater is either dammed behind the ice shelves and the MLSI, with subsequent under-ice freshwater outflows, or pooled in under-ice depressions

  9. Diffuse pollution (pesticides and nitrate) at catchment scale on two constrasted sites: mass balances and characterization of the temporal variability of groundwater quality.

    Science.gov (United States)

    Baran, N.; Gutierrez, A.

    2009-04-01

    characterizations. Notable changes in the use of pesticides generally result from the evolution of regulations. In Europe, the herbicides atrazine and isoproturon have been classified as priority substances (2455/2001/EC, OJEC 2001). The use of atrazine was forbidden in France since September 2003 following restrictions already in force since 1991. In January 2004 the maximum permitted application of isoproturon was reduced from 2500 to 1800 g ha-1. In France, two contrasted hydrogeological systems located in agricultural contexts were intensively monitored for at least a decade in order to i) characterize the spatial and temporal variability of groundwater contamination by different pesticides with varied physical and chemical characteristics (atrazine, isoproturon and their metabolites and chloroacetanilides used as atrazine substitutes) and nitrate, ii) calculate annual pesticide mass balances for a long period including years with contrasted climatic conditions and to iii) identify the different mechanisms influencing water and solute transfer. Although both sites (Brévilles and 3 Fontaines) have very different hydrogeological characteristics (4 vs. 50 sq km, sandy vs. chalky saturated zone, non karstic vs. karstic, …) the monitoring of the major springs representing the outlet of the catchments revealed similarities. For example, atrazine and its metabolite deethylatrazine have been both systematically quantified at the outlet springs despite the stop of atrazine use on the Brévilles and 3 Fontaines catchments since April1999 and September 2003, respectively. For both sites, the mass balances (comparison of inputs and outfluxes) indicated that only few percents of the applied quantity of atrazine reached the spring but led to concentrations higher than the allowed limit for drinkable water. At the opposite, isoproturon which is the pesticide applied with the highest quantities for the last decade on both sites, is detected in a very limited number of samples. The different