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Sample records for binary solution surface

  1. Superficial composition in binary solid solutions A(B): Drastic effect of pure element surface tensions

    Science.gov (United States)

    Rolland, A.; Aufray, B.

    1985-10-01

    This paper deals with a comparative study of surface segragation of Pb and Ni respectively from Ag(Pb)(111) and Ag(Ni)(111) solid solutions. A high level of segregation of the solute is observed for both systems characterized by very low solute solubility. However, the superficial composition strongly depends on the relative surface tensions of the pure elements: the solute atoms are strictly on superficial sites when γ solute is smaller than γ solvent; in contrast uppermost layer consists purely of solvent when γ solute is greater than γ solvent. Two schematic distributions in close proximity to the surface are proposed in the last case.

  2. Bilayer formation in thin films of a binary solution

    International Nuclear Information System (INIS)

    Govor, L.V.; Reiter, G.; Bauer, G.H.; Parisi, J.

    2006-01-01

    We consider the formation of a pattern of micrometer-size droplets formed by phase separation in a binary solution composed of a nitrocellulose (NC) solution in amyl acetate and a hexadecylamine (HDA) solution in hexane. Spreading of this solution on a water surface leads to the formation of a bilayer with a top HDA and a lower NC solution layer. The formation of the bilayer was confirmed via spin-coating a similar binary solution on a Si substrate and an HDA solution in hexane on a NC/Si substrate. The subsequent evaporation of the solvents from both layers gives rise to a fast thickness decrease of the top HDA solution layer that decomposes into droplets. The discretely developing increase of the thickness of the HDA droplets can be explained only with the formation of HDA micelles in solution during solvent evaporation

  3. Bilayer formation in thin films of a binary solution

    Science.gov (United States)

    Govor, L. V.; Reiter, G.; Bauer, G. H.; Parisi, J.

    2006-04-01

    We consider the formation of a pattern of micrometer-size droplets formed by phase separation in a binary solution composed of a nitrocellulose (NC) solution in amyl acetate and a hexadecylamine (HDA) solution in hexane. Spreading of this solution on a water surface leads to the formation of a bilayer with a top HDA and a lower NC solution layer. The formation of the bilayer was confirmed via spin-coating a similar binary solution on a Si substrate and an HDA solution in hexane on a NC/Si substrate. The subsequent evaporation of the solvents from both layers gives rise to a fast thickness decrease of the top HDA solution layer that decomposes into droplets. The discretely developing increase of the thickness of the HDA droplets can be explained only with the formation of HDA micelles in solution during solvent evaporation.

  4. Bilayer formation in thin films of a binary solution

    Energy Technology Data Exchange (ETDEWEB)

    Govor, L.V. [Institute of Physics, University of Oldenburg, D-26111 Oldenburg (Germany)]. E-mail: leonid.govor@uni-oldenburg.de; Reiter, G. [Institut de Chimie des Surfaces et Interfaces, CNRS-UHA, F-8057 Mulhouse cedex (France); Bauer, G.H. [Institute of Physics, University of Oldenburg, D-26111 Oldenburg (Germany); Parisi, J. [Institute of Physics, University of Oldenburg, D-26111 Oldenburg (Germany)

    2006-04-24

    We consider the formation of a pattern of micrometer-size droplets formed by phase separation in a binary solution composed of a nitrocellulose (NC) solution in amyl acetate and a hexadecylamine (HDA) solution in hexane. Spreading of this solution on a water surface leads to the formation of a bilayer with a top HDA and a lower NC solution layer. The formation of the bilayer was confirmed via spin-coating a similar binary solution on a Si substrate and an HDA solution in hexane on a NC/Si substrate. The subsequent evaporation of the solvents from both layers gives rise to a fast thickness decrease of the top HDA solution layer that decomposes into droplets. The discretely developing increase of the thickness of the HDA droplets can be explained only with the formation of HDA micelles in solution during solvent evaporation.

  5. Unification of binary star ephemeris solutions

    International Nuclear Information System (INIS)

    Wilson, R. E.; Van Hamme, W.

    2014-01-01

    Time-related binary system characteristics such as orbital period, its rate of change, apsidal motion, and variable light-time delay due to a third body, are measured in two ways that can be mutually complementary. The older way is via eclipse timings, while ephemerides by simultaneous whole light and velocity curve analysis have appeared recently. Each has its advantages, for example, eclipse timings typically cover relatively long time spans while whole curves often have densely packed data within specific intervals and allow access to systemic properties that carry additional timing information. Synthesis of the two information sources can be realized in a one step process that combines several data types, with automated weighting based on their standard deviations. Simultaneous light-velocity-timing solutions treat parameters of apsidal motion and the light-time effect coherently with those of period and period change, allow the phenomena to interact iteratively, and produce parameter standard errors based on the quantity and precision of the curves and timings. The logic and mathematics of the unification algorithm are given, including computation of theoretical conjunction times as needed for generation of eclipse timing residuals. Automated determination of eclipse type, recovery from inaccurate starting ephemerides, and automated data weighting are also covered. Computational examples are given for three timing-related cases—steady period change (XY Bootis), apsidal motion (V526 Sagittarii), and the light-time effect due to a binary's reflex motion in a triple system (AR Aurigae). Solutions for all combinations of radial velocity, light curve, and eclipse timing input show consistent results, with a few minor exceptions.

  6. Surface tension of dilute alcohol-aqueous binary fluids: n-Butanol/water, n-Pentanol/water, and n-Hexanol/water solutions

    Science.gov (United States)

    Cheng, Kuok Kong; Park, Chanwoo

    2017-07-01

    Surface tension of pure fluids, inherently decreasing with regard to temperature, creates a thermo-capillary-driven (Marangoni) flow moving away from a hot surface. It has been known that few high-carbon alcohol-aqueous solutions exhibit an opposite behavior of the surface tension increasing with regard to temperature, such that the Marangoni flow moves towards the hot surface (self-rewetting effect). We report the surface tensions of three dilute aqueous solutions of n-Butanol, n-Pentanol and n-Hexanol as self-rewetting fluids measured for ranges of alcohol concentration (within solubility limits) and fluid temperatures (25-85 °C). A maximum bubble pressure method using a leak-tight setup was used to measure the surface tension without evaporation losses of volatile components. It was found from this study that the aqueous solutions with higher-carbon alcohols exhibit a weak self-rewetting behavior, such that the surface tensions remain constant or slightly increases above about 60 °C. These results greatly differ from the previously reported results showing a strong self-rewetting behavior, which is attributed to the measurement errors associated with the evaporation losses of test fluids during open-system experiments.

  7. MARVELS Radial Velocity Solutions to Seven Kepler Eclipsing Binaries

    Science.gov (United States)

    Heslar, Michael Francis; Thomas, Neil B.; Ge, Jian; Ma, Bo; Herczeg, Alec; Reyes, Alan; SDSS-III MARVELS Team

    2016-01-01

    Eclipsing binaries serve momentous purposes to improve the basis of understanding aspects of stellar astrophysics, such as the accurate calculation of the physical parameters of stars and the enigmatic mass-radius relationship of M and K dwarfs. We report the investigation results of 7 eclipsing binary candidates, initially identified by the Kepler mission, overlapped with the radial velocity observations from the SDSS-III Multi-Object APO Radial-Velocity Exoplanet Large-Area Survey (MARVELS). The RV extractions and spectroscopic solutions of these eclipsing binaries were generated by the University of Florida's 1D data pipeline with a median RV precision of ~60-100 m/s, which was utilized for the DR12 data release. We performed the cross-reference fitting of the MARVELS RV data and the Kepler photometric fluxes obtained from the Kepler Eclipsing Binary Catalog (V2) and modelled the 7 eclipsing binaries in the BinaryMaker3 and PHOEBE programs. This analysis accurately determined the absolute physical and orbital parameters of each binary. Most of the companion stars were determined to have masses of K and M dwarf stars (0.3-0.8 M⊙), and allowed for an investigation into the mass-radius relationship of M and K dwarfs. Among the cases are KIC 9163796, a 122.2 day period "heartbeat star", a recently-discovered class of eccentric binaries known for tidal distortions and pulsations, with a high eccentricity (e~0.75) and KIC 11244501, a 0.29 day period, contact binary with a double-lined spectrum and mass ratio (q~0.45). We also report on the possible reclassification of 2 Kepler eclipsing binary candidates as background eclipsing binaries based on the analysis of the flux measurements, flux ratios of the spectroscopic and photometric solutions, the differences in the FOVs, the image processing of Kepler, and RV and spectral analysis of MARVELS.

  8. Volumetric studies of some amino acids in binary aqueous solutions ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 117; Issue 3. Volumetric studies of some amino acids in binary aqueous solutions of MgCl2.6H2O at 288.15, and 308.15 K. Amalendu Pal Suresh Kumar. Volume 117 Issue 3 May 2005 pp 267-273 ...

  9. Existence domains for invariant reactions in binary regular solution ...

    Indian Academy of Sciences (India)

    Home; Journals; Bulletin of Materials Science; Volume 26; Issue 4. Existence domains for invariant reactions in binary regular solution phase diagrams exhibiting two phases. B Nageswara Sarma S Srinivas Prasad S Vijayvergiya V Bharath Kumar S Lele. Biomaterials Volume 26 Issue 4 June 2003 pp 423-430 ...

  10. Volumetric studies of some amino acids in binary aqueous solutions

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 117; Issue 3. Volumetric studies of some amino acids in binary aqueous solutions of MgCl2.6H2O at 288.15, and 308.15 K. Amalendu Pal Suresh Kumar. Volume 117 Issue 3 May 2005 pp 267-273 ...

  11. Existence domains for invariant reactions in binary regular solution ...

    Indian Academy of Sciences (India)

    Unknown

    two phases (e.g. a liquid and a solid phase) has been examined using the regular solution model. The necessary conditions for the ... Binary phase diagrams; invariant reactions; regular solution model. 1. Introduction. Using the regular ...... Nb–Ta, Nb–W, Os–Re, Os–Ru, Pd–Pt, Pt–Rh,. Re–Ru, Ta–W, V–W]. R + T MN [Cr–V, ...

  12. The Cool Surfaces of Binaries Near-Earth Asteroids

    NARCIS (Netherlands)

    Delbo, Marco; Walsh, K.; Mueller, M.

    2008-01-01

    We present results from thermal-infrared observations of binary near-Earth asteroids (NEAs). These objects, in general, have surface temperatures cooler than the average values for non-binary NEAs. We discuss how this may be evidence of higher-than-average surface thermal inertia. The comparison of

  13. The eclipsing binary U Cephei - new observations and solutions

    International Nuclear Information System (INIS)

    Markworth, N.L.

    1979-01-01

    Observations of the interacting eclipsing binary system U Cephei in the standard UBV system were obtained at the Rosemary Hill Observatory of the University of Florida during the most recent period of activity (1974 October until 1976 May). Double coverage of more than 95 per cent of the light curve was obtained. Since analysis of the irregularities in the light curve depends greatly on an accurate geometrical model, three solutions by different techniques were attempted. The D.B. Wood solution failed, since asynchronous rotation of the primary star is not included in the model. Reasonable agreement between the Russell-Merrill and Wilson-Devinney solutions was achieved. (author)

  14. Drag of a growing bubble at rectilinear accelerated ascension in pure liquids and binary solutions

    Directory of Open Access Journals (Sweden)

    Ašković Radomir

    2003-01-01

    Full Text Available The problem of predicting the drag coefficient of a growing bubble at rectilinear accelerated ascension in uniformly super­heated pure liquids and in binary solutions with a non-volatile solute at large Reynolds and Peclet numbers is discussed. In the case of pure liquids, the general solution for the drag coefficient of an accelerated growing bubble from its inception at the critical radius and through the surface-tension-, inertia-, and heat-diffusion-controlled regimes is established, as well as some necessary adaptations in the case of binary solutions with a non-volatile solute. Two particular limiting regimes in the case of pure liquids, inertia-controlled and heat-diffusion-controlled regimes, respectively, are analyzed in details, with satisfactory results. .

  15. Heat and mass transfer at adiabatic evaporation of binary zeotropic solutions

    Science.gov (United States)

    Makarov, M. S.; Makarova, S. N.

    2016-01-01

    Results of numerical simulation of heat and mass transfer in a laminar flow of three-component gas at adiabatic evaporation of binary solutions from a flat plate are presented. The studies were carried out for the perfect solution of ethanol/methanol and zeotrope solutions of water/acetone, benzene/acetone, and ethanol/acetone. The liquid-vapor equilibrium is described by the Raoult law for the ideal solution and Carlson-Colburn model for real solutions. The effect of gas temperature and liquid composition on the heat and diffusion flows, and temperature of vapor-gas mixture at the interface is analyzed. The formula for calculating the temperature of the evaporation surface for the binary liquid mixtures using the similarity of heat and mass transfer was proposed. Data of numerical simulations are in a good agreement with the results of calculations based on the proposed dependence for all examined liquid mixtures in the considered range of temperatures and pressures.

  16. Removal of Reactive Anionic Dyes from Binary Solutions by Adsorption onto Quaternized Kenaf Core Fiber

    OpenAIRE

    Idan, Intidhar Jabir; Jamil, Siti Nurul Ain Binti Md.; Abdullah, Luqman Chuah; Choong, Thomas Shean Yaw

    2017-01-01

    The most challenging mission in wastewater treatment plants is the removal of anionic dyes, because they are water-soluble and produce very shining colours in the water. In this regard, kenaf core fiber (KCF) was chemically modified by the quaternized agent (3-chloro-2-hydroxypropyl)trimethylammonium chloride to increase surface area and change the surface properties in order to improve the removing reactive anionic dyes from binary aqueous solution. The influencing operating factors like dye...

  17. Removal of Reactive Anionic Dyes from Binary Solutions by Adsorption onto Quaternized Kenaf Core Fiber

    Directory of Open Access Journals (Sweden)

    Intidhar Jabir Idan

    2017-01-01

    Full Text Available The most challenging mission in wastewater treatment plants is the removal of anionic dyes, because they are water-soluble and produce very shining colours in the water. In this regard, kenaf core fiber (KCF was chemically modified by the quaternized agent (3-chloro-2-hydroxypropyltrimethylammonium chloride to increase surface area and change the surface properties in order to improve the removing reactive anionic dyes from binary aqueous solution. The influencing operating factors like dye concentration, pH, adsorbent dosage, and contact time were examined in a batch mode. The results indicate that the percentage of removal of Reactive Red-RB (RR-RB and Reactive Black-5 (RB-5 dyes from binary solution was increased with increasing dyes concentrations and the maximum percentage of removal reached up to 98.4% and 99.9% for RR-RB and RB-5, respectively. Studies on effect of pH showed that the adsorption was not significantly influenced by pH. The equilibrium analyses explain that, in spite of the extended Langmuir model failure to describe the data in the binary system, it is better than the Jain and Snoeyink model in describing the adsorption behavior of binary dyes onto QKCF. Also, the pseudo-second-order model was better to represent the adsorption kinetics for RR-RB and RB-5 dyes on QKCF.

  18. Proteins in solution: Fractal surfaces in solutions

    Directory of Open Access Journals (Sweden)

    R. Tscheliessnig

    2016-02-01

    Full Text Available The concept of the surface of a protein in solution, as well of the interface between protein and 'bulk solution', is introduced. The experimental technique of small angle X-ray and neutron scattering is introduced and described briefly. Molecular dynamics simulation, as an appropriate computational tool for studying the hydration shell of proteins, is also discussed. The concept of protein surfaces with fractal dimensions is elaborated. We finish by exposing an experimental (using small angle X-ray scattering and a computer simulation case study, which are meant as demonstrations of the possibilities we have at hand for investigating the delicate interfaces that connect (and divide protein molecules and the neighboring electrolyte solution.

  19. Electrohydrodynamics of binary electrolytes driven by modulated surface potentials

    DEFF Research Database (Denmark)

    Mortensen, Asger; Olesen, Laurits Højgaard; Belmon, L.

    2005-01-01

    We study the electrohydrodynamics of the Debye screening layer that arises in an aqueous binary solution near a planar insulating wall when applying a spatially modulated ac voltage. Combining this with first order perturbation theory we establish the governing equations for the full nonequilibrium...... problem and obtain analytic solutions in the bulk for the pressure and velocity fields of the electrolyte and for the electric potential. We find good agreement between the numerics of the full problem and the analytics of the linear theory. Our work provides the theoretical foundations of circuit models...

  20. Biomimetic superhydrophobic surface of high adhesion fabricated with micronano binary structure on aluminum alloy.

    Science.gov (United States)

    Liu, Yan; Liu, Jindan; Li, Shuyi; Liu, Jiaan; Han, Zhiwu; Ren, Luquan

    2013-09-25

    Triggered by the microstructure characteristics of the surfaces of typical plant leaves such as the petals of red roses, a biomimetic superhydrophobic surface with high adhesion is successfully fabricated on aluminum alloy. The essential procedure is that samples were processed by a laser, then immersed and etched in nitric acid and copper nitrate, and finally modified by DTS (CH3(CH2)11Si(OCH3)3). The obtained surfaces exhibit a binary structure consisting of microscale crater-like pits and nanoscale reticula. The superhydrophobicity can be simultaneously affected by the micronano binary structure and chemical composition of the surface. The contact angle of the superhydrophobic surface reaches up to 158.8 ± 2°. Especially, the surface with micronano binary structure is revealed to be an excellent adhesive property with petal-effect. Moreover, the superhydrophobic surfaces show excellent stability in aqueous solution with a large pH range and after being exposed long-term in air. In this way, the multifunctional biomimetic structural surface of the aluminum alloy is fabricated. Furthermore, the preparation technology in this article provides a new route for other metal materials.

  1. Simple model of surface roughness for binary collision sputtering simulations

    International Nuclear Information System (INIS)

    Lindsey, Sloan J.; Hobler, Gerhard; Maciążek, Dawid; Postawa, Zbigniew

    2017-01-01

    Highlights: • A simple model of surface roughness is proposed. • Its key feature is a linearly varying target density at the surface. • The model can be used in 1D/2D/3D Monte Carlo binary collision simulations. • The model fits well experimental glancing incidence sputtering yield data. - Abstract: It has been shown that surface roughness can strongly influence the sputtering yield – especially at glancing incidence angles where the inclusion of surface roughness leads to an increase in sputtering yields. In this work, we propose a simple one-parameter model (the “density gradient model”) which imitates surface roughness effects. In the model, the target’s atomic density is assumed to vary linearly between the actual material density and zero. The layer width is the sole model parameter. The model has been implemented in the binary collision simulator IMSIL and has been evaluated against various geometric surface models for 5 keV Ga ions impinging an amorphous Si target. To aid the construction of a realistic rough surface topography, we have performed MD simulations of sequential 5 keV Ga impacts on an initially crystalline Si target. We show that our new model effectively reproduces the sputtering yield, with only minor variations in the energy and angular distributions of sputtered particles. The success of the density gradient model is attributed to a reduction of the reflection coefficient – leading to increased sputtering yields, similar in effect to surface roughness.

  2. Thermodynamic Relationship between Enthalpy of Mixing and Excess Entropy in Solid Solutions of Binary Alloys

    OpenAIRE

    Hara, Shigeta; Gokcen, Nev A.; Kumar C. Kumar; Morita, Zen-ichiro; Tanaka, Toshihiro

    1996-01-01

    Thermodynamic relationships between enthalpy of mixing and excess entropy, and partial enthalpy of solution and partial excess entropy in solid solutions of binary alloys have been derived based on the free volume theory. Using the above relations, excess entropy and excess Gibbs energy of solid solutions in Ag-Au, Ag-Pd and Au-Pd binary alloys have been calculated from enthalpy of mixing, and compared with the literature values.

  3. Evaporation dynamics and Marangoni number estimation for sessile picoliter liquid drop of binary mixture solution

    OpenAIRE

    Lebedev-Stepanov Peter; Kobelev Alexander; Efimov Sergey

    2016-01-01

    We propose the evaporation model of picoliter sessile drop of binary solvent mixture (with infinitely soluble in each other components) based on Hu and Larson solution for single solvent sessile drop and Raoult law for saturated vapor density of components of binary mixture in wide range of undimensional molar binary concentration of the components. Concentration Marangoni number estimation for such a system is also considered for prediction of liquid flows structure for further applications ...

  4. Study of surface tension and surface properties of binary alcohol/n-alkyl acetate mixtures.

    Science.gov (United States)

    Rafati, Amir Abbas; Ghasemian, Ensieh

    2008-12-15

    The Butler equation is employed to describe quantitatively the nature, properties, and compositions of surface layers in binary liquid mixtures. Bulk mole fraction, surface molar area, and surface tension of pure components are necessary inputs for this equation. In addition, the UNIFAC group contribution method is applied to account for the nonideality of the bulk liquid as well as that of the surface layer. The average relative error obtained from the comparison of experimental and calculated surface tension values for 12 binary systems is less than 1%. Therefore, the model has good accuracy in comparison with other predictive equations. In addition to finding more information about the surface structure of binary mixtures, surface mole fraction was calculated using relative Gibbs adsorption values and an extended Langmuir model (EL). The obtained results show a good consistency between two models employed, i.e., the Gibbs adsorption model and EL model, based on the UNIFAC method.

  5. Evaporation dynamics and Marangoni number estimation for sessile picoliter liquid drop of binary mixture solution

    Directory of Open Access Journals (Sweden)

    Lebedev-Stepanov Peter

    2016-01-01

    Full Text Available We propose the evaporation model of picoliter sessile drop of binary solvent mixture (with infinitely soluble in each other components based on Hu and Larson solution for single solvent sessile drop and Raoult law for saturated vapor density of components of binary mixture in wide range of undimensional molar binary concentration of the components. Concentration Marangoni number estimation for such a system is also considered for prediction of liquid flows structure for further applications in dissipative particle dynamics in binary mixture evaporating drop.

  6. Surface effect theory in binary alloys: surfaces with cut-off

    International Nuclear Information System (INIS)

    Kumar, V.; Silva, C.E.T.G. da; Moran-Lopez, J.L.

    1981-01-01

    A surface effect theory in binary alloys which ore ordered with surfaces with cut-off is presented. This theory is based in a model of pair interaction between first neighbours and includes long and short range effects. The (120) surface with sup(-) (110) monoatomic cut-off and terrace in the (110) planes of an alloy with body centered cubic structure is presented as example. Results for the concentrations in all the different surface sites are given. (L.C.) [pt

  7. Simple model of surface roughness for binary collision sputtering simulations

    Science.gov (United States)

    Lindsey, Sloan J.; Hobler, Gerhard; Maciążek, Dawid; Postawa, Zbigniew

    2017-02-01

    It has been shown that surface roughness can strongly influence the sputtering yield - especially at glancing incidence angles where the inclusion of surface roughness leads to an increase in sputtering yields. In this work, we propose a simple one-parameter model (the "density gradient model") which imitates surface roughness effects. In the model, the target's atomic density is assumed to vary linearly between the actual material density and zero. The layer width is the sole model parameter. The model has been implemented in the binary collision simulator IMSIL and has been evaluated against various geometric surface models for 5 keV Ga ions impinging an amorphous Si target. To aid the construction of a realistic rough surface topography, we have performed MD simulations of sequential 5 keV Ga impacts on an initially crystalline Si target. We show that our new model effectively reproduces the sputtering yield, with only minor variations in the energy and angular distributions of sputtered particles. The success of the density gradient model is attributed to a reduction of the reflection coefficient - leading to increased sputtering yields, similar in effect to surface roughness.

  8. Binary integer programming solution for troubleshooting with dependent actions

    Czech Academy of Sciences Publication Activity Database

    Lín, Václav

    2017-01-01

    Roč. 53, č. 3 (2017), s. 493-512 ISSN 0023-5954 R&D Projects: GA ČR GA13-20012S Institutional support: RVO:67985556 Keywords : binary integer programming * decision-theoretic troubleshooting Subject RIV: JD - Computer Applications, Robotics OBOR OECD: Computer sciences, information science, bioinformathics (hardware development to be 2.2, social aspect to be 5.8) Impact factor: 0.379, year: 2016 http://library.utia.cas.cz/separaty/2017/MTR/lin-0476547.pdf

  9. New binary travelling-wave periodic solutions for the modified KdV equation

    International Nuclear Information System (INIS)

    Yan Zhenya

    2008-01-01

    In this Letter, the modified Korteweg-de Vries (mKdV) equations with the focusing (+) and defocusing (-) branches are investigated, respectively. Many new types of binary travelling-wave periodic solutions are obtained for the mKdV equation in terms of Jacobi elliptic functions such as sn(ξ,m)cn(ξ,m)dn(ξ,m) and their extensions. Moreover, we analyze asymptotic properties of some solutions. In addition, with the aid of the Miura transformation, we also give the corresponding binary travelling-wave periodic solutions of KdV equation

  10. Effect of system variables involved in packed column SFC of nevirapine as model analyte using response surface methodology: application to retention thermodynamics, solute transfer kinetic study and binary diffusion coefficient determination.

    Science.gov (United States)

    Kaul, Neerej; Agrawal, Himani; Paradkar, A R; Mahadik, K R

    2005-08-31

    A multifactor optimization technique is successfully applied to study the effect of simultaneously varying the system variables on feasibility of nevirapine analysis by packed column supercritical fluid chromatography (PC-SFC). The optimal conditions were determined with the aid of the response surface methodology using 3(3) factorial designs. The method is based on methanol-modified carbon dioxide as the mobile phase at flow rate of 3.0 ml/min with elution through a JASCO Finepak SIL-5, [C18 (5-micron, 25 cm x 4.6 mm, i.d.)] column using photodiode array detection. The method has been successfully used to analyze commercial solid dosage form to assess the chromatographic performance of SFC system. The present work briefs the thermodynamic applications of PC-SFC with an emphasis on the results of nevirapine. The foremost of such applications is the determination of solute diffusion coefficient in supercritical mobile phase by Taylor-Aris peak broadening technique.

  11. Liquid-liquid equilibria for binary and ternary polymer solutions with PC-SAFT

    DEFF Research Database (Denmark)

    Lindvig, Thomas; Michelsen, Michael Locht; Kontogeorgis, Georgios

    2004-01-01

    are used for investigating the correlative and predictive capabilities of the thermodynamic model PC-SAFT. The investigation shows that the model correlates well experimental LLE data for binary as well as ternary systems but further predicts the behavior of the ternary systems with reasonably good......Two algorithms for evaluating liquid-liquid equilibria (LLE) for binary and ternary polymer solutions are presented. The binary algorithm provides the temperature versus concentration cloud-point curve at fixed pressure, whereas the ternary algorithm provides component 1 versus component 2...

  12. Thermodynamic Modeling of Surface Tension of Aqueous Electrolyte Solution by Competitive Adsorption Model

    Directory of Open Access Journals (Sweden)

    Mohamad Javad Kamali

    2015-01-01

    Full Text Available Thermodynamic modeling of surface tension of different electrolyte systems in presence of gas phase is studied. Using the solid-liquid equilibrium, Langmuir gas-solid adsorption, and ENRTL activity coefficient model, the surface tension of electrolyte solutions is calculated. The new model has two adjustable parameters which could be determined by fitting the experimental surface tension of binary aqueous electrolyte solution in single temperature. Then the values of surface tension for other temperatures in binary and ternary system of aqueous electrolyte solution are predicted. The average absolute deviations for calculation of surface tension of binary and mixed electrolyte systems by new model are 1.98 and 1.70%, respectively.

  13. Surface Tension of Nonideal Binary Liquid Mixtures as a Function of Composition.

    Science.gov (United States)

    Nath

    1999-01-01

    The composition dependence of the surface tension of highly nonideal organic-organic and aqueous-organic nonelectrolyte solutions is described, based on the assumption that the surface layer can be treated as a separate phase located between vapor and bulk liquid phases. The Wilson, NRTL, and UNIFAC methods are used for activity coefficients of surface and bulk phases and three techniques for calculation of molar surface areas, based on Paquette areas, Rasmussen areas, and a Langmuir-type approach are tested. Comparisons of the calculated surface tensions with experimental data yield mean absolute errors, in the best case, of less than 2.5% for the systems studied, all of which exhibit highly nonideal behavior. The surface tension predictions are found to be extremely sensitive to the values of the molar surface areas used in the computation. A Langmuir-type adsorption model is formulated to determine the surface mole fractions from a knowledge of the mixture surface tension as a function of bulk composition. A novel procedure is developed to obtain the partial molar surface area of the larger organic component as a function of composition in binary aqueous-organic systems, assuming that the two components are very dissimilar in size, and that deviations in the partial molar surface area of the smaller component (water) from its pure component molar surface area contribute negligibly to the total molar surface area of the mixture. This removes the approximation of equality of partial and pure component molar surface area for the larger organic component. Use of the Langmuir-type approach with partial molar surface areas improves surface tension predictions of highly nonideal aqueous-organic mixtures by 20% over use of pure component molar surface areas. It is an important first step in the development of a thermodynamically consistent theory of surfaces for liquid mixtures based on an accurate determination of the composition dependence of partial molar surface

  14. Adsorption of Geosmin and MIB on Activated Carbon Fibers-Single and Binary Solute System

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, Rangesh; Sorial, George A., E-mail: george.sorial@uc.ed [University of Cincinnati, Department of Civil and Environmental Engineering (United States)

    2009-08-15

    The adsorption of two taste- and odor-causing compounds, namely MIB (2-methyl isoborneol-C{sub 11}H{sub 20}O) and geosmin (C{sub 12}H{sub 22}O) on activated carbon was investigated in this study. The impact of adsorbent pore size distribution on adsorption of MIB and geosmin was evaluated through single solute and multicomponent adsorption of these compounds on three types of activated carbon fibers (ACFs) and one granular activated carbon (GAC). The ACFs (ACC-15, ACC-20, and ACC-25) with different degrees of activation had narrow pore size distributions and specific critical pore diameters whereas the GAC (F-400) had a wider pore size distribution and lesser microporosity. The effect of the presence of natural organic matter (NOM) on MIB and geosmin adsorption was also studied for both the single solute and binary systems. The Myers equation was used to evaluate the single solute isotherms as it converges to Henry's law at low coverage and also serves as an input for predicting multicomponent adsorption. The single solute adsorption isotherms fit the Myers equation well and pore size distribution significantly influenced adsorption on the ACFs and GAC. The ideal adsorbed solute theory (IAST), which is a well-established thermodynamic model for multicomponent adsorption, was used to predict the binary adsorption of MIB and geosmin. The IAST predicted well the binary adsorption on the ACFs and GAC. Binary adsorption isotherms were also conducted in the presence of oxygen (oxic) and absence of oxygen (anoxic). There were no significant differences in the binary isotherm between the oxic and anoxic conditions, indicating that adsorption was purely through physical adsorption and no oligomerization was taking place. Binary adsorptions for the four adsorbents were also conducted in the presence of humic acid to determine the effect of NOM and to compare with IAST predictions. The presence of NOM interestingly resulted in deviation from IAST behavior in case of two

  15. Light Curve Solutions of Eclipsing Binaries in the Large Magellanic Cloud

    Science.gov (United States)

    Rawls, Meredith L.; Rao, M. S.

    2012-01-01

    We present model light curves for nine eclipsing binary stars in the Large Magellanic Cloud (LMC). These systems are detached binaries with nearly circular orbits, and were pseudorandomly selected from three of 21 LMC regions in the Optical Gravitational Lensing Experiment II (OGLE-II) survey. We make use of light curves, orbital periods, and binary classification as reported in Wyrzykowski et al. (2003). We present light curve solutions created with the software PHysics Of Eclipsing BinariEs (PHOEBE, Prsa & Zwitter 2005). Each solution has the best-fit mass ratio q, system inclination i, component temperatures T1 and T2, and modified Kopal potentials Ω1 and Ω2. PHOEBE employs a Nelder & Mead's Simplex fitting method that adjusts all the input parameters to find the best fit to the light curve. Many of the light curves have significant scatter, which can lead to multiple degenerate best-fit solutions, and we discuss what can be done in the future to refine our results, derive global stellar parameters, and place these nine systems in a larger context. We acknowledge the support of the International Research Experience for Students (IRES) program, which is sponsored by the NSF and administered by NSO/GONG.

  16. First Principles Calculations of Transition Metal Binary Alloys: Phase Stability and Surface Effects

    Science.gov (United States)

    Aspera, Susan Meñez; Arevalo, Ryan Lacdao; Shimizu, Koji; Kishida, Ryo; Kojima, Kazuki; Linh, Nguyen Hoang; Nakanishi, Hiroshi; Kasai, Hideaki

    2017-06-01

    The phase stability and surface effects on binary transition metal nano-alloy systems were investigated using density functional theory-based first principles calculations. In this study, we evaluated the cohesive and alloying energies of six binary metal alloy bulk systems that sample each type of alloys according to miscibility, i.e., Au-Ag and Pd-Ag for the solid solution-type alloys (SS), Pd-Ir and Pd-Rh for the high-temperature solid solution-type alloys (HTSS), and Au-Ir and Ag-Rh for the phase-separation (PS)-type alloys. Our results and analysis show consistency with experimental observations on the type of materials in the bulk phase. Varying the lattice parameter was also shown to have an effect on the stability of the bulk mixed alloy system. It was observed, particularly for the PS- and HTSS-type materials, that mixing gains energy from the increasing lattice constant. We furthermore evaluated the surface effects, which is an important factor to consider for nanoparticle-sized alloys, through analysis of the (001) and (111) surface facets. We found that the stability of the surface depends on the optimization of atomic positions and segregation of atoms near/at the surface, particularly for the HTSS and the PS types of metal alloys. Furthermore, the increase in energy for mixing atoms at the interface of the atomic boundaries of PS- and HTSS-type materials is low enough to overcome by the gain in energy through entropy. These, therefore, are the main proponents for the possibility of mixing alloys near the surface.

  17. Volumetric studies of some amino acids in binary aqueous solutions ...

    Indian Academy of Sciences (India)

    Unknown

    partial molar volumes (Vφ. 0) of each amino acid have been calculated. These data were combined with the earlier reported Vφ. 0 values of glycine, L-alanine, and L-valine in aqueous MgCl2⋅6H2O solutions at. 298⋅15 K in order to describe the temperature dependence behaviour of partial molar quantities. Group.

  18. Light Curve Solution of the Contact Binary AW UMa

    Directory of Open Access Journals (Sweden)

    J. H. Jeong

    1997-12-01

    Full Text Available A total of 1088 observations (272 in B,272 in V, 272 in R, and 272 in I were made from January to February in 1995 at Chungbuk National University observatory(CbNUO. We constructed BVRI light curves with our data. The photometric solution of these light curves was obtained by means of the Wilson-Devinney method. Our result was compared with those by previous investigators.

  19. Volumetric studies of some amino acids in binary aqueous solutions ...

    Indian Academy of Sciences (India)

    Unknown

    0 values of glycine, L-alanine, and L-valine in aqueous MgCl2⋅6H2O solutions at. 298⋅15 K in order to describe the temperature dependence behaviour of partial molar quantities. Group contributions to partial molar volumes have been determined for the amino acids. The trends of transfer volumes (∆Vφ. 0) have been ...

  20. The K spectral type contact binary NSVS 1557555: Photometric solution and preliminary elements

    Science.gov (United States)

    Barani, C.; Acerbi, F.; Martignoni, M.

    2017-11-01

    We present the first CCD sets of complete light curves for the W Ursae Majoris system NSVS 1557555. The observations were performed in the B, V and Ic bands using the 0.25 m telescope of the Stazione Astronomica Betelgeuse Northern Italy, during 8 nights in October and November 2016. Based on our new eleven Time of Minima (ToM), and two recent ones found in bibliography, the short orbital period of the system is confirmed and revised to P = 0.2725163 days . A reasonable fit of the synthetic light curves of the data indicate that NSVS 1557555 is a late-type (K1+K3) shallow contact binary system of W-Subtype of the W Ursae Majoris systems, with a mass ratio of q = 1.8, a degree of contact factor f = 12.5%, a temperature difference between the components of 240K and inclination i = 85°. The light curves show asymmetries at the maxima with the maximum at phase 0.75 higher the other one (inverse O'Connell effect). To explain the light asymmetries we used a model that involves an hot spotted region on the surface of the cooler star. The definitive solution is only possible with a large amount of third light (L3 = 0.58 in B Filter). It may come from a hot tertiary component. The absolute dimensions of the system are estimated. From the logM-logL diagram it is seen that both components of NSVS 1557555 follow the general pattern of the W subtype W Ursae Majoris systems. The orbital angular momentum is compared with those of other W UMa type binaries and is normal.

  1. (Liquid plus liquid) equilibria of binary polymer solutions using a free-volume UNIQUAC-NRF model

    DEFF Research Database (Denmark)

    Radfarnia, H.R.; Ghotbi, C.; Taghikhani, V.

    2006-01-01

    + liquid) equilibria (LLE) for a number of binary polymer solutions at various temperatures. The values for the binary characteristic energy parameters for the proposed model and the FV-UNIQUAC model along with their average relative deviations from the experimental data were reported. It should be stated...... that the binary polymer solutions studied in this work were considered as monodisperse. The results obtained from the FV-UNIQUAC-NRF model were compared with those obtained from the FV-UNIQUAC model. The results of the proposed model show that the FV-UNIQUAC-NRF model can accurately correlate the experimental...... in predicting the LCST for binary polymer solutions....

  2. Effect of temperature and composition on the surface tension and surface properties of binary mixtures containing DMSO and short chain alcohols

    International Nuclear Information System (INIS)

    Bagheri, Ahmad; Fazli, Mostafa; Bakhshaei, Malihe

    2016-01-01

    Highlights: • Surface tension of DMSO + alcohol (methanol, ethanol and isopropanol) at various temperatures was measured. • The surface tension data of binary mixtures were correlated with four equations. • Intermolecular interaction of DMSO with alcohol was discussed. • The surface mole fraction of alcohol increase with increasing the length of alcohol chain. - Abstract: Surface tension of binary mixtures of methanol, ethanol and isopropanol with DMSO (dimethyl sulfoxide) was measured over the whole range of composition at atmospheric pressure of 82.5 kPa within the temperatures between (298.15 and 328.15) K. The experimental measurements were used to calculate in surface tension deviations (Δσ). The sign of Δσ for all temperatures is negative (except of methanol/DMSO system) because of the factors of hydrogen bonding and dipole–dipole interactions in the DMSO-alcohol systems. Surface tension values of the binary systems were correlated with FLW, MS, RK and LWW models. The mean standard deviation obtained from the comparison of experimental and calculated surface tension values for binary systems with three models (FLW, MS and RK) at various temperatures is less than 0.83. Also, the results of the LWW model were used to account for the interaction energy between alcohols and DMSO in binary mixtures. The temperature dependence of σ (surface tension) at fixed composition of solutions was used to estimate surface enthalpy, H s , and surface entropy, S s . The results obtained show that the values of the thermodynamic parameters for alcohol/DMSO mixtures decrease with increasing alkyl chain length of alcohol. Finally, the results are discussed in terms of surface mole fraction and lyophobicity using the extended Langmuir (EL) isotherm.

  3. Evaluation of a filling system for binary pediatric solutions.

    Science.gov (United States)

    Combeau, D; Rey, J B; Fontan, J E; Arnaud, P; Brion, F

    1998-02-01

    The aim of this study was to assess the use of an automatic filling system (Siframix M31 and M32 system) to prepare pediatric parenteral nutrition. Volumetric accuracy was measured for each siframix system loads cells (bottles during the filling operation modify the accuracy (p = 0.004 for 20 ml and p = 0.009 for 500 ml). A flushing operation is necessary to lower the risk of electrolytic pollution for the filling of little bags. The filling speed for each module was also measured (the maximal filling speed was five liters per minute). The Siframix system allows one to prepare pediatric parenteral nutrition bags when volumes are above 4 ml and with adapted source solutions in terms of concentration and conditioning volumes.

  4. Observations and light curve solutions of four ultrashort-period binaries

    Directory of Open Access Journals (Sweden)

    Kjurkchieva D.

    2016-01-01

    Full Text Available The paper presents light curve solutions of our observations of four new ultrashort-period eclipsing binaries with MS components. Two of them have periods almost at the upper limit (0.22 days of the ultrashort-period binaries, while the periods of around 0.18 days of CSS J171508.5+350658 and CSS J214633.8+120016 are amongst the shortest known orbital periods. CSS J171410.0+ 445850, CSS J214633.8+120016 and CSS J224326.0+154532 are over contact binaries with fill out factors around 0.25 while CSS J171508.5+350658 is a semidetached system. The two targets with shortest periods consist of M dwarfs.

  5. Surface tension of aqueous electrolyte solutions. Thermodynamics

    NARCIS (Netherlands)

    Drzymala, J.; Lyklema, J.

    2012-01-01

    A thermodynamic theory is developed for obtaining the enthalpic and entropic contributions to the surface excess Gibbs energy of electrolyte solutions from the dependence of the surface tension on concentration and temperature. For elaboration, accurate activity coefficients in solution as functions

  6. Polarographic behaviour and determination of selenite and tellurite in simple solutions or in a binary mixture

    International Nuclear Information System (INIS)

    Hassan, A.

    1991-01-01

    The polarographic behaviour of simple solutions of selenite and tellurite in 1 M ammonium salts of formate, acetate, tartrate, oxalate, and benzoate solutions in absence and in presence of Triton X-100 as a maximum suppressor and a temperature of 25 O C has been investigated. Schemes for the mechanism of reductions occuring at the DME have been deduced. A method for analytical determination of selenite and tellurite in simple solutions as well as in a binary mixture in the presence of 4-14 . 10 -3 % Triton X-100 is reported. (author)

  7. Enthalpies of solution of ampicillin, amoxycillin and their binary mixtures at 310.15 K.

    Science.gov (United States)

    Jain, D V; Kashid, N; Kapoor, S; Chadha, R

    2000-05-15

    Enthalpies of solutions of ampicillin, amoxycillin and their binary mixtures have been determined at pH 2, 5, and 7 using C-80 calorimeter. The systems showed endothermic behaviour; molar enthalpies of solutions of ampicillin were determined to be 13.32, 15.89 and 23.21 kJ mol(-1) and amoxycillin were 16.32, 18.45 and 26. 25 kJ mol(-1) at pH 2, 5, and 7, respectively. The excess molar enthalpies of solution have also been calculated to find any interaction between these two drugs.

  8. Analytic vortex solutions on compact hyperbolic surfaces

    International Nuclear Information System (INIS)

    Maldonado, Rafael; Manton, Nicholas S

    2015-01-01

    We construct, for the first time, abelian Higgs vortices on certain compact surfaces of constant negative curvature. Such surfaces are represented by a tessellation of the hyperbolic plane by regular polygons. The Higgs field is given implicitly in terms of Schwarz triangle functions and analytic solutions are available for certain highly symmetric configurations. (paper)

  9. Adsorptive removal of acid blue 113 and tartrazine by fly ash from single and binary dye solutions

    Energy Technology Data Exchange (ETDEWEB)

    Pura, S.; Atun, G. [Istanbul University, Avcilar (Turkey). Dept. of Chemistry

    2009-07-01

    Adsorption of two acid dyestuffs, acid blue 113 (AB) and tartrazine (TA), has been studied from their single and binary solutions by using fly ash (FA) as an adsorbent. The S shaped isotherms observed for dye adsorption from single solutions show that both acid dyes are not preferred at a low concentration region whereas adsorption of the dyes from binary solutions is enhanced via solute-solute interactions. Although the L-shaped isotherm is observed in binary solutions adsorbability of AB decreases in concentrated solutions with respect to single one, time dependency of adsorption is well described with a pseudo-second-order kinetic model as well as the linear relation of Bt vs. t plots (not passing through origin) indicates that film diffusion is effective on dye adsorption. Modeled isotherm curves using isotherm parameters of the Freundlich and Dubinin-Radushkevich (D-R) equations adequately fit to experimental equilibrium data. Equilibrium adsorption of AB in binary solutions has been quite well predicted by the extended Freundlich and the Sheindorf-Rebuhn-Sheintuch (SRS) models. In general, the isotherm curves constructed in the temperature range of 298-328K show that the optimum temperature is 318K for AB removal from both single and binary solutions.

  10. Freezing mechanisms of aqueous binary solution on the oscillating vertical cooled plate

    Energy Technology Data Exchange (ETDEWEB)

    Kawabe, Hiromichi; Fukusako, Shoichiro; Yamada, Masahiko; Yanagida, Koki

    1999-07-01

    An experimental and analytical study concerning the freezing characteristics of aqueous binary solution on the oscillating cooled wall was conducted for the purpose of establishment of the continuous production method of slush ice. Ethylene glycol solution was adopted as the test fluid and froze on a vertical cooled plate with an oscillation motion in a vessel. Experiments were carried out for a variety of conditions such as initial concentration of solution, oscillating acceleration, and stroke of the motion. As a result, it was found that the frozen layer being formed on the cooled plate continuously separated from it under the appropriate conditions. Furthermore, the condition range where the continuous production of slush ice may be available was well predicted by using the present analytical results. The experimental setup is depicted in Figure A-1. The essential components of the apparatus are the test section, a cooling brine circulation loop, and associated instrumentation. Figure A-2 presents the continuous production range of slush ice, in which the ordinate is the maximum acceleration of the cooled plate and the abscissa denotes the initial concentration of aqueous binary solution. It is evident from the figure that the tendency of the production range of slush ice obtained by the present analysis well predicts the experimental results.

  11. Solidification of a binary alloy: Finite-element, single-domain simulation and new benchmark solutions

    Science.gov (United States)

    Le Bars, Michael; Worster, M. Grae

    2006-07-01

    A finite-element simulation of binary alloy solidification based on a single-domain formulation is presented and tested. Resolution of phase change is first checked by comparison with the analytical results of Worster [M.G. Worster, Solidification of an alloy from a cooled boundary, J. Fluid Mech. 167 (1986) 481-501] for purely diffusive solidification. Fluid dynamical processes without phase change are then tested by comparison with previous numerical studies of thermal convection in a pure fluid [G. de Vahl Davis, Natural convection of air in a square cavity: a bench mark numerical solution, Int. J. Numer. Meth. Fluids 3 (1983) 249-264; D.A. Mayne, A.S. Usmani, M. Crapper, h-adaptive finite element solution of high Rayleigh number thermally driven cavity problem, Int. J. Numer. Meth. Heat Fluid Flow 10 (2000) 598-615; D.C. Wan, B.S.V. Patnaik, G.W. Wei, A new benchmark quality solution for the buoyancy driven cavity by discrete singular convolution, Numer. Heat Transf. 40 (2001) 199-228], in a porous medium with a constant porosity [G. Lauriat, V. Prasad, Non-darcian effects on natural convection in a vertical porous enclosure, Int. J. Heat Mass Transf. 32 (1989) 2135-2148; P. Nithiarasu, K.N. Seetharamu, T. Sundararajan, Natural convective heat transfer in an enclosure filled with fluid saturated variable porosity medium, Int. J. Heat Mass Transf. 40 (1997) 3955-3967] and in a mixed liquid-porous medium with a spatially variable porosity [P. Nithiarasu, K.N. Seetharamu, T. Sundararajan, Natural convective heat transfer in an enclosure filled with fluid saturated variable porosity medium, Int. J. Heat Mass Transf. 40 (1997) 3955-3967; N. Zabaras, D. Samanta, A stabilized volume-averaging finite element method for flow in porous media and binary alloy solidification processes, Int. J. Numer. Meth. Eng. 60 (2004) 1103-1138]. Finally, new benchmark solutions for simultaneous flow through both fluid and porous domains and for convective solidification processes are

  12. Spectroscopic and time domain reflectometry studies on acetonitrile - Ethylene glycol binary solutions

    Science.gov (United States)

    Mahendraprabu, A.; Kumbharkhane, A. C.; Joshi, Y. S.; Shaikh, S. S.; Kannan, P. P.; Karthick, N. K.; Arivazhagan, G.

    2017-05-01

    Spectroscopic (FTIR and 13C NMR) and time domain reflectometry (in the frequency range from 10 MHz to 25 GHz) studies have been carried out on the binary solutions of acetonitrile (AN) with ethylene glycol (EG). The presence of EG-EG multimers of various orders in neat EG has been confirmed by spectroscopic studies. AN-EG association through the formation of ∁ ≡ N ⋯ H - O , ∁ ≡ N ⋯ H - C(EG) and (EG) C - O ⋯ H - C(AN) hydrogen bonds have been identified using spectral studies. The principal relaxation process of the heteromolecular entities that involve higher order alcohol association in ethylene glycol rich solutions is found to be relatively slower than that in acetonitrile rich solutions in which lower order alcohol association involves in heterointeraction. The angular correlation among the dipoles appears to be described more precisely when the experimental ε∞ values rather than ε∞ =n2 are used for the calculation of geff .

  13. Thermodynamic principles of classification of binary concentrated aqueous solutions of electrolytes

    International Nuclear Information System (INIS)

    Andreeva, T.A.

    1985-01-01

    A classification of binary concentrated solutions of electrolytes is proposed. The classification is based on the data on thermodynamic and kinetic properties of solutions, on solution structure as well as on the data of theoretical analysis of the electrolyte particle aggregation processes. Concentrated electrolyte solutions are divided into two groups. The first group includes solutions with amorphous structure (electrolytes: CsNO 3 , CsCl, Cs 2 sub(2)SOsub(y), Sr(NO 3 ) 2 xnH 2 O (n=1.4) etc.) for which low values of thermodynamic activity and of activity coefficients are characteristic. The first group electrolyte solubility exceeds the calculated one in case of ideal solution. Solutions with cluster structure (electrolytes: CdNO 3 ) 2 x4H 2 O, UO 2 (NO 3 ) 2 x6H 2 O, SrCl 2 x6H 2 O, BeSO 4 x4H 2 O, etc.) with high values thermodynamic activity and of activity coefficients and with olower solubility in water in comparison with the calculated one, are referred to the second group

  14. Dilational surface rheology of polymer solutions

    International Nuclear Information System (INIS)

    Noskov, B A; Bykov, A G

    2015-01-01

    The review concerns main achievements in dilational rheology of polymer adsorption films at the gas/liquid interfaces reported in the last fifteen years. The theoretical foundations of methods of surface rheology and the key results obtained in studies of solutions of amphiphilic nonionic polymers, polyelectrolytes, proteins and their complexes with low-molecular-mass surfactants are discussed. Interest in the surface dilational rheology is mainly caused by a small number of available experimental methods for investigation of the surface of liquids, by the fact that traditional methods of measurement of the surface tension that are widely used in studies of solutions of low-molecular-mass surfactants provide little information when applied to polymer solutions owing to very slow establishment of equilibrium as well as by weak dependence of the surface tension on the polymer concentration. Progress in the surface rheology is driven by the recent studies of the stability of foams and emulsions that demonstrated a key role of the dilational surface rheological properties in the dynamics of liquid-phase disperse systems. The bibliography includes 191 references

  15. Surge-Resistant Nanocomposite Enameled Wire Using Silica Nanoparticles with Binary Chemical Compositions on the Surface

    OpenAIRE

    Jeseung Yoo; Yongbeom Kim; Suyong Kwon; Joohyun Lee; Young-Soo Seo

    2015-01-01

    We developed polyesterimide (PEI) nanocomposite enameled wires using surface-modified silica nanoparticles with binary chemical compositions on the surface. The modification was done using silanes assisted by ultrasound, which facilitated high density modification. Two different trimethoxysilanes were chosen for the modification on the basis of resemblance of chemical compositions on the silica surface to PEI varnish. The surface-modified silica was well dispersed in PEI varnish, which was co...

  16. Numerical simulation of binary collisions using a modified surface tension model with particle method

    International Nuclear Information System (INIS)

    Sun Zhongguo; Xi Guang; Chen Xi

    2009-01-01

    The binary collision of liquid droplets is of both practical importance and fundamental value in computational fluid mechanics. We present a modified surface tension model within the moving particle semi-implicit (MPS) method, and carry out two-dimensional simulations to investigate the mechanisms of coalescence and separation of the droplets during binary collision. The modified surface tension model improves accuracy and convergence. A mechanism map is established for various possible deformation pathways encountered during binary collision, as the impact speed is varied; a new pathway is reported when the collision speed is critical. In addition, eccentric collisions are simulated and the effect of the rotation of coalesced particle is explored. The results qualitatively agree with experiments and the numerical protocol may find applications in studying free surface flows and interface deformation

  17. Single and binary adsorption of heavy metal ions from aqueous solutions using sugarcane cellulose-based adsorbent.

    Science.gov (United States)

    Wang, Futao; Pan, Yuanfeng; Cai, Pingxiong; Guo, Tianxiang; Xiao, Huining

    2017-10-01

    A high efficient and eco-friendly sugarcane cellulose-based adsorbent was prepared in an attempt to remove Pb 2+ , Cu 2+ and Zn 2+ from aqueous solutions. The effects of initial concentration of heavy metal ions and temperature on the adsorption capacity of the bioadsorbent were investigated. The adsorption isotherms showed that the adsorption of Pb 2+ , Cu 2+ and Zn 2+ followed the Langmuir model and the maximum adsorptions were as high as 558.9, 446.2 and 363.3mg·g -1 , respectively, in single component system. The binary component system was better described with the competitive Langmuir isotherm model. The three dimensional sorption surface of binary component system demonstrated that the presence of Pb 2+ decreased the sorption of Cu 2+ , but the adsorption amount of other metal ions was not affected. The result from SEM-EDAX revealed that the adsorption of metal ions on bioadsorbent was mainly driven by coordination, ion exchange and electrostatic association. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Photocatalytic Solutions Create Self-Cleaning Surfaces

    Science.gov (United States)

    2013-01-01

    A Stennis Space Center researcher investigating the effectiveness of photocatalytic materials for keeping the Center's buildings free of grime turned to a solution created by PURETi Inc. of New York City. Testing proved successful, and NASA and the company now share a Dual Use Technology partnership. PURETi's coatings keep surfaces clean and purify surrounding air, eliminating pollution, odors, and microbes.

  19. A metallic solution model with adjustable parameter for describing ternary thermodynamic properties from its binary constituents

    International Nuclear Information System (INIS)

    Fang Zheng; Qiu Guanzhou

    2007-01-01

    A metallic solution model with adjustable parameter k has been developed to predict thermodynamic properties of ternary systems from those of its constituent three binaries. In the present model, the excess Gibbs free energy for a ternary mixture is expressed as a weighted probability sum of those of binaries and the k value is determined based on an assumption that the ternary interaction generally strengthens the mixing effects for metallic solutions with weak interaction, making the Gibbs free energy of mixing of the ternary system more negative than that before considering the interaction. This point is never considered in the models currently reported, where the only difference in a geometrical definition of molar values of components is considered that do not involve thermodynamic principles but are completely empirical. The current model describes the results of experiments very well, and by adjusting the k value also agrees with those from models used widely in the literature. Three ternary systems, Mg-Cu-Ni, Zn-In-Cd, and Cd-Bi-Pb are recalculated to demonstrate the method of determining k and the precision of the model. The results of the calculations, especially those in Mg-Cu-Ni system, are better than those predicted by the current models in the literature

  20. Photochemical Reaction Between 1,2-Naphthoquinone and Adenine in Binary Water-Acetonitrile Solutions.

    Science.gov (United States)

    Zhou, Qiaohui; Wei, Yaxiong; Liu, Xiang; Chen, Lin; Zhou, Xiaoguo; Liu, Shilin

    2018-01-01

    The photochemical reaction between 1,2-naphthoquinone (NQ) and adenine was investigated using nanosecond time-resolved laser flash photolysis. With photolysis at 355 nm, the lowest triplet state T 1 of NQ was produced via intersystem crossing from its singlet excited state. The triplet-triplet absorption of the state contributes three bands of transient spectra at 374, 596 and 650 nm, respectively, in pure acetonitrile and binary water-acetonitrile solutions. In the presence of adenine, the observation of A· + (at 363 nm) and NQ+H· radical (at 343 and 485 nm) indicates a multistep mechanism of electron transfer process followed by a proton transfer between 3 NQ* and adenine. By fitting with the Stern-Volmer relationship, the quenching rate constant k q of 3 NQ* by adenine in binary water-acetonitrile solutions (4/1, volume ratio, v/v) is determined as 1.66 × 10 9  m -1  s -1 . Additionally, no spectral evidence confirms the existence of electron transfer between 3 NQ* with thymine, cytosine and uracil. © 2017 The American Society of Photobiology.

  1. Molecular interaction forces in acetone + ethanol binary liquid solutions: FTIR and theoretical studies

    Science.gov (United States)

    Jadhav, Deepali L.; Karthick, N. K.; Kannan, P. P.; Shanmugam, R.; Elangovan, A.; Arivazhagan, G.

    2017-02-01

    FTIR spectra of neat acetone, ethanol and their binary solutions at the molar ratios 0.2:0.8 (ethanol: acetone), 0.4:0.6, 0.6:0.4 and 0.8:0.2 have been recorded at room temperature. Theoretical calculations have also been made on acetone (monomer and dimer), ethanol monomer, dimer, trimer, tetramer, pentamer, hexamer and ethanol - acetone complex molecules. 4:1 (ethanol:acetone), 5:1 and 6:2 complexation through the classical Cdbnd O⋯Hsbnd O and (acetone) Csbnd H⋯Osbnd C(ethanol) hydrogen bonds has been identified. Ethanol rich solutions may consist of ethanol multimers such as tetramer, pentamer and hexamer along with 4:1, 5:1 and 6:2 complex molecules depending upon ethanol concentration. Acetone seems to exist as a mixture of monomer and dimer.

  2. Effects of radiation pressure on the equipotential surfaces in x-ray binaries

    International Nuclear Information System (INIS)

    Kondo, Y.; McCluskey, G.E. Jr.; Gulden, S.L.

    1976-01-01

    Equipotential surfaces incorporating the effect of radiation pressure were computed for the x-ray binaries Cen X-3, Cyg X-1 = HDE 226868, Vela XR-1 = 3U 0900-40 = HD 77581, and 3U 1700-37 = HD 153919. The topology of the equipotential surfaces is significantly affected by radiation pressure. In particular, the so-called critical Roche (Jacobian) lobes, the traditional figure 8's, do not exist. The effects of these results on modeling x-ray binaries are discussed

  3. Study of the local structure of binary surfaces by electron diffraction (XPS, LEED)

    OpenAIRE

    Gereová, Katarína

    2006-01-01

    Study of local structure of binary surface with usage of ultra-thin film of cerium deposited on a Pd (111) single-crystal surface is presented. X-ray photoelectron spectroscopy and diffraction (XPS, XPD), angle resolved UV photoemission spectroscopy (ARUPS) and low energy electron diffraction (LEED) was used for our investigations. LEED and X-ray excited photoemission intensities results represent a surface-geometrical structure. As well, mapping of ultra-violet photoelectron intensities as a...

  4. Orbital Solution for the Spectroscopic Binary in the GW Ori Hierarchical Triple

    Science.gov (United States)

    Prato, L.; Ruíz-Rodríguez, Dary; Wasserman, L. H.

    2018-01-01

    We present the first double-lined orbital solution for the close binary in the GW Ori triple system. Using 12 epochs of infrared spectroscopy, we detected the lines of both stars in the inner pair, previously known as single-lined only. Our preliminary infrared orbital solution has an eccentricity of e = 0.21 ± 0.10, a period of P = 241.15 ± 0.72 days, and a mass ratio of q = 0.66 ± 0.13. We find a larger semi-amplitude for the primary star, K1 = 6.57 ± 1.00 km s‑1, with an infrared-only solution compared to K1 = 4.41 ± 0.33 km s‑1 with optical data from the literature, likely the result of line blending and veiling in the optical. The component spectral types correspond to G3 and K0 stars, with v\\sin i values of 43 km s‑1 and 50 km s‑1, respectively. We obtained a flux ratio of α = 0.58 ± 0.14 in the H-band, allowing us to estimate individual masses of 3.2 and 2.7 M ⊙ for the primary and secondary, respectively, using evolutionary tracks. The tracks also yield a coeval age of 1 Myr for both components to within 1σ. GW Ori is surrounded by a circumbinary/circumtriple disk. A tertiary component has been detected in previous studies; however, we did not detect this component in our near-infrared spectra, probably the result of its relative faintness and blending in the absorption lines of these rapidly rotating stars. With these results, GW Ori joins the small number of classical T Tauri, double-lined spectroscopic binaries.

  5. Accurate and fast 3D surface measurement with temporal-spatial binary encoding structured illumination.

    Science.gov (United States)

    Zhu, Jiangping; Zhou, Pei; Su, Xianyu; You, Zhisheng

    2016-12-12

    Balancing the accuracy and speed for 3D surface measurement of object is crucial in many important applications. Binary encoding pattern utilizing the high-speed image switching rate of digital mirror device (DMD)-based projector could be used as the candidate for fast even high-speed 3D measurement, but current most schemes only enable the measurement speed, which limit their application scopes. In this paper, we present a binary encoding method and develop an experimental system aiming to solve such a situation. Our approach encodes one computer-generated standard 8 bit sinusoidal fringe pattern into multiple binary patterns (sequence) with designed temporal-spatial binary encoding tactics. The binary pattern sequence is then high-speed and in-focus projected onto the surface of tested object, and then captured by means of temporal-integration imaging to form one sinusoidal fringe image. Further the combination of phase-shifting technique and temporal phase unwrapping algorithm leads to fast and accurate 3D measurement. The systematic accuracy better than 0.08mm is achievable. The measurement results with mask and palm are given to confirm the feasibility.

  6. Surface properties and phosphate adsorption of binary systems containing goethite and kaolinite

    NARCIS (Netherlands)

    Wei, S.Y.; Tan, W.F.; Liu, F.; Zhao, W.; Weng, L.

    2014-01-01

    In soils goethite and kaolinite are often cemented together as a binary association, which has a significant influence on the physical and chemical properties of soils. In this study, the surface properties and phosphate adsorption of goethite, kaolinite, goethite-kaolinite association (GKA) and

  7. Surface tension of heptane, decane, hexadecane, eicosane, and some of their binary mixtures

    DEFF Research Database (Denmark)

    Rolo, Lara I.; Caco, Ana I.; Queimada, Antonio

    2002-01-01

    Surface tension measurements were performed by the Wilhelmy plate method. Measured systems included pure heptane, decane, hexadecane, eicosane, and some of their binary mixtures at temperatures from 293.15 K to 343.15 K with an average absolute deviation of 1.6%. The results were compared with a ...

  8. Secular dynamics of multiplanetary circumbinary systems: stationary solutions and binary-planet secular resonance

    Science.gov (United States)

    Andrade-Ines, Eduardo; Robutel, Philippe

    2018-01-01

    We present an analytical formalism to study the secular dynamics of a system consisting of N-2 planets orbiting a binary star in outer orbits. We introduce a canonical coordinate system and expand the disturbing function in terms of canonical elliptic elements, combining both Legendre polynomials and Laplace coefficients, to obtain a general formalism for the secular description of this type of configuration. With a quadratic approximation of the development, we present a simplified analytical solution for the planetary orbits for both the single planet and the two-planet cases. From the two-planet model, we show that the inner planet accelerates the precession rate of the binary pericenter, which, in turn, may enter in resonance with the secular frequency of the outer planet, characterizing a secular resonance. We calculate an analytical expression for the approximate location of this resonance and apply it to known circumbinary systems, where we show that it can occur at relatively close orbits, for example at 2.4 au for the Kepler-38 system. With a more refined model, we analyse the dynamics of this secular resonance and we show that a bifurcation of the corresponding fixed points can affect the long- term evolution and stability of planetary systems. By comparing our results with complete integrations of the exact equations of motion, we verified the accuracy of our analytical model.

  9. Artificial Neural Network Solutions to Eclipsing Binary Lightcurves from the Kepler Space Telescope Database

    Science.gov (United States)

    Hause, Connor; Prsa, Andrej; Matijevic, Gal; Guinan, Edward F.

    2017-01-01

    Fully automated methods of data analysis are necessary for surpassing the human bottleneck in astrophysical data processing and maximizing scientific results from the great volume of observations to be taken over the next few decades. Prsa et al. (2008, ApJ, 687:542) addressed this issue by introducing an artificial neural network (ANN) which estimates the principal parameters of detached eclipsing binary (EB) stars. Parameters obtained by the process can be passed on to advanced modeling engines to produce a qualified EB database. The ANN was originally developed and trained for the OGLE EBs. Our project focuses on retraining this ANN for EBs from NASA’s Kepler Space Telescope database and serves as an extension to the eclipsing binaries via artificial intelligence (EBAI) project. The Kepler photometry is much more precise than photometry available from OGLE and other previous ground-based studies.. For our training set, we generated theoretical lightcurves via a Monte Carlo based Python script utilizing PHOEBE which samples EB parameter values according to prior distribution functions. Novel to our analysis is the use of chi-squared statistical tests which serve to qualify the overlap between the calculated exemplars and observed data. This enables the trained ANN to more accurately parameterize each EB. We describe our training process, present principal parameter estimates of Kepler EBs obtained by the ANNs, and discuss ongoing endeavors to refine those solutions. This research was supported by the National Science Foundation grant #1517474 which we gratefully acknowledge.

  10. Surface Structures of Binary Mixture of Ionic Liquids.

    Czech Academy of Sciences Publication Activity Database

    Nakajima, K.; Nakanishi, S.; Lísal, Martin; Kimura, K.

    2017-01-01

    Roč. 230, MARCH (2017), s. 542-549 ISSN 0167-7322 R&D Projects: GA ČR(CZ) GA16-12291S Institutional support: RVO:67985858 Keywords : ionic liquids * mixture * surface structure Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 3.648, year: 2016

  11. Concentration Dependences of the Surface Tension and Density of Solutions of Acetone-Ethanol-Water Systems at 293 K

    Science.gov (United States)

    Dadashev, R. Kh.; Dzhambulatov, R. S.; Mezhidov, V. Kh.; Elimkhanov, D. Z.

    2018-05-01

    Concentration dependences of the surface tension and density of solutions of three-component acetone-ethanol-water systems and the bounding binary systems at 273 K are studied. The molar volume, adsorption, and composition of surface layers are calculated. Experimental data and calculations show that three-component solutions are close to ideal ones. The surface tensions of these solutions are calculated using semi-empirical and theoretical equations. Theoretical equations qualitatively convey the concentration dependence of surface tension. A semi-empirical method based on the Köhler equation allows us to predict the concentration dependence of surface tension within the experimental error.

  12. [Effect of Cr (VI) anions on the Cu (II) adsorption behavior of two kinds of clay minerals in single and binary solution].

    Science.gov (United States)

    Liu, Juan-Juan; Liang, Dong-Li; Wu, Xiao-Long; Qu, Guang-Zhou; Qian, Xun

    2014-01-01

    The adsorption of Cu (II) on kaolinite and montmorillonite was investigated through batch adsorption experiment. Several adsorption models were employed to describe the adsorption of Cu (II) on the two clay minerals in single Cu (II) and Cu(II)-Cr (VI) binary solutions, and the impact of solution with various pH values on the adsorption of Cu (II) on the two target mineral clays was investigated in order to explain the environmental chemical behavior of heavy metals in soil and to provide theoretical basis in remediation of multi-element contaminated soil. The results indicated that the adsorption process of Cu (II) on kaolinite and montmorillonite in both single and binary solutions was fast at the beginning and then slowed down. Adsorption equilibrium was observed within 120 min. In both single and binary solutions, pseudo-second-order model (R2 > 0.983) showed the highest agreement with the adsorption of Cu (II) on the two mineral clays, followed by the intra-particle diffusion model and pseudo-first-order model. Both Intra-particle diffusion model and Boyd model illustrated that the film diffusion process was the rate-limiting step, which mainly occurred at the edge and surface of mineral clays. Copper adsorption on kaolinite was well fitted with the Freundlich equation (R2 > 0.971), which could be attributed to the heterogeneity of kaolinite surface with adsorption sites that have different energies of adsorption. Langmuir equation was best fitted with the isotherm for montmorillonite (R2 > 0.983), which indicated that the adsorption was on a single molecular layer or chemisorptions. In both single and binary solutions, the adsorption of Cu (II ) on the two clay minerals first increased and then decreased with the rising of pH values. The maximum adsorption amount was found at pH = 5.0, and was in the order of Qmon. > Qkao. and Q(Single-Cu) > Q(Cu-Cr binary). Cr (VI) in the solution reduced the adsorption of Cu (II), and the minimal influence of Cr (VI) on Cu

  13. The influence of surface roughness and solution concentration on pool boiling process in Diethanolamine aqueous solution

    Science.gov (United States)

    Khoshechin, Mohsen; Salimi, Farhad; Jahangiri, Alireza

    2018-04-01

    In this research, the effect of surface roughness and concentration of solution on bubble departing frequency and nucleation site density for pool boiling of water/diethanolamine (DEA) binary solution were investigated experimentally. In this investigation, boiling heat transfer coefficient, bubble departing frequency and nucleation site density have been experimentally investigated in various concentrations and heat fluxes. Microstructured surfaces with a wide range of well-defined surface roughness were fabricated, and a heat flux between 1.5-86 kW/m2 was achieved under atmospheric conditions. The Results indicated that surface roughness and concentration of solution increase the bubble departing frequency and nucleation site density with increasing heat flux. The boiling heat transfer coefficient in mixtures of water/DEA increases with increasing concentration of DEA in water. The experimental results were compared with predictions of several used correlations in the literatures. Results showed that the boiling heat transfer coefficients of this case study are much higher than the predicted values by major existing correlations and models. The excellent agreement for bubble departing frequency found between the models of Jackob and Fritz (1966) and experimental data and also the nucleation site density were in close agreement with the model of Paul (1983) data. f bubble departure frequency, 1/s or Hz N Number of nucleation sites per area per time R c Minimum cavity size, m D c critical diameter, m g gravitational acceleration, m/s2 ρ density, kg/m3 T temperature, °c ΔT temperature difference, °c d d vapor bubble diameter, m h fg enthalpy of vaporization, J/kg R Roughness, μm Ja Jakob number cp specific heat, J/kg °c Pr Prandtl number Ar Archimedes number h Heat transfer coefficient, J/(m2 °c) tg time it takes to grow a bubble, s q/A heat flux (kW/m2) tw time required to heat the layer, s gc Correction coefficient of incompatible units R a Surface

  14. Electrodeposition of Pd based binary catalysts on Carbon paper via surface limited redox-replacement reaction for oxygen reduction reaction

    CSIR Research Space (South Africa)

    Modibedi, RM

    2014-05-01

    Full Text Available attention as it is more abundant and also cheaper than Pt. In this presentation, Electrochemical Atomic Layer Deposition (ECALD) was used in the preparation of binary ORR catalysts. The binary nanoclusters were synthesised via surface-limited redox-replacement...

  15. Surface tension of decane binary and ternary mixtures with eicosane, docosane, and tetracosane

    DEFF Research Database (Denmark)

    Queimada, Antonio; Cao, A.I.; Marrucho, I.M.

    2005-01-01

    -C24H50 and the ternary n-C10H22 + n-C20H42 + n-C24H50 were measured from 293.15 K (or above the solution melting temperature) up to 343.15 K. An average absolute deviation of 1.3% was obtained in comparison with pure component literature data. No mixture information for the reported systems was found......A tensiometer operating on the Wilhelmy plate method was employed to measure liquid-vapor interfacial tensions of three binary mixtures and one ternary mixture of decane with eicosane, docosane, and tetracosane. Tensions of binary mixtures n-C10H22 + n-C20H42, n-C10H22 + n-C22H46, and n-C10H22 + n...

  16. The effect of structural properties on rheological behaviour of starches in binary dimethyl sulfoxide-water solutions.

    Directory of Open Access Journals (Sweden)

    Anna Ptaszek

    Full Text Available This research study analysed the rheological properties of potato amylose and potato amylopectin in binary solutions of the following water and dimethyl sulfoxide concentrations: 90% DMSO (1, 80% DMSO (2 and 50% DMSO (3, with preparation methodology involving the dissolution at the temperature of 98°C. The studies of dynamic light scattering on the biopolymer coils and the determination of main relaxation times of the solutions were carried out. For the amylose solutions, the fast relaxation phenomena are predominant. The results of the quality tests of the hysteresis loop showed, that the amylose solutions in the solvents (1 and (2 are rheologically stable and shear-thickened. The amylose solutions in solvents (3 reveal oscillatory alterations of viscosity in the time. Amylopectin solutions are characterized by 80% share of slow relaxation phenomena, very low diffusion coefficients and hydrodynamic radii in the range of 2000 nm. The amylopectin solutions are rheologically unstable.

  17. The effect of structural properties on rheological behaviour of starches in binary dimethyl sulfoxide-water solutions

    Science.gov (United States)

    Ptaszek, Paweł; Dziubiński, Marek; Grzesik, N. Mirosław; Liszka-Skoczylas, Marta

    2017-01-01

    This research study analysed the rheological properties of potato amylose and potato amylopectin in binary solutions of the following water and dimethyl sulfoxide concentrations: 90% DMSO (1), 80% DMSO (2) and 50% DMSO (3), with preparation methodology involving the dissolution at the temperature of 98°C. The studies of dynamic light scattering on the biopolymer coils and the determination of main relaxation times of the solutions were carried out. For the amylose solutions, the fast relaxation phenomena are predominant. The results of the quality tests of the hysteresis loop showed, that the amylose solutions in the solvents (1) and (2) are rheologically stable and shear-thickened. The amylose solutions in solvents (3) reveal oscillatory alterations of viscosity in the time. Amylopectin solutions are characterized by 80% share of slow relaxation phenomena, very low diffusion coefficients and hydrodynamic radii in the range of 2000 nm. The amylopectin solutions are rheologically unstable. PMID:28152071

  18. Deposition and characterization of binary Al2O3/SiO2 coating layers on the surfaces of rutile TiO2 and the pigmentary properties

    International Nuclear Information System (INIS)

    Zhang Yunsheng; Yin Hengbo; Wang Aili; Ren Min; Gu Zhuomin; Liu Yumin; Shen Yutang; Yu Longbao; Jiang Tingshun

    2010-01-01

    Binary Al 2 O 3 /SiO 2 -coated rutile TiO 2 composites were prepared by a liquid-phase deposition method starting from Na 2 SiO 3 .9H 2 O and NaAlO 2 . The chemical structure and morphology of binary Al 2 O 3 /SiO 2 coating layers were investigated by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, TG-DSC, Zeta potential, powder X-ray diffraction, and transmission electron microscopy techniques. Binary Al 2 O 3 /SiO 2 coating layers both in amorphous phase were formed at TiO 2 surfaces. The silica coating layers were anchored at TiO 2 surfaces via Si-O-Ti bonds and the alumina coating layers were probably anchored at the SiO 2 -coated TiO 2 surfaces via Al-O-Si bonds. The formation of continuous and dense binary Al 2 O 3 /SiO 2 coating layers depended on the pH value of reaction solution and the alumina loading. The binary Al 2 O 3 /SiO 2 -coated TiO 2 composites had a high dispersibility in water. The whiteness and brightness of the binary Al 2 O 3 /SiO 2 -coated TiO 2 composites were higher than those of the naked rutile TiO 2 and the SiO 2 -coated TiO 2 samples. The relative light scattering index was found to depend on the composition of coating layers.

  19. Surface tension of nitric oxide and its binary mixtures with krypton, methane, and ethene

    Energy Technology Data Exchange (ETDEWEB)

    Calado, J.C.G.; Santos Mendonca, A.F.S. dos; Saramago, B.J.V.; Soares, V.A.M. [Instituto Superior Tecnico, Lisbon (Portugal). Centro de Quimica Estrutural

    1997-05-15

    The surface tension of three binary liquid mixtures of NO with Kr, CH{sub 4}, and C{sub 2}H{sub 4} has been determined as a function of composition in the temperature range 102.0 to 119.0 K. These measurements are a contribution to the study of binary liquid mixtures in which one component is unassociated while the molecules of the other can associate between themselves. Nitric oxide is the simplest molecule capable of forming dimers, but not larger aggregates. This results in the surface tension of liquid nitric oxide having a strong temperature dependence: when the temperature increases the degree of dimerization decreases, contributing to a larger decrease of the surface tension. The surface tension of NO mixtures shows strong deviations from ideality. The mixtures containing Kr and CH{sub 4} exhibit negative deviations, while for the NO + C{sub 2}H{sub 4} system the surface tension shows a complex dependence on the composition. This strong departure from ideality had already been found for the bulk properties of these three systems. The surface tension of the CH{sub 4} + Kr system, already well characterized in the literature, was also measured to test the equipment.

  20. Generalized Bilinear Differential Operators, Binary Bell Polynomials, and Exact Periodic Wave Solution of Boiti-Leon-Manna-Pempinelli Equation

    Directory of Open Access Journals (Sweden)

    Huanhe Dong

    2014-01-01

    Full Text Available We introduce how to obtain the bilinear form and the exact periodic wave solutions of a class of (2+1-dimensional nonlinear integrable differential equations directly and quickly with the help of the generalized Dp-operators, binary Bell polynomials, and a general Riemann theta function in terms of the Hirota method. As applications, we solve the periodic wave solution of BLMP equation and it can be reduced to soliton solution via asymptotic analysis when the value of p is 5.

  1. Calibration of Modulation Transfer Function of Surface Profilometers with 1D and 2D Binary Pseudo-random Array Standards

    International Nuclear Information System (INIS)

    Yashchuk, Valeriy V.; McKinney, Wayne R.; Takacs, Peter Z.

    2008-01-01

    We suggest and describe the use of a binary pseudo-random grating as a standard test surface for calibration of the modulation transfer function of microscopes. Results from calibration of a MicromapTM-570 interferometric microscope are presented.

  2. Optimizing the surface density of polyethylene glycol chains by grafting from binary solvent mixtures

    Science.gov (United States)

    Arcot, Lokanathan; Ogaki, Ryosuke; Zhang, Shuai; Meyer, Rikke L.; Kingshott, Peter

    2015-06-01

    Polyethylene glycol (PEG) brushes are very effective at controlling non-specific deposition of biological material onto surfaces, which is of paramount importance to obtaining successful outcomes in biomaterials, tissue engineered scaffolds, biosensors, filtration membranes and drug delivery devices. We report on a simple 'grafting to' approach involving binary solvent mixtures that are chosen based on Hansen's solubility parameters to optimize the solubility of PEG thereby enabling control over the graft density. The PEG thiol-gold model system enabled a thorough characterization of PEG films formed, while studies on a PEG silane-silicon system examined the versatility to be applied to any substrate-head group system by choosing an appropriate solvent pair. The ability of PEG films to resist non-specific adsorption of proteins was quantitatively assessed by full serum exposure studies and the binary solvent strategy was found to produce PEG films with optimal graft density to efficiently resist protein adsorption.

  3. Surge-Resistant Nanocomposite Enameled Wire Using Silica Nanoparticles with Binary Chemical Compositions on the Surface

    Directory of Open Access Journals (Sweden)

    Jeseung Yoo

    2015-01-01

    Full Text Available We developed polyesterimide (PEI nanocomposite enameled wires using surface-modified silica nanoparticles with binary chemical compositions on the surface. The modification was done using silanes assisted by ultrasound, which facilitated high density modification. Two different trimethoxysilanes were chosen for the modification on the basis of resemblance of chemical compositions on the silica surface to PEI varnish. The surface-modified silica was well dispersed in PEI varnish, which was confirmed by optical observation and viscosity measurement. The glass transition temperature of the silica-PEI nanocomposite increased with the silica content. The silica-dispersed PEI varnish was then used for enameled wire fabrication. The silica-PEI nanocomposite enameled wire exhibited a much longer lifetime compared to that of neat PEI enameled wire in partial discharge conditions.

  4. Application of the regular associated solution model to the Cd-Te and Hg-Te binary systems

    Science.gov (United States)

    Kelley, J. D.; Martin, B. G.; Szofran, F. R.; Lehoczky, S. L.

    1982-01-01

    The regular associated solution model is used to treat the phase diagrams of the binary II-VI semiconductor alloy systems Hg-Te and Cd-Te. The equations for the species activity coefficients are used without approximations regarding the magnitudes of the various binary interchange energies or the functional dependence on component mol fraction. The values of the four-adjustable parameters required for description of each system are fixed by fitting liquidus data, and the resulting activity coefficients are used to calculate component partial pressures, which are compared with experimental values as an indpendent check of the validity of the model. The results show that the regular associated solution model provides a usefully accurate, but not complete, description for both the Hg-Te and Cd-Te systems. The relationship of this work to previous investigations is discussed.

  5. Instability and droplet formation in evaporating thin films of a binary solution

    Science.gov (United States)

    Govor, Leonid V.; Parisi, Jürgen; Bauer, Gottfried H.; Reiter, Günter

    2005-05-01

    We consider an instability phenomenon in a bilayer structure resulting from phase separation in a thin film of mixed solutions located on a water surface. The top layer consists of a hexane/hexadecylamine solution with thickness d2 , the lower one of an amyl acetate/cellulose solution with thickness d1 . During evaporation of the solvents from both layers, their thickness, surface tension, and viscosity change continuously with time. The thickness d2 decreases significantly faster than the thickness d1 , because the evaporation rate of hexane is much larger than that of amyl acetate. Eventually, the top layer decomposes into droplets when its thickness d2 was only a few nm, while the thickness d1 was still some 100nm . In addition to the experiments, we present calculations based on energetic arguments which are in good agreement with experimentally determined geometrical parameters of the droplet pattern, such as droplet diameter, droplet height, interdroplet distance, and number of droplets per unit area.

  6. Theoretical and experimental study of metastable solid solutions and phase stability within the immiscible Ag-Mo binary system

    Science.gov (United States)

    Sarakinos, K.; Greczynski, G.; Elofsson, V.; Magnfält, D.; Högberg, H.; Alling, B.

    2016-03-01

    Metastable solid solutions are phases that are synthesized far from thermodynamic equilibrium and offer a versatile route to design materials with tailor-made functionalities. One of the most investigated classes of metastable solid solutions with widespread technological implications is vapor deposited ternary transition metal ceramic thin films (i.e., nitrides, carbides, and borides). The vapor-based synthesis of these ceramic phases involves complex and difficult to control chemical interactions of the vapor species with the growing film surface, which often makes the fundamental understanding of the composition-properties relations a challenging task. Hence, in the present study, we investigate the phase stability within an immiscible binary thin film system that offers a simpler synthesis chemistry, i.e., the Ag-Mo system. We employ magnetron co-sputtering to grow Ag1-xMox thin films over the entire composition range along with x-ray probes to investigate the films structure and bonding properties. Concurrently, we use density functional theory calculations to predict phase stability and determine the effect of chemical composition on the lattice volume and the electronic properties of Ag-Mo solid solutions. Our combined theoretical and experimental data show that Mo-rich films (x ≥ ˜0.54) form bcc Mo-Ag metastable solid solutions. Furthermore, for Ag-rich compositions (x ≤ ˜0.21), our data can be interpreted as Mo not being dissolved in the Ag fcc lattice. All in all, our data show an asymmetry with regards to the mutual solubility of Ag and Mo in the two crystal structures, i.e., Ag has a larger propensity for dissolving in the bcc-Mo lattice as compared to Mo in the fcc-Ag lattice. We explain these findings in light of isostructural short-range clustering that induces energy difference between the two (fcc and bcc) metastable phases. We also suggest that the phase stability can be explained by the larger atomic mobility of Ag atoms as compared to that

  7. Grouping pursuit through a regularization solution surface.

    Science.gov (United States)

    Shen, Xiaotong; Huang, Hsin-Cheng

    2010-06-01

    Extracting grouping structure or identifying homogenous subgroups of predictors in regression is crucial for high-dimensional data analysis. A low-dimensional structure in particular-grouping, when captured in a regression model, enables to enhance predictive performance and to facilitate a model's interpretability Grouping pursuit extracts homogenous subgroups of predictors most responsible for outcomes of a response. This is the case in gene network analysis, where grouping reveals gene functionalities with regard to progression of a disease. To address challenges in grouping pursuit, we introduce a novel homotopy method for computing an entire solution surface through regularization involving a piecewise linear penalty. This nonconvex and overcomplete penalty permits adaptive grouping and nearly unbiased estimation, which is treated with a novel concept of grouped subdifferentials and difference convex programming for efficient computation. Finally, the proposed method not only achieves high performance as suggested by numerical analysis, but also has the desired optimality with regard to grouping pursuit and prediction as showed by our theoretical results.

  8. A general scheme for the estimation of oxygen binding energies on binary transition metal surface alloys

    DEFF Research Database (Denmark)

    Greeley, Jeffrey Philip; Nørskov, Jens Kehlet

    2005-01-01

    A simple scheme for the estimation of oxygen binding energies on transition metal surface alloys is presented. It is shown that a d-band center model of the alloy surfaces is a convenient and appropriate basis for this scheme; variations in chemical composition, strain effects, and ligand effects...... are all incorporated into the binding energy analysis through this parameter. With few exceptions, the agreement of the results from the simple model with full DFT calculations on hundreds of binary surface alloys is remarkable. The scheme should therefore provide a fast and effective method...... for the estimation of oxygen binding energies on a wide variety of transition metal alloys. (c) 2005 Elsevier B.V. All rights reserved....

  9. Surface tension and related thermodynamic quantities of aqueous electrolyte solutions

    CERN Document Server

    Matubayasi, Norihiro

    2013-01-01

    Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a d

  10. A new model for predicting thermodynamic properties of ternary metallic solution from binary components

    International Nuclear Information System (INIS)

    Fang Zheng; Zhang Quanru

    2006-01-01

    A model has been derived to predict thermodynamic properties of ternary metallic systems from those of its three binaries. In the model, the excess Gibbs free energies and the interaction parameter ω 123 for three components of a ternary are expressed as a simple sum of those of the three sub-binaries, and the mole fractions of the components of the ternary are identical with the sub-binaries. This model is greatly simplified compared with the current symmetrical and asymmetrical models. It is able to overcome some shortcomings of the current models, such as the arrangement of the components in the Gibbs triangle, the conversion of mole fractions between ternary and corresponding binaries, and some necessary processes for optimizing the various parameters of these models. Two ternary systems, Mg-Cu-Ni and Cd-Bi-Pb are recalculated to demonstrate the validity and precision of the present model. The calculated results on the Mg-Cu-Ni system are better than those in the literature. New parameters in the Margules equations expressing the excess Gibbs free energies of three binary systems of the Cd-Bi-Pb ternary system are also given

  11. Density, Viscosity and Surface Tension of Binary Mixtures of 1-Butyl-1-Methylpyrrolidinium Tricyanomethanide with Benzothiophene.

    Science.gov (United States)

    Domańska, Urszula; Królikowska, Marta; Walczak, Klaudia

    2014-01-01

    The effects of temperature and composition on the density and viscosity of pure benzothiophene and ionic liquid (IL), and those of the binary mixtures containing the IL 1-butyl-1-methylpyrrolidynium tricyanomethanide ([BMPYR][TCM] + benzothiophene), are reported at six temperatures (308.15, 318.15, 328.15, 338.15, 348.15 and 358.15) K and ambient pressure. The temperature dependences of the density and viscosity were represented by an empirical second-order polynomial and by the Vogel-Fucher-Tammann equation, respectively. The density and viscosity variations with compositions were described by polynomials. Excess molar volumes and viscosity deviations were calculated and correlated by Redlich-Kister polynomial expansions. The surface tensions of benzothiophene, pure IL and binary mixtures of ([BMPYR][TCM] + benzothiophene) were measured at atmospheric pressure at four temperatures (308.15, 318.15, 328.15 and 338.15) K. The surface tension deviations were calculated and correlated by a Redlich-Kister polynomial expansion. The temperature dependence of the interfacial tension was used to evaluate the surface entropy, the surface enthalpy, the critical temperature, the surface energy and the parachor for pure IL. These measurements have been provided to complete information of the influence of temperature and composition on physicochemical properties for the selected IL, which was chosen as a possible new entrainer in the separation of sulfur compounds from fuels. A qualitative analysis on these quantities in terms of molecular interactions is reported. The obtained results indicate that IL interactions with benzothiophene are strongly dependent on packing effects and hydrogen bonding of this IL with the polar solvent.

  12. Reactive transport in a partially molten system with binary solid solution

    Science.gov (United States)

    Jordan, J.; Hesse, M. A.

    2017-12-01

    Melt extraction from the Earth's mantle through high-porosity channels is required to explain the composition of the oceanic crust. Feedbacks from reactive melt transport are thought to localize melt into a network of high-porosity channels. Recent studies invoke lithological heterogeneities in the Earth's mantle to seed the localization of partial melts. Therefore, it is necessary to understand the reaction fronts that form as melt flows across the lithological interface of a heterogeneity and the background mantle. Simplified melting models of such systems aide in the interpretation and formulation of larger scale mantle models. Motivated by the aforementioned facts, we present a chromatographic analysis of reactive melt transport across lithological boundaries, using theory for hyperbolic conservation laws. This is an extension of well-known linear trace element chromatography to the coupling of major elements and energy transport. Our analysis allows the prediction of the feedbacks that arise in reactive melt transport due to melting, freezing, dissolution and precipitation for frontal reactions. This study considers the simplified case of a rigid, partially molten porous medium with binary solid solution. As melt traverses a lithological contact-modeled as a Riemann problem-a rich set of features arise, including a reacted zone between an advancing reaction front and partial chemical preservation of the initial contact. Reactive instabilities observed in this study originate at the lithological interface rather than along a chemical gradient as in most studies of mantle dynamics. We present a regime diagram that predicts where reaction fronts become unstable, thereby allowing melt localization into high-porosity channels through reactive instabilities. After constructing the regime diagram, we test the one-dimensional hyperbolic theory against two-dimensional numerical experiments. The one-dimensional hyperbolic theory is sufficient for predicting the

  13. (Tl, Sb) and (Tl, Bi) binary surface reconstructions on Ge(111) substrate

    Science.gov (United States)

    Gruznev, D. V.; Bondarenko, L. V.; Tupchaya, A. Y.; Yakovlev, A. A.; Mihalyuk, A. N.; Zotov, A. V.; Saranin, A. A.

    2018-03-01

    2D compounds made of Group-III and Group-V elements on the surface of silicon and germanium attract considerable attention due to prospects of creating III-V binary monolayers, which are predicted to hold advanced physical properties. In the present work, we have investigated two such systems, (Tl, Sb)/Ge(111) and (Tl, Bi)/Ge(111) using scanning tunneling microscopy, low energy electron diffraction observations and density-functional-theory calculations. In addition to the previously reported surface structures of 2D (Tl, Sb) and (Tl, Bi) compounds on Si(111), we found new ones, namely, √{ 7} × √{ 7} and 3 × 3. Formation processes and plausible models of their atomic arrangements are discussed.

  14. Surface solitons in waveguide arrays: Analytical solutions.

    Science.gov (United States)

    Kominis, Yannis; Papadopoulos, Aristeidis; Hizanidis, Kyriakos

    2007-08-06

    A novel phase-space method is employed for the construction of analytical stationary solitary waves located at the interface between a periodic nonlinear lattice of the Kronig-Penney type and a linear or nonlinear homogeneous medium as well as at the interface between two dissimilar nonlinear lattices. The method provides physical insight and understanding of the shape of the solitary wave profile and results to generic classes of localized solutions having either zero or nonzero semi-infinite backgrounds. For all cases, the method provides conditions involving the values of the propagation constant of the stationary solutions, the linear refractive index and the dimensions of each part in order to assure existence of solutions with specific profile characteristics. The evolution of the analytical solutions under propagation is investigated for cases of realistic configurations and interesting features are presented such as their remarkable robustness which could facilitate their experimental observation.

  15. Effect of solute interaction on interfacial and grain boundary embrittlement in binary alloys

    Czech Academy of Sciences Publication Activity Database

    Lejček, Pavel

    2013-01-01

    Roč. 48, č. 6 (2013), 2574-2580 ISSN 0022-2461 R&D Projects: GA ČR GAP108/12/0144 Institutional research plan: CEZ:AV0Z10100520 Keywords : interfacial segregation * grain boundary embrittlement * binary interaction * modeling * thermodynamics Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.305, year: 2013

  16. Directly comparing GW150914 with numerical solutions of Einstein's equations for binary black hole coalescence

    NARCIS (Netherlands)

    Abbott, B. P.; Abbott, R.; Abbott, T. D.; Abernathy, M. R.; Acernese, F.; Ackley, K.; Adams, C.; Phythian-Adams, A.T.; Addesso, P.; Adhikari, R. X.; Adya, V. B.; Affeldt, C.; Agathos, M.; Agatsuma, K.; Aggarwal, N.T.; Aguiar, O. D.; Aiello, L.; Ain, A.; Ajith, P.; Allen, B.; Allocca, A.; Altin, P. A.; Anderson, S. B.; Anderson, W. G.; Arai, K.; Araya, M. C.; Arceneaux, C. C.; Areeda, J. S.; Arnaud, N.; Arun, K. G.; Ascenzi, S.; Ashton, G.; Ast, M.; Aston, S. M.; Astone, P.; Aufmuth, P.; Aulbert, C.; Babak, S.; Bacon, P.; Bader, M. K. M.; Baker, P. T.; Baldaccini, F.; Ballardin, G.; Ballmer, S. W.; Barayoga, J. C.; Barclay, S. E.; Barish, B. C.; Barker, R.D.; Barone, F.; Barr, B.; Barsotti, L.; Barsuglia, M.; Barta, D.; Bartlett, J.; Bartos, I.; Bassiri, R.; Basti, A.; Batch, J. C.; Baune, C.; Bavigadda, V.; Bazzan, M.; Bejger, M.; Bell, A. S.; Berger, B. K.; Bergmann, G.; Berry, C. P. L.; Bersanetti, D.; Bertolini, A.; Betzwieser, J.; Bhagwat, S.; Bhandare, R.; Bilenko, I. A.; Billingsley, G.; Birch, M.J.; Birney, R.; Biscans, S.; Bisht, A.; Bitossi, M.; Biwer, C.; Bizouard, M. A.; Blackburn, J. K.; Blair, C. D.; Blair, D. G.; Blair, R. M.; Bloemen, A.L.S.; Bock, O.; Boer, M.; Bogaert, J.G.; Bogan, C.; Bohe, A.; Bond, T.C; Bondu, F.; Bonnand, R.; Boom, B. A.; Bork, R.; Boschi, V.; Bose, S.; Bouffanais, Y.; Bozzi, A.; Bradaschia, C.; Brady, P. R.; Braginsky, V. B.; Branchesi, M.; Brau, J. E.; Briant, T.; Brillet, A.; Brinkmann, M.; Brisson, V.; Brockill, P.; Broida, J. E.; Brooks, A. F.; Brown, A.D.; Brown, D.; Brown, N. M.; Brunett, S.; Buchanan, C. C.; Buikema, A.; Bulik, T.; Bulten, H. J.; Buonanno, A.; Buskulic, D.; Buy, C.; Byer, R. L.; Cabero, M.; Cadonati, L.; Cagnoli, G.; Cahillane, C.; Bustillo, J. Calderon; Callister, T. A.; Calloni, E.; Camp, J. B.; Cannon, K. C.; Cao, J.; Capano, C. D.; Capocasa, E.; Carbognani, F.; Caride, S.; Diaz, J. Casanueva; Casentini, C.; Caudill, S.; Cavaglia, M.; Cavalier, F.; Cavalieri, R.; Cella, G.; Cepeda, C. B.; Baiardi, L. Cerboni; Cerretani, G.; Cesarini, E.; Chamberlin, S. J.; Chan, M.; Chao, D. S.; Charlton, P.; Chassande-Mottin, E.; Cheeseboro, B. D.; Chen, H. Y.; Chen, Y; Cheng, C.; Chincarini, A.; Chiummo, A.; Cho, H. S.; Cho, M.; Chow, J. H.; Christensen, N.; Chu, Qian; Chua, S. E.; Chung, E.S.; Ciani, G.; Clara, F.; Clark, J. A.; Cleva, F.; Coccia, E.; Cohadon, P. -F.; Colla, A.; Collette, C. G.; Cominsky, L.; Constancio, M., Jr.; Conte, A.; Conti, L.; Cook, D.; Corbitt, T. R.; Cornish, N.; Corsi, A.; Cortese, S.; Costa, A.C.; Coughlin, M. W.; Coughlin, S. B.; Coulon, J. -P.; Countryman, S. T.; Couvares, P.; Cowan, E. E.; Coward, D. M.; Cowart, M. J.; Coyne, D. C.; Coyne, R.; Craig, K.; Creighton, J. D. E.; Cripe, J.; Crowder, S. G.; Cumming, A.; Cunningham, A.L.; Cuoco, E.; Dal Canton, T.; Danilishin, S. L.; D'Antonio, S.; Danzmann, K.; Darman, N. S.; Dasgupta, A.; Costa, C. F. Da Silva; Dattilo, V.; Dave, I.; Davier, M.; Davies, G. S.; Daw, E. J.; Day, R.; De, S.; Debra, D.; Debreczeni, G.; Degallaix, J.; De laurentis, M.; Deleglise, S.; Del Pozzo, W.; Denker, T.; Dent, T.; Dergachev, V.A.; Rosa, R.; DeRosa, R. T.; DeSalvo, R.; Devine, R. C.; Dhurandhar, S.; Diaz, M. C.; Di Fiore, L.; Giovanni, M.G.; Di Girolamo, T.; Di Lieto, A.; Di Pace, S.; Di Palma, I.; Di Virgilio, A.; Dolique, V.; Donovan, F.; Dooley, K. L.; Doravari, S.; Douglas, R.; Downes, T. P.; Drago, M.; Drever, R. W. P.; Driggers, J. C.; Ducrot, M.; Dwyer, S. E.; Edo, T. B.; Edwards, M. C.; Effler, A.; Eggenstein, H. -B.; Ehrens, P.; Eichholz, J.; Eikenberry, S. S.; Engels, W.; Essick, R. C.; Etzel, T.; Evans, T. M.; Evans, T. M.; Everett, R.; Factourovich, M.; Fafone, V.; Fair, H.; Fan, X.M.; Fang, Q.; Farinon, S.; Farr, B.; Farr, W. M.; Favata, M.; Fays, M.; Fehrmann, H.; Fejer, M. M.; Fenyvesi, E.; Ferrante, I.; Ferreira, E. C.; Ferrini, F.; Fidecaro, F.; Fiori, I.; Fiorucci, D.; Fisher, R. P.; Flaminio, R.; Fletcher, M; Fournier, J. -D.; Frasca, S.; Frasconi, F.; Frei, Z.; Freise, A.; Frey, R.; Frey, V.; Fritschel, P.; Frolov, V. V.; Fulda, P.; Fyffe, M.; Gabbard, H. A. G.; Gair, J. R.; Gammaitoni, L.; Gaonkar, S. G.; Garufi, F.; Gaur, G.; Gehrels, N.; Gemme, G.; Geng, P.; Genin, E.; Gennai, A.; George, J.; Gergely, L.; Germain, V.; Ghosh, Abhirup; Ghosh, Archisman; Ghosh, S.; Giaime, J. A.; Giardina, K. D.; Giazotto, A.; Gill, K.P.; Glaefke, A.; Goetz, E.; Goetz, R.; Gondan, L.; Gonzalez, Idelmis G.; Castro, J. M. Gonzalez; Gopakumar, A.; Gordon, N. A.; Gorodetsky, M. L.; Gossan, S. E.; Lee-Gosselin, M.; Gouaty, R.; Grado, A.; Graef, C.; Graff, P. B.; Granata, M.; Grant, A.; Gras, S.; Gray, C.M.; Greco, G.; Green, A. C.; Groot, P.; Grote, H.; Grunewald, S.; Guidi, G. M.; Guo, X.; Gupta, A.; Gupta, M. K.; Gushwa, K. E.; Gustafson, E. K.; Gustafson, R.; Hacker, J. J.; Buffoni-Hall, R.; Hall, E. D.; Hammond, G.L.; Haney, M.; Hanke, M. M.; Hanks, J.; Hanna, C.; Hanson, P.J.; Hardwick, T.; Harms, J.; Harry, G. M.; Harry, I. W.; Hart, M. J.; Hartman, M. T.; Haster, C. -J.; Haughian, K.; Heidmann, A.; Heintze, M. C.; Heitmann, H.; Hello, P.; Hemming, G.; Hendry, M.; Heng, I. S.; Hennig, J.; Henry, J.A.; Heptonstall, A. W.; Heurs, M.; Hild, S.; Hoak, D.; Hofman, D.; Holt, K.; Holz, D. E.; Hopkins, P.; Hough, J.; Houston, E. A.; Howell, E. J.; Hu, Y. M.; Huang, S.; Huerta, E. A.; Huet, D.; Hughey, B.; Huttner, S. H.; Huynh-Dinh, T.; Indik, N.; Ingram, D. R.; Inta, R.; Isa, H. N.; Isac, J. -M.; Isi, M.; Isogai, T.; Iyer, B. R.; Izumi, K.; Jacqmin, T.; Jang, D.H.; Jani, K.; Jaranowski, P.; Jawahar, S.; Jian, L.; Jimenez-Forteza, F.; Johnson, W.; Jones, I.D.; Jones, R.; Jonker, R. J. G.; Ju, L.; Haris, K.; Kalaghatgi, C. V.; Kalogera, V.; Kandhasamy, S.; Kang, G.H.; Kanner, J. B.; Kapadia, S. J.; Karki, S.; Karvinen, K. S.; Kasprzack, M.; Katsavounidis, E.; Katzman, W.; Kaufer, S.; Kaur, T.; Kawabe, K.; Kefelian, F.; Kehl, M. S.; Keitel, D.; Kelley, D. B.; Kells, W.; Kennedy, R.E.; Key, J. S.; Khalili, F. Y.; Khan, I.; Khan, Z.; Khazanov, E. A.; Kijbunchoo, N.; Kim, Chi-Woong; Kim, Chunglee; Kim, J.; Kim, K.; Kim, Namjun; Kim, W.; Kim, Y.M.; Kimbrell, S. J.; King, E. J.; King, P. J.; Kissel, J. S.; Klein, B.; Kleybolte, L.; Klimenko, S.; Koehlenbeck, S. M.; Koley, S.; Kondrashov, V.; Kontos, A.; Korobko, M.; Korth, W. Z.; Kowalska, I.; Kozak, D. B.; Kringel, V.; Krolak, A.; Krueger, C.; Kuehn, G.; Kumar, P.; Kumar, R.; Kuo, L.; Kutynia, A.; Lackey, B. D.; Landry, M.; Lange, J.; Lantz, B.; Lasky, P. D.; Laxen, M.; Lazzarini, A.; Lazzaro, C.; Leaci, P.; Leavey, S.; Lebigot, E. O.; Lee, C.H.; Lee, K.H.; Lee, M.H.; Lee, K.; Lenon, A.; Leonardi, M.; Leong, J. R.; Leroy, N.; Letendre, N.; Levin, Y.; Lewis, J. B.; Li, T. G. F.; Libson, A.; Littenberg, T. B.; Lockerbie, N. A.; Lombardi, A. L.; Lord, J. E.; Lorenzini, M.; Loriette, V.; Lormand, M.; Losurdo, G.; Lough, J. D.; Lueck, H.; Lundgren, A. P.; Lynch, R.; Ma, Y.; Machenschalk, B.; MacInnis, M.; Macleod, D. M.; Magana-Sandoval, F.; Zertuche, L. Magana; Magee, R. M.; Majorana, E.; Maksimovic, I.; Malvezzi, V.; Man, N.; Mandic, V.; Mangano, V.; Mansell, G. L.; Manske, M.; Mantovani, M.; Marchesoni, F.; Marion, F.; Marka, S.; Marka, Z.; Markosyan, A. S.; Maros, E.; Martelli, F.; Martellini, L.; Martin, I. W.; Martynov, D. V.; Marx, J. N.; Mason, K.; Masserot, A.; Massinger, T. J.; Masso-Reid, M.; Mastrogiovanni, S.; Matichard, F.; Matone, L.; Mavalvala, N.; Mazumder, N.; McCarthy, R.; McClelland, D. E.; McCormick, S.; McGuire, S. C.; McIntyre, G.; McIver, J.; McManus, D. J.; McRae, T.; McWilliams, S. T.; Meacher, D.; Meadors, G. D.; Meidam, J.; Melatos, A.; Mendell, G.; Mercer, R. A.; Merilh, E. L.; Merzougui, M.; Meshkov, S.; Messenger, C.; Messick, C.; Metzdorff, R.; Meyers, P. M.; Mezzani, F.; Miao, H.; Michel, C.; Middleton, H.; Mikhailov, E. E.; Milano, L.; Miller, A. L.; Miller, A. L.; Miller, B.; Miller, J.; Millhouse, M.; Minenkov, Y.; Ming, J.; Mirshekari, S.; Mishra, C.; Mitra, S.; Mitrofanov, V. P.; Mitselmakher, G.; Mittleman, R.; Moggi, A.; Mohan, M.; Mohapatra, S. R. P.; Montani, M.; Moore, B.C.; Moore, J.C.; Moraru, D.; Gutierrez Moreno, M.; Morriss, S. R.; Mossavi, K.; Mours, B.; Mow-Lowry, C. M.; Mueller, G.; Muir, A. W.; Mukherjee, Arunava; Mukherjee, S.D.; Mukherjee, S.; Mukund, N.; Mullavey, A.; Munch, J.; Murphy, D. J.; Murray, P.G.; Mytidis, A.; Nardecchia, I.; Naticchioni, L.; Nayak, R. K.; Nedkova, K.; Nelemans, G.; Nelson, T. J. N.; Gutierrez-Neri, M.; Neunzert, A.; Newton-Howes, G.; Nguyen, T. T.; Nielsen, A. B.; Nissanke, S.; Nitz, A.; Nocera, F.; Nolting, D.; Normandin, M. E. N.; Nuttall, L. K.; Oberling, J.; Ochsner, E.; O'Dell, J.; Oelker, E.; Ogin, G. H.; Oh, J.; Oh, S. H.; Ohme, F.; Oliver, M. B.; Oppermann, P.; Oram, Richard J.; O'Reilly, B.; O'Shaughnessy, R.; Ottaway, D. J.; Overmier, H.; Owen, B. J.; Pai, A.; Pai, S. A.; Palamos, J. R.; Palashov, O.; Palomba, C.; Pal-Singh, A.; Pan, H.; Pankow, C.; Pant, B. C.; Paoletti, F.; Paoli, A.; Papa, M. A.; Paris, H. R.; Parker, W.S; Pascucci, D.; Pasqualetti, A.; Passaquieti, R.; Passuello, D.; Patricelli, B.; Patrick, Z.; Pearlstone, B. L.; Pedraza, M.; Pedurand, R.; Pekowsky, L.; Pele, A.; Penn, S.; Perreca, A.; Perri, L. M.; Phelps, M.; Piccinni, O. J.; Pichot, M.; Piergiovanni, F.; Pierro, V.; Pillant, G.; Pinard, L.; Pinto, I. M.; Pitkin, M.; Poe, M.; Poggiani, R.; Popolizio, P.; Post, A.; Powell, J.; Prasad, J.; Predoi, V.; Prestegard, T.; Price, L. R.; Prijatelj, M.; Principe, M.; Privitera, S.; Prodi, G. A.; Prokhorov, L. G.; Puncken, O.; Punturo, M.; Puppo, P.; Puerrer, M.; Qi, H.; Qin, J.; Qiu, S.; Quetschke, V.; Quintero, E. A.; Quitzow-James, R.; Raab, F. J.; Rabeling, D. S.; Radkins, H.; Raffai, P.; Raja, S.; Rajan, C.; Rakhmanov, M.; Rapagnani, P.; Raymond, V.; Razzano, M.; Re, V.; Read, J.; Reed, C. M.; Regimbau, T.; Rei, L.; Reid, S.; Reitze, D. H.; Rew, H.; Reyes, S. D.; Ricci, F.; Riles, K.; Rizzo, D.M.; Robertson, N. A.; Robie, R.; Robinet, F.; Rocchi, A.; Rolland, L.; Rollins, J. G.; Roma, V. J.; Romano, J. D.; Romano, R.; Romanov, G.; Romie, J. H.; Rosinska, D.; Rowan, S.; Ruediger, A.; Ruggi, P.; Ryan, K.A.; Sachdev, P.S.; Sadecki, T.; Sadeghian, L.; Sakellariadou, M.; Salconi, L.; Saleem, M.; Salemi, F.; Samajdar, A.; Sammut, L.; Sanchez, E. J.; Sandberg, V.; Sandeen, B.; Sanders, J. R.; Sassolas, B.; Saulson, P. R.; Sauter, O. E. S.; Savage, R. L.; Sawadsky, A.; Schale, P.; Schilling, R.; Schmidt, J; Schmidt, P.; Schnabel, R.B.; Schofield, R. M. S.; Schoenbeck, A.; Schreiber, K.E.C.; Schuette, D.; Schutz, B. F.; Scott, J.; Scott, M.S.; Sellers, D.; Sengupta, A. S.; Sentenac, D.; Sequino, V.; Sergeev, A.; Setyawati, Y.; Shaddock, D. A.; Shaffer, T. J.; Shahriar, M. S.; Shaltev, M.; Shapiro, B.; Shawhan, P.; Sheperd, A.; Shoemaker, D. H.; Siellez, K.; Siemens, X.; Sieniawska, M.; Sigg, D.; Silva, António Dias da; Singer, A; Singer, L. P.; Singh, A.; Singh, R.; Singhal, A.; Sintes, A. M.; Slagmolen, B. J. J.; Smith, R. J. E.; Smith, N.D.; Smith, R. J. E.; Son, E. J.; Sorazu, B.; Sorrentino, F.; Souradeep, T.; Srivastava, A. K.; Staley, A.; Steinke, M.; Steinlechner, J.; Steinlechner, S.; Steinmeyer, D.; Stephens, B. C.; Stone, J.R.; Strain, K. A.; Straniero, N.; Stratta, G.; Strauss, N. A.; Strigin, S. E.; Sturani, R.; Stuver, A. L.; Summerscales, T. Z.; Sun, L.; Sunil, S.; Sutton, P. J.; Swinkels, B. L.; Szczepanczyk, M. J.; Tacca, M.D.; Talukder, D.; Tanner, D. B.; Tapai, M.; Tarabrin, S. P.; Taracchini, A.; Taylor, W.R.; Theeg, T.; Thirugnanasambandam, M. P.; Thomas, E. G.; Thomas, M.; Thomas, P.; Thorne, K. A.; Thorne, K. S.; Thrane, E.; Tiwari, S.; Tiwari, V.; Tokmakov, K. V.; Toland, K.; Tomlinson, C.; Tonelli, M.; Tornasi, Z.; Torres, C. V.; Torrie, C. I.; Toyra, D.; Travasso, F.; Traylor, G.; Trifiro, D.; Tringali, M. C.; Trozzo, L.; Tse, M.; Turconi, M.; Tuyenbayev, D.; Ugolini, D.; Unnikrishnan, C. S.; Urban, A. L.; Usman, S. A.; Vahlbruch, H.; Vajente, G.; Valdes, G.; van Bakel, N.; Van Beuzekom, Martin; van den Brand, J. F. J.; Van Den Broeck, C.F.F.; Vander-Hyde, D. C.; van der Schaaf, L.; van Heijningen, J. V.; van Veggel, A. A.; Vardaro, M.; Vass, S.; Vasuth, M.; Vaulin, R.; Vecchio, A.; Vedovato, G.; Veitch, J.; Veitch, P.J.; Venkateswara, K.; Verkindt, D.; Vetrano, F.; Vicere, A.; Vinciguerra, S.; Vine, D. J.; Vinet, J. -Y.; Vitale, S.; Vo, T.; Vocca, H.; Vorvick, C.; Voss, D. V.; Vousden, W. D.; Vyatchanin, S. P.; Wade, A. R.; Wade, L. E.; Wade, MT; Walker, M.; Wallace, L.; Walsh, S.; Wang, G.; Wang, H.; Wang, M.; Wang, X.; Wang, Y.; Ward, R. L.; Warner, J.; Was, M.; Weaver, B.; Wei, L. -W.; Weinert, M.; Weinstein, A. J.; Weiss, R.; Wen, L.M.; Wessels, P.; Westphal, T.; Wette, K.; Whelan, J. T.; Whiting, B. F.; Williams, D.R.; Williamson, A. R.; Willis, J. L.; Willke, B.; Wimmer, M. H.; Winkler, W.; Wipf, C. C.; Wittel, H.; Woan, G.; Woehler, J.; Worden, J.; Wright, J.L.; Wu, D.S.; Wu, G.; Yablon, J.; Yam, W.; Yamamoto, H.; Yancey, C. C.; Yu, H.; Yvert, M.; Zadrozny, A.; Zangrando, L.; Zanolin, M.; Zendri, J. -P.; Zevin, M.; Zhang, L.; Zhang, M.; Zhang, Y.; Zhao, C.; Zhou, M.; Zhou, Z.; Zhu, X. J.; Zucker, M. E.; Zuraw, S. E.; Zweizig, J.; Boyle, M.; Campanelli, M.; Chu, I.W.T.; Clark, M.; Fauchon-Jones, E. J.; Fong, H.; Healy, J.; Hemberger, D.; Hinder, I.; Husa, S.; Kalaghati, C.; Khan., S.; Kidder, L. E.; Kinsey, M.; Laguna, P.; London, L. T.; Lousto, C. O.; Lovelace, G.; Ossokine, S.; Pannarale, F.; Pfeiffer, H. P.; Scheel, M.; Shoemaker, D. M.; Szilagyi, B.; Teukolsky, S.; Vinuales, A. Vano; Zlochower, Y.

    2016-01-01

    We compare GW150914 directly to simulations of coalescing binary black holes in full general relativity, including several performed specifically to reproduce this event. Our calculations go beyond existing semianalytic models, because for all simulations—including sources with two independent,

  17. Proton transport in a binary biomimetic solution revealed by molecular dynamics simulation

    NARCIS (Netherlands)

    Liang, Chungwen; Jansen, Thomas L. C.

    2011-01-01

    We report the simulation results of the proton transport in a binary mixture of amphiphilic tetramethylurea (TMU) molecules and water. We identify different mechanisms that either facilitate or retard the proton transport. The efficiency of these mechanisms depends on the TMU concentration. The

  18. Application of experimental design and derivative spectrophotometry methods in optimization and analysis of biosorption of binary mixtures of basic dyes from aqueous solutions.

    Science.gov (United States)

    Asfaram, Arash; Ghaedi, Mehrorang; Ghezelbash, Gholam Reza; Pepe, Francesco

    2017-05-01

    Simultaneous biosorption of malachite green (MG) and crystal violet (CV) on biosorbent Yarrowia lipolytica ISF7 was studied. An appropriate derivative spectrophotometry technique was used to evaluate the concentration of each dye in binary solutions, despite significant interferences in visible light absorbances. The effects of pH, temperature, growth time, initial MG and CV concentration in batch experiments were assessed using Design of Experiment (DOE) according to central composite second order response surface methodology (RSM). The analysis showed that the greatest biosorption efficiency (>99% for both dyes) can be obtained at pH 7.0, T=28°C, 24h mixing and 20mgL -1 initial concentrations for both MG and CV dyes. The quadratic constructed equation ability for fitting experimental data is judged based on criterions like R 2 values, significant p and lack-of-fit value strongly confirm its high adequacy and applicability for prediction of revel behavior of the system under study. The proposed model showed very high correlation coefficients (R 2 =0.9997 for CV and R 2 =0.9989 for MG), while supported by closeness of predicted and experimental value. A kinetic analysis was carried out, showing that for both dyes a pseudo-second order kinetic model adequately describes the available data. The Langmuir isotherm model in single and binary components has better performance for description of dyes biosorption with maximum monolayer biosorption capacity of 59.4 and 62.7mgg -1 in single component and 46.4 and 50.0mgg -1 for CV and MB in binary components, respectively. The surface structure of biosorbents and the possible biosorbents-dyes interactions between were also evaluated by Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). The values of thermodynamic parameters including ΔG° and ΔH° strongly confirm which method is spontaneous and endothermic. Copyright © 2017. Published by Elsevier Inc.

  19. Binary Pseudo-Random Gratings and Arrays for Calibration of Modulation Transfer Functions of Surface Profilometers

    Energy Technology Data Exchange (ETDEWEB)

    Barber, Samuel K.; Anderson, Erik D.; Cambie, Rossana; McKinney, Wayne R.; Takacs, Peter Z.; Stover, John C.; Voronov, Dmitriy L.; Yashchuk, Valeriy V.

    2009-09-11

    A technique for precise measurement of the modulation transfer function (MTF), suitable for characterization of a broad class of surface profilometers, is investigated in detail. The technique suggested in [Proc. SPIE 7077-7, (2007), Opt. Eng. 47(7), 073602-1-5 (2008)]is based on use of binary pseudo-random (BPR) gratings and arrays as standard MTF test surfaces. Unlike most conventional test surfaces, BPR gratings and arrays possess white-noise-like inherent power spectral densities (PSD), allowing the direct determination of the one- and two-dimensional MTF, respectively, with a sensitivity uniform over the entire spatial frequency range of a profiler. In the cited work, a one dimensional realization of the suggested method based on use of BPR gratings has been demonstrated. Here, a high-confidence of the MTF calibration technique is demonstrated via cross comparison measurements of a number of two dimensional BPR arrays using two different interferometric microscopes and a scatterometer. We also present the results of application of the experimentally determined MTF correction to the measurement taken with the MicromapTM-570 interferometric microscope of the surface roughness of a super-polished test mirror. In this particular case, without accounting for the instrumental MTF, the surface rms roughness over half of the instrumental spatial frequency bandwidth would be underestimated by a factor of approximately 1.4.

  20. Experimental and theoretical study of surface tension of binary mixtures of (n-alkyl acetates + heptane, benzene, and toluene)

    International Nuclear Information System (INIS)

    Rafati, Amir Abbas; Ghasemian, Ensieh

    2009-01-01

    Surface properties of binary mixtures of (n-alkyl acetates + heptane, benzene, and toluene) have been measured by surface tension method at T = 298.15 K and atmospheric pressure. Also, the surface tension has been predicted based on the Suarez method. This method combines a model for the description of surface tension of liquid mixtures with a group contribution method for the calculation of activity coefficient. The mean relative standard deviations obtained from the comparison of experimental (measured) and calculated surface tension values for the eight binary systems are less than 1.5%, which leads to concluding that the model shows a good accuracy in different situations in comparison with other predicted equations. In addition, the relative Gibbs adsorption and the surface mole fraction have been evaluated using this model. The surface tension deviations were calculated from experimental results and have been fitted to the Redlich-Kister type polynomial relation

  1. Viscosity and surface tension of binary systems of N,N-dimethylformamide with alkan-1-ols at different temperatures

    International Nuclear Information System (INIS)

    Mohammad, Abubaker A.; Alkhaldi, Khaled H.A.E.; AlTuwaim, Mohammad S.; Al-Jimaz, Adel S.

    2013-01-01

    Highlights: ► Physical properties of binary mixtures of DMF+1-pentanol, 1-hexanol, or 1-heptanol. ► Viscosity and surface tension were measured. ►Δη, Δσ σ and G ∗E were calculated using the experimental data. ► H σ and S σ were determined using the surface tension data. ► Semi-empirical relations were used to estimate the viscosity of liquid mixtures. - Abstract: Viscosity η and surface tension σ were measured for binary mixtures of N,N-dimethylformamide DMF with pentan-1-ol, hexan-1-ol, and heptan-1-ol at T = (298.15, 303.15, 308.15, and 313.15) K and atmospheric pressure over the entire mole fraction range. Deviations in viscosity Δη and surface tension Δσ were calculated using experimental results. Moreover, the values of the excess Gibbs free energy of activation G ∗E , surface enthalpy H σ and surface entropy S σ of these mixtures were determined. Viscosity measurements of the binary systems were correlated with Grunberg and Nissan, the three-body and four-body McAllister expressions. Viscosity deviation, surface tension deviation and excess Gibbs energy of activation functions were fitted to the method of Redlich–Kister (R–K) polynomial to estimate the coefficients and standard deviations. The effects of chain length of alkan-1-ols and temperature on the thermodynamic properties of binary systems were studied.

  2. Evaluation of Surface Mechanical Properties and Grindability of Binary Ti Alloys Containing 5 wt % Al, Cr, Sn, and V

    Directory of Open Access Journals (Sweden)

    Hae-Soon Lim

    2017-11-01

    Full Text Available This study aimed to investigate the relationship between the surface mechanical properties and the grindability of Ti alloys. Binary Ti alloys containing 5 wt % concentrations of Al, Cr, Sn, or V were prepared using a vacuum arc melting furnace, and their surface properties and grindability were compared to those of commercially pure Ti (cp-Ti. Ti alloys containing Al and Sn had microstructures that consisted of only α phase, while Ti alloys containing Cr and V had lamellar microstructures that consisted of α + β phases. The Vickers microhardness of Ti alloys was increased compared to those of cp-Ti by the solid solution strengthening effect. Among Ti alloys, Ti alloy containing Al had the highest Vickers microhardness. At a low SiC wheel speed of 5000 rpm, the grinding rates of Ti alloys showed an increasing tendency as the hardness values of Ti alloys decreased. At a high SiC wheel speed of 10,000 rpm, the grinding rates of Ti alloys showed an increasing tendency as the tensile strength values increased. The Ti alloy containing Al, which showed the lowest tensile strength, had the lowest grinding rate. The grinding ratios of the Ti alloys were higher than those of cp-Ti at both wheel revolution speeds of 5000 and 10,000 rpm. The grinding ratio of the Ti alloy containing Al was significantly increased at 10,000 rpm (p < 0.05.

  3. Synthesis and characterization of β type solid solution in the binary ...

    Indian Academy of Sciences (India)

    Unknown

    Abstract. We have investigated Bi2O3–Eu2O3 binary system by doping with Eu2O3 in the composition range from 1 to 10 mole% via solid state reactions and succeeded to stabilize β-Bi2O3 phase which is metastable when pure. Stability of β-Bi2O3 polymorph was influenced by heat treatment temperature. Tetragonal type.

  4. Determination and correlation of solubility and solution thermodynamics of oxiracetam in three (alcohol + water) binary solvents

    International Nuclear Information System (INIS)

    Li, Kangli; Du, Shichao; Wu, Songgu; Cai, Dongchen; Wang, Jinxu; Zhang, Dejiang; Zhao, Kaifei; Yang, Peng; Yu, Bo; Guo, Baisong; Li, Daixi; Gong, Junbo

    2016-01-01

    Highlights: • The solubility of racemic oxiracetam in three binary solvents were determined. • The experimental solubility of racemic oxiracetam were correlated by four models. • The dissolution thermodynamic properties of racemic oxiracetam were calculated. - Abstract: In this paper, we proposed a static analysis method to experimentally determine the (solid + liquid) equilibrium of racemic oxiracetam in (methanol + water), (ethanol + water) and (isopropanol + water) binary solvents with alcohol mole fraction ranging from 0.30 to 0.90 at atmosphere pressure (p = 0.1 MPa). For the experiments, the temperatures range from (283.15 to 308.15) K. The results showed that the solubility of oxiracetam increased with the increasing temperature, while decreased with the increasing organic solvent fraction in all three tested binary solvent systems. The modified Apelblat model, the CNIBS/Redlich–Kister model, the combined version of Jouyban–Acree model and the NRTL model were employed to correlate the measured solubility values, respectively. Additionally, some of the thermodynamic properties which can help to evaluate its dissolution behavior were obtained based on the NRTL model.

  5. Separation of Lead (Pb2+ and Cadmium (Cd2+ from Single and Binary Salt Aqueous Solutions Using Nanofiltration Membranes

    Directory of Open Access Journals (Sweden)

    Ahmed Abed Mohammed

    2016-04-01

    Full Text Available The present work reports on the performance of three types of nanofiltration membranes in the removal of highly polluting and toxic lead (Pb2+ and cadmium (Cd2+ from single and binary salt aqueous solutions simulating real wastewaters. The effect of the operating variables (pH (5.5-6.5, types of NF membrane and initial ions concentration (10-250 ppm on the separation process and water flux was investigated. It was observed that the rejection efficiency increased with increasing pH of solution and decreasing the initial metal ions concentrations. While the flux decreased with increasing pH of solution and increasing initial metal ions concentrations. The maximum rejection of lead and cadmium ions in single salt solution was 99%, 97.5 % and 98 % at pH 6, 6.5 and 6.2 and 78%, 49.2% and 44% at pH 6.5, 6.2 and 6.5 for NF1, NF2 and NF3 respectively. On the other hand, maximum permeate flux for single NF2 (32.2> NF3 (16.1>NF1 (14.2 (l/m2.h for 100 ppm, higher than binary salt solution was NF2 (23.7 ˃ NF3 (13 ˃ NF1 (8 (l/m2.h for (10 Pb2+/50 Cd2+ ppm. The NF membranes proved able to achieve high separation efficiency of both lead and cadmium ions in very suitable conditions, leaving wastewaters in a condition suitable prior discharged into the environment.

  6. Evaluation of Solid-Solution Hardening in Several Binary Alloy Systems Using Diffusion Couples Combined with Nanoindentation

    Science.gov (United States)

    Kadambi, Sourabh B.; Divya, V. D.; Ramamurty, U.

    2017-10-01

    Analysis of solid-solution hardening (SSH) in alloys requires the synthesis of large composition libraries and the measurement of strength or hardness from these compositions. Conventional methods of synthesis and testing, however, are not efficient and high-throughput approaches have been developed in the past. In the present study, we use a high-throughput combinatorial approach to examine SSH at large concentrations in binary alloys of Fe-Ni, Fe-Co, Pt-Ni, Pt-Co, Ni-Co, Ni-Mo, and Co-Mo. The diffusion couple (DC) method is used to generate concentration ( c) gradients and the nanoindentation (NI) technique to measure the hardness ( H) along these gradients. The obtained H -c profiles are analyzed within the framework of the Labusch model of SSH, and the c^{2/3} dependence of H predicted by the model is found to be generally applicable. The SSH behavior obtained using the combinatorial method is found to be largely consistent with that observed in the literature using conventional and DC-NI methods. This study evaluates SSH in Fe-, Ni-, Co-, and Pt-based binary alloys and confirms the applicability of the DC-NI approach for rapidly screening various solute elements for their SSH ability.

  7. Solution equilibrium of metal ions-binary complexes with 3-(2-ethylamino-1-hydroxyethyl] phenol (Effortil

    Directory of Open Access Journals (Sweden)

    Mohamed Magdy Khalil

    2016-11-01

    Full Text Available Formation of binary complexes of Al(III, Cr(III, Fe(III, Th(IV, UO2(II, Ce(III, La(III, and Gd(III with 3-(2-ethylamino-1-hydroxyethyl] phenol (Effortil were studied potentiometrically at 37.0 °C and I = 0.16 mol dm−3 NaNO3 in aqueous solution. The acid–base properties of Effortil were investigated and discussed. The order of stability of the complexes was investigated and is discussed in terms of the metal ion. The experimental pH titration data were analyzed in order to evaluate the formation constants of various intermediate species formed. The concentration distribution of various species formed in solution was evaluated.

  8. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data.

  9. Selective nonspecific solvation under dielectric saturation and fluorescence spectra of dye solutions in binary solvents.

    Science.gov (United States)

    Bakhshiev, N G; Kiselev, M B

    1991-09-01

    The influence of selective nonspecific solvation on the fluorescence spectra of three substitutedN-methylphthalimides in a binary solvent system consisting of a nonpolar (n-heptane) and a polar (pyridine) component has been studied under conditions close to dielectric saturation. The substantially nonlinearity of the effect is confirmation that the spectral shifts of fluorescence bands depend on the number of polar solvent molecules involved in solvating the dye molecule. The measured fluorescence spectral shifts determined by substituting one nonpolar solvent molecula with a polar one in the proximity of the dye molecule agree quantitatively with the forecasts of the previously proposed semiempirical theory which describes this nonlinear solvation phenomenon.

  10. Surface phase transitions in cu-based solid solutions

    Science.gov (United States)

    Zhevnenko, S. N.; Chernyshikhin, S. V.

    2017-11-01

    We have measured surface energy in two-component Cu-based systems in H2 + Ar gas atmosphere. The experiments on solid Cu [Ag] and Cu [Co] solutions show presence of phase transitions on the surfaces. Isotherms of the surface energy have singularities (the minimum in the case of copper solid solutions with silver and the maximum in the case of solid solutions with cobalt). In both cases, the surface phase transitions cause deficiency of surface miscibility: formation of a monolayer (multilayer) (Cu-Ag) or of nanoscale particles (Cu-Co). At the same time, according to the volume phase diagrams, the concentration and temperature of the surface phase transitions correspond to the solid solution within the volume. The method permits determining the rate of diffusional creep in addition to the surface energy. The temperature and concentration dependence of the solid solutions' viscosity coefficient supports the fact of the surface phase transitions and provides insights into the diffusion properties of the transforming surfaces.

  11. A novel binary shape context for 3D local surface description

    Science.gov (United States)

    Dong, Zhen; Yang, Bisheng; Liu, Yuan; Liang, Fuxun; Li, Bijun; Zang, Yufu

    2017-08-01

    3D local surface description is now at the core of many computer vision technologies, such as 3D object recognition, intelligent driving, and 3D model reconstruction. However, most of the existing 3D feature descriptors still suffer from low descriptiveness, weak robustness, and inefficiency in both time and memory. To overcome these challenges, this paper presents a robust and descriptive 3D Binary Shape Context (BSC) descriptor with high efficiency in both time and memory. First, a novel BSC descriptor is generated for 3D local surface description, and the performance of the BSC descriptor under different settings of its parameters is analyzed. Next, the descriptiveness, robustness, and efficiency in both time and memory of the BSC descriptor are evaluated and compared to those of several state-of-the-art 3D feature descriptors. Finally, the performance of the BSC descriptor for 3D object recognition is also evaluated on a number of popular benchmark datasets, and an urban-scene dataset is collected by a terrestrial laser scanner system. Comprehensive experiments demonstrate that the proposed BSC descriptor obtained high descriptiveness, strong robustness, and high efficiency in both time and memory and achieved high recognition rates of 94.8%, 94.1% and 82.1% on the considered UWA, Queen, and WHU datasets, respectively.

  12. Relationships between surface coverage ratio and powder mechanics of binary adhesive mixtures for dry powder inhalers.

    Science.gov (United States)

    Rudén, Jonas; Frenning, Göran; Bramer, Tobias; Thalberg, Kyrre; Alderborn, Göran

    2018-04-25

    The aim of this paper was to study relationships between the content of fine particles and the powder mechanics of binary adhesive mixtures and link these relationships to the blend state. Mixtures with increasing amounts of fine particles (increasing surface coverage ratios (SCR)) were prepared using Lactopress SD as carrier and micro particles of lactose as fines (2.7 µm). Indicators of unsettled bulk density, compressibility and flowability were derived and the blend state was visually examined by imaging. The powder properties studied showed relationships to the SCR characterised by stages. At low SCR, the fine particles predominantly gathered in cavities of the carriers, giving increased bulk density and unchanged or improved flow. Thereafter, increased SCR gave a deposition of particles at the enveloped carrier surface with a gradually more irregular adhesion layer leading to a reduced bulk density and a step-wise reduced flowability. The mechanics of the mixtures at a certain stage were dependent on the structure and the dynamics of the adhesion layer and transitions between the stages were controlled by the evolution of the adhesion layer. It is advisable to use techniques based on different types of flow in order to comprehensively study the mechanics of adhesive mixtures. Copyright © 2018 Elsevier B.V. All rights reserved.

  13. The Spatiotemporal Oscillations of Order Parameter for Isothermal Model of the Surface-Directed Spinodal Decomposition in Bounded Binary Mixtures

    Directory of Open Access Journals (Sweden)

    Igor B. Krasnyuk

    2009-01-01

    Full Text Available The asymptotical behavior of order parameter in confined binary mixture is considered in one-dimensional geometry. The interaction between bulk and surface forces in the mixture is investigated. Its established conditions are when the bulk spinodal decomposition may be ignored and when the main role in the process of formation of the oscillating asymptotic periodic spatiotemporal structures plays the surface-directed spinodal decomposition which is modelled by nonlinear dynamical boundary conditions.

  14. Phase transitions of n-hexadecane in nanoencapsulated binary solutions of n-hexadecane and 1-octanol.

    Science.gov (United States)

    Tubbs, Kyle W; Nguyen, Vincent T; Adalsteinsson, Thorsteinn

    2012-04-05

    Binary solutions of n-hexadecane and 1-octanol were encapsulated within poly(tert-butyl methacrylate) nanocapsules and the phase transition behavior of the n-hexadecane studied. A sigmoidal correlation was found between the binary composition of the encapsulated oil and the oil formulation prior to encapsulation. At low 1-octanol fractions in the synthesis, almost no alcohol was encapsulated, but at high 1-octanol fractions, the capsules were enriched in alcohol. The freezing point of the encapsulated n-hexadecane was considerably lower than in the bulk phase. This freezing point was further reduced as the radius of the particle was reduced, which is expected from the Gibbs-Thompson equation. The extracted value at infinite radii was, however, 14 °C below the bulk freezing point. The colligative effect of 1-octanol on the freezing point of n-hexadecane, i.e., dT(f)/dx(m), where x(m) is the mass fraction of 1-octanol, was nearly identical to that measured in the bulk system. The specific enthalpy of freezing for the encapsulated system was considerably different from the bulk system. In the bulk system, the freezing enthalpy for n-hexadecane was nearly constant up to 60% mass of 1-octanol. The freezing enthalpy for the encapsulated n-hexadecane showed greater variation with % mass 1-octanol, and had a considerably lower absolute value than the bulk system.

  15. Dynamic surface properties of poly(methylalkyldiallylammonium chloride) solutions

    Czech Academy of Sciences Publication Activity Database

    Novikova, A. A.; Vlasov, P. S.; Lin, S.-Y.; Sedláková, Zdeňka; Noskov, B. A.

    2017-01-01

    Roč. 80, November (2017), s. 122-127 ISSN 1876-1070 Institutional support: RVO:61389013 Keywords : polymer solutions * dynamic surface tension * dilational surface rheology Subject RIV: CD - Macromolecular Chemistry OBOR OECD: Polymer science Impact factor: 4.217, year: 2016

  16. Exact solution to surface displacement associated with sources ...

    African Journals Online (AJOL)

    user

    Usually an exact solution to the surface displacement in an elastic half space is available for sources parallel to the surface. Here we consider a buried elliptic source ... used Laplace–Hankel mixed transform and transfer matrix techniques along with the Fast Hankel transform algorithm for an impulsive ring source within a ...

  17. Maintenance Solutions for Bleeding and Flushed Pavements Surfaced with a Seal Coat or Surface Treatment

    Science.gov (United States)

    2007-02-01

    This report summarizes the findings of research directed at identifying maintenance solutions for bleeding and : flushed asphalt pavements surfaced with seal coats or surface treatments. Although the basic mechanism associated with : both bleeding an...

  18. Ionic enhancement of silica surface nanowear in electrolyte solutions

    KAUST Repository

    Vakarelski, Ivan Uriev

    2012-11-20

    The nanoscale wear and friction of silica and silicon nitride surfaces in aqueous electrolyte solutions were investigated by using sharp atomic force microscope (AFM) cantilever tips coated with silicon nitride. Measurements were carried out in aqueous solutions of varying pH and in monovalent and divalent cation chloride and nitrate solutions. The silica surface was shown to wear strongly in solutions of high pH (≈11.0), as expected, but the presence of simple cations, such as Cs+ and Ca2+, was shown to dramatically effect the wear depth and friction force for the silica surface. In the case of monovalent cations, their hydration enthalpies correlated well with the wear and friction. The weakest hydrated cation of Cs+ showed the most significant enhancement of wear and friction. In the case of divalent cations, a complex dependence on the type of cation was found, where the type of anion was also seen to play an important role. The CaCl2 solution showed the anomalous enhancement of wear depth and friction force, although the solution of Ca(NO3)2 did not. The present results obtained with an AFM tip were also compared with previous nanotribology studies of silica surfaces in electrolyte solutions, and possible molecular mechanisms as to why cations enhance the wear and friction were also discussed. © 2012 American Chemical Society.

  19. Photometry of long-period Algol binaries. VI. Multicolor photometric solutions for RZ Cancri

    Energy Technology Data Exchange (ETDEWEB)

    Olson, E.C. (Illinois Univ., Urbana (USA))

    1989-09-01

    New intermediate-band photometry of the late-giant eclipsing system RZ CNc is used to obtain photometric solutions, both with the Popper (1976) spectroscopic mass ratio and by allowing the mass ratio and gravity-darkening coefficients to vary. New y observations are combined with earlier V data of Lenouvel (1957) and Broglia and Conconi (1973) in one solution set. Additional solutions are obtained from the new observations. The mean photometric mass ratio is somewhat larger than Popper's spectroscopic values; the general indeterminacy of photometric solutions may explain this apparent discrepancy. Possible photometric effects of a mass-transferring stream are discussed, and it is concluded that such effects cannot account for the mass-ratio discrepancy. 26 refs.

  20. Boundary properties of solutions of equations of minimal surface kind

    Science.gov (United States)

    Miklyukov, V. M.

    2001-10-01

    Generalized solutions of equations of minimal-surface type are studied. It is shown that a solution makes at most countably many jumps at the boundary. In particular, a solution defined in the exterior of a disc extends by continuity to the boundary circle everywhere outside a countable point set. An estimate of the sum of certain non-local characteristics of the jumps of a solution at the boundary is presented. A result similar to Fatou's theorem on angular boundary values is proved.

  1. Predicting the vapor-liquid equilibrium of hydrocarbon binary mixtures and polymer solutions using predetermined pure component parameters

    Science.gov (United States)

    Ryu, Sang Kyu; Bae, Young Chan

    2012-05-01

    In our previous work, a new close-packed lattice model was developed for multi-component system of chain fluids with taking the chain length dependence from Monte-Carlo (MC) simulation results into account. In this work, we further extend this model to describe pressure, volume and temperature (PVT) properties, such as vapor-liquid equilibrium (VLE). To consider the effect of pressure on the phase behavior, the volume change effect is taken into account by introducing holes into the incompressible lattice model with two mixing steps. The corresponding new lattice fluid equation of state (LF-EoS) is applied to predict the thermodynamic properties of pure and binary mixtures of hydrocarbons as well as pure polymer solutions. The results of the proposed model are compared to other predictive approaches based on VLE calculations using predetermined pure model parameters without further adjustment. Thermodynamic properties predicted using the method developed in this work are consistent with the experimental data.

  2. The experimental study of establishing local order in binary metallic solid solutions

    International Nuclear Information System (INIS)

    Khwaja, F.A.; Katsnelson, A.A.

    1980-09-01

    The results of investigations of the values of the short-range order parameter are summarized for a number of solid solutions. The values of the short-range order (SRO) parameter are shown to be monotonically dependent upon the annealing temperatures and times and also upon the concentration of the solute atoms in plastically deformed, neutron irradiated or quenched samples of these solid solutions. The appearance of type II SRO, or local order, at a certain stage of annealing has been discussed in a series of transition metal alloys. The possible role of the submicroregions of excess concentration has been analyzed to explain the local order in these alloys. The possibility for the nucleation of Long-Range order in some of the alloys has also been considered. (author)

  3. THE ELM SURVEY. V. MERGING MASSIVE WHITE DWARF BINARIES

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Warren R.; Kenyon, Scott J. [Smithsonian Astrophysical Observatory, 60 Garden St, Cambridge, MA 02138 (United States); Kilic, Mukremin; Gianninas, A. [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W. Brooks St., Norman, OK, 73019 (United States); Allende Prieto, Carlos, E-mail: wbrown@cfa.harvard.edu, E-mail: skenyon@cfa.harvard.edu, E-mail: kilic@ou.edu, E-mail: alexg@nhn.ou.edu, E-mail: callende@iac.es [Instituto de Astrofisica de Canarias, E-38205, La Laguna, Tenerife (Spain)

    2013-05-20

    We present the discovery of 17 low-mass white dwarfs (WDs) in short-period (P {<=} 1 day) binaries. Our sample includes four objects with remarkable log g {approx_equal} 5 surface gravities and orbital solutions that require them to be double degenerate binaries. All of the lowest surface gravity WDs have metal lines in their spectra implying long gravitational settling times or ongoing accretion. Notably, six of the WDs in our sample have binary merger times <10 Gyr. Four have {approx}>0.9 M{sub Sun} companions. If the companions are massive WDs, these four binaries will evolve into stable mass transfer AM CVn systems and possibly explode as underluminous supernovae. If the companions are neutron stars, then these may be millisecond pulsar binaries. These discoveries increase the number of detached, double degenerate binaries in the ELM Survey to 54; 31 of these binaries will merge within a Hubble time.

  4. THE ELM SURVEY. V. MERGING MASSIVE WHITE DWARF BINARIES

    International Nuclear Information System (INIS)

    Brown, Warren R.; Kenyon, Scott J.; Kilic, Mukremin; Gianninas, A.; Allende Prieto, Carlos

    2013-01-01

    We present the discovery of 17 low-mass white dwarfs (WDs) in short-period (P ≤ 1 day) binaries. Our sample includes four objects with remarkable log g ≅ 5 surface gravities and orbital solutions that require them to be double degenerate binaries. All of the lowest surface gravity WDs have metal lines in their spectra implying long gravitational settling times or ongoing accretion. Notably, six of the WDs in our sample have binary merger times 0.9 M ☉ companions. If the companions are massive WDs, these four binaries will evolve into stable mass transfer AM CVn systems and possibly explode as underluminous supernovae. If the companions are neutron stars, then these may be millisecond pulsar binaries. These discoveries increase the number of detached, double degenerate binaries in the ELM Survey to 54; 31 of these binaries will merge within a Hubble time.

  5. Photo-degradation of basic green 1 and basic red 46 dyes in their binary solution by La2O3-Al2O3nanocomposite using first-order derivative spectra and experimental design methodology

    Science.gov (United States)

    Fahimirad, Bahareh; Asghari, Alireza; Rajabi, Maryam

    2017-05-01

    In this work, the lanthanum oxide-aluminum oxide (La2O3-Al2O3) nanocomposite is introduced as an efficient photocatalyst for the photo-degradation of the dyes basic green 1 (BG1) and basic red 46 (BR46) in their binary aqueous solution under the UV light irradiation. The properties of this catalyst are determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET), and UV-visible spectrophotometry. The first-order derivative spectra are used for the simultaneous analysis of the dyes in their binary solution. The screening investigations indicate that five parameters including the catalyst dosage, concentration of the dyes, irradiation time, and solution pH have significant effects on the photo-degradation of the dyes. The effects of these variables together with their interactions in the photo-degradation of the dyes are studied using the Box-Behnken design (BBD). Under the optimum experimental conditions, obtained via the desirability function, the photo-catalytic activities of La2O3-Al2O3 and pure Al2O3 are also investigated. The results obtained show an enhancement in the photo-catalytic activity when La2O3 nanoparticles are loaded on the surface of Al2O3 nanoparticles. The La2O3-Al2O3nanocomposite was synthesized as new photo-catalyst for the degradation of binary dyes. The photo-catalytic effect on the binary dyes solution was followed by the first-order derivative spectrophotometric method. Simultaneous dyes photodegradation methodology was presented by using experimental design.

  6. Forced Spreading of Aqueous Solutions on Zwitterionic Sulfobetaine Surfaces for Rapid Evaporation and Solute Separation.

    Science.gov (United States)

    Wu, Cyuan-Jhang; Singh, Vickramjeet; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2017-08-01

    Solute separation of aqueous mixtures is mainly dominated by water vaporization. The evaporation rate of an aqueous drop grows with increasing the liquid-gas interfacial area. The spontaneous spreading behavior of a water droplet on a total wetting surface provides huge liquid-gas interfacial area per unit volume; however, it is halted by the self-pinning phenomenon upon addition of nonvolatile solutes. In this work, it is shown that the solute-induced self-pinning can be overcome by gravity, leading to anisotropic spreading much faster than isotropic spreading. The evaporation rate of anisotropic spreading on a zwitterionic sulfobetaine surface is 25 times larger as that on a poly(methyl methacrylate) surface. Dramatic enhancement of evaporation is demonstrated by simultaneous formation of fog atop liquid film. During anisotropic spreading, the solutes are quickly precipitated out within 30 s, showing the rapid solute-water separation. After repeated spreading process for the dye-containing solution, the mean concentration of the collection is doubled, revealing the concentration efficiency as high as 100%. Gravity-enhanced spreading on total wetting surfaces at room temperature is easy to scale-up with less energy consumption, and thus it has great potentials for the applications of solute separation and concentration.

  7. Kinetically driven self-assembly of a binary solute mixture with controlled phase separation via electro-hydrodynamic flow of corona discharge

    Science.gov (United States)

    Jung, Hee Joon; Huh, June; Park, Cheolmin

    2012-09-01

    This feature article describes a new and facile process to fabricate a variety of thin films of non-volatile binary solute mixtures suitable for high performance organic electronic devices via electro-hydrodynamic flow of conventional corona discharge. Both Corona Discharge Coating (CDC) and a modified version of CDC, Scanning Corona Discharge Coating (SCDC), are based on utilizing directional electric flow, known as corona wind, of the charged uni-polar particles generated by corona discharge between a metallic needle and a bottom plate under a high electric field (5-10 kV cm-1). The electric flow rapidly spreads out the binary mixture solution on the bottom plate and subsequently forms a smooth and flat thin film in a large area within a few seconds. In the case of SCDC, the static movement of the bottom electrode on which a binary mixture solution is placed provides further control of thin film formation, giving rise to a film highly uniform over a large area. Interesting phase separation behaviors were observed including nanometer scale phase separation of a polymer-polymer binary mixture and vertical phase separation of a polymer-organic semiconductor mixture. Core-shell type phase separation of either polymer-polymer or polymer-colloidal nanoparticle binary mixtures was also developed with a periodically patterned microstructure when the relative location of the corona wind was controlled to a binary solution droplet on a substrate. We also demonstrate potential applications of thin functional films with controlled microstructures by corona coating to various organic electronic devices such as electroluminescent diodes, field effect transistors and non-volatile polymer memories.

  8. On weak solutions to a diffuse interface model of a binary mixture of compressible fluids

    Czech Academy of Sciences Publication Activity Database

    Feireisl, Eduard

    2016-01-01

    Roč. 9, č. 1 (2016), s. 173-183 ISSN 1937-1632 R&D Projects: GA ČR GA13-00522S Institutional support: RVO:67985840 Keywords : Euler-Cahn-Hilliard system * weak solution * diffuse interface model Subject RIV: BA - General Mathematics Impact factor: 0.781, year: 2016 http://aimsciences.org/ journals /displayArticlesnew.jsp?paperID=12093

  9. On weak solutions to a diffuse interface model of a binary mixture of compressible fluids

    Czech Academy of Sciences Publication Activity Database

    Feireisl, Eduard

    2016-01-01

    Roč. 9, č. 1 (2016), s. 173-183 ISSN 1937-1632 R&D Projects: GA ČR GA13-00522S Institutional support: RVO:67985840 Keywords : Euler-Cahn-Hilliard system * weak solution * diffuse interface model Subject RIV: BA - General Mathematics Impact factor: 0.781, year: 2016 http://aimsciences.org/journals/displayArticlesnew.jsp?paperID=12093

  10. Predicting the vapor–liquid equilibrium of hydrocarbon binary mixtures and polymer solutions using predetermined pure component parameters

    International Nuclear Information System (INIS)

    Ryu, Sang Kyu; Bae, Young Chan

    2012-01-01

    Highlights: ► We have developed a close-packed lattice model for chain-like molecules. ► The chain length dependence determined from Monte-Carlo simulation results were used. ► To consider the volume effect, hole theory and two mixing steps were used. ► A lattice fluid equation of state (LF-EoS) is presented for VLE of hydrocarbon mixtures. ► Correlation of pure polymer solutions data with use of the LF-EoS. - Abstract: In our previous work, a new close-packed lattice model was developed for multi-component system of chain fluids with taking the chain length dependence from Monte-Carlo (MC) simulation results into account. In this work, we further extend this model to describe pressure, volume and temperature (PVT) properties, such as vapor–liquid equilibrium (VLE). To consider the effect of pressure on the phase behavior, the volume change effect is taken into account by introducing holes into the incompressible lattice model with two mixing steps. The corresponding new lattice fluid equation of state (LF-EoS) is applied to predict the thermodynamic properties of pure and binary mixtures of hydrocarbons as well as pure polymer solutions. The results of the proposed model are compared to other predictive approaches based on VLE calculations using predetermined pure model parameters without further adjustment. Thermodynamic properties predicted using the method developed in this work are consistent with the experimental data.

  11. Controlling coverage of solution cast materials with unfavourable surface interactions

    KAUST Repository

    Burlakov, V. M.

    2014-03-03

    Creating uniform coatings of a solution-cast material is of central importance to a broad range of applications. Here, a robust and generic theoretical framework for calculating surface coverage by a solid film of material de-wetting a substrate is presented. Using experimental data from semiconductor thin films as an example, we calculate surface coverage for a wide range of annealing temperatures and film thicknesses. The model generally predicts that for each value of the annealing temperature there is a range of film thicknesses leading to poor surface coverage. The model accurately reproduces solution-cast thin film coverage for organometal halide perovskites, key modern photovoltaic materials, and identifies processing windows for both high and low levels of surface coverage. © 2014 AIP Publishing LLC.

  12. Simulation of self-assembled nanopatterns in binary alloys on the fcc(111) surface

    Energy Technology Data Exchange (ETDEWEB)

    Weber, Sebastian

    2008-07-01

    In this PhD thesis, we study the heteroepitaxial crystal growth by means of Monte Carlo simulations. Of particular interest in this work is the influence of the lattice mismatch of the adsorbates relative to the substrate on surface structures. In the framework of an off-lattice model, we consider one monolayer of adsorbate and investigate the emerging nanopatterns in equilibrium and their formation during growth. In chapter 1, a brief introduction is given, which describes the role of computer simulations in the field of the physics of condensed matter. Chapter 2 is devoted to some technical basics of experimental methods of molecular beam epitaxy and the theoretical description. Before a model for the simulation can be designed, it is necessary to make some considerations of the single processes which occur during epitaxial growth. For that purpose we look at an experimental setup and extract the main microscopic processes. Afterwards a brief overview of different theoretical concepts describing that physical procedures is given. In chapter 3, the model used in the simulations is presented. The aim is to investigate the growth of an fcc crystal in the [111] direction. In order to keep the simulation times within a feasible limit a simple pair potential, the Lennard-Jones potential, with continuous particle positions is used, which are necessary to describe effects resulting from the atomic mismatch in the crystal. Furthermore the detailed algorithm is introduced which is based on the idea to calculate the barrier of each diffusion event and to use the barriers in a rejection-free method. Chapter 4 is attended to the simulation of equilibrium. The influence of different parameters on the emerging structures in the first monolayer upon the surface, which is completely covered with two adsorbate materials, is studied. Especially the competition between binding energy and strain leads to very interesting pattern formations like islands or stripes. In chapter 5 the

  13. Approximate solutions of some problems of scattering of surface ...

    Indian Academy of Sciences (India)

    A class of mixed boundary value problems (bvps), occurring in the study of scattering of surface water waves by thin vertical rigid barriers placed in water of finite depth, is examined for their approximate solutions. Two different placings of vertical barriers are analyzed, namely, (i) a partially immersed barrier and(ii) a bottom ...

  14. Adsorption of methylene blue from aqueous solution on the surface ...

    African Journals Online (AJOL)

    Adsorption of dye methylene blue from aqueous solution on the surface of sheep wool and cotton fibers was accomplished under the optimize conditions of temperature, concentration, pH, stay time duration and quantity of adsorbent. Spectrometric technique was used for the measurements of concentration of dye before ...

  15. Approximate solutions of some problems of scattering of surface ...

    Indian Academy of Sciences (India)

    A Choudhary

    Abstract. A class of mixed boundary value problems (bvps), occurring in the study of scattering of surface water waves by thin vertical rigid barriers placed in water of finite depth, is examined for their approximate solutions. Two different placings of vertical barriers are analyzed, namely, (i) a partially immersed barrier and.

  16. Does Nitric Acid Dissociate at the Aqueous Solution Surface?

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, Tanza; Winter, Berndt; Stern, Abraham C.; Baer, Marcel D.; Mundy, Christopher J.; Tobias, Douglas J.; Hemminger, J. C.

    2011-11-03

    Nitric acid is a prevalent component of atmospheric aerosols, and the extent of nitric acid dissociation at aqueous interfaces is relevant to its role in heterogeneous atmospheric chemistry. Several experimental and theoretical studies have suggested that the extent of dissociation of nitric acid near aqueous interfaces is less than in bulk solution. Here, dissociation of HNO3 at the surface of aqueous nitric acid is quantified using X-ray photoelectron spectroscopy of the nitrogen local electronic structure. The relative amounts of undissociated HNO3(aq) and dissociated NO3-(aq) are identified by the distinguishable N1s core-level photoelectron spectra of the two species, and we determine the degree of dissociation, αint, in the interface (the first ~3 layers of solution) as a function of HNO3 concentration. Our measurements show that dissociation is decreased by approximately 20% near the solution interface compared with bulk, and furthermore that dissociation occurs even in the top-most solution layer. The experimental results are supported by first-principles MD simulations, which show that hydrogen-bonds between HNO3 and water molecules at the solution surface stabilize the molecular form at low concentration, in analogy to the stabilization of molecular HNO3 that occurs in bulk solution at high concentration. This work was supported by the U.S. Department of Energy's (DOE) Office of Basic Energy Sciences, Chemical Sciences program. The Pacific Northwest National Laboratory is operated by Battelle for DOE.

  17. Competitive sorption of Cd2+ and Pb2+ from a binary aqueous solution by poly (methyl methacrylate)-grafted montmorillonite clay nanocomposite

    Science.gov (United States)

    Bunhu, Tavengwa; Tichagwa, Lilian; Chaukura, Nhamo

    2017-09-01

    Poly(methyl methacrylate)-grafted montmorillonite (PMMAgMMT) clay and sodium-exchanged montmorillonite (NaMMT) clay were prepared through in situ graft polymerisation and used to remove Cd2+ and Pb2+ from synthetic wastewater. The modification of adsorbent materials was confirmed by fourier transform infra-red spectroscopy (FTIR), thermogravimetric analysis (TGA) and X-ray powder diffraction (XRD) techniques. BET surface area measurements showed NaMMT had a higher surface area than PMMAgMMT. Batch experiments were used to assess the simultaneous uptake of Cd2+ and Pb2+ from a synthetic binary solution. Pb2+ was preferentially sorbed, exhibiting greater affinity for the sorbents compared to Cd2+ as shown by its relatively higher uptake onto the sorbents than Cd2+. The maximum sorption capacities for NaMMT and PMMAgMMT were 18.73 and 19.27 mg/g for Cd2+, and 30.03 and 34.25 mg/g for Pb2+, respectively. The sorption data obeyed the Langmuir model and the pseudo-second order kinetic model with R 2 of at least 0.9800 for both models. The sorbents could also be regenerated up to three cycles without a significant loss in the sorption capacity. FTIR measurements showed the presence of metal-oxygen bonds after sorption, confirming the occurrence of adsorption as one of the heavy metal removal processes. The work demonstrated the potential of using low-cost nanoscale composite material for the removal of Cd2+ and Pb2+ from aqueous solution.

  18. Surface properties of poly(styrene- co- n-butyl acrylate) binary copolymers: Effect of chain microstructure and composition

    Science.gov (United States)

    Bogdanova, Yu. G.; Kostina, J. V.; Dolzhikova, V. D.; Chernikova, E. V.; Plutalova, A. V.

    2015-12-01

    The regularities of changing of surface energy characteristics of poly(styrene- co- n-butyl acrylate) binary copolymers films at varying of chain microstructure, composition and thermodynamic quality of solvent, from which films are formed, with respect to comonomers, were detected. The concordance between the information about characteristics of films surfaces, obtained via contact angle measurements and ATR-FTIR spectroscopy was observed. The type of polymer chain microstructure, provided the best adhesion properties of copolymers with respect to polar phases was detected.

  19. Inelasticity and precipitation of germanium from a solid solution in Al-Ge binary alloys

    Science.gov (United States)

    Kardashev, B. K.; Korchunov, B. N.; Nikanorov, S. P.; Osipov, V. N.

    2015-08-01

    The influence of precipitation of germanium atoms in a solid solution on the dependence of the inelasticity characteristics on the germanium content in aluminum-germanium alloys prepared by directional crystallization has been studied. It has been shown that the Young's modulus defect, the amplitude-dependent decrement, and the microplastic flow stress at a specified cyclic strain amplitude have extreme values at the eutectic germanium content in the alloy. The eutectic composition of the alloy undergoes a ductilebrittle transition. It has been found that there is a correlation between the dependences of the Young's modulus defect, amplitude-dependent decrement, microplastic flow stress, and specific entropy of the exothermal process of germanium precipitation on the germanium content in the hypoeutectic alloy. The concentration dependences of the inelasticity characteristics and their changes after annealing have been explained by the change in the resistance to the motion of intragrain dislocations due to different structures of the Guinier-Preston zones formed during the precipitation of germanium atoms.

  20. Surface Properties and Photocatalytic Activity of KTaO3, CdS, MoS2 Semiconductors and Their Binary and Ternary Semiconductor Composites

    Directory of Open Access Journals (Sweden)

    Beata Bajorowicz

    2014-09-01

    Full Text Available Single semiconductors such as KTaO3, CdS MoS2 or their precursor solutions were combined to form novel binary and ternary semiconductor nanocomposites by the calcination or by the hydro/solvothermal mixed solutions methods, respectively. The aim of this work was to study the influence of preparation method as well as type and amount of the composite components on the surface properties and photocatalytic activity of the new semiconducting photoactive materials. We presented different binary and ternary combinations of the above semiconductors for phenol and toluene photocatalytic degradation and characterized by X-ray powder diffraction (XRD, UV-Vis diffuse reflectance spectroscopy (DRS, scanning electron microscopy (SEM, Brunauer–Emmett–Teller (BET specific surface area and porosity. The results showed that loading MoS2 onto CdS as well as loading CdS onto KTaO3 significantly enhanced absorption properties as compared with single semiconductors. The highest photocatalytic activity in phenol degradation reaction under both UV-Vis and visible light irradiation and very good stability in toluene removal was observed for ternary hybrid obtained by calcination of KTaO3, CdS, MoS2 powders at the 10:5:1 molar ratio. Enhanced photoactivity could be related to the two-photon excitation in KTaO3-CdS-MoS2 composite under UV-Vis and/or to additional presence of CdMoO4 working as co-catalyst.

  1. Solution thermodynamics of creatine monohydrate in binary (water + ethanol) solvent systems at T = (278.15 to 328.15) K

    International Nuclear Information System (INIS)

    Song, Liangcheng; Wei, Lihua; Si, Tao; Guo, Huai; Yang, Chunhui

    2016-01-01

    Highlights: • The solubilities of creatine monohydrate in (ethanol + water) mixtures were investigated. • The solubility data were well correlated by Jouyban–Acree model. • Solution thermodynamic properties were calculated. • The dissolving process of creatine monohydrate in was endothermic and entropy-driven. - Abstract: In order to optimize the crystallization process of creatine monohydrate, the solubility of creatine monohydrate in the binary (water + ethanol) mixture was measured at temperatures ranging from 278.15 K to 328.15 K using the laser monitoring technique. The solubility increased with both the temperature and the mole fraction of water in the solvent mixture. The experimental solubility was well correlated by the Jouyban–Acree model, which generated a sensitive solubility surface for creatine monohydrate. Furthermore, the thermodynamic parameters of this dissolution process were also estimated. The results showed that the dissolution process of creatine monohydrate in each solvent mixture was endothermic and entropy-driven, and that the dissolution of creatine monohydrate became much easier when the mole fraction of water in the solvent mixture increased.

  2. Electrostatic and capillary force directed tunable 3D binary micro- and nanoparticle assemblies on surfaces

    International Nuclear Information System (INIS)

    Singh, G; Pillai, S; Arpanaei, A; Kingshott, P

    2011-01-01

    We report a simple, rapid and cost-effective method based on evaporation induced assembly to grow 3D binary colloidal assemblies on a hydrophobic/hydrophilic substrate by simple drop casting. The evaporation of a mixed colloidal drop results in ring-like or uniform area deposition depending on the concentration of particles, and thus assembly occurs at the periphery of a ring or uniformly all over the drop area. Binary colloidal assemblies of different crystal structure are successfully prepared over a wide range of size ratios (γ = small/large) from 0.06 to 0.30 by tuning the γ of the micro- and nanoparticles used during assembly. The growth mechanism of 3D binary colloidal assemblies is investigated and it is found that electrostatic forces facilitate assembly formation until the end of the evaporation process, with capillary forces also playing a role. In addition, the effects of solvent type, humidity, and salt concentration on crystal formation and ordering behaviour are also examined. Furthermore, long range, highly ordered binary colloidal assemblies can be fabricated by the choice of a low conducting solvent combined with evaporation induced assembly.

  3. Analysis of binary mixtures of aqueous aromatic hydrocarbons with low-phase-noise shear-horizontal surface acoustic wave sensors using multielectrode transducer designs.

    Science.gov (United States)

    Bender, Florian; Mohler, Rachel E; Ricco, Antonio J; Josse, Fabien

    2014-11-18

    The present work investigates a compact sensor system that provides rapid, real-time, in situ measurements of the identities and concentrations of aromatic hydrocarbons at parts-per-billion concentrations in water through the combined use of kinetic and thermodynamic response parameters. The system uses shear-horizontal surface acoustic wave (SH-SAW) sensors operating directly in the liquid phase. The 103 MHz SAW sensors are coated with thin sorbent polymer films to provide the appropriate limits of detection as well as partial selectivity for the analytes of interest, the BTEX compounds (benzene, toluene, ethylbenzene, and xylenes), which are common indicators of fuel and oil accidental releases in groundwater. Particular emphasis is placed on benzene, a known carcinogen and the most challenging BTEX analyte with regard to both regulated levels and its solubility properties. To demonstrate the identification and quantification of individual compounds in multicomponent aqueous samples, responses to binary mixtures of benzene with toluene as well as ethylbenzene were characterized at concentrations below 1 ppm (1 mg/L). The use of both thermodynamic and kinetic (i.e., steady-state and transient) responses from a single polymer-coated SH-SAW sensor enabled identification and quantification of the two BTEX compounds in binary mixtures in aqueous solution. The signal-to-noise ratio was improved, resulting in lower limits of detection and improved identification at low concentrations, by designing and implementing a type of multielectrode transducer pattern, not previously reported for chemical sensor applications. The design significantly reduces signal distortion and root-mean-square (RMS) phase noise by minimizing acoustic wave reflections from electrode edges, thus enabling limits of detection for BTEX analytes of 9-83 ppb (calculated from RMS noise); concentrations of benzene in water as low as ~100 ppb were measured directly. Reliable quantification of BTEX

  4. a Molecular Approach to Electrolyte Solutions: Predicting Phase Behavior and Thermodynamic Properties of Single and Binary-Solvent Systems

    Science.gov (United States)

    Gering, Kevin Leslie

    A molecular formulation based on modern liquid state theory is applied to the properties and phase behavior of electrolyte systems containing volatile species. An electrolyte model based on the exponential modification of the Mean Spherical Approximation (EXP-MSA) is used to describe the cation-cation, cation-anion, and anion-anion distributions of the ionic species. This theory represents an improvement over the nonmodified MSA approach, and goes beyond the usual Debye-Huckel theory and Pitzer correlation for treating concentrated solutions. Electrolyte solutions such as water-salt, ammonia-salt, mixed salts, and mixed -solvent systems are investigated over a wide range of temperatures, pressures, and compositions. The usual salt properties, such as osmotic and mean activity coefficients and other thermodynamic properties (enthalpies), are calculated. The predictions are accurate to saturation limits. In addition, an iterative method is presented that is used to predict vapor-liquid equilibria (VLE) and thermodynamic properties of single-salt multisolvent electrolytes of the form solvent-cosolvent-salt. In this method, a local composition model (LCM) and EXP-MSA theory are combined with traditional phase equilibria relations to estimate the pressures and compositions of a vapor phase in equilibrium with a binary-solvent electrolyte. Also, a pseudo-solvent model is proposed as a means of obtaining a variety of averaged liquid phase electrolyte properties. To predict preferential solvation in mixed solvents, a general framework is developed that is based on predicted solvation numbers of each solvent. Preferential solvation will be shown to influence VLE. Results show that phase equilibria is accurately predicted by the above iterative method. Three mixed-solvent electrolyte systems are investigated: water -ethylene glycol-LiBr, ammonia-water-LiBr, and methanol -water-LiCl. Finally, the above electrolyte model is utilized in predicting design criteria for a single

  5. Surface and redox properties of cobalt–ceria binary oxides: On the effect of Co content and pretreatment conditions

    Energy Technology Data Exchange (ETDEWEB)

    Konsolakis, Michalis, E-mail: mkonsol@science.tuc.gr [School of Production Engineering and Management, Technical University of Crete, GR-73100, Chania, Crete (Greece); Sgourakis, Michalis [School of Production Engineering and Management, Technical University of Crete, GR-73100, Chania, Crete (Greece); Carabineiro, Sónia A.C. [Laboratório de Catálise e Materiais (LCM), Laboratório Associado LSRE/LCM, Faculdade de Engenharia, Universidade do Porto, 4200-465 Porto (Portugal)

    2015-06-30

    Graphical abstract: - Highlights: • Impact of Co content and pretreatment conditions on Co/CeO{sub 2} surface chemistry. • The improved reducibility of Co/CeO{sub 2} compared to single oxides is disclosed. • A synergistic effect between Co and Ce toward more oxygen vacancies is revealed. • Calcination procedure leads to the impoverishment of catalyst surface on cobalt. • Reduction results in a uniform distribution of Co and Ce on the catalyst surface. - Abstract: Ceria-based transition metal catalysts have recently received considerable attention both in heterogeneous catalysis and electro-catalysis fields, due to their unique physicochemical characteristics. Their catalytic performance is greatly affected by the surface local chemistry and oxygen vacancies. The present study aims at investigating the impact of Co/Ce ratio and pretreatment conditions on the surface and redox properties of cobalt–ceria binary oxides. Co–ceria mixed oxides with different Co content (0, 20, 30, 60, 100 wt.%) were prepared by impregnation method and characterized by means of N{sub 2} adsorption at −196 °C, X-ray diffraction (XRD), H{sub 2} temperature-programmed reduction (H{sub 2}-TPR) and X-ray photoelectron spectroscopy (XPS). The results shown the improved reducibility of Co/CeO{sub 2} mixed oxides compared to single oxides, due to a synergistic interaction between cobalt and cerium. Oxidation pretreatment results in a preferential localization of cerium species on the outer surface. In contrast, a uniform distribution of cobalt and cerium species over the entire catalyst surface is obtained by the reduction process, which facilitates the formation of oxygen vacancies though Co{sup 3+}/Co{sup 2+} and Ce{sup 3+}/Ce{sup 4+} redox cycles. Fundamental insights toward tuning the surface chemistry of cobalt–ceria binary oxides are provided, paving the way for real-life industrial applications.

  6. The Surface Brightness-color Relations Based on Eclipsing Binary Stars: Toward Precision Better than 1% in Angular Diameter Predictions

    Energy Technology Data Exchange (ETDEWEB)

    Graczyk, Dariusz; Gieren, Wolfgang [Millennium Institute of Astrophysics (MAS) (Chile); Konorski, Piotr [Obserwatorium Astronomiczne, Uniwersytet Warszawski, Al. Ujazdowskie 4, 00-478, Warsaw (Poland); Pietrzyński, Grzegorz [Universidad de Concepción, Departamento de Astronomia, Casilla 160-C, Concepción (Chile); Storm, Jesper [Leibniz-Institut für Astrophysik Potsdam, An der Sternwarte 16, D-14482 Potsdam (Germany); Nardetto, Nicolas [Université Côte d’Azur, Observatoire de la Côte d’Azur, CNRS, Laboratoire Lagrange, UMR7293, Nice (France); Gallenne, Alexandre [European Southern Observatory, Alonso de Córdova 3107, Casilla 19001, Santiago 19 (Chile); Maxted, Pierre F. L. [Astrophysics Group, Keele University, Staffordshire, ST5 5BG (United Kingdom); Kervella, Pierre [Unidad Mixta Internacional Franco-Chilena de Astronomía (CNRS UMI 3386), Departamento de Astronomía, Universidad de Chile, Camino El Observatorio 1515, Las Condes, Santiago (Chile); Kołaczkowski, Zbigniew, E-mail: darek@astro-udec.cl, E-mail: darek@ncac.torun.pl [Instytut Astronomiczny, Uniwersytet Wrocławski, Kopernika 11, 51-622 Wrocław (Poland)

    2017-03-01

    In this study we investigate the calibration of surface brightness–color (SBC) relations based solely on eclipsing binary stars. We selected a sample of 35 detached eclipsing binaries with trigonometric parallaxes from Gaia DR1 or Hipparcos whose absolute dimensions are known with an accuracy better than 3% and that lie within 0.3 kpc from the Sun. For the purpose of this study, we used mostly homogeneous optical and near-infrared photometry based on the Tycho-2 and 2MASS catalogs. We derived geometric angular diameters for all stars in our sample with a precision better than 10%, and for 11 of them with a precision better than 2%. The precision of individual angular diameters of the eclipsing binary components is currently limited by the precision of the geometric distances (∼5% on average). However, by using a subsample of systems with the best agreement between their geometric and photometric distances, we derived the precise SBC relations based only on eclipsing binary stars. These relations have precisions that are comparable to the best available SBC relations based on interferometric angular diameters, and they are fully consistent with them. With very precise Gaia parallaxes becoming available in the near future, angular diameters with a precision better than 1% will be abundant. At that point, the main uncertainty in the total error budget of the SBC relations will come from transformations between different photometric systems, disentangling of component magnitudes, and for hot OB stars, the main uncertainty will come from the interstellar extinction determination. We argue that all these issues can be overcome with modern high-quality data and conclude that a precision better than 1% is entirely feasible.

  7. Photo-degradation of basic green 1 and basic red 46 dyes in their binary solution by La2O3-Al2O3nanocomposite using first-order derivative spectra and experimental design methodology.

    Science.gov (United States)

    Fahimirad, Bahareh; Asghari, Alireza; Rajabi, Maryam

    2017-05-15

    In this work, the lanthanum oxide-aluminum oxide (La 2 O 3 -Al 2 O 3 ) nanocomposite is introduced as an efficient photocatalyst for the photo-degradation of the dyes basic green 1 (BG1) and basic red 46 (BR46) in their binary aqueous solution under the UV light irradiation. The properties of this catalyst are determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer-Emmett-Teller (BET), and UV-visible spectrophotometry. The first-order derivative spectra are used for the simultaneous analysis of the dyes in their binary solution. The screening investigations indicate that five parameters including the catalyst dosage, concentration of the dyes, irradiation time, and solution pH have significant effects on the photo-degradation of the dyes. The effects of these variables together with their interactions in the photo-degradation of the dyes are studied using the Box-Behnken design (BBD). Under the optimum experimental conditions, obtained via the desirability function, the photo-catalytic activities of La 2 O 3 -Al 2 O 3 and pure Al 2 O 3 are also investigated. The results obtained show an enhancement in the photo-catalytic activity when La 2 O 3 nanoparticles are loaded on the surface of Al 2 O 3 nanoparticles. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Equilibrium Total Pressure and CO2 Solubility in Binary and Ternary Aqueous Solutions of 2-(Diethylamino)ethanol (DEEA) and 3-(Methylamino)propylamine (MAPA)

    DEFF Research Database (Denmark)

    Waseem Arshad, Muhammad; Svendsen, Hallvard Fjøsne; Fosbøl, Philip Loldrup

    2014-01-01

    available calorimeter used as an equilibrium cell. The examined systems were the binary aqueous solutions of 5 M DEEA, 2 M MAPA, and 1 M MAPA and the ternary aqueous mixtures of 5 M DEEA + 2 M MAPA (5D2M) and 5 M DEEA + 1 M MAPA (5D1M), which gave liquid–liquid phase split upon CO2 absorption. The total...

  9. PHASE-TRANSITIONS IN THE BILAYERS OF VESICLES FORMED FROM BINARY-MIXTURES OF SYMMETRICAL DI-N-ALKYLPHOSPHATES IN AQUEOUS-SOLUTIONS

    NARCIS (Netherlands)

    BLANDAMER, MJ; BRIGGS, B; CULLIS, PM; ENGBERTS, JBFN; WAGENAAR, A; SMITS, E; HOEKSTRA, D; KACPERSKA, A

    1994-01-01

    Vesicles in aqueous solutions were prepared from binary equimolar mixtures of di-n-alkyl-phosphates (sodium and potassium), (R(1)O)(2)PO(2)(-)M(+) and (R(2)O)(2)PO(2)(-)M(+). When the number of carbon atoms in R(1) and R(2) differs by two and when R(1) or R(2) = C12H25, C14H29, C16H33 and C18H37 the

  10. TWO STARS TWO WAYS: CONFIRMING A MICROLENSING BINARY LENS SOLUTION WITH A SPECTROSCOPIC MEASUREMENT OF THE ORBIT

    Energy Technology Data Exchange (ETDEWEB)

    Yee, Jennifer C.; Johnson, John Asher; Eastman, Jason; Vanderburg, Andrew [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Skowron, Jan [Warsaw University Observatory, Al. Ujazdowskie 4, 00-478 Warszawa (Poland); Gould, Andrew [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Pineda, J. Sebastian [Department of Astronomy, California Institute of Technology, 1200 East California Boulevard, MC 249-17, Pasadena, CA 91125 (United States); Howard, Andrew, E-mail: jyee@cfa.harvard.edu, E-mail: jjohnson@cfa.harvard.edu, E-mail: jason.eastman@cfa.harvard.edu, E-mail: avanderburg@cfa.harvard.edu [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822-1839 (United States)

    2016-04-20

    Light curves of microlensing events involving stellar binaries and planetary systems can provide information about the orbital elements of the system due to orbital modulations of the caustic structure. Accurately measuring the orbit in either the stellar or planetary case requires detailed modeling of subtle deviations in the light curve. At the same time, the natural, Cartesian parameterization of a microlensing binary is partially degenerate with the microlens parallax. Hence, it is desirable to perform independent tests of the predictions of microlens orbit models using radial velocity (RV) time series of the lens binary system. To this end, we present 3.5 years of RV monitoring of the binary lens system OGLE-2009-BLG-020 L, for which Skowron et al. constrained all internal parameters of the 200–700 day orbit. Our RV measurements reveal an orbit that is consistent with the predictions of the microlens light curve analysis, thereby providing the first confirmation of orbital elements inferred from microlensing events.

  11. Performance of mango seed adsorbents in the adsorption of anthraquinone and azo acid dyes in single and binary aqueous solutions.

    Science.gov (United States)

    Dávila-Jiménez, Martín M; Elizalde-González, María P; Hernández-Montoya, Virginia

    2009-12-01

    In this study the husk of mango seed and two carbonaceous adsorbents prepared from it were used to study the adsorption behavior of eight acid dyes. The adsorbed amount in mmol m(-2) decayed asymptotically as the molecular volume and area increased. The interaction between the studied dyes and the mesoporous carbon was governed by the ionic species in solution and the acidic/basic groups on the surface. Less than 50% of the external surface of the microporous carbon became covered with the dyes molecules, though monolayer formation demonstrating specific interactions only with active sites on the surface and the adsorption magnitudes correlated with the shape parameter of the molecule within a particular dye group. The adsorption behavior in mixtures was determined by the molecular volume of the constituents; the greater the molecular volume difference, the greater the effect on the adsorbed amount. We also demonstrated that the raw husk of the mango seed can be used to remove up to 50% from model 50 mg l(-1) solutions of the studied acid dyes.

  12. Surface interactions, thermodynamics and topography of binary monolayers of Insulin with dipalmitoylphosphatidylcholine and 1-palmitoyl-2-oleoylphosphatidylcholine at the air/water interface.

    Science.gov (United States)

    Grasso, E J; Oliveira, R G; Maggio, B

    2016-02-15

    The molecular packing, thermodynamics and surface topography of binary Langmuir monolayers of Insulin and DPPC (dipalmitoylphosphatidylcholine) or POCP (1-palmitoyl-2-oleoylphosphatidylcholine) at the air/water interface on Zn(2+) containing solutions were studied. Miscibility and interactions were ascertained by the variation of surface pressure-mean molecular area isotherms, surface compressional modulus and surface (dipole) potential with the film composition. Brewster Angle Microscopy was used to visualize the surface topography of the monolayers. Below 20mN/m Insulin forms stable homogenous films with DPPC and POPC at all mole fractions studied (except for films with XINS=0.05 at 10mN/m where domain coexistence was observed). Above 20mN/m, a segregation process between mixed phases occurred in all monolayers without squeezing out of individual components. Under compression the films exhibit formation of a viscoelastic or kinetically trapped organization leading to considerable composition-dependent hysteresis under expansion that occurs with entropic-enthalpic compensation. The spontaneously unfavorable interactions of Insulin with DPPC are driven by favorable enthalpy that is overcome by unfavorable entropic ordering; in films with POPC both the enthalpic and entropic effects are unfavorable. The surface topography reveals domain coexistence at relatively high pressure showing a striped appearance. The interactions of Insulin with two major membrane phospholipids induces composition-dependent and long-range changes of the surface organization that ought to be considered in the context of the information-transducing capabilities of the hormone for cell functioning. Copyright © 2015 Elsevier Inc. All rights reserved.

  13. Turbulent solutal convection and surface patterning in solid dissolution

    International Nuclear Information System (INIS)

    Sullivan, T.S.; Liu, Y.; Ecke, R.E.

    1996-01-01

    We describe experiments in which crystals of NaCl, KBr, and KCl are dissolved from below by aqueous solutions containing concentrations of the respective salts from zero concentration to near saturation. The solution near the solid-liquid interface is gravitationally unstable, producing turbulent hydrodynamic motion similar to thermal convection from a single surface cooled from above. The coupling of the fluid flow with the solid dissolution produces irregular patterns at the solid-liquid interface with a distribution of horizontal length scales. The dissolution mass flux and the pattern length scales are compared with a turbulent boundary layer model. Remarkable agreement is found, showing that the fluid motion controls both the dissolution rate and the interface patterning. copyright 1996 The American Physical Society

  14. Density, viscosity, surface tension, and spectroscopic properties for binary system of 1,2-ethanediamine + diethylene glycol

    International Nuclear Information System (INIS)

    Li, Lihua; Zhang, Jianbin; Li, Qiang; Guo, Bo; Zhao, Tianxiang; Sha, Feng

    2014-01-01

    Graphical abstract: Excess property of the binary system 1,2-ethanediamine (EDA) + diethylene glycol (DEG). - Highlights: • Densities and viscosities of EDA + DEG at 298.15–318.150 K were listed. • Thermodynamics data of EDA + DEG at 298.15–318.15 K were calculated. • Surface tension of EDA + DEG at 298.15 K was measured. • Intermolecular interaction of EDA with DEG was discussed. - Abstract: This paper reports density and viscosity data at T = 298.15, 303.15, 308.15, 313.15, and 318.15 K and surface tension data at 298.15 K for the binary system 1,2-ethanediamine (EDA) + diethylene glycol (DEG) as a function of composition under atmospheric pressure. From the experimental density and viscosity data, the excess molar volume and viscosity deviation were calculated, and the results were fitted to a Redlich–Kister equation to obtain the coefficients and to estimate the standard deviations between the experimental and calculated quantities. Based on the kinematic viscosity data, enthalpy of activation for viscous flow, entropy of activation for the viscous flow, and Gibbs energies of activation of viscous flow were calculated. In addition, based on Fourier transform infrared spectra, UV–vis spectra, and electrical conductivity for the system EDA + DEG with various concentrations, intermolecular interaction of EDA with DEG was discussed

  15. GEOSTATISTICAL SOLUTIONS FOR DOWNSCALING REMOTELY SENSED LAND SURFACE TEMPERATURE

    Directory of Open Access Journals (Sweden)

    Q. Wang

    2017-09-01

    Full Text Available Remotely sensed land surface temperature (LST downscaling is an important issue in remote sensing. Geostatistical methods have shown their applicability in downscaling multi/hyperspectral images. In this paper, four geostatistical solutions, including regression kriging (RK, downscaling cokriging (DSCK, kriging with external drift (KED and area-to-point regression kriging (ATPRK, are applied for downscaling remotely sensed LST. Their differences are analyzed theoretically and the performances are compared experimentally using a Landsat 7 ETM+ dataset. They are also compared to the classical TsHARP method.

  16. Surface treatment of zinc coatings by molybdate solutions

    International Nuclear Information System (INIS)

    Fachikov, L.; Ivanova, D.

    2012-01-01

    Highlights: ► Molybdate conversion treatments on zinc coatings. ► Zn, Mo, P, O and Ni are basic elements in the coatings. ► Better corrosion resistance of zinc coatings after molybdate surface treatment. - Abstract: The influence of different factors such as concentration, temperature, pH and cathodic polarization on formation, properties and composition of coatings obtained under treatment of zinc surfaces by molybdate solutions has been investigated by gravimetric, electrochemical and physical methods. Coatings obtained at pH 4 are distinguished for the best uniformity and density of color. The thicknesses of coatings raise by increasing the cathode current density under other equal conditions. Molybdenum, zinc and phosphorus are the basic components of the passive films.

  17. Screening hydroxyapatite for cadmium and lead immobilization in aqueous solution and contaminated soil: The role of surface area.

    Science.gov (United States)

    Li, Hongying; Guo, Xisheng; Ye, Xinxin

    2017-02-01

    Hydroxyapatite (HAP) has been widely used to immobilize many cationic metals in water and soils. The specific reason why an increase in the surface area of HAP enhances cadmium (Cd) uptake, but has no effect on lead (Pb) uptake, is not clear. The aim of this study was to determine the factors causing the differences in sorption behavior between Cd and Pb by evaluating HAPs with different surface areas. We synthesized HAPs with two different surface areas, which were characterized by X-ray diffraction, N 2 adsorption, and scanning electron microscopy, and then evaluated them as sorbents for Cd and Pb removal by testing in single and binary systems. The sorption capacity of large surface area HAP (1.85mmol/g) for Cd in the single-metal system was higher than that of small surface area HAP (0.64mmol/g), but there were no differences between single- and binary-metal solutions containing Pb. After the Cd experiments, the HAP retained a stable structure and intact morphology, which promotes the accessibility of reactive sites for Cd. However, a newly formed precipitate covered the surface and blocked the channels in the presence of Pb, which reduced the number of potential adsorption sites on HAP for Cd and Pb. Remediation experiments using Cd- and Pb-contaminated soil produced similar results to the solution tests. These results indicate that alterations of the structure and morphology during the reaction is an important factor influencing metal sorption to HAP. Copyright © 2016. Published by Elsevier B.V.

  18. Structure of aqueous electrolyte solutions near a hydrophobic surface

    Directory of Open Access Journals (Sweden)

    M.Kinoshita

    2007-09-01

    Full Text Available The structure of aqueous solutions of 1:1 salts (KCl, NaCl, KF,and CsI near a hydrophobic surface is analysed using the angle-dependent integral equation theory. Water molecules are taken to be hard spheres imbedded with multipolar moments including terms up to octupole order, and hard spherical ions are immersed in this model water. The many-body interactions associated with molecular polarizability are treated at the self-consistent mean field level. The effects of cationic and anionic sizes and salt concentration in the bulk are discussed in detail. As the salt concentration increases, the layer of water molecules next to the surface becomes denser but its orientational order remains almost unchanged. The concentration of each ion at the surface can be drastically different from that in the bulk. Asa striking example, at sufficiently low salt concentrations, the concentration of I- is about 500 times higher than that of F- at the surface.

  19. Binary pseudo-random gratings and arrays for calibration of the modulation transfer function of surface profilometers: recent developments

    Energy Technology Data Exchange (ETDEWEB)

    Barber, Samuel K.; Soldate, Paul; Anderson, Erik H.; Cambie, Rossana; Marchesini, Stefano; McKinney, Wanye R.; Takacs, Peter Z.; Voronov, Dmitry L.; Yashchuk, Valeriy V.

    2009-07-07

    The major problem of measurement of a power spectral density (PSD) distribution of the surface heights with surface profilometers arises due to the unknown Modulation Transfer Function (MTF) of the instruments. The MTF tends to distort the PSD at higher spatial frequencies. It has been suggested [Proc. SPIE 7077-7, (2007), Opt. Eng. 47 (7), 073602-1-5 (2008)] that the instrumental MTF of a surface profiler can be precisely measured using standard test surfaces based on binary pseudo-random (BPR) patterns. In the cited work, a one dimensional (1D) realization of the suggested method based on use of BPR gratings has been demonstrated. Here, we present recent achievements made in fabricating and using two-dimensional (2D) BPR arrays that allow for a direct 2D calibration of the instrumental MTF. The 2D BPRAs were used as standard test surfaces for 2D MTF calibration of the MicromapTM-570 interferometric microscope with all available objectives. The effects of fabrication imperfections on the efficiency of calibration are also discussed.

  20. Effects of decontamination solutions on the surface of titanium: investigation of surface morphology, composition, and roughness.

    Science.gov (United States)

    Wheelis, Sutton E; Gindri, Izabelle M; Valderrama, Pilar; Wilson, Thomas G; Huang, Jessica; Rodrigues, Danieli C

    2016-03-01

    To investigate the impact of treatments used to detoxify dental implants on the oxide layer morphology and to infer how changes in morphology created by these treatments may impact re-osseointegration of an implant. Pure titanium (cpTi) and the alloy Ti6Al4V were subjected to a series of chemical treatments and mechanical abrasion simulating surface decontamination of dental implants. The morphology and roughness of the surface layer before and after treatment with these solutions were investigated with optical and atomic force microscopy (OM, AFM). The solutions employed are typically used for detoxification of dental implants. These included citric acid, 15% hydrogen peroxide, chlorhexidine gluconate, tetracycline, doxycycline, sodium fluoride, peroxyacetic acid, and treatment with carbon dioxide laser. The treatments consisted of both immersions of samples in solution and rubbing with cotton swabs soaked in solution for 1, 2, and 5 min. Cotton swabs used were analyzed with energy dispersive spectroscopy (EDS). The microscopy investigation showed that corrosion and pitting of the samples were present in both metal grades with immersion and rubbing methods when employing more acidic solutions, which had pH acidic solutions caused surface discoloration when coupled with rubbing but did not cause corrosion with immersion. Neutral or basic treatments resulted in no signs of corrosion with both methods. EDS results revealed the presence of titanium particles on all rubbing samples. It was demonstrated in this study that acidic environments coupled with rubbing are able to introduce noticeable morphological changes and corrosion on the surface of both titanium grades. © 2015 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  1. Binary effectivity rules

    DEFF Research Database (Denmark)

    Keiding, Hans; Peleg, Bezalel

    2006-01-01

    effectivity rule is regular if it is the effectivity rule of some regular binary SCR. We characterize completely the family of regular binary effectivity rules. Quite surprisingly, intrinsically defined von Neumann-Morgenstern solutions play an important role in this characterization...

  2. Modeling of the branching influence on liquid–liquid equilibrium of binary and ternary polymer solutions by lattice–cluster theory

    International Nuclear Information System (INIS)

    Browarzik, Dieter; Langenbach, Kai; Enders, Sabine; Browarzik, Christina

    2013-01-01

    Highlights: ► Liquid–liquid equilibrium (LLE) is calculated with the lattice–cluster theory (LCT). ► Equations of the LCT are reduced to only three geometrical parameters. ► Branching influence on the LLE is modeled for binary and ternary polymer solutions. ► Branched and linear solvents and polymers are compared in their influence on LLE. ► Solutions of branched polymers in branched solvents show the best miscibility. -- Abstract: The liquid–liquid equilibrium (LLE) of ternary model systems of the type solvent A + polymer B + solvent C is treated in the framework of lattice–cluster theory (LCT). There are a linear and a branched type of A-molecules as well as a linear and two types of strongly branched polymer molecules. The C-molecules are assumed to occupy only one lattice site. For nine binary and six ternary polymer solutions the branching influence on LLE is discussed. Currently, the LCT is the most useful model to take the architecture of the molecules into account. However, particularly for ternary systems the model is not comfortable because of the very numerous terms of the Gibbs energy. Using some relationships between the geometrical parameters of the model a considerable simplification is possible. In this paper the new and simpler equations of the LCT are presented. For comparison with experimental data critical temperatures of solutions of linear and branched polyethylene samples in diphenyl ether are calculated

  3. A Safe Solution to Dopant Gas Desorption from Metal Surfaces

    Science.gov (United States)

    Nakanoya, Tsutomu; Egami, Maki

    2006-11-01

    TOXICAPTURE™ is used to further minimize trace toxic dopant gas inside cylinder valve outlets, which, over time, may desorb from metal surfaces. When outlet caps or connections to ion source gas cylinders are disconnected in order to perform installations or bottle changes, there always is some risk that toxic fumes resulting from desorption of the metal surface in contact with dopant gas are released in air and inhaled by the operator. TOXICAPTURE™ is a simple and easy solution to reduce this risk that may damage human health or may pollute clean room environment. TOXICAPTURE™ will react with the poison gas vapor to form nontoxic and solid material through irreversible chemical reactions. TOXICAPTURE™ prevents contamination and corrosion on gas contact surfaces of gas pipings, pressure regulators, pneumatic valves, mass flow controllers, and other parts in a gas box. TOXICAPTURE™ is highly effective in shortening the time to achieve high vacuum and in extending the lifetime of devices in the gas box. In this paper, we introduce the structure, functions, reactivity, applications, and effectivity of TOXICAPTURE™.

  4. Parameterizing the Leaching Surface by Combining Curve-Fitting for Solute Breakthrough and for Spatial Solute Distribution

    NARCIS (Netherlands)

    Bloem, E.; Gee, de M.; Rooij, de G.H.

    2012-01-01

    Multi-compartment samplers (MCSs) measure unsaturated solute transport in space and time at a given depth. Sorting the breakthrough curves (BTCs) for individual compartments in descending order of total solute amount and plotting in 3D produces the leaching surface. The leaching surface is a useful

  5. Simultaneous solution of the geoid and the surface density anomalies

    Science.gov (United States)

    Ardalan, A. A.; Safari, A.; Karimi, R.; AllahTavakoli, Y.

    2012-04-01

    The main application of the land gravity data in geodesy is "local geoid" or "local gravity field" modeling, whereas the same data could play a vital role for the anomalous mass-density modeling in geophysical explorations. In the realm of local geoid computations based on Geodetic Boundary Value Problems (GBVP), it is needed that the effect of the topographic (or residual terrain) masses be removed via application of the Newton integral in order to perform the downward continuation in a harmonic space. However, harmonization of the downward continuation domain may not be perfectly possible unless accurate information about the mass-density of the topographic masses be available. On the other hand, from the exploration point of view the unwanted topographical masses within the aforementioned procedure could be regarded as the signal. In order to overcome the effect of the remaining masses within the remove step of the GBVP, which cause uncertainties in mathematical modeling of the problem, here we are proposing a methodology for simultaneous solution of the geoid and residual surface density modeling In other words, a new mathematical model will be offered which both provides the needed harmonic space for downward continuation and at the same time accounts for the non-harmonic terms of gravitational field and makes use of it for residual mass density modeling within the topographic region. The presented new model enjoys from uniqueness of the solution, opposite to the inverse application of the Newton integral for mass density modeling which is non-unique, and only needs regularization to remove its instability problem. In this way, the solution of the model provides both the incremental harmonic gravitational potential on surface of the reference ellipsoid as the gravity field model and the lateral surface mass-density variations via the second derivatives of the non harmonic terms of gravitational field. As the case study and accuracy verification, the proposed

  6. Effect of temperature and chain length on the viscosity and surface tension of binary systems of N,N-dimethylformamide with 1-octanol, 1-nonanol and 1-decanol

    International Nuclear Information System (INIS)

    Mohammad, Abubaker A.; Alkhaldi, Khaled H.A.E.; AlTuwaim, Mohammad S.; Al-Jimaz, Adel S.

    2014-01-01

    Highlights: • Effect of temperature and chain length on η and σ of DMF + 1-alkanol binary systems. • Viscosity and surface tension were obtained. • Δη, Δσ and G ∗E were calculated using the experimental data. • H σ and S σ were determined using the surface tension data. • Semi-empirical relations were used to estimate the viscosity of liquid mixtures. - Abstract: Viscosity and surface tension of binary systems of N,N-dimethylformamide DMF with higher 1-alkanols (C 8 –C 10 ) were measured at atmospheric pressure and four different temperatures over the entire range of mole fraction. The experimental measurements were used to calculate the deviations in viscosity and surface tension. Furthermore, the excess Gibbs free energy of activation, surface enthalpy and surface entropy of the (DMF + 1-alkanols) binary mixtures were determined. In addition, the deviation and excess properties were fitted to the method of Redlich–Kister (R–K) polynomial. Viscosity data of the binary systems were correlated with three different expressions (Grunberg and Nissan, the three-body, and four-body McAllister). The effects of the chain length of the higher 1-alkanols and temperature were investigated

  7. Phase equilibrium properties of binary aqueous solutions containing ethanediamine, 1,2-diaminopropane, 1,3-diaminopropane, or 1,4-diaminobutane at several temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Nouria Chiali-Baba [LATA2M, Laboratoire de Thermodynamique Appliquee et Modelisation Moleculaire, University AbouBekr Belkaid of Tlemcen, P.O. Box 119, Tlemcen 13000 (Algeria); Negadi, Latifa, E-mail: l_negadi@mail.univ-tlemcen.d [LATA2M, Laboratoire de Thermodynamique Appliquee et Modelisation Moleculaire, University AbouBekr Belkaid of Tlemcen, P.O. Box 119, Tlemcen 13000 (Algeria); Mokbel, Ilham; Jose, Jacques [LSA, Laboratoire des Sciences Analytiques, CNRS-UMR 5180, Universite Claude Bernard - Lyon I. 43, Bd du 11 Novembre 1918, Villeurbanne Cedex 69622 (France)

    2011-05-15

    Research highlights: Vapour pressures of ethanediamine (EDA), 1,2-diaminopropane, 1,3-diaminopropane (1,3-DAP), or 1,4-diaminobutane (1,4-DAB) aqueous solutions are reported between (293 and 363) K. The two first mixtures show negative azeotropic behaviour. The aqueous solutions of EDA, 1,2-DAP, or 1,3-DAP exhibit negative G{sup E} whereas the one containing 1,4-DAB shows either negative G{sup E} or sinusoidal shape for G{sup E}. - Abstract: The vapour pressures of {l_brace}ethanediamine (EDA) + water{r_brace}, {l_brace}1,2-diaminopropane (1,2-DAP) + water{r_brace}, {l_brace}1,3-diaminopropane (1,3-DAP) + water{r_brace} or {l_brace}1,4-diaminobutane (1,4-DAB) + water{r_brace} binary mixtures, and of pure EDA, 1,2-DAP, 1,3-DAP, 1,4-DAB, and water components were measured by means of two static devices at temperatures between (293 and 363) K. The data were correlated with the Antoine equation. From these data, the excess Gibbs function (G{sup E}) was calculated for several constant temperatures and fitted to a fourth-order Redlich-Kister equation using the Barker's method. The {l_brace}ethanediamine (EDA) + water{r_brace}, and {l_brace}1,2-diaminopropane (1,2-DAP) + water{r_brace} binary systems show negative azeotropic behaviour. The aqueous solutions of EDA, 1,2-DAP, or 1,3-DAP exhibit negative deviations in G{sup E} for all investigated temperatures over the whole composition range whereas the (1,4-DAB + water) binary mixture shows negative G{sup E} for temperatures (293.15 < T/K < 353.15) and a sinusoidal shape for G{sup E} at T = 363.15 K.

  8. Conductance Studies on Complex Formation between c-Methylcalix[4]resorcinarene and Titanium (III in Acetonitrile-H2O Binary Solutions

    Directory of Open Access Journals (Sweden)

    Naghmeh Saadati

    2013-09-01

    Full Text Available Calixresorcinarenes have proved to be unique molecules for molecular recognition via hydrogen bonding, hydrophobic and ionic interactions with suitable substrates such as cations. The study of the interactions involved in the complexation of different cations with calixresorcinarenes in solvent mixtures is important for a better understanding of the mechanism of biological transport, molecular recognition, and other analytical applications. This article summarizes different aspects of the complexes of the Ti3+ metal cation with c-methylcalix[4]resorcinarene (CMCR as studied by conductometry in acetonitrile (AN–water (H2O binary mixtures at different temperatures. Conductance data show that the metal cation/ligand (ML stoichiometry of the complexes in solution is 1:1 in all cases. Non-linear behaviour was observed for the variation of logKf of the complexes vs. the composition of the binary solvent mixtures. Selectivity of CMCR for the Ti3+ cation is sensitive to solvent composition; in some cases and at certain compositions of the mixed solvent systems, the selectivity order is changed. Values of thermodynamic parameters (, for formation of the CMCR–Ti3+ complexes in AN–H2O binary systems were obtained from the temperature dependence of stability constants, and the results show that the thermodynamics of complexation reactions are affected by the nature and composition of the mixed solvents.

  9. Fouling of Structured Surfaces during Pool Boiling of Aqueous Solutions

    International Nuclear Information System (INIS)

    Esawy, M.

    2011-01-01

    Bubble characteristics in terms of density, size, frequency and motion are key factors that contribute to the superiority of nucleate pool boiling over the other modes of heat transfer. Nevertheless, if heat transfer occurs in an environment which is prone to fouling, the very same parameters may lead to accelerated deposit formation due to concentration effects beneath the growing bubbles. This has led heat exchanger designers frequently to maintain the surface temperature below the boiling point if fouling occurs, e.g. in thermal seawater desalination plants. The present study investigates the crystallization fouling of various structured surfaces during nucleate pool boiling of CaSO 4 solutions to shed light into their fouling behaviour compared with that of plain surfaces for the same operating conditions. As for the experimental part, a comprehensive set of clean and fouling experiments was performed rigorously. The structured tubes included low finned tubes of different fin densities, heights and materials and re-entrant cavity Turbo-B tube types.The fouling experiments were carried out at atmospheric pressure for different heat fluxes ranging from 100 to 300 k W/m 2 and CaSO 4 concentrations of 1.2 and 1.6 g/L. For the sake of comparison, similar runs were performed on plain stainless steel and copper tubes.Overall for the finned tubes, the experimental results showed a significant reduction of fouling resistances of up to 95% compared to those of the stainless steel and copper plain tubes. In addition, the scale formation that occurred on finned tubes was primarily a scattered and thin crystalline layer which differs significantly from those of plain tubes which suffered from a thick and homogenous layer of deposit with strong adhesion. Higher fin densities and lower fin heights always led to better antifouling performance for all investigated finned tubes. It was also shown that the surface material strongly affects the scale formation of finned tubes i

  10. Online Surface Defect Identification of Cold Rolled Strips Based on Local Binary Pattern and Extreme Learning Machine

    Directory of Open Access Journals (Sweden)

    Yang Liu

    2018-03-01

    Full Text Available In the production of cold-rolled strip, the strip surface may suffer from various defects which need to be detected and identified using an online inspection system. The system is equipped with high-speed and high-resolution cameras to acquire images from the moving strip surface. Features are then extracted from the images and are used as inputs of a pre-trained classifier to identify the type of defect. New types of defect often appear in production. At this point the pre-trained classifier needs to be quickly retrained and deployed in seconds to meet the requirement of the online identification of all defects in the environment of a continuous production line. Therefore, the method for extracting the image features and the training for the classification model should be automated and fast enough, normally within seconds. This paper presents our findings in investigating the computational and classification performance of various feature extraction methods and classification models for the strip surface defect identification. The methods include Scale Invariant Feature Transform (SIFT, Speeded Up Robust Features (SURF and Local Binary Patterns (LBP. The classifiers we have assessed include Back Propagation (BP neural network, Support Vector Machine (SVM and Extreme Learning Machine (ELM. By comparing various combinations of different feature extraction and classification methods, our experiments show that the hybrid method of LBP for feature extraction and ELM for defect classification results in less training and identification time with higher classification accuracy, which satisfied online real-time identification.

  11. Surface tension and density of binary lead and lead-free Sn-based solders

    Science.gov (United States)

    Kaban, I.; Mhiaoui, S.; Hoyer, W.; Gasser, J.-G.

    2005-12-01

    The surface tension and density of the liquid Sn60Pb40, Sn90Pb10, Sn96.5Ag3.5 and Sn97Cu3 solder alloys (wt%) have been determined experimentally over a wide temperature interval. It is established that the surface tension of liquid Sn90Pb10 is about 7% higher than that of a traditional Sn60Pb40 solder and that the surface tension of Sn96.5Ag3.5 and Sn97Cu3 alloys is about 12% higher than that of Sn60Pb40. The analytical expressions for the temperature dependences of the surface tension and density are given.

  12. A nonlinear model for surface segregation and solute trapping during planar film growth

    International Nuclear Information System (INIS)

    Han, Xiaoying; Spencer, Brian J.

    2007-01-01

    Surface segregation and solute trapping during planar film growth is one of the important issues in molecular beam epitaxy, yet the study on surface composition has been largely restricted to experimental work. This paper introduces some mathematical models of surface composition during planar film growth. Analytical solutions are obtained for the surface composition during growth

  13. Interacting binary stars

    CERN Document Server

    Sahade, Jorge; Ter Haar, D

    1978-01-01

    Interacting Binary Stars deals with the development, ideas, and problems in the study of interacting binary stars. The book consolidates the information that is scattered over many publications and papers and gives an account of important discoveries with relevant historical background. Chapters are devoted to the presentation and discussion of the different facets of the field, such as historical account of the development in the field of study of binary stars; the Roche equipotential surfaces; methods and techniques in space astronomy; and enumeration of binary star systems that are studied

  14. (Vapour + liquid) equilibria, volumetric and compressibility behaviour of binary and ternary aqueous solutions of 1-hexyl-3-methylimidazolium chloride, methyl potassium malonate, and ethyl potassium malonate

    International Nuclear Information System (INIS)

    Sadeghi, Rahmat; Mahdavi, Adibeh

    2012-01-01

    Highlights: ► VLE and volumetry of binary and ternary [C 6 mim][Cl], MPM and EPM aqueous solutions. ► Constant a w lines show small negative deviation from the linear isopiestic relation. ► Solute–water interactions follow the order: EPM > MPM > [C 6 mim][Cl]. ► MPM and EPM have a very weak salting-out effect on [C 6 mim][Cl] aqueous solutions. - Abstract: (Vapour + liquid) equilibrium data (water activity, vapour pressure, osmotic coefficient, and activity coefficient) of binary aqueous solutions of 1-hexyl-3-methylimidazolium chloride ([C 6 mim][Cl]), methyl potassium malonate, and ethyl potassium malonate and ternary {[C 6 mim][Cl] + methyl potassium malonate} and {[C 6 mim][Cl] + ethyl potassium malonate} aqueous solutions were obtained through the isopiestic method at T = 298.15 K. These results reveal that the ionic liquid behaves as surfactant-like and aggregates in aqueous solutions at molality about 0.4 mol · kg −1 . The constant water activity lines of all the ternary systems investigated show small negative deviations from the linear isopiestic relation (Zdanovskii–Stokes–Robinson rule) derived using the semi-ideal hydration model. The density and speed of sound measurements were carried out on solutions of methyl potassium malonate and ethyl potassium malonate in water and of [C 6 mim][Cl] in aqueous solutions of 0.25 mol · kg −1 methyl potassium malonate and ethyl potassium malonate at T = (288.15 to 308.15) K at atmospheric pressure. From the experimental density and speed of sound data, the values of the apparent molar volume, apparent molar isentropic compressibility and excess molar volume were evaluated and from which the infinite dilution apparent molar volume and infinite dilution apparent molar isentropic compressibility were calculated at each temperature. Although, there are no clear differences between the values of the apparent molar volume of [C 6 mim][Cl] in pure water and in methyl potassium malonate or ethyl

  15. A Precise Distance to the Host Galaxy of the Binary Neutron Star Merger GW170817 Using Surface Brightness Fluctuations

    Science.gov (United States)

    Cantiello, Michele; Jensen, J. B.; Blakeslee, J. P.; Berger, E.; Levan, A. J.; Tanvir, N. R.; Raimondo, G.; Brocato, E.; Alexander, K. D.; Blanchard, P. K.; Branchesi, M.; Cano, Z.; Chornock, R.; Covino, S.; Cowperthwaite, P. S.; D’Avanzo, P.; Eftekhari, T.; Fong, W.; Fruchter, A. S.; Grado, A.; Hjorth, J.; Holz, D. E.; Lyman, J. D.; Mandel, I.; Margutti, R.; Nicholl, M.; Villar, V. A.; Williams, P. K. G.

    2018-02-01

    The joint detection of gravitational waves (GWs) and electromagnetic radiation from the binary neutron star (BNS) merger GW170817 has provided unprecedented insight into a wide range of physical processes: heavy element synthesis via the r-process; the production of relativistic ejecta; the equation of state of neutron stars and the nature of the merger remnant; the binary coalescence timescale; and a measurement of the Hubble constant via the “standard siren” technique. In detail, all of these results depend on the distance to the host galaxy of the merger event, NGC 4993. In this Letter we measure the surface brightness fluctuation (SBF) distance to NGC 4993 in the F110W and F160W passbands of the Wide Field Camera 3 Infrared Channel (WFC3/IR) on the Hubble Space Telescope (HST). For the preferred F110W passband we derive a distance modulus of (m-M) =33.05+/- 0.08+/- 0.10 mag, or a linear distance d = 40.7 ± 1.4 ± 1.9 Mpc (random and systematic errors, respectively); a virtually identical result is obtained from the F160W data. This is the most precise distance to NGC 4993 available to date. Combining our distance measurement with the corrected recession velocity of NGC 4993 implies a Hubble constant H 0 = 71.9 ± 7.1 km s‑1 Mpc‑1. A comparison of our result to the GW-inferred value of H 0 indicates a binary orbital inclination of i ≳ 137°. The SBF technique can be applied to early-type host galaxies of BNS mergers to ∼100 Mpc with HST and possibly as far as ∼300 Mpc with the James Webb Space Telescope, thereby helping to break the inherent distance-inclination degeneracy of the GW data at distances where many future BNS mergers are likely to be detected. Based on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with Program #15329 (PI: E

  16. Parsimonious classification of binary lacunarity data computed from food surface images using kernel principal component analysis and artificial neural networks.

    Science.gov (United States)

    Iqbal, Abdullah; Valous, Nektarios A; Sun, Da-Wen; Allen, Paul

    2011-02-01

    Lacunarity is about quantifying the degree of spatial heterogeneity in the visual texture of imagery through the identification of the relationships between patterns and their spatial configurations in a two-dimensional setting. The computed lacunarity data can designate a mathematical index of spatial heterogeneity, therefore the corresponding feature vectors should possess the necessary inter-class statistical properties that would enable them to be used for pattern recognition purposes. The objectives of this study is to construct a supervised parsimonious classification model of binary lacunarity data-computed by Valous et al. (2009)-from pork ham slice surface images, with the aid of kernel principal component analysis (KPCA) and artificial neural networks (ANNs), using a portion of informative salient features. At first, the dimension of the initial space (510 features) was reduced by 90% in order to avoid any noise effects in the subsequent classification. Then, using KPCA, the first nineteen kernel principal components (99.04% of total variance) were extracted from the reduced feature space, and were used as input in the ANN. An adaptive feedforward multilayer perceptron (MLP) classifier was employed to obtain a suitable mapping from the input dataset. The correct classification percentages for the training, test and validation sets were 86.7%, 86.7%, and 85.0%, respectively. The results confirm that the classification performance was satisfactory. The binary lacunarity spatial metric captured relevant information that provided a good level of differentiation among pork ham slice images. Copyright © 2010 The American Meat Science Association. Published by Elsevier Ltd. All rights reserved.

  17. Comparative acid-base properties of the surface of components of the CdTe-ZnS system in series of substitutional solid solutions and their analogs

    Science.gov (United States)

    Kirovskaya, I. A.; Kasatova, I. Yu.

    2011-07-01

    The acid-base properties of the surface of solid solutions and binary components of the CdTe-ZnS system are studied by hydrolytic adsorption, nonaqueous conductometric titration, mechanochemistry, IR spectroscopy, and Raman scattering spectroscopy. The strength, nature, and concentration of acid centers on the original surface and that exposed to CO are determined. The changes in acid-base properties in dependence on the composition of the system under investigation in the series of CdB6, ZnB6 analogs are studied.

  18. Fast and accurate solution for the SCUC problem in large-scale power systems using adapted binary programming and enhanced dual neural network

    International Nuclear Information System (INIS)

    Shafie-khah, M.; Moghaddam, M.P.; Sheikh-El-Eslami, M.K.; Catalão, J.P.S.

    2014-01-01

    Highlights: • A novel hybrid method based on decomposition of SCUC into QP and BP problems is proposed. • An adapted binary programming and an enhanced dual neural network model are applied. • The proposed EDNN is exactly convergent to the global optimal solution of QP. • An AC power flow procedure is developed for including contingency/security issues. • It is suited for large-scale systems, providing both accurate and fast solutions. - Abstract: This paper presents a novel hybrid method for solving the security constrained unit commitment (SCUC) problem. The proposed formulation requires much less computation time in comparison with other methods while assuring the accuracy of the results. Furthermore, the framework provided here allows including an accurate description of warmth-dependent startup costs, valve point effects, multiple fuel costs, forbidden zones of operation, and AC load flow bounds. To solve the nonconvex problem, an adapted binary programming method and enhanced dual neural network model are utilized as optimization tools, and a procedure for AC power flow modeling is developed for including contingency/security issues, as new contributions to earlier studies. Unlike classical SCUC methods, the proposed method allows to simultaneously solve the unit commitment problem and comply with the network limits. In addition to conventional test systems, a real-world large-scale power system with 493 units has been used to fully validate the effectiveness of the novel hybrid method proposed

  19. Application of a radioactive sourced semi portable X-ray spectrometer to the solution of binary mix compositions

    International Nuclear Information System (INIS)

    Butcher, B.M.

    1988-01-01

    In many cases it is far more economically viable to transport individual constituents to a blending plant and produce a series of custom made products than to manufacture at site. This situation exists in many heavy chemical industries or on large building sites. In the cement industry inter-mixed or interground blends containing slag, fly ash, or limestone are produced. These mixes are designed to enhance certain physical properties and to reduce costs. This paper summarises experience of the application of portable isotope source X-ray analysers in achieving quality control of binary mixes

  20. Metal thin film growth on multimetallic surfaces: From quaternary metallic glass to binary crystal

    Energy Technology Data Exchange (ETDEWEB)

    Jing, Dapeng [Iowa State Univ., Ames, IA (United States)

    2010-01-01

    The work presented in this thesis mainly focuses on the nucleation and growth of metal thin films on multimetallic surfaces. First, we have investigated the Ag film growth on a bulk metallic glass surface. Next, we have examined the coarsening and decay of bilayer Ag islands on NiAl(110) surface. Third, we have investigated the Ag film growth on NiAl(110) surface using low-energy electron diffraction (LEED). At last, we have reported our investigation on the epitaxial growth of Ni on NiAl(110) surface. Some general conclusions can be drawn as follows. First, Ag, a bulk-crystalline material, initially forms a disordered wetting layer up to 4-5 monolayers on Zr-Ni-Cu-Al metallic glass. Above this coverage, crystalline 3D clusters grow, in parallel with the flatter regions. The cluster density increases with decreasing temperature, indicating that the conditions of island nucleation are far-from-equilibrium. Within a simple model where clusters nucleate whenever two mobile Ag adatoms meet, the temperature-dependence of cluster density yields a (reasonable) upper limit for the value of the Ag diffusion barrier on top of the Ag wetting layer of 0.32 eV. Overall, this prototypical study suggests that it is possible to grow films of a bulk-crystalline metal that adopt the amorphous character of a glassy metal substrate, if film thickness is sufficiently low. Next, the first study of coarsening and decay of bilayer islands has been presented. The system was Ag on NiAl(110) in the temperature range from 185 K to 250 K. The coarsening behavior, has some similarities to that seen in the Ag(110) homoepitaxial system studied by Morgenstern and co-workers. At 185 K and 205 K, coarsening of Ag islands follows a Smoluchowski ripening pathway. At 205 K and 250 K, the terrace diffusion limited Ostwald ripening dominants. The experimental observed temperature for the transition from SR to OR is 205 K. The SR exhibits anisotropic island diffusion and the OR exhibits 1D decay of island

  1. Investigating the surface and subsurface properties of the Didymos binary asteroid with a landed CubeSat

    Science.gov (United States)

    Murdoch, Naomi; Cadu, Alexandre; Mimoun, David; Karatekin, Ozgur; Garcia, Raphael; Carrasco, José; Garcia de Quiros, Javier; Vasseur, Hugues; Ritter, Birgit; Eubanks, Marshall; Radley, Charles; Dehant, Veronique

    2016-04-01

    Despite the successes of recent space missions (e.g., Cheng et al., 1997; Fujiwara et al., 2006), there is still no clear understanding of the asteroid internal structure(s). Depending on their size, evolution and physical properties, many different asteroid internal structure models have been suggested from completely cohesive bodies, through to rubble pile objects. The Asteroid Geophysical Explorer (AGEX), a COPINS payload selected by ESA*, will land geophysical instrument packages on the surface of Didymoon; the secondary object in the (65803) Didymos (1996 GT) binary system (Karatekin et al 2016). The instruments will characterize the asteroid surface mechanical properties and probe, for the first time, the sub-surface structure of an asteroid. AGEX will be deployed from AIM on a ballistic transfer to the asteroid surface, several days before the MASCOT-2 package. We expect that AGEX will bounce multiple times before coming to rest on the surface of the asteroid thus providing a unique opportunity to study the asteroid surface properties, perhaps at several locations, using accelerometers. Once stationary, the seismological surface-monitoring phase, using a three-axis set of geophones, can begin. The high speed DART impact will be a major seismic source on Didymoon. However, the seismic payload may also be able to perform seismological investigations using natural seismic sources such as micrometeoroid impacts (e.g., Garcia et al., 2015), thermal cracks (e.g., Delbo et al., 2014), internal quakes due to tidal forces (e.g., Richardson et al. 1998) and other geophysical processes (see Murdoch et al., 2015). We will present the expected signal characteristics of the landing and also of the natural seismic sources that may occur on Didymoon. An understanding of the amplitude and frequency content of such signals is necessary in order to design the optimal geophysical payload for small body exploration using a CubeSat platform. [1.] Cheng, A. et al., Journal of

  2. Surface tension of ionic liquids and ionic liquid solutions.

    Science.gov (United States)

    Tariq, Mohammad; Freire, Mara G; Saramago, Benilde; Coutinho, João A P; Lopes, José N Canongia; Rebelo, Luís Paulo N

    2012-01-21

    Some of the most active scientific research fronts of the past decade are centered on ionic liquids. These fluids present characteristic surface behavior and distinctive trends of their surface tension versus temperature. One way to explore and understand their unique nature is to study their surface properties. This critical review analyses most of the surface tension data reported between 2001 and 2010 (187 references).

  3. Competitive removal of hazardous dyes from aqueous solution by MIL-68(Al): Derivative spectrophotometric method and response surface methodology approach

    Science.gov (United States)

    Tehrani, Mahnaz Saghanejhad; Zare-Dorabei, Rouholah

    2016-05-01

    MIL-68(Al) as a metal-organic framework (MOF) was synthesized and characterized by different techniques such as SEM, BET, FTIR, and XRD analysis. This material was then applied for simulations removal of malachite green (MG) and methylene blue (MB) dyes from aqueous solutions using second order derivative spectrophotometric method (SODS) which was applied to resolve the overlap between the spectra of these dyes. The dependency of dyes removal efficiency in binary solutions was examined and optimized toward various parameters including initial dye concentration, pH of the solution, adsorbent dosage and ultrasonic contact time using central composite design (CCD) under response surface methodology (RSM) approach. The optimized experimental conditions were set as pH 7.78, contact time 5 min, initial MB concentration 22 mg L- 1, initial MG concentration 12 mg L- 1 and adsorbent dosage 0.0055 g. The equilibrium data was fitted to isotherm models such as Langmuir, Freundlich and Tempkin and the results revealed the suitability of the Langmuir model. The maximum adsorption capacity of 666.67 and 153.85 mg g- 1 was obtained for MB and MG removal respectively. Kinetics data fitting to pseudo-first order, pseudo-second order and Elovich models confirmed the applicability of pseudo-second order kinetic model for description of the mechanism and adsorption rate. Dye-loaded MIL-68(Al) can be easily regenerated using methanol and applied for three frequent sorption/desorption cycles with high performance. The impact of ionic strength on removal percentage of both dyes in binary mixture was studied by using NaCl and KCl soluble salts at different concentrations. According to our findings, only small dosage of the proposed MOF is considerably capable to remove large amounts of dyes at room temperature and in very short time that is a big advantage of MIL-68(Al) as a promising adsorbent for adsorptive removal processes.

  4. Calibration of the modulation transfer function of surface profilometers with binary pseudo-random test standards: expanding the application range

    Energy Technology Data Exchange (ETDEWEB)

    Yashchuk, Valeriy V.; Anderson, Erik H.; Barber, Samuel K.; Bouet, Nathalie; Cambie, Rossana; Conley, Raymond; McKinney, Wayne R.; Takacs, Peter Z.; Voronov, Dmitriy L.

    2011-03-14

    A modulation transfer function (MTF) calibration method based on binary pseudo-random (BPR) gratings and arrays [Proc. SPIE 7077-7 (2007), Opt. Eng. 47, 073602 (2008)] has been proven to be an effective MTF calibration method for a number of interferometric microscopes and a scatterometer [Nucl. Instr. and Meth. A616, 172 (2010)]. Here we report on a further expansion of the application range of the method. We describe the MTF calibration of a 6 inch phase shifting Fizeau interferometer. Beyond providing a direct measurement of the interferometer's MTF, tests with a BPR array surface have revealed an asymmetry in the instrument's data processing algorithm that fundamentally limits its bandwidth. Moreover, the tests have illustrated the effects of the instrument's detrending and filtering procedures on power spectral density measurements. The details of the development of a BPR test sample suitable for calibration of scanning and transmission electron microscopes are also presented. Such a test sample is realized as a multilayer structure with the layer thicknesses of two materials corresponding to BPR sequence. The investigations confirm the universal character of the method that makes it applicable to a large variety of metrology instrumentation with spatial wavelength bandwidths from a few nanometers to hundreds of millimeters.

  5. Calibration of the modulation transfer function of surface profilometers with binary pseudo-random test standards: Expanding the application range

    Energy Technology Data Exchange (ETDEWEB)

    Yashchuk, Valeriy V; Anderson, Erik H.; Barber, Samuel K.; Bouet, Nathalie; Cambie, Rossana; Conley, Raymond; McKinney, Wayne R.; Takacs, Peter Z.; Voronov, Dmitriy L.

    2010-07-26

    A modulation transfer function (MTF) calibration method based on binary pseudo-random (BPR) gratings and arrays [Proc. SPIE 7077-7 (2007), Opt. Eng. 47(7), 073602-1-5 (2008)] has been proven to be an effective MTF calibration method for a number of interferometric microscopes and a scatterometer [Nucl. Instr. and Meth. A 616, 172-82 (2010]. Here we report on a significant expansion of the application range of the method. We describe the MTF calibration of a 6 inch phase shifting Fizeau interferometer. Beyond providing a direct measurement of the interferometer's MTF, tests with a BPR array surface have revealed an asymmetry in the instrument's data processing algorithm that fundamentally limits its bandwidth. Moreover, the tests have illustrated the effects of the instrument's detrending and filtering procedures on power spectral density measurements. The details of the development of a BPR test sample suitable for calibration of scanning and transmission electron microscopes are also presented. Such a test sample is realized as a multilayer structure with the layer thicknesses of two materials corresponding to BPR sequence. The investigations confirm the universal character of the method that makes it applicable to a large variety of metrology instrumentation with spatial wavelength bandwidths from a few nanometers to hundreds of millimeters.

  6. A binary genetic programing model for teleconnection identification between global sea surface temperature and local maximum monthly rainfall events

    Science.gov (United States)

    Danandeh Mehr, Ali; Nourani, Vahid; Hrnjica, Bahrudin; Molajou, Amir

    2017-12-01

    The effectiveness of genetic programming (GP) for solving regression problems in hydrology has been recognized in recent studies. However, its capability to solve classification problems has not been sufficiently explored so far. This study develops and applies a novel classification-forecasting model, namely Binary GP (BGP), for teleconnection studies between sea surface temperature (SST) variations and maximum monthly rainfall (MMR) events. The BGP integrates certain types of data pre-processing and post-processing methods with conventional GP engine to enhance its ability to solve both regression and classification problems simultaneously. The model was trained and tested using SST series of Black Sea, Mediterranean Sea, and Red Sea as potential predictors as well as classified MMR events at two locations in Iran as predictand. Skill of the model was measured in regard to different rainfall thresholds and SST lags and compared to that of the hybrid decision tree-association rule (DTAR) model available in the literature. The results indicated that the proposed model can identify potential teleconnection signals of surrounding seas beneficial to long-term forecasting of the occurrence of the classified MMR events.

  7. Calibration of the modulation transfer function of surface profilometers with binary pseudo-random test standards: expanding the application range

    International Nuclear Information System (INIS)

    Yashchuk, Valeriy V.; Anderson, Erik H.; Barber, Samuel K.; Bouet, Nathalie; Cambie, Rossana; Conley, Raymond; McKinney, Wayne R.; Takacs, Peter Z.; Voronov, Dmitriy L.

    2011-01-01

    A modulation transfer function (MTF) calibration method based on binary pseudo-random (BPR) gratings and arrays (Proc. SPIE 7077-7 (2007), Opt. Eng. 47, 073602 (2008)) has been proven to be an effective MTF calibration method for a number of interferometric microscopes and a scatterometer (Nucl. Instr. and Meth. A616, 172 (2010)). Here we report on a further expansion of the application range of the method. We describe the MTF calibration of a 6 inch phase shifting Fizeau interferometer. Beyond providing a direct measurement of the interferometer's MTF, tests with a BPR array surface have revealed an asymmetry in the instrument's data processing algorithm that fundamentally limits its bandwidth. Moreover, the tests have illustrated the effects of the instrument's detrending and filtering procedures on power spectral density measurements. The details of the development of a BPR test sample suitable for calibration of scanning and transmission electron microscopes are also presented. Such a test sample is realized as a multilayer structure with the layer thicknesses of two materials corresponding to BPR sequence. The investigations confirm the universal character of the method that makes it applicable to a large variety of metrology instrumentation with spatial wavelength bandwidths from a few nanometers to hundreds of millimeters.

  8. Synthesis of novel binary and ternary Zn2+ complexes with putrescine and phosphocreatine and the metal complexes study in aqueous solution

    Science.gov (United States)

    Szyfman, Natalie Waissmann; Tenório, Thaís; Ribeiro, Tatiana S.; Felcman, Judith; Mercê, Ana Lucia Ramalho

    2014-09-01

    Binary and ternary systems of Zn2+ complexes with phosphocreatine (PCr) and putrescine (Put) were investigated in aqueous solution using potentiometric titrations, Raman spectroscopy, Nuclear Magnetic Resonance (1H NMR) and molecular modeling. The stability constants of the complexes and molecular adducts, determined by potentiometry (T = 25.0 °C, I = 0.100 mol L-1, KNO3), are for some of the calculated complexes log KZnPCr = 10.63 ± 0.03, log KZnPut = 5.22 ± 0.08 and for log KZnPCrPut = 16.56 ± 0.02. PCr acts as a bidentate ligand and Put as a monodentate ligand until around pH 11. The Raman and 1H NMR spectra and minimum total molecular energies calculations confirm the coordination modes of all systems. The ternary species are suggested by the values of the stability constants found as, when compared to those of the binary complexes with each ligand, they are neither the sum of the two or a value less than each one separately complexed with Zn2+. An intermolecular interaction was suggested for the ZnPCrPut species. However, for ZnPCrPutH species it was not possible to establish the same kind of interaction due to the long distance between the carboxylate group of phosphocreatine and the NH3+ group of Put.

  9. Different photolysis kinetics at the surface of frozen freshwater vs. frozen salt solutions

    Directory of Open Access Journals (Sweden)

    T. F. Kahan

    2010-11-01

    Full Text Available Reactions at air-ice interfaces can proceed at very different rates than those in aqueous solution, due to the unique disordered region at the ice surface known as the quasi-liquid layer (QLL . The physical and chemical nature of the surfacial region of ice is greatly affected by solutes such as sodium halide salts. In this work, we studied the effects of sodium chloride and sodium bromide on the photolysis kinetics of harmine, an aromatic organic compound, in aqueous solution and at the surface of frozen salt solutions above the eutectic temperature. In common with other aromatic organic compounds we have studied, harmine photolysis is much faster on ice surfaces than in aqueous solution, but the presence of NaCl or NaBr – which does not affect photolysis kinetics in solution – reduces the photolysis rate on ice. The rate decreases monotonically with increasing salt concentration; at the concentrations found in seawater, harmine photolysis at the surface of frozen salt solutions proceeds at the same rate as in aqueous solution. These results suggest that the brine excluded to the surfaces of frozen salt solutions is a true aqueous solution, and so it may be possible to use aqueous-phase kinetics to predict photolysis rates at sea ice surfaces. This is in marked contrast to the result at the surface of frozen freshwater samples, where reaction kinetics are often not well-described by aqueous-phase processes.

  10. Auger electron spectroscopy study of surface segregation in the binary alloys copper-1 atomic percent indium, copper-2 atomic percent tin, and iron-6.55 atomic percent silicon

    Science.gov (United States)

    Ferrante, J.

    1973-01-01

    Auger electron spectroscopy was used to examine surface segregation in the binary alloys copper-1 at. % indium, copper-2 at. % tin and iron-6.55 at. % silicon. The copper-tin and copper-indium alloys were single crystals oriented with the /111/ direction normal to the surface. An iron-6.5 at. % silicon alloy was studied (a single crystal oriented in the /100/ direction for study of a (100) surface). It was found that surface segregation occurred following sputtering in all cases. Only the iron-silicon single crystal alloy exhibited equilibrium segregation (i.e., reversibility of surface concentration with temperature) for which at present we have no explanation. McLean's analysis for equilibrium segregation at grain boundaries did not apply to the present results, despite the successful application to dilute copper-aluminum alloys. The relation of solute atomic size and solubility to surface segregation is discussed. Estimates of the depth of segregation in the copper-tin alloy indicate that it is of the order of a monolayer surface film.

  11. binary complexes

    African Journals Online (AJOL)

    Preferred Customer

    the temperature constant, two hollow metallic plates coated with thin plastic paper on the outer surface were used ... of metal carbonates from 0.1 M solution of sodium carbonate (Analytical Reagent grade, BDH,. UK). ... different pH values of the background electrolyte (variation in pH was made by addition of caustic soda ...

  12. Wick rotations of solutions to the minimal surface equation, the zero ...

    Indian Academy of Sciences (India)

    60

    1 From left to right: The doubly periodic Scherk minimal surface, Scherk type zero mean curvature surface in [19] and the corresponding solution to (3). In general, solutions to the equations (1), (2) and (3) are related by changing pa- rameters called Wick rotations. In 1954, the physicist Wick [25] argued that one is allowed to ...

  13. Effect of concentration and temperature on surface tension of sodium hyaluronate saline solutions.

    Science.gov (United States)

    Ribeiro, Walkiria; Mata, José Luis; Saramago, Benilde

    2007-06-19

    The effect of concentration and temperature on the surface tension of sodium hyaluronate (NaHA) saline solutions was investigated using the technique of the shape of pendant drops. The decay rate of the surface tension with the increase of NaHA concentration was well-described by the empirical Hua-Rosen equation. Adsorption at the air-liquid interface was estimated using the Gibbs equation. The temperature dependence of a dilute solution and a semidilute entangled solution was numerically fitted with a second-order polynomial equation. The surface behavior of the NaHA saline solutions was interpreted in terms of their known viscoelastic properties.

  14. Kinetics of hydrolysis of 4-methoxyphenyl-2,2-dichloroethanoate in binary water-cosolvent mixtures; the role of solvent activity and solute-solute interactions

    NARCIS (Netherlands)

    Rispens, Theo; Cabaleiro-Lago, Celia; Engberts, Jan B. F. N.

    2005-01-01

    Rate constants are reported for the pH-independent hydrolysis of 4-methoxyphenyl-2,2-dichloroethanoate in aqueous solution as a function of the concentration of added cyanomethane (acetonitrile), polyethylene glycol (PEG 400) and tetrahydrofuran (THF). The concentration of water was varied between

  15. Kinetics of hydrolysis of 4-methoxyphenyl-2,2-dichloroethanoate in binary water-cosolvent mixtures; the role of solvent activity and solute-solute interactions

    NARCIS (Netherlands)

    Rispens, T; Cabaleiro-Lago, C; Engberts, JBFN

    2005-01-01

    Rate constants are reported for the pH-independent hydrolysis of 4-methoxyphenyl-2,2-dichloroethanoate in aqueous solution as a function of the concentration of added cyanomethane ( acetonitrile), polyethylene glycol ( PEG 400) and tetrahydrofuran ( THF). The concentration of water was varied

  16. Approximate solutions of some problems of scattering of surface ...

    Indian Academy of Sciences (India)

    A Choudhary

    reflection coefficients are compared to the known results obtained by utilizing a Galerkin type of approximate method after reducing the bvps to integral equations whose complete solutions are difficult to be determined. Various combinations of discretization of the resulting dual series relations obtained in the present ...

  17. Surface Complexation of Calcium Minerals in Aqueous Solution.

    Science.gov (United States)

    Wu; Forsling; Holmgren

    2000-04-15

    The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorite particles has been investigated by means of potentiometric titrations, adsorption experiments, and zeta-potential measurements in 0.1 mol dm(-3) KCl ionic medium at 25.0 degrees C, as well as by UV/visible specular reflectance, FT-IR, and FT-Raman spectroscopy. Chemical reaction models describing the equilibria of ARS (HA(2-)) at the aqueous fluorite surfaces ( identical withX) have been established as follows: Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. Surface complexation mechanisms involving the R-SO(3)(-), R-beta-OH, and R-alpha-OH active groups of the ARS molecule are proposed to describe coordination to the fluorite surface. Copyright 2000 Academic Press.

  18. Formation process of micro arc oxidation coatings obtained in a sodium phytate containing solution with and without CaCO{sub 3} on binary Mg-1.0Ca alloy

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, R.F. [School of Material and Electromechanics, Jiangxi Science and Technology Normal University, Nanchang 330013 (China); Zhang, Y.Q. [Zhejiang DunAn Light Alloy Technology CO,.LTD, Zhuji 311835 (China); Hunan University of Science and Technology, Xiangtan 411201 (China); Zhang, S.F.; Qu, B. [School of Material and Electromechanics, Jiangxi Science and Technology Normal University, Nanchang 330013 (China); Guo, S.B. [Hunan University of Science and Technology, Xiangtan 411201 (China); Xiang, J.H., E-mail: xiangjunhuai@163.com [School of Material and Electromechanics, Jiangxi Science and Technology Normal University, Nanchang 330013 (China)

    2015-01-15

    Highlights: • Compared to the Mg phase, the area of Mg{sub 2}Ca phase is much smaller. • The coatings are preferentially developed on the area adjacent to Mg{sub 2}Ca phase. • During MAO process, some sodium phytate molecules are hydrolyzed. • Anodic coatings are developed from uneven to uniform. - Abstract: Micro arc oxidation (MAO) is an effective method to improve the corrosion resistance of magnesium alloys. In order to reveal the influence of alloying element Ca and CaCO{sub 3} electrolyte on the formation process and chemical compositions of MAO coatings on binary Mg-1.0Ca alloy, anodic coatings after different anodizing times were prepared on binary Mg-1.0Ca alloy in a base solution containing 3 g/L sodium hydroxide and 15 g/L sodium phytate with and without addition of CaCO{sub 3}. The coating formation was studied by using scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). The results show that Mg-1.0Ca alloy is composed of two phases, the Mg phase and Mg{sub 2}Ca phase. After treating for 5 s, the coating began to develop and was preferentially formed on the area nearby Mg{sub 2}Ca phase, which may be resulted from the intrinsic electronegative potential of the Mg phase than that of Mg{sub 2}Ca phase. Anodic coatings unevenly covered the total surface after 20 s. After 80 s, the coatings were uniformly developed on Mg-1.0Ca alloy with micro pores. During MAO process, some sodium phytate molecules are hydrolyzed into inorganic phosphate. CaCO{sub 3} has minor influence on the calcium content of the obtained MAO coatings.

  19. NUMERICAL AND ANALYTIC SOLUTION OF PRANDTL’S EQUATION FOR SOLID BODIES WITH AGREED CONTACT SURFACES

    Directory of Open Access Journals (Sweden)

    A. Chigarev

    2013-01-01

    Full Text Available The paper considers a method for problem solution pertaining to compression of elastic bodies bounded by cylindrical surfaces whose radii are almost equal. The objective aim does not allow to apply the Hertz theory and reduces to finding approximate solutions of the Prandtl’s equation. The  resulting solution is compared with the solution in the ANSYS system. 

  20. Dynamics of intramolecular spin exchange interaction of a nitronyl nitroxide diradical in solution and on surfaces

    OpenAIRE

    Lloveras Montserrat, Vega; Badetti, Elena; Veciana Miró, Jaume; Vidal-Gancedo, José

    2016-01-01

    In this paper we report the study of the dynamics of a thermally modulated intramolecular spin exchange interaction of a novel diradical nitronyl nitroxide-substituted disulfide in solution and when it is grafted on a gold surface. The structure of this diradical was designed to have flexible chains leading to intramolecular collisions and hence spin exchange interaction, and with an appropriate binding group to be grafted on the gold surface to study its behavior on the surface. In solution,...

  1. Solidification of salt solutions on a horizontal surface

    International Nuclear Information System (INIS)

    Braga, S.L.; Viskanta, R.

    1990-01-01

    The freezing of water-salt solutions on a horizontal wall is investigated experimentally and theoretically. The growth of the solid-liquid region is observed for NaCl - H sub(2)O and N H sub(4)Cl - H sub(2)O systems under different temperature and concentration conditions. A unidirectional mathematical model is used to predict the solidification process. The transport of heat is by diffusion, and convection is absent. The mass diffusion is neglected and the growth of crystal is governed by the transport of heat. In all experiments, the solution salt concentration is smaller than the eutectic composition, and the wall temperature is higher than the eutectic temperature. The predicted temperature and salt concentration profiles, as well as the interface position, are compared with experimental data. (author)

  2. Physicochemical properties of binary solutions of propylene carbonate-acetonitrile in the range of 253.15-313.15 K

    Science.gov (United States)

    Tyunina, E. Yu.; Chekunova, M. D.

    2017-05-01

    The density, dynamic viscosity, and dielectric constant of propylene carbonate solutions with acetonitrile are measured over the composition of a mixed solvent at temperatures of 253.15, 273.15, 293.15, and 313.15 K. The molar volume, molar viscosity, and molar capacity of a mixture of propylene carbonate-acetonitrile and an excess amount of it are calculated. The effect the temperature and composition of the mixture have on the excess molar properties is discussed. A linear correlation is observed between the values of the molar fluidity, capacity, polarization, and molar volume of the studied system.

  3. Vapor pressure of heat transfer fluids of absorption refrigeration machines and heat pumps: Binary solutions of lithium nitrate with methanol

    International Nuclear Information System (INIS)

    Safarov, Javid T.

    2005-01-01

    Vapor pressure p of LiNO 3 + CH 3 OH solutions at T = (298.15 to 323.15) K was reported, osmotic φ and activity coefficients γ; and activity of solvent a s have been evaluated. The experiments were carried out in molality range m = (0.18032 to 5.2369) mol . kg -1 . The Antoine equation was used for the empiric description of experimental vapor pressure results. The Pitzer-Mayorga model with inclusion of Archer's ionic strength dependence of the third virial coefficient was used for the description of calculated osmotic coefficients. The parameters of Archer extended Pitzer model were used for evaluation of activity coefficients

  4. Conical intersections of free energy surfaces in solution: Effect of electron correlation on a protonated Schiff base in methanol solution

    International Nuclear Information System (INIS)

    Mori, Toshifumi; Nakano, Katsuhiro; Kato, Shigeki

    2010-01-01

    The minimum energy conical intersection (MECI) optimization method with taking account of the dynamic electron correlation effect [T. Mori and S. Kato, Chem. Phys. Lett. 476, 97 (2009)] is extended to locate the MECI of nonequilibrium free energy surfaces in solution. A multistate electronic perturbation theory is introduced into the nonequilibrium free energy formula, which is defined as a function of solute and solvation coordinates. The analytical free energy gradient and interstate coupling vectors are derived, and are applied to locate MECIs in solution. The present method is applied to study the cis-trans photoisomerization reaction of a protonated Schiff base molecule (PSB3) in methanol (MeOH) solution. It is found that the effect of dynamic electron correlation largely lowers the energy of S 1 state. We also show that the solvation effect strongly stabilizes the MECI obtained by twisting the terminal C=N bond to become accessible in MeOH solution, whereas the conical intersection is found to be unstable in gas phase. The present study indicates that both electron correlation and solvation effects are important in the photoisomerization reaction of PSB3. The effect of counterion is also examined, and seems to be rather small in solution. The structures of free energy surfaces around MECIs are also discussed.

  5. Surface Force of Polystyrene Latex Particles in Aqueous Anionic Amphipathic Solutions

    Science.gov (United States)

    Fujii, Masatoshi; Hamochi, Nagisa; Kato, Tadashi

    2008-07-01

    The surface forces between a polystyrene particle (negatively charged surface) of latex and a flat silica plate for several concentrations of aqueous solution of anionic amphipathic molecules (sodium dodecylsulfonate) were investigated using an atomic force microscope (AFM) colloidal probe method. In the lower concentration region approximately 1-2 mM, the surface force showed general repulsive profiles according to normal Derjaguin-Landau-Verwey-Overbeek (DLVO) theory between the surfaces having the same sign of surface charge under an electrolyte aqueous solution. While in the higher concentration region at less than the critical micelle concentration (cmc), the surface force showed attractive profiles. Findings suggest that the anionic amphipathic molecules adsorbed to the polystyrene particle in the higher concentration region and induced changes in the surface morphology and properties of the surface region. The change in the surface morphology is believed to be one of the origins of the attractive interaction.

  6. Effect of temperature on the behavior of surface properties of alcohols in aqueous solution

    International Nuclear Information System (INIS)

    Romero, Carmen M.; Jimenez, Eulogio; Suarez, Felipe

    2009-01-01

    The influence of temperature on the behavior of surface properties of aqueous solutions has often been used to obtain information about solute structural effects on water. In this work, we present experimental results for surface tension of aqueous solutions of n-pentanol, n-hexanol, n-heptanol, and n-octanol at T = (283.15, 288.15, 293.15, 298.15, 303.15, and 308.15) K at several concentrations. The results were used to evaluate the limiting experimental slopes of surface tension with respect to mole fraction and the hydrophobicity constant of the Connors model at each temperature. The thermodynamic behavior of aqueous alcohol solutions is discussed in terms of the effect of the hydrocarbon chain on water structure. The temperature dependence of the limiting slopes of surface tension with respect to mole fraction, as well as the hydrophobicity constant derived from surface measurements, is interpreted in terms of alcohol hydration

  7. Interacting binaries

    CERN Document Server

    Shore, S N; van den Heuvel, EPJ

    1994-01-01

    This volume contains lecture notes presented at the 22nd Advanced Course of the Swiss Society for Astrophysics and Astronomy. The contributors deal with symbiotic stars, cataclysmic variables, massive binaries and X-ray binaries, in an attempt to provide a better understanding of stellar evolution.

  8. Influence of solution chemistry on the deposition and detachment kinetics of RNA on silica surfaces.

    Science.gov (United States)

    Shen, Yun; Kim, Hyunjung; Tong, Meiping; Li, Qingyun

    2011-02-01

    The deposition kinetics of RNA extracted from both virus and bacteria on silica surfaces were examined in both monovalent (NaCl) and divalent (CaCl(2)) solutions under a wide range of environmentally relevant ionic strength and pH conditions by utilizing a quartz crystal microbalance with dissipation (QCM-D). To better understand the RNA deposition mechanisms, QCM-D data were complemented by diffusion coefficients and zeta potentials of RNA as a function of examined solution chemistry conditions. Favorable deposition of RNA on poly-l-lysine-coated (positively charged) silica surfaces was governed by the convective-diffusive transport of RNA to the surfaces. The deposition kinetics of RNA on bare silica surfaces were controlled by classic Derjaguin-Landau-Verwey-Overbeek (DLVO) interactions. The presence of divalent cations (Ca(2+)) in solutions greatly enhanced the deposition kinetics of RNA on silica surfaces. Solution pH also affected the deposition behavior of RNA on silica surfaces. Release experiments showed that detachment of RNA from silica surfaces was significant in NaCl solutions, whereas, the deposited RNA on silica surfaces in CaCl(2) solutions was more likely to be irreversible. Copyright © 2010 Elsevier B.V. All rights reserved.

  9. Surface Crystallization of Aqueous Salt Solution Under Overheating and Overcooling

    Directory of Open Access Journals (Sweden)

    Nakoryakov Vladimir

    2016-01-01

    Full Text Available The investigation of the surface crystallization with low negative and high positive temperatures were carried in the paper. Crystallization curves for distillate (Ts0 = −9 °C and different mass salt concentrations NaCl (Ts0 = 80 °C were obtained. Experimental data indicate that the crystallization centers influence each other and the number of centers does not change with time. The maximum speeds for the crystallization front reached 0.3–0.5 m/s. There are a significant anisotropy and a curvature of crystallization front. The surface kinetics should be considered to clarify the rate of freezing and melting of ice in modeling global warming.

  10. Analytical solutions of linked fault tree probabilistic risk assessments using binary decision diagrams with emphasis on nuclear safety applications

    International Nuclear Information System (INIS)

    Nusbaumer, O. P. M.

    2007-01-01

    This study is concerned with the quantification of Probabilistic Risk Assessment (PRA) using linked Fault Tree (FT) models. Probabilistic Risk assessment (PRA) of Nuclear Power Plants (NPPs) complements traditional deterministic analysis; it is widely recognized as a comprehensive and structured approach to identify accident scenarios and to derive numerical estimates of the associated risk levels. PRA models as found in the nuclear industry have evolved rapidly. Increasingly, they have been broadly applied to support numerous applications on various operational and regulatory matters. Regulatory bodies in many countries require that a PRA be performed for licensing purposes. PRA has reached the point where it can considerably influence the design and operation of nuclear power plants. However, most of the tools available for quantifying large PRA models are unable to produce analytically correct results. The algorithms of such quantifiers are designed to neglect sequences when their likelihood decreases below a predefined cutoff limit. In addition, the rare event approximation (e.g. Moivre's equation) is typically implemented for the first order, ignoring the success paths and the possibility that two or more events can occur simultaneously. This is only justified in assessments where the probabilities of the basic events are low. When the events in question are failures, the first order rare event approximation is always conservative, resulting in wrong interpretation of risk importance measures. Advanced NPP PRA models typically include human errors, common cause failure groups, seismic and phenomenological basic events, where the failure probabilities may approach unity, leading to questionable results. It is accepted that current quantification tools have reached their limits, and that new quantification techniques should be investigated. A novel approach using the mathematical concept of Binary Decision Diagram (BDD) is proposed to overcome these deficiencies

  11. Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential

    Directory of Open Access Journals (Sweden)

    Kovo G. Akpomie

    2015-09-01

    Full Text Available The potential of a low-cost Nigerian montmorillonite for the adsorption of Ni(II and Mn(II ions from aqueous solution was investigated by batch mode. XRD, SEM and BET analysis were used to characterize the adsorbent. The experiments were performed as a function of pH, particle size, adsorbent dose, initial metal ion concentration, contact time, ligands and temperature. The process was found to be dependent on all the parameters investigated, with a pH of 6.0 obtained for optimum removal of both metal ions. The Langmuir monolayer adsorption capacity of 166.67 and 142.86 mg/g was obtained for Ni(II and Mn(II ions respectively. The Freundlich isotherm gave the best fit to the experimental data than the Langmuir, Temkin and Dubinin–Radushkevich isotherms. The scatchard plot analysis indicated the existence of more than one type of active site on the montmorillonite which corroborates the good fit of the Freundlich model. The pseudo-first order, pseudo-second order and intraparticle diffusion models were applied to the kinetic data. The best fit was achieved with the pseudo-first order model and the existence of intraparticle diffusion mechanism was indicated. Thermodynamic studies showed an endothermic, dissociative, spontaneous and a physical adsorption process between the metal ions and the montmorillonite. Desorption studies revealed over 90% desorption of both metal ions from the metal loaded adsorbent.

  12. Micellar solubilization in strongly interacting binary surfactant systems. [Binary surfactant systems of: dodecyltrimethylammonium chloride + sodium dodecyl sulfate; benzyldimethyltetradecylammonium chloride + tetradecyltrimethylammonium chloride

    Energy Technology Data Exchange (ETDEWEB)

    Treiner, C. (Universite Pierre et Marie Curie, Paris (France)); Nortz, M.; Vaution, C. (Faculte de Pharmacie de Paris-sud, Chatenay-Malabry (France))

    1990-07-01

    The apparent partition coefficient P of barbituric acids between micelles and water has been determined in mixed binary surfactant solutions from solubility measurements in the whole micellar composition range. The binary systems chosen ranged from the strongly interacting system dodecyltrimethylammonium chloride + sodium dodecyl sulfate to weakly interacting systems such as benzyldimethyltetradecylammonium chloride + tetradecyltrimethyammonium chloride. In all cases studied, mixed micelle formation is unfavorable to micellar solubilization. A correlation is found between the unlike surfactants interaction energy, as measured by the regular solution parameter {beta} and the solute partition coefficient change upon surfactant mixing. By use of literature data on micellar solubilization in binary surfactant solutions, it is shown that the change of P for solutes which are solubilized by surface adsorption is generally governed by the sign and amplitude of the interaction parameter {beta}.

  13. The surface tension of aqueous solutions of some atmospheric water-soluble organic compounds

    Science.gov (United States)

    Tuckermann, Rudolf; Cammenga, Heiko K.

    The surface tensions of aqueous solutions of levoglucosan, 3-hydroxybutanoic acid, 3-hydroxybenzoic acid, azelaic acid, pinonic acid, and humic acid have been measured. These compounds are suggested as model substances for the water-soluble organic compounds (WSOC) in atmospheric aerosols and droplets which may play an important role in the aerosol cycle because of their surface-active potentials. The reductions in surface tension induced by single and mixed WSOC in aqueous solution of pure water is remarkable. However, the results of this investigation cannot explain the strong reduction in surface tension in real cloud and fog water samples at concentrations of WSOC below 1 mg/mL.

  14. An initial research on solute migration model coupled with adsorption of surface complexation in groundwater

    International Nuclear Information System (INIS)

    Qian Tianwei; Chen Fanrong

    2003-01-01

    The influence of solution chemical action in groundwater on solute migration has attracted increasing public attention, especially adsorption action occurring on surface of solid phase and liquid phase, which has play a great role in solute migration. There are various interpretations on adsorption mechanism, in which surface complexion is one of successful hypothesis. This paper first establishes a geochemical model based on surface complexion and then coupled it with traditional advection-dispersion model to constitute a solute migration model, which can deal with surface complexion action. The simulated results fit very well with those obtained by the precursors, as compared with a published famous example, which indicates that the model set up by this paper is successful. (authors)

  15. Separation of uranium(V I) from binary solution mixtures with thorium(IV), zirconium(IV) and cerium(III) by foaming

    International Nuclear Information System (INIS)

    Shakir, K.; Aziz, M.; Benyamin, K.

    1992-01-01

    Foam separation has been investigated for the removal of uranium(V I), thorium(IV), zirconium(IV) and cerium(III) from dilute aqueous solutions at pH values ranging from about I to about II. Sodium laurel sulphate (Na L S) and acetyl trimethyl ammonium bromide (CTAB), being a strong anionic and a strong cationic surfactants, were used as collectors. The results indicate that Na L S can efficiently remove thorium(IV), zirconium(IV) and cerium(III) but not uranium(V I). CTAB, on the other hand, can successfully float only uranium(V I) and zirconium(IV). These differences in flotation properties of the different cations could be used to establish methods for the separation of uranium(V I) from binary mixtures with thorium(IV), zirconium(IV) or cerium(III). The results are discussed in terms of the hydrolytic behaviour of the tested cations and properties of used collectors.2 fig., 1 tab

  16. Azetidinium Functionalized Polytetrahydrofurans: Antimicrobial Properties in Solution and Application to Prepare Non Leaching Antimicrobial Surfaces

    Directory of Open Access Journals (Sweden)

    Subrata Chattopadhyay

    2014-05-01

    Full Text Available In this work, we report the antimicrobial efficacy of azetidinium functionalized polytetrahydrofurans in solution and their application in the preparation of non leaching, antimicrobial surfaces. The excellent antimicrobial efficacy of these water soluble polymers both in solution and on surfaces (>99.99%–100% bacterial growth inhibition makes them excellent candidates for solving the hygiene related problems in the medical and hospital environment.

  17. Influence of chemical additives on the surface reactivity of Si in KOH solution

    NARCIS (Netherlands)

    Philipsen, H.G.G.; Kelly, J.J.

    2009-01-01

    It is known that the electrochemistry of silicon in alkaline solution is closely linked to the anisotropic etching of the semiconductor. In this work the influence of two commonly used additives, hydrogen peroxide and isopropyl alcohol, on the surface chemistry of silicon in KOH solution was

  18. Colloid transport with wetting fronts: interactive effects of solution surface tension and ionic strength.

    Science.gov (United States)

    Zhuang, Jie; Goeppert, Nadine; Tu, Ching; McCarthy, John; Perfect, Edmund; McKay, Larry

    2010-02-01

    Transport of colloids with transient wetting fronts represents an important mechanism of contaminant migration in the vadose zone. The work presented here used steady-state saturated and transient unsaturated flow columns to evaluate the transport of a fluorescent latex microsphere (980 nm in diameter) with capillary wetting fronts of different solution surface tensions and ionic strengths. The saturated transport experiments demonstrated that decreasing solution surface tension and ionic strength decreased colloid deposition at the solid-liquid interface and increased colloid recovery in the column effluent. The effect of solution surface tension on colloid transport and deposition was greater at lower ionic strength, suggesting an interaction between these two factors. Under transient unsaturated flow conditions, the number of colloids retained in sand decreased exponentially with travel distance through the porous media. However, lowering the solution surface tension and ionic strength resulted in a more even distribution of colloids along the column. The measured zeta potentials of colloids in different solutions suggest that both lowering surface tension and ionic strength would enhance the electrostatic repulsion between colloid and sand. The experimental results revealed that the effects are nonlinear, implying the possible existence of critical threshold values, beyond which the effects were not significant. In addition, colloid migration slowed down as solution surface tension decreased due to reduction of capillary forces that drove liquid movement. Copyright 2009 Elsevier Ltd. All rights reserved.

  19. Fabrication of superhydrophobic wood surfaces via a solution-immersion process

    Science.gov (United States)

    Liu, Changyu; Wang, Shuliang; Shi, Junyou; Wang, Chengyu

    2011-11-01

    Superhydrophobic wood surfaces were fabricated from potassium methyl siliconate (PMS) through a convenient solution-immersion method. The reaction involves a hydrogen bond assembly and a polycondensation process. The silanol was formed by reacting PMS aqueous solution with CO2, which was assembled on the wood surface via hydrogen bonds with the wood surface -OH groups. The polymethylsilsesquioxane coating was obtained through the polycondensation reaction of the hydroxyl between wood and silanol. The morphology of products were characterized using a scanning electron microscope (SEM), the surface chemical composition was determined using energy dispersive X-ray analysis (EDXA), Fourier transform infrared spectroscopy (FT-IR), thermogravimetry (TGA) and contact angle measurement. Analytical results revealed that rough protuberances uniformly covered the wood surface, thus transforming the wood surface from hydrophilic to superhydrophobic. The water contact angle of the superhydrophobic wood surface was about 153° and a sliding angle was 4.6°.

  20. Formation of CaCO3 deposits on hard surfaces--effect of bulk solution conditions and surface properties.

    Science.gov (United States)

    Wang, Hao; Alfredsson, Viveka; Tropsch, Juergen; Ettl, Roland; Nylander, Tommy

    2013-05-22

    We have studied nucleation and crystal growth of calcium carbonate on hard surfaces, i.e. stainless steel and silica, at different temperatures, in relation to the corresponding bulk processes, using scanning electron microscopy (SEM), X-ray diffraction (XRD), and ellipsometry. In the bulk solution, a mixture of all three calcium carbonate crystalline polymorphs, calcite, aragonite, and vaterite, as well as amorphous particles was observed at 25 °C, while at 55 °C aragonite and calcite crystals dominated. On surfaces only calcite crystals were observed at 25 °C, whereas aragonite and calcite crystal adsorbed on the surfaces at 55 °C. Two kinds of nucleation and adsorption mechanism of CaCO3 crystals on hard surfaces were observed, depending on the surface orientation (vertical or horizontal, i.e., subject to sedimentation) in the bulk solution. A model for the relation between interfacial layer structure, the substrate, and the solution crystallization is discussed based on the observed difference in deposition between type of surfaces and surface orientation. In addition, the effect of magnesium ion on the morphology of calcium carbonate crystals is discussed.

  1. Efficient Solution of Three-Dimensional Problems of Acoustic and Electromagnetic Scattering by Open Surfaces

    Science.gov (United States)

    Turc, Catalin; Anand, Akash; Bruno, Oscar; Chaubell, Julian

    2011-01-01

    We present a computational methodology (a novel Nystrom approach based on use of a non-overlapping patch technique and Chebyshev discretizations) for efficient solution of problems of acoustic and electromagnetic scattering by open surfaces. Our integral equation formulations (1) Incorporate, as ansatz, the singular nature of open-surface integral-equation solutions, and (2) For the Electric Field Integral Equation (EFIE), use analytical regularizes that effectively reduce the number of iterations required by iterative linear-algebra solution based on Krylov-subspace iterative solvers.

  2. Invariant description of solutions of hydrodynamic-type systems in hodograph space: hydrodynamic surfaces

    International Nuclear Information System (INIS)

    Ferapontov, E.V.

    2002-01-01

    Hydrodynamic surfaces are solutions of hydrodynamic-type systems viewed as non-parametrized submanifolds of the hodograph space. We propose an invariant differential-geometric characterization of hydrodynamic surfaces by expressing the curvature form of the characteristic web in terms of the reciprocal invariants. (author)

  3. Molecular dynamics study of salt–solution interface: Solubility and surface charge of salt in water

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Kazuya; Liang, Yunfeng, E-mail: y-liang@earth.kumst.kyoto-u.ac.jp, E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi, E-mail: y-liang@earth.kumst.kyoto-u.ac.jp, E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp [Environment and Resource System Engineering, Kyoto University, Kyoto 615-8540 (Japan); Sakka, Tetsuo [Department of Energy and Hydrocarbon Chemistry, Kyoto University, Kyoto 615-8510 (Japan)

    2014-04-14

    The NaCl salt–solution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl salt–solution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a salt–solution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  4. Fem Simulation of Triple Diffusive Natural Convection Along Inclined Plate in Porous Medium: Prescribed Surface Heat, Solute and Nanoparticles Flux

    Directory of Open Access Journals (Sweden)

    Goyal M.

    2017-12-01

    Full Text Available In this paper, triple diffusive natural convection under Darcy flow over an inclined plate embedded in a porous medium saturated with a binary base fluid containing nanoparticles and two salts is studied. The model used for the nanofluid is the one which incorporates the effects of Brownian motion and thermophoresis. In addition, the thermal energy equations include regular diffusion and cross-diffusion terms. The vertical surface has the heat, mass and nanoparticle fluxes each prescribed as a power law function of the distance along the wall. The boundary layer equations are transformed into a set of ordinary differential equations with the help of group theory transformations. A wide range of parameter values are chosen to bring out the effect of buoyancy ratio, regular Lewis number and modified Dufour parameters of both salts and nanofluid parameters with varying angle of inclinations. The effects of parameters on the velocity, temperature, solutal and nanoparticles volume fraction profiles, as well as on the important parameters of heat and mass transfer, i.e., the reduced Nusselt, regular and nanofluid Sherwood numbers, are discussed. Such problems find application in extrusion of metals, polymers and ceramics, production of plastic films, insulation of wires and liquid packaging.

  5. Fem Simulation of Triple Diffusive Natural Convection Along Inclined Plate in Porous Medium: Prescribed Surface Heat, Solute and Nanoparticles Flux

    Science.gov (United States)

    Goyal, M.; Goyal, R.; Bhargava, R.

    2017-12-01

    In this paper, triple diffusive natural convection under Darcy flow over an inclined plate embedded in a porous medium saturated with a binary base fluid containing nanoparticles and two salts is studied. The model used for the nanofluid is the one which incorporates the effects of Brownian motion and thermophoresis. In addition, the thermal energy equations include regular diffusion and cross-diffusion terms. The vertical surface has the heat, mass and nanoparticle fluxes each prescribed as a power law function of the distance along the wall. The boundary layer equations are transformed into a set of ordinary differential equations with the help of group theory transformations. A wide range of parameter values are chosen to bring out the effect of buoyancy ratio, regular Lewis number and modified Dufour parameters of both salts and nanofluid parameters with varying angle of inclinations. The effects of parameters on the velocity, temperature, solutal and nanoparticles volume fraction profiles, as well as on the important parameters of heat and mass transfer, i.e., the reduced Nusselt, regular and nanofluid Sherwood numbers, are discussed. Such problems find application in extrusion of metals, polymers and ceramics, production of plastic films, insulation of wires and liquid packaging.

  6. Surface modification of polystyrene with atomic oxygen radical anions-dissolved solution

    International Nuclear Information System (INIS)

    Wang Lian; Yan Lifeng; Zhao Peitao; Torimoto, Yoshifumi; Sadakata, Masayoshi; Li Quanxin

    2008-01-01

    A novel approach to surface modification of polystyrene (PS) polymer with atomic oxygen radical anions-dissolved solution (named as O - water) has been investigated. The O - water, generated by bubbling of the O - (atomic oxygen radical anion) flux into the deionized water, was characterized by UV-absorption spectroscopy and electron paramagnetic resonance (EPR) spectroscopy. The O - water treatments caused an obvious increase of the surface hydrophilicity, surface energy, surface roughness and also caused an alteration of the surface chemical composition for PS surfaces, which were indicated by the variety of contact angle and material characterization by atomic force microscope (AFM) imaging, field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), and attenuated total-reflection Fourier transform infrared (ATR-FTIR) measurements. Particularly, it was found that some hydrophilic groups such as hydroxyl (OH) and carbonyl (C=O) groups were introduced onto the polystyrene surfaces via the O - water treatment, leading to the increases of surface hydrophilicity and surface energy. The active oxygen species would react with the aromatic ring molecules on the PS surfaces and decompose the aromatic compounds to produce hydrophilic hydroxyl and carbonyl compounds. In addition, the O - water is also considered as a 'clean solution' without adding any toxic chemicals and it is easy to be handled at room temperature. Present method may suit to the surface modification of polymers and other heat-sensitive materials potentially

  7. Modulation of physiological hemostasis by irrigation solution: comparison of various irrigation solutions using a mouse brain surface bleeding model.

    Science.gov (United States)

    Fujita, Yasutaka; Doi, Kazuhisa; Harada, Daisuke; Kamikawa, Shuji

    2010-04-01

    Intraoperative bleeding often obscures the surgical field and may cause neurological damage. The irrigation fluids used during surgery might affect physiological hemostasis because they modulate the extracellular fluid composition of the bleeding area directly. The authors therefore investigated the influence of irrigation fluid on hemostasis in a mouse brain surface bleeding model. The cerebral cortices of ddY strain mice were exposed under irrigation with normal saline, lactated Ringer (LR) solution, or artificial CSF (ACF-95). To investigate the influence of electrolytes, calcium, potassium, or both were also added to the saline. After 10 minutes of irrigation at 100 ml/hour, sequential photographs of the surgical area were taken with a microscope, and the number of bleeding points was counted visually. Irrigation and counting were performed in a masked manner. There were significantly more bleeding points after irrigation with normal saline than with ACF-95; LR solution had a similar effect on physiological hemostasis as ACF-95. Saline augmented with calcium or potassium and calcium was superior to normal saline in terms of hemostasis. The authors demonstrated that the irrigation fluid used in neurosurgery affects bleeding at the surgical site. To avoid surgical site bleeding, ACF-95 and LR solution should be used as irrigation fluids instead of normal saline. The calcium and potassium content of irrigation solutions seems to be important in hemostasis.

  8. Iterative discrete ordinates solution of the equation for surface-reflected radiance

    Science.gov (United States)

    Radkevich, Alexander

    2017-11-01

    This paper presents a new method of numerical solution of the integral equation for the radiance reflected from an anisotropic surface. The equation relates the radiance at the surface level with BRDF and solutions of the standard radiative transfer problems for a slab with no reflection on its surfaces. It is also shown that the kernel of the equation satisfies the condition of the existence of a unique solution and the convergence of the successive approximations to that solution. The developed method features two basic steps: discretization on a 2D quadrature, and solving the resulting system of algebraic equations with successive over-relaxation method based on the Gauss-Seidel iterative process. Presented numerical examples show good coincidence between the surface-reflected radiance obtained with DISORT and the proposed method. Analysis of contributions of the direct and diffuse (but not yet reflected) parts of the downward radiance to the total solution is performed. Together, they represent a very good initial guess for the iterative process. This fact ensures fast convergence. The numerical evidence is given that the fastest convergence occurs with the relaxation parameter of 1 (no relaxation). An integral equation for BRDF is derived as inversion of the original equation. The potential of this new equation for BRDF retrievals is analyzed. The approach is found not viable as the BRDF equation appears to be an ill-posed problem, and it requires knowledge the surface-reflected radiance on the entire domain of both Sun and viewing zenith angles.

  9. Corrosion Resistance and Durability of Superhydrophobic Copper Surface in Corrosive NaCl Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Chun-Wei Yao

    2018-02-01

    Full Text Available Artificial superhydrophobic copper surfaces play an important role in modern applications such as self-cleaning and dropwise condensation; however, corrosion resistance and durability often present as major concerns in such applications. In this study, the anti-corrosion properties and mechanical durability of superhydrophobic copper surface have been investigated. The superhydrophobic copper surfaces were achieved with wet chemical etching and an immersion method to reduce the complexity of the fabrication process. The surface structures and materials were characterized using scanning electron microscope (SEM, energy dispersive X-ray spectroscopy (EDX, and Fourier transform infrared spectrometer (FTIR. The corrosion resistance and mechanical properties of the superhydrophobic copper surface were characterized after immersing surfaces in a 3.5 wt % NaCl solution. The chemical stability of the superhydrophobic copper surface in the NaCl solution for a short period of time was also evaluated. An abrasion test and an ultrasound oscillation were conducted to confirm that the copper surface contained durable superhydrophobic properties. In addition, an atomic force microscope was employed to study the surface mechanical property in the corrosion conditions. The present study shows that the resulting superhydrophobic copper surface exhibit enhanced corrosion resistance and durability.

  10. Effect of a New Surface Treatment Solution on the Bond Strength of Composite to Enamel

    Science.gov (United States)

    2016-06-01

    a lubricated highspeed handpiece. In addition to handpiece lubricant, contaminants such as saliva, blood, dental cements , and imaging powder could...HEALTH SCIENCES AIR FORCE POSTGRADUATE DENTAL SCHOOL 2450 Pepperrell Street Lackland AFB Texas, 78236-5345 http://www.usuhs.ml1 "The author hereby...Solution on the Bond Strength of Composite to Enamel ABSTRACT Clean & Boost (Apex Dental Materials) is a novel surface treatment solution

  11. Modeling of Bisphenol A (BPA) Removal from Aqueous Solutions by Adsorption Using Response Surface Methodology (RSM)

    OpenAIRE

    Mohammad Ali Zazouli; Farzaneh Veisi; Amir Veisi

    2016-01-01

    Bisphenol A (BPA) is an organic synthetic compound that has many applications in various industries and is known as persistent pollutant. The aim of this research was to evaluate the efficiency of bone ash and banana peel as adsorbents for BPA adsorption from aqueous solution by using Response Surface Methodology. The effects of some variables such as sorbent dose, detention time, solution pH, and BPA concentration on the sorption efficiency was examined. All analyses were carried out accordi...

  12. Superhydrophobic copper surfaces fabricated by fatty acid soaps in aqueous solution for excellent corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Wenlong; Hu, Yuanyuan; Bao, Wenda; Xie, Xiaoyu; Liu, Yiran; Song, Aixin, E-mail: songaixin@sdu.edu.cn; Hao, Jingcheng

    2017-03-31

    Highlights: • The superhydrophobic property can be realized in a much quicker process (7.5 min) in aqueous solution than in ethanol. • The fabrication process of superhydrophobic metal surfaces greatly increases the safety in industrial manufacture in commercial scale. • The superhydrophobic copper surfaces show excellent corrosion resistance. - Abstract: A simple and safe one-step immersion method was developed to obtain the stable superhydrophobic copper surfaces with excellent corrosion resistance ability using fatty acids in water-medium instead of ethanol. An organic alkali, N,N-dimethylcyclohexylamine (DMCHA), was chosen to solve the poor solubility of fatty acids in water and the high Krafft point of carboxylate salts with inorganic counterions. The superhydrophobic property can be realized in a much quicker process (7.5 min) in aqueous solution than in ethanol (more than 2 d), which is universally feasible for the fabrication of superhydrophobic metal surfaces in industry scale, thereby greatly increasing the safety in industrial manufacture.

  13. INFLUENCE OF AISI 316Ti STAINLESS STELL SURFACE TREATMENT ON PITTING CORROSION IN VARIOUS SOLUTIONS

    Directory of Open Access Journals (Sweden)

    Pavol Fajnor

    2010-12-01

    Full Text Available Investigation of the surface treatment effect on the resistance of AISI 316Ti stainless steel to pitting corrosion is presented in this paper. The grinded surfaces without additional chemical treatment, grinded and pickled, grinded, pickled and passivated surfaces are tested. The corrosion tests are carried out by exposition in solution which evoke pitting and by electrochemical cyclic potential - sweep method. According to the results the surface treatment has a great influence on the resistance of the tested material to pitting. It is not possible to estimate the best surface treatment because behavior of AISI 316Ti stainless steel with different surface state depends on the mechanism of corrosion processes which vary in the used experimental methods.

  14. Experiment and model for the surface tension of amine–ionic liquids aqueous solutions

    International Nuclear Information System (INIS)

    Zhang, Pan; Du, LeiXia; Fu, Dong

    2014-01-01

    Highlights: • The surface tensions of MEA/DEA–ionic liquids aqueous solutions were measured. • The experiments were modeled satisfactorily by using a thermodynamic equation. • The temperature dependence of the surface tension was illustrated. • The effects of the mass fractions of MEA/DEA and ionic liquids were demonstrated. - Abstract: The surface tension (γ) of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF 4 ])–monoethanolamine (MEA), 1-butyl-3-methylimidazolium bromide ([Bmim][Br])–MEA, [Bmim][BF 4 ]–diethanolamine (DEA) and [Bmim][Br]–DEA aqueous solutions was measured by using the BZY-1 surface tension meter. The temperature ranged from (293.2 to 323.2) K. The mass fraction of amines and ionic liquids (ILS) respectively ranged from 0.15 to 0.30 and 0.05 to 0.10. A thermodynamic equation was proposed to model the surface tension of amines–ILS aqueous solutions and the calculated results agreed well with the experiments. The effects of temperature, mass fraction of amines and ILS on the surface tension were demonstrated on the basis of experiments and calculations

  15. Wet etching of InSb surfaces in aqueous solutions: Controlled oxide formation

    Energy Technology Data Exchange (ETDEWEB)

    Aureau, D., E-mail: damien.aureau@chimie.uvsq.fr [Institut Lavoisier UVSQ-CNRS UMR 8180, 45 avenue des Etats Unis, Versailles, 78035 (France); Chaghi, R.; Gerard, I. [Institut Lavoisier UVSQ-CNRS UMR 8180, 45 avenue des Etats Unis, Versailles, 78035 (France); Sik, H.; Fleury, J. [Sagem Defense Sécurité, 72-74, rue de la tour Billy, 95101, Argenteuil Cedex (France); Etcheberry, A. [Institut Lavoisier UVSQ-CNRS UMR 8180, 45 avenue des Etats Unis, Versailles, 78035 (France)

    2013-07-01

    This paper investigates the wet etching of InSb surfaces by two different oxidant agents: Br{sub 2} and H{sub 2}O{sub 2} and the consecutive oxides generation onto the surfaces. The strong dependence between the chemical composition of the etching baths and the nature of the final surface chemistry of this low band-gap III–V semiconductor will be especially highlighted. One aqueous etching solution combined hydrobromic acid and Bromine (HBr–Br{sub 2}:H{sub 2}O) with adjusted concentrations. The other solution combines orthophosphoric and citric acids with hydrogen peroxide (H{sub 3}PO{sub 4}–H{sub 2}O{sub 2}:H{sub 2}O). Depending on its composition, each formulation gave rise to variable etching rate. The dosage of Indium traces in the etching solution by atomic absorption spectroscopy (AAS) gives the kinetic variation of the dissolution process. The variations on etching rates are associated to the properties and the nature of the formed oxides on InSb surfaces. Surface characterization is specifically performed by X-ray photoelectron spectroscopy (XPS). A clear evidence of the differences between the formed oxides is highlighted. Atomic force microscopy is used to monitor the surface morphology and pointed out that very different final morphologies can be reached. This paper presents new results on the strong variability of the InSb oxides in relation with the InSb reactivity toward environment interaction.

  16. Far from equilibrium enstatite dissolution rates in alkaline solutions at earth surface conditions

    Science.gov (United States)

    Halder, Sougata; Walther, John V.

    2011-12-01

    Far from equilibrium enstatite dissolution rates both open to atmospheric CO 2 and CO 2 purged were measured as a function of solution pH from 8 to 13 in batch reactors at room temperature. Congruent dissolution was observed after an initial period of incongruent dissolution with preferential Si release from the enstatite. Steady-state dissolution rates in open to atmospheric CO 2 conditions decrease with increase in solution pH from 8 to 12 similar to the behavior reported by other investigators. Judging from the pH 13 dissolution rate, rates increase with pH above pH 12. This is thought to occur because of the increase in overall negative surface charges on enstatite as Mg surface sites become negative above pH 12.4, the pH of zero surface charge of MgO. Steady-state dissolution rates of enstatite increase above pH 10 when CO 2 was purged by performing the experiments in a N 2 atmosphere. This suggests inhibition of dissolution rates above pH 10 when experiments were open to the atmosphere. The dissolved carbonate in these solutions becomes dominantly CO 32- above pH 10.33. It is argued that CO 32- forms a >Mg 2-CO 3 complex at positively charged Mg surface sites on enstatite, resulting in stabilization of the surface Si-O bonds. Therefore, removal of solution carbonate results in an increase in dissolution rates of enstatite above pH 10. The log rate of CO 2-purged enstatite dissolution in moles per cm 2 per s as a function of increasing pH above pH 10 is equal to 0.35. This is consistent with the model of silicate mineral dissolution in the absence of surface carbonation in alkaline solutions proposed earlier in the literature.

  17. pH-specific hydrothermal assembly of binary and ternary Pb(II)-(O,N-carboxylic acid) metal organic framework compounds: correlation of aqueous solution speciation with variable dimensionality solid-state lattice architecture and spectroscopic signatures.

    Science.gov (United States)

    Gabriel, C; Perikli, M; Raptopoulou, C P; Terzis, A; Psycharis, V; Mateescu, C; Jakusch, T; Kiss, T; Bertmer, M; Salifoglou, A

    2012-09-03

    Hydrothermal pH-specific reactivity in the binary/ternary systems of Pb(II) with the carboxylic acids N-hydroxyethyl-iminodiacetic acid (Heida), 1,3-diamino-2-hydroxypropane-N,N,N',N'-tetraacetic acid (Dpot), and 1,10-phenanthroline (Phen) afforded the new well-defined crystalline compounds [Pb(Heida)](n)·nH(2)O(1), [Pb(Phen)(Heida)]·4H(2)O(2), and [Pb(3)(NO(3))(Dpot)](n)(3). All compounds were characterized by elemental analysis, FT-IR, solution or/and solid-state NMR, and single-crystal X-ray diffraction. The structures in 1-2 reveal the presence of a Pb(II) center coordinated to one Heida ligand, with 1 exhibiting a two-dimensional (2D) lattice extending to a three-dimensional (3D) one through H-bonding interactions. The concurrent aqueous speciation study of the binary Pb(II)-Heida system projects species complementing the synthetic efforts, thereby lending credence to a global structural speciation strategy in investigating binary/ternary Pb(II)-Heida/Phen systems. The involvement of Phen in 2 projects the significance of nature and reactivity potential of N-aromatic chelators, disrupting the binary lattice in 1 and influencing the nature of the ultimately arising ternary 3D lattice. 3 is a ternary coordination polymer, where Pb(II)-Dpot coordination leads to a 2D metal-organic-framework material with unique architecture. The collective physicochemical properties of 1-3 formulate the salient features of variable dimensionality metal-organic-framework lattices in binary/ternary Pb(II)-(hydroxy-carboxylate) structures, based on which new Pb(II) materials with distinct architecture and spectroscopic signature can be rationally designed and pursued synthetically.

  18. Elastic-Plastic J-Integral Solutions or Surface Cracks in Tension Using an Interpolation Methodology

    Science.gov (United States)

    Allen, P. A.; Wells, D. N.

    2013-01-01

    No closed form solutions exist for the elastic-plastic J-integral for surface cracks due to the nonlinear, three-dimensional nature of the problem. Traditionally, each surface crack must be analyzed with a unique and time-consuming nonlinear finite element analysis. To overcome this shortcoming, the authors have developed and analyzed an array of 600 3D nonlinear finite element models for surface cracks in flat plates under tension loading. The solution space covers a wide range of crack shapes and depths (shape: 0.2 less than or equal to a/c less than or equal to 1, depth: 0.2 less than or equal to a/B less than or equal to 0.8) and material flow properties (elastic modulus-to-yield ratio: 100 less than or equal to E/ys less than or equal to 1,000, and hardening: 3 less than or equal to n less than or equal to 20). The authors have developed a methodology for interpolating between the goemetric and material property variables that allows the user to reliably evaluate the full elastic-plastic J-integral and force versus crack mouth opening displacement solution; thus, a solution can be obtained very rapidly by users without elastic-plastic fracture mechanics modeling experience. Complete solutions for the 600 models and 25 additional benchmark models are provided in tabular format.

  19. Preliminary solution of traffic surfaces within the parcel of the faculty of civil Engineering in Subotica

    Directory of Open Access Journals (Sweden)

    Škondrić Jovan

    2017-01-01

    Full Text Available Extension of the capacities of the Faculty of Civil Engineering building in Subotica in the form of annexes and sports hall (second phase requires an adequate traffic infrastructure that would satisfy the additional demands. The paper presents the possible solution of traffic surfaces that service the entire lot, as well as the landscaping on the free part of the lot.

  20. Self-Complementary Recognition of Supramolecular Urea - Aminotriazines in Solution and on Surfaces

    NARCIS (Netherlands)

    Embrechts, A.; Velders, Aldrik; Vancso, Gyula J.; Schönherr, Holger

    2011-01-01

    The recognition of self-complementary quadruple urea–aminotriazine (UAT)-based hydrogen-bonded arrays was investigated in solution and at surfaces. For this purpose, an UAT-based donor–acceptor–donor–acceptor (DADA) array and complementary receptors were synthesized. Two-dimensional proton nuclear

  1. Solubility of N2O in and density, viscosity, and surface tension of aqueous piperazine solutions

    NARCIS (Netherlands)

    Derks, P. W.; Hogendoorn, K. J.; Versteeg, G. F.

    2005-01-01

    The physical solubility of N2O in and the density and viscosity of aqueous piperazine solutions have been measured over a temperature range of (293.15 to 323.15) K for piperazine concentrations ranging from about (0.6 to 1.8) kmol·mr-3. Furthermore, the present study contains experimental surface

  2. SURFACE WAKE OF A CIRCULAR CYLINDER IN DILUTE AQUEOUS SOLUTIONS OF POLY(ETHYLENE OXIDE).

    Science.gov (United States)

    The wake formed by surface-piercing circular cylinders towed through 0, 100, and 200 parts per million (by weight) aqueous solutions of Poly( ethylene ... oxide ), Polyox WSR-301, was examined photographically. Cylinder diameters ranged from 1/4 in. to 2 in.; Froude numbers from 0.6 to 10. Measurements

  3. In situ nanoscale observations of metatorbernite surfaces interacted with aqueous solutions.

    Science.gov (United States)

    Astilleros, José Manuel; Pinto, André Jorge; Gonçalves, Mário A; Sánchez-Pastor, Nuria; Fernández-Díaz, Lurdes

    2013-03-19

    Metatorbernite (Cu(UO(2))(2)(PO(4))(2)·8H(2)O) has been identified in contaminated sediments as a phase controlling the fate of U. Here, we applied atomic force microscopy (AFM) to observe in situ the interaction between metatorbernite cleavage surfaces and flowing aqueous solutions (residence time = 1 min) with different pHs. In contact with deionized water the features of (001) surfaces barely modify. However, changes are remarkable both under acidic and basic conditions. In acidic solutions (pH = 2.5) metatorbernite surface develops a rough altered layer and large pits nucleate on it. The altered layer shows a low adhesion and is removed by the AFM tip during the scanning. The large pits spread rapidly, at few tens of nm/s, indicating a collapse of the structure. The combination of dissolution and the presence of defects in the metatorbernite structure can explain both the collapse process and the alteration of the surfaces under acidic conditions. Other mechanisms such as ion exchange reactions remain speculative. In NaOH solutions (pH = 11.5) metatorbernite dissolves by formation of etch pits bounded by steps parallel to [100], the direction of the most straight periodic bond chains (PBCs) in metatorbernite structure. These steps retreat at ∼0.15 nm/s. Under these conditions dissolution is promoted by the formation of stable uranyl carbonate complexes in solution.

  4. Conformation and hydration of surface grafted and free polyethylene oxide chains in solutions

    Science.gov (United States)

    Dahal, Udaya; Wang, Zilu; Dormidontova, Elena

    Due to the wide application of polyethylene oxide (PEO), ranging from biomedicine to fuel cells, it is one of the most studied polymers in the scientific world. In order to elucidate detailed molecular-level insights on the impact of surface grafting on PEO conformation, we performed atomistic molecular dynamics simulations of PEO chains in solution and grafted to a flat gold surface in different solvents. We examined the hydration as well as conformation of the free chain compared to the grafted polymer in pure water and mixed solvents. We find that grafted chains are stiffer and have a stronger tendency to form helical structures in isobutyric acid or mixture of isobutyric acid and water solution than the free chains in corresponding solutions. For grafted chains exposed to pure water the random coil conformation is retained at low grafting density, but becomes stretched and more dehydrated as the grafting density or temperature increases. This research is supported by NSF (DMR-1410928).

  5. Corrosion resistance, chemistry, and mechanical aspects of Nitinol surfaces formed in hydrogen peroxide solutions

    Energy Technology Data Exchange (ETDEWEB)

    Shabalovskay, Svetlana A.; Anderegg, James W.; Undisz, Andreas; Rettenmayr, Markus; Rondelli, Gianni C.

    2012-06-12

    Ti oxides formed naturally on Nitinol surfaces are only a few nanometers thick. To increase their thickness, heat treatments are explored. The resulting surfaces exhibit poor resistance to pitting corrosion. As an alternative approach to accelerate surface oxidation and grow thicker oxides, the exposure of Nitinol to strong oxidizing H2O2 aqueous solutions (3 and 30%) for various periods of time was used. Using X-Ray Photoelectron Spectroscopy (XPS) and Auger spectroscopy, it was found that the surface layers with variable Ti (6–15 at %) and Ni (5–13 at %) contents and the thickness up to 100 nm without Ni-enriched interfaces could be formed. The response of the surface oxides to stress in superelastic regime of deformations depended on oxide thickness. In the corrosion studies performed in both strained and strain-free states using potentiodynamic and potentiostatic polarizations, the surfaces treated in H2O2 showed no pitting in corrosive solution that was assigned to higher chemical homogeneity of the surfaces free of secondary phases and inclusions that assist better biocompatibility of Nitinol medical devices. © 2012 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater 100B: 1490–1499, 2012

  6. Effect of solution chemistry on the adsorption of perfluorooctane sulfonate onto mineral surfaces.

    Science.gov (United States)

    Tang, Chuyang Y; Shiang Fu, Q; Gao, Dawen; Criddle, Craig S; Leckie, James O

    2010-04-01

    Perfluorooctane sulfonate (PFOS) is an emergent contaminant of substantial environmental concerns, yet very limited information has been available on PFOS adsorption onto mineral surfaces. PFOS adsorption onto goethite and silica was investigated by batch adsorption experiments under various solution compositions. Adsorption onto silica was only marginally affected by pH, ionic strength, and calcium concentration, likely due to the dominance of non-electrostatic interactions. In contrast, PFOS uptake by goethite increased significantly at high [H+] and [Ca2+], which was likely due to enhanced electrostatic attraction between the negatively charged PFOS molecules and positively charged goethite surface. The effect of pH was less significant at high ionic strength, likely due to electrical double layer compression. PFOS uptake was reduced at higher ionic strength for a strongly positively charged goethite surface (pH 3), while it increased for a weakly charged surface (pH 7 and 9), which could be attributed to the competition between PFOS-surface electrostatic attraction and PFOS-PFOS electrostatic repulsion. A conceptual model that captures PFOS-surface and PFOS-PFOS electrostatic interactions as well as non-electrostatic interaction was also formulated to understand the effect of solution chemistry on PFOS adsorption onto goethite and silica surfaces. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  7. Bioaccumulation of the synthetic dye Basic Violet 3 and heavy metals in single and binary systems by Candida tropicalis grown in a sugarcane bagasse extract medium: Modelling optimal conditions using response surface methodology (RSM) and inhibition kinetics

    International Nuclear Information System (INIS)

    Das, Devlina; Charumathi, D.; Das, Nilanjana

    2011-01-01

    Single and binary effects of dye Basic Violet 3 and heavy metals, 'namely', Pb(II) and Cd(II), were investigated for their role in dye and heavy metal bioaccumulation by Candida tropicalis that was grown in a sugarcane bagasse extract medium containing 8 g/L, 16 g/L or 24 g/L of sugar. The optimum pH was found to be 4.0 in the single system and 5.0 in the binary system. A central composite design was successfully used to analyse the experimental results. Four numerical correlations that were fitted to a second order quadratic equation were used to estimate optimum combinations predicted by response surface methodology. In the dye-Pb(II) binary system, C. tropicalis was capable of bioaccumulating 49.5% of the dye and 49.6% of the Pb(II), in comparison to 15.9% of the dye and 55.5% of the Cd(II) in the dye-Cd(II) binary system. In these two systems, the pollutants were dispersed at minimum working concentration levels. Competitive inhibition was observed in both the single and binary systems, which was suggested by an increase in the saturation constant, K s , and a simultaneous decrease in the specific growth rate that was calculated from Lineweaver-Burk plots. Atomic force microscopy images demonstrated changes in yeast cell morphology by exposure to these contaminants in the dye-Pb(II) binary system grown in a bioaccumulation medium.

  8. Asymptotic solutions for MHD systems with a rapid jump near a moving surface

    Science.gov (United States)

    Allilueva, Anna I.; Shafarevich, Andrei I.

    2018-02-01

    We study the Cauchy problem for a nonlinear system of Magnetohydrodynamics. The viscosity and conductivity are assumed to be small and the initial fields are assumed to jump rapidly near certain smooth 2D-surface in 3D-space. We construct formal asymptotic solution for this Cauchy problem. We study the spatial structure and time behavior of the solution. In particular, we derive free boundary problem for the limit values of the magnetic field and the velocity field of the fluid. This problem also governs the evolution of the surface of the jump. We derive equations on the moving surface, describing the evolution of the field profile. In particular, we prove that the effect of the instantaneous growth of the magnetic field takes place only for degenerate asymptotic modes.

  9. Surface tension anomalies in room temperature ionic liquids-acetone solutions

    Science.gov (United States)

    Abe, Hiroshi; Murata, Keisuke; Kiyokawa, Shota; Yoshimura, Yukihiro

    2018-05-01

    Surface tension anomalies were observed in room temperature ionic liquid (RTIL)-acetone solutions. The RTILs are 1-alkyl-3-methylimidazorium iodide with [Cnmim][I] in a [Cnmim][I]-x mol% acetone. The maximum value of the surface tension appeared at 40 mol% acetone, although density decreased monotonically with an increase in acetone concentration. A small alkyl chain length effect of the Cnmim+ cations was observed in the surface tension. By the Gibbs adsorption isotherm, it was found that I- anion-mediated surface structure became dominant above 40 mol%. In the different [Cnmim][TFSI]-acetone mixtures, normal decay of the surface tension was observed on the acetone concentration scale, where TFSI- is bis(trifluoromethanesulfonyl)imide.

  10. Evaluation of interatomic potentials for rainbow scattering under axial channeling at KCl(0 0 1) surface by three-dimensional computer simulations based on binary collision approximation

    Energy Technology Data Exchange (ETDEWEB)

    Takeuchi, Wataru, E-mail: take@sp.ous.ac.jp

    2017-05-01

    The rainbow angles corresponding to prominent peaks in the angular distributions of scattered projectiles with small angle, attributed to rainbow scattering (RS), under axial surface channeling conditions are strongly influenced by the interatomic potentials between projectiles and target atoms. The dependence of rainbow angles on normal energy of projectile energy to the target surface, being experimentally obtained by Specht et al. for RS of He, N, Ne and Ar atoms under 〈1 0 0〉 and 〈1 1 0〉 axial channeling conditions at a KCl(0 0 1) surface with projectile energies of 1–60 keV, was evaluated by the three-dimensional computer simulations using the ACOCT code based on the binary collision approximation with interatomic pair potentials. Good agreement between the ACOCT results using the ZBL pair potential and the individual pair potentials calculated from Hartree-Fock (HF) wave functions and the experimental ones was found for RS of He, N and Ne atoms from the atomic rows along 〈1 0 0〉 direction. For 〈1 1 0〉 direction, the ACOCT results employing the Moliere pair potential with adjustable screening length of O’Connor-Biersack (OB) formula, the ZBL pair potential and the individual HF pair potentials except for Ar → KCl using the OB pair potential are nearly in agreement with the experimental ones.

  11. Evaluation of interatomic potentials for rainbow scattering under axial channeling at KCl(0 0 1) surface by three-dimensional computer simulations based on binary collision approximation

    Science.gov (United States)

    Takeuchi, Wataru

    2017-05-01

    The rainbow angles corresponding to prominent peaks in the angular distributions of scattered projectiles with small angle, attributed to rainbow scattering (RS), under axial surface channeling conditions are strongly influenced by the interatomic potentials between projectiles and target atoms. The dependence of rainbow angles on normal energy of projectile energy to the target surface, being experimentally obtained by Specht et al. for RS of He, N, Ne and Ar atoms under and axial channeling conditions at a KCl(0 0 1) surface with projectile energies of 1-60 keV, was evaluated by the three-dimensional computer simulations using the ACOCT code based on the binary collision approximation with interatomic pair potentials. Good agreement between the ACOCT results using the ZBL pair potential and the individual pair potentials calculated from Hartree-Fock (HF) wave functions and the experimental ones was found for RS of He, N and Ne atoms from the atomic rows along direction. For direction, the ACOCT results employing the Moliere pair potential with adjustable screening length of O'Connor-Biersack (OB) formula, the ZBL pair potential and the individual HF pair potentials except for Ar → KCl using the OB pair potential are nearly in agreement with the experimental ones.

  12. Manufacture of nanosized apatite coatings on titanium with different surface treatments using a supersaturated calcification solution

    Directory of Open Access Journals (Sweden)

    Adrian Paz Ramos

    Full Text Available The biomimetic method is used for the deposition of calcium phosphate coatings (Ca - P on the surface of different biomaterials. However, the application of this method requires long exposure times in order to obtain a suitable layer thickness for its use in medical devices. In this paper, we present a fast approach to obtain apatite coatings on titanium, using a combination of supersaturated calcification solution (SCS with chemical modification of the titanium surface. Also, it was evaluated the effect of four different surface treatments on the apatite deposition rate. Commercially pure titanium plates were activated by chemical or thermochemical treatments. Then, the activated samples were immersed in a solution with high content of calcium and phosphate ions at 37 ºC for 24 h, mimicking the physiological conditions. The coatings were studied by Fourier transform infrared spectroscopy (FTIR, X-ray diffraction (XRD, scanning electron microscopy (SEM and energy dispersive X-ray spectroscopy (EDX. The use of SCS solutions allowed the formation of crystalline hydroxyapatite coatings within a period of 24 h with a thickness between 1 and 5.3 µm. Besides, precipitates of hydroxyapatite nanoparticles with a globular configuration, forming aggregates with submicrometer size, were found in SCS solutions.

  13. Content identification: binary content fingerprinting versus binary content encoding

    Science.gov (United States)

    Ferdowsi, Sohrab; Voloshynovskiy, Svyatoslav; Kostadinov, Dimche

    2014-02-01

    In this work, we address the problem of content identification. We consider content identification as a special case of multiclass classification. The conventional approach towards identification is based on content fingerprinting where a short binary content description known as a fingerprint is extracted from the content. We propose an alternative solution based on elements of machine learning theory and digital communications. Similar to binary content fingerprinting, binary content representation is generated based on a set of trained binary classifiers. We consider several training/encoding strategies and demonstrate that the proposed system can achieve the upper theoretical performance limits of content identification. The experimental results were carried out both on a synthetic dataset with different parameters and the FAMOS dataset of microstructures from consumer packages.

  14. Characterization of surface processes on mineral surfaces in aqueous solutions. Annual report for fiscal year 1993

    International Nuclear Information System (INIS)

    Leckie, J.O.

    1993-11-01

    Performance assessments by Los Alamos National Laboratory for the DOE's Yucca Mountain Site Characterization Project (YMP) are being done investigating the environmental risk related to long-term disposal of hazardous wastes resulting from the use of radioactive materials that must subsequently be isolated from the environment. The YMP site, located in southwestern Nevada, is intended for the storage of high-level wastes generated by nuclear energy-related activities, including spent fuel and waste from reprocessed fuel rods. The work covered by this contract is necessary for producing a defensible model and dataset, and may be critical for evaluation of repository compliance. This work, performed by the Environmental Engineering and Science research group at Stanford University, will quantify the adsorption of uranyl on various minerals. The project's principle objective is to provide sorption coefficients for uranyl and other ions of interest to predict radionuclide movements form the repository to accessible environments. This adsorption data is essential for the unambiguous interpretation of field experiments and observations. In this report, details of the activity and progress made with respect to the study of uranyl adsorption on mineral surfaces is presented and discussed

  15. Fouling of roughened stainless steel surfaces during convective heat transfer to aqueous solutions

    International Nuclear Information System (INIS)

    Herz, A.; Malayeri, M.R.; Mueller-Steinhagen, H.

    2008-01-01

    The deterioration of heat transfer performance due to fouling is the prime cause for higher energy consumption and inefficiency in many industrial heat exchangers such as those in power plants, refineries, food and dairy industries. Fouling is also a very complex process in which many geometrical, physical and operating parameters are involved with poorly understood interaction. Among them, the surface roughness is an important surface characteristic that would greatly influence crystallisation fouling mechanisms and hence deposition morphology and stickability to the surface. In this work, the effect of the surface roughness of AISI 304 BA stainless steel surfaces on fouling of an aqueous solution with inverse solubility behaviour has been investigated under convective heat transfer. Several experiments have been performed on roughened surfaces ranging from 0.18 to 1.55 μm for different bulk concentrations and heat fluxes. The EDTA titration method was used to measure the concentration of the calcium sulphate salt in order to maintain it at constant value during each fouling run. Experimental results show that the heat transfer coefficient of very rough surfaces (1.55 μm) decreases more rapidly than that of 0.54 μm. Several facts contribute to this behaviour notably (1) increased of primary heterogeneous nucleation rate on the surfaces; (2) reduction of local shear stress in the valleys and (3) reduced removal rate of the crystals from the surfaces where the roughness elements protrude out of the viscous sub-layer. The results also show linear and proportional variation of the fouling rate and heat flux within the range of operating conditions. In addition, the deposition process in terms of fouling rate could only be affected at lower surface contact angles. Such results would particularly be of interest for new surface treatment technologies which aim at altering the surface texture

  16. Properties of binary surfactant systems of nonionic surfactants C12E10, C12E23, and C12E42 with a cationic gemini surfactant in aqueous solutions.

    Science.gov (United States)

    Hu, Changchao; Li, Rongqiang; Yang, Hui; Wang, Jinben

    2011-04-15

    Properties of binary surfactant systems of nonionic surfactants poly(ethylene oxide) (PEO) lauryl ethers (C(12)E(10), C(12)E(23), C(12)E(42)) with a cationic gemini surfactant, butanediyl-α,ω-bis(tetradecyldimethylammonium bromide) (14-4-14), have been investigated by Steady-state Fluorescence (FL), zeta potential, Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM), Cryogenic Transmission Electron Microscopy (CryoTEM), and X-ray Diffraction (XRD). Through FL measurements, critical micelle concentration (CMC) of the three binary systems for different mixing mole fractions is determined and the values fall between those of pure constituent surfactants. Ideal CMC (CMC(ideal)), mole fraction in aggregates (X), interaction parameter (β), activity coefficients (f(1) and f(2)), and excess free energy of mixing (ΔG(ex)) have been calculated. All these parameters indicate nonideal behavior and synergistic interactions between the constituent surfactants, which is explained in terms of electrostatic attraction between headgroups of constituent surfactants and reduction of electrostatic repulsion between headgroups of 14-4-14 due to the presence of nonionic surfactants. DLS, TEM and CryoTEM results show that nonionic surfactants facilitate the formation of larger aggregates. Micelles and vesicles in larger size compared with those of 14-4-14 coexist in the mixed solutions. Both surfactant composition and PEO chain length are found to play a strong effect on the properties of the binary systems. Copyright © 2011 Elsevier Inc. All rights reserved.

  17. Anatomy of topological surface states: Exact solutions from destructive interference on frustrated lattices

    Science.gov (United States)

    Kunst, Flore K.; Trescher, Maximilian; Bergholtz, Emil J.

    2017-08-01

    The hallmark of topological phases is their robust boundary signature whose intriguing properties—such as the one-way transport on the chiral edge of a Chern insulator and the sudden disappearance of surface states forming open Fermi arcs on the surfaces of Weyl semimetals—are impossible to realize on the surface alone. Yet, despite the glaring simplicity of noninteracting topological bulk Hamiltonians and their concomitant energy spectrum, the detailed study of the corresponding surface states has essentially been restricted to numerical simulation. In this work, however, we show that exact analytical solutions of both topological and trivial surface states can be obtained for generic tight-binding models on a large class of geometrically frustrated lattices in any dimension without the need for fine-tuning of hopping amplitudes. Our solutions derive from local constraints tantamount to destructive interference between neighboring layer lattices perpendicular to the surface and provide microscopic insights into the structure of the surface states that enable analytical calculation of many desired properties including correlation functions, surface dispersion, Berry curvature, and the system size dependent gap closing, which necessarily occurs when the spatial localization switches surface. This further provides a deepened understanding of the bulk-boundary correspondence. We illustrate our general findings on a large number of examples in two and three spatial dimensions. Notably, we derive exact chiral Chern insulator edge states on the spin-orbit-coupled kagome lattice, and Fermi arcs relevant for recently synthesized slabs of pyrochlore-based Eu2Ir2O7 and Nd2Ir2O7 , which realize an all-in-all-out spin configuration, as well as for spin-ice-like two-in-two-out and one-in-three-out configurations, which are both relevant for Pr2Ir2O7 . Remarkably, each of the pyrochlore examples exhibit clearly resolved Fermi arcs although only the one

  18. Construction of super - hydrophobic copper alloy surface by one - step mixed solution immersion method

    Science.gov (United States)

    Gu, Qiang; Chen, Ying; Chen, Dong; Zhang, Zeting

    2018-01-01

    This paper presents a method for preparing a super hydrophobic surface with a fast, simple, low-cost, one-step reaction by immersing copper alloy in an ethanol solution containing silver nitrate and myristic acid. The effects of reaction time, reaction temperature, reactant concentration and reaction time on the wettability of the material were studied. The surface wettability, appearance, chemical composition, durability and chemical stability of the prepared samples was measured by water contact angle (CA), scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The results show that when the reaction time is only 10min, the surface WCA of the prepared material can reach 154.9. This study provides an effective method for the rapid preparation of stable super hydrophobic surfaces.

  19. Spectrophotometric and conductometric study of the complexation of N-salicylidene-2-aminophenol with Cu2+ in methanol + 1,4-dioxane binary solutions

    Directory of Open Access Journals (Sweden)

    Biswas Rashmidipta

    2014-01-01

    Full Text Available The complexation reaction between N-salicylidene-2-aminophenol, abbreviated as SAP, with Cu2+ ion was studied in binary mixtures of methanol and 1,4-dioxane by using conductometric and spectrophotometric method at different temperatures. The stability constants (Kf for the 1:1 complex, Cu2+-SAP, were calculated from computer fitting of absorbance and molar conductance data against various mole ratios (cM:cL or cL:cM in different binary solvent mixtures. A non-linear behaviour was observed for the variation of logKf for the complex against the solvent compositions. Various thermodynamic parameters (ΔH, ΔS and ΔG for the formation of Cu2+-SAP complex were determined from the temperature dependence of stability constants (Kf. The overall results showed that the complexation reaction is entropy driven and is affected by the nature and composition of the mixed solvents.

  20. (Pressure + volume + temperature) properties for binary oligomeric solutions of poly(ethylene glycol mono-4-octylphenyl ether) with 1-octanol or acetophenone at pressures up to 50 MPa

    International Nuclear Information System (INIS)

    Lee, M.-J.; Ku, T.-J.; Lin Homu

    2009-01-01

    Densities were measured with a high-pressure densitometer for two binary oligomeric systems of poly(ethylene glycol mono-4-octylphenyl ether) (PEGOPE) with 1-octanol or acetophenone at temperatures from 298.15 K to 348.15 K and pressures up to 50 MPa. While the excess volumes are negative in (acetophenone + PEGOPE) over the entire composition range, those are found to change from positive to negative with increasing mole fraction of the solvent in (1-octanol + PEGOPE). The pressure-effect on the liquid densities can be represented accurately by the Tait equation. Moreover, an empirical equation with two characteristic parameters correlates well the PVT data over the entire experimental conditions for each binary system. The experimental specific volumes were also correlated with the Flory-Orwoll-Vrij (FOV) and the Schotte equations of state to within the experimental uncertainty.

  1. Effects of Microporosity and Surface Chemistry on Separation Performances of N-Containing Pitch-Based Activated Carbons for CO2/N2 Binary Mixture

    Science.gov (United States)

    Lee, Min-Sang; Park, Mira; Kim, Hak Yong; Park, Soo-Jin

    2016-03-01

    In this study, N-containing pitch-based activated carbons (NPCs) were prepared using petroleum pitch with a low softening point and melamine with a high nitrogen content. The major advantage of the preparation method is that it enables variations in chemical structures and textural properties by steam activation at high temperatures. The adequate micropore structures, appropriate chemical modifications, and high adsorption enthalpies of NPCs are favorable for CO2 adsorption onto carbon surfaces. Furthermore, the structure generates a considerable gas/N-containing carbon interfacial area, and provides selective access to CO2 molecules over N2 molecules by offering an increased number of active sites on the carbon surfaces. The highest CO2/N2 selectivity, i.e., 47.5, and CO2 adsorption capacity for a CO2/N2 (0.15:0.85) binary gas mixture, i.e., 5.30 wt%, were attained at 298 K. The NPCs also gave reversible and durable CO2-capturing performances. All the results suggest that NPCs are promising CO2 sorbents, which can meet the challenges of current CO2 capture and separation techniques.

  2. Surface characterisation of ethylene-propylene-diene rubber upon exposure to aqueous acidic solution

    DEFF Research Database (Denmark)

    Mitra, S.; Ghanbari-Siahkali, Afshin; Kingshott, P.

    2006-01-01

    but significantly different with respect to molar mass and the presence of long chain branching. Both rubbers contained 5-ethylidene-2-norbomene (ENB) as diene. Solution cast films of pure EPDM samples were exposed in two different acidic solutions, viz. chromosulphuric (Cr (VI)/H2SO4) and sulphuric acid (H2SO4....... Furthermore, 20% Cr (VI)/H2SO4 also attacked the allylic carbon-hydrogen (C-H) bonds of ENB resulting in more oxygenated species on the surface compared to 20% H2SO4 under identical conditions. Cr (VI) in the 20% Cr (VI)/H2SO4 was found to play an important role in alteration of surface chemistry. Studies...

  3. Interactions of Lysozyme and Azobenzene Derivatives in the Solution and on a Surface

    Science.gov (United States)

    Wei, Tao; Shing, Katherine

    2015-03-01

    The reversible isomerization of the azobenzene and its derivatives can control protein structure in an aqueous environment with the alternation of visible and UV lights for very promising applications in drug delivery. However, an atomistic description of Azo-molecules and protein amino acid residues is still lacking. In this study we performed atomistic molecular dynamics simulation to study the interactions between a lysozyme molecule and the Azobenzene derivative (in the bulk solution and grafted on the Silica surfaces). Protein structural arrangements (i.e., the shape and secondary structures) and its mobility, as a function of tran/cis ratio in the bulk solution and on the self-assembling monolayer surface's density and morphology, are systematically investigated.

  4. Three-variable solution in the (2+1)-dimensional null-surface formulation

    Science.gov (United States)

    Harriott, Tina A.; Williams, J. G.

    2018-04-01

    The null-surface formulation of general relativity (NSF) describes gravity by using families of null surfaces instead of a spacetime metric. Despite the fact that the NSF is (to within a conformal factor) equivalent to general relativity, the equations of the NSF are exceptionally difficult to solve, even in 2+1 dimensions. The present paper gives the first exact (2+1)-dimensional solution that depends nontrivially upon all three of the NSF's intrinsic spacetime variables. The metric derived from this solution is shown to represent a spacetime whose source is a massless scalar field that satisfies the general relativistic wave equation and the Einstein equations with minimal coupling. The spacetime is identified as one of a family of (2+1)-dimensional general relativistic spacetimes discovered by Cavaglià.

  5. Temperature duality on Riemann surface and cosmological solutions for genus g = 1 and 2

    International Nuclear Information System (INIS)

    Yan Jun; Wang Shunjin

    1999-01-01

    A bosonic string model at finite temperature on the gravitation g μν and the dilaton φ background field is examined. Moreover, the duality relation of energy momentum tensor on high genus Riemann surface is derived. At the same time, the temperature duality invariance for the action of string gas matter is proved in 4-D Robertson-Walker metric, the string cosmological solutions and temperature duality of the equations of motion for genus g = 1 and 2 are also investigated

  6. Solution of volume-surface integral equations using higher-order hierarchical Legendre basis functions

    DEFF Research Database (Denmark)

    Kim, Oleksiy S.; Meincke, Peter; Breinbjerg, Olav

    2007-01-01

    The problem of electromagnetic scattering by composite metallic and dielectric objects is solved using the coupled volume-surface integral equation (VSIE). The method of moments (MoM) based on higher-order hierarchical Legendre basis functions and higher-order curvilinear geometrical elements...... with the analytical Mie series solution. Scattering by more complex metal-dielectric objects are also considered to compare the presented technique with other numerical methods....

  7. Exceptionally crystalline and conducting acid doped polyaniline films by level surface assisted solution casting approach

    Energy Technology Data Exchange (ETDEWEB)

    Puthirath, Anand B.; Varma, Sreekanth J.; Jayalekshmi, S., E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Cochin, Kerala 682022 (India); Methattel Raman, Shijeesh [Nanophotonic and Optoelectronic Devices Laboratory, Department of Physics, Cochin University of Science and Technology, Cochin, Kerala 682022 (India)

    2016-04-18

    Emeraldine salt form of polyaniline (PANI) was synthesized by chemical oxidative polymerisation method using ammonium persulfate as oxidant. Resultant emeraldine salt form of PANI was dedoped using ammonia solution and then re-doped with camphor sulphonic acid (CSA), naphthaline sulphonic acid (NSA), hydrochloric acid (HCl), and m-cresol. Thin films of these doped PANI samples were deposited on glass substrates using solution casting method with m-cresol as solvent. A level surface was employed to get homogeneous thin films of uniform thickness. Detailed X-ray diffraction studies have shown that the films are exceptionally crystalline. The crystalline peaks observed in the XRD spectra can be indexed to simple monoclinic structure. FTIR and Raman spectroscopy studies provide convincing explanation for the exceptional crystallinity observed in these polymer films. FESEM and AFM images give better details of surface morphology of doped PANI films. The DC electrical conductivity of the samples was measured using four point probe technique. It is seen that the samples also exhibit quite high DC electrical conductivity, about 287 S/cm for CSA doped PANI, 67 S/cm for NSA doped PANI 65 S/cm for HCl doped PANI, and just below 1 S/cm for m-cresol doped PANI. Effect of using the level surface for solution casting is studied and correlated with the observed crystallinity.

  8. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  9. Oxidation and etching behaviors of the InAs surface in various acidic and basic chemical solutions

    Science.gov (United States)

    Na, Jihoon; Lee, Seunghyo; Lim, Sangwoo

    2017-04-01

    Indium arsenide (InAs) is the candidate of choice as a new channel material for application in future technologies beyond the Si-based electronic devices because it has a much higher electron mobility than silicon. In this study, the oxidation and etching behaviors of InAs (100) in various acidic and basic solutions, such as HF, HCl, H2SO4, NaOH, KOH, and NH4OH, were investigated. In addition, the effect of pH on the oxidation and etching reactions taking place on the InAs surface was studied using solutions with a pH ranging from 1 to 13. It was observed that the oxidation of the InAs surface was hindered in acidic solutions, which was attributed to the dissolution of the oxidized surface layer. In particular, the treatment of the InAs surface using a strongly acidic solution with a pH of less than 3 produced an oxide-free surface due to the predominant etching of the InAs surface. The addition of H2O2 to the acidic solutions greatly increased the etching rate of the InAs surface, which suggests that the oxidation process is the rate-limiting step in the sequence of reactions that occur during the etching of the InAs surface in acidic solutions. The etching of InAs was suppressed in neutral solutions, which resulted in the formation of a relatively thicker oxide layer on the surface, and mild etching of the InAs surface took place in basic solutions. However, in basic solutions, the addition of H2O2 did not significantly contribute to the increase of the oxidation state of the InAs surface; thus, its effect on the etching rate of InAs was smaller than in acidic solutions.

  10. Solution electrostatic levitator for measuring surface properties and bulk structures of an extremely supersaturated solution drop above metastable zone width limit

    Science.gov (United States)

    Lee, Sooheyong; Jo, Wonhyuk; Cho, Yong chan; Lee, Hyun Hwi; Lee, Geun Woo

    2017-05-01

    We report on the first integrated apparatus for measuring surface and thermophysical properties and bulk structures of a highly supersaturated solution by combining electrostatic levitation with real-time laser/x-ray scattering. Even today, a proper characterization of supersaturated solutions far above their solubility limits is extremely challenging because heterogeneous nucleation sites such as container walls or impurities readily initiate crystallization before the measurements can be performed. In this work, we demonstrate simultaneous measurements of drying kinetics and surface tension of a potassium dihydrogen phosphate (KH2PO4) aqueous solution droplet and its bulk structural evolution beyond the metastable zone width limit. Our experimental finding shows that the noticeable changes of the surface properties are accompanied by polymerizations of hydrated monomer clusters. The novel electrostatic levitation apparatus presented here provides an effective means for studying a wide range of highly concentrated solutions and liquids in deep metastable states.

  11. Parametric binary dissection

    Science.gov (United States)

    Bokhari, Shahid H.; Crockett, Thomas W.; Nicol, David M.

    1993-01-01

    Binary dissection is widely used to partition non-uniform domains over parallel computers. This algorithm does not consider the perimeter, surface area, or aspect ratio of the regions being generated and can yield decompositions that have poor communication to computation ratio. Parametric Binary Dissection (PBD) is a new algorithm in which each cut is chosen to minimize load + lambda x(shape). In a 2 (or 3) dimensional problem, load is the amount of computation to be performed in a subregion and shape could refer to the perimeter (respectively surface) of that subregion. Shape is a measure of communication overhead and the parameter permits us to trade off load imbalance against communication overhead. When A is zero, the algorithm reduces to plain binary dissection. This algorithm can be used to partition graphs embedded in 2 or 3-d. Load is the number of nodes in a subregion, shape the number of edges that leave that subregion, and lambda the ratio of time to communicate over an edge to the time to compute at a node. An algorithm is presented that finds the depth d parametric dissection of an embedded graph with n vertices and e edges in O(max(n log n, de)) time, which is an improvement over the O(dn log n) time of plain binary dissection. Parallel versions of this algorithm are also presented; the best of these requires O((n/p) log(sup 3)p) time on a p processor hypercube, assuming graphs of bounded degree. How PBD is applied to 3-d unstructured meshes and yields partitions that are better than those obtained by plain dissection is described. Its application to the color image quantization problem is also discussed, in which samples in a high-resolution color space are mapped onto a lower resolution space in a way that minimizes the color error.

  12. Silver deposition on stainless steel container surfaces in contact with disinfectant silver aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Petala, M., E-mail: petala@civil.auth.gr [Department of Civil Engineering, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Tsiridis, V. [Department of Civil Engineering, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Mintsouli, I. [Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Pliatsikas, N. [Department of Physics, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Spanos, Th. [Department of Petroleum and Mechanical Engineering Sciences, Eastern Macedonia and Thrace Institute of Technology, Kavala, 65404 (Greece); Rebeyre, P. [ESA/ESTEC, P.O.Box 299, 2200 AG, Noordwijk (Netherlands); Darakas, E. [Department of Civil Engineering, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Patsalas, P.; Vourlias, G. [Department of Physics, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece); Kostoglou, M.; Sotiropoulos, S.; Karapantsios, Th. [Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, 54124 (Greece)

    2017-02-28

    Highlights: • Silver is one of the biocides of water consumed in the International Space Station. • Ionic silver is depleted from potable water when in contact with stainless steel (SS). • SEM and XPS analysis reveal a uniform silver deposition over the SS surface. • Silver deposits in its metallic form, in line with a galvanic deposition mechanism. • Evidence is provided that Cr and/ or Ni oxide builds-up on SS surfaces. - Abstract: Silver is the preservative used on the Russian segment of the International Space Station (ISS) to prevent microbial proliferation within potable water supplies. Yet, in the frame of the European Automated Transfer Vehicle (ATV) missions to ISS, silver depletion from water has been detected during ground transportation of this water to launch site, thereby indicating a degradation of water quality. This study investigates the silver loss from water when in contact with stainless steel surfaces. Experiments are conducted with several types of stainless steel surfaces being exposed to water containing 10 or 0.5 mg/L silver ions. Results show that silver deposits on stainless steel surfaces even when a passivation layer protects the metallic surface. The highest protection to silver deposition is offered by acid passivated and electropolished SS 316L. SEM and XPS experiments were carried out at several locations of the sample area that was in contact with the Ag solution and found similar morphological (SEM) and compositional (sputter-etch XPS) results. The results reveal that silver deposits uniformly across the wetted surface to a thickness larger than 3 nm. Moreover, evidence is provided that silver deposits in its metallic form on all stainless steel surfaces, in line with a galvanic deposition mechanism. Combination of ICP-MS and XPS results suggests a mechanism for Ag deposition/reduction with simultaneous substrate oxidation resulting in oxide growth at the exposed stainless steel surface.

  13. Silver deposition on stainless steel container surfaces in contact with disinfectant silver aqueous solutions

    International Nuclear Information System (INIS)

    Petala, M.; Tsiridis, V.; Mintsouli, I.; Pliatsikas, N.; Spanos, Th.; Rebeyre, P.; Darakas, E.; Patsalas, P.; Vourlias, G.; Kostoglou, M.; Sotiropoulos, S.; Karapantsios, Th.

    2017-01-01

    Highlights: • Silver is one of the biocides of water consumed in the International Space Station. • Ionic silver is depleted from potable water when in contact with stainless steel (SS). • SEM and XPS analysis reveal a uniform silver deposition over the SS surface. • Silver deposits in its metallic form, in line with a galvanic deposition mechanism. • Evidence is provided that Cr and/ or Ni oxide builds-up on SS surfaces. - Abstract: Silver is the preservative used on the Russian segment of the International Space Station (ISS) to prevent microbial proliferation within potable water supplies. Yet, in the frame of the European Automated Transfer Vehicle (ATV) missions to ISS, silver depletion from water has been detected during ground transportation of this water to launch site, thereby indicating a degradation of water quality. This study investigates the silver loss from water when in contact with stainless steel surfaces. Experiments are conducted with several types of stainless steel surfaces being exposed to water containing 10 or 0.5 mg/L silver ions. Results show that silver deposits on stainless steel surfaces even when a passivation layer protects the metallic surface. The highest protection to silver deposition is offered by acid passivated and electropolished SS 316L. SEM and XPS experiments were carried out at several locations of the sample area that was in contact with the Ag solution and found similar morphological (SEM) and compositional (sputter-etch XPS) results. The results reveal that silver deposits uniformly across the wetted surface to a thickness larger than 3 nm. Moreover, evidence is provided that silver deposits in its metallic form on all stainless steel surfaces, in line with a galvanic deposition mechanism. Combination of ICP-MS and XPS results suggests a mechanism for Ag deposition/reduction with simultaneous substrate oxidation resulting in oxide growth at the exposed stainless steel surface.

  14. Novel quantum inspired binary neural network algorithm

    Indian Academy of Sciences (India)

    In this paper, a quantum based binary neural network algorithm is proposed, named as novel quantum binary neural network algorithm (NQ-BNN). It forms a neural network structure by deciding weights and separability parameter in quantum based manner. Quantum computing concept represents solution probabilistically ...

  15. ANALYTICAL SOLUTION FOR WAVES IN PLANETS WITH ATMOSPHERIC SUPERROTATION. II. LAMB, SURFACE, AND CENTRIFUGAL WAVES

    Energy Technology Data Exchange (ETDEWEB)

    Peralta, J.; López-Valverde, M. A. [Instituto de Astrofísica de Andalucía (CSIC), Glorieta de la Astronomía, 18008 Granada (Spain); Imamura, T. [Institute of Space and Astronautical Science-Japan Aerospace Exploration Agency 3-1-1, Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Read, P. L. [Clarendon Laboratory, Department of Physics, University of Oxford, Parks Road, Oxford (United Kingdom); Luz, D. [Centro de Astronomia e Astrofísica da Universidade de Lisboa (CAAUL), Observatório Astronómico de Lisboa, Tapada da Ajuda, 1349-018 Lisboa (Portugal); Piccialli, A., E-mail: peralta@iaa.es [LATMOS, UVSQ, 11 bd dAlembert, 78280 Guyancourt (France)

    2014-07-01

    This paper is the second in a two-part study devoted to developing tools for a systematic classification of the wide variety of atmospheric waves expected on slowly rotating planets with atmospheric superrotation. Starting with the primitive equations for a cyclostrophic regime, we have deduced the analytical solution for the possible waves, simultaneously including the effect of the metric terms for the centrifugal force and the meridional shear of the background wind. In those cases where the conditions for the method of the multiple scales in height are met, these wave solutions are also valid when vertical shear of the background wind is present. A total of six types of waves have been found and their properties were characterized in terms of the corresponding dispersion relations and wave structures. In this second part, we study the waves' solutions when several atmospheric approximations are applied: Lamb, surface, and centrifugal waves. Lamb and surface waves are found to be quite similar to those in a geostrophic regime. By contrast, centrifugal waves turn out to be a special case of Rossby waves that arise in atmospheres in cyclostrophic balance. Finally, we use our results to identify the nature of the waves behind atmospheric periodicities found in polar and lower latitudes of Venus's atmosphere.

  16. Use of 3-aminopropyltriethoxysilane deposited from aqueous solution for surface modification of III-V materials

    International Nuclear Information System (INIS)

    Knorr Jr, Daniel B.; Williams, Kristen S.; Baril, Neil F.; Weiland, Conan; Andzelm, Jan W.; Lenhart, Joseph L.; Woicik, Joseph C.; Fischer, Daniel A.; Tidrow, Meimei Z.; Bandara, Sumith V.; Henry, Nathan C.

    2014-01-01

    Graphical abstract: - Highlights: • HCl and citric acid showed excellent oxide removal on III/V surfaces. • Aminosilane (APTES) passivation coatings were deposited at 1–20 nm on InAs and GaSb. • These coatings showed high ionic nitrogen levels near the interface via XPS. • DFT was used to find adsorption energies of APTES with and without -OH groups. • DFT modeling showed APTES–NH 3 + hydrogen abstraction to form surface -OH groups. - Abstract: Focal plane arrays of strained layer superlattices (SLSs) composed of InAs/GaSb are excellent candidates for infrared imaging, but one key factor limiting their utility is the lack of a surface passivation technique capable of protecting the mesa sidewall from degradation. Along these lines, we demonstrate the use of aqueous 3-aminopropyl triethoxysilane (APTES) deposited as a surface functionalizing agent for subsequent polymer passivation on InAs and GaSb surfaces following a HCl/citric acid procedure to remove the conductive oxide In 2 O 3 . Using atomic force microscopy, variable angle spectroscopic ellipsometry, X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS), and modeling with density functional theory (DFT), we demonstrate that APTES films can successfully be deposited on III-V substrates by spin coating and directly compare these films to those deposited on silicon substrates. The HCl/citric acid surface preparation treatment is particularly effective at removing In 2 O 3 without the surface segregation of In oxides observed from use of HCl alone. However, HCl/citric acid surface treatment method does result in heavy oxidation of both Ga and Sb, accompanied by segregation of Ga oxide to the surface. Deposited APTES layer thickness did not depend on the substrate choice, and thicknesses between 1 and 20 nm were obtained for APTES solution concentrations ranging from 0.1 to 2.5 vol %. XPS results for the N1s band of APTES showed that the content of ionic nitrogen

  17. Use of 3-aminopropyltriethoxysilane deposited from aqueous solution for surface modification of III-V materials

    Energy Technology Data Exchange (ETDEWEB)

    Knorr Jr, Daniel B., E-mail: daniel.knorr.civ@mail.mil [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Williams, Kristen S. [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Baril, Neil F. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Weiland, Conan [National Institute of Standards and Technology, Gaithersburg, MD 20899, United States of America (United States); Andzelm, Jan W. [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Lenhart, Joseph L., E-mail: joseph.l.lenhart.civ@mail.mil [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Woicik, Joseph C.; Fischer, Daniel A. [National Institute of Standards and Technology, Gaithersburg, MD 20899, United States of America (United States); Tidrow, Meimei Z.; Bandara, Sumith V. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Henry, Nathan C. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Corbin Company, Alexandria, VA 22314, United States of America (United States)

    2014-11-30

    Graphical abstract: - Highlights: • HCl and citric acid showed excellent oxide removal on III/V surfaces. • Aminosilane (APTES) passivation coatings were deposited at 1–20 nm on InAs and GaSb. • These coatings showed high ionic nitrogen levels near the interface via XPS. • DFT was used to find adsorption energies of APTES with and without -OH groups. • DFT modeling showed APTES–NH{sub 3}{sup +} hydrogen abstraction to form surface -OH groups. - Abstract: Focal plane arrays of strained layer superlattices (SLSs) composed of InAs/GaSb are excellent candidates for infrared imaging, but one key factor limiting their utility is the lack of a surface passivation technique capable of protecting the mesa sidewall from degradation. Along these lines, we demonstrate the use of aqueous 3-aminopropyl triethoxysilane (APTES) deposited as a surface functionalizing agent for subsequent polymer passivation on InAs and GaSb surfaces following a HCl/citric acid procedure to remove the conductive oxide In{sub 2}O{sub 3}. Using atomic force microscopy, variable angle spectroscopic ellipsometry, X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS), and modeling with density functional theory (DFT), we demonstrate that APTES films can successfully be deposited on III-V substrates by spin coating and directly compare these films to those deposited on silicon substrates. The HCl/citric acid surface preparation treatment is particularly effective at removing In{sub 2}O{sub 3} without the surface segregation of In oxides observed from use of HCl alone. However, HCl/citric acid surface treatment method does result in heavy oxidation of both Ga and Sb, accompanied by segregation of Ga oxide to the surface. Deposited APTES layer thickness did not depend on the substrate choice, and thicknesses between 1 and 20 nm were obtained for APTES solution concentrations ranging from 0.1 to 2.5 vol %. XPS results for the N1s band of APTES showed that

  18. Topography evolution of rough-surface metallic substrates by solution deposition planarization method

    Science.gov (United States)

    Chu, Jingyuan; Zhao, Yue; Liu, Linfei; Wu, Wei; Zhang, Zhiwei; Hong, Zhiyong; Li, Yijie; Jin, Zhijian

    2018-01-01

    As an emerging technique for surface smoothing, solution deposition planarization (SDP) has recently drawn more attention on the fabrication of the second generation high temperature superconducting (2G-HTS) tapes. In our work, a number of amorphous oxide layers were deposited on electro-polished or mirror-rolled metallic substrates by chemical solution route. Topography evolution of surface defects on these two types of metallic substrates was thoroughly investigated by atomic force microscopy (AFM). It was showed that root mean square roughness values (at 50 × 50 μm2 scanning scale) on both rough substrates reduced to ∼5 nm after coating with SDP-layer. The smoothing effect was mainly attributed to decrease of the depth at grain boundary grooving on the electro-polished metallic substrate. On the mirror-rolled metallic substrates, the amplitude and frequency of the height fluctuation perpendicular to the rolling direction were gradually reduced as depositing more numbers of SDP-layer. A high Jc value of 4.17 MA cm-2 (at 77 K, s.f.) was achieved on a full stack of YBCO/CeO2/IBAD-MgO/SDP-layer/C276 sample. This study enhanced understanding of the topography evolution on the surface defects covered by the SDP-layer, and demonstrated a low-cost route for fabricating IBAD-MgO based YBCO templates with a simplified architecture.

  19. Redox-triggered mixing and demixing of surfactants within assemblies formed in solution and at surfaces.

    Science.gov (United States)

    Smith, Timothy J; Wang, Chenxuan; Abbott, Nicholas L

    2017-09-15

    We report experiments that test the hypothesis that redox-triggered changes in the architectures of surfactants permit control of mixing of surfactants within assemblies. Specifically, we describe surface tension, light scattering, atomic force microscopy, and quartz crystal microbalance measurements that characterize the redox-dependent behaviors of cationic surfactants with a ferrocene group located either at the surfactant terminus (11-ferrocenylundecyl-trimethylammonium bromide; FTMA) or head (N,N-dimethylferrocenylmethyldecylammonium bromide; DMFA). In bulk solution, we find that reduced and oxidized FTMA do not mix within micellar assemblies but that reduced and oxidized DMFA do form mixed micelles. Because oxidized FTMA has the architecture of a bolaform surfactant whereas oxidized DMFA has a conventional surfactant architecture with a divalent head group, these results suggest that redox-triggered changes in molecular architecture permit control of the extent of mixing of surfactants in micellar assemblies in bulk solution. This conclusion receives further support from measurements performed with mixtures of dodecyltrimethylammonium bromide and FTMA, with FTMA in either reduced or oxidized states, and was found to extend to hemimicellar assemblies formed at hydrophobic solid surfaces but not to mixed monolayers formed at the surface of water. The latter is attributed to differences in the conformations of surfactants within monolayers and micellar assemblies. Overall, these results provide insight into the design of surfactant assemblies within which mixing can be controlled reversibly using redox processes. Copyright © 2017 Elsevier Inc. All rights reserved.

  20. Thermodynamic Stability of Actinide-Dioxide Solid Solutions and Surface Interactions with Water

    Science.gov (United States)

    Asta, Mark

    2012-02-01

    Fluorite-structured actinide dioxides are the most common forms of fuel used in nuclear energy production worldwide. This talk will provide an overview of insights into the energetics of these compounds derived through the combination of density-functional-theory-based computational studies (including Hubbard-U corrections) and calorimetric measurements. The talk will focus on two main topics: the mixing energetics of cation solid solutions, and the energetics of water adsorption on the surfaces of these compounds. For the first topic, we present results for ThO2 and UO2 based solid solutions, highlighting the roles of elastic energy arising from cation size mismatch, electrostatic interactions, and charge-transfer reactions, in governing the sign and magnitude of the mixing energetics. For water adsorption, we contrast results for surface and adsorption energies on two fluorite-structured compounds, ThO2 and CeO2, that are relevant for understanding the behavior of water on actinide oxide surfaces more generally. Through a comparison between calorimetric measurements and computational results we assess the level of accuracy achieved in the computational modeling, and suggest areas where further experimental studies would be particularly useful.

  1. Study of surface potential contamination in radioisotope and radiopharmaceutical production facilities and alternative solutions

    International Nuclear Information System (INIS)

    Suhaedi Muhammad; Rimin Sumantri; Farida Tusafariah; Djarwanti Rahayu Pipin Soedjarwo

    2013-01-01

    Radioisotope and radiopharmaceutical production facilities that exist in their operations around the world in the form of radiological impacts of radiation exposure, contamination of surface and air contamination. Given the number of existing open source in radioisotope and radiopharmaceutical production facility, then the possibility of surface contamination in the work area is quite high. For that to protect the safety and health of both workers, the public and the environment, then the licensee must conduct an inventory of some of the potential that could result in contamination of surfaces in radioisotope and radiopharmaceutical production facilities. Several potential to cause surface contamination in radioisotope and radiopharmaceutical production facilities consist of loss of resources, the VAC system disorders, impaired production facilities, limited resources and lack of work discipline and radioactive waste handling activities. From the study of some potential, there are several alternative solutions that can be implemented by the licensee to address the contamination of the surface so as not to cause adverse radiological impacts for both radiation workers, the public or the environment. (author)

  2. Modeling surface disinfection kinetics of fresh tomato (Lycopersicum esculentum using chlorine solutions

    Directory of Open Access Journals (Sweden)

    Miguel Ángel Solano Cornejo

    2013-03-01

    Full Text Available Fresh tomatoes Italian variety were subjected to surface disinfection processes using calcium hypochlorite solutions to determine their germicidal efficiency and kinetics that governs the surface inactivation process in aerobic mesophilic bacteria, yeasts and molds. Chlorine as surface disinfectant was effective against aerobic mesophilic bacteria, yeasts and molds in this order, the resistance of aerobic mesophilic bacteria, yeasts and molds of their values expressed in zchlorine was 455, 500 and 625 ppm respectively. Aerobic mesophilic bacteria present in the tomato surface show a higher resistance to chlorine disinfection according contact time germtomato skin is greater due to a better adherence to the tomato skin making it difficult for the action of chlorine on germs; this effect is not present in the case of yeasts or molds. Experimental Dchlorine 20°C values and Dchlorine_20°C values predicted by the First Bigelow’s Model were fit with a correlation of between 0.91 and 0.99. The experimental zchlorine values and values zchlorine predicted by the Second Bigelow’s Model were adjusted with a correlation of 0.72 to 0.86. The variability in the values zchlorine was because germs analyzed to validate the proposed model were composed of various genera. So, the Bigelow’s Method applied to inactivation kinetics of surface chlorine was validated.

  3. Studies on deposition of gadolinium from its nitrate solution of zircaloy-2 surfaces

    International Nuclear Information System (INIS)

    Shah, G.C.; Unny, V.K.P.; Vartak, D.G.

    1981-01-01

    Gadolinium nitrate solution (25000 ppm) is proposed as a neutron poison in tertiary shut down system of R-5 reactor at Trombay, Bombay. The gadolinium nitrate solution when in contact with the zircaloy tube can get deposited and thus, affect the reactivity of the reactor during operation. Experiments were conducted to evaluate the rate of deposition of gadolinium on zircaloy-2 surfaces at various temperatures and at different periods of time. Studies were also conducted to determine the deposition of gadolinium when exposed to various 60 Co γ-ray irradiation doses. The studies indicated that deposition of gadolinium increases with increase in temperature while there was no increase in rate of deposition by 60 Co γ-ray irradiation upto 440 Mrads. (author)

  4. An algorithm for analytical solution of basic problems featuring elastostatic bodies with cavities and surface flaws

    Science.gov (United States)

    Penkov, V. B.; Levina, L. V.; Novikova, O. S.; Shulmin, A. S.

    2018-03-01

    Herein we propose a methodology for structuring a full parametric analytical solution to problems featuring elastostatic media based on state-of-the-art computing facilities that support computerized algebra. The methodology includes: direct and reverse application of P-Theorem; methods of accounting for physical properties of media; accounting for variable geometrical parameters of bodies, parameters of boundary states, independent parameters of volume forces, and remote stress factors. An efficient tool to address the task is the sustainable method of boundary states originally designed for the purposes of computerized algebra and based on the isomorphism of Hilbertian spaces of internal states and boundary states of bodies. We performed full parametric solutions of basic problems featuring a ball with a nonconcentric spherical cavity, a ball with a near-surface flaw, and an unlimited medium with two spherical cavities.

  5. Fast Adsorption of Soft Hydrogel Microspheres on Solid Surfaces in Aqueous Solution.

    Science.gov (United States)

    Matsui, Shusuke; Kureha, Takuma; Hiroshige, Seina; Shibata, Mikihiro; Uchihashi, Takayuki; Suzuki, Daisuke

    2017-09-25

    The real-time adsorption behavior of polymeric colloidal microspheres onto solid surfaces in aqueous solution was visualized for the first time using high-speed atomic force microscopy (HS-AFM) to reveal how the softness of the microspheres affects their dynamic adsorption. Studies that focus on the deformability of microspheres upon dynamic adsorption have not yet been reported, most likely on account of a lack of techniques that appropriately depict the dynamic adsorption and deformation behavior of individual microspheres at the nanoscale in real time. In this study, the deformability of microspheres plays a crucial role on the adsorption kinetics, that is, soft hydrogel microspheres adsorb faster than harder elastomeric or rigid microspheres. These results should provide insight towards development of new colloidal nanomaterials that exhibit effective adsorption on specific sites in aqueous solution. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Investigation of ALEGRA shock hydrocode algorithms using an exact free surface jet flow solution.

    Energy Technology Data Exchange (ETDEWEB)

    Hanks, Bradley Wright.; Robinson, Allen C

    2014-01-01

    Computational testing of the arbitrary Lagrangian-Eulerian shock physics code, ALEGRA, is presented using an exact solution that is very similar to a shaped charge jet flow. The solution is a steady, isentropic, subsonic free surface flow with significant compression and release and is provided as a steady state initial condition. There should be no shocks and no entropy production throughout the problem. The purpose of this test problem is to present a detailed and challenging computation in order to provide evidence for algorithmic strengths and weaknesses in ALEGRA which should be examined further. The results of this work are intended to be used to guide future algorithmic improvements in the spirit of test-driven development processes.

  7. Temperature dependence of the surface enhanced raman spectroelectrochemistry of iron in aqueous solutions.

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, L. J.; Melendres, C. A.; Chemical Engineering

    1996-06-01

    The effect of temperature on the composition of the corrosion film on iron in aqueous sodium hydroxide and borate solutions was investigated using surface enhanced Raman spectroelectrochemistry (SERS). Fe(OH){sub 2} and Fe{sub 3}O{sub 4} were observed in the prepassivation region, while Fe{sub 3}O{sub 4} and FeOOH accounted for most of the passivated film at 25, 60 and 95 C. Fe(OH){sub 2} was found to be a stable component of the corrosion film on iron at 95 C, which is contrary to recently published theoretical calculations.

  8. Weakly Hydrated Surfaces and the Binding Interactions of Small Biological Solutes

    Energy Technology Data Exchange (ETDEWEB)

    Brady, J. W.; Tavagnacco, L.; Ehrlich, L.; Chen, M.; Schnupf, U.; Himmel, M. E.; Saboungi, M. L.; Cesaro, A.

    2012-04-01

    Extended planar hydrophobic surfaces, such as are found in the side chains of the amino acids histidine, phenylalanine, tyrosine, and tryptophan, exhibit an affinity for the weakly hydrated faces of glucopyranose. In addition, molecular species such as these, including indole, caffeine, and imidazole, exhibit a weak tendency to pair together by hydrophobic stacking in aqueous solution. These interactions can be partially understood in terms of recent models for the hydration of extended hydrophobic faces and should provide insight into the architecture of sugar-binding sites in proteins.

  9. Surface decoration and dispersibility of carbon nanofibers in aqueous surfactant solution

    Science.gov (United States)

    Wang, B. M.; Zhang, Y.; Liu, S.

    2014-03-01

    As a novel functional nanomaterial, the dispersion effect of carbon nanofibers (CNFs) has a significant influence on the application of CNFs in the composites. Two effective surfactants, methylcellulose (MC) and polycarboxylate superplasticizer, were used to analyze the dispersion of CNFs in aqueous solution. A method utilizing ultrasonic processing was employed to achieve a homogenous CNF suspension, and the dispersion effect was further characterized by the method of measuring ultraviolet absorbency (UV absorbency), zeta potential, surface tension and transmission electron microscopy (TEM) micrographs. The results show that the zeta potential and surface tension reach the saturation plateau at MC concentration and polycarboxylate superplasticizer concentration of about 0.4 and 0.8 g/L, respectively, which reflects that the optimum concentration ratio of MC to CNFs is 2: 1, and the optimum dispersing polycarboxylate superplasticizer to CNFs ratio of 4: 1 is required to achieve dispersions with maximum achievable dispersion of CNFs.

  10. Anisotropic surface hole-transport property of triphenylamine-derivative single crystal prepared by solution method

    Energy Technology Data Exchange (ETDEWEB)

    Umeda, Minoru, E-mail: mumeda@vos.nagaokaut.ac.jp [Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Katagiri, Mitsuhiko; Shironita, Sayoko [Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nagayama, Norio [Nagaoka University of Technology, Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Ricoh Company, Ltd., Nishisawada, Numazu, Shizuoka 410-0007 (Japan)

    2016-12-01

    Highlights: • A hole transport molecule was investigated based on its electrochemical redox characteristics. • The solubility and supersolubility curves of the molecule were measured in order to prepare a large crystal. • The polarization micrograph and XRD results revealed that a single crystal was obtained. • An anisotropic surface conduction, in which the long-axis direction exceeds that of the amorphous layer, was observed. • The anisotropic surface conduction was well explained by the molecular stacked structure. - Abstract: This paper reports the anisotropic hole transport at the triphenylamine-derivative single crystal surface prepared by a solution method. Triphenylamine derivatives are commonly used in a hole-transport material for organic photoconductors of laser-beam printers, in which the materials are used as an amorphous form. For developing organic photovoltaics using the photoconductor’s technology, preparation of a single crystal seems to be a specific way by realizing the high mobility of an organic semiconductor. In this study, a single crystal of 4-(2,2-diphenylethenyl)-N,N-bis(4-methylphenyl)-benzenamine (TPA) was prepared and its anisotropic hole-transport property measured. First, the hole-transport property of the TPA was investigated based on its chemical structure and electrochemical redox characteristics. Next, a large-scale single crystal formation at a high rate was developed by employing a solution method based on its solubility and supersolubility curves. The grown TPA was found to be a single crystal based on the polarization micrograph observation and crystallographic analysis. For the TPA single crystal, an anisotropic surface conduction was found, which was well explained by its molecular stack structure. The measured current in the long-axis direction is one order of magnitude greater than that of amorphous TPA.

  11. Solutal Marangoni flows of miscible liquids drive transport without surface contamination

    Science.gov (United States)

    Kim, Hyoungsoo; Muller, Koen; Shardt, Orest; Afkhami, Shahriar; Stone, Howard A.

    2017-11-01

    Mixing and spreading of different liquids are omnipresent in nature, life and technology, such as oil pollution on the sea, estuaries, food processing, cosmetic and beverage industries, lab-on-a-chip devices, and polymer processing. However, the mixing and spreading mechanisms for miscible liquids remain poorly characterized. Here, we show that a fully soluble liquid drop deposited on a liquid surface remains as a static lens without immediately spreading and mixing, and simultaneously a Marangoni-driven convective flow is generated, which are counterintuitive results when two liquids have different surface tensions. To understand the dynamics, we develop a theoretical model to predict the finite spreading time and length scales, the Marangoni-driven convection flow speed, and the finite timescale to establish the quasi-steady state for the Marangoni flow. The fundamental understanding of this solutal Marangoni flow may enable driving bulk flows and constructing an effective drug delivery and surface cleaning approach without causing surface contamination by immiscible chemical species.

  12. Real surface area of the aluminium electrode in sodium chloride solution

    Directory of Open Access Journals (Sweden)

    Z. RAKOCEVIC

    1999-11-01

    Full Text Available By combining the techniques of electrochemical slow potentiodynamic, AC impedance and atomic force microscopy (AFM, it was shown that the differences in the anodic dissolution rates of Al in 0.5 NaCl solutions as measured experimentally in the potential region between the corrosion and pitting potential, are mainly due to differences in surface roughness of the electrodes used. It was shown that mechanical grinding and polishing of the electrode surface with emery paper (400 grit and alumina polishing powder (f 0.25 mm can produce surfaces differing by a factor of 6 in the roughness factor Ra. By using AFM estimates of the roughness factors a true electrode capacitance of 4.63 µC cm-2 and thickness dox ~ 2.0 nm for the barrier layer of the surface film was estamited. The outer part of the film is porous, partly as amorphous Al(OH3, or crystalline bayerite (Al2O3.3H2O.

  13. Removal of methylene blue from aqueous solution by wood millet carbon optimization using response surface methodology

    Science.gov (United States)

    Ghaedi, Mehrorang; Kokhdan, Syamak Nasiri

    2015-02-01

    The use of cheep, non-toxic, safe and easily available adsorbent are efficient and recommended material and alternative to the current expensive substance for pollutant removal from wastewater. The activated carbon prepared from wood waste of local tree (millet) extensively was applied for quantitative removal of methylene blue (MB), while simply. It was used to re-used after heating and washing with alkaline solution of ethanol. This new adsorbent was characterized by using BET surface area measurement, FT-IR, pH determination at zero point of charge (pHZPC) and Boehm titration method. Response surface methodology (RSM) by at least the number of experiments main and interaction of experimental conditions such as pH of solution, contact time, initial dye concentration and adsorbent dosage was optimized and set as pH 7, contact time 18 min, initial dye concentration 20 ppm and 0.2 g of adsorbent. It was found that variable such as pH and amount of adsorbent as solely or combination effects seriously affect the removal percentage. The fitting experimental data with conventional models reveal the applicability of isotherm models Langmuir model for their well presentation and description and Kinetic real rate of adsorption at most conditions efficiently can be represented pseudo-second order, and intra-particle diffusion. It novel material is good candidate for removal of huge amount of MB (20 ppm) in short time (18 min) by consumption of small amount (0.2 g).

  14. The illusion of specific capture: surface and solution studies of suboptimal oligonucleotide hybridization

    Science.gov (United States)

    2013-01-01

    Background Hybridization based assays and capture systems depend on the specificity of hybridization between a probe and its intended target. A common guideline in the construction of DNA microarrays, for instance, is that avoiding complementary stretches of more than 15 nucleic acids in a 50 or 60-mer probe will eliminate sequence specific cross-hybridization reactions. Here we present a study of the behavior of partially matched oligonucleotide pairs with complementary stretches starting well below this threshold complementarity length – in silico, in solution, and at the microarray surface. The modeled behavior of pairs of oligonucleotide probes and their targets suggests that even a complementary stretch of sequence 12 nt in length would give rise to specific cross-hybridization. We designed a set of binding partners to a 50-mer oligonucleotide containing complementary stretches from 6 nt to 21 nt in length. Results Solution melting experiments demonstrate that stable partial duplexes can form when only 12 bp of complementary sequence are present; surface hybridization experiments confirm that a signal close in magnitude to full-strength signal can be obtained from hybridization of a 12 bp duplex within a 50mer oligonucleotide. Conclusions Microarray and other molecular capture strategies that rely on a 15 nt lower complementarity bound for eliminating specific cross-hybridization may not be sufficiently conservative. PMID:23445545

  15. Regulating urban surface runoff through nature-based solutions - An assessment at the micro-scale.

    Science.gov (United States)

    Zölch, Teresa; Henze, Lisa; Keilholz, Patrick; Pauleit, Stephan

    2017-08-01

    Urban development leads to changes of surface cover that disrupt the hydrological cycle in cities. In particular, impermeable surfaces and the removal of vegetation reduce the ability to intercept, store and infiltrate rainwater. Consequently, the volume of stormwater runoff and the risk of local flooding rises. This is further amplified by the anticipated effects of climate change leading to an increased frequency and intensity of heavy rain events. Hence, urban adaptation strategies are required to mitigate those impacts. A nature-based solution, more and more promoted in politics and academia, is urban green infrastructure as it contributes to the resilience of urban ecosystems by providing services to maintain or restore hydrological functions. However, this poses a challenge to urban planners in deciding upon effective adaptation measures as they often lack information on the performance of green infrastructure to moderate surface runoff. It remains unclear what type of green infrastructure (e.g. trees, green roofs), offers the highest potential to reduce discharge volumes and to what extent. Against this background, this study provides an approach to gather quantitative evidence on green infrastructure's regulation potential. We use a micro-scale scenario modelling approach of different variations of green cover under current and future climatic conditions. The scenarios are modelled with MIKE SHE, an integrated hydrological simulation tool, and applied to a high density residential area of perimeter blocks in Munich, Germany. The results reveal that both trees and green roofs increase water storage capacities and hence reduce surface runoff, although the main contribution of trees lies in increasing interception and evapotranspiration, whereas green roofs allow for more retention through water storage in their substrate. With increasing precipitation intensities as projected under climate change their regulating potential decreases due to limited water

  16. Dynamics of intramolecular spin exchange interaction of a nitronyl nitroxide diradical in solution and on surfaces

    Science.gov (United States)

    Lloveras, V.; Badetti, E.; Veciana, J.; Vidal-Gancedo, J.

    2016-02-01

    In this paper we report the study of the dynamics of a thermally modulated intramolecular spin exchange interaction of a novel diradical nitronyl nitroxide-substituted disulfide in solution and when it is grafted on a gold surface. The structure of this diradical was designed to have flexible chains leading to intramolecular collisions and hence spin exchange interaction, and with an appropriate binding group to be grafted on the gold surface to study its behavior on the surface. In solution, this diradical shows a strong spin exchange interaction between both radicals which is modulated by temperature, but also gold nanoparticles (AuNPs) functionalized with this diradical permit investigation of such a phenomenon in surface-grafted radicals. The spin-labelled AuNP synthesis was optimized to obtain high coverage of spin labels to lead to high spin exchange interaction. The obtained AuNPs were studied by Electron Paramagnetic Resonance (EPR), UV-Vis, and IR spectroscopies, HR-TEM microscopy, Cyclic Voltammetry (CV), Energy Dispersive X-ray analysis (EDX) and Thermogravimetric Analysis (TGA). This inorganic-organic hybrid material also showed dipolar interactions between its radicals which were confirmed by the appearance in the EPR spectra of an |Δms| = 2 transition at half-field. This signal gives direct evidence of the presence of a high-spin state and permitted us to study the nature of the magnetic coupling between the spins which was found to be antiferromagnetic. Self-Assembled Monolayers (SAMs) of these radicals on the Au (111) substrate were also prepared and studied by contact angle, X-Ray Photoelectron Spectroscopy (XPS), Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS), Cyclic Voltammetry and EPR. The magnetic as well as the electrochemical properties of the hybrid surfaces were studied and compared with the properties of this diradical in solution. Analogies between the properties of AuNPs with high coverage of radicals and those of SAM were

  17. Experimental study of geometrical characteristics of distilled water and aqueous ethanol solution droplets evaporating on aluminum surface

    OpenAIRE

    Islamova Anastasiya; Orlova Evgeniya; Zykov Ilya

    2017-01-01

    Change of geometrical characteristics of distilled water and aqueous ethanol solution droplets was studied under their evaporation on aluminum surface. According to change in the contact diameter three evaporation modes of distilled water droplet on polished aluminum surface were detected: increase in the contact area, pinning of a droplet (constant contact area), and droplet depinning (decrease in the contact diameter). During evaporation of aqueous ethanol solution droplets, two evaporation...

  18. Montmorillonite surface properties and sorption characteristics for heavy metal removal from aqueous solutions

    International Nuclear Information System (INIS)

    Ijagbemi, Christianah Olakitan; Baek, Mi-Hwa; Kim, Dong-Su

    2009-01-01

    Surface properties of montmorillonite (MMT) and its adsorption characteristics for heavy metals have been investigated with nickel and copper as sorbate from aqueous solutions. Employing the potentiometric and mass titration techniques in batch experimental methods, the point of zero charge (PZC) and point of zero net proton charge (PZNPC) of MMT edges at different ionic strengths present pH PZC and pH PZNPC to be 3.4 ± 0.2. A crossing point was observed for the proton adsorption vs. pH curves at different ionic strengths of KCl electrolyte and in investigating MMT remediation potentialities as sorbent for heavy metals polluted waters, the effects of heavy metal concentration, pH, MMT dosage, reaction time and temperature for Cu 2+ and Ni 2+ uptake were studied. The sorption of metal ions by MMT was pH dependent and the adsorption kinetics revealed sorption rate could be well fitted by the pseudo-second-order rate model. The data according to mass transfer and intraparticle diffusion models confirmed diffusion of solutes inside the clay particles as the rate-controlling step and more important for the adsorption rate than the external mass transfer. Adsorption isotherms showed that the uptake of Cu 2+ and Ni 2+ could be described by the Langmuir model and from calculations on thermodynamic parameters, the positive ΔG o values at different temperatures suggest that the sorption of both metal ions were non-spontaneous. Change in enthalpy (ΔH o ) for Ni 2+ and Cu 2+ were 28.9 and 13.27 kJ/mol K respectively, hence an endothermic diffusion process, as ion uptake increased with increase in temperature. Values of ΔS o indicate low randomness at the solid/solution interface during the uptake of both Cu 2+ and Ni 2+ by MMT. Montmorillonite has a considerable potential for the removal of heavy metal cationic species from aqueous solution and wastewater.

  19. Identifying Key Issues and Potential Solutions for Integrated Arrival, Departure, Surface Operations by Surveying Stakeholder Preferences

    Science.gov (United States)

    Aponso, Bimal; Coppenbarger, Richard A.; Jung, Yoon; Quon, Leighton; Lohr, Gary; O’Connor, Neil; Engelland, Shawn

    2015-01-01

    NASA's Aeronautics Research Mission Directorate (ARMD) collaborates with the FAA and industry to provide concepts and technologies that enhance the transition to the next-generation air-traffic management system (NextGen). To facilitate this collaboration, ARMD has a series of Airspace Technology Demonstration (ATD) sub-projects that develop, demonstrate, and transitions NASA technologies and concepts for implementation in the National Airspace System (NAS). The second of these sub-projects, ATD-2, is focused on the potential benefits to NAS stakeholders of integrated arrival, departure, surface (IADS) operations. To determine the project objectives and assess the benefits of a potential solution, NASA surveyed NAS stakeholders to understand the existing issues in arrival, departure, and surface operations, and the perceived benefits of better integrating these operations. NASA surveyed a broad cross-section of stakeholders representing the airlines, airports, air-navigation service providers, and industry providers of NAS tools. The survey indicated that improving the predictability of flight times (schedules) could improve efficiency in arrival, departure, and surface operations. Stakeholders also mentioned the need for better strategic and tactical information on traffic constraints as well as better information sharing and a coupled collaborative planning process that allows stakeholders to coordinate IADS operations. To assess the impact of a potential solution, NASA sketched an initial departure scheduling concept and assessed its viability by surveying a select group of stakeholders for a second time. The objective of the departure scheduler was to enable flights to move continuously from gate to cruise with minimal interruption in a busy metroplex airspace environment using strategic and tactical scheduling enhanced by collaborative planning between airlines and service providers. The stakeholders agreed that this departure concept could improve schedule

  20. Stable, metastable and unstable solutions of a spin-1 Ising system based on the free energy surfaces

    Science.gov (United States)

    Keskİin, Mustafa; Özgan, Şükrü

    1990-04-01

    Stable, metastable and unstable solutions of a spin-1 Ising model with bilinear and biquadratic interactions are found by using the free energy surfaces. The free energy expression is obtained in the lowest approximation of the cluster variation method. All these solutions are shown in the two-dimensional phase space, especially the unstable solutions which in some cases are difficult to illustrate in the two-dimensional phase space, found by Keskin et al. recently.

  1. Surface tension prevails over solute effect in organic-influenced cloud droplet activation

    Science.gov (United States)

    Ovadnevaite, Jurgita; Zuend, Andreas; Laaksonen, Ari; Sanchez, Kevin J.; Roberts, Greg; Ceburnis, Darius; Decesari, Stefano; Rinaldi, Matteo; Hodas, Natasha; Facchini, Maria Cristina; Seinfeld, John H.; O' Dowd, Colin

    2017-06-01

    The spontaneous growth of cloud condensation nuclei (CCN) into cloud droplets under supersaturated water vapour conditions is described by classic Köhler theory. This spontaneous activation of CCN depends on the interplay between the Raoult effect, whereby activation potential increases with decreasing water activity or increasing solute concentration, and the Kelvin effect, whereby activation potential decreases with decreasing droplet size or increases with decreasing surface tension, which is sensitive to surfactants. Surface tension lowering caused by organic surfactants, which diminishes the Kelvin effect, is expected to be negated by a concomitant reduction in the Raoult effect, driven by the displacement of surfactant molecules from the droplet bulk to the droplet-vapour interface. Here we present observational and theoretical evidence illustrating that, in ambient air, surface tension lowering can prevail over the reduction in the Raoult effect, leading to substantial increases in cloud droplet concentrations. We suggest that consideration of liquid-liquid phase separation, leading to complete or partial engulfing of a hygroscopic particle core by a hydrophobic organic-rich phase, can explain the lack of concomitant reduction of the Raoult effect, while maintaining substantial lowering of surface tension, even for partial surface coverage. Apart from the importance of particle size and composition in droplet activation, we show by observation and modelling that incorporation of phase-separation effects into activation thermodynamics can lead to a CCN number concentration that is up to ten times what is predicted by climate models, changing the properties of clouds. An adequate representation of the CCN activation process is essential to the prediction of clouds in climate models, and given the effect of clouds on the Earth’s energy balance, improved prediction of aerosol-cloud-climate interactions is likely to result in improved assessments of future

  2. Surface tension prevails over solute effect in organic-influenced cloud droplet activation.

    Science.gov (United States)

    Ovadnevaite, Jurgita; Zuend, Andreas; Laaksonen, Ari; Sanchez, Kevin J; Roberts, Greg; Ceburnis, Darius; Decesari, Stefano; Rinaldi, Matteo; Hodas, Natasha; Facchini, Maria Cristina; Seinfeld, John H; O' Dowd, Colin

    2017-06-29

    The spontaneous growth of cloud condensation nuclei (CCN) into cloud droplets under supersaturated water vapour conditions is described by classic Köhler theory. This spontaneous activation of CCN depends on the interplay between the Raoult effect, whereby activation potential increases with decreasing water activity or increasing solute concentration, and the Kelvin effect, whereby activation potential decreases with decreasing droplet size or increases with decreasing surface tension, which is sensitive to surfactants. Surface tension lowering caused by organic surfactants, which diminishes the Kelvin effect, is expected to be negated by a concomitant reduction in the Raoult effect, driven by the displacement of surfactant molecules from the droplet bulk to the droplet-vapour interface. Here we present observational and theoretical evidence illustrating that, in ambient air, surface tension lowering can prevail over the reduction in the Raoult effect, leading to substantial increases in cloud droplet concentrations. We suggest that consideration of liquid-liquid phase separation, leading to complete or partial engulfing of a hygroscopic particle core by a hydrophobic organic-rich phase, can explain the lack of concomitant reduction of the Raoult effect, while maintaining substantial lowering of surface tension, even for partial surface coverage. Apart from the importance of particle size and composition in droplet activation, we show by observation and modelling that incorporation of phase-separation effects into activation thermodynamics can lead to a CCN number concentration that is up to ten times what is predicted by climate models, changing the properties of clouds. An adequate representation of the CCN activation process is essential to the prediction of clouds in climate models, and given the effect of clouds on the Earth's energy balance, improved prediction of aerosol-cloud-climate interactions is likely to result in improved assessments of future

  3. SOLUTIONING

    Directory of Open Access Journals (Sweden)

    Maria de Hoyos Guajardo, Ph.D. Candidate, M.Sc., B.Eng.

    2004-11-01

    Full Text Available The theory that is presented below aims to conceptualise how a group of undergraduate students tackle non-routine mathematical problems during a problem-solving course. The aim of the course is to allow students to experience mathematics as a creative process and to reflect on their own experience. During the course, students are required to produce a written ‘rubric’ of their work, i.e., to document their thoughts as they occur as well as their emotionsduring the process. These ‘rubrics’ were used as the main source of data.Students’ problem-solving processes can be explained as a three-stage process that has been called ‘solutioning’. This process is presented in the six sections below. The first three refer to a common area of concern that can be called‘generating knowledge’. In this way, generating knowledge also includes issues related to ‘key ideas’ and ‘gaining understanding’. The third and the fourth sections refer to ‘generating’ and ‘validating a solution’, respectively. Finally, once solutions are generated and validated, students usually try to improve them further before presenting them as final results. Thus, the last section deals with‘improving a solution’. Although not all students go through all of the stages, it may be said that ‘solutioning’ considers students’ main concerns as they tackle non-routine mathematical problems.

  4. Osmotic and activity coefficients in the binary solutions of 1-butyl-3-methylimidazolium chloride and bromide in methanol or ethanol at T = 298.15 K from isopiestic measurements

    International Nuclear Information System (INIS)

    Sardroodi, Jaber Jahanbin; Azamat, Jafar; Atabay, Maryam

    2011-01-01

    Highlights: → The osmotic coefficients of the solutions of 1-butyl-3-methylimidazolium chloride and bromide in ethanol and methanol have been measured. → Measured osmotic coefficients were correlated using NRTL and Pitzer models. → Vapor pressures were evaluated from the correlated osmotic coefficients. → Model parameters have been interpreted in terms of ion-ion and ion-solvent interactions. - Abstract: Osmotic coefficients of the binary solutions of two room-temperature ionic liquids (1-butyl-3-methylimidazolium chloride and bromide) in methanol and ethanol have been measured at T = 298.15 K by the isopiestic method. The experimental osmotic coefficient data have been correlated using a forth-order polynomial in terms of (molality) 0.5 , with both, ion interaction model of Pitzer and electrolyte non-random two liquid (e-NRTL) model of Chen. The values of vapor pressures of above-mentioned solutions have been calculated from the osmotic coefficients. The model parameters fitted to the experimental osmotic coefficients have been used for prediction of the mean ionic activity coefficients of those ionic liquids in methanol and ethanol.

  5. Simultaneous determination of binary solution of triphenylmethane dyes in complex matrices onto magnetic amino-rich SWCNT using second-order calibration method.

    Science.gov (United States)

    Bayat, Mehrnoosh; Shemirani, Farzaneh; Ghasemi, Jahan B

    2017-10-30

    This study suggested a new method for simultaneous quantification of two dyes in complex matrices using second-order data by spectrophotometry. Second-order data was generated simply without any expensive instrument using two independent variables including wavelength and the monotonic addition of sodium dodecyl sulfate. Solid-phase extraction (SPE) based on amino-rich magnetic single-walled carbon nanotube as an adsorbent was employed prior to second-order data generation. SPE optimization was performed by Box-Behnken design, and parameters and their interaction which were dependent on the simultaneous extraction of dyes were examined. Competitive Langmuir and Freundlich isotherms for a binary system and individual dyes could all represent the equilibrium data well. The second-order data was processed by parallel factor analysis (PARAFAC and PARAFAC2) and multivariate curve resolution-alternating least squares (MCR-ALS). Figures of merit of the model including a limit of detection of 3.0 and 2.5 ng mL -1 for crystal violet and malachite green, respectively, were estimated using the MCR-ALS method. The combination of the second-order calibration and SPE presents an easy and versatile method for determination of the mixture of two dyes in the presence of uncalibrated interferences in environmental water, synthetic, and fish samples with the recoveries of 94-104.

  6. A Model Approach for Finding Cleaning Solutions for Plasticized Poly(Vinyl Chloride) Surfaces of Collections Objects

    DEFF Research Database (Denmark)

    Sanz Landaluze, Jon; Egsgaard, Helge; Morales Munoz, Clara

    2014-01-01

    This study focused on developing a surface cleaning treatment for one type of commercially available plasticized poly(vinyl chloride). The effects of cleaning solutions on samples of plasticized poly(vinyl chloride) were examined by several methods. The sample surface, prior to and after artifici...

  7. Using CFD Surface Solutions to Shape Sonic Boom Signatures Propagated from Off-Body Pressure

    Science.gov (United States)

    Ordaz, Irian; Li, Wu

    2013-01-01

    The conceptual design of a low-boom and low-drag supersonic aircraft remains a challenge despite significant progress in recent years. Inverse design using reversed equivalent area and adjoint methods have been demonstrated to be effective in shaping the ground signature propagated from computational fluid dynamics (CFD) off-body pressure distributions. However, there is still a need to reduce the computational cost in the early stages of design to obtain a baseline that is feasible for low-boom shaping, and in the search for a robust low-boom design over the entire sonic boom footprint. The proposed design method addresses the need to reduce the computational cost for robust low-boom design by using surface pressure distributions from CFD solutions to shape sonic boom ground signatures propagated from CFD off-body pressure.

  8. Similarity Solutions for Flow and Heat Transfer of Non-Newtonian Fluid over a Stretching Surface

    Directory of Open Access Journals (Sweden)

    Atta Sojoudi

    2014-01-01

    Full Text Available Similarity solutions are carried out for flow of power law non-Newtonian fluid film on unsteady stretching surface subjected to constant heat flux. Free convection heat transfer induces thermal boundary layer within a semi-infinite layer of Boussinesq fluid. The nonlinear coupled partial differential equations (PDE governing the flow and the boundary conditions are converted to a system of ordinary differential equations (ODE using two-parameter groups. This technique reduces the number of independent variables by two, and finally the obtained ordinary differential equations are solved numerically for the temperature and velocity using the shooting method. The thermal and velocity boundary layers are studied by the means of Prandtl number and non-Newtonian power index plotted in curves.

  9. Review of singular potential integrals for method of moments solutions of surface integral equations

    Directory of Open Access Journals (Sweden)

    A. Tzoulis

    2004-01-01

    Full Text Available Accurate evaluation of singular potential integrals is essential for successful method of moments (MoM solutions of surface integral equations. In mixed potential formulations for metallic and dielectric scatterers, kernels with 1/R and r1/R singularities must be considered. Several techniques for the treatment of these singularities will be reviewed. The most common approach solves the MoM source integrals analytically for specific observation points, thus regularizing the integral. However, in the case of r1/R a logarithmic singularity remains for which numerical evaluation of the testing integral is still difficult. A recently by Yl¨a-Oijala and Taskinen proposed remedy to this issue is discussed and evaluated within a hybrid finite element – boundary integral technique. Convergence results for the MoM coupling integrals are presented where also higher-order singularity extraction is considered.

  10. Analytical Solution for Elliptical Cloaks Based on The Frequency Selective Surface

    Directory of Open Access Journals (Sweden)

    E. Ghasemi Mizuji

    2015-01-01

    Full Text Available In this paper the elliptical dielectric cylinder which is covered with FSS cloak is considered. Frequency selective surface cloak which Alu named it mantle cloak is one of the recent techniques for cloaking. In this method an appropriate FSS can act as cloaking device for suppressing  the scattering of object  in the desired frequency. With using this method the dimension of the cloaks is extremely reduced. By this proposed structure, the RCS of elliptical cylinder  is reduced about 10-20 dB and designed cloak has an appropriate performance.  The analytical solution for the wave in each layer is presented and with using simulation, the electric field and the scattering pattern has been drawn.

  11. Calorimetric investigations of hydrogen bonding in binary mixtures containing pyridine and its methyl-substituted derivatives. II. The dilute solutions of methanol and 2-methyl-2-propanol

    International Nuclear Information System (INIS)

    Marczak, Wojciech; Heintz, Andreas; Bucek, Monika

    2004-01-01

    Enthalpies of solution of methanol and 2-methyl-2-propanol (tert-butanol) in pyridine and its methyl derivatives were investigated in the range of mole fractions of alcohol x≤0.02 at temperature 298.15 K by a titration calorimeter. Dissolution of methanol is an exothermic process, with heat effects very close to those for water reported in part I of this study. The negative enthalpy of solution increases in the following order: pyridine < 3-methylpyridine < 4-methylpyridine < 2-methylpyridine < 2,6-dimethylpyridine < 2,4,6-trimethylpyridine. Positive enthalpies of solution of 2-methyl-2-propanol increase as follows: 2-methylpyridine < 2,4,6-trimethylpyridine < 4-methylpyridine < 2,6-dimethylpyridine < 3-methylpyridine < pyridine. The propensity of pyridine derivatives to hydrogen bonding is enhanced by the ortho effect. Methyl groups are probably too small to prevent the nitrogen atom in the pyridine ring from hydrogen bonding. However, spacious hydrocarbon group in 2-methyl-2-propanol molecule makes the bonding difficult for 2,6-dimethylpyridine and 2,4,6-trimethylpyridine, thus the number of O-H···N bonds is smaller than that in the solutions of methanol or water. The two latter seem to be very close to each other

  12. Standard Methods of Analysis of Sulfochromate Etch Solution Used in Surface Preparation of Aluminum

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2012-01-01

    1.1 These methods offer a means for controlling the effectiveness of the etchant which is normally used for preparing the surface of aluminum alloys for subsequent adhesive bonding. As the etchant reacts with the aluminum, hexavalent chromium is converted to trivalent chromium; a measure of the two and the difference can be used to determine the amount of dichromate used. 1.2 The sulfochromate solution can be replenished by restoring the sodium dichromate and the sulfuric acid to the original formulation levels. The lower limit of usefulness will vary depending upon solution storage, adhesives used, critical nature of bond capability, variety of metals processed, etc. and should be determined. Replenishment will be limited to the number of times the chemical ingredients can be restored and maintained to the required levels and should be determined by the user. Sludge collecting in the bottom of a tank should be minimized by periodic removal of sludge. For some applications, the hexavalent chromium should not ...

  13. Removal of fluoride from aqueous solution by adsorption on hydroxyapatite (HAp using response surface methodology

    Directory of Open Access Journals (Sweden)

    M. Mourabet

    2015-11-01

    Full Text Available A study on the adsorption of fluoride onto hydroxyapatite was conducted and the process parameters were optimized using Response Surface Methodology (RSM. Hydroxyapatite has been characterized by using different physicochemical methods. In order to determine the effects of process parameters namely temperature (20–40 °C, initial solution pH (4–11, adsorbent dose (0.1–0.3 g and initial fluoride concentration (10–20 mg L−1 on fluoride uptake from aqueous solution, a three-level, four-factor, Box–Behnken design has been employed. The second order mathematical model was developed by regression analysis of the experimental data obtained from 29 batch runs. The optimum pH, temperature, adsorbent dose and initial concentration were found by desirability function to be 4.16, 39.02 °C, 0.28 g and 20 mg L−1, respectively. Fluoride removal was 86.34% at the optimum combination of process parameters. Dynamic adsorption data were applied to pseudo-first-order and pseudo-second-order rate equations. The time data fitted well to pseudo second order kinetic model. According to the correlation coefficients, the adsorption of fluoride on the hydroxyapatite was correlated well with the Langmuir and Freundlich models.

  14. Theoretical study of the amphoteric oxide nanoparticle surface charge during multi-particle interactions in aqueous solutions

    Science.gov (United States)

    Alfimov, A. V.; Aryslanova, E. M.; Chivilikhin, S. A.

    2015-11-01

    Nanoparticle surface charge plays an important role in many biological applications. In this study, an analytical surface charging model for the amphoteric oxide nanoparticles has been presented. The model accounts for the particle's electric double layer self-action on the charging process and the charge regulation during multi-particle interactions in aqueous solutions. The employment of the model allows to explicitly describe the nanoparticle agglomeration process and the accompanying agglomerate surface charge variation.

  15. Evaporation of sessile droplets of dilute aqueous solutions containing sodium n-alkylates from polymer surfaces: influences of alkyl length and concentration of solute.

    Science.gov (United States)

    Kim, Jung-Hoon; Ahn, Sung Il; Kim, Jae Hyun; Kim, Jong Soo; Cho, Kilwon; Jung, Jin Chul; Chang, Taihyun; Ree, Moonhor; Zin, Wang-Cheol

    2008-10-21

    The evaporation of sessile droplets placed on polymer surfaces was studied by microscopic observation of the changes in shape of aqueous solution droplets in which the alkyl lengths and the initial concentrations of sodium n-alkylates were varied. Although the initial contact angles of the droplets were not significantly different, the evaporation process varied significantly with the alkyl length of the sodium n-alkylate employed. For the sodium dodecanoate (C 12), showing the highest surface activity, the concentration was found to have a significant effect on the evaporation process of the droplets. In the evaporation of water droplets, variations in the three distinct stages were caused by the different concentration of solutes distributed near or at the air/water interface. It is revealed that the concentration of droplet solute near the air/water interface requires not only solvent evaporation but also some affinity of the solute for the interface. The initial C 12 concentration-dependence of the evaporation of C 12 solution droplets is discussed with particular emphasis on the sudden spreading or sudden contraction of the contact area near the end of evaporation. It is suggested that the cluster formation by C 12 molecules at the air/liquid interface during the evaporation causes Marangoni instability in an evaporating droplet, and the clusters are expected to move dynamically, depending on the droplet concentration of C 12, from the droplet center to the contact line and vice versa, showing Marangoni flow along the air/water interface.

  16. Phytofilter - environmental friendly solution for purification of surface plate from urbanized territories

    Science.gov (United States)

    Ruchkinova, O.; Shchuckin, I.

    2017-06-01

    Its proved, that phytofilters are environmental friendly solution of problem of purification of surface plate from urbanized territories. Phytofilters answer the nowadays purposes to systems of purification of land drainage. The main problem of it is restrictions, connecter with its use in the conditions of cold temperature. Manufactured a technology and mechanism, which provide a whole-year purification of surface plate and its storage. Experimentally stated optimal makeup of filtering load: peat, zeolite and sand in per cent of volume, which provides defined hydraulic characteristics. Stated sorbate and ion-selective volume of complex filtering load of ordered composition in dynamic conditions. Estimated dependences of exit concentrations of oil products and heavy metals on temperature by filtering through complex filtering load of ordered composition. Defined effectiveness of purification at phytofiltering installation. Fixed an influence of embryophytes on process of phytogeneration and capacity of filtering load. Recommended swamp iris, mace reed and reed grass. Manufactured phytofilter calculation methodology. Calculated economic effect from use of phytofiltration technology in comparison with traditional block-modular installations.

  17. Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions

    International Nuclear Information System (INIS)

    Rotaru, Ileana; Varvara, Simona; Gaina, Luiza; Muresan, Liana Maria

    2014-01-01

    Graphical abstract: - Highlights: • All four investigated antibacterial drugs act as corrosion inhibitors for bronze surface. • In the presence of antibiotics, a 3RC electric circuit simulates the corrosion system. • The electrochemical results indicate as best inhibitors Doxy, followed by Strepto. • HOMO–LUMO energy gap increases in the order: Doxy > Strepto > Cipro > Amoxi. • The thin protective film on bronze is reinforced by the presence of the antibiotics. - Abstract: The present study is aiming to investigate the effect of four antibiotics (amoxicillin, ciprofloxacin, doxycycline and streptomycin,) belonging to different classes of antibacterial drugs on bronze corrosion in a solution simulating an acid rain (pH 4). Due to their ability to form protective films on the metal surface, the tested antibiotics act as corrosion inhibitors for bronze. The antibiotics were tested at various concentrations in order to determine the optimal concentration range for the best corrosion inhibiting effect. In evaluating the inhibition efficiency, polarization curves, electrochemical impedance spectroscopy, SEM and XPS measurements were used. Moreover, a correlation between the inhibition efficiency of some antibacterial drugs and certain molecular parameters was determined by quantum chemical computations. Parameters like energies E HOMO and E LUMO and HOMO–LUMO energy gap were used for correlation with the corrosion data

  18. Antibacterial drugs as corrosion inhibitors for bronze surfaces in acidic solutions

    Energy Technology Data Exchange (ETDEWEB)

    Rotaru, Ileana [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania); Varvara, Simona, E-mail: svarvara@uab.ro [Department of Exact Sciences and Engineering, “1 Decembrie 1918” University, 11-13 Nicolae Iorga St., 510009 Alba Iulia (Romania); Gaina, Luiza [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania); Muresan, Liana Maria, E-mail: limur@chem.ubbcluj.ro [Department of Chemical Engineering, “Babes-Bolyai” University, 11 Arany-Janos St., 400028 Cluj-Napoca (Romania)

    2014-12-01

    Graphical abstract: - Highlights: • All four investigated antibacterial drugs act as corrosion inhibitors for bronze surface. • In the presence of antibiotics, a 3RC electric circuit simulates the corrosion system. • The electrochemical results indicate as best inhibitors Doxy, followed by Strepto. • HOMO–LUMO energy gap increases in the order: Doxy > Strepto > Cipro > Amoxi. • The thin protective film on bronze is reinforced by the presence of the antibiotics. - Abstract: The present study is aiming to investigate the effect of four antibiotics (amoxicillin, ciprofloxacin, doxycycline and streptomycin,) belonging to different classes of antibacterial drugs on bronze corrosion in a solution simulating an acid rain (pH 4). Due to their ability to form protective films on the metal surface, the tested antibiotics act as corrosion inhibitors for bronze. The antibiotics were tested at various concentrations in order to determine the optimal concentration range for the best corrosion inhibiting effect. In evaluating the inhibition efficiency, polarization curves, electrochemical impedance spectroscopy, SEM and XPS measurements were used. Moreover, a correlation between the inhibition efficiency of some antibacterial drugs and certain molecular parameters was determined by quantum chemical computations. Parameters like energies E{sub HOMO} and E{sub LUMO} and HOMO–LUMO energy gap were used for correlation with the corrosion data.

  19. Tuning colloidal quantum dot band edge positions through solution-phase surface chemistry modification

    Science.gov (United States)

    Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P.; McNichols, Brett W.; Miller, Elisa M.; Gu, Jing; Nozik, Arthur J.; Sellinger, Alan; Galli, Giulia; Beard, Matthew C.

    2017-05-01

    Band edge positions of semiconductors determine their functionality in many optoelectronic applications such as photovoltaics, photoelectrochemical cells and light emitting diodes. Here we show that band edge positions of lead sulfide (PbS) colloidal semiconductor nanocrystals, specifically quantum dots (QDs), can be tuned over 2.0 eV through surface chemistry modification. We achieved this remarkable control through the development of simple, robust and scalable solution-phase ligand exchange methods, which completely replace native ligands with functionalized cinnamate ligands, allowing for well-defined, highly tunable chemical systems. By combining experiments and ab initio simulations, we establish clear relationships between QD surface chemistry and the band edge positions of ligand/QD hybrid systems. We find that in addition to ligand dipole, inter-QD ligand shell inter-digitization contributes to the band edge shifts. We expect that our established relationships and principles can help guide future optimization of functional organic/inorganic hybrid nanostructures for diverse optoelectronic applications.

  20. Adsorption of Zn(2+) and Ni(2+) in a binary aqueous solution by biosorbents derived from sawdust and water hyacinth (Eichhornia crassipes).

    Science.gov (United States)

    Gwenzi, Willis; Musarurwa, Tinashe; Nyamugafata, Phillip; Chaukura, Nhamo; Chaparadza, Allen; Mbera, Sharron

    2014-01-01

    The Zn(2+) and Ni(2+) adsorption capacities of six biosorbents derived from water hyacinth (Eichhornia crassipes) (WH) and sawdust (SD) were investigated, with activated carbon as the control. The biosorbents were raw biomass (WH, SD), charred WH (BWH) and SD and sulphonated bio-chars of WH and SD. The effect of the initial solution pH and Zn(2+) and Ni(2+) concentrations on adsorption capacity was studied, and adsorption isotherms for Zn(2+) and Ni(2+) evaluated. The initial solution pH significantly influenced adsorption (p adsorption on all biosorbents. The adsorption capacities of the biosorbents were statistically (p ≤ 0.05) similar to or higher than that of activated carbon. The effects of pyrolysis and bio-char sulphonation on adsorption were inconsistent and dependent on biomass type; in most cases bio-char was a better biosorbent than the original biomass, while sulphonation resulted in less or comparable adsorption. Adsorption data obeyed at least one of three isotherms (linear, Langmuir and Freundlich) (r(2) = 0.90-0.995, p < 0.05). The study revealed that low-cost biosorbents may be used as alternatives to activated carbon in applications including selective separation of Zn(2+) from multi-metal ion solutions containing Ni(2+), and water and wastewater treatment.

  1. Adsorption of ibuprofen from aqueous solution on chemically surface-modified activated carbon cloths

    Directory of Open Access Journals (Sweden)

    Hanen Guedidi

    2017-05-01

    Full Text Available This study aims to investigate the performance of an activated carbon cloth for adsorption of ibuprofen. The cloth was oxidized by a NaOCl solution (0.13 mol L−1 or thermally treated under N2 (700 °C for 1 hour. The raw and modified cloths were characterized by N2 adsorption–desorption measurement at 77 K, CO2 adsorption at 273 K, Boehm titrations, pHPZC measurements, X-ray Photoelectron Spectroscopy analysis, and by infrared spectroscopy. The NaOCl treatment increases the acidic sites, mostly creating phenolic and carboxylic groups and decreases both the specific surface area and slightly the micropore volume. However, the thermal treatment at 700 °C under N2 induced a slight increase in the BET specific surface area and yielded to the only increase in the carbonyl group content. Ibuprofen adsorption studies of kinetics and isotherms were carried out at pH = 3 and 7. The adsorption properties were correlated to the cloth porous textures, surface chemistry and pH conditions. The isotherms of adsorption were better reproduced by Langmuir–Freundlich models at 298, 313 and 328 K. The adsorption of ibuprofen on the studied activated carbon cloths at pH 3 was an endothermic process. The pore size distributions of all studied ibuprofen-loaded fabrics were determined by DFT method to investigate the accessible porosity of the adsorbate. Both treatments do not influence the kind of micropores where the adsorption of ibuprofen occurred.

  2. Possible Time-Dependent Effect of Ions and Hydrophilic Surfaces on the Electrical Conductivity of Aqueous Solutions

    Science.gov (United States)

    Verdel, Nada; Jerman, Igor; Krasovec, Rok; Bukovec, Peter; Zupancic, Marija

    2012-01-01

    The purpose of this work was to determine the influence of mechanical and electrical treatment on the electrical conductivity of aqueous solutions. Solutions were treated mechanically by iteration of two steps: 1:100 dilution and vigorous shaking. These two processes were repeated until extremely dilute solutions were obtained. For electrical treatment the solutions were exposed to strong electrical impulses. Effects of mechanical (as well as electrical) treatment could not be demonstrated using electrical conductivity measurements. However, significantly higher conductivity than those of the freshly prepared chemically analogous solutions was found in all aged solutions except for those samples stored frozen. The results surprisingly resemble a previously observed weak gel-like behavior in water stored in closed flasks. We suggest that ions and contact with hydrophilic glass surfaces could be the determinative conditions for the occurrence of this phenomenon. PMID:22605965

  3. Influence of synthesis methods on tungsten dispersion, structural deformation, and surface acidity in binary WO3-ZrO2 system.

    Science.gov (United States)

    Cortés-Jácome, M A; Toledo, J A; Angeles-Chavez, C; Aguilar, M; Wang, J A

    2005-12-08

    WO3-ZrO2 catalysts were synthesized by precipitating the aqueous solutions of zirconium oxynitrate and ammonium metatungstate with ammonium hydroxide. The white slurry precipitate was treated under three different conditions. In the as-made materials, the amorphous phase was formed in the aged and refluxed samples, while well-crystallized tetragonal and monoclinic phases were obtained in the hydrothermally treated sample. The real amount of tungsten loaded in the samples was similar for the three samples, independently of the treatments; however, the tungsten surface atomic density in the annealed WO3-ZrO2 samples varied between 6 and 9 W atoms/nm2. Two different contrast types of aggregates were determined by scanning electron microscopy, the white particles which are rich in W, and the gray ones which are rich in zirconium; both of them were formed in the calcined solids prepared under aging or reflux condition. A very high dispersion of tungsten species on the zirconia surface was achieved in the hydrothermally treated sample. The degree of the interaction between WO(x) and ZrO2 surface strongly modified the Zr-O bond lengths and bond angles in the structure of tetragonal zirconia as proved by X-ray diffraction analysis and the Rietveld refinement. The catalyst obtained under hydrothermal condition exhibited the highest dispersion of tungsten species in the zirconia, which in turn causes strong structural deformation of the tetragonal ZrO2 phase responsible of the strongest surface acidity and, consequently, the optimum catalytic activity for n-hexane isomerization.

  4. Multi-response optimization using Taguchi design and principle component analysis for removing binary mixture of alizarin red and alizarin yellow from aqueous solution by nano γ-alumina.

    Science.gov (United States)

    Zolgharnein, Javad; Asanjrani, Neda; Bagtash, Maryam; Azimi, Gholamhasan

    2014-05-21

    The nanostructure of γ-alumina was used as an effective adsorbent for simultaneous removing of a mixture of alizarin red and alizarin yellow from aqueous solutions. The Taguchi design and principle component analysis were applied to explore effective parameters for achieving a higher adsorption capacity and removal percentage of the binary mixture containing alizarin red and alizarin yellow. Seven factors including temperature, contact time, initial pH value, the shaker rate, the sorbent dose, and initial concentrations of alizarin red and alizarin yellow in three levels were considered through the Taguchi technique. A L27 orthogonal array was used to determine the signal-to-noise ratio. Then, the removal percentage (R%) and adsorption capacity (q) of the above-mentioned dyes were transformed into an accurate S/N ratio. The Taguchi method indicates that the solution pH has the most contribution in controlling the removal percentage of alizarin red and alizarin yellow. Under optimal condition, the maximum removal percentages of 99% and 78.5%, and the capacity uptake of 54.4 and 39.0mg g(-1) were obtained for both alizarin red and alizarin yellow, respectively. Isotherm modeling and kinetic investigations showed that Langmuir, modified Langmuir, and pseudo-second-order models describe both the adsorption equilibrium and kinetic behavior well. The Fourier transform infrared analysis also firmly confirmed the involving active sites of nano γ-alumina in the adsorption process. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. ACOUSTIC EFFECTS ON BINARY AEROELASTICITY MODEL

    Directory of Open Access Journals (Sweden)

    Kok Hwa Yu

    2011-10-01

    Full Text Available Acoustics is the science concerned with the study of sound. The effects of sound on structures attract overwhelm interests and numerous studies were carried out in this particular area. Many of the preliminary investigations show that acoustic pressure produces significant influences on structures such as thin plate, membrane and also high-impedance medium like water (and other similar fluids. Thus, it is useful to investigate the structure response with the presence of acoustics on aircraft, especially on aircraft wings, tails and control surfaces which are vulnerable to flutter phenomena. The present paper describes the modeling of structural-acoustic interactions to simulate the external acoustic effect on binary flutter model. Here, the binary flutter model which illustrated as a rectangular wing is constructed using strip theory with simplified unsteady aerodynamics involving flap and pitch degree of freedom terms. The external acoustic excitation, on the other hand, is modeled using four-node quadrilateral isoparametric element via finite element approach. Both equations then carefully coupled and solved using eigenvalue solution. The mentioned approach is implemented in MATLAB and the outcome of the simulated result are later described, analyzed and illustrated in this paper.

  6. Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    DePaolo, D.

    2010-10-15

    A surface reaction kinetic model is developed for predicting Ca isotope fractionation and metal/Ca ratios of calcite as a function of rate of precipitation from aqueous solution. The model is based on the requirements for dynamic equilibrium; i.e. proximity to equilibrium conditions is determined by the ratio of the net precipitation rate (R{sub p}) to the gross forward precipitation rate (R{sub f}), for conditions where ionic transport to the growing crystal surface is not rate-limiting. The value of R{sub p} has been experimentally measured under varying conditions, but the magnitude of R{sub f} is not generally known, and may depend on several factors. It is posited that, for systems with no trace constituents that alter the surface chemistry, R{sub f} can be estimated from the bulk far-from-equilibrium dissolution rate of calcite (R{sub b} or k{sub b}), since at equilibrium R{sub f} = R{sub b}, and R{sub p} = 0. Hence it can be inferred that R{sub f} {approx} R{sub p} + R{sub b}. The dissolution rate of pure calcite is measureable and is known to be a function of temperature and pH. At given temperature and pH, equilibrium precipitation is approached when R{sub p} (= R{sub f} - R{sub b}) << R{sub b}. For precipitation rates high enough that R{sub p} >> R{sub b}, both isotopic and trace element partitioning are controlled by the kinetics of ion attachment to the mineral surface, which tend to favor more rapid incorporation of the light isotopes of Ca and discriminate weakly between trace metals and Ca. With varying precipitation rate, a transition region between equilibrium and kinetic control occurs near R{sub p} {approx} R{sub b} for Ca isotopic fractionation. According to this model, Ca isotopic data can be used to estimate R{sub f} for calcite precipitation. Mechanistic models for calcite precipitation indicate that the molecular exchange rate is not constant at constant T and pH, but rather is dependent also on solution saturation state and hence R{sub p

  7. Reduction in Friction and Wear of Alumina Surfaces as Assisted with Surface-Adsorbing Polymers in Aqueous Solutions

    DEFF Research Database (Denmark)

    Røn, Troels; Lee, Seunghwan

    2016-01-01

    electrostatic attraction and form a protective layer. For example, polyacrylic acid (PAA) showed a reduction in coefficient of friction by ca. 28% and wear rate by 50% at a concentration of 10 mg/mL in PBS solution compared to polymer-free buffer solution. This effect was comparable to reported lubricating...

  8. In situ X-ray scattering studies of protein solution droplets drying on micro- and nanopatterned superhydrophobic PMMA surfaces.

    Science.gov (United States)

    Accardo, Angelo; Gentile, Francesco; Mecarini, Federico; De Angelis, Francesco; Burghammer, Manfred; Di Fabrizio, Enzo; Riekel, Christian

    2010-09-21

    Superhydrophobic poly(methyl methacrylate) surfaces with contact angles of ∼170° and high optical and X-ray transparencies have been fabricated through the use of optical lithography and plasma etching. The surfaces contain either a microscale pattern of micropillars or a random nanofibrillar pattern. Nanoscale asperities on top of the micropillars closely resemble Nelumbo nucifera lotus leaves. The evolution of the contact angle of water and lysozyme solution droplets during evaporation was studied on the micro- and nanopatterned surfaces, showing in particular contact-line pinning for the protein solution droplet on the nanopatterned surface. The microstructural evolution of lysozyme solution droplets was studied on both types of surfaces in situ under nearly contact-free conditions by synchrotron radiation microbeam wide-angle and small-angle X-ray scattering revealing the increasing protein concentration and the onset of precipitation. The solid residuals show hollow sphere morphologies. Rastermicrodiffraction of the detached residuals suggests about a 1/3 volume fraction of ≥17 nm lysozyme nanocrystalline domains and about a 2/3 short-range-order volume fraction. About 5-fold larger nanocrystalline domains were observed at the attachment points of the sphere to the substrates, which is attributed to particle growth in a shear flow. Such surfaces represent nearly contact-free sample supports for studies of inorganic and organic solution droplets, which find applications in biochips.

  9. Solving a binary puzzle

    NARCIS (Netherlands)

    P.H. Utomo (Putranto); R.H. Makarim (Rusydi)

    2017-01-01

    textabstractA Binary puzzle is a Sudoku-like puzzle with values in each cell taken from the set (Formula presented.). Let (Formula presented.) be an even integer, a solved binary puzzle is an (Formula presented.) binary array that satisfies the following conditions: (1) no three consecutive ones and

  10. Eclipsing binaries in open clusters

    DEFF Research Database (Denmark)

    Southworth, John; Clausen, J.V.

    2006-01-01

    Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August......Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August...

  11. The first solution heats and primary curvature of formation enthalpy isotherms of liquid binary iron alloys with scandium, yttrium, lanthanum and cerium

    International Nuclear Information System (INIS)

    Esin, Yu.O.; Valishev, M.G.; Ermakov, A.F.; Demin, S.E.; Gel'd, P.V.

    1984-01-01

    Experimental values of the first solution heats Δ anti Hsub(i)sup(0) and initial curvature Δ 2 anti Hsub(i)sup(0) of formation enthalpy isotherms of alloys for diluted iron alloys with scandium, yttrium, lanthanum and cerium are discussed. The first partial enthalpy of liquid scandium dissolution in liquid iron is shown to be equal to - (42.3+-3) kJ/g-at. The minimum value of integral formation enthalpy, as calculated by means of a polynomial approximating the experimental data, makes up - (8+-1) kJ/g-at. at 29 at.% Sc. The value Δsup(2)anti Hsub(Sc)sup(0) turned out to be equal to 46+-20 kJ/g-at. The considered electronic structure model correctly reflects basic features of the alloy formation energetics in the investigated systems

  12. Green synthesis of Ag-Cr-AC nanocomposites by Azadirachta indica and its application for the simultaneous removal of binary mixture of dyes by ultrasonicated assisted adsorption process using Response Surface Methodology.

    Science.gov (United States)

    Saad, Muhammad; Tahir, Hajira; Ali, Duaa

    2017-09-01

    In the present studies the Ag-Cr-AC nanocomposites were synthesized by Azadirachta indica leaves extract. They were inoculated on the amorphous surface of activated carbon. The surface morphology and structural identification was determined by SEM, FTIR and XRD techniques. The simultaneous removal of binary dye system of Reactive Red and Crystal Violet were performed by ultrasonicated assisted adsorption process utilizing Ag-Cr-AC nanocomposites. Central Composite Design (CCD) having 5 factors of time, pH, amount of Ag-Cr-AC (adsorbent), concentrations of Reactive Red (RR) and Crystal Violet (CV) was employed. Response Surface Methodology was applied to study the Optimum Operating Parameters (OOP) for the adsorption process. The current studies showed that they can be efficiently employed to remove the coloured effluent from aqueous media as the simultaneous removal of dyes was observed to be 64.92% and 82.47% for RR and CV dyes respectively. Adsorption equilibrium was studied by Freundlich, Langmuir, Dubinin-Radushkevich, Temkin and Harkins-Jura Isotherm Models. The Langmuir isotherm was observed to be followed by the RR-Ag-Cr-AC system while CV-Ag-Cr-AC followed Harkins-Jura Isotherm model. For the binary system, the removal of CV and RR dyes by the nanocomposites obeyed Harkins-Jura model at temperature of 40°C. Thermodynamics studies affirmed the spontaneous nature of adsorption process. pH pzc was evaluated to be 6.29. The purification cost per cubic meter of the effluent was evaluated to be US$ 85.08. The proposed method might prove to be an efficient and cost effective way to eradicate color from the binary mixture of RR and CV dyes. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Direct protein quantification in complex sample solutions by surface-engineered nanorod probes

    KAUST Repository

    Schrittwieser, Stefan

    2017-06-30

    Detecting biomarkers from complex sample solutions is the key objective of molecular diagnostics. Being able to do so in a simple approach that does not require laborious sample preparation, sophisticated equipment and trained staff is vital for point-of-care applications. Here, we report on the specific detection of the breast cancer biomarker sHER2 directly from serum and saliva samples by a nanorod-based homogeneous biosensing approach, which is easy to operate as it only requires mixing of the samples with the nanorod probes. By careful nanorod surface engineering and homogeneous assay design, we demonstrate that the formation of a protein corona around the nanoparticles does not limit the applicability of our detection method, but on the contrary enables us to conduct in-situ reference measurements, thus further strengthening the point-of-care applicability of our method. Making use of sandwich assays on top of the nanorods, we obtain a limit of detection of 110 pM and 470 pM in 10-fold diluted spiked saliva and serum samples, respectively. In conclusion, our results open up numerous applications in direct protein biomarker quantification, specifically in point-of-care settings where resources are limited and ease-of-use is of essence.

  14. Modelling and optimization of process variables for the solution polymerization of styrene using response surface methodology

    Directory of Open Access Journals (Sweden)

    Rasheed Uthman Owolabi

    2018-01-01

    Full Text Available A satisfactory model for predicting monomer conversion in free radical polymerization has been a challenge due to the complexity and rigors associated with classical kinetic models. This renders the usage of such model an exciting endeavour in the academia but not exactly so in industrial practice. In this study, the individual and interactive effects of three processing conditions (reaction temperature, reaction time and initiator concentration on monomer conversion in the solution polymerization of styrene using acetone as solvent was investigated in a batch reactor through the central composite design (CCD model of response surface methodology (RSM for experimental design, modelling and process optimization. The modelled optimization conditions are: reaction time of 30 min, reaction temperature of 120 °C, and initiator concentration of 0.1135 mol/l, with the corresponding monomer conversion of 76.82% as compared to the observed conversion of 70.86%. A robust model for predicting monomer conversion that is very suitable for routine industrial usage is thus obtained.

  15. Surface Film Adsorption and Lubricity of Soybean Oil In-Water Emulsion and Triblock Copolymer Aqueous Solution: A Comparative Study

    Directory of Open Access Journals (Sweden)

    Reza Taheri

    2016-12-01

    Full Text Available This paper investigates the surface film adsorption and lubricity of two different types of potential environmentally friendly cold metal forming lubricants: soybean vegetable oil in water VO/W emulsions and triblock copolymer aqueous solutions. The lubricants have different visual appearance, surface film adsorption characteristic, lubricity and surface cleaning behaviour. The effects of concentration, temperature and emulsification ultrasonic energy (for VO/W emulsion are studied. The result shows that the soybean VO/W emulsions have stronger adsorption, superior lubricity and anti-wear property compared to the copolymer solutions. The effect of temperature is investigated at 30 °C and 65 °C which are below and above cloud point of the aqueous copolymer solutions. Both lubricants show improved friction and anti-wear property at 65 °C. However, tenacious residual film remained on the discs surface after surface cleaning indicates lower cleanability of the soybean VO/W emulsions compared to the copolymer solutions, postulating the need for extra post-processing cleaning operations after cold forming process with VO/W emulsion lubricant.

  16. Analytical solutions of linked fault tree probabilistic risk assessments using binary decision diagrams with emphasis on nuclear safety applications[Dissertation 17286

    Energy Technology Data Exchange (ETDEWEB)

    Nusbaumer, O. P. M

    2007-07-01

    This study is concerned with the quantification of Probabilistic Risk Assessment (PRA) using linked Fault Tree (FT) models. Probabilistic Risk assessment (PRA) of Nuclear Power Plants (NPPs) complements traditional deterministic analysis; it is widely recognized as a comprehensive and structured approach to identify accident scenarios and to derive numerical estimates of the associated risk levels. PRA models as found in the nuclear industry have evolved rapidly. Increasingly, they have been broadly applied to support numerous applications on various operational and regulatory matters. Regulatory bodies in many countries require that a PRA be performed for licensing purposes. PRA has reached the point where it can considerably influence the design and operation of nuclear power plants. However, most of the tools available for quantifying large PRA models are unable to produce analytically correct results. The algorithms of such quantifiers are designed to neglect sequences when their likelihood decreases below a predefined cutoff limit. In addition, the rare event approximation (e.g. Moivre's equation) is typically implemented for the first order, ignoring the success paths and the possibility that two or more events can occur simultaneously. This is only justified in assessments where the probabilities of the basic events are low. When the events in question are failures, the first order rare event approximation is always conservative, resulting in wrong interpretation of risk importance measures. Advanced NPP PRA models typically include human errors, common cause failure groups, seismic and phenomenological basic events, where the failure probabilities may approach unity, leading to questionable results. It is accepted that current quantification tools have reached their limits, and that new quantification techniques should be investigated. A novel approach using the mathematical concept of Binary Decision Diagram (BDD) is proposed to overcome these

  17. Durable protection of the surface of wood used outdoors: material constraints, problems and approaches to solutions

    Directory of Open Access Journals (Sweden)

    Merlin A.

    2018-01-01

    Full Text Available The aesthetic durability of wooden structures is a major challenge for the use of this material in construction. Wood is used for its technical performances but also for its architectural qualities and its aesthetic perception. The premature aging of the wooden structures is detrimental because these disorders, even if they do not affect the strength of the structures, are mostly irremediable. The surface protection of wood is generally ensured by the use of a finish, whose essential role is to protect wood from climatic aggressions (water, solar radiation, oxygen, .... The secondary wood processing industry consists of a series of manufacturing and processing activities, each containing a portion of the added value of the product. The application of a finish on a wood-based work is usually the last and most visible step in this value chain.In outdoor use, the protection of the wood surface with transparent finishes is not yet sufficiently durable to be able to compete with materials used in industrial carpentry such as PVC or aluminum. Opaque finishes generally provide more durable protection but they mask the appearance of the wood sought by users.With the aim of positioning wood in this construction sector, research on transparent finishes has focused on the efficiency and improvement of the durability of the protection of the surface appearance of structures. Faced with climatic aggressions, the optimum conservation of a structure is not only linked to the performance of the finish but also to the characteristics of the wood material. In particular, in order to fulfill its protective function, the finish film must be able to follow the dimensional variations of the wood it covers without breaking and without detachment. In addition to the criteria for the effectiveness of finishes in the protection of structures, the environmental impact must be considered with increasing attention. Currently, more than 80% of composite or solid wood

  18. Continuous agglomerate model for identifying the solute- indifferent part of colloid nanoparticle's surface charge

    International Nuclear Information System (INIS)

    Alfimov, A V; Aryslanova, E M; Chivilikhin, S A

    2016-01-01

    This work proposes an explicit analytical model for the surface potential of a colloidal nano-agglomerate. The model predicts that when an agglomerate reaches a certain critical size, its surface potential becomes independent of the agglomerate radius. The model also provides a method for identifying and quantifying the solute-indifferent charge in nanocolloids, that allows to assess the stability of toxicologically significant parameters of the system. (paper)

  19. Elastic-Plastic J-Integral Solutions or Surface Cracks in Tension Using an Interpolation Methodology. Appendix C -- Finite Element Models Solution Database File, Appendix D -- Benchmark Finite Element Models Solution Database File

    Science.gov (United States)

    Allen, Phillip A.; Wells, Douglas N.

    2013-01-01

    No closed form solutions exist for the elastic-plastic J-integral for surface cracks due to the nonlinear, three-dimensional nature of the problem. Traditionally, each surface crack must be analyzed with a unique and time-consuming nonlinear finite element analysis. To overcome this shortcoming, the authors have developed and analyzed an array of 600 3D nonlinear finite element models for surface cracks in flat plates under tension loading. The solution space covers a wide range of crack shapes and depths (shape: 0.2 less than or equal to a/c less than or equal to 1, depth: 0.2 less than or equal to a/B less than or equal to 0.8) and material flow properties (elastic modulus-to-yield ratio: 100 less than or equal to E/ys less than or equal to 1,000, and hardening: 3 less than or equal to n less than or equal to 20). The authors have developed a methodology for interpolating between the goemetric and material property variables that allows the user to reliably evaluate the full elastic-plastic J-integral and force versus crack mouth opening displacement solution; thus, a solution can be obtained very rapidly by users without elastic-plastic fracture mechanics modeling experience. Complete solutions for the 600 models and 25 additional benchmark models are provided in tabular format.

  20. Determination of electrostatic potential distribution by atomic force microscopy (AFM) on model silica and alumina surfaces in aqueous electrolyte solutions

    International Nuclear Information System (INIS)

    Yelken, Gulnihal Ozek; Polat, Mehmet

    2014-01-01

    Graphical abstract: - Highlights: • Atomic force microscopy was employed to quantitatively determine the surface potential on silica and alumina surfaces immersed in aqueous electrolyte solutions at various pH values using the DLVO theory. • Potential distributions could be presented in the form of a potential map by repeating the procedure on multiple locations on these surfaces. • The average potential of the distributions agreed very well with the surface potentials measured by electrophoretic techniques. • Several experimental procedures required to achieve the very sensitive force measurements were outlined and demonstrated. - Abstract: AFM was employed as a physicochemical probe to determine the electrostatic potential distribution quantitatively on selected ideal oxide surfaces (quartz 0 0 0 1 and sapphire 0 0 0 1) in aqueous media. The force of interaction between a silicon nitride tip and the oxide surface was measured at a given point under well-defined solution conditions. Relevant theories were used to isolate the electrostatic component from the total force of interaction which was then employed to estimate the surface potential at that point. Repeating the procedure on selected locations generated a potential map of the surface. Comparison of these potentials with those obtained from independent electrokinetic measurements confirmed the validity of the approach

  1. Desorption of 1,3,5-Trichlorobenzene from Multi-Walled Carbon Nanotubes: Impact of Solution Chemistry and Surface Chemistry

    Directory of Open Access Journals (Sweden)

    Sheikh Uddin

    2013-05-01

    Full Text Available The strong affinity of carbon nanotubes (CNTs to environmental contaminants has raised serious concern that CNTs may function as a carrier of environmental pollutants and lead to contamination in places where the environmental pollutants are not expected. However, this concern will not be realized until the contaminants are desorbed from CNTs. It is well recognized that the desorption of environmental pollutants from pre-laden CNTs varies with the environmental conditions, such as the solution pH and ionic strength. However, comprehensive investigation on the influence of solution chemistry on the desorption process has not been carried out, even though numerous investigations have been conducted to investigate the impact of solution chemistry on the adsorption of environmental pollutants on CNTs. The main objective of this study was to determine the influence of solution chemistry (e.g., pH, ionic strength and surface functionalization on the desorption of preloaded 1,3,5-trichlorobenzene (1,3,5-TCB from multi-walled carbon nanotubes (MWNTs. The results suggested that higher pH, ionic strength and natural organic matter in solution generally led to higher desorption of 1,3,5-TCB from MWNTs. However, the extent of change varied at different values of the tested parameters (e.g., pH 7. In addition, the impact of these parameters varied with MWNTs possessing different surface functional groups, suggesting that surface functionalization could considerably alter the environmental behaviors and impact of MWNTs.

  2. Determination of Surface Tension of Surfactant Solutions through Capillary Rise Measurements: An Image-Processing Undergraduate Laboratory Experiment

    Science.gov (United States)

    Huck-Iriart, Cristia´n; De-Candia, Ariel; Rodriguez, Javier; Rinaldi, Carlos

    2016-01-01

    In this work, we described an image processing procedure for the measurement of surface tension of the air-liquid interface using isothermal capillary action. The experiment, designed for an undergraduate course, is based on the analysis of a series of solutions with diverse surfactant concentrations at different ionic strengths. The objective of…

  3. Solution of the wave equation for open surfaces involving a line integral over the edge. [for supersonic propeller noise prediction

    Science.gov (United States)

    Farassat, F.

    1984-01-01

    A simple mathematical model of a stationary source distribution for the supersonic-propeller noise-prediction formula of Farassat (1983) is developed to test the validity of the formula solutions. The conventional thickness source term is used in place of the Isom thickness formula; the relative importance of the line and surface integrals in the solutions is evaluated; and the numerical results are compared with those obtained with a conventional retarded-time solution in tables. Good agreement is obtained over elevation angles from 10 to 90 deg, and the line-integral contribution is found to be significant at all elevation angles and of the same order of magnitude as the surface-integral contribution at angles less than 30 deg. The amplitude-normalized directivity patterns for the four cases computed (x = 1.5 or 10; k = 5.0 or 50) are presented graphically.

  4. Use of response surface methodology for optimization of fluoride adsorption in an aqueous solution by Brushite

    Directory of Open Access Journals (Sweden)

    M. Mourabet

    2017-05-01

    Full Text Available In the present study, Response surface methodology (RSM was employed for the removal of fluoride on Brushite and the process parameters were optimized. Four important process parameters including initial fluoride concentration (40–50 mg/L, pH (4–11, temperature (10–40 °C and B dose (0.05–0.15 g were optimized to obtain the best response of fluoride removal using the statistical Box–Behnken design. The experimental data obtained were analyzed by analysis of variance (ANOVA and fitted to a second-order polynomial equation using multiple regression analysis. Numerical optimization applying desirability function was used to identify the optimum conditions for maximum removal of fluoride. The optimum conditions were found to be initial concentration = 49.06 mg/L, initial solution pH = 5.36, adsorbent dose = 0.15 g and temperature = 31.96 °C. A confirmatory experiment was performed to evaluate the accuracy of the optimization procedure and maximum fluoride removal of 88.78% was achieved under the optimized conditions. Several error analysis equations were used to measure the goodness-of-fit. Kinetic studies showed that the adsorption followed a pseudo-second order reaction. The equilibrium data were analyzed using Langmuir, Freundlich, and Sips isotherm models at different temperatures. The Langmuir model was found to be describing the data. The adsorption capacity from the Langmuir isotherm (QL was found to be 29.212, 35.952 and 36.260 mg/g at 298, 303, and 313 K respectively.

  5. Contact Binary Asteroids

    Science.gov (United States)

    Rieger, Samantha

    2015-05-01

    Recent observations have found that some contact binaries are oriented such that the secondary impacts with the primary at a high inclination. This research investigates the evolution of how such contact binaries came to exist. This process begins with an asteroid pair, where the secondary lies on the Laplace plane. The Laplace plane is a plane normal to the axis about which the pole of a satellites orbit precesses, causing a near constant inclination for such an orbit. For the study of the classical Laplace plane, the secondary asteroid is in circular orbit around an oblate primary with axial tilt. This system is also orbiting the Sun. Thus, there are two perturbations on the secondarys orbit: J2 and third body Sun perturbations. The Laplace surface is defined as the group of orbits that lie on the Laplace plane at varying distances from the primary. If the secondary is very close to the primary, the inclination of the Laplace plane will be near the equator of the asteroid, while further from the primary the inclination will be similar to the asteroid-Sun plane. The secondary will lie on the Laplace plane because near the asteroid the Laplace plane is stable to large deviations in motion, causing the asteroid to come to rest in this orbit. Assuming the secondary is asymmetrical in shape and the bodys rotation is synchronous with its orbit, the secondary will experience the BYORP effect. BYORP can cause secular motion such as the semi-major axis of the secondary expanding or contracting. Assuming the secondary expands due to BYORP, the secondary will eventually reach the unstable region of the Laplace plane. The unstable region exists if the primary has an obliquity of 68.875 degrees or greater. The unstable region exists at 0.9 Laplace radius to 1.25 Laplace radius, where the Laplace radius is defined as the distance from the central body where the inclination of the Laplace plane orbit is half the obliquity. In the unstable region, the eccentricity of the orbit

  6. Effects of geometric modulation and surface potential heterogeneity on electrokinetic flow and solute transport in a microchannel

    Science.gov (United States)

    Bera, Subrata; Bhattacharyya, S.

    2018-04-01

    A numerical investigation is performed on the electroosmotic flow (EOF) in a surface-modulated microchannel to induce enhanced solute mixing. The channel wall is modulated by placing surface-mounted obstacles of trigonometric shape along which the surface potential is considered to be different from the surface potential of the homogeneous part of the wall. The characteristics of the electrokinetic flow are governed by the Laplace equation for the distribution of external electric potential; the Poisson equation for the distribution of induced electric potential; the Nernst-Planck equations for the distribution of ions; and the Navier-Stokes equations for fluid flow simultaneously. These nonlinear coupled set of governing equations are solved numerically by a control volume method over the staggered system. The influence of the geometric modulation of the surface, surface potential heterogeneity and the bulk ionic concentration on the EOF is analyzed. Vortical flow develops near a surface modulation, and it becomes stronger when the surface potential of the modulated region is in opposite sign to the surface potential of the homogeneous part of the channel walls. Vortical flow also depends on the Debye length when the Debye length is in the order of the channel height. Pressure drop along the channel length is higher for a ribbed wall channel compared to the grooved wall case. The pressure drop decreases with the increase in the amplitude for a grooved channel, but increases for a ribbed channel. The mixing index is quantified through the standard deviation of the solute distribution. Our results show that mixing index is higher for the ribbed channel compared to the grooved channel with heterogeneous surface potential. The increase in potential heterogeneity in the modulated region also increases the mixing index in both grooved and ribbed channels. However, the mixing performance, which is the ratio of the mixing index to pressure drop, reduces with the rise in

  7. Synchrotron Spectroscopic Studies of the Reaction of Cleaved Pyrite ( {FeS2}) Surfaces with Cr(VI) Solutions

    Science.gov (United States)

    Doyle, C. S.; Kendelewicz, T.; Bostick, B. C.; Brown, G. E.

    2002-12-01

    Pyrite is one of the most common sulfide ores, and the separation of valuable sulfide minerals from it has been an area of considerable interest for a long time. This extraction has led to a large quantity of pyrite waste, typically remaining in mine tailings piles which can interact with oxygen and surface water. The oxidation of pyrite under these conditions leads to the commonly known environmental problem of acid mine drainage, with acidification of surface waters, and the release of potentially toxic metals remaining within the pyrite matrix. A microscopic understanding of this oxidation process is extremely important and has been the aim of a number of studies. We apply the methods of synchrotron based surface science to this problem, utilizing surface sensitive photoemission and X-ray absorption spectroscopy to study the surface species present on the pyrite surface at the initial stages of oxidation. We have reacted pyrite surfaces with solutions containing chromate. Chromium exists in solution in two principal valence states, trivalent Cr(III) and hexavalent Cr(VI). Hexavalent chromium is itself considered an environmental problem due to its high toxicity and solubility, and thus mobility, whilst trivalent chromium is much less toxic and relatively insoluble. Hexavalent chromate is a strong oxidizing agent, and will react rapidly with the pyrite surface allowing the identification of oxidized iron and sulfur surface species. The possibility of using pyrite as a means of reducing chromate, and at the same time using chromate to passivate the pyrite surface to further oxidation through the buildup of a non-reactive iron-chromium (oxy)hydroxide layer will be investigated. The work was performed on rods cut from a natural pyrite single crystal from the Logroño region of Spain. The rods were then fractured over a reaction vessel, producing a fresh (100) surface for each experiment. The pyrite surfaces were reacted with 50 μM Cr(VI) solutions for 5 minutes at

  8. Effect of immersion time of restorative glass ionomer cements and immersion duration in calcium chloride solution on surface hardness.

    Science.gov (United States)

    Shiozawa, Maho; Takahashi, Hidekazu; Iwasaki, Naohiko; Wada, Takahiro; Uo, Motohiro

    2014-12-01

    The objective of this study was to evaluate the effect of immersion time of restorative glass ionomer cements (GICs) and immersion duration in calcium chloride (CaCl2) solution on the surface hardness. Two high-viscosity GICs, Fuji IX GP and GlasIonomer FX-II, were selected. Forty-eight specimens were randomly divided into two groups. Sixty minutes after being mixed, half of them were immersed in a 42.7wt% CaCl2 solution for 10, 30, or 60min (Group 1); the remaining specimens were immersed after an additional 1-week of storage (Group 2). The surface hardness of the specimens was measured and analyzed with two-way ANOVA and the Tukey HSD test (α=0.05). The surface compositions were examined using energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The surface hardness of Group 1 significantly increased as the immersion duration in CaCl2 increased; that of Group 2 significantly increased only after 60-minute CaCl2 immersion. After CaCl2 immersion, the amounts of Ca increased as the immersion duration increased. The surface hardness after CaCl2 immersion significantly correlated with the amount of Ca in Group 1, but not in Group 2. The binding energy of the Ca2p peak was similar to that of calcium polyalkenoate. These findings indicated that the Ca ions from the CaCl2 solution created chemical bonds with the carboxylic acid groups in the cement matrix. Immersion of GICs in CaCl2 solution at the early stage of setting was considered to enhance the formation of the polyacid salt matrix; as a result, the surface hardness increased. Copyright © 2014. Published by Elsevier Ltd.

  9. Binary Masking & Speech Intelligibility

    DEFF Research Database (Denmark)

    Boldt, Jesper

    The purpose of this thesis is to examine how binary masking can be used to increase intelligibility in situations where hearing impaired listeners have difficulties understanding what is being said. The major part of the experiments carried out in this thesis can be categorized as either experime......The purpose of this thesis is to examine how binary masking can be used to increase intelligibility in situations where hearing impaired listeners have difficulties understanding what is being said. The major part of the experiments carried out in this thesis can be categorized as either...... experiments under ideal conditions or as experiments under more realistic conditions useful for real-life applications such as hearing aids. In the experiments under ideal conditions, the previously defined ideal binary mask is evaluated using hearing impaired listeners, and a novel binary mask -- the target...... binary mask -- is introduced. The target binary mask shows the same substantial increase in intelligibility as the ideal binary mask and is proposed as a new reference for binary masking. In the category of real-life applications, two new methods are proposed: a method for estimation of the ideal binary...

  10. Examination and Manipulation of Protein Surface Charge in Solution with Electrospray Ionization Mass Spectrometry

    Science.gov (United States)

    Gross, Deborah S.; Van Ryswyk, Hal

    2014-01-01

    Electrospray ionization mass spectrometry (ESI-MS) is a powerful tool for examining the charge of proteins in solution. The charge can be manipulated through choice of solvent and pH. Furthermore, solution-accessible, protonated lysine side chains can be specifically tagged with 18-crown-6 ether to form noncovalent adducts. Chemical derivatization…

  11. Synthesis of silver particles on copper substrates using ethanol-based solution for surface-enhanced Raman spectroscopy

    Directory of Open Access Journals (Sweden)

    Li Chen

    2014-03-01

    Full Text Available The displacement reaction of AgNO3 and copper metal is an effective and economical way to fabricate Ag-Cu surface enhanced Raman scattering (SERS substrates. Aqueous solutions of AgNO3 are usually used for substrate preparation. In this work, a new method for Ag-Cu SERS substrate preparation is proposed, which uses an ethanol solution rather than an aqueous AgNO3 solution. Analysis of the surface morphologies of sample substrates by field emission scanning electron microscopy (FESEM showed that the silver nanoparticles prepared by this new method were more regular than those prepared in the traditional aqueous solution. The SERS spectra of Rhodamine 6G (R6G adsorbed on these Ag-Cu substrates were then investigated and compared. It was found that the Ag-Cu substrates prepared by this method provide significant improvements in Raman signal sensitivity and large-area uniformity. The enhancement factor of this new substrate is about 330 times higher than that prepared using an aqueous AgNO3 solution under identical experimental conditions. It was also found that 70% of the original sensitivity of the substrate remains after 15 days of exposure to air.

  12. Surface and adsorptive properties of Moringa oleifera bark for removal of V(V) from aqueous solutions.

    Science.gov (United States)

    Mnisi, Robert Londi; Ndibewu, Peter Papoh

    2017-11-04

    The bark of Moringa oleifera, a cheap and readily available natural biopolymeric resource material, found to significantly reduce coliform load and turbidity in contaminated water is investigated in this paper. Its surface and adsorptive properties are investigated to explore its adsorptive potential in removing V(V) from aqueous solutions. Surface properties were investigated using FTIR, HRSEM/EDS, IC, and BET-N 2 adsorption techniques. Adsorptive properties were investigated by optimizing adsorption parameters such as pH, temperature, initial metal concentration, and adsorbent dosage, using V(V) as an adsorbate. The adsorption-desorption isotherms are typical of type II with a H3 hysteresis loop and is characteristic of a largely macroporous material. Bottle ink pores are observed, which can provide good accessibility of the active sites, even though the internal BET surface area is typically low (1.79 g/m 2 ). Solution pH significantly influences the adsorptive potential of the material. The low surface area negatively impacts on the adsorption capacity, but is compensated for by the exchangeable anions (Cl - , F - , PO 4 3- , NO 3 - , and SO 4 2- ) and cations (Ca 2+ , K + , Mg 2+ , and Al 3+ ) at the surface and the accessibility of the active sites. Adsorption isotherm modeling show that the surface is largely heterogeneous with complex multiple sites and adsorption is not limited to monolayer.

  13. Analytical solutions for the surface response to small amplitude perturbations in boundary data in the shallow-ice-stream approximation

    Directory of Open Access Journals (Sweden)

    G. H. Gudmundsson

    2008-07-01

    Full Text Available New analytical solutions describing the effects of small-amplitude perturbations in boundary data on flow in the shallow-ice-stream approximation are presented. These solutions are valid for a non-linear Weertman-type sliding law and for Newtonian ice rheology. Comparison is made with corresponding solutions of the shallow-ice-sheet approximation, and with solutions of the full Stokes equations. The shallow-ice-stream approximation is commonly used to describe large-scale ice stream flow over a weak bed, while the shallow-ice-sheet approximation forms the basis of most current large-scale ice sheet models. It is found that the shallow-ice-stream approximation overestimates the effects of bed topography perturbations on surface profile for wavelengths less than about 5 to 10 ice thicknesses, the exact number depending on values of surface slope and slip ratio. For high slip ratios, the shallow-ice-stream approximation gives a very simple description of the relationship between bed and surface topography, with the corresponding transfer amplitudes being close to unity for any given wavelength. The shallow-ice-stream estimates for the timescales that govern the transient response of ice streams to external perturbations are considerably more accurate than those based on the shallow-ice-sheet approximation. In particular, in contrast to the shallow-ice-sheet approximation, the shallow-ice-stream approximation correctly reproduces the short-wavelength limit of the kinematic phase speed given by solving a linearised version of the full Stokes system. In accordance with the full Stokes solutions, the shallow-ice-sheet approximation predicts surface fields to react weakly to spatial variations in basal slipperiness with wavelengths less than about 10 to 20 ice thicknesses.

  14. Key parameters of the sediment surface morphodynamics in an estuary - An assessment of model solutions

    Science.gov (United States)

    Sampath, D. M. R.; Boski, T.

    2018-05-01

    Large-scale geomorphological evolution of an estuarine system was simulated by means of a hybrid estuarine sedimentation model (HESM) applied to the Guadiana Estuary, in Southwest Iberia. The model simulates the decadal-scale morphodynamics of the system under environmental forcing, using a set of analytical solutions to simplified equations of tidal wave propagation in shallow waters, constrained by empirical knowledge of estuarine sedimentary dynamics and topography. The key controlling parameters of the model are bed friction (f), current velocity power of the erosion rate function (N), and sea-level rise rate. An assessment of sensitivity of the simulated sediment surface elevation (SSE) change to these controlling parameters was performed. The model predicted the spatial differentiation of accretion and erosion, the latter especially marked in the mudflats within mean sea level and low tide level and accretion was mainly in a subtidal channel. The average SSE change mutually depended on both the friction coefficient and power of the current velocity. Analysis of the average annual SSE change suggests that the state of intertidal and subtidal compartments of the estuarine system vary differently according to the dominant processes (erosion and accretion). As the Guadiana estuarine system shows dominant erosional behaviour in the context of sea-level rise and sediment supply reduction after the closure of the Alqueva Dam, the most plausible sets of parameter values for the Guadiana Estuary are N = 1.8 and f = 0.8f0, or N = 2 and f = f0, where f0 is the empirically estimated value. For these sets of parameter values, the relative errors in SSE change did not exceed ±20% in 73% of simulation cells in the studied area. Such a limit of accuracy can be acceptable for an idealized modelling of coastal evolution in response to uncertain sea-level rise scenarios in the context of reduced sediment supply due to flow regulation. Therefore, the idealized but cost

  15. Mass transfer in fuel cells. [electron microscopy of components, thermal decomposition of Teflon, water transport, and surface tension of KOH solutions

    Science.gov (United States)

    Walker, R. D., Jr.

    1973-01-01

    Results of experiments on electron microscopy of fuel cell components, thermal decomposition of Teflon by thermogravimetry, surface area and pore size distribution measurements, water transport in fuel cells, and surface tension of KOH solutions are described.

  16. Molecular-scale model for the mass density of electrolyte solutions bound by clay surfaces: application to bentonites.

    Science.gov (United States)

    Gonçalvès, J; Rousseau-Gueutin, P

    2008-04-15

    A model to simulate the density of solutions adsorbed onto clay mineral surfaces is proposed. In this model, the alteration of the ionic distribution caused by the electric field associated with the surface charge of clay platelets is accounted for using an electrical triple-layer model with an overlapping diffuse layer. The combined effects of ion hydration and the electric field on the structure of water are introduced through their influence on the partial molar volume of water. This model, applied to Na-montmorillonite, simulates the distribution of the interplatelet solution density as a function of the distance to the mineral surface. High densities in the direct vicinity of the surface and slightly lower density (a few percent) than the normal density in the diffuse layer are obtained. These results show good consistency with the available data on bentonite and with the densities that can be inferred from molecular dynamics simulations. This model shows that the interplatelet distance plays an important role in the distribution of the mass density of the solution in the pore space of clay rocks.

  17. Colloidal stability of gold nanorod solution upon exposure to excised human skin: Effect of surface chemistry and protein adsorption.

    Science.gov (United States)

    Mahmoud, Nouf N; Al-Qaoud, Khaled M; Al-Bakri, Amal G; Alkilany, Alaaldin M; Khalil, Enam A

    2016-06-01

    In this study, we evaluated the colloidal stability of gold nanorods (with positive, negative and neutral surface charge) in solution upon contact with excised human skin. UV-vis absorption, plasmon peak broadening index (PPBI%) and transmission electron microscope analysis were used to follow nanoparticles aggregation in solution. Our results show that positively charged gold nanorods aggregate extensively upon exposure to excised human skin compared to negatively and neutrally charged gold nanorods. Skin-induced aggregation of cationic gold nanorods was linked to the adsorption of proteins released from the dermis layer to the surface of gold nanorods. Protein adsorption significantly screen nanorod's effective surface charge and induce their aggregation. Moreover, we demonstrate that the presence of polyethylene glycol polymer on the surface of cationic gold nanorods minimize this aggregation significantly by providing steric repulsion (non-electrostatic stabilization mechanism). This work highlights the importance of evaluating the colloidal stability of nanoparticles in solution upon contact with skin, which is a "usually overlooked" parameter when studying the nanoparticle-skin interaction. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Effects of surface treatment using aqua regia solution on the change of surface band bending of p-type GaN

    Science.gov (United States)

    Kim, Jong Kyu; Kim, Ki-Jeong; Kim, Bongsoo; Kim, Jae Nam; Kwak, Joon Seop; Park, Yong Jo; Lee, Jong-Lam

    2001-03-01

    Effects of surface treatment on the change of band bending at the surface of p-type GaN were studied using synchrotron radiation photoemission spectroscopy, and the results were used to interpret the reduction of contact resistivity by the surface treatment. The contact resistivity on p-type GaN decreased from (5.1±1.2)×10-1 to (9.3±3.5)×10-5Ω cm2 by the surface treatment using aqua regia prior to Pt deposition. Surface band bending was reduced by 0.58 eV and 0.87 eV after the surface treatments by HCl and aqua regia solutions, respectively. The atomic ratio of Ga/N decreased as the photoelectron detection angle was decreased, indicating that the surface oxide was mainly composed of Ga and O, GaOx, formed during high-temperature annealing for the generation of holes, and Ga vacancies, VGa, were produced below the GaOx layer. Consequently, the aqua regia treatment plays a role in removing GaOx formed on p-type GaN, leading to the shift of the Fermi level toward the energy levels of VGa located near the valence band edge. This causes the decrease of barrier height for the transport of holes, resulting in the good ohmic contacts to p-type GaN.

  19. Fluoro-apatite surface composition in aqueous solution deduced from potentiometric, electrokinetic, and solubility measurements, and spectroscopic observations

    International Nuclear Information System (INIS)

    Chairat, C.; Oelkers, E.H.; Schott, J.; Lartigue, J.E.

    2007-01-01

    The surface chemistry of fluoro-apatite in aqueous solution was investigated using electrokinetic techniques, potentiometric titrations, solubility measurements, and attenuated total reflection infrared spectroscopy. All methods indicate the formation of Ca/F depleted, P enriched altered layer via exchange reactions between H + and Ca 2+ , and OH - and F - at the fluoro-apatite (FAP) surface. Observations suggest that this leached layer has a di-calcium phosphate (CaHPO 4 ) composition and that it controls the apparent solubility of FAP. Electrokinetic measurements yield an iso-electric point value of 1 ± 0.5 consistent with a negatively charged FAP surface at pH ≥ 1. In contrast, surface titrations give an apparent pH of point of zero charge of similar to 7.7, consistent with a positively charged surface at pH ≤ 7.7. These differences are shown to stem from proton consumption by both proton exchange and dissolution reactions at the FAP surface. After taking account for these effects, FAP surface charge is shown to be negative to at least pH 4 by surface titration analysis. (authors)

  20. Wick rotations of solutions to the minimal surface equation, the zero ...

    Indian Academy of Sciences (India)

    60

    By (1) and the identity theorem, the right hand side of the above equation is equal to zero for any (x,y). Hence h satisfies (3). Solutions to (3) obtained from solutions to (1) as Propositions 1 and 2 are zero mean curvature graphs over a domain of the timelike tx-plane in L3(t,x,y). From now on, we study geometric properties of ...

  1. Binary colloidal crystals

    NARCIS (Netherlands)

    Christova-Zdravkova, C.G.

    2005-01-01

    Binary crystals are crystals composed of two types of particles having different properties like size, mass density, charge etc. In this thesis several new approaches to make binary crystals of colloidal particles that differ in size, material and charge are reported We found a variety of crystal

  2. Adsorption of TX-100 and SDBS on the surface of alumina and maghemite nanoparticles from aqueous solutions

    Directory of Open Access Journals (Sweden)

    R. R. Mansurov

    2014-11-01

    Full Text Available Adsorption equilibriums in aqueous aluminum and iron oxides nanosuspensions stabilized by SDBS and TX-100 were investigated using UV spectrophotometry. It was established that the non-ionic surfactant TritonX-100 is not adsorbed from aqueous solution on a hydrophilic surface of both aluminum and iron oxide nanoparticles. At the same time adsorption of the anionic surfactant SDBS was observed in both oxides nanoparticles. In the investigated range of concentrations adsorption isotherms SDBS from aqueous solution on the surfaces of nanoparticles Al2O3 and γ-Fe2O3 not reach saturation. The share of the particles surface occupied by surfactant molecules were estimated based on the value of an area of molecules SDBS in the adsorption layer, which was derived from the isotherm of surface tension (0.10 nm2. The calculations showed that at the investigated concentrations SDBS Al2O3 employed approximately 30 % of surface of nanoparticles, and for γ-Fe2O3 – up to 10%.

  3. The increase of surface area of a Brazilian palygorskite clay activated with sulfuric acid solutions using a factorial design

    Directory of Open Access Journals (Sweden)

    R. N. Oliveira

    2013-01-01

    Full Text Available Palygorskite is fibrous clay in which the structural tetrahedral and octahedral layers are organized in a way that structural channels are formed, leading to high surface area. However, impurities inside the channels and aggregated ones considerably reduce the available area. In order to increase the surface area, an activation treatment can be considered useful. The goal of this work is the activation of palygorskite from Guadalupe, Piauí, via sulfuric acid treatment using a two-level factorial design. The influence of three parameters (solution molarity, temperature and time on BET surface area was determined. Moreover, samples were characterized via X-ray diffraction (XRD and fluorescence (XRF, Fourier-transform infrared spectroscopy (FTIR and transmission electron microscopy (TEM. The largest surface area (282 m²/g without considerable changes in clay structure and morphology was found in a sample treated with 5M H2SO4 at 70°C for 1h. The main parameters that favored the improvement of the surface area were the solution's molarity, temperature and their interaction.

  4. Solution of underground mine gas emissions on surface of abandoned mining sites where steep deposited coal seams have been exploited

    Energy Technology Data Exchange (ETDEWEB)

    Takla, G.; Froml, K. [OKD, DPB, Paskov (Czech Republic)

    2005-07-01

    The solution of uncontrolled gas emissions from abandoned underground coal mine sites in Ostrava-Karvina coal-field to surface ground in connection with old mine shafts and drifts and with old mining workings in horizontal and inclined coal seams has many forms. It varies according to geological and mining conditions and the disposition of the site surface. Since four years the gas emission risk has appeared in the area of former exploited vertical coal seams within the historical centre of Orlova town, which is protected by State Monument Protection office. A project based on such special nature of mining-geological and urban conditions was elaborated and already implemented. (authors)

  5. Effect of hydrogen charging on the stability of SAE 10B22 steel surface in alkaline solutions

    International Nuclear Information System (INIS)

    Modiano, S.; Carreno, J.A.; Fugivara, C.S.; Benedetti, A.V.; Mattos, O.R.

    2005-01-01

    The influence of hydrogen charging into a quenched and tempered boron steel membrane electrode (SAE 10B22) was studied using borate buffer (pH 8.4) and NaOH solutions (pH 12.7), with or without the addition of 0.01 M EDTA. At the hydrogen input side, hydrogen charging influenced cyclic voltammograms increasing the anodic charge of iron(II) hydroxide formation, and decreasing the donor density of passive films. These results suggest that the hydrogen ingress caused instability of metallic surface, increasing the surface area activity

  6. Solution of underground mine gas emissions on surface of abandoned mining sites where steep deposited coal seams have been exploited

    International Nuclear Information System (INIS)

    Takla, G.; Froml, K.

    2005-01-01

    The solution of uncontrolled gas emissions from abandoned underground coal mine sites in Ostrava-Karvina coal-field to surface ground in connection with old mine shafts and drifts and with old mining workings in horizontal and inclined coal seams has many forms. It varies according to geological and mining conditions and the disposition of the site surface. Since four years the gas emission risk has appeared in the area of former exploited vertical coal seams within the historical centre of Orlova town, which is protected by State Monument Protection office. A project based on such special nature of mining-geological and urban conditions was elaborated and already implemented. (authors)

  7. Research note : Miscibility behaviour of binary mixtures of benzyl ...

    African Journals Online (AJOL)

    Miscibility of binary mixtures of benzyl benzoate and liquid paraffin as functions of temperature and composition has been determined using phase separation method. The binary mixtures demonstrated a critical (upper) solution temperature of 35 °C at 101325 Nm-2 with a mixing gap. A tie-line drawn at 28 °C across the ...

  8. Dimerization of tri(4-bromophenyl)benzene by aryl-aryl coupling from solution on a gold surface.

    Science.gov (United States)

    Russell, James C; Blunt, Matthew O; Garfitt, Jason M; Scurr, David J; Alexander, Morgan; Champness, Neil R; Beton, Peter H

    2011-03-30

    Monolayers of monomer 1,3,5-tri(4-bromophenyl)benzene (TBPB) and the dimerized product 3,3''',5,5'''-tetra(4-bromophenyl)quaterphenyl (TBPQ) on a gold surface have been studied using ambient scanning tunneling microscopy and time-of-flight secondary ion mass spectrometry (ToF-SIMS). Molecular layers are prepared by allowing sessile drops of solution to dry on a gold substrate. For room-temperature deposition we observe ordered arrays of TBPB in three distinct packing arrangements. Deposition on a heated substrate leads to the formation of the dimerized product, TBPQ, through a surface-induced aryl-aryl coupling. Regions of TBPQ coexist with regions of disordered multiply linked molecules. The conversion of monomer TPBP to dimers is confirmed using ToF-SIMS. Our results demonstrate an alternative, solution-phase approach to the formation of large molecules and nanostructures by coupling reactions.

  9. Surface Corrosion and Microstructure Degradation of Calcium Sulfoaluminate Cement Subjected to Wet-Dry Cycles in Sulfate Solution

    Directory of Open Access Journals (Sweden)

    Wuman Zhang

    2017-01-01

    Full Text Available The hydration products of calcium sulfoaluminate (CSA cement are different from those of Portland cement. The degradation of CSA cement subjected to wet-dry cycles in sulfate solution was studied in this paper. The surface corrosion was recorded and the microstructures were examined by scanning electron microscopy (SEM. The results show that SO42-, Na+, Mg2+, and Cl− have an effect on the stability of ettringite. In the initial period of sulfate attack, salt crystallization is the main factor leading to the degradation of CSA cement specimens. The decomposition and the carbonation of ettringite will cause long-term degradation of CSA cement specimens under wet-dry cycles in sulfate solution. The surface spalling and microstructure degradation increase significantly with the increase of wet-dry cycles, sulfate concentration, and water to cement ratio. Magnesium sulfate and sodium chloride reduce the degradation when the concentration of sulfate ions is a constant value.

  10. ACCESS MARS: Study of the viability of Mars Caves as an alternative to surface-based habitation solutions

    Science.gov (United States)

    Perez-Poch, Antoni; Laufer, Ren; Zavaleta, Jhony; Davila, Alfonso; Gallardo, Beatriz; Antonakopoulos, Konstantinos; de Carufel, Guy

    This paper summarizes a team project report that was produced during the Summer Space Program of the International Space University, held at NASA-Ames Research Center (CA, USA), by 56 students from 15 countries. Chair of the team project was René Laufer. Facilitators were Alfonso Dévila and Jhonny Zavaleta, and teacher associate supporting the team was a Beatriz Gallardo. Currently proposed Mars missions have identified a number of challenges such as high levels of radiation, harsh climate and limited launch windows. Recently discovered lava tubes on Mars present potential solutions to some of these issues, but raise a variety of intriguing new challenges. These encompass not only technological and engineering considerations, but also legal, ethical and societal issues such as planetary protection and crew safety. This paper assesses the feasibility of overcoming such challenges through the exploitation of Mars caves. Cave suitability is considered with respect to size, type, location and their potential to mitigate hazards. They are also assessed with respect to their potential for scientific work adhering to astrobiology guidelines and the search for extra-terrestrial life. This report compares surface and subsurface habitat options. Engineering challenges arising from the use of caves are addressed along with proposals for alternate architecture solutions. Different types of habitat are described and evaluated. The implications of sub-surface operations on thermal control, communications and power systems are investigated, and recommendations given. Crew selection, training methods and life support system solutions are also addressed. A Mission architecture analysis from the same Team Project is given in another paper from the same authors, at COSPAR 2010 B02 Technical Session. The ACCESS Mars Team concludes that using lava tubes as human habitats is not merely a viable habitat solution for a Mars expedition, but also potentially more beneficial than proposed

  11. Coupling Fluid and Solute Dynamics Within the Ocular Surface Tear Film: A Modelling Study of Black Line Osmolarity

    KAUST Repository

    Zubkov, V. S.

    2012-07-06

    We present a mathematical model describing the spatial distribution of tear film osmolarity across the ocular surface of a human eye during one blink cycle, incorporating detailed fluid and solute dynamics. Based on the lubrication approximation, our model comprises three coupled equations tracking the depth of the aqueous layer of the tear film, the concentration of the polar lipid, and the concentration of physiological salts contained in the aqueous layer. Diffusive boundary layers in the salt concentration occur at the thinnest regions of the tear film, the black lines. Thus, despite large Peclet numbers, diffusion ameliorates osmolarity around the black lines, but nonetheless is insufficient to eliminate the build-up of solute in these regions. More generally, a heterogeneous distribution of solute concentration is predicted across the ocular surface, indicating that measurements of lower meniscus osmolarity are not globally representative, especially in the presence of dry eye. Vertical saccadic eyelid motion can reduce osmolarity at the lower black line, raising the prospect that select eyeball motions more generally can assist in alleviating tear film hyperosmolarity. Finally, our results indicate that measured evaporative rates will induce excessive hyperosmolarity at the black lines, even for the healthy eye. This suggests that further evaporative retardation at the black lines, for instance due to the cellular glycocalyx at the ocular surface or increasing concentrations of mucus, will be important for controlling hyperosmolarity as the black line thins. © 2012 Society for Mathematical Biology.

  12. On the properties of two binary NiTi shape memory alloys. Effects of surface finish on the corrosion behaviour and in vitro biocompatibility.

    Science.gov (United States)

    Es-Souni, Mohammed; Es-Souni, Martha; Fischer-Brandies, Helge

    2002-07-01

    The present paper compares the transformation behaviour and mechanical properties of two orthodontic wires of close chemical compositions. The effects of surface topography and surface finish residues on the potentiodynamic corrosion behaviour and biocompatibility are also reported. The cytotoxicity tests were performed on both alloys in fibroblast cell cultures from human gingiva using the MTT test. It is shown that the surface finish and the amounts of surface finish residues affect dramatically the corrosion resistance. Bad surface finish results in lower corrosion resistance. The in vitro biocompatibility, though not affected to the extent of corrosion resistance, is also reduced as the surface roughness and the amounts of residues increase. This is thought to be due to surface effects on corrosion and metallic ions release.

  13. Influence of solvent polarization and non-uniform ion size on electrostatic properties between charged surfaces in an electrolyte solution

    Science.gov (United States)

    Sin, Jun-Sik

    2017-12-01

    In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using the mean-field approach accounting for solvent polarization and non-uniform size effects. Applying a free energy formalism accounting for unequal ion sizes and orientational ordering of water dipoles, we derive coupled and self-consistent equations to calculate electrostatic properties between charged surfaces. Electrostatic properties for similarly charged surfaces depend on the counterion size but not on the coion size. Moreover, electrostatic potential and osmotic pressure between similarly charged surfaces are found to be increased with increasing counterion size. On the other hand, the corresponding ones between oppositely charged surfaces are related to both sizes of positive and negative ions. For oppositely charged surfaces, the electrostatic potential, number density of solvent molecules, and relative permittivity of an electrolyte having unequal ion sizes are not symmetric about the centerline between the charged surfaces. For either case, the consideration of solvent polarization results in a decrease in the electrostatic potential and the osmotic pressure compared to the case without the effect.

  14. Antimicrobial Polymers in Solution and on Surfaces: Overview and Functional Principles

    Directory of Open Access Journals (Sweden)

    Felix Siedenbiedel

    2012-01-01

    Full Text Available The control of microbial infections is a very important issue in modern society. In general there are two ways to stop microbes from infecting humans or deteriorating materials—disinfection and antimicrobial surfaces. The first is usually realized by disinfectants, which are a considerable environmental pollution problem and also support the development of resistant microbial strains. Antimicrobial surfaces are usually designed by impregnation of materials with biocides that are released into the surroundings whereupon microbes are killed. Antimicrobial polymers are the up and coming new class of disinfectants, which can be used even as an alternative to antibiotics in some cases. Interestingly, antimicrobial polymers can be tethered to surfaces without losing their biological activity, which enables the design of surfaces that kill microbes without releasing biocides. The present review considers the working mechanisms of antimicrobial polymers and of contact-active antimicrobial surfaces based on examples of recent research as well as on multifunctional antimicrobial materials.

  15. On Possible Similarity Solutions for Three-Dimensional Incompressible Laminar Boundary-Layer Flows Over Developable Surfaces and with Proportional Mainstream Velocity Components

    Science.gov (United States)

    Hansen, Arthur G.

    1958-01-01

    Analysis is presented on the possible similarity solutions of the three-dimensional, laminar, incompressible, boundary-layer equations referred to orthogonal, curvilinear coordinate systems. Requirements of the existence of similarity solutions are obtained for the following: flow over developable surface and flow over non-developable surfaces with proportional mainstream velocity components.

  16. Effect of Surface Precipitate on the Crevice Corrosion in HYBRID and Oxalic Acid Solution

    International Nuclear Information System (INIS)

    Park, S. Y.; Jung, J. Y.; Won, H. J.; Kim, S. B.; Choi, W. K.; Moon, J. K.; Park, S. J.

    2015-01-01

    In this study, we investigated the characteristics of the crevice corrosion for Inconel-600 and 304SS in OA solution according to the change in pH. The evaluation of the crevice corrosion with the chemical thermodynamic analysis identified the effect of the residual chemicals such as iron-oxalate and nickeloxalate to the crevice corrosion behavior. Test results were compared with those of HYBRID (HYdrizine Base Reductive metal Ion Decontamination). The crevice corrosion properties of 304 SS and Inconel-600 in HYBRID and oxalic acid solution were evaluated. In case of oxalic acid solution, the corrosion rate on 304SS was rapidly increased with a pH decrease of around 2, but there was no increase in the corrosion rate on Inconel-600

  17. Analytical Solutions for the Surface States of Bi1-xSbx (0 ≤ x ≲ 0.1)

    Science.gov (United States)

    Fuseya, Yuki; Fukuyama, Hidetoshi

    2018-04-01

    Analytical solutions for the surface state (SS) of an extended Wolff Hamiltonian, which is a common Hamiltonian for strongly spin-orbit coupled systems, are obtained both for semi-infinite and finite-thickness boundary conditions. For the semi-infinite system, there are two types of SS solutions: (I-a) linearly crossing SSs in the direct bulk band gap, and (I-b) SSs with linear dispersions entering the bulk conduction or valence bands away from the band edge. For the finite-thickness system, a gap opens in the SS of solution I-a. Numerical solutions for the SS are also obtained based on the tight-binding model of Liu and Allen [https://doi.org/10.1103/PhysRevB.52.1566, Phys. Rev. B 52, 1566 (1995)] for Bi1-xSbx (0 ≤ x ≤ 0.1). A perfect correspondence between the analytic and numerical solutions is obtained around the \\bar{M} point including their thickness dependence. This is the first time that the character of the SS numerically obtained is identified with the help of analytical solutions. The size of the gap for I-a SS can be larger than that of bulk band gap even for a "thick" films ( ≲ 200 bilayers ≃ 80 nm) of pure bismuth. Consequently, in such a film of Bi1-xSbx, there is no apparent change in the SSs through the band inversion at x ≃ 0.04, even though the nature of the SS is changed from solution I-a to I-b. Based on our theoretical results, the experimental results on the SS of Bi1-xSbx (0 ≤ x ≲ 0.1) are discussed.

  18. Relationship between metal speciation in soil solution and metal adsorption at the root surface of ryegrass

    NARCIS (Netherlands)

    Kalis, E.J.J.; Temminghoff, E.J.M.; Town, R.M.; Unsworth, E.R.; Riemsdijk, van W.H.

    2008-01-01

    Received for publication October 12, 2007. The total metal content of the soil or total metal concentration in the soil solution is not always a good indicator for metal availability to plants. Therefore, several speciation techniques have been developed that measure a defined fraction of the total

  19. Absolute Dimensions of Contact Binary Stars in Baade Window

    Directory of Open Access Journals (Sweden)

    Young Woon Kang

    1999-12-01

    Full Text Available The light curves of the representative 6 contact binary stars observed by OGLE Project of searching for dark matter in our Galaxy have been analyzed by the method of the Wilson and Devinney Differential Correction to find photometric solutions. The orbital inclinations of these binaries are in the range of 52 deg - 69 deg which is lower than that of the solar neighborhood binaries. The Roche lobe filling factor of these binaries are distributed in large range of 0.12 - 0.90. Since absence of spectroscopic observations for these binaries we have found masses of the 6 binary systems based on the intersection between Kepler locus and locus derived from Vandenberg isochrones in the mass - luminosity plane. Then absolute dimensions and distances have been found by combining the masses and the photometric solutions. The distances of the 6 binary systems are distributed in the range of 1 kpc - 6 kpc. This distance range is the limiting range where the contact binaries which have period shorter than a day are visible. Most contact binaries discovered in the Baade window do not belong to the Galactic bulge.

  20. Numerical solutions for magnetohydrodynamic flow of nanofluid over a bidirectional non-linear stretching surface with prescribed surface heat flux boundary

    Energy Technology Data Exchange (ETDEWEB)

    Mahanthesh, B., E-mail: bmanths@gmail.com [Department of Mathematics, AIMS Institutes, Peenya, 560058 Bangalore (India); Department of Studies and Research in Mathematics, Kuvempu University, Shankaraghatta, 577451 Shimoga, Karnataka (India); Gireesha, B.J., E-mail: bjgireesu@rediffmail.com [Department of Studies and Research in Mathematics, Kuvempu University, Shankaraghatta, 577451 Shimoga, Karnataka (India); Department of Mechanical Engineering, Cleveland State University, Cleveland, OH (United States); Gorla, R.S. Reddy, E-mail: r.gorla@csuohio.edu [Department of Mechanical Engineering, Cleveland State University, Cleveland, OH (United States); Abbasi, F.M., E-mail: abbasisarkar@gmail.com [Department of Mathematics, Comsats Institute of Information Technology, Islamabad 44000 (Pakistan); Shehzad, S.A., E-mail: ali_qau70@yahoo.com [Department of Mathematics, Comsats Institute of Information Technology, Sahiwal 57000 (Pakistan)

    2016-11-01

    Numerical solutions of three-dimensional flow over a non-linear stretching surface are developed in this article. An electrically conducting flow of viscous nanoliquid is considered. Heat transfer phenomenon is accounted under thermal radiation, Joule heating and viscous dissipation effects. We considered the variable heat flux condition at the surface of sheet. The governing mathematical equations are reduced to nonlinear ordinary differential systems through suitable dimensionless variables. A well-known shooting technique is implemented to obtain the results of dimensionless velocities and temperature. The obtained results are plotted for multiple values of pertinent parameters to discuss the salient features of these parameters on fluid velocity and temperature. The expressions of skin-friction coefficient and Nusselt number are computed and analyzed comprehensively through numerical values. A comparison of present results with the previous results in absence of nanoparticle volume fraction, mixed convection and magnetic field is computed and an excellent agreement noticed. We also computed the results for both linear and non-linear stretching sheet cases. - Highlights: • Hydromagnetic flow of nanofluid over a bidirectional non-linear stretching surface is examined. • Cu, Al{sub 2}O3 and TiO{sub 2} types nanoparticles are taken into account. • Numerical solutions have been computed and addressed. • The values of skin-friction and Nusselt number are presented.

  1. Numerical solutions for magnetohydrodynamic flow of nanofluid over a bidirectional non-linear stretching surface with prescribed surface heat flux boundary

    International Nuclear Information System (INIS)

    Mahanthesh, B.; Gireesha, B.J.; Gorla, R.S. Reddy; Abbasi, F.M.; Shehzad, S.A.

    2016-01-01

    Numerical solutions of three-dimensional flow over a non-linear stretching surface are developed in this article. An electrically conducting flow of viscous nanoliquid is considered. Heat transfer phenomenon is accounted under thermal radiation, Joule heating and viscous dissipation effects. We considered the variable heat flux condition at the surface of sheet. The governing mathematical equations are reduced to nonlinear ordinary differential systems through suitable dimensionless variables. A well-known shooting technique is implemented to obtain the results of dimensionless velocities and temperature. The obtained results are plotted for multiple values of pertinent parameters to discuss the salient features of these parameters on fluid velocity and temperature. The expressions of skin-friction coefficient and Nusselt number are computed and analyzed comprehensively through numerical values. A comparison of present results with the previous results in absence of nanoparticle volume fraction, mixed convection and magnetic field is computed and an excellent agreement noticed. We also computed the results for both linear and non-linear stretching sheet cases. - Highlights: • Hydromagnetic flow of nanofluid over a bidirectional non-linear stretching surface is examined. • Cu, Al 2 O3 and TiO 2 types nanoparticles are taken into account. • Numerical solutions have been computed and addressed. • The values of skin-friction and Nusselt number are presented.

  2. Surface properties of aqueous amino acid solutions II. Leucine-leucine hydrochloride and leucine-sodium leucinate mixtures.

    Science.gov (United States)

    Matubayasi, Norihiro; Matsuyama, Shohei; Akizuki, Ryosuke

    2005-08-15

    To understand the distinction between the effects of zwitterionic, anionic, and cationic l-leucine upon adsorption and lateral interactions at air/water surface, the surface tensions of aqueous solutions of l-leucine-l-leucine hydrochloride and l-leucine-sodium l-leucinate mixtures were measured as a function of concentration and composition at 25 degrees C. The surface activity decreases in the order l-leucine >l-leucine hydrochloride > sodium l-leucinate. Both l-leucine hydrochloride and sodium l-leucinate form gaseous adsorbed films through the experimentally accessible concentration range, while the adsorbed film of zwitterionic l-leucine shows a transition between gaseous and expanded film.

  3. Antimicrobial Polymers in Solution and on Surfaces: Overview and Functional Principles

    OpenAIRE

    Felix Siedenbiedel; Joerg C. Tiller

    2012-01-01

    The control of microbial infections is a very important issue in modern society. In general there are two ways to stop microbes from infecting humans or deteriorating materials—disinfection and antimicrobial surfaces. The first is usually realized by disinfectants, which are a considerable environmental pollution problem and also support the development of resistant microbial strains. Antimicrobial surfaces are usually designed by impregnation of materials with biocides that are released into...

  4. The effects of the glass surface area/solution volume ratio on glass corrosion: A critical review

    Energy Technology Data Exchange (ETDEWEB)

    Ebert, W.L. [Argonne National Lab., IL (United States). Chemical Technology Div.

    1995-03-01

    This report reviews and summarizes the present state of knowledge regarding the effects of the glass surface area/solution volume (SA/V) ratio on the corrosion behavior of borosilicate waste glasses. The SA/V ratio affects the rate of glass corrosion through the extent of dilution of corrosion products released from the glass into the leachate solution: glass corrosion products are diluted more in tests conducted at low SA/V ratios than they are in tests conducted at high SA/V ratios. Differences in the solution chemistries generated in tests conducted at different SA/V ratios then affect the observed glass corrosion behavior. Therefore, any testing parameter that affects the solution chemistry will also affect the glass corrosion rate. The results of static leach tests conducted to assess the effects of the SA/V are discussed with regard to the effects of SA/V on the solution chemistry. Test results show several remaining issues with regard to the long-term glass corrosion behavior: can the SA/V ratio be used as an accelerating parameter to characterize the advanced stages of glass corrosion relevant to long disposal times; is the alteration of the glass surface the same in tests conducted at different SA/V, and in tests conducted with monolithic and crushed glass samples; what are the effects of the SA/V and the extent of glass corrosion on the disposition of released radionuclides? These issues will bear on the prediction of the long-term performance of waste glasses during storage. The results of an experimental program conducted at ANL to address these and other remaining issues regarding the effects of SA/V on glass corrosion are described. 288 refs., 59 figs., 16 tabs.

  5. Radiation induced segregation and point defects in binary copper alloys

    International Nuclear Information System (INIS)

    Monteiro, W.A.

    1984-01-01

    Considerable progress, both theoretical and experimental, has been made in establishing and understanding the influence of factors such as temperature, time, displacement rate dependence and the effect of initial solute misfit on radiation induced solute diffusion and segregation. During irradiation, the composition of the alloy changes locally, due to defect flux driven non-equilibrium segregation near sinks such as voids, external surfaces and grain boundaries. This change in composition could influence properties and phenomena such as ductility, corrosion resistance, stress corrosion cracking, sputtering and blistering of materials used in thermo-nuclear reactors. In this work, the effect of 1 MeV electron irradiation on the initiation and development of segregation and defect diffusion in binary copper alloys has been studied in situ, with the aid of a high voltage electron microscope. The binary copper alloys had Be, Pt and Sn as alloying elements which had atomic radii less than, similar and greater than that of copper, respectively. It has been observed that in a wide irradiation temperature range, stabilization and growth of dislocation loops took place in Cu-Sn and Cu-Pt alloys. Whereas in the Cu-Be alloy, radiation induced precipitates formed and transformed to the stable γ phase. (Author) [pt

  6. Evidence of nonspecific surface interactions between laser-polarized xenon and myoglobin in solution

    OpenAIRE

    Rubin, Seth M.; Spence, Megan M.; Goodson, Boyd M.; Wemmer, David E.; Pines, Alexander

    2000-01-01

    The high sensitivity of the magnetic resonance properties of xenon to its local chemical environment and the large 129Xe NMR signals attainable through optical pumping have motivated the use of xenon as a probe of macromolecular structure and dynamics. In the present work, we report evidence for nonspecific interactions between xenon and the exterior of myoglobin in aqueous solution, in addition to a previously reported internal binding interaction. 129Xe chemical shift measurements in denatu...

  7. Travelling wave solutions for a surface wave equation in fluid mechanics

    Directory of Open Access Journals (Sweden)

    Tian Yi

    2016-01-01

    Full Text Available This paper considers a non-linear wave equation arising in fluid mechanics. The exact traveling wave solutions of this equation are given by using G'/G-expansion method. This process can be reduced to solve a system of determining equations, which is large and difficult. To reduce this process, we used Wu elimination method. Example shows that this method is effective.

  8. Ion beam induced surface pattern formation and stable travelling wave solutions.

    Science.gov (United States)

    Numazawa, Satoshi; Smith, Roger

    2013-03-06

    The formation of ripple structures on ion bombarded semiconductor surfaces is examined theoretically. Previous models are discussed and a new nonlinear model is formulated, based on the infinitesimal local atomic relocation induced by elastic nuclear collisions in the early stages of collision cascades and an associated density change in the near surface region. Within this framework ripple structures are shown to form without the necessity to invoke surface diffusion or large sputtering as important mechanisms. The model can also be extended to the case where sputtering is important, and it is shown that in this case certain 'magic' angles can occur at which the ripple patterns are most clearly defined. The results are in very good agreement with experimental observations.

  9. BINARY MINOR PLANETS

    Data.gov (United States)

    National Aeronautics and Space Administration — The data set lists orbital and physical properties for well-observed or suspected binary/multiple minor planets including the Pluto system, compiled from the...

  10. Close binary stars

    International Nuclear Information System (INIS)

    Larsson-Leander, G.

    1979-01-01

    Studies of close binary stars are being persued more vigorously than ever, with about 3000 research papers and notes pertaining to the field being published during the triennium 1976-1978. Many major advances and spectacular discoveries were made, mostly due to increased observational efficiency and precision, especially in the X-ray, radio, and ultraviolet domains. Progress reports are presented in the following areas: observational techniques, methods of analyzing light curves, observational data, physical data, structure and models of close binaries, statistical investigations, and origin and evolution of close binaries. Reports from the Coordinates Programs Committee, the Committee for Extra-Terrestrial Observations and the Working Group on RS CVn binaries are included. (Auth./C.F.)

  11. Long-range attractive forces extending from the alumina’s nanolayer surface in aqueous solutions

    Directory of Open Access Journals (Sweden)

    Leonid A. Kaledin

    2015-07-01

    Full Text Available Aluminum oxide-hydroxide nanolayer with a thickness of approximately 1.2 nm is electroadhesively deposited onto silicious support material with large surface area of about 50 m2/g, forming a highly electropositive composite of boehmite nanolayer in the form of monocrystalline oxide/hydroxide (α-Al2O3·H2O on the second electronegative solid. The composite can be viewed as a sphere with a rough surface and charge density of approximately 0.08 C/m2. This creates a significant electric field with negligible screening (ka ≪ 1 in the region close to the surface of the nanocomposite. This field attracts nano- and micron-sized particles from as far as 200 μm in a few seconds, many orders of magnitude greater than conventional Derjaguin–Landau–Verwey–Overbeek (DLVO theory, which predicts only nanometer-scale effects arising from the presence of the surface. The strong electric field on the surface is then able to retain small particles such as viruses, atomically thin sheets of graphene oxide, RNA, DNA, proteins, dyes as well as heavy metals such as cobalt, arsenic, and lead. Alumina’s nanolayer surface can be further functionalized by adding other sub-micron or nano-sized particles to target a specific contaminant. An example is shown where alumina nanolayer is coated with nano-sized iron monohydrate to yield an arsenic sorbent that shows high sorption capacity.

  12. Binary and ternary systems

    International Nuclear Information System (INIS)

    Petrov, D.A.

    1986-01-01

    Conditions for thermodynamical equilibrium in binary and ternary systems are considered. Main types of binary and ternary system phase diagrams are sequently constructed on the basis of general regularities on the character of transition from one equilibria to others. New statements on equilibrium line direction in the diagram triple points and their isothermal cross sections are developed. New represenations on equilibria in case of monovariant curve minimum and maximum on three-phase equilibrium formation in ternary system are introduced

  13. Binary and Millisecond Pulsars

    OpenAIRE

    Lorimer, D. R.

    2005-01-01

    We review the main properties, demographics and applications of binary and millisecond radio pulsars. Our knowledge of these exciting objects has greatly increased in recent years, mainly due to successful surveys which have brought the known pulsar population to over 1800. There are now 83 binary and millisecond pulsars associated with the disk of our Galaxy, and a further 140 pulsars in 26 of the Galactic globular clusters. Recent highlights include the discovery of the young relativistic b...

  14. Astrophysics of white dwarf binaries

    NARCIS (Netherlands)

    Nelemans, G.A.

    2006-01-01

    White dwarf binaries are the most common compact binaries in the Universe and are especially important for low-frequency gravitational wave detectors such as LISA. There are a number of open questions about binary evolution and the Galactic population of white dwarf binaries that can be solved using

  15. Surface detail reproduction and dimensional accuracy of stone models: influence of disinfectant solutions and alginate impression materials.

    Science.gov (United States)

    Guiraldo, Ricardo Danil; Borsato, Thaís Teixeira; Berger, Sandrine Bittencourt; Lopes, Murilo Baena; Gonini, Alcides; Sinhoreti, Mário Alexandre Coelho

    2012-01-01

    This study compared the surface detail reproduction and dimensional accuracy of stone models obtained from molds disinfected with 2% sodium hypochlorite, 2% chlorhexidine digluconate or 0.2% peracetic acid to models produced using molds which were not disinfected, with 3 alginate materials (Cavex ColorChange, Hydrogum 5 and Jeltrate Plus). The molds were prepared over matrix containing 20-, 50-, and 75-µm lines, performed under pressure with perforated metal tray. The molds were removed following gelation and either disinfected (using one of the solutions by spraying followed by storage in closed jars for 15 min) or not disinfected. The samples were divided into 12 groups (n=5). Molds were filled with dental gypsum Durone IV and 1 h after the start of the stone mixing the models were separated from the tray. Surface detail reproduction and dimensional accuracy were evaluated using optical microscopy on the 50-µm line with 25 mm in length, in accordance with the ISO 1563 standard. The dimensional accuracy results (%) were subjected to ANOVA. The 50 µm-line was completely reproduced by all alginate impression materials regardless of the disinfection procedure. There was no statistically significant difference in the mean values of dimensional accuracy in combinations between disinfectant procedure and alginate impression material (p=0.2130) or for independent factors. The disinfectant solutions and alginate materials used in this study are no factors of choice regarding the surface detail reproduction and dimensional accuracy of stone models.

  16. Photosensitizing effects of nanometer TiO2 on chlorothalonil photodegradation in aqueous solution and on the surface of pepper.

    Science.gov (United States)

    Tan, Yong Qiang; Xiong, Hai Xia; Shi, Tao Zhong; Hua, Ri Mao; Wu, Xiang Wei; Cao, Hai Qun; Li, Xue De; Tang, Jun

    2013-05-29

    The present study examined the effects of anatase nanometer TiO2 on photochemical degradation of chlorothalonil in aqueous solution and on the plant surface. Results showed that nanometer TiO2 exhibited a strong photosensitizing effect on the degradation of chlorothalonil both in aqueous solution and on the surface of green pepper. The photosensitization rate was the highest in the sunlight compared to illumination under high-pressure mercury and UV lamps. Use of distinct hydroxyl radical scavengers indicated that nanometer TiO2 acted by producing hydroxyl radicals with strong oxidizing capacity. Notably, nanometer TiO2 facilitated complete photodegradation of chlorothalonil with no detectable accumulation of the intermediate chlorothalonil-4-hydroxy. Nanometer TiO2 was also active on the surface of green pepper under natural sunlight both inside and outside of plastic greenhouse. These results together suggest that nanometer TiO2 can be used as a photosensitizer to accelerate degradation of the pesticides under greenhouse conditions.

  17. Evolution of cataclysmic binaries

    International Nuclear Information System (INIS)

    Paczynski, B.

    1981-01-01

    Cataclysmic binaries with short orbital periods have low mass secondary components. Their nuclear time scale is too long to be of evolutionary significance. Angular momentum loss from the binary drives the mass transfer between the two components. As long as the characteristic time scale is compared with the Kelvin-Helmholtz time scale of the mass losing secondary the star remains close to the main sequence, and the binary period decreases with time. If angular momentum loss is due to gravitational radiation then the mass transfer time scale becomes comparable to the Kelvin-Helmoltz time scale when the secondary's mass decreases to 0.12 Msub(sun), and the binary period is reduced to 80 minutes. Later, the mass losing secondary departs from the main sequence and gradually becomes degenerate. Now the orbital period increases with time. The observed lower limit to the orbital periods of hydrogen rich cataclysmic binaries implies that gravitational radiation is the main driving force for the evolution of those systems. It is shown that binaries emerging from a common envelope phase of evolution are well detached. They have to lose additional angular momentum to become semidetached cataclysmic variables. (author)

  18. Spontaneous Structuration of Hydrophobic Polymer Surfaces in Contact with Salt Solutions

    NARCIS (Netherlands)

    Sîretanu, Igor; Saadaoui, Hassan; Chapel, Jean Paul; Drummond, Carlos; Rodriguez-Hernandez, Juan; Drummond, Carlos

    2015-01-01

    It has been described in previous chapters how spontaneous instabilities related to interfacial phenomena can be used to produce controlled patterns on polymer surfaces. Strategies of polymer patterning assisted by dewetting or water drop condensation were described. In this chapter we present a

  19. Harnessing surface-bound enzymatic reactions to organize microcapsules in solution.

    Science.gov (United States)

    Shklyaev, Oleg E; Shum, Henry; Sen, Ayusman; Balazs, Anna C

    2016-03-01

    By developing new computational models, we examine how enzymatic reactions on an underlying surface can be harnessed to direct the motion and organization of reagent-laden microcapsules in a fluid-filled microchannel. In the presence of appropriate reagents, surface-bound enzymes can act as pumps, which drive large-scale fluid flows. When the reagents diffuse through the capsules' porous shells, they can react with enzymatic sites on the bottom surface. The ensuing reaction generates fluid density variations, which result in fluid flows. These flows carry the suspended microcapsules and drive them to aggregate into "colonies" on and near the enzyme-covered sites. This aggregation continues until the reagent has been depleted and the convection stops. We show that the shape of the assembled colonies can be tailored by patterning the distribution of enzymes on the surface. This fundamental physicochemical mechanism could have played a role in the self-organization of early biological cells (protocells) and can be used to regulate the autonomous motion and targeted delivery of microcarriers in microfluidic devices.

  20. Finite-difference time domain solution of light scattering by arbitrarily shaped particles and surfaces

    DEFF Research Database (Denmark)

    Tanev, Stoyan; Sun, Wenbo

    2012-01-01

    This chapter reviews the fundamental methods and some of the applications of the three-dimensional (3D) finite-difference time-domain (FDTD) technique for the modeling of light scattering by arbitrarily shaped dielectric particles and surfaces. The emphasis is on the details of the FDTD algorithm...

  1. System DECON - an innovative solution for the decontamination of surfaces in buildings

    International Nuclear Information System (INIS)

    Schulz, T.; Schlag, J.

    2003-01-01

    One of the most important tasks in decommissioning nuclear facilities is, in disposal-oriented dismantling, the removal of contaminated surfaces. These coatings are traditionally removed manually by chiseling, abrasive blasting or sanding. With these processes it is often the case that the dust particles are then released into the air and settle on surrounding surfaces (secondary contamination); the material lands on the floor. The time limits set by the Nuclear Energy Withdrawal Act increase the demand by the industry for a suitable system for decontamination work. Since the end of 2000 the tool-head DECON 300 is being used in connection with a powerful DECON vacuum system from HOCHTIEF for decontamination work. The initial experiences were gained in the pilot nuclear plant Kahl (VAK) and in the former fuel rods factory NUKEM-Alt, Hanau, and the performance specifications determined. The system was used for both the removal of concrete as well as for the removal of the decontamination coating, bricks and plaster. With the DECON system the entire range of contaminated surfaces on floors, masonries and ceilings can be handled ''in situ''. The efficiency of this mechanical removal process is proven by the total of the removal performance, the quality of the surface, the lack of dust and handling, while simultaneously meeting the requirements of the StrSchV (German Radiation Protection Ordinance). (orig.)

  2. Simulation of surface-directed phase separation in a solution-processed polymer/PCBM blend

    NARCIS (Netherlands)

    Michels, J.J.; Moons, E.

    2013-01-01

    The formation of the surface-induced stratified lamellar composition profile experimentally evidenced in spincoated layers of the photovoltaic donor-acceptor blend consisting of poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-5,5- (4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole]/ phenyl-C61-butyric acid

  3. Structural changes and molecular interactions of hydrophobin SC3 in solution and on a hydrophobic surface

    NARCIS (Netherlands)

    Wang, X.; Vocht, M.L. de; Poolman, B.; Robillard, G.T.; Wang, [No Value; Jonge, J. de

    2002-01-01

    The hydrophobin SC3 belongs to a class of small proteins functioning in the growth and development of fungi. Its unique amphipathic property and remarkable surface activity make it interesting not only for biological studies but also for medical and industrial applications. Biophysical studies have

  4. Contact Antimicrobial Surface Obtained by Chemical Grafting of Microfibrillated Cellulose in Aqueous Solution Limiting Antibiotic Release.

    Science.gov (United States)

    Saini, Seema; Belgacem, Naceur; Mendes, Joana; Elegir, Graziano; Bras, Julien

    2015-08-19

    Contact active surfaces are an innovative tool for developing antibacterial products. Here, the microfibrillated cellulose (MFC) surface was modified with the β-lactam antibiotic benzyl penicillin in aqueous medium to prepare antimicrobial films. Penicillin was grafted on the MFC surface using a suspension of these nanofilaments or directly on films. Films prepared from the penicillin-modified MFC were characterized by Fourier transform infrared spectroscopy, contact angle measurements, elemental analysis, and X-ray photoelectron spectroscopy and tested for antibacterial activity against the Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli. Penicillin-grafted MFC films exhibited successful killing effect on Gram-positive bacteria with 3.5-log reduction whereas bacteriostatic efficiency was found in penicillin-grafted MFC suspension. The zone of inhibition test and leaching dynamic assay demonstrated that penicillin was not diffused into the surrounding media, thus proving that the films were indeed contact active. Thus, penicillin can be chemically bound to the modified substrate surface to produce promising nonleaching antimicrobial systems.

  5. Probing Earth’s conductivity structure beneath oceans by scalar geomagnetic data: autonomous surface vehicle solution

    DEFF Research Database (Denmark)

    Kuvshinov, Alexey; Matzka, Jürgen; Poedjono, Benny

    2016-01-01

    to the conductivity structure beneath the ocean. We conclude that the sensitivity, depending on the bathymetry gradient, is typically largest near the coast offshore. We show that such sea-surface marine induction surveys can be performed with the Wave Glider, an easy-to-deploy, autonomous, energy-harvesting floating...

  6. The application of surface science in the solution of aircraft materials problems

    International Nuclear Information System (INIS)

    Arnott, D.R.

    1999-01-01

    Full text: There is now a tendency for both commercial and military aircraft to be maintained and operated for several decades. Indeed some of our front-line defence aircraft have programme withdrawal lives approaching half a century. This places significant demands on the materials used in engines and airframes. The properties and performance of the materials can degrade with time leading to an increase in the importance of repair and maintenance technologies. As most materials problems start at a surface or an interface, it is not surprising that surface sensitive tools are used to resolve many degradation problems. In some cases, the resolution of problems can lead to life-enhancing improvements for the aircraft. This paper will examine some of the practical issues in the use of surface analytical tools for the examination and resolution of practical aircraft problems. Illustrations will be drawn from the application of surface analysis in the areas of corrosion, fracture and adhesive bonding. Copyright (1999) Australian X-ray Analytical Association Inc

  7. Rotation, activity, and lithium abundance in cool binary stars

    Science.gov (United States)

    Strassmeier, K. G.; Weber, M.; Granzer, T.; Järvinen, S.

    2012-10-01

    We have used two robotic telescopes to obtain time-series high-resolution optical echelle spectroscopy and V I and/or by photometry for a sample of 60 active stars, mostly binaries. Orbital solutions are presented for 26 double-lined systems and for 19 single-lined systems, seven of them for the first time but all of them with unprecedented phase coverage and accuracy. Eighteen systems turned out to be single stars. The total of 6609 {R=55 000} échelle spectra are also used to systematically determine effective temperatures, gravities, metallicities, rotational velocities, lithium abundances and absolute Hα-core fluxes as a function of time. The photometry is used to infer unspotted brightness, {V-I} and/or b-y colors, spot-induced brightness amplitudes and precise rotation periods. An extra 22 radial-velocity standard stars were monitored throughout the science observations and yield a new barycentric zero point for our STELLA/SES robotic system. Our data are complemented by literature data and are used to determine rotation-temperature-activity relations for active binary components. We also relate lithium abundance to rotation and surface temperature. We find that 74 % of all known rapidly-rotating active binary stars are synchronized and in circular orbits but 26 % (61 systems) are rotating asynchronously of which half have {P_rot>P_orb} and {e>0}. Because rotational synchronization is predicted to occur before orbital circularization active binaries should undergo an extra spin-down besides tidal dissipation. We suspect this to be due to a magnetically channeled wind with its subsequent braking torque. We find a steep increase of rotation period with decreasing effective temperature for active stars, P_rot ∝ T_eff-7, for both single and binaries, main sequence and evolved. For inactive, single giants with {P_rot>100} d, the relation is much weaker, {P_rot ∝ T_eff-1.12}. Our data also indicate a period-activity relation for Hα of the form {R_Hα ∝ P

  8. Lubrication model for evaporation of binary sessile drops

    Science.gov (United States)

    Williams, Adam; Sáenz, Pedro; Karapetsas, George; Matar, Omar; Sefiane, Khellil; Valluri, Prashant

    2017-11-01

    Evaporation of a binary mixture sessile drop from a solid substrate is a highly dynamic and complex process with flow driven both thermal and solutal Marangoni stresses. Experiments on ethanol/water drops have identified chaotic regimes on both the surface and interior of the droplet, while mixture composition has also been seen to govern drop wettability. Using a lubrication-type approach, we present a finite element model for the evaporation of an axisymmetric binary drop deposited on a heated substrate. We consider a thin drop with a moving contact line, taking also into account the commonly ignored effects of inertia which drives interfacial instability. We derive evolution equations for the film height, the temperature and the concentration field considering that the mixture comprises two ideally mixed volatile components with a surface tension linearly dependent on both temperature and concentration. The properties of the mixture such as viscosity also vary locally with concentration. We explore the parameter space to examine the resultant effects on wetting and evaporation where we find qualitative agreement with experiments in both these areas. This enables us to understand the nature of the instabilities that spontaneously emerge over the drop lifetime. EPSRC - EP/K00963X/1.

  9. An approximate analytical solution for describing surface runoff and sediment transport over hillslope

    Science.gov (United States)

    Tao, Wanghai; Wang, Quanjiu; Lin, Henry

    2018-03-01

    Soil and water loss from farmland causes land degradation and water pollution, thus continued efforts are needed to establish mathematical model for quantitative analysis of relevant processes and mechanisms. In this study, an approximate analytical solution has been developed for overland flow model and sediment transport model, offering a simple and effective means to predict overland flow and erosion under natural rainfall conditions. In the overland flow model, the flow regime was considered to be transitional with the value of parameter β (in the kinematic wave model) approximately two. The change rate of unit discharge with distance was assumed to be constant and equal to the runoff rate at the outlet of the plane. The excess rainfall was considered to be constant under uniform rainfall conditions. The overland flow model developed can be further applied to natural rainfall conditions by treating excess rainfall intensity as constant over a small time interval. For the sediment model, the recommended values of the runoff erosion calibration constant (cr) and the splash erosion calibration constant (cf) have been given in this study so that it is easier to use the model. These recommended values are 0.15 and 0.12, respectively. Comparisons with observed results were carried out to validate the proposed analytical solution. The results showed that the approximate analytical solution developed in this paper closely matches the observed data, thus providing an alternative method of predicting runoff generation and sediment yield, and offering a more convenient method of analyzing the quantitative relationships between variables. Furthermore, the model developed in this study can be used as a theoretical basis for developing runoff and erosion control methods.

  10. Development of binary and ternary titanium alloys for dental implants.

    Science.gov (United States)

    Cordeiro, Jairo M; Beline, Thamara; Ribeiro, Ana Lúcia R; Rangel, Elidiane C; da Cruz, Nilson C; Landers, Richard; Faverani, Leonardo P; Vaz, Luís Geraldo; Fais, Laiza M G; Vicente, Fabio B; Grandini, Carlos R; Mathew, Mathew T; Sukotjo, Cortino; Barão, Valentim A R

    2017-11-01

    The aim of this study was to develop binary and ternary titanium (Ti) alloys containing zirconium (Zr) and niobium (Nb) and to characterize them in terms of microstructural, mechanical, chemical, electrochemical, and biological properties. The experimental alloys - (in wt%) Ti-5Zr, Ti-10Zr, Ti-35Nb-5Zr, and Ti-35Nb-10Zr - were fabricated from pure metals. Commercially pure titanium (cpTi) and Ti-6Al-4V were used as controls. Microstructural analysis was performed by means of X-ray diffraction and scanning electron microscopy. Vickers microhardness, elastic modulus, dispersive energy spectroscopy, X-ray excited photoelectron spectroscopy, atomic force microscopy, surface roughness, and surface free energy were evaluated. The electrochemical behavior analysis was conducted in a body fluid solution (pH 7.4). The albumin adsorption was measured by the bicinchoninic acid method. Data were evaluated through one-way ANOVA and the Tukey test (α=0.05). The alloying elements proved to modify the alloy microstructure and to enhance the mechanical properties, improving the hardness and decreasing the elastic modulus of the binary and ternary alloys, respectively. Ti-Zr alloys displayed greater electrochemical stability relative to that of controls, presenting higher polarization resistance and lower capacitance. The experimental alloys were not detrimental to albumin adsorption. The experimental alloys are suitable options for dental implant manufacturing, particularly the binary system, which showed a better combination of mechanical and electrochemical properties without the presence of toxic elements. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  11. Evidence of nonspecific surface interactions between laser-polarized xenon and myoglobin in solution.

    Science.gov (United States)

    Rubin, S M; Spence, M M; Goodson, B M; Wemmer, D E; Pines, A

    2000-08-15

    The high sensitivity of the magnetic resonance properties of xenon to its local chemical environment and the large (129)Xe NMR signals attainable through optical pumping have motivated the use of xenon as a probe of macromolecular structure and dynamics. In the present work, we report evidence for nonspecific interactions between xenon and the exterior of myoglobin in aqueous solution, in addition to a previously reported internal binding interaction. (129)Xe chemical shift measurements in denatured myoglobin solutions and under native conditions with varying xenon concentrations confirm the presence of nonspecific interactions. Titration data are modeled quantitatively with treatment of the nonspecific interactions as weak binding sites. Using laser-polarized xenon to measure (129)Xe spin-lattice relaxation times (T(1)), we observed a shorter T(1) in the presence of 1 mM denatured apomyoglobin in 6 M deuterated urea (T(1) = 59 +/- 1 s) compared with that in 6 M deuterated urea alone (T(1) = 291 +/- 2 s), suggesting that nonspecific xenon-protein interactions can enhance (129)Xe relaxation. An even shorter T(1) was measured in 1 mM apomyoglobin in D(2)O (T(1) = 15 +/- 0.3 s), compared with that in D(2)O alone (T(1) = 506 +/- 5 s). This difference in relaxation efficiency likely results from couplings between laser-polarized xenon and protons in the binding cavity of apomyoglobin that may permit the transfer of polarization between these nuclei via the nuclear Overhauser effect.

  12. Induced alignment of a solution-cast discotic hexabenzocoronene derivative for electronic devices investigated by surface X-ray diffraction

    DEFF Research Database (Denmark)

    Bunk, Oliver; Nielsen, Martin Meedom; Sølling, Theis Ivan

    2003-01-01

    A surface X-ray diffraction study is presented showing that highly ordered and uniaxially aligned hexa(3,7-dimethyl-octanyl)hexa-peri-hexabenzocoronene (HBC-C8,2) films can be fabricated by crystallization from solution onto friction-transferred poly(tetrafluoroethylene) (PTFE) layers. Three...... crystalline HBC-C8,2 majority phases result. In all three phases, the HBC-C8,2 molecules self-organize into columns which are uniaxially aligned along the direction defined by the PTFE macromolecules of the substrate. The three phases are quite similar, the major difference being their orientation...

  13. Use of cadmium in solution in the EL 4 reactor moderator irreversible fixing of cadmium on the metallic surfaces; Utilisation du cadmium en solution dans le moderateur du reacteur EL 4 - fixation irreversible du cadmium sur les surfaces metalliques

    Energy Technology Data Exchange (ETDEWEB)

    Croix, O.; Paoli, O.; Lecomte, J.; Dolle, L.; Gallic, Y. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    In the framework of research into the poisoning of the EL-4 reactor by cadmium sulphate, measurements have been made by two different methods of the residual amounts of cadmium liable to be fixed irreversibly on the surfaces in contact with the heavy water. A marked influence of the pH has been noticed. The mechanism of the irreversible fixing is compatible with the hypothesis of an ion-exchange in the surface oxide layer. In a sufficiently wide range of pH the cadmium thus fixed causes very little residual poisoning. The stability of the cadmium sulphate solutions is however rather low in the conditions of poisoning. (authors) [French] Dans le cadre des etudes sur l'empoisonnement du reacteur EL-4 par le sulfate de cadmium, les quantites residuelles de cadmium susceptibles de se fixer irreversiblement sur les parois que mouillerait l'eau lourde, ont ete mesurees experimentalement par deux methodes differentes. On observe une influence nette du pH. Le mecanisme de la fixation irreversible est compatible avec l'hypothese d'un echange d'ions dans la pellicule d'oxyde superficielle. Dans des limites suffisamment larges de pH, la cadmium ainsi fixe n'occasionne pas d'empoisonnement residuel important. La stabilite des solutions de sulfate de cadmium dans les conditions de l'empoisonnement est cependant mediocre. (auteurs)

  14. An efficient solution to the decoherence enhanced trivial crossing problem in surface hopping

    Science.gov (United States)

    Bai, Xin; Qiu, Jing; Wang, Linjun

    2018-03-01

    We provide an in-depth investigation of the time interval convergence when both trivial crossing and decoherence corrections are applied to Tully's fewest switches surface hopping (FSSH) algorithm. Using one force-based and one energy-based decoherence strategies as examples, we show decoherence corrections intrinsically enhance the trivial crossing problem. We propose a restricted decoherence (RD) strategy and incorporate it into the self-consistent (SC) fewest switches surface hopping algorithm [L. Wang and O. V. Prezhdo, J. Phys. Chem. Lett. 5, 713 (2014)]. The resulting SC-FSSH-RD approach is applied to general Hamiltonians with different electronic couplings and electron-phonon couplings to mimic charge transport in tens to hundreds of molecules. In all cases, SC-FSSH-RD allows us to use a large time interval of 0.1 fs for convergence and the simulation time is reduced by over one order of magnitude. Both the band and hopping mechanisms of charge transport have been captured perfectly. SC-FSSH-RD makes surface hops in the adiabatic representation and can be implemented in both diabatic and locally diabatic representations for wave function propagation. SC-FSSH-RD can potentially describe general nonadiabatic dynamics of electrons and excitons in organics and other materials.

  15. Deciphering the role and nature of phosphate species at the surface of stainless steel immersed in phosphoric acid solutions

    Science.gov (United States)

    Liascukiene, I.; Ben Salah, M.; Sabot, R.; Refait, Ph.; Dhouibi, L.; Méthivier, C.; Landoulsi, J.; Jeannin, M.

    2018-03-01

    We investigate the evolution of the surface of a highly alloyed stainless steel (Sanicro 28) upon immersion in aqueous phosphoric acid solutions. For this purpose, both short- (few hours) and long-term immersion (several days) were carried out. A detailed analysis of XPS spectra allowed a distinction to be made between oxygen originating from the organic adlayer (adventitious contamination), the passive oxide layer, and adsorbed phosphate species. By estimating the fraction of oxygen due to phosphate species (Oph), it was shown that the Oph/P molar concentration ratio was ranging from about 2 to 3. This suggests the presence of a polyphosphate layer at the stainless steel surface, as also supported by Raman analysis, which influence the electrochemical behavior of SS in the acidic media.

  16. Characterization of interference thin films grown on stainless steel surface by alternate pulse current in a sulphochromic solution

    Directory of Open Access Journals (Sweden)

    Rosa Maria Rabelo Junqueira

    2008-12-01

    Full Text Available The aim of this work was to characterize thin interference films grown on the surface of AISI 304 stainless steel for decorative purposes. Films were grown in a sulphochromic solution at room temperature by an alternating pulse current method. The morphology and chemical state of the elements in the films were investigated by field emission scanning electron microscopy (FESEM, atomic force microscopy (AFM, glow discharge optical emission spectrometry (GDOES, and infrared Fourier transform spectroscopy (FTIR. Depth-sensing indentation (DSI experiments and wear abrasion tests were employed to assess the mechanical resistance of the films. The coloration process resulted in porous thin films which increased the surface roughness of the substrate. The interference films mainly consisted of hydrated chromium oxide containing iron. Increasing film thickness produced different colors and affected the mechanical properties of the coating-substrate system. Thicker films, such as those producing gold and green colors, were softer but more abrasion resistant.

  17. Boundary layers of aqueous surfactant and block copolymer solutions against hydrophobic and hydrophilic solid surfaces

    International Nuclear Information System (INIS)

    Steitz, Roland; Schemmel, Sebastian; Shi Hongwei; Findenegg, Gerhard H

    2005-01-01

    The boundary layer of aqueous surfactants and amphiphilic triblock copolymers against flat solid surfaces of different degrees of hydrophobicity was investigated by neutron reflectometry (NR), grazing incidence small angle neutron scattering (GISANS) and atomic force microscopy (AFM). Solid substrates of different hydrophobicities were prepared by appropriate surface treatment or by coating silicon wafers with polymer films of different chemical natures. For substrates coated with thin films (20-30 nm) of deuterated poly(styrene) (water contact angle θ w ∼ 90), neutron reflectivity measurements on the polymer/water interface revealed a water depleted liquid boundary layer of 2-3 nm thickness and a density about 90% of the bulk water density. No pronounced depletion layer was found at the interface of water against a less hydrophobic polyelectrolyte coating (θ w ∼ 63). It is believed that the observed depletion layer at the hydrophobic polymer/water interface is a precursor of the nanobubbles which have been observed by AFM at this interface. Decoration of the polymer coatings by adsorbed layers of nonionic C m E n surfactants improves their wettability by the aqueous phase at surfactant concentrations well below the critical micellar concentration (CMC) of the surfactant. Here, GISANS experiments conducted on the system SiO 2 /C 8 E 4 /D 2 O reveal that there is no preferred lateral organization of the C 8 E 4 adsorption layers. For amphiphilic triblock copolymers (PEO-PPO-PEO) it is found that under equilibrium conditions they form solvent-swollen brushes both at the air/water and the solid/water interface. In the latter case, the brushes transform to uniform, dense layers after extensive rinsing with water and subsequent solvent evaporation. The primary adsorption layers maintain properties of the precursor brushes. In particular, their thickness scales with the number of ethylene oxide units (EO) of the block copolymer. In the case of dip-coating without

  18. Surface controlled dissolution rates of gypsum in aqueous solutions exhibit nonlinear dissolution kinetics

    Science.gov (United States)

    Jeschke, Alexander A.; Vosbeck, Katrin; Dreybrodt, Wolfgang

    2001-01-01

    The effective dissolution rates of gypsum are determined by mixed kinetics, where the rate constants of dissolution at the surface and the transport constant of molecular diffusion of dissolved material are similar. To obtain the surface reaction rate law it is necessary to know the transport constant. We have determined the surface rate law for monocrystalline selenite by using a rotating disc set-up, where the transport coefficients are well known. As a result, up to a calcium concentration of 0.6 · ceq, we find a nearly linear rate law Rs = ksl (1- cs/ ceq) n1, where cs is the total calcium concentration at the surface and ceq the equilibrium concentration with respect to gypsum, n1 = 1.2 ± 0.2, and ksl = 1.1 · 10 -4 mmol cm -2 s -1 ± 15%. We also employed batch-experiments for selenite, alabaster and gypsum rock samples. The result of these experiments were interpreted by using a transport constant determined by NaCl dissolution experiments under similar physical conditions. The batch experiments reveal a dissolution rate law Rs = ksl (1- cs/ ceq) n1, ksl = 1.3 · 10 -4 mmol · cm -2 s -1, n1 = 1.2 ± 0.2 for c ≤ 0.94 · ceq. Close to equilibrium a nonlinear rate law, Rs = ks2 (1- cs/ ceq) n2, is observed, where ks2 is in the order of 10 mmol · cm -2 s -1 and n2 ≈ 4.5. The experimentally observed gypsum dissolution rates from the batch experiments could be accurately fitted, with only minor variations of the surface reaction constant obtained from the rotating disk experiment and the transport coefficient from the NaCl dissolution batch experiment. Batch experiments on pure synthetic gypsum, reveal a linear rate law up to equilibrium. This indicates inhibition of dissolution in natural samples close to equilibrium, as is known also for calcite minerals.

  19. Improved GaSb surfaces using a (NH4)2S/(NH4)2S04 solution

    International Nuclear Information System (INIS)

    Murape, D.M.; Eassa, N.; Nyamhere, C.; Neethling, J.H.; Betz, R.; Coetsee, E.; Swart, H.C.; Botha, J.R.; Venter, A.

    2012-01-01

    Bulk (1 0 0) n-GaSb surfaces have been treated with a sulphur based solution ((NH 4 ) 2 S/(NH 4 ) 2 SO 4 ) to which sulphur has been added, not previously reported for the passivation of GaSb surfaces. Au/n-GaSb Schottky barrier diodes (SBDs) fabricated on the treated material show significant improvement compared to that of the similar SBDs on the as-received material as evidenced by the lower ideality factor (n), higher barrier height (φ b ) and lower contact resistance obtained. Additionally, the reverse leakage current, although not saturating, has been reduced by almost an order of magnitude at −0.2 V. The sample surfaces were studied by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The native oxide, Sb–O, present on the as-received material is effectively removed on treating with ([(NH 4 ) 2 S/(NH 4 ) 2 SO 4 ]+S) and (NH 4 ) 2 S. Analysis of the as-received surface by XPS, prior to and after argon sputtering, suggests that the native oxide layer is ≤8.5 nm.

  20. Hydrogen Evolution Reaction Property in Alkaline Solution of Molybdenum Disulfide Modified by Surface Anchor of Nickel–Phosphorus Coating

    Directory of Open Access Journals (Sweden)

    Jun He

    2017-06-01

    Full Text Available Molybdenum disulfide (MoS2 is unfavorable for practical application in the hydrogen evolution reaction (HER process due to its inert basal surface, inferior conductivity, and limited amount of active edge sites. For the purpose of enhancing the HER performance of this catalyst, the HER activity of its basal surface should be increased. Herein, three types of nickel-phosphorus (Ni–P coatings—namely, low phosphorus (LP, medium phosphorus (MP and high phosphorus (HP —were anchored onto the surfaces of MoS2 nanoparticles via an electroless plating process; thus, three Ni–P/MoS2 composites (Ni–LP/MoS2, Ni–MP/MoS2, and Ni–HP/MoS2 were fabricated. Crystal structures, morphologies, chemical components, and HER performances of each in an alkaline solution were characterized. Both Ni–LP/MoS2 and Ni–MP/MoS2 showed a crystal nature, while the amorphous feature for Ni–HP/MoS2 was validated. The three Ni–P/MoS2 composites exhibited a higher HER activity than the pure MoS2. The HER performance of the Ni–MP/MoS2 composite was more outstanding than those of other two composites, which could be attributed to the presence of metastable nickel phosphides, and the excellent conductivity of Ni–MP coating anchored on the basal surface of MoS2.

  1. A space-charge treatment of the increased concentration of reactive species at the surface of a ceria solid solution

    Energy Technology Data Exchange (ETDEWEB)

    Zurhelle, Alexander F.; Souza, Roger A. de [Institute of Physical Chemistry, RWTH Aachen University (Germany); Tong, Xiaorui; Mebane, David S. [Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown, WV (United States); Klein, Andreas [Institute of Materials Science, TU Darmstadt (Germany)

    2017-11-13

    A space-charge theory applicable to concentrated solid solutions (Poisson-Cahn theory) was applied to describe quantitatively as a function of temperature and oxygen partial pressure published data obtained by in situ X-ray photoelectron spectroscopy (XPS) for the concentration of Ce{sup 3+} (the reactive species) at the surface of the oxide catalyst Ce{sub 0.8}Sm{sub 0.2}O{sub 1.9}. In contrast to previous theoretical treatments, these calculations clearly indicate that the surface is positively charged and compensated by an attendant negative space-charge zone. The high space-charge potential that develops at the surface (>0.8 V) is demonstrated to be hardly detectable by XPS measurements because of the short extent of the space-charge layer. This approach emphasizes the need to take into account defect interactions and to allow deviations from local charge neutrality when considering the surfaces of oxide catalysts. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  2. Potential dependence of surface crystal structure of iron passive films in borate buffer solution

    International Nuclear Information System (INIS)

    Deng, Huihua; Nanjo, Hiroshi; Qian, Pu; Santosa, Arifin; Ishikawa, Ikuo; Kurata, Yoshiaki

    2007-01-01

    The effect of passivation potential on surface crystal structure, apparent thickness and passivity of oxide films formed on pure iron prepared by plasma sputter deposition was investigated. The crystallinity was improved with passivation potential and the width of atomically flat terraces was expanded to 6 nm when passivating at 750 mV for 15 min, as observed by ex situ scanning tunneling microscopy (STM) after aging in air (<30% RH). Apparent thickness and passivity are linearly dependent on passivation potential. The former weakly depends on passivation duration, the latter strongly depends on passivation duration. This is well explained by the correlation between crystal structure and passivity

  3. Probing the surface of aqueous surfactant-perfume mixed solutions during perfume evaporation

    OpenAIRE

    Penfold, J; Thomas, RK; Bradbury, R; Tucker, I; Petkov, JT; Jones, CW; Webster, JRP

    2017-01-01

    The rate of release or evaporation of perfume molecules from surfaces is a key factor in determining the impact of the perfume in a range of applications relating to home and personal care products. For mixtures of the anionic surfactant sodium dodecylsulfate and the model perfume linalool the rate of change of adsorption with time due to forced air flow over a fixed headspace was evaluated using neutron reflectivity over a period of up to ∼250 min. The measurements were made in the limit of ...

  4. The Tarantula Massive Binary Monitoring. I. Observational campaign and OB-type spectroscopic binaries

    Science.gov (United States)

    Almeida, L. A.; Sana, H.; Taylor, W.; Barbá, R.; Bonanos, A. Z.; Crowther, P.; Damineli, A.; de Koter, A.; de Mink, S. E.; Evans, C. J.; Gieles, M.; Grin, N. J.; Hénault-Brunet, V.; Langer, N.; Lennon, D.; Lockwood, S.; Maíz Apellániz, J.; Moffat, A. F. J.; Neijssel, C.; Norman, C.; Ramírez-Agudelo, O. H.; Richardson, N. D.; Schootemeijer, A.; Shenar, T.; Soszyński, I.; Tramper, F.; Vink, J. S.

    2017-02-01

    Context. Massive binaries play a crucial role in the Universe. Knowing the distributions of their orbital parameters is important for a wide range of topics from stellar feedback to binary evolution channels and from the distribution of supernova types to gravitational wave progenitors, yet no direct measurements exist outside the Milky Way. Aims: The Tarantula Massive Binary Monitoring project was designed to help fill this gap by obtaining multi-epoch radial velocity (RV) monitoring of 102 massive binaries in the 30 Doradus region. Methods: In this paper we analyze 32 FLAMES/GIRAFFE observations of 93 O- and 7 B-type binaries. We performed a Fourier analysis and obtained orbital solutions for 82 systems: 51 single-lined (SB1) and 31 double-lined (SB2) spectroscopic binaries. Results: Overall, the binary fraction and orbital properties across the 30 Doradus region are found to be similar to existing Galactic samples. This indicates that within these domains environmental effects are of second order in shaping the properties of massive binary systems. A small difference is found in the distribution of orbital periods, which is slightly flatter (in log space) in 30 Doradus than in the Galaxy, although this may be compatible within error estimates and differences in the fitting methodology. Also, orbital periods in 30 Doradus can be as short as 1.1 d, somewhat shorter than seen in Galactic samples. Equal mass binaries (q> 0.95) in 30 Doradus are all found outside NGC 2070, the central association that surrounds R136a, the very young and massive cluster at 30 Doradus's core. Most of the differences, albeit small, are compatible with expectations from binary evolution. One outstanding exception, however, is the fact that earlier spectral types (O2-O7) tend to have shorter orbital periods than later spectral types (O9.2-O9.7). Conclusions: Our results point to a relative universality of the incidence rate of massive binaries and their orbital properties in the

  5. Proximity Operations in Microgravity, a Robotic Solution for Maneuvering about an Asteroid Surface

    Science.gov (United States)

    Indyk, Stephen; Scheidt, David; Moses, Kenneth; Perry, Justin; Mike, Krystal

    Asteroids remain some of the most under investigated bodies in the solar system. Addition-ally, there is a distinct lack of directly collected information. This is in part due to complex sampling and motion problems that must be overcome before more detailed missions can be formulated. The chief caveat lies in formulating a technique for precision operation in mi-crogravity. Locomotion, in addition to sample collection, involve forces significantly greater than the gravitational force keeping a robot on the surface. The design of a system that can successfully maneuver over unfamiliar surfaces void of natural anchor points is an incredible challenge. This problem was investigated at Johns Hopkins University Applied Physics Laboratory as part of the 2009 NASA Lunar and Planetary Academy. Examining the problem through a two-dimensional robotic simulation, a swarm robotics approach was applied. In simplest form, this was comprised of three grappling robots and one sampling robot. Connected by tethers, the grappling robots traverse a plane and reposition the sampling robot through tensioning the tethers. This presentation provides information on the design of the robotic system, as well as gait analysis and future considerations for a three dimensional system.

  6. A Maugis-Dugdale cohesive solution for adhesion of a surface with a dimple.

    Science.gov (United States)

    Papangelo, A; Ciavarella, M

    2017-02-01

    We study the adhesion of a surface with a 'dimple' which shows a mechanism for a bi-stable adhesive system in surfaces with spaced patterns of depressions, leading to adhesion enhancement, high dissipation and hysteresis. Recent studies were limited mainly to the very short range of adhesion (the so-called JKR regime), while we generalize the study to a Maugis cohesive model. A 'generalized Tabor parameter', given by the ratio of theoretical strength to elastic modulus, multiplied by the ratio of dimple width to depth has been found. It is shown that bistability disappears for generalized Tabor parameter less than about 2. Introduction of the theoretical strength is needed to have significant results when the system has gone in full contact, unless one postulates alternative limits to full contact, such as air entrapment, contaminants or fine scale roughness. Simple equations are obtained for the pull-off and for the full contact pressure in the entire set of the two governing dimensionless parameters. A qualitative comparison with results of recent experiments with nanopatterned bioinspired dry adhesives is attempted in light of the present model. © 2017 The Author(s).

  7. Binary Neutron Star Mergers

    Directory of Open Access Journals (Sweden)

    Joshua A. Faber

    2012-07-01

    Full Text Available We review the current status of studies of the coalescence of binary neutron star systems. We begin with a discussion of the formation channels of merging binaries and we discuss the most recent theoretical predictions for merger rates. Next, we turn to the quasi-equilibrium formalisms that are used to study binaries prior to the merger phase and to generate initial data for fully dynamical simulations. The quasi-equilibrium approximation has played a key role in developing our understanding of the physics of binary coalescence and, in particular, of the orbital instability processes that can drive binaries to merger at the end of their lifetimes. We then turn to the numerical techniques used in dynamical simulations, including relativistic formalisms, (magneto-hydrodynamics, gravitational-wave extraction techniques, and nuclear microphysics treatments. This is followed by a summary of the simulations performed across the field to date, including the most recent results from both fully relativistic and microphysically detailed simulations. Finally, we discuss the likely directions for the field as we transition from the first to the second generation of gravitational-wave interferometers and while supercomputers reach the petascale frontier.

  8. Skewed Binary Search Trees

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Moruz, Gabriel

    2006-01-01

    It is well-known that to minimize the number of comparisons a binary search tree should be perfectly balanced. Previous work has shown that a dominating factor over the running time for a search is the number of cache faults performed, and that an appropriate memory layout of a binary search tree...... can reduce the number of cache faults by several hundred percent. Motivated by the fact that during a search branching to the left or right at a node does not necessarily have the same cost, e.g. because of branch prediction schemes, we in this paper study the class of skewed binary search trees....... For all nodes in a skewed binary search tree the ratio between the size of the left subtree and the size of the tree is a fixed constant (a ratio of 1/2 gives perfect balanced trees). In this paper we present an experimental study of various memory layouts of static skewed binary search trees, where each...

  9. Magnetite nanoparticles supported on organically modified montmorillonite for adsorptive removal of iodide from aqueous solution: Optimization using response surface methodology.

    Science.gov (United States)

    Jang, Jiseon; Lee, Dae Sung

    2018-02-15

    Magnetite nanoparticles supported on organically modified montmorillonite (MNP-OMMTs) were successfully synthesized by a facile coprecipitation method. The surface of natural clay was modified using a cationic surfactant, hexadecyltrimethylammonium. The synthesized MNP-OMMTs were used as an adsorbent to remove iodide from aqueous solutions. The maximum adsorption capacity of the adsorbent was 322.42mg/g, which is much higher than other previously reported adsorbents for removing iodide in aqueous solution. The experimental data were well fitted to a pseudo-second-order kinetic model, and the adsorption behavior followed the Langmuir isotherm. A thermodynamic study indicated that iodide adsorption was spontaneous and endothermic. The individual and combined effects of key process parameters (pH, temperature, and initial iodide concentration) were studied using a response surface methodology. The maximum iodide removal efficiency of 93.81% was obtained under the optimal conditions of pH3.9, a temperature of 41.3°C, and an initial iodide concentration of 113.8mg/L. Copyright © 2017 Elsevier B.V. All rights reserved.

  10. Removal of Methyl Red from Aqueous Solution by Adsorption on Treated Banana Pseudo stem Fibers Using Response Surface Method (RSM)

    International Nuclear Information System (INIS)

    Zaida Rahayu Yet; Mohd Zulkhairi Abdul Rahim

    2014-01-01

    The effect of adsorbent dose, pH and contact times on the removal of Methyl Red (MR) from aqueous solution by using agriculture waste (NaOH treated banana pseudo stem fibers) were studied. The influence of these parameters on the removal of Methyl Red was examined by using a response surface method (RSM). The experiment was conducted by combining three parameters: adsorbent dose (500-1500 mg/L), pH (2-8) dan contact time (5-75 minutes ). The Box-Behnken Design (BBD) in Response Surface Methodology (RSM) by Design Expert Version 8.0.4 (Stat Ease, USA) was used for designing the experiments. Results showed that the optimum conditions for removal of Methyl Red from an aqueous solution (100 mg/L) were as follows: adsorbent dose (1417.70 mg/L), pH (2.08) and contact time (42.94 minutes) with the value of a coefficient of determination, R2 is 98.98 %. Meanwhile, the second-order polynomial equation indicates that pH and contact times mostly affect the removal of Methyl Red. (author)

  11. Oxidizing dissolution of spent MOX47 fuel subjected to water radiolysis: Solution chemistry and surface characterization by Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Jegou, C., E-mail: christophe.jegou@cea.f [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Caraballo, R.; De Bonfils, J.; Broudic, V.; Peuget, S. [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France); Vercouter, T. [Commissariat a l' Energie Atomique (CEA), Saclay Reasearch Center, B.P. 11, F-91191 Gif-sur-Yvette Cedex (France); Roudil, D. [Commissariat a l' Energie Atomique (CEA), Marcoule Reasearch Center, B.P. 17171, F-30207 Bagnols-sur-Ceze Cedex (France)

    2010-04-01

    The mechanisms of oxidizing dissolution of spent MOX fuel (MIMAS TU2 (registered) ) subjected to water radiolysis were investigated experimentally by leaching spent MOX47 fuel samples in pure water at 25 deg. C under different oxidizing conditions (with and without external gamma irradiation); the leached surfaces were characterized by Raman spectroscopy. The highly oxidizing conditions resulting from external gamma irradiation significantly increased the concentration of plutonium (Pu(V)) and uranium (U(VI)) compared with a benchmark experiment (without external irradiation). The oxidation behavior of the plutonium-enriched aggregates differed significantly from that of the UO{sub 2} matrix after several months of leaching in water under gamma irradiation. The plutonium in the aggregates appears to limit fuel oxidation. The only secondary phases formed and identified to date by Raman spectroscopy are uranium peroxides that generally precipitate on the surface of the UO{sub 2} grains. Concerning the behavior of plutonium, solution analysis results appear to be compatible with a conventional explanation based on an equilibrium with a Pu(OH){sub 4(am)} phase. The fission product release - considered as a general indicator of matrix alteration - from MOX47 fuel also increases under external gamma irradiation and a change in the leaching mode is observed. Diffusive leaching was clearly identified, coinciding with the rapid onset of steady-state actinide concentrations in the bulk solution.

  12. Sputtering yield calculation for binary target

    International Nuclear Information System (INIS)

    Jimenez-Rodriguez, J.J.; Rodriguez-Vidal, M.; Valles-Abarca, J.A.

    1979-01-01

    The generalization for binary targets, of the ideas proposed by Sigmund for monoatomic targets, leads to a set of coupled intergrodifferential equations for the sputtering functions. After moment decomposition, the final formulae are obtained by the standard method based on the Laplace Transform, where the inverse transform is made with the aid of asymptotic expansions in the limit of very high projectile energy as compared to the surface binding energy. The possible loss of stoichiometry for binary targets is analyzed. Comparison of computed values of sputtering yield for normal incidence, with experimental results shows good agreement. (author)

  13. Electrochemical characteristics of bioresorbable binary MgCa alloys in Ringer's solution: Revealing the impact of local pH distributions during in-vitro dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Mareci, D., E-mail: danmareci@yahoo.com [Faculty of Chemical Engineering and Environmental Protection, The “Gheorghe Asachi” Technical University of Iasi, 700050, Iasi (Romania); Bolat, G. [Faculty of Chemical Engineering and Environmental Protection, The “Gheorghe Asachi” Technical University of Iasi, 700050, Iasi (Romania); Izquierdo, J. [Department of Chemistry, University of La Laguna, P.O. Box 456, E-38200 La Laguna (Tenerife) (Spain); Crimu, C.; Munteanu, C. [Faculty of Mechanical Engineering, The “Gheorghe Asachi” Technical University of Iasi, 700050, Iasi (Romania); Antoniac, I. [Faculty of Materials Science and Engineering, Politehnica of Bucharest, 060042 Bucharest (Romania); Souto, R.M., E-mail: rsouto@ull.es [Department of Chemistry, University of La Laguna, P.O. Box 456, E-38200 La Laguna (Tenerife) (Spain); Faculty of Materials Science and Engineering, Politehnica of Bucharest, 060042 Bucharest (Romania)

    2016-03-01

    Biodegradable magnesium–calcium (MgCa) alloy is a very attractive biomaterial. Two MgCa alloys below the solid solubility of Ca were considered, as to solely investigate the effect of Ca content on the behavior of magnesium and the pH changes associated to metal dissolution. X-ray diffraction analysis and optical microscopy showed that both Mg–0.63Ca and Mg–0.89Ca alloys were solely composed of α(Mg) phase. Degradation characteristics and electrochemical characterization of MgCa alloys were investigated during exposure to Ringer's solution at 37 °C by electrochemical impedance spectroscopy and scanning electrochemical microscopy. The impedance behavior showed both capacitive and inductive features that are related to the alloy charge transfer reaction and the relaxation of the absorbed corrosion compounds, and can be described in terms of an equivalent circuit. Scanning electron microscopy (SEM) was employed to view the surface morphology of the MgCa samples after 1 week immersion in Ringer's solution showing extensive precipitation of corrosion products, whereas the substrate shows evidence of a non-uniform corrosion process. Energy dispersive analysis showed that the precipitates contained oxygen, calcium, magnesium and chlorine, and the Mg:Ca ratios were smaller than in the alloys. Scanning electrochemical microscopy (SECM) was used to visualize local pH changes associated to these physicochemical processes with high spatial resolution. The occurrence of pH variations in excess of 3 units between anodic and cathodic half-cell reactions was monitored in situ. - Highlights: • Spontaneous degradation of MgCa alloys in Ringer's solution characterized at 37 °C • Reactivity differences between Mg0.63Ca and Mg0.89Ca are evidenced using multiscale electrochemical characterization. • Electrochemical activation occurs heterogeneously on the alloy surface. • Metal dissolution is accompanied by local pH changes. • Mg0.63Ca degrades faster

  14. Modelling binary data

    CERN Document Server

    Collett, David

    2002-01-01

    INTRODUCTION Some Examples The Scope of this Book Use of Statistical Software STATISTICAL INFERENCE FOR BINARY DATA The Binomial Distribution Inference about the Success Probability Comparison of Two Proportions Comparison of Two or More Proportions MODELS FOR BINARY AND BINOMIAL DATA Statistical Modelling Linear Models Methods of Estimation Fitting Linear Models to Binomial Data Models for Binomial Response Data The Linear Logistic Model Fitting the Linear Logistic Model to Binomial Data Goodness of Fit of a Linear Logistic Model Comparing Linear Logistic Models Linear Trend in Proportions Comparing Stimulus-Response Relationships Non-Convergence and Overfitting Some other Goodness of Fit Statistics Strategy for Model Selection Predicting a Binary Response Probability BIOASSAY AND SOME OTHER APPLICATIONS The Tolerance Distribution Estimating an Effective Dose Relative Potency Natural Response Non-Linear Logistic Regression Models Applications of the Complementary Log-Log Model MODEL CHECKING Definition of Re...

  15. Evolution of dwarf binaries

    International Nuclear Information System (INIS)

    Tutukov, A.V.; Fedorova, A.V.; Yungel'son, L.R.

    1982-01-01

    The conditions of mass exchange in close binary systems with masses of components less or equal to one solar mass have been analysed for the case, when the system radiates gravitational waves. It has been shown that the mass exchange rate depends in a certain way on the mass ratio of components and on the mass of component that fills its inner critical lobe. The comparison of observed periods, masses of contact components, and mass exchange rates of observed cataclysmic binaries have led to the conclusion that the evolution of close binaries WZ Sge, OY Car, Z Cha, TT Ari, 2A 0311-227, and G 61-29 may be driven by the emission of gravitational waves [ru

  16. Evolution of dwarf binaries

    International Nuclear Information System (INIS)

    Tutukov, A.V.; Fedorova, A.V.; Yungel'son, L.R.

    1982-01-01

    The circumstances of mass exchange in close binary systems whose components have a mass < or approx. =1 M/sub sun/ are analyzed for the case where the system is losing orbital angular momentum by radiation of gravitational waves. The mass exchange rate will depend on the mass ratio of the components and on the mass of the component that is overfilling its critical Roche lobe. A comparison of the observed orbital periods, masses of the components losing material, and mass exchange rates against the theoretical values for cataclysmic binaries indicates that the evolution of the close binaries WZ Sge, OY Car, Z Cha, TT Ari, 2A 0311-227, and G61-29 may be driven by the emission of gravitational waves

  17. Binary and Millisecond Pulsars

    Directory of Open Access Journals (Sweden)

    Lorimer Duncan R.

    2008-11-01

    Full Text Available We review the main properties, demographics and applications of binary and millisecond radio pulsars. Our knowledge of these exciting objects has greatly increased in recent years, mainly due to successful surveys which have brought the known pulsar population to over 1800. There are now 83 binary and millisecond pulsars associated with the disk of our Galaxy, and a further 140 pulsars in 26 of the Galactic globular clusters. Recent highlights include the discovery of the young relativistic binary system PSR J1906+0746, a rejuvination in globular cluster pulsar research including growing numbers of pulsars with masses in excess of 1.5M_⊙, a precise measurement of relativistic spin precession in the double pulsar system and a Galactic millisecond pulsar in an eccentric (e = 0.44 orbit around an unevolved companion.

  18. The COBAIN (COntact Binary Atmospheres with INterpolation) Code for Radiative Transfer

    Science.gov (United States)

    Kochoska, Angela; Prša, Andrej; Horvat, Martin

    2018-01-01

    Standard binary star modeling codes make use of pre-existing solutions of the radiative transfer equation in stellar atmospheres. The various model atmospheres available today are consistently computed for single stars, under different assumptions - plane-parallel or spherical atmosphere approximation, local thermodynamical equilibrium (LTE) or non-LTE (NLTE), etc. However, they are nonetheless being applied to contact binary atmospheres by populating the surface corresponding to each component separately and neglecting any mixing that would typically occur at the contact boundary. In addition, single stellar atmosphere models do not take into account irradiance from a companion star, which can pose a serious problem when modeling close binaries. 1D atmosphere models are also solved under the assumption of an atmosphere in hydrodynamical equilibrium, which is not necessarily the case for contact atmospheres, as the potentially different densities and temperatures can give rise to flows that play a key role in the heat and radiation transfer.To resolve the issue of erroneous modeling of contact binary atmospheres using single star atmosphere tables, we have developed a generalized radiative transfer code for computation of the normal emergent intensity of a stellar surface, given its geometry and internal structure. The code uses a regular mesh of equipotential surfaces in a discrete set of spherical coordinates, which are then used to interpolate the values of the structural quantites (density, temperature, opacity) in any given point inside the mesh. The radiaitive transfer equation is numerically integrated in a set of directions spanning the unit sphere around each point and iterated until the intensity values for all directions and all mesh points converge within a given tolerance. We have found that this approach, albeit computationally expensive, is the only one that can reproduce the intensity distribution of the non-symmetric contact binary atmosphere and

  19. Impacts of anions on the oxygen reduction reaction kinetics on platinum and palladium surfaces in alkaline solutions.

    Science.gov (United States)

    Zhu, Shangqian; Hu, Xiaomeng; Shao, Minhua

    2017-03-15

    The fundamental understanding of the impacts induced by anions on oxygen reduction reaction (ORR) in alkaline media is of great importance in the design of more advanced catalysts for alkaline fuel cells (AFC). In this study, the specific adsorption of F - , Cl - , ClO 4 - , CO 3 2- , SO 4 2- , and citrate anions on Pt/C and Pd/C catalysts, and their impacts on the ORR kinetics in alkaline solutions were systematically studied. It was found that F - , Cl - and ClO 4 - did not specifically adsorb on Pt or Pd surfaces and had no poisoning effect on ORR. CO 3 2- and SO 4 2- had significant effects on Pt/C and lowered the activity even at a very low concentration. On the other hand, their impacts on Pd/C were negligible. Self-dissociation of citrate anions was found to occur on both Pt/C and Pd/C in the H adsorption/desorption and double layer regions. For the first time, surface enhanced infrared absorption spectroscopy (SEIRAS) with the attenuated total reflection (ATR) technique was used to investigate the self-dissociation of citrate on Pt and Pd thin film electrodes. The breaking of carboxylic groups and the carbon backbone was proposed as a possible dissociation pathway for citrate. The adsorbed species have a negligible effect on ORR activity on Pt/C as they are removed by oxidation before 0.75 V. In contrast, their oxidation on Pd/C surfaces is not completed until 0.91 V, which causes a lower ORR activity observed in rotating disk electrode measurements. The findings in this paper emphasize the importance of specific adsorption of anions and double-layer interfacial effects on the ORR activity measurement in alkaline solutions.

  20. The Brightest Binaries

    Science.gov (United States)

    Vanbeveren, D., Van Rensbergen, W., De Loore, C.

    Massive stars are distributed all over the upper part of the Hertzsprung-Russell diagram according to their subsequent phases of stellar evolution from main sequence to supernova. Massive stars may either be single or they may be a component of a close binary. The observed single star/binary frequency is known only in a small part of the Galaxy. Whether this holds for the whole galaxy or for the whole cosmos is questionable and needs many more high quality observations. Massive star evolution depends critically on mass loss by stellar wind and this stellar wind mass loss may change dramatically when stars evolve from one phase to another. We start the book with a critical discussion of observations of the different types of massive stars, observations that are of fundamental importance in relation to stellar evolution, with special emphasis on mass loss by stellar wind. We update our knowledge of the physics that models the structure and evolution of massive single stars and we present new calculations. The conclusions resulting from a comparison between these calculations and observations are then used to study the evolution of massive binaries. This book provides our current knowledge of a great variety of massive binaries, and hence of a great variety of evolutionary phases. A large number of case studies illustrates the existence of these phases. Finally, we present the results of massive star population number synthesis, including the effect of binaries. The results indicate that neglecting them leads to a conclusion which may be far from reality. This book is written for researchers in massive star evolution. We hope that, after reading this book, university-level astrophysics students will become fascinated by the exciting world of the `Brightest Binaries'.

  1. Encounters of binaries

    International Nuclear Information System (INIS)

    Mikkola, S.

    1983-01-01

    Gravitational encounters of pairs of binaries have been studied numerically. Various cross-sections have been calculated for qualitative final results of the interaction and for energy transfer between the binding energy and the centre of mass kinetic energy. The distribution of the kinetic energies, resulting from the gravitational collision, were found to be virtually independent of the impact velocity in the case of collision of hard binaries. It was found that one out of five collisions, which are not simple fly-by's, leads to the formation of a stable three-body system. (author)

  2. Binary and Millisecond Pulsars

    Directory of Open Access Journals (Sweden)

    Duncan R. Lorimer

    1998-09-01

    Full Text Available Our knowledge of binary and millisecond pulsars has greatly increased in recent years. This is largely due to the success of large-area surveys which have brought the known population of such systems in the Galactic disk to around 50. As well as being interesting as a population of astronomical sources, many pulsars turn out to be superb celestial clocks. In this review we summarise the main properties of binary and millisecond pulsars and highlight some of their applications to relativistic astrophysics.

  3. Binary and Millisecond Pulsars

    Directory of Open Access Journals (Sweden)

    Lorimer Duncan R.

    2005-11-01

    Full Text Available We review the main properties, demographics and applications of binary and millisecond radio pulsars. Our knowledge of these exciting objects has greatly increased in recent years, mainly due to successful surveys which have brought the known pulsar population to over 1700. There are now 80 binary and millisecond pulsars associated with the disk of our Galaxy, and a further 103 pulsars in 24 of the Galactic globular clusters. Recent highlights have been the discovery of the first ever double pulsar system and a recent flurry of discoveries in globular clusters, in particular Terzan 5.

  4. Surface Tension of Binary Mixtures Including Polar Components Modeled by the Density Gradient Theory Combined with the PC-SAFT Equation of State

    Czech Academy of Sciences Publication Activity Database

    Vinš, Václav; Planková, Barbora; Hrubý, Jan

    2013-01-01

    Roč. 34, č. 5 (2013), s. 792-812 ISSN 0195-928X R&D Projects: GA AV ČR IAA200760905; GA ČR(CZ) GPP101/11/P046; GA ČR GA101/09/1633 Institutional research plan: CEZ:AV0Z20760514 Institutional support: RVO:61388998 Keywords : chemical polarity * gradient theory * surface tension Subject RIV: BJ - Thermodynamics Impact factor: 0.623, year: 2013 http://www.springerlink.com/openurl.asp?genre=article&id=doi:10.1007/s10765-012-1207-z

  5. Detection of low-concentration contaminants in solution by exploiting chemical derivatization in surface-enhanced Raman spectroscopy.

    Science.gov (United States)

    Hardy, Mike; Doherty, Matthew D; Krstev, Igor; Maier, Konrad; Möller, Torgny; Müller, Gerhard; Dawson, Paul

    2014-09-16

    A simple derivatization methodology is shown to extend the application of surface-enhanced Raman spectroscopy (SERS) to the detection of trace concentration of contaminants in liquid form. Normally in SERS the target analyte species is already present in the molecular form in which it is to be detected and is extracted from solution to occupy sites of enhanced electromagnetic field on the substrate by means of chemisorption or drop-casting and subsequent evaporation of the solvent. However, these methods are very ineffective for the detection of low concentrations of contaminant in liquid form because the target (ionic) species (a) exhibits extremely low occupancy of enhancing surface sites in the bulk liquid environment and (b) coevaporates with the solvent. In this study, the target analyte species (acid) is detected via its solid derivative (salt) offering very significant enhancement of the SERS signal because of preferential deposition of the salt at the enhancing surface but without loss of chemical discrimination. The detection of nitric acid and sulfuric acid is demonstrated down to 100 ppb via reaction with ammonium hydroxide to produce the corresponding ammonium salt. This yields an improvement of ~4 orders of magnitude in the low-concentration detection limit compared with liquid phase detection.

  6. Orbital motion in pre-main sequence binaries

    Energy Technology Data Exchange (ETDEWEB)

    Schaefer, G. H. [The CHARA Array of Georgia State University, Mount Wilson Observatory, Mount Wilson, CA 91023 (United States); Prato, L. [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Simon, M. [Department of Physics and Astronomy, Stony Brook University, Stony Brook, NY 11794 (United States); Patience, J., E-mail: schaefer@chara-array.org [Astrophysics Group, School of Physics, University of Exeter, Exeter, EX4 4QL (United Kingdom)

    2014-06-01

    We present results from our ongoing program to map the visual orbits of pre-main sequence (PMS) binaries in the Taurus star forming region using adaptive optics imaging at the Keck Observatory. We combine our results with measurements reported in the literature to analyze the orbital motion for each binary. We present preliminary orbits for DF Tau, T Tau S, ZZ Tau, and the Pleiades binary HBC 351. Seven additional binaries show curvature in their relative motion. Currently, we can place lower limits on the orbital periods for these systems; full solutions will be possible with more orbital coverage. Five other binaries show motion that is indistinguishable from linear motion. We suspect that these systems are bound and might show curvature with additional measurements in the future. The observations reported herein lay critical groundwork toward the goal of measuring precise masses for low-mass PMS stars.

  7. Using self-consistent Gibbs free energy surfaces to calculate size distributions of neutral and charged clusters for the sulfuric acid-water binary system

    Science.gov (United States)

    Smith, J. A.; Froyd, K. D.; Toon, O. B.

    2012-12-01

    We construct tables of reaction enthalpies and entropies for the association reactions involving sulfuric acid vapor, water vapor, and the bisulfate ion. These tables are created from experimental measurements and quantum chemical calculations for molecular clusters and a classical thermodynamic model for larger clusters. These initial tables are not thermodynamically consistent. For example, the Gibbs free energy of associating a cluster consisting of one acid molecule and two water molecules depends on the order in which the cluster was assembled: add two waters and then the acid or add an acid and a water and then the second water. We adjust the values within the tables using the method of Lagrange multipliers to minimize the adjustments and produce self-consistent Gibbs free energy surfaces for the neutral clusters and the charged clusters. With the self-consistent Gibbs free energy surfaces, we calculate size distributions of neutral and charged clusters for a variety of atmospheric conditions. Depending on the conditions, nucleation can be dominated by growth along the neutral channel or growth along the ion channel followed by ion-ion recombination.

  8. Crystallographic Textures and Morphologies of Solution Cast Ibuprofen Composite Films at Solid Surfaces

    Science.gov (United States)

    2014-01-01

    The preparation of thin composite layers has promising advantages in a variety of applications like transdermal, buccal, or sublingual patches. Within this model study the impact of the matrix material on the film forming properties of ibuprofen–matrix composite films is investigated. As matrix materials polystyrene, methyl cellulose, or hydroxyl-ethyl cellulose were used. The film properties were either varied by the preparation route, i.e., spin coating or drop casting, or via changes in the relative ratio of the ibuprofen and the matrix material. The resulting films were investigated via X-ray diffraction and atomic force microscope experiments. The results show that preferred (100) textures can be induced via spin coating with respect to the glass surface, while the drop casting results in a powder-like behavior. The morphologies of the films are strongly impacted by the ibuprofen amount rather than the preparation method. A comparison of the various matrix materials in terms of their impact on the dissolution properties show a two times faster zero order release from methyl cellulose matrix compared to a polystyrene matrix. The slowest rate was observed within the hydroxyl ethyl cellulose as the active pharmaceutical ingredients (APIs) release is limited by diffusion through a swollen matrix. The investigation reveals that the ibuprofen crystallization and film formation is only little effected by the selected matrix material than that compared to the dissolution. A similar experimental approach using other matrix materials may therefore allow to find an optimized composite layer useful for a defined application. PMID:25275801

  9. Landscape linkages between geothermal activity and solute composition and ecological response in surface waters draining the Atlantic slope of Costa Rica

    Science.gov (United States)

    Pringle, Catherine M.; Rowe, Gary L.; Triska, Frank J.; Fernandez, Jose F.; West, John

    1993-01-01

    Surface waters draining three different volcanoes in Costa Rica, ranging from dormant to moderately active to explosive, have a wide range of solute compositions that partly reflects the contribution of different types of solute-rich, geothermal waters. Three major physical transport vectors affect flows of geothermally derived solutes: thermally driven convection of volcanic gases and geothermal fluids; lateral and gravity-driven downward transport of geothermal fluids; and wind dispersion of ash, gases, and acid rain. Specific vector combinations interact to determine landscape patterns in solute chemistry and biota: indicator taxa of algae and bacteria reflect factors such as high temperature, wind-driven or hydrologically transported acidity, high concentrations of various solutes, and chemical precipitation reactions. Many streams receiving geothermally derived solutes have high levels of soluble reactive phosphorus (SRP) (up to 400 µg liter−1), a nutrient that is typically not measured in geochemical studies of geothermal waters. Regional differences in levels of SRP and other solutes among volcanoes were typically not significant due to high local variation in solute levels among geothermally modified streams and between geothermally modified and unmodified streams on each volcano. Geothermal activity along the volcanic spine of Costa Rica provides a natural source of phosphorus, silica, and other solutes and plays an important role in determining emergent landscape patterns in the solute chemistry of surface waters and aquatic biota.

  10. Binary and ternary binding affinities between exonuclease-deficient Klenow fragment (Kf-exo(-)) and various arylamine DNA lesions characterized by surface plasmon resonance.

    Science.gov (United States)

    Vaidyanathan, V G; Xu, Lifang; Cho, Bongsup P

    2012-08-20

    We used surface plasmon resonance (SPR) to characterize the binding interactions between the exonulease-free Klenow fragment (Kf-exo(-)) and unmodified and modified dG adducts derived from arylamine carcinogens: fluorinated 2-aminofluorene (FAF), 2-acetylaminofluorene (FAAF), and 4-aminobiphenyl (FABP). Tight polymerase binding was detected with unmodified dG and the correct dCTP. The discrimination of correct versus incorrect nucleotides was pronounced with K(D) values in the order of dCTP ≪ dTTP Kf-exo(-) binding tighter to the FAAF (k(off): 0.02 s(-1)) and FABP (k(off): 0.01 s(-1)) lesions than to FAF (k(off): 0.04 s(-1)).

  11. Binary black hole initial data from matched asymptotic expansions

    International Nuclear Information System (INIS)

    Yunes, Nicolas; Owen, Benjamin J.; Tichy, Wolfgang; Bruegmann, Bernd

    2006-01-01

    We present an approximate metric for a binary black-hole spacetime to construct initial data for numerical relativity. This metric is obtained by asymptotically matching a post-Newtonian metric for a binary system to a perturbed Schwarzschild metric for each hole. In the inner zone near each hole, the metric is given by the Schwarzschild solution plus a quadrupolar perturbation corresponding to an external tidal gravitational field. In the near zone, well outside each black hole but less than a reduced wavelength from the center of mass of the binary, the metric is given by a post-Newtonian expansion including the lowest-order deviations from flat spacetime. When the near zone overlaps each inner zone in a buffer zone, the post-Newtonian and perturbed Schwarzschild metrics can be asymptotically matched to each other. By demanding matching (over a 4-volume in the buffer zone) rather than patching (choosing a particular 2-surface in the buffer zone), we guarantee that the errors are small in all zones. The resulting piecewise metric is made formally C ∞ with smooth transition functions so as to obtain the finite extrinsic curvature of a 3-slice. In addition to the metric and extrinsic curvature, we present explicit results for the lapse and the shift, which can be used as initial data for numerical simulations. This initial data is not accurate all the way to the asymptotically flat ends inside each hole, and therefore must be used with evolution codes which employ black hole excision rather than puncture methods. This paper lays the foundations of a method that can be straightforwardly iterated to obtain initial data to higher perturbative order

  12. Interacting binary stars

    International Nuclear Information System (INIS)

    Pringle, J.E.; Wade, R.A.

    1985-01-01

    This book reviews the theoretical and observational knowledge of interacting binary stars. The topics discussed embrace the following features of these objects: their orbits, evolution, mass transfer, angular momentum losses, X-ray emission, eclipses, variability, and other related phenomena. (U.K.)

  13. Equational binary decision diagrams

    NARCIS (Netherlands)

    J.F. Groote (Jan Friso); J.C. van de Pol (Jaco)

    2000-01-01

    textabstractWe incorporate equations in binary decision diagrams (BDD). The resulting objects are called EQ-BDDs. A straightforward notion of ordered EQ-BDDs (EQ-OBDD) is defined, and it is proved that each EQ-BDD is logically equivalent to an EQ-OBDD. Moreover, on EQ-OBDDs satisfiability and

  14. N-Bit Binary Resistor

    Science.gov (United States)

    Tcheng, Ping

    1989-01-01

    Binary resistors in series tailored to precise value of resistance. Desired value of resistance obtained by cutting appropriate traces across resistors. Multibit, binary-based, adjustable resistor with high resolution used in many applications where precise resistance required.

  15. Influence of Surface Pretreatment on the Corrosion Resistance of Cold-Sprayed Nickel Coatings in Acidic Chloride Solution

    Science.gov (United States)

    Scendo, Mieczyslaw; Zorawski, Wojciech; Staszewska-Samson, Katarzyna; Makrenek, Medard; Goral, Anna

    2018-03-01

    Corrosion resistance of the cold-sprayed nickel coatings deposited on the Ni surface (substrate) without and with abrasive grit-blasting treatment of the substrate was investigated. The corundum powder with different grain sizes was used. The corrosive environment contained an acidic chloride solution. The mechanism of the corrosion of nickel was suggested and discussed. Corrosion electrochemical parameters were determined by electrochemical methods. The corrosion effect of a nickel coating depends on the grain size used to prepare the substrate. The nickel coating after the medium grit-blasting treatment of the substrate was found to be the most corrosion resistant. However, the smallest resistance on the corrosion effect should be attributed to the nickel coating on the substrate after the coarse grit-blasting treatment.

  16. Composition profile determination in isomorphous binary alloys

    International Nuclear Information System (INIS)

    An, C.Y.; Bandeira, I.N.

    1983-07-01

    The inhomogeneity along the growth axis of the pseudo-binary alloys is due to the segregation of the solute which will be mixed in the melt due to convective and diffusive flows. A process for determination of the exact composition profile by measurements of the crystal density, for alloys of the type A sub(1-x) B sub(x), is shown. (Author) [pt

  17. Binary DNA Nanostructures for Data Encryption

    OpenAIRE

    Halvorsen, Ken; Wong, Wesley P.

    2012-01-01

    We present a simple and secure system for encrypting and decrypting information using DNA self-assembly. Binary data is encoded in the geometry of DNA nanostructures with two distinct conformations. Removing or leaving out a single component reduces these structures to an encrypted solution of ssDNA, whereas adding back this missing "decryption key" causes the spontaneous formation of the message through self-assembly, enabling rapid read out via gel electrophoresis. Applications include auth...

  18. Binary DNA nanostructures for data encryption.

    Science.gov (United States)

    Halvorsen, Ken; Wong, Wesley P

    2012-01-01

    We present a simple and secure system for encrypting and decrypting information using DNA self-assembly. Binary data is encoded in the geometry of DNA nanostructures with two distinct conformations. Removing or leaving out a single component reduces these structures to an encrypted solution of ssDNA, whereas adding back this missing "decryption key" causes the spontaneous formation of the message through self-assembly, enabling rapid read out via gel electrophoresis. Applications include authentication, secure messaging, and barcoding.

  19. Simultaneous surface coating and chemical activation of the Li-rich solid solution lithium rechargeable cathode and its improved performance

    International Nuclear Information System (INIS)

    Wu, Yingqiang; Ming, Jun; Zhuo, Linhai; Yu, Yancun; Zhao, Fengyu

    2013-01-01

    In this study, highly dispersive spherical Li-rich solid solution (Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 ) particles are successfully synthesized by a co-precipitation method. Then these particles are treated with aluminum nitrates ethanol solution at 80 °C. The treatment can extract lithium (Li 2 O) from the Li 2 MnO 3 component in the composite of Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 . Simultaneously, a thin layer of Al 2 O 3 can be precipitated on the surface of the electrode particles via direct thermal decomposition of aluminum nitrates. After treatment, the first-cycle coulombic efficiency of the electrode increases from 72.1% to 93.6%, meanwhile it shows a superior cycling stability at 100 mA g −1 with a discharge capacity of around 220 mAh g −1 and retention of 92.5% after 100 cycles, which is much higher than that of the pristine electrode (83.2%). Even at a high current density of 2 A g −1 (10 C), the discharge capacity could still achieve and well maintain as high as 140 mAh g −1

  20. Response surface modeling of boron adsorption from aqueous solution by vermiculite using different adsorption agents: Box-Behnken experimental design.

    Science.gov (United States)

    Demirçivi, Pelin; Saygılı, Gülhayat Nasün

    2017-07-01

    In this study, a different method was applied for boron removal by using vermiculite as the adsorbent. Vermiculite, which was used in the experiments, was not modified with adsorption agents before boron adsorption using a separate process. Hexadecyltrimethylammonium bromide (HDTMA) and Gallic acid (GA) were used as adsorption agents for vermiculite by maintaining the solid/liquid ratio at 12.5 g/L. HDTMA/GA concentration, contact time, pH, initial boron concentration, inert electrolyte and temperature effects on boron adsorption were analyzed. A three-factor, three-level Box-Behnken design model combined with response surface method (RSM) was employed to examine and optimize process variables for boron adsorption from aqueous solution by vermiculite using HDTMA and GA. Solution pH (2-12), temperature (25-60 °C) and initial boron concentration (50-8,000 mg/L) were chosen as independent variables and coded x 1 , x 2 and x 3 at three levels (-1, 0 and 1). Analysis of variance was used to test the significance of variables and their interactions with 95% confidence limit (α = 0.05). According to the regression coefficients, a second-order empirical equation was evaluated between the adsorption capacity (q i ) and the coded variables tested (x i ). Optimum values of the variables were also evaluated for maximum boron adsorption by vermiculite-HDTMA (HDTMA-Verm) and vermiculite-GA (GA-Verm).

  1. Synthesis and surface physicochemical properties of (CdTe)0.03(ZnSe)0.97 solid solution

    Science.gov (United States)

    Podgornyi, S. O.; Podgornaya, O. T.; Skutin, E. D.; Demesko, I. P.; Lukoyanova, O. V.; Muromtsev, I. V.

    2018-01-01

    The research is centered on (CdTe)0.03(ZnSe)0.97 solid solutions. The article is aimed at developing innovative primary transducer material for semi-conductor sensors, investigating their surface physicochemical properties and evaluation their applicability in carbon monoxide diagnostics. Powders and nanofilms of (CdTe)0.03(ZnSe)0.97 solid solutions were obtained by isothermal diffusion and discrete thermal evaporation in vacuum. (CdTe)0.03(ZnSe)0.97 applicability in gas analysis was investigated. IR spectroscopy of multiple disturbed complete internal reflections and hydrolytic adsorption were used to study chemical composition and acid-base properties of (CdTe)0.03(ZnSe)0.97. Adsorption properties of the given material for carbon oxide (II) and oxygen were studied by the piezoquartz microweighing and volumetrically. The principles of adsorption, depending on the process conditions, were established. Based on the obtained experimental data, CO micro-impurities sensors were developed, the laboratory tests passed successfully

  2. Thermally conductive tough flexible elastomers as composite of slide-ring materials and surface modified boron nitride particles via plasma in solution

    Science.gov (United States)

    Goto, Taku; Iida, Masaki; Tan, Helen; Liu, Chang; Mayumi, Koichi; Maeda, Rina; Kitahara, Koichi; Hatakeyama, Kazuto; Ito, Tsuyohito; Shimizu, Yoshiki; Yokoyama, Hideaki; Kimura, Kaoru; Ito, Kohzo; Hakuta, Yukiya; Terashima, Kazuo

    2018-03-01

    We have developed a thermally conductive flexible elastomer as a composite material with slide-ring (SR) materials and boron nitride (BN) particles surface-modified via plasma in solution. This composite shows excellent properties as a flexible insulator for thermal management. Surface modification of BN particles using plasma in solution increases the tensile strength, extension ratio at break, toughness, and rubber characteristics of the composites, compared to SR and non-modified BN, while the Young's modulus values are identical. Furthermore, the thermal conductivity also improved as a result of plasma surface modification.

  3. Black holes in binary stars

    NARCIS (Netherlands)

    Wijers, R.A.M.J.

    1996-01-01

    Introduction Distinguishing neutron stars and black holes Optical companions and dynamical masses X-ray signatures of the nature of a compact object Structure and evolution of black-hole binaries High-mass black-hole binaries Low-mass black-hole binaries Low-mass black holes Formation of black holes

  4. Adsorção e propriedades de volume de misturas binárias água álcool: um experimento didático com base em medidas de tensão superficial An undergraduate experiment in physical chemistry: adsorption and bulk properties of alcohol-water mixtures based on surface tension measurements

    Directory of Open Access Journals (Sweden)

    Michelly C. dos Santos

    2010-01-01

    Full Text Available An undergraduate physical chemistry experiment based on the drop counting method for surface tension measurements is proposed to demonstrate adsorption isotherms of binary aqueous solutions of ethanol, n-propanol, and n-butanol. Excess surface is obtained by the derivative of surface tension taken with respect to alcohol activity, after this activity calculation using van Laar equation. Laboratory class contents are surface tension, excess surface, percolation of hydrogen bonds, micelle, activity, and ideal solution.

  5. Equilibrium surface tension and the interaction energy of DMSO with tert-butyl alcohol or iso-amyl alcohol at various temperatures

    International Nuclear Information System (INIS)

    Bagheri, Ahmad; Moradian, Zohreh

    2014-01-01

    Highlights: • Surface tension of non-ideal binary systems of alcohol/DMSO determined. • The surface tension data of binary mixtures were correlated with five equations. • The interaction energy values were calculated by using LWW model. • The U 12 value shows different behavior for two systems with increasing temperature. - Abstract: Surface tension of binary mixtures of tert-butyl alcohol (TBA) and iso-amyl alcohol (IAA) with DMSO (dimethyl sulfoxide) were measured over the entire concentration range at pressure of 82.5 kPa at temperatures between (298.15 and 328.15) K. Correlating the surface tension and surface tension deviation of the above mentioned binary systems was performed with empirical and thermodynamic based models. The average relative error obtained from the comparison of experimental and calculated surface tension values for the two binary systems with five models at various temperatures is less than 2%. The effect of temperature on the interaction energy values in binary mixtures has been used to obtain information about solute structural effects on DMSO. Also, the experimental data were used to evaluate the nature and type of intermolecular interactions in binary mixtures

  6. Young and Waltzing Binary Stars

    Science.gov (United States)

    2001-10-01

    of the stars, as they move along their orbits and periodically approach and recede from the observer. Such spectroscopic observations therefore allow to measure the orbital velocities of the stars. It is exactly the same technique that is used to study and weigh extra-solar planets orbiting other stars [3]. However, this method has an important limitation. From the spectroscopical observations alone, it is only possible to deduce limits on the masses, as the inclination of orbits to the line-of-sight is usually unknown. The masses derived in this way (for stars as well as for exoplanets) are therefore only lower limits on the actual masses. Eclipsing Binaries However, fortunate observational circumstances sometimes allow to obtain all information about the stellar orbits. If a binary system is viewed (almost exactly) edge-on, the stars may pass in front of each other from time to time. Astronomers refer to this phenomenon as an "eclipse" and speak about an "eclipsing binary". The effect is similar to a "solar" eclipse as seen on the Earth, whenever the Moon passes in front of the Sun. Like the Moon blocks the sunlight, less light is received from the eclipsed star and thus the combined light from the binary system decreases during the eclipse. The way this happens (astronomers speak about the system's "lightcurve") then provides the additional information about the inclination of the orbit that is needed to determine exactly the stellar masses in a "spectroscopic" binary system. Very accurate values for the stellar diameters and the surface temperatures of the two stars can also be deduced. In short, when a full set of observations is available, it is possible to give a comprehensive description of an eclipsing binary system and its components. Eclipsing, spectroscopic binaries thus represent true cornerstones for the determination of stellar masses , and as such they are fundamental for our understanding of stellar evolution . Rather few such systems are known, but

  7. Boundary layer flow of Maxwell fluid in rotating frame with binary chemical reaction and activation energy

    Directory of Open Access Journals (Sweden)

    Z. Shafique

    Full Text Available Here we study the heat/mass transfer effects on revolving flow of Maxwell fluid due to unidirectional stretching surface. Mass transfer process is modeled in terms of binary chemical reaction and activation energy. Modified Arrhenius function for activation energy is invoked. Traditional boundary layer approximations are utilized to simplify the governing equations. Using similarity method, self-similar form of boundary layer equations are derived which are solved numerically. The solutions depend on dimensionless numbers such as the rotation parameter λ, the Deborah number β, the Prandtl number Pr, the Schmidt number Sc, activation energy E, fitted rate constant n and temperature difference parameter δ. We found that the solute concentration in binary mixture is proportional to both rotation parameter λ and activation energy E. The reaction rate σ and fitted rate n both provide reduction in the solute concentration. Thermal boundary layer becomes thicker and heat transfer rate diminishes when fluid is subjected to a larger rotation rate. Keywords: Maxwell fluid, Activation energy, Chemical reaction, Numerical solution, Rotating frame, Stretching sheet

  8. Compressing Binary Decision Diagrams

    DEFF Research Database (Denmark)

    Hansen, Esben Rune; Satti, Srinivasa Rao; Tiedemann, Peter

    2008-01-01

    The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to ......-2 bits per node. Empirical results for our compression technique are presented, including comparisons with previously introduced techniques, showing that the new technique dominate on all tested instances......The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to 1...

  9. Compressing Binary Decision Diagrams

    DEFF Research Database (Denmark)

    Rune Hansen, Esben; Srinivasa Rao, S.; Tiedemann, Peter

    The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to ......-2 bits per node. Empirical results for our compression technique are presented, including comparisons with previously introduced techniques, showing that the new technique dominate on all tested instances.......The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to 1...

  10. Binary Masking & Speech Intelligibility

    OpenAIRE

    Boldt, Jesper

    2010-01-01

    The purpose of this thesis is to examine how binary masking can be used to increase intelligibility in situations where hearing impaired listeners have difficulties understanding what is being said. The major part of the experiments carried out in this thesis can be categorized as either experiments under ideal conditions or as experiments under more realistic conditions useful for real-life applications such as hearing aids. In the experiments under ideal conditions, the previously defined i...

  11. The Effect of Surface Roughness on the Corrosion Properties of Type AISI 304 Stainless Steel in Diluted NaCl and Urban Rain Solution

    Science.gov (United States)

    Leban, Mirjam Bajt; Mikyška, Črt; Kosec, Tadeja; Markoli, Boštjan; Kovač, Janez

    2014-05-01

    Due to their good corrosion resistance, favorable mechanical properties, and reasonable price regarding their excellent properties, austenitic stainless steels have, over recent decades, become one of the alloys that are increasingly used in civil engineering and building, as well as for specific architectural purposes. Architects often design stainless steel exterior elements with higher surface roughnesses, which are not resistant to corrosion processes. The aim of this work was to investigate the influence of different types of surface finishes to stainless steel of quality AISI 304 on the corrosion properties of this steel. In order to achieve this goal, electrochemical tests were performed on different surface finishes in two different environments: in an NaCl aqueous solution, and in simulated urban rain which contained no chlorides. In addition to the electrochemical methods used, surface roughness was also measured, and XPS surface analyses were performed. The results of the investigation showed that surface roughness affects the growth of the passive layer in urban rain significantly; however, the growth of such a film is retarded in the case of the NaCl aqueous solution. Based on the results of the performed analyses, it was found that, in the NaCl solution, the pitting potential depended strongly upon the surface roughness and the surface finish, but this was not true for the samples tested in urban rain.

  12. Synthesis and characterization of graft copolymers of chitosan with NIPAM and binary monomers for removal of Cr(VI), Cu(II) and Fe(II) metal ions from aqueous solutions.

    Science.gov (United States)

    Lalita; Singh, Anirudh P; Sharma, Rajeev Kr

    2017-06-01

    To develop pH responsive hydrogels, N-isopropylacrylamide (NIPAM) has been grafted on to chitosan by free radical initiation method using azoisobutrylnitrile (AIBN) as an initiator. The optimum grafting conditions were worked out for grafting of NIPAM onto 1g of chitosan by varying one reaction parameter at a time and keeping all other parameters constant. Binary monomers were grafted for five different concentrations of comonomers acrylic acid (AAc), acrylamide (AAm) and acrylonitrile (AN) at optimum grafting conditions evaluated for GMA alone onto chitosan. The grafted copolymers were analyzed by FTIR, TGA/DTA, XRD and SEM. The swelling studies for the grafted samples were performed at various pH in order to explore their end use in sorption of Cr(VI), Fe(II) and Cu(II) ions from water system. Metal ion sorption behaviour of polymeric samples was studied as function of time, temperature and pH. Various metal ion sorption parameters such as percent uptake (P u ), partition coefficient (K d ) and retention capacity (Q r ) were discussed. Chitosan grafted with binary monomers NIPAM-co-AAc and NIPAM-co-AAm showed best results for sorption of all three metal ions. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Effect of surface chemistry, solution pH, and ionic strength on the removal of herbicides diuron and amitrole from water by an activated carbon fiber.

    Science.gov (United States)

    Fontecha-Cámara, M A; López-Ramón, M V; Alvarez-Merino, M A; Moreno-Castilla, C

    2007-01-30

    A study was conducted on the effects of carbon surface chemistry, solution pH, and ionic strength on the removal of diuron and amitrole from aqueous solutions by adsorption on an as-received and oxidized activated carbon fiber. Results obtained were explained by the surface characteristics of the adsorbents and the characteristics of the herbicide molecules. Under the experimental conditions used, diuron uptake was much higher than that of amitrole, despite its larger molecular dimensions, due to the lesser water solubility, greater hydrophobicity, and larger dipolar moment of diuron compared with amitrole. Uptake variations associated with differences in carbon surface oxidation, solution pH, and ionic strength were explained by corresponding changes in electrostatic, hydrophobic, and van der Waals interactions.

  14. Groundwater-Surface Water Interactions and Downstream Transport of Water, Heat, and Solutes in a Hydropeaked River

    Science.gov (United States)

    Ferencz, S. B.; Cardenas, M. B.; Neilson, B. T.; Watson, J.

    2017-12-01

    A majority of the world's largest river systems are regulated by dams. In addition to being used for water resources management and flood prevention, many large dams are also used for hydroelectric power generation. In the United States, dams account for 7% of domestic electricity, and hydropower accounts for 16% of worldwide electricity production. To help meet electricity demand during peak usage times, hydropower utilities often increase their releases of water during high demand periods. This practice, termed hydropeaking, can cause large transient flow regimes downstream of hydroelectric dams. These transient flow increases can result in order of magnitude daily fluctuations in discharge, and the released water can have different thermal and chemical properties than ambient river water. As hydropeaking releases travel downstream, the temporary rise in stage and increase in discharge can enhance surface water-groundwater (SW-GW) exchange between the river and its alluvial aquifer. This dam-induced SW-GW exchange, combined with hydrodynamic attenuation and heat exchange processes, result in complex responses downstream. The dam-regulated Lower Colorado River downstream of Austin, TX was used as a natural laboratory to observe SW-GW interactions and downstream transport of water, heat, and solutes under hydropeaking conditions. To characterize SW-GW interactions, well transects were installed in the banks of the river to observe exchanges between the river and alluvial aquifer. The well transects were installed at three different distances from the dam (15km, 35km, and 80km). At each well transect conductivity, temperature, and pressure sensors were deployed in the monitoring wells and in the channel. Additional conductivity and temperature sensors were deployed along the study reach to provide a more detailed record of heat and solute transport during hydropeaking releases. The field data spans over two months of daily dam releases that were punctuated by two

  15. Effect of surface-active additives on the temperature behavior of interfacial tension in water- n-hexane systems

    Science.gov (United States)

    Ataev, G. M.

    2012-03-01

    The temperature dependence of interface tension in a water- n-hexane system without additives and after addition of stearic acid was experimentally studied at four different concentrations. A method for determining the excess surface chemical potential from experimental data on the temperature dependence of interfacial or surface tension is proposed for a diluted solution of surface-active impurity. The excess surface chemical potential of stearic acid at the interface of a water- n-hexane binary mixture is determined.

  16. Mass and heat transfer between evaporation and condensation surfaces: Atomistic simulation and solution of Boltzmann kinetic equation.

    Science.gov (United States)

    Zhakhovsky, Vasily V; Kryukov, Alexei P; Levashov, Vladimir Yu; Shishkova, Irina N; Anisimov, Sergey I

    2018-04-16

    Boundary conditions required for numerical solution of the Boltzmann kinetic equation (BKE) for mass/heat transfer between evaporation and condensation surfaces are analyzed by comparison of BKE results with molecular dynamics (MD) simulations. Lennard-Jones potential with parameters corresponding to solid argon is used to simulate evaporation from the hot side, nonequilibrium vapor flow with a Knudsen number of about 0.02, and condensation on the cold side of the condensed phase. The equilibrium density of vapor obtained in MD simulation of phase coexistence is used in BKE calculations for consistency of BKE results with MD data. The collision cross-section is also adjusted to provide a thermal flux in vapor identical to that in MD. Our MD simulations of evaporation toward a nonreflective absorbing boundary show that the velocity distribution function (VDF) of evaporated atoms has the nearly semi-Maxwellian shape because the binding energy of atoms evaporated from the interphase layer between bulk phase and vapor is much smaller than the cohesive energy in the condensed phase. Indeed, the calculated temperature and density profiles within the interphase layer indicate that the averaged kinetic energy of atoms remains near-constant with decreasing density almost until the interphase edge. Using consistent BKE and MD methods, the profiles of gas density, mass velocity, and temperatures together with VDFs in a gap of many mean free paths between the evaporation and condensation surfaces are obtained and compared. We demonstrate that the best fit of BKE results with MD simulations can be achieved with the evaporation and condensation coefficients both close to unity.

  17. Optical analogue of relativistic Dirac solitons in binary waveguide arrays

    Energy Technology Data Exchange (ETDEWEB)

    Tran, Truong X., E-mail: truong.tran@mpl.mpg.de [Department of Physics, Le Quy Don University, 236 Hoang Quoc Viet str., 10000 Hanoi (Viet Nam); Max Planck Institute for the Science of Light, Günther-Scharowsky str. 1, 91058 Erlangen (Germany); Longhi, Stefano [Department of Physics, Politecnico di Milano and Istituto di Fotonica e Nanotecnologie del Consiglio Nazionale delle Ricerche, Piazza L. da Vinci 32, I-20133 Milano (Italy); Biancalana, Fabio [Max Planck Institute for the Science of Light, Günther-Scharowsky str. 1, 91058 Erlangen (Germany); School of Engineering and Physical Sciences, Heriot-Watt University, EH14 4AS Edinburgh (United Kingdom)

    2014-01-15

    We study analytically and numerically an optical analogue of Dirac solitons in binary waveguide arrays in the presence of Kerr nonlinearity. Pseudo-relativistic soliton solutions of the coupled-mode equations describing dynamics in the array are analytically derived. We demonstrate that with the found soliton solutions, the coupled mode equations can be converted into the nonlinear relativistic 1D Dirac equation. This paves the way for using binary waveguide arrays as a classical simulator of quantum nonlinear effects arising from the Dirac equation, something that is thought to be impossible to achieve in conventional (i.e. linear) quantum field theory. -- Highlights: •An optical analogue of Dirac solitons in nonlinear binary waveguide arrays is suggested. •Analytical solutions to pseudo-relativistic solitons are presented. •A correspondence of optical coupled-mode equations with the nonlinear relativistic Dirac equation is established.

  18. The use of in situ Fourier-transform infrared spectroscopy for the study of surface phenomena on electrodes in selected lithium battery electrolyte solutions

    Science.gov (United States)

    Aurbach, D.; Chusid, O.

    This paper presents some examples of surface studies of noble metals and Li electrodes in Li battery electrolyte solutions using in situ FT-IR spectroscopic techniques. These examples include the study of a mixture of solvents, the role of the reduction of salt in the build-up of surface films on the electrodes and the impact of contaminants such as traces of oxgen and water. The techniques included multiple and single internal reflectance modes and external reflectance (SNIFTIRS-type) mode. The following conclusions were drawn from this study: (i) salts containing the -SO 2CF 3 group are much more reactive on Li than LiAsF 6. Their reduction dominates the surface chemistry developed on Li in ethereal solutions; (ii) water reduction on Li in wet 1,3-dioxolane solution may not form stable LiOH films due to the further reaction of the hydroxy group with the solvent; (iii) in spite of its low solubility, oxygen dissolved in propylene carbonate and tetrahydrofuran solutions has some impact on the surface chemistry developed on Li in these solutions (probably due to Li 2O formation).

  19. Adsorption and nanowear properties of bovine submaxillary mucin films on solid surfaces: Influence of solution pH and substrate hydrophobicity

    DEFF Research Database (Denmark)

    Sotres, Javier; Madsen, Jan Busk; Arnebrant, Thomas

    2014-01-01

    The adsorption and mechanical stability of bovine submaxillary mucins (BSM) films at solid-liquid interfaces were studied with respect to both substrate hydrophobicity and solution pH. Dynamic light scattering revealed a single peak distribution in neutral aqueous solution (pH 7.4) and a small...... fraction with enhanced aggregation was observed in acidic solution (pH 3.8). Both substrate hydrophobicity and solution pH were found to affect the spontaneous adsorption of BSM onto solid surfaces; BSM adsorbed more onto hydrophobic surfaces than hydrophilic ones, and adsorbed more at pH 3.8 than at pH 7.......4. Thus, the highest "dry" adsorbed mass was observed for hydrophobic surfaces in pH 3.8 solution. However, a highest "wet" adsorbed mass, i.e. which includes the solvent coupled to the film, was observed for hydrophobic surfaces at pH 7.4. The mechanical stability of the films was studied...

  20. Massive Black Hole Binary Evolution

    Directory of Open Access Journals (Sweden)

    Merritt David

    2005-11-01

    Full Text Available Coalescence of binary supermassive black holes (SBHs would constitute the strongest sources of gravitational waves to be observed by LISA. While the formation of binary SBHs during galaxy mergers is almost inevitable, coalescence requires that the separation between binary components first drop by a few orders of magnitude, due presumably to interaction of the binary with stars and gas in a galactic nucleus. This article reviews the observational evidence for binary SBHs and discusses how they would evolve. No completely convincing case of a bound, binary SBH has yet been found, although a handful of systems (e.g. interacting galaxies; remnants of galaxy mergers are now believed to contain two SBHs at projected separations of <~ 1kpc. N-body studies of binary evolution in gas-free galaxies have reached large enough particle numbers to reproduce the slow, “diffusive” refilling of the binary’s loss cone that is believed to characterize binary evolution in real galactic nuclei. While some of the results of these simulations - e.g. the binary hardening rate and eccentricity evolution - are strongly N-dependent, others - e.g. the “damage” inflicted by the binary on the nucleus - are not. Luminous early-type galaxies often exhibit depleted cores with masses of ~ 1-2 times the mass of their nuclear SBHs, consistent with the predictions of the binary model. Studies of the interaction of massive binaries with gas are still in their infancy, although much progress is expected in the near future. Binary coalescence has a large influence on the spins of SBHs, even for mass ratios as extreme as 10:1, and evidence of spin-flips may have been observed.

  1. Uncertainty in positive matrix factorization solutions for PAHs in surface sediments of the Yangtze River Estuary in different seasons.

    Science.gov (United States)

    Liu, Ruimin; Men, Cong; Yu, Wenwen; Xu, Fei; Wang, Qingrui; Shen, Zhenyao

    2018-01-01

    To examine the variabilities of source contributions in the Yangtze River Estuary (YRE), the uncertainty based on the positive matrix factorization (PMF) was applied to the source apportionment of the 16 priority PAHs in 120 surface sediment samples from four seasons. Based on the signal-to-noise ratios, the PAHs categorized as "Bad" might drop out of the estimation of bootstrap. Next, the spatial variability of residuals was applied to determine which species with non-normal curves should be excluded. The median values from the bootstrapped solutions were chosen as the best estimate of the true factor contributions, and the intervals from 5th to 95th percentile represent the variability in each sample factor contribution. Based on the results, the median factor contributions of wood grass combustion and coke plant emissions were highly correlated with the variability (R 2  = 0.6797-0.9937) in every season. Meanwhile, the factor of coal and gasoline combustion had large variability with lower R 2 values in every season, especially in summer (0.4784) and winter (0.2785). The coefficient of variation (CV) values based on the Bootstrap (BS) simulations were applied to indicate the uncertainties of PAHs in every factor of each season. Acy, NaP and BgP always showed higher CV values, which suggested higher uncertainties in the BS simulations, and the PAH with the lowest concentration among all PAHs usually became the species with higher uncertainties. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Mesoscopic Simulations of the Phase Behavior of Aqueous EO 19 PO 29 EO 19 Solutions Confined and Sheared by Hydrophobic and Hydrophilic Surfaces

    KAUST Repository

    Liu, Hongyi

    2012-01-25

    The MesoDyn method is used to investigate associative structures in aqueous solution of a nonionic triblock copolymer consisting of poly(propylene oxide) capped on both ends with poly(ethylene oxide) chains. The effect of adsorbing (hydrophobic) and nonadsorbing (hydrophilic) solid surfaces in contact with aqueous solutions of the polymer is elucidated. The macromolecules form self-assembled structures in solution. Confinement under shear forces is investigated in terms of interfacial behavior and association. The formation of micelles under confinement between hydrophilic surfaces occurs faster than in bulk aqueous solution while layered structures assemble when the polymers are confined between hydrophobic surfaces. Micelles are deformed under shear rates of 1 μs -1 and eventually break to form persistent, adsorbed layered structures. As a result, surface damage under frictional forces is prevented. Overall, this study indicates that aqueous triblock copolymers of poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) (Pluronics, EO mPO nEO m) act as a boundary lubricant for hydrophobic surfaces but not for hydrophilic ones. © 2011 American Chemical Society.

  3. A METHOD FOR POST-TREATMENT OF AN ARTICLE WITH A METALLIC SURFACE AS WELL AS A TREATMENT SOLUTION TO BE USED IN THE METHOD

    DEFF Research Database (Denmark)

    1993-01-01

    A method and a treatment solution for post-treatment of an article with a metallic surface, where the metallic surface is made of one or more metals of a standard oxidation potential within the range -2.5 to +0.5 V. A thin coating is formed on the metallic surface by a treatment with an aqueous...... conditions where the metal surface is maintained at a potential within the range of -600 and -1800 mV/nhe. A corrosion-protecting and/or decorative effect is obtained which can be compared with the effect obtained by conventional chromate treatment, and which avoids the environmental and toxicologic...... solution containing a molybdenum compound selected among molybdic acid and salts thereof in a concentration of 2.9 to 9.8 g/l calculated as molybdenum, as well as a compound capable of forming a heteropolymolybdate, such as phosphoric acid, together with a molybdate. The treatment is performed under...

  4. Calcium Hypochlorite Solutions: Evaluation of Surface Tension and Effect of Different Storage Conditions and Time Periods over pH and Available Chlorine Content.

    Science.gov (United States)

    Leonardo, Natália Gomes e Silva; Carlotto, Israel Bangel; Luisi, Simone Bonato; Kopper, Patrícia Maria Poli; Grecca, Fabiana Soares; Montagner, Francisco

    2016-04-01

    The aim of this study was to evaluate the pH and the available chlorine content from sodium hypochlorite (NaOCl) and calcium hypochlorite (Ca[OCl]2) solutions stored in different conditions and time periods and the surface tension of Ca(OCl)2 solutions in comparison with NaOCl. Solutions at 0.5%, 1%, 2.5%, and 5.25% concentrations were prepared. The pH level and the available chlorine content of freshly prepared solutions and solutions stored for 30, 60, and 90 days at 25°C, 4°C, or 37°C were evaluated in a digital pH meter and by titration, respectively. Surface tension was tested using a Du Nouy tensiometer (Sigma 702, Force Tensiometer; Attension, Espoo, Finland). Descriptive and inferential statistical analyses were performed. A precipitate formed by 2.5% and 5.25% Ca(OCl)2 solutions was observed. Ca(OCl)2 showed a higher concentration of available chlorine than NaOCl. Both 2.5% and 5.25% NaOCl and Ca(OCl)2 had a decrease in the available chlorine content when compared with freshly prepared solutions; 0.5% and 1% NaOCl tend to have a lower pH compared with 0.5% and 1% Ca(OCl)2. NaOCl, 5.25%, showed higher pH compared with 5.25% Ca(OCl)2. NaOCl and Ca(OCl)2 in 0.5% and 1% concentrations tend to show a reduced pH level, whereas 2.5% and 5.25% solutions showed an increase in pH. The heat contributed to the instability of the solutions. NaOCl showed lower surface tension values than Ca(OCl)2. Ca(OCl)2 solutions are extremely alkaline and tend to have more available chlorine content than NaOCl but have a higher surface tension than NaOCl. Regarding the available chlorine content, these solutions tend to be stable to 30 days of storage when kept at 4°C or at 25°C. Copyright © 2016 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  5. Efficient Computational Research Protocol to Survey Free Energy Surface for Solution Chemical Reaction in the QM/MM Framework: The FEG-ER Methodology and Its Application to Isomerization Reaction of Glycine in Aqueous Solution.

    Science.gov (United States)

    Takenaka, Norio; Kitamura, Yukichi; Nagaoka, Masataka

    2016-03-03

    In solution chemical reaction, we often need to consider a multidimensional free energy (FE) surface (FES) which is analogous to a Born-Oppenheimer potential energy surface. To survey the FES, an efficient computational research protocol is proposed within the QM/MM framework; (i) we first obtain some stable states (or transition states) involved by optimizing their structures on the FES, in a stepwise fashion, finally using the free energy gradient (FEG) method, and then (ii) we directly obtain the FE differences among any arbitrary states on the FES, efficiently by employing the QM/MM method with energy representation (ER), i.e., the QM/MM-ER method. To validate the calculation accuracy and efficiency, we applied the above FEG-ER methodology to a typical isomerization reaction of glycine in aqueous solution, and reproduced quite satisfactorily the experimental value of the reaction FE. Further, it was found that the structural relaxation of the solute in the QM/MM force field is not negligible to estimate correctly the FES. We believe that the present research protocol should become prevailing as one computational strategy and will play promising and important roles in solution chemistry toward solution reaction ergodography.

  6. Magnetic binary nanofillers

    Energy Technology Data Exchange (ETDEWEB)

    Morales Mendoza, N. [INQUIMAE, CONICET-UBA, Ciudad Universitaria, Pab2, (C1428EHA) Bs As (Argentina); LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Goyanes, S. [LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Chiliotte, C.; Bekeris, V. [LBT, Dep. De Fisica, FCEN-UBA. Ciudad Universitaria, Pab1, C1428EGA CABA (Argentina); Rubiolo, G. [LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Unidad de Actividad Materiales, CNEA, Av Gral. Paz 1499, San Martin (1650), Prov. de Bs As (Argentina); Candal, R., E-mail: candal@qi.fcen.uba.ar [INQUIMAE, CONICET-UBA, Ciudad Universitaria, Pab2, (C1428EHA) Bs As (Argentina); Escuela de Ciencia y Tecnologia, 3iA, Universidad de Gral. San Martin, San Martin, Prov. Bs As (Argentina)

    2012-08-15

    Magnetic binary nanofillers containing multiwall carbon nanotubes (MWCNT) and hercynite were synthesized by Chemical Vapor Deposition (CVD) on Fe/AlOOH prepared by the sol-gel method. The catalyst precursor was fired at 450 Degree-Sign C, ground and sifted through different meshes. Two powders were obtained with different particle sizes: sample A (50-75 {mu}m) and sample B (smaller than 50 {mu}m). These powders are composed of iron oxide particles widely dispersed in the non-crystalline matrix of aluminum oxide and they are not ferromagnetic. After reduction process the powders are composed of {alpha}-Fe nanoparticles inside hercynite matrix. These nanofillers are composed of hercynite containing {alpha}-Fe nanoparticles and MWCNT. The binary magnetic nanofillers were slightly ferromagnetic. The saturation magnetization of the nanofillers depended on the powder particle size. The nanofiller obtained from powder particles in the range 50-75 {mu}m showed a saturation magnetization 36% higher than the one formed from powder particles smaller than 50 {mu}m. The phenomenon is explained in terms of changes in the magnetic environment of the particles as consequence of the presence of MWCNT.

  7. Coarse-grained modeling of proline rich protein 1 (PRP-1) in bulk solution and adsorbed to a negatively charged surface.

    Science.gov (United States)

    Skepö, Marie; Linse, Per; Arnebrant, Thomas

    2006-06-22

    Structural properties of the acidic proline rich protein PRP-1 of salivary origin in bulk solution and adsorbed onto a negatively charged surface have been studied by Monte Carlo simulations. A simple model system with focus on electrostatic interactions and short-ranged attractions among the uncharged amino acids has been used. In addition to PRP-1, some mutants were considered to assess the role of the interactions in the systems. Contrary to polyelectrolytes, the protein has a compact structure in salt-free bulk solutions, whereas at high salt concentration the protein becomes more extended. The protein adsorbs to a negatively charged surface, although its net charge is negative. The adsorbed protein displays an extended structure, which becomes more compact upon addition of salt. Hence, the conformational response upon salt addition in the adsorbed state is the opposite as compared to that in bulk solution. The conformational behavior of PRP-1 in bulk solution and at charged surfaces as well as its propensity to adsorb to surfaces with the same net charge are rationalized by the block polyampholytic character of the protein. The presence of a triad of positively charged amino acids in the C-terminal was found to be important for the adsorption of the protein.

  8. Electron Transfer Mediator Effects in Water Oxidation Catalysis by Solution and Surface-Bound Ruthenium Bpy-Dicarboxylate Complexes

    Energy Technology Data Exchange (ETDEWEB)

    Sheridan, Matthew V.; Sherman, Benjamin D.; Marquard, Seth L.; Fang, Zhen; Ashford, Dennis L.; Wee, Kyung-Ryang; Gold, Alexander S.; Alibabaei, Leila; Rudd, Jennifer A.; Coggins, Michael K.; Meyer, Thomas J.

    2015-11-12

    Electrocatalytic water oxidation by the catalyst, ruthenium 2,2'-bipyridine-6,6'-dicarboxylate (bda) bis-isoquinoline (isoq), [Ru(bda)(isoq)2], 1, was investigated at metal oxide electrodes surface-derivatized with electron transfer (ET) mediators. At indium-doped tin oxide (ITO) in pH 7.2 in H2PO4–/HPO42– buffers in 0.5 M NaClO4 with added acetonitrile (MeCN), the catalytic activity of 1 is enhanced by the surface-bound redox mediators [Ru (4,4'-PO3H2-bpy)(4,4'-R-bpy)2]2+ (RuPbpyR22+, R = Br, H, Me, or OMe, bpy = 2,2'-bipyridine). Rate-limiting ET between the Ru3+ form of the mediator and the RuIV(O) form in the [RuV/IV(O)]+/0 couple of 1 is observed at relatively high concentrations of HPO42– buffer base under conditions where O···O bond formation is facilitated by atom-proton transfer (APT). For the solution [Ru(bpy)3]3+/2+ mediator couple and 1 as the catalyst, catalytic currents vary systematically with the concentration of mediator and the HPO42– buffer base concentration. Electron transfer mediation of water oxidation catalysis was also investigated on nanoparticle TiO2 electrodes co-loaded with catalyst [Ru(bda)(py-4-O(CH2)3-PO3H2)2], 2, (py = pyridine) and RuPbpyR22+ (R = H, Me, or OMe) with an interplay between rate-limiting catalyst oxidation and rate-limiting O···O bond formation by APT. Lastly, the co-loaded assembly RuPbpyR22+ + 2 has been investigated in a dye-sensitized photoelectrosynthesis cell for water splitting.

  9. The influence of surface modification, coating agents and pH value of aqueous solutions on physical properties of magnetite nanoparticles investigated by ESR method

    Science.gov (United States)

    Dobosz, Bernadeta; Krzyminiewski, Ryszard; Kurczewska, Joanna; Schroeder, Grzegorz

    2017-05-01

    The article presents the results of electron spin resonance (ESR) studies for aqueous solutions of functionalized superparamagnetic iron(II,III) oxide nanoparticles. The samples studied differed in type of organic ligands at the magnetite surface, type of coating agent and pH value of aqueous solutions. The ESR spectra of the samples were obtained at room temperature and at 230 K. The field cooling (FC) experiment was performed for selected samples, and the effective anisotropy field (HK2) and the first order magnetocrystalline anisotropy constant (K1) was calculated. The process of the nanoparticles diffusion in different environments (human blood, human serum) forced by an inhomogeneous magnetic field was monitored and their interactions with different solvents have been discussed. It has been shown that ESR method is useful to observe the impact of organic ligands at the magnetite surface, type of coating agent and pH value of aqueous solutions on the properties of iron(II,III) oxide nanoparticles.

  10. LUT observations of the mass-transferring binary AI Dra

    Science.gov (United States)

    Liao, Wenping; Qian, Shengbang; Li, Linjia; Zhou, Xiao; Zhao, Ergang; Liu, Nianping

    2016-06-01

    Complete UV band light curve of the eclipsing binary AI Dra was observed with the Lunar-based Ultraviolet Telescope (LUT) in October 2014. It is very useful to adopt this continuous and uninterrupted light curve to determine physical and orbital parameters of the binary system. Photometric solutions of the spot model are obtained by using the W-D (Wilson and Devinney) method. It is confirmed that AI Dra is a semi-detached binary with secondary component filling its critical Roche lobe, which indicates that a mass transfer from the secondary component to the primary one should happen. Orbital period analysis based on all available eclipse times suggests a secular period increase and two cyclic variations. The secular period increase was interpreted by mass transfer from the secondary component to the primary one at a rate of 4.12 ×10^{-8}M_{⊙}/yr, which is in agreement with the photometric solutions. Two cyclic oscillations were due to light travel-time effect (LTTE) via the presence of two cool stellar companions in a near 2:1 mean-motion resonance. Both photometric solutions and orbital period analysis confirm that AI Dra is a mass-transferring binary, the massive primary is filling 69 % of its critical Roche lobe. After the primary evolves to fill the critical Roche lobe, the mass transfer will be reversed and the binary will evolve into a contact configuration.

  11. Assessing biogeochemical cycling and transient storage of surface water in Eastern Siberian streams using short-term solute additions

    Science.gov (United States)

    Schade, J. D.; Seybold, E.; Drake, T. W.; Bulygina, E. B.; Bunn, A. G.; Chandra, S.; Davydov, S.; Frey, K. E.; Holmes, R. M.; Sobczak, W. V.; Spektor, V. V.; Zimov, S. A.; Zimov, N.

    2009-12-01

    Recent studies highlight the role of stream networks in the processing of nutrient and organic matter inputs from the surrounding watershed. Clear evidence exists that streams actively regulate fluxes of carbon, nitrogen, and phosphorus from upland terrestrial ecosystems to downstream aquatic environments. This is of particular interest in Arctic streams because of the potential impact of permafrost thaw due to global warming on inputs of nutrients and organic matter to small streams high in the landscape. Knowledge of functional characteristics of these stream ecosystems is paramount to our ability to predict changes in stream ecosystems as climate changes. Biogeochemical models developed by stream ecologists, specifically nutrient spiraling models, provide a set of metrics that we used to assess nutrient processing rates in several streams in the Eastern Siberian Arctic. We quantified these metrics using solute addition experiments in which nitrogen and phosphorus were added simultaneously with chloride as a conservative tracer. We focused on 5 streams, three flowing across upland yedoma soils and two floodplain streams. Yedoma streams showed higher uptake of N than P, suggesting N limitation of biological processes, with large variation between these three streams in the severity of N limitation. Floodplain streams both showed substantially higher P uptake than N uptake, indicating strong P limitation. Given these results, it is probable that these two types of streams will respond quite differently to changes in nutrient and organic matter inputs as permafrost thaws. Furthermore, uptake was strongly linked to discharge and transient storage of surface water, measured using temporal patterns of the conservative tracer, with higher nutrient uptake in low discharge, high transient storage streams. Given the possibility that both discharge and nutrient inputs will increase as permafrost thaws, longer-term nutrient enrichment experiments are needed to develop

  12. Using neutron reflectometry and reflection geometry 'near-surface' SANS to investigate surfactant micelle organization at a solid-solution interface

    International Nuclear Information System (INIS)

    Hamilton, W.A.; Porcar, L.; Magid, L.J.

    2005-01-01

    We have used simultaneous neutron reflectometry (NR) and reflection geometry 'near-surface' small angle neutron scattering (NS-SANS) to investigate the ordering of cetyltrimethylammonium bromide (CTAB) micelles in aqueous (D2O) solution in the proximity of a quartz surface as a function of concentration and temperature. The NR measurements allow us to determine coherent micellar organization within a few thousand angstroms of the interface while NS-SANS allows simultaneous monitoring of 'bulk' states to the greater depth of grazing incidence penetration into the solution, typically 10-100μm. We illustrate the utility of this monitoring using the example of an apparent Poiseuille surface shear-induced change in micellar organization which is more probably the result of slight temperature increase

  13. Modeling solid-state dewetting of a single-crystal binary alloy thin films

    Science.gov (United States)

    Khenner, Mikhail

    2018-01-01

    Dewetting of a binary alloy thin film is studied using a continuum many-parameter model that accounts for the surface and bulk diffusion, the bulk phase separation, the surface segregation, and the particle formation. An analytical solution is found for the quasistatic equilibrium concentration of a surface-segregated atomic species. This solution is factored into the nonlinear and coupled evolution partial differential equations (PDEs) for the bulk composition and surface morphology. The stability of a planar film surface with respect to small perturbations of shape and composition is analyzed, revealing the dependence of the particle size on major physical parameters. The computations show various scenarios of the particle formation and the redistribution of the alloy components inside the particles and on their surface. In most situations, for the alloy film composed initially of 50% A and 50% B atoms, core-shell particles are formed, and they are located atop a wetting layer that is modestly rich in the B phase. Then the particle shell is the nanometric segregated layer of the A phase, and the core is the alloy that is modestly rich in the A phase.

  14. Relativistic Binaries in Globular Clusters

    Directory of Open Access Journals (Sweden)

    Matthew J. Benacquista

    2013-03-01

    Full Text Available Galactic globular clusters are old, dense star systems typically containing 10^4 – 10^6 stars. As an old population of stars, globular clusters contain many collapsed and degenerate objects. As a dense population of stars, globular clusters are the scene of many interesting close dynamical interactions between stars. These dynamical interactions can alter the evolution of individual stars and can produce tight binary systems containing one or two compact objects. In this review, we discuss theoretical models of globular cluster evolution and binary evolution, techniques for simulating this evolution that leads to relativistic binaries, and current and possible future observational evidence for this population. Our discussion of globular cluster evolution will focus on the processes that boost the production of tight binary systems and the subsequent interaction of these binaries that can alter the properties of both bodies and can lead to exotic objects. Direct N-body integrations and Fokker–Planck simulations of the evolution of globular clusters that incorporate tidal interactions and lead to predictions of relativistic binary populations are also discussed. We discuss the current observational evidence for cataclysmic variables, millisecond pulsars, and low-mass X-ray binaries as well as possible future detection of relativistic binaries with gravitational radiation.

  15. Real-time measurement system for tracking birefringence, weight, thickness, and surface temperature during drying of solution cast coatings and films

    Science.gov (United States)

    Unsal, E.; Drum, J.; Yucel, O.; Nugay, I. I.; Yalcin, B.; Cakmak, M.

    2012-02-01

    This paper describes the design and performance of a new instrument to track temporal changes in physical parameters during the drying behavior of solutions, as well as curing of monomers. This real-time instrument follows in-plane and out-of-plane birefringence, weight, thickness, and surface temperature during the course of solidification of coatings and films through solvent evaporation and thermal or photocuring in a controlled atmosphere. It is specifically designed to simulate behavior of polymer solutions inside an industrial size, continuous roll-to-roll solution casting line and other coating operations where resins are subjected to ultraviolet (UV) curing from monomer precursors. Controlled processing parameters include air speed, temperature, initial cast thickness, and solute concentration, while measured parameters are thickness, weight, film temperature, in-plane and out-of-plane birefringence. In this paper, we illustrate the utility of this instrument with solution cast and dried poly (amide-imide)/DMAc (Dimethylacetamide) solution, water based black paint, and organo-modified clay/NMP (N-Methylpyrrolidone) solution. In addition, the physical changes that take place during UV photo polymerization of a monomer are tracked. This instrument is designed to be generic and it can be used for tracking any drying/swelling/solidification systems including paper, foodstuffs such as; grains, milk as well as pharmaceutical thin paste and slurries.

  16. Discovery of a Faint Eclipsing Binary GSC 02265-01456 DF Guo1, K ...

    Indian Academy of Sciences (India)

    Abstract. When observing the transiting extrasolar planets, we found a new eclipsing binary named GSC 02265-01456. The V and Rc obser- vations were carried out for this binary. The photometric light curves of the two bands were simultaneously analyzed using the W–D code. The solutions show that GSC 02265-01456 ...

  17. Combined analysis of the binary lens caustic-crossing event MACHO 98-SMC-1

    NARCIS (Netherlands)

    Afonso, C; Alard, C; Albert, JN; Andersen, J; Ansari, R; Aubourg, E; Bareyre, P; Bauer, F; Beaulieu, JP; Bouquet, A; Char, S; Charlot, [No Value; Couchot, F; Coutures, C; Derue, F; Ferlet, R; Glicenstein, JF; Goldman, B; Gould, A; Graff, D; Gros, M; Haissinski, J; Hamilton, JC; Hardin, D; de Kat, J; Kim, A; Lasserre, T; Lesquoy, E; Loup, C; Magneville, C; Marquette, JB; Maurice, E; Milsztajn, A; Moniez, M; Palanque-Delabrouille, N; Perdereau, O; Prevot, L; Regnault, N; Rich, J; Spiro, M; Vidal-Madjar, A; Vigroux, L; Zylberajch, S; Alcock, C; Allsman, RA; Alves, D; Axelrod, TS; Becker, AC; Cook, KH; Drake, AJ; Freeman, KC; Griest, K; King, LJ; Lehner, MJ; Marshall, SL; Minniti, D; Peterson, BA; Pratt, MR; Quinn, PJ; Rodgers, AW; Stetson, PB; Stubbs, CW; Sutherland, W; Tomaney, A; Vandehei, T; Rhie, SH; Bennett, DP; Fragile, PC; Johnson, BR; Quinn, J; Udalski, A; Kubiak, M; Szymanski, M; Pietrzynski, G; Wozniak, P; Zebrun, K; Albrow, MD; Caldwell, JAR; DePoy, DL; Dominik, M; Gaudi, BS; Greenhill, J; Hill, K; Kane, S; Martin, R; Menzies, J; Pogge, RW; Pollard, KR; Sackett, PD; Sahu, KC; Vermaak, P; Watson, R; Williams, A

    2000-01-01

    We fit the data for the binary lens microlensing event MACHO 98-SMC-1 from five different microlensing collaborations and find two distinct solutions characterized by binary separation d and mass ratio q: (d, q) = (0.54, 0.50) and (d, q) = (3.65, 0.36), where d is in units of the Einstein radius.

  18. Spectral properties of binary asteroids

    Science.gov (United States)

    Pajuelo, Myriam; Birlan, Mirel; Carry, Benoît; DeMeo, Francesca E.; Binzel, Richard P.; Berthier, Jérôme

    2018-04-01

    We present the first attempt to characterize the distribution of taxonomic class among the population of binary asteroids (15% of all small asteroids). For that, an analysis of 0.8-2.5{μ m} near-infrared spectra obtained with the SpeX instrument on the NASA/IRTF is presented. Taxonomic class and meteorite analog is determined for each target, increasing the sample of binary asteroids with known taxonomy by 21%. Most binary systems are bound in the S-, X-, and C- classes, followed by Q and V-types. The rate of binary systems in each taxonomic class agrees within uncertainty with the background population of small near-Earth objects and inner main belt asteroids, but for the C-types which are under-represented among binaries.

  19. Planets in Binary Star Systems

    CERN Document Server

    Haghighipour, Nader

    2010-01-01

    The discovery of extrasolar planets over the past decade has had major impacts on our understanding of the formation and dynamical evolution of planetary systems. There are features and characteristics unseen in our solar system and unexplainable by the current theories of planet formation and dynamics. Among these new surprises is the discovery of planets in binary and multiple-star systems. The discovery of such "binary-planetary" systems has confronted astrodynamicists with many new challenges, and has led them to re-examine the theories of planet formation and dynamics. Among these challenges are: How are planets formed in binary star systems? What would be the notion of habitability in such systems? Under what conditions can binary star systems have habitable planets? How will volatiles necessary for life appear on such planets? This volume seeks to gather the current research in the area of planets in binary and multistar systems and to familiarize readers with its associated theoretical and observation...

  20. The effect of surface-active solutes on water flow and contaminant transport in variably saturated porous media with capillary fringe effects.

    Science.gov (United States)

    Henry, E J; Smith, J E

    2002-06-01

    Organic contaminants that decrease the surface tension of water (surfactants) can have an effect on unsaturated flow through porous media due to the dependence of capillary pressure on surface tension. We used an intermediate-scale 2D flow cell (2.44 x 1.53 x 0.108 m) packed with a fine silica sand to investigate surfactant-induced flow perturbations. Surfactant solution (7% 1-butanol and dye tracer) was applied at a constant rate at a point source located on the soil surface above an unconfined synthetic aquifer with ambient groundwater flow and a capillary fringe of approximately 55 cm. A glass plate allowed for visual flow and transport observations. Thirty instrumentation stations consist of time domain reflectometry probes and tensiometers measured in-situ moisture content and pressure head, respectively. As surfactant solution was applied at the point source, a transient flow perturbation associated with the advance of the surfactant solution was observed. Above the top of the capillary fringe the advance of the surfactant solution caused a visible drainage front that radiated from the point source. Upon reaching the capillary fringe, the drainage front caused a localized depression of the capillary fringe below the point source because the air-entry pressure decreased in proportion to the decrease in surface tension caused by the surfactant. Eventually, a new capillary fringe height was established. The height of the depressed capillary fringe was proportional to height of the initial capillary fringe multiplied by the relative surface tension of the surfactant solution. The horizontal transport of surfactant in the depressed capillary fringe, driven primarily by the ambient groundwater flow, caused the propagation of a wedge-shaped drying front in the downgradient direction. Comparison of dye transport during the surfactant experiment to dye transport in an experiment without surfactant indicated that because surfactant-induced drainage decreased the