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Sample records for binary miscibility gap

  1. No miscibility gap in Pt–Rh binary alloys: A first-principles study

    International Nuclear Information System (INIS)

    Recently, diffraction experiments and bond-order calculations gave given cause for distrust in the widely accepted phase diagram of binary Pt–Rh, suggesting it forms a solid solution below 1100 K. This is in contrast to the phase diagram published by Raub in 1959. In order to clarify this situation, we use a first-principles approach to conduct an exhaustive ground-state search and set up a cluster-expansion Hamiltonian. This allows for grand-canonical Monte-Carlo simulations in order to investigate the phase behavior. We show that the miscibility gap does not in fact exist. We also present simulated diffraction patterns extracted from the cluster-expansion Hamiltonian, which are in good agreement with experimental data.

  2. Molecular Driving Forces behind the Tetrahydrofuran-Water Miscibility Gap.

    Science.gov (United States)

    Smith, Micholas Dean; Mostofian, Barmak; Petridis, Loukas; Cheng, Xiaolin; Smith, Jeremy C

    2016-02-01

    The tetrahydrofuran-water binary system exhibits an unusual closed-loop miscibility gap (transitions from a miscible regime to an immiscible regime back to another miscible regime as the temperature increases). Here, using all-atom molecular dynamics simulations, we probe the structural and dynamical behavior of the binary system in the temperature regime of this gap at four different mass ratios, and we compare the behavior of bulk water and tetrahydrofuran. The changes in structure and dynamics observed in the simulations indicate that the temperature region associated with the miscibility gap is distinctive. Within the miscibility-gap temperature region, the self-diffusion of water is significantly altered and the second virial coefficients (pair-interaction strengths) show parabolic-like behavior. Overall, the results suggest that the gap is the result of differing trends with temperature of minor structural changes, which produces interaction virials with parabolic temperature dependence near the miscibility gap. PMID:26734991

  3. The liquid metastable miscibility gap in Cu-based systems

    DEFF Research Database (Denmark)

    Curiotto, S.; Greco, R.; Pryds, Nini;

    2007-01-01

    Some Cu-based alloys, like Cu–Co, Cu–Fe and Cu–Co–Fe, display a liquid metastable miscibility gap. When the melt is undercooled below a certain temperature depending on the alloy composition, they present a separation in two liquid phases, followed by coagulation before dendritic solidification....... In order to predict the phase equilibria and the mechanisms of microstructure formation, a determination of the metastable monotectics in the phase diagrams is essential. This paper focuses on the up-to-date findings on the Cu–Co, Cu–Fe and Cu–Co–Fe metastable miscibility gap in the liquid phase...

  4. Phase separation in transparent liquid-liquid miscibility gap systems

    International Nuclear Information System (INIS)

    A program to be carried out on transparent liquid-phase miscibility gap materials was developed for the purpose of acquiring additional insight into the separation process occurring in these systems. The transparency feature allows the reaction to be viewed directly through light scattering and holographic methods

  5. Phase separation in transparent liquid-liquid miscibility gap systems

    Science.gov (United States)

    Gelles, S. H.; Bhat, B. N.; Laub, R. J.

    1979-01-01

    A program to be carried out on transparent liquid-phase miscibility gap materials was developed for the purpose of acquiring additional insight into the separation process occurring in these systems. The transparency feature allows the reaction to be viewed directly through light scattering and holographic methods.

  6. Transport phenomena and microscopic structure in partially miscible binary fluids: A simulation study of the symmetrical Lennard-Jones mixture

    OpenAIRE

    Das, Subir K.; Horbach, Jürgen; Binder, Kurt

    2003-01-01

    Static and dynamic structure factors and various transport coefficients are computed for a Lennard-Jones model of a binary fluid (A,B) with a symmetrical miscibility gap, varying both temperature and relative concentration of the mixture. The model is first equilibrated by a semi-grandcanonical Monte Carlo method, choosing the temperature and chemical potential difference $\\Delta \\mu$ between the two species as the given independent variables. Varying for $\\Delta \\mu=0$ the temperature and pa...

  7. Direct Measurement of the Metastable Liquid Miscibility Gap in Fe-Co-Cu Ternary Alloy System

    Institute of Scientific and Technical Information of China (English)

    CAO Chong-De; Georg P.G(O)RLER

    2005-01-01

    @@ The metastable liquid-liquid phase separation in undercooled Fe-Co-Cu ternary alloy melts (XCu = 0.10-0.84;XCo:XFe = 1:3,1:1 and 3:1) is investigated by differential thermal analysis in combination with glass fluxing technique. In almost every case, the undercooling of the homogeneous alloy melt was sufficient to reach the boundary line of the submerged miscibility gap. The differential-thermal-analysis signals indicate that this separation into a (Fe, Co)-rich liquid phase L1 and a Cu-rich liquid L2 is exothermic and proceeds until the rapid solidification of the L1 phase occurs. At a given Cu concentration and with the increase of Co content, the phase separation temperatures decrease monotonically between the corresponding values of the boundary systems Fe-Cu and Co-Cu. The boundary lines of the miscibility gap, which are determined for the three quasi-binary cross-sections of the (Fe, Co)-Cu alloy system, show remarkably flat domes. The occurrence of the liquid phase separation shows an evident influence on the subsequent γ-Fe(Co, Cu)→α-Fe(Co, Cu) solid phase transformation.

  8. Flash-Point prediction for binary partially miscible aqueous-organic mixtures

    OpenAIRE

    Liaw, Horng-Jang; Chen, Chien Tsun; Gerbaud, Vincent

    2008-01-01

    Flash point is the most important variable used to characterize fire and explosion hazard of liquids. Herein, partially miscible mixtures are presented within the context of liquid-liquid extraction processes and heterogeneous distillation processes. This paper describes development of a model for predicting the flash point of binary partially miscible mixtures of aqueous-organic system. To confirm the predictive efficiency of the derived flash points, the model was verified by comparing the ...

  9. Review of small angle neutron scattering for measuring miscibility binary polymeric mixtures

    International Nuclear Information System (INIS)

    Blending polymers is intended for developing new materials with superior properties. Multiphase appeared in polymer blends demand the fundamental relationships of structure and properties from the individual constituent polymers to control the structures satisfying the properties required. The relationships concern with the molecular parameters such as miscibility, phase diagrams, and critical phenomena. Binary blends of polidienes are preferable systems for such studies and Small Angle Neutron Scattering (SANS) is a powerful technique for the study of it. As an example the measurement of the binary blend polymers miscibility of protonated polybutadiene and deuterated polybutadiene, PBH and PBD using SANS which has been done by Sinichi Sakurai was reviewed. (author)

  10. Closure of the Fe-S-Si liquid miscibility gap at high pressure

    Science.gov (United States)

    Sanloup, C.; Fei, Y.

    2004-10-01

    A high pressure investigation of melting relationships in the Fe-S-Si system has been conducted in a multi-anvil apparatus from 10 to 27 GPa and up to 2343 K. At 1 atm, the Fe-S-Si ternary system exhibits a vast miscibility gap [Raghavan, V., 1988. Phase diagrams of ternary iron alloys. Part 2: Ternary systems containing iron and sulphur. Indian Institute of Metals, Calcutta]. Quenched samples from experiments conducted at 10 and 12 GPa show an emulsion of immiscible liquids (an Fe-S melt and an Fe-Si melt). The liquid miscibility gap persists to at least 2343 K at 10 GPa. At 15 GPa, only one liquid is quenched, with a fine homogeneous dendritic texture. The results provide a mechanism to incorporate both S and Si as the light elements into the Earth's core during a moderately high-pressure differentiation, consistent with geochemical models predicting up to 15 wt.% of light elements in the Earth's core with 2-5 wt.% S and 7-10 wt.% Si. In contrast, for small planets such as Mars and Ganymede, differentiation took place within the pressure range of the miscibility gap. The composition of these cores is likely to be S-rich but Si-poor.

  11. Miscibility gap in the U-Nd-O phase diagram: a new approach of nuclear oxides in the environment?

    International Nuclear Information System (INIS)

    To some extent, rare-earth-doped UO2 is representative of an irradiated nuclear fuel. The two phases we observed previously in neodymium-doped UO2 are now interpreted as the existence of a miscibility gap in the U-Nd-O phase diagram using new results obtained with Raman spectroscopy. Extrapolating the miscibility gap in the U-Nd-O phase diagram to irradiated UO2 opens the path to a new understanding of nuclear oxides in the environment. (authors)

  12. Oxygen miscibility gap and spin glass formation in the pyrochlore Lu2Mo2O7

    International Nuclear Information System (INIS)

    Rare earth (R) molybdate pyrochlores, R2Mo2O7, are of interest as frustrated magnets. Polycrystalline samples of Lu2Mo2O7−x prepared at 1600 °C display a coexistence of cubic pyrochlore phases. Rietveld fits to powder neutron diffraction data and chemical analyses show that the miscibility gap is between a stoichiometric x=0 and an oxygen-deficient x≈0.4 phase. Lu2Mo2O7 behaves as a spin glass material, with a divergence of field cooled and zero field cooled DC magnetic susceptibilities at a spin freezing temperature Tf=16 K, that varies with frequency in AC measurements following a Vogel–Fulcher law. Lu2Mo2O6.6 is more highly frustrated spin glass and has Tf=20 K. - Graphical abstract: The cubic Lu2Mo2O7−x system exhibits a miscibility gap between coexisting pyrochlore phases at 1600 °C. Neutron powder diffraction refinement and chemical analysis shows that the gap separates stoichiometric x=0 and oxygen-deficient x≈0.4 phases. Lu2Mo2O7−x has a frustrated spin glass ground state that is sensitive to the oxygen content. - Highlights: • The cubic Lu2Mo2O7−x system has a miscibility gap between coexisting pyrochlore phases at 1600 °C. • Neutron powder diffraction shows that the gap separates x=0 and oxygen-deficient x≈0.4 phases. • Lu2Mo2O7−x has a frustrated spin glass ground state that is sensitive to the oxygen content

  13. Microstructural Evolution of Alloy Powder for Electronic Materials with Liquid Miscibility Gap

    Science.gov (United States)

    Ohnuma, I.; Saegusa, T.; Takaku, Y.; Wang, C. P.; Liu, X. J.; Kainuma, R.; Ishida, K.

    2009-01-01

    The microstructure of powders that are applicable for electronic materials were studied for some systems in which there is a liquid miscibility gap. The characteristic morphologies of an egg-like core type and a uniform second-phase dispersion are shown in relation to the phase diagram, where thermodynamic calculations are a powerful tool for alloy design and the prediction of microstructure. Typical examples of microstructural evolution and properties of Pb-free solders and Ag-based micropowders with high electrical conductivity produced by a gas-atomizing method are presented.

  14. Low temperature synthesis of Ru–Cu alloy nanoparticles with the compositions in the miscibility gap

    Energy Technology Data Exchange (ETDEWEB)

    Martynova, S.A. [Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090 (Russian Federation); Filatov, E.Yu., E-mail: decan@niic.nsc.ru [Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Korenev, S.V.; Kuratieva, N.V. [Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Sheludyakova, L.A. [Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090 (Russian Federation); Plusnin, P.E.; Shubin, Yu.V. [Nicolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation); Slavinskaya, E.M. [Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090 (Russian Federation); Boronin, A.I. [Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090 (Russian Federation); Novosibirsk State University, Novosibirsk 630090 (Russian Federation)

    2014-04-01

    A complex salt [Ru(NH{sub 3}){sub 5}Cl][Cu(C{sub 2}O{sub 4}){sub 2}H{sub 2}O]—the precursor of nanoalloys combining ruthenium and copper was prepared. It crystallizes in the monoclinic space group P2{sub 1}/n. Thermal properties of the prepared salt were examined in different atmospheres (helium, hydrogen, oxygen). Thermal decomposition of the precursor in inert atmosphere was thoroughly examined and the intermediate products were characterized. Experimental conditions for preparation of copper-rich (up to 12 at% of copper) metastable solid solution Cu{sub x}Ru{sub 1−x} (based on Ru structure) were optimized, what is in sharp contrast to the bimetallic miscibility gap known for the bulk counterparts in a wide composition range. Catalytic properties of copper–ruthenium oxide composite were tested in catalytic oxidation of CO. - Highlights: • We synthesized new precursor of CuRu metastable nanoalloys. • Thermal properties of the prepared salt were examined in different atmospheres. • Thermodestruction mechanism of precursor are studied. • Cu{sub 0.12}Ru{sub 0.88} nanoalloy with the compositions in the miscibility gap is obtained. • Catalytic conversion of CO on copper–ruthenium oxide composite were examined.

  15. Calculation of activities in some gallium-based systems with a miscibility gap

    Directory of Open Access Journals (Sweden)

    IWAO KATAYAMA

    2003-09-01

    Full Text Available The calculations of thermodynamic properties in some gallium-based systems with a miscibility gap – Ga–Tl, Ga–Hg and Ga–Pb are presented in this paper. The determination of the gallium activities in the mentioned liquid alloys was based on their known phase diagrams using the Zhang-Chou method for calculating activities from phase diagrams involving two liquid or solid coexisting phases. The activities of gallium in Ga–Tl, Ga–Hg and Ga–Pb system were calculated in the 973–1273 K, 573–873 K and 1000–1100 K, temperature ranges, respectively. The activities of the other component in all the investigated systems were obtained by the Gibbs-Duhem equation. The results of the calculations are compared with literature data.

  16. Miscibility and Phase Behavior of N-Acylethanolamine/Diacylphosphatidylethanolamine Binary Mixtures of Matched Acyl Chainlengths (n = 14, 16)

    Science.gov (United States)

    Kamlekar, Ravi Kanth; Satyanarayana, S.; Marsh, Derek; Swamy, Musti J.

    2007-01-01

    The miscibility and phase behavior of hydrated binary mixtures of two N-acylethanolamines (NAEs), N-myristoylethanolamine (NMEA), and N-palmitoylethanolamine (NPEA), with the corresponding diacyl phosphatidylethanolamines (PEs), dimyristoylphosphatidylethanolamine (DMPE), and dipalmitoylphosphatidylethanolamine (DPPE), respectively, have been investigated by differential scanning calorimetry (DSC), spin-label electron spin resonance (ESR), and 31P-NMR spectroscopy. Temperature-composition phase diagrams for both NMEA/DMPE and NPEA/DPPE binary systems were established from high sensitivity DSC. The structures of the phases involved were determined by 31P-NMR spectroscopy. For both systems, complete miscibility in the fluid and gel phases is indicated by DSC and ESR, up to 35 mol % of NMEA in DMPE and 40 mol % of NPEA in DPPE. At higher contents of the NAEs, extensive solid-fluid phase separation and solid-solid immiscibility occur depending on the temperature. Characterization of the structures of the mixtures formed with 31P-NMR spectroscopy shows that up to 75 mol % of NAE, both DMPE and DPPE form lamellar structures in the gel phase as well as up to at least 65°C in the fluid phase. ESR spectra of phosphatidylcholine spin labeled at the C-5 position in the sn-2 acyl chain present at a probe concentration of 1 mol % exhibit strong spin-spin broadening in the low-temperature region for both systems, suggesting that the acyl chains pack very tightly and exclude the spin label. However, spectra recorded in the fluid phase do not exhibit any spin-spin broadening and indicate complete miscibility of the two components. The miscibility of NAE and diacyl PE of matched chainlengths is significantly less than that found earlier for NPEA and dipalmitoylphosphatidylcholine, an observation that is consistent with the notion that the NAEs are most likely stored as their precursor lipids (N-acyl PEs) and are generated only when the system is subjected to membrane stress. PMID

  17. Miscibility gap alloys with inverse microstructures and high thermal conductivity for high energy density thermal storage applications

    International Nuclear Information System (INIS)

    New high energy-density thermal storage materials are proposed which use miscibility gap binary alloy systems to operate through the latent heat of fusion of one component dispersed in a thermodynamically stable matrix. Using trial systems Al–Sn and Fe–Cu, we demonstrate the development of the required inverse microstructure (low melting point phase embedded in high melting point matrix) and excellent thermal storage potential. Several other candidate systems are discussed. It is argued that such systems offer enhancement over conventional phase change thermal storage by using high thermal conductivity microstructures (50–400 W/m K); minimum volume of storage systems due to high energy density latent heat of fusion materials (0.2–2.2 MJ/L); and technical utility through adaptability to a great variety of end uses. Low (<300 °C), mid (300–400 °C) and high (600–1400 °C) temperature options exist for applications ranging from space heating and process drying to concentrated solar thermal energy conversion and waste heat recovery. -- Highlights: ► Alloys of immiscible metals are proposed as thermal storage systems. ► High latent heat of fusion per unit volume and tunable temperature are advantageous. ► Thermal storage systems with capacities of 0.2–2.2 MJ/L are identified. ► Heat delivery is via a rigid non-reactive high thermal conductivity matrix. ► The required inverse microstructures were developed for Sn–Al and Cu–Fe systems

  18. Estimation of CE–CVM energy parameters from miscibility gap data

    Indian Academy of Sciences (India)

    G Srinivasa Gupta; G Vamsi Madhav; A Pandey; B Nageswara Sarma; S Lele

    2005-04-01

    The powerful framework of cluster expansion–cluster variation methods (CE–CVM) expresses alloy free energy in terms of energy (model) parameters, macroscopic variables (composition and temperature) and microscopic variables (correlation functions). A simultaneous optimization of thermodynamic and phase equilibria data using CE–CVM is critically dependent on giving good initial values of energy parameters, macroscopic and microscopic variables, respectively. No standard method for obtaining the initial values of the energy parameters is available in literature. As a starting point, a method has been devised to estimate the values of energy parameters from consolute point (miscibility gap maximum) data. Empirical relations among energy parameters, temperature (c), composition (c) and 2}/2 at the consolute point, have been developed using CE–CVM free energy functions for bcc and fcc structures in the tetrahedron and tetrahedron–octahedron approximations, respectively. Thus from the observed data of c, c and 2}/2 in the above relations, good initial values of energy parameters can be obtained. Further, a necessary modification to the classical NR method for solving simultaneous nonlinear/transcendental equations with a double root in one variable and a simple root in the other has been presented.

  19. Enhanced sampling simulation analysis of the structure of lignin in the THF-water miscibility gap.

    Science.gov (United States)

    Smith, Micholas Dean; Petridis, Loukas; Cheng, Xiaolin; Mostofian, Barmak; Smith, Jeremy C

    2016-03-01

    Using temperature replica-exchange molecular dynamics, we characterize a globule-to-coil transition for a softwood-like lignin biopolymer in a tetrahydrofuran (THF)-water cosolvent system at temperatures at which the cosolvent undergoes a de-mixing transition. The lignin is found to be in a coil state, similar to that in the high-temperature miscible region. Analysis of the transition kinetics indicates that THF acts in a surfactant-like fashion. The present study thus suggests that THF-water based pretreatments may efficiently remove lignin from biomass even at relatively low (non-water boiling) temperatures. PMID:26862597

  20. Microstructure Evolution in a Rapidly Solidified Cu85Fe15 Alloy Undercooled into the Metastable Miscibility Gap

    Institute of Scientific and Technical Information of China (English)

    Jie HE; Jiuzhou ZHAO

    2005-01-01

    A model has been developed to describe the microstructure evolution in the atomized droplets of Cu-Fe alloy during cooling through the metastable miscibility gap. Calculations have been performed for Cu85Fe15 alloy to investigate the process of liquid-liquid phase transformation. The numerical results indicate that the minority phase droplets are nucleated in a temperature region around the peak of the supersaturation. The average radius of the Fe-rich droplets decreases and the number density of the minority phase droplets increases with decreasing the atomized droplet size.The simulated results were compared with the experimental ones. The kinetic process of the liquid-liquid phase transformation was discussed in detail.

  1. Existence of a miscibility gap in the U-Nd-O ternary system and its relationship with the HBS of irradiated nuclear fuel

    International Nuclear Information System (INIS)

    Today, the most used nuclear fuel in pressurized water reactors operating in French power plants is uranium dioxide UO2. Under irradiation, this ceramic undergoes many modifications, a very interesting one is the incorporation of fission products (Nd,Ce,Eu..) in the crystallographic structure of the fuel. In this thesis, we focused on the modifications of the crystallographic structures of the fuel caused by fission product incorporation. In order to achieve this objective, we conceived a plan formed by steps of increasing complexity and involving two types of materials: non irradiated nuclear fuel (U1-yNdy)O2 (neodymium is the most abundant cationic fission product), and highly irradiated UO2 fuels. Firstly, we have studied the evolution of crystallographic structure of a sample (U1-yNdy)O2 during an annealing treatment. The results allowed us to confirm a previous hypothesis formulated in the group suggesting that Nd is not totally soluble in UO2, as traditionally considered. Instead of that, there is a miscibility gap in the ternary system U-Nd-O. Afterwards, we have characterized this miscibility gap, determining its tie-lines by means of two approaches: a) experimentally, by means of XRD measurements, to estimate the chemical composition of both phases in the biphasic samples, b) theoretically, by means of the thermodynamic assessment of the phase diagram U-Nd-O by the CALPHAD method, including for the assessment the tie-lines previously calculated for our samples, in order to determine the tie-lines for all composition and temperatures of this miscibility gap. We have also distinguished many others systems (U,L)O2 (U,L,L')O2, in which 'L' means lanthanides or actinides existing in the irradiated fuel, that exhibit a miscibility gap. As a consequence, we formulated the hypothesis that a miscibility gap could also exist in the irradiated fuel, which could be, consequently, considered as a pseudo phase diagram U-PF-O (PF: cationic fission products

  2. General continuum boundary conditions for miscible binary fluids from molecular dynamics simulations.

    Science.gov (United States)

    Denniston, Colin; Robbins, Mark O

    2006-12-01

    Molecular dynamics simulations are used to explore the flow behavior and diffusion of miscible fluids near solid surfaces. The solid produces deviations from bulk fluid behavior that decay over a distance of the order of the fluid correlation length. Atomistic results are mapped onto two types of continuum model: Mesoscopic models that follow this decay and conventional sharp interface boundary conditions for the stress and velocity. The atomistic results, and mesoscopic models derived from them, are consistent with the conventional Marangoni stress boundary condition. However, there are deviations from the conventional Navier boundary condition that states that the slip velocity between wall and fluid is proportional to the strain rate. A general slip boundary condition is derived from the mesoscopic model that contains additional terms associated with the Marangoni stress and diffusion, and is shown to describe the atomistic simulations. The additional terms lead to strong flows when there is a concentration gradient. The potential for using this effect to make a nanomotor or pump is evaluated. PMID:17166010

  3. Experiments and Direct Numerical Simulations of binary collisions of miscible liquid droplets with different viscosities

    CERN Document Server

    Focke, C; Kuschel, M; Sommerfeld, M

    2012-01-01

    Binary droplet collisions are of importance in a variety of practical applications comprising dispersed two-phase flows. The background of our research is the prediction of properties of particulate products formed in spray processes. To gain a more thorough understanding of the elementary sub-processes inside a spray, experiments and direct numerical simulations of binary droplet collisions are used. The aim of these investigations is to develop semi-analytical descriptions for the outcome of droplet collisions. Such collision models can then be employed as closure terms for scale-reduced simulations. In the present work we focus on the collision of droplets of different liquids. These kinds of collisions take place in every spray drying process when droplets with different solids contents collide in recirculation zones. A new experimental method has been developed allowing for high spatial and time resolved recordings via Laser-induced fluorescence. The results obtained with the proposed method will be comp...

  4. The role of magnetism in the formation of the two-phase miscibility gap in β Cu–Al–Mn

    Energy Technology Data Exchange (ETDEWEB)

    Lanzini, Fernando, E-mail: flanzini@exa.unicen.edu.ar [Instituto de Física de Materiales Tandil (IFIMAT), Universidad Nacional del Centro de la Provincia de Buenos Aires (UNCPBA), Pinto 399, 7000 Tandil (Argentina); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) (Argentina); Alés, Alejandro [Instituto de Física de Materiales Tandil (IFIMAT), Universidad Nacional del Centro de la Provincia de Buenos Aires (UNCPBA), Pinto 399, 7000 Tandil (Argentina); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) (Argentina)

    2015-12-01

    A theoretical study of the ground state properties of alloys with compositions along the pseudobinary line Cu{sub 3}Al–Cu{sub 2}AlMn is presented. Cohesive energies, lattice parameters and magnetic moments of the two limiting compounds and three intermediate compositions are calculated by means of density functional theory. In order to evaluate the role of magnetism, both the spin-polarized (SP) and the non spin-polarized (NSP) cases have been considered. It is shown that magnetism plays a central role on the stabilization of the L2{sub 1} crystal structure in Cu{sub 2}AlMn, and in the formation of the miscibility gap in Cu{sub 3}Al–Cu{sub 2}AlMn. The considerable lattice mismatch between the end compounds can be attributed also to magnetic effects. - Highlights: • Alloys with compositions Cu{sub 3−x}AlMn{sub x} were studied by first principles methods. • Both spin-polarized (SP) and non-spin-polarized (NSP) calculations were done. • Cohesive energies, lattice parameters and magnetic moments were determined. • The phase separation Cu{sub 3}Al+Cu{sub 2}AlMn is attributable to magnetic effects. • In the NSP case, L2{sub 1} Cu{sub 2}AlMn is predicted to be unstable against the F43m structure.

  5. Structural and dynamical heterogeneity of undercooled Fe{sub 75}Cu{sub 25} melts with miscibility gap

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Yu; Wang, Li; Wang, Shenghai, E-mail: shenghaiw@163.com; Li, Xuelian; Cui, Wenchao

    2014-12-05

    Highlights: • We simulate the undercooled Fe{sub 75}Cu{sub 25} melts with miscibility gap at atomic level. • Fe{sub 75}Cu{sub 25} melts separate into Cu-rich and Fe-rich liquid upon relaxation. • The process is controlled by the nucleation and grows mechanism. • Both PPCFs and CN confirm that L–L phase separation is a successive process. - Abstract: Molecular dynamics simulation (MD) based upon the developed embedded atom method (EAM) has been performed to explore the structural and dynamical heterogeneity of Fe{sub 75}Cu{sub 25} melts. The results show that the melts separate into Cu-rich droplets surround by the Fe-rich matrix controlled by nucleation and growth mechanism. The larger undercoolings suggest the higher nucleation rate and growth rate of droplets. The growth of droplet is achieved by the aggregation and coagulation of neighbor droplet with the characteristics of collective movement for homogeneous atoms. A sharp increase of S{sub CC} (q = 0) is found at all simulated temperature, which means concentration fluctuation on large length scales are much pronounced. Both partial pair correlation functions (PPCFs) and coordination number (CN) confirm that liquid–liquid (L–L) phase separation is a successive process with a stronger interaction of homogeneous pairs than that of heterogeneous pairs in Fe{sub 75}Cu{sub 25} melts. The studies above characterize the phase separation of metal melts on the atomic scale.

  6. Miscibility of Two Components in a Binary Mixture of 9-Phenyl Anthracene Mixed with Stearic Acid or Polymethyl Methacrylate at Air-Water Interface

    Institute of Scientific and Technical Information of China (English)

    P. K. Paul; Md. N. Islam; D. Bhattacharjee; S. A. Hussain

    2007-01-01

    We report the miscibility characteristics of two components in a binary mixture of 9-phenyl anthracene (PA) mixed with stearic acid (SA) or polymethyl methacrylate (PMMA). The behaviour of surface pressure versus area per molecule isotherms reveal that the area per molecule decreases systematically with increasing molefractions of PA. The characteristics of areas per molecule versus molefractions and collapse pressure vs molefraction indicate that various interactions involved among the sample and matrix molecules. The interaction scheme is found to change with the change in surface pressure and molefraction of mixing. Scanning electron microscopic study confirms the aggregation of PA molecules in the mixed films.

  7. Binary Disk interaction II: Gap-Opening criteria for unequal mass binaries

    CERN Document Server

    del Valle, Luciano

    2013-01-01

    We study the interaction between an unequal mass binary with an isothermal circumbinary disk, motivated by the theoretical and observational evidence that after a major merger of gas-rich galaxies, a massive gaseous disk with a SMBH binary will be formed in the nuclear region. We focus on the gravitational torques that the binary exerts onto the disk and how these torques can drive the formation of a gap in the disk. This exchange of angular momentum between the binary and the disk is mainly driven by the gravitational interaction between the binary and a strong non-axisymmetric density perturbation that is produced in the disk, as response to the presence of the binary. Using SPH numerical simulations we tested two gap-opening criterion, one that assumes that the geometry of the density perturbation is an ellipsoid/thick-spirals and another that assumes a geometry of flat-spirals for the density perturbation. We find that the flat-spirals gap opening criterion successfully predicts which simulations will hav...

  8. Determination of the equilibrium miscibility gap in the Pd-Rh alloy system using metal nanopowders obtained by decomposition of coordination compounds

    International Nuclear Information System (INIS)

    Highlights: • The Pd-Rh phase diagram has been experimentally reinvestigated. • The true equilibrium was achieved with the two-way approach. • The critical point of the miscibility gap lie at 58 at.% Rh and 820 °C. - Abstract: The Pd-Rh phase diagram has been reinvestigated in the subsolidus region using X-ray diffraction, scanning and transmission electron microscopy. The true equilibrium at the miscibility boundary was achieved with the two-way approach. Nanosized powders of metastable solid solutions and two-phase palladium-rhodium mixtures were used to shorten the time required to equilibrate the system. The initial samples were prepared by decomposition of coordination compounds [Pd(NH3)2Cl2], [Rh(NH3)5Cl]Cl2, [Pd(NH3)4]3[Rh(NO2)6]2 and [Pd(NH3)4][Rh(NH3)(NO2)5]. The obtained phase diagram exhibits miscibility gap wider than generally accepted with the critical point of solubility at 58 at.% Rh and 820 °C

  9. Miscibility gap and phonon thermodynamics of Fe-Au alloys studied by inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering

    Energy Technology Data Exchange (ETDEWEB)

    Muñoz, Jorge A. [Intel Corporation, Information Technology Research, Hillsboro, OR 97124 (United States); Fultz, Brent [California Institute of Technology, Department of Applied Physics and Materials Science, Pasadena, CA 91125 (United States)

    2015-07-23

    Recent measurements of the phonon spectra of several Au-rich alloys of face-centered-cubic Fe-Au using inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering are summarized. The Wills-Harrison model, accounting for charge transfer upon alloying, is used to explain the observed negative excess vibrational entropy of mixing, which increases the miscibility gap temperature in the system by an estimated maximum of 550 K and we adjudicate to a charge transfer from the Fe to the Au atoms that results in an increase in the electron density in the free-electron-like states and in stronger sd-hybridization. When Au is the solvent, this softens the Fe–Fe bonds but stiffens the Au–Au and Au–Fe bonds which results in a net stiffening relative to the elemental components.

  10. Miscibility gap and phonon thermodynamics of Fe-Au alloys studied by inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering

    International Nuclear Information System (INIS)

    Recent measurements of the phonon spectra of several Au-rich alloys of face-centered-cubic Fe-Au using inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering are summarized. The Wills-Harrison model, accounting for charge transfer upon alloying, is used to explain the observed negative excess vibrational entropy of mixing, which increases the miscibility gap temperature in the system by an estimated maximum of 550 K and we adjudicate to a charge transfer from the Fe to the Au atoms that results in an increase in the electron density in the free-electron-like states and in stronger sd-hybridization. When Au is the solvent, this softens the Fe–Fe bonds but stiffens the Au–Au and Au–Fe bonds which results in a net stiffening relative to the elemental components

  11. Thermodynamic analysis of the Ga-Pb binary system

    Directory of Open Access Journals (Sweden)

    Manasijević Dragan

    2003-01-01

    Full Text Available Thermodynamic properties of binary Ga-Pb alloys were investigated experimentally and analytically. Quantitative differential thermal analysis was used for determination of integral mixing enthalpies for the gallium-reach alloys, at the constant temperature inside the liquid two-phase region. Calculation of gallium activities in the temperature range of 800-1000 K was done using Chou’s calculation model developed for binary systems with miscibility gap existence.

  12. The Effect of Data Gaps on LISA Galactic Binary Parameter Estimation

    CERN Document Server

    Carré, Jérôme

    2010-01-01

    In the last few years there has been an enormous effort in parameter estimation studies for different sources with the space based gravitational wave detector, LISA. While these studies have investigated sources of differing complexity, the one thing they all have in common is they assume continuous data streams. In reality, the LISA data stream will contain gaps from such possible events such as repointing of the satellite antennae, to discharging static charge build up on the satellites, to disruptions due to micro-meteor strikes. In this work we conduct a large scale Monte Carlo parameter estimation simulation for galactic binaries assuming data streams containing gaps. As the expected duration and frequency of the gaps are currently unknown, we have decided to focus on gaps of approximately one hour, occurring either once per day or once per week. We also study the case where, as well as the expected periodic gaps, we have a data drop-out of one continuous week. Our results show that for for galactic bina...

  13. Contact melting and the structure of binary eutectic near the eutectic point

    OpenAIRE

    Bystrenko, Oleksiy; Kartuzov, Valeriy

    2014-01-01

    Computer simulations of contact melting and associated interfacial phenomena in binary eutectic systems were performed on the basis of the standard phase-field model with miscibility gap in solid state. It is shown that the model predicts the existence of equilibrium three-phase (solid-liquid-solid) states above the eutectic temperature, which suggest the explanation of the phenomenon of phase separation in liquid eutectic observed in experiments. The results of simulations provide the interp...

  14. Rheology of miscible polymer blends with hydrogen bonding

    Science.gov (United States)

    Yang, Zhiyi

    -based miscible blends with hydrogen bonding. Specifically, functional norbornenes with carboxylic (-COOH) group or hydroxyl (-OH) group were first synthesized and then they were polymerized, via ring-opening metathesis polymerization followed by hydrogenation, to obtain HFPNBs, HPNBCOOH and HPNBOH. Subsequently, the miscibility of binary blends consisting of (1) HPBNCOOH and polycarbonate (PC), (2) HPBNCOOH and poly(2-vinylpyridine) (P2VP), and (3) HPBNOH and PC was investigated using DSC and FTIR spectroscopy. It has been found that both PC/HPBNCOOH and P2VP/HPBNCOOH blend systems exhibit a broad, single glass transition over the entire blend compositions as determined by DSC, indicating that the respective blend systems are miscible, and they form hydrogen bonds as determined by FTIR spectroscopy. On the other hand, PC/HPBNOH blends were found to exhibit two glass transition temperatures, indicating that the blends are not miscible. The dynamic oscillatory shear rheometry has shown that reduced log G' versus log aTo and log G" versus log aTo plots, and also log G' versus log G" plots of PC/HPBNCOOH and P2VP/HPBNCOOH blend systems are independent of temperature. We have concluded that an application of TTS to the miscible polymer blends with hydrogen bonding is warranted although the difference in component glass transition temperatures is as large as 91C for the PC/HPNBCOOH blend system.

  15. Miscibility behavior and single chain properties in polymer blends: a bond fluctuation model study

    OpenAIRE

    Mueller, Marcus

    1999-01-01

    Computer simulation studies on the miscibility behavior and single chain properties in binary polymer blends are reviewed. We consider blends of various architectures in order to identify important architectural parameters on a coarse grained level and study their qualitative consequences for the miscibility behavior. The phase diagram, the relation between the exchange chemical potential and the composition, and the intermolecular paircorrelation functions for symmetric blends of linear chai...

  16. Miscibility of polymer blends with engineering models

    DEFF Research Database (Denmark)

    Vassilis, Harismiadis; van Bergen, A. R. D.; Goncalves, Ana Saraiva;

    1996-01-01

    The miscibility behavior of polymer blends that do not exhibit strong specific interactions is examined. Phase equilibrium calculations are presented with the van der Waals equation of state and three group-contribution models (UNIFAC, Entropic-FV, and GC-Flory). Performance of these models is also...... compared. The van der Waals equation of state was recently shown to accurately correlate and predict vapor-liquid and liquid-liquid equilibria for binary polymer/solvent solutions. In this work, it is demonstrated that it correlates the upper critical solution behavior of polymer blends with excellent......, the upper critical solution temperature can be predicted with an average error of less than 45 degrees C. The van der Waals equation of state can correlate the lower critical solution behavior of polymer blends, using an interaction parameter that is a linear function of temperature. The UNIFAC and...

  17. Miscibility and structure-property relationships in some novel polyolefins

    Science.gov (United States)

    Kamdar, Akshay Rajprakash

    In the first chapter, miscibility of homogeneous propylene/ethylene (P/E) copolymers of relatively narrow molecular weight distribution was studied as a function of constituent comonomer content. Polymers with up to 31 mol% ethylene were blended in pairs in order to vary the comonomer content difference. Copolymers of molecular weight about 200 kg mol-1 were miscible if the difference in ethylene content was less than about 18 mol%, and immiscible if the ethylene content difference was greater than about 20 mol%. Blends with constituent composition difference in the range of 18-20 mol% exhibited partial miscibility in the melt. In the second chapter, the effect of chain microstructure on the miscibility and phase behavior of ethylene-octene (EO) copolymer blends was studied. Binary blends of two statistical copolymers (EO/EO blends) that differed in comonomer content were compared with blends of an EO with an olefinic blocky ethylene-octene copolymer, OBC (EO/OBC blends). Two EOs of molecular weight about 100 kg/mol were miscible if the difference in octene content was less than about 10 mol% and immiscible if the octene content difference was greater than about 13 mol%. The blocky nature of the OBCs reduced the miscibility and broadened the partial miscibility window of EO/OBC blends compared to EO/EO blends. The EO/OBC blends were miscible if the octene content difference was less than 7 mol% and immiscible above 13 mol% octene content difference. In the third chapter, the adhesion of some ethylene-octene copolymers to polypropylene (PP) and high density polyethylene (HDPE) was studied in order to evaluate their suitability as compatibilizers for PP/HDPE blends. A one-dimensional model of the compatibilized blend was fabricated by layer-multiplying coextrusion. The microlayered tapes consisted of many alternating layers of PP and HDPE with a thin tie-layer inserted at each interface. The thickness of the tie-layer varied from 0.1 to 14 mum, which included

  18. The Effect of Data Gaps on LISA Galactic Binary Parameter Estimation

    OpenAIRE

    Carré, Jérôme; Porter, Edward K.

    2010-01-01

    In the last few years there has been an enormous effort in parameter estimation studies for different sources with the space based gravitational wave detector, LISA. While these studies have investigated sources of differing complexity, the one thing they all have in common is they assume continuous data streams. In reality, the LISA data stream will contain gaps from such possible events such as repointing of the satellite antennae, to discharging static charge build up on the satellites, to...

  19. Ordering in binary transition metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Rusakov, G. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Son, L., E-mail: ldson@yandex.ru [Ural State Pedagogical University, 26 Cosmonavtov Ave, 620017 Ekaterinburg (Russian Federation); Efimova, E. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Dubinin, N. [Institute for Metallurgy UB RAS, 101 Amundsen St., 620016 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation)

    2012-03-20

    We present the phenomenological thermodynamic modeling of binary alloys which demonstrate solubility of the components at high temperatures, and form intermediate phase near equiatomic composition at lower ones (the so-called sigma-phase). Besides, the regular solution miscibility gap takes place also. The nonequilibrium thermodynamic potential is written out as a sum of the free energy of regular solution and polynomial term of scalar order parameter {phi}, which describes the {sigma}-phase ordering. There are four parameters in the model: the energy of regular solution mixing, the energy of {sigma}-phase formation at zero temperature, and the widths of temperature and concentration intervals of {sigma}-phase existence in the alloy with frozen-in random distribution of components. Up to now, both phase transitions which take place in a number of transition metals binary alloys (the {sigma}-phase formation and miscibility in the regular solution) have been treated separately. In present work, the standard technique of phase diagram calculation allows us to analyze all possible phase diagrams which may arise in the alloy.

  20. The GAPS programme with HARPS-N at TNG. X. Differential abundances in the XO-2 planet-hosting binary

    Science.gov (United States)

    Biazzo, K.; Gratton, R.; Desidera, S.; Lucatello, S.; Sozzetti, A.; Bonomo, A. S.; Damasso, M.; Gandolfi, D.; Affer, L.; Boccato, C.; Borsa, F.; Claudi, R.; Cosentino, R.; Covino, E.; Knapic, C.; Lanza, A. F.; Maldonado, J.; Marzari, F.; Micela, G.; Molaro, P.; Pagano, I.; Pedani, M.; Pillitteri, I.; Piotto, G.; Poretti, E.; Rainer, M.; Santos, N. C.; Scandariato, G.; Zanmar Sanchez, R.

    2015-11-01

    Binary stars hosting exoplanets are a unique laboratory where chemical tagging can be performed to measure the elemental abundances of both stellar components with high accuracy, with the aim to investigate the formation of planets and their subsequent evolution. Here, we present a high-precision differential abundance analysis of the XO-2 wide stellar binary based on high-resolution HARPS-N at TNG spectra. Both components are very similar K-dwarfs and host planets. Since they formed presumably within the same molecular cloud, we expect that they possess the same initial elemental abundances. We investigated whether planets can cause some chemical imprints in the stellar atmospheric abundances. We measure abundances of 25 elements for both stars with a range of condensation temperature TC = 40-1741 K, achieving typical precisions of ~0.07 dex. The northern component shows abundances in all elements higher by +0.067 ± 0.032 dex on average, with a mean difference of +0.078 dex for elements with TC > 800 K. The significance of the XO-2N abundance difference relative to XO-2S is at the 2σ level for almost all elements. We discuss that this result might be interpreted as the signature of the ingestion of material by XO-2N or depletion in XO-2S that is due to locking of heavy elements by the planetary companions. We estimate a mass of several tens of M⊕ in heavy elements. The difference in abundances between XO-2N and XO-2S shows a positive correlation with the condensation temperatures of the elements, with a slope of (4.7 ± 0.9) × 10-5 dex K-1, which could mean that both components have not formed terrestrial planets, but first experienced the accretion of rocky core interior to the subsequent giant planets. Based on observations made with the Italian Telescopio Nazionale Galileo (TNG), operated on the island of La Palma by the INAF - Fundación Galileo Galilei at the Roche de los Muchachos Observatory of the Instituto de Astrofísica de Canarias (IAC) in the

  1. The Zr–Sn binary system: New experimental results and thermodynamic assessment

    OpenAIRE

    Jerlerud Pérez, Rosa; Toffolon-Masclet, C.; Joubert, J.-M.; Sundman, Bo

    2008-01-01

    The Zr–Sn binary system has been reinvestigated by several experimental techniques: X-ray diffraction, electron probe micro-analysis, mass density and calorimetry measurements. The existence of a miscibility gap inside the homogeneity domain of the phase (Zr5Sn3–Zr5Sn4) has been confirmed. It has been also shown that Zr substitution on the Sn sublattice is responsible for the non-stoichiometry of the A15 phase (Zr4Sn). The temperature of the peritectoid reaction Zr+A15 $ Zr has been determin...

  2. Miscibility in a degenerate fermionic mixture induced by linear coupling

    International Nuclear Information System (INIS)

    We consider a one-dimensional mean-field-hydrodynamic model of a two-component degenerate Fermi gas in an external trap, each component representing a spin state of the same atom. We demonstrate that the interconversion between them (linear coupling), imposed by a resonant electromagnetic wave, transforms the immiscible binary gas into a miscible state, if the coupling constant, κ, exceeds a critical value, κcr. The effect is predicted in a variational approximation, and confirmed by numerical solutions. Unlike the recently studied model of a binary Bose-Einstein condensate with the linear coupling, the components in the immiscible phase of the binary fermion mixture never fill two separated domains with a wall between them, but rather form antilocked (π-phase-shifted) density waves. Another difference from the bosonic mixture is spontaneous breaking of symmetry between the two components in terms of the numbers of atoms in them, N1 and N2. The latter effect is characterized by the parameter ν≡(N1-N2)/(N1+N2) (only N1+N2 is a conserved quantity), the onset of miscibility at κ≥κcr meaning a transition to ν≡0. At κcr, ν features damped oscillations as a function of κ. We also briefly consider an asymmetric model, with a chemical-potential difference between the two components. The relation between the imbalance in the spin population, induced by the linear coupling, and the developing spatial structure resembles the known Larkin-Ovchinnikov-Fulde-Ferrell states in the Fermi mixture. Dynamical states, when κ is suddenly switched from zero to a value exceeding κcr, are considered too. In the latter case, the system features oscillatory relaxation to the mixed state

  3. An Improved CO2-Crude Oil Minimum Miscibility Pressure Correlation

    OpenAIRE

    Hao Zhang; Dali Hou; Kai Li

    2015-01-01

    Minimum miscibility pressure (MMP), which plays an important role in miscible flooding, is a key parameter in determining whether crude oil and gas are completely miscible. On the basis of 210 groups of CO2-crude oil system minimum miscibility pressure data, an improved CO2-crude oil system minimum miscibility pressure correlation was built by modified conjugate gradient method and global optimizing method. The new correlation is a uniform empirical correlation to calculate the MMP for both t...

  4. Surface Tension and Fingering of Miscible Interfaces

    Science.gov (United States)

    Abib, Mohammed; Liu, Jian-Bang; Ronney, Paul D.

    1999-01-01

    Experiments on miscible, buoyantly unstable reaction-diffusion fronts and non-reacting displacement fronts in Hele-Shaw cells show a fingering-type instability whose wavelengths (lambda*) are consistent with an interfacial tension (sigma) at the front caused by the change in chemical composition, even though the solutions are miscible in all proportions. In conjunction with the Saffman-Taylor model, the relation sigma = K/tau, where tau is the interface thickness and K approximately equal 4 +/- 2 x 10(exp -6) dyne, enables prediction of our measured values of lambda* as well as results from prior experiments on miscible interfaces. These results indicate that even for miscible fluids, surface tension is generally a more significant factor than diffusion in interfacial stability and flow characteristics.

  5. Miscibility behavior of two-component monolayers at the air-water interface: perfluorocarboxylic acids and DMPE.

    Science.gov (United States)

    Yokoyama, Hiroki; Nakahara, Hiromichi; Nakagawa, Takahiro; Shimono, Satoshi; Sueishi, Kunihiko; Shibata, Osamu

    2009-09-01

    Surface pressure (pi)-molecular area (A) and surface potential (DeltaV)-A isotherms have been measured for two-component monolayers of four different perfluorocarboxylic acids [FCn; perfluorododecanoic acid (FC12), perfluorotetradecanoic acid (FC14), perfluorohexadecanoic acid (FC16), and perfluorooctadecanoic acid (FC18)] and dimyristoylphosphatidylethanolamine (DMPE) on 0.15M NaCl (pH 2) at 298.2K. The present study is focused on the miscibility and the interfacial behavior for the binary DMPE/FCn monolayers upon compression. From the isotherms, the miscibility has been elucidated in terms of the additivity rule, the interaction parameter, and the interaction energy. The interaction parameter (or energy) is compared with that for the previous dipalmitoylphosphatidylcholine (DPPC)/FCn systems [Colloids Surf. B 41 (2005) 285-298] to understand the effect of phospholipids' polar headgroup on the binary miscibility. Furthermore, the phase behavior of the DMPE/FCn systems has been morphologically examined using fluorescence microscopy (FM) and atomic force microscopy (AFM). These images reveal the different interaction modes among the four systems; DMPE can be miscible with FC12 and FC14 and immiscible with FC16 and FC18 in the monolayer state. These systematic examinations indicate that the miscibility of perfluorocarboxylic acids and phospholipids depends on combination of hydrocarbon and fluorocarbon chain lengths and on phospholipids' polar headgroups within a monolayer. PMID:19481762

  6. Immiscibility in the Nickel Ferrite-Zinc Ferrite Spinel Binary

    Energy Technology Data Exchange (ETDEWEB)

    SE Ziemniak; AR Gaddipati; PC Sander; SB Rice

    2006-06-21

    Immiscibility in the trevorite (NiFe{sub 2}O{sub 4}) - franklinite (ZnFe{sub 2}O{sub 4}) spinel binary is investigated by reacting 1:1:2 molar ratio mixtures of NiO, ZnO and Fe{sub 2}O{sub 3} in a molten salt solvent at temperatures in the range 400-1000 C. Single phase stability is demonstrated down to about 730 C (the estimated consolute solution temperature, T{sub cs}). A miscibility gap/solvus exists below Tcs. The solvus becomes increasingly asymmetric at lower temperatures and extrapolates to n - values = 0.15, 0.8 at 300 C. A thermodynamic analysis, which accounts for changes in configurational and magnetic ordering entropies during cation mixing, predicts solvus phase compositions at room temperature in reasonable agreement with those determined by extrapolation of experimental results. The delay between disappearance of magnetic ordering above T{sub C} = 590 C (for NiFe{sub 2}O{sub 4}) and disappearance of a miscibility gap at T{sub cs} is explained by the persistence of long-range ordering correlations in a quasi-paramagnetic region above T{sub C}.

  7. Flow of a miscible in a Berea sandstone

    Energy Technology Data Exchange (ETDEWEB)

    Friedman, F.

    1976-01-01

    A mathematical model for the miscible displacement of a resident fluid by a surfactant solution in a Berea sandstone is derived from first principles, using the concept of volume averaging. The single phase model is scaled and solved by a state variable, finite difference scheme. From the results of the simulation, an experimental program is designed to determine the main model parameters. These include rock parameters (porosity, dead-space volume), fluid properties (binary diffusion coefficient) and flow properties (dispersion coefficient) obtained from displacement experiments. These data are important factors which are needed for the simulation of more complex systems such as the displacement of tertiary residual oil and formation water by aqueous surfactant solutions.

  8. Intrinsic nanoscale phase separation in miscible mixtures and supramolecular assemblies

    OpenAIRE

    Lei Zhang

    2011-01-01

    A model is used to describe the intrinsic nanoscale phase separation in miscible mixtures and supramolecular assemblies. Phase-separated nanostructures related to size-dependent surface tension, molecular structural factors and strong interphase interactions exist in miscible mixtures and supramolecular assemblies. The intrinsic nanoscale phase separation may exist universally in miscible mixtures.

  9. Investigation of segregation for AlxIn1-x liquid binary alloys

    International Nuclear Information System (INIS)

    Segregation of AlxIn1-x liquid binary alloys is systematically investigated from the energetic point of view using the electronic theory of metals. The free energy of mixing is calculated at different thermodynamic states characterized by temperatures for the full range of concentration by using the perturbation approach. The interionic interaction is described by a local pseudopotential. This study enables us to predict the correct miscibility gap as well as critical temperature (T=1160 K) and critical concentration (x=0.5) of segregation for the concerned alloys. These results agree well with available experimental data. Most importantly, results of our calculations have precisely identified for the first time that, the volume dependent term of the energy of mixing is mostly responsible for the total energy of mixing to be positive, which is one of the most significant indicators of segregation of liquid metals in binary alloys

  10. Dynamics of binary phase separation in liquid He-3-He-4 mixtures

    Science.gov (United States)

    Hoffer, J. K.; Sinha, D. N.

    1986-01-01

    Binary phase-separation dynamics in liquid mixtures of He-3 and He-4 has been investigated near the tricritical point with laser-light scattering techniques. Rapid decompression of the mixtures results in quenches into the miscibility gap so that both the metastable and unstable (spinodal) regions can be probed. Quenches into the unstable region allowed measurements of the normalized dynamic structure factor S(k,t) that confirm the dynamical scaling hypotheses for spinodal decomposition. Measurements made for concentrations well away from the tricritical value show different behavior and suggest the presence of a spinodal boundary. Forward scattering intensities for shallow quenches probe nucleation phenomena and permit quantitative measurements of anomalous super-cooling as a function of quench rate. Comparisons with data in organic binary mixtures are given.

  11. The GAPS Programme with HARPS-N at TNG. IX. Differential abundances in the XO-2 planet hosting binary

    CERN Document Server

    Biazzo, K; Desidera, S; Lucatello, S; Sozzetti, A; Bonomo, A S; Damasso, M; Gandolfi, D; Affer, L; Boccato, C; Borsa, F; Claudi, R; Cosentino, R; Covino, E; Knapic, C; Lanza, A F; Maldonado, J; Marzari, F; Micela, G; Molaro, P; Pagano, I; Pedani, M; Pillitteri, I; Piotto, G; Poretti, E; Rainer, M; Santos, N C; Scandariato, G; Sanchez, R Zanmar

    2015-01-01

    Binary stars hosting exoplanets are a unique laboratory where chemical tagging can be performed to measure with high accuracy the elemental abundances of both stellar components, with the aim to investigate the formation of planets and their subsequent evolution. Here, we present a high-precision differential abundance analysis of the XO-2 wide stellar binary based on high resolution HARPS-N@TNG spectra. Both components are very similar K-dwarfs and host planets. Since they formed presumably within the same molecular cloud, we expect they should possess the same initial elemental abundances. We investigate if the presence of planets can cause some chemical imprints in the stellar atmospheric abundances. We measure abundances of 25 elements for both stars with a range of condensation temperature $T_{\\rm C}=40-1741$ K, achieving typical precisions of $\\sim 0.07$ dex. The North component shows abundances in all elements higher by $+0.067 \\pm 0.032$ dex on average, with a mean difference of +0.078 dex for element...

  12. Miscibility of polymer blends with engineering models

    DEFF Research Database (Denmark)

    Vassilis, Harismiadis; van Bergen, A. R. D.; Goncalves, Ana Saraiva; Kontogeorgis, Georgios; Fredenslund, Aage; Dimitrios, Tassios

    1996-01-01

    The miscibility behavior of polymer blends that do not exhibit strong specific interactions is examined. Phase equilibrium calculations are presented with the van der Waals equation of state and three group-contribution models (UNIFAC, Entropic-FV, and GC-Flory). Performance of these models is also...

  13. Discrete gap solitons in binary positive-negative index nonlinear waveguide arrays with strong second-order couplings.

    Science.gov (United States)

    Dovgiy, Alexander A; Besedin, Ilya S

    2015-09-01

    We report on the existence and properties of discrete gap solitons in zigzag arrays of alternating waveguides with positive and negative refractive indices. The zigzag quasi-one-dimensional configuration of the waveguide array introduces strong next-to-nearest neighbor interaction in addition to nearest neighbor coupling. Effective diffraction can be controlled both in size and in sign by the value of the next-to-nearest neighbor coupling coefficient and can even be canceled completely. In the regime where instabilities occur, we found different families of discrete solitons bifurcating from the gap edges of the linear spectrum. We show that both staggered and unstaggered discrete solitons can become highly localized states near the zero diffraction points even for low powers. Stability analysis has shown that the soliton solutions are stable over a wide range of parameters and can exist in focusing, defocusing, and even in an alternating focusing-defocusing array. PMID:26465537

  14. A new class of large band gap quantum spin hall insulators: 2D fluorinated group-IV binary compounds

    Science.gov (United States)

    Padilha, J. E.; Pontes, R. B.; Schmidt, T. M.; Miwa, R. H.; Fazzio, A.

    2016-01-01

    We predict a new class of large band gap quantum spin Hall insulators, the fluorinated PbX (X = C, Si, Ge and Sn) compounds, that are mechanically stable two-dimensional materials. Based on first principles calculations we find that, while the PbX systems are not topological insulators, all fluorinated PbX (PbXF2) compounds are 2D topological insulators. The quantum spin Hall insulating phase was confirmed by the explicitly calculation of the Z2 invariant. In addition we performed a thorough investigation of the role played by the (i) fluorine saturation, (ii) crystal field, and (iii) spin-orbital coupling in PbXF2. By considering nanoribbon structures, we verify the appearance of a pair of topologically protected Dirac-like edge states connecting the conduction and valence bands. The insulating phase which is a result of the spin orbit interaction, reveals that this new class of two dimensional materials present exceptional nontrivial band gaps, reaching values up to 0.99 eV at the Γ point, and an indirect band gap of 0.77 eV. The topological phase is arisen without any external field, making this system promising for nanoscale applications, using topological properties. PMID:27212604

  15. Physical Aging of Miscible Polymer Blends

    OpenAIRE

    Robertson, Christopher

    1999-01-01

    Physical aging measurements were performed on various polymeric glasses with the overriding goal of developing a better molecular picture of the nonequilibrium glassy state. To this end, aging-induced changes in mechanical properties and in the thermodynamic state (volume and enthalpy) were assessed for two different miscible polymer blends as a function of both composition and aging temperature. This investigation considered the physical aging behavior of blends containing atactic polystyr...

  16. Dynamics of miscible displacements in round tubes

    Energy Technology Data Exchange (ETDEWEB)

    Meiburg, E.; Maxworthy, T.; Chen, C.Y. [Univ. of Southern California, Los Angeles, CA (United States); Petitjeans, P. [Ecole Superieure de Physique et de Chimie Industrielles, Paris (France)

    1995-12-31

    A combined experimental and numerical investigation of miscible two-phase flow in a capillary tube is reported. The fraction of fluid left behind on the wall is obtained as a function of the Peclet, Atwood, and Froude numbers. Scaling arguments are presented for two distinct flow regimes, dominated by diffusion and convection, respectively. In the latter one, an effective surface tension value can be estimated.

  17. Liquid-liquid miscibility and volumetric properties of aqueous solutions of ionic liquids as a function of temperature

    OpenAIRE

    Wang, Silu; Johan JACQUEMIN; Husson, Pascale; Hardacre, Christpher; Costa Gomes, Margarita F.

    2009-01-01

    The volumetric properties of seven {water + ionic liquid} binary mixtures have been studied as a function of temperature from (293 to 343) K. The phase behaviour of the systems was first investigated using a nephelometric method and excess molar volumes were calculated from densities measured using an Anton Paar densimeter and fitted using a Redlich-Kister type equation. Two ionic liquids fully miscible with water (1-butyl-3-methylimidazolium tetrafluoroborate ([CCIm][BF]) and 1-ethyl-3-methy...

  18. On the Class II Methanol Maser Periodic Variability due to the Rotating Spiral Shocks in the Gaps of Disks Around Young Binary Stars

    CERN Document Server

    Parfenov, S Yu

    2014-01-01

    We argue that the periodic variability of Class II methanol masers can be explained by variations of the dust temperature in the accretion disk around proto-binary star with at least one massive component. The dust temperature variations are caused by rotation of hot and dense material of the spiral shock wave in the disk central gap. The aim of this work is to show how different can be the Class II methanol maser brightness in the disk during the Moment of Maximum Illumination by the Spiral Shock material (hereafter MMISS) and the Moment when the disk is Illuminated by the Stars Only (MISO). We used the code CLOUDY (v13.02) to estimate physical conditions in the flat disk in the MISO and the MMISS. Model physical parameters of the disk were then used to estimate the brightness of 6.7, 9.9, 12.1 and 107 GHz masers at different impact parameters $p$ using LVG approximation. It was shown that the strong masers experience considerable brightness increase during the MMISS with respect to MISO. There can happen bo...

  19. XMM-NEWTON MONITORING OF THE CLOSE PRE-MAIN-SEQUENCE BINARY AK SCO. EVIDENCE OF TIDE-DRIVEN FILLING OF THE INNER GAP IN THE CIRCUMBINARY DISK

    International Nuclear Information System (INIS)

    AK Sco stands out among pre-main-sequence binaries because of its prominent ultraviolet excess, the high eccentricity of its orbit, and the strong tides driven by it. AK Sco consists of two F5-type stars that get as close as 11 R* at periastron passage. The presence of a dense (ne ∼ 1011 cm–3) extended envelope has been unveiled recently. In this article, we report the results from an XMM-Newton-based monitoring of the system. We show that at periastron, X-ray and UV fluxes are enhanced by a factor of ∼3 with respect to the apastron values. The X-ray radiation is produced in an optically thin plasma with T ∼ 6.4 × 106 K and it is found that the NH column density rises from 0.35 × 1021 cm–2 at periastron to 1.11 × 1021 cm–2 at apastron, in good agreement with previous polarimetric observations. The UV emission detected in the Optical Monitor band seems to be caused by the reprocessing of the high-energy magnetospheric radiation on the circumstellar material. Further evidence of the strong magnetospheric disturbances is provided by the detection of line broadening of 278.7 km s–1 in the N V line with Hubble Space Telescope/Space Telescope Imaging Spectrograph. Numerical simulations of the mass flow from the circumbinary disk to the components have been carried out. They provide a consistent scenario with which to interpret AK Sco observations. We show that the eccentric orbit acts like a gravitational piston. At apastron, matter is dragged efficiently from the inner disk border, filling the inner gap and producing accretion streams that end as ring-like structures around each component of the system. At periastron, the ring-like structures come into contact, leading to angular momentum loss, and thus producing an accretion outburst.

  20. On the phase-field modelling of a miscible liquid/liquid boundary.

    Science.gov (United States)

    Xie, Ruilin; Vorobev, Anatoliy

    2016-02-15

    Mixing of miscible liquids is essential for numerous processes in industry and nature. Mixing, i.e. interpenetration of molecules through the liquid/liquid boundary, occurs via interfacial diffusion. Mixing can also involve externally or internally driven hydrodynamic flows, and can lead to deformation or disintegration of the liquid/liquid boundary. At the moment, the mixing dynamics remains poorly understood. The classical Fick's law, generally accepted for description of the diffusion process, does not explain the experimental observations, in particular, the recent experiments with dissolution of a liquid solute by a liquid solvent within a horizontal capillary (Stevar and Vorobev, 2012). We present the results of the numerical study aimed at development of an advanced model for the dissolution dynamics of liquid/liquid binary mixtures. The model is based on the phase-field (Cahn-Hilliard) approach that is used as a physics-based model for the thermo- and hydrodynamic evolution of binary mixtures. Within this approach, the diffusion flux is defined through the gradient of chemical potential, and, in particular, includes the effect of barodiffusion. The dynamic interfacial stresses at the miscible interface are also taken into account. The simulations showed that such an approach can accurately reproduce the shape of the solute/solvent boundary, and some aspects of the diffusion dynamics. Nevertheless, all experimentally-observed features of the diffusion motion of the solute/solvent boundary, were not reproduced. PMID:26609922

  1. Existence domains for invariant reactions in binary regular solution phase diagrams exhibiting two phases

    Indian Academy of Sciences (India)

    B Nageswara Sarma; S Srinivas Prasad; S Vijayvergiya; V Bharath Kumar; S Lele

    2003-06-01

    The thermodynamic origin of various types of phase diagrams in simple binary systems exhibiting two phases (e.g. a liquid and a solid phase) has been examined using the regular solution model. The necessary conditions for the occurrence of each of these types are identified in terms of the appropriate intersections of the miscibility gap boundaries (in solid/liquid phases) and the liquidus/solidus/iso- curves. Thus, the regions of occurrence of the different types of possible phase diagrams in the space of the regular solution interchange energy parameters (, ) are clearly delineated. This analysis makes it easier to make intelligent initial selections of model (energy) parameters for their optimization in the calculation of phase diagrams using thermodynamic models such as CALPHAD/CVM.

  2. XMM-NEWTON MONITORING OF THE CLOSE PRE-MAIN-SEQUENCE BINARY AK SCO. EVIDENCE OF TIDE-DRIVEN FILLING OF THE INNER GAP IN THE CIRCUMBINARY DISK

    Energy Technology Data Exchange (ETDEWEB)

    Gomez de Castro, Ana Ines [S. D. Astronomia y Geodesia and Instituto de Matematica Interdisciplinar, Fac. de CC Matematicas, Universidad Complutense, E-28040 Madrid (Spain); Lopez-Santiago, Javier [Departamento de Astrofisica, Fac de CC Fisicas, Universidad Complutense, E-28040 Madrid (Spain); Talavera, Antonio [European Space Astronomy Center, Villanueva de la Canada, E-28691, Madrid (Spain); Sytov, A. Yu.; Bisikalo, D. [Institute of Astronomy of the Russian Academy of Sciences, Pyatnitskaya St. 48, 109017 Moscow (Russian Federation)

    2013-03-20

    AK Sco stands out among pre-main-sequence binaries because of its prominent ultraviolet excess, the high eccentricity of its orbit, and the strong tides driven by it. AK Sco consists of two F5-type stars that get as close as 11 R{sub *} at periastron passage. The presence of a dense (n{sub e} {approx} 10{sup 11} cm{sup -3}) extended envelope has been unveiled recently. In this article, we report the results from an XMM-Newton-based monitoring of the system. We show that at periastron, X-ray and UV fluxes are enhanced by a factor of {approx}3 with respect to the apastron values. The X-ray radiation is produced in an optically thin plasma with T {approx} 6.4 Multiplication-Sign 10{sup 6} K and it is found that the N{sub H} column density rises from 0.35 Multiplication-Sign 10{sup 21} cm{sup -2} at periastron to 1.11 Multiplication-Sign 10{sup 21} cm{sup -2} at apastron, in good agreement with previous polarimetric observations. The UV emission detected in the Optical Monitor band seems to be caused by the reprocessing of the high-energy magnetospheric radiation on the circumstellar material. Further evidence of the strong magnetospheric disturbances is provided by the detection of line broadening of 278.7 km s{sup -1} in the N V line with Hubble Space Telescope/Space Telescope Imaging Spectrograph. Numerical simulations of the mass flow from the circumbinary disk to the components have been carried out. They provide a consistent scenario with which to interpret AK Sco observations. We show that the eccentric orbit acts like a gravitational piston. At apastron, matter is dragged efficiently from the inner disk border, filling the inner gap and producing accretion streams that end as ring-like structures around each component of the system. At periastron, the ring-like structures come into contact, leading to angular momentum loss, and thus producing an accretion outburst.

  3. Miscibility Phase Diagram of Ring Polymer Blends: A Topological Effect

    OpenAIRE

    Sakaue, Takahiro; Nakajima, Chihiro H.

    2016-01-01

    The miscibility of polymer blends, a classical problem in polymer science, may be altered, if one or both of the component do not have chain ends. Based on the idea of {\\it topological volume}, we propose a mean-field theory to clarify how the topological constraints in ring polymers affect the phase behavior of the blends. While the large enhancement of the miscibility is expected for ring-linear polymer blends, the opposite trend toward demixing, albeit comparatively weak, is predicted for ...

  4. Evidence for broken ergodicity due to chemical alloying from the dissociation kinetics of binary clusters

    OpenAIRE

    Yurtsever, Ersin; Calvo, Florent

    2014-01-01

    The interplay between thermal relaxation and statistical dissociation in binary Morse clusters (AB)N has been investigated using numerical simulations and simple statistical approaches, for a variety of interaction parameters covering miscible and non-miscible regimes. While all clusters exhibit a core/shell phase separation pattern in their most stable, T = 0 structure, different melting mechanisms are identified depending on the ranges and their mismatch, including two-step melting of the s...

  5. Experimental observation of magnetically induced phase separation and thermodynamic assessment in the Co–V binary system

    International Nuclear Information System (INIS)

    The phase equilibria of Co–V binary system were experimentally investigated, and the magnetically induced phase separation in the fcc phase was observed in a Co/V diffusion couple. Based on previous research and present work, a thermodynamic reassessment in the Co–V binary system was carried out by means of the CALPHAD method. The calculated results are consistent with the experimental data. The metastable miscibility gap of the hcp phase in the Co–V binary system was thermodynamically calculated. According to the calculation, the Co–V thin films with three concentrations were designed and deposited by magnetron sputtering. The transmission electron microscope (TEM) results prove that the metastable phase separation in the hcp phase exists in the Co–V system. The determined magnetic properties of the thin films reveal that the values of coercivity and remanence ratio are function of V content. - Highlights: • The magnetically induced phase separation of (αfCo) + (αpCo) was determined. • A thermodynamic reassessment of the Co–V binary system has been carried out. • The phase separation in the (εfCo) was observed in the Co85V15 thin film. • The coercivity and remanence ratio of the thin films are function of V content

  6. Experimental observation of magnetically induced phase separation and thermodynamic assessment in the Co–V binary system

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Cuiping [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Research Center of Materials Design and Applications, Xiamen University, Xiamen 361005 (China); Zhao, Cancan [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Lu, Yong [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Research Center of Materials Design and Applications, Xiamen University, Xiamen 361005 (China); Li, Tian; Peng, Dongliang [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Shi, Ji [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, Tokyo 152–8552 (Japan); Liu, Xingjun, E-mail: lxj@xmu.edu.cn [Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005 (China); Research Center of Materials Design and Applications, Xiamen University, Xiamen 361005 (China)

    2015-07-15

    The phase equilibria of Co–V binary system were experimentally investigated, and the magnetically induced phase separation in the fcc phase was observed in a Co/V diffusion couple. Based on previous research and present work, a thermodynamic reassessment in the Co–V binary system was carried out by means of the CALPHAD method. The calculated results are consistent with the experimental data. The metastable miscibility gap of the hcp phase in the Co–V binary system was thermodynamically calculated. According to the calculation, the Co–V thin films with three concentrations were designed and deposited by magnetron sputtering. The transmission electron microscope (TEM) results prove that the metastable phase separation in the hcp phase exists in the Co–V system. The determined magnetic properties of the thin films reveal that the values of coercivity and remanence ratio are function of V content. - Highlights: • The magnetically induced phase separation of (α{sub f}Co) + (α{sub p}Co) was determined. • A thermodynamic reassessment of the Co–V binary system has been carried out. • The phase separation in the (ε{sub f}Co) was observed in the Co{sub 85}V{sub 15} thin film. • The coercivity and remanence ratio of the thin films are function of V content.

  7. Dynamic Heterogeneity in Interacting Miscible Polymer Blends

    Science.gov (United States)

    Gaikwad, Ashish; Lodge, Timothy

    2008-03-01

    Dynamic heterogeneity leading to time-temperature superposition (tTS) failure has been widely reported in non-interacting/weakly interacting miscible polymer blends. However, coupling of the component dynamic response in blends, even with a huge dynamic asymmetry in the pure components, is possible with H-bonding interactions. This study is focused on finding the minimum level of interaction necessary for thermo-rheological simplicity in blends. Blends of styrene-co-vinylphenol (PSVPh) and poly(vinyl methyl ether) (PVME) were chosen. Incorporation of styrene provides an effective way to modulate H-bonding interactions in the system. Linear viscoelastic data indicate that tTS fails for PS/PVME blends, whereas data obtained for different PVPh/PVME blends showed that tTS was obeyed a over wide temperature range. For PSVPh/PVME blends with low PSVPh content, tTS was successful. This suggests that the presence of alternating styrene and vinyl phenol units was insufficient for dynamic response decoupling. Further studies are in progress, with varying vinyl phenol content in PSVPh, to explore the influence of H-bonding on dynamic heterogeneity and blend dynamics.

  8. An Improved CO2-Crude Oil Minimum Miscibility Pressure Correlation

    Directory of Open Access Journals (Sweden)

    Hao Zhang

    2015-01-01

    Full Text Available Minimum miscibility pressure (MMP, which plays an important role in miscible flooding, is a key parameter in determining whether crude oil and gas are completely miscible. On the basis of 210 groups of CO2-crude oil system minimum miscibility pressure data, an improved CO2-crude oil system minimum miscibility pressure correlation was built by modified conjugate gradient method and global optimizing method. The new correlation is a uniform empirical correlation to calculate the MMP for both thin oil and heavy oil and is expressed as a function of reservoir temperature, C7+ molecular weight of crude oil, and mole fractions of volatile components (CH4 and N2 and intermediate components (CO2, H2S, and C2~C6 of crude oil. Compared to the eleven most popular and relatively high-accuracy CO2-oil system MMP correlations in the previous literature by other nine groups of CO2-oil MMP experimental data, which have not been used to develop the new correlation, it is found that the new empirical correlation provides the best reproduction of the nine groups of CO2-oil MMP experimental data with a percentage average absolute relative error (%AARE of 8% and a percentage maximum absolute relative error (%MARE of 21%, respectively.

  9. Application of miscible displacement for Field MTX low permeability formations

    International Nuclear Information System (INIS)

    Miscible displacement is a very effective method of recovery efficiency improvement. It is widely used in the world, but this technology is not widely used in Russia. For this reason, it is necessary to study global experience and physical aspects of this EOR method. The most important factors and limitations of miscible displacement application from the geological point of view (heterogeneity) and from the physical point of view (properties of injected fluids and reservoir fluids) should be determined. The results of this analysis should be tested on the low permeability reservoir of field MTX with analytical, proxy calculation and simulation methods

  10. Evaluating miscible flood projects for acquisition or viability

    International Nuclear Information System (INIS)

    Very little information exists regarding evaluating enhanced oil recovery (EOR) projects, in particular miscible floods. Due to the size and scope of most tertiary recovery projects, standard evaluation rules and techniques are too general and vague to adequately model these schemes. A procedure for identifying the risks associated with miscible EOR projects is presented. It is essential to set up a cash flow model that accurately represents the future performance of a miscible flood. Included in the model are the timing of crucial events such as expected solvent breakthrough and the injection of trace gas. The cash flow analysis allows a quick audit procedure and converts production into a monetary or economic evaluation criteria that can easily be compared to other investment alternatives. When evaluating a miscible flood project, forecasting production, solvent and chase gas recovery costs can become quite complex. An organized procedure for an evaluation will ensure that a comprehensive and thorough examination of all the data is completed, and will increase confidence levels associated with decision making. 32 refs., 4 figs., 4 tabs

  11. Miscibility evolution of polycarbonate/polystyrene blends during compounding

    DEFF Research Database (Denmark)

    Chuai, Chengzhi; Almdal, Kristoffer; Johannsen, Ib;

    2002-01-01

    The miscibility evolution of polycarbonate/polystyrene (PC/PS) blends during the compounding process in three blending methods of industrial relevance, namely melt blending, remelt blending in a twin-screw extruder and third melt blending in an injection molding machine, was investigated by...

  12. Effective Algorithm for Calculation of Minimum Miscibility Pressure

    DEFF Research Database (Denmark)

    Jessen, Kristian; Michelsen, Michael Locht; Stenby, Erling Halfdan

    1998-01-01

    This paper describes a new algorithm developed for calculation of the minimum miscibility pressure (MMP) for the displacement of oil by a multicomponent injection gas. The algorithm is based on the key tie line identification approach initially studied by Wang and Orr . A new global formulation i...

  13. Effective Algorithm for Calculation of Minimum Miscibility Pressure

    DEFF Research Database (Denmark)

    Jessen, Kristian; Michelsen, Michael Locht; Stenby, Erling Halfdan

    This paper describes a new algorithm developed for calculation of the minimum miscibility pressure (MMP) for the displacement of oil by a multicomponent injection gas. The algorithm is based on the key tie line identification approach initially studied by Wang and Orr . A new global formulation i...

  14. Uniform temporal convergence of numerical schemes for incompressible miscible displacement

    OpenAIRE

    Talbot, Kyle S.

    2015-01-01

    The Hybrid Mimetic Mixed (HMM) family of discretisations includes the Hybrid Finite Volume method, the Mimetic Finite Difference method and the Mixed Finite Volume method. This note demonstrates that HMM discretisations of the equations describing the single-phase, miscible displacement through a porous medium of one incompressible fluid by another converge uniformly in time for the concentration variable.

  15. New ordered phase in the quasi-binary UAl3-USi3 system.

    Science.gov (United States)

    Rafailov, Gennady; Dahan, Isaac; Meshi, Louisa

    2014-06-01

    The industrial importance of the U-Al-Si system stems from the fact that during processing the Al-based alloy (containing Si as impurity), used for the cladding of U (fuel in nuclear reactors), undergoes heat treatment which stimulates diffusion between the fuel and the cladding. One of the possible ways to represent the ternary U-Al-Si phase diagram is the construction of an UAl3-USi3 quasi-binary phase diagram. On the one hand, since the UAl3 and USi3 phases are isostructural, an isomorphous phase diagram is expected; on the other hand, some researchers observed a miscibility gap at lower temperatures. During our study of the UAl3-USi3 quasi-binary phase diagram, a new stable U(Alx,Si1 - x)3 phase was identified. The structure of this phase was determined, using a combination of electron crystallography and powder X-ray diffraction methods, as tetragonal [I4/mmm (No.139) space group], with lattice parameters a = b = 8.347 (1), c = 16.808 (96) Å. Its unit cell has 64 atoms and it can be described as an ordered variant of the U(Al,Si)3 solid solution. A Bärnighausen tree was constructed using the original U(Al,Si)3 structure as an aristotype. PMID:24892604

  16. New ordered phase in the quasi-binary UAI3-USi3 system

    International Nuclear Information System (INIS)

    Industrial importance of U-Al-Si system stems from the fact that during processing – Albased alloy (containing Si as impurity), used for cladding of U (fuel in nuclear reactors), undergo heat treatment which stimulates the diffusion among the fuel and the cladding. One of the possible ways to represent ternary U-Al-Si phase diagram is construction of UAl3-USi3 quasi-binary phase diagram. On the one hand, since both UAl3 and USi3 phases are isostructural - an isomorphous phase diagram is expected, on the other hand - some researchers observed miscibility gap at lower temperatures. During our study of the UAl3USi3 quasi binary phase diagram, new stable U(Alx,Si(1-x))3 phase was identified. The structure of this phase was determined using a combination of electron crystallography and powder X-ray diffraction methods as tetragonal (I4/mmm (No.121) space group), with lattice parameters of a=b= 0.8347(1) nm, c= 1.6808(96) nm. Its unit cell has 64 atoms and it can be described as an ordered variant of the U(Al,Si)3 solid solution. The ordering can be explained and atom positions re-calculated by means of Bärnighausen tree which was constructed using the original U(Al,Si)3 structure as an aristotype

  17. Miscible transfer of solute in different types of rough fractures: from random to multiscale fracture walls heights

    CERN Document Server

    Auradou, Harold; Chertcoff, Ricardo; D'Angelo, Maria Veronica; Hulin, Jean-Pierre; Ippolito, Irene

    2009-01-01

    Miscible tracer dispersion measurements in transparent model fractures with different types of wall roughness are reported. The nature (Fickian or not) of dispersion is determined by studying variations of the mixing front as a function of the traveled distance but also as a function of the lateral scale over which the tracer concentration is averaged. The dominant convective dispersion mechanisms (velocity profile in the gap, velocity variations in the fracture plane) are established by comparing measurements using Newtonian and shear thinning fluids. For small monodisperse rugosities, front spreading is diffusive with a dominant geometrical dispersion (dispersion coefficient $D \\propto Pe$) at low P\\'eclet numbers $Pe$; at higher $Pe$ values one has either $D \\propto Pe^2$ ({\\it i.e.} Taylor dispersion) for obstacles of height smaller than the gap or $D \\propto Pe^{1.35}$ for obstacles bridging the gap. For a self affine multiscale roughness like in actual rocks and a relative shear displacement $\\vec{\\delt...

  18. XMM-Newton monitoring of the close pre-main-sequence binary AK Sco. Evidence of tide driven filling of the inner gap in the circumbinary disk

    CERN Document Server

    de Castro, Ana I Gomez; Talavera, Antonio; Sytov, A Yu; Bisikalo, D

    2013-01-01

    AK~Sco stands out among pre-main sequence binaries because of its prominent ultraviolet excess, the high eccentricity of its orbit and the strong tides driven by it. AK Sco consists of two F5 type stars that get as close as 11R$_*$ at periastron passage. The presence of a dense ($n_e \\sim 10^{11}$~cm$^{-3}$) extended envelope has been unveiled recently. In this article, we report the results from a XMM-Newton based monitoring of the system. We show that at periastron, X-ray and UV fluxes are enhanced by a factor of $\\sim 3$ with respect to the apastron values. The X-ray radiation is produced in an optically thin plasma with T$\\sim 6.4\\times 10^{6}$ K and it is found that the N$_H$ column density rises from 0.35$\\times 10^{21}$~cm$^{-2}$ at periastron to 1.11$\\times 10^{21}$~cm$^{-2}$ at apastron, in good agreement with previous polarimetric observations. The UV emission detected in the Optical Monitor band seems to be caused by the reprocessing of the high energy magnetospheric radiation on the circumstellar ...

  19. Effects of vibrations on dynamics of miscible liquids

    Science.gov (United States)

    Gaponenko, Yu.; Shevtsova, V.

    2010-01-01

    We report on a numerical study of the mixing of two miscible fluids in gravitationally stable configuration. In the absence of external forces the diffusion process leads to the mixing of species. The aim of this study is to analyze the physical mechanism by which vibrations affect the mixing characteristic of two stratified miscible fluids. The translational periodic vibrations of a rigid cell filled with different mixtures of water-isopropanol are imposed. The vibrations with a constant frequency and amplitude are directed along the interface. In absence of gravity vibration-induced mass transport is incomparably faster than in diffusion regime. Our results highlight the strong interplay between gravity and vibrational impact, the relative weight of each effect is determined by ratio vibrational and classical Rayleigh numbers.

  20. TIME-TEMPERATURE-MISCIBILITY AND MORPHOLOGY OF POLYOLEFIN BLENDS

    Institute of Scientific and Technical Information of China (English)

    Robert A.Shanks; Jun Li; Fei Chen; Gandara Amarasinghe

    2000-01-01

    Miscibility and crystallization have been studied for polypropylene-polyethylene and polyethylene-polyethylene blends. In the case of the polypropylene blends the composition of interest is 20% polypropylene. At this composition the polypropylene has been found to be soluble in linear low density polyethylene but insoluble in high, low and very low density polyethylenes. The miscibility has been concluded from the crystallization kinetics and polarised optical microscopy with a hot stage. Polyethylene-polyethylene blends have been formed from polymers with similar average branching content but where they have different melting temperatures. Important consequences are to introduce long branches into a polyethylene that only has short branches, and to modify the morphology of a polyethylenes so that haze, gloss and strain hardening are improved. Polyethylene blends must be developed after careful consideration of the branch content and distribution within each of the constituents. It is not sufficient to simply blend polyethylenes, with the desired range of properties, without regard to the miscibility of the blend composition.

  1. Calibration Binaries

    Science.gov (United States)

    Drummond, J.

    2011-09-01

    Two Excel Spreadsheet files are offered to help calibrate telescope or camera image scale and orientation with binary stars for any time. One is a personally selected list of fixed position binaries and binaries with well-determined orbits, and the other contains all binaries with published orbits. Both are derived from the web site of the Washington Double Star Library. The spreadsheets give the position angle and separation of the binaries for any entered time by taking advantage of Excel's built in iteration function to solve Kepler's transcendental equation.

  2. Miscibility and Morphology of Poly(lactic ACID)/POLY(Β-HYDROXYBUTYRATE) Blends

    Science.gov (United States)

    Tri Phuong, Nguyen; Guinault, Alain; Sollogoub, Cyrille

    2011-01-01

    The miscibility and morphology of poly(lactic)acid (PLA)/polyβ-hydroxybutyrate (PHB) prepared by melt blending method were investigated by Fourier transform infrared (FTIR), Differential scanning calorimetry (DSC), melt rheology and scanning electron microscopy (SEM) observations. FTIR and DSC methods present some limits to examine the miscibility state of PLA/PHB blends. This drawback can be overcome with the Cole-Cole method by observing the η" = f(η') curves to confirm the miscibility of semicrystalline PLA/ semicrystalline PHB blends. MEB micrographs of fractured surface of blends were also used to investigate the miscibility of these blends.

  3. Towards construction of quasi-binary UAI3-USi3 phase diagram

    International Nuclear Information System (INIS)

    Ternary U-Al-Si system has been extensively investigated due to the high potential of Uranium alloyed with Silicon as low-enriched fuel. Another interest in the U-Al-Si ternary system originates from the use of Aluminum alloy, where Silicon is a major alloying element, as U-fuel cladding. In this system, UAl3 and USi3 phases are of special importance. Since UAl3 and USi3 are isostructural and follow the Hume-Rothery rules closely, it would be expected that their quasi-binary phase diagram will be isomorphous. However, previous studies have shown that this system does not display complete liquid and solid solubility. Moreover, conflicting results were reported regarding the phases found . In current work, several compositions were cast and then heat-treated in order to reach equilibrium for subsequent characterization of Si-rich part of the USi3-UAl3 quasi-binary phase diagram. The as-cast and heat-treated alloys were characterized by scanning and transmission electron microscopy and X-ray diffraction (XRD) methods. Quantitative results were obtained from Rietveld analysis performed on XRD data. The results show that the ordered U(Si,Al)3 phase, identified in an earlier study of the Al-rich region is present also in the Si-rich region (studied in present research). Furthermore, ordered phase exhibited substantial stability over quite large range of compositions and temperature. Our results unambiguously point out that this quasi-binary system contains an order-disorder transformation and not a miscibility gap at low temperatures in the studied range of compositions

  4. Phase behavior of miscible block copolymer blends and baraplastic property

    International Nuclear Information System (INIS)

    The phase behavior of the multi-component polymer systems such as blends and block copolymers (BCPs) has been studied extensively, as it determines the chemical and physical properties of the polymeric materials in practical applications. Above all, polymer baroplasticity is a desirable property for the recycling and regenerating industries, since it allows the polymers to flow at relatively mild pressure. Particularly, the compressibility issue on the enhanced miscibility with pressure has been an attractive topic, because an ordered state of the baroplastic BCPs becomes a phase-mixed state (or disordered phase) between the two dissimilar blocks upon pressurizing. This is in contrast to the incompressibility that was dictated by the enthalpic effect arising from the increased unfavorable contacts between the two blocks by increasing pressure. The phase behaviors of BCP blends composed of the weakly interacting (with no specific interaction) polystyrene-b-poly(n-butyl methacrylate) (PS-b-PnBMA) and deuterated polystyreneb- poly-(n-hexyl methacrylate) (dPS-b-PnHMA) were investigated by Small-Angle Neutron Scattering(SANS) and Depolarized Light Scattering (DPLS) measurements. Interestingly, pressure dependence of various phase transitions for the miscible BCP blends was significantly changed, in which the blends consist of a PS-b-PnBMA and a deuterated dPS-b-PnHMA. To elucidate the origin and difference in baroplasticity of weakly interacting BCP blends, the pressure dependence of transition temperatures was evaluated using enthalpic and volumetric changes at phase transitions. We also demonstrate that the entropic compressibility for the miscible BCP blends is a baroplastic indicator, which was characterized by the negative volume change on mixing (ΔVmix) at transitions.

  5. A reduced model for fingering instability in miscible displacement

    International Nuclear Information System (INIS)

    The classical problem of fingering instability in miscible displacement is revisited. The finger-forming dynamics is considered as a multiple-scale process involving a thin inter-diffusion layer and large-scale background flow affected by the viscosity and/or density stratification. Upon an appropriate separation of 'fast' and 'slow' variables one ends up with a reduced model dealing directly with the evolving displacement front. As an illustration, the new model is applied for description of fingering in a source-supported flow and in a flow within a vertical channel

  6. Molecular order, miscibility, and rheology of molten polyethylenes

    Science.gov (United States)

    Hussein, Ibnelwaleed Ali

    New evidence of high-temperature transitions and molecular order in molten polyethylenes is presented, and its influence on the miscibility of polyethylenes is discussed. Thermal and rheological techniques were used to investigate commercial HDPE, LDPE and Ziegler-Natta and Metallocene LLDPEs. Adequate amounts of extra antioxidants were added to the polyethylenes during melt conditioning, following a separate investigation. Polystyrene was utilized to demonstrate the typical behavior of isotropic polymer melts. Temperature sweeps during torque measurements in a melt blender, and when using a rheometer and DSC, showed thermal transitions at about 208°C and 227°C. Torque in the blender over the temperature range 208°--227°C showed a flat profile or an increase in torque near 227°C, unique behavior associated with thermotropic liquid crystal polymers (LCP). Additional support for the liquid-state order that agree with theoretical predictions for a LCP is found. These include indications of an approach to a sign change in the first normal stress difference, N1( ġ ), at low values of the steady shear rate, ġ , and a kink in the non-Newtonian viscosity eta( ġ ). A rheological investigation found no evidence of the attainment of the isotropic state at high temperature and suggested the persistence of order above these transitions. However, highly branched metallocene LLDPE ( ˜ 40 CH3/1000 C) did not show transitions or any evidence of molecular order. It is suggested that polyethylenes possess different molecular conformation in the melt state ranging from the chain-folded HDPE to the amorphous highly-branched LLDPE. It is this molecular order and mismatch of the molecular conformations of different polyethylene structures that provide an explanation for the immiscibility of polyethylenes, as revealed by the dependence of their rheological properties on blend composition. The influence of molecular weight, comonomer type, and mixing temperature on the miscibility

  7. Interfacial pattern selection in miscible liquids under vibration.

    Science.gov (United States)

    Gaponenko, Y; Torregrosa, M M; Yasnou, V; Mialdun, A; Shevtsova, V

    2015-11-14

    We explore the peculiar behaviour of an interface between two miscible liquids of similar (but non-identical) viscosities and densities under horizontal vibration with a frequency less than 25 Hz. Significant differences in the structure of the formed patterns were found between microgravity and ground experiments. In a gravity field, a spatially periodic saw-tooth frozen structure is generated in the interface which dissipates at long times. By contrast, under the low gravity conditions of a parabolic flight, the long lived pattern consists of a series of vertical columns of alternating liquids. PMID:26365134

  8. Instability patterns in a miscible core annular flow

    Science.gov (United States)

    D'Olce, Marguerite; Martin, Jerome; Rakotomalala, Nicole; Salin, Dominique; Talon, Laurent

    2006-11-01

    Laboratoire FAST, batiment 502, campus universitaire, 91405 Orsay Cedex (France). Experiments are performed with two miscible fluids of equal density but different viscosities. The fluids are injected co-currently and concentrically into a cylindrical pipe. The so-obtained base state is an axisymmetric parallel flow, for which the ratio of the flow rates of the two fluids monitors the relative amount (and so the radius) of the fluids. Depending on this relative amount and on the total flow rate of the fluids, unstable axisymmetric patterns such as mushrooms and pearls are observed. We delineate the diagram of occurrence of the two patterns and characterize the instabilities.

  9. Calculation of minimum miscibility pressure using fast slimtube simulation

    DEFF Research Database (Denmark)

    Yan, Wei; Michelsen, Michael Locht; Stenby, Erling Halfdan

    2012-01-01

    Minimum misciblility pressure (MMP) is a critical parameter in designing a miscible gas injection process. It is expected that 100% displacement efficiency on the microscopic scale can be achieved provided the injection pressure is above MMP. Two approaches are usually employed for equation of st...... strategy is poroposed to reduce the number of slimtube simulations needed. In addition, it is also discussed how to parallelize slimtube simulations for modem computers with multiple CPU cores to further chop the computation time. Copyright 2012, Society of Petroleum Engineers....

  10. Concentration-dependent diffusion instability in reactive miscible fluids.

    Science.gov (United States)

    Bratsun, Dmitry; Kostarev, Konstantin; Mizev, Aleksey; Mosheva, Elena

    2015-07-01

    We report on chemoconvective pattern formation phenomena observed in a two-layer system of miscible fluids filling a vertical Hele-Shaw cell. We show both experimentally and theoretically that the concentration-dependent diffusion coupled with frontal acid-base neutralization can give rise to the formation of a local unstable zone low in density, resulting in a perfectly regular cell-type convective pattern. The described effect gives an example of yet another powerful mechanism which allows the reaction-diffusion processes to govern the flow of reacting fluids under gravity conditions. PMID:26274115

  11. Refractive Indices of Semiconductors from Energy gaps

    CERN Document Server

    Tripathy, S K

    2015-01-01

    An empirical relation based on energy gap and refractive index data has been proposed in the present study to calculate the refractive index of semiconductors. The proposed model is then applied to binary as well as ternary semiconductors for a wide range of energy gap. Using the relation, dielectric constants of some III-V group semiconductors are calculated. The calculated values for different group of binary semiconductors, alkali halides and ternary semiconductors fairly agree with other calculations and known values over a wide range of energy gap. The temperature variation of refractive index for some binary semiconductors have been calculated.

  12. Interacting binaries

    CERN Document Server

    Shore, S N; van den Heuvel, EPJ

    1994-01-01

    This volume contains lecture notes presented at the 22nd Advanced Course of the Swiss Society for Astrophysics and Astronomy. The contributors deal with symbiotic stars, cataclysmic variables, massive binaries and X-ray binaries, in an attempt to provide a better understanding of stellar evolution.

  13. On molecular and continuum boundary conditions for a miscible binary fluid

    OpenAIRE

    Denniston, Colin; Robbins, Mark O.

    2001-01-01

    We show that molecular dynamics simulations can furnish useful boundary conditions at a solid surface bounding a two-component fluid. In contrast to some previous reports, convective-diffusive flow is consistent with continuum equations down to atomic scales. However, concentration gradients can produce flow without viscous dissipation that is inconsistent with the commonly used Navier slip condition. Also, differential wetting of the two components coupled to a concentration gradient can dri...

  14. Studies of mixing properties of binary systems of 2-propanol with hexadecane and squalane at T = (298.15, 303.15, and 308.15) K

    International Nuclear Information System (INIS)

    The present paper reports the experimental data for density, ρ, viscosity, η, and speeds of sound, u for the binary mixtures of 2-propanol, (CH3)2CHOH with hexadecane, C16H34 over the miscibility region (0 1 30H62 over the miscibility region (0 1 mE, viscosity deviations, Δη, excess molar isentropic compressibility, KS,mE, and deviations in speed of sound, uD, from their ideal values uid. These excess parameters and deviations are used to interpret the molecular interactions in these binary mixtures

  15. Simulation of miscible laboratory displacements by the total dispersion method

    International Nuclear Information System (INIS)

    The total dispersion method was developed to simulate first-contact miscible displacements performed in the laboratory. Simulations applying this method add sufficient dispersivity to the numerical dispersion inherent in finite differencing methods so the sum approximates the actual physical dispersion. This paper describes the application of this technique to model three floods taken from the literature and three displacements performed in a CT scanner. A key variable for modelling miscible displacements is dispersion. Numerical dispersion for both 1-point and 2-point upstream weighing was characterized as a function of grid block size and through put for an IMPES simulator. After quantifying numerical dispersion, three floods reported in the literature were simulated to confirm the total dispersion method. Recovery curves for two displacements dominated by viscous fingering that one exhibiting gravity override were modelled with good agreement. The authors' next objective was to determine if concentration profiles as well as recovery curves could be matched in a well characterized rock. First, longitudinal convective dispersion was measured for Bentheimer sandstone by a series of tritiated water displacements

  16. Qualitative and quantitative methods to determine miscibility in amorphous drug-polymer systems.

    Science.gov (United States)

    Meng, Fan; Dave, Vivek; Chauhan, Harsh

    2015-09-18

    Amorphous drug-polymer systems or amorphous solid dispersions are commonly used in pharmaceutical industry to enhance the solubility of compounds with poor aqueous solubility. The degree of miscibility between drug and polymer is important both for solubility enhancement as well as for the formation of a physically stable amorphous system. Calculation of solubility parameters, Computational data mining, Tg measurements by DSC and Raman mapping are established traditional methods used to qualitatively detect the drug-polymer miscibility. Calculation of Flory-Huggins interaction parameter, computational analysis of X-Ray Diffraction (XRD) data, solid state Nuclear Magnetic Resonance (NMR) spectroscopy and Atomic Forced Microscopy (AFM) have been recently developed to quantitatively determine the miscibility in amorphous drug-polymer systems. This brief review introduces and compiles these qualitative and quantitative methods employed in the evaluation of drug-polymer miscibility. Combination of these techniques can provide deeper insights into the true miscibility of the drug-polymer systems. PMID:26006307

  17. Mutual diffusion of binary liquid mixtures containing methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride

    Science.gov (United States)

    Guevara-Carrion, Gabriela; Janzen, Tatjana; Muñoz-Muñoz, Y. Mauricio; Vrabec, Jadran

    2016-03-01

    Mutual diffusion coefficients of all 20 binary liquid mixtures that can be formed out of methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride without a miscibility gap are studied at ambient conditions of temperature and pressure in the entire composition range. The considered mixtures show a varying mixing behavior from almost ideal to strongly non-ideal. Predictive molecular dynamics simulations employing the Green-Kubo formalism are carried out. Radial distribution functions are analyzed to gain an understanding of the liquid structure influencing the diffusion processes. It is shown that cluster formation in mixtures containing one alcoholic component has a significant impact on the diffusion process. The estimation of the thermodynamic factor from experimental vapor-liquid equilibrium data is investigated, considering three excess Gibbs energy models, i.e., Wilson, NRTL, and UNIQUAC. It is found that the Wilson model yields the thermodynamic factor that best suits the simulation results for the prediction of the Fick diffusion coefficient. Four semi-empirical methods for the prediction of the self-diffusion coefficients and nine predictive equations for the Fick diffusion coefficient are assessed and it is found that methods based on local composition models are more reliable. Finally, the shear viscosity and thermal conductivity are predicted and in most cases favorably compared with experimental literature values.

  18. Fluid characterization for miscible EOR projects and CO2 sequestration

    DEFF Research Database (Denmark)

    Jessen, Kristian; Stenby, Erling Halfdan

    2007-01-01

    injected fluid(s). The mixtures that form when gas displaces oil in a porous medium will, in many cases, differ significantly from compositions created in swelling tests and other standard pressure/volume/temperature (PVT) experiments. Multicontact experiments (e.g., slimtube displacements) are often used...... this paper, we present a detailed analysis of the quality of two different characterization procedures over a broad range of reservoir fluids (13 samples) for which experimental swelling-test and slinitube-displacement data are available. We explore the impact of including swelling-test and slimtube...... experiments in the data reduction and demonstrate that for some gas/oil systems, swelling tests do not contribute to a more accurate prediction of multicontact miscibility. Finally, we report on the impact that use of EOS models based on different characterization procedures can have on recovery predictions...

  19. Miscible displacement fronts of shear thinning fluids inside rough fractures

    CERN Document Server

    Boschan, A; Ippolito, I; Chertcoff, R; Hulin, J P; Boschan, Alexandro; Auradou, Harold; Ippolito, Irene; Chertcoff, Ricardo; Hulin, Jean-Pierre

    2006-01-01

    The miscible displacement of a shear-thinning fluid by another of same rheological properties is studied experimentally in a transparent fracture by an optical technique imaging relative concentration distributions. The fracture walls have complementary self-affine geometries and are shifted laterally in the direction perpendicular to the mean flow velocity {\\bf U} : the flow field is strongly channelized and macro dispersion controls the front structure for P\\'{e}clet numbers above a few units. The global front width increases then linearly with time and reflects the velocity distribution between the different channels. In contrast, at the local scale, front spreading is similar to Taylor dispersion between plane parallel surfaces. Both dispersion mechanisms depend strongly on the fluid rheology which shifts from Newtonian to shear-thinning when the flow rate increases. In the latter domain, increasing the concentration enhances the global front width but reduces both Taylor dispersion (due to the flattening...

  20. Molecular Dynamics Simulation of Miscibility in Several Polymer Blends

    CERN Document Server

    Ahmadi, Amirhossein

    2009-01-01

    The miscibility in several polymer blend mixtures (polymethylmethacrylate/polystyrene, (1,4-cis) polyisoprene/polystyrene, and polymethylmethacrylate/polyoxyethylene) has been investigated using Molecular Dynamics simulations for atomistic representations of the polymer chains. The trajectories obtained from simulation boxes representing the mixtures have been analyzed in terms of the collective scattering structure function. The Flory-Huggins parameter is determined from fits of the simulation results for this function to the random phase approximation expression. The numerical values of this parameter and its variation with temperature obtained with this procedure show a general qualitative and quantitative agreement with existing experimental data for the different systems. These results together with those previously obtained for the polyvylmethylether/polystyrene blends with the same method are compared with data yielded by other computational simpler approaches.

  1. Miscible viscous fingering involving production of gel by chemical reactions

    Science.gov (United States)

    Nagatsu, Yuichiro; Hoshino, Kenichi

    2015-11-01

    We have experimentally investigated miscible viscous fingering with chemical reactions producing gel. Here, two systems were employed. In one system, sodium polyacrylate (SPA) solution and aluminum ion (Al3 +) solution were used as the more and less viscous liquids, respectively. In another system, SPA solution and ferric ion (Fe3 +) solution were used as the more and less viscous liquids, respectively. In the case of Al3 +, displacement efficiency was smaller than that in the non-reactive case, whereas in the case of Fe3 +, the displacement efficiency was larger. We consider that the difference in change of the patterns in the two systems will be caused by the difference in the properties of the gels. Therefore, we have measured the rheological properties of the gels by means of a rheometer. We discuss relationship between the VF patterns and the rheological measurement.

  2. Laminar flow of two miscible fluids in a simple network

    CERN Document Server

    Karst, Casey M; Geddes, John B

    2012-01-01

    When a fluid comprised of multiple phases or constituents flows through a network, non-linear phenomena such as multiple stable equilibrium states and spontaneous oscillations can occur. Such behavior has been observed or predicted in a number of networks including the flow of blood through the microcirculation, the flow of picoliter droplets through microfluidic devices, the flow of magma through lava tubes, and two-phase flow in refrigeration systems. While the existence of non-linear phenomena in a network with many inter-connections containing fluids with complex rheology may seem unsurprising, this paper demonstrates that even simple networks containing Newtonian fluids in laminar flow can demonstrate multiple equilibria. The paper describes a theoretical and experimental investigation of the laminar flow of two miscible Newtonian fluids of different density and viscosity through a simple network. The fluids stratify due to gravity and remain as nearly distinct phases with some mixing occurring only by d...

  3. Theoretical and experimental investigation of drug-polymer interaction and miscibility and its impact on drug supersaturation in aqueous medium.

    Science.gov (United States)

    Baghel, Shrawan; Cathcart, Helen; O'Reilly, Niall J

    2016-10-01

    Amorphous solid dispersions (ASDs) have the potential to offer higher apparent solubility and bioavailability of BCS class II drugs. Knowledge of the solid state drug-polymer solubility/miscibility and their mutual interaction are fundamental requirements for the effective design and development of such systems. To this end, we have carried out a comprehensive investigation of various ASD systems of dipyridamole and cinnarizine in polyvinylpyrrolidone (PVP) and polyacrylic acid (PAA) at different drug loadings. Theoretical and experimental examinations (by implementing binary and ternary Flory-Huggins (F-H) theory) related to drug-polymer interaction/miscibility including solubility parameter approach, melting point depression method, phase diagram, drug-polymer interaction in the presence of moisture and the effect of drug loading on interaction parameter were performed. The information obtained from this study was used to predict the stability of ASDs at different drug loadings and under different thermal and moisture conditions. Thermal and moisture sorption analysis not only provided the composition-dependent interaction parameter but also predicted the composition dependent miscibility. DPM-PVP, DPM-PAA and CNZ-PAA systems have shown molecular level mixing over the complete range of drug loading. For CNZ-PVP, the presence of a single Tg at lower drug loadings (10, 20 and 35%w/w) indicates the formation of solid solution. However, drug recrystallization was observed for samples with higher drug weight fractions (50 and 65%w/w). Finally, the role of polymer in maintaining drug supersaturation has also been explored. It has been found that drug-polymer combinations capable of hydrogen-bonding in the solution state (DPM-PVP, DPM-PAA and CNZ-PAA) are more effective in preventing drug crystallization compared to the drug-polymer systems without such interaction (CNZ-PVP). The DPM-PAA system outperformed all other ASDs in various stability conditions (dry-state, in

  4. Liquid-liquid miscibility and volumetric properties of aqueous solutions of ionic liquids as a function of temperature

    International Nuclear Information System (INIS)

    The volumetric properties of seven {water + ionic liquid} binary mixtures have been studied as a function of temperature from (293 to 343) K. The phase behaviour of the systems was first investigated using a nephelometric method and excess molar volumes were calculated from densities measured using an Anton Paar densimeter and fitted using a Redlich-Kister type equation. Two ionic liquids fully miscible with water (1-butyl-3-methylimidazolium tetrafluoroborate ([C1C4Im][BF4]) and 1-ethyl-3-methylimidazolium ethylsulfate ([C1C2Im][EtSO4])) and five ionic liquids only partially miscible with water (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C1C2Im][NTf2]), 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C1C4Im][NTf2]), 1-butyl-3-methylimidazolium hexafluorophosphate ([C1C4Im][PF6]), 1-butyl-3-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C1C4Pyrro][NTf2]), and butyltrimethylammonium bis(trifluoromethylsulfonyl)imide ([N4111][NTf2])) were chosen. Small excess volumes (less than 0.5 cm3 . mol-1 at 298 K) are obtained compared with the molar volumes of the pure components (less than 0.3% of the molar volume of the pure ionic liquid). For all the considered systems, except for {[C1C2Im][EtSO4] + water}, positive excess molar volumes were calculated. Finally, an increase of the non-ideality character is observed for all the systems as temperature increases.

  5. Liquid-liquid miscibility and volumetric properties of aqueous solutions of ionic liquids as a function of temperature

    Energy Technology Data Exchange (ETDEWEB)

    Wang Silu [QUILL Research Center, School of Chemistry, Queen' s University of Belfast (United Kingdom); Jacquemin, Johan [QUILL Research Center, School of Chemistry, Queen' s University of Belfast (United Kingdom); Thermodynamique et Interactions Moleculaires, FRE 3099, Universite Blaise Pascal Clermont-Ferrand/CNRS, 24 avenue des Landais, 63177 Aubiere Cedex (France); Husson, Pascale [Thermodynamique et Interactions Moleculaires, FRE 3099, Universite Blaise Pascal Clermont-Ferrand/CNRS, 24 avenue des Landais, 63177 Aubiere Cedex (France)], E-mail: pascale.husson@univ-bpclermont.fr; Hardacre, Christopher [QUILL Research Center, School of Chemistry, Queen' s University of Belfast (United Kingdom); Costa Gomes, Margarida F. [Thermodynamique et Interactions Moleculaires, FRE 3099, Universite Blaise Pascal Clermont-Ferrand/CNRS, 24 avenue des Landais, 63177 Aubiere Cedex (France)

    2009-11-15

    The volumetric properties of seven {l_brace}water + ionic liquid{r_brace} binary mixtures have been studied as a function of temperature from (293 to 343) K. The phase behaviour of the systems was first investigated using a nephelometric method and excess molar volumes were calculated from densities measured using an Anton Paar densimeter and fitted using a Redlich-Kister type equation. Two ionic liquids fully miscible with water (1-butyl-3-methylimidazolium tetrafluoroborate ([C{sub 1}C{sub 4}Im][BF{sub 4}]) and 1-ethyl-3-methylimidazolium ethylsulfate ([C{sub 1}C{sub 2}Im][EtSO{sub 4}])) and five ionic liquids only partially miscible with water (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C{sub 1}C{sub 2}Im][NTf{sub 2}]), 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C{sub 1}C{sub 4}Im][NTf{sub 2}]), 1-butyl-3-methylimidazolium hexafluorophosphate ([C{sub 1}C{sub 4}Im][PF{sub 6}]), 1-butyl-3-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C{sub 1}C{sub 4}Pyrro][NTf{sub 2}]), and butyltrimethylammonium bis(trifluoromethylsulfonyl)imide ([N{sub 4111}][NTf{sub 2}])) were chosen. Small excess volumes (less than 0.5 cm{sup 3} . mol{sup -1} at 298 K) are obtained compared with the molar volumes of the pure components (less than 0.3% of the molar volume of the pure ionic liquid). For all the considered systems, except for {l_brace}[C{sub 1}C{sub 2}Im][EtSO{sub 4}] + water{r_brace}, positive excess molar volumes were calculated. Finally, an increase of the non-ideality character is observed for all the systems as temperature increases.

  6. Use of tracers to monitor in situ miscibility of solvent in oil reservoirs during EOR

    International Nuclear Information System (INIS)

    This patent describes a method for monitoring in situ miscibility of a solvent with reservoir oil. It comprises selecting at least two tracers from the group consisting of halo-hydrocarbons, halocarbons, sulfur hexafluoride, tritium gas, radioactive isotopes of inert gases, and triated or carbon 14tagged hydrocarbons, the tracers being miscible with the solvent and having different boiling points; forming a mixture comprising the tracers and the solvent; injecting the mixture into an injection well; producing fluids from a production well in communication with the injection well; and analyzing the fluids for the presence of the tracers to determine solvent miscibility with the reservoir oil

  7. Size effects in band gap bowing in nitride semiconducting alloys

    DEFF Research Database (Denmark)

    Gorczyca, I.; Suski, T.; Christensen, Niels Egede;

    2011-01-01

    Chemical and size contributions to the band gap bowing of nitride semiconducting alloys (InxGa1-xN, InxAl1-xN, and AlxGa1-xN) are analyzed. It is shown that the band gap deformation potentials of the binary constituents determine the gap bowing in the ternary alloys. The particularly large gap...

  8. Gap Junctions

    OpenAIRE

    Goodenough, Daniel A.; Paul, David L.

    2009-01-01

    Gap junctions are aggregates of intercellular channels that permit direct cell–cell transfer of ions and small molecules. Initially described as low-resistance ion pathways joining excitable cells (nerve and muscle), gap junctions are found joining virtually all cells in solid tissues. Their long evolutionary history has permitted adaptation of gap-junctional intercellular communication to a variety of functions, with multiple regulatory mechanisms. Gap-junctional channels are composed of hex...

  9. Gap Junctions

    OpenAIRE

    Nielsen, Morten Schak; Axelsen, Lene Nygaard; Sorgen, Paul L.; Verma, Vandana; Delmar, Mario; Holstein-Rathlou, Niels-Henrik

    2012-01-01

    Gap junctions are essential to the function of multicellular animals, which require a high degree of coordination between cells. In vertebrates, gap junctions comprise connexins and currently 21 connexins are known in humans. The functions of gap junctions are highly diverse and include exchange of metabolites and electrical signals between cells, as well as functions, which are apparently unrelated to intercellular communication. Given the diversity of gap junction physiology, regulation of ...

  10. MISCIBILITY, SOLUBILITY, AND VISCOSITY MEASUREMENTS FOR R-236EA WITH POTENTIAL LUBRICANTS

    Science.gov (United States)

    The report gives results of miscibility, solubility, and viscosity measurements of refrigerant R-236ea with three potential lubricants. (NOTE: The data were needed to determine the suitability of refrigerant/lubricant combinations for use in refrigeration systems.) The lubricants...

  11. Determination of Minimum Miscibility Pressure in supercritical extractor using oil saturated sample

    DEFF Research Database (Denmark)

    Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Abbasi, Waqas A.;

    2009-01-01

      The main parameter for determination of the possibilities to enhance oil recovery by e.g. CO2 injection into a specific oil field is the measurement of Minimum Miscibility Pressure (MMP). This pressure is the lowest pressure for which a gas can obtain miscibility through a multi contact process...... the breakover point criterion the MMP read from the plot was found equal to 20 MPa.  ...

  12. Increasing Membrane Tension Decreases Miscibility Temperatures; an Experimental Demonstration via Micropipette Aspiration

    OpenAIRE

    Portet, Thomas; Gordon, Sharona E.; Keller, Sarah L.

    2012-01-01

    It has been hypothesized that cytoskeletal tension prevents large-scale phase separation within cell plasma membranes. Here, we microaspirate giant unilamellar vesicles to determine the effect of mechanical stress on the liquid/liquid miscibility temperature of a membrane composed of a ternary lipid mixture. An increase in tension of 0.1 mN/m induces a decrease in miscibility temperature on the order of a few tenths of a degree K, which validates recent theoretical predictions.

  13. Rectangular Decomposition of Binary Images

    Czech Academy of Sciences Publication Activity Database

    Suk, Tomáš; Höschl, Cyril; Flusser, Jan

    Berlin : Springer, 2012 - (Blanc-Talon, J.; Popescu, D.; Philips, W.; Scheunders, P.), s. 213-224 ISBN 978-3-642-33139-8. - (Lecture Notes in Computer Science. 7517). [Advanced Concepts for Intelligent Vision Systems (Acivs 2012). Brno (CZ), 04.09.2012-07.09.2012] R&D Projects: GA ČR GAP103/11/1552 Institutional support: RVO:67985556 Keywords : binary image decomposition * generalized delta-method * distance transformation * quadtree * bipartite graph * image compression * fast convolution Subject RIV: IN - Informatics, Computer Science http://library.utia.cas.cz/separaty/2012/ZOI/suk-rectangular decomposition of binary images.pdf

  14. Binary Planets

    Science.gov (United States)

    Ryan, Keegan; Nakajima, Miki; Stevenson, David J.

    2014-11-01

    Can a bound pair of similar mass terrestrial planets exist? We are interested here in bodies with a mass ratio of ~ 3:1 or less (so Pluto/Charon or Earth/Moon do not qualify) and we do not regard the absence of any such discoveries in the Kepler data set to be significant since the tidal decay and merger of a close binary is prohibitively fast well inside of 1AU. SPH simulations of equal mass “Earths” were carried out to seek an answer to this question, assuming encounters that were only slightly more energetic than parabolic (zero energy). We were interested in whether the collision or near collision of two similar mass bodies would lead to a binary in which the two bodies remain largely intact, effectively a tidal capture hypothesis though with the tidal distortion being very large. Necessarily, the angular momentum of such an encounter will lead to bodies separated by only a few planetary radii if capture occurs. Consistent with previous work, mostly by Canup, we find that most impacts are disruptive, leading to a dominant mass body surrounded by a disk from which a secondary forms whose mass is small compared to the primary, hence not a binary planet by our adopted definition. However, larger impact parameter “kissing” collisions were found to produce binaries because the dissipation upon first encounter was sufficient to provide a bound orbit that was then rung down by tides to an end state where the planets are only a few planetary radii apart. The long computational times for these simulation make it difficult to fully map the phase space of encounters for which this outcome is likely but the indications are that the probability is not vanishingly small and since planetary encounters are a plausible part of planet formation, we expect binary planets to exist and be a non-negligible fraction of the larger orbital radius exoplanets awaiting discovery.

  15. Silk fibroin and sodium alginate blend: Miscibility and physical characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Agostini de Moraes, Mariana; Silva, Mariana Ferreira; Weska, Raquel Farias; Beppu, Marisa Masumi, E-mail: beppu@feq.unicamp.br

    2014-07-01

    Films of silk fibroin (SF) and sodium alginate (SA) blends were prepared by solution casting technique. The miscibility of SF and SA in those blends was evaluated and scanning electron microscopy (SEM) revealed that SF/SA 25/75 wt.% blends underwent microscopic phase separation, resulting in globular structures composed mainly of SF. X-ray diffraction indicated the amorphous nature of these blends, even after a treatment with ethanol that turned them insoluble in water. Thermal analyses of blends showed the peaks of degradation of pristine SF and SA shifted to intermediate temperatures. Water vapor permeability, swelling capacity and tensile strength of SF films could be enhanced by blending with SA. Cell viability remained between 90 and 100%, as indicated by in vitro cytotoxicity test. The SF/SA blend with self-assembled SF globules can be used to modulate structural and mechanical properties of the final material and may be used in designing high performance wound dressing. - Highlights: • Blend films of fibroin and alginate were prepared with microscopic phase separation; • Self-assembled globular microdomains were mainly composed by fibroin; • It was possible to obtain a film with better mechanical and physical properties; • Blend films of fibroin and alginate represent a novel material in biomaterials field.

  16. Damping of Quasi-stationary Waves Between Two Miscible Liquids

    Science.gov (United States)

    Duval, Walter M. B.

    2002-01-01

    Two viscous miscible liquids with an initially sharp interface oriented vertically inside a cavity become unstable against oscillatory external forcing due to Kelvin-Helmholtz instability. The instability causes growth of quasi-stationary (q-s) waves at the interface between the two liquids. We examine computationally the dynamics of a four-mode q-s wave, for a fixed energy input, when one of the components of the external forcing is suddenly ceased. The external forcing consists of a steady and oscillatory component as realizable in a microgravity environment. Results show that when there is a jump discontinuity in the oscillatory excitation that produced the four-mode q-s wave, the interface does not return to its equilibrium position, the structure of the q-s wave remains imbedded between the two fluids over a long time scale. The damping characteristics of the q-s wave from the time history of the velocity field show overdamped and critically damped response; there is no underdamped oscillation as the flow field approaches steady state. Viscous effects serve as a dissipative mechanism to effectively damp the system. The stability of the four-mode q-s wave is dependent on both a geometric length scale as well as the level of background steady acceleration.

  17. Uphill diffusion and phase separation in partially miscible multicomponent mixtures

    Science.gov (United States)

    He, Ping; Raghavan, Ashwin; Ghoniem, Ahmed

    2015-11-01

    The partially miscible multicomponent mixtures, which are frequently encountered in green chemistry processes, often exhibit complicated behaviors, and are critical to the production rate, energy efficiency, and pollution controls. Recent studies have been mainly focused on phase behaviors. However, the coupled phase equilibrium and transport process, which may be the answer to phase separations observed in experiments, is not well researched. Here, we present a numerical and theoretical study on coupled mixing of heavy oil and supercritical water, and the results of our state-of-art modeling agree with experimental measurements. We find that due to the non-ideal diffusion driving force, (1) strong uphill diffusion of heavy oil fractions occurs, (2) a new heavy oil phase is separated starting from the plait point, and heavy fractions become highly concentrated, and (3) water diffusion initially overshoots in oil, and is expelled lately. Finally, we conclude our analysis applicable to different molecules and conditions. The authors thank Saudi Aramco for supporting this work (contract number 6600023444).

  18. MISCIBILITY, CRYSTALLIZATION AND MECHANICAL PROPERTIES OF PPC/PBS BLENDS

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In this paper, melt blends of poly(propylene carbonate) (PPC) with poly(butylene succinate) (PBS) were characterized by dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), tensile testing, wide-angle X-ray diffraction (WAXD), polarized optical microscopy and thermogravimetric analysis (TGA). The results indicated that the glass transition temperature of PPC in the 90/10 PPC/PBS blend was decreased by about 11 K comparing with that of pure PPC. The presence of 10% PBS was partially miscible with PPC. The 90/10 PPC/PBS blend had better impact and tensile strength than those of the other PPC/PBS blends. The glass transition temperature of PPC in the 80/20, 70/30, and 60/40 PPC/PBS blends was improved by about 4.9 K, 4.2 K, and 13 K comparing with that of pure PPC, respectively; which indicated the immiscibility between PPC and PBS. The DSC results indicated that the crystallization of PBS became more difficult when the PPC content increased. The matrix of PPC hindered the crystallization process of PBS. While the content of PBS was above 20%, significant crystallization-induced phase separation was observed by polarized optical microscopy.It was found from the WAXD analysis that the crystal structure of PBS did not change, and the degree of crystallinity increased with increasing PBS content in the PPC/PBS blends.

  19. Spinodal decomposition of chemically reactive binary mixtures

    Science.gov (United States)

    Lamorgese, A.; Mauri, R.

    2016-08-01

    We simulate the influence of a reversible isomerization reaction on the phase segregation process occurring after spinodal decomposition of a deeply quenched regular binary mixture, restricting attention to systems wherein material transport occurs solely by diffusion. Our theoretical approach follows a diffuse-interface model of partially miscible binary mixtures wherein the coupling between reaction and diffusion is addressed within the frame of nonequilibrium thermodynamics, leading to a linear dependence of the reaction rate on the chemical affinity. Ultimately, the rate for an elementary reaction depends on the local part of the chemical potential difference since reaction is an inherently local phenomenon. Based on two-dimensional simulation results, we express the competition between segregation and reaction as a function of the Damköhler number. For a phase-separating mixture with components having different physical properties, a skewed phase diagram leads, at large times, to a system converging to a single-phase equilibrium state, corresponding to the absolute minimum of the Gibbs free energy. This conclusion continues to hold for the critical phase separation of an ideally perfectly symmetric binary mixture, where the choice of final equilibrium state at large times depends on the initial mean concentration being slightly larger or less than the critical concentration.

  20. Synthesis of levan in water-miscible organic solvents.

    Science.gov (United States)

    Castillo, E; López-Munguía, A

    2004-10-19

    The synthesis of levan using a levansucrase from a strain of Bacillus subtilis was studied in the presence of the water-miscible solvents: acetone, acetonitrile and 2-methyl-2-propanol (2M2P). It was found that while the enzyme activity is only slightly affected by acetone and acetonitrile, 2M2P has an activating effect increasing the total activity 35% in 40-50% (v/v) 2M2P solutions at 30 degrees C. The enzyme is highly stable in water at 30 degrees C; however, incubation in the presence of 15 and 50% (v/v) 2M2P reduced the half-life time to 23.6 and 1.8 days, respectively. This effect is reversed in 83% 2M2P, where a half-life time of 11.8 days is observed. The presence of 2M2P in the system increases the transfer/hydrolysis ratio of levansucrase. As the reaction proceeds with 10% (w/v) sucrose in 50/50 water/2M2P sucrose is converted to levan and an aqueous two-phase system (2M2P/Levan) is formed and more sucrose can be added in a fed batch mode. It is shown that high molecular weight levan is obtained as an hydrogel and may be easily recovered from the reaction medium. However, when high initial sucrose concentrations (40% (w/v) in 50/50 water/2M2P) are used, an aqueous two-phase system (2M2P/sucrose) is induce, where the synthesized levan has a similar molecular weight distribution as in water and remains in solution. PMID:15464614

  1. Calcium Carbonate Crystal Growth in Porous Media, in the presence of Water Miscible and Non-Miscible Organic Fluids

    Science.gov (United States)

    Jaho, Sofia; Sygouni, Varvara; Paraskeva, Christakis A.

    2015-04-01

    The deposition of sparingly soluble salts (scaling) within porous media is a major problem encountered in many industrial and environmental applications. In the oil industry scaling causes severe operational malfunctions and, therefore, increasing the total operating and maintenance cost [1]. The most common types of sparingly soluble salts located in oil fields include carbonate and sulfate salts of calcium, strondium and barium[1,2]. Multiple phase flow and tubing surface properties are some of the factors affecting scale formation [3]. The main purpose of the present work was the investigation of the precipitation mechanisms of calcium carbonate (CaCO3) through in situ mixing of two soluble salt solutions in a flow granular medium, in the presence of water miscible organic fluid (ethylene glycol) or non-miscible organic fluid (n-dodecane). All series of experiments were carried out in a two dimensional porous medium made of Plexiglas. For all solutions used in the experiments, the contact angles with the surface of the porous medium and the interfacial tensions were measured. During the experiments, the calcium carbonate crystal growth was continuously monitored and recorded through an optical microscope equipped with a digital programmed video camera. The snap-shots were taken within specific time intervals and their detailed procession gave information concerning the crystal growth rate and kinetics. The pH of the effluent was measured and fluids samples were collected for calcium analysis using Atomic Absorption Spectroscopy (AAS). In all experiments effluent calcium concentration decreased as a function of time, suggesting that CaCO3 precipitation took place inside the porous medium. Crystals of the precipitated salt were identified using Infrared Spectroscopy (IR) and the morphology of the crystals was examined using Scanning Electron Microscopy (SEM). The induction time for precipitation of CaCO3 crystals in the presence of n-dodecane was significantly

  2. Influence of viscosity contrast on buoyantly unstable miscible fluids in porous media

    CERN Document Server

    Pramanik, Satyajit; Mishra, Manoranjan

    2015-01-01

    The influence of viscosity contrast on buoyantly unstable miscible fluids in a porous medium is investigated through a linear stability analysis (LSA) as well as direct numerical simulations (DNS). The linear stability method implemented in this paper is based on an initial value approach, which helps to capture the onset of instability more accurately than the quasi-steady state analysis. In the absence of displacement, we show that viscosity contrast delays the onset of instability in buoyantly unstable miscible fluids. Further, it is observed that suitably choosing the viscosity contrast and injection velocity a gravitationally unstable miscible interface can be stabilized completely. Through LSA we draw a phase diagram, which shows three distinct stability regions in a parameter space spanned by the displacement velocity and the viscosity contrast. DNS are performed corresponding to parameters from each regime and the results obtained are in accordance with the linear stability results. Moreover, the conv...

  3. Measurement of hydrodynamic interaction parameter for miscibility test of polymer blends by positron lifetime method

    International Nuclear Information System (INIS)

    Positron Annihilation Lifetime Spectroscopy is used to determine the free volume content in the blends of SAN/PMMA and PS/PVC. Though the free volume data indicate the miscible/immiscible nature of the blends, the extent of miscibility for different weight compositions is not forthcoming. Therefore the hydrodynamic interaction parameter α which accounts for the excess friction between the constituents of the blend system is evaluated for this purpose. The SAN/PMMA system produces a maximum α of -209 at 20% of PMMA concentration while PS/PVC almost zero. It appears sound that hydrodynamic interaction parameter, α, is a suitable parameter to understand the composition dependent miscibility level in polymer blends. (author)

  4. Knowledge Gaps

    DEFF Research Database (Denmark)

    Lyles, Marjorie; Pedersen, Torben; Petersen, Bent

    2003-01-01

    , assimilating, and utilizing knowledge - are crucial determinants ofknowledge gap elimination. In contrast, the two factors deemed essential in traditionalinternationalization process theory - elapsed time of operations and experientiallearning - are found to have no or limited effect.Key words...

  5. A comparative study of gas-gas miscibility processes in underground gas storage reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Rafiee, M.M.; Schmitz, S. [DBI - Gastechnologisches Institut gGmbH, Freiberg (Germany)

    2013-08-01

    Intermixture of gases in underground gas reservoirs have had great weight for natural gas storage in UGS projects with substitution of cushion gas by inert gases or changing the stored gas quality or origin, as for the replacement of town gas by natural gas. It was also investigated during the last years for Enhanced Gas Recovery (EGR) and Carbon Capture and Storage (CCS) projects. The actual importance of its mechanisms is discussed for the H{sub 2} storage in Power to Gas to Power projects (PGP). In these approaches miscibility of the injected gas with the gas in place in the reservoir plays an important role in the displacement process. The conditions and parameters for the gas-gas displacement and mixing have been investigated in previous projects, as e.g. the miscibility of CO{sub 2} with natural gas (CLEAN). Furthermore the miscibility process of town gas with natural gas and sauer gas with sweet gas were also previously measured and compared in laboratory. The objective of this work is to investigate the miscibility of H{sub 2} injection into natural gas reservoirs using a compositional and a black oil reservoir simulator. Three processes of convection, dispersion and diffusion are considered precisely. The effect of gas miscibility is studied for both simulators and the results are compared to find optimum miscibility parameters. The findings of this work could be helpful for further pilot and field case studies to predict and monitor the changes in gas composition and quality. In future this monitoring might become more important when PGP together with H{sub 2}-UGS, as storage technology, will help to successfully implement the change to an energy supply from more renewable sources. Similarly the method confirms the use of the black oil simulator as an alternative for gas-gas displacement and sequestration reservoir simulation in comparison to the compositional simulator. (orig.)

  6. Investigated Miscible CO2 Flooding for Enhancing Oil Recovery in Wettability Altered Chalk and Sandstone Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Tabrizy, Vahid Alipour

    2012-07-01

    The thesis addresses oil recovery by miscible CO2 flooding from modified sandstone and chalk rocks. Calcite mineral surface is modified with stearic acid (SA) and asphaltene, and the silicate mineral surfaces are modified with N,N-dimethyldodecylamine (NN-DMDA) and asphaltene. The stability of adsorbed polar components in presence of SO4 2- and Mg2 + ions is also investigated. Recovery from sandstone cores is consistently lower than that from chalk cores saturated with the same oil and flooded with CO2 at all miscible flooding conditions. This may be due to the larger permeability contrasts in sandstone cores, which promote the fingering phenomenon. Miscible CO2 flooding for chalk and sandstone cores with distilled water, as initial water saturation, shows also lower oil recovery than cores saturated with different ions. At higher miscible flooding conditions, higher oil recovery is obtained. However, presence of light components (such as C1 or C3) in oil reduced the recovery. Oil recovery in presence of methane (C1) is lower than that in presence of methane and propane (C1/C3). A ternary diagram was constructed in order to understand the CO2 flooding mechanism(s) at the different flooding conditions and in presence of light components. The side effect of the flooding with CO2 is the probability for asphaltene deposition. An approach based on solubility parameter in the liquid, is used to assess the risk for asphaltene deposition during CO2 miscible flooding. The light components (C1/C3) and higher flooding conditions enhanced the risk for asphaltene instability. It is also shown higher amount of asphaltene deposition in chalk cores than that in sandstone cores at similar miscibility conditions.(au)

  7. Mythic gaps

    Directory of Open Access Journals (Sweden)

    William Hansen

    2014-11-01

    Full Text Available Different kinds of omissions sometimes occur, or are perceived to occur, in traditional narratives and in tradition-inspired literature. A familiar instance is when a narrator realizes that he or she does not fully remember the story that he or she has begun to tell, and so leaves out part of it, which for listeners may possibly result in an unintelligible narrative. But many instances of narrative gap are not so obvious. From straightforward, objective gaps one can distinguish less-obvious subjective gaps: in many cases narrators do not leave out anything crucial or truly relevant from their exposition, and yet readers perceive gaps and take steps to fill them. The present paper considers four examples of subjective gaps drawn from ancient Greek literature (the Pandora myth, ancient Roman literature (the Pygmalion legend, ancient Hebrew literature (the Joseph legend, and early Christian literature (the Jesus legend. I consider the quite varied ways in which interpreters expand the inherited texts of these stories, such as by devising names, manufacturing motives, creating backstories, and in general filling in biographical ellipses. Finally, I suggest an explanation for the phenomenon of subjective gaps, arguing that, despite their variety, they have a single cause.

  8. Influence of the degree of hydrolysis of poly(styrene-alt-maleic anhydride) on miscibility with poly(vinyl acetate)

    NARCIS (Netherlands)

    Bosma, M.; Vorenkamp, E.J.; Brinke, G. ten; Challa, G.

    1988-01-01

    The influence of the hydrolysis of anhydride groups in poly(styrene-alt-maleic anhydride) (PSMA) on its miscibility with poly(vinyl acetate) (PVAc) is investigated. The cloudpoint curves of these blends are determined as a function of the degree of hydrolysis. The miscibility is shown to improve wit

  9. Miscibility study of hexanoyl chitosan in blend with epoxidized natural rubber by viscometric analysis

    Science.gov (United States)

    Jamal, Asheila; Chan, C. H.; Muhammad, F. H.; Winie, Tan

    2015-08-01

    Miscibility of blends of hexanoyl chitosan and epoxidized natural rubber with 25 mol% epoxidation level (ENR25) was investigated by dilute solution viscometry (DSV). Experimental results obey the Huggins' equation in the concentration range under investigation. Intrinsic viscosities are found to vary linearly with blend composition. The difference between experimental and ideal Huggins coefficients, κ =K12-√{K1ṡK2 } is proposed to evaluate the miscibility behavior of the blends. Negative deviations from the ideal behavior indicated immiscibility between hexanoyl chitosan and ENR25.

  10. Miscibility Development Computation in Enhanced Oil Recovery by Flare Gas Flooding

    OpenAIRE

    Tjokorde Walmiki Samadhi; Utjok W.R. Siagian; Angga P. Budiono

    2012-01-01

    The use of flare gas as injection gas in miscible gas flooding enhanced oil recovery (MGF-EOR) presents a potential synergy between oil production improvement and greenhouse gases emission mitigation. This work is a preliminary evaluation of the feasibility of miscible flare gas injection based on phase behavior computations of a model oil (43%n-C5H12 : 57%n-C16H34) and a model flare gas (91%CH4 : 9%C2H6). The computations employed the multiple mixing-cell model with Peng-Robinson and PC-SAFT...

  11. Thermodynamics and Phase Behavior of Miscible Polymer Blends in the Presence of Supercritical Carbon Dioxide

    Science.gov (United States)

    Young, Nicholas Philip

    The design of environmentally-benign polymer processing techniques is an area of growing interest, motivated by the desire to reduce the emission of volatile organic compounds. Recently, supercritical carbon dioxide (scCO 2) has gained traction as a viable candidate to process polymers both as a solvent and diluent. The focus of this work was to elucidate the nature of the interactions between scCO2 and polymers in order to provide rational insight into the molecular interactions which result in the unexpected mixing thermodynamics in one such system. The work also provides insight into the nature of pairwise thermodynamic interactions in multicomponent polymer-polymer-diluent blends, and the effect of these interactions on the phase behavior of the mixture. In order to quantify the strength of interactions in the multicomponent system, the binary mixtures were characterized individually in addition to the ternary blend. Quantitative analysis of was made tractable through the use of a model miscible polymer blend containing styrene-acrylonitrile copolymer (SAN) and poly(methyl methacrylate) (dPMMA), a mixture which has been considered for a variety of practical applications. In the case of both individual polymers, scCO2 is known to behave as a diluent, wherein the extent of polymer swelling depends on both temperature and pressure. The solubility of scCO 2 in each polymer as a function of temperature and pressure was characterized elsewhere. The SAN-dPMMA blend clearly exhibited lower critical solution temperature behavior, forming homogeneous mixtures at low temperatures and phase separating at elevated temperature. These measurements allowed the determination of the Flory-Huggins interaction parameter chi23 for SAN (species 2) and dPMMA (species 3) as a function of temperature at ambient pressure, in the absence of scCO2 (species 1). Characterization of the phase behavior of the multicomponent (ternary) mixture was also carried out by SANS. An in situ SANS

  12. GAP Analysis Program (GAP) Raster

    Data.gov (United States)

    Kansas Data Access and Support Center — The Kansas GAP Land Cover database depicts 43 land cover classes for the state of Kansas. The database was generated using a two-stage hybrid classification of...

  13. MISCIBILITY, SOLUBILITY, VISCOSITY, AND DENSITY MEASUREMENTS FOR R-236EA WITH FOUR DIFFERENT EXXON LUBRICANTS

    Science.gov (United States)

    The report discusses miscibility, solubility, viscosity, and density data for the refrigerant hydrofluorocarbon (HFC)-236ea (or R-236ea) and four lubricants supplied by Exxon Corporation. Such data are needed to determine the suitability of refrigerant/lubricant combinations for ...

  14. MISCIBILITY, SOLUBILITY, VISCOSITY, AND DENSITY MEASUREMENTS FOR R-236FA WITH POTENTIAL LUBRICANTS

    Science.gov (United States)

    The report gives results of miscibility, solubility, viscosity, and density measurements for refrigerant R-236fa and two potential lubricants . (The data are needed to determine the suitability of refrigerant/lubricant combinations for use in refrigeration systems.) The tested oi...

  15. Compositional and Relative Permeability Hysteresis Effects on Near-Miscible WAG

    DEFF Research Database (Denmark)

    Christensen, Jes Reimer; Stenby, Erling Halfdan; Skauge, Arne

    1998-01-01

    Evaluation of compositional effects and fluid flow description on near-miscible (water-alternating-gas) WAG modeling have been studied for a North Sea oil field starting production in 1998. A sector model with four wells was applied to simulate a heterogeneous sandstone reservoir, and a compositi...

  16. Serpentine diffusion trajectories and the Ouzo effect in partially miscible ternary liquid mixtures

    NARCIS (Netherlands)

    R. Krishna

    2015-01-01

    This work investigates the transient equilibration process when partially miscible ternary liquid mixtures of two different compositions are brought into contact with each other. Diffusional coupling effects are shown to become increasingly significant as the mixture compositions approach the meta-s

  17. Magnetic resonance imaging study on near miscible supercritical CO2 flooding in porous media

    Science.gov (United States)

    Song, Yongchen; Zhu, Ningjun; Zhao, Yuechao; Liu, Yu; Jiang, Lanlan; Wang, Tonglei

    2013-05-01

    CO2 flooding is one of the most popular secondary or tertiary recoveries for oil production. It is also significant for studying the mechanisms of the two-phase and multiphase flow in porous media. In this study, an experimental study was carried out by using magnetic resonance imaging technique to examine the detailed effects of pressure and rates on CO2/decane flow in a bead-pack porous media. The displacing processes were conducted under various pressures in a region near the minimum miscibility pressure (the system tuned from immiscible to miscible as pressure is increasing in this region) and the temperature of 37.8 °C at several CO2 injection volumetric rates of 0.05, 0.10, and 0.15 ml/min (or linear rates of 3.77, 7.54, and 11.3 ft/day). The evolution of the distribution of decane and the characteristics of the two phase flow were investigated and analyzed by considering the pressure and rate. The area and velocity of the transition zone between the two phases were calculated and analyzed to quantify mixing. The area of transition zone decreased with pressure at near miscible region and a certain injection rate and the velocity of the transition zone was always less than the "volumetric velocity" due to mutual solution and diffusion of the two phases. Therefore, these experimental results give the fundamental understanding of tertiary recovery processes at near miscible condition.

  18. PRELIMINARY INVESTIGATION ON THE MISCIBILITY OF ISOTACTIC POLYPROPYLENE(iPP) AND SYNDIOTACTIC POLYPROPYLENE(sPP)BLENDS

    Institute of Scientific and Technical Information of China (English)

    Chun-xiao Zheng; Duan-fu Xu; Xiu-qin Zhang; Joerg Rottstegge; Xia Dong; Ying Zhao; Du-jin Wang; Shan-nong Zhu; Zhi-gang Wang; Charles C. Han

    2006-01-01

    Experimental miscibility studies were performed on different compositions of iPP/sPP blends, where sPP has a low syndiotacticity ([rrrr] = 81%). Combining optical microscopy, rheology, and solid state NMR spectroscopy, the miscibility of the blends was investigated at different scales in the traditionally thought to be "immiscible" iPP/sPP blends. For the composition of iPP/sPP (90/10) blend, it shows to be miscible in the melt, and furthermore, the existence of intermolecular chain interactions between sPP and iPP components was detected in the solid state.

  19. Scale-up of miscible flood processes for heterogeneous reservoirs. Quarterly report, January 1--March 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Orr, F.M. Jr.

    1994-04-01

    The current project is a systematic research effort aimed at quantifying relationships between process mechanisms that can lead to improved recovery from gas injection processes performed in heterogeneous Class 1 and Class 2 reservoirs. It will provide a rational basis for the design of displacement processes that take advantage of crossfiow due to capillary, gravity and viscous forces to offset partially the adverse effects of heterogeneity. In effect, the high permeability zones are used to deliver fluid by crossflow to zones that would otherwise be flooded only very slowly. Thus, the research effort is divided into five areas: development of miscibility in multicomponent systems; design estimates for nearly miscible displacements; design of miscible floods for fractured reservoirs; compositional flow visualization experiments and simulation of near-miscible flow in heterogeneous systems. The status of the research effort in each area is reviewed briefly. In addition, results from pore-level modelling of three-phase flow in porous media are presented.

  20. Miscibility influence in the thermal stability and kinetic parameters of poly (3-hydroxybutyrate)/poly (ethylene terephthalate) sulphonated blends

    OpenAIRE

    Rafael Silva; Gizilene M. Carvalho; Muniz, Edvani C.; Adley F. Rubira

    2010-01-01

    The thermal degradation of miscible and immiscible poly (3-hidroxy butyrate) PHB/ poly (ethylene terephthalate) sulphonated (PETs) blends was investigated using thermogravimetric analyses. Model-free kinetic analysis, Vyazovkin and Flynn-Wall-Ozawa's methods, were used to determine the apparent activation energy in the whole interval of degradation of the pure polymers, immiscible blends, and miscible blends. The thermal stability of both polymers in their blends is higher when compared to th...

  1. Miscibility of lubricating oils with carbon dioxide; Mischbarkeit von Schmieroelen mit Kohlendioxid

    Energy Technology Data Exchange (ETDEWEB)

    Heide, R. [Inst. fuer Luft- und Kaeltetechnik gGmbH, Dresden (Germany); Fahl, J. [Fuchs DEA Schmierstoffe GmbH and Co. KG, Hamburg (Germany). F+E Lab.

    2001-10-01

    Due to its advantageous ecological and energetical properties CO{sub 2} presents again an interesting working fluid for various applications. For the proper design and operation of refrigeration circuits, the knowledge of miscibility characteristics of lubricating oils with CO{sub 2} is essential. Results of miscibility investigations on selected lubricants demonstrate a strong influence of chemical structure on phase behaviour with CO{sub 2}. (orig.) [German] Aufgrund seiner vorteilhaften oekologischen und energetischen Eigenschaften stellt CO{sub 2} heute trotz seines hohen Druckniveaus wieder ein interessantes Kaeltemittel fuer unterschiedliche Anwendungen dar. Fuer die Konstruktion und den Betrieb einer Kaelteanlage ist die Kenntnis der Mischungseigenschaften der Schmieroele mit CO{sub 2} erforderlich. Im folgenden werden Messergebnisse zur Mischbarkeit unterschiedlicher Oeltypen mit CO{sub 2} vorgestellt. Anhand der Mischungsluecken der untersuchten CO{sub 2}-Oel-Gemische wurde ein grossen Einfluss der chemischen Struktur auf das Phasenverhalten beobachtet. (orig.)

  2. A correlation for miscible flood displacement efficiency in the San Andres with NMR relaxation

    International Nuclear Information System (INIS)

    This paper reports that a set of San Andres crystalline dolomite cores was examined for the relationship between pore attributes discernible from NMR relaxation and miscible flooding displacement efficiency. A strong correlation was observed between the inferred abundance of long relaxation time components and laboratory measured residual oil to a multicontact miscible displacement process. NMR relaxation time distribution proved to be a simple, noninvasive, nondestructive indicator of flow performance in the 12 San Andres dolomite samples examined. Spin-lattice relaxation measurements were conducted on clean, brine saturated core end pieces from plugs taken adjacent to those used for flow displacement studies. Sample data were deconvoluted into a distribution of relaxation times, which is ultimately related to surface-to-volume ratio distribution. The median relaxation time was determined to be the most sensitive statistics to convey flow performance. Residual oil saturation was adequately represented by a power law function of the median relaxation time

  3. Non-modal linear stability analysis of miscible viscous fingering in a Hele-Shaw cell

    CERN Document Server

    Hota, Tapan Kumar; Mishra, Manoranjan

    2015-01-01

    For miscible viscous fingering (VF) in a Hele-Shaw cell or in two dimensional homogeneous porous media, the transient growth of disturbances is investigated by non-modal linear stability analysis (NMA). Due to the non-autonomous nature of the linearized perturbed equations, the linear stability theory prohibits using the normal mode analysis. The linearized perturbed equations for Darcy's law coupled with a convection-diffusion equation is discretized using finite difference method. The resultant matrix valued initial value problem is then solved by fourth order Runge-Kutta method, followed by a singular value decomposition (SVD) of the propagator matrix. We demonstrate the dominant perturbation that experiences the maximum amplification within the linear regime which lead to the transient growth. This feature was previously unattained in the existing linear stability methods for miscible VF. To explore the relevance of the optimal perturbation obtained from non-modal analysis of the physical system, we perfo...

  4. Fluid-fluid interaction during miscible and immiscible displacement under ultrasonic waves

    Science.gov (United States)

    Hamida, T.; Babadagli, T.

    2007-12-01

    This paper aims at identifying and analyzing the influence of high-frequency, high-intensity ultrasonic radiation at the interface between immiscible (different types of oils and aqueous solutions) and miscible (different types of oil and solvent) fluids. An extensive set of Hele-Shaw type experiments were performed for several viscosity ratios, and interfacial tension. Fractal analysis techniques were applied to quantify the degree of fingering and branching. This provided a rough assessment of the degree of perturbation generated at the interface when the capillary forces along with the viscous forces are effective. Miscible Hele-Shaw experiments were also presented to isolate the effect of viscous forces. We found that ultrasound acts to stabilize the interfacial front, and that such effect is most pronounced at low viscosity ratios.

  5. Miscibility phase diagram of ring-polymer blends: A topological effect

    Science.gov (United States)

    Sakaue, Takahiro; Nakajima, Chihiro H.

    2016-04-01

    The miscibility of polymer blends, a classical problem in polymer science, may be altered, if one or both of the component do not have chain ends. Based on the idea of topological volume, we propose a mean-field theory to clarify how the topological constraints in ring polymers affect the phase behavior of the blends. While the large enhancement of the miscibility is expected for ring-linear polymer blends, the opposite trend toward demixing, albeit comparatively weak, is predicted for ring-ring polymer blends. Scaling formulas for the shift of critical point for both cases are derived. We discuss the valid range of the present theory, and the crossover to the linear polymer blends behaviors, which is expected for short chains. These analyses put forward a view that the topological constraints could be represented as an effective excluded-volume effects, in which the topological length plays a role of the screening factor.

  6. Binary effectivity rules

    DEFF Research Database (Denmark)

    Keiding, Hans; Peleg, Bezalel

    2006-01-01

    Abstract  A social choice rule (SCR) is a collection of social choice correspondences, one for each agenda. An effectivity rule is a collection of effectivity functions, one for each agenda. We prove that every monotonic and superadditive effectivity rule is the effectivity rule of some SCR. A SCR...... is binary if it is rationalized by an acyclic binary relation. The foregoing result motivates our definition of a binary effectivity rule as the effectivity rule of some binary SCR. A binary SCR is regular if it satisfies unanimity, monotonicity, and independence of infeasible alternatives. A binary...... effectivity rule is regular if it is the effectivity rule of some regular binary SCR. We characterize completely the family of regular binary effectivity rules. Quite surprisingly, intrinsically defined von Neumann-Morgenstern solutions play an important role in this characterization...

  7. Investigated Miscible CO2 Flooding for Enhancing Oil Recovery in Wettability Altered Chalk and Sandstone Rocks

    OpenAIRE

    Tabrizy, Vahid Alipour

    2012-01-01

    The thesis addresses oil recovery by miscible CO2 flooding from modified sandstone and chalk rocks. Calcite mineral surface is modified with stearic acid (SA) and asphaltene, and the silicate mineral surfaces are modified with N,N-dimethyldodecylamine (NN-DMDA) and asphaltene. The stability of adsorbed polar components in presence of SO4 2- and Mg2 + ions is also investigated. Recovery from sandstone cores is consistently lower than that from chalk cores saturated with...

  8. The spontaneous motion of a slug of miscible liquids in a capillary tube

    OpenAIRE

    Sellier, Mathieu; Verdier, Claude; Nock, Volker

    2015-01-01

    This contribution explores a droplet actuation mechanism which involves mixing two different liquids slugs in a glass capillary. The resulting contrast in surface tension which arises provides the necessary propulsive power for the droplet. The conceptual idea is demonstrated for an ethanol-water system. The droplet is observed to rapidly reach a peak velocity which then gradually decreases with time as the two miscible liquids mix. A model is proposed based on Newton’s second law which is ab...

  9. Local and chain dynamics in miscible polymer blends: A Monte Carlo simulation study

    OpenAIRE

    Luettmer-Strathmann, Jutta; Mantina, Manjeera

    2005-01-01

    Local chain structure and local environment play an important role in the dynamics of polymer chains in miscible blends. In general, the friction coefficients that describe the segmental dynamics of the two components in a blend differ from each other and from those of the pure melts. In this work, we investigate polymer blend dynamics with Monte Carlo simulations of a generalized bond-fluctuation model, where differences in the interaction energies between non-bonded nearest neighbors distin...

  10. Miscibility of Methylmethacrylate-co-methacrylic Acid Polymer with Magnesium, Zinc, and Manganese Sulfonated Polystyrene Ionomers

    OpenAIRE

    ALKAN, Cemil; YURTSEVEN, Nebahat; ARAS, Leyla

    2005-01-01

    The miscibility of methyl methacrylate-co-methacrylic acid polymer (MMA-MAA) with metal neutralized sulfonated polystyrene ionomers was investigated by viscometry, differential scanning calorimetry (DSC), and Fourier transform infrared radiation spectroscopy (FTIR) techniques. Polystyrene (PS) was sulfonated by acetic anhydride and sulfuric acid and the sulfonation degree was found to be 2.6 mole percent, and 2.6 mole percent sulfonated polystyrene was neutralized by Mg, Zn, and Mn sa...

  11. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  12. Eclipsing binaries in open clusters

    DEFF Research Database (Denmark)

    Southworth, John; Clausen, J.V.

    Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August......Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August...

  13. The Effect of Molecular Structure and Environment on the Miscibility and Diffusivity in Polythiophene-Methanofullerene Bulk Heterojunctions: Theory and Modeling with the RISM Approach

    Directory of Open Access Journals (Sweden)

    Alexander E. Kobryn

    2016-04-01

    Full Text Available Although better means to model the properties of bulk heterojunction molecular blends are much needed in the field of organic optoelectronics, only a small subset of methods based on molecular dynamics- and Monte Carlo-based approaches have been hitherto employed to guide or replace empirical characterization and testing. Here, we present the first use of the integral equation theory of molecular liquids in modelling the structural properties of blends of phenyl-C61-butyric acid methyl ester (PCBM with poly(3-hexylthiophene (P3HT and a carboxylated poly(3-butylthiophene (P3BT, respectively. For this, we use the Reference Interaction Site Model (RISM with the Universal Force Field (UFF to compute the microscopic structure of blends and obtain insight into the miscibility of its components. Input parameters for RISM, such as optimized molecular geometries and charge distribution of interaction sites, are derived by the Density Functional Theory (DFT methods. We also run Molecular Dynamics (MD simulation to compare the diffusivity of the PCBM in binary blends with P3HT and P3BT, respectively. A remarkably good agreement with available experimental data and results of alternative modelling/simulation is observed for PCBM in the P3HT system. We interpret this as a step in the validation of the use of our approach for organic photovoltaics and support of its results for new systems that do not have reference data for comparison or calibration. In particular, for the less-studied P3BT, our results show that expectations about its performance in binary blends with PCBM may be overestimated, as it does not demonstrate the required level of miscibility and short-range structural organization. In addition, the simulated mobility of PCBM in P3BT is somewhat higher than what is expected for polymer blends and falls into a range typical for fluids. The significance of our predictive multi-scale modelling lies in the insights it offers into nanoscale

  14. The effect of ionic liquid hydrophobicity and solvent miscibility on pluronic amphiphile self-assembly.

    Science.gov (United States)

    Sharma, Suraj Chandra; Atkin, Rob; Warr, Gregory G

    2013-11-21

    The phase behavior of the triblock copolymer, (EO)20(PO)70(EO)20 (P123), in the water-immiscible (hydrophobic) ionic liquids (ILs), 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF6), and tris(pentafluoroethyl)trifluorophosphate (bmimFAP), has been investigated, and its amphiphilic self-assembly examined using small-angle X-ray scattering. The results obtained are contrasted with those for P123 in water. Direct and water-swellable micellar, hexagonal, and lamellar phases of P123 are found in bmimPF6, which behaves like a polar solvent despite being water immiscible, but bmimFAP behaves as a truly hydrophobic solvent, forming only a lamellar phase over a narrow composition range. The miscibility of bmimPF6 and water is increased by P123 addition, and at sufficiently high P123 concentrations, a single lamellar phase forms in which bmimPF6 and water are miscible in all proportions. In contrast, the preferential solubilization of bmimPF6 by PEO chains and bmimFAP by PPO chains causes the nanosegregation of these miscible ILs in concentrated P123 solutions. This leads to the formation of a P123/bmimPF6/bmimFAP microemulsion where bmimPF6 is the polar solvent and bmimFAP is the non-polar solvent. PMID:24138343

  15. Polymer-polymer miscibility in PEO/cationic starch and PEO/hydrophobic starch blends

    Directory of Open Access Journals (Sweden)

    2010-08-01

    Full Text Available The main purposes were evaluating the influence of different starches on the miscibility with Poly(ethylene oxide (PEO and their effects on the spherulite growth rate. Polymer-polymer miscibility in PEO/cationic starch and PEO/hydrophobic starch blends consisting of different w/w ratios (100/0, 95/05, 90/10, 80/20, 70/30, 65/35 and 60/40 was investigated. This analysis was based on the depression in the equilibrium melting temperature (Tm0. By treating the data of thermal analysis (Differential Scanning Calorimetry – DSC with Nishi-Wang equation, a positive value (0.68 was found for the interaction parameter of PEO/cationic starch. For PEO/hydrophobic starch blends, a negative value (–0.63 was obtained for the interaction parameter. The results suggested that PEO/cationic starch system should be immiscible. However, the system PEO/hydrophobic starch was considered to be miscible in the whole range of studied compositions. Through optical microscopy analysis, it was concluded that the spherulite growth rate is significantly affected by changing the amount and the type of starch as well.

  16. Solid state drug-polymer miscibility studies using the model drug ABT-102.

    Science.gov (United States)

    Jog, Rajan; Gokhale, Rajeev; Burgess, Diane J

    2016-07-25

    Amorphous solid dispersions typically suffer storage stability issues due to: their amorphous nature, high drug loading, uneven drug:stabilizer ratio and plasticization effects as a result of hygroscopic excipients. An extensive solid state miscibility study was conducted to aid in understanding the mechanisms involved in drug/stabilizer interactions. ABT-102 (model drug) and nine different polymers with different molecular weights and viscosities were selected to investigate drug/polymer miscibility. Three different polymer:drug ratios (1:3, 1:1 and 3:1, w/w) were analyzed using: DSC, FTIR and PXRD. Three different techniques were used to prepare the amorphous solid dispersions: serial dilution, solvent evaporation and spray drying. Spray drying was the best method to obtain amorphous solid dispersions. However, under certain conditions amorphous formulations could be obtained using solvent evaporation. Melting point depression was used to calculate interaction parameters and free energy of mixing for the various drug polymer mixtures. The spray dried solid dispersions yielded a negative free energy of mixing which indicated strong drug-polymer miscibility compared to the solvent evaporation and serial dilution method. Soluplus was the best stabilizer compared to PVP and HPMC, which is probably a consequence of strong hydrogen bonding between the two CO moieties of soluplus and the drug NH moieities. PMID:27265312

  17. The effect of additives interaction on the miscibility and crystal structure of two immiscible biodegradable polymers

    Directory of Open Access Journals (Sweden)

    Ahmed Mohamed El-Hadi

    2014-01-01

    Full Text Available Poly lactic acid (PLLA is a promising biopolymer, obtained from polymerization of lactic acid that is derived from renewable resources through fermentation. The characteristic brittleness of PLLA is attributed to slow crystallization rates, which results in the formation of the large spherulites. Its glass temperature is relative high, above room temperature and close to 60 ºC, and therefore its applications are limited. The additives poly((R-3-hydroxybutyrate (PHB, poly(vinyl acetate (PVAc and tributyl citrate (TBC were used as compatibilizers in the biodegradable polymer blend of (PLLA/PPC. Results from DSC and POM analysis indicated that the blends of PLLA and PPC are immiscible. However, the blends with additives are miscible. TBC as plasticizer was added to PLLA to reduce its Tg. PVAc was used as compatibilizer to improve the miscibility between PLLA and PPC. FT-IR showed about 7 cm-1 shift in the C=O peak in miscible blends due to physical interactions. POM experiments together with the results of DSC and WAXD showed that PHB enhances the crystallization behavior of PLLA by acting as bio nuclei and the crystallization process can occur more quickly. Consequently an increase was observed in the peak intensity in WAXD.

  18. Learning Compact Binary Face Descriptor for Face Recognition.

    Science.gov (United States)

    Lu, Jiwen; Liong, Venice Erin; Zhou, Xiuzhuang; Zhou, Jie

    2015-10-01

    Binary feature descriptors such as local binary patterns (LBP) and its variations have been widely used in many face recognition systems due to their excellent robustness and strong discriminative power. However, most existing binary face descriptors are hand-crafted, which require strong prior knowledge to engineer them by hand. In this paper, we propose a compact binary face descriptor (CBFD) feature learning method for face representation and recognition. Given each face image, we first extract pixel difference vectors (PDVs) in local patches by computing the difference between each pixel and its neighboring pixels. Then, we learn a feature mapping to project these pixel difference vectors into low-dimensional binary vectors in an unsupervised manner, where 1) the variance of all binary codes in the training set is maximized, 2) the loss between the original real-valued codes and the learned binary codes is minimized, and 3) binary codes evenly distribute at each learned bin, so that the redundancy information in PDVs is removed and compact binary codes are obtained. Lastly, we cluster and pool these binary codes into a histogram feature as the final representation for each face image. Moreover, we propose a coupled CBFD (C-CBFD) method by reducing the modality gap of heterogeneous faces at the feature level to make our method applicable to heterogeneous face recognition. Extensive experimental results on five widely used face datasets show that our methods outperform state-of-the-art face descriptors. PMID:26340256

  19. PHOEBE: PHysics Of Eclipsing BinariEs

    Science.gov (United States)

    Prsa, Andrej; Matijevic, Gal; Latkovic, Olivera; Vilardell, Francesc; Wils, Patrick

    2011-06-01

    PHOEBE (PHysics Of Eclipsing BinariEs) is a modeling package for eclipsing binary stars, built on top of the widely used WD program (Wilson & Devinney 1971). This introductory paper overviews most important scientific extensions (incorporating observational spectra of eclipsing binaries into the solution-seeking process, extracting individual temperatures from observed color indices, main-sequence constraining and proper treatment of the reddening), numerical innovations (suggested improvements to WD's Differential Corrections method, the new Nelder & Mead's downhill Simplex method) and technical aspects (back-end scripter structure, graphical user interface). While PHOEBE retains 100% WD compatibility, its add-ons are a powerful way to enhance WD by encompassing even more physics and solution reliability.

  20. Encounters of binaries

    International Nuclear Information System (INIS)

    Numerical integrations of encounters of pairs of binaries have been used to study the class of interactions, called fly-bys, in which the two-binary configuration survives. It is shown that these typically weak interactions can be treated by means of a first-order perturbation theory. A simple simulation model for obtaining the energy transfer rate between various degrees of freedom has been constructed. The model was employed to estimate the additional energy transfer arising from impact parameters larger than those used in the numerical experiments. In the hard binary limit the total energy transfer caused by binary-binary encounters is dominated by the collisional interactions in which the two-binary configuration is destroyed. (author)

  1. Miscibility and interactions in chitosan acetate/poly(N-vinylpyrrolidone) blends

    International Nuclear Information System (INIS)

    Graphical abstract: In the present study, the blends of chitosan (Ch) and poly(vinylpyrrolidone) (PVP) were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), Fourier transform infrared spectroscopy (FTIR) and wide angle X-ray diffraction (WAXD). Research highlights: → The purpose of paper was the evaluation of the miscibility PVP with chitosan. → The thermal properties, WAXD and FTIR analysis were investigated. → The influence of molecular weight on the properties blends has been discussed. → The results reported in this paper provide an indication that blends are poor miscible. - Abstract: In the present study, the blends of chitosan (Ch) and poly(N-vinylpyrrolidone) (PVP) were investigated by differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), Fourier transform infrared spectroscopy (FTIR) and wide angle X-ray diffraction (WAXD). WAXD patterns of homopolymers and their blends indicated that blending of amorphous materials, such as PVP, with semicrystalline polymer, such as chitosan gives rise to an amorphous structure. From thermal curves the glass transitions temperature have been determined and compared. The thermal results indicated that in the solid ChA/PVP blends the components are poorly miscible. The FTIR spectra of film blends, in the carbonyl stretching region of PVP and the hydroxyl stretching bands of chitosan have been analyzed. The observed shift of these bands and the change of their shape depends on (I) the blend composition, on (II) the chemical structure of chitosan {chitosan in its amine form (Ch) or chitosan acetate (ChA)}, and on (III) the molecular weight of PVP, whereas the influence of temperature in the range of 298-403 K seems to be negligible.

  2. NUMERICAL METHODS FOR MISCIBLE DISPLACEMENT IN POROUS MEDIA INFLUENCED BY MOBILE WATER AND IMMOBILE WATER

    Institute of Scientific and Technical Information of China (English)

    崔明; 梁栋

    2002-01-01

    The numerical methods for miscible displacment in aggregated or sorbing medium areconsidered. A mixed finite element method is adopted for the pressure equation. The concentra-tion in the mobile water is approximated by a combination of a Galerkin finite element method andthe method of characteristics and the concentration in immobile water is approximated by a stan-dard Galerkin method. The moving mesh technique which depends on time t is adopted here. Themoving meshes can vary in different spacial domains with different variable times. Optima errorestimates in energy norm and L2 norm are obtained under certain constraints.

  3. Video of Miscible Fluid Experiment Conducted on NASA Low Gravity Airplane

    Science.gov (United States)

    2003-01-01

    This is a video of dyed water being injected into glycerin in a 2.2 centimeter (cm) diameter test tube. The experiment was conducted on the KC-135 aircraft, a NASA plane that creates microgravity and 2g conditions as it maneuvers through multiple parabolas. The water is less dense and so it rises to the top of the glycerin. The goal of the experiment was to determine if a blob of a miscible fluid would spontaneously become spherical in a microgravity environment.

  4. Flash Point Measurements and Modeling for Ternary Partially Miscible Aqueous­Organic Mixtures

    OpenAIRE

    Liaw, Horng-Jang; Gerbaud, Vincent; Wu, Hsuan-Ta

    2010-01-01

    Flash point is the most important variable used to characterize the fire and explosion hazard of liquids. This paper presents the first partially miscible aqueousorganic mixtures flash point measurements and modeling for the ternary type-I mixtures, water + ethanol + 1-butanol, water + ethanol + 2-butanol, and the type-II mixture, water + 1-butanol + 2-butanol. Results reveal that the flash points are constant in each tie line. Handling the non-ideality of the liquid phase through the use of...

  5. Low-Temperature Miscibility of Ethanol-Gasoline-Water Blends in Flex Fuel Applications

    DEFF Research Database (Denmark)

    Johansen, T.; Schramm, Jesper

    2009-01-01

    The miscibility of blends of gasoline and hydrous ethanol was investigated experimentally at - 25 degrees C and - 2 degrees C. Furthermore, the maximum water content was found for ethanol in flex fuel blends. The results strongly indicate that blends containing ethanol with a water content above...... that of the ethanol/water azeotrope (4.4% water by mass) can be used as Flex Fuel blends together with gasoline at ambient temperatures of 25 degrees C and 2 degrees C, without phase separation occurring. Additionally, it was shown that the ethanol purity requirement of ethanol-rich flex fuel blends...... falls with increasing ethanol content in the gasoline-rich flex fuel blend....

  6. Miscibility and Molecular Orientation of Carbazole in Mixed Langmuir and Langrnuir-Blodgett Films

    Institute of Scientific and Technical Information of China (English)

    Md. N. Islam; D. Bhattacharjee; S. A. Hussain

    2007-01-01

    We report the miscibility and molecular orientation of carbazole (CA) molecules in the mixed Langmuir and Langmuir-Blodgett (LB) films of CA in polymethyl methacrylate (PMMA) and stearic acid (SA) matrices. The r-A isotherm confirms the formation of stable Langmuir films of CA mixed with either PMMA or SA at airwater interface. Characteristics of area per molecule versus molefraction and collapse pressure versus molefraction reveal complete demixing of CA and the matrix PMMA/SA molecules in the mixed films. Absorption spectroscopy certainly confirms the fact that CA molecules have preferred orientation on the substrate of the LB films.

  7. Dark-dark solitons and modulational instability in miscible two-component Bose-Einstein condensates

    Energy Technology Data Exchange (ETDEWEB)

    Hoefer, M. A. [North Carolina State University, Department of Mathematics, Raleigh, North Carolina 27695 (United States); Chang, J. J.; Hamner, C.; Engels, P. [Washington State University, Department of Physics and Astronomy, Pullman, Washington 99164 (United States)

    2011-10-15

    We investigate the dynamics of two miscible superfluids experiencing fast counterflow in a narrow channel. The superfluids are formed by two distinguishable components of a trapped dilute-gas Bose-Einstein condensate (BEC). The onset of counterflow-induced modulational instability throughout the cloud is observed and shown to lead to the proliferation of dark-dark vector solitons. These solitons do not exist in single-component systems, exhibit intriguing beating dynamics, and can experience a transverse instability leading to vortex line structures. Experimental results and multidimensional numerical simulations are presented.

  8. Interacting binary stars

    CERN Document Server

    Sahade, Jorge; Ter Haar, D

    1978-01-01

    Interacting Binary Stars deals with the development, ideas, and problems in the study of interacting binary stars. The book consolidates the information that is scattered over many publications and papers and gives an account of important discoveries with relevant historical background. Chapters are devoted to the presentation and discussion of the different facets of the field, such as historical account of the development in the field of study of binary stars; the Roche equipotential surfaces; methods and techniques in space astronomy; and enumeration of binary star systems that are studied

  9. Dissipative particle dynamics simulation study on the binary mixture phase separation coupled with polymerization.

    Science.gov (United States)

    Liu, Hong; Qian, Hu-Jun; Zhao, Ying; Lu, Zhong-Yuan

    2007-10-14

    The influence of polymerization on the phase separation of binary immiscible mixtures has been investigated by the dissipative particle dynamics simulations in two dimensions. During polymerization, the bulk viscosity increases, which consequently slows down the spinodal decomposition process. The domain size growth is monitored in the simulations. The absence of 23 exponent for inertial hydrodynamic mechanism clearly reflects the suppressing effect of polymerization on the phase separation. Due to the increasing viscosity, the individual phase may be trapped in a metastable stage instead of the lamellar morphology identified for symmetric mixtures. Moreover, the polymerization induced phase separation in the binary miscible mixture has been studied. The domain growth is strongly dependent on the polymerization probability, which is naturally related to the activation energy for polymerization. The observed complex phase separation behavior is attributed to the interplay between the increasing thermodynamic driving force for phase separation and the increasing viscosity that suppresses phase separation as the polymerization proceeds. PMID:17935435

  10. DSC study of phase transitions of cephalin pseudo-binary systems in excess water

    Institute of Scientific and Technical Information of China (English)

    王邦宁; 谈夫

    1999-01-01

    The gel-liquid crystal phase transitions of the pseudo-binary systems of cephalins DMPE and DHPE in excess water were studied by differential scanning calorimetry. The phase diagram of the pseudo-binary systems has been given. The experiments showed that the partial phase separation in gel phase might occur at least at the mole fractions of DHPE below 0.1. The analysis by the model of ideal solution showed that both the cephalins were non-ideally miscible both in the gel phases and in the liquid crystal phases. The analysis by the model of regular solution showed that all the non-ideality parameters in the gel phases were larger than those in the liquid crystal phases at the same temperature. All the non-ideality parameters were not constant, but rather dependent on temperature.

  11. Binary breath figures for straightforward and controllable self-assembly of microspherical caps.

    Science.gov (United States)

    Gong, Jianliang; Xu, Bingang; Tao, Xiaoming; Li, Lei

    2016-05-11

    The intense interest surrounding asymmetrical microparticles originates from their unique anisotropic properties and promising applications. In this work, direct self-assembly of polymeric microspherical caps without the assistance of any additives has been achieved by using low-surface-tension methanol (MeOH) and high-surface-tension water as binary breath figures (BFs). With the evaporation of polystyrene (PS) solution containing low-boiling-point solvent in the binary vapors, the formed MeOH BFs could quickly diffuse into solution, while water BFs tended to remain at the solution surface. This led to the formation of a gradient nonsolvent layer at the vapor/solution interface, which induced the formation of nuclei and guided further asymmetrical growth of polymer particles. After the spontaneous removal of MeOH, water and residual solvent by evaporation, polymeric microspherical caps were left on the substrate. Through controlling the proportion of water introduced by adjusting the ratios of MeOH and water, polymeric microspherical caps with a range of controllable shapes (divided at different positions of a sphere) were successfully obtained. The formation mechanism was explained based on the difference of vapor pressure, surface tension and miscibility between the employed solvents and nonsolvents. A solvent possessing a high vapor pressure, low surface tension and good miscibility with MeOH contributed to the formation of microspherical caps. This flexible, green and straightforward technique is a nondestructive strategy, and avoids complicated work on design, preparation and removal of hard templates and additives. PMID:27139817

  12. Aggregation properties of tetrachloroperylene-tetracarboxylic acid in binary Langmuir and Langmuir–Blodgett films

    International Nuclear Information System (INIS)

    The Langmuir and Langmuir–Blodgett films formed of tetra-n-butyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylate and its binary mixtures with 4-octyl-4′-cyanobiphenyl and arachidic acid have been studied. The Langmuir films were characterized by surface pressure versus mean molecular area isotherms and the films morphology observations were made by means of a Brewster angle microscope. The miscibility of the compounds was determined. Subsequently, the Langmuir films were transferred onto hydrophilic quartz substrates forming the monolayer Langmuir–Blodgett films. The electronic absorption and fluorescence spectra reveal aggregation of the chromophores in ground state driven by π–π molecular orbitals interactions. Perylene-like dye aggregation depends upon the dye concentration in the dye/liquid crystal mixed films and is concentration-independent in dye/arachidic acid one. -- Highlights: • A new perylene derivative with four chlorine atoms in the core was synthetized. • Langmuir films of pure dye and its binary mixtures were studied thermodynamically. • The miscibility of the components in the films changes the π–π stacking of the dye. • We describe the dye aggregation in the pure and mixed films deposited onto quartz

  13. Aggregation properties of tetrachloroperylene-tetracarboxylic acid in binary Langmuir and Langmuir–Blodgett films

    Energy Technology Data Exchange (ETDEWEB)

    Modlińska, Anna; Piosik, Emilia [Faculty of Technical Physics, Poznan University of Technology, Poznan (Poland); Paluszkiewicz, Joanna [Institute of Polymers and Dyes Technology, Lodz University of Technology, Lodz (Poland); Martyński, Tomasz, E-mail: tomasz.martynski@put.poznan.pl [Faculty of Technical Physics, Poznan University of Technology, Poznan (Poland)

    2014-04-15

    The Langmuir and Langmuir–Blodgett films formed of tetra-n-butyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxylate and its binary mixtures with 4-octyl-4′-cyanobiphenyl and arachidic acid have been studied. The Langmuir films were characterized by surface pressure versus mean molecular area isotherms and the films morphology observations were made by means of a Brewster angle microscope. The miscibility of the compounds was determined. Subsequently, the Langmuir films were transferred onto hydrophilic quartz substrates forming the monolayer Langmuir–Blodgett films. The electronic absorption and fluorescence spectra reveal aggregation of the chromophores in ground state driven by π–π molecular orbitals interactions. Perylene-like dye aggregation depends upon the dye concentration in the dye/liquid crystal mixed films and is concentration-independent in dye/arachidic acid one. -- Highlights: • A new perylene derivative with four chlorine atoms in the core was synthetized. • Langmuir films of pure dye and its binary mixtures were studied thermodynamically. • The miscibility of the components in the films changes the π–π stacking of the dye. • We describe the dye aggregation in the pure and mixed films deposited onto quartz.

  14. Miscibility and Hydrogen Bonding in Blends of Poly(4-vinylphenol/Poly(vinyl methyl ketone

    Directory of Open Access Journals (Sweden)

    Hana Bourara

    2014-10-01

    Full Text Available The miscibility and phase behavior of poly(4-vinylphenol (PVPh with poly(vinyl methyl ketone (PVMK was investigated by differential scanning calorimetry (DSC, Fourier transform infrared spectroscopy (FTIR and scanning electron microscopy (SEM. It was shown that all blends of PVPh/PVMK are totally miscible. A DSC study showed the apparition of a single glass transition (Tg over their entire composition range. When the amount of PVPh exceeds 50% in blends, the obtained Tgs are found to be significantly higher than those observed for each individual component of the mixture, indicating that these blends are capable of forming interpolymer complexes. FTIR analysis revealed the existence of preferential specific interactions via hydrogen bonding between the hydroxyl and carbonyl groups, which intensified when the amount of PVPh was increased in blends. Furthermore, the quantitative FTIR study carried out for PVPh/PVMK blends was also performed for the vinylphenol (VPh and vinyl methyl ketone (VMK functional groups. These results were also established by scanning electron microscopy study (SEM.

  15. Effects of sweep rates of external magnetic fields on the labyrinthine instabilities of miscible magnetic fluids

    Science.gov (United States)

    Wen, C.-Y.; Lin, J.-Z.; Chen, M.-Y.; Chen, L.-Q.; Liang, T.-K.

    2011-05-01

    The interfacial instability of miscible magnetic fluids in a Hele-Shaw Cell is studied experimentally, with different magnitudes and sweep rates of the external magnetic field. The initial circular oil-based magnetic fluid drop is surrounded by the miscible fluid, diesel. The external uniform magnetic fields induce small fingerings around the initial circular interface, so call labyrinthine fingering instability, and secondary waves. When the magnetic field is applied at a given sweep rate, the interfacial length grows significantly at the early stage. It then decreases when the magnetic field reaches the preset values, and finally approaches a certain asymptotic value. In addition, a dimensionless parameter, Pe, which includes the factors of diffusion and sweep rate of the external magnetic field, is found to correlate the experimental data. It is shown that the initial growth rate of the interfacial length is linearly proportional to Pe for the current experimental parameter range and is proportional to the square root of the sweep rate at the onset of labyrinthine instability.

  16. Schlieren Imaging of Gravitational Instabilities during Miscible Viscous Fingering of Glycerol-Water Systems

    Science.gov (United States)

    Marin, Daniela; Stewart, Simone; Bunton, Patrick; Meiburg, Eckart; de Wit, Anne

    2015-11-01

    Viscous fingering occurs when a lower viscosity fluid displaces a higher viscosity fluid causing interfacial instabilities creating finger-like patterns. In a typical flow, the less viscous fluid is injected into the higher viscous fluid that is between the plates of a Hele-Shaw cell. In most cases for transparent flows, dye is dissolved into the displacing fluid in order to observe it. This work uses Schlieren imaging of miscible fluid displacements in a horizontal Hele-Shaw Cell, which reveals new information about the three-dimensional nature of VF. A Schlieren system is composed of a parallel light beam, a lens that brings the light to a focus, a cutoff of some type, and a camera. Schlieren does not require dye, ensuring the natural flow of the fluids is undisturbed. Here the imaging system is described followed by results of miscible flows of water in to aqueous glycerol solutions. Structures attributable to three-dimensional buoyancy-driven flows are readily observed. These results are interpreted in light of recent three-dimensional calculations. Supported by National Science Foundation CBET-1335739.

  17. The role of solvent and morphology on miscibility of methanofullerene and poly(3-hexylthiophene)

    International Nuclear Information System (INIS)

    A bicontinuous, percolating bulk heterojunction morphology is integral to organic polymer solar cells. Understanding the factors affecting the miscibility of photovoltaic polymers with a fullerene electron acceptor molecule is a key to controlling the morphology. Starting from discreet pure phases – a poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) bilayer film – the evolution of the P3HT–PCBM interface was studied with particular attention to the role of residual solvent in P3HT on PCBM interdiffusion. This investigation shows that in the bilayer geometry PCBM can rapidly diffuse into amorphous P3HT, but phase separation is maintained if the P3HT layer is cast from a very volatile solvent or if it is annealed prior to casting the PCBM overlayer to complete the bilayer geometry. - Highlights: ► We examine miscibility of P3HT with a fullerene molecule PCBM. ► Amorphous polymer morphology enhances interdiffusion. ► Annealed bilayer is subjected to large phase-separation if PCBM is cast on dry P3HT. ► Phase-separated PCBM clusters extend throughout the bilayer film.

  18. Development of a method for evaluating carbon dioxide miscible flooding prospects. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Green, D.W.; Swift, G.W.

    1985-03-01

    Research was undertaken to develop a method of evaluating reservoirs as prospects for carbon dioxide flooding. Evaluation was to be based on a determination of miscibility pressure and displacement efficiency under idealized conditions. To reach the objective, project work was divided into five areas: (1) conducting of phase-equilibrium studies of carbon dioxide with synthetic oils; (2) application of an equation of state to simulate the phase behavior of carbon dioxide - oil systems; (3) conducting of linear displacements of crude oils and synthetic oils by carbon dioxide in a slim-tube apparatus; (4) application of the equation of state, the phase-behavior data and slim-tube data to develop a method of screening reservoirs for carbon dioxide flooding based on determination of minimum miscibility pressure and displacement efficiency; (5) development of a one-dimensional mathematical model, based on the equation of state, for application in conjunction with the results of Parts 1 to 4. The accomplishments for these five areas are discussed in five chapters. 44 references, 90 figures, 42 tables.

  19. Buoyancy driven mixing of miscible fluids by volumetric energy deposition of microwaves.

    Science.gov (United States)

    Wachtor, Adam J; Mocko, Veronika; Williams, Darrick J; Goertz, Matthew P; Jebrail, Farzaneh F

    2013-01-01

    An experiment that seeks to investigate buoyancy driven mixing of miscible fluids by microwave volumetric energy deposition is presented. The experiment involves the use of a light, non-polar fluid that initially rests on top of a heavier fluid which is more polar. Microwaves preferentially heat the polar fluid, and its density decreases due to thermal expansion. As the microwave heating continues, the density of the lower fluid eventually becomes less than that of the upper, and buoyancy driven Rayleigh-Taylor mixing ensues. The choice of fluids is crucial to the success of the experiment, and a description is given of numerous fluid combinations considered and characterized. After careful consideration, the miscible pair of toluene/tetrahydrofuran (THF) was determined as having the best potential for successful volumetric energy deposition buoyancy driven mixing. Various single fluid calibration experiments were performed to facilitate the development of a heating theory. Thereafter, results from two-fluid mixing experiments are presented that demonstrate the capability of this novel Rayleigh-Taylor driven experiment. Particular interest is paid to the onset of buoyancy driven mixing and unusual aspects of the experiment in the context of typical Rayleigh-Taylor driven mixing. PMID:24779141

  20. Miscibility and mechanical properties for blends of sulfonated polystyrene with polyurethane

    Energy Technology Data Exchange (ETDEWEB)

    Shen Jiarui; Yong Wei; Zhu Shuihan [South China Univ. of Technology, Guangzhou (China)

    1996-10-01

    In this paper, the structure and mechanical properties for blends of sulfonated polystyrene with polyurethane containing a tertiary amine group were investigated. Dynamic mechanical results show that the miscibility of blends is improved distinctly due to ion-ion interaction. MDSC studies indicate that the miscibility as well as soft segment purity of blends enhances with the increase of SO{sub 3}H group content in SPS. The stress-strain curve of SPS/PU (50/50) blend shows the cold-drawing behavior. The synergism of tensile strength occurs in whole range of composition. There is a maximum value around 50 wt% content of SPS (the equivalent point of functional group). The tensile strength of SPS/PU (30/70) enhances with the SO{sub 3}H group content increasing and the elongation decreases up to 4.8 mol%, then levels off. It is due to the increase of ionic crosslinking density caused by ion interaction and the formation of cluster in SPS.

  1. Stability of viscosity stratified flows down an incline: Role of miscibility and wall slip

    CERN Document Server

    Ghosh, Sukhendu

    2016-01-01

    The effects of wall velocity slip on the linear stability of a gravity-driven miscible two-fluid flow down an incline are examined. The fluids have the matched density but different viscosity. A smooth viscosity stratification is achieved due to the presence of a thin mixed layer between the fluids. The results show that the presence of slip exhibits a promise for stabilizing the miscible flow system by raising the critical Reynolds number at the onset and decreasing the bandwidth of unstable wave numbers beyond the threshold of the dominant instability. This is different from its role in the case of a single fluid down a slippery substrate where slip destabilizes the flow system at the onset. Though the stability properties are analogous to the same flow system down a rigid substrate, slip is shown to delay the surface mode instability for any viscosity contrast. It has a damping/promoting effect on the overlap modes (which exist due to the overlap of critical layer of dominant disturbance with the mixed lay...

  2. MISCIBILITY, THERMAL STABILITY AND RETENTION OF PVP FOR CROSSLINKED PVA/PVP BLENDS

    Institute of Scientific and Technical Information of China (English)

    LIANG Guomei; ZHANG Kun; FENG Rongyin

    1994-01-01

    The thermal behavior, miscibility, crystallite conformation and thermal stability of crosslinked(CL-) PVA/PVP blends were studied by DSC and TG methods, respectively. DSC results showed that in the blend, the crystallinity,Tm and Tc of PVA were obviously lower than those of pure PVA; the crystal growth changed from three dimensional to two dimensional and only a single Tg was detected . These facts demonstrated that this crystalline and amorphous blend have good miscibility. TG curves showed that providing the quantity of K2S2O8 added is more than 3 wt % ,in the blends PVA will form a stable CL-network, whose thermal degradation temperature was near to that of PVP. But crosslinking reaction will not take place for PVP. The processes of thermal degradation of CL-blends are based on combining both the thermal degradation of PVP and that of PVA crosslinked with corresponding quantity of K2S2O8 CL-agent, respectively.The UV measurements showed that 75 wt% of PVP may be remained in CL-blend hydrogels crosslinked by adding (3- 5 wt % )K2S2O8.This is mainly due to the stable CL-network formed and the good compatibility and proper entanglement between the composites in the CL-blends.

  3. Compositional and Relative Permeability Hysteresis Effects on Near-Miscible WAG

    DEFF Research Database (Denmark)

    Christensen, Jes Reimer; Stenby, Erling Halfdan; Skauge, Arne

    Evaluation of compositional effects and fluid flow description on near-miscible (water-alternating-gas) WAG modeling have been studied for a North Sea oil field starting production in 1998. A sector model with four wells was applied to simulate a heterogeneous sandstone reservoir, and a compositi......Evaluation of compositional effects and fluid flow description on near-miscible (water-alternating-gas) WAG modeling have been studied for a North Sea oil field starting production in 1998. A sector model with four wells was applied to simulate a heterogeneous sandstone reservoir, and a...... injection gases. Result obtained shows the WAG injection gives improved recovery compared to water injection, due to better sweep and lower residual oil saturation. Simulations with and without relative permeability hysteresis (two-phase model) were compared. The effect of trapped gas on oil recovery does...... not seem significant with the compositional model. The WAG process has been optimized with respect to slug size and the water-gas ratio. A black-oil-model was generated tuned to fit the results from the compositional simulations. A WAG three-phase relative permeability hysteresis model using cycle...

  4. Real-scale miscible grout injection experiment and performance of advection-dispersion-filtration model

    Science.gov (United States)

    Bouchelaghem, F.; Vulliet, L.; Leroy, D.; Laloui, L.; Descoeudres, F.

    2001-10-01

    A model was developed, to describe miscible grout propagation in a saturated deformable porous medium, based on Bear's statistical model with spatial volume averaging. In a previous paper, the model was first successfully confronted to one-dimensional laboratory experiments.In the present paper, the numerical model is used to simulate practical grouting operation in a cylindrical injection model. The cylindrical injection model lends itself to study main flow and propagation character istics for a dispersed suspension-type grout, under axisymmetric conditions close to real scale conditions.Comparison between numerical solutions and experimental results is essential to confirm the validity and accuracy of the proposed model from a phenomenological standpoint. The numerical model performances show that the underlying mathematical model constitutes a realistic predictive model reproducing most prominent features during injection of a suspension-type grout into a deformable porous medium. The basic mechanism by which injected miscible grout permeates a soil mass is discussed in detail. Such a tool leads to quality control criteria for grouting on a theoretical basis, which complements existing criteria acquired through engineering practice.

  5. Mathematical and numerical filtration-advection-dispersion model of miscible grout propagation in saturated porous media

    Science.gov (United States)

    Bouchelaghem, F.; Vulliet, L.

    2001-10-01

    The development of a predictive model of behaviour of porous media during injection of miscible grout, taking into account convection, dilution and filtration of grout solution with interstitial water, as well as consolidation aspects, is presented. Model assumptions are reviewed and discussed first. During the establishment of the model, we insist on surface terms and their physical relevance in expressing adsorption effects. Constitutive laws such as Fick's law for diffusive mass transport, hydrodynamic dispersion tensor dealing with miscibility, are modified by taking into account filtration effects. A new surface term appears in mass balance equations as a consequence of filtration. According to the filtration laws used, an initial filtration rate is estimated on the basis of a one-dimensional experimental campaign. The field equations are discretized by using Galerkin finite element and -scheme standard method. For transport equation, Streamline Upwind Petrov Galerkin method is employed to prevent numerical oscillations. Lastly, confrontation of numerical results with laboratory experiments constitutes a first step to validate the model on a realistic basis.

  6. Nanoparticle induced miscibility in LCST polymer blends: critically assessing the enthalpic and entropic effects.

    Science.gov (United States)

    Xavier, Priti; Rao, Praveen; Bose, Suryasarathi

    2016-01-01

    The use of copolymer and polymer blends widened the possibility of creating materials with multilayered architectures. Hierarchical polymer systems with a wide array of micro and nanostructures are generated by thermally induced phase separation (TIPS) in partially miscible polymer blends. Various parameters like the interaction between the polymers, concentration, solvent/non-solvent ratio, and quenching temperature have to be optimized to obtain these micro/nanophase structures. Alternatively, the addition of nanoparticles is another strategy to design materials with desired hetero-phase structures. The dynamics of the polymer nanocomposite depends on the statistical ordering of polymers around the nanoparticle, which is dependent on the shape of the nanoparticle. The entropic loss due to deformation of polymer chains, like the repulsive interactions due to coiling and the attractive interactions in the case of swelling has been highlighted in this perspective article. The dissipative particle dynamics has been discussed and is correlated with the molecular dynamics simulation in the case of polymer blends. The Cahn-Hillard-Cook model on variedly shaped immobile fillers has shown difference in the propagation of the composition wave. The nanoparticle shape has a contributing effect on the polymer particle interaction, which can change the miscibility window in the case of these phase separating polymer blends. Quantitative information on the effect of spherical particles on the demixing temperature is well established and further modified to explain the percolation of rod shaped particles in the polymer blends. These models correlate well with the experimental observations in context to the dynamics induced by the nanoparticle in the demixing behavior of the polymer blend. The miscibility of the LCST polymer blend depends on the enthalpic factors like the specific interaction between the components, and the solubility product and the entropic losses occurring due

  7. A Simple Analytical Model for Gaps in Protoplanetary Disks

    CERN Document Server

    Duffell, Paul C

    2015-01-01

    An analytical model is presented for calculating the surface density as a function of radius $\\Sigma(r)$ in protoplanetary disks in which a planet has opened a gap. This model is also applicable to circumbinary disks with extreme binary mass ratios. The gap profile can be solved for algebraically, without performing any numerical integrals. In contrast with previous one-dimensional gap models, this model correctly predicts that low-mass (sub-Jupiter) planets can open gaps in sufficiently low-viscosity disks, and it correctly recovers the power-law dependence of gap depth on planet-to-star mass ratio $q$, disk aspect ratio $h/r$, and dimensionless viscosity $\\alpha$ found in previous numerical studies. Analytical gap profiles are compared with numerical calculations over a range of parameter space in $q$, $h/r$, and $\\alpha$, demonstrating accurate reproduction of the "partial gap" regime, and general agreement over a wide range of parameter space.

  8. Thermodynamic assessment of the Fe-Hf binary system

    International Nuclear Information System (INIS)

    The Fe-Hf system was critically assessed by means of the Calphad approach. The solution phases (liquid, BCC, FCC and HCP) were described with the sublattice formalism and the excess model with the Redlich-Kister equation by imposing additional constraints to avoid the appearance of unwanted inverted miscibility gap in the liquid phase during the phase diagram calculation up to 6000 K. The λ sub-stoichiometric intermetallic compound, which melts congruently and has an homogeneity range, was treated as the usual C14 Laves phases, with the formula (Fe)0.6667(Hf,Fe)0.3333, by a two-sublattice model with Fe alone in the first sublattice and Fe and Hf in the second one. The others polytypes Fe2HfHT, Fe2HfLT as well as FeHf2 were treated as stoichiometric compounds. The calculated phase diagram and thermodynamic properties are in good agreement with the experimental data

  9. The Miscibility and Depth Profile of PCBM in P3HT: Thermodynamic Information to Improve Organic Photovoltaics

    Energy Technology Data Exchange (ETDEWEB)

    Dadmun, Mark D [ORNL

    2012-01-01

    Recent work has shown that poly(3-hexylthiophene) (P3HT) and the surface functionalized fullerene 1-(3-methyloxycarbonyl)propy(1-phenyl [6,6]) C61 (PCBM) are much more miscible than originally thought, and the evidence of this miscibility requires a return to understanding the optimal morphology and structure of organic photovoltaic active layers. This manuscript describes the results of experiments that were designed to provide quantitative thermodynamic information on the miscibility, interdiffusion, and depth profile of P3HT:PCBM thin films that are formed by thermally annealing initial bilayers. It is found that the resultant thin films consist of a bulk layer that is not influenced by the air or substrate surface. The composition of PCBM in this bulk layer increases with increased PCBM loading in the original bilayer until the bulk layer contains 22 vol% PCBM. The introduction of additional PCBM into the sample does not increase the amount of PCBM dispersed in this bulk layer. This observation is interpreted to indicate that the miscibility limit of PCBM in P3HT is 22 vol%, while the precise characterization of the depth profiles in these films shows that the PCBM selectively segregates to the silicon and near air surface. The selective segregation of the PCBM near the air surface is ascribed to an entropic driving force.

  10. Molecular dynamics simulation of a binary mixture near the lower critical point

    Science.gov (United States)

    Pousaneh, Faezeh; Edholm, Olle; Maciołek, Anna

    2016-07-01

    2,6-lutidine molecules mix with water at high and low temperatures but in a wide intermediate temperature range a 2,6-lutidine/water mixture exhibits a miscibility gap. We constructed and validated an atomistic model for 2,6-lutidine and performed molecular dynamics simulations of 2,6-lutidine/water mixture at different temperatures. We determined the part of demixing curve with the lower critical point. The lower critical point extracted from our data is located close to the experimental one. The estimates for critical exponents obtained from our simulations are in a good agreement with the values corresponding to the 3D Ising universality class.

  11. Between the Gap

    OpenAIRE

    McDevitt, Mary Jean

    2009-01-01

    The reveal is an important architectural element. In many buildings, reveals define transitions between dissimilar materials, textures, finishes or planes. A reveal can also be thought of as a gap. Webster's dictionary defines a gap as "an opening made by breaking or parting." Often the word "gap" is associated with a deficiency or failure, but a gap similar to a reveal, can be intentional and essential to the success of a building. The visually impaired experience a "gap" with the sight...

  12. The binary proletariat

    OpenAIRE

    Bolt, Nate

    2000-01-01

    In the endless quest to transform itself, capitalism has spawned a new working class. The proletariat was an essential product of the industrial revolution, and the lighter, more efficient capitalism of the digital revolution has created the Binary Proletariat.

  13. Optimal Control of Partially Miscible Two-Phase Flow with Applications to Subsurface CO2 Sequestration

    KAUST Repository

    Simon, Moritz

    2013-01-01

    Motivated by applications in subsurface CO2 sequestration, we investigate constrained optimal control problems with partially miscible two-phase flow in porous media. The objective is, e.g., to maximize the amount of trapped CO2 in an underground reservoir after a fixed period of CO2 injection, where the time-dependent injection rates in multiple wells are used as control parameters. We describe the governing two-phase two-component Darcy flow PDE system and formulate the optimal control problem. For the discretization we use a variant of the BOX method, a locally conservative control-volume FE method. The timestep-wise Lagrangian of the control problem is implemented as a functional in the PDE toolbox Sundance, which is part of the HPC software Trilinos. The resulting MPI parallelized Sundance state and adjoint solvers are linked to the interior point optimization package IPOPT. Finally, we present some numerical results in a heterogeneous model reservoir.

  14. Acousto-optic method used to control water pollution by miscible liquids

    Science.gov (United States)

    Ferria, Kouider; Griani, Lazhar; Laouar, Naamane

    2012-05-01

    An acousto-optic (A.O.) method has been developed for controlling the quality of water mixed by miscible liquids like acetone or ethanol… The liquid mixture is filled in a rectangular glass cell, which is placed orthogonally to the incident collimated beam of light. This cell consists of a piezoelectric transducer for generating ultrasonic waves. The collimated light while passing through this cell undergoes a diffraction phenomenon. The diffracted dots are collected by a converging photographic objective and displayed in its back focal plane. The location of the diffracted dots and their intensity are sensitive to any variation of the interaction medium. This result leads to decide about the quality of the water.

  15. Upwind finite difference method for miscible oil and water displacement problem with moving boundary values

    Institute of Scientific and Technical Information of China (English)

    Yi-rang YUAN; Chang-feng LI; Cheng-shun YANG; Yu-ji HAN

    2009-01-01

    The research of the miscible oil and water displacement problem with moving boundary values is of great value to the history of oil-gas transport and accumulation in the basin evolution as well as to the rational evaluation in prospecting and exploiting oil-gas resources. The mathematical model can be described as a coupled system of nonlinear partial differential equations with moving boundary values. For the two-dimensional bounded region, the upwind finite difference schemes are proposed. Some techniques, such as the calculus of variations, the change of variables, and the theory of a priori estimates, are used. The optimal order l2-norm estimates are derived for the errors in the approximate solutions. The research is important both theoretically and practically for the model analysis in the field, the model numerical method, and the software development.

  16. Buoyancy-driven instabilities around miscible A+B→C reaction fronts: a general classification.

    Science.gov (United States)

    Trevelyan, P M J; Almarcha, C; De Wit, A

    2015-02-01

    Upon contact between miscible solutions of reactants A and B along a horizontal interface in the gravity field, various buoyancy-driven instabilities can develop when an A+B→C reaction takes place and the density varies with the concentrations of the various chemicals. To classify the possible convective instability scenarios, we analyze the spatial dependence of the large time asymptotic density profiles as a function of the key parameters of the problem, which are the ratios of diffusion coefficients and of solutal expansion coefficients of species A, B, and C. We find that 62 different density profiles can develop in the reactive problem, whereas only 6 of them can be obtained in the nonreactive one. PMID:25768591

  17. Miscible Organic Solvents Soak Bonding Method Use in a PMMA Multilayer Microfluidic Device

    Directory of Open Access Journals (Sweden)

    He Zhang

    2014-12-01

    Full Text Available In this paper, we proposed a novel bonding technology to fabricate a microfluidic device based on Poly(methyl methacrylate (PMMA. The method, which used chloroform and ethanol as miscible bonding solvent, can complete complex structures rapid assembly (10 min at 40°C. A bonding strength of 267.5 N/cm2 can be achieved, while the micro channel deformation was less than 7.26%. Then we utilized this method to produce a three layers micro mixer, which included a T-shaped inlet channel and six H-shaped mixing units. Numerical simulation indicated that, the well mixing length of the mixer was only about 6 mm when Re = 10. Finally, fluorescence microscopy was used to verify mixer performance. The method provided the potential for mass production of multilayer rigid polymer microfluidic devices.

  18. Dynamics, Miscibility, and Morphology in Polymer-Molecule Blends: The Impact of Chemical Functionality

    KAUST Repository

    Do, Khanh

    2015-10-22

    In the quest to improve the performance of organic bulk-heterojunction solar cells, many recent efforts have focused on developing molecular and polymer alternatives to commonly used fullerene acceptors. Here, molecular dynamics simulations are used to investigate polymer-molecule blends comprised of the polymer donor poly(3-hexylthiophene) (P3HT) with a series of acceptors based on trialkylsilylethynyl-substituted pentacene. A matrix of nine pentacene derivatives, consisting of systematic chemical variation both in the nature of the alkyl groups and electron-withdrawing moieties appended to the acene, is used to draw connections between the chemical structure of the acene acceptor and the nanoscale properties of the polymer-molecule blend. These connections include polymer and molecular diffusivity, donor-acceptor packing and interfacial (contact) area, and miscibility. The results point to the very significant role that seemingly modest changes in chemical structure play during the formation of polymer-molecule blend morphologies.

  19. STUDIES ON MISCIBILITY AND MORPHOLOGICAL FEATURES OF BLENDS OF LC COPOLYESTER AND PET

    Institute of Scientific and Technical Information of China (English)

    XIE Ping; CHEN Shouxi; SHEN Deyan; YING Xinfang; JIN Yongze; LU Daohui

    1988-01-01

    The morphology of a special blend system composed of liquid crystalline aromatic random copolyester (LCP) and semiflexible polyester PET over the whole composition range has been studied by means of polarized microscope, density measurement, DSC, FTIR and SEM. Based on the microscopic observation, it is found that under suitable mechanical mixing condition, LCP may be rather homogeneously dispersed in the PET matrix, with the middle composition range of the contents of LCP at 30-70 wt % the anisotropic and isotropic phase segregation appears. while with LCP contents over 80 wt% the blends exhibit wholly anisotropic. The DSC thermographs of the melt-pressed and quenched films show single Tg, Tcc and Tm. Tg increases with increasing content of LCP and ap. proaches to the Tg of pure LCP. The experimental results indicate that the two components of this blend system are miscible, there exist some specific interactions between them.

  20. Investigation of asphaltene precipitation in miscible gas injection processes: experimental study and modeling

    Directory of Open Access Journals (Sweden)

    S. Moradi

    2012-09-01

    Full Text Available Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate the effects of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples have been studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Extensive published data from the literature are also used in model development. The scaling approach is attractive because it is simple and complex asphaltene properties are not involved in the calculations. Moreover, the proposed model provides universal parameters for different fluid samples over a wide range of pressure and temperature that makes it novel for evaluation of future gas injection projects when simple PVT data are available.

  1. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    Energy Technology Data Exchange (ETDEWEB)

    Alan Byrnes; G. Paul Willhite; Don Green; Richard Pancake; JyunSyung Tsau; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2010-03-07

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide was injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide was injected to displace the oil bank to the production wells by water injection. By March 7,2010, 8,736 bbl of oil were produced from the pilot. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver A7, Colliver A3, Colliver A14 and Graham A4 located on adjacent leases. About 19,166 bbl of incremental oil were estimated to have been produced from these wells as of March 7, 2010. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Estimated oil recovery attributed to the CO2 flood is 27,902 bbl which is equivalent to a gross CO2 utilization of 4.8 MCF/bbl. The pilot project is not economic.

  2. Origin of Scale-Dependent Dispersivity and Its Implications For Miscible Gas Flooding

    Energy Technology Data Exchange (ETDEWEB)

    Steven Bryant; Russ Johns; Larry Lake; Thomas Harmon

    2008-09-30

    Dispersive mixing has an important impact on the effectiveness of miscible floods. Simulations routinely assume Fickian dispersion, yet it is well established that dispersivity depends on the scale of measurement. This is one of the main reasons that a satisfactory method for design of field-scale miscible displacement processes is still not available. The main objective of this project was to improve the understanding of the fundamental mechanisms of dispersion and mixing, particularly at the pore scale. To this end, microsensors were developed and used in the laboratory to measure directly the solute concentrations at the scale of individual pores; the origin of hydrodynamic dispersion was evaluated from first principles of laminar flow and diffusion at the grain scale in simple but geometrically completely defined porous media; techniques to use flow reversal to distinguish the contribution to dispersion of convective spreading from that of true mixing; and the field scale impact of permeability heterogeneity on hydrodynamic dispersion was evaluated numerically. This project solved a long-standing problem in solute transport in porous media by quantifying the physical basis for the scaling of dispersion coefficient with the 1.2 power of flow velocity. The researchers also demonstrated that flow reversal uniquely enables a crucial separation of irreversible and reversible contributions to mixing. The interpretation of laboratory and field experiments that include flow reversal provides important insight. Other advances include the miniaturization of long-lasting microprobes for in-situ, pore-scale measurement of tracers, and a scheme to account properly in a reservoir simulator (grid-block scale) for the contributions of convective spreading due to reservoir heterogeneity and of mixing.

  3. Magnetic Resonance Imaging Study on the Miscibility of a CO2/n-Decane System

    Institute of Scientific and Technical Information of China (English)

    SONG Yong-Chen; ZHU Ning-Jun; LIU Yu; ZHAO Jia-Fei; LIU Wei-Guo; ZHANG Yi; ZHAO Yue-Chao; JIANG Lan-Lan

    2011-01-01

    @@ We provide a feasible method to estimate the minimum miscibility pressure(MMP)of a CO2/n-decane system by using high spatial resolution magnetic resonance imaging(MRI).During the measurement,the signal intensity of n-decane with CO2 dissolved is measured.The MRI images show that the signal intensity of n-decane decreases to zero and the interface disappears at the MMP.A good exponential growth relation is found between the signal intensity and the pressure of the CO2/n-decane system.The relationship between the MMP and the temperature is established quantitatively,which is in close agreement with previous studies.Moreover it could be used to predict the MMP of the CO2/n-decane system.%We provide a feasible method to estimate the minimum miscibility pressure (MMP) of a CO2/n-decane system by using high spatial resolution magnetic resonance imaging (MRI). During the measurement, the signal intensity of n-decane with CO2 dissolved is measured. The MRI images show that the signal intensity of n-decane decreases to zero and the interface disappears at the MMP. A good exponential growth relation is found between the signal intensity and the pressure of the Coi/n-decane system. The relationship between the MMP and the temperature is established quantitatively, which is in close agreement with previous studies. Moreover it could be used to predict the MMP of the CO2/'n-decane system.

  4. Eclipsing Binary Pulsars

    CERN Document Server

    Freire, P C C

    2004-01-01

    The first eclipsing binary pulsar, PSR B1957+20, was discovered in 1987. Since then, 13 other eclipsing low-mass binary pulsars have been found, 12 of these are in globular clusters. In this paper we list the known eclipsing binary pulsars and their properties, with special attention to the eclipsing systems in 47 Tuc. We find that there are two fundamentally different groups of eclipsing binary pulsars; separated by their companion masses. The less massive systems (M_c ~ 0.02 M_sun) are a product of predictable stellar evolution in binary pulsars. The systems with more massive companions (M_c ~ 0.2 M_sun) were formed by exchange encounters in globular clusters, and for that reason are exclusive to those environments. This class of systems can be used to learn about the neutron star recycling fraction in the globular clusters actively forming pulsars. We suggest that most of these binary systems are undetectable at radio wavelengths.

  5. Binary Evolutionary Models

    CERN Document Server

    Han, Z

    2008-01-01

    In this talk, we present the general principles of binary evolution and give two examples. The first example is the formation of subdwarf B stars (sdBs) and their application to the long-standing problem of ultraviolet excess (also known as UV-upturn) in elliptical galaxies. The second is for the progenitors of type Ia supernovae (SNe Ia). We discuss the main binary interactions, i.e., stable Roche lobe overflow (RLOF) and common envelope (CE) evolution, and show evolutionary channels leading to the formation of various binary-related objects. In the first example, we show that the binary model of sdB stars of Han et al. (2002, 2003) can reproduce field sdB stars and their counterparts, extreme horizontal branch (EHB) stars, in globular clusters. By applying the binary model to the study of evolutionary population synthesis, we have obtained an ``a priori'' model for the UV-upturn of elliptical galaxies and showed that the UV-upturn is most likely resulted from binary interactions. This has major implications...

  6. Idea Gaps, Object Gaps, and Trust Gaps in Economic Development

    OpenAIRE

    Barrett, Christopher B.

    1995-01-01

    Growth theory emphasizes capital accumulation and technological change or, as Romer [1993] describes them, idea gaps and object gaps. This paper makes the case for a third and final crucial element: trust. Trust has both direct effects on the process of economic development, especially in facilitating increased exchange, and indirect effects through its influence on incentives to investment in human and physical capital (objects) and to the acquisition and processing of knowledge (ideas). Int...

  7. The prototype GAPS (pGAPS) experiment

    International Nuclear Information System (INIS)

    The General Antiparticle Spectrometer (GAPS) experiment is a novel approach for the detection of cosmic ray antiparticles. A prototype GAPS (pGAPS) experiment was successfully flown on a high-altitude balloon in June of 2012. The goals of the pGAPS experiment were: to test the operation of lithium drifted silicon (Si(Li)) detectors at balloon altitudes, to validate the thermal model and cooling concept needed for engineering of a full-size GAPS instrument, and to characterize cosmic ray and X-ray backgrounds. The instrument was launched from the Japan Aerospace Exploration Agency's (JAXA) Taiki Aerospace Research Field in Hokkaido, Japan. The flight lasted a total of 6 h, with over 3 h at float altitude (∼33km). Over one million cosmic ray triggers were recorded and all flight goals were met or exceeded

  8. Phenomenological gravitational waveforms from spinning coalescing binaries

    CERN Document Server

    Sturani, R; Cadonati, L; Guidi, G M; Healy, J; Shoemaker, D; Vicere', A

    2010-01-01

    An accurate knowledge of the coalescing binary gravitational waveform is crucial for match filtering techniques, which are currently used in the observational searches performed by the LIGO-Virgo collaboration. Following an earlier paper by the same authors we expose the construction of analytical phenomenological waveforms describing the signal sourced by generically spinning binary systems. The gap between the initial inspiral part of the waveform, described by spin-Taylor approximants, and its final ring-down part, described by damped exponentials, is bridged by a phenomenological phase calibrated by comparison with the dominant spherical harmonic mode of a set of waveforms including both numerical and phenomenological waveforms of a different type. All waveforms considered describe equal mass systems with dimension-less spin magnitudes equal to 0.6. The noise-weighted overlap integral between numerical and phenomenological waveforms ranges between 0.93 and 0.98 for a wide span of mass values.

  9. Miscibility, Crystallization, and Rheological Behavior of Solution Casting Poly(3-hydroxybutyrate)/poly(ethylene succinate) Blends Probed by Differential Scanning Calorimetry, Rheology, and Optical Microscope Techniques

    Science.gov (United States)

    Sun, Wei-hua; Qiao, Xiao-ping; Cao, Qi-kun; Liu, Jie-ping

    2010-02-01

    The miscibility and crystallization of solution casting biodegradable poly(3-hydroxybutyrate)/poly(ethylene succinate) (PHB/PES) blends was investigated by differential scanning calorimetry, rheology, and optical microscopy. The blends showed two glass transition temperatures and a depression of melting temperature of PHB with compositions in phase diagram, which indicated that the blend was partially miscible. The morphology observation supported this result. It was found that the PHB and PES can crystallize simultaneously or upon stepwise depending on the crystallization temperatures and compositions. The spherulite growth rate of PHB increased with increasing of PES content. The influence of compositions on the spherulitic growth rate for the partially miscible polymer blends was discussed.

  10. HD 161306: a radiatively interacting Be binary?

    Czech Academy of Sciences Publication Activity Database

    Koubský, Pavel; Kotková, Lenka; Kraus, Michaela; Yang, S.; Šlechta, Miroslav; Harmanec, P.; Wolf, M.; Votruba, Viktor; Kubát, Jiří; Kubátová, Brankica; Niemczura, E.; Škoda, Petr

    2014-01-01

    Roč. 567, July (2014), A57/1-A57/4. ISSN 0004-6361 R&D Projects: GA ČR(CZ) GA14-21373S; GA MŠk LG14026 Grant ostatní: ESA(XE) ESA-PECS project no. 98058; GA ČR(CZ) GAP209/10/0715 Institutional support: RVO:67985815 Keywords : binaries: spectroscopic * stars: emission-line * Be: stars Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 4.378, year: 2014

  11. Assessing the development gap

    OpenAIRE

    Sinitsina, Irina; Chubrik, Alexander; Denisova, Irina; Dubrovskiy, Vladimir; Kartseva, Marina; Makenbaeva, Irina; Rokicka, Magdalena; Tokmazishvili, Michael

    2007-01-01

    Current report aims to identify major existing gaps in the four socio-economic dimensions (economic, human, environmental, and institutional) and to reveal those gaps which could potentially hinder social and economic integration of neighbor states with the EU. To achieve this, the authors aim to assess the existing trends in the size of the gaps across countries and problem areas, taking into consideration the specific origin of the gap between EU15/EU12, on the one hand, and FSU republics, ...

  12. Binary Neutron Star Mergers

    Directory of Open Access Journals (Sweden)

    Joshua A. Faber

    2012-07-01

    Full Text Available We review the current status of studies of the coalescence of binary neutron star systems. We begin with a discussion of the formation channels of merging binaries and we discuss the most recent theoretical predictions for merger rates. Next, we turn to the quasi-equilibrium formalisms that are used to study binaries prior to the merger phase and to generate initial data for fully dynamical simulations. The quasi-equilibrium approximation has played a key role in developing our understanding of the physics of binary coalescence and, in particular, of the orbital instability processes that can drive binaries to merger at the end of their lifetimes. We then turn to the numerical techniques used in dynamical simulations, including relativistic formalisms, (magneto-hydrodynamics, gravitational-wave extraction techniques, and nuclear microphysics treatments. This is followed by a summary of the simulations performed across the field to date, including the most recent results from both fully relativistic and microphysically detailed simulations. Finally, we discuss the likely directions for the field as we transition from the first to the second generation of gravitational-wave interferometers and while supercomputers reach the petascale frontier.

  13. Skewed Binary Search Trees

    DEFF Research Database (Denmark)

    Brodal, Gerth Stølting; Moruz, Gabriel

    2006-01-01

    It is well-known that to minimize the number of comparisons a binary search tree should be perfectly balanced. Previous work has shown that a dominating factor over the running time for a search is the number of cache faults performed, and that an appropriate memory layout of a binary search tree...... can reduce the number of cache faults by several hundred percent. Motivated by the fact that during a search branching to the left or right at a node does not necessarily have the same cost, e.g. because of branch prediction schemes, we in this paper study the class of skewed binary search trees. For...... all nodes in a skewed binary search tree the ratio between the size of the left subtree and the size of the tree is a fixed constant (a ratio of 1/2 gives perfect balanced trees). In this paper we present an experimental study of various memory layouts of static skewed binary search trees, where each...

  14. Behind the Pay Gap

    Science.gov (United States)

    Dey, Judy Goldberg; Hill, Catherine

    2007-01-01

    Women have made remarkable gains in education during the past three decades, yet these achievements have resulted in only modest improvements in pay equity. The gender pay gap has become a fixture of the U.S. workplace and is so ubiquitous that many simply view it as normal. "Behind the Pay Gap" examines the gender pay gap for college graduates.…

  15. Binary Popldation Synthcsis Study

    Institute of Scientific and Technical Information of China (English)

    HAN Zhanwen

    2011-01-01

    Binary population synthesis (BPS), an approach to evolving millions of stars (including binaries) simultaneously, plays a crucial role in our understanding of stellar physics, the structure and evolution of galaxies, and cosmology. We proposed and developed a BPS approach, and used it to investigate the formation of many peculiar stars such as hot subdwarf stars, progenitors of type la supernovae, barium stars, CH stars, planetary nebulae, double white dwarfs, blue stragglers, contact binaries, etc. We also established an evolution population synthesis (EPS) model, the Yunnan Model, which takes into account binary interactions for the first time. We applied our model for the origin of hot subdwarf stars in the study of elliptical galaxies and explained their far-UV radiation.

  16. Binary and Millisecond Pulsars

    Directory of Open Access Journals (Sweden)

    Lorimer Duncan R.

    2008-11-01

    Full Text Available We review the main properties, demographics and applications of binary and millisecond radio pulsars. Our knowledge of these exciting objects has greatly increased in recent years, mainly due to successful surveys which have brought the known pulsar population to over 1800. There are now 83 binary and millisecond pulsars associated with the disk of our Galaxy, and a further 140 pulsars in 26 of the Galactic globular clusters. Recent highlights include the discovery of the young relativistic binary system PSR J1906+0746, a rejuvination in globular cluster pulsar research including growing numbers of pulsars with masses in excess of 1.5M_⊙, a precise measurement of relativistic spin precession in the double pulsar system and a Galactic millisecond pulsar in an eccentric (e = 0.44 orbit around an unevolved companion.

  17. Binary and Millisecond Pulsars

    CERN Document Server

    Lorimer, D R

    2008-01-01

    We review the main properties, demographics and applications of binary and millisecond radio pulsars. Our knowledge of these exciting objects has greatly increased in recent years, mainly due to successful surveys which have brought the known pulsar population to over 1800. There are now 83 binary and millisecond pulsars associated with the disk of our Galaxy, and a further 140 pulsars in 26 of the Galactic globular clusters. Recent highlights include the discovery of the young relativistic binary system PSR J1906+0746, a rejuvination in globular cluster pulsar research including growing numbers of pulsars with masses in excess of 1.5 solar masses, a precise measurement of relativistic spin precession in the double pulsar system and a Galactic millisecond pulsar in an eccentric (e=0.44) orbit around an unevolved companion.

  18. Hypervelocity binary stars: smoking gun of massive binary black holes

    CERN Document Server

    Lu, Youjun; Lin, D N C

    2007-01-01

    The hypervelocity stars recently found in the Galactic halo are expelled from the Galactic center through interactions between binary stars and the central massive black hole or between single stars and a hypothetical massive binary black hole. In this paper, we demonstrate that binary stars can be ejected out of the Galactic center with velocities up to 10^3 km/s, while preserving their integrity, through interactions with a massive binary black hole. Binary stars are unlikely to attain such high velocities via scattering by a single massive black hole or through any other mechanisms. Based on the above theoretical prediction, we propose a search for binary systems among the hypervelocity stars. Discovery of hypervelocity binary stars, even one, is a definitive evidence of the existence of a massive binary black hole in the Galactic center.

  19. Milli-arcsecond Binaries

    CERN Document Server

    Torres, R M; Mioduszewki, A; Rodríguez, L F

    2008-01-01

    As part of an astrometric program, we have used the Very Long Baseline Array to measure the trigonometric parallax of several young stars in the Taurus and Ophiuchus star-forming regions with great accuracy. Additionally, we have obtained an unprecedented sample of high-resolution (~ 1 mas) images of several young stellar systems. These images revealed that about 70% of the stars in our sample are very tight binary stars (with separations of a few mas). Since it is highly unlikely that 70% of all stars are such tight binaries, we argue that selection effects are at work.

  20. Binary Cumulant Varieties

    CERN Document Server

    Sturmfels, Bernd

    2011-01-01

    Algebraic statistics for binary random variables is concerned with highly structured algebraic varieties in the space of 2x2x...x2-tensors. We demonstrate the advantages of representing such varieties in the coordinate system of binary cumulants. Our primary focus lies on hidden subset models. Parametrizations and implicit equations in cumulants are derived for hyperdeterminants, for secant and tangential varieties of Segre varieties, and for certain context-specific independence models. Extending work of Rota and collaborators, we explore the polynomial inequalities satisfied by cumulants.

  1. Effect of doped and undoped POMA on the morphology and miscibility of blends with Poly(vinylidene fluoride (PVDF

    Directory of Open Access Journals (Sweden)

    I.S. Rocha

    1999-04-01

    Full Text Available The effect of the addition of small amounts of doped and undoped poly(o-methoxyaniline (POMA on the morphology of melt crystallized PVDF was investigated by means of polarized light optical microscopy. Undoped POMA (POMA-EB inhibits nucleation and growth of non ringed spherulites, partially formed by the polar gphase, whereas POMA doped with toluene sulfonic acid (POMA-TSA favors this process. Moreover, the doping of POMA increases the miscibility between the components of the PVDF/POMA blends, resulting in more homogeneous films. A possible cause of this miscibility increase and for the favoring of the polar gphase, is the higher polarity of the POMA chains as a result of the doping.

  2. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs; ANNUAL

    International Nuclear Information System (INIS)

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results)

  3. Enhanced Oil Recovery (EOR by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

    Directory of Open Access Journals (Sweden)

    Edwin A. Chukwudeme

    2009-09-01

    Full Text Available An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane, model oil (n-C10, SA, toluene and 0.35 wt % asphaltene and crude oil (10 wt % asphaltene obtained from the Middle East. Stearic acid (SA is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years it is shown that there is almost no difference between the recovered oils by water and CO2, after which (> 3 years oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO2 flooding of asphaltenic oil at combined temperatures and pressures of 50 °C/90 bar and 70 °C/120 bar (no significant difference between the two cases, about 1% compared to 80 °C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO2 flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure.

  4. Polymer blends based on PEO and starch: Miscibility and spherulite growth rate evaluated through DSC and optical microscopy

    International Nuclear Information System (INIS)

    The miscibility and PEO spherulite growth rate in PEO/starch blends (starch from cassava) were evaluated using the depression in the melting point (by DSC) and optical polarized microscope, respectively, and compared to pure PEO. The PEO/starch blend ratio changed from 100/0 to 60/40 (weight/weight). The starch induces changes in PEO crystallization on PEO/starch blends but the crystallization rates do not change linearly to the blend ratio. For 90/10, 80/20, 70/30, 65/35 and 60/40 ratios, lower values for the equilibrium melting temperature were observed as compared to the pure PEO. The obtained interaction parameter value was - 0.25 by the use of Nishi-Wang equation. The depression in the equilibrium melting temperatures and the negative value for the polymer-polymer interaction parameter suggest that the blends are miscible in the molten state in the range of investigated ratios, except for the 95/05 ratio in which the equilibrium melting temperature increased relative to the pure PEO. The miscibility should be due to the H-bonds among the hydroxyl groups from starch and oxygen atoms of repeat units of PEO

  5. A simulation research on evaluation of development in shale oil reservoirs by near-miscible CO2 flooding

    Science.gov (United States)

    Lai, Fengpeng; Li, Zhiping; Fu, Yingkun; Yang, Zhihao; Li, Hong

    2015-08-01

    Shale oil is a key resource that could mitigate the impending energy shortage in the future. Despite its abundance in China, studies on shale oil are still at the preliminary stage. Shale oil development through CO2 flooding has been successfully implemented in the United States. Therefore, the mechanics of CO2 flooding in shale oil reservoirs should be investigated. This study applies a simulation method to evaluate the development efficiency of CO2 flooding in shale oil reservoirs. Near-miscible CO2 flooding can effectively develop shale oil. After 20 years, recovery could improve by up to 9.56% as a result of depletion development under near-miscible CO2 flooding with 0.5% pore volume gas injection. Horizontal well injection is better than vertical well injection in terms of sweep efficiency and recovery. Cyclic gas injection is superior to continuous gas injection because the former reduces gas channelling. Thus, the use of horizontal wells with near-miscible cyclic gas injections has the potential to effectively develop shale oil reservoirs.

  6. COMPUTER SIMULATION OF MISCIBILITY AND SELF-ASSEMBLY STRUCTURE FOR POLYMER-CONTAINING SYSTEMS WITH SPECIAL INTERACTIONS

    Institute of Scientific and Technical Information of China (English)

    Tong-fei Shi; Ying Zhang; Wei Jiang; Li-jia An; Bin-yao Li

    2003-01-01

    The miscibility and structure ofA-B copolymer/C homopolymer blends with special interactions were studied by a Monte Carlo simulation in two dimensions. The interaction between segment A and segment C was repulsive, whereas it was attractive between segment B and segment C. In order to study the effect of copolymer chain structure on the morphology and structure of A-B copolymer/C homopolymer blends, the alternating, random and block A-B copolymers were introduced into the blends, respectively. The simulation results indicated that the miscibility of A-B block copolymer/C homopolymer blends depended on the chain structure of the A-B copolymer. Compared with. alternating or random copolymer, the block copolymer, especially the diblock copolymer, could lead to a poor miscibility of A-B copolymer/C homopolymer blends.Moreover, for diblock A-B copolymer/C homopolymer blends, obvious self-organized core-shell structure was observed in the segment B composition region from 20% to 60%. However, if diblock copolymer composition in the blends is less than 40%, obvious self-organized core-shell structure could be formed in the B-segment component region from 10 to 90%.Furthermore, computer statistical analysis for the simulation results showed that the core sizes tended to increase continuously and their distribution became wider with decreasing B-segment component.

  7. Formation of binary radio pulsars

    International Nuclear Information System (INIS)

    In the framework of the standard scenario of the evolution of massive binary stars a study is made of the formation of final binary systems in which at least one of the components is a neutron star. It is found that about every fortieth radio pulsar must be a member of a close binary system. This is confirmed by observations. Radio pulsars are not formed in wide binary systems, possibly because of the very slow rotation of the presupernova stars

  8. NOAA Climate Data Record (CDR) of Zonal Mean Ozone Binary Database of Profiles (BDBP), version 1.0

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This NOAA Climate Data Record (CDR) of Zonal Mean Ozone Binary Database of Profiles (BDBP) dataset is a vertically resolved, global, gap-free and zonal mean dataset...

  9. Compressing Binary Decision Diagrams

    DEFF Research Database (Denmark)

    Hansen, Esben Rune; Satti, Srinivasa Rao; Tiedemann, Peter

    The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to 1...

  10. Equational binary decision diagrams

    NARCIS (Netherlands)

    Groote, J.F.; Pol, J.C. van de

    2000-01-01

    We incorporate equations in binary decision diagrams (BDD). The resulting objects are called EQ-BDDs. A straightforward notion of ordered EQ-BDDs (EQ-OBDD) is defined, and it is proved that each EQ-BDD is logically equivalent to an EQ-OBDD. Moreover, on EQ-OBDDs satisfiability and tautology checkin

  11. Investigation of miscibility of p(3hydroxybutyrate-co-3hydroxyhexanoate) and epoxidized natural rubber blends

    Science.gov (United States)

    Akram, Faridah; Chan, Chin Han; Natarajan, Valliyappan David

    2015-08-01

    Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate [P(3HB-co-3HHx)] produced by C. necator PHB-4 harboring phaCcs from crude palm kernel oil with 21 mol% of 3-hydroxyhexanoate and epoxidized natural rubber with 25 mol% of epoxy content (ENR-25) were used to study the miscibility of the blends by attenuated total reflection-Fourier transform infrared (ATR-FTIR) and differential scanning calorimetry (DSC). The polymers used were purified and the blends were prepared by solution casting method. Nuclear magnetic resonance (NMR) spectra confirm the purity and molecular structures of P(3HB-co-3HHx) and ENR-25. FTIR spectra for different compositions of P(3HB-co-3HHx) and ENR-25 blends show absorbance change of the absorbance bands but with no significant shifting of the absorbance bands as the P(3HB-co-3HHx) content decreases, which shows that there is no intermolecular interaction between the parent polymer blends. On top of that, there are two Tgs present for the blends and both remain constant for different compositions which corresponds to the Tgs of the parent polymers. This indicates that the blends are immiscible.

  12. Influencing solvent miscibility and aqueous stability of aluminum nanoparticles through surface functionalization with acrylic monomers.

    Science.gov (United States)

    Crouse, Christopher A; Pierce, Christian J; Spowart, Jonathan E

    2010-09-01

    With growing interest in the development of new composite systems for a variety of applications that require easily processable materials and adequate structural properties with high energy densities, we have pursued the chemical functionalization of oxide-passivated aluminum nanoparticles (nAl) using three acrylic monomers, 3-methacryloxypropyltrimethoxysilane (MPS), 2-carboxyethyl acrylate (CEA), and phosphonic acid 2-hydroxyethyl methacrylate ester (PAM), to provide chemical compatibility within various solvent and polymeric systems. Fourier transform infrared and X-ray photoelectron spectroscopy suggest that attachment of MPS and PAM monomers occurs through the formation of bonds directly to the passivated oxide surface upon reaction with surface hydroxyls, whereas CEA monomers interact through the formation of ionic carboxylate binding to aluminum atoms within the oxide. The coated particles demonstrate enhanced miscibility in common organic solvents and monomers; MPS and PAM coatings are additionally shown to inhibit oxidation of the aluminum particles when exposed to aqueous environments at room temperature, and PAM coatings are stable at even elevated temperatures. PMID:20795650

  13. Thermodynamic modelling of miscibility in (InAs) x (GaAs)1-x solid solutions

    Science.gov (United States)

    Adhikari, Jhumpa

    2013-05-01

    Current methods used to model the solution thermodynamics of III-V compound semiconductors involve the use of the valence force field as the molecular model and the regular solution model (with the temperature independent interaction parameter and underlying assumption of random mixing) as the engineering model. In this study, excess free energy models (with three or less adjustable parameters) are investigated to predict the solid-solid miscibility of (InAs) x (GaAs)1- x . The models investigated include the Porter/one-constant Margules (OCM) model, the two-constant Margules (TCM) model and the non-random two liquid (NRTL) model. These models are fit to excess free energy values derived from free energy change of mixing (variation with composition) data available from molecular simulations at different temperatures. The parameters in all the models have been found to be temperature dependent. The coexistence compositions are best predicted by the NRTL model, indicating the need to consider non-random mixing effects present in these solid solutions. The TCM model predicts better equilibrium composition data as compared to the OCM model.

  14. Analysis of the vertical penetration of a heated fluid layer in a solid, miscible bed

    International Nuclear Information System (INIS)

    The present study investigates the mass and heat transfer for the vertical penetration of a heated fluid layer in a solid, miscible bed using water-salt solutions (ZnBr2, NaBr) and polyethylenglycol 1500 (PEG) as simulation materials. The time depending spatial distribution of the molten material (PEG) has been measured for the first time with conductivity probes. The dependence of the downward heat flux on the density ratio rho*, i.e. the density of the fluid / the density of the molten solid, has been investigated with two different methods of heating, planar heating with a heat exchanger in a defined initial distance to the PEG-surface and electrolytical volume heating with a defined and timely constant power input. For 1 2 two layers have been observed in the fluid. This phenomenon is caused among other things by an anomality of the mixture density of the system salt solution-PEG. This process affects the downward heat flux so strongly, that it is impossible to transfer the results of such a system in this region of rho* to another system, for example to a corecatcher. The discrepancies between the measured heat fluxes and heat transfer coefficients of this study and that of other authors can be explained by the different construction of the planar heater, or by different boundary conditions in the case of volume heating. (orig.)

  15. Antiwear performance and mechanism of an oil-miscible ionic liquid as a lubricant additive.

    Science.gov (United States)

    Qu, Jun; Bansal, Dinesh G; Yu, Bo; Howe, Jane Y; Luo, Huimin; Dai, Sheng; Li, Huaqing; Blau, Peter J; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald J

    2012-02-01

    An ionic liquid (IL) trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate has been investigated as a potential antiwear lubricant additive. Unlike most other ILs that have very low solubility in nonpolar fluids, this IL is fully miscible with various hydrocarbon oils. In addition, it is thermally stable up to 347 °C, showed no corrosive attack to cast iron in an ambient environment, and has excellent wettability on solid surfaces (e.g., contact angle on cast iron lubricating oils. For example, a 5 wt % addition into a synthetic base oil eliminated the scuffing failure experienced in neat oil and, as a result, reduced the friction coefficient by 60% and the wear rate by 3 orders of magnitude. A synergistic effect on wear protection was observed with the current antiwear additive when added into a fully formulated engine oil. Nanostructure examination and composition analysis revealed a tribo-boundary film and subsurface plastic deformation zone for the metallic surface lubricated by the IL-containing lubricants. This protective boundary film is believed to be responsible for the IL's antiscuffing and antiwear functionality. PMID:22248297

  16. Investigation of miscibility of p(3hydroxybutyrate-co-3hydroxyhexanoate) and epoxidized natural rubber blends

    International Nuclear Information System (INIS)

    Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate [P(3HB-co-3HHx)] produced by C. necator PHB−4 harboring phaCcs from crude palm kernel oil with 21 mol% of 3-hydroxyhexanoate and epoxidized natural rubber with 25 mol% of epoxy content (ENR-25) were used to study the miscibility of the blends by attenuated total reflection-Fourier transform infrared (ATR-FTIR) and differential scanning calorimetry (DSC). The polymers used were purified and the blends were prepared by solution casting method. Nuclear magnetic resonance (NMR) spectra confirm the purity and molecular structures of P(3HB-co-3HHx) and ENR-25. FTIR spectra for different compositions of P(3HB-co-3HHx) and ENR-25 blends show absorbance change of the absorbance bands but with no significant shifting of the absorbance bands as the P(3HB-co-3HHx) content decreases, which shows that there is no intermolecular interaction between the parent polymer blends. On top of that, there are two Tgs present for the blends and both remain constant for different compositions which corresponds to the Tgs of the parent polymers. This indicates that the blends are immiscible

  17. Scale-up of miscible flood processes. Quarterly report, July 1, 1993--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Orr, F.M. Jr.

    1993-12-31

    Progress is reported for a comprehensive investigation of the scaling behavior of gas injection processes in heterogeneous reservoirs. The interplay of phase behavior, viscous fingering, gravity segregation, capillary imbibition and drainage, and reservoir heterogeneity is examined in a series of simulations and experiments. Compositional and first-contact miscible simulations of viscous fingering and gravity segregation are compared to show that the two techniques can give very different results. Also, analyzed are two-dimensional and three-dimensional flows in which gravity segregation and viscous fingering interact. The simulations show that 2D and 3D flows can differ significantly. A comparison of analytical solutions for three-component two-phase flow with experimental results for oil/water/alcohol systems is reported. While the experiments and theory show reasonable agreement, some differences remain to be explained. The scaling behavior of the interaction of gravity segregation and capillary forces is investigated through simulations and through scaling arguments based on analysis of the differential equations. The simulations show that standard approaches do not agree well with results of low IFT displacements. The scaling analyses, however, reveal flow regimes where capillary, gravity, or viscous forces dominate the flow.

  18. Influence of rheology on buoyancy driven instabilities of miscible displacements in 2D micromodels

    International Nuclear Information System (INIS)

    The stability of miscible displacements of Newtonian and shear-thinning fluids of slightly different densities (Δρ/ρ ∼ 3x 10-4) with a mean flow velocity U is investigated in a 2D transparent network of channels (average width = 0.33 mm). Concentration maps providing information at both the global and local scale are obtained through optical absorption measurements and compared in gravitationally stable and unstable vertical flow configurations; the influence of buoyant flows of typical velocity Ug is characterized by the gravity number Ng = Ug/|U|. For Ng d = D/U. For the Newtonian water-glycerol solution, ld is only the same in the stable and unstable configurations for |Ng| g d is increased by buoyancy in the unstable configuration and increasingly large front structures are observed on the concentration maps; for Ng > 0.2, front spreading is not diffusive any more. In the stable configuration, in contrast, the front is flattened by buoyancy for Ng d reaches values of the order of the length of individual channels. For the shear thinning water-polymer solution, both the concentration maps and the value of ld are the same in the stable and unstable configurations over the full range of U values investigated: this stabilization is explained by their high effective viscosity at low shear rates keeping Ng below the instability threshold even at the lowest velocities.

  19. Investigation of miscibility of p(3hydroxybutyrate-co-3hydroxyhexanoate) and epoxidized natural rubber blends

    Energy Technology Data Exchange (ETDEWEB)

    Akram, Faridah; Chan, Chin Han; Natarajan, Valliyappan David [Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, 40450 Selangor Darul Ehsan (Malaysia)

    2015-08-28

    Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate [P(3HB-co-3HHx)] produced by C. necator PHB{sup −}4 harboring phaC{sub cs} from crude palm kernel oil with 21 mol% of 3-hydroxyhexanoate and epoxidized natural rubber with 25 mol% of epoxy content (ENR-25) were used to study the miscibility of the blends by attenuated total reflection-Fourier transform infrared (ATR-FTIR) and differential scanning calorimetry (DSC). The polymers used were purified and the blends were prepared by solution casting method. Nuclear magnetic resonance (NMR) spectra confirm the purity and molecular structures of P(3HB-co-3HHx) and ENR-25. FTIR spectra for different compositions of P(3HB-co-3HHx) and ENR-25 blends show absorbance change of the absorbance bands but with no significant shifting of the absorbance bands as the P(3HB-co-3HHx) content decreases, which shows that there is no intermolecular interaction between the parent polymer blends. On top of that, there are two T{sub g}s present for the blends and both remain constant for different compositions which corresponds to the T{sub g}s of the parent polymers. This indicates that the blends are immiscible.

  20. Growth dynamics of isotactic polypropylene single crystals during isothermal crystallization from a miscible polymeric solvent

    Science.gov (United States)

    Mehta, Rujul; Keawwattana, Wirunya; Kyu, Thein

    2004-02-01

    The present article presents a spatiotemporal growth of isotactic polypropylene (iPP) single crystals, melt crystallized from a polymeric solvent, i.e., poly (ethylene octene) copolymer that is known to be miscible with iPP. Optical and atomic force microscopic investigations reveal that the melt grown single crystals of iPP develop in the form of two parallel rows of crystal lamellae, but these crystals merge at the tips. To elucidate the mechanism of these emerging parallel rows of iPP crystals, a phase field model pertaining to solidification phenomena has been employed that involves a nonconserved crystal order parameter and a chain-tilting angle. This phase field model is based on the free energy of crystallization, having an asymmetric double well, and a tensorial surface free energy of the crystal interface coupled with a curvature elastic free energy that is possessed by the solid-liquid interface. The spatiotemporal simulation of iPP single crystal growth has been carried out on a square lattice based on the finite difference method for spatial steps and an explicit method for temporal steps with a periodic boundary condition. The appearance of the seemingly twin crystal is captured in the simulation, which may be attributed to the sector demarcation that is taking place in the anisotropically growing single crystal of iPP.

  1. Investigating the factors influencing recovery of asphaltenic oil by water and miscible CO{sub 2} flooding

    Energy Technology Data Exchange (ETDEWEB)

    Chukwudeme, Edwin Andrew

    2009-09-15

    Conclusions that may be drawn from this work on the influence of CO{sub 2}, temperature, pressure and water composition on the recovery of asphaltenic oil by water and CO{sub 2} flooding are as follows: Asphaltene is found to alter outcrop chalk wettability from water-wet to more oil wet, which influence oil recovery by miscible CO{sub 2} and water flooding. Modification of Hirschberg solubility model for predicting asphaltene deposition has been done to account for the effect of CO{sub 2} fraction in the liquid phase during miscible flooding. This is done based on data from this work and literature. This model made it possible to isolate the effect of CO{sub 2} fraction in liquid phase on asphaltene deposition during miscible flooding. Hence, determine the critical fraction of CO{sub 2} that initiate the asphaltene deposition. The critical fraction of CO{sub 2} is estimated to be between 17 to 42 mol percent (mol%), with 33 mol% as average value. A ternary diagram is developed and is based on solubility parameter ratio (S.P.R) and molar volume ratio (V{sub CO2}/V{sub L}) and their relation to asphaltene deposition using data from this work and literature. From this data, it may be suggested that S.P.R is a determining factor for asphaltene deposition during CO{sub 2} flooding, which is not unreasonable since it is influenced by the molar volume ratio, hence temperature, pressure and composition. It is interesting to see a linear relationship between asphaltene precipitation and pressure drop regardless of the flowing pressure at isothermal condition. This is tested for under-saturated fluids. Oil recovery by miscible CO{sub 2} flooding shows low ultimate oil recovery with increasing temperature and pressure for asphaltenic oil compared to non-asphaltenic. CO{sub 2} flooding is found to be plausible for asphaltenic reservoir at lower temperature (< 70 C). From simulation studies, EOR by CO{sub 2} initiated after at least three years of water injection show the

  2. Bridging the Gap

    DEFF Research Database (Denmark)

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska;

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures.......Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures....

  3. Bridging the Gap

    OpenAIRE

    Kramer Overgaard, Majken; Broeng, Jes; Jensen, Monika Luniewska; Murdock, Karen; Schmidt, Iben Julie

    2015-01-01

    Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ventures. Bridging the Gap (BtG) is a 2-year project funded by The Danish Industry Foundation. The goal of Bridging the Gap has been to create a new innovation model which will increase the rate at which Danish universities can spinout new technology ve...

  4. Omnidirectional photonic band gap of one-dimensional ternary plasma photonic crystals

    International Nuclear Information System (INIS)

    An omnidirectional photonic band gap (PBG) is presented in one-dimensional ternary plasma photonic crystal (PPC). In contrast to the omnidirectional PBG coming from a zero- n-tilde gap or single negative (SNG) (permittivity- or permittivity-negative) gap, this gap originates from a Bragg gap. It has been shown that the ternary PPC, compared with the usual binary photonic crystal (PC), has a superior feature in the enhancement of the high-reflectance range (HRR) and the modulation of the omnidirectional PBG. Omnidirectional PBGs can be utilized as omnidirectional or large incident angle filters or reflectors in microwave devices

  5. Binary MEMS gas sensors

    International Nuclear Information System (INIS)

    A novel sensing mechanism for electrostatic MEMS that employs static bifurcation-based sensing and binary detection is demonstrated. It is implemented as an ethanol vapour sensor that exploits the static pull-in bifurcation. Sensor detection of 5 ppm of ethanol vapour in dry nitrogen, equivalent to a detectable mass of 165 pg, is experimentally demonstrated. Sensor robustness to external disturbances is also demonstrated. A closed-form expression for the sensitivity of statically detected electrostatic MEMS sensors is derived. It is shown that the sensitivity of static bifurcation-based binary electrostatic MEMS sensors represents an upper bound on the sensitivity of static detection for given sensor dimensions and material properties. (paper)

  6. Binary Tetrahedral Flavor Symmetry

    CERN Document Server

    Eby, David A

    2013-01-01

    A study of the T' Model and its variants utilizing Binary Tetrahedral Flavor Symmetry. We begin with a description of the historical context and motivations for this theory, together with some conceptual background for added clarity, and an account of our theory's inception in previous works. Our model endeavors to bridge two categories of particles, leptons and quarks, a unification made possible by the inclusion of additional Higgs particles, shared between the two fermion sectors and creating a single coherent system. This is achieved through the use of the Binary Tetrahedral symmetry group and an investigation of the Tribimaximal symmetry evidenced by neutrinos. Our work details perturbations and extensions of this T' Model as we apply our framework to neutrino mixing, quark mixing, unification, and dark matter. Where possible, we evaluate model predictions against experimental results and find excellent matching with the atmospheric and reactor neutrino mixing angles, an accurate prediction of the Cabibb...

  7. Compressing Binary Decision Diagrams

    CERN Document Server

    Hansen, Esben Rune; Tiedemann, Peter

    2008-01-01

    The paper introduces a new technique for compressing Binary Decision Diagrams in those cases where random access is not required. Using this technique, compression and decompression can be done in linear time in the size of the BDD and compression will in many cases reduce the size of the BDD to 1-2 bits per node. Empirical results for our compression technique are presented, including comparisons with previously introduced techniques, showing that the new technique dominate on all tested instances.

  8. Evaluation of binary solvent mixtures for efficient monoacylglycerol production by continuous enzymatic glycerolysis.

    Science.gov (United States)

    Damstrup, Marianne L; Abildskov, Jens; Kiil, Søren; Jensen, Anker D; Sparsø, Flemming V; Xu, Xuebing

    2006-09-20

    This study was aimed at evaluating different binary solvent mixtures for efficient industrial monoacylglycerol (MAG) production by enzymatic glycerolysis. Of all investigated cases, the binary mixture of tert-butanol:tert-pentanol (TB:TP) 80:20 vol % was the most suitable organic medium for continuous enzymatic glycerolysis, ensuring high MAG formation in a short time, reasonable solvent price, and easy handling during distillation/condensation processing. A minimum solvent dosage of 44-54 wt % of the reaction mixture was necessary to achieve high MAG yields of 47-56 wt %, within 20 min. The melting and boiling points of the TB:TP mixture were estimated to be 7 and 85 degrees C, respectively, using thermodynamic models. These predictions were in good agreement with experimentally determined values. In spite of the high reaction efficiency in the binary TB:TP system, the mixture of glycerol and sunflower oil (containing 97.1% triacylglycerol) yielded surprisingly a liquid/liquid phase split behavior even at high temperatures (>80 degrees C). This in contrast to thermodynamic model calculations suggested full miscibility in all proportions. These findings suggest that enhanced reaction efficiency in organic solvent also depends upon aspects other than the system homogeneity such as reduced viscosity, reduced mass transfer limitations, and the accessibility of the substrate to the active site of the enzyme. PMID:16968070

  9. Chemical control of dissolution-driven convection in partially miscible systems: theoretical classification.

    Science.gov (United States)

    Loodts, V; Rongy, L; De Wit, A

    2015-11-28

    Dissolution-driven convection occurs in the host phase of a partially miscible system when a buoyantly unstable density stratification develops upon dissolution. Reactions can impact such convection by changing the composition and thus the density of the host phase. Here we study the influence of A + B → C reactions on such convective dissolution when A is the dissolving species and B a reactant initially in solution in the host phase. We perform a linear stability analysis of related reaction-diffusion density profiles to compare the growth rate of the instability in the reactive case to its non reactive counterpart when all species diffuse at the same rate. We classify the stabilizing or destabilizing influence of reactions on the buoyancy-driven convection in a parameter space spanned by the solutal Rayleigh numbers RA,B,C of chemical species A, B, C and by the ratio β of initial concentrations of the reactants. For RA > 0, the non reactive dissolution of A in the host phase is buoyantly unstable. In that case, we show that the reaction is enhancing convection provided C is sufficiently denser than B. Increasing the ratio β of initial reactant concentrations increases the effect of chemistry but does not significantly impact the stabilizing/destabilizing classification. When the non reactive case is buoyantly stable (RA≤ 0), reactions can create in time an unstable density stratification and trigger convection if RC > RB. Our theoretical approach allows classifying previous results in a unifying picture and developing strategies for the chemical control of convective dissolution. PMID:26486608

  10. Influence of rheology on buoyancy driven instabilities of miscible displacements in 2D micromodels

    Energy Technology Data Exchange (ETDEWEB)

    D' Angelo, M V; Rosen, M [University Buenos Aires, CONICET. Grupo de Medios Porosos, Facultad de IngenierIa, Paseo Colon 850, 1063 Buenos-Aires (Argentina); Auradou, H; Hulin, J P, E-mail: vdangelo@fi.uba.a, E-mail: auradou@fast.u-psud.f [University Pierre et Marie Curie-Paris 6, University Paris-Sud, CNRS. Lab. FAST, Bat 502, Campus Universitaire, F-91405 Orsay (France)

    2009-05-01

    The stability of miscible displacements of Newtonian and shear-thinning fluids of slightly different densities (DELTArho/rho approx 3x 10{sup -4}) with a mean flow velocity U is investigated in a 2D transparent network of channels (average width = 0.33 mm). Concentration maps providing information at both the global and local scale are obtained through optical absorption measurements and compared in gravitationally stable and unstable vertical flow configurations; the influence of buoyant flows of typical velocity U{sub g} is characterized by the gravity number N{sub g} = U{sub g}/|U|. For N{sub g} < 0.2, the spreading of the mean relative concentration profile is diffusive for both types of rheologies and characterized by a single dispersivity value l{sub d} = D/U. For the Newtonian water-glycerol solution, l{sub d} is only the same in the stable and unstable configurations for |N{sub g}| < 0.01. For 0.01 < N{sub g} < 0.2, l{sub d} is increased by buoyancy in the unstable configuration and increasingly large front structures are observed on the concentration maps; for N{sub g} > 0.2, front spreading is not diffusive any more. In the stable configuration, in contrast, the front is flattened by buoyancy for N{sub g} < -0.01 and l{sub d} reaches values of the order of the length of individual channels. For the shear thinning water-polymer solution, both the concentration maps and the value of l{sub d} are the same in the stable and unstable configurations over the full range of U values investigated: this stabilization is explained by their high effective viscosity at low shear rates keeping N{sub g} below the instability threshold even at the lowest velocities.

  11. Binary-Signal Recovery

    Science.gov (United States)

    Griebeler, Elmer L.

    2011-01-01

    Binary communication through long cables, opto-isolators, isolating transformers, or repeaters can become distorted in characteristic ways. The usual solution is to slow the communication rate, change to a different method, or improve the communication media. It would help if the characteristic distortions could be accommodated at the receiving end to ease the communication problem. The distortions come from loss of the high-frequency content, which adds slopes to the transitions from ones to zeroes and zeroes to ones. This weakens the definition of the ones and zeroes in the time domain. The other major distortion is the reduction of low frequency, which causes the voltage that defines the ones or zeroes to drift out of recognizable range. This development describes a method for recovering a binary data stream from a signal that has been subjected to a loss of both higher-frequency content and low-frequency content that is essential to define the difference between ones and zeroes. The method makes use of the frequency structure of the waveform created by the data stream, and then enhances the characteristics related to the data to reconstruct the binary switching pattern. A major issue is simplicity. The approach taken here is to take the first derivative of the signal and then feed it to a hysteresis switch. This is equivalent in practice to using a non-resonant band pass filter feeding a Schmitt trigger. Obviously, the derivative signal needs to be offset to halfway between the thresholds of the hysteresis switch, and amplified so that the derivatives reliably exceed the thresholds. A transition from a zero to a one is the most substantial, fastest plus movement of voltage, and therefore will create the largest plus first derivative pulse. Since the quiet state of the derivative is sitting between the hysteresis thresholds, the plus pulse exceeds the plus threshold, switching the hysteresis switch plus, which re-establishes the data zero to one transition

  12. Massive Black Hole Binary Evolution

    Directory of Open Access Journals (Sweden)

    Merritt David

    2005-11-01

    Full Text Available Coalescence of binary supermassive black holes (SBHs would constitute the strongest sources of gravitational waves to be observed by LISA. While the formation of binary SBHs during galaxy mergers is almost inevitable, coalescence requires that the separation between binary components first drop by a few orders of magnitude, due presumably to interaction of the binary with stars and gas in a galactic nucleus. This article reviews the observational evidence for binary SBHs and discusses how they would evolve. No completely convincing case of a bound, binary SBH has yet been found, although a handful of systems (e.g. interacting galaxies; remnants of galaxy mergers are now believed to contain two SBHs at projected separations of <~ 1kpc. N-body studies of binary evolution in gas-free galaxies have reached large enough particle numbers to reproduce the slow, “diffusive” refilling of the binary’s loss cone that is believed to characterize binary evolution in real galactic nuclei. While some of the results of these simulations - e.g. the binary hardening rate and eccentricity evolution - are strongly N-dependent, others - e.g. the “damage” inflicted by the binary on the nucleus - are not. Luminous early-type galaxies often exhibit depleted cores with masses of ~ 1-2 times the mass of their nuclear SBHs, consistent with the predictions of the binary model. Studies of the interaction of massive binaries with gas are still in their infancy, although much progress is expected in the near future. Binary coalescence has a large influence on the spins of SBHs, even for mass ratios as extreme as 10:1, and evidence of spin-flips may have been observed.

  13. Decomposition of Binary images - A Survey and Comparison

    Czech Academy of Sciences Publication Activity Database

    Suk, Tomáš; Höschl, Cyril; Flusser, Jan

    2012-01-01

    Roč. 45, č. 12 (2012), s. 4279-4291. ISSN 0031-3203 R&D Projects: GA ČR GAP103/11/1552 Institutional support: RVO:67985556 Keywords : Binary image decomposition * Bipartite graph * Image compression * Moment computation Subject RIV: JD - Computer Applications, Robotics Impact factor: 2.632, year: 2012 http://library.utia.cas.cz/separaty/2012/ZOI/suk-0381722.pdf

  14. Comparative studies of empirical correlations for calculation of minimum miscibility pressure; Estudo comparativo de correlacoes empiricas para o calculo da pressao minima de miscibilidade

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, P.S. [PETROBRAS, Salvador, BA (Brazil). Unidade de Negocios da Bahia]. E-mail: psrocha@petrobras.com.br; Meirelles, C.P.; Santos, R.B.; Costa, G.M.N. [Universidade Salvador (UNIFACS), Salvador, BA (Brazil). Centro de Estudos em Petroleo e Gas Natural (CEPGN)]. E-mail: gloria.costa@unifacs.br

    2003-07-01

    The miscible recovery of oil can be obtained by displacing it using CO{sub 2} at a pressure greater than a minimum level, called minimum miscibility pressure. In this study we used three correlations for the calculation of the minimum miscibility pressure in multiple contact: Yellig and Metcalfe method; Alston, Kokolis and James method; and Enick, Holden and Morsi method. For a carefully evaluation of the range of application and restrictions, a data base from the literature containing 125 combinations of oils, temperatures and solvents, for which the minimum miscibility pressures were available using pure or impure CO{sub 2} from experiments in slim tube apparatus. This study revealed that the best method is the Alston, Kokolis and James one, although the average relative error and the standard deviation are greater than the values cited by the authors. An evaluation of the correlation coefficient revealed that the number of independent variables in each method is insufficient. Although the second and third methods consider the impurities in the CO{sub 2}, the error obtained in the calculation of the minimum miscibility pressure using pure CO{sub 2} is lower than the one for impure CO{sub 2}, showing that the effects of the contaminants are not well described by the correlations as the authors say. (author)

  15. SPARK GAP SWITCH

    Science.gov (United States)

    Neal, R.B.

    1957-12-17

    An improved triggered spark gap switch is described, capable of precisely controllable firing time while switching very large amounts of power. The invention in general comprises three electrodes adjustably spaced and adapted to have a large potential impressed between the outer electrodes. The central electrode includes two separate elements electrically connected togetaer and spaced apart to define a pair of spark gaps between the end electrodes. Means are provided to cause the gas flow in the switch to pass towards the central electrode, through a passage in each separate element, and out an exit disposed between the two separate central electrode elements in order to withdraw ions from the spark gap.

  16. Filling the Income Gap

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    @@ Income distribution has become one of the people's main concerns in China where more than 30years of reform and opening up have also resulted in an ever-expanding wealth gap.But narrowing down the rich-poor disparity will prove to be no easy task.Wei Zhong,a researcher with the Institute of Economics under the Chinese Academy of Social Sciences,elaborated on the origins and trends of China's widening income gap,and discussed solutions to curb the gap,in a recent article.Edited excerpts follow:

  17. Modelling Gender Pay Gaps

    OpenAIRE

    Olsen, W K., Jamie Morgan.

    2004-01-01

    EXECUTIVE SUMMARYIntroductionThere has been little change in the full-time gender pay gap since the mid 1990s andin the female part-time/male full-time pay gap since the mid 1970s. The gender gapin hourly earnings for those employed full-time in Britain in 2003 was 18 per cent,while that between women working part-time and men working full-time was 40 percent.This research uses statistical methods to identify how much of the gender pay gap isassociated with different factors. The data set ana...

  18. Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

    KAUST Repository

    Kou, Jisheng

    2016-05-10

    In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng-Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from the microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young-Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young-Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young-Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests

  19. Multi-scale diffuse interface modeling of multi-component two-phase flow with partial miscibility

    Science.gov (United States)

    Kou, Jisheng; Sun, Shuyu

    2016-08-01

    In this paper, we introduce a diffuse interface model to simulate multi-component two-phase flow with partial miscibility based on a realistic equation of state (e.g. Peng-Robinson equation of state). Because of partial miscibility, thermodynamic relations are used to model not only interfacial properties but also bulk properties, including density, composition, pressure, and realistic viscosity. As far as we know, this effort is the first time to use diffuse interface modeling based on equation of state for modeling of multi-component two-phase flow with partial miscibility. In numerical simulation, the key issue is to resolve the high contrast of scales from the microscopic interface composition to macroscale bulk fluid motion since the interface has a nanoscale thickness only. To efficiently solve this challenging problem, we develop a multi-scale simulation method. At the microscopic scale, we deduce a reduced interfacial equation under reasonable assumptions, and then we propose a formulation of capillary pressure, which is consistent with macroscale flow equations. Moreover, we show that Young-Laplace equation is an approximation of this capillarity formulation, and this formulation is also consistent with the concept of Tolman length, which is a correction of Young-Laplace equation. At the macroscopical scale, the interfaces are treated as discontinuous surfaces separating two phases of fluids. Our approach differs from conventional sharp-interface two-phase flow model in that we use the capillary pressure directly instead of a combination of surface tension and Young-Laplace equation because capillarity can be calculated from our proposed capillarity formulation. A compatible condition is also derived for the pressure in flow equations. Furthermore, based on the proposed capillarity formulation, we design an efficient numerical method for directly computing the capillary pressure between two fluids composed of multiple components. Finally, numerical tests

  20. Phononic First Band Gap of Quaternary Layered Periodic Structure with the Lumped-Mass Method

    Directory of Open Access Journals (Sweden)

    Chen Yuan

    2014-01-01

    Full Text Available Existing band gap analysis is mostly focused on the binary structure, while the researches on the quaternary layered periodic structure are still lacking. In this paper, the unidimensional lumped-mass method in the phonic crystal theory is firstly improved so that the material viscoelasticity can be taken into consideration. Then, the binary layered periodic structure is converted into a quaternary one and band gaps appear at low frequency range. Finally, the effects of density, elastic modulus, damping ratio, and the thickness of single material on the first band gap of the quaternary layered periodic structure are analyzed after the algorithm is promoted. The research findings show that effects of density, elastic modulus, and thickness of materials on the first band gap are considerable but those of damping ratio are not so distinct. This research provides theoretical bases for band gap design of the quaternary layered periodic structure.

  1. Biclustering Sparse Binary Genomic Data

    OpenAIRE

    Van Uitert, M.; Meuleman, W.; Wessels, L. F. A.

    2008-01-01

    Genomic datasets often consist of large, binary, sparse data matrices. In such a dataset, one is often interested in finding contiguous blocks that (mostly) contain ones. This is a biclustering problem, and while many algorithms have been proposed to deal with gene expression data, only two algorithms have been proposed that specifically deal with binary matrices. None of the gene expression biclustering algorithms can handle the large number of zeros in sparse binary matrices. The two propos...

  2. ASSESSMENT OF THE ABILITY OF STANDARD SLURRY PUMPS TO MIX MISCIBLE AND IMMISCIBLE LIQUIDS IN TANK 50H

    Energy Technology Data Exchange (ETDEWEB)

    Poirier, M.

    2011-06-15

    Tank 50H is the feed tank for the Saltstone Production Facility (SPF). At present, Tank 50H contains two standard slurry pumps and two Quad Volute slurry pumps. Current requirements and mixing operation is to run three pumps for one hour prior to initiating a feed transfer to SPF. Savannah River Site (SRS) Liquid Waste would like to move one or both of the Quad Volute pumps from Tank 50H to Tank 51H to replace pumps in Tank 51H that are failing. In addition, one of the standard pumps in Tank 50H exhibits high seal leakage and vibration. SRS Liquid Waste requested Savannah River National (SRNL) to conduct a study to evaluate the feasibility of mixing the contents of Tank 50H with one to three standard slurry pumps. To determine the pump requirements to blend miscible and immiscible liquids in Tank 50H, the author reviewed the pilot-scale blending work performed for the Salt Disposition Integration Project (SDIP) and the technical literature, and applied the results to Tank 50H to determine the number, size, and operating parameters needed to blend the tank contents. The conclusions from this analysis are: (1) A single rotating standard slurry pump (with a 13.6 ft{sup 2}/s U{sub 0}D) will be able to blend miscible liquids (i.e., salt solution) in Tank 50H within 4.4 hours. (2) Two rotating standard slurry pumps will be able to blend miscible liquids in Tank 50H within 3.1 hours. (3) Three rotating standard slurry pumps will be able to blend miscible liquids in Tank 50H within 2.5 hours. (4) A single rotating standard slurry pump (with a 13.6 ft{sup 2}/s U{sub 0}D) will disperse Isopar L{reg_sign} droplets that are less than or equal to 15 micron in diameter. If the droplets are less than 15 micron, they will be dispersed within 4.4 hours. Isopar L{reg_sign} provides a lower bound on the maximum size of droplets that will be dispersed by the slurry pumps in Tank 50H. (5) Two rotating standard slurry pumps will disperse Isopar L{reg_sign} droplets less than 15 micron

  3. Evolution of Close Binary Systems

    Energy Technology Data Exchange (ETDEWEB)

    Yakut, K; Eggleton, P

    2005-01-24

    We collected data on the masses, radii, etc. of three classes of close binary stars: low-temperature contact binaries (LTCBs), near-contact binaries (NCBs), and detached close binaries (DCBs). They restrict themselves to systems where (1) both components are, at least arguably, near the Main Sequence, (2) the periods are less than a day, and (3) there is both spectroscopic and photometric analysis leading to reasonably reliable data. They discuss the possible evolutionary connections between these three classes, emphasizing the roles played by mass loss and angular momentum loss in rapidly-rotating cool stars.

  4. Report IAU Comm. 42, Close Binary Stars

    OpenAIRE

    Ribas, Ignasi; Scarfe, Colin D.; Torres, Guillermo; Rucinski, Slavek M.; Sion, Edward M.; Richards, Mercedes T.; Niarchos, Panayiotis; Olah, Katalin

    2008-01-01

    Brief summaries are given about (1) close binary research from the perspective of the Bibliography of Close Binaries, (2) low-mass binaries and model discrepancies, (3) W UMa-type binaries, (4) cataclysmic variables, (5) Algol binaries, (6) the oEA stars, (7) effects of binarity on stellar activity.

  5. Near-Infrared Polarimetry of the GG Tauri A Binary System

    CERN Document Server

    Itoh, Yoichi; Kudo, Tomoyuki; Kusakabe, Nobuhiko; Hashimoto, Jun; Abe, Lyu; Brandner, Wolfgang; Brandt, Timothy D; Carson, Joseph C; Egner, Sebastian; Feldt, Markus; Grady, Carol A; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko S; Henning, Thomas; Hodapp, Klaus W; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R; Kuzuhara, Masayuki; Kwon, Jungmi; Matsuo, Taro; McElwain, Michael W; Miyama, Shoken; Morino, Jun-Ichi; Moro-Martin, Amaya; Nishimura, Tetsuo; Pyo, Tae-Soo; Serabyn, Eugene; Suenaga, Takuya; Suto, Hiroshi; Suzuki, Ryuji; Takahashi, Yasuhiro H; Takato, Naruhisa; Terada, Hiroshi; Thalmann, Christian; Tomono, Daigo; Turner, Edwin L; Watanabe, Makoto; Wisniewski, John; Yamada, Toru; Mayama, Satoshi; Currie, Thayne; Takami, Hideki; Usuda, Tomonori; Tamura, Motohide

    2015-01-01

    A high angular resolution near-infrared polarized-intensity image of the GG Tau A binary system was obtained with the Subaru Telescope. The image shows the circumbinary disk scattering the light from the central binary. The azimuthal profile of the polarized intensity of the circumbinary disk is roughly reproduced by a simple disk model with the Henyey-Greenstein function and the Rayleigh function, indicating small dust grains at the surface of the disk. Combined with a previous observation of the circumbinary disk, our image indicates that the gap structure in the circumbinary disk orbits anti-clockwise, while material in the disk orbit clockwise. We propose a shadow of material located between the central binary and the circumbinary disk. The separations and position angles of the stellar components of the binary in the past 20 years are consistent with the binary orbit with a = 33.4 AU and e = 0.34.

  6. Wide-Gap Chalcopyrites

    CERN Document Server

    Siebentritt, Susanne

    2006-01-01

    Chalcopyrites, in particular those with a wide band gap, are fascinating materials in terms of their technological potential in the next generation of thin-film solar cells and in terms of their basic material properties. They exhibit uniquely low defect formation energies, leading to unusual doping and phase behavior and to extremely benign grain boundaries. This book collects articles on a number of those basic material properties of wide-gap chalcopyrites, comparing them to their low-gap cousins. They explore the doping of the materials, the electronic structure and the transport through interfaces and grain boundaries, the formation of the electric field in a solar cell, the mechanisms and suppression of recombination, the role of inhomogeneities, and the technological role of wide-gap chalcopyrites.

  7. Filling the Income Gap

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Income distribution has become one of the people’s main concerns in China where more than 30 years of reform and opening up have also resulted in an ever-expanding wealth gap. But narrowing down the

  8. Tail gap grouting

    Czech Academy of Sciences Publication Activity Database

    Kolymbas, D.; Maehr, M.; Herle, Ivo

    Torino: Associazione Georisorse e Ambiente , 2002, s. -. [International Conference ACUUS 2002. Torino (IT), 14.11.2002-16.11.2002] Institutional research plan: CEZ:AV0Z2071913 Keywords : tunnel construction, tail gap, grouting Subject RIV: JM - Building Engineering

  9. Gaps in Oncology

    Science.gov (United States)

    The first plenary of the EPEC-O (Education in Palliative and End-of-Life Care for Oncology) Self-Study Original Version provides background for the curriculum and identifies gaps in current and desired comprehensive cancer care.

  10. Photonic band gap materials

    International Nuclear Information System (INIS)

    An overview of the theoretical and experimental efforts in obtaining a photonic band gap, a frequency band in three-dimensional dielectric structures in which electromagnetic waves are forbidden, is presented

  11. Low autocorrelation binary sequences

    Science.gov (United States)

    Packebusch, Tom; Mertens, Stephan

    2016-04-01

    Binary sequences with minimal autocorrelations have applications in communication engineering, mathematics and computer science. In statistical physics they appear as groundstates of the Bernasconi model. Finding these sequences is a notoriously hard problem, that so far can be solved only by exhaustive search. We review recent algorithms and present a new algorithm that finds optimal sequences of length N in time O(N {1.73}N). We computed all optimal sequences for N≤slant 66 and all optimal skewsymmetric sequences for N≤slant 119.

  12. The Gender Pay Gap

    OpenAIRE

    Alan Manning

    1996-01-01

    Empirical research on gender pay gaps has traditionally focused on the role of gender-specific factors, particularly gender differences in qualifications and differences in the treatment of otherwise equally qualified male and female workers (i.e., labor market discrimination). This paper explores the determinants of the gender pay gap and argues for the importance of an additional factor, wage structure, the array of prices set for labor market skills and the rewards received for employment ...

  13. Gap polariton solitons

    CERN Document Server

    Gorbach, A V; Skryabin, D V

    2009-01-01

    We report the existence, and study mobility and interactions of gap polariton solitons in a microcavity with a periodic potential, where the light field is strongly coupled to excitons. Gap solitons are formed due to the interplay between the repulsive exciton-exciton interaction and cavity dispersion. The analysis is carried out in an analytical form, using the coupled-mode (CM) approximation, and also by means of numerical methods.

  14. DISK-SATELLITE INTERACTION IN DISKS WITH DENSITY GAPS

    International Nuclear Information System (INIS)

    Gravitational coupling between a gaseous disk and an orbiting perturber leads to angular momentum exchange between them that can result in gap opening by planets in protoplanetary disks and clearing of gas by binary supermassive black holes (SMBHs) embedded in accretion disks. Understanding the co-evolution of the disk and the orbit of the perturber in these circumstances requires knowledge of the spatial distribution of the torque exerted by the latter on a highly non-uniform disk. Here we explore disk-satellite interaction in disks with gaps in linear approximation both in Fourier and in physical space, explicitly incorporating the disk non-uniformity in the fluid equations. Density gradients strongly displace the positions of Lindblad resonances in the disk (which often occur at multiple locations), and the waveforms of modes excited close to the gap edge get modified compared to the uniform disk case. The spatial distribution of the excitation torque density is found to be quite different from the existing prescriptions: most of the torque is exerted in a rather narrow region near the gap edge where Lindblad resonances accumulate, followed by an exponential falloff with the distance from the perturber. Despite these differences, for a given gap profile, the full integrated torque exerted on the disk agrees with the conventional uniform disk theory prediction at the level of ∼10%. The nonlinearity of the density wave excited by the perturber is shown to decrease as the wave travels out of the gap, slowing down its nonlinear evolution and damping. Our results suggest that gap opening in protoplanetary disks and gas clearing around SMBH binaries can be more efficient than the existing theories predict. They pave the way for self-consistent calculations of the gap structure and the orbital evolution of the perturber using accurate prescription for the torque density behavior.

  15. Observations of homogeneous phase separation in liquid He3-He4 mixtures

    Science.gov (United States)

    Hoffer, J. K.; Campbell, L. J.; Bartlett, R. J.

    1980-01-01

    The so-called miscibility gap that exists below the critical point in liquid He-3 - H-4 mixtures makes it possible to study binary phase composition, and the ensuing dispersions, in a system possessing an additional order parameter in one of the components. The physical behavior of a superfluid dispersion produced by pressure quenching an He-3 - He-4 mixture into the miscibility gap is described. The description applies both to quenches of homogeneous and phase-separated initial states in various regions of the miscibility gap.

  16. Calcium nitrate miscible displacement at different concentrations in packed soil columns

    Science.gov (United States)

    Previatello da Silva, Livia; Alves de Oliveira, Luciano; Honorio de Miranda, Jarbas

    2015-04-01

    Studies on miscible displacement provide us with rational means to understand the important physical phenomena involved leaching in soils, fertilizers, movement of ions and other similar processes. With current environmental concerns and the need to understand the processes that govern movement of water and solutes in soil, studies are needed to allow increasing the efficiency of input use in agriculture that somehow can mitigate the impact of activities of this sector on groundwater contamination. Contamination of soil and groundwater and surface water in areas with fertilizer application and reuse of effluent is closely linked to materials chemical characteristics, and retention and transmission of water and soil solutes. Solute mobility in soil is inversely related to their adsorption to solid fraction or to environmental conditions that favor ions precipitation. Ion adsorption to soil exchange complex makes ion maintains exchange with the soil solution, providing once their retention by the solid fraction, another its availability in aqueous medium. Nitrate leaching is a physical phenomenon, favored by low energy involved in adsorption to soil particles and also by its high solubility in water. This high solubility and the weak interaction with soil matrix to allow anion follow the wetting front. Therefore, the objective was determine nitrate transport parameters in soil, through Breakthrough Curves (BTC) development under conditions of disturbed soil samples (saturated soil and steady state conditions) in columns (20.0 cm in height and 5 cm in diameter), by calcium nitrate solution application at two concentrations, 50 and 130 g m-3 NO3-, in two tropical soil types, Yellow Oxisol (S1) and Anfisol (S2). Research was carried out in laboratory. Transport parameters for both soils and nitrate concentrations were obtained by numerical fit using STANMOD software, by the inverse modelling. Results showed predominance of convective transport in S1, which had a higher

  17. Detached cataclysmic variables are crossing the orbital period gap

    Science.gov (United States)

    Zorotovic, M.; Schreiber, M. R.; Parsons, S. G.; Gänsicke, B. T.; Hardy, A.; Agurto-Gangas, C.; Nebot Gómez-Morán, A.; Rebassa-Mansergas, A.; Schwope, A. D.

    2016-04-01

    A central hypothesis in the theory of cataclysmic variable (CV) evolution is the need to explain the observed lack of accreting systems in the ≃2-3 h orbital period range, known as the period gap. The standard model, disrupted magnetic braking (DMB), reproduces the gap by postulating that CVs transform into inconspicuous detached white dwarf (WD) plus main sequence systems, which no longer resemble CVs. However, observational evidence for this standard model is currently indirect and thus this scenario has attracted some criticism throughout the last decades. Here, we perform a simple but exceptionally strong test of the existence of detached CVs (dCVs). If the theory is correct, dCVs should produce a peak in the orbital period distribution of detached close binaries consisting of a WD and an M4-M6 secondary star. We measured six new periods which brings the sample of such binaries with known periods below 10 h to 52 systems. An increase of systems in the ≃2-3 h orbital period range is observed. Comparing this result with binary population models, we find that the observed peak cannot be reproduced by post-common envelope binaries (PCEBs) alone and that the existence of dCVs is needed to reproduce the observations. Also, the WD mass distribution in the gap shows evidence of two populations in this period range, i.e. PCEBs and more massive dCVs, which is not observed at longer periods. We therefore conclude that CVs are indeed crossing the gap as detached systems, which provides strong support for the DMB theory.

  18. Magnetic binary nanofillers

    International Nuclear Information System (INIS)

    Magnetic binary nanofillers containing multiwall carbon nanotubes (MWCNT) and hercynite were synthesized by Chemical Vapor Deposition (CVD) on Fe/AlOOH prepared by the sol-gel method. The catalyst precursor was fired at 450 °C, ground and sifted through different meshes. Two powders were obtained with different particle sizes: sample A (50-75 μm) and sample B (smaller than 50 μm). These powders are composed of iron oxide particles widely dispersed in the non-crystalline matrix of aluminum oxide and they are not ferromagnetic. After reduction process the powders are composed of α-Fe nanoparticles inside hercynite matrix. These nanofillers are composed of hercynite containing α-Fe nanoparticles and MWCNT. The binary magnetic nanofillers were slightly ferromagnetic. The saturation magnetization of the nanofillers depended on the powder particle size. The nanofiller obtained from powder particles in the range 50-75 μm showed a saturation magnetization 36% higher than the one formed from powder particles smaller than 50 μm. The phenomenon is explained in terms of changes in the magnetic environment of the particles as consequence of the presence of MWCNT.

  19. Computing on Binary Strings

    CERN Document Server

    Bu, Tian-Ming; Zhang, Peng

    2011-01-01

    Many problems in Computer Science can be abstracted to the following question: given a set of objects and rules respectively, which new objects can be produced? In the paper, we consider a succinct version of the question: given a set of binary strings and several operations like conjunction and disjunction, which new binary strings can be generated? Although it is a fundamental problem, to the best of our knowledge, the problem hasn't been studied yet. In this paper, an O(m^2n) algorithm is presented to determine whether a string s is representable by a set W, where n is the number of strings in W and each string has the same length m. However, looking for the minimum subset from a set to represent a given string is shown to be NP-hard. In addition, we prove that counting the number of strings representable is #P-complete. But if the operator negation can be used, the number is some power of 2. This di?erence maybe help us understand the problem more profoundly.

  20. Effect of stratification on segregation in carbon dioxide miscible flooding in a water-flooded oil reservoir

    International Nuclear Information System (INIS)

    Oil reservoirs are subjected to tertiary recovery by deploying any enhanced oil recovery (EOR) technique for the recovery of left over oil. Amongst many EOR methods one of the widely applied worldwide is CO/sub 2/ flooding through miscible, near miscible or immiscible displacement processes. CO/sub 2/ flooding process responds to a number of reservoir and fluid characteristics. These characteristics have strong effect on overall efficiency of the displacement process. Better understanding of the effect of different characteristics on displacement process is important to plan an efficient displacement process. In this work, the effect of stratification resulting in gravity segregation of the injected fluid is studied in an oil reservoir which is water-flooded during secondary phase of recovery. Sensitivity analysis is performed through successive simulation on Eclipse 300 (compositional) reservoir simulator. Process involves the continuous CO/sub 2/ injection in an oil reservoir with more than 1/3rd of original oil in place left after water flooding. Reservoir model with four different permeability layers is studied. Four patterns by changing the arrangement of the permeabilities of the layers are analysed. The effect of different arrangement or stratification on segregation of CO/sub 2/ and ultimately on the incremental oil recovery, is investigated. It has been observed that out of four arrangements, upward fining pattern relatively overcame the issue of the segregation of CO/sub 2/ and consequently 33% more oil with half injection volume is recovered when compared with the downward fining pattern. (author)

  1. Relativistic Binaries in Globular Clusters

    Directory of Open Access Journals (Sweden)

    Benacquista Matthew J.

    2006-02-01

    Full Text Available The galactic population of globular clusters are old, dense star systems, with a typical cluster containing 10^4 - 10^7 stars. As an old population of stars, globular clusters contain many collapsed and degenerate objects. As a dense population of stars, globular clusters are the scene of many interesting close dynamical interactions between stars. These dynamical interactions can alter the evolution of individual stars and can produce tight binary systems containing one or two compact objects. In this review, we discuss the theoretical models of globular cluster evolution and binary evolution, techniques for simulating this evolution which lead to relativistic binaries, and current and possible future observational evidence for this population. Globular cluster evolution will focus on the properties that boost the production of hard binary systems and on the tidal interactions of the galaxy with the cluster, which tend to alter the structure of the globular cluster with time. The interaction of the components of hard binary systems alters the evolution of both bodies and can lead to exotic objects. Direct N-body integrations and Fokker-Planck simulations of the evolution of globular clusters that incorporate tidal interactions and lead to predictions of relativistic binary populations are also discussed. We discuss the current observational evidence for cataclysmic variables, millisecond pulsars, and low-mass X-ray binaries as well as possible future detection of relativistic binaries with gravitational radiation.

  2. Relativistic Binaries in Globular Clusters

    Directory of Open Access Journals (Sweden)

    Matthew J. Benacquista

    2013-03-01

    Full Text Available Galactic globular clusters are old, dense star systems typically containing 10^4 – 10^6 stars. As an old population of stars, globular clusters contain many collapsed and degenerate objects. As a dense population of stars, globular clusters are the scene of many interesting close dynamical interactions between stars. These dynamical interactions can alter the evolution of individual stars and can produce tight binary systems containing one or two compact objects. In this review, we discuss theoretical models of globular cluster evolution and binary evolution, techniques for simulating this evolution that leads to relativistic binaries, and current and possible future observational evidence for this population. Our discussion of globular cluster evolution will focus on the processes that boost the production of tight binary systems and the subsequent interaction of these binaries that can alter the properties of both bodies and can lead to exotic objects. Direct N-body integrations and Fokker–Planck simulations of the evolution of globular clusters that incorporate tidal interactions and lead to predictions of relativistic binary populations are also discussed. We discuss the current observational evidence for cataclysmic variables, millisecond pulsars, and low-mass X-ray binaries as well as possible future detection of relativistic binaries with gravitational radiation.

  3. PERIODIC COMPLEMENTARY BINARY SEQUENCE PAIRS

    Institute of Scientific and Technical Information of China (English)

    XuChengqian; ZhaoXiaoqun

    2002-01-01

    A new set of binary sequences-Periodic Complementary Binary Sequence Pair (PCSP)is proposed .A new class of block design-Difference Family Pair (DFP)is also proposed .The relationship between PCSP and DFP,the properties and exising conditions of PCSP and the recursive constructions for PCSP are given.

  4. PERIODIC COMPLEMENTARY BINARY SEQUENCE PAIRS

    Institute of Scientific and Technical Information of China (English)

    Xu Chengqian; Zhao Xiaoqun

    2002-01-01

    A new set of binary sequences-Periodic Complementary Binary Sequence Pair (PCSP) is proposed. A new class of block design-Difference Family Pair (DFP) is also proposed.The relationship between PCSP and DFP, the properties and existing conditions of PCSP and the recursive constructions for PCSP are given.

  5. Pairing mechanisms for binary stars

    CERN Document Server

    Kouwenhoven, M B N; Goodwin, S P; Zwart, S F Portegies; Kaper, L; 10.1002/asna.200811061

    2008-01-01

    Knowledge of the binary population in stellar groupings provides important information about the outcome of the star forming process in different environments. Binarity is also a key ingredient in stellar population studies and is a prerequisite to calibrate the binary evolution channels. In these proceedings we present an overview of several commonly used methods to pair individual stars into binary systems, which we refer to as the pairing function. Many pairing functions are frequently used by observers and computational astronomers, either for the mathematical convenience, or because they roughly describe the expected outcome of the star forming process. We discuss the consequences of each pairing function for the interpretation of observations and numerical simulations. The binary fraction and mass ratio distribution generally depend strongly on the selection of the range in primary spectral type in a sample. These quantities, when derived from a binary survey with a mass-limited sample of target stars, ...

  6. Planets in Binary Star Systems

    CERN Document Server

    Haghighipour, Nader

    2010-01-01

    The discovery of extrasolar planets over the past decade has had major impacts on our understanding of the formation and dynamical evolution of planetary systems. There are features and characteristics unseen in our solar system and unexplainable by the current theories of planet formation and dynamics. Among these new surprises is the discovery of planets in binary and multiple-star systems. The discovery of such "binary-planetary" systems has confronted astrodynamicists with many new challenges, and has led them to re-examine the theories of planet formation and dynamics. Among these challenges are: How are planets formed in binary star systems? What would be the notion of habitability in such systems? Under what conditions can binary star systems have habitable planets? How will volatiles necessary for life appear on such planets? This volume seeks to gather the current research in the area of planets in binary and multistar systems and to familiarize readers with its associated theoretical and observation...

  7. Bridging a cultural gap

    Science.gov (United States)

    Leviatan, Talma

    2008-09-01

    There has been a broad wave of change in tertiary calculus courses in the past decade. However, the much-needed change in tertiary pre-calculus programmes—aimed at bridging the gap between high-school mathematics and tertiary mathematics—is happening at a far slower pace. Following a discussion on the nature of the gap and the objectives of a potential bridging programme, this paper aims at demonstrating that the gap can be bridged, by presenting an ongoing modular bridging programme especially designed for the diverse types of student populations in teachers training colleges. We also present here some innovative teaching and assessment methods that were judged essential for the success of these programmes—focusing mainly on the "Questionnaire Based Instruction Method". Finally we suggest directions of follow up and research.

  8. Erraticity of rapidity gaps

    International Nuclear Information System (INIS)

    The use of rapidity gaps is proposed as a measure of the spatial pattern of an event. When the event multiplicity is low, the gaps between neighboring particles carry far more information about an event than multiplicity spikes, which may occur very rarely. Two moments of the gap distribution are suggested for characterizing an event. The fluctuations of those moments from event to event are then quantified by an entropy-like measure, which serves to describe erraticity. We use ECOMB to simulate the exclusive rapidity distribution of each event, from which the erraticity measures are calculated. The dependences of those measures on the order q of the moments provide single-parameter characterizations of erraticity. (c) 2000 The American Physical Society

  9. Towards Physarum Binary Adders

    CERN Document Server

    Jones, Jeff; 10.1016/j.biosystems.2010.04.005

    2010-01-01

    Plasmodium of \\emph{Physarum polycephalum} is a single cell visible by unaided eye. The plasmodium's foraging behaviour is interpreted in terms of computation. Input data is a configuration of nutrients, result of computation is a network of plasmodium's cytoplasmic tubes spanning sources of nutrients. Tsuda et al (2004) experimentally demonstrated that basic logical gates can be implemented in foraging behaviour of the plasmodium. We simplify the original designs of the gates and show --- in computer models --- that the plasmodium is capable for computation of two-input two-output gate $ \\to $ and three-input two-output $ \\to $. We assemble the gates in a binary one-bit adder and demonstrate validity of the design using computer simulation.

  10. Eccentric Binary Millisecond Pulsars

    CERN Document Server

    Freire, Paulo C C

    2009-01-01

    In this paper we review the recent discovery of several millisecond pulsars (MSPs) in eccentric binary systems. Timing these MSPs we were able to estimate (and in one case precisely measure) their masses. These results suggest that, as a class, MSPs have a much wider range of masses (1.3 to > 2 solar masses) than the normal and mildly recycled pulsars found in double neutron star (DNS) systems (1.25 < Mp < 1.44 solar masses). This is very likely to be due to the prolonged accretion episode that is thought to be required to form a MSP. The likely existence of massive MSPs makes them a powerful probe for understanding the behavior of matter at densities larger than that of the atomic nucleus; in particular, the precise measurement of the mass of PSR J1903+0327 ($1.67 +/- 0.01 solar masses) excludes several "soft" equations of state for dense matter.

  11. Binaries and distances

    Science.gov (United States)

    Pourbaix, D.; Arenou, F.; Halbwachs, J.-L.; Siopis, C.

    2013-02-01

    Gaia's five-year observation baseline might naively lead to the expectation that it will be possible to fit the parallax of any sufficiently nearby object with the default five-parameter model (position at a reference epoch, parallax and proper motion). However, simulated Gaia observations of a `model Universe' composed of nearly 107 objects, 50% of which turn out to be multiple stars, show that the single-star hypothesis can severely affect parallax estimation and that more sophisticated models must be adopted. In principle, screening these spurious single-star solutions is rather straightforward, for example by evaluating the quality of the fits. However, the simulated Gaia observations also reveal that some seemingly acceptable single-star solutions can nonetheless lead to erroneous distances. These solutions turn out to be binaries with an orbital period close to one year. Without auxiliary (e.g., spectroscopic) data, they will remain unnoticed.

  12. A self-consistent optimization of multicomponent solution properties: ab initio molecular dynamic simulations and the MgO-SiO_2 miscibility gap under pressure

    OpenAIRE

    Harvey, Jean-Phillipe; Aïmen E. Gheribi; Asimow, Paul D.

    2015-01-01

    We propose a new approach to parameterizing the Gibbs energy of a multicomponent solution as a function of temperature, pressure and composition. It uses the quasichemical model in the second nearest neighbour approximation and considers both a polynomial representation (for low pressure) and an exponential decay representation (for moderate-to-high pressure) of the excess molar volume v^(xs) to extend thermodynamic behaviour to elevated pressure. This approach differs from previous configura...

  13. The longevity gender gap

    DEFF Research Database (Denmark)

    Aviv, Abraham; Shay, Jerry; Christensen, Kaare;

    2005-01-01

    In this Perspective, we focus on the greater longevity of women as compared with men. We propose that, like aging itself, the longevity gender gap is exceedingly complex and argue that it may arise from sex-related hormonal differences and from somatic cell selection that favors cells more...... resistant to the ravages of time. We discuss the interplay of these factors with telomere biology and oxidative stress and suggest that an explanation for the longevity gender gap may arise from a better understanding of the differences in telomere dynamics between men and women....

  14. 'Mind the Gap!'

    DEFF Research Database (Denmark)

    Persson, Karl Gunnar

    This paper challenges the widely held view that sharply falling real transport costs closed the transatlantic gap in grain prices in the second half of the 19th century. Several new results emerge from an analysis of a new data set of weekly wheat prices and freight costs from New York to UK mark...

  15. Estimating Gender Wage Gaps

    Science.gov (United States)

    McDonald, Judith A.; Thornton, Robert J.

    2011-01-01

    Course research projects that use easy-to-access real-world data and that generate findings with which undergraduate students can readily identify are hard to find. The authors describe a project that requires students to estimate the current female-male earnings gap for new college graduates. The project also enables students to see to what…

  16. Indirectly suspended droplet microextraction of water-miscible organic solvents by salting-out effect for the determination of polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Daneshfar, Ali; Khezeli, Tahere

    2014-12-01

    A simple and low-cost method that indirectly suspended droplet microextraction of water-miscible organic solvents (ISDME) by salting-out effect before high-performance liquid chromatography and ultraviolet (HPLC-UV) detection was used for the determination of polycyclic aromatic hydrocarbons (PAHs) in different samples. The ISDME is a combination of salting-out extraction of water-miscible organic solvent and directly suspended droplet microextraction (DSDME). Ninety-five microliters water-miscible organic solvent (1-propanol) was added to a 500-µL sample. A homogeneous solution was formed immediately. To produce a steady vortex at the top of the solution, the sample was agitated at 700 rpm using a magnetic stirrer. By the addition of ammonium sulfate (saturated solution) to the homogeneous solution, 1-propanol was separated and collected at the bottom of the steady vortex. Finally, 20 µL 1-propanol was injected into HPLC-UV. The effects of important parameters such as water-miscible organic solvent (type and volume), type of salt, and extraction time were evaluated. Under optimum conditions, the method has a good linear calibration range (0.1 µg/L-300 µg/L), coefficients of determination (R(2) > 0.998), low limits of detection (between 0.02 µg/L and 0.27 µg/L), and acceptable recovery (>85.0%). PMID:25242239

  17. Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal - Appendix)

    Energy Technology Data Exchange (ETDEWEB)

    Bou-Mikael, Sami

    2002-02-05

    The main objective of the Port Neches Project was to determine the feasibility and producibility of CO2 miscible flooding techniques enhanced with horizontal drilling applied to a Fluvial Dominated Deltaic reservoir. The second was to disseminate the knowledge gained through established Technology Transfer mechanisms to support DOE's programmatic objectives of increasing domestic oil production and reducing abandonment of oil fields.

  18. Effects of Water Miscible Organic Solvents on the Activity and Conformation of the Baeyer-Villiger Monooxygenases From Thermobifida fusca and Acinetobacter calcoaceticus : A Comparative Study

    NARCIS (Netherlands)

    Secundo, Francesco; Fiala, Stefano; Fraaije, Marco W.; de Gonzalo, Gonzalo; Meli, Massimiliano; Zambianchi, Francesca; Ottolina, Gianluca

    2011-01-01

    A broader exploitation of enzymes in organic synthesis can be achieved by increasing their tolerance toward organic solvents. In this study, the stability and activity of Baeyer-Villiger monooxygenases from Thermobifida fusca (PAMO) and Acinetobacter sp. (CHMO) in the presence of water miscible orga

  19. Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I

    Energy Technology Data Exchange (ETDEWEB)

    Bou-Mikael, Sami

    2002-02-05

    This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field.

  20. Minimum miscibility pressure estimation for a CO{sub 2}/n-decane system in porous media by X-ray CT

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yu; Jiang, Lanlan; Tang, Lingyue; Song, Yongchen; Zhao, Jiafei; Zhang, Yi; Wang, Dayong; Yang, Mingjun [Dalian University of Technology, Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian (China)

    2015-07-15

    Accurate determination of gas-fluid miscibility conditions is important to optimize the displacement efficiency during CO{sub 2}-enhanced oil recovery. This paper presents a new technique to investigate the phase behavior and to estimate the minimum miscibility pressure (MMP) of a CO{sub 2}/n-decane system using an X-ray computerized tomography (CT) scanner. CT scans of the CO{sub 2}/n-decane system are taken at various pressures during the experiments. The image intensity values taken from the CT images have a linear relationship with the densities of the measured objects; therefore, we can estimate the miscible point of CO{sub 2} and n-decane because the difference between the intensity values for each phase decays to zero as the pressure increases toward the MMP. This paper provides experimental evidence for the validity of the new CT method by comparing the results with previous studies and presents an application of the method to investigate the MMP of the CO{sub 2}/n-decane system in porous media. Additionally, the influence of porous media on the equilibrium state when the CO{sub 2}/n-decane system is close to miscibility is discussed. (orig.)

  1. Effects of ethyl and benzyl groups on the miscibility and properties of castor oil-based polyurethane/starch derivative semi-interpenetrating polymer networks.

    Science.gov (United States)

    Cao, Xiaodong; Wang, Yixiang; Zhang, Lina

    2005-09-16

    Cornstarch derivative (ES), prepared using diethyl sulfate as an etherifying reagent, was blended with castor oil-based polyurethane (PU) prepolymer to obtain a series of semi-interpenetrating polymer network (semi-IPN) materials, named as UES films. Simultaneously, other kinds of semi-IPN (UBS2) were prepared from PU and benzyl starch (BS2) to compare the effects of the substitute groups. The differences in the miscibility and properties of the two series of materials were investigated using attenuated total reflection Fourier transform infrared spectroscopy, atomic force microscopy, dynamic mechanical thermal analysis, ultraviolet-visible spectroscopy, water-sensitivity and tensile testing. The experimental results revealed that UBS2 films exhibit stronger interfacial attraction and better phase mixing than the UES films, as a result of specific interactions between the PU hard segments and BS2 phenyl groups. The optical transmittance, water-resistivity, tensile strength, and elongation at break of the UBS2 films were clearly higher than those of the UES films containing the same concentration of PU. In particular, the miscibility and properties of the UES film with 40 wt.-% ES, were very poor, whereas the semi-IPN films containing 70 wt.-% benzyl starch still had a certain miscibility and good properties. Therefore, the phenyl groups play an important role in the improvement of the miscibility and properties of the semi-IPN materials. PMID:16143996

  2. Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal - Appendix); FINAL

    International Nuclear Information System (INIS)

    The main objective of the Port Neches Project was to determine the feasibility and producibility of CO2 miscible flooding techniques enhanced with horizontal drilling applied to a Fluvial Dominated Deltaic reservoir. The second was to disseminate the knowledge gained through established Technology Transfer mechanisms to support DOE's programmatic objectives of increasing domestic oil production and reducing abandonment of oil fields

  3. Post Waterflood CO2 Miscible Flood in Light Oil, Fluvial-Dominated Deltaic Reservoir (Pre-Work and Project Proposal), Class I; FINAL

    International Nuclear Information System (INIS)

    This project outlines a proposal to improve the recovery of light oil from waterflooded fluvial dominated deltaic (FDD) reservoir through a miscible carbon dioxide (CO2) flood. The site is the Port Neches Field in Orange County, Texas. The field is well explored and well exploited. The project area is 270 acres within the Port Neches Field

  4. Expected gaps between prime numbers

    OpenAIRE

    Holt, Fred B.

    2007-01-01

    We study the gaps between consecutive prime numbers directly through Eratosthenes sieve. Using elementary methods, we identify a recursive relation for these gaps and for specific sequences of consecutive gaps, known as constellations. Using this recursion we can estimate the numbers of a gap or of a constellation that occur between a prime and its square. This recursion also has explicit implications for open questions about gaps between prime numbers, including three questions posed by Erd\\...

  5. Mathematical and numerical analysis of a multi-velocity multi-fluid model for interpenetration of miscible fluids; Analyse mathematique et numerique d'un modele multifluide multivitesse pour l'interpenetration de fluides miscibles

    Energy Technology Data Exchange (ETDEWEB)

    Enaux, C

    2007-11-15

    The simulation of indirect laser implosion requires an accurate knowledge of the inter-penetration of the laser target materials turned into plasma. This work is devoted to the study of a multi-velocity multi-fluid model recently proposed by Scannapieco and Cheng (SC) to describe the inter-penetration of miscible fluids. In this document, we begin with presenting the SC model in the context of miscible fluids flow modelling. Afterwards, the mathematical analysis of the model is carried out (study of the hyperbolicity, existence of a strictly convex mathematical entropy, asymptotic analysis and diffusion limit). As a conclusion the problem is well set. Then, we focus on the problem of numerical resolution of systems of conservation laws with a relaxation source term, because SC model belongs to this class. The main difficulty of this task is to capture on a coarse grid the asymptotic behaviour of the system when the source term is stiff. The main contribution of this work lies in the proposition of a new technique, allowing us to construct a Lagrangian numerical flux taking into account the presence of the source term. This technique is applied first on the model-problem of a one-dimensional Euler system with friction, and then on the multi-fluid SC model. In both cases, we prove that the new scheme is asymptotic-preserving and entropic under a CFL-like condition. The two-dimensional extension of the scheme is done by using a standard alternate directions method. Some numerical results highlight the contribution of the new flux, compared with a standard Lagrange plus Remap scheme where the source term is processed using an operator splitting. (author)

  6. Binary black hole spectroscopy

    International Nuclear Information System (INIS)

    We study parameter estimation with post-Newtonian (PN) gravitational waveforms for the quasi-circular, adiabatic inspiral of spinning binary compact objects. In particular, the performance of amplitude-corrected waveforms is compared with that of the more commonly used restricted waveforms, in Advanced LIGO and EGO. With restricted waveforms, the properties of the source can only be extracted from the phasing. In the case of amplitude-corrected waveforms, the spectrum encodes a wealth of additional information, which leads to dramatic improvements in parameter estimation. At distances of ∼100 Mpc, the full PN waveforms allow for high-accuracy parameter extraction for total mass up to several hundred solar masses, while with the restricted ones the errors are steep functions of mass, and accurate parameter estimation is only possible for relatively light stellar mass binaries. At the low-mass end, the inclusion of amplitude corrections reduces the error on the time of coalescence by an order of magnitude in Advanced LIGO and a factor of 5 in EGO compared to the restricted waveforms; at higher masses these differences are much larger. The individual component masses, which are very poorly determined with restricted waveforms, become measurable with high accuracy if amplitude-corrected waveforms are used, with errors as low as a few per cent in Advanced LIGO and a few tenths of a per cent in EGO. The usual spin-orbit parameter β is also poorly determined with restricted waveforms (except for low-mass systems in EGO), but the full waveforms give errors that are small compared to the largest possible value consistent with the Kerr bound. This suggests a way of finding out if one or both of the component objects violate this bound. On the other hand, we find that the spin-spin parameter σ remains poorly determined even when the full waveform is used. Generally, all errors have but a weak dependence on the magnitudes and orientations of the spins. We also briefly

  7. Disk-satellite interaction in disks with density gaps

    CERN Document Server

    Petrovich, Cristobal

    2012-01-01

    Gravitational coupling between a gaseous disk and an orbiting perturber leads to angular momentum exchange between them which can result in gap opening by planets in protoplanetary disks and clearing of gas by binary supermassive black holes (SMBHs) embedded in accretion disks. Understanding the co-evolution of the disk and the orbit of the perturber in these circumstances requires knowledge of the spatial distribution of the torque exerted by the latter on a highly nonuniform disk. Here we explore disk-satellite interaction in disks with gaps in linear approximation both in Fourier and in physical space, explicitly incorporating the disk non-uniformity in the fluid equations. Density gradients strongly displace the positions of Lindblad resonances in the disk (which often occur at multiple locations), and the waveforms of modes excited close to the gap edge get modified compared to the uniform disk case. The spatial distribution of the excitation torque density is found to be quite different from the existin...

  8. Strong Lensing by Binary Galaxies

    CERN Document Server

    Shin, E M

    2008-01-01

    We study the problem of gravitational lensing by binary galaxies, idealized as two isothermal spheres. In a wide binary, each galaxy possesses individual tangential, nearly astroidal, caustics and roundish radial caustics. As the separation of the binary is made smaller, the caustics undergo a sequence of metamorphoses. The first metamorphosis occurs when the tangential caustics merge to form a single six-cusped caustic, lying interior to the radial caustics. At still smaller separations, the six-cusped caustic undergoes the second metamorphosis and splits into a four-cusped caustic and two three-cusped caustics, which shrink to zero size (an elliptic umbilic catastrophe) before they enlarge again and move away from the origin perpendicular to the binary axis. Finally, a third metamorphosis occurs as the three-cusp caustics join the radial caustics, leaving an inner distorted astroid caustic enclosed by two outer caustics. The maximum number of images possible is 7. Classifying the multiple imaging according ...

  9. Magnetic braking in ultracompact binaries

    CERN Document Server

    Farmer, Alison

    2010-01-01

    Angular momentum loss in ultracompact binaries, such as the AM Canum Venaticorum stars, is usually assumed to be due entirely to gravitational radiation. Motivated by the outflows observed in ultracompact binaries, we investigate whether magnetically coupled winds could in fact lead to substantial additional angular momentum losses. We remark that the scaling relations often invoked for the relative importance of gravitational and magnetic braking do not apply, and instead use simple non-empirical expressions for the braking rates. In order to remove significant angular momentum, the wind must be tied to field lines anchored in one of the binary's component stars; uncertainties remain as to the driving mechanism for such a wind. In the case of white dwarf accretors, we find that magnetic braking can potentially remove angular momentum on comparable or even shorter timescales than gravitational waves over a large range in orbital period. We present such a solution for the 17-minute binary AM CVn itself which a...

  10. Discs in misaligned binary systems

    CERN Document Server

    Rawiraswattana, Krisada; Goodwin, Simon P

    2016-01-01

    We perform SPH simulations to study precession and changes in alignment between the circumprimary disc and the binary orbit in misaligned binary systems. We find that the precession process can be described by the rigid-disc approximation, where the disc is considered as a rigid body interacting with the binary companion only gravitationally. Precession also causes change in alignment between the rotational axis of the disc and the spin axis of the primary star. This type of alignment is of great important for explaining the origin of spin-orbit misaligned planetary systems. However, we find that the rigid-disc approximation fails to describe changes in alignment between the disc and the binary orbit. This is because the alignment process is a consequence of interactions that involve the fluidity of the disc, such as the tidal interaction and the encounter interaction. Furthermore, simulation results show that there are not only alignment processes, which bring the components towards alignment, but also anti-...

  11. Cryptography with DNA binary strands.

    Science.gov (United States)

    Leier, A; Richter, C; Banzhaf, W; Rauhe, H

    2000-06-01

    Biotechnological methods can be used for cryptography. Here two different cryptographic approaches based on DNA binary strands are shown. The first approach shows how DNA binary strands can be used for steganography, a technique of encryption by information hiding, to provide rapid encryption and decryption. It is shown that DNA steganography based on DNA binary strands is secure under the assumption that an interceptor has the same technological capabilities as sender and receiver of encrypted messages. The second approach shown here is based on steganography and a method of graphical subtraction of binary gel-images. It can be used to constitute a molecular checksum and can be combined with the first approach to support encryption. DNA cryptography might become of practical relevance in the context of labelling organic and inorganic materials with DNA 'barcodes'. PMID:10963862

  12. Effect of solute interaction on interfacial and grain boundary embrittlement in binary alloys

    Czech Academy of Sciences Publication Activity Database

    Lejček, Pavel

    2013-01-01

    Roč. 48, č. 6 (2013), 2574-2580. ISSN 0022-2461 R&D Projects: GA ČR GAP108/12/0144 Institutional research plan: CEZ:AV0Z10100520 Keywords : interfacial segregation * grain boundary embrittlement * binary interaction * modeling * thermodynamics Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.305, year: 2013

  13. Miscibility and crystallization behavior of poly (3-hydroxybutyrate) and poly (ethylene glycol) blends studied by positron annihilation spectroscopy

    International Nuclear Information System (INIS)

    Positron annihilation Lifetime (PAL) spectroscopy has been used to study the effect of PEG concentrations on the free volume properties of PHB. The data revealed that the ortho-positronium (o-Ps) lifetime τPs increases with 20% increase in concentration, decrease as the concentration increases to 40%, then rapid increase at 50% concentration of PEG. The o-Ps intensity, I3, shows a linear dependence as the concentration increases with a discontinuity at 20% concentration of PEG. Furthermore, the results presented and discussed in this work show that the PHB and PEG are miscible up to 40% of PEG but greater than 40%, the blend is immiscible. In addition, the mechanical properties of PHB are well improved by the addition of PEG with a low concentration up to 20%, while at higher concentration the blend becomes waxy.

  14. Miscibility and crystallization behavior of poly (3-hydroxybutyrate) and poly (ethylene glycol) blends studied by positron annihilation spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Hady, E E; Abdel-Hamed, M O; Hammam, A M, E-mail: esamhady@yahoo.com [Physics Department, Faculty of Science, Minia University, Minia (Egypt)

    2011-01-01

    Positron annihilation Lifetime (PAL) spectroscopy has been used to study the effect of PEG concentrations on the free volume properties of PHB. The data revealed that the ortho-positronium (o-Ps) lifetime {tau}{sub Ps} increases with 20% increase in concentration, decrease as the concentration increases to 40%, then rapid increase at 50% concentration of PEG. The o-Ps intensity, I{sub 3}, shows a linear dependence as the concentration increases with a discontinuity at 20% concentration of PEG. Furthermore, the results presented and discussed in this work show that the PHB and PEG are miscible up to 40% of PEG but greater than 40%, the blend is immiscible. In addition, the mechanical properties of PHB are well improved by the addition of PEG with a low concentration up to 20%, while at higher concentration the blend becomes waxy.

  15. Miscibility and crystallization behavior of poly (3-hydroxybutyrate) and poly (ethylene glycol) blends studied by positron annihilation spectroscopy

    Science.gov (United States)

    Abdel-Hady, E. E.; Abdel-Hamed, M. O.; Hammam, A. M.

    2011-01-01

    Positron annihilation Lifetime (PAL) spectroscopy has been used to study the effect of PEG concentrations on the free volume properties of PHB. The data revealed that the ortho-positronium (o-Ps) lifetime τPs increases with 20% increase in concentration, decrease as the concentration increases to 40%, then rapid increase at 50% concentration of PEG. The o-Ps intensity, I3, shows a linear dependence as the concentration increases with a discontinuity at 20% concentration of PEG. Furthermore, the results presented and discussed in this work show that the PHB and PEG are miscible up to 40% of PEG but greater than 40%, the blend is immiscible. In addition, the mechanical properties of PHB are well improved by the addition of PEG with a low concentration up to 20%, while at higher concentration the blend becomes waxy.

  16. Effect of Melt Miscibility on Crystallization and Melting of Blends of Different Polyethylenes: Small Angle Light Scattering (SALS) Studies

    Science.gov (United States)

    Akpalu, Y.; Stein, R. S.; Muthukumar, M.; Hsiao, B.

    1997-03-01

    We have performed time resolved SALS in the HV and VV polarization modes during crystallization and melting of blends of a linear ( ~ 1 branch per 1000 backbone carbon atoms) ethylene-octene copolymer with branched ethylene copolymers. During melting, we observe a monotonic decrease in the HV and VV invariants when the branched content of the branched copolymer is low (copolymer is high (> 50 branches per 1000 backbone carbon atoms). These observations are in agreement with known theoretically predicted intensity variations during melting of crystals formed from miscible and immiscible melts respectively. We will discuss the results of our studies in relation to the theoretical predictions, and correlate changes in the crystallization mechanism with phase separation.

  17. Studies of miscibility and specific interactions of antitumor-active anhydride copolymer and poly(ethylene glycol) blends.

    Science.gov (United States)

    Can, Hatice Kaplan; Parvizikhosroshahi, Shahed; Uluışık, Erdem C

    2016-01-01

    The blending of polymers is of great interest, since the modification gives rise to diverse physical properties with the functionality of a polymer, without synthesis. Water-soluble antitumor-active poly(maleic anhydride-alt-acrylic acid) poly(MA-alt-AA) and poly(ethylene glycol) (PEG) blends were prepared by casting, and compatible properties were investigated by dilute solution viscometry. Viscosity measurements were made on ternary systems of polymer (1)/polymer (2)/solvent (H2O) and p-dioxane, at different concentrations of PEG and poly(MA-alt-AA). The interaction parameters Δβ, μ, Δk, Δb, β and α, which have been proposed, have been obtained using the viscosity data, to probe the miscibility of the polymer blends. The solid blends prepared were characterized with ATR-FTIR, (1)H-NMR, DTA and TGA. PMID:25406735

  18. Combustion-process derived comparable performances of Zn-(In:Sn)-O thin-film transistors with a complete miscibility

    International Nuclear Information System (INIS)

    Amorphous zinc-indium-tin oxide (a-ZITO) thin-film transistors (TFTs) have been prepared using a low-temperature combustion process, with an emphasis on complete miscibility of In and Sn contents. The a-ZITO TFTs were comparatively studied in detail, especially for the working stability. The a-ZITO TFTs all exhibited acceptable and excellent behaviors from Sn-free TFTs to In-free TFTs. The obtained a-ZTO TFTs presented a field-effect mobility of 1.20 cm2 V−1 s−1, an on/off current ratio of 4.89 × 106, and a long-term stability under positive bias stress, which are comparable with those of the a-ZIO TFTs. The In-free a-ZTO TFTs are very potential for electrical applications with a low cost.

  19. AN IMPROVED DESIGN OF REVERSIBLE BINARY TO BINARY CODED DECIMAL CONVERTER FOR BINARY CODED DECIMAL MULTIPLICATION

    Directory of Open Access Journals (Sweden)

    Praveena Murugesan

    2014-01-01

    Full Text Available Reversible logic gates under ideal conditions produce zero power dissipation. This factor highlights the usage of these gates in optical computing, low power CMOS design, quantum optics and quantum computing. The growth of decimal arithmetic in various applications as stressed the need to propose the study on reversible binary to BCD converter which plays a greater role in decimal multiplication for providing faster results. The different parameters such as gate count,garbage output and constant input are more optimized in the proposed fixed bit binary to binary coded decimal converter than the existing design.

  20. Transient Black Hole Binaries

    CERN Document Server

    Belloni, T M

    2016-01-01

    The last two decades have seen a great improvement in our understand- ing of the complex phenomenology observed in transient black-hole binary systems, especially thanks to the activity of the Rossi X-Ray Timing Explorer satellite, com- plemented by observations from many other X-ray observatories and ground-based radio, optical and infrared facilities. Accretion alone cannot describe accurately the intricate behavior associated with black-hole transients and it is now clear that the role played by different kinds of (often massive) outflows seen at different phases of the outburst evolution of these systems is as fundamental as the one played by the accretion process itself. The spectral-timing states originally identified in the X-rays and fundamentally based on the observed effect of accretion, have acquired new importance as they now allow to describe within a coherent picture the phenomenology observed at other wave- length, where the effects of ejection processes are most evident. With a particular focu...

  1. Binary nucleation beyond capillarity approximation

    OpenAIRE

    Kalikmanov, V.I.

    2010-01-01

    Large discrepancies between binary classical nucleation theory (BCNT) and experiments result from adsorption effects and inability of BCNT, based on the phenomenological capillarity approximation, to treat small clusters. We propose a model aimed at eliminating both of these deficiencies. Adsorption is taken into account within Gibbsian approximation. Binary clusters are treated by means of statistical-mechanical considerations: tracing out the molecular degrees of freedom of the more volatil...

  2. Clostridium difficile binary toxin CDT

    OpenAIRE

    Gerding, Dale N.; Johnson, Stuart; Rupnik, Maja; Aktories, Klaus

    2013-01-01

    Binary toxin (CDT) is frequently observed in Clostridium difficile strains associated with increased severity of C. difficile infection (CDI). CDT belongs to the family of binary ADP-ribosylating toxins consisting of two separate toxin components: CDTa, the enzymatic ADP-ribosyltransferase which modifies actin, and CDTb which binds to host cells and translocates CDTa into the cytosol. CDTb is activated by serine proteases and binds to lipolysis stimulated lipoprotein receptor. ADP-ribosylatio...

  3. Coalescence of Binary Neutron Stars

    OpenAIRE

    Oohara, Ken-ichi; Namamura, Takashi

    1996-01-01

    The most important sources for laser-interferometric gravitational-wave detectors like LIGO or VIRGO are catastrophic events such as coalescence of a neutron-star binary. The final phase, or the last three milliseconds, of coalescence is considered. We describe results of numerical simulations of coalescing binary neutron stars using Newtonian and post-Newtonian hydrodynamics code and then discuss recent development of our 3D GR code.

  4. Band Gap Engineering of Cd1-xBexSe Alloys

    Directory of Open Access Journals (Sweden)

    Djillali Bensaid

    2014-01-01

    Full Text Available The structural and electronic properties of the ternary Cd1-xBexSe alloys have been calculated using the full-potential linear muffin-tin-orbital (FP-LMTO method based on density functional theory within local density approximation (LDA. The calculated equilibrium lattice constants and bulk moduli are compared with previous results. The concentration dependence of the electronic band structure and the direct and indirect band gaps are investigated. Moreover, the refractive index and the optical dielectric constant for Cd1-xBexSe are studied. The thermodynamic stability of the alloys of interest is investigated by means of the miscibility. This is the first quantitative theoretical prediction to investigate the effective masses, optical and thermodynamic properties for Cd1-xBexSe alloy, and still awaits experimental.

  5. Miscibility and alignment effects of mixed monolayer cyanobiphenyl liquid-crystal-capped gold nanoparticles in nematic cyanobiphenyl liquid crystal hosts.

    Science.gov (United States)

    Qi, Hao; Kinkead, Brandy; Marx, Vanessa M; Zhang, Huai R; Hegmann, Torsten

    2009-06-01

    Against the rule: Liquid crystal hosts (5CB and 8CB) are doped with different thiol decorated gold nanoparticles (see figure). The "simple" hexanethiol and dodecanethiol capped nanoparticles (Au1 and Au2) are more compatible to the nematic cyanobiphenyl liquid crystals than nanoparticles capped simultaneously with alkylthiols and a nematic cyanobiphenyl thiol (Au3 and Au4).This study focuses on the miscibility of liquid crystal (LC) decorated gold nanoparticles (NPs) in nematic LCs. To explore if LC functional groups on the gold NP corona improve the compatibility (miscibility) with structurally related LC hosts, we examined mixtures of two LC hosts, 5CB and 8CB, doped at 5 wt % with different types of gold NPs. Four alkanethiol-capped NPs were synthesized; two homogeneously coated with alkanethiols (Au1 with C(6)H(13)SH and Au2 with C(12)H(25)SH), and two that were additionally capped at a different ratio with a mesogenic cyanobiphenyl end-functionalized alkanethiol HS10OCB (C(6)H(13)SH + HS10OCB for Au3 and C(12)H(25)SH + HS10OCB for Au4). Investigating these mixtures in the bulk for settling of the NPs, and in thin films using polarized optical microscopy (POM) between untreated glass slides as well as POM studies and electro-optic tests in planar ITO/polyimide test cells, reveal that the alkanethiol capped NPs Au1 and Au2 are more compatible with the two polar cyanobiphenyl hosts in comparison to the NPs decorated with the cyanobiphenyl moieties. All NPs induce homeotropic alignment in 5CB and 8CB between untreated glass slides, with Au1 and Au2 showing characteristic birefringent stripes, and Au3 and A4 exhibiting clear signs of aggregation. In rubbed polyimide cells, however, Au3 and Au4 fail to induce homeotropic alignment and show clear signs of macroscopic aggregation. PMID:19334026

  6. Melting and crystallization behavior of partially miscible high density polyethylene/ethylene vinyl acetate copolymer (HDPE/EVA) blends

    International Nuclear Information System (INIS)

    Highlights: • HDPE/EVA blends undergo phase separation, making it an interesting topic to investigate the relationships between miscibility and crystallization. • Influences from blending on the crystallization kinetics were successfully evaluated by Friedman's and Khanna's method. • X-ray diffraction studies revealed that blending with EVA the unit length of the unit cell of the HDPE increases. • Thermal fractionation method was successfully used to characterize the co-crystallization in HDPE/EVA blends. - Abstract: Crystallization studies on HDPE/EVA blends and the individual components were performed with differential scanning calorimetry (DSC) technique and wide angle X-ray scattering (WAXS). Influences of blending on the crystallization kinetics of each component in HDPE/EVA mixture were evaluated by Friedman's activation energy and Khanna's crystallization rate coefficient (CRC). The addition of more HDPE into the EVA matrix causes more heterogeneous nucleation while the addition of EVA would hinder the nucleation of HDPE at the beginning of cooling process. Inter-molecular interaction in the melt facilitated the crystallization of both EVA and HDPE components. X-ray diffraction studies revealed that HDPE and EVA have orthorhombic unit cell. Blending with EVA did not affect the crystalline structure of HDPE. In addition, a little shift of (1 1 0), (2 0 0) and (0 2 0) crystalline peaks toward lower 2θ values of samples indicating a little increase of unit cell parameters of the orthorhombic unit cell of polyethylene. Thermal fractionation results showed that co-crystallization took place in the HDPE/EVA blend. All those results indicated that the polymer pair we choose was partially miscible

  7. Mathematical and numerical analysis of a multi-velocity multi-fluid model for interpenetration of miscible fluids

    International Nuclear Information System (INIS)

    The simulation of indirect laser implosion requires an accurate knowledge of the inter-penetration of the laser target materials turned into plasma. This work is devoted to the study of a multi-velocity multi-fluid model recently proposed by Scannapieco and Cheng (SC) to describe the inter-penetration of miscible fluids. In this document, we begin with presenting the SC model in the context of miscible fluids flow modelling. Afterwards, the mathematical analysis of the model is carried out (study of the hyperbolicity, existence of a strictly convex mathematical entropy, asymptotic analysis and diffusion limit). As a conclusion the problem is well set. Then, we focus on the problem of numerical resolution of systems of conservation laws with a relaxation source term, because SC model belongs to this class. The main difficulty of this task is to capture on a coarse grid the asymptotic behaviour of the system when the source term is stiff. The main contribution of this work lies in the proposition of a new technique, allowing us to construct a Lagrangian numerical flux taking into account the presence of the source term. This technique is applied first on the model-problem of a one-dimensional Euler system with friction, and then on the multi-fluid SC model. In both cases, we prove that the new scheme is asymptotic-preserving and entropic under a CFL-like condition. The two-dimensional extension of the scheme is done by using a standard alternate directions method. Some numerical results highlight the contribution of the new flux, compared with a standard Lagrange plus Remap scheme where the source term is processed using an operator splitting. (author)

  8. Melting and crystallization behavior of partially miscible high density polyethylene/ethylene vinyl acetate copolymer (HDPE/EVA) blends

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yang; Zou, Huawei, E-mail: hwzou@163.com; Liang, Mei, E-mail: liangmeiww@163.com; Cao, Ya

    2014-06-01

    Highlights: • HDPE/EVA blends undergo phase separation, making it an interesting topic to investigate the relationships between miscibility and crystallization. • Influences from blending on the crystallization kinetics were successfully evaluated by Friedman's and Khanna's method. • X-ray diffraction studies revealed that blending with EVA the unit length of the unit cell of the HDPE increases. • Thermal fractionation method was successfully used to characterize the co-crystallization in HDPE/EVA blends. - Abstract: Crystallization studies on HDPE/EVA blends and the individual components were performed with differential scanning calorimetry (DSC) technique and wide angle X-ray scattering (WAXS). Influences of blending on the crystallization kinetics of each component in HDPE/EVA mixture were evaluated by Friedman's activation energy and Khanna's crystallization rate coefficient (CRC). The addition of more HDPE into the EVA matrix causes more heterogeneous nucleation while the addition of EVA would hinder the nucleation of HDPE at the beginning of cooling process. Inter-molecular interaction in the melt facilitated the crystallization of both EVA and HDPE components. X-ray diffraction studies revealed that HDPE and EVA have orthorhombic unit cell. Blending with EVA did not affect the crystalline structure of HDPE. In addition, a little shift of (1 1 0), (2 0 0) and (0 2 0) crystalline peaks toward lower 2θ values of samples indicating a little increase of unit cell parameters of the orthorhombic unit cell of polyethylene. Thermal fractionation results showed that co-crystallization took place in the HDPE/EVA blend. All those results indicated that the polymer pair we choose was partially miscible.

  9. Deterministic multidimensional nonuniform gap sampling

    Science.gov (United States)

    Worley, Bradley; Powers, Robert

    2015-12-01

    Born from empirical observations in nonuniformly sampled multidimensional NMR data relating to gaps between sampled points, the Poisson-gap sampling method has enjoyed widespread use in biomolecular NMR. While the majority of nonuniform sampling schemes are fully randomly drawn from probability densities that vary over a Nyquist grid, the Poisson-gap scheme employs constrained random deviates to minimize the gaps between sampled grid points. We describe a deterministic gap sampling method, based on the average behavior of Poisson-gap sampling, which performs comparably to its random counterpart with the additional benefit of completely deterministic behavior. We also introduce a general algorithm for multidimensional nonuniform sampling based on a gap equation, and apply it to yield a deterministic sampling scheme that combines burst-mode sampling features with those of Poisson-gap schemes. Finally, we derive a relationship between stochastic gap equations and the expectation value of their sampling probability densities.

  10. Mind the Gap!

    DEFF Research Database (Denmark)

    Schmidt, Kjeld; Simone, Carla

    2000-01-01

    CSCW at large seems to be pursuing two diverging strategies: on one hand a strategy aiming at coordination technologies that reduce the complexity of coordinating cooperative activities by regulating the coordinative interactions, and on the other hand a strategy that aims at radically flexible m...... and blended in the course of real world cooperative activities. On the basis of this discussion the paper outlines an approach which may help CSCW research to bridge this gap....... means of interaction which do not regulate interaction but rather leave it to the users to cope with the complexity of coordinating their activities. As both strategies reflect genuine requirements, we need to address the issue of how the gap can be bridged, that is, how the two strategies can...

  11. Beyond the gap

    OpenAIRE

    Büger, Christian; Villumsen, Trine

    2015-01-01

    International Relations (IR) has cultivated the idea of a gap between the theory and the practice/praxis of IR. This division into two different spheres of knowledge is related to the predominant objectivist conception of science in IR, where the scientist is said to be observing reality from a distance without affecting it. Poststructuralists have denied that this distinction is meaningful and have even argued that it is dangerous to be oblivious to the structuring effects science may have o...

  12. Mind the Gap

    OpenAIRE

    SMITH, KIRK R.; Peel, Jennifer L.

    2010-01-01

    Background Recent analysis has demonstrated a remarkably consistent, nonlinear relationship between estimated inhaled dose of combustion particles measured as PM2.5 (particulate matter with aerodynamic diameter ≤ 2.5 μm) and cardiovascular disease mortality over several orders of magnitude of dose—from cigarette smoking, environmental tobacco smoke (ETS) exposure, and ambient air pollution exposure. Objectives Here we discuss the implications of this relationship and point out the gaps in our...

  13. BRIDGING SERVICE QUALITY GAPS

    OpenAIRE

    BARKATH UNISSA

    2012-01-01

    Bridging the Service quality gaps is one of the foremost areas of concern for amarketer. Service marketing is inherently different from product or goods marketing.Services are distinctively characterized by their intangible, heterogeneous, inseparableand perishable nature. The importance of the service sector in today's world is a verywidely accepted and renowned idea. “We are already experiencing a service society“services do have some basic characteristics which make them fundamentally diff...

  14. Gapped Ferromagnetic Graphene Nanoribbons

    OpenAIRE

    Hou, D.; J. H. Wei; Xie, S. J.

    2010-01-01

    We theoretically design a graphene-based all-organic ferromagnetic semiconductor by terminating zigzag graphene nanoribbons (ZGNRs) with organic magnets. A large spin-split gap with 100% spin polarized density of states near the Fermi energy is obtained, which is of potential application in spin transistors. The interplays among electron, spin and lattice degrees of freedom are studied using the first-principles calculations combined with fundamental model analysis. All of the calculations co...

  15. Complete phenomenological gravitational waveforms from spinning coalescing binaries

    CERN Document Server

    Sturani, R; Cadonati, L; Guidi, G M; Healy, J; Shoemaker, D; Viceré, A

    2010-01-01

    The quest for gravitational waves from coalescing binaries is customarily performed by the LIGO-Virgo collaboration via matched filtering, which requires a detailed knowledge of the signal. Complete analytical coalescence waveforms are currently available only for the non-precessing binary systems. In this paper we introduce complete phenomenological waveforms for the dominant quadrupolar mode of generically spinning systems. These waveforms are constructed by bridging the gap between the analytically known inspiral phase, described by spin Taylor (T4) approximants in the restricted waveform approximation, and the ring-down phase through a phenomenological intermediate phase, calibrated by comparison with specific, numerically generated waveforms, describing equal mass systems with dimension-less spin magnitudes equal to 0.6. The overlap integral between numerical and phenomenological waveforms ranges between 0.95 and 0.99.

  16. Complete phenomenological gravitational waveforms from spinning coalescing binaries

    Energy Technology Data Exchange (ETDEWEB)

    Sturani, R; Guidi, G M; Vicere, A [Dipartimento di Matematica, Fisica e Informatica, Universita degli Studi di Urbino ' Carlo Bo' , I-61029 Urbino (Italy); Fischetti, S; Cadonati, L [Physics Department, University of Massachusetts, Amherst, MA 01003 (United States); Healy, J; Shoemaker, D, E-mail: riccardo.sturani@uniurb.i [Center for Relativistic Astrophysics, Georgia Tech, Atlanta, GA 30332 (United States)

    2010-08-01

    The quest for gravitational waves from coalescing binaries is customarily performed by the LIGO-Virgo collaboration via matched filtering, which requires a detailed knowledge of the signal. Complete analytical coalescence waveforms are currently available only for the non-precessing binary systems. In this paper we introduce complete phenomenological waveforms for the dominant quadrupolar mode of generically spinning systems. These waveforms are constructed by bridging the gap between the analytically known inspiral phase, described by spin Taylor (T4) approximants in the restricted waveform approximation, and the ring-down phase through a phenomenological intermediate phase, calibrated by comparison with specific, numerically generated waveforms, describing equal mass systems with dimension-less spin magnitudes equal to 0.6. The overlap integral between numerical and phenomenological waveforms ranges between 0.95 and 0.99.

  17. Positronium in solid phases of n-alkane binary mixtures

    International Nuclear Information System (INIS)

    Highlights: • Rotator phase in even alkanes CnH2n+2 with n ⩽ 20 appears in mixed samples only. • Interlamellar gap width is the same for shorter chain alkane concentration x and 1 − x. • Excess electron trapping diminishes with broadening of alkane chain distribution Δn. - Abstract: Binary mixtures of even-numbered normal alkanes CnH2n+2 and Cn+2H2n+6 with n ⩽ 18 were investigated by positron annihilation spectroscopy. Formation of the rotator phase was observed in mixed structures, while no such a phase in neat alkanes in this range of n was found. Phase diagrams for n = 18 and n = 16 are very similar to the diagrams for binary mixtures of odd-numbered alkanes. The effect of positronium formation with trapped excess electrons weakens with decreasing n, at low n values the time constant of Ps rise contains the component much shorter than 1 h

  18. Tidal Disruption Events by a Massive Black Hole Binary

    CERN Document Server

    Ricarte, Angelo; Dai, Lixin; Coppi, Paolo

    2015-01-01

    Massive black hole binaries (MBHBs) are a natural byproduct of galaxy mergers. Previous studies have shown that flares from stellar tidal disruption events (TDEs) are modified by the presence of a secondary perturber, causing interruptions in the light curve. We study the dynamics of TDE debris in the presence of a milliparsec-separated MBHB by integrating ballistic particle orbits in the time-varying potential of the binary. We find that gaps in the light curve appear when material misses the accretion radius on its first return to pericentre. Subsequent recurrences can be decomposed into "continuous" and "delayed" components, which exhibit different behaviour. We find that this potential can substantially alter the locations of stream self-intersections. When debris is confined to the plane, we find that close encounters with the secondary BH leave noticeable signatures on the fallback rate and can result in significant accretion onto the secondary BH. Tight, equal-mass MBHBs accrete equally, periodically t...

  19. SUBORDINATE GAPS IN MANDARIN CHINESE

    Directory of Open Access Journals (Sweden)

    Ting-Chi Wei

    2011-06-01

    Full Text Available The existence of subordinate gaps in Mandarin Chinese casts doubt on analyses built on canonical coordinate gapping. We observe that the minimality of contrastive focus and the type of subordinate clause determine the acceptability of a missing gap in subordinate structure. Along this vein, we propose that a semantic-based deletion account can be used to interpret gapping in Mandarin. Such account relies on two violable constraints, AvoidF and Focus condition on gapping (Schwarzchild 1999, Merchant 2001 to compute the acceptability of a gap.

  20. GapBlaster—A Graphical Gap Filler for Prokaryote Genomes

    Science.gov (United States)

    Veras, Adonney; de Melo, Diego Magalhães; Soares, Siomar; Pinheiro, Kenny; Guimarães, Luis; Azevedo, Vasco; Silva, Artur; Ramos, Rommel T. J.

    2016-01-01

    The advent of NGS (Next Generation Sequencing) technologies has resulted in an exponential increase in the number of complete genomes available in biological databases. This advance has allowed the development of several computational tools enabling analyses of large amounts of data in each of the various steps, from processing and quality filtering to gap filling and manual curation. The tools developed for gap closure are very useful as they result in more complete genomes, which will influence downstream analyses of genomic plasticity and comparative genomics. However, the gap filling step remains a challenge for genome assembly, often requiring manual intervention. Here, we present GapBlaster, a graphical application to evaluate and close gaps. GapBlaster was developed via Java programming language. The software uses contigs obtained in the assembly of the genome to perform an alignment against a draft of the genome/scaffold, using BLAST or Mummer to close gaps. Then, all identified alignments of contigs that extend through the gaps in the draft sequence are presented to the user for further evaluation via the GapBlaster graphical interface. GapBlaster presents significant results compared to other similar software and has the advantage of offering a graphical interface for manual curation of the gaps. GapBlaster program, the user guide and the test datasets are freely available at https://sourceforge.net/projects/gapblaster2015/. It requires Sun JDK 8 and Blast or Mummer. PMID:27171416

  1. GapBlaster-A Graphical Gap Filler for Prokaryote Genomes.

    Directory of Open Access Journals (Sweden)

    Pablo H C G de Sá

    Full Text Available The advent of NGS (Next Generation Sequencing technologies has resulted in an exponential increase in the number of complete genomes available in biological databases. This advance has allowed the development of several computational tools enabling analyses of large amounts of data in each of the various steps, from processing and quality filtering to gap filling and manual curation. The tools developed for gap closure are very useful as they result in more complete genomes, which will influence downstream analyses of genomic plasticity and comparative genomics. However, the gap filling step remains a challenge for genome assembly, often requiring manual intervention. Here, we present GapBlaster, a graphical application to evaluate and close gaps. GapBlaster was developed via Java programming language. The software uses contigs obtained in the assembly of the genome to perform an alignment against a draft of the genome/scaffold, using BLAST or Mummer to close gaps. Then, all identified alignments of contigs that extend through the gaps in the draft sequence are presented to the user for further evaluation via the GapBlaster graphical interface. GapBlaster presents significant results compared to other similar software and has the advantage of offering a graphical interface for manual curation of the gaps. GapBlaster program, the user guide and the test datasets are freely available at https://sourceforge.net/projects/gapblaster2015/. It requires Sun JDK 8 and Blast or Mummer.

  2. GapBlaster-A Graphical Gap Filler for Prokaryote Genomes.

    Science.gov (United States)

    de Sá, Pablo H C G; Miranda, Fábio; Veras, Adonney; de Melo, Diego Magalhães; Soares, Siomar; Pinheiro, Kenny; Guimarães, Luis; Azevedo, Vasco; Silva, Artur; Ramos, Rommel T J

    2016-01-01

    The advent of NGS (Next Generation Sequencing) technologies has resulted in an exponential increase in the number of complete genomes available in biological databases. This advance has allowed the development of several computational tools enabling analyses of large amounts of data in each of the various steps, from processing and quality filtering to gap filling and manual curation. The tools developed for gap closure are very useful as they result in more complete genomes, which will influence downstream analyses of genomic plasticity and comparative genomics. However, the gap filling step remains a challenge for genome assembly, often requiring manual intervention. Here, we present GapBlaster, a graphical application to evaluate and close gaps. GapBlaster was developed via Java programming language. The software uses contigs obtained in the assembly of the genome to perform an alignment against a draft of the genome/scaffold, using BLAST or Mummer to close gaps. Then, all identified alignments of contigs that extend through the gaps in the draft sequence are presented to the user for further evaluation via the GapBlaster graphical interface. GapBlaster presents significant results compared to other similar software and has the advantage of offering a graphical interface for manual curation of the gaps. GapBlaster program, the user guide and the test datasets are freely available at https://sourceforge.net/projects/gapblaster2015/. It requires Sun JDK 8 and Blast or Mummer. PMID:27171416

  3. Binary Encodings of Non-binary Constraint Satisfaction Problems: Algorithms and Experimental Results

    CERN Document Server

    Samaras, N; 10.1613/jair.1776

    2011-01-01

    A non-binary Constraint Satisfaction Problem (CSP) can be solved directly using extended versions of binary techniques. Alternatively, the non-binary problem can be translated into an equivalent binary one. In this case, it is generally accepted that the translated problem can be solved by applying well-established techniques for binary CSPs. In this paper we evaluate the applicability of the latter approach. We demonstrate that the use of standard techniques for binary CSPs in the encodings of non-binary problems is problematic and results in models that are very rarely competitive with the non-binary representation. To overcome this, we propose specialized arc consistency and search algorithms for binary encodings, and we evaluate them theoretically and empirically. We consider three binary representations; the hidden variable encoding, the dual encoding, and the double encoding. Theoretical and empirical results show that, for certain classes of non-binary constraints, binary encodings are a competitive op...

  4. The Infrastructure Gap and Decentralization

    OpenAIRE

    Luis Andres; Dan Biller; Jordan Schwartz

    2014-01-01

    This paper proposes an economic logic for underpinning decentralization in the infrastructure sectors. It starts by detailing the definition of the infrastructure gap and the methodologies to calculate it. It provides some global trends for developing countries in terms of the gap and briefly discusses financing possibilities for developing countries to address the gap. Then it turns to the discussion of the link between the infrastructure gap and decentralization, providing a typology infras...

  5. Gaps in nonsymmetric numerical semigroups

    International Nuclear Information System (INIS)

    There exist two different types of gaps in the nonsymmetric numerical semigroups S(d1, . . . , dm) finitely generated by a minimal set of positive integers {d1, . . . , dm}. We give the generating functions for the corresponding sets of gaps. Detailed description of both gap types is given for the 1st nontrivial case m = 3. (author)

  6. Physical elements of the eclipsing binary δ Orionis

    Czech Academy of Sciences Publication Activity Database

    Mayer, P.; Harmanec, P.; Wolf, M.; Božič, H.; Šlechta, Miroslav

    2010-01-01

    Roč. 520, Sep-Oct (2010), A89/1-A89/12. ISSN 0004-6361 R&D Projects: GA ČR GA205/06/0584 Grant ostatní: GA ČR(CZ) GA205/06/0304; GA ČR(CZ) GAP209/10/0715 Institutional research plan: CEZ:AV0Z10030501 Keywords : eclipsing binaries * early-type stars * fundamental parameters Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 4.410, year: 2010

  7. Gap Opening in 3D: Single Planet Gaps

    CERN Document Server

    Fung, Jeffrey

    2016-01-01

    Giant planets can clear deep gaps when embedded in 2D (razor-thin) viscous circumstellar disks. We show by direct simulation that giant planets are just as capable of carving out gaps in 3D. Surface density maps are similar between 2D and 3D, even in detail. In particular, the scaling $\\Sigma_{\\rm gap} \\propto q^{-2}$ of gap surface density with planet mass, derived from a global "zero-dimensional" balance of Lindblad and viscous torques, applies equally well to results obtained at higher dimensions. Our 3D simulations reveal extensive, near-sonic, meridional flows both inside and outside the gaps; these large-scale circulations might bear on disk compositional gradients, in dust or other chemical species. At high planet mass, gap edges are mildly Rayleigh unstable and intermittently shed streams of material into the gap - less so in 3D than in 2D.

  8. Binaries and Globular Cluster Dynamics

    CERN Document Server

    Rasio, F A; Joshi, K J; Rasio, Frederic A.; Fregeau, John M.; Joshi, Kriten J.

    2001-01-01

    We summarize the results of recent theoretical work on the dynamical evolution of globular clusters containing primordial binaries. Even a very small initial binary fraction (e.g., 10%) can play a key role in supporting a cluster against gravothermal collapse for many relaxation times. Inelastic encounters between binaries and single stars or other binaries provide a very significant energy source for the cluster. These dynamical interactions also lead to the production of large numbers of exotic systems such as ultracompact X-ray binaries, recycled radio pulsars, double degenerate systems, and blue stragglers. Our work is based on a new parallel supercomputer code implementing Henon's Monte Carlo method for simulating the dynamical evolution of dense stellar systems in the Fokker-Planck approximation. This new code allows us to calculate very accurately the evolution of a cluster containing a realistic number of stars (N ~ 10^5 - 10^6) in typically a few hours to a few days of computing time. The discrete, s...

  9. Exoplanets Bouncing Between Binary Stars

    CERN Document Server

    Moeckel, Nickolas

    2012-01-01

    Exoplanetary systems are found not only among single stars, but also binaries of widely varying parameters. Binaries with separations of 100--1000 au are prevalent in the Solar neighborhood; at these separations planet formation around a binary member may largely proceed as if around a single star. During the early dynamical evolution of a planetary system, planet--planet scattering can eject planets from a star's grasp. In a binary, the motion of a planet ejected from one star has effectively entered a restricted three-body system consisting of itself and the two stars, and the equations of motion of the three body problem will apply as long as the ejected planet remains far from the remaining planets. Depending on its energy, escape from the binary as a whole may be impossible or delayed until the three-body approximation breaks down, and further close interactions with its planetary siblings boost its energy when it passes close to its parent star. Until then this planet may be able to transition from the ...

  10. Stabilité d'un écoulement miscible radial en milieu poreux : étude théorique et expérimentale Stabilitv of a Radial Miscible Flow in Porous Media: Theoretical and Experimental

    Directory of Open Access Journals (Sweden)

    Bertin H.

    2006-11-01

    Full Text Available Les instabilités de déplacements miscibles radiaux en milieu poreux dues à un contraste de mobilité sont étudiées de manière théorique et expérimentale. Dans une première partie, la mise au point d'un modèle numérique bidimensionnel permet la visualisation mathématique d'une configuration instable. A partir des équations aux perturbations linéarisées, l'étude nous permet d'évaluer l'influence de chacun des paramètres conditionnant la stabilité d'un tel écoulement. Ces résultats, dans la gamme des paramètres étudiés, nous permettent d'établir un critère d'instabilité. La deuxième partie, expérimentale, nous permet de visualiser, grâce à une méthode optique basée sur l'effet Christiansen, des instabilités dues au contraste de mobilité (développement notable de digitations. L'interprétation des résultats expérimentaux est comparée aux prédictions théoriques. The instabilities of radial miscible displacements in porous media due to a mobility contrast are examined theoretically and experimentally. The first part describes a two-dimensional numerical model used for the mathematical visualization of an unstable configuration. On the basis of linearized perturbation equations, we can evaluate the influence of each parameter governing the stability of the displacement. In the range of parameters investigated, these results enable an instability criterion to be established. The second part is experimental. An optical method based on the Christiansen effect is used to visualize instabilities due to mobility contrast (appreciable development of fingerings. The interpretation of the experimental results is compared to theoretical predictions.

  11. The effect of pressure, isotopic (H/D) substitution, and other variables on miscibility in polymer-solvent systems. The nature of the demixing process; dynamic light scattering and small angle neutron scattering studies. Final report

    International Nuclear Information System (INIS)

    A research program examining the effects of pressure, isotope substitution and other variables on miscibility in polymer solvent systems is described. The techniques employed included phase equilibrium measurements and dynamic light scattering and small angle neutron scattering

  12. Using Binary Code Instrumentation in Computer Security

    Directory of Open Access Journals (Sweden)

    Marius POPA

    2013-01-01

    Full Text Available The paper approaches the low-level details of the code generated by compilers whose format permits outside actions. Binary code modifications are manually done when the internal format is known and understood, or automatically by certain tools developed to process the binary code. The binary code instrumentation goals may be various from security increasing and bug fixing to development of malicious software. The paper highlights the binary code instrumentation techniques by code injection to increase the security and reliability of a software application. Also, the paper offers examples for binary code formats understanding and how the binary code injection may be applied.

  13. Gap Task Force

    CERN Multimedia

    Lissuaer, D

    One of the more congested areas in the ATLAS detector is the GAP region (the area between the Barrel Calorimeter and the End Cap calorimeter) where Inner Detector services, LAr Services and some Tile services all must co-habitat in a very limited area. It has been clear for some time that the space in the GAP region is not sufficient to accommodate all that is needed. In the last few month additional problems of routing all the services to Z=0 have been encountered due to the very limited space between the Tile Calorimeter and the first layer of Muon chambers. The Technical Management Board (TMB) and the Executive Board (EB) decided in the middle of March to establish a Task Force to look at this problem and come up with a solution within well-specified guidelines. The task force consisted of experts from the ID, Muon, Liquid Argon and Tile systems in addition to experts from the Technical Coordination team and the Physics coordinator. The task force held many meetings and in general there were some very l...

  14. Closing the value gap

    International Nuclear Information System (INIS)

    It's a predicament. For the most part, investor-owned electric utilities trade at a deep discount to the actual (that is, replacement-cost) value to their assets. That's because most utilities fail to earn real returns large enough to justify raising and investing capital. The result is a value gap, where overall market value is significantly lower than the replacement costs of the assets. This gap is wider for utilities than for virtually any other industry in our economy. In addition to providing education and awareness, senior management must determine which businesses and activities create value and which diminish it. Then, management must allocate capital and human resources appropriately, holding down investments in value-diminishing areas until they can improve their profitability, and aggressively investing in value-enhancing businesses while preserving their profitability. But value management must not stop with resource-allocation decisions. To create a lasting transition to a value management philosophy, the utility's compensation system must also change: executives will have motivation to create value when compensation stems from this goal, not from such misleading accounting measures as earnings-per-share growth or ROE. That requires clear value-creation goals, and the organization must continuously evaluate top management's performance in light of the progress made toward those goals

  15. Board affiliation and pay gap

    Institute of Scientific and Technical Information of China (English)

    Shenglan; Chen; Hui; Ma; Danlu; Bu

    2014-01-01

    This paper examines the effects of board affiliation on the corporate pay gap.Using a sample of Chinese listed firms from 2005 to 2011, we find that boards with a greater presence of directors appointed by block shareholders have lower pay gaps. Furthermore, the governance effects of board affiliation with and without pay are distinguished. The empirical results show that board affiliation without pay is negatively related to the pay gap, while board affiliation with pay is positively related to the pay gap. Overall, the results shed light on how block shareholders affect their companies’ pay gaps through board affiliation.

  16. The structure of contact binaries

    CERN Document Server

    Kaehler, H

    2003-01-01

    In radiative layers of rotating stars the luminosity carried by circulation currents through a surface of constant entropy (circulation luminosity) is shown to be positive. The corresponding decrease in the temperature gradient is important in the secondary of contact binaries. This result removes the deadlock in the theory of contact binaries. The resulting treatment of contact binaries is investigated, assuming thermal equilibrium. If the circulation luminosity is adjusted to give a prescribed temperature difference between the components, details turn out to be unimportant. The temperature difference is bound to be positive. The fractional extent of radiative regions is larger in the secondary than in the primary. In the course of evolution the period increases and the mass ratio decreases. A survey of unevolved and evolved contact configurations is presented. Observational tests are passed. In stable systems the degree of contact is small. Stable systems in the period-colour diagram, unevolved and evolved...

  17. Isomorphous miscibility in MEO4 (scheelite) - LnVO4 (zircon) systems, where M=Ca, Sr, Ba, Cd, Pb; E=Mo, W; Ln=Y and lanthanides

    International Nuclear Information System (INIS)

    Method of X-ray phase analysis was used to study phase relations in MEO4 (scheelite) - LnVO4 (zircon) systems, where M=Ca, Sr, Ba, Cd, Pb; E=Mo, W; Ln=Y, Ce, Nd, Eu. Formation of limited solid solutions M1-xVxO4 was established. Evaluation of isomorphous miscibility in scheelite-zircon systems according to the statements of energy theory of isomorphous miscibility was conducted

  18. Practical Binary Adaptive Block Coder

    CERN Document Server

    Reznik, Yuriy A

    2007-01-01

    This paper describes design of a low-complexity algorithm for adaptive encoding/ decoding of binary sequences produced by memoryless sources. The algorithm implements universal block codes constructed for a set of contexts identified by the numbers of non-zero bits in previous bits in a sequence. We derive a precise formula for asymptotic redundancy of such codes, which refines previous well-known estimate by Krichevsky and Trofimov, and provide experimental verification of this result. In our experimental study we also compare our implementation with existing binary adaptive encoders, such as JBIG's Q-coder, and MPEG AVC (ITU-T H.264)'s CABAC algorithms.

  19. Coalescing binaries and Doppler experiments

    OpenAIRE

    Vecchio, A.; Bertotti, B.; Iess, L.

    1997-01-01

    We discuss the sensitivity of the CASSINI experiments to gravitational waves emitted by the in-spiral of compact binaries. We show that the maximum distance reachable by the instrument is $\\sim 100$ Mpc. In particular, CASSINI can detect massive black hole binaries with chirp mass $\\simgt 10^6 \\Ms$ in the Virgo Cluster with signal-to-noise ratio between 5 and 30 and possible compact objects of mass $\\simgt 30 \\Ms$ orbiting the massive black hole that our Galactic Centre is likely to harbour.

  20. Determining CO2 storage potential during miscible CO2 enhanced oil recovery: noble gas and stable isotope tracers

    Science.gov (United States)

    Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter; Drake, Ronald; John E. McCray

    2016-01-01

    Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2 flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2 retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2 produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2 dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination of

  1. Blending of Polyhydroxybutyrate-co-valerate with Polylactic Acid for Packaging Applications – Reflections on Miscibility and Effects on the Mechanical and Barrier Properties

    OpenAIRE

    Jost, V.; Kopitzky, R.

    2015-01-01

    Biopolymers for packaging applications offer many advantages and are therefore of increasing interest. In order to develop a sustainable alternative for petrochemical-based polymers the biobased and biodegradable polymers, the focus of this work are polyhydroxybutyrate-co-valerate (PHBV) and polylactic acid (PLA) (and copolymers). Blending of these two biopolymers was reviewed under thermodynamic aspects and backed with own results. Additionally, different ways of improving the miscibility we...

  2. The GAP-TPC

    CERN Document Server

    Rossi, B; Boiano, A; Catalanotti, S; Cocco, A G; Covone, G; Di Meo, P; Longo, G; Vanzanella, A; Walker, S; Wang, H; Wang, Y; Fiorillo, G

    2016-01-01

    Several experiments have been conducted worldwide, with the goal of observing low-energy nuclear recoils induced by WIMPs scattering off target nuclei in ultra-sensitive, low-background detectors. In the last few decades noble liquid detectors designed to search for dark matter in the form of WIMPs have been extremely successful in improving their sensitivities and setting the best limits. One of the crucial problems to be faced for the development of large size (multi ton-scale) liquid argon experiments is the lack of reliable and low background cryogenic PMTs: their intrinsic radioactivity, cost, and borderline performance at 87 K rule them out as a possible candidate for photosensors. We propose a brand new concept of liquid argon-based detector for direct dark matter search: the Geiger-mode Avalanche Photodiode Time Projection Chamber (GAP-TPC) optimized in terms of residual radioactivity of the photosensors, energy and spatial resolution, light and charge collection efficiency

  3. Gaps in Political Interest

    DEFF Research Database (Denmark)

    Robison, Joshua

    2015-01-01

    sought to measure respondents’ general interest in politics by asking them how often they follow public affairs. In this article, we uncover novel sources of measurement error concerning this question. We first show that other nationally representative surveys that frequently use this item deliver......Political interest fundamentally influences political behavior, knowledge, and persuasion (Brady, Verba, & Schlozman, 1995; Delli Carpini & Keeter, 1996; Luskin, 1990; Zukin, Andolina, Keeter, Jenkins, & Delli Carpini, 2006). Since the early 1960s, the American National Election Studies (ANES) has...... drastically higher estimates of mass interest. We then use a survey experiment included on a wave of the ANES’ Evaluating Government and Society Surveys (EGSS) to explore the influence of question order in explaining this systemic gap in survey results. We show that placing batteries of political...

  4. Kepler Eclipsing Binaries with Stellar Companions

    CERN Document Server

    Gies, D R; Guo, Z; Lester, K V; Orosz, J A; Peters, G J

    2015-01-01

    Many short-period binary stars have distant orbiting companions that have played a role in driving the binary components into close separation. Indirect detection of a tertiary star is possible by measuring apparent changes in eclipse times of eclipsing binaries as the binary orbits the common center of mass. Here we present an analysis of the eclipse timings of 41 eclipsing binaries observed throughout the NASA Kepler mission of long duration and precise photometry. This subset of binaries is characterized by relatively deep and frequent eclipses of both stellar components. We present preliminary orbital elements for seven probable triple stars among this sample, and we discuss apparent period changes in seven additional eclipsing binaries that may be related to motion about a tertiary in a long period orbit. The results will be used in ongoing investigations of the spectra and light curves of these binaries for further evidence of the presence of third stars.

  5. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The National Energy Strategy Plan (NES) has called for 900,000 barrels/day production of heavy oil in the mid-1990s to meet our national needs. To achieve this goal, it is important that the Alaskan heavy oil fields be brought to production. Alaska has more than 25 billion barrels of heavy oil deposits. Conoco, and now BP Exploration have been producing from Schrader Bluff Pool, which is part of the super heavy oil field known as West Sak Field. Schrader Bluff reservoir, located in the Milne Point Unit, North Slope of Alaska, is estimated to contain up to 1.5 billion barrels of (14 to 21{degrees}API) oil in place. The field is currently under production by primary depletion; however, the primary recovery will be much smaller than expected. Hence, waterflooding will be implemented earlier than anticipated. The eventual use of enhanced oil recovery (EOR) techniques, such as hydrocarbon miscible solvent slug injection process, is vital for recovery of additional oil from this reservoir. The purpose of this research project was to determine the nature of miscible solvent slug which would be commercially feasible, to evaluate the performance of the hydrocarbon miscible solvent slug process, and to assess the feasibility of this process for improved recovery of heavy oil from Schrader Bluff reservoir. The laboratory experimental work includes: slim tube displacement experiments and coreflood experiments. The components of solvent slug includes only those which are available on the North Slope of Alaska.

  6. Frame theory for binary vector spaces

    OpenAIRE

    Bodmann, Bernhard G.; Le, My; Reza, Letty; Tobin, Matthew; Tomforde, Mark

    2009-01-01

    We develop the theory of frames and Parseval frames for finite-dimensional vector spaces over the binary numbers. This includes characterizations which are similar to frames and Parseval frames for real or complex Hilbert spaces, and the discussion of conceptual differences caused by the lack of a proper inner product on binary vector spaces. We also define switching equivalence for binary frames, and list all equivalence classes of binary Parseval frames in lowest dimensions, excluding cases...

  7. Using Binary Code Instrumentation in Computer Security

    OpenAIRE

    Marius POPA; Sergiu Marin CAPISIZU

    2013-01-01

    The paper approaches the low-level details of the code generated by compilers whose format permits outside actions. Binary code modifications are manually done when the internal format is known and understood, or automatically by certain tools developed to process the binary code. The binary code instrumentation goals may be various from security increasing and bug fixing to development of malicious software. The paper highlights the binary code instrumentation techniques by code injection to...

  8. Discs in misaligned binary systems

    Science.gov (United States)

    Rawiraswattana, Krisada; Hubber, David A.; Goodwin, Simon P.

    2016-08-01

    We perform SPH simulations to study precession and changes in alignment between the circumprimary disc and the binary orbit in misaligned binary systems. We find that the precession process can be described by the rigid-disc approximation, where the disc is considered as a rigid body interacting with the binary companion only gravitationally. Precession also causes change in alignment between the rotational axis of the disc and the spin axis of the primary star. This type of alignment is of great important for explaining the origin of spin-orbit misaligned planetary systems. However, we find that the rigid-disc approximation fails to describe changes in alignment between the disc and the binary orbit. This is because the alignment process is a consequence of interactions that involve the fluidity of the disc, such as the tidal interaction and the encounter interaction. Furthermore, simulation results show that there are not only alignment processes, which bring the components towards alignment, but also anti-alignment processes, which tend to misalign the components. The alignment process dominates in systems with misalignment angle near 90°, while the anti-alignment process dominates in systems with the misalignment angle near 0° or 180°. This means that highly misaligned systems will become more aligned but slightly misaligned systems will become more misaligned.

  9. A Galactic Binary Detection Pipeline

    Science.gov (United States)

    Littenberg, Tyson B.

    2011-01-01

    The Galaxy is suspected to contain hundreds of millions of binary white dwarf systems, a large fraction of which will have sufficiently small orbital period to emit gravitational radiation in band for space-based gravitational wave detectors such as the Laser Interferometer Space Antenna (LISA). LISA's main science goal is the detection of cosmological events (supermassive black hole mergers, etc.) however the gravitational signal from the galaxy will be the dominant contribution to the data - including instrumental noise over approximately two decades in frequency. The catalogue of detectable binary systems will serve as an unparalleled means of studying the Galaxy. Furthermore, to maximize the scientific return from the mission, the data must be "cleansed" of the galactic foreground. We will present an algorithm that can accurately resolve and subtract 2:: 10000 of these sources from simulated data supplied by the Mock LISA Data Challenge Task Force. Using the time evolution of the gravitational wave frequency, we will reconstruct the position of the recovered binaries and show how LISA will sample the entire compact binary population in the Galaxy.

  10. CFD Simulations of Binary Nucleation

    Czech Academy of Sciences Publication Activity Database

    Herrmann, E.; Brus, David; Hyvärinen, A-P.; Kulmala, M.

    Helsinki : -, 2010, P3U16. ISBN N. [International Aerosol Conference IAC 2010. Helsinki (FI), 29.08.2010-03.09.2010] Grant ostatní: FCR(FI) 1118615 Institutional research plan: CEZ:AV0Z40720504 Keywords : nucleation * binary * parameterization Subject RIV: CF - Physical ; Theoretical Chemistry www.iac2010.fi

  11. Eccentricity distribution of wide binaries

    CERN Document Server

    Tokovinin, Andrei

    2015-01-01

    A sample of 477 solar-type binaries within 67pc with projected separations larger than 50AU is studied by a new statistical method. Speed and direction of the relative motion are determined from the short observed arcs or known orbits, and their joint distribution is compared to the numerical simulations. By inverting the observed distribution with the help of simulations, we find that average eccentricity of wide binaries is 0.59+-0.02 and the eccentricity distribution can be modeled as f(e) ~= 1.2 e + 0.4. However, wide binaries containing inner subsystems, i.e. triple or higher-order multiples, have significantly smaller eccentricities with the average e = 0.52+-0.05 and the peak at e ~ 0.5. We find that the catalog of visual orbits is strongly biased against large eccentricities. A marginal evidence of eccentricity increasing with separation (or period) is found for this sample. Comparison with spectroscopic binaries proves the reality of the controversial period-eccentricity relation. The average eccentr...

  12. A Redundant Binary Algorithm for RSA

    Institute of Scientific and Technical Information of China (English)

    施荣华

    1996-01-01

    The normal form and modified normal form for binary redundant representation are defined.A redundant binary algorithm to compute modular exponentiation for very large integers is proposed.It is shown that the proposed algorithm requires the minimum number of basic operations(modular multiplications)among all possible binary redundant representations.

  13. Competitive learning for binary valued data

    OpenAIRE

    Leisch, Friedrich; Weingessel, Andreas; Dimitriadou, Evgenia

    1998-01-01

    We propose a new approach for using online competitive learning on binary data. The usual Euclidean distance is replaced by binary distance measures, which take possible asymmetries of binary data into account and therefore provide a "different point of view" for looking at the data. The method is demonstrated on two artificial examples and applied on tourist marketing research data. (author's abstract)

  14. Effect of water miscible organic solvents on p-nitrophenol hydroxylase (CYP2E1 activity in rat liver microsomes

    Directory of Open Access Journals (Sweden)

    Pranali G Patil

    2015-01-01

    Full Text Available Organic solvents used for solubilization of the substrates/NCEs are known to affect the activity of cytochrome P450 enzymes. Further, this effect varies with the solvents used, the substrates and CYP450 isoforms in question. In the present study, we have investigated the effect of ten commonly used water miscible organic solvents (methanol, ethanol, 1-propanol, 2-propanol, acetonitrile, acetone, dimethyl sulphoxide, N,N-dimethyl formamide, dioxane and polyethylene glycol 400 on p-nitrophenol hydroxylase activity at 0, 0.1, 0.25, 0.5, 0.75 and 1% v/v concentration in rat liver microsomes. All the solvents studied showed concentration dependent inhibition of the p-nitrophenol hydroxylase activity except acetonitrile which showed activation of the activity at concentration range studied. Out of ten solvents studied, dioxane was found to be the most inhibitory solvent (inhibition >90% at 0.25% v/v concentration. Overall, solvents like dimethyl sulphoxide, dimethyl formamide and dioxane appeared to be unsuitable for characterizing p-nitrophenol hydroxylase (CYP2E1-mediated reactions due to a high degree of inhibition. On the other hand, methanol and acetonitrile at concentrations <0.5% v/v appeared to be appropriate solvents for substrate solubilization while evaluating CYP2E1-mediated catalysis. The results of this study imply that caution should be exercised while choosing solvents for dissolution of substrate during enzyme studies in liver microsomes.

  15. Effect of P\\'{e}clet number on miscible rectilinear displacement in a Hele-Shaw cell

    CERN Document Server

    Pramanik, Satyajit

    2014-01-01

    Influence of fluid dispersion on the Saffman-Taylor instability in miscible fluids has been investigated both in the linear and nonlinear regimes. The convective characteristic scales are used for the dimensionless formulation that incorporates P\\'{e}clet number (Pe) into the governing equations as a measure for the fluid dispersion. A linear stability analysis (LSA) has been performed in a similarity transformation domain using the quasi-steady-state approximation. LSA results show that systems with large Pe become more unstable and the onset of instability occurs earlier compared to the case when Pe is smaller. Variations of the most unstable wave number and the cut-off wave number with Pe have been analyzed. Fourier spectral method has been used for the numerical simulations of the fully nonlinear system. The results indicate that the wave numbers of the unstable modes increase with Pe. Influence of the anisotropic dispersion on the onset in both the linear and nonlinear regimes has been analyzed. Large tr...

  16. Effect of water-miscible organic solvents on CYP450-mediated metoprolol and imipramine metabolism in rat liver microsomes

    Directory of Open Access Journals (Sweden)

    T S Shah

    2015-01-01

    Full Text Available The catalytic activity of cytochrome P450 enzymes is known to be affected by presence of organic solvents in in vitro assays. However, these effects tend to be variable and depend on the substrate and CYP450 isoform in question. In the present study, we have investigated effect of ten water miscible organic solvents (methanol, ethanol, propanol, isopropanol, acetone, acetonitrile, dimethylsulphoxide, dimethylformamide, dioxane and PEG400 on water soluble substrates of CYP450, metoprolol and imipramine, at 0, 0.1, 0.25, 0.5, 0.75 and 1% v/v concentration in rat liver microsomes. Organic solvents studied had a concentration dependent inhibitory effect on the metoprolol and imipramine metabolism activity. Metoprolol metabolism was found to be more susceptible to the organic solvents, almost all the ten solvents had more or less inhibitory effect compared to imipramine metabolism. Except acetone, PEG400 and dimethylsulphoxide, all solvents had ~50% inhibition of total metoprolol metabolism activity, while in case of imipramine metabolism activity, only n-propanol, isopropanol and PEG400 had ~50% inhibition at 1% v/v. Interestingly, methanol, dimethylsulphoxide and acetonitrile had negligible effect on the imipramine metabolism (less than 10% inhibition at 1% v/v while, total metoprolol metabolism activity was substantially inhibited by these solvents (MeOH 52%, DMSO 29% and ACN 47% at 1% v/v. In both cases, dioxane was found to be the most inhibitory solvent (~90% inhibition at 1% v/v.

  17. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2007-06-30

    The objective of this research project was to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in the hopes of observing changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE No.DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data. Attribute analysis was a very useful tool in enhancing changes in seismic character present, but difficult to interpret on time amplitude slices. Lessons learned from and tools/techniques developed during this project will allow high-resolution seismic imaging to be routinely applied to many CO{sub 2} injection programs in a large percentage of shallow carbonate oil fields in the midcontinent.

  18. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2005-09-01

    The objective of this research project is to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data to observe changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 18 months of seismic monitoring, one baseline and six monitor surveys clearly imaged changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators.

  19. Properties of the band gaps in one-dimensional ternary lossy photonic crystal containing double-negative materials

    CERN Document Server

    Aghajamali, Alireza; Barati, Mahmood

    2013-01-01

    In this paper, theoretically, the characteristics matrix method is employed to investigate and compare the properties of the band gaps of the one-dimensional ternary and binary lossy photonic crystals which are composed of double-negative and -positive materials. This study shows that by varying the angle of incidence, the band gaps for TM and TE waves behave differently in both ternary and binary lossy structures. The results demonstrate that by increasing the angle of incidence for the TE wave, the width and the depth of zero-n, zero-\\mu, and Bragg gap increase in both ternary and binary structures. On the other hand, the enhancement of the angle of incidence for the TM wave, contributes to reduction of the width and the depth of the zero-n and Bragg gaps, and they finally disappear for incidence angles greater than 50 and 60 for the binary structure, and 40 and 45 for the ternary structures, respectively. In addition, the details of the edges of the band gaps variations as a function of incidence angle for...

  20. Properties of the Band Gaps in 1D Ternary Lossy Photonic Crystal Containing Double-Negative Materials

    Directory of Open Access Journals (Sweden)

    Alireza Aghajamali

    2014-01-01

    Full Text Available Theoretically, the characteristics matrix method is employed to investigate and compare the properties of the band gaps of the one-dimensional ternary and binary lossy photonic crystals which are composed of double-negative and double-positive materials. This study shows that by varying the angle of incidence, the band gaps for TM and TE waves behave differently in both ternary and binary lossy structures. The results demonstrate that, by increasing the angle of incidence for the TE wave, the width and the depth of zero-n¯, zero-μ, and Bragg gap increase in both ternary and binary structures. On the other hand, the enhancement of the angle of incidence for the TM wave contributes to reduction of the width and the depth of the zero-n¯ and Bragg gaps, and they finally disappear for incidence angles greater than 50° and 60° for the binary structure and 40° and 45° for the ternary structures, respectively. In addition, the details of the edges of the band gaps variations as a function of incidence angle for both structures are studied.

  1. The Adaptation Finance Gap Report

    DEFF Research Database (Denmark)

    UNEP’s Adaptation Gap Report series focuses on Finance, Technology and Knowledge gaps in climate change adaptation. It compliments the Emissions Gap Report series, and explores the implications of failing to close the emissions gap. The report builds on a 2014 assessment by the United Nations...... Environment Programme (UNEP), which laid out the concept of ‘adaptation gaps’ and outlined three such gaps: technology, finance and knowledge. The 2016 Adaptation Gap Report assesses the difference between the financial costs of adapting to climate change in developing countries and the amount of money...... actually available to meet these costs – a difference known as the “adaptation finance gap”. Like the 2014 report, the 2016 report focuses on developing countries, where adaptation capacity is often the lowest and needs the highest, and concentrates on the period up to 2050. The report identifies trends...

  2. Service Quality Gaps & Six Sigma

    OpenAIRE

    Ali Dehghan; Arash Shahin; Bahman Zenouzi

    2011-01-01

    Nowadays almost all organizations are realizing the significance of customer centered philosophies. One of the key challenges they are facing is how to manage service quality, which holds a great importance to customer satisfaction. This paper has attempted to investigate the gap between customers, service providers and managers in terms of service quality dimensions.  For this purpose, gaps 1 and 6 of the SERVQUAL model have been studied, as well as two new gaps, proposed for comparing custo...

  3. Understanding the Tax Gap1

    OpenAIRE

    Mazur, Mark J.; Plumley, Alan H.

    2007-01-01

    The Tax Gap is defined as the difference between the amount of tax imposed by the Tax Code and the amount that is reported and paid with timely filed returns. For the federal government, the gross tax gap is estimated at $345 billion for Tax Year 2001 (after the collection of late and enforced payments, the net tax gap is estimated at $290 billion for Tax Year 2001). This paper explains the concept of the tax gap, discusses how it is estimated, and points out some limitations with the estimates.

  4. The Growing US Fiscal Gap

    OpenAIRE

    Daniel Shaviro

    2002-01-01

    The United States has a huge long-term fiscal gap, perhaps with a present value as great as $74 trillion. The US may thus be unable to continue meeting its current spending commitments without eventually enacting huge tax increases. The tax cut enacted in 2001 may have increased the fiscal gap by about $13 trillion, but the main cause of the gap is increasing life expectancy, which raises the cost of Social Security and Medicare. While the fiscal gap can in theory be eliminated at the stroke ...

  5. Axial gap rotating electrical machine

    Energy Technology Data Exchange (ETDEWEB)

    None

    2016-02-23

    Direct drive rotating electrical machines with axial air gaps are disclosed. In these machines, a rotor ring and stator ring define an axial air gap between them. Sets of gap-maintaining rolling supports bear between the rotor ring and the stator ring at their peripheries to maintain the axial air gap. Also disclosed are wind turbines using these generators, and structures and methods for mounting direct drive rotating electrical generators to the hubs of wind turbines. In particular, the rotor ring of the generator may be carried directly by the hub of a wind turbine to rotate relative to a shaft without being mounted directly to the shaft.

  6. Permutation Entropy for Random Binary Sequences

    Directory of Open Access Journals (Sweden)

    Lingfeng Liu

    2015-12-01

    Full Text Available In this paper, we generalize the permutation entropy (PE measure to binary sequences, which is based on Shannon’s entropy, and theoretically analyze this measure for random binary sequences. We deduce the theoretical value of PE for random binary sequences, which can be used to measure the randomness of binary sequences. We also reveal the relationship between this PE measure with other randomness measures, such as Shannon’s entropy and Lempel–Ziv complexity. The results show that PE is consistent with these two measures. Furthermore, we use PE as one of the randomness measures to evaluate the randomness of chaotic binary sequences.

  7. Skill gaps: existence and efficiency

    OpenAIRE

    Fernando Pueyo; Marcos Sanso

    2002-01-01

    Given the interdependences between human capital accumulation and technological change, skill gaps may arise in equilibrium. However, they are not necessarily inefficient, and in this paper we present a model in which the simple absence of such a skill gap can be inefficient.

  8. PhoneGap for enterprise

    CERN Document Server

    Shotts, Kerri

    2014-01-01

    This book is intended for developers who wish to use PhoneGap to develop useful, rich, secure mobile applications for their enterprise environment. The book assumes you have working knowledge of PhoneGap, HTML5, CSS3, and JavaScript, and a reasonable understanding of networking and n-tier architectures.

  9. Mongolia; Measuring the Output Gap

    OpenAIRE

    Julia Bersch; Tara M. Sinclair

    2011-01-01

    This paper compares the output gap estimates for Mongolia based on a number of different methods. Special attention is paid to the substantial role of mining in the Mongolian economy. We find that a Blanchard and Quah-type joint model of output and inflation provides a more robust estimate of the output gap for Mongolia than the traditional statistical decompositions.

  10. Remnants of compact binary mergers

    CERN Document Server

    Domainko, W

    2006-01-01

    We investigate the long-term evolution and observability of remnants originating from the merger of compact binary systems and discuss the differences to supernova remnants. Compact binary mergers expel much smaller amounts of mass at much higher velocities, as compared to supernovae, which will affect the dynamical evolution of their remnants. The ejecta of mergers consist of very neutron rich nuclei. Some of these neutron rich nuclei will produce observational signatures in form of gamma ray lines during their decay. The composition of the ejecta might even give interesting constraints about the internal structure of the neutron star. We further discuss the possibility that merger remnants appear as recently discovered 'dark accelerators' which are extended TeV sources which lack emission in other bands.

  11. Event Rates for Binary Inspiral

    CERN Document Server

    Kalogera, V

    2001-01-01

    Double compact objects (neutron stars and black holes) found in binaries with small orbital separations are known to spiral in and are expected to coalesce eventually because of the emission of gravitational waves. Such inspiral and merger events are thought to be primary sources for ground based gravitational-wave interferometric detectors (such as LIGO). Here, we present a brief review of estimates of coalescence rates and we examine the origin and relative importance of uncertainties associated with the rate estimates. For the case of double neutron star systems, we compare the most recent rate estimates to upper limits derived in a number of different ways. We also discuss the implications of the formation of close binaries with two non-recycled pulsars.

  12. Modified binary particle swam optimization

    Institute of Scientific and Technical Information of China (English)

    Sangwook Lee; Sangmoon Soak; Sanghoun Oh; Witold Pedrycz; Moongu Jeon

    2008-01-01

    This paper presents a modified binary particle swarm optimization(BPSO)which adopts concepts of the genotype-phenotype rep-resentation and the mutation operator of genetic algorithms.Its main feature is that the BPSO can be treated as a continuous PSO.The proposed BPSO algorithm is tested on various benchmark functions,and its performance is compared with that of the original BPSO.Experimental results show that the modified BPSO outperforms the original BPSO algorithm.

  13. Tides in asynchronous binary systems

    OpenAIRE

    Toledano, Oswaldo; Moreno, Edmundo; Koenigsberger, Gloria; Detmers, R.; Langer, Norbert

    2006-01-01

    Stellar oscillations are excited in non-synchronously rotating stars in binary systems due to the tidal forces. Tangential components of the tides can drive a shear flow which behaves as a differentially forced rotating structure in a stratified outer medium. In this paper we show that our single-layer approximation for the calculation of the forced oscillations yields results that are consistent with the predictions for the synchronization timescales in circular orbits. In addition, calibrat...

  14. GAP Analysis Bulletin Number 15

    Science.gov (United States)

    Maxwell, Jill, (Edited By); Gergely, Kevin; Aycrigg, Jocelyn; Canonico, Gabrielle; Davidson, Anne; Coffey, Nicole

    2008-01-01

    The Mission of the Gap Analysis Program (GAP) is to promote conservation by providing broad geographic information on biological diversity to resource managers, planners, and policy makers who can use the information to make informed decisions. As part of the National Biological Information Infrastructure (NBII) ?a collaborative program to provide increased access to data and information on the nation?s biological resources--GAP data and analytical tools have been used in hundreds of applications: from basic research to comprehensive state wildlife plans; from educational projects in schools to ecoregional assessments of biodiversity. The challenge: keeping common species common means protecting them BEFORE they become threatened. To do this on a state or regional basis requires key information such as land cover descriptions, predicted distribution maps for native animals, and an assessment of the level of protection currently given to those plants and animals. GAP works cooperatively with Federal, state, and local natural resource professionals and academics to provide this kind of information. GAP activities focus on the creation of state and regional databases and maps that depict patterns of land management, land cover, and biodiversity. These data can be used to identify ?gaps? in conservation--instances where an animal or plant community is not adequately represented on the existing network of conservation lands. GAP is administered through the U.S. Geological Survey. Through building partnerships among disparate groups, GAP hopes to foster the kind of collaboration that is needed to address conservation issues on a broad scale. For more information, contact: John Mosesso National GAP Director 703-648-4079 Kevin Gergely National GAP Operations Manager 208-885-3565

  15. Detached cataclysmic variables are crossing the orbital period gap

    CERN Document Server

    Zorotovic, Monica; Parsons, Steven G; Gänsicke, Boris T; Hardy, Adam; Agurto-Gangas, Carolina; Gómez-Morán, Ada Nebot; Rebassa-Mansergas, Alberto; Schwope, Axel D

    2016-01-01

    A central hypothesis in the theory of cataclysmic variable (CV) evolution is the need to explain the observed lack of accreting systems in the ~2-3 h orbital period range, known as the period gap. The standard model, disrupted magnetic braking (DMB), reproduces the gap by postulating that CVs transform into inconspicuous detached white dwarf (WD) plus main sequence (MS) systems, which no longer resemble CVs. However, observational evidence for this standard model is currently indirect and thus this scenario has attracted some criticism throughout the last decades. Here we perform a simple but exceptionally strong test of the existence of detached CVs (dCVs). If the theory is correct dCVs should produce a peak in the orbital period distribution of detached close binaries consisting of a WD and an M4-M6 secondary star. We measured six new periods which brings the sample of such binaries with known periods below 10 h to 52 systems. An increase of systems in the ~2-3 h orbital period range is observed. Comparing ...

  16. Study of optical band gap of zinc-borate glasses

    International Nuclear Information System (INIS)

    The present study deals with binary xZnO-(100-x)B/sub 2/O/sub 3) (x=50-60%) and ternary yV/sub 2/O/sub 5/-50ZnO-(50-y)B/sub 2/O/sub 3/ (y=5-10%) glass systems. The mass density, oxygen packing density, molar volume and optical energy gap of these glasses were measured at room temperature. The density varies in the range of 2.92 - 3.57 g cm/sup 03/. The absorption spectra of these glasses were recorded in the UV-visible range. The optical band gap energies for these glasses were estimated from absorption data using the Mott and Davis relation and found to be in the range of 1.14 approx. equal to 2.92 eV. These results show that E/sub opt/ decreases with decreasing concentration of ZnO in binary glasses. In ternary glasses E/sub opt/ decreases with increasing concentration of V/sub 2/O/sub 5/ for a fixed amount of ZnO.(author)

  17. The fluctuating gap model

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Xiaobin

    2011-01-15

    The quasi-one-dimensional systems exhibit some unusual phenomenon, such as the Peierls instability, the pseudogap phenomena and the absence of a Fermi-Dirac distribution function line shape in the photoemission spectroscopy. Ever since the discovery of materials with highly anisotropic properties, it has been recognized that fluctuations play an important role above the three-dimensional phase transition. This regime where the precursor fluctuations are presented can be described by the so called fluctuating gap model (FGM) which was derived from the Froehlich Hamiltonian to study the low energy physics of the one-dimensional electron-phonon system. Not only is the FGM of great interest in the context of quasi-one-dimensional materials, liquid metal and spin waves above T{sub c} in ferromagnets, but also in the semiclassical approximation of superconductivity, it is possible to replace the original three-dimensional problem by a directional average over effectively one-dimensional problem which in the weak coupling limit is described by the FGM. In this work, we investigate the FGM in a wide temperature range with different statistics of the order parameter fluctuations. We derive a formally exact solution to this problem and calculate the density of states, the spectral function and the optical conductivity. In our calculation, we show that a Dyson singularity appears in the low energy density of states for Gaussian fluctuations in the commensurate case. In the incommensurate case, there is no such kind of singularity, and the zero frequency density of states varies differently as a function of the correlation lengths for different statistics of the order parameter fluctuations. Using the density of states we calculated with non-Gaussian order parameter fluctuations, we are able to calculate the static spin susceptibility which agrees with the experimental data very well. In the calculation of the spectral functions, we show that as the correlation increases, the

  18. The fluctuating gap model

    International Nuclear Information System (INIS)

    The quasi-one-dimensional systems exhibit some unusual phenomenon, such as the Peierls instability, the pseudogap phenomena and the absence of a Fermi-Dirac distribution function line shape in the photoemission spectroscopy. Ever since the discovery of materials with highly anisotropic properties, it has been recognized that fluctuations play an important role above the three-dimensional phase transition. This regime where the precursor fluctuations are presented can be described by the so called fluctuating gap model (FGM) which was derived from the Froehlich Hamiltonian to study the low energy physics of the one-dimensional electron-phonon system. Not only is the FGM of great interest in the context of quasi-one-dimensional materials, liquid metal and spin waves above Tc in ferromagnets, but also in the semiclassical approximation of superconductivity, it is possible to replace the original three-dimensional problem by a directional average over effectively one-dimensional problem which in the weak coupling limit is described by the FGM. In this work, we investigate the FGM in a wide temperature range with different statistics of the order parameter fluctuations. We derive a formally exact solution to this problem and calculate the density of states, the spectral function and the optical conductivity. In our calculation, we show that a Dyson singularity appears in the low energy density of states for Gaussian fluctuations in the commensurate case. In the incommensurate case, there is no such kind of singularity, and the zero frequency density of states varies differently as a function of the correlation lengths for different statistics of the order parameter fluctuations. Using the density of states we calculated with non-Gaussian order parameter fluctuations, we are able to calculate the static spin susceptibility which agrees with the experimental data very well. In the calculation of the spectral functions, we show that as the correlation increases, the quasi

  19. Galaxy Rotation and Rapid Supermassive Binary Coalescence

    Science.gov (United States)

    Holley-Bockelmann, Kelly; Khan, Fazeel Mahmood

    2015-09-01

    Galaxy mergers usher the supermassive black hole (SMBH) in each galaxy to the center of the potential, where they form an SMBH binary. The binary orbit shrinks by ejecting stars via three-body scattering, but ample work has shown that in spherical galaxy models, the binary separation stalls after ejecting all the stars in its loss cone—this is the well-known final parsec problem. However, it has been shown that SMBH binaries in non-spherical galactic nuclei harden at a nearly constant rate until reaching the gravitational wave regime. Here we use a suite of direct N-body simulations to follow SMBH binary evolution in both corotating and counterrotating flattened galaxy models. For N > 500 K, we find that the evolution of the SMBH binary is convergent and is independent of the particle number. Rotation in general increases the hardening rate of SMBH binaries even more effectively than galaxy geometry alone. SMBH binary hardening rates are similar for co- and counterrotating galaxies. In the corotating case, the center of mass of the SMBH binary settles into an orbit that is in corotation resonance with the background rotating model, and the coalescence time is roughly a few 100 Myr faster than a non-rotating flattened model. We find that counterrotation drives SMBHs to coalesce on a nearly radial orbit promptly after forming a hard binary. We discuss the implications for gravitational wave astronomy, hypervelocity star production, and the effect on the structure of the host galaxy.

  20. Visual Binaries in the Orion Nebula Cluster

    CERN Document Server

    Reipurth, Bo; Connelley, Michael S; Bally, John

    2007-01-01

    We have carried out a major survey for visual binaries towards the Orion Nebula Cluster using HST images obtained with an H-alpha filter. Among 781 likely ONC members more than 60" from theta-1 Ori C, we find 78 multiple systems (75 binaries and 3 triples), of which 55 are new discoveries, in the range from 0.1" to 1.5". About 9 binaries are likely line-of-sight associations. We find a binary fraction of 8.8%+-1.1% within the limited separation range from 67.5 to 675 AU. The field binary fraction in the same range is a factor 1.5 higher. Within the range 150 AU to 675 AU we find that T Tauri associations have a factor 2.2 more binaries than the ONC. The binary separation distribution function of the ONC shows unusual structure, with a sudden steep decrease in the number of binaries as the separation increases beyond 0.5", corresponding to 225 AU. We have measured the ratio of binaries wider than 0.5" to binaries closer than 0.5" as a function of distance from the Trapezium, and find that this ratio is signifi...

  1. New binaries among UV-selected, hot subdwarf stars and population properties

    Czech Academy of Sciences Publication Activity Database

    Kawka, Adela; Vennes, Stephane; O' Toole, S.; Nemeth, P.; Burton, D.; Kotze, E.; Buckley, D.A.H.

    2015-01-01

    Roč. 450, č. 4 (2015), s. 3514-3548. ISSN 0035-8711 R&D Projects: GA ČR GAP209/12/0217; GA ČR GA13-14581S; GA MŠk LG14013 Institutional support: RVO:67985815 Keywords : close binaries * spectroscopic * subdwarfs Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 5.107, year: 2014

  2. GapBlaster—A Graphical Gap Filler for Prokaryote Genomes

    OpenAIRE

    de Sá, Pablo H. C. G.; Fábio Miranda; Adonney Veras; Diego Magalhães de Melo; Siomar Soares; Kenny Pinheiro; Luis Guimarães; Vasco Azevedo; Artur Silva; Ramos, Rommel T. J.

    2016-01-01

    The advent of NGS (Next Generation Sequencing) technologies has resulted in an exponential increase in the number of complete genomes available in biological databases. This advance has allowed the development of several computational tools enabling analyses of large amounts of data in each of the various steps, from processing and quality filtering to gap filling and manual curation. The tools developed for gap closure are very useful as they result in more complete genomes, which will influ...

  3. Evolution of binary stars in multiple-population globular clusters - II. Compact binaries

    Science.gov (United States)

    Hong, Jongsuk; Vesperini, Enrico; Sollima, Antonio; McMillan, Stephen L. W.; D'Antona, Franca; D'Ercole, Annibale

    2016-04-01

    We present the results of a survey of N-body simulations aimed at exploring the evolution of compact binaries in multiple-population globular clusters. We show that as a consequence of the initial differences in the structural properties of the first-generation (FG) and the second-generation (SG) populations and the effects of dynamical processes on binary stars, the SG binary fraction decreases more rapidly than that of the FG population. The difference between the FG and SG binary fraction is qualitatively similar to but quantitatively smaller than that found for wider binaries in our previous investigations. The evolution of the radial variation of the binary fraction is driven by the interplay between binary segregation, ionization and ejection. Ionization and ejection counteract in part the effects of mass segregation but for compact binaries the effects of segregation dominate and the inner binary fraction increases during the cluster evolution. We explore the variation of the difference between the FG and the SG binary fraction with the distance from the cluster centre and its dependence on the binary binding energy and cluster structural parameters. The difference between the binary fraction in the FG and the SG populations found in our simulations is consistent with the results of observational studies finding a smaller binary fraction in the SG population.

  4. Wide gap semiconductor microwave devices

    International Nuclear Information System (INIS)

    A review of properties of wide gap semiconductor materials such as diamond, diamond-like carbon films, SiC, GaP, GaN and AlGaN/GaN that are relevant to electronic, optoelectronic and microwave applications is presented. We discuss the latest situation and perspectives based on experimental and theoretical results obtained for wide gap semiconductor devices. Parameters are taken from the literature and from some of our theoretical works. The correspondence between theoretical results and parameters of devices is critically analysed. (review article)

  5. The Income Gap GROWS Large

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The income gap between regions, urban and rural areas, industries and various social groups is widening in China. The gap, as indicated by the Gini Coefficient, extended beyond an alarming level. A World Bank report said the Gini Coefficient for China surged to 0.47 in 2009, exceeding the "red line" of 0.4. The problems caused by the rising income disparity have been the focus of public attention. Some experts believe that it is high time for China to shrink this income gap. A Xinhua News Agency research team recently analyzed this trend, and published an article in the Economic Information Daily. Edited excerpts follow:

  6. The Income Gap Grows Large

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    @@ The income gap between regions,urban and rural areas,industries and various social groups is widening in China.The gap,as indicated by the Gini Coefficient,extended beyond an alarming level.A World Bank report said the Gini Coefficient for China surged to 0A7 in 2009,exceeding the "red line"of 0.4.The problems caused by the rising income disparity have been the focus of public attention.Some experts believe that it is high time for China to shrink this income gap.

  7. Gaps in discrete random samples

    OpenAIRE

    Grübel, Rudolf; Hitczenko, Paweł

    2009-01-01

    Let (Xi)i∈ℕ be a sequence of independent and identically distributed random variables with values in the set ℕ0 of nonnegative integers. Motivated by applications in enumerative combinatorics and analysis of algorithms we investigate the number of gaps and the length of the longest gap in the set {X1,...,Xn} of the first n values. We obtain necessary and sufficient conditions in terms of the tail sequence (qk)k∈ℕ0, qk=P(X1≥ k), for the gaps to vanish ...

  8. Band Gap of Cubic AlN, GaN and InN Compounds Under Pressure

    OpenAIRE

    BERRAH, S.; H. Abid; Boukortt, A.; SEHIL, M.

    2006-01-01

    Numerical simulation based on FP-LAPW calculations is applied to study the lattice parameters, bulk modulus and band gap energy of zinc blende binaries AlN, GaN and InN under hydrostatic pressure. The results obtained are in a good agreement with experimental and theoretical values.

  9. Non-coalescence of sessile drops from different but miscible liquids: Hydrodynamic analysis of the twin drop contour as self stabilizing, traveling wave

    CERN Document Server

    Karpitschka, Stefan

    2015-01-01

    Capillarity always favors drop fusion. Nevertheless sessile drops from different but completely miscible liquids often do not fuse instantaneously upon contact. Rather, intermediate non-coalescence is observed. Two separate drop bodies, connected by a thin liquid neck move over the substrate. Supported by new experimental data a thin film hydrodynamic analysis of this state is presented. Presumably advective and diffusive volume fluxes in the neck region establish a localized and temporarily stable surface tension gradient. This induces a local surface (Marangoni) flow that stabilizes a traveling wave i.e., the observed moving twin drop configuration. The theoretical predictions are in excellent agreement with the experimental findings.

  10. Miscibility,Thermal Stability,Rheological and Mechanical Properties of Blends Derived from Polysulfone Oligomer and Poly (phthalazinone ether sulfone ketone)

    Institute of Scientific and Technical Information of China (English)

    Guimei WANG; Xigao JIAN; Gongxiong LIAO; Lihao WU

    2004-01-01

    Poly(phthalazinone ether sulfone ketone) (PPESK) was melt blended with bisphenol-A polysulfone oligomer (O-PSF)to produce a thermoplastic polymer blends. The miscibility, thermal stability, theological and mechanical properties of the blends were investigated by scanning electron microscopy (SEM), differential scanning calorimetry (DSC),thermogravimetric analysis (TGA) and capillary rheometry. The blends showed single Tg over the composition range and possess homogeneous microstructure. The addition of O-PSF slightly affected the thermal properties of the blends. PSF oligomer, as a processing aid, could markedly improve the processability of the PPESK. In addition, the mechanical properties of the blends were increased, to some degree, by adding O-PSF.

  11. THERMAL PROPERTY, MISCIBILITY AND CRYSTALLIZATION BEHAVIOR OF POLY(3-HYDROXYBUTYRATE-co 3-YDROXYHEXANOATE) AND POLY(BUTYLENE SUCCINATE-ADIPATE) (PHBHHX/PBSA) BLENDS

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Blends of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) and poly(butylene succinate-adipate) (PBSA), both biodegradable semicrystalline polyesters, were prepared with the ratio of PHBHHx/PBSA ranging from 80/20 to 20/80 by melt mixing method. Differential scanning calorimetry (DSC), thermogravimetry analysis (TGA), dynamic mechanical thermal analysis (DMA), polarizing optical microscopy (POM) and wide angle X-ray diffractometer (WAXD) were used to study the miscibility and crystallization behavior of PHBHHx/PBSA blends. Experimental results indicate that PHBHHx is immiscible with PBSA as shown by the almost unchanged glass transition temperature and the biphasic melt.

  12. Orbital eccentricities in primordial black holes binaries

    OpenAIRE

    Cholis, Ilias; Kovetz, Ely D.; Ali-Haïmoud, Yacine; Bird, Simeon; Kamionkowski, Marc; Muñoz, Julian B.; Raccanelli, Alvise

    2016-01-01

    It was recently suggested that the merger of $\\sim30\\,M_\\odot$ primordial black holes (PBHs) may provide a significant number of events in gravitational-wave observatories over the next decade, if they make up an appreciable fraction of the dark matter. Here we show that measurement of the eccentricities of the inspiralling binary black holes can be used to distinguish these binaries from those produced by more traditional astrophysical mechanisms. These PBH binaries are formed on highly ecce...

  13. Asteroid Systems: Binaries, Triples, and Pairs

    CERN Document Server

    Margot, Jean-Luc; Taylor, Patrick; Carry, Benoît; Jacobson, Seth

    2015-01-01

    In the past decade, the number of known binary near-Earth asteroids has more than quadrupled and the number of known large main belt asteroids with satellites has doubled. Half a dozen triple asteroids have been discovered, and the previously unrecognized populations of asteroid pairs and small main belt binaries have been identified. The current observational evidence confirms that small (20 km) binaries with small satellites are most likely created during large collisions.

  14. Relativistic Gravity and Binary Radio Pulsars

    OpenAIRE

    Kaspi, V. M.

    1999-01-01

    Following a summary of the basic principles of pulsar timing, we present a review of recent results from timing observations of relativistic binary pulsars. In particular, we summarize the status of timing observations of the much celebrated original binary pulsar PSR B1913+16, draw attention to the recent confirmation of strong evidence for geodetic precession in this system, review the recent measurement of multiple post-Keplerian binary parameters for PSR B1534+12, and describe the Parkes ...

  15. Microlensing Signature of Binary Black Holes

    Science.gov (United States)

    Schnittman, Jeremy; Sahu, Kailash; Littenberg, Tyson

    2012-01-01

    We calculate the light curves of galactic bulge stars magnified via microlensing by stellar-mass binary black holes along the line-of-sight. We show the sensitivity to measuring various lens parameters for a range of survey cadences and photometric precision. Using public data from the OGLE collaboration, we identify two candidates for massive binary systems, and discuss implications for theories of star formation and binary evolution.

  16. Detection of unresolved binaries with multicolor photometry

    CERN Document Server

    Chulkov, D; Malkov, O; Sichevskij, S; Krussanova, N; Mironov, A; Zakharov, A; Kniazev, A

    2016-01-01

    The principal goal of this paper is to specify conditions of detection of unresolved binaries by multicolor photometry. We have developed a method for estimating the critical distance at which an unresolved binary of given mass and age can be detected. The method is applied to the photometric system of the planned Lyra-B spaceborne experiment. We have shown that some types of unresolved binary stars can be discovered and distinguished from single stars solely by means of photometric observations.

  17. Closing the Cybersecurity Skills Gap

    Directory of Open Access Journals (Sweden)

    Rebecca Vogel

    2016-05-01

    Full Text Available The current consensus is that there is a worldwide gap in skills needed for a competent cybersecurity workforce. This skills gap has implications for the national security sector, both public and private. Although the view is that this will take a concerted effort to rectify, it presents an opportunity for IT professionals, university students, and aspirants to take-up jobs in national security national intelligence as well military and law enforcement intelligence. This paper examines context of the issue, the nature of the cybersecurity skills gap, and some key responses by governments to address the problem. The paper also examines the emerging employment trends, some of the employment challenges, and what these might mean for practice. The paper argues that the imperative is to close the cyber skills gap by taking advantage of the window of opportunity, allowing individuals interested in moving into the cybersecurity field to do so via education and training.

  18. Gap Surface Plasmon Waveguide Analysis

    DEFF Research Database (Denmark)

    Nielsen, Michael Grøndahl; Bozhevolnyi, Sergey I.

    2014-01-01

    Plasmonic waveguides supporting gap surface plasmons (GSPs) localized in a dielectric spacer between metal films are investigated numerically and the waveguiding properties at telecommunication wavelengths are presented. Especially, we emphasize that the mode confinement can advantageously be...

  19. Closing the Cybersecurity Skills Gap

    OpenAIRE

    Rebecca Vogel

    2016-01-01

    The current consensus is that there is a worldwide gap in skills needed for a competent cybersecurity workforce. This skills gap has implications for the national security sector, both public and private. Although the view is that this will take a concerted effort to rectify, it presents an opportunity for IT professionals, university students, and aspirants to take-up jobs in national security national intelligence as well military and law enforcement intelligence. This paper examines contex...

  20. Relativistic Gravity and Binary Radio Pulsars

    CERN Document Server

    Kaspi, V M

    1999-01-01

    Following a summary of the basic principles of pulsar timing, we present a review of recent results from timing observations of relativistic binary pulsars. In particular, we summarize the status of timing observations of the much celebrated original binary pulsar PSR B1913+16, draw attention to the recent confirmation of strong evidence for geodetic precession in this system, review the recent measurement of multiple post-Keplerian binary parameters for PSR B1534+12, and describe the Parkes Multibeam survey, a major survey of the Galactic Plane which promises to discover new relativistic binary pulsar systems.

  1. Speech perception of noise with binary gains

    DEFF Research Database (Denmark)

    Wang, DeLiang; Kjems, Ulrik; Pedersen, Michael Syskind;

    2008-01-01

    For a given mixture of speech and noise, an ideal binary time-frequency mask is constructed by comparing speech energy and noise energy within local time-frequency units. It is observed that listeners achieve nearly perfect speech recognition from gated noise with binary gains prescribed by the i...... by the ideal binary mask. Only 16 filter channels and a frame rate of 100 Hz are sufficient for high intelligibility. The results show that, despite a dramatic reduction of speech information, a pattern of binary gains provides an adequate basis for speech perception....

  2. The equations for binary density and the binary stream of particles of electro conducting magnetic liquids

    International Nuclear Information System (INIS)

    In work on the basis of a method of the kinetic equations it is output the differential equations for binary density and a binary stream of particles of electro conducting magnetic liquids. These equations are the nonuniform equations of parabolic type. The solution of these equations completely feature existential behaviour of binary density and a binary stream of particles of electro conducting magnetic liquids, i.e. process of a structural relaxation. (author)

  3. Near-Infrared Polarimetry of the GG Tauri A Binary System

    Science.gov (United States)

    Itoh, Yoichi; Oasa, Yumiko; Kudo, Tomoyuki; Kusakabe, Nobuhiko; Hashimoto, Jun; Abe, Lyu; Brandner, Wolfgang; Brandt, Timothy D.; Carson, Joseph C.; Egner, Sebastian; Feldt, Markus; Grady, Carol A.; Guyon, Olivier; Hayano, Yutaka; Hayashi, Masahiko; Hayashi, Saeko S.; Henning, Thomas; Hodapp, Klaus W.; Ishii, Miki; Iye, Masanori; Janson, Markus; Kandori, Ryo; Knapp, Gillian R.; Kuzuhara, Masayuki; Kwon, Jungmi; Matsuo, Taro; McElwain, Michael W.; Miyama, Shoken; Morino, Jun-Ichi; Moro-Martin, Amaya; Nishimura, Tetsuo; Pyo, Tae-Soo; Serabyn, Eugene; Suenaga, Takuya; Suto, Hiroshi

    2014-01-01

    A high angular resolution near-infrared image that shows the intensity of polarization for the GG Tau A binary system was obtained with the Subaru Telescope. The image shows a circumbinary disk scattering the light from the central binary. The azimuthal profile of the intensity of polarization for the circumbinary disk is roughly reproduced by a simple disk model with the Henyey-Greenstein phase function and the Rayleigh function, indicating there are small dust grains at the surface of the disk. Combined with a previous observation of the circumbinary disk, our image indicates that the gap structure in the circumbinary disk orbits counterclockwise, but material in the disk orbits clockwise. We propose that there is a shadow caused by material located between the central binary and the circumbinary disk. The separations and position angles of the stellar components of the binary in the past 20 yr are consistent with the binary orbit with a = 33.4 AU and e = 0.34.

  4. Near-infrared polarimetry of the GG Tauri A binary system

    International Nuclear Information System (INIS)

    A high angular resolution near-infrared image that shows the intensity of polarization for the GG Tau A binary system was obtained with the Subaru Telescope. The image shows a circumbinary disk scattering the light from the central binary. The azimuthal profile of the intensity of polarization for the circumbinary disk is roughly reproduced by a simple disk model with the Henyey-Greenstein phase function and the Rayleigh function, indicating there are small dust grains at the surface of the disk. Combined with a previous observation of the circumbinary disk, our image indicates that the gap structure in the circumbinary disk orbits counterclockwise, but material in the disk orbits clockwise. We propose that there is a shadow caused by material located between the central binary and the circumbinary disk. The separations and position angles of the stellar components of the binary in the past 20 yr are consistent with the binary orbit with a = 33.4 AU and e = 0.34. (research papers)

  5. On the BICM Capacity - Part I: Binary Labelings, Arbitrary Input Distributions, and First-Order Asymptotics

    CERN Document Server

    Alvarado, Alex

    2010-01-01

    In this semitutorial paper (Part I of a two-part paper), the capacity of bit-interleaved coded modulation (BICM) is analyzed. We introduce a general model for BICM which considers all the variables affecting the BICM capacity: the binary labeling, the input distribution, and the signal set. We show that the relation between the BICM capacity and Eb/N0 is not always a one-to-one function, we analyze how to increase the BICM capacity by modifying the input symbol distribution, and we develop first-order asymptotics of the BICM capacity for constellations with arbitrary input distributions, dimensions, mean, variance, and binary labeling. For 8-ary pulse amplitude modulation (PAM) and around Es/N0=0 dB (0.75 bit/symbol), the folded binary code (FBC) results in a higher capacity than the binary reflected gray code (BRGC) and the natural binary code (NBC). For the same SNR, the 1 dB gap between the additive white Gaussian noise (AWGN) capacity and the BICM capacity can be reduced to 0.2 dB if the input symbol dist...

  6. Probing the models: Abundances for high-mass stars in binaries

    CERN Document Server

    Pavlovski, K

    2013-01-01

    The complexity of composite spectra of close binary star system makes study of the spectra of their component stars extremely difficult. For this reason there exists very little information on the photospheric chemical composition of stars in close binaries, despite its importance for informing our understanding of the evolutionary processes of stars. In a long-term observational project we aim to fill this gap with systematic abundance studies for the variety of binary systems. The core of our analysis is the spectral disentangling technique, which allows isolation of the individual component star spectra from the time-series of observed spectra. We present new results for high-mass stars in close binaries. So far, we have measured detailed abundances for 22 stars in a dozen detached binary systems. The parameter space for the stars in our sample comprises masses in the range 8--22 M_sun, surface gravities of 3.1--4.2 (c.g.s.) and projected rotational velocities of 30--240 km/s. Whilst recent evolutionary mo...

  7. Massive Stars in Interactive Binaries

    Science.gov (United States)

    St.-Louis, Nicole; Moffat, Anthony F. J.

    Massive stars start their lives above a mass of ~8 time solar, finally exploding after a few million years as core-collapse or pair-production supernovae. Above ~15 solar masses, they also spend most of their lives driving especially strong, hot winds due to their extreme luminosities. All of these aspects dominate the ecology of the Universe, from element enrichment to stirring up and ionizing the interstellar medium. But when they occur in close pairs or groups separated by less than a parsec, the interaction of massive stars can lead to various exotic phenomena which would not be seen if there were no binaries. These depend on the actual separation, and going from wie to close including colliding winds (with non-thermal radio emission and Wolf-Rayet dust spirals), cluster dynamics, X-ray binaries, Roche-lobe overflow (with inverse mass-ratios and rapid spin up), collisions, merging, rejuventation and massive blue stragglers, black-hole formation, runaways and gamma-ray bursts. Also, one wonders whether the fact that a massive star is in a binary affects its parameters compared to its isolated equivalent. These proceedings deal with all of these phenomena, plus binary statistics and determination of general physical properties of massive stars, that would not be possible with their single cousins. The 77 articles published in these proceedings, all based on oral talks, vary from broad revies to the lates developments in the field. About a third of the time was spent in open discussion of all participants, both for ~5 minutes after each talk and 8 half-hour long general dialogues, all audio-recorded, transcribed and only moderately edited to yield a real flavour of the meeting. The candid information in these discussions is sometimes more revealing than the article(s) that preceded them and also provide entertaining reading. The book is suitable for researchers and graduate students interested in stellar astrophysics and in various physical processes involved when

  8. Young and Waltzing Binary Stars

    Science.gov (United States)

    2001-10-01

    ADONIS Observes Low-mass Eclipsing System in Orion Summary A series of very detailed images of a binary system of two young stars have been combined into a movie . In merely 3 days, the stars swing around each other. As seen from the earth, they pass in front of each other twice during a full revolution, producing eclipses during which their combined brightness diminishes . A careful analysis of the orbital motions has now made it possible to deduce the masses of the two dancing stars . Both turn out to be about as heavy as our Sun. But while the Sun is about 4500 million years old, these two stars are still in their infancy. They are located some 1500 light-years away in the Orion star-forming region and they probably formed just 10 million years ago . This is the first time such an accurate determination of the stellar masses could be achieved for a young binary system of low-mass stars . The new result provides an important piece of information for our current understanding of how young stars evolve. The observations were obtained by a team of astronomers from Italy and ESO [1] using the ADaptive Optics Near Infrared System (ADONIS) on the 3.6-m telescope at the ESO La Silla Observatory. PR Photo 29a/01 : The RXJ 0529.4+0041 system before primary eclipse PR Photo 29b/01 : The RXJ 0529.4+0041 system at mid-primary eclipse PR Photo 29c/01 : The RXJ 0529.4+0041 system after primary eclipse PR Photo 29d/01 : The RXJ 0529.4+0041 system before secondary eclipse PR Photo 29e/01 : The RXJ 0529.4+0041 system at mid-secondary eclipse PR Photo 29f/01 : The RXJ 0529.4+0041 system after secondary eclipse PR Video Clip 06/01 : Video of the RXJ 0529.4+0041 system Binary stars and stellar masses Since some time, astronomers have noted that most stars seem to form in binary or multiple systems. This is quite fortunate, as the study of binary stars is the only way in which it is possible to measure directly one of the most fundamental quantities of a star, its mass. The mass of a

  9. The structures of binary compounds

    CERN Document Server

    Hafner, J; Jensen, WB; Majewski, JA; Mathis, K; Villars, P; Vogl, P; de Boer, FR

    1990-01-01

    - Up-to-date compilation of the experimental data on the structures of binary compounds by Villars and colleagues. - Coloured structure maps which order the compounds into their respective structural domains and present for the first time the local co-ordination polyhedra for the 150 most frequently occurring structure types, pedagogically very helpful and useful in the search for new materials with a required crystal structure. - Crystal co-ordination formulas: a flexible notation for the interpretation of solid-state structures by chemist Bill Jensen. - Recent important advances in unders

  10. Binary stellar mergers with marginally bound ejecta: excretion discs, inflated envelopes, outflows, and their luminous transients

    Science.gov (United States)

    Pejcha, Ondřej; Metzger, Brian D.; Tomida, Kengo

    2016-09-01

    We study mass-loss from the outer Lagrange point (L2) in binary stellar mergers and their luminous transients by means of radiative hydrodynamical simulations. Previously, we showed that for binary mass ratios 0.06 ≲ q ≲ 0.8, synchronous L2 mass-loss results in a radiatively inefficient, dust-forming unbound equatorial outflow. A similar outflow exists irrespective of q if the ratio of the sound speed to the orbital speed at the injection point is sufficiently large, ε ≡ cT/vorb ≳ 0.15. By contrast, for cold L2 mass-loss (ε ≲ 0.15) from binaries with q ≲ 0.06 or q ≳ 0.8, the equatorial outflow instead remains marginally bound and falls back to the binary over tens to hundreds of binary orbits, where it experiences additional tidal torquing and shocking. As the bound gas becomes virialized with the binary, the luminosity of the system increases slowly at approximately constant photosphere radius, causing the temperature to rise. Subsequent evolution depends on the efficiency of radiative cooling. If the bound atmosphere is able to cool efficiently, as quantified by radiative diffusion time being shorter than the advection time (tdiff/tadv ≪ 1), then the virialized gas collapses to an excretion disc, while for tdiff/tadv ≳ 1 an isotropic wind is formed. Between these two extremes, an inflated envelope transports the heat generated near the binary to the surface by meridional flows. In all cases, the radiated luminosity reaches a fraction ˜10-2 to 10-1 of dot{M}v_orb^2/2, where dot{M} is the mass outflow rate. We discuss the implications of our results for transients in the luminosity gap between classical novae and supernovae, such as V1309 Sco and V838 Mon.

  11. Drug-polymer miscibility across a spray dryer: a case study of naproxen and miconazole solid dispersions.

    Science.gov (United States)

    Worku, Zelalem Ayenew; Aarts, Jolie; Singh, Abhishek; Van den Mooter, Guy

    2014-04-01

    The structural and physical stability of solid dispersions have not been adequately explored during spray drying manufacturing processes. In this study a wide range of compositions of naproxen/PVP-VA 64 (poly(1-vinylpyrrolidone-co-vinyl acetate)) and miconazole/PVP-VA 64 solid dispersions prepared by different laboratory spray dryers were collected from various selected locations and used to investigate the drug-polymer mixing across spray dryers. Spray-dried dispersions with 30% (w/w) naproxen collected from the transport tube of the Pro-C-epT Microspray dryer showed the narrowest glass transition width, which apparently indicates the highest degree of drug-polymer mixing compared to the other locations. The intensity of the naproxen-PVP-VA 64 interaction peak at 1654 cm(-1) of IR spectra differs for solid dispersions (SDs) from the collector and transport tube of Pro-C-epT Microspray dryer with a higher intensity for the latter. Samples with 50% (w/w) naproxen loading collected from the cyclone and the cyclone steel part of the Buchi mini spray dryer showed a melting endotherm (Tm at 112.2 ± 0.8 °C and ΔHf between 0.7 and 1.8 J/g), whereas samples from the cyclone tube to the drying chamber were devoid of crystalline material. The variations in drug-polymer mixing extend to miconazole/PVP-VA solid dispersions where 20% drug loading showed location-dependent drug-polymer mixing. This study clearly showed that the variation in drug-polymer miscibility and solid form of the drug in solid dispersions can occur across spray dryer in small-scale manufacturing processes. The optimization of formulation parameters and spray drying process parameters is imperative to diminish these variations to enhance homogeneity of solid dispersions in laboratory scale spray dryers. The same problem can occur in geometrically large spray drying manufacturing equipment, and the robustness of the processes should be carefully assessed. PMID:24533891

  12. R144 : a very massive binary likely ejected from R136 through a binary-binary encounter

    CERN Document Server

    Oh, Seungkyung; Banerjee, Sambaran

    2013-01-01

    R144 is a recently confirmed very massive, spectroscopic binary which appears isolated from the core of the massive young star cluster R136. The dynamical ejection hypothesis as an origin for its location is claimed improbable by Sana et al. due to its binary nature and high mass. We demonstrate here by means of direct N-body calculations that a very massive binary system can be readily dynamically ejected from a R136-like cluster, through a close encounter with a very massive system. One out of four N-body cluster models produces a dynamically ejected very massive binary system with a mass comparable to R144. The system has a system mass of $\\approx$ 355 Msun and is located at 36.8 pc from the centre of its parent cluster, moving away from the cluster with a velocity of 57 km/s at 2 Myr as a result of a binary-binary interaction. This implies that R144 could have been ejected from R136 through a strong encounter with an other massive binary or single star. In addition, we discuss all massive binaries and sin...

  13. Is There a Gap in the Gap? Regional Differences in the Gender Pay Gap

    OpenAIRE

    Hirsch, Boris; König, Marion; Möller, Joachim

    2009-01-01

    In this paper, we investigate regional differences in the gender pay gap both theoretically and empirically. Within a spatial oligopsony model, we show that more densely populated labour markets are more competitive and constrain employers' ability to discriminate against women. Utilising a large administrative data set for western Germany and a flexible semi-parametric propensity score matching approach, we find that the unexplained gender pay gap for young workers is substantially lower in ...

  14. The Organisational Gap Model for Hotel Management

    OpenAIRE

    Maja Uran

    2010-01-01

    This paper describes the development of the organisational gap model for hotel management. It descries a management measurement instrument that helps to assess the 3 organizational service gaps that are preconditions for delivering service quality (the positioning gap, specification gap and evaluation gap). The described theoretical model was constructed based upon the four organisational gaps of the Parasuraman et al. service quality model, then redefined and reassessed. Data were gathered o...

  15. Millisecond Pulsars in Close Binaries

    CERN Document Server

    Tauris, Thomas M

    2015-01-01

    In this Habilitationsschrift (Habilitation thesis) I present my research carried out over the last four years at the Argelander Institute for Astronomy (AIfA) and the Max Planck Institute for Radio Astronomy (MPIfR). The thesis summarizes my main findings and has been written to fulfill the requirements for the Habilitation qualification at the University of Bonn. Although my work is mainly focused on the topic of millisecond pulsars (MSPs), there is a fairly broad spread of research areas ranging from the formation of neutron stars (NSs) in various supernova (SN) events, to their evolution, for example, via accretion processes in binary and triple systems, and finally to their possible destruction in merger events. The thesis is organized in the following manner: A general introduction to neutron stars and millisecond pulsars is given in Chapter 1. A selection of key papers published in 2011-2014 are presented in Chapters 2-10, ordered within five main research areas (ultra-stripped SNe in close binaries, ma...

  16. Polarization in binary microlensing events

    International Nuclear Information System (INIS)

    The light received by source stars in microlensing events may be significantly polarized if both an efficient photon-scattering mechanism is active in the source stellar atmosphere and a differential magnification is therein induced by the lensing system. The best candidate events for observing polarization are highly magnified events with source stars belonging to the class of cool, giant stars in which the stellar light is polarized by photon scattering on dust grains contained in their envelopes. The presence in the stellar atmosphere of an internal cavity devoid of dust produces polarization profiles with a two peaks structure. Hence, the time interval between them gives an important observable quantity directly related to the size of the internal cavity and to the model parameters of the lens system. We show that, during a microlensing event, the expected polarization variability can solve an ambiguity that arises in some cases, related to the binary or planetary lensing interpretation of the perturbations observed near the maximum of the event light-curve. We consider a specific event case for which the parameter values corresponding to the two solutions are given. Then, assuming a polarization model for the source star, we compute the two expected polarization profiles. The position of the two peaks appearing in the polarization curves and the characteristic time interval between them allow us to distinguish between the binary and planetary lens solutions. (paper)

  17. Thermal and FTIR analysis of the miscibility and phase behaviour of poly (isobutyl methacrylate-co-4-vinylpyridine)/poly (styrene-co-acrylic acid) systems

    Energy Technology Data Exchange (ETDEWEB)

    Hadj-Hamou, Assia Siham; Habi, Abderrahmane [Laboratoire des Materiaux Polymeres, Faculte de Chimie, Universite des Sciences et de la Technologie Houari Boumediene, B.P. 32, El Alia, Algiers 16111 (Algeria); Djadoun, Said, E-mail: matpolylab@yahoo.fr [Laboratoire des Materiaux Polymeres, Faculte de Chimie, Universite des Sciences et de la Technologie Houari Boumediene, B.P. 32, El Alia, Algiers 16111 (Algeria)

    2010-01-10

    The miscibility and phase behaviour of poly (isobutyl methacrylate-co-4-vinylpyridine) containing 20 mol% of 4-vinylpyridine (IBM4VP20) and poly (styrene-co-acrylic acid) containing 27 or 32 mol% of acrylic acid (SAA27 or SAA32) mixtures were investigated by DSC, TGA and FTIR spectroscopy in the 25-180 {sup o}C temperature range. The results showed that sufficient specific carboxyl-pyridine hydrogen bonding interactions occurred between these copolymers and led to miscible blends as cast from THF and to inter-polymer complexes of significantly improved thermal stability when butan-2-one is the common solvent. The self-association effect on the inter-polymer interactions was evidenced by the decrease of complexation yields, observed when the carboxylic content is increased above 27 mol% as with SAA32. The trend of phase behaviour predicted by a thermodynamic analysis of the specific interactions of hydrogen bonding type that occurred between the two components of the SAA27/IBM4VP20 blends, neglecting the weak carboxyl-ester interactions and the functional group accessibility effect, carried out using the Painter-Coleman association model that considers the screening effects, is in a fair agreement with the experimental results. Moreover an LCST is predicted to occur at relatively high temperature.

  18. Thermal and FTIR analysis of the miscibility and phase behaviour of poly (isobutyl methacrylate-co-4-vinylpyridine)/poly (styrene-co-acrylic acid) systems

    International Nuclear Information System (INIS)

    The miscibility and phase behaviour of poly (isobutyl methacrylate-co-4-vinylpyridine) containing 20 mol% of 4-vinylpyridine (IBM4VP20) and poly (styrene-co-acrylic acid) containing 27 or 32 mol% of acrylic acid (SAA27 or SAA32) mixtures were investigated by DSC, TGA and FTIR spectroscopy in the 25-180 oC temperature range. The results showed that sufficient specific carboxyl-pyridine hydrogen bonding interactions occurred between these copolymers and led to miscible blends as cast from THF and to inter-polymer complexes of significantly improved thermal stability when butan-2-one is the common solvent. The self-association effect on the inter-polymer interactions was evidenced by the decrease of complexation yields, observed when the carboxylic content is increased above 27 mol% as with SAA32. The trend of phase behaviour predicted by a thermodynamic analysis of the specific interactions of hydrogen bonding type that occurred between the two components of the SAA27/IBM4VP20 blends, neglecting the weak carboxyl-ester interactions and the functional group accessibility effect, carried out using the Painter-Coleman association model that considers the screening effects, is in a fair agreement with the experimental results. Moreover an LCST is predicted to occur at relatively high temperature.

  19. Recombination spot identification Based on gapped k-mers.

    Science.gov (United States)

    Wang, Rong; Xu, Yong; Liu, Bin

    2016-01-01

    Recombination is crucial for biological evolution, which provides many new combinations of genetic diversity. Accurate identification of recombination spots is useful for DNA function study. To improve the prediction accuracy, researchers have proposed several computational methods for recombination spot identification. The k-mer feature is one of the most useful features for modeling the properties and function of DNA sequences. However, it suffers from the inherent limitation. If the value of word length k is large, the occurrences of k-mers are closed to a binary variable, with a few k-mers present once and most k-mers are absent. This usually causes the sparse problem and reduces the classification accuracy. To solve this problem, we add gaps into k-mer and introduce a new feature called gapped k-mer (GKM) for identification of recombination spots. By using this feature, we present a new predictor called SVM-GKM, which combines the gapped k-mers and Support Vector Machine (SVM) for recombination spot identification. Experimental results on a widely used benchmark dataset show that SVM-GKM outperforms other highly related predictors. Therefore, SVM-GKM would be a powerful predictor for computational genomics. PMID:27030570

  20. Carrying a Torch for Dust in Binary Star Systems

    CERN Document Server

    Cotton, Daniel V; Bott, Kimberly; Kedziora-Chudczer, Lucyna; Bailey, Jeremy

    2016-01-01

    Young stars are frequently observed to host circumstellar disks, within which their attendant planetary systems are formed. Scattered light imaging of these proto-planetary disks reveals a rich variety of structures including spirals, gaps and clumps. Self-consistent modelling of both imaging and multi-wavelength photometry enables the best interpretation of the location and size distribution of disks' dust. Epsilon Sagittarii is an unusual star system. It is a binary system with a B9.5III primary that is also believed to host a debris disk in an unstable configuration. Recent polarimetric measurements of the system with the High Precision Polarimetric Instrument (HIPPI) revealed an unexpectedly high fractional linear polarisation, one greater than the fractional infrared excess of the system. Here we develop a spectral energy distribution model for the system and use this as a basis for radiative transfer modelling of its polarisation with the RADMC-3D software package. The measured polarisation can be repro...

  1. Pulsating Components in Binary and Multiple Stellar Systems --- A Catalog of Oscillating Binaries

    OpenAIRE

    Zhou, A. -Y.

    2010-01-01

    We present an up-to-date catalog of pulsating binaries, i.e. the binary and multiple stellar systems containing pulsating components, along with a statistics on them. Compared to the earlier compilation by Soydugan et al.(2006a) of 25 delta Scuti-type `oscillating Algol-type eclipsing binaries' (oEA), the recent collection of 74 oEA by Liakos et al.(2012), and the collection of Cepheids in binaries by Szabados (2003a), the numbers and types of pulsating variables in binaries are now extended....

  2. The Evolution of Compact Binary Star Systems

    Directory of Open Access Journals (Sweden)

    Yungelson, Lev R.

    2006-12-01

    Full Text Available We review the formation and evolution of compact binary stars consisting of white dwarfs (WDs, neutron stars (NSs, and black holes (BHs. Binary NSs and BHs are thought to be the primary astrophysical sources of gravitational waves (GWs within the frequency band of ground-based detectors, while compact binaries of WDs are important sources of GWs at lower frequencies to be covered by space interferometers (LISA. Major uncertainties in the current understanding of properties of NSs and BHs most relevant to the GW studies are discussed, including the treatment of the natal kicks which compact stellar remnants acquire during the core collapse of massive stars and the common envelope phase of binary evolution. We discuss the coalescence rates of binary NSs and BHs and prospects for their detections, the formation and evolution of binary WDs and their observational manifestations. Special attention is given to AM CVn-stars -- compact binaries in which the Roche lobe is filled by another WD or a low-mass partially degenerate helium-star, as these stars are thought to be the best LISA verification binary GW sources.

  3. The Evolution of Compact Binary Star Systems

    Directory of Open Access Journals (Sweden)

    Konstantin A. Postnov

    2014-05-01

    Full Text Available We review the formation and evolution of compact binary stars consisting of white dwarfs (WDs, neutron stars (NSs, and black holes (BHs. Mergings of compact-star binaries are expected to be the most important sources for forthcoming gravitational-wave (GW astronomy. In the first part of the review, we discuss observational manifestations of close binaries with NS and/or BH components and their merger rate, crucial points in the formation and evolution of compact stars in binary systems, including the treatment of the natal kicks, which NSs and BHs acquire during the core collapse of massive stars and the common envelope phase of binary evolution, which are most relevant to the merging rates of NS-NS, NS-BH and BH-BH binaries. The second part of the review is devoted mainly to the formation and evolution of binary WDs and their observational manifestations, including their role as progenitors of cosmologically-important thermonuclear SN Ia. We also consider AM CVn-stars, which are thought to be the best verification binary GW sources for future low-frequency GW space interferometers.

  4. Eliciting Subjective Probabilities with Binary Lotteries

    DEFF Research Database (Denmark)

    Harrison, Glenn W.; Martínez-Correa, Jimmy; Swarthout, J. Todd

    We evaluate the binary lottery procedure for inducing risk neutral behavior in a subjective belief elicitation task. Harrison, Martínez-Correa and Swarthout [2013] found that the binary lottery procedure works robustly to induce risk neutrality when subjects are given one risk task defined over o...

  5. Pulsed Accretion onto Eccentric and Circular Binaries

    CERN Document Server

    Muñoz, Diego J

    2016-01-01

    We present numerical simulations of circumbinary accretion onto eccentric and circular binaries using the moving-mesh code AREPO. This is the first set of simulations to tackle the problem of binary accretion using a finite-volume scheme on a freely moving mesh, which allows for accurate measurements of accretion onto individual stars for arbitrary binary eccentricity. While accretion onto a circular binary shows bursts with period of ~5 times the binary period P_b,accretion onto an eccentric binary is predominantly modulated at the period ~1P_b. For an equal-mass circular binary, the accretion rates onto individual stars are quite similar to each other, following the same variable pattern in time. By contrast, for eccentric binaries, one of the stars can accrete at a rate 10-20 times larger than its companion. This "symmetry breaking" between the stars, however, alternates over timescales of order 200 P_b, and can be attributed to a slowly precessing, eccentric circumbinary disk. Over longer timescales, the ...

  6. ECCENTRIC EVOLUTION OF SUPERMASSIVE BLACK HOLE BINARIES

    International Nuclear Information System (INIS)

    In recent numerical simulations, it has been found that the eccentricity of supermassive black hole (SMBH)-intermediate black hole (IMBH) binaries grows toward unity through interactions with the stellar background. This increase of eccentricity reduces the merging timescale of the binary through the gravitational radiation to a value well below the Hubble time. It also gives a theoretical explanation of the existence of eccentric binaries such as that in OJ287. In self-consistent N-body simulations, this increase of eccentricity is always observed. On the other hand, the result of the scattering experiment between SMBH binaries and field stars indicated that the eccentricity dose not change significantly. This discrepancy leaves the high eccentricity of the SMBH binaries in N-body simulations unexplained. Here, we present a stellar-dynamical mechanism that drives the increase of the eccentricity of an SMBH binary with a large mass ratio. There are two key processes involved. The first one is the Kozai mechanism under a non-axisymmetric potential, which effectively randomizes the angular momenta of surrounding stars. The other is the selective ejection of stars with prograde orbits. Through these two mechanisms, field stars extract the orbital angular momentum of the SMBH binary. Our proposed mechanism causes the increase in the eccentricity of most of SMBH binaries, resulting in the rapid merger through gravitational wave radiation. Our result has given a definite solution to the 'last-parsec problem'.

  7. Microlensing Binaries with Candidate Brown Dwarf Companions

    DEFF Research Database (Denmark)

    Shin, I.-G; Han, C.; Gould, A.;

    2012-01-01

    Brown dwarfs are important objects because they may provide a missing link between stars and planets, two populations that have dramatically different formation histories. In this paper, we present the candidate binaries with brown dwarf companions that are found by analyzing binary microlensing ...

  8. Gravitational radiation, inspiraling binaries, and cosmology

    Science.gov (United States)

    Chernoff, David F.; Finn, Lee S.

    1993-01-01

    We show how to measure cosmological parameters using observations of inspiraling binary neutron star or black hole systems in one or more gravitational wave detectors. To illustrate, we focus on the case of fixed mass binary systems observed in a single Laser Interferometer Gravitational-wave Observatory (LIGO)-like detector. Using realistic detector noise estimates, we characterize the rate of detections as a function of a threshold SNR Rho(0), H0, and the binary 'chirp' mass. For Rho(0) = 8, H0 = 100 km/s/Mpc, and 1.4 solar mass neutron star binaries, the sample has a median redshift of 0.22. Under the same assumptions but independent of H0, a conservative rate density of coalescing binaries implies LIGO will observe about 50/yr binary inspiral events. The precision with which H0 and the deceleration parameter q0 may be determined depends on the number of observed inspirals. For fixed mass binary systems, about 100 observations with Rho(0) = 10 in the LIGO will give H0 to 10 percent in an Einstein-DeSitter cosmology, and 3000 will give q0 to 20 percent. For the conservative rate density of coalescing binaries, 100 detections with Rho(0) = 10 will require about 4 yrs.

  9. Gravitational waves from inspiralling binary black holes

    International Nuclear Information System (INIS)

    Binary black holes are the most promising candidate sources for the first generation of earth-based interferometric gravitational-wave detectors. We summarize and discuss the state-of-the-art analytical techniques developed during the last few years to better describe the late dynamical evolution of binary black holes of comparable masses

  10. Bayesian analysis of exoplanet and binary orbits

    CERN Document Server

    Schulze-Hartung, Tim; Henning, Thomas

    2012-01-01

    We introduce BASE (Bayesian astrometric and spectroscopic exoplanet detection and characterisation tool), a novel program for the combined or separate Bayesian analysis of astrometric and radial-velocity measurements of potential exoplanet hosts and binary stars. The capabilities of BASE are demonstrated using all publicly available data of the binary Mizar A.

  11. Positronium in solid phases of n-alkane binary mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Zgardzińska, B.; Goworek, T.

    2015-09-08

    Highlights: • Rotator phase in even alkanes C{sub n}H{sub 2n+2} with n ⩽ 20 appears in mixed samples only. • Interlamellar gap width is the same for shorter chain alkane concentration x and 1 − x. • Excess electron trapping diminishes with broadening of alkane chain distribution Δn. - Abstract: Binary mixtures of even-numbered normal alkanes C{sub n}H{sub 2n+2} and C{sub n+2}H{sub 2n+6} with n ⩽ 18 were investigated by positron annihilation spectroscopy. Formation of the rotator phase was observed in mixed structures, while no such a phase in neat alkanes in this range of n was found. Phase diagrams for n = 18 and n = 16 are very similar to the diagrams for binary mixtures of odd-numbered alkanes. The effect of positronium formation with trapped excess electrons weakens with decreasing n, at low n values the time constant of Ps rise contains the component much shorter than 1 h.

  12. Tidal disruption events by a massive black hole binary

    Science.gov (United States)

    Ricarte, Angelo; Natarajan, Priyamvada; Dai, Lixin; Coppi, Paolo

    2016-05-01

    Massive black hole binaries (MBHBs) are a natural byproduct of galaxy mergers. Previous studies have shown that flares from stellar tidal disruption events (TDEs) are modified by the presence of a secondary perturber, causing interruptions in the light curve. We study the dynamics of TDE debris in the presence of a milliparsec-separated MBHB by integrating ballistic particle orbits in the time-varying potential of the binary. We find that gaps in the light curve appear when material misses the accretion radius on its first return to pericentre. Subsequent recurrences can be decomposed into `continuous' and `delayed' components, which exhibit different behaviour. We find that this potential can substantially alter the locations of stream self-intersections. When debris is confined to the plane, we find that close encounters with the secondary massive black hole (MBH) leave noticeable signatures on the fallback rate and can result in significant accretion on to the secondary MBH. Tight, equal-mass MBHBs accrete equally, periodically trading the infalling stream.

  13. Planet Scattering Around Binaries: Ejections, Not Collisions

    CERN Document Server

    Smullen, Rachel A; Shannon, Andrew

    2016-01-01

    Transiting circumbinary planets discovered by Kepler provide unique insight into binary and planet formation. Several features of this new found population, for example the apparent pile-up of planets near the innermost stable orbit, may distinguish between formation theories. In this work, we determine how planet-planet scattering shapes planetary systems around binaries as compared to single stars. In particular, we look for signatures that arise due to differences in dynamical evolution in binary systems. We carry out a parameter study of N-body scattering simulations for four distinct planet populations around both binary and single stars. While binarity has little influence on the final system multiplicity or orbital distribution, the presence of a binary dramatically effects the means by which planets are lost from the system. Most circumbinary planets are lost due to ejections rather than planet-planet or planet-star collisions. The most massive planet in the system tends to control the evolution. Asid...

  14. Orbital dynamics of binary boson star systems

    International Nuclear Information System (INIS)

    We extend our previous studies of head-on collisions of boson stars by considering orbiting binary boson stars. We concentrate on equal-mass binaries and study the dynamical behavior of boson/boson and boson/antiboson pairs. We examine the gravitational wave output of these binaries and compare with other compact binaries. Such a comparison lets us probe the apparent simplicity observed in gravitational waves produced by black hole binary systems. In our system of interest however, there is an additional internal freedom which plays a significant role in the system's dynamics, namely, the phase of each star. Our evolutions show rather simple behavior at early times, but large differences occur at late times for the various initial configurations

  15. Logistic chaotic maps for binary numbers generations

    International Nuclear Information System (INIS)

    Two pseudorandom binary sequence generators, based on logistic chaotic maps intended for stream cipher applications, are proposed. The first is based on a single one-dimensional logistic map which exhibits random, noise-like properties at given certain parameter values, and the second is based on a combination of two logistic maps. The encryption step proposed in both algorithms consists of a simple bitwise XOR operation of the plaintext binary sequence with the keystream binary sequence to produce the ciphertext binary sequence. A threshold function is applied to convert the floating-point iterates into binary form. Experimental results show that the produced sequences possess high linear complexity and very good statistical properties. The systems are put forward for security evaluation by the cryptographic committees.

  16. Direct band gap silicon allotropes.

    Science.gov (United States)

    Wang, Qianqian; Xu, Bo; Sun, Jian; Liu, Hanyu; Zhao, Zhisheng; Yu, Dongli; Fan, Changzeng; He, Julong

    2014-07-16

    Elemental silicon has a large impact on the economy of the modern world and is of fundamental importance in the technological field, particularly in solar cell industry. The great demand of society for new clean energy and the shortcomings of the current silicon solar cells are calling for new materials that can make full use of the solar power. In this paper, six metastable allotropes of silicon with direct or quasidirect band gaps of 0.39-1.25 eV are predicted by ab initio calculations at ambient pressure. Five of them possess band gaps within the optimal range for high converting efficiency from solar energy to electric power and also have better optical properties than the Si-I phase. These Si structures with different band gaps could be applied to multiple p-n junction photovoltaic modules. PMID:24971657

  17. Virtual gap dielectric wall accelerator

    Energy Technology Data Exchange (ETDEWEB)

    Caporaso, George James; Chen, Yu-Jiuan; Nelson, Scott; Sullivan, Jim; Hawkins, Steven A

    2013-11-05

    A virtual, moving accelerating gap is formed along an insulating tube in a dielectric wall accelerator (DWA) by locally controlling the conductivity of the tube. Localized voltage concentration is thus achieved by sequential activation of a variable resistive tube or stalk down the axis of an inductive voltage adder, producing a "virtual" traveling wave along the tube. The tube conductivity can be controlled at a desired location, which can be moved at a desired rate, by light illumination, or by photoconductive switches, or by other means. As a result, an impressed voltage along the tube appears predominantly over a local region, the virtual gap. By making the length of the tube large in comparison to the virtual gap length, the effective gain of the accelerator can be made very large.

  18. Gap Junctions in C. elegans

    Directory of Open Access Journals (Sweden)

    ChristianC.Naus

    2014-02-01

    Full Text Available As in other multicellular organisms, the nematode Caenorhabditis elegans uses gap junctions to provide direct cell-to-cell contact. The nematode gap junctions are formed by innexins (invertebrate analogs of the connexins; a family of proteins that surprisingly share no primary sequence homology, but do share structural and functional similarity with connexins. The model organism C. elegans contains 25 innexin genes and innexins are found in virtually all cell types and tissues. Additionally, many innexins have dynamic expression patterns during development, and several innexins are essential genes in the nematode. C. elegans is a popular invertebrate model due to several features including a simple anatomy, a complete cell lineage, sequenced genome and an array of genetic resources. Thus the worm has potential to offer valuable insights into the various functions of gap junction mediated intercellular communication.

  19. Folk Belief Theory, the Rigor Gap, and the Achievement Gap

    Science.gov (United States)

    Torff, Bruce

    2014-01-01

    Folk belief theory is suggested as a primary cause for the persistence of the achievement gap. In this research-supported theory, culturally specified folk beliefs about learning and teaching prompt educators to direct more rigorous curriculum to high-advantage students but not to low-advantage students, resulting in impoverished pedagogy in…

  20. Microstrip microwave band gap structures

    Indian Academy of Sciences (India)

    V Subramanian

    2008-04-01

    Microwave band gap structures exhibit certain stop band characteristics based on the periodicity, impedance contrast and effective refractive index contrast. These structures though formed in one-, two- and three-dimensional periodicity, are huge in size. In this paper, microstrip-based microwave band gap structures are formed by removing the substrate material in a periodic manner. This paper also demonstrates that these structures can serve as a non-destructive characterization tool for materials, a duplexor and frequency selective coupler. The paper presents both experimental results and theoretical simulation based on a commercially available finite element methodology for comparison.

  1. Do roots mind the gap?

    OpenAIRE

    A. Carminati; Vetterlein, D; Koebernick, N.; Blaser, S; Weller, U; Vogel, H.-J.

    2012-01-01

    Roots need to be in good contact with the soil to take up water and nutrients. However, when the soil dries and roots shrink, air-filled gaps form at the root-soil interface. Do gaps actually limit the root water uptake, or do they form after water flow in soil is already limiting?Four white lupins were grown in cylinders of 20 cm height and 8 cm diameter. The dynamics of root and soil structure were recorded using X-ray CT at regular intervals during one drying/wetting cycle. Tensiometers we...

  2. The Emissions Gap Report 2014

    DEFF Research Database (Denmark)

    This fifth Emissions Gap report has a different focus from previous years. While it updates the 2020 emissions gap analysis, it gives particular attention to the implications of the global carbon dioxide emissions budget for staying within the 2 °C limit beyond 2020. It does so because countries...... are giving increasing attention to where they need to be in 2025, 2030 and beyond. Furthermore, this year’s update of the report benefits from the findings on the emissions budget from the latest series of Intergovernmental Panel on Climate Change (IPCC) reports...

  3. GlobalGAP-standardi vihannestuotannossa

    OpenAIRE

    Tuominen, Riina

    2011-01-01

    Opinnäytetyön tavoitteena oli antaa tietoa siitä, miten yritys voi valmistautua GlobalGAP-sertifiointiin ja kuinka viljelijät kokevat laatujärjestelmän. Työssä perehdytiin myös siihen, mitä GlobaGAPlaatujärjestelmä vaatii yrityksiltä ja kuinka se osaltaan turvaa yrityksen tuotteen laadun. Selvitys tehtiin GlobaGAP-prosessia havainnoimalla sekä kyselyllä ja haastattelulla GlobalGAPvalmennukseen osallistuneille viljelijöille. Apuna työssä käytettiin myös ennen valmennuksen aloitusta täytett...

  4. Polarization in binary microlensing events

    CERN Document Server

    Ingrosso, G; Nucita, A A; Strafella, F; Novati, S Calchi; Jetzer, Ph; Liuzzi, G; Zakharov, A

    2013-01-01

    The light received by source stars in microlensing events may be significantly polarized if both an efficient photon scattering mechanism is active in the source stellar atmosphere and a differential magnification is therein induced by the lensing system. The best candidate events for observing polarization are highly magnified events with source stars belonging to the class of cool, giant stars {in which the stellar light is polarized by photon scattering on dust grains contained in their envelopes. The presence in the stellar atmosphere of an internal cavity devoid of dust produces polarization profiles with a two peaks structure. Hence, the time interval between them gives an important observable quantity directly related to the size of the internal cavity and to the model parameters of the lens system.} We show that {during a microlensing event} the expected polarization variability can solve an ambiguity, that arises in some cases, related to the binary or planetary lensing interpretation of the perturba...

  5. Binary Cepheids from optical interferometry

    CERN Document Server

    Gallenne, A; Mérand, A; Monnier, J D; Pietrzyński, J Breitfelder G; Gieren, W

    2013-01-01

    Classical Cepheid stars have been considered since more than a century as reliable tools to estimate distances in the universe thanks to their Period-Luminosity (P-L) relationship. Moreover, they are also powerful astrophysical laboratories, providing fundamental clues for studying the pulsation and evolution of intermediate-mass stars. When in binary systems, we can investigate the age and evolution of the Cepheid, estimate the mass and distance, and constrain theoretical models. However, most of the companions are located too close to the Cepheid (1-40 mas) to be spatially resolved with a 10-meter class telescope. The only way to spatially resolve such systems is to use long-baseline interferometry. Recently, we have started a unique and long-term interferometric program that aims at detecting and characterizing physical parameters of the Cepheid companions, with as main objectives the determination of accurate masses and geometric distances.

  6. Binary theory of electronic stopping

    CERN Document Server

    Sigmund, P

    2002-01-01

    Binary stopping theory has been developed to characterize the electronic stopping of swift heavy ions in matter. It is an extension of Bohr's classical theory of 1913 incorporating screening, higher-order-Z sub 1 and shell corrections, high-speed quantum and relativity corrections as well as projectile excitation and ionization. The main numerical input comes from optical properties. The computation of shell corrections involves orbital velocity distributions of target and projectile electrons. Calculated stopping parameters depend on ion charge. Equilibrium stopping forces may be computed by adoption of a suitable model for the equilibrium charge state. This paper summarizes the current status of the theory, in particular the sensitivity of its predictions to pertinent input. Charge-dependent stopping forces have been calculated for selected systems and compared to experimental results. Equilibrium stopping forces calculated for a wide variety of ion-target combinations are compared with experimental data fr...

  7. Binary mixtures of chiral gases

    CERN Document Server

    Presilla, Carlo

    2015-01-01

    A possible solution of the well known paradox of chiral molecules is based on the idea of spontaneous symmetry breaking. At low pressure the molecules are delocalized between the two minima of a given molecular potential while at higher pressure they become localized in one minimum due to the intermolecular dipole-dipole interactions. Evidence for such a phase transition is provided by measurements of the inversion spectrum of ammonia and deuterated ammonia at different pressures. In particular, at pressure greater than a critical value no inversion line is observed. These data are well accounted for by a model previously developed and recently extended to mixtures. In the present paper, we discuss the variation of the critical pressure in binary mixtures as a function of the fractions of the constituents.

  8. Development of an inter-atomic potential for the Pd-H binary system.

    Energy Technology Data Exchange (ETDEWEB)

    Zimmerman, Jonathan A.; Hoyt, Jeffrey John (McMaster University, Hamilton, Ontario, Canada); Leonard, Francois Leonard; Griffin, Joshua D.; Zhou, Xiao Wang

    2007-09-01

    Ongoing research at Sandia National Laboratories has been in the area of developing models and simulation methods that can be used to uncover and illuminate the material defects created during He bubble growth in aging bulk metal tritides. Previous efforts have used molecular dynamics calculations to examine the physical mechanisms by which growing He bubbles in a Pd metal lattice create material defects. However, these efforts focused only on the growth of He bubbles in pure Pd and not on bubble growth in the material of interest, palladium tritide (PdT), or its non-radioactive isotope palladium hydride (PdH). The reason for this is that existing inter-atomic potentials do not adequately describe the thermodynamics of the Pd-H system, which includes a miscibility gap that leads to phase separation of the dilute (alpha) and concentrated (beta) alloys of H in Pd at room temperature. This document will report the results of research to either find or develop inter-atomic potentials for the Pd-H and Pd-T systems, including our efforts to use experimental data and density functional theory calculations to create an inter-atomic potential for this unique metal alloy system.

  9. The Adaptation Gap Report - a Preliminary Assessment

    DEFF Research Database (Denmark)

    Alverson, Keith; Olhoff, Anne; Noble, Ian;

    This first Adaptation Gap report provides an equally sobering assessment of the gap between adaptation needs and reality, based on preliminary thinking on how baselines, future goals or targets, and gaps between them might be defined for climate change adaptation. The report focuses on gaps in...... developing countries in three important areas: finance, technology and knowledge....

  10. Brain Responses to Filled Gaps

    Science.gov (United States)

    Hestvik, Arild; Maxfield, Nathan; Schwartz, Richard G.; Shafer, Valerie

    2007-01-01

    An unresolved issue in the study of sentence comprehension is whether the process of gap-filling is mediated by the construction of empty categories (traces), or whether the parser relates fillers directly to the associated verb's argument structure. We conducted an event-related potentials (ERP) study that used the violation paradigm to examine…

  11. Large gap magnetic suspension system

    Science.gov (United States)

    Abdelsalam, Moustafa K.; Eyssa, Y. M.

    1991-01-01

    The design of a large gap magnetic suspension system is discussed. Some of the topics covered include: the system configuration, permanent magnet material, levitation magnet system, superconducting magnets, resistive magnets, superconducting levitation coils, resistive levitation coils, levitation magnet system, and the nitrogen cooled magnet system.

  12. Denmark and the gap year

    DEFF Research Database (Denmark)

    Katznelson, Noemi; Juul, Tilde Mette

    2013-01-01

    This paper describes three different educational offers to young people: “The Folk High School”, “The ‘After-school’” and 10th class. All can be considered optional Gap Years. The following diagram shows how the Danish education system is structured. The Folk High School is a training course...

  13. Closing the Gaps. Research Brief

    Science.gov (United States)

    Johnston, Howard

    2011-01-01

    Achievement gaps between groups of students (minority and white, rich and poor, English speakers and English language learners) are complex and intractable. Increasingly, they are being seen as a result of disparities between opportunities for learning available to different groups. By changing the opportunity structures of schools and…

  14. Demand-Supply Gap Analysis

    OpenAIRE

    Aized H. Mir; Abidi, Sohail; Amer Z. Durrani

    2007-01-01

    An essential part of the Pakistan Infrastructure Implementation Capacity Assessment (PIICA) was an assessment of available resources and the demand generated for these resources by the proposed infrastructure projects. A demand-supply gap analysis for Human Resources (HR), major construction materials and equipment keeping in view the Medium Term Development Framework (MTDF) for up to 2010...

  15. A PHOTONIC BAND GAP FIBRE

    DEFF Research Database (Denmark)

    1999-01-01

    An optical fibre having a periodicidal cladding structure provididing a photonic band gap structure with superior qualities. The periodical structure being one wherein high index areas are defined and wherein these are separated using a number of methods. One such method is the introduction of...

  16. Band gap ion mass filter

    International Nuclear Information System (INIS)

    Ions in a plasma may be radially separated according to mass using a combination of an axial magnetic field and either a radial or azimuthal electric field. The separation is qualitatively different from that obtained by a plasma centrifuge and the characteristics of confined and unconfined ion orbits are analogous to the phenomenon of band gaps in semiconductors

  17. Gamma-ray binaries and related systems

    CERN Document Server

    Dubus, Guillaume

    2013-01-01

    After initial claims and a long hiatus, it is now established that several binary stars emit high (0.1-100 GeV) and very high energy (>100 GeV) gamma rays. A new class has emerged called 'gamma-ray binaries', since most of their radiated power is emitted beyond 1 MeV. Accreting X-ray binaries, novae and a colliding wind binary (eta Car) have also been detected - 'related systems' that confirm the ubiquity of particle acceleration in astrophysical sources. Do these systems have anything in common ? What drives their high-energy emission ? How do the processes involved compare to those in other sources of gamma rays: pulsars, active galactic nuclei, supernova remnants ? I review the wealth of observational and theoretical work that have followed these detections, with an emphasis on gamma-ray binaries. I present the current evidence that gamma-ray binaries are driven by rotation-powered pulsars. Binaries are laboratories giving access to different vantage points or physical conditions on a regular timescale as ...

  18. Interrupted Binary Mass Transfer in Star Clusters

    CERN Document Server

    Leigh, Nathan W C; Toonen, Silvia

    2016-01-01

    Binary mass transfer is at the forefront of some of the most exciting puzzles of modern astrophysics, including Type Ia supernovae, gamma-ray bursts, and the formation of most observed exotic stellar populations. Typically, the evolution is assumed to proceed in isolation, even in dense stellar environments such as star clusters. In this paper, we test the validity of this assumption via the analysis of a large grid of binary evolution models simulated with the SeBa code. For every binary, we calculate analytically the mean time until another single or binary star comes within the mean separation of the mass-transferring binary, and compare this time-scale to the mean time for stable mass transfer to occur. We then derive the probability for each respective binary to experience a direct dynamical interruption. The resulting probability distribution can be integrated to give an estimate for the fraction of binaries undergoing mass transfer that are expected to be disrupted as a function of the host cluster pro...

  19. The chromatic gap and its extremes

    CERN Document Server

    Gyárfás, András; Trotignon, Nicolas

    2011-01-01

    The {\\em chromatic gap} is the difference between the chromatic number and the clique number of a graph. Here we investigate $\\gap(n)$, the maximum chromatic gap over graphs on $n$ vertices. Can the extremal graphs be explored? While computational problems related to the chromatic gap are hopeless, an interplay between Ramsey theory and matching theory leads to a simple and (almost) exact formula for $\\gap(n)$ in terms of Ramsey numbers.

  20. Band gaps of primary metallic carbon nanotubes

    OpenAIRE

    Kleiner, Alex; Eggert, Sebastian

    2000-01-01

    Primary metallic, or small gap semiconducting nanotubes, are tubes with band gaps that arise solely from breaking the bond symmetry due to the curvature. We derive an analytic expression for these gaps by considering how a general symmetry breaking opens a gap in nanotubes with a well defined chiral wrapping vector. This approach provides a straightforward way to include all types of symmetry breaking effects, resulting in a simple unified gap equation as a function of chirality and deformati...

  1. Pd-Si binary bulk metallic glass

    Institute of Scientific and Technical Information of China (English)

    YAO KeFu; CHEN Na

    2008-01-01

    Pd80+xSi20-x (x=0, 1, and 2) binary metallic glasses with the diameter ranging from 7 to 8 mm were prepared by a combination of fluxing and water quenching or air cooling. Thermal analysis results show that with increasing Si content, the glass transition temperature Tg, the initial crystallization temperature Tx and the onset crystalliza-tion temperature Tp of Pd-Si binary glassy alloys increase. Moreover, the super-cooled liquid region reaches 61 K. It indicates that Pd-Si binary alloys possess large glass forming ability, which can be greatly improved by fluxing treatment.

  2. Pd-Si binary bulk metallic glass

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Pd80+xSi20-x (x=0,1,and 2) binary metallic glasses with the diameter ranging from 7 to 8 mm were prepared by a combination of fluxing and water quenching or air cooling. Thermal analysis results show that with increasing Si content,the glass transition temperature Tg,the initial crystallization temperature Tx and the onset crystalliza-tion temperature Tp of Pd-Si binary glassy alloys increase. Moreover,the super-cooled liquid region reaches 61 K. It indicates that Pd-Si binary alloys possess large glass forming ability,which can be greatly improved by fluxing treatment.

  3. Eliciting Subjective Probabilities with Binary Lotteries

    DEFF Research Database (Denmark)

    Harrison, Glenn W.; Martínez-Correa, Jimmy; Swarthout, J. Todd

    2014-01-01

    We evaluate a binary lottery procedure for inducing risk neutral behavior in a subjective belief elicitation task. Prior research has shown this procedure to robustly induce risk neutrality when subjects are given a single risk task defined over objective probabilities. Drawing a sample from the...... same subject population, we find evidence that the binary lottery procedure also induces linear utility in a subjective probability elicitation task using the Quadratic Scoring Rule. We also show that the binary lottery procedure can induce direct revelation of subjective probabilities in subjects with...

  4. Cassini states for black hole binaries

    OpenAIRE

    Correia, Alexandre C. M.

    2015-01-01

    Cassini states correspond to the equilibria of the spin axis of a body when its orbit is perturbed. They were initially described for planetary satellites, but the spin axes of black hole binaries also present this kind of equilibria. In previous works, Cassini states were reported as spin-orbit resonances, but actually the spin of black hole binaries is in circulation and there is no resonant motion. Here we provide a general description of the spin dynamics of black hole binary systems base...

  5. Fast algorithms for generating binary holograms

    CERN Document Server

    Stuart, Dustin; Kuhn, Axel

    2014-01-01

    We describe three algorithms for generating binary-valued holograms. Our methods are optimised for producing large arrays of tightly focussed optical tweezers for trapping particles. Binary-valued holograms allow us to use a digital mirror device (DMD) as the display element, which is much faster than other alternatives. We describe how our binary amplitude holograms can be used to correct for phase errors caused by optical aberrations. Furthermore, we compare the speed and accuracy of the algorithms for both periodic and arbitrary arrangements of traps, which allows one to choose the ideal scheme depending on the circumstances.

  6. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. II. P-TYPE BINARIES

    International Nuclear Information System (INIS)

    We have developed a comprehensive methodology for calculating the circumbinary habitable zone (HZ) in planet-hosting P-type binary star systems. We present a general formalism for determining the contribution of each star of the binary to the total flux received at the top of the atmosphere of an Earth-like planet and use the Sun's HZ to calculate the inner and outer boundaries of the HZ around a binary star system. We apply our calculations to the Kepler's currently known circumbinary planetary systems and show the combined stellar flux that determines the boundaries of their HZs. We also show that the HZ in P-type systems is dynamic and, depending on the luminosity of the binary stars, their spectral types, and the binary eccentricity, its boundaries vary as the stars of the binary undergo their orbital motion. We present the details of our calculations and discuss the implications of the results

  7. CALCULATING THE HABITABLE ZONE OF BINARY STAR SYSTEMS. II. P-TYPE BINARIES

    Energy Technology Data Exchange (ETDEWEB)

    Haghighipour, Nader [Institute for Astronomy and NASA Astrobiology Institute, University of Hawaii-Manoa, Honolulu, HI 96822 (United States); Kaltenegger, Lisa [MPIA, Koenigstuhl 17, Heidelberg, D-69117 (Germany)

    2013-11-10

    We have developed a comprehensive methodology for calculating the circumbinary habitable zone (HZ) in planet-hosting P-type binary star systems. We present a general formalism for determining the contribution of each star of the binary to the total flux received at the top of the atmosphere of an Earth-like planet and use the Sun's HZ to calculate the inner and outer boundaries of the HZ around a binary star system. We apply our calculations to the Kepler's currently known circumbinary planetary systems and show the combined stellar flux that determines the boundaries of their HZs. We also show that the HZ in P-type systems is dynamic and, depending on the luminosity of the binary stars, their spectral types, and the binary eccentricity, its boundaries vary as the stars of the binary undergo their orbital motion. We present the details of our calculations and discuss the implications of the results.

  8. Wavelet-based method for computing elastic band gaps of one-dimensional phononic crystals

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A wavelet-based method was developed to compute elastic band gaps of one-dimensional phononic crystals. The wave field was expanded in the wavelet basis and an equivalent eigenvalue problem was derived in a matrix form involving the adaptive computation of integrals of the wavelets. The method was then applied to a binary system. For comparison, the elastic band gaps of the same one-di- mensional phononic crystals computed with the wavelet method and the well- known plane wave expansion (PWE) method are both presented in this paper. The numerical results of the two methods are in good agreement while the computation costs of the wavelet method are much lower than that of PWE method. In addition, the adaptability of wavelets makes the method possible for efficient band gap computation of more complex phononic structures.

  9. Compact Binaries in Star Clusters I - Black Hole Binaries Inside Globular Clusters

    OpenAIRE

    Downing, J. M. B.; Benacquista, M. J.; Giersz, M.; Spurzem, R.

    2009-01-01

    We study the compact binary population in star clusters, focusing on binaries containing black holes, using a self-consistent Monte Carlo treatment of dynamics and full stellar evolution. We find that the black holes experience strong mass segregation and become centrally concentrated. In the core the black holes interact strongly with each other and black hole-black hole binaries are formed very efficiently. The strong interactions, however, also destroy or eject the black hole-black hole bi...

  10. Properties of planets in binary systems. The role of binary separation

    OpenAIRE

    Desidera, S.; Barbieri, M.

    2006-01-01

    The statistical properties of planets in binaries were investigated. Any difference to planets orbiting single stars can shed light on the formation and evolution of planetary systems. As planets were found around components of binaries with very different separation and mass ratio, it is particularly important to study the characteristics of planets as a function of the effective gravitational influence of the companion. A compilation of planets in binary systems was made; a search for compa...

  11. Were most Low Mass X ray Binaries born in Globular Clusters?

    CERN Document Server

    D'Antona, F; Ventura, P; Antona, Francesca D'; Teodorescu, Anamaria; Ventura, Paolo

    2006-01-01

    We summarize the status of art of the secular evolution of low mass X-ray binaries (LMXBs) and take a close look at the orbital period distribution of LMXBs and of binary millisecond pulsars (MSP), in the hypothesis that this latter results from the LMXB evolution. The deficiency of systems below the period gap, which in cataclysmic binaries occurs between ~ 2 and 3 hr, points to a very different secular evolution of LMXBs with respect to their counterparts containing a white dwarf compact object. The presence of several ultrashort period LMXBs (some of which are also X-ray millisecond pulsars), the important fraction of binary MSPs at periods between 0.1 and 1 day, the periods (26 and 32hr) of two ``interacting'' MSPs in Globular Clusters are other pieces of the puzzle in the period distribution. We consider the possible explanations for these peculiarities, and point out that Grindlay's old proposal that all (most of) LMXBs in the field were originally born in globular clusters must be carefully reconsidere...

  12. Air Gap Effects in LX-17

    Energy Technology Data Exchange (ETDEWEB)

    Souers, P C; Ault, S; Avara, R; Bahl, K L; Boat, R; Cunningham, B; Gidding, D; Janzen, J; Kuklo, D; Lee, R; Lauderbach, L; Weingart, W C; Wu, B; Winer, K

    2005-09-26

    Three experiments done over twenty years on gaps in LX-17 are reported. For the detonation front moving parallel to the gaps, jets of gas products were seen coming from the gaps at velocities greater than the detonation velocity. A case can be made that the jet velocity increased with gap thickness but the data is scattered. For the detonation front moving transverse to the gap, time delays were seen. The delays roughly increase with gap width, going from 0-70 ns at 'zero gap' to around 300 ns at 0.5-1 mm gap. Larger gaps of up to 6 mm width almost certainly stopped the detonation, but this was not proved. Real-time resolution of the parallel jets and determination of the actual re-detonation or failure in the transverse case needs to be done in future experiments.

  13. Binaries in the Hipparcos data: Keep digging

    CERN Document Server

    Pourbaix, D; Jorissen, A

    2004-01-01

    Among the 120 000 objects in the Hipparcos catalogue, only 235 were fitted with an orbital model. Besides these 235 original astrometric binaries, most Hipparcos entries with a known spectroscopic orbit (extrasolar planet or stellar companion) have now been re-processed, as part of the on-going construction of the 9th Catalogue of Spectroscopic Binary Orbits (SB9, available at http://sb9.astro.ulb.ac.be). The pitfalls and successes of this re-processing are discussed in various contexts, like (i) orbital inclinations: the holy grail for extrasolar planets (ii) searching for binaries without a priori knowledge of their spectroscopic orbital elements, and application to barium stars (iii) why not all SB9 entries yield acceptable astrometric solutions? The lessons learned from this study are useful to devise the best possible binary-detection and orbit-determination algorithms for future astrometric missions like GAIA.

  14. A mesoscopic model for binary fluids

    CERN Document Server

    Echeverria, C; Alvarez-Llamoza, O; Orozco-Guillén, E E; Morales, M; Cosenza, M G

    2016-01-01

    We propose a model to study symmetric binary fluids, based in the mesoscopic molecular simulation technique known as multiparticle collision, where space and state variables are continuous while time is discrete. We include a repulsion rule to simulate segregation processes that does not require the calculation of the interaction forces between particles, thus allowing the description of binary fluids at a mesoscopic scale. The model is conceptually simple, computationally efficient, maintains Galilean invariance, and conserves the mass and the energy in the system at micro and macro scales; while momentum is conserved globally. For a wide range of temperatures and densities, the model yields results in good agreement with the known properties of binary fluids, such as density profile, width of the interface, phase separation and phase growth. We also apply the model to study binary fluids in crowded environments with consistent results.

  15. Red-giant stars in eccentric binaries

    Directory of Open Access Journals (Sweden)

    Beck P. G.

    2015-01-01

    Full Text Available The unparalleled photometric data obtained by NASA’s Kepler Space Telescope has led to improved understanding of red-giant stars and binary stars. We discuss the characterization of known eccentric system, containing a solar-like oscillating red-giant primary component. We also report several new binary systems that are candidates for hosting an oscillating companion. A powerful approach to study binary stars is to combine asteroseimic techniques with light curve fitting. Seismology allows us to deduce the properties of red giants. In addition, by modeling the ellipsoidal modulations we can constrain the parameters of the binary system. An valuable independent source are ground-bases, high-resolution spectrographs.

  16. Evolution of Binary Stars in Multiple-Population Globular Clusters - II. Compact Binaries

    CERN Document Server

    Hong, Jongsuk; Sollima, Antonio; McMillan, Stephen L W; D'Antona, Franca; D'Ercole, Annibale

    2016-01-01

    We present the results of a survey of N-body simulations aimed at exploring the evolution of compact binaries in multiple-population globular clusters.We show that as a consequence of the initial differences in the structural properties of the first-generation (FG) and the second-generation (SG) populations and the effects of dynamical processes on binary stars, the SG binary fraction decreases more rapidly than that of the FG population. The difference between the FG and SG binary fraction is qualitatively similar to but quantitatively smaller than that found for wider binaries in our previous investigations.The evolution of the radial variation of the binary fraction is driven by the interplay between binary segregation, ionization and ejection. Ionization and ejection counteract in part the effects of mass segregation but for compact binaries the effects of segregation dominate and the inner binary fraction increases during the cluster evolution. We explore the variation of the difference between the FG an...

  17. Tidal capture formation of Low Mass X-Ray Binaries from wide binaries in the field

    CERN Document Server

    Michaely, Erez

    2015-01-01

    We present a potentially efficient dynamical formation scenario for Low Mass X-ray Binaries (LMXBs) in the field, focusing on black-hole (BH) LMXBs. In this formation channel LMXBs are formed from wide binaries $(>1000$ AU) with a BH component and a stellar companion. The wide binary is perturbed by fly-by's of field stars and its orbit random-walks and changes over time. This diffusion process can drive the binary into a sufficiently eccentric orbit such that the binary components tidally interact at peri-center and the binary evolves to become a short period binary, which eventually evolves into an LMXB. The formation rate of LMXBs through this channel mostly depends on the number of such BH wide binaries progenitors, which in turn depends on the velocity kicks imparted to BHs (or NSs) at birth. We consider several models for the formation and survival of such wide binaries, and calculate the LMXB formation rates for each model. We find that models where BHs form through direct collapse with no/little natal...

  18. Binary is Good: A Binary Inference Framework for Primary User Separation in Cognitive Radio Networks

    CERN Document Server

    Nguyen, Huy; Han, Zhu

    2010-01-01

    Primary users (PU) separation concerns with the issues of distinguishing and characterizing primary users in cognitive radio (CR) networks. We argue the need for PU separation in the context of collaborative spectrum sensing and monitor selection. In this paper, we model the observations of monitors as boolean OR mixtures of underlying binary latency sources for PUs, and devise a novel binary inference algorithm for PU separation. Simulation results show that without prior knowledge regarding PUs' activities, the algorithm achieves high inference accuracy. An interesting implication of the proposed algorithm is the ability to effectively represent n independent binary sources via (correlated) binary vectors of logarithmic length.

  19. Improved efficiency of miscible CO{sub 2} floods and enhanced prospects for CO{sub 2} flooding heterogeneous reservoirs. Annual report, June 1, 1997--May 31, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Grigg, R.B.; Schechter, D.S.

    1998-07-01

    The goal of this project is to improve the efficiency of miscible CO{sub 2} floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the first year of the three-year project that will be exploring three principle areas: (1) Fluid and matrix interactions (understanding the problems): interfacial tension (IFT), phase behavior, miscibility, capillary number, injectivity, wettability, and gravity drainage; (2) Conformance control/sweep efficiency (solving the problems): reduction of mobility using foam, diversion by selective mobility reduction (SMR) using foam, improved injectivity, alternating water and gas injection, and using horizontal wells; and (3) Reservoir simulation for improved oil recovery (predicting results): gravity drainage, SMR, CO{sub 2}-foam flooding, interfacial tension, injectivity profile, horizontal wells, and naturally fractured reservoirs. Studies of surfactant foam quality were performed during this first year. Simulation studies on a foam pilot area resulted in an acceptable history match model. The results confirm that the communication path between the foam injection well and a production well had a strong impact on the production performance. A laboratory study to aid in the development of a gravity drainage reservoir was undertaken on the Wellman Unit. Experiments were begun meant to duplicate situations of injectivity loss in WAG flooding and identify factors affecting the injectivity loss. The preliminary results indicate that for a given rock the injectivity loss depends on oil saturation in the core during WAG flooding. The injectivity loss is higher in cores with high in-situ oil saturations during WAG flooding. This effect is being verified by more experimental data.

  20. The Emissions Gap Report 2015

    DEFF Research Database (Denmark)

    Following the historic signing of the 2030 Agenda for Sustainable Development, this sixth edition of the UNEP Emissions Gap Report comes as world leaders start gathering in Paris to establish a new agreement on climate change. The report offers an independent assessment of the mitigation contribu......Following the historic signing of the 2030 Agenda for Sustainable Development, this sixth edition of the UNEP Emissions Gap Report comes as world leaders start gathering in Paris to establish a new agreement on climate change. The report offers an independent assessment of the mitigation...... contributions from the Intended Nationally Determined Contributions (INDC) committed to by 1 October 2015, by the 146 countries that account for around 90 per cent of global emissions. It compares the 2030 emission levels that would result from these commitments with what science tells us would keep average...