WorldWideScience

Sample records for bet surface area

  1. Characterization of pigment-leached antifouling coatings using BET surface area measurements and mercury porosimetry

    DEFF Research Database (Denmark)

    Kiil, Søren; Dam-Johansen, Kim

    2007-01-01

    In this work BET surface area measurements and mercury porosimetry are used to characterize leached layers formed when seawater-soluble pigments (Cu2O and ZnO) dissolve during accelerated leaching of simple antifouling coatings. Measurements on single-pigment coatings show that an increasing...

  2. Optimum BET surface areas for activated carbon produced from textile sewage sludges and its application as dye removal.

    Science.gov (United States)

    Kacan, Erdal

    2016-01-15

    The purpose of this experimental study is to determine optimum preparation conditions for activated carbons obtained from textile sewage sludge (TSS) for removal of dyes from aqueous solutions. The textile sewage sludge activated carbon (TSSAC) was prepared by chemical activation with potassium hydroxide using Response Surface Methodology (RSM). The most influential factor on each experimental design responses was identified via ANNOVA analysis. Based on the central composite design (CCD), quadratic model was developed to correlate the preparation variables for one response which is the Brunauer-Emmelt-Teller (BET) surface area. RSM based on a three-variable CCD was used to determine the effect of pyrolyzed temperature (400-700 °C), carbonization time (45-180 min) and KOH: weight of TSS (wt%) impregnation ratio (0.5:1-1.5:1) on BET surface area. According to the results, pyrolyzed temperature and impregnation ratio were found as the significant factors for maximizing the BET surface area. The major effect which influences the BET surface area was found as pyrolyzed temperature. Both carbonization time and impregnation ratio of KOH had no significant effect. The optimum conditions for preparing TSSAC, based on response surface and contour plots, were found as follows: pyrolyzed temperature 700 °C, carbonization time of 45 min and chemical impregnation ratio of 0.5. The maximum and optimum BET surface area of TSSAC were found as 336 m(2)/g and 310.62 m(2)/g, respectively. Synozol Blue reactive (RSB) and Setapers Yellow-Brown (P2RFL) industrial textile dyes adsorption capacities were investigated. As expected the TSSAC which has the biggest BET surface area (336 m(2)/g) adsorbed dye best. The maximum (RSB) and (P2RFL) uptake capacities were found as 8.5383 mg/g and 5.4 mg/g, respectively. The results of this study indicated the applicability of TSSAC for removing industrial dyes from aqueous solution. PMID:26496841

  3. Specific Surface versus Electrochemically Active Area of the Carbon/Polypyrrole Capacitor: Correlation of Ion Dynamics Studied by an Electrochemical Quartz Crystal Microbalance with BET Surface.

    Science.gov (United States)

    Mosch, Heike L K S; Akintola, Oluseun; Plass, Winfried; Höppener, Stephanie; Schubert, Ulrich S; Ignaszak, Anna

    2016-05-10

    Carbon/polypyrrole (PPy) composites are promising electrode materials for energy storage applications such as lightweight capacitors. Although these materials are composed of relatively inexpensive components, there is a gap of knowledge regarding the correlation between surface, porosity, ion exchange dynamics, and the interplay of the double layer capacitance and pseudocapacitance. In this work we evaluate the specific surface area analyzed by the BET method and the area accessible for ions using electrochemical quartz-crystal microbalance (EQCM) for SWCNT/PPy and carbon black Vulcan XC72-R/PPy composites. The study revealed that the polymer has significant influence on the pore size of the composites. Although the BET surface is low for the polypyrrole, the electrode mass change and thus the electrochemical area are large for the polymer-containing electrodes. This indicates that multiple redox active centers in the charged polymer chain are good ion scavengers. Also, for the composite electrodes, the effective charge storage occurs at the polypyrrole-carbon junctions, which are easy to design/multiply by a proper carbon-to-polymer weight ratio. The specific BET surface and electrochemically accessible surface area are both important parameters in calculation of the electrode capacitance. SWCNTs/PPy showed the highest capacitances normalized to the BET and electrochemical surface as compared to the polymer-carbon black. TEM imaging revealed very homogeneous distribution of the nanosized polymer particles onto the CNTs, which facilitates the synergistic effect of the double layer capacitance (CNTs) and pseudocapacitance (polymer). The trend in the electrode mass change in correlation with the capacitance suggest additional effects such as a solvent co-insertion into the polymer and the contribution of the charge associated with the redox activity of oxygen-containing functional groups on the carbon surface. PMID:27082127

  4. Effect of BET surface area of recycled U3O8 powder on Mn-Al doped UO2 pellets property

    International Nuclear Information System (INIS)

    Research on fuel pellets focuses on increasing the pellet density and grain size to increase the uranium contents and the high burn-up safety margins for LWRs. In the commercial manufacturing of UO2 fuel pellets, defective UO2 pellets that do not meet the manufacturing specifications of density and diameter may be produced. Defective UO2 pellets or scraps of pellets should be reused in manufacturing new UO2 pellets. A commonly used recycling method for defective UO2 pellets or scraps of pellets is that defective UO2 pellets are oxidized in air at about 450 .deg. C to make U3O8 powder and then added to UO2 powder. Because the recycled U3O8 powder has a low sinter-ability compared to the raw UO2 powder, addition of U3O8 to UO2 leads to a drop in the pellet density, impeding a grain growth and the formation of undesired graph-like pore segregates. This adverse effect of recycled U3O8 powder on UO2 pellet property becomes more severe in large grain sized UO2 pellets. In general, the sinter-active powder should have small size and large BET surface area. However, since the powder property of U3O8 depends on the initial grain size of UO2 pellets, larger grain UO2 pellet produces poorer sinter-active U3O8 powders having larger particle size and smaller BET surface area. In this paper, the effects of several process parameters on U3O8 powder properties have been tested. It is suggested that BET surface area of recycled U3O8 powder can be increased by applying low temperature oxidation and/or sequential cyclic thermal treatment procedures. The effect of those recycled U3O8 powder on the UO2 pellet properties is also investigated. The U3O8 powders having higher BET surface area can mitigate the UO2 pellet density drop

  5. Assessment of solvent extraction efficiency in sandstones using BET [Brunauer-Emmett-Teller] specific surface area measurements

    Energy Technology Data Exchange (ETDEWEB)

    French, P.R.; Mannhardt, K.; DeBree, N.; Shaw, J.C. [Petroleum Recovery Inst. (Canada)

    1995-03-01

    Cleaning core is standard procedure prior to routine measurement of parameters such as porosity and permeability, and before performing special core analyses. It is shown that the cleaning efficiency of different solvents and the degree of cleanliness of a core can be assessed through specific surface area measurements. Berea and Crossfield Cardium sandstone sandstone core plugs containing residual Crossfield Cardium oil from laboratory core floods were extracted with the azeotropic mixture of chloroform/methanol, toluene, and methylene chloride, and the specific surface areas were measured as a function of cleaning time. Solvent cleaning increased the specific surface areas by a factor of three to four in some instances. Cloroform/methanol was found to be the most efficient of the three tested solvents. It is shown that the presence of residual oil may render a drastically reduced specific surface area for a rock, but the specific surface area can be restored to its original value by extraction with chloroform/methanol. The solvent itself does not seem to alter the clay structure within the rock. 19 refs., 4 figs., 5 tabs.

  6. Synthesis of MOF having hydroxyl functional side groups and optimization of activation process for the maximization of its BET surface area

    International Nuclear Information System (INIS)

    To accomplish the postsynthetic modification of MOF with organic-metal precursors (OMPs) described in our previous researches more efficiently, synthesis of MOF (HCC-2) possessing relatively larger pore size as well as higher number of hydroxyl functional side groups per its base unit than those of HCC-1 has been successfully conducted via adopting 1,4-di-(4-carboxy-2,6-dihydroxyphenyl)benzene as an organic ligand and Zn(NO3)2·6H2O as a metal source, respectively. Also, optimization about the Activation process of HCC-2 was performed to maximize its BET (Brunauer–Emmett–Teller) surface area which was proved to be proportional to the number of exposed active sites on which its postsynthetic modification occurred. However, Activation process having been validated to be so effective with the acquirement of highly-purified HCC-1 (CO2 supercritical drying step followed by vacuum drying step) was less satisfactory with the case of HCC-2. This might be attributed to relatively higher hydrophilicity and bulkier molecular structure of organic ligand of HCC-2. However, it was readily settled by simple modification of above Activation process. Moreover, indispensable residues composed of both DMF and its thermally degraded derivatives which were chemically attached via coordination bond with hydroxyl functionalities even after Activation process III might enable their H2 adsorption properties to be seriously debased compared to that of IRMOF-16 having no hydroxyl functionalities. - Graphical abstract: Synthesis of new-structured MOF (HCC-2) simultaneously possessing relatively larger pore size as well as higher number of hydroxyl functional side groups per its base unit at the same time than those of HCC-1 has been performed via adopting 1,4-di-(4-carboxy-2,6-dihydroxyphenyl)benzene as an organic ligand and Zn(NO3)2·6H2O as a metal source, respectively. Also, the optimization of activation process for HCC-2 was conducted to maximize its BET surface area while the

  7. COMPARISON OF BET AND WATER ADSORPTION TECHNIQUES

    OpenAIRE

    B. H. Diyaâuddeen; I. A. Mohammed; B. Y. Jibril; I. M. Bugaje

    2013-01-01

    The effect of activated carbon surface area on the amount of fluid adsorbed is significant. Thus, the surface area of an adsorbent is an important factor. The use of the costly BET measurement method is the standard. However, water adsorption method was proposed as an alternate method. Nevertheless, results presented were for activated carbon prepared and surface areas reported were based on BET literature values. In this study, chemically activated carbons were produced from corn cobs by imp...

  8. The determination of surface of powders by BET method using nitrogen and krypton with computer calculation of the results

    International Nuclear Information System (INIS)

    A computer program written in FORTRAN language for calculations of final results of specific surface analysis based on BET theory has been described. Two gases - nitrogen and krypton were used. A technical description of measuring apparaturs is presented as well as theoretical basis of the calculations together with statistical analysis of the results for uranium compounds powders. (author)

  9. BET measurements: Outgassing of minerals

    DEFF Research Database (Denmark)

    Clausen, Liselotte; Fabricius, Ida Lykke

    2000-01-01

    in minor errors, implying that aquifer sediments containing poorly crystalline materials can be outgassed at low temperatures if the outgassing time is increased. Scanning electron microscopy of the studied minerals demonstrated that the particle size as calculated from BET data compares well with......Outgassing minerals at elevated temperatures prior to BET measurements can lead to phase changes, especially in the case of amorphous and poorly crystalline materials. In order to evaluate the applicability of the BET method when low outgassing temperatures are required, selected aquifer minerals...... were outgassed at different temperatures and for different times. The studied minerals are 2-line ferrihydrite, goethite, lepidocrocite, quartz, calcite, ®-alumina, and kaolinite. The results demonstrate that measured specific surface areas of iron oxides are strongly dependent on outgassing conditions...

  10. Rattleback bet

    Science.gov (United States)

    Dail, Steve

    2011-05-01

    A neat twist to the "rattleback" or "celt" demonstration was revealed to me after a "bet" with one of my AP® Physics students.2 I asked the class to try to explain what is responsible for the spinning piece of plastic to suddenly reverse its direction of spin. Some thought about air friction, others discussed the offset center of gravity. There are many online sources with detailed explanations, as well as in TPT,3 so I will not try to explain it here, but I felt that friction between the rattleback and the table definitely played a major role in the explanation. My student disagreed. The next day my student showed up to class with a small container of Vaseline and declared, "We will settle this right now. Let's grease up a lab table and spin the rattleback and see what happens." (I wish all my students were this curious!) First, we spun the rattleback several times on a clean table to see the interesting spin reversal. Then after applying a thin layer of Vaseline to the table, we spun the rattleback. Try it yourself (or email me) to see who won the bet!

  11. Betting exchanges : the future of sports betting?

    NARCIS (Netherlands)

    Koning, Ruud H.; Velzen, B. van

    2009-01-01

    Sports betting and sports have always been strongly connected. Traditionally, these betting markets have been cleared by bookmakers, who accept bets on certain events. These bookmakers carry the risk of paying the amount wagered if the event occurs. Recently, a new type of betting market has appeare

  12. Epitope grafting, re-creating a conformational Bet v 1 antibody epitope on the surface of the homologous apple allergen Mal d 1

    DEFF Research Database (Denmark)

    Holm, Jens; Ferreras, Mercedes; Ipsen, Henrik; Würtzen, Peter A; Gajhede, Michael; Larsen, Jørgen N; Lund, Kaare; Spangfort, Michael D

    2011-01-01

    Birch-allergic patients often experience oral allergy syndrome upon ingestion of vegetables and fruits, most prominently apple, that is caused by antibody cross-reactivity of the IgE antibodies in patients to proteins sharing molecular surface structures with the major birch pollen group 1 allergen...... from Betula verrucosa (Bet v 1). Still, to what extent two molecular surfaces need to be similar for clinically relevant antibody cross-reactivity to occur is unknown. Here, we describe the grafting of a defined conformational antibody epitope from Bet v 1 onto the surface of the homologous apple...... allergen Malus domestica group 1 (Mal d 1). Engineering of the epitope was accomplished by genetic engineering substituting amino acid residues in Mal d 1 differing between Bet v 1 and Mal d 1 within the epitope defined by the mAb BV16. The kinetic parameters characterizing the antibody binding interaction...

  13. Specific surface area of some minerals commonly found in granite

    OpenAIRE

    Dubois, Isabelle E.

    2011-01-01

    The specific surface area, determined by the BET method, is a parameter often used to scale results of mineral studies of surface reactions in terms of rate and capacity to the field scale. Such extrapolations of results from small-scale laboratory experiments to the field-scale are important within many environmental applications. An example of this is for the prediction of radionuclide retention in the bedrock surrounding a deep repository for radioactive waste, following failure of the eng...

  14. High surface area calcite

    Science.gov (United States)

    Schultz, L. N.; Andersson, M. P.; Dalby, K. N.; Müter, D.; Okhrimenko, D. V.; Fordsmand, H.; Stipp, S. L. S.

    2013-05-01

    Calcite (CaCO3) is important in many fields—in nature, because it is a component of aquifers, oil reservoirs and prospective CO2 storage sites, and in industry, where it is used in products as diverse as paper, toothpaste, paint, plastic and aspirin. It is difficult to obtain high purity calcite with a high surface area but such material is necessary for industrial applications and for fundamental calcite research. Commercial powder is nearly always contaminated with growth inhibitors such as sugars, citrate or pectin and most laboratory synthesis methods deliver large precipitates, often containing vaterite or aragonite. To address this problem, we (i) adapted the method of carbonating a Ca(OH)2 slurry with CO2 gas to develop the first simple, cheap, safe and reproducible procedure using common laboratory equipment, to obtain calcite that reproducibly had a surface area of 14-17 m2/g and (ii) conducted a thorough characterization of the product. Scanning electron microscopy (SEM) revealed nanometer scale, rhombohedral crystals. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (IR) confirmed highly crystalline, pure calcite that more closely resembles the dimensions of the biogenic calcite produced by algae in coccoliths than other methods for synthesizing calcite. We suggest that this calcite is useful when purity and high surface area are important.

  15. An investigation into the correlation between different surface area determination techniques applied to various limestone-related compounds

    Energy Technology Data Exchange (ETDEWEB)

    Potgieter, J.H. [PPC Technical Services, Johannesburg (South Africa); Strydom, C.A. [Univ. of Pretoria (South Africa)

    1996-11-01

    This communication reports an investigation between various methods used to measure the surface area of ground materials used in the cement industry. From the results it seems possible to make a reasonable estimate of the limestone, lime and gypsum BET surface areas from a Blaine surface area determination.

  16. Synthesis and characterization of high-surface-area millimeter-sized silica beads with hierarchical multi-modal pore structure by the addition of agar

    International Nuclear Information System (INIS)

    Millimeter-sized spherical silica foams (SSFs) with hierarchical multi-modal pore structure featuring high specific surface area and ordered mesoporous frameworks were successfully prepared using aqueous agar addition, foaming and drop-in-oil processes. The pore-related properties of the prepared spherical silica (SSs) and SSFs were systematically characterized by field emission-scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), small-angle X-ray diffraction (SAXRD), Hg intrusion porosimetry, and N2 adsorption–desorption isotherm measurements. Improvements in the BET surface area and total pore volume were observed at 504 m2 g−1 and 5.45 cm3 g−1, respectively, after an agar addition and foaming process. Despite the increase in the BET surface area, the mesopore wall thickness and the pore size of the mesopores generated from the block copolymer with agar addition were unchanged based on the SAXRD, TEM, and BJH methods. The SSFs prepared in the present study were confirmed to have improved BET surface area and micropore volume through the agar loading, and to exhibit interconnected 3-dimensional network macropore structure leading to the enhancement of total porosity and BET surface area via the foaming process. - Highlights: • Millimeter-sized spherical silica foams (SSFs) are successfully prepared. • SSFs exhibit high BET surface area and ordered hierarchical pore structure. • Agar addition improves BET surface area and micropore volume of SSFs. • Foaming process generates interconnected 3-D network macropore structure of SSFs

  17. Ultrasonic-induced synthesis of high surface area colloids CeO2-ZrO2

    International Nuclear Information System (INIS)

    The nanostructures of high surface area ceria-zirconia colloids have been successfully synthesized via a sonochemical method in the presence of polyethylene glycol 600. Their structural characteristics have been investigated using powder XRD, FESEM, BET surface area, TG, and other techniques. The average size of CeO2-ZrO2 nanoparticles is estimated to be 3.7 nm using Debye-Scherrer's equation. The BET analysis indicates that colloids CeO2-ZrO2 have a remarkably high surface area of 226 m2 g-1.

  18. Metal-organic framework materials with ultrahigh surface areas

    Science.gov (United States)

    Farha, Omar K.; Hupp, Joseph T.; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Gomez-Gualdron, Diego A.; Borah, Bhaskarjyoti

    2015-12-22

    A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

  19. Tritium retention in nanostructured tungsten with large effective surface area

    International Nuclear Information System (INIS)

    Tungsten specimens with fiberform nanostructure (Nano-W) were prepared by exposure to helium plasma in the divertor plasma simulator NAGDIS-II with different amounts of helium fluence. For comparison, tungsten specimens with smooth surface (Polished-W) were also prepared. Surface area of Nano-W was measured by using Brunauer, Emmet and Teller (B.E.T.) method. Tritium retention of Nano-W and Polished-W was investigated by an imaging plate (IP) and β-ray induced X-ray spectrometry (BIXS) technique exposure to mixture gas of deuterium and tritium. It was found that surface area of Nano-W was significantly larger than that of Polished-W and increased in proportion to the amount of helium irradiation. On the other hand, tritium retention showed a saturation trend when the helium fluence was higher than 5.0 × 1025 m−2

  20. Dominating IgE-binding epitope of Bet v 1, the major allergen of birch pollen, characterized by X-ray crystallography and site-directed mutagenesis

    DEFF Research Database (Denmark)

    Spangfort, Michael D; Mirza, Osman; Ipsen, Henrik;

    2003-01-01

    surface area of Bet v 1 and is clearly conformational. A synthetic peptide representing a sequential motif in the epitope (11 of 16 residues) did not inhibit the binding of mAb BV16 to Bet v 1, illustrating limitations in the use of peptides for B cell epitope characterization. The single amino acid...

  1. Synthesis and application of magnesium oxide nanospheres with high surface area

    International Nuclear Information System (INIS)

    Graphical abstract: Display Omitted Highlights: ► MgO nanospheres with high specific surface area synthesized by the polyol method. ► The BET specific surface area of nanopowders was 102 m2/g by calcining at ∼250 °C. ► MgO nanospheres were applied to remove hexavalent chromium. -- Abstract: Magnesium oxide (MgO) nanospheres with a high specific surface area were synthesized by the polyol method. The BET specific surface area of the nanopowders was ∼90 m2/g by adjusting the molar ratio of the precursor, the reaction time, and the washing solution. It was increased to 102 m2/g by calcining at ∼250 °C. Scanning electron microscopic and transmission electron microscopic observations showed that the MgO nanospheres composed of highly folded flakes, which were responsible for the observed high surface area. The high BET characteristic of the MgO nanospheres can be applied to sintering of microwave ceramics at a reducing sintering temperature, uniformed grain size distribution, and high bulk density. Finally, their capacity to remove hexavalent chromium was presented.

  2. Betting Against Beta

    DEFF Research Database (Denmark)

    Frazzini, Andrea; Heje Pedersen, Lasse

    .S. equities, 20 international equity markets, Treasury bonds, corporate bonds, and futures; (2) A betting-against-beta (BAB) factor, which is long leveraged low beta assets and short high-beta assets, produces significant positive risk-adjusted returns; (3) When funding constraints tighten, the return of the...

  3. AN EXAMPLE IN SURFACE AREA*

    Science.gov (United States)

    Goffman, Casper

    1969-01-01

    For length and area, a central fact is that the value of the length of a curve or the area of a surface, as given by the Lebesgue theory, is at least as great as that given by the classical formula, whenever the latter has meaning. This is now found not to be valid in higher dimensions. We give an example of a continuous mapping of the unit cube into itself for which the value given by the formula exceeds the three-dimensional Lebesgue area of the corresponding suface. PMID:16591750

  4. Superconducting properties and Fermi-surface topology of the quasi-two-dimensional organic superconductor λ-(BETS)2GaCl4 (BETS≡bis(ethylene-dithio)tetraselenafulvalene)

    International Nuclear Information System (INIS)

    The Fermi-surface topology of the organic superconductor λ-(BETS)2GaCl4 has been determined using the Shubnikov-de Haas and magnetic breakdown effects and angle-dependent magnetoresistance oscillations. The former experiments were carried out in pulsed fields of up to 60 T, whereas the latter employed quasistatic fields of up to 30 T. All of these data show that the Fermi-surface topology of λ-(BETS)2GaCl4 is very similar to that of the most heavily studied organic superconductor, κ-(BEDT-TTF)2Cu(NCS)2 (BEDT-TTF≡bis(ethylene-dithio)tetrathiafulvalene), except in one important respect: the interplane transfer integral of λ-(BETS)2GaCl4 is a factor ∼5 larger than that of κ-(BEDT-TTF)2Cu(NCS)2. The increased three-dimensionality of λ-(BETS)2GaCl4 is manifested in radio-frequency penetration-depth measurements, which show a clear dimensional crossover in the behaviour of Hc2(T). The radio-frequency measurements have also been used to extract the Labusch parameter determining the fluxoid interactions as a function of temperature, and to map the flux-lattice melting curve. (author)

  5. BET is active on Sellafield site

    International Nuclear Information System (INIS)

    Several companies, all part of BET Plant Services are carrying out work at the British Nuclear Fuels (BNFL) site at Sellafield, Cumbria, on one of the largest construction projects in Europe. The main development scheme is the THORP (Thermal Oxide Reprocessing Plant) buildings. One of the BET companies has the contract to paint the inside of the fuel storage ponds. It will also coat the surfaces of the MASWEP (Medium Active Solid Waste Encapsulation Plant) complex. Other work includes insulation and fire prevention installation. Scaffolding at the EARP (Enhanced Actinide Removal Plant) site is being provided on a common user basis so all the contractors can use the scaffolding and share the cost. Temporary office and living accommodation blocks have been provide by another BET company. (author)

  6. Facile synthesis of high surface area molybdenum nitride and carbide

    International Nuclear Information System (INIS)

    The synthesis of high surface area γ-Mo2N and α-Mo2C is reported (116 and 120 m2/g) without the temperature programmed reduction of MoO3. γ-Mo2N was prepared in an NH3-free synthesis using forming gas (7 at% H2, N2-balance) as the reactive atmosphere. Three precursors were studied ((NH4)6Mo7O24·4H2O, (NH4)2 Mg(MoO4)2, and MgMoO4) along with the sacrificial support method (SSM) as a means of reducing the particle size of Mo2N and Mo2C. In situ X-ray diffraction (XRD) studies were carried out to identify reaction intermediates, the temperature at which various intermediates form, and the average domain size of the Mo2N products. Materials were synthesized in bulk and further characterized by XRD, HRTEM, XPS, and BET. - Highlights: • Facile synthesis of γ-Mo2N and α-Mo2C with surface area exceeding 100 m2/g. • Sacrificial support method was used to achieve these high surface areas. • Materials can serve as catalysts or supports in (electro)chemical processes

  7. The Change in Surface Area Properties of Blast Furnace

    Directory of Open Access Journals (Sweden)

    Rađenović, A.

    2009-04-01

    Full Text Available Blast furnace sludge-BFS is a by-product and waste material of the iron and steel industry. Recently, the adsorption capabilities of blast furnace sludge have been attracting great interest. It is known that materials with modified surface properties can be obtained by different chemical and thermal treatments.The aim of this work was to investigate the influence of chemical treatment by acetic acid and thermal treatment by heating at 700 °C, on the surface properties of blast furnace sludge. Chemical treatment was performed by acetic acid adsorption on BFS.Microscopic observation was conducted using scanning electron microscopy (SEM method. Changes in examined surface area properties were analyzed by Brunauer-Emmett-Teller (BET and Barrett-Joyner-Halenda (BJH methods.Increasing of specific surface area, decreasing of pore size and better pore size distribution in BFS samples were registered after the applied experimental procedure. The obtained results revealed that the performed chemical and heat treatment presented the activation of blast furnace sludge.

  8. Synthesis of high surface area TiO2 coatings on stainless steel by electrophoretic deposition

    OpenAIRE

    Schiemann, Daniel; Alphonse, Pierre; Taberna, Pierre-Louis

    2013-01-01

    Large surface area, homogenous, and adhesive TiO2 coatings on stainless steel substrates were prepared by electrophoretic deposition (EPD) of colloidal dispersions of TiO2 nanoparticles in water and ethanol. Several chemical additives were used to optimize the deposition process. The best results were obtained for dispersions in water containing a mixture of Tiron and Pluronic® F127, which gave homogeneous layers, showing excellent adhesion and a large BET surface area, close to 200 m2/g. Eth...

  9. Dye-Sensitized Solar Cells Based on High Surface Area Nanocrystalline Zinc Oxide Spheres

    Directory of Open Access Journals (Sweden)

    Pavuluri Srinivasu

    2011-01-01

    Full Text Available High surface area nanocrystalline zinc oxide material is fabricated using mesoporous nanostructured carbon as a sacrificial template through combustion process. The resulting material is characterized by XRD, N2 adsorption, HR-SEM, and HR-TEM. The nitrogen adsorption measurement indicates that the materials possess BET specific surface area ca. 30 m2/g. Electron microscopy images prove that the zinc oxide spheres possess particle size in the range of 0.12 μm–0.17 μm. The nanocrystalline zinc oxide spheres show 1.0% of energy conversion efficiency for dye-sensitized solar cells.

  10. T-bet as a key regulator of mucosal immunity.

    Science.gov (United States)

    Mohamed, Rami; Lord, Graham M

    2016-04-01

    Initially understood to be a key regulator of interferon-γ-producing helper T cells, our knowledge of T-bet's functional roles has expanded to encompass a growing range of cellular lineages. In addition to regulating other interferon-γ-producing adaptive immune cells, it is now clear that T-bet plays a fundamental role in the regulation of innate immune responses across mucosal surfaces. This homeostatic role is demonstrated by the spontaneous colitis that occurs when T-bet is deleted from innate immune cells in RAG(-/-) mice. Using this model as a focal point, we review our understanding of T-bet's regulation of adaptive and innate immune systems, focusing particularly on mucosal populations including innate lymphoid cells, dendritic cells and intraepithelial lymphocytes. With the increasingly diverse effects of T-bet on different lineages, the classical binding-centric paradigm of T-bet's molecular functionality has increasingly struggled to account for the versatility of T-bet's biological effects. Recent recognition of the synergistic interactions between T-bet and other canonical transcription factors has led to a co-operative paradigm that has provided greater explanatory power. Synthesizing insights from ChIP-seq and comparative biology, we expand the co-operative paradigm further and suggest a network approach as a powerful way to understand and model T-bet's diverse functionality. PMID:26726991

  11. Pore Scale Heterogeneity in the Mineral Distribution and Surface Area of Porous Rocks

    Science.gov (United States)

    Lai, Peter; Krevor, Sam

    2015-04-01

    An important control on rate of interfacial processes between minerals and aqueous solutions such as nucleation of solids, and mineral dissolution and growth is reactive surface area. In geochemical modelling, the continuum hypothesis is based on the assumption that the system can be represented by a sufficiently large number of representative elemental volumes. There has been recent interest in studying the impact of this assumption on reaction-transport coupled systems. In this study, the impact of pore-scale heterogeneity on the distribution of reactive surface area is discussed. 3D images obtained using x-ray micro-tomography were used to characterise the distribution of reactive surface area. The results were compared to independent observations. Mineral identification using x- ray diffraction and fluorescence suggested general agreement with CT analysis. Nitrogen BET surface areas were one to two orders of magnitude higher than measurements from x-ray imagery. Co- registered images of Berea sandstone from x-ray and energy dispersive spectroscopy imagery suggested that quartz, K-feldspar and most clays could be identified. However, minor minerals such as albite and illite did not exhibit enough contrast. In Berea sandstone, mineral surface area fraction was poorly correlated to the mineral volumetric fraction. Clay and feldspar minerals exhibited higher surface area fractions than bulk mineralogy suggested. In contrast, in the Edwards carbonate samples, modal mineral composition correlated with mineral-specific surface area. Berea sandstone revealed a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. Conversely, the carbonate samples suggested a continuous range of pore sizes across length scales. A comparison with pore network model simulations from the literature was made. First order estimates of mineral specific correlations between geometric area measured in the x-ray images were used to convert the CT

  12. Determination of oxide film thickness on aluminium using 14-MeV neutron activation and BET method

    International Nuclear Information System (INIS)

    A new method is described for the determination of the mean film thickness of aluminium oxides by 14-MeV neutron activation analysis of the oxygen and by BET measurement of the surface area. The mean film thickness obtained is independent of the surface roughness. Stable oxide films consisting of only a few atomic layers of oxygen are detected on aluminium. (author)

  13. The Importance of Betting Early

    OpenAIRE

    Alessandro Innocenti; Tommaso Nannicini; Roberto Ricciuti

    2012-01-01

    We analyze more than 1,250,000 bets on Italian soccer league matches. Our findings show that bettors do not improve their performance as the season progresses. We obtain evidence that early bettors, who place bets the days before the match, performed better then late bettors, who place bets on the same day of the event. We attribute this outcome to the increase of noisy information released the last day impairing late bettors’ capacity to use very simple prediction methods, such as team ranki...

  14. Effective reactive surface area: An anisotropic property of physically and chemically heterogeneous porous media

    International Nuclear Information System (INIS)

    Although transport calculations are often formulated in terms of mass-based isotropic distribution coefficients, it is the abundance of reactive surface areas of subsurface materials that controls contaminant adsorption. In water-saturated homogeneous systems devoid of advective fluxes (e.g., batch experiments), the available reactive surface area is similar to the total surface area (as measured by conventional methods such as BET gas adsorption). However, in physically and chemically heterogeneous systems with advective fluxes, the effective reactive surface area (i.e., the surface area that a packet of advecting water interacts with) is smaller than the laboratory measured surface area and is a complex function of advective velocity and the correlation structures of the physical and chemical heterogeneities. Theoretical derivations for an important but simple type of heterogeneity (fine-scale horizontal layering) suggest that the effective reactive surface area is an anisotropic property of the medium and is inversely correlated with the anisotropy in hydraulic conductivity. The implications of reactive transport anisotropy include the concept that the retardation factor should be treated as a directional property rather than being treated as a constant. Furthermore, because of the inverse relationship between effective reactive surface area and hydraulic conductivity, batch adsorption experiments tend to overestimate the retention of contaminants relative to intact natural materials

  15. Body Surface Area Prediction in Odorrana grahami

    Institute of Scientific and Technical Information of China (English)

    Guiying CHEN; Jiongyu LIU; Qiang DAI; Jianping JIANG

    2014-01-01

    Body surface area (BSA) was regarded as a more readily quantiifable parameter relative to body mass in the normalization of comparative biochemistry and physiology. The BSA prediction has attracted unceasing research back more than a century on animals, especially on humans and rats. Few studies in this area for anurans were reported, and the equation for body surface area (S) and body mass (W):S=9.9 W 0.56, which was concluded from toads of four species in 1969, was generally adopted to estimate the body surface areas for anurans until recent years. However, this equation was not applicable to Odorrana grahami. The relationship between body surface area and body mass for this species was established as:S=15.4 W 0.579. Our current results suggest estimation equations should be used cautiously across different species and body surface area predictions on more species need to be conducted.

  16. Preparation of High Surface Area, Large Pore Volume Alumina by Using β-Cyclodextrin as a Non-surfactant Template

    Institute of Scientific and Technical Information of China (English)

    Lai Jun WANG; Ming Fen WEN; Yu Shan LI; Dong YANG; Jing CHEN; Chong Li SONG

    2006-01-01

    A series of alumina samples were prepared using β-cyclodextrin as the non-surfactant template. These samples were characterized by XRD, BET and TEM. The results showed that the alumina samples prepared using β-cyclodextrin template had the higher surface areas (124-484 m2/g), larger pore volumes (0.7-1.27 mL/g) and more thermal stability than samples prepared without using β-cyclodextrin.

  17. Comparison of various sources of high surface area carbon prepared by different types of activation

    International Nuclear Information System (INIS)

    Activated carbon has been known as an excellent adsorbent and is widely used due to its large adsorption capacity. Activation condition and types of activation influence the surface area and porosity of the activated carbon produced. In this study, palm kernel shells and commercially activated carbon were used. To convert palm kernel shells into coal, two methods were employed, namely chemical activation and physical activation. For chemical activation, two activating agents, zinc chloride and potassium carbonate, were used. The activated carbons were analyzed using Fourier Transform Infrared (FTIR) spectroscopy, single point BET and free emission scanning electron microscopy (FESEM). The commercial activated carbon was also characterized. FTIR results indicate that all the palm kernel shells were successfully converted to carbon. Single point BET surface area of all the carbons prepared were obtained. From FESEM micrograph, the chemically activated palm kernel shells shows well highly defined cavities and pores. This study also shows that palm kernel shells can be used to be a better source of high surface area carbon. (author)

  18. Corporate Social Responsibility in the Gambling and Betting Activities Industry

    OpenAIRE

    Ševčíková, Terézia

    2016-01-01

    The bachelor thesis is focused on Corporate Social Responsibility in the Gambling and Betting Activities Industry in the Czech Republic. Based on the quantitative research in gambling and betting enterprises in the Czech Republic an analysis was performed and current CSR situation was evaluated. Analysis revealed that the selected sector supports relatively actively CSR activities in all three areas. Furthermore, considerable number of enterprises engages the corporate social responsibility i...

  19. Nondestructive, stereological estimation of canopy surface area

    DEFF Research Database (Denmark)

    Wulfsohn, Dvora-Laio; Sciortino, Marco; Aaslyng, Jesper M.; García-Fiñana, Marta

    2010-01-01

    We describe a stereological procedure to estimate the total leaf surface area of a plant canopy in vivo, and address the problem of how to predict the variance of the corresponding estimator. The procedure involves three nested systematic uniform random sampling stages: (i) selection of plants from...... a canopy using the smooth fractionator, (ii) sampling of leaves from the selected plants using the fractionator, and (iii) area estimation of the sampled leaves using point counting. We apply this procedure to estimate the total area of a chrysanthemum (Chrysanthemum morifolium L.) canopy and...... counting is high. Using a grid intensity of 1.76 cm2/point we estimated plant and canopy surface areas with accuracies similar to or better than those obtained using image analysis and a commercial leaf area meter. For canopy surface areas of approximately 1 m2 (10 plants), the fractionator leaf approach...

  20. Mesoporous high surface area Ce0.9Gd0.1O1.95 synthesized by spray drying

    DEFF Research Database (Denmark)

    Lundberg, Mats; Wang, Hsiang-Jen; Blennow Tullmar, Peter;

    2011-01-01

    Mesoporous gadolinium doped cerium dioxide with high surface area was produced by spray drying using Pluronic 123 as surfactant. The powder, when calcined at 400 °C, had a BET surface area of 136 m2 g−1 and was polycrystalline as confirmed by XRD and TEM. XEDS confirmed Ce, Gd and O, as the only......, corresponding to the crystallite size calculated from XRD data. The similar size range of the mesopores and the observed crystallite size indicates that the porosity is partly formed from intergranular mesoporosity. Using the spray drying method of a surfactant assisted liquid precursor solution it can be...

  1. Archaeology of Bet Dwarka Island

    Digital Repository Service at National Institute of Oceanography (India)

    Sundaresh; Gaur, A.S.

    the protohistoric and historic period were found. The former include a seal, inscriptions and pottery, while the latter consist of coins and pottery. The earliest settlement at Bet Dwarka may be dated to the late phase of the Indus Civilization, i.e. c. 1400 B...

  2. Kelly Criterion revisited: optimal bets

    CERN Document Server

    Piotrowski, E W; Piotrowski, Edward W.; Schroeder, Malgorzata

    2006-01-01

    Kelly criterion, that maximizes the expectation value of the logarithm of wealth for bookmaker bets, gives an advantage over different class of strategies. We use projective symmetries for a explanation of this fact. Kelly's approach allows for an interesting financial interpretation of the Boltzmann/Shannon entropy. A "no-go" hypothesis for big investors is suggested.

  3. Characterization and use of high surface area activated carbons prepared from cane pith for liquid-phase adsorption

    International Nuclear Information System (INIS)

    Carbonaceous adsorbents with controllable surface areas were chemically activated with KOH at 780 deg. C from char that had been carbonized from cane pith at 450 deg. C. The pore properties including the BET surface area, pore volume, pore size distribution, and mean pore diameter of these activated carbons were characterized and derived using the t-plot method based on N2 adsorption isotherms. The activated cane pith carbons, with KOH/char ratios of 2-6, exhibited BET surface areas ranging from 912 to 2299 m2 g-1. The scanning electron microscopic (SEM) observations revealed that the surface morphology of honeycombed holes on all activated cane pith carbons was significantly influenced by the KOH/char ratio. The adsorption kinetics and equilibrium isotherms of acid blue 74, methylene blue, basic brown 1, p-nitrophenol, p-chlorophenol, p-cresol, and phenol from water at 30 deg. C on the activated carbons were studied. The adsorption kinetics were suitably described by a simplified kinetic model, the Elovich equation. All adsorption equilibrium isotherms were in agreement with the Langmuir equation, and were used to compare the covered area (S c/S p) of the activated carbons at different KOH/char ratios. The high-surface-area activated carbons were proven to be promising adsorbents for pollution control and for other applications

  4. Determining surface areas of marine alga cells by acid-base titration method.

    Science.gov (United States)

    Wang, X; Ma, Y; Su, Y

    1997-09-01

    A new method for determining the surface area of living marine alga cells was described. The method uses acid-base titration to measure the surface acid/base amount on the surface of alga cells and uses the BET (Brunauer, Emmett, and Teller) equation to estimate the maximum surface acid/base amount, assuming that hydrous cell walls have carbohydrates or other structural compounds which can behave like surface Brönsted acid-base sites due to coordination of environmental H2O molecules. The method was applied to 18 diverse alga species (including 7 diatoms, 2 flagellates, 8 green algae and 1 red alga) maintained in seawater cultures. For the species examined, the surface areas of individual cells ranged from 2.8 x 10(-8) m2 for Nannochloropsis oculata to 690 x 10(-8) m2 for Dunaliella viridis, specific surface areas from 1,030 m2.g-1 for Dunaliella salina to 28,900 m2.g-1 for Pyramidomonas sp. Measurement accuracy was 15.2%. Preliminary studies show that the method may be more promising and accurate than light/electron microscopic measurements for coarse estimation of the surface area of living algae. PMID:9297794

  5. Betting on wind energy

    International Nuclear Information System (INIS)

    In the first part of this study, the authors try to identify whether the economical and environmental context is adapted to the wind energy development. In order to do so, they discuss wind energy as a possible answer to climate emergency, critics formulated against wind energy, the effects of the financial crisis and the opportunities offered by wind energy within this crisis. In the second part, they discuss the French context and the debates on wind energy, highlighting the importance of some parameters in the cost analysis of wind turbine, presenting the results of a sensitivity analysis, and highlighting the importance of the over-cost calculation. They assess the current development status of the French wind energy industry and underline the opportunities for the future. In the third part, they describe the development status, lever and perspectives in different countries: Germany where the development of this sector has been successful, China which is becoming a major actor, the United States which are displaying the highest growth in this area, and Denmark which is the world leader

  6. Adsorbed Natural Gas Storage in Optimized High Surface Area Microporous Carbon

    Science.gov (United States)

    Romanos, Jimmy; Rash, Tyler; Nordwald, Erik; Shocklee, Joshua Shawn; Wexler, Carlos; Pfeifer, Peter

    2011-03-01

    Adsorbed natural gas (ANG) is an attractive alternative technology to compressed natural gas (CNG) or liquefied natural gas (LNG) for the efficient storage of natural gas, in particular for vehicular applications. In adsorbants engineered to have pores of a few molecular diameters, a strong van der Walls force allows reversible physisorption of methane at low pressures and room temperature. Activated carbons were optimized for storage by varying KOH:C ratio and activation temperature. We also consider the effect of mechanical compression of powders to further enhance the volumetric storage capacity. We will present standard porous material characterization (BET surface area and pore-size distribution from subcritical N2 adsorption) and methane isotherms up to 250 bar at 293K. At sufficiently high pressure, specific surface area, methane binding energy and film density can be extracted from supercritical methane adsorption isotherms. Research supported by the California Energy Commission (500-08-022).

  7. Powder characterisation-surface area measurement of porous granular materials and powder specimens used in nuclear industry

    International Nuclear Information System (INIS)

    As surface area is one of the important parameters for characterising the catalytic activity and the reactivity of powders and compacts, determination of surface area of precursor materials is therefore, essential to optimize process control. In nuclear technology, many aspects like monitoring sinterability of powders for fuel pin fabrication, dissolution of crust developed from corrosion products in coolant channels and sorption of active gases for cooling the activity before releasing the gases into the environment require a knowledge of surface area of precursor specimens to assess the efficiency of these catalyst or sorbents. This paper discusses the surface area analyser built in Analytical Chemistry Division, B.A.R.C., based on single point BET nitrogen adsorption isotherm, and its use in characterizing many specimens like activated carbon, palladium coated alumina catalysts, magnetite, haematite, etc. (author)

  8. Monitoring System for ALICE Surface Areas

    CERN Document Server

    Demirbasci, Oguz

    2016-01-01

    I have been at CERN for 12 weeks within the scope of Summer Student Programme working on a monitoring system project for surface areas of the ALICE experiment during this period of time. The development and implementation of a monitoring system for environmental parameters in the accessible areas where a cheap hardware setup can be deployed were aim of this project. This report explains how it was developed by using Arduino, Raspberry PI, WinCC OA and DIM protocol.

  9. Chemical weathering rates of a soil chronosequence on granitic alluvium: I. Quantification of mineralogical and surface area changes and calculation of primary silicate reaction rates

    Science.gov (United States)

    White, A.F.; Blum, A.E.; Schulz, M.S.; Bullen, T.D.; Harden, J.W.; Peterson, M.L.

    1996-01-01

    Mineral weathering rates are determined for a series of soils ranging in age from 0.2-3000 Ky developed on alluvial terraces near Merced in the Central Valley of California. Mineralogical and elemental abundances exhibit time-dependent trends documenting the chemical evolution of granitic sand to residual kaolinite and quartz. Mineral losses with time occur in the order: hornblende > plagioclase > K-feldspar. Maximum volume decreases of >50% occur in the older soils. BET surface areas of the bulk soils increase with age, as do specific surface areas of aluminosilicate mineral fractions such as plagioclase, which increases from 0.4-1.5 m2 g-1 over 600 Ky. Quartz surface areas are lower and change less with time (0.11-0.23 m2 g-1). BET surface areas correspond to increasing external surface roughness (?? = 10-600) and relatively constant internal surface area (??? 1.3 m2 g-1). SEM observations confirm both surface pitting and development of internal porosity. A numerical model describes aluminosilicate dissolution rates as a function of changes in residual mineral abundance, grain size distributions, and mineral surface areas with time. A simple geometric treatment, assuming spherical grains and no surface roughness, predicts average dissolution rates (plagioclase, 10-17.4; K-feldspar, 10-17.8; and hornblende, 10-17.5 mol cm-1 s-1) that are constant with time and comparable to previous estimates of soil weathering. Average rates, based on BET surface area measurements and variable surface roughnesses, are much slower (plagioclase, 10-19.9; K-feldspar, 10-20.5; and hornblende 10-20.1 mol cm-2 s-1). Rates for individual soil horizons decrease by a factor of 101.5 over 3000 Ky indicating that the surface reactivities of minerals decrease as the physical surface areas increase. Rate constants based on BET estimates for the Merced soils are factors of 103-104 slower than reported experimental dissolution rates determined from freshly prepared silicates with low surface

  10. Surface area estimation: pocket calculator v nomogram.

    OpenAIRE

    Briars, G L; Bailey, B J

    1994-01-01

    Three sheets of 10 surface area determinations were completed by 10 subjects using a nomogram and a formula. The formula was faster to calculate, 4.27 v 7.6 minutes for each sheet, and resulted in fewer serious errors (three v 30 errors).

  11. Have betting exchanges corrupted horse racing?

    OpenAIRE

    Brown, Alasdair; Yang, Fuyu

    2016-01-01

    Betting exchanges allow punters to bet on a horse to lose a race. This, many argue, has opened up the sport to a new form of corruption, where races will be deliberately lost in order to profit from betting. We examine whether anecdotal evidence of the fixing of horses to lose - of which there are many examples - is indicative of wider corruption. Following a ‘forensic economics’ approach, we build an asymmetric information model of exchange betting, and take it to betting data on 9,560 races...

  12. Low-Risk Investing without Industry Bets

    DEFF Research Database (Denmark)

    Asness, Clifford S.; Frazzini, Andrea; Heje Pedersen, Lasse

    2014-01-01

    The strategy of buying safe low-beta stocks while shorting (or underweighting) riskier high-beta stocks (“betting against beta”) has been shown to deliver significant risk-adjusted returns. Some have suggested, however, that such “low-risk investing” delivers high returns primarily because of...... industry bets that favor a slowly changing set of stodgy, stable industries. The authors refute this notion by showing that a strategy of betting against beta has delivered positive returns both as an industry-neutral bet within each industry and as a pure bet across industries....

  13. Synthesis of high surface area ZnO powder by continuous precipitation

    International Nuclear Information System (INIS)

    Graphical abstract: High surface area ZnO powders are synthesized by a low temperature continuous precipitation under ultrasonication. Urea is used as precipitating agent so that no contamination of ZnO powder emanating from precipitating agent, such as, alkalis, is observed. pH and type of precursor greatly affects the surface area and other properties. In this manuscript, we report a very simple and effective continuous precipitation to synthesize high surface area ZnO powder. Highlights: ► The synthesis of high surface area ZnO powder was achieved at 90 °C in a continuous precipitation unit. ► Continuous precipitation unit was ultrasonicated to improve final product homogeneity. ► Precipitation intermediate, hydrozincite, was led to high surface area ZnO powder. ► The synthesized ZnO nanoparticles had a rather uniform mesoporous structure. -- Abstract: Synthesis of high surface area ZnO powder was achieved by continuous precipitation using zinc ions and urea at low temperature of 90 °C. The powder precipitated resulted in high-purity single-phase ZnO powder when calcined at 280 °C for 3 h in air. The solution pH and the precipitation duration strongly affected the surface area of the calcined ZnO powder. Detailed structural characterizations demonstrated that the synthesized ZnO powder were single crystalline with wurtzite hexagonal phase. The powdered samples precipitated by homogeneous precipitation crystallized directly to hydrozincite without any intermediate phase formation. The phase structures, morphologies and properties of the final ZnO powders were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), dynamic light scattering particle size analysis (DLS), and nitrogen physisorption in order to determine the specific surface area (BET) and the pore size distribution (BJH).

  14. Sol-gel preparation of high surface area potassium tetratitanate for the immobilization of nuclear waste metal ions

    International Nuclear Information System (INIS)

    Potassium tetratinates(K2Ti4O9) were synthesized by using the sol-gel method to produce ion-exchangeable materials with high surface area. The effects of mole ratios of K/Ti and H2O/Ti were examined. K2Ti4O9 was obtained at 740 deg. C by the sol-gel method, which uses a lower temperature than the melting method. After calcination at 800 deg. C, K2Ti4O exhibits a needle shape which is quite different from the shape of K2Ti6O13 powder. The surface areas of K2Ti4O9 was 15 m2/g by the sol-gel method after calcining at 800 C. The enhancement of BET area to 25 m2/g was obtained after supercritical drying using EtOH as solvent. By using the sodium alginate method, needle type potassium titanate 10μm in length, the longest aspect ratio of 1,3 x 103 could be obtained. There are variations in the Sr2+ ion exchange rate and capacity according to the preparation method. Larger BET surface area provides fast ion exchange and larger capacity for Sr2+ ion in the order; sol-gel process with supercritical drying > sol-gel process > melting process. (author). 17 refs, 21 figs, 1 tab

  15. Bet-hedging applications for conservation

    Indian Academy of Sciences (India)

    Mark S Boyce; Eileen M Kirsch; Christopher Servheen

    2002-07-01

    One of the early tenets of conservation biology is that population viability is enhanced by maintaining multiple populations of a species. The strength of this tenet is justified by principles of bet-hedging. Management strategies that reduce variance in population size will also reduce risk of extinction. Asynchrony in population fluctuations in independent populations reduces variance in the aggregate of populations whereas environmental correlation among areas increases the risk that all populations will go extinct. We review the theoretical rationale of bet-hedging and suggest applications for conservation management of least terns in Nebraska and grizzly bears in the northern Rocky Mountains of the United States. The risk of extinction for least terns will be reduced if we can sustain the small central Platte River population in addition to the larger population on the lower Platte. Similarly, by restoring grizzly bears to the Bitterroot wilderness of Idaho and Montana can reduce the probability of extinction for grizzly bears in the Rocky Mountains of the United States by as much as 69–93%.

  16. High surface area fibrous silica nanoparticles

    KAUST Repository

    Polshettiwar, Vivek

    2014-11-11

    Disclosed are high surface area nanoparticles that have a fibrous morphology. The nanoparticles have a plurality of fibers, wherein each fiber is in contact with one other fiber and each fiber has a length of between about 1 nm and about 5000 nm. Also disclosed are applications of the nanoparticles of the present invention, and methods of fabrication of the nanoparticles of the present invention.

  17. The effect of specific surface area on radionuclide sorption on crushed crystalline rock

    International Nuclear Information System (INIS)

    The sorption of sodium (22Na), calcium (45Ca) and strontium (85Sr) was studied on mica gneiss, unaltered, moderately altered and strongly altered tonalite samples taken from hole SY-KR7 drilled in the Syyry area in Sievi, Western Finland. The crushed rock samples were sieved into six fractions from 71 microm to 1,250 microm. A proportional mineral composition for the different fractions were estimated by X-ray diffraction. The specific fraction surface areas were determined by the BET nitrogen adsorption method. The fractal method was applied to characterize rocks and to describe quantitatively surface irregularity. The mass distribution ratio values for each fraction were determined using the static batch method. The sorption of tracers onto different minerals was observed using rock thin sections. Kd-values calculated from thin section Ka-values and Kd-values obtained from batch experiments were in good agreement. Mass distribution ratios for different size fractions are given, and the effect of the specific surface area is discussed. Owing to larger specific surface areas considerably higher sorption on smaller fractions was found for altered tonalities

  18. The effect of specific surface area on radionuclide sorption on crushed crystalline rock

    Energy Technology Data Exchange (ETDEWEB)

    Hoelttae, P.; Siitari-Kauppi, M.; Huikuri, P. [Univ. of Helsinki (Finland). Dept. of Chemistry; Lindberg, A. [Geological Survey of Finland, Espoo (Finland); Hautojaervi, A. [VTT Energy (Finland)

    1997-12-31

    The sorption of sodium ({sup 22}Na), calcium ({sup 45}Ca) and strontium ({sup 85}Sr) was studied on mica gneiss, unaltered, moderately altered and strongly altered tonalite samples taken from hole SY-KR7 drilled in the Syyry area in Sievi, Western Finland. The crushed rock samples were sieved into six fractions from 71 {micro}m to 1,250 {micro}m. A proportional mineral composition for the different fractions were estimated by X-ray diffraction. The specific fraction surface areas were determined by the BET nitrogen adsorption method. The fractal method was applied to characterize rocks and to describe quantitatively surface irregularity. The mass distribution ratio values for each fraction were determined using the static batch method. The sorption of tracers onto different minerals was observed using rock thin sections. K{sub d}-values calculated from thin section K{sub a}-values and K{sub d}-values obtained from batch experiments were in good agreement. Mass distribution ratios for different size fractions are given, and the effect of the specific surface area is discussed. Owing to larger specific surface areas considerably higher sorption on smaller fractions was found for altered tonalities.

  19. Scalable synthesis of three-dimensional interconnected mesoporous TiO2 nanotubes with ultra-large surface area

    International Nuclear Information System (INIS)

    Mesoporous nanotubes represent a unique class of nanostructures with numerous applications including biomaterials, lithium ion battery anodes, and photocatalysts. Herein we describe for the first time a general, scalable, and reproducible approach for the production of 3D interconnected mesoporous TiO2 nanotubes with ultrahigh specific surface area and large pore volume by using a nanofibrous template of bacterial cellulose (BC). The obtained samples were characterized by Brunauer–Emmett–Teller (BET) surface area measurement, X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results demonstrated that TiO2 nanotubes sustained the 3D interconnected structure of pristine BC and exhibited an average diameter of 36 nm and a mesoporous wall with a mean mesopore size of 3.2 nm. The particular structure endows TiO2 nanotubes with ultra-large surface area (1629 m2 g−1) and high photocatalytic activity

  20. Optimized preparation for large surface area activated carbon from date (Phoenix dactylifera L.) stone biomass

    International Nuclear Information System (INIS)

    The preparation of activated carbon from date stone treated with phosphoric acid was optimized using rotatable central composite design of response surface methodology (RSM). The chemical activating agent concentration and temperature of activation plays a crucial role in preparation of large surface area activated carbons. The optimized activated carbon was characterized using thermogravimetric analysis, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, powder X-ray diffraction, and Fourier transform infrared spectroscopy. The results showed that the larger surface area of activated carbon from date stone can be achieved under optimum activating agent (phosphoric acid) concentration, 50.0% (8.674 mol L−1) and activation temperature, 900 °C. The Brunauer–Emmett–Teller (BET) surface area of optimized activated carbon was found to be 1225 m2 g−1, and thermogravimetric analysis revealed that 55.2% mass of optimized activated carbon was found thermally stable till 900 °C. The leading chemical functional groups found in the date stone activated carbon were aliphatic carboxylic acid salt ν(C=O) 1561.22 cm−1 and 1384.52 cm−1, aliphatic hydrocarbons ν(C–H) 2922.99 cm−1 (C–H sym./asym. stretch frequency), aliphatic phosphates ν(P–O–C) 1054.09 cm−1, and secondary aliphatic alcohols ν(O–H) 3419.81 cm−1 and 1159.83 cm−1. - Highlights: • RSM optimization was done for the production of large surface area activated carbon. • Two independent variables with two responses were selected for optimization. • Characterization was done for surface area, morphology and chemical constituents. • Optimized date stone activated carbon achieved surface area 1225 m2 g−1

  1. Soil Specific Surface Area and Non-Singularity of Soil-Water Retention at Low Saturations

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Møldrup, Per;

    2013-01-01

    The dry end of the soil water characteristic (SWC) is important for modeling vapor flow dynamics and predicting soil properties such as specific surface area (SSA) and clay content (CL). Verification of new instrumentation for rapid measurement of the dry end of the SWC is relevant to avoid long...... Or (TO) and new single-parameter non-singularity (SPN) models; and evaluate estimates of SSA from water sorption, ethylene glycol monoethyl ether (EGME), and N2–BET methods. The AquaSorp successfully measured water sorption isotherms (∼140 data points) within a reasonably short time (1–3 d). The SPN...... model well described the distinct non-singularity between the adsorption and desorption branches, while the TO model captured the adsorption data reasonably well (<5% deviation from measurements), except for matric potentials below –200 MPa. The SSA derived from water sorption and the TO model were...

  2. Constant Bet Size? Don't Bet on It! Testing Expected Utility Theory on Betfair Data

    OpenAIRE

    Frantisek Kopriva

    2015-01-01

    I analyze the risk preferences of bettors using data from the world's largest betting exchange, Betfair. The assumption of a constant bet size, commonly used in the current literature, leads to an unrealistic model of bettors' decision making as a choice between a high return - low variance and low return - high variance bet, automatically implying risk-loving preferences of bettors. However, the data show that bettors bet different amounts on different odds. Thus, simply by introducing the c...

  3. Effect of Preparation Method on Surface Area and Crystalline Form of CeO2-ZrO2 Solid Solution

    Institute of Scientific and Technical Information of China (English)

    王晓红; 郭耘; 卢冠忠; 郭杨龙; 王筠松; 张志刚; 刘晓晖

    2004-01-01

    The CeO2-ZrO2 solid solutions were prepared by a reverse microemulsion method. The effect of preparation parameters on the surface area and crystalline form of the solid solutions were studied by the BET surface area and XRD analysis. The studies indicate that the separation of the microemulsion phase during the preparation procedure can decrease the specific surface area of sample, adding hydrogen peroxide in the matrix solution can increase the specific surface area and stability of sample. The surface area of sample calcined at 550 ℃ for 5 h is 149 m2·g-1, and that calcined at 900 ℃ for 6 h is 88 m2·g-1.The sample with tetragonal symmetry Ce0.5Zr0.5O2 phase has a higher stability.

  4. Biggest bets in the universe unveiled

    CERN Multimedia

    Jamieson, Valerie

    2004-01-01

    Betting on the greatest unsolved problems in the universe is no longer the preserve of academic superstars such as Stephen Hawking. From Thursday, anyone will be able to place bets on whether the biggest physics experiments in the world will come good before 2010

  5. Bookmaker and pari-mutuel betting

    DEFF Research Database (Denmark)

    Koch, Alexander; Shing, Hui-Fai

    2008-01-01

    A widely documented empirical regularity in gambling markets is that bets on high probability events (a race won by a "favourite") have higher expected returns than bets on low probability events (a "longshot" wins). Such favourite-longshot (FL) biases however appear to be more severe and persist...

  6. Dependence of the specific surface area of the nuclear fuel with the matrix oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Gomez, F.; Quinones, J.; Iglesias, E.; Rodriguez, N. [CIEMAT. Avda. Complutense 22, 28040-Madrid (Spain)

    2008-07-01

    This paper is focused on the study of the changes in the specific surface area measured using BET techniques. The objective is to obtain a relation between this parameter and the change in the matrix stoichiometry (i.e., oxidation increase). None of the actual models used for extrapolating the behaviour of the spent fuel matrix under repository conditions have included this dependence yet. In this work the specific surface area of different uranium oxide were measured using N{sub 2}(g) and Kr(g). The starting material was UO{sub 2+x}(s) with a size powder distribution lower than 20 {mu}m. The results included in this paper shown a strong dependence on specific surface area with the matrix stoichiometry, i.e., and increase of more than one order of magnitude (SUO{sub 2} = 6 m{sup 2}*g{sup -1} and SU{sub 3}O{sub 8} = 16.07 m{sup 2}*g{sup -1}). Furthermore, the particle size distribution measured as a function of the thermal treatment done shows changes on the powder size related to the changes observed in the uranium oxide stoichiometry. (authors)

  7. Dependence of the specific surface area of the nuclear fuel with the matrix oxidation

    International Nuclear Information System (INIS)

    This paper is focused on the study of the changes in the specific surface area measured using BET techniques. The objective is to obtain a relation between this parameter and the change in the matrix stoichiometry (i.e., oxidation increase). None of the actual models used for extrapolating the behaviour of the spent fuel matrix under repository conditions have included this dependence yet. In this work the specific surface area of different uranium oxide were measured using N2(g) and Kr(g). The starting material was UO2+x(s) with a size powder distribution lower than 20 μm. The results included in this paper shown a strong dependence on specific surface area with the matrix stoichiometry, i.e., and increase of more than one order of magnitude (SUO2 = 6 m2*g-1 and SU3O8 = 16.07 m2*g-1). Furthermore, the particle size distribution measured as a function of the thermal treatment done shows changes on the powder size related to the changes observed in the uranium oxide stoichiometry. (authors)

  8. The role of advanced reactive surface area characterization in improving predictions of mineral reaction rates

    Science.gov (United States)

    Beckingham, L. E.; Zhang, S.; Mitnick, E.; Cole, D. R.; Yang, L.; Anovitz, L. M.; Sheets, J.; Swift, A.; Kneafsey, T. J.; Landrot, G.; Mito, S.; Xue, Z.; Steefel, C. I.; DePaolo, D. J.; Ajo Franklin, J. B.

    2014-12-01

    Geologic sequestration of CO2 in deep sedimentary formations is a promising means of mitigating carbon emissions from coal-fired power plants but the long-term fate of injected CO2 is challenging to predict. Reactive transport models are used to gain insight over long times but rely on laboratory determined mineral reaction rates that have been difficult to extrapolate to field systems. This, in part, is due to a lack of understanding of mineral reactive surface area. Many models use an arbitrary approximation of reactive surface area, applying orders of magnitude scaling factors to measured BET or geometric surface areas. Recently, a few more sophisticated approaches have used 2D and 3D image analyses to determine mineral-specific reactive surface areas that account for the accessibility of minerals. However, the ability of these advanced surface area estimates to improve predictions of mineral reaction rates has yet to be determined. In this study, we fuse X-ray microCT, SEM QEMSCAN, XRD, SANS, and SEM-FIB analysis to determine mineral-specific accessible reactive surface areas for a core sample from the Nagaoka pilot CO2 injection site (Japan). This sample is primarily quartz, plagioclase, smectite, K-feldspar, and pyroxene. SEM imaging shows abundant smectite cement and grain coatings that decrease the fluid accessibility of other minerals. However, analysis of FIB-SEM images reveals that smectite nano-pores are well connected such that access to underlying minerals is not occluded by smectite coatings. Mineral-specific accessible surfaces are determined, accounting for the connectivity of the pore space with and without connected smectite nano-pores. The large-scale impact of variations in accessibility and dissolution rates are then determined through continuum scale modeling using grid-cell specific information on accessible surface areas. This approach will be compared with a traditional continuum scale model using mineral abundances and common surface area

  9. Pore scale heterogeneity in the mineral distribution and surface area of porous rocks

    Science.gov (United States)

    Lai, Peter; Moulton, Kevin; Krevor, Samuel

    2014-05-01

    There are long-standing challenges in characterizing reactive transport in porous media at scales larger than individual pores. This hampers the prediction of the field-scale impact of geochemical processes on fluid flow [1]. This is a source of uncertainty for carbon dioxide injection, which results in a reactive fluid-rock system, particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2,3]. The objective of this study was to quantify heterogeneity in reactive surface and observe the extent of its non-normal character. In this study we describe our work in using micron-scale x-ray imaging and other spectroscopic techniques for the purpose of describing the statistical distribution of reactive surface area within a porous medium, and identifying specific mineral phases and their distribution in 3-dimensions. Using in-house image processing techniques and auxilary charactersation with thin section, electron microscope and spectroscopic techniques we quantified the surface area of each mineral phase in the x-ray CT images. This quantification was validated against nitrogen BET surface area and backscattered electron imaging measurements of the CT-imaged samples. Distributions in reactive surface area for each mineral phase were constructed by calculating surface areas in thousands of randomly selected subvolume images of the total sample, each normalized to the pore volume in that image. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be

  10. Estimation of surface area and surface area measure of three-dimensional sets from digitizations

    DEFF Research Database (Denmark)

    Ziegel, Johanna; Kiderlen, Markus

    2010-01-01

    . The method is based on an exact asymptotic result that holds for increasing resolution of the digitization. It states that the number of occurrences of a 2 ×  2 × 2 configuration is asymptotically proportional to an integral of its “h-function” with respect to the surface area measure of the object....... We find explicit representations for these h-functions. Analyzing them in detail, we determine weights that lead to an asymptotic worst case error for surface area estimation of less than 4%. We show that this worst case error is the best possible. Exploiting the local nature of the asymptotic result...

  11. Accessible surface area from NMR chemical shifts

    Energy Technology Data Exchange (ETDEWEB)

    Hafsa, Noor E.; Arndt, David; Wishart, David S., E-mail: david.wishart@ualberta.ca [University of Alberta, Department of Computing Science (Canada)

    2015-07-15

    Accessible surface area (ASA) is the surface area of an atom, amino acid or biomolecule that is exposed to solvent. The calculation of a molecule’s ASA requires three-dimensional coordinate data and the use of a “rolling ball” algorithm to both define and calculate the ASA. For polymers such as proteins, the ASA for individual amino acids is closely related to the hydrophobicity of the amino acid as well as its local secondary and tertiary structure. For proteins, ASA is a structural descriptor that can often be as informative as secondary structure. Consequently there has been considerable effort over the past two decades to try to predict ASA from protein sequence data and to use ASA information (derived from chemical modification studies) as a structure constraint. Recently it has become evident that protein chemical shifts are also sensitive to ASA. Given the potential utility of ASA estimates as structural constraints for NMR we decided to explore this relationship further. Using machine learning techniques (specifically a boosted tree regression model) we developed an algorithm called “ShiftASA” that combines chemical-shift and sequence derived features to accurately estimate per-residue fractional ASA values of water-soluble proteins. This method showed a correlation coefficient between predicted and experimental values of 0.79 when evaluated on a set of 65 independent test proteins, which was an 8.2 % improvement over the next best performing (sequence-only) method. On a separate test set of 92 proteins, ShiftASA reported a mean correlation coefficient of 0.82, which was 12.3 % better than the next best performing method. ShiftASA is available as a web server ( http://shiftasa.wishartlab.com http://shiftasa.wishartlab.com ) for submitting input queries for fractional ASA calculation.

  12. Accessible surface area from NMR chemical shifts

    International Nuclear Information System (INIS)

    Accessible surface area (ASA) is the surface area of an atom, amino acid or biomolecule that is exposed to solvent. The calculation of a molecule’s ASA requires three-dimensional coordinate data and the use of a “rolling ball” algorithm to both define and calculate the ASA. For polymers such as proteins, the ASA for individual amino acids is closely related to the hydrophobicity of the amino acid as well as its local secondary and tertiary structure. For proteins, ASA is a structural descriptor that can often be as informative as secondary structure. Consequently there has been considerable effort over the past two decades to try to predict ASA from protein sequence data and to use ASA information (derived from chemical modification studies) as a structure constraint. Recently it has become evident that protein chemical shifts are also sensitive to ASA. Given the potential utility of ASA estimates as structural constraints for NMR we decided to explore this relationship further. Using machine learning techniques (specifically a boosted tree regression model) we developed an algorithm called “ShiftASA” that combines chemical-shift and sequence derived features to accurately estimate per-residue fractional ASA values of water-soluble proteins. This method showed a correlation coefficient between predicted and experimental values of 0.79 when evaluated on a set of 65 independent test proteins, which was an 8.2 % improvement over the next best performing (sequence-only) method. On a separate test set of 92 proteins, ShiftASA reported a mean correlation coefficient of 0.82, which was 12.3 % better than the next best performing method. ShiftASA is available as a web server ( http://shiftasa.wishartlab.com http://shiftasa.wishartlab.com ) for submitting input queries for fractional ASA calculation

  13. Pore scale heterogeneity in the mineral distribution and reactive surface area of rocks

    Science.gov (United States)

    Lai, P. E.; Krevor, S. C.

    2013-12-01

    There are long-standing challenges in characterizing reactive transport in porous media at scales larger than individual pores. This hampers the prediction of the field-scale impact of geochemical processes on fluid flow [1]. This is a source of uncertainty for CO2 injection, which results in a reactive fluid-rock system, particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2,3]. In this study we have created μm resolution 3D images of 3 sandstone and 4 carbonate rocks using x-ray microtomography. Using in-house image processing techniques and auxiliary characterisation with thin section, electron microscope and spectroscopic techniques we quantified the surface area of each mineral phase in the x-ray CT images. This quantification was validated against N2 BET surface area and He porosity measurements of the imaged samples. Distributions in reactive surface area for each mineral phase were constructed by calculating surface areas in thousands of randomly selected subvolume images of the total sample, each normalized to the pore volume in that image. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be characterized at multiple length scales for an accurate description of reactive transport. [1] Maher, Steefel, Depaolo and Vianni (2006) Geochimica et Cosmochimica Acta, 70, 337-363 [2] Landrot, Ajo-Franklin, Yang, Cabrini and Steefel (2012) Chemical Geology 318-319, 113-125 [3] Li, Peters and Celia (2007) American Journal of Science 307, 1146

  14. Quantification of surface amorphous content using dispersive surface energy: the concept of effective amorphous surface area.

    Science.gov (United States)

    Brum, Jeffrey; Burnett, Daniel

    2011-09-01

    We investigate the use of dispersive surface energy in quantifying surface amorphous content, and the concept of effective amorphous surface area is introduced. An equation is introduced employing the linear combination of surface area normalized square root dispersive surface energy terms. This equation is effective in generating calibration curves when crystalline and amorphous references are used. Inverse gas chromatography is used to generate dispersive surface energy values. Two systems are investigated, and in both cases surface energy data collected for physical mixture samples comprised of amorphous and crystalline references fits the predicted response with good accuracy. Surface amorphous content of processed lactose samples is quantified using the calibration curve, and interpreted within the context of effective amorphous surface area. Data for bulk amorphous content is also utilized to generate a thorough picture of how disorder is distributed throughout the particle. An approach to quantifying surface amorphous content using dispersive surface energy is presented. Quantification is achieved by equating results to an effective amorphous surface area based on reference crystalline, and amorphous materials. PMID:21725707

  15. Metal-Free Counter Electrode for Efficient Dye-Sensitized Solar Cells through High Surface Area and Large Porous Carbon

    Directory of Open Access Journals (Sweden)

    Pavuluri Srinivasu

    2011-01-01

    Full Text Available Highly efficient, large mesoporous carbon is fabricated as a metal-free counter electrode for dye-sensitized solar cells. The mesoporous carbon shows very high energy conversion efficiency of 7.1% compared with activated carbon. The mesoporous carbon is prepared and characterized by nitrogen adsorption, scanning electron microscopy (SEM, and transmission electron microscopy (TEM. The nitrogen adsorption data reveals that the material possesses BET specific surface area ca.1300 m2/g and pore diameter 4.4 nm. Hexagonal rod-like morphology and ordered pore structure of mesoporous carbon are confirmed by electron microscopy data. The better performance of this carbon material is greatly benefited from its ordered interconnected mesoporous structure and high surface area.

  16. Surface area of montmorillonite from the dynamic sorption of nitrogen and carbon dioxide

    Science.gov (United States)

    Thomas, J., Jr.; Bohor, B.F.

    1968-01-01

    Surface area determinations were made on a montmorillonite with various cations emplaced on the exchangeable sites, utilizing nitrogen and carbon dioxide as adsorbates at 77 ??K and 195 ??K, respectively, in a dynamic system. From the fraction of a Mississippi montmorillonite less than about 1 ?? in size, samples were prepared by replacing the original exchangeable cations with Li+, Na+, K+, Rb+, Cs+, Mg++, Ca++, Ba++, and NH4+, forming a series of homoionic montmorillonite species. Surface areas from 3-point B.E.T. plots (half-hour adsorption points), with nitrogen as the adsorbate, ranged from 61 m2/g for Li-montmorillonite to 138 m2/g for Cs-montmorillonite, thus reflecting a certain degree of nitrogen penetration between layers. Complete penetration should theoretically result in a surface area of over 300 m2/g for this clay with a nitrogen monolayer between each pair of platelets. The experimental data indicate that the extent of penetration is time-dependent and is also a function of the interlayer forces as governed by the size and charge of the replaceable cation. This finding negates the generally accepted concept that nitrogen at 77 ??K does not penetrate the layers and provides a measure only of the external surface of expandable clay minerals. A further measure of the variation of interlayer forces is provided by the adsorption of carbon dioxide at 195 ??K. Surface area values ranged from 99 m2/g for Li-montmorillonite to 315 m2/g for Csmontmorillonite. Although the carbon dioxide molecule is larger than the nitrogen molecule, its greater penetration apparently is a result of its being kinetically more energetic (with a larger diffusion coefficient) at its higher adsorption temperature. Similar differences have been found with both adsorbates in the study of microporous substances, such as coal, where activated diffusion is of considerable significance. ?? 1968.

  17. Casimir effect in dielectrics Surface area contribution

    CERN Document Server

    Molina-Paris, C; Molina-Paris, Carmen; Visser, Matt

    1997-01-01

    In this paper we take a deeper look at the technically elementary but physically robust viewpoint in which the Casimir energy in dielectric media is interpreted as the change in the total zero point energy of the electromagnetic vacuum summed over all states. Extending results presented in previous papers [hep-th/9609195; hep-th/9702007] we approximate the sum over states by an integral over the density of states including finite volume corrections. For an arbitrarily-shaped finite dielectric, the first finite-volume correction to the density of states is shown to be proportional to the surface area of the dielectric interface and is explicitly evaluated as a function of the permeability and permitivity. Since these calculations are founded in an elementary and straightforward way on the underlying physics of the Casimir effect they serve as an important consistency check on field-theoretic calculations. As a concrete example we discuss Schwinger's suggestion that the Casimir effect might be the underlying ph...

  18. The increase of surface area of a Brazilian palygorskite clay activated with sulfuric acid solutions using a factorial design

    Directory of Open Access Journals (Sweden)

    R. N. Oliveira

    2013-01-01

    Full Text Available Palygorskite is fibrous clay in which the structural tetrahedral and octahedral layers are organized in a way that structural channels are formed, leading to high surface area. However, impurities inside the channels and aggregated ones considerably reduce the available area. In order to increase the surface area, an activation treatment can be considered useful. The goal of this work is the activation of palygorskite from Guadalupe, Piauí, via sulfuric acid treatment using a two-level factorial design. The influence of three parameters (solution molarity, temperature and time on BET surface area was determined. Moreover, samples were characterized via X-ray diffraction (XRD and fluorescence (XRF, Fourier-transform infrared spectroscopy (FTIR and transmission electron microscopy (TEM. The largest surface area (282 m²/g without considerable changes in clay structure and morphology was found in a sample treated with 5M H2SO4 at 70°C for 1h. The main parameters that favored the improvement of the surface area were the solution's molarity, temperature and their interaction.

  19. Pore Scale Heterogeneity in the Mineral Distribution, Surface Area and Adsorption in Porous Rocks

    Science.gov (United States)

    Lai, P. E. P.; Krevor, S. C.

    2014-12-01

    The impact of heterogeneity in chemical transport and reaction is not understood in continuum (Darcy/Fickian) models of reactive transport. This is manifested in well-known problems such as scale dependent dispersion and discrepancies in reaction rate observations made at laboratory and field scales [1]. Additionally, this is a source of uncertainty for carbon dioxide injection, which produces a reactive fluid-rock system particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2, 3]. We use x-ray micro tomography to describe the non-normal 3-dimensional distribution of reactive surface area within a porous medium according to distinct mineral groups. Using in-house image processing techniques, thin sections, nitrogen BET surface area, backscattered electron imaging and energy dispersive spectroscopy, we compare the surface area of each mineral phase to those obtained from x-ray CT imagery. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be characterized at multiple length scales for an accurate description of reactive transport. We combine the mineral specific surface area characterisation to dynamic tomography, imaging the flow of water and solutes, to observe flow dependent and mineral specific adsorption. The observations may contribute to the incorporation of experimentally based statistical descriptions of pore scale heterogeneity in reactive transport into upscaled models, moving it closer to predictive capabilities for field scale

  20. Targeting BET bromodomains for cancer treatment.

    Science.gov (United States)

    Jung, Marie; Gelato, Kathy A; Fernández-Montalván, Amaury; Siegel, Stephan; Haendler, Bernard

    2015-01-01

    The bromodomain and extraterminal (BET) subfamily of bromodomain-containing proteins has emerged in the last few years as an exciting, novel target group. BRD4, the best studied BET protein, is implicated in a number of hematological and solid tumors. This is linked to its role in modulating transcription elongation of essential genes involved in cell cycle and apoptosis such as c-Myc and BCL2. Potent BET inhibitors with promising antitumor efficacy in a number of preclinical cancer models have been identified in recent years. This led to clinical studies focusing mostly on the treatment of leukemia and lymphoma, and first encouraging signs of efficacy have already been reported. Here we discuss the biology of BRD4, its known interaction partners and implication in different tumor types. Further, we summarize the current knowledge on BET bromodomain inhibitors. PMID:26077433

  1. Effects of expertise on football betting

    OpenAIRE

    Khazaal Yasser; Chatton Anne; Billieux Joël; Bizzini Lucio; Monney Grégoire; Fresard Emmanuelle; Thorens Gabriel; Bondolfi Guido; El-Guebaly Nady; Zullino Daniele; Khan Riaz

    2012-01-01

    Abstract Background Football (soccer) is one of the most popular sports in the world, including Europe. It is associated with important betting activities. A common belief, widely spread among those who participate in gambling activities, is that knowledge and expertise on football lead to better prediction skills for match outcomes. If unfounded, however, this belief should be considered as a form of “illusion of control.” The aim of this study was to examine whether football experts are bet...

  2. Information processing in children's choices among bets

    OpenAIRE

    Hommers, Wilfried

    2010-01-01

    Children's information processing of risky choice alternatives was investigated in two studies without using verbal reports. In Study 1, the ability to integrate the probabilities and the payoffs of simple bets was examined using the rating scale methodology. Children's choices among three of those simple bets were recorded also. By cross-classifying the children's choice and rating behavior it was shown that a three-stage developmental hypothesis of decision making is not sufficient. A four-...

  3. Predicting skin deficits through surface area measurements in ear reconstruction and adult ear surface area norms.

    Science.gov (United States)

    Yazar, Memet; Sevim, Kamuran Zeynep; Irmak, Fatih; Yazar, Sevgi Kurt; Yeşilada, Ayşin Karasoy; Karşidağğ, Semra Hacikerim; Tatlidede, Hamit Soner

    2013-07-01

    Ear reconstruction is one of the most challenging procedures in plastic surgery practice. Many studies and techniques have been described in the literature for carving a well-pronounced framework. However, just as important as the cartilage framework is the ample amount of delicate skin coverage of the framework. In this report, we introduce an innovative method of measuring the skin surface area of the auricle from a three-dimensional template created from the healthy ear.The study group consisted of 60 adult Turkish individuals who were randomly selected (30 men and 30 women). The participant ages ranged from 18 to 45 years (mean, 31.5 years), and they had no history of trauma or congenital anomalies. The template is created by dividing the ear into aesthetic subunits and using ImageJ software to estimate the necessary amount of total skin surface area required.Reconstruction of the auricle is a complicated process that requires experience and patience to provide the auricular details. We believe this estimate will shorten the learning curve for residents and surgeons interested in ear reconstruction and will help surgeons obtain adequate skin to drape over the well-sculpted cartilage frameworks by providing a reference list of total ear skin surface area measurements for Turkish men and women. PMID:23851770

  4. Reduction Expansion Synthesis as Strategy to Control Nitrogen Doping Level and Surface Area in Graphene

    Directory of Open Access Journals (Sweden)

    Russell Canty

    2015-10-01

    Full Text Available Graphene sheets doped with nitrogen were produced by the reduction-expansion (RES method utilizing graphite oxide (GO and urea as precursor materials. The simultaneous graphene generation and nitrogen insertion reactions are based on the fact that urea decomposes upon heating to release reducing gases. The volatile byproducts perform two primary functions: (i promoting the reduction of the GO and (ii providing the nitrogen to be inserted in situ as the graphene structure is created. Samples with diverse urea/GO mass ratios were treated at 800 °C in inert atmosphere to generate graphene with diverse microstructural characteristics and levels of nitrogen doping. Scanning electron microscopy (SEM and transmission electron microscopy (TEM were used to study the microstructural features of the products. The effects of doping on the samples structure and surface area were studied by X-ray diffraction (XRD, Raman Spectroscopy, and Brunauer Emmet Teller (BET. The GO and urea decomposition-reduction process as well as nitrogen-doped graphene stability were studied by thermogravimetric analysis (TGA coupled with mass spectroscopy (MS analysis of the evolved gases. Results show that the proposed method offers a high level of control over the amount of nitrogen inserted in the graphene and may be used alternatively to control its surface area. To demonstrate the practical relevance of these findings, as-produced samples were used as electrodes in supercapacitor and battery devices and compared with conventional, thermally exfoliated graphene.

  5. Palatal Surface Area of Maxillary Plaster Casts

    DEFF Research Database (Denmark)

    Darvann, Tron Andre; Hermann, Nuno V.; Ersbøll, Bjarne Kjær;

    2007-01-01

    Objective: To investigate the relationship between corresponding two-dimensional and three-dimensional measurements on maxillary plaster casts taken from photographs and three-dimensional surface scans, respectively. Materials and Methods: Corresponding two-dimensional and three-dimensional measu......Objective: To investigate the relationship between corresponding two-dimensional and three-dimensional measurements on maxillary plaster casts taken from photographs and three-dimensional surface scans, respectively. Materials and Methods: Corresponding two-dimensional and three...

  6. Impacts of water surface area of watershed on design flood

    Institute of Scientific and Technical Information of China (English)

    Qing-hua ZHANG; Yan-fang DIAO; Jie DONG

    2014-01-01

    In order to analyze the impact of the water surface area of a watershed on the design flood, the watershed was classified into a land watershed and a water surface watershed for flood flow calculation at the same time interval. Then, the design flood of the whole watershed was obtained by adding the two flood flows together. Using this method, we calculated design floods with different water surface areas of three reservoirs and analyzed the impact of water surface area on the flood volume and peak flow. The results indicate that larger water surface areas lead to greater impacts on the flood volume and peak flow. For the same watershed area, the impact of water surface area on the flood volume and peak flow is positively proportional to the flood frequency, i.e., the higher the frequency, the greater the impact becomes.

  7. SURFACE WATER QUALITY MANAGEMENT IN PRAHOVA AREA

    Directory of Open Access Journals (Sweden)

    CASEN PANAITESCU

    2014-05-01

    Full Text Available To achieve an appropriate management strategy was monitored surface water quality in the county of Prahova. In this regard were determinate major physical and chemical indicators: pH, BOD5, COD, nitrates, nitrites, and suspended solids. Depending on the value of the data obtained was identified water quality classes corresponding to each surface water body studied. The correlation values obtained with the best solutions for water service and maintenance of water courses is a management plan for surface water in the county of Prahova. The novelty of the paper consists of study of water resources in the county and not in the Basin as is done at present by the Romanian Waters National Administration

  8. Asphalt-derived high surface area activated porous carbons for carbon dioxide capture.

    Science.gov (United States)

    Jalilov, Almaz S; Ruan, Gedeng; Hwang, Chih-Chau; Schipper, Desmond E; Tour, Josiah J; Li, Yilun; Fei, Huilong; Samuel, Errol L G; Tour, James M

    2015-01-21

    Research activity toward the development of new sorbents for carbon dioxide (CO2) capture have been increasing quickly. Despite the variety of existing materials with high surface areas and high CO2 uptake performances, the cost of the materials remains a dominant factor in slowing their industrial applications. Here we report preparation and CO2 uptake performance of microporous carbon materials synthesized from asphalt, a very inexpensive carbon source. Carbonization of asphalt with potassium hydroxide (KOH) at high temperatures (>600 °C) yields porous carbon materials (A-PC) with high surface areas of up to 2780 m(2) g(-1) and high CO2 uptake performance of 21 mmol g(-1) or 93 wt % at 30 bar and 25 °C. Furthermore, nitrogen doping and reduction with hydrogen yields active N-doped materials (A-NPC and A-rNPC) containing up to 9.3% nitrogen, making them nucleophilic porous carbons with further increase in the Brunauer-Emmett-Teller (BET) surface areas up to 2860 m(2) g(-1) for A-NPC and CO2 uptake to 26 mmol g(-1) or 114 wt % at 30 bar and 25 °C for A-rNPC. This is the highest reported CO2 uptake among the family of the activated porous carbonaceous materials. Thus, the porous carbon materials from asphalt have excellent properties for reversibly capturing CO2 at the well-head during the extraction of natural gas, a naturally occurring high pressure source of CO2. Through a pressure swing sorption process, when the asphalt-derived material is returned to 1 bar, the CO2 is released, thereby rendering a reversible capture medium that is highly efficient yet very inexpensive. PMID:25531980

  9. Calculation of cell volumes and surface areas in MCNP

    International Nuclear Information System (INIS)

    MCNP is a general Monte Carlo neutron-photon particle transport code which treats an arbitrary three-dimensional configuration of materials in geometric cells bounded by first- and second-degree surfaces, and some special fourth-degree surfaces. It is necessary to calculate cell volumes and surface areas so that cell masses, fluxes, and other important information can be determined. The volume/area calculation in MCNP computes cell volumes and surface areas for cells and surfaces rotationally symmetric about any arbitrary axis. 5 figures, 1 table

  10. Surface Area Distribution Descriptor for object matching

    Directory of Open Access Journals (Sweden)

    Mohamed F. Gafar

    2010-07-01

    Full Text Available Matching 3D objects by their similarity is a fundamental problem in computer vision, computer graphics and many other fields. The main challenge in object matching is to find a suitable shape representation that can be used to accurately and quickly discriminate between similar and dissimilar shapes. In this paper we present a new volumetric descriptor to represent 3D objects. The proposed descriptor is used to match objects under rigid transformations including uniform scaling. The descriptor represents the object by dividing it into shells, acquiring the area distribution of the object through those shells. The computed areas are normalised to make the descriptor scale-invariant in addition to rotation and translation invariant. The effectiveness and stability of the proposed descriptor to noise and variant sampling density as well as the effectiveness of the similarity measures are analysed and demonstrated through experimental results.

  11. On semiautomatic estimation of surface area

    DEFF Research Database (Denmark)

    Dvorak, J.; Jensen, Eva B. Vedel

    2013-01-01

    convex particles, the estimator is equal to four times the area of the support set (flower set) of the particle transect. We study the statistical properties of the flower estimator and compare its performance to that of two discretizations of the flower estimator, namely the pivotal estimator and the...... surfactor. For ellipsoidal particles, it is shown that the flower estimator is equal to the pivotal estimator based on support function measurements along four perpendicular rays. This result makes the pivotal estimator a powerful approximation to the flower estimator. In a simulation study of prolate and...

  12. Plasma-Engraved Co3 O4 Nanosheets with Oxygen Vacancies and High Surface Area for the Oxygen Evolution Reaction.

    Science.gov (United States)

    Xu, Lei; Jiang, Qianqian; Xiao, Zhaohui; Li, Xingyue; Huo, Jia; Wang, Shuangyin; Dai, Liming

    2016-04-18

    Co3 O4 , which is of mixed valences Co(2+) and Co(3+) , has been extensively investigated as an efficient electrocatalyst for the oxygen evolution reaction (OER). The proper control of Co(2+) /Co(3+) ratio in Co3 O4 could lead to modifications on its electronic and thus catalytic properties. Herein, we designed an efficient Co3 O4 -based OER electrocatalyst by a plasma-engraving strategy, which not only produced higher surface area, but also generated oxygen vacancies on Co3 O4 surface with more Co(2+) formed. The increased surface area ensures the Co3 O4 has more sites for OER, and generated oxygen vacancies on Co3 O4 surface improve the electronic conductivity and create more active defects for OER. Compared to pristine Co3 O4 , the engraved Co3 O4 exhibits a much higher current density and a lower onset potential. The specific activity of the plasma-engraved Co3 O4 nanosheets (0.055 mA cm(-2) BET at 1.6 V) is 10 times higher than that of pristine Co3 O4 , which is contributed by the surface oxygen vacancies. PMID:26990905

  13. Indexing aortic valve area by body surface area increases the prevalence of severe aortic stenosis

    DEFF Research Database (Denmark)

    Jander, Nikolaus; Gohlke-Bärwolf, Christa; Bahlmann, Edda;

    2014-01-01

    To account for differences in body size in patients with aortic stenosis, aortic valve area (AVA) is divided by body surface area (BSA) to calculate indexed AVA (AVAindex). Cut-off values for severe stenosis are...

  14. Study of the silica aerogel densifications by SAXS and BET

    International Nuclear Information System (INIS)

    Silica gels were made by hydrolysis and polycondensation of solutions containing tetramethoxysilane (TMOS), methanol and water in a neutral medium. After hypercritical drying, the aerogels were densified at high temperatures (10800C). The obtained porous materials have apparent densities between 0,71 and 2,20 g/cm3 and specific surfaces, measured by BET, below 295 m2/g. The structural evolution of the porous material was studied by small-angle X-ray scattering (SAXS). There are two competitive mechanisms that contribute to Densification: the elimination and coalescence of mesopores, and the progressive densification of the nearly homogeneous vitreous matrix. (author)

  15. Area minimizing surfaces in mean convex 3-manifolds

    OpenAIRE

    Coşkunüzer, Barış; Bourni, Theodora

    2015-01-01

    J. reine angew. Math. 704 (2015), 135–167 Journal für die reine und angewandte Mathematik DOI 10.1515/ crelle-2013-0050 © De Gruyter 2015 Area minimizing surfaces in mean convex 3-manifolds By Theodora Bourni at Berlin and Baris Coskunuzer at Istanbul Abstract. In this paper, we give several results on area minimizing surfaces in strictly mean convex 3-manifolds. First, we study the genus of absolutely area minimizing surfaces in a compact, orientable, strictly mean conve...

  16. Salt-assisted Low Temperature Solid State Synthesis of High Surface Area CoFe2O4 Nanoparticles

    Institute of Scientific and Technical Information of China (English)

    Runhua Qin; Fengsheng Li; Wei Jiang; Li Liu

    2009-01-01

    A novel salt-assisted low temperature solid state method using CoCl2·6H2O, FeCl3·6H2O and NaOH as pre-cursor and using NaCl as a dispersant to synthesize high surface area CoFe2O4 nanoparticles, has been investigated. The effects of the molar ratio of added salt and calcination temperature on the characteristics of the products were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM) and Brunauer, Emmett and Teller (BET) surface area analysis. Results showed that the introduction of leachable inert inorganic salt as a hard agglomeration inhibitor in the mixture precursorled to the formation of high dispersive CoFe2O4 nanoparticles; and the increase in specific surface area from 28.28 to 73.97 m2/g, and the saturation magnetization is 84.6 emu/g.

  17. Low-temperature preparation of nanocrystalline TiO{sub 2} photocatalyst with a very large specific surface area

    Energy Technology Data Exchange (ETDEWEB)

    Liu, A.R. [Department of Chemistry, Xuchang University, Xuchang 461000 (China)]. E-mail: ar_liu1948@yahoo.com.cn; Wang, S.M. [Department of Chemistry, Xuchang University, Xuchang 461000 (China); Zhao, Y.R. [Department of Chemistry, Xuchang University, Xuchang 461000 (China); Zheng, Z. [Institute of Advanced Materials, Xuchang University, Xuchang, 461000 (China)

    2006-09-10

    A facile method for obtaining highly photoactive bi-phase TiO{sub 2} photocatalyst with a small crystalline size and very large specific surface area was developed. This was simply done by hydrolysis of titanium tetraisopropoxide (TTIP) in pure water at 70 deg. C and followed by drying at 100 deg. C. The prepared TiO{sub 2} powder samples were characterized with X-ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and BET surface areas. The photocatalytic activity was evaluated by the photocatalytic oxidation of acetone in air. The results showed that the photocatalytic activity of the prepared TiO{sub 2} powder slightly exceeded that of Degussa P25. This might be attributed to the fact that the prepared TiO{sub 2} powder had a very large specific surface area (750 m{sup 2} g{sup -1}) and small crystallite size (about 5 nm), but relative low crystallinity, comparing with Degussa P25 photocatalyst.

  18. Naphthyridines as novel BET family bromodomain inhibitors.

    Science.gov (United States)

    Mirguet, Olivier; Lamotte, Yann; Chung, Chun-Wa; Bamborough, Paul; Delannée, Delphine; Bouillot, Anne; Gellibert, Françoise; Krysa, Gael; Lewis, Antonia; Witherington, Jason; Huet, Pascal; Dudit, Yann; Trottet, Lionel; Nicodeme, Edwige

    2014-03-01

    Bromodomains (BRDs) are small protein domains found in a variety of proteins that recognize and bind to acetylated histone tails. This binding affects chromatin structure and facilitates the localisation of transcriptional complexes to specific genes, thereby regulating epigenetically controlled processes including gene transcription and mRNA elongation. Inhibitors of the bromodomain and extra-terminal (BET) proteins BRD2-4 and T, which prevent bromodomain binding to acetyl-modified histone tails, have shown therapeutic promise in several diseases. We report here the discovery of 1,5-naphthyridine derivatives as potent inhibitors of the BET bromodomain family with good cell activity and oral pharmacokinetic parameters. X-ray crystal structures of naphthyridine isomers have been solved and quantum mechanical calculations have been used to explain the higher affinity of the 1,5-isomer over the others. The best compounds were progressed in a mouse model of inflammation and exhibited dose-dependent anti-inflammatory pharmacology. PMID:24000170

  19. Effects of expertise on football betting

    Directory of Open Access Journals (Sweden)

    Khazaal Yasser

    2012-05-01

    Full Text Available Abstract Background Football (soccer is one of the most popular sports in the world, including Europe. It is associated with important betting activities. A common belief, widely spread among those who participate in gambling activities, is that knowledge and expertise on football lead to better prediction skills for match outcomes. If unfounded, however, this belief should be considered as a form of “illusion of control.” The aim of this study was to examine whether football experts are better than nonexperts at predicting football match scores. Methods Two hundred and fifty-eight persons took part in the study: 21.3% as football experts, 54.3% as laypersons (non-initiated to football, and 24.4% as football amateurs. They predicted the scores of the first 10 matches of the 2008 UEFA European Football Championship. Logistic regressions were carried out to assess the link between the accuracy of the forecasted scores and the expertise of the participants (expert, amateur, layperson, controlling for age and gender. Results The variables assessed did not predict the accuracy of scoring prognosis (R2 ranged from 1% to 6%. Conclusions Expertise, age, and gender did not appear to have an impact on the accuracy of the football match prognoses. Therefore, the belief that football expertise improves betting skills is no more than a cognitive distortion called the “illusion of control.” Gamblers may benefit from psychological interventions that target the illusion of control related to their believed links between betting skills and football expertise. Public health policies may need to consider the phenomenon in order to prevent problem gambling related to football betting.

  20. Discovery, Design, and Optimization of Isoxazole Azepine BET Inhibitors.

    Science.gov (United States)

    Gehling, Victor S; Hewitt, Michael C; Vaswani, Rishi G; Leblanc, Yves; Côté, Alexandre; Nasveschuk, Christopher G; Taylor, Alexander M; Harmange, Jean-Christophe; Audia, James E; Pardo, Eneida; Joshi, Shivangi; Sandy, Peter; Mertz, Jennifer A; Sims, Robert J; Bergeron, Louise; Bryant, Barbara M; Bellon, Steve; Poy, Florence; Jayaram, Hariharan; Sankaranarayanan, Ravichandran; Yellapantula, Sreegouri; Bangalore Srinivasamurthy, Nandana; Birudukota, Swarnakumari; Albrecht, Brian K

    2013-09-12

    The identification of a novel series of small molecule BET inhibitors is described. Using crystallographic binding modes of an amino-isoxazole fragment and known BET inhibitors, a structure-based drug design effort lead to a novel isoxazole azepine scaffold. This scaffold showed good potency in biochemical and cellular assays and oral activity in an in vivo model of BET inhibition. PMID:24900758

  1. A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Xiu-Liang [Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, Beijing University of Technology, Beijing 100124 (China); Tong, Minman; Huang, Hongliang [College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029 (China); Wang, Bin; Gan, Lei [Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, Beijing University of Technology, Beijing 100124 (China); Yang, Qingyuan [College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029 (China); Zhong, Chongli [College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029 (China); State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029 (China); Li, Jian-Rong, E-mail: jrli@bjut.edu.cn [Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, Beijing University of Technology, Beijing 100124 (China); State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029 (China)

    2015-03-15

    Exploitation of new metal–organic framework (MOF) materials with high surface areas has been attracting great attention in related research communities due to their broad potential applications. In this work, a new Zr(IV)-based MOF, [Zr{sub 6}O{sub 4}(OH){sub 4}(eddb){sub 6}] (BUT-30, H{sub 2}eddb=4,4′-(ethyne-1,2-diyl)dibenzoic acid) has been solvothermally synthesized, characterized, and explored for gases and dyes adsorptions. Single-crystal X-ray diffraction analysis demonstrates a three-dimensional cubic framework structure of this MOF, in which each Zr{sub 6}O{sub 4}(OH){sub 4} building unit is linked by 12 linear eddb ligands. BUT-30 has been found stable up to 400 °C and has a Brunauer–Emmett–Teller (BET) surface area as high as 3940.6 m{sup 2} g{sup −1} (based on the N{sub 2} adsorption at 77 K) and total pore volume of 1.55 cm{sup 3} g{sup −1}. It is more interesting that this MOF exhibits stepwise adsorption behaviors for Ar, N{sub 2}, and CO{sub 2} at low temperatures, and selective uptakes towards different ionic dyes. - Graphical abstract: A new Zr(IV)-based MOF with high surface area has been synthesized and structurally characterized, which shows stepwise gas adsorption at low temperature and selective dye uptake from solution. - Highlights: • A new Zr-based MOF was synthesized and structurally characterized. • This MOF shows a higher surface area compared with its analogous UiO-67 and 68. • This MOF shows a rare stepwise adsorption towards light gases at low temperature. • This MOF performs selective uptakes towards cationic dyes over anionic ones. • Using triple-bond spacer is confirmed feasible in enhancing MOF surface areas.

  2. A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

    International Nuclear Information System (INIS)

    Exploitation of new metal–organic framework (MOF) materials with high surface areas has been attracting great attention in related research communities due to their broad potential applications. In this work, a new Zr(IV)-based MOF, [Zr6O4(OH)4(eddb)6] (BUT-30, H2eddb=4,4′-(ethyne-1,2-diyl)dibenzoic acid) has been solvothermally synthesized, characterized, and explored for gases and dyes adsorptions. Single-crystal X-ray diffraction analysis demonstrates a three-dimensional cubic framework structure of this MOF, in which each Zr6O4(OH)4 building unit is linked by 12 linear eddb ligands. BUT-30 has been found stable up to 400 °C and has a Brunauer–Emmett–Teller (BET) surface area as high as 3940.6 m2 g−1 (based on the N2 adsorption at 77 K) and total pore volume of 1.55 cm3 g−1. It is more interesting that this MOF exhibits stepwise adsorption behaviors for Ar, N2, and CO2 at low temperatures, and selective uptakes towards different ionic dyes. - Graphical abstract: A new Zr(IV)-based MOF with high surface area has been synthesized and structurally characterized, which shows stepwise gas adsorption at low temperature and selective dye uptake from solution. - Highlights: • A new Zr-based MOF was synthesized and structurally characterized. • This MOF shows a higher surface area compared with its analogous UiO-67 and 68. • This MOF shows a rare stepwise adsorption towards light gases at low temperature. • This MOF performs selective uptakes towards cationic dyes over anionic ones. • Using triple-bond spacer is confirmed feasible in enhancing MOF surface areas

  3. OXYANION SORPTION TO HIGH SURFACE AREA IRON AND ALUMINUM OXIDES

    Science.gov (United States)

    Sorption of selected oxyanions (Mo, As, and P) to high surface area iron and aluminum oxides was investigated using in situ Raman and ATR-FTIR spectroscopy, batch sorption methods, electrophoretic mobility measurements, and surface complexation modeling. In situ ATR-FTIR and Raman spectra were coup...

  4. Quantifying object and material surface areas in residences

    Energy Technology Data Exchange (ETDEWEB)

    Hodgson, Alfred T.; Ming, Katherine Y.; Singer, Brett C.

    2005-01-05

    The dynamic behavior of volatile organic compounds (VOCs) in indoor environments depends, in part, on sorptive interactions between VOCs in the gas phase and material surfaces. Since information on the types and quantities of interior material surfaces is not generally available, this pilot-scale study was conducted in occupied residences to develop and demonstrate a method for quantifying surface areas of objects and materials in rooms. Access to 33 rooms in nine residences consisting of bathrooms, bedroom/offices and common areas was solicited from among research group members living in the East San Francisco Bay Area. A systematic approach was implemented for measuring rooms and objects from 300 cm{sup 2} and larger. The ventilated air volumes of the rooms were estimated and surface area-to-volume ratios were calculated for objects and materials, each segregated into 20 or more categories. Total surface area-to-volume ratios also were determined for each room. The bathrooms had the highest total surface area-to-volume ratios. Bedrooms generally had higher ratios than common areas consisting of kitchens, living/dining rooms and transitional rooms. Total surface area-to-volume ratios for the 12 bedrooms ranged between 2.3 and 4.7 m{sup 2} m{sup -3}. The importance of individual objects and materials with respect to sorption will depend upon the sorption coefficients for the various VOC/materials combinations. When combined, the highly permeable material categories, which may contribute to significant interactions, had a median ratio of about 0.5 m{sup 2} m{sup -3} for all three types of rooms.

  5. Tropical cyclone rainfall area controlled by relative sea surface temperature

    OpenAIRE

    Lin, Yanluan; ZHAO Ming; Zhang, Minghua

    2015-01-01

    Tropical cyclone rainfall rates have been projected to increase in a warmer climate. The area coverage of tropical cyclones influences their impact on human lives, yet little is known about how tropical cyclone rainfall area will change in the future. Here, using satellite data and global atmospheric model simulations, we show that tropical cyclone rainfall area is controlled primarily by its environmental sea surface temperature (SST) relative to the tropical mean SST (that is, the relative ...

  6. Characterization of large area nanostructured surfaces using AFM measurements

    DEFF Research Database (Denmark)

    Calaon, Matteo; Hansen, Hans Nørgaard; Tosello, Guido;

    2012-01-01

    A surface characterisation study has been developed to validate an innovative tool making solution for nano patterning large areas via anodizing of aluminium (Al) and subsequent nickel electroforming. A surface topography characterization through atomic force microscopy (AFM) indicated a decreased...... magnitude of the 3D surface amplitude parameters chosen for the analysis, when increasing the Al purity from 99,5% to 99,999%. AFM was then employed to evaluate the periodical arrangements of the nano structured cells. Image processing was used to estimate the average areas value, the height variation...

  7. Surface area considerations for corroding N reactor fuel

    International Nuclear Information System (INIS)

    The N Reactor fuel is corroding at sites where the Zircaloy cladding was damaged when the fuel was discharged from the reactor. Corroding areas are clearly visible on the fuel stored in open cans in the K East Basin. There is a need to estimate the area of the corroding uranium to analyze aspects of fuel behavior as it is transitioned. from current wet storage to dry storage. In this report, the factors that contribute to open-quotes trueclose quotes surface area are analyzed in terms of what is currently known about the N Reactor fuel. Using observations from a visual examinations of the fuel in the K East wet storage facility, a value for the corroding geometric area is estimated. Based on observations of corroding uranium and surface roughness values for other metals, a surface roughness factor is also estimated and applied to the corroding K East fuel to provide an estimated open-quotes trueclose quotes surface area. While the estimated area may be modified as additional data become available from fuel characterization studies, the estimate provides a basis to assess effects of exposed uranium metal surfaces on fuel behavior in operations involved in transitioning from wet to dry storage, during shipment and staging, conditioning, and dry interim storage

  8. Students' and Teachers' Application of Surface Area to Volume Relationships

    Science.gov (United States)

    Taylor, Amy R.; Jones, M. Gail

    2013-02-01

    The National Science Education Standards emphasize teaching unifying concepts and processes such as basic functions of living organisms, the living environment, and scale (NRC 2011). Scale includes understanding that different characteristics, properties, or relationships within a system might change as its dimensions are increased or decreased (NRC 2011). One such relationship involves surface area to volume which is a pervasive concept that can be found throughout different sciences. This concept is important for students to not only understand the association of the two, but to also be able to apply this relationship in science contexts. The purpose of this study is to investigate the factors that influence the understanding surface area to volume relationships. This study examined middle school students', high school students', and science teachers' logical thinking skills (including proportional reasoning), visual-spatial skills, and understandings of surface area to volume relationships. Regression results indicated that participants' reasoning abilities and components of visual-spatial skills could be possible predictors for one's ability to understand surface area to volume relationships. Implications for teaching scale concepts such as surface area to volume relationships in the science classroom are discussed.

  9. Can foot anthropometric measurements predict dynamic plantar surface contact area?

    Directory of Open Access Journals (Sweden)

    Collins Natalie

    2009-10-01

    Full Text Available Abstract Background Previous studies have suggested that increased plantar surface area, associated with pes planus, is a risk factor for the development of lower extremity overuse injuries. The intent of this study was to determine if a single or combination of foot anthropometric measures could be used to predict plantar surface area. Methods Six foot measurements were collected on 155 subjects (97 females, 58 males, mean age 24.5 ± 3.5 years. The measurements as well as one ratio were entered into a stepwise regression analysis to determine the optimal set of measurements associated with total plantar contact area either including or excluding the toe region. The predicted values were used to calculate plantar surface area and were compared to the actual values obtained dynamically using a pressure sensor platform. Results A three variable model was found to describe the relationship between the foot measures/ratio and total plantar contact area (R2 = 0.77, p R2 = 0.76, p Conclusion The results of this study indicate that the clinician can use a combination of simple, reliable, and time efficient foot anthropometric measurements to explain over 75% of the plantar surface contact area, either including or excluding the toe region.

  10. Bayesian logistic betting strategy against probability forecasting

    CERN Document Server

    Kumon, Masayuki; Takemura, Akimichi; Takeuchi, Kei

    2012-01-01

    We propose a betting strategy based on Bayesian logistic regression modeling for the probability forecasting game in the framework of game-theoretic probability by Shafer and Vovk (2001). We prove some results concerning the strong law of large numbers in the probability forecasting game with side information based on our strategy. We also apply our strategy for assessing the quality of probability forecasting by the Japan Meteorological Agency. We find that our strategy beats the agency by exploiting its tendency of avoiding clear-cut forecasts.

  11. MCO gas composition for low reactive surface areas

    International Nuclear Information System (INIS)

    This calculation adjusts modeled output (HNF-SD-SNF-TI-040, Rev. 2) by considering lower reactive fuel surface areas and by increasing the input helium backfill overpressure from 0.5 to 1.5 atm (2.5 atm abs) to verify that MCO gas-phase oxygen concentrations can remain below 4 mole % over a 40 year interim period under a worst case condition of zero reactive surface area. Added backfill gas will dilute any gases generated during interim storage and is a strategy within the current design capability. The zero reactive surface area represents a hypothetical worst case example where there is no fuel scrap and/or damaged spent fuel rods in an MCO. Also included is a hypothetical case where only K East fuel exists in an MCO with an added backfill overpressure of 0.5 atm (1.5 atm abs)

  12. MCO gas composition for low reactive surface areas

    Energy Technology Data Exchange (ETDEWEB)

    Packer, M.J.

    1998-07-23

    This calculation adjusts modeled output (HNF-SD-SNF-TI-040, Rev. 2) by considering lower reactive fuel surface areas and by increasing the input helium backfill overpressure from 0.5 to 1.5 atm (2.5 atm abs) to verify that MCO gas-phase oxygen concentrations can remain below 4 mole % over a 40 year interim period under a worst case condition of zero reactive surface area. Added backfill gas will dilute any gases generated during interim storage and is a strategy within the current design capability. The zero reactive surface area represents a hypothetical worst case example where there is no fuel scrap and/or damaged spent fuel rods in an MCO. Also included is a hypothetical case where only K East fuel exists in an MCO with an added backfill overpressure of 0.5 atm (1.5 atm abs).

  13. STEREOLOGICAL ESTIMATION OF SURFACE AREA FROM DIGITAL IMAGES

    Directory of Open Access Journals (Sweden)

    Johanna Ziegel

    2011-05-01

    Full Text Available A sampling design of local stereology is combined with a method from digital stereology to yield a novel estimator of surface area based on counts of configurations observed in a digitization of an isotropic 2- dimensional slice with thickness s. As a tool, a result of the second author and J. Rataj on infinitesimal increase of volumes of morphological transforms is refined and used. The proposed surface area estimator is asymptotically unbiased in the case of sets contained in the ball centred at the origin with radius s and in the case of balls centred at the origin with unknown radius. For general shapes bounds for the asymptotic expected relative worst case error are given. A simulation example is discussed for surface area estimation based on 2×2×2-configurations.

  14. Dependence of friction noise of rough surfaces with contact area

    OpenAIRE

    Le Bot, Alain; Dang, Viet Hung; Bou Chakra, Elie

    2012-01-01

    The noise emitted during the friction of rough surfaces is a wide band noise generated by the numerous impacts occuring between antagonist asperites of surfaces. This study presents an experiment which investigates the law between the acoustical power and a varying number of identical sliders i.e. the nominal contact area. It is found that in some cases, the acoustical power is proportional to the number of sliders while the sound is constant in some others. This result is explained by introd...

  15. Stereological estimation of surface area from digital images

    DEFF Research Database (Denmark)

    Ziegel, Johanna; Kiderlen, Markus

    2010-01-01

    A sampling design of local stereology is combined with a method from digital stereology to yield a novel estimator of surface area based on counts of configurations observed in a digitization of an isotropic 2- dimensional slice with thickness s. As a tool, a result of the second author and J....... Rataj on infinitesimal increase of volumes of morphological transforms is refined and used. The proposed surface area estimator is asymptotically unbiased in the case of sets contained in the ball centred at the origin with radius s and in the case of balls centred at the origin with unknown radius. For...

  16. Examples of Area-Minimizing Surfaces in 3-manifolds

    OpenAIRE

    Coşkunuzer, Barış

    2014-01-01

    In this paper, we give some examples of area-minimizing surfaces to clarify some wellknown features of these surfaces in more general settings. The first example is about Meeks–Yau’s result on the embeddedness of the solution to the Plateau problem. We construct an example of a simple closed curve in R3 which lies in the boundary of a mean convex domain in R3, but the area-minimizing disk in R3 bounding this curve is not embedded. Our second example shows that White’s boundary decomposition t...

  17. Nanocrystalline GaSbO{sub 4} with high surface area prepared via a facile hydrothermal method and its photocatalytic activity study

    Energy Technology Data Exchange (ETDEWEB)

    Fu Yanghe; Xue Hun; Qin Meng; Liu Ping; Fu Xianzhi [Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis - State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (China); Li Zhaohui, E-mail: zhaohuili1969@yahoo.com [Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis - State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (China)

    2012-05-05

    Graphical abstract: Nanocrystalline GaSbO{sub 4} prepared via a facile hydrothermal method possesses large specific surface area and exhibits photocatalytic activity for the degradations of salicylic acid and acetone. Highlights: Black-Right-Pointing-Pointer Facile hydrothermal method to nanocrystalline GaSbO{sub 4} with large surface area. Black-Right-Pointing-Pointer GaSbO{sub 4} shows photocatalytic activity for the degradations of salicylic acid and acetone. Black-Right-Pointing-Pointer The photocatalytic mechanism of GaSbO{sub 4} was proposed based on the ESR result. - Abstract: Nanocrystalline GaSbO{sub 4} with small particle size and large BET specific area was successfully prepared via a facile hydrothermal method from Sb{sub 2}O{sub 5}. The influence of the reaction pH on the formation of the final product was investigated. The obtained sample was characterized by X-ray diffraction (XRD), N{sub 2}-sorption BET surface area, UV-vis diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM). The photocatalytic activity for the degradations of salicylic acid and acetone over nanocrystalline GaSbO{sub 4} under UV irradiations was for the first time revealed. Based on the electron spin resonance (ESR) result, the reactive species involved in the photocatalytic reaction over nanocrytalline GaSbO{sub 4} are determined to be HO{center_dot} and O{sub 2}{sup -}{center_dot}. The photocatalytic mechanism of GaSbO{sub 4} was proposed.

  18. Error bounds for surface area estimators based on Crofton's formula

    DEFF Research Database (Denmark)

    Kiderlen, Markus; Meschenmoser, Daniel

    2009-01-01

    According to Crofton’s formula, the surface area S(A) of a sufficiently regular compact set A in R^d is proportional to the mean of all total projections pA (u) on a linear hyperplane with normal u, uniformly averaged over all unit vectors u. In applications, pA (u) is only measured in k directions...

  19. Surface water and groundwater interaction in Marala - Khanki area, Punjab

    International Nuclear Information System (INIS)

    Isotope hydrological investigations were carried out in two selected areas of Indus Basin viz. Haripur Area and Chashma- Taunsa Area for elucidating various aspects of surface water and groundwater interaction. Groundwater samples were collected on seasonal basis (low and high river discharge periods) while surface water samples were collected more frequently (weekly or monthly basis). Isotopic data suggested that there is no contribution of surface water to groundwater recharge in Haripur Area and rain is the prevailing source of groundwater recharge. The data further revealed that isotopic values of the Haripur pocket of Tarbela Lake are higher than those of Main Lake / Indus River meaning that there is a significant contribution of base flow in this pocket. Indus River appeared to be the dominant source of groundwater recharge at most of the locations in Chashma- Taunsa Area. Isotopic data of Indus River showed an increase at Taunsa as compared to Chashma in low flow period indicating the high contribution of base flow at this point in time. Stable isotopes were successfully used to quantify the base flow contribution. (author)

  20. Scaling Up Nature: Large Area Flexible Biomimetic Surfaces.

    Science.gov (United States)

    Li, Yinyong; John, Jacob; Kolewe, Kristopher W; Schiffman, Jessica D; Carter, Kenneth R

    2015-10-28

    The fabrication and advanced function of large area biomimetic superhydrophobic surfaces (SHS) and slippery lubricant-infused porous surfaces (SLIPS) are reported. The use of roll-to-roll nanoimprinting techniques enabled the continuous fabrication of SHS and SLIPS based on hierarchically wrinkled surfaces. Perfluoropolyether hybrid molds were used as flexible molds for roll-to-roll imprinting into a newly designed thiol-ene based photopolymer resin coated on flexible polyethylene terephthalate films. The patterned surfaces exhibit feasible superhydrophobicity with a water contact angle around 160° without any further surface modification. The SHS can be easily converted into SLIPS by roll-to-roll coating of a fluorinated lubricant, and these surfaces have outstanding repellence to a variety of liquids. Furthermore, both SHS and SLIPS display antibiofouling properties when challenged with Escherichia coli K12 MG1655. The current article describes the transformation of artificial biomimetic structures from small, lab-scale coupons to low-cost, large area platforms. PMID:26423494

  1. Definition of Method of Measurement of Supporting and Control Surface Areas, Special Report

    Science.gov (United States)

    1931-01-01

    Definitions of methods of measurements of supporting and control surface areas are presented. Methods for measuring the supporting surface, i.e., the wing area, and the control surfaces, i.e., the horizontal tail area, the vertical tail area, and the trailing control surface areas are defined. Illustrations of each of the areas are included.

  2. Synthesis of large surface area LaFeO3 nanoparticles by SBA-16 template method as high active visible photocatalysts

    International Nuclear Information System (INIS)

    Nanosized LaFeO3 with large specific surface area has been successfully synthesized by an impregnation process, with mesoporous silica SBA-16 as hard template and corresponding metal nitrates as La and Fe resources, and the resulting LaFeO3 is also characterized by thermogravimetry-differential thermal analysis (TG-DTA), X-ray diffraction (XRD), N2 adsorption-desorptions, Brunauer Emmett Teller (BET) technique, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-visible diffuse reflection spectrum (UV-Vis DRS), and surface photovoltage spectroscopy (SPS). It is found that, compared with that prepared by the conventional citrate method, the as-prepared LaFeO3 with 20-50 nm particle size has remarkable large specific surface area, even still with the surface area as large as about 85 m2 g-1 after calcination at 800 oC, which is attributed to its mesoporous structure as well as the small particle size. During the photocatalytic degradation of Rhodamine B solution under visible irradiation, all the LaFeO3 samples obtained are superior to P25 TiO2, and the activity becomes high with increasing calcination temperature. It is revealed that the excellent photocatalytic performance is mainly ascribed to the large surface area and high photogenerated charge separation rate.

  3. How many independent bets are there?

    CERN Document Server

    Polakow, D; Polakow, Daniel; Gebbie, Tim

    2006-01-01

    We discuss a robust alternative to the ex-post decomposition of a portfolio into the fundamental law co-efficients using statistically estimated breadth. The breadth of a market provides a measure of the number of independent bets available to the investor. We use the Keiser-Gutman stopping criterion to select the integer valued effective dimension - eigenvalues greater-than or equal to 1. Such a method for the estimation of breadth relies critically on the appropriate estimation of the covariance matrix of price fluctuations (returns). In a emerging market such as South African it is not surprising to find that the breadth is low because of market concentration, exposure to the global commodity cycle and currency volatility. The implications of refocussing investment objectives on effective dimensionality are further discussed.

  4. Small carpal bone surface area, a characteristic of Turner's syndrome

    International Nuclear Information System (INIS)

    An abnormality which has received little attention but may be easily recognized on radiographs of the hand of patients with Turner's syndrome is described. Eleven of thirty-one patients (35.5%) with Turner's syndrome were shown on radiographs of the hand to have a visually detectable smallness of the bone surface area of the carpus when compared to the area of the second through fifth metacarpals. Values for the ''C/M'' ratio (the area of the carpals divided by the area of the second through fifth metacarpals) were calculated for films of 31 individuals with gonadal dysgenesis and compared with those from bone age-matched films of seventy-six individuals with normal development of the hand and wrist. A consistent difference with minimal overlap was documented. (orig./WL)

  5. Tropical cyclone rainfall area controlled by relative sea surface temperature.

    Science.gov (United States)

    Lin, Yanluan; Zhao, Ming; Zhang, Minghua

    2015-01-01

    Tropical cyclone rainfall rates have been projected to increase in a warmer climate. The area coverage of tropical cyclones influences their impact on human lives, yet little is known about how tropical cyclone rainfall area will change in the future. Here, using satellite data and global atmospheric model simulations, we show that tropical cyclone rainfall area is controlled primarily by its environmental sea surface temperature (SST) relative to the tropical mean SST (that is, the relative SST), while rainfall rate increases with increasing absolute SST. Our result is consistent with previous numerical simulations that indicated tight relationships between tropical cyclone size and mid-tropospheric relative humidity. Global statistics of tropical cyclone rainfall area are not expected to change markedly under a warmer climate provided that SST change is relatively uniform, implying that increases in total rainfall will be confined to similar size domains with higher rainfall rates. PMID:25761457

  6. Body surface area determined by whole-body CT scanning

    DEFF Research Database (Denmark)

    Villa, Chiara; Primeau, Charlotte; Hesse, Ulrik;

    2016-01-01

    Calculation of the estimated body surface area (BSA) by body height and weight has been a challenge in the past centuries due to lack of a well-documented gold standard. More recently, available techniques such as 3D laser surface scanning and CT scanning may be expected to quantify the BSA...... in an easier and more accurate way. This study provides the first comparison between BSA obtained from post-mortem whole-body CT scans and BSA calculated by nine predictive formulae. The sample consisted of 54 male cadavers ranging from 20 to 87 years old. 3D reconstructions were generated from CT scans using...

  7. Exploring a novel approach to fabricate vanadium carbide encapsulated into carbon nanotube (VC@C) with large specific surface area

    Indian Academy of Sciences (India)

    Yifu Zhang; Juecheng Zhang; Meijuan Fan; Yan’an Long; Yalan Zhong; Xinghai Liu; Chi Huang

    2013-06-01

    A novel approach to the fabrication of vanadium carbide encapsulated into carbon nanotube (VC@C) core-shell structured composite by thermal treatment with the precursor V3O7.H2O@C was developed for the first time. The as-obtained VC@C were characterized by X-ray powder diffraction (XRD), Raman spectrum, energydispersive X-ray spectrometer (EDX), elemental analysis (EA), Fourier transform infrared spectroscopy (FT)–(IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET). The results showed that VC@C with core-shell structures could be successfully synthesized at 1000 °C for 2 h. The specific surface area, average pore size and measured pore volume of VC@C were 135.46 m2/g, 4.443 nm and 0.180 cm3/g, respectively indicating that the as-obtained VC@C composite could be used as a mesoporous material. Furthermore, thermal behaviour of the as-obtained VC@C composite in air was investigated by thermogravimetric/differential thermal analyser (TG/DTA). The experimental result revealed that the carbon coated on the surface of VC has high activity with O2 in air atmosphere.

  8. Coal combustion: correlation between surface area and thermogravimetric analysis data

    Energy Technology Data Exchange (ETDEWEB)

    Ghetti, P.; De Robertis, U.; D' Antone, S.; Villani, M.; Chiellini, E.

    1985-07-01

    A series of coals of different rank has been characterized by surface area measurements performed by sorption of both nitrogen and carbon dioxide. While the data obtained with nitrogen do not discriminate among the different coal samples, those based on carbon dioxide sorption do give a significant distinction between the samples. This technique has also been applied to the determination of the surface area of coal samples quenched after stepwise combustion in air atmosphere. It has been possible to establish a useful correlation between the latter data and the burning profile measured by derivative thermogravimetry. The aim of the present study was to gain a better understanding of the coal combustion process on a laboratory scale which could reasonably be extended to combustion plants. 19 references.

  9. Excess Surface Area in Bioelectrochemical Systems Causes ion Transport Limitations

    Energy Technology Data Exchange (ETDEWEB)

    Harrington, Timothy D.; Babauta, Jerome T.; Davenport, Emily K.; Renslow, Ryan S.; Beyenal, Haluk

    2015-05-01

    We investigated ion transport limitations on 3D graphite felt electrodes by growing Geobacter sulfurreducens biofilms with advection to eliminate external mass transfer limitations. We characterized ion transport limitations by: (i) showing that serially increasing NaCl concentration up to 200mM increased current linearly up to a total of þ273% vs. 0mM NaCl under advective conditions; (ii) growing the biofilm with a starting concentration of 200mM NaCl, which led to a maximum current increase of 400% vs. current generation without NaCl, and (iii) showing that un-colonized surface area remained even after steadystate current was reached. After accounting for iR effects, we confirmed that the excess surface area existed despite a non-zero overpotential. The fact that the biofilm was constrained from colonizing and producing further current under these conditions confirmed the biofilms under study here were ion transport-limited. Our work demonstrates that the use of high surface area electrodes may not increase current density when the system design allows ion transport limitations to become dominant.

  10. Adsorption of naphthenic acids on high surface area activated carbons.

    Science.gov (United States)

    Iranmanesh, Sobhan; Harding, Thomas; Abedi, Jalal; Seyedeyn-Azad, Fakhry; Layzell, David B

    2014-01-01

    In oil sands mining extraction, water is an essential component; however, the processed water becomes contaminated through contact with the bitumen at high temperature, and a portion of it cannot be recycled and ends up in tailing ponds. The removal of naphthenic acids (NAs) from tailing pond water is crucial, as they are corrosive and toxic and provide a substrate for microbial activity that can give rise to methane, which is a potent greenhouse gas. In this study, the conversion of sawdust into an activated carbon (AC) that could be used to remove NAs from tailings water was studied. After producing biochar from sawdust by a slow-pyrolysis process, the biochar was physically activated using carbon dioxide (CO2) over a range of temperatures or prior to producing biochar, and the sawdust was chemically activated using phosphoric acid (H3PO4). The physically activated carbon had a lower surface area per gram than the chemically activated carbon. The physically produced ACs had a lower surface area per gram than chemically produced AC. In the adsorption tests with NAs, up to 35 mg of NAs was removed from the water per gram of AC. The chemically treated ACs showed better uptake, which can be attributed to its higher surface area and increased mesopore size when compared with the physically treated AC. Both the chemically produced and physically produced AC provided better uptake than the commercially AC. PMID:24766592

  11. Determination of hand and palm area as a ratio of body surface area in Indian population

    Directory of Open Access Journals (Sweden)

    Agarwal Pawan

    2010-01-01

    Full Text Available Background: Accurate estimation of body surface area (BSA burn is important. In small and patchy burns, the patient′s hand is used to estimate percentage of burn which is traditionally considered as 1%. There is discrepancy about what percentage of TBSA is constituted by the palm and hand. Therefore, this study was designed to determine correctly the TBSA represented by the palmar surface of the entire hand and palm in the Indian population. Material and Methods: 300 healthy adult (male and female and 300 healthy children (male and female were included in the study. TBSA was calculated using DuBois formula and hand and palm surface area was calculated using hand tracing on plain paper. The hand/palm percentage of BSA (ratio was determined by dividing hand/palm surface area by total BSA. Results: The mean hand and palm ratio for adults was 0.92% and 0.50%, respectively. The mean hand and palm ratio in children was 1.06% and 0.632%, respectively. Conclusion: The hand area (palm plus digits is more closely represented to 1% of TBSA in Indian population.

  12. Spectral theory of infinite-area hyperbolic surfaces

    CERN Document Server

    Borthwick, David

    2016-01-01

    This text introduces geometric spectral theory in the context of infinite-area Riemann surfaces, providing a comprehensive account of the most recent developments in the field. For the second edition the context has been extended to general surfaces with hyperbolic ends, which provides a natural setting for development of the spectral theory while still keeping technical difficulties to a minimum. All of the material from the first edition is included and updated, and new sections have been added. Topics covered include an introduction to the geometry of hyperbolic surfaces, analysis of the resolvent of the Laplacian, scattering theory, resonances and scattering poles, the Selberg zeta function, the Poisson formula, distribution of resonances, the inverse scattering problem, Patterson-Sullivan theory, and the dynamical approach to the zeta function. The new sections cover the latest developments in the field, including the spectral gap, resonance asymptotics near the critical line, and sharp geometric constan...

  13. STS-40 descent BET products: Development and results

    Science.gov (United States)

    Oakes, Kevin F.; Wood, James S.; Findlay, John T.

    1991-01-01

    Descent Best Estimate Trajectory (BET) Data were generated for the final Orbiter Experiments Flight, STS-40. This report discusses the actual development of these post-flight products: the inertial BET, the Extended BET, and the Aerodynamic BET. Summary results are also included. The inertial BET was determined based on processing Tracking and Data Relay Satellite (TDRSS) coherent Doppler data in conjunction with observations from eleven C-band stations, to include data from the Kwajalein Atoll and the usual California coastal radars, as well as data from five cinetheodolite cameras in the vicinity of the runways at EAFB. The anchor epoch utilized for the trajectory reconstruction was 53,904 Greenwich Mean Time (GMT) seconds which corresponds to an altitude at epoch of approximately 708 kft. Atmospheric data to enable development of an Extended BET for this mission were upsurped from the JSC operational post-flight BET. These data were evaluated based on Space Shuttle-derived considerations as well as model comparisons. The Aerodynamic BET includes configuration information, final mass properties, and both flight-determined and predicted aerodynamic performance estimates. The predicted data were based on the final pre-operational databook, updated to include flight determined incrementals based on an earlier ensemble of flights. Aerodynamic performance comparisons are presented and correlated versus statistical results based on twenty-two previous missions.

  14. Influence of spatial heterogeneity of local surface albedo on the area-averaged surface albedo retrieved from airborne irradiance measurements

    OpenAIRE

    E. Jäkel; M. Wendisch; Mayer, Bernhard

    2013-01-01

    Spectral airborne upward and downward irradiance measurements are used to derive the area-averaged surface albedo. Real surfaces are not homogeneous in their reflectivity. Therefore, this work studies the effects of the heterogeneity of surface reflectivity on the area-averaged surface albedo to quantify how well aircraft measurements can resolve the small-scale variability of the local surface albedo.

  15. A high surface area tunnel-type α-MnO2 nanorod cathode by a simple solvent-free synthesis for rechargeable aqueous zinc-ion batteries

    Science.gov (United States)

    Alfaruqi, Muhammad Hilmy; Islam, Saiful; Gim, Jihyeon; Song, Jinju; Kim, Sungjin; Pham, Duong Tung; Jo, Jeonggeun; Xiu, Zhiliang; Mathew, Vinod; Kim, Jaekook

    2016-04-01

    Tunnel-type α-MnO2 with a nanorod morphology was prepared via a simple solvent-free synthesis method for use in aqueous zinc-ion battery (ZIB). This synthesis method produced α-MnO2 with a high BET surface area of 153 m2 g-1. α-MnO2 electrode demonstrated remarkable zinc storage properties (first and second discharge capacities of 323 and 270 mAh g-1 at 16 mA g-1) with good capacity retentions and rate capability. After charging within only 60 s, the α-MnO2 nanorod cathode delivered a considerable discharge capacity of 115 mAh g-1 when cycled at current density of 16 mA g-1.

  16. Selective adsorption of volatile hydrocarbons and gases in high surface area chalcogels containing [ES3]3- anions (E = As, Sb)

    KAUST Repository

    Ahmed, Ejaz

    2014-11-25

    We describe the sol-gel synthesis of the two new chalcogels KFeSbS3 and NaFeAsS3, which demonstrate excellent adsorption selectivity for volatile hydrocarbons and gases. These predominantly mesoporous materials have been synthesized by reacting Fe(OAc)2 with K3SbS3 or Na3AsS3 in a formamide/water mixture at room temperature. Aerogels obtained after supercritical drying have BET surface areas of 636 m2/g and 505 m2/g for KFeSbS3 and NaFeAsS3, respectively, with pore sizes in the micro- (below 2 nm), meso- (2-50 nm), and macro- (above 50 nm) regions.

  17. Surface area-dependent second harmonic generation from silver nanorods.

    Science.gov (United States)

    Ngo, Hoang Minh; Luong, Thanh Tuyen; Ledoux-Rak, Isabelle

    2016-08-17

    The nonlinear optical (NLO) properties of metallic nanoparticles strongly depend on their size and shape. Metallic gold nanorods have already been widely investigated, but other noble metals could also be used for nanorod fabrication towards applications in photonics. Here we report on the synthesis and NLO characterization of silver nanorods (AgNRs) with controllable localized surface plasmon resonance. We have implemented an original, one-step and seedless synthesis method, based on a spontaneous particle growth technique in the presence of polyvinylpyrrolidone (PVP) as a capping agent. Colloidal solutions of AgNRs with various aspect ratios (5.0; 6.3; 7.5; 8.2 and 9.7) have been obtained and characterized using Harmonic light scattering (HLS) at 1064 nm, in order to investigate their quadratic NLO properties. From HLS experiments, we demonstrate that hyperpolarizability (β) values of AgNRs display a strong dependence on their surface area. PMID:27498825

  18. Variance of surface area estimators using spatial grids of lines

    Czech Academy of Sciences Publication Activity Database

    Janáček, Jiří; Kubínová, Lucie

    Vol. 2. Kraków : Polish Society for Stereology, 2005 - (Chrapoński, J.; Cwajna, J.; Wojnar, L.), s. 252-256 ISBN 83-917834-4-8. [European Congress on Stereology and Image Analysis /9./ and International Conference on Stereology and Image Analysis in Materials Science STERMAT /7./. Zakopane (PL), 10.05.2005-13.05.2005] R&D Projects: GA AV ČR(CZ) IAA100110502; GA AV ČR(CZ) IAA600110507; GA ČR(CZ) GA304/05/0153 Institutional research plan: CEZ:AV0Z50110509 Keywords : variance * stereology * surface area Subject RIV: BA - General Mathematics

  19. Asymptotic variance of grey-scale surface area estimators

    DEFF Research Database (Denmark)

    Svane, Anne Marie

    Grey-scale local algorithms have been suggested as a fast way of estimating surface area from grey-scale digital images. Their asymptotic mean has already been described. In this paper, the asymptotic behaviour of the variance is studied in isotropic and sufficiently smooth settings, resulting in a...... general asymptotic bound. For compact convex sets with nowhere vanishing Gaussian curvature, the asymptotics can be described more explicitly. As in the case of volume estimators, the variance is decomposed into a lattice sum and an oscillating term of at most the same magnitude....

  20. High surface area graphene-supported metal chalcogenide assembly

    Science.gov (United States)

    Worsley, Marcus A.; Kuntz, Joshua; Orme, Christine A.

    2016-04-19

    A composition comprising at least one graphene-supported assembly, which comprises a three-dimensional network of graphene sheets crosslinked by covalent carbon bonds, and at least one metal chalcogenide compound disposed on said graphene sheets, wherein the chalcogen of said metal chalcogenide compound is selected from S, Se and Te. Also disclosed are methods for making and using the graphene-supported assembly, including graphene-supported MoS.sub.2. Monoliths with high surface area and conductivity can be achieved. Lower operating temperatures in some applications can be achieved. Pore size and volume can be tuned.

  1. Topology-guided design and syntheses of highly stable mesoporous porphyrinic zirconium metal-organic frameworks with high surface area

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Tian -Fu [Texas A & M Univ., College Station, TX (United States); Feng, Dawei [Texas A & M Univ., College Station, TX (United States); Chen, Ying -Pin [Texas A & M Univ., College Station, TX (United States); Zou, Lanfang [Texas A & M Univ., College Station, TX (United States); Bosch, Mathieu [Texas A & M Univ., College Station, TX (United States); Yuan, Shuai [Texas A & M Univ., College Station, TX (United States); Wei, Zhangwen [Texas A & M Univ., College Station, TX (United States); Fordham, Stephen [Texas A & M Univ., College Station, TX (United States); Wang, Kecheng [Texas A & M Univ., College Station, TX (United States); Zhou, Hong -Cai [Texas A & M Univ., College Station, TX (United States)

    2015-01-14

    Through a topology-guided strategy, a series of Zr₆-containing isoreticular porphyrinic metal–organic frameworks (MOFs), PCN-228, PCN-229, and PCN-230, with ftw-a topology were synthesized using the extended porphyrinic linkers. The bulky porphyrin ring ligand effectively prevents the network interpenetration which often appears in MOFs with increased linker length. The pore apertures of the structures range from 2.5 to 3.8 nm, and PCN-229 demonstrates the highest porosity and BET surface area among the previously reported Zr-MOFs. Additionally, by changing the relative direction of the terminal phenyl rings, this series replaces a Zr₈ cluster with a smaller Zr₆ cluster in a topologically identical framework. The high connectivity of the Zr₆ cluster yields frameworks with enhanced stability despite high porosity and ultralarge linker. As a representative example, PCN-230, constructed with the most extended porphyrinic linker, shows excellent stability in aqueous solutions with pH values ranging from 0 to 12 and demonstrates one of the highest pH tolerances among all porphyrinic MOFs. This work not only presents a successful example of rational design of MOFs with desired topology, but also provides a strategy for construction of stable mesoporous MOFs.

  2. Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal-Organic Frameworks with High Surface Area

    Energy Technology Data Exchange (ETDEWEB)

    Liu, TF; Feng, DW; Chen, YP; Zou, LF; Bosch, M; Yuan, S; Wei, ZW; Fordham, S; Wang, KC; Zhou, HC

    2015-01-14

    Through a topology-guided strategy, a series of Zr-6-containing isoreticular porphyrinic metalorganic frameworks (MOFs), PCN-228, PCN-229, and PCN-230, with ftw-a topology were synthesized using the extended porphyrinic linkers. The bulky porphyrin ring ligand effectively prevents the network interpenetration which often appears in MOFs with increased linker length. The pore apertures of the structures range from 2.5 to 3.8 nm, and PCN-229 demonstrates the highest porosity and BET surface area among the previously reported Zr-MOFs. Additionally, by changing the relative direction of the terminal phenyl rings, this series replaces a Zr-8 cluster with a smaller Zr-6 cluster in a topologically identical framework. The high connectivity of the Zr-6 cluster yields frameworks with enhanced stability despite high porosity and ultralarge linker. As a representative example, PCN-230, constructed with the most extended porphyrinic linker, shows excellent stability in aqueous solutions with pH values ranging from 0 to 12 and demonstrates one of the highest pH tolerances among all porphyrinic MOFs. This work not only presents a successful example of rational design of MOFs with desired topology, but also provides a strategy for construction of stable mesoporous MOFs.

  3. Recovery of high surface area mesoporous silica from waste hexafluorosilicic acid (H2SiF6) of fertilizer industry

    International Nuclear Information System (INIS)

    In this article we report recovery of mesoporous silica from the waste material (hexafluorosilicic acid) of phosphate fertilizer industry. The process involves the reaction of hexafluorosilicic acid (50 ml, 24 wt% H2SiF6) and 100 ml, 0.297 M Na2CO3 to generate the alkaline aqueous slurry. Silica was separated from the slurry by filtration and the sodium fluoride was extracted from the aqueous solution by evaporation method. The obtained mesoporous silica was characterized by N2 absorption/desorption (BET), thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscope (SEM), and EDS. The results confirm that the separation of silica and NaF was successful and the final products have high purity. The silica product was found to have an average pore diameter of 4.14 nm and a high surface area (up to 800 m2/g). The process reported in this study may significantly reduce the release of hazardous materials into the environment and it might confer economic benefits to the responsible industries.

  4. A pair of universal sequence-set betting strategies

    OpenAIRE

    Petrović, Tomislav

    2012-01-01

    We introduce the sequence-set betting game, a generalization of An. A. Muchnik's non-monotonic betting game. Instead of successively partitioning the infinite binary strings by their value of a bit at a chosen position, as in the non-monotonic game, the player is allowed to partition the strings into any two clopen sets with equal measure. We show that, while there is no single computable sequence-set betting strategy that predicts all non-Martin-L\\"of random strings, we can construct two str...

  5. Surface States and Effective Surface Area on Photoluminescent P-Type Porous Silicon

    Science.gov (United States)

    Weisz, S. Z.; Porras, A. Ramirez; Resto, O.; Goldstein, Y.; Many, A.; Savir, E.

    1997-01-01

    The present study is motivated by the possibility of utilizing porous silicon for spectral sensors. Pulse measurements on the porous-Si/electrolyte system are employed to determine the surface effective area and the surface-state density at various stages of the anodization process used to produce the porous material. Such measurements were combined with studies of the photoluminescence spectra. These spectra were found to shift progressively to the blue as a function of anodization time. The luminescence intensity increases initially with anodization time, reaches a maximum and then decreases with further anodization. The surface state density, on the other hand, increases with anodization time from an initial value of about 2 x 10(exp 12)/sq cm surface to about 1013 sq cm for the anodized surface. This value is attained already after -2 min anodization and upon further anodization remains fairly constant. In parallel, the effective surface area increases by a factor of 10-30. This behavior is markedly different from the one observed previously for n-type porous Si.

  6. Influence of spatial heterogeneity of local surface albedo on the area-averaged surface albedo retrieved from airborne irradiance measurements

    OpenAIRE

    E. Jäkel; M. Wendisch; Mayer, B.

    2012-01-01

    Spectral airborne upward and downward irradiance measurements are used to derive the area-averaged surface albedo. Real surfaces are not homogeneous in their reflectivity. Therefore, this work studies the effects of the heterogeneity of surface reflectivity on the area-averaged surface albedo to quantify how well aircraft measurements can resolve the small-scale variability of the local surface albedo. For that purpose spatially heterogeneous surface albedo maps were input into a 3-dimensiona...

  7. Influence of spatial heterogeneity of local surface albedo on the area-averaged surface albedo retrieved from airborne irradiance measurements

    OpenAIRE

    E. Jäkel; M. Wendisch; Mayer, B.

    2013-01-01

    Spectral airborne upward and downward irradiance measurements are used to derive the area-averaged surface albedo. Real surfaces are not homogeneous in their reflectivity. Therefore, this work studies the effects of the heterogeneity of surface reflectivity on the area-averaged surface albedo to quantify how well aircraft measurements can resolve the small-scale variability of the local surface albedo. For that purpose spatially heterogeneous surface albedo maps were inpu...

  8. Estimation of surface area and length with the orientator.

    Science.gov (United States)

    Mattfeldt, T; Mall, G; Gharehbaghi, H; Möller, P

    1990-09-01

    The orientator is a new technique for the estimation of length and surface density and other stereological parameters using isotropic sections. It is an unbiased, design-based approach to the quantitative study of anisotropic structures such as muscle, myocardium, bone and cartilage. A simple method for the practical generation of such isotropic planes in biological specimens is described. No special technical equipment is necessary. Knowledge of an axis of anisotropy can be exploited to optimize the efficiency. To randomize directions in space, points are selected with uniform probability in a square using various combinations of simple random, stratified random, and systematic random sampling. The point patterns thus produced are mapped onto the surface of a hemisphere. The mapped points define directions of sectional planes in space. The mapping algorithm ensures that these planes are isotropic, hence unbiased estimates of surface and length density can be obtained via the classical stereological formulae. Various implementations of the orientator are outlined: the prototype version, the orientator-generated ortrip, two systematic versions, and the smooth version. Orientator sections can be generated without difficulty in large specimens; we investigated human skeletal muscle, myocardium, placenta, and gut tissue. Slight practical modifications extend the applicability of the method to smaller organs like rat hearts. At the ultrastructural level, a correction procedure for the loss of anisotropic mitochondrial membranes due to oblique orientation relative to the electron beam is suggested. Other potential applications of the orientator in anisotropic structures include the estimation of individual particle surface area with isotropic nucleators, the determination of the connectivity of branching networks with isotropic disectors, and generation of isotropic sections for second-order stereology (three-dimensional pattern analysis). PMID:2243364

  9. Asthma: T-bet – A Master Controller?

    OpenAIRE

    Robinson, Douglas S.; Lloyd, Clare M.

    2002-01-01

    The transcription factors T-bet and GATA3 are important reciprocal determinants of Th1 and Th2 T helper cell differentiation. Recent evidence suggests that these factors may affect airway immunopathology in asthma.

  10. Testing Market Efficiency in a Fixed Odds Betting Market

    OpenAIRE

    Jakobsson, Robin; Karlsson, Niklas

    2007-01-01

    This paper tests the hypothesis of market efficiency for the fixed odds betting market of Swedish trotting head-to-head matches. The hypothesis is carried out by a Wald test within a logistic regression model. Data support rejection of semi-strong efficiency at the 5 percent level of significance, while the weak form efficiency cannot be rejected. Moreover, evaluation of the simple strategy to bet on those horses where, conditional on the estimated model, the expected profit is positive resul...

  11. Tests of the Efficiency of Racetrack Betting Using Bookmaker Odds

    OpenAIRE

    Ron Bird; Michael McCrae

    1987-01-01

    The objective of this study is to evaluate the informational efficiency of the market for betting on horse races. Whereas the price data used in previous studies have been drawn largely from totalizator (parimutuel) odds, the data used in this study are derived from bookmaker odds. The availability of a series of prices throughout betting facilitates the use of filter tests to evaluate market efficiency. We conclude that this gambling market is efficient in the use of information supplied via...

  12. Method for producing high surface area chromia materials for catalysis

    Science.gov (United States)

    Gash, Alexander E.; Satcher, Joe; Tillotson, Thomas; Hrubesh, Lawrence; Simpson, Randall

    2007-05-01

    Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m.sup.2/g and 520 m.sup.2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

  13. Estimating the surface area of birds: using the homing pigeon (Columba livia as a model

    Directory of Open Access Journals (Sweden)

    Cristina R. Perez

    2014-05-01

    Full Text Available Estimation of the surface area of the avian body is valuable for thermoregulation and metabolism studies as well as for assessing exposure to oil and other surface-active organic pollutants from a spill. The use of frozen carcasses for surface area estimations prevents the ability to modify the posture of the bird. The surface area of six live homing pigeons in the fully extended flight position was estimated using a noninvasive method. An equation was derived to estimate the total surface area of a pigeon based on its body weight. A pigeon's surface area in the fully extended flight position is approximately 4 times larger than the surface area of a pigeon in the perching position. The surface area of a bird is dependent on its physical position, and, therefore, the fully extended flight position exhibits the maximum area of a bird and should be considered the true surface area of a bird.

  14. Surface water and groundwater interaction in Marala-Khanki area

    International Nuclear Information System (INIS)

    Isotope hydrological investigations were carried out in a selected sub-catchment of Indus Basin (Marala-Khanki Area) for elucidating various aspects of surface water and groundwater interaction. Groundwater samples were collected on seasonal basis (low and high river discharge periods) while surface water (Chenab River) samples were collected more frequently (weekly or monthly basis). Gamma /sup 18/O values of groundwater along the right bank are generally higher and vary over a narrow range of -3 to -6.5%. These values are close to the rain index. The data points of these samples lie below the local meteoric water line (LMWL) which indicates the evaporation effect. This trend is not altered even in the monsoon season when the river has very high discharge proving that the area receives recharge mainly from the rain and there is no significant contribution of river water. Data points pertaining to groundwater samples collected from the stations along the left bank of the river show large variations in gamma/sup 18/O and the values range from -10.2 to -2.5%. Some samples from this side indicate contribution of the river. Tritium and CFC dating suggest groundwater residence time ranging from >50 years to few years. The data further revealed that isotopic values of the river Chenab at Khanki (average gamma /sup 18/O and gamma /sup 2/H = -7.7% and -46%) are higher than those at Marala (average gamma /sup 18/O and gamma /sup 2/H = -9.4% and -56%). Enrichment of gamma/sup 18/O and gamma 2/H in river water at Khanki during low flow period as compared to Marala indicates the contribution of isotopically enriched base flow. Average base flow contribution in this river section during low flow period calculated by isotope data was about 30%. (orig./A.B.)

  15. Surface ozone in the urban area of Manaus, Amazonas, Brazil

    Science.gov (United States)

    Souza, R. A. F. D.; Costa, P. S.; Silva, C.; Godoi, R. M.; Martin, S. T.; Tota, J.; Barbosa, H. M.; Pauliquevis, T.; Ferreira De Brito, J.; Artaxo, P.; Manzi, A. O.; Wolf, S. A.; Cirino, G. G.

    2014-12-01

    When nitrogen oxides from vehicle and industrial emissions mix with volatile organic compounds from trees and plants with exposure to sunlight, a chemical reaction occurs contributing to ground-level ozone pollution. The preliminary results of the surface ozone study in urban area of Manaus, Amazonas State, Brazil, are presented for the first intensive operating period (IOP1) of the GoAmazon experiment (February/March 2014). Photochemical ozone production was found to be a regular process, with an afternoon maximum of the ozone mixing ratio of lower than 20 ppbv for cloudy days or clear sky weather. Typical ozone concentrations at mid-day were low (about 10 ppb). On the other hand, several high-value ozone episodes with surface ozone mixing ratios up to three times larger were registered during the dry season of 2013 (September/October). At the beginning of the wet season, the ozone concentration in Manaus decreased significantly, but diurnal variations can be found during the days with rainfall and other fast changes of meteorological conditions. Possible explanations of the nature of pulsations are discussed. Photochemical ozone production by local urban plumes of Manaus is named as a first possible source of the ozone concentration and biomass burning or power plant emissions are suggested as an alternative or an additional source.

  16. Mapping ear canal movement using area-based surface matching

    Science.gov (United States)

    Grenness, Malcolm J.; Osborn, Jon; Weller, W. Lee

    2002-02-01

    Movement of the external ear canal, associated with jaw motion, relative to the concha region of the pinna has been studied. Pairs of open-jaw and closed-jaw impressions were taken of 14 ears from 10 subjects. Three-dimensional coordinate data were obtained from the concha and the anterior surface of the canal using a reflex microscope. Proprietary area-based matching software was used to evaluate distortion of the two surfaces between the two jaw positions. The canal data from each pair were placed into the same coordinate system with their respective concha regions aligned. Difference maps of the canal data were used to demonstrate the amount of anterior-posterior (A-P), superior-inferior (S-I), and medial-lateral (M-L) movement, relative to the concha, that occurred between the open- and closed-jaw impressions. The concha regions did not undergo significant deformation. The canal regions underwent varying amounts of deformation with all canals conforming within an rms of 136 μm across the entire surface. The majority of canals underwent significant movement relative to the concha. M-L movement ranged from +2.0 to -3.8 mm; eight canals moved laterally, five moved medially, and two showed no movement. S-I movement ranged from +3.7 to -2.7 mm; nine canals moved inferiorly, two moved superiorly, and three showed no movement. A-P movement ranged between +7.5 and -8.5 mm, with five canals moving anteriorly, three posteriorly, and four in a mixed fashion. This study has shown the variability of canal movement relative to the concha and does not support previous reports that suggest that the ear canal only widens with jaw opening.

  17. Bacterial signaling and motility: Sure bets

    Energy Technology Data Exchange (ETDEWEB)

    Zhulin, Igor B [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

    2008-01-01

    The IX International Conference on Bacterial Locomotion and Signal Transduction (BLAST IX) was held from 14 to 19 January 2007 in Laughlin, NV, a town in the Mojave Desert on the Nevada-Arizona border near old Route 66 and along the banks of the Colorado River. This area is a home to rattlesnakes, sagebrush, abandoned gold mines, and compulsive gamblers. What better venue could scientists possibly dream of for a professional meeting? So there they were, about 190 scientists gathered in the Aquarius Casino Resort, the largest hotel and casino in Laughlin, discussing the latest advances in the field. Aside from a brief excursion to an abandoned gold mine and a dinner cruise on the Colorado River, the scientists focused on nothing but their data and hypotheses, in spirited arguments and rebuttals, and outlined their visions and future plans in a friendly and open environment. The BLAST IX program was dense, with nearly 50 talks and over 90 posters. For that reason, this meeting report will not attempt to be comprehensive; instead it will first provide general background information on the central topics of the meeting and then highlight only a few talks that were of special interest to us and hopefully to the wider scientific community. We will also attempt to articulate some of the future directions or perspectives to the best of our abilities. The best known and understood bacterial motility mechanism is swimming powered by flagella. The rotation of bacterial flagella drives this form of bacterial movement in an aqueous environment. A bacterial flagellum consists of a helical filament attached to the cell body through a complex structure known as the hook-basal body, which drives flagellar rotation. The essential components of the basal body are the MotA-MotB motor-stator proteins bound to the cytoplasmic membrane. These stator proteins interact with proteins that comprise the supramembrane and cytoplasmic rings, which are components of the motor imbedded in the

  18. Surface-based morphometry reveals distinct cortical thickness and surface area profiles in Williams syndrome.

    Science.gov (United States)

    Green, Tamar; Fierro, Kyle C; Raman, Mira M; Saggar, Manish; Sheau, Kristen E; Reiss, Allan L

    2016-04-01

    Morphometric investigations of brain volumes in Williams syndrome (WS) consistently show significant reductions in gray matter volume compared to controls. Cortical thickness (CT) and surface area (SA) are two constituent parts of cortical gray matter volume that are considered genetically distinguishable features of brain morphology. Yet, little is known about the independent contribution of cortical CT and SA to these volumetric differences in WS. Thus, our objectives were: (i) to evaluate whether the microdeletion in chromosome 7 associated with WS has a distinct effect on CT and SA, and (ii) to evaluate age-related variations in CT and SA within WS. We compared CT and SA values in 44 individuals with WS to 49 age- and sex-matched typically developing controls. Between-group differences in CT and SA were evaluated across two age groups: young (age range 6.6-18.9 years), and adults (age range 20.2-51.5 years). Overall, we found contrasting effects of WS on cortical thickness (increases) and surface area (decreases). With respect to brain topography, the between-group pattern of CT differences showed a scattered pattern while the between-group surface area pattern was widely distributed throughout the brain. In the adult subgroup, we observed a cluster of increases in cortical thickness in WS across the brain that was not observed in the young subgroup. Our findings suggest that extensive early reductions in surface area are the driving force for the overall reduction in brain volume in WS. The age-related cortical thickness findings might reflect delayed or even arrested development of specific brain regions in WS. © 2016 Wiley Periodicals, Inc. PMID:26852730

  19. The impact of built-up surfaces on land surface temperatures in Italian urban areas.

    Science.gov (United States)

    Morabito, Marco; Crisci, Alfonso; Messeri, Alessandro; Orlandini, Simone; Raschi, Antonio; Maracchi, Giampiero; Munafò, Michele

    2016-05-01

    Urban areas are characterized by the very high degree of soil sealing and continuous built-up areas: Italy is one of the European countries with the highest artificial land cover rate, which causes a substantial spatial variation in the land surface temperature (LST), modifying the urban microclimate and contributing to the urban heat island effect. Nevertheless, quantitative data regarding the contribution of different densities of built-up surfaces in determining urban spatial LST changes is currently lacking in Italy. This study, which aimed to provide clear and quantitative city-specific information on annual and seasonal spatial LST modifications resulting from increased urban built-up coverage, was conducted generally throughout the whole year, and specifically in two different periods (cool/cold and warm/hot periods). Four cities (Milan, Rome, Bologna and Florence) were included in the study. The LST layer and the built-up-surface indicator were obtained via use of MODIS remote sensing data products (1km) and a very high-resolution map (5m) of built-up surfaces recently developed by the Italian National Institute for Environmental Protection and Research. The relationships between the dependent (mean daily, daytime and nighttime LST values) and independent (built-up surfaces) variables were investigated through linear regression analyses, and comprehensive built-up-surface-related LST maps were also developed. Statistically significant linear relationships (p<0.001) between built-up surfaces and spatial LST variations were observed in all the cities studied, with a higher impact during the warm/hot period than in the cool/cold ones. Daytime and nighttime LST slope patterns depend on the city size and relative urban morphology. If implemented in the existing city plan, the urban maps of built-up-surface-related LST developed in this study might be able to support more sustainable urban land management practices by identifying the critical areas (Hot

  20. Lung deposited surface area size distributions of particulate matter in different urban areas

    Science.gov (United States)

    Kuuluvainen, Heino; Rönkkö, Topi; Järvinen, Anssi; Saari, Sampo; Karjalainen, Panu; Lähde, Tero; Pirjola, Liisa; Niemi, Jarkko V.; Hillamo, Risto; Keskinen, Jorma

    2016-07-01

    Lung deposited surface area (LDSA) concentration is considered as a relevant metric for the negative health effects of aerosol particles. We report for the first time the size distributions of the LDSA measured in urban air. The measurements were carried out in the metropolitan area of Helsinki, including mobile laboratory and stationary measurements in different outdoor environments, such as traffic sites, a park area, the city center and residential areas. The main instrument in this study was an electrical low pressure impactor (ELPI), which was calibrated in the field to measure the LDSA concentration. The calibration factor was determined to be 60 μm2/(cm3 pA). In the experiments, the LDSA size distributions were found to form two modes at the traffic sites and in the city center. Both of these traffic related particle modes, the nucleation mode and the soot mode, had a clear contribution to the total LDSA concentration. The average total concentrations varied from 12 to 94 μm2/cm3, measured in the park area and at the traffic site next to a major road, respectively. The LDSA concentration was found to correlate with the mass of fine particles (PM2.5), but the relation of these two metrics varied between different environments, emphasizing the influence of traffic on the LDSA. The results of this study provide valuable information on the total concentrations and size distributions of the LDSA for epidemiological studies. The size distributions are especially important in estimating the contribution of outdoor concentrations on the concentrations inside buildings and vehicles through size-dependent penetration factors.

  1. Human lung volume, alveolar surface area, and capillary length

    DEFF Research Database (Denmark)

    Wiebe, B. M.; Laursen, Henning

    1995-01-01

    Cavalieri's principle, length density, morphometry, stereology, surface density, vertical sections, vertical slices......Cavalieri's principle, length density, morphometry, stereology, surface density, vertical sections, vertical slices...

  2. The winds regime of surface in the Colombian coffee area

    International Nuclear Information System (INIS)

    The characteristics of the address and gust of wind of the surface winds have been studied in 15 stations of the Colombian coffee area. It was found that the relief plays an important paper in the wind circulation so that during the day (7 a.m. - 7 p.m.) these they blow of the low sector toward the mountain and at night (7 p.m. - 7 a.m.) this situation is invested, that which is consistent with the characteristic pattern of circulation valley-mountain of the mountainous regions. For this fact, in most of the analyzed places a single day and night dominant address that it takes the orientation in that it is the respective hydrographic basin. It was not observed that the Alisios winds of the northeast and southeast modify the address settled down by the local circulation (valley-mountain) on the other hand a remarkable increase of the gust of wind was appreciated in July and August in the Florida and Ospina, stations located to the south of the country, as direct consequence of the Alisios of the southeast. The daily gust of wind in most of the studied places is low and it doesn't exceed of the 10 km/h, reason why it can consider that the Colombian coffee area is free of important damages for the action of the wind. Nevertheless, in some stations as Alban, Maracay and Paraguaicito the daily maximum gust of wind can surpass the 30 km/h and in occasions to cause damage mechanic to cultivations of high behavior and not well anchored facilities

  3. Modeling surface area to volume effects on borosilicate glass dissolution

    International Nuclear Information System (INIS)

    We simulated the reaction of SRL-131 glass with equilibrated J-13 water in order to investigate the effects of surface area to volume ratio (SA/V) on glass dissolution. We show that glass-fluid ion exchange causes solution pH to rise to progressively higher values as SA/V increases. Because the ion exchange is rapid relative to the duration of the glass dissolution experiment, the pH effect does not scale with (SA/V)*time. Experiments compared at the same (SA/V)*time value therefore have different pHs, with higher pHs at higher SA/V ratios. Both experimental data and our simulation results show similar trends of increasing reaction rate as a function of SA/V ratio when scaled to (SA/V)*time. Glasses which react in systems of differing SA/V ratio therefore follow different reaction paths and high SA/V ratios cannot be used to generate data which accurately scales to long time periods unless the ion exchange effect is taken into account. We suggest some simple test designs which enable more reliable high. SA/V accelerated tests

  4. Bicontinuous ceramics with high surface area from block copolymer templates.

    Science.gov (United States)

    Hsueh, Han-Yu; Ho, Rong-Ming

    2012-06-01

    Mesoporous polymers with gyroid nanochannels can be fabricated from the self-assembly of degradable block copolymer, polystyrene-b-poly(L-lactide) (PS-PLLA), followed by hydrolysis of PLLA block. Well-defined polymer/ceramic nanohybrid materials with inorganic gyroid nanostructures in a PS matrix can be obtained by using the mesoporous PS as a template for sol-gel reaction. Titanium tetraisopropoxide (TTIP) is used as a precursor to give a model system for the fabrication of metal oxide nanostructures from reactive transition metal alkoxides. By controlling the rates of capillary-driven pore filling and sol-gel reaction, the templated synthesis can be well-developed. Also, by taking advantage of calcination, bicontinuous TiO(2) with controlled crystalline phase (i.e., anatase phase) can be fabricated after removal of the PS template and crystallization of TiO(2) by calcination leading to high photocatalytic efficiency. This new approach provides an easy way to fabricate high-surface-area and high-porosity ceramics with self-supporting structure and controlled crystalline phase for practical applications. As a result, a platform technology to fabricate precisely controlled polymer/ceramic nanohybrids and mesoporous ceramic materials can be established. PMID:22530553

  5. Understanding the effects of the impervious surfaces pattern on land surface temperature in an urban area

    Science.gov (United States)

    Nie, Qin; Xu, Jianhua

    2015-06-01

    It is well known that urban impervious surface (IS) has a warming effect on urban land surface temperature (LST). However, the influence of an IS's structure, components, and spatial distribution on LST has rarely been quantitatively studied within strictly urban areas. Using ETM+ remote sensing images from the downtown area of Shanghai, China in 2010, this study characterized and quantified the influence of the IS spatial pattern on LST by selecting the percent cover of each IS cover feature and ten configuration metrics. The IS fraction was estimated by linear spectral mixture analysis (LSMA), and LST was retrieved using a mono-window algorithm. The results indicate that high fraction IS cover features account for the majority of the study area. The high fraction IS cover features are widely distributed and concentrated in groups, which is similar with that of high temperature zones. Both the percent composition and the configuration of IS cover features greatly affect the magnitude of LST, but the percent composition is a more important factor in determining LST than the configuration of those features. The significances and effects of the given configuration variables on LST vary greatly among IS cover features.

  6. Is the surface area of the red cell membrane skeleton locally conserved?

    OpenAIRE

    Fischer, T M

    1992-01-01

    The incompressibility of the lipid bilayer keeps the total surface area of the red cell membrane constant. Local conservation of membrane surface area requires that each surface element of the membrane skeleton keeps its area when its aspect ratio is changed. A change in area would require a flow of lipids past the intrinsic proteins to which the skeleton is anchored. in fast red cell deformations, there is no time for such a flow. Consequently, the bilayer provides for local area conservatio...

  7. Determination of surface-accessible acidic hydroxyls and surface area of lignin by cationic dye adsorption.

    Science.gov (United States)

    Sipponen, Mika Henrikki; Pihlajaniemi, Ville; Littunen, Kuisma; Pastinen, Ossi; Laakso, Simo

    2014-10-01

    A new colorimetric method for determining the surface-accessible acidic lignin hydroxyl groups in lignocellulose solid fractions was developed. The method is based on selective adsorption of Azure B, a basic dye, onto acidic hydroxyl groups of lignin. Selectivity of adsorption of Azure B on lignin was demonstrated using lignin and cellulose materials as adsorbents. Adsorption isotherms of Azure B on wheat straw (WS), sugarcane bagasse (SGB), oat husk, and isolated lignin materials were determined. The maximum adsorption capacities predicted by the Langmuir isotherms were used to calculate the amounts of surface-accessible acidic hydroxyl groups. WS contained 1.7-times more acidic hydroxyls (0.21 mmol/g) and higher surface area of lignin (84 m(2)/g) than SGB or oat husk materials. Equations for determining the amount of surface-accessible acidic hydroxyls in solid fractions of the three plant materials by a single point measurement were developed. A method for high-throughput characterization of lignocellulosic materials is now available. PMID:25033327

  8. Mercury Underpotential Deposition to Determine Iridium and Iridium Oxide Electrochemical Surface Areas

    Energy Technology Data Exchange (ETDEWEB)

    Alia, Shaun M.; Hurst, Katherine E.; Kocha, Shyam S.; Pivovar, Bryan S.

    2016-06-02

    Determining the surface areas of electrocatalysts is critical for separating the key properties of area-specific activity and electrochemical surface area from mass activity. Hydrogen underpotential deposition and carbon monoxide oxidation are typically used to evaluate iridium (Ir) surface areas, but are ineffective on oxides and can be sensitive to surface oxides formed on Ir metals. Mercury underpotential deposition is presented in this study as an alternative, able to produce reasonable surface areas on Ir and Ir oxide nanoparticles, and able to produce similar surface areas prior to and following characterization in oxygen evolution. Reliable electrochemical surface areas allow for comparative studies of different catalyst types and the characterization of advanced oxygen evolution catalysts. They also enable the study of catalyst degradation in durability testing, both areas of increasing importance within electrolysis and electrocatalysis.

  9. Summertime evolution of snow specific surface area close to the surface on the Antarctic Plateau

    Science.gov (United States)

    Libois, Q.; Picard, G.; Arnaud, L.; Dumont, M.; Lafaysse, M.; Morin, S.; Lefebvre, E.

    2015-12-01

    On the Antarctic Plateau, snow specific surface area (SSA) close to the surface shows complex variations at daily to seasonal scales which affect the surface albedo and in turn the surface energy budget of the ice sheet. While snow metamorphism, precipitation and strong wind events are known to drive SSA variations, usually in opposite ways, their relative contributions remain unclear. Here, a comprehensive set of SSA observations at Dome C is analysed with respect to meteorological conditions to assess the respective roles of these factors. The results show an average 2-to-3-fold SSA decrease from October to February in the topmost 10 cm in response to the increase of air temperature and absorption of solar radiation in the snowpack during spring and summer. Surface SSA is also characterized by significant daily to weekly variations due to the deposition of small crystals with SSA up to 100 m2 kg-1 onto the surface during snowfall and blowing snow events. To complement these field observations, the detailed snowpack model Crocus is used to simulate SSA, with the intent to further investigate the previously found correlation between interannual variability of summer SSA decrease and summer precipitation amount. To this end, some Crocus parameterizations have been adapted to Dome C conditions, and the model was forced by ERA-Interim reanalysis. It successfully matches the observations at daily to seasonal timescales, except for the few cases when snowfalls are not captured by the reanalysis. On the contrary, the interannual variability of summer SSA decrease is poorly simulated when compared to 14 years of microwave satellite data sensitive to the near-surface SSA. A simulation with disabled summer precipitation confirms the weak influence in the model of the precipitation on metamorphism, with only 6 % enhancement. However, we found that disabling strong wind events in the model is sufficient to reconciliate the simulations with the observations. This suggests that

  10. Extracting local information from crowds through betting markets

    Science.gov (United States)

    Weijs, Steven

    2015-04-01

    In this research, a set-up is considered in which users can bet against a forecasting agency to challenge their probabilistic forecasts. From an information theory standpoint, a reward structure is considered that either provides the forecasting agency with better information, paying the successful providers of information for their winning bets, or funds excellent forecasting agencies through users that think they know better. Especially for local forecasts, the approach may help to diagnose model biases and to identify local predictive information that can be incorporated in the models. The challenges and opportunities for implementing such a system in practice are also discussed.

  11. On Loss Aversion, Level-1 Reasoning, and Betting

    DEFF Research Database (Denmark)

    Erev, Ido; Gilat-Yihyie, Sharon; Marchiori, Davide;

    2014-01-01

    Previous research suggests that human reaction to risky opportunities reflects two contradicting biases: “loss aversion”, and “limited level of reasoning” that leads to overconfidence. Rejection of attractive gambles is explained by loss aversion, while counterproductive risk seeking is attributed...... to limited level of reasoning. The current research highlights a shortcoming of this popular (but often implicit) “contradicting biases” assertion. Studies of “negative-sum betting games” reveal high rate of counterproductive betting even when limited level of reasoning and loss aversion imply no...

  12. Surface chemistry of mineral powders: 1

    International Nuclear Information System (INIS)

    Low surface areas of non-porous mineral and oxide powders have been determined by adsorption calorimetry to a precision of +-15 percent. Five standards with surface areas in the range 0.64 to 24.3 m2/g were examined to check the internal consistency of our method. Our surface area values agree within +-10 percent with supplied values, obtained by the Brunauer, Emmett and Teller (BET) nitrogen adsorption technique at -196 deg C. The present technique is less time consuming than commercial systems and requires small sample size (< 1 g per run). Also, the technique works at 25 degrees C, rather than at -196 degrees C, and can be adapted for routine operation. Finally, the technique appears preferable to a relatively tedious gas-solid chromatographic method, which uses large samples (200 to 300 g), and yields values in poor agreement with BET results

  13. Estimating the surface area of birds: using the homing pigeon (Columba livia) as a model

    OpenAIRE

    Cristina R. Perez; Moye, John K.; Chris A. Pritsos

    2014-01-01

    ABSTRACT Estimation of the surface area of the avian body is valuable for thermoregulation and metabolism studies as well as for assessing exposure to oil and other surface-active organic pollutants from a spill. The use of frozen carcasses for surface area estimations prevents the ability to modify the posture of the bird. The surface area of six live homing pigeons in the fully extended flight position was estimated using a noninvasive method. An equation was derived to estimate the total s...

  14. Measuring and comparing brain cortical surface area and other areal quantities

    OpenAIRE

    Winkler, Anderson M.; Sabuncu, Mert R.; Yeo, B.T. Thomas; Fischl, Bruce; Greve, Douglas N.; Kochunov, Peter; Nichols, Thomas E.; Blangero, John; Glahn, David C

    2012-01-01

    Structural analysis of MRI data on the cortical surface usually focuses on cortical thickness. Cortical surface area, when considered, has been measured only over gross regions or approached indirectly via comparisons with a standard brain. Here we demonstrate that direct measurement and comparison of the surface area of the cerebral cortex at a fine scale is possible using mass conservative interpolation methods. We present a framework for analyses of the cortical surface area, as well as fo...

  15. Regulation of Sports Betting in the Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Hamerník, Pavel

    The Hague: T.M.C. ASSER PRESS, 2011 - (Anderson, P.; Blackshaw, I.; Siekmann, R.; Soek, J.), s. 333-340 ISBN 978-90-6704-798-2 Institutional support: RVO:68378122 Keywords : sport * betting * lottery Subject RIV: AG - Legal Sciences

  16. Afghanistan: Håbet lever – og elektrikerne er tilkaldt

    DEFF Research Database (Denmark)

    Vestenskov, David

    2013-01-01

    bet for den civile afghaner kan til tider virke som et skamskudt fyrtårn, og det bliver næppe genopbygget af kritiske observationer og selvretfærdig debat. Operationens fokus forud for de udenlandske troppers exit er at udvikle sikkerhedsinstitutionerne og skabe arbejdspladser...

  17. Determining eyeball surface area directly exposed to the effects of external factors.

    Science.gov (United States)

    Juliszewski, Tadeusz; Kadłuczka, Filip; Kiełbasa, Paweł

    2016-01-01

    This article discusses determining the surface area of eyeballs of men and women exposed to the direct effects of external factors in the working environment. For one eye, the mean surface is 172-182 mm(2). The determined surface area can be used in formulas for calculating the exposure of eyeballs to harmful chemical substances in workplace air. PMID:26758027

  18. High-surface-area silica nanospheres (KCC-1) with a fibrous morphology

    KAUST Repository

    Polshettiwar, Vivek

    2010-08-02

    Fibrous nanosilica: A new family of high-surface-area silica nanospheres (KCC-1) have been prepared (see picture). KCC-1 features excellent physical properties, including high surface area, unprecedented fibrous surface morphology, high thermal (up to 950 °C) and hydrothermal stabilities, and high mechanical stability. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Restoration of eroded surfaces in Serbian ski-areas

    Directory of Open Access Journals (Sweden)

    Ristić Ratko

    2009-01-01

    Full Text Available The environmental impacts in Serbian ski areas are very strong, leading to landscape degradation and functionality losses. Construction or improvement works cause serious destruction of topsoil and native vegetation. Some activities enhance erosion production and sediment yield: clear cuttings; trunk transport down the slope; road construction and large excavations. Also, lack of erosion control works in ski areas, especially between April and October, result in various forms of land degradation such as furrows, gullies, landslides, or debris from rock weathering. The consequences of mismanagement in ski areas are noticeable in downstream sections of river beds, causing floods and bed-load deposition. Planning and designing activities, with the application of technical and biotechnical erosion control structures, through the concept of restoration, are necessary measures in the protection of ski areas.

  20. Restoration of eroded surfaces in Serbian ski-areas

    OpenAIRE

    Ristić Ratko; Radić Boris; Vasiljević Nevena

    2009-01-01

    The environmental impacts in Serbian ski areas are very strong, leading to landscape degradation and functionality losses. Construction or improvement works cause serious destruction of topsoil and native vegetation. Some activities enhance erosion production and sediment yield: clear cuttings; trunk transport down the slope; road construction and large excavations. Also, lack of erosion control works in ski areas, especially between April and October, result in various forms of land degradat...

  1. 30 CFR 922.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 922.762 Section 922.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MICHIGAN § 922.762 Criteria for designating areas as unsuitable for surface coal...

  2. 30 CFR 941.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 941.762 Section 941.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface...

  3. 30 CFR 939.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 939.762 Section 939.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface...

  4. 30 CFR 921.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 921.762 Section 921.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface...

  5. 30 CFR 912.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 912.762 Section 912.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE IDAHO § 912.762 Criteria for designating areas as unsuitable for surface coal...

  6. 30 CFR 937.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 937.762 Section 937.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OREGON § 937.762 Criteria for designating areas as unsuitable for surface coal...

  7. 30 CFR 947.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 947.762 Section 947.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface...

  8. 30 CFR 933.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 933.762 Section 933.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designation Areas Unsuitable for Surface...

  9. 30 CFR 910.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 910.762 Section 910.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE GEORGIA § 910.762 Criteria for designating areas as unsuitable for surface coal...

  10. 30 CFR 903.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 903.762 Section 903.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE ARIZONA § 903.762 Criteria for designating areas as unsuitable for surface coal...

  11. 30 CFR 905.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 905.762 Section 905.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface...

  12. Large-area fabrication of superhydrophobic surfaces for practical applications: an overview

    Directory of Open Access Journals (Sweden)

    Chao-Hua Xue, Shun-Tian Jia, Jing Zhang and Jian-Zhong Ma

    2010-01-01

    Full Text Available This review summarizes the key topics in the field of large-area fabrication of superhydrophobic surfaces, concentrating on substrates that have been used in commercial applications. Practical approaches to superhydrophobic surface construction and hydrophobization are discussed. Applications of superhydrophobic surfaces are described and future trends in superhydrophobic surfaces are predicted.

  13. Large-area fabrication of superhydrophobic surfaces for practical applications: an overview

    International Nuclear Information System (INIS)

    This review summarizes the key topics in the field of large-area fabrication of superhydrophobic surfaces, concentrating on substrates that have been used in commercial applications. Practical approaches to superhydrophobic surface construction and hydrophobization are discussed. Applications of superhydrophobic surfaces are described and future trends in superhydrophobic surfaces are predicted. (topical review)

  14. Large-area fabrication of superhydrophobic surfaces for practical applications: an overview

    OpenAIRE

    Chao-Hua Xue, Shun-Tian Jia, Jing Zhang and Jian-Zhong Ma

    2010-01-01

    This review summarizes the key topics in the field of large-area fabrication of superhydrophobic surfaces, concentrating on substrates that have been used in commercial applications. Practical approaches to superhydrophobic surface construction and hydrophobization are discussed. Applications of superhydrophobic surfaces are described and future trends in superhydrophobic surfaces are predicted.

  15. Surface albedo measurements in Mexico City metropolitan area

    Energy Technology Data Exchange (ETDEWEB)

    Castro, T; Mar, B; Longoria, R; Ruiz Suarez, L. G [Centro de Ciencias de la Atmosfera, UNAM, Mexico, D.F. (Mexico); Morales, L [Instituto de Geografia, UNAM, Mexico, D.F. (Mexico)

    2001-04-01

    Optical and thermal properties of soils are important input data for the meteorological and photochemical modules of air quality models. As development of these models increase on spatial resolution good albedo data become more important. In this paper measurements of surface albedo of UV (295-385 nm) and visible (450-550 nm) radiation are reported for different urban and rural surfaces in the vicinity of Mexico City. It was found for the downtown zone and average albedo value of 0.05 which is in very good agreement with reported values for urban surfaces. Our albedo values measured in UV region for grey cement and green grass are of 0.10 and 0.009, respectively, and quite similar to those found at the literature of 0.11 and 0.008 for those type of surfaces. [Spanish] Las propiedades opticas y termicas de suelos son datos importantes para los modulos meteorologicos y fotoquimicos de los modelos de calidad del aire. Conforme aumenta la resolucion espacial del modelo se vuelve mas importante contar con buenos datos de albedo. En este articulo se presentan mediciones de albedo superficial de radiacion Ultravioleta (295-385 nm) y visible (450-550 nm) para diferentes superficies urbanas. Los valores medidos de albedo en la region UV para cemento gris y pasto verde son de 0.10 y 0.009, respectivamente, y son muy similares a los reportados en la literatura, 0.11 y 0.008 para este tipo de superficies.

  16. Determination of catchment area of surface water in gis for suitable land management

    OpenAIRE

    Kovačič, Primož

    2009-01-01

    The main purpose of this diploma thesis is defining the catchment areas of surface waters for suitable land management, which is also reflected on water quality. Besides basic concepts, legal backgrounds in Slovenia, which are related to water areas and water management, are introduced. The thesis presents the existing models of catchment areas of waters in Slovenia and it especially exposes the subsistent methodology of defining catchment areas of surface waters on the basis of digital eleva...

  17. CXCR6 marks a novel subset of T-bet(lo)Eomes(hi) natural killer cells residing in human liver.

    Science.gov (United States)

    Stegmann, Kerstin A; Robertson, Francis; Hansi, Navjyot; Gill, Upkar; Pallant, Celeste; Christophides, Theodoros; Pallett, Laura J; Peppa, Dimitra; Dunn, Claire; Fusai, Giuseppe; Male, Victoria; Davidson, Brian R; Kennedy, Patrick; Maini, Mala K

    2016-01-01

    Natural killer cells (NK) are highly enriched in the human liver, where they can regulate immunity and immunopathology. We probed them for a liver-resident subset, distinct from conventional bone-marrow-derived NK. CXCR6+ NK were strikingly enriched in healthy and diseased liver compared to blood (p bright)CD16-CD57-), and expressed the tissue-residency marker CD69. CXCR6+ NK produced fewer cytotoxic mediators and pro-inflammatory cytokines than the non-liver-specific CXCR6- fraction. Instead CXCR6+ NK could upregulate TRAIL, a key death ligand in hepatitis pathogenesis. CXCR6 demarcated liver NK into two transcriptionally distinct populations: T-bet(hi)Eomes(lo)(CXCR6-) and T-bet(lo)Eomes(hi)(CXCR6+); the latter was virtually absent in the periphery. The small circulating CXCR6+ subset was predominantly T-bet(hi)Eomes(lo), suggesting its lineage was closer to CXCR6- peripheral than CXCR6+ liver NK. These data reveal a large subset of human liver-resident T-bet(lo)Eomes(hi) NK, distinguished by their surface expression of CXCR6, adapted for hepatic tolerance and inducible anti-viral immunity. PMID:27210614

  18. Bet-hedging as an evolutionary game: the trade-off between egg size and number

    OpenAIRE

    Olofsson, Helen; Ripa, Jörgen; Jonzén, Niclas

    2009-01-01

    Bet-hedging theory addresses how individuals should optimize fitness in varying and unpredictable environments by sacrificing mean fitness to decrease variation in fitness. So far, three main bet-hedging strategies have been described: conservative bet-hedging (play it safe), diversified bet-hedging (don’t put all eggs in one basket) and adaptive coin flipping (choose a strategy at random from a fixed distribution). Within this context, we analyse the trade-off between many small eggs (or see...

  19. In Search of a Fair Bet in the Lottery

    OpenAIRE

    Kent R. Grote; Victor A. Matheson

    2006-01-01

    Although state-operated lotto games have the worst average expected payoffs among common games of chance, because the jackpot can accumulate, the maximum expected payoff is potentially unlimited. It is possible, therefore, that lotto can exhibit a positive expected return. This paper examines 18,000 drawings in 34 American lotteries and finds approximately 1 percent of these drawings provided players with a fair bet. If it were possible for a bettor to purchase every possible combination, how...

  20. BLM National Surface Management Agency: Area Polygons, Withdrawal Area Polygons, and Special Public Purpose Withdrawal Area Polygons

    Data.gov (United States)

    Federal Geographic Data Committee — The SMA implementation is comprised of one feature dataset, with several polygon feature classes, rather than a single feature class. SurfaceManagementAgency: The...

  1. Relationship between Mineral Soil Surface Area and the Biological Degradation of Biosolids Added to Soil

    OpenAIRE

    Dongqi Wen; Wenjuan Zhai; Demetrios Moschandreas; Guanglong Tian; Noll, Kenneth E.

    2015-01-01

    Geochemical and biological processes that operate in the soil matrix and on the soil surface are important to the degradation of biosolids in soil. Due to the large surface area of soils it is assumed that the microbial ecology is associated with mineral soil surface area. The total mineral surface areas were determined for soils from eight different fields selected from a long term study (1972–2006) of annual biosolids application to 41 fields in central Illinois varying in size from 3.6 to ...

  2. Area estimates and rigidity of capillary $H-$surfaces in three-manifolds with boundary

    OpenAIRE

    Espinar, José M.; Rosenberg, Harold

    2015-01-01

    We obtain a bound for the area of a capillary $H-$surface in a three-manifold with umbilic boundary and controlled sectional curvature. We then analyze the geometry when this area bound is realized, and obtain rigidity theorems. As a side product, we obtain existence of totally geodesic embedded surfaces in hyperbolic three-manifolds under the assumption of the existence of a $H-$surface realizing the area bound, in particular, under the existence of a totally umbilic $H-$surface.

  3. Target surface area effects on hot electron dynamics from high intensity laser–plasma interactions

    Science.gov (United States)

    Zulick, C.; Raymond, A.; McKelvey, A.; Chvykov, V.; Maksimchuk, A.; Thomas, A. G. R.; Willingale, L.; Yanovsky, V.; Krushelnick, K.

    2016-06-01

    Reduced surface area targets were studied using an ultra-high intensity femtosecond laser in order to determine the effect of electron sheath field confinement on electron dynamics. X-ray emission due to energetic electrons was imaged using a {K}α imaging crystal. Electrons were observed to travel along the surface of wire targets, and were slowed mainly by the induced fields. Targets with reduced surface areas were correlated with increased hot electron densities and proton energies. Hybrid Vlasov–Fokker–Planck simulations demonstrated increased electric sheath field strength in reduced surface area targets.

  4. A method for increasing the surface area of perovskite-type oxides

    Indian Academy of Sciences (India)

    S Banerjee; V R Choudhary

    2000-10-01

    A method based on hydrothermal treatments is described for increasing the surface area of sintered ABO3-type perovskite oxides. Influence of hydrothermal treatments, such as water treatment at 125-300°C under autogeneous pressure and steam treatment at 350-800°C, to low surface area (or sintered) LaCoO3 and LaMnO3 perovskite oxides on their surface properties (viz. surface area, crystal size and morphology and surface La/(Co or Mn) ratio) and also catalytic activity in complete combustion of methane at different temperatures (450-600°C) has been thoroughly investigated. The hydrothermal treatments result in the activation of the perovskite oxides by increasing their surface area very markedly.

  5. Surface and subsurface conditions in permafrost areas - a literature review

    International Nuclear Information System (INIS)

    This report contains a summary of some of the information within existing technical and scientific literature on permafrost. Permafrost is viewed as one of the future climate driven process domains that may exist in Scandinavia, and that may give rise to significantly different surface and subsurface conditions than the present. Except for changes in the biosphere, permafrost may impact hydraulic, mechanical, and chemical subsurface processes and conditions. Permafrost and its influences on the subsurface conditions are thus of interest for the performance and safety assessments of deep geological waste repositories. The definition of permafrost is 'ground that stays at or below 0 deg C for at least two consecutive years'. Permafrost will effect the geological subsurface to some depth. How deep the permafrost may grow is a function of the heat balance, thermal conditions at the surface and within the ground, and the geothermal heat flux from the Earth's inner parts. The main chapters of the report summaries the knowledge on permafrost evolution, occurrence and distribution, and extracts information concerning hydrology and mechanical and chemical impacts due to permafrost related conditions. The results of a literature review are always dependent on the available literature. Concerning permafrost there is some literature available from investigations in the field of long-term repositories and some from mining industries. However, reports of these investigations are few and the bulk of permafrost literature comes from the science departments concerned with surficial processes (e.g. geomorphology, hydrology, agriculture, etc) and from engineering concerns, such as foundation of constructions and pipeline design. This focus within the permafrost research inevitably yields a biased but also an abundant amount of information on localised surficial processes and a limited amount on regional and deep permafrost characteristics. Possible conclusions are that there is

  6. Surface and subsurface conditions in permafrost areas - a literature review

    Energy Technology Data Exchange (ETDEWEB)

    Vidstrand, Patrik [Bergab, Goeteborg (Sweden)

    2003-02-01

    This report contains a summary of some of the information within existing technical and scientific literature on permafrost. Permafrost is viewed as one of the future climate driven process domains that may exist in Scandinavia, and that may give rise to significantly different surface and subsurface conditions than the present. Except for changes in the biosphere, permafrost may impact hydraulic, mechanical, and chemical subsurface processes and conditions. Permafrost and its influences on the subsurface conditions are thus of interest for the performance and safety assessments of deep geological waste repositories. The definition of permafrost is 'ground that stays at or below 0 deg C for at least two consecutive years'. Permafrost will effect the geological subsurface to some depth. How deep the permafrost may grow is a function of the heat balance, thermal conditions at the surface and within the ground, and the geothermal heat flux from the Earth's inner parts. The main chapters of the report summaries the knowledge on permafrost evolution, occurrence and distribution, and extracts information concerning hydrology and mechanical and chemical impacts due to permafrost related conditions. The results of a literature review are always dependent on the available literature. Concerning permafrost there is some literature available from investigations in the field of long-term repositories and some from mining industries. However, reports of these investigations are few and the bulk of permafrost literature comes from the science departments concerned with surficial processes (e.g. geomorphology, hydrology, agriculture, etc) and from engineering concerns, such as foundation of constructions and pipeline design. This focus within the permafrost research inevitably yields a biased but also an abundant amount of information on localised surficial processes and a limited amount on regional and deep permafrost characteristics. Possible conclusions are that

  7. Density and Stability of Soil Organic Carbon beneath Impervious Surfaces in Urban Areas

    OpenAIRE

    Wei, Zongqiang; WU, SHAOHUA; Yan, Xiao; Zhou, Shenglu

    2014-01-01

    Installation of impervious surfaces in urban areas has attracted increasing attention due to its potential hazard to urban ecosystems. Urban soils are suggested to have robust carbon (C) sequestration capacity; however, the C stocks and dynamics in the soils covered by impervious surfaces that dominate urban areas are still not well characterized. We compared soil organic C (SOC) densities and their stabilities under impervious surface, determined by a 28-d incubation experiment, with those i...

  8. Contact Area and Temperature of Same-Parameter Fractal Surfaces in Sliding Process

    Directory of Open Access Journals (Sweden)

    Bingbing Liu

    2015-01-01

    Full Text Available To evaluate the ability of fractal parameters for characterizing tribological properties of surfaces, some stable fractal surfaces, which possess the same fractal dimension, scale factor and root-mean-square deviation of surface topography, were synthesized, and then simulated using finite element analysis to calculate the maximum temperature and contact area during sliding process. It was found that for same-parameter fractal surfaces the maximum temperature and contact area fluctuated dramatically. Thus, the tribological properties of surfaces can not be characterized by some simple parameters.

  9. High Surface Area Tungsten Carbides: Synthesis, Characterization and Catalytic Activity towards the Hydrogen Evolution Reaction in Phosphoric Acid at Elevated Temperatures

    DEFF Research Database (Denmark)

    Tomás García, Antonio Luis; Li, Qingfeng; Jensen, Jens Oluf;

    2014-01-01

    nitride route and with carbon black as template, the obtained tungsten carbide samples had higher BET area. In 100% H3PO4 at temperatures up to 185°C, the carbide powders showed superior activity towards the hydrogen evolution reaction. A deviation was found in the correlation between the BET area and...... catalytic activity; this was attributed to the presence of excess amorphous carbon in the carbide powder. TEM imaging and TGA-DTA results revealed a better correlation of the activity with the carbide particle size.......Tungsten carbide powders were synthesized as a potential electrocatalyst for the hydrogen evolution reaction in phosphoric acid at elevated temperatures. With ammonium metatungstate as the precursor, two synthetic routes with and without carbon templates were investigated. Through the intermediate...

  10. 30 CFR 941.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 941.761 Section 941.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE SOUTH DAKOTA § 941.761 Areas designated unsuitable for surface coal mining by act...

  11. 30 CFR 921.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by Act of Congress. 921.761 Section 921.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MASSACHUSETTS § 921.761 Areas designated unsuitable for surface coal mining by Act...

  12. 30 CFR 922.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 922.761 Section 922.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MICHIGAN § 922.761 Areas designated unsuitable for surface coal mining by act...

  13. 30 CFR 905.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 905.761 Section 905.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE CALIFORNIA § 905.761 Areas designated unsuitable for surface coal mining by act...

  14. 30 CFR 933.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by Act of Congress. 933.761 Section 933.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NORTH CAROLINA § 933.761 Areas designated unsuitable for surface coal mining by Act...

  15. 30 CFR 942.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 942.761 Section 942.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE TENNESSEE § 942.761 Areas designated unsuitable for surface coal mining by act...

  16. 30 CFR 903.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 903.761 Section 903.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE ARIZONA § 903.761 Areas designated unsuitable for surface coal mining by act...

  17. 30 CFR 912.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 912.761 Section 912.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE IDAHO § 912.761 Areas designated unsuitable for surface coal mining by act of...

  18. 30 CFR 942.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 942.762 Section 942.762 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS... mining operations. (a) Part 762 of this chapter, Criteria for Designating Areas as Unsuitable for...

  19. 30 CFR 939.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by Act of Congress. 939.761 Section 939.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE RHODE ISLAND § 939.761 Areas designated unsuitable for surface coal mining by Act...

  20. 30 CFR 910.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by Act of Congress. 910.761 Section 910.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE GEORGIA § 910.761 Areas designated unsuitable for surface coal mining by Act...

  1. 30 CFR 937.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by Act of Congress. 937.761 Section 937.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OREGON § 937.761 Areas designated unsuitable for surface coal mining by Act of...

  2. 30 CFR 947.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... mining by act of Congress. 947.761 Section 947.761 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE WASHINGTON § 947.761 Areas designated unsuitable for surface coal mining by act...

  3. 30 CFR 912.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 912.764 Section 912.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE IDAHO § 912.764...

  4. 30 CFR 933.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 933.764 Section 933.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE NORTH CAROLINA §...

  5. 30 CFR 939.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 939.764 Section 939.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE RHODE ISLAND §...

  6. 30 CFR 941.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 941.764 Section 941.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE SOUTH DAKOTA §...

  7. 30 CFR 910.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 910.764 Section 910.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE GEORGIA § 910.764...

  8. 30 CFR 937.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 937.764 Section 937.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OREGON § 937.764...

  9. 30 CFR 903.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 903.764 Section 903.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE ARIZONA § 903.764...

  10. 30 CFR 905.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 905.764 Section 905.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE CALIFORNIA §...

  11. 30 CFR 922.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 922.764 Section 922.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MICHIGAN §...

  12. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE TENNESSEE §...

  13. 30 CFR 921.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 921.764 Section 921.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MASSACHUSETTS §...

  14. 30 CFR 947.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Process for designating areas unsuitable for surface coal mining operations. 947.764 Section 947.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE WASHINGTON §...

  15. Three-year changes of surface albedo of degraded grassland and cropland surfaces in a semiarid area

    Institute of Scientific and Technical Information of China (English)

    LIU HuiZhi; TU Gang; DONG WenJie

    2008-01-01

    Diurnal, seasonal and interannual variations of surface albedo of degraded grassland and cropland surfaces at a semiarid area of Tognyu have been investigated based on the continuous three years observational data from 2003 to 2005. The changes of surface albedo with solar elevation angle and soil moisture have been discussed also. It has been found that surface albedo has almost the same diurnal and seasonal variations on degraded grassland and cropland surfaces in the semiarid area, while sur-face albedo is large in winter and small in summer. The diurnal variation of the surface albedo has re-lationship with the weather condition. The diurnal cycle of the surface albedo likes the "U" shape curve in sunny day, while it is low-high after the rain, and high-low after the snow. The surface albedo has large variation in cloudy day, while it has no any variation in overcast day. The large difference of the surface albedo can be 0.04 in winter between two land surfaces, because the snow has large effects on the surface albedo in winter. The rainfall is an important factor in summer on the surface albedo, while the difference of the surface albedo is 0.01 only between two land surfaces. The differences of the surface aibedo can also be 0.04 in autumn due to vegetation growing. The seasonal-average surface albeo from 2003-2005 is 0.25, 0.22, 0.24, 0.32 respectively in spring, summer, autumn and winter on the degraded grassland surface, while it is 0.25, 0.21,0.22, 0.33 respectively in spring, summer, autumn and winter on the cropland surface. The surface albedo becomes smaller with the increase of solar elevation angle. When the solar elevation angle is greater than 40°, the surface albedo changes very little and tends to be a constant. The surface albedo has negative exponent functions with soil moisture in the growing season.

  16. Surface and groundwater Nitrate distribution in the area of Vicenza

    International Nuclear Information System (INIS)

    Public aqueducts in the Province of Vicenza (Italy) are supplied entirely by various kinds of water sources: the sub river bed strata of the mountain valleys, water-bearing aquifers of the high plan, pressurized water-bearing aquifers of the middle plain, karstic reservoirs of the mountain massifs and local springs. Progressive increase in nitrate concentration has long been detected in the underground water of many parts of the Vicenza region. The nitrates originate from various sources: human waste, industrial dumping (e.g. the tanning industry) and the use of animal and chemical fertilizers. Nitrate distribution was studied in all wells used for extracting underground water including source waters which replenishing underground aquifers. During the study period ('91-'95), water courses in the recharge areas were found to have nitrate concentrations ranging between 2.0 and 42.0 mg/l. These values remained substantially stable in time. Underground aquifers showed stable nitrate concentration between 5.0 mg/l (mountain karstic aquifers; sub-river bed strata of valley bottom) and 44.0 mg/l (water bearing strata of the high plain of Astico and Brenta rivers). The pressurized flooding aquifers of the middle plain have lower concentrations (6.0-21.0 mg/l) but tend to increase by about 0.5 mg/l per year

  17. Perceived Social Impacts of Legalized Betting: The Case of Famagusta, TRNC

    OpenAIRE

    Momodu, Herschell Shaka

    2014-01-01

    ABSTRACT: Over time, the features of gaming in TRNC has been altering, influenced mostly by the establishment of the gaming, but in addition to the growing accessibility of other types of gaming like widespread sport-betting and online betting. Even as there is mounting attention on the perceived social impacts of these new types of gaming on TRNC residents. The scale of betting have been on the rise after betting in Turkey was banned in 1997 and Turkish betting operators moved their activiti...

  18. A program to compute the area of an irregular polygon on a spheroidal surface

    Digital Repository Service at National Institute of Oceanography (India)

    Sivakholundu, K.M.; Prabaharan, N.

    - ticularly if the area is large and in the form of an irregular polygon. The area computation of a polygon on a spheroi- dal surface is complicated due to the following fac- tors: (a) The convergence of meridians reduces the area enclosed by a unit latitude... render the computation of area on the spheroidal surface amenable only to some form of integration along the latitude. Analytical solutions are complicated and may not be possible for all shapes of an area. On the other hand the averaging of the scale...

  19. Measuring and comparing brain cortical surface area and other areal quantities.

    Science.gov (United States)

    Winkler, Anderson M; Sabuncu, Mert R; Yeo, B T Thomas; Fischl, Bruce; Greve, Douglas N; Kochunov, Peter; Nichols, Thomas E; Blangero, John; Glahn, David C

    2012-07-16

    Structural analysis of MRI data on the cortical surface usually focuses on cortical thickness. Cortical surface area, when considered, has been measured only over gross regions or approached indirectly via comparisons with a standard brain. Here we demonstrate that direct measurement and comparison of the surface area of the cerebral cortex at a fine scale is possible using mass conservative interpolation methods. We present a framework for analyses of the cortical surface area, as well as for any other measurement distributed across the cortex that is areal by nature. The method consists of the construction of a mesh representation of the cortex, registration to a common coordinate system and, crucially, interpolation using a pycnophylactic method. Statistical analysis of surface area is done with power-transformed data to address lognormality, and inference is done with permutation methods. We introduce the concept of facewise analysis, discuss its interpretation and potential applications. PMID:22446492

  20. Tuneable ultra high specific surface area Mg/Al-CO3 layered double hydroxides.

    Science.gov (United States)

    Chen, Chunping; Wangriya, Aunchana; Buffet, Jean-Charles; O'Hare, Dermot

    2015-10-01

    We report the synthesis of tuneable ultra high specific surface area Aqueous Miscible Organic solvent-Layered Double Hydroxides (AMO-LDHs). We have investigated the effects of different solvent dispersion volumes, dispersion times and the number of re-dispersion cycles specific surface area of AMO-LDHs. In particular, the effects of acetone dispersion on two different morphology AMO-LDHs (Mg3Al-CO3 AMO-LDH flowers and Mg3Al-CO3 AMO-LDH plates) was investigated. It was found that the amount of acetone used in the dispersion step process can significantly affect the specific surface area of Mg3Al-CO3 AMO-LDH flowers while the dispersion time in acetone is critical factor to obtain high specific surface area Mg3Al-CO3 AMO-LDH plates. Optimisation of the acetone washing steps enables Mg3Al-CO3 AMO-LDH to have high specific surface area up to 365 m(2) g(-1) for LDH flowers and 263 m(2) g(-1) for LDH plates. In addition, spray drying was found to be an effective and practical drying method to increase the specific surface area by a factor of 1.75. Our findings now form the basis of an effective general strategy to obtain ultrahigh specific surface area LDHs. PMID:26308729

  1. Research on fiber-based portable large area surface contamination monitor

    International Nuclear Information System (INIS)

    Large area portable surface contamination monitor is suitable searching the hot point, especially in the situations of large contamination area such as work site radioactive monitoring, nuclear facility decommissioning or nuclear emergency response. This paper focus on beta radioactive surface contamination. Through researching upon the detector which is made of large area plastic scintillation coupled with fibers, the first large area plastic scintillation surface contamination monitor was established. The effective area of detector reaches 1200 cm2. The verifying experiments indicates that the detection efficiency to 90Sr-90Y plate source comes to 7%. The results show this kind of detector is competent for beta radioactive surface contamination. This work laid a foundation for research and development of the relative instrument. (authors)

  2. Estimating the surface area of non-convex particles from central planar sections

    DEFF Research Database (Denmark)

    Thórisdóttir, Ólöf; H.Rafati, Ali; Kiderlen, Markus

    this section plane a modification of the area tangent count method is used. The Morse type estimator generalizes Cruz-Orive's pivotal estimator for convex objects to non-convex objects. The advantages of the Morse type estimator over existing local surface area estimators are illustrated in a......In this paper, we present a new surface area estimator in local stereology. This new estimator is called the 'Morse type surface area estimator' and is obtained using a two-stage sampling procedure. First a plane section through a fixed reference point of a three-dimensional structure is taken. In...... simulation study. The Morse type estimator is well suited for computer assisted confocal microscopy and we demonstrate its practicability in a biological application: the surface area estimation of the nuclei of giant-cell glioblastoma from microscopy images. We also present an interactive software that...

  3. Flower-like nanostructure MNb2O6 (M = Mn, Zn) with high surface area: Hydrothermal synthesis and enhanced photocatalytic performance

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • MNb2O6 was prepared by a mild two-step hydrothermal method. • Their flower-like nanostructure morphology was studied by SEM and TEM. • High BET surface areas for MnNb2O6 (∼50 m2/g) and ZnNb2O6 (∼100 m2/g). • Band gap energies were estimated by UV–vis diffuse reflectance spectra. • Photocatalytic activities were evaluated under UV-light irradiation. - Abstract: Nano-scaled MNb2O6 (M = Mn, Zn) was successfully synthesized via a two-step hydrothermal method. It is important to control the exact pH of the reaction solution in order to obtain pure products. The as-prepared samples both crystallize in the columbite structure. Interestingly, the products possess a flower-like morphology in a pseudo-six-fold symmetry, which is in fact arrayed by two-dimensional nanosheets. Their surface areas (51 m2/g for MnNb2O6 and 103 m2/g for ZnNb2O6) are about 25–50 times of those prepared by solid state reaction. UV–vis diffuse reflectance spectra show the nano-scaled sample has a stronger absorption and a narrower band gap than its bulk form. The estimated band gap energies are 2.70 eV (MnNb2O6) and 3.77 eV (ZnNb2O6), respectively. The nano-scaled ZnNb2O6 exhibits a double enhancement of photocatalytic activity in the decolorization of methylene blue than bulk ZnNb2O6

  4. Assessment of heavy metal levels in surface sediments of estuaries and adjacent coastal areas in China

    Science.gov (United States)

    Liu, Xianbin; Li, Deliang; Song, Guisheng

    2016-05-01

    This article investigates the variations of contamination levels of heavy metals such as copper, lead, chromium, cadmium, zinc, arsenic, and mercury over time in surface sediments of the Changjiang River Estuary (CRE), Yellow River Estuary (YRE), Pearl River Estuary (PRE), and their adjacent coastal areas in China. The contamination factor (CF), pollution load index (PLI), and geoaccumulation index (I geo) are used to evaluate the quality of the surface sediments in the study areas. The results showed that the CRE, YRE, and their adjacent coastal areas were at a low risk of contamination in terms of heavy metals, while the PRE and its adjacent coastal area were at a moderate level. By comparison, the concentrations of heavy metals in the surface sediments of the YRE and its adjacent coastal area were relatively lower than those in the CRE, PRE, and their adjacent coastal areas.

  5. High Surface Area of Nano Pores Activated Carbon Derived From Agriculture Waste

    International Nuclear Information System (INIS)

    In this study, the high surface area of nano pores activated carbon rice husk originated from local biomass was investigated. The comparison in terms of surface area, porosity and behavior in electrochemical analysis with commercial activated carbon was studied in details. The nano pores activated carbon rice husk was synthesis using consecutive of carbonization and activation under purified nitrogen and carbon dioxide purge. Interestingly, the surface area and capacity of the nano pores activated carbon rice indicated higher in comparison to commercial activated carbon. This indicated that the nano pores activated carbon has potential to be developed further as an alternative material in reducing suspension on commercial activated carbon. (author)

  6. PyBetVH: A Python tool for probabilistic volcanic hazard assessment and for generation of Bayesian hazard curves and maps

    Science.gov (United States)

    Tonini, Roberto; Sandri, Laura; Anne Thompson, Mary

    2015-06-01

    PyBetVH is a completely new, free, open-source and cross-platform software implementation of the Bayesian Event Tree for Volcanic Hazard (BET_VH), a tool for estimating the probability of any magmatic hazardous phenomenon occurring in a selected time frame, accounting for all the uncertainties. New capabilities of this implementation include the ability to calculate hazard curves which describe the distribution of the exceedance probability as a function of intensity (e.g., tephra load) on a grid of points covering the target area. The computed hazard curves are (i) absolute (accounting for the probability of eruption in a given time frame, and for all the possible vent locations and eruptive sizes) and (ii) Bayesian (computed at different percentiles, in order to quantify the epistemic uncertainty). Such curves allow representation of the full information contained in the probabilistic volcanic hazard assessment (PVHA) and are well suited to become a main input to quantitative risk analyses. PyBetVH allows for interactive visualization of both the computed hazard curves, and the corresponding Bayesian hazard/probability maps. PyBetVH is designed to minimize the efforts of end users, making PVHA results accessible to people who may be less experienced in probabilistic methodologies, e.g. decision makers. The broad compatibility of Python language has also allowed PyBetVH to be installed on the VHub cyber-infrastructure, where it can be run online or downloaded at no cost. PyBetVH can be used to assess any type of magmatic hazard from any volcano. Here we illustrate how to perform a PVHA through PyBetVH using the example of analyzing tephra fallout from the Okataina Volcanic Centre (OVC), New Zealand, and highlight the range of outputs that the tool can generate.

  7. Stability estimation of a large-sized pool boiling superconductor. Dependence on surface orientation and area fraction of surface treatment

    International Nuclear Information System (INIS)

    For the purpose of the stability analysis of a pool boiling superconductor, many studies on the heat transfer of LHe have been conducted. There are a number of variables that affect heat transfer. It is well-known that to variables are surface orientation and surface treatment. Surface orientation of a superconductor is varied by magnet winding. The change is associated with the variation of gravitational force on the surface, thus causing heat transfer characteristics to change. Usually, the surface of a superconductor is treated to improve heat-transfer characteristics; for example, oxidation. During the winding process, the winding machine may strip off the treatment at some locations. The resulting damage may change the heat-transfer characteristics and degrade the stability of the superconducting magnet. In this study, the heat transfer of polished Cu, oxidized Cu and partially oxidized surfaces were measured as a function of orientation. The critical and minimum heat fluxes depend on the area fraction of oxidation. The calculation method for the heat flux of a partially oxidized surface was established. Heat-transfer measurements of a prototype superconductor with polished surfaces were also conducted to change the surface orientation. The heat-transfer characteristics with the prototype superconductor were degraded as compared with those of the Cu surface. It became clear that heat transfer for a stability analysis must be measured using a prototype superconductor. Next, the recovery current for a large-sized pool boiling superconductor, which is a helical coil superconductor, was calculated according to the experimental results of heat transfer. The dependence of the recovery current on surface orientation and the area fraction of surface treatment was estimated. The calculated results were compared with the measured recovery currents of the short sample. The calculated recovery current agreed well with the experimental result. (author)

  8. Identification of a novel series of BET family bromodomain inhibitors: binding mode and profile of I-BET151 (GSK1210151A).

    Science.gov (United States)

    Seal, Jonathan; Lamotte, Yann; Donche, Frédéric; Bouillot, Anne; Mirguet, Olivier; Gellibert, Françoise; Nicodeme, Edwige; Krysa, Gael; Kirilovsky, Jorge; Beinke, Soren; McCleary, Scott; Rioja, Inma; Bamborough, Paul; Chung, Chun-Wa; Gordon, Laurie; Lewis, Toni; Walker, Ann L; Cutler, Leanne; Lugo, David; Wilson, David M; Witherington, Jason; Lee, Kevin; Prinjha, Rab K

    2012-04-15

    A novel series of quinoline isoxazole BET family bromodomain inhibitors are discussed. Crystallography is used to illustrate binding modes and rationalize their SAR. One member, I-BET151 (GSK1210151A), shows good oral bioavailability in both the rat and minipig as well as demonstrating efficient suppression of bacterial induced inflammation and sepsis in a murine in vivo endotoxaemia model. PMID:22437115

  9. Effects of area and radius of curvature of downward-facing curved surfaces on pool boiling

    International Nuclear Information System (INIS)

    Quenching experiments were performed to investigate the effects of surface area and radius of curvature on pool boiling from downward-facing, curved copper surfaces in saturated water. The maximum heat flux (qMHF) was highest at the lowermost position and decreased with increasing local inclination (or elevation) on the surface. A higher vapor release angle reduced vapor accumulation on the boiling surface, which enhanced surface coolability and shortened the quenching time. The surface area, however, insignificantly affected the local values of qMHF. Transient pool boiling from downward-facing convex surfaces in water is of interest in many applications. One example is in nuclear reactor safety for assessing the coolability of the lower head of the reactor pressure vessel, following a core meltdown accident

  10. Relationship between Mineral Soil Surface Area and the Biological Degradation of Biosolids Added to Soil

    Directory of Open Access Journals (Sweden)

    Dongqi Wen

    2015-12-01

    Full Text Available Geochemical and biological processes that operate in the soil matrix and on the soil surface are important to the degradation of biosolids in soil. Due to the large surface area of soils it is assumed that the microbial ecology is associated with mineral soil surface area. The total mineral surface areas were determined for soils from eight different fields selected from a long term study (1972–2006 of annual biosolids application to 41 fields in central Illinois varying in size from 3.6 to 66 ha. The surface areas for the soils varied from 1 to 9 m2/g of soil. The biological degradation rates for the eight soils were determined using a biological degradation rate model (DRM and varied from 0.02 to 0.20/year−1. Regression analysis revealed that the degradation rate was positively associated with mineral soil surface area (1 m2/g produces 0.018 year−1 increase in the degradation rate. The annual soil sequestration rate was calculated to increase from 1% to 6% when the soil total surface area increased from 1 to 9 m2/g of soil. Therefore, land application of biosolids is an effective way to enhance carbon sequestration in soils and reduce greenhouse gas emissions.

  11. Thermal exchanges in the B.E.T. method (1960)

    International Nuclear Information System (INIS)

    Studies of textural properties are useful both in powder metallurgy and in heterogeneous kinetics and at a time when use of the B.E.T. method is becoming more widespread it seems desirable to point out a limitation to the exactness of the absolute measurements: it is due to the uncertainty concerning the exact temperature of the powdered solid. One assumes in general that this temperature is the same as that of the liquefied gas around the sample. Several cases have been studied and this assumption has been found to be incorrect; it is thus necessary to introduce into the method another experimental variable: the exact temperature of the adsorbent. (author)

  12. Ion exchange capacities and surface areas of some major components and common fracture filling materials of igneous rocks

    International Nuclear Information System (INIS)

    Surface/mass ratios have been determined by the ethylene glycol method and the BET-method, and an- and cation exchange capacities vs pH have been measured by an isotopic dilution technique for some 30-35 pure minerals. These minerals, which are representative of major components and common accessory minerals, including fracture minerals, of crystalline rocks, have also been used in radionuclide sorption studies within the Swedish waste program. Generally, the anion exchange capacities are low (< 1 meq/kg) for all the minerals. The cation exchange capacities, which increase with pH, are < 1 meq/kg for the non-silicates with few exceptions, 1-10 meq/kg for most of the silicates except the phyllosilicates and ranging from 10 up to 800 meq/kg for clay minerals (e.g. montmorillonite) and some of the zeolites (e.g. stilbite). (authors)

  13. Radio ecological situation for surface pools and contiguous terrains in the affected area of Tashlykskaya GAES

    International Nuclear Information System (INIS)

    The results of a radio ecological monitoring for surface pools and contiguous terrains in the Tashlykskaya GAES's affected area obtained by State Scientific Engineering Center of Control Systems and Emergency Response during 2002-2005 are analyzed

  14. Evolution of Specific Surface Area Inside Glass Immersed in Beishan Groundwater

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    <正>The surface area of the fissure inside the glass block is an important parameter influencing the long term behavior of high-level radioactive waste glass in the aqueous media during the deep geological

  15. Predominance of Intraglomerular T-bet or GATA3 May Determine Mechanism of Transplant Rejection

    Science.gov (United States)

    Sun, Qiquan; Cheng, Dongrui; Zhang, Mingchao; He, Qunpeng; Chen, Zhaohong

    2011-01-01

    The transcription factors T-bet and GATA3 determine the differentiation of helper T cells into Th1 or Th2 cells, respectively. An altered ratio of their relative expression promotes the pathogenesis of certain immunological diseases, but whether this may also contribute to the pathogenesis of antibody-mediated rejection (ABMR) versus T cell-mediated rejection (TCMR) is unknown. Here, we characterized the intragraft expression of T-bet and GATA3 and determined the correlation of their levels with the presence of typical lesions of ABMR and TCMR. We found a predominant intraglomerular expression of T-bet in patients with ABMR, which was distinct from that in patients with TCMR. In ABMR, interstitial T-bet expression was typically located in peritubular capillaries, although the overall quantity of interstitial T-bet was less than that observed in TCMR. The expression of intraglomerular T-bet correlated with infiltration of CD4+ and CD8+ lymphocytes, which express T-bet, as well as intraglomerular CD68+ monocyte/macrophages, which do not express T-bet. The predominance of intraglomerular T-bet expression relative to GATA3 expression associated with poor response to treatment with bolus steroid. In summary, predominance of intraglomerular T-bet expression correlates with antibody-mediated rejection and resistance to steroid treatment. PMID:21289214

  16. Method of forming macro-structured high surface area transparent conductive oxide electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Forman, Arnold J.; Chen, Zhebo; Jaramillo, Thomas F.

    2016-01-05

    A method of forming a high surface area transparent conducting electrode is provided that includes depositing a transparent conducting thin film on a conductive substrate, where the transparent conducting thin film includes transparent conductive particles and a solution-based transparent conducting adhesive layer which serves to coat and bind together the transparent conducting particles, and heat treating the transparent conducting adhesion layer on the conductive substrate, where an increased surface area transparent conducting electrode is formed.

  17. Interdependence between body surface area and ultraviolet B dose in vitamin D production

    DEFF Research Database (Denmark)

    Bogh, M K B; Schmedes, Anne; Philipsen, P A;

    2011-01-01

    Ultraviolet (UV) B radiation increases serum vitamin D level expressed as 25-hydroxyvitamin-D(3) [25(OH)D], but the relationship to body surface area and UVB dose needs investigation.......Ultraviolet (UV) B radiation increases serum vitamin D level expressed as 25-hydroxyvitamin-D(3) [25(OH)D], but the relationship to body surface area and UVB dose needs investigation....

  18. Age Differences in Prefrontal Surface Area and Thickness in Middle Aged to Older Adults

    OpenAIRE

    Dotson, Vonetta M.; Sarah M. Szymkowicz; Sozda, Christopher N.; Kirton, Joshua W.; Green, Mackenzie L.; O’Shea, Andrew; McLaren, Molly E.; Anton, Stephen D.; Manini, Todd M; Woods, Adam J.

    2016-01-01

    Age is associated with reductions in surface area and cortical thickness, particularly in prefrontal regions. There is also evidence of greater thickness in some regions at older ages. Non-linear age effects in some studies suggest that age may continue to impact brain structure in later decades of life, but relatively few studies have examined the impact of age on brain structure within middle-aged to older adults. We investigated age differences in prefrontal surface area and cortical thick...

  19. Estimation of Surface Area and Volume of a Nematode from Morphometric Data

    OpenAIRE

    Simon Brown; Kevin C. Pedley; David C. SIMCOCK

    2016-01-01

    Nematode volume and surface area are usually based on the inappropriate assumption that the animal is cylindrical. While nematodes are approximately circular in cross section, the radius varies longitudinally. We use standard morphometric data to obtain improved estimates of volume and surface area based on (i) a geometrical approach and (ii) a Bézier representation of the nematode. These new estimators require only the morphometric data available from Cobb’s ratios, but if fewer coordinates ...

  20. Models of bedrock surface and overburden thickness over Olkiluoto island and nearby sea area

    Energy Technology Data Exchange (ETDEWEB)

    Moenkkoenen, H. [WSP Finland Oy, Helsinki (Finland)

    2012-04-15

    In this report, a model of bedrock surface and a model of overburden thickness over the Olkiluoto Island and the nearby sea area are presented. Also in purpose to produce material for biosphere and radionuclide transport modelling, stratigraphy models of different sediment layers were created at two priority areas north and south of the Olkiluoto Island. The work concentrated on the collection and description of available data of bedrock surface and overburden thickness. Because the information on the bedrock surface and overburden is collected from different sources and is based on a number of types of data the quality and applicability of data sets varies. Consequently also the reliability in different parts of the models varies. Input data for the bedrock surface and overburden thickness models include 2928 single points and additional outcrops observations (611 polygons) in the modelled area. In addition, the input data include 173 seismic refraction lines (6534 points) and acousticseismic sounding lines (26655 points from which 13721 points are located in model area) in the Olkiluoto offshore area. The average elevation of bedrock surface in area is 2.1 metres above the sea level. The average thickness of overburden is 2.5 metres varying typically between 2 - 4 metres. Thickest overburden covers (approximately 16 metres) of terrestrial area are located at the western end of the Olkiluoto Island and in sea basin south of the island. (orig.)

  1. Performance modeling of a wearable brain PET (BET) camera

    Science.gov (United States)

    Schmidtlein, C. R.; Turner, J. N.; Thompson, M. O.; Mandal, K. C.; Häggström, I.; Zhang, J.; Humm, J. L.; Feiglin, D. H.; Krol, A.

    2016-03-01

    Purpose: To explore, by means of analytical and Monte Carlo modeling, performance of a novel lightweight and low-cost wearable helmet-shaped Brain PET (BET) camera based on thin-film digital Geiger Avalanche Photo Diode (dGAPD) with LSO and LaBr3 scintillators for imaging in vivo human brain processes for freely moving and acting subjects responding to various stimuli in any environment. Methods: We performed analytical and Monte Carlo modeling PET performance of a spherical cap BET device and cylindrical brain PET (CYL) device, both with 25 cm diameter and the same total mass of LSO scintillator. Total mass of LSO in both the BET and CYL systems is about 32 kg for a 25 mm thick scintillator, and 13 kg for 10 mm thick scintillator (assuming an LSO density of 7.3 g/ml). We also investigated a similar system using an LaBr3 scintillator corresponding to 22 kg and 9 kg for the 25 mm and 10 mm thick systems (assuming an LaBr3 density of 5.08 g/ml). In addition, we considered a clinical whole body (WB) LSO PET/CT scanner with 82 cm ring diameter and 15.8 cm axial length to represent a reference system. BET consisted of distributed Autonomous Detector Arrays (ADAs) integrated into Intelligent Autonomous Detector Blocks (IADBs). The ADA comprised of an array of small LYSO scintillator volumes (voxels with base a×a: 1.0 energy resolution was 10.8% and 3.3% for LSO and LaBr3 respectively and the coincidence window was set at 2 ns. The brain was simulated as a sphere of uniform F-18 activity with diameter of 10 cm embedded in a center of water sphere with diameter of 10 cm. Results: Analytical and Monte Carlo models showed similar results for lower energy window values (458 keV versus 445 keV for LSO, and 492 keV versus 485 keV for LaBr3), and for the relative performance of system sensitivity. Monte Carlo results further showed that the BET geometry had >50% better noise equivalent count (NEC) performance relative to the CYL geometry, and >1100% better performance than a WB

  2. Determination of surface-accessible acidic hydroxyls and surface area of lignin by cationic dye adsorption

    OpenAIRE

    Sipponen, Mika Henrikki; Pihlajaniemi, Ville; Littunen, Kuisma; Pastinen, Ossi; Laakso, Simo

    2014-01-01

    A new colorimetric method for determining the surface-accessible acidic lignin hydroxyl groups in lignocellulose solid fractions was developed. The method is based on selective adsorption of Azure B, a basic dye, onto acidic hydroxyl groups of lignin. Selectivity of adsorption of Azure B on lignin was demonstrated using lignin and cellulose materials as adsorbents. Adsorption isotherms of Azure B on wheat straw (WS), sugarcane bagasse (SGB), oat husk, and isolated lignin materials were determ...

  3. A mathematical analysis of an exchange-traded horse race betting fund with deterministic payoff betting strategy for institutional investment to challenge EMH

    Directory of Open Access Journals (Sweden)

    Craig George Leslie Hopf

    2015-12-01

    Full Text Available This paper’s primary alternative hypothesis is Ha: profitable exchange-traded horserace betting fund with deterministic payoff exists for acceptable institutional portfolio return—risk. The primary hypothesis challenges the semi-strong efficient market hypothesis applied to horse race wagering. An optimal deterministic betting model (DBM is derived from the existing stochastic model fundamentals, mathematical pooling principles, and new theorem. The exchange-traded betting fund (ETBF is derived from force of interest first principles. An ETBF driven by DBM processes conjointly defines the research’s betting strategy. Alpha is excess return above financial benchmark, and invokes betting strategy alpha that is composed of model alpha and fund alpha. The results and analysis from statistical testing of a global stratified data sample of three hundred galloper horse races accepted at the ninety-five percent confidence-level positive betting strategy alpha, to endorse an exchange-traded horse race betting fund with deterministic payoff into financial market.

  4. Density and stability of soil organic carbon beneath impervious surfaces in urban areas.

    Science.gov (United States)

    Wei, Zongqiang; Wu, Shaohua; Yan, Xiao; Zhou, Shenglu

    2014-01-01

    Installation of impervious surfaces in urban areas has attracted increasing attention due to its potential hazard to urban ecosystems. Urban soils are suggested to have robust carbon (C) sequestration capacity; however, the C stocks and dynamics in the soils covered by impervious surfaces that dominate urban areas are still not well characterized. We compared soil organic C (SOC) densities and their stabilities under impervious surface, determined by a 28-d incubation experiment, with those in open areas in Yixing City, China. The SOC density (0-20 cm) under impervious surfaces was, on average, 68% lower than that in open areas. Furthermore, there was a significantly (Pdensities of SOC and total nitrogen (N) in the open soils, whereas the correlation was not apparent for the impervious-covered soils, suggesting that the artificial soil sealing in urban areas decoupled the cycle of C and N. Cumulative CO2-C evolved during the 28-d incubation was lower from the impervious-covered soils than from the open soils, and agreed well with a first-order decay model (Ct = C1+C0(1-e-kt)). The model results indicated that the SOC underlying capped surfaces had weaker decomposability and lower turnover rate. Our results confirm the unique character of urban SOC, especially that beneath impervious surface, and suggest that scientific and management views on regional SOC assessment may need to consider the role of urban carbon stocks. PMID:25299685

  5. Euclidean Wilson loops and minimal area surfaces in lorentzian AdS 3

    Science.gov (United States)

    Irrgang, Andrew; Kruczenski, Martin

    2015-12-01

    The AdS/CFT correspondence relates Wilson loops in N=4 SYM theory to minimal area surfaces in AdS 5 × S 5 space. If the Wilson loop is Euclidean and confined to a plane ( t, x) then the dual surface is Euclidean and lives in Lorentzian AdS 3 ⊂ AdS 5. In this paper we study such minimal area surfaces generalizing previous results obtained in the Euclidean case. Since the surfaces we consider have the topology of a disk, the holonomy of the flat current vanishes which is equivalent to the condition that a certain boundary Schrödinger equation has all its solutions anti-periodic. If the potential for that Schrödinger equation is found then reconstructing the surface and finding the area become simpler. In particular we write a formula for the Area in terms of the Schwarzian derivative of the contour. Finally an infinite parameter family of analytical solutions using Riemann Theta functions is described. In this case, both the area and the shape of the surface are given analytically and used to check the previous results.

  6. Euclidean Wilson loops and Minimal Area Surfaces in Minkowski AdS3

    CERN Document Server

    Irrgang, Andrew

    2015-01-01

    The AdS/CFT correspondence relates Wilson loops in N=4 SYM theory to minimal area surfaces in AdS5xS5 space. If the Wilson loop is Euclidean and confined to a plane (t,x) then the dual surface is Euclidean and lives in Minkowski AdS3. In this paper we study such minimal area surfaces generalizing previous results obtained in the Euclidean case. Since the surfaces we consider have the topology of a disk, the holonomy of the flat current vanishes which is equivalent to the condition that a certain boundary Schroedinger equation has all its solutions anti-periodic. If the potential for that Schroedinger equation is found then reconstructing the surface and finding the area become simpler. In particular we write a formula for the Area in terms of the Schwarzian derivative of the contour. Finally an infinite parameter family of analytical solutions using Riemann Theta functions is described. In this case, both the area and the shape of the surface are given analytically and used to check the previous results.

  7. Sensitivity of human lung adenocarcinoma cell lines to targeted inhibition of BET epigenetic signaling proteins

    OpenAIRE

    Lockwood, William W; Zejnullahu, Kreshnik; James E Bradner; Varmus, Harold

    2012-01-01

    Bromodomain and extra terminal domain (BET) proteins function as epigenetic signaling factors that associate with acetylated histones and facilitate transcription of target genes. Inhibitors targeting the activity of BET proteins have shown potent antiproliferative effects in hematological cancers through the suppression of c-MYC and downstream target genes. However, as the epigenetic landscape of a cell varies drastically depending on lineage, transcriptional coactivators such as BETs would ...

  8. Cyclic Regulation of T-Bet and GATA-3 in Human Endometrium

    OpenAIRE

    Inman, Danielle; Kawana, Kei; Schust, Danny; Lininger, Ruth; Young, Steven

    2008-01-01

    Endometrial cytokine expression is poorly understood. T-Bet and GATA-3 regulate cytokine expression in T-lymphocytes. Previous work has demonstrated expression of T-Bet in human endometrium. Changes in human endometrial T-Bet and GATA-3 mRNA and protein expression during the normal menstrual cycle were characterized. Human endometrium from each phase of the menstrual cycle underwent real-time reverse-transcriptase polymerase chain reaction and immunohistochemistry to examine expression and lo...

  9. Estimating surface fluxes over the north Tibetan Plateau area with ASTER imagery

    Directory of Open Access Journals (Sweden)

    Weiqiang Ma

    2009-01-01

    Full Text Available Surface fluxes are important boundary conditions for climatological modeling and Asian monsoon system. The recent availability of high-resolution, multi-band imagery from the ASTER (Advanced Space-borne Thermal Emission and Reflection radiometer sensor has enabled us to estimate surface fluxes to bridge the gap between local scale flux measurements using micrometeorological instruments and regional scale land-atmosphere exchanges of water and heat fluxes that are fundamental for the understanding of the water cycle in the Asian monsoon system. A parameterization method based on ASTER data and field observations has been proposed and tested for deriving surface albedo, surface temperature, Normalized Difference Vegetation Index (NDVI, Modified Soil Adjusted Vegetation Index (MSAVI, vegetation coverage, Leaf Area Index (LAI, net radiation flux, soil heat flux, sensible heat flux and latent heat flux over heterogeneous land surface in this paper. As a case study, the methodology was applied to the experimental area of the Coordinated Enhanced Observing Period (CEOP Asia-Australia Monsoon Project (CAMP on the Tibetan Plateau (CAMP/Tibet, located at the north Tibetan Plateau. The ASTER data of 24 July 2001, 29 November 2001 and 12 March 2002 was used in this paper for the case of summer, winter and spring. To validate the proposed methodology, the ground-measured surface variables (surface albedo and surface temperature and land surface heat fluxes (net radiation flux, soil heat flux, sensible heat flux and latent heat flux were compared to the ASTER derived values. The results show that the derived surface variables and land surface heat fluxes in three different months over the study area are in good accordance with the land surface status. Also, the estimated land surface variables and land surface heat fluxes are in good accordance with ground measurements, and all their absolute percentage difference (APD is less than 10% in the validation sites

  10. Scalable syntheses of the BET bromodomain inhibitor JQ1

    Science.gov (United States)

    Syeda, Shameem Sultana; Jakkaraj, Sudhakar; Georg, Gunda I.

    2015-01-01

    We have developed methods involving the use of alternate, safer reagents for the scalable syntheses of the potent BET bromodomain inhibitor JQ1. A one-pot three step method, involving the conversion of a benzodiazepine to a thioamde using Lawesson’s reagent, followed by amidrazone formation and installation of the triazole moiety furnished JQ1. This method provides good yields and a facile purification process. For the synthesis of enantiomerically enriched (+)-JQ1, the highly toxic reagent diethyl chlorophosphate, used in a previous synthesis, was replaced with the safer reagent diphenyl chlorophosphate in the three-step one-pot triazole formation without effecting yields and enantiomeric purity of (+)-JQ1. PMID:26034331

  11. Exposure to particle number, surface area and PM concentrations in pizzerias

    Science.gov (United States)

    Buonanno, G.; Morawska, L.; Stabile, L.; Viola, A.

    2010-10-01

    The aim of this work was to quantify exposure to particles emitted by wood-fired ovens in pizzerias. Overall, 15 microenvironments were chosen and analyzed in a 14-month experimental campaign. Particle number concentration and distribution were measured simultaneously using a Condensation Particle Counter (CPC), a Scanning Mobility Particle Sizer (SMPS), an Aerodynamic Particle Sizer (APS). The surface area and mass distributions and concentrations, as well as the estimation of lung deposition surface area and PM 1 were evaluated using the SMPS-APS system with dosimetric models, by taking into account the presence of aggregates on the basis of the Idealized Aggregate (IA) theory. The fraction of inhaled particles deposited in the respiratory system and different fractions of particulate matter were also measured by means of a Nanoparticle Surface Area Monitor (NSAM) and a photometer (DustTrak DRX), respectively. In this way, supplementary data were obtained during the monitoring of trends inside the pizzerias. We found that surface area and PM 1 particle concentrations in pizzerias can be very high, especially when compared to other critical microenvironments, such as the transport hubs. During pizza cooking under normal ventilation conditions, concentrations were found up to 74, 70 and 23 times higher than background levels for number, surface area and PM 1, respectively. A key parameter is the oven shape factor, defined as the ratio between the size of the face opening in respect to the diameter of the semicircular oven door, and particular attention must also be paid to hood efficiency.

  12. Study of measurement methods of ultrafine aerosols surface-area for characterizing occupational exposure

    International Nuclear Information System (INIS)

    This work aims at improving knowledge on ultrafine aerosols surface-area measurement. Indeed, the development of nano-technologies may lead to occupational exposure to airborne nano-structured particles, which involves a new prevention issue. There is currently no consensus concerning what parameter (mass, surface-area, number) should be measured. However, surface-area could be a relevant metric, since it leads to a satisfying correlation with biological effects when nano-structured particles are inhaled. Hence, an original theoretical work was performed to position the parameter of surface-area in relation to other aerosol characteristics. To investigate measurement techniques of nano-structured aerosols surface-area, the experimental facility CAIMAN (Characterization of Instruments for the Measurement of Aerosols of Nano-particles) was designed and built. Within CAIMAN, it is possible to produce nano-structured aerosols with varying and controlled properties (size, concentration, chemical nature, morphology, state-of-charge), stable and reproducible in time. The generated aerosols were used to experimentally characterize the response of the instruments in study (NSAM and AeroTrak 9000 TSI, LQ1-DC Matter Engineering). The response functions measured with monodisperse aerosols show a good agreement with the corresponding theoretical curves in a large size range, from 15 to 520 nm. Furthermore, hypotheses have been formulated to explain the reasonable biases observed when measuring poly-disperse aerosols. (author)

  13. Scalable surface area characterization by electrokinetic analysis of complex anion adsorption.

    Science.gov (United States)

    Hanaor, Dorian A H; Ghadiri, Maliheh; Chrzanowski, Wojciech; Gan, Yixiang

    2014-12-23

    By means of the in situ electrokinetic assessment of aqueous particles in conjunction with the addition of anionic adsorbates, we develop and examine a new approach to the scalable characterization of the specific accessible surface area of particles in water. For alumina powders of differing morphology in mildly acidic aqueous suspensions, the effective surface charge was modified by carboxylate anion adsorption through the incremental addition of oxalic and citric acids. The observed zeta potential variation as a function of the proportional reagent additive was found to exhibit inverse hyperbolic sine-type behavior predicted to arise from monolayer adsorption following the Grahame-Langmuir model. Through parameter optimization by inverse problem solving, the zeta potential shift with relative adsorbate addition revealed a nearly linear correlation of a defined surface-area-dependent parameter with the conventionally measured surface area values of the powders, demonstrating that the proposed analytical framework is applicable for the in situ surface area characterization of aqueous particulate matter. The investigated methods have advantages over some conventional surface analysis techniques owing to their direct applicability in aqueous environments at ambient temperature and the ability to modify analysis scales by variation of the adsorption cross section. PMID:25495551

  14. Sea surface temperature and torrential rains in the Valencia region: modelling the role of recharge areas

    Science.gov (United States)

    Pastor, Francisco J.

    2016-04-01

    Heavy rain events are frequently recorded in the Western Mediterranean causing economic and human losses. A main factor in the development of torrential rains is ocean-atmosphere exchange of heat and moisture that can destabilize air masses travelling over the sea. The study of air mass trajectories previous to the rain event permits the identification of sea areas that could probably contribute to the development or intensification of rainfall. From a Mediterranean sea surface temperature climatology, its spatio-temporal distribution patterns have been studied showing two main distribution modes in winter and summer and transitional regimes in spring and autumn. Hence, three heavy precipitation events, for such winter and summer sea temperature regimes and for fall transition, affecting the Valencia region have been selected to study the effect of sea surface temperature in torrential rains. Simulations with perturbed sea surface temperature in different areas along the air mass path were run to compare results with unperturbed simulation. The variation of sea surface temperature in certain areas caused significant changes in model accumulated values and its spatial distribution. Therefore, the existence of areas that at a greater extent favour air-sea interaction leading to the development of torrential rainfall in the Valencia region is shown. This methodology could be extended to other Mediterranean regions to look for such potential recharge areas. The identification of sea areas that contribute to the development or intensification of heavy rain events in the Mediterranean countries could be a useful prognosis and/or monitoring tool.

  15. Highly efficient industrial large-area black silicon solar cells achieved by surface nanostructured modification

    Science.gov (United States)

    Li, Ping; Wei, Yi; Zhao, Zengchao; Tan, Xin; Bian, Jiming; Wang, Yuxuan; Lu, Chunxi; Liu, Aimin

    2015-12-01

    Traditional black silicon solar cells show relatively low efficiencies due to the high surface recombination occurring at the front surfaces. In this paper, we present a surface modification process to suppress surface recombination and fabricate highly efficient industrial black silicon solar cells. The Ag-nanoparticle-assisted etching is applied to realize front surface nanostructures on silicon wafers in order to reduce the surface reflectance. Through a further tetramethylammonium hydroxide (TMAH) treatment, the carrier recombination at and near the surface is greatly suppressed, due to a lower surface dopant concentration after the surface modification. This modified surface presents a low reflectivity in a range of 350-1100 nm. Large-area solar cells with an average conversion efficiency of 19.03% are achieved by using the TMAH treatment of 30 s. This efficiency is 0.18% higher than that of standard silicon solar cells with pyramidal surfaces, and also a remarkable improvement compared with black silicon solar cells without TMAH modifications.

  16. DMSA scan nomograms for renal length and area: Related to patient age and to body weight, height or surface area

    International Nuclear Information System (INIS)

    Aim: To create nomograms for renal size as measured from DMSA renal studies, and to test the nomograms for their ability to separate normal from abnormal kidneys. Method: Renal length was measured from posterior oblique views and renal area from posterior views. Results from 253 patients with bilateral normal kidneys were used to create nomograms for renal size relative to patient age, body height, weight or body surface area (BSA). The nomograms enclosed 95% of the normal kidneys, thus indicating the range for 95% confidence limits, and hence the specificity. Each nomogram was then tested against 46 hypertrophied kidneys and 46 damaged kidneys. Results: The results from nomograms of renal length and renal area, compared to age, body height, body weight and BSA are presented. For each nomogram, the range is presented as a fraction of the mean value, and the number of abnormal kidneys (hypertrophied or damaged) outside the normal range is presented as a percentage (indicating the sensitivity). Conclusion: Renal Area was no better than renal length for detecting abnormal kidneys. Patient age was the least useful method of normalisation. BSA normalisation produced the best results most frequently (narrower ranges and highest detection of abnormal kidneys)

  17. Microbiology of the surface water samples in the high background radiation areas of Ramsar, Iran

    International Nuclear Information System (INIS)

    Residents of high background radiation areas of Ramsar have lived in these areas for many generations and received radiation doses much higher than the dose limit recommended by ICRP for radiation workers. The radioactivity of the high background radiation areas of Ramsar is reported to be due to 226Ra and its decay products, which have been brought to the surface by the waters of hot springs. Over the past years the department has focused on different aspects of the health effects of the elevated levels of natural radiation in Ramsar. This study was aimed to perform a preliminary investigation on the bioeffects of exposure to elevated levels of natural radiation on the microbiology of surface water samples. Water samples were collected from surface water streams in Talesh Mahalleh district, Ramsar as well as a nearby area with normal levels of background radiation. Only two strains of bacteria, that is, Providencia stuartii and Shimwellia blattae, could be isolated from the water samples collected from high background radiation areas, while seven strains (Escherichia coli, Enterobacter asburiae, Klebsiella pneumoniae, Shigella dysenteriae, Buttiauxella agerstis, Tatumella punctuata and Raoultella ornithinolytica) were isolated from the water samples collected from normal background radiation areas. All the bacteria isolated from water samples of high and normal background radiation areas were sensitive to ultraviolet radiation, heat, betadine, alcohol, and deconex. Although other investigators have reported that bacteria isolated from hot springs show radioresistance, the results reported here do not reveal any adaptive response. (author)

  18. A MATHEMATICAL ANALYSIS OF THE INCLUSION OF INSTITUTIONAL BETTING FUNDS INTO STOCK MARKET: THE CASE OF TECHNICAL AND FUNDAMENTAL PAYOFF MODELS IN HORSERACE BETTING

    Directory of Open Access Journals (Sweden)

    Craig George Leslie Hopf

    2014-01-01

    Full Text Available Horserace win and place returns have yet to be considered seriously as portfolio inputs in financial trading markets. However there exist technical and fundamental stochastic models of parametric and nonparametric distribution that appear to optimize expected returns from win and place investing in the horserace wagering market. In this study, a complex number optimization technique is introduced and applied to develop a deterministic betting model that calculates actual returns from the win and place betting. Using classes of models mentioned, field win bet payoff results were generated for a sample of successive global galloper races from Australasia, Asia and the United Kingdom. It was noted double digit returns exceeding 10% were consistently achieved within minutes of horserace investing, with arbitrage opportunity locked into prerace from the deterministic model. The results from this study provide evidence for serious investigation into the inclusion and benefit of Institutional Betting Funds into the local stock market.

  19. Uncovering surface area and micropores in almond shell biochars by rainwater wash.

    Science.gov (United States)

    Thomas Klasson, K; Uchimiya, Minori; Lima, Isabel M

    2014-09-01

    Biochars have been considered for adsorption of contaminants in soil and water, as well as conditioning and improving soil quality. Pore surface area is an important property of biochar. Biochars were created from shells of two almond varieties with different ash content. The pyrolysis was performed at 650 and 800°C for 40-240min. Significant surface areas developed at the higher temperature and at pyrolysis times of 120min and longer. Washing the materials in synthetic rainwater removed ash and exposed additional surface area, particularly in small-diameter pores. When results from low-ash almond shell biochars were compared with high-ash almond shell biochars, it was found that the pore distribution was more uniform for the high-ash starting material and almost independent of pyrolysis time or washing. The result from the washing study is important as it suggested that adsorptive properties may change once biochars are exposed to rainwater. PMID:24997909

  20. High surface area electrodes by template-free self-assembled hierarchical porous gold architecture.

    Science.gov (United States)

    Morag, Ahiud; Golub, Tatiana; Becker, James; Jelinek, Raz

    2016-06-15

    The electrode active surface area is a crucial determinant in many electrochemical applications and devices. Porous metal substrates have been employed in electrode design, however construction of such materials generally involves multistep processes, generating in many instances electrodes exhibiting incomplete access to internal pore surfaces. Here we describe fabrication of electrodes comprising hierarchical, nano-to-microscale porous gold matrix, synthesized through spontaneous crystallization of gold thiocyanate in water. Cyclic voltammetry analysis revealed that the specific surface area of the conductive nanoporous Au microwires was very high and depended only upon the amount of gold used, not electrode areas or geometries. Application of the electrode in a pseudo-capacitor device is presented. PMID:27016632

  1. APPLICATION OF HIERARCHY ARTIFICIAL NEURAL NETWORK TO EVALUATE THE EXPLOITATION CONDITITONS OF SURFACE MINING AREA

    Institute of Scientific and Technical Information of China (English)

    李新春; 范力军

    1998-01-01

    It always adopts the direct hierarchy analysis to value the exploitation conditions of surface mining areas. This way has some unavoidable shortcomings because it is mainly under theaid of experts and it is affected by the subjective thinking of the experts. This paper puts forwards a new approach that divides the whole exploitation conditions into sixteen subsidiary systems and each subsidiary system forms a neural network system. The whole decision system of exploitation conditions of surface mining areas is composed of sixteen subsidiary neural network systems. Each neural network is practiced with the data of the worksite, which is reasonable and scientific. This way will be a new decision approach for exploiting the surface mining areas.

  2. Application of stereological methods to estimate post-mortem brain surface area using 3T MRI

    DEFF Research Database (Denmark)

    Furlong, Carolyn; García-Fiñana, Marta; Puddephat, Michael;

    2013-01-01

    The Cavalieri and Vertical Sections methods of design based stereology were applied in combination with 3 tesla (i.e. 3T) Magnetic Resonance Imaging (MRI) to estimate cortical and subcortical volume, area of the pial surface, area of the grey-white matter boundary, and thickness of the cerebral...... cortex. The material comprises eight human cadaveric cerebri which had been separated into sixteen cerebral hemisphere specimens prior to embedding in agar gel. The results from MRI were compared with corresponding 'gold standard' values subsequently obtained by application of the same methodology using...... physical sectioning of the specimens. 95% agreement intervals revealed poor agreement between MR imaging and physical sectioning, specially for pial surface and thickness, as well as cerebral cortex and subcortex volumes. On average, pial surface area was estimated to be almost half the extent using MRI...

  3. The first BETS radical cation salts with dicyanamide anion: Crystal growth, structure and conductivity study

    International Nuclear Information System (INIS)

    Electrochemical oxidation of bis(ethylenedithio)tetraselenafulvalene (BETS) has been investigated. Simple and complex dicyanamides of transition metals (Mn2+, Ni2+ and Fe2+) were used as electrolytes. The correlation between composition of prepared radical cation salts and metal nature in electrolytes was established. Manganese dicyanamides provide the formation of BETS salts with the {Mn[N(CN)2]3}- and [N(CN)2]-XH2O anions. When Ni- or Fe-containing electrolytes were used only metalless BETS salts, α''-BETS2[N(CN)2].2H2O (I) and θ-BETS2[N(CN)2].3.6H2O (II), formed. Structures and conducting properties of these salts were analyzed. Both salts exhibit layered structure. Conducting radical cation layers have α'' (I)- or θ-type (II). Anion sheets appear as two-dimensional polymer networks of different types. These networks are formed by [N(CN)]2- anions and water molecules interlinked by hydrogen bonds. Salt I is a semiconductor and II demonstrates resistance drop down to150 K at normal pressure and down to 72 K at ∼0.4 kbar pressure. - Graphical abstract: We studied electrochemical oxidation of BETS donor in the presence of simple and/or complex dicyanamides of transition metals (Ni, Fe, Mn) as electrolytes. New conducting salts α''-BETS2[N(CN)2].2H2O and θ-BETS2[N(CN)2].3.8H2O have been synthesized and characterized. Highlights: → We studied electrochemical oxidation of BETS donor. → Dicyanamides of transition metals (Ni, Fe, Mn) were used as electrolytes. → We found a well-reproducible synthesis of magnetic superconductor BETS2Mn[N(CN)2]3. → Two new metalless BETS salts form when Ni and Fe electrolytes were used. → Their structure and conductivity were investigated.

  4. Description of surface systems. Preliminary site description Simpevarp sub area - Version 1.2

    Energy Technology Data Exchange (ETDEWEB)

    Lindborg, Tobias (ed.)

    2005-03-01

    Swedish Nuclear Fuel and Waste Management Co is currently conducting site characterisation in the Simpevarp area. The area is divided into two subareas, the Simpevarp and the Laxemar subarea. The two subareas are surrounded by a common regional model area, the Simpevarp area. This report describes both the regional area and the subareas. This report is an interim version (model version 1.2) of the description of the surface systems at the Simpevarp area, and should be seen as a background report to the site description of the Simpevarp area, version 1.2, SKB-R--05-08. The basis for this description is quality-assured field data available in the SKB SICADA and GIS databases, together with generic data from the literature. The Surface system, here defined as everything above the bedrock, comprises a number of separate disciplines (e.g. hydrology, geology, topography, oceanography and ecology). Each discipline has developed descriptions and models for a number of properties that together represent the site description. The current methodology for developing the surface system description and the integration to ecosystem models is documented in a methodology strategy report SKB-R--03-06. The procedures and guidelines given in that report were followed in this report. Compared with version 1.1 of the surface system description SKB-R--04-25, this report presents considerable additional features, especially in the ecosystem description (Chapter 4) and in the description of the surface hydrology (Section 3.4). A first attempt has also been made to connect the flow of matter (carbon) between the different ecosystems into an overall ecosystem model at a landscape level. A summarised version of this report is also presented in SKB-R--05-08 together with geological-, hydrogeological-, transport properties-, thermal properties-, rock mechanics- and hydrogeochemical descriptions.

  5. Description of surface systems. Preliminary site description Simpevarp sub area - Version 1.2

    International Nuclear Information System (INIS)

    Swedish Nuclear Fuel and Waste Management Co is currently conducting site characterisation in the Simpevarp area. The area is divided into two subareas, the Simpevarp and the Laxemar subarea. The two subareas are surrounded by a common regional model area, the Simpevarp area. This report describes both the regional area and the subareas. This report is an interim version (model version 1.2) of the description of the surface systems at the Simpevarp area, and should be seen as a background report to the site description of the Simpevarp area, version 1.2, SKB-R--05-08. The basis for this description is quality-assured field data available in the SKB SICADA and GIS databases, together with generic data from the literature. The Surface system, here defined as everything above the bedrock, comprises a number of separate disciplines (e.g. hydrology, geology, topography, oceanography and ecology). Each discipline has developed descriptions and models for a number of properties that together represent the site description. The current methodology for developing the surface system description and the integration to ecosystem models is documented in a methodology strategy report SKB-R--03-06. The procedures and guidelines given in that report were followed in this report. Compared with version 1.1 of the surface system description SKB-R--04-25, this report presents considerable additional features, especially in the ecosystem description (Chapter 4) and in the description of the surface hydrology (Section 3.4). A first attempt has also been made to connect the flow of matter (carbon) between the different ecosystems into an overall ecosystem model at a landscape level. A summarised version of this report is also presented in SKB-R--05-08 together with geological-, hydrogeological-, transport properties-, thermal properties-, rock mechanics- and hydrogeochemical descriptions

  6. Influence of Alkali Treatment on the Surface Area of Aluminium Dross

    OpenAIRE

    Zauzi, N. S. Ahmad; M. Z. H. Zakaria; Baini, R.; Rahman, M. R.; N. Mohamed Sutan; Hamdan, S

    2016-01-01

    Aluminium dross is an industrial waste from aluminium refining industry and classified as toxic substances. However, the disposal of dross as a waste is a burden to aluminium manufacturer industries due to its negative effects to the ecosystem, surface, and ground water. Therefore the purpose of this study is to evaluate the influence of sodium hydroxide (NaOH) on the surface area and pore size of aluminium dross. There were 3 stages in the treatment activities, which were leaching, precipita...

  7. Increased gyrification, but comparable surface area in adolescents with autism spectrum disorders

    OpenAIRE

    Wallace, Gregory L.; Robustelli, Briana; Dankner, Nathan; Kenworthy, Lauren; GIEDD, JAY N.; Martin, Alex

    2013-01-01

    Autism spectrum disorders are associated with atypically excessive early brain growth. Recent studies suggest that later cortical development, specifically cortical thickness, during adolescence and young adulthood is also aberrant. Nevertheless, previous studies of other surface-based metrics (e.g. surface area and gyrification) at high-resolution in autism spectrum disorders are limited. Forty-one males with autism spectrum disorders and 39 typically developing males matched on age (mean ∼1...

  8. Changes in surface area and concentrations of semivolatile organic contaminants in aging snow.

    Science.gov (United States)

    Burniston, Debbie A; Strachan, William J M; Hoff, John T; Wania, Frank

    2007-07-15

    During the winter of 1999/2000 five snowpacks at Turkey Lake Watershed east of Lake Superior were sampled immediately after falling and again after several days of aging for the analysis of specific snow surface area and the concentrations of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). The snow surface could be determined with a relative coefficient of variation of 6% using frontal chromatography, measuring the retention of ethyl acetate, a substance with known adsorption coefficient on the ice surface. The snow surface area of fresh snow varied from 1000 to 1330 cm2/g and was higher for snow falling during colder days. The aged snow samples had consistently lower surface areas ranging from 520 to 780 cm2/g, corresponding to an average loss of half of the initial surface area during aging. The rate of loss of surface area was faster at higher temperatures. Dieldrin, alpha-HCH, and gamma-HCH were the most abundant OCPs in snowmelt water, but endosulfan, chlordane-related substances, heptachlor epoxide, pp'-DDT, pp'-DDE, and chlorinated benzenes were also consistently present. Three midwinter snowpacks that aged during relatively cold temperatures generally experienced a loss of PCBs and OCPs that was of the same order of magnitude as the observed loss of snow surface area. However, no relationship between the extent of loss and the strength of a contaminants' sorption to snow was apparent. Few significant changes in snowpack concentrations of OCPs and PCBs were observed in a snowpack that fell at relatively high temperatures and aged under colder conditions. Concentrations of OCPs and PCBs increased in a late-winter snowpack that aged while temperatures rapidly increased to above freezing. Concentrations of pp'-DDE and endosulfan-II that increased in snowpacks that saw simultaneous decreases in the levels of pp'-DDT and endosulfan-I hint at the occurrence of sunlight induced conversions in snow. While surface area decreases clearly

  9. Preparation of Zirconia-Ceria Powders with High Specific Surface Area

    Institute of Scientific and Technical Information of China (English)

    Wang Enguo; Mei Fang

    2004-01-01

    Zirconia-ceria mixed oxide powders were prepared by high temperature aging method.The effects of the temperature and the time of aging, cerium content and calcination on powder performance were studied.The result shows that high temperature aging is an efficient way of preparation of ZrO2-CeO2 mixed oxide powders with high specific surface area and good thermal stability, and that addition of a small amount of cerium to hydrous zirconia can promote the preparation of high specific surface area powders.

  10. A Template-Free, Ultra-Adsorbing, High Surface Area Carbonate Nanostructure

    OpenAIRE

    Johan Forsgren; Sara Frykstrand; Kathryn Grandfield; Albert Mihranyan; Maria Strømme

    2013-01-01

    We report the template-free, low-temperature synthesis of a stable, amorphous, and anhydrous magnesium carbonate nanostructure with pore sizes below 6 nm and a specific surface area of ∼ 800 m(2) g(-1), substantially surpassing the surface area of all previously described alkali earth metal carbonates. The moisture sorption of the novel nanostructure is featured by a unique set of properties including an adsorption capacity ∼50% larger than that of the hygroscopic zeolite-Y at low relative hu...

  11. Investigation of Aerosol Surface Area Estimation from Number and Mass Concentration Measurements: Particle Density Effect

    Science.gov (United States)

    Ku, Bon Ki; Evans, Douglas E.

    2015-01-01

    For nanoparticles with nonspherical morphologies, e.g., open agglomerates or fibrous particles, it is expected that the actual density of agglomerates may be significantly different from the bulk material density. It is further expected that using the material density may upset the relationship between surface area and mass when a method for estimating aerosol surface area from number and mass concentrations (referred to as “Maynard’s estimation method”) is used. Therefore, it is necessary to quantitatively investigate how much the Maynard’s estimation method depends on particle morphology and density. In this study, aerosol surface area estimated from number and mass concentration measurements was evaluated and compared with values from two reference methods: a method proposed by Lall and Friedlander for agglomerates and a mobility based method for compact nonspherical particles using well-defined polydisperse aerosols with known particle densities. Polydisperse silver aerosol particles were generated by an aerosol generation facility. Generated aerosols had a range of morphologies, count median diameters (CMD) between 25 and 50 nm, and geometric standard deviations (GSD) between 1.5 and 1.8. The surface area estimates from number and mass concentration measurements correlated well with the two reference values when gravimetric mass was used. The aerosol surface area estimates from the Maynard’s estimation method were comparable to the reference method for all particle morphologies within the surface area ratios of 3.31 and 0.19 for assumed GSDs 1.5 and 1.8, respectively, when the bulk material density of silver was used. The difference between the Maynard’s estimation method and surface area measured by the reference method for fractal-like agglomerates decreased from 79% to 23% when the measured effective particle density was used, while the difference for nearly spherical particles decreased from 30% to 24%. The results indicate that the use of

  12. Investigation of near-surface saline groundwaters in the area of Gorleben

    International Nuclear Information System (INIS)

    By systematic sampling with a ram well device local high salinity zones were observed in near surface groundwaters of some marsh areas in the surroundings of the Gorleben salt dome (District of Luechow-Dannenberg). Based on analyses results, a possible inflow of saline deep groundwaters into the near surface aquifer of some separate sections can be expected whereas other occured salt enrichment zones are caused by effects of agricultural use and/or evaporation. Meanwhile, a network of short groundwater observation wells was established in the areas with a possible deep-water rise to gain informations about the origin and dynamics of the salt concentration anomalies. (orig.)

  13. Estimation of Surface Area and Volume of a Nematode from Morphometric Data

    Directory of Open Access Journals (Sweden)

    Simon Brown

    2016-01-01

    Full Text Available Nematode volume and surface area are usually based on the inappropriate assumption that the animal is cylindrical. While nematodes are approximately circular in cross section, the radius varies longitudinally. We use standard morphometric data to obtain improved estimates of volume and surface area based on (i a geometrical approach and (ii a Bézier representation of the nematode. These new estimators require only the morphometric data available from Cobb’s ratios, but if fewer coordinates are available the geometric approach reduces to the standard estimates. Consequently, these new estimators are better than the standard alternatives.

  14. Hierarchical Porous and High Surface Area Tubular Carbon as Dye Adsorbent and Capacitor Electrode.

    Science.gov (United States)

    Chen, Long; Ji, Tuo; Brisbin, Logan; Zhu, Jiahua

    2015-06-10

    Hierarchically porous tubular carbon (HPTC) with large surface area of 1094 m(2)/g has been successfully synthesized by selectively removing lignin from natural wood. No templates or chemicals are involved during the process. By further KOH activation, surface area of activated HPTC reaches up to 2925 m(2)/g. These materials show unprecedented high adsorption capacity toward organic dyes (methylene blue, 838 mg/g; methyl orange, 264 mg/g) and large electrochemical capacitance of >200 F/g. The sustainable feature of the wood precursor and demonstrated superior adsorption and energy storage properties allow promising applications of the processed materials in energy and environmental related fields. PMID:25980528

  15. Observation of contact area of bubbles with heating surface in pool boiling of water under microgravity

    International Nuclear Information System (INIS)

    Burnout heat flux was measured in subcooled pool boiling of water under attached boiling bubbles on heating surface with bubble holding plate in ground experiment. A thin stainless flat plate was employed for heating surface. The experimental setup and the heating procedures were same as used in reduced gravity experiment performed by a parabolic flight of jet aircraft. Same burnout heat flux as in the reduced gravity was obtained by adjusting the clearance between the bubble holder and the heating surface. They were 100 ∝ 400 percent higher than the widely accepted existing theories. As extending heating time longer than the reduced gravity duration until burnout occurred, burnout heat flux decreased gradually and became a constant value calculated from the existing theories. In a result of observing contact area of boiling bubbles with transparent heating surface, the contact area was smaller in quick heating time than that in long time heating at same heat flux. The experimental results suggest in microgravity that liquid layer is remained between rapidly expanded bubbles and heating surface. In microgravity experiment by a drop shaft facility, contact area of bubbles with heating surface increased considerably at starting of microgravity. (orig.)

  16. Roles of surface water areas for water and solute cycle in Hanoi city, Viet Nam

    Science.gov (United States)

    Hayashi, Takeshi; Kuroda, Keisuke; Do Thuan, An; Tran Thi Viet, Nga; Takizawa, Satoshi

    2013-04-01

    Hanoi city, the capital of Viet Nam, has developed beside the Red river. Recent rapid urbanization of this city has reduced a large number of natural water areas such as lakes, ponds and canals not only in the central area but the suburban area. Contrary, the urbanization has increased artificial water areas such as pond for fish cultivation and landscaping. On the other hand, the urbanization has induced the inflow of waste water from households and various kinds of factories to these water areas because of delay of sewerage system development. Inflow of the waste water has induced eutrophication and pollution of these water areas. Also, there is a possibility of groundwater pollution by infiltration of polluted surface water. However, the role of these water areas for water cycle and solute transport is not clarified. Therefore, this study focuses on the interaction between surface water areas and groundwater in Hanoi city to evaluate appropriate land development and groundwater resource management. We are carrying out three approaches: a) understanding of geochemical characteristics of surface water and groundwater, b) monitoring of water levels of pond and groundwater, c) sampling of soil and pond sediment. Correlation between d18O and dD of precipitation (after GNIP), the Red River (after GNIR) and the water samples of this study showed that the groundwater is composed of precipitation, the Red River and surface water that has evaporation process. Contribution of the surface water with evaporation process was widely found in the study area. As for groundwater monitoring, the Holocene aquifers at two sites were in unconfined condition in dry season and the groundwater levels in the aquifer continued to increase through rainy season. The results of isotopic analysis and groundwater level monitoring showed that the surface water areas are one of the major groundwater sources. On the other hand, concentrations of dissolved Arsenic (filtered by 0.45um) in the pore

  17. Surface area of early visual cortex predicts individual speed of traveling waves during binocular rivalry.

    Science.gov (United States)

    Genç, Erhan; Bergmann, Johanna; Singer, Wolf; Kohler, Axel

    2015-06-01

    Binocular rivalry ensues when different images are presented to the 2 eyes with conscious perception alternating between the possible interpretations. For large rivalry displays, perceptual transitions are initiated at one location and spread to other parts of the visual field, a phenomenon termed "traveling wave." Previous studies investigated the underlying neural mechanisms of the traveling wave and surmised that primary visual cortex might play an important role. We used magnetic resonance imaging and behavioral measures in humans to explore how interindividual differences in observers' subjective experience of the wave are related to anatomical characteristics of cortical regions. We measured wave speed in participants and confirmed the long-term stability of the individual values. Retinotopic mapping was employed to delineate borders of visual areas V1-V3 in order to determine surface area and cortical thickness in those regions. Only the surface areas of V1 and V2, but not V3 showed a correlation with wave speed. For individuals with larger V1/V2 area, the traveling wave needed longer to spread across the same distance in visual space. Our results highlight the role of early visual areas in mediating binocular rivalry and suggest possible mechanisms for the correlation between surface area and the traveling waves. PMID:24334918

  18. Photocatalytic Activity in CH3CN Related to the Surface Properties of TiO2 Powders Prepared by Sol-Gel Method

    Directory of Open Access Journals (Sweden)

    Marta Bettoni

    2009-01-01

    Full Text Available Some TiO2 powders, prepared from titanium(IVtetraisopropoxide by the sol-gel method and thermally treated between 100 and 1000∘C, have been characterized by X-ray powder diffraction and by nitrogen adsorption and desorption at 77 K to calculate the BET-specific surface area, from which the micropore volume and the external surface area can be derived. The photocatalytic activity (ka of the above powders has been evaluated considering the TiO2-sensitized photo-oxidation of 4-methoxybenzyl alcohol in CH3CN as the test reaction. The decrease of ka have been related to the decrease of the BET surface area, the micropore volume, and the external surface area of the TiO2 powders, but a satisfactory linear correlation is observed only for the last superficial parameter.

  19. The role of body surface area in quantity discrimination in angelfish (Pterophyllum scalare).

    Science.gov (United States)

    Gómez-Laplaza, Luis M; Gerlai, Robert

    2013-01-01

    Although some fish species have been shown to be able to discriminate between two groups (shoals) of conspecifics differing in the number of members, most studies have not controlled for continuous variables that covary with number. Previously, using angelfish (Pterophyllum scalare) we started the systematic analysis of the potential influence of such continuous variables, and found that they play different roles in shoal discrimination depending on whether large (≥ 4 fish) or small (<4 fish) shoals were contrasted. Here, we examine the potential role of the overall body surface area of stimulus fish in shoal preference, a prominent variable not yet examined in angelfish. We report that both when numerically large (5 versus 10 fish) and when small (2 versus 3 fish) shoals were contrasted, angelfish were unable to discriminate the numerically different shoals as long as the surface area of the contrasted shoals was equated. Thus, we conclude that body surface may be an important continuous variable in shoal discrimination. This conclusion was further supported by the analysis of preference when shoals of the same numerical size but different body surface area were contrasted. We found subjects to spend significantly more time close to the shoals with the greater overall surface area. Last, we conducted an experiment in which we simultaneously controlled a set of continuous variables, including overall surface area, and found angelfish to use the number of shoal members as a cue only in large shoal contrasts but not in small shoal contrasts. This result suggests the potential existence of different processing systems for large and small numbers in fish. PMID:24386299

  20. The role of body surface area in quantity discrimination in angelfish (Pterophyllum scalare.

    Directory of Open Access Journals (Sweden)

    Luis M Gómez-Laplaza

    Full Text Available Although some fish species have been shown to be able to discriminate between two groups (shoals of conspecifics differing in the number of members, most studies have not controlled for continuous variables that covary with number. Previously, using angelfish (Pterophyllum scalare we started the systematic analysis of the potential influence of such continuous variables, and found that they play different roles in shoal discrimination depending on whether large (≥ 4 fish or small (<4 fish shoals were contrasted. Here, we examine the potential role of the overall body surface area of stimulus fish in shoal preference, a prominent variable not yet examined in angelfish. We report that both when numerically large (5 versus 10 fish and when small (2 versus 3 fish shoals were contrasted, angelfish were unable to discriminate the numerically different shoals as long as the surface area of the contrasted shoals was equated. Thus, we conclude that body surface may be an important continuous variable in shoal discrimination. This conclusion was further supported by the analysis of preference when shoals of the same numerical size but different body surface area were contrasted. We found subjects to spend significantly more time close to the shoals with the greater overall surface area. Last, we conducted an experiment in which we simultaneously controlled a set of continuous variables, including overall surface area, and found angelfish to use the number of shoal members as a cue only in large shoal contrasts but not in small shoal contrasts. This result suggests the potential existence of different processing systems for large and small numbers in fish.

  1. Measurement of Friction Noise Versus Contact Area of Rough Surfaces Weakly Loaded

    OpenAIRE

    Le Bot, Alain; Bou-Chakra, Elie

    2010-01-01

    This study presents an experiment to measure the dependence of friction noise versus the nominal contact area. The friction-induced vibration is generated by the sliding of two rough surfaces. The normal load is low leading to a weak contact. The normal load and the sliding velocity are maintained constant. The nominal contact area ranges over two orders of magnitude. It is found that two regimes exist. On the one hand, the vibration energy is proportional to the contact area. But on the seco...

  2. Transparent self-cleaning lubricant-infused surfaces made with large-area breath figure patterns

    Science.gov (United States)

    Zhang, Pengfei; Chen, Huawei; Zhang, Liwen; Ran, Tong; Zhang, Deyuan

    2015-11-01

    Nepenthes pitcher inspired slippery lubricant-infused porous surfaces greatly impact the understanding of liquid-repellent surfaces construction and have attracted extensive attention in recent years due to their potential applications in self-cleaning, anti-fouling, anti-icing, etc. In this work, we have successfully fabricated transparent slippery lubricant-infused surfaces based on breath figure patterns (BFPs). Large-area BFPs with interconnected pores were initially formed on the glass substrate and then a suitable lubricant was added onto the surfaces. The interconnected pores in BFPs were able to hold the lubricant liquid in place and form a stable liquid/solid composite surface capable of repelling a variety of liquids. The liquid-repellent surfaces show extremely low critical sliding angles for various liquids, thus providing the surfaces with efficient self-cleaning property. It was also found that the liquid droplets' sliding behaviors on the surfaces were significantly influenced by the tilting angle of the substrate, liquid volume, liquid chemical properties, and pore sizes of the surfaces.

  3. Bromodomain and extra-terminal (BET) family proteins: New therapeutic targets in major diseases

    Indian Academy of Sciences (India)

    Balasundaram Padmanabhan; Shruti Mathur; Manjula Ramu; Shailesh Tripathi

    2016-06-01

    The bromodomains and extra-terminal domain (BET) family proteins recognize acetylated chromatin through their bromodomains (BDs) and helps in regulating gene expression. BDs are chromatin ‘readers’; by interacting with acetylated lysines on the histone tails, they recruit chromatin-regulating proteins on the promoter region to regulate gene expression and repression. Extensive efforts have been employed by the scientific communities worldwide, to identify and develop potential inhibitors of BET family BDs to regulate protein expression by inhibiting acetylated histone (H3/H4) interactions. Several small molecule inhibitors have been reported, which not only have high affinity, but also have high specificity to BET BDs. These developments make BET family proteins to be an important therapeutic targets, for major diseases such as cancer, neurological disorders, obesity and inflammation. Here, we review and discuss the structural biology of BET family BDs and their applications in major diseases.

  4. Bayesian Ensemble Trees (BET) for Clustering and Prediction in Heterogeneous Data

    Science.gov (United States)

    Duan, Leo L.; Clancy, John P.; Szczesniak, Rhonda D.

    2016-01-01

    We propose a novel “tree-averaging” model that utilizes the ensemble of classification and regression trees (CART). Each constituent tree is estimated with a subset of similar data. We treat this grouping of subsets as Bayesian Ensemble Trees (BET) and model them as a Dirichlet process. We show that BET determines the optimal number of trees by adapting to the data heterogeneity. Compared with the other ensemble methods, BET requires much fewer trees and shows equivalent prediction accuracy using weighted averaging. Moreover, each tree in BET provides variable selection criterion and interpretation for each subset. We developed an efficient estimating procedure with improved estimation strategies in both CART and mixture models. We demonstrate these advantages of BET with simulations and illustrate the approach with a real-world data example involving regression of lung function measurements obtained from patients with cystic fibrosis. Supplemental materials are available online. PMID:27524872

  5. The major birch pollen allergen Bet v 1 induces different responses in dendritic cells of birch pollen allergic and healthy individuals.

    Directory of Open Access Journals (Sweden)

    Ursula Smole

    Full Text Available Dendritic cells play a fundamental role in shaping the immune response to allergens. The events that lead to allergic sensitization or tolerance induction during the interaction of the major birch pollen allergen Bet v 1 and dendritic cells are not very well studied. Here, we analyzed the uptake of Bet v 1 and the cross-reactive celery allergen Api g 1 by immature monocyte-derived dendritic cells (iMoDCs of allergic and normal donors. In addition, we characterized the allergen-triggered intracellular signaling and transcriptional events. Uptake kinetics, competitive binding, and internalization pathways of labeled allergens by iMoDCs were visualized by live-cell imaging. Surface-bound IgE was detected by immunofluorescence microscopy and flow cytometry. Allergen- and IgE-induced gene expression of early growth response genes and Th1 and Th2 related cytokines and chemokines were analyzed by real-time PCR. Phosporylation of signaling kinases was analyzed by Western blot. Internalization of Bet v 1 by iMoDCs of both donor groups, likely by receptor-mediated caveolar endocytosis, followed similar kinetics. Bet v 1 outcompeted Api g 1 in cell surface binding and uptake. MoDCs of allergic and healthy donors displayed surface-bound IgE and showed a pronounced upregulation of Th2 cytokine- and NFκB-dependent genes upon non-specific Fcε receptor cross-linking. In contrast to these IgE-mediated responses, Bet v 1-stimulation increased transcript levels of the Th2 cytokines IL-4 and IL-13 but not of NFκB-related genes in MoDCs of BP allergic donors. Cells of healthy donors were either unresponsive or showed elevated mRNA levels of Th1-promoting chemokines. Moreover, Bet v 1 was able to induce Erk1/2 and p38 MAPK activation in BP allergics but only a slight p38 activation in normal donors. In conclusion, our data indicate that Bet v 1 favors the activation of a Th2 program only in DCs of BP allergic individuals.

  6. Minimal area surfaces dual to Wilson loops and the Mathieu equation

    CERN Document Server

    Huang, Changyu; Kruczenski, Martin

    2016-01-01

    The AdS/CFT correspondence relates Wilson loops in N=4 SYM to minimal area surfaces in $AdS_5\\times S^5$ space. Recently, a new approach to study minimal area surfaces in $AdS_3 \\subset AdS_5$ was discussed based on a Schroedinger equation with a periodic potential determined by the Schwarzian derivative of the shape of the Wilson loop. Here we use the Mathieu equation, a standard example of a periodic potential, to obtain a class of Wilson loops such that the area of the dual minimal area surface can be computed analytically in terms of eigenvalues of such equation. As opposed to previous examples, these minimal surfaces have an umbilical point (where the principal curvatures are equal) and are invariant under $\\lambda$-deformations. In various limits they reduce to the single and multiple wound circular Wilson loop and to the regular light-like polygons studied by Alday and Maldacena. In this last limit, the periodic potential becomes a series of deep wells each related to a light-like segment. Small correc...

  7. An empirical method for estimating surface area of aggregates in hot mix asphalt

    Directory of Open Access Journals (Sweden)

    R.P. Panda

    2016-04-01

    Full Text Available Bitumen requirement in hot mix asphalt (HMA is directly dependent on the surface area of the aggregates in the mix, which in turn has effect on the asphalt film thickness and the flow characteristics. The surface area of aggregate blend in HMA is calculated using the specific surface area factors assigned to percentage passing through some specific standard sieve sizes and the imaging techniques. The first process is less capital intensive, but purely manual and labour intensive and prone to human errors. Imaging techniques though eliminating the human errors, still have limited use due to capital intensiveness and requirement of well-established laboratories with qualified technicians. Most of the developing countries like India are shortage of well-equipped laboratories and qualified technicians. To overcome these difficulties, the present mathematical model has been developed to estimate the surface area of aggregate blend of HMA from physical properties of aggregates evaluated using simple laboratory equipment. This model has been validated compared with the existing established methods of calculations and can be used as one of the tools in different developing and under developed countries for proper design of HMA.

  8. Escaping the correction for body surface area when calculating glomerular filtration rate in children

    Energy Technology Data Exchange (ETDEWEB)

    Piepsz, Amy; Tondeur, Marianne [CHU St. Pierre, Department of Radioisotopes, Brussels (Belgium); Ham, Hamphrey [University Hospital Ghent, Department of Nuclear Medicine, Ghent (Belgium)

    2008-09-15

    {sup 51}Cr ethylene diamine tetraacetic acid ({sup 51}Cr EDTA) clearance is nowadays considered as an accurate and reproducible method for measuring glomerular filtration rate (GFR) in children. Normal values in function of age, corrected for body surface area, have been recently updated. However, much criticism has been expressed about the validity of body surface area correction. The aim of the present paper was to present the normal GFR values, not corrected for body surface area, with the associated percentile curves. For that purpose, the same patients as in the previous paper were selected, namely those with no recent urinary tract infection, having a normal left to right {sup 99m}Tc MAG3 uptake ratio and a normal kidney morphology on the early parenchymal images. A single blood sample method was used for {sup 51}Cr EDTA clearance measurement. Clearance values, not corrected for body surface area, increased progressively up to the adolescence. The percentile curves were determined and allow, for a single patient, to estimate accurately the level of non-corrected clearance and the evolution with time, whatever the age. (orig.)

  9. 3D-Microalgae software used for the estimation of microalgae biovolumes and surface area

    Directory of Open Access Journals (Sweden)

    Anton M. Lyakh

    2012-03-01

    Full Text Available The main steps of using of an original software package 3D-Microalgae for constructing three-dimensional geometric models of microalgae shells and estimating of their biovolume and surface areas are described. An improved method realized in the software allows significantly increasing the accuracy of that morphometrical characteristics calculation

  10. Learning about Surface Area through a Digital Fabrication-Augmented Unit

    Science.gov (United States)

    Corum, Kimberly; Garofalo, Joe

    2016-01-01

    Surface area is consistently identified as a curriculum standard for K-12 students and it regularly appears on national and international assessments. Recently, many schools began acquiring digital fabrication and advanced manufacturing equipment. The growing use of digital fabrication in classrooms raises the question of whether or not this…

  11. Periodic Mesoporous Organosilica Nanocubes with Ultrahigh Surface Areas for Efficient CO2 Adsorption

    Science.gov (United States)

    Wei, Yong; Li, Xiaomin; Zhang, Renyuan; Liu, Yong; Wang, Wenxing; Ling, Yun; El-Toni, Ahmed Mohamed; Zhao, Dongyuan

    2016-02-01

    Ultrahigh surface area single-crystals of periodic mesoporous organosilica (PMOs) with uniform cubic or truncated-cubic morphology and organic/inorganic components homogeneously distributed over the whole frameworks have successfully been prepared by a sol-gel surfactant-templating method. By tuning the porous feature and polymerization degree, the surface areas of the obtained PMO nanocubes can reach as high as 2370 m2/g, which is the highest for silica-based mesoporous materials. The ultrahigh surface area of the obtained PMO single crystals is mainly resulted from abundant micropores in the mesoporous frameworks. Furthermore, the diameter of the nanocubes can also be well controlled from 150 to 600 nm. The materials show ultrahigh CO2 adsorption capacity (up to 1.42 mmol/g at 273 K) which is much higher than other porous silica materials and comparable to some carbonaceous materials. The adsorption of CO2 into the PMO nanocubes is mainly in physical interaction, therefore the adsorption-desorption process is highly reversible and the adsorption capacity is much dependent on the surface area of the materials. Moreover, the selectivity is also very high (~11 times to N2) towards CO2 adsorption.

  12. Periodic Mesoporous Organosilica Nanocubes with Ultrahigh Surface Areas for Efficient CO₂ Adsorption.

    Science.gov (United States)

    Wei, Yong; Li, Xiaomin; Zhang, Renyuan; Liu, Yong; Wang, Wenxing; Ling, Yun; El-Toni, Ahmed Mohamed; Zhao, Dongyuan

    2016-01-01

    Ultrahigh surface area single-crystals of periodic mesoporous organosilica (PMOs) with uniform cubic or truncated-cubic morphology and organic/inorganic components homogeneously distributed over the whole frameworks have successfully been prepared by a sol-gel surfactant-templating method. By tuning the porous feature and polymerization degree, the surface areas of the obtained PMO nanocubes can reach as high as 2370 m(2)/g, which is the highest for silica-based mesoporous materials. The ultrahigh surface area of the obtained PMO single crystals is mainly resulted from abundant micropores in the mesoporous frameworks. Furthermore, the diameter of the nanocubes can also be well controlled from 150 to 600 nm. The materials show ultrahigh CO2 adsorption capacity (up to 1.42 mmol/g at 273 K) which is much higher than other porous silica materials and comparable to some carbonaceous materials. The adsorption of CO2 into the PMO nanocubes is mainly in physical interaction, therefore the adsorption-desorption process is highly reversible and the adsorption capacity is much dependent on the surface area of the materials. Moreover, the selectivity is also very high (~11 times to N2) towards CO2 adsorption. PMID:26868049

  13. Specific surface area effect on adsorption of chlorpyrifos and TCP by soils and modeling

    Science.gov (United States)

    The adsorption of chlorpyrifos and TCP (3,5,6, trichloro-2-pyridinol) was determined in four soils (Mollisol, Inceptisol, Entisol, Alfisol) having different specific surface areas (19–84 m2/g) but rather similar organic matter content (2.4–3.5%). Adsorption isotherms were derived from batch equilibr...

  14. Preparation of MgO Catalytic Support in Shaped Mesoporous High Surface Area Form

    Czech Academy of Sciences Publication Activity Database

    Gulková, Daniela; Šolcová, Olga; Zdražil, Miroslav

    2004-01-01

    Roč. 76, 1-3 (2004), s. 137-149. ISSN 1387-1811 R&D Projects: GA AV ČR IAA4072306 Institutional research plan: CEZ:AV0Z4072921 Keywords : MgO support * sigh Surface area * texture Subject RIV: CC - Organic Chemistry Impact factor: 2.093, year: 2004

  15. Toward Understanding Whether Interactive Surface Area Could Direct Ordered Macroscopic Supramolecular Self-Assembly.

    Science.gov (United States)

    Akram, Raheel; Cheng, Mengjiao; Guo, Fengli; Iqbal, Saleem; Shi, Feng

    2016-04-19

    The mismatching phenomena are ubiquitous in complex and advanced self-assembly, such as hierarchical assembly, macroscopic supramolecular assembly, and so on. Recently, for macroscopic supramolecular assembly, the strategy of maximizing the interactive surface area was used and supposed to handle this problem; however, now there is little understanding of whether interactive surface area is the dominant factor to guide the assembly patterns. Herein by taking millimeter cylinder building blocks with different diameter/height (d/h) ratios as model systems, we have investigated the interactive-surface-area-dependent assembling behaviors in macroscopic supramolecular assembly. The results showed that the increasing d/h ratio of cylinders contributed to selectivity of face-to-face assembled pattern over face-to-side or side-to-side geometries, thus having improved the ordering degree of the assembled structures; however, the mismatching phenomena could not be totally avoided due to high colliding chances in kinetics and the thermally favorable stability of these structures. We further confirmed the above hypothesis by in situ measurements of interactive forces of building blocks with different assembled patterns. This work of macroscopic supramolecular assembly provides an in situ visible platform, which is significant to clarify the influences of interactive surface area on the assembly behaviors. PMID:27029028

  16. High surface area carbon for bifunctional air electrodes applied in zinc-air batteries

    Energy Technology Data Exchange (ETDEWEB)

    Arai, H. [on leave from NTT Laboratories (Japan); Mueller, S.; Haas, O. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Bifunctional air electrodes with high surface area carbon substrates showed low reduction overpotential, thus are promising for enhancing the energy efficiency and power capability of zinc-air batteries. The improved performance is attributed to lower overpotential due to diffusion of the reaction intermediate, namely the peroxide ion. (author) 1 fig., 2 refs.

  17. Specific surface area behavior of a dissolving population of particles. Augmenting Mercer Dissolution Theory

    International Nuclear Information System (INIS)

    Specific surface area (Sp) measurements were made on two uranium oxide aerosol materials before and after in vitro dissolution studies were performed on the materials. The results of these Sp measurements were evaluated relative to predictions made from extending Mercer dissolution theory to describe the Sp behavior of a dissolving population of particles

  18. Fabrication of nanoelectromechanical systems via the integration of high surface area glancing angle deposition thin films

    International Nuclear Information System (INIS)

    Nanoelectromechanical systems (NEMS) coated with a high surface area thin film are fabricated. Glancing angle deposition (GLAD) is used to uniformly deposit high surface area, nanostructured SiO2 films on top of released NEMS. The resonance frequencies and quality factors are measured to assess the potential of the high surface area NEMS for sensing experiments. Resonance frequencies of coated cantilevers, although reduced by mass loading, can be predicted accurately using our derived model. Compressive stress makes the resonance frequencies of coated doubly-clamped beams difficult to predict. The quality factors of the coated NEMS are reduced by one order of magnitude by a quasi-continuous layer at the base of the GLAD film, which also introduces an estimated compressive stress of 5.3–9.3 MPa. The limit of detection is demonstrated to be ∼2 pg cm−2. With this successful proof-of-concept demonstration, we anticipate the future use of these devices as high surface area gravimetric mass sensors for applications such as gas chromatography. (paper)

  19. Proportional Reasoning Ability and Concepts of Scale: Surface Area to Volume Relationships in Science

    Science.gov (United States)

    Taylor, Amy; Jones, Gail

    2009-01-01

    The "National Science Education Standards" emphasise teaching unifying concepts and processes such as basic functions of living organisms, the living environment, and scale. Scale influences science processes and phenomena across the domains. One of the big ideas of scale is that of surface area to volume. This study explored whether or not there…

  20. Determination of colloidal gold nanoparticle surface areas, concentrations, and sizes through quantitative ligand adsorption.

    Science.gov (United States)

    Gadogbe, Manuel; Ansar, Siyam M; He, Guoliang; Collier, Willard E; Rodriguez, Jose; Liu, Dong; Chu, I-Wei; Zhang, Dongmao

    2013-01-01

    Determination of the true surface areas, concentrations, and particle sizes of gold nanoparticles (AuNPs) is a challenging issue due to the nanoparticle morphological irregularity, surface roughness, and size distributions. A ligand adsorption-based technique for determining AuNP surface areas in solution is reported. Using a water-soluble, stable, and highly UV-vis active organothiol, 2-mercaptobenzimidazole (MBI), as the probe ligand, we demonstrated that the amount of ligand adsorbed is proportional to the AuNP surface area. The equivalent spherical AuNP sizes and concentrations were determined by combining the MBI adsorption measurement with Au(3+) quantification of aqua regia-digested AuNPs. The experimental results from the MBI adsorption method for a series of commercial colloidal AuNPs with nominal diameters of 10, 30, 50, and 90 nm were compared with those determined using dynamic light scattering, transmission electron microscopy, and localized surface plasmonic resonance methods. The ligand adsorption-based technique is highly reproducible and simple to implement. It only requires a UV-vis spectrophotometer for characterization of in-house-prepared AuNPs. PMID:23092965

  1. Contrasting characteristics of the surface energy balance between the urban and rural areas of Beijing

    Science.gov (United States)

    Wang, Linlin; Gao, Zhiqiu; Miao, Shiguang; Guo, Xiaofeng; Sun, Ting; Liu, Maofeng; Li, Dan

    2015-04-01

    A direct comparison of urban and rural surface energy balances, as well as a variety of other variables including incoming shortwave/longwave radiation and aerosol optical depth, is conducted for the Beijing metropolitan area. The results indicate that, overall, the urban area receives a smaller amount of incoming shortwave radiation but a larger amount of incoming longwave radiation. However, comparisons in the aerosol optical depth and cloud fraction at the two locations suggest that neither aerosol optical depth nor cloud fraction alone can explain the difference in the incoming shortwave radiation. The urban-rural differences in the incoming longwave radiation are unlikely to be caused by the presence of more abundant greenhouse gases over the urban area, as suggested by some previous studies, given that water vapor is the most dominant greenhouse gas and precipitable water is found to be less in urban areas. The higher incoming longwave radiation observed over the urban area is mostly likely due to the higher temperatures of the ambient air. The urban area is also found to always produce higher sensible heat fluxes and lower latent heat fluxes in the growing season. Furthermore, the urban area is associated with a larger amount of available energy (the sum of sensible and latent heat fluxes) than the rural area, except in May and October when evapotranspiration in the rural area significantly exceeds that in the urban area. This study provides observational evidence of urban-rural contrasts in relevant energy-balance components that plausibly arise from urban-rural differences in atmospheric and land-surface conditions.

  2. Changes in the surface area of lakes in the Gwda River basin

    Directory of Open Access Journals (Sweden)

    Katarzyna Kubiak-Wójcicka

    2015-03-01

    Full Text Available This paper presents lake surface area changes that have taken place in the Gwda River basin. The studies were conducted on the basis of the cartographic materials released since the beginning of the twentieth century until the present times. The starting point was the area of all lakes greater than 1 ha which are present on the MPHP map from 2010. The assessment of the changes in the surface area of lakes in the Gwda River basin during approximately the last 100 years was possible thanks to the use of German topographic maps, so called Messtischblatt, at a scale of 1: 25 000 released between 1919 and 1944. The area of all the studied lakes has decreased by 465.09 ha (from 12783.62 ha at the beginning of the twentieth century to 12318.53 ha at the present time. Despite the general trend of lake atrophy, in particular cases one may observe an increase in the water surface area. This is the result of hydrotechnical works leading to river and lake damming, which in turn hampers the pace of atrophy.

  3. Hydrochemistry of surface water and groundwater from a fractured carbonate aquifer in the Helwan area, Egypt

    Indian Academy of Sciences (India)

    Fathy A Abdalla; Traugott Scheytt

    2012-02-01

    Groundwater is an important water resource in the Helwan area, not only for drinking and agricultural purposes, but also because several famous mineral springs have their origin in the fractured carbonate aquifer of the region. The area is heavily populated with a high density of industrial activities which may pose a risk for groundwater and surface water resources. The groundwater and surface water quality was investigated as a basis for more future investigations. The results revealed highly variable water hydrochemistry. High values of chloride, sulphate, hardness and significant mineralization were detected under the industrial and high-density urban areas. High nitrate contents in the groundwater recorded in the southern part of the study area are probably due to irrigation and sewage infiltrations from the sewage treatment station. The presence of shale and marl intercalation within the fissured and cavernous limestone aquifer promotes the exchange reactions and dissolution processes. The groundwater type is sodium, sulphate, chloride reflecting more mineralized than surface water. The results also showed that water in the study area (except the Nile water) is unsuitable for drinking purposes, but it can be used for irrigation and industrial purposes with some restrictions.

  4. Stem diameter and bark surface area of the fluted trunk of Balanites maughamii (Balanitaceae

    Directory of Open Access Journals (Sweden)

    V. L. Williams

    2007-12-01

    Full Text Available Balanites maughamii Sprague (Balanitaceae is a woodland tree used and harvested for bark products in the traditional medicine trade o f South Africa. The tree has a distinctively fluted and buttressed stem, especially in mature individuals. This short communication quantifies the relationship between two diameter measurements D1 and D2 that respectively exclude and include the bark surface contained in the convolutions of the flutes at five height intervals up the stem to 2 m. Regressions show D1 to be an accurate predictor of D2 (r^ =0.97-0.99 over a range of tree sizes, hence obviating the necessity to measure both D1 and D2. The circumference and bark surface area on the stem was determined to estimate the quantity of bark that can potentially be harvested. At least 69% of the stem circumference and bark surface area was estimated to be contained within the convolutions of the flutes.

  5. Interrelationships among plant biomass, plant surface area and the interception of particulate deposition by grasses

    International Nuclear Information System (INIS)

    The interrelationships among plant biomass, plant surface area and interception fraction were determined for the interception by corn of 238Pu-bearing particles released to the atmosphere from the H-Area nuclear fuels chemical separations facility on the U.S. Department of Energy's Savannah River Plant in Barnwell County, South Carolina. The relationship between interception fraction and corn biomass was accurately approximated by a filtration model with an absorption coefficient of 3.60 m2 kg-1. A filtration model with an absorption coefficient of 2.91 m2 kg-1 accurately approximated the relationship between biomass and interception fraction for data compiled from the literature for a variety of grass species. A linear regression model accurately approximated the relationship between interception fraction and surface area, but was not a better predictor of interception fraction than the filtration model for biomass

  6. Comprehensive cortical thickness and surface area comparison between young Uyghur and Han Chinese cohorts.

    Science.gov (United States)

    Lu, Jun; Jiang, Chunhui; Wang, Jian; Jia, Wenxiao

    2016-10-01

    We hypothesized that the brain structural differences as discovered previously between Westerners and East Asians could also be revealed between Han Chinese and Uyghur, which were genetically related ethnic groups with distinct languages. We conducted a brain MRI structural comparison in terms of cortical thickness and surface area between 15 healthy young Uyghurs and 15 age-matched Han Chinese. Widespread regions with significantly greater cortical thickness were found in the Uyghurs, and their distribution showed strong resemblance to previous "Westerners vs. Asians" findings. While surface area analysis displayed less widespread brain differences. Notably, our detected regions with structural differences contained a large part of language-specific or at least closely language-related brain areas, which may partly be attributable to the brain plasticity respectively driven by Uyghur and Mandarin. Our findings will help to better understand the neurobiological basis of interethnic differences along with the language processing mechanisms of Han Chinese and Uyghur. PMID:27067474

  7. Regional brain differences in cortical thickness, surface area and subcortical volume in individuals with Williams syndrome.

    Directory of Open Access Journals (Sweden)

    Shashwath A Meda

    Full Text Available Williams syndrome (WS is a rare genetic neurodevelopmental disorder characterized by increased non-social anxiety, sensitivity to sounds and hypersociability. Previous studies have reported contradictory findings with regard to regional brain variation in WS, relying on only one type of morphological measure (usually volume in each study. The present study aims to contribute to this body of literature and perhaps elucidate some of these discrepancies by examining concurrent measures of cortical thickness, surface area and subcortical volume between WS subjects and typically-developing (TD controls. High resolution MRI scans were obtained on 31 WS subjects and 50 typically developing control subjects. We derived quantitative regional estimates of cortical thickness, cortical surface area, and subcortical volume using FreeSurfer software. We evaluated between-group ROI differences while controlling for total intracranial volume. In post-hoc exploratory analyses within the WS group, we tested for correlations between regional brain variation and Beck Anxiety Inventory scores. Consistent with our hypothesis, we detected complex patterns of between-group cortical variation, which included lower surface area in combination with greater thickness in the following cortical regions: post central gyrus, cuneus, lateral orbitofrontal cortex and lingual gyrus. Additional cortical regions showed between-group differences in one (but not both morphological measures. Subcortical volume was lower in the basal ganglia and the hippocampus in WS versus TD controls. Exploratory correlations revealed that anxiety scores were negatively correlated with gray matter surface area in insula, OFC, rostral middle frontal, superior temporal and lingual gyrus. Our results were consistent with previous reports showing structural alterations in regions supporting the socio-affective and visuospatial impairments in WS. However, we also were able to effectively capture novel and

  8. Geology and surface geochemistry of the Roosevelt Springs Known Geothermal Resource Area, Utah

    Energy Technology Data Exchange (ETDEWEB)

    Lovell, J.S.; Meyer, W.T.; Atkinson, D.J.

    1980-01-01

    Available data on the Roosevelt area were synthesized to determine the spatial arrangement of the rocks, and the patterns of mass and energy flow within them. The resulting model lead to a new interpretation of the geothermal system, and provided ground truth for evaluating the application of soil geochemistry to exploration for concealed geothermal fields. Preliminary geochemical studies comparing the surface microlayer to conventional soil sampling methods indicated both practical and chemical advantages for the surface microlayer technique, which was particularly evident in the case of As, Sb and Cs. Subsequent multi-element analyses of surface microlayer samples collected over an area of 100 square miles were processed to produce single element contour maps for 41 chemical parameters. Computer manipulation of the multi-element data using R-mode factor analysis provided the optimum method of interpretation of the surface microlayer data. A trace element association of As, Sb and Cs in the surface microlayer provided the best indication of the leakage of geothermal solutions to the surface, while regional mercury trends may reflect the presence of a mercury vapour anomaly above a concealed heat source.

  9. Snow specific surface area simulation using the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS

    Directory of Open Access Journals (Sweden)

    A. Roy

    2012-12-01

    Full Text Available Snow grain size is a key parameter for modeling microwave snow emission properties and the surface energy balance because of its influence on the snow albedo, thermal conductivity and diffusivity. A model of the specific surface area (SSA of snow was implemented in the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS version 3.4. This offline multilayer model (CLASS-SSA simulates the decrease of SSA based on snow age, snow temperature and the temperature gradient under dry snow conditions, whereas it considers the liquid water content for wet snow metamorphism. We compare the model with ground-based measurements from several sites (alpine, Arctic and sub-Arctic with different types of snow. The model provides simulated SSA in good agreement with measurements with an overall point-to-point comparison RMSE of 8.1 m2 kg−1, and a RMSE of 4.9 m2 kg−1 for the snowpack average SSA. The model, however, is limited under wet conditions due to the single-layer nature of the CLASS model, leading to a single liquid water content value for the whole snowpack. The SSA simulations are of great interest for satellite passive microwave brightness temperature assimilations, snow mass balance retrievals and surface energy balance calculations with associated climate feedbacks.

  10. The balloon-borne electron telescope with scintillating fibers (BETS)

    International Nuclear Information System (INIS)

    We describe a new detector system developed for high-altitude balloon flights to observe the cosmic-ray electrons above 10 GeV. The Balloon borne Electron Telescope with Scintillating (BETS) fibers instrument is an imaging calorimeter which is capable of selecting electrons against the large background of protons. The calorimeter is composed of a sandwich of scintillating optical-fiber belts and lead plates with a combination of three plastic scintillators for shower trigger. The total thickness of lead is 40 mm (∼ 7.1 r.l.) and the number of fiber belts is nine. In each belt, alternating layers are oriented in orthogonal (x and y) directions. Two sets of an intensified CCD camera are adopted for read-out of the scintillating fibers in the x and y direction, respectively. The accelerator beam tests were carried out to study the performance of detector for electrons in 1996 and for protons in 1997 at CERN-SPS. The instrument was successfully flown aboard high-altitude balloon in 1997 and 1998. It is demonstrated by the flight data that a reliable identification of the electron component has been achieved in 10-100 GeV and the energy spectrum has been obtained

  11. Betting on Illusory Patterns: Probability Matching in Habitual Gamblers.

    Science.gov (United States)

    Gaissmaier, Wolfgang; Wilke, Andreas; Scheibehenne, Benjamin; McCanney, Paige; Barrett, H Clark

    2016-03-01

    Why do people gamble? A large body of research suggests that cognitive distortions play an important role in pathological gambling. Many of these distortions are specific cases of a more general misperception of randomness, specifically of an illusory perception of patterns in random sequences. In this article, we provide further evidence for the assumption that gamblers are particularly prone to perceiving illusory patterns. In particular, we compared habitual gamblers to a matched sample of community members with regard to how much they exhibit the choice anomaly 'probability matching'. Probability matching describes the tendency to match response proportions to outcome probabilities when predicting binary outcomes. It leads to a lower expected accuracy than the maximizing strategy of predicting the most likely event on each trial. Previous research has shown that an illusory perception of patterns in random sequences fuels probability matching. So does impulsivity, which is also reported to be higher in gamblers. We therefore hypothesized that gamblers will exhibit more probability matching than non-gamblers, which was confirmed in a controlled laboratory experiment. Additionally, gamblers scored much lower than community members on the cognitive reflection task, which indicates higher impulsivity. This difference could account for the difference in probability matching between the samples. These results suggest that gamblers are more willing to bet impulsively on perceived illusory patterns. PMID:25921650

  12. The determination of specific surface of sodium polyuranates

    International Nuclear Information System (INIS)

    Three different sodium polyuranates were prepared by titration of uranyl nitrate with a sodium hydroxide solution labeled with 22Na as the radiotracer. Polyuranates whose composition was *Na2O.7,5UO3.11H2O (sample A), *Na2O.4,3 UO3.4,7H2O (sample B), and *Na2O.2UO3.4H2O (sample C) were precipitated at pH 5.6, 8.5 and 11.2, respectively. The specific surface areas of these samples were determined by the BET method using methylene blue (MB) as the adsorbate. The sodium polyuranate surfaces were saturated by sequential adsorption of MB. The adsorption data gave an S-shaped isotherm and were fitted to the BET equation. The specific surface areas calculated from the BET isotherm decreased in order A > B > C. The isotope and ion exchange reactions between the sodium polyuranates and Li+, Na+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ ions were compared before and after MB coverage. The results showed that the isotope and ion exchange fractions decrease on the covered surfaces indicating particle diffusion mechanism dominated exchange reactions

  13. Impact of industrial wastewater disposal on surface water bodies in Mostord area north Greater Cairo

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The studied area (Shoubra El-Khima, Bahteem and Mostorod) lies in the industrial area north of Greater Cairo. The area suffers from several environmental problems such as sewage and disposal of pollutants from the surrounding factories into the surface water pathways in the area. Water samples were collected seasonally from different waterways found in the area, domestic and or industrial liquid wastes from 12 discharge tubes of different factories (as a point source of pollution). Chemical characteristics of different water samples and its heavy metals content were determined using ion coupled plasma technique (ICP). Results indicate that industrial and domestic wastewater samples contain several toxic levels of tested heavy metals (Cd, Co, Pb and Ni) which have a serious impact on surface waterways in the area.Shebin El-Qanater collector drain samples exhibited the highest levels of Cd, Co, Pb and Ni compared to other tested water bodies Mostorod collector drain samples showed the highest levels of Zn and Cu. Industrial effluent samples collected from Cairo Company for Fabric industry had the highest amounts of total Zn Cu, Cd, Co and Pb, while Delta steel company discharges the highest amounts of total Fe and Mn. Al-Ahleya Plastic Company discharges the highest amounts of total-Ni. Generally, it is necessary to impose the environmental laws and its regulation regarding the industrial wastewater treatments and disposals to minimize the risk of the adverse effects of these pollutants.

  14. Perfluorinated compounds in soil, surface water, and groundwater from rural areas in eastern China.

    Science.gov (United States)

    Chen, Shu; Jiao, Xing-Chun; Gai, Nan; Li, Xiao-Jie; Wang, Xiao-Chun; Lu, Guo-Hui; Piao, Hai-Tao; Rao, Zhu; Yang, Yong-Liang

    2016-04-01

    Little research on perfluorinated compounds (PFCs) has been conducted in rural areas, although rural PFC sources are less complicated than in urban and industrial areas. To determine the levels and geographical distribution of 17 PFC compounds, samples of soil, surface water, and groundwater were collected from eight rural areas in eastern China. The total PFC concentrations (∑PFCs) in soils ranged from 0.34 to 65.8 ng/g ∑PFCs in surface waters ranged from 7.0 to 489 ng/L and ∑PFCs in groundwater ranged from 5.3 to 615 ng/L. Ratios of perfluorononanoic acid/perfluorooctanoic acid (PFNA/PFOA), perfluoro-n-butyric acid/perfluorooctanoic acid (PFBA/PFOA), and perfluoroheptanoic acid/perfluorooctanoic acid (PFHpA/PFOA) in rainwater increased due to the fluorine chemical plants in the surrounding rural and urban areas, suggesting that atmospheric precipitation may carry PFCs and their precursors from the fluorochemical industrial area to the adjacent rural areas. PMID:26745397

  15. Description of climate, surface hydrology, and near-surface hydrogeology. Preliminary site description. Forsmark area - version 1.2

    International Nuclear Information System (INIS)

    The present report is a background report describing the meteorological conditions and the modelling of surface hydrology and near-surface hydrogeology in support of the Forsmark version 1.2 SDM based on the data available in the Forsmark 1.2 ''data freeze'' (July 31, 2004). The area covered in the conceptual and descriptive modelling is characterised by a low relief and a small-scale topography. Almost the whole area is located below 20 m a s l (metres above sea level). The corrected mean annual precipitation is 600-650 mm and the mean annual evapotranspiration can be estimated to a little more than 400 mm, leaving approximately 200 mm x year-1 for runoff. Till is the dominating Quaternary deposit covering approximately 75% of the area. In most of the area, the till is sandy. Bedrock outcrops are frequent but cover only approximately 5% of the area. Direct groundwater recharge from precipitation is the dominant source of groundwater recharge. The small-scale topography implies that many local, shallow groundwater flow systems are formed in the Quaternary deposits, overlaying more large-scale flow systems associated with groundwater flows at greater depths. Groundwater level time series from wells in till and bedrock within the same areas show a considerably higher groundwater level in the till than in the bedrock. The sediment stratigraphy of lakes and wetlands is crucial for their function as discharge areas for groundwater. Comparisons between measured lake water levels and groundwater levels below and around lakes indicate that the lakes in some cases may act as sources of groundwater recharge. Specifically, observations from Lake Bolundsfjaerden and Lake Eckarfjaerden show that such conditions were at hand during the dry summer of 2003. However, whether the observed water level relations correspond to significant water fluxes depends also on the hydrogeological properties of the lake sediments and the underlying Quaternary deposits. ''Old'' water with high

  16. Reinforced Epoxy Nanocomposite Sheets Utilizing Large Interfacial Area from a High Surface Area Single-Walled Carbon Nanotube Scaffold

    Science.gov (United States)

    Kobashi, Kazufumi; Nishino, Hidekazu; Yamada, Takeo; Futaba, Don; Yumura, Motoo; Hata, Kenji

    2011-03-01

    We employed single-walled carbon nanotubes (SWNTs) with the available highest specific surface area (more than 1000 m2/g) that provided very large interfacial area for the matrix to fabricate epoxy composite sheets. Through mechanical redirection of the SWNT alignment to horizontal to create a laterally aligned scaffold sheet, into which epoxy resin was impregnated. The SWNT scaffold was engineered in structure to meet the these two nearly mutually exclusive demands, i.e. to have nanometer meso-pores (2-50 nm) to facilitate homogeneous impregnation of the epoxy resin and to have mechanical strength to tolerate the compaction forces generated during impregnation. Through this approach, a SWNT/epoxy composite sheet with a nearly ideal morphology was realized where long and aligned SWNTs were loaded at high weight fraction (33 percent) with an intertube distance approaching the radius of gyration for polymers. The resultant composite showed a Young's modulus of 15.0 GPa and a tensile strength of 104 MPa, thus achieving 5.4 and 2.1 times reinforcement as compared to the neat epoxy resin.

  17. Plaque Size Is Decreased but M1 Macrophage Polarization and Rupture Related Metalloproteinase Expression Are Maintained after Deleting T-Bet in ApoE Null Mice

    Science.gov (United States)

    Tsaousi, Aikaterini; Hayes, Elaine M.; Di Gregoli, Karina; Bond, Andrew R.; Bevan, Laura

    2016-01-01

    Background Thelper1 (Th1) lymphocytes have been previously implicated in atherosclerotic plaque growth but their role in plaque vulnerability to rupture is less clear. We investigated whether T-bet knockout that prevents Th1 lymphocyte differentiation modulates classical (M1) macrophage activation or production of matrix degrading metalloproteinases (MMPs) and their tissue inhibitors, TIMPs. Methods & Results We studied the effect of T-bet deletion in apolipoproteinE (ApoE) knockout mice fed a high fat diet (HFD) or normal chow diet (ND). Transcript levels of M1/M2 macrophage polarization markers, selected MMPs and TIMPs were measured by RT-qPCR in macrophages isolated from subcutaneous granulomas or in whole aortae. Immunohistochemistry of aortic sinus (AS) and brachiocephalic artery (BCA) plaques was conducted to quantify protein expression of the same factors. Deletion of T-bet decreased mRNA for the M1 marker NOS-2 in granuloma macrophages but levels of M2 markers (CD206, arginase-1 and Ym-1), MMPs-2, -9, -12, -13, -14 and -19 or TIMPs-1 to -3 were unchanged. No mRNA differences were observed in aortic extracts from mice fed a HFD for 12 weeks. Moreover, AS and BCA plaques were similarly sized between genotypes, and had similar areas stained for NOS-2, COX-2, MMP-12 and MMP-14 proteins. T-bet deletion increased MMP-13, MMP-14 and arginase-1 in AS plaques. After 35 weeks of ND, T-bet deletion reduced the size of AS and BCA plaques but there were no differences in the percentage areas stained for M1 or M2 markers, MMPs-12, -13, -14, or TIMP-3. Conclusions Absence of Th1 lymphocytes is associated with reduced plaque size in ApoE knockout mice fed a normal but not high fat diet. In either case, M1 macrophage polarization and expression of several MMPs related to plaque instability are either maintained or increased. PMID:26886778

  18. Plaque Size Is Decreased but M1 Macrophage Polarization and Rupture Related Metalloproteinase Expression Are Maintained after Deleting T-Bet in ApoE Null Mice.

    Directory of Open Access Journals (Sweden)

    Aikaterini Tsaousi

    Full Text Available Thelper1 (Th1 lymphocytes have been previously implicated in atherosclerotic plaque growth but their role in plaque vulnerability to rupture is less clear. We investigated whether T-bet knockout that prevents Th1 lymphocyte differentiation modulates classical (M1 macrophage activation or production of matrix degrading metalloproteinases (MMPs and their tissue inhibitors, TIMPs.We studied the effect of T-bet deletion in apolipoproteinE (ApoE knockout mice fed a high fat diet (HFD or normal chow diet (ND. Transcript levels of M1/M2 macrophage polarization markers, selected MMPs and TIMPs were measured by RT-qPCR in macrophages isolated from subcutaneous granulomas or in whole aortae. Immunohistochemistry of aortic sinus (AS and brachiocephalic artery (BCA plaques was conducted to quantify protein expression of the same factors. Deletion of T-bet decreased mRNA for the M1 marker NOS-2 in granuloma macrophages but levels of M2 markers (CD206, arginase-1 and Ym-1, MMPs-2, -9, -12, -13, -14 and -19 or TIMPs-1 to -3 were unchanged. No mRNA differences were observed in aortic extracts from mice fed a HFD for 12 weeks. Moreover, AS and BCA plaques were similarly sized between genotypes, and had similar areas stained for NOS-2, COX-2, MMP-12 and MMP-14 proteins. T-bet deletion increased MMP-13, MMP-14 and arginase-1 in AS plaques. After 35 weeks of ND, T-bet deletion reduced the size of AS and BCA plaques but there were no differences in the percentage areas stained for M1 or M2 markers, MMPs-12, -13, -14, or TIMP-3.Absence of Th1 lymphocytes is associated with reduced plaque size in ApoE knockout mice fed a normal but not high fat diet. In either case, M1 macrophage polarization and expression of several MMPs related to plaque instability are either maintained or increased.

  19. Cortical Thickness, Surface Area and Subcortical Volume Differentially Contribute to Cognitive Heterogeneity in Parkinson's Disease.

    Science.gov (United States)

    Gerrits, Niels J H M; van Loenhoud, Anita C; van den Berg, Stan F; Berendse, Henk W; Foncke, Elisabeth M J; Klein, Martin; Stoffers, Diederick; van der Werf, Ysbrand D; van den Heuvel, Odile A

    2016-01-01

    Parkinson's disease (PD) is often associated with cognitive deficits, although their severity varies considerably between patients. Recently, we used voxel-based morphometry (VBM) to show that individual differences in gray matter (GM) volume relate to cognitive heterogeneity in PD. VBM does, however, not differentiate between cortical thickness (CTh) and surface area (SA), which might be independently affected in PD. We therefore re-analyzed our cohort using the surface-based method FreeSurfer, and investigated (i) CTh, SA, and (sub)cortical GM volume differences between 93 PD patients and 45 matched controls, and (ii) the relation between these structural measures and cognitive performance on six neuropsychological tasks within the PD group. We found cortical thinning in PD patients in the left pericalcarine gyrus, extending to cuneus, precuneus and lingual areas and left inferior parietal cortex, bilateral rostral middle frontal cortex, and right cuneus, and increased cortical surface area in the left pars triangularis. Within the PD group, we found negative correlations between (i) CTh of occipital areas and performance on a verbal memory task, (ii) SA and volume of the frontal cortex and visuospatial memory performance, and, (iii) volume of the right thalamus and scores on two verbal fluency tasks. Our primary findings illustrate that i) CTh and SA are differentially affected in PD, and ii) VBM and FreeSurfer yield non-overlapping results in an identical dataset. We argue that this discrepancy is due to technical differences and the subtlety of the PD-related structural changes. PMID:26919667

  20. High surface area nanocrystalline hausmannite synthesized by a solvent-free route

    International Nuclear Information System (INIS)

    Highlights: ► High surface area Mn3O4 nanoparticles obtained by a solvent-free low temperature route. ► 3,6,9-Trioxadecanoic acid allows to obtain nanocrystalline hausmannite. ► Tape casted electrodes show up to 300 mAh g−1 capacity after more than 40 cycles at a C/3 rate. ► Upper cut off voltage strongly influences capacity retention upon cycling at high C rates. -- Abstract: Nanocrystalline high surface area Mn3O4 powder was obtained at low temperature by a solvent-free route. The precursor was a mixture of manganese (II) acetate, 3,6,9-trioxadecanoic acid (TODA) and ammonium acetate that were intimately mixed by grounding in an agate mortar. Nanocrystalline Mn3O4 was obtained by thermal treatment at 120 °C. Powder X-ray diffraction, selected area electron diffraction, high resolution transmission electron microscopy, and Fourier transformed infrared characterization confirmed the formation of the hausmannite phase. The as-prepared mesoporous material has high specific surface area (120 m2 g−1). The performances of tape casted Mn3O4 nanopowder electrodes were investigated as anode material for lithium ion batteries. High capacity values were achieved at diverse C rates. Capacity fading was found to be dependent on the upper cut off voltage, the presence of a plateau at 2.25 V vs. Li+/Li being detrimental for long term cyclability.

  1. Nanotechnological Advances in Catalytic Thin Films for Green Large-Area Surfaces

    Directory of Open Access Journals (Sweden)

    Suzan Biran Ay

    2015-01-01

    Full Text Available Large-area catalytic thin films offer great potential for green technology applications in order to save energy, combat pollution, and reduce global warming. These films, either embedded with nanoparticles, shaped with nanostructuring techniques, hybridized with other systems, or functionalized with bionanotechnological methods, can include many different surface properties including photocatalytic, antifouling, abrasion resistant and mechanically resistive, self-cleaning, antibacterial, hydrophobic, and oleophobic features. Thus, surface functionalization with such advanced structuring methods is of significance to increase the performance and wide usage of large-area thin film coatings specifically for environmental remediation. In this review, we focus on methods to increase the efficiency of catalytic reactions in thin film and hence improve the performance in relevant applications while eliminating high cost with the purpose of widespread usage. However, we also include the most recent hybrid architectures, which have potential to make a transformational change in surface applications as soon as high quality and large area production techniques are available. Hence, we present and discuss research studies regarding both organic and inorganic methods that are used to structure thin films that have potential for large-area and eco-friendly coatings.

  2. Natural and planted flora of the log mountain surface - mined demonstration area, Bell County, Kentucky

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, R.L. [Berea College, KY (United States); Wade, G.L. [USDA Forest Service, Burlington, VT (United States); Straw, R.A. [Univ. of Tennessee Plateau Experiment Station, Crossville, TN (United States)

    1996-12-31

    A descriptive study of the naturally invading and planted flora was conducted during 1984-1985 on a 14- and 21-year-old contour surface mine the 14.2 ha Log Mountain Demonstration Area (LMDA), in Bell County, Kentucky. Six habitats are designated from areas created from coal mining; the 1963 bench, 1970 bench, bench highwalls, mine outslopes, mine seeps, and coal haul-telephone microwave tower road. Twenty-four of 25 woody and herbaceous species (11 indigenous, 13 non-indigenous) have persisted from plantings by personnel of the Northeastern Forest Experiment Station, USDA Forest Service. We recommend 11 native and exotic woody and herbaceous species for planting on coal surface-mined areas. An annotated list of vascular plants comprises 360 taxa (286 indigenous, 74 non-indigenous) in 224 genera from 82 families. Taxa consist of 1 Lycopodiophyta, 1 Equisetophyta, 8 Polypodiophyta, 7 Pinophyta, and 343 Magnoliophyta. The most species-rich families are the Asteraceae (64), Poaceae (39), Fabaceae (20), Cyperaceae (16), Rosaceae (13), and Lamiaceae (11). A total of 155 Bell County distribution records were documented. Three threatened Kentucky species (Gentiana decora, Liparis loeselii, Silene ovata) were present in refugial habitats created by surface mining. The high species richness has resulted from native and naturalized invading species from the environs, native and exotic planted species, and species from the remnant seed bank. Forest vegetation is a complex mosaic of natural and semi-natural plant communities on the unplanted and planted areas of LMDA.

  3. Uncertainty studies of real anode surface area in computational analysis for molten salt electrorefining

    International Nuclear Information System (INIS)

    Highlights: → Numerical electrochemo-fluid modeling of pyrochemical electrorefining in cross comparison with 2D and 3D analysis models. → Benchmark study on cell potential of molten LiCl-KCl electrorefining with Mark-IV electrorefiner containing EBR-II spent fuel. → Determination of real anode surface area profile model governing electrorefining performance. → Identification of uncertainty factors in electrorefining causing disagreements between simulation and experiment. → Fully transient performance analysis of 80 hours Mark-IV electrorefining with multi-species multi-reaction 1D model. - Abstract: This study examines how much cell potential changes with five differently assumed real anode surface area cases. Determining real anode surface area is a significant issue to be resolved for precisely modeling molten salt electrorefining. Based on a three-dimensional electrorefining model, calculated cell potentials compare with an experimental cell potential variation over 80 h of operation of the Mark-IV electrorefiner with driver fuel from the Experimental Breeder Reactor II. We succeeded to achieve a good agreement with an overall trend of the experimental data with appropriate selection of a mode for real anode surface area, but there are still local inconsistencies between theoretical calculation and experimental observation. In addition, the results were validated and compared with two-dimensional results to identify possible uncertainty factors that had to be further considered in a computational electrorefining analysis. These uncertainty factors include material properties, heterogeneous material distribution, surface roughness, and current efficiency. Zirconium's abundance and complex behavior have more impact on uncertainty towards the latter period of electrorefining at given batch of fuel. The benchmark results found that anode materials would be dissolved from both axial and radial directions at least for low burn-up metallic fuels after active

  4. Small carpal bone surface area, a characteristic of Turner's syndrome

    Energy Technology Data Exchange (ETDEWEB)

    Cleveland, R.H.; Done, S.; Correia, J.A.; Crawford, J.D.; Kushner, D.C.; Herman, T.E.

    1985-02-01

    An abnormality which has received little attention but may be easily recognized on radiographs of the hand of patients with Turner's syndrome is described. Eleven of thirty-one patients (35.5%) with Turner's syndrome were shown on radiographs of the hand to have a visually detectable smallness of the bone surface area of the carpus when compared to the area of the second through fifth metacarpals. Values for the ''C/M'' ratio (the area of the carpals divided by the area of the second through fifth metacarpals) were calculated for films of 31 individuals with gonadal dysgenesis and compared with those from bone age-matched films of seventy-six individuals with normal development of the hand and wrist. A consistent difference with minimal overlap was documented.

  5. Assessment of Groundwater and Surface Water Pollution at Mitm Area, Ibb City, Yemen

    Directory of Open Access Journals (Sweden)

    Esmail A. Sabahi

    2009-01-01

    Full Text Available Groundwater and surface water samples were collected from Mitm area to study the possible impact of wastewater treatment percolation into the groundwater and surface water. The objective of the study is to assess the groundwater and surface water pollution due to wastewater treatment at Mitm area of Ibb city, in the Republic of Yemen. The concentrations of various physiochemical parameters include heavy metals (Pb, Zn, Ni, Cr, Cd, Cu pH, temperature, Electrical Conductivity (EC, Total Dissolved Solids (TDS, and Dissolved Oxygen (DO, anions and nutrients (F-, Cl-, SO4-2, NO2, NO3-,NH3-N, major cations (Fe, Na, K, Ca, Mg and parameters (COD, BOD5, and coliform group bacteria were measured from the groundwater samples. The results show that three out of five boreholes are contaminated, where the concentration of physic-chemical parameters are above the standard acceptable levels which required for drinking water adapted by Yemen's Ministry of Water and Environment (YMWE, 1999. On the other hand, surface water is affected by the discharge of untreated wastewater. The concentrations of physiochemical parameters are above the standard acceptable levels which required for irrigation purpose adopted by Yemen's Ministry of Water and Environment (YMWE, 1999. Boreholes 1 and 2 are suitable for drinking water, whereas boreholes 3, 4 and 5 are not suitable for drinking water. Therefore, urgency for wastewater treatment at this site is recommended to prevent further contamination to surface and groundwater.

  6. Verification of surface source's characteristics using large-area 2π gas flow counter

    International Nuclear Information System (INIS)

    Power Reactor and Nuclear Fuel Development Corporation (PNC) has large-area 2π gas flow counter for the purpose of measuring activity of surface sources of alpha or beta ray emitter. Surface sources are used for the calibration of radiation measuring equipment for radiation control. Due to sequent use of sources, the surface of these sources are inclined to go in bad condition because of unwanted accidental incidents. For the better calibration achievement of radiation measuring instruments the rate of emission of these sources are to be checked periodically by the large-area 2π gas flow counter. In this paper described that eight U3O8 surface sources were selected from many sources of PNC Tokai Works and activity of these sources was measured by the 2π gas flow counter. The results were compared with the values certified by Japan Radio Isotope Association (JRIA). It is evident from the result of comparison that the surface sources are in good condition, i.e., the sources are reliable to calibrate the radiation control instruments. (author)

  7. Towards evidence-based emergency medicine: Best BETs from the Manchester Royal Infirmary.

    Science.gov (United States)

    Mackway-Jones, Kevin C

    2013-07-01

    Best Evidence Topic reports (BETs) summarise the evidence pertaining to particular clinical questions. They are not systematic reviews, but rather contain the best (highest level) evidence that can be practically obtained by busy practicing clinicians. The search strategies used to find the best evidence are reported in detail in order to allow clinicians to update searches whenever necessary. Each BET is based on a clinical scenario and ends with a clinical bottom line which indicates, in the light of the evidence found, what the reporting clinician would do if faced with the same scenario again. The BETs published below were first reported at the Critical Appraisal Journal Club at the Manchester Royal Infirmary¹ or placed on the BestBETs website. Each BET has been constructed in the four stages that have been described elsewhere.² The BETs shown here together with those published previously and those currently under construction can be seen at http://www.bestbets.org.³ Three BETs are included in this issue of the journal. Capillary blood gases as an alternative to arterial puncture in diabetic ketoacidosis. Effect of warming local anaesthetics on pain of infiltration. Use of tamsulosin in patients with urinary calculi to increase spontaneous stone passage. PMID:23765766

  8. Cortical thickness and surface area in neonates at high risk for schizophrenia.

    Science.gov (United States)

    Li, Gang; Wang, Li; Shi, Feng; Lyall, Amanda E; Ahn, Mihye; Peng, Ziwen; Zhu, Hongtu; Lin, Weili; Gilmore, John H; Shen, Dinggang

    2016-01-01

    Schizophrenia is a neurodevelopmental disorder associated with subtle abnormal cortical thickness and cortical surface area. However, it is unclear whether these abnormalities exist in neonates associated with genetic risk for schizophrenia. To this end, this preliminary study was conducted to identify possible abnormalities of cortical thickness and surface area in the high-genetic-risk neonates. Structural magnetic resonance images were acquired from offspring of mothers (N = 21) who had schizophrenia (N = 12) or schizoaffective disorder (N = 9), and also matched healthy neonates of mothers who were free of psychiatric illness (N = 26). Neonatal cortical surfaces were reconstructed and parcellated as regions of interest (ROIs), and cortical thickness for each vertex was computed as the shortest distance between the inner and outer surfaces. Comparisons were made for the average cortical thickness and total surface area in each of 68 cortical ROIs. After false discovery rate (FDR) correction, it was found that the female high-genetic-risk neonates had significantly thinner cortical thickness in the right lateral occipital cortex than the female control neonates. Before FDR correction, the high-genetic-risk neonates had significantly thinner cortex in the left transverse temporal gyrus, left banks of superior temporal sulcus, left lingual gyrus, right paracentral cortex, right posterior cingulate cortex, right temporal pole, and right lateral occipital cortex, compared with the control neonates. Before FDR correction, in comparison with control neonates, male high-risk neonates had significantly thicker cortex in the left frontal pole, left cuneus cortex, and left lateral occipital cortex; while female high-risk neonates had significantly thinner cortex in the bilateral paracentral, bilateral lateral occipital, left transverse temporal, left pars opercularis, right cuneus, and right posterior cingulate cortices. The high-risk neonates also had significantly

  9. Liquidity, Market Efficiency and the Influence of Noise Traders: Quasi-Experimental Evidence from the Betting Industry

    OpenAIRE

    Raphael Flepp; Stephan Nüesch; Egon Franck

    2013-01-01

    This paper examines how liquidity affects market efficiency in a market environment where securities' true values are revealed at a predetermined point in time. We employ differences in minimum tick sizes at the betting exchange Betfair as a source of exogenous variation in liquidity. The results show that liquidity significantly decreases market efficiency for bets on weekend matches but not for bets on weekday matches. Because uninformed noise bettors are more likely to bet on weekends than...

  10. GFM-II large area surface monitor for alpha beta contamination

    CERN Document Server

    Du Xiang Yang; Han Shu Ping; Zhang Xia

    2002-01-01

    GFM-II large area surface monitor for alpha/beta contamination is equipped with four independent detecting channels, each channel consists one probe and one charge sensitive amplifier. The pancake probe is flow gas proportional counter tubes array. Total active area of the instrument is 1000 cm sup 2. This instrument has an rolling frame, so it can move rapidly on flat ground. Its characteristics is that: 1) Use flow gas proportional counter array instead of single counter, 2) Lower working voltage, 3) Simultaneously rapid measurement for alpha/beta

  11. GFM-II large area surface monitor for α β contamination

    International Nuclear Information System (INIS)

    GFM-II large area surface monitor for α/β contamination is equipped with four independent detecting channels, each channel consists one probe and one charge sensitive amplifier. The pancake probe is flow gas proportional counter tubes array. Total active area of the instrument is 1000 cm2. This instrument has an rolling frame, so it can move rapidly on flat ground. Its characteristics is that: 1) Use flow gas proportional counter array instead of single counter, 2) Lower working voltage, 3) Simultaneously rapid measurement for α/β

  12. How much global burned area can be forecast on seasonal time scales using sea surface temperatures?

    Science.gov (United States)

    Chen, Yang; Morton, Douglas C.; Andela, Niels; Giglio, Louis; Randerson, James T.

    2016-04-01

    Large-scale sea surface temperature (SST) patterns influence the interannual variability of burned area in many regions by means of climate controls on fuel continuity, amount, and moisture content. Some of the variability in burned area is predictable on seasonal timescales because fuel characteristics respond to the cumulative effects of climate prior to the onset of the fire season. Here we systematically evaluated the degree to which annual burned area from the Global Fire Emissions Database version 4 with small fires (GFED4s) can be predicted using SSTs from 14 different ocean regions. We found that about 48% of global burned area can be forecast with a correlation coefficient that is significant at a p accounting for about 1/3 of the total predictable global burned area. A model that combined two indices from different oceans considerably improved model performance, suggesting that fires in many regions respond to forcing from more than one ocean basin. Using OCI—burned area relationships and a clustering algorithm, we identified 12 hotspot regions in which fires had a consistent response to SST patterns. Annual burned area in these regions can be predicted with moderate confidence levels, suggesting operational forecasts may be possible with the aim of improving ecosystem management.

  13. Optimizing parameter choice for FSL-Brain Extraction Tool (BET) on 3D T1 images in multiple sclerosis

    DEFF Research Database (Denmark)

    Popescu, Valeriu; Battaglini, M; Hoogstrate, W S; Verfaillie, S C J; Sluimer, I C; van Schijndel, R A; van Dijk, B W; Cover, K S; Knol, D L; Jenkinson, M; Barkhof, F; de Stefano, N; Vrenken, H; Frederiksen, Jette Lautrup Battistini

    2012-01-01

    Brain atrophy studies often use FSL-BET (Brain Extraction Tool) as the first step of image processing. Default BET does not always give satisfactory results on 3DT1 MR images, which negatively impacts atrophy measurements. Finding the right alternative BET settings can be a difficult and time...

  14. A betting interpretation for probabilities and Dempster-Shafer degrees of belief

    CERN Document Server

    Shafer, Glenn

    2010-01-01

    There are at least two ways to interpret numerical degrees of belief in terms of betting: (1) you can offer to bet at the odds defined by the degrees of belief, or (2) you can judge that a strategy for taking advantage of such betting offers will not multiply the capital it risks by a large factor. Both interpretations can be applied to ordinary additive probabilities and used to justify updating by conditioning. Only the second can be applied to Dempster-Shafer degrees of belief and used to justify Dempster's rule of combination.

  15. The T-box Transcription Factor T-bet in Immunity and Autoimmunity

    Institute of Scientific and Technical Information of China (English)

    Stanford L. Peng

    2006-01-01

    The T-box transcription factor T-bet (Tbx21) has emerged as a key regulator of type 1-like immunity, playing critical roles in the establishment and/or maintenance of effector cell fates in T and B lymphocytes, as well as dendritic cells and natural killer cells. Several autoimmune diseases, especially those classically considered related to T helper 1 (Th1) immunity, appear to require T-bet, at least as judged in mouse models. This review summarizes a current understanding of T-bet's role in immunity, as well as its importance in autoimmunity, with implications for therapeutic intervention.

  16. Sonochemical preparation of high surface area MgAl2O4 spinel.

    Science.gov (United States)

    Troia, A; Pavese, M; Geobaldo, F

    2009-01-01

    High surface area MgAl(2)O(4) has been synthesised by a sonochemical method. Two kinds of precursors were used, alkoxides and nitrates/acetates and in both cases nanostructured MgAl(2)O(4) was obtained. The effect of the addition of a surfactant during the sonication, cetyl trimethyl ammonium bromide, was also investigated. In the case of alkoxides precursors the as-made product is a mixture of hydroxides of aluminium and magnesium, while with nitrates/acetates a gel is obtained after sonication, containing the metal hydroxides and ammonium nitrate. Heating at 500 degrees C transforms the as-made products into MgAl(2)O(4) spinel phase. The surface area is up to 267 m(2)/g after treatment at 500 degrees C and 138 m(2)/g at 800 degrees C. PMID:18658004

  17. Specific surface area of overlapping spheres in the presence of obstructions

    Science.gov (United States)

    Jenkins, D. R.

    2013-02-01

    This study considers the random placement of uniform sized spheres, which may overlap, in the presence of another set of randomly placed (hard) spheres, which do not overlap. The overlapping spheres do not intersect the hard spheres. It is shown that the specific surface area of the collection of overlapping spheres is affected by the hard spheres, such that there is a minimum in the specific surface area as a function of the relative size of the two sets of spheres. The occurrence of the minimum is explained in terms of the break-up of pore connectivity. The configuration can be considered to be a simple model of the structure of a porous composite material. In particular, the overlapping particles represent voids while the hard particles represent fillers. Example materials are pervious concrete, metallurgical coke, ice cream, and polymer composites. We also show how the material properties of such composites are affected by the void structure.

  18. Large-scale genomics unveil polygenic architecture of human cortical surface area.

    Science.gov (United States)

    Chen, Chi-Hua; Peng, Qian; Schork, Andrew J; Lo, Min-Tzu; Fan, Chun-Chieh; Wang, Yunpeng; Desikan, Rahul S; Bettella, Francesco; Hagler, Donald J; Westlye, Lars T; Kremen, William S; Jernigan, Terry L; Le Hellard, Stephanie; Steen, Vidar M; Espeseth, Thomas; Huentelman, Matt; Håberg, Asta K; Agartz, Ingrid; Djurovic, Srdjan; Andreassen, Ole A; Schork, Nicholas; Dale, Anders M

    2015-01-01

    Little is known about how genetic variation contributes to neuroanatomical variability, and whether particular genomic regions comprising genes or evolutionarily conserved elements are enriched for effects that influence brain morphology. Here, we examine brain imaging and single-nucleotide polymorphisms (SNPs) data from ∼2,700 individuals. We show that a substantial proportion of variation in cortical surface area is explained by additive effects of SNPs dispersed throughout the genome, with a larger heritable effect for visual and auditory sensory and insular cortices (h(2)∼0.45). Genome-wide SNPs collectively account for, on average, about half of twin heritability across cortical regions (N=466 twins). We find enriched genetic effects in or near genes. We also observe that SNPs in evolutionarily more conserved regions contributed significantly to the heritability of cortical surface area, particularly, for medial and temporal cortical regions. SNPs in less conserved regions contributed more to occipital and dorsolateral prefrontal cortices. PMID:26189703

  19. Changing surface-atmosphere energy exchange and refreezing capacity of the lower accumulation area, West Greenland

    DEFF Research Database (Denmark)

    Charalampidis, C.; Van As, D.; Box, J. E.;

    2015-01-01

    negative surface mass budget (SMB) and surface meltwater run-off. The observed run-off was due to a large ice fraction in the upper 10 m of firn that prevented meltwater from percolating to available pore volume below. Analysis reveals an anomalously low 2012 summer-averaged albedo of 0.71 (typically ∼ 0...... lowering resulted from high atmospheric temperatures, up to a +2.6 °C daily average, indicating that 2012 would have been a negative SMB year at this site even without the melt-albedo feedback. Longer time series of SMB, regional temperature, and remotely sensed albedo (MODIS) show that 2012 was the first...... strongly negative SMB year, with the lowest albedo, at this elevation on record. The warm conditions of recent years have resulted in enhanced melt and reduction of the refreezing capacity in the lower accumulation area. If high temperatures continue, the current lower accumulation area will turn into a...

  20. Phenomenological study of aerosol dry deposition in urban area: surface properties, turbulence and local meteorology influences

    International Nuclear Information System (INIS)

    Aerosol dry deposition is not much known for urban areas due to the lack of data. Knowledge on this phenomenon is necessary to understand pollutant fluxes in cities and to estimate inhabitant exposition to ionizing radiation of radioactive aerosols. A data providing could enable to enhance dry deposition models for these areas. An original experimental approach is performed to study submicron aerosol dry deposition on urban surfaces. Wind tunnel coupled to in situ experiments give results to study different physical phenomenon governing dry deposition. Dry deposition velocities are measured using aerosol tracers. These data are associated to turbulent and meteorological measured conditions. This database permits to classify the principal physical phenomenon for each experiment type. Finally, different phenomenon must be considered for chronic and acute exposition of urban surfaces to atmospheric particles. (author)

  1. Pore structure and surface area of silica SBA-15: influence of washing and scale-up

    Directory of Open Access Journals (Sweden)

    Jörg P. Thielemann

    2011-02-01

    Full Text Available The removal of the surfactant (EO20PO70EO20 by washing before final calcination is a critical step in the synthesis of silica SBA-15. In contrast to washing with pure water or ethanol, washing with water and ethanol may, depending on the quantity of solvent used, alter the homogeneity and order of the pores, but also lead to an increase of the surface area of SBA-15. A reduction of solvent volume and a controlled washing protocol allow the synthesis of high surface area SBA-15 materials with a narrow monomodal pore size distribution. For larger batch sizes the influence of the quantity of solvent on the quality of the SBA-15 is reduced.

  2. Preparation and characterization of boron nitride/carbon fiber composite with high specific surface area

    International Nuclear Information System (INIS)

    Boron nitride can be used as a good catalyst carrier because of its high thermal conductivity and chemical stability. However, a high specific surface area of boron nitride is still desirable. In this work, a carbon fiber composite coated with boron nitride villous nano-film was prepared, and was also characterized by means of scanning electron microscopy, high resolution transmission electron microscopy, Fourier transform infrared spectroscopy, and Brunauer-Emmett-Teller analysis. The results indicated that the carbon fibers were covered by uniform villous boron nitride films whose thickness was about 150 - 200 nm. The specific surface area of the boron nitride/carbon fiber composite material was 96 m2 g-1, which was markedly improved compared with conventional boron nitride materials. (orig.)

  3. [Distribution, surface and protected area of palm-swamps in Costa Rica and Nicaragua].

    Science.gov (United States)

    Serrano-Sandí, Juan; Bonilla-Murillo, Fabian; Sasa, Mahmood

    2013-09-01

    In Central America, palm swamps are known collectively as yolillales. These wetlands are usually dominated by the raffia palm Raphia taedigera, but also by the royal palm Manicaria saccifera and -in lower extensions- by the American oil palm Elaeis oleifera. The yolillales tend to be poor in woody species and are characteristic of regions with high rainfall and extensive hydroperiods, so they remain flooded most of the year. The dominance of large raffia palm leaves in the canopy, allow these environments to be distinguishable in aerial photographs, which consequently has helped to map them along most of their distribution. However, while maps depicting yolillales are available, the extent of their surface area, perimeter and connectivity remains poorly understood. This is particularly true for yolillales in Costa Rica and Nicaragua, countries that share a good proportion of palm dominated swaps in the Rio San Juan Basin. In addition, it is not known the actual area of these environments that is under any category of protection according to the conservation systems of both countries. As a first step to catalog yolillal wetlands in Costa Rica and Nicaragua, this paper evaluates cartographic maps to delineate yolillales in the region. A subsample of yolillales mapped in this study were visited and we geo-referenced them and evaluate the extent and condition of the swamp. A total of 110 883.2ha are classified as yolillales in Nicaragua, equivalent to 22% of wetland surface area recorded for that country (excluding the Cocibolca and Xolothn Lakes). In Costa Rica, 53 931.3ha are covered by these palm dominated swamps, which represent 16.24% of the total surface area covered by wetlands. About 47% of the area covered by yolillales in Nicaragua is under some category of protection, the largest extensions protected by Cerro Silva, Laguna Tale Sulumas and Indio Maiz Nature Reserves. In Costa Rica, 55.5% of the area covered by yolillal is located within protected areas

  4. The Average Body Surface Area of Adult Cancer Patients in the UK: A Multicentre Retrospective Study

    OpenAIRE

    Sacco, Joseph J.; Joanne Botten; Fergus Macbeth; Adrian Bagust; Peter Clark

    2010-01-01

    The majority of chemotherapy drugs are dosed based on body surface area (BSA). No standard BSA values for patients being treated in the United Kingdom are available on which to base dose and cost calculations. We therefore retrospectively assessed the BSA of patients receiving chemotherapy treatment at three oncology centres in the UK between 1(st) January 2005 and 31(st) December 2005.A total of 3613 patients receiving chemotherapy for head and neck, ovarian, lung, upper GI/pancreas, breast ...

  5. n-Alkylamine-assisted preparation of a high surface area vanadyl phosphate/tetraethylorthosilicate nanocomposite

    International Nuclear Information System (INIS)

    Graphical abstract: CuKα X-ray diffraction patterns of the VP, VPOc, VPOcT, VPOcT200 and VPOcT500. Highlights: ► TEOS and octylamine incorporation into the VP was achieved by expanding the lamellar. ► The specific surface area increased from 15 m2 g−1 in VP to 237 m2 g−1 in VPOcT. ► The VPOcT exhibited thermal resistance up to 200 °C in air. ► Upon thermal treatment up to 500 °C, the surface area increased to 838 m2 g−1. -- Abstract: We have developed a vanadyl phosphate/tetraethylorthosilicate (VPO/TEOS) nanocomposite comprised of silicate chains interleaved with VPO layers, prepared by using an n-alkylamines such as octylamine as the structure directing agent. The nanocomposites were synthesized by reacting amine-intercalated vanadyl phosphate with tetraethylorthosilicate via the soft chemistry approach. The synthetic procedure encompassed the exfoliation of the layered vanadyl phosphate as well as the reorganization of this exfoliated solid into a mesostructured lamellar phase with the same V–P–O connectivity as in the original matrix. TEOS incorporation into the vanadyl phosphate was achieved by expanding the lamellar structure with n-alkylamine (Δd = 13 Å with n-octylamine). The specific surface area increased from 15 m2 g−1 in the vanadyl phosphate matrix to 237 m2 g−1 in VPOcT, and the isotherm curves revealed the characteristic hysteresis of mesoporous materials. Upon thermal treatment up to 500 °C, the surface area increased to 837 m2 g−1, which is suitable for catalytic purposes.

  6. n-Alkylamine-assisted preparation of a high surface area vanadyl phosphate/tetraethylorthosilicate nanocomposite

    Energy Technology Data Exchange (ETDEWEB)

    Ferreira, João Paulo L., E-mail: billbrujah@yahoo.com.br [Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. Bandeirantes 3900, Ribeirão Preto, SP 14040-901 (Brazil); Zampronio, Elaine C.; Oliveira, Herenilton P. [Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Av. Bandeirantes 3900, Ribeirão Preto, SP 14040-901 (Brazil)

    2013-02-15

    Graphical abstract: CuK{sub α} X-ray diffraction patterns of the VP, VPOc, VPOcT, VPOcT200 and VPOcT500. Highlights: ► TEOS and octylamine incorporation into the VP was achieved by expanding the lamellar. ► The specific surface area increased from 15 m{sup 2} g{sup −1} in VP to 237 m{sup 2} g{sup −1} in VPOcT. ► The VPOcT exhibited thermal resistance up to 200 °C in air. ► Upon thermal treatment up to 500 °C, the surface area increased to 838 m{sup 2} g{sup −1}. -- Abstract: We have developed a vanadyl phosphate/tetraethylorthosilicate (VPO/TEOS) nanocomposite comprised of silicate chains interleaved with VPO layers, prepared by using an n-alkylamines such as octylamine as the structure directing agent. The nanocomposites were synthesized by reacting amine-intercalated vanadyl phosphate with tetraethylorthosilicate via the soft chemistry approach. The synthetic procedure encompassed the exfoliation of the layered vanadyl phosphate as well as the reorganization of this exfoliated solid into a mesostructured lamellar phase with the same V–P–O connectivity as in the original matrix. TEOS incorporation into the vanadyl phosphate was achieved by expanding the lamellar structure with n-alkylamine (Δd = 13 Å with n-octylamine). The specific surface area increased from 15 m{sup 2} g{sup −1} in the vanadyl phosphate matrix to 237 m{sup 2} g{sup −1} in VPOcT, and the isotherm curves revealed the characteristic hysteresis of mesoporous materials. Upon thermal treatment up to 500 °C, the surface area increased to 837 m{sup 2} g{sup −1}, which is suitable for catalytic purposes.

  7. METHODS TO DETECT ATMOSPHERIC AND SURFACE HEAT ISLANDS IN URBAN AREAS

    OpenAIRE

    I. HERBEL; A. E. CROITORU; A. M. IMBROANE; D. PETREA

    2015-01-01

    Intensification of the urbanization process and its associated climatic effects is nowadays a major problem of large cities worldwide. One of these climatic effects is the urban heat island (UHI), that implies increased air and surface temperature values in the city when compared to the nearby rural areas. This phenomenon threatens the health of the population, especially during heat waves, affects the quality of the environment and the quality of life, and also generates significant costs to...

  8. A new-type large-area plasma source produced by electromagnetic surface waves

    International Nuclear Information System (INIS)

    The design and experimental investigation of a new-type plasma source produced by electromagnetic surface waves is given. The experimental results show that the source has successfully produced a homogeneous plasma column in diameter over 160 mm with electron density of 1010-1011 cm-3 and electron temperature of several eV at a pressure below 230 Pa. This manifests that the source is adaptable to large-area and large-volume plasmas

  9. Cocycles of area preserving diffeomorphisms and anomalies in theory of relativistic surfaces

    International Nuclear Information System (INIS)

    A theory of relativistic bosonic membrane of different topology is studied. In the lightcone gauge a residual symmetry consists of a group of area preserving diffeomorphisms of two-dimensional surface of membrane; its structure constants as well as the first and second groups of cohomologies H1(S,S) and H2(S,R) are calculated which determine the right and central extensions of this group under quantization. 10 refs

  10. GPU/CPU Algorithm for Generalized Born/Solvent-Accessible Surface Area Implicit Solvent Calculations

    OpenAIRE

    Tanner, David E.; Phillips, James C.; Schulten, Klaus

    2012-01-01

    Molecular dynamics methodologies comprise a vital research tool for structural biology. Molecular dynamics has benefited from technological advances in computing, such as multi-core CPUs and graphics processing units (GPUs), but harnessing the full power of hybrid GPU/CPU computers remains difficult. The generalized Born/solvent-accessible surface area implicit solvent model (GB/SA) stands to benefit from hybrid GPU/CPU computers, employing the GPU for the GB calculation and the CPU for the S...

  11. Sol-gel preparation of low oxygen content, high surface area silicon nitride and imidonitride materials.

    Science.gov (United States)

    Sardar, Kripasindhu; Bounds, Richard; Carravetta, Marina; Cutts, Geoffrey; Hargreaves, Justin S J; Hector, Andrew L; Hriljac, Joseph A; Levason, William; Wilson, Felix

    2016-04-01

    Reactions of Si(NHMe)4 with ammonia are effectively catalysed by small ammonium triflate concentrations, and can be used to produce free-standing silicon imide gels. Firing at various temperatures produces amorphous or partially crystallised silicon imidonitride/nitride samples with high surface areas and low oxygen contents. The crystalline phase is entirely α-Si3N4 and structural similarities are observed between the amorphous and crystallised materials. PMID:26931152

  12. Nanotextured gold coatings on carbon nanofiber scaffolds as ultrahigh surface-area electrodes

    OpenAIRE

    COLAVITA, PAULA

    2012-01-01

    PUBLISHED High surface area metal electrodes are desirable for applications in energy storage and energy conversion. Here, the formation and electrochemical characterization of a hybrid material made by electroless deposition of gold onto a scaffolding of vertically aligned carbon nanofibers is described. Vertically aligned carbon nanofibers, ~80 nm in diameter, provided mechanical support and electrical contact to the highly textured nanoscale gold coatings. By chemically functionalizing ...

  13. Association of body surface area and body composition with heart structural characteristics of female swimmers

    OpenAIRE

    SHEIKHSARAF, BAHAREH; ALLAH, NIKBAKHT HOJAT; ALI, AZARBAYJANI MOHAMMAD

    2010-01-01

    In healthy nonathletic populations, some left ventricle (LV) parameters such as LV mass (LVM) and LV end diastolic dimension (LVEDD) can be predicted by some of body size parameters such as body surface area (BSA), fat-free mass (FFM), and height (H). These body size parameters use to remove covariate influence of body size from cardiac dimension variables and allow comparisons to be made between individuals and groups of different body size. Endurance exercise has been associated with change...

  14. A simple and highly effective process for the preparation of activated carbons with high surface area

    International Nuclear Information System (INIS)

    Highlights: → High surface area activated carbon can be prepared by rice husk H3PO4 without pretreatment. → The characteristics of the activated carbon were greatly influenced by post-processing method. → The lower SiO2 content of the activated carbons, the higher pore volume the carbons had. → Some silica in rice husk reacted with H3PO4 to form SiP2O7 which could be removed by post-process. - Abstract: Activated carbons with high surface area were prepared by phosphoric acid as activation agent and rice husks as precursors. It was found that the characteristics of the activated carbons were influenced not only by the preparation but also by the post-processing method. The high surface area of the activated carbons was prepared under the optimum condition (50% H3PO4 with impregnation ratio of 5:1, activation temperature of 500 deg. C, activation time of 0.5 h, wash water temperature of 100 deg. C). SiO2 content could affect the surface area of activated carbons, either. The lower SiO2 content of the activated carbons, the higher pore volume the carbons had. The SiO2 content was 11.2% when used the optimum condition. The explanation was that silicon element in rice husks reacted with H3PO4 to form silicon phosphate (SiP2O7), and it could be proved further by X-ray diffraction analysis, SiP2O7 could be removed by post-process.

  15. A simple and highly effective process for the preparation of activated carbons with high surface area

    Energy Technology Data Exchange (ETDEWEB)

    Li Ying, E-mail: liyingjlu@163.com [College of Chemistry, Jilin University, Changchun 130012 (China); Ding Xuefeng; Guo Yupeng; Wang Lili; Rong Chunguang; Qu Yuning; Ma Xiaoyu [College of Chemistry, Jilin University, Changchun 130012 (China); Wang Zichen, E-mail: wangzc@jlu.edu.cn [College of Chemistry, Jilin University, Changchun 130012 (China)

    2011-06-15

    Highlights: {yields} High surface area activated carbon can be prepared by rice husk H{sub 3}PO{sub 4} without pretreatment. {yields} The characteristics of the activated carbon were greatly influenced by post-processing method. {yields} The lower SiO{sub 2} content of the activated carbons, the higher pore volume the carbons had. {yields} Some silica in rice husk reacted with H{sub 3}PO{sub 4} to form SiP{sub 2}O{sub 7} which could be removed by post-process. - Abstract: Activated carbons with high surface area were prepared by phosphoric acid as activation agent and rice husks as precursors. It was found that the characteristics of the activated carbons were influenced not only by the preparation but also by the post-processing method. The high surface area of the activated carbons was prepared under the optimum condition (50% H{sub 3}PO{sub 4} with impregnation ratio of 5:1, activation temperature of 500 deg. C, activation time of 0.5 h, wash water temperature of 100 deg. C). SiO{sub 2} content could affect the surface area of activated carbons, either. The lower SiO{sub 2} content of the activated carbons, the higher pore volume the carbons had. The SiO{sub 2} content was 11.2% when used the optimum condition. The explanation was that silicon element in rice husks reacted with H{sub 3}PO{sub 4} to form silicon phosphate (SiP{sub 2}O{sub 7}), and it could be proved further by X-ray diffraction analysis, SiP{sub 2}O{sub 7} could be removed by post-process.

  16. Changing Surface-Atmosphere Energy Exchange and Refreezing Capacity of the Lower Accumulation Area, West Greenland

    Science.gov (United States)

    Charalampidis, C.; van As, D.; Machguth, H.; Smeets, P.; van den Broeke, M. R.; Box, J. E.

    2014-12-01

    We present five years (2009-2013) of automatic weather station (AWS) data from the lower accumulation area (1840 m above sea level) of the Kangerlussuaq region, western Greenland ice sheet. The summers of 2010 and 2012 were both exceptionally warm, but only 2012 resulted in negative surface mass budget (SMB) and surface runoff. The observed runoff was due to a large ice fraction in the upper 10 m of firn that prevented melt water from percolating to available pore space below. Analysis of the in situ data reveals a relatively low 2012 summer albedo of ~0.7 as melt water was present at the surface. Consequently, during the 2012 melt season the surface absorbed 30% (213 MJ m-2) more solar radiation than in 2010. We drive a surface energy balance model with the AWS data to evaluate the seasonal and interannual variability of all surface energy fluxes. The model is able to reproduce the observed melt rates as well as the SMB for each season. While the drive for melt is solar radiation, year-to-year differences are controlled by terrestrial radiation, apart from 2012 when solar radiation dominated melt. Sensitivity tests reveal that 72% of the excess solar energy in 2012 was used for melt, corresponding to 40% (0.67 m) of the 2012 surface ablation. The remaining ablation (0.99 m) was primarily due to the relatively high atmospheric temperatures up to +2.6 °C daily average, indicating that 2012 would have been a negative SMB year in the lower accumulation area even without the melt-albedo feedback. Longer time series of SMB, regional temperature and remotely sensed albedo (MODIS) suggest that 2012 was the first negative SMB year with the lowest albedo at this elevation on record. The warming conditions of the last years resulted in enhanced melt and reduction of the refreezing capacity of the lower accumulation area. If the warming continues the lower accumulation area will be transformed into superimposed ice.

  17. Combining Spectral and Texture Features Using Random Forest Algorithm: Extracting Impervious Surface Area in Wuhan

    Science.gov (United States)

    Shao, Zhenfeng; Zhang, Yuan; Zhang, Lei; Song, Yang; Peng, Minjun

    2016-06-01

    Impervious surface area (ISA) is one of the most important indicators of urban environments. At present, based on multi-resolution remote sensing images, numerous approaches have been proposed to extract impervious surface, using statistical estimation, sub-pixel classification and spectral mixture analysis method of sub-pixel analysis. Through these methods, impervious surfaces can be effectively applied to regional-scale planning and management. However, for the large scale region, high resolution remote sensing images can provide more details, and therefore they will be more conducive to analysis environmental monitoring and urban management. Since the purpose of this study is to map impervious surfaces more effectively, three classification algorithms (random forests, decision trees, and artificial neural networks) were tested for their ability to map impervious surface. Random forests outperformed the decision trees, and artificial neural networks in precision. Combining the spectral indices and texture, random forests is applied to impervious surface extraction with a producer's accuracy of 0.98, a user's accuracy of 0.97, and an overall accuracy of 0.98 and a kappa coefficient of 0.97.

  18. Video inspection of lattice tube rolled joint area with structured lighting for enhanced surface profiling

    International Nuclear Information System (INIS)

    Retube Tubesheet Bore Dressing is a series of operations being performed by the Bruce Retube Project between calandria tube removal and installation of the new calandria tubes. Specialized remotely-operated tooling has been designed and developed to perform the task to ensure proper tubesheet bore conditions prior to making the new calandria tube rolled joint. A key part of the tool is the video inspection module. During operation, the module scans the area to ensure proper tool location and to assess surface condition. The tool may then be used to perform either rotary brushing or milling to improve the groove profile. Following dressing, the system re-inspects the bore to verify the operation. The tool may also perform a video inspection of the inboard section of the lattice tube and verify the condition of the inboard bearing. In order to enhance the operator's ability to evaluate the machined surface, structured lighting has been used, consisting of an axially projected laser light stripe. This was included in the design to better define the surface profile during scanning. Surface inspection images are shown to demonstrate the performance of the unit. By analysing a series of captured images from the surface scan, both a surface profile and diametral measurements of the tubesheet bore can be calculated, extending the technique from a qualitative to a quantitative method. (author)

  19. Monolithic nanoporous gold disks with large surface area and high-density plasmonic hot-spots

    Science.gov (United States)

    Zhao, Fusheng; Zeng, Jianbo; Arnob, Md Masud Parvez; Santos, Greggy M.; Shih, Wei-Chuan

    2015-03-01

    Plasmonic metal nanostructures have shown great potential in sensing, photovoltaics, imaging and biomedicine, principally due to enhancement of the local electric field by light-excited surface plasmons, the collective oscillation of conduction band electrons. Thin films of nanoporous gold have received a great deal of interest due to the unique 3- dimensional bicontinuous nanostructures with high specific surface area. However, in the form of semi-infinite thin films, nanoporous gold exhibits weak plasmonic extinction and little tunability in the plasmon resonance, because the pore size is much smaller than the wavelength of light. Here we show that by making nanoporous gold in the form of disks of sub-wavelength diameter and sub-100 nm thickness, these limitations can be overcome. Nanoporous gold disks (NPGDs) not only possess large specific surface area but also high-density, internal plasmonic "hot-spots" with impressive electric field enhancement, which greatly promotes plasmon-matter interaction as evidenced by spectral shifts in the surface plasmon resonance. In addition, the plasmonic resonance of NPGD can be easily tuned from 900 to 1850 nm by changing the disk diameter from 300 to 700 nm. The coupling between external and internal nanoarchitecture provides a potential design dimension for plasmonic engineering. The synergy of large specific surface area, high-density hot spots, and tunable plasmonics would profoundly impact applications where plasmonic nanoparticles and non-plasmonic mesoporous nanoparticles are currently employed, e.g., in in-vitro and in-vivo biosensing, molecular imaging, photothermal contrast agents, and molecular cargos.

  20. Rippled area formed by surface plasmon polaritons upon femtosecond laser double-pulse irradiation of silicon.

    Science.gov (United States)

    Derrien, Thibault J-Y; Krüger, Jörg; Itina, Tatiana E; Höhm, Sandra; Rosenfeld, Arkadi; Bonse, Jörn

    2013-12-01

    The formation of near-wavelength laser-induced periodic surface structures (LIPSS) on silicon upon irradiation with sequences of Ti:sapphire femtosecond laser pulse pairs (pulse duration 150 fs, central wavelength 800 nm) is studied theoretically. For this purpose, the nonlinear generation of conduction band electrons in silicon and their relaxation is numerically calculated using a two-temperature model approach including intrapulse changes of optical properties, transport, diffusion and recombination effects. Following the idea that surface plasmon polaritons (SPP) can be excited when the material turns from semiconducting to metallic state, the "SPP active area" is calculated as function of fluence and double-pulse delay up to several picoseconds and compared to the experimentally observed rippled surface areas. Evidence is presented that multi-photon absorption explains the large increase of the rippled area for temporally overlapping pulses. For longer double-pulse delays, relevant relaxation processes are identified. The results demonstrate that femtosecond LIPSS on silicon are caused by the excitation of SPP and can be controlled by temporal pulse shaping. PMID:24514516

  1. Effects of acid treatment on the clay palygorskite: XRD, surface area, morphological and chemical composition

    International Nuclear Information System (INIS)

    The palygorskite is an aluminum-magnesium silicate that has a fibrous morphology. Their physicochemical characteristics are the result of high surface area, porosity and thermal resistance which make it an attractive adsorbent. Its adsorption capacity can be increased through chemical reactions and/or heat treatments. The objective of this work is to verify the effects of acid activation on the palygorskite, treated with HCl at 90 °C at concentrations of 2, 4 and 6 mol L-1 in 2 and 4 hours, with clay/acid solution ratio 1 g 10 mL-1 and characterized by techniques: XRF, XRD and surface area. A significant increase in specific surface area was observed in the sample treated with HCl at the concentration 6 mol L-1. The changes were more pronounced at stricter concentrations of acidity, with decreasing intensity of reflection of the clay indicated in the XRD. These changes were confirmed in the XRF with the leaching of some oxides and with increasing concentration of SiO2. (author)

  2. Glacier melting and precipitation trends detected by surface area changes in Himalayan ponds

    Science.gov (United States)

    Salerno, Franco; Thakuri, Sudeep; Guyennon, Nicolas; Viviano, Gaetano; Tartari, Gianni

    2016-07-01

    Climatic time series for high-elevation Himalayan regions are decidedly scarce. Although glacier shrinkage is now sufficiently well described, the changes in precipitation and temperature at these elevations are less clear. This contribution shows that the surface area variations of unconnected glacial ponds, i.e. ponds not directly connected to glacier ice, but that may have a glacier located in their hydrological basin, can be considered as suitable proxies for detecting past changes in the main hydrological components of the water balance. On the south side of Mt Everest, glacier melt and precipitation have been found to be the main drivers of unconnected pond surface area changes (detected mainly with Landsat imagery). In general, unconnected ponds have decreased significantly by approximately 10 ± 5 % in terms of surface area over the last 50 years (1963-2013 period) in the study region. Here, an increase in precipitation occurred until the mid-1990s followed by a decrease until recent years. Until the 1990s, glacier melt was constant. An increase occurred in the early 2000s, while a declining trend in maximum temperature has caused a reduction in the glacier melt during recent years.

  3. Effects of acid treatment on the clay palygorskite: XRD, surface area, morphological and chemical composition

    Energy Technology Data Exchange (ETDEWEB)

    Xavier, Katiane Cruz Magalhaes; Santos, Maria do Socorro Ferreira dos; Santos, Maria Rita Morais Chaves; Oliveira, Marilia Evelyn Rodrigues; Osajima, Josy Antevelli; Silva Filho, Edson Cavalcanti da [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil); Carvalho, Maria Wilma Nunes Cordeiro, E-mail: edsonfilho@ufpi.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2014-08-15

    The palygorskite is an aluminum-magnesium silicate that has a fibrous morphology. Their physicochemical characteristics are the result of high surface area, porosity and thermal resistance which make it an attractive adsorbent. Its adsorption capacity can be increased through chemical reactions and/or heat treatments. The objective of this work is to verify the effects of acid activation on the palygorskite, treated with HCl at 90 °C at concentrations of 2, 4 and 6 mol L{sup -1} in 2 and 4 hours, with clay/acid solution ratio 1 g 10 mL{sup -1} and characterized by techniques: XRF, XRD and surface area. A significant increase in specific surface area was observed in the sample treated with HCl at the concentration 6 mol L{sup -1}. The changes were more pronounced at stricter concentrations of acidity, with decreasing intensity of reflection of the clay indicated in the XRD. These changes were confirmed in the XRF with the leaching of some oxides and with increasing concentration of SiO{sub 2}. (author)

  4. Evaluation of The Surface Ozone Concentrations In Greater Cairo Area With Emphasis On Helwan, Egypt

    International Nuclear Information System (INIS)

    Various biogenic and anthropogenic sources emit huge quantities of surface ozone. The main purpose of this study is to evaluate the surface ozone levels present at Helwan area in order to improve the knowledge and understanding troposphere processes. Surface Ozone has been measured at 2 sites at Helwan; these sites cover the most populated area in Helwan. Ozone concentration is continuously monitored by UV absorption photometry using the equipment O3 41 M UV Photometric Ozone Analyzer. The daily maximum values of the ozone concentration in the greater Cairo area have approached but did not exceeded the critical levels during the year 2008. Higher ozone concentrations at Helwan are mainly due to the transport of ozone from regions further to the north of greater Cairo and to a lesser extent of ozone locally generated by photochemical smog process. The summer season has the largest diurnal variation, with the tendency of the daily ozone maxima occur in the late afternoon. The night time concentration of ozone was significantly higher at Helwan because there are no fast acting sinks, destroying ozone since the average night time concentration of ozone is maintained at 40 ppb at the site. No correlation between the diurnal total suspended particulate (TSP) matter and the diurnal cumulative ozone concentration was observed during the Khamasin period

  5. Synthesis of high surface area nanometer magnesia by solid-state chemical reaction

    Institute of Scientific and Technical Information of China (English)

    GUAN Hongbo; WANG Pei; ZHAO Biying; ZHU Yuexiang; XIE Youchang

    2007-01-01

    Nanometer MgO samples with high surface area,small crystal size and mesoporous texture were synthesized tion process accelerated the sintering of MgO,and MgO with calcining its precursor in flowing dry nitrogen at 520℃ for 4 h.The samples were characterized by X-ray diffraction,N2 adsorption,transmission electron microscopy,thermogravimetry,and differential thermal analysis.The as-prepared MgO was composed of nanocrystals with a size of about 4-5 nm and formed a wormhole-like porous structure.The MgO also had good thermal stability,and its surface areas remained at 357 and 153 m2.g-1 after calcination at 600 and 800℃ for 2 h,respectively.Compared with the MgO sample prepared by the precipitation method,MgO prepared by solid-state chemical reaction has uniform pore size distribution,surface area,and crystal size.The solid-state chemical method has the advantages of low cost,low pollution,and high yield,therefore it appears to be a promising method in the industrial manufacture of nanometer MgO.

  6. Surface area and pore size distribution of activated carbon produced from low cost precursors

    International Nuclear Information System (INIS)

    Fast growing wood (Paulownia tomentos-PT, Ailanthus altissima-AA. Salvadara oleoides-SO) and animal bones were utilized for the preparation of activated carbon. The carbon samples were activated by thermal means (400-1000 degree C). The samples were characterized by surface area (Langmuir and BJH) with micropore and meso pores volume (BJH). The surface area of other carbon samples activated at 800 degree C was found in the sequence: 654.9 for Salvadora oleoides > 615.8 for Ailanthus altissima > 346.3 for Paulownia tomentosa > 300.0 for animal bones. BJH surface area (m/sup 2/g/sup -l/) analysis of the carbon samples activated at 800 degree C was found in the sequence: 274.6 for Salvadora oleoides > 261.76 for animal bones> 224.8 for Paulownia tomentosa > 200.2 for Ailanthus altissima. The micropore volume (BJH method) of 800 degree C activated carbon samples were in the sequence: 0.15 for Ailanthus altissima > 0.13 for Salvadora oleoides > 0.08 for animal bones. (author)

  7. ERROR BOUNDS FOR SURFACE AREA ESTIMATORS BASED ON CROFTON’S FORMULA

    Directory of Open Access Journals (Sweden)

    Markus Kiderlen

    2011-05-01

    Full Text Available According to Crofton's formula, the surface area S(A of a sufficiently regular compact set A in Rd is proportional to the mean of all total projections pA (u on a linear hyperplane with normal u, uniformly averaged over all unit vectors u. In applications, pA (u is only measured in k directions and the mean is approximated by a finite weighted sum bS(A of the total projections in these directions. The choice of the weights depends on the selected quadrature rule. We define an associated zonotope Z (depending only on the projection directions and the quadrature rule, and show that the relative error bS (A/S (A is bounded from below by the inradius of Z and from above by the circumradius of Z. Applying a strengthened isoperimetric inequality due to Bonnesen, we show that the rectangular quadrature rule does not give the best possible error bounds for d =2. In addition, we derive asymptotic behavior of the error (with increasing k in the planar case. The paper concludes with applications to surface area estimation in design-based digital stereology where we show that the weights due to Bonnesen's inequality are better than the usual weights based on the rectangular rule and almost optimal in the sense that the relative error of the surface area estimator is very close to the minimal error.

  8. Growth of Hierarchically Structured High-Surface Area Alumina on FeCrAl Alloy Wires

    Directory of Open Access Journals (Sweden)

    Chandni Rallan

    2013-01-01

    Full Text Available The formation of metastable alumina phases due to the oxidation of commercial FeCrAl alloy wires (0.5 mm thickness at various temperatures and time periods has been examined. Samples were isothermally oxidised in air using a thermogravimetric analyzer (TGA. The morphology of the oxidised samples was analyzed using an Electronic Scanning Electron Microscope (ESEM and X-ray on the surface analysis was done using an Energy Dispersive X-Ray (EDX analyzer. The technique of X-Ray Diffraction (XRD was used to characterize the phase of the oxide growth. The entire study showed that it was possible to grow high-surface area gamma alumina on the FeCrAl alloy wire surfaces when isothermally oxidised above 800°C over several hours.

  9. Evapotranspiration and runoff from large land areas: Land surface hydrology for atmospheric general circulation models

    Science.gov (United States)

    Famiglietti, J. S.; Wood, Eric F.

    1993-01-01

    A land surface hydrology parameterization for use in atmospheric GCM's is presented. The parameterization incorporates subgrid scale variability in topography, soils, soil moisture and precipitation. The framework of the model is the statistical distribution of a topography-soils index, which controls the local water balance fluxes, and is therefore taken to represent the large land area. Spatially variable water balance fluxes are integrated with respect to the topography-soils index to yield our large topography-soils distribution, and interval responses are weighted by the probability of occurrence of the interval. Grid square averaged land surface fluxes result. The model functions independently as a macroscale water balance model. Runoff ratio and evapotranspiration efficiency parameterizations are derived and are shown to depend on the spatial variability of the above mentioned properties and processes, as well as the dynamics of land surface-atmosphere interactions.

  10. METHODS TO DETECT ATMOSPHERIC AND SURFACE HEAT ISLANDS IN URBAN AREAS

    Directory of Open Access Journals (Sweden)

    I. HERBEL

    2015-10-01

    Full Text Available Intensification of the urbanization process and its associated climatic effects is nowadays a major problem of large cities worldwide. One of these climatic effects is the urban heat island (UHI, that implies increased air and surface temperature values in the city when compared to the nearby rural areas. This phenomenon threatens the health of the population, especially during heat waves, affects the quality of the environment and the quality of life, and also generates significant costs to ensure the inhabitants' thermal comfort. In this study we present a review of the UHI concept and three of the main methods used to detect the atmospheric and surface urban heat islands. Satellite image data analysis seems an easier and time-saving solution, but due to its limitations, we consider that a combination of both surfaces and lower atmospheric layer temperature data analysis is the best choice in order to get accurate results of the intensity and spatial extension of the UHI.

  11. Description of climate, surface hydrology, and near-surface hydrogeology. Preliminary site description. Forsmark area - version 1.2

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Per-Olof [Artesia Grundvattenkonsult AB, Stockholm (Sweden); Werner, Kent [SWECO VIAK AB/Golder Associates AB, Stockholm (Sweden); Bosson, Emma; Berglund, Sten [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden); Juston, John [DBE Sweden, Uppsala (Sweden)

    2005-06-15

    The Swedish Nuclear Fuel and Waste Management Company (SKB) is conducting site investigations at two different locations, the Forsmark and Simpevarp areas, with the objective of siting a geological repository for spent nuclear fuel. The results from the investigations at the sites are used as a basic input to the development of Site Descriptive Models (SDM). The SDM shall summarise the current state of knowledge of the site, and provide parameters and models to be used in further analyses within Safety Assessment, Repository Design and Environmental Impact Assessment. The present report is a background report describing the meteorological conditions and the modelling of surface hydrology and near-surface hydrogeology in support of the Forsmark version 1.2 SDM based on the data available in the Forsmark 1.2 'data freeze' (July 31, 2004). The groundwater is very shallow, with groundwater levels within one meter below ground as an annual mean for almost all groundwater monitoring wells. Also, the annual groundwater level amplitude is less than 1.5 m for most wells. The shallow groundwater levels mean that there is a strong interaction between evapotranspiration, soil moisture and groundwater. In the modelling, surface water and near-surface groundwater divides are assumed to coincide. The small-scale topography implies that many local, shallow groundwater flow systems are formed in the Quaternary deposits, overlaying more large-scale flow systems associated with groundwater flows at greater depths. Groundwater level time series from wells in till and bedrock within the same areas show a considerably higher groundwater level in the till than in the bedrock. The observed differences in levels are not fully consistent with the good hydraulic contact between overburden and bedrock indicated by the hydraulic tests in the Quaternary deposits. However, the relatively lower groundwater levels in the bedrock may be caused by the horizontal to sub-horizontal highly

  12. Near-Surface Seismic Refraction Methods to Characterize Areas of Karst Geology near Carlsbad, NM

    Science.gov (United States)

    Cafferky, S.; Bonal, N. D.; Barnhart, K.

    2012-12-01

    Near-surface seismic refraction methods applied to karst geology can give some ideas as to the nature of the void spaces as well as the stratigraphy of the area. A seismic geophone array was laid out near Carlsbad, NM, an area known to contain karst features. Using an impact (sledge hammer), seismic data was collected along two intersecting lines of geophones as well as two gridded areas to get three-dimensional information. The data was picked for the first arrivals of the P-wave, which were graphed and examined for changes in slope and inconsistencies in shape. The data analyzed shows a two-layer model and some inconsistencies such as polarity reversals and delayed arrival times that may represent karst features. Additional processing is used to enhances these features and map them in three-dimensions. The mapped features are compared with known karst features in the area (e.g. sinkholes) for ground-truth information. These methods may be used in the future for detection and classification of other near-surface voids. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  13. Measurement of surface emission flux rates for volatile organic compounds at Technical Area 54

    Energy Technology Data Exchange (ETDEWEB)

    Trujillo, V.; Morgenstern, M.; Krier, D. [Los Alamos National Lab., NM (United States); Gilkeson, R. [Weirich and Associates, Albuquerque, NM (United States)

    1998-06-01

    The survey described in this report was conducted to estimate the mass of volatile organic compounds venting to the atmosphere from active and inactive waste disposal sites at Technical Area 54. A large number of nonintrusive passive sample collection devices were placed on the ground surface for 72 hours to characterize an area of approximately 150 acres. Results provided an indication of the boundary location of the known volatile organic plume, plume constituents, and isolated high concentration areas. The data from this survey enhanced existing data from a limited number of monitor wells currently used for plume surveillance. Results indicate that the estimated mass emission to the atmosphere is orders of magnitude lower than what is considered a small flux rate at a spill site or a Resource Conservation and Recovery Act landfill and is far below the threshold limit established by the State of New Mexico as an air quality concern.

  14. Surface ozone concentrations and solar radiation in polluted and remote areas in Egypt

    International Nuclear Information System (INIS)

    this work discusses sources of ozone in the troposphere, particularly with regard to the relative contributions of flues from the stratosphere and that created due to photochemical reactions in the troposphere. Measurements of surface ozone at cairo and the oases Dakhla are used as a a comparative study between the formation of ozone in a polluted area and that of clean atmosphere. The daily maximum ozone concentrations found to be 105 ppb in cairo and 52 ppb in Dakhla. The results show that the budget of ozone in the polluted air masses is dominated by photochemistry, and there is a significant correlation between the monthly mean value use of ozone and global radiation. The ozone budget in free troposphere and rural areas, where the diurnal variation is very low compared to that of polluted areas, is governed by vertical transport

  15. Digitized generalized areas where surface-water resources likely or potentially are susceptible to groundwater withdrawals in adjacent valleys, Great Basin National Park area, Nevada

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Polygons delineate generalized areas in and around Great Basin National Park where surface-water resources likely or potentially are susceptible to groundwater...

  16. Surface connection between different areas in Mediterranean Sea derived from drifter data

    Science.gov (United States)

    Celentano, Paolo; Carlson, Daniel F.; Falco, Pierpaolo; Zambianchi, Enrico

    2016-04-01

    The surface connection of five study areas in the Mediterranean Sea (Sicily Strait, Gulf of Lyon, Ionian Sea, Alborán Sea and Crete Passage) is studied by looking at the statistical properties of near-surface lagrangian trajectories. The choice of the areas is due to the geographical distribution of data and the key role of these sub-basins in the dynamics of the Mediterranean. We used Lagrangian drifter data taken from the Mediterranean Surface Velocity Programme (http://nettuno.ogs.trieste.it/sire/medsvp/). The most common surface drifter used is the CODE-type drifter (Davis, 1985), designed to follow the vertical average velocity of the upper 1 m layer of the water column. The dataset consist of 1547 trajectories, deployed between 1986 and 2015 in all Mediterranean sub basins. By examining the drifter paths through the study areas, we computed transit and residence time, pseudo-Eulerian statistics and connection probabilities. Given the small number of drifters and the non-normal distribution of transit times, it is possible to use a bootstrap method (Efron and Tibshirani, 1986) to estimate the average transit time. In particular, we divided it into forward and backward transit times to consider the time taken by drifters respectively, from the exit of study area to end of its trajectory and from the deployment position to the study area. The main results indicate that the transit time between Sicily Strait and coast of Libya is about 83-103 days and between the Strait and the Gulf of Lyon is approximately 134 days. The time to reach the Adriatic Sea from the Ionian is around 30-40 days; the drifters take around 70 days to go from Alborán Sea to Sardinia channel and 43 days between Crete and the Ionian Sea. The Ionian Sea due has the highest number of drifter trajectories and the highest residence time, about 42 days. Also the Crete Passage has a high value of residence time, approximately 35 days; the other study areas are characterized by residence times of

  17. Corrective Action Decision Document for Corrective Action Unit 417: Central Nevada Test Area Surface, Nevada

    International Nuclear Information System (INIS)

    This Corrective Action Decision Document (CADD) identifies and rationalizes the U.S. Department of Energy, Nevada Operations Office's selection of a recommended corrective action alternative (CAA) appropriate to facilitate the closure of Corrective Action Unit (CAU) 417: Central Nevada Test Area Surface, Nevada, under the Federal Facility Agreement and Consent Order. Located in Hot Creek Valley in Nye County, Nevada, and consisting of three separate land withdrawal areas (UC-1, UC-3, and UC-4), CAU 417 is comprised of 34 corrective action sites (CASs) including 2 underground storage tanks, 5 septic systems, 8 shaker pad/cuttings disposal areas, 1 decontamination facility pit, 1 burn area, 1 scrap/trash dump, 1 outlier area, 8 housekeeping sites, and 16 mud pits. Four field events were conducted between September 1996 and June 1998 to complete a corrective action investigation indicating that the only contaminant of concern was total petroleum hydrocarbon (TPH) which was found in 18 of the CASs. A total of 1,028 samples were analyzed. During this investigation, a statistical approach was used to determine which depth intervals or layers inside individual mud pits and shaker pad areas were above the State action levels for the TPH. Other related field sampling activities (i.e., expedited site characterization methods, surface geophysical surveys, direct-push geophysical surveys, direct-push soil sampling, and rotosonic drilling located septic leachfields) were conducted in this four-phase investigation; however, no further contaminants of concern (COCs) were identified. During and after the investigation activities, several of the sites which had surface debris but no COCs were cleaned up as housekeeping sites, two septic tanks were closed in place, and two underground storage tanks were removed. The focus of this CADD was to identify CAAs which would promote the prevention or mitigation of human exposure to surface and subsurface soils with contaminant

  18. Stone anchors from Bet Dwarka Island, Gujarat, Coast, India: Significance to historical period maritime activities

    Digital Repository Service at National Institute of Oceanography (India)

    Sundaresh; Gaur, A.S.; Tripati, S.; Gudigar, P.; Bandodkar, S.N.

    Bet Dwarka Island is situated on the extreme west of Indian territory in Jamnagar district of Gujarat. Underwater, the most preserved remains of ancient maritime activity could be the stone anchors of different types, as every boat requires...

  19. Interaction between surface water areas and groundwater in Hanoi city, Viet Nam

    Science.gov (United States)

    Hayashi, T.; Kuroda, K.; Do Thuan, A.; Tran Thi Viet, N.; Takizawa, S.

    2012-12-01

    Hanoi is the capital of Viet Nam and the second largest city in this country (population: 6.45 million in 2009). Hanoi city has developed along the Red River and has many lakes, ponds and canals. However, recent rapid urbanization of this city has reduced number of natural water areas such as ponds and lakes by reclamation not only in the central area but the suburban area. Canals also have been reclaimed or cut into pieces. Contrary, number of artificial water areas such as fish cultivation pond has rapidly increased. On the other hand, various kind of waste water flows into these natural and artificial water areas and induces pollution and eutrophication. These waste waters also have possibility of pollution of groundwater that is one of major water resources in this city. In addition, groundwater in this area has high concentrations of Arsenic, Fe and NH4. Thus, groundwater use may causes re-circulation of Arsenic. However, studies on the interaction between surface water areas and groundwater and on the role of surface water areas for solute transport with water cycle are a few. Therefore, we focused on these points and took water samples of river, pond and groundwater from four communities in suburban areas: two communities are located near the Red River and other two are far from the River. Also, columnar sediment samples of these ponds were taken and pore water was abstracted. Major dissolved ions, metals and stable isotopes of oxygen and hydrogen of water samples were analyzed. As for water cycle, from the correlation between δ18O and δD, the Red River water (after GNIR) were distributed along the LMWL (δD=8.2δ18O+14.1, calculated from precipitation (after GNIP)). On the other hand, although the pond waters in rainy season were distributed along the LMWL, that in dry season were distributed along the local evaporation line (LEL, slope=5.6). The LEL crossed with the LMWL at around the point of weighted mean values of precipitation in rainy season and of

  20. Preparation and Characteristics of SiOx Coated Carbon Nanotubes with High Surface Area

    Directory of Open Access Journals (Sweden)

    Doohwan Jung

    2012-06-01

    Full Text Available An easy method to synthesize SiOx coated carbon nanotubes (SiOx-CNT through thermal decomposition of polycarbomethylsilane adsorbed on the surface of CNTs is reported. Physical properties of SiOx-CNT samples depending on various Si contents and synthesis conditions are examined by X-ray diffraction (XRD, X-ray photoelectron spectroscopy (XPS, nitrogen isotherm, scanning electron microscope (SEM, and transmission electron microscope (TEM. Morphology of the SiOx-CNT appears to be perfectly identical to that of the pristine CNT. It is confirmed that SiOx is formed in a thin layer of approximately 1 nm thickness over the surface of CNTs. The specific surface area is significantly increased by the coating, because thin layer of SiOx is highly porous. The surface properties such as porosity and thickness of SiOx layers are found to be controlled by SiOx contents and heat treatment conditions. The preparation method in this study is to provide useful nano-hybrid composite materials with multi-functional surface properties.

  1. Loss aversion and mental accounting: The favorite-longshot bias in parimutuel betting

    OpenAIRE

    Qiu, Jianying

    2009-01-01

    Parimutuel betting markets are simpliï¬ ed ï¬ nancial markets, and can thus provide a clearer view of pricing issues which are more complicated elsewhere. Though empirical studies generally conclude that the parimutuel betting markets are surprisingly effcient, it is also found that for horses with lowest odds (favorites), market estimates of winning probabilities are smaller than objective winning probabilities; for horses with highest odds (longshot), the opposite is observed. This phenomen...

  2. Visualization of Lake Mead Surface Area Changes from 1972 to 2009

    Directory of Open Access Journals (Sweden)

    David M. Atkinson

    2012-06-01

    Full Text Available For most of the last decade, the south-western portion of the United States has experienced a severe and enduring drought. This has caused serious concerns about water supply and management in the region. In this research, 30 orthorectified Landsat satellite images from the United States Geological Service (USGS Earth Explorer archive were analyzed for the 1972 to 2009 period. The images encompassed Lake Mead (a major reservoir in this region and were examined for changes in water surface area. Decadal lake area minimums/maximums were achieved in 1972/1979, 1981/1988, 1991/1998, and 2009/2000. The minimum lake area extent occurred in 2009 (356.4 km2, while the maximum occurred in 1998 (590.6 km2. Variable trends in water level and lake area were observed throughout the analysis period, however progressively lower values were observed since 2000. The Landsat derived lake areas show a very strong relationship with actual measured water levels at the Hoover Dam. Yearly water level variations at the dam vary minimally from the satellite derived estimates. A complete (yearly record of satellite images may have helped to reduce the slight deviations in the time series.

  3. Surface deformation of active volcanic areas retrieved with the SBAS-DInSAR technique: an overview

    Directory of Open Access Journals (Sweden)

    G. Zeni

    2008-06-01

    Full Text Available This paper presents a comprehensive overview of the surface deformation retrieval capability of the Differential Synthetic Aperture Radar Interferometry (DInSAR algorithm, referred to as Small BAseline Subset (SBAS technique, in the context of active volcanic areas. In particular, after a brief description of the algorithm some experiments relevant to three selected case-study areas are presented. First, we concentrate on the application of the SBAS algorithm to a single-orbit scenario, thus considering a set of SAR data composed by images acquired on descending orbits by the European Remote Sensing (ERS radar sensors and relevant to the Long Valley caldera (eastern California area. Subsequently, we address the capability of the SBAS technique in a multipleorbit context by referring to Mt. Etna volcano (southern Italy test site, with respect to which two different ERS data set, composed by images acquired both on ascending and descending orbits, are available. Finally, we take advantage of the capability of the algorithm to work in a multi-platform scenario by jointly exploiting two different sets of SAR images collected by the ERS and the Environment Satellite (ENVISAT radar sensors in the Campi Flegrei caldera (southern Italy area. The presented results demonstrate the effectiveness of the algorithm to investigate the deformation field in active volcanic areas and the potential of the DInSAR methodologies within routine surveillance scenario.

  4. T-bet Activates Th1 Genes through Mediator and the Super Elongation Complex.

    Science.gov (United States)

    Hertweck, Arnulf; Evans, Catherine M; Eskandarpour, Malihe; Lau, Jonathan C H; Oleinika, Kristine; Jackson, Ian; Kelly, Audrey; Ambrose, John; Adamson, Peter; Cousins, David J; Lavender, Paul; Calder, Virginia L; Lord, Graham M; Jenner, Richard G

    2016-06-21

    The transcription factor T-bet directs Th1 cell differentiation, but the molecular mechanisms that underlie this lineage-specific gene regulation are not completely understood. Here, we show that T-bet acts through enhancers to allow the recruitment of Mediator and P-TEFb in the form of the super elongation complex (SEC). Th1 genes are occupied by H3K4me3 and RNA polymerase II in Th2 cells, while T-bet-mediated recruitment of P-TEFb in Th1 cells activates transcriptional elongation. P-TEFb is recruited to both genes and enhancers, where it activates enhancer RNA transcription. P-TEFb inhibition and Mediator and SEC knockdown selectively block activation of T-bet target genes, and P-TEFb inhibition abrogates Th1-associated experimental autoimmune uveitis. T-bet activity is independent of changes in NF-κB RelA and Brd4 binding, with T-bet- and NF-κB-mediated pathways instead converging to allow P-TEFb recruitment. These data provide insight into the mechanism through which lineage-specifying factors promote differentiation of alternative T cell fates. PMID:27292648

  5. T-bet Activates Th1 Genes through Mediator and the Super Elongation Complex

    Directory of Open Access Journals (Sweden)

    Arnulf Hertweck

    2016-06-01

    Full Text Available The transcription factor T-bet directs Th1 cell differentiation, but the molecular mechanisms that underlie this lineage-specific gene regulation are not completely understood. Here, we show that T-bet acts through enhancers to allow the recruitment of Mediator and P-TEFb in the form of the super elongation complex (SEC. Th1 genes are occupied by H3K4me3 and RNA polymerase II in Th2 cells, while T-bet-mediated recruitment of P-TEFb in Th1 cells activates transcriptional elongation. P-TEFb is recruited to both genes and enhancers, where it activates enhancer RNA transcription. P-TEFb inhibition and Mediator and SEC knockdown selectively block activation of T-bet target genes, and P-TEFb inhibition abrogates Th1-associated experimental autoimmune uveitis. T-bet activity is independent of changes in NF-κB RelA and Brd4 binding, with T-bet- and NF-κB-mediated pathways instead converging to allow P-TEFb recruitment. These data provide insight into the mechanism through which lineage-specifying factors promote differentiation of alternative T cell fates.

  6. Mating portfolios: bet-hedging, sexual selection and female multiple mating

    Science.gov (United States)

    Garcia-Gonzalez, Francisco; Yasui, Yukio; Evans, Jonathan P.

    2015-01-01

    Polyandry (female multiple mating) has profound evolutionary and ecological implications. Despite considerable work devoted to understanding why females mate multiply, we currently lack convincing empirical evidence to explain the adaptive value of polyandry. Here, we provide a direct test of the controversial idea that bet-hedging functions as a risk-spreading strategy that yields multi-generational fitness benefits to polyandrous females. Unfortunately, testing this hypothesis is far from trivial, and the empirical comparison of the across-generations fitness payoffs of a polyandrous (bet hedger) versus a monandrous (non-bet hedger) strategy has never been accomplished because of numerous experimental constraints presented by most ‘model’ species. In this study, we take advantage of the extraordinary tractability and versatility of a marine broadcast spawning invertebrate to overcome these challenges. We are able to simulate multi-generational (geometric mean) fitness among individual females assigned simultaneously to a polyandrous and monandrous mating strategy. Our approaches, which separate and account for the effects of sexual selection and pure bet-hedging scenarios, reveal that bet-hedging, in addition to sexual selection, can enhance evolutionary fitness in multiply mated females. In addition to offering a tractable experimental approach for addressing bet-hedging theory, our study provides key insights into the evolutionary ecology of sexual interactions. PMID:25411448

  7. Characteristics of surface O{sub 3} over Qinghai Lake area in Northeast Tibetan Plateau, China

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Zhenxing, E-mail: zxshen@mail.xjtu.edu.cn [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China); Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Cao, Junji [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Zhang, Leiming [Air Quality Research Division, Environment Canada, Toronto (Canada); Zhao, Zhuzi [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Dong, Jungang [School of Architecture, Xi' an University of Architecture and Technology, Xi' an 710055 (China); Wang, Linqing [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China); Wang, Qiyuan; Li, Guohui; Liu, Suixin [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Zhang, Qian [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China)

    2014-12-01

    Surface O{sub 3} was monitored continuously during Aug. 12, 2010 to Jul. 21, 2011 at a high elevation site (3200 m above sea level) in Qinghai Lake area (36°58′37″N, 99°53′56″E) in Northeast Tibetan Plateau, China. Daily average O{sub 3} ranged from 21.8 ppbv to 65.3 ppbv with an annual average of 41.0 ppbv. Seasonal average of O{sub 3} followed a decreasing order of summer > autumn > spring > winter. Diurnal variations of O{sub 3} showed low concentrations during daytime and high concentrations during late night and early morning. An intensive campaign was also conducted during Aug. 13–31, 2010 to investigate correlations between meteorological or chemical conditions and O{sub 3}. It was found that O{sub 3} was poorly correlated with solar radiation due to the insufficient NO{sub x} in the ambient air, thus limiting O{sub 3} formation under strong solar radiation. In contrast, high O{sub 3} levels always coincided with strong winds, suggesting that stratospheric O{sub 3} and long range transport might be the main sources of O{sub 3} in this rural area. Back-trajectory analysis supported this hypothesis and further indicated the transport of air masses from northwest, northeast and southeast directions. - Highlights: • Surface O{sub 3} was measured in Qinghai Lake area in Northeast Tibetan Plateau, China. • The O{sub 3} chemical formation was under a strong NOx-limited in Qinghai Lake areas. • Stratospheric O{sub 3} and transport might be the main sources of O{sub 3} in this area.

  8. Characteristics of surface O3 over Qinghai Lake area in Northeast Tibetan Plateau, China

    International Nuclear Information System (INIS)

    Surface O3 was monitored continuously during Aug. 12, 2010 to Jul. 21, 2011 at a high elevation site (3200 m above sea level) in Qinghai Lake area (36°58′37″N, 99°53′56″E) in Northeast Tibetan Plateau, China. Daily average O3 ranged from 21.8 ppbv to 65.3 ppbv with an annual average of 41.0 ppbv. Seasonal average of O3 followed a decreasing order of summer > autumn > spring > winter. Diurnal variations of O3 showed low concentrations during daytime and high concentrations during late night and early morning. An intensive campaign was also conducted during Aug. 13–31, 2010 to investigate correlations between meteorological or chemical conditions and O3. It was found that O3 was poorly correlated with solar radiation due to the insufficient NOx in the ambient air, thus limiting O3 formation under strong solar radiation. In contrast, high O3 levels always coincided with strong winds, suggesting that stratospheric O3 and long range transport might be the main sources of O3 in this rural area. Back-trajectory analysis supported this hypothesis and further indicated the transport of air masses from northwest, northeast and southeast directions. - Highlights: • Surface O3 was measured in Qinghai Lake area in Northeast Tibetan Plateau, China. • The O3 chemical formation was under a strong NOx-limited in Qinghai Lake areas. • Stratospheric O3 and transport might be the main sources of O3 in this area

  9. Influence of Alkali Treatment on the Surface Area of Aluminium Dross

    Directory of Open Access Journals (Sweden)

    N. S. Ahmad Zauzi

    2016-01-01

    Full Text Available Aluminium dross is an industrial waste from aluminium refining industry and classified as toxic substances. However, the disposal of dross as a waste is a burden to aluminium manufacturer industries due to its negative effects to the ecosystem, surface, and ground water. Therefore the purpose of this study is to evaluate the influence of sodium hydroxide (NaOH on the surface area and pore size of aluminium dross. There were 3 stages in the treatment activities, which were leaching, precipitation, and calcination process. The optimum result from this study was the surface area of aluminium dross increases from 10.1 m2/g up to 80.0 m2/g at 40°C, 1% NaOH, and 15-minute reaction time. Thus, aluminium dross has a potential to be converted into other useful material such as catalyst and absorbent. The benefit of this research is that the hazardous industrial waste can be turned into wealth to be used in other applications such as in catalytic activities and absorber in waste water treatment. Further investigation on the physicochemical of aluminium dross with different acid or alkali should be conducted to get deeper understanding on the aluminium dross as a catalyst-type material.

  10. Seasonal Distribution of Organic Carbon in the Surface Sediments of the Terengganu Nearshore Coastal Area

    Directory of Open Access Journals (Sweden)

    S. Hasrizal

    2009-01-01

    Full Text Available Problem statement: The distribution of organic carbon in the surface sediment is a crucial indicator for current productivity in the ocean especially in the nearshore area. The difference of organic carbon in the surface sediment reflects the influence of current movement on the bottom sediment. Approach: This study was carried out to oversee the difference of organic carbon distribution during pre and post-monsoon seasons. For the purpose of the study, 42 surface sediments in the Terengganu near shore area were collected and determined for organic carbon by using the wet dichromate acid method. Results: The concentration of organic carbon was significantly different between the seasons showing a relatively higher content during pre-monsoon seasons. In this study, the average concentration of organic carbon in pre-monsoon was 1.14±0.29% and varied from 0.60-1.80%. Meanwhile during post-monsoon seasons, the average concentration of organic carbon was slightly lower to 0.82±0.23% and ranged from 0.24-1.32%. Conclusion: Generally, the average concentration of organic carbon in South China Sea was low compared to the occurrence in riverine environment as well as the mangrove environment.

  11. 33 CFR 334.1180 - Strait of Juan de Fuca, Wash.; air-to-surface weapon range, restricted area.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 3 2010-07-01 2010-07-01 false Strait of Juan de Fuca, Wash.; air-to-surface weapon range, restricted area. 334.1180 Section 334.1180 Navigation and Navigable... REGULATIONS § 334.1180 Strait of Juan de Fuca, Wash.; air-to-surface weapon range, restricted area. (a)...

  12. Where Does the Formula Come from? Students Investigating Total Surface Areas of a Pyramid and Cone Using Models and Technology

    Science.gov (United States)

    Obara, Samuel

    2009-01-01

    Spatial reasoning is a skill that needs to be developed in students as it is important in geometry for determining total surface areas and volumes of 3-dimensional shapes (Liedtke, 1995). Simply teaching children the formulae, in this case for finding total surface areas, can limit them in understanding mathematics conceptually (Bonotto, 2003).…

  13. The Effects of 3D-Representation Instruction on Composite-Solid Surface-Area Learning for Elementary School Students

    Science.gov (United States)

    Sung, Yao-Ting; Shih, Pao-Chen; Chang, Kuo-En

    2015-01-01

    Providing instruction on spatial geometry, specifically how to calculate the surface areas of composite solids, challenges many elementary school teachers. Determining the surface areas of composite solids involves complex calculations and advanced spatial concepts. The goals of this study were to build on students' learning processes for…

  14. Catalytic Chemical Vapor Deposition Synthesis of Carbon Aerogels of High-Surface Area and Porosity

    Directory of Open Access Journals (Sweden)

    Armando Peña

    2012-01-01

    Full Text Available In this work carbon aerogels were synthesized by catalytic chemical vapor deposition method (CCVD. Ferrocene were employed as a source both of catalytic material (Fe and of carbon. Gaseous hydrogen and argon were used as reductant and carrier gas, respectively. The products of reaction were collected over alumina. The morphology and textural properties of the soot produced in the reaction chamber were investigated using Scanning Electron Microscopy, High-Resolution Transmission Electron Microscopy, X-ray photoelectron spectroscopy, and N2 physisorption (BET and BHJ methods. After the evaluation of the porous structure of the synthesized products, 780 ± 20 m2/g of SBET and 0.55 ± 0.02 cm3/g of VBJH were found. The presence of iron carbide and the partial oxidation of carbon nanostructures were revealed by XPS.

  15. Paramagnetic Metal—Antiferromagnetic Insulator Transition in π-d System λ-BETS2FeCl4, BETS = Bis(ethylenedithiotetraselenafulvalene

    Directory of Open Access Journals (Sweden)

    Hiroshi Akiba

    2012-07-01

    Full Text Available Quasi-two-dimensional organic conductor λ-BETS2FeCl4 (BETS = bis(ethylenedithiotetraselenafulvalene transforms from a paramagnetic metal (PM to an antiferromagnetic insulator (AFI at a transition temperature, TMI, of 8.3 K under zero magnetic field. To understand the mechanism of this PM-AFI phase transition, we studied the thermodynamic properties of λ-BETS2FeCl4. We observed, below TMI, a six-level Schottky hump in its specific heat and a broad shoulder in its magnetic susceptibility. Just below the transition temperature TMI, about 80% of 3d spin degree of freedom is sustained. These temperature dependences clarify that π and 3d spins do not cooperatively form the AF order at TMI. In λ-BETS2FexGa1−xCl4 system, the increasing Fe 3d spin density enhances the internal magnetic field caused by π spin antiferromagnetic (AF ordering, although the 3d spin itself maintains large entropy against the AF ordering. It was confirmed that the Fe 3d spin provided favorable conditions for this mysterious PM-AFI phase transition in the π electron system. We propose that this phase transition originates from the magnetic anisotropy introduced by the π-d interaction, which suppressed the low dimensional fluctuation in the π spin system.

  16. Study of the nitric acid influence on the production of Ce O2 with high specific surface area

    International Nuclear Information System (INIS)

    The cerium oxide (Ce O2) main characteristics for use as catalyst in an exhaust gases purification system are: high specific surface area (approximately 30 m2/g after calcination at 800 deg C/ 2 hs), and thermal stability. The Ce O2 powders obtained by conventional route, i.e., precipitation, and submitted high temperature (800 deg C) heat treatments, showed low specific surface area. In this work nitric acid effects on the Ce O2 surface area values were investigated. The variables studied were nitric acid concentration, humidity content in the raw material, re pulp after leaching, addition of hydrogen peroxide (H2 O2) and starting material specific surface area. By this process, it was possible to obtain powders with specific surface area larger than 40 m2/g, after treatment at 800 deg C during two hours. (author)

  17. Can formaldehyde column densities be used to estimate near-surface ozone in urban areas?

    Science.gov (United States)

    Schroeder, Jason

    2016-04-01

    Understanding pollutant exposure for populations in urban areas requires air quality monitoring at a finer scale than can be reasonably provided by surface networks. Satellite measurements of short-lived trace gases could potentially help shape our understanding of the distribution of near-surface ozone throughout entire regions, thus aiding the development of more effective mitigation strategies. In this work, the extensive vertical profiling performed by aircraft in support of NASA's DISCOVER-AQ field campaign is used to examine the relationship between formaldehyde column measurements and near-surface ozone. At large spatial and temporal scales, a fairly strong relationship exists between column formaldehyde and near-surface ozone, but this relationship often weakens at smaller spatial and temporal scales. The cause of these small-scale discrepancies was determined to be an artifact of the difference in lifetimes between ozone and formaldehyde. While ozone has a long lifetime (multiple days) and tends to accumulate throughout the day, formaldehyde has a very short lifetime (a couple hours) and tends to reflect the local hydrocarbon oxidation environment. In Maryland, where biogenic emissions dominate the hydrocarbon mix, a stronger correlation between ozone and formaldehyde was seen than in Texas, where anthropogenic emissions dominated the hydrocarbon mix. This is because in Maryland, while ozone was accumulating throughout the day, formaldehyde was also increasing in conjunction with changes in biogenic emissions. When data are segregated spatially and averaged over the duration of each campaign, a clear trend can be seen between column formaldehyde and surface ozone measurements. While not useful for day-to-day monitoring, this could be useful for long-term exposure estimates and could help facilitate the re-distribution of surface monitoring sites.

  18. Geomorphometric analysis of fine-scale morphology for extensive areas: a new surface-texture operator

    Science.gov (United States)

    Trevisani, Sebastiano; Rocca, Michele

    2014-05-01

    The application of geomorphometric analysis to high resolution digital terrain models (HRDTM) amplifies our capability to characterize and interpret fine-scale solid earth surface morphology. In this context it is possible to analyze fine-scale morphology in term of surface texture (e.g. Trevisani, 2012; Lucieer, 2005) and retrieve information linked to the different geomorphic processes and factors; this kind of analysis has an interesting potential to be exploited in the context of quantitative geomorphologic/geologic interpretation and geo-engineering. We developed a multiscale texture operator capable to synthetize the main characteristics of local surface texture in an efficient way. The proposed operator can be viewed as an hybrid between classical geostatistical spatial continuity indexes (e.g. variogram, Atkinson, 2000) and the well-known operator based on (rotation invariant) local binary patterns (Ojala, 2002). An important characteristic of the operator is to derive information on surface texture in an easily interpretable form so as to facilitate its use by experts for the interpretation of geomorphic processes and factors. Moreover this surface texture operator could be used for the derivation of more complex and ad-hoc surface texture indexes. We present the application of the operator in the analysis of different HRDTMs, mainly in the context of alpine environment. A particular interesting example is the application of the surface texture analysis in an extensive area (hundreds of km2), including also urbanized zones, and the evaluation of potential links between surface texture and lithological and geo-structural factors. References Atkinson, P.M. & Lewis, P. 2000, "Geostatistical classification for remote sensing: An introduction", Computers and Geosciences, vol. 26, no. 4, pp. 361-371. Lucieer, A., Stein, A., 2005. Texture-based landform segmentation of LiDAR imagery. International Journal of Applied Earth Observation and Geoinformation 6, 261

  19. Energy fluxes and surface characteristics over a cultivated area in Benin: daily and seasonal dynamics

    Directory of Open Access Journals (Sweden)

    O. Mamadou

    2013-08-01

    Full Text Available Latent and sensible heat fluxes are known as key factors in the West African monsoon dynamics. However, few long-term observations of these land surface fluxes are available to document their impact in the climate variability of this region. The present study took advantage of the Sudanian site of the AMMA-CATCH (African Monsoon Multidisciplinary Analysis – Coupling the Tropical Atmosphere and Hydrological Cycle observatory where turbulent fluxes were measured using the eddy covariance technique. One full year of data of energy budget over a cultivated site located in northern Benin was examined. Four contrasted seasons were identified and detailed focusing on their corresponding daily cycles. The flux partitioning was investigated through the evaporative fraction (EF and the Bowen ratio (β at both seasonal and daily scales. Finally, the surface conductance (Gs and the decoupling coefficient (Ω were calculated and confronted with specific bare soil or canopy models to identify the main processes for each season. The results pointed out the contrasted seasonal variations of sensible and latent heat fluxes due to changing atmospheric and surface conditions. During the wet season, surface conditions barely affected EF, which remained in steady regime (EF = 0.75, while latent heat flux was dominant and β was about 0.4. During the transitional periods, both EF and β were highly variable. A low but significant evapotranspiration was measured in the dry season (EF = 0.08 attributed to few scattered bushes, distributed on a bare area, possibly fed by the water table. Nevertheless, sensible heat fluxes were largely dominant (β ~ 10 during dry season. Moreover, β revealed the ligneous vegetation flowering dynamics during the dry season. The results also showed a strong surface atmosphere coupling, which suggests a systematic mixing of the flow within the canopy with the atmospheric surface layer whatever the atmospheric conditions and vegetation

  20. On the extension of the sensitive area of an extensive air shower surface array

    CERN Document Server

    Kh, H Hedayati

    2016-01-01

    A large distance between true and reconstructed core locations of an extensive air shower (EAS) may results in great systematic mis-estimation of EAS parameters. The reconstruction of those EASs whose core locations are outside the boundary of a surface array (outside EAS (OEAS)) results in a large distance of the reconstructed core location from the true one, especially when the true core is far outside the array. Although it may not be mentioned, the identification of OEASs is a necessary and important step in the reconstruction procedure of an EAS. In this paper, an existing technique is optimized for the identification of OEASs. The simultaneous use of this technique and a recently developed approach for reconstructing the core location of an EAS can significantly increase the sensitive area of a surface array.

  1. Functionality in Electrospun Nanofibrous Membranes Based on Fiber’s Size, Surface Area, and Molecular Orientation

    Directory of Open Access Journals (Sweden)

    Akihiko Tanioka

    2011-08-01

    Full Text Available Electrospinning is a versatile method for forming continuous thin fibers based on an electrohydrodynamic process. This method has the following advantages: (i the ability to produce thin fibers with diameters in the micrometer and nanometer ranges; (ii one-step forming of the two- or three-dimensional nanofiber network assemblies (nanofibrous membranes; and (iii applicability for a broad spectrum of molecules, such as synthetic and biological polymers and polymerless sol-gel systems. Electrospun nanofibrous membranes have received significant attention in terms of their practical applications. The major advantages of nanofibers or nanofibrous membranes are the functionalities based on their nanoscaled-size, highly specific surface area, and highly molecular orientation. These functionalities of the nanofibrous membranes can be controlled by their fiber diameter, surface chemistry and topology, and internal structure of the nanofibers. This report focuses on our studies and describes fundamental aspects and applications of electrospun nanofibrous membranes.

  2. Changes in porosity, permeability and surface area during rock dissolution: effects of mineralogical heterogeneity

    CERN Document Server

    Min, Ting; Chen, Li; Kang, Qinjun; Tao, Wen-Quan

    2015-01-01

    Effects of heterogeneity of mineral distribution and reaction rate on the rock dissolution process are investigated using a pore-scale reactive transport model based on the lattice Boltzmann method. Coupled fluid flow, species transport, chemical reaction and solid structure alternation due to dissolution are simulated. Effects of mineral distributions and chemical heterogeneity on the dissolution behaviors and evolutions of hydrologic properties are studied under different reactive transport conditions. Simulation results show that the coupling between advection, diffusion and reaction as well as the mineralogical heterogeneity leads to complex reactive transport behaviors and complicated temporal evolutions of hydrologic properties including porosity, permeability and reactive surface. Diverse relationships between surface area and volume are predicted, which cannot be described by simple models such as the spherical-grain model. Porosity-permeability relationships also differ under different mineral distri...

  3. Large-Area, Highly Ordered Array of Graphitic Carbon Materials Using Surface Active Chitosan Prepatterns.

    Science.gov (United States)

    Baek, Youn-Kyoung; Kim, Dae Woo; Yang, Seung Bo; Lee, Jung-Goo; Kim, Young Kuk; Jung, Hee-Tae

    2015-02-01

    We demonstrate that chitosan prepatterns can generate not only highly periodic DNA pattern but also various types of graphitic carbon materials such as single-walled carbon nanotubes (SWNTs), graphene oxide (GO) and reduced graphene oxide (RGO). Scanning electron microscopy (SEM), fluorescence imaging and Raman spectroscopic results revealed that the graphitic carbon materials were selectively deposited on the surface of the periodic chitosan patterns by the electrostatic interaction between protonated amine groups of chitosan and the negative charged carbon materials. One proof-of-concept application of the system to the fabrication of electrical devices based on the micropatterns of SWNTs and RGO was also demonstrated. The strategy to use highly surface active chitosan pattern that can easily fabricate highly periodic pattern via a variety of lithographic tools may pave the way for the production of periodic arrays of graphitic carbon materials for large area device integration. PMID:26353637

  4. Replication fidelity assessment of large area sub-μm structured polymer surfaces using scatterometry

    International Nuclear Information System (INIS)

    The present study addresses one of the key challenges in the product quality control of transparent structured polymer substrates, the replication fidelity of sub-μm structures over a large area. Additionally the work contributes to the development of new techniques focused on in-line characterization of large nanostructured surfaces using scatterometry. In particular an approach to quantify the replication fidelity of high volume manufacturing processes such as polymer injection moulding is presented. Both periodic channels and semi-spherical structures were fabricated on nickel shims used for later injection moulding of Cyclic-olefin-copolymer (COC) substrate were the sub-μm features where ultimately transferred. The scatterometry system was validated using calibrated atomic force microscopy measurements and a model based on scalar diffraction theory employed to calculate the expected angular distribution of the reflected and the transmitted intensity for the nickel surfaces and structured COC and, respectively. (paper)

  5. Topographic Effects on the Surface Emissivity of a Mountainous Area Observed by a Spaceborne Microwave Radiometer

    Science.gov (United States)

    Pulvirenti, Luca; Pierdicca, Nazzareno; Marzano, Frank S.

    2008-01-01

    A simulation study to understand the influence of topography on the surface emissivity observed by a satellite microwave radiometer is carried out. We analyze the effects due to changes in observation angle, including the rotation of the polarization plane. A mountainous area in the Alps (Northern Italy) is considered and the information on the relief extracted from a digital elevation model is exploited. The numerical simulation refers to a radiometric image, acquired by a conically-scanning radiometer similar to AMSR-E, i.e., flying at 705 km of altitude with an observation angle of 55°. To single out the impact on surface emissivity, scattering of the radiation due to the atmosphere or neighboring elevated surfaces is not considered. C and X bands, for which atmospheric effects are negligible, and Ka band are analyzed. The results indicate that the changes in the local observation angle tend to lower the apparent emissivity of a radiometric pixel with respect to the corresponding flat surface characteristics. The effect of the rotation of the polarization plane enlarges (vertical polarization), or attenuates (horizontal polarization) this decrease. By doing some simplifying assumptions for the radiometer antenna, the conclusion is that the microwave emissivity at vertical polarization is underestimated, whilst the opposite occurs for horizontal polarization, except for Ka band, for which both under- and overprediction may occur. A quantification of the differences with respect to a flat soil and an approximate evaluation of their impact on soil moisture retrieval are yielded.

  6. Surface Wave Plasma Driven by Ring Dielectric Line for Producing Dense, Large Area, Uniform Plasmas

    Science.gov (United States)

    Matsumoto, Naoki

    1999-10-01

    Surface Wave excited Plasma (SWP), has been put into practice as a plasma source for the fabrication process of ULSI and LCD devices. This plasma has several advanced features: 1) Very high electron density with relatively low electron temperature; 2) Very uniform plasma density over large areas; 3) Operation from gas pressure of few mT to the order of thousands of mT. We present a newly developed microwave driven surface wave plasma source called a Ring Dielectric Line (RDL). The RDL is a metal ring wave-guide, filled with dielectric material, driven by a microwave. Slots for coupling the microwave power are symmetrically arrayed under the dielectric, facing towards the processing chamber. The electromagnetic power generates an electromagnetic surface wave, which in turn excites a plasma surface wave on the bottom side of the quartz plate in the processing chamber. In terms of its plasma characteristics, the uniformly distributed argon plasma with wide range of pressure of 20, 40 and 80mT as well as with high density about 5×10^17/m^3 over the cutoff density was observed. The electron temperature was about 2eV. In addition, in the 5000-minutes continuous running test for C_4F8 etching, it achieved repeatability of +/-0.7% and non-uniformity of about +/-3%.

  7. Luminosity and surface brightness distribution of K-band galaxies from the UKIDSS Large Area Survey

    CERN Document Server

    Smith, Anthony J; Cross, Nicholas J G

    2008-01-01

    We present luminosity and surface brightness distributions of 36,663 galaxies with K-band photometry from the UKIRT Infrared Deep Sky Survey (UKIDSS) Large Area Survey (LAS), Data Release 3 and optical photometry from Data Release 5 of the Sloan Digital Sky Survey (SDSS). Various features and limitations of the new UKIDSS data are examined, such as a problem affecting Petrosian magnitudes of extended sources. Selection limits in K- and r-band magnitude, K-band surface brightness and K-band radius are included explicitly in the 1/Vmax estimation of the space density and luminosity function. The bivariate brightness distribution in K-band absolute magnitude and surface brightness is presented and found to display a clear luminosity-surface brightness correlation that flattens at high luminosity and broadens at low luminosity, consistent with similar analyses at optical wavelengths. Best fitting Schechter function parameters for the K-band luminosity function are found to be M*-5log h=-23.17 +/- 0.04, alpha=-0.8...

  8. Protonation Dynamics on Lipid Nanodiscs: Influence of the Membrane Surface Area and External Buffers.

    Science.gov (United States)

    Xu, Lei; Öjemyr, Linda Näsvik; Bergstrand, Jan; Brzezinski, Peter; Widengren, Jerker

    2016-05-10

    Lipid membrane surfaces can act as proton-collecting antennae, accelerating proton uptake by membrane-bound proton transporters. We investigated this phenomenon in lipid nanodiscs (NDs) at equilibrium on a local scale, analyzing fluorescence fluctuations of individual pH-sensitive fluorophores at the membrane surface by fluorescence correlation spectroscopy (FCS). The protonation rate of the fluorophores was ∼100-fold higher when located at 9- and 12-nm diameter NDs, compared to when in solution, indicating that the proton-collecting antenna effect is maximal already for a membrane area of ∼60 nm(2). Fluorophore-labeled cytochrome c oxidase displayed a similar increase when reconstituted in 12 nm NDs, but not in 9 nm NDs, i.e., an acceleration of the protonation rate at the surface of cytochrome c oxidase is found when the lipid area surrounding the protein is larger than 80 nm(2), but not when below 30 nm(2). We also investigated the effect of external buffers on the fluorophore proton exchange rates at the ND membrane-water interfaces. With increasing buffer concentrations, the proton exchange rates were found to first decrease and then, at millimolar buffer concentrations, to increase. Monte Carlo simulations, based on a simple kinetic model of the proton exchange at the membrane-water interface, and using rate parameter values determined in our FCS experiments, could reconstruct both the observed membrane-size and the external buffer dependence. The FCS data in combination with the simulations indicate that the local proton diffusion coefficient along a membrane is ∼100 times slower than that observed over submillimeter distances by proton-pulse experiments (Ds ∼ 10(-5)cm(2)/s), and support recent theoretical studies showing that proton diffusion along membrane surfaces is time- and length-scale dependent. PMID:27166807

  9. Automated Generation of Digital Terrain Model using Point Clouds of Digital Surface Model in Forest Area

    Directory of Open Access Journals (Sweden)

    Yoshikazu Kamiya

    2011-04-01

    Full Text Available At present, most of the digital data acquisition methods generate Digital Surface Model (DSM and not a Digital Elevation Model (DEM. Conversion from DSM to DEM still has some drawbacks, especially the removing of off terrain point clouds and subsequently the generation of DEM within these spaces even though the methods are automated. In this paper it was intended to overcome this issue by attempting to project off terrain point clouds to the terrain in forest areas using Artificial Neural Networks (ANN instead of removing them and then filling gaps by interpolation. Five sites were tested and accuracies assessed. They all give almost the same results. In conclusion, the ANN has ability to obtain the DEM by projecting the DSM point clouds and greater accuracies of DEMs were obtained. If the size of the hollow areas resulting from the removal of DSM point clouds are larger the accuracies are reduced.

  10. Identification of motility clusters per area in surfaces colonized by Pseudomonas aeruginosa

    International Nuclear Information System (INIS)

    The biofilms are involved in pathogenesis and antibiotic persistence and resistance. The number of cells of a given species that will adhere to surfaces depends not only on the affinity of the cells but also on their number available for attachment. Therefore, the quick identification of the motile microorganism's area should be of great interest. The analysis of bacterial spatial patterns at the initial stage of biofilm formation is very important to know the success of the bacterial colonization. We propose a post processing method capable to distinguish motile microorganisms area of colonization in dynamic speckle images by applying Mathematical Morphologic techniques. The methodology would be effective for segmenting, detecting and describing patterns of colonization known not to be completely spatially random. The presented method is fast, reproducible, convenient, robust, and can be used to control the pattern, spacing, and orientation between colonies of different bacteria in order to prevent biofilm development.

  11. Radioecological state of some surface water systems of contaminated areas of both Gomel and Mogilev Regions

    International Nuclear Information System (INIS)

    The radioecological situation of different ecosystems of Belarus and their components has been analysed. Such components of the surface water ecosystems as water, suspensions, sediments and soils of water-collection areas were used for the investigation of the content of cesium 137 and strontium 90. The received data were given since 1990. The content of cesium 137 and strontium 90 in the components of water ecosystems was counted in the laboratory conditions by means of standard methods of beta radiometry, semiconductor gamma spectrometry and radiochemistry. The error of measurement of radioactivity was not higher than 25 and 35% for cesium 137 and strontium 90 accordingly. Water ecosystems were distinguished by the state of contamination of water-collection areas and hydrological parameters. These and some other reasons considered in the article influence on the character of cesium 137 and strontium 90 behaviour in water ecosystems

  12. Vector cavity solitons in broad area Vertical-Cavity Surface-Emitting Lasers.

    Science.gov (United States)

    Averlant, Etienne; Tlidi, Mustapha; Thienpont, Hugo; Ackemann, Thorsten; Panajotov, Krassimir

    2016-01-01

    We report the experimental observation of two-dimensional vector cavity solitons in a Vertical-Cavity Surface-Emitting Laser (VCSEL) under linearly polarized optical injection when varying optical injection linear polarization direction. The polarization of the cavity soliton is not the one of the optical injection as it acquires a distinct ellipticity. These experimental results are qualitatively reproduced by the spin-flip VCSEL model. Our findings open the road to polarization multiplexing when using cavity solitons in broad-area lasers as pixels in information technology. PMID:26847004

  13. octanol/water partition coefficient using solvation free energy and solvent-accessible surface area

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The regression model for octanol/water partition coefficients (Kow ), is founded with only two molecular descriptors available through quantum chemical calculations: solvation free energy (△ Gs ), and solvent-accessible surface area (SASA). For the properties of 47 organic compounds from 17 types, the model gives a oonection coefficient (adjusted for degrees of freedom) of 0.959 and a standard error of 0.277 log unit. It is a suitable way to predict the partition properties that are related to solute-solvent interactions in the water phase.

  14. Turbostratic boron nitride coated on high-surface area metal oxide templates

    DEFF Research Database (Denmark)

    Klitgaard, Søren Kegnæs; Egeblad, Kresten; Brorson, M.;

    2007-01-01

    Boron nitride coatings on high-surface area MgAl2O4 and Al2O3 have been synthesized and characterized by transmission electron microscopy and by X-ray powder diffraction. The metal oxide templates were coated with boron nitride using a simple nitridation in a flow of ammonia starting from ammonium...... borate adsorbed on MgAl2O4 or gamma-Al2O3. This procedure resulted in the formation of a turbostratic boron nitride film with a thickness of a few individual BN layers....

  15. Surface area of lipid membranes regulates the DNA-binding capacity of cationic liposomes

    Science.gov (United States)

    Marchini, Cristina; Montani, Maura; Amici, Augusto; Pozzi, Daniela; Caminiti, Ruggero; Caracciolo, Giulio

    2009-01-01

    We have applied electrophoresis on agarose gels to investigate the DNA-binding capacity of cationic liposomes made of cationic DC-cholesterol and neutral dioleoylphosphatidylethanolamine as a function of membrane charge density and cationic lipid/DNA charge ratio. While each cationic liposome formulation exhibits a distinctive DNA-protection ability, here we show that such a capacity is universally regulated by surface area of lipid membranes available for binding in an aspecific manner. The relevance of DNA protection for gene transfection is also discussed.

  16. Nitrogen-doped porous carbon with an ultrahigh specific surface area for superior performance supercapacitors

    Science.gov (United States)

    Long, Chao; Zhuang, Jianle; Xiao, Yong; Zheng, Mingtao; Hu, Hang; Dong, Hanwu; Lei, Bingfu; Zhang, Haoran; Liu, Yingliang

    2016-04-01

    Owing to its abundant nitrogen content, silk cocoon is a promising precursor for the synthesis of Nitrogen-doped porous carbon (N-PC). Using a simple staged KOH activation, the prepared sample displays particular nanostructure with ultrahigh specific surface area (3841 m2 g-1) and appropriate pore size, providing favorable pathways for transportation and penetration of electrolyte ions. Additionally, the doped nitrogen atoms ensure the samples with pseudocapacitive behavior. Those special characteristics endow N-PCs with high capacity, low resistance, and long-term stability, indicating a wonderful potential for application in energy-storage devices.

  17. Measurement of surface area of biological structures, based on 3D microscopic image data

    Czech Academy of Sciences Publication Activity Database

    Kubínová, Lucie; Janáček, Jiří

    Vol. 1. Berlin : Springer, 2008 - (Luysberg, M.; Tillman, K.; Weirich, T.), s. 785-786 ISBN 978-3-540-85154-7. [European Microscopy Congress EMC 2008 /14./. Aachen (DE), 01.09.2008-05.09.2008] R&D Projects: GA MŠk(CZ) LC06063; GA AV ČR(CZ) IAA600110507; GA AV ČR(CZ) IAA100110502; GA AV ČR(CZ) IAA500200510 Institutional research plan: CEZ:AV0Z50110509 Keywords : surface area * stereology * confocal microscopy Subject RIV: EA - Cell Biology

  18. The Effect of Surface Area of Implant on Bonding Strength between Implant and Bone

    Energy Technology Data Exchange (ETDEWEB)

    Cho, S.A. [Kyungbook National University, Taegu (Korea, Republic of)

    1998-07-01

    The effect of the surface area of implant on degree of osseointegration was investigated by putting the 10 grade- II titanium screw implants into 10 isogenic rabbits tibia. Implants were divided in 2 groups into 3mm diameter and 5 mm diameter. After 6 weeks, animals were sacrificed and removal torques were measured with Tohnichi 15 BTG-N Torque Gauge Manometer. The results were as follows : The removal torques was higher in 5 mm diameter group than the 3 mm diameter group.(p=0.008). (author). 13 refs., 1 tabs.

  19. Understanding the growth mechanism of carbon nanotubes via the ``cluster volume to surface area" model

    Science.gov (United States)

    Mandati, Sreekanth; Kunstmann, Jens; Boerrnert, Felix; Schoenfelder, Ronny; Ruemmeli, Mark; Kar, Kamal K.; Cuniberti, Gianaurelio

    2010-03-01

    The influence of mixed catalysts for the high yield production of carbon nanotubes (CNTs) has been studied systematically. Based on extensive experimental data a ``Catalyst Volume to Surface Area'' (CVSA) model was developed to understand the influence of the process parameters on the yield and CNT diameter distribution [1]. In our study, we present a refined version of the CVSA model developed by combining experiments and simulations. We discuss our current understanding of the growth mechanism and how the model might be used to increase CNT yields by using mixed catalysts.[4pt] [1] S. Tetali et al., ACS Nano (2009), DOI: 10.1021/nn9012548.

  20. High specific surface area carbon nanotubes from catalytic chemical vapor deposition process

    OpenAIRE

    Bacsa, Revathi; Laurent, Christophe; Peigney, Alain; Bacsa, Wolfgang; Vaugien, Thibaud; Rousset, Abel

    2000-01-01

    A carbon nanotube specimen with a carbon content of 83 wt.% (95 vol.%) and a specific surface area equal to 790 m2/g (corresponding to 948 m2/g of carbon) is prepared by a catalytic chemical vapor deposition method. The nanotubes, 90% of which are single- and double-walled, are individual rather than in bundles. High-resolution electron microscopy shows a diameter distribution in the range 0.8-5 nm and Raman spectroscopy shows a high proportion of tubular carbon. Both techniques reveal a maxi...

  1. Surface water areas significantly impacted 2014 dengue outbreaks in Guangzhou, China.

    Science.gov (United States)

    Tian, Huaiyu; Huang, Shanqian; Zhou, Sen; Bi, Peng; Yang, Zhicong; Li, Xiujun; Chen, Lifan; Cazelles, Bernard; Yang, Jing; Luo, Lei; Jing, Qinlong; Yuan, Wenping; Pei, Yao; Sun, Zhe; Yue, Tianxiang; Kwan, Mei-Po; Liu, Qiyong; Wang, Ming; Tong, Shilu; Brownstein, John S; Xu, Bing

    2016-10-01

    Dengue transmission in urban areas is strongly influenced by a range of biological and environmental factors, yet the key drivers still need further exploration. To better understand mechanisms of environment-mosquito-urban dengue transmission, we propose an empirical model parameterized and cross-validated from a unique dataset including viral gene sequences, vector dynamics and human dengue cases in Guangzhou, China, together with a 36-year urban environmental change maps investigated by spatiotemporal satellite image fusion. The dengue epidemics in Guangzhou are highly episodic and were not associated with annual rainfall over time. Our results indicate that urban environmental changes, especially variations in surface area covered by water in urban areas, can substantially alter the virus population and dengue transmission. The recent severe dengue outbreaks in Guangzhou may be due to the surge in an artificial lake construction, which could increase infection force between vector (mainly Aedes albopictus) and host when urban water area significantly increased. Impacts of urban environmental change on dengue dynamics may not have been thoroughly investigated in the past studies and more work needs to be done to better understand the consequences of urbanization processes in our changing world. PMID:27336234

  2. Spatio-Temporal Modelling of Dust Transport over Surface Mining Areas and Neighbouring Residential Zones

    Directory of Open Access Journals (Sweden)

    Eva Gulikova

    2008-06-01

    Full Text Available Projects focusing on spatio-temporal modelling of the living environment need to manage a wide range of terrain measurements, existing spatial data, time series, results of spatial analysis and inputs/outputs from numerical simulations. Thus, GISs are often used to manage data from remote sensors, to provide advanced spatial analysis and to integrate numerical models. In order to demonstrate the integration of spatial data, time series and methods in the framework of the GIS, we present a case study focused on the modelling of dust transport over a surface coal mining area, exploring spatial data from 3D laser scanners, GPS measurements, aerial images, time series of meteorological observations, inputs/outputs form numerical models and existing geographic resources. To achieve this, digital terrain models, layers including GPS thematic mapping, and scenes with simulation of wind flows are created to visualize and interpret coal dust transport over the mine area and a neighbouring residential zone. A temporary coal storage and sorting site, located near the residential zone, is one of the dominant sources of emissions. Using numerical simulations, the possible effects of wind flows are observed over the surface, modified by natural objects and man-made obstacles. The coal dust drifts with the wind in the direction of the residential zone and is partially deposited in this area. The simultaneous display of the digital map layers together with the location of the dominant emission source, wind flows and protected areas enables a risk assessment of the dust deposition in the area of interest to be performed. In order to obtain a more accurate simulation of wind flows over the temporary storage and sorting site, 3D laser scanning and GPS thematic mapping are used to create a more detailed digital terrain model. Thus, visualization of wind flows over the area of interest combined with 3D map layers enables the exploration of the processes of coal dust

  3. Impacts of urban land-surface forcing on ozone air quality in the Seoul metropolitan area

    Directory of Open Access Journals (Sweden)

    Y.-H. Ryu

    2013-02-01

    Full Text Available Modified local meteorology owing to heterogeneities in the urban–rural surface can affect urban air quality. In this study, the impacts of urban land-surface forcing on ozone air quality during a high ozone (O3 episode in the Seoul metropolitan area, South Korea, are investigated using a high-resolution chemical transport model (CMAQ. Under fair weather conditions, the temperature excess (urban heat island significantly modifies boundary layer characteristics/structures and local circulations. The modified boundary layer and local circulations result in an increase in O3 levels in the urban area of 16 ppb in the nighttime and 13 ppb in the daytime. Enhanced turbulence in the deep urban boundary layer dilutes pollutants such as NOx, and this contributes to the elevated O3 levels through the reduced O3 destruction by NO in the NOx-rich environment. The advection of O3 precursors over the mountains near Seoul by the prevailing valley-breeze circulation in the mid- to late morning results in the build-up of O3 over the mountains in conjunction with biogenic volatile organic compound (BVOC emissions there. As the prevailing local circulation in the afternoon changes to urban-breeze circulation, the O3-rich air masses over the mountains are advected over the urban area. The urban-breeze circulation exerts significant influences on not only the advection of O3 but also the chemical production of O3 under the circumstances in which both anthropogenic and biogenic (natural emissions play important roles in O3 formation. As the air masses that are characterized by low NOx and high BVOC levels and long OH chain length are advected over the urban area from the surroundings, the ozone production efficiency increases in the urban area. The relatively strong vertical mixing in the urban boundary layer embedded in the

  4. AFM-based tribological study of nanopatterned surfaces: the influence of contact area instabilities

    International Nuclear Information System (INIS)

    Although the importance of morphology on the tribological properties of surfaces has long been proved, an exhaustive understanding of nanopatterning effects is still lacking due to the difficulty in both fabricating ‘really nano-’ structures and detecting their tribological properties. In the present work we show how the probe–surface contact area can be a critical parameter due to its remarkable local variability, making a correct interpretation of the data very difficult in the case of extremely small nanofeatures. Regular arrays of parallel 1D straight nanoprotrusions were fabricated by means of a low-dose focused ion beam, taking advantage of the amorphization-related swelling effect. The tribological properties of the patterns were detected in the presence of air and in vacuum (dry ambient) by atomic force microscopy. We have introduced a novel procedure and data analysis to reduce the uncertainties related to contact instabilities. The real time estimation of the radius of curvature of the contacting asperity enables us to study the dependence of the tribological properties of the patterns from their geometrical characteristics. The effect of the patterns on both adhesion and the coefficient of friction strongly depends on the contact area, which is linked to the local radius of curvature of the probe. However, a detectable hydrophobic character induced on the hydrophilic native SiO2 has been observed as well. The results suggest a scenario for capillary formation on the patterns. (paper)

  5. Porous MgO material with ultrahigh surface area as the matrix for phase change composite

    International Nuclear Information System (INIS)

    Highlights: • Porous MgO material with ultrahigh surface area was synthesized. • A composite PCM was prepared from PEG-1000 and the porous MgO. • The phase change temperatures and enthalpy of the composite were measured. • The composite PCM performed good shape-stabilized property. - Abstract: Mesoporous magnesium oxide (MgO) material was synthesized using an integration of the evaporation-induced surfactant assembly and magnesium nitrate pyrolysis. The as-prepared MgO material is well crystalline, and possesses three-dimensional interconnected mesopores and a surface area as high as 596 m2/g. Using the porous MgO as a matrix and polyethylene glycol (PEG-1000) as the functional phase for heat energy storage, a shape-stabilized phase change composite of PEG/MgO was fabricated by an easy impregnation method. In the composite, mesoporous MgO material provides structural strength and prevents the leakage of the molten PEG during the phase change process. The compositions and microstructures of the PEG/MgO composite were determined by Fourier transformation infrared spectroscope (FT-IR), X-ray diffractometer (XRD), scanning electronic microscope (SEM) and thermogravimetric analyzer (TGA), respectively. The phase change properties of the PEG/MgO composite were determined by differential scanning calorimeter (DSC). The high heat-energy storage capability and good thermal stability of the composite enable it extensive applications in the future

  6. High-Surface-Area Nitrogen-Doped Reduced Graphene Oxide for Electric Double-Layer Capacitors.

    Science.gov (United States)

    Youn, Hee-Chang; Bak, Seong-Min; Kim, Myeong-Seong; Jaye, Cherno; Fischer, Daniel A; Lee, Chang-Wook; Yang, Xiao-Qing; Roh, Kwang Chul; Kim, Kwang-Bum

    2015-06-01

    A two-step method consisting of solid-state microwave irradiation and heat treatment under NH3 gas was used to prepare nitrogen-doped reduced graphene oxide (N-RGO) with a high specific surface area (1007 m(2)  g(-1) ), high electrical conductivity (1532 S m(-1) ), and low oxygen content (1.5 wt %) for electrical double-layer capacitor applications. The specific capacitance of N-RGO was 291 F g(-1) at a current density of 1 A g(-1) , and a capacitance of 261 F g(-1) was retained at 50 A g(-1) , which indicated a very good rate capability. N-RGO also showed excellent cycling stability and preserved 96 % of the initial specific capacitance after 100 000 cycles. Near-edge X-ray absorption fine-structure spectroscopy results provided evidenced for the recovery of π conjugation in the carbon networks with the removal of oxygenated groups and revealed chemical bonding of the nitrogen atoms in N-RGO. The good electrochemical performance of N-RGO is attributed to its high surface area, high electrical conductivity, and low oxygen content. PMID:25916491

  7. Effect of lung injuries on [14C]urea permeability-surface area product in dogs

    International Nuclear Information System (INIS)

    To determine whether [14C]urea permeability-surface area product (PS) is a reliable indicator of changes in permeability in various injuries and its relationship to indicator-dilution and gravimetric lung water contents, we studied six groups of anesthetized, paralyzed, and mechanically ventilated dogs (5 animals each). The groups consisted of control dogs, those injured by intravenous alloxan, oleic acid, or glass beads, and those exposed to acute hypoxia or increased left atrial pressure from volume loading (Pla). Interanimal variation of PS was large (3.0-15.0 ml/s), but successive hourly values in individual animals were stable for 2 h in experimental groups and for 4 h in controls. The PS increased after alloxan, elevated Pla, and 2 h of hypoxia; PS decreased after oleic acid and micremboli. The gravimetric lung water increased after alloxan, oleic acid, and microemboli, and indicator-dilution lung water increased only after alloxan. We conclude (1) that intersubject variability requires normalization to enable detection of significant deviation from base line, and (2) that decreased PS after oleic acid and microvascular injury occurred because vascular obstruction, which decreased surface area, masked probable coexisting increases in capillary permeability

  8. Closure Report for Corrective Action Unit 417: Central Nevada Test Area Surface, Nevada

    International Nuclear Information System (INIS)

    This Closure Report provides the documentation for closure of the Central Nevada Test Area (CNTA) surface Corrective Action Unit (CAU) 417. The CNTA is located in Hot Creek Valley in Nye County, Nevada, approximately 22.5 kilometers (14 miles) west of U.S. State Highway 6 near the Moores Station historical site, and approximately 137 kilometers (85 miles) northeast of Tonopah, Nevada. The CNTA consists of three separate land withdrawal areas commonly referred to as UC-1, UC-3, and UC-4, all of which are accessible to the public. A nuclear device for Project Faultless was detonated approximately 975 meters (3,200 feet) below ground surface on January 19, 1968, in emplacement boring UC-1 (Department of Energy, Nevada Operation Office [DOE/NV], 1997). CAU 417 consists of 34 Corrective Action Sites (CASs). Site closure was completed using a Nevada Department of Environmental Protection (NDEP) approved Corrective Action Plan (CAP) (DOE/NV, 2000) which was based on the recommendations presented in the NDEP-approved Corrective Action Decision Document (DOE/NV, 1999). Closure of CAU 417 was completed in two phases. Phase I field activities were completed with NDEP concurrence during 1999 as outlined in the Phase I Work Plan, Appendix A of the CAP (DOE/NV, 2000), and as summarized in Section 2.1.2 of this document

  9. Spherical torus plasma interactions with large-area liquid lithium surfaces in CDX-U

    International Nuclear Information System (INIS)

    The current drive experiment-upgrade (CDX-U) device at the Princeton Plasma Physics Laboratory (PPPL) is a spherical torus (ST) dedicated to the exploration of liquid lithium as a potential solution to reactor first-wall problems such as heat load and erosion, neutron damage and activation, and tritium inventory and breeding. Initial lithium limiter experiments were conducted with a toroidally-local liquid lithium rail limiter (L3) from the University of California at San Diego (UCSD). Spectroscopic measurements showed a clear reduction of impurities in plasmas with the L3, compared to discharges with a boron carbide limiter. The evidence for a reduction in recycling was less apparent, however. This may be attributable to the relatively small area in contact with the plasma, and the presence of high-recycling surfaces elsewhere in the vacuum chamber. This conclusion was tested in subsequent experiments with a fully toroidal lithium limiter that was installed above the floor of the vacuum vessel. The new limiter covered over ten times the area of the L3 facing the plasma. Experiments with the toroidal lithium limiter have recently begun. This paper describes the conditioning required to prepare the lithium surface for plasma operations, and effect of the toroidal liquid lithium limiter on discharge performance

  10. Our Reclamation Future: The Missing Bet on Trees.

    Science.gov (United States)

    Ashby, W. Clark; And Others

    This document discusses reclamation alternatives for land that has been surface-mined. Special attention is given to the use of tree planting as a desirable reclamation method. Contents include Illinoian reclamation history, knowledge of forestry techniques and successes on surface-mined lands, recreational and educational use of the reclaimed…

  11. Accurate measurements of surface emission rate for large-area alpha and beta reference sources

    International Nuclear Information System (INIS)

    For alpha emitters and beta emitters with maximum beta energy greater than 0.150 MeV, the characteristics of reference sources for the calibration of surface contamination monitors are specified by the international standard ISO 8769. According to this standard, the surface emission rate of reference sources has to be measured by absolute methods or by using an instrument that has been calibrated by means of sources that has been measured absolutely. Moreover, the surface emission rate has to be measured by the national standards laboratory with an uncertainty which must not exceed 3% (one standard deviation). In this paper, the counting system and the experimental conditions needed for accurate measurements of the surface emission rate are presented. The uncertainty of such measurements is much smaller than 3%. The evaluation of this uncertainty is also described. The counting system used for absolute alpha and beta surface emission rate measurements is composed of a large area, gas-flow, windowless proportional detector, an integral and a spectrometric counting channels. The method of measurement for alpha and beta surface emission rate is very simple but it is necessary to achieve the optimum experimental conditions of counting for obtaining accurate measurement results. Thus, the proportional detector has to work under a continuous and stable gas-flow and its plateau has to be long with a very low slope. To obtain a counting efficiency of 100%, it has to use a tight detector and a very pure counting gas. Additionally, the detector must be flushed and then operated under a steady gas-flow for several hours prior to measurements in order to be cleaned of air impurities. To perform alpha and beta surface emission rate measurements we optimized first the conditions of counting. For beta sources, the discrimination level has been adjusted by means of a 55 Fe source. Using this spectrum, we checked the stability of the counting system because the peak, corresponding

  12. Topographic Effects on the Surface Emissivity of a Mountainous Area Observed by a Spaceborne Microwave Radiometer

    Directory of Open Access Journals (Sweden)

    Frank S. Marzano

    2008-03-01

    Full Text Available A simulation study to understand the influence of topography on the surfaceemissivity observed by a satellite microwave radiometer is carried out. We analyze theeffects due to changes in observation angle, including the rotation of the polarization plane.A mountainous area in the Alps (Northern Italy is considered and the information on therelief extracted from a digital elevation model is exploited. The numerical simulation refersto a radiometric image, acquired by a conically-scanning radiometer similar to AMSR-E,i.e., flying at 705 km of altitude with an observation angle of 55°. To single out the impacton surface emissivity, scattering of the radiation due to the atmosphere or neighboringelevated surfaces is not considered. C and X bands, for which atmospheric effects arenegligible, and Ka band are analyzed. The results indicate that the changes in the localobservation angle tend to lower the apparent emissivity of a radiometric pixel with respectto the corresponding flat surface characteristics. The effect of the rotation of thepolarization plane enlarges (vertical polarization, or attenuates (horizontal polarizationthis decrease. By doing some simplifying assumptions for the radiometer antenna, theconclusion is that the microwave emissivity at vertical polarization is underestimated,whilst the opposite occurs for horizontal polarization, except for Ka band, for which bothunder- and overprediction may occur. A quantification of the differences with respect to aflat soil and an approximate evaluation of their impact on soil moisture retrieval areyielded.

  13. Fabrication of large-area arrays of hybrid nanostructures on polymer-derived chemically patterned surfaces

    Science.gov (United States)

    Liu, Xiaoying; Nepal, Dhriti; Biswas, Sushmita; Park, Kyoungweon; Vaia, Richard; Nealey, Paul; Air Force Research Laboratories Collaboration; University of Chicago Team

    2014-03-01

    The precise placement and assembly of nanoparticles (NPs) into large-area nanostructure arrays will allow for the design and implementation of advanced nanoscale devices for applications in fields such as quantum computing, optical sensing, superlenses, photocatalysis, photovoltaics, and non-linear optics. Our work is focused on using chemically nanopatterned surfaces to fabricate arrays of hybrid nanostructures with each component of the building block at well-defined positions. The precise chemical contrast patterns with densities and resolution of features created using standard tools of lithography, polymer self-assembly, and surface functionalization allow for control of position and interparticle spacing through selective surface-particle and particle-particle interactions. We have demonstrated the assembly of NPs, including metallic NPs and semiconductor quantum dots, into arrays of hybrid structures with various geometries, such as monomers, dimers, quatrefoils, stripes, and chains. We have developed protocols to fabricate NP arrays over a variety of substrates, which allows for the design and characterization of optical and electronic nanostructures and devices to meet the requirements of various technological applications.

  14. Diversity of Bacterial Communities of Fitness Center Surfaces in a U.S. Metropolitan Area

    Directory of Open Access Journals (Sweden)

    Nabanita Mukherjee

    2014-12-01

    Full Text Available Public fitness centers and exercise facilities have been implicated as possible sources for transmitting community-acquired bacterial infections. However, the overall diversity of the bacterial community residing on the surfaces in these indoor environments is still unknown. In this study, we investigated the overall bacterial ecology of selected fitness centers in a metropolitan area (Memphis, TN, USA utilizing culture-independent pyrosequencing of the 16S rRNA genes. Samples were collected from the skin-contact surfaces (e.g., exercise instruments, floor mats, handrails, etc. within fitness centers. Taxonomical composition revealed the abundance of Firmicutes phyla, followed by Proteobacter and Actinobacteria, with a total of 17 bacterial families and 25 bacterial genera. Most of these bacterial genera are of human and environmental origin (including, air, dust, soil, and water. Additionally, we found the presence of some pathogenic or potential pathogenic bacterial genera including Salmonella, Staphylococcus, Klebsiella, and Micrococcus. Staphylococcus was found to be the most prevalent genus. Presence of viable forms of these pathogens elevates risk of exposure of any susceptible individuals. Several factors (including personal hygiene, surface cleaning and disinfection schedules of the facilities may be the reasons for the rich bacterial diversity found in this study. The current finding underscores the need to increase public awareness on the importance of personal hygiene and sanitation for public gym users.

  15. Impact of the bioresorbable vascular scaffold surface area on on-treatment platelet reactivity.

    Science.gov (United States)

    Gross, Lisa; Sibbing, Dirk; Eickhoff, Madeleine; Baquet, Moritz; Orban, Martin; Krieg, Anne; Grujic, Katarina; Theiss, Hans D; Brunner, Stefan; Teupser, Daniel; Holdt, Lesca; Massberg, Steffen; Mehilli, Julinda

    2016-07-01

    While promising data with the novel bioresorbable vascular scaffold (BVS) are accumulating, signals of scaffold thrombosis (ST) were noted in recent reports. We aimed to assess the relationship between the total surface area (TSA) of implanted everolimus-eluting BVSs and the on-treatment adenosine diphosphate (ADP)-induced platelet reactivity in patients undergoing percutaneous coronary intervention (PCI). 202 consecutive patients undergoing BVS implantation and platelet function testing were included. For investigating the impact of the scaffold surface on platelet reactivity, patients were stratified into two groups regarding the median BVS TSA. The on-treatment ADP-induced platelet reactivity was determined with the Multiplate analyzer and 30-day follow-up was available in 98% of patients. ADP-induced platelet aggregation values (median, [IQR]) did not differ between the two study groups (12.0 [9.0-19.0] U for patients with TSA > 1.39 cm(2) and 13.0 [9.0-19.5] U for patients with TSA ≤ 1.39 cm(2); p = 0.69). No correlation was observed between the BVS TSA and levels of platelet reactivity (Spearman rank correlation = -0.10, p = 0.16). At 30 days after PCI, two early STs (1%) were documented. Thus, in patients on a dual antiplatelet treatment regimen following BVS implantation, the extent of blood-to-BVS contact surface does not negatively affect levels of on-treatment platelet reactivity. PMID:26940818

  16. Synthesis of high-surface-area {gamma}-Al{sub 2}O{sub 3} from aluminum scrap and its use for the adsorption of metals: Pb(II), Cd(II) and Zn(II)

    Energy Technology Data Exchange (ETDEWEB)

    Asencios, Yvan J.O., E-mail: yvan@iqsc.usp.br [Instituto de Quimica de Sao Carlos, Universidade de Sao Paulo, Av. Trabalhador Saocarlense, 400, 13560-970, Sao Carlos, SP (Brazil); Sun-Kou, Maria R., E-mail: msun@pucp.edu.pe [Seccion Quimica, Departamento de Ciencias, Pontificia Universidad Catolica del Peru, Av. Universitaria 1801, Lima 32 (Peru)

    2012-10-01

    Highlights: Black-Right-Pointing-Pointer Aluminum hydroxide obtained from aluminum scrap led to the formation of gamma alumina. Black-Right-Pointing-Pointer Acidic pH of precipitation favored the formation of small particles of high surface areas. Black-Right-Pointing-Pointer Higher aging temperature favored the formation of large structures of large pore sizes. Black-Right-Pointing-Pointer Higher aging temperature generated symmetrical solids of regular hexagonal prism forms. Black-Right-Pointing-Pointer Aluminas of large pores adsorbed metals as following: Pb (1.75 Angstrom-Sign ) > Cd (1.54 Angstrom-Sign ) > Zn (1.38 Angstrom-Sign ). - Abstract: Several types of alumina were synthesized from sodium aluminate (NaAlO{sub 2}) by precipitation with sulfuric acid (H{sub 2}SO{sub 4}) and subsequently calcination at 500 Degree-Sign C to obtain {gamma}-Al{sub 2}O{sub 3}. The precursor aluminate was derived from aluminum scrap. The various {gamma}-Al{sub 2}O{sub 3} synthesized were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), adsorption-desorption of N{sub 2} (S{sub BET}) and scanning electron microscopy (SEM). XRD revealed that distinct phases of Al{sub 2}O{sub 3} were formed during thermal treatment. Moreover, it was observed that conditions of synthesis (pH, aging time and temperature) strongly affect the physicochemical properties of the alumina. A high-surface-area alumina (371 m{sup 2} g{sup -1}) was synthesized under mild conditions, from inexpensive raw materials. These aluminas were tested for the adsorption of Cd(II), Zn(II) and Pb(II) from aqueous solution at toxic metal concentrations, and isotherms were determined.

  17. [Spatial-temporal characteristics of land surface temperature in Tianshan Mountains area based on MODIS data].

    Science.gov (United States)

    Guan, Yan-long; Wang, Rang-hui; Li, Cheng; Yao, Jian; Zhang, Meng; Zhao, Jian-ping

    2015-03-01

    Based on the MODIS/MOD11A2 data from 2001 to 2013, this paper researched the characteristics of land surface temperature (LST) of Tianshan Mountains area. The results indicated that the average of LST in the study area was 1.73 °C , and LST was much higher in the east than in the west. The inter-annual variation range of LST in the northwest was significantly large than in other regions, with the largest above 0.55 °C in some areas. The LST tended to slowly increase with time, and the increase rate was 0.147 °C . a-1. It showed a significant seasonal difference, and the fluctuation of winter was significantly larger than in other seasons with the coefficient of variation reaching 12.7%. The LST difference of day time was greater than that at night, and that in summer was greater than in other seasons. The LST differed with land use types, and the fitted results were inconsistent between the LST and NDVI. With the increase of NDVI of woodland and grassland, the LST decreased dramatically. The LST of construction land and cropland under the influence of human activities had higher sensitivity with NDVI than other land types. PMID:26211048

  18. Sub-Pixel Classification of MODIS EVI for Annual Mappings of Impervious Surface Areas

    Directory of Open Access Journals (Sweden)

    Narumasa Tsutsumida

    2016-02-01

    Full Text Available Regular monitoring of expanding impervious surfaces areas (ISAs in urban areas is highly desirable. MODIS data can meet this demand in terms of frequent observations but are lacking in spatial detail, leading to the mixed land cover problem when per-pixel classifications are applied. To overcome this issue, this research develops and applies a spatio-temporal sub-pixel model to estimate ISAs on an annual basis during 2001–2013 in the Jakarta Metropolitan Area, Indonesia. A Random Forest (RF regression inferred the ISA proportion from annual 23 values of MODIS MOD13Q1 EVI and reference data in which such proportion was visually allocated from very high-resolution images in Google Earth over time at randomly selected locations. Annual maps of ISA proportion were generated and showed an average increase of 30.65 km2/year over 13 years. For comparison, a series of RF per-pixel classifications were also developed from the same reference data using a Boolean class constructed from different thresholds of ISA proportion. Results from per-pixel models varied when such thresholds change, suggesting difficulty of estimation of actual ISAs. This research demonstrated the advantages of spatio-temporal sub-pixel analysis for annual ISAs mapping and addresses the problem associated with definitions of thresholds in per-pixel approaches.

  19. Nonselective inhibition of the epigenetic transcriptional regulator BET induces marked lymphoid and hematopoietic toxicity in mice.

    Science.gov (United States)

    Lee, Dong U; Katavolos, Paula; Palanisamy, Gopinath; Katewa, Arna; Sioson, Charly; Corpuz, Janice; Pang, Jodie; DeMent, Kevin; Choo, Edna; Ghilardi, Nico; Diaz, Dolores; Danilenko, Dimitry M

    2016-06-01

    Bromo and extra terminal (BET) proteins (BRD2, BRD3, BRD4 and BRDT) are epigenetic transcriptional regulators required for efficient expression of growth promoting, cell cycle progression and antiapoptotic genes. Through their bromodomain, these proteins bind to acetylated lysine residues of histones and are recruited to transcriptionally active chromatin. Inhibition of the BET-histone interaction provides a tractable therapeutic strategy to treat diseases that may have epigenetic dysregulation. JQ1 is a small molecule that blocks BET interaction with histones. It has been shown to decrease proliferation of patient-derived multiple myeloma in vitro and to decrease tumor burden in vivo in xenograft mouse models. While targeting BET appears to be a viable and efficacious approach, the nonclinical safety profile of BET inhibition remains to be well-defined. We report that mice dosed with JQ1 at efficacious exposures demonstrate dose-dependent decreases in their lymphoid and immune cell compartments. At higher doses, JQ1 was not tolerated and due to induction of significant body weight loss led to early euthanasia. Flow cytometry analysis of lymphoid tissues showed a decrease in both B- and T-lymphocytes with a concomitant decrease in peripheral white blood cells that was confirmed by hematology. Further investigation with the inactive enantiomer of JQ1 showed that these in vivo effects were on-target mediated and not elicited through secondary pharmacology due to chemical structure. PMID:27078884

  20. RVX-297- a novel BD2 selective inhibitor of BET bromodomains.

    Science.gov (United States)

    Kharenko, Olesya A; Gesner, Emily M; Patel, Reena G; Norek, Karen; White, Andre; Fontano, Eric; Suto, Robert K; Young, Peter R; McLure, Kevin G; Hansen, Henrik C

    2016-08-12

    Bromodomains are epigenetic readers that specifically bind to the acetyl lysine residues of histones and transcription factors. Small molecule BET bromodomain inhibitors can disrupt this interaction which leads to potential modulation of several disease states. Here we describe the binding properties of a novel BET inhibitor RVX-297 that is structurally related to the clinical compound RVX-208, currently undergoing phase III clinical trials for the treatment of cardiovascular diseases, but is distinctly different in its biological and pharmacokinetic profiles. We report that RVX-297 preferentially binds to the BD2 domains of the BET bromodomain and Extra Terminal (BET) family of protein. We demonstrate the differential binding modes of RVX-297 in BD1 and BD2 domains of BRD4 and BRD2 using X-ray crystallography, and describe the structural differences driving the BD2 selective binding of RVX-297. The isothermal titration calorimetry (ITC) data illustrate the related differential thermodynamics of binding of RVX-297 to single as well as dual BET bromodomains. PMID:27282480

  1. The BET Family of Proteins Targets Moloney Murine Leukemia Virus Integration near Transcription Start Sites

    Directory of Open Access Journals (Sweden)

    Jan De Rijck

    2013-11-01

    Full Text Available A hallmark of retroviral replication is integration of the viral genome into host cell DNA. This characteristic makes retrovirus-based vectors attractive delivery vehicles for gene therapy. However, adverse events in gene therapeutic trials, caused by activation of proto-oncogenes due to murine leukemia virus (MLV-derived vector integration, hamper their application. Here, we show that bromodomain and extraterminal (BET proteins (BRD2, BRD3, and BRD4 and MLV integrase specifically interact and colocalize within the nucleus of the cell. Inhibition of the BET proteins’ chromatin interaction via specific bromodomain inhibitors blocks MLV virus replication at the integration step. MLV integration site distribution parallels the chromatin binding profile of BET proteins, and expression of an artificial fusion protein of the BET integrase binding domain with the chromatin interaction domain of the lentiviral targeting factor LEDGF/p75 retargets MLV integration away from transcription start sites and into the body of actively transcribed genes, conforming to the HIV integration pattern. Together, these data validate BET proteins as MLV integration targeting factors.

  2. The BET family of proteins targets Moloney Murine Leukemia Virus integration near transcription start sites

    Science.gov (United States)

    De Rijck, Jan; de Kogel, Christine; Demeulemeester, Jonas; Vets, Sofie; Ashkar, Sara El; Malani, Nirav; Bushman, Frederic D; Landuyt, Bart; Husson, Steven J.; Busschots, Katrien; Gijsbers, Rik; Debyser, Zeger

    2014-01-01

    Summary A hallmark of retroviral replication is integration of the viral genome in the host cell DNA. This characteristic makes retrovirus-based vectors attractive delivery vehicles for gene therapy. However, adverse events in gene therapeutic trials, caused by activation of proto-oncogenes due to Murine Leukemia Virus (MLV)-derived vector integration, hamper their application. Here we show that bromodomain and extraterminal (BET) proteins (BRD2, BRD3 and BRD4) and MLV integrase specifically interact and co-localize within the nucleus of the cell. Inhibition of the BET proteins chromatin interaction via specific bromodomain inhibitors blocks MLV virus replication at the integration step. MLV integration site distribution parallels the chromatin binding profile of BET proteins, and expression of an artificial fusion protein of the BET integrase binding domain with the chromatin interaction domain of the lentiviral targeting factor LEDGF/p75, retargets MLV integration away from TSS and into the body of actively transcribed genes, conform to the Human Immunodeficiency Virus (HIV) integration pattern. Together these data validate BET proteins as MLV integration targeting factors. PMID:24183673

  3. Component Ratios of Independent and Herding Betters in a Racetrack Betting Market

    CERN Document Server

    Mori, Shintaro

    2010-01-01

    We study the time series data of the racetrack betting market in the Japan Racing Association (JRA). As the number of votes t increases, the win bet fraction x(t) converges to the final win bet fraction x_{f}. We observe the power law $(x(t)-x_{f})^{2} \\propto t^{-\\beta}$ with $\\beta\\simeq 0.488$. We measure the degree of the completeness of the ordering of the horses using an index AR, the horses are ranked according to the size of the win bet fraction. AR(t) also obeys the power law and behaves as $\\mbox{AR}_{f}-\\mbox{AR}(t)\\propto t^{-\\gamma}$ with $\\gamma\\simeq 0.589$, where AR_{f} is the final value of AR. We introduce a simple voting model with two types of voters-independent and herding. Independent voters provide information about the winning probability of the horses and herding voters decide their votes based on the popularities of the horses.This model can explain two power laws of the betting process. The component ratio of the independent voter to the herding voter is 1:3.

  4. Woody vegetation and succession on the Fonde surface mine demonstration area, Bell County, Kentucky

    International Nuclear Information System (INIS)

    The long term impact of surface mining on vegetation and plant succession has always been of concern to environmentalists and residents of Appalachia. The Fonde Surface Mine Demonstration Area is a 7.3-ha, NE-NW-aspect contour coal mine at an elevation of 562 m. It was reclaimed in 1965 to show state-of-the-art surface mine reclamation techniques consistent with then-current law and regulations after coal mining in 1959 and 1963. The mine spoils were lightly graded to control erosion and crates a bench with water control and two sediment ponds. Soil pH ranged from 2.8 to 5.9. About 80 percent of the mine was planted with 18 tree and shrub species including plantations of mixed pine, mixed hardwoods, black locust, and shrubs for wildlife. In a complete floristic inventory conducted 25 years later, the authors found the woody flora consisted of 34 families, 53 genera, and 70 species including 7 exotics. This inventory of the Fonde mine shows that a diverse forest vegetation can be reestablished after extreme disturbances in Appalachia. Black locust, yellow poplar, and Virginia pine reproduction varied significantly among plantation types. Canopy tree species significantly affected ground layer cover, total species richness, number of tree seedling species, and total number of tree seedlings present. Mine soil type affected ground layer percent cover and total species richness. Pre-SMCRA (Surface Mining Control and Reclamation Act of 1977) reclaimed and inventoried mines can be used to evaluate biodiversity on post-SMCRA mines

  5. Application of three-dimensionally area-selective atomic layer deposition for selectively coating the vertical surfaces of standing nanopillars

    Science.gov (United States)

    Dong, Wenjing; Zhang, Kenan; Zhang, Yun; Wei, Tiaoxing; Sun, Yan; Chen, Xin; Dai, Ning

    2014-01-01

    We describe a strategy for selectively coating the vertical surfaces of standing nanopillars using area-selective atomic layer deposition (ALD). Hydrophobic self-assembled monolayers (SAMs) are utilised to selectively inhibit the coating of oxides on the modified horizontal regions to ensure that only the vertical surfaces of vertical standing nanorods are coated using ALD processes. This method makes it possible to fabricate vertical nanodevices using a simple process of depositing oxide layer on a vertical surface, and can also be applied to the area-selective surface passivation of other standing structures. PMID:24662775

  6. Long-term evolution of the surface environment of the Campine area, Northern Belgium

    International Nuclear Information System (INIS)

    Document available in extended abstract form only. The Boom Clay in the Campine Basin is studied as the reference host formation for the geological disposal of radioactive waste. Near Mol, it is covered by approximately 200 m of sediment which protects the clay layer. Here, we will give a preliminary assessment of the long-term evolution of the surface environment in the Campine area for the next 1 Ma, with respect to geomorphological, pedological and hydrological processes. The current surface environment started to develop after the last major marine regression around 2 Ma ago. Then, the climatic and tectonic evolution caused significant changes in surficial geology, relief intensity, soils and hydrography. The palaeo-geographical evolution during the Quaternary is characterized by important stream divergences, relative uplift and erosion. Tectonic uplift of the Campine Plateau forced the river Meuse to incise into the substrate. To the west, erosional processes shaped the Nete and the Lower Scheldt basins as a result of combined uplift and gradual sea-level drop. The Campine Plateau being covered by coarse fluvial deposits from the Early and Middle Pleistocene, is largely protected from erosion. The same is true for the Campine Cuesta, that stands out as a result of the cohesive and erosion resistant Kempen Clay substrate. Burial graphs covering the last few million years from different locations in the Boom Clay sub-crop zone reflect processes of subsidence, uplift, sea level variations and climate change in relation to the erodibility of the substrate. Continuous burial during the Quaternary as a result of subsidence is observed near the Dutch border, and for the Roer Valley Graben. Burial graphs for the Campine Plateau do not show important erosional phases during the last several million years. This is due to the protecting cover of coarse fluvial deposits. The area that is now occupied by the Lower Scheldt and the Nete basin has experienced erosion during

  7. Energetic changes in the surface of activated carbons and relationship with Ni(II) adsorption from aqueous solution

    Science.gov (United States)

    Rodríguez-Estupiñan, Paola; Giraldo, Liliana; Moreno-Piraján, Juan Carlos

    2013-12-01

    This study investigated Ni(II) ion adsorption from aqueous solution on activated carbons obtained by chemically modifying the surface with the oxidizing agents nitric acid and hydrogen peroxide (CAGoxP and CAGoxN, respectively). The activated carbons were characterized by total acidity and basicity, pH at the point of charge zero determination and IR spectroscopy. Textural parameters such as the BET area and pore volumes were evaluated by gas adsorption. The BET area of the materials was between 816 and 876 m2 g-1. Additionally, the immersion enthalpies of the activated carbons in water and benzene were determined. The experimental results on adsorption in solution were adjusted to the Langmuir and Freundlich models, obtaining values for the monolayer capacity between 29.68 and 50.97 mg g-1, which indicates that the adsorption capacity depends largely on solid surface chemistry.

  8. Trajectories of cortical surface area and cortical volume maturation in normal brain development

    Directory of Open Access Journals (Sweden)

    Simon Ducharme

    2015-12-01

    Full Text Available This is a report of developmental trajectories of cortical surface area and cortical volume in the NIH MRI Study of Normal Brain Development. The quality-controlled sample included 384 individual typically-developing subjects with repeated scanning (1–3 per subject, total scans n=753 from 4.9 to 22.3 years of age. The best-fit model (cubic, quadratic, or first-order linear was identified at each vertex using mixed-effects models, with statistical correction for multiple comparisons using random field theory. Analyses were performed with and without controlling for total brain volume. These data are provided for reference and comparison with other databases. Further discussion and interpretation on cortical developmental trajectories can be found in the associated Ducharme et al.׳s article “Trajectories of cortical thickness maturation in normal brain development – the importance of quality control procedures” (Ducharme et al., 2015 [1].

  9. N,N-Dilauryl Chitosan:Synthesis and Surface Pressure-area Isotherm

    Institute of Scientific and Technical Information of China (English)

    XIN Mei-hua; WANG Min; LI Ming-chun; LIU Chao; SUN Duo-xian; MITSUISHI Masaya; MIYASHITA Tokuji

    2004-01-01

    With sodium dodecyl sulfonate(SDS) as the phase transferring catalyst, N,N-Dilauryl chitosans with a high degree of alkyl group substitution were prepared and characterized by means of FTIR, 1H NMR and elemental analyses. The results indicate that the average degree of alkyl group substitution on the chitosan increases with decreasing the molecular weight of the chitosan. The fully N,N-dilaurylated chitosan was found to be dissolvable in chloroform. The collapsed pressures of the samples derived from chitosan with 3000,5000 and 10000 dalton are 47.6, 48.2 and 51.0 mN/m, respectively. The surface area occupied by the monomer unit (glucosamine) of all those samples is 0.6 nm2.

  10. Alterations in cell surface area and deformability of individual human red blood cells in stored blood

    CERN Document Server

    Park, HyunJoo; Lee, SangYun; Kim, Kyoohyun; Sohn, Yong-Hak; Jang, Seongsoo; Park, YongKeun

    2015-01-01

    The functionality and viability of stored human red blood cells (RBCs) is an important clinical issue in transfusion. To systematically investigate changes in stored whole blood, the hematological properties of individual RBCs were quantified in blood samples stored for various periods with and without a preservation solution called CPDA-1. With 3-D quantitative phase imaging techniques, the optical measurements of the 3-D refractive index (RI) distributions and membrane fluctuations were done at the individual cell level. From the optical measurements, the morphological (volume, surface area and sphericity), biochemical (hemoglobin content and concentration), and mechanical parameters (dynamic membrane fluctuation) were simultaneously quantified to investigate the functionalities and their progressive alterations in stored RBCs. Our results show that the stored RBCs without CPDA-1 had a dramatic morphological transformation from discocytes to spherocytes within 2 weeks which was accompanied with significant ...

  11. Macrostructure-dependent photocatalytic property of high-surface-area porous titania films

    International Nuclear Information System (INIS)

    Porous titania films with different macrostructures were prepared with precise control of condensation degree and density of the oxide frameworks in the presence of spherical aggregates of polystyrene-block-poly(oxyethylene) (PS-b-PEO) diblock copolymer. Following detailed explanation of the formation mechanisms of three (reticular, spherical, and large spherical) macrostructures by the colloidal PS-b-PEO templating, structural variation of the titania frameworks during calcination were investigated by X-ray diffraction and X-ray photoelectron spectroscopy. Then, photocatalytic performance of the macroporous titania films was evaluated through simple degradation experiments of methylene blue under an UV irradiation. Consequently, absolute surface area of the film and crystallinity of the titania frameworks were important for understanding the photocatalytic performance, but the catalytic performance can be improved further by the macrostructural design that controls diffusivity of the targeted molecules inside the film and their accessibility to active sites

  12. Printed Large-Area Single-Mode Photonic Crystal Bandedge Surface-Emitting Lasers on Silicon.

    Science.gov (United States)

    Zhao, Deyin; Liu, Shihchia; Yang, Hongjun; Ma, Zhenqiang; Reuterskiöld-Hedlund, Carl; Hammar, Mattias; Zhou, Weidong

    2016-01-01

    We report here an optically pumped hybrid III-V/Si photoic crystal surface emitting laser (PCSEL), consisting of a heterogeneously integrated III-V InGaAsP quantum well heterostructure gain medium, printed on a patterned defect-free Si photonic crystal (PC) bandedge cavity. Single mode lasing was achieved for a large area laser, with a side-mode suppression ratio of 28 dB, for lasing operation temperature ~ 200 K. Two types of lasers were demonstrated operating at different temperatures. Detailed modal analysis reveals the lasing mode matches with the estimated lasing gain threshold conditions. Our demonstration promises a hybrid laser sources on Si towards three-dimensional (3D) integrated Si photonics for on-chip wavelength-division multiplex (3D WDM) systems for a wide range of volume photonic/electronic applications in computing, communication, sensing, imaging, etc. PMID:26727551

  13. FreeSASA: An open source C library for solvent accessible surface area calculations

    Science.gov (United States)

    Mitternacht, Simon

    2016-01-01

    Calculating solvent accessible surface areas (SASA) is a run-of-the-mill calculation in structural biology. Although there are many programs available for this calculation, there are no free-standing, open-source tools designed for easy tool-chain integration. FreeSASA is an open source C library for SASA calculations that provides both command-line and Python interfaces in addition to its C API. The library implements both Lee and Richards’ and Shrake and Rupley’s approximations, and is highly configurable to allow the user to control molecular parameters, accuracy and output granularity. It only depends on standard C libraries and should therefore be easy to compile and install on any platform. The library is well-documented, stable and efficient. The command-line interface can easily replace closed source legacy programs, with comparable or better accuracy and speed, and with some added functionality. PMID:26973785

  14. A STUDY ON THE CHARACTERISTICS OF INTERNAL AND EXTERNAL WALL SURFACE TEMPERATURE IN THE URBAN AREA

    Institute of Scientific and Technical Information of China (English)

    何云玲; 张一平; 刘玉洪; 马友鑫; 李佑荣; 窦军霞; 郭萍

    2004-01-01

    Internal and external wall surface temperatures (Tws) in April, August and December in Kunming, a city in low latitude plateau, were investigated. Results showed that the Tws in April were of the highest among the three, followed by August and December. The Tws differences among walls with different orientation were higher in April and December when the weather tends to be sunny, and lower in August with more cloudy days in the time. In April and August, Tws of E-wall was the highest, followed by S- and N-wall. But in December Tws of S-wall might be sometimes higher than E one. Diurnal range of internal Tws was usually smaller than that of the external, with also a time lag for the occurrence of its maximum and minimum. The results can serve as a basis for further research on building microclimate and urban architecture designs. It also gives suggestions for similar studies in other areas.

  15. Lithium inclusion in indium metal-organic frameworks showing increased surface area and hydrogen adsorption

    International Nuclear Information System (INIS)

    Investigation of counterion exchange in two anionic In-Metal-Organic Frameworks (In-MOFs) showed that partial replacement of disordered ammonium cations was achieved through the pre-synthetic addition of LiOH to the reaction mixture. This resulted in a surface area increase of over 1600% in (Li [In(1,3 − BDC)2])n and enhancement of the H2 uptake of approximately 275% at 80 000 Pa at 77 K. This method resulted in frameworks with permanent lithium content after repeated solvent exchange as confirmed by inductively coupled plasma mass spectrometry. Lithium counterion replacement appears to increase porosity after activation through replacement of bulkier, softer counterions and demonstrates tuning of pore size and properties in MOFs

  16. Lithium inclusion in indium metal-organic frameworks showing increased surface area and hydrogen adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Bosch, Mathieu; Zhang, Muwei; Feng, Dawei; Yuan, Shuai; Wang, Xuan [Department of Chemistry, Texas A and M University, College Station, Texas 77842 (United States); Chen, Ying-Pin [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77842 (United States); Zhou, Hong-Cai, E-mail: zhou@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77842 (United States); Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77842 (United States)

    2014-12-01

    Investigation of counterion exchange in two anionic In-Metal-Organic Frameworks (In-MOFs) showed that partial replacement of disordered ammonium cations was achieved through the pre-synthetic addition of LiOH to the reaction mixture. This resulted in a surface area increase of over 1600% in (Li [In(1,3 − BDC){sub 2}]){sub n} and enhancement of the H{sub 2} uptake of approximately 275% at 80 000 Pa at 77 K. This method resulted in frameworks with permanent lithium content after repeated solvent exchange as confirmed by inductively coupled plasma mass spectrometry. Lithium counterion replacement appears to increase porosity after activation through replacement of bulkier, softer counterions and demonstrates tuning of pore size and properties in MOFs.

  17. Environmental protection management by monitoring the surface water quality in Semenic area

    Directory of Open Access Journals (Sweden)

    Dana SÂMBOTIN

    2011-08-01

    Full Text Available Environment seems to have been the war against all. In fact recently most people polluted the environment and those few are cared for his cleaning. Today, the relationship evolvedas societies have changed in favour of ensuring environmental protection. With modern technology, performance, monitoring the environment becomes part of human activity ever more necessary, more possible and more efficient. The quality of the environment, its components: air, water, soil, plants, vegetable and animal products, is a condition "sine qua non" for the life of the modern man. The consequences of environmental pollution areso dangerous that modern man cannot afford considering them. Through this paper I will study the environmental quality by monitoring the surfaces waters from the Semenic- Gărâna area.

  18. Lithium inclusion in indium metal-organic frameworks showing increased surface area and hydrogen adsorption

    Directory of Open Access Journals (Sweden)

    Mathieu Bosch

    2014-12-01

    Full Text Available Investigation of counterion exchange in two anionic In-Metal-Organic Frameworks (In-MOFs showed that partial replacement of disordered ammonium cations was achieved through the pre-synthetic addition of LiOH to the reaction mixture. This resulted in a surface area increase of over 1600% in {Li [In(1,3 − BDC2]}n and enhancement of the H2 uptake of approximately 275% at 80 000 Pa at 77 K. This method resulted in frameworks with permanent lithium content after repeated solvent exchange as confirmed by inductively coupled plasma mass spectrometry. Lithium counterion replacement appears to increase porosity after activation through replacement of bulkier, softer counterions and demonstrates tuning of pore size and properties in MOFs.

  19. Monitoring of surface water quality in Khanpur dam area and Rawal dam

    International Nuclear Information System (INIS)

    Water is the most essential of all living things and it supports the life process. Without water it would not have been possible to sustain life on the earth. Presently, the water quality is a more serious problem in this country than its volume because according to WHO standards only 40% of the total population is having potable water. Therefore, samples were collected from Khanpur Dam Area and Rawal dam /associated facilities for investigations. In the present investigation it was found that the concentrations of all physical parameters such as nitrate, nitrite sulphate, chloride, pH, conductivity were within the normal limits. The level of metals in water was also low. Turbidity in surfaces water at some points exceeds recommended guide lines value. Similar situations faced with the exceed values of total suspended matter where high Coliform levels were found which cause growth of bacteria/micro organisms. (author)

  20. Ocular surface area and human eye blink frequency during VDU work

    DEFF Research Database (Denmark)

    Nielsen, Pernille Kofoed; Søgaard, Karen; Skotte, Jørgen;

    2008-01-01

    The purpose of this study was to investigate how the ocular surface area (OSA) and the eye blink frequency (BF) are affected by a high versus a low-monitor position during visual display unit (VDU) work with varying cognitive demands. In a balanced randomized (2 x 2) design ten healthy subjects...... (five males, five females) completed two different tasks on the VDU in a simulated office environment (23 degrees C and 30-35% relative humidity); an active task with demands on vision and hand-eye coordination, and a passive task. Two monitor positions were used: high (the monitors' upper edge at the...... same height as the subjects' eyes) and low (lowered by 25 degrees and perpendicular to gaze angle). Each task lasted 10 min. An OSA-proxy was measured from video recordings, and BF was sampled by electrooculography. The effect of lowering the gaze angle by 25 degrees decreased the OSA...

  1. Printed Large-Area Single-Mode Photonic Crystal Bandedge Surface-Emitting Lasers on Silicon

    Science.gov (United States)

    Zhao, Deyin; Liu, Shihchia; Yang, Hongjun; Ma, Zhenqiang; Reuterskiöld-Hedlund, Carl; Hammar, Mattias; Zhou, Weidong

    2016-01-01

    We report here an optically pumped hybrid III-V/Si photoic crystal surface emitting laser (PCSEL), consisting of a heterogeneously integrated III-V InGaAsP quantum well heterostructure gain medium, printed on a patterned defect-free Si photonic crystal (PC) bandedge cavity. Single mode lasing was achieved for a large area laser, with a side-mode suppression ratio of 28 dB, for lasing operation temperature ~200 K. Two types of lasers were demonstrated operating at different temperatures. Detailed modal analysis reveals the lasing mode matches with the estimated lasing gain threshold conditions. Our demonstration promises a hybrid laser sources on Si towards three-dimensional (3D) integrated Si photonics for on-chip wavelength-division multiplex (3D WDM) systems for a wide range of volume photonic/electronic applications in computing, communication, sensing, imaging, etc.

  2. Intestinal epithelial function and villus surface area in rats with bile fistulae

    International Nuclear Information System (INIS)

    We have previously found reduced absorption of vitamin B-12 in rats with choledochocolic fistulae. To investigate whether the reduction is caused by epithelial dysfunction or mucosal hypoplasia, choledocholic fistulae were made in 11 rats, whereas 10 rats were sham-operated. The epithelial function was evaluated 9 days later by measuring the uptake of 57CoB 1 2 and glucose in perfused intestinal segments, and by determining the activities of 11 mucosal enzymes. Hypoplasia was investigated by performing morphometric measurements of the villus surface area and by measuring the weight, protein, and DNA in mucosal scrapings. The results suggest that choledochocolic fistulae in rats do not impair epithelial function or cause mucosal hypoplasia. The urinary excretion of indican was increased in the fistula-operated rats, but further studies are needed to establish the significance of this observation

  3. Application of 3D Scanned Imaging Methodology for Volume, Surface Area, and Envelope Density Evaluation of Densified Biomass

    Science.gov (United States)

    Measurement of surface area, volume, and density is an essential for quantifying, evaluating, and designing the biomass densification, storage, and transport operations. Acquiring accurate and repeated measurements of these parameters for hygroscopic densified biomass are not straightforward and on...

  4. Nickel catalysts supported on MgO with different specific surface area for carbon dioxide reforming of methane

    Institute of Scientific and Technical Information of China (English)

    Luming; Zhang; Lin; Li; Yuhua; Zhang; Yanxi; Zhao; Jinlin; Li

    2014-01-01

    In this paper, three kinds of MgO with different specific surface area were prepared, and their effects on the catalytic performance of nickel catalysts for the carbon dioxide reforming of methane were investigated. The results showed that MgO support with the higher specific surface area led to the higher dispersion of the active metal, which resulted in the higher initial activity. On the other hand, the specific surface area of MgO materials might not be the dominant factor for the basicity of support to chemisorb and activate CO2, which was another important factor for the performance of catalysts. Herein, Ni/MgO(CA) catalyst with proper specific surface area and strong ability to activate CO2exhibited stable catalytic property and the carbon species deposited on the Ni/MgO(CA) catalyst after 10 h of reaction at 650 ?C were mainly activated carbon species.

  5. Efficiency of the exchange betting market for men's professional tennis: is there a favourite-longshot bias?

    OpenAIRE

    Valtonen, Ville-Veikko

    2013-01-01

    PURPOSE OF THE STUDY: Modern exchange betting markets represent an interesting phenomenon for economists since they closely resemble traditional financial markets. As such, they provide a practical real-life setup for testing the efficient market hypothesis. Unlike many financial assets, bets have finite life periods after which their true payoffs are revealed. Nevertheless, research on exchange betting markets is scarce to date. This thesis aspires to add to the previous literature by pr...

  6. BET Bromodomain Inhibition Suppresses the Function of Hematopoietic Transcription Factors in Acute Myeloid Leukemia.

    Science.gov (United States)

    Roe, Jae-Seok; Mercan, Fatih; Rivera, Keith; Pappin, Darryl J; Vakoc, Christopher R

    2015-06-18

    The bromodomain and extraterminal (BET) protein BRD4 is a validated drug target in leukemia, yet its regulatory function in this disease is not well understood. Here, we show that BRD4 chromatin occupancy in acute myeloid leukemia closely correlates with the hematopoietic transcription factors (TFs) PU.1, FLI1, ERG, C/EBPα, C/EBPβ, and MYB at nucleosome-depleted enhancer and promoter regions. We provide evidence that these TFs, in conjunction with the lysine acetyltransferase activity of p300/CBP, facilitate BRD4 recruitment to their occupied sites to promote transcriptional activation. Chemical inhibition of BET bromodomains was found to suppress the functional output of each hematopoietic TF, thereby interfering with essential lineage-specific transcriptional circuits in this disease. These findings reveal a chromatin-based signaling cascade comprised of hematopoietic TFs, p300/CBP, and BRD4 that supports leukemia maintenance and is suppressed by BET bromodomain inhibition. PMID:25982114

  7. A strongly heterogeneous hydrothermal area imaged by surface waves: the case of Solfatara, Campi Flegrei, Italy

    Science.gov (United States)

    Serra, Marcello; Festa, Gaetano; Roux, Philippe; Gresse, Marceau; Vandemeulebrouck, Jean; Zollo, Aldo

    2016-06-01

    We investigated the shallow structure of the Solfatara, a volcano within the Campi Flegrei caldera, southern Italy, using surface waves as a diagnostic tool. We analysed data collected during the RICEN campaign, where a 3-D active seismic experiment was performed on a dense regular grid of 90 m × 115 m using a Vibroseis as the seismic source. After removal of the source time function, we analysed the surface wave contribution to the Green's function. Here, a 1-D approximation can hold for subgrids of 40 m × 40 m. Moreover, we stacked all of the signals in the subgrid according to source-receiver distance bins, despite the absolute location of the source and the receiver, to reduce the small-scale variability in the data. We then analysed the resulting seismic sections in narrow frequency bands between 7 and 25 Hz. We obtained phase and group velocities from a grid search, and a cost function based on the spatial coherence of both the waveforms and their envelopes. We finally jointly inverted the dispersion curves of the phase and group velocities to retrieve a 1-D S-wave model local to the subgrid. Together, the models provided a 3-D description of the S-wave model in the area. We found that the maximum penetration depth is 15 m. In the first 4 m, we can associate the changes in the S-wave field to the temperature gradient, while at greater depths, the seismic images correlate with the resistivity maps, which indicate the water layer close to the Fangaia area and an abrupt variation moving towards the northeast.

  8. A strongly heterogeneous hydrothermal area imaged by surface waves: the case of Solfatara, Campi Flegrei, Italy.

    Science.gov (United States)

    Serra, Marcello; Festa, Gaetano; Roux, Philippe; Gresse, Marceau; Vandemeulebrouck, Jean; Zollo, Aldo

    2016-04-01

    We investigated the shallow structure of the Solfatara, a volcano within the Campi Flegrei caldera, southern Italy, using surface waves as a diagnostic tool. We analyzed data collected during the RICEN campaign, where a three-dimensional active seismic experiment was performed on a dense regular grid of 90 m × 115 m using a Vibroseis as the seismic source. After removal of the source time function, we analyzed the surface-wave contribution to the Green's function. Here, a one-dimensional approximation can hold for subgrids of 40 m × 40 m. Moreover, we stacked all of the signals in the subgrid according to source-receiver distance bins, despite the absolute location of the source and the receiver, to reduce the small scale variability in the data. We then analyzed the resulting seismic sections in narrow frequency bands between 7 Hz and 25 Hz. We obtained phase and group velocities from a grid search, and a cost function based on the spatial coherency of both the waveforms and their envelopes. We finally jointly inverted the dispersion curves of the phase and group velocities to retrieve a one-dimensional S-wave model local to the subgrid. Together, the models provided a three-dimensional description of the S-wave model in the area. We found that the maximum penetration depth is 15 m. In the first 4 m, we can associate the changes in the S-wave field to the temperature gradient, while at greater depths, the seismic images correlate with the resistivity maps, which indicate the water layer close to the Fangaia area, and an abrupt variation moving toward the north-east.

  9. Renal function maturation in children: is normalization to surface area valid?

    International Nuclear Information System (INIS)

    Full text: Gamma camera DTPA renograms were analysed to measure renal function by the rate at which the kidneys took up tracer from the blood. This was expressed either directly as the fractional uptake rate (FUR), which is not related to body size, or it was converted to a camera-based GFR by the formula GFR blood volume x FUR, and this GFR was normalized to a body surface area of 1.73 m2. Most of the patients studied had one completely normal kidney, and one kidney with reflux but normal function and no large scars. The completely normal kidneys contributed, on average, 50% of the total renal function. The results were considered in age bands, to display the effect of age on renal function. The camera-GFR measurements showed the conventional results of poor renal function in early childhood, with a slow rise to near-adult values by the age of 2 years, and somewhat low values throughout childhood. The uptake values showed a different pattern, with renal function rising to adult equivalent values by the age of 4 months, and with children having better renal function than adults throughout most of their childhood. The standard deviations expressed as coefficients of variation (CV) were smaller for the FUR technique than the GFR (Wilcoxon rank test, P < 0.01). These results resemble recent published measurements of absolute DMSA uptake, which are also unrelated to body size and show early renal maturation. The results also suggest that the reason children have lower serum creatinine levels than adults is that they have better renal function. If this were confirmed, it would raise doubts about the usefulness of normalizing renal function to body surface area in children

  10. Transport and retention of phosphorus in surface water in an urban slum area

    Directory of Open Access Journals (Sweden)

    P. M. Nyenje

    2013-08-01

    Full Text Available The transport of excessive phosphorus (P discharged from unsewered informal settlements (slums due to poor on-site sanitation is largely unknown. Hence, we investigated the processes governing P transport in a 28 km2 slum-dominated catchment in Kampala, Uganda. During high runoff events and a period of base flow, we collected hourly water samples (over 24 h from a primary channel draining the catchment and from a small size tertiary channel draining one of the contributing slum areas (0.5 km2. Samples were analyzed for orthophosphate (PO4-P, particulate P (PP, total P (TP and selected hydro-chemical parameters. Channel bed and suspended sediments were collected to determine their sorption potential, geo-available metals and dominant P forms. We found that P inputs in the catchment originated mainly from domestic wastewater as evidenced by high concentrations of Cl (36–144 mg L-1, HCO3 and other cations in the channels. Most P discharged during low flow conditions was particulate implying that much of it was retained in bed sediments. Retained P was mostly bound to Ca and Fe/Al oxides. Hence, we inferred that mineral precipitation and adsorption to Ca-minerals were the dominant P retention processes. Bed sediments were P-saturated and showed a tendency to release P to discharging waters. P released was likely due to Ca-bound P because of the strong correlation between Ca and total P in sediments (r2 = 0.9. High flows exhibited a strong flush of PP and SS implying that part of P retained was frequently flushed out of the catchment by surface erosion and resuspension of bed sediment. Our findings suggest that P accumulated in the channel bed during low flows and then was slowly released into surface water. Hence, it will likely take some time, even with improved wastewater management practices, before P loads to downstream areas can be significantly reduced.

  11. Contrast structure and EDLC performances of activated spherical carbons with medium and large surface areas

    International Nuclear Information System (INIS)

    Two spherical carbons of 500 and 3000 m2/g, respectively, activated with NaOH (M500) and KOH (M3000), were examined in relation to their carbon structure and electrochemical behavior to explain their contrast capacitances as EDLC electrode. M500 and M3000 showed capacitances per weight (F/g) and volume (F/ml) of 35 and 35 (M500), 40 and 25 (M3000), respectively. The charge profile of M500 by galvanostat charge indicated that the charge took place rapidly below 1.5 V and then very gradually increased up to the final voltage of 2.7 V in the first charge. Such electrochemical behavior suggests electric field activation of this particular activated carbon at the charge. The charge profile of M3000 was conventional. The structure of M500 suffered a certain marked expansion at the charge, however the 0 0 2 diffractions profile shifted very slightly to a lower angle at the change. Such charge appears reversible while the structure of expansion was more or less irreversible. No expansion was observed with M3000 at the charge to the same voltage. Such a structure allows high efficiency of EDLC due to small pores and electric field activation to induce small pores among the graphitic units. In contrast, M3000 with its larger surface areas of relatively large pores in the graphitic structure showed a larger capacitance per weight. However many useless pores cause lower the capacitance per volume. In addition, large pores lose the efficiency for the formation of an electric double layer per unit surface area of the pore, while the non-graphitic wall of M3000 fails to introduce small pores with a higher capacitance

  12. Albedo and land surface temperature shift in hydrocarbon seepage potential area, case study in Miri Sarawak Malaysia

    International Nuclear Information System (INIS)

    The presence of hydrocarbon seepage is generally associated with rock or mineral alteration product exposures, and changes of soil properties which manifest with bare development and stress vegetation. This alters the surface thermodynamic properties, changes the energy balance related to the surface reflection, absorption and emission, and leads to shift in albedo and LST. Those phenomena may provide a guide for seepage detection which can be recognized inexpensively by remote sensing method. District of Miri is used for study area. Available topographic maps of Miri and LANDSAT ETM+ were used for boundary construction and determination albedo and LST. Three land use classification methods, namely fixed, supervised and NDVI base classifications were employed for this study. By the intensive land use classification and corresponding statistical comparison was found a clearly shift on albedo and land surface temperature between internal and external seepage potential area. The shift shows a regular pattern related to vegetation density or NDVI value. In the low vegetation density or low NDVI value, albedo of internal area turned to lower value than external area. Conversely in the high vegetation density or high NDVI value, albedo of internal area turned to higher value than external area. Land surface temperature of internal seepage potential was generally shifted to higher value than external area in all of land use classes. In dense vegetation area tend to shift the temperature more than poor vegetation area

  13. 30 CFR 785.19 - Surface coal mining and reclamation operations on areas or adjacent to areas including alluvial...

    Science.gov (United States)

    2010-07-01

    ... stream, in the arid and semiarid regions of the United States, as an initial step in the permit process... application process, to separately determine the applicability of the statutory exclusions set forth in... farm's agricultural productivity and not related to surface coal operations. (c) Summary denial. If...

  14. Acid/base bifunctional carbonaceous nanomaterial with large surface area: Preparation, characterization, and adsorption properties for cationic and anionic compounds

    International Nuclear Information System (INIS)

    Nanostructured carbonaceous materials are extremely important in the nano field, yet developing simple, mild, and “green” methods that can make such materials possess large surface area and rich functional groups on their surfaces still remains a considerable challenge. Herein, a one-pot and environment-friendly method, i.e., thermal treatment (180 °C; 18 h) of water mixed with glucose and chitosan (CTS), has been proposed. The resultant carbonaceous nanomaterials were characterized by field emitting scanning electron microscope, N2 adsorption/desorption, Fourier transform infrared spectroscope, X-ray photoelectron spectroscopy, and zeta-potential analysis. It was found that, in contrast to the conventional hydrothermally carbonized product from pure glucose, with low surface area (9.3 m2 g−1) and pore volume (0.016 cm3 g−1), the CTS-added carbonaceous products showed satisfactory textural parameters (surface area and pore volume up to 254 m2 g−1 and 0.701 cm3 g−1, respectively). Moreover, it was also interestingly found that these CTS-added carbonaceous products possessed both acidic (–COOH) and basic (–NH2) groups on their surfaces. Taking the advantages of large surface area and –COOH/–NH2 bifunctional surface, the carbonaceous nanomaterials exhibited excellent performance for adsorptions of cationic compound (i.e., methylene blue) at pH 10 and anionic compound (i.e., acid red 18) at pH 2, respectively. This work not only provides a simple and green route to prepare acid/base bifunctional carbonaceous nanomaterials with large surface area but also well demonstrates their potential for application in adsorption. - Highlights: • A simple and green method was proposed to prepare carbon nanomaterials. • The carbon product showed acid/base bifunctional surface with large surface area. • The carbon material could efficiently adsorb both cationic and anionic compounds

  15. Study of Radiolaria in the surface sediments from the area east of Taiwan Island

    Institute of Scientific and Technical Information of China (English)

    CHENGZhenbo; SHIXuefa; TANZhiyuan; WUYonghua; WANGKunshan; JUXiaohua

    2004-01-01

    The species and characteristics of Radiolaria in the surface sediments were systematcally investigated in the sea east of Taiwan Island. One hundred and seventy-eight species of Radiolaria (including 21 unidentified species) have been identified in the surface sediments, and they belong to 2 orders, 34 families and 101 genera. Among them there are 19 families, 70 genera, 134 species of Spumellaria and 15 families, 31 genera, 44 species of NasseUaria. Of the 178 species of Radiolaria, the individual number of Spumellaria amounts to 88.1% of the total individual number, and that of Nassellaria amounts to 11.9% of the total individual number. It is shown that most of the dominant species belong to the tropical and subtropical dominant species and are brought into the area mainly by the Kuroshio, and some affecting factors including the submarine topography, submarine sediments, upwelling current east of Taiwan Island and carbonate dissolution play a secondary role in forming the Radiolaria distributions.

  16. Passivation of copper surfaces for selective-area ALD using a thiol self-assembled monolayer

    Science.gov (United States)

    Färm, Elina; Vehkamäki, Marko; Ritala, Mikko; Leskelä, Markku

    2012-07-01

    Self-assembled monolayers (SAMs) of 1-dodecanethiol (CH3(CH2)11SH) were prepared from the vapor phase and used as a passivation layer for selective-area ALD. Thiol SAMs have commonly been prepared by immersing the substrates into a solution containing alkyl thiols. Formation of SAMs from the vapor phase, however, has advantages compared to liquid phase preparation. Passivation of surface can be done as a part of the ALD process forming a SAM first and then continuing with the common ALD process. SAMs can also be applied to three-dimensional structures relying on chemical selectivity of the thiol SAM formation. For example in the copper damascene process the thiol SAMs should form only on the copper surface but not on the insulators. In this study, the SAMs were prepared by placing the substrate and the alkylthiol to the reaction chamber and heating the system to the temperature of 73 °C. Preparation time varied from 0.5 to 24 h. Passivation properties of SAMs were tested with ALD iridium and polyimide processes. Iridium was deposited at 250  ° C for 500 cycles and polyimide at 160  ° C for 20 cycles.

  17. Surface-water hydrologic data for the Houston metropolitan area, Texas, water years 1990?95

    Science.gov (United States)

    Sneck-Fahrer, Debra A.; Liscum, Fred; East, Jeffrey W.

    2003-01-01

    Most of the Sacramento-San Joaquin Delta was leveed, drained, and converted to agricultural use by the 1930s. Land-surface elevations have since subsided by more than 20 feet in some areas. Subsidence increases the likelihood of levee failure and flooding, which, in turn, jeopardizes water delivery and water quality in the Delta. This is of major concern because the Delta supplies water to two-thirds of California. Previous research has shown that oxidation of peat soils is the primary cause of subsidence in the Delta. Therefore, a possible strategy for remedying this situation is to convert drained agricultural fields back to wetlands, which are flooded at least part of the year. Rehabilitation of wetlands would promote the growth of peat, thereby mitigating and possibly reversing subsidence. This report describes a study that evaluated this strategy. In three experimental enclosures or ponds, carbon inputs were measured in the form of plant biomass and outputs in the form of carbon dioxide (CO2) and methane (CH4) fluxes. Each of the ponds received one of the following water treatments: seasonally flooded, seasonally flooded and irrigated, or permanently flooded. Land-surface elevation, ground-water levels, and soil and air temperature also were measured. This report presents the data collected during the initial phase of the study, which ran from November 1992 through September 1995.

  18. Development and Testing of High Surface Area Iridium Anodes for Molten Oxide Electrolysis

    Science.gov (United States)

    Shchetkovskiy, Anatoliy; McKechnie, Timothy; Sadoway, Donald R.; Paramore, James; Melendez, Orlando; Curreri, Peter A.

    2010-01-01

    Processing of lunar regolith into oxygen for habitat and propulsion is needed to support future space missions. Direct electrochemical reduction of molten regolith is an attractive method of processing, because no additional chemical reagents are needed. The electrochemical processing of molten oxides requires high surface area, inert anodes. Such electrodes need to be structurally robust at elevated temperatures (1400-1600?C), be resistant to thermal shock, have good electrical conductivity, be resistant to attack by molten oxide (silicate), be electrochemically stable and support high current density. Iridium with its high melting point, good oxidation resistance, superior high temperature strength and ductility is the most promising candidate for anodes in high temperature electrochemical processes. Several innovative concepts for manufacturing such anodes by electrodeposition of iridium from molten salt electrolyte (EL-Form? process) were evaluated. Iridium electrodeposition to form of complex shape components and coating was investigated. Iridium coated graphite, porous iridium structure and solid iridium anodes were fabricated. Testing of electroformed iridium anodes shows no visible degradation. The result of development, manufacturing and testing of high surface, inert iridium anodes will be presented.

  19. Creation of surface defects on carbon nanofibers by steam treatment

    Institute of Scientific and Technical Information of China (English)

    Zhengfeng; Shao; Min; Pang; Wei; Xia; Martin; Muhler; Changhai; Liang

    2013-01-01

    A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment.Nitrogen physisorption,XRD,Raman spectra,SEM and TEM analyses proved the existence of the new defects on CNFs.BET surface area of CNFs after steam treatment was enhanced from 20 to 378 m2/g.Pd catalysts supported on CNFs were also prepared by colloidal deposition method.The different activity of Pd/CNFs catalysts in the partial hydrogenation of phenylacetylene further demonstrated the diverse surfaces of CNFs could be formed by steam treatment.

  20. Responsiveness of the major birch allergen Bet v 1 scaffold to the gastric environment: Impact on structure and allergenic activity

    DEFF Research Database (Denmark)

    Sancho, Ana I; Wangorsch, Andrea; Jensen, Bettina M;

    2011-01-01

    Four Bet v 1 homologous food allergens from celeriac (rApi g 1), apple (rMal d 1), peach (rPru p 1) and hazelnut (rCor a 1), were used to probe the structural responsiveness of the Bet v 1 scaffold to gastric digestion conditions and its impact on allergenicity.......Four Bet v 1 homologous food allergens from celeriac (rApi g 1), apple (rMal d 1), peach (rPru p 1) and hazelnut (rCor a 1), were used to probe the structural responsiveness of the Bet v 1 scaffold to gastric digestion conditions and its impact on allergenicity....