WorldWideScience

Sample records for bench scale hydrotreating

  1. Determination and modeling of the influence of the fluid-dynamics in hydro-treating bench scale plants

    Energy Technology Data Exchange (ETDEWEB)

    Burkhardt, T.

    1999-09-16

    At an industrial scale, the hydro-treating of oil fractions is carried out in multiphase fixed bed reactors. The oil and hydrogen cross the catalyst bed, usually in co-current downflow. Since the product specifications are steadily becoming more severe, the testing of new catalysts and of modified operating conditions in pilot plants becomes increasingly important. Although these pilot plants are frequently by a factor of 100 000 smaller than the industrial units, they still have to allow the up-scaling to industrial units. In the literature relatively low conversion degrees in pilot plants are frequently reported, especially in downflow. The significantly lower fluid velocities in pilot plants seem to be responsible for such differences, as the influence of fluid-dynamic non-idealities and of the extra-particle mass transfer phenomena increases with a decrease of the fluid velocities. In the present work, the influence of important fluid-dynamic non-idealities on the hydro-treating of gas oil fractions in pilot plants was examined. This was done on the one hand in experiments with different pilot plants and on the other hand by simulations with an especially developed multiphase model. The phenomena were considered as well in an isolated manner. In order to examine any interactions with the chemical reactions, they were also studied in a reactive system. This methodology was applied to the phenomena, 'axial dispersion'and 'gas-liquid mass transfer'. (author)

  2. BENCH SCALE SALTSTONE PROCESS DEVELOPMENT MIXING STUDY

    Energy Technology Data Exchange (ETDEWEB)

    Cozzi, A.; Hansen, E.

    2011-08-03

    The Savannah River National Laboratory (SRNL) was requested to develop a bench scale test facility, using a mixer, transfer pump, and transfer line to determine the impact of conveying the grout through the transfer lines to the vault on grout properties. Bench scale testing focused on the effect the transfer line has on the rheological property of the grout as it was processed through the transfer line. Rheological and other physical properties of grout samples were obtained prior to and after pumping through a transfer line. The Bench Scale Mixing Rig (BSMR) consisted of two mixing tanks, grout feed tank, transfer pump and transfer hose. The mixing tanks were used to batch the grout which was then transferred into the grout feed tank. The contents of the feed tank were then pumped through the transfer line (hose) using a progressive cavity pump. The grout flow rate and pump discharge pressure were monitored. Four sampling stations were located along the length of the transfer line at the 5, 105 and 205 feet past the transfer pump and at 305 feet, the discharge of the hose. Scaling between the full scale piping at Saltstone to bench scale testing at SRNL was performed by maintaining the same shear rate and total shear at the wall of the transfer line. The results of scaling down resulted in a shorter transfer line, a lower average velocity, the same transfer time and similar pressure drops. The condition of flow in the bench scale transfer line is laminar. The flow in the full scale pipe is in the transition region, but is more laminar than turbulent. The resulting plug in laminar flow in the bench scale results in a region of no-mixing. Hence mixing, or shearing, at the bench scale should be less than that observed in the full scale, where this plug is non existent due to the turbulent flow. The bench scale tests should be considered to be conservative due to the highly laminar condition of flow that exists. Two BSMR runs were performed. In both cases, wall

  3. Bench-Scale Evaluation of Hydrothermal Processing Technology for Conversion of Wastewater Solids to Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Marrone, Philip A.; Elliott, Douglas C.; Billing, Justin M.; Hallen, Richard T.; Hart, Todd R.; Kadota, Paul; Moeller, Jeff C.; Randel, Margaaret A.; Schmidt, Andrew J.

    2018-04-01

    Hydrothermal Liquefaction (HTL) and Catalytic Hydrothermal Gasification (CHG) proof-of-concept bench-scale tests were performed to assess the potential of hydrothermal treatment for handling municipal wastewater sludge. HTL tests were conducted at 300-350°C and 20 MPa on three different feeds: primary sludge, secondary sludge, and digested solids. Corresponding CHG tests were conducted at 350°C and 20 MPa on the HTL aqueous phase output using a ruthenium based catalyst. Biocrude yields ranged from 25-37%. Biocrude composition and quality were comparable to biocrudes generated from algae feeds. Subsequent hydrotreating of biocrude resulted in a product with comparable physical and chemical properties to crude oil. CHG product gas methane yields on a carbon basis ranged from 47-64%. Siloxane concentrations in the CHG product gas were below engine limits. The HTL-CHG process resulted in a chemical oxygen demand (COD) reduction of > 99.9% and a reduction in residual solids for disposal of 94-99%.

  4. Application of bench-scale biocalorimetry to photoautotrophic cultures

    NARCIS (Netherlands)

    Janssen, M.; Patino, R.; Stockar, von U.

    2005-01-01

    Bench-scale biocalorimetry (=1 L) allows for the determination of the metabolic heat flow during bioprocesses under complete control of all process conditions for extended periods of time. It can be combined with a number of on-line and off-line measurement techniques. This combination can

  5. Bench Scale Saltcake Dissolution Test Report

    International Nuclear Information System (INIS)

    BECHTOLD, D.B.; PACQUET, E.A.

    2000-01-01

    A potential scenario for retrieving saltcake from single shell tanks is the ''Rainbird(reg s ign) sprinkler'' method. Water is distributed evenly across the surface of the saltcake and allowed to percolate by gravity through the waste. The salt dissolves in the water, forming a saturated solution. The saturated liquid is removed by a saltwell pump situated near the bottom of the tank. By this method, there is never a large inventory of liquid in the tank that could pose a threat of leakage. There are many variables or factors that can influence the hydrodynamics of this retrieval process. They include saltcake porosity; saltwell pumping rate; salt dissolution chemistry; factors that could promote flow channeling (e.g. tank walls, dry wells, inclusions or discontinuities in the saltcake); method of water distribution; plug formation due to crystal formations or accumulation of insoluble solids. A brief literature search indicates that very little experimental data exist on these aspects of saltcake dissolution (Wiersma 1996, 1997). The tests reported here were planned (Herting, 2000) to provide preliminary data and information for planning future, scaled-up tests of the sprinkler method

  6. Trickle bed reactor model to simulate the performance of commercial diesel hydrotreating unit

    Energy Technology Data Exchange (ETDEWEB)

    C. Murali; R.K. Voolapalli; N. Ravichander; D.T. Gokak; N.V. Choudary [Bharat Petroleum Corporation Ltd., Udyog Kendra (India). Corporate R& amp; D Centre

    2007-05-15

    A two phase mathematical model was developed to simulate the performance of bench scale and commercial hydrotreating reactors. Major hydrotreating reactions, namely, hydrodesulphurization, hydrodearomatization and olefins saturation were modeled. Experiments were carried out in a fixed bed reactor to study the effect of different process variables and these results were used for estimating kinetic parameters. Significant amount of feed vaporization (20-50%) was estimated under normal operating conditions of DHDS suggesting the importance of considering feed vaporization in DHDS modeling. The model was validated with plant operating data, under close to ultra low sulphur levels by correctly accounting for feed vaporization in heat balance relations and appropriate use of hydrodynamic correlations. The model could predict the product quality, reactor bed temperature profiles and chemical hydrogen consumption in commercial plant adequately. 14 refs., 7 figs., 6 tabs.

  7. Bench-scale magnetic separation of Department of Energy wastes

    International Nuclear Information System (INIS)

    Hoegler, J.M.

    1987-07-01

    Criteria were developed for selection of candidate wastes for testing magnetic separation of uranium and/or other paramagnetic materials. A survey of Department of Energy (DOE) hazardous wastes was conducted to determine good candidates for bench-scale magnetic separation tests. Representatives of 21 DOE sites were contacted, and 11 materials were identified as potential candidates for magnetic separation. To date, seven samples have been obtained and tested for separability of uranium with a bench-scale magnetic assaying device. The samples tested have been obtained from the K-1401B and K-1401C ponds in Oak Ridge, Tennessee; from waste piles in Maywood, New Jersey; from North and South Ponds in Richland, Washington; and from magnesium fluoride drums in Fernald, Ohio. The magnetic device utilized in these tests can be used in an open-gradient mode with dry particulate or liquid-suspended materials. Uranium separation from magnesium fluoride has shown exceptionally good performance in both open- and high-gradient modes and could be an important application of the technology

  8. Bench-Scale Evaluation of the Genifuel Hydrothermal Processing Technology for Wastewater Solids

    Energy Technology Data Exchange (ETDEWEB)

    Marrone, Philip A.; Elliott, Douglas C.; Billing, Justin M.; Hallen, Richard T.; Hart, Todd R.; Kadota, Paul; Moeller, Jeff C.; Randel, Margaaret A.; Schmidt, Andrew J.

    2017-10-03

    Hydrothermal Liquefaction (HTL) and Catalytic Hydrothermal Gasification (CHG) proof-of-concept bench-scale tests were performed to assess the potential of the Genifuel hydrothermal process technology for handling municipal wastewater sludge. HTL tests were conducted at 300-350°C and 20 MPa on three different feeds: primary sludge (11.9 wt% solids), secondary sludge (9.7 wt% solids), and post-digester sludge (also referred to as digested solids) (16.0 wt% solids). Corresponding CHG tests were conducted at 350°C and 20 MPa on the HTL aqueous phase output using a ruthenium based catalyst. A comprehensive analysis of all feed and effluent phases was also performed. Total mass and carbon balances closed to within ± 15% in all but one case. Biocrude yields from HTL tests were 37%, 25%, and 34% for primary sludge, secondary sludge, and digested solids feeds, respectively. The biocrude yields accounted for 59%, 39%, and 49% of the carbon in the feed for primary sludge, secondary sludge, and digested solids feeds, respectively. Biocrude composition and quality were comparable to that seen with biocrudes generated from algae feeds. Subsequent hydrotreating (i.e., upgrading) of the biocrude produced from primary sludge and digested solids resulted in a product with comparable physical and chemical properties to petroleum crude oil. CHG product gas consisted primarily of methane, with methane yields (relative to CHG input) on a carbon basis of 47%, 61%, and 64% for aqueous feeds that were the output of HTL tests with primary sludge, secondary sludge, and digested solids, respectively. Siloxane concentrations in the CHG product gas were below the detection limit and well below fuel input composition limits set by several engine manufacturers. Relative to that of the sludge feeds, the HTL-CHG process resulted in a reduction in chemical oxygen demand (COD) of greater than 99.9% and a reduction in residual solids for disposal of 94-99%. The test results, as a whole, support

  9. Bench-Scale Demonstration of Hot-Gas Desulfurization Technology

    International Nuclear Information System (INIS)

    Portzer, Jeffrey W.; Gangwal, Santosh K.

    1997-01-01

    Prior to the current project, development of the DSRP was done in a laboratory setting, using synthetic gas mixtures to simulate the regeneration off-gas and coal gas feeds. The objective of the current work is to further the development of zinc titanate fluidized-bed desulfurization (ZTFBD) and the DSRP for hot-gas cleanup by testing with actual coal gas. The objectives of this project are to: (1) Develop and test an integrated, skid-mounted, bench-scale ZTFBD/DSRP reactor system with a slipstream of actual coal gas; (2) Test the bench-scale DSRP over an extended period with a slipstream of actual coal gas to quantify the degradation in performance, if any, caused by the trace contaminants present in coal gas (including heavy metals, chlorides, fluorides, and ammonia); (3) Expose the DSRP catalyst to actual coal gas for extended periods and then test its activity in a laboratory reactor to quantify the degradation in performance, if any, caused by static exposure to the trace contaminants in coal gas; (4) Design and fabricate a six-fold larger-scale DSRP reactor system for future slipstream testing; (5) Further develop the fluidized-bed DSRP to handle high concentrations (up to 14 percent) of SO 2 that are likely to be encountered when pure air is used for regeneration of desulfurization sorbents; and (6) Conduct extended field testing of the 6X DSRP reactor with actual coal gas and high concentrations of SO 2 . The accomplishment of the first three objectives--testing the DSRP with actual coal gas, integration with hot-gas desulfurization, and catalyst exposure testing--was described previously (Portzer and Gangwal, 1994, 1995; Portzer et al., 1996). This paper summarizes the results of previous work and describes the current activities and plans to accomplish the remaining objectives

  10. Bench-scale/field-scale interpretations: Session overview

    International Nuclear Information System (INIS)

    Cunningham, A.B.; Peyton, B.M.

    1995-04-01

    In situ bioremediation involves complex interactions between biological, chemical, and physical processes and requires integration of phenomena operating at scales ranging from that of a microbial cell (10 -6 ) to that of a remediation site (10 to 1000 m). Laboratory investigations of biodegradation are usually performed at a relatively small scale, governed by convenience, cost, and expedience. However, extending the results from a laboratory-scale experimental system to the design and operation of a field-scale system introduces (1) additional mass transport mechanisms and limitations; (2) the presence of multiple phases, contants, and competing microorganisms (3) spatial geologic heterogeneities; and (4) subsurface environmental factors that may inhibit bacterial growth such as temperature, pH, nutrient, or redox conditions. Field bioremediation rates may be limited by the availability of one of the necessary constituents for biotransformation: substrate, contaminant, electron acceptor, nutrients, or microorganisms capable of degrading the target compound. The factor that limits the rate of bioremediation may not be the same in the laboratory as it is in the field, thereby leading, to development of unsuccessful remediation strategies

  11. Goethite Bench-scale and Large-scale Preparation Tests

    Energy Technology Data Exchange (ETDEWEB)

    Josephson, Gary B.; Westsik, Joseph H.

    2011-10-23

    The Hanford Waste Treatment and Immobilization Plant (WTP) is the keystone for cleanup of high-level radioactive waste from our nation's nuclear defense program. The WTP will process high-level waste from the Hanford tanks and produce immobilized high-level waste glass for disposal at a national repository, low activity waste (LAW) glass, and liquid effluent from the vitrification off-gas scrubbers. The liquid effluent will be stabilized into a secondary waste form (e.g. grout-like material) and disposed on the Hanford site in the Integrated Disposal Facility (IDF) along with the low-activity waste glass. The major long-term environmental impact at Hanford results from technetium that volatilizes from the WTP melters and finally resides in the secondary waste. Laboratory studies have indicated that pertechnetate ({sup 99}TcO{sub 4}{sup -}) can be reduced and captured into a solid solution of {alpha}-FeOOH, goethite (Um 2010). Goethite is a stable mineral and can significantly retard the release of technetium to the environment from the IDF. The laboratory studies were conducted using reaction times of many days, which is typical of environmental subsurface reactions that were the genesis of this new process. This study was the first step in considering adaptation of the slow laboratory steps to a larger-scale and faster process that could be conducted either within the WTP or within the effluent treatment facility (ETF). Two levels of scale-up tests were conducted (25x and 400x). The largest scale-up produced slurries of Fe-rich precipitates that contained rhenium as a nonradioactive surrogate for {sup 99}Tc. The slurries were used in melter tests at Vitreous State Laboratory (VSL) to determine whether captured rhenium was less volatile in the vitrification process than rhenium in an unmodified feed. A critical step in the technetium immobilization process is to chemically reduce Tc(VII) in the pertechnetate (TcO{sub 4}{sup -}) to Tc(Iv)by reaction with the

  12. Oxygen-controlled Biosurfactant Production in a Bench Scale Bioreactor

    Science.gov (United States)

    de Kronemberger, Frederico Araujo; Anna, Lidia Maria Melo Santa; Fernandes, Ana Carolina Loureiro Brito; de Menezes, Reginaldo Ramos; Borges, Cristiano Piacsek; Freire, Denise Maria Guimarães

    Rhamnolipids have been pointed out as promising biosurfactants. The most studied microorganisms for the aerobic production of these molecules are the bacteria of the genus Pseudomonas. The aim of this work was to produce a rhamnolipid-type biosurfactant in a bench-scale bioreactor by one strain of Pseudomonas aeruginosa isolated from oil environments. To study the microorganism growth and production dependency on oxygen, a nondispersive oxygenation device was developed, and a programmable logic controller (PLC) was used to set the dissolved oxygen (DO) concentration. Using the data stored in a computer and the predetermined characteristics of the oxygenation device, it was possible to evaluate the oxygen uptake rate (OUR) and the specific OUR (SOUR) of this microorganism. These rates, obtained for some different DO concentrations, were then compared to the bacterial growth, to the carbon source consumption, and to the rhamnolipid and other virulence factors production. The SOUR presented an initial value of about 60.0 mg02/gdw h. Then, when the exponential growth phase begins, there is a rise in this rate. After that, the SOUR reduces to about 20.0 mg02/gdw h. The carbon source consumption is linear during the whole process.

  13. A bench-scale biotreatability methodology to evaluate field bioremediation

    International Nuclear Information System (INIS)

    Saberiyan, A.G.; MacPherson, J.R. Jr.; Moore, R.; Pruess, A.J.; Andrilenas, J.S.

    1995-01-01

    A bench-scale biotreatability methodology was designed to assess field bioremediation of petroleum contaminated soil samples. This methodology was performed successfully on soil samples from more than 40 sites. The methodology is composed of two phases, characterization and experimentation. The first phase is physical, chemical, and biological characterization of the contaminated soil sample. This phase determines soil parameters, contaminant type, presence of indigenous contaminant-degrading bacteria, and bacterial population size. The second phase, experimentation, consists of a respirometry test to measure the growth of microbes indirectly (via generation of CO 2 ) and the consumption of their food source directly (via contaminant loss). Based on a Monod kinetic analysis, the half-life of a contaminant can be calculated. Abiotic losses are accounted for based on a control test. The contaminant molecular structure is used to generate a stoichiometric equation. The stoichiometric equation yields a theoretical ratio for mg of contaminant degraded per mg of CO 2 produced. Data collected from the respirometry test are compared to theoretical values to evaluate bioremediation feasibility

  14. Bench scale demonstration and conceptual engineering for DETOXSM catalyzed wet oxidation

    International Nuclear Information System (INIS)

    Moslander, J.; Bell, R.; Robertson, D.; Dhooge, P.; Goldblatt, S.

    1994-01-01

    Laboratory and bench scale studies of the DETOX SM catalyzed wet oxidation process have been performed with the object of developing the process for treatment of hazardous and mixed wastes. Reaction orders, apparent rates, and activation energies have been determined for a range of organic waste surrogates. Reaction intermediates and products have been analyzed. Metals' fates have been determined. Bench scale units have been designed, fabricated, and tested with solid and liquid organic waste surrogates. Results from the laboratory and bench scale studies have been used to develop conceptual designs for application of the process to hazardous and mixed wastes

  15. Bench-scale studies with mercury contaminated SRS soil

    International Nuclear Information System (INIS)

    Cicero, C.A.

    1995-01-01

    Bench-scale studies with mercury contaminated soil were performed at the SRTC to determine the optimum waste loading obtainable in the glass product without sacrificing durability, leach resistance, and processability. Vitrifying this waste stream also required offgas treatment for the capture of the vaporized mercury. Four soil glasses with slight variations in composition were produced, which were capable of passing the Product Consistency Test (PCT) and the Toxicity Characteristic Leaching Procedure (TCLP). The optimum glass feed composition contained 60 weight percent soil and produced a soda-lime-silica glass when melted at 1,350 C. The glass additives used to produce this glass were 24 weight percent Na 2 CO 3 and 16 weight percent CaCO 3 . Volatilized mercury released during the vitrification process was released to the proposed mercury collection system. The proposed mercury collection system consisted of quartz and silica tubing with a Na 2 S wash bottle followed by a NaOH wash bottle. Once in the system, the volatile mercury would pass through the wash bottle containing Na 2 S, where it would be converted to Hg 2 S, which is a stable form of mercury. However, attempts to capture the volatilized mercury in a Na 2 S solution wash bottle were not as successful as anticipated. Maximum mercury captured was only about 3.24% of the mercury contained in the feed. Mercury capture efforts then shifted to condensing and capturing the volatilized mercury. These attempts were much more successful at capturing the volatile mercury, with a capture efficiency of 34.24% when dry ice was used to pack the condenser. This captured mercury was treated on a mercury specific resin after digestion of the volatilized mercury

  16. Study on saccharification of cellulosic wastes with bench scale test plant, (5)

    International Nuclear Information System (INIS)

    Kasai, Noboru; Tamada, Masao; Kumakura, Minoru

    1989-05-01

    This report completed the results that were obtained on the studies of continuous saccharification of radiation pretreated chaff with a saccharification equipment unit of bench scale test plant for cellulosic wastes. The problem on the continuous saccharification in bench scale and its countermeasure were clarified. The glucose concentration obtained in the continuous saccharification was examined from the point of a scale up effect. It was found that there are not a scale up effect between flask scale (100 ml) and bench scale (50 l) and then the same concentration of glucose was obtained in both scales. It was clarified that the contamination of the process let decrease markedly the concentration of produced glucose solution and brings on a large trouble for the saccharification. The addition of 1 % ethyl acetate made it possible to prevent the contamination of the saccharification process in flask scale. However, in the case of continuous saccharification in bench scale, the addition of ethyl acetate in nitrogen gas atmosphere was necessary to prevent the contamination. It was found that the solution of 1.7 % glucose concentration was continuously produced in the continuous saccharification with the most longest period for 26 days. It was, also, suggested that the selection of a suitable retention time is necessary to attain a high glucose productivity in the continuous saccharification. (author)

  17. Bench-scale treatability studies for simulated incinerator scrubber blowdown containing radioactive cesium and strontium

    International Nuclear Information System (INIS)

    Coroneos, A.C.; Taylor, P.A.; Arnold, W.D. Jr.; Bostick, D.A.; Perona, J.J.

    1994-12-01

    The purpose of this report is to document the results of bench-scale testing completed to remove 137 Cs and 90 Sr from the Oak Ridge K-25 Site Toxic Substances Control Act (TSCA) Incinerator blowdown at the K-25 Site Central Neutralization Facility, a wastewater treatment facility designed to remove heavy metals and uranium from various wastewaters. The report presents results of bench-scale testing using chabazite and clinoptilolite zeolites to remove cesium and strontium; using potassium cobalt ferrocyanide (KCCF) to remove cesium; and using strontium chloride coprecipitation, sodium phosphate coprecipitation, and calcium sulfate coprecipitation to remove strontium. Low-range, average-range, and high-range concentration blowdown surrogates were used to complete the bench-scale testing

  18. Cometabolic biotreatment of TCE-contaminated groundwater: Laboratory and bench-scale development studies

    International Nuclear Information System (INIS)

    Donaldson, T.L.; Jennings, H.L.; Lucero, A.J.; Strandberg, G.W.; Morris, M.I.; Palumbo, A.V.; Boerman, P.A.; Tyndall, R.L.

    1992-01-01

    The Oak Ridge National Laboratory is conducting a demonstration of two cometabolic technologies for biotreatment of groundwater contaminated with trichloroethylene (TCE) and other organics. Technologies based on methanotrophic (methane-utilizing) and toluene-degrading microorganisms will be compared side-by-side on the same groundwater stream. Laboratory and bench-scale bioreactor studies have been conducted to guide selection of microbial cultures and operating conditions for the field demonstration. This report presents the results of the laboratory and bench-scale studies for the methanotrophic system

  19. Cometabolic biotreatment of TCE-contaminated groundwater - Laboratory and bench-scale development studies

    Energy Technology Data Exchange (ETDEWEB)

    Donaldson, T L; Palumbo, A V; Boerman, P A; Jennings, H L; Lucero, A J; Tyndall, R L; Strandberg, G W; Morris, M I [Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    1992-07-01

    The Oak Ridge National Laboratory is conducting a demonstration of two cometabolic technologies for biotreatment of groundwater contaminated with trichloroethylene (TCE) and other organics. Technologies based on methanotrophic (methane-utilizing) and toluene-degrading microorganisms will be compared side-by-side on the same groundwater stream. Laboratory and bench-scale bioreactor studies have been conducted to guide selection of microbial cultures and operating conditions for the field demonstration. This report presents the results of the laboratory and bench-scale studies for the methanotrophic system. (author)

  20. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    Energy Technology Data Exchange (ETDEWEB)

    Gary Blythe; John Currie; David DeBerry

    2008-03-31

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling

  1. Performance evaluation of the DCMD desalination process under bench scale and large scale module operating conditions

    KAUST Repository

    Francis, Lijo; Ghaffour, NorEddine; Alsaadi, Ahmad Salem; Nunes, Suzana Pereira; Amy, Gary L.

    2014-01-01

    The flux performance of different hydrophobic microporous flat sheet commercial membranes made of poly tetrafluoroethylene (PTFE) and poly propylene (PP) was tested for Red Sea water desalination using the direct contact membrane distillation (DCMD) process, under bench scale (high δT) and large scale module (low δT) operating conditions. Membranes were characterized for their surface morphology, water contact angle, thickness, porosity, pore size and pore size distribution. The DCMD process performance was optimized using a locally designed and fabricated module aiming to maximize the flux at different levels of operating parameters, mainly feed water and coolant inlet temperatures at different temperature differences across the membrane (δT). Water vapor flux of 88.8kg/m2h was obtained using a PTFE membrane at high δT (60°C). In addition, the flux performance was compared to the first generation of a new locally synthesized and fabricated membrane made of a different class of polymer under the same conditions. A total salt rejection of 99.99% and boron rejection of 99.41% were achieved under extreme operating conditions. On the other hand, a detailed water characterization revealed that low molecular weight non-ionic molecules (ppb level) were transported with the water vapor molecules through the membrane structure. The membrane which provided the highest flux was then tested under large scale module operating conditions. The average flux of the latter study (low δT) was found to be eight times lower than that of the bench scale (high δT) operating conditions.

  2. Performance evaluation of the DCMD desalination process under bench scale and large scale module operating conditions

    KAUST Repository

    Francis, Lijo

    2014-04-01

    The flux performance of different hydrophobic microporous flat sheet commercial membranes made of poly tetrafluoroethylene (PTFE) and poly propylene (PP) was tested for Red Sea water desalination using the direct contact membrane distillation (DCMD) process, under bench scale (high δT) and large scale module (low δT) operating conditions. Membranes were characterized for their surface morphology, water contact angle, thickness, porosity, pore size and pore size distribution. The DCMD process performance was optimized using a locally designed and fabricated module aiming to maximize the flux at different levels of operating parameters, mainly feed water and coolant inlet temperatures at different temperature differences across the membrane (δT). Water vapor flux of 88.8kg/m2h was obtained using a PTFE membrane at high δT (60°C). In addition, the flux performance was compared to the first generation of a new locally synthesized and fabricated membrane made of a different class of polymer under the same conditions. A total salt rejection of 99.99% and boron rejection of 99.41% were achieved under extreme operating conditions. On the other hand, a detailed water characterization revealed that low molecular weight non-ionic molecules (ppb level) were transported with the water vapor molecules through the membrane structure. The membrane which provided the highest flux was then tested under large scale module operating conditions. The average flux of the latter study (low δT) was found to be eight times lower than that of the bench scale (high δT) operating conditions.

  3. Domestic Wastewater Reuse in Concrete Using Bench-Scale Testing and Full-Scale Implementation

    Directory of Open Access Journals (Sweden)

    Ayoup M. Ghrair

    2016-08-01

    Full Text Available Demand for fresh water by the construction sector is expected to increase due to the high increase in the growth of construction activities in Jordan. This study aims to evaluate the potential of scale-up of the application of treated domestic wastewater in concrete from bench-scale to a full-scale. On the lab scale, concrete and mortar mixes using Primary and Secondary Treated Wastewater (PTW, STW and Distilled Water (DW were cast and tested after various curing ages (7, 28, 120, and 200 days. Based on wastewater quality, according to IS 456-2000, the STW is suitable for mortar and concrete production. Mortar made with STW at curing time up to 200 days has no significant negative effect on the mortar’s compressive strength. Conversely, the PTW exceeded the maximum permissible limits of total organic content and E coli. for concrete mixing-water. Using PTW results, a significant increase in the initial setting time of up to 16.7% and a decrease in the concrete workability are observed. In addition, using PTW as mixing water led to a significant reduction in the compressive strength up to 19.6%. The results that came out from scaling up to real production operation of ready-mix concrete were in harmony with the lab-scale results.

  4. Process developments in gasoil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Lawrence, R.C.; Kinley, D.H.; Wood, M.A. [Davy Process Technology Limited, London (United Kingdom)

    1997-07-01

    Changing demand patterns and legislation increase the pressure upon hydrotreating capacities at many refineries. To meet these pressures, improvements have been and will be necessary not only in catalysts, but also in the hydrotreating process. On the basis of its hydrogenation experience, Davy Process Technology has developed and tested a number of concepts aimed at improving the effectiveness of the basic process - enabling economic deep desulfurisation and opening up the potential for an integrated HDS/HDA flowsheet using sulphur tolerant HDA Catalysts.

  5. Bench-Scale Evaluation of Peracetic Acid and Twin Oxide ™ as Disinfectants in Drinking Water

    Science.gov (United States)

    Chlorine is widely used as an inexpensive and potent disinfectant in the United States for drinking water. However, chlorine has the potential for forming carcinogenic and mutagenic disinfection by-products (DBPs). In this study, bench scale experiments were conducted at the U.S...

  6. Genifuel Hydrothermal Processing Bench Scale Technology Evaluation Project (WE&RF Report LIFT6T14)

    Science.gov (United States)

    Hydrothermal Liquefaction (HTL) and Catalytic Hydrothermal Gasification (CHG) proof-of-concept bench-scale tests were performed to assess the potential of the Genifuel hydrothermal process technology for handling municipal wastewater sludge. HTL tests were conducted at 300-350◦C ...

  7. DEGRADATION OF POLYNUCLEAR AROMATIC HYDROCARBONS UNDER BENCH-SCALE COMPOST CONDITIONS

    Science.gov (United States)

    The relationship between biomass growth and degradation of polynuclear aromatic hydrocarbons (PAHs) in soil, and subsequent toxicity reduction, was evaluated in 10 in-vessel, bench-scale compost units. Field soil was aquired from the Reilly Tar and Chemical Company Superfund site...

  8. Hydrotreating of coal-derived liquids

    Energy Technology Data Exchange (ETDEWEB)

    Lott, S.E.; Stohl, F.V.; Diegert, K.V. [Sandia National Lab., Albuquerque, NM (United States)] [and others

    1995-12-31

    To develop a database relating hydrotreating parameters to feed and product quality by experimentally evaluating options for hydrotreating whole coal liquids, distillate cuts of coal liquids, petroleum, and blends of coal liquids with petroleum.

  9. Atomic-scale insight into the origin of pyridine inhibition of MoS2-based hydrotreating catalysts

    DEFF Research Database (Denmark)

    Temel, Burcin; Tuxen, Anders K.; Kibsgaard, Jakob

    2010-01-01

    in earlier IR experiments on high surface alumina-supported MoS2 catalyst. The adsorption sites appear to be very similar to the brim sites involved in hydrogenation reactions in HDS. Thus, the combined STM and DFT results provide new atomic-scale insight into the inhibition effect of basic N......-compounds in HDS and the first direct observation of the adsorption mode of basic N-compounds on the catalytically active MoS2 edges. Our results lend further support to previously reported correlations between inhibiting strength and proton affinity for the N-containing compounds....

  10. Atomic-scale investigation of the interaction of organic molecules with MoS2-based hydrotreating model catalysts

    DEFF Research Database (Denmark)

    Salazar Moreira, Norberto José

    The aim of this work is to provide new insight into the formation, activation and reactivity of hydrotreating catalysts extensively used in the refinery for the conversion of heavy feedstocks and for improving the quality of the final oil products. This is done through numerous studies of the con......The aim of this work is to provide new insight into the formation, activation and reactivity of hydrotreating catalysts extensively used in the refinery for the conversion of heavy feedstocks and for improving the quality of the final oil products. This is done through numerous studies...... of the conversion of molybdenum oxides and metallic precursors into molybdenum disulfide (MoS2), the active phase involved in most of the hydrotreating reactions, especially for those dedicated to the removal of sulfur from various fuel fractions, commonly referred to as hydrodesulfurization (HDS). The evolution...... the presence of the reduced MoOx phase impedes the MoS2 growth and leads to rather stable amorphous oxysulfide phases. The sulfidation in H2S atmosphere of molybdenum metal and bimetallic cobalt-molybdenum clusters deposited on Au(111) facilitate instead the formation of well-dispersed MoS2 and Co-promoted Mo...

  11. 100 Area soil washing bench-scale test procedures

    International Nuclear Information System (INIS)

    Freeman, H.D.; Gerber, M.A.; Mattigod, S.V.; Serne, R.J.

    1993-03-01

    This document describes methodologies and procedures for conducting soil washing treatability tests in accordance with the 100 Area Soil Washing Treatability Test Plan (DOE-RL 1992, Draft A). The objective of this treatability study is to evaluate the use of physical separation systems and chemical extraction methods as a means of separating chemically and radioactively contaminated soil fractions from uncontaminated soil fractions. These data will be primarily used for determining feasibility of the individual unit operations and defining the requirements for a system, or systems, for pilot-scale testing

  12. Bench-scale and full-scale studies of nitric oxides reduction by gaseous fuel reburning

    International Nuclear Information System (INIS)

    Su, S.; Xiang, J.; Sun, L.S.; Hu, S.; Zhu, J.M.

    2008-01-01

    Nitrogen oxides (NOx) emissions from coal-fired boilers are significant contributors to atmospheric pollution. China has specified more rigorous legal limits for NOx emissions from power plants. As a result of the need to reduce NOx emissions, cost-effective NOx reduction strategies must be explored. This paper presented detailed experimental studies on a gaseous fuel reburning process that was performed in a 36 kilowatt bench-scale down-fired furnace to define the optimal reburning operating conditions when different Chinese coals were fired in the furnace. In addition, the combustion system of a 350 megawatt full-scale boiler was retrofitted according to the experimental results. Finally, the gaseous fuel reburning was applied to the retrofitted full-scale boiler. The purpose of the study was to obtain a better understanding of the influence of the key parameters on nitric oxide (NO) reduction efficiency of the reburning process and demonstrate the gaseous fuel reburning on a 350 MWe coal-fired boiler in China. The paper described the experimental procedure with particular reference to the experimental facility and measurement; a schematic diagram of the experimental system; experimental fuels; and characteristics of coals for the reburning experiments. Results that were presented included influence of reburn zone residence time; influence of gaseous reburn fuel per cent; influence of excess air coefficient; and unburned carbon in fly ash. It was concluded that both an above 50 per cent NO reduction efficiency and low carbon loss can be obtained by the gaseous fuel reburning process under the optimal operating conditions. 20 refs., 5 tabs., 10 figs

  13. Bench-Scale and Pilot-Scale Treatment Technologies for the ...

    Science.gov (United States)

    Coal mine water (CMW) is typically treated to remove suspended solids, acidity, and soluble metals, but high concentrations of total dissolved solids (TDS) have been reported to impact the environment at several CMW discharge points. Consequently, various states have established TDS wastewater regulations and the US EPA has proposed a benchmark conductivity limit to reduce TDS impacts in streams near mining sites. Traditional CMW treatment effectively removes some TDS components, but is not effective in removing major salt ions due to their higher solubility. This paper describes the basic principles, effectiveness, advantages and disadvantages of various TDS removal technologies (adsorption, bioremediation, capacitive deionization, desalination, electro-chemical ion exchange, electrocoagulation, electrodialysis, ion exchange, membrane filtration, precipitation, and reverse osmosis) that have at least been tested in bench- and pilot-scale experiments. Recent discussions about new regulations to include total dissolved solids TDS) limits would propel interest in the TDS removal technologies focused on coal mine water. TDS removal is not a new concept and has been developed using different technologies for a number of applications, but coal mine water has unique characteristics (depending on the site, mining process, and solid-water-oxygen interactions), which make it unlikely to have a single technology predominating over others. What are some novel technolog

  14. Simulation of large scale air detritiation operations by computer modeling and bench-scale experimentation

    International Nuclear Information System (INIS)

    Clemmer, R.G.; Land, R.H.; Maroni, V.A.; Mintz, J.M.

    1978-01-01

    Although some experience has been gained in the design and construction of 0.5 to 5 m 3 /s air-detritiation systems, little information is available on the performance of these systems under realistic conditions. Recently completed studies at ANL have attempted to provide some perspective on this subject. A time-dependent computer model was developed to study the effects of various reaction and soaking mechanisms that could occur in a typically-sized fusion reactor building (approximately 10 5 m 3 ) following a range of tritium releases (2 to 200 g). In parallel with the computer study, a small (approximately 50 liter) test chamber was set up to investigate cleanup characteristics under conditions which could also be simulated with the computer code. Whereas results of computer analyses indicated that only approximately 10 -3 percent of the tritium released to an ambient enclosure should be converted to tritiated water, the bench-scale experiments gave evidence of conversions to water greater than 1%. Furthermore, although the amounts (both calculated and observed) of soaked-in tritium are usually only a very small fraction of the total tritium release, the soaked tritium is significant, in that its continuous return to the enclosure extends the cleanup time beyond the predicted value in the absence of any soaking mechanisms

  15. Data Quality Objectives For Selecting Waste Samples For Bench-Scale Reformer Treatability Studies

    International Nuclear Information System (INIS)

    Banning, D.L.

    2011-01-01

    This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required. The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.

  16. Design and fabrication of a glovebox for the Plasma Hearth Process radioactive bench-scale system

    International Nuclear Information System (INIS)

    Wahlquist, D.R.

    1996-01-01

    This paper presents some of the design considerations and fabrication techniques for building a glovebox for the Plasma Hearth Process (PHP) radioactive bench-scale system. The PHP radioactive bench-scale system uses a plasma torch to process a variety of radioactive materials into a final vitrified waste form. The processed waste will contain plutonium and trace amounts of other radioactive materials. The glovebox used in this system is located directly below the plasma chamber and is called the Hearth Handling Enclosure (HHE). The HHE is designed to maintain a confinement boundary between the processed waste and the operator. Operations that take place inside the HHE include raising and lowering the hearth using a hydraulic lift table, transporting the hearth within the HHE using an overhead monorail and hoist system, sampling and disassembly of the processed waste and hearth, weighing the hearth, rebuilding a hearth, and sampling HEPA filters. The PHP radioactive bench-scale system is located at the TREAT facility at Argonne National Laboratory-West in Idaho Falls, Idaho

  17. Embedded Sensors and Controls to Improve Component Performance and Reliability -- Bench-scale Testbed Design Report

    Energy Technology Data Exchange (ETDEWEB)

    Melin, Alexander M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kisner, Roger A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Drira, Anis [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Reed, Frederick K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-09-01

    Embedded instrumentation and control systems that can operate in extreme environments are challenging due to restrictions on sensors and materials. As a part of the Department of Energy's Nuclear Energy Enabling Technology cross-cutting technology development programs Advanced Sensors and Instrumentation topic, this report details the design of a bench-scale embedded instrumentation and control testbed. The design goal of the bench-scale testbed is to build a re-configurable system that can rapidly deploy and test advanced control algorithms in a hardware in the loop setup. The bench-scale testbed will be designed as a fluid pump analog that uses active magnetic bearings to support the shaft. The testbed represents an application that would improve the efficiency and performance of high temperature (700 C) pumps for liquid salt reactors that operate in an extreme environment and provide many engineering challenges that can be overcome with embedded instrumentation and control. This report will give details of the mechanical design, electromagnetic design, geometry optimization, power electronics design, and initial control system design.

  18. Competition Between Hydrotreating and Polymerization Reactions During Pyrolysis Oil Hydrodeoxygenation

    NARCIS (Netherlands)

    Mercader, F. De Miguel; Koehorst, P. J. J.; Heeres, H. J.; Kersten, S. R. A.; Hogendoorn, J. A.

    2011-01-01

    Hydrodeoxygenation (HDO) of pyrolysis oil is an upgrading step that allows further coprocessing of the oil product in (laboratory-scale) standard refinery units to produce advanced biofuels. During HDO, desired hydrotreating reactions are in competition with polymerization reactions that can lead to

  19. Interferometric 30 m bench for calibrations of 1D scales and optical distance measuring instruments

    International Nuclear Information System (INIS)

    Unkuri, J; Rantanen, A; Manninen, J; Esala, V-P; Lassila, A

    2012-01-01

    During construction of a new metrology building for MIKES, a 30 m interferometric bench was designed. The objective was to implement a straight, stable, adjustable and multifunctional 30 m measuring bench for calibrations. Special attention was paid to eliminating the effects of thermal expansion and inevitable concrete shrinkage. The linear guide, situated on top of a monolithic concrete beam, comprises two parallel round shafts with adjustable fixtures every 1 m. A carriage is moved along the rail and its position is followed by a reference interferometer. Depending on the measurement task, one or two retro-reflectors are fixed on the carriage. A microscope with a CCD camera and a monitor can be used to detect line mark positions on different line standards. When calibrating optical distance measuring instruments, various targets can be fixed to the carriage. For the most accurate measurements an online Abbe-error correction based on simultaneous carriage pitch measurement by a separate laser interferometer is applied. The bench is used for calibrations of machinist scales, tapes, circometers, electronic distance meters, total stations and laser trackers. The estimated expanded uncertainty for 30 m displacement for highest accuracy calibrations is 2.6 µm. (paper)

  20. Accumulation of uranium, cesium, and radium by microbial cells: bench-scale studies

    International Nuclear Information System (INIS)

    Strandberg, G.W.; Shumate, S.E. II.

    1982-07-01

    This report describes bench-scale studies on the utilization of microbial cells for the concentration and removal of uranium, radium, and cesium from nuclear processing waste streams. Included are studies aimed at elucidating the basic mechanism of uranium uptake, process development efforts for the use of a combined denitrification-uranium removal process to treat a specific nuclear processing waste stream, and a preliminary investigation of the applicability of microorganisms for the removal of 137 Cs and 226 Ra from existing waste solutions

  1. Coal flotation - bench-scale study. Flotacao de carvao estudo em escala de bancada

    Energy Technology Data Exchange (ETDEWEB)

    Campos, A.R. de; Almeida, S L.M. de; Santos, A.T. dos

    1979-01-01

    Run-of-mine coal and pre-washed coal from Santa Catarina, Brazil, were characterized using washability curves and by particle size analysis after crushing. Bench-scale froth flotation tests were then conducted with the pre-washed coal. Kerosene and diesel oil were used as the collectors, and pine oil as the frother. The influence of starch (as depressor) on flotation was also studied. The effects of feed particle size, pH, collector addition, frother addition, depressor addition and flotation time were investigated. A 9.5% ash content coal could be obtained with a mass recovery of about 29%. (17 refs.)

  2. Electrokinetic soil decontamination - summary of results of various studies in laboratory, bench-scale and field

    Energy Technology Data Exchange (ETDEWEB)

    Kutschan, B.; Wutzler, R.; Goldmann, T. [INTUS Inst. fuer Technologie und Umweltschutz e.V., Berlin (Germany)

    2001-07-01

    In electroremediation, contaminants are removed form soil and groundwater by the action of an electric potential applied across electrodes embedded in the contaminated medium. Driving the remediation are the electrokinetic phenomena of electro-osmosis, ion migration and electrophoresis. Other common physicochemical phenomena that are also present are diffusion, chemical reactions, hydrolysis (change of pH-value), ion exchange, complexation and others. The complex interactions between all these phenomena determine the processes. Important process parameters are transition rates, bulk liquid velocity, {zeta}-potential (Helmholtz-Smoluchowski-equation) and others. Some parameters are determined at laboratory-, bench- and field scale. (orig.)

  3. Bench- and field-scale evaluation of chromium and cadmium extraction by electrokinetics

    International Nuclear Information System (INIS)

    Gent, David B.; Bricka, R. Mark; Alshawabkeh, Akram N.; Larson, Steven L.; Fabian, Gene; Granade, Steve

    2004-01-01

    The results of bench-scale laboratory tests and in situ, pilot-scale demonstration of electrokinetic extraction of chromium and cadmium from contaminated soil are presented. The laboratory tests were conducted using 10 cm long samples under current density of 5 A/m 2 for 1200 h. Tests were conducted with and without citric acid amendment at the cathode. The results showed that citric acid improved extraction, especially in the sections near the cathode. However, processing was not enough to result in complete cleanup. The field demo was conducted at the Naval Air Weapon Station (NAWS), Point Mugu, California. Three cathodes were centered between six anodes. The anode-cathode spacing was 4.45 m (15 ft). Constant voltage of 60 V (∼13 V/m) was applied for 20 days and then was reduced to 45 V (10 V/m) for 6 months. Citric acid was used to maintain the cathode pH at 4. After 6 months of treatment, 78% of the soil volume has been cleared of chromium or treated to below natural background levels. The results also indicated that 70% of the soil between the electrodes had been cleared of cadmium contamination. A comparison between the bench-scale and field demo showed that the field process was more effective than the lab tests. This indicated that small sample size will induce a negative effect on the efficiency of the process due to an increased impact of the boundaries on the overall process

  4. Bench-Scale Silicone Process for Low-Cost CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Wood, Benjamin; Genovese, Sarah; Perry, Robert; Spiry, Irina; Farnum, Rachael; Sing, Surinder; Wilson, Paul; Buckley, Paul; Acharya, Harish; Chen, Wei; McDermott, John; Vipperia, Ravikumar; Yee, Michael; Steele, Ray; Fresia, Megan; Vogt, Kirk

    2013-12-31

    A bench-scale system was designed and built to test an aminosilicone-based solvent. A model was built of the bench-scale system and this model was scaled up to model the performance of a carbon capture unit, using aminosilicones, for CO{sub 2} capture and sequestration (CCS) for a pulverized coal (PC) boiler at 550 MW. System and economic analysis for the carbon capture unit demonstrates that the aminosilicone solvent has significant advantages relative to a monoethanol amine (MEA)-based system. The CCS energy penalty for MEA is 35.9% and the energy penalty for aminosilicone solvent is 30.4% using a steam temperature of 395 °C (743 °F). If the steam temperature is lowered to 204 °C (400 °F), the energy penalty for the aminosilicone solvent is reduced to 29%. The increase in cost of electricity (COE) over the non-capture case for MEA is ~109% and increase in COE for aminosilicone solvent is ~98 to 103% depending on the solvent cost at a steam temperature of 395 °C (743 °F). If the steam temperature is lowered to 204 °C (400 °F), the increase in COE for the aminosilicone solvent is reduced to ~95-100%.

  5. In situ remediation of hexavalent chromium with pyrite fines : bench scale demonstration

    International Nuclear Information System (INIS)

    Cathum, S.; Wong, W.P.; Brown, C.E.

    2002-01-01

    An in situ remediation technique for chromium contaminated soil with pyrite fines was presented. Past industrial activities and lack of disposal facilities have contributed to a serious problem dealing with chromium, which cannot be eliminated from the environment because it is an element. Both bench-scale and laboratory testing was conducted to confirm the efficiency of the proposed process which successfully converted Cr(VI) into Cr(III) in soil and water. Cr(III) is less toxic and immobile in the environment compared to Cr(VI) which moves freely in the soil matrix, posing a risk to the groundwater quality. pH in the range of 2.0 to 7.6 has no effect on the reactivity of pyrite towards Cr(VI). The optimization of the bench-scale treatment resulted in a large volume of chromium waste, mostly from the control experiments and column hydrology testing. These waste streams were treated according to municipal guidelines before disposal to the environment. Samples of chromium waste before and after treatment were analyzed. Cr (VI) was completely mineralized to below guideline levels. It was determined that several conditions, including contact time between pyrite and Cr(VI), are crucial for complete mineralization of Cr(VI). 13 refs., 8 tabs., 9 figs

  6. Evaluation of malodor for automobile air conditioner evaporator by using laboratory-scale test cooling bench.

    Science.gov (United States)

    Kim, Kyung Hwan; Kim, Sun Hwa; Jung, Young Rim; Kim, Man Goo

    2008-09-12

    As one of the measures to improve the environment in an automobile, malodor caused by the automobile air-conditioning system evaporator was evaluated and analyzed using laboratory-scale test cooling bench. The odor was simulated with an evaporator test cooling bench equipped with an airflow controller, air temperature and relative humidity controller. To simulate the same odor characteristics that occur from automobiles, one previously used automobile air conditioner evaporator associated with unpleasant odors was selected. The odor was evaluated by trained panels and collected with aluminum polyester bags. Collected samples were analyzed by thermal desorption into a cryotrap and subsequent gas chromatographic separation, followed by simultaneous olfactometry, flame ionization detector and identified by atomic emission detection and mass spectrometry. Compounds such as alcohols, aldehydes, and organic acids were identified as responsible odor-active compounds. Gas chromatography/flame ionization detection/olfactometry combined sensory method with instrumental analysis was very effective as an odor evaluation method in an automobile air-conditioning system evaporator.

  7. A novel bench-scale column assay to investigate site-specific nitrification biokinetics in biological rapid sand filters

    DEFF Research Database (Denmark)

    Tatari, Karolina; Smets, Barth F.; Albrechtsen, Hans-Jørgen

    2013-01-01

    A bench-scale assay was developed to obtain site-specific nitrification biokinetic information from biological rapid sand filters employed in groundwater treatment. The experimental set-up uses granular material subsampled from a full-scale filter, packed in a column, and operated with controlled...

  8. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    Energy Technology Data Exchange (ETDEWEB)

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The

  9. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    International Nuclear Information System (INIS)

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-01-01

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The

  10. Final PHP bench-scale report for the DOE-ID/SAIC sole source contract

    International Nuclear Information System (INIS)

    1997-04-01

    The Plasma Hearth Process (PHP) Technology Development Project was established to develop, test, and evaluate a new concept for treating mixed waste. The new concept uses direct current (dc) transferred-arc plasma torch technology to process mixed waste into a glass-like end-product. Under the cognizance of the US Department of Energy (DOE) Office of Technology Development (OTD) Mixed Waste Focus Area (MWFA), the technology is being explored for its potential to treat mixed waste. Because it is a mature technology, well-understood and commercially available, it is expected to develop rapidly in this new application. This report summarizes the radioactive bench-scale system activities funded under PHP Sole Source Contract DE-AC07-94ID13266 through the end of the contract

  11. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    Energy Technology Data Exchange (ETDEWEB)

    Suardini, P.J. [Custom Coals, International, Pittsburgh, PA (United States)

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  12. The hot bench scale plant Ester for the vitrification of high level wastes

    International Nuclear Information System (INIS)

    Nannicini, R.; Strazzer, A.; Cantale, C; Donato, A.; Grossi, G.

    1985-01-01

    In this paper the hot bench-scale plant ESTER for the vitrification of the high-level radioactive wastes is described, and the main results of the first radioactive campaign are reported. The ESTER plant, which is placed in the ADECO-ESSOR hot cells of the C.C.R.-EURATOM-ISPRA, has been built and is operated by the ENEA, Departement of Fuel Cycle. It began operating with real radioactive wastes about 1 year ago, solidifying a total of 12 Ci of fission products into 2,02 Kg of borosilicate glass, corresponding to 757 ml of glass. During the vitrification many samples of liquid and gaseous streams have been taken and analyzed. A radioactivity balance in the plant has been calculated, as well as a mass balance of nitrates and of the 137 Cs and 106 Ru volatized in the process

  13. A comparison of large-scale electron beam and bench-scale 60Co irradiations of simulated aqueous waste streams

    Science.gov (United States)

    Kurucz, Charles N.; Waite, Thomas D.; Otaño, Suzana E.; Cooper, William J.; Nickelsen, Michael G.

    2002-11-01

    The effectiveness of using high energy electron beam irradiation for the removal of toxic organic chemicals from water and wastewater has been demonstrated by commercial-scale experiments conducted at the Electron Beam Research Facility (EBRF) located in Miami, Florida and elsewhere. The EBRF treats various waste and water streams up to 450 l min -1 (120 gal min -1) with doses up to 8 kilogray (kGy). Many experiments have been conducted by injecting toxic organic compounds into various plant feed streams and measuring the concentrations of compound(s) before and after exposure to the electron beam at various doses. Extensive experimentation has also been performed by dissolving selected chemicals in 22,700 l (6000 gal) tank trucks of potable water to simulate contaminated groundwater, and pumping the resulting solutions through the electron beam. These large-scale experiments, although necessary to demonstrate the commercial viability of the process, require a great deal of time and effort. This paper compares the results of large-scale electron beam irradiations to those obtained from bench-scale irradiations using gamma rays generated by a 60Co source. Dose constants from exponential contaminant removal models are found to depend on the source of radiation and initial contaminant concentration. Possible reasons for observed differences such as a dose rate effect are discussed. Models for estimating electron beam dose constants from bench-scale gamma experiments are presented. Data used to compare the removal of organic compounds using gamma irradiation and electron beam irradiation are taken from the literature and a series of experiments designed to examine the effects of pH, the presence of turbidity, and initial concentration on the removal of various organic compounds (benzene, toluene, phenol, PCE, TCE and chloroform) from simulated groundwater.

  14. A comparison of large-scale electron beam and bench-scale 60Co irradiations of simulated aqueous waste streams

    International Nuclear Information System (INIS)

    Kurucz, Charles N.; Waite, Thomas D.; Otano, Suzana E.; Cooper, William J.; Nickelsen, Michael G.

    2002-01-01

    The effectiveness of using high energy electron beam irradiation for the removal of toxic organic chemicals from water and wastewater has been demonstrated by commercial-scale experiments conducted at the Electron Beam Research Facility (EBRF) located in Miami, Florida and elsewhere. The EBRF treats various waste and water streams up to 450 l min -1 (120 gal min -1 ) with doses up to 8 kilogray (kGy). Many experiments have been conducted by injecting toxic organic compounds into various plant feed streams and measuring the concentrations of compound(s) before and after exposure to the electron beam at various doses. Extensive experimentation has also been performed by dissolving selected chemicals in 22,700 l (6000 gal) tank trucks of potable water to simulate contaminated groundwater, and pumping the resulting solutions through the electron beam. These large-scale experiments, although necessary to demonstrate the commercial viability of the process, require a great deal of time and effort. This paper compares the results of large-scale electron beam irradiations to those obtained from bench-scale irradiations using gamma rays generated by a 60 Co source. Dose constants from exponential contaminant removal models are found to depend on the source of radiation and initial contaminant concentration. Possible reasons for observed differences such as a dose rate effect are discussed. Models for estimating electron beam dose constants from bench-scale gamma experiments are presented. Data used to compare the removal of organic compounds using gamma irradiation and electron beam irradiation are taken from the literature and a series of experiments designed to examine the effects of pH, the presence of turbidity, and initial concentration on the removal of various organic compounds (benzene, toluene, phenol, PCE, TCE and chloroform) from simulated groundwater

  15. Treatment of Synthetic Wastewater Containing AB14 Pigment by Electrooxidation in both Pilot and Bench Scale Reactors

    Directory of Open Access Journals (Sweden)

    Jalal Basiri parsa

    2016-01-01

    Full Text Available The electrochemical oxidation process was used for the degradation of Acid Brown 14 in both bench and pilot scale reactors. The bench scale one with a working volume of 0.5 L was equipped with platinum plate used as the anode and stainless steel (SS-304 plates as the cathode. The pilot scale reactor had a volume of 9 L and was equipped with SS-304 plates used as both the anode and the cathode. Experiments were run using these reactors to investigate the two parameters of energy consumption and anode efficiency. The bench scale reactor was capable of removing 92% and 36% of the dye and COD, respectively, after 18 min of operation. The pilot scale reactor, however, was capable of removing 87% and 59% of the dye and the COD content, respectively, after 60 min of operation. The kinetic study of both the bench and pilot reactors for dye and COD removals showed that both processes followed a zero order kinetic.

  16. Runoff and sediment generation on bench -terraced hillsides: measurements and up-scaling of a field-based model

    NARCIS (Netherlands)

    van Dijk, A.I.J.M.; Bruijnzeel, L.A.; Vertessy, R.A.; Ruijter, J.

    2006-01-01

    Despite widespread bench-terracing, stream sediment yields from agricultural hillsides in upland West Java remain high. We studied the causes of this lack of effect by combining measurements at different spatial scales using an erosion process model. Event runoff and sediment yield from two 4-ha

  17. Bench-scale demonstration of treatment technologies for contaminated sediments in Sydney Tar Ponds

    International Nuclear Information System (INIS)

    Volchek, K.; Velicogna, D.; Punt, M.; Wong, B.; Weimer, L.; Tsangaris, A.; Brown, C.E.

    2003-01-01

    A series of bench-scale tests were conducted to determine the capabilities of selected commercially available technologies for treating contaminated sediments from the South Pond of Sydney Tar Ponds. This study was conducted under the umbrella of a technology demonstration program aimed at evaluating technologies to be used in the remediation of such sediments. The following approach was proposed by SAIC Canada for the treatment of the sediments: (1) solvent extraction for the removal of organic contaminants, (2) acid/chelant leaching for the removal of inorganic contaminants such as heavy metals, and (3) plasma hearth process for the destruction of toxic streams resulting from the first two processes. Solvent extraction followed by plasma treatment proved effective for removing and destroying organic contaminants. The removal of metals did not achieve the expected results through leaching. An approach was proposed for treating those sediments based on the results of the study. The approach differed depending on the level of organic content. An assessment of associated process costs for both a pilot-scale field demonstration and a full-scale treatment was provided. 11 tabs., 4 figs

  18. Bench scale studies: Ozonation as a potential treatment for waters contaminated with hydrocarbons or dioxins and furans

    International Nuclear Information System (INIS)

    Schaal, W.

    1995-01-01

    The objective of the bench scale studies was to examine the destruction efficiency and efficacy of ozone on chemicals of concern (COC's) commonly found in contaminated ground water and rhenoformer wash water. The ground water used in these tests contained aromatic petroleum hydrocarbons, chlorinated hydrocarbons, and mineral spirits. The rhenoformer wash water used in these tests contained a variety of dioxins (including 2,3,7,8-tetrachlorodibenzo-p-dioxin) and furans. Summaries are presented of the bench scale studies by describing the COCs, methodologies, test reactors, observations, and results. The summaries also detail which applications hold promise with respect to ozonation and which ones do not. Bench test results for the experiments in which aromatic petroleum hydrocarbons, chlorinated hydrocarbons, and mineral spirits where the COCs were relatively successful. Concentrations for the COCs ranging from 300 to 3,400 micrograms per liter (microg/L) were brought below levels specified for storm sewer discharge per the National Priority Discharge Elimination Systems (NPDES) permit requirements. Bench test results for the experiments in which dioxins and furans were the COCs were less promising and revealed that additional processes would have to be used in conjunction with ozonation to bring the concentration of COCs within the targeted ranges. It was realized, however, that the effectiveness and efficacy of ozonation were diminished by the presence of particulates, to which some of the dioxin and furan compounds adhered

  19. Environmental data from laboratory- and bench-scale Pressurized Fluidized-Bed Hydroretorting of Eastern oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Mensinger, M.C.; Rue, D.M.; Roberts, M.J.

    1991-01-01

    As part of a 3-year program to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) Process for Eastern oil shales, IGT conducted tests in laboratory-scale batch and continuous units as well as a 45-kg/h bench-scale unit to generate a data base for 6 Eastern shales. Data were collected during PFH processing of raw Alabama and Indiana shales and a beneficiated Indiana shale for environmental mitigation analyses. The data generated include trace element analyses of the raw feeds and spent shales, product oils, and sour waters. The sulfur compounds present in the product gas and trace components in the sour water were also determined. In addition, the leaching characteristics of the feed and residue solids were determined. The data obtained were used to evaluate the environmental impact of a shale processing plant based on the PFH process. This paper presents the environmental data obtained from bench-scale tests conducted during the program.

  20. Environmental data from laboratory- and bench-scale Pressurized Fluidized-Bed Hydroretorting of Eastern oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Mensinger, M.C.; Rue, D.M.; Roberts, M.J.

    1991-12-31

    As part of a 3-year program to develop the Pressurized Fluidized-Bed Hydroretorting (PFH) Process for Eastern oil shales, IGT conducted tests in laboratory-scale batch and continuous units as well as a 45-kg/h bench-scale unit to generate a data base for 6 Eastern shales. Data were collected during PFH processing of raw Alabama and Indiana shales and a beneficiated Indiana shale for environmental mitigation analyses. The data generated include trace element analyses of the raw feeds and spent shales, product oils, and sour waters. The sulfur compounds present in the product gas and trace components in the sour water were also determined. In addition, the leaching characteristics of the feed and residue solids were determined. The data obtained were used to evaluate the environmental impact of a shale processing plant based on the PFH process. This paper presents the environmental data obtained from bench-scale tests conducted during the program.

  1. Treatment studies of plutonium-bearing INEEL waste surrogates in a bench-scale arc furnace

    International Nuclear Information System (INIS)

    Freeman, C.J.

    1997-05-01

    Since 1989, the Subsurface Disposal Area (SDA) at the Idaho National Environmental and Engineering Laboratory (INEEL) has been included on the National Priority List for remediation. Arc- and plasma-heated furnaces are being considered for converting the radioactive mixed waste buried in the SDA to a stabilized-vitreous form. Nonradioactive, surrogate SDA wastes have been melted during tests in these types of furnaces, but data are needed on the behavior of transuranic (TRU) constituents, primarily plutonium, during thermal treatment. To begin collecting this data, plutonium-spiked SDA surrogates were processed in a bench-scale arc furnace to quantify the fate of the plutonium and other hazardous and nonhazardous metals. Test conditions included elevating the organic, lead, chloride, and sodium contents of the surrogates. Blends having higher organic contents caused furnace power levels to fluctuate. An organic content corresponding to 50% INEEL soil in a soil-waste blend was the highest achievable before power fluctuations made operating conditions unacceptable. The glass, metal, and off-gas solids produced from each surrogate blend tested were analyzed for elemental (including plutonium) content and the partitioning of each element to the corresponding phase was calculated

  2. Safety analysis of the CSTR-1 bench-scale coal liquefaction unit

    Energy Technology Data Exchange (ETDEWEB)

    Hulburt, D.A.

    1981-05-01

    The objective of the program reported herein was to provide a Safety Analysis of the CSTR-1 bench scale unit located in Building 167 at the Pittsburgh Energy Technology Center. It was apparent that considerable effort was expended in the design and construction of the unit, and in the development of operating procedures, with regard to safety. Exhaust ventilation, H/sub 2/ and H/sub 2/S monitoring, overpressure protection, overtemperature protection, and interlock systems have been provided. Present settings on the pressure and temperature safety systems are too high, however, to insure prevention of vessel deformation or damage in all cases. While the occurrence of catastrophic rupture of a system pressure vessel (e.g., reactor, high pressure separators) is unlikely, the potential consequences to personnel are severe. Feasibility of providing shielding for these components should be considered. A more probable mode of vessel failure in the event of overpressure or overtemperature and failure of the safety system is yielding of the closure bolts followed by high pressure flow across the mating surfaces. As a minimum, shielding should be designed to restrict travel of resultant spray. The requirements for personal protective equipment are presently stated in rather broad and general terms in the operating procedures. Safe practices and procedures would be more assured if specific requirements were stated and included for each operational step. Recommendations were developed for all hazards triggered by the guidelines.

  3. Rapid pyrolysis of wheat straw in a Bench-Scale circulating Fluidized-Bed downer reactor

    Energy Technology Data Exchange (ETDEWEB)

    Ding, T. [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing (China); Graduate School of Chinese Academy of Sciences, Beijing (China); Li, S.; Xie, J.; Song, W.; Yao, J.; Lin, W. [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing (China)

    2012-12-15

    The effects of acid washing treatment on the pyrolysis product distribution and product properties were investigated in a bench-scale circulating fluidized-bed (CFB) downer reactor with wheat straw as feedstock. The acid treatment not only removes most of the inorganic species present in the biomass but also alters the distribution of the remaining organic constituents. It was found that the removal of the inorganic species increases the yield of liquid product and reduces char formation and gas yield. CO and CO{sub 2} are the dominant components in the gaseous product, accounting for over 90 %. The concentration of CO in the gaseous product increases after acid treatment, while the CO{sub 2} concentration decreases. The oxygen and water contents in the liquid product are decreased on acid treatment, leading to a relatively high heating value and viscosity. More volatiles can be found in the char derived from the acid-treated wheat straw than from the raw wheat straw. This may suggest that a longer residence time is needed for pyrolysis of the acid-treated wheat straw in order to obtain the maximal yield of volatile matter. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  4. Continuous thermal degradation of pyrolytic oil in a bench scale CSTR reaction system

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kyong Hwan; Nam, Ki Yun [Climate Change Technology Research Division, Korea Institute of Energy Research, 102 Gajeong-ro, Yuseong-gu, Daejeon 305-343 (Korea)

    2010-05-15

    Continuous thermal degradation of two pyrolytic oils with low (LPO) and high boiling point distribution (HPO) was conducted in a constant stirrer tank reactor (CSTR) with bench scale. Raw pyrolytic oil as a reactant was obtained from the commercial rotary kiln pyrolysis plant for municipal plastic waste. The degradation experiment was conducted by temperature programming with 10 C/min of heating rate up to 450 C and then maintained with long lapse time at 450 C. Liquid product was sampled at initial reaction time with different degradation temperatures up to 450 C and then constant interval lapse time at 450 C. The product characteristics over two pyrolytic oils were compared by using a continuous reaction system. As a reactant, heavy pyrolytic oil (HPO) showed higher boiling point distribution than that of diesel and also light pyrolytic oil (LPO) was mainly consisting of a mixture of gasoline and kerosene range components. In the continuous reaction, LPO showed higher yield of liquid product and lower residue than those of HPO. The characteristics of liquid products were influenced by the type of raw pyrolytic oil. Also, the result obtained under degradation temperature programming was described. (author)

  5. 100 Area soil washing: Bench scale tests on 116-F-4 pluto crib soil

    Energy Technology Data Exchange (ETDEWEB)

    Field, J.G.

    1994-06-10

    The Pacific Northwest Laboratory conducted a bench-scale treatability study on a pluto crib soil sample from 100 Area of the Hanford Site. The objective of this study was to evaluate the use of physical separation (wet sieving), treatment processes (attrition scrubbing, and autogenous surface grinding), and chemical extraction methods as a means of separating radioactively-contaminated soil fractions from uncontaminated soil fractions. The soil washing treatability study was conducted on a soil sample from the 116-F-4 Pluto Crib that had been dug up as part of an excavation treatability study. Trace element analyses of this soil showed no elevated concentrations above typically uncontaminated soil background levels. Data on the distribution of radionuclide in various size fractions indicated that the soil-washing tests should be focused on the gravel and sand fractions of the 116-F-4 soil. The radionuclide data also showed that {sup 137}Cs was the only contaminant in this soil that exceeded the test performance goal (TPG). Therefore, the effectiveness of subsequent soil-washing tests for 116-F-4 soil was evaluated on the basis of activity attenuation of {sup 137}Cs in the gravel- and sand-size fractions.

  6. 100 Area soil washing: Bench scale tests on 116-F-4 pluto crib soil

    International Nuclear Information System (INIS)

    Field, J.G.

    1994-01-01

    The Pacific Northwest Laboratory conducted a bench-scale treatability study on a pluto crib soil sample from 100 Area of the Hanford Site. The objective of this study was to evaluate the use of physical separation (wet sieving), treatment processes (attrition scrubbing, and autogenous surface grinding), and chemical extraction methods as a means of separating radioactively-contaminated soil fractions from uncontaminated soil fractions. The soil washing treatability study was conducted on a soil sample from the 116-F-4 Pluto Crib that had been dug up as part of an excavation treatability study. Trace element analyses of this soil showed no elevated concentrations above typically uncontaminated soil background levels. Data on the distribution of radionuclide in various size fractions indicated that the soil-washing tests should be focused on the gravel and sand fractions of the 116-F-4 soil. The radionuclide data also showed that 137 Cs was the only contaminant in this soil that exceeded the test performance goal (TPG). Therefore, the effectiveness of subsequent soil-washing tests for 116-F-4 soil was evaluated on the basis of activity attenuation of 137 Cs in the gravel- and sand-size fractions

  7. Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

    Energy Technology Data Exchange (ETDEWEB)

    Bauman, R.F.; Coless, L.A.; Davis, S.M. [and others

    1995-12-31

    In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

  8. Destruction of chemical agent simulants in a supercritical water oxidation bench-scale reactor

    Energy Technology Data Exchange (ETDEWEB)

    Veriansyah, Bambang [Supercritical Fluid Research Laboratory, Clean Technology Research Center, Korea Institute of Science and Technology (KIST), 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of) and Department of Green Process and System Engineering, University of Science and Technology, 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of)]. E-mail: vaveri@kist.re.kr; Kim, Jae-Duck [Supercritical Fluid Research Laboratory, Clean Technology Research Center, Korea Institute of Science and Technology (KIST), 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of) and Department of Green Process and System Engineering, University of Science and Technology, 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791 (Korea, Republic of)]. E-mail: jdkim@kist.re.kr; Lee, Jong-Chol [Agency for Defense Development (ADD), P.O. Box 35-1, Yuseong-gu, Daejeon (Korea, Republic of)]. E-mail: jcleeadd@hanafos.com

    2007-08-17

    A new design of supercritical water oxidation (SCWO) bench-scale reactor has been developed to handle high-risk wastes resulting from munitions demilitarization. The reactor consists of a concentric vertical double wall in which SCWO reaction takes place inside an inner tube (titanium grade 2, non-porous) whereas pressure resistance is ensured by a Hastelloy C-276 external vessel. The performances of this reactor were investigated with two different kinds of chemical warfare agent simulants: OPA (a mixture of isopropyl amine and isopropyl alcohol) as the binary precursor for nerve agent of sarin and thiodiglycol [TDG (HOC{sub 2}H{sub 4}){sub 2}S] as the model organic sulfur heteroatom. High destruction rates based on total organic carbon (TOC) were achieved (>99.99%) without production of chars or undesired gases such as carbon monoxide and methane. The carbon-containing product was carbon dioxide whereas the nitrogen-containing products were nitrogen and nitrous oxide. Sulfur was totally recovered in the aqueous effluent as sulfuric acid. No corrosion was noticed in the reactor after a cumulative operation time of more than 250 h. The titanium tube shielded successfully the pressure vessel from corrosion.

  9. Treatment studies of plutonium-bearing INEEL waste surrogates in a bench-scale arc furnace

    Energy Technology Data Exchange (ETDEWEB)

    Freeman, C.J.

    1997-05-01

    Since 1989, the Subsurface Disposal Area (SDA) at the Idaho National Environmental and Engineering Laboratory (INEEL) has been included on the National Priority List for remediation. Arc- and plasma-heated furnaces are being considered for converting the radioactive mixed waste buried in the SDA to a stabilized-vitreous form. Nonradioactive, surrogate SDA wastes have been melted during tests in these types of furnaces, but data are needed on the behavior of transuranic (TRU) constituents, primarily plutonium, during thermal treatment. To begin collecting this data, plutonium-spiked SDA surrogates were processed in a bench-scale arc furnace to quantify the fate of the plutonium and other hazardous and nonhazardous metals. Test conditions included elevating the organic, lead, chloride, and sodium contents of the surrogates. Blends having higher organic contents caused furnace power levels to fluctuate. An organic content corresponding to 50% INEEL soil in a soil-waste blend was the highest achievable before power fluctuations made operating conditions unacceptable. The glass, metal, and off-gas solids produced from each surrogate blend tested were analyzed for elemental (including plutonium) content and the partitioning of each element to the corresponding phase was calculated.

  10. Experience gained in bench scale and pilot scale fluidised bed processing

    CSIR Research Space (South Africa)

    Hadley, TD

    2005-01-01

    Full Text Available of titanium dioxide. Expertise in the design and commissioning of industrial-scale plants has led to the supply (through licensees) of a biomass sludge incinerator/boiler generating 26t/h steam, a 20 MW high-sulphur pitch incinerator and a 12 MW fluidised bed...

  11. Cyanobacteria, Toxins and Indicators: Full-Scale Monitoring & Bench-Scale Treatment Studies

    Science.gov (United States)

    Summary of: 1) Lake Erie 2014 bloom season full-scale treatment plant monitoring data for cyanobacteria and cyanobacteria toxins; 2) Follow-up work to examine the impact of pre-oxidation on suspensions of intact toxin-producing cyanobacterial cells.

  12. Results of bench-scale plasma system testing in support of the Plasma Hearth Process

    International Nuclear Information System (INIS)

    Leatherman, G.L.; Cornelison, C.; Frank, S.

    1996-01-01

    The Plasma Hearth Process (PHP) is a high-temperature process that destroys hazardous organic components and stabilizes the radioactive components and hazardous metals in a leach-resistant vitreous slag waste form. The PHP technology development program is targeted at mixed waste that cannot be easily treated by conventional means. For example, heterogeneous debris, which may contain hazardous organics, toxic metals, and radionuclides, is difficult to characterize and cannot be treated with conventional thermal, chemical, or physical treatment methods. A major advantage of the PHP over other plasma processes is its ability to separate nonradioactive, non-hazardous metals from the non-metallic and radioactive components which are contained in the vitreous slag. The overall PHP program involves the design, fabrication, and operation of test hardware to demonstrate and certify that the PHP concept is viable for DOE waste treatment. The program involves bench-scale testing of PHP equipment in radioactive service, as well as pilot-scale demonstration of the PHP concept using nonradioactive, surrogate test materials. The fate of secondary waste streams is an important consideration for any technology considered for processing mixed waste. The main secondary waste stream generated by the PHP is flyash captured by the fabric- filter baghouse. The PHP concept is that flyash generated by the process can, to a large extent, be treated by processing this secondary waste stream in the PHP. Prior to the work presented in the paper, however, the PHP project has not quantitatively demonstrated the ability to treat PHP generated flyash. A major consideration is the quantity of radionuclides and RCRA-regulated metals in the flyash that can be retained the resultant waste form

  13. Bench-scale enhanced sludge washing and gravity settling of Hanford Tank C-106 Sludge

    International Nuclear Information System (INIS)

    Brooks, K.P.; Myers, R.L.; Rappe, K.G.

    1997-01-01

    This report summarizes the results of a bench-scale sludge pretreatment demonstration of the Hanford baseline flowsheet using liter-quantities of sludge from Hanford Site single-shell tank 241-C-106 (tank C-106). The leached and washed sludge from these tests provided Envelope D material for the contractors supporting Tank Waste Remediation System (TWRS) Privatization. Pretreatment of the sludge included enhanced sludge washing and gravity settling tests and providing scale-up data for both these unit operations. Initial and final solids as well as decanted supernatants from each step of the process were analyzed chemically and radiochemically. The results of this work were compared to those of Lumetta et al. (1996a) who performed a similar experiment with 15 grams of C-106, sludge. A summary of the results are shown in Table S.1. Of the major nonradioactive components, those that were significantly removed with enhanced sludge washing included aluminum (31%), chromium (49%), sodium (57%), and phosphorus (35%). Of the radioactive components, a significant amount of 137 Cs (49%) were removed during the enhanced sludge wash. Only a very small fraction of the remaining radionuclides were removed, including 90 Sr (0.4%) and TRU elements (1.5%). These results are consistent with those of the screening test. All of the supernatants (both individually and as a blend) removed from these washing steps, once vitrified as LLW glasses (at 20 wt% Na 2 O), would be less than NRC Class C in TRU elements and less than NRC Class B in 90 Sr

  14. Catalytic multi-stage liquefaction of coal at HTI: Bench-scale studies in coal/waste plastics coprocessing

    Energy Technology Data Exchange (ETDEWEB)

    Pradhan, V.R.; Lee, L.K.; Stalzer, R.H. [Hydrocarbon Technologies, Inc., Lawrenceville, NJ (United States)] [and others

    1995-12-31

    The development of Catalytic Multi-Stage Liquefaction (CMSL) at HTI has focused on both bituminous and sub-bituminous coals using laboratory, bench and PDU scale operations. The crude oil equivalent cost of liquid fuels from coal has been curtailed to about $30 per barrel, thus achieving over 30% reduction in the price that was evaluated for the liquefaction technologies demonstrated in the late seventies and early eighties. Contrary to the common belief, the new generation of catalytic multistage coal liquefaction process is environmentally very benign and can produce clean, premium distillates with a very low (<10ppm) heteroatoms content. The HTI Staff has been involved over the years in process development and has made significant improvements in the CMSL processing of coals. A 24 month program (extended to September 30, 1995) to study novel concepts, using a continuous bench scale Catalytic Multi-Stage unit (30kg coal/day), has been initiated since December, 1992. This program consists of ten bench-scale operations supported by Laboratory Studies, Modelling, Process Simulation and Economic Assessments. The Catalytic Multi-Stage Liquefaction is a continuation of the second generation yields using a low/high temperature approach. This paper covers work performed between October 1994- August 1995, especially results obtained from the microautoclave support activities and the bench-scale operations for runs CMSL-08 and CMSL-09, during which, coal and the plastic components for municipal solid wastes (MSW) such as high density polyethylene (HDPE)m, polypropylene (PP), polystyrene (PS), and polythylene terphthlate (PET) were coprocessed.

  15. Performance study of protective clothing against hot water splashes: from bench scale test to instrumented manikin test.

    Science.gov (United States)

    Lu, Yehu; Song, Guowen; Wang, Faming

    2015-03-01

    Hot liquid hazards existing in work environments are shown to be a considerable risk for industrial workers. In this study, the predicted protection from fabric was assessed by a modified hot liquid splash tester. In these tests, conditions with and without an air spacer were applied. The protective performance of a garment exposed to hot water spray was investigated by a spray manikin evaluation system. Three-dimensional body scanning technique was used to characterize the air gap size between the protective clothing and the manikin skin. The relationship between bench scale test and manikin test was discussed and the regression model was established to predict the overall percentage of skin burn while wearing protective clothing. The results demonstrated strong correlations between bench scale test and manikin test. Based on these studies, the overall performance of protective clothing against hot water spray can be estimated on the basis of the results of the bench scale hot water splashes test and the information of air gap size entrapped in clothing. The findings provide effective guides for the design and material selection while developing high performance protective clothing. Published by Oxford University Press on behalf of the British Occupational Hygiene Society 2014.

  16. Bench-scale studies of reactor-based treatment of fuel-contaminated soils

    International Nuclear Information System (INIS)

    Truax, D.D.; Britto, R.; Sherrard, J.H.

    1995-01-01

    Biological treatment of hazardous wastes from accidental spills or underground storage tank leaks has generated interest in bioremediation as a natural, economical mechanism for site decontamination. Because of drawbacks of batch systems, and the successful use of continuous flow treatment of wastewater for several decades, it was felt that continuous treatment of such soils would be a feasible alternative treatment technique. Therefore, bench-scale bioreactor treatability studies were conducted and used contaminated soil made in the laboratory using No. 2 diesel fuel and sand. Contamination levels studied were from 1,335--6,675 mg (TPH) as derived from No. 2 fuel oil per kg sand. Variation in mean cell age was obtained between reactors, with sufficient nutrients and oxygen made available to ensure the fuel oil organics were the only limit to microbial growth. A theoretical biokinetic model was formulated based on Monod's theory of limiting substrate and continuous cultures. Biokinetic constants and removal efficiencies were evaluated. The off-gases, CO 2 , and volatile hydrocarbons were monitored for mass balance analysis of the process. The solids retention times for evaluating final TPH concentration of 100 mg/kg were also calculated. Removal efficiencies of up to 91% were attained at a loading of 1,335 mg TPH/kg wet sand, operated at a biological solid retention time (BSRT) of 60 days. Experiments also showed that TPH desorption and volatilization were not rate-limiting in the overall removal process. Sand-to-moisture ratios in excess of 3:1 were also shown to retard TPH removal rates very little. However, biokinetic constants were found to vary over a range of values. This was particularly true at varying diesel loading levels. Nevertheless, significant removal efficiency (up to 86%) was noted at the highest loading level tested, 6,675 mg TPH/kg wet sand

  17. Bench-scale arc melter for R ampersand D in thermal treatment of mixed wastes

    International Nuclear Information System (INIS)

    Kong, P.C.; Grandy, J.D.; Watkins, A.D.; Eddy, T.L.; Anderson, G.L.

    1993-05-01

    A small dc arc melter was designed and constructed to run bench-scale investigations on various aspects of development for high-temperature (1,500-1,800 degrees C) processing of simulated transuranic-contaminated waste and soil located at the Radioactive Waste Management Complex (RWMC). Several recent system design and treatment studies have shown that high-temperature melting is the preferred treatment. The small arc melter is needed to establish techniques and procedures (with surrogates) prior to using a similar melter with the transuranic-contaminated wastes in appropriate facilities at the site. This report documents the design and construction, starting and heating procedures, and tests evaluating the melter's ability to process several waste types stored at the RWMC. It is found that a thin graphite strip provides reliable starting with initial high current capability for partially melting the soil/waste mixture. The heating procedure includes (1) the initial high current-low voltage mode, (2) a low current-high voltage mode that commences after some slag has formed and arcing dominates over the receding graphite conduction path, and (3) a predominantly Joule heating mode during which the current can be increased within the limits to maintain relatively quiescent operation. Several experiments involving the melting of simulated wastes are discussed. Energy balance, slag temperature, and electrode wear measurements are presented. Recommendations for further refinements to enhance its processing capabilities are identified. Future studies anticipated with the arc melter include waste form processing development; dissolution, retention, volatilization, and collection for transuranic and low-level radionuclides, as well as high vapor pressure metals; electrode material development to minimize corrosion and erosion; refractory corrosion and/or skull formation effects; crucible or melter geometry; metal oxidation; and melt reduction/oxidation (redox) conditions

  18. Bioleaching of heavy metals from soil using fungal-organic acids : bench scale testing

    Energy Technology Data Exchange (ETDEWEB)

    Cathum, S.J.; Ousmanova, D.; Somers, A.; Punt, M. [SAIC Canada, Ottawa, ON (Canada); Brown, C.E. [Environment Canada, Ottawa, ON (Canada). Emergencies Engineering Division]|[Environment Canada, Ottawa, ON (Canada). Environmental Technology Centre

    2006-07-01

    The ability of fungi to solubilize metals from solid materials may present new opportunities in environmental remediation. This paper presented details of a bench scale experiment that evaluated the leaching of heavy metals from contaminated soil using in situ fungal-generated organic acids. Rice was used as the growing media for organic acid production by A. foetidus. The cultivated fungus was placed on large pieces of potato-dextrose agar (PDA) plates and suspended in 5 L of sterilized water. The cooked rice was inoculated by pouring the 5 L spore suspension over the rice layer. Soil was obtained from a soil pile impacted with heavy metals at a private industrial site and augmented with Pb-contaminated soil. A polyethylene tub was used with a drain pipe leading to a leachate vessel. Crushed stone was spread over the bottom of the tub to assist leachate drainage. Approximately 45 kg of the contaminated soil was spread evenly over the stone layer to a depth of 10 cm. The concentrated spore suspension was sprinkled over the rice. Each week the leachate collection vessel was removed from the bioleaching system and the fine soil particles were allowed to settle. A control was run using the contaminated soil and solid substrate without fungus. Growth of A. foetidus was observed in both control experiment and test experiment after a period of 35 days. The pH of the leachate was measured as the fungal growth progressed. The process was assessed using ICP Mass Spectroscopy and electron spectroscopy, which showed that approximately 65 g of heavy metals were mobilized from 45 kg of soil, and that the biological leaching process resulted in greater mobilization of heavy metals relative to the control experiment. It was concluded that organic acids generated by A. foetidus were capable of leaching heavy metals from the soil. 30 refs., 4 tabs., 15 figs.

  19. Bench-scale experimental determination of the thermal diffusivity of crushed tuff

    International Nuclear Information System (INIS)

    Ryder, E.E.; Finley, R.E.; George, J.T.; Ho, C.K.; Longenbaugh, R.S.; Connolly, J.R.

    1996-06-01

    A bench-scale experiment was designed and constructed to determine the effective thermal diffusivity of crushed tuff. Crushed tuff particles ranging from 12.5 mm to 37.5 mm (0.5 in. to 1.5 in.) were used to fill a cylindrical volume of 1.58 m 3 at an effective porosity of 0.48. Two iterations of the experiment were completed; the first spanning approximately 502 hours and the second 237 hours. Temperatures near the axial heater reached 700 degrees C, with a significant volume of the test bed exceeding 100 degrees C. Three post-test analysis techniques were used to estimate the thermal diffusivity of the crushed tuff. The first approach used nonlinear parameter estimation linked to a one dimensional radial conduction model to estimate thermal diffusivity from the first 6 hours of test data. The second method used the multiphase TOUGH2 code in conjunction with the first 20 hours of test data not only to estimate the crushed tuffs thermal diffusivity, but also to explore convective behavior within the test bed. Finally, the nonlinear conduction code COYOTE-II was used to determine thermal properties based on 111 hours of cool-down data. The post-test thermal diffusivity estimates of 5.0 x 10-7 m 2 /s to 6.6 x 10-7 m 2 /s were converted to effective thermal conductivities and compared to estimates obtained from published porosity-based relationships. No obvious match between the experimental data and published relationships was found to exist; however, additional data for other particle sizes and porosities are needed

  20. Bench-Scale Silicone Process for Low-Cost CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Fresia, Megan; Vogt, Kirk

    2013-12-31

    GE Global Research is developing technology to remove carbon dioxide (CO{sub 2}) from the flue gas of coal-fired power plants. A mixture of 3-aminopropyl end-capped polydimethylsiloxane (GAP-1m) and triethylene glycol (TEG) is the preferred CO{sub 2} capture solvent. GE Global Research was contracted by the Department of Energy to test a bench-scale continuous CO{sub 2} absorption/desorption system using a GAP-1m/TEG mixture as the solvent. SiVance LLC was sub-contracted to provide the GAP-1m material and conduct an Environmental, Health, and Safety (EH&S) assessment for a 550 MW coal-fired power plant. Five components of the solvent, CAS#2469-55-8 (GAP-0), CAS#106214-84-0 (GAP-1-4), TEG, and methanol and xylene (minor contaminants from the aminosilicone) are included in this assessment. One by-product, GAP-1m/SOX salt, and dodecylbenzenesulfonic acid (DDBSA) were also identified for analysis. All of the solvent components and DDBSA are listed on the EPA’s TSCA Inventory allowing companies to manufacture and use the chemicals commercially. The toxicological effects of each component were defined, and control mechanisms necessary to comply with U.S. EH&S regulations are summarized. An engineering and control system, including environmental abatement, was described for minimizing exposure and release of the chemical components. Proper handling and storage recommendations are made for each chemical to minimize risk to workers and the surrounding community.

  1. Bench-scale arc melter for R&D in thermal treatment of mixed wastes

    Energy Technology Data Exchange (ETDEWEB)

    Kong, P.C.; Grandy, J.D.; Watkins, A.D.; Eddy, T.L.; Anderson, G.L.

    1993-05-01

    A small dc arc melter was designed and constructed to run bench-scale investigations on various aspects of development for high-temperature (1,500-1,800{degrees}C) processing of simulated transuranic-contaminated waste and soil located at the Radioactive Waste Management Complex (RWMC). Several recent system design and treatment studies have shown that high-temperature melting is the preferred treatment. The small arc melter is needed to establish techniques and procedures (with surrogates) prior to using a similar melter with the transuranic-contaminated wastes in appropriate facilities at the site. This report documents the design and construction, starting and heating procedures, and tests evaluating the melter`s ability to process several waste types stored at the RWMC. It is found that a thin graphite strip provides reliable starting with initial high current capability for partially melting the soil/waste mixture. The heating procedure includes (1) the initial high current-low voltage mode, (2) a low current-high voltage mode that commences after some slag has formed and arcing dominates over the receding graphite conduction path, and (3) a predominantly Joule heating mode during which the current can be increased within the limits to maintain relatively quiescent operation. Several experiments involving the melting of simulated wastes are discussed. Energy balance, slag temperature, and electrode wear measurements are presented. Recommendations for further refinements to enhance its processing capabilities are identified. Future studies anticipated with the arc melter include waste form processing development; dissolution, retention, volatilization, and collection for transuranic and low-level radionuclides, as well as high vapor pressure metals; electrode material development to minimize corrosion and erosion; refractory corrosion and/or skull formation effects; crucible or melter geometry; metal oxidation; and melt reduction/oxidation (redox) conditions.

  2. Reuse of Hydrotreating Spent Catalyst

    International Nuclear Information System (INIS)

    Habib, A.M.; Menoufy, M.F.; Amhed, S.H.

    2004-01-01

    All hydro treating catalysts used in petroleum refining processes gradually lose activity through coking, poisoning by metal, sulfur or halides or lose surface area from sintering at high process temperatures. Waste hydrotreating catalyst, which have been used in re-refining of waste lube oil at Alexandria Petroleum Company (after 5 years lifetime) compared with the same fresh catalyst were used in the present work. Studies are conducted on partial extraction of the active metals of spent catalyst (Mo and Ni) using three leaching solvents,4% oxidized oxalic acid, 10% aqueous sodium hydroxide and 10% citric acid. The leaching experiments are conducting on the de coked extrude [un crushed] spent catalyst samples. These steps are carried out in order to rejuvenate the spent catalyst to be reused in other reactions. The results indicated that 4% oxidized oxalic acid leaching solution gave total metal removal 45.6 for de coked catalyst samples while NaOH gave 35% and citric acid gave 31.9 % The oxidized leaching agent was the most efficient leaching solvent to facilitate the metal removal, and the rejuvenated catalyst was characterized by the unchanged crystalline phase The rejuvenated catalyst was applied for hydrodesulfurization (HDS) of vacuum gas oil as a feedstock, under different hydrogen pressure 20-80 bar in order to compare its HDS activity

  3. Bench Scale Thin Film Composite Hollow Fiber Membranes for Post-Combustion Carbon Dioxide Capture

    Energy Technology Data Exchange (ETDEWEB)

    Glaser, Paul [General Electric Global Research, Niskayuna, NY (United States); Bhandari, Dhaval [General Electric Global Research, Niskayuna, NY (United States); Narang, Kristi [General Electric Global Research, Niskayuna, NY (United States); McCloskey, Pat [General Electric Global Research, Niskayuna, NY (United States); Singh, Surinder [General Electric Global Research, Niskayuna, NY (United States); Ananthasayanam, Balajee [General Electric Global Research, Niskayuna, NY (United States); Howson, Paul [General Electric Global Research, Niskayuna, NY (United States); Lee, Julia [General Electric Global Research, Niskayuna, NY (United States); Wroczynski, Ron [General Electric Global Research, Niskayuna, NY (United States); Stewart, Frederick [Idaho National Lab. (INL), Idaho Falls, ID (United States); Orme, Christopher [Idaho National Lab. (INL), Idaho Falls, ID (United States); Klaehn, John [Idaho National Lab. (INL), Idaho Falls, ID (United States); McNally, Joshua [Idaho National Lab. (INL), Idaho Falls, ID (United States); Rownaghi, Ali [Georgia Inst. of Technology, Atlanta, GA (United States); Lu, Liu [Georgia Inst. of Technology, Atlanta, GA (United States); Koros, William [Georgia Inst. of Technology, Atlanta, GA (United States); Goizueta, Roberto [Georgia Inst. of Technology, Atlanta, GA (United States); Sethi, Vijay [Western Research Inst., Laramie, WY (United States)

    2015-04-01

    GE Global Research, Idaho National Laboratory (INL), Georgia Institute of Technology (Georgia Tech), and Western Research Institute (WRI) proposed to develop high performance thin film polymer composite hollow fiber membranes and advanced processes for economical post-combustion carbon dioxide (CO2) capture from pulverized coal flue gas at temperatures typical of existing flue gas cleanup processes. The project sought to develop and then optimize new gas separations membrane systems at the bench scale, including tuning the properties of a novel polyphosphazene polymer in a coating solution and fabricating highly engineered porous hollow fiber supports. The project also sought to define the processes needed to coat the fiber support to manufacture composite hollow fiber membranes with high performance, ultra-thin separation layers. Physical, chemical, and mechanical stability of the materials (individual and composite) towards coal flue gas components was considered via exposure and performance tests. Preliminary design, technoeconomic, and economic feasibility analyses were conducted to evaluate the overall performance and impact of the process on the cost of electricity (COE) for a coal-fired plant including capture technologies. At the onset of the project, Membranes based on coupling a novel selective material polyphosphazene with an engineered hollow fiber support was found to have the potential to capture greater than 90% of the CO2 in flue gas with less than 35% increase in COE, which would achieve the DOE-targeted performance criteria. While lab-scale results for the polyphosphazene materials were very promising, and the material was incorporated into hollow-fiber modules, difficulties were encountered relating to the performance of these membrane systems over time. Performance, as measured by both flux of and selectivity for CO2 over other flue gas constituents was found to deteriorate over time, suggesting a system that was

  4. Loading Intensity Prediction by Velocity and the OMNI-RES 0-10 Scale in Bench Press.

    Science.gov (United States)

    Naclerio, Fernando; Larumbe-Zabala, Eneko

    2017-02-01

    Naclerio, F and Larumbe-Zabala, E. Loading intensity prediction by velocity and the OMNI-RES 0-10 scale in bench press. J Strength Cond Res 32(1): 323-329, 2017-This study examined the possibility of using movement velocity and the perceived exertion as indicators of relative load in the bench press (BP) exercise. A total of 308 young, healthy, resistance trained athletes (242 men and 66 women) performed a progressive strength test up to the one repetition maximum for the individual determination of the full load-velocity and load-exertion relationships. Longitudinal regression models were used to predict the relative load from the average velocity (AV) and the OMNI-Resistance Exercise Scales (OMNI-RES 0-10 scale), considering sets as the time-related variable. Load associated with the AV and the OMNI-RES 0-10 scale value expressed after performing a set of 1-3 repetitions were used to construct 2 adjusted predictive equations: Relative load = 107.75 - 62.97 × average velocity; and Relative load = 29.03 + 7.26 × OMNI-RES 0-10 scale value. The 2 models were capable of estimating the relative load with an accuracy of 84 and 93%, respectively. These findings confirm the ability of the 2 calculated regression models, using load-velocity and load-exertion from the OMNI-RES 0-10 scale, to accurately predict strength performance in BP.

  5. Bench-scale production of liquid fuel from woody biomass via gasification

    Energy Technology Data Exchange (ETDEWEB)

    Hanaoka, Toshiaki; Liu, Yanyong; Matsunaga, Kotetsu; Miyazawa, Tomohisa; Hirata, Satoshi; Sakanishi, Kinya [Biomass Technology Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Suehiro 2-2-2, Hiro, Kure, Hiroshima 737-0197 (Japan)

    2010-08-15

    The bench-scale production of hydrocarbon liquid fuel was achieved from woody biomass via gasification. The daily production capacity of the biomass-to-liquid (BTL) plant used in this study was 7.8 L of hydrocarbon liquid from 48 kg of woody biomass (on a dry basis), corresponding to 0.05 barrels. The BTL process involved the following steps: oxygen-enriched air gasification of the woody biomass, wet and dry gas cleaning, gas compression, carbon dioxide removal, and the Fischer-Tropsch (FT) synthesis reaction. In the gasification step, oxygen-enriched air gasification was carried out using a downdraft fixed-bed gasifier. The content of oxygen, which acts as the gasifying agent, was increased from 21.0 to 56.7 vol%; maximum values of the conversion to gas on a carbon basis and cold gas efficiency-approximately 96 C-mol% and 87.8%, respectively-were obtained at an oxygen content of around 30 vol%. With the increased oxygen content, the concentrations of CO, H{sub 2}, and CO{sub 2} increased from 22.8 to 36.5 vol%, from 16.8 to 28.1 vol%, and from 9.8 to 14.8 vol%, respectively, while that of N{sub 2} decreased from 48.8 to 16.0 vol%. The feed gas for the FT synthesis reaction was obtained by passing the product gas from the gasification step through a scrubber, carbon dioxide removal tower, and desulfurization tower; its composition was 30.8 vol% CO, 25.2 vol% H{sub 2}, 0.9 vol% CO{sub 2}, 2.5 vol% CH{sub 4}, 40.6 vol% N{sub 2}, < 5 ppb H{sub 2}S, and < 5 ppb COS. The hydrocarbon fuel was synthesized in a slurry bed reactor using hexadecane as the solvent and a Co/SiO{sub 2} catalyst. For hydrocarbons with carbon chain lengths of more than 5 carbon atoms (collectively referred to as C{sub 5+}) in the liquid fuel, a selectivity of 87.5% was obtained along with a chain growth probability of 0.84 under the following conditions: 4 MPa, 280 to 340 C, and a ratio of catalyst weight to feed gas rate (W/F) of 9.3 g.h/mol. (author)

  6. A long-term bench-scale investigation of permanganate consumption by aquifer materials.

    Science.gov (United States)

    Xu, Xiuyuan; Thomson, Neil R

    2009-11-20

    In situ chemical oxidation (ISCO) applications using permanganate involve the injection or release of permanganate into the subsurface to destroy various target contaminants. Naturally occurring reduced components associated with aquifer materials can exert a significant oxidant demand thereby reducing the amount of permanganate available for the destruction of contaminants as well as reducing the overall rate of oxidation. Quantification of this natural oxidant demand (NOD) is a requirement for site-specific assessment and the design of cost-effective oxidant delivery systems. To further our understanding of the interaction between permanganate and aquifer materials, aerobic and anaerobic aquifer materials from eight representative sites throughout North America were tested in a series of systematic bench-scale experiments. Various permanganate to aquifer solids mass loading ratios at different initial permanganate concentrations in well-mixed batch reactors were monitored for >300 days. All NOD temporal profiles demonstrated an initial fast consumption rate followed by a persistent slower consumption rate. The data generated show that the mass loading ratio, the initial permanganate concentration, and the nature and quantity of reduced aquifer material species are the main factors controlling permanganate consumption rates. A higher initial permanganate concentration or a larger mass loading ratio produced a larger fast NOD consumption rate and generated a corresponding higher maximum NOD value. Hence, both the NOD temporal profile and the maximum NOD are not single-valued but are heavily dependent on the experimental conditions. Predictive relationships were developed to estimate the maximum NOD and the NOD at 7 days based on aquifer material properties. The concentration of manganese oxides deposited on the aquifer solids was highly correlated with the mass of permanganate consumed suggesting that passivation of NOD reaction sites occurred due to the formation

  7. Soluble Microbial Product Characterization of Biofilm Formation in Bench-Scale

    KAUST Repository

    Mines, Paul

    2012-12-01

    The biological process known as activated sludge (AS) in conjunction with membrane separation technology for the treatment of wastewater has been employed for over four decades. While, membrane biological reactors (MBR) are now widely employed, the phenomenon of membrane fouling is still the most significant factor leading to performance decline of MBRs. Although much research has been done on the subject of MBR fouling over the past two decades, many questions remain unanswered, and consensus within the scientific community is rare. However, research has led to one system parameter generally being regarded as a contributor to membrane fouling, extracellular polymeric compounds (EPS). EPS, and more specifically, the soluble fraction of EPS known as soluble microbial products (SMP), must be further investigated in order to better understand membrane fouling. The biological activity and performance of the MBR is affected by myriad operational parameters, which in turn affects the SMP generated. A commonly varied operational parameter is, depending on the specific treatment needs of a MBR, the sludge retention time (SRT). This study aims to characterize the SMP in three bench-scale MBRs as the SRT is gradually lowered. By studying how the SMP change as the operation of the system is altered, greater understanding of how SMP are related to fouling can be achieved. At the onset of the study, a steady state was established in the system with a SRT of 20 days. Upon stabilization of a 20 day SRT, the system was gradually transitioned to a five and a half day SRT, in stepwise adjustments. Initially, both the trans-membrane pressure (TMP) and the SMP concentrations were at relatively low values, indicating the presence of minimal amounts of biofilm on the membrane surfaces. As the system was altered and more activated sludge was wasted from the reactors, the SRT inherently decreased. As the lower SRT was transitioned and established, the data from TMP measurements, as well

  8. EFRT M12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    Energy Technology Data Exchange (ETDEWEB)

    Rapko, Brian M.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2009-08-14

    20 wt% solids using cross-flow ultrafiltration before the addition of caustic. For wastes that have significantly high chromium content, the caustic leaching and slurry dewatering is followed by adding sodium permanganate to UFP-VSL-T02A, and the slurry is subjected to oxidative leaching at nominally ambient temperature. The purpose of the oxidative leaching is to selectively oxidize the poorly alkaline-soluble Cr(III) believed to be the insoluble form in Hanford tank sludge to the much more alkaline-soluble Cr(VI), e.g., chromate. The work described in this report provides the test results that are related to the efficiency of the oxidative leaching process to support process modeling based on tests performed with a Hanford waste simulant. The tests were completed both at the lab-bench scale and in the PEP. The purpose of this report is to summarize the results from both scales that are related to oxidative leaching chemistry to support a scale factor for the submodels to be used in the G2 model, which predicts WTP operating performance. Owing to schedule constraints, the PEP test data to be included in this report are limited to those from Integrated Tests A (T01 A/B caustic leaching) and B (T02A caustic leaching).

  9. Application of magnetic resonance imaging (MRI) to determine the influence of fluid dynamics on desulfurization in Bench scale reactors

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, N.L.; Reimert, R. [Engler-Bunte-Institut, Bereich Gas, Erdoel und Kohle, Universitaet Karlsruhe (T.H.) (Germany); Hardy, E.H. [Institut fuer Mechanische Verfahrenstechnik und Mechanik, Universitaet Karlsruhe (T.H.) (Germany)

    2006-07-15

    The influence of fluid dynamics on the hydrodesulfurization (HDS) reactions of a diesel oil in bench-scale reactors was evaluated. The porosities and liquid saturations of catalyst beds were quantified by using the MRI technique. The gas-liquid systems used in the experiments were nitrogen diesel and hydrogen diesel. An apparatus was especially constructed, allowing in situ measurements of gas and liquid distributions in packed beds at elevated pressure and temperature up to 20 bar and 200 C, respectively. The reactor itself had a length of 500 mm and an internal diameter of 19 mm. The packed beds used in this MRI study consisted of: (1) 2 mm diameter nonporous spherical glass beads and (2) 1.3 mm diameter porous Al{sub 2}O{sub 3} trilobes having the same size as the original trilobe catalyst used in HDS bench-scale experiments. The superficial gas and liquid velocities were set within the range of trickle flow, e.g., u{sub 0G} = 20-500 mm/s and u{sub 0L} = 0.1-6 mm/s. In parallel with the MRI experiments, the hydrodesulfurization of a gas oil was investigated in a bench-scale plant. Its reactor had the same dimensions of the trickle-bed column used in the MRI experiments and was filled with original trilobe catalyst. These catalytic experiments were carried out at a wide range of operating conditions (p = 30-80 bar, T = 300-380 C, LHSV = 1-4 h{sup -1}). The results of both fluid dynamic and catalytic reaction experiments were then combined for developing a simulation model to predict the HDS performance by accounting for fluid dynamic nonidealities. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  10. Characterization of Hydrotreated Fast Pyrolysis Liquids

    NARCIS (Netherlands)

    Oasmaa, A.; Kuoppala, E.; Ardiyanti, A.; Venderbosch, R. H.; Heeres, H. J.

    This paper focuses on analytical methods to determine the composition of hydrotreated fast pyrolysis liquids. With this information, it is possible to gain insights in the chemical transformations taking place during catalytic hydrotreatment (hydrogenation and/or hydrodeoxygenation, H DO) of

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  12. Treatment of waste gas containing low concentration of dimethyl sulphide (DMS) in a bench-scale biofilter.

    Science.gov (United States)

    Giri, B S; Mudliar, S N; Deshmukh, S C; Banerjee, S; Pandey, R A

    2010-04-01

    Biological treatment of dimethyl sulphide (DMS) was investigated in a bench-scale biofilter, packed with compost along with wood chips, and enriched with DMS degrading microorganism Bacillus sphaericus. The biofilter could remove 62-74% of the inlet DMS, at an optimum loading of 0.484 g/m(3)/h with optimum empty bed contact time (EBCT) of 384 s and an average moisture range of 65-70%. The biodegradative products of DMS were sulphide, thiosulphate and sulphate. Evaluation of microbiological status of the biofilter indicated the presence of other bacterial cultures viz. Paenibacillus polymyxa, and Bacillus megaterium, besides B. sphaericus. Copyright 2009 Elsevier Ltd. All rights reserved.

  13. Thermochemical water-splitting cycle, bench-scale investigations and process engineering. Annual report, October 1, 1978-September 30, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Caprioglio, G.; McCorkle, K.H.; Besenbruch, G.E.; Rode, J.S.

    1980-03-01

    A program to investigate thermochemical water splitting has been under way at General Atomic Company (GA) since October 1972. This document is an annual progress report of Department of Energy (DOE) sponsored process development work on the GA sulfur-iodine thermochemical water splitting cycle. The work consisted of laboratory bench-scale investigations, demonstration of the process in a closed-loop cycle demonstrator, and process engineering design studies. A bench-scale system, consisting of three subunits, has been designed to study the cycle under continuous flow conditions. The designs of subunit I, which models the main solution reaction and product separation, and subunit II, which models the concentration and decomposition of sulfuric acid, were presented in an earlier annual report. The design of subunit III, which models the purification and decomposition of hydrogen iodide, is given in this report. Progress on the installation and operation of subunits I and II is described. A closed-loop cycle demonstrator was installed and operated based on a DOE request. Operation of the GA sulfur-iodine cycle was demonstrated in this system under recycle conditions. The process engineering addresses the flowsheet design of a large-scale production process consisting of four chemical sections (I through IV) and one helium heat supply section (V). The completed designs for sections I through V are presented. The thermal efficiency of the process calculated from the present flowsheet is 47%.

  14. Regeneration of Hydrotreating and FCC Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    CM Wai; JG Frye; JL Fulton; LE Bowman; LJ Silva; MA Gerber

    1999-09-30

    Hydrotreating, hydrocracking, and fluid catalytic cracking (FCC) catalysts are important components of petroleum refining processes. Hydrotreating and hydrocracking catalysts are used to improve the yield of high-quality light oil fractions from heavier crude oil and petroleum feedstocks containing high levels of impurities. FCC catalysts improve the yield of higher octane gasoline from crude oil. Residuum hydrotreating and cracking catalysts are susceptible to irreversible deactivation caused by adsorption of sulfur and by metals impurities, such as vanadium and nickel. The gradual buildup of these impurities in a hydrotreating catalyst eventually plugs the pores and deactivates it. Nickel and vanadium adversely affect the behavior of cracking catalysts, reducing product yield and quality. Replacing deactivated catalysts represents a significant cost in petroleum refining. Equally important are the costs and potential liabilities associated with treating and disposing spent catalysts. For example, recent US Environmental Protection Agency rulings have listed spent hydrotreating and hydrorefining catalysts as hazardous wastes. FCC catalysts, though more easily disposed of as road-base or as filler in asphalt and cement, are still an economic concern mainly because of the large volumes of spent catalysts generated. New processes are being considered to increase the useful life of catalysts or for meeting more stringent disposal requirements for spent catalysts containing metals. This report discusses a collaborative effort between Pacific Northwest National Laboratory (PNNL) and Phillips Petroleum, Inc., to identify promising chemical processes for removing metals adhered to spent hydrodesulfurization (HDS, a type of hydrotreating catalyst) and FCC catalysts. This study, conducted by PNNL, was funded by the US Department of Energy's Bartlesville Project Office. Fresh and spent catalysts were provided by Phillips Petroleum. The FCC catalyst was a rare

  15. Removal of 226Ra from tailings pond effluents and stabilization of uranium mine tailings. Bench and pilot scale studies

    International Nuclear Information System (INIS)

    Schmidtke, N.W.; Averill, D.; Bryant, D.N.; Wilkinson, P.; Schmidt, J.W.

    1978-01-01

    Increased world demand for uranium has resulted in recent expansion of Canadian uranium mining operations. Problems have been identified with the discharge of radionuclides such as 226 Ra from tailings pond effluents and with the stabilization of mine tailings. At Environment Canada's Wastewater Technology Centre (WTC) two projects were undertaken in cooperation with the Canadian Uranium Mining Industry and other federal government agencies to address these problems. The first project reports on the progress of bench and pilot scale process simulations for the development of a data base for the design of a full scale mechanical physical/chemical 226 Ra removal waste treatment system with an effluent target level of 10 pCi 226 Ra total per litre. The second project addresses problems of the leachability of radionuclides and the stabilization of both uranium mine tailings and BaRaSO 4 sediments from the treatment of acid seepages

  16. The use of bench- and field-scale data for design of an in situ carbon tetrachloride bioremediation system

    International Nuclear Information System (INIS)

    Peyton, B.M.; Truex, M.J.; Skeen, R.S.

    1995-04-01

    A suite of simulation models were developed as a design tool in support of an in situ bioremediation demonstration at the Hanford site in Washington state. The design tool, calibrated with field - and bench-scale data, was used to answer four field-scale system design questions: (1) What are the important reaction processes and kinetics? (2) How will biomass distribute in the aquifer in response to injected substrate? (3) What well configuration best ensures proper nutrient transport and process control? (4) What operating and monitoring strategy should be used to confirm effective remediation? This paper does not describe the design tool itself, but describes how the design tool was used to optimize field site design parameters such as well spacing, hydraulic control, contaminant destruction, and nutrient injection strategies

  17. Runoff and sediment generation on bench-terraced hillsides: measurements and up-scaling of a field-based model

    Science.gov (United States)

    van Dijk, A. I. J. M.; Bruijnzeel, L. A.; Vertessy, R. A.; Ruijter, J.

    2005-05-01

    Despite widespread bench-terracing, stream sediment yields from agricultural hillsides in upland West Java remain high. We studied the causes of this lack of effect by combining measurements at different spatial scales using an erosion process model. Event runoff and sediment yield from two 4-ha terraced hillside subcatchments were measured and field surveys of land use, bench-terrace geometry and storage of sediment in the drainage network were conducted for two consecutive years. Runoff was 3.0-3.9% of rainfall and sediment yield was 11-30 t ha-1 yr-1 for different years, subcatchments and calculation techniques. Sediment storage changes in the subcatchment drainage network were less than 2 t ha-1, whereas an additional 0.3-1.5 t ha-1 was stored in the gully between the subcatchment flumes and the main stream. This suggests mean annual sediment delivery ratios of 86-125%, or 80-104% if this additional storage is included. The Terrace Erosion and Sediment Transport (TEST) model developed and validated for the studied environment was parameterized using erosion plot studies, land use surveys and digital terrain analysis to simulate runoff and sediment generation on the terraced hillsides. This resulted in over-estimates of runoff and under-estimates of runoff sediment concentration. Relatively poor model performance was attributed to sample bias in the six erosion plots used for model calibration and unaccounted covariance between important terrain attributes such as slope, infiltration capacity, soil conservation works and vegetation cover.

  18. Experimental and modelling studies on continuous synthesis and refining of biodiesel in a dedicated bench scale unit using centrifugal contactor separator technology

    NARCIS (Netherlands)

    Abduh, Muhammad Yusuf; Martinez, Alberto Fernandez; Kloekhorst, Arjan; Manurung, Robert; Heeres, Hero J.

    Continuous synthesis and refining of biodiesel (FAME) using a laboratory scale bench scale unit was explored. The unit consists of three major parts: (i) a continuous centrifugal contactor separator (CCCS) to perform the reaction between sunflower oil and methanol; (ii) a washing unit for the crude

  19. Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for Coal-Fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Lail, Marty

    2017-09-12

    The project aimed to advance RTI’s non-aqueous amine solvent technology by improving the solvent to reduce volatility, demonstrating long-term continuous operation at lab- (0.5 liters solvent) and bench-scale (~120 liters solvent), showing low reboiler heat duty measured during bench-scale testing, evaluating degradation products, building a rate-based process model, and evaluating the techno-economic performance of the process. The project team (RTI, SINTEF, Linde Engineering) and the technology performed well in each area of advancement. The modifications incorporated throughout the project enabled the attainment of target absorber and regenerator conditions for the process. Reboiler duties below 2,000 kJt/kg CO2 were observed in a bench-scale test unit operated at RTI.

  20. Bench Scale Development and Testing of Aerogel Sorbents for CO2 Capture Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Begag, Redouane [Aspen Aerogels, Northborough, MA (United States)

    2017-03-30

    The primary objective of this project was scaling up and evaluating a novel Amine Functionalized Aerogel (AFA) sorbent in a bench scale fluidized bed reactor. The project team (Aspen Aerogels, University of Akron, ADA-ES, and Longtail Consulting) has carried out numerous tests and optimization studies to demonstrate the CO2 capture performance of the AFA sorbent in all its forms: powder, pellet, and bead. The CO2 capture target performance of the AFA sorbent (all forms) were set at > 12 wt.% and > 6 wt.% for total and working CO2 capacity, respectively (@ 40 °C adsorption / 100 – 120 °C desorption). The optimized AFA powders outperformed the performance targets by more than 30%, for the total CO2 capacity (14 - 20 wt.%), and an average of 10 % more for working CO2 capacity (6.6 – 7.0 wt.%, and could be as high as 9.6 wt. % when desorbed at 120 °C). The University of Akron developed binder formulations, pellet production methods, and post treatment technology for increased resistance to attrition and flue gas contaminants. In pellet form the AFA total CO2 capacity was ~ 12 wt.% (over 85% capacity retention of that of the powder), and there was less than 13% degradation in CO2 capture capacity after 20 cycles in the presence of 40 ppm SO2. ADA-ES assessed the performance of the AFA powder, pellet, and bead by analyzing sorption isotherms, water uptake analysis, cycling stability, jet cup attrition and crush tests. At bench scale, the hydrodynamic and heat transfer properties of the AFA sorbent pellet in fluidized bed conditions were evaluated at Particulate Solid Research, Inc. (PSRI). After the process design requirements were completed, by Longtail Consulting LLC, a techno-economic analysis was achieved using guidance from The National Energy Technology Laboratory (NETL) report. This report provides the necessary framework to estimate costs for a temperature swing post

  1. Appling hydrolysis acidification-anoxic–oxic process in the treatment of petrochemical wastewater: From bench scale reactor to full scale wastewater treatment plant

    International Nuclear Information System (INIS)

    Wu, Changyong; Zhou, Yuexi; Sun, Qingliang; Fu, Liya; Xi, Hongbo; Yu, Yin; Yu, Ruozhen

    2016-01-01

    Highlights: • Hydrolysis acidification-anoxic–oxic process can be used to treat petrochemical wastewater. • The toxicity and treatability changed significantly after hydrolysis acidification. • The type and concentration of organics reduced greatly after treatment. • The effluent shows low acute toxicity by luminescent bacteria assay. • Advanced treatment is recommended for the effluent. - Abstract: A hydrolysis acidification (HA)-anoxic–oxic (A/O) process was adopted to treat a petrochemical wastewater. The operation optimization was carried out firstly by a bench scale experimental reactor. Then a full scale petrochemical wastewater treatment plant (PCWWTP, 6500 m 3 h −1 ) was operated with the same parameters. The results showed that the BOD 5 /COD of the wastewater increased from 0.30 to 0.43 by HA. The effluent COD was 54.4 mg L −1 for bench scale reactor and 60.9 mg L −1 for PCWWTP when the influent COD was about 480 mg L −1 on optimized conditions. The organics measured by gas chromatography-mass spectrometry (GC–MS) reduced obviously and the total concentration of the 5 organics (1,3-dioxolane, 2-pentanone, ethylbenzene, 2-chloromethyl-1,3-dioxolane and indene) detected in the effluent was only 0.24 mg L −1 . There was no obvious toxicity of the effluent. However, low acute toxicity of the effluent could be detected by the luminescent bacteria assay, indicating the advanced treatment is needed. The clone library profiling analysis showed that the dominant bacteria in the system were Acidobacteria, Proteobacteria and Bacteriodetes. HA-A/O process is suitable for the petrochemical wastewater treatment.

  2. Comparison of complex effluent treatability in different bench scale microbial electrolysis cells

    KAUST Repository

    Ullery, Mark L.

    2014-10-01

    A range of wastewaters and substrates were examined using mini microbial electrolysis cells (mini MECs) to see if they could be used to predict the performance of larger-scale cube MECs. COD removals and coulombic efficiencies corresponded well between the two reactor designs for individual samples, with 66-92% of COD removed for all samples. Current generation was consistent between the reactor types for acetate (AC) and fermentation effluent (FE) samples, but less consistent with industrial (IW) and domestic wastewaters (DW). Hydrogen was recovered from all samples in cube MECs, but gas composition and volume varied significantly between samples. Evidence for direct conversion of substrate to methane was observed with two of the industrial wastewater samples (IW-1 and IW-3). Overall, mini MECs provided organic treatment data that corresponded well with larger scale reactor results, and therefore it was concluded that they can be a useful platform for screening wastewater sources. © 2014 Elsevier Ltd.

  3. In Developping a Bench-Scale Circulating Fluidized Bed Combustor to Burn High Ash Brazilian Coal-Dolomites Mixtures

    Science.gov (United States)

    Ramírez Behainne, Jhon Jairo; Hory, Rogério Ishikawa; Goldstein, Leonardo; Bernárdez Pécora, Araí Augusta

    This work considers some of the questions in burning high ash Brazilian coal-dolomite mixtures in a bench-scale circulating fluidized bed combustor (CFBC). Experimental tests were performed with the CE4500 coal from Santa Catarina State, in southern Brazil, with a Sauter mean diameter d p =43 μm. The coal particles were mixed with dolomite particles of d p = 111 μm and this fuel mixture was fed into the circulating fluidized reactor, previously loaded with quartz sand particles of d p =353 μm. This inert material was previously heated by the combustion of liquefied petroleum gas up to the ignition temperature of the fuel mixture. The CFBC unit has a 100mm internal diameter riser, 4.0m high, as well as a 62.8mm internal diameter downcomer. The loop has a cyclone, a sampling valve to collect particles and a 62.8mm internal diameter L-valve to recirculate the particles in the loop. A screw feeder with a rotation control system was used to feed the fuel mixture to the reactor. The operational conditions were monitored by pressure taps and thermocouples installed along the loop. A data acquisition system showed the main operational conditions to control. Experimental tests performed put in evidence the problems found during bed operation, with special attention to the solids feed device, to the L-valve operation, to particle size, solids inventory, fluidized gas velocity, fuel mixture and recirculated solids feeding positions.

  4. Comparison of glassy slag waste forms produced in laboratory crucibles and in a bench-scale plasma furnace

    International Nuclear Information System (INIS)

    Feng, X.; Wronkiewicz, D.J.; Brown, N.R.; Gong, M.; Whitworth, C.; Filius, K.; Battleson, D.

    1994-01-01

    Vitrification is currently the best demonstrated available technology for the disposal of high-level radioactive wastes. An innovative vitrification approach known as minimum additive waste stabilization (MAWS) is being developed. Both homogeneous glass and glassy slags have been used in implementing MAWS. Glassy slags (vitro-ceramics) are glass-crystal composites, and they are composed of various metal oxide crystalline phases embedded in an aluminosilicate glass matrix. Glassy slags with compositions developed in crucible melts at Argonne National Laboratory (ANL) were successfully produced in a bench-scale Retech plasma centrifugal furnace (PCF) by MSE, Inc. Detailed examinations of these materials showed that the crucible melts and the PCF produced similar glass and crystalline phases. The two sets of glassy slags exhibited similar chemical durability in terms of normalized releases of their major components. The slags produced in the PCF furnace using metals were usually less oxidized, although this had no effect on the corrosion behavior of the major components of the slags. However, the normalized release rate of cerium was initially lower for the PCF slags. This difference diminished with time as the redox sates of the metal oxides in slags began to be controlled by exposure to air in the tests. Thus, the deference in cerium release due to the differences in slag redox state may be transitory. The cerium solubility is a complex function of redox state and solution pH and Eh

  5. Passive flux meter measurement of water and nutrient flux in saturated porous media: bench-scale laboratory tests.

    Science.gov (United States)

    Cho, Jaehyun; Annable, Michael D; Jawitz, James W; Hatfield, Kirk

    2007-01-01

    The passive nutrient flux meter (PNFM) is introduced for simultaneous measurement of both water and nutrient flux through saturated porous media. The PNFM comprises a porous sorbent pre-equilibrated with a suite of alcohol tracers, which have different partitioning coefficients. Water flux was estimated based on the loss of loaded resident tracers during deployment, while nutrient flux was quantified based on the nutrient solute mass captured on the sorbent. An anionic resin, Lewatit 6328 A, was used as a permeable sorbent and phosphate (PO4(3-)) was the nutrient studied. The phosphate sorption capacity of the resin was measured in batch equilibration tests as 56 mg PO4(3-) g(-1), which was determined to be adequate capacity to retain PO4(3-) loads intercepted over typical PNFM deployment periods in most natural systems. The PNFM design was validated with bench-scale laboratory tests for a range of 9.8 to 28.3 cm d(-1) Darcy velocities and 6 to 43 h deployment durations. Nutrient and water fluxes measured by the PNFM averaged within 6 and 12% of the applied values, respectively, indicating that the PNFM shows promise as a tool for simultaneous measurement of water and nutrient fluxes.

  6. In-situ biogas upgrading during anaerobic digestion of food waste amended with walnut shell biochar at bench scale.

    Science.gov (United States)

    Linville, Jessica L; Shen, Yanwen; Ignacio-de Leon, Patricia A; Schoene, Robin P; Urgun-Demirtas, Meltem

    2017-06-01

    A modified version of an in-situ CO 2 removal process was applied during anaerobic digestion of food waste with two types of walnut shell biochar at bench scale under batch operating mode. Compared with the coarse walnut shell biochar, the fine walnut shell biochar has a higher ash content (43 vs. 36 wt%) and higher concentrations of calcium (31 vs. 19 wt% of ash), magnesium (8.4 vs. 5.6 wt% of ash) and sodium (23.4 vs. 0.3 wt% of ash), but a lower potassium concentration (0.2 vs. 40% wt% of ash). The 0.96-3.83 g biochar (g VS added ) -1 fine walnut shell biochar amended digesters produced biogas with 77.5%-98.1% CH 4 content by removing 40%-96% of the CO 2 compared with the control digesters at mesophilic and thermophilic temperature conditions. In a direct comparison at 1.83 g biochar (g VS added ) -1 , the fine walnut shell biochar amended digesters (85.7% CH 4 content and 61% CO 2 removal) outperformed the coarse walnut shell biochar amended digesters (78.9% CH 4 content and 51% CO 2 removal). Biochar addition also increased alkalinity as CaCO 3 from 2800 mg L -1 in the control digesters to 4800-6800 mg L -1 , providing process stability for food waste anaerobic digestion.

  7. PNNL Report on the Development of Bench-scale CFD Simulations for Gas Absorption across a Wetted Wall Column

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chao; Xu, Zhijie; Lai, Canhai; Whyatt, Greg A.; Marcy, Peter; Gattiker, J. R.; Sun, Xin

    2016-05-01

    This report is prepared for the demonstration of hierarchical prediction of carbon capture efficiency of a solvent-based absorption column. A computational fluid dynamics (CFD) model is first developed to simulate the core phenomena of solvent-based carbon capture, i.e., the CO2 physical absorption and chemical reaction, on a simplified geometry of wetted wall column (WWC) at bench scale. Aqueous solutions of ethanolamine (MEA) are commonly selected as a CO2 stream scrubbing liquid. CO2 is captured by both physical and chemical absorption using highly CO2 soluble and reactive solvent, MEA, during the scrubbing process. In order to provide confidence bound on the computational predictions of this complex engineering system, a hierarchical calibration and validation framework is proposed. The overall goal of this effort is to provide a mechanism-based predictive framework with confidence bound for overall mass transfer coefficient of the wetted wall column (WWC) with statistical analyses of the corresponding WWC experiments with increasing physical complexity.

  8. Dynamics of bacterial populations during bench-scale bioremediation of oily seawater and desert soil bioaugmented with coastal microbial mats.

    Science.gov (United States)

    Ali, Nidaa; Dashti, Narjes; Salamah, Samar; Sorkhoh, Naser; Al-Awadhi, Husain; Radwan, Samir

    2016-03-01

    This study describes a bench-scale attempt to bioremediate Kuwaiti, oily water and soil samples through bioaugmentation with coastal microbial mats rich in hydrocarbonoclastic bacterioflora. Seawater and desert soil samples were artificially polluted with 1% weathered oil, and bioaugmented with microbial mat suspensions. Oil removal and microbial community dynamics were monitored. In batch cultures, oil removal was more effective in soil than in seawater. Hydrocarbonoclastic bacteria associated with mat samples colonized soil more readily than seawater. The predominant oil degrading bacterium in seawater batches was the autochthonous seawater species Marinobacter hydrocarbonoclasticus. The main oil degraders in the inoculated soil samples, on the other hand, were a mixture of the autochthonous mat and desert soil bacteria; Xanthobacter tagetidis, Pseudomonas geniculata, Olivibacter ginsengisoli and others. More bacterial diversity prevailed in seawater during continuous than batch bioremediation. Out of seven hydrocarbonoclastic bacterial species isolated from those cultures, only one, Mycobacterium chlorophenolicum, was of mat origin. This result too confirms that most of the autochthonous mat bacteria failed to colonize seawater. Also culture-independent analysis of seawater from continuous cultures revealed high-bacterial diversity. Many of the bacteria belonged to the Alphaproteobacteria, Flavobacteria and Gammaproteobacteria, and were hydrocarbonoclastic. Optimal biostimulation practices for continuous culture bioremediation of seawater via mat bioaugmentation were adding the highest possible oil concentration as one lot in the beginning of bioremediation, addition of vitamins, and slowing down the seawater flow rate. © 2016 The Author. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  9. Bench-scale crossflow filtration of Hanford tank C-106, C-107, B-110, and U-110 sludge slurries

    International Nuclear Information System (INIS)

    Geeting, J.G.H.; Reynolds, B.A.

    1997-09-01

    Pacific Northwest National Laboratory has a bench-scale crossflow filter installed in a shielded hot cell for testing radioactive feeds. During FY97 experiments were conducted on slurries from radioactive Hanford waste from tanks C-106, C-107, B-110, and U-110. Each tank was tested at three slurry concentrations (8, 1.5, and 0.05 wt% solids). A two-parameter central composite design which tested transmembrane pressure from 5 to 40 psig and axial velocity from 3 to 9 ft/s was used for all feeds. Crossflow filtration was found to remove solids effectively, as judged by filtrate clarity and radiochemical analysis. If the filtrates from these tests were immobilized in a glass matrix, the resulting transuranic and ( 90 Sr) activity would not breach low activity waste glass limits of 100nCi/g (TRU) and 20 μCi/ml ( 90 Sr). Two exceptions were the transuranic activity in filtrates from processing 1.5 and 8 wt% C-106 tank waste. Subsequent analyses indicated that the source of the TRU activity in the filtrate was most likely due to soluble activity, but obviously proved ineffective at removing the soluble plutonium species. Re-testing of the C-106 supported this hypothesis. These data suggest the need to control carbonate and pH when processing tank wastes for immobilization

  10. Bench-scale cross flow filtration of Tank S-107 sludge slurries and Tank C-107 supernatant

    International Nuclear Information System (INIS)

    Geeting, J.G.H.; Reynolds, B.A.

    1996-10-01

    Hanford tank waste filtration experiments were conducted using a bench-scale cross flow filter on 8 wt%, 1.5 wt%, and 0.05 wt% Tank S- 107 sludge slurries and on Tank C-107 supernatant. For comparison, two simulants each with solids loadings of 8 wt% and 0.05 wt% were also tested. The purpose of the tests was to determine the efficacy of cross flow filtration on slurries of various solids loadings. -In addition, filtrate flux dependency on axial velocity and transmembrane pressure was sought so that conditions for future experiments might be better selected. The data gathered are compared to the simulants and three cross flow filtration models. A two- parameter central composite design which tested. transmembrane pressure from 5 to 40 psig and axial Velocity from 3 to 9 ft/s was used for all feeds. The cross flow filter effectively removed solids from the liquid, as 19 of 20 filtrate samples had particle concentrations below the resolution limit of the photon correlation spectrometer used in the Hanford Radiocolloid Laboratory. Radiochemical analysis indicate that all filtrate samples were below Class A waste classification standards for 9OSr and transuranics

  11. Production of uranium hexafluoride by the catalysed fluorox process: pilot plant and supporting bench-scale studies

    International Nuclear Information System (INIS)

    Janov, J.; Charlton, B.G.; LePage, A.H.; Vilkaitis, V.K.

    1982-04-01

    The feasibility of producing UF 6 by the catalysed reaction of UF 4 with oxygen (the Fluorox process) was investigated in a 150 mm diameter fluidised bed reactor and in supporting bench-scale experiments. The rate of the Fluorox reaction in batch experiments was increased by an order of magnitude with 1 to 5 per cent catalyst (containing 3 to 4 per cent platinum on alumina). The maximum UF 6 production rate at 650 deg. C was 0.9 kg h -1 . However, the platinum catalyst was completely poisoned after production of only 1 and 20 kg UF 6 per kg of catalyst when using respectively French and British UF 4 . Regeneration of the catalyst was demonstrated to be technically feasible by washing with water or ammonium oxalate solution or treating with hydrogen and hydrogen fluoride at 350-650 deg. C. However, since the very fast rate of poisoning would necessitate higher catalyst concentrations and/or frequent regeneration, the catalysed Fluorox process in unlikely to be economically competitive with the direct fluorination of UF 4

  12. Hydrogen generation from bioethanol reforming: bench-scale unit performance with Cu/Nb2O5 catalyst

    International Nuclear Information System (INIS)

    Fernandes Machado, N.R.C.; Schmal, M.; Cantao, M.P.

    2003-01-01

    As an alternative route for hydrogen production, ethanol reforming was studied in a bench-scale unit using a 5%Cu/Nb 2 O 5 catalyst previously selected in a micro reactor. X-Ray Diffraction analysis has shown that this catalyst contains copper oxide in an amorphous form, or in particles smaller than 20 nm, while the Nb 2 O 5 is highly crystalline. Analysis of the calcinated catalyst by X-Ray Photoelectron Spectroscopy revealed that 35% of total copper was on the surface as Cu I (55%) or Cu II (45%). The catalyst presented a low surface area (35 m 2 /g), mainly from meso and macropores, as textural analysis revealed. Temperature Programmed Reduction showed a two-step reduction of Cu II to Cu, at 245 o C and 306 o C. It was also observed the reduction of 6% of Nb 2 O 5 . The reaction unit consisted of an integral reactor with 16 g of catalyst pellets, approximately 3 mm x 5 mm in size. Reaction temperature and feed rate were varied to optimize hydrogen production, with CO 2 as the main byproduct. Reagents (water and ethanol) in stoichiometric proportion were fed into an electric pre-heater and vaporized. An increase on reaction temperature from 300 o C to 400 o C has led to an increase in mean conversion from 17% to 35%. Ethene and ethyl ether were also detected as minor byproducts. (author)

  13. Bench-scale study of active mine water treatment using cement kiln dust (CKD) as a neutralization agent.

    Science.gov (United States)

    Mackie, Allison L; Walsh, Margaret E

    2012-02-01

    The overall objective of this study was to investigate the potential impact on settled water quality of using cement kiln dust (CKD), a waste by-product, to replace quicklime in the active treatment of acidic mine water. Bench-scale experiments were conducted to evaluate the treatment performance of calcium hydroxide (Ca(OH)(2)) slurries generated using four different CKD samples compared to a control treatment with quicklime (CaO) in terms of reducing acidity and metals concentrations in acid mine drainage (AMD) samples taken from the effluent of a lead/zinc mine in Atlantic Canada. Results of the study showed that all of the CKD samples evaluated were capable of achieving greater than 97% removal of total zinc and iron. The amount of solid alkaline material required to achieve pH targets required for neutralization of the AMD was found to be higher for treatment with the CKD slurries compared to the quicklime slurry control experiments, and varied linearly with the free lime content of the CKD. The results of this study also showed that a potential benefit of treating mine water with CKD could be reduced settled sludge volumes generated in the active treatment process, and further research into the characteristics of the sludge generated from the use of CKD-generated calcium hydroxide slurries is recommended. Copyright © 2011 Elsevier Ltd. All rights reserved.

  14. Bench-scale study of the effect of phosphate on an aerobic iron oxidation plant for mine water treatment.

    Science.gov (United States)

    Tischler, Judith S; Wiacek, Claudia; Janneck, Eberhard; Schlömann, Michael

    2014-01-01

    At the opencast pit Nochten acidic iron- and sulfate-rich mine waters are treated biotechnologically in a mine-water treatment plant by microbial iron oxidation. Due to the low phosphate concentration in such waters the treatment plant was simulated in bench-scale to investigate the influence of addition of potassium dihydrogen phosphate on chemical and biological parameters of the mine-water treatment. As a result of the phosphate addition the number of cells increased, which resulted in an increase of the iron oxidation rate in the reactor with phosphate addition by a factor of 1.7 compared to a reference approach without phosphate addition. Terminal restriction fragment length polymorphism (T-RFLP) analysis during the cultivation revealed a shift of the microbial community depending on the phosphate addition. While almost exclusively iron-oxidizing bacteria related to "Ferrovum" sp. were detected with phosphate addition, the microbial community was more diverse without phosphate addition. In the latter case, iron-oxidizing bacteria ("Ferrovum" sp., Acidithiobacillus spp.) as well as non-iron-oxidizing bacteria (Acidiphilium sp.) were identified. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. EFRT M-12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    International Nuclear Information System (INIS)

    Rapko, Brian M.; Schonewill, Philip P.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2010-01-01

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, 'Undemonstrated Leaching Processes' of the External Flowsheet Review Team (EFRT) issue response plan. The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  16. EFRT M-12 Issue Resolution: Comparison of PEP and Bench-Scale Oxidative Leaching Results

    Energy Technology Data Exchange (ETDEWEB)

    Rapko, Brian M.; Schonewill, Philip P.; Brown, Christopher F.; Eslinger, Paul W.; Fountain, Matthew S.; Hausmann, Tom S.; Huckaby, James L.; Hanson, Brady D.; Kurath, Dean E.; Minette, Michael J.

    2010-01-01

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed, and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  17. Destruction of hazardous and mixed wastes using mediated electrochemical oxidation in a Ag(II)HNO3 bench scale system

    International Nuclear Information System (INIS)

    Balazs, B.; Chiba, Z.; Hsu, P.; Lewis, P.; Murguia, L.; Adamson, M.

    1997-01-01

    Mediated Electrochemical Oxidation (MEO) is a promising technology for the destruction of organic containing wastes and the remediation of mixed wastes containing transuranic components. The combination of a powerful oxidant and an acid solution allows the conversion of nearly all organics, whether present in hazardous or in mixed waste, to carbon dioxide. Insoluble transuranics are dissolved in this process and may be recovered by separation and precipitation.The MEO technique offers several advantages which are inherent in the system. First, the oxidation/dissolution processes are accomplished at near ambient pressures and temperatures (30-70 degrees C). Second, all waste stream components and oxidation products (with the exception of evolved gases) are contained in an aqueous environment. This electrolyte acts as an accumulator for inorganics which were present in the original waste stream, and the large volume of electrolyte provides a thermal buffer for the energy released during oxidation of the organics. Third, the generation of secondary waste is minimal, as the process needs no additional reagents. Finally, the entire process can be shut down by simply turning off the power, affording a level of control unavailable in some other techniques.Numerous groups, both in the United States and Europe, have made substantial progress in the last decade towards understanding the mechanistic pathways, kinetics, and engineering aspects of the process. At Lawrence Livermore National Laboratory, substantial contributions have been made to this knowledge base in these areas and others. Conceptual design and engineering development have been completed for a pilot plant-scale MEO system, and numerous data have been gathered on the efficacy of the process for a wide variety of anticipated waste components. This presentation will review the data collected at LLNL for a bench scale system based primarily on the use of a Ag(II) mediator in a nitric acid electrolyte; results

  18. Investigations into NOx emissions and burnout for coals with high ash content in a bench scale test facility

    Energy Technology Data Exchange (ETDEWEB)

    Greul, U.; Kluger, F.; Peter, G.; Spliethoff, H.; Hein, K.R.G. [University of Stuttgart, Stuttgart (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen

    2000-07-01

    At the Stuttgart University's Institute of Process Engineering and Power Plant Technology (IVD) investigations of in-furnace DeNOx technologies with regard to their NOx reduction efficiency are carried out using an electrically heated bench-scale test facility to evaluate the effect of different process parameters independently. The DeNOx technologies of air and fuel staging have been demonstrated to be effective control techniques to reduce NOx from stationary sources. For a wide range of brown and hard coals from Europe, South Africa and Australia test runs with air-staged combustion have been carried out. The ash content of the hard coals used was in the range between 8 and 28%. The investigated parameters were temperature (1000-1300{degree}C), stoichiometry (1.25-0.55), and residence time (1-6 s) in the fuel rich primary zone. With increasing temperatures and residence times in fuel-rich conditions in air-staged combustion NOx emissions below 300 mg/m{sup 3} can be achieved even with hard coals. For a few brown coals NOx values lower than 100 mg/m{sup 3} are possible. Dependent on the coal rank individual parameters are more important than others. For low and medium volatile hard coals the increasing of the residence time is more effective than higher temperature or lower air ratios in the primary zone. However, with high volatile hard coal or brown coal as primary fuel the influence of temperature and stoichiometry in the primary zone plays a key role for NOx reduction effectiveness. The burnout led to restrictions in large scale applications for air-staged combustion especially with hard coals as primary fuel. Investigations at different primary air ratios and temperatures show the effect of these parameters on the burnout values along the course of combustion. 7 refs., 14 figs., 2 tabs.

  19. Bench-scale studies on capture of mercury on mineral non-carbon based sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yang [Huazhong Univ. of Science and Technology, Wuhan (China). State Key Lab. of Coal Combustion; Utah Univ., Salt Lake City, UT (United States). Dept. of Chemical Engineering; Wendt, Jost O.L. [Utah Univ., Salt Lake City, UT (United States). Dept. of Chemical Engineering; Zhang, Junying; Zheng, Chuguang [Huazhong Univ. of Science and Technology, Wuhan (China). State Key Lab. of Coal Combustion

    2013-07-01

    A new high-temperature, mineral non-carbon based dispersed sorbent derived from paper recycling products has been shown to capture mercury at high temperatures in excess of 600 C. The sorbent is consisted of kaolinite/calcite/lime mixtures. Experiments have been conducted on chemi-sorption of elemental mercury in air on a packed bed. The sorption occurs at temperatures between 600 and 1,100 C and requires activation of the minerals contained within the sorbents. Mercury capture is dominated by temperature and capture on sorbents over long time scales. The capture shows a maximum effectiveness at 1,000 C and increases monotonically with temperature. The presence of oxygen is also the required. Freshly activated sorbent is the most effective, and deactivation of sorbents occurs at high temperatures with long pre-exposure times. This activation is suspected to involve a solid-solid reaction between intimately mixed calcium oxide and silica that are both contained within the sorbent. Deactivation occurs at temperatures higher than 1,000 C, and this is due to melting of the substrate and pore closure. The situation in packed beds is complicated because the bed also shrinks, thus allowing channeling and by-passing, and consequent ambiguities in determining sorbent saturation. Sorbent A had significantly greater capacity for mercury sorption than did Sorbent B, for all temperatures and exposure time examined. The effect of SiO{sub 2} on poor Sorbent B is much larger than sorbent A.

  20. Kinetics experiments and bench-scale system: Background, design, and preliminary experiments

    International Nuclear Information System (INIS)

    Rofer, C.K.

    1987-10-01

    The project, Supercritical Water Oxidation of Hazardous Chemical Waste, is a Hazardous Waste Remedial Actions Program (HAZWRAP) Research and Development task being carried out by the Los Alamos National Laboratory. Its objective is to obtain information for use in understanding the basic technology and for scaling up and applying oxidation in supercritical water as a viable process for treating a variety of DOE-DP waste streams. This report gives the background and rationale for kinetics experiments on oxidation in supercritical water being carried out as a part of this HAZWRAP Research and Development task. It discusses supercritical fluid properties and their relevance to applying this process to the destruction of hazardous wastes. An overview is given of the small emerging industry based on applications of supercritical water oxidation. Factors that could lead to additional applications are listed. Modeling studies are described as a basis for the experimental design. The report describes plug flow reactor and batch reactor systems, and presents preliminary results. 28 refs., 4 figs., 5 tabs

  1. Results with a bench scale downdraft biomass gasifier for agricultural and forestry residues

    Energy Technology Data Exchange (ETDEWEB)

    Olgun, Hayati [TUBITAK Marmara Research Center, Energy Institute, P.O. Box 21, 41470 Gebze, Kocaeli (Turkey); Ozdogan, Sibel; Yinesor, Guzide [Marmara University-Goztepe Campus, Faculty of Engineering - Department of Mechanical Engineering, 34722 Kuyubasi Kadikoy Istanbul (Turkey)

    2011-01-15

    A small scale fixed bed downdraft gasifier system to be fed with agricultural and forestry residues has been designed and constructed. The downdraft gasifier has four consecutive reaction zones from the top to the bottom, namely drying, pyrolysis, oxidation and reduction zones. Both the biomass fuel and the gases move in the same direction. A throat has been incorporated into the design to achieve gasification with lower tar production. The experimental system consists of the downdraft gasifier and the gas cleaning unit made up by a cyclone, a scrubber and a filter box. A pilot burner is utilized for initial ignition of the biomass fuel. The product gases are combusted in the flare built up as part of the gasification system. The gasification medium is air. The air to fuel ratio is adjusted to produce a gas with acceptably high heating value and low pollutants. Within this frame, different types of biomass, namely wood chips, barks, olive pomace and hazelnut shells are to be processed. The developed downdraft gasifier appears to handle the investigated biomass sources in a technically and environmentally feasible manner. This paper summarizes selected design related issues along with the results obtained with wood chips and hazelnut shells. (author)

  2. Bench Scale Development and Testing of a Novel Adsorption Process for Post-Combustion CO₂ Capture

    Energy Technology Data Exchange (ETDEWEB)

    Jain, Ravi [Innosepra Limited Liability Company, Middlesex, NJ (United States)

    2015-09-01

    A physical sorption process to produce dry CO₂ at high purity (>98%) and high recovery (>90%) from the flue gas taken before or after the FGD was demonstrated both in the lab and in the field (one ton per day scale). A CO₂ recovery of over 94% and a CO₂ purity of over 99% were obtained in the field tests. The process has a moisture, SOX, and Hg removal stage followed by a CO₂ adsorption stage. Evaluations based on field testing, process simulation and detailed engineering studies indicate that the process has the potential for more than 40% reduction in the capital and more than 40% reduction in parasitic power for CO₂ capture compared to MEA. The process has the potential to provide CO₂ at a cost (<$40/tonne) and quality (<1 ppm H₂O, <1 ppm SOX, <10 ppm O₂) suitable for EOR applications which can make CO₂ capture profitable even in the absence of climate legislation. The process is applicable to power plants without SOX, Hg and NOX removal equipment.

  3. Investigation and Modelling of Diesel Hydrotreating Reactions

    DEFF Research Database (Denmark)

    Boesen, Rasmus Risum

    on a commercial CoMo catalyst, and a simple kinetic model is presented. Hydrogenation of fused aromatic rings are known to be fast, and it is possible, that the reaction rates are limited by either internal or external mass transfer. An experiment conducted at industrial temperatures and pressure, using...... naphthalene as a model compound, have shown, that intra-particle diffusion resistance are likely to limit the reaction rate. In order to produce ULSD it is necessary to remove sulfur from some of the most refrac- tive sulfur compounds, such as sterically hindered dibenzothiophenes. Basic nitrogen com- pounds...... are known to inhibit certain hydrotreating reactions. Experimental results are pre- sented, showing the effect of 3 different nitrogen compounds, acridine, 1,4-dimethylcarabazole and 3-methylindole, on the hydrodesulfurization of a real feed and of a model compound, 4,6-dimethyldibenzothiophene. It is shown...

  4. Uncertainty Quantification Analysis of Both Experimental and CFD Simulation Data of a Bench-scale Fluidized Bed Gasifier

    Energy Technology Data Exchange (ETDEWEB)

    Shahnam, Mehrdad [National Energy Technology Lab. (NETL), Morgantown, WV (United States). Research and Innovation Center, Energy Conversion Engineering Directorate; Gel, Aytekin [ALPEMI Consulting, LLC, Phoeniz, AZ (United States); Subramaniyan, Arun K. [GE Global Research Center, Niskayuna, NY (United States); Musser, Jordan [National Energy Technology Lab. (NETL), Morgantown, WV (United States). Research and Innovation Center, Energy Conversion Engineering Directorate; Dietiker, Jean-Francois [West Virginia Univ. Research Corporation, Morgantown, WV (United States)

    2017-10-02

    Adequate assessment of the uncertainties in modeling and simulation is becoming an integral part of the simulation based engineering design. The goal of this study is to demonstrate the application of non-intrusive Bayesian uncertainty quantification (UQ) methodology in multiphase (gas-solid) flows with experimental and simulation data, as part of our research efforts to determine the most suited approach for UQ of a bench scale fluidized bed gasifier. UQ analysis was first performed on the available experimental data. Global sensitivity analysis performed as part of the UQ analysis shows that among the three operating factors, steam to oxygen ratio has the most influence on syngas composition in the bench-scale gasifier experiments. An analysis for forward propagation of uncertainties was performed and results show that an increase in steam to oxygen ratio leads to an increase in H2 mole fraction and a decrease in CO mole fraction. These findings are in agreement with the ANOVA analysis performed in the reference experimental study. Another contribution in addition to the UQ analysis is the optimization-based approach to guide to identify next best set of additional experimental samples, should the possibility arise for additional experiments. Hence, the surrogate models constructed as part of the UQ analysis is employed to improve the information gain and make incremental recommendation, should the possibility to add more experiments arise. In the second step, series of simulations were carried out with the open-source computational fluid dynamics software MFiX to reproduce the experimental conditions, where three operating factors, i.e., coal flow rate, coal particle diameter, and steam-to-oxygen ratio, were systematically varied to understand their effect on the syngas composition. Bayesian UQ analysis was performed on the numerical results. As part of Bayesian UQ analysis, a global sensitivity analysis was performed based on the simulation results, which shows

  5. Effect of temperature downshifts on a bench-scale hybrid A/O system: Process performance and microbial community dynamics.

    Science.gov (United States)

    Zhou, Hexi; Li, Xiangkun; Chu, Zhaorui; Zhang, Jie

    2016-06-01

    Effect of temperature downshifts on process performance and bacterial community dynamics was investigated in a bench-scale hybrid A/O system treating real domestic wastewater. Results showed that the average COD removal in this system reached 90.5%, 89.1% and 90.3% for Run 1 (25 °C), Run 2 (15 °C) and Run 3 (10 °C), respectively, and variations in temperature barely affected the effluent COD concentration. The average removal efficiencies of NH4(+)-N were 98.4%, 97.8%, 95.7%, and that of TN were 77.1%, 61.8%, 72% at 25 °C, 15 °C and 10 °C, respectively. Although the hybrid system was subjected to low temperature, this process effectively removed NH4(+)-N and TN even at 10 °C with the average effluent concentrations of 2.4 mg/L and 14.3 mg/L, respectively. Results from high-throughput sequencing analysis revealed that when the operation temperature decreased from 25 °C to 10 °C, the richness and diversity indexes of the system decreased in the sludge samples, while underwent an increase in the biofilm samples. Furthermore, the major heterotrophic bacteria consisted of Lewinella, Lutimonas, Chitinophaga and Fluviicola at 10 °C, which could be central to effective COD removal at low temperature. Additionally, Azospira, one denitrifying-related genus increased from 0.4% to 4.45% in the biofilm samples, with a stable TN removal in response to temperature downshifts. Nitrosomonas and Nitrospira increased significantly in the biofilm samples, implying that the attached biofilm contributed to more nitrification at low temperature. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Treatment of simulated high-level radioactive waste with formic acid: Bench-scale study on hydrogen evolution

    International Nuclear Information System (INIS)

    Hsu, C.L.W.; Ritter, J.A.

    1996-01-01

    At the Savannah River Site, the Defense Waste Processing Facility (DWPF) was constructed to vitrify high-level radioactive liquid waste in borosilicate glass for permanent storage. Formic acid, which serves as both an acid and a reducing agent, is used to treat the washed alkaline sludge during melter feed preparation primarily to improve the processability of the feed and to reduce mercury to its zero state for steam stripping. The high-level sludge is composed of many transition metal hydroxides. Among them, there are small quantities of platinum group metals. During the treatment of simulated sludge with formic acid, significant amounts of hydrogen were generated when the platinum group metals were included in the sludge. Apparently the noble metals in the sludge were reduced to their zero states and caused formic acid to decompose catalytically into hydrogen and carbon dioxide, usually with an induction period. The production of hydrogen gas presented the DWPF with a safety issue. Therefore, the objective of this research was to gain a fundamental understanding of what controlled the hydrogen evolution so that a practical solution to the safety issue could be obtained. A bench-scale parametric study revealed the following: increasing the amount of formic acid added to the sludge increased the hydrogen generation rate dramatically; once the catalysts were activated, the hydrogen generation rate decreased significantly with a lowering of the temperature of the sludge; the relative catalytic activities of the noble metals in the sludge decreased in the following order: rhodium > ruthenium much-gt palladium; ammonium ions were generated catalytically from the reaction between formic acid and nitrate; and when present, the noble metals caused higher upward drifts of the sludge pH

  7. Experimental investigation of pyrolysis of rice straw using bench-scale auger, batch and fluidized bed reactors

    International Nuclear Information System (INIS)

    Nam, Hyungseok; Capareda, Sergio C.; Ashwath, Nanjappa; Kongkasawan, Jinjuta

    2015-01-01

    Energy conversion efficiencies of three pyrolysis reactors (bench-scale auger, batch, and fluidized bed) were investigated using rice straw as the feedstock at a temperature of 500 °C. The highest bio-oil yield of 43% was obtained from the fluidized bed reactor, while the maximum bio-char yield of 48% was obtained from the batch reactor. Similar bio-oil yields were obtained from the auger and batch type reactors. The GCMS and FTIR were used to evaluate the liquid products from all reactors. The best quality bio-oil and bio-char from the batch reactor was determined to have a heating value of 31 MJ/kg and 19 MJ/kg, respectively. The highest alkali mineral was found in the bio-char produced from the auger reactor. The energy conversion efficiencies of the three reactors indicated that the majority of the energy (50–64%) was in the bio-char products from the auger and batch reactors, while the bio-oil from the fluidized bed reactor contained the highest energy (47%). A Sankey diagram has been produced to show the flows of product energy from each pyrolysis process. The result will help determine which conversion process would be optimal for producing specific products of bio-char, bio-oil, and gas depending on the needs. - Highlights: • Pyrolysis products from auger, batch, and fluidized bed reactor were examined. • O/C ratios of bio-oils stayed in specific ranges depending on the process reactors. • The largest quantity of bio-oil from fluidized, while the best quality from batch. • The highest alkali concentration of 37 g/kg included in the auger based bio-char. • Sankey diagram was used to understand the energy distribution from reactors.

  8. Bench Scale Process for Low Cost CO2 Capture Using a Phase-Changing Absorbent: Final Scientific/Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Westendorf, Tiffany [GE Global Research, Niskayuna, New York (United States); Buddle, Stanlee [GE Global Research, Niskayuna, New York (United States); Caraher, Joel [GE Global Research, Niskayuna, New York (United States); Chen, Wei [GE Global Research, Niskayuna, New York (United States); Doherty, Mark [GE Global Research, Niskayuna, New York (United States); Farnum, Rachel [GE Global Research, Niskayuna, New York (United States); Giammattei, Mark [GE Global Research, Niskayuna, New York (United States); Hancu, Dan [GE Global Research, Niskayuna, New York (United States); Miebach, Barbara [GE Global Research, Niskayuna, New York (United States); Perry, Robert [GE Global Research, Niskayuna, New York (United States); Rubinsztajn, Gosia; Spiry, Irina; Wilson, Paul; Wood, Benjamin

    2017-05-31

    The objective of this project is to design and build a bench-scale process for a novel phase-changing aminosilicone-based CO2-capture solvent. The project will establish scalability and technical and economic feasibility of using a phase-changing CO2-capture absorbent for post-combustion capture of CO2 from coal-fired power plants. The U.S. Department of Energy’s goal for Transformational Carbon Capture Technologies is the development of technologies available for demonstration by 2025 that can capture 90% of emitted CO2 with at least 95% CO2 purity for less than $40/tonne of CO2 captured. In the first budget period of the project, the bench-scale phase-changing CO2 capture process was designed using data and operating experience generated under a previous project (ARPA-e project DE-AR0000084). Sizing and specification of all major unit operations was completed, including detailed process and instrumentation diagrams. The system was designed to operate over a wide range of operating conditions to allow for exploration of the effect of process variables on CO2 capture performance. In the second budget period of the project, individual bench-scale unit operations were tested to determine the performance of each of each unit. Solids production was demonstrated in dry simulated flue gas across a wide range of absorber operating conditions, with single stage CO2 conversion rates up to 75mol%. Desorber operation was demonstrated in batch mode, resulting in desorption performance consistent with the equilibrium isotherms for GAP-0/CO2 reaction. Important risks associated with gas humidity impact on solids consistency and desorber temperature impact on thermal degradation were explored, and adjustments to the bench-scale process were made to address those effects. Corrosion experiments were conducted to support selection of suitable materials of construction for the major

  9. Influence of toluene and salinity on biosurfactant production by Bacillus sp.: scale up from flasks to a bench-scale bioreactor

    Directory of Open Access Journals (Sweden)

    Ellen Cristina Souza

    Full Text Available ABSTRACT To select the best biosurfactant producer, Pseudomonas putida, Bacillus megatherium, Bacillus licheniformis and Bacillus subtilis were cultured in flasks on media with different salinity [low salinity (LS, Bushnell-Haas (BH and artificial sea water (SW media] supplemented or not with toluene as a model pollutant. Toluene inhibited the growth of all microorganisms and stimulated the biosurfactant production. B. subtilis exhibited the best performance, being able to lower the surface tension (ST in the LS medium to 65.5 mN/min in the absence of toluene, and to 46.5 mN/min in the BH medium in the presence of toluene, corresponding to ST reductions of 13.0 and 27.5 mN/m, respectively. Scaling up the process to a bench-scale fermentor, the best results were obtained in the LS medium, where B. subtilis was able to reduce the toluene concentration from 26.0 to 4.3 g/L within 12 h and ST by 17.2 mN/m within 18 h. The results of this study point out that B. subtilis is an interesting biosurfactant producer, which could be used in the bioremediation of toluene-contaminated water.

  10. Bench-Scale Synthetic Optimization of 1,2-bis(2-aminophenylthio)ethane (APO-Link) Used in the Production of APO-BMI Resin

    Energy Technology Data Exchange (ETDEWEB)

    Hilary Wheeler; Crystal Densmore

    2007-07-31

    The diamine reagent 1,2-bis(2-aminophenylthio)ethane is no longer commercially available but still required for the synthesis of the bismaleimide resin, APO-BMI, used in syntactic foams. In this work, we examined the hydrolysis of benzothiazole followed the by reaction with dichloroethane or dibromoethane. We also studied the deprotonation of 2-aminothiophenol followed by the reaction with dibromoethane. We optimized the latter for scale-up by scrutinizing all aspects of the reaction conditions, work-up and recrystallization. On bench-scale, our optimized procedure consistently produced a 75-80% overall yield of finely divided, high purity product (>95%).

  11. Loading intensity prediction by velocity and the OMNI-RES 0–10 scale in bench press

    OpenAIRE

    Naclerio, Fernando; Larumbe-Zabala, Eneko

    2017-01-01

    This study examined the possibility of using movement velocity and the perceived exertion as indicators of relative load in the bench press exercise. Three hundred eight young, healthy, resistance trained athletes (242 male and 66 female) performed a progressive strength test up to the one-repetition maximum for the individual determination of the full load-velocity and load-exertion relationships. Longitudinal regression models were used to predict the relative load from the average velocity...

  12. Hydrothermal and alkaline hydrothermal pretreatments plus anaerobic digestion of sewage sludge for dewatering and biogas production: Bench-scale research and pilot-scale verification.

    Science.gov (United States)

    Li, Chunxing; Wang, Xingdong; Zhang, Guangyi; Yu, Guangwei; Lin, Jingjiang; Wang, Yin

    2017-06-15

    To test the feasibility and practicability of the process combing hydrothermal pretreatment for dewatering with biogas production for full utilization of sewage sludge, hydrothermal/alkaline hydrothermal pretreatments and in turn anaerobic digestion of the filtrates obtained after dewatering the pretreated sludge were performed at bench- and pilot-scales. The hydrothermal temperature fell within the range of 140 °C-220 °C and the pretreatment time varied from 30 min to 120 min. For the alkaline hydrothermal pretreatment the pH value of the sludge was adjusted to 9.0-11.0 by adding Ca(OH) 2 . The results showed that the dewaterability of the sewage sludge was improved with increasing pretreatment temperature but the impact of the pretreatment time was not significant. The addition of Ca(OH) 2 gave better performance on the subsequent mechanical dewatering of the pretreated sludge compared to pure hydrothermal pretreatment, and the higher the pH value was, the better the dewaterability of the pretreated sludge was. The conditions of 180 °C/30 min and 160 °C/60 min/pH = 10.0 (for hydrothermal and alkaline hydrothermal pretreatments, respectively) resulted in relatively good results in the theoretical energy balance, which were verified in the pilot-scale tests. Based on the data from the pilot tests, the alkaline hydrothermal process realized self-sufficiency in energy at the cost of a proper amount of CaO. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Sulfur and octane trade off in FCC naphta conventional hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Badra, C. [INTEVEP S.A. Research and Technological Support Center of Petroleos de Venzuela, Caracas (Venezuela). Dept. de Refinacion; Perez, J.A. [INTEVEP S.A. Research and Technological Support Center of Petroleos de Venzuela, Caracas (Venezuela). Dept. de Refinacion; Salazar, J.A. [INTEVEP S.A. Research and Technological Support Center of Petroleos de Venzuela, Caracas (Venezuela). Dept. de Refinacion; Cabrera, L. [INTEVEP S.A. Research and Technological Support Center of Petroleos de Venzuela, Caracas (Venezuela). Dept. de Refinacion; Gracia, W. [INTEVEP S.A. Research and Technological Support Center of Petroleos de Venzuela, Caracas (Venezuela). Dept. de Refinacion

    1997-06-01

    A model to predict the change of octane numbers expected in an FCC naphtha hydrotreating process as a function of the hydroprocessing severity (degree of sulfur removal) and the type of naphtha (expressed as the sulfur content and bromine number in the feedstock) is presented. When considering hydrotreating as an option for processing their catalytic naphthas, refiners search for the proper balance between the desired reduction of sulfur and olefins and the resulting undesired reduction of octane (RON and MON). In doing so, refiners should study the possibility of performing the hydrotreating at mild severities and/or the possibility of fractionating FCC naphthas to just treat a specific cut. This paper provides simple tools to study and analyze these study cases and to assess the sulfur-octane trade offs. (orig.)

  14. Spectroscopy, microscopy and theoretical study of NO adsorption on MoS2 and Co-Mo-S hydrotreating catalysts

    DEFF Research Database (Denmark)

    Topsøe, Nan-Yu; Tuxen, Anders Kyrme; Hinnemann, Berit

    2011-01-01

    nfrared (IR) spectroscopy using NO as a probe molecule has been one of the important methods for characterizing hydrotreating catalysts, since this technique provides information on the nature and quantity of active edge sites of these catalysts. However, due to the strong adsorption of NO, which......) calculations, we present new atomic-scale insight into the nature of NO adsorption on MoS2 and Co-Mo-S nanoclusters. The DFT calculations and STM experiments show that NO does not adsorb at fully sulfided MoS2 edges not containing hydrogen. However, typical sulfided catalysts will have hydrogen present...... NO as a probe molecule to obtain detailed atomic-scale information on hydrotreating catalysts and the origins of activity differences. (C) 2011 Published by Elsevier Inc....

  15. Upgrading of waste oils into transportation fuels using hydrotreating technologies

    Directory of Open Access Journals (Sweden)

    Sudipta De

    2014-12-01

    Full Text Available The generation of organic waste continues to increase, causing severe environmental pollution. Waste valorization is currently an emerging technology that can address this problem with an extra benefit of producing a range of valued products. In this contribution, we report the current developments in hydrotreating technologies for upgrading waste oil fractions into usable transportation fuels. Particular focus is given on the catalysts selection for a general hydroprocessing technique as well as the competitive role of those catalysts in hydrotreating and hydrocracking processes.

  16. Green Diesel from Hydrotreated Vegetable Oil Process Design Study

    NARCIS (Netherlands)

    Hilbers, T.J.; Sprakel, Lisette Maria Johanna; van den Enk, L.B.J.; Zaalberg, B.; van den Berg, Henderikus; van der Ham, Aloysius G.J.

    2015-01-01

    A systematic approach was applied to study the process of hydrotreating vegetable oils. During the three phases of conceptual, detailed, and final design, unit operations were designed and sized. Modeling of the process was performed with UniSim Design®. Producing green diesel and jet fuel from

  17. Enriched-air fluidized bed gasification using bench and pilot scale reactors of dairy manure with sand bedding based on response surface methods

    International Nuclear Information System (INIS)

    Nam, Hyungseok; Maglinao, Amado L.; Capareda, Sergio C.; Rodriguez-Alejandro, David Aaron

    2016-01-01

    Enriched-air gasification was performed in fluidized bed reactors using the processed dairy manure which was mixed with sand bedding. The effects of temperature, modified equivalence ratio (ER_m), and oxygen concentration on the gas products were investigated based on the statistical models using a bench-scale reactor in order to obtain empirical correlations. Then, the empirical equations were applied to compare the produced gases from a pilot-scale fluidized bed gasifier. The empirical and actual H_2 and CH_4 compositions were within a 10% error, while the sum of produced CO and CO_2 gases showed similar composition within 3% error. The most influential factors for the syngas heating value were temperature followed by the oxygen concentration and ER (equivalence ratio). The composition of H_2 (2.1–11.5%) and CO (5.9–20.3%) rose with an increase in temperature and oxygen concentration. The variation of CO_2 (16.8–31.6%) was mainly affected by the degree of oxygen concentration in the gasifying agent. The ranges of the LHV (lower heating value), carbon conversion efficiency and cold gas efficiency were discussed. An economic review showed favorable indications for on-site dairy manure gasification process for electric power based on the depreciable payback period and the power production costs. - Highlights: • Sand mixed dairy manure obtained directly from a dairy farm was processed and used. • Response surface methodology was used to investigate the enriched-air gasification. • Syngas results from bench and pilot scale gasifiers were compared and reviewed. • A highest LVH of 8 MJ/Nm"3 was obtained from the enriched-air gasification. • The power production costs were determined to be $0.053/kWh

  18. Bench-Scale Development of a Hot Carbonate Absorption Process with Crystallization-Enabled High-Pressure Stripping for Post-Combustion CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Yongqi; DeVries, Nicholas; Ruhter, David; Manoranjan, Sahu; Ye, Qing; Ye, Xinhuai; Zhang, Shihan; Chen, Scott; Li, Zhiwei; O' Brien, Kevin

    2014-03-31

    A novel Hot Carbonate Absorption Process with Crystallization-Enabled High-Pressure Stripping (Hot-CAP) has been developed by the University of Illinois at Urbana-Champaign and Carbon Capture Scientific, LLC in this three-year, bench-scale project. The Hot-CAP features a concentrated carbonate solution (e.g., K{sub 2}CO{sub 3}) for CO{sub 2} absorption and a bicarbonate slurry (e.g., KHCO{sub 3}) for high-pressure CO{sub 2} stripping to overcome the energy use and other disadvantages associated with the benchmark monoethanolamine (MEA) process. The project was aimed at performing laboratory- and bench-scale experiments to prove its technical feasibility and generate process engineering and scale-up data, and conducting a techno-economic analysis (TEA) to demonstrate its energy use and cost competitiveness over MEA. To meet project goals and objectives, a combination of experimental, modeling, process simulation, and economic analysis studies were applied. Carefully designed and intensive experiments were conducted to measure thermodynamic and reaction engineering data relevant to four major unit operations in the Hot-CAP (i.e., CO{sub 2} absorption, CO{sub 2} stripping, bicarbonate crystallization, and sulfate reclamation). The rate promoters that could accelerate the CO{sub 2} absorption rate into the potassium carbonate/bicarbonate (PCB) solution to a level greater than that into the 5 M MEA solution were identified, and the superior performance of CO{sub 2} absorption into PCB was demonstrated in a bench-scale packed-bed column. Kinetic data on bicarbonate crystallization were developed and applied for crystallizer design and sizing. Parametric testing of high-pressure CO{sub 2} stripping with concentrated bicarbonate-dominant slurries at high temperatures ({>=}140{degrees}C) in a bench-scale stripping column demonstrated lower heat use than with MEA. The feasibility of a modified process for combining SO{sub 2} removal with CO{sub 2} capture was preliminarily

  19. Hydropyrolysis of sugar cane bagasse: effect of sample configuration on bio-oil yields and structures from two bench-scale reactors

    Energy Technology Data Exchange (ETDEWEB)

    Pindoria, R.V.; Chatzakis, I.N.; Lim, J.-Y.; Herod, A.A.; Dugwell, D.R.; Kandiyoti, R. [Imperial College of Science, Technology and Medicine, London (United Kingdom). Dept. of Chemical Engineering and Chemical Technology

    1999-01-01

    A wire-mesh reactor has been used as base-case in the study of product yields and structures from the pyrolysis and hydropyrolysis of a sample of sugar cane bagasse in a fixed bed `hot-rod` reactor. Results from the two reactors have been compared to determine how best to assess bench-scale data which might be used for eventual process development. Experiments have been carried out at 600{degree}C at pressures up to 70 bar. Structural features of the bio-oils have been examined by size exclusion chromatography and FT-infrared spectroscopy. In both reactors the effect of increasing pressure was to reduce the bio-oil and total volatile yields: hydropyrolysis bio-oil yields were marginally higher than pyrolysis yields under equivalent operating conditions. The data indicate that about one-third of the original biomass may be converted to oil by direct pyrolysis. 33 refs., 10 figs.

  20. Bench-scale testing of on-line control of column flotation using a novel analyzer. Third quarterly technical progress report, April 1, 1993--June 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-24

    This document contains the third quarterly technical progress report for PTI`s Bench-Scale Testing Project of a circuit integrating PTI`s KEN-FLOTETM Column Flotation Technology and PTI`s On-Line Quality Monitor and Control System. The twelve-month project involves installation and testing of a 200--300 lb/hr. bench-scale flotation circuit at PETC`s Coal Preparation Process Research Facility (CPPRF) for two bituminous coals (Upper Freeport and Pittsburgh No. 8 Seam Raw Coals). Figure 1 contains the project plan, as well as the approach to completing the major tasks within the twelve-month project schedule. The project is broken down into three phases, which include: Phase I -- Preparation: The preparation phase was performed principally at PTI`s Calumet offices from October through December, 1992. It involved building of the equipment and circuitry, as well as some preliminary design and equipment testing; Phase II -- ET Circuit Installation and Testing: This installation and testing phase of the project was performed at PETC`s CPPRF from January through June, 1993, and was the major focus of the project. It involved testing of the continuous 200--300 lb/hr. circuit; and Phase III -- Project Finalization: The project finalization phase is occurring from July through September, 1993, at PTI`s Calumet offices and involves finalizing analytical work and data evaluation, as well as final project reporting. This Third Quarterly Technical Progress Report principally summarizes the results from the benchscale testing with the second coal (Pittsburgh No. 8 Seam Coal), which occurred in April through June, 1993. It also contains preliminary economic evaluations that will go into the Final Report, as well as the plan for the final reporting task.

  1. Mapping reactor operating regimes for heavy gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Munteanu, Mugurel Catalin; Chen, Jinwen [CanmetENERGY, Natural Resources Canada (Canada)

    2011-07-01

    Hydrotreating (HDT) is used in oil refineries at temperatures of 350-400 degree C and pressure of 50-100 bars in a fixed bed to improve the quality of distillate fraction. HDT operates as a gas-liquid-solid process, trickle bed. Efforts have been made to model it but volatilization of liquid oil is often ignored. The aim of this paper is to predict vapor-liquid equilibrium (VLE) for a typical heavy distillate feed in pilot plant hydrotreaters. The study was conducted under various operating conditions and a flash calculation program calibrated in-house was used to predict VLE. VLE values were found and results showed that higher pressure, lower gas/oil ratio and temperature should be used to maintain the desired operating regimes when hydrotreating heavy distillate feed. This study determined the operating conditions for maintaining the desired operating regimes and these findings could be useful for operators.

  2. Corrosion resistance of heat exchange equipment in hydrotreating Orenburg Condensate

    International Nuclear Information System (INIS)

    Teslya, B.M.; Burlov, V.V.; Parputs, I.V.; Parputs, T.P.

    1986-01-01

    The authors study the corrosion resistance of materials of construction and select appropriate materials for the fabrication of heat exchange equipment that will be serviceable under hydrotreating conditions. This paper discusses the Orenburg condensate hydrotreating unit which has been shut down repeatedly for repair because of corrosion damage to components of heat exchangers in the reactor section: tube bundles (08Kh18N10T steel), corrugated compensators (12Kh18N10T steel), and pins of the floating heads (37Kh13N8G8MFB steel). The authors recommend that the tube bundles and the compensators in heat exchangers in the reaction section should be fabricated of 08Kh21N6M2T or 10Kh17N13M2T steel. The pins have been replaced by new pins made of 10Kh17N13 X M2T steel, increasing the service life from 6-12 months to 2 years

  3. Upgrading of waste oils into transportation fuels using hydrotreating technologies

    OpenAIRE

    Sudipta De; Rafael Luque

    2014-01-01

    The generation of organic waste continues to increase, causing severe environmental pollution. Waste valorization is currently an emerging technology that can address this problem with an extra benefit of producing a range of valued products. In this contribution, we report the current developments in hydrotreating technologies for upgrading waste oil fractions into usable transportation fuels. Particular focus is given on the catalysts selection for a general hydroprocessing technique as wel...

  4. Catalytic hydrotreating of bio-oil derived from Chlorococcum sp.

    Science.gov (United States)

    Subagyono, R. R. D. J. N.; Marshall, M.; Jackson, W. R.; Chaffee, A. L.

    2018-04-01

    Hydrotreating of bio-oil derived from Chlorococcum sp. in the absence of NiMo/Al-SBA-15 catalysts has been investigated. The silica alumina supports decreased product yields (DCM solubles and hydrocarbon gases) due to severe coking. Incorporation of NiMo increased the product yields to up to 65 wt.% and increased the proportion of products in the kerosene boiling point range (C12-C17).The superiority of the high acidity supports persisted after incorporation of NiMo.

  5. Bench- and pilot-scale demonstration of thermal desorption for removal of mercury from the Lower East Fork Poplar Creek floodplain soils

    International Nuclear Information System (INIS)

    Morris, M.I.; Sams, R.J.; Gillis, G.; Helsel, R.W.; Alperin, E.S.; Geisler, T.J.; Groen, A.; Root, D.

    1995-01-01

    Thermal desorption is an innovative technology that has seen significant growth in applications to organically contaminated soils and sludges for the remediation of hazardous, radioactive and mixed waste sites. This paper will present the results of a bench and pilot-scale demonstration of this technology for the removal of mercury from the Lower East Fork Poplar Creek floodplain soil. Results demonstrate that the mercury in this soil can be successfully removed to the target treatment levels of 10 milligrams per kilogram (mg/kg) and that all process residuals could be rendered RCRA-nonhazardous as defined by the Resource Conservation and Recovery Act. Sampling and analyses of the desorber off-gas before and after the air pollution control system demonstrated effective collection of mercury and organic constituents. Pilot-scale testing was also conducted to verify requirements for material handling of soil into and out of the process. This paper will also present a conceptual design and preliminary costs of a full-scale system, including feed preparation, thermal treatment, and residuals handling for the soil

  6. Correlation between mass transfer coefficient kLa and relevant operating parameters in cylindrical disposable shaken bioreactors on a bench-to-pilot scale.

    Science.gov (United States)

    Klöckner, Wolf; Gacem, Riad; Anderlei, Tibor; Raven, Nicole; Schillberg, Stefan; Lattermann, Clemens; Büchs, Jochen

    2013-12-02

    Among disposable bioreactor systems, cylindrical orbitally shaken bioreactors show important advantages. They provide a well-defined hydrodynamic flow combined with excellent mixing and oxygen transfer for mammalian and plant cell cultivations. Since there is no known universal correlation between the volumetric mass transfer coefficient for oxygen kLa and relevant operating parameters in such bioreactor systems, the aim of this current study is to experimentally determine a universal kLa correlation. A Respiration Activity Monitoring System (RAMOS) was used to measure kLa values in cylindrical disposable shaken bioreactors and Buckingham's π-Theorem was applied to define a dimensionless equation for kLa. In this way, a scale- and volume-independent kLa correlation was developed and validated in bioreactors with volumes from 2 L to 200 L. The final correlation was used to calculate cultivation parameters at different scales to allow a sufficient oxygen supply of tobacco BY-2 cell suspension cultures. The resulting equation can be universally applied to calculate the mass transfer coefficient for any of seven relevant cultivation parameters such as the reactor diameter, the shaking frequency, the filling volume, the viscosity, the oxygen diffusion coefficient, the gravitational acceleration or the shaking diameter within an accuracy range of +/- 30%. To our knowledge, this is the first kLa correlation that has been defined and validated for the cited bioreactor system on a bench-to-pilot scale.

  7. DESTRUCTION OF TETRAPHENYLBORATE IN TANK 48H USING WET AIR OXIDATION BATCH BENCH SCALE AUTOCLAVE TESTING WITH ACTUAL RADIOACTIVE TANK 48H WASTE

    Energy Technology Data Exchange (ETDEWEB)

    Adu-Wusu, K; Paul Burket, P

    2009-03-31

    Wet Air Oxidation (WAO) is one of the two technologies being considered for the destruction of Tetraphenylborate (TPB) in Tank 48H. Batch bench-scale autoclave testing with radioactive (actual) Tank 48H waste is among the tests required in the WAO Technology Maturation Plan. The goal of the autoclave testing is to validate that the simulant being used for extensive WAO vendor testing adequately represents the Tank 48H waste. The test objective was to demonstrate comparable test results when running simulated waste and real waste under similar test conditions. Specifically: (1) Confirm the TPB destruction efficiency and rate (same reaction times) obtained from comparable simulant tests, (2) Determine the destruction efficiency of other organics including biphenyl, (3) Identify and quantify the reaction byproducts, and (4) Determine off-gas composition. Batch bench-scale stirred autoclave tests were conducted with simulated and actual Tank 48H wastes at SRNL. Experimental conditions were chosen based on continuous-flow pilot-scale simulant testing performed at Siemens Water Technologies Corporation (SWT) in Rothschild, Wisconsin. The following items were demonstrated as a result of this testing. (1) Tetraphenylborate was destroyed to below detection limits during the 1-hour reaction time at 280 C. Destruction efficiency of TPB was > 99.997%. (2) Other organics (TPB associated compounds), except biphenyl, were destroyed to below their respective detection limits. Biphenyl was partially destroyed in the process, mainly due to its propensity to reside in the vapor phase during the WAO reaction. Biphenyl is expected to be removed in the gas phase during the actual process, which is a continuous-flow system. (3) Reaction byproducts, remnants of MST, and the PUREX sludge, were characterized in this work. Radioactive species, such as Pu, Sr-90 and Cs-137 were quantified in the filtrate and slurry samples. Notably, Cs-137, boron and potassium were shown as soluble as a

  8. Toxic Combustion Product Yields as a Function of Equivalence Ratio and Flame Retardants in Under-Ventilated Fires: Bench-Large-Scale Comparisons

    Directory of Open Access Journals (Sweden)

    David A. Purser

    2016-09-01

    Full Text Available In large-scale compartment fires; combustion product yields vary with combustion conditions mainly in relation to the fuel:air equivalence ratio (Φ and the effects of gas-phase flame retardants. Yields of products of inefficient combustion; including the major toxic products CO; HCN and organic irritants; increase considerably as combustion changes from well-ventilated (Φ < 1 to under-ventilated (Φ = 1–3. It is therefore essential that bench-scale toxicity tests reproduce this behaviour across the Φ range. Yield data from repeat compartment fire tests for any specific fuel show some variation on either side of a best-fit curve for CO yield as a function of Φ. In order to quantify the extent to which data from the steady state tube furnace (SSTF [1]; ISO TS19700 [2] represents compartment fire yields; the range and average deviations of SSTF data for CO yields from the compartment fire best-fit curve were compared to those for direct compartment fire measurements for six different polymeric fuels with textile and non-textile applications and for generic post-flashover fire CO yield data. The average yields; range and standard deviations of the SSTF data around the best-fit compartment fire curves were found to be close to those for the compartment fire data. It is concluded that SSTF data are as good a predictor of compartment fire yields as are repeat compartment fire test data.

  9. Cesium Removal From Tanks 241-AN-103 and 241-SX-105 and 241-AZ-101 and 241-AZ-102 Composite For Testing In Bench Scale Steam Reformer

    International Nuclear Information System (INIS)

    Duncan, J.B.; Huber, H.J.

    2011-01-01

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using

  10. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN JB; HUBER HJ

    2011-04-21

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using

  11. Characterization of L-asparaginase from marine-derived Aspergillus niger AKV-MKBU, its antiproliferative activity and bench scale production using industrial waste.

    Science.gov (United States)

    Vala, Anjana K; Sachaniya, Bhumi; Dudhagara, Dushyant; Panseriya, Haresh Z; Gosai, Haren; Rawal, Rakesh; Dave, Bharti P

    2018-03-01

    L-asparaginase (LA), an enzyme with anticancer activities, produced by marine-derived Aspergillus niger was subjected to purification and characterization. The purified enzyme was observed to have molecular weight ∼90KDa. The enzyme retained activity over a wide range of pH, i.e. pH 4-10. The enzyme was quite stable in temperature range 20-40°C. Tween 80 and Triton X-100 were observed to enhance LA activity while inhibition of LA activity was observed in presence of heavy metals. The values for K m was found to be 0.8141 mM and V max was 6.228μM/mg/min. The enzyme exhibited noteworthy antiproliferative activity against various cancer cell lines tested. Successful bench scale production (in 5L bioreacator) of LA using groundnut oil cake as low cost substrate has also been carried out. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Flexible Bench-Scale Recirculating Flow CPC Photoreactor for Solar Photocatalytic Degradation of Methylene Blue Using Removable TiO2 Immobilized on PET Sheets

    Directory of Open Access Journals (Sweden)

    Doaa M. EL-Mekkawi

    2016-01-01

    Full Text Available TiO2 immobilized on polyethylene (PET nonwoven sheet was used in the solar photocatalytic degradation of methylene blue (MB. TiO2 Evonik Aeroxide P25 was used in this study. The amount of loaded TiO2 on PET was approximately 24%. Immobilization of TiO2 on PET was conducted by dip coating process followed by exposing to mild heat and pressure. TiO2/PET sheets were wrapped on removable Teflon rods inside home-made bench-scale recirculating flow Compound Parabolic Concentrator (CPC photoreactor prototype (platform 0.7 × 0.2 × 0.4 m3. CPC photoreactor is made up of seven low iron borosilicate glass tubes connected in series. CPC reflectors are made of stainless steel 304. The prototype was mounted on a platform tilted at 30°N local latitude in Cairo. A centrifugal pump was used to circulate water containing methylene blue (MB dye inside the glass tubes. Efficient photocatalytic degradation of MB using TiO2/PET was achieved upon the exposure to direct sunlight. Chemical oxygen demand (COD analyses reveal the complete mineralization of MB. Durability of TiO2/PET composite was also tested under sunlight irradiation. Results indicate only 6% reduction in the amount of TiO2 after seven cycles. No significant change was observed for the physicochemical characteristics of TiO2/PET after the successive irradiation processes.

  13. Bench Scale Process for Low Cost CO2 Capture Using a Phase-Changing Absorbent: Topical Report EH&S Risk Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Westendorf, Tiffany; Farnum, Rachel; Perry, Robert; Herwig, Mark; Giolando, Salvatore; Green, Dianne; Morall, Donna

    2016-05-11

    GE Global Research was contracted by the Department of Energy to design and build a bench-scale process for a novel phase-changing aminosilicone-based CO2 capture solvent (award number DEFE0013687). As part of this program, a technology EH&S assessment (Subtask 5.1) has been completed for a CO2 capture system for a 550 MW coal-fired power plant. The assessment focuses on two chemicals used in the process, the aminosilicone solvent, GAP-0, and dodecylbenzenesulfonic acid (DDBSA), the GAP-0 carbamate formed upon reaction of the GAP-0 with CO2, and two potential byproducts formed in the process, GAP-0/SOx salts and amine-terminated, urea-containing silicone (also referred to as “ureas” in this report). The EH&S assessment identifies and estimates the magnitude of the potential air and water emissions and solid waste generated by the process and reviews the toxicological profiles of the chemicals associated with the process. Details regarding regulatory requirements, engineering controls, and storage and handling procedures are also provided in the following sections.

  14. Bench scale model studies on sanitary landfill leachate treatment with M. oleifera seed extract and hollow fibre micro-filtration membrane

    Directory of Open Access Journals (Sweden)

    S. A. Muyibi

    2002-10-01

    Full Text Available A laboratory-based study using a Bench Scale model of four unit operations made up of coagulation (using Moringa oleifera seed extract as a coagulant, flocculation, sedimentation and micro-filtration, have been adopted to treat the leachate from Air Hitman Sanitary Landfill at Puchong in Malaysia. M. oleifera dosages of 150 and 175 mg/L had achieved 43.8% Cadmium removal, 21.2% Total Chromium removal, 66.8% Lead removal and 16% Iron removal. It also removed 55.4% of Total Suspended Solids, 10% of Total Dissolved Solids and 24.2% of Volatile Suspended Solids. Micro-filtration hollow fibre membrane decreased the turbidity, total suspended solids, total dissolved solids, volatile suspended solids, and organic matter in the leachate by 98.3%, 96.7%, 20.8%, 36.6% and 21.9% respectively. Overall heavy metals removal after micro-filtration using hollow fibre membrane was 94% for Cadmium, 29.8% for Total Chromium, 73.2% for Lead, and 18.3% for Iron. The results have shown that M. oleifera is a promising natural polymer for removing heavy metals from leachates and may be used as a pre-treatment to eliminate a portion of the toxic heavy metals, which limits the activity of micro organisms in the leachates.

  15. From biomass to fuels: Hydrotreating of oxygenated compounds

    Energy Technology Data Exchange (ETDEWEB)

    Gandarias, I.; Barrio, V.L.; Requies, J.; Arias, P.L.; Cambra, J.F.; Gueemez, M.B. [School of Engineering (UPV/EHU), c/ Alameda Urquijo s/n, 48013 Bilbao (Spain)

    2008-07-15

    Biomass is a renewable alternative to fossil raw materials in the production of liquid fuels and chemicals. Pyrolyzed biomass derived liquids contain oxygenated molecules that need to be removed to improve the stability of these liquids. A hydrotreating process, hydrodeoxygenation (HDO), is commonly used for this purpose. Thus, the aim of this work is to examine the role of advanced NiMo and NiW catalysts developed for HDS purposes in a HDO reaction. In addition, product distribution and catalyst stability are studied against changes in the feed composition, the solvent, and the catalyst pretreatment. (author)

  16. Deep hydrotreating of middle distillates from crude and shale oils

    Energy Technology Data Exchange (ETDEWEB)

    Landau, M.V. [The Blechner Center for Industrial Catalysis and Process Development, Ben-Gurion University of the Negev, Beer-Sheva (Israel)

    1997-06-20

    The potential scientific and technological solutions to the problems that appear as a result of shifting the hydrotreating of crude oil middle distillates and shale oils from the `normal` to the `deep` mode are considered on the basis of the reactivities and transformation routes of the least-reactive sulfur-, nitrogen-, and oxygen-containing compounds. The efficiency of selecting the optimal feedstock, increasing the process severity, improving the catalysts activity, and using alternative catalytic routes are compared, taking into account the specific issues related to deep hydrodesulfurization/hydrodenitrogenation/hydrodeoxygenation, i.e., chemical aspects, kinetics and catalysts

  17. Model Feed for Hydrotreating of Fat for Biodiesel Production

    DEFF Research Database (Denmark)

    Biodiesel production by the transesterification of oils and fats with an alcohol to fatty acid alkyl esters is rapidly increasing worldwide. Plant oils are usually suited for transesterification, but feedstocks from waste products like trap greases and abattoir wastes are difficult to react due...... resulted in lower conversions and a much higher degree of hydrogenation than with the Pt catalyst. This protocol represents a facile method of studying hydrotreating of waste fats and oils for biodiesel production, which may be a viable alternative to current dominating transesterification technology. 1...

  18. Hydrogen production with short contact time. Catalytic partial oxidation of hydrocarbons and oxygenated compounds: Recent advances in pilot- and bench-scale testing and process design

    Energy Technology Data Exchange (ETDEWEB)

    Guarinoni, A.; Ponzo, R.; Basini, L. [ENI Refining and Marketing Div., San Donato Milanese (Italy)

    2010-12-30

    ENI R and D has been active for fifteen years in the development of Short Contact Time - Catalytic Partial Oxidation (SCT-CPO) technologies for producing Hydrogen/Synthesis Gas. From the beginning the experimental work addressed either at defining the fundamental principles or the technical and economical potential of the technology. Good experimental responses, technical solutions' simplicity and flexibility, favourable techno-economical evaluations promoted the progressive widening of the field of the investigations. From Natural Gas (NG) the range of ''processable'' Hydrocarbons extended to Liquefied Petroleum Gas (LPG) and Gasoils, including those characterised by high levels of unsaturated and sulphurated molecules and, lately, to other compounds with biological origin. The extensive work led to the definition of different technological solutions, grouped as follows: Technology 1: Air Blown SCT-CPO of Gaseous Hydrocarbons and/or Light Compounds with biological origin Technology 2: Enriched Air/Oxygen Blown SCT-CPO of Gaseous Hydrocarbons and/or Light Compounds with biological origin Technology 3: Enriched Air/Oxygen Blown SCT-CPO of Liquid Hydrocarbons and/or Compounds with biological origin Recently, the licence rights on a non-exclusive basis for the commercialisation of SCT-CPO based processes for H{sub 2}/Synthesis gas production from light hydrocarbons with production capacity lower than 5,000 Nm{sup 3}/h of H{sub 2} or 7,500 Nm3/h of syngas have been assigned to two external companies. In parallel, development of medium- and large-scale plant solutions is progressing within the ENI group framework. These last activities are addressed to the utilisation of SCT-CPO for matching the variable Hydrogen demand in several contexts of oil refining operation. This paper will report on the current status of SCT-CPO with a focus on experimental results obtained, either at pilot- and bench- scale level. (orig.)

  19. CFD modeling of space-time evolution of fast pyrolysis products in a bench-scale fluidized-bed reactor

    International Nuclear Information System (INIS)

    Boateng, A.A.; Mtui, P.L.

    2012-01-01

    A model for the evolution of pyrolysis products in a fluidized bed has been developed. In this study the unsteady constitutive transport equations for inert gas flow and decomposition kinetics were modeled using the commercial computational fluid dynamics (CFD) software FLUENT-12. The Eulerarian-Eulerian multiphase model system described herein is a fluidized bed of sand externally heated to a predetermined temperature prior to introduction of agricultural biomass. We predict the spontaneous emergence of pyrolysis vapors, char and non-condensable (permanent) gases and confirm the observation that the kinetics are fast and that bio-oil vapor evolution is accomplished in a few seconds, and occupying two-thirds of the spatial volume of the reactor as widely reported in the open literature. The model could be advantageous in the virtual design of fast pyrolysis reactors and their optimization to meet economic scales required for distributed or satellite units. - Highlights: ► We model the evolution of pyrolysis products in a fluidized bed via CFD. ► We predict the spontaneous emergence of pyrolysis products. ► We confirm the experimental observation that the kinetics are fast. ► And that bio-oil vapor evolution is accomplished in a few seconds. ► The model is advantageous in the virtual design of fast pyrolysis reactors.

  20. Study On Hydrotreating Of -Coker Distillate(S)

    International Nuclear Information System (INIS)

    Menoufy, M.F.; Abdel- Aleim, G.M.; Ebrahim, M.S.; Abdel-Aaty, M.

    2004-01-01

    The primary method to remove sulfur , improve cetane index and reduce aromatic content of gas oil I diesel is hydro processing. Therefore, the significant advancements in hydro treating of light coker gas oil (LCGO) derived from delayed coker unit at Suez Oil Processing Company have been performed in a cata-test fixed bed micro-reactor unit, using a commercial CoMo/ Al 2 O 3 Catalyst after sulfidation. The operating conditions were varied in order to study the impact of these processes conditions (temperature 275-400 degree C, hydrogen pressure 30-85 bar, and hourly space velocity 0.5-1.5 h -1 ) on the yield , and quality of gas oil within hydrotreating regime, which is the important to aid the optimization of the process from the environmental regulations and national market demands point of view. The present investigation is conducted on the LCGO, which was selected as a hydrotreated feedstock due to its higher unsaturated hydrocarbon contents ( aromatics and olefins) and hetero atom (sulfur and nitrogen), in order to produce an upgraded gas oil acceptable as transportation fuel according to the environmental and national regulation, and /or the world wide fuel charter december 2002

  1. Effects of catalytic hydrotreating on light cycle oil fuel quality

    International Nuclear Information System (INIS)

    Anabtawi, J.A.; Ali, S.A.

    1991-01-01

    This paper reports on a pilot plant study that was conducted to evaluate three commercial catalysts for hydrotreating of light cycle oil to reduce its aromatic content and improve the cetane index. The operating parameters were varied between 325 and 400 degrees C, 1 and 3 h - 1 , and 4 and 10 MPa at 535 L/L. The data showed that, in general, the product density and aromatic content decreased as the temperature or pressure increased or space velocity decreased. The cetane index improvement ranged from 7.3 to 10.0 for the Ni-W/Al 2 O 3 catalyst and from 6.1 to 10.1 for the Ni-Mo/Al 2 O 3 catalysts. The catalyst performance was evaluated in terms of hydrodesulfurization, hydrodenitrogenation, hydrogenation, aromatic saturation, and hydrogen consumption. This study confirms that light cycle oil can be hydrotreated to improve its cetane quality, thus increasing the extent of its blending ratio into the diesel pool

  2. A bench-scale study on the removal and recovery of phosphate by hydrous zirconia-coated magnetite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhe; Fang, Wenkan; Xing, Mingchao; Wu, Deyi, E-mail: dywu@sjtu.edu.cn

    2017-02-15

    Owing to the easy magnetic separation from water for reuse, magnetic nanoparticles have drawn great interest as adsorbents. Herein hydrous zirconia-coated magnetite nanoparticles (Fe{sub 3}O{sub 4}@ZrO{sub 2}) were created by a facile method and a bench–scale study was undertaken to evaluate its effectiveness and mechanism to remove phosphate at low concentrations. Results indicated that phosphate removal by Fe{sub 3}O{sub 4}@ZrO{sub 2} was fast (95% of phosphate removal within 10 min) and nearly complete removal could be achieved at the adsorbent dosage >0.6 g/L. In tap water or wastewater where competitive anions coexist, regulation of pH was found to be quite effective to augment the performance of phosphate removal. In pH–lowered adsorption systems, phosphate removal followed a good pattern similarly to pure water, i.e., a continuous high efficiency removal followed by a rapid saturation. Adsorption–desorption–regeneration studies showed that Fe{sub 3}O{sub 4}@ZrO{sub 2} could be repeatedly used for phosphate removal and adsorbed phosphate could be stripped for recovery. The fractionation of adsorbed phosphorus suggested that NaOH-P fraction was dominant. We also found that the adsorption reaction of phosphate with Fe{sub 3}O{sub 4}@ZrO{sub 2} shifted the isoelectric point of Fe{sub 3}O{sub 4}@ZrO{sub 2} from ~9.0 to ~3.0. FTIR measurements further showed the direct coordination of phosphate onto zirconium by replacement of hydroxyl groups. The formation of the monodentate (ZrO)PO{sub 2}(OH) complex was proposed. - Highlights: • Hydrous zirconia–coated magnetite was used for phosphate capture. • Regulation of pH was able to enhance P removal in the presence of coexisting ions. • Phosphate was coordinated onto zirconium by replacement of hydroxyl groups. • The material could be easily separated from water for reuse by a magnet. • Desorption of phosphate from the material could be achieved with NaOH treatment.

  3. Radioactive Bench-scale Steam Reformer Demonstration of a Monolithic Steam Reformed Mineralized Waste Form for Hanford Waste Treatment Plant Secondary Waste - 12306

    Energy Technology Data Exchange (ETDEWEB)

    Evans, Brent; Olson, Arlin; Mason, J. Bradley; Ryan, Kevin [THOR Treatment Technologies, LLC - 106 Newberry St. SW, Aiken, SC 29801 (United States); Jantzen, Carol; Crawford, Charles [Savannah River Nuclear Solutions (SRNL), LLC, Aiken, SC 29808 (United States)

    2012-07-01

    Hanford currently has 212,000 m{sup 3} (56 million gallons) of highly radioactive mixed waste stored in the Hanford tank farm. This waste will be processed to produce both high-level and low-level activity fractions, both of which are to be vitrified. Supplemental treatment options have been under evaluation for treating portions of the low-activity waste, as well as the liquid secondary waste from the low-activity waste vitrification process. One technology under consideration has been the THOR{sup R} fluidized bed steam reforming process offered by THOR Treatment Technologies, LLC (TTT). As a follow-on effort to TTT's 2008 pilot plant FBSR non-radioactive demonstration for treating low-activity waste and waste treatment plant secondary waste, TTT, in conjunction with Savannah River National Laboratory, has completed a bench scale evaluation of this same technology on a chemically adjusted radioactive surrogate of Hanford's waste treatment plant secondary waste stream. This test generated a granular product that was subsequently formed into monoliths, using a geo-polymer as the binding agent, that were subjected to compressibility testing, the Product Consistency Test and other leachability tests, and chemical composition analyses. This testing has demonstrated that the mineralized waste form, produced by co-processing waste with kaolin clay using the TTT process, is as durable as low-activity waste glass. Testing has shown the resulting monolith waste form is durable, leach resistant, and chemically stable, and has the added benefit of capturing and retaining the majority of Tc-99, I-129, and other target species at high levels. (authors)

  4. Studies on catalytic hydrotreating of recycled solvents from coal liquefaction process. Part 1. Characteristics changes of recycled solvents during hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Morimura, Y.; Nakata, S.; Yokota, Y.; Shirota, Y.; Nakamura, M. [Chiyoda Corp., Tokyo (Japan); Mitarai, Y. [Sumitomo Metal Mining Co. Ltd., Tokyo (Japan); Inoue, Y. [Nippon Ketjen Co. Ltd., Tokyo (Japan)

    1995-07-01

    A bituminous coal liquefaction process, called the NEDOL process, is under development by the New Energy and Industrial Technology Development Organization (NEDO). Important features of this process include the capacity to produce hydrogen-donatable solvents, obtained by hydrogenation of middle distillates of coal derived oils, and to recycle these solvents to a liquefaction stage as hydrogen donor solvents. These recycled solvents, obtained by liquefaction of Wandoan coal, and their catalytic hydrotreated oils, have been extensively characterized, using a variety of analytical methods. The following items have been examined and are discussed in this study: (1) Influence of chemical hydrogen consumption on the reactivities of hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodeoxygenation (HDO) and hydrogenation of aromatic-rings, during hydrotreating; (2) Changes in composition of hydrocarbon types, nitrogen- and oxygen-containing compounds, as a function of chemical hydrogen consumption; (3) Changes of average molecular weights; (4) Characteristics changes of oxygen- and nitrogen-containing compounds, and reactivities of HDO and HDN; (5) Characteristics changes of donatable hydrogen as a function of a degree of hydrogenation ({delta}fa). 14 refs., 14 figs., 3 tabs.

  5. In-situ subaqueous capping of mercury-contaminated sediments in a fresh-water aquatic system, Part I—Bench-scale microcosm study to assess methylmercury production

    International Nuclear Information System (INIS)

    Randall, Paul M.; Fimmen, Ryan; Lal, Vivek; Darlington, Ramona

    2013-01-01

    Bench-scale microcosm experiments were designed to provide a better understanding of the potential for Hg methylation in sediments from an aquatic environment. Experiments were conducted to examine the function of sulfate concentration, lactate concentration, the presence/absence of an aqueous inorganic Hg spike, and the presence/absence of inoculums of Desulfovibrio desulfuricans, a strain of sulfate-reducing bacteria (SRB) commonly found in the natural sediments of aquatic environments. Incubations were analyzed for both the rate and extent of (methylmercury) MeHg production. Methylation rates were estimated by analyzing MeHg and Hg after 2, 7, 14, 28, and 42 days. The production of metabolic byproducts, including dissolved gases as a proxy for metabolic utilization of carbon substrate, was also monitored. In all treatments amended with lactate, sulfate, Hg, and SRB, MeHg was produced (37 ng/g-sediment dry weight) after only 48 h of incubation and reached a maximum sediment concentration of 127 ng/g-sediment dry weight after the 42 day incubation period. Aqueous phase production of MeHg was observed to be 10 ng/L after 2 day, reaching a maximum observed concentration of 32.8 ng/L after 14 days, and declining to 10.8 ng/L at the end of the incubation period (42 day). The results of this study further demonstrates that, in the presence of an organic carbon substrate, sulfate, and the appropriate consortia of microorganisms, sedimentary Hg will be transformed into MeHg through bacterial metabolism. Further, this study provided the basis for evaluation of an in-situ subaqueous capping strategy that may limit (or potentially enhance) MeHg production. -- Highlights: • Hg methylation by SRB is limited by the depletion of sulfate and carbon. • Hg methylation is sensitive to competition by methanogens for carbon substrate. • In high lactate environment, all lactate was utilized in the microcosms within seven days. • In the absence of adequate metabolic fuel, Me

  6. In-situ subaqueous capping of mercury-contaminated sediments in a fresh-water aquatic system, Part I—Bench-scale microcosm study to assess methylmercury production

    Energy Technology Data Exchange (ETDEWEB)

    Randall, Paul M., E-mail: randall.paul@epa.gov [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 W. Martin Luther King Drive, Cincinnati, OH 45268 (United States); Fimmen, Ryan [Geosyntec Consultants, 150 E. Wilson Bridge Road, Suite 232, Worthington, OH 43085 (United States); Lal, Vivek; Darlington, Ramona [Battelle, 505 King Ave., Columbus, OH 43201 (United States)

    2013-08-15

    Bench-scale microcosm experiments were designed to provide a better understanding of the potential for Hg methylation in sediments from an aquatic environment. Experiments were conducted to examine the function of sulfate concentration, lactate concentration, the presence/absence of an aqueous inorganic Hg spike, and the presence/absence of inoculums of Desulfovibrio desulfuricans, a strain of sulfate-reducing bacteria (SRB) commonly found in the natural sediments of aquatic environments. Incubations were analyzed for both the rate and extent of (methylmercury) MeHg production. Methylation rates were estimated by analyzing MeHg and Hg after 2, 7, 14, 28, and 42 days. The production of metabolic byproducts, including dissolved gases as a proxy for metabolic utilization of carbon substrate, was also monitored. In all treatments amended with lactate, sulfate, Hg, and SRB, MeHg was produced (37 ng/g-sediment dry weight) after only 48 h of incubation and reached a maximum sediment concentration of 127 ng/g-sediment dry weight after the 42 day incubation period. Aqueous phase production of MeHg was observed to be 10 ng/L after 2 day, reaching a maximum observed concentration of 32.8 ng/L after 14 days, and declining to 10.8 ng/L at the end of the incubation period (42 day). The results of this study further demonstrates that, in the presence of an organic carbon substrate, sulfate, and the appropriate consortia of microorganisms, sedimentary Hg will be transformed into MeHg through bacterial metabolism. Further, this study provided the basis for evaluation of an in-situ subaqueous capping strategy that may limit (or potentially enhance) MeHg production. -- Highlights: • Hg methylation by SRB is limited by the depletion of sulfate and carbon. • Hg methylation is sensitive to competition by methanogens for carbon substrate. • In high lactate environment, all lactate was utilized in the microcosms within seven days. • In the absence of adequate metabolic fuel, Me

  7. Bench-scale Development of an Advanced Solid Sorbent-based CO2 Capture Process for Coal-fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Thomas [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Kataria, Atish [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Soukri, Mustapha [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Farmer, Justin [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Mobley, Paul [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Tanthana, Jak [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Dongxiang [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Wang, Xiaoxing [Research Triangle Institute (RTI), Research Triangle Park, NC (United States); Song, Chunshan [Research Triangle Institute (RTI), Research Triangle Park, NC (United States)

    2015-12-31

    It is increasingly clear that CO2 capture and sequestration (CCS) must play a critical role in curbing worldwide CO2 emissions to the atmosphere. Development of these technologies to cost-effectively remove CO2 from coal-fired power plants is very important to mitigating the impact these power plants have within the world’s power generation portfolio. Currently, conventional CO2 capture technologies, such as aqueous-monoethanolamine based solvent systems, are prohibitively expensive and if implemented could result in a 75 to 100% increase in the cost of electricity for consumers worldwide. Solid sorbent CO2 capture processes – such as RTI’s Advanced Solid Sorbent CO2, Capture Process – are promising alternatives to conventional, liquid solvents. Supported amine sorbents – of the nature RTI has developed – are particularly attractive due to their high CO2 loadings, low heat capacities, reduced corrosivity/volatility and the potential to reduce the regeneration energy needed to carry out CO2 capture. Previous work in this area has failed to adequately address various technology challenges such as sorbent stability and regenerability, sorbent scale-up, improved physical strength and attrition-resistance, proper heat management and temperature control, proper solids handling and circulation control, as well as the proper coupling of process engineering advancements that are tailored for a promising sorbent technology. The remaining challenges for these sorbent processes have provided the framework for the project team’s research and development and target for advancing the technology beyond lab- and bench-scale testing. Under a cooperative agreement with the US Department of Energy, and part of NETL’s CO2 Capture Program, RTI has led an effort to address and mitigate the challenges associated with solid sorbent CO2 capture. The overall objective

  8. Catalytic hydrotreating of lignin with water-soluble molybdenum catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Osmaa, A.; Johansson, A. (Technical Research Centre of Finland, Espoo (Finland). Lab. of Fuel and Process Technology)

    High yields (61% of the original lignin) of low molecular weight oil (84% of the oil eluted through GC) have been obtained by hydrotreating kraft pine lignin with a water-soluble molybdenum catalyst at 430[degree]C for 60 min. The main compounds in the product oil were phenols (8.7% of the original lignin), cyclohexanes (5.0%), benzenes (3.8%), naphthalenes (4.0%), and phenanthrenes (1.2%). The degree of hydrodeoxygenation was 98%. The quality (measured by GPC and GC) of the product was as good as when using more expensive solid NiMo-CR[sub 2]O[sub 3] catalysts. 30 refs., 6 tabs.

  9. Catalytic hydrotreating of waste cooking oil for renewable diesel production

    Energy Technology Data Exchange (ETDEWEB)

    Bezergianni, Stella; Dimitriadis, Athanasios [Centre for Research and Technology Hellas (CERTH), Thessaloniki (Greece)

    2013-06-01

    A new technology based on catalytic hydrotreating of Waste Cooking Oil (WCO) for biodiesel production has been developed in the Centre for Research and Technology Hellas (CERTH). The main premise of this process is the conversion of the WCO fatty acids into normal- and iso-paraffins. The technology was evaluated in hydroprocessing pilot plants of CERTH where feedstock origin as well as optimal catalysts and operating parameters where identified. The fractionated diesel product, called ''white'' diesel exhibits excellent fuel properties including higher heating value (over 49 MJ/kg), negligible acidity, higher oxidation stability and higher cetane number ({proportional_to}77) than conventional biodiesel. The overall product yield is {proportional_to}92% v/v. This new suggested technology is extremely appealing as it employs existing refinery infrastructure and expertise, offers feedstock flexibility, leaves no by-product and above all is economically attractive. (orig.)

  10. Upgrading of coker distillate under variable hydrotreating operating conditions

    Directory of Open Access Journals (Sweden)

    H.A. Elsayed

    2011-06-01

    Full Text Available Studies on hydrotreating coker distillates, produced from a delayed coker unit were done using a commercially available CoMo/γ-Al2O3 catalyst, on which 0.2 wt% P2O5 was added in order to improve its characteristics. The experimental studies were conducted in a fixed-bed continuous-reactor (cata-test unit at temperatures (300–400 °C and total hydrogen pressure (40–65 bar. These conditions have affected the feedstock characteristics and great reduction of sulfur, aromatics and boiling ranges. Other improvements were obtained in diesel index (DI due to hydrogenation reaction of aromatics and desulfurization of its sulfur contents.

  11. JV TASK 45-MERCURY CONTROL TECHNOLOGIES FOR ELECTRIC UTILITIES BURNING LIGNITE COAL, PHASE I BENCH-AND PILOT-SCALE TESTING

    Energy Technology Data Exchange (ETDEWEB)

    John H. Pavlish; Michael J. Holmes; Steven A. Benson; Charlene R. Crocker; Edwin S. Olson; Kevin C. Galbreath; Ye Zhuang; Brandon M. Pavlish

    2003-10-01

    The Energy & Environmental Research Center has completed the first phase of a 3-year, two-phase consortium project to develop and demonstrate mercury control technologies for utilities that burn lignite coal. The overall project goal is to maintain the viability of lignite-based energy production by providing utilities with low-cost options for meeting future mercury regulations. Phase I objectives are to develop a better understanding of mercury interactions with flue gas constituents, test a range of sorbent-based technologies targeted at removing elemental mercury (Hg{sup o}) from flue gases, and demonstrate the effectiveness of the most promising technologies at the pilot scale. The Phase II objectives are to demonstrate and quantify sorbent technology effectiveness, performance, and cost at a sponsor-owned and operated power plant. Phase I results are presented in this report along with a brief overview of the Phase II plans. Bench-scale testing provided information on mercury interactions with flue gas constituents and relative performances of the various sorbents. Activated carbons were prepared from relatively high-sodium lignites by carbonization at 400 C (752 F), followed by steam activation at 750 C (1382 F) and 800 C (1472 F). Luscar char was also steam-activated at these conditions. These lignite-based activated carbons, along with commercially available DARCO FGD and an oxidized calcium silicate, were tested in a thin-film, fixed-bed, bench-scale reactor using a simulated lignitic flue gas consisting of 10 {micro}g/Nm{sup 3} Hg{sup 0}, 6% O{sub 2}, 12% CO{sub 2}, 15% H{sub 2}O, 580 ppm SO{sub 2}, 120 ppm NO, 6 ppm NO{sub 2}, and 1 ppm HCl in N{sub 2}. All of the lignite-based activated (750 C, 1382 F) carbons required a 30-45-minute conditioning period in the simulated lignite flue gas before they exhibited good mercury sorption capacities. The unactivated Luscar char and oxidized calcium silicate were ineffective in capturing mercury. Lignite

  12. Bench Scale Process for Low Cost CO2 Capture Using a PhaseChanging Absorbent: Techno-Economic Analysis Topical Report

    Energy Technology Data Exchange (ETDEWEB)

    Miebach, Barbara [GE Global Research, Niskayuna, New York (United States); McDuffie, Dwayne [GE Global Research, Niskayuna, New York (United States); Spiry, Irina [GE Global Research, Niskayuna, New York (United States); Westendorf, Tiffany [GE Global Research, Niskayuna, New York (United States)

    2017-01-27

    The objective of this project is to design and build a bench-scale process for a novel phase-changing CO2 capture solvent. The project will establish scalability and technical and economic feasibility of using a phase-changing CO2 capture absorbent for post-combustion capture of CO2 from coal-fired power plants with 90% capture efficiency and 95% CO2 purity at a cost of $40/tonne of CO2 captured by 2025 and a cost of <$10/tonne of CO2 captured by 2035. This report presents system and economic analysis for a process that uses a phase changing aminosilicone solvent to remove CO2 from pulverized coal (PC) power plant flue gas. The aminosilicone solvent is a pure 1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane (GAP-0). Performance of the phase-changing aminosilicone technology is compared to that of a conventional carbon capture system using aqueous monoethanolamine (MEA). This analysis demonstrates that the aminosilicone process has significant advantages relative to an MEA-based system. The first-year CO2 removal cost for the phase-changing CO2 capture process is $52.1/tonne, compared to $66.4/tonne for the aqueous amine process. The phase-changing CO2 capture process is less costly than MEA because of advantageous solvent properties that include higher working capacity, lower corrosivity, lower vapor pressure, and lower heat capacity. The phase-changing aminosilicone process has approximately 32% lower equipment capital cost compared to that of the aqueous amine process. However, this solvent is susceptible to thermal degradation at CSTR desorber operating temperatures, which could add as much as $88/tonne to the CO2 capture cost associated with solvent makeup. Future work is focused on mitigating this critical risk by developing an advanced low-temperature desorber that can deliver comparable desorption performance and significantly reduced

  13. The effects of physical separtation treatment on the removal of uranium from contaminated soils at Fernald: A bench-scale study

    International Nuclear Information System (INIS)

    Sadler, K.G.; Krstich, M.A.

    1994-01-01

    A bench-scale treatability study incorporating the use of physical separation techniques and chemical dispersants/extractants was conducted on uranium contaminated soils at the Fernald Environmental Management Project (FEMP) site. The soils contained approximately 497 and 450 milligrams per kilogram (mg/kg) of total uranium, respectively. Geotechnical characterization indicated that 77.4 and 74.6 percent of the soil was in the less that 50 micrometer (μm) size fraction for the ID-A and ID-B soils, respectively. An initial characterization effort indicated that uranium was distributed among all particle size fractions. After each soil was dispersed in water, it was noted that the uranium concentrated in the sand and clay fractions for the ID-A soil (1028 and 1475 mg kg -1 , respectively) and the clay fraction for ID-B soil (2710 mg kg -1 ). Four 1 millimolar (mM) sodium reagent solutions (sodium hydroxide, sodium carbonate, sodium bicarbonate, and a sodium citrate-bicarbonate-dithionite mixture) and potable water were evaluated for effectiveness in dispersing each soil into single grain separates and extracting total uranium from each of the resulting particle size fractions. Dilute sodium solutions were more effective than water in dispersing the soil. The use of dispersants, as compared to water, on the less than 2 mm size fraction causes a shift in the distribution of uranium out of the sand fraction and into the silt and clay fractions for ID-A soil and into the clay fraction for the ID-B soil. Attrition scrubbing tests were conducted on the less than 2 mm size fraction for the ID-A and ID-B soils using water and three alkaline extraction solutions, sodium pyrophosphate, sodium carbonate/bicarbonate, and ammonium carbonate/bicarbonate. There was little difference among the chemical extractants on their effectiveness in removing uranium from the greater than 53 μm (sand) or less than 53 μm (silt and clay) soil fraction

  14. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-25

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using similar methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The "as received" feedstock to the pyrolysis plant will be "reactor ready". This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps: feed

  15. Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Valkenburt, Corinne; Walton, Christie W.; Elliott, Douglas C.; Holladay, Johnathan E.; Stevens, Don J.; Kinchin, Christopher; Czernik, Stefan

    2009-02-28

    The purpose of this study is to evaluate a processing pathway for converting biomass into infrastructure-compatible hydrocarbon biofuels. This design case investigates production of fast pyrolysis oil from biomass and the upgrading of that bio-oil as a means for generating infrastructure-ready renewable gasoline and diesel fuels. This study has been conducted using the same methodology and underlying basis assumptions as the previous design cases for ethanol. The overall concept and specific processing steps were selected because significant data on this approach exists in the public literature. The analysis evaluates technology that has been demonstrated at the laboratory scale or is in early stages of commercialization. The fast pyrolysis of biomass is already at an early stage of commercialization, while upgrading bio-oil to transportation fuels has only been demonstrated in the laboratory and at small engineering development scale. Advanced methods of pyrolysis, which are under development, are not evaluated in this study. These may be the subject of subsequent analysis by OBP. The plant is designed to use 2000 dry metric tons/day of hybrid poplar wood chips to produce 76 million gallons/year of gasoline and diesel. The processing steps include: 1.Feed drying and size reduction 2.Fast pyrolysis to a highly oxygenated liquid product 3.Hydrotreating of the fast pyrolysis oil to a stable hydrocarbon oil with less than 2% oxygen 4.Hydrocracking of the heavy portion of the stable hydrocarbon oil 5.Distillation of the hydrotreated and hydrocracked oil into gasoline and diesel fuel blendstocks 6. Hydrogen production to support the hydrotreater reactors. The “as received” feedstock to the pyrolysis plant will be “reactor ready.” This development will likely further decrease the cost of producing the fuel. An important sensitivity is the possibility of co-locating the plant with an existing refinery. In this case, the plant consists only of the first three steps

  16. Hierarchical calibration and validation framework of bench-scale computational fluid dynamics simulations for solvent-based carbon capture. Part 2: Chemical absorption across a wetted wall column: Original Research Article: Hierarchical calibration and validation framework of bench-scale computational fluid dynamics simulations

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chao [Pacific Northwest National Laboratory, Physical and Computational Sciences Directorate, Richland WA; Xu, Zhijie [Pacific Northwest National Laboratory, Physical and Computational Sciences Directorate, Richland WA; Lai, Kevin [Pacific Northwest National Laboratory, Physical and Computational Sciences Directorate, Richland WA; Whyatt, Greg [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA; Marcy, Peter W. [Los Alamos National Laboratory, Statistical Sciences Group, Los Alamos NM; Sun, Xin [Oak Ridge National Laboratory, Energy and Transportation Science Division, Oak Ridge TN

    2017-10-24

    The first part of this paper (Part 1) presents a numerical model for non-reactive physical mass transfer across a wetted wall column (WWC). In Part 2, we improved the existing computational fluid dynamics (CFD) model to simulate chemical absorption occurring in a WWC as a bench-scale study of solvent-based carbon dioxide (CO2) capture. To generate data for WWC model validation, CO2 mass transfer across a monoethanolamine (MEA) solvent was first measured on a WWC experimental apparatus. The numerical model developed in this work has the ability to account for both chemical absorption and desorption of CO2 in MEA. In addition, the overall mass transfer coefficient predicted using traditional/empirical correlations is conducted and compared with CFD prediction results for both steady and wavy falling films. A Bayesian statistical calibration algorithm is adopted to calibrate the reaction rate constants in chemical absorption/desorption of CO2 across a falling film of MEA. The posterior distributions of the two transport properties, i.e., Henry’s constant and gas diffusivity in the non-reacting nitrous oxide (N2O)/MEA system obtained from Part 1 of this study, serves as priors for the calibration of CO2 reaction rate constants after using the N2O/CO2 analogy method. The calibrated model can be used to predict the CO2 mass transfer in a WWC for a wider range of operating conditions.

  17. Calibration bench of flowmeters

    International Nuclear Information System (INIS)

    Bremond, J.; Da Costa, D.; Calvet, A.; Vieuxmaire, C.

    1966-01-01

    This equipment is devoted to the comparison of signals from two turbines installed in the Cabri experimental loop. The signal is compared to the standard turbine. The characteristics and the performance of the calibration bench are presented. (A.L.B.)

  18. Electron microscopy studies of activation mechanisms in hydrotreating catalysis

    DEFF Research Database (Denmark)

    Dahl-Petersen, Christian

    The aim of this work is to remedy the limited fundamental insight that exists in terms of the activation and formation of hydrotreating catalysts utilized in industrial oil refining of crude oil. This is done through numerous studies of the conversion of industrially relevant molybdenum oxide...... larger amount of formed MoS2. MoS2 forms in one of two conformations of the two-dimensional atomic structure that is either in an orientation parallel or perpendicular to the nanoparticle surface. Both the initial growth of MoS2 and the subsequent formation of multi-layered structures is addressed....... This shows that initial growth tends to form an apparent bond between the MoO2 surface and the MoS2 edge and that the layer size increases through coalescence. For multi-layered structures, it is found that MoS2 layers grow through a layer-under-layer mechanism, where defects in the outer layers enable...

  19. Hierarchical calibration and validation framework of bench-scale computational fluid dynamics simulations for solvent-based carbon capture. Part 2: Chemical absorption across a wetted wall column: Original Research Article: Hierarchical calibration and validation framework of bench-scale computational fluid dynamics simulations

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Chao [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate; Xu, Zhijie [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate; Lai, Kevin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate; Whyatt, Greg [Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate; Marcy, Peter W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sun, Xin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division

    2017-10-24

    Part 1 of this paper presents a numerical model for non-reactive physical mass transfer across a wetted wall column (WWC). In Part 2, we improved the existing computational fluid dynamics (CFD) model to simulate chemical absorption occurring in a WWC as a bench-scale study of solvent-based carbon dioxide (CO2) capture. In this study, to generate data for WWC model validation, CO2 mass transfer across a monoethanolamine (MEA) solvent was first measured on a WWC experimental apparatus. The numerical model developed in this work can account for both chemical absorption and desorption of CO2 in MEA. In addition, the overall mass transfer coefficient predicted using traditional/empirical correlations is conducted and compared with CFD prediction results for both steady and wavy falling films. A Bayesian statistical calibration algorithm is adopted to calibrate the reaction rate constants in chemical absorption/desorption of CO2 across a falling film of MEA. The posterior distributions of the two transport properties, i.e., Henry's constant and gas diffusivity in the non-reacting nitrous oxide (N2O)/MEA system obtained from Part 1 of this study, serves as priors for the calibration of CO2 reaction rate constants after using the N2O/CO2 analogy method. Finally, the calibrated model can be used to predict the CO2 mass transfer in a WWC for a wider range of operating conditions.

  20. Studies on Hydrotreating Process of Microcrystalline Wax Produced from Marine Belayim Crude Oil

    International Nuclear Information System (INIS)

    EI Karashi, S.; Marawan, H.

    2004-01-01

    Abstract Microcrystalline wax was produced from solvent dewaxing process of vacuum residue raffinate produced from Marine Belayim origin. The untreated microcrystalline wax contains trace amounts of sulfur, oxygen, nitrogen and organometallic compounds as well as heavy aromatics which affect the properties of wax applications in pharmaceutical and technical fields . Microcrystalline wax hydrotreating process was studied using digital controlled unit and Ni O-MoO 3 / Al 2 O 3 catalyst, where operating parameters that controlled the efficiency of the hydrotreated wax were studied separately at different values including reactor temperature, reactor pressure, liquid hourly space velocity and hydrogen to hydrocarbon ratio . Hydrotreated microcrystalline wax at operating conditions (temperature 300 degree C, pressure 73 kg/cm 2 , LHS V 0.52 h-l and H 2 /HC ratio 266.6 Nm 3 /m 3 ) has the best quality to be used as food grade wax

  1. Determination of sulfur compounds in hydrotreated transformer base oil by potentiometric titration.

    Science.gov (United States)

    Chao, Qiu; Sheng, Han; Cheng, Xingguo; Ren, Tianhui

    2005-06-01

    A method was developed to analyze the distribution of sulfur compounds in model sulfur compounds by potentiometric titration, and applied to analyze hydrotreated transformer base oil. Model thioethers were oxidized to corresponding sulfoxides by tetrabutylammonium periodate and sodium metaperiodate, respectively, and the sulfoxides were titrated by perchloric acid titrant in acetic anhydride. The contents of aliphatic thioethers and total thioethers were then determined from that of sulfoxides in solution. The method was applied to determine the organic sulfur compounds in hydrotreated transformer base oil.

  2. A Methodology for Reducing Bench Strength in Information Technology Companies

    Directory of Open Access Journals (Sweden)

    Boby John

    2015-07-01

    Full Text Available One of the major risks in information technology (IT project execution is the non-availability of resources with required skill sets to meet the project demands. To mitigate this risk, almost every IT organization maintains a portion of their resources on bench. The bench strength reduces the delay in starting the project due to the non-availability of skilled resources. But bench strength or buffer is cost to the company. A medium scale Indian IT company incurs around USD 142,347 monthly on maintaining the bench strength. Hence this study is undertaken to develop a methodology to reduce the bench strength in IT companies. The proposed methodology is to obtain an optimum mix of resources from bench and through recruitment to meet the demands at a minimum cost. This is done by formulating the problem as an integer programming problem. The problem aims to minimize the total cost of obtaining the skilled resources without violating the constraints on demand, bench strength availability and recruitment lead time. The problem can be solved using Microsoft excel solver function or any other optimization packages like CPLEX, Gurobi, etc. A case study on the application of proposed methodology is also discussed in the paper. The case study showed that the proposed methodology is superior to the existing practice of maintaining large bench strengths to meet the demands for resources with various skills.

  3. Astrophysics on the Lab Bench

    Science.gov (United States)

    Hughes, Stephen W.

    2010-01-01

    In this article some basic laboratory bench experiments are described that are useful for teaching high school students some of the basic principles of stellar astrophysics. For example, in one experiment, students slam a plastic water-filled bottle down onto a bench, ejecting water towards the ceiling, illustrating the physics associated with a…

  4. Characterization of catalytically hydrotreated coal liquid produced by solvolytic liquefaction in petroleum asphalt

    Energy Technology Data Exchange (ETDEWEB)

    Mochida, I.; Oishi, T.; Korai, Y.; Fujitsu, H.; Takeshita, K.

    1983-03-01

    A hydrotreated coal liquid produced by solvolytic liquefaction of a feed originally consisting of 66% petroleum asphalt and 34% coal liquid was characterized. The hydrotreatment was carried out over a Co-Mo catalyst in order to upgrade moderately and selectively the coal-derived fraction. The present process was found very effective to depolymerize rather selectively the coal-derived fraction, originally benzene insoluble, to be soluble in benzene in the dominant presence of petroleum asphalt, while 20% of the asphalt was converted to be distillable with ..cap alpha..-methylnaphthalene (the hydrotreatment solvent). Structural analyses of the fractions before and after hydrotreatment were compared to reveal what kinds of chemical reactions had taken place during hydro treatment. The major reactions of the coal derived fraction are hydrodeoxygenation and hydrodealkylation, both of which are effective for depolymerization. No significant hydrogenation on aromatic rings was observed. Hydrotreated liquid was further pyrolyzed to obtain oils and cokes of high quality. (14 refs.)

  5. Emission and Performance analysis of hydrotreated refined sunflower oil as alternate fuel

    Directory of Open Access Journals (Sweden)

    J. Hemanandh

    2015-09-01

    Full Text Available The experiments were conducted by using the hydrotreated refined sunflower oil as alternative fuel in a 4-stroke, stationary DI diesel engine at a constant speed of 1500 rpm. The effects of hydrotreated vegetable oil blends on diesel engine emission and performance were studied. The emission and performance were studied for different proportions such as HTSF B25 and HTSF B100 and at different loading conditions and comparison was made with petrodiesel. The emission and performance results of HTSF B25 and HTSF B100 showed that decrease in CO by 9% and 37%, HC by 42% and 55%, NOx by 10% and 18.18%, BSFC by 25% and 12.5%. The increase in brake thermal efficiency was by 10% and 38%. It was observed from the study that hydrotreatment of refined sunflower oil could be one of the best alternative fuels for the diesel engine.

  6. Hydrotreating of heavy distillate derived from Wandoan coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Y. [National Institute for Resources and Environment, Osaka (Japan). Hydrocarbon Research Lab.

    1997-12-03

    The paper reports how the hydrotreatment of coal-derived heavy distillate, obtained from the liquefaction of Wandoan coal using a 1 t/day bench unit, was performed to clarify the effects of catalyst species, reaction temperature and hydrogen pressure on the chemical composition of the product. Experimental runs were carried out over alumina-supported Go-Mo and Ni-Mo catalysts in a fixed bed reactor of 20 ml in volume at 350-390{degree}C under hydrogen pressure of 50-150 kg/cm{sup 2}G with liquid hourly space velocity (LHSV) of 0.5-2 h{sup -1}. The product, as analyzed by gas chromatography, indicated that larger amounts of alkylbenzenes such as toluene or xylenes were produced at the elevated temperature of 390{degree}C, but the concentrations of condensed aromatics such as naphthalene, biphenyl, fluorene and phenanthrene decreased with the severity of reaction conditions. Pyrene and methylpyrene decreased in amount with a shorter LHSV and higher hydrogen pressure, but increased at higher temperature of 390{degree}C. Shorter LHSV and higher hydrogen pressure are much more effective in hydrogenation, hydrodnitrogenation and hydrodeoxygenation than the higher reaction temperature up to 390{degree}C.

  7. Upgrading of syngas hydrotreated fractionated oxidized bio-oil to transportation grade hydrocarbons

    International Nuclear Information System (INIS)

    Luo, Yan; Hassan, El Barbary; Guda, Vamshi; Wijayapala, Rangana; Steele, Philip H.

    2016-01-01

    Highlights: • Hydrotreating of fractionated oxidized bio-oil with syngas was feasible. • Hydrocarbon properties were similar with all syngas H_2/CO molar ratios except viscosity. • Syngas with H_2/CO molar ratio of (4:6) produced the highest hydrocarbon yield. • The produced hydrocarbons were in the range of gasoline, jet fuel and diesel boiling points. - Abstract: Fast pyrolysis bio-oils have the potential to replace a part of transportation fuels obtained from fossil. Bio-oil can be successfully upgraded into stable hydrocarbons (gasoline, jet fuel and diesel) through a two-stage hydrodeoxygenation process. Consumption large amount of expensive hydrogen during this process is the major hurdle for commercialization of this technology. Applying syngas in the hydrotreating step can significantly reduce the cost of the whole process and make it competitive. In this study, four different models of syngas with different H_2 concentrations (H_2/CO molar ratios = 2:8, 4:6, 6:4 and 8:2) were used for the 1st-stage hydrotreating step of oxidized fractionated bio-oil (OFB). The 2nd-stage hydrocracking step was performed on the produced organic liquid products (OLPs) by using pure H_2 gas. The effect of syngas H_2 concentrations on the yields and properties of OLPs and the 2nd-stage hydrocarbons (HCs) was investigated. Physical and chemical properties of the 2nd-stage hydrocarbons were similar regardless syngas H_2 content, with the exception of the viscosity. Syngas with H_2/CO molar ratio of 4:6 gave significantly highest HCs yield (24.8 wt.%) based on the OFB. Simulated distillation analysis proved that all 2nd-stage hydrocarbons were mixture from a wide range boiling point fuels. These results also indicated that the successful 1st-stage syngas hydrotreating step was having the potential to produce different hydrocarbons.

  8. Geodetic Control Points, Benchmarks; Vertical elevation bench marks for monumented geodetic survey control points for which mean sea level elevations have been determined., Published in 1995, 1:24000 (1in=2000ft) scale, Rhode Island and Providence Plantations.

    Data.gov (United States)

    NSGIC State | GIS Inventory — Geodetic Control Points dataset current as of 1995. Benchmarks; Vertical elevation bench marks for monumented geodetic survey control points for which mean sea level...

  9. Bench-Scale Study of Hydrogen Separation Using Pre-Commercial Membranes; Estudio, a Escala de Planta Piloto, del Proceso de Separacion de Hidrogeno mediante Membranas Pre-Comerciales

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez Hervas, J. M.; Marano, M.

    2011-11-10

    This report compiles the research undertaken by CIEMAT over 2009-2011 in the sub-project 8 Purification and Separation of Hydrogen of the PSE H2ENOV Project funded by the Spanish Ministry of Science and Innovation, MICINN. Permeability and hydrogen selectivity of a pre-commercial palladium membrane was studied at bench scale level. The effect of main operating parameters - pressure, temperature and feed-flow-rate- on permeate flow-rate was determined. The influence of other gas components on hydrogen permeation was evaluated. Mixtures of H{sub 2}-N{sub 2} and H{sub 2}-CO{sub 2} were studied. Although nitrogen and carbon dioxide did not permeate, both components decreased hydrogen permeation rate. Operating the membrane for around 1000 h under various conditions showed a small decrease in hydrogen permeation, but not in selectivity. A literature review was done in order to identify causes for permeation inhibition and reduction and for the definition of procedures for membrane regeneration. (Author) 29 refs.

  10. Performance analysis of K-based KEP-CO2P1 solid sorbents in a bench-scale continuous dry-sorbent CO{sub 2} capture process

    Energy Technology Data Exchange (ETDEWEB)

    Park, Young Cheol; Jo, Sung-Ho; Lee, Seung-Yong; Moon, Jong-Ho; Yi, Chang-Keun [Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon (Korea, Republic of); Ryu, Chong Kul; Lee, Joong Beom [Korea Electric Power Corporation Research Institute, Daejeon (Korea, Republic of)

    2016-01-15

    Korea Institute of Energy Research (KIER) and Korea Electric Power Corporation Research Institute (KEPCORI) have been developing a CO{sub 2} capture technology using dry sorbents. In this study, KEP-CO2P1, a potassium-based dry sorbent manufactured by a spray-drying method, was used. We employed a bench-scale dry-sorbent CO{sub 2} capture fluidized-bed process capable of capturing 0.5 ton CO{sub 2}/day at most. We investigated the sorbent performance in continuous operation mode with solid circulation between a fast fluidized-bed-type carbonator and a bubbling fluidizedbed- type regenerator. We used a slip stream of a real flue gas from 2MWe coal-fired circulating fluidized-bed (CFB) power facilities installed at KIER. Throughout more than 50 hours of continuous operation, the temperature of the carbonator was maintained around 70-80 .deg. C using a jacket-type heat exchanger, while that of the regenerator was kept above 180 .deg. C using an electric furnace. The differential pressure of both the carbonator and regenerator was maintained at a stable level. The maximum CO{sub 2} removal was greater than 90%, and the average CO{sub 2} removal was about 83% during 50 hours of continuous operation.

  11. Increasing Desalination by Mitigating Anolyte pH Imbalance Using Catholyte Effluent Addition in a Multi-Anode Bench Scale Microbial Desalination Cell

    KAUST Repository

    Davis, Robert J.; Kim, Younggy; Logan, Bruce E.

    2013-01-01

    A microbial desalination cell (MDC) uses exoelectrogenic bacteria to oxidize organic matter while desalinating water. Protons produced from the oxidation of organics at the anode result in anolyte acidification and reduce performance. A new method was used here to mitigate anolyte acidification based on adding non-buffered saline catholyte effluent from a previous cycle to the anolyte at the beginning of the next cycle. This method was tested using a larger-scale MDC (267 mL) containing four anode brushes and a three cell pair membrane stack. With an anolyte salt concentration increased by an equivalent of 75 mM NaCl using the catholyte effluent, salinity was reduced by 26.0 ± 0.5% (35 g/L NaCl initial solution) in a 10 h cycle, compared to 18.1 ± 2.0% without catholyte addition. This improvement was primarily due to the increase in buffering capacity of the anolyte, although increased conductivity slightly improved performance as well. There was some substrate loss from the anolyte by diffusion into the membrane stack, but this was decreased from 11% to 2.6% by increasing the anolyte conductivity (7.6 to 14 mS/cm). These results demonstrated that catholyte effluent can be utilized as a useful product for mitigating anolyte acidification and improving MDC performance. © 2013 American Chemical Society.

  12. Effect of Tidal Cycling Rate on the Distribution and Abundance of Nitrogen-Oxidizing Bacteria in a Bench-Scale Fill-and-Drain Bioreactor

    Directory of Open Access Journals (Sweden)

    Joseph M. Battistelli

    2018-04-01

    Full Text Available Most domestic wastewater can be effectively treated for secondary uses by engineered biological systems. These systems rely on microbial activity to reduce nitrogen (N content of the reclaimed water. Such systems often employ a tidal-flow process to minimize space requirements for the coupling of aerobic and anaerobic metabolic processes. In this study, laboratory-scale tidal-flow treatment systems were studied to determine how the frequency and duration of tidal cycling may impact reactor performance. Fluorescent in situ hybridization and epifluorescence microscopy were used to enumerate the key functional groups of bacteria responsible for nitrification and anaerobic ammonium oxidation (anammox, and N-removal efficiency was calculated via a mass-balance approach. When water was cycled (i.e., reactors were filled and drained at high frequencies (16–24 cycles day−1, nitrate accumulated in the columns—presumably due to inadequate periods of anoxia that limited denitrification. At lower frequencies, such as 4 cycles day−1, nearly complete N removal was achieved (80–90%. These fill-and-drain systems enriched heavily for nitrifiers, with relatively few anammox-capable organisms. The microbial community produced was robust, surviving well through short (up to 3 h anaerobic periods and frequent system-wide perturbation.

  13. A hybrid froth flotation-filtration system as a pretreatment for oil sands tailings pond recycle water management: Bench- and pilot-scale studies.

    Science.gov (United States)

    Loganathan, Kavithaa; Bromley, David; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed

    2015-09-15

    Through sustainable water management, oil sands companies are working to reduce their reliance on fresh water by minimizing the amount of water required for their operations and by recycling water from tailings ponds. This study was the first pilot-scale testing of a hybrid technology consisting of froth flotation combined with filtration through precoated submerged stainless steel membranes used to treat recycle water from an oil sands facility. The results indicated that the most important factor affecting the performance of the hybrid system was the influent water quality. Any rise in the levels of suspended solids or total organic carbon of the feed water resulted in changes of chemical consumption rates, flux rates, and operating cycle durations. The selections of chemical type and dosing rates were critical in achieving optimal performance. In particular, the froth application rate heavily affected the overall recovery of the hybrid system as well as the performance of the flotation process. Optimum surfactant usage to generate froth (per liter of treated water) was 0.25 mL/L at approximately 2000 NTU of influent turbidity and 0.015 mL/L at approximately 200 NTU of influent turbidity. At the tested conditions, the optimal coagulant dose was 80 mg/L (as Al) at approximately 2000 NTU of influent turbidity and recycle water. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Increasing Desalination by Mitigating Anolyte pH Imbalance Using Catholyte Effluent Addition in a Multi-Anode Bench Scale Microbial Desalination Cell

    KAUST Repository

    Davis, Robert J.

    2013-09-03

    A microbial desalination cell (MDC) uses exoelectrogenic bacteria to oxidize organic matter while desalinating water. Protons produced from the oxidation of organics at the anode result in anolyte acidification and reduce performance. A new method was used here to mitigate anolyte acidification based on adding non-buffered saline catholyte effluent from a previous cycle to the anolyte at the beginning of the next cycle. This method was tested using a larger-scale MDC (267 mL) containing four anode brushes and a three cell pair membrane stack. With an anolyte salt concentration increased by an equivalent of 75 mM NaCl using the catholyte effluent, salinity was reduced by 26.0 ± 0.5% (35 g/L NaCl initial solution) in a 10 h cycle, compared to 18.1 ± 2.0% without catholyte addition. This improvement was primarily due to the increase in buffering capacity of the anolyte, although increased conductivity slightly improved performance as well. There was some substrate loss from the anolyte by diffusion into the membrane stack, but this was decreased from 11% to 2.6% by increasing the anolyte conductivity (7.6 to 14 mS/cm). These results demonstrated that catholyte effluent can be utilized as a useful product for mitigating anolyte acidification and improving MDC performance. © 2013 American Chemical Society.

  15. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02

    ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  16. Radioactive Demonstration Of Final Mineralized Waste Forms For Hanford Waste Treatment Plant Secondary Waste By Fluidized Bed Steam Reforming Using The Bench Scale Reformer Platform

    International Nuclear Information System (INIS)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-01-01

    . The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of 125/129 I and 99 Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  17. Bench-scale feasibility testing of pulsed-air technology for in-tank mixing of dry cementitious solids with tank liquids and settled solids

    International Nuclear Information System (INIS)

    Whyatt, G.A.; Hymas, C.R.

    1997-09-01

    This report documents the results of testing performed to determine the feasibility of using a pulsed-air mixing technology (equipment developed by Pulsair Systems, Inc., Bellevue, WA) to mix cementitious dry solids with supernatant and settled solids within a horizontal tank. The mixing technology is being considered to provide in situ stabilization of the open-quotes Vclose quotes tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). The testing was performed in a vessel roughly 1/6 the scale of the INEEL tanks. The tests used a fine soil to simulate settled solids and water to simulate tank supernatants. The cementitious dry materials consisted of Portland cement and Aquaset-2H (a product of Fluid Tech Inc. consisting of clay and Portland cement). Two scoping tests were conducted to allow suitable mixing parameters to be selected. The scoping tests used only visual observations during grout disassembly to assess mixing performance. After the scoping tests indicated the approach may be feasible, an additional two mixing tests were conducted. In addition to visual observations during disassembly of the solidified grout, these tests included addition of chemical tracers and chemical analysis of samples to determine the degree of mixing uniformity achieved. The final two mixing tests demonstrated that the pulsed-air mixing technique is capable of producing slurries containing substantially more cementitious dry solids than indicated by the formulations suggested by INEEL staff. Including additional cement in the formulation may have benefits in terms of increasing mobilization of solids, reducing water separation during curing, and increasing the strength of the solidified product. During addition to the tank, the cementitious solids had a tendency to form clumps which broke down with continued mixing

  18. Generalized Test Plan for the Vitrification of Simulated High-Level -Waste Calcine in the Idaho National Laboratory's Bench -Scale Cold Crucible Induction Melter

    International Nuclear Information System (INIS)

    Maio, Vince

    2011-01-01

    This Preliminary Idaho National Laboratory (INL) Test Plan outlines the chronological steps required to initially evaluate the validity of vitrifying INL surrogate (cold) High-Level-Waste (HLW) solid particulate calcine in INL's Cold Crucible Induction Melter (CCIM). Its documentation and publication satisfies interim milestone WP-413-INL-01 of the DOE-EM (via the Office of River Protection) sponsored work package, WP 4.1.3, entitled 'Improved Vitrification' The primary goal of the proposed CCIM testing is to initiate efforts to identify an efficient and effective back-up and risk adverse technology for treating the actual HLW calcine stored at the INL. The calcine's treatment must be completed by 2035 as dictated by a State of Idaho Consent Order. A final report on this surrogate/calcine test in the CCIM will be issued in May 2012-pending next fiscal year funding In particular the plan provides; (1) distinct test objectives, (2) a description of the purpose and scope of planned university contracted pre-screening tests required to optimize the CCIM glass/surrogate calcine formulation, (3) a listing of necessary CCIM equipment modifications and corresponding work control document changes necessary to feed a solid particulate to the CCIM, (4) a description of the class of calcine that will be represented by the surrogate, and (5) a tentative tabulation of the anticipated CCIM testing conditions, testing parameters, sampling requirements and analytical tests. Key FY -11 milestones associated with this CCIM testing effort are also provided. The CCIM test run is scheduled to be conducted in February of 2012 and will involve testing with a surrogate HLW calcine representative of only 13% of the 4,000 m3 of 'hot' calcine residing in 6 INL Bin Sets. The remaining classes of calcine will have to be eventually tested in the CCIM if an operational scale CCIM is to be a feasible option for the actual INL HLW calcine. This remaining calcine's make-up is HLW containing

  19. Polymeric Traypack Integrity: Bench-Scale Unit

    National Research Council Canada - National Science Library

    Canavan, Jeffrey

    2002-01-01

    .... Additional experimentation was conducted to determine the applicability of the unit for non-destructive residual gas testing since current destructive tests represent a substantial continuing expense...

  20. THOR Bench-Scale Steam Reforming Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    D. W. Marshall; N. R. Soelberg; K. M. Shaber

    2003-05-01

    The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

  1. TWR Bench-Scale Steam Reforming Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, D.W.; Soelberg, N.R.

    2003-05-21

    The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

  2. THOR Bench-Scale Steam Reforming Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

    2003-05-21

    The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

  3. TWR Bench-Scale Steam Reforming Demonstration

    Energy Technology Data Exchange (ETDEWEB)

    D. W. Marshall; N. R. Soelberg

    2003-05-01

    The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

  4. THOR Bench-Scale Steam Reforming Demonstration

    International Nuclear Information System (INIS)

    Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

    2003-01-01

    The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful

  5. Report on results of R and D of coal liquefaction technology under Sunshine Project in fiscal 1981. Development of direct hydro-liquefaction plant (research on liquefaction by bench scale equipment, and research on solid-liquid separation method); 1981 nendo sekitan ekika gijutsu no kenkyu kaihatsu, chokusetsu suiten ekika plant no kaihatsu seika hokokusho. Bench scale sochi ni yoru ekika kenkyu, koeki bunriho ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This paper explains the results of development of direct hydro-liquefaction plant under the Sunshine Project in fiscal 1981. As element studies for supplementing and supporting a 2.4 t/day PDU (process development unit), in the research using a 0.1 t/day bench scale continuous type equipment of fiscal 1981, a hydrogenation experiment was conducted for anthracene oil and also, an examination was made on the reaction conditions of Taiheiyo coal and Horonai coal, as well as on the catalyst and reaction ratio and on the product material distribution. A medium oil equalizing test was performed using Taiheiyo coal in order to obtain knowledge about equalized medium oil. Liquefaction characteristics in the preheating process and reaction process were elucidated by means of a semi-batch device. Comparative studies were made between domestic and overseas coals, in coal properties and liquefaction characteristics using a shaking type autoclave. The performance of iron-sulfur based catalysts was also examined. In the research on a solid-liquid separation method, the basic properties of coal liquefied crude oil were measured such as general properties, solid grading distribution and distillation characteristics, with the basic tests carried out for standing separation, filtrating separation and centrifuging separation, providing selected materials of the solid-liquid separation method suitable for the crude oil produced by the direct hydro-liquefaction method. In addition, studies were conducted on the use of residual oil generated by solid-liquid separation, providing knowledge of the viscosity and thermal cracking. (NEDO)

  6. Flame spray synthesis of CoMo/Al2O3 hydrotreating catalysts

    DEFF Research Database (Denmark)

    Høj, Martin; Linde, Kasper; Hansen, Thomas Klint

    2011-01-01

    containing 16wt.% Mo (atomic ratio Co/Mo=1/3), which did not contain crystalline MoO3 and only small amounts of CoAl2O4. The hydrotreating activity was approximately 75% of that of commercial cobalt molybdenum catalysts prepared by wet impregnation of pre-shaped alumina extrudates. Since the commercial...... obtained consisted mostly of γ-Al2O3 with some CoAl2O4, as evidenced by X-ray diffraction (XRD) and UV–vis spectroscopy. Bulk MoO3 was not detected by XRD, except at the highest molybdenum content (32wt.%) and in the unsupported sample, indicating that molybdenum is well dispersed on the surface.......After activation by sulfidation the activity of the catalysts were measured for the three hydrotreating reactions hydrodesulfurization, hydrodenitrogenation and hydrogenation using a model oil containing dibenzothiophene, indole and naphthalene in n-heptane solution. The best catalyst was the FSP-produced material...

  7. Quantitative Surface Analysis by Xps (X-Ray Photoelectron Spectroscopy: Application to Hydrotreating Catalysts

    Directory of Open Access Journals (Sweden)

    Beccat P.

    1999-07-01

    Full Text Available XPS is an ideal technique to provide the chemical composition of the extreme surface of solid materials, vastly applied to the study of catalysts. In this article, we will show that a quantitative approach, based upon fundamental expression of the XPS signal, has enabled us to obtain a consistent set of response factors for the elements of the periodic table. In-depth spadework has been necessary to know precisely the transmission function of the spectrometer used at IFP. The set of response factors obtained enables to perform, on a routine basis, a quantitative analysis with approximately 20% relative accuracy, which is quite acceptable for an analysis of such a nature. While using this quantitative approach, we have developed an analytical method specific to hydrotreating catalysts that allows obtaining the sulphiding degree of molybdenum quite reliably and reproducibly. The usage of this method is illustrated by two examples for which XPS spectroscopy has provided with information sufficiently accurate and quantitative to help understand the reactivity differences between certain MoS2/Al2O3 or NiMoS/Al2O3-type hydrotreating catalysts.

  8. A New Approach to Deep Desulfurization of Light Cycle Oil over Ni2P Catalysts: Combined Selective Oxidation and Hydrotreating

    Directory of Open Access Journals (Sweden)

    Gwang-Nam Yun

    2018-03-01

    Full Text Available Amphiphilic phosphotungstic acid (A-PTA and Ni2P/SBA-15 catalysts were prepared to apply for selective oxidation of refractory sulfur compounds in light cycle oils and hydrotreating of the oxidized S compounds, respectively. Physical properties of the catalyst samples were analyzed by BET, CO uptake chemisorption, and TEM. Structural properties for the supported Ni2P catalysts were analyzed by X-ray diffraction (XRD and extended X-ray absorption fine structure (XAFS spectroscopy. The selective oxidation of S compounds in the LCO feed was conducted in a batch reactor at H2O2/S ratio of 10, atmospheric pressure and 353 K and then the products were fed to a continuous flow fixed-bed reactor for hydrotreating at 623 K, 3.0 MPa, and LHSV’s of 0.5–2.0 h−1. A-PTA catalyst showed a high oxidation conversion of 95% for a real LCO feed. The following hydrotreating led to a hydrodesulfurization (HDS conversion of 99.6% and a hydrodenitrogenation (HDN conversion of 94.7% over Ni2P/SBA-15, which were much higher than those of direct hydrotreating results which gave an HDS conversion of 63.5% and an HDN conversion of 17.5% based on the same LHSV of 2.0 h−1. It was revealed that the reduction in refractory nitrogen compounds after oxidative treatment contributed to the increase of the following HDS activity.

  9. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-12-31

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  10. Characterization and utilization of hydrotreated products produced from the Whiterocks (Utah) tar sand bitumen-derived liquid

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, C.H.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.; Oblad, A.G.

    1991-01-01

    The bitumen-derived liquid produced in a 4-inch diameter fluidized-bed reactor from the mined and crushed ore from the Whiterocks tar sand deposit has been hydrotreated in a fixed-bed reactor. The purpose was to determine the extent of upgrading as a function of process operating variable. A sulfided nickel-molybendum on alumina hydrodenitrogenation catalyst was used in all experiments. Moderately severe operating conditions were employed; that is, high reaction temperature (617--680 K) high reactor pressure (11.0--17.1 MPa) and low liquid feed rate (0.18--0.77 HSV); to achieve the desired reduction in heteroatom content. Detailed chemical structures of the bitumen-derived liquid feedstock and the hydrotreated total liquid products were determined by high resolution gas chromatography - mass spectrometry analyses. The compounds identified in the native bitumen included isoprenoids; bicyclic, tricycle, and tetracyclic terpenoids; steranes; hopanes; and perhydro-{beta}-carotenes. In addition, normal and branched alkanes and alkenes and partially dehydrogenated hydroaromatics were identified in the bitumen-derived liquid. The dominant pyrolysis reactions were: (1) the dealkylation of long alkyl side chains to form {alpha} - and isoolefins; and (2) the cleavage of alkyl chains linking aromatic and hydroaromatic clusters. Olefinic bonds were not observed in the hydrotreated product and monoaromatic hydrocarbons were the predominant aromatic species. The properties of the jet fuel fractions from the hydrotreated products met most of the jet fuel specifications. The cetane indices indicated these fractions would be suitable for use as diesel fuels.

  11. Oil extracted from spent coffee grounds for bio-hydrotreated diesel production

    International Nuclear Information System (INIS)

    Phimsen, Songphon; Kiatkittipong, Worapon; Yamada, Hiroshi; Tagawa, Tomohiko; Kiatkittipong, Kunlanan; Laosiripojana, Navadol; Assabumrungrat, Suttichai

    2016-01-01

    Highlights: • The spent coffee oil with high FFAs was hydrotreated to liquid biofuel. • Pd/C gave higher olefins while NiMo/γ-Al_2O_3 gave higher isoparaffins liquid products. • The diesel fuel fraction can have a cetane number as high as 80. • The physiochemical properties of diesel fraction comply with commercial standard. - Abstract: Oil extracted from spent coffee grounds is utilized as a renewable source for bio-hydrotreated fuel production. In the present work, oil yield up to 13% can be obtained by Soxhlet extraction with hexane as a solvent. As the extracted oil contained high content of free fatty acids (6.14%), therefore one step alkali-catalyzed for ester based biodiesel production is impractical. Hydrotreating of extracted oil was performed over two catalysts i.e. NiMo/γ-Al_2O_3 and Pd/C with different operating parameters i.e. reaction time, operating temperature, and H_2/oil. It was found that the reaction time of 2 h and the reaction temperature of 400 °C are favorable operating conditions. The liquid products mostly consisted of n-pentadecane and n-heptadecane, which contain one carbon atom shorter than the corresponding fatty acid (C_n_−_1) i.e. palmitic and stearic acid, respectively. Unfavorable cracking of diesel product is pronounced at high temperature and prolonged reaction time. In addition, although increased H_2/oil promoted overall reaction and hydrodeoxygenation activity (C_n_−_1/C_n decreased) for both catalysts, hydrocracking is enhanced over Pd/C, leading to significant increase in gasoline yield. Moreover, Pd/C gave higher olefin content in liquid product (22.3 wt%) than NiMo/γ-Al_2O_3 (4.8 wt%). However, NiMo/γ-Al_2O_3 shows higher isomerization activity. The amount of isoparaffins catalyzed by NiMo/γ-Al_2O_3 and Pd/C were 10.8 and 1.7 wt%, respectively. Physiochemical analysis of the diesel fraction exhibit satisfactory properties. The density and kinematic viscosity were consistent with the specification of

  12. Syntheses, Characterization and Kinetics of Nickel-Tungsten Nitride Catalysts for Hydrotreating of Gas Oil

    Science.gov (United States)

    Botchwey, Christian

    This thesis summarizes the methods and major findings of Ni-W(P)/gamma-Al 2O3 nitride catalyst synthesis, characterization, hydrotreating activity, kinetic analysis and correlation of the catalysts' activities to their synthesis parameters and properties. The range of parameters for catalyst synthesis were W (15-40 wt%), Ni (0-8 wt%), P (0-5 wt%) and nitriding temperature (TN) (500-900 °C). Characterization techniques used included: N2 sorption studies, chemisorption, elemental analysis, temperature programmed studies, x-ray diffraction, scanning electron microscopy, energy dispersive x-ray, infrared spectroscopy, transmission electron microscopy and x-ray absorption near edge structure. Hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatization (HDA) were performed at: temperature (340-380 °C), pressure (6.2-9.0 MPa), liquid hourly space velocity (1-3 h-1) and hydrogen to oil ratio (600 ml/ml, STP). The predominant species on the catalyst surface were Ni3N, W2N and bimetallic Ni2W3N. The bimetallic Ni-W nitride species was more active than the individual activities of the Ni3N and W2N. P increased weak acid sites while nitriding temperature decreased amount of strong acid sites. Low nitriding temperature enhanced dispersion of metal particles. P interacted with Al 2O3 which increased the dispersion of metal nitrides on the catalyst surface. HDN activity increased with Ni and P loading but decreased with increase in nitriding temperature (optimum conversion; 60 wt%). HDS and HDA activities went through a maximum with increase in the synthesis parameters (optimum conversions; 88. wt% for HDS and 47 wt% for HDA). Increase in W loading led to increase in catalyst activity. The catalysts were stable to deactivation and had the nitride structure conserved during hydrotreating in the presence of hydrogen sulfide. The results showed good correlation between hydrotreating activities (HDS and HDN) and the catalyst nitrogen content, number of exposed

  13. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    International Nuclear Information System (INIS)

    Chacon, R.; Canale, A.; Bouza, A.; Sanchez, Y.

    2012-01-01

    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H 2 ), hydrogen sulfide (H 2 S) and ammonia (NH 3 ) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H 2 /feed ratio and the inhibiting effect of H 2 S on HDS and NH 3 on HDN. (author)

  14. Role of hydrotreating products in deposition of fine particles in reactors

    Energy Technology Data Exchange (ETDEWEB)

    Wang, S.; Chung, K.; Gray, M.R. [University of Alberta, Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

    2001-06-11

    Hydrotreating reactions may affect the deposition of fine particles, which can eventually lead to reactor plugging. The deposition of fine particles from gas oil was measured in an internally recirculating reactor at 375{degree}C under hydrogen. H{sub 2}S from hydrodesulfurization would convert corrosion products to metal sulfides. Iron sulfide deposited rapidly in the packed bed because the mineral surface did not retain a stabilizing layer of asphaltenic material. Addition of water, to test the role of hydrodeoxygenation, doubled the deposition of clay particles by reducing the surface coating of organic material. Neither ammonia or quinoline had any effect on particle deposition, therefore, hydrodenitrogenation did not affect particle behavior. 16 refs., 4 figs., 3 tabs.

  15. Synthesis of carbon nanotubes by CCVD of natural gas using hydrotreating catalysts

    Directory of Open Access Journals (Sweden)

    Ahmed E. Awadallah

    2012-12-01

    Full Text Available Carbon nanotubes have been successfully synthesized using the catalytic chemical vapor deposition (CCVD technique over typical refining hydrotreating catalysts (hydrodesulfurization and hydrodenitrogenation containing Ni–Mo and Co–Mo supported on Al2O3 catalysts at 700°C in a fixed bed horizontal reactor using natural gas as a carbon source. The catalysts and the as-grown CNTs were characterized by transmission electron microscopy, HRTEM, X-ray diffraction patterns, EDX and TGA–DTG. The obtained data clarified that the Ni–Mo catalyst gives higher yield, higher purity and selectivity for CNTs compared to Co–Mo catalyst. XRD, TEM and TGA reveal also that the Ni–Mo catalyst produces mostly CNTs with different diameters whereas the Co–Mo catalyst produces largely amorphous carbon.

  16. In-line estimation of sulfur and nitrogen contents during hydrotreating of middle distillates

    Directory of Open Access Journals (Sweden)

    M. E. Pacheco

    2009-12-01

    Full Text Available The main objective of this work is analyzing whether it is possible to develop an empirical correlation for in-line estimation of the sulfur and nitrogen contents of the middle distillates Hydrotreating (HDT products for control purposes. Correlations are based only on readily available in-line information of specific gravity variation between feedstock and products, without considering any piece of information about the kinetic behavior of the catalyst. Experimental data were obtained in pilot plants under operating conditions that are representative of refinery operations. Results indicate that the removal of nitrogen and sulfur compounds during middle distillates HDT can be monitored in-line in real time, based on the available measurements of specific gravity. This allows for development and implementation of advanced in-line procedures for monitoring and control of the HDT process in real time.

  17. BWR Mark I pressure suppression study: bench mark experiments

    International Nuclear Information System (INIS)

    Lai, W.; McCauley, E.W.

    1977-01-01

    Computer simulations representative of the wetwell of Mark I BWR's have predicted pressures and related phenomena. However, calculational predictions for purposes of engineering decision will be possible only if the code can be verified, i.e., shown to compute in accord with measured values. Described in the report is a set of single downcomer spherical flask bench mark experiments designed to produce quantitative data to validate various air-water dynamic computations; the experiments were performed since relevant bench mark data were not available from outside sources. Secondary purposes of the study were to provide a test bed for the instrumentation and post-experiment data processing techniques to be used in the Laboratory's reactor safety research program and to provide additional masurements for the air-water scaling study

  18. HVO, hydrotreated vegetable oil. A premium renewable biofuel for diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, Seppo [Neste Oil, Porvoo (Finland); Honkanen, Markku; Kuronen, Markku [Neste Oil, Espoo (Finland)

    2013-06-01

    HVO is renewable paraffinic diesel fuel produced from vegetable oils or animal fats by hydrotreating and isomerization. Composition is similar to GTL. HVO is not ''biodiesel'' which is a definition reserved for FAME. HVO can be used in diesel fuel without any ''blending wall'' as well as in addition to the FAME in EN 590. As a blending component HVO enhances fuel properties thanks to its high cetane, zero aromatics and reasonable distillation range. HVO can be used for upgrading gas oils to meet diesel fuel standard and for producing premium diesel fuels. HVO is comparable to fossil diesel regarding fuel logistics, stability, water separation and microbiological growth. The use of HVO as such or in blends reduces NO{sub x} and particulate emissions. Risks for fuel system deposits and engine oil deterioration are low. Combustion is practically ash-free meaning low risk for exhaust aftertreatment life-time. Winter grade fuels down to -40 C cloud point can be produced by HVO process from many kinds of feedstocks. HVO is fully accepted by directives and fuel standards. (orig.)

  19. Hydrotreating of compounds and mixtures of compounds having mercapto and hydroxyl groups

    Energy Technology Data Exchange (ETDEWEB)

    Viljava, T.R.; Krause, A.O.I. [Helsinki University of Technology, Espoo (Finland)

    1997-07-01

    Simultaneous hydrodesulfurization (HDS) and hydrodeoxygenation (HDO) of mercapto and hydroxyl group containing benzenes was studied using a commercial presulfided CoMo/{gamma}- Al{sub 2}O{sub 3} catalyst under hydrotreating conditions (150-280 deg C, 7 MPa). Mercaptobenzene, phenol and 4-mercaptophenol were used as model compounds, and CS{sub 2} was used as precursor for H{sub 2}S. The HDS rate of a mercapto group in the presence of a hydroxyl substituent in the para position was higher than that for the molecule containing only a mercapto group. When the hydroxyl group was present as phenol, the HDS rate of the mercapto group was about 30% lower than that for mercaptobenzene without an oxygen-containing additive. The decrease in the HDS rate was independent of the initial molar ratio of sulfur and oxygen within the ratios studied (5:1-1:1). The HDO rate of a hydroxyl group was suppressed by the mercapto group present either in the same or in a separate molecule. HDO reactions did not start until HDS conversion was almost complete. CS{sub 2} also decreased the HDO rate of phenol. When compared to the reactions of phenol alone, the rate of the hydrogenolysis route to benzene was decreased in the presence of a sulfur additive more than the hydrogenolysis- hydrogenation route to cyclohexane. 19 refs.

  20. A study on the hydrotreating of coal hydro liquefaction residue and its kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Huang, J.; Lu, X.; Zhang, D.; Gao, J. [Department of Chemical Engineering for Energy Resources, East China University of Science and Technology, Shanghai (China)

    2010-09-15

    Hydro-conversion of coal hydro liquefaction residue obtained from a 6 t/day pilot plant of Shenhua Group in Shanghai was carried out under the hydrotreating condition. The coal hydro liquefaction residue and its product were extracted in sequence with n-hexane, toluene and tetrahydrofuran in a Soxhlet apparatus. The n-hexane soluble fractions increased with the increase of reaction temperature and time. Its amount increased from 14.14% to a maximum of 40.86% under the conditions of 470 {sup o}C and 30 min, which meant that moderate extension of coal residence time in the coal hydro liquefaction reactor is beneficial to the increase of oil yield. A 4-lumped kinetic model of coal hydro liquefaction residue hydro-conversion was performed using solubility-based lumped fractions. In the model, the tetrahydrofuran insoluble fractions were classified into two parts: easily reactive part and unreactive part. The kinetic parameters were estimated by a fourth-order Runge-Kutta method and a nonlinear least squares method, and the apparent activation energies were calculated according to the Arrhenius Equation. A large quantity of total catalyst consisting of remained liquefaction catalyst, part of the mineral from raw coal and additive Fe-based catalyst could considerably reduce the apparent activation energy of hydro-conversion for the toluene insoluble/tetrahydrofuran insoluble fractions to 36.79 kJ-mol{sup -1}. The calculated values of the model coincided well with the experimental values. (authors)

  1. A Study on the Hydrotreating of Coal Hydroliquefaction Residue and its Kinetics

    Directory of Open Access Journals (Sweden)

    Jinsheng Gao

    2010-09-01

    Full Text Available Hydro-conversion of coal hydroliquefaction residue obtained from a 6t/day pilot plant of Shenhua Group in Shanghai was carried out under the hydrotreating condition. The coal hydroliquefaction residue and its product were extracted in sequence with n-hexane, toluene and tetrahydrofuran in a Soxhlet apparatus. The n-hexane soluble fractions increased with the increase of reaction temperature and time. Its amount increased from 14.14% to a maximum of 40.86% under the conditions of 470 °C and 30 min, which meant that moderate extension of coal residence time in the coal hydroliquefaction reactor is beneficial to the increase of oil yield. A 4-lumped kinetic model of coal hydroliquefaction residue hydro-conversion was performed using solubility-based lumped fractions. In the model, the tetrahydrofuran insoluble fractions were classified into two parts: easily reactive part and unreactive part. The kinetic parameters were estimated by a fourth-order Runge-Kutta method and a nonlinear least squares method, and the apparent activation energies were calculated according to the Arrhenius Equation. A large quantity of total catalyst consisting of remained liquefaction catalyst, part of the mineral from raw coal and additive Fe-based catalyst could considerably reduce the apparent activation energy of hydro-conversion for the toluene insoluble/tetrahydrofuran insoluble fractions to 36.79 kJ•mol-1. The calculated values of the model coincided well with the experimental values.

  2. Modeling of a three-phase reactor for bitumen-derived gas oil hydrotreating

    Energy Technology Data Exchange (ETDEWEB)

    Chacon, R.; Canale, A.; Bouza, A. [Departamento de Termodinamica y Fenomenos de Transporte. Universidad Simon Bolivar, Caracas (Venezuela, Bolivarian Republic of); Sanchez, Y. [Departamento de Procesos y Sistemas. Universidad Simon Bolivar (Venezuela, Bolivarian Republic of)

    2012-01-15

    A three-phase reactor model for describing the hydrotreating reactions of bitumen-derived gas oil was developed. The model incorporates the mass-transfer resistance at the gas-liquid and liquid-solid interfaces and a kinetic rate expression based on a Langmuir-Hinshelwood-type model. We derived three correlations for determining the solubility of hydrogen (H{sub 2}), hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) in hydrocarbon mixtures and the calculation of the catalyst effectiveness factor was included. Experimental data taken from the literature were used to determine the kinetic parameters (stoichiometric coefficients, reaction orders, reaction rate and adsorption constants for hydrodesulfuration (HDS) and hydrodenitrogenation (HDN)) and to validate the model under various operating conditions. Finally, we studied the effect of operating conditions such as pressure, temperature, LHSV, H{sub 2}/feed ratio and the inhibiting effect of H{sub 2}S on HDS and NH{sub 3} on HDN. (author)

  3. Features of hydrotreating catalytic cracking feed and heavy slow coking gas oils

    Energy Technology Data Exchange (ETDEWEB)

    Yefremov, N.I.; Kushnarev, D.F.; Frolov, P.A.; Chagovets, A.N.; Kalabin, G.A.

    1993-12-31

    A possible means of more extensive processing of crude oil is the use, in catalytic cracking, of heavy coking gas oils (HCGOs), a feature of which is a higher content of polycyclic aromatic compounds and resins by comparison with straight-run vacuum distillates. The presence of these compounds in catalytic cracking feed causes a reduction in the product yield and increased coke formation. Therefore, one of the problems of hydrotreating feedstock of this kind is the hydrogenation of polycyclic arenes. Processes of extensive desulphurization and denitration occur in parallel, since the sulphur and nitrogen compounds of HCGO are chiefly condensed benzoderivatives of thiophene, pyridine and carbazole, and largely concentrated in heavy aromatic and resinous fractions. The composition of the saturated part of the cracking feed plays a large role in achieving the optimum yields of gaseous and gasoline fractions. Thus an increase in the proportion of cyclanes in the feed raises the gasoline yield. In this way, an investigation of the hydrocarbon conversions during the hydrotreatment of cracking feed is of great importance. The present paper sets out the results for studying the change in the group-structural characteristics of the hydrogenation products of a mixture containing 30% HCGOs according to data of {sup 1}H and {sup 13}C NMR spectroscopy. 7 refs., 7 figs., 1 tab.

  4. Environmental Impacts and Costs of Hydrotreated Vegetable Oils, Transesterified Lipids and Woody BTL—A Review

    Directory of Open Access Journals (Sweden)

    Andreas Brekke

    2011-05-01

    Full Text Available This article reviews and compares assessments of three biodiesel fuels: (1 transesterified lipids, (2 hydrotreated vegetable oils (HVO, and (3 woody biomass-to-liquid (BTL Fischer-Tropsch diesel and selected feedstock options. The article attempts to rank the environmental performance and costs of fuel and feedstock combinations. Due to inter-study differences in goal and study assumptions, the ranking was mostly qualitative and intra-study results are emphasized. Results indicate that HVO made from wastes or by-products such as tall oil, tallow or used cooking oil outperform transesterified lipids and BTL from woody material, both with respect to environmental life cycle impacts and costs. These feedstock options are, however, of limited availability, and to produce larger volumes of biofuels other raw materials must also be used. BTL from woody biomass seems promising with good environmental performance and the ability not to compete with food production. Production of biofuels from agricultural feedstock sources requires much energy and leads to considerable emissions due to agrochemical inputs. Thus, such biodiesel fuels are ranked lowest in this comparison. Production of feedstock is the most important life cycle stage. Avoiding detrimental land use changes and maintaining good agricultural or forestry management practices are the main challenges to ensure that biofuels can be a sustainable option for the future transport sector.

  5. Simulation of Induction Traction Drive with Supercapacitor Energy Storage System Test Bench

    Directory of Open Access Journals (Sweden)

    Stana Girts

    2015-12-01

    Full Text Available The paper describes the application of supercapacitor energy storage system for induction traction drive test bench that replaces a real electric public transport for performing testing and researches. The suitability and usage of such bench for research purposes is explained and the importance of the development of software mathematical model for performing simulations to be done before physical implementation measures is reasoned. The working principle of the bench and applied components are described. A virtual model of the bench was built and simulations were performed using Matlab/Simulink software. The basic topology of the virtual bench model is described as well. The calculations of this work show the scaling of supercapacitor energy storage system by setting different limits of working voltage range in order to adjust them to test bench parameters, whereas the modelling compares two simulation cases – the application of less supercapacitors and the application of more supercapacitors with the same common rated voltage. The autonomous mode simulations were also performed. Simulation results are analyzed and recommendations for the application of the supercapacitor energy storage system, with respect to initial supercapacitor circuit voltage, are given.

  6. PENGARUH PERBEDAAN SIFAT PENYANGGA ALUMINA TERHADAP SIFAT KATALIS HYDROTREATING BERBASIS NIKEL-MOLIBDENUM

    Directory of Open Access Journals (Sweden)

    Maria Ulfah

    2012-11-01

    Full Text Available EFFECT OF ALUMINA SUPPORT PROPERTIES ON THE NICKEL-MOLIBDENUM BASE HYDROTREATING CATALYST. Effect of surface characteristics of three species of synthesized γ-alumina (alumina-1, alumina-2 and alumina-3 on characteristics NiMo catalysts has been studied. Those aluminas are derived from boehmite Catapal B by varying rasio mol nitric acid to boehmite. A sol-gel method is used to synthesize γ-Al2O3 support. The Nitrogen adsorption, X-ray diffraction (XRD, Temperature Programmed Reduction (TPR of H2, Temperature Programmed Desorption (TPD of NH3, and mechanical strength are used to characterize the supports and catalysts. The results showed that the surface area alumina affects the formation of crystalline MoO3 in the NiMo catalyst, while γ-Al2O3-3 support which has the highest surface area (about 195 m2/g compared to the other two types of alumina (>195 m2/g does not have a crystalline MoO3. The formation of crystalline MoO3 is not influenced by the acidity alumina. Based on the results of XRD, it is  indicated that the supported alumina-3 NiMo catalyst (having the highest acid strength shows that there is no presence of crystalline MoO3. Pore size distribution of support did not change significantly after the deposition of Ni and Mo oxides. Mechanical strength of support also affects the strength NiMo catalyst. Support alumina-3 which has the highest mechanical strength gives the mechanical strength of the highest NiMo catalyst. Pengaruh sifat penyangga γ-alumina hasil pengembangan (alumina-1, alumina-2 dan alumina-3 pada karakter katalis hydrotreating nikel-molibdenum (NiMo telah dipelajari. Ketiga jenis γ-alumina diturunkan dari boehmite “Catapal B” dengan menvariasikan nisbah mol asam nitrat terhadap boehmite. Pembuatan γ-alumina menggunakan metoda sol-gel. Adsorpsi Nitrogen, X-ray difraksi (XRD, Temperature Programmed Reduction (TPR H2, Temperature Programmed Desorption (TPD NH3, dan kekuatan mekanik digunakan untuk

  7. Influence of bench angle on upper extremity muscular activation during bench press exercise.

    Science.gov (United States)

    Lauver, Jakob D; Cayot, Trent E; Scheuermann, Barry W

    2016-01-01

    This study compared the muscular activation of the pectoralis major, anterior deltoid and triceps brachii during a free-weight barbell bench press performed at 0°, 30°, 45° and -15° bench angles. Fourteen healthy resistance trained males (age 21.4 ± 0.4 years) participated in this study. One set of six repetitions for each bench press conditions at 65% one repetition maximum were performed. Surface electromyography (sEMG) was utilised to examine the muscular activation of the selected muscles during the eccentric and concentric phases. In addition, each phase was subdivided into 25% contraction durations, resulting in four separate time points for comparison between bench conditions. The sEMG of upper pectoralis displayed no difference during any of the bench conditions when examining the complete concentric contraction, however differences during 26-50% contraction duration were found for both the 30° [122.5 ± 10.1% maximal voluntary isometric contraction (MVIC)] and 45° (124 ± 9.1% MVIC) bench condition, resulting in greater sEMG compared to horizontal (98.2 ± 5.4% MVIC) and -15 (96.1 ± 5.5% MVIC). The sEMG of lower pectoralis was greater during -15° (100.4 ± 5.7% MVIC), 30° (86.6 ± 4.8% MVIC) and horizontal (100.1 ± 5.2% MVIC) bench conditions compared to the 45° (71.9 ± 4.5% MVIC) for the whole concentric contraction. The results of this study support the use of a horizontal bench to achieve muscular activation of both the upper and lower heads of the pectoralis. However, a bench incline angle of 30° or 45° resulted in greater muscular activation during certain time points, suggesting that it is important to consider how muscular activation is affected at various time points when selecting bench press exercises.

  8. SP2Bench: A SPARQL Performance Benchmark

    Science.gov (United States)

    Schmidt, Michael; Hornung, Thomas; Meier, Michael; Pinkel, Christoph; Lausen, Georg

    A meaningful analysis and comparison of both existing storage schemes for RDF data and evaluation approaches for SPARQL queries necessitates a comprehensive and universal benchmark platform. We present SP2Bench, a publicly available, language-specific performance benchmark for the SPARQL query language. SP2Bench is settled in the DBLP scenario and comprises a data generator for creating arbitrarily large DBLP-like documents and a set of carefully designed benchmark queries. The generated documents mirror vital key characteristics and social-world distributions encountered in the original DBLP data set, while the queries implement meaningful requests on top of this data, covering a variety of SPARQL operator constellations and RDF access patterns. In this chapter, we discuss requirements and desiderata for SPARQL benchmarks and present the SP2Bench framework, including its data generator, benchmark queries and performance metrics.

  9. Test Bench Development for Femur Stability Assessment

    Directory of Open Access Journals (Sweden)

    Samuel SANCHEZ-CABALLERO

    2015-01-01

    Full Text Available This paper shows the design and development of a test bench for humanfemurs. The main uses of this test bench will run from artificial femurs comparisonwith real femurs, to join stability assessment after bone a fracture repair. Amongthis uses is specially designed for condylar fractures testing. The test bench isdeveloped from a self-made existing tensile/compression testing machine. Thedesign procedure is supported by a literature review about the bone mechanicalbehavior and composition generally and the knee joint performance and repairparticularly. On the basis of this review, the machine was designed to simulate theadduction and abduction movements of the joint. The magnitudes to be measuredare: the compression force, the bone displacement (vertical and the knee jointrotation

  10. The national hydrologic bench-mark network

    Science.gov (United States)

    Cobb, Ernest D.; Biesecker, J.E.

    1971-01-01

    The United States is undergoing a dramatic growth of population and demands on its natural resources. The effects are widespread and often produce significant alterations of the environment. The hydrologic bench-mark network was established to provide data on stream basins which are little affected by these changes. The network is made up of selected stream basins which are not expected to be significantly altered by man. Data obtained from these basins can be used to document natural changes in hydrologic characteristics with time, to provide a better understanding of the hydrologic structure of natural basins, and to provide a comparative base for studying the effects of man on the hydrologic environment. There are 57 bench-mark basins in 37 States. These basins are in areas having a wide variety of climate and topography. The bench-mark basins and the types of data collected in the basins are described.

  11. Relationship of pectoralis major muscle size with bench press and bench throw performances.

    Science.gov (United States)

    Akagi, Ryota; Tohdoh, Yukihiro; Hirayama, Kuniaki; Kobayashi, Yuji

    2014-06-01

    This study examined the relationship of muscle size indices of the pectoralis major muscle with bench press and bench throw performances in 18 male collegiate athletes. The maximal cross-sectional area (MCSAMAx) and volume (MV) of the pectoralis major muscle were determined by magnetic resonance imaging. First, subjects were tested for their one repetition maximum bench press strength (1RMBP) using a Smith machine. At a later date, subjects performed bench throws using the Smith machine with several different loads ranging from 30.0 kg to 90% of 1RMBP. Barbell positions were measured by a linear position transducer, and bench throw power was calculated using a dynamic equation. Three trials were performed for each load. In all the trials, the maximal peak power was adopted as bench throw peak power (PPBT). The 1RMBP was significantly correlated with MCSAMAx. Similarly, the correlation coefficient between MV and PPBT was significant. In contrast to the y-intercept of the MV-PPBT regression line, that of the MCSAMAx-1RMBP regression line was not significantly different from 0. These results suggested that, although the dependence on pectoralis major muscle size is slightly different between bench press strength and bench throw power, the pectoralis major muscle size has a significant impact on bench press and throw performances. Greater muscle size leads to heavier body weight, which can be a negative factor in some sports. We therefore recommend that athletes and their coaches develop training programs for improving sports performance by balancing the advantage of increased muscle size and the potential disadvantage of increased body weight.

  12. Simulation-based rhomboid flap skills training during medical education: comparing low- and high-fidelity bench models.

    Science.gov (United States)

    Denadai, Rafael; Saad-Hossne, Rogerio; Raposo-Amaral, Cassio Eduardo

    2014-11-01

    To assess if the bench model fidelity interferes in the acquisition of rhomboid flap skills by medical students. Sixty novice medical students were randomly assigned to 5 practice conditions with instructor-directed Limberg rhomboid flap skills training: didactic materials (control group 1), low-fidelity rubberized line (group 2) or ethylene-vinyl acetate (group 3) bench models; high-fidelity chicken leg skin (group 4) or pig foot skin (group 5) bench models. Pretests and posttests were applied, and Global Rating Scale, effect size, and self-perceived confidence were used to evaluate all flap performances. Medical students from groups 2 to 5 showed better flap performances based on the Global Rating Scale (all P 0.05). The magnitude of the effect was considered large (>0.80) in all measurements. There was acquisition of rhomboid flap skills regardless of bench model fidelity.

  13. Distal clavicular osteolysis in adults: association with bench pressing intensity

    International Nuclear Information System (INIS)

    Nevalainen, Mika T.; Morrison, William B.; Zoga, Adam C.; Roedl, Johannes B.; Ciccotti, Michael G.

    2016-01-01

    To investigate the association between distal clavicular osteolysis (DCO) and bench pressing intensity. From a retrospective review of MRI shoulder reports of individuals between 20 and 40 years of age, 262 male patients with DCO and 227 age-matched male patients without DCO were selected. All patients had completed a bench pressing questionnaire. The patients' bench pressing frequency (times per week), duration (years of bench pressing), bench pressing weight (maximum bench pressing weight with one repetition = 1RM) and the ratio of bench pressing weight to body weight were compared between both groups using Chi-square and Mann-Whitney tests. The results showed that 56 % (146/262) of patients with DCO were high-intensity bench pressers (1RM more than 1.5 times the body weight) compared to 6 % (14/227) in patients without DCO. High-intensity bench pressing was a risk factor for DCO (OR = 19; 95 %CI = 11-35; p 1 x /week) and duration (>5 years) of bench pressing were risk factors. In bench pressers who suffered from DCO, the mean 1RM was 283 lbs (±SD 57) compared to 209 lbs (±SD 60) in bench pressers not affected by DCO (p < 0.001, Mann-Whitney). High-intensity, but not low-intensity bench pressing is a risk factor for DCO. (orig.)

  14. Production of bio-hydrogenated diesel by catalytic hydrotreating of palm oil over NiMoS2/γ-Al2O3 catalyst.

    Science.gov (United States)

    Srifa, Atthapon; Faungnawakij, Kajornsak; Itthibenchapong, Vorranutch; Viriya-Empikul, Nawin; Charinpanitkul, Tawatchai; Assabumrungrat, Suttichai

    2014-04-01

    Catalytic hydrotreating of palm oil (refined palm olein type) to produce bio-hydrogenated diesel (BHD) was carried out in a continuous-flow fixed-bed reactor over NiMoS2/γ-Al2O3 catalyst. Effects of dominant hydrotreating parameters: temperature: 270-420°C; H2 pressure: 15-80 bar; LHSV: 0.25-5.0 h(-1); and H2/oil ratio: 250-2000 N(cm(3)/cm(3)) on the conversion, product yield, and a contribution of hydrodeoxygenation (HDO) and decarbonylation/decarboxylation (DCO/DCO2) were investigated to find the optimal hydrotreating conditions. All calculations including product yield and the contribution of HDO and DCO/DCO2 were extremely estimated based on mole balance corresponding to the fatty acid composition in feed to fully understand deoxygenation behaviors at different conditions. These analyses demonstrated that HDO, DCO, and DCO2 reactions competitively occurred at each condition, and had different optimal and limiting conditions. The differences in the hydrotreating reactions, liquid product compositions, and gas product composition were also discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  15. NetBench. Automated Network Performance Testing

    CERN Document Server

    Cadeddu, Mattia

    2016-01-01

    In order to evaluate the operation of high performance routers, CERN has developed the NetBench software to run benchmarking tests by injecting various traffic patterns and observing the network devices behaviour in real-time. The tool features a modular design with a Python based console used to inject traffic and collect the results in a database, and a web user

  16. Stem Cell Transplantation from Bench to Bedside

    Indian Academy of Sciences (India)

    Table of contents. Stem Cell Transplantation from Bench to Bedside · Slide 2 · Slide 3 · Slide 4 · Principles of an allogeneic stem cell transplant · Principle of an allogeneic stem cell transplant · Principle of an autologous Stem Cell Transplant · Slide 8 · Conditioning · Slide 10 · Slide 11 · Stem Cell Transplantation · Slide 13.

  17. Mathematical Lens: How Much Can You Bench?

    Science.gov (United States)

    Bolognese, Chris A.

    2013-01-01

    "How Much Can You Bench?" appears in the "Mathematical Lens" section of "Mathematics Teacher." "Mathematical Lens" uses photographs as a springboard for mathematical inquiry and appears in every issue of "Mathematics Teacher." This month the mathematics behind the photograph includes finding areas…

  18. ESPRESSO optical bench: from mind to reality

    Science.gov (United States)

    Tenegi, F.; Santana, S.; Gómez, J.; Rodilla, E.; Hughes, I.; Mégevand, D.; Rebolo, R.; Riva, M.; Luis-Simoes, R.

    2016-07-01

    ESPRESSO [1] is a high-resolution spectrograph under development for the VLT telescope. In general, the Optical Bench (OB) structure can be considered as a 3D one, conformed by welding thin plates of Structural Steel (St-52) with a nickelplated surface treatment, combined for getting maximum stiffness and minimum weight, that will be finally re-machined to get stringent geometrical and dimensional tolerances at I/Fs positions. TIG conventional welding procedure has been selected to minimize the cost and facilitate the own welding process. This solution follows the inheritance from HARPS [2] due to its success to achieve the required performance for the bench. This paper contains an overview of the whole process of designing and manufacturing the Optical Bench of ESPRESSO, from the very first beginning with the specifications to the current status of the bench with its integration on the Spectrograph (including the Finite Element Models and the delivery of the final structure by the supplier) and lessons learned.

  19. Spontaneous pneumomediastinum after bench press training.

    Science.gov (United States)

    Nishino, Tomoya

    2017-04-01

    Spontaneous pneumomediastinum is often associated with asthma and mainly affects adolescent males with a tall, thin body habitus. A 17-year-old man complained of chest and pharyngeal pain after bench press training and spontaneous pneumomediastinum was diagnosed. It should be considered in the differential diagnosis of chest pain of uncertain cause.

  20. Encounters on a Shape-changing Bench

    DEFF Research Database (Denmark)

    Kinch, Sofie; Grönvall, Erik; Petersen, Marianne Graves

    2014-01-01

    ; a concert hall, an airport and a shopping mall. We gathered insights from more than 120 people, as they unexpectedly encountered the shape changing capabilities of the bench. By taking the user tests out of the lab and into the wild, we explored the influence of context on the users experience of a shape...

  1. RemBench: A Digital Workbench for Rembrandt Research

    NARCIS (Netherlands)

    Verberne, Suzan; Van Leeuwen, Rudie; Gerritsen, G.H.; Boves, Lou

    2016-01-01

    In this paper, we present RemBench, a search engine for research into the life and works of Rembrandt van Rijn. RemBench combines the data from four different databases behind one interface using federated search technology. Metadata filtering is enabled through faceted search. RemBench enables art

  2. An elegant Breadboard of the optical bench for eLISA/NGO

    Science.gov (United States)

    d'Arcio, Luigi; Bogenstahl, Johanna; Diekmann, Christian; Fitzsimons, Ewan D.; Heinzel, Gerhard; Hogenhuis, Harm; Killow, Christian J.; Lieser, Maike; Nikolov, Susanne; Perreur-Lloyd, Michael; Pijnenburg, Joep; Robertson, David I.; Taylor, Alasdair; Tröbs, Michael; Ward, Harry; Weise, Dennis

    2017-11-01

    The Laser Interferometer Space Antenna, as well as its reformulated European-only evolution, the New Gravitational-Wave Observatory, both employ heterodyne laser interferometry on million kilometer scale arm lengths in a triangular spacecraft formation, to observe gravitational waves at frequencies between 3 × 10-5 Hz and 1 Hz. The Optical Bench as central payload element realizes both the inter-spacecraft as well as local laser metrology with respect to inertial proof masses, and provides further functions, such as point-ahead accommodation, acquisition sensing, transmit beam conditioning, optical power monitoring, and laser redundancy switching. These functions have been combined in a detailed design of an Optical Bench Elegant Breadboard, which is currently under assembly and integration. We present an overview of the realization and current performances of the Optical Bench subsystems, which employ ultraprecise piezo mechanism, ultrastable assembly techniques, and shot noise limited RF detection to achieve translation and tilt metrology at Picometer and Nanoradian noise levels.

  3. Improving fuel quality by whole crude oil hydrotreating: A kinetic model for hydrodeasphaltenization in a trickle bed reactor

    International Nuclear Information System (INIS)

    Jarullah, A.T.; Mujtaba, I.M.; Wood, A.S.

    2012-01-01

    Highlights: ► Asphaltene contaminant must be removed to a large extent from the fuel to meet the regulatory demand. ► Kinetics for hydrodeasphaltenization are estimated via experimentation and modeling. ► Using the kinetic parameters, a full process model for the trickle bed reactor (TBR) is developed. ► The model is used for simulating the behavior of the TBR to get further insight of the process. ► The influences of operating conditions in the hydrodeasphaltenization process are reported. -- Abstract: Fossil fuel is still a predominant source of the global energy requirement. Hydrotreating of whole crude oil has the ability to increase the productivity of middle distillate fractions and improve the fuel quality by simultaneously reducing contaminants such as sulfur, nitrogen, vanadium, nickel and asphaltene to the levels required by the regulatory bodies. Hydrotreating is usually carried out in a trickle bed reactor (TBR) where hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodemetallization (HDM) and hydrodeasphaltenization (HDAs) reactions take place simultaneously. To develop a detailed and a validated TBR process model which can be used for design and optimization of the hydrotreating process, it is essential to develop kinetic models for each of these reactions. Most recently, the authors have developed kinetic models for all of these chemical reactions except that of HDAs. In this work, a kinetic model (in terms of kinetic parameters) for the HDAs reaction in the TBR is developed. A three phase TBR process model incorporating the HDAs reactions with unknown kinetic parameters is developed. Also, a series of experiments has been conducted in an isothermal TBR under different operating conditions affecting the removal of asphaltene. The unknown kinetic parameters are then obtained by applying a parameter estimation technique based on minimization of the sum of square errors (SSEs) between the experimental and predicted concentrations of

  4. SAFIRA project B.3.3: in-situ-treatment of contaminated ground water by catalytic oxidation. Final report; Sanierungsforschung in regional kontaminierten Aquiferen (SAFIRA). Projekt B.3.3: In situ-Behandlung von kontaminierten Grundwaessern durch katalytische Oxidation. Teilvorhaben 1: Untersuchungen im Labormassstab. Teilvorhaben 2: Tests in der bench-scale-Anlage und Teilvorhaben 3: Die Erprobung in der Pilotanlage am Modellstandort. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Hofmann, J.; Haentzschel, D.; Freier, U.; Wecks, M.

    2003-06-27

    A new technology for treatment of contaminated ground water was developed. In this process heterogeneous catalysts (full metal catalyst, mixed oxide catalyst or iron-containing zeolites) in combination with hydrogen peroxide are used. In the reactor catalytic oxidation and aerob biological degradation occur simultaneously. A complete degradation of chlorobenzene was observed in a bench-scale-equipment (2 liter) and also in the pilot plant at the model site located in Bitterfeld (30 liter reactor). The technology can be applied to the ground and waste water treatment. (orig.) [German] Fuer die Behandlung von Grundwaessern, die mit organischen Schadstoffen belastet sind, wurde ein neuartiges Verfahren entwickelt. Bei der katalytischen Oxidation werden heterogene Katalysatoren in Form von Vollmetall-, Mischoxid- und Traegerkatalysatoren in Verbindung mit Wasserstoffperoxid als Oxidationsmittel eingesetzt. In den Katalysereaktoren laufen die heterogen-katalytische Oxidation und der aerob-biologische Abbau nebeneinander ab. Es werden synergistische Effekte erzielt. Mit dem Verfahren wurde in einer bench-scale-Angle (2 Liter) und in der Pilotanlage am Modellstandort in Bitterfeld (30 l Reaktor) der Schadstoff Chlorbenzol vollstaendig umgesetzt. Das Verfahren kann zur Grund- und Abwasserbehandlung eingesetzt werden. (orig.)

  5. Bench press exercise: the key points.

    Science.gov (United States)

    Padulo, J; Laffaye, G; Chaouachi, A; Chamari, K

    2015-06-01

    The bench press exercise (BPE) is receiving increasing interest as a field testing, training/therapeutic modality to improve neuromuscular performance or to increase bone mass density. Several studies have been performed using BPE as a standard for increasing upper-limb strength. For this purpose, the position of the bar, the loads, the sets, the number of repetitions, the recovery time in-between sets, the movement speed, the muscular work and the use of the determination of the one repetition maximum (1-RM) are the classical tools investigated in the literature that have been shown to affect the BPE effect on neuromuscular. The goal of the present short review is to make a picture of the current knowledge on the bench press exercise, which could be very helpful for a better understanding of this standard movement and its effects. Based on the related literature, several recommendations on these key points are presented here.

  6. A PMT-Block test bench

    International Nuclear Information System (INIS)

    Adragna, P.; Antonaki, A.

    2006-01-01

    The front-end electronics of the ATLAS hadronic calorimeter (Tile Cal) is housed in a unit, called PMT-Block. The PMT-Block is a compact instrument comprising a light mixer, a PMT together with its divider and a 3-in-1 card, which provides shaping, amplification and integration for the signals. This instrument needs to be qualified before being assembled on the detector. A PMT-Block test bench has been developed for this purpose. This test bench is a system which allows fast, albeit accurate enough, measurements of the main properties of a complete PMT-Block. The system, both hardware and software, and the protocol used for the PMT-Blocks characterization are described in detail in this report. The results obtained in the test of about 10 000 PMT-Blocks needed for the instrumentation of the ATLAS (LHC-CERN) hadronic Tile Calorimeter are also reported

  7. A PMT-Block test bench

    Energy Technology Data Exchange (ETDEWEB)

    Adragna, P [Dipartimento di Fisica ' E.Fermi' , Universita di Pisa and Istituto Nazionale di Fisica Nucleare, Sezione di Pisa, Largo B. Pontecorvo 3, Pisa 56127 (Italy); Universita degli studi di Siena, via Roma 56, 53100 Siena (Italy); Antonaki, A [Institute of Accelerating Systems and Applications, P.O. Box 17214, Athens 10024 (Greece); National Capodistrian University of Athens, 30 Panepistimiou st., Athens 10679 (Greece)] (and others)

    2006-08-01

    The front-end electronics of the ATLAS hadronic calorimeter (Tile Cal) is housed in a unit, called PMT-Block. The PMT-Block is a compact instrument comprising a light mixer, a PMT together with its divider and a 3-in-1 card, which provides shaping, amplification and integration for the signals. This instrument needs to be qualified before being assembled on the detector. A PMT-Block test bench has been developed for this purpose. This test bench is a system which allows fast, albeit accurate enough, measurements of the main properties of a complete PMT-Block. The system, both hardware and software, and the protocol used for the PMT-Blocks characterization are described in detail in this report. The results obtained in the test of about 10 000 PMT-Blocks needed for the instrumentation of the ATLAS (LHC-CERN) hadronic Tile Calorimeter are also reported.

  8. Distal clavicular osteolysis in adults: association with bench pressing intensity

    Energy Technology Data Exchange (ETDEWEB)

    Nevalainen, Mika T.; Morrison, William B.; Zoga, Adam C.; Roedl, Johannes B. [Sidney Kimmel Medical College at Thomas Jefferson University, Division of Musculoskeletal Imaging and Interventions, Department of Radiology, Thomas Jefferson University Hospital, Philadelphia, PA (United States); Ciccotti, Michael G. [Sidney Kimmel Medical College at Thomas Jefferson University, Division of Sports Medicine, Department of Orthopedic Surgery, Thomas Jefferson University Hospital, Rothman Institute, Philadelphia, PA (United States)

    2016-11-15

    To investigate the association between distal clavicular osteolysis (DCO) and bench pressing intensity. From a retrospective review of MRI shoulder reports of individuals between 20 and 40 years of age, 262 male patients with DCO and 227 age-matched male patients without DCO were selected. All patients had completed a bench pressing questionnaire. The patients' bench pressing frequency (times per week), duration (years of bench pressing), bench pressing weight (maximum bench pressing weight with one repetition = 1RM) and the ratio of bench pressing weight to body weight were compared between both groups using Chi-square and Mann-Whitney tests. The results showed that 56 % (146/262) of patients with DCO were high-intensity bench pressers (1RM more than 1.5 times the body weight) compared to 6 % (14/227) in patients without DCO. High-intensity bench pressing was a risk factor for DCO (OR = 19; 95 %CI = 11-35; p < 0.001). Low-intensity bench pressing (1RM less than 1.5 times the body weight) was not a risk factor for DCO (OR = 0.6; 95 % CI = 0.4-0.8). High frequency (>1 x /week) and duration (>5 years) of bench pressing were risk factors. In bench pressers who suffered from DCO, the mean 1RM was 283 lbs (±SD 57) compared to 209 lbs (±SD 60) in bench pressers not affected by DCO (p < 0.001, Mann-Whitney). High-intensity, but not low-intensity bench pressing is a risk factor for DCO. (orig.)

  9. Bench-scale treatability testing of biological, UV oxidation, distillation, and ion-exchange treatment of trench water from a low-level radioactive waste disposal area at West Valley, New York

    Energy Technology Data Exchange (ETDEWEB)

    Sundquist, J.A.; Gillings, J.C. [Ecology and Environment, Inc. (United States); Sonntag, T.L. [New York State Energy Research and Development Authority (United States); Denault, R.P. [Pacific Nuclear, Inc. (United States)

    1993-03-01

    Ecology and Environment, Inc. (E and E), under subcontract to Pacific Nuclear Services (PNS), conducted for the New York State Energy Research and Development Authority (NYSERDA) treatability tests to support the selection and design of a treatment system for leachate from Trench 14 of the West Valley State-Licensed, Low-Level Radioactive Waste Disposal Area (SDA). In this paper E and E presents and discusses the treatability test results and provides recommendations for the design of the full-scale treatment system.

  10. Evaluation of the Small-Tank Tetraphenylborate Process Using a Bench-Scale, 20-L Continuous Stirred Tank Reactor System at Oak Ridge National Laboratory: Results of Test 5

    International Nuclear Information System (INIS)

    Lee, D.D.

    2001-01-01

    The goal of the Savannah River Salt Waste Processing Program (SPP) is to evaluate the presently available technologies and select the most effective approach for treatment of high-level waste salt solutions currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site in Aiken, South Carolina. One of the three technologies currently being developed for this application is the Small-Tank Tetraphenylborate Process (STTP). This process uses sodium tetraphenylborate (TPB) to precipitate and remove radioactive cesium from the waste and monosodium titanate (MST) to sorb and remove radioactive strontium and actinides. Oak Ridge National Laboratory is demonstrating this process at the 1:4000 scale using a 20-L-capacity continuous-flow stirred-tank reactor (CSTR) system. Since March 1999, five operating campaigns of the 20-L CSTR have been conducted. The ultimate goal is to verify that this process, under certain extremes of operating conditions, can meet the minimum treatment criteria necessary for processing and disposing of the salt waste at the Savannah River Saltstone Facility. The waste acceptance criteria (WAC) for 137 Cs, 90 Sr, and total alpha nuclides are 137 Cs and 90 Sr are to obtain decontamination factors (DFs) of 40,000 (99.998% removal) and 26 (96.15% removal), respectively. (DF is mathematically defined as the concentration of contaminant in the waste feed divided by the concentration of contaminant in the effluent stream.)

  11. Oil removal of spent hydrotreating catalyst CoMo/Al{sub 2}O{sub 3} via a facile method with enhanced metal recovery

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yue [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Xu, Shengming, E-mail: smxu@tsinghua.edu.cn [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Beijing Key Lab of Radioactive Wastes Treatment, Tsinghua University, Beijing 100084 (China); Li, Zhen [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Wang, Jianlong [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Beijing Key Lab of Radioactive Wastes Treatment, Tsinghua University, Beijing 100084 (China); Zhao, Zhongwei [School of Metallurgy and Environment, Central South University, Changsha 410083, Hunan (China); Xu, Zhenghe, E-mail: zhenghe.xu@ualberta.ca [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Department of Chemical and Material Engineering, University of Alberta, Edmonton, Alberta T6G 1H9 (Canada)

    2016-11-15

    Highlights: • A novel approach for oil removal from spent hydrotreating catalysts has been developed. • Oil removal possibility is analyzed through surface characteristics. • Oil is successfully removed from spent catalysts via aqueous surfactant solution. • Over 98% Mo can be leached after oil removal and thermal treatment. • The proposed deoiling method helps to avoid detrimental impurity generation (CoMoO{sub 4}) and enhance metal recovery. - Abstract: Deoiling process is a key issue for recovering metal values from spent hydrotreating catalysts. The oils can be removed with organic solvents, but the industrialized application of this method is greatly hampered by the high cost and complex processes. Despite the roasting method is simple and low-cost, it generates hardest-to-recycle impurities (CoMoO{sub 4} or NiMoO{sub 4}) and enormous toxic gases. In this study, a novel and facile approach to remove oils from the spent hydrotreating catalysts is developed. Firstly, surface properties of spent catalysts are characterized to reveal the possibility of oil removal. And then, oils are removed with water solution under the conditions of 90 °C, 0.1 wt% SDS, 2.0 wt% NaOH and 10 ml/g L/S ratio for 4 h. Finally, thermal treatment and leaching tests are carried out to further explore the advantages of oil removal. The results show that no hardest-to-recycle impurity CoMoO{sub 4} is found in XPS spectra of thermally treated samples after deoiling and molybdenum is leached completely with sodium carbonate solution. It means that the proposed deoiling method can not only remove oils simply and without enormous harmful gases generating, but also avoid the generation of detrimental impurity and promote recycling of valuable metals from spent hydrotreating catalysts.

  12. Oil removal of spent hydrotreating catalyst CoMo/Al2O3 via a facile method with enhanced metal recovery.

    Science.gov (United States)

    Yang, Yue; Xu, Shengming; Li, Zhen; Wang, Jianlong; Zhao, Zhongwei; Xu, Zhenghe

    2016-11-15

    Deoiling process is a key issue for recovering metal values from spent hydrotreating catalysts. The oils can be removed with organic solvents, but the industrialized application of this method is greatly hampered by the high cost and complex processes. Despite the roasting method is simple and low-cost, it generates hardest-to-recycle impurities (CoMoO4 or NiMoO4) and enormous toxic gases. In this study, a novel and facile approach to remove oils from the spent hydrotreating catalysts is developed. Firstly, surface properties of spent catalysts are characterized to reveal the possibility of oil removal. And then, oils are removed with water solution under the conditions of 90°C, 0.1wt% SDS, 2.0wt% NaOH and 10ml/gL/S ratio for 4h. Finally, thermal treatment and leaching tests are carried out to further explore the advantages of oil removal. The results show that no hardest-to-recycle impurity CoMoO4 is found in XPS spectra of thermally treated samples after deoiling and molybdenum is leached completely with sodium carbonate solution. It means that the proposed deoiling method can not only remove oils simply and without enormous harmful gases generating, but also avoid the generation of detrimental impurity and promote recycling of valuable metals from spent hydrotreating catalysts. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Diagnostics at JINR LHEP photogun bench

    International Nuclear Information System (INIS)

    Nozdrin, M.A.; Balalykin, N.I.; Minashkin, V.F.; Shirkov, G.D.

    2016-01-01

    The photoinjector electron beam quality dramatically depends on the laser driver beam quality. For laser beam diagnostics a 'virtual cathode' system was realized at the JINR LHEP photogun bench. The system allows one to image laser beam profile at the cathode. The AVINE software complex developed in DESY Zeuthen is being used for imaging. Equipment for emittance measurement using the slit method was installed. The original emittance calculation software EmCa was created and tested with the laser beam.

  14. Modified IRC bench-scale arc melter for waste processing

    International Nuclear Information System (INIS)

    Eddy, T.L.; Sears, J.W.; Grandy, J.D.; Kong, P.C.; Watkins, A.D.

    1994-03-01

    This report describes the INEL Research Center (IRC) arc melter facility and its recent modifications. The arc melter can now be used to study volatilization of toxic and high vapor pressure metals and the effects of reducing and oxidizing (redox) states in the melt. The modifications include adding an auger feeder, a gas flow control and monitoring system, an offgas sampling and exhaust system, and a baghouse filter system, as well as improving the electrode drive, slag sampling system, temperature measurement and video monitoring and recording methods, and oxidation lance. In addition to the volatilization and redox studies, the arc melter facility has been used to produce a variety of glass/ceramic waste forms for property evaluation. Waste forms can be produced on a daily basis. Some of the melts performed are described to illustrate the melter's operating characteristics

  15. Development of continuous bench scale unit for direct liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1996-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  16. Lab and Bench-Scale Pelletization of Torrefied Wood Chips

    DEFF Research Database (Denmark)

    Shang, Lei; Nielsen, Niels Peter K.; Stelte, Wolfgang

    2013-01-01

    Combined torrefaction and pelletization is used to increase the fuel value of biomass by increasing its energy density and improving its handling and combustion properties. In the present study, a single-pellet press tool was used to screen for the effects of pellet die temperature, moisture cont...... of the torrefied pellets was higher and the particle size distribution after grinding the pellets was more uniform compared to conventional wood pellets....

  17. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    2000-01-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2)TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2)TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  18. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    1999-01-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2)TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2)TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  19. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    International Nuclear Information System (INIS)

    Unknown

    1999-01-01

    The U.S. Department of Energy (DOE), Federal Energy Technology Center (FETC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn(sub 2) TiO(sub 4) or ZnTiO(sub 3)), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO(sub 2)), is currently one of the leading sorbents. Overall chemical reactions with Zn(sub 2) TiO(sub 4) during the desulfurization (sulfidation)-regeneration cycle are shown below: Sulfidation: Zn(sub 2) TiO(sub 4)+ 2H(sub 2)S(yields) 2ZnS+ TiO(sub 2)+ 2H(sub 2)O; Regeneration: 2ZnS+ TiO(sub 2)+ 3O(sub 2)(yields) Zn(sub 2) TiO(sub 4)+ 2SO(sub 2) The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO(sub 2)

  20. Thymol Hydrogenation in Bench Scale Trickle Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Dudas, J.; Hanika, Jiří; Lepuru, J.; Barkhuysen, M.

    2005-01-01

    Roč. 19, č. 3 (2005), s. 255-262 ISSN 0352-9568 Institutional research plan: CEZ:AV0Z40720504 Keywords : thymol hydrogenation * trickle bed reactor * gas-liquid-solid reaction Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 0.632, year: 2005

  1. Bench-Scale Studies with Argentine Ion Exchange Material

    International Nuclear Information System (INIS)

    Cicero-Herman, C.A.

    2002-01-01

    The United States Department of Energy (DOE), as well as international atomic energy commission, facilities use ion exchange materials for purification of aqueous streams in the nuclear industry. Unfortunately, the use of the ion exchange materials creates a waste stream that can be very high in both organic and radioactive constituents. Therefore, disposal of the spent resins often becomes an economic problem because of the large volumes of resin produced and the relatively few technologies that are capable of economically stabilizing this waste. Vitrification of this waste stream presents a reasonable disposable alternative because of its inherent destruction capabilities, the volume reductions obtainable, and the durable product that it produces

  2. Development of continuous bench scale unit for direct liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Wang Lai [Korea Inst. of Energy and Resources, Daeduk (Korea, Republic of)

    1995-12-31

    Batch coal liquefaction experiments using tubing bombs and continuous experiments by cell liquefaction test facility were carried out. The main purpose was to maximize the coal liquefaction yields by improving the activity of coal dissolution catalysts which are oil soluble transition metal naphthenate and to supplement the incomplete research results. In the meantime, the study on the reaction characteristics of coal liquefaction and coal liquid upgrading catalyst upon sulfiding conditions and phosphorous addition have been conducted (author). 102 refs., 35 figs.

  3. Implementation of Canflex bundle manufacture - from 'bench scale' to production

    International Nuclear Information System (INIS)

    Pant, A.

    1999-01-01

    Zircatec Precision Industries (ZPI) has been involved with the development of the 43 element Canflex bundle design since 1986. This development included several 'prototype' campaigns involving the manufacture of small quantities of test bundles using enriched fuel. Manufacturing and inspection methods for this fuel were developed at ZPI as the design progressed. The most recent campaign involved the production of 26 bundles of the final Canflex design for a demonstration irradiation in the Point Lepreau Generating Station. This presentation will explore issues pertaining to the introduction of a new product line from initial trial quantities to full production levels. The Canflex fuel experience and a brief review of development efforts will be used as an example. (author)

  4. Electrodialytic remediation of air pollution control residues in bench scale

    DEFF Research Database (Denmark)

    Jensen, Pernille Erland; Ferreira, Celia; Hansen, Henrik K.

    2008-01-01

    Air pollution control (APC) residue from municipal solid waste incineration (MSWI) is considered a hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist in different regions; however, most commercial soluti...

  5. Comparison of Myoelectric Activity of a Selection of Upper Extremity Muscles while Doing Bench Press in Two Training Methods of TRX and Barbell Bench Press

    Directory of Open Access Journals (Sweden)

    Ahmad Reza Zibaei

    2016-12-01

    Conclusion: Considering these results it can be maintained that TRX bench press resistance training can be an alternative and effective practice for barbell bench press because, given the results, it can be appreciated that TRX bench press, dips low in the trunk, can lead to muscle activity close to the level of muscle activity during the barbell bench press drill.

  6. Two-Nozzle Flame Spray Pyrolysis (FSP) Synthesis of CoMo/Al2O3 Hydrotreating Catalysts

    DEFF Research Database (Denmark)

    Høj, Martin; Pham, David K.; Brorson, Michael

    2013-01-01

    and the hydrodenitrogenation activity improved from 70 to 90 % relative activity. This suggests that better promotion of the active molybdenum sulfide phase was achieved when using two-nozzle FSP synthesis, probably due to less formation of the undesired phase CoAl2O4, which makes Co unavailable for promotion.......Two-nozzle frame spray analysis (FSP) synthesis of CoMo/Al2O3 where Co and Al are sprayed in separate flames was applied to minimize the formation of CoAl2O4 observed in one-nozzle flame spray pyrolysis (FSP) synthesis and the materials were characterized by N2-adsorption (BET), X-ray diffraction...... (XRD), UV–vis diffuse reflectance spectroscopy, Raman spectroscopy, transmission electron microscopy, and catalytic performances in hydrotreating. By varying the flame mixing distances (81–175 mm) the amount of CoAl2O4 could be minimized. As evidenced by UV–vis spectroscopy, CoAl2O4 was detected only...

  7. Field-to-Fuel Performance Testing of Lignocellulosic Feedstocks: An Integrated Study of the Fast Pyrolysis/Hydrotreating Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Daniel T.; Westover, Tyler; Carpenter, Daniel; Santosa, Daniel M.; Emerson, Rachel; Deutch, Steve; Starace, Anne; Kutnyakov, Igor V.; Lukins, Craig D.

    2015-05-21

    Feedstock composition can affect final fuel yields and quality for the fast pyrolysis and hydrotreatment upgrading pathway. However, previous studies have focused on individual unit operations rather than the integrated system. In this study, a suite of six pure lignocellulosic feedstocks (clean pine, whole pine, tulip poplar, hybrid poplar, switchgrass, and corn stover) and two blends (equal weight percentages whole pine/tulip poplar/switchgrass and whole pine/clean pine/hybrid poplar) were prepared and characterized at Idaho National Laboratory. These blends then underwent fast pyrolysis at the National Renewable Energy Laboratory and hydrotreatment at Pacific Northwest National Laboratory. Although some feedstocks showed a high fast pyrolysis bio-oil yield such as tulip poplar at 57%, high yields in the hydrotreater were not always observed. Results showed overall fuel yields of 15% (switchgrass), 18% (corn stover), 23% (tulip poplar, Blend 1, Blend 2), 24% (whole pine, hybrid poplar) and 27% (clean pine). Simulated distillation of the upgraded oils indicated that the gasoline fraction varied from 39% (clean pine) to 51% (corn stover), while the diesel fraction ranged from 40% (corn stover) to 46% (tulip poplar). Little variation was seen in the jet fuel fraction at 11 to 12%. Hydrogen consumption during hydrotreating, a major factor in the economic feasibility of the integrated process, ranged from 0.051 g/g dry feed (tulip poplar) to 0.070 g/g dry feed (clean pine).

  8. Geologic bench marks by terrestrial photography

    Science.gov (United States)

    Malde, Harold E.

    1973-01-01

    A photograph made with a level camera, if taken at a known height above a permanent mark on the ground, can be later repeated with exactness for measurement of changes in terrain. Such a photograph is one of several means for establishing a geologic bench mark and is especially useful for monitoring the subtle qualities of a landscape that are otherwise hard to map and describe, including the effects of man's use. Moreover, the geometry of such a photograph provides the same angular measurements between objects as can be made with a transit. A measurement of distance on a single photograph, however, requires control points. These can be surveyed at any convenient time, not necessarily when the initial photograph is made. Distances can also be determined by simple stereophotography from a base line of suitable length.

  9. Kinematics and kinetics of the bench-press and bench-pull exercises in a strength-trained sporting population.

    Science.gov (United States)

    Pearson, Simon N; Cronin, John B; Hume, Patria A; Slyfield, David

    2009-09-01

    Understanding how loading affects power production in resistance training is a key step in identifying the most optimal way of training muscular power - an essential trait in most sporting movements. Twelve elite male sailors with extensive strength-training experience participated in a comparison of kinematics and kinetics from the upper body musculature, with upper body push (bench press) and pull (bench pull) movements performed across loads of 10-100% of one repetition maximum (1RM). 1RM strength and force were shown to be greater in the bench press, while velocity and power outputs were greater for the bench pull across the range of loads. While power output was at a similar level for the two movements at a low load (10% 1RM), significantly greater power outputs were observed for the bench pull in comparison to the bench press with increased load. Power output (Pmax) was maximized at higher relative loads for both mean and peak power in the bench pull (78.6 +/- 5.7% and 70.4 +/- 5.4% of 1RM) compared to the bench press (53.3 +/- 1.7% and 49.7 +/- 4.4% of 1RM). Findings can most likely be attributed to differences in muscle architecture, which may have training implications for these muscles.

  10. Terrace erosion and sediment transport model: a new tool for soil conservation planning in bench-terraced steeplands.

    NARCIS (Netherlands)

    van Dijk, A.I.J.M.; Bruijnzeel, L.A.

    2003-01-01

    Despite widespread bench-terracing soil erosion remains a major problem in Java's uplands. To elucidate the causes for this lack of impact, runoff and erosion processes were studied at a variety of spatial scales within a volcanic catchment in West Java. Research indicated that soil loss occurs via

  11. From biomass to fuels: hydrotreating of oxygen-containing feeds on a CoMo/Al{sub 2}O{sub 3} hydrodesulfurization catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Viljava, T.-R.

    2001-07-01

    thus facilitating the adsorption of the reactant on the active site of the catalyst. Otherwise, the HDS rate declined due to strong competitive adsorption of the oxygen-containing compounds on the active sites of the catalyst, and due to the formation of less reactive sulfur compounds via methyl transfer from the methoxy groups to sulfur. In conclusion, simultaneous hydrotreating of sulfur- and oxygen-containing feeds leads to strong suppression of oxygen removal reactions and usually also to a decrease in the efficiency of sulfur removal. The effect of low molecular weight sulfiding agents, H{sub 2}S and CS{sub 2} on HDO of phenol and anisole was studied first in a batch and then in a flow reactor to see whether the addition of sulfiding agents might improve the stability of the presulfided catalyst without decreasing the rate and without affecting the selectivity of HDO. The HDO rate of phenol decreased noticeably in the presence of CS{sub 2}, in the batch reactor, and the selectivities of the HDO reaction paths were changed: the hydrogenation-hydrogenolysis route was less sensitive to the sulfur compound than was the CA{sub Arom}-O hydrogenolysis path. At higher concentrations of the sulfiding agent, also the hydrogenation route became inhibited. With anisole, there was an increase in the rate of demethylation to phenol, but oxygen removal was virtually unaffected. In the flow reactor studies, the formation of hydrogenated HDO products of phenol remained constant up to the highest concentration of H{sub 2}S in the feed, but a dramatic decrease in the yield of the aromatic reaction product occurred already at low concentrations of H{sub 2}S. Selective inhibition of one of the HDO paths confirmed the presence of at least two kinds of active sites on the catalyst. This means that addition of an inhibitor can be used to adjust the product distribution of HDO in process scale. However, the presulfided catalyst deactivated with time on stream also in the presence of

  12. Bench for mechanical cleaning of circular welded joints

    International Nuclear Information System (INIS)

    Sklifasovskij, V.M.

    1986-01-01

    A special bench for weld reinforcement removal and mechanical cleaning of the heat affected zones was designed to provide for a possibility of an ultrasonic testing of welded joints in the course of steam generator section fabrication. The bench comprises a mechanized roller support for fixing and rotating the workpiece; a lap-cutting device for external machining; milling/grinding tractor for internal machining and a delivery table for tractor approach and departure. The bench performance and overall view are presented. The operation succession is described

  13. Comparison among hydrotreating technologies to produce high quality diesel; Comparacao de tecnologias de hidrotratamento para obtencao de diesel de alta qualidade

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Jorge R.D.; Rosa, Carlos A.R. da; Belato, Donizeti A.S.; Monteiro, Denise B. da R.; Monteiro, Carlos A.A.; Lima, Daniela D.S. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The PETROBRAS Refineries, over a long time, are being adapted to be able to process crude oil from Campos Basin, which today is responsible for 70-80% of total Brazilian production. However the Campos Basin crude has very individual characteristics - when compared with the well known Arabian Light - and therefore it became necessary to acquire the knowledge of its behavior together with its refined products in traditional processes, in which we include the Hydrotreating (HDT). The main objective of this work is to analyze the HDT process schemes and its performance when operating with such a different feedstock, in order to achieve the product's quality requirements. (author)

  14. Comparison among hydrotreating technologies to produce high quality diesel; Comparacao de tecnologias de hidrotratamento para obtencao de diesel de alta qualidade

    Energy Technology Data Exchange (ETDEWEB)

    Lima, Jorge R.D.; Rosa, Carlos A.R. da; Belato, Donizeti A.S.; Monteiro, Denise B. da R.; Monteiro, Carlos A.A.; Lima, Daniela D.S. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The PETROBRAS Refineries, over a long time, are being adapted to be able to process crude oil from Campos Basin, which today is responsible for 70-80% of total Brazilian production. However the Campos Basin crude has very individual characteristics - when compared with the well known Arabian Light - and therefore it became necessary to acquire the knowledge of its behavior together with its refined products in traditional processes, in which we include the Hydrotreating (HDT). The main objective of this work is to analyze the HDT process schemes and its performance when operating with such a different feedstock, in order to achieve the product's quality requirements. (author)

  15. Hydrotreating and hydrocracking of Athabasca bitumen derived heavy gas oils using NiMo catalyst supported on titania modified alumina

    Energy Technology Data Exchange (ETDEWEB)

    Ferdous, D.; Bakhshi, N.N.; Dalai, A.K.; Adjaye, J. [Saskatchewan Univ., Saskatoon, SK (Canada). Dept. of Chemical Engineering, Catalysis and Chemical Reaction Engineering Laboratories]|[Syncrude Canada Ltd., Edmonton, AB (Canada)

    2006-07-01

    Different NiMo catalysts supported on titania modified Al{sub 2}O{sub 3} were synthesized and characterized in an effort to study the hydrodenitrigenation (HDN) and hydrodesulfurization (HDS) of different gas oils derived from Athabasca bitumen. The Al{sub x}O{sub 3} supports were modified by incorporating up to 9 wt per cent titanium (Ti). All modified supports as well as fresh and spent catalysts were characterized by BET surface area, pore volume and pore diameter, XRD, TPR, TPD and SEM. A trickle-bed reactor using 3 different gas oils from the Athabasca bitumen was used to test the initial activity of these catalysts. The 3 oils were light gas oil (LGO), heavy gas oil (HGO) and blended gas oil having 50 per cent LGO and 50 per cent HGO. The study showed that nitrogen conversion increased for all the gas oils when Ti was incorporated into the alumina. With an increase in Ti concentrations from 0 to 6 wt per cent, nitrogen conversion increased from 57-69.5 wt per cent, 75-80.2 wt per cent, 83-91.5 wt per cent and for LGO, HGO and blended, respectively. Nearly 86 wt per cent sulphur conversion was obtained for all Ti concentrations for LGO, while HGO and blended sulphur conversions were in the range of 96-97 wt per cent. Detailed hydrotreating and hydrocracking of HGO was then performed using the 6 wt per cent Ti modified catalyst because it achieved the maximum nitrogen conversion. This paper also presented the temperature, pressure and liquid hourly space velocity for this catalyst along with the maximum nitrogen and sulphur conversions. Results were compared with those of commercial catalysts. tabs., figs.

  16. Scales

    Science.gov (United States)

    Scales are a visible peeling or flaking of outer skin layers. These layers are called the stratum ... Scales may be caused by dry skin, certain inflammatory skin conditions, or infections. Examples of disorders that ...

  17. Retrofit designs for small bench-type blood cell counters.

    Science.gov (United States)

    Ferris, C D

    1991-01-01

    This paper describes several retrofit designs to correct operational problems associated with small bench-type blood cell counters. Replacement electronic circuits as well as modifications to the vacuum systems are discussed.

  18. Additive Manufactured Coronagraph Bench for Detection of Exoplanets

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to use additive manufacturing (AM) to build a Coronagraph Bench engineering test unit.  The versatility inherent in the 3D-printing process allows for a...

  19. Effect of nutrient sources on bench scale vinegar production using response surface methodology Efeito das fontes de nutrientes sobre a produção de vinagre em escala de bancada, usando-se a metodologia de superfície de resposta

    Directory of Open Access Journals (Sweden)

    Joelma M. Ferreira

    2005-03-01

    Full Text Available The present work aims to evaluate on a bench scale, the effects of nitrogen and phosphorous nutrient source concentrations in vinegar production, a process that is used by small scale industries in the State of Paraiba. The response surface methodology has been utilized for modeling and optimization of the fermentation process. Initially a 2³ complete factorial design was used, where the effects of initial concentrations of ethyl alcohol, phosphorous and nitrogen sources were observed. After this analysis the concentration range of the nutrient variables were extended and a two level plus a star configuration factorial experimental design was performed. The experimental values are well represented by the linear and quadratic model equations obtained. The optimum concentration of ethanol was 4% in which the yield and the productivity of the acetic acid were maximized to the values of 70% and 0.87 g L-1 h-1 respectively, for a 24 hours fermentation period. The evaluation of the quadratic models showed that the yield of vinegar is maximized from 28.1 to 51.04% and the productivity from 0.69 to 1.29 g L-1 h-1 when the concentration of the nitrogen nutrient in the medium is increased from 0.2 to 2.3 g mL-1. Thus, at the optimized nitrogen nutrient concentration both the yield and the productivity of the vinegar are increased by 1.85 times.Objetivou-se com o presente trabalho, estudar em escala de bancada, os efeitos de concentrações de fontes dos nutrientes nitrogênio e fósforo sobre a produção de vinagre de álcool, um processo muito utilizado nas indústrias de pequeno porte do Estado da Paraíba. A metodologia de superfície de resposta foi usada na modelagem e otimização de processo de fermentação acética. Inicialmente, a metodologia de planejamento fatorial completo 2³ foi utilizada, onde os efeitos das concentrações iniciais de etanol, de fontes de fósforo e de nitrogênio foram observados. Após esta análise as faixas das

  20. Cellular and Molecular Anesthesia: from Bench to Bedside

    Directory of Open Access Journals (Sweden)

    Ali Dabbagh

    2015-12-01

    Full Text Available Cellular and Molecular Anesthesia: from Bench to BedsideIn the current practice of anesthesia, each day, anesthesiologists deal with a great work: they use the cellular mechanisms of drug molecules to induce their desired effects for induction and maintenance of anesthesia to achieve appropriate tolerance of surgery and its pain, modulation of stress response, sedation needed for performing a variety of procedures, emergency anesthesia care, acute and chronic pain management or other everyday jobs of anesthesiologists during perioperative period.As a matter of fact, molecular anesthesia has been cited for more than 6 decades though in avery limited scale. In 1956, the molecular mechanisms of morphine and pethidine are described (1. Pauling in 1961 published an article in Science describing a molecular theorey for general anesthesia (2.In its report “the World in 2025”, Thomson Reuters has predicted clinical medicine would be the most active research front; while molecular biology has the 9th rank (3. But are we still practicing in clinic the same as today?In fact, the future trend of anesthesia is highly dependent on finding the novel cellular and molecular mechanisms and the possible interactions of the newly discovered molecules and inreraction mechanisms with organ systems. Today, we emphasize on the role of pharmacologists, physiologists, immunologists, anatomists, embryologists, geneticians, cellular medicine specialists, physicists and other basic science specialists; some very interesting examples are published in this volume of the Journal (4-7.However, changes that have well started now would “revolutionize” our daily practice during the next decade in such a way that it will change the basis of medicine: presumably we will have a new model medicine known as “personalized medicine” or “precision medicine”. In this approach, the content of each patient’s genes accompanied with his/her cellular and molecular analysis is

  1. HEV Test Bench Based on CAN Bus Sensor Communication

    Directory of Open Access Journals (Sweden)

    Shupeng ZHAO

    2014-02-01

    Full Text Available The HEV test bench based on Controller Area Network bus was studied and developed. Control system of HEV power test bench used the CAN bus technology. The application of CAN bus technology on control system development has opened up a new research direction for domestic automobile experimental platform. The HEV power control system development work was completed, including power master controller, electric throttle controller, driving simulation platform, CAN2.0 B communication protocol procedures for formulation, CAN communication monitoring system, the simulation model based on MATLAB code automatic generation technology research, etc. Maximum absorption power of the test bench is 90 kW, the test bench top speed is 6000 r/min, the CAN communication data baud rate is 10~500 k, the conventional electric measurement parameter part precision satisfies the requirement of development of HEV. On the HEV test bench the result of regenerative braking experiment shows that the result got by the test bench was closer to the results got by outdoor road test. And the fuel consumption experiment test results show that the HEV fuel consumption and the charge-discharge character are in linear relationship. The establishment of the test platform for the evaluation of the development of hybrid electric vehicle and power provides physical simulation and test platform.

  2. Correlating optical bench performance with clinical defocus curves in varifocal and trifocal intraocular lenses.

    Science.gov (United States)

    Plaza-Puche, Ana B; Alió, Jorge L; MacRae, Scott; Zheleznyak, Len; Sala, Esperanza; Yoon, Geunyoung

    2015-05-01

    To investigate the correlations existing between a trifocal intraocular lens (IOL) and a varifocal IOL using the "ex vivo" optical bench through-focus image quality analysis and the clinical visual performance in real patients by study of the defocus curves. This prospective, consecutive, nonrandomized, comparative study included a total of 64 eyes of 42 patients. Three groups of eyes were differentiated according to the IOL implanted: 22 eyes implanted with the varifocal Lentis Mplus LS-313 IOL (Oculentis GmbH, Berlin, Germany); 22 eyes implanted with the trifocal FineVision IOL (Physiol, Liege, Belgium), and 20 eyes implanted with the monofocal Acrysof SA60AT IOL (Alcon Laboratories, Inc., Fort Worth, TX). Visual outcomes and defocus curve were evaluated postoperatively. Optical bench through-focus performance was quantified by computing an image quality metric and the cross-correlation coefficient between an unaberrated reference image and captured retinal images from a model eye with a 3.0-mm artificial pupil. Statistically significant differences among defocus curves of different IOLs were detected for the levels of defocus from -4.00 to -1.00 diopters (D) (P < .01). Significant correlations were found between the optical bench image quality metric results and logMAR visual acuity scale in all groups (Lentis Mplus group: r = -0.97, P < .01; FineVision group: r = -0.82, P < .01; Acrys of group: r = -0.99, P < .01). Linear predicting models were obtained. Significant correlations were found between logMAR visual acuity and image quality metric for the multifocal and monofocal IOLs analyzed. This finding enables surgeons to predict visual outcomes from the optical bench analysis. Copyright 2015, SLACK Incorporated.

  3. Development of Fuzzy Logic Controller for Quanser Bench-Top Helicopter

    Science.gov (United States)

    Jafri, M. H.; Mansor, H.; Gunawan, T. S.

    2017-11-01

    Bench-top helicopter is a laboratory scale helicopter that usually used as a testing bench of the real helicopter behavior. This helicopter is a 3 Degree of Freedom (DOF) helicopter which works by three different axes wshich are elevation, pitch and travel. Thus, fuzzy logic controller has been proposed to be implemented into Quanser bench-top helicopter because of its ability to work with non-linear system. The objective for this project is to design and apply fuzzy logic controller for Quanser bench-top helicopter. Other than that, fuzzy logic controller performance system has been simulated to analyze and verify its behavior over existing PID controller by using Matlab & Simulink software. In this research, fuzzy logic controller has been designed to control the elevation angle. After simulation has been performed, it can be seen that simulation result shows that fuzzy logic elevation control is working for 4°, 5° and 6°. These three angles produce zero steady state error and has a fast response. Other than that, performance comparisons have been performed between fuzzy logic controller and PID controller. Fuzzy logic elevation control has a better performance compared to PID controller where lower percentage overshoot and faster settling time have been achieved in 4°, 5° and 6° step response test. Both controller are have zero steady state error but fuzzy logic controller is managed to produce a better performance in term of settling time and percentage overshoot which make the proposed controller is reliable compared to the existing PID controller.

  4. Velocity- and power-load relationships of the bench pull vs. bench press exercises.

    Science.gov (United States)

    Sánchez-Medina, L; González-Badillo, J J; Pérez, C E; Pallarés, J G

    2014-03-01

    This study compared the velocity- and power-load relationships of the antagonistic upper-body exercises of prone bench pull (PBP) and bench press (BP). 75 resistance-trained athletes performed a progressive loading test in each exercise up to the one-repetition maximum (1RM) in random order. Velocity and power output across the 30-100% 1RM were significantly higher for PBP, whereas 1RM strength was greater for BP. A very close relationship was observed between relative load and mean propulsive velocity for both BP (R2=0.97) and PBP (R2=0.94) which enables us to estimate %1RM from velocity using the obtained prediction equations. Important differences in the load that maximizes power output (Pmax) and the power profiles of both exercises were found according to the outcome variable used: mean (MP), peak (PP) or mean propulsive power (MPP). When MP was considered, the Pmax load was higher (56% BP, 70% PBP) than when PP (37% BP, 41% PBP) or MPP (37% BP, 46% PBP) were used. For each variable there was a broad range of loads at which power output was not significantly different. The differing velocity- and power-load relationships between PBP and BP seem attributable to the distinct muscle architecture and moment arm levers involved in these exercises. © Georg Thieme Verlag KG Stuttgart · New York.

  5. The Effects of Bench Press Variations in Competitive Athletes on Muscle Activity and Performance

    OpenAIRE

    Saeterbakken, Atle Hole; Mo, Dag-Andr?; Scott, Suzanne; Andersen, Vidar

    2017-01-01

    Abstract The aim of the study was to compare the EMG activity performing 6RM competition style bench press (flat bench-wide grip) with 1) medium and narrow grip widths on a flat bench and 1) inclined and declined bench positions with a wide grip. Twelve bench press athletes competing at national and international level participated in the study. EMG activity was measured in the pectoralis major, anterior and posterior deltoid, biceps brachii, triceps brachii and latissimus dorsi. Non-signific...

  6. Elbow joint fatigue and bench-press training.

    Science.gov (United States)

    Huang, Yen-Po; Chou, You-Li; Chen, Feng-Chun; Wang, Rong-Tyai; Huang, Ming-Jer; Chou, Paul Pei-Hsi

    2014-01-01

    Bench-press exercises are among the most common form of training exercise for the upper extremity because they yield a notable improvement in both muscle strength and muscle endurance. The literature contains various investigations into the effects of different bench-press positions on the degree of muscle activation. However, the effects of fatigue on the muscular performance and kinetics of the elbow joint are not understood fully. To investigate the effects of fatigue on the kinetics and myodynamic performance of the elbow joint in bench-press training. Controlled laboratory study. Motion research laboratory. A total of 18 physically healthy male students (age = 19.6 ± 0.8 years, height = 168.7 ± 5.5 cm, mass = 69.6 ± 8.6 kg) participated in the investigation. All participants were right-hand dominant, and none had a history of upper extremity injuries or disorders. Participants performed bench-press training until fatigued. Maximal possible number of repetitions, cycle time, myodynamic decline rate, elbow-joint force, and elbow-joint moment. We observed a difference in cycle time in the initial (2.1 ± 0.42 seconds) and fatigue (2.58 ± 0.46 seconds) stages of the bench-press exercise (P = .04). As the participants fatigued, we observed an increase in the medial-lateral force (P = .03) and internal-external moment (P ≤ .04) acting on the elbow joint. Moreover, a reduction in the elbow muscle strength was observed in the elbow extension-flexion (P ≤ .003) and forearm supination-pronation (P ≤ .001) conditions. The results suggest that performing bench-press exercises to the point of fatigue increases elbow-joint loading and may further increase the risk of injury. Therefore, when clinicians design bench-press exercise regimens for general athletic training, muscle strengthening, or physical rehabilitation, they should control carefully the maximal number of repetitions.

  7. Movement Features Which Describe the Flat Bench Press

    Directory of Open Access Journals (Sweden)

    Król Henryk

    2017-06-01

    Full Text Available Introduction. In sport technique studies, motion features can be useful as they have a certain defined measure [1]. In this work, we examined the following three features: the structure of the movement (all the characteristics of the movement, the fluency of the movement, and the rhythm of the movement. The aim of the study was to determine the usefulness of the selected movement features in the evaluation of the flat bench press. The protocol of the study included a flat bench press with free weights and a “touch-and-go” technique. Material and methods. The study involved twenty healthy men; however, only two were selected for analysis. The first subject was a 25-year-old powerlifter (body mass = 95 kg; body height = 182 cm; 1-RM in flat bench press = 145 kg. The second one was a 25-year-old bodybuilder (body mass = 77 kg; body height = 175 cm; 1-RM in flat bench press = 100 kg. The subjects performed consecutive sets of a single repetition of flat bench pressing with an increasing load (70, 80, 90, and 100% 1-RM, with the anticipated maximum weight, until the completion of one repetition maximum. Multidimensional movement analysis was made with the measuring system Smart-E (BTS, Italy, which consisted of six infrared cameras (120 Hz and a wireless module to measure muscle bioelectric activity (Pocket EMG. Results. It was demonstrated that the internal structure of the bench press performed by the bodybuilder and the powerlifter was different. As the time-history of barbell kinematics (the acceleration-time curve showed, with increased loading of the barbell, the rhythm of the flat bench press changed, and the fluidity of the movement worsened.

  8. The structure and function of supported molybdenum nitride and molybdenum carbide hydrotreating catalysts

    Science.gov (United States)

    Dolce, Gregory Martin

    1997-11-01

    -dimensional raft-like particles. The HDN activity of the nitrides decreased as the loading increased, while that of the carbides was relatively constant. Carbon monoxide and methylamine adsorbed on the same types of sites on the nitrides and carbides. Infrared spectroscopy and temperature programmed desorption revealed that some methylamine underwent HDN on the nitrides and carbides. Carbon monoxide appeared to adsorb on two types of sites. One type of site adsorbed CO which desorbed upon heating while the other type of site adsorbed CO which dissociated when the material was heated. The relative amounts of desorbed CO and methylamine scaled with the activity of the nitrides suggesting that CO and methylamine titrated the active sites. It appeared that the active sites of the supported carbides were different from those on the supported nitrides. It was proposed that the active sites on the supported nitrides were at the perimeter of the two-dimensional particles while the active sites of the carbides were "on top" of the particles.

  9. New pocket tools for Physics: create a star on one's laboratory bench

    International Nuclear Information System (INIS)

    Larousserie, D.

    2001-01-01

    Big science means huge investment in giant physics instruments like particle accelerators or fusion reactors. Today this way of making physics enters in competition with more bench-scale research, this research requires less financial means and then can be developed in university laboratories. This trend has been made possible by the recent technological progress in the field of power lasers. A source of X-radiation, similar to that obtained from a big synchrotron can be designed by using adequate lasers. Thermonuclear reactions have been recently produced in laser targets. (A.C.)

  10. The HSOB GAIA: a cryogenic high stability cesic optical bench for missions requiring sub-nanometric optical stability

    Science.gov (United States)

    Courteau, Pascal; Poupinet, Anne; Kroedel, Mathias; Sarri, Giuseppe

    2017-11-01

    Global astrometry, very demanding in term of stability, requires extremely stable material for optical bench. CeSiC developed by ECM and Alcatel Alenia Space for mirrors and high stability structures, offers the best compromise in term of structural strength, stability and very high lightweight capability, with characteristics leading to be insensitive to thermo-elastic at cryogenic T°. The HSOB GAIA study realised by Alcatel Alenia Space under ESA contract aimed to design, develop and test a full scale representative High Stability Optical Bench in CeSiC. The bench has been equipped with SAGEIS-CSO laser metrology system MOUSE1, Michelson interferometer composed of integrated optics with a nm resolution. The HSOB bench has been submitted to an homogeneous T° step under vacuum to characterise the homothetic behaviour of its two arms. The quite negligible inter-arms differential measured with a nm range reproducibility, demonstrates that a complete 3D structure in CeSiC has the same CTE homogeneity as characterisation samples, fully in line with the GAIA need (1pm at 120K). This participates to the demonstration that CeSiC properties at cryogenic T° is fully appropriate to the manufacturing of complex highly stable optical structures. This successful study confirms ECM and Alcatel Alenia Space ability to define and manufacture monolithic lightweight highly stable optical structures, based on inner cells triangular design made only possible by the unique CeSiC manufacturing process.

  11. Description and evaluation of a bench porcine model for teaching surgical residents vascular anastomosis skills

    Directory of Open Access Journals (Sweden)

    Jauch Karl-Walter

    2010-07-01

    Full Text Available Abstract Background Numerous models, of variable quality, exist to impart the complex skills required to perform vascular anastomosis. These models differ with regard to the kinds of materials used, as well as their sizes, the time needed for their preparation, their availability, and the associated costs. The present study describes a bench model that uses formalin-fixed porcine aorta, and its evaluation by young surgical residents during a recent skills course. Findings The aortic segments used were a by-product of slaughtering. They were fixed and stored after harvesting for eventual use. Ten young surgical residents participated, and each performed one end-to-side vascular anastomosis. The evaluation was a questionnaire maintaining anonymity of the participant containing questions addressing particular aspects of the model and the experiences of the trainee, along with their ratings concerning the need for a training course to learn vascular anastomosis techniques. The scoring on the survey was done using a global 6-point rating scale (Likert Scale. In addition, we ranked the present model by reviewing the current literature for models that address vascular anastomosis skills. The trainees who participated were within their first two years of training (1.25 ± 0.46. A strong agreement in terms of the necessity of training for vascular anastomosis techniques was evident among the participating trainees (5.90 ± 0.32, who had only few prior manual experiences (total number 1.50 ± 0.53. The query revealed a strong agreement that porcine aorta is a suitable model that fits the needs for training vascular anastomosis skills (5.70 ± 0.48. Only a few bench models designed to teach surgical residents vascular anastomosis techniques were available in the literature. Conclusions The preparatory and financial resources needed to perform anastomosis skills training using porcine aorta are few. The presented bench model appears to be appropriate for

  12. Bench mark spectra for high-energy neutron dosimetry

    International Nuclear Information System (INIS)

    Dierckx, R.

    1986-01-01

    To monitor radiation damage experiments, activation detectors are commonly used. The precision of the results obtained by the multiple foil analysis is largely increased by the intercalibration in bench-mark spectra. This technique is already used in dosimetry measurements for fission reactors. To produce neutron spectra similar to fusion reactor and high-energy high-intensity neutron sources (d-Li or spallation), accelerators can be used. Some possible solutions as p-Be and d-D 2 O neutron sources, useful as bench-mark spectra are described. (author)

  13. Influence of the "Slingshot" bench press training aid on bench press kinematics and neuromuscular activity in competitive powerlifters.

    Science.gov (United States)

    Dugdale, James H; Hunter, Angus; Di Virgilio, Thomas; Macgregor, Lewis J; Hamilton, D Lee

    2017-02-13

    This study examined the acute effects of the 'Slingshot' on bench-press performance, prime-mover surface electromyographic (sEMG) amplitude, and barbell velocity during maximal and submaximal bench-pressing in competitive male powerlifters. Fifteen male powerlifters (mean ± SD age: 27.05 ± 5.94 years; mass: 94.15kg; 1RM bench-press: 139.7 ± 16.79kg) participated in the study. Bench-press strength, average barbell velocity, and sEMG amplitude of the prime mover muscles (triceps brachii, pectoralis major and anterior deltoid) were measured during two conditions; 'Raw' (without use of any assistance) and 'Slingshot' [using the 'Slingshot' to perform both the weight achieved during 'Raw' 1RM testing (Raw max/SS), and absolute 1RM using the 'Slingshot' (SS)]. The results showed that the 'Slingshot' significantly increased bench press 1RM performance by a mean ± SD of 20.67kg ± 3.4kg. Barbell velocity and stick point analysis indicate that this improvement is likely driven by an increase in peak and pre-stick barbell velocity as triceps RMS was lower throughout all rep max phases with the 'Slingshot'. The 'Slingshot' also caused reductions in RMS, specifically of the triceps at all rep ranges but barbell velocity was better maintained in the last reps of all sets. These data indicate that the 'Slingshot' specifically de-loaded the triceps muscle throughout all rep ranges and provide assistance to maintaining barbell velocity under fatigue during later repetitions of multiple-repetition sets. The 'Slingshot' training aid could therefore be used in de-load phases of bench press training or as an over-reaching and velocity training aid.

  14. EMG analysis and modelling of flat bench press using artificial ...

    African Journals Online (AJOL)

    The objective of this study was to evaluate the contribution of particular muscle groups during the Flat Bench Press (FBP) with different external loads. Additionally, the authors attempted to determine whether regression models or Artificial Neural Networks (ANNs) can predict FBP results more precisely and whether they can ...

  15. Test benches for studying the properties of car tyres

    Science.gov (United States)

    Kuznetsov, N. Yu.; Fedotov, A. I.; Vlasov, V. G.

    2017-12-01

    The article describes the design of the measuring systems of test benches used to study the properties of elastic tyres. The bench has two autonomous systems - for testing the braking properties of elastic tyres rolling in a plane parallel way and for testing tyre slip properties. The system for testing braking properties determines experimental characteristics of elastic tyres as the following dependencies: longitudinal response vs time, braking torque vs slip, angular velocity vs slip, and longitudinal response vs slip. The system for studying tyre slip properties determines both steady (dependence of the lateral response in a contact area on the slipping angle) and non-steady characteristics (time variation of the slipping angle as a result of turning from -40 to +40 degrees) of tyre slip. The article presents the diagrams of bench tests of elastic tyres. The experimental results show metrological parameters and functional capabilities of the bench for studying tyre properties in driving and braking modes. The metrological indices of the recorded parameters of the measuring system for studying tyre properties are presented in the table.

  16. Bidirectional converter interface for a battery energy storage test bench

    DEFF Research Database (Denmark)

    Trintis, Ionut; Thomas, Stephan; Blank, Tobias

    2011-01-01

    This paper presents the bidirectional converter interface for a 6 kV battery energy storage test bench. The power electronic interface consists a two stage converter topology having a low voltage dc-ac grid connected converter and a new dual active bridge dc-dc converter with high transformation...

  17. Automatic integrated testing bench for tubes in translation

    International Nuclear Information System (INIS)

    Dufayet, J.P.; Perdijon, J.

    1976-01-01

    All the nondestructive tests required for receiving the cladding tubes intended for fast nuclear reactor are integrated on this bench: quality control by eddy currents and ultra-sounds, thickness and (inner and outer) diameter measurement. The linear displacement of the tube allows very high rates to be attained [fr

  18. ReaderBench: An Integrated Cohesion-Centered Framework

    NARCIS (Netherlands)

    Dascalu, Mihai; Stavarache, Lucia Larise; Dessus, Philippe; Trausan-Matu, Stefan; McNamara, Danielle S.; Bianco, Maryse

    2015-01-01

    Dascalu, M., Stavarache, L.L., Dessus, P., Trausan-Matu, S., McNamara, D.S., & Bianco, M. (2015). ReaderBench: An Integrated Cohesion-Centered Framework. In G. Conole, T. Klobucar, C. Rensing, J. Konert & É. Lavoué (Eds.), 10th European Conf. on Technology Enhanced Learning (pp. 505–508). Toledo,

  19. Bench Blasting Design for Optimum Recovery of Blocks in ...

    African Journals Online (AJOL)

    In this research work, breaking factor is used in place of powder factor since breaking is required not powder. The aim of this research work is to establish a standard breaking factor for bench blasting in dimension quarries that will improve recovery. Two cases were considered. In case 1, gun powder is used for basal ...

  20. Calibration bench of flowmeters; Banc d'etalonnage de debitmetres

    Energy Technology Data Exchange (ETDEWEB)

    Bremond, J; Da Costa, D; Calvet, A; Vieuxmaire, C

    1966-07-01

    This equipment is devoted to the comparison of signals from two turbines installed in the Cabri experimental loop. The signal is compared to the standard turbine. The characteristics and the performance of the calibration bench are presented. (A.L.B.)

  1. A Study on introduction of Bench Marking in the power industry - concentrated on the Bench Marking issue in the power industry

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Hyuck Soo [Korea Energy Economics Institute, Euiwang (Korea)

    1998-08-01

    Recently it takes too much pains for enterprises to be adapted to the more complicated social structure. There are no guarantees to survive in competition only with improving service quality of a product, reducing cost by improving production efficiency, and reducing labors. To survive in a keen competition, it is important to acquire new management techniques and management theories. Among them, a benchmarking technique, improving competitive power through the analysis of top-ranking companies or companies with excellent results in a comparative sector, is in the spotlight recently. Therefore, the approaches to bench marking were discussed with the focus on the adaptation of KEPCO with a new paradigm. However, this study contained the limit of applying benchmarking technique due to its huge scale. Therefore, it was focused on brining up benchmarking issue by reflecting the basic problems of power industry to the developed countries. (author). 29 refs., 16 figs., 41 tabs.

  2. Comparison of concentric and eccentric bench press repetitions to failure.

    Science.gov (United States)

    Kelly, Stephen B; Brown, Lee E; Hooker, Steven P; Swan, Pamela D; Buman, Matthew P; Alvar, Brent A; Black, Laurie E

    2015-04-01

    Eccentric muscle actions (ECC) are characterized by muscle lengthening, despite actin-myosin crossbridge formation. Muscles acting eccentrically are capable of producing higher levels of force compared with muscles acting concentrically. The purpose of this study was to determine whether ECC bench press yields greater strength than concentric (CON) as determined by 1 repetition maximum (1RM). Additionally, a comparison was made examining differences in the number of repetitions to failure at different relative intensities of 1RM. Thirty healthy men (age = 24.63 ± 5.6 years) were tested for 1RM in CON and ECC bench press and the number of repetitions completed at 60, 70, 80, and 90% 1RM. For CON repetitions, the weight was mechanically lowered to the chest, and the participant pressed it up until the elbows were fully extended. The ECC bench press consisted of lowering a barbell from a fully extended elbow position to the chest in a continuous controlled manner for 3 seconds as determined by electronic metronome. Paired t-tests showed that ECC 1RM (115.99 ± 31.08 kg) was significantly (p ≤ 0.05) greater than CON 1RM (93.56 ± 26.56 kg), and the number of repetitions completed at 90% 1RM was significantly (p ≤ 0.05) greater in ECC (7.67 ± 3.24) as compared with CON (4.57 ± 2.21). There were no significant differences in number of completed repetitions during CON and ECC bench press at 60, 70, and 80% 1RM. These data indicate that ECC actions yield increased force capabilities (∼120%) as compared with CON in the bench press and may be less prone to fatigue, especially at higher intensities. These differences suggest a need to develop unique strategies for training eccentrically.

  3. Cost-benefit of bench terraces, a case study in Peru

    NARCIS (Netherlands)

    Posthumus, H.; Graaff, de J.

    2005-01-01

    Soil and water conservation measures like bench terraces can reduce erosion in highland crop production. A cost-benefit analysis for 11 cases of bench terraces was undertaken on the basis of both measured data and data obtained from farmers. It showed that the profitability of bench terraces was

  4. The Effects of Bench Press Variations in Competitive Athletes on Muscle Activity and Performance.

    Science.gov (United States)

    Saeterbakken, Atle Hole; Mo, Dag-André; Scott, Suzanne; Andersen, Vidar

    2017-06-01

    The aim of the study was to compare the EMG activity performing 6RM competition style bench press (flat bench-wide grip) with 1) medium and narrow grip widths on a flat bench and 1) inclined and declined bench positions with a wide grip. Twelve bench press athletes competing at national and international level participated in the study. EMG activity was measured in the pectoralis major, anterior and posterior deltoid, biceps brachii, triceps brachii and latissimus dorsi. Non-significant differences in activation were observed between the three bench positions with the exception of 58.5-62.6% lower triceps brachii activation, but 48.3-68.7% greater biceps brachii activation in the inclined bench compared with the flat and declined bench position. Comparing the three grip widths, non-significant differences in activations were observed, with the exception of 25.9-30.5% lower EMG activity in the biceps brachii using a narrow grip, compared to the medium and wide grip conditions. The 6-RM loads were 5.8-11.1% greater using a medium and wide grip compared to narrow grip width and 18.5-21.5% lower in the inclined bench position compared with flat and declined. Comparing the EMG activity during the competition bench press style with either the inclined and declined bench position (wide grip) or using a narrow and medium grip (flat bench), only resulted in different EMG activity in the biceps- and triceps brachii. The 6RM loads varied with each bench press variation and we recommend the use of a wide grip on a flat bench during high load hypertrophy training to bench press athletes.

  5. Analysis of the reactivity of sulphur compounds in petroleum cuts: kinetics and modelling of hydro-treating; Analyse de la reactivite des composes soufres dans les coupes petrolieres: cinetique et modelisation de l'hydrotraitement

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Garcia, C

    2000-12-01

    The study of the hydro-treating of middle distillates comprised the following steps: - Identification and reactivity study of the sulphur compounds present in these petroleum cuts; - Modelling of the process by a chemical kinetic approach. The hydro-treating of middle distillates is a refining process that allows elimination of organic compounds containing sulphur, nitrogen, oxygen and metals. The process also hydrogenates the aromatic compounds providing improved cetane index gas-oils while respecting the regulations that severely limit the content of sulphur compounds. The extension and the improvement of a kinetic model for the hydro-treating of LCO gas-oils (light cycle oil gas-oils) are presented in this work. In order to improve the hydro-desulfurization model predictions, a detailed identification of the sulphur compounds contained in LCO gas-oils was carried out using gas chromatography with a sulphur chemiluminescence detector (GC-SCD). The most refractory sulphur compounds (alkyl-di-benzothiophenes) were identified and lumped into different families. Based on a lumped reaction scheme with a Langmuir-Hinshelwood representation, the model takes into account the influence of temperature, total pressure and hydrogen sulphide partial pressure on the reaction rates for hydro-desulfurization, hydro-denitrogenation and hydro-de-aromatization. The model parameter estimation was based on experiments that were carried out on a micro-pilot unit using an industrial sulfided NiMo/Al{sub 2}O{sub 3} catalyst and LCO feedstocks. The analytical study of the sulphur compounds was also extended to the case of straight run gas-oils (SR). For these feedstocks, a method using high-resolution mass spectrometry coupled with gas chromatography (GC-HRMS) was developed. In this way, the kinetic model can now be extended for the SR gas-oil hydro-treating or for LCO-SR mixtures. (author)

  6. Analysis of the reactivity of sulphur compounds in petroleum cuts: kinetics and modelling of hydro-treating; Analyse de la reactivite des composes soufres dans les coupes petrolieres: cinetique et modelisation de l'hydrotraitement

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Garcia, C.

    2000-12-01

    The study of the hydro-treating of middle distillates comprised the following steps: - Identification and reactivity study of the sulphur compounds present in these petroleum cuts; - Modelling of the process by a chemical kinetic approach. The hydro-treating of middle distillates is a refining process that allows elimination of organic compounds containing sulphur, nitrogen, oxygen and metals. The process also hydrogenates the aromatic compounds providing improved cetane index gas-oils while respecting the regulations that severely limit the content of sulphur compounds. The extension and the improvement of a kinetic model for the hydro-treating of LCO gas-oils (light cycle oil gas-oils) are presented in this work. In order to improve the hydro-desulfurization model predictions, a detailed identification of the sulphur compounds contained in LCO gas-oils was carried out using gas chromatography with a sulphur chemiluminescence detector (GC-SCD). The most refractory sulphur compounds (alkyl-di-benzothiophenes) were identified and lumped into different families. Based on a lumped reaction scheme with a Langmuir-Hinshelwood representation, the model takes into account the influence of temperature, total pressure and hydrogen sulphide partial pressure on the reaction rates for hydro-desulfurization, hydro-denitrogenation and hydro-de-aromatization. The model parameter estimation was based on experiments that were carried out on a micro-pilot unit using an industrial sulfided NiMo/Al{sub 2}O{sub 3} catalyst and LCO feedstocks. The analytical study of the sulphur compounds was also extended to the case of straight run gas-oils (SR). For these feedstocks, a method using high-resolution mass spectrometry coupled with gas chromatography (GC-HRMS) was developed. In this way, the kinetic model can now be extended for the SR gas-oil hydro-treating or for LCO-SR mixtures. (author)

  7. Diesel with low sulfur content and high cetane number produced by two stages hydrotreating procedures; Diesel com baixos teores de enxofre e alto numero de cetano a partir de hidrotratamento em dois estagios

    Energy Technology Data Exchange (ETDEWEB)

    Zotin, J L; Pacheco, M E; Souza, V P; Belato, D; Silva, R M.S. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    According to the Brazilian specifications for diesel, lower sulfur content and higher cetane number can be expected in the near future, leading to an increased capacity of hydrotreating processes. PETROBRAS has proved technology for hydrotreating processes with 8 high pressure single stage units in operation. However, the production of ultra low sulfur diesel with high cetane number may require two stages processes, with conventional hydrotreating in the first step and deep aromatic saturation (HDA), with increase in the cetane number, in the second one. In this approach, noble metal catalysts, which are more active for hydrogenation but more sensitive to sulfur and nitrogen poisoning, can be used in the second stage. In the present work, the 2 stages approach was studied for maximizing cetane number of Brazilian gasoils. The influence of operating variables and the inhibition effect by sulfur and nitrogen were analyzed. Diesel with sulfur content below 10 ppm and high aromatic conversions at relatively mild conditions were obtained with noble metal catalysts, with a cetane number increase up to 6 points in the second stage. Sulfur compounds have a stronger inhibition effect than basic nitrogen compounds on hydrogenation reaction rates, but a synergetic effect was observed when both contaminants were present in high concentrations. (author)

  8. A new BETSI test bench at CEA/Saclay

    International Nuclear Information System (INIS)

    Nyckees, S.; Adroit, G.; Delferriere, O.; Duperrier, R.; Gauthier, Y.; Gobin, R.; Harrault, F.; Mateo, C.M.; Napoly, O.; Pottin, B.; Sauce, Y.; Senee, F.; Tuske, O.; Vacher, T.

    2012-01-01

    In the nineties, CEA has undertaken to develop the production of high intensity light ion beams from plasma generated by electron cyclotron resonance (ECR). Important results were obtained with the SILHI source in pulsed or continuous mode. Presently, CEA/Saclay is now involved in the construction of different injectors dedicated to large infrastructures like IFMIF or SPIRAL2. Other installations are also interested by high intensity ion sources like ESS or FAIR. To improve and test new sources, a new test bench named BETSI (Banc d'Etudes et de Tests des Sources d'Ions) has been operating for several years. Low energy beam line diagnostics consist of a Faraday cup, cameras and a species analyzer. The SILHI emittance scanner can also be installed on the beam line. On this test bench, different permanent magnet source configurations are tested. The paper is followed by the associated poster. (authors)

  9. Wind Generators Test Bench. Optimal Design of PI Controller

    Directory of Open Access Journals (Sweden)

    TUDORACHE, T.

    2011-08-01

    Full Text Available This paper proposes a novel and robust strategy for the optimal design of the drive system integrated in a wind generators test bench. The PI regulator coefficients used in control systems are usually computed based on simplified hypotheses and then tuned manually so as the system response meet certain specifications in terms of stability, accuracy and speed. The proposed methodology permits the automatic identification of PI regulator coefficients using intelligent optimization algorithms, the initial guess for the search procedure being determined based on particular simplified hypotheses. The proposed procedure can help the design engineers to drastically reduce the effort for finding the best PI regulator coefficients offering a range of feasible solutions depending on the imposed optimum criteria. The characteristics and performances of the optimization strategy are highlighted by using it for the design of a DC motor drive system used to simulate the wind prime mover integrated in a wind generators test bench.

  10. Improvement of bench life-tests for automotive batteries

    Science.gov (United States)

    Richter, G.

    A common method for rating the endurance of automotive batteries is the bench life-test according to DIN, IEC, SAE or JIS. With an increasing number of maintenance-free batteries on the market, the application of these tests becomes more problematic. This is due to a step-by-step capacity decline during cycling if the content of autimony in the grid-alloy is decreased. The degradation in performance is caused by the phenomenon of acid stratification. Because this debilitating effect occurs only rarely in service (vehicle movement) if charging and discharging is well balanced, there is a need for a new bench life-test with conditions that are more representative of practical conditions. Research has shown that the main changes should be: (i) an accelerated (moved) battery during cycling; (ii) slightly lower charging or discharging capacity amplitude, also with a lower mean value.

  11. The R and D D's bearing test benches

    International Nuclear Information System (INIS)

    Vialettes, J.M.

    1997-01-01

    In power generation plants, rotating machines are involved in energy transformation processes and safety systems. The bearings supporting the rotors and the thrust bearings play a crucial role in the reliability of these machines. The phenomena encountered straddle several disciplines: hydrodynamics, tribology, thermomechanics, materials and vibrations in a specific environment, namely: thin fluid film, solid mechanical components and shaft rotation. Means of analysing the behaviour of these components (bearings and thrust bearings) have been developed and implemented. These consists of the EDYOS (Etude Dynamique des Organes de Supportage) code for dynamically studying bearing devices and several related bench tests. In reality, in order to understand the complex physical phenomena encountered in these components, it is vital to carry out analyses and experimental validations. Since these investigations cannot be carried out on actual machines, test benches have been built which can subject the sample bearings to the equivalent stresses. (author)

  12. Development of training simulator based on critical assemblies test bench

    International Nuclear Information System (INIS)

    Narozhnyi, A.T.; Vorontsov, S.V.; Golubeva, O.A.; Dyudyaev, A.M.; Il'in, V.I.; Kuvshinov, M.I.; Panin, A.V.; Peshekhonov, D.P.

    2007-01-01

    When preparing critical mass experiment, multiplying system (MS) parts are assembled manually. This work is connected with maximum professional risk to personnel. Personnel training and keeping the skill of working experts is the important factor of nuclear safety maintenance. For this purpose authors develop a training simulator based on functioning critical assemblies test bench (CATB), allowing simulation of the MS assemblage using training mockups made of inert materials. The control program traces the current status of MS under simulation. A change in the assembly neutron physical parameters is mapped in readings of the regular devices. The simulator information support is provided by the computer database on physical characteristics of typical MS components The work in the training mode ensures complete simulation of real MS assemblage on the critical test bench. It makes it possible to elaborate the procedures related to CATB operation in a standard mode safely and effectively and simulate possible abnormal situations. (author)

  13. On line isotopic separator test benches at GANIL

    International Nuclear Information System (INIS)

    Anne, R.; Bru, B.; Joubert, A.; Leroy, R.; Obert, J.; Putaux, J.C.; Liang, C.F.; Paris, P.; Orr, N.; Steckmeyer, J.C.

    1993-01-01

    A first version of isotopic separator on line test bench has been built in order to test the feasibility of the production of radioactive species from 96 MeV/u of 20 Ne impinging a thick target of MgO. This test bench was equipped with a very compact ECR ion source (Nanogan) entirely made from permanent magnets and operating at 10 Ghz. 18 Ne 2,4+ ; 19N e 1,2,3,4+ and 23,24 Ne 1+ has been produced and ionized. A new more performing separator (SIRa) allowing the use of different types of ion sources will be completed by the end of 1993. (author) 4 refs., 4 figs., 1 tab

  14. Thiomers--from bench to market.

    Science.gov (United States)

    Bonengel, Sonja; Bernkop-Schnürch, Andreas

    2014-12-10

    Thiolated polymers or designated thiomers are obtained by immobilization of sulhydryl bearing ligands on the polymeric backbone of well-established polymers such as poly(acrylates) or chitosans. This functionalization leads to significantly improved mucoadhesive properties compared to the corresponding unmodified polymers, as disulfide bonds between thiol groups of thiomers and cysteine-rich glycoproteins of the mucus gel layer are formed. Furthermore, enzyme- and efflux-pump inhibiting as well as improved permeation-enhancing properties are advantages of thiolization. By the covalent attachment of mercaptonicotinamide substructures via disulfide bonds to thiolated polymers these properties are even substantially further improved and stability towards oxidation even in aqueous media can be provided. Meanwhile, more than 50 research groups worldwide are working on thiolated polymers. For certain thiomers the scale up process for industrial production has already been done and GMP material is available. Furthermore, safety of thiolated poly(acrylic acid), thiolated chitosan and thiolated hyaluronic acid could be demonstrated via orientating studies in human volunteers and via various clinical trials. The first product (Lacrimera® eye drops, Croma-Pharma) containing a chitosan-N-acetylcysteine conjugate for treatment of dry eye syndrome will enter the European market this year. It is the only product providing a sustained protective effect on the ocular surface due to its comparatively much more prolonged residence time worldwide. Various further products utilizing, for instance, thiolated hyaluronic acid in ocular surgery are in the pipeline. Copyright © 2014 Elsevier B.V. All rights reserved.

  15. Simulation of the LHC injection kicker impedance test bench

    CERN Document Server

    Tsutsui, H

    2003-01-01

    The coupling impedance measurements of the LHC injection kicker test bench are simulated by HFSS code. The simulation gives qualitatively good agreement with the measurement. In order to damp the resonances, some ferrite rings are tested in the simulation. Longitudinal resonances are damped by a ferrite ring of large tan$\\delta_{\\mu}$. The effect of the ferrite ring is small for damping the transverse impedance resonance around 30 MHz.

  16. Study and designing of the ''caliprax'' measurement bench

    International Nuclear Information System (INIS)

    Barriere, J.Ch.

    2001-09-01

    Probing the matter in order to check its elementary constituents, that is the goal of the particle physic. In this field, the experiments consist in colliding highly energetic particle beams and observing the new born particles. These observations are based on big particle detectors whose running is dependant on the precise knowledge of their geometry (position of the detection chambers). To achieve this, the detectors are equipped with alignment sensors, which have to be calibrated before. This document describes the study and the making of a calibration bench for the 'Praxial' (PRoximity AXIAL) type sensors, and other works related to these sensors. In a first part, we determine and apply a method to set the tools used to fix the sensor stands on the detection chambers. These settings are made with the use of a tridimensional measuring machine. Then, we study the stands themselves. These investigations concern mechanics: positioning quality of the sensors in their stands, bending of the supports due to the tightening. In this part too, the studies are in the field of dimensional metrology. After this, the works are reoriented toward the bench, with the choice of the displacement sensors among two different technologies: optical, with the Rasnik system, and mechanical, with linear probes as LVDT (Linear Variable Differential Transformer). Following the discovery of an ambiguity on the Rasnik system, we go on the tests to understand its behaviour. We introduce the theory of the alignment sensors calibration, which is based on a minimization calculation. The computer programs are explained in a chapter, and in an other, the implementation of the quality assurance procedures. An other part describes the mechanical studies and the problems they cause. Because of a delay onset of the project, we make a model of the bench. This dummy allows us to test every single function of the final bench. With this device, we record manually the first calibration data and use them

  17. Full-Scale and Bench-Scale Studies on the Removal of Strontium from Water (abstract)

    Science.gov (United States)

    Strontium (Sr) is a natural and commonly occurring alkaline earth metal which has an oxidation state of +2 under normal environmental conditions. Stable strontium is suspended in water and is dissolved after water runs through rocks and soil. It behaves very similar to calcium. G...

  18. Experience gained in pilot-scale and bench-scale fluidised beds processing

    CSIR Research Space (South Africa)

    Hadley, TD

    2006-02-01

    Full Text Available for clean coal technology thrust COMMISSIONED PLANTS Slagment Hot Gas Generator Client : Slagment Bed area : 25 m2 Plant purpose : A 10 MW plant for the combustion of duff coal at greater than 98% burnout to provide hot gases for the drying...

  19. A virtual model of the bench press exercise.

    Science.gov (United States)

    Rahmani, Abderrahmane; Rambaud, Olivier; Bourdin, Muriel; Mariot, Jean-Pierre

    2009-08-07

    The objective of this study was to design and validate a three degrees of freedom model in the sagittal plane for the bench press exercise. The mechanical model was based on rigid segments connected by revolute and prismatic pairs, which enabled a kinematic approach and global force estimation. The method requires only three simple measurements: (i) horizontal position of the hand (x(0)); (ii) vertical displacement of the barbell (Z) and (iii) elbow angle (theta). Eight adult male throwers performed maximal concentric bench press exercises against different masses. The kinematic results showed that the vertical displacement of each segment and the global centre of mass followed the vertical displacement of the lifted mass. Consequently, the vertical velocity and acceleration of the combined centre of mass and the lifted mass were identical. Finally, for each lifted mass, there were no practical differences between forces calculated from the bench press model and those simultaneously measured with a force platform. The error was lower than 2.5%. The validity of the mechanical method was also highlighted by a standard error of the estimate (SEE) ranging from 2.0 to 6.6N in absolute terms, a coefficient of variation (CV) or =0.99 for all the lifts (pbench press exercises in both field and laboratory conditions.

  20. Utilization of institutional delivery service and associated factors in Bench Maji zone, Southwest Ethiopia: community based, cross sectional study.

    Science.gov (United States)

    Tadele, Niguse; Lamaro, Tafesse

    2017-02-01

    At the end of Millennium development goals, Ethiopia was included among 10 countries which constitutes about 59% of maternal deaths due to complications of pregnancy and/or childbirth every year globally. Institutional delivery, which is believed to contribute in reduction of maternal mortality is still low. Hence this study was conducted in order to assess utilization of institutional delivery and related factors in Bench Maji zone, Southwest Ethiopia. Cross sectional study was employed from September 1st - 30th, 2015 in Bench Maji Zone, Southwest Ethiopia where 765 mothers who deliver 2 years preceding the study provided data for this research. Data were collected by enumerators who were trained. In addition to descriptive statistics, binary and multivariate logistic regression analyses were performed. Statistical significance was considered at a p-value delivery which was significant. In Bench Maji Zone institutional delivery was shown to be comparatively good compared to other studies in the region and in Ethiopia in general even though it is below the health sector transformation plan of Ethiopia which aimed to increase deliveries attended by skilled health personnel to 95%. Empowering women, increasing awareness about institutional delivery and proper scaling up of antenatal care services which is an entry point for institutional delivery are recommended.

  1. A comparison of muscle activation between a Smith machine and free weight bench press.

    Science.gov (United States)

    Schick, Evan E; Coburn, Jared W; Brown, Lee E; Judelson, Daniel A; Khamoui, Andy V; Tran, Tai T; Uribe, Brandon P

    2010-03-01

    The bench press exercise exists in multiple forms including the machine and free weight bench press. It is not clear though how each mode differs in its effect on muscle activation. The purpose of this study was to compare muscle activation of the anterior deltoid, medial deltoid, and pectoralis major during a Smith machine and free weight bench press at lower (70% 1 repetition maximum [1RM]) and higher (90% 1RM) intensities. Normalized electromyography amplitude values were used during the concentric phase of the bench press to compare muscle activity between a free weight and Smith machine bench press. Participants were classified as either experienced or inexperienced bench pressers. Two testing sessions were used, each of which entailed either all free weight or all Smith machine testing. In each testing session, each participant's 1RM was established followed by 2 repetitions at 70% of 1RM and 2 repetitions at 90% of 1RM. Results indicated greater activation of the medial deltoid on the free weight bench press than on the Smith machine bench press. Also, there was greater muscle activation at the 90% 1RM load than at the 70% 1RM load. The results of this study suggest that strength coaches should consider choosing the free weight bench press over the Smith machine bench press because of its potential for greater upper-body muscular development.

  2. Design of a Test Bench for Intraocular Lens Optical Characterization

    Energy Technology Data Exchange (ETDEWEB)

    Alba-Bueno, Francisco; Vega, Fidel; Millan, Maria S, E-mail: francisco.alba-bueno@upc.edu, E-mail: fvega@oo.upc.edu, E-mail: millan@oo.upc.edu [Departamento de Optica y Optometria, Universidad Politecnica de Cataluna, C/ Violinista Vellsola 37, 08222 Terrassa (Spain)

    2011-01-01

    The crystalline lens is the responsible for focusing at different distances (accommodation) in the human eye. This organ grows throughout life increasing in size and rigidity. Moreover, due this growth it loses transparency through life, and becomes gradually opacified causing what is known as cataracts. Cataract is the most common cause of visual loss in the world. At present, this visual loss is recoverable by surgery in which the opacified lens is destroyed (phacoemulsification) and replaced by the implantation of an intraocular lens (IOL). If the IOL implanted is mono-focal the patient loses its natural capacity of accommodation, and as a consequence they would depend on an external optic correction to focus at different distances. In order to avoid this dependency, multifocal IOLs designs have been developed. The multi-focality can be achieved by using either, a refractive surface with different radii of curvature (refractive IOLs) or incorporating a diffractive surface (diffractive IOLs). To analyze the optical quality of IOLs it is necessary to test them in an optical bench that agrees with the ISO119679-2 1999 standard (Ophthalmic implants. Intraocular lenses. Part 2. Optical Properties and Test Methods). In addition to analyze the IOLs according to the ISO standard, we have designed an optical bench that allows us to simulate the conditions of a real human eye. To do that, we will use artificial corneas with different amounts of optical aberrations and several illumination sources with different spectral distributions. Moreover, the design of the test bench includes the possibility of testing the IOLs under off-axis conditions as well as in the presence of decentration and/or tilt. Finally, the optical imaging quality of the IOLs is assessed by using common metrics like the Modulation Transfer Function (MTF), the Point Spread Function (PSF) and/or the Strehl ratio (SR), or via registration of the IOL's wavefront with a Hartmann-Shack sensor and its

  3. Design guidelines for high dimensional stability of CFRP optical bench

    Science.gov (United States)

    Desnoyers, Nichola; Boucher, Marc-André; Goyette, Philippe

    2013-09-01

    In carbon fiber reinforced plastic (CFRP) optomechanical structures, particularly when embodying reflective optics, angular stability is critical. Angular stability or warping stability is greatly affected by moisture absorption and thermal gradients. Unfortunately, it is impossible to achieve the perfect laminate and there will always be manufacturing errors in trying to reach a quasi-iso laminate. Some errors, such as those related to the angular position of each ply and the facesheet parallelism (for a bench) can be easily monitored in order to control the stability more adequately. This paper presents warping experiments and finite-element analyses (FEA) obtained from typical optomechanical sandwich structures. Experiments were done using a thermal vacuum chamber to cycle the structures from -40°C to 50°C. Moisture desorption tests were also performed for a number of specific configurations. The selected composite material for the study is the unidirectional prepreg from Tencate M55J/TC410. M55J is a high modulus fiber and TC410 is a new-generation cyanate ester designed for dimensionally stable optical benches. In the studied cases, the main contributors were found to be: the ply angular errors, laminate in-plane parallelism (between 0° ply direction of both facesheets), fiber volume fraction tolerance and joints. Final results show that some tested configurations demonstrated good warping stability. FEA and measurements are in good agreement despite the fact that some defects or fabrication errors remain unpredictable. Design guidelines to maximize the warping stability by taking into account the main dimensional stability contributors, the bench geometry and the optical mount interface are then proposed.

  4. Quality Assessment of Vertical Angular Deviations for Photometer Calibration Benches

    International Nuclear Information System (INIS)

    Ribeiro, A Silva; Santos, A Costa; E Sousa, J Alves; Forbes, A B

    2015-01-01

    Lighting, both natural and electric, constitutes one of the most important aspects of the life of human beings, allowing us to see and perform our daily tasks in outdoor and indoor environments. The safety aspects of lighting are self-evident in areas such as road lighting, urban lighting and also indoor lighting. The use of photometers to measure lighting levels requires traceability obtained in accredited laboratories, which must provide an associated uncertainty. It is therefore relevant to study the impact of known uncertainty sources like the vertical angular deviation of photometer calibration benches, in order to define criteria to its quality assessment

  5. Dynamic balance abilities of collegiate men for the bench press.

    Science.gov (United States)

    Piper, Timothy J; Radlo, Steven J; Smith, Thomas J; Woodward, Ryan W

    2012-12-01

    This study investigated the dynamic balance detection ability of college men for the bench press exercise. Thirty-five college men (mean ± SD: age = 22.4 ± 2.76 years, bench press experience = 8.3 ± 2.79 years, and estimated 1RM = 120.1 ± 21.8 kg) completed 1 repetition of the bench press repetitions for each of 3 bar loading arrangements. In a randomized fashion, subjects performed the bench press with a 20-kg barbell loaded with one of the following: a balanced load, one 20-kg plate on each side; an imbalanced asymmetrical load, one 20-kg plate on one side and a 20-kg plate plus a 1.25-kg plate on the other side; or an imbalanced asymmetrical center of mass, 20-kg plate on one side and sixteen 1.25-kg plates on the other side. Subjects were blindfolded and wore ear protection throughout all testing to decrease the ability to otherwise detect loads. Binomial data analysis indicated that subjects correctly detected the imbalance of the imbalanced asymmetrical center of mass condition (p[correct detection] = 0.89, p < 0.01) but did not correctly detect the balanced condition (p[correct detection] = 0.46, p = 0.74) or the imbalanced asymmetrical condition (p[correct detection] = 0.60, p = 0.31). Although it appears that a substantial shift in the center of mass of plates leads to the detection of barbell imbalance, minor changes of the addition of 1.25 kg (2.5 lb) to the asymmetrical condition did not result in consistent detection. Our data indicate that the establishment of a biofeedback loop capable of determining balance detection was only realized under a high degree of imbalance. Although balance detection was not present in either the even or the slightly uneven loading condition, the inclusion of balance training for upper body may be futile if exercises are unable to establish such a feedback loop and thus eliciting an improvement of balance performance.

  6. STS-65 crewmembers participate in bench review at Boeing Building

    Science.gov (United States)

    1994-01-01

    Attired in clean suits, STS-65 Payload Commander (PLC) Richard J. Hieb (left) and Payload Specialist Chiaki Mukai examine the contents of a stowage locker during a bench review at Boeing's Flight Equipment Processing Facility (FEPF) near the Johnson Space Center (JSC). In the background, Commander Robert D. Cabana inspects additional equipment to be carried aboard the Space Shuttle Columbia, Orbiter Vehicle (OV) 102, for the scheduled July flight of the second International Microgravity Laboratory (IML-2) mission. Mukai represents Japan's National Space Development Agency (NASDA). Photo taken by NASA JSC contract photographer Scott A. Wickes.

  7. Comparative tests of bench equipment for fuel control system testing of gas-turbine engine

    Science.gov (United States)

    Shendaleva, E. V.

    2018-04-01

    The relevance of interlaboratory comparative researches is confirmed by attention of world metrological community to this field of activity. Use of the interlaboratory comparative research methodology not only for single gages collation, but also for bench equipment complexes, such as modeling stands for fuel control system testing of gas-turbine engine, is offered. In this case a comparative measure of different bench equipment will be the control fuel pump. Ensuring traceability of measuring result received at test benches of various air enterprises, development and introduction of national standards to practice of bench tests and, eventually, improvement of quality and safety of a aircraft equipment is result of this approach.

  8. Bench-marking beam-beam simulations using coherent quadrupole effects

    International Nuclear Information System (INIS)

    Krishnagopal, S.; Chin, Y.H.

    1992-06-01

    Computer simulations are used extensively in the study of the beam-beam interaction. The proliferation of such codes raises the important question of their reliability, and motivates the development of a dependable set of bench-marks. We argue that rather than detailed quantitative comparisons, the ability of different codes to predict the same qualitative physics should be used as a criterion for such bench-marks. We use the striking phenomenon of coherent quadrupole oscillations as one such bench-mark, and demonstrate that our codes do indeed observe this behaviour. We also suggest some other tests that could be used as bench-marks

  9. Bench-marking beam-beam simulations using coherent quadrupole effects

    International Nuclear Information System (INIS)

    Krishnagopal, S.; Chin, Y.H.

    1992-01-01

    Computer simulations are used extensively in the study of the beam-beam interaction. The proliferation of such codes raises the important question of their reliability, and motivates the development of a dependable set of bench-marks. We argue that rather than detailed quantitative comparisons, the ability of different codes to predict the same qualitative physics should be used as a criterion for such bench-marks. We use the striking phenomenon of coherent quadrupole oscillations as one such bench-mark, and demonstrate that our codes do indeed observe this behavior. We also suggest some other tests that could be used as bench-marks

  10. Moving-Bed Process for Residue Hydrotreating Procédé à lit mobile pour l'hydrotraitement des résidus

    Directory of Open Access Journals (Sweden)

    Euzen J. P.

    2006-11-01

    Full Text Available A lot of chemical, petrochemical or refining processes require contact between three phases : a liquid feed, a gaseous reactant and a solid catalyst. Frequently, the catalyst activity is reduced by poisoning of active sites or coke deposits. This is especially the case with the processes used in heavy residual oils hydrotreating. As the catalyst life is reduced, the substitution or regeneration of the inactive catalyst is frequently necessary. Various solutions, such, as fixed beds used with swing reactors, fluidized beds, or moving beds with down flow of the catalyst and co-current or counter-current of the feed, can be proposed to perform this task with a minimum of time and production losses. A theoretical comparison between the performances of the various technologies has been made by means of a detailed simulation of the behaviour of each of these catalytic beds over a long period. Of course, in the models, some assumptions are necessary, like the ideal fluid and solids flows. Nevertheless, the problem remains complex because hydrodynamic, kinetic, catalyst deactivation, or thermal effects occur simultaneously, within the particules and/or in the bed as a whole. Various pilot plant data are of course used in order to build the kinetic part of the models. This comparison shows a marked advantage for the moving bed with counter-current flow between feed and catalyst owing to the systematic optimum use of the catalyst potential. Consequently, a series of experiments was made on various sized cold mockups designed to simulate counter-current movind beds. These experiments were necessary to demonstrate the feasability of the process, to specify the relations among gas and liquid superficial velocities, particles and fluids properties, and hydrodynamic regimes, and to develop the scale-up rules. The main goal is to secure a uniform distribution of the two fluids through out the whole bed of catalyst, and at the same time a regular progression of

  11. Research on Test-bench for Sonic Logging Tool

    Directory of Open Access Journals (Sweden)

    Xianping Liu

    2016-01-01

    Full Text Available In this paper, the test-bench for sonic logging tool is proposed and designed to realize automatic calibration and testing of the sonic logging tool. The test-bench System consists of Host Computer, Embedded Controlling Board, and functional boards. The Host Computer serves as the Human Machine Interface (HMI and processes uploaded data. The software running on Host Computer is designed on VC++, which is developed based on multithreading, Dynamic Linkable Library (DLL and Multiple Document Interface (MDI techniques. The Embedded Controlling Board uses ARM7 as the microcontroller and communicates with Host Computer via Ethernet. The Embedded Controlling Board software is realized based on embedded uclinux operating system with a layered architecture. The functional boards are designed based on Field Programmable Gate Array (FPGA and provide test interfaces for the logging tool. The functional board software is divided into independent sub-modules that can repeatedly be used by various functional boards and then integrated those sub-modules in the top layer. With the layered architecture and modularized design, the software system is highly reliable and extensible. With the help of designed system, a test has been conducted quickly and successfully on the electronic receiving cabin of the sonic logging tool. It demonstrated that the system could greatly improve the production efficiency of the sonic logging tool.

  12. Streamflow characteristics at hydrologic bench-mark stations

    Science.gov (United States)

    Lawrence, C.L.

    1987-01-01

    The Hydrologic Bench-Mark Network was established in the 1960's. Its objectives were to document the hydrologic characteristics of representative undeveloped watersheds nationwide and to provide a comparative base for studying the effects of man on the hydrologic environment. The network, which consists of 57 streamflow gaging stations and one lake-stage station in 39 States, is planned for permanent operation. This interim report describes streamflow characteristics at each bench-mark site and identifies time trends in annual streamflow that have occurred during the data-collection period. The streamflow characteristics presented for each streamflow station are (1) flood and low-flow frequencies, (2) flow duration, (3) annual mean flow, and (4) the serial correlation coefficient for annual mean discharge. In addition, Kendall's tau is computed as an indicator of time trend in annual discharges. The period of record for most stations was 13 to 17 years, although several stations had longer periods of record. The longest period was 65 years for Merced River near Yosemite, Calif. Records of flow at 6 of 57 streamflow sites in the network showed a statistically significant change in annual mean discharge over the period of record, based on computations of Kendall's tau. The values of Kendall's tau ranged from -0.533 to 0.648. An examination of climatological records showed that changes in precipitation were most likely the cause for the change in annual mean discharge.

  13. Effects of different vibration exercises on bench press.

    Science.gov (United States)

    Marín, P J; Torres-Luque, G; Hernández-García, R; García-López, D; Garatachea, N

    2011-10-01

    This study was undertaken to analyze the effects of different vibration recovery strategies via feet or hands on the number of repetitions performed and on mean velocity, peak velocity and blood lactate concentration during consecutive bench-press sets. 9 elite judo athletes performed 3 sets of bench press at 60% of one-repetition maximum (1RM), leading to failure and allowing a 180 s rest period between sets. During the rest period, 1 of the 3 following procedures was performed: 150 s rest plus 30 s push-up vibration exercise (Push-up), 150 s rest plus 30 s squat vibration exercise (Squat) or 180 s only rest (Passive). Statistical analysis revealed that the Squat condition resulted in a significant increase in the number of repetitions achieved, in comparison with all other rest strategies. However, kinematic parameters and blood lactate concentration were not affected by vibration. These data suggest that a vibration stimulus applied to the feet, between sets, can result in positive improvements in upper body resistance exercise performance. Although the mechanisms are not fully understood, this positive effect of vibration could be due to an increased motor cortex excitability and voluntary drive. © Georg Thieme Verlag KG Stuttgart · New York.

  14. Muscle synergies during bench press are reliable across days.

    Science.gov (United States)

    Kristiansen, Mathias; Samani, Afshin; Madeleine, Pascal; Hansen, Ernst Albin

    2016-10-01

    Muscle synergies have been investigated during different types of human movement using nonnegative matrix factorization. However, there are not any reports available on the reliability of the method. To evaluate between-day reliability, 21 subjects performed bench press, in two test sessions separated by approximately 7days. The movement consisted of 3 sets of 8 repetitions at 60% of the three repetition maximum in bench press. Muscle synergies were extracted from electromyography data of 13 muscles, using nonnegative matrix factorization. To evaluate between-day reliability, we performed a cross-correlation analysis and a cross-validation analysis, in which the synergy components extracted in the first test session were recomputed, using the fixed synergy components from the second test session. Two muscle synergies accounted for >90% of the total variance, and reflected the concentric and eccentric phase, respectively. The cross-correlation values were strong to very strong (r-values between 0.58 and 0.89), while the cross-validation values ranged from substantial to almost perfect (ICC3, 1 values between 0.70 and 0.95). The present findings revealed that the same general structure of the muscle synergies was present across days and the extraction of muscle synergies is thus deemed reliable. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Innovative lightweight substrate for stable optical benches and mirrors

    Science.gov (United States)

    Rugi Grond, E.; Herren, A.; Mérillat, S.; Fermé, J. J.

    2017-11-01

    High precision space optics, such as spectrometers, relay optics, and filters, require ultra stable, lightweight platforms. These equipped platforms have on one side to survive the launch loads, on the other side they have to maintain their stability also under the varying thermal loads occurring in space. Typically such platforms have their equipment (prisms, etalons, beam expanders, etc.) mounted by means of classical bonding, hydro-catalytic bonding or optical contacting. Therefore such an optical bench requires to provide an excellent flatness, minimal roughness and is usually made of the same material as the equipment it carries (glass, glass ceramics). For space systems, mass is a big penalty, therefore such optical platforms are in most cases light weighted by means of machining features (i.e. pockets). Besides of being not extremely mass efficient, such pockets reduce the load carrying capability of the base material significantly. The challenge for Oerlikon Space, in this context, was to develop, qualify and deliver such optical benches, providing a substantial mass reduction compared to actual light weighted systems, while maintaining most of the full load carrying capacity of the base material. Additionally such a substrate can find an attractive application for mirror substrates. The results of the first development and of the first test results will be presented.

  16. LiveBench-1: continuous benchmarking of protein structure prediction servers.

    Science.gov (United States)

    Bujnicki, J M; Elofsson, A; Fischer, D; Rychlewski, L

    2001-02-01

    We present a novel, continuous approach aimed at the large-scale assessment of the performance of available fold-recognition servers. Six popular servers were investigated: PDB-Blast, FFAS, T98-lib, GenTHREADER, 3D-PSSM, and INBGU. The assessment was conducted using as prediction targets a large number of selected protein structures released from October 1999 to April 2000. A target was selected if its sequence showed no significant similarity to any of the proteins previously available in the structural database. Overall, the servers were able to produce structurally similar models for one-half of the targets, but significantly accurate sequence-structure alignments were produced for only one-third of the targets. We further classified the targets into two sets: easy and hard. We found that all servers were able to find the correct answer for the vast majority of the easy targets if a structurally similar fold was present in the server's fold libraries. However, among the hard targets--where standard methods such as PSI-BLAST fail--the most sensitive fold-recognition servers were able to produce similar models for only 40% of the cases, half of which had a significantly accurate sequence-structure alignment. Among the hard targets, the presence of updated libraries appeared to be less critical for the ranking. An "ideally combined consensus" prediction, where the results of all servers are considered, would increase the percentage of correct assignments by 50%. Each server had a number of cases with a correct assignment, where the assignments of all the other servers were wrong. This emphasizes the benefits of considering more than one server in difficult prediction tasks. The LiveBench program (http://BioInfo.PL/LiveBench) is being continued, and all interested developers are cordially invited to join.

  17. Hydrothermal liquefaction oil and hydrotreated product from pine feedstock characterized by heteronuclear two-dimensional NMR spectroscopy and FT-ICR mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Sudasinghe, Nilusha; Cort, John R.; Hallen, Richard T.; Olarte, Mariefel V.; Schmidt, Andrew J.; Schaub, Tanner

    2014-12-01

    Hydrothermal liquefaction (HTL) crude oil and hydrotreated product from pine tree farm waste (forest product residual, FPR) have been analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) in both positive- and negative-ionization modes and high-resolution twodimensional heteronuclear 1H-13C NMR spectroscopy. FT-ICR MS resolves thousands of compounds in complex oils and provides unparalleled compositional details for individual molecules for identification of compound class (heteroatom content), type (number of rings plus double bonds to carbon or double bond equivalents (DBE) and carbon number (degree of alkylation). Heteronuclear 1H-13C NMR spectroscopy provides one-bond and multiple-bond correlations between pairs of 1H and 13C chemical shifts that are characteristic of different organic functional groups. Taken together this information provides a picture of the chemical composition of these oils. Pyrolysis crude oil product from pine wood was characterized for comparison. Generally, pyrolysis oil is comprised of a more diverse distribution of heteroatom classes with higher oxygen number relative to HTL oil as shown by both positive- and negative-ion ESI FT-ICR MS. A total of 300 N1, 594 O1 and 267 O2 compounds were observed as products of hydrotreatment. The relative abundance of N1O1, N1O2, N1O3, N2, N2O1, N2O2 and O3 compounds are reduced to different degrees after hydrotreatment and other higher heteroatom containing species (O4-O10, N1O4, N1O5 and N2O3) are completely removed by hydrotreatment.

  18. Machine Shop I. Learning Activity Packets (LAPs). Section C--Hand and Bench Work.

    Science.gov (United States)

    Oklahoma State Board of Vocational and Technical Education, Stillwater. Curriculum and Instructional Materials Center.

    This document contains two learning activity packets (LAPs) for the "hand and bench work" instructional area of a Machine Shop I course. The two LAPs cover the following topics: hand and bench work and pedestal grinder. Each LAP contains a cover sheet that describes its purpose, an introduction, and the tasks included in the LAP;…

  19. Principles of developing the bench mark net for radioecological monitoring in the territory of Byelorussia

    International Nuclear Information System (INIS)

    Doroshkevich, M.N.

    1991-01-01

    The principles of developing the radioecological monitoring bench mark net proposed include the regularity pattern of reference point setting, the bench mark net hierarchy, accounting for a land-tenure structure and the landscape and geochemical conditions of the radionuclide migration as well as a passport system and informational adequacy. The expression has been obtained for determining the location of sampling points

  20. Association Between Maximal Bench Press Strength and Isometric Handgrip Strength Among Breast Cancer Survivors.

    Science.gov (United States)

    Rogers, Benjamin H; Brown, Justin C; Gater, David R; Schmitz, Kathryn H

    2017-02-01

    To characterize the relationship between 1-repetition maximum (1-RM) bench press strength and isometric handgrip strength among breast cancer survivors. Cross-sectional study. Laboratory. Community-dwelling breast cancer survivors (N=295). Not applicable. 1-RM bench press strength was measured with a barbell and exercise bench. Isometric handgrip strength was measured using an isometric dynamometer, with 3 maximal contractions of the left and right hands. All measures were conducted by staff with training in clinical exercise testing. Among 295 breast cancer survivors, 1-RM bench press strength was 18.2±6.1kg (range, 2.2-43.0kg), and isometric handgrip strength was 23.5±5.8kg (range, 9.0-43.0kg). The strongest correlate of 1-RM bench press strength was the average isometric handgrip strength of both hands (r=.399; Pisometric handgrip strength of both hands overestimated 1-RM bench press strength by 4.7kg (95% limits of agreement, -8.2 to 17.6kg). In a multivariable linear regression model, the average isometric handgrip strength of both hands (β=.31; Pstrength (R 2 =.23). Isometric handgrip strength is a poor surrogate for 1-RM bench press strength among breast cancer survivors. 1-RM bench press strength and isometric handgrip strength quantify distinct components of muscular strength. Copyright © 2016 American Congress of Rehabilitation Medicine. Published by Elsevier Inc. All rights reserved.

  1. Recreation Sports to host Sixth Annual Bench Press Competition March 17

    OpenAIRE

    Kropff, Catherine L.

    2007-01-01

    Music will blare, red and white lights will flash, and fans will cheer at the Sixth Annual Bench Press Competition to be held Saturday, March 17 at Virginia Tech. Participants will go to the bench to show their lifting skills beginning at 10 a.m. in War Memorial Gym.

  2. [A man with a painful upper arm after bench press exercise].

    Science.gov (United States)

    Sijtsma, Ben C T; van der Veen, Hugo C; van Raay, Jos J A M

    2015-01-01

    A 22-year-old male bodybuilder presented with pain and a haematoma of his right upper arm after bench press exercises. Suspicion of a pectoralis muscle tear was confirmed by MRI and surgical repair was performed. Ruptures of the pectoralis major muscle are rare, but may occur in young male bodybuilders, typically after bench press exercises.

  3. Strontium Removal: Full-Scale Ohio Demonstrations

    Science.gov (United States)

    The objectives of this presentation are to present a brief overview of past bench-scale research to evaluate the impact lime softening on strontium removal from drinking water and present full-scale drinking water treatment studies to impact of lime softening and ion exchange sof...

  4. A test-bench for measurement of electrical static parameters of strip silicon detectors

    International Nuclear Information System (INIS)

    Golutvin, I.A.; Dmitriev, A.Yu.; Elsha, V.V.

    2003-01-01

    An automated test-bench for electrical parameters input control of the strip silicon detectors, used in the End-Cap Preshower detector of the CMS experiment, is described. The test-bench application allows one to solve a problem of silicon detectors input control in conditions of mass production - 1800 detectors over 2 years. The test-bench software is realized in Delphi environment and contains a user-friendly operator interface for data processing and visualization as well as up-to-date facilities for MS-Windows used for the network database. High operating characteristics and reliability of the test-bench were confirmed while more than 800 detectors were tested. Some technical solutions applied to the test-bench could be useful for design and construction of automated facilities for electrical parameters measurements of the microstrip detectors input control. (author)

  5. A Test-Bench for Measurement of Electrical Static Parameters of Strip Silicon Detectors

    CERN Document Server

    Golutvin, I A; Danilevich, V G; Dmitriev, A Yu; Elsha, V V; Zamiatin, Y I; Zubarev, E V; Ziaziulia, F E; Kozus, V I; Lomako, V M; Stepankov, D V; Khomich, A P; Shumeiko, N M; Cheremuhin, A E

    2003-01-01

    An automated test-bench for electrical parameters input control of the strip silicon detectors, used in the End-Cap Preshower detector of the CMS experiment, is described. The test-bench application allows one to solve a problem of silicon detectors input control in conditions of mass production - 1800 detectors over 2 years. The test-bench software is realized in Delphi environment and contains a user-friendly operator interface for measurement data processing and visualization as well as up-to-date facilities for MS-Windows used for the network database. High operating characteristics and reliability of the test-bench were confirmed while more than 800 detectors were tested. Some technical solutions applied to the test-bench could be useful for design and construction of automated facilities for electrical parameters measurements of the microstrip detectors input control.

  6. Development of Real-Time Dual-Display Handheld and Bench-Top Hybrid-Mode SD-OCTs

    Directory of Open Access Journals (Sweden)

    Nam Hyun Cho

    2014-01-01

    Full Text Available Development of a dual-display handheld optical coherence tomography (OCT system for retina and optic-nerve-head diagnosis beyond the volunteer motion constraints is reported. The developed system is portable and easily movable, containing the compact portable OCT system that includes the handheld probe and computer. Eye posterior chambers were diagnosed using the handheld probe, and the probe could be fixed to the bench-top cradle depending on the volunteers’ physical condition. The images obtained using this handheld probe were displayed in real time on the computer monitor and on a small secondary built-in monitor; the displayed images were saved using the handheld probe’s built-in button. Large-scale signal-processing procedures such as k-domain linearization, fast Fourier transform (FFT, and log-scaling signal processing can be rapidly applied using graphics-processing-unit (GPU accelerated processing rather than central-processing-unit (CPU processing. The Labview-based system resolution is 1,024 × 512 pixels, and the frame rate is 56 frames/s, useful for real-time display. The 3D images of the posterior chambers including the retina, optic-nerve head, blood vessels, and optic nerve were composed using real-time displayed images with 500 × 500 × 500 pixel resolution. A handheld and bench-top hybrid mode with a dual-display handheld OCT was developed to overcome the drawbacks of the conventional method.

  7. The Association between Maximal Bench Press Strength and Isometric Handgrip Strength among Breast Cancer Survivors

    Science.gov (United States)

    Rogers, Benjamin H.; Brown, Justin C.; Gater, David R.; Schmitz, Kathryn H.

    2016-01-01

    Objective One-repetition maximum (1-RM) bench press strength is considered the gold standard to quantify upper-body muscular strength. Isometric handgrip strength is frequently used as a surrogate for 1-RM bench press strength among breast cancer (BrCa) survivors. The relationship between 1-RM bench press strength and isometric handgrip strength, however, has not been characterized among BrCa survivors. Design Cross-sectional study. Setting Laboratory. Participants Community-dwelling BrCa survivors. Interventions Not applicable. Main Outcome Measure 1-RM bench press strength was measured with a barbell and exercise bench. Isometric handgrip strength was measured using an isometric dynamometer with three maximal contractions of left and right hands. All measures were conducted by staff with training in clinical exercise testing. Results Among 295 BrCa survivors, 1-RM bench press strength was 18.2±6.1 kg (range: 2.2-43.0) and isometric handgrip strength was 23.5±5.8 kg (range: 9.0-43.0). The strongest correlate of 1-RM bench press strength was the average isometric handgrip strength of both hands (r=0.399; Pisometric handgrip strength of both hands overestimated 1-RM bench press strength by 4.7 kg (95% limits of agreement: −8.2 to 17.6). In a multivariable linear regression model, the average isometric handgrip strength of both hands (β=0.31; Pstrength (R2=0.23). Conclusions Isometric handgrip strength is a poor surrogate for 1-RM bench press strength among BrCa survivors. 1-RM bench press and isometric handgrip strength quantify distinct components of muscular strength. PMID:27543047

  8. Old star clusters: Bench tests of low mass stellar models

    Directory of Open Access Journals (Sweden)

    Salaris M.

    2013-03-01

    Full Text Available Old star clusters in the Milky Way and external galaxies have been (and still are traditionally used to constrain the age of the universe and the timescales of galaxy formation. A parallel avenue of old star cluster research considers these objects as bench tests of low-mass stellar models. This short review will highlight some recent tests of stellar evolution models that make use of photometric and spectroscopic observations of resolved old star clusters. In some cases these tests have pointed to additional physical processes efficient in low-mass stars, that are not routinely included in model computations. Moreover, recent results from the Kepler mission about the old open cluster NGC6791 are adding new tight constraints to the models.

  9. Studies of cooling tower components on the Mistral test bench

    International Nuclear Information System (INIS)

    Legrand, G.

    1992-07-01

    The conception of a humid air cooling tower with natural or forced draught, requires the knowledge of the thermal and aerodynamic exchange surfaces performances. Several points, among which the distribution nozzles and drift eliminators efficiencies, or the mechanical behavior of the components, should be considered. In order to be able to test this type of equipment and analyse its behavior, ELECTRICITE DE FRANCE set up in 1987 of a large dimensions test bench: MISTRAL. The investigations performed over the 3000 working hours of MISTRAL concern mainly the optimization of the counterflow and crossflow exchange surfaces proposed by the industrial cooling tower equipment suppliers. The quality of the experimental results is assured by the implementation of an extensive instrumentation on the air and water circuits, and by a severe control of the tests conditions

  10. Medical immunology: two-way bridge connecting bench and bedside.

    Science.gov (United States)

    Rijkers, Ger T; Damoiseaux, Jan G M C; Hooijkaas, Herbert

    2014-12-01

    Medical immunology in The Netherlands is a laboratory specialism dealing with immunological analyses as well as pre- and post-analytical consultation to clinicians (clinical immunologists and other specialists) involved in patients with immune mediated diseases. The scope of medical immunology includes immunodeficiencies, autoimmune diseases, allergy, transfusion and transplantation immunology, and lymphoproliferative disorders plus the monitoring of these patients. The training, professional criteria, quality control of procedures and laboratories is well organized. As examples of the bridge function of medical immunology between laboratory (bench) and patient (bedside) the contribution of medical immunologists to diagnosis and treatment of primary immunodeficiency diseases (in particular: humoral immunodeficiencies) as well as autoantibodies (anti-citrullinated proteins in rheumatoid arthritis) are given. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Dynamic MTF, an innovative test bench for detector characterization

    Science.gov (United States)

    Emmanuel, Rossi; Raphaël, Lardière; Delmonte, Stephane

    2017-11-01

    PLEIADES HR are High Resolution satellites for Earth observation. Placed at 695km they reach a 0.7m spatial resolution. To allow such performances, the detectors are working in a TDI mode (Time and Delay Integration) which consists in a continuous charge transfer from one line to the consecutive one while the image is passing on the detector. The spatial resolution, one of the most important parameter to test, is characterized by the MTF (Modulation Transfer Function). Usually, detectors are tested in a staring mode. For a higher level of performances assessment, a dedicated bench has been set-up, allowing detectors' MTF characterization in the TDI mode. Accuracy and reproducibility are impressive, opening the door to new perspectives in term of HR imaging systems testing.

  12. The Bench: An open drug scene and its people

    Directory of Open Access Journals (Sweden)

    Grønnestad Trond Erik

    2015-04-01

    Full Text Available AIMS - This article describes life in an open illicit drug milieu in a Norwegian city. This site, called “the Bench”, is a stigmatised place, and if one sits there, one is marked with the stigma of the place. Our aim is to gain insights into what stigmatised people gain from frequently visiting and staying in a public place that in itself is stigmatised. METHOD - One of the authors spent a year of participant observation, studying what went on at the Bench. He managed to build rapport in a gradual process of inclusion. The theoretical perspective rests on classic ethnography, symbolic interactionism and sociology on labelling and purity and dirt. RESULTS - “The Bench” is not only a local drug market, but also a social meeting place in which one can feel dignity, and where a certain humanisation process takes place through the rituals of everyday life. On “the Bench” it is possible to tell stories of decay, failures and shortcomings in life, stories that in other social arenas would be interpreted as symbols of stigma and degradation. “The Bench” is also a place in which different established power relations may be turned around through storytelling and jokes. This provides the bench-sitters with a sense of mutual control and agency. CONCLUSION - Socialising at “the Bench” is an expression of the need among social human beings to have their existences confirmed, in a society where they have been marginalised and looked upon as second-class citizens, as urban outcasts.

  13. Fatigue effects on bar kinematics during the bench press.

    Science.gov (United States)

    Duffey, Michael J; Challis, John H

    2007-05-01

    The bench press is one of the most popular weight training exercises. Although most training regimens incorporate multiple repetition sets, there are few data describing how the kinematics of a lift change during a set to failure. To examine these changes, recreational lifters (10 men and 8 women) were recruited. The maximum weight each subject could bench press (1RM) was determined. Subjects then performed as many repetitions as possible at 75% of the 1RM load. Three-dimensional kinematic data were recorded and analyzed for all lifts. Statistical analysis revealed that differences between maximal and submaximal lifts and the kinematics of a submaximal lift change as a subject approaches failure in a set. The time to lift the bar more than doubled from the first to the last repetition, causing a decrease in both mean and peak upward velocity. Furthermore, the peak upward velocity occurred much earlier in the lift phase in these later repetitions. The path the bar followed also changed, with subjects keeping the bar more directly over the shoulder during the lift. In general, most of the kinematic variables analyzed became more similar to those of the maximal lift as the subjects progressed through the set, but there was considerable variation between subjects as to which repetition was most like the maximal lift. This study shows that there are definite changes in the lifting kinematics in recreational lifters during a set to failure and suggests it may be particularly important for coaches and less-skilled lifters to focus on developing the proper bar path, rather than reaching momentary muscular failure, in the early part of a training program.

  14. Presence of Spotters Improves Bench Press Performance: A Deception Study.

    Science.gov (United States)

    Sheridan, Andrew; Marchant, David C; Williams, Emily L; Jones, Hollie S; Hewitt, Phil A; Sparks, S Andy

    2017-10-24

    Sheridan, A, Marchant, DC, Williams, EL, Jones, HS, Hewitt, PA, and Sparks, SA. Presence of spotters improves bench press performance: a deception study. J Strength Cond Res XX(X): 000-000, 2017-Resistance exercise is a widely used method of physical training in both recreational exercise and athletic populations. The use of training partners and spotters during resistance exercise is widespread, but little is known about the effect of the presence of these individuals on exercise performance. The purpose of the current study was to investigate the effect of spotter presence on bench press performance. Twelve recreationally trained participants (age, 21.3 ± 0.8 years, height, 1.82 ± 0.1 m, and weight, 84.8 ± 11.1 kg) performed 2 trials of 3 sets to failure at 60% of 1 repetition maximum on separate occasions. The 2 trials consisted of spotters being explicitly present or hidden from view (deception). During the trials, total repetitions (reps), total weight lifted, ratings of perceived exertion (RPE), and self-efficacy were measured. Total reps and weight lifted were significantly greater with spotters (difference = 4.5 reps, t = 5.68, p < 0.001 and difference = 209.6 kg, t = 5.65, p < 0.001, respectively). Although RPE and local RPE were significantly elevated in the deception trials (difference = 0.78, f = 6.16, p = 0.030 and difference = 0.81, f = 5.89, p = 0.034, respectively), self-efficacy was significantly reduced (difference = 1.58, f = 26.90, p < 0.001). This study demonstrates that resistance exercise is improved by the presence of spotters, which is facilitated by reduced RPE and increased self-efficacy. This has important implications for athletes and clients, who should perform resistance exercise in the proximity of others, to maximize total work performed.

  15. Virtual Reality Compared with Bench-Top Simulation in the Acquisition of Arthroscopic Skill: A Randomized Controlled Trial.

    Science.gov (United States)

    Banaszek, Daniel; You, Daniel; Chang, Justues; Pickell, Michael; Hesse, Daniel; Hopman, Wilma M; Borschneck, Daniel; Bardana, Davide

    2017-04-05

    Work-hour restrictions as set forth by the Accreditation Council for Graduate Medical Education (ACGME) and other governing bodies have forced training programs to seek out new learning tools to accelerate acquisition of both medical skills and knowledge. As a result, competency-based training has become an important part of residency training. The purpose of this study was to directly compare arthroscopic skill acquisition in both high-fidelity and low-fidelity simulator models and to assess skill transfer from either modality to a cadaveric specimen, simulating intraoperative conditions. Forty surgical novices (pre-clerkship-level medical students) voluntarily participated in this trial. Baseline demographic data, as well as data on arthroscopic knowledge and skill, were collected prior to training. Subjects were randomized to 5-week independent training sessions on a high-fidelity virtual reality arthroscopic simulator or on a bench-top arthroscopic setup, or to an untrained control group. Post-training, subjects were asked to perform a diagnostic arthroscopy on both simulators and in a simulated intraoperative environment on a cadaveric knee. A more difficult surprise task was also incorporated to evaluate skill transfer. Subjects were evaluated using the Global Rating Scale (GRS), the 14-point arthroscopic checklist, and a timer to determine procedural efficiency (time per task). Secondary outcomes focused on objective measures of virtual reality simulator motion analysis. Trainees on both simulators demonstrated a significant improvement (p virtual reality simulation group consistently outperformed the bench-top model group in the diagnostic arthroscopy crossover tests and in the simulated cadaveric setup. Furthermore, the virtual reality group demonstrated superior skill transfer in the surprise skill transfer task. Both high-fidelity and low-fidelity simulation trainings were effective in arthroscopic skill acquisition. High-fidelity virtual reality

  16. Benchmarking network for clinical and humanistic outcomes in diabetes (BENCH-D) study: protocol, tools, and population.

    Science.gov (United States)

    Nicolucci, Antonio; Rossi, Maria C; Pellegrini, Fabio; Lucisano, Giuseppe; Pintaudi, Basilio; Gentile, Sandro; Marra, Giampiero; Skovlund, Soren E; Vespasiani, Giacomo

    2014-01-01

    In the context of the DAWN-2 initiatives, the BENCH-D Study aims to test a model of regional benchmarking to improve not only the quality of diabetes care, but also patient-centred outcomes. As part of the AMD-Annals quality improvement program, 32 diabetes clinics in 4 Italian regions extracted clinical data from electronic databases for measuring process and outcome quality indicators. A random sample of patients with type 2 diabetes filled in a questionnaire including validated instruments to assess patient-centred indicators: SF-12 Health Survey, WHO-5 Well-Being Index, Diabetes Empowerment Scale, Problem Areas in Diabetes, Health Care Climate Questionnaire, Patients Assessment of Chronic Illness Care, Barriers to Medications, Patient Support, Diabetes Self-care Activities, and Global Satisfaction for Diabetes Treatment. Data were discussed with participants in regional meetings. Main problems, obstacles and solutions were identified through a standardized process, and a regional mandate was produced to drive the priority actions. Overall, clinical indicators on 78,854 patients have been measured; additionally, 2,390 patients filled-in the questionnaire. The regional mandates were officially launched in March 2012. Clinical and patient-centred indicators will be evaluated again after 18 months. A final assessment of clinical indicators will take place after 30 months. In the context of the BENCH-D study, a set of instruments has been validated to measure patient well-being and satisfaction with the care. In the four regional meetings, different priorities were identified, reflecting different organizational resources of the different areas. In all the regions, a major challenge was represented by the need of skills and instruments to address psychosocial issues of people with diabetes. The BENCH-D study allows a field testing of benchmarking activities focused on clinical and patient-centred indicators.

  17. Direction-specific recruitment of rotator cuff muscles during bench press and row.

    Science.gov (United States)

    Wattanaprakornkul, Duangjai; Halaki, Mark; Cathers, Ian; Ginn, Karen A

    2011-12-01

    Recent studies indicate that rotator cuff (RC) muscles are recruited in a reciprocal, direction-specific pattern during shoulder flexion and extension exercises. The main purpose of this study was to determine if similar reciprocal RC recruitment occurs during bench press (flexion-like) and row (extension-like) exercises. In addition, shoulder muscle activity was comprehensively compared between bench press and flexion; row and extension; and bench press and row exercises. Electromyographic (EMG) activity was recorded from 9 shoulder muscles sites in 15 normal volunteers. All exercises were performed at 20, 50 and 70% of subjects' maximal load. EMG data were normalized to standard maximal voluntary contractions. Infraspinatus activity was significantly higher than subscapularis during bench press, with the converse pattern during the row exercise. Significant differences in activity levels were found in pectoralis major, deltoid and trapezius between the bench press and flexion exercises and in lower trapezius between the row and extension exercises. During bench press and row exercises, the recruitment pattern in each active muscle did not vary with load. During bench press and row exercises, RC muscles contract in a reciprocal direction-specific manner in their role as shoulder joint dynamic stabilizers to counterbalance antero-posterior translation forces. Copyright © 2011 Elsevier Ltd. All rights reserved.

  18. Effect of Fatigue Upon Performance and Electromyographic Activity in 6-RM Bench Press

    OpenAIRE

    van den Tillaar, Roland; Saeterbakken, Atle

    2014-01-01

    The aim of this study was to examine the effect of fatigue during one set of 6-RM bench pressing upon the muscle patterning and performance. Fourteen resistance-trained males (age 22.5±2.0 years, stature 1.82±0.07 m, body mass 82.0±7.8 kg) conducted a 6-RM bench press protocol. Barbell kinematics and EMG activity of pectoralis major, deltoid anterior, biceps brachii, triceps brachii, rectus abdominis, oblique external and erector spinae were measured in each repetition during the 6-RM bench p...

  19. Using bench press load to predict upper body exercise loads in physically active individuals.

    Science.gov (United States)

    Wong, Del P; Ngo, Kwan-Lung; Tse, Michael A; Smith, Andrew W

    2013-01-01

    This study investigated whether loads for assistance exercises of the upper body can be predicted from the loads of the bench press exercise. Twenty-nine physically active collegiate students (age: 22.6 ± 2.5; weight training experience: 2.9 ± 2.1 years; estimated 1RM bench press: 54.31 ± 14.60 kg; 1RM: body weight ratio: 0.80 ± 0.22; BMI: 22.7 ± 2.1 kg·m(-2)) were recruited. The 6RM loads for bench press, barbell bicep curl, overhead dumbbell triceps extension, hammer curl and dumbbell shoulder press were measured. Test-retest reliability for the 5 exercises as determined by Pearson product moment correlation coefficient was very high to nearly perfect (0.82-0.98, p bench press load was significantly correlated with the loads of the 4 assistance exercises (r ranged from 0.80 to 0.93, p bench press load was a significant (R(2) range from 0.64 to 0.86, p Bench press load (0.28) + 6.30 kg, (b) Barbell biceps curl = Bench press load (0.33) + 6.20 kg, (c) Overhead triceps extension = Bench press load (0.33) - 0.60 kg, and (d) Dumbbell shoulder press = Bench press load (0.42) + 5.84 kg. The difference between the actual load and the predicted load using the four equations ranged between 6.52% and 8.54%, such difference was not significant. Fitness professionals can use the 6RM bench press load as a time effective and accurate method to predict training loads for upper body assistance exercises. Key pointsThe bench press load was significantly correlated with the loads of the 4 assistance exercises.No significant differences were found between the actual load and the predicted load in the four equations.6RM bench press load can be a time effective and accurate method to predict training loads for upper body assistance exercises.

  20. Comportement en vapocraquage de molécules modèles et de distillats sous vide hydrotraités. Première partie : potentialité de craquage, réacteur à profil de température rectangulaire et à court temps de séjour Steam-Cracking Behavior of Model Molecules and Hydrotreated Vacuum Distillates

    Directory of Open Access Journals (Sweden)

    Berthelin M.

    2006-11-01

    to determine a scale of cracking potential, so that the performances of a pretreatment catalyst could be oriented, i. e. optimization of hydrogen consumption and better upgrading of heavy feedstocks during steam cracking. Thanks to the rectangular temperature profile of the micropilot plant, very great improvements in ethylene production and very low asphaltene production were revealed by the pyrolysis of hydrotreated vacuum distillates. The primordial importance of temperature in the temperature/residence-time pair was confirmed.

  1. Pattern Generator for Bench Test of Digital Boards

    Science.gov (United States)

    Berkun, Andrew C.; Chu, Anhua J.

    2012-01-01

    All efforts to develop electronic equipment reach a stage where they need a board test station for each board. The SMAP digital system consists of three board types that interact with each other using interfaces with critical timing. Each board needs to be tested individually before combining into the integrated digital electronics system. Each board needs critical timing signals from the others to be able to operate. A bench test system was developed to support test of each board. The test system produces all the outputs of the control and timing unit, and is delivered much earlier than the timing unit. Timing signals are treated as data. A large file is generated containing the state of every timing signal at any instant. This file is streamed out to an IO card, which is wired directly to the device-under-test (DUT) input pins. This provides a flexible test environment that can be adapted to any of the boards required to test in a standalone configuration. The problem of generating the critical timing signals is then transferred from a hardware problem to a software problem where it is more easily dealt with.

  2. The "sticking period" in a maximum bench press.

    Science.gov (United States)

    van den Tillaar, Roland; Ettema, Gertjan

    2010-03-01

    The purpose of this study was to examine muscle activity and three-dimensional kinematics in the ascending phase of a successful one-repetition maximum attempt in bench press for 12 recreational weight-training athletes, with special attention to the sticking period. The sticking period was defined as the first period of deceleration of the upward movement (i.e. from the highest barbell velocity until the first local lowest barbell velocity). All participants showed a sticking period during the upward movement that started about 0.2 s after the initial upward movement, and lasted about 0.9 s. Electromyography revealed that the muscle activity of the prime movers changed significantly from the pre-sticking to the sticking and post-sticking periods. A possible mechanism for the existence of the sticking period is the diminishing potentiation of the contractile elements during the upward movement together with the limited activity of the pectoral and deltoid muscles during this period.

  3. Surfactant from neonatal to pediatric ICU: bench and bedside evidence.

    Science.gov (United States)

    Boet, A; Brat, R; Aguilera, S S; Tissieres, P; De Luca, D

    2014-12-01

    Surfactant is a cornerstone of neonatal critical care for the treatment of respiratory distress syndrome of preterm babies. However, other indications have been studied for various clinical conditions both in term neonates and in children beyond neonatal age. A high degree of evidence is not yet available in some cases and this is due to the complex and not yet totally understood physiopathology of the different types of pediatric and neonatal lung injury. We here summarise the state of the art of the bench and bedside knowledge about surfactant use for the respiratory conditions usually cared for in neonatal and pediatric intensive care units. Future research direction will also be presented. On the whole, surfactant is able to improve oxygenation in infection related respiratory failure, pulmonary hemorrhage and meconium aspiration syndrome. Bronchoalveolar lavage with surfactant solution is currently the only means to reduce mortality or need for extracorporeal life support in neonates with meconium aspiration. While surfactant bolus or lavage only improves the oxygenation and ventilatory requirements in other types of postneonatal acute respiratory distress syndrome (ARDS), there seems to be a reduction in the mortality of small infants with RSV-related ARDS.

  4. Mechanisms of Inflammation in Proliferative Vitreoretinopathy: From Bench to Bedside

    Directory of Open Access Journals (Sweden)

    Stavros N. Moysidis

    2012-01-01

    Full Text Available Proliferative vitreoretinopathy (PVR is a vision-threatening disease and a common complication of surgery to correct rhegmatogenous retinal detachment (RRD. Several models of the pathogenesis of this disease have been described with some of these models focusing on the role of inflammatory cells and other models focusing on the role of growth factors and cytokines in the vitreous which come into contact with intraretinal and retinal pigment epithelial cells. New experiments have shed light on the pathogenesis of PVR and offer promising avenues for clinical intervention before PVR develops. One such target is the indirect pathway of activation of platelet-derived growth factor receptor alpha (PDGRα, which plays an important role in PVR. Clinical trials assessing the efficacy of 5-fluorouracil (5-FU and low-molecular-weight heparin (LMWH, daunorubicin, and 13-cis-retinoic acid, among other therapies, have yielded mixed results. Here we review inflammatory and other mechanisms involved in the pathogenesis of PVR, we highlight important clinical trials, and we discuss how findings at the bench have the potential to be translated to the bedside.

  5. Effect of different pushing speeds on bench press.

    Science.gov (United States)

    Padulo, J; Mignogna, P; Mignardi, S; Tonni, F; D'Ottavio, S

    2012-05-01

    The purpose of this study was to investigate the effect on muscular strength after a 3-week training with the bench-press at a fixed pushing of 80-100% maximal speed (FPS) and self-selected pushing speed (SPS). 20 resistance-trained subjects were divided at random in 2 groups differing only regarding the pushing speed: in the FPS group (n=10) it was equal to 80-100% of the maximal speed while in the SPS group (n=10) the pushing speed was self-selected. Both groups were trained twice a week for 3 weeks with a load equal to 85% of 1RM and monitored with the encoder. Before and after the training we measured pushing speed and maximum load. Significant differences between and within the 2 groups were pointed out using a 2-way ANOVA for repeated measures. After 3 weeks a significant improvement was shown especially in the FPS group: the maximum load improved by 10.20% and the maximal speed by 2.22%, while in the SPS group the effect was <1%. This study shows that a high velocity training is required to increase the muscle strength further in subjects with a long training experience and this is possible by measuring the individual performance speed for each load. © Georg Thieme Verlag KG Stuttgart · New York.

  6. A high frequency test bench for rapid single-flux-quantum circuits

    International Nuclear Information System (INIS)

    Engseth, H; Intiso, S; Rafique, M R; Tolkacheva, E; Kidiyarova-Shevchenko, A

    2006-01-01

    We have designed and experimentally verified a test bench for high frequency testing of rapid single-flux-quantum (RSFQ) circuits. This test bench uses an external tunable clock signal that is stable in amplitude, phase and frequency. The high frequency external clock reads out the clock pattern stored in a long shift register. The clock pattern is consequently shifted out at high speed and split to feed both the circuit under test and an additional shift register in the test bench for later verification at low speed. This method can be employed for reliable high speed verification of RSFQ circuit operation, with use of only low speed read-out electronics. The test bench consists of 158 Josephson junctions and the occupied area is 3300 x 660 μm 2 . It was experimentally verified up to 33 GHz with ± 21.7% margins on the global bias supply current

  7. Rhode Island Flood Plain Management Services; Bench & Reference Mark Catalogue Portsmouth, Newport and Warwick, Rhode Island

    National Research Council Canada - National Science Library

    Hatfield, Christopher

    1994-01-01

    This study, which developed a catalog of bench and reference marks for several communities in Rhode Island, was conducted by the Long Range Planning Branch, Planning Directorate, New England Division, U.S...

  8. Bench press training program with attached chains for female volleyball and basketball athletes.

    Science.gov (United States)

    Burnham, Timothy R; Ruud, Jason D; McGowan, Robert

    2010-02-01

    Attaching chains to barbells to increase strength and power has become popular for athletes; however, little scientific evidence supports this practice. The present purpose was to compare chain training to traditional training for the bench press. Women collegiate athletes in volleyball and basketball (N = 19) participated in a 16-session bench press program. They were matched into either a Traditional or a Chain training group by 1-repetition maximum (1RM). The Traditional group performed the bench press with conventional equipment, while the Chain group trained with attached chains (5% of weight). Analysis showed a significant increase in 1RM for both groups over 16 sessions, Traditional +11.8% and Chain +17.4%. The difference between the groups was not statistically significant, but suggests the women who trained with attached chains improved their bench press more than the Traditional group.

  9. System of Thermal Balance Maintenance in Modern Test Benches for Centrifugal Pumps

    Directory of Open Access Journals (Sweden)

    A. I. Petrov

    2015-01-01

    Full Text Available The article “Systems of the heat balance maintenance in modern test benches for centrifugal pumps” makes the case to include cooling systems of a working fluid (heat setting in test bench for impeller pumps. It briefly summarizes an experience of bench building to test centrifugal pumps, developed at the BMSTU Department E-10 over the last 10 years. The article gives the formulas and the algorithm to calculate the heat capacity of different types of impeller pumps when tested at the bench as ell as to determine the heating time of the liquid in the bench without external cooling. Based on analysis of the power balance of a centrifugal pump, it is shown that about 90% of the pump unit-consumed electric power in terminals is used for heating up the working fluid in the loop of the test bench. The article gives examples of elementary heat calculation of the pump operation within the test bench. It presents the main types of systems to maintain thermal balance, their advantages, disadvantages and possible applications. The cooling system schemes for open and closed version of the benches both with built-in and with an independent cooling circuit are analysed. The paper separately considers options of such systems for large benches using the cooling tower as a cooling device in the loop, and to test the pumps using the hydraulic fluids other than water, including those at high temperatures of working fluids; in the latter case a diagram of dual-circuit cooling system "liquid-liquid-air" is shown. The paper depicts a necessity to use ethylene glycol coolant in the two-loop cooling bench. It provides an example of combining the functions of cooling and filtration in a single cooling circuit. Criteria for effectiveness of these systems are stated. Possible ways for developing systems to maintain a thermal balance, modern methods of regulation and control are described. In particular, the paper shows the efficiency of frequency control of the

  10. Errors of car wheels rotation rate measurement using roller follower on test benches

    Science.gov (United States)

    Potapov, A. S.; Svirbutovich, O. A.; Krivtsov, S. N.

    2018-03-01

    The article deals with rotation rate measurement errors, which depend on the motor vehicle rate, on the roller, test benches. Monitoring of the vehicle performance under operating conditions is performed on roller test benches. Roller test benches are not flawless. They have some drawbacks affecting the accuracy of vehicle performance monitoring. Increase in basic velocity of the vehicle requires increase in accuracy of wheel rotation rate monitoring. It determines the degree of accuracy of mode identification for a wheel of the tested vehicle. To ensure measurement accuracy for rotation velocity of rollers is not an issue. The problem arises when measuring rotation velocity of a car wheel. The higher the rotation velocity of the wheel is, the lower the accuracy of measurement is. At present, wheel rotation frequency monitoring on roller test benches is carried out by following-up systems. Their sensors are rollers following wheel rotation. The rollers of the system are not kinematically linked to supporting rollers of the test bench. The roller follower is forced against the wheels of the tested vehicle by means of a spring-lever mechanism. Experience of the test bench equipment operation has shown that measurement accuracy is satisfactory at small rates of vehicles diagnosed on roller test benches. With a rising diagnostics rate, rotation velocity measurement errors occur in both braking and pulling modes because a roller spins about a tire tread. The paper shows oscillograms of changes in wheel rotation velocity and rotation velocity measurement system’s signals when testing a vehicle on roller test benches at specified rates.

  11. Low-load bench press and push-up induce similar muscle hypertrophy and strength gain.

    Science.gov (United States)

    Kikuchi, Naoki; Nakazato, Koichi

    2017-06-01

    To investigate the effect of push-up training with a similar load of to 40% of 1- repetition maximumal (1RM) bench press on muscle hypertrophy and strength gain in men. Eighteen male participants (age, 20.2 ± 0.73 years, range: 19-22 years, height: 169.8 ± 4.4 cm, weight: 64.5 ± 4.7 kg) were randomly assigned to one of two experimental groups: bench press at 40%1RM (bench-press group, n = 9) or push-ups with position adjusted (e.g. kneeling) to the same load of bench-press 40%1RM (push-up group, n = 9), performed twice per week for 8 weeks. Muscle thickness at three sites (biceps, triceps, and pectoralis major), bench-press 1RM, maximum repetition at 40%1RM, and power output (medicine ball throw) were measured before and after the training period. Significant increases in 1RM and muscle thickness (triceps and pectoralis major) were observed in bench-press group (1RM, from 60.0 ± 12.1 kg to 65.0 ± 12.1 kg, p bench-press group (28.4 ± 3.3 mm to 31.5 ± 3.7 mm, p bench press is comparably effective for muscle hypertrophy and strength gain over an 8-week training period.

  12. TACLeBench: A benchmark collection to support worst-case execution time research

    DEFF Research Database (Denmark)

    Falk, Heiko; Altmeyer, Sebastian; Hellinckx, Peter

    2016-01-01

    -source programs, adapted them to a common coding style, and provide the collection in open-source. The benchmark collection is called TACLeBench and is available from GitHub in version 1.9 at the publication date of this paper. One of the main features of TACLeBench is that all programs are self-contained without...... any dependencies on standard libraries or an operating system....

  13. Study of the boron homogenizing process employing an experimental low-pressure bench simulating the IRIS reactor pressurizer – Part I

    International Nuclear Information System (INIS)

    Bezerra, Jair de Lima; Lira, Carlos Alberto Brayner de Oliveira; Barroso, Antonio Carlos de Oliveira; Lima, Fernando Roberto de Andrade; Bezerra da Silva, Mário Augusto

    2013-01-01

    Highlights: ► Experimental bench with test section made of transparent acrylic, simulating the pressurizer reactor IRIS. ► Workbench used to study the process of homogenization of boron in the pressurizer IRIS nuclear reactor. ► Results were obtained through videos and digital photos of the test section. - Abstract: The reactivity control of a nuclear reactor to pressurized water is made by means of controlling bars or by boron dilution in the water from the coolant of a primary circuit. The control with boron dilution has great importance, despite inserting small variations in the reactivity in the reactor, as it does not significantly affect the distribution of the neutron flux. A simplified experimental bench with a test section manufactured in transparent acrylic, was built in reduced scale as to be used in a boron homogenizing process, simulating an IRIS reactor pressurizer (International Reactor Innovative and Secure). The bench was assembled in the Centro Regional de Ciências Nucleares do Nordeste (CRCN-NE), an entity linked to the Comissão Nacional de Energia Nuclear (CNEN), Recife – PE

  14. Study of the boron homogenizing process employing an experimental low-pressure bench simulating the IRIS reactor pressurizer – Part II

    International Nuclear Information System (INIS)

    Bezerra, Jair de Lima; Lira, Carlos Alberto Brayner de Oliveira; Barroso, Antonio Carlos de Oliveira; Lima, Fernando Roberto de Andrade; Silva, Mário Augusto Bezerra da

    2013-01-01

    Highlights: • Experimental bench with test section made of transparent acrylic, simulating the pressurizer reactor IRIS. • Workbench used to study the process of homogenization of boron in the pressurizer IRIS nuclear reactor. • Results were obtained through videos and digital photos of the test section. - Abstract: The reactivity control of a nuclear reactor to pressurized water is made by means of controlling bars or by boron dilution in the water from the coolant of a primary circuit. The control with boron dilution has great importance, despite inserting small variations in the reactivity in the reactor, as it does not significantly affect the distribution of the neutron flux. A simplified experimental bench with a test section manufactured in transparent acrylic, was built in reduced scale as to be used in a boron homogenizing process, simulating an IRIS reactor pressurizer (International Reactor Innovative and Secure). The bench was assembled in the Centro Regional de Ciências Nucleares do Nordeste (CRCN-NE), an entity linked to the Comissão Nacional de Energia Nuclear (CNEN), Recife–PE

  15. Effect of Fatigue Upon Performance and Electromyographic Activity in 6-RM Bench Press.

    Science.gov (United States)

    van den Tillaar, Roland; Saeterbakken, Atle

    2014-03-27

    The aim of this study was to examine the effect of fatigue during one set of 6-RM bench pressing upon the muscle patterning and performance. Fourteen resistance-trained males (age 22.5±2.0 years, stature 1.82±0.07 m, body mass 82.0±7.8 kg) conducted a 6-RM bench press protocol. Barbell kinematics and EMG activity of pectoralis major, deltoid anterior, biceps brachii, triceps brachii, rectus abdominis, oblique external and erector spinae were measured in each repetition during the 6-RM bench press. Total lifting time increased and the velocity in the ascending movement decreased (p≤0.001). However, the kinematics in the descending phase deferred: the time decreased and velocity increased during the 6-RM (p≤0.001). Generally, muscles increased their EMG amplitude during the six repetitions in the ascending movement, while only three of the seven measured muscles showed an increase over the six repetitions in the descending part in 6-RM bench pressing. It was concluded that the bench pressing performance decreased (lower barbell velocities and longer lifting times) with increasing fatigue in the 6-RM execution. Furthermore EMG increased in the prime movers and the trunk stabilizers (abdominal and spine), while the antagonist muscle (biceps) activity was not affected by fatigue during the lifting phase in a single set of 6-RM bench pressing.

  16. Location of Instability During a Bench Press Alters Movement Patterns and Electromyographical Activity.

    Science.gov (United States)

    Nairn, Brian C; Sutherland, Chad A; Drake, Janessa D M

    2015-11-01

    Instability training devices with the bench press exercise are becoming increasingly popular. Typically, the instability device is placed at the trunk/upper body (e.g., lying on a Swiss ball); however, a recent product called the Attitube has been developed, which places the location of instability at the hands by users lifting a water-filled tube. Therefore, the purpose of this study was to analyze the effects of different instability devices (location of instability) on kinematic and electromyographical patterns during the bench press exercise. Ten healthy males were recruited and performed 1 set of 3 repetitions for 3 different bench press conditions: Olympic bar on a stable bench (BENCH), Olympic bar on a stability ball (BALL), and Attitube on a stable bench (TUBE). The eccentric and concentric phases were analyzed in 10% intervals while electromyography was recorded from 24 electrode sites, and motion capture was used to track elbow flexion angle and 3-dimensional movement trajectories and vertical velocity of the Bar/Attitube. The prime movers tended to show a reduction in muscle activity during the TUBE trials; however, pectoralis major initially showed increased activation during the eccentric phase of the TUBE condition. The trunk muscle activations were greatest during the TUBE and smallest during the BAR. In addition, the TUBE showed decreased range of elbow flexion and increased medial-lateral movement of the Attitube itself. The results further support the notion that instability devices may be more beneficial for trunk muscles rather than prime movers.

  17. Contextual interference effects on the acquisition of skill and strength of the bench press.

    Science.gov (United States)

    Naimo, Marshall A; Zourdos, Michael C; Wilson, Jacob M; Kim, Jeong-Su; Ward, Emery G; Eccles, David W; Panton, Lynn B

    2013-06-01

    The purpose of this study was to investigate contextual interference effects on skill acquisition and strength gains during the learning of the bench press movement. Twenty-four healthy, college-aged males and females were stratified to control, high contextual interference (HCI), and low contextual interference (LCI) groups. Treatment groups were provided with written and visual instruction on proper bench press form and practiced the bench press and dart throwing for four weeks. Within each session, LCI performed all bench press sets before undertaking dart-throws. HCI undertook dart-throws immediately following each set of bench press. Control only did testing. Measurements, including one repetition maximum (1RM), checklist scores based on video recordings of participants' 1RM's, and dart-throw test scores were taken at pre-test, 1 week, 2 week, post-test, and retention test. Results were consistent with the basic premise of the contextual interference effect. LCI had significant improvements in percent 1RM and checklist scores during training, but were mostly absent after training (post-test and retention test). HCI had significant improvements in percent 1RM and checklist scores both during and after training. Thus, HCI may augment strength and movement skill on the bench press since proper technique is an important component of resistance exercise movements. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Hydrotreating of triglyceride containing gasoils

    Energy Technology Data Exchange (ETDEWEB)

    Krar, M.; Kasza, T.; Toth, C.; Baladincz, P.; Hancsok, J. (Univ. of Pannonia, Veszprem (Hungary)), Email: krarm@almos.uni-pannon.hu

    2009-07-01

    Because of the disadvantages of biodiesel, it is necessary to develop transformation methods, where excellent quality gas oil blending components are produced from triglycerides. An especially favourable opportunity could be the combination of the conversion of the triglycerides with a simultaneous upgrading of the gas oil stream. The main goal of our experiments was to investigate the feasibility of these two processes simultaneously in one catalytic system. In our experiments, sunflower oil (max. 25 %) gas oil blends were converted into products with gas oil boiling range. On the investigated catalyst under optimal process parameter combinations, product mixtures in the gas oil boiling point range with yield and excellent quality was produced successfully. The cetane number of the product mixtures were increased by 4-16 units, the CFPP values were increased by 5-7 deg C, when feedstock with 25 % sunflower oil content was used instead of feedstocks containing no sunflower oil. The reason is that the triglycerides were converted into normal paraffins, which are having high cetane number and poor cold-flow properties. It was concluded, that the blending of the sunflower oil into the gas oil did not reduce the HDS and HDA activity of the catalyst, however, its HDN activity significantly decreased. (orig.)

  19. Biodiesel via hydrotreating of fat

    DEFF Research Database (Denmark)

    Madsen, Anders Theilgaard; Ahmed, El Hadi; Christensen, Claus Hviid

    Biodiesel production via transesterification to fatty acid alkyl esters is rising rapidly worldwide due to the limited availability of fossil resources and the problems of global warming. Often, however, the use of 2nd-generation feedstock like animal waste fat and trap greases etc. is made...

  20. Reliability assessment of ballistic jump squats and bench throws.

    Science.gov (United States)

    Alemany, Joseph A; Pandorf, Clay E; Montain, Scott J; Castellani, John W; Tuckow, Alexander P; Nindl, Bradley C

    2005-02-01

    The purpose of this investigation was to determine the test-retest reliability and coefficient of variation of 2 novel physical performance tests. Ten healthy men (22.0 +/- 3.0 years, 87.0 +/- 8.0 kg, 20.0 +/- 5.0% body fat) performed 30 continuous and dynamic jump squats (JS) and bench throws (BT) on 4 separate occasions. The movements were performed under loaded conditions utilizing 30% of subject's predetermined 1 repetition maximum in the back squat and bench press. Mean power (MP; W), peak power (PP; W), mean velocity (MV; m.s(-1)), peak velocity (PV; m.s(-1)), and total work (TW; J) were assessed using a ballistic measurement system (Innervations Inc., Muncie, IN). Data were analyzed using repeated measures analysis of variance with Duncan's post hoc test when mean differences were p < or = 0.05. Intraclass correlation coefficient (ICC) and within-subject coefficient of variation (CV%) were also calculated. All values are presented as mean +/- SE. BT variables were statistically similar across the 4 sessions: MP (350.0 +/- 13.9 W), PP (431.4 +/- 18.5 W) MV (1.6 +/- 0.03 m.s(-1)), PV (2.0 +/- 0.03 m.s(-1)), and TW (199.1 +/- 7.2 J). For JS, session 3 PP (1,669.8 +/- 111.2 W) was significantly greater vs. sessions 1, 2, and 4 (1,601.2 +/- 58.4 W). Session 4 MP (1,403.2 +/- 88.6 W) and MV (1.9 +/- 0.1 m.s(-1)) for JS were significantly lower during sessions 1, 2, and 3 (MP: 1,479.4.5 +/- 44.8 W, MV: 2.0 +/- 0.05 m.s(-1)). TW (834.7 +/- 24.3 J) and PV (2.2 +/- 0.04 m.s(-1)) were statistically similar during all sessions for JS. The CVs ranged from 3.0 to 7.6% for the BT and 3.2 to 5.7% for the JS. ICCs for MP, PP, MV, PV, and TW were 0.92, 0.95, 0.94, 0.91, and 0.95, respectively, during BT. ICCs during JS for MP, PP, MV, PV, and TW were 0.96, 0.98, 0.94, 0.94, and 0.89, respectively. The results of the current study support the use of a 30 continuous and dynamic BT protocol as a reliable upper-body physical performance test, which can be administered with

  1. ESCRIME: testing bench for advanced operator workstations in future plants

    International Nuclear Information System (INIS)

    Poujol, A.; Papin, B.

    1994-01-01

    The problem of optimal task allocation between man and computer for the operation of nuclear power plants is of major concern for the design of future plants. As the increased level of automation induces the modification of the tasks actually devoted to the operator in the control room, it is very important to anticipate these consequences at the plant design stage. The improvement of man machine cooperation is expected to play a major role in minimizing the impact of human errors on plant safety. The CEA has launched a research program concerning the evolution of the plant operation in order to optimize the efficiency of the human/computer systems for a better safety. The objective of this program is to evaluate different modalities of man-machine share of tasks, in a representative context. It relies strongly upon the development of a specific testing facility, the ESCRIME work bench, which is presented in this paper. It consists of an EDF 1300MWe PWR plant simulator connected to an operator workstation. The plant simulator model presents at a significant level of details the instrumentation and control of the plant and the main connected circuits. The operator interface is based on the generalization of the use of interactive graphic displays, and is intended to be consistent to the tasks to be performed by the operator. The functional architecture of the workstation is modular, so that different cooperation mechanisms can be implemented within the same framework. It is based on a thorough analysis and structuration of plant control tasks, in normal as well as in accident situations. The software architecture design follows the distributed artificial intelligence approach. Cognitive agents cooperate in order to operate the process. The paper presents the basic principles and the functional architecture of the test bed and describes the steps and the present status of the program. (author)

  2. Eating disorders: from bench to bedside and back.

    Science.gov (United States)

    Gaetani, Silvana; Romano, Adele; Provensi, Gustavo; Ricca, Valdo; Lutz, Thomas; Passani, Maria Beatrice

    2016-12-01

    The central nervous system and viscera constitute a functional ensemble, the gut-brain axis, that allows bidirectional information flow that contributes to the control of feeding behavior based not only on the homeostatic, but also on the hedonic aspects of food intake. The prevalence of eating disorders, such as anorexia nervosa, binge eating and obesity, poses an enormous clinical burden, and involves an ever-growing percentage of the population worldwide. Clinical and preclinical research is constantly adding new information to the field and orienting further studies with the aim of providing a foundation for developing more specific and effective treatment approaches to pathological conditions. A recent symposium at the XVI Congress of the Societá Italiana di Neuroscienze (SINS, 2015) 'Eating disorders: from bench to bedside and back' brought together basic scientists and clinicians with the objective of presenting novel perspectives in the neurobiology of eating disorders. Clinical studies presented by V. Ricca illustrated some genetic aspects of the psychopathology of anorexia nervosa. Preclinical studies addressed different issues ranging from the description of animal models that mimic human pathologies such as anorexia nervosa, diet-induced obesity, and binge eating disorders (T. Lutz), to novel interactions between peripheral signals and central circuits that govern food intake, mood and stress (A. Romano and G. Provensi). The gut-brain axis has received increasing attention in the recent years as preclinical studies are demonstrating that the brain and visceral organs such as the liver and guts, but also the microbiota are constantly engaged in processes of reciprocal communication, with unexpected physiological and pathological implications. Eating is controlled by a plethora of factors; genetic predisposition, early life adverse conditions, peripheral gastrointestinal hormones that act directly or indirectly on the central nervous system, all are

  3. Bench calibration of INDUS-2 beam position indicators

    International Nuclear Information System (INIS)

    Tyagi, Y.; Banerji, Anil; Kotaiah, S.

    2005-01-01

    A third generation synchrotron radiation source of energy 2.5 GeV named INDUS-2 at Centre for Advanced Technology (C.A.T), Indore (M.P) is in the advanced stage of construction. Accurate determination and correction of beam closed orbit in INDUS-2 machine within 100 of microns is a very desirable goal. Bench based calibration of Beam Position Indicators (BPI) play a very important and useful role during initial commissioning of electron machines. To precisely measure transverse position of electron beam in the Indus-2 storage ring, 56 Beam Position Indicators (BPI) will be installed in INDUS-2 machine. Out of 56 Beam Position Indicators 40 are of individual type whereas 16 are integrated with dipole vacuum chamber. The Beam Position Indicators are required to be calibrated before they can be installed. The calibration is done to determine electrical offset with respect to defined mechanical centre, to determine displacement sensitivities as well as non linearity's of BPI. Ideally when beam passes through the geometrical center of BPI's, all electrodes should have same signal strength. However due to different capacitance of electrodes and offset and drift in electronics, the electrical centre (mechanical x, y where all electrodes shows same signal strength) differs from mechanical centre of BPI. A fully automatic calibration system has been developed to carry out the calibration of Beam Position Indicators. A calibration software has been developed which has necessary utilities to process and display calibration data and results. This paper describes the calibration results of Indus-2 BPM. (author)

  4. Bench-test comparison of 26 emergency and transport ventilators.

    Science.gov (United States)

    L'Her, Erwan; Roy, Annie; Marjanovic, Nicolas

    2014-10-15

    Numerous emergency and transport ventilators are commercialized and new generations arise constantly. The aim of this study was to evaluate a large panel of ventilators to allow clinicians to choose a device, taking into account their specificities of use. This experimental bench-test took into account general characteristics and technical performances. Performances were assessed under different levels of FIO2 (100%, 50% or Air-Mix), respiratory mechanics (compliance 30,70,120 mL/cmH2O; resistance 5,10,20 cmH2O/mL/s), and levels of leaks (3.5 to 12.5 L/min), using a test lung. In total 26 emergency and transport ventilators were analyzed and classified into four categories (ICU-like, n = 5; Sophisticated, n = 10; Simple, n = 9; Mass-casualty and military, n = 2). Oxygen consumption (7.1 to 15.8 L/min at FIO2 100%) and the Air-Mix mode (FIO2 45 to 86%) differed from one device to the other. Triggering performance was heterogeneous, but several sophisticated ventilators depicted triggering capabilities as efficient as ICU-like ventilators. Pressurization was not adequate for all devices. At baseline, all the ventilators were able to synchronize, but with variations among respiratory conditions. Leak compensation in most ICU-like and 4/10 sophisticated devices was able to correct at least partially for system leaks, but with variations among ventilators. Major differences were observed between devices and categories, either in terms of general characteristics or technical reliability, across the spectrum of operation. Huge variability of tidal volume delivery with some devices in response to modifications in respiratory mechanics and FIO2 should make clinicians question their use in the clinical setting.

  5. CPAP Devices for Emergency Prehospital Use: A Bench Study.

    Science.gov (United States)

    Brusasco, Claudia; Corradi, Francesco; De Ferrari, Alessandra; Ball, Lorenzo; Kacmarek, Robert M; Pelosi, Paolo

    2015-12-01

    CPAP is frequently used in prehospital and emergency settings. An air-flow output minimum of 60 L/min and a constant positive pressure are 2 important features for a successful CPAP device. Unlike hospital CPAP devices, which require electricity, CPAP devices for ambulance use need only an oxygen source to function. The aim of the study was to evaluate and compare on a bench model the performance of 3 orofacial mask devices (Ventumask, EasyVent, and Boussignac CPAP system) and 2 helmets (Ventukit and EVE Coulisse) used to apply CPAP in the prehospital setting. A static test evaluated air-flow output, positive pressure applied, and FIO2 delivered by each device. A dynamic test assessed airway pressure stability during simulated ventilation. Efficiency of devices was compared based on oxygen flow needed to generate a minimum air flow of 60 L/min at each CPAP setting. The EasyVent and EVE Coulisse devices delivered significantly higher mean air-flow outputs compared with the Ventumask and Ventukit under all CPAP conditions tested. The Boussignac CPAP system never reached an air-flow output of 60 L/min. The EasyVent had significantly lower pressure excursion than the Ventumask at all CPAP levels, and the EVE Coulisse had lower pressure excursion than the Ventukit at 5, 15, and 20 cm H2O, whereas at 10 cm H2O, no significant difference was observed between the 2 devices. Estimated oxygen consumption was lower for the EasyVent and EVE Coulisse compared with the Ventumask and Ventukit. Air-flow output, pressure applied, FIO2 delivered, device oxygen consumption, and ability to maintain air flow at 60 L/min differed significantly among the CPAP devices tested. Only the EasyVent and EVE Coulisse achieved the required minimum level of air-flow output needed to ensure an effective therapy under all CPAP conditions. Copyright © 2015 by Daedalus Enterprises.

  6. Therapeutics discovery: From bench to first in-human trials.

    Science.gov (United States)

    Al-Hujaily, Ensaf M; Khatlani, Tanvir; Alehaideb, Zeyad; Ali, Rizwan; Almuzaini, Bader; Alrfaei, Bahauddeen M; Iqbal, Jahangir; Islam, Imadul; Malik, Shuja; Marwani, Bader A; Massadeh, Salam; Nehdi, Atef; Alsomaie, Barrak; Debasi, Bader; Bushnak, Ibraheem; Noibi, Saeed; Hussain, Syed; Wajid, Wahid Abdul; Armand, Jean-Pierre; Gul, Sheraz; Oyarzabal, Julen; Rais, Rana; Bountra, Chas; Alaskar, Ahmed; Knawy, Bander Al; Boudjelal, Mohamed

    2018-03-01

    The 'Therapeutics discovery: From bench to first in-human trials' conference, held at the King Abdullah International Medical Research Center (KAIMRC), Ministry of National Guard Health Affairs (MNGHA), Kingdom of Saudi Arabia (KSA) from October 10-12, 2017, provided a unique opportunity for experts worldwide to discuss advances in drug discovery and development, focusing on phase I clinical trials. It was the first event of its kind to be hosted at the new research center, which was constructed to boost drug discovery and development in the KSA in collaboration with institutions, such as the Academic Drug Discovery Consortium in the United States of America (USA), Structural Genomics Consortium of the University of Oxford in the United Kingdom (UK), and Institute of Materia Medica of the Chinese Academy of Medical Sciences in China. The program was divided into two parts. A pre-symposium day took place on October 10, during which courses were conducted on clinical trials, preclinical drug discovery, molecular biology and nanofiber research. The attendees had the opportunity for one-to-one meetings with international experts to exchange information and foster collaborations. In the second part of the conference, which took place on October 11 and 12, the clinical trials pipeline, design and recruitment of volunteers, and economic impact of clinical trials were discussed. The Saudi Food and Drug Administration presented the regulations governing clinical trials in the KSA. The process of preclinical drug discovery from small molecules, cellular and immunologic therapies, and approaches to identifying new targets were also presented. The recommendation of the conference was that researchers in the KSA must invest more fund, talents and infrastructure to lead the region in phase I clinical trials and preclinical drug discovery. Diseases affecting the local population, such as Middle East Respiratory Syndrome and resistant bacterial infections, represent the optimal

  7. Multifaceted bench comparative evaluation of latest intensive care unit ventilators.

    Science.gov (United States)

    Garnier, M; Quesnel, C; Fulgencio, J-P; Degrain, M; Carteaux, G; Bonnet, F; Similowski, T; Demoule, A

    2015-07-01

    Independent bench studies using specific ventilation scenarios allow testing of the performance of ventilators in conditions similar to clinical settings. The aims of this study were to determine the accuracy of the latest generation ventilators to deliver chosen parameters in various typical conditions and to provide clinicians with a comprehensive report on their performance. Thirteen modern intensive care unit ventilators were evaluated on the ASL5000 test lung with and without leakage for: (i) accuracy to deliver exact tidal volume (VT) and PEEP in assist-control ventilation (ACV); (ii) performance of trigger and pressurization in pressure support ventilation (PSV); and (iii) quality of non-invasive ventilation algorithms. In ACV, only six ventilators delivered an accurate VT and nine an accurate PEEP. Eleven devices failed to compensate VT and four the PEEP in leakage conditions. Inspiratory delays differed significantly among ventilators in invasive PSV (range 75-149 ms, P=0.03) and non-invasive PSV (range 78-165 ms, Pventilation algorithms efficiently prevented the decrease in pressurization capacities and PEEP levels induced by leaks in, respectively, 10 and 12 out of the 13 ventilators. We observed real heterogeneity of performance amongst the latest generation of intensive care unit ventilators. Although non-invasive ventilation algorithms appear to maintain adequate pressurization efficiently in the case of leakage, basic functions, such as delivered VT in ACV and pressurization in PSV, are often less reliable than the values displayed by the device suggest. © The Author 2015. Published by Oxford University Press on behalf of the British Journal of Anaesthesia. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  8. A comparison of muscle activity in concentric and counter movement maximum bench press.

    Science.gov (United States)

    van den Tillaar, Roland; Ettema, Gertjan

    2013-01-01

    The purpose of this study was to compare the kinematics and muscle activation patterns of regular free-weight bench press (counter movement) with pure concentric lifts in the ascending phase of a successful one repetition maximum (1-RM) attempt in the bench press. Our aim was to evaluate if diminishing potentiation could be the cause of the sticking region. Since diminishing potentiation cannot occur in pure concentric lifts, the occurrence of a sticking region in this type of muscle actions would support the hypothesis that the sticking region is due to a poor mechanical position. Eleven male participants (age 21.9 ± 1.7 yrs, body mass 80.7 ± 10.9 kg, body height 1.79 ± 0.07 m) conducted 1-RM lifts in counter movement and in pure concentric bench presses in which kinematics and EMG activity were measured. In both conditions, a sticking region occurred. However, the start of the sticking region was different between the two bench presses. In addition, in four of six muscles, the muscle activity was higher in the counter movement bench press compared to the concentric one. Considering the findings of the muscle activity of six muscles during the maximal lifts it was concluded that the diminishing effect of force potentiation, which occurs in the counter movement bench press, in combination with a delayed muscle activation unlikely explains the existence of the sticking region in a 1-RM bench press. Most likely, the sticking region is the result of a poor mechanical force position.

  9. Test-bench for characterization of steady state magnetic sensors parameters in wide temperature range

    International Nuclear Information System (INIS)

    Kovařík, Karel; Ďuran, Ivan; Sentkerestiová, Jana; Šesták, David

    2013-01-01

    Highlights: •Prepared test bench for calibration of steady state magnetic sensors. •Test-bench design optimized for calibration up to 300 °C. •Test-bench is remotely controllable and allows long term measurements. •Construction allows easy manipulation with even irradiated samples. -- Abstract: Magnetic sensors in ITER tokamak and in other future fusion devices will face an environment with temperature often elevated well above 200 °C. Dedicated test benches are needed to allow characterization of performance of magnetic sensors at such elevated temperatures. This contribution describes realization of test bench for calibration of steady state magnetic sensors based on Hall effect. The core of the set-up is the coil providing DC calibration magnetic field. Optimization of coils design to ensure its compatibility with elevated temperature up to 300 °C is described. Optimized coil was manufactured, and calibrated both at room temperature and at temperature of 250 °C. Measured calibration magnetic field of the coil biased by a 30 A commercial laboratory power supplies is 224 mT. The coil is supplemented by PID regulated air cooling system for fine control of sensors temperature during measurements. Data acquisition system is composed from PC A/D converter boards with resolution below 1 μV. The key parameters of the test bench are remotely controllable and the system allows long term continuous measurements including tests of irradiated samples. The performance of the test bench is demonstrated on recent measurements with metal Hall sensors based on thin copper sensing layers

  10. Comparison of complex effluent treatability in different bench scale microbial electrolysis cells

    KAUST Repository

    Ullery, Mark L.; Logan, Bruce E.

    2014-01-01

    between the two reactor designs for individual samples, with 66-92% of COD removed for all samples. Current generation was consistent between the reactor types for acetate (AC) and fermentation effluent (FE) samples, but less consistent with industrial (IW

  11. Biofilm Community Dynamics in Bench-Scale Annular Reactors Simulating Arrestment of Chloraminated Drinking Water Nitrification

    Science.gov (United States)

    Annular reactors (ARs) were used to study biofilm community succession and provide an ecological insight during nitrification arrestment through simultaneously increasing monochloramine (NH2Cl) and chlorine to nitrogen mass ratios, resulting in four operational periods (I to IV)....

  12. Bench scale studies on separation of rare earths by ion exchange

    International Nuclear Information System (INIS)

    Aroonrung-Areeya, A.

    1976-01-01

    The method of ion exchange was applied to the separation of mixtures of rare earth oxides into the pure components. The method consists of eluting a band of mixed rare earths adsorbed on a cation-exchange resin through a second cation-exchange bed in the copper II state. The eluent consists of an ammonia buffered solution of ethylenediamine tetraacetic acid. The mixed rare earth oxide used as testing material was obtained from the digestion of Thai monazite. The amounts varied from 1, 5 to 50 grams. The purity of the rare earth fractions were analyzed either by neutron activation of X-ray fluorescence. The Cu.EDTA was recovered by the addition of lime. It was found that gram quantities of pure rare earths could be obtained by this method

  13. Biodegradation of alkanolamine-related wastes in bioslurries and bench-scale landfarms

    International Nuclear Information System (INIS)

    Gallagher, J.R.; Sorensen, J.A.; Knutson, R.

    1997-01-01

    The subsurface transport and fate of monoethanolamine (MEA) and its related reaction products were studied and the effectiveness of landfarming as a technique for the remediation of MEA-sludge contaminated soil was examined. MEAs are used regularly by the natural gas industry to remove hydrogen sulfide, carbon dioxide and other acid gases from natural gas. The following critical issues were examined: (1) the biodegradability of the recalcitrant fraction observed in slurry bioreactor investigations, (2) the biodegradability of selected MEA-related thermal reaction products, and (3) the effectiveness of landfarming for the remediation of MEA-contaminated soils. Key factors that may limit biodegradation of the recalcitrant fraction of organic matter in MEA wastes included inhibition due to ammonia, nutrient limitations, and insufficient time to adapt to the material and inherent resistance to biodegradation. A land treatment alternative that collects leachate for possible treatment may be the most suitable method to deal with these wastes

  14. Copper recovery in a bench-scale carrier facilitated tubular supported liquid membrane system

    Directory of Open Access Journals (Sweden)

    Makaka S.

    2010-01-01

    Full Text Available The extraction of copper ions in a tubular supported liquid membrane using LIX 984NC as a mobile carrier was studied, evaluating the effect of the feed characteristics (flowrate, density, viscosity on the feedside laminar layer of the membrane. A vertical countercurrent, double pipe perspex benchscale reactor consisting of a single hydrophobic PVDF tubular membrane mounted inside was used in all test work. The membrane was impregnated with LIX 984NC and became the support for this organic transport medium. Dilute Copper solution passed through the centre pipe and sulphuric acid as strippant passed through the shell side. Copper was successfully transported from the feedside to the stripside and from the data obtained, a relationship between Schmidt, Reynolds and Sherwood number was achieved of.

  15. Recommendations for Filler Material Composition and Delivery Method for Bench-Scale Testing

    Energy Technology Data Exchange (ETDEWEB)

    Hardin, Ernest [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Brady, Patrick Vane [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2018-03-01

    This report supplements Joint Workplan on Filler Investigations for DPCs (SNL 2017) providing new and some corrected information for use in planning Phase 1 laboratory testing of slurry cements as possible DPC fillers. The scope description is to "Describe a complete laboratory testing program for filler composition, delivery, emplacement in surrogate canisters, and post-test examination. To the extent possible specify filler material and equipment sources." This report includes results from an independent expert review (Dr. Arun Wagh, retired from Argonne National Laboratory and contracted by Sandia) that helped to narrow the range of cement types for consideration, and to provide further guidance on mix variations to optimize injectability, durability, and other aspects of filler performance.

  16. BENCH-SCALE EVALUATION OF AMMONIA REMOVAL FROM WASTEWATER BY STEAM STRIPPING

    Science.gov (United States)

    The purpose of the study was to generate laboratory data to support the development of wastewater discharge standards for ammonia in nonferrous metal winning processes. The objective was accomplished by studying ammonia removal from synthetically compounded 'wastewater' samples u...

  17. Bench Scale Treatability Studies of Contaminated Soil Using Soil Washing Technique

    OpenAIRE

    Gupta, M. K.; Srivastava, R. K.; Singh, A. K.

    2010-01-01

    Soil contamination is one of the most widespread and serious environmental problems confronting both the industrialized as well as developing nations like India. Different contaminants have different physicochemical properties, which influence the geochemical reactions induced in the soils and may bring about changes in their engineering and environmental behaviour. Several technologies exist for the remediation of contaminated soil and water. In the present study soil washing technique using...

  18. Bench Scale Treatability Studies of Contaminated Soil Using Soil Washing Technique

    Directory of Open Access Journals (Sweden)

    M. K. Gupta

    2010-01-01

    Full Text Available Soil contamination is one of the most widespread and serious environmental problems confronting both the industrialized as well as developing nations like India. Different contaminants have different physicochemical properties, which influence the geochemical reactions induced in the soils and may bring about changes in their engineering and environmental behaviour. Several technologies exist for the remediation of contaminated soil and water. In the present study soil washing technique using plain water with surfactants as an enhancer was used to study the remediation of soil contaminated with (i an organic contaminant (engine lubricant oil and (ii an inorganic contaminant (heavy metal. The lubricant engine oil was used at different percentages (by dry weight of the soil to artificially contaminate the soil. It was found that geotechnical properties of the soil underwent large modifications on account of mixing with the lubricant oil. The sorption experiments were conducted with cadmium metal in aqueous medium at different initial concentration of the metal and at varying pH values of the sorbing medium. For the remediation of contaminated soil matrices, a nonionic surfactant was used for the restoration of geotechnical properties of lubricant oil contaminated soil samples, whereas an anionic surfactant was employed to desorb cadmium from the contaminated soil matrix. The surfactant in case of soil contaminated with the lubricant oil was able to restore properties to an extent of 98% vis-à-vis the virgin soil, while up to 54% cadmium was desorbed from the contaminated soil matrix in surfactant aided desorption experiments.

  19. Technical Approach for In Situ Biological Treatment Research: Bench- Scale Experiments

    Science.gov (United States)

    1993-08-01

    1984) have summarized the structure, degrada- bility, and toxicity of hydrocarbons in soil based on the reviews of Bartha and Atlas (1977), Atlas (1981...the environmental charac- teristics and microbial ecology of specific microorganisms that are active on petroleum hydrocarbons in nature is very limited...addition to the reviews of Atlas (1981), (1984), see Jones (1977); Westlake, Jobson, and Cook (1978); Dibble and Bartha (1979); Fedorak and Westlake

  20. From a single pellet press to a bench scale pellet mill - Pelletizing six different biomass feedstocks

    DEFF Research Database (Denmark)

    Puig Arnavat, Maria; Shang, Lei; Sárossy, Zsuzsa

    2016-01-01

    The increasing demand for biomass pellets requires the investigation of alternative raw materials for pelletizetion. In the present paper, the pelletization process of fescue, alfalfa, sorghum, triticale, miscanthus and willow is studied to determine if results obtained in a single pellet press (...

  1. Heavy metal contaminant remediation study of western Xiamen Bay sediment, China: laboratory bench scale testing results.

    Science.gov (United States)

    Zhang, Luoping; Feng, Huan; Li, Xiaoxia; Ye, Xin; Jing, Youhai; Ouyang, Tong; Yu, Xingtian; Liang, Rongyuan; Chen, Weiqi

    2009-12-15

    A surface sediment sample (metal removal, whereas agitation, aeration and rotation of the samples in chemical complexation solutions yield much better metal removal efficiency (up to 90%). A low pH condition (e.g., pHliquid ratio (e.g., S:L=1:50) could increase metal removal efficiency. The experimental results suggest that 0.20 M (NH4)2C2O4+0.025 M EDTA combination with solid:liquid ratio=1:50 and 0.50 M ammonium acetate (NH4Ac)+0.025 M EDTA combination with solid:liquid ratio=1:50 are the most effective methods for metal removal from the contaminated sediments. This research provides additional useful information for sediment metal remediation technology development.

  2. DESIGN AND EVALUATION OF BENCH-SCALE COMPOST TREATMENT SYSTEM FOR HAZARDOUS WASTE

    Science.gov (United States)

    Soil bound contamination presents a significant set of problems to those attempting to remediate the soil. Bioremediation has received considerable attention, as a potential answer to the obvious remediation needs. Composting technology represents a promising means to use indigen...

  3. Bacterial communities associated with biofouling materials used in bench-scale hydrocarbon bioremediation.

    Science.gov (United States)

    Al-Mailem, Dina; Kansour, Mayada; Radwan, Samir

    2015-03-01

    Biofouling material samples from the Arabian (Persian) Gulf, used as inocula in batch cultures, brought about crude oil and pure-hydrocarbon removal in a mineral medium. Without any added nitrogen fertilizers, the hydrocarbon-removal values were between about 10 and 50 %. Fertilization with NaNO3 alone or together with a mixture of the vitamins thiamine, pyridoxine, vitamin B12, biotin, riboflavin, and folic acid increased the hydrocarbon-removal values, to reach 90 %. Biofouling material samples harbored total bacteria in the magnitude of 10(7) cells g(-1), about 25 % of which were hydrocarbonoclastic. These numbers were enhanced by NaNO3 and vitamin amendment. The culture-independent analysis of the total bacterioflora revealed the predominance of the gammaproteobacterial genera Marinobacter, Acinetobacter, and Alcanivorax, the Flavobacteriia, Flavobacterium, Gaetbulibacter, and Owenweeksia, and the Alphaproteobacteria Tistrella, Zavarzinia, and others. Most of those bacteria are hydrocarbonoclastic. Culture-dependent analysis of hydrocarbonoclastic bacteria revealed that Marinobacter hydrocarbonoclasticus, Dietzia maris, and Gordonia bronchialis predominated in the fouling materials. In addition, each material had several more-specific hydrocarbonoclastic species, whose frequencies were enhanced by NaNO3 and vitamin fertilization. The same samples of fouling materials were used in four successive crude-oil-removal cycles without any dramatic loss of their hydrocarbon-removal potential nor of their associated hydrocarbonoclastic bacteria. In the fifth cycle, the oil-removal value was reduced by about 50 % in only one of the studied samples. This highlights how firmly biofouling materials were immobilizing the hydrocarbonoclastic bacteria.

  4. Development of a bench-scale fluidized bed combustor (FBC) for ...

    African Journals Online (AJOL)

    The high technological level of equipment for combustion of fuels, as well as the necessity for rational and efficient use of non-renewable energy resources, has resulted demanding requirements that must be fulfilled by equipment for energy production, via combustion. These requirements form the characteristics of ...

  5. Evaluation of effluents from bench-scale treatment combinations for landfill leachate in Ibadan, Nigeria.

    Science.gov (United States)

    Aluko, Olufemi Oludare; Sridhar, Mkc

    2014-01-01

    The removal of pollutants in landfill leachate was investigated using constructed wetlands, a trickling filter, alum flocculation and coagulation, and a sequencing batch reactor in various combinations. Thirteen combined operations were investigated involving three out of the four unit treatment methods in series. The study was conducted because unit operations, though achieved reductions in pollutants concentrations had effluent values above the national regulatory guideline values. The suspended solids of effluents were permissible in most treatment processes, while reductions in 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD) and ammonia (NH3) of leachates ranged from 80% to 97%; 86% to 97% and 92% to 98% respectively. However, there were significant increases in nitrate (85%) and dissolved oxygen of treatment (218%). In addition, the characteristics of the recommended treatment sequence, involving constructed wetlands, alum and trickling filter produced effluents with reductions in colour (97%), alkalinity (97%), BOD (97%), COD (97%) and NH3 (98%), and in metals, except nickel (29% reduction from the influent values). The recommended treatment combination is suitable for effective leachate management at the landfill. The cost of constructing and operating the recommended treatment combination at the facility, for 5 years, would be NGN6,009,750.00 ($38,036.39). The performance should be monitored on site prior to full adoption if effluent characteristics remain consistently low over dry and wet seasons.

  6. Removal of uranium from uranium-contaminated soils -- Phase 1: Bench-scale testing

    International Nuclear Information System (INIS)

    Francis, C.W.

    1993-09-01

    To address the management of uranium-contaminated soils at Fernald and other DOE sites, the DOE Office of Technology Development formed the Uranium in Soils Integrated Demonstration (USID) program. The USID has five major tasks. These include the development and demonstration of technologies that are able to (1) characterize the uranium in soil, (2) decontaminate or remove uranium from the soil, (3) treat the soil and dispose of any waste, (4) establish performance assessments, and (5) meet necessary state and federal regulations. This report deals with soil decontamination or removal of uranium from contaminated soils. The report was compiled by the USID task group that addresses soil decontamination; includes data from projects under the management of four DOE facilities [Argonne National Laboratory (ANL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), and the Savannah River Plant (SRP)]; and consists of four separate reports written by staff at these facilities. The fundamental goal of the soil decontamination task group has been the selective extraction/leaching or removal of uranium from soil faster, cheaper, and safer than current conventional technologies. The objective is to selectively remove uranium from soil without seriously degrading the soil's physicochemical characteristics or generating waste forms that are difficult to manage and/or dispose of. Emphasis in research was placed more strongly on chemical extraction techniques than physical extraction techniques

  7. Degradation of polynuclear aromatic hydrocarbons under bench-scale compost conditions

    Energy Technology Data Exchange (ETDEWEB)

    Potter, C.L.; Glaser, J.A.; Chang, L.W.; Meier, J.R.; Dosani, M.A.; Herrmann, R.F. [US Environmental Protection Agency, Cincinnati, OH (United States). National Risk Management Research Lab.

    1999-05-15

    Polycyclic aromatic hydrocarbons are a concern at many sites, including wood-treating facilities and manufactured gas plants. This research sought to evaluate the relationship between aerobic biomass development and removal of 19 individual PAHs and toxicity from field soil during the composting process in in-vessel reactors located at the US Environmental Protection Agency (EPA) Test & Evaluation (T & E) Facility in Cincinnati, OH. Five compost amendment conditions were formulated from different nutrients or amendments to the reactor mixtures. Operating parameters of interest included aeration, moisture dynamics, and heat production. Toxicity tests were conducted to evaluate the effect of composting on soil toxicity. Seed germination and root elongation tests were evaluated in lettuce and oats, and genotoxicity (mitotic abberations) testing was performed on Allium cepa (onion). Composting of PAH contaminated soil decreased toxicity to earthworms and oat roots but had no significant effect on lettuce root toxicity. Untreated soil evoked genotoxicity in the Allium assay. After composting, no significant genotoxicity was observed in Reilly soil. 35 refs., 5 figs., 7 tabs.

  8. Engineering development of selective agglomeration: Task 5, Bench- scale process testing

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    Under the overall objectives of DOE Contract Engineering Development of Selective Agglomeration,'' there were a number of specific objectives in the Task 5 program. The prime objectives of Task 5 are highlighted below: (1) Maximize process performance in pyritic sulfur rejection and BTU recovery, (2) Produce a low ash product, (3) Compare the performance of the heavy agglomerant process based on diesel and the light agglomerant process using heptane, (4) Define optimum processing conditions for engineering design, (5) Provide first-level evaluation of product handleability, and (6) Explore and investigate process options/ideas which may enhance process performance and/or product handleability.

  9. Engineering development of selective agglomeration: Task 5, Bench- scale process testing

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    Under the overall objectives of DOE Contract ``Engineering Development of Selective Agglomeration,`` there were a number of specific objectives in the Task 5 program. The prime objectives of Task 5 are highlighted below: (1) Maximize process performance in pyritic sulfur rejection and BTU recovery, (2) Produce a low ash product, (3) Compare the performance of the heavy agglomerant process based on diesel and the light agglomerant process using heptane, (4) Define optimum processing conditions for engineering design, (5) Provide first-level evaluation of product handleability, and (6) Explore and investigate process options/ideas which may enhance process performance and/or product handleability.

  10. Bench scale testing - Phase I, Task 4. Topical progress report, September 1994--January 1995

    International Nuclear Information System (INIS)

    1995-07-01

    The Department of Energy (DOE) is now faced with the task of meeting decontamination and decommissioning obligations at numerous facilities by the year 2019. Due to the tremendous volume of material involved, innovative decontamination technologies are being sought that can reduce the volumes of contaminated waste materials and secondary wastes requiring disposal. With sufficient decontamination, some of the material from DOE facilities could be released as scrap into the commercial sector for recycle, thereby reducing the volume of radioactive waste requiring disposal. Although recycling may initially prove to be more costly than current disposal practices, rapidly increasing disposal costs are expected to make recycling more and more cost effective. Additionally, recycling is now perceived as the ethical choice in a world where the consequences of replacing resources and throwing away reusable materials are impacting the well-being of the environment

  11. Bench-Scale Investigation Of Mercury Phytoremediation By Water Hyacinths (Eichhornia crassipes) In Heavily Contaminated Sediments

    Science.gov (United States)

    Phytoremediation has the potential to be implemented at mercury (Hg) and methylmercury (MeHg) contaminated sites. Water hyacinths (Eichhornia crassipes) were investigated for their ability to assimilate Hg and MeHg into plant biomass, in both aquatic and sediment-associat...

  12. Bench evaluation of 7 home-care ventilators.

    Science.gov (United States)

    Blakeman, Thomas C; Rodriquez, Dario; Hanseman, Dennis; Branson, Richard D

    2011-11-01

    Portable ventilators continue to decrease in size while increasing in performance. We bench-tested the triggering, battery duration, and tidal volume (V(T)) of 7 portable ventilators: LTV 1000, LTV 1200, Puritan Bennett 540, Trilogy, Vela, iVent 101, and HT50. We tested triggering with a modified dual-chamber test lung to simulate spontaneous breathing with weak, normal, and strong inspiratory effort. We measured battery duration by fully charging the battery and operating the ventilator with a V(T) of 500 mL, a respiratory rate of 20 breaths/min, and PEEP of 5 cm H(2)O until breath-delivery ceased. We tested V(T) accuracy with pediatric ventilation scenarios (V(T) 50 mL or 100 mL, respiratory rate 50 breaths/min, inspiratory time 0.3 s, and PEEP 5 cm H(2)O) and an adult ventilation scenario (V(T) 400 mL, respiratory rate 30 breaths/min, inspiratory time 0.5 s, and PEEP 5 cm H(2)O). We measured and analyzed airway pressure, volume, and flow signals. At the adult settings the measured V(T) range was 362-426 mL. On the pediatric settings the measured V(T) range was 51-182 mL at the set V(T) of 50 mL, and 90-141 mL at the set V(T) of 100 mL. The V(T) delivered by the Vela at both the 50 mL and 100 mL, and by the HT50 at 100 mL, did not meet the American Society for Testing and Materials standard for V(T) accuracy. Triggering response and battery duration ranged widely among the tested ventilators. There was wide variability in battery duration and triggering sensitivity. Five of the ventilators performed adequately in V(T) delivery across several settings. The combination of high respiratory rate and low V(T) presented problems for 2 of the ventilators.

  13. A Coupling Vibration Test Bench and the Simulation Research of a Maglev Vehicle

    Directory of Open Access Journals (Sweden)

    Weihua Ma

    2015-01-01

    Full Text Available To study the characteristics of the coupling vibration between a maglev vehicle and its track beam system and to improve the performance of the levitation system, a new type of vibration test bench was developed. Take a single maglev frame as the study object; simulation of the coupling vibration of the maglev vehicle, levitation system, and track beam were achieved. In addition, all types of real track irregularity excitations can be simulated using hydraulic actuators of the test bench. To expand the research scope, a simulation model was developed that can conduct the simulation research synergistically with the test bench. Based on a dynamics model of the test bench, the dynamics simulation method determined the influence on the levitation control performance of three factors: the track beam support stiffness, the track beam mass, and the track irregularity. The vibration resonance phenomenon of the vehicle/track system was reproduced by the dynamics simulation, and a portion of the simulation results were validated by the test results. By combining the test bench and the dynamics model, experiments can be guided by the simulation results, and the experimental results can validate the dynamics simulation results.

  14. Test bench for measurements of NOvA scintillator properties at JINR

    Science.gov (United States)

    Velikanova, D. S.; Antoshkin, A. I.; Anfimov, N. V.; Samoylov, O. B.

    2018-04-01

    The NOvA experiment was built to study oscillation parameters, mass hierarchy, CP- violation phase in the lepton sector and θ23 octant, via vɛ appearance and vμ disappearance modes in both neutrino and antineutrino beams. These scientific goals require good knowledge about NOvA scintillator basic properties. The new test bench was constructed and upgraded at JINR. The main goal of this bench is to measure scintillator properties (for solid and liquid scintillators), namely α/β discrimination and Birk's coefficients for protons and other hadrons (quenching factors). This knowledge will be crucial for recovering the energy of the hadronic part of neutrino interactions with scintillator nuclei. α/β discrimination was performed on the first version of the bench for LAB-based and NOvA scintillators. It was performed again on the upgraded version of the bench with higher statistic and precision level. Preliminary result of quenching factors for protons was obtained. A technical description of both versions of the bench and current results of the measurements and analysis are presented in this work.

  15. Comparative Performance of Rear Facing Child Restraint Systems on the CMVSS 213 Bench and Vehicle Seats

    Science.gov (United States)

    Tylko, Suzanne; Locey, Caitlin M.; Garcia-Espana, J. Felipe; Arbogast, Kristy B.; Maltese, Matthew R.

    2013-01-01

    The purpose of this study was to compare the dynamic response of rear-facing child restraint systems (RFCRS) installed on the CMVSS 213 sled bench and a selection of vehicle seats. Thirty-six sled tests were conducted: three models of rear facing CRS with an anthropomorphic test device (ATD) representing a 12 month old child (CRABI) were affixed via lower anchors (LATCH), 3 point belt without CRS base, and 3 point belt with CRS base to one of three vehicle seats or the CMVSS 213 bench seat. All CRS were subjected to an identical sled acceleration pulse. Two types of matched pair analysis: “bench-to-vehicle” and “method of attachment” were conducted. Statistically significant differences were observed in the kinematic responses of the ATD and the CRS. This is the first study to quantify differences between the regulatory bench and vehicle seats on a system level and evaluate the influence of attachment method. Our results show that the difference in RFCRS forward excursion between 3-point belt with base and LATCH installations was between 1 and 7 percent on the bench and 22 to 76 percent on the vehicle seats. When evaluating the dynamic performance of RFCRS, the use of real vehicle seats from vehicles that commonly carry children may provide valuable insight. The findings would require further confirmation using a broader selection of RFCRS and vehicle seats, before generalizable conclusions can be drawn. PMID:24406967

  16. Effects of Variable Resistance Using Chains on Bench Throw Performance in Trained Rugby Players.

    Science.gov (United States)

    Godwin, Mark S; Fernandes, John F T; Twist, Craig

    2018-04-01

    Godwin, MS, Fernandes, JFT, and Twist, C. Effects of variable resistance using chains on bench throw performance in trained rugby players. J Strength Cond Res 32(4): 950-954, 2018-This study sought to determine the effects of variable resistance using chain resistance on bench throw performance. Eight male rugby union players (19.4 ± 2.3 years, 88.8 ± 6.0 kg, 1RM 105.6 ± 17.0 kg) were recruited from a national league team. In a randomized crossover design, participant's performed 3 bench throws at 45% one repetition maximum (1RM) at a constant load (no chains) or a variable load (30% 1RM constant load and 15% 1RM variable load; chains) with 7 days between conditions. For each repetition, the peak and mean velocity, peak power, peak acceleration, and time to peak velocity were recorded. Differences in peak and mean power were very likely trivial and unclear between the chain and no chain conditions, respectively. Possibly greater peak and likely greater mean bar velocity were accompanied by likely to most likely greater bar velocity between 50 and 400 ms from initiation of bench press in the chain condition compared with the no chain condition. Accordingly, bar acceleration was very likely greater in the chain condition compared with the no chain condition. In conclusion, these results show that the inclusion of chain resistance can acutely enhance several variables in the bench press throw and gives support to this type of training.

  17. Optimization Of Blasting Design Parameters On Open Pit Bench A Case Study Of Nchanga Open Pits

    Directory of Open Access Journals (Sweden)

    Victor Mwango Bowa

    2015-08-01

    Full Text Available Abstract In hard rock mining blasting is the most productive excavation technique applied to fragment insitu rock to the required size for efficient loading and crushing. In order to blast the insitu rock to the desired fragment size blast design parameter such as bench height hole diameter spacing burden hole length bottom charge specific charge and rock factor are considered. The research was carried out as a practical method on Nchanga Open Pits NOP ore Bench to optimize the blasting design parameters that can yield the required fragmentation size thereby reducing the shovel loading times and maximizing efficiency of the subsequent mining unit operations such as hauling and crushing. Fragmentation characteristics such as the mean fragment size were measured by means of a digital measuring tape and predicated using the Kuznetsov equation and rock factor value of ore bench was calculated using Lilly 1986 equations by means of rock characteristics. Traditional blasting design parameters were acquired for NOP and modified using Langerfors and Sharma P.A approaches. Several blast operations were conducted using both traditional and modified blasting design parameters on the same ore bench with the same geological conditions. Loading times of the shovel and fragment sizes were obtained after the blasts from ore bench where both the traditional and modified blasting design parameters were applied. Results show that mean fragment size and loading times were reduced from 51cm and 12minutes to 22cm and 3minutes where traditional and modified blasting design parameters were applied respectively.

  18. CarbonSAFE Rocky Mountain Phase I : Seismic Characterization of the Navajo Reservoir, Buzzard Bench, Utah

    Science.gov (United States)

    Haar, K. K.; Balch, R. S.; Lee, S. Y.

    2017-12-01

    The CarbonSAFE Rocky Mountain project team is in the initial phase of investigating the regulatory, financial and technical feasibility of commercial-scale CO2 capture and storage from two coal-fired power plants in the northwest region of the San Rafael Swell, Utah. The reservoir interval is the Jurassic Navajo Sandstone, an eolian dune deposit that at present serves as the salt water disposal reservoir for Ferron Sandstone coal-bed methane production in the Drunkards Wash field and Buzzard Bench area of central Utah. In the study area the Navajo sandstone is approximately 525 feet thick and is at an average depth of about 7000 feet below the surface. If sufficient porosity and permeability exist, reservoir depth and thickness would provide storage for up to 100,000 metric tonnes of CO2 per square mile, based on preliminary estimates. This reservoir has the potential to meet the DOE's requirement of having the ability to store at least 50 million metric tons of CO2 and fulfills the DOE's initiative to develop protocols for commercially sequestering carbon sourced from coal-fired power plants. A successful carbon storage project requires thorough structural and stratigraphic characterization of the reservoir, seal and faults, thereby allowing the creation of a comprehensive geologic model with subsequent simulations to evaluate CO2/brine migration and long-term effects. Target formation lithofacies and subfacies data gathered from outcrop mapping and laboratory analysis of core samples were developed into a geologic model. Synthetic seismic was modeled from this, allowing us to seismically characterize the lithofacies of the target formation. This seismic characterization data was then employed in the interpretation of 2D legacy lines which provided stratigraphic and structural control for more accurate model development of the northwest region of the San Rafael Swell. Developing baseline interpretations such as this are crucial toward long-term carbon storage

  19. Design and construction of the HESR BPM prototype wire test bench at COSY, Forschungzentrum Juelich

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, Sudharsan; Kamerdzhiev, Vsevolod; Boehme, Christian [Forschungszentrum Juelich GmbH (Germany)

    2016-07-01

    The Institute of Nuclear Physics 4(IKP-4), of the Research Center Juelich (FZJ), is in charge of building and commissioning the High Energy Storage Ring (HESR) within the international facility, Facility for Antiproton and Ion Research (FAIR) at Darmstadt. Beam Position Monitors (BPMs) are an essential instrument for any accelerator allowing operators to accurately monitor and control the accelerated beam. The demand for a BPM test bench will be showcased which will help to assess the design's ability to meet the system requirements. The weight is on the factors considered for the development of the initial test bench, its functional components, the metrology tests for ensuring positional measurement accuracy, and the design modifications from metrology investigations leading to the conceptual development of a new test bench.

  20. Recovery of pectoralis major and triceps brachii after bench press exercise.

    Science.gov (United States)

    Ferreira, Diogo V; Gentil, Paulo; Soares, Saulo Rodrigo Sampaio; Bottaro, Martim

    2017-11-01

    The present study evaluated and compared the recovery of pectoralis major (PM) and triceps brachii (TB) muscles of trained men after bench press exercise. Eighteen volunteers performed eight sets of bench press exercise to momentary muscle failure and were evaluated for TB and PM peak torque and total work on an isokinetic dynamometer. PM peak torque and total work remained lower than baseline for 72 and 96 h, respectively. TB peak torque was only different from baseline immediately post training, while total work was significantly lower than baseline immediately and 48 h after training. Normalized peak torque values were only different between TB and PM at 48 h after training. Considering the small and nonsignificant difference between the recovery of TB and PM muscles, the results suggest that bench press exercise may promote a similar stress on these muscles. Muscle Nerve 56: 963-967, 2017. © 2016 Wiley Periodicals, Inc.

  1. Acute chest pain after bench press exercise in a healthy young adult.

    Science.gov (United States)

    Smereck, Janet A; Papafilippaki, Argyro; Sudarshan, Sawali

    2016-01-01

    Bench press exercise, which involves repetitive lifting of weights to full arm extension while lying supine on a narrow bench, has been associated with complications ranging in acuity from simple pectoral muscle strain, to aortic and coronary artery dissection. A 39-year-old man, physically fit and previously asymptomatic, presented with acute chest pain following bench press exercise. Diagnostic evaluation led to the discovery of critical multivessel coronary occlusive disease, and subsequently, highly elevated levels of lipoprotein (a). Judicious use of ancillary testing may identify the presence of "high-risk" conditions in a seemingly "low-risk" patient. Emergency department evaluation of the young adult with acute chest pain must take into consideration an extended spectrum of potential etiologies, so as to best guide appropriate management.

  2. A bench-top K X-ray fluorescence system for quantitative measurement of gold nanoparticles for biological sample diagnostics

    Energy Technology Data Exchange (ETDEWEB)

    Ricketts, K., E-mail: k.ricketts@ucl.ac.uk [Division of Surgery and Interventional Sciences, University College London, Royal Free Campus, Rowland Hill Street, London NW3 2PF (United Kingdom); Guazzoni, C.; Castoldi, A. [Dipartimento di Elettronica, Informazione e Bioingegneria Politecnico di Milano and INFN, Sezione di Milano P.za Leonardo da Vinci, 32-20133 Milano (Italy); Royle, G. [Department of Medical Physics and Bioengineering, University College London, Malet Place Engineering Building, Gower Street, London WC1E 6BT (United Kingdom)

    2016-04-21

    Gold nanoparticles can be targeted to biomarkers to give functional information on a range of tumour characteristics. X-ray fluorescence (XRF) techniques offer potential quantitative measurement of the distribution of such heavy metal nanoparticles. Biologists are developing 3D tissue engineered cellular models on the centimetre scale to optimise targeting techniques of nanoparticles to a range of tumour characteristics. Here we present a high energy bench-top K-X-ray fluorescence system designed for sensitivity to bulk measurement of gold nanoparticle concentration for intended use in such thick biological samples. Previous work has demonstrated use of a L-XRF system in measuring gold concentrations but being a low energy technique it is restricted to thin samples or superficial tumours. The presented system comprised a high purity germanium detector and filtered tungsten X-ray source, capable of quantitative measurement of gold nanoparticle concentration of thicker samples. The developed system achieved a measured detection limit of between 0.2 and 0.6 mgAu/ml, meeting specifications of biologists and being approximately one order of magnitude better than the detection limit of alternative K-XRF nanoparticle detection techniques. The scatter-corrected K-XRF signal of gold was linear with GNP concentrations down to the detection limit, thus demonstrating potential in GNP concentration quantification. The K-XRF system demonstrated between 5 and 9 times less sensitivity than a previous L-XRF bench-top system, due to a fundamental limitation of lower photoelectric interaction probabilities at higher K-edge energies. Importantly, the K-XRF technique is however less affected by overlying thickness, and so offers future potential in interrogating thick biological samples.

  3. Neuromuscular activity during bench press exercise performed with and without the preexhaustion method.

    Science.gov (United States)

    Brennecke, Allan; Guimarães, Thiago M; Leone, Ricardo; Cadarci, Mauro; Mochizuki, Luiz; Simão, Roberto; Amadio, Alberto Carlos; Serrão, Júlio C

    2009-10-01

    The purpose of the present study was to investigate the effects of exercise order on the tonic and phasic characteristics of upper-body muscle activity during bench press exercise in trained subjects. The preexhaustion method involves working a muscle or a muscle group combining a single-joint exercise immediately followed by a multi-joint exercise (e.g., flying exercise followed by bench press exercise). Twelve subjects performed 1 set of bench press exercises with and without the preexhaustion method following 2 protocols (P1-flying before bench press; P2-bench press). Both exercises were performed at a load of 10 repetition maximum (10RM). Electromyography (EMG) sampled at 1 kHz was recorded from the pectoralis major (PM), anterior deltoid (DA), and triceps brachii (TB). Kinematic data (60 Hz) were synchronized to define upward and downward phases of exercise. No significant (p > 0.05) changes were seen in tonic control of PM and DA muscles between P1 and P2. However, TB tonic aspect of neurophysiologic behavior of motor units was significantly higher (p 0.05). The kinematic pattern of movement changed as a result of muscular weakness in P1. Angular velocity of the right shoulder performed during the upward phase of the bench press exercise was significantly slower (p < 0.05) during P1. Our results suggest that the strategies set by the central nervous system to provide the performance required by the exercise are held constant throughout the exercise, but the tonic aspects of the central drive are increased so as to adapt to the progressive occurrence of the neuromuscular fatigue. Changes in tonic control as a result of the muscular weakness and fatigue can cause changes in movement techniques. These changes may be related to limited ability to control mechanical loads and mechanical energy transmission to joints and passive structures.

  4. Effect of Barbell Weight on the Structure of the Flat Bench Press.

    Science.gov (United States)

    Król, Henryk; Gołaś, Artur

    2017-05-01

    Król, H and Gołaś, A. Effect of barbell weight on the structure of the flat bench press. J Strength Cond Res 31(5): 1321-1337, 2017-In this study, we have used the multimodular measuring system SMART. The system consisted of 6 infrared cameras and a wireless module to measure muscle bioelectric activity. In addition, the path of the barbell was measured with a special device called the pantograph. Our study concerns the change in the structure of the flat bench press when the weight of the barbell is increased. The research on the bench press technique included both the causes of the motion: the internal structure of the movement and the external kinematic structure showing the effects of the motion, i.e., all the characteristics of the movement. Twenty healthy, male recreational weight trainers with at least 1 year of lifting experience (the mean ± SD = 3.3 ± 1.6 years) were recruited for this study. The subjects had a mean body mass of 80.2 ± 8.6 kg, an average height of 1.77 ± 0.08 m, and their average age was 24.7 ± 0.9 years. In the measuring session, the participants performed consecutive sets of a single repetition of bench pressing with an increasing load (about 70, 80, 90, and 100% of their 1 repetition maximum [1RM]). The results showed a significant change in the phase structure of the bench press, as the barbell weight was increased. While doing the bench press at a 100% 1RM load, the pectoralis major changes from being the prime mover to being the supportive prime mover. At the same time, the role of the prime mover is taken on by the deltoideus anterior. The triceps brachii, in particular, clearly shows a greater involvement.

  5. Robust, small-scale cultivation platform for Streptomyces coelicolor

    DEFF Research Database (Denmark)

    Sohoni, Sujata Vijay; Bapat, Prashant Madhusudan; Lantz, Anna Eliasson

    2012-01-01

    rates of antibiotics. CONCLUSION: We observed good agreement of the physiological data obtained in the developed MTP platform with bench-scale. Hence, the described MTP-based screening platform has a high potential for investigation of secondary metabolite biosynthesis in Streptomycetes and other....... The MTP cultivations were found to behave similar to bench-scale in terms of growth rate, productivity and substrate uptake rate and so was the onset of antibiotic synthesis. Shake flask cultivations however, showed discrepancy with respect to morphology and had considerably reduced volumetric production...

  6. Neuromuscular Control During the Bench Press Movement in an Elite Disabled and Able-Bodied Athlete

    Directory of Open Access Journals (Sweden)

    Gołaś Artur

    2017-12-01

    Full Text Available The disabled population varies significantly in regard to physical fitness, what is conditioned by the damage to the locomotor system. Recently there has been an increased emphasis on the role of competitive sport in enhancing health and the quality of life of individuals with disability. One of the sport disciplines of Paralympics is the flat bench press. The bench press is one of the most popular resistance exercises used for the upper body in healthy individuals. It is used not only by powerlifters, but also by athletes in most strength-speed oriented sport disciplines. The objective of the study was to compare neuromuscular control for various external loads (from 60 to 100% 1RM during the flat bench press performed by an elite able-bodied athlete and an athlete with lower limb disability. The research project is a case study of two elite bench press athletes with similar sport results: an able-bodied athlete (M.W., age 34 years, body mass 103 kg, body height 1.72 m, 1RM in the flat bench press 200 kg and a disabled athlete (M.T., age 31 years, body mass 92 kg, body height 1.70 m, 1RM in the flat bench press 190 kg. The activity was recorded for four muscles: pectoralis major (PM, anterior deltoid (AD, as well as for the lateral and long heads of the triceps brachii (TBlat and TBlong. The T-test revealed statistically significant differences between peak activity of all the considered muscles (AD with p = 0.001; PM with p = 0.001; TBlat with p = 0.0021 and TBlong with p = 0.002 between the 2 athletes. The analysis of peak activity differences of M.W and M.T. in relation to the load revealed statistically significant differences for load changes between: 60 to 100% 1RM (p = 0.007, 70 to 100% 1RM (p = 0.016 and 80 to 100% 1RM (p = 0.032. The flat bench press performed without legs resting firmly on the ground leads to the increased engagement of upper body muscles and to their greater activation. Isolated initial positions can be used to

  7. Inter- and intrasubject similarity of muscle synergies during bench press with slow and fast velocity

    DEFF Research Database (Denmark)

    Samani, Afshin; Kristiansen, Mathias

    2018-01-01

    We investigated the effect of low and high bar velocity on inter- and intra-subject similarity of muscle synergies during bench press. Thirteen trained male subjects underwent two exercise conditions, i.e. a slow and a fast velocity bench press. Surface electromyography was recorded from thirteen...... to describe the dataset variability. For the second activation coefficient, the inter-subject similarity within the fast velocity condition was greater than the intra-subject similarity of the activation coefficient across the conditions. An opposite pattern was observed for the first muscle synergy vector...

  8. Importance of Upper-Limb Inertia in Calculating Concentric Bench Press Force

    OpenAIRE

    RAMBAUD, O; RAHMANI, A; MOYEN, B; BOURDIN, M

    2008-01-01

    The purpose of this study was to investigate the influence of upper-limb inertia on the force-velocity relationship and maximal power during concentric bench press exercise. Reference peak force values (Fpeakp) measured with a force plate positioned below the bench were compared to those measured simultaneously with a kinematic device fixed on the barbell by taking (Fpeakt) or not taking (Fpeakb) upper-limb inertia into account. Thirteen men (27.8 6 4.1 years, 184.6 6 5.5 cm, 99.5 6 18.6 kg) ...

  9. Neuromuscular Control During the Bench Press Movement in an Elite Disabled and Able-Bodied Athlete.

    Science.gov (United States)

    Gołaś, Artur; Zwierzchowska, Anna; Maszczyk, Adam; Wilk, Michał; Stastny, Petr; Zając, Adam

    2017-12-01

    The disabled population varies significantly in regard to physical fitness, what is conditioned by the damage to the locomotor system. Recently there has been an increased emphasis on the role of competitive sport in enhancing health and the quality of life of individuals with disability. One of the sport disciplines of Paralympics is the flat bench press. The bench press is one of the most popular resistance exercises used for the upper body in healthy individuals. It is used not only by powerlifters, but also by athletes in most strength-speed oriented sport disciplines. The objective of the study was to compare neuromuscular control for various external loads (from 60 to 100% 1RM) during the flat bench press performed by an elite able-bodied athlete and an athlete with lower limb disability. The research project is a case study of two elite bench press athletes with similar sport results: an able-bodied athlete (M.W., age 34 years, body mass 103 kg, body height 1.72 m, 1RM in the flat bench press 200 kg) and a disabled athlete (M.T., age 31 years, body mass 92 kg, body height 1.70 m, 1RM in the flat bench press 190 kg). The activity was recorded for four muscles: pectoralis major (PM), anterior deltoid (AD), as well as for the lateral and long heads of the triceps brachii (TBlat and TBlong). The T-test revealed statistically significant differences between peak activity of all the considered muscles (AD with p = 0.001; PM with p = 0.001; TBlat with p = 0.0021 and TBlong with p = 0.002) between the 2 athletes. The analysis of peak activity differences of M.W and M.T. in relation to the load revealed statistically significant differences for load changes between: 60 to 100% 1RM (p = 0.007), 70 to 100% 1RM (p = 0.016) and 80 to 100% 1RM (p = 0.032). The flat bench press performed without legs resting firmly on the ground leads to the increased engagement of upper body muscles and to their greater activation. Isolated initial positions can be used to generate

  10. The bench scientist’s perspective on the unique considerations in nanoparticle regulation

    International Nuclear Information System (INIS)

    Marquis, Bryce J.; Maurer-Jones, Melissa A.; Ersin, Özlem H.; Lin, Yu-shen; Haynes, Christy L.

    2011-01-01

    The emergence and use of nanotechnologies in commercially available products, including nanotherapeutics, have necessitated the response of regulatory agencies to ensure that these products are safely employed. While bench scientists are at the forefront of nanoparticle development and design, many are unaware of the regulatory requirements necessary to transform their laboratory discoveries into marketable products. As bench scientists, we performed a “thought experiment” using multifunctional mesoporous silica nanoparticles synthesized in our lab, which we considered as a combination product, to try to understand the steps necessary for pre-clinical approval from the Food and Drug Administration. This thought experiment illuminated challenges associated with nanoparticle risk assessment and regulation.

  11. Test bench HEATREC for heat loss measurement on solar receiver tubes

    Science.gov (United States)

    Márquez, José M.; López-Martín, Rafael; Valenzuela, Loreto; Zarza, Eduardo

    2016-05-01

    In Solar Thermal Electricity (STE) plants the thermal energy of solar radiation is absorbed by solar receiver tubes (HCEs) and it is transferred to a heat transfer fluid. Therefore, heat losses of receiver tubes have a direct influence on STE plants efficiency. A new test bench called HEATREC has been developed by Plataforma Solar de Almería (PSA) in order to determinate the heat losses of receiver tubes under laboratory conditions. The innovation of this test bench consists in the possibility to determine heat losses under controlled vacuum.

  12. PXIe-based LLRF architecture and versatile test bench for heavy ion linear acceleration

    OpenAIRE

    Jugo, I. Badillo J.; Portilla, J.; Feutchwanger, J.; Vicente, C. San; Etxebarria, V.

    2014-01-01

    This work describes the architecture of a digital LLRF system for heavy-ion acceleration developed under the specification of the projected future heavy-ion accelerator facility in Huelva, Spain. A prototype LLRF test bench operating at 80MHz in CW mode has been designed and built. The core LLRF control has been digitally implemented on a PXIe chassis, including an FPGA for digital signal processing and a real time controller. The test bench is completed with a good quality signal generator u...

  13. Scaling up for the industrial production of rifamycin B; optimization of the process conditions in bench-scale fermentor

    Directory of Open Access Journals (Sweden)

    Hewaida F. El-Sedawy

    2013-06-01

    Full Text Available Optimization of fermentation process conditions using a gene amplified variant of Amycolatopsis mediterranei (NCH was carried out. The use of aeration level 1.5 vvm increased the yield by 16.6% (from 13.81 to 16.1 g/l upon controlling the temperature at 28 °C. Adjustment of the aeration level at 1.5 vvm for 3 days then controlling the dissolved oxygen (DO at 30% saturation further increased the yield to 17.8 g/l. The optimum pH was 6.5 for 3 days then 7 thereafter when a production yield of 16.1 g/l was recorded using an aeration rate of 1.5 vvm. Controlling the pH at constant value (6.5 or 7 all through the fermentation process decreased the yield by 5–21%. Controlling the temperature at 30 °C for 3 days then 28 °C thereafter slightly increased the yield by 5% upon using an aeration rate of 1 vvm while it decreased upon using an aeration rate of 1.5 vvm. Integration of the most optimum conditions increased the production yield by 22% from 13.81 to 17.8 g/l.

  14. T and D-Bench--Innovative Combined Support for Education and Research in Computer Architecture and Embedded Systems

    Science.gov (United States)

    Soares, S. N.; Wagner, F. R.

    2011-01-01

    Teaching and Design Workbench (T&D-Bench) is a framework aimed at education and research in the areas of computer architecture and embedded systems. It includes a set of features not found in other educational environments. This set of features is the result of an original combination of design requirements for T&D-Bench: that the…

  15. Experimental and kinetics studies of aromatic hydrogenation in a two-stage hydrotreating process using NiMo/Al{sub 2}O{sub 3} and NiW/Al{sub 2}O{sub 3} catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Owusu-Boakye, A.; Dalai, A.K.; Ferdous, D. [Saskatchewan Univ., Saskatoon, SK (Canada). Dept. of Chemical Engineering, Catalysis and Chemical Reaction Engineering Laboratories; Adjaye, J. [Syncrude Canada Ltd., Edmonton, AB (Canada)

    2006-10-15

    The degree of hydrogenation of aromatics in light gas oil (LGO) feed from Athabasca bitumen was examined using a two-stage process. Experiments were conducted in a trickle-bed reactor using 2 catalysts, namely nickel molybdenum alumina (NiMo/Al{sub 2}O{sub 3}) in stage one and nickel tungsten alumina (NiW/Al{sub 2}O{sub 3}) in the second stage. NiMo/Al{sub 2}O{sub 3} was used in the first stage in order to remove nitrogen and sulphur containing heteroatoms. NiW/Al{sub 2}O{sub 3} was used in the second stage for saturation of the aromatic rings in the hydrocarbon species. The catalysts were used under a range of temperature and pressure condition. Temperature and liquid hourly space velocity ranged from 350 to 390 degrees C and 1.0 to 1.5 per hour, respectively. Pressure was kept constant at 11.0 MPa for all experiments. Reaction time results from the two-stage process were compared with those from a single-stage where hydrotreating was performed over NiMo/AL{sub 2}O{sub 3}. Product samples from different feedstocks were analyzed with respect to sulfur, nitrogen and aromatic content. Gasoline selectivity and kinetic parameters for hydrodesulphurization (HDS) or hydrodenitrogenation (HDN) reactions for the feed materials were also compared. The effect of hydrogen sulphide (H{sub 2}S) inhibition on aromatics hydrogenation (HDA) was also kinetically modelled using the Langmuir-Hinshelwood approach. Kinetic analysis of the single-stage hydrotreating process showed that HDA and HDS activities were slowed by the presence of hydrogen sulphide that is produced as a by-product of the HDS process. However, with inter-stage removal of hydrogen sulphide in the two-stage process, significant improvement of the HDA and HDS activities were noted. It was concluded that the experimental data was successfully predicted by the Langmuir-Hinshelwood kinetic models. 27 refs., 4 tabs., 8 figs.

  16. Alternatives for recovering metals from spent catalysts for hydrotreating of heavy hydrocarbons: a case study; Alternativas para la recuperacion de metales a partir de catalizadores gastados del hidrotratamiento de hidrocarburos pesados: un caso de estudio

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Fernando; Ramirez, Sergio; Ancheyta, Jorge; Mavil, Martha [Instituto Mexicano del Petroleo, Mexico, D.F. (Mexico)]. E-mail: jancheyt@imp.mx

    2008-05-15

    The increasing production of spent hydrotreating catalysts used for processing heavy hydrocarbons and the problems related to their disposal are described in this work. These catalysts contain important amounts of heavy metals such as molybdenum (Mo), nickel (Ni), cobalt (Co) and vanadium (V), which can be recovered and hence an economical benefit may be obtained. The results of experimental tests for alkaline leaching (NaOH) to recover V and Mo, and the effect of operating conditions on metal recovery are also presented. The results show that, in general, the highest recovery of Mo is obtained at pH 8.5 and leaching time of 12 hours, while in the case of V, the highest recovery is observed at pH 9.0 and 8 hours. In both cases, the leaching solution contained 10 wt % alkaline. Based on the experimental information and data from a commercial plant, a preliminary economy study was developed, in which the expected economical benefits of metals recovery from spent catalysts used for hydrotreating heavy hydrocarbon are estimated. [Spanish] En el presente trabajo se describe la problematica de la creciente produccion de catalizadores gastados de los procesos de hidrotratamiento de hidrocarburos pesados. Estos catalizadores contienen cantidades importantes de metales pesados como molibdeno (Mo), niquel (Ni), cobalto (Co) y vanadio (V), que son susceptibles de recuperarse y obtener con ello un beneficio economico. Tambien se presentan resultados de pruebas experimentales de lixiviacion alcalina (NaOH) para la recuperacion de V y Mo, y el efecto de las variables de operacion sobre la recuperacion de metales. En general, se encontro que las mejores recuperaciones de Mo fueron a pH de 8.5 y 12 h, mientras que para el V fueron a pH de 9.0 y 8 h, ambos a una concentracion del agente lixiviante de 10% en peso. Con base en la informacion experimental obtenida y datos de una planta industrial se presenta un estudio economico preliminar, en el que se estiman los beneficios

  17. High league bench players and starters: differences in group interactions, group cohesion, role acceptance and self-confidence in football teams

    OpenAIRE

    Simonenkova Irina Petrovna

    2015-01-01

    Main staff players differ from bench players in their perceptions and demonstrate different responses. This research compares the situation of bench players with the situation of starters in high league Latvian football teams.

  18. Effect of bench time polymerization on depth of cure of dental composite resin

    Science.gov (United States)

    Harahap, K.; Yudhit, A.; Sari, F.

    2017-07-01

    The aim of this research was to investigate the effect of bench time before light cured polymerization on the depth of cure of dental composite resin. Nanofiller composite resin (Filtek Z350 XT,3M, ESPE,China) was used in this study. Sixty samples of nanofiller composite resin were made and divided into control and test groups with bench time for 0, 15, 30, 45, and 60 min. For the test group, composite resins were stored in refrigerator with 4°C temperatures. Meanwhile, for the control groups, the composite resin was stored at room temperature. The samples were prepared using metal mould with size diameter of 6 mm and 4 mm in thickness. Samples were cured for 20 s by using visible blue light curing unit. Part of samples that unpolymerized were removed by using a plastic spatula. The remaining parts of samples were measured by digital caliper and noted as depth of cure (mm). Data were analyzed to one-way ANOVA and LSD tests (p≤0.05). Results showed there was no significance differences between test groups (p=0.5). A 60 minutes bench time group showed the highest depth of cure value among test group, and it was almost similar with control group value. It can be concluded that longer bench time can increase the depth of cure of composite resin.

  19. Development of remote data acquisition system based on OPC for brake test bench

    Science.gov (United States)

    Wang, Yiwei; Wu, Mengling; Tian, Chun; Ma, Tianhe

    2017-08-01

    The 1:1 train brake system test bench can be used to carry out brake-related adhesion-slid control, stability test, noise test and dynamic test. To collect data of the test bench, a data acquisition method is needed. In this paper, the remote data acquisition system of test bench is built by LabVIEW based on OPC technology. Unlike the traditional hardwire way connecting PLC acquisition module with sensors, the novel method is used to collect data and share them through the internal LAN built by Ethernet switches, which avoids the complex wiring interference in an easy, efficient and flexible way. The system has been successfully applied to the data acquisition activities of the comprehensive brake system test bench of CRRC Nanjing Puzhen Haitai Brake Equipment Co., Ltd., and the relationship test between the adhesion coefficient and the slip-ratio is realized. The speed signal, torque signal and brake disc temperature can be collected and displayed. The results show that the system is reliable, convenient, and efficient, and can meet the requirements of data acquisition.

  20. Bench top and portable mineral analysers, borehole core analysers and in situ borehole logging

    International Nuclear Information System (INIS)

    Howarth, W.J.; Watt, J.S.

    1982-01-01

    Bench top and portable mineral analysers are usually based on balanced filter techniques using scintillation detectors or on low resolution proportional detectors. The application of radioisotope x-ray techniques to in situ borehole logging is increasing, and is particularly suited for logging for tin and higher atomic number elements

  1. Usage of DNA Fingerprinting Technology for Quality Control in Molecular Lab Bench Work.

    Science.gov (United States)

    McIntosh, Linda Y; Lal, Janella E; Qin, Dahui

    2018-01-01

    One of the major quality assurance (QA) goals in many molecular laboratories is to avoid sample pipetting errors on the lab bench; especially when pipetting into multiwell plates. A pipetting error can cause a switch in patient samples, which can lead to recording the wrong results for the patient samples involved. Such pipetting errors are difficult to identify when it happens in lab bench work. DNA fingerprinting is a powerful tool in determining sample identities. Our laboratory has explored the usage of this technology in our QA process and successfully established that DNA fingerprinting can be used to monitor possible sample switch in gene rearrangement lab bench work. We use florescent light to quench the florescence in the gene rearrangement polymerase chain reaction products. After that, DNA fingerprinting technology is used to identify the sample DNA in the gene rearrangement polymerase chain reaction plate. The result is compared with the corresponding patient's blood sample DNA to determine whether there is a sample switch during the lab bench work.

  2. ReaderBench goes Online: A Comprehension-Centered Framework for Educational Purposes

    NARCIS (Netherlands)

    Gutu, Gabriel; Dascalu, Mihai; Trausan-Matu, Stefan; Dessus, Philippe

    2016-01-01

    In this paper we introduce the online version of our ReaderBench framework, which includes multi-lingual comprehension-centered web services designed to address a wide range of individual and collaborative learning scenarios, as follows. First, students can be engaged in reading a course

  3. Submicronic Particle Measurement Instrumentation Test Bench Data Acquisition and Control System

    International Nuclear Information System (INIS)

    Alberdi, J.; Barcala, J. M.; Sanz, D.; Gomez, F. J.; Molinero, A.; Navarrete, J. J.

    1999-01-01

    This document describes the SAD-100 system characteristics. The unit makes the instrumentation test bench data acquisition and control, SAD-100 was designed and developed by Electronic and Automation Area (CIEMAT) and Aerosol Technology in Energy Generation Project (CIEMAT). (Author) 2 refs

  4. 41 CFR 109-27.5005 - Shop, bench, cupboard or site stock.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Shop, bench, cupboard or site stock. 109-27.5005 Section 109-27.5005 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS SUPPLY AND...

  5. A comparison of successful and unsuccessful attempts in maximal bench pressing.

    Science.gov (United States)

    van den Tillaar, Roland; Ettema, Gertjan

    2009-11-01

    This study was designed to compare the differences in EMG and kinematics between successful and unsuccessful attempts in bench pressing at one repetition maximum (1RM) in recreational weight-trained subjects. We hypothesized that failure occurs during the sticking period (the period during which there is a temporary reduction in movement velocity). Eleven male subjects (age = 21.9 +/- 1.8 yr, mass = 80.0 +/- 11.2 kg, height = 1.79 +/- 0.08 m) with at least 1 yr of bench press training experience participated in this study. They performed attempts at 1RM and 1RM + 2.5 kg in bench press during which kinematics and muscle activity were recorded. One successful attempt and one unsuccessful attempt were used for further analysis. Both attempts showed the same sticking period, but only half of the failures occurred during that period. The main differences in the kinematics occurred during the sticking period. Muscle activity, in contrast, showed the same pattern in both attempts and only differed during the downward and the start of the upward movement of the lift. The sticking period occurs in both successful and unsuccessful attempts in maximal bench press. However, failure does not always occur during the sticking period.

  6. Anthropometry as a predictor of bench press performance done at different loads.

    Science.gov (United States)

    Caruso, John F; Taylor, Skyler T; Lutz, Brant M; Olson, Nathan M; Mason, Melissa L; Borgsmiller, Jake A; Riner, Rebekah D

    2012-09-01

    The purpose of our study was to examine the ability of anthropometric variables (body mass, total arm length, biacromial width) to predict bench press performance at both maximal and submaximal loads. Our methods required 36 men to visit our laboratory and submit to anthropometric measurements, followed by lifting as much weight as possible in good form one time (1 repetition maximum, 1RM) in the exercise. They made 3 more visits in which they performed 4 sets of bench presses to volitional failure at 1 of 3 (40, 55, or 75% 1RM) submaximal loads. An accelerometer (Myotest Inc., Royal Oak MI) measured peak force, velocity, and power after each submaximal load set. With stepwise multivariate regression, our 3 anthropometric variables attempted to explain significant amounts of variance for 13 bench press performance indices. For criterion measures that reached significance, separate Pearson product moment correlation coefficients further assessed if the strength of association each anthropometric variable had with the criterion was also significant. Our analyses showed that anthropometry explained significant amounts (p bench press prowess in athletes.

  7. How Adequate is your CV? Analyzing French CVs with ReaderBench

    NARCIS (Netherlands)

    Gutu, Gabriel; Dascalu, Mihai; Trausan-Matu, Stefan; Lepoivre, Olivier

    2017-01-01

    This study is aimed at presenting a new ReaderBench-based tool built to support candidates in increasing the quality of their CV for a job opening. Both the visual quality and the textual content are considered while also providing an overview and corresponding feedback for the entire CV.

  8. The effect of active recovery on power performance during the bench press exercise.

    Science.gov (United States)

    Lopes, Felipe A S; Panissa, Valéria L G; Julio, Ursula F; Menegon, Elton M; Franchini, Emerson

    2014-03-27

    The objective of this study was to verify the effect of active and passive recovery on blood lactate concentration and power performance. Twelve male subjects were submitted to a maximal strength test in the the bench press, a maximal aerobic test in the bench step, and to four sets of bench press exercise performed as fast and as long as possible, using 80% of maximal strength when active or passive recovery was performed. The maximum number of repetitions, mean and peak power in eccentric and concentric phases were computed and blood lactate concentration was measured. Comparisons for the variables were made using a two-way variance analysis (recovery type and set numer) with repeated measures in the second factor. When significant differences were detected (p 2, 3, and 4; 2 > 3 and 4; 3 > 4). Mean and peak power in both eccentric and concentric phases also differed across sets (1 > 2, 3, and 4; 2 > 4). There was also a main effect for the recovery type, with lower values (p bench press exercise.

  9. Postactivation potentiation: effect of various recovery intervals on bench press power performance.

    Science.gov (United States)

    Ferreira, Sandra Lívia de Assis; Panissa, Valéria Leme Gonçalves; Miarka, Bianca; Franchini, Emerson

    2012-03-01

    Postactivation potentiation (PAP) is a strategy used to improve performance in power activities. The aim of this study was to determine if power during bench press exercise was increased when preceded by 1 repetition maximum (1RM) in the same exercise and to determine which time interval could optimize PAP response. For this, 11 healthy male subjects (age, 25 ± 4 years; height, 178 ± 6 cm; body mass, 74 ± 8 kg; bench press 1RM, 76 ± 19 kg) underwent 6 sessions. Two control sessions were conducted to determine both bench press 1RM and power (6 repetitions at 50% 1RM). The 4 experimental sessions were composed of a 1RM exercise followed by power sets with different recovery intervals (1, 3, 5, and 7 minutes), performed on different days, and determined randomly. Power values were measured via Peak Power equipment (Cefise, Nova Odessa, São Paulo, Brazil). The conditions were compared using an analysis of variance with repeated measures, followed by a Tukey test. The significance level was set at p bench press and that such a strategy could be applied as an interesting alternative to enhance the performance in tasks aimed at increasing upper-body power performance.

  10. Activation of selected shoulder muscles during unilateral wall and bench press tasks under submaximal isometric effort.

    Science.gov (United States)

    Tucci, Helga T; Ciol, Marcia A; de Araújo, Rodrigo C; de Andrade, Rodrigo; Martins, Jaqueline; McQuade, Kevin J; Oliveira, Anamaria S

    2011-07-01

    Controlled laboratory study. To assess the activation of 7 shoulder muscles under 2 closed kinetic chain (CKC) tasks for the upper extremity using submaximal isometric effort, thus providing relative quantification of muscular isometric effort for these muscles across the CKC exercises, which may be applied to rehabilitation protocols for individuals with shoulder weakness. CKC exercises favor joint congruence, reduce shear load, and promote joint dynamic stability. Additionally, knowledge about glenohumeral and periscapular muscle activity elicited during CKC exercises may help clinicians to design protocols for shoulder rehabilitation. Using surface electromyography, activation level was measured across 7 shoulder muscles in 20 healthy males, during the performance of a submaximal isometric wall press and bench press. Signals were normalized to the maximal voluntary isometric contraction, and, using paired t tests, data were analyzed between the exercises for each muscle. Compared to the wall press, the bench press elicited higher activity for most muscles, except for the upper trapezius. Levels of activity were usually low but were above 20% maximal voluntary isometric contraction for the serratus anterior on both tasks, and for the long head triceps brachii on the bench press. Both the bench press and wall press, as performed in this study, led to relatively low EMG activation levels for the muscles measured and may be considered for use in the early phases of rehabilitation.

  11. Bench Press Upper-Body Muscle Activation Between Stable and Unstable Loads.

    Science.gov (United States)

    Dunnick, Dustin D; Brown, Lee E; Coburn, Jared W; Lynn, Scott K; Barillas, Saldiam R

    2015-12-01

    The bench press is one of the most commonly used upper-body exercises in training and is performed with many different variations, including unstable loads (ULs). Although there is much research on use of an unstable surface, there is little to none on the use of an UL. The purpose of this study was to investigate muscle activation during the bench press while using a stable load (SL) vs. UL. Twenty resistance-trained men (age = 24.1 ± 2 years; ht = 177.5 ± 5.8 cm; mass = 88.7 ± 13.7 kg) completed 2 experimental conditions (SL and UL) at 2 different intensities (60 and 80% one repetition maximum). Unstable load was achieved by hanging 16 kg kettlebells by elastic bands from the end of the bar. All trial lifts were set to a 2-second cadence with a slight pause at the bottom. Subjects had electrodes attached to 5 muscles (pectoralis major, anterior deltoid, medial deltoid, triceps brachii, and latissimus dorsi) and performed 3 isometric bench press trials to normalize electromyographic data. All 5 muscles demonstrated significantly greater activation at 80% compared with 60% load and during concentric compared with eccentric actions. These results suggest that upper body muscle activation is not different in the bench press between UL and SL. Therefore, coaches should use their preference when designing training programs.

  12. An Electromyograph Comparison of an Isokenetic Bench Press at Three Speeds.

    Science.gov (United States)

    Ridgeway, M.; And Others

    The muscle action potentials (MAP) of the anterior deltoid, pectoralis major, biceps brachii, and the triceps muscle were studied by quantitative electromyography (emg) during a bench press exercise at three controlled speeds. Bipolar surface electrodes with standard placement were employed throughout the study. Eleven volunteer college women…

  13. Optimization of an Optical Test Bench for Tire Properties Measurement and Tread Defects Characterization

    Directory of Open Access Journals (Sweden)

    Juan Jesús Castillo Aguilar

    2017-03-01

    Full Text Available Tire characteristics and behavior are of great importance in vehicle dynamics since the forces transmitted in the tire-road contact are the main contributors to global vehicle performance. Several research groups have focused on the study and modeling of tires. Some of the most important factors that need to be known are tread characteristics and pressure distribution in the tire-ground contact patch. In this work, a test bench has been used to adequately determine the aforementioned factors. The measurement principle of the test bench is the frustration of total internal reflection (FTIR of light. It makes use of a laterally illuminated glass on which the tire leans. An interposed plastic interface between them causes the reflection of light. Finally, a video camera captures the bright image formed through the glass. The brightness level in each pixel of the image is related to existing normal pressure. A study of the parameters that affect the test bench calibration such as type of interface material used, diffuse light, hysteresis, creep and transverse light absorption is performed. Experimental tests are conducted to relate tire inflation pressure and camber angle to the pressure distribution. Furthermore, the test bench is used to detect and evaluate the influence of defects in the tire on the contact pressures.

  14. A Bench Measurement of the Energy Loss of a Stored Beam to a Cavity

    Energy Technology Data Exchange (ETDEWEB)

    Sands, M; Rees, J.; /SLAC

    2016-12-19

    A rather simple electronic bench experiment is proposed for obtaining a measure of the impulse energy loss of a stored particle bunch to an rf cavity or other vacuum-chamber structure--the so-called "cavity radiation". The proposed method is analyzed in some detail.

  15. Importance of upper-limb inertia in calculating concentric bench press force.

    Science.gov (United States)

    Rambaud, Olivier; Rahmani, Abderrahmane; Moyen, Bernard; Bourdin, Muriel

    2008-03-01

    The purpose of this study was to investigate the influence of upper-limb inertia on the force-velocity relationship and maximal power during concentric bench press exercise. Reference peak force values (Fpeakp) measured with a force plate positioned below the bench were compared to those measured simultaneously with a kinematic device fixed on the barbell by taking (Fpeakt) or not taking (Fpeakb) upper-limb inertia into account. Thirteen men (27.8 +/- 4.1 years, 184.6 +/- 5.5 cm, 99.5 +/- 18.6 kg) performed all-out concentric bench press exercise against 8 loads ranging between 7 and 74 kg. The results showed that for each load, Fpeakb was significantly less than Fpeakp (P force (F0), maximal velocity (V0), optimal velocity (Vopt), and maximal power (Pmax), extrapolated from the force- and power-velocity relationships determined with the kinematic device, were significantly underestimated when upper-limb inertia was ignored. The results underline the importance of taking account of the total inertia of the moving system to ensure precise evaluation of upper-limb muscular characteristics in all-out concentric bench press exercise with a kinematic device. A major application of this study would be to develop precise upper-limb muscular characteristic evaluation in laboratory and field conditions by using a simple and cheap kinematic device.

  16. Dynamics of water and nutrients for potted plants induced by flooded bench fertigation : experiments and simulation

    NARCIS (Netherlands)

    Otten, W.

    1994-01-01

    Dynamics of water and nutrients as affected by physical and chemical characteristics of a substrate, fertigation method and schedule, and plant uptake were studied for a flooded bench fertigation system for potted plants, through a detailed experimental study of the root environment and a

  17. Characterization benches for neutrino telescope Optical Modules at the APC laboratory

    Science.gov (United States)

    Avgitas, Theodore; Creusot, Alexandre; Kouchner, Antoine

    2016-04-01

    As has been demonstrated by the first generation of neutrino telescopes Antares and IceCube, precise knowledge of the photon detection efficiency of optical modules is of fundamental importance for the understanding of the instrument and accurate event reconstruction. Dedicated test benches have been developed to measure all related quantities for the Digital Optical Modules of the KM3NeT neutrino telescope being currently deployed in the Mediterranean sea. The first bench is a black box with robotic arms equipped with a calibrated single photon source or laser which enable a precise mapping of the detection efficiency at arbitrary incident angles as well as precise measurements of the time delays induced by the photodetection chain. These measurement can be incorporated and compared to full GEANT MonteCarlo simulations of the optical modules. The second bench is a 2 m×2 m ×2 m water tank equipped with muon hodoscopes on top and bottom. It enables to study and measure the angular dependence of the DOM's detection efficiency of the Cherenkov light produced in water by relativistic muons, thus reproducing in situ detection conditions. We describe these two benches and present their first results and status.

  18. Portable test bench for the studies concerning ion sources and ion beam extraction and focusing systems

    International Nuclear Information System (INIS)

    Cordero Lopez, F.

    1961-01-01

    A portable test bench is described, which was designed to check ion sources, ion beam extraction and focusing systems before its use in a 600 KeV Cockcroft-Walton accelerator. The vacuum possibilities of the system are specially analyzed in connection with its particular use. The whole can be considered as a portable accelerator of low energy (50 keV). (Author)

  19. RPE and Velocity Relationships for the Back Squat, Bench Press, and Deadlift in Powerlifters.

    Science.gov (United States)

    Helms, Eric R; Storey, Adam; Cross, Matt R; Brown, Scott R; Lenetsky, Seth; Ramsay, Hamish; Dillen, Carolina; Zourdos, Michael C

    2017-02-01

    Helms, ER, Storey, A, Cross, MR, Browm, SR, Lenetsky, S, Ramsay, H, Dillen, C, and Zourdos, MC. RPE and velocity relationships for the back squat, bench press, and deadlift in powerlifters. J Strength Cond Res 31(2): 292-297, 2017-The purpose of this study was to compare average concentric velocity (ACV) and rating of perceived exertion (RPE) based on repetitions in reserve on the squat, bench press, and deadlift. Fifteen powerlifters (3 women and 12 men, mean age 28.4 ± 8.5 years) worked up to a one repetition maximum (1RM) on each lift. Rating of perceived exertion was recorded on all sets, and the ACV was recorded for all sets performed at 80% of estimated 1RM and higher, up to 1RM. Rating of perceived exertion at 1RM on squat, bench press, and deadlift was 9.6 ± 0.5, 9.7 ± 0.4, and 9.6 ± 0.5, respectively and was not significantly different (p > 0.05). The ACV at 1RM on squat, bench press and deadlift was 0.23 ± 0.05, 0.10 ± 0.04, and 0.14 ± 0.05 m·second, respectively. Squat was faster than both bench press and deadlift (p > 0.001), and deadlift was faster than bench press (p = 0.05). Very strong relationships (r = 0.88-0.91) between percentage 1RM and RPE were observed on each lift. The ACV showed strong (r = -0.79 to -0.87) and very strong (r = -0.90 to 92) inverse relationships with RPE and percentage 1RM on each lift, respectively. We conclude that RPE may be a useful tool for prescribing intensity for squat, bench press, and deadlift in powerlifters, in addition to traditional methods such as percentage of 1RM. Despite high correlations between percentage 1RM and ACV, a "velocity load profile" should be developed to prescribe intensity on an individual basis with appropriate accuracy.

  20. Electromyographic activity and 6RM strength in bench press on stable and unstable surfaces.

    Science.gov (United States)

    Saeterbakken, Atle H; Fimland, Marius S

    2013-04-01

    The purpose of the study was to compare 6-repetition maximum (6RM) loads and muscle activity in bench press on 3 surfaces, namely, stable bench, balance cushion, and Swiss ball. Sixteen healthy, resistance-trained men (age 22.5 ± 2.0 years, stature 1.82 ± 6.6 m, and body mass 82.0 ± 7.8 kg) volunteered for 3 habituation/strength testing sessions and 1 experimental session. In randomized order on the 3 surfaces, 6RM strength and electromyographic activity of pectoralis major, deltoid anterior, biceps brachii, triceps brachii, rectus abdominis, oblique external and erector spinae were assessed. Relative to stable bench, the 6RM strength was approximately 93% for balance cushion (p ≤ 0.001) and approximately 92% for Swiss ball (p = 0.008); the pectoralis major electromyographic (EMG) activity was approximately 90% using the balance cushion (p = 0.080) and approximately 81% using Swiss ball (p = 0.006); the triceps EMG was approximately 79% using the balance cushion (p = 0.028) and approximately 69% using the Swiss ball (p = 0.002). Relative to balance cushion, the EMG activity in pectoralis, triceps, and erector spinae using Swiss ball was approximately 89% (p = 0.016), approximately 88% (p = 0.014) and approximately 80% (p = 0.020), respectively. In rectus abdominis, the EMG activity relative to Swiss ball was approximately 69% using stable bench (p = 0.042) and approximately 65% using the balance cushion (p = 0.046). Similar EMG activities between stable and unstable surfaces were observed for deltoid anterior, biceps brachii, and oblique external. In conclusion, stable bench press had greater 6RM strength and triceps and pectoralis EMG activity compared with the unstable surfaces. These findings have implications for athletic training and rehabilitation, because they demonstrate an inferior effect of unstable surfaces on muscle activation of prime movers and strength in bench press. If an unstable surface in bench press is desirable, a balance cushion should

  1. Fatigue effects upon sticking region and electromyography in a six-repetition maximum bench press.

    Science.gov (United States)

    van den Tillaar, Roland; Saeterbakken, Atle Hole

    2013-01-01

    The aim of the study was to examine the sticking region and concomitant neuromuscular activation of the prime movers during six-repetition maximum (RM) bench pressing. We hypothesised that both peak velocities would decrease and that the electromyography (EMG) of the prime movers (deltoid, major pectoralis and triceps) would increase during the pre-sticking and sticking region during the six repetitions due to fatigue. Thirteen resistance-trained males (age 22.8 ± 2.2 years, stature 1.82 ± 0.06 m, body mass 83.4 ± 7.6 kg) performed 6-RM bench presses. Barbell kinematics and EMG activity of pectoralis major, deltoid anterior, and triceps brachii during the pre-, sticking and post-sticking region of each repetition in a 6-RM bench press were analysed. For both the sticking as the post-sticking region, the time increased significantly from the first to the sixth repetition. Vertical barbell height at the start of sticking region was lower, while the height at the end of the sticking region and post-sticking region did not change during the six repetitions. It was concluded that in 6-RM bench pressing performance, the sticking region is a poor mechanical force region due to the unchanged barbell height at the end of the sticking region. Furthermore, when fatigue occurs, the pectoralis and the deltoid muscles are responsible for surpassing the sticking region as indicated by their increased activity during the pre- and sticking region during the six-repetitions bench press.

  2. Effect of an Unstable Load on Primary and Stabilizing Muscles During the Bench Press.

    Science.gov (United States)

    Ostrowski, Stephanie J; Carlson, Lara A; Lawrence, Michael A

    2017-02-01

    Ostrowski, SJ, Carlson, LA, and Lawrence, MA. Effect of an unstable load on primary and stabilizing muscles during the bench press. J Strength Cond Res 31(2): 430-434, 2017-Unstable resistance exercises are performed to increase activity of stabilizing muscles. The premise is that this increase in activity will yield greater strength gains than traditional resistance exercises. The purpose of this study was to determine if an unstable load increases muscle activity of stabilizing muscles during a bench press as compared with a standard bench press with a typical load. Fifteen resistance-trained males (age 24.2 ± 2.7 years, mass 84.8 ± 12.0 kg, height 1.77 ± 0.05 m, weight lifting experience 9.9 ± 3.4 years, and bench press 1 repetition maximum [1RM] 107.5 ± 25.9 kg) volunteered for this study. Subjects pressed 2 sets of 5 repetitions in both stable (75% 1RM) and unstable (60% 1RM) conditions using a standard barbell and a flexible Earthquake bar, respectively. Surface electromyography was used to detect muscle activity of primary movers (pectoralis major, anterior deltoid, and triceps) and stabilizing musculature (latissimus dorsi, middle and posterior deltoid, biceps brachii, and upper trapezius). Muscle activity was compared using a multivariate analysis of variance to determine significant (p ≤ 0.05) phase and condition differences. The right and left biceps and the left middle deltoid were significantly more active in the unstable condition. Some of the stabilizing muscles were found to be significantly more active in the unstable condition with 15% less weight. Therefore, bench pressing with an unstable load appears promising in activating stabilizing musculature compared with pressing a typical barbell.

  3. The development of a repetition-load scheme for the eccentric-only bench press exercise.

    Science.gov (United States)

    Moir, Gavin L; Erny, Kyle F; Davis, Shala E; Guers, John J; Witmer, Chad A

    2013-01-01

    The purpose of the present study was to develop a repetition-load scheme for the eccentric-only bench press exercise. Nine resistance trained men (age: 21.6 ± 1.0 years; 1-repetition maximum [RM] bench press: 137.7 ± 30.4 kg) attended four testing sessions during a four week period. During the first session each subject's 1-RM bench press load utilizing the stretch-shortening cycle was determined. During the remaining sessions they performed eccentric-only repetitions to failure using supra-maximal loads equivalent to 110%, 120% and 130% of their 1-RM value with a constant cadence (30 reps·min(-1)). Force plates and a three dimensional motion analysis system were used during these final three sessions in order to evaluate kinematic and kinetic variables. More repetitions were completed during the 110% 1-RM condition compared to the 130% 1-RM condition (p=0.01). Mean total work (p=0.046) as well as vertical force (p=0.049), vertical work (p=0.017), and vertical power output (p=0.05) were significantly greater during the 130% 1-RM condition compared to the 110% 1-RM condition. A linear function was fitted to the number of repetitions completed under each load condition that allowed the determination of the maximum number of repetitions that could be completed under other supra-maximal loads. This linear function predicted an eccentric-only 1-RM in the bench press with a load equivalent to 164.8% 1-RM, producing a load of 227.0 ± 50.0 kg. The repetition-load scheme presented here should provide a starting point for researchers to investigate the kinematic, kinetic and metabolic responses to eccentric-only bench press workouts.

  4. Comparison of the goals and MISTELS scores for the evaluation of surgeons on training benches.

    Science.gov (United States)

    Wolf, Rémi; Medici, Maud; Fiard, Gaëlle; Long, Jean-Alexandre; Moreau-Gaudry, Alexandre; Cinquin, Philippe; Voros, Sandrine

    2018-01-01

    Evaluation of surgical technical abilities is a major issue in minimally invasive surgery. Devices such as training benches offer specific scores to evaluate surgeons but cannot transfer in the operating room (OR). A contrario, several scores measure performance in the OR, but have not been evaluated on training benches. Our aim was to demonstrate that the GOALS score, which can effectively grade in the OR the abilities involved in laparoscopy, can be used for evaluation on a laparoscopic testbench (MISTELS). This could lead to training systems that can identify more precisely the skills that have been acquired or must still be worked on. 32 volunteers (surgeons, residents and medical students) performed the 5 tasks of the MISTELS training bench and were simultaneously video-recorded. Their performance was evaluated with the MISTELS score and with the GOALS score based on the review of the recording by two experienced, blinded laparoscopic surgeons. The concurrent validity of the GOALS score was assessed using Pearson and Spearman correlation coefficients with the MISTELS score. The construct validity of the GOALS score was assessed with k-means clustering and accuracy rates. Lastly, abilities explored by each MISTELS task were identified with multiple linear regression. GOALS and MISTELS scores are strongly correlated (Pearson correlation coefficient = 0.85 and Spearman correlation coefficient = 0.82 for the overall score). The GOALS score proves to be valid for construction for the tasks of the training bench, with a better accuracy rate between groups of level after k-means clustering, when compared to the original MISTELS score (accuracy rates, respectively, 0.75 and 0.56). GOALS score is well suited for the evaluation of the performance of surgeons of different levels during the completion of the tasks of the MISTELS training bench.

  5. Hydrotreating of heavy gas oil derived from Athabasca bitumen using NiMo/Al2O3 catalyst containing boron and phosphorus : effects of process conditions on the product selectivity

    Energy Technology Data Exchange (ETDEWEB)

    Ferdous, D.; Dalai, A.K. [Saskatchewan Univ., Saskatoon, SK (Canada). Dept. of Chemistry and Chemical Engineering; Adjaye, J. [Syncrude Canada Ltd., Edmonton, AB (Canada). Edmonton Research Centre

    2004-07-01

    In response to concerns regarding the depletion of conventional oil reserves, there has been much interest in modifying the hydrotreating process for upgrading tar sands and shale oils for producing transportation fuels. Oil sand bitumens and their derived products have a high level of nitrogen which deactivates the catalysts used in fluid catalytic cracking and hydrocracking. A better catalyst is needed to efficiently remove nitrogen from oil sand-derived gas oils. In this study, a trickle-bed reactor containing NiMo/Al{sub 2}O{sub 3} catalysts with boron and phosphorous was used to remove the sulfur and nitrogen from heavy gas oils derived from Athabasca bitumen. The operating conditions of the reactor in terms of temperature and pressure were described. Sulfur and nitrogen conversion was found to increase substantially with the boron catalysts. Gasoline selectivity also increased with an increase in temperature. However, a change in operating conditions did not significantly affect the net content of the gas oil fraction. This study also compared the results of using either the boron or phosphorous catalyst.

  6. Studies on the hydroprocessing of deashed oil. 10. ; Comparison of the reaction performance between pilot plant and BSU. Deashed oil no suisoka bunkai hanno ni kansuru kenkyu. 10. ; Pilot to bench hanno sochi no hanno tokusei no hikaku

    Energy Technology Data Exchange (ETDEWEB)

    Hijiriyama, M.; Kaneko, T. (Mitsubishi Kasei Co., Tokyo (Japan)); Kageyama, Y. (Nippon Brown Coal Liquefaction Co. Ltd., Tokyo (Japan))

    1990-11-29

    The secondary hydroprocessing process in the two-stage hydrogenating liquefaction equipment under development at Nippon Brown Coal Liquefaction Company uses a fixed bed system. This paper describes operation of a bench reaction equipment using catalyst used in the pilot plant to compare it with fresh catalyst, and compare characteristics of the bench scale equipment with those of the pilot reactor. The catalyst is Ca-Ni-No/Al2O. The reaction was carried out in a gas-liquid downward parallel-flow fixed-bed reactor using deashed oil (DAO) with the same material as that used in the pilot plant and the same equilibrium solvent. The experiment result indicates that the used catalyst had its activity fallen below the fresh catalyst, but its temperature dependence was identical, and the selectivity on products of both catalysts was also identical. The result of reactions in the bench scale equipment clarified that the relationship between the DAO conversion rate and denitrogenation activity and the relationship between fa and H/C in the products are in good agreement, and that there is no difference in reaction selectivity. 5 refs., 6 figs., 1 tab.

  7. Design of full scale debris washing system

    International Nuclear Information System (INIS)

    Taylor, M.L.; Dosani, M.A.; Wentz, J.A.; Patkar, A.N.; Barkley, N.P.

    1992-01-01

    Since 1987, IT Environmental Programs Inc. (ITEP, a subsidiary of International Technology Corporation) in conjunction with EPA/RREL in Cincinnati, Ohio, have been developing and conducting bench scale and pilot scale testing of a transportable debris washing system which can be used on-site for the decontamination of debris. During the initial phase of the debris decontamination project, a series of bench scale tests were performed in the laboratory to assess the ability of the system to remove contaminants from debris and to facilitate selection of the most efficient surfactant solution. Five nonionic, non-toxic, low foaming, surfactant solution (BG-5, MC-2000, LF-330, BB-100, and L-433) were selected for an experimental evaluation to determine their capacity to solubilize and remove contaminants from the surfaces of corroded steel places. The pieces of corroded steel were coated with a heavy grease mixture prepared in the laboratory and these pieces of debris were placed in a bench scale spray tank on a metal tray and subjected in a high-pressure spray for each surfactant solution for 15 minutes. At the end of the spray cycle, The tray was transferred to a second bench scale system, a high-turbulence wash tank, where the debris was washed for 30 minutes with the same surfactant solution as the used in the spray tank. After the was cycle was completed, the tray was removed from the wash tank and the debris was allowed to air-dry. Before and after treatment, surface-wipe samples were obtained from each of the six pieces of debris and were analyzed for oil and graese. Based on the results, BG-5 was selected as the solution best suited for cleaning grease-laden, metallic debris. 2 refs

  8. The effect of sodium bicarbonate ingestion on back squat and bench press exercise to failure.

    Science.gov (United States)

    Duncan, Michael J; Weldon, Anthony; Price, Michael J

    2014-05-01

    This study examined the acute effects of NaHCO3 ingestion on repetitions to failure and rating of perceived exertion in the back squat and bench press in trained men. Eight resistance-trained men took part in this double-blind, randomized crossover experimental study whereby they ingested NaHCO3 (0.3 g·kg(-1) body mass) or placebo (sodium chloride NaCl: 0.045 g·kg(-1) body mass) solution 60 minutes before completing a bout of resistance exercise (3 sets of bench press and back squat exercise to failure at an intensity of 80% 1 repetition maximum). Experimental conditions were separated by at least 48 hours. Participants completed more repetitions to failure in the back squat after NaHCO3 ingestion (p = 0.04) but not for bench press (p = 0.679). Mean ± SD of total repetitions was 31.3 ± 15.3 and 24.6 ± 16.2 for back squat and 28.7 ± 12.2 and 26.7 ± 10.2 for bench press in NaHCO3 and placebo conditions, respectively. Repetitions to failure decreased as set increased for the back squat and bench press (p = 0.001, both). Rating of perceived exertion significantly increased with set for the back squat and bench press (p = 0.002, both). There was no significant change in blood lactate across time or between conditions. There were however treatment × time interactions for blood pH (p = 0.014) and blood HCO3 concentration (p = 0.001). After ingestion, blood pH and HCO3 (p = 0.008) concentrations were greater for the NaHCO3 condition compared with the placebo condition (p < 0.001). The results of this study suggest that sodium bicarbonate ingestion can enhance resistance exercise performance using a repetition to failure protocol in the first exercise in a resistance exercise session.

  9. Work related injuries and associated factors among small scale ...

    African Journals Online (AJOL)

    Objective: This study aims to assess the magnitude of work related injury and associated factors among small scale industrial workers in Mizan-Aman town, Bench Maji Zone, Southwest Ethiopia. Method: A cross-sectional study design was conducted from February to May, 2016. Data was collected using a structured face to ...

  10. Development and Validity of a Scale of Perception of Velocity in Resistance Exercise

    OpenAIRE

    Bautista, Iker J.; Chirosa, Ignacio J.; Chirosa, Luis J.; Martín, Ignacio; González, Andrés; Robertson, Robert J.

    2014-01-01

    This aims of this study were twofold; 1) to development a new scale of perceived velocity in the bench press exercise and 2) to examine the scales concurrent validity. Twenty one physically active males with mean ±SD age, height and weights of: 27.5 ± 4.7 years, 1.77 ± 0.07 m, and 79.8 ± 10.3 kg respectively, took part in the study. The criterion variable used to test the validity of the new scale was the mean execution velocity (Velreal) of the bench press exercise. Three intensities (light ...

  11. Design and test of the benches for the magnetic measurement of the LHC dipoles

    International Nuclear Information System (INIS)

    Billan, J.; Buckley, J.; Saban, R.; Sievers, P.; Walckiers, L.

    1994-01-01

    The magnetic measurement of more than 1,300 LHC dipoles comprises the content of higher harmonic field components, field direction and field integrals. The measurements will be carried out along a warm bore installed inside the magnet cold bore, thus allowing the use of rotating coils at room temperature. This coil, together with Hall and NMR detectors is mounted at one end of a 12.5 m long shaft which is specially designed for very high rotational stiffness and which is controlled from its far end by a motor, an angular encoder and a level meter, all standard components placed outside the magnetic field without space restrictions. Particular emphasis has been put on the user-friendliness of the bench and its automated, computer-controlled operation requiring a minimum of staff, an important issue during production measurements of large series of magnets. The bench and its performed and precision achieved during its commissioning are described

  12. Bench-marking effects in the blaming of professionals for incidents of aggression and assault.

    Science.gov (United States)

    Carifio, J; Lanza, M

    1994-01-01

    This study compared all possible orders of responding to three vignettes describing incidents between a male patient and a female nurse in which the nurse is mildly assaulted, severely assaulted, or verbally abused by the patient (the control condition). Subjects were 32 female senior-year nursing students and 28 practicing nurses. It was found that response levels to a given vignette could predict a respondent's response to the other vignettes. Also, a significant "bench-marking" effect was found: if a subject responded to the mild assault vignette first, the subject's overall response pattern best fit the general nonlinear assignment-of-blame pattern observed, but if the subject responded to the severe assault or control vignette first, this vignette set a bench mark for responding from which the subject's subsequent responses did not deviate greatly, which slightly distorted the subject's V-shaped nonlinear response pattern.

  13. ComprehensiveBench: a Benchmark for the Extensive Evaluation of Global Scheduling Algorithms

    Science.gov (United States)

    Pilla, Laércio L.; Bozzetti, Tiago C.; Castro, Márcio; Navaux, Philippe O. A.; Méhaut, Jean-François

    2015-10-01

    Parallel applications that present tasks with imbalanced loads or complex communication behavior usually do not exploit the underlying resources of parallel platforms to their full potential. In order to mitigate this issue, global scheduling algorithms are employed. As finding the optimal task distribution is an NP-Hard problem, identifying the most suitable algorithm for a specific scenario and comparing algorithms are not trivial tasks. In this context, this paper presents ComprehensiveBench, a benchmark for global scheduling algorithms that enables the variation of a vast range of parameters that affect performance. ComprehensiveBench can be used to assist in the development and evaluation of new scheduling algorithms, to help choose a specific algorithm for an arbitrary application, to emulate other applications, and to enable statistical tests. We illustrate its use in this paper with an evaluation of Charm++ periodic load balancers that stresses their characteristics.

  14. Bench-mark experiments to study the neutron distribution in a heterogeneous reactor shielding

    International Nuclear Information System (INIS)

    Bolyatko, V.V.; Vyrskij, M.Yu.; Mashkovich, V.P.; Nagaev, R.Kh.; Prit'mov, A.P.; Sakharov, V.K.; Troshin, V.S.; Tikhonov, E.G.

    1981-01-01

    The bench-mark experiments performed at the B-2 facility of the BR-10 reactor to investigate the spatial and energy neutron distributions are described. The experimental facility includes the neutron beam channel with a slide, a mo shielding composition investigated consisted of sequential layers of steel (1KH18N9T) and graphite slabs. The neutron spectra were measured by activation method, a set of treshold and resonance detectors having been used. The detectors made it possible to obtain the absolute neutron spectra in the 1.4 eV-10 MeV range. The comparison of calculations with the results of the bench-mark experiments made it possible to prove the neutron transport calculational model realized in the ROZ-9 and ARAMAKO-2F computer codes and evaluate the validity of the ARAMAKO constants for the class of shielding compositions in question [ru

  15. Interset stretching does not influence the kinematic profile of consecutive bench-press sets.

    Science.gov (United States)

    García-López, David; Izquierdo, Mikel; Rodríguez, Sergio; González-Calvo, Gustavo; Sainz, Nuria; Abadía, Olaia; Herrero, Azael J

    2010-05-01

    This study was undertaken to examine the role of interset stretching on the time course of acceleration portion AP and mean velocity profile during the concentric phase of 2 bench-press sets with a submaximal load (60% of the 1 repetition maximum). Twenty-five college students carried out, in 3 different days, 2 consecutive bench-press sets leading to failure, performing between sets static stretching, ballistic stretching, or no stretching. Acceleration portion and lifting velocity patterns of the concentric phase were not altered during the second set, regardless of the stretching treatment performed. However, when velocity was expressed in absolute terms, static stretching reduced significantly (p velocity during the second set compared to the first one. Therefore, if maintenance of a high absolute velocity over consecutive sets is important for training-related adaptations, static stretching should be avoided or replaced by ballistic stretching.

  16. Inter- and Intrasubject Similarity of Muscle Synergies During Bench Press With Slow and Fast Velocity.

    Science.gov (United States)

    Samani, Afshin; Kristiansen, Mathias

    2018-01-01

    We investigated the effect of low and high bar velocity on inter- and intrasubject similarity of muscle synergies during bench press. A total of 13 trained male subjects underwent two exercise conditions: a slow- and a fast-velocity bench press. Surface electromyography was recorded from 13 muscles, and muscle synergies were extracted using a nonnegative matrix factorization algorithm. The intrasubject similarity across conditions and intersubject similarity within conditions were computed for muscle synergy vectors and activation coefficients. Two muscle synergies were sufficient to describe the dataset variability. For the second synergy activation coefficient, the intersubject similarity within the fast-velocity condition was greater than the intrasubject similarity of the activation coefficient across the conditions. An opposite pattern was observed for the first muscle synergy vector. We concluded that the activation coefficients are robust within conditions, indicating a robust temporal pattern of muscular activity across individuals, but the muscle synergy vector seemed to be individually assigned.

  17. Comparison of electromyographic activity during the bench press and barbell pulloverexercises

    Directory of Open Access Journals (Sweden)

    Yuri de Almeida Costa Campos

    2014-06-01

    Full Text Available The aim of the study was to compare the electromyographic (EMG activity of the following muscles: clavicular portion of pectoralis major, sternal portion of pectoralis major, long portion of triceps brachii, anterior deltoid, posterior deltoid and latissimus dorsi during dynamic contractions between flat horizontal bench press and barbell pulloverexercises. The sample comprised 12 males individuals experienced in resistance training. The volunteers made three visits to the laboratory. The first one consisted of 12 repetitions of the exercises for the electromyographic data collection. The results showed a higher EMG activation of the pectoralis major and anterior deltoid muscles in the flat horizontal bench press in comparison with the barbell pullover. The triceps brachii and latissimus dorsi muscles were more activated in the barbell pullover.

  18. Effects of whole-body vibration applied to lower extremity muscles during decline bench press exercise.

    Science.gov (United States)

    García-Gutiérrez, M T; Hazell, T J; Marín, P J

    2016-09-07

    To evaluate the effects of whole-body vibration (WBV) on skeletal muscle activity and power performance of the upper body during decline bench press exercise at different loads. Forty-seven healthy young and active male students volunteered. Each performed dynamic decline bench press repetitions with and without WBV (50 Hz, 2.2 mm) applied through a hamstring bridge exercise at three different loads of their 1-repetition maximum (1RM): 30%, 50%, and 70% 1RM. Muscle activity of the triceps brachii (TB), biceps brachii (BB), pectoralis major (PM), and biceps femoris (BF) was measured with surface electromyography electrodes and kinetic parameters of the repetitions were measured with a rotary encoder. WBV increased peak power (PP) output during the 70% 1RM condition (pbench press and this augmentation contributes to an increased peak power at higher loads and increased peak acceleration at lower loads.

  19. Pollution effects on stone benches of the Eagle Warriors Precinct at the Major Temple, Mexico City

    International Nuclear Information System (INIS)

    Miranda, J.; Gallardo, M.L.; Grimaldi, D.M.; Roman-Berrelleza, J.A.; Ruvalcaba-Sil, J.L.; Ontalba Salamanca, M.A.; Morales, J.G.

    1999-01-01

    During Major Temple archaeological site excavations in Downtown Mexico City, the precinct of one of the most important Mexica military caste, the Eagle Warriors, was discovered. The ceremonial enclosure is composed of three rooms surrounded by paintings on 11 stone benches placed against the walls. Nowadays, these paintings and the stones present the effects of different deterioration processes produced by the underground water level, high humidity, and the presence of soil, water, and air pollutants. Ion beam analysis of samples from the benches and wall paintings was performed using PIXE and RBS techniques. Using enrichment factors of elements relative to iron concentrations, possible contamination by sulfur and chlorine salts was found, as well as airborne zinc scavenged by rain

  20. Numerical modelling of orthogonal cutting: application to woodworking with a bench plane

    OpenAIRE

    Nairn, John A.

    2016-01-01

    A numerical model for orthogonal cutting using the material point method was applied to woodcutting using a bench plane. The cutting process was modelled by accounting for surface energy associated with wood fracture toughness for crack growth parallel to the grain. By using damping to deal with dynamic crack propagation and modelling all contact between wood and the plane, simulations could initiate chip formation and proceed into steady-state chip propagation including chip curling. Once st...

  1. Comparison of electromyographic activity during the bench press and barbell pulloverexercises

    OpenAIRE

    Campos, Yuri de Almeida Costa; Silva, Sandro Fernandes da

    2014-01-01

    The aim of the study was to compare the electromyographic (EMG) activity of the following muscles: clavicular portion of pectoralis major, sternal portion of pectoralis major, long portion of triceps brachii, anterior deltoid, posterior deltoid and latissimus dorsi during dynamic contractions between flat horizontal bench press and barbell pulloverexercises. The sample comprised 12 males individuals experienced in resistance training. The volunteers made three visits to the laboratory. The fi...

  2. Developing of a software for determining advanced brake failures in brakes test bench

    Directory of Open Access Journals (Sweden)

    Hakan Köylü

    2016-08-01

    Full Text Available At present time, the brake test bench conducts the braking and suspension tests of front or rear axles and the test results are evaluated through one axle. The purpose of the brake testing system is to determine braking force and damping coefficient dissymmetry of one axle. Thus, this test system evaluates the performance of service brake, hand brake and suspension systems by considering separately front and rear axle dissymmetry. For this reason, the effects of different braking and damping forces applied by right and left wheels of both axles on braking performance of all vehicle are not determined due to available algorithm of the test bench. Also, the other brake failures are not occurred due to the algorithm of brake test system. In this study, the interface has been developed to determine the other effects of dissymmetry and the other brake failures by using the one axle results of brake test bench. The interface has algorithm computing the parameters according to the interaction between front and rear axles by only using measured test results. Also, it gives the warnings by comparing changes in the parameters with braking performance rules. Braking and suspension tests of three different vehicles have been conducted by using brake test bench to determine the performance of the algorithm. Parameters based on the axle interaction have been calculated by transferring brake test results to the interface and the test results have been evaluated. As a result, the effects of brake and suspension failures on braking performance of both axle and vehicle have been determined thanks to the developed interface.

  3. Tests of the Daimler D-IVa Engine at a High Altitude Test Bench

    Science.gov (United States)

    Noack, W G

    1920-01-01

    Reports of tests of a Daimler IVa engine at the test-bench at Friedrichshafen, show that the decrease of power of that engine, at high altitudes, was established, and that the manner of its working when air is supplied at a certain pressure was explained. These tests were preparatory to the installation of compressors in giant aircraft for the purpose of maintaining constant power at high altitudes.

  4. arXiv Bench Measurements and Simulations of Beam Coupling Impedance

    CERN Document Server

    Niedermayer, Uwe

    After a general introduction, the basic principles of wake-field and beamcoupling- impedance computations are explained. This includes time domain, frequency domain, and methods that do not include excitations by means of a particle beam. The second part of this paper deals with radio frequency bench measurements of beam coupling impedances. The general procedure of the wire measurement is explained, and its features and limitations are discussed.

  5. Test-retest reliability of barbell velocity during the free-weight bench-press exercise.

    Science.gov (United States)

    Stock, Matt S; Beck, Travis W; DeFreitas, Jason M; Dillon, Michael A

    2011-01-01

    The purpose of this study was to calculate test-retest reliability statistics for peak barbell velocity during the free-weight bench-press exercise for loads corresponding to 10-90% of the 1-repetition maximum (1RM). Twenty-one healthy, resistance-trained men (mean ± SD age = 23.5 ± 2.7 years; body mass = 90.5 ± 14.6 kg; 1RM bench press = 125.4 ± 18.4 kg) volunteered for this study. A minimum of 48 hours after a maximal strength testing and familiarization session, the subjects performed single repetitions of the free-weight bench-press exercise at each tenth percentile (10-90%) of the 1RM on 2 separate occasions. For each repetition, the subjects were instructed to press the barbell as rapidly as possible, and peak barbell velocity was measured with a Tendo Weightlifting Analyzer. The test-retest intraclass correlation coefficients (model 2,1) and corresponding standard errors of measurement (expressed as percentages of the mean barbell velocity values) were 0.717 (4.2%), 0.572 (5.0%), 0.805 (3.1%), 0.669 (4.7%), 0.790 (4.6%), 0.785 (4.8%), 0.811 (5.8%), 0.714 (10.3%), and 0.594 (12.6%) for the weights corresponding to 10-90% 1RM. There were no mean differences between the barbell velocity values from trials 1 and 2. These results indicated moderate to high test-retest reliability for barbell velocity from 10 to 70% 1RM but decreased consistency at 80 and 90% 1RM. When examining barbell velocity during the free-weight bench-press exercise, greater measurement error must be overcome at 80 and 90% 1RM to be confident that an observed change is meaningful.

  6. Influence of bench press exercise modality on the iso-inertial performance

    OpenAIRE

    Jidovtseff, Boris; Croisier, Jean-Louis; Crielaard, Jean-Michel

    2006-01-01

    Introduction. - This study used an iso-inertial dynamometer to investigate the influence of counter-movement and barbell throwing during bench press exercise. A critical analysis of these modalities during muscular evaluation was also performed. Methods. - The action of muscle stretch during the counter-movement induced an increase in average velocity and a shortening of the time to reach the peak power and peak velocity. The barbell throwing did not alter the initial part of the movement yet...

  7. Influence of ballistic bench press on upper body power output in professional rugby players.

    Science.gov (United States)

    West, Daniel J; Cunningham, Daniel J; Crewther, Blair T; Cook, Christian J; Kilduff, Liam P

    2013-08-01

    The use of heavy resistance exercise provides an effective preload stimulus for inducing postactivation potentiation (PAP) and increasing peak power output (PPO). However, this approach has limited application in many sporting situations (e.g., incorporation in a precompetition warm-up); and therefore, more practical strategies for inducing PAP need to be investigated. The aim of the present study was to compare the PPO changes after performing a preload stimulus of either a ballistic exercise or a traditional heavy resistance exercise. Twenty professional rugby union players completed 3 testing sessions, each separated by 48 hours. On the first occasion, subjects underwent a 3 repetition maximum (3RM)-bench press testing session. On the next 2 occasions, subjects performed a ballistic bench throw at baseline (30% of 1RM), followed by a preload stimulus of either heavy resistance training (HRT) (heavy bench press: 3 sets of 3 repetitions at 87% 1RM) or BBP (3 sets of 3 repetitions at 30% on 1RM) followed by ballistic bench throw after 8 minutes recovery. The trials were randomized and counterbalanced. Both preload stimuli protocols increased PPO compared with baseline (BBP baseline 892 ± 108 vs. 8 minutes 924 ± 119 W, p < 0.001; HRT baseline 893 ± 104 vs. 8 minutes 931 ± 116 W; p < 0.001). There were no conditional differences between PPO at 8 minutes (p = 0.141); moreover, the change in PPO from baseline was also similar between conditions (BBP Δ + 33 ± 18; HRT Δ + 38 ± 21 W; p = 0.112). In conclusion, a ballistic exercise provided an effective method of inducing PAP and increasing upper-body PPO; moreover, this elicited similar increases in PPO as a traditional heavy resistance exercise preloading stimulus.

  8. Effects of 5 Weeks of Bench Press Training on Muscle Synergies: A Randomized Controlled Study.

    Science.gov (United States)

    Kristiansen, Mathias; Samani, Afshin; Madeleine, Pascal; Hansen, Ernst A

    2016-07-01

    Kristiansen, M, Samani, A, Madeleine, P, and Hansen, EA. Effects of 5 weeks of bench press training on muscle synergies: A randomized controlled study. J Strength Cond Res 30(7): 1948-1959, 2016-The ability to perform forceful muscle contractions has important implications in sports performance and in activities of daily living. However, there is a lack of knowledge on adaptations in intermuscular coordination after strength training. The purpose of this study was therefore to assess muscle synergies before and after 5 weeks of bench press training. Thirty untrained male subjects were randomly allocated to a training group (TRA) or a control group (CON). After the pretest, TRA completed 5 weeks of bench press training, before completing a posttest, whereas subjects in CON continued their normal life. During test sessions, surface electromyography (EMG) was recorded from 13 different muscles. Muscle synergies were extracted from EMG data using nonnegative matrix factorization. To evaluate differences between pretest and posttest, we performed a cross-correlation analysis and a cross-validation analysis, in which the synergy components extracted in the pretest session were recomputed, using the fixed synergy components from the posttest session. Two muscle synergies accounted for 90% of the total variance and reflected the concentric and eccentric phase, respectively. TRA significantly increased 3 repetition maximum in bench press with 19.0% (25th; 75th percentile, 10.3%; 21.7%) (p < 0.001), whereas no change occurred in CON. No significant differences were observed in synergy components between groups. However, decreases in correlation values for intragroup comparisons in TRA may suggest that the synergy components changed, whereas this was not the case in CON. Strength and conditioning professionals may consider monitoring changes in muscle synergies in training and rehabilitation programs as a way to benchmark changes in intermuscular coordination.

  9. The influence of isometric preload on power expressed during bench press in strength-trained men.

    Science.gov (United States)

    Bartolomei, Sandro; Fukuda, David H; Hoffman, Jay R; Stout, Jeffrey R; Merni, Franco

    2017-03-01

    The purpose of this study was to compare the power expressed during the bench press exercise in resistance-trained men following different pre-activation conditions. Twenty-two trained men (age 24.1 ± 1.7 years, height 178.6 ± 6.1 cm, body mass 81.1 ± 10.6 kg) completed a maximal effort bench press (1-RM) test (100.0 kg ± 8.1 kg). In a subsequent assessment, each participant performed concentric bench press movements with loads of 20%, 30%, 40% and 50% of their 1-RM preceded by either a concentric contraction (CC), a low isometric preload (LIP; 70% 1-RM) or a high isometric preload (HIP; 100% 1-RM) conditions. All movements were performed in a Smith machine with a settable quick-release device. Participants performed all three conditions in randomized fashion. Results indicated that power outputs during the bench press exercise following HIP were significantly (p < 0.05) greater than CC at 20% 1-RM (+9%), 30% 1-RM (+16%) and 40% 1-RM (+14%), and LIP at 20% 1-RM (+4%), 30% 1-RM (+20%) and 40% 1-RM (+15%). No differences were found between conditions at 50% 1-RM. Area under the force-power curve with HIP was greater (p < 0.05) than with CC and LIP. In conclusion, results of this study indicate that the use of a HIP (100% 1-RM) in trained participants results in significantly greater power output during the concentric phase of a multi-joint exercise when compared to standard concentric movement.

  10. Inter-subject variability of muscle synergies during bench press in power lifters and untrained individuals.

    Science.gov (United States)

    Kristiansen, M; Madeleine, P; Hansen, E A; Samani, A

    2015-02-01

    The purpose of the study was to elucidate the role of expertise on muscle synergies involved in bench press. Ten expert power lifters (EXP) and nine untrained participants (UNT) completed three sets of eight repetitions at 60% of three repetition maximum in bench press. Muscle synergies were extracted from surface electromyography data of 21 bench press cycles using non-negative matrix factorization algorithm. The synergy activation coefficient represents the relative contribution of the muscle synergy to the overall muscle activity pattern, while the muscle synergy vector represents the relative weighting of each muscle within each synergy. Describing more than 90% of the variability, two muscle synergies reflected the eccentric and concentric phase. The cross-correlations (ρ(max)) for synergy activation coefficient 2 (concentric phase) were 0.83 [0.71;0.88] and 0.59 [0.49;0.77] [Median ρ(max) (25th;75th percentile)] (P = 0.001) in UNT and EXP, respectively. Median correlation coefficient (ρ) for muscle synergy vector 2 was 0.15 [-0.08;0.46] and 0.48 [0.02;0.70] (P = 0.03) in UNT and EXP, respectively. Thus, EXP showed larger inter-subject variability than UNT in the synergy activation coefficient during the concentric phase, while the muscle synergy vectors were less variable in EXP. This points at the importance of a specialized neural strategy in elite bench press performance. © 2013 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  11. Design and Construction of a Test Bench to Characterize Efficiency and Reliability of High Voltage Battery Energy Storage Systems

    DEFF Research Database (Denmark)

    Blank, Tobias; Thomas, Stephan; Roggendorf, Christoph

    2010-01-01

    system efficiency. High voltage batteries may be advantageous for future medium voltage DC-grids as well. In all cases, high availability and reliability is indispensable. Investigations on the operating behavior of such systems are needed. For this purpose, a test bench for high voltage storage systems...... was built to analyze these processes for different battery technologies. A special safety infrastructure for the test bench was developed due to the high voltage and the storable energy of approximately 120 kWh. This paper presents the layout of the test bench for analyzing high voltage batteries with about...... 4,300 volts including all components, the safety requirements with the resultant safety circuit and the aim of the investigations to be performed with the test bench....

  12. Clearing up the hazy road from bench to bedside: A framework for integrating the fourth hurdle into translational medicine

    Directory of Open Access Journals (Sweden)

    John Jürgen H

    2008-09-01

    Full Text Available Abstract Background New products evolving from research and development can only be translated to medical practice on a large scale if they are reimbursed by third-party payers. Yet the decision processes regarding reimbursement are highly complex and internationally heterogeneous. This study develops a process-oriented framework for monitoring these so-called fourth hurdle procedures in the context of product development from bench to bedside. The framework is suitable both for new drugs and other medical technologies. Methods The study is based on expert interviews and literature searches, as well as an analysis of 47 websites of coverage decision-makers in England, Germany and the USA. Results Eight key steps for monitoring fourth hurdle procedures from a company perspective were determined: entering the scope of a healthcare payer; trigger of decision process; assessment; appraisal; setting level of reimbursement; establishing rules for service provision; formal and informal participation; and publication of the decision and supplementary information. Details are given for the English National Institute for Health and Clinical Excellence, the German Federal Joint Committee, Medicare's National and Local Coverage Determinations, and for Blue Cross Blue Shield companies. Conclusion Coverage determination decisions for new procedures tend to be less formalized than for novel drugs. The analysis of coverage procedures and requirements shows that the proof of patient benefit is essential. Cost-effectiveness is likely to gain importance in future.

  13. A Comparative Study of Ground and Underground Vibrations Induced by Bench Blasting

    Directory of Open Access Journals (Sweden)

    Xiuzhi Shi

    2016-01-01

    Full Text Available Ground vibrations originating from bench blasting may cause damage to slopes, structures, and underground workings in close proximity to an operating open-pit mine. It is important to monitor and predict ground vibration levels induced by blasting and to take measures to reduce their hazardous effects. The aims of this paper are to determine the weaker protection objects by comparatively studying bench blasting induced vibrations obtained at surface and in an underground tunnel in an open-pit mine and thus to seek vibration control methods to protect engineering objects at the site. Vibrations arising from measurement devices at surface and in an underground tunnel at the Zijinshan Open-Pit Mine were obtained. Comparative analysis of the peak particle velocities shows that, in the greatest majority of cases, surface values are higher than underground values for the same vibration distance. The transmission laws of surface and underground vibrations were established depending on the type of rock mass, the explosive charge, and the distance. Compared with the Chinese Safety Regulations for Blasting (GB6722-2014, the bench blasting induced vibrations would not currently cause damage to the underground tunnel. According to the maximum allowable peak particle velocities for different objects, the permitted maximum charges per delay are obtained to reduce damage to these objects at different distances.

  14. Complex analysis of movement in evaluation of flat bench press performance.

    Science.gov (United States)

    Król, Henryk; Golas, Artur; Sobota, Grzegorz

    2010-01-01

    The complex methodology of investigations was applied to study a movement structure on bench press. We have checked the usefulness of multimodular measuring system (SMART-E, BTS company, Italy) and a special device for tracking the position of barbell (pantograph). Software Smart Analyser was used to create a database allowing chosen parameters to be compared. The results from different measuring devices are very similar, therefore the replacement of many devices by one multimodular system is reasonable. In our study, the effect of increased barbell load on the values of muscles activity and bar kinematics during the flat bench press movement was clearly visible. The greater the weight of a barbell, the greater the myoactivity of shoulder muscles and vertical velocity of the bar. It was also confirmed the presence of the so-called sticking point (period) during the concentric phase of the bench press. In this study, the initial velocity of the barbell decreased (v(min)) not only under submaximal and maximal loads (90 and 100% of the one repetition maximum; 1-RM), but also under slightly lighter weights (70 and 80% of 1-RM).

  15. Muscular outputs during dynamic bench press under stable versus unstable conditions.

    Science.gov (United States)

    Koshida, Sentaro; Urabe, Yukio; Miyashita, Koji; Iwai, Kanzunori; Kagimori, Aya

    2008-09-01

    Previous studies have suggested that resistance training exercise under unstable conditions decreases the isometric force output, yet little is known about its influence on muscular outputs during dynamic movement. The objective of this study was to investigate the effect of an unstable condition on power, force, and velocity outputs during the bench press. Twenty male collegiate athletes (mean age, 21.3 +/- 1.5 years; mean height, 167.7 +/- 7.7 cm; mean weight, 75.9 +/- 17.5 kg) participated in this study. Each subject attempted 3 sets of single bench presses with 50% of 1 repetition maximum (1RM) under a stable condition with a flat bench and an unstable condition with a Swiss ball. Acceleration data were obtained with an accelerometer attached to the center of a barbell shaft, and peak outputs of power, force, and velocity were computed. Although significant loss of the peak outputs was found under the unstable condition (p velocity outputs, compared with previous findings. Such small reduction rates of muscular outputs may not compromise the training effect. Prospective studies are necessary to confirm whether the resistance training under an unstable condition permits the improvement of dynamic performance and trunk stability.

  16. Analysis of Muscle Activity Utilizing Bench Presses in the AnyBody Simulation Modelling System

    Directory of Open Access Journals (Sweden)

    Zhongqiu Ji

    2016-01-01

    Full Text Available Using the AnyBody human modeling system with identical weights and varying grip distance (40.0 cm, 50.0 cm, and 60.0 cm, the stress distribution for the pectoralis and the muscle of upper extremity during a bench press was simulated, and the surface myoelectricity (EMG method was validated. Methods. The physical parameters driving the model of the human body were selected as weights of 35.0% (25.0 kg and grip distances. Conclusion. The validation of AnyBody software was proved as a high validity by using EMG test of four muscles’ activity compared to AnyBody software. During a bench press, the pectoralis major is the main muscle, the pectoralis major discharge increases with the height of barbell increases, and the pectoralis major discharge decreases as the short grip width increases. When the grip width equals the shoulder width, the value of pectoralis minor is lowest; when the grip width is smaller or larger than the shoulder width, the value is larger. As the short grip distance increases, the discharge of posterior deltoid muscle and triceps surface myoelectricity increases; thus, as the short grip distance increases, the deltoid muscle and triceps assist the pectoralis major during a bench press.

  17. Rest Interval Required for Power Training With Power Load in the Bench Press Throw Exercise.

    Science.gov (United States)

    Hernández Davó, Jose L; Solana, Rafael Sabido; Sarabia Marín, Jose M; Fernández Fernández, Jaime; Moya Ramón, Manuel

    2016-05-01

    This study aimed to test the influence of various rest interval (RI) durations used between sets on power output performance and physiological and perceptual variables during a strength training session using 40% of the 1 repetition maximum (1RM) in the bench press throw exercise. Thirty-one college students (18 males and 13 females) took part in the study. The experimental protocol consists of 5 sets of 8 repetitions of the bench press throw exercise with a load representing 40% of 1RM. Subjects performed the experimental protocol on 3 different occasions, differing by the RI between sets (1, 2, or 3 minutes). During the sessions, power data (mean power and peak power), physiological (lactate concentration [La]) and perceptual (rating of perceived exertion) variables were measured. In addition, delayed onset muscular soreness was reported 24 and 48 hours after the training session. One-way repeated-measures analysis of variance showed that 1-minute RI entailed higher power decreases and greater increases in values of physiological and perceptual variables compared with both 2- and 3-minute RIs. Nevertheless, no differences were found between 2- and 3-minute RIs. Therefore, this study showed that, when training with 40% of 1RM in the bench press throw exercise, a 2-minute RI between sets can be enough to avoid significant decreases in power output. Consequently, training sessions' duration could be reduced without causing excessive fatigue, allowing additional time to focus on other conditioning priorities.

  18. Inter-Investigator Reliability of Anthropometric Prediction of 1RM Bench Press in College Football Players.

    Science.gov (United States)

    Schumacher, Richard M; Arabas, Jana L; Mayhew, Jerry L; Brechue, William F

    2016-01-01

    The purpose of this study was to determine the effect of inter-investigator differences in anthropometric assessments on the prediction of one-repetition maximum (1RM) bench press in college football players. Division-II players (n = 34, age = 20.4 ± 1.2 y, 182.3 ± 6.6 cm, 99.1 ± 18.4 kg) were measured for selected anthropometric variables and 1RM bench press at the conclusion of a heavy resistance training program. Triceps, subscapular, and abdominal skinfolds were measured in triplicate by three investigators and used to estimate %fat. Arm circumference was measured around a flexed biceps muscle and was corrected for triceps skinfold to estimate muscle cross-sectional area (CSA). Chest circumference was measured at mid-expiration. Significant differences among the testers were evident in six of the nine anthropometric variables, with the least experienced tester being significantly different from the other testers on seven variables, although average differences among investigators ranged from 1-2% for circumferences to 4-9% for skinfolds. The two more experienced testers were significantly different on only one variable. Overall agreement among testers was high (ICC>0.895) for each variable, with low coefficients of variation (CVbench press using a non-performance anthropometric equation. Minimal experience in anthropometry may not impede strength and conditioning specialists from accurately estimating 1RM bench press.

  19. Unknown loads affect force production capacity in early phases of bench press throws.

    Science.gov (United States)

    Hernández Davó, J L; Sabido Solana, R; Sarabia Marínm, J M; Sánchez Martos, Á; Moya Ramón, M

    2015-10-01

    Explosive strength training aims to improve force generation in early phases of movement due to its importance in sport performance. The present study examined the influence of lack of knowledge about the load lifted in explosive parameters during bench press throws. Thirteen healthy young men (22.8±2.0 years) participated in the study. Participants performed bench press throws with three different loads (30, 50 and 70% of 1 repetition maximum) in two different conditions (known and unknown loads). In unknown condition, loads were changed within sets in each repetition and participants did not know the load, whereas in known condition the load did not change within sets and participants had knowledge about the load lifted. Results of repeated-measures ANOVA revealed that unknown conditions involves higher power in the first 30, 50, 100 and 150 ms with the three loads, higher values of ratio of force development in those first instants, and differences in time to reach maximal rate of force development with 50 and 70% of 1 repetition maximum. This study showed that unknown conditions elicit higher values of explosive parameters in early phases of bench press throws, thereby this kind of methodology could be considered in explosive strength training.

  20. The National Football League-225 Bench Press Test and the Size-Weight Illusion.

    Science.gov (United States)

    Luebbers, Paul E; Buckingham, Gavin; Butler, Michael S

    2017-06-01

    The purpose of this study was to test reports that size and arrangement manipulations of weight plates (i.e., inducing a size-weight illusion [SWI]) effect athletic weightlifting performance. The participants were 72 experienced, weight-trained collegiate American football players. Across three weeks, each athlete performed three different repetitions-to-fatigue bench press tests (NFL-225, SWI-225, and SWI-215). A multiple regression revealed a positive association between participants' strength relative to the test load and repetitions for NFL-225 and SWI-215, but no association with SWI-225. To explore these results, players were ranked into quartiles based on their one-repetition maximum relative to 102.27 kg (225 lb), and a 3 × 4 repeated measures analysis of variance was conducted. The primary finding was a significant Test Condition × Quartile interaction ( p = .004). Bonferroni-corrected pairwise comparisons revealed that Quartile 4 (those with lowest strength relative to test load) completed more repetitions for SWI-225 compared with NFL-225 ( p = .049). These results suggest that alternate weight plate arrangements may be beneficial for those whose bench press load is near the lifter's one-repetition maximum. However, variations of the SWI do not appear to affect the performance of repetitions-to-fatigue bench press tests for the majority of collegiate American football players.