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Sample records for bed reactor electronic

  1. Removal of VOCs by hybrid electron beam reactor with catalyst bed

    International Nuclear Information System (INIS)

    Kim, Jinkyu; Han, Bumsoo; Kim, Yuri; Lee, J.H.; Park, C.R.; Kim, J.C.; Kim, J.C.; Kim, K.J.

    2004-01-01

    Electron beam decomposition of volatile organic compounds (VOCs) was studied in order to obtain information for developing effective treatment method of off-gases from industries. We have examined the combination of electron beam and catalyst honeycomb which is either 1% platinum based or ceramic honeycomb- based aluminum oxide, using a hybrid reactor in order to improve removal efficiency and CO 2 formation; and to suppress undesirable by-product formation e.g. O 3 , aerosol, H x C y. , and tar. The experiments were conducted using a pilot-scale treatment system (maximum capacity; 1800 N m 3 /h) that fitted the field size to scale up from the traditional laboratory scale system for VOC removal with electron beam irradiation. Toluene was selected as a typical VOC that was irradiated to investigate product formation, effect of ceramic and catalyst, and factors effecting overall efficiency of degradation. Styrene was selected as the most odorous compound among the VOCs of interest. It was found that VOCs could be destroyed more effectively using a hybrid system with catalyst bed than with electron beam irradiation only

  2. Transformation of carbon tetrachloride in an anaerobic packed-bed reactor without addition of another electron donor

    NARCIS (Netherlands)

    de Best, JH; Hunneman, P; Doddema, HJ; Janssen, DB; Harder, W; Doddema, Hans J.

    1999-01-01

    Carbon tetrachloride (52 mu M) was biodegraded for more than 72% in an anaerobic packed-bed reactor without addition of an external electron donor. The chloride mass balance demonstrated that all carbon tetrachloride transformed was completely dechlorinated. Chloroform and dichloromethane were

  3. Transformation of carbon tetrachloride in an anaerobic packed-bed reactor without addition of another electron donor

    NARCIS (Netherlands)

    Best, J.H. de; Hunneman, P.; Doddema, H.J.; Janssen, D.B.; Harder, W.

    1999-01-01

    Carbon tetrachloride (52 μM) was biodegraded for more than 72% in an anaerobic packed-bed reactor without addition of an external electron donor. The chloride mass balance demonstrated that all carbon tetrachloride transformed was completely dechlorinated. Chloroform and dichloromethane were

  4. Particle bed reactor modeling

    Science.gov (United States)

    Sapyta, Joe; Reid, Hank; Walton, Lew

    The topics are presented in viewgraph form and include the following: particle bed reactor (PBR) core cross section; PBR bleed cycle; fuel and moderator flow paths; PBR modeling requirements; characteristics of PBR and nuclear thermal propulsion (NTP) modeling; challenges for PBR and NTP modeling; thermal hydraulic computer codes; capabilities for PBR/reactor application; thermal/hydralic codes; limitations; physical correlations; comparison of predicted friction factor and experimental data; frit pressure drop testing; cold frit mask factor; decay heat flow rate; startup transient simulation; and philosophy of systems modeling.

  5. Pebble-bed reactor

    International Nuclear Information System (INIS)

    Lohnert, G.; Mueller-Frank, U.; Heil, J.

    1976-01-01

    A pebble-bed nuclear reactor of large power rating comprises a container having a funnel-shaped bottom forming a pebble run-out having a centrally positioned outlet. A bed of downwardly-flowing substantially spherical nuclear fuel pebbles is positioned in the container and forms a reactive nuclear core maintained by feeding unused pebbles to the bed's top surface while used or burned-out pebbles run out and discharge through the outlet. A substantially conical body with its apex pointing upwardly and its periphery spaced from the periphery of the container spreads the bottom of the bed outwardly to provide an annular flow down the funnel-shaped bottom forming the runout, to the discharge outlet. This provides a largely constant downward velocity of the spheres throughout the diameter of the bed throughout a substantial portion of the down travel, so that all spheres reach about the same burned-out condition when they leave the core, after a single pass through the core area

  6. Gas fluidized bed reactor

    International Nuclear Information System (INIS)

    Bernardelli, H. da C.

    1976-03-01

    The equations of motion for both gas and particles in a gas fluidised system are stablished through general assumptions which are generally accepted on physical grounds. The resulting model is used to study the velocity fields of each phase in the case of an isolated bubble rising close to the flat distributor plate. A well posed problem results for the solution of Laplace's equation of the potential flow of the particles when consideration is given to the presence of the distributor as a boundary condition. The corresponding stream functions are also obtained which enable the drawing of the motion patterns using numerical techniques. The following two dimensional cases are analysed: S/b=1; S/b=1,5; S/b=2,5; S/b=5 and the limiting case S/b→αinfinite. The results for the interphase exchange between bubbles and particulate phases are applied to a gas fluidised bed reactor and its effect on the chemical conversion is studied for the simplest cases of piston flow and perfect mixing in the particulate phase [pt

  7. Electrochemical Recovery of Gold from Waste Electric and Electronic Equipment Using Circulating Particulate Bed Reactor (CPBE)

    Science.gov (United States)

    Ravinder, T.; Ali, U. F. M.; Ridwan, F. M.; Ibrahim, N.; Azmi, N. H.

    2017-06-01

    The utilization of electrochemical process recovery involving low reactant concentrations of metal requires electrodes with high mass transport rates and specific surface areas. This is essential to increase cross-sectional current densities whilst optimizing the capital and operating costs. Experimental results demonstrated that Circulating Particulate Bed Reactor (CPBE) is suitable for the recovery of low concentrations of gold from aqueous chloride solution containing {{AuCl}}4- and {{AuCl}}2- of less than 0.5 mol m-3(< 102 g m-3). Elemental gold was successfully obtained on 0.5-1 mm gr particles in an electrochemical reactor incorporating a cation- permeable membrane and operated in bath recycle mode. Depletion to concentration < 5 × 10-3 mol m-3 (< 1 g m-3) appeared to be mass transport controlled at an applied potential of +0.20 V (SCE), specific electrical energy consumption (SEEC) of ca. 800-1300 kWh h (tonne Au)-1 for cell voltages (U) of 2.0-3.0 V, and fractional current efficiencies of ca. 0.95. However, atomic absorption and UV spectrophotometry established that as the ([{{AuCl}}4-+[{{AuCl}}2-]) concentration decayed, the [{{AuCl}}4-]:[{{AuCl}}2-] molar ratio changed. A multi-step mechanism for reduction of {{AuCl}}4- ions explained this behavior in terms of changing overpotentials for {{AuCl}}4- and {{AuCl}}2- reduction as total dissolved gold concentration decreased. In addition, SEM images confirmed that adherent and coherent Au deposits were achieved with CPBE for Au deposition under mass transport control at 0.20 V (SCE).

  8. Particle Bed Reactor scaling relationships

    International Nuclear Information System (INIS)

    Slovik, G.; Araj, K.; Horn, F.L.; Ludewig, H.; Benenati, R.

    1987-01-01

    Scaling relationships for Particle Bed Reactors (PBRs) are discussed. The particular applications are short duration systems, i.e., for propulsion or burst power. Particle Bed Reactors can use a wide selection of different moderators and reflectors and be designed for such a wide range of power and bed power densities. Additional design considerations include the effect of varying the number of fuel elements, outlet Mach number in hot gas channel, etc. All of these variables and options result in a wide range of reactor weights and performance. Extremely light weight reactors (approximately 1 kg/MW) are possible with the appropriate choice of moderator/reflector and power density. Such systems are very attractive for propulsion systems where parasitic weight has to be minimized

  9. Fluidized-bed nuclear reactor

    International Nuclear Information System (INIS)

    Grimmett, E.S.; Kunze, J.F.

    1975-01-01

    A reactor vessel containing a fluidized-bed region of particulate material including both a neutron-moderating and a fertile substance is described. A gas flow including fissile material passes through the vessel at a sufficient rate to fluidize the particulate material and at a sufficient density to support a thermal fission reaction within the fluidized-bed region. The high-temperature portion of a heat transfer system is located within the fluidized-bed region of the reactor vessel in direct contact with the fluidized particles. Heat released by fission is thereby transferred at an enhanced rate to a coolant circulating within the heat transfer system. Fission products are continuously removed from the gas flow and supplemental fissile material added during the reactor operation. (U.S.)

  10. MIT pebble bed reactor project

    Energy Technology Data Exchange (ETDEWEB)

    Kadak, Andrew C. [Massachusetts Institute of Technology, Cambridge (United States)

    2007-03-15

    The conceptual design of the MIT modular pebble bed reactor is described. This reactor plant is a 250 Mwth, 120 Mwe indirect cycle plant that is designed to be deployed in the near term using demonstrated helium system components. The primary system is a conventional pebble bed reactor with a dynamic central column with an outlet temperature of 900 C providing helium to an intermediate helium to helium heat exchanger (IHX). The outlet of the IHX is input to a three shaft horizontal Brayton Cycle power conversion system. The design constraint used in sizing the plant is based on a factory modularity principle which allows the plant to be assembled 'Lego' style instead of constructed piece by piece. This principle employs space frames which contain the power conversion system that permits the Lego-like modules to be shipped by truck or train to sites. This paper also describes the research that has been conducted at MIT since 1998 on fuel modeling, silver leakage from coated fuel particles, dynamic simulation, MCNP reactor physics modeling and air ingress analysis.

  11. MIT pebble bed reactor project

    International Nuclear Information System (INIS)

    Kadak, Andrew C.

    2007-01-01

    The conceptual design of the MIT modular pebble bed reactor is described. This reactor plant is a 250 Mwth, 120 Mwe indirect cycle plant that is designed to be deployed in the near term using demonstrated helium system components. The primary system is a conventional pebble bed reactor with a dynamic central column with an outlet temperature of 900 C providing helium to an intermediate helium to helium heat exchanger (IHX). The outlet of the IHX is input to a three shaft horizontal Brayton Cycle power conversion system. The design constraint used in sizing the plant is based on a factory modularity principle which allows the plant to be assembled 'Lego' style instead of constructed piece by piece. This principle employs space frames which contain the power conversion system that permits the Lego-like modules to be shipped by truck or train to sites. This paper also describes the research that has been conducted at MIT since 1998 on fuel modeling, silver leakage from coated fuel particles, dynamic simulation, MCNP reactor physics modeling and air ingress analysis

  12. Particle bed reactor scaling relationships

    Science.gov (United States)

    Slovik, G.; Araj, K.; Horn, F. L.; Ludewig, H.; Benenati, R.

    The Particle Bed Reactor (PBR) concept can be used in several applications both as part of a power generating system or as a direct propulsion unit. In order to carry out optimization studies of systems involving a PBR, it is necessary to know the variation of the critical mass with pertinent system parameters such as weight, size, power level and thrust level. A parametric study is presented for all the practical combinations of fuel and moderating material. The PBR is described, the practical combinations of materials and dimensions are discussed, and an example is presented.

  13. Particle Bed Reactor engine technology

    Science.gov (United States)

    Sandler, S.; Feddersen, R.

    1992-03-01

    This paper discusses the Particle Bed Reactor (PBR) based propulsion system being developed under the Space Nuclear Thermal Propulsion (SNTP) program. A PBR engine is a light weight, compact propulsion system which offers significant improvement over current technology systems. Current performance goals are a system thrust of 75,000 pounds at an Isp of 1000 sec. A target thrust to weight ratio (T/W) of 30 has been established for an unshielded engine. The functionality of the PBR, its pertinent technology issues and the systems required to make up a propulsion system are described herein. Accomplishments to date which include hardware development and tests for the PBR engine are also discussed. This paper is intended to provide information on and describe the current state-of-the-art of PBR technology.

  14. Particle Bed Reactor engine technology

    International Nuclear Information System (INIS)

    Sandler, S.; Feddersen, R.

    1992-01-01

    This paper discusses the Particle Bed Reactor (PBR) based propulsion system being developed under the Space Nuclear Thermal Propulsion (SNTP) program. A PBR engine is a light weight, compact propulsion system which offers significant improvement over current technology systems. Current performance goals are a system thrust of 75,000 pounds at an Isp of 1000 sec. A target thrust to weight ratio (T/W) of 30 has been established for an unshielded engine. The functionality of the PBR, its pertinent technology issues and the systems required to make up a propulsion system are described herein. Accomplishments to date which include hardware development and tests for the PBR engine are also discussed. This paper is intended to provide information on and describe the current state-of-the-art of PBR technology. 4 refs

  15. Fluidized Bed Reactor as Solid State Fermenter

    Directory of Open Access Journals (Sweden)

    Krishnaiah, K.

    2005-01-01

    Full Text Available Various reactors such as tray, packed bed, rotating drum can be used for solid-state fermentation. In this paper the possibility of fluidized bed reactor as solid-state fermenter is considered. The design parameters, which affect the performances are identified and discussed. This information, in general can be used in the design and the development of an efficient fluidized bed solid-state fermenter. However, the objective here is to develop fluidized bed solid-state fermenter for palm kernel cake conversion into enriched animal and poultry feed.

  16. Core homogenization method for pebble bed reactors

    International Nuclear Information System (INIS)

    Kulik, V.; Sanchez, R.

    2005-01-01

    This work presents a core homogenization scheme for treating a stochastic pebble bed loading in pebble bed reactors. The reactor core is decomposed into macro-domains that contain several pebble types characterized by different degrees of burnup. A stochastic description is introduced to account for pebble-to-pebble and pebble-to-helium interactions within a macro-domain as well as for interactions between macro-domains. Performance of the proposed method is tested for the PROTEUS and ASTRA critical reactor facilities. Numerical simulations accomplished with the APOLLO2 transport lattice code show good agreement with the experimental data for the PROTEUS reactor facility and with the TRIPOLI4 Monte Carlo simulations for the ASTRA reactor configuration. The difference between the proposed method and the traditional volume-averaged homogenization technique is negligible while only one type of fuel pebbles present in the system, but it grows rapidly with the level of pebble heterogeneity. (authors)

  17. FBR and RBR particle bed space reactors

    International Nuclear Information System (INIS)

    Powell, J.R.; Botts, T.E.

    1983-01-01

    Compact, high-performance nuclear reactor designs based on High-Temperature Gas Reactors (HTGRs) particulate fuel are investigated. The large surface area available with the small-diameter (approx. 500 microns) particulate fuel allows very high power densities (MW's/liter), small temperature differences between fuel and coolant (approx. 10 0 K), high coolant-outlet temperatures (1500 to 3000 0 K, depending on design), and fast reactor startup (approx. 2 to 3 seconds). Two reactor concepts are developed - the Fixed Bed Reactor (FBR), where the fuel particles are packed into a thin annular bed between two porous cylindrical drums, and the Rotating Bed Reactor (RBR), where the fuel particles are held inside a cold rotating (typically approx. 500 rpm) porous cylindrical drum. The FBR can operate steady-state in the closed-cycle He-cooled mode or in the open-cycle H 2 -cooled mode. The RBR will operate only in the open-cycle H 2 -cooled mode

  18. A new fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Sefidvash, F.

    1986-01-01

    A new nuclear reactor design based on the fluidized bed concept is proposed. A current design utilizes spherical fuel of slightly enriched Zircaloy-clad uranium dioxide fluidized by light water under pressure. The reactor is modular in system; therefore, any size reactor can be constructed from the basic standard modul. The reactor physics calculations show that reactivity increases with porosity to a maximum value and thereafter decreases. This produces inherent safety and eliminates the need for control rods and burnable poisons. The heat transfer calculations show that the maximum power extracted from the reactor core is not limited to the material temperature limits but to the maximum mass flow of coolant, which corresponds to the desired operating porosity. Design simplicity and inherent safety make it an attractive small reactor design. (Author) [pt

  19. Particle bed reactor nuclear rocket concept

    International Nuclear Information System (INIS)

    Ludewig, H.

    1991-01-01

    The particle bed reactor nuclear rocket concept consists of fuel particles (in this case (U,Zr)C with an outer coat of zirconium carbide). These particles are packed in an annular bed surrounded by two frits (porous tubes) forming a fuel element; the outer one being a cold frit, the inner one being a hot frit. The fuel element are cooled by hydrogen passing in through the moderator. These elements are assembled in a reactor assembly in a hexagonal pattern. The reactor can be either reflected or not, depending on the design, and either 19 or 37 elements, are used. Propellant enters in the top, passes through the moderator fuel element and out through the nozzle. Beryllium used for the moderator in this particular design to withstand the high radiation exposure implied by the long run times

  20. Fungi solubilisation of low rank coal: performances of stirred tank, fluidised bed and packed bed reactors

    CSIR Research Space (South Africa)

    Oboirien, BO

    2013-02-01

    Full Text Available Coal biosolubilisation was investigated in stirred tank reactor, fluidised bed and fixed bed bioreactors with a view to highlight the advantages and shortcomings of each of these reactor configurations. The stirred aerated bioreactor and fluidised...

  1. Pebble Bed Reactor Dust Production Model

    Energy Technology Data Exchange (ETDEWEB)

    Abderrafi M. Ougouag; Joshua J. Cogliati

    2008-09-01

    The operation of pebble bed reactors, including fuel circulation, can generate graphite dust, which in turn could be a concern for internal components; and to the near field in the remote event of a break in the coolant circuits. The design of the reactor system must, therefore, take the dust into account and the operation must include contingencies for dust removal and for mitigation of potential releases. Such planning requires a proper assessment of the dust inventory. This paper presents a predictive model of dust generation in an operating pebble bed with recirculating fuel. In this preliminary work the production model is based on the use of the assumption of proportionality between the dust production and the normal force and distance traveled. The model developed in this work uses the slip distances and the inter-pebble forces computed by the authors’ PEBBLES. The code, based on the discrete element method, simulates the relevant static and kinetic friction interactions between the pebbles as well as the recirculation of the pebbles through the reactor vessel. The interaction between pebbles and walls of the reactor vat is treated using the same approach. The amount of dust produced is proportional to the wear coefficient for adhesive wear (taken from literature) and to the slip volume, the product of the contact area and the slip distance. The paper will compare the predicted volume with the measured production rates. The simulation tallies the dust production based on the location of creation. Two peak production zones from intra pebble forces are predicted within the bed. The first zone is located near the pebble inlet chute due to the speed of the dropping pebbles. The second peak zone occurs lower in the reactor with increased pebble contact force due to the weight of supported pebbles. This paper presents the first use of a Discrete Element Method simulation of pebble bed dust production.

  2. Pebble Bed Reactor Dust Production Model

    International Nuclear Information System (INIS)

    Abderrafi M. Ougouag; Joshua J. Cogliati

    2008-01-01

    The operation of pebble bed reactors, including fuel circulation, can generate graphite dust, which in turn could be a concern for internal components; and to the near field in the remote event of a break in the coolant circuits. The design of the reactor system must, therefore, take the dust into account and the operation must include contingencies for dust removal and for mitigation of potential releases. Such planning requires a proper assessment of the dust inventory. This paper presents a predictive model of dust generation in an operating pebble bed with recirculating fuel. In this preliminary work the production model is based on the use of the assumption of proportionality between the dust production and the normal force and distance traveled. The model developed in this work uses the slip distances and the inter-pebble forces computed by the authors PEBBLES. The code, based on the discrete element method, simulates the relevant static and kinetic friction interactions between the pebbles as well as the recirculation of the pebbles through the reactor vessel. The interaction between pebbles and walls of the reactor vat is treated using the same approach. The amount of dust produced is proportional to the wear coefficient for adhesive wear (taken from literature) and to the slip volume, the product of the contact area and the slip distance. The paper will compare the predicted volume with the measured production rates. The simulation tallies the dust production based on the location of creation. Two peak production zones from intra pebble forces are predicted within the bed. The first zone is located near the pebble inlet chute due to the speed of the dropping pebbles. The second peak zone occurs lower in the reactor with increased pebble contact force due to the weight of supported pebbles. This paper presents the first use of a Discrete Element Method simulation of pebble bed dust production

  3. Small propulsion reactor design based on particle bed reactor concept

    International Nuclear Information System (INIS)

    Ludewig, H.; Lazareth, O.; Mughabghab, S.; Perkins, K.; Powell, J.R.

    1989-01-01

    In this paper Particle Bed Reactor (PBR) designs are discussed which use 233 U and /sup 242m/Am as fissile materials. A constant total power of 100MW is assumed for all reactors in this study. Three broad aspects of these reactors is discussed. First, possible reactor designs are developed, second physics calculations are outlined and discussed and third mass estimates of the various candidates reactors are made. It is concluded that reactors with a specific mass of 1 kg/MW can be envisioned of 233 U is used and approximately a quarter of this value can be achieved if /sup 242m/Am is used. If this power level is increased by increasing the power density lower specific mass values are achievable. The limit will be determined by uncertainties in the thermal-hydraulic analysis. 5 refs., 5 figs., 6 tabs

  4. Hydrodynamics of multi-phase packed bed micro-reactors

    NARCIS (Netherlands)

    Márquez Luzardo, N.M.

    2010-01-01

    Why to use packed bed micro-reactors for catalyst testing? Miniaturized packed bed reactors have a large surface-to-volume ratio at the reactor and particle level that favors the heat- and mass-transfer processes at all scales (intra-particle, inter-phase and inter-particle or reactor level). If the

  5. Mathematical modelling of fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Werther, J [BASF A.G., Ludwigshafen am Rhein (Germany, F.R.)

    1978-11-01

    Among the many fluidized bed models to be found in the literature, the two-phase model originally proposed by May has proved most suitable for accomodation of recent advances in flow mechanics: this model resolves the gas/solids fluidized bed into a bubble phase and a suspension phase surrounding the bubbles. Its limitation to slow reactions is a disadvantage. On the basis of the analogy between fluidized beds and gas/liquid systems, a general two-phase model that is valid for fast reactions has therefore been developed and its validity is confirmed by comparison with the experimental results obtained by others. The model describes mass transfer across the phase interface with the aid of the film theory known from gas/liquid reactor technology, and the reaction occurring in the suspension phase as a pseudo-homogeneous reaction. Since the dependence of the performance of fluidized bed reactors upon geometry is accounted for, the model can also be used for scale-up calculations. Its use is illustrated with the aid of design diagrams.

  6. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    Energy Technology Data Exchange (ETDEWEB)

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  7. The Pebble Bed Modular Reactor: An obituary

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Steve, E-mail: stephen.thomas@gre.ac.u [Public Services International Research Unit (PSIRU), Business School, University of Greenwich, 30 Park Row, London SE10 9LS (United Kingdom)

    2011-05-15

    The High Temperature Gas-cooled Reactor (HTGR) has exerted a peculiar attraction over nuclear engineers. Despite many unsuccessful attempts over half a century to develop it as a commercial power reactor, there is still a strong belief amongst many nuclear advocates that a highly successful HTGR technology will emerge. The most recent attempt to commercialize an HTGR design, the Pebble Bed Modular Reactor (PBMR), was abandoned in 2010 after 12 years of effort and the expenditure of a large amount of South African public money. This article reviews this latest attempt to commercialize an HTGR design and attempts to identify which issues have led to its failure and what lessons can be learnt from this experience. It concludes that any further attempts to develop HTGRs using Pebble Bed technology should only be undertaken if there is a clear understanding of why earlier attempts have failed and a high level of confidence that earlier problems have been overcome. It argues that the PBMR project has exposed serious weaknesses in accountability mechanisms for the expenditure of South African public money. - Research highlights: {yields} In this study we examine the reasons behind the failure of the South African PBMR programme. {yields} The study reviews the technical issues that have arisen and lessons for future reactor developments. {yields} The study also identifies weaknesses in the accountability mechanisms for public spending.

  8. The ESKOM pebble bed modular reactor

    International Nuclear Information System (INIS)

    Gittus, J.H.

    1999-01-01

    An audit has been made of the design, construction, safety, economics and marketability of the ESKOM pebble bed modular reactor (PBMR). In this paper that audit is briefly summarized. The principal conclusions of the audit are as follows. The design is sound. It is a logical development of the designs proposed for other, modern, high-temperature gas-cooled reactors. More than 80% of the cost of constructing and commissioning a series of PBMRs would be spent in South Africa. The PBMR is much safer than existing nuclear power reactors and for many practical purposes it may be treated as a conventional chemical plant. The PBMR is economically competitive with thermal power stations. There is a substantial global market for the PBMR. (author)

  9. A Numerical Model for Trickle Bed Reactors

    Science.gov (United States)

    Propp, Richard M.; Colella, Phillip; Crutchfield, William Y.; Day, Marcus S.

    2000-12-01

    Trickle bed reactors are governed by equations of flow in porous media such as Darcy's law and the conservation of mass. Our numerical method for solving these equations is based on a total-velocity splitting, sequential formulation which leads to an implicit pressure equation and a semi-implicit mass conservation equation. We use high-resolution finite-difference methods to discretize these equations. Our solution scheme extends previous work in modeling porous media flows in two ways. First, we incorporate physical effects due to capillary pressure, a nonlinear inlet boundary condition, spatial porosity variations, and inertial effects on phase mobilities. In particular, capillary forces introduce a parabolic component into the recast evolution equation, and the inertial effects give rise to hyperbolic nonconvexity. Second, we introduce a modification of the slope-limiting algorithm to prevent our numerical method from producing spurious shocks. We present a numerical algorithm for accommodating these difficulties, show the algorithm is second-order accurate, and demonstrate its performance on a number of simplified problems relevant to trickle bed reactor modeling.

  10. Modelling of a falling sludge bed reactor using AQUASIM | Ristow ...

    African Journals Online (AJOL)

    Modelling of a falling sludge bed reactor using AQUASIM. ... AFRICAN JOURNALS ONLINE (AJOL) · Journals · Advanced Search · USING AJOL · RESOURCES ... a system of mixed reactors connected by water flow and mass flux streams.

  11. Evolution of Particle Bed Reactor Fuel

    Science.gov (United States)

    Jensen, Russell R.; Evans, Robert S.; Husser, Dewayne L.; Kerr, John M.

    1994-07-01

    To realize the potential performance advantages inherent in a particle bed reactor (PBR) for nuclear thermal propulsion (NTP) applications, high performance particle fuel is required. This fuel must operate safely and without failure at high temperature in high pressure, flowing hydrogen propellant. The mixed mean outlet temperature of the propellant is an important characteristic of PBR performance. This temperature is also a critical parameter for fuel particle design because it dictates the required maximum fuel operating temperature. In this paper, the evolution in PBR fuel form to achieve higher operating temperatures is discussed and the potential thermal performance of the different fuel types is evaluated. It is shown that the optimum fuel type for operation under the demanding conditions in a PBR is a coated, solid carbide particle.

  12. Fluidized-bed reactors processes and operating conditions

    CERN Document Server

    Yates, John G

    2016-01-01

    The fluidized-bed reactor is the centerpiece of industrial fluidization processes. This book focuses on the design and operation of fluidized beds in many different industrial processes, emphasizing the rationale for choosing fluidized beds for each particular process. The book starts with a brief history of fluidization from its inception in the 1940’s. The authors present both the fluid dynamics of gas-solid fluidized beds and the extensive experimental studies of operating systems and they set them in the context of operating processes that use fluid-bed reactors. Chemical engineering students and postdocs as well as practicing engineers will find great interest in this book.

  13. Theoretical comparison of packed bed and fluidized bed membrane reactors for methane reforming

    NARCIS (Netherlands)

    Gallucci, F.; van Sint Annaland, M.; Kuipers, J.A.M.

    2010-01-01

    In this theoretical work the performance of different membrane reactor concepts, both fluidized bed and packed bed membrane reactors, has been compared for ultra-pure hydrogen production via methane reforming. Using detailed theoretical models, the required membrane area to reach a given conversion

  14. Comparison of packed bed and fluidized bed membrane reactors for methane reforming

    NARCIS (Netherlands)

    Gallucci, F.; van Sint Annaland, M.; Kuipers, J.A.M.

    2009-01-01

    In this work the performance of different membrane reactor concepts, both fluidized bed and packed bed membrane reactors, have been compared for the reforming of methane for the production of ultra-pure hydrogen. Using detailed theoretical models, the required membrane area to reach a given

  15. Fixed-bed Reactor Dynamics and Control - A Review

    DEFF Research Database (Denmark)

    Jørgensen, S. B.

    1986-01-01

    The industrial diversity of fixed bed reactors offers a challenging and relevant set of control problems. These intricate problems arise due to the rather complex dynamics of fixed bed reactors and to the complexity of actual reactor configurations. Many of these control problems are nonlinear...... and multi-variable. During the last decade fixed bed reactor control strategies have been proposed and investigated experimentally. This paper reviews research on these complex control problems with an emphasis upon solutions which have been demon-strated to work in the laboratory and hold promise...

  16. The fixed bed nuclear reactor concept

    International Nuclear Information System (INIS)

    Sahin, S.; Sefidvash, F.

    2007-01-01

    The core of a water moderated Fixed Bed Nuclear Reactor (FBNR), possessing, for instance, an electrical power of 40 MW, consists of 1.35 million fuel pellets (9.5 t) with a diameter of 1.5 cm each. The low enriched uranium fuel is made of TRISO type microspheres used in the HTGR, embedded in a graphite matrix and cladded by a shell of 1 mm SiC. Under any thinkable operational condition the fuel temperature will be below 400 C whereas its stability limit is at about 1600 C. The first characteristic of the FBNR is, therefore, its robust fuel under relatively 'cold' operating conditions and - due to the outer SiC - shell layer - the freedom from any hydrogen production. To operate the reactor the fuel pellets are pumped by a flow of water from below into the core regions where they form a stable fixed bed of about 4 cubic meter and become critical for energy production heating the outlet water to about 330 C (at 160 bar) which feeds a steam generator. The new safety feature is now the following: In case of any abnormity (e.g. external power failure, overheating etc.) the circulating pump stops and - due to gravity - the fuel pellets fall automatically out of the core region into a helical 'fuel chamber' underneath the core where their decay heat is transferred passively by natural circulation to a water tank housing the fuel chamber. The safety principle, applied here, is: The loss of an active component (circulating pump) induces a self-controlled, passively working shut-down manoeuvre accompanied by a foolproof decay heat removal without any emergency power system or any human interaction. The fuel chamber is sealed and is transported as the only reactor component to and from the reactor site. There is no possibility to irradiate fertile fuel, too. For a long-life core (larger than a 10 years cycle time) the fuel can either be poisoned by gadolinium-oxide or by a piston type core limiter adjusting the height and controlling thereby the number of the fuel pellets in

  17. Study of reactivity of fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Rammsy, J.E.M.

    1985-01-01

    The reactor physics calculations of a 19 module Fluidized Bed Nuclear Reactor using Leopard and Odog codes are performed. The behaviour of the reactor was studied by calculating the reactivity of the reactor as a function of the parameters governing the operational and accidental conditions of the reactor. The effects of temperature, pressure, and vapor generation in the core on the reactivity are calculated. Also the start up behaviour of the reactor is analyzed. For the purpose of the study of a prototype research reactor, the calculations on a one module reactor have been performed. (Author) [pt

  18. Fluidized bed nuclear reactor as a IV generation reactor

    International Nuclear Information System (INIS)

    Sefidvash, Farhang

    2002-01-01

    The object of this paper is to analyze the characteristics of the Fluidized Bed Nuclear Reactor (FBNR) concept under the light of the requirements set for the IV generation nuclear reactors. It is seen that FBNR generally meets the goals of providing sustainable energy generation that meets clean air objectives and promotes long-term availability of systems and effective fuel utilization for worldwide energy production; minimize and manage their nuclear waste and notably reduce the long term stewardship burden in the future, thereby improving protection for the public health and the environment; increase the assurance that it is a very unattractive and least desirable route for diversion or theft of weapons-usable materials; excel in safety and reliability; have a very low likelihood and degree of reactor core damage; eliminate the need for offsite emergency response; have a clear life-cycle cost advantage over other energy sources; have a level of financial risk comparable to other energy projects. The other advantages of the proposed design are being modular, low environmental impact, exclusion of severe accidents, short construction period, flexible adaptation to demand, excellent load following characteristics, and competitive economics. (author)

  19. An energy amplifier fluidized bed nuclear reactor concept

    International Nuclear Information System (INIS)

    Sefidvash, F.; Seifritz, W.

    2001-01-01

    The concept of a fluidized bed nuclear reactor driven by an energy amplifier system is described. The reactor has promising characteristics of inherent safety and passive cooling. The reactor can easily operate with any desired spectrum in order to be a plutonium burner or have it operate with thorium fuel cycle. (orig.) [de

  20. Operational methods of the fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Borges, V.; Sefidvash, F.

    1993-01-01

    The operational curve of reactivity as a function of porosity of the Fluidized Bed Nuclear Reactor is presented. The strategies for start-up, shut-down and maintaining the reactor critical during operation are described. The inherent safety of the reactor from neutronic point of view under steady state condition is demonstrated. (author)

  1. A Pebble Bed Reactor cross section methodology

    International Nuclear Information System (INIS)

    Hudson, Nathanael H.; Ougouag, Abderrafi M.; Rahnema, Farzad; Gougar, Hans

    2009-01-01

    A method is presented for the evaluation of microscopic cross sections for the Pebble Bed Reactor (PBR) neutron diffusion computational models during convergence to an equilibrium (asymptotic) fuel cycle. This method considers the isotopics within a core spectral zone and the leakages from such a zone as they arise during reactor operation. The randomness of the spatial distribution of fuel grains within the fuel pebbles and that of the fuel and moderator pebbles within the core, the double heterogeneity of the fuel, and the indeterminate burnup of the spectral zones all pose a unique challenge for the computation of the local microscopic cross sections. As prior knowledge of the equilibrium composition and leakage is not available, it is necessary to repeatedly re-compute the group constants with updated zone information. A method is presented to account for local spectral zone composition and leakage effects without resorting to frequent spectrum code calls. Fine group data are pre-computed for a range of isotopic states. Microscopic cross sections and zone nuclide number densities are used to construct fine group macroscopic cross sections, which, together with fission spectra, flux modulation factors, and zone buckling, are used in the solution of the slowing down balance to generate a new or updated spectrum. The microscopic cross-sections are then re-collapsed with the new spectrum for the local spectral zone. This technique is named the Spectral History Correction (SHC) method. It is found that this method accurately recalculates local broad group microscopic cross sections. Significant improvement in the core eigenvalue, flux, and power peaking factor is observed when the local cross sections are corrected for the effects of the spectral zone composition and leakage in two-dimensional PBR test problems.

  2. Biological perchlorate reduction in packed bed reactors using elemental sulfur.

    Science.gov (United States)

    Sahu, Ashish K; Conneely, Teresa; Nüsslein, Klaus R; Ergas, Sarina J

    2009-06-15

    Sulfur-utilizing perchlorate (ClO4-)-reducing bacteria were enriched from a denitrifying wastewater seed with elemental sulfur (S0) as an electron donor. The enrichment was composed of a diverse microbial community, with the majority identified as members of the phylum Proteobacteria. Cultures were inoculated into bench-scale packed bed reactors (PBR) with S0 and crushed oyster shell packing media. High ClO4-concentrations (5-8 mg/L) were reduced to PBR performance decreased when effluent recirculation was applied or when smaller S0 particle sizes were used, indicating that mass transfer of ClO4- to the attached biofilm was not the limiting mechanism in this process, and that biofilm acclimation and growth were key factors in overall reactor performance. The presence of nitrate (6.5 mg N/L) inhibited ClO4- reduction. The microbial community composition was found to change with ClO4- availability from a majority of Beta-Proteobacteria near the influent end of the reactor to primarily sulfur-oxidizing bacteria near the effluent end of the reactor.

  3. Theory and measurements of electrophoretic effects in monolith, fixed-bed, and fluidized-bed plasma reactors

    International Nuclear Information System (INIS)

    Morin, T.J.

    1989-01-01

    Pressure gradients and secondary flow fields generated by the passage of electrical current in a d.c. gas discharge or gas laser are topics of longstanding interest in the gaseous electronics literature. These hydrodynamic effects of space charge fields and charged particle density gradients have been principally exploited in the development of gas separation and purification processes. In recent characterization studies of fixed-bed and fluidized-bed plasma reactors several anomalous flow features have been observed. These reactors involve the contacting of a high-frequency, resonantly-sustained, disperse gas discharge with granular solids in a fixed or fluidized bed. Anomalies in the measured pressure drops and fluidization velocities have motivated the development of an appropriate theoretical approach to, and some additional experimental investigations of electrophoretic effects in disperse gas discharges. In this paper, a theory which includes the effects of space charge and diffusion is used to estimate the electric field and charged particle density profiles. These profiles are then used to calculate velocity fields and gas flow rates for monolith, fixed-bed, and fluidized-bed reactors. These results are used to rationalize measurements of gas flow rates and axial pressure gradients in high-frequency disperse gas discharges with and without an additional d.c. axial electric field

  4. Packed Bed Reactor Technology for Chemical-Looping Combustion

    NARCIS (Netherlands)

    Noorman, S.; Sint Annaland, van M.; Kuipers, J.A.M.

    2007-01-01

    Chemical-looping combustion (CLC) has emerged as an alternative for conventional power production processes to intrinsically integrate power production and CO2 capture. In this work a new reactor concept for CLC is proposed, based on dynamically operated packed bed reactors. With analytical

  5. Biological Phosphorus Removal in a Moving Bed Biofilm Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Helness, Herman

    2007-09-15

    The scope of this study was to investigate use of the moving bed biofilm reactor (MBBR) process for biological phosphorus removal. The goal has been to describe the operating conditions required for biological phosphorus and nitrogen removal in a MBBR operated as a sequencing batch reactor (SBR), and determine dimensioning criteria for such a process

  6. Mixing and scale affect moving bed biofilm reactor (MBBR) performance

    NARCIS (Netherlands)

    Kamstra, Andries; Blom, Ewout; Terjesen, Bendik Fyhn

    2017-01-01

    Moving Bed Biofilm Reactors (MBBR) are used increasingly in closed systems for farming of fish. Scaling, i.e. design of units of increasing size, is an important issue in general bio-reactor design since mixing behaviour will differ between small and large scale. Research is mostly performed on

  7. Fluidized bed reactor for working up carbon coated particles

    International Nuclear Information System (INIS)

    Marschollek, M.; Simon, W.; Walter, C.

    1981-01-01

    A fluidized bed reactor is described for working up carbon coated particles, particularly nuclear fuel particles or fertile material particles consisting essentially of a cylindrical portion connected to a conical portion. Gas supply pipes, gas distribution space and gas distribution heads are provided within the conical reactor lower portion, the gas distribution members being arranged in at least two superimposed planes and distributed symmetrically over the cross-section of the reactor

  8. Agglomeration of ash during combustion of peat and biomass in fluidized-bed reactors. Development of image analysis technique based on scanning electron microscopy; Tuhkan muuntuminen leijukerroskaasutuksessa ja -poltossa. Haitallisten hivenmetallien vapautuminen ja alkalien kaeyttaeytyminen

    Energy Technology Data Exchange (ETDEWEB)

    Kauppinen, E. [VTT Chemistry, Espoo (Finland); Arpiainen, V.; Jokiniemi, J. [VTT Energy, Espoo (Finland)] [and others

    1996-12-01

    The objective of the project is to study the behaviour of alkali metals (Na and K) and hazardous trace elements (Sb, As, Be, Cd, Cr, Co, Pb, Mn, Ni, Se and Zn) during fluidized bed combustion and gasification of solid fuels. The areas of interest are the release of elements studied from the bed and the behaviour of gaseous and particle-phase species after the release from the bed. During 1995 combustion and gasification experiments of Polish coal in bubbling bed were carried out with a laboratory scale fluidized bed gasifier in atmospheric pressure. Flue gas samples were drawn from the freeboard of the reactor and cooled quickly using a dilution probe. Ash particle size distributions were determined using low pressure impactors and differential mobility analyser. The morphology of the ash particles was studied with a scanning electron microscope (SEM) and will be further studied with transmission electron microscopy (TEM). The ash matrix elements (Si, Al, Fe, Ca and Mg) and the alkali metals (Na and K) were not significantly vaporized during the combustion process. More than 99 % of each of these elements was found in ash particles larger than 0.4 {mu}m. In Polish coal the alkali metals are bound mainly in silicates. The alkali metals were not released from the silicate minerals during the combustion process. A significant fraction of As, Cd and Pb was vaporized, released as gaseous species from the fuel particle and condensed mainly on the fine ash particles. 20 - 34 % of cadmium was present in fly ash particles smaller than 0.6 {mu}m (during combustion in 950 deg C), whereas only 1 % of the total ash was in this size fraction. All of the hazardous trace elements studied (As, Be, Cd, Co, Cr, Mn and Zn) were enriched in ash size fraction 0.6 - 5 {mu}m. The enrichment of Co, Cr, Mn, Ni, Pb and Sb was more significant during combustion in 950 deg C than in lower temperature (850 deg C)

  9. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    Energy Technology Data Exchange (ETDEWEB)

    Rokkam, Ram [Iowa State Univ., Ames, IA (United States)

    2012-01-01

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  10. Selenate removal in methanogenic and sulfate-reducing upflow anaerobic sludge bed reactors

    NARCIS (Netherlands)

    Lenz, M.; Hullebusch, van E.D.; Hommes, G.; Corvini, P.F.X.; Lens, P.N.L.

    2008-01-01

    This paper evaluates the use of upflow anaerobic sludge bed (UASB) bioreactors (30 degrees C, pH = 7.0) to remove selenium oxyanions from contaminated waters (790 mu g Se L-1) under methanogenic and sulfate-reducing conditions using lactate as electron donor. One UASB reactor received sulfate at

  11. Passive cooling of a fixed bed nuclear reactor

    International Nuclear Information System (INIS)

    Petry, V.J.; Bortoli, A.L. de; Sefidwash, F.

    2005-01-01

    Small nuclear reactors without the need for on-site refuelling have greater simplicity, better compliance with passive safety systems, and are more adequate for countries with small electric grids and limited investment capabilities. Here the passive cooling characteristic of the fixed bed nuclear reactor (FBNR), that is being developed under the International Atomic Energy Agency (IAEA) Coordinated Research Project, is studied. A mathematical model is developed to calculate the temperature distribution in the fuel chamber of the reactor. The results demonstrate the passive cooling of this nuclear reactor concept. (authors)

  12. Experimental study of flow field characteristics on bed configurations in the pebble bed reactor

    International Nuclear Information System (INIS)

    Jia, Xinlong; Gui, Nan; Yang, Xingtuan; Tu, Jiyuan; Jia, Haijun; Jiang, Shengyao

    2017-01-01

    Highlights: • PTV study of flow fields of pebble bed reactor with different configurations are carried out. • Some criteria are proposed to quantify vertical velocity field and flow uniformity. • The effect of different pebble bed configurations is also compared by the proposed criteria. • The displacement thickness is used analogically to analyze flow field characteristics. • The effect of mass flow variation in the stagnated region of the funnel flow is measured. - Abstract: The flow field characteristics are of fundamental importance in the design work of the pebble bed high temperature gas cooled reactor (HTGR). The different effects of bed configurations on the flow characteristics of pebble bed are studied through the PTV (Particle Tracking Velocimetry) experiment. Some criteria, e.g. flow uniformity (σ) and mass flow level (α), are proposed to estimate vertical velocity field and compare the bed configurations. The distribution of the Δθ (angle difference between the individual particle velocity and the velocity vector sum of all particles) is also used to estimate the resultant motion consistency level. Moreover, for each bed configuration, the thickness of displacement is analyzed to measure the effect of the funnel flow zone based on the boundary layer theory. Detailed information shows the quantified characteristics of bed configuration effects on flow uniformity and other characteristics; and the sequence of levels of each estimation criterion is obtained for all bed configurations. In addition, a good design of the pebble bed configuration is suggested and these estimation criteria can be also applied and adopted in testing other geometry designs of pebble bed.

  13. Methanol steam-reforming in a catalytic fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Duesterwald, H G; Hoehlein, B; Kraut, H; Meusinger, J; Peters, R [Research Centre Juelich (KFA) (Germany). Inst. of Energy Process Engineering; Stimming, U [Technische Univ. Muenchen, Garching (Germany). Inst. fuer Festkoerperphysik und Techn. Phys.

    1997-12-01

    Designing an appropriate methanol steam reformer requires detailed knowledge about the processes within such a reactor. Thus, the axial temperature and concentration gradients and catalyst ageing were investigated. It was found that for a fresh catalyst load, the catalyst located in the reactor entrance was most active during the experiment. The activity of this part of the catalyst bed decreased after some time of operation due to ageing. With further operation, the most active zone moved through the catalyst bed. From the results concerning hydrogen production and catalyst degradation, the necessary amount of catalyst for a mobile PEMFC-system can be estimated. (orig.)

  14. Nonlinear dynamics and control of a recycle fixed bed reactor

    DEFF Research Database (Denmark)

    Recke, Bodil; Jørgensen, Sten Bay

    1997-01-01

    The purpose of this paper is twofold. Primarily to describe the dynamic behaviour that can be observed in a fixed bed reactor with recycle of unconverted reactant. Secondly to describe the possibilities of model reduction in order to facilitate control design. Reactant recycle has been shown...... to introduce periodic solution to the fixed bed reactor, a phenomenon which is not seen for the system without the recycle, at least not within the Peclet number range investigated in the present work. The possibility of model reduction by the methods of modal decomposition, and by characteristics...

  15. Thermalhydraulics of flowing particle-bed-type fusion reactor blankets

    International Nuclear Information System (INIS)

    Nietert, R.E.; Abdelk-Khalik, S.I.

    1982-01-01

    An experimental investigation has been conducted to determine the heat transfer characteristics of gravity-flowing particle beds using a special heat transfer loop. Glass microspheres were allowed to flow by gravity at controlled rates through an electrically heated stainless steel tubular test section. Values of the local and average convective heat transfer coefficient as a function of the average bed velocity, particle size and heat flux were determined. Such information is necessary for the design of gravity-flowing particle-bed type fusion reactor-blankets and associated tritium recovery systems. (orig.)

  16. Effect of bed configuration on pebble flow uniformity and stagnation in the pebble bed reactor

    International Nuclear Information System (INIS)

    Gui, Nan; Yang, Xingtuan; Tu, Jiyuan; Jiang, Shengyao

    2014-01-01

    Highlights: • Pebble flow uniformity and stagnation characteristics are very important for HTR-PM. • Arc- and brachistochrone-shaped configuration effects are studied by DEM simulation. • Best bed configurations with uniform flow and no stagnated pebbles are suggested. • Detailed quantified characteristics of bed configuration effects are shown for explanation. - Abstract: Pebble flow uniformity and stagnation characteristics are very important for the design of pebble bed high temperature gas-cooled reactor. Pebble flows inside some specifically designed contraction configurations of pebble bed are studied by discrete element method. The results show the characteristics of stagnation rates, recycling rates, radial distribution of pebble velocity and residence time. It is demonstrated clearly that the bed with a brachistochrone-shaped configuration achieves optimum levels of flow uniformity and recycling rate concentration, and almost no pebbles are stagnated in the bed. Moreover, the optimum choice among the arc-shaped bed configurations is demonstrated too. Detailed information shows the quantified characteristics of bed configuration effects on flow uniformity. In addition, a good design of the pebble bed configuration is suggested

  17. Nonproliferation and safeguard considerations: Pebble Bed reactor fuel cycle evaluation

    International Nuclear Information System (INIS)

    1978-09-01

    Nuclear fuel cycles were evaluated for the Pebble Bed Gas Cooled Reactor under development in the Federal Republic of Germany. The basic fuel cycle specified for the HTR-K and PNP is well qualified and will meet the requirements of these reactors. Twenty alternate fuel cycles are described, including high-conversion cycles, net-breeding cycles, and proliferation-resistant cycles. High-conversion cycles, which have a high probability of being successfully developed, promise a significant improvement in resource utilization. Proliferation-resistant cycles, also with a high probability of successful development, conpare very favorably with those for other types of reactors. Most of the advanced cycles could be adapted to first-generation pebble bed reactors with no significant modifications

  18. High power density reactors based on direct cooled particle beds

    Science.gov (United States)

    Powell, J. R.; Horn, F. L.

    Reactors based on direct cooled High Temperature Gas Cooled Reactor (HTGR) type particle fuel are described. The small diameter particle fuel is packed between concentric porous cylinders to make annular fuel elements, with the inlet coolant gas flowing inwards. Hot exit gas flows out along the central channel of each element. Because of the very large heat transfer area in the packed beds, power densities in particle bed reactors (PBRs) are extremely high resulting in compact, lightweight systems. Coolant exit temperatures are high, because of the ceramic fuel temperature capabilities, and the reactors can be ramped to full power and temperature very rapidly. PBR systems can generate very high burst power levels using open cycle hydrogen coolant, or high continuous powers using closed cycle helium coolant. PBR technology is described and development requirements assessed.

  19. Steam reforming of heptane in a fluidized bed membrane reactor

    Science.gov (United States)

    Rakib, Mohammad A.; Grace, John R.; Lim, C. Jim; Elnashaie, Said S. E. H.

    n-Heptane served as a model compound to study steam reforming of naphtha as an alternative feedstock to natural gas for production of pure hydrogen in a fluidized bed membrane reactor. Selective removal of hydrogen using Pd 77Ag 23 membrane panels shifted the equilibrium-limited reactions to greater conversion of the hydrocarbons and lower yields of methane, an intermediate product. Experiments were conducted with no membranes, with one membrane panel, and with six panels along the height of the reactor to understand the performance improvement due to hydrogen removal in a reactor where catalyst particles were fluidized. Results indicate that a fluidized bed membrane reactor (FBMR) can provide a compact reformer for pure hydrogen production from a liquid hydrocarbon feedstock at moderate temperatures (475-550 °C). Under the experimental conditions investigated, the maximum achieved yield of pure hydrogen was 14.7 moles of pure hydrogen per mole of heptane fed.

  20. DEGRADATION OF AROMATIC COMPOUNDS USING MOVING BED BIOFILM REACTORS

    Directory of Open Access Journals (Sweden)

    B. Ayati, H. Ganjidoust, M. Mir Fattah

    2007-04-01

    Full Text Available For biological treatment of water, there are many different biofilm systems in use. Examples of them are trickling filters, rotating biological contactors, fixed media submerged biofilters, granular media biofilters and fluidized bed reactors. They all have their advantages and disadvantages. Hence, the Moving Bed Biofilm Reactor process was developed in Norway in the late 1980s and early 1990s to adopt the best features of the activated sludge process as well as those of the biofilter processes, without including the worst. Two cylindrical moving bed biofilm reactors were used in this study working in upflow stream conditions. Experiments have been done in aerobic batch flow regime. Laboratory experiments were conducted at room temperature (23–28C and synthetic wastewater comprising a composition of phenol and hydroquinone in each reactor as the main organic constituents, plus balanced nutrients and alkalinity were used to feed the reactor. The ratio of influent to effluent COD was determined at different retention times. The results indicated that the removal efficiency of each selected compound is affected by the detention time. At low phenol and hydroquinone concentration (from 700 to 1000 mg/L maximum removal efficiency (over 80 % was obtained. By further increasing in COD loading rate up to 3000 mg/L, a decrease in COD removal rate was occurred. In the reactor containing pyrogallol in COD of 1500 mg/L, the removal rate decreased to 10 percent because of its toxicity for microorganisms.

  1. Anaerobic treatment of winery wastewater in fixed bed reactors.

    Science.gov (United States)

    Ganesh, Rangaraj; Rajinikanth, Rajagopal; Thanikal, Joseph V; Ramanujam, Ramamoorty Alwar; Torrijos, Michel

    2010-06-01

    The treatment of winery wastewater in three upflow anaerobic fixed-bed reactors (S9, S30 and S40) with low density floating supports of varying size and specific surface area was investigated. A maximum OLR of 42 g/l day with 80 +/- 0.5% removal efficiency was attained in S9, which had supports with the highest specific surface area. It was found that the efficiency of the reactors increased with decrease in size and increase in specific surface area of the support media. Total biomass accumulation in the reactors was also found to vary as a function of specific surface area and size of the support medium. The Stover-Kincannon kinetic model predicted satisfactorily the performance of the reactors. The maximum removal rate constant (U(max)) was 161.3, 99.0 and 77.5 g/l day and the saturation value constant (K(B)) was 162.0, 99.5 and 78.0 g/l day for S9, S30 and S40, respectively. Due to their higher biomass retention potential, the supports used in this study offer great promise as media in anaerobic fixed bed reactors. Anaerobic fixed-bed reactors with these supports can be applied as high-rate systems for the treatment of large volumes of wastewaters typically containing readily biodegradable organics, such as the winery wastewater.

  2. Lagrangian Approach to Study Catalytic Fluidized Bed Reactors

    Science.gov (United States)

    Madi, Hossein; Hossein Madi Team; Marcelo Kaufman Rechulski Collaboration; Christian Ludwig Collaboration; Tilman Schildhauer Collaboration

    2013-03-01

    Lagrangian approach of fluidized bed reactors is a method, which simulates the movement of catalyst particles (caused by the fluidization) by changing the gas composition around them. Application of such an investigation is in the analysis of the state of catalysts and surface reactions under quasi-operando conditions. The hydrodynamics of catalyst particles within a fluidized bed reactor was studied to improve a Lagrangian approach. A fluidized bed methanation employed in the production of Synthetic Natural Gas from wood was chosen as the case study. The Lagrangian perspective was modified and improved to include different particle circulation patterns, which were investigated through this study. Experiments were designed to evaluate the concepts of the model. The results indicate that the setup is able to perform the designed experiments and a good agreement between the simulation and the experimental results were observed. It has been shown that fluidized bed reactors, as opposed to fixed beds, can be used to avoid the deactivation of the methanation catalyst due to carbon deposits. Carbon deposition on the catalysts tested with the Lagrangian approach was investigated by temperature programmed oxidation (TPO) analysis of ex-situ catalyst samples. This investigation was done to identify the effects of particles velocity and their circulation patterns on the amount and type of deposited carbon on the catalyst surface. Ecole Polytechnique Federale de Lausanne(EPFL), Paul Scherrer Institute (PSI)

  3. Parametric study for high conversion pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Teuchert, E.; Ruetten, H. J.

    1975-06-15

    Tables are presented of fuel cycle costs, conversion ratios and accompanying variations in fuel element designs for a 3,00 MWth high conversion pebble bed reactor with initial high enriched uranium/thorium cycle and subsequent recycling of U-233, Pu-239 and Pu-241.

  4. The Performance of Structured Packings in Trickle-Bed Reactors

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, W.P.M. van

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped

  5. Dimensioning of aerated submerged fixed bed biofilm reactors ...

    African Journals Online (AJOL)

    The description of a biofilm mathematical model application for dimensioning an aerated fixed bed biofilm reactor (ASFBBR) for petrochemical wastewater polishing is presented. A simple one-dimensional model of biofilm, developed by P Harremöes, was chosen for this purpose. The model was calibrated and verified ...

  6. Thymol Hydrogenation in Bench Scale Trickle Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Dudas, J.; Hanika, Jiří; Lepuru, J.; Barkhuysen, M.

    2005-01-01

    Roč. 19, č. 3 (2005), s. 255-262 ISSN 0352-9568 Institutional research plan: CEZ:AV0Z40720504 Keywords : thymol hydrogenation * trickle bed reactor * gas-liquid-solid reaction Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 0.632, year: 2005

  7. Trickle Bed Reactor Operation under Forced Liquid Feed Rate Modulation

    Czech Academy of Sciences Publication Activity Database

    Hanika, Jiří; Jiřičný, Vladimír; Karnetová, P.; Kolena, J.; Lederer, J.; Skála, D.; Staněk, Vladimír; Tukač, V.

    2007-01-01

    Roč. 13, č. 4 (2007), s. 192-198 ISSN 1451-9372 R&D Projects: GA MPO(CZ) FT-TA/039 Institutional research plan: CEZ:AV0Z40720504 Keywords : trickle -bed reactor * period * feed rate Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  8. Dicyclopentadiene Hydrogenation in Trickle Bed Reactor under Forced Periodic Control

    Czech Academy of Sciences Publication Activity Database

    Skála, D.; Hanika, Jiří

    2008-01-01

    Roč. 62, č. 2 (2008), s. 215-218 ISSN 1336-7242 R&D Projects: GA MPO(CZ) FT-TA/039 Institutional research plan: CEZ:AV0Z40720504 Keywords : periodic control * trickle -bed reactor * dicyclopentadiene Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  9. Small particle bed reactors: Sensitivity to Brayton cycle parameters

    Science.gov (United States)

    Coiner, John R.; Short, Barry J.

    Relatively simple particle bed reactor (PBR) algorithms were developed for optimizing low power closed Brayton cycle (CBC) systems. These algorithms allow the system designer to understand the relationship among key system parameters as well as the sensitivity of the PBR size and mass (a major system component) to variations in these parameters. Thus, system optimization can be achieved.

  10. Thermal-hydraulic modeling of porous bed reactors

    International Nuclear Information System (INIS)

    Araj, K.J.; Nourbakhsh, H.P.

    1987-01-01

    Optimum design of nuclear reactor core requires an iterative approach between the thermal-hydraulic, neutronic and operational analysis. This paper concentrates on the thermal-hydraulic behavior of a hydrogen cooled, small particle bed reactor (PBR). The PBR core, modeled here, consists of a hexagonal array of fuel elements embedded in a moderator matrix. The fuel elements are annular packed beds of fuel particles held between two porous cylindrical frits. These particles, 500 to 600 μm in diameter, have a uranium carbide core, which is coated by two layers of graphite and an outer coating of zirconium carbide. Coolant flow, radially inward, from the cold frit through the packed bed and hot frit and axially out the channel, formed by the hot frit, to a common plenum. 5 refs., 1 fig., 2 tabs

  11. Study on transient of fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Streck, E.E.

    1988-01-01

    The point kinetic equations for a Fluidized-Bed Nuclear Reactor are solved by the method of Hansen. Due to the time varying nature of the reactor volume, the equations have a non-conventional formulation (moving boundary problem), but the method of solution preserves its asymptotic convergence and efficiency characteristics under this formulation. A one dimensional and linearized thermal hydraulics feedback model was coupled to the point kinetic equations in order to obtain a more realistic representation of the reactor power. The resulting equations are solved by the Euler explicit method. (author)

  12. Pellet bed reactor for multi-modal space power

    International Nuclear Information System (INIS)

    Buden, D.; Williams, K.; Mast, P.; Mims, J.

    1987-01-01

    A review of forthcoming space power needs for both civil and military missions indicates that power requirements will be in the tens of megawatts. The electrical power requirements are envisioned to be twofold: long-duration lower power levels will be needed for station keeping, communications, and/or surveillance; short-duration higher power levels will be required for pulsed power devices. These power characteristics led to the proposal of a multi-modal space power reactor using a pellet bed design. Characteristics desired for such a multimegawatt reactor power source are standby, alert, and pulsed power modes; high-thermal output heat source (approximately 1000 MWt peak power); long lifetime station keeping power (10 to 30 years); high temperature output (1500 K to 1800 K); rapid-burst power transition; high reliability (above 95 percent); and stringent safety standards compliance. The proposed pellet bed reactor is designed to satisfy these characteristics

  13. Operation of Packed-Bed Reactors Studied in Microgravity

    Science.gov (United States)

    Motil, Brian J.; Balakotaiah, Vemuri

    2004-01-01

    The operation of a packed bed reactor (PBR) involves gas and liquid flowing simultaneously through a fixed-bed of solid particles. Depending on the application, the particles can be various shapes and sizes but are generally designed to force the two fluid phases through a tortuous route of narrow channels connecting the interstitial space. The PBR is the most common type of reactor in industry because it provides for intimate contact and high rates of transport between the phases needed to sustain chemical or biological reactions. The packing may also serve as either a catalyst or as a support for growing biological material. Furthermore, this type of reactor is relatively compact and requires minimal power to operate. This makes it an excellent candidate for unit operations in support of long-duration human space activities.

  14. High power density reactors based on direct cooled particle beds

    International Nuclear Information System (INIS)

    Powell, J.R.; Horn, F.L.

    1985-01-01

    Reactors based on direct cooled HTGR type particle fuel are described. The small diameter particle fuel is packed between concentric porous cylinders to make annular fuel elements, with the inlet coolant gas flowing inwards. Hot exit gas flows out long the central channel of each element. Because of the very large heat transfer area in the packed beds, power densities in particle bed reactors (PBR's) are extremely high resulting in compact, lightweight systems. Coolant exit temperatures are high, because of the ceramic fuel temperature capabilities, and the reactors can be ramped to full power and temperature very rapidly. PBR systems can generate very high burst power levels using open cycle hydrogen coolant, or high continuous powers using closed cycle helium coolant. PBR technology is described and development requirements assessed. 12 figs

  15. Pebble Bed Reactor: core physics and fuel cycle analysis

    Energy Technology Data Exchange (ETDEWEB)

    Vondy, D.R.; Worley, B.A.

    1979-10-01

    The Pebble Bed Reactor is a gas-cooled, graphite-moderated high-temperature reactor that is continuously fueled with small spherical fuel elements. The projected performance was studied over a broad range of reactor applicability. Calculations were done for a burner on a throwaway cycle, a converter with recycle, a prebreeder and breeder. The thorium fuel cycle was considered using low, medium (denatured), and highly enriched uranium. The base calculations were carried out for electrical energy generation in a 1200 MW/sub e/ plant. A steady-state, continuous-fueling model was developed and one- and two-dimensional calculations were used to characterize performance. Treating a single point in time effects considerable savings in computer time as opposed to following a long reactor history, permitting evaluation of reactor performance over a broad range of design parameters and operating modes.

  16. Rotating bed reactor for CLC: Bed characteristics dependencies on internal gas mixing

    International Nuclear Information System (INIS)

    Håkonsen, Silje Fosse; Grande, Carlos A.; Blom, Richard

    2014-01-01

    Highlights: • A mathematical model for the rotating CLC reactor has been developed. • The model reflects the gas distribution in the reactor during CLC operation. • Radial dispersion in the rotating bed is the main cause for internal gas mixing. • The model can be used to optimize the reactor design and particle characteristics. - Abstract: A newly designed continuous lab-scale rotating bed reactor for chemical looping combustion using CuO/Al 2 O 3 oxygen carrier spheres and methane as fuel gives around 90% CH 4 conversion and >90% CO 2 capture efficiency based on converted methane at 800 °C. However, from a series of experiments using a broad range of operating conditions potential CO 2 purities only in the range 20–65% were yielded, mostly due to nitrogen slip from the air side of the reactor into the effluent CO 2 stream. A mathematical model was developed intending to understand the air-mixing phenomena. The model clearly reflects the gas slippage tendencies observed when varying the process conditions such as rotation frequency, gas flow and the flow if inert gas in the two sectors dividing the air and fuel side of the reactor. Based on the results, it is believed that significant improvements can be made to reduce gas mixing in future modified and scaled-up reactor versions

  17. Properties Influencing Plasma Discharges in Packed Bed Reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Kushner, Mark J.

    2016-09-01

    Atmospheric pressure dielectric barrier discharges (DBDs) sustained in packed bed reactors (PBRs) are being investigated for CO2 removal and conversion of waste gases into higher value compounds. We report on results of a computational investigation of PBR-DBD properties using the plasma hydrodynamics simulator nonPDPSIM with a comparison to experiments. Dielectric beads (rods in 2D) were inserted between two coplanar electrodes, 1 cm apart filled by humid air. A step-pulse of -30 kV was applied to the top electrode. Material properties of the beads (dielectric constant, secondary emission coefficient) and gas properties (photoionization and photo-absorption cross-sections, temperature) were varied. We found that photoionization plays a critical role in the propagation of the discharge through the PBR, as it serves to seed charges in regions of high electric field. Increasing rates of photo-ionization enable increases in the discharge propagation velocity, ionization rates and production of radicals. A transition between DBD-like and arc-like discharges occurs as the radiation mean free path decreases. Increasing the dielectric constant of the beads increased electric fields in the gas, which translated to increased discharge propagation velocity and charge density until ɛ/ɛ0 100. Secondary electron emission coefficient and gas temperature have minimal impacts on the discharge propagation though the latter did affect the production of reactive species. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  18. Biodenitrification of gaseous diffusion plant aqueous wastes: stirred bed reactor

    International Nuclear Information System (INIS)

    Holland, M.E.

    1980-01-01

    Approximately 30 kilograms of nitrates per day are discarded in the raffinates (acid wastes) of the Portsmouth Gaseous Diffusion Plant's X-705 Uranium Recovery and Decontamination Facility. A biodenitrification process employing continuous-flow, stirred-bed reactors has been successfully used to remove nitrates from similar acid wastes at the Oak Ridge Y-12 Plant. Laboratory studies have been made at Portsmouth to characterize the X-705 raffinates and to test the stirred-bed biodenitrification process on such raffinates. Raffinates which had been previously characterized were pumped through continuous-flow, stirred-bed, laboratory-scale reactors. Tests were conducted over a period of 146 days and involved variations in composition, mixing requirements, and the fate of several metal ions in the raffinates. Tests results show that 20 weight percent nitrates were reduced to a target nitrate effluent concentration of 100 μg/ml with a 99.64 percent efficiency. However, the average denitrification rate achieved was only 33% of that demonstrated with the Y-12 stirred-bed system. These low rates were probably due to the toxic effects of heavy metal ions on the denitrifying bacteria. Also, most of the uranium in the raffinate feed remained in the biomass and calcite, which collected in the reactor. This could cause criticality problems. For these reasons, it was decided not to make use of the stirred-bed bioreactor at Portsmouth. Instead, the biodenitrification installation now planned will use fluidized bed columns whose performance will be the subject of a subsequent report

  19. Researchers solve big mysteries of pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Shams, Afaque; Roelofs, Ferry; Komen, E.M.J. [Nuclear Research and Consultancy Group (NRG), Petten (Netherlands); Baglietto, Emilio [Massachusetts Institute of Technology, Cambridge, MA (United States). Dept. of Nuclear Science and Engineering; Sgro, Titus [CD-adapco, London (United Kingdom). Technical Marketing

    2014-03-15

    The PBR is one type of High Temperature Reactors, which allows high temperature work while preventing the fuel from melting (bringing huge safety margins to the reactor) and high electricity efficiency. The design is also highly scalable; a plant could be designed to be as large or small as needed, and can even be made mobile, allowing it to be used onboard a ship. In a PBR, small particles of nuclear fuel, embedded in a moderating graphite pebble, are dropped into the reactor as needed. At the bottom, the pebbles can be removed simply by opening a small hatch and letting gravity pull them down. To cool the reactor and create electricity, helium gas is pumped through the reactor to pull heat out which is then run through generators. One of the most difficult problems to deal with has been the possible appearance of local temperature hotspots within the pebble bed heating to the point of melting the graphite moderators surrounding the fuel. Obviously, constructing a reactor and experimenting to investigate this possibility is out of the question. Instead, nuclear engineers have been attempting to simulate a PBR with various CFD codes. The thermo-dynamic analysis to simulate realistic conditions in a pebble bed are described and the results are shown. (orig.)

  20. Thermal-hydraulic considerations for particle bed reactors

    Science.gov (United States)

    Benenati, R.; Araj, K. J.; Horn, F.

    In the design of particle bed reactor (PBR) cores, consideration must be given to the gas coolant channels and their configuration. Neutronics analysis provides the relative volume fractions of the component materials, but these must be arranged in such a manner as to allow proper cooling of all components by the gas flow at relatively low pressure drops. The thermal hydraulic aspects of this problem are addressed. A description of the computer model used in the analysis of the steady state condition is also included. Blowdown tests on hot particle bed fuel elements were carried out and are described.

  1. Preliminary Study of 20 MWth Experiment Power Reactor based on Pebble Bed Reactor

    Science.gov (United States)

    Irwanto, Dwi; Permana, Sidik; Pramuditya, Syeilendra

    2017-07-01

    In this study, preliminary design calculations for experimental small power reactor (20 MWt) based on Pebble Bed Reactor (PBR) are performed. PBR technology chosen due to its advantages in neutronic and safety aspects. Several important parameters, such as fissile enrichment, number of fuel passes, burnup and effective multiplication factor are taken into account in the calculation to find neutronic characteristics of the present reactor design.

  2. Fluidized bed reactor for processing particles coated with carbon

    International Nuclear Information System (INIS)

    Marschollek, M.; Simon, W.; Walter, C.

    1978-01-01

    The carbon coating of production returns of these particles first has to be removed before the heavy metal core released can be reprocessed. For reasons of criticality, removal of burnt-up particles downwards must be possible in the fluidized bed reactor even if the reactor diameter is greater than 800 mm, and the material temperatures must not exceed 650 0 C. It consists of an upper cylindrical and a lower conical part, where, according to the invention, the gas distributor heads in the conical part are situated in several planes above one another for the fluidisation and combustion gas and where they are evently distributed over the reactor crossection, so that an even flow profile is achieved over the reactor cross section. (HP) [de

  3. Improved lignin pyrolysis for phenolics production in a bubbling bed reactor--Effect of bed materials.

    Science.gov (United States)

    Li, Dongbing; Briens, Cedric; Berruti, Franco

    2015-01-01

    Lignin pyrolysis was studied in a bubbling fluidized bed reactor equipped with a fractional condensation train, using nitrogen as the fluidization gas. The effect of different bed materials (silica sand, lignin char, activated lignin char, birch bark char, and foamed glass beads) on bio-oil yield and quality was investigated for a pyrolysis temperature of 550 °C. Results how that a bed of activated lignin char is preferable to the commonly used silica sand: pyrolysis of Kraft lignin with a bed of activated lignin char not only provides a pure char product, but also a higher dry bio-oil yield (with a relative increase of 43%), lower pyrolytic water production, and better bio-oil quality. The bio-oil obtained from Kraft lignin pyrolysis with a bed of activated lignin char has a lower average molecular weight, less tar, more phenolics, and less acidity than when sand is used as bed material. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Modeling a Packed Bed Reactor Utilizing the Sabatier Process

    Science.gov (United States)

    Shah, Malay G.; Meier, Anne J.; Hintze, Paul E.

    2017-01-01

    A numerical model is being developed using Python which characterizes the conversion and temperature profiles of a packed bed reactor (PBR) that utilizes the Sabatier process; the reaction produces methane and water from carbon dioxide and hydrogen. While the specific kinetics of the Sabatier reaction on the RuAl2O3 catalyst pellets are unknown, an empirical reaction rate equation1 is used for the overall reaction. As this reaction is highly exothermic, proper thermal control is of the utmost importance to ensure maximum conversion and to avoid reactor runaway. It is therefore necessary to determine what wall temperature profile will ensure safe and efficient operation of the reactor. This wall temperature will be maintained by active thermal controls on the outer surface of the reactor. Two cylindrical PBRs are currently being tested experimentally and will be used for validation of the Python model. They are similar in design except one of them is larger and incorporates a preheat loop by feeding the reactant gas through a pipe along the center of the catalyst bed. The further complexity of adding a preheat pipe to the model to mimic the larger reactor is yet to be implemented and validated; preliminary validation is done using the smaller PBR with no reactant preheating. When mapping experimental values of the wall temperature from the smaller PBR into the Python model, a good approximation of the total conversion and temperature profile has been achieved. A separate CFD model incorporates more complex three-dimensional effects by including the solid catalyst pellets within the domain. The goal is to improve the Python model to the point where the results of other reactor geometry can be reasonably predicted relatively quickly when compared to the much more computationally expensive CFD approach. Once a reactor size is narrowed down using the Python approach, CFD will be used to generate a more thorough prediction of the reactors performance.

  5. Optimization of a packed bed reactor for liquid waste treatment

    International Nuclear Information System (INIS)

    Schmidt, C.A.; Brower, M.J.; Coogan, J.J.; Tennant, R.A.

    1993-01-01

    The authors describe an optimization study of a packed bed reactor (PBR), developed for the treatment of hazardous liquid wastes. The focus is on the destruction of trichloroethylene (TCE). The PBR technology offers many distinct advantages over other processes: simple design, high destruction rates (99.99%), low costs, ambient pressure operation, easy maintenance and scaleability. The cost effectiveness, optimal operating parameters and scaleability were determined. As a second stage of treatment, a silent discharge plasma (SDP) reactor was installed to further treat offgases from the PBR. A primary advantage of this system is closed loop operation, where exhaust gases are continuously recycled and not released into the atmosphere

  6. Cleaning of porous filters in fossilized bed reactors

    International Nuclear Information System (INIS)

    Rodrigo Otero, A.; Sancho Rod, J.

    1965-01-01

    In this report are established the optimum working conditions of a filter cleaning system by blow back. For this purpose it was determined in the first place the blow back air rate necessary to have a good cleaning. The reasons for which it was not possible until now to control the pressure in a fluidized bed calcination reactor are analyzed and a criteria is established to calculate the optimum floe necessary to clean efficiently a porous by this procedures. (Author)

  7. Automated Design and Optimization of Pebble-bed Reactor Cores

    International Nuclear Information System (INIS)

    Gougar, Hans D.; Ougouag, Abderrafi M.; Terry, William K.

    2010-01-01

    We present a conceptual design approach for high-temperature gas-cooled reactors using recirculating pebble-bed cores. The design approach employs PEBBED, a reactor physics code specifically designed to solve for and analyze the asymptotic burnup state of pebble-bed reactors, in conjunction with a genetic algorithm to obtain a core that maximizes a fitness value that is a function of user-specified parameters. The uniqueness of the asymptotic core state and the small number of independent parameters that define it suggest that core geometry and fuel cycle can be efficiently optimized toward a specified objective. PEBBED exploits a novel representation of the distribution of pebbles that enables efficient coupling of the burnup and neutron diffusion solvers. With this method, even complex pebble recirculation schemes can be expressed in terms of a few parameters that are amenable to modern optimization techniques. With PEBBED, the user chooses the type and range of core physics parameters that represent the design space. A set of traits, each with acceptable and preferred values expressed by a simple fitness function, is used to evaluate the candidate reactor cores. The stochastic search algorithm automatically drives the generation of core parameters toward the optimal core as defined by the user. The optimized design can then be modeled and analyzed in greater detail using higher resolution and more computationally demanding tools to confirm the desired characteristics. For this study, the design of pebble-bed high temperature reactor concepts subjected to demanding physical constraints demonstrated the efficacy of the PEBBED algorithm.

  8. Nuclear Safeguards Considerations For The Pebble Bed Modular Reactor (PBMR)

    Energy Technology Data Exchange (ETDEWEB)

    Phillip Casey Durst; David Beddingfield; Brian Boyer; Robert Bean; Michael Collins; Michael Ehinger; David Hanks; David L. Moses; Lee Refalo

    2009-10-01

    High temperature reactors (HTRs) have been considered since the 1940s, and have been constructed and demonstrated in the United Kingdom (Dragon), United States (Peach Bottom and Fort Saint Vrain), Japan (HTTR), Germany (AVR and THTR-300), and have been the subject of conceptual studies in Russia (VGM). The attraction to these reactors is that they can use a variety of reactor fuels, including abundant thorium, which upon reprocessing of the spent fuel can produce fissile U-233. Hence, they could extend the stocks of available uranium, provided the fuel is reprocessed. Another attractive attribute is that HTRs typically operate at a much higher temperature than conventional light water reactors (LWRs), because of the use of pyrolytic carbon and silicon carbide coated (TRISO) fuel particles embedded in ceramic graphite. Rather than simply discharge most of the unused heat from the working fluid in the power plant to the environment, engineers have been designing reactors for 40 years to recover this heat and make it available for district heating or chemical conversion plants. Demonstrating high-temperature nuclear energy conversion was the purpose behind Fort Saint Vrain in the United States, THTR-300 in Germany, HTTR in Japan, and HTR-10 and HTR-PM, being built in China. This resulted in nuclear reactors at least 30% or more thermodynamically efficient than conventional LWRs, especially if the waste heat can be effectively utilized in chemical processing plants. A modern variant of high temperature reactors is the Pebble Bed Modular Reactor (PBMR). Originally developed in the United States and Germany, it is now being redesigned and marketed by the Republic of South Africa and China. The team examined historical high temperature and high temperature gas reactors (HTR and HTGR) and reviewed safeguards considerations for this reactor. The following is a preliminary report on this topic prepared under the ASA-100 Advanced Safeguards Project in support of the NNSA Next

  9. Carbon dioxide hydrate formation in a fixed-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Fan, S.; Lang, X. [South China Univ. of Technology, Guangzhou (China). Key Laboratory of Enhanced Heat Transfer and Energy Conservation; Wang, Y.; Liang, D. [Chinese Academy of Sciences, Guangzhou (China). Guangzhou Inst. of Energy Conversion and Guangzhou Center of Natural Gas Hydrate; Sun, X.; Jurcik, B. [Air Liquide Laboratories, Tsukuba (Japan)

    2008-07-01

    Gas hydrates are thermodynamically stable at high pressures and near the freezing temperature of pure water. Methane hydrates occur naturally in sediments in the deep oceans and permafrost regions and constitute an extensive hydrocarbon reservoir. Carbon dioxide (CO{sub 2}) hydrates are of interest as a medium for marine sequestration of anthropogenic carbon dioxide. Sequestering CO{sub 2} as hydrate has potential advantages over most methods proposed for marine CO{sub 2} sequestration. Because this technique requires a shallower depth of injection when compared with other ocean sequestration methods, the costs of CO{sub 2} hydrate sequestration may be lower. Many studies have successfully used different continuous reactor designs to produce CO{sub 2} hydrates in both laboratory and field settings. This paper discussed a study that involved the design and construction of a fixed-bed reactor for simulation of hydrate formation system. Water, river sands and carbon dioxide were used to simulate the seep kind of hydrate formation. Carbon dioxide gas was distributed as small bubbles to enter from the bottom of the fixed-bed reactor. The paper discussed the experimental data and presented a diagram of the gas hydrate reactor system. The morphology as well as the reaction characters of CO{sub 2} hydrate was presented in detail. The results were discussed in terms of experimental phenomena and hydrate formation rate. A mathematical model was proposed for describing the process. 17 refs., 7 figs.

  10. Tightly Coupled Multiphysics Algorithm for Pebble Bed Reactors

    International Nuclear Information System (INIS)

    Park, HyeongKae; Knoll, Dana; Gaston, Derek; Martineau, Richard

    2010-01-01

    We have developed a tightly coupled multiphysics simulation tool for the pebble-bed reactor (PBR) concept, a type of Very High-Temperature gas-cooled Reactor (VHTR). The simulation tool, PRONGHORN, takes advantages of the Multiphysics Object-Oriented Simulation Environment library, and is capable of solving multidimensional thermal-fluid and neutronics problems implicitly with a Newton-based approach. Expensive Jacobian matrix formation is alleviated via the Jacobian-free Newton-Krylov method, and physics-based preconditioning is applied to minimize Krylov iterations. Motivation for the work is provided via analysis and numerical experiments on simpler multiphysics reactor models. We then provide detail of the physical models and numerical methods in PRONGHORN. Finally, PRONGHORN's algorithmic capability is demonstrated on a number of PBR test cases.

  11. Pellet bed reactor for nuclear thermal propelled vehicles

    International Nuclear Information System (INIS)

    El-Genk, M.; Morley, N.J.; Haloulakos, V.E.

    1991-01-01

    The Pellet Bed Reactor (PeBR) concept is capable of operating at a high power density of up to 3.0 kWt/cu cm and an exit hydrogen gas temperature of 3000 K. The nominal reactor thermal power is 1500 MW and the reactor core is 0.80 m in diameter and 1.3 m high. The nominal PeBR engine generates a thrust of approximately 315 kN at a specific impulse of 1000 s for a mission duration to Mars of 250 days requiring a total firing time of 170 minutes. Because of its low diameter-to-height ratio, PeBR has enough surface area for passive removal of the decay heat from the reactor core. The reactor is equipped with two independent shutdown mechanisms; 8-B4C safety rods and 26 BeO/B4C control drums; each system is capable of operating and scraming the reactor safely. Due to the absence of core internal support structures, the PeBR can be fueled and refueled in orbit using the vacuum of space. These unique features of the PeBR provide for safety during launch, simplicity of handling, deployment, and end-of-life disposal, and vehicle extended lifetime. 11 refs

  12. Electron beam solenoid reactor concept

    International Nuclear Information System (INIS)

    Bailey, V.; Benford, J.; Cooper, R.; Dakin, D.; Ecker, B.; Lopez, O.; Putman, S.; Young, T.S.T.

    1977-01-01

    The electron Beam Heated Solenoid (EBHS) reactor is a linear magnetically confined fusion device in which the bulk or all of the heating is provided by a relativistic electron beam (REB). The high efficiency and established technology of the REB generator and the ability to vary the coupling length make this heating technique compatible with several radial and axial enery loss reduction options including multiple-mirrors, electrostatic and gas end-plug techniques. This paper addresses several of the fundamental technical issues and provides a current evaluation of the concept. The enhanced confinement of the high energy plasma ions due to nonadiabatic scattering in the multiple mirror geometry indicates the possibility of reactors of the 150 to 300 meter length operating at temperatures > 10 keV. A 275 meter EBHS reactor with a plasma Q of 11.3 requiring 33 MJ of beam eneergy is presented

  13. Thermal-hydraulic modeling of porous bed reactors

    International Nuclear Information System (INIS)

    Araj, K.J.; Nourbakhsh, H.P.

    1987-01-01

    Optimum design of nuclear reactor cores requires an iterative approach between the thermal-hydraulic, neutronic, and operational analysis. This paper will concentrate on the thermal-hydraulic behavior of a hydrogen-cooled small particle bed reactor (PBR). The PBR core modeled here consists of a hexagonal array of fuel elements embedded in a moderator matrix. The fuel elements are annular packed beds of fuel particles held between two porous cylindrical frits. These particles, 500 to 600 μm in diameter, have a uranium carbide core, which is coated by two layers of graphite and an outer coating of zirconium carbide. Coolant flows, radially inward, from the cold frit through the packed bed and hot frit and axially out the channel, formed by the hot frit to a common plenum. A fast running one-dimensional lumped-parameter steady-state code (FTHP) was developed to evaluate the effects of design changes in fuel assembly and power distribution. Another objective for the code was to investigate various methods of coolant control to minimize hot channel effects and maximize outlet temperatures

  14. Thermal hydraulic and neutronic interaction in the rotating bed reactor

    International Nuclear Information System (INIS)

    Lee, C.C.

    1986-01-01

    Power transient characteristics in a rotating fluidized bed reactor (RBR) are investigated theoretically. A propellant flow perturbation is assumed to occur in an initially equilibrium state of the core. Transfer functions representing quasi-one-dimensional mutual feedback between thermal hydraulics and neutronics are developed and analyzed in the frequency domain. Neutronic responses are determined by Fermi-age theory for slowing down of fast neutrons and diffusion theory for thermal neutron distribution. Neutron leakage through the exhaust nozzle is accounted for by applying diffuse view factors similar to those applied in radiative heat transfer. The bed expansion behavior is described by a kinematic wave equation derived from the continuity of the gas phase. The drift flux approach is used to determine the yield fractions in the equilibrium bed. Thermal responses of fuel are evaluated by dividing it into several volume-averaged zones to better account for the transient effects over single zone models. Sample calculations are undertaken for the various operation conditions and design parameters of the RBR based on 250 MW/sub t/, 1000 MW/sub t/, and 5000 MW/sub t/ power reactors. The results show that power transients are dependent on the parametric changes of optical thickness and view factors

  15. Gas reactor international cooperative program interim report. Pebble bed reactor fuel cycle evaluation

    International Nuclear Information System (INIS)

    1978-09-01

    Nuclear fuel cycles were evaluated for the Pebble Bed Gas Cooled Reactor under development in the Federal Republic of Germany. The basic fuel cycle specified for the HTR-K and PNP is well qualified and will meet the requirements of these reactors. Twenty alternate fuel cycles are described, including high-conversion cycles, net-breeding cycles, and proliferation-resistant cycles. High-conversion cycles, which have a high probability of being successfully developed, promise a significant improvement in resource utilization. Proliferation-resistant cycles, also with a high probability of successful development, compare very favorably with those for other types of reactors. Most of the advanced cycles could be adapted to first-generation pebble bed reactors with no significant modifications

  16. Pellet bed reactor for nuclear propelled vehicles: Part 1: Reactor technology

    Science.gov (United States)

    El-Genk, Mohamed S.

    1991-01-01

    The pellet bed reactor (PBR) for nuclear propelled vehicles is briefly discussed. Much of the information is given in viewgraph form. Viewgraphs include information on the layout for a Mars mission using a PBR nuclear thermal rocket, the rocket reactor layout, the fuel pellet design, materials compatibility, fuel microspheres, microsphere coating, melting points in quasibinary systems, stress analysis of microspheres, safety features, and advantages of the PBR concept.

  17. Pellet bed reactor for nuclear propelled vehicles: Part 1: Reactor technology

    International Nuclear Information System (INIS)

    El-genk, M.S.

    1991-01-01

    The pellet bed reactor (PBR) for nuclear propelled vehicles is briefly discussed. Much of the information is given in viewgraph form. Viewgraphs include information on the layout for a Mars mission using a PBR nuclear thermal rocket, the rocket reactor layout, the fuel pellet design, materials compatibility, fuel microspheres, microsphere coating, melting points in quasibinary systems, stress analysis of microspheres, safety features, and advantages of the PBR concept

  18. PERKEMBANGAN BIOFILM NITRIFIKASI DI FIXED BED REACTOR PADA SALINITAS TINGGI

    Directory of Open Access Journals (Sweden)

    Sudarno

    2012-03-01

    Full Text Available Development of nitrification biomass that is growing attached on carried material was examined by measuring its ammonium or nitrit oxidation rates. Porous ceramic rings (36 pieces were put into the fixed bed reactor (FBR . The fixed bed reactor that was operated continuously for more than 500 day was continued to be operated at a HRT of 1 day, a DO of above 5 mg L-1 and pH of 8. Ammonia concentration in the feeding was 50 mg NH4+-N L-1. At days 1, 5, 12, 20, 33 and 50, six porous ceramic rings were taken out and then ammonia and nitrite removal rate by biofilm in the ceramic rings was separately measured. The measurement of rates was done in small cylindrical glass reactors with initial concentration of ammonia and nitrite was 10 mg N L-1. Until 50 days of incubation AORs were always higher than NORs. Additionally, ammonia oxidizers attach or grow faster in the porous ceramic material than nitrite oxidizers.

  19. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids

    Directory of Open Access Journals (Sweden)

    Renu Gupta

    2010-10-01

    Full Text Available Hydrodynamic studies of trickle bed reactors (TBRs are essential for the design and prediction of their performance. The hydrodynamic characteristics involving pressure drop and dynamic liquid saturation are greatly affected by the physical properties of the liquids. In the present study experiments have been carried out in a concurrent downflow air - liquid trickle bed reactor to investigate the dynamic liquid saturation and pressure drop for the water (non-foaming and 3% polyethylene glycol and 4% polyethylene glycol foaming liquids in the gas continuous regime (GCF and foaming pulsing regime (FP. In the GCF regime the dynamic liquid saturation was found to increase with increase in liquid flow rate for non-foaming and foaming liquids. While for 3% and 4% polyethylene glycol solutions the severe foaming was observed in the high interaction regime and the regime is referred to as foaming pulsing (FP regime. The decrease in dynamic liquid saturation followed by a sharp rise in the pressure drop was observed during transition from gas GCF to FP regime. However in the FP regime, a dip in the dynamic liquid saturation was observed. The pressure drop for foaming liquids is observed to be manifolds higher compared to non-foaming liquid in the GCF regime. ©2010 BCREC UNDIP. All rights reserved(Received: 16th January 2010, Revised: 10th February 2010, Accepted: 21st Feberuary 2010[How to Cite: R. Gupta, A. Bansal. (2010. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids. Bulletin of Chemical Reaction Engineering & Catalysis, 5 (1: 31-37. doi:10.9767/bcrec.5.1.7127.31-37][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.5.1.7127.31-37 || or local:  http://ejournal.undip.ac.id/index.php/bcrec/article/view/7127][Cited by: Scopus 1 | ] 

  20. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids

    Directory of Open Access Journals (Sweden)

    Ajay Bansal

    2010-10-01

    Full Text Available Hydrodynamic studies of trickle bed reactors (TBRs are essential for the design and prediction of their performance. The hydrodynamic characteristics involving pressure drop and dynamic liquid saturation are greatly affected by the physical properties of the liquids. In the present study experiments have been carried out in a concurrent downflow air - liquid trickle bed reactor to investigate the dynamic liquid saturation and pressure drop for the water (non-foaming and 3% polyethylene glycol and 4% polyethylene glycol foaming liquids in the gas continuous regime (GCF and foaming pulsing regime (FP. In the GCF regime the dynamic liquid saturation was found to increase with increase in liquid flow rate for non-foaming and foaming liquids. While for 3% and 4% polyethylene glycol solutions the severe foaming was observed in the high interaction regime and the regime is referred to as foaming pulsing (FP regime. The decrease in dynamic liquid saturation followed by a sharp rise in the pressure drop was observed during transition from gas GCF to FP regime. However in the FP regime, a dip in the dynamic liquid saturation was observed. The pressure drop for foaming liquids is observed to be manifolds higher compared to non-foaming liquid in the GCF regime. ©2010 BCREC UNDIP. All rights reserved(Received: 16th January 2010, Revised: 10th February 2010, Accepted: 21st Feberuary 2010[How to Cite: R. Gupta, A. Bansal. (2010. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids. Bulletin of Chemical Reaction Engineering & Catalysis, 5 (1: 31-37. doi:10.9767/bcrec.5.1.775.31-37][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.5.1.775.31-37 ][Cited by: Scopus 1 |

  1. Experimental and theoretical investigation of anaerobic fluidized bed biofilm reactors

    Directory of Open Access Journals (Sweden)

    M. Fuentes

    2009-09-01

    Full Text Available This work presents an experimental and theoretical investigation of anaerobic fluidized bed reactors (AFBRs. The bioreactors are modeled as dynamic three-phase systems. Biochemical transformations are assumed to occur only in the fluidized bed zone. The biofilm process model is coupled to the system hydrodynamic model through the biofilm detachment rate; which is assumed to be a first-order function of the energy dissipation parameter and a second order function of biofilm thickness. Non-active biomass is considered to be particulate material subject to hydrolysis. The model includes the anaerobic conversion for complex substrate degradation and kinetic parameters selected from the literature. The experimental set-up consisted of two mesophilic (36±1ºC lab-scale AFBRs (R1 and R2 loaded with sand as inert support for biofilm development. The reactor start-up policy was based on gradual increments in the organic loading rate (OLR, over a four month period. Step-type disturbances were applied on the inlet (glucose and acetic acid substrate concentration (chemical oxygen demand (COD from 0.85 to 2.66 g L-1 and on the feed flow rate (from 3.2 up to 6.0 L d-1 considering the maximum efficiency as the reactor loading rate switching. The predicted and measured responses of the total and soluble COD, volatile fatty acid (VFA concentrations, biogas production rate and pH were investigated. Regarding hydrodynamic and fluidization aspects, variations of the bed expansion due to disturbances in the inlet flow rate and the biofilm growth were measured. As rate coefficients for the biofilm detachment model, empirical values of 3.73⋅10(4 and 0.75⋅10(4 s² kg-1 m-1 for R1 and R2, respectively, were estimated.

  2. Safety aspects of Particle Bed Reactor plutonium burner system

    International Nuclear Information System (INIS)

    Powell, J.R.; Ludewig, H.; Todosow, M.

    1993-01-01

    An assessment is made of the safety aspects peculiar to using the Particle Bed Reactor (PBR) as the burner in a plutonium disposal system. It is found that a combination of the graphitic fuel, high power density possible with the PBR and engineered design features results in an attractive concept. The high power density potentially makes it possible to complete the plutonium burning without requiring reprocessing and remanufacturing fuel. This possibility removes two hazardous steps from a plutonium burning complex. Finally, two backup cooling systems depending on thermo-electric converters and heat pipes act as ultimate heat removal sinks in the event of accident scenarios which result in loss of fuel cooling

  3. Modeling stationary and dynamic pebbles in a pebble bed reactor

    International Nuclear Information System (INIS)

    Zhao, Xiang; Montgomery, Trent; Zhang, Sijun

    2011-01-01

    This paper presents a numerical study of the stationary and dynamic pebbles in a pebble bed reactor (PBR) by means of discrete element method (DEM). At first, the packing structure of stationary pebbles is simulated by filling process until the settling of pebbles into PBR. The packing structural properties are obtained and analyzed. Subsequently, when the outlet of PBR is open during the operational maintenance of PBR, the stationary pebbles start to flow downward and are removed at the bottom of PBR. The dynamic behavior of pebbles is predicted and discussed. Our results indicate the DEM can offer both macroscopic and microscopic information for PBR design calculations and safety assessment. (author)

  4. Critical Issues for Particle-Bed Reactor Fuels

    Science.gov (United States)

    Evans, Robert S.; Husser, Dewayne L.; Jensen, Russell R.; Kerr, John M.

    1994-07-01

    Particle-Bed Reactors (PBRs) potentially offer performance advantages for nuclear thermal propulsion, including very high power densities, thrust-to-weight ratios, and specific impulses. A key factor in achieving all of these is the development of a very-high-temperature fuel. The critical issues for all such PBR fuels are uranium loading, thermomechanical and thermochemical stability, compatibility with contacting materials, fission product retention, manufacturability, and operational tolerance for particle failures. Each issue is discussed with respect to its importance to PBR operation, its status among current fuels, and additional development needs. Mixed-carbide-based fuels are recommended for further development to support high-performance PBRs.

  5. Glucose isomerization in simulated moving bed reactor by Glucose isomerase

    Directory of Open Access Journals (Sweden)

    Eduardo Alberto Borges da Silva

    2006-05-01

    Full Text Available Studies were carried out on the production of high-fructose syrup by Simulated Moving Bed (SMB technology. A mathematical model and numerical methodology were used to predict the behavior and performance of the simulated moving bed reactors and to verify some important aspects for application of this technology in the isomerization process. The developed algorithm used the strategy that considered equivalences between simulated moving bed reactors and true moving bed reactors. The kinetic parameters of the enzymatic reaction were obtained experimentally using discontinuous reactors by the Lineweaver-Burk technique. Mass transfer effects in the reaction conversion using the immobilized enzyme glucose isomerase were investigated. In the SMB reactive system, the operational variable flow rate of feed stream was evaluated to determine its influence on system performance. Results showed that there were some flow rate values at which greater purities could be obtained.Neste trabalho a tecnologia de Leito Móvel Simulado (LMS reativo é aplicada no processo de isomerização da glicose visando à produção de xarope concentrado de frutose. É apresentada a modelagem matemática e uma metodologia numérica para predizer o comportamento e o desempenho de unidades reativas de leito móvel simulado para verificar alguns aspectos importantes para o emprego desta tecnologia no processo de isomerização. O algoritmo desenvolvido utiliza a abordagem que considera as equivalências entre as unidades reativas de leito móvel simulado e leito móvel verdadeiro. Parâmetros cinéticos da reação enzimática são obtidos experimentalmente usando reatores em batelada pela técnica Lineweaver-Burk. Efeitos da transferência de massa na conversão de reação usando a enzima imobilizada glicose isomerase são verificados. No sistema reativo de LMS, a variável operacional vazão da corrente de alimentação é avaliada para conhecer o efeito de sua influência no

  6. Safe design and operation of fluidized-bed reactors: Choice between reactor models

    NARCIS (Netherlands)

    Westerink, E.J.; Westerterp, K.R.

    1990-01-01

    For three different catalytic fluidized bed reactor models, two models presented by Werther and a model presented by van Deemter, the region of safe and unique operation for a chosen reaction system was investigated. Three reaction systems were used: the oxidation of benzene to maleic anhydride, the

  7. Characterization of biofilm in 200W fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Michelle H. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Saurey, Sabrina D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lee, Brady D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Parker, Kent E. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Eisenhauer, Emalee E. R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Cordova, Elsa A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Golovich, Elizabeth C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-09-29

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry

  8. ITER: a technology test bed for a fusion reactor

    International Nuclear Information System (INIS)

    Huguet, M.; Green, B.J.

    1996-01-01

    The ITER Project aims to establish nuclear fusion as an energy source that has potential safety and environmental advantages, and to develop the technologies required for a fusion reactor. ITER is a collaborative project between the European Union, Japan, the Russian Federation and the United States of America. During the current phase of the Project, an R and D programme of about 850 million dollars is underway to develop the technologies required for ITER. This technological effort should culminate in the construction of the components and systems of the ITER machine and its auxiliaries. The main areas of technological development include the first wall and divertor technology, the blanket technology and tritium breeding, superconducting magnet technology, pulsed power technology and remote handling. ITER is a test bed and an essential step to establish the technology of future fusion reactors. Many of the ITER technologies are of potential interest to other fields and their development is expected to benefit the industries involved. (author)

  9. Transformation products of clindamycin in moving bed biofilm reactor (MBBR)

    DEFF Research Database (Denmark)

    Ooi, Gordon Tze Hoong; Escola Casas, Monica; Andersen, Henrik Rasmus

    2017-01-01

    Clindamycin is widely prescribed for its ability to treat a number of common bacterial infections. Thus, clindamycin enters wastewater via human excretion or disposal of unused medication and widespread detection of pharmaceuticals in rivers proves the insufficiency of conventional wastewater...... treatment plants in removing clindamycin. Recently, it has been discovered that attached biofilm reactors, e.g., moving bed biofilm reactors (MBBRs) obtain a higher removal of pharmaceuticals than conventional sludge wastewater treatment plants. Therefore, this study investigated the capability of MBBRs...... process converts clindamycin into the, possibly persistent, products clindamycin sulfoxide and N-desmethyl clindamycin as well as 3 other mono-oxygenated products. Subsequently, the removal kinetics of clindamycin and the formation of the two identified products were investigated in batch experiments...

  10. Pyrolysis of Softwood Carbohydrates in a Fluidized Bed Reactor

    Directory of Open Access Journals (Sweden)

    Dmitry Yu. Murzin

    2008-09-01

    Full Text Available In the present work pyrolysis of pure pine wood and softwood carbohydrates, namely cellulose and galactoglucomannan (the major hemicellulose in coniferous wood, was conducted in a batch mode operated fluidized bed reactor. Temperature ramping (5°C/min was applied to the heating until a reactor temperature of 460 °C was reached. Thereafter the temperature was kept until the release of non-condensable gases stopped. The different raw materials gave significantly different bio-oils. Levoglucosan was the dominant product in the cellulose pyrolysis oil. Acetic acid was found in the highest concentrations in both the galactoglucomannan and in the pine wood pyrolysis oils. Acetic acid is most likely formed by removal of O-acetyl groups from mannose units present in GGM structure.

  11. Pyrolysis of softwood carbohydrates in a fluidized bed reactor.

    Science.gov (United States)

    Aho, Atte; Kumar, Narendra; Eränen, Kari; Holmbom, Bjarne; Hupa, Mikko; Salmi, Tapio; Murzin, Dmitry Yu

    2008-09-01

    In the present work pyrolysis of pure pine wood and softwood carbohydrates, namely cellulose and galactoglucomannan (the major hemicellulose in coniferous wood), was conducted in a batch mode operated fluidized bed reactor. Temperature ramping (5 degrees C/min) was applied to the heating until a reactor temperature of 460 degrees C was reached. Thereafter the temperature was kept until the release of non-condensable gases stopped. The different raw materials gave significantly different bio-oils. Levoglucosan was the dominant product in the cellulose pyrolysis oil. Acetic acid was found in the highest concentrations in both the galactoglucomannan and in the pine wood pyrolysis oils. Acetic acid is most likely formed by removal of O-acetyl groups from mannose units present in GGM structure.

  12. Pebble bed reactor fuel cycle optimization using particle swarm algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Tavron, Barak, E-mail: btavron@bgu.ac.il [Planning, Development and Technology Division, Israel Electric Corporation Ltd., P.O. Box 10, Haifa 31000 (Israel); Shwageraus, Eugene, E-mail: es607@cam.ac.uk [Department of Engineering, University of Cambridge, Trumpington Street, Cambridge CB2 1PZ (United Kingdom)

    2016-10-15

    Highlights: • Particle swarm method has been developed for fuel cycle optimization of PBR reactor. • Results show uranium utilization low sensitivity to fuel and core design parameters. • Multi-zone fuel loading pattern leads to a small improvement in uranium utilization. • Thorium mixes with highly enriched uranium yields the best uranium utilization. - Abstract: Pebble bed reactors (PBR) features, such as robust thermo-mechanical fuel design and on-line continuous fueling, facilitate wide range of fuel cycle alternatives. A range off fuel pebble types, containing different amounts of fertile or fissile fuel material, may be loaded into the reactor core. Several fuel loading zones may be used since radial mixing of the pebbles was shown to be limited. This radial separation suggests the possibility to implement the “seed-blanket” concept for the utilization of fertile fuels such as thorium, and for enhancing reactor fuel utilization. In this study, the particle-swarm meta-heuristic evolutionary optimization method (PSO) has been used to find optimal fuel cycle design which yields the highest natural uranium utilization. The PSO method is known for solving efficiently complex problems with non-linear objective function, continuous or discrete parameters and complex constrains. The VSOP system of codes has been used for PBR fuel utilization calculations and MATLAB script has been used to implement the PSO algorithm. Optimization of PBR natural uranium utilization (NUU) has been carried out for 3000 MWth High Temperature Reactor design (HTR) operating on the Once Trough Then Out (OTTO) fuel management scheme, and for 400 MWth Pebble Bed Modular Reactor (PBMR) operating on the multi-pass (MEDUL) fuel management scheme. Results showed only a modest improvement in the NUU (<5%) over reference designs. Investigation of thorium fuel cases showed that the use of HEU in combination with thorium results in the most favorable reactor performance in terms of

  13. Pebble bed reactor fuel cycle optimization using particle swarm algorithm

    International Nuclear Information System (INIS)

    Tavron, Barak; Shwageraus, Eugene

    2016-01-01

    Highlights: • Particle swarm method has been developed for fuel cycle optimization of PBR reactor. • Results show uranium utilization low sensitivity to fuel and core design parameters. • Multi-zone fuel loading pattern leads to a small improvement in uranium utilization. • Thorium mixes with highly enriched uranium yields the best uranium utilization. - Abstract: Pebble bed reactors (PBR) features, such as robust thermo-mechanical fuel design and on-line continuous fueling, facilitate wide range of fuel cycle alternatives. A range off fuel pebble types, containing different amounts of fertile or fissile fuel material, may be loaded into the reactor core. Several fuel loading zones may be used since radial mixing of the pebbles was shown to be limited. This radial separation suggests the possibility to implement the “seed-blanket” concept for the utilization of fertile fuels such as thorium, and for enhancing reactor fuel utilization. In this study, the particle-swarm meta-heuristic evolutionary optimization method (PSO) has been used to find optimal fuel cycle design which yields the highest natural uranium utilization. The PSO method is known for solving efficiently complex problems with non-linear objective function, continuous or discrete parameters and complex constrains. The VSOP system of codes has been used for PBR fuel utilization calculations and MATLAB script has been used to implement the PSO algorithm. Optimization of PBR natural uranium utilization (NUU) has been carried out for 3000 MWth High Temperature Reactor design (HTR) operating on the Once Trough Then Out (OTTO) fuel management scheme, and for 400 MWth Pebble Bed Modular Reactor (PBMR) operating on the multi-pass (MEDUL) fuel management scheme. Results showed only a modest improvement in the NUU (<5%) over reference designs. Investigation of thorium fuel cases showed that the use of HEU in combination with thorium results in the most favorable reactor performance in terms of

  14. Studies on air ingress for pebble bed reactors

    International Nuclear Information System (INIS)

    Moore, R.L.; Oh, C.H.; Merrill, B.J.; Petti, D.A.

    2002-01-01

    A loss-of-coolant accident (LOCA) has been considered a critical event for helium-cooled pebbled bed reactors. Following helium depressurization, it is anticipated that unless countermeasures are taken air will enter the core through the break and then by molecular diffusion and ultimately by natural convection leading to oxidation of the in-core graphite structure and graphite pebbles. Thus, without any mitigating features a LOCA will lead to an air ingress event. The INEEL is studying such an event with two well-respected light water reactor transient response codes: RELAP5/ATHENA and MELCOR. To study the degree of graphite oxidation occurring due to an air ingress event, a MELCOR model of a reference pebble bed design was constructed. A modified version of MELCOR developed at INEEL, which includes graphite oxidation capabilities, and molecular diffusion of air into helium was used for these calculations. Results show that the lower reflector graphite consumes all of the oxygen before reaching the core. The results also show a long time delay between the time that the depressurization phase of the accident is over and the time that natural circulation air through the core occurs. (author)

  15. Coal-char combustion in a fluidised bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Mehrotra, S.P.; Pande, M. [Indian Institute of Technolgy, Kanpur (India)

    2001-12-01

    Combustion of bituminous coal chars ranging from 0.8 mm to 1.8 mm has been studied in a fluidised bed reactor at temperatures ranging from 500 to 850{sup o}C. The fluidised bed consists of inert sand particles of average size of 0.5 mm and reactive coal char particles. A heat balance has been worked out to calculate the rate of combustion of char from measured incremental changes in the bed temperature during combustion. Investigations on partially burnt particles suggest that the ash layer which builds up around the burning core of char particles is non-flaking and the particles burn in a shrinking core manner. Analysis of rate data indicates that the rate of combustion is controlled by chemical reaction kinetics, though diffusion of oxygen through the bundary layer begins to influence the overall reaction kinetics at higher temperatures. The burnt out time varies linearly with particle size. Activation energy for the chemical reaction control regime is found to be around 68 kJ/mole.

  16. Improving hydrolysis of food waste in a leach bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Browne, James D.; Allen, Eoin; Murphy, Jerry D., E-mail: jerry.murphy@ucc.ie

    2013-11-15

    Highlights: • This paper assesses leaching of food waste in a two phase digestion system. • Leaching is assessed with and without an upflow anaerobic sludge blanket (UASB). • Without the UASB, low pH reduces hydrolysis, while increased flows increase leaching. • Inclusion of the UASB increases pH to optimal levels and greatly improves leaching. • The optimal conditions are suggested as low flow with connection to the UASB. - Abstract: This paper examines the rate of degradation of food waste in a leach bed reactor (LBR) under four different operating conditions. The effects of leachate recirculation at a low and high flow rate are examined with and without connection to an upflow anaerobic sludge blanket (UASB). Two dilution rates of the effective volume of the leach bed reactors were investigated: 1 and 6 dilutions per LBR per day. The increase in dilution rate from 1 to 6 improved the destruction of volatile solids without connection to the UASB. However connection to the UASB greatly improved the destruction of volatile solids (by almost 60%) at the low recirculation rate of 1 dilution per day. The increase in volatile solids destruction with connection to the UASB was attributed to an increase in leachate pH and buffering capacity provided by recirculated effluent from the UASB to the leach beds. The destruction of volatile solids for both the low and high dilution rates was similar with connection to the UASB, giving 82% and 88% volatile solids destruction respectively. This suggests that the most efficient leaching condition is 1 dilution per day with connection to the UASB.

  17. Improving hydrolysis of food waste in a leach bed reactor

    International Nuclear Information System (INIS)

    Browne, James D.; Allen, Eoin; Murphy, Jerry D.

    2013-01-01

    Highlights: • This paper assesses leaching of food waste in a two phase digestion system. • Leaching is assessed with and without an upflow anaerobic sludge blanket (UASB). • Without the UASB, low pH reduces hydrolysis, while increased flows increase leaching. • Inclusion of the UASB increases pH to optimal levels and greatly improves leaching. • The optimal conditions are suggested as low flow with connection to the UASB. - Abstract: This paper examines the rate of degradation of food waste in a leach bed reactor (LBR) under four different operating conditions. The effects of leachate recirculation at a low and high flow rate are examined with and without connection to an upflow anaerobic sludge blanket (UASB). Two dilution rates of the effective volume of the leach bed reactors were investigated: 1 and 6 dilutions per LBR per day. The increase in dilution rate from 1 to 6 improved the destruction of volatile solids without connection to the UASB. However connection to the UASB greatly improved the destruction of volatile solids (by almost 60%) at the low recirculation rate of 1 dilution per day. The increase in volatile solids destruction with connection to the UASB was attributed to an increase in leachate pH and buffering capacity provided by recirculated effluent from the UASB to the leach beds. The destruction of volatile solids for both the low and high dilution rates was similar with connection to the UASB, giving 82% and 88% volatile solids destruction respectively. This suggests that the most efficient leaching condition is 1 dilution per day with connection to the UASB

  18. State of the art of the fluidized bed nuclear reactor concept

    International Nuclear Information System (INIS)

    Sefidvash, F.; Vilhena, M.T.M.B. de; Streck, E.; Borges, V.; Johansson, M.

    1987-01-01

    A small and simple nuclear reactors with inherent safety using the fluidized bed concept is under research and study. In this paper a brief study neutronics and thermal hydraulics of this reactor concept is presented. (Author) [pt

  19. Preliminary Neutronic Design of High Burnup OTTO Cycle Pebble Bed Reactor

    OpenAIRE

    Setiadipura, T; Irwanto, D; Zuhair, Zuhair

    2015-01-01

    The pebble bed type High Temperature Gas-cooled Reactor (HTGR) is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR) which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO) cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor ...

  20. Fluidized bed coupled rotary reactor for nanoparticles coating via atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Chen-Long; Liu, Xiao; Chen, Rong, E-mail: rongchen@mail.hust.edu.cn, E-mail: bshan@mail.hust.edu.cn [State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei 430074 (China); Shan, Bin, E-mail: rongchen@mail.hust.edu.cn, E-mail: bshan@mail.hust.edu.cn [State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei 430074 (China)

    2015-07-15

    A fluidized bed coupled rotary reactor has been designed for coating on nanoparticles (NPs) via atomic layer deposition. It consists of five major parts: reaction chamber, dosing and fluidizing section, pumping section, rotary manipulator components, as well as a double-layer cartridge for the storage of particles. In the deposition procedure, continuous fluidization of particles enlarges and homogenizes the void fraction in the particle bed, while rotation enhances the gas-solid interactions to stabilize fluidization. The particle cartridge presented here enables both the fluidization and rotation acting on the particle bed, demonstrated by the analysis of pressure drop. Moreover, enlarged interstitials and intense gas–solid contact under sufficient fluidizing velocity and proper rotation speed facilitate the precursor delivery throughout the particle bed and consequently provide a fast coating process. The cartridge can ensure precursors flowing through the particle bed exclusively to achieve high utilization without static exposure operation. By optimizing superficial gas velocities and rotation speeds, minimum pulse time for complete coating has been shortened in experiment, and in situ mass spectrometry showed the precursor usage can reach 90%. Inductively coupled plasma-optical emission spectroscopy results suggested a saturated growth of nanoscale Al{sub 2}O{sub 3} films on spherical SiO{sub 2} NPs. Finally, the uniformity and composition of the shells were characterized by high angle annular dark field-transmission electron microscopy and energy dispersive X-ray spectroscopy.

  1. Semi-dry flue gas desulfurization using Ca(OH)2 in a fluidized bed reactor with bed materials

    International Nuclear Information System (INIS)

    Park, Young Oak; Roh, Hak Jae; Oh, Chang Sup; Kim, Yong Ha

    2010-01-01

    The main objective of present work is to reduce sulfur dioxide emission from power plant for the environment protection. The fluidized bed (FB) was used as the reactor with bed materials in a new semi-dry flue gas desulfurization (FGD) process to achieve high desulfurization efficiency (>98%). Fine powder of Ca(OH) 2 as sorbent and water were continuously fed separately to the bed reactor where bed materials (2 mm glass beads) were fluidized vigorously with flue gas (flow 720 Nm 3 / hr) using bench scale plant of stainless steel column. We have investigated different effects of water injection flow rate, Ca/ S molar ratio and weight of bed materials on SO 2 removal. The increments in the Ca/ S molar ratio and water injection flow rate have been resulted higher desulfurization efficiency with certain disadvantages such as higher sorbent cost and lower temperature of the treated flue gas, respectively. (author)

  2. Risk-informed design of a pebble bed gas reactor

    International Nuclear Information System (INIS)

    Ritterbusch, Stanley; Dimitrijevic, Vesna; Simic Zdenko; Savkina Marina

    2003-01-01

    One of the major challenges to the successful deployment of new nuclear plants in the United States is the regulatory process, which is largely based on water-reactor design technology and operating experience. While ongoing and expected efforts to license new LWR designs are based primarily on current regulations, guidance, and past experience, the pre-application review of the gas-cooled Pebble Bed Modular Reactor (PBMR) has shown that efforts are being made to provide additional 'risk-informed' improvements to the licensing process. These improvements are aimed at resolving new design and regulatory issues using a plant-wide integrated evaluation method - state-of-the-art Probabilistic Risk Assessment - which addresses all significant design features and operating modes. The integrated PRA evaluation is supported by the usual deterministic design analyses, engineering judgments, and margins added to address uncertainties (i.e., defense-in-depth). The work performed for this paper was completed as part of the United States Department of Energy's Nuclear Energy Research Initiative. The purpose of this particular project was to develop the methods for a new 'highly risk-informed' design and regulatory process. In this work. PRA techniques were applied in order to provide an integrated and systematic analysis of the plant design, to quantify uncertainties and explicitly account for defense-in-depth features. This work concentrates on the application of the risk-informed principles to a new plant design such as the PBMR. The implementation example completed for this project included specification of the design configuration, use of the PRA to evaluate the design, and iterations to identify design changes that improve the overall level of safety and system reliability. This paper summarizes the new 'highly risk-informed' design process, the design of the PBMR, and the results obtained. These results, consistent with the known inherent safety features of a pebble-bed

  3. Mathematical modeling of a three-phase trickle bed reactor

    Directory of Open Access Journals (Sweden)

    J. D. Silva

    2012-09-01

    Full Text Available The transient behavior in a three-phase trickle bed reactor system (N2/H2O-KCl/activated carbon, 298 K, 1.01 bar was evaluated using a dynamic tracer method. The system operated with liquid and gas phases flowing downward with constant gas flow Q G = 2.50 x 10-6 m³ s-1 and the liquid phase flow (Q L varying in the range from 4.25x10-6 m³ s-1 to 0.50x10-6 m³ s-1. The evolution of the KCl concentration in the aqueous liquid phase was measured at the outlet of the reactor in response to the concentration increase at reactor inlet. A mathematical model was formulated and the solutions of the equations fitted to the measured tracer concentrations. The order of magnitude of the axial dispersion, liquid-solid mass transfer and partial wetting efficiency coefficients were estimated based on a numerical optimization procedure where the initial values of these coefficients, obtained by empirical correlations, were modified by comparing experimental and calculated tracer concentrations. The final optimized values of the coefficients were calculated by the minimization of a quadratic objective function. Three correlations were proposed to estimate the parameters values under the conditions employed. By comparing experimental and predicted tracer concentration step evolutions under different operating conditions the model was validated.

  4. Power Peaking Effect of OTTO Fuel Scheme Pebble Bed Reactor

    Science.gov (United States)

    Setiadipura, T.; Suwoto; Zuhair; Bakhri, S.; Sunaryo, G. R.

    2018-02-01

    Pebble Bed Reactor (PBR) type of Hight Temperature Gas-cooled Reactor (HTGR) is a very interesting nuclear reactor design to fulfill the growing electricity and heat demand with a superior passive safety features. Effort to introduce the PBR design to the market can be strengthen by simplifying its system with the Once-through-then-out (OTTO) cycle PBR in which the pebble fuel only pass the core once. Important challenge in the OTTO fuel scheme is the power peaking effect which limit the maximum nominal power or burnup of the design. Parametric survey is perform in this study to investigate the contribution of different design parameters to power peaking effect of OTTO cycle PBR. PEBBED code is utilized in this study to perform the equilibrium PBR core analysis for different design parameter and fuel scheme. The parameters include its core diameter, height-per-diameter (H/D), power density, and core nominal power. Results of this study show that diameter and H/D effectsare stronger compare to the power density and nominal core power. Results of this study might become an importance guidance for design optimization of OTTO fuel scheme PBR.

  5. Gas Reactor International Cooperative Program. Interim report. Safety and licensing evaluaion of German Pebble Bed Reactor concepts

    International Nuclear Information System (INIS)

    1978-09-01

    The Pebble Bed Gas Cooled Reactor, as developed in the Federal Republic of Germany, was reviewed from a United States Safety and Licensing perspective. The primary concepts considered were the steam cycle electric generating pebble bed (HTR-K) and the process heat pebble bed (PNP), although generic consideration of the direct cycle gas turbine pebble bed (HHT) was included. The study examines potential U.S. licensing issues and offers some suggestions as to required development areas

  6. Celebrating 40 years anaerobic sludge bed reactors for industrial wastewater treatment

    NARCIS (Netherlands)

    Van Lier, J.B.; Van der Zee, F.P.; Frijters, C.T.M.J.; Ersahin, M.E.

    2015-01-01

    In the last 40 years, anaerobic sludge bed reactor technology evolved from localized lab-scale trials to worldwide successful implementations at a variety of industries. High-rate sludge bed reactors are characterized by a very small foot print and high applicable volumetric loading rates. Best

  7. Localization of the hot spots in a pebble bed reactor

    International Nuclear Information System (INIS)

    Chen, Leisheng; Lee, Wooram; Lee, Jaeyoung

    2016-01-01

    The pebble bed reactor (PBR) is a candidate reactor type for the very high temperature reactor (VHTR), which is one of the Generation-IV reactor types. The HTGR design concept exhibits excellent safety features due to the low power density and the large amount of graphite present in the core which gives a large thermal inertia in an accident such as loss of coolant. The conclusions are made and may contribute to a better design of a PBR core and a closer inspection of the local hot spots to avoid destruction of pebbles from happening. Thermal field of a PBR core is investigated in this study. Specifically, experiments on measuring the pebbles' surface temperature are performed. It is found that the upper pebble has an overall higher temperature profile than the other pebbles and the stagnation zone under does not increase its surface's temperature. In addition, the temperature profile of the side pebble shows a concave form and it keeps decreasing from the contact point to the vertex in the lower pebble. Lastly, the maximum temperature difference among these points is 5.83 deg. C. These findings above are validated by CFX simulations under two different turbulence models (k-e, SST) and two contact areas (diameter of 6mm and 3.5mm). By contrasting the temperature variation trends of all simulation cases, it is concluded that SST turbulence model with 20% intensity shows a better agreement with the experiment result, nevertheless, slightly deviation is also found in terms of total temperature difference and the peak appears in position 17-19 in experiments

  8. Localization of the hot spots in a pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Leisheng; Lee, Wooram; Lee, Jaeyoung [Handong Global University, Pohang (Korea, Republic of)

    2016-05-15

    The pebble bed reactor (PBR) is a candidate reactor type for the very high temperature reactor (VHTR), which is one of the Generation-IV reactor types. The HTGR design concept exhibits excellent safety features due to the low power density and the large amount of graphite present in the core which gives a large thermal inertia in an accident such as loss of coolant. The conclusions are made and may contribute to a better design of a PBR core and a closer inspection of the local hot spots to avoid destruction of pebbles from happening. Thermal field of a PBR core is investigated in this study. Specifically, experiments on measuring the pebbles' surface temperature are performed. It is found that the upper pebble has an overall higher temperature profile than the other pebbles and the stagnation zone under does not increase its surface's temperature. In addition, the temperature profile of the side pebble shows a concave form and it keeps decreasing from the contact point to the vertex in the lower pebble. Lastly, the maximum temperature difference among these points is 5.83 deg. C. These findings above are validated by CFX simulations under two different turbulence models (k-e, SST) and two contact areas (diameter of 6mm and 3.5mm). By contrasting the temperature variation trends of all simulation cases, it is concluded that SST turbulence model with 20% intensity shows a better agreement with the experiment result, nevertheless, slightly deviation is also found in terms of total temperature difference and the peak appears in position 17-19 in experiments.

  9. Spectral zone selection methodology for pebble bed reactors

    International Nuclear Information System (INIS)

    Mphahlele, Ramatsemela; Ougouag, Abderrafi M.; Ivanov, Kostadin N.; Gougar, Hans D.

    2011-01-01

    A methodology is developed for determining boundaries of spectral zones for pebble bed reactors. A spectral zone is defined as a region made up of a number of nodes whose characteristics are collectively similar and that are assigned the same few-group diffusion constants. The spectral zones are selected in such a manner that the difference (error) between the reference transport solution and the diffusion code solution takes a minimum value. This is achieved by choosing spectral zones through optimally minimizing this error. The objective function for the optimization algorithm is the total reaction rate error, which is defined as the sum of the leakage, absorption and fission reaction rates errors in each zone. The selection of these spectral zones is such that the core calculation results based on diffusion theory are within an acceptable tolerance as compared to a proper transport reference solution. Through this work, a consistent approach for identifying spectral zones that yield more accurate diffusion results is introduced.

  10. Pebble bed reactor with one-zone core

    International Nuclear Information System (INIS)

    Mueller-Frank, U.; Lohnert, G.

    1977-01-01

    The claim deals with measures to differentiate the flow rate and to remove spherical fuel elements in the core of a pebble bed reactor. Hence the vertical rate of the fuel elements in the border region is for example twice as much as in the centre. A central funnel-shaped outlet on the floor of the core container over which a conical body is placed with its peak pointing upwards, or also the forming of several outlets can be used to adjust to a certain exit rate for the fuel elements. The main target of the invention is a radially extensively constant coolant outlet temperature at the outlet of the core which determines the effectiveness of the connected heat exchanger and thus contributes to economy. (UA) [de

  11. Modeling stationary and moving pebbles in a pebble bed reactor

    International Nuclear Information System (INIS)

    Zhao, Xiang; Montgomery, Trent; Zhang, Sijun

    2015-01-01

    Highlights: • The stationary and moving pebbles in a PBR are numerically studied by DEM. • The packing structure of stationary pebbles is simulated by a filling process. • The packing structural properties are obtained and analyzed. • The dynamic behavior of pebbles is predicted and discussed. - Abstract: This paper presents a numerical study of the stationary and moving pebbles in a pebble bed reactor (PBR) by means of discrete element method (DEM). The packing structure of stationary pebbles is simulated by a filling process that terminates with the settling of the pebbles into a PBR. The packing structural properties are obtained and analyzed. Subsequently, when the outlet of the PBR is opened during the operation of the PBR, the stationary pebbles start to flow downward and are removed at the bottom of the PBR. The dynamic behavior of pebbles is predicted and discussed. Our results indicate the DEM can offer both macroscopic and microscopic information for PBR design calculations and safety assessment

  12. Continuous thermophilic biohydrogen production in packed bed reactor

    International Nuclear Information System (INIS)

    Roy, Shantonu; Vishnuvardhan, M.; Das, Debabrata

    2014-01-01

    Highlights: • Continuous H 2 production in whole cell immobilized system was compared with CSTR. • Suitability of environment friendly support matrix for immobilization of whole cells was explored. • Pack bed reactor showed higher stability as compared to CSTR at lower HRTs. • Flow cytometry study showed the influence of recycle ratio on viability of cells. • Novel approach to find out the effect of NADH/NAD + ratio during H 2 production. - Abstract: The present research work deals with the performance of packed bed reactor for continuous H 2 production using cane molasses as a carbon source. Maximum H 2 production rate of 1.7 L L −1 h −1 was observed at a dilution rate and recycle ratio of 0.8 h −1 and 0.6, respectively which was corresponding to the lowest NADH/NAD + ratio. This suggests that the utilization of NADH pool for H 2 and metabolite production might lead to decrement in NADH/NAD + ratio. Thus NADH/NAD + ratio show inverse relation with hydrogen production. The substrate degradation kinetics was investigated as a function of flow rate considering the external film diffusion model. At a flow rate of 245 mL h −1 , the contribution of external film mass transfer coefficient and first order substrate degradation constant were 55.4% and 44.6% respectively. Recycle ratio of 0.6 improved the hydrogen production rates by 9%. The viable cell count was directly proportional to the recycle ratio (within the range 0.1–0.6). Taguchi design showed the significant influence of the feed pH on continuous H 2 production followed by dilution rate and recycle ratio. Thus environmentally friendly and cheaper solid matrix like coconut coir could be efficiently used for thermophilic continuous hydrogen production

  13. Thermofluid effect on energy storage in fluidized bed reactor

    Science.gov (United States)

    Mahfoudi, Nadjiba; El Ganaoui, Mohammed; Moummi, Abdelhafid

    2016-05-01

    The development of innovative systems of heat storage is imperative to improve the efficiency of the existing systems used in the thermal solar energy applications. Several techniques were developed and realized in this context. The technology of the sand fluidized bed (sandTES) offers a promising alternative to the current state-of-the-art of the heat storage systems, such as fixed bed using a storage materials, as sand, ceramic, and stones, etc. Indeed, the use of the fluidization technique allows an effective heat transfer to the solid particles. With the sand, an important capacity of storage is obtained by an economic and ecological material [N. Mahfoudi, A. Moummi, M. El Ganaoui, Appl. Mech. Mater. 621, 214 (2014); N. Mahfoudi, A. Khachkouch, A. Moummi B. Benhaoua, M. El Ganaoui, Mech. Ind. 16, 411 (2015); N. Mahfoudi, A. Moummi, M. El Ganaoui, F. Mnasri, K.M. Aboudou, 3e Colloque internationale Francophone d"énergétique et mécanique, Comores, 2014, p. 91]. This paper presents a CFD simulation of the hydrodynamics and the thermal transient behavior of a fluidized bed reactor of sand, to determine the characteristics of storage. The simulation shows a symmetry breaking that occurs and gave way to chaotic transient generation of bubble formation after 3 s. Furthermore, the predicted average temperature of the solid phase (sand) increases gradually versus the time with a gain of 1 °C in an interval of 10 s. Contribution to the topical issue "Materials for Energy Harvesting, Conversion and Storage (ICOME 2015) - Elected submissions", edited by Jean-Michel Nunzi, Rachid Bennacer and Mohammed El Ganaoui

  14. Pebble bed blanket design for deuterium burning tandem mirror reactors

    International Nuclear Information System (INIS)

    Grotz, S.P.; Dhir, V.K.

    1983-01-01

    The UCLA tandem mirror reactor, SATYR, was developed around the capability of tandem mirrors with thermal barriers to burn deuterium at reasonable efficiency levels. The pebble bed concept has been incorporated into our blanket design for the following reasons: 1) Large area-to-volume ratio for purposes of heat removal; 2) Large volume of structure for high thermal capacity thus increasing the safety margin during off-normal incidents; 3) Relatively inexpensive manufacturing costs because of large acceptable tolerances and lack of exotic materials (i.e., lithium). A simplified stress analysis of the blanket module was performed to optimize and simplify the design. The pre-specified stress intensity limitations used were based upon a 30-year predicted lifetime for each module. Along with stress analysis of the vessel a detailed thermal hydraulic analysis of the pebble bed has been completed. Parameters affecting the pebble bed design are fluidization velocity, pressure drop, heat transfer coefficient, thermally induced stress in the spheres and spatial variation of the power density. Although reasonable gross thermal efficiencies of the 2 designs has been achieved (28% for H 2 O and 39% for He) the high net recirculating power fraction for heating and neutral beams results in relatively low net plant efficiencies (21% and 27%). The results show that a blanket can be designed with good thermal efficiency and a relative-ly simple configuration. However, application of this concept to the high Q deuterium-tritium fuel cycle would have difficulties resulting from the need for continuous removal of the tritium. (orig./HP)

  15. Advanced modularity design for the MIT pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kadak, Andrew C. [Department of Nuclear Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, 24-202 Cambridge, MA 02139-4307 (United States)]. E-mail: kadak@mit.edu; Berte, Marc V. [Department of Nuclear Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, 24-202 Cambridge, MA 02139-4307 (United States)]. E-mail: mvberte@yahoo.com

    2006-03-15

    The future of all reactors will depend on whether they can be economically built and operated. One of the major impediments to new nuclear construction is the capital cost due in large part to the length of construction time and complexity of the plant. Pebble bed reactors offer the opportunity to reduce the complexity of the plant because the number of safety systems required is significantly reduced due to the inherent safety of the technology. However, because of its small size, the capital cost per kilowatt is likely to be large if traditional construction approaches are followed. This strongly suggests the need for innovative construction concepts to reduce the construction time and cost. MIT has proposed a modularity approach in which the plant is pre-built in space-frame type modules which are built in factories. These space frames would contain all the equipment contained in a given volume. Once equipment in the space frame is installed, the space frame would then be shipped to the site and assembled 'lego-style.' Studies presently underway have demonstrated the feasibility of the concept. Thermal stress analysis has been performed and an integrated design with the space frames has been developed. It is expected that this modularity approach will significantly shorten construction time and expense. This paper proposes a concept for further development, not a final design for the entire plant.

  16. Advanced modularity design for the MIT pebble bed reactor

    International Nuclear Information System (INIS)

    Kadak, Andrew C.; Berte, Marc V.

    2006-01-01

    The future of all reactors will depend on whether they can be economically built and operated. One of the major impediments to new nuclear construction is the capital cost due in large part to the length of construction time and complexity of the plant. Pebble bed reactors offer the opportunity to reduce the complexity of the plant because the number of safety systems required is significantly reduced due to the inherent safety of the technology. However, because of its small size, the capital cost per kilowatt is likely to be large if traditional construction approaches are followed. This strongly suggests the need for innovative construction concepts to reduce the construction time and cost. MIT has proposed a modularity approach in which the plant is pre-built in space-frame type modules which are built in factories. These space frames would contain all the equipment contained in a given volume. Once equipment in the space frame is installed, the space frame would then be shipped to the site and assembled 'lego-style.' Studies presently underway have demonstrated the feasibility of the concept. Thermal stress analysis has been performed and an integrated design with the space frames has been developed. It is expected that this modularity approach will significantly shorten construction time and expense. This paper proposes a concept for further development, not a final design for the entire plant

  17. Transmutation of plutonium in pebble bed type high temperature reactors

    International Nuclear Information System (INIS)

    Bende, E.E.

    1997-01-01

    The pebble bed type High Temperature Reactor (HTR) has been studied as a uranium-free burner of reactor grade plutonium. In a parametric study, the plutonium loading per pebble as well as the type and size of the coated particles (CPs) have been varied to determine the plutonium consumption, the final plutonium burnup, the k ∞ and the temperature coefficients as a function of burnup. The plutonium loading per pebble is bounded between 1 and 3 gr Pu per pebble. The upper limit is imposed by the maximal allowable fast fluence for the CPs. A higher plutonium loading requires a longer irradiation time to reach a desired burnup, so that the CPs are exposed to a higher fast fluence. The lower limit is determined by the temperature coefficients, which become less negative with increasing moderator-actinide ratio. A burnup of about 600 MWd/kgHM can be reached. With the HTR's high efficiency of 40%, a plutonium supply of 1520 kg/GW e a is achieved. The discharges of plutonium and minor actinides are then 450 and 110 kg/GW e a, respectively. (author)

  18. Powder bed charging during electron-beam additive manufacturing

    International Nuclear Information System (INIS)

    Cordero, Zachary C.; Meyer, Harry M.; Nandwana, Peeyush; Dehoff, Ryan R.

    2017-01-01

    Electrons injected into the build envelope during powder bed electron-beam additive manufacturing can accumulate on the irradiated particles and cause them to repel each other. Under certain conditions, these electrostatic forces can grow so large that they drive the particles out of the build envelope in a process known as “smoking”. In the present work, we investigate the causes of powder bed charging and smoking during electron-beam additive manufacturing. In the first part of the paper, we characterize the surface chemistry of a common feedstock material—gas-atomized Ti-6Al-4V powder—and find that a thick, electrically insulating oxide overlayer encapsulates the particles. Based on these experimental results, we then formulate an analytical model of powder bed charging in which each particle is approximated as a capacitor, where the particle and its substrate are the electrodes and the oxide overlayer is the dielectric. Using this model, we estimate the charge distribution in the powder bed, the electrostatic forces acting on the particles, and the conditions under which the powder bed will smoke. It is found that the electrical resistivity of the oxide overlayer strongly influences the charging behavior of the powder bed and that a high resistivity promotes charge accumulation and consequent smoking. This analysis suggests new quality control and process design measures that can help suppress smoking.

  19. Sorption-enhanced steam methane reforming in fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Johnsen, Kim

    2006-10-15

    Hydrogen is considered to be an important potential energy carrier; however, its advantages are unlikely to be realized unless efficient means can be found to produce it without generation of CO{sub 2}. Sorption-enhanced steam methane reforming (SE-SMR) represent a novel, energy-efficient hydrogen production route with in situ CO{sub 2} capture, shifting the reforming and water gas shift reactions beyond their conventional thermodynamic limits. The use of fluidized bed reactors for SE-SMR has been investigated. Arctic dolomite, a calcium-based natural sorbent, was chosen as the primary CO{sub 2}-acceptor in this study due to high absorption capacity, relatively high reaction rate and low cost. An experimental investigation was conducted in a bubbling fluidized bed reactor of diameter 0.1 m, which was operated cyclically and batch wise, alternating between reforming/carbonation conditions and higher-temperature calcination conditions. Hydrogen concentrations of >98 mole% on a dry basis were reached at 600 C and 1 atm, for superficial gas velocities in the range of {approx}0.03-0.1 m/s. Multiple reforming-regeneration cycles showed that the hydrogen concentration remained at {approx}98 mole% after four cycles. The total production time was reduced with an increasing number of cycles due to loss of CO{sub 2}-uptake capacity of the dolomite, but the reaction rates of steam reforming and carbonation seemed to be unaffected for the conditions investigated. A modified shrinking core model was applied for deriving carbonation kinetics of Arctic dolomite, using experimental data from a novel thermo gravimetric reactor. An apparent activation energy of 32.6 kj/mole was found from parameter fitting, which is in good agreement with previous reported results. The derived rate expression was able to predict experimental conversion up to {approx}30% very well, whereas the prediction of higher conversion levels was poorer. However, the residence time of sorbent in a continuous

  20. Nuclear safeguards considerations for pebble bed reactors (PBRs)

    International Nuclear Information System (INIS)

    Moses, David L.

    2012-01-01

    Recent reports by the Department of Energy National Laboratories have discussed safeguards considerations for low enriched uranium (LEU)-fueled pebble bed reactors (PBRs) and the need for bulk accountancy of the plutonium in “used fuel.” These reports fail to account for the degree of plutonium dilution in the graphitized-carbon pebbles that is sufficient to meet the International Atomic Energy Agency (IAEA) “provisional” guidelines for termination of safeguards on “measured discards.” The thrust of this finding is not to terminate safeguards but to limit the need for specific accountancy of plutonium in stored used fuel. While the residual uranium in the used fuel is not sufficiently diluted to meet the IAEA provisional guidelines for termination of safeguards, the estimated quantities of the uranium minor isotopes 232 U and 236 U in the used fuel at the target burnup of ∼90 Gigawatt-days per metric ton (GWD/MT) exceed standard specification limits for reprocessed uranium and will require extensive blending with either natural uranium or uranium enrichment tails to dilute the 236 U content to fall within specification. Hence, the PBR used fuel is less desirable for commercial reprocessing and reuse than that from light water reactors. Also the PBR specific activity of a reprocessed uranium isotopic mixture and its A 2 values for effective dose limits if released in a dispersible form during a transportation accident are more limiting than the equivalent values for light-water-reactor used fuel at 55 GWD/MT without accounting for the presence of the principal carry-over fission product (technetium, 99 Tc) and plutonium contamination. Thus, the potentially recoverable uranium from PBR used fuel carries reactivity penalties and radiological penalties likely greater than those for reprocessed uranium from light water reactors. These factors impact the economics of reprocessing, but a more significant consideration is that reprocessing technologies for

  1. Gas-solid hydroxyethylation of potato starch in a stirred vibrating fluidized bed reactor

    NARCIS (Netherlands)

    Kuipers, N.J M; Stamhuis, Eize; Beenackers, A.A C M

    A novel reactor for modifying cohesive C-powders such as in the gas-solid hydroxyethylation of semidry potato starch is characterized, the so-called stirred vibrating fluidized bed reactor. Good fluidization characteristics are obtained in this reactor for certain combinations of stirring and

  2. Nitrification of industrial and domestic saline wastewaters in moving bed biofilm reactor and sequencing batch reactor

    International Nuclear Information System (INIS)

    Bassin, Joao P.; Dezotti, Marcia; Sant'Anna, Geraldo L.

    2011-01-01

    Nitrification of saline wastewaters was investigated in bench-scale moving-bed biofilm reactors (MBBR). Wastewater from a chemical industry and domestic sewage, both treated by the activated sludge process, were fed to moving-bed reactors. The industrial wastewater contained 8000 mg Cl - /L and the salinity of the treated sewage was gradually increased until that level. Residual substances present in the treated industrial wastewater had a strong inhibitory effect on the nitrification process. Assays to determine inhibitory effects were performed with the industrial wastewater, which was submitted to ozonation and carbon adsorption pretreatments. The latter treatment was effective for dissolved organic carbon (DOC) removal and improved nitrification efficiency. Nitrification percentage of the treated domestic sewage was higher than 90% for all tested chloride concentrations up to 8000 mg/L. Results obtained in a sequencing batch reactor (SBR) were consistent with those attained in the MBBR systems, allowing tertiary nitrification and providing adequate conditions for adaptation of nitrifying microorganisms even under stressing and inhibitory conditions.

  3. Pebble bed modular reactor - The first Generation IV reactor to be constructed

    International Nuclear Information System (INIS)

    Ion, S.; Nicholls, D.; Matzie, R.; Matzner, D.

    2004-01-01

    Substantial interest has been generated in advanced reactors over the past few years. This interest is motivated by the view that new nuclear power reactors will be needed to provide low carbon generation of electricity and possibly hydrogen to support the future growth in demand for both of these commodities. Some governments feel that substantially different designs will be needed to satisfy the desires for public perception, improved safety, proliferation resistance, reduced waste and competitive economics. This has motivated the creation of the Generation IV Nuclear Energy Systems programme in which ten countries have agreed on a framework for international cooperation in research for advanced reactors. Six designs have been selected for continued evaluation, with the objective of deployment by 2030. One of these designs is the very high temperature reactor (VHTR), which is a thermal neutron spectrum system with a helium-cooled core utilising carbon-based fuel. The pebble bed modular reactor (PBMR), being developed in South Africa through a worldwide international collaborative effort led by Eskom, the national utility, will represent a key milestone on the way to achievement of the VHTR design objectives, but in the much nearer term. This paper outlines the design objectives, safety approach and design details of the PBMR, which is already at a very advanced stage of development. (author)

  4. Hydrolysis of cellulose in a cellulase-bead fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Karube, I; Tanaka, S; Shirai, T; Suzuki, S

    1977-08-01

    Cellulase was immobilized in a collagen fibril matrix, and no leakage of cellulase from the collagen fibril matrix was observed. The immobilized cellulase was more stable than the native cellulase. The substrate cellulose was hydrolyzed quantitatively with immobilized cellulase. The final reaction product was identified as glucose. Immobilized cellulase was used in a fluidized bed reactor where the pressure drop of the fluidized bed reactor was low and constant. Cellulose was hydrolyzed to glucose by the cellulase-bead fluidized bed reactor. The minimum flow velocity (U/sub mf/) was 0.5 cm/sec and the optimum flow velocity of the cellulose hydrolysis was 1 cm/sec.

  5. Coupling membrane pervaporation with a fixed-bed reactor for enhanced esterification of oleic acid with ethanol

    International Nuclear Information System (INIS)

    Han, Ying; Lv, Enmin; Ma, Lingling; Lu, Jie; Chen, Kexun; Ding, Jincheng

    2015-01-01

    Highlights: • The reactor coupling membrane pervaporation with a fixed-bed reactor was studied. • The factors effecting the esterification of oleic acid were investigated. • NaA zeolite membrane was used for dehydration in the coupled reactor. - Abstract: Process intensification through membrane pervaporation (PV) integrated with a fixed-bed reactor could be successfully applied to the esterification of oleic acid and ethanol, which is a crucial step in the biodiesel synthesis using waste oil and grease as resource. The properties of the NaA zeolite membrane such as structure, formulation and separation were investigated by scanning electronic microscopy–energy dispersive spectrometry (SEM–EDS), X-ray diffractometry (XRD) and PV dehydration. Results showed that the NaA zeolite membrane had good separating property for removing water from the organics mixture. The operating conditions were optimized as the ethanol to oleic acid molar ratio of 15:1, feedstock flow rate of 1.0 ml/min, reaction temperature of 80.0 °C and catalyst bed height of 132 mm. The final conversion of oleic acid increased from 84.23% to 87.18% by PV using the NaA zeolite membrane at 24.0 h of operation. The membrane showed good PV performance after used for eight successive runs in the PV-assisted esterification. The resin exhibited a much high catalytic activity and operation stability after used for 100 h in the consecutive single pass fixed-bed esterification.

  6. Sustainability and the Fixed Bed Nuclear Reactor (FBNR

    Directory of Open Access Journals (Sweden)

    Farhang Sefidvash

    2012-08-01

    Full Text Available Sustainability as a multifaceted and holistic concept is analyzed. Sustainability involves human relationship with elements such as natural environment, economy, power, governance, education and technology with the ultimate purpose of carrying forward an ever-advancing civilization. The Fixed Bed Nuclear Reactor (FBNR is an innovative, small, simple in design, inherently safe, non-proliferating, and environmentally friendly concept that its deployment can generate energy in a sustainable manner contributing to the prosperity of humanity. The development of FBNR will provide electricity as well as desalinated water through a simple but advanced technology for the developing, as well as developed countries. FBNR is environmentally friendly due to its inherent safety and the convenience of using its spent fuel as the source of radiation for irradiation purposes in agriculture, industry, and medicine. Politically, if a ping pong game brought peace between China and USA, a program of development of FBNR supported by the peace loving international community can become a more mature means to bring peace among certain apparently hostile nations who crave sustainable energy, desalinated water and simple advanced technology.

  7. Packed bed reactor treatment of liquid hazardous and mixed wastes

    International Nuclear Information System (INIS)

    Tennant, R.A.; Wantuck, P.J.; Vargas, R.

    1992-01-01

    We are developing thermal-based packed bed reactor (PBR) technology as an alternative to incineration for treatment of hazardous organic liquid wastes. The waste streams targeted by this technology are machining fluids contaminated with chlorocarbons and/or chlorofluorocarbons and low levels of plutonium or tritium The PBR offers several distinct advantages including simplistic design, rugged construction, ambient pressure processing, economical operations, as well as ease of scalability and maintainability. In this paper, we provide a description of the apparatus as well as test results using prepared mixtures of machining oils/emulsions with trichloroethylene (TCE), carbon tetrachloride (CCl 4 ), trichloroethane (TCA), and Freon TF. The current treatment system is configured as a two stage device with the PBR (1st stage) coupled to a silent discharge plasma (SDP) cell. The SDP serves as a second stage for further treatment of the gaseous effluent from the PBR. One of the primary advantages of this two stage system is that its suitability for closed loop operation where radioactive components are well contained and even CO 2 is not released to the environment

  8. Raising distillate selectivity and catalyst life time in Fischer-Tropsch synthesis by using a novel dual-bed reactor

    International Nuclear Information System (INIS)

    Tavasoli, A.; Sadaghiani, K.; Khodadadi, A. A.; Mortazavi, Y.

    2007-01-01

    In a novel dual bed reactor Fischer-Tropsch synthesis was studied by using two diff rent cobalt catalysts. An alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a Raiment promoted cobalt catalyst in the second bed. The activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed reactor system. The methane selectivity in the dual-bed reactor was about 18.9% less compared to that of the single-bed reactor. The C 5+ selectivity for the dual-bed reactor was 10.9% higher than that of the single-bed reactor. Accelerated deactivation of the catalysts in the dual-bed reactor was 42% lower than that of the single-bed reactor. It was revealed that the amount of catalysts activity recovery after regeneration at 400 d eg C in the dual-bed system is higher than that of the single-bed system

  9. Gas reactor international cooperative program interim report: German Pebble Bed Reactor design and technology review

    International Nuclear Information System (INIS)

    1978-09-01

    This report describes and evaluates several gas-cooled reactor plant concepts under development within the Federal Republic of Germany (FRG). The concepts, based upon the use of a proven Pebble Bed Reactor (PBR) fuel element design, include nuclear heat generation for chemical processes and electrical power generation. Processes under consideration for the nuclear process heat plant (PNP) include hydrogasification of coal, steam gasification of coal, combined process, and long-distance chemical heat transportation. The electric plant emphasized in the report is the steam turbine cycle (HTR-K), although the gas turbine cycle (HHT) is also discussed. The study is a detailed description and evaluation of the nuclear portion of the various plants. The general conclusions are that the PBR technology is sound and that the HTR-K and PNP plant concepts appear to be achievable through appropriate continuing development programs, most of which are either under way or planned

  10. Neutronic modeling of pebble bed reactors in APOLLO2

    International Nuclear Information System (INIS)

    Grimod, M.

    2010-01-01

    In this thesis we develop a new iterative homogenization technique for pebble bed reactors, based on a 'macro-stochastic' transport approximation in the collision probability method. A model has been developed to deal with the stochastic distribution of pebbles with different burnup in the core, considering spectral differences in homogenization and depletion calculations. This is generally not done in the codes presently used for pebble bed analyses, where a pebble with average isotopic composition is considered to perform the cell calculation. Also an iterative core calculation scheme has been set up, where the low-order RZ S N full-core calculation computes the entering currents in the spectrum zones subdividing the core. These currents, together with the core k eff , are then used as surface source in the fine-group heterogeneous calculation of the multi-pebble geometries. The developed method has been verified using reference Monte Carlo simulations of a simplified PBMR- 400 model. The pebbles in this model are individually positioned and have different randomly assigned burnup values. The APOLLO2 developed method matches the reference core k eff within ± 100 pcm, with relative differences on the production shape factors within ± 4%, and maximum discrepancy of 3% at the hotspot. Moreover, the first criticality experiment of the HTR-10 reactor was used to perform a first validation of the developed model. The computed critical number of pebbles to be loaded in the core is very close to the experimental value of 16890, only 77 pebbles less. A method to calculate the equilibrium reactor state was also developed and applied to analyze the simplified PBMR-400 model loaded with different fuel types (UO 2 , Pu, Pu + MA). The potential of the APOLLO2 method to compute different fluxes for the different pebble types of a multi-pebble geometry was used to evaluate the bias committed by the average composition pebble approximation. Thanks to a 'compensation of error

  11. Low-energy collisions between electrons and BeD+

    Science.gov (United States)

    Niyonzima, S.; Pop, N.; Iacob, F.; Larson, Å; Orel, A. E.; Mezei, J. Zs; Chakrabarti, K.; Laporta, V.; Hassouni, K.; Benredjem, D.; Bultel, A.; Tennyson, J.; Reiter, D.; Schneider, I. F.

    2018-02-01

    Multichannel quantum defect theory is applied in the treatment of the dissociative recombination and vibrational excitation processes for the BeD+ ion in the 24 vibrational levels of its ground electronic state ({{X}}{}1{{{Σ }}}+,{v}{{i}}+=0\\ldots 23). Three electronic symmetries of BeD** states ({}2{{\\Pi }}, {}2{{{Σ }}}+, and {}2{{Δ }}) are considered in the calculation of cross sections and the corresponding rate coefficients. The incident electron energy range is 10-5-2.7 eV and the electron temperature range is 100-5000 K. The vibrational dependence of these collisional processes is highlighted. The resulting data are useful in magnetic confinement fusion edge plasma modeling and spectroscopy, in devices with beryllium based main chamber materials, such as ITER and JET, and operating with the deuterium-tritium fuel mix. An extensive rate coefficients database is presented in graphical form and also by analytic fit functions whose parameters are tabulated in the supplementary material.

  12. Production of specific-structured lipids by enzymatic interesterification in a pilot continuous enzyme bed reactor

    DEFF Research Database (Denmark)

    Xu, Xuebing; Balchen, Steen; Høy, Carl-Erik

    1998-01-01

    Production of specific-structured lipids (interesterified lipids with a specific structure) by enzymatic interesterification was carried out in a continuous enzyme bed pilot scale reactor. Commercial immobilized lipase (Lipozyme IM) was used and investigations of acyl migration, pressure drop...

  13. Complex nonlinear behaviour of a fixed bed reactor with reactant recycle

    DEFF Research Database (Denmark)

    Recke, Bodil; Jørgensen, Sten Bay

    1999-01-01

    The fixed bed reactor with reactant recycle investigated in this paper can exhibit periodic solutions. These solutions bifurcate from the steady state in a Hopf bifurcation. The Hopf bifurcation encountered at the lowest value of the inlet concentration turns the steady state unstable and marks......,that the dynamic behaviour of a fixed bed reactor with reactant recycle is much more complex than previously reported....

  14. A novel approach for harnessing biofilm communities in moving bed biofilm reactors for industrial wastewater treatment

    OpenAIRE

    Joe A. Lemire; Marc A. Demeter; Iain George; Howard Ceri; Raymond J. Turner

    2015-01-01

    Moving bed biofilm reactors (MBBRs) are an effective biotechnology for treating industrial wastewater. Biomass retention on moving bed biofilm reactor (MBBR) carriers (biofilm support materials), allows for the ease-of-operation and high treatment capacity of MBBR systems. Optimization of MBBR systems has largely focused on aspects of carrier design, while little attention has been paid to enhancing strategies for harnessing microbial biomass. Previously, our research group demonstrated that ...

  15. Oxidation of ethene in a wall-cooled packed-bed reactor

    NARCIS (Netherlands)

    Schouten, E.P.S.; Borman, P.C.; Westerterp, K.R.

    1994-01-01

    The selective oxidation of ethene over a silver on α-alumina catalyst was studied in a pilot plant with a wall-cooled tubular packed bed reactor. Gas and solid temperatures in the catalyst bed were measured at different axial and radial positions as well as concentrations at different axial

  16. Advantages of forced non-steady operated trickle-bed reactors

    NARCIS (Netherlands)

    Boelhouwer, J.G.; Piepers, H.W.; Drinkenburg, A.A.H.

    2002-01-01

    Trickle-bed reactors are usually operated in the steady state trickle flow regime. Uneven liquid distribution and the formation of hot spots are the most serious problems experienced during trickle flow operation. In this paper, we advocate the use of non-steady state operation of trickle-bed

  17. Catalytic fast pyrolysis of white oak wood in-situ using a bubbling fluidized bed reactor

    Science.gov (United States)

    Catalytic fast pyrolysis was performed on white oak wood using two zeolite-type catalysts as bed material in a bubbling fluidized bed reactor. The two catalysts chosen, based on a previous screening study, were Ca2+ exchanged Y54 (Ca-Y54) and a proprietary ß-zeolite type catalyst (catalyst M) both ...

  18. Chemical-looping combustion in a reverse-flow fixed bed reactor

    International Nuclear Information System (INIS)

    Han, Lu; Bollas, George M.

    2016-01-01

    A reverse-flow fixed bed reactor concept for CLC (chemical-looping combustion) is explored. The limitations of conventional fixed bed reactors, as applied to CLC, are overcome by reversing the gas flow direction periodically to enhance the mixing characteristics of the bed, thus improving oxygen carrier utilization and energy efficiency with respect to power generation. The reverse-flow reactor is simulated by a dusty-gas model and compared with an equivalent fixed bed reactor without flow reversal. Dynamic optimization is used to calculate conditions at which each reactor operates at maximum energy efficiency. Several cases studies illustrate the benefits of reverse-flow operation for the CLC with CuO and NiO oxygen carriers and methane and syngas fuels. The results show that periodic reversal of the flow during reduction improves the contact between the fuel and unconverted oxygen carrier, enabling the system to suppress unwanted catalytic reactions and axial temperature and conversion gradients. The operational scheme presented reduces the fluctuations of temperature during oxidation and increases the high-temperature heat produced by the process. CLC in a reverse-flow reactor has the potential to achieve higher energy efficiency than conventional fixed bed CLC reactors, when integrated with a downstream gas turbine of a combined cycle power plant. - Highlights: • Reverse-flow fixed bed CLC reactors for combined cycle power systems. • Dynamic optimization tunes operation of batch and transient CLC systems. • The reverse-flow CLC system provides stable turbine-ready gas stream. • Reverse-flow CLC fixed bed reactor has superior CO 2 capture and thermal efficiency.

  19. Development of a trickle bed reactor of electro-Fenton process for wastewater treatment

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Yangming [Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 401122 (China); School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Liu, Hong, E-mail: liuhong@cigit.ac.cn [Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 401122 (China); Shen, Zhemin, E-mail: zmshen@sjtu.edu.cn [School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Wang, Wenhua [School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2013-10-15

    Highlights: • An electrochemical trickle bed reactor was composed of C-PTFE-coated graphite chips. • The trickle bed reactor had a high H{sub 2}O{sub 2} production rate in a dilute electrolyte. • An azo dye was effectively decomposed by the electro-Fenton process in the reactor. -- Abstract: To avoid electrolyte leakage and gas bubbles in the electro-Fenton (E-Fenton) reactors using a gas diffusion cathode, we developed a trickle bed cathode by coating a layer composed of carbon black and polytetrafluoroethylene (C-PTFE) onto graphite chips instead of carbon cloth. The trickle bed cathode was optimized by single-factor and orthogonal experiments, in which carbon black, PTFE, and a surfactant were considered as the determinant of the performance of graphite chips. In the reactor assembled by the trickle bed cathode, H{sub 2}O{sub 2} was generated with a current of 0.3 A and a current efficiency of 60%. This performance was attributed to the fine distribution of electrolyte and air, as well as the effective oxygen transfer from the gas phase to the electrolyte–cathode interface. In terms of H{sub 2}O{sub 2} generation and current efficiency, the developed trickle bed reactor had a performance comparable to that of the conventional E-Fenton reactor using a gas diffusion cathode. Further, 123 mg L{sup −1} of reactive brilliant red X-3B in aqueous solution was decomposed in the optimized trickle bed reactor as E-Fenton reactor. The decolorization ratio reached 97% within 20 min, and the mineralization reached 87% within 3 h.

  20. Development of a trickle bed reactor of electro-Fenton process for wastewater treatment

    International Nuclear Information System (INIS)

    Lei, Yangming; Liu, Hong; Shen, Zhemin; Wang, Wenhua

    2013-01-01

    Highlights: • An electrochemical trickle bed reactor was composed of C-PTFE-coated graphite chips. • The trickle bed reactor had a high H 2 O 2 production rate in a dilute electrolyte. • An azo dye was effectively decomposed by the electro-Fenton process in the reactor. -- Abstract: To avoid electrolyte leakage and gas bubbles in the electro-Fenton (E-Fenton) reactors using a gas diffusion cathode, we developed a trickle bed cathode by coating a layer composed of carbon black and polytetrafluoroethylene (C-PTFE) onto graphite chips instead of carbon cloth. The trickle bed cathode was optimized by single-factor and orthogonal experiments, in which carbon black, PTFE, and a surfactant were considered as the determinant of the performance of graphite chips. In the reactor assembled by the trickle bed cathode, H 2 O 2 was generated with a current of 0.3 A and a current efficiency of 60%. This performance was attributed to the fine distribution of electrolyte and air, as well as the effective oxygen transfer from the gas phase to the electrolyte–cathode interface. In terms of H 2 O 2 generation and current efficiency, the developed trickle bed reactor had a performance comparable to that of the conventional E-Fenton reactor using a gas diffusion cathode. Further, 123 mg L −1 of reactive brilliant red X-3B in aqueous solution was decomposed in the optimized trickle bed reactor as E-Fenton reactor. The decolorization ratio reached 97% within 20 min, and the mineralization reached 87% within 3 h

  1. A CFD Study on Inlet Plenum Flow Field of Pebble Bed Reactor

    International Nuclear Information System (INIS)

    Kim, Min Hwan; Lee, Won Jae; Chang, Jong Hwa

    2005-01-01

    High temperature gas cooled reactor, largely divided into two types of PBR (Pebble Bed Reactor) and PMR (Prismatic Modular Reactor), has becomes great interest of researchers in connection with the hydrogen production. KAERI has started a project to develop the gas cooled reactor for the hydrogen production and has been doing in-depth study for selecting the reactor type between PBR and PMR. As a part of the study, PBMR (Pebble Bed Modular Reactor) was selected as a reference PBR reactor for the CFD analysis and the flow field of its inlet plenum was simulated with computational fluid dynamics program CFX5. Due to asymmetrical arrangement of pipes to the inlet plenum, non-uniform flow distribution has been expected to occur, giving rise to non-uniform power distribution at the core. Flow fields of different arrangement of inlet pipes were also investigated, as one of measures to reduce the non-uniformity

  2. Neutron Fluence And DPA Rate Analysis In Pebble-Bed HTR Reactor Vessel Using MCNP

    Science.gov (United States)

    Hamzah, Amir; Suwoto; Rohanda, Anis; Adrial, Hery; Bakhri, Syaiful; Sunaryo, Geni Rina

    2018-02-01

    In the Pebble-bed HTR reactor, the distance between the core and the reactor vessel is very close and the media inside are carbon and He gas. Neutron moderation capability of graphite material is theoretically lower than that of water-moderated reactors. Thus, it is estimated much more the fast neutrons will reach the reactor vessel. The fast neutron collisions with the atoms in the reactor vessel will result in radiation damage and could be reducing the vessel life. The purpose of this study was to obtain the magnitude of neutron fluence in the Pebble-bed HTR reactor vessel. Neutron fluence calculations in the pebble-bed HTR reactor vessel were performed using the MCNP computer program. By determining the tally position, it can be calculated flux, spectrum and neutron fluence in the position of Pebble-bed HTR reactor vessel. The calculations results of total neutron flux and fast neutron flux in the reactor vessel of 1.82x108 n/cm2/s and 1.79x108 n/cm2/s respectively. The fast neutron fluence in the reactor vessel is 3.4x1017 n/cm2 for 60 years reactor operation. Radiation damage in stainless steel material caused by high-energy neutrons (> 1.0 MeV) will occur when it has reached the neutron flux level of 1.0x1024 n/cm2. The neutron fluence results show that there is no radiation damage in the Pebble-bed HTR reactor vessel, so it is predicted that it will be safe to operate at least for 60 years.

  3. Solid phase transport in series fluidised bed reactors

    International Nuclear Information System (INIS)

    Hayes, M.R.

    1980-01-01

    In a multistage counter-current fluidised bed column, fluidised bed material is recycled within each stage and a fraction is continuously withdrawn to the next lower stage at a rate dependent only on the rate of removal of the fluidised bed material from the base of the column. It has a particular application to the ion exchange treatment of liquids containing suspended solids, for example leach solutions from uranium ores. (author)

  4. Comparative study between fluidized bed and fixed bed reactors in methane reforming with CO2 and O2 to produce syngas

    International Nuclear Information System (INIS)

    Jing Qiangshan; Lou Hui; Mo Liuye; Zheng Xiaoming

    2006-01-01

    Reforming of methane with carbon dioxide and oxygen was investigated over Ni/MgO-SiO 2 catalysts using fixed bed and fluidized bed reactors. The conversions of CH 4 and CO 2 in a fluidized bed reactor were close to thermodynamic equilibrium. The activity and stability of the catalyst in the fixed bed reactor were lower than that in the fluidized bed reactor due to carbon deposition and nickel sintering. TGA and TEM techniques were used to characterize the spent catalysts. The results showed that a lot of whisker carbon was found on the catalyst in the rear of the fixed bed reactor, and no deposited carbon was observed on the catalysts in the fluidized bed reactor after reaction. It is suggested that this phenomenon is related to a permanent circulation of catalyst particles between the oxygen rich and oxygen free zones. That is, fluidization of the catalysts in the fluidized bed reactor favors inhibiting deposited carbon and thermal uniformity in the reactor

  5. Design of particle bed reactors for the space nuclear thermal propulsion program

    International Nuclear Information System (INIS)

    Ludewig, H.; Powell, J.R.; Todosow, M.; Maise, G.; Barletta, R.; Schweitzer, D.G.

    1996-01-01

    This paper describes the design for the Particle Bed Reactor (PBR) that was considered for the Space Nuclear Thermal Propulsion (SNTP) Program. The methods of analysis and their validation are outlined first. Monte Carlo methods were used for the physics analysis, several new algorithms were developed for the fluid dynamics, heat transfer and transient analysis; and commercial codes were used for the stress analysis. We carried out a critical experiment, prototypic of the PBR to validate the reactor physics; blowdown experiments with beds of prototypic dimensions were undertaken to validate the power-extraction capabilities from particle beds. In addition, materials and mechanical design concepts for the fuel elements were experimentally validated. (author)

  6. Anaerobic Digestion of Sugarcane Vinasse Through a Methanogenic UASB Reactor Followed by a Packed Bed Reactor.

    Science.gov (United States)

    Cabrera-Díaz, A; Pereda-Reyes, I; Oliva-Merencio, D; Lebrero, R; Zaiat, M

    2017-12-01

    The anaerobic treatment of raw vinasse in a combined system consisting in two methanogenic reactors, up-flow anaerobic sludge blanket (UASB) + anaerobic packed bed reactors (APBR), was evaluated. The organic loading rate (OLR) was varied, and the best condition for the combined system was 12.5 kg COD m -3 day -1 with averages of 0.289 m 3 CH 4  kg COD r -1 for the UASB reactor and 4.4 kg COD m -3 day -1 with 0.207 m 3 CH 4  kg COD r -1 for APBR. The OLR played a major role in the emission of H 2 S conducting to relatively stable quality of biogas emitted from the APBR, with H 2 S concentrations <10 mg L -1 . The importance of the sulphate to COD ratio was demonstrated as a result of the low biogas quality recorded at the lowest ratio. It was possible to develop a proper anaerobic digestion of raw vinasse through the combined system with COD removal efficiency of 86.7% and higher CH 4 and a lower H 2 S content in biogas.

  7. Dispersed plug flow model for upflow anaerobic sludge bed reactors with focus on granular sludge dynamics

    NARCIS (Netherlands)

    Kalyuzhnyi, S.V.; Fedorovich, V.V.; Lens, P.N.L.

    2006-01-01

    A new approach to model upflow anaerobic sludge bed (UASB)-reactors, referred to as a one-dimensional dispersed plug flow model, was developed. This model focusses on the granular sludge dynamics along the reactor height, based on the balance between dispersion, sedimentation and convection using

  8. Conceptual design of a fluidized bed nuclear reactor : Statics, dynamics and safety-related aspects

    NARCIS (Netherlands)

    Agung, A.

    2007-01-01

    In this thesis a conceptual design of an innovative high temperature reactor based on the fluidization principle (FLUBER) is proposed. The reactor should satisfy the following requirements: (a) modular and low power, (b)) large shutdown margin, (c) able to produce power when the bed of particles

  9. Model description and kinetic parameter analysis of MTBE biodegradation in a packed bed reactor

    DEFF Research Database (Denmark)

    Waul, Christopher Kevin; Arvin, Erik; Schmidt, Jens Ejbye

    2008-01-01

    A dynamic modeling approach was used to estimate in-situ model parameters, which describe the degradation of methyl tert-butyl ether (MTBE) in a laboratory packed bed reactor. The measured dynamic response of MTBE pulses injected at the reactor's inlet was analyzed by least squares and parameter...

  10. Discharge Characteristics of Series Surface/Packed-Bed Discharge Reactor Diven by Bipolar Pulsed Power

    International Nuclear Information System (INIS)

    Hu Jian; Jiang Nan; Li Jie; Shang Kefeng; Lu Na; Wu Yan; Mizuno Akira

    2016-01-01

    The discharge characteristics of the series surface/packed-bed discharge (SSPBD) reactor driven by bipolar pulse power were systemically investigated in this study. In order to evaluate the advantages of the SSPBD reactor, it was compared with traditional surface discharge (SD) reactor and packed-bed discharge (PBD) reactor in terms of the discharge voltage, discharge current, and ozone formation. The SSPBD reactor exhibited a faster rising time and lower tail voltage than the SD and PBD reactors. The distribution of the active species generated in different discharge regions of the SSPBD reactor was analyzed by optical emission spectra and ozone analysis. It was found that the packed-bed discharge region (3.5 mg/L), rather than the surface discharge region (1.3 mg/L) in the SSPBD reactor played a more important role in ozone generation. The optical emission spectroscopy analysis indicated that more intense peaks of the active species (e.g. N2 and OI) in the optical emission spectra were observed in the packed-bed region. (paper)

  11. Discharge Characteristics of Series Surface/Packed-Bed Discharge Reactor Diven by Bipolar Pulsed Power

    Science.gov (United States)

    Hu, Jian; Jiang, Nan; Li, Jie; Shang, Kefeng; Lu, Na; Wu, Yan; Mizuno, Akira

    2016-03-01

    The discharge characteristics of the series surface/packed-bed discharge (SSPBD) reactor driven by bipolar pulse power were systemically investigated in this study. In order to evaluate the advantages of the SSPBD reactor, it was compared with traditional surface discharge (SD) reactor and packed-bed discharge (PBD) reactor in terms of the discharge voltage, discharge current, and ozone formation. The SSPBD reactor exhibited a faster rising time and lower tail voltage than the SD and PBD reactors. The distribution of the active species generated in different discharge regions of the SSPBD reactor was analyzed by optical emission spectra and ozone analysis. It was found that the packed-bed discharge region (3.5 mg/L), rather than the surface discharge region (1.3 mg/L) in the SSPBD reactor played a more important role in ozone generation. The optical emission spectroscopy analysis indicated that more intense peaks of the active species (e.g. N2 and OI) in the optical emission spectra were observed in the packed-bed region. supported by National Natural Science Foundation of China (No. 51177007), the Joint Funds of National Natural Science Foundation of China (No. U1462105), and Dalian University of Technology Fundamental Research Fund of China (No. DUT15RC(3)030)

  12. Cost analysis of enzymatic biodiesel production in small-scaled packed-bed reactors

    NARCIS (Netherlands)

    Budzaki, S.; Miljic, G.; Sundaram, S.; Tisma, M.; Hessel, V.

    2017-01-01

    A cost analysis of enzymatic biodiesel production in small-scaled packed-bed reactors using refined sunflower oil is performed in this work. A few enzymatic micro-flow reactors have so far reached a performance close to gram-scale, which might be sufficient for the pharmaceutical industry. This

  13. Thermofluid-neutronic stability of the rotating, fluidized bed, space-power reactor

    International Nuclear Information System (INIS)

    Lee, C.C.; Jones, O.C.; Becker, M.

    1993-01-01

    A rotating fluidized bed nuclear reactor has the potential of being a vary attractive option for ultra-high power space systems, especially for propulsion. Research has already examined fuel bed expansion due to variations in state variables, propellant flow rate, and rotational speed, and has also considered problems related to thermal stress. This paper describes the results of a coupled thermofluid-neutronic analysis where perturbations in fuel bed height caused by maneuvering changes in operating conditions alter power levels due to varying absorption of neutrons which would otherwise leak from the system, mainly through the nozzle. This first analysis was not a detailed stability analysis. Rather, it utilized simplified neutronic methods, and was intended to provide an order-of-magnitude assessment of the stability of the reactor with the intention to determine whether or not stability might be a 'concept killer'. Stability was compared with a fixed-fuel-bed reactor of identical geometry for three different cases comprising a set of small, medium and large sizes/powers from 250 MW to 5 GW. It was found that power fluctuations in the fluidized bed reactor were larger by 100 db or more than expected in a packed bed reactor of the same geometry, but never resulted in power excursions. Margins to unit gain in some cases, however, were sufficiently small that the approximations in this quasi-2-dimensional model may not be sufficiently accurate to preclude significant excursions. (orig.)

  14. Continuous removal and recovery of tellurium in an upflow anaerobic granular sludge bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Mal, Joyabrata, E-mail: joyabrata2006@gmail.com [UNESCO-IHE, Westvest 7, 2611 AX Delft (Netherlands); Nancharaiah, Yarlagadda V. [Biofouling and Biofilm Processes Section, Water and Steam Chemistry Division, Bhabha Atomic Research Centre, Kalpakkam, 603102, Tamil Nadu (India); Homi Bhabha National Institute, Anushakti Nagar Complex, Mumbai 400094 (India); Maheshwari, Neeraj [CNRS UMR 7338, BMBI University de Technologie Compiegne, 60200 Compiegne (France); Hullebusch, Eric D. van [UNESCO-IHE, Westvest 7, 2611 AX Delft (Netherlands); Université Paris-Est, Laboratoire Géomatériaux et Environnement (LGE), EA 4508, UPEM, 77454, Marne-la-Vallée (France); Lens, Piet N.L. [UNESCO-IHE, Westvest 7, 2611 AX Delft (Netherlands); Department of Chemistry and Bioengineering, Tampere University of Technology, P.O-Box 541, Tampere (Finland)

    2017-04-05

    Highlights: • Tellurite bioreduction coupled to recovery of biogenic Te(0) nanocrystals. • First report on continuous tellurite removal in a UASB reactor. • Biogenic Te(0) was mainly associated with loosely-bound EPS of granular sludge. • Repeated exposure to tellurite caused compositional changes in the EPS matrix. - Abstract: Continuous removal of tellurite (TeO{sub 3}{sup 2−}) from synthetic wastewater and subsequent recovery in the form of elemental tellurium was studied in an upflow anaerobic granular sludge bed (UASB) reactor operated at 30 °C. The UASB reactor was inoculated with anaerobic granular sludge and fed with lactate as carbon source and electron donor at an organic loading rate of 0.6 g COD L{sup −1} d{sup −1}. After establishing efficient and stable COD removal, the reactor was fed with 10 mg TeO{sub 3}{sup 2−} L{sup −1} for 42 d before increasing the influent concentration to 20 mg TeO{sub 3}{sup 2−} L{sup −1}. Tellurite removal (98 and 92%, respectively, from 10 and 20 mg Te L{sup −1}) was primarily mediated through bioreduction and most of the removed Te was retained in the bioreactor. Characterization using XRD, Raman spectroscopy, SEM-EDX and TEM confirmed association of tellurium with the granular sludge, typically in the form of elemental Te(0) deposits. Furthermore, application of an extracellular polymeric substances (EPS) extraction method to the tellurite reducing sludge recovered up to 78% of the tellurium retained in the granular sludge. This study demonstrates for the first time the application of a UASB reactor for continuous tellurite removal from tellurite-containing wastewater coupled to elemental Te(0) recovery.

  15. Continuous reduction of tellurite to recoverable tellurium nanoparticles using an upflow anaerobic sludge bed (UASB) reactor.

    Science.gov (United States)

    Ramos-Ruiz, Adriana; Sesma-Martin, Juan; Sierra-Alvarez, Reyes; Field, Jim A

    2017-01-01

    According to the U.S. Department of Energy and the European Union, tellurium is a critical element needed for energy and defense technology. Thus methods are needed to recover tellurium from waste streams. The objectives of this study was to determine the feasibility of utilizing upflow anaerobic sludge bed (UASB) reactors to convert toxic tellurite (Te IV ) oxyanions to non-toxic insoluble elemental tellurium (Te 0 ) nanoparticles (NP) that are amendable to separation from aqueous effluents. The reactors were supplied with ethanol as the electron donating substrate to promote the biological reduction of Te IV . One reactor was additionally amended with the redox mediating flavonoid compound, riboflavin (RF), with the goal of enhancing the bioreduction of Te IV . Its performance was compared to a control reactor lacking RF. The continuous formation of Te 0 NPs using the UASB reactors was found to be feasible and remarkably improved by the addition of RF. The presence of this flavonoid was previously shown to enhance the conversion rate of Te IV by approximately 11-fold. In this study, we demonstrated that this was associated with the added benefit of reducing the toxic impact of Te IV towards the methanogenic consortium in the UASB and thus enabled a 4.7-fold higher conversion rate of the chemical oxygen demand. Taken as a whole, this work demonstrates the potential of a methanogenic granular sludge to be applied as a bioreactor technology producing recoverable Te 0 NPs in a continuous fashion. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Continuous removal and recovery of tellurium in an upflow anaerobic granular sludge bed reactor

    International Nuclear Information System (INIS)

    Mal, Joyabrata; Nancharaiah, Yarlagadda V.; Maheshwari, Neeraj; Hullebusch, Eric D. van; Lens, Piet N.L.

    2017-01-01

    Highlights: • Tellurite bioreduction coupled to recovery of biogenic Te(0) nanocrystals. • First report on continuous tellurite removal in a UASB reactor. • Biogenic Te(0) was mainly associated with loosely-bound EPS of granular sludge. • Repeated exposure to tellurite caused compositional changes in the EPS matrix. - Abstract: Continuous removal of tellurite (TeO 3 2− ) from synthetic wastewater and subsequent recovery in the form of elemental tellurium was studied in an upflow anaerobic granular sludge bed (UASB) reactor operated at 30 °C. The UASB reactor was inoculated with anaerobic granular sludge and fed with lactate as carbon source and electron donor at an organic loading rate of 0.6 g COD L −1 d −1 . After establishing efficient and stable COD removal, the reactor was fed with 10 mg TeO 3 2− L −1 for 42 d before increasing the influent concentration to 20 mg TeO 3 2− L −1 . Tellurite removal (98 and 92%, respectively, from 10 and 20 mg Te L −1 ) was primarily mediated through bioreduction and most of the removed Te was retained in the bioreactor. Characterization using XRD, Raman spectroscopy, SEM-EDX and TEM confirmed association of tellurium with the granular sludge, typically in the form of elemental Te(0) deposits. Furthermore, application of an extracellular polymeric substances (EPS) extraction method to the tellurite reducing sludge recovered up to 78% of the tellurium retained in the granular sludge. This study demonstrates for the first time the application of a UASB reactor for continuous tellurite removal from tellurite-containing wastewater coupled to elemental Te(0) recovery.

  17. Computational and experimental prediction of dust production in pebble bed reactors, Part II

    Energy Technology Data Exchange (ETDEWEB)

    Hiruta, Mie; Johnson, Gannon [Department of Mechanical Engineering, University of Idaho, 1776 Science Center Drive, Idaho Falls, ID 83401 (United States); Rostamian, Maziar, E-mail: mrostamian@asme.org [Department of Mechanical Engineering, University of Idaho, 1776 Science Center Drive, Idaho Falls, ID 83401 (United States); Potirniche, Gabriel P. [Department of Mechanical Engineering, University of Idaho, 1776 Science Center Drive, Idaho Falls, ID 83401 (United States); Ougouag, Abderrafi M. [Idaho National Laboratory, 2525 N Fremont Avenue, Idaho Falls, ID 83401 (United States); Bertino, Massimo; Franzel, Louis [Department of Physics, Virginia Commonwealth University, Richmond, VA 23284 (United States); Tokuhiro, Akira [Department of Mechanical Engineering, University of Idaho, 1776 Science Center Drive, Idaho Falls, ID 83401 (United States)

    2013-10-15

    Highlights: • Custom-built high temperature, high pressure tribometer is designed. • Two different wear phenomena at high temperatures are observed. • Experimental wear results for graphite are presented. • The graphite wear dust production in a typical Pebble Bed Reactor is predicted. -- Abstract: This paper is the continuation of Part I, which describes the high temperature and high pressure helium environment wear tests of graphite–graphite in frictional contact. In the present work, it has been attempted to simulate a Pebble Bed Reactor core environment as compared to Part I. The experimental apparatus, which is a custom-designed tribometer, is capable of performing wear tests at PBR relevant higher temperatures and pressures under a helium environment. This environment facilitates prediction of wear mass loss of graphite as dust particulates from the pebble bed. The experimental results of high temperature helium environment are used to anticipate the amount of wear mass produced in a pebble bed nuclear reactor.

  18. Sintering study in vertical fixed bed reactor for synthetic aggregate production

    International Nuclear Information System (INIS)

    Quaresma, D.S.; Neves, A.S.S.; Melo, A.O.; Pereira, L.F.S.; Bezerra, P.T.S.; Macedo, E.N.; Souza, J.A.S.

    2017-01-01

    The synthetic aggregates are being employed in civil construction for the reduction of mineral extraction activities. Within this context, the recycling of industrial waste is the basis of the majority of processes to reduce the exploitation of mineral resources. In this work the sintering in a vertical fixed bed reactor for synthetic aggregate production using 20% pellets and 80% charcoal was studied. The pellets were prepared from a mixture containing clay, charcoal and fly ash. Two experiments varying the speed of air sucking were carried out. The material produced was analyzed by X-ray diffraction, scanning electron microscopy, measures of their ceramic properties, and particle size analysis. The results showed that the solid-state reactions, during the sintering process, were efficient and the produced material was classified as coarse lightweight aggregate. The process is interesting for the sintering of aggregates, and can be controlled by composition, particle size, temperature gradient and gaseous flow. (author)

  19. Review of PSI studies on reactor physics and thermal fluid dynamics of pebble bed reactors

    International Nuclear Information System (INIS)

    Prasser, Horst-Michael

    2014-01-01

    Switzerland is member of the Generation IV International Forum (GIF). The related work takes entirely place at PSI in the working groups of Gas-Cooled Fast Reactors and Very High Temperature Reactors. In the past, PSI has performed experimental and theoretical studies on criticality issues of pebble beds at the PROTEUS reactor, as well as a preliminary risk assessment of a prototypal HTR as an input for a comparison of energy supply options. PROTEUS was a critical assembly with an annular driver zone. The central region was filled by arrangements of fuel spheres. The reactivity effect of a water ingress was investigated by simulating the water by polyethylene rods of different diameter inserted into the gaps of a regular package. For sub-criticality measurements in pebble beds, a built-in pulsed neutron source was used. The experimental results were used to validate diffusion and higher order neutron transport models. Concerning thermal hydraulics of gas flows, the vast experience of PSI is focused on hydrogen transport, accumulation, and dispersion in containments of light water reactors. The phenomena are comparable in many aspects to the fluid dynamic issues relevant to HTR. Experiments on hydrogen flows are performed for numerous scenarios in the large-scale containment test facility PANDA. Hydrogen is substituted by helium as a model fluid. An important generic aspect is turbulent mixing in the presence of strong stratification, which is relevant for HTR as well. In a parallel project, generic small-scale mixing experiments with a high density ratio of 1:7 are carried out in a horizontal rectangular channel, where helium and nitrogen flows are brought into contact downstream of the rear edge of a splitter plate. Due to the high density ratio, turbulent mixing is affected by strong non-Boussinesq effects. The measurements taken by Particle Imaging Velocimetry (PIV) and Laser Induced Fluorescence techniques are compared to RANS and LES simulations. Similar large

  20. Development of a trickle bed reactor of electro-Fenton process for wastewater treatment.

    Science.gov (United States)

    Lei, Yangming; Liu, Hong; Shen, Zhemin; Wang, Wenhua

    2013-10-15

    To avoid electrolyte leakage and gas bubbles in the electro-Fenton (E-Fenton) reactors using a gas diffusion cathode, we developed a trickle bed cathode by coating a layer composed of carbon black and polytetrafluoroethylene (C-PTFE) onto graphite chips instead of carbon cloth. The trickle bed cathode was optimized by single-factor and orthogonal experiments, in which carbon black, PTFE, and a surfactant were considered as the determinant of the performance of graphite chips. In the reactor assembled by the trickle bed cathode, H2O2 was generated with a current of 0.3A and a current efficiency of 60%. This performance was attributed to the fine distribution of electrolyte and air, as well as the effective oxygen transfer from the gas phase to the electrolyte-cathode interface. In terms of H2O2 generation and current efficiency, the developed trickle bed reactor had a performance comparable to that of the conventional E-Fenton reactor using a gas diffusion cathode. Further, 123 mg L(-1) of reactive brilliant red X-3B in aqueous solution was decomposed in the optimized trickle bed reactor as E-Fenton reactor. The decolorization ratio reached 97% within 20 min, and the mineralization reached 87% within 3h. Copyright © 2013 Elsevier B.V. All rights reserved.

  1. Experimental and theoretical studies on hydrogenation of olefins in multiphase fixed bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Battsengel, B.; Datsevitch, L.; Jess, A. [Bayreuth Univ. (Germany). Dept. of Chemical Engineering

    2003-07-01

    Multi phase reactors like trickle bed systems are frequently used for gas-liquid reactions. In general, they have complex mass and heat transfer characteristics; scale-up is therefore difficult. The present work focuses on the role of mass transfer on the effective reaction rate, taking catalytic octene hydrogenation as a model reaction. The reaction rate in a trickle bed reactor is by a factor of about 20 smaller than (theoretically) in the absence of any mass transfer limitations. Based on the experimental results, the so-called pre-saturation concept is presented, where only the liquid saturated with hydrogen is fed into the reactor. The effective reaction rate in this two phase system (liquid and solid cat.) is equal or even higher than in a trickle bed reactor. Scale-up problems do not occur, and the pre-saturation concept has also other advantages (lower energy consumption), as discussed in detail in this paper. (orig.)

  2. Thermal safety analysis for pebble bed blanket fusion-fission hybrid reactor

    International Nuclear Information System (INIS)

    Wei Renjie

    1998-01-01

    Pebble bed blanket hybrid reactor may have more advantages than slab element blanket hybrid reactor in nuclear fuel production and nuclear safety. The thermo-hydraulic calculations of the blanket in the Tokamak helium cooling pebble bed blanket fusion-fission hybrid reactor developed in China are carried out using the Code THERMIX and auxiliary code. In the calculations different fuel pebble material and steady state, depressurization and total loss of flow accident conditions are included. The results demonstrate that the conceptual design of the Tokamak helium cooling pebble bed blanket fusion-fission hybrid reactor with dump tank is feasible and safe enough only if the suitable fuel pebble material is selected and the suitable control system and protection system are established. Some recommendations for due conceptual design are also presented

  3. Continuous biological waste gas treatment in stirred trickle-bed reactor with discontinuous removal of biomass.

    Science.gov (United States)

    Laurenzis, A; Heits, H; Wübker, S; Heinze, U; Friedrich, C; Werner, U

    1998-02-20

    A new reactor for biological waste gas treatment was developed to eliminate continuous solvents from waste gases. A trickle-bed reactor was chosen with discontinuous movement of the packed bed and intermittent percolation. The reactor was operated with toluene as the solvent and an optimum average biomass concentration of between 5 and 30 kg dry cell weight per cubic meter packed bed (m3pb). This biomass concentration resulted in a high volumetric degradation rate. Reduction of surplus biomass by stirring and trickling caused a prolonged service life and prevented clogging of the trickle bed and a pressure drop increase. The pressure drop after biomass reduction was almost identical to the theoretical pressure drop as calculated for the irregular packed bed without biomass. The reduction in biomass and intermittent percolation of mineral medium resulted in high volumetric degradation rates of about 100 g of toluene m-3pb h-1 at a load of 150 g of toluene m-3pb h-1. Such a removal rate with a trickle-bed reactor was not reported before. Copyright 1998 John Wiley & Sons, Inc.

  4. Numerical simulation for debris bed behavior in sodium cooled fast reactor

    International Nuclear Information System (INIS)

    Tagami, Hirotaka; Tobita, Yoshiharu

    2014-01-01

    For safety analysis of SFR, it is necessary to evaluate behavior along with coolability of debris bed in lower plenum which is formed in severe accident. In order to analyze debris behavior, model for dense sediment particles behavior was proposed and installed in SFR safety analysis code SIMMER. SIMMER code could adequately reproduce experimental results simulating the self-leveling phenomena with appropriate model parameters for bed stiffness. In reactor condition, the self-leveling experiment for prototypical debris bed has not been performed. Additionally, the prototypical debris bed consists of non-spherical particles and it is difficult to quantify model parameters. This situation brings sensitivity analysis to investigate effect of model parameters on the self-leveling phenomena of prototypical debris bed in present paper. As initial condition for sensitivity analysis, simple mound-like debris bed in sodium-filled lower plenum in reactor vessel is considered. The bed consists of the mixture of fuel debris of 3,300 kg and steel debris of 1,570 kg. Decay heat is given to this fuel debris. The model parameter is chosen as sensitivity parameter. Sensitivity analysis shows that the model parameters can effect on intensity of self-leveling phenomena and eventual flatness of bed. In all analyses, however, coolant and sodium vapor break the debris bed at mainly center part of bed and the debris is relocated to outside of bed. Through this process, the initial debris bed is almost planarized before re-melting of debris. This result shows that the model parameters affect the self-leveling phenomena, but its effect in the safety analysis of SFRs is limited. (author)

  5. Elemental mercury vapor capture by powdered activated carbon in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Fabrizio Scala; Riccardo Chirone; Amedeo Lancia [Istituto di Ricerche sulla Combustione - CNR, Napoli (Italy)

    2011-06-15

    A bubbling fluidized bed of inert material was used to increase the activated carbon residence time in the reaction zone and to improve its performance for mercury vapor capture. Elemental mercury capture experiments were conducted at 100{sup o}C in a purposely designed 65 mm ID lab-scale pyrex reactor, that could be operated both in the fluidized bed and in the entrained bed configurations. Commercial powdered activated carbon was pneumatically injected in the reactor and mercury concentration at the outlet was monitored continuously. Experiments were carried out at different inert particle sizes, bed masses, fluidization velocities and carbon feed rates. Experimental results showed that the presence of a bubbling fluidized bed led to an increase of the mercury capture efficiency and, in turn, of the activated carbon utilization. This was explained by the enhanced activated carbon loading and gas-solid contact time that establishes in the reaction zone, because of the large surface area available for activated carbon adhesion/deposition in the fluidized bed. Transient mercury concentration profiles at the bed outlet during the runs were used to discriminate between the controlling phenomena in the process. Experimental data have been analyzed in the light of a phenomenological framework that takes into account the presence of both free and adhered carbon in the reactor as well as mercury saturation of the adsorbent. 14 refs., 7 figs.

  6. CFD study on the supercritical carbon dioxide cooled pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Dali, E-mail: ydlmitd@outlook.com; Peng, Minjun; Wang, Zhongyi

    2015-01-15

    Highlights: • An innovation concept of supercritical carbon dioxide cooled pebble bed reactor is proposed. • Body-centered cuboid (BCCa) arrangement is adopted for the pebbles. • S-CO{sub 2} would be a good candidate coolant for using in pebble bed reactor. - Abstract: The thermal hydraulic study of using supercritical carbon dioxide (S-CO{sub 2}), a superior fluid state brayton cycle medium, in pebble bed type nuclear reactor is assessed through computational fluid dynamics (CFD) methodology. Preliminary concept design of this S-CO{sub 2} cooled pebble bed reactor (PBR) is implemented by the well-known KTA heat transfer correlation and Ergun pressure drop equation. Eddy viscosity transport turbulence model is adopted and verified by KTA calculated results. Distributions of the temperature, velocity, pressure and Nusselt (Nu) number of the coolant near the surface of the middle spherical fuel element are obtained and analyzed. The conclusion of the assessment is that S-CO{sub 2} would be a good candidate coolant for using in pebble bed reactor due primarily to its good heat transfer characteristic and large mass density, which could lead to achieve lower pressure drop and higher power density.

  7. Conversion of metallurgical coke and coal using a Coal Direct Chemical Looping (CDCL) moving bed reactor

    International Nuclear Information System (INIS)

    Luo, Siwei; Bayham, Samuel; Zeng, Liang; McGiveron, Omar; Chung, Elena; Majumder, Ankita; Fan, Liang-Shih

    2014-01-01

    Highlights: • Accumulated more than 300 operation hours were accomplished for the moving bed reducer reactor. • Different reactor operation variables were investigated with optimal conditions identified. • High conversions of sub-bituminous coal and bituminous coal were achieved without flow problems. • Co-current and counter-current contact modes were tested and their applicability was discussed. - Abstract: The CLC process has the potential to be a transformative commercial technology for a carbon-constrained economy. The Ohio State University Coal Direct Chemical Looping (CDCL) process directly converts coal, eliminating the need for a coal gasifier oran air separation unit (ASU). Compared to other solid-fuel CLC processes, the CDCL process is unique in that it consists of a countercurrent moving bed reducer reactor. In the proposed process, coal is injected into the middle of the moving bed, whereby the coal quickly heats up and devolatilizes, splitting the reactor roughly into two sections with no axial mixing. The top section consists of gaseous fuel produced from the coal volatiles, and the bottom section consists of the coal char mixed with the oxygen carrier. A bench-scale moving bed reactor was used to study the coal conversion with CO 2 as the enhancing gas. Initial tests using metallurgical cokefines as feedstock were conducted to test the effects of operational variables in the bottom section of the moving bed reducer, e.g., reactor temperature, oxygen carrier to char ratio, enhancer gas CO 2 flow rate, and oxygen carrier flow rates. Experiments directly using coal as the feedstock were subsequently carried out based on these test results. Powder River Basin (PRB) coal and Illinois #6 coal were tested as representative sub-bituminous and bituminous coals, respectively. Nearly complete coal conversion was achieved using composite iron oxide particles as the oxygen carriers without any flow problems. The operational results demonstrated that a

  8. Evaluation of Packed-Bed Reactor and Continuous Stirred Tank Reactor for the Production of Colchicine Derivatives

    OpenAIRE

    Dubey, Kashyap Kumar; Kumar, Dhirendra; Kumar, Punit; Haque, Shafiul; Jawed, Arshad

    2013-01-01

    Bioconversion of colchicine into its pharmacologically active derivative 3-demethylated colchicine (3-DMC) mediated by P450BM3 enzyme is an economic and promising strategy for the production of this inexpensive and potent anticancer drug. Continuous stirred tank reactor (CSTR) and packed-bed reactor (PBR) of 3 L and 2 L total volumes were compared for the production of 3-demethylated colchicine (3-DMC) a colchicine derivative using Bacillus megaterium MTCC*420 under aerobic conditions. Statis...

  9. Transformation of 1,1,1-trichloroethane in an anaerobic packed-bed reactor at various concentrations of 1,1,1-trichloroethane, acetate and sulfate

    NARCIS (Netherlands)

    deBest, JH; Jongema, H; Weijling, A; Doddema, HJ; Janssen, DB; Harder, W

    Biotransformation of 1,1,1-trichloroethane (CH3CCl3) was observed in an anaerobic packed-bed reactor under conditions of both sulfate reduction and methanogenesis. Acetate (1 mM) served as an electron donor. CH3CCl3 was completely converted up to the highest investigated concentration of 10 mu M.

  10. Structural characterisation of pretreated solids from flow-through liquid hot water treatment of sugarcane bagasse in a fixed-bed reactor

    CSIR Research Space (South Africa)

    Reddy, P

    2015-05-01

    Full Text Available Untreated sugarcane bagasse and sugarcane bagasse pretreated with flow-through liquid hot water (LHW) treatment (170-207°C and 204-250 ml/min) in a fixed-bed reactor have been structurally characterised. Field emission gun scanning electron...

  11. Pebble bed test reactor in peu-a-peu load

    International Nuclear Information System (INIS)

    Kranz, L.

    1988-03-01

    The presented work deals with a new type of load model for high temperature reactors with spherical fuels: the peu-a-peu load system. Using this load system the reactor core is only filled partially in the beginning of the power operation. But it has to be a critical base core. With proceeding burn-off the reactor is filled up with further fuel elements the way that it stays always just critically. When the reactor is filled up completely with fuel elements, the reactor operation has to be interrupted and the reactor has to be discharged. Afterwards a new cycle can start like the one just described. A reference reactor with 100 MW thermal power is investigated in this work in detail and should make clear the way of function of the load system and the base idea of 'simplicity and safety'. The improvement proposal to use again a part of the fuel elements of a cycle for the next cycle minimizes the higher specific uranium need of a peu-a-peu reactor decisively. (orig.) [de

  12. Pebble bed reactor fiscal year 1980: review summary report

    International Nuclear Information System (INIS)

    1980-07-01

    Information on high-temperature reactor development is presented concerning reactor operating experience; core performance assessment; core control and shutdown; reflector and core support; maintenance and availability; safety aspects of PBR and prismatic comparison; PCRV dimensions; and fuel reprocessing cost estimate

  13. Thermal-hydraulic analysis techniques for axisymmetric pebble bed nuclear reactor cores

    International Nuclear Information System (INIS)

    Stroh, K.R.

    1979-03-01

    The pebble bed reactor's cylindrical core volume contains a random bed of small, spherical fuel-moderator elements. These graphite spheres, containing a central region of dispersed coated-particle fissile and fertile material, are cooled by high pressure helium flowing through the connected interstitial voids. A mathematical model and numerical solution technique have been developed which allow calculation of macroscopic values of thermal-hydraulic variables in an axisymmetric pebble bed nuclear reactor core. The computer program PEBBLE is based on a mathematical model which treats the bed macroscopically as a generating, conducting porous medium. The steady-state model uses a nonlinear Forchheimer-type relation between the coolant pressure gradient and mass flux, with newly derived coefficients for the linear and quadratic resistance terms. The remaining equations in the model make use of mass continuity, and thermal energy balances for the solid and fluid phases

  14. The effects of baffles and gas superficial velocity on a bubble fluidized bed reactor's applications

    International Nuclear Information System (INIS)

    Ghorbanpour, A.; Ghannadi Maragheh, M.; Mallah, M. H.

    2008-01-01

    Baffles are used for decreasing bubbles diameter in order to increase the conversion rate along the bubbling fluidized bed reactors. The appearance of this phenomenon is due to bursting of the bubbles during the pass of bubbles from baffles. In this work, a computerized modeling and simulation have been performed in order to obtain a fundamental knowledge of the influence of the baffles on the bubble diameter and the specific mass transfer area. The height of the bed is 5 meters and its diameter is 0.3 meter. Baffles are located at 1 and 2 meters from the bottom of the bed. A two phase model together with a comprehensive fluid dynamical description of bubbling fluidized is presented. The effects of baffles and gas superficial velocity on the operating behavior of fluidized bed reactors are considered. The results are compared to the previously reported documents, and the experiments which have been carried out. MATLAB software is used in this simulation

  15. Combustion in fluidized bed reactors; Verbrennung in Wirbelschichtreaktoren

    Energy Technology Data Exchange (ETDEWEB)

    Thome-Kozmiensky, Karl J. [vivis CONSULT GmbH, Nietwerder (Germany)

    2013-03-01

    Since the first application for the coal gasification, the fluidized bed technology has passed an impressive development. Nowadays, the fluidized bed technology is utilized at chemical processes, drying and cooling, gasification, combustion and purification of exhaust gas. In the firing technology, the fluidized technology initially has been proved in the combustion of very high ash coal and sewage sludge. Recently, the fluidized bed technology also is applied in the drying of sewage sludge, combustion of domestic waste - as in Japan and Sweden - as well as in the gasification and combustion of substitute fuels, biomass - wood pellets, wood chips, straw, cocoa shells and so forth - and residues from the paper manufacturing - such as in Germany and Austria. Under this aspect, the author of the contribution under consideration reports on the combustion of sewage sludge, substitute fuels and biomass.

  16. Thermal denitrification of evaporators concentrates in reactor with fluidized bed

    International Nuclear Information System (INIS)

    Brugnot, C.

    1993-11-01

    As part of the treatments of liquid wastes coming from the Marcoule reprocessing plant, the study of a thermal denitrification process for evaporator concentrates has been chosen by the CEA/CEN Cadarache: the fluidized-bed calcination. This work presents the study of a calcination pilot-plant for wastes with a very high sodium nitrate content. After a reactional analysis carried out in a thermobalance on samples which are representative of the fluidized-bed compounds, the perfecting of many of the plant parameters - such as the solution injection system - was carried out on a scale-model at first. Then, it was verified on the pilot-plant, and some experiments have been carried out. A mathematical model for the particle growth inside the fluidized-bed is proposed. (author). 179 refs., 65 figs., 23 tabs

  17. Simulation of petcoke gasification in slagging moving bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Nagpal, Soumitro; Sarkar, T.K.; Sen, P.K. [Research and Development Center, Engineers India Limited, Gurgaon 122001 (India)

    2005-03-25

    A mathematical model for simulation of moving bed petcoke gasifiers was developed. The model introduces a new feed characterization method, gas-phase resistance and volatilization models. The model is validated using reported data for a slagging gasifier. Effect of feed oxygen-to-coke and steam-to-coke ratios and feed coke rates on gasification performance was examined. Slagging zone moving bed gasifier operation with very high petcoke fluxes of over 4000 kg/m{sup 2}/h was possible with high petcoke conversion. Peak gas temperatures exceeded 1500 {sup o}C. Fluxes higher than 5000 kg/m{sup 2}/h are limited by an approach to fluidization of small particles in the combustion zone. The moving bed gasifier performance was found superior to performance of an entrained flow gasifier (EFG) with respect to energy efficiency and oxygen consumption.

  18. Thermo-catalytic pyrolysis of waste polyethylene bottles in a packed bed reactor with different bed materials and catalysts

    International Nuclear Information System (INIS)

    Obeid, Farah; Zeaiter, Joseph; Al-Muhtaseb, Ala’a H.; Bouhadir, Kamal

    2014-01-01

    Highlights: • Thermo-catalytic pyrolysis of waste polyethylene bottles was investigated. • The highest yield of liquid (82%) was obtained over a cement powder bed. • Acidic catalysts narrowed the carbon chain length of the paraffins to C 10 –C 28 . • Combination of cement bed with HBeta catalyst gave the highest yield of liquid. • Significant yield of aromatics was obtained mainly naphthalene and D-limonene. - Abstract: Plastic waste is an increasing economic and environmental problem as such there is a great need to process this waste and reduce its environmental impact. In this work, the pyrolysis of high density polyethylene (HDPE) waste products was investigated using both thermal and catalytic cracking techniques. The experimental work was carried out using packed bed reactor operating under an inert atmosphere at 450 °C. Different reactor bed materials, including sand, cement and white clay were used to enhance the thermal cracking of HDPE. In addition, the catalytic effect of sodium hydroxide, HUSY and HBeta zeolite catalysts on the degradation of HDPE waste was also investigated. The reactor beds were found to significantly alter the yield as well as the product composition. Products such as paraffins (⩽C 44 ), olefins (⩽C 22 ), aromatics (⩽C 14 ) and alcohols (C 16 and C 17 ) were obtained at varying rates. The highest yield of liquid (82%) was obtained over a cement powder bed with a paraffin yield of 58%. The yield of paraffins and olefins followed separate paths, for paraffins it was found to increase in the order or Cement > White clay > Silica Sand, whereas for the olefins it was in the reverse order Silica Sand > White clay > Cement. The results obtained in this work exhibited a higher P/O ratio than expected, where the amount of generated paraffins was greater than 60% in most cases. Less olefin was generated as a consequence. This indicates that the product generated is more suited to be used as a fuel rather than as a chemical

  19. Pellet bed reactor for nuclear propelled vehicles: Part 2: Missions and vehicle integration trades

    International Nuclear Information System (INIS)

    Haloulakos, V.E.

    1991-01-01

    Mission and vehicle integration tradeoffs involving the use of the pellet bed reactor (PBR) for nuclear powered vehicles is discussed, with much of the information being given in viewgraph form. Information is given on propellant tank geometries, shield weight requirements for conventional tank configurations, effective specific impulse, radiation mapping, radiation dose rate after shutdown, space transfer vehicle design data, a Mars mission summary, sample pellet bed nuclear orbit transfer vehicle mass breakdown, and payload fraction vs. velocity increment

  20. Pellet bed reactor for nuclear propelled vehicles: Part 2: Missions and vehicle integration trades

    Science.gov (United States)

    Haloulakos, V. E.

    1991-01-01

    Mission and vehicle integration tradeoffs involving the use of the pellet bed reactor (PBR) for nuclear powered vehicles is discussed, with much of the information being given in viewgraph form. Information is given on propellant tank geometries, shield weight requirements for conventional tank configurations, effective specific impulse, radiation mapping, radiation dose rate after shutdown, space transfer vehicle design data, a Mars mission summary, sample pellet bed nuclear orbit transfer vehicle mass breakdown, and payload fraction vs. velocity increment.

  1. Rotary Bed Reactor for Chemical-Looping Combustion with Carbon Capture. Part 1: Reactor Design and Model Development

    KAUST Repository

    Zhao, Zhenlong; Chen, Tianjiao; Ghoniem, Ahmed F.

    2013-01-01

    Chemical-looping combustion (CLC) is a novel and promising technology for power generation with inherent CO2 capture. Currently, almost all of the research has been focused on developing CLC-based interconnected fluidized-bed reactors. In this two

  2. Chemical looping reforming in packed-bed reactors : modelling, experimental validation and large-scale reactor design

    NARCIS (Netherlands)

    Spallina, V.; Marinello, B.; Gallucci, F.; Romano, M.C.; van Sint Annaland, M.

    This paper addresses the experimental demonstration and model validation of chemical looping reforming in dynamically operated packed-bed reactors for the production of H2 or CH3OH with integrated CO2 capture. This process is a combination of auto-thermal and steam methane reforming and is carried

  3. Burnup performance of OTTO cycle pebble bed reactors with ROX fuel

    International Nuclear Information System (INIS)

    Ho, Hai Quan; Obara, Toru

    2015-01-01

    Highlights: • A 300 MW t Small Pebble Bed Reactor with Rock-like oxide fuel is proposed. • Using ROX fuel can achieve high discharged burnup of spent fuel. • High geological stability can be expected in direct disposal of the spent ROX fuel. • The Pebble Bed Reactor with ROX fuel can be critical at steady state operation. • All the reactor designs have a negative temperature coefficient. - Abstract: A pebble bed high-temperature gas-cooled reactor (PBR) with rock-like oxide (ROX) fuel was designed to achieve high discharged burnup and improve the integrity of the spent fuel in geological disposal. The MCPBR code with a JENDL-4.0 library, which developed the analysis of the Once-Through-Then-Out (OTTO) cycle in PBR, was used to perform the criticality and burnup analysis. Burnup calculations for eight cases were carried out for both ROX fuel and a UO 2 fuel reactor with different heavy-metal loading conditions. The effective multiplication factor of all cases approximately equalled unity in the equilibrium condition. The ROX fuel reactor showed lower FIFA than the UO 2 fuel reactor at the same heavy-metal loading, about 5–15%. However, the power peaking factor and maximum power per fuel ball in the ROX fuel core were lower than that of UO 2 fuel core. This effect makes it possible to compensate for the lower-FIFA disadvantage in a ROX fuel core. All reactor designs had a negative temperature coefficient that is needed for the passive safety features of a pebble bed reactor

  4. Comparison of Several Thermal Conductivity Constants for Thermal Hydraulic Calculation of Pebble Bed Reactor

    Science.gov (United States)

    Irwanto, Dwi; Setiadipura, Topan; Pramutadi, Asril

    2017-07-01

    There are two type of High Temperature Gas Reactor (HTGR), prismatic and pebble bed. Pebble Bed type has unique configuration because the fuels are randomly distributed inside the reactor core. In term of safety features, Pebble Bed Reactor (PBR) is one of the most promising reactor type in avoiding severe nuclear accidents. In order to analyze heat transfer and safety of this reactor type, a computer code is now under development. As a first step, calculation method proposed by Stroh [1] is adopted. An approach has been made to treat randomly distributed pebble balls contains fissile material inside the reactor core as a porous medium. Helium gas act as coolant on the reactor system are carrying heat flowing in the area between the pebble balls. Several parameters and constants are taken into account in the new developed code. Progress of the development of the code especially comparison of several thermal conductivity constants for a certain PBR-case are reported in the present study.

  5. Gasification of Coal and PET in Fluidized Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Pohořelý, Michael; Vosecký, Martin; Kameníková, Petra; Punčochář, Miroslav; Skoblia, Sergej; Staf, M.; Vošta, J.; Koutský, B.; Svoboda, Karel

    2006-01-01

    Roč. 85, 17-18 (2006), s. 2458-2468 ISSN 0016-2361 R&D Projects: GA ČR(CZ) GA104/04/0829 Institutional research plan: CEZ:AV0Z40720504 Keywords : fludized bed * gasification * plastic waste Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.358, year: 2006

  6. Styrene biofiltration in a trickle-bed reactor

    Directory of Open Access Journals (Sweden)

    V. Novak

    2008-04-01

    Full Text Available The biological treatment of styrene waste gas in a trickle-bed filter (TBF was investigated. The bioreactor consisted of a two-part glass cylinder (ID 150 mm filled with 25 mm polypropylene Pall rings serving as packing material. The bed height was 1m. Although the laboratory temperature was maintained at 22 ºC, the water temperature in the trickle-bed filter was slightly lower (about 18 ºC.The main aim of our study was to observe the effect of empty-bed residence time (EBRT on bioreactor performance at a constant pollutant concentration over an extended time period. The bioreactor was inoculated with a mixed microbial consortium isolated from a styrene-degrading biofilter that had been running for the previous two years. After three weeks of acclimation period, the bioreactor was loaded with styrene (100 mg.m-3. EBRT was in the range of 53 s to 13 s. A maximum elimination capacity (EC of 11.3 gC.m-3.h-1 was reached at an organic loading (OL rate of 18.6 gC.m-3.h-1.

  7. Determination of pressure distribution in an aerated bed in a controlled pilot-scale compost reactor

    Energy Technology Data Exchange (ETDEWEB)

    Solowiej, P. [Warmia and Mazury Univ., Olsztyn (Poland)

    2010-07-01

    This study investigated the effectiveness of dealing with biological waste by composting. In particular, it examined the feasibility of recovering excess thermal energy produced in the process of composting biological waste in terms of mass and energy transport parameters required in the aerated compost bed. An experiment was performed in which a 100 dm{sup 3} adiabatic, leak-tight reactor equipped with a controlled aeration system was constructed to study the temperature and pressure distribution in the bed. Sensors were used to determine the amount and humidity of emitted gases under variable external physical conditions. The perforated bottom of the reactor allowed for bed aeration. As such, the humidity and heat were transported upwards, forced by the air pumped in and by natural convection. In terms of pressure distribution inside the composted and aerated bed, the study results showed that there were considerable differences in pressure for the selected places of the bed of the composted biological material. An increase in upwards pressure was observed in the heap throughout the experiment. Pressure differences in the same plane of the bed were also noted. The study results should facilitate the development of a model of mass and energy transport in a bed of composted material.

  8. Discussion on Design Transients of Pebble-bed High Temperature Gas-cooled Reactor

    International Nuclear Information System (INIS)

    Wang Yan; Li Fu; Zheng Yanhua

    2014-01-01

    In order to assure high quality for the components and their supports in the reactor coolant system, etc., some thermal-hydraulic transient conditions will be selected and researched for equipment design evaluation to satisfy the requirements ASME code, which are based on the conservative estimates of the magnitude and frequency of the temperature and pressure transients resulting from various operating conditions in the plant. In the mature design on pressurized water reactor, five conditions are considered. For the developing advanced pebble-bed high temperature gas-cooled reactor(HTGR), its design and operation has much difference with other reactors, so the transients of the pebble-bed high temperature gas-cooled reactor have distinctive characteristics. In this paper, the possible design transients of the pebble-bed HTGR will be discussed, and the frequency of design transients for equipment fatigue analysis and stress analysis due to cyclic stresses is also studied. The results will provide support for the design and construct of the pebble-bed HTGR. (author)

  9. Air gasification of rice husk in bubbling fluidized bed reactor with bed heating by conventional charcoal.

    Science.gov (United States)

    Makwana, J P; Joshi, Asim Kumar; Athawale, Gaurav; Singh, Dharminder; Mohanty, Pravakar

    2015-02-01

    An experimental study of air gasification of rice husk was conducted in a bench-scale fluidized bed gasifier (FBG) having 210 mm diameter and 1600 mm height. Heating of sand bed material was performed using conventional charcoal fuel. Different operating conditions like bed temperature, feeding rate and equivalence ratio (ER) varied in the range of 750-850 °C, 25-31.3 kg/h, and 0.3-0.38, respectively. Flow rate of air was kept constant (37 m(3)/h) during FBG experiments. The carbon conversion efficiencies (CCE), cold gas efficiency, and thermal efficiency were evaluated, where maximum CCE was found as 91%. By increasing ER, the carbon conversion efficiency was decreased. Drastic reduction in electric consumption for initial heating of gasifier bed with charcoal compared to ceramic heater was ∼45%. Hence rice husk is found as a potential candidate to use directly (without any processing) in FBG as an alternative renewable energy source from agricultural field. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. The influence of bamboo-packed configuration to mixing characteristics in a fixed-bed reactor

    Science.gov (United States)

    Detalina, M.; Pradanawati, S. A.; Widyarani; Mamat; Nilawati, D.; Sintawardani, N.

    2018-03-01

    Fixed-bed reactors are commonly used as bioreactors for various applications, including chemicals production and organic wastewater treatment. Bioreactors are fixed with packing materials for attaching microorganisms. Packing materials should have high surface area and enable sufficient fluid flow in the reactor. Natural materials e.g. rocks and fibres are often used as packing materials. Commercially, packing materials are also produced from polymer with the advantage of customizable shapes. The objective of this research was to study the mixing pattern in a packed-bed reactor using bamboo as packing material. Bamboo was selected for its pipe-like and porous form, as well as its abundant availability in Indonesia. The cut bamboo sticks were installed in a reactor in different configurations namely vertical, horizontal, and random. Textile dye was used as a tracer. Our results show that the vertical configuration gave the least liquid resistant flow. Yet, the random configuration was the best configuration during mixing process.

  11. Simultaneous nitrification-denitrification and phosphorus removal in a fixed bed sequencing batch reactor (FBSBR)

    International Nuclear Information System (INIS)

    Rahimi, Yousef; Torabian, Ali; Mehrdadi, Naser; Shahmoradi, Behzad

    2011-01-01

    Research highlights: → Sludge production in FSBR reactor is 20-30% less than SBR reactor. → FSBR reactor showed more nutrient removal rate than SBR reactor. → FSBR reactor showed less VSS/TSS ratio than SBR reactor. - Abstract: Biological nutrient removal (BNR) was investigated in a fixed bed sequencing batch reactor (FBSBR) in which instead of activated sludge polypropylene carriers were used. The FBSBR performance on carbon and nitrogen removal at different loading rates was significant. COD, TN, and phosphorus removal efficiencies were at range of 90-96%, 60-88%, and 76-90% respectively while these values at SBR reactor were 85-95%, 38-60%, and 20-79% respectively. These results show that the simultaneous nitrification-denitrification (SND) is significantly higher than conventional SBR reactor. The higher total phosphorus (TP) removal in FBSBR correlates with oxygen gradient in biofilm layer. The influence of fixed media on biomass production yield was assessed by monitoring the MLSS concentrations versus COD removal for both reactors and results revealed that the sludge production yield (Y obs ) is significantly less in FBSBR reactors compared with SBR reactor. The FBSBR was more efficient in SND and phosphorus removal. Moreover, it produced less excess sludge but higher in nutrient content and stabilization ratio (less VSS/TSS ratio).

  12. Simultaneous nitrification-denitrification and phosphorus removal in a fixed bed sequencing batch reactor (FBSBR)

    Energy Technology Data Exchange (ETDEWEB)

    Rahimi, Yousef, E-mail: you.rahimi@gmail.com [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Torabian, Ali, E-mail: atorabi@ut.ac.ir [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Mehrdadi, Naser, E-mail: mehrdadi@ut.ac.ir [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Shahmoradi, Behzad, E-mail: bshahmorady@gmail.com [Department of Environmental Science, University of Mysore, MGM-06 Mysore (India)

    2011-01-30

    Research highlights: {yields} Sludge production in FSBR reactor is 20-30% less than SBR reactor. {yields} FSBR reactor showed more nutrient removal rate than SBR reactor. {yields} FSBR reactor showed less VSS/TSS ratio than SBR reactor. - Abstract: Biological nutrient removal (BNR) was investigated in a fixed bed sequencing batch reactor (FBSBR) in which instead of activated sludge polypropylene carriers were used. The FBSBR performance on carbon and nitrogen removal at different loading rates was significant. COD, TN, and phosphorus removal efficiencies were at range of 90-96%, 60-88%, and 76-90% respectively while these values at SBR reactor were 85-95%, 38-60%, and 20-79% respectively. These results show that the simultaneous nitrification-denitrification (SND) is significantly higher than conventional SBR reactor. The higher total phosphorus (TP) removal in FBSBR correlates with oxygen gradient in biofilm layer. The influence of fixed media on biomass production yield was assessed by monitoring the MLSS concentrations versus COD removal for both reactors and results revealed that the sludge production yield (Y{sub obs}) is significantly less in FBSBR reactors compared with SBR reactor. The FBSBR was more efficient in SND and phosphorus removal. Moreover, it produced less excess sludge but higher in nutrient content and stabilization ratio (less VSS/TSS ratio).

  13. Design of a power conversion system for an indirect cycle, helium cooled pebble bed reactor system

    International Nuclear Information System (INIS)

    Wang, C.; Ballinger, R.G.; Stahle, P.W.; Demetri, E.; Koronowski, M.

    2002-01-01

    A design is presented for the turbomachinery for an indirect cycle, closed, helium cooled modular pebble bed reactor system. The design makes use of current technology and will operate with an overall efficiency of 45%. The design uses an intermediate heat exchanger which isolated the reactor cycle from the turbomachinery. This design excludes radioactive fission products from the turbomachinery. This minimizes the probability of an air ingress accident and greatly simplifies maintenance. (author)

  14. CFD Model of HDS Catalyst Tests in Trickle-Bed Reactor

    OpenAIRE

    Tukač, V.

    2014-01-01

    The goal of this study was to evaluate hydrodynamic influence on experimental HDS catalyst activity measurement carried out in pilot scale trickle-bed reactor. Hydrodynamic data were evaluated by RTD method in laboratory glass model of pilot reactor. Mathematical models of the process were formulated both like 1D pseudohomogeneou and 3D heterogeneous ones. The aim of this work was to forecast interaction between intrinsic reaction kinetic, hydrodynamics and mass transfer.

  15. Probabilistic safety assessment framework of pebble-bed modular high-temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Liu Tao; Tong Jiejuan; Zhao Jun; Cao Jianzhu; Zhang Liguo

    2009-01-01

    After an investigation of similar reactor type probabilistic safety assessment (PSA) framework, Pebble-bed Modular High-Temperature Gas-cooled Reactor (HTR-PM) PSA framework was presented in correlate with its own design characteristics. That is an integral framework which spreads through event sequence structure with initiating events at the beginning and source term categories in the end. The analysis shows that it is HTR-PM design feature that determines its PSA framework. (authors)

  16. Development of a safeguards system for the THTR pebble bed reactor

    International Nuclear Information System (INIS)

    Engelhardt, H.

    1978-08-01

    This report provides a survey of the technical possibilities of safeguarding the THTR-300 pebble bed reactor in accordance with the NPT. Description of the reactor system, the operational mode, and the operator's material control system are presented in Sections 2, 3 and 4. A suggested safeguards approach which is based on an item counting of pebble elements with containment and surveillance as a supplementary measure is described in the Sections 5 and 6

  17. Carbon Shale Combustion in the Fluidized Bed Reactor

    Directory of Open Access Journals (Sweden)

    Olek Małgorzata

    2014-06-01

    Full Text Available The purpose of this article is to present the possibilities of coal shale combustion in furnaces with bubbling fluidized bed. Coal shale can be autothermally combusted in the fluidized bed, despite the low calorie value and high ash content of fuel. Established concentrations of CO (500 ppm and VOC (30 mg/m3 have indicated a high conversion degree of combustible material during combustion process. Average concentrations of SO2 and NOx in the flue gas were higher than this received from the combustion of high quality hard coal, 600 ppm and 500 ppm, respectively. Optional reduction of SO2 and NOx emission may require the installation of flue gas desulphurization and de-NOx systems.

  18. Experimental, kinetic and numerical modeling of hydrogen production by catalytic reforming of crude ethanol over a commercial catalyst in packed bed tubular reactor and packed bed membrane reactor

    International Nuclear Information System (INIS)

    Aboudheir, Ahmed; Akande, Abayomi; Idem, Raphael

    2006-01-01

    The demand for hydrogen energy has increased tremendously in recent years essentially because of the increase in the word energy consumption as well as recent developments in fuel cell technologies. The energy information administration has projected that world energy consumption will increase by 59% over the next two decades, from 1999 to 2020, in which the largest share is still dominated by fossil fuels (oil, natural gas and coal). Carbon dioxide (CO 2 ) emissions resulting from the combustion of these fossil fuels currently are estimated to account for three-fourth of human-caused CO 2 emissions worldwide. Greenhouse gas emission, including CO 2 , should be limited, as recommended at the Kyoto Conference, Japan, in December 1997. In this regard, hydrogen (H 2 ) has a significant future potential as an alternative fuel that can solve the problems of CO 2 emissions as well as the emissions of other air contaminants. One of the techniques to produce hydrogen is by reforming of hydrocarbons or biomass. Crude ethanol (a form of biomass, which essentially is fermentation broth) is easy to produce, is free of sulphur, has low toxicity, and is also safe to handle, transport and store. In addition, crude ethanol consists of oxygenated hydrocarbons, such as ethanol, lactic acid, glycerol, and maltose. These oxygenated hydrocarbons can be reformed completely to H 2 and CO 2 , the latter of which could be separated from H 2 by membrane technology. This provides for CO 2 capture for eventual storage or destruction. In the case of using crude ethanol, this will result in negative CO 2 , emissions. In this paper, we conducted experimental work on production of hydrogen by the catalytic reforming of crude ethanol over a commercial promoted Ni-based catalyst in a packed bed tubular reactor as well as a packed bed membrane reactor. As well, a rigorous numerical model was developed to simulate this process in both the catalytic packed bed tubular reactor and packed bed membrane

  19. Sludge combustion in fluidized bed reactors at laboratory scale

    International Nuclear Information System (INIS)

    Chirone, R.; Cammarota, A.

    2001-01-01

    The combustion of a dried sewage sludge in laboratory scale fluidized bed has been studied in Naples by the Istituto di ricerche sulla combustione (Irc) in the framework of a National project named Thermal Process with Energy Recovery to be used in laboratory and pre-pilot scale apparatus. The attention has been focused on emissions of unreacted carbon as elutriated fines, on the emissions of pollutant gases and on the assessment of the inventory of fly- and bottom ashes. The combustion behaviour of sewage sludge has been compared with those of a market available Tyre Derived Fuel (TDF) and a biomass from Mediterranean area (Robinia Pseudoacacia) and with that of a South African bituminous coal. Stationary combustion tests were carried out at 850 0 C by feeding particles in the size range 0-1 mm into a bed of silica sand without any sorbent addition. The fluidized bed combustor has been operated, at a superficial gas velocity of 0.4 m/s and different excesses of air ranging between 14 and 98%. Relatively high combustion efficiency, larger than 98.9% has been obtained in experiments carried out with sewage sludge and excess of air larger than 20%. These values, are comparable with those obtained in previously experimental activity carried out under similar operative conditions with a South Africa Bituminous coal (97-98%). It is larger than those obtained by using a Tyre Derived Fuel (89-90%) and the Robinia Pseudoacacia Biomass (93-93%). The relative importance of carbon fines elutriation, CO emissions and volatile bypassing the bed in determining the loss of combustion efficiency has been evaluated for the different fuels tested [it

  20. Gasification of wood in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, L.C. de; Marti, T; Frankenhaeuser, M [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    A first series of gasification experiments with our fluidized bed gasifier was performed using clean sawdust as fuel. The installation and the analytical systems were tested in a parametric study in which gasification temperature and equivalence ratio were varied. The data acquired will serve to establish the differences between the gasification of clean wood and the gasification of Altholz (scrapwood) and wood/plastics mixtures. (author) 1 fig., 3 tabs., 5 refs.

  1. Comparison of the Effects of Fluidized-Bed and Fixed-Bed Reactors in Microwave-Assisted Catalytic Decomposition of TCE by Hydrogen

    Directory of Open Access Journals (Sweden)

    Lili Ren

    2012-01-01

    Full Text Available Trichloroethylene (TCE decomposition by hydrogen with microwave heating under different reaction systems was investigated. The activities of a series of catalysts for microwave-assisted TCE hydrodechlorination were tested through the fixed-bed and the fluidized-bed reactor systems. This study found that the different reaction system is suitable for different catalyst type. And there is an interactive relationship between the catalyst type and the reaction bed type.

  2. Distributed secondary gas injection via a fractal injector : A nature-inspired approach to improving conversion in fluidized bed reactors

    NARCIS (Netherlands)

    Christensen, D.O.

    2008-01-01

    The conversion in bubbling fluidized bed reactors is suppressed because the interphase mass transfer and gas-solid contact in bubbling fluidized bed reactors are often poor. Most of the gas is present in the form of bubbles, which have low surface-to-volume ratios and are nearly devoid of catalyst

  3. Design and development of fluidized bed reactor system for production of trichlorosilane as a precursor for high purity silicon

    International Nuclear Information System (INIS)

    Kumar, Rajesh; Mohan, Sadhana; Bhanja, K.; Nayak, S.; Bhattacharya, S.K.

    2009-01-01

    Trichlorosilane is widely used as precursor material for production of high purity silicon. It is mainly produced by reaction of metallurgical grade silicon with anhydrous HCl gas in a fluidized bed reactor. To develop this process on commercial scale a pilot size fluidized bed reactor system was designed and developed and successfully operated. This paper discusses the critical issues related to these activities. (author)

  4. Transient Effects in Fischer-Tropsch Reactor with a Fixed Bed of Catalyst Particles

    Directory of Open Access Journals (Sweden)

    I. V. Derevich

    2015-01-01

    Full Text Available Based on analysis of small temperature disturbances in the Fischer-Tropsch reactor with a fixed bed of catalyst particles various scenarios of thermal instability were investigated. There are two possible scenarios of thermal instability of the reactor. First, thermal explosion may occur due to growth of temperature disturbances inside a catalytic granule. Second scenario connected with loss of thermal stability as a result of an initial increase in temperature in the reactor volume. The boundaries of thermal stability of the reactor were estimated by solving the eigenvalue problems for spherical catalyst particles and cylindrical reactor. Processes of diffusional resistance inside the catalytic granule and heat transfer from wall of the reactor tube are taken into account. Estimation of thermal stability area is compared with the results of numerical simulation of behavior of temperature and concentration of synthesis gas.

  5. Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor

    Science.gov (United States)

    Ramos, A.; Filtvedt, W. O.; Lindholm, D.; Ramachandran, P. A.; Rodríguez, A.; del Cañizo, C.

    2015-12-01

    Polysilicon production costs contribute approximately to 25-33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward to design and build large scale polysilicon manufacturing plants. In this paper we present thermal models for two processes for poly production, viz., the Siemens process using trichlorosilane (TCS) as precursor and the fluid bed process using silane (monosilane, MS). We validate the models with some experimental measurements on prototype laboratory reactors relating the temperature profiles to product quality. A model sensitivity analysis is also performed, and the effects of some key parameters such as reactor wall emissivity and gas distributor temperature, on temperature distribution and product quality are examined. The information presented in this paper is useful for further understanding of the strengths and weaknesses of both deposition technologies, and will help in optimal temperature profiling of these systems aiming at lowering production costs without compromising the solar cell quality.

  6. A Pebble-Bed Breed-and-Burn Reactor

    International Nuclear Information System (INIS)

    Greenspan, Ehud

    2016-01-01

    The primary objective of this project is to use three-dimensional fuel shuffling in order to reduce the minimum peak radiation damage of ~550 dpa present Breed-and-Burn (B&B) fast nuclear reactor cores designs (they feature 2-D fuel shuffling) call for to as close as possible to the presently accepted value of 200 dpa thereby enabling earlier commercialization of B&B reactors which could make substantial contribution to energy sustainability and economic stability without need for fuel recycling. Another objective is increasing the average discharge burnup for the same peak discharge burnup thereby (1) increasing the fuel utilization of 2-D shuffled B&B reactors and (2) reducing the reprocessing capacity required to support a given capacity of FRs that are to recycle fuel.

  7. A Pebble-Bed Breed-and-Burn Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Greenspan, Ehud [Univ. of California, Berkeley, CA (United States)

    2016-03-31

    The primary objective of this project is to use three-dimensional fuel shuffling in order to reduce the minimum peak radiation damage of ~550 dpa present Breed-and-Burn (B&B) fast nuclear reactor cores designs (they feature 2-D fuel shuffling) call for to as close as possible to the presently accepted value of 200 dpa thereby enabling earlier commercialization of B&B reactors which could make substantial contribution to energy sustainability and economic stability without need for fuel recycling. Another objective is increasing the average discharge burnup for the same peak discharge burnup thereby (1) increasing the fuel utilization of 2-D shuffled B&B reactors and (2) reducing the reprocessing capacity required to support a given capacity of FRs that are to recycle fuel.

  8. Modelling of a falling sludge bed reactor using AQUASIM

    African Journals Online (AJOL)

    drinie

    2001-10-04

    Oct 4, 2001 ... products are then used for the biological treatment of acid mine drainage. A mathematical ... solid matter into three valleys inside the reactor, as opposed to an ... conversion of PSS in the presence of sulphate-reducing bacteria ... indicate substrate flow (stoichiometrically) in the form of COD ..... fermentation.

  9. How to prevent runaways in trickle-bed reactors for Pygas hydrogenation

    NARCIS (Netherlands)

    Westerterp, K.R.; Kronberg, Alexandre E.

    2002-01-01

    In the past, several runaways have occurred in Trickle-Bed Reactors (TBR) used for the hydrogenation of pyrolysis gasoline as produced in ethylene cracking installations. This phenomenon has been studied in the framework of a special program in the Netherlands, which is administered by the National

  10. Optimized core design and fuel management of a pebble-bed type nuclear reactor

    NARCIS (Netherlands)

    Boer, B.

    2009-01-01

    The core design of a pebble-bed type Very High Temperature Reactor (VHTR) is optimized, aiming for an increase of the coolant outlet temperature to 1000 C, while retaining its inherent safety features. The VHTR has been selected by the international Generation IV research initiative as one of the

  11. Fast pyrolysis of biomass in a fluidized bed reactor: in-situ filtering of the vapors

    NARCIS (Netherlands)

    Hoekstra, E.; Hogendoorn, Kees; Wang, X.; Westerhof, Roel Johannes Maria; Kersten, Sascha R.A.; van Swaaij, Willibrordus Petrus Maria; Groeneveld, M.J.

    2009-01-01

    A system to remove in situ char/ash from hot pyrolysis vapors has been developed and tested at the University of Twente. The system consists of a continuous fluidized bed reactor (0.7 kg/h) with immersed filters (wire mesh, pore size 5 μm) for extracting pyrolysis vapors. Integration of the filter

  12. Nature and characteristics of pulsing flow in trickle-bed reactors

    NARCIS (Netherlands)

    Boelhouwer, J.G.; Piepers, H.W.; Drinkenburg, A.A.H.

    2002-01-01

    Pulsing flow is well known for its advantages in terms of an increase in mass and heat transfer rates, complete catalyst wetting and a decrease in axial dispersion compared to trickle flow. The operation of a trickle-bed reactor in the pulsing flow regime is favorable in terms of a capacity increase

  13. Enlargement of the pulsing flow regime by periodic operation of a trickle-bed reactor.

    NARCIS (Netherlands)

    Boelhouwer, J.G.; Piepers, H.W.; Drinkenburg, A.A.H.

    1999-01-01

    Potential advantages of pulsing flow in trickle-bed reactors include capacity increase and elimination of hot spots through the enhanced mass and heat transfer rates. A disadvantage of naturally occurring pulsing flow is the necessity of relatively high gas and liquid flow rates, especially at

  14. Application of point kinetic model in the study of fluidized bed reactor dynamic

    International Nuclear Information System (INIS)

    Borges, Volnei; Vilhena, Marco Tullio de; Streck, Elaine E.

    1995-01-01

    In this work the dynamical behavior of the fluidized bed nuclear reactor is analysed. The main goal consist to study the effect of the acceleration term in the point kinetic equations. Numerical simulations are reported considering constant acceleration. (author). 7 refs, 4 figs

  15. Fabrication of the fuel elements cladding for utilization in the fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Schaeffer, L.; Sefidvash, F.

    1986-01-01

    A method for the fabrication of cladding of the spherical fuel elements for the utilization in the fluidized bed nuclear reactor is presented. Some prelimminary experiments were performed to adopt a method which adapt itself to mass production with the desired high quality. Still methods for cladding fabrication are under study. (Author) [pt

  16. Membrane assisted fluidized bed reactor: experimental demonstration for partial oxidation of methanol

    NARCIS (Netherlands)

    Deshmukh, S.A.R.K.

    2004-01-01

    In this thesis the reactor concept has been developed on the basis of an experimental study on the effect of fluidization conditions on the membrane permeation rate in a MAFBR, the extent of gas back mixing and the tube-to-bed heat transfer rates in the presence of membrane bundles with and without

  17. Modelling of an adiabatic trickle-bed reactor with phase change

    DEFF Research Database (Denmark)

    Ramirez Castelan, Carlos Eduardo; Hidalgo-Vivas, Angelica; Brix, Jacob

    2017-01-01

    This paper describes a modelling approach of the behavior of trickle-bed reactors used for catalytic hydrotreating of oil fractions. A dynamic plug-flow heterogeneous one-dimensional adiabatic model was used to describe the main reactions present in the hydrotreating process: hydrodesulfurization...

  18. CFD-DEM simulation of a conceptual gas-cooled fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Almeida, Lucilla C.; Su, Jian

    2015-01-01

    Several conceptual designs of the fluidized-bed nuclear reactor have been proposed due to its many advantages over conventional nuclear reactors such as PWRs and BWRs. Amongst their characteristics, the enhanced heat transfer and mixing enables a more uniform temperature distribution, reducing the risk of hot-spot and excessive fuel temperature, in addition to resulting in a higher burnup of the fuel. Furthermore, the relationship between the bed height and reactor neutronics turns the coolant flow rate control into a power production mechanism. Moreover, the possibility of removing the fuel by gravity from the movable core in case of a loss-of-cooling accident increases its safety. High-accuracy modeling of particles and coolant flow in fluidized bed reactors is needed to evaluate reliably the thermal-hydraulic efficiency and safety margin. The two-way coupling between solid and fluid can account for high-fidelity solid-solid interaction and reasonable accuracy in fluid calculation and fluid-solid interaction. In the CFD-DEM model, the particles are modeled as a discrete phase, following the DEM approach, whereas the fluid flow is treated as a continuous phase, described by the averaged Navier-Stokes equations on a computational cell scale. In this work, the coupling methodology between Fluent and Rocky is described. The numerical approach was applied to the simulation of a bubbling fluidized bed and the results were compared to experimental data and showed good agreement. (author)

  19. Production of structured lipids in a packed-bed reactor with Thermomyces lanuginosa lipase

    DEFF Research Database (Denmark)

    Xu, Xuebing; Porsgaard, Trine; Zhang, Hong

    2002-01-01

    Lipase-catalyzed interesterification between fish oil and medium-chain TAG has been investigated in a packed-bed reactor with a commercially immobilized enzyme. The enzyme, a Thermomyces lanuginosa lipase immobilized on silica by granulation (Lipozyme TL IM; Novozymes A/S, Bagsvaerd, Denmark), ha...

  20. Consideration of emergency source terms for pebble-bed high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Tao, Liu; Jun, Zhao; Jiejuan, Tong; Jianzhu, Cao

    2009-01-01

    Being the last barrier in the nuclear power plant defense-in-depth strategy, emergency planning (EP) is an integrated project. One of the key elements in this process is emergency source terms selection. Emergency Source terms for light water reactor (LWR) nuclear power plant (NPP) have been introduced in many technical documents, and advanced NPP emergency planning is attracting attention recently. Commercial practices of advanced NPP are undergoing in the world, pebble-bed high-temperature gas-cooled reactor (HTGR) power plant is under construction in China which is considered as a representative of advanced NPP. The paper tries to find some pieces of suggestion from our investigation. The discussion of advanced NPP EP will be summarized first, and then the characteristics of pebble-bed HTGR relating to EP will be described. Finally, PSA insights on emergency source terms selection and current pebble-bed HTGR emergency source terms suggestions are proposed

  1. Computational and experimental prediction of dust production in pebble bed reactors, Part II

    Energy Technology Data Exchange (ETDEWEB)

    Mie Hiruta; Gannon Johnson; Maziar Rostamian; Gabriel P. Potirniche; Abderrafi M. Ougouag; Massimo Bertino; Louis Franzel; Akira Tokuhiro

    2013-10-01

    This paper is the continuation of Part I, which describes the high temperature and high pressure helium environment wear tests of graphite–graphite in frictional contact. In the present work, it has been attempted to simulate a Pebble Bed Reactor core environment as compared to Part I. The experimental apparatus, which is a custom-designed tribometer, is capable of performing wear tests at PBR relevant higher temperatures and pressures under a helium environment. This environment facilitates prediction of wear mass loss of graphite as dust particulates from the pebble bed. The experimental results of high temperature helium environment are used to anticipate the amount of wear mass produced in a pebble bed nuclear reactor.

  2. High flux Particle Bed Reactor systems for rapid transmutation of actinides and long lived fission products

    International Nuclear Information System (INIS)

    Powell, J.; Ludewig, H.; Maise, G.; Steinberg, M.; Todosow, M.

    1993-01-01

    An initial assessment of several actinide/LLFP burner concepts based on the Particle Bed Reactor (PBR) is described. The high power density/flux level achievable with the PBR make it an attractive candidate for this application. The PBR based actinide burner concept also possesses a number of safety and economic benefits relative to other reactor based transmutation approaches including a low inventory of radionuclides, and high integrity, coated fuel particles which can withstand extremely high in temperatures while retaining virtually all fission products. In addition the reactor also posesses a number of ''engineered safety features,'' which, along with the use of high temperature capable materials further enhance its safety characteristics

  3. Degradation of whey in an anaerobic fixed bed (AnFB) reactor

    OpenAIRE

    Handajani, Marisa

    2004-01-01

    An Anaerobic Fixed Bed (AnFB) reactor was run as an upflow anaerobic reactor with an arrangement of supporting material for growth of a biofilm. The supporting material was made from Liapor-clay-polyethylene sinter lamellas (Herding Co., Amberg). The AnFB reactor was used for treating high concentrations of whey-containing wastewater. Optimal operating conditions for whey treatment at a concentration of COD in the influent of around 50 g whey·l-1 were found for a hydraulic retention ...

  4. Effects of random pebble distribution on the multiplication factor in HTR pebble bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Auwerda, G.J., E-mail: g.j.auwerda@tudelft.n [Department of Physics of Nuclear Reactors at the Delft University of Technology, Mekelweg 15, Delft (Netherlands); Kloosterman, J.L.; Lathouwers, D.; Hagen, T.H.J.J. van der [Department of Physics of Nuclear Reactors at the Delft University of Technology, Mekelweg 15, Delft (Netherlands)

    2010-08-15

    In pebble bed reactors the pebbles have a random distribution within the core. The usual approach in modeling the bed is homogenizing the entire bed. To quantify the errors arising in such a model, this article investigates the effect on k{sub eff} of three phenomena in random pebble distributions: non-uniform packing density, neutron streaming in between the pebbles, and variations in Dancoff factor. For a 100 cm high cylinder with reflective top and bottom boundary conditions 25 pebble beds were generated. Of each bed three core models were made: a homogeneous model, a zones model including density fluctuations, and an exact model with all pebbles modeled individually. The same was done for a model of the PROTEUS facility. k{sub eff} calculations were performed with three codes: Monte Carlo, diffusion, and finite element transport. By comparing k{sub eff} of the homogenized and zones model the effect of including density fluctuations in the pebble bed was found to increase k{sub eff} by 71 pcm for the infinite cylinder and 649 pcm for PROTEUS. The large value for PROTEUS is due to the low packing fraction near the top of the pebble bed, causing a significant lower packing fraction for the bulk of the pebble bed in the homogenized model. The effect of neutron streaming was calculated by comparing the zones model with the exact model, and was found to decrease k{sub eff} by 606 pcm for the infinite cylinder, and by 1240 pcm for PROTEUS. This was compared with the effect of using a streaming correction factor on the diffusion coefficient in the zones model, which resulted in {Delta}{sub streaming} values of 340 and 1085 pcm. From this we conclude neutron streaming is an important effect in pebble bed reactors, and is not accurately described by the correction factor on the diffusion coefficient. Changing the Dancoff factor in the outer part of the pebble bed to compensate for the lower probability of neutrons to enter other fuel pebbles caused no significant changes

  5. Experimental and Computational Study of Multiphase Flow Hydrodynamics in 2D Trickle Bed Reactors

    Science.gov (United States)

    Nadeem, H.; Ben Salem, I.; Kurnia, J. C.; Rabbani, S.; Shamim, T.; Sassi, M.

    2014-12-01

    Trickle bed reactors are largely used in the refining processes. Co-current heavy oil and hydrogen gas flow downward on catalytic particle bed. Fine particles in the heavy oil and/or soot formed by the exothermic catalytic reactions deposit on the bed and clog the flow channels. This work is funded by the refining company of Abu Dhabi and aims at mitigating pressure buildup due to fine deposition in the TBR. In this work, we focus on meso-scale experimental and computational investigations of the interplay between flow regimes and the various parameters that affect them. A 2D experimental apparatus has been built to investigate the flow regimes with an average pore diameter close to the values encountered in trickle beds. A parametric study is done for the development of flow regimes and the transition between them when the geometry and arrangement of the particles within the porous medium are varied. Liquid and gas flow velocities have also been varied to capture the different flow regimes. Real time images of the multiphase flow are captured using a high speed camera, which were then used to characterize the transition between the different flow regimes. A diffused light source was used behind the 2D Trickle Bed Reactor to enhance visualizations. Experimental data shows very good agreement with the published literature. The computational study focuses on the hydrodynamics of multiphase flow and to identify the flow regime developed inside TBRs using the ANSYS Fluent Software package. Multiphase flow inside TBRs is investigated using the "discrete particle" approach together with Volume of Fluid (VoF) multiphase flow modeling. The effect of the bed particle diameter, spacing, and arrangement are presented that may be used to provide guidelines for designing trickle bed reactors.

  6. Development of research reactor simulator and its application to dynamic test-bed

    International Nuclear Information System (INIS)

    Kwon, Kee-Choon; Baang, Dane; Park, Jae-Chang; Lee, Seung-Wook; Bae, Sung Won

    2014-01-01

    We developed a real-time simulator for 'High-flux Advanced Neutron Application ReactOr (HANARO), and the Jordan Research and Training Reactor (JRTR). The main purpose of this simulator is operator training, but we modified this simulator into a dynamic test-bed (DTB) to test the functions and dynamic control performance of reactor regulating system (RRS) in HANARO or JRTR before installation. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The software includes a mathematical model that implements plant dynamics in real-time, an instructor station module that manages user instructions, and a human machine interface module. The developed research reactor simulators are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by actual RRS cabinet, and was interfaced using a hard-wired and network-based interface. RRS cabinet generates control signals for reactor power control based on the various feedback signals from DTB, and the DTB runs plant dynamics based on the RRS control signals. Thus the Hardware-In-the-Loop Simulation between RRS and the emulated plant (DTB) has been implemented and tested in this configuration. The test result shows that the developed DTB and actual RRS cabinet works together simultaneously resulting in quite good dynamic control performances. (author)

  7. Failure analysis of pebble bed reactors during earthquake by discrete element method

    International Nuclear Information System (INIS)

    Keppler, Istvan

    2013-01-01

    Highlights: ► We evaluated the load acting on the central reflector beam of a pebble bed reactor. ► The load acting on the reflector beam highly depends on fuel element distribution. ► The contact force values do not show high dependence on fuel element distribution. ► Earthquake increases the load of the reflector, not the contact forces. -- Abstract: Pebble bed reactors (PBR) are graphite-moderated, gas-cooled nuclear reactors. PBR reactors use a large number of spherical fuel elements called pebbles. From mechanical point of view, the arrangement of “small” spherical fuel elements in a container poses the same problem, as the so-called silo problem in powder technology and agricultural engineering. To get more exact information about the contact forces arising between the fuel elements in static and dynamic case, we simulated the static case and the effects of an earthquake on a model reactor by using discrete element method. We determined the maximal contact forces acting between the individual fuel elements. We found that the value of the maximal bending moment in the central reflector beam has a high deviation from the average value even in static case, and it can significantly increase in case of an earthquake. Our results can help the engineers working on the design of such types of reactors to get information about the contact forces, to determine the dust production and the crush probability of fuel elements within the reactor, and to model different accident scenarios

  8. Failure analysis of pebble bed reactors during earthquake by discrete element method

    Energy Technology Data Exchange (ETDEWEB)

    Keppler, Istvan, E-mail: keppler.istvan@gek.szie.hu [Department of Mechanics and Engineering Design, Szent István University, Páter K.u.1., Gödöllő H-2103 (Hungary)

    2013-05-15

    Highlights: ► We evaluated the load acting on the central reflector beam of a pebble bed reactor. ► The load acting on the reflector beam highly depends on fuel element distribution. ► The contact force values do not show high dependence on fuel element distribution. ► Earthquake increases the load of the reflector, not the contact forces. -- Abstract: Pebble bed reactors (PBR) are graphite-moderated, gas-cooled nuclear reactors. PBR reactors use a large number of spherical fuel elements called pebbles. From mechanical point of view, the arrangement of “small” spherical fuel elements in a container poses the same problem, as the so-called silo problem in powder technology and agricultural engineering. To get more exact information about the contact forces arising between the fuel elements in static and dynamic case, we simulated the static case and the effects of an earthquake on a model reactor by using discrete element method. We determined the maximal contact forces acting between the individual fuel elements. We found that the value of the maximal bending moment in the central reflector beam has a high deviation from the average value even in static case, and it can significantly increase in case of an earthquake. Our results can help the engineers working on the design of such types of reactors to get information about the contact forces, to determine the dust production and the crush probability of fuel elements within the reactor, and to model different accident scenarios.

  9. Breakthrough of toluene vapours in granular activated carbon filled packed bed reactor

    International Nuclear Information System (INIS)

    Mohan, N.; Kannan, G.K.; Upendra, S.; Subha, R.; Kumar, N.S.

    2009-01-01

    The objective of this research was to determine the toluene removal efficiency and breakthrough time using commercially available coconut shell-based granular activated carbon in packed bed reactor. To study the effect of toluene removal and break point time of the granular activated carbon (GAC), the parameters studied were bed lengths (2, 3, and 4 cm), concentrations (5, 10, and 15 mg l -1 ) and flow rates (20, 40, and 60 ml/min). The maximum percentage removal of 90% was achieved and the maximum carbon capacity for 5 mg l -1 of toluene, 60 ml/min flow rate and 3 cm bed length shows 607.14 mg/g. The results of dynamic adsorption in a packed bed were consistent with those of equilibrium adsorption by gravimetric method. The breakthrough time and quantity shows that GAC with appropriate surface area can be utilized for air cleaning filters. The result shows that the physisorption plays main role in toluene removal.

  10. Accounting for porous structure in effective thermal conductivity calculations in a pebble bed reactor

    International Nuclear Information System (INIS)

    Antwerpen, W. van; Rousseau, P.G.; Toit, C.G. du

    2009-01-01

    A proper understanding of the mechanisms of heat transfer, flow and pressure drop through a packed bed of spheres is of utmost importance in the design of a high temperature pebble bed reactor. A thorough knowledge of the porous structure within the packed bed is important to any rigorous analysis of the transport phenomena, as all the heat and flow mechanisms are influenced by the porous structure. In this paper a new approach is proposed to simulate the effective thermal conductivity employing a combination of new and existing correlations for randomly packed beds. More attention is given to packing structure based on coordination number and contact angles, resulting in a more rigorous differentiation between the bulk and near-wall regions. The model accounts for solid conduction, gas conduction, contact area, surface roughness as well as radiation. (author)

  11. The importance of the AVR pebble-bed reactor for the future of nuclear power

    International Nuclear Information System (INIS)

    Pohl, P.

    2006-01-01

    The AVR pebble-bed high temperature gas-cooled reactor (HTGR) at Juelich (Germany)) operated from 1967 to 1988 and was certainly the most important HTGR project of the past. The reactor was the mass test bed for all development steps of HTGR pebble fuel. Some early fuel charges failed under high temperature conditions and contaminated the reactor. An accurate pebble measurement (Cs 137) allowed to clean the core from unwanted pebbles after 1981. The coolant activity went down and remained very low for the remaining reactor operation. A melt-wire experiment in 1986 revealed max. coolant temperatures of >1280 deg. C and fuel temperatures of >1350 deg. C, explained by under-estimated bypasses. The fuel still in the core achieved high burn-ups and showed under the extreme temperature conditions excellent fission product retention. Thus, the AVR operation qualified the HTGR fuel, and an average discharge burn-up of 112% fifa revealed an excellent fuel economy of the pebble-bed reactor. Furthermore, the AVR operation offers many meaningful data for code-to-experiment comparisons. (authors)

  12. Rotary Bed Reactor for Chemical-Looping Combustion with Carbon Capture. Part 1: Reactor Design and Model Development

    KAUST Repository

    Zhao, Zhenlong

    2013-01-17

    Chemical-looping combustion (CLC) is a novel and promising technology for power generation with inherent CO2 capture. Currently, almost all of the research has been focused on developing CLC-based interconnected fluidized-bed reactors. In this two-part series, a new rotary reactor concept for gas-fueled CLC is proposed and analyzed. In part 1, the detailed configuration of the rotary reactor is described. In the reactor, a solid wheel rotates between the fuel and air streams at the reactor inlet and exit. Two purging sectors are used to avoid the mixing between the fuel stream and the air stream. The rotary wheel consists of a large number of channels with copper oxide coated on the inner surface of the channels. The support material is boron nitride, which has high specific heat and thermal conductivity. Gas flows through the reactor at elevated pressure, and it is heated to a high temperature by fuel combustion. Typical design parameters for a thermal capacity of 1 MW have been proposed, and a simplified model is developed to predict the performances of the reactor. The potential drawbacks of the rotary reactor are also discussed. © 2012 American Chemical Society.

  13. Effect of Mass-Transport Limitations on the Performance of a Packed Bed Membrane Reactor for Partial Oxidations. Transport from the Membrane to the Packed Bed

    NARCIS (Netherlands)

    van Sint Annaland, M.; Kurten, U.; Kuipers, J.A.M.

    2007-01-01

    With a packed bed membrane reactor, the product yield can be significantly enhanced for partial oxidation systems, via distributive addition of oxygen to the reaction mixture along the axial coordinate of the reactor, provided that the reaction order in oxygen of the formation rate of the target

  14. Effect of mass-transport limitations on the performance of a packed bed membrane reactor for partial oxidations. Transport from the membrane to the packed bed

    NARCIS (Netherlands)

    Sint Annaland, van M.; Kurten, U.; Kuipers, J.A.M.

    2007-01-01

    With a packed bed membrane reactor, the product yield can be significantly enhanced for partial oxidation systems, via distributive addition of oxygen to the reaction mixture along the axial coordinate of the reactor, provided that the reaction order in oxygen of the formation rate of the target

  15. Denitrification performance of Pseudomonas denitrificans in a fluidized-bed biofilm reactor and in a stirred tank reactor

    Energy Technology Data Exchange (ETDEWEB)

    Cattaneo, C.; Nicolella, C.; Rovatti, M. [Department of Chemical and Process Engineering, Faculty of Engineering, University of Genoa, Via Opera Pia 15, 16145 Genoa (Italy)

    2003-04-09

    Denitrification of a synthetic wastewater containing nitrates and methanol as carbon source was carried out in two systems - a fluidized-bed biofilm reactor (FBBR) and a stirred tank reactor (STR) - using Pseudomonas denitrificans over a period of five months. Nitrogen loading was varied during operation of both reactors to assess differences in the response to transient conditions. Experimental data were analyzed to obtain a comparison of denitrification kinetics in biofilm and suspended growth reactors. The comparison showed that the volumetric degradation capacity in the FBBR (5.36 kg {sub N} . m{sup -3} . d{sup -1}) was higher than in the STR, due to higher biomass concentration (10 kg {sub BM} . m{sup -3} vs 1.2 kg {sub BM} m{sup -3}). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

  16. Kinetic evaluation of an anaerobic fluidised-bed reactor treating slaughterhouse wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Borja, R. [Consejo Superior de Investigaciones Cientificas, Seville (Spain). Inst. de la Grasa; Banks, C.J.; Zhengjian Wang [Manchester Univ. (United Kingdom). Inst. of Science and Technology

    1995-09-01

    An anaerobic fluidised-bed reactor for purification of slaughterhouse wastewater was modelled as a continuous-flow, completely-mixed homogeneous microbial system, with the feed COD as the limiting-substrate concentration. The average microbial residence time in the reactor was defined in terms of conventional sludge-retention-time. The experimental data obtained indicated that the Michaelis-Menten expression was applicable to a description of substrate utilisation (i.e. COD removal) in the anaerobic fluidised-bed system. The maximum substrate utilisation rate, k, and the Michaelis constant, K{sub s}, were determined to be 1.2/day and 0.039 g/l. The observed biomass yield in the reactor decreased with increasing sludge-retention-time. The specific methane production rate observed was a linear function of the specific substrate-utilisation rate. (Author)

  17. Trickle bed reactor model to simulate the performance of commercial diesel hydrotreating unit

    Energy Technology Data Exchange (ETDEWEB)

    C. Murali; R.K. Voolapalli; N. Ravichander; D.T. Gokak; N.V. Choudary [Bharat Petroleum Corporation Ltd., Udyog Kendra (India). Corporate R& amp; D Centre

    2007-05-15

    A two phase mathematical model was developed to simulate the performance of bench scale and commercial hydrotreating reactors. Major hydrotreating reactions, namely, hydrodesulphurization, hydrodearomatization and olefins saturation were modeled. Experiments were carried out in a fixed bed reactor to study the effect of different process variables and these results were used for estimating kinetic parameters. Significant amount of feed vaporization (20-50%) was estimated under normal operating conditions of DHDS suggesting the importance of considering feed vaporization in DHDS modeling. The model was validated with plant operating data, under close to ultra low sulphur levels by correctly accounting for feed vaporization in heat balance relations and appropriate use of hydrodynamic correlations. The model could predict the product quality, reactor bed temperature profiles and chemical hydrogen consumption in commercial plant adequately. 14 refs., 7 figs., 6 tabs.

  18. Mathematical simulation of hazardous ion retention from radioactive waste in fixed bed reactor

    International Nuclear Information System (INIS)

    Sohsah, M.A.; Gohneim, M.M.; Othman, S.H.; El-Anadouli, B.E.

    2007-01-01

    Reactor design for fluid-solid, noncatalytic reaction depends on the prediction of the performance of the reactor kinetically. The most mathematical models used to handle fixed bed reactor in which the solid bed constitute one of the reactants, while a second reactant is in the fluid phase are complex and difficult to handle. A new mathematical model which easier to handle has been developed to describe the system under investigation. The model was examined theoretically and experimentally. A column backed with chelating cloth filter to separate radionuclide form radioactive waste solution is used as a practical application for the model. Comparison of the model predictions with the experimental results gives satisfactory agreement at most of the process stages

  19. Analysis of startup strategies for a particle bed reactor nuclear rocket engine

    Science.gov (United States)

    Suzuki, D. E.

    1993-06-01

    This paper develops and analyzes engine system startup strategies for a particle bed reactor (PBR) nuclear rocket engine. The strategies are designed to maintain stable flow through the PBR fuel element while reaching the design conditions as quickly as possible. The analyses are conducted using a computer model of a representative particle bed reactor and engine system. Elements of the startup strategy considered include: the coordinated control of reactor power and coolant flow; turbine inlet temperature and flow control; and use of an external starter system. The simulation results indicate that the use of an external starter system enables the engine to reach design conditions very quickly while maintaining the flow well away from the unstable regime. If a bootstrap start is used instead, the transient does not progress as fast and approaches closer to the unstable flow regime, but allows for greater engine reusability. These results can provide important information for engine designers and mission planners.

  20. Fluid flow and heat transfer investigation of pebble bed reactors using mesh-adaptive LES

    International Nuclear Information System (INIS)

    Pavlidis, Dimitrios; Lathouwers, Danny

    2013-01-01

    The very high temperature reactor is one of the designs currently being considered for nuclear power generation. One its variants is the pebble bed reactor in which the coolant passes through complex geometries (pores) at high Reynolds numbers. A computational fluid dynamics model with anisotropic mesh adaptivity is used to investigate coolant flow and heat transfer in such reactors. A novel method for implicitly incorporating solid boundaries based on multi-fluid flow modelling is adopted. The resulting model is able to resolve and simulate flow and heat transfer in randomly packed beds, regardless of the actual geometry, starting off with arbitrarily coarse meshes. The model is initially evaluated using an orderly stacked square channel of channel-height-to-particle diameter ratio of unity for a range of Reynolds numbers. The model is then applied to the face-centred cubical geometry. coolant flow and heat transfer patterns are investigated

  1. Improved performance of parallel surface/packed-bed discharge reactor for indoor VOCs decomposition: optimization of the reactor structure

    International Nuclear Information System (INIS)

    Jiang, Nan; Hui, Chun-Xue; Li, Jie; Lu, Na; Shang, Ke-Feng; Wu, Yan; Mizuno, Akira

    2015-01-01

    The purpose of this paper is to develop a high-efficiency air-cleaning system for volatile organic compounds (VOCs) existing in the workshop of a chemical factory. A novel parallel surface/packed-bed discharge (PSPBD) reactor, which utilized a combination of surface discharge (SD) plasma with packed-bed discharge (PBD) plasma, was designed and employed for VOCs removal in a closed vessel. In order to optimize the structure of the PSPBD reactor, the discharge characteristic, benzene removal efficiency, and energy yield were compared for different discharge lengths, quartz tube diameters, shapes of external high-voltage electrode, packed-bed discharge gaps, and packing pellet sizes, respectively. In the circulation test, 52.8% of benzene was removed and the energy yield achieved 0.79 mg kJ −1 after a 210 min discharge treatment in the PSPBD reactor, which was 10.3% and 0.18 mg kJ −1 higher, respectively, than in the SD reactor, 21.8% and 0.34 mg kJ −1 higher, respectively, than in the PBD reactor at 53 J l −1 . The improved performance in benzene removal and energy yield can be attributed to the plasma chemistry effect of the sequential processing in the PSPBD reactor. The VOCs mineralization and organic intermediates generated during discharge treatment were followed by CO x selectivity and FT-IR analyses. The experimental results indicate that the PSPBD plasma process is an effective and energy-efficient approach for VOCs removal in an indoor environment. (paper)

  2. [Rapid startup and nitrogen removal characteristic of anaerobic ammonium oxidation reactor in packed bed biofilm reactor with suspended carrier].

    Science.gov (United States)

    Chen, Sheng; Sun, De-zhi; Yu, Guang-lu

    2010-03-01

    Packed bed biofilm reactor with suspended carrier was used to cultivate ANAMMOX bacteria with sludge inoculums from WWTP secondary settler. The startup of ANAMMOX reactor was comparatively studied using high nitrogen loading method and low nitrogen loading method with aerobically biofilmed on the carrier, and the nitrogen removal characteristic was further investigated. The results showed that the reactor could be started up successfully within 90 days using low nitrogen loading method, the removal efficiencies of ammonium and nitrite were nearly 100% and the TN removal efficiencywas over 75% , however, the high nitrogen loading method was proved unsuccessfully for startup of ANAMMOX reactor probably because of the inhibition effect of high concentration of ammonium and nitrite. The pH value of effluent was slightly higher than the influent and the pH value can be used as an indicator for the process of ANAMMOX reaction. The packed bed ANAMMOX reactor with suspended carrier showed good characteristics of high nitrogen loading and high removal efficiency, 100% of removal efficiency could be achieved when the influent ammonium and nitrite concentration was lower than 800 mg/L.

  3. Deleterious Thermal Effects due to Randomized Flow Paths in Pebble Bed, and Particle Bed Style Reactors

    Science.gov (United States)

    Moran, Robert P.

    2013-01-01

    Reactor fuel rod surface area that is perpendicular to coolant flow direction (+S) i.e. perpendicular to the P creates areas of coolant stagnation leading to increased coolant temperatures resulting in localized changes in fluid properties. Changes in coolant fluid properties caused by minor increases in temperature lead to localized reductions in coolant mass flow rates leading to localized thermal instabilities. Reductions in coolant mass flow rates result in further increases in local temperatures exacerbating changes to coolant fluid properties leading to localized thermal runaway. Unchecked localized thermal runaway leads to localized fuel melting. Reactor designs with randomized flow paths are vulnerable to localized thermal instabilities, localized thermal runaway, and localized fuel melting.

  4. Tests of candidate materials for particle bed reactors

    International Nuclear Information System (INIS)

    Horn, F.L.; Powell, J.R.; Wales, D.

    1987-01-01

    Rhenium metal hot frits and zirconium carbide-coated fuel particles appear suitable for use in flowing hydrogen to at least 2000 K, based on previous tests. Recent tests on alternate candidate cooled particle and frit materials are described. Silicon carbide-coated particles began to react with rhenium frit material at 1600 K, forming a molten silicide at 2000 K. Silicon carbide was extensively attacked by hydrogen at 2066 K for 30 minutes, losing 3.25% of its weight. Vitrous carbon was also rapidly attacked by hydrogen at 2123 K, losing 10% of its weight in two minutes. Long term material tests on candidate materials for closed cycle helium cooled particle bed fuel elements are also described. Surface imperfections were found on the surface of pyrocarbon-coated fuel particles after ninety days exposure to flowing (∼500 ppM) impure helium at 1143 K. The imperfections were superficial and did not affect particle strength

  5. Cleaning of porous filters in fossilized bed reactors; Estudio de limpieza de filtros porosos en reactores de lecho fluidizado

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigo Otero, A; Sancho Rod, J

    1965-07-01

    In this report are established the optimum working conditions of a filter cleaning system by blow back. For this purpose it was determined in the first place the blow back air rate necessary to have a good cleaning. The reasons for which it was not possible until now to control the pressure in a fluidized bed calcination reactor are analyzed and a criteria is established to calculate the optimum floe necessary to clean efficiently a porous by this procedures. (Author)

  6. Removal of micropollutants in Moving Bed Biofilm reactors (MBBRs)

    DEFF Research Database (Denmark)

    Torresi, Elena

    Numerous pollutants such as pharmaceuticals and personal care products are continuously released into municipal wastewater treatment plants (WWTP). Present at concentration of nano- to milligram per liter, they are defined as micropollutants. Micropollutants are only partially removed, possibly due...... compared to conventional activated sludge. In MBBRs, biofilm grow on plastic carriers kept in suspension in the reactor basin via mechanical mixing or aeration, offering a suit of benefits, amongst all comparably small footprint. Despite few existing evidences in aerobic MBBR, an in-depth understanding...

  7. Effect of a flow-corrective insert on the flow pattern in a pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yu; Gui, Nan; Yang, Xingtuan [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, Key Laboratory of Advanced Reactor Engineering and Safety of Ministry of Education, Tsinghua University, Beijing 100084 (China); Tu, Jiyuan [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, Key Laboratory of Advanced Reactor Engineering and Safety of Ministry of Education, Tsinghua University, Beijing 100084 (China); School of Aerospace, Mechanical & Manufacturing Engineering, RMIT University, Melbourne 3083, VIC (Australia); Jiang, Shengyao, E-mail: shengyaojiang@sina.com [Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Energy Technology, Key Laboratory of Advanced Reactor Engineering and Safety of Ministry of Education, Tsinghua University, Beijing 100084 (China)

    2016-04-15

    Highlights: • Effect of an insert on improving flow uniformity and eliminating stagnant zone is studied. • Three values concerned with the stagnant zone, radial uniformity and flow sequence are used. • Outlet diameter is a critical parameter that determines balancing mechanism of the insert. • Height/location is varied to let the insert work in unbalanced region and avoid adverse effect. - Abstract: A flow-corrective insert is adopted in the pebble-bed high temperature gas-cooled reactor (HTGR) to improve flow performance of the pebble flow for the first time. 3D discrete element method (DEM) modeling is employed to study this slow and dense granular flow. It is verified that locating a properly designed insert in the bed can help transform unsatisfactory flow field to the preferred flow pattern for pebble bed reactors. Three characteristic values on the stagnant zone, radial uniformity and flow sequence of pebble flow are defined to evaluate uniformity of the overall flow field quantitatively. The results demonstrate that the pebble bed equipped with an insert performs better than normal beds from all these three aspects. Moreover, based on numerical experiments, several universal tips for insert design on height, location and outlet diameter are suggested.

  8. Effect of friction on pebble flow pattern in pebble bed reactor

    International Nuclear Information System (INIS)

    Li, Yu; Gui, Nan; Yang, Xingtuan; Tu, Jiyuan; Jiang, Shengyao

    2016-01-01

    Highlights: • A 3D DEM study on particle–wall/particle friction in pebble bed reactor is carried out. • Characteristic values are defined to evaluate features of pebble flow pattern quantitatively. • Particle–wall friction is dominant to determine flow pattern in a specific pebble bed. • Friction effect of hopper part on flow field is more critical than that of cylinder part. • Three cases of 1:1 full scale practical pebble beds are simulated for demonstration. - Abstract: Friction affects pebble flow pattern in pebble-bed high temperature gas-cooled reactor (HTGR) significantly. Through a series of three dimensional DEM (discrete element method) simulations it is shown that reducing friction can be beneficial and create a uniform and consistent flow field required by nuclear engineering. Particle–wall friction poses a decisive impact on flow pattern, and particle–particle friction usually plays a secondary role; relation between particle–wall friction and flow pattern transition is also concluded. Moreover, new criteria are created to describe flow patterns quantitatively according to crucial issues in HTGR like stagnant zone, radial uniformity and flow sequence. Last but not least, it is proved that friction control of hopper part is more important than that of cylinder part in practical pebble beds, so reducing friction between pebbles and hopper surface is the engineering priority.

  9. Experimental and computational investigation of flow of pebbles in a pebble bed nuclear reactor

    Science.gov (United States)

    Khane, Vaibhav B.

    The Pebble Bed Reactor (PBR) is a 4th generation nuclear reactor which is conceptually similar to moving bed reactors used in the chemical and petrochemical industries. In a PBR core, nuclear fuel in the form of pebbles moves slowly under the influence of gravity. Due to the dynamic nature of the core, a thorough understanding about slow and dense granular flow of pebbles is required from both a reactor safety and performance evaluation point of view. In this dissertation, a new integrated experimental and computational study of granular flow in a PBR has been performed. Continuous pebble re-circulation experimental set-up, mimicking flow of pebbles in a PBR, is designed and developed. Experimental investigation of the flow of pebbles in a mimicked test reactor was carried out for the first time using non-invasive radioactive particle tracking (RPT) and residence time distribution (RTD) techniques to measure the pebble trajectory, velocity, overall/zonal residence times, flow patterns etc. The tracer trajectory length and overall/zonal residence time is found to increase with change in pebble's initial seeding position from the center towards the wall of the test reactor. Overall and zonal average velocities of pebbles are found to decrease from the center towards the wall. Discrete element method (DEM) based simulations of test reactor geometry were also carried out using commercial code EDEM(TM) and simulation results were validated using the obtained benchmark experimental data. In addition, EDEM(TM) based parametric sensitivity study of interaction properties was carried out which suggests that static friction characteristics play an important role from a packed/pebble beds structural characterization point of view. To make the RPT technique viable for practical applications and to enhance its accuracy, a novel and dynamic technique for RPT calibration was designed and developed. Preliminary feasibility results suggest that it can be implemented as a non

  10. Experiment and modeling of low-concentration methane catalytic combustion in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Yang, Zhongqing; Yang, Peng; Zhang, Li; Guo, Mingnv; Ran, Jingyu

    2016-01-01

    Highlights: • The catalytic combustion of 0.15~3 vol. % low concentration methane in a fluidized bed was studied. • A mathematical model was proposed on the basis of gas–solid flow theory. • A comparative analysis of the established model with plug flow, mixed flow and K-L models was carried out. • The axial methane profile along fluidized bed was predicted by using the mathematical model. • The bed temperature has greater impact on methane conversion than fluidized velocity. - Abstract: This study undertakes a theoretical analysis and an experimental investigation into the characteristics of low-concentration methane catalytic combustion in a bubbling fluidized bed reactor using 0.5 wt.% Pd/Al_2O_3 as catalytic particles. A mathematical model is established based on gas–solid flow theory and is used to study the effects of bed temperature and fluidized velocity on methane catalytic combustion, and predict the dimensionless methane concentration axial profile in reactor. It is shown that methane conversion increases with bed temperature, but decreases with increasing fluidized velocity. These theoretical results are found to correlate well with the experimental measurement, with a deviation within 5%. A comparative analysis of the developed model with plug flow, mixed flow and K-L models is also carried out, and this further verifies that the established model better reflects the characteristics of low-concentration methane catalytic combustion in a bubbling fluidized bed. Using this reaction model, it was found that the difference in methane conversion between dense and freeboard zones gradually increases with bed temperature; the dense zone reaction levels off at 650 °C, thereby minimizing the difference between the dense and freeboard regions to around 15%. With an increase in bed temperature, the dimensionless methane concentration in the dense zone decreases exponentially, while in the splash zone, it varies from an exponential decay to a slow

  11. Catalytic wet oxidation of phenol in a trickle bed reactor over a Pt/TiO2 catalyst.

    Science.gov (United States)

    Maugans, Clayton B; Akgerman, Aydin

    2003-01-01

    Catalytic wet oxidation of phenol was studied in a batch and a trickle bed reactor using 4.45% Pt/TiO2 catalyst in the temperature range 150-205 degrees C. Kinetic data were obtained from batch reactor studies and used to model the reaction kinetics for phenol disappearance and for total organic carbon disappearance. Trickle bed experiments were then performed to generate data from a heterogeneous flow reactor. Catalyst deactivation was observed in the trickle bed reactor, although the exact cause was not determined. Deactivation was observed to linearly increase with the cumulative amount of phenol that had passed over the catalyst bed. Trickle bed reactor modeling was performed using a three-phase heterogeneous model. Model parameters were determined from literature correlations, batch derived kinetic data, and trickle bed derived catalyst deactivation data. The model equations were solved using orthogonal collocations on finite elements. Trickle bed performance was successfully predicted using the batch derived kinetic model and the three-phase reactor model. Thus, using the kinetics determined from limited data in the batch mode, it is possible to predict continuous flow multiphase reactor performance.

  12. Analysis of the start-up and control of a particle bed reactor

    International Nuclear Information System (INIS)

    Lazareth, O.W.; Araj, K.J.; Horn, F.L.; Ludewig, H.; Powell, J.R.

    1987-01-01

    This study describes the modeling of start-up transients in Particle Bed Reactors (PBR) for burst electric power. Two computer programs have been developed to analyze the start-up process. The first program (named KINETIC) analyzes the entire fuel element, calculating time dependent solutions for power and the temperature distribution in the packed bed. The second program (named SPHEAT, for Spherical Heating) calculates time-dependent temperatures inside individual, cladded fuel particles. The two programs provide powerful analytical tools for evaluation of material and geometrical options, power and time constraints, and conditions that could lead to element failures

  13. Homogeneity of Continuum Model of an Unsteady State Fixed Bed Reactor for Lean CH4 Oxidation

    Directory of Open Access Journals (Sweden)

    Subagjo

    2014-07-01

    Full Text Available In this study, the homogeneity of the continuum model of a fixed bed reactor operated in steady state and unsteady state systems for lean CH4 oxidation is investigated. The steady-state fixed bed reactor system was operated under once-through direction, while the unsteady-state fixed bed reactor system was operated under flow reversal. The governing equations consisting of mass and energy balances were solved using the FlexPDE software package, version 6. The model selection is indispensable for an effective calculation since the simulation of a reverse flow reactor is time-consuming. The homogeneous and heterogeneous models for steady state operation gave similar conversions and temperature profiles, with a deviation of 0.12 to 0.14%. For reverse flow operation, the deviations of the continuum models of thepseudo-homogeneous and heterogeneous models were in the range of 25-65%. It is suggested that pseudo-homogeneous models can be applied to steady state systems, whereas heterogeneous models have to be applied to unsteady state systems.

  14. Neutronic design of a Liquid Salt-cooled Pebble Bed Reactor (LSPBR)

    International Nuclear Information System (INIS)

    De Zwaan, S. J.; Boer, B.; Lathouwers, D.; Kloosterman, J. L.

    2006-01-01

    A renewed interest has been raised for liquid salt cooled nuclear reactors. The excellent heat transfer properties of liquid salt coolants provide several benefits, like lower fuel temperatures, higher coolant outlet temperatures, increased core power density and better decay heat removal. In order to benefit from the online refueling capability of a pebble bed reactor, the Liquid Salt Pebble Bed Reactor (LSPBR) is proposed. This is a high temperature pebble-bed reactor with a fuel design similar to existing HTRs, but using a liquid salt as a coolant. In this paper, the selection criteria for the liquid salt coolant are described. Based on its neutronic properties, LiF-BeF 2 (FLIBE) was selected for the LSPBR. Two designs of the LSPBR were considered: a cylindrical core and an annular core with a graphite inner reflector. Coupled neutronic-thermal hydraulic calculations were performed to obtain the steady state power distribution and the corresponding fuel temperatures. Finally, calculations were performed to investigate the decay heat removal capability in a protected loss-of-forced cooling accident. The maximum allowable power that can be produced with the LSPBR is hereby determined. (authors)

  15. The combustion of coal blends in a fluidised bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Boavida, Dulce; Abelha, Pedro; Gulyurtlu, Ibrahim; Cabrita, Isabel

    1999-07-01

    Combustion studies of five coals of different origin were carried out in a laboratory scale fluidised bed combustor. Five blends prepared by mixing two coals based on their petrological characterisation, in varying amounts, were selected to study the possibility of reduction NO{sub x}, N{sub 2}O and SO{sub 2} emissions. The results showed that some blends had the opposite behaviour concerning the release of NO{sub x} and SO{sub 2} in relation to parent coals, and the emissions were higher than expected. The N{sub 2}O amounts observed were, however, in almost all blends tested, lower than predicted values. With some blends, the mixing levels intended to reduce SO{sub 2} were not always found to correspond to those for simultaneous decrease of Nox. Most of the blends studied showed some evidence of interaction between them. Varying the proportion of the blend components was observed to alter the temperatures at which interactions were stronger.

  16. Experimental and numerical validation of a two-region-designed pebble bed reactor with dynamic core

    International Nuclear Information System (INIS)

    Jiang, S.Y.; Yang, X.T.; Tang, Z.W.; Wang, W.J.; Tu, J.Y.; Liu, Z.Y.; Li, J.

    2012-01-01

    Highlights: ► The experimental installation has been built to investigate the pebble flow. ► The feasibility of two-region pebble bed reactor has been verified. ► The pebble flow is more uniform in a taller vessel than that in a lower vessel. ► Larger base cone angle will decrease the scale of the stagnant zone. - Abstract: The pebble flow is the principal issue for the design of the pebble bed reactor. In order to verify the feasibility of a two-region-designed pebble bed reactor, the experimental installation with a taller vessel has been built, which is proportional to the real pebble bed reactor. With the aid of the experimental installation, the stable establishment and maintenance of the two-region arrangement has been verified, at the same time, the applicability of the DEM program has been also validated. Research results show: (1) The pebble's bouncing on the free surface is an important factor for the mixing of the different colored pebbles. (2) Through the guide plates installed in the top of the pebble packing, the size of the mixing zone can be reduced from 6–7 times to 3–4 times the pebble diameter. (3) The relationship between the width of the central region and the ratio of loading pebbles is approximately linear in the taller vessel. (4) The heighten part of the pebble packing can improve the uniformity of the flowing in the lower. (5) To increase the base cone angle can decrease the scale of the stagnant zone. All of these conclusions are meaningful to the design of the real pebble reactor.

  17. Radioisotope tracer study in a pilot-scale trickle bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Pant, H.J.; Pendharkar, A.S. [Bhabha Atomic Research Centre, Isotope Applications Div, Bombay (India); Prasad, J.S.; Maiti, R.N.; Chawla, R.; Lahri, R.N.; Ram Babu, D. [Engineers India Limited, Gurgaon, Haryana (India); Berne, Ph. [CEA Grenoble, DTEN/SAT, 38 (France)

    2001-07-01

    Trickle bed reactor (TBR) is a reactor in which a liquid and a gas phase flow concurrently downwards through a fixed bed of catalyst particles while the reaction takes place. The trickle bed reactors find a number of applications in petroleum refining, chemical. petro-chemical and bio-chemical processes due to their suitability for hydro-processing operations.The knowledge of radial distribution, mean residence time (MRT). liquid holdup and degree of axial mixing is a basic requirement to evaluate the reactor performance of a TBR, its optimal size, the physical and chemical interactions and the pumping requirements. Measurement and analysis of residence time distribution (RTD) of liquid phase facilitate the determination of these parameters. This paper describes the measurement of RTD of liquid phase in a pilot-scale trickle bed reactor operating at high pressure. Kerosene and nitrogen were used as liquid and gas phase, respectively. Porous alumina catalyst particles were used as packing. Bromine-82 as para-di-bromo benzene was used as a tracer to measure RTD of organic liquid phase. The RTD of kerosene was measured as a function of liquid and gas flow rates and pressure. The axial dispersion model with exchange between active and dead zones was proposed and used to simulate the measured RTD data and model parameters i.e mean residence time ({tau}), Peclet Number (Pe), dynamic fraction of the liquid ({phi}) and the number of transfer units (N) were obtained. The results of the simulations indicated intermediate degree of axial mixing of liquid phase. The RTD predicted by the axial dispersion model with exchange between active and dead zones fits well to the experimentally measured RTD data and thus is a suitable model to describe the dynamics of the liquid phase in TBRs filled with porous catalyst particles. (authors)

  18. Pebble Bed Reactors Design Optimization Methods and their Application to the Pebble Bed Fluoride Salt Cooled High Temperature Reactor (PB-FHR)

    Science.gov (United States)

    Cisneros, Anselmo Tomas, Jr.

    The Fluoride salt cooled High temperature Reactor (FHR) is a class of advanced nuclear reactors that combine the robust coated particle fuel form from high temperature gas cooled reactors, direct reactor auxillary cooling system (DRACS) passive decay removal of liquid metal fast reactors, and the transparent, high volumetric heat capacitance liquid fluoride salt working fluids---flibe (33%7Li2F-67%BeF)---from molten salt reactors. This combination of fuel and coolant enables FHRs to operate in a high-temperature low-pressure design space that has beneficial safety and economic implications. In 2012, UC Berkeley was charged with developing a pre-conceptual design of a commercial prototype FHR---the Pebble Bed- Fluoride Salt Cooled High Temperature Reactor (PB-FHR)---as part of the Nuclear Energy University Programs' (NEUP) integrated research project. The Mark 1 design of the PB-FHR (Mk1 PB-FHR) is 236 MWt flibe cooled pebble bed nuclear heat source that drives an open-air Brayton combine-cycle power conversion system. The PB-FHR's pebble bed consists of a 19.8% enriched uranium fuel core surrounded by an inert graphite pebble reflector that shields the outer solid graphite reflector, core barrel and reactor vessel. The fuel reaches an average burnup of 178000 MWt-d/MT. The Mk1 PB-FHR exhibits strong negative temperature reactivity feedback from the fuel, graphite moderator and the flibe coolant but a small positive temperature reactivity feedback of the inner reflector and from the outer graphite pebble reflector. A novel neutronics and depletion methodology---the multiple burnup state methodology was developed for an accurate and efficient search for the equilibrium composition of an arbitrary continuously refueled pebble bed reactor core. The Burnup Equilibrium Analysis Utility (BEAU) computer program was developed to implement this methodology. BEAU was successfully benchmarked against published results generated with existing equilibrium depletion codes VSOP

  19. Factors affecting biological reduction of CO{sub 2} into CH{sub 4} using a hydrogenotrophic methanogen in a fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae Hyung; Pak, Daewon [Seoul National University of Science and Technology, Seoul (Korea, Republic of); Chang, Won Seok [Korea District Heating Corp, Seongnam (Korea, Republic of)

    2015-10-15

    Biological conversion of CO{sub 2} was examined in a fixed bed reactor inoculated with anaerobic mixed culture to investigate influencing factors, the type of packing material and the composition of the feeding gas mixture. During the operation of the fixed bed reactor by feeding the gas mixture (80% H{sub 2} and 20% CO{sub 2} based on volume basis), the volumetric CO{sub 2} conversion rate was higher in the fixed bed reactor packed with sponge due to its large surface area and high mass transfer from gas to liquid phase compared with PS ball. Carbon dioxide loaded into the fixed bed reactor was not completely converted because some of H{sub 2} was used for biomass growth. When a mole ratio of H{sub 2} to CO{sub 2} in the feeding gas mixture increased from 4 to 5, CO{sub 2} was completely converted into CH{sub 4}. The packing material with large surface area is effective in treating gaseous substrate such as CO{sub 2} and H{sub 2}. H{sub 2}, electron donor, should be providing more than required according to stoichiometry because some of it is used for biomass growth.

  20. Prevention of clogging in a biological trickle-bed reactor removing toluene from contaminated air.

    Science.gov (United States)

    Weber, F J; Hartmans, S

    1996-04-05

    Removal of organic compounds like toluene from waste gases with a trickle-bed reactor can result in clogging of the reactor due to the formation of an excessive amount of biomass. We therefore limited the amount of nutrients available for growth, to prevent clogging of the reactor. As a consequence of this nutrient limitation a lower removal rate was observed. However, when a fungal culture was used to inoculate the reactor, the toluene removal rate under nutrient limiting conditions was higher. Over a period of 375 days, an average removal rate of 27 g C/(m(3) h) was obtained with the reactor inoculated with the fungal culture. From the carbon balance over the reactor and the nitrogen availability it was concluded that, under these nutrient-limited conditions, large amounts of carbohydrates are probably formed. We also studied the application of a NaOH wash to remove excess biomass, as a method to prevent clogging. Under these conditions an average toluene removal rate of 35 g C/(m(3) h) was obtained. After about 50 days there was no net increase in the biomass content of the reactor. The amount of biomass which was formed in the reactor equaled the amount removed by the NaOH wash.

  1. Modeling of reaction kinetics in bubbling fluidized bed biomass gasification reactor

    Energy Technology Data Exchange (ETDEWEB)

    Thapa, R.K.; Halvorsen, B.M. [Telemark University College, Kjolnes ring 56, P.O. Box 203, 3901 Porsgrunn (Norway); Pfeifer, C. [University of Natural Resources and Life Sciences, Vienna (Austria)

    2013-07-01

    Bubbling fluidized beds are widely used as biomass gasification reactors as at the biomass gasification plant in Gussing, Austria. The reactor in the plant is a dual circulating bubbling fluidized bed gasification reactor. The plant produces 2MW electricity and 4.5MW heat from the gasification of biomass. Wood chips as biomass and olivine particles as hot bed materials are fluidized with high temperature steam in the reactor. As a result, biomass undergoes endothermic chemical reaction to produce a mixture of combustible gases in addition to some carbon-dioxide (CO2). The combustible gases are mainly hydrogen (H2), carbon monoxide (CO) and methane (CH4). The gas is used to produce electricity and heat via utilization in a gas engine. Alternatively, the gas is further processed for gaseous or liquid fuels, but still on the process of development level. Composition and quality of the gas determine the efficiency of the reactor. A computational model has been developed for the study of reaction kinetics in the gasification rector. The simulation is performed using commercial software Barracuda virtual reactor, VR15. Eulerian-Lagrangian approach in coupling of gas-solid flow has been implemented. Fluid phase is treated with an Eulerian formulation. Discrete phase is treated with a Lagrangian formulation. Particle-particle and particle-wall interactions and inter-phase heat and mass transfer have been taken into account. Series of simulations have been performed to study model prediction of the gas composition. The composition is compared with data from the gasifier at the CHP plant in Güssing, Austria. The model prediction of the composition of gases has good agreements with the result of the operating plant.

  2. Pressurizing Behavior on Ingress of Coolant into Pebble Bed of Blanket of Fusion DEMO Reactor

    International Nuclear Information System (INIS)

    Daigo Tsuru; Mikio Enoeda; Masato Akiba

    2006-01-01

    Solid breeder blankets are being developed as candidate blankets for the Fusion DEMO reactor in Japan. JAEA is performing the development of the water cooled and helium cooled solid breeder blankets. The blanket utilizes ceramic breeder pebbles and multiplier pebbles beds cooled by high pressure water or high pressure helium in the cooling tubes placed in the blanket box structure. In the development of the blanket, it is very important to incorporate the safety technology as well as the performance improvement on tritium production and energy conversion. In the safety design and technology, coolant ingress in the blanket box structure is one of the most important events as the initiators. Especially the thermal hydraulics in the pebble bed in the case of the high pressure coolant ingress is very important to evaluate the pressure propagation and coolant flow behavior. This paper presents the preliminary results of the pressure loss characteristics by the coolant ingress in the pebble bed. Experiments have been performed by using alumina pebble bed (4 litter maximum volume of the pebble bed) and nitrogen gas to simulate the helium coolant ingress into breeder and multiplier pebble beds. Reservoir tank of 10 liter is filled with 1.0 MPa nitrogen. The nitrogen gas is released at the bottom part of the alumina pebble bed whose upper part is open to the atmosphere. The pressure change in the pebble bed is measured to identify the pressure loss. The measured values are compared with the predicted values by Ergun's equation, which is the correlation equation on pressure loss of the flow through porous medium. By the results of the experiments with no constraint on the alumina pebble bed, it was clarified that the measured value agreed in the lower flow rate. However, in the higher flow rate where the pressure loss is high, the measured value is about half of the predicted value. The differences between the measured values and the predicted values will be discussed from

  3. Development of Research Reactor Simulator and Its Application to Dynamic Test-bed

    International Nuclear Information System (INIS)

    Kwon, Kee Choon; Park, Jae Chang; Lee, Seung Wook; Bang, Dane; Bae, Sung Won

    2014-01-01

    We developed HANARO and the Jordan Research and Training Reactor (JRTR) real-time simulator for operating staff training. The main purpose of this simulator is operator training, but we modified this simulator as a dynamic test-bed to test the reactor regulating system in HANARO or JRTR before installation. The simulator configuration is divided into hardware and software. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The simulator software is divided into three major parts: a mathematical modeling module, which executes the plant dynamic modeling program in real-time, an instructor station module that manages user instructions, and a human machine interface (HMI) module. The developed research reactors are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by a hardware controller and the simulator and target controller were interfaced with a hard-wired and network-based interface

  4. Integrated design approach of the pebble BeD modular reactor using models

    International Nuclear Information System (INIS)

    Venter, Pieter J.; Mitchell, Mark N.

    2007-01-01

    The pebble bed modular reactor (PBMR) is the first pebble bed reactor that will be utilised in a high temperature direct Brayton cycle configuration. This implies that there are a number of unique features in the PBMR that extend from the German experience base. One of the challenges in the design of the PBMR is developing an understanding of the expected behaviour of the reactor through analyses and simulations and managing the integrated design process between the designers, the physicists and the analysts. This integrated design process is managed through model-based development work. Three-dimensional CAD models are constructed of the components and parts in the reactor. From the CAD models, CFD models, neutronic models, shielding models, FEM models and other thermodynamic models are derived. These models range from very simple models to extremely detailed and complex models. The models are used in legacy software as well as commercial off-the-shelf software. The different models are also used in code-to-code comparisons to verify the results. This paper will briefly discuss the different models and the interaction between the models, and how the models are used in the iterative design process that is used in the development of the reactor at PBMR

  5. Development of Research Reactor Simulator and Its Application to Dynamic Test-bed

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Kee Choon; Park, Jae Chang; Lee, Seung Wook; Bang, Dane; Bae, Sung Won [KAERI, Daejeon (Korea, Republic of)

    2014-08-15

    We developed HANARO and the Jordan Research and Training Reactor (JRTR) real-time simulator for operating staff training. The main purpose of this simulator is operator training, but we modified this simulator as a dynamic test-bed to test the reactor regulating system in HANARO or JRTR before installation. The simulator configuration is divided into hardware and software. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The simulator software is divided into three major parts: a mathematical modeling module, which executes the plant dynamic modeling program in real-time, an instructor station module that manages user instructions, and a human machine interface (HMI) module. The developed research reactors are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by a hardware controller and the simulator and target controller were interfaced with a hard-wired and network-based interface.

  6. Study on neutron diffusion and time dependence heat ina fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Vilhena, M.T. de.

    1988-01-01

    The purpose of this work is to model the neutron diffusion and heat transfer for a Fluidized Bed Nuclear Reactor and its solution by Laplace Transform Technique with numerical inversion using Fourier Series. Also Gaussian quadrature and residues techniques were applied for numerical inversion. The neutron transport, diffusion, and point Kinetic equation for this nuclear reactor concept are developed. A matricial and Taylor Series methods are proposed for the solution of the point Kinetic equation which is a time scale problem of Stiff type

  7. Packed-fluidized-bed blanket concept for a thorium-fueled commercial tokamak hybrid reactor

    International Nuclear Information System (INIS)

    Chi, J.W.H.; Miller, J.W.; Karbowski, J.S.; Chapin, D.L.; Kelly, J.L.

    1980-09-01

    A preliminary design of a thorium blanket was carried out as a part of the Commercial Tokamak Hybrid Reactor (CTHR) study. A fixed fuel blanket concept was developed as the reference CTHR blanket with uranium carbide fuel and helium coolant. A fixed fuel blanket was initially evaluated for the thorium blanket study. Subsequently, a new type of hybrid blanket, a packed-fluidized bed (PFB), was conceived. The PFB blanket concept has a number of unique features that may solve some of the problems encountered in the design of tokamak hybrid reactor blankets. This report documents the thorium blanket study and describes the feasibility assessment of the PFB blanket concept

  8. Rotating-bed reactor as a power source for EM gun applications

    Energy Technology Data Exchange (ETDEWEB)

    Powell, J.; Botts, T.; Stickley, C.M.; Meth, S.

    1980-01-01

    Electromagnetic gun applications of the Rotating Bed Reactor (RBR) are examined. The RBR is a compact (approx. 1 m/sup 3/), (up to several thousand MW(th)), high-power reactor concept, capable of producing a high-temperature (up to approx. 300/sup 0/K) gas stream with a MHD generator coupled to it, the RBR can generate electric power (up to approx. 1000 MW(e)) in the pulsed or cw modes. Three EM gun applications are investigated: a rail gun thruster for orbit transfer, a rapid-fire EM gun for point defense, and a direct ground-to-space launch. The RBR appears suitable for all applications.

  9. Adjustement of Dancoff factor for calculating the cell of fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Borges, V.; Sefidvash, F.

    1988-01-01

    A new nuclear reactor design based on the fluidized bed concept is under reserch and development. It utilized spherical fuel of slightly enriched zircaloy-clad uranium dioxide fluidized by light water under pressure since the Leopard code has been developed for light water reactor analysis, it was necessary to develop a method to determine the dimensions of the hypothetical fuel rod lattice, which are neutronically equivalent to the spherical fuel pellet lattice. This method is shown to calculate the Dancoff factor correctly. (author) [pt

  10. Rotating-bed reactor as a power source for EM gun applications

    International Nuclear Information System (INIS)

    Powell, J.; Botts, T.; Stickley, C.M.; Meth, S.

    1980-01-01

    Electromagnetic gun applications of the Rotating Bed Reactor (RBR) are examined. The RBR is a compact (approx. 1 m 3 ), (up to several thousand MW(th)), high-power reactor concept, capable of producing a high-temperature (up to approx. 300 0 K) gas stream with a MHD generator coupled to it, the RBR can generate electric power (up to approx. 1000 MW(e)) in the pulsed or cw modes. Three EM gun applications are investigated: a rail gun thruster for orbit transfer, a rapid-fire EM gun for point defense, and a direct ground-to-space launch. The RBR appears suitable for all applications

  11. Drying kinetics characteristic of Indonesia lignite coal (IBC) using lab scale fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kang, TaeJin; Jeon, DoMan; Namkung, Hueon; Jang, DongHa; Jeon, Youngshin; Kim, Hyungtaek [Ajou Univ., Suwon (Korea, Republic of). Div. of Energy Systems Research

    2013-07-01

    Recent instability of energy market arouse a lot of interest about coal which has a tremendous amount of proven coal reserves worldwide. South Korea hold the second rank by importing 80 million tons of coal in 2007 following by Japan. Among various coals, there is disused coal. It's called Low Rank Coal (LRC). Drying process has to be preceded before being utilized as power plant. In this study, drying kinetics of LRC is induced by using a fixed bed reactor. The drying kinetics was deduced from particle size, the inlet gas temperature, the drying time, the gas velocity, and the L/D ratio. The consideration on Reynold's number was taken for correction of gas velocity, particle size, and the L/D ratio was taken for correction packing height of coal. It can be found that active drying of free water and phase boundary reaction is suitable mechanism through the fixed bed reactor experiments.

  12. Hydrogen sulfide removal from air by Acidithiobacillus thiooxidans in a trickle bed reactor.

    Science.gov (United States)

    Ramirez, M; Gómez, J M; Cantero, D; Páca, J; Halecký, M; Kozliak, E I; Sobotka, M

    2009-09-01

    A strain of Acidithiobacillus thiooxidans immobilized in polyurethane foam was utilized for H(2)S removal in a bench-scale trickle-bed reactor, testing the limits of acidity and SO(4) (2-) accumulation. The use of this acidophilic strain resulted in remarkable stability in the performance of the system. The reactor maintained a >98-99 % H(2)S removal efficiency for c of up to 66 ppmv and empty bed residence time 98 % H(2)S was achieved under steady-state conditions, over the pH range of 0.44-7.30. Despite the accumulation of acidity and SO(4) (2-) (up to 97 g/L), the system operated without inhibition.

  13. Immobilized glucose oxidase--catalase and their deactivation in a differential-bed loop reactor.

    Science.gov (United States)

    Prenosil, J E

    1979-01-01

    Glucose oxidase containing catalase was immobilized with a copolymer of phenylenediamine and glutaraldehyde on pumice and titania carrier to study the enzymatic oxidation of glucose in a differential-bed loop reactor. The reaction rate was found to be first order with respect to the concentration of limiting oxygen substrate, suggesting a strong external mass-transfer resistance for all the flow rates used. The partial pressure of oxygen was varied from 21.3 up to 202.6 kPa. The use of a differential-bed loop reactor for the determination of the active enzyme concentration in the catalyst with negligible internal pore diffusion resistance is shown. Catalyst deactivation was studied, especially with respect to the presence of catalase. It is believed that the hydrogen peroxide formed in the oxidation reaction deactivates catalase first; if an excess of catalase is present, the deactivation of glucose oxidase remains small. The mathematical model subsequently developed adequately describes the experimental results.

  14. Analysis of impact of mixing flow on the pebble bed high temperature reactor

    International Nuclear Information System (INIS)

    Hao Chen; Li Fu; Guo Jiong

    2014-01-01

    The impact of the mixing flow in the pebble flow on pebble bed high temperature gas cooled reactor (HTR) was analyzed in the paper. New code package MFVSOP which can simulate the mixing flow was developed. The equilibrium core of HTR-PM was selected as reference case, the impact of the mixing flow on the core parameters such as core power peak factor, power distribution was analyzed with different degree of mixing flow, and uncertainty analysis was carried out. Numerical results showed that the mixing flow had little impact on key parameters of pebble bed HTR, and the multiple-pass-operation-mode in pebble bed HTR can reduce the uncertainty arouse from the mixing flow. (authors)

  15. Characteristics of convective heat transport in a packed pebble-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Abdulmohsin, Rahman S., E-mail: rsar62@mst.edu [Department of Chemical and Biochemical Engineering, Missouri University of Science and Technology, 400 West 11th Street/231 Schrenk Hall, Rolla, MO 65409-1230 (United States); Al-Dahhan, Muthanna H., E-mail: aldahhanm@mst.edu [Department of Chemical and Biochemical Engineering, Missouri University of Science and Technology, 400 West 11th Street/231 Schrenk Hall, Rolla, MO 65409-1230 (United States); Department of Nuclear Engineering, 301 W. 14th St./222 Fulton Hall (United States)

    2015-04-01

    Highlights: • A fast-response heat transfer probe has been developed and used in this work. • Heat transport has been quantified in terms of local heat transfer coefficients. • The method of the electrically heated single sphere in packing has been applied. • The heat transfer coefficient increases from the center to the wall of packed bed. • This work advancing the knowledge of heat transport in the studied packed bed. - Abstract: Obtaining more precise results and a better understanding of the heat transport mechanism in the dynamic core of packed pebble-bed reactors is needed because this mechanism poses extreme challenges to the reliable design and efficient operation of these reactors. This mechanism can be quantified in terms of a solid-to-gas convective heat transfer coefficient. Therefore, in this work, the local convective heat transfer coefficients and their radial profiles were measured experimentally in a separate effect pilot-plant scale and cold-flow experimental setup of 0.3 m in diameter, using a sophisticated noninvasive heat transfer probe of spherical type. The effect of gas velocity on the heat transfer coefficient was investigated over a wide range of Reynolds numbers of practical importance. The experimental investigations of this work include various radial locations along the height of the bed. It was found that an increase in coolant gas flow velocity causes an increase in the heat transfer coefficient and that effect of the gas flow rate varies from laminar to turbulent flow regimes at all radial positions of the studied packed pebble-bed reactor. The results show that the local heat transfer coefficient increases from the bed center to the wall due to the change in the bed structure, and hence, in the flow pattern of the coolant gas. The findings clearly indicate that one value of an overall heat transfer coefficient cannot represent the local heat transfer coefficients within the bed; therefore, correlations are needed to

  16. Core-adjacent instrumentation systems for pebble bed reactors for process heat application - state of planning

    International Nuclear Information System (INIS)

    Benninghofen, G.; Serafin, N.; Spillekothen, H.G.; Hecker, R.; Brixy, H.; Serpekian, T.

    1982-06-01

    Planning and theoretical/experimental development work for core surveillance instrumentation systems is being performed to meet requirements of pebble bed reactors for process heat application. Detailed and proved instrumentation concepts are now available for the core-adjacent instrumentation systems. The current work and the results of neutron flux measurements at high temperatures are described. Operation devices for long-term accurate gas outlet temperature measurements up to approximately 1423 deg. K will also be discussed. (author)

  17. Modeling and Performance of Waste Tires as Media in Fixed Bed Sequence Batch Reactor

    Directory of Open Access Journals (Sweden)

    Zahra Derakhshan

    2016-12-01

    Results: The maximum removal efficiencies of dissolved chemical oxygen demand for FBSBR and SBR reactors were 98.3 % and 97.9 %, respectively. In addition, Stover-Kincannon model provided a very suitable fitness (R2   > 0.99 for loading the bioreactor FBSBR. Conclusion: According to the results, not only waste tires can be reused, but also these wastes can be employed as a proper biological bed in wastewater refineries to improve their efficiency.

  18. Trickle bed reactor for the oxidation of phenol over active carbon catalyst

    OpenAIRE

    Gabbiye, Nigus; Font Capafons, Josep; Fortuny Sanromá, Agustín; Bengoa, Christophe José; Fabregat Llangotera, Azael; Stüber, Frank Erich

    2009-01-01

    The catalytic wet air oxidation of phenol using activated carbon has been performed in a laboratory trickle bed reactor over a wide range of operating variables (PO2, T, FL and Cph,o) and hydrodynamic conditions. The influence of different start-up procedures (saturation of activated carbon) has also been tested. Further improvement of activity and stability has been checked for by using dynamic TBR operation concept or impregnated Fe/carbon catalyst. The results obtained confi...

  19. PEBBLES: A COMPUTER CODE FOR MODELING PACKING, FLOW AND RECIRCULATIONOF PEBBLES IN A PEBBLE BED REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    Joshua J. Cogliati; Abderrafi M. Ougouag

    2006-10-01

    A comprehensive, high fidelity model for pebble flow has been developed and embodied in the PEBBLES computer code. In this paper, a description of the physical artifacts included in the model is presented and some results from using the computer code for predicting the features of pebble flow and packing in a realistic pebble bed reactor design are shown. The sensitivity of models to various physical parameters is also discussed.

  20. Cleaning of porous filters in fluidized bed reactors. Use of one ejector for various filters

    International Nuclear Information System (INIS)

    Sancho Rod, J.; Rodrigo Otero, A.

    1966-01-01

    Tests to know the efficiency of a porous filters cleaning system by blow-back that uses on ejector for each set of simultaneously cleaned filters were carried out. A Calculation method to obtain the optimum ejector for this system was shown, taking n=2, as optimum number of working for the fluidized bed reactors belonging to the Pilot plant of the Materials Division at JEN. That is two filters for each ejector. (Author)

  1. Ozo-Dyes mixture degradation in a fixed bed biofilm reactor packed with volcanic porous rock

    International Nuclear Information System (INIS)

    Contreras-Blancas, E.; Cobos-Vasconcelos, D. de los; Juarez-Ramirez, C.; Poggi-Varaldo, H. M.; Ruiz-Ordaz, N.; Galindez-Mayer, J.

    2009-01-01

    Textile industries discharge great amounts of dyes and dyeing-process auxiliaries, which pollute streams and water bodies. Several dyes, especially the ones containing the azo group, can cause harmful effects to different organisms including humans. Through bacterial and mammalian tests, azo dyes or their derived aromatic amines have shown cell genotoxicity. The purpose of this work was to evaluate the effect of air flow rate on azo-dyes mixture biodegradation by a microbial community immobilized in a packed bed reactor. (Author)

  2. Computer-aided modeling framework – a generic modeling template for catalytic membrane fixed bed reactors

    DEFF Research Database (Denmark)

    Fedorova, Marina; Sin, Gürkan; Gani, Rafiqul

    2013-01-01

    and users to generate and test models systematically, efficiently and reliably. In this way, development of products and processes can be faster, cheaper and very efficient. In this contribution, as part of the framework a generic modeling template for the systematic derivation of problem specific catalytic...... membrane fixed bed models is developed. The application of the modeling template is highlighted with a case study related to the modeling of a catalytic membrane reactor coupling dehydrogenation of ethylbenzene with hydrogenation of nitrobenzene....

  3. A bibliographic review of mathematical models of packed-bed biological reactors (PBR

    Directory of Open Access Journals (Sweden)

    Deisy Corredor

    2005-09-01

    Full Text Available Several authors have sublected packed-bed biological reactors to mathematical and theoretical analysis. They have taken reaction kinetics and single-dimensional, homogeneous, pseudo-homogeneous and heterogeneous models into account. Numerical methods have provided the set of equations so developed. The effect of physically important process variables in terms of design and operation have been investigated (i.e. residence time, operating- flow, substrate conversion, bio-film area and film thickness.

  4. A particle bed reactor based NTP in the 112,500 N thrust class

    International Nuclear Information System (INIS)

    Ludewig, H.; Powell, J.R.; Lazareth, O.W. Jr.; Todosow, M.

    1993-01-01

    This paper discusses the application of a Particle Bed Reactor (PBR) to a 112,500 N thrust Nuclear Thermal Propulsion (NTP) Engine. The method of analysis is described, followed by a presentation of the results. It is concluded that the PBR would result in a very competitive NTP engine. In addition, due to the high power densities possible with a PBR, high thrust/weight ratios are possible. This conclusion can be used to satisfy a variety of mission goals

  5. A particle bed reactor based NTP in the 112,500 N thrust class

    Science.gov (United States)

    Ludewig, Hans; Powell, James R.; Lazareth, Otto W.; Todosow, Michael

    1993-01-01

    This paper discusses the application of a Particle Bed Reactor (PBR) to a 112,500 N thrust Nuclear Thermal Propulsion (NTP) Engine. The method of analysis is described, followed by a presentation of the results. It is concluded that the PBR would result in a very competitive NTP engine. In addition, due to the high power densities possible with a PBR, high thrust/weight ratios are possible. This conclusion can be used to satisfy a variety of mission goals.

  6. Immobilised native plant cysteine proteases: packed-bed reactor for white wine protein stabilisation

    OpenAIRE

    Benucci, Ilaria; Lombardelli, Claudio; Liburdi, Katia; Acciaro, Giuseppe; Zappino, Matteo; Esti, Marco

    2015-01-01

    This research presents a feasibility study of using a continuous packed-bed reactor (PBR), containing immobilised native plant cysteine proteases, as a specific and mild alternative technique relative to the usual bentonite fining for white wine protein stabilisation. The operational parameters for a PBR containing immobilised bromelain (PBR-br) or immobilised papain (PBR-pa) were optimised using model wine fortified with synthetic substrate (Bz-Phe-Val-Arg-pNA). The effectiveness of PBR-br, ...

  7. Nuclear thermal propulsion engine based on particle bed reactor using light water steam as a propellant

    Science.gov (United States)

    Powell, James R.; Ludewig, Hans; Maise, George

    1993-01-01

    In this paper the possibility of configuring a water cooled Nuclear Thermal Propulsion (NTP) rocket, based on a Particle Bed Reactor (PBR) is investigated. This rocket will be used to operate on water obtained from near earth objects. The conclusions reached in this paper indicate that it is possible to configure a PBR based NTP rocket to operate on water and meet the mission requirements envisioned for it. No insurmountable technology issues have been identified.

  8. Operation of a steam hydro-gasifier in a fluidized bed reactor

    OpenAIRE

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    Carbonaceous material, which can comprise municipal waste, biomass, wood, coal, or a natural or synthetic polymer, is converted to a stream of methane and carbon monoxide rich gas by heating the carbonaceous material in a fluidized bed reactor using hydrogen, as fluidizing medium, and using steam, under reducing conditions at a temperature and pressure sufficient to generate a stream of methane and carbon monoxide rich gas but at a temperature low enough and/or at a pressure high enough to en...

  9. Ozo-Dyes mixture degradation in a fixed bed biofilm reactor packed with volcanic porous rock

    Energy Technology Data Exchange (ETDEWEB)

    Contreras-Blancas, E.; Cobos-Vasconcelos, D. de los; Juarez-Ramirez, C.; Poggi-Varaldo, H. M.; Ruiz-Ordaz, N.; Galindez-Mayer, J.

    2009-07-01

    Textile industries discharge great amounts of dyes and dyeing-process auxiliaries, which pollute streams and water bodies. Several dyes, especially the ones containing the azo group, can cause harmful effects to different organisms including humans. Through bacterial and mammalian tests, azo dyes or their derived aromatic amines have shown cell genotoxicity. The purpose of this work was to evaluate the effect of air flow rate on azo-dyes mixture biodegradation by a microbial community immobilized in a packed bed reactor. (Author)

  10. Nuclear thermal propulsion engine based on particle bed reactor using light water steam as a propellant

    International Nuclear Information System (INIS)

    Powell, J.R.; Ludewig, H.; Maise, G.

    1993-01-01

    In this paper the possibility of configuring a water cooled Nuclear Thermal Propulsion (NTP) rocket, based on a Particle Bed Reactor (PBR) is investigated. This rocket will be used to operate on water obtained from near earth objects. The conclusions reached in this paper indicate that it is possible to configure a PBR based NTP rocket to operate on water and meet the mission requirements envisioned for it. No insurmountable technology issues have been identified

  11. Liquid distribution in trickle-bed reactor; Distribution du liquide en reacteur a lit ruisselant

    Energy Technology Data Exchange (ETDEWEB)

    Marcandelli, C.; Wild, G. [Centre National de la Recherche Scientifique (CNRS-ENSIC), Lab. des Sciences du Genie Chimique, 54 - Nancy (France); Lamine, A.S. [CNRS-Universite de Paris-Nord, Lab. d' Ingenierie des Materiaux et des Hautes Pressions, 93 - Villetaneuse (France); Bernard, J.R. [Elf Antar France, Centre de Recherche Elf de Solaize, 69 - Solaize (France)

    2000-07-01

    The aim of this study is to develop techniques to qualify the efficiency of liquid distribution in trickle-bed reactors, using cold mockups. The experimental setup consists mainly in a 0.3-m-ID packed-bed column with three different plates used to vary the quality of inlet liquid distribution. Liquid distribution has been qualified using several techniques: global pressure drop measurements, global RTD (Residence-Time Distribution) of the liquid, local heat transfer probes, capacitance tomography, collector at the bottom of the reactor with nine equal zones. The bed pressure drop and the overall external liquid saturation decrease when the maldistribution increases; quantitative information is however difficult to obtain this way. Global RTD of the liquid allows quantifying of the average liquid distribution in the bed. The local thermal sensors give an indication of local liquid velocity and indicate possible local maldistribution of the liquid (scale mm) even when global distribution is good. Concerning the results obtained with the collector, a maldistribution index is defined ranging from 0 (ideal distribution) to 1 (worst possible distribution), and the influence of the different operating parameters (gas and liquid velocities, particle shape) is discussed. (authors)

  12. Random detailed model for probabilistic neutronic calculation in pebble bed Very High Temperature Reactors

    International Nuclear Information System (INIS)

    Perez Curbelo, J.; Rosales, J.; Garcia, L.; Garcia, C.; Brayner, C.

    2013-01-01

    The pebble bed nuclear reactor is one of the main candidates for the next generation of nuclear power plants. In pebble bed type HTRs, the fuel is contained within graphite pebbles in the form of TRISO particles, which form a randomly packed bed inside a graphite-walled cylindrical cavity. Pebble bed reactors (PBR) offer the opportunity to meet the sustainability requirements, such as nuclear safety, economic competitiveness, proliferation resistance and a minimal production of radioactive waste. In order to simulate PBRs correctly, the double heterogeneity of the system must be considered. It consists on randomly located pebbles into the core and TRISO particles into the fuel pebbles. These features are often neglected due to the difficulty to model with MCPN code. The main reason is that there is a limited number of cells and surfaces to be defined. In this study, a computational tool which allows getting a new geometrical model of fuel pebbles for neutronic calculations with MCNPX code, was developed. The heterogeneity of system is considered, and also the randomly located TRISO particles inside the pebble. Four proposed fuel pebble models were compared regarding their effective multiplication factor and energy liberation profiles. Such models are: Homogeneous Pebble, Five Zone Homogeneous Pebble, Detailed Geometry, and Randomly Detailed Geometry. (Author)

  13. Chaotic behavior in a hydrodynamic model of a fluidized bed reactor

    International Nuclear Information System (INIS)

    Schouten, J.C.; van den Bleek, C.M.

    1991-01-01

    Recent preliminary experimental studies using time-series analysis have demonstrated that the multi-phase flow in fluidized bed reactors can be characterized as chaotic. In the present paper, it is therefore argued that the chaotic time-dependence of fluidization is a characteristic feature which should be included in scaling rules for fluidized bed reactors. For example, the similarity groups applied in dimensionless fluidized bed scaling should be improved by extending them with functions of the relevant numbers from chaos theory, such as the correlation and embedding dimension or the maximum Lyapunov exponent. This requires that the dependence of these numbers on fluidization parameters must be theoretically and experimentally investigated. The concept of chaos in fluidization also requires that the classical, empirically developed, hydrodynamic models that are applied in fluidized bed scaling are amended to include time-dependence, non-linearity as well as a sufficient level of complexity before they can predict any chaotic behavior. An example is given of chaotic behavior generated in the classical counter-current flow model according to Van Deemter by writing the upwards solids velocity as a harmonic oscillating function of time. A low-dimensional strange attractor is found, embedded in two-dimensional phase space, of which the correlation dimension depends on the solids exchange coefficient

  14. Advanced Core Design And Fuel Management For Pebble-Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hans D. Gougar; Abderrafi M. Ougouag; William K. Terry

    2004-10-01

    A method for designing and optimizing recirculating pebble-bed reactor cores is presented. At the heart of the method is a new reactor physics computer code, PEBBED, which accurately and efficiently computes the neutronic and material properties of the asymptotic (equilibrium) fuel cycle. This core state is shown to be unique for a given core geometry, power level, discharge burnup, and fuel circulation policy. Fuel circulation in the pebble-bed can be described in terms of a few well?defined parameters and expressed as a recirculation matrix. The implementation of a few heat?transfer relations suitable for high-temperature gas-cooled reactors allows for the rapid estimation of thermal properties critical for safe operation. Thus, modeling and design optimization of a given pebble-bed core can be performed quickly and efficiently via the manipulation of a limited number key parameters. Automation of the optimization process is achieved by manipulation of these parameters using a genetic algorithm. The end result is an economical, passively safe, proliferation-resistant nuclear power plant.

  15. Molecular analysis of the biomass of a fluidized bed reactor treating synthetic vinasse at anaerobic and micro-aerobic conditions

    NARCIS (Netherlands)

    Rodriguez, E.; Lopes, A.; Fdz-Polanco, M.; Stams, A.J.M.; Garcia Encina, P.A.

    2012-01-01

    The microbial communities (Bacteria and Archaea) established in an anaerobic fluidized bed reactor used to treat synthetic vinasse (betaine, glucose, acetate, propionate, and butyrate) were characterized by denaturing gradient gel electrophoresis (DGGE) and phylogenetic analysis. This study was

  16. Studi Awal Desain Pebble Bed Reactor Berbasis Htr-pm Dengan Skema Resirkulasi Bahan Bakar Once-through-then-out

    OpenAIRE

    Setiadipura, Topan; Pane, Jupiter Sitorus; Zuhair, Zuhair

    2016-01-01

    STUDI AWAL DESAIN PEBBLE BED REACTOR BERBASIS HTR-PM DENGAN RESIRKULASI BAHAN BAKAR ONCE-THROUGH-THEN-OUT. Reaktor nuklir tipe pebble bed reactor (PBR) adalah salah satu reaktor canggih dengan fitur keselamatan pasif yang kuat. Pada desain tipe ini berpotensi untuk dilakukan kogenerasi yang bermanfaat untuk pengolahan berbagai mineral di berbagai pulau di Indonesia. Operasi PBR dapat lebih disederhanakan dengan menerapkan skema pengisian bahan bakar once-through-then-out (OTTO) dimana bahan b...

  17. Design Strategy for CO2 Adsorption from Ambient Air Using a Supported Amine Based Sorbent in a Fixed Bed Reactor

    NARCIS (Netherlands)

    Yu, Qian; Brilman, D. W.F.

    In this work, a fixed bed reactor is evaluated for CO2 capture from ambient air using an amine based ion exchange resin. Using adsorption experiments, the effect of superficial velocity and bed length on process economics is investigated. It is shown that the optimal conditions are found at an

  18. A simulation of a pebble bed reactor core by the MCNP-4C computer code

    Directory of Open Access Journals (Sweden)

    Bakhshayesh Moshkbar Khalil

    2009-01-01

    Full Text Available Lack of energy is a major crisis of our century; the irregular increase of fossil fuel costs has forced us to search for novel, cheaper, and safer sources of energy. Pebble bed reactors - an advanced new generation of reactors with specific advantages in safety and cost - might turn out to be the desired candidate for the role. The calculation of the critical height of a pebble bed reactor at room temperature, while using the MCNP-4C computer code, is the main goal of this paper. In order to reduce the MCNP computing time compared to the previously proposed schemes, we have devised a new simulation scheme. Different arrangements of kernels in fuel pebble simulations were investigated and the best arrangement to decrease the MCNP execution time (while keeping the accuracy of the results, chosen. The neutron flux distribution and control rods worth, as well as their shadowing effects, have also been considered in this paper. All calculations done for the HTR-10 reactor core are in good agreement with experimental results.

  19. Performance Evaluation of Moving Bed Bio Film Reactor in Saline Wastewater Treatment

    Directory of Open Access Journals (Sweden)

    M Ahmadi

    2013-06-01

    Full Text Available Background and purpose:Moving Bed Biofilm Reactor is an aerobic attached growth with better biofilm thickness control, lack of plugging and lower head loss. Consequently, this system is greatly used by different wastewater treatment plants. High TDS wastewater produced petrochemical, leather tanning, sea food processing, cannery, pickling and dairy industries. The aim of this study was to evaluate the performance of MBBR in saline wastewater treatment. Materials and methods: In this study, 50 percent of a cylindrical reactor with 9.5 liter occupied media with 650 m2.m-3. In the first step, hydraulic regime was evaluated and startup reactor was done by sanitary sludge. Bio film was generated with glucose as the sole carbon source in synthetic wastewater. MBBR performance evaluation was performed in 6:30 and 8:45 with saline wastewater after bio film produced on media. Results: After 83 days of passing MBBR operation with saline wastewater containing 3000-12000 mg.L-1 TDS, organic loading rate of 2.2-3.5 kg/m3.d COD removal efficiency reached 80-92%. Conclusion: Moving bed biofilm reactor is effective in organic load elimination from saline wastewater.

  20. Gas-Liquid Two-Phase Flows Through Packed Bed Reactors in Microgravity

    Science.gov (United States)

    Motil, Brian J.; Balakotaiah, Vemuri

    2001-01-01

    The simultaneous flow of gas and liquid through a fixed bed of particles occurs in many unit operations of interest to the designers of space-based as well as terrestrial equipment. Examples include separation columns, gas-liquid reactors, humidification, drying, extraction, and leaching. These operations are critical to a wide variety of industries such as petroleum, pharmaceutical, mining, biological, and chemical. NASA recognizes that similar operations will need to be performed in space and on planetary bodies such as Mars if we are to achieve our goals of human exploration and the development of space. The goal of this research is to understand how to apply our current understanding of two-phase fluid flow through fixed-bed reactors to zero- or partial-gravity environments. Previous experiments by NASA have shown that reactors designed to work on Earth do not necessarily function in a similar manner in space. Two experiments, the Water Processor Assembly and the Volatile Removal Assembly have encountered difficulties in predicting and controlling the distribution of the phases (a crucial element in the operation of this type of reactor) as well as the overall pressure drop.

  1. Numerical Simulation of a Coolant Flow and Heat Transfer in a Pebble Bed Reactor

    International Nuclear Information System (INIS)

    In, Wang-Kee; Kim, Min-Hwan; Lee, Won-Jae

    2008-01-01

    Pebble Bed Reactor(PBR) is one of the very high temperature gas cooled reactors(VHTR) which have been reviewed in the Generation IV International Forum as potential sources for future energy needs, particularly for a hydrogen production. The pebble bed modular reactor(PBMR) exhibits inherent safety features due to the low power density and the large amount of graphite present in the core. PBR uses coated fuel particles(TRISO) embedded in spherical graphite fuel pebbles. The fuel pebbles flow down through the PBR core during a reactor operation and the coolant flows around randomly distributed spheres. For the reliable operation and the safety of the PBR, it is important to understand the coolant flow structure and the fuel pebble temperature in the PBR core. There have been few experimental and numerical studies to investigate the fluid and heat transfer phenomena in the PBR core. The objective of this paper is to predict the fluid and heat transfer in the PBR core. The computational fluid dynamics (CFD) code, STAR-CCM+(V2.08) is used to perform the CFD analysis using the design data for the PBMR400

  2. Optimized Core Design and Fuel Management of a Pebble-Bed Type Nuclear Reactor

    International Nuclear Information System (INIS)

    Boer, Brian

    2007-01-01

    The Very High Temperature Reactor (VHTR) has been selected by the international Generation IV research initiative as one of the six most promising nuclear reactor concepts that are expected to enter service in the second half of the 21st century. The VHTR is characterized by a high plant efficiency and a high fuel discharge burnup level. More specifically, the (pebble-bed type) High Temperature Reactor (HTR) is known for its inherently safe characteristics, coming from a negative temperature reactivity feedback, a low power density and a large thermal inertia of the core. The core of a pebble-bed reactor consists of graphite spheres (pebbles) that form a randomly packed porous bed, which is cooled by high pressure helium. The pebbles contain thousands of fuel particles, which are coated with several pyrocarbon and silicon carbon layers that are designed to contain the fission products that are formed during operation of the reactor. The inherent safety concept has been demonstrated in small pebble-bed reactors in practice, but an increase in the reactor size and power is required for cost-effective power production. An increase of the power density in order to increase the helium coolant outlet temperature is attractive with regard to the efficiency and possible process heat applications. However, this increase leads in general to higher fuel temperatures, which could lead to a consequent increase of the fuel coating failure probability. This thesis deals with the pebble-bed type VHTR that aims at an increased coolant outlet temperature of 1000 degrees C and beyond. For the simulation of the neutronic and thermal-hydraulic behavior of the reactor the DALTON-THERMIX coupled code system has been developed and has been validated against experiments performed in the AVR and HTR-10 reactors. An analysis of the 400 MWth Pebble Bed Modular Reactor (PBMR) design shows that the inherent safety concept that has been demonstrated in practice in the smaller AVR and HTR-10

  3. Influence of operating pressure on the biological hydrogen methanation in trickle-bed reactors.

    Science.gov (United States)

    Ullrich, Timo; Lindner, Jonas; Bär, Katharina; Mörs, Friedemann; Graf, Frank; Lemmer, Andreas

    2018-01-01

    In order to investigate the influence of pressures up to 9bar absolute on the productivity of trickle-bed reactors for biological methanation of hydrogen and carbon dioxide, experiments were carried out in a continuously operated experimental plant with three identical reactors. The pressure increase promises a longer residence time and improved mass transfer of H 2 due to higher gas partial pressures. The study covers effects of different pressures on important parameters like gas hourly space velocity, methane formation rate, conversion rates and product gas quality. The methane content of 64.13±3.81vol-% at 1.5bar could be increased up to 86.51±0.49vol-% by raising the pressure to 9bar. Methane formation rates of up to 4.28±0.26m 3 m -3 d -1 were achieved. Thus, pressure increase could significantly improve reactor performance. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Las degradation in a fluidized bed reactor and phylogenetic characterization of the biofilm

    Directory of Open Access Journals (Sweden)

    L. L. Oliveira

    2013-09-01

    Full Text Available A fluidized bed reactor was used to study the degradation of the surfactant linear alkylbenzene sulfonate (LAS. The reactor was inoculated with anaerobic sludge and was fed with a synthetic substrate supplemented with LAS in increasing concentrations (8.2 to 45.8 mg l-1. The removal efficiency of 93% was obtained after 270 days of operation. Subsequently, 16S rRNA gene sequencing and phylogenetic analysis of the sample at the last stage of the reactor operation recovered 105 clones belonging to the domain Bacteria. These clones represented a variety of phyla with significant homology to Bacteroidetes (40%, Proteobacteria (42%, Verrucomicrobia (4%, Acidobacteria (3%, Firmicutes (2%, and Gemmatimonadetes (1%. A small fraction of the clones (8% was not related to any phylum. Such phyla variety indicated the role of microbial consortia in degrading the surfactant LAS.

  5. Phenol degradation in an anaerobic fluidized bed reactor packed with low density support materials

    Directory of Open Access Journals (Sweden)

    G. P. Sancinetti

    2012-03-01

    Full Text Available The objective of this research was to study phenol degradation in anaerobic fluidized bed reactors (AFBR packed with polymeric particulate supports (polystyrene - PS, polyethylene terephthalate - PET, and polyvinyl chloride - PVC. The reactors were operated with a hydraulic retention time (HRT of 24 h. The influent phenol concentration in the AFBR varied from 100 to 400 mg L-1, resulting in phenol removal efficiencies of ~100%. The formation of extracellular polymeric substances yielded better results with the PVC particles; however, deformations in these particles proved detrimental to reactor operation. PS was found to be the best support for biomass attachment in an AFBR for phenol removal. The AFBR loaded with PS was operated to analyze the performance and stability for phenol removal at feed concentrations ranging from 50 to 500 mg L-1. The phenol removal efficiency ranged from 90-100%.

  6. Sequential UASB and dual media packed-bed reactors for domestic wastewater treatment - experiment and simulation.

    Science.gov (United States)

    Rodríguez-Gómez, Raúl; Renman, Gunno

    2016-01-01

    A wastewater treatment system composed of an upflow anaerobic sludge blanket (UASB) reactor followed by a packed-bed reactor (PBR) filled with Sorbulite(®) and Polonite(®) filter material was tested in a laboratory bench-scale experiment. The system was operated for 50 weeks and achieved very efficient total phosphorus (P) removal (99%), 7-day biochemical oxygen demand removal (99%) and pathogenic bacteria reduction (99%). However, total nitrogen was only moderately reduced in the system (40%). A model focusing on simulation of organic material, solids and size of granules was then implemented and validated for the UASB reactor. Good agreement between the simulated and measured results demonstrated the capacity of the model to predict the behaviour of solids and chemical oxygen demand, which is critical for successful P removal and recovery in the PBR.

  7. Cold flow study of liquid cooled pebble bed reactor (LC-PBR) through radioisotope techniques

    International Nuclear Information System (INIS)

    Verma, Rupesh; Upadhyay, Rajesh K.; Pant, H.J.

    2017-01-01

    As the world's demand for energy continues to increase burning of coal, oil and natural gases continue to increase which will eventually cause build-up in emission of greenhouse gasses. To overcome this challenge worldwide effort is in progress to develop an economical, more efficient and safer nuclear power. Higher thermal efficiency and enhances safety feature of Generation IV liquid cooled pebble bed reactor (LC-PBR) makes it viable option to replace existing nuclear reactor. However, this reactor is still in research stage and need detailed study before commercialization. In current work, hydrodynamics of LC-PBR is studied by using radioisotope based techniques, radioactive particle tracking and gamma-ray densitometry. Pebble flow profile and distribution are measured for different operating conditions. Optimal operating parameters are identified for operating LC-PBR based on hydrodynamics. (author)

  8. Butanol production by Clostridium acetobutylicum in a continuous packed bed reactor.

    Science.gov (United States)

    Napoli, Fabio; Olivieri, Giuseppe; Russo, Maria Elena; Marzocchella, Antonio; Salatino, Piero

    2010-06-01

    In this study, we report on a butanol production process by immobilized Clostridium acetobutylicum in a continuous packed bed reactor (PBR) using Tygon rings as a carrier. The medium was a solution of lactose (15-30 g/L) and yeast extract (3 g/L) to emulate the cheese whey, an abundant lactose-rich wastewater. The reactor was operated under controlled conditions with respect to the pH and to the dilution rate. The pH and the dilution rate ranged between 4 and 5, the dilution rate between 0.54 and 2.4 h(-1) (2.5 times the maximum specific growth rate assessed for suspended cells). The optimal performance of the reactor was recorded at a dilution rate of 0.97 h(-1): the butanol productivity was 4.4 g/Lh and the selectivity of solvent in butanol was 88%(w).

  9. Gas Reactor International Cooperative program. Pebble bed reactor plant: screening evaluation. Volume 2. Conceptual balance of plant design

    Energy Technology Data Exchange (ETDEWEB)

    1979-11-01

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW(t) Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. This volume describes the conceptual balance-of-plant (BOP) design and was prepared by United Engineers and Constructors, Inc. of Philadelphia, Pennsylvania. The major emphasis of the BOP study was a preliminary design of an overall plant to provide a basis for future studies.

  10. Gas Reactor International Cooperative program. Pebble bed reactor plant: screening evaluation. Volume 2. Conceptual balance of plant design

    International Nuclear Information System (INIS)

    1979-11-01

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW(t) Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. This volume describes the conceptual balance-of-plant (BOP) design and was prepared by United Engineers and Constructors, Inc. of Philadelphia, Pennsylvania. The major emphasis of the BOP study was a preliminary design of an overall plant to provide a basis for future studies

  11. Strategies for the startup of methanogenic inverse fluidized-bed reactors using colonized particles.

    Science.gov (United States)

    Alvarado-Lassman, A; Sandoval-Ramos, A; Flores-Altamirano, M G; Vallejo-Cantú, N A; Méndez-Contreras, J M

    2010-05-01

    One of the inconveniences in the startup of methanogenic inverse fluidized-bed reactors (IFBRs) is the long period required for biofilm formation and stabilization of the system. Previous researchers have preferred to start up in batch mode to shorten stabilization times. Much less work has been done with continuous-mode startup for the IFBR configuration of reactors. In this study, we prepared two IFBRs with similar characteristics to compare startup times for batch- and continuous-operation modes. The reactors were inoculated with a small quantity of colonized particles and run for a period of 3 months, to establish the optimal startup strategy using synthetic media as a substrate (glucose as a source of carbon). After the startup stage, the continuous- and batch-mode reactors removed more than 80% of the chemical oxygen demand (COD) in 51 and 60 days of operation, respectively; however, at the end of the experiments, the continuous-mode reactor had more biomass attached to the support media than the batch-mode reactor. Both reactors developed fully covered support media, but only the continuous-mode reactor had methane yields close to the theoretical value that is typical of stable reactors. Then, a combined startup strategy was proposed, with industrial wastewater as the substrate, using a sequence of batch cycles followed by continuous operation, which allows stable operation at an organic loading rate of 20 g COD/L x d in 15 days. Using a fraction of colonized support as an inoculum presents advantages, with respect to previously reported strategies.

  12. Effect of sulfide concentration on the location of the metal precipitates in inversed fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Villa-Gomez, D., E-mail: d.villagomez@unesco-ihe.org [Core Pollution Prevention and Control, UNESCO-IHE, Institute for Water Education, PO Box 3015, 2601 DA Delft (Netherlands); Ababneh, H.; Papirio, S.; Rousseau, D.P.L.; Lens, P.N.L. [Core Pollution Prevention and Control, UNESCO-IHE, Institute for Water Education, PO Box 3015, 2601 DA Delft (Netherlands)

    2011-08-15

    Highlights: {yields} Sulfide concentration governs the location of metal precipitates in sulfate reducing bioreactors. {yields} High dissolved sulfide induces metal precipitation in the bulk liquid as fines. {yields} Low dissolved sulfide concentrations yield local supersaturation and thus metal precipitation in the biofilm. -- Abstract: The effect of the sulfide concentration on the location of the metal precipitates within sulfate-reducing inversed fluidized bed (IFB) reactors was evaluated. Two mesophilic IFB reactors were operated for over 100 days at the same operational conditions, but with different chemical oxygen demand (COD) to SO{sub 4}{sup 2-} ratio (5 and 1, respectively). After a start up phase, 10 mg/L of Cu, Pb, Cd and Zn each were added to the influent. The sulfide concentration in one IFB reactor reached 648 mg/L, while it reached only 59 mg/L in the other one. In the high sulfide IFB reactor, the precipitated metals were mainly located in the bulk liquid (as fines), whereas in the low sulfide IFB reactor the metal preciptiates were mainly present in the biofilm. The latter can be explained by local supersaturation due to sulfide production in the biofilm. This paper demonstrates that the sulfide concentration needs to be controlled in sulfate reducing IFB reactors to steer the location of the metal precipitates for recovery.

  13. Global scaling analysis for the pebble bed advanced high temperature reactor

    International Nuclear Information System (INIS)

    Blandford, E.D.; Peterson, P.F.

    2009-01-01

    Scaled Integral Effects Test (IET) facilities play a critical role in the design certification process of innovative reactor designs. Best-estimate system analysis codes, which minimize deliberate conservatism, require confirmatory data during the validation process to ensure an acceptable level of accuracy as defined by the regulator. The modular Pebble Bed Advanced High Temperature Reactor (PB-AHTR), with a nominal power output of 900 MWth, is the most recent UC Berkeley design for a liquid fluoride salt cooled, solid fuel reactor. The PB-AHTR takes advantage of technologies developed for gas-cooled high temperature thermal and fast reactors, sodium fast reactors, and molten salt reactors. In this paper, non-dimensional scaling groups and similarity criteria are presented at the global system level for a loss of forced circulation transient, where single-phase natural circulation is the primary mechanism for decay heat removal following a primary pump trip. Due to very large margin to fuel damage temperatures, the peak metal temperature of primary-loop components was identified as the key safety parameter of interest. Fractional Scaling Analysis (FSA) methods were used to quantify the intensity of each transfer process during the transient and subsequently rank them by their relative importance while identifying key sources of distortion between the prototype and model. The results show that the development of a scaling hierarchy at the global system level informs the bottom-up scaling analysis. (author)

  14. Dynamic analysis and application of fuel elements pneumatic transportation in a pebble bed reactor

    International Nuclear Information System (INIS)

    Liu, Hongbing; Du, Dong; Han, Zandong; Zou, Yirong; Pan, Jiluan

    2015-01-01

    Almost 10,000 spherical fuel elements are transported pneumatically one by one in the pipeline outside the core of a pebble bed reactor every day. Any failure in the transportation will lead to the shutdown of the reactor, even safety accidents. In order to ensure a stable and reliable transportation, it's of great importance to analyze the motion and force condition of the fuel element. In this paper, we focus on the dynamic analysis of the pneumatic transportation of the fuel element and derive kinetic equations. Then we introduce the design of the transportation pipeline. On this basis we calculate some important data such as the velocity of the fuel element, the force between the fuel element and the pipeline and the efficiency of the pneumatic transportation. Then we analyze these results and provide some suggestions for the design of the pipeline. The experiment was carried out on an experimental platform. The velocities of the fuel elements were measured. The experimental results were consistent with and validated the theoretical analysis. The research may offer the basis for the design of the transportation pipeline and the optimization of the fuel elements transportation in a pebble bed reactor. - Highlights: • The kinetic equations of the fuel element in pneumatic transportation are derived. • The dynamic characteristics of the fuel element are analyzed. • Some important parameters are calculated based on the kinetic equations. • The experimental results were consistent with the analysis and verified the analysis. • This paper may offer an important guide to the research of a pebble bed reactor

  15. Experimental and modelling study of drinking water hydrogenotrophic denitrification in packed-bed reactors

    International Nuclear Information System (INIS)

    Vasiliadou, I.A.; Karanasios, K.A.; Pavlou, S.; Vayenas, D.V.

    2009-01-01

    The aim of this work was to study hydrogenotrophic denitrification in packed-bed reactors under draw-fill and continuous operation. Three bench-scale packed-bed reactors with gravel in different sizes (mean diameter 1.75, 2.41 and 4.03 mm) as support media were used, in order to study the effect of particle size on reactors performance. The maximum denitrification rate achieved under draw-fill operation was 4.4 g NO 3 - -N/ld for the filter with gravel of 2.41 mm. This gravel size was chosen to perform experiments under continuous operation. Feed NO 3 - -N concentrations and hydraulic loadings (HL) ranged between 20-200 mg/l and 5.7-22.8 m 3 /m 2 d, respectively. A comparison between the two operating modes showed that, for low HL the draw-fill operation achieved higher denitrification rates, while for high HL and intermediate feed concentrations (40-60 mg NO 3 - -N/l) the continuous operation achieved higher denitrification rates (4.67-5.65 g/ld). Finally, experiments with three filters in series (with gravels of 4.03, 2.41 and 1.75 mm mean diameter) were also performed under continuous operation. The maximum denitrification rate achieved was 6.2 g NO 3 - -N/ld for feed concentration of 340 mg/l and HL of 11.5 m 3 /m 2 d. A model, which describes denitrification in packed-bed reactors, was also developed. The model predicts the concentration profiles of NO 3 - -N along filter height, in draw-fill as well as in continuous operation, satisfactorily.

  16. Pebble bed reactors simulation using MCNP: The Chinese HTR-10 reactor

    Directory of Open Access Journals (Sweden)

    SA Hosseini

    2013-09-01

    Full Text Available   Given the role of Gas-Graphite reactors as the fourth generation reactors and their recently renewed importance, in 2002 the IAEA proposed a set of Benchmarking problems. In this work, we propose a model both efficient in time and resources and exact to simulate the HTR-10 reactor using MCNP-4C code. During the present work, all of the pressing factors in PBM reactor design such as the inter-pebble leakage, fuel particle distribution and fuel pebble packing fraction effects have been taken into account to obtain an exact and easy to run model. Finally, the comparison between the results of the present work and other calculations made at INEEL proves the exactness of the proposed model.

  17. Galacto-oligosaccharide production with immobilized ß-galactosidase in a packed-bed reactor vs. free ß-galactosidase in a batch reactor

    NARCIS (Netherlands)

    Warmerdam, A.; Benjamins, E.; Leeuw de, T.F.; Broekhuis, T.A.; Boom, R.M.; Janssen, A.E.M.

    2014-01-01

    We report here that the usage of immobilized enzyme in a continuous packed bed reactor (PBR) can be a good alternative for GOS production instead of the traditional use of free enzyme in a batch reactor. The carbohydrate composition of the product of the PBR with immobilized enzyme was comparable to

  18. Numerical investigation of the flow at the pebble bed of the high temperature gas cooled reactors

    International Nuclear Information System (INIS)

    Costa, Franklin C.; Navarro, Moyses A.; Santos, Andre A.C.

    2011-01-01

    This paper presents a numerical investigation of the thermal and fluid dynamics among the fuel spheres and the cooling fluid, appearing in the core of pebble bed reactor (PBR-Peeble Bed Reactor) using the CFD-Computational Fluid Dynamics CFX 13.0. The paper presents the two analysis results. In the first phase it was considered two heat transfer models for the fuel spheres. In a model it was established volumetric load generation, with thermal conduction for both the fuel and coating. The other model prescribes a heat flux at the sphere surfaces. In this analysis, it was proceed two simulation in the two sphere arrangements, one considering the spheres in contact, and the other with 2 mm spacing between them. At the second analysis it was evaluated the sphere arrangement influence on the thermal and fluid dynamic behavior of the bed. The four simulations present differences in the flow and in the surface and maximum temperature profiles of the coating.(author)

  19. Summary of particle bed reactor designs for the Space Nuclear Thermal Propulsion Program

    Science.gov (United States)

    Powell, J. R.; Ludewig, H.; Todosow, M.

    1993-09-01

    A summary report of the Particle Bed Reactor (PBR) designs considered for the space nuclear thermal propulsion program has been prepared. The first chapters outline the methods of analysis, and their validation. Monte Carlo methods are used for the physics analysis, several new algorithms are used for the fluid dynamics heat transfer and engine system analysis, and commercially available codes are used for the stress analysis. A critical experiment, prototypic of the PBR was used for the physics validation, and blowdown experiments using fuel beds of prototypic dimensions were used to validate the power extraction capabilities from particle beds. In all four different PBR rocket reactor designs were studied to varying degrees of detail. They varied in power from 400 MW to 2000 MW. These designs were all characterized by a negative prompt coefficient, due to Doppler feedback, and the feedback due to moderator heat up varied from slightly negative to slightly positive. In all practical cases, the coolant worth was positive, although core configurations with negative coolant worth could be designed. In all practical cases the thrust/weight ratio was greater than 20.

  20. Catalytic pyrolysis of woody biomass in a fluidized bed reactor: influence of the zeolite structure

    Energy Technology Data Exchange (ETDEWEB)

    A. Aho; N. Kumar; K. Eranen; T. Salmi; M. Hupa; D.Yu. Murzin [Aabo Akademi University, Aabo/Turku (Finland). Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering

    2008-09-15

    Catalytic pyrolysis of biomass from pine wood was carried out in a fluidized bed reactor at 450{sup o}C. Different structures of acidic zeolite catalysts were used as bed material in the reactor. Proton forms of Beta, Y, ZSM-5, and Mordenite were tested as catalysts in the pyrolysis of pine, while quartz sand was used as a reference material in the non-catalytic pyrolysis experiments. The yield of the pyrolysis product phases was only slightly influenced by the structures, at the same time the chemical composition of the bio-oil was dependent on the structure of acidic zeolite catalysts. Ketones and phenols were the dominating groups of compounds in the bio-oil. The formation of ketones was higher over ZSM-5 and the amount of acids and alcohols lower than over the other bed materials tested. Mordenite and quartz sand produced smaller quantities of polyaromatic hydrocarbons than the other materials tested. It was possible to successfully regenerate the spent zeolites without changing the structure of the zeolite. 12 refs., 9 figs., 5 tabs.

  1. Experimental investigation of pyrolysis of rice straw using bench-scale auger, batch and fluidized bed reactors

    International Nuclear Information System (INIS)

    Nam, Hyungseok; Capareda, Sergio C.; Ashwath, Nanjappa; Kongkasawan, Jinjuta

    2015-01-01

    Energy conversion efficiencies of three pyrolysis reactors (bench-scale auger, batch, and fluidized bed) were investigated using rice straw as the feedstock at a temperature of 500 °C. The highest bio-oil yield of 43% was obtained from the fluidized bed reactor, while the maximum bio-char yield of 48% was obtained from the batch reactor. Similar bio-oil yields were obtained from the auger and batch type reactors. The GCMS and FTIR were used to evaluate the liquid products from all reactors. The best quality bio-oil and bio-char from the batch reactor was determined to have a heating value of 31 MJ/kg and 19 MJ/kg, respectively. The highest alkali mineral was found in the bio-char produced from the auger reactor. The energy conversion efficiencies of the three reactors indicated that the majority of the energy (50–64%) was in the bio-char products from the auger and batch reactors, while the bio-oil from the fluidized bed reactor contained the highest energy (47%). A Sankey diagram has been produced to show the flows of product energy from each pyrolysis process. The result will help determine which conversion process would be optimal for producing specific products of bio-char, bio-oil, and gas depending on the needs. - Highlights: • Pyrolysis products from auger, batch, and fluidized bed reactor were examined. • O/C ratios of bio-oils stayed in specific ranges depending on the process reactors. • The largest quantity of bio-oil from fluidized, while the best quality from batch. • The highest alkali concentration of 37 g/kg included in the auger based bio-char. • Sankey diagram was used to understand the energy distribution from reactors.

  2. Development of a membrane-assisted fluidized bed reactor - 2 - Experimental demonstration and modeling for the partial oxidation of methanol

    NARCIS (Netherlands)

    Deshmukh, S.A.R.K.; Laverman, J.A.; van Sint Annaland, M.; Kuipers, J.A.M.

    2005-01-01

    A small laboratory-scale membrane-assisted fluidized bed reactor (MAFBR) was constructed in order to experimentally demonstrate the reactor concept for the partial oxidation of methanol to formaldehyde. Methanol conversion and product selectivities were measured at various overall fluidization

  3. Performance and population analysis of a non-sterile trickle bed reactor inoculated with Caldicellulosiruptor saccharolyticus, a thermophilic hydrogen producer

    NARCIS (Netherlands)

    Groenestijn, van J.W.; Geelhoed, J.S.; Goorissen, H.P.; Meesters, K.P.H.; Stams, A.J.M.; Claassen, P.A.M.

    2009-01-01

    Non-axenic operation of a 400 L trickle bed reactor inoculated with the thermophile Caldicellulosiruptor saccharolyticus, yielded 2.8 mol H2/mol hexose converted. The reactor was fed with a complex medium with sucrose as the main substrate, continuously flushed with nitrogen gas, and operated at

  4. Performance and population analysis of a non-sterile trickle bed reactor inoculated with caldicellulosiruptor saccharolyticus, a thermophilic hydrogen producer

    NARCIS (Netherlands)

    Groenestijn, J.W. van; Geelhoed, J.S.; Goorissen, H.P.; Meesters, K.P.M.; Stams, A.J.M.; Claassen, P.A.M.

    2009-01-01

    Non-axenic operation of a 400 L trickle bed reactor inoculated with the thermophile Caldicellulosiruptor saccharolyticus, yielded 2.8 molH 2mol hexose converted. The reactor was fed with a complex medium with sucrose as the main substrate, continuously flushed with nitrogen gas, and operated at

  5. Reactor design and operation strategies for a large-scale packed-bed CLC power plant with coal syngas

    NARCIS (Netherlands)

    Spallina, V.; Chiesa, P.; Martelli, E; Gallucci, F.; Romano, M.C.; Lozza, G.; Sint Annaland, van M.

    2015-01-01

    This paper deals with the design and operation strategies of dynamically operated packed-bed reactors (PBRs) of a chemical looping combustion (CLC) system included in an integrated gasification combined cycle (IGCC) for electric power generation with low CO2 emission from coal. The CLC reactors,

  6. Molecular analysis of the biomass of a fluidized bed reactor treating synthetic vinasse at anaerobic and micro-aerobic conditions.

    Science.gov (United States)

    Rodríguez, Elisa; Lopes, Alexandre; Fdz-Polanco, María; Stams, Alfons J M; García-Encina, Pedro A

    2012-03-01

    The microbial communities (Bacteria and Archaea) established in an anaerobic fluidized bed reactor used to treat synthetic vinasse (betaine, glucose, acetate, propionate, and butyrate) were characterized by denaturing gradient gel electrophoresis (DGGE) and phylogenetic analysis. This study was focused on the competitive and syntrophic interactions between the different microbial groups at varying influent substrate to sulfate ratios of 8, 4, and 2 and anaerobic or micro-aerobic conditions. Acetogens detected along the anaerobic phases at substrate to sulfate ratios of 8 and 4 seemed to be mainly involved in the fermentation of glucose and betaine, but they were substituted by other sugar or betaine degraders after oxygen application. Typical fatty acid degraders that grow in syntrophy with methanogens were not detected during the entire reactor run. Likely, sugar and betaine degraders outnumbered them in the DGGE analysis. The detected sulfate-reducing bacteria (SRB) belonged to the hydrogen-utilizing Desulfovibrio. The introduction of oxygen led to the formation of elemental sulfur (S(0)) and probably other sulfur compounds by sulfide-oxidizing bacteria (γ-Proteobacteria). It is likely that the sulfur intermediates produced from sulfide oxidation were used by SRB and other microorganisms as electron acceptors, as was supported by the detection of the sulfur respiring Wolinella succinogenes. Within the Archaea population, members of Methanomethylovorans and Methanosaeta were detected throughout the entire reactor operation. Hydrogenotrophic methanogens mainly belonging to the genus Methanobacterium were detected at the highest substrate to sulfate ratio but rapidly disappeared by increasing the sulfate concentration.

  7. Determination of the catalyst velocity profile along the riser of a fluidized bed reactor model by nuclear techniques

    International Nuclear Information System (INIS)

    Santos, V.A. dos; Dantas, C.C.

    1982-01-01

    A method adequated to industrial applications of flow measurements in fuidized bed reactor was developed. To measure the medium velocity of a catalyst, where the velocity is low, a radioactive tracer was used, 59 Fe and, to measure density by gamma attenuation, a standard source of 241 Am was used. The signals produced in NaI (Tl) scintilators detectors, were sent simultaneously to an electronic clock, to register the transit time, in the medium velocity measure of the catalyst whose reproductibility was 0.4%. The total estimated error for the method was a maximum of 4%. Important simplifications and pratical advantages are presented, if the method is compared to conventional measures with tracers. (E.G.) [pt

  8. Population dynamics of biofilm development during start-up of a butyrate-degrading fluidized-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Zellner, G.; Geveke, M.; Diekmann, H. (Hannover Univ. (Germany). Inst. fuer Mikrobiologie); Conway de Macario, E. (New York State Dept. of Health, Albany, NY (United States). Wadsworth Center for Laboratories and Research)

    1991-12-01

    Population dynamics during start-up of a fluidized-bed reactor with butyrate or butyrate plus acetate as sole substrates as well as biofilm development on the sand substratum were studied microbiologically, immunologically and by scanning electron microscopy. An adapted syntrophic consortium consisting of Syntrophospora sp., Methanothrix soehngenii, Methanosarcina mazei and Methanobrevibacter arboriphilus or Methanogenium sp. achieved high-rate butyrate degradation to methane and carbon dioxide. Desulfovibrio sp., Methanocorpusculum sp., and Methanobacterium sp. were also present in lower numbers. Immunological analysis demonstrated methanogens antigenically related to Methanobrevibacter ruminantium M1, Methanosarcina mazei S6, M. thermophila TM1, Methanobrevibacter arboriphilus AZ and Methanothrix soehngenii Opfikon in the biofilm. Immunological analysis also showed that the organisms isolated from the butyrate-degrading culture used as a source of inoculum were related to M. soehngenii Opfikon, Methanobacterium formicium MF and Methanospirillum hungatei JF1. (orig.).

  9. Method of neutronic calculations for a spherical cell equivalent to cylindrical one for using computer codes in light water reactors in the fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    Borges, V.; Sefidvash, F.; Rastogi, E.P.; Huria, H.C.; Krishnani, P.D.

    1989-01-01

    In order to use the existing light water reactor cell calculation codes for fluidized bed nuclear reactor having spherical fuel cells, an equivalence method has been developed. This method is shown to be adequate in calculation of the Dancoff factor. This method also was applicable in LEOPARD code and the results obtained in calculation of K ∞ was compared with the obtained using the DTF IV code, the results showed that the method is adequate for the calculations neutronics of the fluidized bed nuclear reactor. (author) [pt

  10. Remediation of trichloroethylene by bio-precipitated and encapsulated palladium nanoparticles in a fixed bed reactor.

    Science.gov (United States)

    Hennebel, Tom; Verhagen, Pieter; Simoen, Henri; De Gusseme, Bart; Vlaeminck, Siegfried E; Boon, Nico; Verstraete, Willy

    2009-08-01

    Trichloroethylene is a toxic and recalcitrant groundwater pollutant. Palladium nanoparticles bio-precipitated on Shewanella oneidensis were encapsulated in polyurethane, polyacrylamide, alginate, silica or coated on zeolites. The reactivity of these bio-Pd beads and zeolites was tested in batch experiments and trichloroethylene dechlorination followed first order reaction kinetics. The calculated k-values of the encapsulated catalysts were a factor of six lower compared to non-encapsulated bio-Pd. Bio-Pd, used as a catalyst, was able to dechlorinate 100 mgL(-1) trichloroethylene within a time period of 1h. The main reaction product was ethane; yet small levels of chlorinated intermediates were detected. Subsequently polyurethane cubes empowered with bio-Pd were implemented in a fixed bed reactor for the treatment of water containing trichloroethylene. The influent recycle configuration resulted in a cumulative removal of 98% after 22 h. The same reactor in a flow through configuration achieved removal rates up to 1059 mg trichloroethylene g Pd(-1)d(-1). This work showed that fixed bed reactors with bio-Pd polyurethane cubes can be instrumental for remediation of water contaminated with trichloroethylene.

  11. A Photocatalytic Active Adsorbent for Gas Cleaning in a Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Peter Pucher

    2008-01-01

    Full Text Available Efficient photocatalysis for gas cleaning purposes requires a large accessible, illuminated active surface in a simple and compact reactor. Conventional concepts use powdered catalysts, which are nontransparent. Hence a uniform distribution of light is difficult to be attained. Our approach is based on a coarse granular, UV-A light transparent, and highly porous adsorbent that can be used in a simple fixed bed reactor. A novel sol-gel process with rapid micro mixing is used to coat a porous silica substrate with TiO2-based nanoparticles. The resulting material posses a high adsorption capacity and a photocatalytic activity under UV-A illumination (PCAA = photocatalytic active adsorbent. Its photocatalytic performance was studied on the oxidation of trichloroethylene (TCE in a fixed bed reactor setup in continuous and discontinuous operation modes. Continuous operation resulted in a higher conversion rate due to less slip while discontinuous operation is superior for a total oxidation to CO2 due to a user-defined longer residence time.

  12. Engineering aspects of fluidized bed reactor operation applied to lactase treatment of whole whey

    Energy Technology Data Exchange (ETDEWEB)

    Metzdorf, C; Fauquex, P F; Flaschel, E; Renken, A

    1985-01-01

    An interesting possibility for the use of lactoserum in human nutrition is the hydrolysis of lactose to glucose and galactose, sugars which exhibit a better digestibility, a higher solubility, and which have a greater sweetening power than lactose. The hydrolysis is catalyzed by an enzyme, the ..beta..-galactosidase which, due to its high price, must be used continuously, preferentially in immobilized form. The enzyme used for these studies has been immobilized on silica gel precoated with chitosan. When whole whey or partially deproteinized whey is treated, a fluidized bed reactor seems to be the most appropriate to circumvent problems with protein adsorption and reactor plugging. However the fluidization of fine particles with a small density difference between the solid and the liquid may give rise to stability problems. In order to prevent unstable operation of the fluidized bed, the reactor has been equipped with special internals. They impose a radial distribution of the liquid and the solid phase and increase the linear velocity required to achieve a given expansion by a factor of five. Besides the resulting high solids content, the back-mixing of the liquid decreases significantly when static mixer-packings are used.

  13. Early stages in biofilm development in methanogenic fluidized-bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Lauwers, A.M.; Heinen, W.; Gorris, L.G.M.; Drift, C. van der (Katholieke Univ. Nijmegen (Netherlands). Dept. of Microbiology and Evolution Biology)

    1990-06-01

    Biofilm development in methanogenic fluidized-bed reactors with sand as the carrier was studied on a laboratory scale. The microorganisms present in consecutive layers of the biofilm of mature sludge granules were prelimilarily characterized on the basis of their morphology, element composition and adhesion capacity and were compared to bacteria which take part in the initial colonization of sand. The early phase of biofilm development was monitored with reactors receiving waste-waters containing different mixtures of volatile fatty acids and inoculated with fluidized-bed reactor effluent for different lengths of time. The results obtained indicate that facultative anaerobic bacteria abundantly present in the outermost biofilm layers of mature sludge granules are probably the main primary colonizers of the sand. Methanothrix spp. or other methanogens were rarely observed among the primary colonizers. The course of biofilm formation was comparable under the various start-up conditions employed including variations in waste-water composition, inoculation and anaerobicity. However, omission of waste-water and thus of substrate resulted in rapid wash-out of the attached biomass. (orig.).

  14. A CFD model for biomass fast pyrolysis in fluidized-bed reactors

    Science.gov (United States)

    Xue, Qingluan; Heindel, T. J.; Fox, R. O.

    2010-11-01

    A numerical study is conducted to evaluate the performance and optimal operating conditions of fluidized-bed reactors for fast pyrolysis of biomass to bio-oil. A comprehensive CFD model, coupling a pyrolysis kinetic model with a detailed hydrodynamics model, is developed. A lumped kinetic model is applied to describe the pyrolysis of biomass particles. Variable particle porosity is used to account for the evolution of particle physical properties. The kinetic scheme includes primary decomposition and secondary cracking of tar. Biomass is composed of reference components: cellulose, hemicellulose, and lignin. Products are categorized into groups: gaseous, tar vapor, and solid char. The particle kinetic processes and their interaction with the reactive gas phase are modeled with a multi-fluid model derived from the kinetic theory of granular flow. The gas, sand and biomass constitute three continuum phases coupled by the interphase source terms. The model is applied to investigate the effect of operating conditions on the tar yield in a fluidized-bed reactor. The influence of various parameters on tar yield, including operating temperature and others are investigated. Predicted optimal conditions for tar yield and scale-up of the reactor are discussed.

  15. Comparative evaluation of pebble-bed and prismatic fueled high-temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kasten, P.R.; Bartine, D.E.

    1981-01-01

    A comparative evaluation has been performed of the HTGR and the Federal Republic of Germany's Pebble Bed Reactor (PBR) for potential commercial applications in the US. The evaluation considered two reactor sizes (1000 and 3000 MW(t)) and three process applications (steam cycle, direct cycle, and process heat, with outlet coolant temperatures of 750, 850, and 950/sup 0/C, respectively). The primary criterion for the comparison was the levelized (15-year) cost of producing electricity or process heat. Emphasis was placed on the cost impact of differences between the prismatic-type HTGR core, which requires periodic refuelings during reactor shutdowns, and the pebble bed PBR core, which is refueled continuously during reactor operations. Detailed studies of key technical issues using reference HTGR and PBR designs revealed that two cost components contributing to the levelized power costs are higher for the PBR: capital costs and operation and maintenance costs. A third cost component, associated with nonavailability penalties, tended to be higher for the PBR except for the process heat application, for which there is a large uncertainty in the HTGR nonavailability penalty at the 950/sup 0/C outlet coolant temperature. A fourth cost component, fuel cycle costs, is lower for the PBR, but not sufficiently lower to offset the capital cost component. Thus the HTGR appears to be slightly superior to the PBR in economic performance. Because of the advanced development of the HTGR concept, large HTGRs could also be commercialized in the US with lower R and D costs and shorter lead times than could large PBRs. It is recommended that the US gas-cooled thermal reactor program continue giving primary support to the HTGR, while also maintaining its cooperative PBR program with FRG.

  16. Comparative evaluation of pebble-bed and prismatic fueled high-temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    Kasten, P.R.; Bartine, D.E.

    1981-01-01

    A comparative evaluation has been performed of the HTGR and the Federal Republic of Germany's Pebble Bed Reactor (PBR) for potential commercial applications in the US. The evaluation considered two reactor sizes [1000 and 3000 MW(t)] and three process applications (steam cycle, direct cycle, and process heat, with outlet coolant temperatures of 750, 850, and 950 0 C, respectively). The primary criterion for the comparison was the levelized (15-year) cost of producing electricity or process heat. Emphasis was placed on the cost impact of differences between the prismatic-type HTGR core, which requires periodic refuelings during reactor shutdowns, and the pebble bed PBR core, which is refueled continuously during reactor operations. Detailed studies of key technical issues using reference HTGR and PBR designs revealed that two cost components contributing to the levelized power costs are higher for the PBR: capital costs and operation and maintenance costs. A third cost component, associated with nonavailability penalties, tended to be higher for the PBR except for the process heat application, for which there is a large uncertainty in the HTGR nonavailability penalty at the 950 0 C outlet coolant temperature. A fourth cost component, fuel cycle costs, is lower for the PBR, but not sufficiently lower to offset the capital cost component. Thus the HTGR appears to be slightly superior to the PBR in economic performance. Because of the advanced development of the HTGR concept, large HTGRs could also be commercialized in the US with lower R and D costs and shorter lead times than could large PBRs. It is recommended that the US gas-cooled thermal reactor program continue giving primary support to the HTGR, while also maintaining its cooperative PBR program with FRG

  17. Butanol production by bioconversion of cheese whey in a continuous packed bed reactor.

    Science.gov (United States)

    Raganati, F; Olivieri, G; Procentese, A; Russo, M E; Salatino, P; Marzocchella, A

    2013-06-01

    Butanol production by Clostridium acetobutylicum DSM 792 fermentation was investigated. Unsupplemented cheese whey was adopted as renewable feedstock. The conversion was successfully carried out in a biofilm packed bed reactor (PBR) for more than 3 months. The PBR was a 4 cm ID, 16 cm high glass tube with a 8 cm bed of 3mm Tygon rings, as carriers. It was operated at the dilution rate between 0.4h(-1) and 0.94 h(-1). The cheese whey conversion process was characterized in terms of metabolites production (butanol included), lactose conversion and biofilm mass. Under optimized conditions, the performances were: butanol productivity 2.66 g/Lh, butanol concentration 4.93 g/L, butanol yield 0.26 g/g, butanol selectivity of the overall solvents production 82 wt%. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Pebble bed modular reactor safeguards: developing new approaches and implementing safeguards by design

    Energy Technology Data Exchange (ETDEWEB)

    Beyer, Brian David [Los Alamos National Laboratory; Beddingfield, David H [Los Alamos National Laboratory; Durst, Philip [INL; Bean, Robert [INL

    2010-01-01

    The design of the Pebble Bed Modular Reactor (PBMR) does not fit or seem appropriate to the IAEA safeguards approach under the categories of light water reactor (LWR), on-load refueled reactor (OLR, i.e. CANDU), or Other (prismatic HTGR) because the fuel is in a bulk form, rather than discrete items. Because the nuclear fuel is a collection of nuclear material inserted in tennis-ball sized spheres containing structural and moderating material and a PBMR core will contain a bulk load on the order of 500,000 spheres, it could be classified as a 'Bulk-Fuel Reactor.' Hence, the IAEA should develop unique safeguards criteria. In a multi-lab DOE study, it was found that an optimized blend of: (i) developing techniques to verify the plutonium content in spent fuel pebbles, (ii) improving burn-up computer codes for PBMR spent fuel to provide better understanding of the core and spent fuel makeup, and (iii) utilizing bulk verification techniques for PBMR spent fuel storage bins should be combined with the historic IAEA and South African approaches of containment and surveillance to verify and maintain continuity of knowledge of PBMR fuel. For all of these techniques to work the design of the reactor will need to accommodate safeguards and material accountancy measures to a far greater extent than has thus far been the case. The implementation of Safeguards-by-Design as the PBMR design progresses provides an approach to meets these safeguards and accountancy needs.

  19. COMPARISON OF UASB AND FLUIDIZED-BED REACTORS FOR SULFATE REDUCTION

    Directory of Open Access Journals (Sweden)

    S. M. Bertolino

    2015-03-01

    Full Text Available Abstract Reactor hydrodynamics is important for sulfidogenesis because sulfate reduction bacteria (SRB do not granulate easily. In this work, the sulfate reduction performance of two continuous anaerobic bioreactors was investigated: (i an upflow anaerobic sludge blanket (UASB reactor and (ii a fluidized bed reactor (FBR. Organic loading, sulfate reduction, and COD removal were the main parameters monitored during lactate and glycerol degradation. The UASB reactor with biomass recirculation showed a specific sulfate reduction rate of 0.089±0.014 g.gSSV-1.d-1 (89% reduction, whereas values twice as high were achieved in the FBR treating either lactate (0.200±0.017 g.gSSV-1.d-1 or glycerol (0.178±0.010 g.gSSV-1.d-1. Sulfate reduction with pure glycerol produced a smaller residual COD (1700 mg.L-1 than that produced with lactate (2500 mg.L-1 at the same COD.sulfate-1 mass ratio. It was estimated that 50% of glycerol degradation was due to sulfate reduction and 50% to fermentation, which was supported by the presence of butyrate in the FBR effluent. The UASB reactor was unable to produce effluents with sulfate concentrations below 250 mg.L-1 due to poor mixing conditions, whereas the FBR consistently ensured residual sulfate concentrations below such a value.

  20. Influence of the type of organisms on the biomass hold-up in a fluidized-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Timmermans, P.; Haute, A. van

    1984-01-01

    In the last few years, the use of fluidized-bed reactors for biological wastewater treatment has got increasing attention. In 1981, Shieh et al. proposed a model to predict the biomass concentration in a fluidized-bed reactor. From this model one can see that the biofilm density plays a very important role in determining the total biomass hold-up. In this article the influence of the type of carbon source on the biomass concentration, and as a consequence the type of organisms selected, is studied. The growth of a filamentous, budforming bacteria in a reactor treating nitrate rich surface water supplied with methanol as carbon source, results in a biomass concentration only half of the concentration which can normally be obtained in a fluidized-bed reactor treating synthetic wastewater; in this latter case rod-shaped bacteria are enriched which permit a dense packing.

  1. Fission Product Transport and Source Terms in HTRs: Experience from AVR Pebble Bed Reactor

    Directory of Open Access Journals (Sweden)

    Rainer Moormann

    2008-01-01

    Full Text Available Fission products deposited in the coolant circuit outside of the active core play a dominant role in source term estimations for advanced small pebble bed HTRs, particularly in design basis accidents (DBA. The deposited fission products may be released in depressurization accidents because present pebble bed HTR concepts abstain from a gas tight containment. Contamination of the circuit also hinders maintenance work. Experiments, performed from 1972 to 88 on the AVR, an experimental pebble bed HTR, allow for a deeper insight into fission product transport behavior. The activity deposition per coolant pass was lower than expected and was influenced by fission product chemistry and by presence of carbonaceous dust. The latter lead also to inconsistencies between Cs plate out experiments in laboratory and in AVR. The deposition behavior of Ag was in line with present models. Dust as activity carrier is of safety relevance because of its mobility and of its sorption capability for fission products. All metal surfaces in pebble bed reactors were covered by a carbonaceous dust layer. Dust in AVR was produced by abrasion in amounts of about 5 kg/y. Additional dust sources in AVR were ours oil ingress and peeling of fuel element surfaces due to an air ingress. Dust has a size of about 1  m, consists mainly of graphite, is partly remobilized by flow perturbations, and deposits with time constants of 1 to 2 hours. In future reactors, an efficient filtering via a gas tight containment is required because accidents with fast depressurizations induce dust mobilization. Enhanced core temperatures in normal operation as in AVR and broken fuel pebbles have to be considered, as inflammable dust concentrations in the gas phase.

  2. Electrical Capacitance Volume Tomography for the Packed Bed Reactor ISS Flight Experiment

    Science.gov (United States)

    Marashdeh, Qussai; Motil, Brian; Wang, Aining; Liang-Shih, Fan

    2013-01-01

    Fixed packed bed reactors are compact, require minimum power and maintenance to operate, and are highly reliable. These features make this technology a highly desirable unit operation for long duration life support systems in space. NASA is developing an ISS experiment to address this technology with particular focus on water reclamation and air revitalization. Earlier research and development efforts funded by NASA have resulted in two hydrodynamic models which require validation with appropriate instrumentation in an extended microgravity environment. To validate these models, the instantaneous distribution of the gas and liquid phases must be measured.Electrical Capacitance Volume Tomography (ECVT) is a non-invasive imaging technology recently developed for multi-phase flow applications. It is based on distributing flexible capacitance plates on the peripheral of a flow column and collecting real-time measurements of inter-electrode capacitances. Capacitance measurements here are directly related to dielectric constant distribution, a physical property that is also related to material distribution in the imaging domain. Reconstruction algorithms are employed to map volume images of dielectric distribution in the imaging domain, which is in turn related to phase distribution. ECVT is suitable for imaging interacting materials of different dielectric constants, typical in multi-phase flow systems. ECVT is being used extensively for measuring flow variables in various gas-liquid and gas-solid flow systems. Recent application of ECVT include flows in risers and exit regions of circulating fluidized beds, gas-liquid and gas-solid bubble columns, trickle beds, and slurry bubble columns. ECVT is also used to validate flow models and CFD simulations. The technology is uniquely qualified for imaging phase concentrations in packed bed reactors for the ISS flight experiments as it exhibits favorable features of compact size, low profile sensors, high imaging speed, and

  3. Studies on the inhomogeneous core density of a fluidized bed nuclear reactor

    Energy Technology Data Exchange (ETDEWEB)

    Van der Hagen, T.H.J.J.; Van Dam, H.; Hoogenboom, J.E.; Khotylev, V.A. [Delft Univ. of Technology (Netherlands). Interfaculty Reactor Inst.; Harteveld, W.; Mudde, R.F.

    1997-12-31

    Results are reported on the expected time dependent core density profile of a fluidized-bed nuclear fission reactor. Core densities have been measured in a test facility by the gamma-transmission technique. Bubble and particle-cluster sizes, positions, velocities and frequencies could be determined. Neutronic studies have been performed on the influence of core voids on reactivity using Monte-Carlo and neutron-transport codes. Fuel-particle importance has been determined. Point-kinetic parameters have been calculated for linking reactivity perturbations to power fluctuations. (author)

  4. Post-treatment of Fly Ash by Ozone in a Fixed Bed Reactor

    DEFF Research Database (Denmark)

    Pedersen, Kim Hougaard; Melia, M. C.; Jensen, Anker Degn

    2009-01-01

    to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O-3/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data....... prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found...

  5. Renewable side reflector structure for a pebble bed high temperature reactor

    International Nuclear Information System (INIS)

    Martin, Roger.

    1977-01-01

    The description is given of a renewable side reflector structure for a pebble bed high temperature reactor of the kind comprising a cylindrical graphite vessel constituting the neutron reflector, this vessel being filled with graphite pebbles containing the nuclear fuel and enclosed in a concrete protective containment. The internal peripheral area of the vessel is constituted by a line of adjacent graphite rods mounted so that they can rotate about their longitudinal axis and manoeuvrable from outside the concrete containment by means of a shaft passing into it [fr

  6. The fluidized bed reactor in the anaerobic treatment of wine wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Converti, A; Zilli, M; Del Borghi, M; Ferraiolo, G [Genoa Univ. (Italy). Inst. of Chemical Engineering Science and Technology

    1990-02-13

    The aim of the present work is the performance evaluation of a fluidized bed reactor in the anaerobic treatment of a wastewater deriving from the washing operations of the wine industry. The results are in agreement with the ones obtained using a mixture of municipal and food processing waste waters containing high organic contents. A comparison with other liquid wastes shows that no subtrate inhibition phenomenon occurs with the above substrates. A saturation kinetic model is also presented for describing the dependence of the COD removal rate on the organic loading rate. (orig.).

  7. Modeling and Experimental Studies of Mercury Oxidation and Adsorption in a Fixed-Bed Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Buitrago, Paula A.; Morrill, Mike; Lighty, JoAnn S.; Silcox, Geoffrey D.

    2009-06-15

    This report presents experimental and modeling mercury oxidation and adsorption data. Fixed-bed and single-particle models of mercury adsorption were developed. The experimental data were obtained with two reactors: a 300-W, methane-fired, tubular, quartz-lined reactor for studying homogeneous oxidation reactions and a fixed-bed reactor, also of quartz, for studying heterogeneous reactions. The latter was attached to the exit of the former to provide realistic combustion gases. The fixed-bed reactor contained one gram of coconut-shell carbon and remained at a temperature of 150°C. All methane, air, SO2, and halogen species were introduced through the burner to produce a radical pool representative of real combustion systems. A Tekran 2537A Analyzer coupled with a wet conditioning system provided speciated mercury concentrations. At 150°C and in the absence of HCl or HBr, the mercury uptake was about 20%. The addition of 50 ppm HCl caused complete capture of all elemental and oxidized mercury species. In the absence of halogens, SO2 increased the mercury adsorption efficiency to up to 30 percent. The extent of adsorption decreased with increasing SO2 concentration when halogens were present. Increasing the HCl concentration to 100 ppm lessened the effect of SO2. The fixed-bed model incorporates Langmuir adsorption kinetics and was developed to predict adsorption of elemental mercury and the effect of multiple flue gas components. This model neglects intraparticle diffusional resistances and is only applicable to pulverized carbon sorbents. It roughly describes experimental data from the literature. The current version includes the ability to account for competitive adsorption between mercury, SO2, and NO2. The single particle model simulates in-flight sorbent capture of elemental mercury. This model was developed to include Langmuir and Freundlich isotherms, rate equations, sorbent feed rate, and

  8. The Behavior of Pilot Trickle-Bed Reactor under Periodic Operation

    Czech Academy of Sciences Publication Activity Database

    Tukač, V.; Šimíčková, M.; Chyba, V.; Lederer, J.; Kolena, J.; Hanika, Jiří; Jiřičný, Vladimír; Staněk, Vladimír; Stavárek, Petr

    2007-01-01

    Roč. 62, 18-20 (2007), s. 4891-4895 ISSN 0009-2509. [International Symposium on Chemical Reaction Engineering - From Science to Innovative Engineering /19./. Potsdam/Berlin, 03.09.2006-06.09.2006] R&D Projects: GA MPO(CZ) FT-TA/039 Grant - others:CYCLOP(XE) G1RD/CT2000/00225 Institutional research plan: CEZ:AV0Z40720504 Source of funding: R - rámcový projekt EK Keywords : olefine hydrogenation * pilot-scale * trickle-bed reactor Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.775, year: 2007

  9. Anaerobic up flow fluidized bed reactor performance as a primary treatment unit in domestic wastewater treatment

    Directory of Open Access Journals (Sweden)

    M.A. Moharram

    2016-04-01

    The efficiencies of Total nitrogen removal ranged between 2.23 and 10.83% with an apparent decrease during the low temperature high rate stages. Nitrite removal was in the range of (23.08–77% with up to the 2 mg/L in the effluent water when obtaining high organic loading and warm temperature. These results demonstrated that the domestic wastewater could be anaerobically treated in a fluidized bed UASB reactor with very low HRT reaching 2.5 h.

  10. Packed bed reactor for degradation of simulated cyanide-containing wastewater

    OpenAIRE

    Kumar, Virender; Kumar, Vijay; Bhalla, Tek Chand

    2014-01-01

    The discharge of cyanide-containing effluents into the environment contaminates water bodies and soil. Effective methods of treatment which can detoxify cyanide are the need of the hour. The aim of the present study is to develop a bioreactor for complete degradation of cyanide using immobilized cells of Serratia marcescens RL2b. Alginate-entrapped cells of S. marcescens RL2b were used for complete degradation of cyanide in a packed bed reactor (PBR). Cells grown in minimal salt medium (pH 6....

  11. Nuclear propulsion systems for orbit transfer based on the particle bed reactor

    International Nuclear Information System (INIS)

    Powell, J.R.; Ludewig, H.; Horn, F.L.

    1987-01-01

    The technology of nuclear direct propulsion orbit transfer systems based on the Particle Bed Reactor (PBR) is described. A 200 megawatt illustrative design is presented for LEO to GEO and other high ΔV missions. The PBR-NOTV can be used in a one-way mode with the shuttle or an expendable launch vehicle, e.g., the Titan 34D7, or as a two-way reusable space tug. In the one-way mode, payload capacity is almost three times greater than that of chemical OTV's. PBR technology status is described and development needs outlined

  12. Reactor oscillator - I - III, Part III - Electronic device

    International Nuclear Information System (INIS)

    Lolic, B.; Jovanovic, S.

    1961-12-01

    This report describes functioning of the reactor oscillator electronic system. Two methods of oscillator operation were discussed. The first method is so called method of amplitude modulation of the reactor power, and the second newer method is phase method. Both methods are planned for the present reactor oscillator

  13. Multi-sphere unit cell model to calculate the effective thermal conductivity in pebble bed reactors

    International Nuclear Information System (INIS)

    Van Antwerpen, W.; Rousseau, P.G.; Du Toit, C.G.

    2010-01-01

    A proper understanding of the mechanisms of heat transfer, fluid flow and pressure drop through a packed bed of spheres is of utmost importance in the design of a high temperature Pebble Bed Reactor (PBR). While the gas flows predominantly in the axial direction through the bed, the total effective thermal conductivity is a lumped parameter that characterises the total heat transfer in the radial direction through the packed bed. The study of the effective thermal conductivity is important because it forms an intricate part of the self-acting decay heat removal chain, which is directly related to the PBR safety case. The effective thermal conductivity is the summation of various heat transport phenomena. These are the enhanced thermal conductivity due to turbulent mixing as the fluid passes through the voids between pebbles, heat transfer due to the movement of the solid spheres and thermal conduction and thermal radiation between the spheres in a stagnant fluid environment. In this study, the conduction and radiation between the spheres are investigated. Firstly, existing correlations for the effective thermal conductivity are investigated, with particular attention given to its applicability in the near-wall region. Several phenomena in particular are examined namely: conduction through the spheres, conduction through the contact area between the spheres, conduction through the gas phase and radiation between solid surfaces. A new approach to simulate the effective thermal conductivity for randomly packed beds is then presented, namely the so-called Multi-sphere Unit Cell Model. The model is validated by comparing the results with that obtained in experiments. (authors)

  14. Particle bed reactor propulsion vehicle performance and characteristics as an orbital transfer rocket

    International Nuclear Information System (INIS)

    Horn, F.L.; Powell, J.R.; Lazareth, O.W.

    1986-01-01

    The particle bed reactor designed for 100 to 300 MW power output using hydrogen as a coolant is capable of specific impulses up to 1000 seconds as a nuclear rocket. A single space shuttle compatible vehicle can perform extensive missions from LEO to 3 times GEO and return with multi-ton payloads. The use of hydrogen to directly cool particulate reactor fuel results in a compact, lightweight rocket vehicle, whose duration of usefulness is dependent only upon hydrogen resupply availability. The LEO to GEO mission had a payload capability of 15.4 metric tons with 3.4 meters of shuttle bay. To increase the volume limitation of the shuttle bay, the use of ammonia in the initial boost phase from LEO is used to give greater payload volume with a small decrease in payload mass, 8.7 meters and 12.7 m-tons. 5 refs., 15 figs

  15. Inhibition and recovery of nitrification in treating real coal gasification wastewater with moving bed biofilm reactor

    Institute of Scientific and Technical Information of China (English)

    Huiqiang Li; Hongjun Han; Maoan Du; Wei Wang

    2011-01-01

    Moving bed biofilm reactor (MBBR) was used to treat real coal gasification wastewater.Nitrification of the MBBR was inhibited almost completely during start-up period.Sudden increase of influent total NH3 concentration was the main factor inducing nitrification inhibition.Increasing DO concentration in the bulk liquid (from 2 to 3 mg/L) had little effect on nitrification recovery.Nitrification of the MBBR recovered partially by the addition of nitrifying sludge into the reactor and almost ceased within 5 days.Nitrification ratio of the MBBR achieved 65% within 12 days by increasing dilute ratio of the influent wastewater with tap water.The ratio of nitrification decreased to 25% when infiuent COD concentration increased from 650 to 1000 mg/L after nitrification recovery and recovered 70%for another 4 days.

  16. [Kinetics of catalytic wet air oxidation of phenol in trickle bed reactor].

    Science.gov (United States)

    Li, Guang-ming; Zhao, Jian-fu; Wang, Hua; Zhao, Xiu-hua; Zhou, Yang-yuan

    2004-05-01

    By using a trickle bed reactor which was designed by the authors, the catalytic wet air oxidation reaction of phenol on CuO/gamma-Al2O3 catalyst was studied. The results showed that in mild operation conditions (at temperature of 180 degrees C, pressure of 3 MPa, liquid feed rate of 1.668 L x h(-1) and oxygen feed rate of 160 L x h(-1)), the removal of phenol can be over 90%. The curve of phenol conversion is similar to "S" like autocatalytic reaction, and is accordance with chain reaction of free radical. The kinetic model of pseudo homogenous reactor fits the catalytic wet air oxidation reaction of phenol. The effects of initial concentration of phenol, liquid feed rate and temperature for reaction also were investigated.

  17. CFD Modeling of Flow and Ion Exchange Kinetics in a Rotating Bed Reactor System

    DEFF Research Database (Denmark)

    Larsson, Hilde Kristina; Schjøtt Andersen, Patrick Alexander; Byström, Emil

    2017-01-01

    A rotating bed reactor (RBR) has been modeled using computational fluid dynamics (CFD). The flow pattern in the RBR was investigated and the flow through the porous material in it was quantified. A simplified geometry representing the more complex RBR geometry was introduced and the simplified...... model was able to reproduce the main characteristics of the flow. Alternating reactor shapes were investigated, and it was concluded that the use of baffles has a very large impact on the flows through the porous material. The simulations suggested, therefore, that even faster reaction rates could...... be achieved by making the baffles deeper. Two-phase simulations were performed, which managed to reproduce the deflection of the gas–liquid interface in an unbaffled system. A chemical reaction was implemented in the model, describing the ion-exchange phenomena in the porous material using four different...

  18. Anaerobic biodegradation of diesel fuel-contaminated wastewater in a fluidized bed reactor.

    Science.gov (United States)

    Cuenca, M Alvarez; Vezuli, J; Lohi, A; Upreti, S R

    2006-06-01

    Diesel fuel spills have a major impact on the quality of groundwater. In this work, the performance of an Anaerobic Fluidized Bed Reactor (AFBR) treating synthetic wastewater is experimentally evaluated. The wastewater comprises tap water containing 100, 200 and 300 mg/L of diesel fuel and nutrients. Granular, inert, activated carbon particles are employed to provide support for biomass inside the reactor where diesel fuel is the sole source of carbon for anaerobic microorganisms. For different rates of organic loading, the AFBR performance is evaluated in terms of the removal of diesel fuel as well as chemical oxygen demand (COD) from wastewater. For the aforementioned diesel fuel concentrations and a wastewater flow rate of 1,200 L/day, the COD removal ranges between 61.9 and 84.1%. The concentration of diesel fuel in the effluent is less than 50 mg/L, and meets the Level II groundwater standards of the MUST guidelines of Alberta.

  19. Investigations on accidents with massive water ingress exemplified by the pebble bed reactor PNP-500

    International Nuclear Information System (INIS)

    Moormann, R.

    1986-01-01

    A computer code is used for analyses of massive water ingress accidents in the High-Temperature Gas Cooled Reactor concept PNP-500 with pebble bed core. The analyses are mainly focussed on graphite corrosion processes. For the investigated accidents a correct reactor shut down in assumed. The mass of water ingressing into the primary circuit is varied between 1000 and 7500 kg (i.e., up to hypothetical values). The dependence of accident consequences on parameters such as intensity and starting time of the afterheat removal system or kinetic values of the chemical processes is examined. The results show that even under pessimistic assumptions the extent of the graphite corrosion is relatively low; significant damaging of fuel elements or graphite components does not occur. A primary circuit depressurization, combined with local burning of water gas, would probably not affect the fission product retention potential of the (gastight) containment. Summing up, the risk caused by these accidents remains small. (orig.) [de

  20. Measurement of flow field in the pebble bed type high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Lee, Sa Ya; Lee, Jae Young

    2008-01-01

    In this study, flow field measurement of the Pebble Bed Reactor(PBR) for the High Temperature Gascooled Reactor(HTGR) was performed. Large number of pebbles in the core of PBR provides complicated flow channel. Due to the complicated geometries, numerical analysis has been intensively made rather than experimental observation. However, the justification of computational simulation by the experimental study is crucial to develop solid analysis of design method. In the present study, a wind tunnel installed with pebbles stacked was constructed and equipped with the Particle Image Velocimetry(PIV). We designed the system scaled up to realize the room temperature condition according to the similarity. The PIV observation gave us stagnation points, low speed region so that the suspected high temperature region can be identified. With the further supplementary experimental works, the present system may produce valuable data to justify the Computational Fluid Dynamics(CFD) simulation method

  1. Optimal conditions in direct dimethyl ether synthesis from syngas utilizing a dual-type fluidized bed reactor

    International Nuclear Information System (INIS)

    Yousefi, Ahmad; Eslamloueyan, Reza; Kazerooni, Nooshin Moradi

    2017-01-01

    Concerns over environmental pollution and ever-increasing energy demand have urged the global community to tap clean-burning fuels among which dimethyl ether is a promising candidate for contribution in the transportation sector. Direct dimethyl ether synthesis from syngas, in which methanol production and dehydration take place simultaneously, is arguably the preferred route for large scale production. In this study, direct dimethyl ether synthesis is proposed in an industrial dual-type fluidized bed reactor. This configuration involves two fluidized bed reactors operating in different conditions. In the first catalytic reactor (water-cooled reactor), the synthesis gas is partly converted to methanol after being preheated by the reaction heat in the second reactor (gas-cooled reactor). A two-phase generalized comprehensive reactor model, comprised of the flow in three different regimes is applied and a smooth transition between flow regimes is provided based on the probabilistic averaging approach. The optimal operating conditions are sought by employing differential evolution algorithm as a robust optimization strategy. The dimethyl ether mole fraction is considered as the objective function during the optimization. The results show considerable dimethyl ether enhancement by 16% and 14% compared to the conventional direct dimethyl ether synthesis reactor and dual-type fixed bed dimethyl ether reactor arrangements, respectively. - Highlights: • Dual-type catalytic fluidized bed reactors for dimethyl ether synthesis is studied. • A two-phase comprehensive model comprised of flow in three regimes is used. • Probabilistic averaging approach is applied for smooth transitions between regimes. • Differential evolution method is employed to determine optimal operating conditions. • Production capacity is remarkably enhanced compared to conventional reactor.

  2. Development of an enzyme fluidized bed reactor equipped with static mixers: application to lactose hydrolysis in whey

    Energy Technology Data Exchange (ETDEWEB)

    Fauquex, P F; Flaschel, E; Renken, A

    1984-01-01

    Reactor operation with immobilized enzymes in fixed bed arrangement is often impaired due to the presence of finely divided solid matter, adsorbing substances or gas. The fluidized bed reactor would be applied in such cases owing to a limited pressure drop, a controlled voidage, and the avoidance of perforated plates for catalyst retention. Since enzymic reactions are often slow processes, catalysts of high external surface area should be provided together with sufficient time. However, classical fluidized beds suffer from hydrodynamic instability under these conditions. Therefore, a new reactor design was developed which used motionless mixers as internals. Fluidized bed reactors equipped with internals exhibit an outstanding hydrodynamic stability accompanied by an increase of the operating range in terms of flow rate by a factor of 4 compared to the classical fluidized bed. Results are presented, with emphasis on the backmixing and expansion characteristics. Various motionless mixers were investigated in columns of 39 and 150 mm in diameter. The fluidized bed equipped with internals was used for lactose hydrolysis in partially deproteinized whey. The lactase from Aspergillus niger immobilized on silica gel particles of 125-160 molm had a half-life of approximately 1 mo.

  3. Plutonium burning in a pebble-bed type high temperature nuclear reactor

    Energy Technology Data Exchange (ETDEWEB)

    Bende, E.E

    2000-01-24

    This thesis deals with the pebble-bed High Temperature Reactor that is fuelled with pure reactor-grade plutonium. It is stressed that neither burnable poisons nor fertile materials like 238U and 212Th are present in the calculational models throughout this thesis. Chapter 2 discusses the general properties of the pebble-bed HTR: the passive safety features of this reactor; different fuel scenarios according to which the pebble-bed HTR can be operated; properties of the pebbles and the coated particles (CPs), including a concise overview of the mechanisms that can lead to coated particle failure. Special attention is paid to the effect of Pu as fuel inside these CPs thereby aiming to indicate which mechanisms are of concern when such CPs are considered as fuel in future reactors. In the last part of this chapter constraints are listed that were imposed to the models considered in the framework of this thesis. Chapter 3 presents the results of unit-cell calculations performed with three code systems. The main objective of this chapter is to compare the calculational results of one particular code system, which is a candidate for the generation of cross sections for a full-core calculation, to those of the other two code systems. Also some reactor physics interpretations of the calculational results are presented. The unit-cell calculations embrace the computation of a number of reactor physics parameters for pebbles with a varying plutonium mass per pebble and with different types of coated particles. For one pebble configuration, these parameters have been calculated for various fuel temperatures and over-all (uniform) temperatures. For that particular pebble configuration, also the results of a two burnup calculations were compared. Chapter 4 reports the results of a parameter study in which the number of coated particles per pebble as well as the type and size of the CPs have been varied. The effect of different pebble configurations on several reactor physics

  4. Gas Reactor International Cooperative program. Pebble bed reactor plant: screening evaluation. Volume 3. Appendix A. Equipment list

    International Nuclear Information System (INIS)

    1979-11-01

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW(t) Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. Volume 1 reports the overall plant and reactor system and was prepared by the General Electric Company. Core scoping studies were performed which evaluated the effects of annular and cylindrical core configurations, radial blanket zones, burnup, and ball heavy metal loadings. The reactor system, including the PCRV, was investigated for both the annular and cylindrical core configurations. Volume 3 is an Appendix containing the equipment list for the plant and was also prepared by United Engineers and Constructors, Inc. It tabulates the major components of the plant and describes each in terms of quantity, type, orientation, etc., to provide a basis for cost estimation

  5. Acetone-butanol-ethanol (ABE) fermentation in an immobilized cell trickle bed reactor.

    Science.gov (United States)

    Park, C H; Okos, M R; Wankat, P C

    1989-06-05

    Acetone-butanol-ethanol (ABE) fermentation was successfully carried out in an immobilized cell trickle bed reactor. The reactor was composed of two serial columns packed with Clostridium acetobutylicum ATCC 824 entrapped on the surface of natural sponge segments at a cell loading in the range of 2.03-5.56 g dry cells/g sponge. The average cell loading was 3.58 g dry cells/g sponge. Batch experiments indicated that a critical pH above 4.2 is necessary for the initiation of cell growth. One of the media used during continuous experiments consisted of a salt mixture alone and the other a nutrient medium containing a salt mixture with yeast extract and peptone. Effluent pH was controlled by supplying various fractions of the two different types of media. A nutrient medium fraction above 0.6 was crucial for successful fermentation in a trickle bed reactor. The nutrient medium fraction is the ratio of the volume of the nutrient medium to the total volume of nutrient plus salt medium. Supplying nutrient medium to both columns continuously was an effective way to meet both pH and nutrient requirement. A 257-mL reactor could ferment 45 g/L glucose from an initial concentration of 60 g/L glucose at a rate of 70 mL/h. Butanol, acetone, and ethanol concentrations were 8.82, 5.22, and 1.45 g/L, respectively, with a butanol and total solvent yield of 19.4 and 34.1 wt %. Solvent productivity in an immobilized cell trickle bed reactor was 4.2 g/L h, which was 10 times higher than that obtained in a batch fermentation using free cells and 2.76 times higher than that of an immobilized CSTR. If the nutrient medium fraction was below 0.6 and the pH was below 4.2, the system degenerated. Oxygen also contributed to the system degeneration. Upon degeneration, glucose consumption and solvent yield decreased to 30.9 g/L and 23.0 wt %, respectively. The yield of total liquid product (40.0 wt %) and butanol selectivity (60.0 wt %) remained almost constant. Once the cells were degenerated

  6. Preliminary neutronic design of high burnup OTTO cycle pebble bed reactor

    International Nuclear Information System (INIS)

    Setiadipura, T.; Zuhair; Irwanto, D.

    2015-01-01

    The pebble bed type High Temperature Gas-cooled Reactor (HTGR) is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR) which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO) cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor design in general, is improving the nuclear fuel utilization which is shown by attaining a higher burnup value. This study performed a preliminary neutronic design study of a 200 MWt OTTO cycle PBR with high burnup while fulfilling the safety criteria of the PBR design.The safety criteria of the design was represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. The maximum burnup value was also limited by the tested maximum burnup value which maintained the integrity of the pebble fuel. Parametric surveys were performed to obtain the optimized parameters used in this study, which are the fuel enrichment, per-pebble heavy metal (HM) loading, and the average axial speed of the fuel. An optimum design with burnup value of 131.1 MWd/Kg-HM was achieved in this study which is much higher compare to the burnup of the reference design HTR-MODUL and a previously proposed OTTO-cycle PBR design. This optimum design uses 17% U-235 enrichment with 4 g HM-loading per fuel pebble. (author)

  7. Preliminary Neutronic Design of High Burnup OTTO Cycle Pebble Bed Reactor

    Directory of Open Access Journals (Sweden)

    T. Setiadipura

    2015-04-01

    Full Text Available The pebble bed type High Temperature Gas-cooled Reactor (HTGR is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor design in general, is improving the nuclear fuel utilization which is shown by attaining a higher burnup value. This study performed a preliminary neutronic design study of a 200 MWt OTTO cycle PBR with high burnup while fulfilling the safety criteria of the PBR design.The safety criteria of the design was represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. The maximum burnup value was also limited by the tested maximum burnup value which maintained the integrity of the pebble fuel. Parametric surveys were performed to obtain the optimized parameters used in this study, which are the fuel enrichment, per-pebble heavy metal (HM loading, and the average axial speed of the fuel. An optimum design with burnup value of 131.1 MWd/Kg-HM was achieved in this study which is much higher compare to the burnup of the reference design HTR-MODUL and a previously proposed OTTO-cycle PBR design. This optimum design uses 17% U-235 enrichment with 4 g HM-loading per fuel pebble

  8. Characterization, morphology and composition of biofilm and precipitates from a sulphate-reducing fixed-bed reactor

    International Nuclear Information System (INIS)

    Remoundaki, Emmanouela; Kousi, Pavlina; Joulian, Catherine; Battaglia-Brunet, Fabienne; Hatzikioseyian, Artin; Tsezos, Marios

    2008-01-01

    The characteristics of the biofilm and the solids formed during the operation of a sulphate-reducing fixed-bed reactor, fed with a moderately acidic synthetic effluent containing zinc and iron, are presented. A diverse population of δ-Proteobacteria SRB, affiliated to four distinct genera, colonized the system. The morphology, mineralogy and surface chemistry of the precipitates were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The XRD patterns observed are characteristic of amorphous solid phases. Peaks corresponding to crystalline iron sulphide, marcasite, sphalerite and wurtzite were also identified. SEM-EDX results confirm the predominance of amorphous phases appearing as a cloudy haze. EDX spectra of spots on the surface of these amorphous phases reveal the predominance of iron, zinc and sulphur indicating the formation of iron and zinc sulphides. The predominance of these amorphous phases and the formation of very fine particles, during the operation of the SRB column, are in agreement and can be explained by the formation pathways of metal sulphides at ambient temperature, alkaline pH and reducing conditions. Solids are precipitated either as (i) amorphous phases deposited on the bed material, as well as on surface of crystals, e.g. Mg 3 (PO 4 ) 2 and (ii) as rod-shaped solids characterized by a rough hazy surface, indicating the encapsulation of bacterial cells by amorphous metal sulphides

  9. Degradation of TCE using sequential anaerobic biofilm and aerobic immobilized bed reactor

    Science.gov (United States)

    Chapatwala, Kirit D.; Babu, G. R. V.; Baresi, Larry; Trunzo, Richard M.

    1995-01-01

    Bacteria capable of degrading trichloroethylene (TCE) were isolated from contaminated wastewaters and soil sites. The aerobic cultures were identified as Pseudomonas aeruginosa (four species) and Pseudomonas fluorescens. The optimal conditions for the growth of aerobic cultures were determined. The minimal inhibitory concentration values of TCE for Pseudomonas sps. were also determined. The aerobic cells were immobilized in calcium alginate in the form of beads. Degradation of TCE by the anaerobic and dichloroethylene (DCE) by aerobic cultures was studied using dual reactors - anaerobic biofilm and aerobic immobilized bed reactor. The minimal mineral salt (MMS) medium saturated with TCE was pumped at the rate of 1 ml per hour into the anaerobic reactor. The MMS medium saturated with DCE and supplemented with xylenes and toluene (3 ppm each) was pumped at the rate of 1 ml per hour into the fluidized air-uplift-type reactor containing the immobilized aerobic cells. The concentrations of TCE and DCE and the metabolites formed during their degradation by the anaerobic and aerobic cultures were monitored by GC. The preliminary study suggests that the anaerobic and aerobic cultures of our isolates can degrade TCE and DCE.

  10. Ethanol production by immobilized yeast and its CO2 gas effects on a packed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Cho, G M; Choi, C Y; Choi, Y D; Han, M H

    1982-10-01

    Immobilised yeast trapped in an alginate matrix demonstrated maximum activity at 30 degrees C and showed no pH effect between 3 and 7. Substrate inhibition was observed at glucose concentrations above 8% but the immobilised cells retained 70% of their maximum activity at 20% glucose concentration. The operation stability of immobilised cells was lower in simple glucose solution than in the activation medium in which only 20% of the activity was lost after 10 days operation. Inactivated immobilised yeast beads were reactivated by incubation in activation medium without a significant increase in cell numbers in a bead. During the operation of the immobilised yeast in a packed bed reactor, CO/sub 2/ gas accumulation adversely affected the reactor performance. An ideal plus flow reactor, not taking into account the formation of CO/sub 2/ gas bubbles and the presence of mass trasnfer resistance, was simulated using a kinetic model for the production of ethanol and the simulation results were compared with the actual reactor performance to determine the CO/sub 2/ gas effect, quantitatively. Up to 45% of the substrate conversion was lost due to the accumulation of CO/sub 2/ gas bubbles in all cases. (Refs. 21).

  11. Effect of Different Operating Temperatures on the Biological Hydrogen Methanation in Trickle Bed Reactors

    Directory of Open Access Journals (Sweden)

    Andreas Lemmer

    2018-05-01

    Full Text Available To improve the reactor efficiency, this study investigated the influence of temperature on the biological hydrogen methanation (BHM in trickle-bed reactors (TBR. Rising temperatures increase the metabolic activity of methanogenic microorganisms, thus leading to higher reactor specific methane formation rates (MFR. In order to quantify the potential for improved performance, experiments with four different operating temperatures ranging from 40 to 55 °C were carried out. Methane content increased from 88.29 ± 2.12 vol % at 40 °C to 94.99 ± 0.81 vol % at 55 °C with a stable biological process. Furthermore, a reactor specific methane formation rate (MFR of up to 8.85 ± 0.45 m3 m−3 d−1 was achieved. It could be shown that the microorganisms were able to adapt to higher temperatures within hours. The tests showed that TBR performance with regard to BHM can be significantly increased by increasing the operating temperature.

  12. Phenolic Wastewater Treatment using Activated Carbon in a Three Phase Fluidized-Bed Reactor

    Directory of Open Access Journals (Sweden)

    Pornsiri Tongprem

    2009-11-01

    Full Text Available Phenolic wastewater treatment was investigated using activated carbon in a lab scale three phase fluidized-bed reactor. The reactor with effective volume of 272 ml, 300 mm in height and 40 mm in diameter was made from transparent acrylic that allowed to observe the phenomena occurring inside. Phenol 10 mg/l and air were used as representative agents that were continuously fed to the reactor at a constant flow rate of 1 and 2 l/min with co-current and up-flow, respectively. Comparison of the phenolic adsorption under five different conditions: (a fresh Acs, (b 1st reused Acs, (c fresh Fe/Acs, (d 1st reused Fe/Acs, and (e 2nd reused Fe/Acs, have been carried out. The phenolic wastewater was re-circulated through the reactor and its concentration was measured with respect to time. The experimental adsorption results revealed that both fresh Acs and Fe/Acs gave the better results than reused Acs and reused Fe/Acs, respectively. The adsorption in all cases of Acs and Fe/Acs would follow Pseudo-second order kinetic.

  13. Modeling and simulation of a packed bed reactor for hydrogen by methanol steam reforming

    International Nuclear Information System (INIS)

    Aboudheir, A.; Idem, R.

    2004-01-01

    'Full text:' The performance of a catalytic packed bed tubular reactor for hydrogen production depends on mass transport characteristics and temperature distribution in the reactor. To accurately predict this performance, a rigorous numerical model has been developed based on coupled mass, energy, and momentum balance equations in cylindrical coordinates. This comprehensive model takes into account the variations of the concentration and temperature in both the axial and radial directions as well as the pressure drop along the packed reactor. Also, experimental measurements for hydrogen production were collected using a manganese-promoted co-precipitated Cu-Al catalyst for methanol-steam reforming in a micro-reactor having 10 mm i.d. and 460 mm overall length. The operating temperature ranged from 443 to 523 K and the space-time ranged from 0.1 to 2.5 kg cat h/kmol CH3OH. The simulation results were found to be in close agreement with the experimental data over the various operating conditions. This confirms the validity of both the numerical model of this work and our previous published kinetics models for this reaction system. In addition, the model formulation is applicable to handle reactions, not only for the microreactor presented in this work, but also, for other laboratory size and industrial scale processes for hydrogen production by hydrocarbon reformation. (author)

  14. Mathematical Modeling and Simulation of the Dehydrogenation of Ethyl Benzene to Form Styrene Using Steady-State Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Zaidon M. Shakoor

    2013-05-01

    Full Text Available In this research, two models are developed to simulate the steady state fixed bed reactor used for styrene production by ethylbenzene dehydrogenation. The first is one-dimensional model, considered axial gradient only while the second is two-dimensional model considered axial and radial gradients for same variables.The developed mathematical models consisted of nonlinear simultaneous equations in multiple dependent variables. A complete description of the reactor bed involves partial, ordinary differential and algebraic equations (PDEs, ODEs and AEs describing the temperatures, concentrations and pressure drop across the reactor was given. The model equations are solved by finite differences method. The reactor models were coded with Mat lab 6.5 program and various numerical techniques were used to obtain the desired solution.The simulation data for both models were validated with industrial reactor results with a very good concordance.

  15. Treatment of chemical-pharmaceutical wastewater in packed bed anaerobic reactors

    Energy Technology Data Exchange (ETDEWEB)

    Nacheva, P.M.; Pena-Loera, B.; Moralez-Guzman, F. [Mexican Institute for Water Technology, Jiutepec (Mexico)

    2006-07-01

    Biological degradation in packed bed anaerobic mesophilic reactors with five different support materials was studied for the treatment of chemical-pharmaceutical wastewater with high COD (23-31 g/L), which contains toxic organic compounds. Experimental up-flow bio-filters were operated at different organic loads for a two-year period. Removals of 80-98% were obtained in the reactors with sand, anthracite and black tezontle, but at relatively low organic loads, less than 3.6 kg m{sup -3} d{sup -1}. The reactor with granular activated carbon (GAC) had a better performance; efficiencies higher than 95% were obtained at loads up to 17kg m{sup -3} d{sup -1} and higher than 80% with loads up to 26 kg m{sup -3} d{sup -1}. Second in performance was the reactor with red tezontle which allows COD removals higher than 80% with loads up to 6 kg m{sup -3} d{sup -1}. The use of GAC as support material allows greater biodegradation rates than the rest of the materials and it makes the process more resistant to organic load increases, inhibition effects and toxicity. Methanogenic activity was inhibited at loads higher than 21.9 kg m{sup -3} d{sup -1} in the GAC-reactor and at loads higher than 3.6 kg m{sup -3} d{sup -1} in the rest of the reactors. At loads lower than the previously mentioned, high methane production yield was obtained, 0.32-0.35 m{sup 33}CH4/kg CODremoved.

  16. Adsorptive control of water in esterification with immobilized enzymes: II. fixed-bed reactor behavior.

    Science.gov (United States)

    Mensah, P; Gainer, J L; Carta, G

    1998-11-20

    Experimental and theoretical studies are conducted to understand the dynamic behavior of a continuous-flow fixed-bed reactor in which an esterification is catalyzed by an immobilized enzyme in an organic solvent medium. The experimental system consists of a commercial immobilized lipase preparation known as Lipozyme as the biocatalyst, with propionic acid and isoamyl alcohol (dissolved in hexane) as the reaction substrates. A complex dynamic behavior is observed experimentally as a result of the simultaneous occurrence of reaction and adsorption phenomena. Both propionic acid and water are adsorbed by the biocatalyst resulting in lower reaction rates. In addition, an excessive accumulation of water in the reactor leads to a rapid irreversible inactivation of the enzyme. A model based on previously-obtained adsorption isotherms and kinetic expressions, as well as on adsorption rate measurements obtained in this work, is used to predict the concentration and thermodynamic activity of water along the reactor length. The model successfully predicts the dynamic behavior of the reactor and shows that a maximum thermodynamic activity of water occurs at a point at some distance from the reactor entrance. A cation exchange resin in sodium form, packed in the reactor as a selective water adsorbent together with the catalyst particles, is shown to be an effective means for preventing an excessive accumulation of water formed in the reaction. Its use results in longer cycle times and greater productivity. As predicted by the model, the experimental results show that the water adsorbed on the catalyst and on the ion exchange resin can be removed with isoamyl alcohol with no apparent loss in enzyme activity. Copyright 1998 John Wiley & Sons, Inc.

  17. Pebble bed modular reactor fuel enrichment discrimination using delayed neutrons - HTR2008-58133

    International Nuclear Information System (INIS)

    Skoda, R.; Rataj, J.; Uhera, J.

    2008-01-01

    The Pebble Bed Modular Reactor (PBMR) is a helium-cooled, graphite-moderated high temperature nuclear power reactor which utilise fuel in form of spheres that are randomly loaded and continuously circulated through the core until they reach their prescribed end-of-life burn-up limit. When the reactor is started up for the first time, the lower-enriched start-up fuel is used, mixed with graphite spheres, to bring the core to criticality. As the core criticality is established and the start-up fuel is burned-in, the graphite spheres are progressively removed and replaced with more start-up fuel. Once it becomes necessary for maintaining power output, the higher enriched equilibrium fuel is introduced to the reactor and the start-up fuel is removed. During the initial run of the reactor it is important to discriminate between the irradiated startup fuel and the irradiated equilibrium fuel to ensure that only the equilibrium fuel is returned to the reactor. There is therefore a need for an on-line enrichment discrimination device that can discriminate between irradiated start-up fuel spheres and irradiated equilibrium fuel spheres. The device must also not be confused by the presence of any remaining graphite spheres. Due to it's on-line nature the device must accomplish the discrimination within tight time limits. Theoretical calculations and experiments show that Fuel Enrichment Discrimination based on delayed neutrons detection is possible. The paper presents calculations and experiments showing viability of the method. (authors)

  18. Optimal oxygen feeding policy to maximize the production of Maleic anhydride in unsteady state fixed bed catalytic reactors

    Directory of Open Access Journals (Sweden)

    E. Ali

    2017-07-01

    Full Text Available The effect of different oxygen feeding scenarios in a fixed bed reactor for the production of Maleic anhydride (MA is studied. Two reactor configurations were examined. In the first configuration, a cross flow reactor (CFR with 4 discrete feeding points is considered. Another configuration is the conventional packed-bed reactor (PBR with a single feed. Nonlinear Model Predictive Controller (NLMPC was used as optimal controller to operate the CFR in dynamic mode and to optimize the multiple feed dosages in order to enhance the MA yield. The simulation results indicated that different combinations of the four feed ratios can operate the reactor at the best value for the yield provided the first feeding point is kept as low as possible. For the packed bed reactor configuration, a single oxygen feed is considered and is optimized transiently by NLMPC. The simulation outcomes showed that the reactor performance in terms of the produced MA mole fraction can also be enhanced to the same magnitude obtained by CFR configuration. This improvement requires decreasing the oxygen ratio in the reactor single feed by 70%.

  19. High temperature CO2 capture using calcium oxide sorbent in a fixed-bed reactor

    International Nuclear Information System (INIS)

    Dou Binlin; Song Yongchen; Liu Yingguang; Feng Cong

    2010-01-01

    The gas-solid reaction and breakthrough curve of CO 2 capture using calcium oxide sorbent at high temperature in a fixed-bed reactor are of great importance, and being influenced by a number of factors makes the characterization and prediction of these a difficult problem. In this study, the operating parameters on reaction between solid sorbent and CO 2 gas at high temperature were investigated. The results of the breakthrough curves showed that calcium oxide sorbent in the fixed-bed reactor was capable of reducing the CO 2 level to near zero level with the steam of 10 vol%, and the sorbent in CaO mixed with MgO of 40 wt% had extremely low capacity for CO 2 capture at 550 deg. C. Calcium oxide sorbent after reaction can be easily regenerated at 900 deg. C by pure N 2 flow. The experimental data were analyzed by shrinking core model, and the results showed reaction rates of both fresh and regeneration sorbents with CO 2 were controlled by a combination of the surface chemical reaction and diffusion of product layer.

  20. Start-up and performance characteristics of a trickle bed reactor degrading toluene

    Directory of Open Access Journals (Sweden)

    Ondrej Misiaczek

    2007-09-01

    Full Text Available The objective of this work was to evaluate toluene degradation in a trickle bed reactor when the loading was carried out by changing the air flow rate. The biofiltration system was inoculated with a mixed microbial population, adapted to degradation of hydrophobic compounds. Polypropylene high flow rings were used as a packing material. The system was operated for a period of 50 days at empty bed residence times ranging from 106s to 13s and with a constant inlet concentration of toluene of 100 mg.m-3. The reactor showed high removal efficiency at higher contact times and increasing elimination capacity with higher air-flow rates. The highest EC value reached was 9.8 gC.m-3.h-1 at EBRT = 13s. During the experiment, the consumption of NaOH solution was also measured. No significant variation of this value was found and an average value of 3.84 mmol of NaOH per gram of consumed carbon was recorded.

  1. High performance biological methanation in a thermophilic anaerobic trickle bed reactor.

    Science.gov (United States)

    Strübing, Dietmar; Huber, Bettina; Lebuhn, Michael; Drewes, Jörg E; Koch, Konrad

    2017-12-01

    In order to enhance energy efficiency of biological methanation of CO 2 and H 2 , this study investigated the performance of a thermophilic (55°C) anaerobic trickle bed reactor (ATBR) (58.1L) at ambient pressure. With a methane production rate of up to 15.4m 3 CH4 /(m 3 trickle bed ·d) at methane concentrations above 98%, the ATBR can easily compete with the performance of other mixed culture methanation reactors. Control of pH and nutrient supply turned out to be crucial for stable operation and was affected significantly by dilution due to metabolic water production, especially during demand-orientated operation. Considering practical applications, inoculation with digested sludge, containing a diverse biocenosis, showed high adaptive capacity due to intrinsic biological diversity. However, no macroscopic biofilm formation was observed at thermophilic conditions even after 313days of operation. The applied approach illustrates the high potential of thermophilic ATBRs as a very efficient energy conversion and storage technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. New sampling method in continuous energy Monte Carlo calculation for pebble bed reactors

    International Nuclear Information System (INIS)

    Murata, Isao; Takahashi, Akito; Mori, Takamasa; Nakagawa, Masayuki.

    1997-01-01

    A pebble bed reactor generally has double heterogeneity consisting of two kinds of spherical fuel element. In the core, there exist many fuel balls piled up randomly in a high packing fraction. And each fuel ball contains a lot of small fuel particles which are also distributed randomly. In this study, to realize precise neutron transport calculation of such reactors with the continuous energy Monte Carlo method, a new sampling method has been developed. The new method has been implemented in the general purpose Monte Carlo code MCNP to develop a modified version MCNP-BALL. This method was validated by calculating inventory of spherical fuel elements arranged successively by sampling during transport calculation and also by performing criticality calculations in ordered packing models. From the results, it was confirmed that the inventory of spherical fuel elements could be reproduced using MCNP-BALL within a sufficient accuracy of 0.2%. And the comparison of criticality calculations in ordered packing models between MCNP-BALL and the reference method shows excellent agreement in neutron spectrum as well as multiplication factor. MCNP-BALL enables us to analyze pebble bed type cores such as PROTEUS precisely with the continuous energy Monte Carlo method. (author)

  3. Determination of the enzyme reaction rate in a differential fixed-bed reactor: a case study

    Directory of Open Access Journals (Sweden)

    Baruque Filho E.A.

    2001-01-01

    Full Text Available The reaction rate of starch hydrolysis catalyzed by a glucoamylase covalently bound to chitin particles was measured in a Differential Fixed-Bed Reactor (DFBR. Under selected test conditions the initial reaction rate may represent biocatalyst activity. Some aspects which influence measurement of the initial reaction rate of an immobilized enzyme were studied: the amount of desorbed enzyme and its hydrolytic activity, the extent of pore blockage of the biocatalyst caused by substrate solution impurities and the internal and external diffusional mass transfer effects. The results showed that the enzyme glucoamylase was firmly bound to the support, as indicated by the very low amount of desorbed protein found in the recirculating liquid. Although this protein was very active, its contribution to the overall reaction rate was negligible. It was observed that the biocatalyst pores were susceptible to being blocked by the impurities of the starch solution. This latter effect was accumulative, increasing with the number of sequential experiments carried out. When the substrate solution was filtered before use, very reliable determinations of immobilized enzyme reaction rates could be performed in the DFBR. External and internal diffusional resistences usually play a significant role in fixed-bed reactors. However, for the experimental system studied, internal mass transfer effects were not significant, and it was possible to select an operational condition (recirculation flow rate value that minimized the external diffusional limitations.

  4. The Cross-Flow Mixing Analysis of Quasi-Static Pebble Flow in Pebble Bed Reactor

    International Nuclear Information System (INIS)

    Fang Xiang; Liu Zhiyong; Sun Yanfei; Yang Xingtuan; Jiang Shengyao

    2014-01-01

    In the pebble bed reactor, large number of fuel pebbles’ movement law and moving state can affect the reactor’s design, operation and safety directly. Therefore the pebble flow, which is based on the theory of particle streaming, is one of the most important research subjects of the pebble bed reactor engineering. The in-core pebble flow is a very slow particle flow (or called quasi-static particle flow), which is very different from the usual particle motion. How to accurately describe the characteristics of in-core pebble flow is a central issue for this subject. Due to the presence of random flow, the cross-mixing phenomenon will occur inevitably. In the present paper, the mixing phenomenon of pebble flow is generalized on the basis of experiment results. The pebble flow cross-mixing probability serves as the parameter which describes both the regularity and the randomness of pebble flow. The results are provided in the form of diagrammatic presentation. (author)

  5. Hydrogen production by biomass steam gasification in fluidized bed reactor with Co catalyst

    International Nuclear Information System (INIS)

    Kazuhiko Tasaka; Atsushi Tsutsumi; Takeshi Furusawa

    2006-01-01

    The catalytic performances of Co/MgO catalysts were investigated in steam gasification of cellulose and steam reforming of tar derived from cellulose gasification. For steam reforming of cellulose tar in a secondary fixed bed reactor, 12 wt.% Co/MgO catalyst attained more than 80% of tar reduction. The amount of produced H 2 and CO 2 increased with the presence of catalyst, and kept same level during 2 hr at 873 K. It is indicated that steam reforming of cellulose tar proceeds sufficiently over Co/MgO catalyst. For steam gasification of cellulose in a fluidized bed reactor, it was found that tar reduction increases with Co loading amount and 36 wt.% Co/MgO catalyst showed 84% of tar reduction. The amounts of produced gas kept for 2 hr indicating that 36 wt.% Co/MgO catalyst is stable during the reaction. It was concluded that these Co catalysts are promising systems for the steam gasification of cellulose and steam reforming of cellulose tar. (authors)

  6. Investigation of flow dynamics of liquid phase in a pilot-scale trickle bed reactor using radiotracer technique

    International Nuclear Information System (INIS)

    Pant, H.J.; Sharma, V.K.

    2016-01-01

    A radiotracer investigation was carried out to measure residence time distribution (RTD) of liquid phase in a trickle bed reactor (TBR). The main objectives of the investigation were to investigate radial and axial mixing of the liquid phase, and evaluate performance of the liquid distributor/redistributor at different operating conditions. Mean residence times (MRTs), holdups (H) and fraction of flow flowing along different quadrants were estimated. The analysis of the measured RTD curves indicated radial non-uniform distribution of liquid phase across the beds. The overall RTD of the liquid phase, measured at the exit of the reactor was simulated using a multi-parameter axial dispersion with exchange model (ADEM), and model parameters were obtained. The results of model simulations indicated that the TBR behaved as a plug flow reactor at most of the operating conditions used in the investigation. The results of the investigation helped to improve the existing design as well as to design a full-scale industrial TBR for petroleum refining applications. - Highlights: • Residence time distributions of liquid phase were measured in a trickle bed reactor. • Bromine-82 as ammonium bromide was used as a radiotracer. • Mean residence times, holdups and radial distribution of liquid phase were quantified. • Axial dispersion with exchange model was used to simulate the measured data. • The trickle bed reactor behaved as a plug flow reactor.

  7. 78 FR 71675 - Update of the Office of Nuclear Reactor Regulation's Electronic Operating Reactor Correspondence

    Science.gov (United States)

    2013-11-29

    ... NUCLEAR REGULATORY COMMISSION [NRC-2013-0260] Update of the Office of Nuclear Reactor Regulation's Electronic Operating Reactor Correspondence The U.S. Nuclear Regulatory Commission (NRC) is issuing this Federal Register notice to inform the public of a slight change in the manner of distribution of publicly available operating reactor licensing...

  8. Suspended-Bed Reactor preliminary design, 233U--232Th cycle. Final report (revised)

    International Nuclear Information System (INIS)

    Karam, R.A.; Alapour, A.; Lee, C.C.

    1977-11-01

    The preliminary design Suspended-Bed Reactor is described. Coated particles about 2 mm in diameter are used as the fuel. The coatings consist of three layers: (1) low density pyrolytic graphite, 70 μ thick, (2) silicon carbide pressure vessel, 30 μ thick, and (3) ZrC layer, 50 μ thick, to protect the pressure vessel from moisture and oxygen. The fuel kernel can be either uranium-thorium dicarbide or metal. The coated particles are suspended by helium gas (coolant) in a cluster of pressurized tubes. The upward flow of helium fluidizes the coated particles. As the flow rate increases, the bed of particles is lifted upward to the core section. The particles are restrained at the upper end of the core by a suitable screen. The overall particle density in the core is just enough for criticality condition. Should the helium flow cease, the bed in the core section will collapse, and the particles will flow downward into the section where the increased physical spacings among the tubes brings about a safe shutdown. By immersing this section of the tubes in a large graphite block to serve as a heat sink, dissipation of decay heat becomes manageable. This eliminates the need for emergency core cooling systems

  9. Hydrodynamic Modelling of Municipal Solid Waste Residues in a Pilot Scale Fluidized Bed Reactor

    Directory of Open Access Journals (Sweden)

    João Cardoso

    2017-11-01

    Full Text Available The present study investigates the hydrodynamics and heat transfer behavior of municipal solid waste (MSW gasification in a pilot scale bubbling fluidized bed reactor. A multiphase 2-D numerical model following an Eulerian-Eulerian approach within the FLUENT framework was implemented. User defined functions (UDFs were coupled to improve hydrodynamics and heat transfer phenomena, and to minimize deviations between the experimental and numerical results. A grid independence study was accomplished through comparison of the bed volume fraction profiles and by reasoning the grid accuracy and computational cost. The standard deviation concept was used to determine the mixing quality indexes. Simulated results showed that UDFs improvements increased the accuracy of the mathematical model. Smaller size ratio of the MSW-dolomite mixture revealed a more uniform mixing, and larger ratios enhanced segregation. Also, increased superficial gas velocity promoted the solid particles mixing. Heat transfer within the fluidized bed showed strong dependence on the MSW solid particles sizes, with smaller particles revealing a more effective process.

  10. Characteristic Studies of Micron Zinc Particle Hydrolysis in a Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Lv Ming

    2015-09-01

    Full Text Available Zinc fuel is considered as a kind of promising energy sources for marine propeller. As one of the key steps for zinc marine energy power system, zinc hydrolysis process had been studied experimentally in a fixed bed reactor. In this study, we focus on the characteristics of micron zinc particle hydrolysis. The experimental results suggested that the steam inner diffusion is the controlling step of accumulative zinc particles hydrolysis reaction at a relative lower temperature and a relative higher water partial pressure. In other conditions, the chemical reaction kinetics was the controlling step. And two kinds of chemical reaction kinetics appeared in experiments: the surface reaction and the gas-gas reaction. The latter one occurs usually for larger zinc particles and high reaction temperature. Temperature seems to be one of the most important parameters for the dividing of different reaction mechanisms. Several parameters of the hydrolysis process including heating rate, water partial pressure, the particle size and temperature were also studied in this paper. Results show that the initial reaction temperature of zinc hydrolysis in fixed bed is about 410°C. And the initial reaction temperature increases as the heating rate increases and as the water partial pressure decreases. The total hydrogen yield increases as the heating rate decreases, as the water partial pressure increases, as the zinc particle size decreases, and as the reaction temperature increases. A hydrogen yield of more than 81.5% was obtained in the fixed bed experiments.

  11. Safeguards Challenges for Pebble-Bed Reactors (PBRs):Peoples Republic of China (PRC)

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, Charles W. [Massachusetts Institute of Technology (MIT); Moses, David Lewis [ORNL

    2009-11-01

    The Peoples Republic of China (PRC) is operating the HTR-10 pebble-bed reactor (PBR) and is in the process of building a prototype PBR plant with two modular reactors (250-MW(t) per reactor) feeding steam to a single turbine-generator. It is likely to be the first modular hightemperature reactor to be ready for commercial deployment in the world because it is a highpriority project for the PRC. The plant design features multiple modular reactors feeding steam to a single turbine generator where the number of modules determines the plant output. The design and commercialization strategy are based on PRC strengths: (1) a rapidly growing electric market that will support low-cost mass production of modular reactor units and (2) a balance of plant system based on economics of scale that uses the same mass-produced turbine-generator systems used in PRC coal plants. If successful, in addition to supplying the PRC market, this strategy could enable China to be the leading exporter of nuclear reactors to developing countries. The modular characteristics of the reactor match much of the need elsewhere in the world. PBRs have major safety advantages and a radically different fuel. The fuel, not the plant systems, is the primary safety system to prevent and mitigate the release of radionuclides under accident conditions. The fuel consists of small (6-cm) pebbles (spheres) containing coatedparticle fuel in a graphitized carbon matrix. The fuel loading per pebble is small (~9 grams of low-enriched uranium) and hundreds of thousands of pebbles are required to fuel a nuclear plant. The uranium concentration in the fuel is an order of magnitude less than in traditional nuclear fuels. These characteristics make the fuel significantly less attractive for illicit use (weapons production or dirty bomb); but, its unusual physical form may require changes in the tools used for safeguards. This report describes PBRs, what is different, and the safeguards challenges. A series of

  12. Safeguards Challenges for Pebble-Bed Reactors (PBRs):Peoples Republic of China (PRC)

    International Nuclear Information System (INIS)

    Forsberg, Charles W.; Moses, David Lewis

    2009-01-01

    The Peoples Republic of China (PRC) is operating the HTR-10 pebble-bed reactor (PBR) and is in the process of building a prototype PBR plant with two modular reactors (250-MW(t) per reactor) feeding steam to a single turbine-generator. It is likely to be the first modular high temperature reactor to be ready for commercial deployment in the world because it is a high priority project for the PRC. The plant design features multiple modular reactors feeding steam to a single turbine generator where the number of modules determines the plant output. The design and commercialization strategy are based on PRC strengths: (1) a rapidly growing electric market that will support low-cost mass production of modular reactor units and (2) a balance of plant system based on economics of scale that uses the same mass-produced turbine-generator systems used in PRC coal plants. If successful, in addition to supplying the PRC market, this strategy could enable China to be the leading exporter of nuclear reactors to developing countries. The modular characteristics of the reactor match much of the need elsewhere in the world. PBRs have major safety advantages and a radically different fuel. The fuel, not the plant systems, is the primary safety system to prevent and mitigate the release of radionuclides under accident conditions. The fuel consists of small (6-cm) pebbles (spheres) containing coated particle fuel in a graphitized carbon matrix. The fuel loading per pebble is small (∼9 grams of low-enriched uranium) and hundreds of thousands of pebbles are required to fuel a nuclear plant. The uranium concentration in the fuel is an order of magnitude less than in traditional nuclear fuels. These characteristics make the fuel significantly less attractive for illicit use (weapons production or dirty bomb); but, its unusual physical form may require changes in the tools used for safeguards. This report describes PBRs, what is different, and the safeguards challenges. A series of

  13. Aerobic biodegradation of a sulfonated phenylazonaphthol dye by a bacterial community immobilized in a multistage packed-bed BAC reactor.

    Science.gov (United States)

    Ruiz-Arias, Alfredo; Juárez-Ramírez, Cleotilde; de los Cobos-Vasconcelos, Daniel; Ruiz-Ordaz, Nora; Salmerón-Alcocer, Angélica; Ahuatzi-Chacón, Deifilia; Galíndez-Mayer, Juvencio

    2010-11-01

    A microbial community able to aerobically degrade the azo dye Acid Orange 7 was selected from riparian or lacustrine sediments collected at sites receiving textile wastewaters. Three bacterial strains, pertaining to the genera Pseudomonas, Arthrobacter, and Rhizobium, constitute the selected community. The biodegradation of AO7 was carried out in batch-suspended cell culture and in a continuously operated multistage packed-bed BAC reactor. The rapid decolorization observed in batch culture, joined to a delay of about 24 h in COD removal and cell growth, suggests that enzymes involved in biodegradation of the aromatic amines generated after AO7 azo-bond cleavage (1-amino-2-naphthol [1-A2N] and 4-aminobenzenesulfonic acid [4-ABS]), are inducible in this microbial consortium. After this presumptive induction period, the accumulated byproducts, measured through COD, were partially metabolized and transformed in cell mass. At all azo dye loading rates used, complete removal of AO7 and 1-A2N was obtained in the multistage packed-bed BAC reactor (PBR).; however, the overall COD (eta ( COD )) and 4-ABS (eta ( ABS )) removal efficiencies obtained in steady state continuous culture were about 90%. Considering the toxicity of 1-A2N, its complete removal has particular relevance. In the first stages of the packed-bed BAC reactor (Fig. 4a-c), major removal was observed. In the last stage, only a slight removal of COD and 4-ABS was obtained. Comparing to several reported studies, the continuously operated multistage packed-bed BAC reactor showed similar or superior results. In addition, the operation of large-packed-bed BAC reactors could be improved by using several shallow BAC bed stages, because the pressure drop caused by bed compaction of a support material constituted by small and fragile particles can be reduced.

  14. Study on Characteristic of Temperature Coefficient of Reactivity for Plutonium Core of Pebbled Bed Reactor

    Science.gov (United States)

    Zuhair; Suwoto; Setiadipura, T.; Bakhri, S.; Sunaryo, G. R.

    2018-02-01

    As a part of the solution searching for possibility to control the plutonium, a current effort is focused on mechanisms to maximize consumption of plutonium. Plutonium core solution is a unique case in the high temperature reactor which is intended to reduce the accumulation of plutonium. However, the safety performance of the plutonium core which tends to produce a positive temperature coefficient of reactivity should be examined. The pebble bed inherent safety features which are characterized by a negative temperature coefficient of reactivity must be maintained under any circumstances. The purpose of this study is to investigate the characteristic of temperature coefficient of reactivity for plutonium core of pebble bed reactor. A series of calculations with plutonium loading varied from 0.5 g to 1.5 g per fuel pebble were performed by the MCNPX code and ENDF/B-VII library. The calculation results show that the k eff curve of 0.5 g Pu/pebble declines sharply with the increase in fuel burnup while the greater Pu loading per pebble yields k eff curve declines slighter. The fuel with high Pu content per pebble may reach long burnup cycle. From the temperature coefficient point of view, it is concluded that the reactor containing 0.5 g-1.25 g Pu/pebble at high burnup has less favorable safety features if it is operated at high temperature. The use of fuel with Pu content of 1.5 g/pebble at high burnup should be considered carefully from core safety aspect because it could affect transient behavior into a fatal accident situation.

  15. Continuous Packed Bed Reactor with Immobilized β-Galactosidase for Production of Galactooligosaccharides (GOS

    Directory of Open Access Journals (Sweden)

    Barbara Rodriguez-Colinas

    2016-11-01

    Full Text Available The β-galactosidase from Bacillus circulans was covalently attached to aldehyde-activated (glyoxal agarose beads and assayed for the continuous production of galactooligosaccharides (GOS in a packed-bed reactor (PBR. The immobilization was fast (1 h and the activity of the resulting biocatalyst was 97.4 U/g measured with o-nitrophenyl-β-d-galactopyranoside (ONPG. The biocatalyst showed excellent operational stability in 14 successive 20 min reaction cycles at 45 °C in a batch reactor. A continuous process for GOS synthesis was operated for 213 h at 0.2 mL/min and 45 °C using 100 g/L of lactose as a feed solution. The efficiency of the PBR slightly decreased with time; however, the maximum GOS concentration (24.2 g/L was obtained after 48 h of operation, which corresponded to 48.6% lactose conversion and thus to maximum transgalactosylation activity. HPAEC-PAD analysis showed that the two major GOS were the trisaccharide Gal-β(1→4-Gal-β(1→4-Glc and the tetrasaccharide Gal-β(1→4-Gal-β(1→4-Gal-β(1→4-Glc. The PBR was also assessed in the production of GOS from milk as a feed solution. The stability of the bioreactor was satisfactory during the first 8 h of operation; after that, a decrease in the flow rate was observed, probably due to partial clogging of the column. This work represents a step forward in the continuous production of GOS employing fixed-bed reactors with immobilized β-galactosidases.

  16. Partial oxidation of Raffinate II and other mixtures of n-Butane and n-Butenes to maleic anhydride in a fixed-bed reactor

    OpenAIRE

    Brandstädter, Willi Michael

    2008-01-01

    The utilisation of the C4 streams of steamcrackers by converting raffinate II to maleic anhydride was studied. The oxidation reactions were investigated in a laboratory-scale fixed-bed reactor to determine reaction kinetics. The effects of pore diffusional resistance were investigated and explained. A two-dimensional pseudo-homogeneous reactor model was used for the simulation of a production-scale fixed-bed reactor. A flow scheme of the reactor section including a recycle was proposed.

  17. Influence of dissolved oxygen on the nitrification kinetics in a circulating bed biofilm reactor

    Energy Technology Data Exchange (ETDEWEB)

    Nogueira, R.; Melo, L.F. [University of Minho, Braga (Portugal). Dept. Bioengineering; Lazarova, V.; Manem, J. [Centre of International Research for Water and Environment (CIRSEE), Lyonnaise des Eaux, Le Pecq (France)

    1998-12-01

    The influence of dissolved oxygen concentration on the nitrification kinetics was studied in the circulating bed reactor (CBR). The study was partly performed at laboratory scale with synthetic water, and partly at pilot scale with secondary effluent as feed water. The nitrification kinetics of the laboratory CBR as a function of the oxygen concentration can be described according to the half order and zero order rate equations of the diffusion-reaction model applied to porous catalysts. When oxygen was the rate limiting substrate, the nitrification rate was close to a half order function of the oxygen concentration. The average oxygen diffusion coefficient estimated by fitting the diffusion-reaction model to the experimental results was around 66% of the respective value in water. The experimental results showed that either the ammonia or the oxygen concentration could be limiting for the nitrification kinetics. The latter occurred for an oxygen to ammonia concentration ratio below 1.5-2 gO{sub 2}/gN-NH{sub 4}{sup +} for both laboratory and pilot scale reactors. The volumetric oxygen mass transfer coefficient (k{sub L}a) determined in the laboratory scale reactor was 0.017 s{sup -1} for a superficial air velocity of 0.02 m s{sup -1}, and the one determined in the pilot scale reactor was 0.040 s{sup -1} for a superficial air velocity of 0.031 m s{sup -1}. The k{sub L}a for the pilot scale reactor did not change significantly after biofilm development, compared to the value measured without biofilm. (orig.) With 7 figs., 5 tabs., 24 refs.

  18. Pore Scale Thermal Hydraulics Investigations of Molten Salt Cooled Pebble Bed High Temperature Reactor with BCC and FCC Configurations

    Directory of Open Access Journals (Sweden)

    Shixiong Song

    2014-01-01

    CFD results and empirical correlations’ predictions of pressure drop and local Nusselt numbers. Local pebble surface temperature distributions in several default conditions are investigated. Thermal removal capacities of molten salt are confirmed in the case of nominal condition; the pebble surface temperature under the condition of local power distortion shows the tolerance of pebble in extreme neutron dose exposure. The numerical experiments of local pebble insufficient cooling indicate that in the molten salt cooled pebble bed reactor, the pebble surface temperature is not very sensitive to loss of partial coolant. The methods and results of this paper would be useful for optimum designs and safety analysis of molten salt cooled pebble bed reactors.

  19. Process development and modeling of fluidized-bed reactor with coimmobilized biocatalyst for fuel ethanol production

    Science.gov (United States)

    Sun, May Yongmei

    This research focuses on two steps of commercial fuel ethanol production processes: the hydrolysis starch process and the fermentation process. The goal of this research is to evaluate the performance of co-immobilized biocatalysts in a fluidized bed reactor with emphasis on economic and engineering aspects and to develop a predictive mathematical model for this system. The productivity of an FBR is higher than productivity of a traditional batch reactor or CSTR. Fluidized beds offer great advantages over packed beds for immobilized cells when small particles are used or when the reactant feed contains suspended solids. Plugging problems, excessive pressure drops (and thus attrition), or crushing risks may be avoided. No mechanical stirring is required as mixing occurs due to the natural turbulence in the fluidized process. Both enzyme and microorganism are immobilized in one catalyst bead which is called co-immobilization. Inside this biocatalyst matrix, starch is hydrolyzed by the enzyme glucoamylase to form glucose and then converted to ethanol and carbon dioxide by microorganisms. Two biocatalysts were evaluated: (1) co-immobilized yeast strain Saccharomyces cerevisiae and glucoamylase. (2) co-immobilized Zymomonas mobilis and glucoamylase. A co-immobilized biocatalyst accomplishes the simultaneous saccharification and fermentation (SSF process). When compared to a two-step process involving separate saccharification and fermentation stages, the SSF process has productivity values twice that given by the pre-saccharified process when the time required for pre-saccharification (15--25 h) was taken into account. The SSF process should also save capital cost. The information about productivity, fermentation yield, concentration profiles along the bed, ethanol inhibition, et al., was obtained from the experimental data. For the yeast system, experimental results showed that: no apparent decrease of productivity occurred after two and half months, the productivity

  20. Flow distribution of pebble bed high temperature gas cooled reactors using large eddy simulation

    International Nuclear Information System (INIS)

    Gokhan Yesilyurt; Hassan, Y.A.

    2003-01-01

    A High Temperature Gas-cooled Reactor (HTGR) is one of the renewed reactor designs to play a role in nuclear power generation. This reactor design concepts is currently under consideration and development worldwide. Since the HTGR concept offers inherent safety, has a very flexible fuel cycle with capability to achieve high burnup levels, and provides good thermal efficiency of power plant, it can be considered for further development and improvement as a reactor concept of generation IV. The combination of coated particle fuel, inert helium gas as coolant and graphite moderated reactor makes it possible to operate at high temperature yielding a high efficiency. In this study the simulation of turbulent transport for the gas through the gaps of the spherical fuel elements (fuel pebbles) will be performed. This will help in understanding the highly three-dimensional, complex flow phenomena in pebble bed caused by flow curvature. Under these conditions, heat transfer in both laminar and turbulent flows varies noticeably around curved surfaces. Curved flows would be present in the presence of contiguous curved surfaces. In the case of a laminar flow and of an appreciable effect of thermogravitional forces, the Nusselt (Nu) number depends significantly on the curvature shape of the surface. It changes with order of 10 times. The flow passages through the gap between the fuel balls have concave and convex configurations. Here the action of the centrifugal forces manifests itself differently on convex and concave parts of the flow path (suppression or stimulation of turbulence). The flow of this type has distinctive features. In such flow there is a pressure gradient, which strongly affects the boundary layer behavior. The transition from a laminar to turbulent flow around this curved flow occurs at deferent Reynolds (Re) numbers. Consequently, noncircular curved flows as in the pebble-bed situation, in detailed local sense, is interesting to be investigated. To the

  1. Improved Performances of a Fluidized Bed Photo reactor by a Microscale Illumination System

    International Nuclear Information System (INIS)

    Ciambelli, P.; Sannino, D.; Palma, V.; Vaiano, V.; Mazzei, R.S.; Ciambelli, P.; Sannino, D.

    2009-01-01

    The performances of a gas-solid two-dimensional fluidized bed reactor in photo catalytic selective oxidation reactions, irradiated with traditional UV lamps or with a microscale illumination system based on UV emitting diodes (UV A-LEDs), have been compared. In the photo catalytic oxidative dehydrogenation of cyclohexane to benzene on MoOx/TiO 2 -A1 2 O 3 catalyst the use of UV A-LEDs modules allowed to achieve a cyclohexane conversion and benzene yield higher than those obtained with traditional UV lamps. The better performances with UV A-LEDs are due to the UV A-LEDs small dimensions and small-angle emittance, which allow photons beam be directed towards the photo reactor windows, reducing the dispersion outside of photo reactor or the optical path length. As a consequence, the effectively illuminated mass of catalyst is greater. We have found that this illumination system is efficient for photo-oxidative dehydrogenation of cyclohexane to cyclohexene on sulphated MoOx-A1 2 O 3 and ethanol to acetaldehyde on VOx/TiO 2 .

  2. Effect of hydraulic retention time on metal precipitation in sulfate reducing inverse fluidized bed reactors

    KAUST Repository

    Villa-Gómez, Denys Kristalia

    2014-02-13

    BACKGROUND: Metal sulfide recovery in sulfate reducing bioreactors is a challenge due to the formation of small precipitates with poor settling properties. The size of the metal sulfide precipitates with the change in operational parameters such as pH, sulfide concentration and reactor configuration has been previously studied. The effect of the hydraulic retention time (HRT) on the metal precipitate characteristics such as particle size for settling has not yet been addressed. RESULTS: The change in size of the metal (Cu, Zn, Pb and Cd) sulfide precipitates as a function of the HRT was studied in two sulfate reducing inversed fluidized bed (IFB) reactors operating at different chemical oxygen demand concentrations to produce high and low sulfide concentrations. The decrease of the HRT from 24 to 9h in both IFB reactors affected the contact time of the precipitates formed, thus making differences in aggregation and particle growth regardless of the differences in sulfide concentration. Further HRT decrease to 4.5h affected the sulfate reducing activity for sulfide production and hence, the supersaturation level and solid phase speciation. Metal sulfide precipitates affected the sulfate reducing activity and community in the biofilm, probably because of the stronger local supersaturation causing metal sulfides accumulation in the biofilm. CONCLUSIONS: This study shows that the HRT is an important factor determining the size and thus the settling rate of the metal sulfides formed in bioreactors.

  3. Improvement of burnup analysis for pebble bed reactors with an accumulative fuel loading scheme

    International Nuclear Information System (INIS)

    Simanullang, Irwan Liapto; Obara, Toru

    2015-01-01

    Given the limitations of natural uranium resources, innovative nuclear power plant concepts that increase the efficiency of nuclear fuel utilization are needed. The Pebble Bed Reactor (PBR) shows some potential to achieve high efficiency in natural uranium utilization. To simplify the PBR concept, PBR with an accumulation fuel loading scheme was introduced and the Fuel Handling System (FHS) removed. In this concept, the pebble balls are added little by little into the reactor core until the pebble balls reach the top of the reactor core, and all pebble balls are discharged from the core at the end of the operation period. A code based on the MVP/MVP-BURN method has been developed to perform an analysis of a PBR with the accumulative fuel loading scheme. The optimum fuel composition was found using the code for high burnup performance. Previous efforts provided several motivations to improve the burnup performance: First, some errors in the input code were corrected. This correction, and an overall simplification of the input code, was implemented for easier analysis of a PBR with the accumulative fuel loading scheme. Second, the optimum fuel design had been obtained in the infinite geometry. To improve the optimum fuel composition, a parametric survey was obtained by varying the amount of Heavy Metal (HM) uranium per pebble and the degree of uranium enrichment. Moreover, an entire analysis of the parametric survey was obtained in the finite geometry. The results show that improvements in the fuel composition can lead to more accurate analysis with the code. (author)

  4. Decolourization of remazol black-5 textile dyes using moving bed bio-film reactor

    Science.gov (United States)

    Pratiwi, R.; Notodarmojo, S.; Helmy, Q.

    2018-01-01

    The desizing and dyeing processes in the textile industries produces wastewaster containing high concentration of organic matter and colour, so it needs treatment before released to environment. In this research, removal of azo dye (Remazol Black 5/RB 5) and organic as COD was performed using Moving Bed Biofilm Reactor (MBBR). MBBR is biological treatment process with attached growth media system that can increase removal of organic matter in textile wastewater. The effectiveness of ozonation as pre-treatment process to increase the removal efficiency in MBBR was studied. The results showed that in MBBR batch system with detention time of 1 hour, pre-treatment with ozonation prior to MBBR process able to increase the colour removal efficiency of up to 86.74%. While on the reactor without ozone pre-treatment, the colour removal efficiency of up to 68.6% was achieved. From the continuous reactor experiments found that both colour and COD removal efficiency depends on time detention of RB-5 dyes in the system. The higher of detention time, the higher of colour and COD removal efficiency. It was found that optimum removal of colour and COD was achieved in 24 hour detention time with its efficiency of 96.9% and 89.13%, respectively.

  5. The use of moving bed bio-reactor to laundry wastewater treatment

    Science.gov (United States)

    Bering, Sławomira; Mazur, Jacek; Tarnowski, Krzysztof; Janus, Magdalena; Mozia, Sylwia; Waldemar Morawski, Antoni

    2017-11-01

    Large laboratory scale biological treatment test of industrial real wastewater, generated in industrial big laundry, has been conducted in the period of May 2016-August 2016. The research aimed at selection of laundry wastewater treatment technology included tests of two-stage Moving Bed Bio Reactor (MBBR), with two reactors filled with carriers Kaldnes K5 (specific area - 800 m2/m3), have been realized in aerobic condition. Operating on site, in the laundry, reactors have been fed real wastewater from laundry retention tank. To the laundry wastewater, contained mainly surfactants and impurities originating from washed fabrics, a solution of urea to supplement nitrogen content and a solution of acid to correct pH have been added. Daily flow of raw wastewater Qd was equal to 0.6-0.8 m3/d. The values of determined wastewater quality indicators showed that substantial decrease of pollutants content have been reached: BOD5 by 94.7-98.1%, COD by 86.9-93.5%, the sum of anionic and nonionic surfactants by 98.7-99.8%. The quality of the purified wastewater, after star-up period, meets the legal requirements regarding the standards for wastewater discharged to the environment.

  6. Simultaneous Coproduction of Hydrogen and Ethanol in Anaerobic Packed-Bed Reactors

    Directory of Open Access Journals (Sweden)

    Cristiane Marques dos Reis

    2014-01-01

    Full Text Available This study evaluated the use of an anaerobic packed-bed reactor for hydrogen production at different hydraulic retention times (HRT (1–8 h. Two reactors filled with expanded clay and fed with glucose (3136–3875 mg L−1 were operated at different total upflow velocities: 0.30 cm s−1 (R030 and 0.60 cm s−1 (R060. The effluent pH of the reactors was maintained between 4 and 5 by adding NaHCO3 and HCl solutions. It was observed a maximum hydrogen production rate of 0.92 L H2 h−1 L−1 in R030 at HRT of 1 h. Furthermore, the highest hydrogen yield of 2.39 mol H2 mol−1 glucose was obtained in R060. No clear trend was observed by doubling the upflow velocities at this experiment. High ethanol production was also observed, indicating that the ethanol-pathway prevailed throughout the experiment.

  7. CFD Simulation of Dimethyl Ether Synthesis from Methanol in an Adiabatic Fixed-bed Reactor

    Directory of Open Access Journals (Sweden)

    Mohammad Golshadi

    2013-04-01

    Full Text Available A computational fluid dynamic (CFD study of methanol (MeOH to dimethyl ether (DME process in an adiabatic fixed-bed reactor is presented. One of the methods of industrial DME production is the catalytic dehydration of MeOH. Kinetic model was derived based on Bercic rate. The parameters of this equation for a specific catalyst were tuned by solving a one-dimensional homogenous model using MATLAB optimization module. A two-dimensional CFD simulation of the reaction is demonstrated and considered as numerical experiments. A sensitivity analysis was run in order to find the effect of temperature, pressure, and WHSV on the reactor performance. Good agreement was achieved between bench experimental data and the model. The results show that the maximum conversion of reaction (about 85.03% is obtained at WHSV=10 h-1 and T=563.15 K, whereas the inlet temperature has a greater effect on methanol conversion. Moreover, the effect of water in inlet feed on methanol conversion is quantitatively studied. It was concluded that the results obtained from CFD analysis give precise guidelines for further studies on the optimization of reactor performance.

  8. Pebble bed modular reactors versus other generation technologies. Costs and challenges for South Africa

    International Nuclear Information System (INIS)

    Grubert, Emily; Parks, Brian; Schneider, Erich; Sekar, Srinivas

    2011-01-01

    South Africa is Africa's major economy, with plans to double its electricity generation capacity by 2026. South Africa has spent almost two decades developing a nuclear reactor known as a Pebble Bed Modular Reactor (PBMR), which could provide substantial benefits to the electricity grid but was recently mothballed due to high costs. This work estimates the lifecycle financial costs of South African PBMRs, then compares these costs to those of five other generation options: coal, nuclear as pressurized water reactors (PWRs), wind, and solar as photovoltaics (PV) or concentrating solar power (CSP). Each technology is evaluated with low, base case, and high assumptions for capital costs, construction time, and interest rates. Decommissioning costs, project lifetime, capacity factors, and sensitivity to carbon price are also considered. PBMR could be cost competitive with coal under certain low cost conditions, even without a carbon price. However, international lending practices and other factors suggest that a high capital cost, high interest rate nuclear plant is likely to be competing with a low capital cost, low interest rate coal plant in a market where cost recovery is challenging. PBMR could potentially become more competitive if low rate international loans were available to nuclear projects or became unavailable to coal projects. (author)

  9. Influence of mass transfer resistance on overall nitrate removal rate in upflow sludge bed reactors.

    Science.gov (United States)

    Ting, Wen-Huei; Huang, Ju-Sheng

    2006-09-01

    A kinetic model with intrinsic reaction kinetics and a simplified model with apparent reaction kinetics for denitrification in upflow sludge bed (USB) reactors were proposed. USB-reactor performance data with and without sludge wasting were also obtained for model verification. An independent batch study showed that the apparent kinetic constants k' did not differ from the intrinsic k but the apparent Ks' was significantly larger than the intrinsic Ks suggesting that the intra-granule mass transfer resistance can be modeled by changes in Ks. Calculations of the overall effectiveness factor, Thiele modulus, and Biot number combined with parametric sensitivity analysis showed that the influence of internal mass transfer resistance on the overall nitrate removal rate in USB reactors is more significant than the external mass transfer resistance. The simulated residual nitrate concentrations using the simplified model were in good agreement with the experimental data; the simulated results using the simplified model were also close to those using the kinetic model. Accordingly, the simplified model adequately described the overall nitrate removal rate and can be used for process design.

  10. CFD analysis of hot spot formation through a fixed bed reactor of Fischer-Tropsch synthesis

    Directory of Open Access Journals (Sweden)

    Hamed Aligolzadeh

    2015-12-01

    Full Text Available One of the interesting methods for conversion of synthesis gas to heavy hydrocarbons is Fischer–Tropsch process. The process has some bottlenecks, such as hot spot formation and low degree of conversion. In this work, computational fluid dynamics technique was used to simulate conversion of synthetic gas and product distribution. Also, hot spot formation in the catalytic fixed-bed reactor was investigated in several runs. Simulation results indicated that hot spot formation occurred more likely in the early and middle part of reactor due to high reaction rates. Based on the simulation results, the temperature of hot spots increased with increase in the inlet temperature as well as pressure. Among the many CFD runs conducted, it is found that the optimal temperature and pressure for Fischer–Tropsch synthesis are 565 K and 20 bar, respectively. As it seems that the reactor shall work very well under optimal conditions, the reaction rates and catalyst duration would simultaneously be maximum .

  11. Start-up and bacterial community compositions of partial nitrification in moving bed biofilm reactor.

    Science.gov (United States)

    Liu, Tao; Mao, Yan-Jun; Shi, Yan-Ping; Quan, Xie

    2017-03-01

    Partial nitrification (PN) has been considered as one of the promising processes for pretreatment of ammonium-rich wastewater. In this study, a kind of novel carriers with enhanced hydrophilicity and electrophilicity was implemented in a moving bed biofilm reactor (MBBR) to start up PN process. Results indicated that biofilm formation rate was higher on modified carriers. In comparison with the reactor filled with traditional carriers (start-up period of 21 days), it took only 14 days to start up PN successfully with ammonia removal efficiency and nitrite accumulation rate of 90 and 91%, respectively, in the reactor filled with modified carriers. Evident changes of spatial distributions and community structures had been detected during the start-up. Free-floating cells existed in planktonic sludge, while these microorganisms trended to form flocs in the biofilm. High-throughput pyrosequencing results indicated that Nitrosomonas was the predominant ammonia-oxidizing bacterium (AOB) in the PN system, while Comamonas might also play a vital role for nitrogen oxidation. Additionally, some other bacteria such as Ferruginibacter, Ottowia, Saprospiraceae, and Rhizobacter were selected to establish stable footholds. This study would be potentially significant for better understanding the microbial features and developing efficient strategies accordingly for MBBR-based PN operation.

  12. 3D DEM simulation and analysis of void fraction distribution in a pebble bed high temperature reactor

    International Nuclear Information System (INIS)

    Yang, Xingtuan; Gui, Nan; Tu, Jiyuan; Jiang, Shengyao

    2014-01-01

    Highlights: • We show a detailed analysis of void fraction (VF) in HTR-10 of China using DEM. • Radial distribution (RD) of VF is uniform in the core and oscillated near the wall. • Axial distribution (AD) is linearly varied along height due to effect of gravity. • Steady RD of VF in the conical base is Gaussian-like, larger than packing bed. • Joint linear and normal distribution of VF is analyzed and explained. - Abstract: The current work analyzes the radial and axial distributions of void fraction of a pebble bed high temperature reactor. A three-dimensional pebble bed corresponding to our test facility of pebble bed type gas-cooled high temperature reactor (HTR-10) in Tsinghua University is simulated via discrete element method, and the radial and axial void fraction profiles are calculated. It validates the oscillating characteristics of radial void fraction near the wall. Detailed calculations show the differences of void fraction profiles between the stationary packing bed and the dynamically discharging bed. Based on the vertically and circumferentially averaged radial distribution and horizontally averaged axial distribution of void fraction, a fully three-dimensional analytical distribution of void fraction throughout the bed is established. The results show the combined effects of gravity and void variation in the pebble bed caused by the pebble discharging. It indicates the linearly increased packing effect caused by gravity in the vertical (axial) direction and the normal distribution of void in the horizontal (radial) direction by pebble drainage. These two effects coexist in the conical base of the bed whereas only the former effect exists in the cylindrical volume of the bed

  13. Dating the Naisiusiu Beds, Olduvai Gorge, by electron spin resonance

    Science.gov (United States)

    Skinner, A. R.; Hay, R. L.; Masao, F.; Blackwell, B. A. B.

    2003-05-01

    The lower beds at Olduvai Gorge are well known for containing early hominid fossils and Oldowan stone tools, and their ages have been established by 40Ar/ 39Ar dating and paleomagnetic stratigraphy. Ages are generally less certain for the upper deposits at Olduvai Gorge because of the scarcity of datable tuffs. The youngest archaeologically significant site at Olduvai is microlithic LSA, which lies in the type section of the Naisiusiu Beds. The age for the site is controversial, with 14C dates of 17,000-17,550 (Hay, R.L., 1976 Geology of Olduvai Gorge, University of California Press, Berkeley) and >42,000 BP (Manega, P.C., 1993. Geochronology, geochemistry, and isotopic study of the Plio-Pleistocene Hominid sites and the Ngorongoro Volcanic Highland in Northern Tanzania. Unpublished Ph.D. Thesis, University of Colorado, Boulder, CO). The tuff bed in the zone with artifacts does not contain materials datable by 40Ar/ 39Ar, and some other dating method was needed. In the summer of 2001, five equid teeth were collected from the type Naisiusiu site. Another tooth had previously been collected. ESR ages have been determined for three teeth from the archaeological level and their ages cluster around 62±5 ka, assuming linear uranium uptake. Another tooth from a level without artifacts and believed to be significantly younger dated to 39±5 ka, again assuming LU. These dates are considerably older than previous estimates and suggest that the East African MSA/LSA transition occurred very early.

  14. Optimization of a radially cooled pebble bed reactor - HTR2008-58117

    International Nuclear Information System (INIS)

    Boer, B.; Kloosterman, J. L.; Lathouwers, D.; Van Der Hagen, T. H. J. J.; Van Dam, H.

    2008-01-01

    By altering the coolant flow direction in a pebble bed reactor from axial to radial, the pressure drop can be reduced tremendously. In this case the coolant flows from the outer reflector through the pebble bed and finally to flow paths in the inner reflector. As a consequence, the fuel temperatures are elevated due to the reduced heat transfer of the coolant. However, the power profile and pebble size in a radially cooled pebble bed reactor can be optimized to achieve lower fuel temperatures than current axially cooled designs, while the low pressure drop can be maintained. The radial power profile in the core can be altered by adopting multi-pass fuel management using several radial fuel zones in the core. The optimal power profile yielding a flat temperature profile is derived analytically and is approximated by radial fuel zoning. In this case, the pebbles pass through the outer region of the core first and each consecutive pass is located in a fuel zone closer to the inner reflector. Thereby, the resulting radial distribution of the fissile material in the core is influenced and the temperature profile is close to optimal. The fuel temperature in the pebbles can be further reduced by reducing the standard pebble diameter from 6 cm to a value as low as I cm. An analytical investigation is used to demonstrate the effects on the fuel temperature and pressure drop for both radial and axial cooling. Finally, two-dimensional numerical calculations were performed, using codes for neutronics, thermal-hydraulics and fuel depletion analysis, in order to validate the results for the optimized design that were obtained from the analytical investigations. It was found that for a radially cooled design with an optimized power profile and reduced pebble diameter (below 3.5 cm) both a reduction in the pressure drop (Δp = -2.6 bar), which increases the reactor efficiency with several percent, and a reduction in the maximum fuel temperature (ΔT = -50 deg. C) can be achieved

  15. Chemical looping reactor system design double loop circulating fluidized bed (DLCFB)

    Energy Technology Data Exchange (ETDEWEB)

    Bischi, Aldo

    2012-05-15

    Chemical looping combustion (CLC) is continuously gaining more importance among the carbon capture and storage (CCS) technologies. It is an unmixed combustion process which takes place in two steps. An effective way to realize CLC is to use two interconnected fluidized beds and a metallic powder circulating among them, acting as oxygen carrier. The metallic powder oxidizes at high temperature in one of the two reactors, the air reactor (AR). It reacts in a highly exothermic reaction with the oxygen of the injected fluidising air. Afterwards the particles are sent to the other reactor where the fuel is injected, the fuel reactor (FR). There, they transport heat and oxygen necessary for the reaction with the injected fuel to take place. At high temperatures, the particle's oxygen reacts with the fuel producing Co2 and steam, and the particles are ready to start the loop again. The overall reaction, the sum of the enthalpy changes of the oxygen carrier oxidation and reduction reactions, is the same as for the conventional combustion. Two are the key features, which make CLC promising both for costs and capture efficiency. First, the high inherent irreversibility of the conventional combustion is avoided because the energy is utilized stepwise. Second, the Co2 is intrinsically separated within the process; so there is in principle no need either of extra carbon capture devices or of expensive air separation units to produce oxygen for oxy-combustion. A lot of effort is taking place worldwide on the development of new chemical looping oxygen carrier particles, reactor systems and processes. The current work is focused on the reactor system: a new design is presented, for the construction of an atmospheric 150kWth prototype working with gaseous fuel and possibly with inexpensive oxygen carriers derived from industrial by-products or natural minerals. It consists of two circulating fluidized beds capable to operate in fast fluidization regime; this will increase the

  16. Packed- and fluidized-bed biofilm reactor performance for anaerobic wastewater treatment.

    Science.gov (United States)

    Denac, M; Dunn, I J

    1988-07-05

    Anaerobic degradation performance of a laboratory-scale packed-bed reactor (PBR) was compared with two fluidized-bed biofilm reactors (FBRs) on molasses and whey feeds. The reactors were operated under constant pH (7) and temperature (35 degrees C) conditions and were well mixed with high recirculation rates. The measured variables were chemical oxygen demand (COD), individual organic acids, gas composition, and gas rates. As carrier, sand of 0.3-0.5 mm diameter was used in the FBR, and porous clay spheres of 6 mm diameter were used in the PBR. Startup of the PBR was achieved with 1-5 day residence times. Start-up of the FBR was only successful if liquid residence times were held low at 2-3 h. COD degradations of 86% with molasses (90% was biodegradable) were reached in both the FBR and PBR at 6 h residence time and loadings of 10 g COD/L day. At higher loadings the FBR gave the best performance; even at 40-45 g COD/L day, with 6 h residence times, 70% COD was degraded. The PBR could not be operated above 20 g COD/L day without clogging. A comparison of the reaction rates show that the PBR and FBR per formed similarly at low concentrations in the reactors up to 1 g COD/L, while above 3 g COD/L the rates were 17.4 g COD/L day for the PBR and 38.4 g COD/L day for the FBR. This difference is probably due to diffusion limitations and a less active biomass content of the PBR compared with the fluidized bed.The results of dynamic step change experiments, in which residence times and feed concentrations were changed hanged at constant loading, demonstrated the rapid response of the reactors. Thus, the response times for an increase in gas rate or an increase in organic acids due to an increase in feed concentration were less than 1 day and could be explained by substrate limitation. Other slower responses were observed in which the reactor culture adapted over periods of 5-10 days; these were apparently growth related. An increase in loading of over 100% always resulted

  17. Study of the obtainment of Mo_2C by gas-solid reaction in a fixed and rotary bed reactor

    International Nuclear Information System (INIS)

    Araujo, C.P.B. de; Souza, C.P. de; Souto, M.V.M.; Barbosa, C.M.; Frota, A.V.V.M.

    2016-01-01

    Carbides' synthesis via gas-solid reaction overcomes many of the difficulties found in other processes, requiring lower temperatures and reaction times than traditional metallurgic routes, for example. In carbides' synthesis in fixed bed reactors (FB) the solid precursor is permeated by the reducing/carburizing gas stream forming a packed bed without mobility. The use of a rotary kiln reactor (RK) adds a mixing character to this process, changing its fluid-particle dynamics. In this work ammonium molybdate was subjected to carbo-reduction reaction (CH4 / H2) in both reactors under the same gas flow (15L / h) and temperature (660 ° C) for 180 minutes. Complete conversion was observed Mo2C (dp = 18.9nm modal particles sizes' distribution) in the fixed bed reactor. In the RK reactor this conversion was only partial (∼ 40%) and Mo2C and MoO3 (34nm dp = bimodal) could be observed on the produced XRD pattern. Partial conversion was attributed to the need to use higher solids loading in the reactor CR (50% higher) to avoid solids to centrifuge. (author)

  18. Impact on burnup performance of coated particle fuel design in pebble bed reactor with ROX fuel

    International Nuclear Information System (INIS)

    Ho, Hai Quan; Obara, Toru

    2015-01-01

    The pebble bed reactor (PBR), a kind of high-temperature gas-cooled reactor (HTGR), is expected to be among the next generation of nuclear reactors as it has excellent passive safety features, as well as online refueling and high thermal efficiency. Rock-like oxide (ROX) fuel has been studied at the Japan Atomic Energy Agency (JAEA) as a new once-through type fuel concept. Rock-like oxide used as fuel in a PBR can be expected to achieve high burnup and improve chemical stabilities. In the once-through fuel concept, the main challenge is to achieve as high a burnup as possible without failure of the spent fuel. The purpose of this study was to investigate the impact on burnup performance of different coated fuel particle (CFP) designs in a PBR with ROX fuel. In the study, the AGR-1 Coated Particle design and Deep-Burn Coated Particle design were used to make the burnup performance comparison. Criticality and core burnup calculations were performed by MCPBR code using the JENDL-4.0 library. Results at equilibrium showed that the two reactors utilizing AGR-1 Coated Particle and Deep-Burn Coated Particle designs could be critical with almost the same multiplication factor k eff . However, the power peaking factor and maximum power per fuel ball in the AGR-1 coated particle design was lower than that of Deep-Burn coated particle design. The AGR-1 design also showed an advantage in fissions per initial fissile atoms (FIFA); the AGR-1 coated particle design produced a higher FIFA than the Deep-Burn coated particle design. These results suggest that the difference in coated particle fuel design can have an effect on the burnup performance in ROX fuel. (author)

  19. Thermal and mechanical behaviour of oxygen carrier materials for chemical looping combustion in a packed bed reactor

    International Nuclear Information System (INIS)

    Jacobs, M.; Van Noyen, J.; Larring, Y.; Mccann, M.; Pishahang, M.; Amini, S.; Ortiz, M.; Galluci, F.; Sint-Annaland, M.V.; Tournigant, D.; Louradour, E.; Snijkers, F.

    2015-01-01

    Highlights: • Ilmenite-based oxygen carriers were developed for packed-bed chemical looping. • Addition of Mn_2O_3 increased mechanical strength and microstructure of the carriers. • Oxygen carriers were able to withstand creep and thermal cycling up to 1200 °C. • Ilmenite-based granules are a promising shape for packed-bed reactor conditions. - Abstract: Chemical looping combustion (CLC) is a promising carbon capture technology where cyclic reduction and oxidation of a metallic oxide, which acts as a solid oxygen carrier, takes place. With this system, direct contact between air and fuel can be avoided, and so, a concentrated CO_2 stream is generated after condensation of the water in the exit gas stream. An interesting reactor system for CLC is a packed bed reactor as it can have a higher efficiency compared to a fluidized bed concept, but it requires other types of oxygen carrier particles. The particles must be larger to avoid a large pressure drop in the reactor and they must be mechanically strong to withstand the severe reactor conditions. Therefore, oxygen carriers in the shape of granules and based on the mineral ilmenite were subjected to thermal cycling and creep tests. The mechanical strength of the granules before and after testing was investigated by crush tests. In addition, the microstructure of these oxygen particles was studied to understand the relationship between the physical properties and the mechanical performance. It was found that the granules are a promising shape for a packed bed reactor as no severe degradation in strength was noticed upon thermal cycling and creep testing. Especially, the addition of Mn_2O_3 to the ilmenite, which leads to the formation of an iron–manganese oxide, seems to results in stronger granules than the other ilmenite-based granules.

  20. Conceptual design of a passively safe thorium breeder Pebble Bed Reactor

    International Nuclear Information System (INIS)

    Wols, F.J.; Kloosterman, J.L.; Lathouwers, D.; Hagen, T.H.J.J. van der

    2015-01-01

    Highlights: • This work proposes three possible designs for a thorium Pebble Bed Reactor. • A high-conversion PBR (CR > 0.96), passively safe and within practical constraints. • A thorium breeder PBR (220 cm core) in practical regime, but not passively safe. • A passively safe breeder, requiring higher fuel reprocessing and recycling rates. - Abstract: More sustainable nuclear power generation might be achieved by combining the passive safety and high temperature applications of the Pebble Bed Reactor (PBR) design with the resource availability and favourable waste characteristics of the thorium fuel cycle. It has already been known that breeding can be achieved with the thorium fuel cycle inside a Pebble Bed Reactor if reprocessing is performed. This is also demonstrated in this work for a cylindrical core with a central driver zone, with 3 g heavy metal pebbles for enhanced fission, surrounded by a breeder zone containing 30 g thorium pebbles, for enhanced conversion. The main question of the present work is whether it is also possible to combine passive safety and breeding, within a practical operating regime, inside a thorium Pebble Bed Reactor. Therefore, the influence of several fuel design, core design and operational parameters upon the conversion ratio and passive safety is evaluated. A Depressurized Loss of Forced Cooling (DLOFC) is considered the worst safety scenario that can occur within a PBR. So, the response to a DLOFC with and without scram is evaluated for several breeder PBR designs using a coupled DALTON/THERMIX code scheme. With scram it is purely a heat transfer problem (THERMIX) demonstrating the decay heat removal capability of the design. In case control rods cannot be inserted, the temperature feedback of the core should also be able to counterbalance the reactivity insertion by the decaying xenon without fuel temperatures exceeding 1600 °C. Results show that high conversion ratios (CR > 0.96) and passive safety can be combined in

  1. Fundamental burn-up mode in a pebble-bed type reactor

    International Nuclear Information System (INIS)

    Chen, Xue-Nong; Kiefhaber, Edgar; Maschek, Werner

    2008-01-01

    This paper deals with a pebble-bed type reactor, in which the fuel is loaded from one side (top) and discharged from the other side (bottom). A boundary value problem of a single group diffusion equation coupled with simplified burn-up equations is studied, where the natural radioactive decay processes are neglected in the burn-up modelling. An asymptotic burning wave solution is found analytically in the one-dimensional case, which is called as fundamental burn-up mode. Among this solution family there are two particular cases, namely, a classic fundamental solution with a zero burn-up and a partial solitary burn-up wave solution with a highest burn-up. An example of Th-U conversion is considered and the solutions are presented in order to show the mechanism of the burning wave. (author)

  2. Preliminary neutronic study on Pu-based OTTO cycle pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Setiadipura, Topan; Zuhair [National Nuclear Energy Agency of Indonesia (BATAN), Selatan (Indonesia). Center for Nuclear Reactor Technology and Safety; Irwanto, Dwi [Bandung Institute of Technology (ITB), Bandung (Indonesia). Nuclear Physics and Biophysics Research Group

    2017-12-15

    The neutron physics characteristic of Pebble Bed Reactor (PBR) allows a better incineration of plutonium (Pu). An optimized design of simple PBR might give a symbiotic solution of providing a safe energy source, effective fuel utilization shown by a higher burnup value, and incineration of Pu stockpiles. This study perform a preliminary neutronic design study of a 200 MWt Once Through Then Out (OTTO) cycle PBR with Pu-based fuel. The safety criteria of the design were represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. In this preliminary phase, the parametric survey is limited to the heavy metal (HM) loading per pebble and the average axial speed of the fuel. An optimum high burnup of 419.7 MWd/kg-HM was achieved in this study. This optimum design uses a HM loading of 2.5 g/pebble with average axial fuel velocity 0.5 cm/day.

  3. Microbiological and chemical approaches to degradation of mecoprop in a Moving-Bed Biofilm-Reactor

    DEFF Research Database (Denmark)

    Escola, Monica; Tue Kjærgaard Nielsen, Tue; Hansen, Lars Hestbjerg

    Micro-pollutants are ubiquitous in wastewater effluents. Therefore, in-situ treatments of highly polluted water or polishing treatments after classical wastewater treatment have been proposed as a solution. Moving Bed Biofilm-Reactors (MBBRs) are a recent-developed biofilm technology for wastewater...... treatment. MBBRs consist incontain biofilms which are grown on small (1-4 cm diameter) plastic chips that are suspended and mixed in a water tank. These systems have been recognized as robust and versatile. Besides, biofilm systems fdescribe acilitatedemonstrate a clear, but slow, biodegradation of some...... recalcitrant compounds. For all these reasonsThus, MBBRs are pointed as a valuable tool for the elimination of micro-pollutants. Several studies have focused in on describing degradation processes in biofilm by quantifying the loss of micro-pollutants over time. This can be helpful foraid optimizing...

  4. Effect of packing fraction variations on reactivity in pebble-bed reactor

    International Nuclear Information System (INIS)

    Snoj, L.; Ravnik, M.

    2004-01-01

    The pebble-bed reactor (PBR) core consists of large number of randomly packed spherical fuel elements. The effect of fuel element packing density variations on multiplication factor in a typical PBR is studied using WIMS code. It is observed that at normal conditions the k-eff increases with packing fraction. Effects of secondary coolant ingress (water or molten lead) in the core at accidental conditions are studied at various packing densities. The effect of water ingress on reactivity depends strongly on water density and packing fraction and is prevailingly positive, while the lead ingress reduces multiplication factor regardless of lead effective density and packing fraction. Both effects are stronger at lower packing fractions. (author)

  5. Effect of fuel particles' size variations on multiplication factor in pebble-bed nuclear reactor

    International Nuclear Information System (INIS)

    Snoj, L.; Ravnik, M.

    2005-01-01

    The pebble-bed reactor (Pbr) spherical fuel element consists of two radial zones: the inner zone, in which the fissile material in form of the so-called TRISO particles is uniformly dispersed in graphite matrix and the outer zone, a shell of pure graphite. A TRISO particle is composed of a fissile kernel (UO 2 ) and several layers of carbon composites. The effect of TRISO particles' size variations and distance between them on PBR multiplication factor is studied using MCNP code. Fuel element is modelled in approximation of a cubical unit cell with periodic boundary condition. The multiplication factor of the fuel element depends on the size of the TRISO particles due to resonance self-shielding effect and on the inter-particle distance due to inter-kernel shadowing. (author)

  6. Catalytic performance improvement of styrene hydrogenation in trickle bed reactor by using periodic operation

    International Nuclear Information System (INIS)

    Wongkia, Atittahn; Praserthdam, Piyasan; Assabumrungrat, Suttichai; Suriye, Kongkiat; Nonkhamwong, Anuwat

    2013-01-01

    We investigated the catalytic performance improvement of styrene hydrogenation in a trickle bed reactor by using periodic operation. The effects of cycle period and split on relative conversion, which is defined as styrene conversion obtained from periodic operation over that from steady state operation, were examined at various operating conditions including gas and average liquid flow rates, pressure and temperature. The experimental results reveal that both cycle period and split have strong influence on the catalytic performance. The fast mode (short cycle period) is a favorable condition. The improvement by the periodic operation becomes less pronounced for operations at high average liquid flow rate, pressure and temperature. From this study, a maximum improvement of styrene conversion of 18% is observed

  7. Deuterium exchange between hydrogen and water in a trickle bed reactor

    International Nuclear Information System (INIS)

    Enright, J.T.; Chuang, T.T.

    1978-01-01

    The catalyzed exchange of deuterium between hydrogen and liquid water has been studied as the basis for a heavy water production process. Platinum catalyst which had been waterproofed with Teflon was tested in a 0.2 m diameter trickle bed reactor at pressures and temperatures up to 6 MPa and 440 K. Extensive experimental data were used to test a model of the system which was developed from fundamental principles. It was found that mass transfer plays a very important role in the overall exchange and the conventional theory of vapour/liquid mass transfer does not adequately describe the absorption process. Modelling of the data has resulted in the postulation of a second method of mass transfer whereby HDO transfers directly from the catalyst to the bulk liquid phase. (author)

  8. Catalytic performance improvement of styrene hydrogenation in trickle bed reactor by using periodic operation

    Energy Technology Data Exchange (ETDEWEB)

    Wongkia, Atittahn; Praserthdam, Piyasan; Assabumrungrat, Suttichai [Chulalongkorn University, Bangkok (Thailand); Suriye, Kongkiat; Nonkhamwong, Anuwat [SCG Chemicals Co. Ltd., Bangkok (Thailand)

    2013-03-15

    We investigated the catalytic performance improvement of styrene hydrogenation in a trickle bed reactor by using periodic operation. The effects of cycle period and split on relative conversion, which is defined as styrene conversion obtained from periodic operation over that from steady state operation, were examined at various operating conditions including gas and average liquid flow rates, pressure and temperature. The experimental results reveal that both cycle period and split have strong influence on the catalytic performance. The fast mode (short cycle period) is a favorable condition. The improvement by the periodic operation becomes less pronounced for operations at high average liquid flow rate, pressure and temperature. From this study, a maximum improvement of styrene conversion of 18% is observed.

  9. Yield optimization in a cycled trickle-bed reactor: ethanol catalytic oxidation as a case study

    Energy Technology Data Exchange (ETDEWEB)

    Ayude, A.; Haure, P. [INTEMA, CONICET, Mar del Plata (Argentina); Cassanello, M. [Universidad de Buenos Aires, PINMATE, Departamento de Industrias, FCEyN, Buenos Aires (Argentina); Martinez, O. [Departamento de Ingenieria Quimica, FI-UNLP-CINDECA, La Plata (Argentina)

    2012-05-15

    The effect of slow ON-OFF liquid flow modulation on the yield of consecutive reactions is investigated for oxidation of aqueous ethanol solutions using a 0.5 % Pd/Al{sub 2}O{sub 3} commercial catalyst in a laboratory trickle-bed reactor. Experiments with modulated liquid flow rate (MLFR) were performed under the same hydrodynamic conditions (degree of wetting, liquid holdup) as experiments with constant liquid flow rate (CLFR). Thus, the impact of the duration of wet and dry cycles as well as the period can be independently investigated. Depending on cycling conditions, acetaldehyde or acetic acid production is favored with MLFR compared to CLFR. Results suggest both the opportunity and challenge of finding a way to tune the cycling parameters for producing the most appropriate product. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. Reactivity of coal chars prepared in a fluidised bed reactor at different burn-off degrees

    Energy Technology Data Exchange (ETDEWEB)

    Moreno, A.H.; Arenillas, A.; Rubiera, F.; Fuente, E.; Pis, J.J. [Inst. Nacional del Carbon, Oviedo (Spain)

    1997-12-31

    The main goal of this work has been to study the effect of the textural properties of coal chars, obtained from partially burned coal, on their reactivity to oxygen. A low volatile bituminous coal was used to prepare chars, with different levels of burn-off, in a bench-scale fluidised bed reactor. Textural characterisation of the samples was accomplished by measuring true (helium) and apparent (mercury) densities, and mercury porosimetry. An increase in the burn-off degree gave rise to a densification of the chars. Porosity development greatly changed during progressive burning of the samples. DTG burning profiles and isothermal gasification were utilised to estimate the reactivities of the precursor coal and its partially burned chars. Reactivity reached a maximum value at an intermediate burn-off and strongly decreased at higher burn-off degrees. (orig.)

  11. Preliminary analysis on in-core fuel management optimization of molten salt pebble-bed reactor

    International Nuclear Information System (INIS)

    Xia Bing; Jing Xingqing; Xu Xiaolin; Lv Yingzhong

    2013-01-01

    The Nuclear Hot Spring (NHS) is a molten salt pebble-bed reactor featured by full power natural circulation. The unique horizontal coolant flow of the NHS demands the fuel recycling schemes based on radial zoning refueling and the corresponding method of fuel management optimization. The local searching algorithm (LSA) and the simulated annealing algorithm (SAA), the stochastic optimization methods widely used in the refueling optimization problems in LWRs, were applied to the analysis of refueling optimization of the NHS. The analysis results indicate that, compared with the LSA, the SAA can survive the traps of local optimized solutions and reach the global optimized solution, and the quality of optimization of the SAA is independent of the choice of the initial solution. The optimization result gives excellent effects on the in-core power flattening and the suppression of fuel center temperature. For the one-dimensional zoning refueling schemes of the NHS, the SAA is an appropriate optimization method. (authors)

  12. Kinetics study of the fluorination of uranium tetrafluoride in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Khani, M.H.; Pahlavanzadeh, H.; Ghannadi, M.

    2008-01-01

    The kinetics of reaction of the uranium tetrafluoride conversion to the uranium hexafluoride with fluorine gas taking place in a fluidized bed reactor operating in industrial conditions have been studied. The external and internal diffusion effects are investigated by Mears and Weisz-Prater criterions. The kinetic equation for the fluorination of uranium tetrafluoride is developed in the absence of diffusional limitation using an integral method by assuming that the gas flow is of plug or perfectly mixed type. A good agreement is observed between the experimental data and a first-order model with respect to fluorine in the CSTR system. The activation energy of the reaction and the pre-exponential factor are obtained using analytical results from a better model

  13. A fluidized bed membrane bioelectrochemical reactor for energy-efficient wastewater treatment.

    Science.gov (United States)

    Li, Jian; Ge, Zheng; He, Zhen

    2014-09-01

    A fluidized bed membrane bioelectrochemical reactor (MBER) was investigated using fluidized granular activated carbon (GAC) as a mean of membrane fouling control. During the 150-day operation, the MBER generated electricity with contaminant removal from either synthetic solution or actual wastewater, as a standalone or a coupled system. It was found that fluidized GAC could significantly reduce transmembrane pressure (TMP), although its function as a part of the anode electrode was minor. When the MBER was linked to a regular microbial fuel cell (MFC) for treating a wastewater from a cheese factory, the MFC acted as a major process for energy recovery and contaminant removal, and the coupled system removed more than 90% of chemical oxygen demand and >80% of suspended solids. The analysis showed that the ratio of energy recovery and consumption was slightly larger than one, indicating that the coupled system could be theoretically energy neutral. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Hydropyrolysis of extracted Euphorbia rigida in a well-swept fixed-bed tubular reactor

    Energy Technology Data Exchange (ETDEWEB)

    Gercel, H.F.; Putun, A.E.; Putun, E.

    2002-05-01

    Tubular reactor fixed-bed hydropyrolysis experiments have been conducted on a sample of extracted Euphorbia rigida to determine the possibility of being a potential source of renewable fuels and chemical feedstock. The effects of hydropyrolysis temperature and heating rate on the hydropyrolysis yields and chemical compositions have been investigated. The maximum bio-oil yield of 39.8 wt% was obtained in H{sub 2} atmosphere at a hydrogen pressure of 150 bar, a hydrogen flow rate of 5 dm{sup 3} min{sup -} {sup 1}, a hydropyrolysis temperature of 550{sup o}C, and a heating rate of 100{sup o}C min{sup -1}. Then this bio-oil was characterized by elemental analysis and {sup 1}H nuclear magnetic resonance (NMR) techniques. (author)

  15. Attached biomass growth and substrate utilization rate in a moving bed biofilm reactor

    Directory of Open Access Journals (Sweden)

    J. J. Marques

    2008-12-01

    Full Text Available A moving bed bioreactor containing cubes of polyether foam immersed in a synthetic wastewater (an aqueous mixture of meat extract, yeast extract, dextrose, meat peptone, ammonium chloride, potassium chloride, sodium chloride, sodium bicarbonate, potassium mono-hydrogen-phosphate and magnesium sulphate was used to evaluate bacterial growth and biomass yield parameters based on Monod's equation. The wastewater was supplied in the bottom of the equipment flowing ascending in parallel with a diffused air current that provided the mixing of the reactor content. Suspended and attached biomass concentration was measured through gravimetric methods. Good agreement was found between experimental kinetic parameters values and those obtained by other researchers. The only significant difference was the high global biomass content about 2 times the values obtained in conventional processes, providing high performance with volumetric loading rates up to 5.5 kg COD/m³/d.

  16. Investigation of the Time Evolution and Species Production in a 2-Dimensional Packed Bed Reactor

    Science.gov (United States)

    Engeling, Kenneth; Kruszelnicki, Juliusz; Kushner, Mark; Foster, John

    2016-09-01

    Plasma production in microporous media has potential to enable a number of technologies ranging from flameless combustion to environmental hazard mitigation addressing air borne pollutants. Packed bed reactors (PBRs) is one such technology that relies on plasma production in microporous media. The physics of plasma production and transport in such media however remains poorly understood. In order to better understand the plasma propagation and plasma driven chemical reaction within microporous media, absorption spectroscopy and time-resolved imaging diagnostics are being utilized. We report on plasma driven species formation and plasma discharge spatial structure and evolution characteristics found in the 2-dimensional representation of a PBR. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  17. A unique nuclear thermal rocket engine using a particle bed reactor

    Science.gov (United States)

    Culver, Donald W.; Dahl, Wayne B.; McIlwain, Melvin C.

    1992-01-01

    Aerojet Propulsion Division (APD) studied 75-klb thrust Nuclear Thermal Rocket Engines (NTRE) with particle bed reactors (PBR) for application to NASA's manned Mars mission and prepared a conceptual design description of a unique engine that best satisfied mission-defined propulsion requirements and customer criteria. This paper describes the selection of a sprint-type Mars transfer mission and its impact on propulsion system design and operation. It shows how our NTRE concept was developed from this information. The resulting, unusual engine design is short, lightweight, and capable of high specific impulse operation, all factors that decrease Earth to orbit launch costs. Many unusual features of the NTRE are discussed, including nozzle area ratio variation and nozzle closure for closed loop after cooling. Mission performance calculations reveal that other well known engine options do not support this mission.

  18. Inulinase production in a packed bed reactor by solid state fermentation.

    Science.gov (United States)

    Dilipkumar, M; Rajamohan, N; Rajasimman, M

    2013-07-01

    In this work, production of inulinase was carried out in a packed bed reactor (PBR) under solid state fermentation. Kluyveromyces marxianus var. marxianus was used to produce the inulinase using pressmud as substrate. The parameters like air flow rate, packing density and particle size were optimized using response surface methodology (RSM) to maximize the inulinase production. The optimum conditions for the maximum inulinase production were: air flow rate - 0.82 L/min, packing density - 40 g/L and particle size - 0.0044 mm (mesh - 14/20). At these optimized conditions, the production of inulinase was found to be 300.5 unit/gram of dry substrate (U/gds). Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. High-rate wastewater treatment combining a moving bed biofilm reactor and enhanced particle separation.

    Science.gov (United States)

    Helness, H; Melin, E; Ulgenes, Y; Järvinen, P; Rasmussen, V; Odegaard, H

    2005-01-01

    Many cities around the world are looking for compact wastewater treatment alternatives since space for treatment plants is becoming scarce. In this paper development of a new compact, high-rate treatment concept with results from experiments in lab-scale and pilot-scale are presented. The idea behind the treatment concept is that coagulation/floc separation may be used to separate suspended and colloidal matter (resulting in > 70% organic matter removal in normal wastewater) while a high-rate biofilm process (based on Moving Bed biofilm reactors) may be used for removing low molecular weight, easily biodegradable, soluble organic matter. By using flotation for floc/biomass separation, the total residence time for a plant according to this concept will normally be treatment) and sufficient P-removal.

  20. Fluidized bed bio reactor sewage treatment system and wastewater quality at Kudankulam

    International Nuclear Information System (INIS)

    Vijayakumar, B.; George, Thomas; Rajan, P.S.; Kumar, M.; Rajan, M.P.

    2006-01-01

    With the availability of fresh water becoming exiguous in certain coastal belts, it has become imperative to manage water resources in a resourceful and judicious manner. The focus has also shifted to minimum or zero tolerance from existing waste treatment plants so as not to contaminate or pollute the already shrinking drinking water resources. Many of the modern waste treatment approaches are already aiming at zero discharge with a view to conserving the ecological balance and to protect the rich bio diversity, flora and fauna. This paper describes one such domestic sewage treatment system called fluidized bed bio reactor operating in the residential colony and plant site area of Kudankulam Nuclear Power Project. Wastewater quality of the resulting effluent water is also discussed. (author)

  1. Process integration for biological sulfate reduction in a carbon monoxide fed packed bed reactor.

    Science.gov (United States)

    Kumar, Manoj; Sinharoy, Arindam; Pakshirajan, Kannan

    2018-05-09

    This study examined immobilized anaerobic biomass for sulfate reduction using carbon monoxide (CO) as the sole carbon source under batch and continuous fed conditions. The immobilized bacteria with beads made of 10% polyvinyl alcohol (PVA) showed best results in terms of sulfate reduction (84 ± 3.52%) and CO utilization (98 ± 1.67%). The effect of hydraulic retention time (HRT), sulfate loading rate and CO loading rate on sulfate and CO removal was investigated employing a 1L packed bed bioreactor containing the immobilized biomass. At 48, 24 and 12 h HRT, the sulfate removal was 94.42 ± 0.15%, 89.75 ± 0.47% and 61.08 ± 0.34%, respectively, along with a CO utilization of more than 90%. The analysis of variance (ANOVA) of the results obtained showed that only the initial CO concentration significantly affected the sulfate reduction process. The reactor effluent sulfate concentrations were 27.41 ± 0.44, 59.16 ± 1.08, 315.83 ± 7.33 mg/L for 250, 500 and 1000 mg/L of influent sulfate concentrations respectively, under the optimum operating conditions. The sulfate reduction rates matched well with low inlet sulfate loading rates, indicating stable performance of the bioreactor system. Overall, this study yielded very high sulfate reduction efficiency by the immobilized anaerobic biomass under high CO loading condition using the packed bed reactor system. Copyright © 2018 Elsevier Ltd. All rights reserved.

  2. A novel approach for harnessing biofilm communities in moving bed biofilm reactors for industrial wastewater treatment

    Directory of Open Access Journals (Sweden)

    Joe A. Lemire

    2015-10-01

    Full Text Available Moving bed biofilm reactors (MBBRs are an effective biotechnology for treating industrial wastewater. Biomass retention on moving bed biofilm reactor (MBBR carriers (biofilm support materials, allows for the ease-of-operation and high treatment capacity of MBBR systems. Optimization of MBBR systems has largely focused on aspects of carrier design, while little attention has been paid to enhancing strategies for harnessing microbial biomass. Previously, our research group demonstrated that mixed-species biofilms can be harvested from an industrial wastewater inoculum [oil sands process water (OSPW] using the Calgary Biofilm Device (CBD. Moreover, the resultant biofilm communities had the capacity to degrade organic toxins (naphthenic acids—NAs that are found in OSPW. Therefore, we hypothesized that harnessing microbial communities from industrial wastewater, as biofilms, on MBBR carriers may be an effective method to bioremediate industrial wastewater.Here, we detail our methodology adapting the workflow employed for using the CBD, to generate inoculant carriers to seed an MBBR.In this study, OSPW-derived biofilm communities were successfully grown, and their efficacy evaluated, on commercially available MBBR carriers affixed within a modified CBD system. The resultant biofilms demonstrated the capacity to transfer biomass to recipient carriers within a scaled MBBR. Moreover, MBBR systems inoculated in this manner were fully active 2 days post-inoculation, and readily degraded a select population of NAs. Together, these findings suggest that harnessing microbial communities on carriers affixed within a modified CBD system may represent a facile and rapid method for obtaining functional inoculants for use in wastewater MBBR treatment systems.

  3. Fast oxidative pyrolysis of sugar cane straw in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Mesa-Pérez, Juan Miguel; Rocha, José Dilcio; Barbosa-Cortez, Luis Augusto; Penedo-Medina, Margarita; Luengo, Carlos Alberto; Cascarosa, Esther

    2013-01-01

    This study focuses on the technical viability evaluation of the fast pyrolysis of sugar cane straw for its energy use. By means of this thermochemical process, the sugar cane straw is converted into bio-fuels (biochar, bio-oil) and non-condensable gases. The bio-fuels obtained could be used as fuel or as raw material in the chemical industry. The fast pyrolysis of sugar cane straw has been developed in a fluidized bed reactor. In order to improve this process to obtain high bio-oil yield, the influence of the operational conditions (equivalence ratio and temperature) on the product yields and on their characteristics was evaluated. The product yields of bio-oil and char were up to 35.5 wt.% and 48.2 wt.% respectively. The maximum bio-oil yield was achieved at temperature and equivalence ratio conditions of 470 °C and 0.14. The bio-oil obtained has low oxygen content (38.48 wt.% dry basis), very low water content, and a lower heating value of 22.95 MJ/kg. The gas chromatographic analyses allowed the identification of oxygenated compounds and heterocyclic aromatic hydrocarbons. The bio-oil pH ranged between 3.14 and 3.57 due to the presence of acid organic compounds. The char obtained has a high fixed carbon and volatile matter content. Its HHV value is 13.54 MJ/kg. -- Highlights: • Pyrolysis of sugar cane straw was studied in a fluidized bed reactor. • The product yields were evaluated. • The composition of the liquid and solid products obtained was analyzed. • This is an environmentally friendly use for this waste

  4. Development of Monte Carlo-based pebble bed reactor fuel management code

    International Nuclear Information System (INIS)

    Setiadipura, Topan; Obara, Toru

    2014-01-01

    Highlights: • A new Monte Carlo-based fuel management code for OTTO cycle pebble bed reactor was developed. • The double-heterogeneity was modeled using statistical method in MVP-BURN code. • The code can perform analysis of equilibrium and non-equilibrium phase. • Code-to-code comparisons for Once-Through-Then-Out case were investigated. • Ability of the code to accommodate the void cavity was confirmed. - Abstract: A fuel management code for pebble bed reactors (PBRs) based on the Monte Carlo method has been developed in this study. The code, named Monte Carlo burnup analysis code for PBR (MCPBR), enables a simulation of the Once-Through-Then-Out (OTTO) cycle of a PBR from the running-in phase to the equilibrium condition. In MCPBR, a burnup calculation based on a continuous-energy Monte Carlo code, MVP-BURN, is coupled with an additional utility code to be able to simulate the OTTO cycle of PBR. MCPBR has several advantages in modeling PBRs, namely its Monte Carlo neutron transport modeling, its capability of explicitly modeling the double heterogeneity of the PBR core, and its ability to model different axial fuel speeds in the PBR core. Analysis at the equilibrium condition of the simplified PBR was used as the validation test of MCPBR. The calculation results of the code were compared with the results of diffusion-based fuel management PBR codes, namely the VSOP and PEBBED codes. Using JENDL-4.0 nuclide library, MCPBR gave a 4.15% and 3.32% lower k eff value compared to VSOP and PEBBED, respectively. While using JENDL-3.3, MCPBR gave a 2.22% and 3.11% higher k eff value compared to VSOP and PEBBED, respectively. The ability of MCPBR to analyze neutron transport in the top void of the PBR core and its effects was also confirmed

  5. Evaluation of the properties of tyre pyrolysis oils obtained in a conical spouted bed reactor

    International Nuclear Information System (INIS)

    Alvarez, J.; Lopez, G.; Amutio, M.; Mkhize, N.M.; Danon, B.; Gryp, P. van der; Görgens, J.F.; Bilbao, J.; Olazar, M.

    2017-01-01

    Waste truck tyre valorization by fast pyrolysis has been performed in a conical spouted bed reactor in the 425–575 °C range. The tyre pyrolysis oil (TPO) yield was found to decrease with increasing temperature whilst the yield of gas increased. The effect of temperature on TPO properties has been studied in order to establish the best possible valorization route. FTIR and chromatographic analysis revealed the presence of some undesired compounds with sulphur, nitrogen or oxygen functionalities (benzotiatholes, nitriles and carboxylic acids amongst others) and an increase of TPO aromaticity with increasing temperature. The carbon and sulphur content and the heating value of the TPO increased with temperature. The simulated distillation showed that approximately 70% of the TPOs produced at 425 and 475 °C correspond to diesel range, whereas that TPO obtained at 575 °C is between diesel and gasoline range. The properties of the TPOs evidenced their potential to substitute conventional fuels. However, some of them need to be improved, i.e., by reduction of the sulphur, nitrogen and aromatic content. Additionally, the TPO obtained at 425 and 475 °C could be an important source of limonene and that at 575 °C of xylenes, although current removal methods present some limitations. - Highlights: • The conical spouted bed reactor is suitable for truck tyre fast pyrolysis. • The highest oil yields are attained between 425 and 475 °C (≈58 wt %). • Tyre oil is a mixture of water, aromatic, aliphatic and heteroaromatic compounds. • Limonene is the major compound with a maximum yield of 13.30 wt % at 475 °C. • 425 and 475 °C oils share similarities with diesel and 575 °C one with gasoline.

  6. Synthesis of Biodiesel in Batch and Packed-Bed Reactors Using Powdered and Granular Sugar Catalyst

    Science.gov (United States)

    Janaun, J.; Lim, P. M.; Balan, W. S.; Yaser, A. Z.; Chong, K. P.

    2017-06-01

    Increasing world production of palm oil warrants effective utilization of its waste. In particular, conversion of waste cooking oil into biodiesel has obtained global interest because of renewable energy need and reduction of CO2 emission. In this study, oleic acid used as a model compound for waste cooking oil conversion using esterification reaction catalysed by sugar catalyst (SC) in powdered (P-SC) and granular (G-SC) forms. The catalysts were synthesized via incomplete carbonization of D-glucose followed by functionalization with concentrated sulphuric acid. Catalysts characterizations were done for their physical and chemical properties using modern tools. Batch and packed-bed reactor systems were used to evaluate the reactivity of the catalysts. The results showed that G-SC had slightly higher total acidity and more porous than P-SC. The experimental conditions for batch reaction were temperature of 60°C, molar ratio of 1:20 (Oleic Acid:Methanol) and 2 wt. catalyst with respect to oleic acid. The results showed the maximum oleic acid conversion using G-SC and P-SC were 52 and 48, respectively. Whereas, the continuous reaction with varying feed flow rate as a function of retention time was studied by using 3 g of P-SC in 60 °C and 1:20 molar ratio in a packed-bed reactor. The results showed that a longer retention time which was 6.48 min and feed flow rate 1.38 ml/min, achieved higher average conversion of 9.9 and decreased with further increasing flow rate. G-SC showed a better average conversion of 10.8 at lowest feed flow rate of 1.38 ml/min in continuous reaction experiments. In a broader perspective, large scale continuous biodiesel production is feasible using granular over powdered catalyst mainly due to it lower pressure drop.

  7. Local liquid velocity measurement of Trickle Bed Reactor using Digital Industrial X-ray Radiography

    Science.gov (United States)

    Mohd Salleh, Khairul Anuar

    Trickle Bed Reactors (TBRs) are fixed beds of particles in which both liquid and gas flow concurrently downward. They are widely used to produce not only fuels but also lubrication products. The measurement and the knowledge of local liquid velocities (VLL) in TBRs is less which is essential for advancing the understanding of its hydrodynamics and for validation computational fluid dynamics (CFD). Therefore, this work focused on developing a new, non-invasive, statistically reliable technique that can be used to measure local liquid velocity (VLL) in two-dimensions (2-D). This is performed by combining Digital Industrial X-ray Radiography (DIR) and Particle Tracking Velocimetry (PTV) techniques. This work also make possible the development of three-dimensional (3-D) VLL measurements that can be taken in TBRs. Measurements taken through both the combined and the novel technique, once validated, were found to be comparable to another technique (a two-point fiber optical probe) currently being developed at Missouri University of Science and Technology. The results from this study indicate that, for a gas-liquid-solid type bed, the measured VLL can have a maximum range that is between 35 and 51 times that of its superficial liquid velocity (VSL). Without the existence of gas, the measured VLL can have a maximum range that is between 4 and 4.7 times that of its VSL. At a higher V SL, the particle tracer was greatly distributed and became carried away by a high liquid flow rate. Neither the variance nor the range of measured VLL varied for any of the replications, confirming the reproducibility of the experimental measurements used, regardless of the VSL . The liquid's movement inside the pore was consistent with findings from previous studies that used various techniques.

  8. Phenols removal using ozonation-adsorption with granular activated carbon (GAC) in rotating packed bed reactor

    Science.gov (United States)

    Karamah, E. F.; Leonita, S.; Bismo, S.

    2018-01-01

    Synthetic wastewater containing phenols was treated using combination method of ozonation-adsorption with GAC (Granular Activated Carbon) in a packed bed rotating reactor. Ozone reacts quickly with phenol and activated carbon increases the oxidation process by producing hydroxyl radicals. Performance parameters evaluated are phenol removal percentage, the quantity of hydroxyl radical formed, changes in pH and ozone utilization, dissolved ozone concentration and ozone concentration in off gas. The performance of the combination method was compared with single ozonation and single adsorption. The influence of GAC dose and initial pH of phenols were evaluated in ozonation-adsorption method. The results show that ozonation-adsorption method generates more OH radicals than a single ozonation. Quantity of OH radical formation increases with increasing pH and quantity of the GAC. The combination method prove better performance in removing phenols. At the same operation condition, ozonation-adsorption method is capable of removing of 78.62% phenols as compared with single ozonation (53.15%) and single adsorption (36.67%). The increasing percentage of phenol removal in ozonation-adsorption method is proportional to the addition of GAC dose, solution pH, and packed bed rotator speed. Maximum percentage of phenol removal is obtained under alkaline conditions (pH 10) and 125 g of GAC

  9. Artificial neural network based modelling approach for municipal solid waste gasification in a fluidized bed reactor.

    Science.gov (United States)

    Pandey, Daya Shankar; Das, Saptarshi; Pan, Indranil; Leahy, James J; Kwapinski, Witold

    2016-12-01

    In this paper, multi-layer feed forward neural networks are used to predict the lower heating value of gas (LHV), lower heating value of gasification products including tars and entrained char (LHV p ) and syngas yield during gasification of municipal solid waste (MSW) during gasification in a fluidized bed reactor. These artificial neural networks (ANNs) with different architectures are trained using the Levenberg-Marquardt (LM) back-propagation algorithm and a cross validation is also performed to ensure that the results generalise to other unseen datasets. A rigorous study is carried out on optimally choosing the number of hidden layers, number of neurons in the hidden layer and activation function in a network using multiple Monte Carlo runs. Nine input and three output parameters are used to train and test various neural network architectures in both multiple output and single output prediction paradigms using the available experimental datasets. The model selection procedure is carried out to ascertain the best network architecture in terms of predictive accuracy. The simulation results show that the ANN based methodology is a viable alternative which can be used to predict the performance of a fluidized bed gasifier. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Computational simulation of the biomass gasification process in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Rojas Mazaira, Leorlen Y.; Gamez Rodriguez, Abel; Andrade Gregori, Maria Dolores; Armas Cardona, Raul

    2009-01-01

    In an agro-industrial country as Cuba many residues of cultivation like the rice and the cane of sugar take place, besides the forest residues in wooded extensions. Is an interesting application for all this biomass, the gasification technology, by its high efficiency and its positive environmental impact. The computer simulation appears like a useful tool in the researches of parameters of operation of a gas- emitting, because it reduces the number of experiments to realise and the cost of the researches. In the work the importance of the application of the computer simulation is emphasized to anticipate the hydrodynamic behavior of fluidized bed and of the process of combustion of the biomass for different residues and different conditions of operation. A model using CFD for the simulation of the process of combustion in a gas- emitting of biomass sets out of fluidized bed, the hydrodynamic parameters of the multiphasic flow from the elaboration of a computer simulator that allows to form and to vary the geometry of the reactor, as well as the influence of the variation of magnitudes are characterized such as: speed, diameter of the sand and equivalent reason. Experimental results in cylindrical channels appear, to complete the study of the computer simulation realised in 2D. (author)

  11. Fuel Design for Particle-Bed Reactors for Thermal Propulsion Applications

    Science.gov (United States)

    Husser, Dewayne L.; Evans, Robert S.; Jensen, Russell R.; Kerr, John M.

    1994-07-01

    The design of particle bed reactor (PBR) fuels is an iterative process involving close coordination of design and manufacturing operations. The process starts with the generation of an initial particle design, based on a knowledge of the system requirements and interfaces (such as, fissile loading requirements, coolant type, exit gas temperatures, operation time, number of cycles, contacting materials, etc.). The designer must consider materials property data, heat-transfer and thermal-hydraulic characteristics of the particle and particle bed, and available (or anticipated) manufacturing technology. The design process also uses parametric studies to identify the influences of composition, size, and coating thickness on fuel performance. This resulting design is then used to provide a target manufacturing specification against which initial manufacturing development can be assessed and which provides the framework for manufacturing and testing derived feedback that can be incorporated into the subsequent particle design modifications. In this paper, an example of this design process for a hypothetical particle using a (U,Zr)C kernel and a NbC outer coating designed for a thermal propulsion application is given.

  12. Simulation in CFD of a Pebble Bed: Advanced high temperature reactor core using OpenFOAM

    International Nuclear Information System (INIS)

    Dahl, Pamela M.; Su, Jian

    2017-01-01

    Numerical simulations of a Pebble Bed nuclear reactor core are presented using the multi-physics tool-kit OpenFOAM. The HTR-PM is modeled using the porous media approach, accounting both for viscous and inertial effects through the Darcy and Forchheimer model. Initially, cylindrical 2D and 3D simulations are compared, in order to evaluate their differences and decide if the 2D simulations carry enough of the sought information, considering the savings in computational costs. The porous medium is considered to be isotropic, with the whole length of the packed bed occupied homogeneously with the spherical fuel elements. Steady-state simulations for normal equilibrium operation are performed, using a semi sine function of the power density along the vertical axis as the source term for the energy balance equation.Total pressure drop is calculated and compared with that obtained from literature for a similar case. At a second stage, transient simulations are performed, where relevant parameters are calculated and compared to those of the literature. (author)

  13. Simulation in CFD of a Pebble Bed: Advanced high temperature reactor core using OpenFOAM

    Energy Technology Data Exchange (ETDEWEB)

    Dahl, Pamela M.; Su, Jian, E-mail: sujian@nuclear.ufrj.br [Coordenacao de Pos-Graduacao e Pesquisa de Engenharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear

    2017-07-01

    Numerical simulations of a Pebble Bed nuclear reactor core are presented using the multi-physics tool-kit OpenFOAM. The HTR-PM is modeled using the porous media approach, accounting both for viscous and inertial effects through the Darcy and Forchheimer model. Initially, cylindrical 2D and 3D simulations are compared, in order to evaluate their differences and decide if the 2D simulations carry enough of the sought information, considering the savings in computational costs. The porous medium is considered to be isotropic, with the whole length of the packed bed occupied homogeneously with the spherical fuel elements. Steady-state simulations for normal equilibrium operation are performed, using a semi sine function of the power density along the vertical axis as the source term for the energy balance equation.Total pressure drop is calculated and compared with that obtained from literature for a similar case. At a second stage, transient simulations are performed, where relevant parameters are calculated and compared to those of the literature. (author)

  14. Biological biogas upgrading capacity of a hydrogenotrophic community in a trickle-bed reactor

    International Nuclear Information System (INIS)

    Rachbauer, Lydia; Voitl, Gregor; Bochmann, Günther; Fuchs, Werner

    2016-01-01

    Highlights: • Data on long term operation of a system supplied with real biogas are presented. • Ex-situ biological methanation is feasible for biogas upgrading. • Gas quality obtained complies with strictest direct grid injection criteria. • Biomethane can act as flexible storage for renewable surplus electricity. - Abstract: The current study reports on biological biogas upgrading by means of hydrogen addition to obtain biomethane. A mesophilic (37 °C) 0.058 m"3 trickle-bed reactor with an immobilized hydrogenotrophic enrichment culture was operated for a period of 8 months using a substrate mix of molecular hydrogen (H_2) and biogas (36–42% CO_2). Complete CO_2 conversion (> 96%) was achieved up to a H_2 loading rate of 6.5 m_n"3 H_2/m"3_r_e_a_c_t_o_r _v_o_l_. × d, corresponding to 2.3 h gas retention time. The optimum H_2/CO_2 ratio was determined to be between 3.67 and 4.15. CH_4 concentrations above 96% were achieved with less than 0.1% residual H_2. This gas quality complies even with tightest standards for grid injection without the need for additional CO_2 removal. If less rigid standards must be fulfilled H_2 loading rates can be almost doubled (10.95 versus 6.5 m_n"3 H_2/m"3_r_e_a_c_t_o_r _v_o_l_. × d) making the process even more attractive. At this H_2 loading the achieved methane productivity was 2.52 m_n"3 CH_4/m"3_r_e_a_c_t_o_r _v_o_l_. × d. In terms of biogas this corresponds to an upgrading capacity of 6.9 m_n"3 biogas/m"3_r_e_a_c_t_o_r _v_o_l_. × d. The conducted experiments demonstrate that biological methanation in an external reactor is well feasible for biogas upgrading under the prerequisite that an adequate H_2 source is available.

  15. Heat-transfer characteristics of flowing and stationary particle-bed-type fusion-reactor blankets

    International Nuclear Information System (INIS)

    Nietert, R.E.

    1983-02-01

    The following five appendices are included: (1) physical properties of materials, (2) thermal entrance length Nusselt number variations, (3) stationary particle bed temperature variations, (4) falling bed experimental data and calculations, and (5) stationary bed experimental data and calculations

  16. Modeling the competitive effect of ammonium oxidizers and heterotrophs on the degradation of MTBE in a packed bed reactor

    DEFF Research Database (Denmark)

    Waul, Christopher Kevin; Arvin, Erik; Schmidt, Jens Ejbye

    2008-01-01

    A mathematical model was used to study effects on the degradation of methyl tert-butyl ether (MTBE) in a packed bed reactor due to the presence of contaminants such as ammonium, and the mix of benzene, toluene, ethylbenzene and xylenes (BTEX). It was shown that competition between the slower...

  17. Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

    Science.gov (United States)

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-09-23

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  18. Bubbling bed catalytic hydropyrolysis process utilizinig larger catalyst particles and small biomass particles featuring an anti-slugging reactor

    Science.gov (United States)

    Marker, Terry L.; Felix, Larry G.; Linck, Martin B.; Roberts, Michael J.

    2016-12-06

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  19. Media arrangement impacts cell growth in anaerobic fixed-bed reactors treating sugarcane vinasse: Structured vs. randomic biomass immobilization.

    Science.gov (United States)

    de Aquino, Samuel; Fuess, Lucas Tadeu; Pires, Eduardo Cleto

    2017-07-01

    This study reports on the application of an innovative structured-bed reactor (FVR) as an alternative to conventional packed-bed reactors (PBRs) to treat high-strength solid-rich wastewaters. Using the FVR prevents solids from accumulating within the fixed-bed, while maintaining the advantages of the biomass immobilization. The long-term operation (330days) of a FVR and a PBR applied to sugarcane vinasse under increasing organic loads (2.4-18.0kgCODm -3 day -1 ) was assessed, focusing on the impacts of the different media arrangements over the production and retention of biomass. Much higher organic matter degradation rates, as well as long-term operational stability and high conversion efficiencies (>80%) confirmed that the FVR performed better than the PBR. Despite the equivalent operating conditions, the biomass growth yield was different in both reactors, i.e., 0.095gVSSg -1 COD (FVR) and 0.066gVSSg -1 COD (PBR), indicating a clear control of the media arrangement over the biomass production in fixed-bed reactors. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Preliminary Safeguards Assessment for the Pebble-Bed Fluoride High-Temperature Reactor (PB-FHR) Concept

    Energy Technology Data Exchange (ETDEWEB)

    Disser, Jay; Arthur, Edward; Lambert, Janine

    2016-09-01

    This report examines a preliminary design for a pebble bed fluoride salt-cooled high temperature reactor (PB-FHR) concept, assessing it from an international safeguards perspective. Safeguards features are defined, in a preliminary fashion, and suggestions are made for addressing further nuclear materials accountancy needs.

  1. Closing the Loop by Combining UASB Reactor and Reactive Bed Filetr Technology for wastewater Treatment : Modelling and Practical Approaches

    OpenAIRE

    Rodríguez-Gómez, Raúl

    2016-01-01

    A laboratory-scale upflow anaerobic sludge blanket (UASB) reactor followed by a packed bed reactor (PBR) filled with Sorbulite® in the lower part and Polonite® in the upper part was used to treat household wastewater in a 50-week experiment. A model was developed to describe the performance of the UASB reactor, including mass transfer through the film around anaerobic granules, intra-particle diffusion and bioconversion of the substrate. In a second model, a numerical expression describing th...

  2. Fast pyrolysis of Miscanthus sinensis in fluidized bed reactors: Characteristics of product yields and biocrude oil quality

    International Nuclear Information System (INIS)

    Bok, Jin Pil; Choi, Hang Seok; Choi, Joon Weon; Choi, Yeon Seok

    2013-01-01

    In the present work, fast pyrolysis of Miscanthus sinensis was performed and the product yields and properties of the resulting biocrude oil were determined for varying reactor configurations and pyrolysis temperatures. Two types of reactors (rectangular and cylindrical fluidized beds) were adopted, and pyrolysis temperature was increased from 400 °C to 550 °C. Based on the results, it was found that the reaction temperature greatly influenced the product yield and the characteristics of biocrude oil. The highest yield of biocrude oil for the rectangular reactor was 48.9 wt.%, produced at 500 °C, and the highest yield for the cylindrical reactor was 50.01 wt.%, produced at 450 °C. Additionally, the biocrude oil yield in the rectangular reactor sharply decreased when reaction temperature was increased to 550 °C, while only a slight decrease was observed in the cylindrical reactor. From GC/MS analysis, biocrude oil was found to contain various chemical components, such as nonaromatic ketones, furans, sugars, lignin-derived phenols, guaiacols and syringols. In particular, the sugar content of the biocrude oil produced in rectangular reactor (2.11–9.35 wt.%) was generally lower than that produced in the cylindrical reactor (7.93–10.79 wt.%). - Highlights: • Fast pyrolysis of Miscanthus sinensis was performed in two fluidized bed reactors to obtain biocrude oil. • The yield and characteristics of the biocrude oil were scrutinized with changing reaction temperature and reactor type. • The reaction temperature was found to be the most influencing parameter for the fast pyrolysis reaction. • The different heating rate caused by reactor type has an effect on the final product yield and characteristics

  3. Biofilm development in fixed bed biofilm reactors: experiments and simple models for engineering design purposes.

    Science.gov (United States)

    Szilágyi, N; Kovács, R; Kenyeres, I; Csikor, Zs

    2013-01-01

    Biofilm development in a fixed bed biofilm reactor system performing municipal wastewater treatment was monitored aiming at accumulating colonization and maximum biofilm mass data usable in engineering practice for process design purposes. Initially a 6 month experimental period was selected for investigations where the biofilm formation and the performance of the reactors were monitored. The results were analyzed by two methods: for simple, steady-state process design purposes the maximum biofilm mass on carriers versus influent load and a time constant of the biofilm growth were determined, whereas for design approaches using dynamic models a simple biofilm mass prediction model including attachment and detachment mechanisms was selected and fitted to the experimental data. According to a detailed statistical analysis, the collected data have not allowed us to determine both the time constant of biofilm growth and the maximum biofilm mass on carriers at the same time. The observed maximum biofilm mass could be determined with a reasonable error and ranged between 438 gTS/m(2) carrier surface and 843 gTS/m(2), depending on influent load, and hydrodynamic conditions. The parallel analysis of the attachment-detachment model showed that the experimental data set allowed us to determine the attachment rate coefficient which was in the range of 0.05-0.4 m d(-1) depending on influent load and hydrodynamic conditions.

  4. Propagation of negative electrical discharges through 2-dimensional packed bed reactors

    International Nuclear Information System (INIS)

    Kruszelnicki, Juliusz; Engeling, Kenneth W; Foster, John E; Xiong, Zhongmin; Kushner, Mark J

    2017-01-01

    Plasma-based pollutant remediation and value-added gas production have recently gained increased attention as possible alternatives to the currently-deployed chemical reactor systems. Electrical discharges in packed bed reactors (PBRs) are of interest, due to their ability to synergistically combine catalytic and plasma chemical processes. In principle, these systems could be tuned to produce specific products, based on their application by combinations of power formats, materials, geometries and working gases. Negative voltage, atmospheric-pressure plasma discharges sustained in humid air in a PBR-like geometry were experimentally characterized using ICCD imaging and simulated in 2-dimensions (2D) to provide insights into possible routes to this tunability. Surface ionization waves (SIWs) and positive restrikes through the lattice of dielectric rods were shown to be the principal means of producing reactive species. The number and intensity of SIWs and restrikes are sensitive functions of the alignment of the lattice of dielectric beads (or rods in 2D) with respect to the applied electric field. Decreased spacing between the dielectric elements leads to an increased electric field enhancement in the gas, and therefore locally higher plasma densities, but does not necessarily impact the types of discharges that occur through the lattice. (paper)

  5. Evaluation of Heavy Metal Removal from Wastewater in a Modified Packed Bed Biofilm Reactor.

    Directory of Open Access Journals (Sweden)

    Shohreh Azizi

    Full Text Available For the effective application of a modified packed bed biofilm reactor (PBBR in wastewater industrial practice, it is essential to distinguish the tolerance of the system for heavy metals removal. The industrial contamination of wastewater from various sources (e.g. Zn, Cu, Cd and Ni was studied to assess the impacts on a PBBR. This biological system was examined by evaluating the tolerance of different strengths of composite heavy metals at the optimum hydraulic retention time (HRT of 2 hours. The heavy metal content of the wastewater outlet stream was then compared to the source material. Different biomass concentrations in the reactor were assessed. The results show that the system can efficiently treat 20 (mg/l concentrations of combined heavy metals at an optimum HRT condition (2 hours, while above this strength there should be a substantially negative impact on treatment efficiency. Average organic reduction, in terms of the chemical oxygen demand (COD of the system, is reduced above the tolerance limits for heavy metals as mentioned above. The PBBR biological system, in the presence of high surface area carrier media and a high microbial population to the tune of 10 000 (mg/l, is capable of removing the industrial contamination in wastewater.

  6. Evaluation of Heavy Metal Removal from Wastewater in a Modified Packed Bed Biofilm Reactor

    Science.gov (United States)

    Azizi, Shohreh; Kamika, Ilunga; Tekere, Memory

    2016-01-01

    For the effective application of a modified packed bed biofilm reactor (PBBR) in wastewater industrial practice, it is essential to distinguish the tolerance of the system for heavy metals removal. The industrial contamination of wastewater from various sources (e.g. Zn, Cu, Cd and Ni) was studied to assess the impacts on a PBBR. This biological system was examined by evaluating the tolerance of different strengths of composite heavy metals at the optimum hydraulic retention time (HRT) of 2 hours. The heavy metal content of the wastewater outlet stream was then compared to the source material. Different biomass concentrations in the reactor were assessed. The results show that the system can efficiently treat 20 (mg/l) concentrations of combined heavy metals at an optimum HRT condition (2 hours), while above this strength there should be a substantially negative impact on treatment efficiency. Average organic reduction, in terms of the chemical oxygen demand (COD) of the system, is reduced above the tolerance limits for heavy metals as mentioned above. The PBBR biological system, in the presence of high surface area carrier media and a high microbial population to the tune of 10 000 (mg/l), is capable of removing the industrial contamination in wastewater. PMID:27186636

  7. Carbon nanotubes shynthesis in fluidized bed reactor equipped with a cyclone

    Science.gov (United States)

    Setyopratomo, P.; Sudibandriyo, M.; Wulan, P. P. D. K.

    2018-03-01

    This work aimed to observe the performance of a fluidized bed reactor which was equipped with a cyclone in the synthesis of carbon nanotubes (CNT) by chemical vapor deposition. Liquefied petroleum gas with a constant volumetric flow rate of 1940 cm3/minutes was fed to the reactor as a carbon source, while a combination of metal components of Fe-Co-Mo supported on MgO was used as catalyst. The CNT synthesis was carried out at a reaction temperature which was maintained at around 800 – 850 °C for 1 hour. The CNT yield was decreased sharply when the catalyst feed was increased. The carbon efficiency is directly proportional to the mass of catalyst fed. It was found from the experiment that the mass of as-grown CNT increased in proportion to the increase of the catalyst mass fed. A sharp increase of the mass percentage of carbon nanotubes entrainment happened when the catalyst feed was raised from 3 to 7 grams. Agglomerates of carbon nanotubes have been formed. The agglomerates composed of mutually entangled carbon nanotubes which have an outer diameter range 8 – 14 nm and an inner diameter range 4 – 10 nm, which confirmed that the multi-walled carbon nanotubes were formed in this synthesis. It was found that the mesopores dominate the pore structure of the CNT product and contribute more than 90 % of the total pore volume.

  8. Passive deca-heat removal in the fixed bed nuclear reactor (FBNR) - 15551

    International Nuclear Information System (INIS)

    Solano Diaz, E.C.; Luna Aguilera, G.M.; Santos, R.A.; Vaca, D.E.

    2015-01-01

    The Fixed Bed Nuclear Reactor (FBNR) is a Generation IV small reactor concept, where the spherical elements contain Triso-type microspheres with UO 2 , which serves as nuclear fuel. In the event that adverse operation conditions occur, the water pump is automatically shut off and the fuel pebbles fall back by gravity into the fuel chamber. Since the FBNR relies on passive security systems, the removal of the decay heat in the fuel chamber is achieved by contact with quiescent water. In the present paper, a mathematical simulation of the passive cooling of the system was conducted in SOLIDWORKS so as to obtain a temperature profile in the body during the decay heat removal process. Homogenization techniques were employed to smooth out spatial variations across the multiphase system and to derive expression for the effective thermophysical properties that are valid through the macroscopic entry (the chamber). The simulation showed that the chamber's temperature rose from 573 K to its maximum temperature, 1234 K, in the first hour. Afterwards, the temperature fluctuated, but stayed under 552 K. Since the temperature of the system was always kept under the value of the safety parameter (1200 C. degrees) the simulation confirmed that an effective passive cooling of the fuel chamber is indeed feasible. (authors)

  9. Simulation for Supporting Scale-Up of a Fluidized Bed Reactor for Advanced Water Oxidation

    Directory of Open Access Journals (Sweden)

    Farhana Tisa

    2014-01-01

    Full Text Available Simulation of fluidized bed reactor (FBR was accomplished for treating wastewater using Fenton reaction, which is an advanced oxidation process (AOP. The simulation was performed to determine characteristics of FBR performance, concentration profile of the contaminants, and various prominent hydrodynamic properties (e.g., Reynolds number, velocity, and pressure in the reactor. Simulation was implemented for 2.8 L working volume using hydrodynamic correlations, continuous equation, and simplified kinetic information for phenols degradation as a model. The simulation shows that, by using Fe3+ and Fe2+ mixtures as catalyst, TOC degradation up to 45% was achieved for contaminant range of 40–90 mg/L within 60 min. The concentration profiles and hydrodynamic characteristics were also generated. A subsequent scale-up study was also conducted using similitude method. The analysis shows that up to 10 L working volume, the models developed are applicable. The study proves that, using appropriate modeling and simulation, data can be predicted for designing and operating FBR for wastewater treatment.

  10. Propagation of negative electrical discharges through 2-dimensional packed bed reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Xiong, Zhongmin; Kushner, Mark J.

    2017-01-01

    Plasma-based pollutant remediation and value-added gas production have recently gained increased attention as possible alternatives to the currently-deployed chemical reactor systems. Electrical discharges in packed bed reactors (PBRs) are of interest, due to their ability to synergistically combine catalytic and plasma chemical processes. In principle, these systems could be tuned to produce specific products, based on their application by combinations of power formats, materials, geometries and working gases. Negative voltage, atmospheric-pressure plasma discharges sustained in humid air in a PBR-like geometry were experimentally characterized using ICCD imaging and simulated in 2-dimensions (2D) to provide insights into possible routes to this tunability. Surface ionization waves (SIWs) and positive restrikes through the lattice of dielectric rods were shown to be the principal means of producing reactive species. The number and intensity of SIWs and restrikes are sensitive functions of the alignment of the lattice of dielectric beads (or rods in 2D) with respect to the applied electric field. Decreased spacing between the dielectric elements leads to an increased electric field enhancement in the gas, and therefore locally higher plasma densities, but does not necessarily impact the types of discharges that occur through the lattice.

  11. Flow instability tests for a particle bed reactor nuclear thermal rocket fuel element

    Science.gov (United States)

    Lawrence, Timothy J.

    1993-05-01

    Recent analyses have focused on the flow stability characteristics of a particle bed reactor (PBR). These laminar flow instabilities may exist in reactors with parallel paths and are caused by the heating of the gas at low Reynolds numbers. This phenomena can be described as follows: several parallel channels are connected at the plenum regions and are stabilized by some inlet temperature and pressure; a perturbation in one channel causes the temperature to rise and increases the gas viscosity and reduces the gas density; the pressure drop is fixed by the plenum regions, therefore, the mass flow rate in the channel would decrease; the decrease in flow reduces the ability to remove the energy added and the temperature increases; and finally, this process could continue until the fuel element fails. Several analyses based on different methods have derived similar curves to show that these instabilities may exist at low Reynolds numbers and high phi's ((Tfinal Tinitial)/Tinitial). These analyses need to be experimentally verified.

  12. Fluidized-bed design for ICF reactor blankets using solid-lithium compounds

    International Nuclear Information System (INIS)

    Sucov, E.W.; Malick, F.S.; Green, L.; Hall, B.O.

    1983-01-01

    A fluidized-bed concept for blankets of dry or wetted first-wall ICF reactors using solid-lithium compounds is described. The reaction chamber is a right cylinder, 32 m high and 20 m in diameter; the blanket is composed of 36 steel tanks, 32 m high, which carry the sintered Li 2 O particles in the fluidizing helium gas. Each tank has a radial thickness of 2 m which generates a tritium breeding ration (TBR) of 1.27 and absorbs over 98% of the neutron energy; reducing the thickness to 1.2 m produces a TBR of 1.2 and energy absorption of 97% which satisfy the design goals. Calculations of tritium diffusion through the grains and heat removal from the grains showed that neither could be removed by the carrier gas; tritium and heat are therefore removed by removing the grains themselves by varying the helium flow rate. The particles are continuously fed into the bottom of the tanks at 300 0 C and removed at the top at 475 0 C. Tritium and heat extraction are easily and conveniently done outside the reactor

  13. Development and testing of nuclear graphite for the German pebble-bed high temperature reactor

    International Nuclear Information System (INIS)

    Haag, G.; Delle, W.; Nickel, H.; Theymann, W.; Wilhelmi, G.

    1987-01-01

    Several types of high temperature reactors have been developed in the Federal Republic of Germany. They are all based on spherical fuel elements being surrounded by graphite as reflector material. As an example, HTR-500 developed by the Hochtemperatur Reaktorbau GmbH is shown. The core consists of the top reflector, the side reflector with inner and outer parts, the bottom reflector and the core support columns. The most serious problem with respect to fast neutron radiation damage had to be solved for the materials of those parts near the pebble bed. Regarding the temperature profile in the core, the top reflector is at 300 deg C, and as cooling gas flows from the top downward, the temperature of the inner side reflector rises to about 700 deg C at the bottom. Fortunately, the highest fast neutron load accumulated during the life time of a reactor corresponds to the lowest temperature. This makes graphite components easier to survive neutron exposure without being mechanically damaged, although the maximum fast neutron fluence is as high as 4 x 10 22 /cm 2 at about 400 deg C. HTR graphite components are divided into four classes according to loading. The raw materials for nuclear graphite, the development of pitch coke nuclear graphite, the irradiation behavior of ATR-2E and ASR-IRS and others are reported. (Kako, I.)

  14. Characteristic behaviour of Pebble Bed High Temperature Gas-cooled Reactors during water ingress events

    International Nuclear Information System (INIS)

    Khoza, Samukelisiwe N.; Serfontein, Dawid E.; Reitsma, Frederik

    2014-01-01

    The presence of water on the tube-side of the steam generators in high temperature gas-cooled reactors (HTGRs) with indirect cycle layouts presents a possibility for a penetration of neutron moderating steam into the core, which may cause a power excursion. This article presents results on the effect of water ingress into the core of the two South African Pebble Bed Modular Reactor design concepts, i.e. the PBMR-200 MW th and the PBMR-400 MW th developed by PBMR SOC Ltd. The VSOP 99/05 suite of codes was used for the simulation of this event. Partial steam vapour pressures were added in stages into the primary circuit in order to investigate the effect of water ingress on reactivity, power profiles and thermal neutron flux profiles. The effects of water ingress into the core are explained by increased neutron moderation, due to the addition of 1 H, which leads to a decrease in resonance capture by 238 U and therefore an increase in the multiplication factor. The more effective moderation of neutrons by definition reduces the fast neutron flux and increases the thermal flux in the core, i.e. leads to a softer spectrum. The more effective moderation also increases the average increase in lethargy between collisions of a neutron with successive fuel kernels, which reduces the probability for neutron capture in the radiative capture resonances of 238 U. The resulting higher resonance escape probability also increases the thermal flux in the core. The softening of the neutron spectrum leads to an increased effective microscopic fission cross section in the fissile isotopes and thus to increased neutron absorption for fission, which reduces the remaining number of neutrons that can diffuse into the reflectors. Therefore water ingress into the core leads to a reduced thermal neutron flux in the reflectors. The power density spatial distribution behaved similarly to the thermal neutron flux in the core. Analysis of possible mechanisms was conducted. The results show that

  15. CFD applications in the Pebble Bed Modular Reactor Project: A decade of progress

    International Nuclear Information System (INIS)

    Janse van Rensburg, J.J.; Kleingeld, M.

    2011-01-01

    Highlights: → This paper evaluates the evolution of Gas Cooled Reactor CFD analysis over the last decade. → It discusses the influence of advances in hardware and software on the evolution of capabilities. → The advances in mesh generation and the physics that can be included is also discussed. → The focus was on the capabilities rather than improving the assumptions and correlations. - Abstract: Of all the systems and components that have to be designed for a nuclear plant, the Reactor Unit is the most significant since it is at the very heart of the plant. At Pebble Bed Modular Reactor (Pty) Ltd. (PBMR), the design of the Reactor Unit is conducted with the aid of extensive analysis work. Due to the rapid computational improvements, the analysis capabilities have had to evolve rather significantly over the last decade. This paper evaluates the evolution of RU Computational Fluid Dynamics (CFD) analysis in particular and presents a historical timeline of the analyses conducted at PBMR. The influence of advances in the hardware and software applications on the evolution of the analysis capabilities is also discussed. When evaluating the evolution of analysis, it is important to look not only at the advances in mesh generation and the representation of the geometry, but also at the improvements regarding the physics that were included in the models. The discussion evaluates the improvements from the pre-conceptual analyses, the concept design, the basic design and finally, the detail design. It is however important to note that the focus of this research was on establishing a methodology for the integrated CFD analysis of High Temperature Reactors. It is recognized however that results from this research can currently only be used to investigate and understand trends and behaviors rather than absolute values. It was therefore required to also launch an extensive V and V program of which the focus was to verify the approach and validate the methodology that

  16. Simultaneous denitrification and anaerobic digestion in GRAnular Bed Baffled Reactor (GRABBR)

    International Nuclear Information System (INIS)

    Baloch, M.I.; Akunna, J.C.

    2002-01-01

    This study elucidates the characteristics of compartmentalised anaerobic system seeded with UASB granules, called GRAanular Bed Baffled Reactor (GRABBR), for combined denitrification and anaerobic digestion processes. The reactor was used for the treatment of glucose enriched synthetic wastewater with various nitrate concentrations. The study was carried out with a 10 litre working volume GRABBR divided into 5 equal compartments operating at organic loading rate (OLR) of 20 kg COD/m 3 .d with a hydraulic retention time (HRT) of 6 hours. At these conditions, phase separation (between acidogenesis and methanogenesis) was created in the system and then the effect of varying nitrate concentrations (50-200 mg/l NO 3 -N) in the acidogenic zone (i.e. first compartment) was studied. Due to its unique compartmentalised design, denitrification was the major pathway for nitrate reduction with no noticeable dissimilatory nitrate reduction to ammonia (DNRA). More than 84% of all added nitrates were removed in the acidogenic zone, showing that acidogens possess high denitrifying capabilities. The denitrification rate increased with increase in nitrate concentration, with maximum value estimated as 175 mg NO 3 -N/l.h at influent nitrate concentration of 200 mg/l NO 3 -N in the acidogenic zone. Although nitrate addition resulted in lower methane production, COD removal efficiencies improved by up to 8% when compared with the reactor performance before nitrate addition. Furthermore, the alkalinity produced during denitrification improved the stability of the system by controlling the decrease in pH resulting from acidogenesis. The system encouraged simultaneous denitrification and anaerobic digestion in a single unit by accommodating denitrifiers in the early compartments and allowing methanogenesis to flourish in the downstream compartments of the system, thus minimising inhibition to methane producing bacteria by nitrates. (author)

  17. Sustainability of thorium-uranium in pebble-bed fluoride salt-cooled high temperature reactor

    International Nuclear Information System (INIS)

    Zhu, G.; Zou, Y.; Xu, H.

    2016-01-01

    Sustainability of thorium fuel in a Pebble-Bed Fluoride salt-cooled High temperature Reactor (PBFHR) is investigated to find the feasible region of high discharge burnup and negative Flibe (2LiF-BeF_2) salt Temperature Reactivity Coefficient (TRC). Dispersion fuel or pellet fuel with SiC cladding and SiC matrix is used to replace the tri-structural-isotropic (TRISO) coated particle system for increasing fuel loading and decreasing excessive moderation. To analyze the neutronic characteristics, an equilibrium calculation method of thorium fuel self-sustainability is developed. We have compared two refueling schemes (mixing flow pattern and directional flow pattern) and two kinds of reflector materials (SiC and graphite). This method found that the feasible region of breeding and negative Flibe TRC is between 20 vol% and 62 vol% fuel loading in the fuel. A discharge burnup could be achieved up to about 200 MWd/kgHM. The case with directional flow pattern and SiC reflector showed superior burnup characteristics but the worst radial power peak factor, while the case with mixing flow pattern and SiC reflector, which was the best tradeoff between discharge burnup and radial power peak factor, could provide burnup of 140 MWd/kgHM and about 1.4 radial power peak factor with 50 vol% dispersion fuel. In addition, Flibe salt displays good neutron properties as a coolant of quasi-fast reactors due to the strong "9Be(n,2n) reaction and low neutron absorption of "6Li (even at 1000 ppm) in fast spectrum. Preliminary thermal hydraulic calculation shows a good safety margin. The greatest challenge of this reactor may be the decades irradiation time of the pebble fuel. (A.C)

  18. Packed bed reactor for degradation of simulated cyanide-containing wastewater.

    Science.gov (United States)

    Kumar, Virender; Kumar, Vijay; Bhalla, Tek Chand

    2015-10-01

    The discharge of cyanide-containing effluents into the environment contaminates water bodies and soil. Effective methods of treatment which can detoxify cyanide are the need of the hour. The aim of the present study is to develop a bioreactor for complete degradation of cyanide using immobilized cells of Serratia marcescens RL2b. Alginate-entrapped cells of S. marcescens RL2b were used for complete degradation of cyanide in a packed bed reactor (PBR). Cells grown in minimal salt medium (pH 6.0) were harvested after 20 h and exhibited 0.4 U mg -1  dcw activity and 99 % cyanide degradation in 10 h. These resting cells were entrapped using 3 % alginate beads and packed in a column reactor (20 × 1.7 cm). Simulated cyanide (12 mmol l -1 )-containing wastewater was loaded and fractions were collected after different time intervals at various flow rates. Complete degradation of 12 m mmol l -1 (780 mg l -1 ) cyanide in 10 h was observed at a flow rate of 1.5 ml h -1 . The degradation of cyanide in PBR showed direct dependence on retention time. The retention time of cyanide in the reactor was 9.27 h. The PBR can degrade 1.2 g of cyanide completely in 1 day.

  19. Heat Transfer in Pebble-Bed Nuclear Reactor Cores Cooled by Fluoride Salts

    Science.gov (United States)

    Huddar, Lakshana Ravindranath

    With electricity demand predicted to rise by more than 50% within the next 20 years and a burgeoning world population requiring reliable emissions-free base-load electricity, can we design advanced nuclear reactors to help meet this challenge? At the University of California, Berkeley (UCB) Fluoride-salt-cooled High Temperature Reactors (FHR) are currently being investigated. FHRs are designed with better safety and economic characteristics than conventional light water reactors (LWR) currently in operation. These reactors operate at high temperature and low pressure making them more efficient and safer than LWRs. The pebble-bed FHR (PB-FHR) variant includes an annular nuclear reactor core that is filled with randomly packed pebble fuel. It is crucial to characterize the heat transfer within this unique geometry as this informs the safety limits of the reactor. The work presented in this dissertation focused on furthering the understanding of heat transfer in pebble-bed nuclear reactor cores using fluoride salts as a coolant. This was done through experimental, analytical and computational techniques. A complex nuclear system with a coolant that has never previously been in commercial use requires experimental data that can directly inform aspects of its design. It is important to isolate heat transfer phenomena in order to understand the underlying physics in the context of the PB-FHR, as well as to make decisions about further experimental work that needs to be done in support of developing the PB-FHR. Certain organic oils can simulate the heat transfer behaviour of the fluoride salt if relevant non-dimensional parameters are matched. The advantage of this method is that experiments can be done at a much lower temperature and at a smaller geometric scale compared to FHRs, thereby lowering costs. In this dissertation, experiments were designed and performed to collect data demonstrating similitude. The limitations of these experiments were also elucidated by

  20. Syngas fermentation by Clostridium carboxidivorans P7 in a horizontal rotating packed bed biofilm reactor with enhanced ethanol production

    International Nuclear Information System (INIS)

    Shen, Yanwen; Brown, Robert C.; Wen, Zhiyou

    2017-01-01

    Highlights: • A novel a horizontal rotating packed bed (h-RPB) reactor for syngas fermentation was reported. • The h-RPB reactor enhanced ethanol productivity by 3.3-folds compared to continuous stirred tank reactor (CSTR). • The h-RPB reactor has a unique feature of transfer gas from both bulk liquid phase and headspace phase. • The mass transfer in the headspace of h-PRB played an important role for enhanced ethanol production. - Abstract: Gasification of lignocellulosic biomass followed by syngas fermentation is a promising process for producing fuels and chemicals. Syngas fermentation, however, is commonly limited by low mass transfer rates. In this work, a horizontally oriented rotating packed bed (h-RPB) reactor was developed to improve mass transfer and enhance ethanol production. In the h-RPB reactor, cell attachment materials were packed in the reactor and half submerged in the liquid and half exposed to the headspace. With continuous rotation of the packing materials, the cells in biofilm were alternately in contact with liquid and headspace; thus, transport of syngas to the cells occurred in both the liquid phase and headspace. The volumetric mass transfer coefficient (k_La) of the h-RPB reactor was lower than that in a traditional continuous stirred tank reactor (CSTR), indicating the mass transfer in the liquid phase of h-PRB was lower than CSTR, and the mass transfer in the headspace phase played an important role in syngas fermentation. The syngas fermentation of Clostridium carboxidivorans P7 in h-RPB resulted in a 7.0 g/L titer and 6.7 g/L/day productivity of ethanol, respectively, 3.3 times higher than those obtained in a CSTR under the same operational conditions. The results demonstrate that the h-RPB reactor is an efficient system for syngas fermentation, making cellulosic ethanol biorefinery one step closer to technical and economic feasibility.