Sample records for bed high temperature

  1. Ultra high temperature particle bed reactor design (United States)

    Lazareth, Otto; Ludewig, Hans; Perkins, K.; Powell, J.


    A direct nuclear propulsion engine which could be used for a mission to Mars is designed. The main features of this reactor design are high values for I(sub sp) and very efficient cooling. This particle bed reactor consists of 37 cylindrical fuel elements embedded in a cylinder of beryllium which acts as a moderator and reflector. The fuel consists of a packed bed of spherical fissionable fuel particles. Gaseous H2 passes over the fuel bed, removes the heat, and is exhausted out of the rocket. The design was found to be neutronically critical and to have tolerable heating rates. Therefore, this particle bed reactor design is suitable as a propulsion unit for this mission.

  2. Core Physics of Pebble Bed High Temperature Nuclear Reactors

    NARCIS (Netherlands)

    Auwerda, G.J.


    To more accurately predict the temperature distribution inside the reactor core of pebble bed type high temperature reactors, in this thesis we investigated the stochastic properties of randomly stacked beds and the effects of the non-homogeneity of these beds on the neutronics and thermal-hydraulic

  3. Granular bed filtration of high temperature biomass gasification gas. (United States)

    Stanghelle, Daniel; Slungaard, Torbjørn; Sønju, Otto K


    High temperature cleaning of producer gas from biomass gasification has been investigated with a granular filter. Field tests were performed for several hours on a single filter element at about 550 degrees C. The results show cake filtration on the granular material and indicate good filtration of the biomass gasification producer gas. The relatively low pressure drop over the filter during filtration is comparable to those of bag filters. The granular filter can operate with high filtration velocities compared to bag filters and maintain high efficiency and a low residual pressure. This work is a part of the BioSOFC-up project that has a goal of utilizing the producer gas from the gasification plant in a solid oxide fuel cell (SOFC). The BioSOFC-up project will continue to the end of 2007.

  4. High Temperature Convective Drying of a Packed Bed with Humid Air at Different Humidities

    Directory of Open Access Journals (Sweden)

    J. Sghaier


    Full Text Available Problem statement: Drying a packed bed of porous particle at high temperature with varying humidity of hot air is an attractive process. Despite, many researches on experimental and simulation on a fixed bed drying at low and average temperature are proposed. Few studies showed drying at high temperature with humid air or using superheated steam. The latest is compared to dry air. Approach: In this study, we show an experimental and numerical study of humid air drying of a fixed bed of moist porous alumina particles. The air velocity, the air temperature and the vapor pressure were varied from 1.7-2.3 m.sec-1, 120-160°C and 0.1-0.65 bar, respectively and the experiments were performed at atmospheric pressure. Then a mathematical describing heat and mass transfer during drying is developed. This model is based on the averaging volume approach using two scale changes. Results: From the experimental works, the solid temperature and the bed moisture content have been presented at different drying conditions. The previous results show that an increase in humidity leads to an increase of the wet bulb temperature and a decrease in the drying time. At the same drying temperature, the variation in the gas velocity affects also the drying time. In addition, we note that the drying time increases if the bed depth increases. The predicted results deduced from the developed model were compared with the experiment. Conclusion: The experimental and predicted results obtained from this study describing drying of a packed bed illustrate clearly the effect of the air humidity on the drying kinetics.

  5. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.


    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  6. Analysis of the fluid-bed stability of FCC catalysts at high temperature in terms of bed elasticity

    Institute of Scientific and Technical Information of China (English)

    Paola Lettieri; Luca Mazzer


    The effect of temperature on the fluid-bed stability of three FCC catalysts has been analyzed through considerations on fluid-bed elasticity. Experimental findings on the effect of temperature on the elasticity modulus at minimum bubbling conditions, (E)mb, were analyzed using the hydrodynamic fluid-bed stability model developed by Foscolo and Gibilaro (1984) and adopting the interparticle-forces-based stability criterion developed by Mutsers and Rietema (1977). For both models, the parameters which control changes in (E)mb with temperature are discussed, in order to establish the origin of the fluid-bed elasticity and analyze the ability of these models to discriminate between the relative importance of the hydrodynamic and interparticle forces on the stability of the fluidized catalysts.

  7. Agglomeration in fluidized beds at high temperatures: Mechanisms, detection and prevention

    Energy Technology Data Exchange (ETDEWEB)

    Malte Bartels; Weigang Lin; John Nijenhuis; Freek Kapteijn; J. Ruud van Ommen [Delft University of Technology - DelftChemTech, Delft (Netherlands)


    Fluidized-bed conversion of solid fuels is a well-established and widely used technology. Yet, operational problems are encountered in industrial practice. One of the most important problems is the occurrence of agglomeration at high temperature, meaning that bed particles adhere to each other to form larger entities (agglomerates). This process is often not recognized until sudden defluidization and often leads to a costly shutdown of the whole installation. In particular, the thermal conversion of certain biomass fuels, which is becoming increasingly popular, increases the risk of agglomeration. This paper critically reviews the current research status of this topic in terms of agglomeration mechanisms, detection and counteraction strategies. To understand the complex phenomenon of agglomeration in fluidized beds at high temperatures different areas are distinguished viz. hydrodynamics, chemical reaction mechanisms, particle interaction mechanisms and molecular cramming. Special emphasis is given to the detection of agglomeration. The range of detection methods is comprised of fuel ash analysis methods to predict potential agglomeration as well as analysis methods based on (on-line) process measurements, such as pressure and temperature. Finally, different methods to counteract agglomeration phenomena are presented; they comprise operational measures, utilization of additives, alternative bed materials and improved reactor design. 176 refs., 22 figs., 1 tab.

  8. Sustainability of thorium-uranium in pebble-bed fluoride salt-cooled high temperature reactor


    Zhu Guifeng; Zou Yang; Xu Hongjie


    Sustainability of thorium fuel in a Pebble-Bed Fluoride salt-cooled High temperature Reactor (PB-FHR) is investigated to find the feasible region of high discharge burnup and negative Flibe (2LiF-BeF2) salt Temperature Reactivity Coefficient (TRC). Dispersion fuel or pellet fuel with SiC cladding and SiC matrix is used to replace the tristructural-isotropic (TRISO) coated particle system for increasing fuel loading and decreasing excessive moderation. To analyze the neutronic characteristics,...

  9. Predicting freeboard heat transfer by using empirical correlations in high temperature fluidized beds

    Energy Technology Data Exchange (ETDEWEB)

    Biyikli, Suleyman [Okan University Tuzla Kampusu, Faculty of Engineering and Architecture (Turkey)], email:


    This article investigates the heat transfer characteristics for horizontal tubes in a freeboard region of high temperature fluidized beds. The freeboard entrainment heights are calculated by using empirical correlations described in detail and used in estimating the heat transfer coefficients from a horizontal tube occurring by radiation, gas convection, and particle contact mechanisms in high temperature a fluidized bed combustor. The total average of these coefficients around a horizontal tube carrying water in high temperature fluidized beds can be written as the sum of convective, radiative, and fluidized-particle contact heat transfer coefficients and these correlations are tested against certain published experimental measurements. In full agreement with this data, it was observed that the calculated heat transfer coefficients increased with increasing gas velocity at a given tube elevation and they decreased and approached the values of single-phase gas convection and radiation with increasing tube elevation in the freeboard region while the relative contribution of radiation increases and approaches a constant fraction of total heat transfer.

  10. High temperature degradation by erosion-corrosion in bubbling fluidized bed combustors

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Peggy Y.; MacAdam, S.; Niu, Y.; Stringer, J.


    Heat-exchanger tubes in fluidized bed combustors (FBCs) often suffer material loss due to combined corrosion and erosion. Most severe damage is believed to be caused by the impact of dense packets of bed material on the lower parts of the tubes. In order to understand this phenomenon, a unique laboratory test rig at Berkeley was designed to simulate the particle hammering interactions between in-bed particles and tubes in bubbling fluidized bed combustors. In this design, a rod shaped specimen is actuated a short distance within a partially fluidized bed. The downward specimen motion is controlled to produce similar frequencies, velocities and impact forces as those experienced by the impacting particle aggregates in practical systems. Room temperature studies have shown that the degradation mechanism is a three-body abrasion process. This paper describes the characteristics of this test rig, reviews results at elevated temperatures and compares them to field experience. At higher temperatures, deposits of the bed material on tube surfaces can act as a protective layer. The deposition depended strongly on the type of bed material, the degree of tube surface oxidation and the tube and bed temperatures. With HCl present in the bed, wastage was increased due to enhanced oxidation and reduced oxide scale adherence.

  11. Evaluation of heat transfer in a catalytic fixed bed reactor at high temperatures

    Directory of Open Access Journals (Sweden)

    L. M. M. JORGE


    Full Text Available Experimental results of fixed-bed heat-transfer experiments with no chemical reaction are presented and discussed. The runs were carried out in a tubular integral reactor heated by an electrical furnace at temperatures in the range of 100 to 500°C. Experimental temperature profiles were determined for the electrical furnace, for the reactor wall, and for the fixed bed center. Industrial catalyst for the prereforming of hydrocarbons was employed as the packing material. The effects of process conditions (furnace temperature, gas flow rate on the heat-transfer coefficients were evaluated. The experimental results were analyzed in terms of the external, wall, and internal thermal resistances, associated in series, and compared with model predictions. Under the conditions studied, the overall coefficient was mostly a function of the external effective heat-transfer coefficient. An alternative data treatment was proposed to determine the internal heat-transfer coefficient in fixed beds when wall temperature is not constant.

  12. Feasibility of Thorium Fuel Cycles in a Very High Temperature Pebble-Bed Hybrid System

    Directory of Open Access Journals (Sweden)

    L.P. Rodriguez


    Full Text Available Nuclear energy presents key challenges to be successful as a sustainable energy source. Currently, the viability of the use thorium-based fuel cycles in an innovative nuclear energy generation system is being investigated in order to solve these key challenges. In this work, the feasibility of three thorium-based fuel cycles (232Th-233U, 232Th-239Pu, and 232Th-U in a hybrid system formed by a Very High Temperature Pebble-Bed Reactor (VHTR and two Pebble-Bed Accelerator Driven Systems (ADSs was evaluated using parameters related to the neutronic behavior such as nuclear fuel breeding, minor actinide stockpile, the energetic contribution of each fissile isotope, and the radiotoxicity of the long lived wastes. These parameters were used to compare the fuel cycles using the well-known MCNPX ver. 2.6e computational code. The results obtained confirm that the 232Th-233U fuel cycle is the best cycle for minimizing the production of plutonium isotopes and minor actinides. Moreover, the inclusion of the second stage in the ADSs demonstrated the possibility of extending the burnup cycle duration and reducing the radiotoxicity of the discharged fuel from the VHTR.

  13. Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater. (United States)

    Shore, Jennifer L; M'Coy, William S; Gunsch, Claudia K; Deshusses, Marc A


    This study examines the use of a moving bed biofilm reactor (MBBR) as a tertiary treatment step for ammonia removal in high temperature (35-45°C) effluents, and quantifies different phenotypes of ammonia and nitrite oxidizing bacteria responsible for nitrification at elevated temperatures. Bench scale reactors operating at 35 and 40°C were able to successfully remove greater than 90% of the influent ammonia (up to 19 mg L(-1) NH(3)-N) in both the synthetic and industrial wastewater. No biotreatment was observed at 45°C, although effective nitrification was rapidly recovered when the temperature was lowered to 30°C. Using qPCR, Nitrosomonas oligotropha was found to be the dominant ammonia oxidizing bacterium in the biofilm for the first phases of reactor operation. In the later phases, Nitrosomonas nitrosa was observed and its increased presence may have been responsible for improved ammonia treatment efficiency. Accumulation of nitrite in some instances appeared to correlate with temporary low presence of Nitrospira spp.

  14. Sustainability of thorium-uranium in pebble-bed fluoride salt-cooled high temperature reactor

    Directory of Open Access Journals (Sweden)

    Zhu Guifeng


    Full Text Available Sustainability of thorium fuel in a Pebble-Bed Fluoride salt-cooled High temperature Reactor (PB-FHR is investigated to find the feasible region of high discharge burnup and negative Flibe (2LiF-BeF2 salt Temperature Reactivity Coefficient (TRC. Dispersion fuel or pellet fuel with SiC cladding and SiC matrix is used to replace the tristructural-isotropic (TRISO coated particle system for increasing fuel loading and decreasing excessive moderation. To analyze the neutronic characteristics, an equilibrium calculation method of thorium fuel self-sustainability is developed. We have compared two refueling schemes (mixing flow pattern and directional flow pattern and two kinds of reflector materials (SiC and graphite. This method found that the feasible region of breeding and negative Flibe TRC is between 20 vol% and 62 vol% fuel loading in the fuel. A discharge burnup could be achieved up to about 200 MWd/kgHM. The case with directional flow pattern and SiC reflector showed superior burnup characteristics but the worst radial power peak factor, while the case with mixing flow pattern and SiC reflector, which was the best tradeoff between discharge burnup and radial power peak factor, could provide burnup of 140 MWd/kgHM and about 1.4 radial power peak factor with 50 vol% dispersion fuel. In addition, Flibe salt displays good neutron properties as a coolant of quasi-fast reactors due to the strong 9Be(n,2n reaction and low neutron absorption of 6Li (even at 1000 ppm in fast spectrum. Preliminary thermal hydraulic calculation shows good safety margin. The greatest challenge of this reactor may be the decades irradiation time of the pebble fuel.

  15. A kinetic study of gaseous potassium capture by coal minerals in a high temperature fixed-bed reactor

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Peter Arendt; Jensen, Anker Degn


    The reactions between gaseous potassium chloride and coal minerals were investigated in a lab-scale high temperature fixed-bed reactor using single sorbent pellets. The applied coal minerals included kaolin, mullite, silica, alumina, bituminous coal ash, and lignite coal ash that were formed...

  16. Analysis of Fluid Flow and Heat Transfer Model for the Pebble Bed High Temperature Gas Cooled Reactor

    Directory of Open Access Journals (Sweden)

    S. Yamoah


    Full Text Available The pebble bed type high temperature gas cooled nuclear reactor is a promising option for next generation reactor technology and has the potential to provide high efficiency and cost effective electricity generation. The reactor unit heat transfer poses a challenge due to the complexity associated with the thermalflow design. Therefore to reliably simulate the flow and heat transport of the pebble bed modular reactor necessitates a heat transfer model that deals with radiation as well as thermal convection and conduction. In this study, a model with the capability to simulate fluid flow and heat transfer in the pebble bed modular reactor core has been developed. The developed model was implemented on a personal computer using FORTRAN 95 programming language. Several important fluid flow and heat transfer parameters have been examined: including the pressure drop over the reactor core, the heat transfer coefficient, the Nusselt number and the effective thermal conductivity of the fuel pebbles. Results obtained from the simulation experiments show a uniform pressure in the radial direction for a core to fuel element diameter (D/d ratio>20 and the heat transfer coefficient increases with increasing temperature and coolant mass flow rate. The model can adequately account for the flow and heat transfer phenomenon and the loss of pressure through friction in the pebble bed type high temperature nuclear reactor.

  17. Experimental Study on an On-Line Measurement of High Temperature Circulating Ash Flux in a Circulating Fluidized Bed Boiler

    Institute of Scientific and Technical Information of China (English)

    Lu Xiaofeng; Li Yourong


    A new kind of measuring method that may be used to measure high temperature circulating solid particles flux in a circulating fluidized bed boiler is studied in this paper. The measuring method is founded on the principle of thermal equilibrium. A series of cold tests and hot tests were carried to optimize the structure and collocation of water-cooling tubes and showed that the method had the advantage of simple, accurate, reliable and good applicability for on-line usage in a circulating fluidized bed boiler.

  18. Very High Temperature Reactor (VHTR) Deep Burn Core and Fuel Analysis -- Complete Design Selection for the Pebble Bed Reactor

    Energy Technology Data Exchange (ETDEWEB)

    B. Boer; A. M. Ougouag


    The Deep-Burn (DB) concept focuses on the destruction of transuranic nuclides from used light water reactor fuel. These transuranic nuclides are incorporated into TRISO coated fuel particles and used in gas-cooled reactors with the aim of a fractional fuel burnup of 60 to 70% in fissions per initial metal atom (FIMA). This high performance is expected through the use of multiple recirculation passes of the fuel in pebble form without any physical or chemical changes between passes. In particular, the concept does not call for reprocessing of the fuel between passes. In principle, the DB pebble bed concept employs the same reactor designs as the presently envisioned low-enriched uranium core designs, such as the 400 MWth Pebble Bed Modular Reactor (PBMR-400). Although it has been shown in the previous Fiscal Year (2009) that a PuO2 fueled pebble bed reactor concept is viable, achieving a high fuel burnup, while remaining within safety-imposed prescribed operational limits for fuel temperature, power peaking and temperature reactivity feedback coefficients for the entire temperature range, is challenging. The presence of the isotopes 239-Pu, 240-Pu and 241-Pu that have resonances in the thermal energy range significantly modifies the neutron thermal energy spectrum as compared to a ”standard,” UO2-fueled core. Therefore, the DB pebble bed core exhibits a relatively hard neutron energy spectrum. However, regions within the pebble bed that are near the graphite reflectors experience a locally softer spectrum. This can lead to power and temperature peaking in these regions. Furthermore, a shift of the thermal energy spectrum with increasing temperature can lead to increased absorption in the resonances of the fissile Pu isotopes. This can lead to a positive temperature reactivity coefficient for the graphite moderator under certain operating conditions. The effort of this task in FY 2010 has focused on the optimization of the core to maximize the pebble discharge

  19. Pebble Bed Reactors Design Optimization Methods and their Application to the Pebble Bed Fluoride Salt Cooled High Temperature Reactor (PB-FHR) (United States)

    Cisneros, Anselmo Tomas, Jr.

    The Fluoride salt cooled High temperature Reactor (FHR) is a class of advanced nuclear reactors that combine the robust coated particle fuel form from high temperature gas cooled reactors, direct reactor auxillary cooling system (DRACS) passive decay removal of liquid metal fast reactors, and the transparent, high volumetric heat capacitance liquid fluoride salt working fluids---flibe (33%7Li2F-67%BeF)---from molten salt reactors. This combination of fuel and coolant enables FHRs to operate in a high-temperature low-pressure design space that has beneficial safety and economic implications. In 2012, UC Berkeley was charged with developing a pre-conceptual design of a commercial prototype FHR---the Pebble Bed- Fluoride Salt Cooled High Temperature Reactor (PB-FHR)---as part of the Nuclear Energy University Programs' (NEUP) integrated research project. The Mark 1 design of the PB-FHR (Mk1 PB-FHR) is 236 MWt flibe cooled pebble bed nuclear heat source that drives an open-air Brayton combine-cycle power conversion system. The PB-FHR's pebble bed consists of a 19.8% enriched uranium fuel core surrounded by an inert graphite pebble reflector that shields the outer solid graphite reflector, core barrel and reactor vessel. The fuel reaches an average burnup of 178000 MWt-d/MT. The Mk1 PB-FHR exhibits strong negative temperature reactivity feedback from the fuel, graphite moderator and the flibe coolant but a small positive temperature reactivity feedback of the inner reflector and from the outer graphite pebble reflector. A novel neutronics and depletion methodology---the multiple burnup state methodology was developed for an accurate and efficient search for the equilibrium composition of an arbitrary continuously refueled pebble bed reactor core. The Burnup Equilibrium Analysis Utility (BEAU) computer program was developed to implement this methodology. BEAU was successfully benchmarked against published results generated with existing equilibrium depletion codes VSOP

  20. Evaluation of dust cake filtration at high temperature with effluence from an atmospheric fluidized-bed combustor

    Energy Technology Data Exchange (ETDEWEB)

    Dennis, R.A.


    In the spring of 1989, two separate test series were simultaneously conducted at the US Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) to examine applied and fundamental behavior of dust cake filtration under high temperature and high pressure (HTHP) conditions. The purpose was to provide information on dust-cake filtration properties to gas stream cleanup researchers associated with the Tidd 70 megawatt (MW) pressurized fluidized-bed combustor (PFBC). The two test facilities included (1) a high-pressure natural-gas combustor with injected particulate, which was fed to two full-size candle filters; and (2) an atmospheric fluidized-bed combustor (AFBC) with coal and limestone sorbent to generate a particulate-laden combustion exhaust gas, which was sent to a single full-size candle filter and a small-scale disc filter. Several major conclusions from these studies are noted below. On average reducing the mean particulate size by 33% and the associated loading carried in the filtrate will increase the dust cake specific flow resistance (K{sub 2}) by 498%. High-temperature and high-pressure filtration can be successfully performed with ceramic candle filters at moderate filtration face velocities and reasonable system pressure drops. Off-line filter cleaning can produce a filter system with a higher apparent permeability than that produced from on-line filter cleaning at the same face velocity. 19 refs., 89 figs., 13 tabs.

  1. Porous cobalt spheres for high temperature gradient magnetically assisted fluidized beds (United States)

    Atwater, James E.; Akse, James R.; Jovanovic, Goran N.; Wheeler, Richard R Jr; Sornchamni, Thana


    Porous metallic cobalt spheres have been prepared as high temperature capable media for employment in gradient magnetically assisted fluidization and filtration technologies. Cobalt impregnated alginate beads are first formed by extrusion of an aqueous suspension of Co3O4 into a Co(II) chloride solution. The organic polymer is thermally decomposed yielding cobalt oxide spheres, followed by reduction to the metallic state, and densification. Cobalt beads have been produced with porosities ranging between 10 and 50%, depending upon sintering conditions. The product media have been characterized by scanning electron microscopy (SEM), nitrogen adsorption porosimetry, and vibrating sample magnetometry. c2003 Elsevier Science Ltd. All rights reserved.

  2. Development and applications of methodologies for the neutronic design of the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) (United States)

    Fratoni, Massimiliano

    This study investigated the neutronic characteristics of the Pebble Bed Advanced High Temperature Reactor (PB-AHTR), a novel nuclear reactor concept that combines liquid salt (7LiF-BeF2---flibe) cooling and TRISO coated-particle fuel technology. The use of flibe enables operation at high power density and atmospheric pressure and improves passive decay-heat removal capabilities, but flibe, unlike conventional helium coolant, is not transparent to neutrons. The flibe occupies 40% of the PB-AHTR core volume and absorbs ˜8% of the neutrons, but also acts as an effective neutron moderator. Two novel methodologies were developed for calculating the time dependent and equilibrium core composition: (1) a simplified single pebble model that is relatively fast; (2) a full 3D core model that is accurate and flexible but computationally intensive. A parametric analysis was performed spanning a wide range of fuel kernel diameters and graphite-to-heavy metal atom ratios to determine the attainable burnup and reactivity coefficients. Using 10% enriched uranium ˜130 GWd/tHM burnup was found to be attainable, when the graphite-to-heavy metal atom ratio (C/HM) is in the range of 300 to 400. At this or smaller C/HM ratio all reactivity coefficients examined---coolant temperature, coolant small and full void, fuel temperature, and moderator temperature, were found to be negative. The PB-AHTR performance was compared to that of alternative options for HTRs, including the helium-cooled pebble-bed reactor and prismatic fuel reactors, both gas-cooled and flibe-cooled. The attainable burnup of all designs was found to be similar. The PB-AHTR generates at least 30% more energy per pebble than the He-cooled pebble-bed reactor. Compared to LWRs the PB-AHTR requires 30% less natural uranium and 20% less separative work per unit of electricity generated. For deep burn TRU fuel made from recycled LWR spent fuel, it was found that in a single pass through the core ˜66% of the TRU can be

  3. Pore Scale Thermal Hydraulics Investigations of Molten Salt Cooled Pebble Bed High Temperature Reactor with BCC and FCC Configurations

    Directory of Open Access Journals (Sweden)

    Shixiong Song


    CFD results and empirical correlations’ predictions of pressure drop and local Nusselt numbers. Local pebble surface temperature distributions in several default conditions are investigated. Thermal removal capacities of molten salt are confirmed in the case of nominal condition; the pebble surface temperature under the condition of local power distortion shows the tolerance of pebble in extreme neutron dose exposure. The numerical experiments of local pebble insufficient cooling indicate that in the molten salt cooled pebble bed reactor, the pebble surface temperature is not very sensitive to loss of partial coolant. The methods and results of this paper would be useful for optimum designs and safety analysis of molten salt cooled pebble bed reactors.

  4. Effects of High-Temperature Preoxidation on the Titanomagnetite Ore Structure and Reduction Behaviors in Fluidized Bed (United States)

    Sun, Haoyan; Adetoro, Ajala Adewole; Pan, Feng; Wang, Zhen; Zhu, Qingshan


    The oxidation behaviors of South Africa (SA) titanomagnetite (TTM) and its effects on the gas solid reduction in the fluidized bed were investigated on the basis of the two-stage short process of direct reduction-electric arc furnace (DR-EAF) melting separation. The results showed that the oxidation phase transformations in the high-temperature range from 1073 K to 1223 K (800 °C to 950 °C) can be divided into two typical processes: with the fast generation of pseudobrookite and with the maghemite generation at the initial stage. The reduction efficiency for SA TTM was improved by the preoxidation treatment, mainly because of the dissociation of titania-ferrous oxides to the easy reducible hematite. However, at a preoxidation temperature higher than 1173 K (900 °C), the improving effect became weak, due to high-temperature sintering and the larger crystallite size of oxidation products. There is an extreme value of the preoxidation influence, and the optimum preoxidation time is different for various temperatures. The reduction metallization degree of SA TTM can be relatively improved by 14.5 and 4.5 pct for the first and second reduction steps, respectively, by 1173 K (900 °C) preoxidation with an optimum time of 30 minutes. Finally, the equilibrium relationship between the metallization degree and the gas reduction potential for TTM ore with preoxidation treatment was built.

  5. Long-term, high frequency in situ measurements of intertidal mussel bed temperatures using biomimetic sensors (United States)

    Helmuth, Brian; Choi, Francis; Matzelle, Allison; Torossian, Jessica L.; Morello, Scott L.; Mislan, K. A. S.; Yamane, Lauren; Strickland, Denise; Szathmary, P. Lauren; Gilman, Sarah E.; Tockstein, Alyson; Hilbish, Thomas J.; Burrows, Michael T.; Power, Anne Marie; Gosling, Elizabeth; Mieszkowska, Nova; Harley, Christopher D. G.; Nishizaki, Michael; Carrington, Emily; Menge, Bruce; Petes, Laura; Foley, Melissa M.; Johnson, Angela; Poole, Megan; Noble, Mae M.; Richmond, Erin L.; Robart, Matt; Robinson, Jonathan; Sapp, Jerod; Sones, Jackie; Broitman, Bernardo R.; Denny, Mark W.; Mach, Katharine J.; Miller, Luke P.; O'Donnell, Michael; Ross, Philip; Hofmann, Gretchen E.; Zippay, Mackenzie; Blanchette, Carol; Macfarlan, J. A.; Carpizo-Ituarte, Eugenio; Ruttenberg, Benjamin; Peña Mejía, Carlos E.; McQuaid, Christopher D.; Lathlean, Justin; Monaco, Cristián J.; Nicastro, Katy R.; Zardi, Gerardo


    At a proximal level, the physiological impacts of global climate change on ectothermic organisms are manifest as changes in body temperatures. Especially for plants and animals exposed to direct solar radiation, body temperatures can be substantially different from air temperatures. We deployed biomimetic sensors that approximate the thermal characteristics of intertidal mussels at 71 sites worldwide, from 1998-present. Loggers recorded temperatures at 10-30 min intervals nearly continuously at multiple intertidal elevations. Comparisons against direct measurements of mussel tissue temperature indicated errors of ~2.0-2.5 °C, during daily fluctuations that often exceeded 15°-20 °C. Geographic patterns in thermal stress based on biomimetic logger measurements were generally far more complex than anticipated based only on ‘habitat-level’ measurements of air or sea surface temperature. This unique data set provides an opportunity to link physiological measurements with spatially- and temporally-explicit field observations of body temperature.

  6. Closed Brayton Cycle power system with a high temperature pellet bed reactor heat source for NEP applications (United States)

    Juhasz, Albert J.; El-Genk, Mohamed S.; Harper, William B., Jr.


    Capitalizing on past and future development of high temperature gas reactor (HTGR) technology, a low mass 15 MWe closed gas turbine cycle power system using a pellet bed reactor heating helium working fluid is proposed for Nuclear Electric Propulsion (NEP) applications. Although the design of this directly coupled system architecture, comprising the reactor/power system/space radiator subsystems, is presented in conceptual form, sufficient detail is included to permit an assessment of overall system performance and mass. Furthermore, an attempt is made to show how tailoring of the main subsystem design characteristics can be utilized to achieve synergistic system level advantages that can lead to improved reliability and enhanced system life while reducing the number of parasitic load driven peripheral subsystems.

  7. Temperature distribution and control in liquefied petroleum gas fluidized beds

    Institute of Scientific and Technical Information of China (English)

    Li Wang; Ping Wu; Yanping Zhang; Jing Yang; Lige Tong


    Temperature distribution and control have been investigated in a liquefied petroleum gas (LPG) fluidized bed with hollow corundum spheres (A12O3) of 0.867-1.212 mm in diameter at moderately high temperatures (800-1100℃). Experiments were carried out for the air consumption coefficient α in the range of 0.3 to 1.0 and the fluidization number N in the range of 1.3 to 3.0. Particle properties, initial bed height, α and N all affect temperature distribution in the bed. Bed temperature can be adjusted about 200℃ by combined the adjusting of α and N.

  8. Development and application of a high-temperature sampling probe for burning chamber conditions of fluidized-bed combustion; Korkean laempoetilan naeytteenottosondin kehittaeminen ja soveltaminen leijukerrospolton tulipesaeolosuhteisiin

    Energy Technology Data Exchange (ETDEWEB)

    Larjava, K.; Paerkkae, M.; Jormanainen, P.; Roine, J.; Paakkinen, K. [VTT Chemistry, Espoo (Finland); Linna, V. [VTT Energy, Jyvaeskylae (Finland)


    A sampling probe for the burning chamber conditions of fluidized-bed combustion will be developed in this project. The probe will be suitable for sampling vaporous heavy and alkali metals and other condensing compounds (e.g. chlorides) as well combustion gases and alternatively also flue gas particles at high temperatures. The knowledge gained with the probe will help understanding, developing and modeling combustion processes and will thus aid the manufacturers of the boilers. (author)

  9. Carbon Dioxide Captured from Flue Gas by Modified Ca-based Sorbents in Fixed-bed Reactor at High Temperature

    Institute of Scientific and Technical Information of China (English)

    YANG Lei; YU Hongbing; WANG Shengqiang; WANG Haowen; ZHOU Qibin


    Four kinds of Ca-based sorbents were prepared by calcination and hydration reactions using different precursors: calcium hydroxide,calcium carbonate,calcium acetate monohydrate and calcium oxide.The CO2 absorption capacity of those sorbents was investigated in a fixed-bed reactor in the temperature range of 350 650 ℃.It was found that all of those sorbents showed higher capacity for CO2 absorption when the operating temperature higher than 450 ℃.The CaAc2-CaO sorbent showed the highest CO2 absorption capacity of 299 mg·g-1.The morphology of those sorbents was examined by scanning electron microscope(SEM),and the changes of composition before and after carbonation were also determined by X-ray diffraction(XRD).Results indicated that those sorbents have the similar chemical compositions and crystalline phases before carbonation reaction [mainly Ca(OH)2],and CaCO3 is the main component after carbonation reaction.The SEM morphology shows clearly that the sorbent pores were filled with reaction products after carbonation reaction,and became much denser than before.The N2 adsorption-desorption isotherms indicated that the CaAc2-CaO and CaCO3-CaO sorbents have higher specific surface area,larger pore volume and appropriate pore size distribution than that of CaO-CaO and Ca(OH)2-CaO.

  10. Development and application of a high-temperature sampling probe for burning chamber conditions in fluidized-bed combustion; Korkean laempoetilan naeytteenottosondin kehittaeminen ja soveltaminen leijukerrospolton tulipesaeolosuhteisiin

    Energy Technology Data Exchange (ETDEWEB)

    Larjava, K.; Paerkkae, M. [VTT Chemical Technology, Espoo (Finland); Linna, V. [VTT Energy, Jyvaeskylae (Finland). Environmental Technology


    Determination of heavy and alkali metals and other condensing compounds (e.g. chlorides) in combustion chamber conditions is limited by the poor suitability of traditional methods for sampling at high temperatures. IFRF has developed a high-temperature sampling probe for sampling HCN and NH{sub 3}, which has been tested for sampling of NH{sub 3} by Chalmers University of Technology in Sweden. VTT Chemical Technology and Chalmers University of Technology have in their preliminary experiments determined contents of vaporous heavy metals in the combustion chamber of a 12 MW circulating fluidized-bed boiler using this probe. According to the results, the modified probe is suitable for heavy metal determination in combustion chamber. Based on this series of experiments, modification of the probe has been started on the own financing of VTT Chemical Technology and a field measurement was performed in November 1994 to test the present version of the probe. Based on the results of that measurement, the probe has been modified further on as a part of this LIEKKI 2 project. Similar kind of a principle has been applied in the probe which has been developed by VTT Energy during 1994. The probe is built for determination of gas composition of fluidized bed in full-scale boilers. The purpose of this project is to develop and test a sampling probe for fluidized bed combustion. The main advantage of the probe is that condensation losses in sampling due to high temperature gradients can be avoided. Thus, the probe is very suitable for sampling vaporous heavy and alkali metals and other condensing species as well as burning gases and alternatively also solids at high temperatures

  11. Advanced Low-Temperature Fluid Bed Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, J.; Slimane, R.B.; Wangerow, J.R. [Institute of Gas Technology, Des Plaines, IL (United States)


    This paper discusses the results obtained in an ongoing study geared towards developing advanced mixed-metal oxide sorbents for desulfurization of coal-derived fuel gases in the temperature range of 350 to 550{degrees}C. The paper focuses on the study related to the development of durable sorbents suitable for fluidized-bed application and addresses thermodynamic considerations, sulfidation kinetics, regenerability, and the physical and chemical characteristics of a number of novel sorbents.

  12. Numerical Studies of the Gas-Solid Hydrodynamics at High Temperature in the Riser of a Bench-Scale Circulating Fluidized Bed

    Directory of Open Access Journals (Sweden)

    Maximilian J. Hodapp


    Full Text Available The hydrodynamics of circulating fluidized beds (CFBs is a complex phenomenon that can drastically vary depending on operational setup and geometrical configuration. A research of the literature shows that studies for the prediction of key variables in CFB systems operating at high temperature still need to be implemented aiming at applications in energy conversion, such as combustion, gasification, or fast pyrolysis of solid fuels. In this work the computational fluid dynamics (CFD technique was used for modeling and simulation of the hydrodynamics of a preheating gas-solid flow in a cylindrical bed section. For the CFD simulations, the two-fluid approach was used to represent the gas-solid flow with the k-epsilon turbulence model being applied for the gas phase and the kinetic theory of granular flow (KTGF for the properties of the dispersed phase. The information obtained from a semiempirical model was used to implement the initial condition of the simulation. The CFD results were in accordance with experimental data obtained from a bench-scale CFB system and from predictions of the semiempirical model. The initial condition applied in this work was shown to be a viable alternative to a more common constant solid mass flux boundary condition.

  13. Analytical Solution of Fick's Law of the TRISO-Coated Fuel Particles and Fuel Elements in Pebble-Bed High Temperature Gas-Cooled Reactors

    Institute of Scientific and Technical Information of China (English)

    CAO Jian-Zhu; FANG Chao; SUN Li-Feng


    T wo kinds of approaches are built to solve the fission products diffusion models (Fick's equation) based on sphere fuel particles and sphere fuel elements exactly. Two models for homogenous TRISO-coated fuel particles and fuel elements used in pebble-bed high temperature gas-cooled reactors are presented, respectively. The analytica,solution of Fick's equation for fission products diffusion in fuel particles is derived by variables separation.In the fuel element system, a modification of the diffusion coefficient from D to D/r is made to characterize the difference of diffusion rates in distinct areas and it is shown that the Laplace and Hankel transformations are effective as the diffusion coefficient in Fick's equation is dependant on the radius of the fuel element. Both the solutions are useful for the prediction of the fission product behaviors and could be programmed in the corresponding engineering calculations.%@@ Two kinds of approaches are built to solve the fission products diffusion models(Fick's equation) based on sphere fuel particles and sphere fuel elements exactly.Two models for homogenous TRISO-coated fuel particles and fuel elements used in pebble-bed high temperature gas-cooled reactors are presented,respectively.The analytical solution of Fick's equation for fission products diffusion in fuel particles is derived by variables separation.In the fuel element system,a modification of the diffusion coefficient from D to D/r is made to characterize the difference of diffusion rates in distinct areas and it is shown that the Laplace and Hankel transformations are effective as the diffusion coefficient in Fick's equation is dependant on the radius of the fuel element.Both the solutions are useful for the prediction of the fission product behaviors and could be programmed in the corresponding engineering calculations.

  14. One-dimensional modeling of radial heat removal during depressurized heatup transients in modular pebble-bed and prismatic high temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Savage, M.G.


    A one-dimensional computational model was developed to evaluate the heat removal capabilities of both prismatic-core and pebble-bed modular HTGRs during depressurized heatup transients. A correlation was incorporated to calculate the temperature- and neutron-fluence-dependent thermal conductivity of graphite. The modified Zehner-Schluender model was used to determine the effective thermal conductivity of a pebble bed, accounting for both conduction and radiation. Studies were performed for prismatic-core and pebble-bed modular HTGRs, and the results were compared to analyses performed by GA and GR, respectively. For the particular modular reactor design studied, the prismatic HTGR peak temperature was 2152.2/sup 0/C at 38 hours following the transient initiation, and the pebble-bed peak temperature was 1647.8/sup 0/C at 26 hours. These results compared favorably with those of GA and GE, with only slight differences caused by neglecting axial heat transfer in a one-dimensional radial model. This study found that the magnitude of the initial power density had a greater effect on the temperature excursion than did the initial temperature.

  15. Comparison of electron beam and laser beam powder bed fusion additive manufacturing process for high temperature turbine component materials

    Energy Technology Data Exchange (ETDEWEB)

    Dryepondt, Sebastien N [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Pint, Bruce A [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ryan, Daniel [Solar Turbines, Inc., San Diego, CA (United States)


    The evolving 3D printer technology is now at the point where some turbine components could be additive manufactured (AM) for both development and production purposes. However, this will require a significant evaluation program to qualify the process and components to meet current design and quality standards. The goal of the project was to begin characterization of the microstructure and mechanical properties of Nickel Alloy X (Ni-22Cr-18Fe-9Mo) test bars fabricated by powder bed fusion (PBF) AM processes that use either an electron beam (EB) or laser beam (LB) power source. The AM materials produced with the EB and LB processes displayed significant differences in microstructure and resultant mechanical properties. Accordingly, during the design analysis of AM turbine components, the specific mechanical behavior of the material produced with the selected AM process should be considered. Comparison of the mechanical properties of both the EB and LB materials to those of conventionally processed Nickel Alloy X materials indicates the subject AM materials are viable alternatives for manufacture of some turbine components.

  16. The Shandong Shidao Bay 200 MWe High-Temperature Gas-Cooled Reactor Pebble-Bed Module (HTR-PM Demonstration Power Plant: An Engineering and Technological Innovation

    Directory of Open Access Journals (Sweden)

    Zuoyi Zhang


    Full Text Available After the first concrete was poured on December 9, 2012 at the Shidao Bay site in Rongcheng, Shandong Province, China, the construction of the reactor building for the world's first high-temperature gas-cooled reactor pebble-bed module (HTR-PM demonstration power plant was completed in June, 2015. Installation of the main equipment then began, and the power plant is currently progressing well toward connecting to the grid at the end of 2017. The thermal power of a single HTR-PM reactor module is 250 MWth, the helium temperatures at the reactor core inlet/outlet are 250/750 °C, and a steam of 13.25 MPa/567 °C is produced at the steam generator outlet. Two HTR-PM reactor modules are connected to a steam turbine to form a 210 MWe nuclear power plant. Due to China's industrial capability, we were able to overcome great difficulties, manufacture first-of-a-kind equipment, and realize series major technological innovations. We have achieved successful results in many aspects, including planning and implementing R&D, establishing an industrial partnership, manufacturing equipment, fuel production, licensing, site preparation, and balancing safety and economics; these obtained experiences may also be referenced by the global nuclear community.

  17. Control of the Bed Temperature of a Circulating Fluidized Bed Boiler by using Particle Swarm Optimization

    Directory of Open Access Journals (Sweden)

    AYGUN, H.


    Full Text Available Circulating fluidized bed boilers are increasingly used in the power generation due to their higher combustion efficiency and lower pollutant emissions. Such boilers require an effective control of the bed temperature, because it influences the boiler combustion efficiency and the rate of harmful emissions. A Particle-Swarm-Optimization-Proportional-Integrative-Derivative (PSO-PID controller for the bed temperature of a circulating fluidized bed boiler is presented. In order to prove the capability of the proposed controller, its performances are compared at different boiler loads with those of a Fuzzy Logic (FL controller. The simulation results demonstrate some advantages of the proposed controller.

  18. Feasibility study - Lowered bed temperature in Fluidised Bed boilers for waste; Foerstudie - Saenkt baeddtemperatur i FB-pannor foer avfallsfoerbraenning

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik


    Waste incineration generally serves two purposes; 1) dispose of waste and 2) generation of heat and power. In the process of power production from waste fuels, the steam temperatures in super heaters are generally limited by the severe fouling and corrosion that occurs at elevated material temperatures, caused by high concentrations of alkali metals and chloride in the flue gas and fly ash. The overall aim of a continuation of present project is to determine if a reduced temperature of the bed zone in a fluidized bed waste incinerator reduces the amount of alkali chlorides in the flue gas. If so, a reduced bed temperature might enable increased steam temperature in super heaters, or, at unchanged steam temperature, improve the lifespan of the super heaters. The results from the project are of interest for plant owners wishing to improve performance of existing plants. The results may also be used to modify the design of future plants by boiler manufacturers. The aim of present pre-study was to determine how far the bed temperature can be reduced in a waste fired fluidized bed boiler in Boraas while maintaining a stable operation with sufficient combustion temperature in the freeboard to fulfil the directives of waste incineration. A continuation of the project will be based on the results from present study. The work is based on experiments at the test boiler. During the present study, no other measurements were performed apart from some sampling of bed material and ashes at different modes of operation. The experiments show that it is possible to alter the air and recycled flue gas in such a manner that the bed temperature is reduced from about 870 deg C to 700 deg C at 100% load and normal fuel mixture, while fulfilling the directive of 850 deg C at 2 seconds. Within normal variations of the fuel properties, however, the bed temperature increases to somewhat above 700 deg C if the fuel turns dry, while it falls below 650 deg C when the fuel turns wet. With

  19. High power density reactors based on direct cooled particle beds (United States)

    Powell, J. R.; Horn, F. L.

    Reactors based on direct cooled High Temperature Gas Cooled Reactor (HTGR) type particle fuel are described. The small diameter particle fuel is packed between concentric porous cylinders to make annular fuel elements, with the inlet coolant gas flowing inwards. Hot exit gas flows out along the central channel of each element. Because of the very large heat transfer area in the packed beds, power densities in particle bed reactors (PBRs) are extremely high resulting in compact, lightweight systems. Coolant exit temperatures are high, because of the ceramic fuel temperature capabilities, and the reactors can be ramped to full power and temperature very rapidly. PBR systems can generate very high burst power levels using open cycle hydrogen coolant, or high continuous powers using closed cycle helium coolant. PBR technology is described and development requirements assessed.

  20. Experimental study on temperature characteristics and energy conversion in packed bed reactor with dielectric barrier discharge (United States)

    Li, Sen; Tang, Zuchen; Gu, Fan


    The temperature characteristics and energy conversion in packed bed reactor combined with a dielectric barrier discharge (DBD) plasma was investigated experimentally. The pellet temperatures of two types packed bed reactor, cylindrical reactor and parallel-plate reactor, was measured in conditions of various inlet voltage of DBD plasma. The relationship between pellet temperature of the packed bed and applied voltage of DBD plasma was discovered. The experimental result indicates a tendency that the pellet temperature of packed bed increases as the applied voltage of inlet plasma increases. When the voltage of inlet plasma is high enough, the pellet temperature increment decreases. Simultaneously,the packed bed temperature is sensitive to the inlet plasma energy and there is a potential application to heat exchanger. Moreover the proportion of energy consumption of plasma inputting into packed bed reactor was analyzed and calculated. The mechanisms that electrical energy of inlet plasma is transformed into heat energy in the two phases, gaseous and pellets of the packed bed reactor are different. The energy consumption in pellet phase is dielectric polarization loss and depends on packed bed geometry and DBD plasma etc. The energy consumption in gaseous phase is plasma sheath procedure. The important factors effecting on gas discharge are gaseous component and voltage, frequency of power.

  1. Biomass staged-gasification characteristics in high-temperature entrained-flow bed%生物质高温气流床分级气化特性

    Institute of Scientific and Technical Information of China (English)

    陈超; 周劲松; 项阳阳; 顾珊; 骆仲泱


    为了满足生物质间接液化中对合成气组成的要求,特别是H2与CO体积比要达到1.0~2.0,采用生物质低温热解炉结合高温气流床的生物质分级气化系统,研究气流床分级气化方式对生物质气化合成气的影响.针对温度、一次气化时间等因素,研究合成气组分、H2与CO体积比、碳转化率、气化效率以及焦油质量浓度等方面的变化情况.结果表明,生物质分级气化和温度的升高均能够提高 H2与CO体积比.生物质分级气化系统的最佳工况是一次气化时间为0.6 s ,当气化温度为1100℃时,此时气化效果最好,气化效率达到75%,H2与CO体积比可达1.22,碳转化率达到96.3%.分级气化合成气中焦油质量浓度比传统气化明显减少,从5.46 g/m3降低到了50 mg/m3.%The raw material requirements for the indirect liquefaction of biomass are strict .The volume ratio of H2 to CO must be greater than or equal to 1 .0~2 .0 .The effect on biomass gasification syngas in staged‐gasification of biomass was analyzed .Biomass staged‐gasification system contained low temperature biomass pyrolysis furnace and high temperature entrained‐flow bed . Influence factors were studied including gasification temperature and first gasification time . T he result investigation contained composition of syngas ,volume ratio of H2 to CO ,carbon conversion ratio ,gasification efficiency and tar mass concentration . Results show that staged‐gasification and increasing temperature can enhance the volume ratio of H2 to CO .The optimum condition of staged gasification was the first gasification time at 0 .6 s and gasification temperature at 1 100 ℃ . The result was best in the conditions . Gasification efficiency was up to 75% ,the volume ratio of H2 to CO reached the maximum at 1 .22 ,and carbon conversion was up to 96 .3% .The tar mass concentration was decreased from 5 .46 g/m3 to 50 mg/m3 .

  2. Behavior of Alkali Metals and Ash in a Low-Temperature Circulating Fluidized Bed (LTCFB) Gasifier

    DEFF Research Database (Denmark)

    Narayan, Vikas; Jensen, Peter Arendt; Henriksen, Ulrik Birk


    A low-temperature circulating fluidized bed system (LTCFB) gasifier allows for pyrolysis and gasification to occurat low temperatures, thereby improving the retention of alkali and other inorganic elements within the system and minimizingthe amount of ash species in the product gas. In addition......, the low reactor temperature ensures that high-alkali biomass fuels canbe used without risk of bed defluidization. This paper presents the first investigation of the fate of alkali metals and ash in lowtemperaturegasifiers. Measurements on bed material and product gas dust samples were made on a 100 k...

  3. 球床高温气冷堆闭式循环特性%Characteristics of closed fuel cycles in the pebble bed high temperature gas cooled reactor

    Institute of Scientific and Technical Information of China (English)

    位金锋; 孙玉良; 李富


    The reuse of uranium and plutonium from high temperature gas-cooled reactor(HTGR) spent fuel will improve resource usage and minimize waste.The characteristics of different closed fuel cycles were studied here for uranium and plutonium recycled from 250 MWth high-temperature gas-cooled reactor pebble-bed-module(HTR-PM) spent fuel from a U-Pu fueled core.PuO2 and MOX fuel elements using recycled plutonium and uranium were then used in new PuO2 or MOX fueled cores with the same geometry as the original reactor.PuO2 from LWR spent fuel was also evaluated.The characteristics of the fuel utilization and transuranic incineration in these closed fuel cycles were studied with the VSOP program.The natural uranium utilization closed fuel for these closed fuel cycle is increased by 6%,8% and 20%,while the plutonium burn rates are 40%,41% and 63%,respectively.Thus,these HTGR closed fuel cycles can effectively burn plutonium isotopes and increase natural uranium utilization.%从提高天然铀利用率和改进废物管理方面考虑,研究球床高温气冷堆乏燃料中铀钚的再利用和不同闭式燃料循环的特性。在250MW热功率球床模块式高温气冷堆示范电站铀钚循环的乏燃料中提取铀和钚为核燃料,设计了PuO2和混合氧化物(MOX)燃料元件,将新设计的燃料元件重新装入与示范电站有同样结构和尺寸的堆芯,分别形成纯钚燃料循环和MOX燃料循环。还研究了基于轻水堆级钚的燃料循环。采用了高温气冷堆物理设计程序VSOP,研究了高温气冷堆不同闭式循环的燃料利用和超铀元素焚烧特性。不同闭式循环钚消耗率分别为50%、46%和71%,天然铀的电利用率分别提高了6%、8%和20%。结果表明:高温气冷堆闭式燃料循环能有效焚烧钚同位素,适度提高天然铀的利用率。

  4. COPROX fixed bed reactor - temperature control schemes

    Energy Technology Data Exchange (ETDEWEB)

    Giunta, P.; Moreno, M.; Marino, F.; Amadeo, N.; Lobarde, M. [Laboratorio de Procesos Cataliticos, Facultad de Ingenieria, Universidad de Buenos Aires, Buenos Aires (Argentina)


    Different temperature control schemes for the COPROX stage of a 5-kW fuel cell system were analyzed. It was found that, among the schemes proposed, i.e., co- and countercurrent heat exchange, single adiabatic reactor and series of adiabatic reactors with interstage heat exchange, the best choice for temperature control was the series of adiabatic reactors with interstage heat exchange. This scheme represented the best way to keep the average temperature around 443 K, which was found to be the most suitable temperature for selectivity towards CO oxidation. If hydrogen is produced from ethanol steam reforming, the heat withdrawal can be carried out by the water/ethanol reformer feed mixture, thus contributing to the energy integration of the overall system. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. The impact of bed temperature on heat transfer characteristic between fluidized bed and vertical rifled tubes (United States)

    Blaszczuk, Artur; Nowak, Wojciech


    In the present work, the heat transfer study focuses on assessment of the impact of bed temperature on the local heat transfer characteristic between a fluidized bed and vertical rifled tubes (38mm-O.D.) in a commercial circulating fluidized bed (CFB) boiler. Heat transfer behavior in a 1296t/h supercritical CFB furnace has been analyzed for Geldart B particle with Sauter mean diameter of 0.219 and 0.246mm. The heat transfer experiments were conducted for the active heat transfer surface in the form of membrane tube with a longitudinal fin at the tube crest under the normal operating conditions of CFB boiler. A heat transfer analysis of CFB boiler with detailed consideration of the bed-to-wall heat transfer coefficient and the contribution of heat transfer mechanisms inside furnace chamber were investigated using mechanistic heat transfer model based on cluster renewal approach. The predicted values of heat transfer coefficient are compared with empirical correlation for CFB units in large-scale.

  6. 高温气冷堆球床等效导热系数实验研究进展%Progress in Pebble Bed Heat Transfer Test Facility of High Temperature Gas-cooled Reactor

    Institute of Scientific and Technical Information of China (English)

    任成; 杨星团; 李聪新; 孙艳飞


    Pebble bed effective thermal conductivity of the reactor core is a vital parameter which directly affects the maximum temperature of fuel and the temperature distribution of reactor core in high temperature gas-cooled reactor and plays a dominant role in afterheat removal. The experimental research of pebble bed effective thermal conductivity is helpful for improving the reactor analytical program, increasing the power of single reactor and the safe analysis of projects. The experiments and results of pebble bed effective thermal conductivity measurement at home and abroad are reviewed. The develop direction is also discussed.%堆芯球床等效导热系数是直接影响高温气冷堆燃料最高温度和堆芯温度分布的关键参数;在余热导出过程中起主导作用.开展球床等效导热系数的实验研究对于反应堆分析程序的完善、研究提高高温气冷堆单堆功率的可能性、以及工程的安全分析具有重要的意义.综述了国内外球床等效导热系数测量的研究现状,给出了清华大学HTR-PM三维堆芯球床等效导热系数测量实验最新成果,总结了各国实验的研究手段,对研究方向进行了讨论.

  7. Temperature and Time Requirements for Controlling Bed Bugs (Cimex lectularius under Commercial Heat Treatment Conditions

    Directory of Open Access Journals (Sweden)

    Stephen A. Kells


    Full Text Available Developing effective alternative approaches for disinfesting bed bugs from residential spaces requires a balance between obtaining complete insect mortality, while minimizing costs and energy consumption. One method of disinfestation is the application of lethal high temperatures directly to rooms and contents within a structure (termed whole-room heat treatments. However, temperature and time parameters for efficacy in whole-room heat treatments are unknown given the slower rate of temperature increase and the probable variability of end-point temperatures within a treated room. The objective of these experiments was to explore requirements to produce maximum mortality from heat exposure using conditions that are more characteristic of whole-room heat treatments. Bed bugs were exposed in an acute lethal temperature (LTemp trial, or time trials at sub-acute lethal temperatures (LTime. The lethal temperature (LTemp99 for adults was 48.3 °C, while LTemp99 for eggs was 54.8 °C. Adult bed bugs exposed to 45 °C had a LTime99 of 94.8 min, while eggs survived 7 h at 45 °C and only 71.5 min at 48 °C. We discuss differences in exposure methodologies, potential reasons why bed bugs can withstand higher temperatures and future directions for research.

  8. Development of Burnup Calculation Code for Pebble-bed High Temperature Reactor at Equilibrium State%球床高温堆平衡态燃耗计算程序的开发

    Institute of Scientific and Technical Information of China (English)

    朱贵凤; 邹杨; 李明海; 严睿; 彭红花; 徐洪杰


    The burnup calculation code PBRE coupling MCNP5 and ORIGEN2 was developed for pebble‐bed high temperature reactor at equilibrium state ,and it can be used to analyze the neutronic performance of equilibrium core .The iteration method was optimized in order to save Monte Carlo calculation time ,and the convergence can be reached in 10 iterative steps .The average discharged burnup for HTR‐10 is consistent with literature ,and it indicates that the PBRE is suitable to analyze the burnup for pebble‐bed reactor at equilibrium state .%基于MCNP5和ORIGEN2耦合方法,开发了平衡态下球床高温堆的燃耗计算程序PBRE ,用于堆的性能价值分析。为节省蒙特卡罗计算时间,对迭代收敛的方法进行优化,使之可在10个迭代步内收敛。使用PBRE对清华大学H T R‐10进行建模计算,得到的平均卸料燃耗深度与文献报道值一致,表明PBRE程序适用于球床堆平衡态的燃耗分析。

  9. Modelling of HTR (High Temperature Reactor Pebble-Bed 10 MW to Determine Criticality as A Variations of Enrichment and Radius of the Fuel (Kernel With the Monte Carlo Code MCNP4C

    Directory of Open Access Journals (Sweden)

    Hammam Oktajianto


    Full Text Available Gas-cooled nuclear reactor is a Generation IV reactor which has been receiving significant attention due to many desired characteristics such as inherent safety, modularity, relatively low cost, short construction period, and easy financing. High temperature reactor (HTR pebble-bed as one of type of gas-cooled reactor concept is getting attention. In HTR pebble-bed design, radius and enrichment of the fuel kernel are the key parameter that can be chosen freely to determine the desired value of criticality. This paper models HTR pebble-bed 10 MW and determines an effective of enrichment and radius of the fuel (Kernel to get criticality value of reactor. The TRISO particle coated fuel particle which was modelled explicitly and distributed in the fuelled region of the fuel pebbles using a Simple-Cubic (SC lattice. The pebble-bed balls and moderator balls distributed in the core zone using a Body-Centred Cubic lattice with assumption of a fresh fuel by the fuel enrichment was 7-17% at 1% range and the size of the fuel radius was 175-300 µm at 25 µm ranges. The geometrical model of the full reactor is obtained by using lattice and universe facilities provided by MCNP4C. The details of model are discussed with necessary simplifications. Criticality calculations were conducted by Monte Carlo transport code MCNP4C and continuous energy nuclear data library ENDF/B-VI. From calculation results can be concluded that an effective of enrichment and radius of fuel (Kernel to achieve a critical condition was the enrichment of 15-17% at a radius of 200 µm, the enrichment of 13-17% at a radius of 225 µm, the enrichments of 12-15% at radius of 250 µm, the enrichments of 11-14% at a radius of 275 µm and the enrichment of 10-13% at a radius of 300 µm, so that the effective of enrichments and radii of fuel (Kernel can be considered in the HTR 10 MW. Keywords—MCNP4C, HTR, enrichment, radius, criticality 

  10. 球床式高温气冷堆的余热不确定性分析%Uncertainty Analysis on Decay Heat of Pebble-bed High Temperature Gas-cooled Reactor

    Institute of Scientific and Technical Information of China (English)

    贠相羽; 郑艳华; 经荥清; 李富


    反应堆在停堆后相当长时间内仍具有较高的剩余发热是核电站的重要特性,也是核电站安全分析的关键.因此,对反应堆余热及其不确定性进行分析,对于合理设计余热排出系统、研究论证燃料元件在事故后的安全特性等均具有重要意义.本工作结合德国针对球床式高温气冷堆制定的余热计算标准,介绍了球床式高温气冷堆剩余发热及其不确定性的计算方法,并结合200 MWe球床模块式高温气冷堆示范工程(HTR-PM)的初步物理设计,对长期运行在满功率平衡堆芯状态下的反应堆停堆后的余热及其不确定性进行了计算分析,为进一步的事故分析提供依据.%The large amount of decay heat in a quite long time after reactor shutdown,which is an important characteristic of the nuclear power plants,should be considered seriously during the safety analysis.Therefore,the study on the decay heat and its uncertainty analysis play an important role in the design of decay heat removal system,as well as in the safety verification of the fuel element during the accident.In referenced to the standard of Germany entitled "Decay Heat Power in Nuclear Fuels of Hightemperature Reactors with Spherical Fuel Elements" especially for pebble-bed high temperature gas-cooled reactor (HTGR),the calculation method of decay heat and its uncertainty of pebble-bed HTGR were introduced.On the basis of the preliminary physical design of Chinese 200 MWe high temperature gas-cooled reactor pebble-bed module (HTR-PM),the decay heat and its uncertainty after reactor shutdown from long-term operation at rated power were analyzed,so as to provide a basis for further accident analysis.

  11. High Temperature Materials Laboratory (United States)

    Federal Laboratory Consortium — The High Temperature Materials Lab provides the Navy and industry with affordable high temperature materials for advanced propulsion systems. Asset List: Arc Melter...

  12. Ash behavior and de-fluidization in low temperature circulating fluidized bed biomass gasifier

    DEFF Research Database (Denmark)

    Narayan, Vikas

    -Temperature Circulating Fluidized Bed System (LTCFB) gasifier allows pyrolysis and gasification of biomass to occur at low temperatures thereby improving the retention of alkali and other ash species within the system and minimizing the amount of ash species in the product gas. In addition, the low reactor temperature......Biomass is increasingly used as a fuel for power generation. Herbaceous fuels however, contain high amounts of alkali metals which get volatilized at high temperatures and forms salts with low melting points and thus condense on pipelines, reactor surfaces and may cause de-fluidization. A Low...... at Risø and a 6 MW LTCFB gasifier owned by DONG ENERGY and placed in Kalundborg. In addition to the analysis of the inorganic elemental composition of the collected samples, SEM and TGA analysis of the samples were made to improve understanding on the behavior of the ash forming species within the system...

  13. Temperature control of electronic components using fluidised beds (United States)

    Bean, R.


    This paper introduces the concept of fluidized bed cooling applied to electronic systems. It is shown that, when fluidized with air, the cooling efficiency and the pumping power are principally dependent on particle characteristics; in particular the mean diameter should not be less than 100 microns. Design rules are developed and applied to two types of fluid-bed systems: (1) a small bed of alumina particles cooling single devices of 40 W power dissipation where the fluidizing air is the main heat transporting medium, and (2) a large bed of cenospheres with a simple integrated heat exchanger to extract more than 1 KW of heat from complete sub-rack assemblies of up to 40 printed circuit boards, for a fluidizing power of about 3 W. The effect of board spacing on the overall thermal performance is considered, and a minimum spacing of 10-20 mm is shown to be required to maintain cooling efficiency.


    Energy Technology Data Exchange (ETDEWEB)

    Williams, M


    Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.


    Institute of Scientific and Technical Information of China (English)

    Xu Longxiang; Zhang Jinyu; Schweitzer Gerhard


    A high temperature displacement sensor based on the principle of eddy-current is investigated. A new temperature compensation technique by using eddy-current effect is presented to satisfy the special requirement at high temperature up to 550℃. The experiment shows that the temperature compensation technique leads to good temperature stability for the sensors. The variation of the sensitivity as well as the temperature drift of the sensor with temperature compensation technique is only about 7.4% and 90~350 mV at 550℃ compared with that at room temperature, and that of the sensor without temperature compensation technique is about 31.2% and 2~3 V at 550℃ compared with that at room temperature. A new dynamic calibration method for the eddy-current displacement sensor is presented, which is very easy to be realized especially in high frequency and at high temperatures. The high temperature displacement sensors developed are successfully used at temperature up to 550℃ in a magnetic bearing system for more than 100 h.

  16. Experimental Study of Integrated Ebullated-bed and Fixed-bed for Hydrotreating Mid-Low Temperature Coal Tar to Clean Fuel

    Institute of Scientific and Technical Information of China (English)

    Meng Zhaohui; Yang Tao; Fang Xiangchen


    A new hydrotreating technology integrating the ebullated-bed (EB) and the fixed-bed (FB) hydrogenation was proposed to investigate the efficiency for hydrotreating mid- low-temperature coal tar to clean fuel, and multiple tests at the bench scale were carried out. The results showed that the distillates obtained from EB reactors were greatly upgraded and could meet the requirements of FB unit without discarding any tail oil. The naphtha produced from FB reactors could be fed to the catalytic reforming unit, while a high quality diesel was also obtained. The unconverted oil (UCO) could be fur-ther hydrocracked to clean fuel. It is found that the removal of impurities from the coal tar oil is related with the molecular aggregation structure and composition of the coal tar. Application of the integrated hydrotreating technology to the high-temperature coal tar processing demonstrated that more than half of heavy components could be effectively upgraded.

  17. High-Temperature Superconductivity (United States)

    Tanaka, Shoji


    A general review on high-temperature superconductivity was made. After prehistoric view and the process of discovery were stated, the special features of high-temperature superconductors were explained from the materials side and the physical properties side. The present status on applications of high-temperature superconductors were explained on superconducting tapes, electric power cables, magnets for maglev trains, electric motors, superconducting quantum interference device (SQUID) and single flux quantum (SFQ) devices and circuits.

  18. Highly efficient high temperature electrolysis

    DEFF Research Database (Denmark)

    Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard;


    High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... internal resistance of the cell, and long-term stable, it is critical to develop electrode materials that are optimal for steam electrolysis. In this article electrolysis cells for electrolysis of water or steam at temperatures above 200 degrees C for production of H-2 are reviewed. High temperature...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...

  19. Effect of char preparation temperature on the evolution of nitrogen-containing species during char oxidation at fluidized bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ren, W.; Lu, J.; Yue, G. [Tsinghua Univ., Beijing (China). Dept. of Thermal Engineering; Beer, J.M. [Massachusetts Inst. of Technology, Boston, MA (United States). Dept. of Chemical and Fuel Engineering; Molina, A.; Sarofim, A.F. [Utah Univ., Salt Lake City, UT (United States). Dept. of Chemical and Fuels Engineering


    Fluidized bed combustion is gaining popularity as a means to burn coal and waste fuels because the low temperatures of fluidized bed combustors generally result in low thermal nitric oxide (NO) production. However, nitrous oxide (N{sub 2}O) emissions can be relativity high and strategies must be developed to reduce emissions of this greenhouse gas. This paper presents the results of a laboratory study that examined the effect of pyrolysis temperature on the conversion of char-N to N{sub 2}O, NO and hydrogen cyanide (HCN) in fluidized bed combustion. When anthracite coal was used, an increase in the pyrolysis temperature resulted in reduced conversion of char-N to N{sub 2}O and HCN. However, the conversion to NO increased. This observation may be due to the lower hydrogen content of the chars produced at higher temperature and their lower reactivity. Other possibilities may be that the lower char reactivity for chars produced at high pyrolysis temperature may affect the reactions occurring in the boundary layer. Chars of lower reactivity in particular, may react at lower particle temperature and under high transient oxygen concentrations. A simplified char combustion representation was used to examine the effect of temperature and equivalence ratio on HCN oxidation. A reduction of equivalence ratio could explain some of the observed variations in product distribution with increased pyrolysis temperature. 19 refs., 1 tab., 5 figs.

  20. High Power Fiber Laser Test Bed (United States)

    Federal Laboratory Consortium — This facility, unique within DoD, power-combines numerous cutting-edge fiber-coupled laser diode modules (FCLDM) to integrate pumping of high power rare earth-doped...

  1. High temperature battery. Hochtemperaturbatterie

    Energy Technology Data Exchange (ETDEWEB)

    Bulling, M.


    To prevent heat losses of a high temperature battery, it is proposed to make the incoming current leads in the area of their penetration through the double-walled insulating housing as thermal throttle, particularly spiral ones.

  2. High-temperature superconductors

    CERN Document Server

    Saxena, Ajay Kumar


    The present book aims at describing the phenomenon of superconductivity and high-temperature superconductors discovered by Bednorz and Muller in 1986. The book covers the superconductivity phenomenon, structure of high-Tc superconductors, critical currents, synthesis routes for high Tc materials, superconductivity in cuprates, the proximity effect and SQUIDs, theories of superconductivity and applications of superconductors.

  3. High Temperature Capacitor Development

    Energy Technology Data Exchange (ETDEWEB)

    John Kosek


    The absence of high-temperature electronics is an obstacle to the development of untapped energy resources (deep oil, gas and geothermal). US natural gas consumption is projected to grow from 22 trillion cubic feet per year (tcf) in 1999 to 34 tcf in 2020. Cumulatively this is 607 tcf of consumption by 2020, while recoverable reserves using current technology are 177 tcf. A significant portion of this shortfall may be met by tapping deep gas reservoirs. Tapping these reservoirs represents a significant technical challenge. At these depths, temperatures and pressures are very high and may require penetrating very hard rock. Logistics of supporting 6.1 km (20,000 ft) drill strings and the drilling processes are complex and expensive. At these depths up to 50% of the total drilling cost may be in the last 10% of the well depth. Thus, as wells go deeper it is increasingly important that drillers are able to monitor conditions down-hole such as temperature, pressure, heading, etc. Commercial off-the-shelf electronics are not specified to meet these operating conditions. This is due to problems associated with all aspects of the electronics including the resistors and capacitors. With respect to capacitors, increasing temperature often significantly changes capacitance because of the strong temperature dependence of the dielectric constant. Higher temperatures also affect the equivalent series resistance (ESR). High-temperature capacitors usually have low capacitance values because of these dielectric effects and because packages are kept small to prevent mechanical breakage caused by thermal stresses. Electrolytic capacitors do not operate at temperatures above 150oC due to dielectric breakdown. The development of high-temperature capacitors to be used in a high-pressure high-temperature (HPHT) drilling environment was investigated. These capacitors were based on a previously developed high-voltage hybridized capacitor developed at Giner, Inc. in conjunction with a

  4. High Temperature ESP Monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Jack Booker; Brindesh Dhruva


    The objective of the High Temperature ESP Monitoring project was to develop a downhole monitoring system to be used in wells with bottom hole well temperatures up to 300°C for measuring motor temperature, formation pressure, and formation temperature. These measurements are used to monitor the health of the ESP motor, to track the downhole operating conditions, and to optimize the pump operation. A 220 ºC based High Temperature ESP Monitoring system was commercially released for sale with Schlumberger ESP motors April of 2011 and a 250 ºC system with will be commercially released at the end of Q2 2011. The measurement system is now fully qualified, except for the sensor, at 300 °C.

  5. High Temperature Electrolysis

    DEFF Research Database (Denmark)

    Elder, Rachael; Cumming, Denis; Mogensen, Mogens Bjerg


    High temperature electrolysis of carbon dioxide, or co-electrolysis of carbon dioxide and steam, has a great potential for carbon dioxide utilisation. A solid oxide electrolysis cell (SOEC), operating between 500 and 900. °C, is used to reduce carbon dioxide to carbon monoxide. If steam is also...... input to the cell then hydrogen is produced giving syngas. This syngas can then be further reacted to form hydrocarbon fuels and chemicals. Operating at high temperature gives much higher efficiencies than can be achieved with low temperature electrolysis. Current state of the art SOECs utilise a dense...

  6. High Temperature Piezoelectric Drill (United States)

    Bao, Xiaoqi; Scott, James; Boudreau, Kate; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom; Zhang, Shujun


    The current NASA Decadal mission planning effort has identified Venus as a significant scientific target for a surface in-situ sampling/analyzing mission. The Venus environment represents several extremes including high temperature (460 deg C), high pressure (9 MPa), and potentially corrosive (condensed sulfuric acid droplets that adhere to surfaces during entry) environments. This technology challenge requires new rock sampling tools for these extreme conditions. Piezoelectric materials can potentially operate over a wide temperature range. Single crystals, like LiNbO3, have a Curie temperature that is higher than 1000 deg C and the piezoelectric ceramics Bismuth Titanate higher than 600 deg C. A study of the feasibility of producing piezoelectric drills that can operate in the temperature range up to 500 deg C was conducted. The study includes the high temperature properties investigations of engineering materials and piezoelectric ceramics with different formulas and doping. The drilling performances of a prototype Ultrasonic/Sonic Drill/Corer (USDC) using high temperate piezoelectric ceramics and single crystal were tested at temperature up to 500 deg C. The detailed results of our study and a discussion of the future work on performance improvements are presented in this paper.

  7. Incineration of kitchen waste with high nitrogen in vortexing fluidized-bed incinerator and its NO emission characteristics

    Institute of Scientific and Technical Information of China (English)

    Feng Duan; Chiensong Chyang; Jiaruei Wen; Jim Tso


    Some municipal solid waste (MSW) can be used as the fuel.Combustion of MSW with high nitrogen content is successfully conducted in a lab-scale vortexing fluidized-bed incinerator (VFBI).Pigskin with 16.5 wt.% nitrogen content was used to simulate the high nitrogen content kitchen waste,and silica sand was used as the bed material.The effects of operating conditions,such as the bed temperature,freeboard temperature,excess oxygen ratio,and static bed height on the CO and NO concentrations at the exit of combustor and cyclone were investigated.The experimental results show that the freeboard temperature is the most important factor for CO emission.The order of operating conditions impact on the NO emission is:(1) excess oxygen ratio; (2) bed temperature; (3)freeboard temperature; and (4) static bed height.Utilizing cyclone can significantly reduce the CO emission concentration when the CO concentration released from the freeboard is higher than 50 ppm.On the other hand,the cyclone has no significant effect on the NO emission.Despite having high nitrogen content,a low conversion from fuel-N to NO was attained.Compared with other types of combustors,VFBI reduces the CO and NO emission concentrations much better when burning MSW with high nitrogen content.

  8. Incineration of kitchen waste with high nitrogen in vortexing fluidized-bed incinerator and its NO emission characteristics. (United States)

    Duan, Feng; Chyang, Chiensong; Wen, Jiaruei; Tso, Jim


    Some municipal solid waste (MSW) can be used as the fuel. Combustion of MSW with high nitrogen content is successfully conducted in a lab-scale vortexing fluidized-bed incinerator (VFBI). Pigskin with 16.5 wt.% nitrogen content was used to simulate the high nitrogen content kitchen waste, and silica sand was used as the bed material. The effects of operating conditions, such as the bed temperature, freeboard temperature, excess oxygen ratio, and static bed height on the CO and NO concentrations at the exit of combustor and cyclone were investigated. The experimental results show that the freeboard temperature is the most important factor for CO emission. The order of operating conditions impact on the NO emission is: (1) excess oxygen ratio; (2) bed temperature; (3) freeboard temperature; and (4) static bed height. Utilizing cyclone can significantly reduce the CO emission concentration when the CO concentration released from the freeboard is higher than 50 ppm. On the other hand, the cyclone has no significant effect on the NO emission. Despite having high nitrogen content, a low conversion from fuel-N to NO was attained. Compared with other types of combustors, VFBI reduces the CO and NO emission concentrations much better when burning MSW with high nitrogen content.

  9. Discrete particle modeling of granular temperature distribution in a bubbling fluidized bed

    Institute of Scientific and Technical Information of China (English)

    Yurong He; Tianyu Wang; Niels Deen; Martin van Sint Annaland; Hans Kuipers; Dongsheng Wen


    The discrete hard sphere particle model (DPM) is applied in this work to study numerically the distributions of particle and bubble granular temperatures in a bubbling fluidized bed.The dimensions of the bed and other parameters are set to correspond to those of Müller et al.(2008).Various drag models and operational parameters are investigated to find their influence on particle and bubble granular temperatures.Various inlet superficial gas velocities are used in this work to obtain their effect on flow characteristics.It is found that the superficial gas velocity has the most important effect on granular temperatures including bubble granular temperature,particle translational granular temperature and particle rotational granular temperature.The drag force model affects more seriously the large scale variables such as the bubble granular temperature.Restitution coefficient influences all granular temperatures to some degree.Simulation results are compared with experimental results by Müller et al.(2008) showing reasonable agreement.

  10. High temperature storage loop :

    Energy Technology Data Exchange (ETDEWEB)

    Gill, David Dennis; Kolb, William J.


    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  11. Desulfurization at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Panula-Nikkilae, E.; Kurkela, E.; Mojtahedi, W.


    Two high-temperature desulfurization methods, furnace injection and gasification-desulfurization are presented. In furnace injection, the efficiency of desulfurization is 50-60%, but this method is applied in energy production plants, where flue gas desulfurization cannot be used. Ca-based sorbents are used as desulfurization material. Factors affecting desulfurization and the effect of injection on the boiler and ash handling are discussed. In energy production based on gasification, very low sulfur emissions can be achieved by conventional low-temperature cleanup. However, high-temperature gas cleaning leads to higher efficiency and can be applied to smaller size classes. Ca-, Fe-, or Zn-based sorbents or mixed metals can be used for desulfurization. Most of the methods under development are based on the use of regenerative sorbents in a cleanup reactor located outside the gasifier. So far, only calcium compounds have been used for desulfurization inside the gasifier.

  12. Advanced control system for temperature control in the pressurized fluid bed of Escatron Thermal Plant Power; Sistema de Control Avanzado para Control de la Temperatura del Lecho Fluido a Presion de la Central Termica de Escatron

    Energy Technology Data Exchange (ETDEWEB)



    In the P. F-B. C a small problem appears, particularly in Escatron the bed temperature gradient is very high. Such gradient very occasionally reaches 50 degree centigree in a same plane. With the reduction of bed difference of temperature, the average bed temperature could be increased with the result steam cycle benefit, at the same time combustion gases would go at a higher temperature to the gas turbine, increasing therefore its performance. The SCAP system will allow to face the resolution of the injection of combustible problem and in this manner achieve the homogenization of bed temperature in Escatron PFBC Thermal Power Station. (Author)

  13. A Feasibility Study on Low Temperature Thermochemical Treatments of Austenitic Stainless Steel in Fluidized Bed Furnace (United States)

    Haruman, Esa; Sun, Yong; Triwiyanto, Askar; Manurung, Yupiter H. P.; Adesta, Erry Y.


    In this work, the feasibility of using an industrial fluidized bed furnace to perform low temperature thermochemical treatments of austenitic stainless steels has been studied, with the aim to produce expanded austenite layers with combined wear and corrosion resistance, similar to those achievable by plasma and gaseous processes. Several low temperature thermochemical treatments were studied, including nitriding, carburizing, combined nitridingcarburizing (hybrid treatment), and sequential carburizing and nitriding. The results demonstrate that it is feasible to produce expanded austenite layers on the investigated austenitic stainless steel by the fluidized bed heat treatment technique, thus widening the application window for the novel low temperature processes. The results also demonstrate that the fluidized bed furnace is the most effective for performing the hybrid treatment, which involves the simultaneous incorporation of nitrogen and carbon together into the surface region of the component in nitrogen and carbon containing atmospheres. Such hybrid treatment produces a thicker and harder layer than the other three processes investigated.

  14. Experimental study on temperature profile of fixed - bed gasification of oil-palm fronds (United States)

    Atnaw, Samson M.; Sulaiman, Shaharin A.; Moni, M. Nazmi Z.


    Currently the world's second largest palm oil producer Malaysia produces large amount of oil palm biomass each year. The abundance of the biomass introduces a challenge to utilize them as main feedstock for heat and energy generation. Although some oil palm parts and derivatives like empty fruit bunch and fibre have been commercialized as fuel, less attention has been given to oil palm fronds (OPF). Initial feasibility and characterization studies of OPF showed that it is highly feasible as fuel for gasification to produce high value gaseous fuel or syngas. This paper discusses the experimental gasification attempt carried out on OPF using a 50 kW lab scale downdraft gasifier and its results. The conducted study focused on the temperature distributions within the reactor and the characteristics of the dynamic temperature profile for each temperature zones during operation. OPF feedstock of one cubic inch in individual size with 15% average moisture content was utilized. An average pyrolysis zone temperature of 324°Cand an average oxidation zone temperature of 796°Cwere obtained over a total gasification period of 74 minutes. A maximum oxidation zone temperature of 952°Cwas obtained at 486 lpm inlet air flow rate and 10 kg/hr feedstock consumption rate. Stable bluish flare was produced for more than 70% of the total gasification time. The recorded temperature profiles produced closely similar patterns with the temperature profiles recorded from the gasification of woody materials. Similar temperature profile was obtained comparing the results from OPF gasification with that of woody biomass. Furthermore, the successful ignition of the syngas produced from OPF gasification ascertained that OPF indeed has a higher potential as gasification feedstock. Hence, more detailed studies need to be done for better understanding in exploiting the biomass as a high prospect alternative energy solution. In addition, a study of the effect of initial moisture content of OPF

  15. Application of Distributed Temperature Sensing for coupled mapping of sedimentation processes and spatio-temporal variability of groundwater discharge in soft-bedded streams

    DEFF Research Database (Denmark)

    Sebök, Éva; Calvache, Carlos Duque; Engesgaard, Peter Knudegaard;


    -induced temperature anomalies resemble the signal of groundwater discharge while scouring will cause the cable to float in the water column and measure stream water temperatures. DTS applied in a looped layout with nine fibre optic cable rows in a 70 × 5 m section of a soft-bedded stream made it possible to detect......The delineation of groundwater discharge areas based on Distributed Temperature Sensing (DTS) data of the streambed can be difficult in soft-bedded streams where sedimentation and scouring processes constantly change the position of the fibre optic cable relative to the streambed. Deposition...... on the simultaneous interpretation of streambed temperature and elevation data, a method is proposed to delineate potential high-groundwater discharge areas and identify deposition-induced temperature anomalies in soft-bedded streams. Potential high-discharge sites were detected using as metrics the daily minimum...

  16. High temperature superconducting compounds (United States)

    Goldman, Allen M.


    The major accomplishment of this grant has been to develop techniques for the in situ preparation of high-Tc superconducting films involving the use of ozone-assisted molecular beam epitaxy. The techniques are generalizable to the growth of trilayer and multilayer structures. Films of both the DyBa2Cu3O(7-x) and YBa2Cu3O(7-x) compounds as well as the La(2-x)Sr(x)CuO4 compound have been grown on the usual substrates, SrTiO3, YSZ, MgO, and LaAlO3, as well as on Si substrates without any buffer layer. A bolometer has been fabricated on a thermally isolated SiN substrate coated with YSZ, an effort carried out in collaboration with Honeywell Inc. The deposition process facilitates the fabrication of very thin and transparent films creating new opportunities for the study of superconductor-insulator transitions and the investigation of photo-doping with carriers of high temperature superconductors. In addition to a thin film technology, a patterning technology has been developed. Trilayer structures have been developed for FET devices and tunneling junctions. Other work includes the measurement of the magnetic properties of bulk single crystal high temperature superconductors, and in collaboration with Argonne National Laboratory, measurement of electric transport properties of T1-based high-Tc films.

  17. High Temperature Piezoelectric Drill (United States)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom


    Venus is one of the planets in the solar systems that are considered for potential future exploration missions. It has extreme environment where the average temperature is 460 deg C and its ambient pressure is about 90 atm. Since the existing actuation technology cannot maintain functionality under the harsh conditions of Venus, it is a challenge to perform sampling and other tasks that require the use of moving parts. Specifically, the currently available electromagnetic actuators are limited in their ability to produce sufficiently high stroke, torque, or force. In contrast, advances in developing electro-mechanical materials (such as piezoelectric and electrostrictive) have enabled potential actuation capabilities that can be used to support such missions. Taking advantage of these materials, we developed a piezoelectric actuated drill that operates at the temperature range up to 500 deg C and the mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) configuration. The detailed results of our study are presented in this paper

  18. High temperature materials and mechanisms

    CERN Document Server


    The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the ...

  19. High temperature superconductors

    CERN Document Server

    Paranthaman, Parans


    This essential reference provides the most comprehensive presentation of the state of the art in the field of high temperature superconductors. This growing field of research and applications is currently being supported by numerous governmental and industrial initiatives in the United States, Asia and Europe to overcome grid energy distribution issues. The technology is particularly intended for densely populated areas. It is now being commercialized for power-delivery devices, such as power transmission lines and cables, motors and generators. Applications in electric utilities include current limiters, long transmission lines and energy-storage devices that will help industries avoid dips in electric power.

  20. Effect of Temperature in Fluidized Bed Fast Pyrolysis of Biomass: Oil Quality Assessment in Test Units

    NARCIS (Netherlands)

    Westerhof, R.J.M.; Brilman, D.W.F.; Swaaij, van W.P.M.; Kersten, S.R.A.


    Pine wood was pyrolyzed in a 1 kg/h fluidized bed fast pyrolysis reactor that allows a residence time of pine wood particles up to 25 min. The reactor temperature was varied between 330 and 580 °C to study the effect on product yields and oil composition. Apart from the physical−chemical analysis, a


    Institute of Scientific and Technical Information of China (English)

    Heping Cui; Jamal Chaouki


    Previous reports and current studies show that fluidization of some Geldart A particles is enhanced by increasing bed temperature. Both the averaged local particle concentration and the particle concentration in the dense phase decrease with increasing bed temperature, at constant superficial gas velocities. However, conventional models fail to predict these changes, because the role of interparticle forces is usually neglected at different bed temperatures.Here, the interparticle forces are analyzed to explore the mechanism of gas-solid fluidization at high temperatures. Indeed, as the temperature increases, the interparticle attractive forces decrease while the interparticle repulsive forces increase. Consequently, fluidization behaviors of some Geldart A particles seem to increasingly shift from typical Geldart A towards B with increasing temperature.

  2. Gasification of high ash, high ash fusion temperature bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang


    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in C. to C. range as well as in excess of C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  3. High Temperature Aquifer Storage (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas


    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  4. High temperature interfacial superconductivity (United States)

    Bozovic, Ivan [Mount Sinai, NY; Logvenov, Gennady [Port Jefferson Station, NY; Gozar, Adrian Mihai [Port Jefferson, NY


    High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

  5. Temperature and time influence on the waste plastics pyrolysis in the fixed bed reactor

    Directory of Open Access Journals (Sweden)

    Papuga Saša V.


    Full Text Available Pyrolysis as a technique of chemical recycling of plastic materials is causing an increasing level of interest as an environmentally and economically acceptable option for the processing of waste materials. Studies of these processes are carried out under different experimental conditions, in different types of reactors and with different raw materials, which makes the comparison of different processes and the direct application of process parameters quite complex. This paper presents the results of investigation of the influence of temperature in the range of 450°C to 525°C, on the yield of the process of pyrolysis of waste plastics mixture, composed of 45% polypropylene, 35% low density polyethylene and 25% high density polyethylene. Also, this paper presents results of the investigation of the effect of the reaction, atintervals of 30-90 [min], on the yield of pyrolysis of the mentioned waste plastics mixture. Research was conducted in a fixed bed pilot reactor, which was developed for this purpose. The results of the research show that at a temperature of 500°C, complete conversion of raw materials was achieved, for a period of 45 [min], with a maximum yield of the pyrolysis oil of 32.80%, yield of the gaseous products of 65.75% and the solid remains of 1.46%. Afurther increase of temperature increases the yield of gaseous products, at the expense of reducing the yield of pyrolysis oil. Obtained pyrolysis oil has a high calorific value of 45.96 [MJ/kg], and in this regard has potential applications as an alternative fuel.

  6. An experimental analysis of bed load transport in gravel-bed braided rivers with high grain Reynolds numbers (United States)

    De Vincenzo, Annamaria; Brancati, Francesco; Pannone, Marilena


    Laboratory experiments were performed with nearly uniform fluvial gravel (D50=9 mm, D10=5 mm and D90=13 mm) to analyse the relationship between stream power and bed load transport rate in gravel-bed braided rivers at high grain Reynolds numbers. The values of the unit-width dimensionless bed-load rate qb* and unit-width dimensionless stream power ω* were evaluated in equilibrium conditions based on ten different experimental runs. Then, they were plotted along with values obtained during particularly representative field studies documented in the literature, and a regression law was derived. For comparison, a regression analysis was performed using the data obtained from laboratory experiments characterized by smaller grain sizes and, therefore, referring to relatively low grain Reynolds numbers. A numerical integration of Exner's equation was performed to reconstruct the local and time-dependent functional dependence of qb* and ω*. The results led to the following conclusions: 1) At equilibrium, the reach-averaged bed load transport rate is related to the reach-averaged stream power by different regression laws at high and low grain Reynolds numbers. Additionally, the transition from bed to suspended load transport is accelerated by low Re*, with the corresponding bed load discharge increasing with stream power at a lower, linear rate. 2) When tested against the gravel laboratory measurements, the high Re* power law derived in the present study performs considerably better than do previous formulas. 3) The longitudinal variability of the section-averaged equilibrium stream power is much more pronounced than that characterizing the bed load rate, at least for high Re*. Thus, the stream power and its local-scale heterogeneity seem to be directly responsible for transverse sediment re-distribution and, ultimately, for the determination of the spatial and temporal scales that characterize the gravel bedforms. 4) Finally, the stochastic interpretation of the wetted

  7. Morphological characteristics of overdeepenings in high-mountain glacier beds (United States)

    Haeberli, Wilfried; Cochachin, Alejo; Fischer, Urs; Giráldez, Claudia; Linsbauer, Andreas; Salazar, Cesar


    Overdeepenings, i.e. closed topographic depressions with adverse slopes in the flow direction, are characteristic for glacier beds and glacially sculpted landscapes. Besides their importance as geomorphological landforms, groundwater bodies and sedimentary archives, they are of increasing interest in relation to climate-induced lake formation in de-glaciating landscapes and to depth erosion under ice age conditions in connection with the long-term safety of radioactive waste repositories in some mid-latitude countries. Quantitative predictions of their shape, distribution and conditions of occurrence, however, remain difficult. One major problem thereby relates to the still unsatisfactory treatment in glacier erosion theory of sediment evacuation at glacier beds, especially by subglacial meltwater. An alternative way of searching for realistic/empirical quantitative estimates is, therefore, to analyse the geometry of well-documented overdeepenings. The present study attempts to do this by combining statistical analyses of (a) detailed bathymetries from recently exposed lakes in the Peruvian Andes, (b) numerous bed overdeepenigs below still existing glaciers of the Swiss Alps and the Himalaya-Karakoram region modelled with a robust shear stress approximation linking surface slope to ice thickness at high resolution, and (c, for comparison) reconstructed overdeepenings produced by ice age glaciers in the Swiss Plateau based on numerous drillings and geophysical soundings. The sample of (a) has the advantage that geometries are exactly measured and only subject to young/small sedimentation effects. Sample (b) allows for a comparison with a modern model calculation and with known glacier characteristics. Sample (c) may provide some insights into the question how safely results from high mountain topography can be transferred to sites with markedly different topographic, climatic and glaciological controls (cold-arid lowland). Where possible, mean and maximum values of


    Directory of Open Access Journals (Sweden)

    E. D. Chertov


    Full Text Available The work is devoted to the creation of a new type of mixer to produce homogeneous mixtures of dissimilar materials applied to recycling of housing and communal services waste. The article describes the design of a dual-chamber device of the original high-temperature vacuum mixer, there investigated the processes occurring in the chambers of such devices. The results of theoretical and experimental research of the process of mixing recycled polyethylene with a mixture of "grinded food waste – Eco wool” are presented. The problem of the optimum choice of bending the curvilinear blades in the working volume of the seal, which is achieved by setting their profile in the form of involute arc of several circles of different radii, is examined . The dependences, allowing to define the limits of the changes of the main mode parameters the angular velocity of rotation of the working body of the mixer using two ways of setting the profile of the curvilinear blade mixer are obtained. Represented design of the mixer is proposed to use for a wide range of tasks associated with the mixing of the components with a strongly pronounced difference of physic al chemical properties and, in particular, in the production of composites out of housing and communal services waste.

  9. An Investigation on Low-Temperature Thermochemical Treatments of Austenitic Stainless Steel in Fluidized Bed Furnace (United States)

    Haruman, E.; Sun, Y.; Triwiyanto, A.; Manurung, Y. H. P.; Adesta, E. Y.


    In this study, the feasibility of using an industrial fluidized bed furnace to perform low-temperature thermochemical treatments of austenitic stainless steels has been studied, with the aim to produce expanded austenite layers with combined wear and corrosion resistance, similar to those achievable by plasma and gaseous processes. Several low-temperature thermochemical treatments were studied, including nitriding, carburizing, combined nitriding-carburizing (hybrid treatment), and sequential carburizing and nitriding. The results demonstrate that it is feasible to produce expanded austenite layers on the investigated austenitic stainless steel by the fluidized bed heat treatment technique, thus widening the application window for the novel low-temperature processes. The results also demonstrate that the fluidized bed furnace is the most effective for performing the hybrid treatment, which involves the simultaneous incorporation of nitrogen and carbon together into the surface region of the component in nitrogen- and carbon-containing atmospheres. Such hybrid treatment produces a thicker and harder layer than the other three processes investigated.


    Directory of Open Access Journals (Sweden)

    Iwona Skoczko


    Full Text Available Rising demands concerning water treatment and conservation make it necessary to search for more effective as well as cheap and ecologically safe solutions. During the filtration process quartz sand is replaced by filter materials which also have a strong effect on account of reactions taking place on a bed’s surface. Today’s technologies for groundwater and seepage water treatment in rapid filters make use of oxidation beds. They are able to effectively remove manganese (II and iron (II compounds based on heterogeneous oxidation catalysis. The main catalyst of the manganese removal process in terms of its catalytic oxidation in filtration beds is manganese dioxide. This compound is used as an oxidizing agent in many processes. The research conducted as part of this paper was aimed at creating a product with the qualities similar to a popular Greensand bed protected by patent. The authors tested washed quartz sand varying in granulation which was subject to activation in 10% KMnO4 solution. Grains of quartz sand after covering them with a permanent coat of manganese oxide developed the superficial oxidation layer. While performing the tests, a temperature of the process served as a variable. The beds produced as a result of the experiment enable the removal of iron and manganese from water without prior alkylation. Furthermore, they are an effective method of purifying water of organic pollutants and ammoniacal nitrogen. They function as oxidizing and filtering masses.

  11. Advances in high temperature chemistry

    CERN Document Server

    Eyring, Leroy


    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as w

  12. High temperature nanoplasmonics (United States)

    Alabastri, Alessandro; Toma, Andrea; Malerba, Mario; De Angelis, Francesco; Proietti Zaccaria, Remo


    Metallic nanostructures can be utilized as heat nano-sources which can find application in different areas such as photocatalysis, nanochemistry or sensor devices. Here we show how the optical response of plasmonic structures is affected by the increase of temperature. In particular we apply a temperature dependent dielectric function model to different nanoparticles finding that the optical responses are strongly dependent on shape and aspect-ratio. The idea is that when metallic structures interact with an electromagnetic field they heat up due to Joule effect. The corresponding temperature increase modifies the optical response of the particle and thus the heating process. The key finding is that, depending on the structures geometry, absorption efficiency can either increase or decrease with temperature. Since absorption relates to thermal energy dissipation and thus to temperature increase, the mechanism leads to positive or negative loops. Consequently, not only an error would be made by neglecting temperature but it would be not even possible to know, a priori, if the error is towards higher or lower values.

  13. Ultra-High Temperature Gratings

    Institute of Scientific and Technical Information of China (English)

    John Canning; Somnath Bandyopadhyay; Michael Stevenson; Kevin Cook


    Regenerated gratings seeded by type-Ⅰ gratings are shown to withstand temperatures beyond 1000 ℃. The method of regeneration offers a new approach to increasing temperature resistance of stable fibre Bragg and other gratings. These ultra-high temperature (UHT) gratings extend the applicability of silicate based components to high temperature applications such as monitoring of smelters and vehicle and aircraft engines to high power fibre lasers.

  14. High-Temperature Piezoelectric Sensing

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang


    Full Text Available Piezoelectric sensing is of increasing interest for high-temperature applications in aerospace, automotive, power plants and material processing due to its low cost, compact sensor size and simple signal conditioning, in comparison with other high-temperature sensing techniques. This paper presented an overview of high-temperature piezoelectric sensing techniques. Firstly, different types of high-temperature piezoelectric single crystals, electrode materials, and their pros and cons are discussed. Secondly, recent work on high-temperature piezoelectric sensors including accelerometer, surface acoustic wave sensor, ultrasound transducer, acoustic emission sensor, gas sensor, and pressure sensor for temperatures up to 1,250 °C were reviewed. Finally, discussions of existing challenges and future work for high-temperature piezoelectric sensing are presented.

  15. Bed mixing dryer for high moisture content fuels

    Energy Technology Data Exchange (ETDEWEB)

    Hulkkonen, S.; Heinonen, O. [Imatran Voima Oy, Vantaa (Finland)


    Bed mixing dryer is a new type of fuel drying technology for fluidized bed combustion. The idea is to extract hot bed material from the fluidized bed and use it as a heat source for drying the fuel. Drying occurs at steam atmosphere which makes it possible to recover the latent heat of evaporation to process. This improves the thermal efficiency of the power plant process considerably, especially in combined heat and power applications. Imatran Voima Oy (IVO) has developed the Bed Mixing Dryer technology since early 1990s. The first pilot plant was built in 1994 to IVO`s Kuusamo peat and wood fired power plant. The capacity of the plant is 6 MW{sub e} and 20 MW of district heat. In Kuusamo the dryer is connected to a bubbling fluidized bed. Since it`s commissioning the dryer has been used successfully for about 3000 hours during the heating season in wintertime. The second application of the technology will be a demonstration project in Oerebro (S). IVO Power Engineering Ltd will supply in 1997 a dryer to Oerebro Energi`s peat, wood and coal fired CHP plant equipped with circulating fluidized bed boiler. The fuel to be dried is sawdust with fuel input of about 60 MW. In Kuusamo the dryer produces 3 MW of additional district heat and in Oerebro 6 MW. The fuels in Kuusamo are peat, saw dust and bark. In addition to the municipal heat production this type of drying technology has its benefits in pulp and paper industry processes. Disposal of paper mill sludges is becoming more difficult and costly which has resulted in need of alternative treatment. Drying of the sludge before combustion in a boiler for power production is an attractive option. At the moment IVO is carrying out several studies to apply the Bed Mixing Dryer in pulp and paper industry processes. Economy of drying the sludge looks promising

  16. Standard metabolic rate of the bed bug, Cimex lectularius: effects of temperature, mass, and life stage. (United States)

    Devries, Zachary C; Kells, Stephen A; Appel, Arthur G


    Metabolic rates provide important information about the biology of organisms. For ectothermic species such as insects, factors such as temperature and mass heavily influence metabolism, but these effects differ considerably between species. In this study we examined the standard metabolic rate of the bed bug, Cimex lectularius L. We used closed system respirometry and measured both O2 consumption and CO2 production across a range of temperatures (10, 20, 25, 30, 35°C) and life stages, while also accounting for activity. Temperature had a stronger effect on the mass specific .VO2 (mlg(-1)h(-1)) of mated males (Q10=3.29), mated females (Q10=3.19), unmated males (Q10=3.09), and nymphs that hatched (first instars, Q10=3.05) than on unmated females (Q10=2.77) and nymphs that molted (second through fifth instars, Q10=2.78). First instars had significantly lower respiratory quotients (RQ) than all other life stages. RQ of all stages was not affected by temperature. .VO2 (mlh(-1)) scaled more with mass than values previously reported for other arthropods or that would be predicted by the 3/4-power law. The results are used to understand the biology and ecology of the bed bug.

  17. Multi-Bed Multi-Stage Adsorption Refrigeration Cycle-Reducing Driving Heat Source Temperature (United States)

    Alam, K. C. Amanul; Akahira, Akira; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao; Saha, Bidyut Baran; Koyama, Shigeru; Ng, Kim Choon; Chua, Hui Tong

    The study aims at designing a multi-bed multi-stage adsorption chiller that can be driven by waste heat at near ambient temperature. The chiller is designed such a way that it can be switched into different modes depending on the driving heat source temperature. Stage regeneration techniques have been applied to operate the chiller by relatively low temperature heat source. Driving heat source temperature is validated by simulated data and the performances obtained from different modes are compared. In terms of COP (Coefficient of performance),the chiller shows best performance in conventional single-stage mode for driving heat source temperature greater than 60°C, two stage mode for driving source temperature between 42 and 60°C,in three-stage mode for driving source temperature less than 42°C. In terms of cooling capacity, it shows the best performance in single-stage mode for heat source temperature greater than 70°C. The mass recovery process in single-stage mode is also examined. It is seen that the mass recovery process improve cooling capacity significantly, specially for the low regenerating temperature region.

  18. High temperature materials; Materiaux a hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)



    The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

  19. High Temperature Fluoride Salt Test Loop

    Energy Technology Data Exchange (ETDEWEB)

    Aaron, Adam M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cunningham, Richard Burns [Univ. of Tennessee, Knoxville, TN (United States); Fugate, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holcomb, David Eugene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kisner, Roger A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Peretz, Fred J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robb, Kevin R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wilson, Dane F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yoder, Jr, Graydon L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)


    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels

  20. High Temperature Superconductor Machine Prototype

    DEFF Research Database (Denmark)

    Mijatovic, Nenad; Jensen, Bogi Bech; Træholt, Chresten


    A versatile testing platform for a High Temperature Superconductor (HTS) machine has been constructed. The stationary HTS field winding can carry up to 10 coils and it is operated at a temperature of 77K. The rotating armature is at room temperature. Test results and performance for the HTS field...

  1. Modeling of river bed deformation composed of frozen sediments with increasing environmental temperature

    Directory of Open Access Journals (Sweden)

    E. I. Debolskaya


    Full Text Available This paper is devoted to investigation of the influence of river flow and of the temperature rise on the deformation of the coastal slopes composed of permafrost with the inclusion of ice layer. The method of investigation is the laboratory and mathematical modeling. The laboratory experiments have shown that an increase in water and air temperature changes in a laboratory analogue of permafrost causes deformation of the channel even without wave action, i.e. at steady-state flow and non-erosive water flow velocity. The previously developed model of the bed deformation was improved to account for long-term changes of soil structure with increasing temperature. The three-dimensional mathematical model of coastal slopes thermoerosion of the rivers flowing in permafrost regions, and its verification was based on the results of laboratory experiments conducted in the hydraulic tray. Analysis of the results of mathematical and laboratory modeling showed that bed deformation of the rivers flowing in the permafrost zone, significantly different from the deformation of channels composed of soils not susceptible to the influence of the phase transition «water-ice», and can occur even under the non-erosive velocity of the water flow.

  2. Water and sediment temperatures at mussel beds in the upper Mississippi River basin (United States)

    Newton, Teresa J.; Sauer, Jennifer; Karns, Byron


    Native freshwater mussels are in global decline and urgently need protection and conservation. Declines in the abundance and diversity of North American mussels have been attributed to human activities that cause pollution, waterquality degradation, and habitat destruction. Recent studies suggest that effects of climate change may also endanger native mussel assemblages, as many mussel species are living close to their upper thermal tolerances. Adult and juvenile mussels spend a large fraction of their lives burrowed into sediments of rivers and lakes. Our objective was to measure surface water and sediment temperatures at known mussel beds in the Upper Mississippi (UMR) and St. Croix (SCR) rivers to estimate the potential for sediments to serve as thermal refugia. Across four mussel beds in the UMR and SCR, surface waters were generally warmer than sediments in summer, and were cooler than sediments in winter. This suggests that sediments may act as a thermal buffer for mussels in these large rivers. Although the magnitude of this effect was usually <3.0°C, sediments were up to 7.5°C cooler at one site in May, suggesting site-specific variation in the ability of sediments to act as thermal buffers. Sediment temperatures in the UMR exceeded those shown to cause mortality in laboratory studies. These data suggest that elevated water temperatures resulting from global warming, thermal discharges, water extraction, and/or droughts have the potential to adversely affect native mussel assemblages.

  3. Modeling the microbial growth and temperature profile in a fixed-bed bioreactor. (United States)

    da Silveira, Christian L; Mazutti, Marcio A; Salau, Nina P G


    Aiming to scale up and apply control and optimization strategies, currently is required the development of accurate plant models to forecast the process nonlinear dynamics. In this work, a mathematical model to predict the growth of the Kluyveromyces marxianus and temperature profile in a fixed-bed bioreactor for solid-state fermentation using sugarcane bagasse as substrate was built up. A parameter estimation technique was performed to fit the mathematical model to the experimental data. The estimated parameters and the model fitness were evaluated with statistical analyses. The results have shown the estimated parameters significance, with 95 % confidence intervals, and the good quality of process model to reproduce the experimental data.

  4. High Temperature Electrostrictive Ceramics Project (United States)

    National Aeronautics and Space Administration — TRS Technologies proposes to develop high temperature electrostrictors from bismuth-based ferroelectrics. These materials will exhibit high strain and low loss in...

  5. An investigation of moving bed biofilm reactor nitrification during long-term exposure to cold temperatures. (United States)

    Hoang, Valerie; Delatolla, Robert; Laflamme, Edith; Gadbois, Alain


    Biological treatment is the most common and economical means of ammonia removal in wastewater; however, nitrification rates can become completely impeded at cold temperatures. Attached growth processes and, specifically, moving bed biofilm reactors (MBBRs) have shown promise with respect to low-temperature nitrification. In this study, two laboratory MBBRs were used to investigate MBBR nitrification rates at 20, 5, and 1 degree C. Furthermore, the solids detached by the MBBR reactors were investigated and Arrhenius temperature correction models used to predict nitrification rates after long-term low-temperature exposure was evaluated. The nitrification rate at 5 degrees C was 66 +/- 3.9% and 64 +/- 3.7% compared to the rate measured at 20 degrees C for reactors 1 and 2, respectively. The nitrification rates at 1 degree C over a 4-month exposure period compared to the rate at 20 degrees C were 18.7 +/- 5.5% and 15.7 +/- 4.7% for the two reactors. The quantity of solids detached from the MBBR biocarriers was low and the mass of biofilm per carrier did not vary significantly at 20 degrees C compared to that after long-term exposure at 1 degree C. Lastly, a temperature correction model based on exposure time to cold temperatures showed a strong correlation to the calculated ammonia removal rates relative to 20 degrees C following a gradual acclimatization period to cold temperatures.

  6. Analysis of the high-temperature particulate collection problem

    Energy Technology Data Exchange (ETDEWEB)

    Razgaitis, R.


    Particulate agglomeration and separation at high temperatures and pressures are examined, with particular emphasis on the unique features of the direct-cycle application of fluidized-bed combustion. The basic long-range mechanisms of aerosol separation are examined, and the effects of high temperature and high pressure on usable collection techniques are assessed. Primary emphasis is placed on those avenues that are not currently attracting widespread research. The high-temperature, particulate-collection problem is surveyed, together with the peculiar requirements associated with operation of turbines with particulate-bearing gas streams. 238 references.

  7. Hydrodynamic description of a vibrofluidized granular bed driven at high frequency (United States)

    Sheikh, Nadeem A.; Manzoor, Shehryar; Mahabat Khan, Muhammad; Ali, Muzaffar


    Results are reported for a dry granular bed vertically excited at high and low frequencies with constant peak base velocity. Previous experimental data sets using Nuclear Magnetic Resonance are used for comparison at low (~38 Hz) and high (~11 kHz) vibration frequencies. Packing fractions and granular temperatures are compared against hydrodynamic and molecular dynamics simulation models. At low frequency hydrodynamic and MD simulations results show the presence of a heat wave. Whilst at high frequencies soft sphere potential based MD simulations highlight the role of finite duration collisions between particles and the vibrating wall. In this region the timescales of vibration and collision duration are not well separated, as observed in experimental results.

  8. Fluidisation and dispersion behaviour of small high density pellicular expanded bed adsorbents

    DEFF Research Database (Denmark)

    Theodossiou, Irini; Elsner, H.D.; Thomas, Owen R. T.;


    The fluidisation and dispersion properties of various agarose-based expanded bed matrices-small high density stainless steel cored prototypes and standard commercial types-were studied in I-cm diameter expanded bed contactors in which fluid entering the column base is locally stirred. In all cases...

  9. The influence of temperature on limestone sulfation and attrition under fluidized bed combustion conditions

    Energy Technology Data Exchange (ETDEWEB)

    Montagnaro, Fabio [Dipartimento di Chimica - Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant' Angelo, 80126 Napoli (Italy); Salatino, Piero [Istituto di Ricerche sulla Combustione - CNR, Piazzale Vincenzo Tecchio 80, 80125 Napoli (Italy); Dipartimento di Ingegneria Chimica - Universita degli Studi di Napoli Federico II, Piazzale Vincenzo Tecchio 80, 80125 Napoli (Italy); Scala, Fabrizio [Istituto di Ricerche sulla Combustione - CNR, Piazzale Vincenzo Tecchio 80, 80125 Napoli (Italy)


    The influence of temperature on attrition of two limestones during desulfurization in a fluidized bed reactor was investigated. Differences in the microstructure of the two limestones were reflected by a different thickness of the sulfate shell formed upon sulfation and by a different value of the ultimate calcium conversion degree. Particle attrition and fragmentation were fairly small under moderately bubbling fluidization conditions for both limestones. An increase of temperature from 850 C to 900 C led to an increase of the attrition rate, most likely because of a particle weakening effect caused by a faster CO{sub 2} evolution during calcination. This weakening effect, however, was not sufficiently strong to enhance particle fragmentation in the bed. The progress of sulfation, associated to the build-up of a hard sulfate shell around the particles, led in any case to a decrease of the extent of attrition. Sulfation at 900 C was less effective than at 850 C, and this was shown to be related to the porosimetric features of the different samples. (author)

  10. Influence of temperature and particle size on the fixed bed pyrolysis of orange peel residues

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, L. [Departamento de Mecanica, Universidad de Pinar del Rio, Cuba. Calle Marti 270, final, Pinar del Rio (Cuba); Marquez-Montesinos, F. [Departamento de Quimica, Universidad de Pinar del Rio, Cuba. Calle Marti 270, final, Pinar del Rio (Cuba); Gonzalo, A.; Sanchez, J.L.; Arauzo, J. [Thermochemical Processes Group (GPT), Aragon Institute for Engineering Research (I3A), University of Zaragoza, Maria de Luna 3, 50018 Zaragoza (Spain)


    Orange peel is a residue from the production of juice. Its energetic valorisation could be interesting in areas where a different use, such as animal feed, is not possible. In order to investigate the viability of energy recovery, the pyrolysis of orange peel residues was studied in a fixed bed reactor, as an initial assessment of this process. The influence of pyrolysis temperature (300-600 C) and particle size (d{sub p}<300{mu}m and d{sub p}>800{mu}m) on product distribution, gas composition and char heating value has been investigated using a factorial design of experiments. Gas, char and water are the main products obtained; tar is only about 6 wt.% of the initial residue. Temperature was found to be the parameter which exerts a more important influence on the results than particle size. (author)

  11. Impact of temperature on ammonium and nitrite removal rates in RAS moving bed biofilters

    DEFF Research Database (Denmark)

    Kinyage, John Peter Hewa; Pedersen, Lars-Flemming


    at each of the six temperatures (6, 12, 18, 24, 30 and 36 °C) and then spiked with ammonium chloride or sodium nitrite under identical conditions. The average surface specific TAN removal (STR) increased a six-fold from 6 to 30 °C (0.04–0.25 g TAN m−2 day−1) and dropped significantly at 36 °C–0.14 g TAN m......The impact of temperature on bacterial processes is well known; however temperature related data on nitrification rates in aquaculture systems are fragmented and compiled from different studies. We sought to determine ammonium and nitrite removal kinetics over a temperature range from 6 to 36 °C...... by using moving bed bio-elements from a freshwater RAS in steady state operated at 18 °C. The impact of temperature on ammonium and nitrite oxidation rates was evaluated by transferring the colonized bio elements to six liter batch reactors (triplicated setup). Each reactor was acclimatized for 24 h...

  12. High Temperature Materials Laboratory (HTML) (United States)

    Federal Laboratory Consortium — The six user centers in the High Temperature Materials Laboratory (HTML), a DOE User Facility, are dedicated to solving materials problems that limit the efficiency...

  13. High Temperature Bell Motor Project (United States)

    National Aeronautics and Space Administration — The National Research Council (NRC) has identified the need for motors and actuators that can operate in extreme high and low temperature environments as a technical...

  14. Effect of temperature and salinity on the wastewater treatment performance of aerobic submerged fixed bed biofilm reactors. (United States)

    Chapanova, G; Jank, M; Schlegel, S; Koeser, H


    The influence of temperature (5-35 C) and salinity (up to 20 g/l NaCl) on the wastewater purification process in completely mixed and aerated submerged fixed bed biofilm reactors (SFBBRs) was studied. C- and N-conversion in SFBBRs designed according to the DWA (German Association for Water, Wastewater and Waste) rules for carbon removal was investigated for several months on synthetic wastewater. The DOC degradation rate was even at, according to the DWA, high DOC/BOD loading rates not much affected by temperatures between 5-35 degrees C and salt contents up to 20 g/L NaCl. At these high DOC loadings an appreciable ammonium conversion could also be observed. The ammonium conversion proved to be sensitive to temperature and salinity. At 5 degrees C the ammonium removal rate decreased by a factor of five compared to 25-35 degrees C. Under many operation conditions investigated more than 50% of the converted ammonium was transformed into gaseous nitrogen. The addition of 20 g/L NaCl caused a strong inhibition of the ammonium removal rate over the whole temperature range investigated.

  15. Modeling the temperature in coal char particle during fluidized bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    Vasilije Manovic; Mirko Komatina; Simeon Oka [University of Belgrade, Belgrade (Serbia)


    The temperatures of a coal char particle in hot bubbling fluidized bed (FB) were analyzed by a model of combustion. The unsteady model includes phenomena of heat and mass transfer through a porous char particle, as well as heterogeneous reaction at the interior char surface and homogeneous reaction in the pores. The parametric analysis of the model has shown that above 550{sup o}C combustion occurs under the regime limited by diffusion. The experimental results of temperature measurements by thermocouple in the particle center during FB combustion at temperatures in the range 590-710{sup o}C were compared with the model predictions. Two coals of different rank were used: lignite and brown coal, with particle size in the range 5-10 mm. The comparisons have shown that the model can adequately predict the histories of temperatures in char particles during combustion in FB. In the first order, the model predicts the influence of the particle size, coal rank (via porosity), and oxygen concentration in its surroundings. 53 refs., 6 figs., 2 tabs.

  16. Studies of Alkali Sorption Kinetics for Pressurized Fluidized Bed Combustion by High Pressure Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, K.J.; Willenborg, W.; Fricke, C.; Prikhodovsky, A.; Hilpert, K.; Singheiser, L.


    This work describes the first approach to use High Pressure Mass Spectrometry (HPMS) for the quantification and analysis of alkali species in a gas stream downstream a sorbent bed of different tested alumosilicates.

  17. Gallium phosphide high temperature diodes (United States)

    Chaffin, R. J.; Dawson, L. R.


    High temperature (300 C) diodes for geothermal and other energy applications were developed. A comparison of reverse leakage currents of Si, GaAs, and GaP was made. Diodes made from GaP should be usable to 500 C. A Liquid Phase Epitaxy (LPE) process for producing high quality, grown junction GaP diodes is described. This process uses low vapor pressure Mg as a dopant which allows multiple boat growth in the same LPE run. These LPE wafers were cut into die and metallized to make the diodes. These diodes produce leakage currents below ten to the -9th power A/sq cm at 400 C while exhibiting good high temperature rectification characteristics. High temperature life test data is presented which shows exceptional stability of the V-I characteristics.

  18. Temperature optimization of high con

    Directory of Open Access Journals (Sweden)

    M. Sabry


    Full Text Available Active cooling is essential for solar cells operating under high optical concentration ratios. A system comprises four solar cells that are in thermal contact on top of a copper tube is proposed. Water is flowing inside the tube in order to reduce solar cells temperature for increasing their performance. Computational Fluid Dynamics (CFD simulation of such system has been performed in order to investigate the effect of water flow rate, tube internal diameter, and convective heat transfer coefficient on the temperature of the solar cells. It is found that increasing convective heat transfer coefficient has a significant effect on reducing solar cells temperatures operating at low flow rates and high optical concentration ratios. Also, a further increase of water flow rate has no effect on reducing cells temperatures.

  19. RPC operation at high temperature

    CERN Document Server

    Aielli, G; Cardarelli, R; Di Ciaccio, A; Di Stante, L; Liberti, B; Paoloni, A; Pastori, E; Santonico, R


    The resistive electrodes of RPCs utilised in several current experiments (ATLAS, CMS, ALICE, BABAR and ARGO) are made of phenolic /melaminic polymers, with room temperature resistivities ranging from 10**1**0 Omega cm, for high rate operation in avalanche mode, to 5 multiplied by 10**1**1 Omega cm, for streamer mode operation at low rate. The resistivity has however a strong temperature dependence, decreasing exponentially with increasing temperature. We have tested several RPCs with different electrode resistivities in avalanche as well as in streamer mode operation. The behaviours of the operating current and of the counting rate have been studied at different temperatures. Long-term operation has also been studied at T = 45 degree C and 35 degree C, respectively, for high and low resistivity electrodes RPCs.

  20. Solute strengthening at high temperatures (United States)

    Leyson, G. P. M.; Curtin, W. A.


    The high temperature behavior of solute strengthening has previously been treated approximately using various scaling arguments, resulting in logarithmic and power-law scalings for the stress-dependent energy barrier Δ E(τ ) versus stress τ. Here, a parameter-free solute strengthening model is extended to high temperatures/low stresses without any a priori assumptions on the functional form of Δ E(τ ) . The new model predicts that the well-established low-temperature, with energy barrier Δ {{E}\\text{b}} and zero temperature flow stress {τy0} , transitions to a near-logarithmic form for stresses in the regime 0.2data on solution strengthening in Cu alloys and captures the experimental results quantitatively and qualitatively. Most importantly, the model accurately captures the transition in strength from the low-temperature to intermediate-temperature and the associated transition for the activation volume. Overall, the present analysis unifies the different qualitative models in the literature and, when coupled with the previous parameter-free solute strengthening model, provides a single predictive model for solute strengthening as a function of composition, temperature, and strain rate over the full range of practical utility.


    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Qingfeng, Li; He, Ronghuan


    This paper will report recent results from our group on polymer fuel cells (PEMFC) based on the temperature resistant polymer polybenzimidazole (PBI), which allow working temperatures up to 200°C. The membrane has a water drag number near zero and need no water management at all. The high working...... temperature allows for utilization of the excess heat for fuel processing. Moreover, it provides an excellent CO tolerance of several percent, and the system needs no purification of hydrogen from a reformer. Continuous service for over 6 months at 150°C has been demonstrated....

  2. Influences of Temperature and Coal Particle Size on the Flash Pyrolysis of Coal in a Fast-entrained Bed

    Institute of Scientific and Technical Information of China (English)


    The experiments on the flash pyrolysis of a lignite were carried out in a fast-entrained bed reactor as a basic study on a so-called 'coal topping process'. The investigation focused on the effects of pyrolysis temperature and coal particle size on the product distribution and composition. The experimental results show that an increase in the pyrolysis temperature results in a higher yield of gaseous products while a larger particle size leads to a decrease of the liquid yield. An optimum temperature for the liquid yield was found to be 650 ℃. A certain amount of phenol groups was found in the liquid products, which may be used to produce high-valued fine chemicals. The FTIR analyses of the coal and chars show that aliphatic structures in the chars are gradually replaced by aromatic structures with the increasing of pyrolysis temperature and coal particle size. The results of this study provide fundamental data and optimal conditions to maximize light oils yields for the coal topping process.

  3. Interface high-temperature superconductivity (United States)

    Wang, Lili; Ma, Xucun; Xue, Qi-Kun


    Cuprate high-temperature superconductors consist of two quasi-two-dimensional (2D) substructures: CuO2 superconducting layers and charge reservoir layers. The superconductivity is realized by charge transfer from the charge reservoir layers into the superconducting layers without chemical dopants and defects being introduced into the latter, similar to modulation-doping in the semiconductor superlattices of AlGaAs/GaAs. Inspired by this scheme, we have been searching for high-temperature superconductivity in ultra-thin films of superconductors epitaxially grown on semiconductor/oxide substrates since 2008. We have observed interface-enhanced superconductivity in both conventional and unconventional superconducting films, including single atomic layer films of Pb and In on Si substrates and single unit cell (UC) films of FeSe on SrTiO3 (STO) substrates. The discovery of high-temperature superconductivity with a superconducting gap of ∼20 meV in 1UC-FeSe/STO has stimulated tremendous interest in the superconductivity community, for it opens a new avenue for both raising superconducting transition temperature and understanding the pairing mechanism of unconventional high-temperature superconductivity. Here, we review mainly the experimental progress on interface-enhanced superconductivity in the three systems mentioned above with emphasis on 1UC-FeSe/STO, studied by scanning tunneling microscopy/spectroscopy, angle-resolved photoemission spectroscopy and transport experiments. We discuss the roles of interfaces and a possible pairing mechanism inferred from these studies.

  4. High-Temperature Optical Sensor (United States)

    Adamovsky, Grigory; Juergens, Jeffrey R.; Varga, Donald J.; Floyd, Bertram M.


    A high-temperature optical sensor (see Figure 1) has been developed that can operate at temperatures up to 1,000 C. The sensor development process consists of two parts: packaging of a fiber Bragg grating into a housing that allows a more sturdy thermally stable device, and a technological process to which the device is subjected to in order to meet environmental requirements of several hundred C. This technology uses a newly discovered phenomenon of the formation of thermally stable secondary Bragg gratings in communication-grade fibers at high temperatures to construct robust, optical, high-temperature sensors. Testing and performance evaluation (see Figure 2) of packaged sensors demonstrated operability of the devices at 1,000 C for several hundred hours, and during numerous thermal cycling from 400 to 800 C with different heating rates. The technology significantly extends applicability of optical sensors to high-temperature environments including ground testing of engines, flight propulsion control, thermal protection monitoring of launch vehicles, etc. It may also find applications in such non-aerospace arenas as monitoring of nuclear reactors, furnaces, chemical processes, and other hightemperature environments where other measurement techniques are either unreliable, dangerous, undesirable, or unavailable.

  5. High temperature corrosion in gasifiers

    Directory of Open Access Journals (Sweden)

    Bakker Wate


    Full Text Available Several commercial scale coal gasification combined cycle power plants have been built and successfully operated during the last 5-10 years. Supporting research on materials of construction has been carried out for the last 20 years by EPRI and others. Emphasis was on metallic alloys for heat exchangers and other components in contact with hot corrosive gases at high temperatures. In this paper major high temperature corrosion mechanisms, materials performance in presently operating gasifiers and future research needs will be discussed.

  6. High temperature polymer matrix composites (United States)

    Serafini, Tito T. (Editor)


    These are the proceedings of the High Temperature Polymer Matrix Composites Conference held at the NASA Lewis Research Center on March 16 to 18, 1983. The purpose of the conference is to provide scientists and engineers working in the field of high temperature polymer matrix composites an opportunity to review, exchange, and assess the latest developments in this rapidly expanding area of materials technology. Technical papers are presented in the following areas: (1) matrix development; (2) adhesive development; (3) Characterization; (4) environmental effects; and (5) applications.

  7. High temperature superconductor current leads

    Energy Technology Data Exchange (ETDEWEB)

    Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)


    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  8. The sensitivity of production temperatures and thermal recharge of low-enthalpy geothermal reservoirs to the thermal conductivity of the confining beds (United States)

    Erbs Poulsen, Søren; Balling, Niels; Bom Nielsen, Søren


    The exploration and exploitation of low-enthalpy geothermal energy has increased globally within recent decades in the pursuit of sustainable, low carbon emission energy sources. In 2009 funding was dedicated to a national multi-disciplinary research project with the aim of quantifying the thermal properties and temperature distributions of geothermal reservoirs in Denmark and to develop models for utilisation. The Danish subsurface encompasses low-enthalpy geothermal reservoirs of Triassic, Jurassic, and Cretaceous age with formation temperatures between 40° C and 80° C. In previous literature it is shown that the ratio between the circulation rate in doublet well configurations and the vertical thermal conductivity of confining rocks significantly influences the temporal development in production temperatures in low-enthalpy geothermal reservoirs. We analyse the thermal interplay between a reservoir which is utilised by an injection- and production well, and its confining beds in four conceptual reservoir systems, inspired by the low-enthalpy reservoirs found in Denmark. The analysis is based on state-of-the-art high resolution finite element modelling. Three of the four conceptual reservoirs represent different geological settings in which the confining beds of the reservoir have different thermal conductivities. In the first case, no heat is conducted across the boundaries of the reservoir, which serves merely as a reference. In the three remaining cases, the matrix thermal conductivity of the confining beds is set equal to 1.5, 3 and 4.5 W/m/K. In one additional case study, the anisotropy of the thermal conductivity of the confining beds is increased from 1 (isotropic) to 1.7 (horizontal conductivity is set equal to 1.5 W/m/K). For the considered reservoirs, we calculate the ratio between the accumulated energy that can be attributed conductive heat flow from the confining beds to the reservoir and the accumulated extracted energy from the pumping well

  9. Nonlinear plasmonics at high temperatures

    Directory of Open Access Journals (Sweden)

    Sivan Yonatan


    Full Text Available We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  10. Nonlinear plasmonics at high temperatures (United States)

    Sivan, Yonatan; Chu, Shi-Wei


    We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW) illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  11. Nonlinear plasmonics at high temperatures

    CERN Document Server

    Sivan, Yonatan


    We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW) illumination. Unlike previous studies, we rely on {\\em experimentally}-measured data for the metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution, and thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modelling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high temperature non...

  12. Establishing Bedding Requirements during Transport and Monitoring Skin Temperature during Cold and Mild Seasons after Transport for Finishing Pigs

    Directory of Open Access Journals (Sweden)

    John McGlone


    Full Text Available The broad aim of this study was to determine whether bedding level in the transport trailer influenced pig performance and welfare. Specifically, the objective was to define the bedding requirements of pigs during transportation in commercial settings during cold and mild weather. Animals (n = 112,078 pigs on 572 trailers used were raised in commercial finishing sites and transported in trailers to commercial processing plants. Dead on arrival (DOA, non-ambulatory (NA, and total dead and down (D&D data were collected and skin surface temperatures of the pigs were measured by infrared thermography. Data were collected during winter (Experiment 1 and fall/spring (Experiment 2. Total D&D percent showed no interaction between bedding level and outside air temperature in any experiments. Average skin surface temperature during unloading increased with outside air temperature linearly in both experiments (P < 0.01. In conclusion, over-use of bedding may be economically inefficient. Pig skin surface temperature could be a useful measure of pig welfare during or after transport.

  13. High-temperature Titanium Alloys

    Directory of Open Access Journals (Sweden)

    A.K. Gogia


    Full Text Available The development of high-temperature titanium alloys has contributed significantly to the spectacular progress in thrust-to-weight ratio of the aero gas turbines. This paper presents anoverview on the development of high-temperature titanium alloys used in aero engines and potential futuristic materials based on titanium aluminides and composites. The role of alloychemistry, processing, and microstructure, in determining the mechanical properties of titanium alloys is discussed. While phase equilibria and microstructural stability consideration haverestricted the use of conventional titanium alloys up to about 600 "C, alloys based on TiPl (or,, E,AINb (0, TiAl (y, and titaniumltitanium aluminides-based composites offer a possibility ofquantum jump in the temperature capability of titanium alloys.

  14. Chemistry of high temperature superconductors

    CERN Document Server


    This review volume contains the most up-to-date articles on the chemical aspects of high temperature oxide superconductors. These articles are written by some of the leading scientists in the field and includes a comprehensive list of references. This is an essential volume for researchers working in the fields of ceramics, materials science and chemistry.

  15. An Experimental Study on Axial Temperature Distribution of Combustion of Dewatered Poultry Sludge in Fluidized bed combustor

    Directory of Open Access Journals (Sweden)

    Abbas A.H.


    Full Text Available A laboratory scale bubbling fluidized bed combustor was designed and fabricated to study the combustion of dewatered poultry sludge at different operational parameters. This paper present a study on the influence of equivalent ratio, secondary to primary air ratio and the fuel feed rate on the temperature distribution along the combustor. The equivalent ratio has been changed between 0.8 to 1.4% under poultry sludge feed rate of 10 kg/h and from 0.8 to 1 under poultry sludge feed rate of 15 kg/h. The secondary to primary air ratio was varied from 0.1 to 0.5 at 0.65 m injection height and 1.25 equivalent ratio. The results showed that these factors had a significant influence on the combustion characteristics of poultry sludge. The temperature distribution along the combustor was found to be strongly dependent on the fuel feed rate and the equivalent ratio and it increased when these two factors increased. However, the secondary air ratio increased the temperature in the lower region of the combustor while no significant effect was observed at the upper region of the combustor. The results suggested that the poultry sludge can be used as a fuel with high thermal combustor efficiency.

  16. Three-Dimensional Analysis of the Hot-Spot Fuel Temperature in Pebble Bed and Prismatic Modular Reactors

    Energy Technology Data Exchange (ETDEWEB)

    In, W. K.; Lee, S. W.; Lim, H. S.; Lee, W. J. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    High temperature gas-cooled reactors(HTGR) have been reviewed as potential sources for future energy needs, particularly for a hydrogen production. Among the HTGRs, the pebble bed reactor(PBR) and a prismatic modular reactor(PMR) are considered as the nuclear heat source in Korea's nuclear hydrogen development and demonstration project. PBR uses coated fuel particles embedded in spherical graphite fuel pebbles. The fuel pebbles flow down through the core during an operation. PMR uses graphite fuel blocks which contain cylindrical fuel compacts consisting of the fuel particles. The fuel blocks also contain coolant passages and locations for absorber and control material. The maximum fuel temperature in the core hot spot is one of the important design parameters for both a PBR and a PMR. The objective of this study is to predict the hot-spot fuel temperature distributions in a PBR and a PMR at a steady state. The computational fluid dynamics(CFD) code, CFX-10 is used to perform the three-dimensional analysis. The latest design data was used here based on the reference reactor designs, PBMR400 and GTMHR60.

  17. High temperature, high power piezoelectric composite transducers. (United States)

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, Stewart


    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined.

  18. High Temperature Sorbents for Oxygen (United States)

    Sharma, Pramod K. (Inventor)


    A sorbent capable of removing trace amounts of oxygen (ppt) from a gas stream at a high temperature above 200 C is introduced. The sorbent comprises a porous alumina silicate support such as zeolite containing from 1 to 10 percent by weight of ion exchanged transition metal such as copper or cobalt ions and 0.05 to 1.0 percent by weight of an activator selected from a platinum group metal such as platinum. The activation temperature, oxygen sorption and reducibility are all improved by the presence of the platinum activator.

  19. Preliminary Neutronic Design of High Burnup OTTO Cycle Pebble Bed Reactor

    Directory of Open Access Journals (Sweden)

    T. Setiadipura


    Full Text Available The pebble bed type High Temperature Gas-cooled Reactor (HTGR is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor design in general, is improving the nuclear fuel utilization which is shown by attaining a higher burnup value. This study performed a preliminary neutronic design study of a 200 MWt OTTO cycle PBR with high burnup while fulfilling the safety criteria of the PBR design.The safety criteria of the design was represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. The maximum burnup value was also limited by the tested maximum burnup value which maintained the integrity of the pebble fuel. Parametric surveys were performed to obtain the optimized parameters used in this study, which are the fuel enrichment, per-pebble heavy metal (HM loading, and the average axial speed of the fuel. An optimum design with burnup value of 131.1 MWd/Kg-HM was achieved in this study which is much higher compare to the burnup of the reference design HTR-MODUL and a previously proposed OTTO-cycle PBR design. This optimum design uses 17% U-235 enrichment with 4 g HM-loading per fuel pebble

  20. High gradient magnetic separation versus expanded bed adsorption: a first principle comparison

    DEFF Research Database (Denmark)

    Hubbuch, Jürgen; Matthiesen, D.B.; Hobley, Timothy John


    A robust new adsorptive separation technique specifically designed for direct product capture from crude bioprocess feedstreams is introduced and compared with the current bench mark technique, expanded bed adsorption. The method employs product adsorption onto sub-micron sized non...... system exhibited substantially enhanced productivity over expanded bed adsorption when operated at processing velocities greater than 48 m h(-1). Use of the bacitracin- linked magnetic supports for a single cycle of batch adsorption and subsequent capture by high gradient magnetic separation...... at a processing rate of 12 m h(-1) resulted in a 2.2-fold higher productivity relative to expanded bed adsorption, while an increase in adsorbent collection rate to 72 m h(-1) raised the productivity to 10.7 times that of expanded bed adsorption. When the number of batch adsorption cycles was then increased...

  1. 高温堆球床等效导热系数测量实验加热系统设计及可行性验证%Heating system design and validation for the pebble bed effective thermal conductivity experiment in a high temperature gas-cooled reactor

    Institute of Scientific and Technical Information of China (English)

    任成; 杨星团; 李聪新; 孙艳飞; 姜胜耀


    A high temperature gas cooled reactor full-scale pebble bed effective thermal conductivity experimental facility was developed to measure the effective thermal conductivity for the full range of temperatures.This paper describes the materials,structures and insulation of the heating system of the experimental facility.A small validation experiment showed several technical problems,such as the heater material,carbonization of the ceramic parts and heat dissipation in the insulating layers.The central heater consisted of nine tubular graphite heating units and a 100 mm thick graphite sleeve to make the temperature more uniform.The validation experiment results show that the test temperature could reach 1 600 ℃ and be maintained for a long period,which indicated the material and heater structure met the design requirements for the effective thermal conductivity experimental facility.%为保障高温气冷核反应堆全尺寸堆芯球床等效导热系数研究实验装置在金工况温度范围内实验的顺利实施,详细设计了等效导热系数实验装置加热系统的选材、结构、绝缘及引出方式.进行了比例缩小的验证实验,分析讨论了实验体现出的加热器材料、绝缘件碳化及保温层内散热等技术难点问题.加热器由9组管状石墨单体连接而成,形成圆柱形中心加热体,外置厚100 mm的石墨均温套筒.验证实验结果表明:测试温度达到1 600℃以上可长时间稳定可靠运行,关键结构和材料达到设计要求,可有效保障导热系数实验的测量需求.

  2. High temperature structural sandwich panels (United States)

    Papakonstantinou, Christos G.

    High strength composites are being used for making lightweight structural panels that are being employed in aerospace, naval and automotive structures. Recently, there is renewed interest in use of these panels. The major problem of most commercial available sandwich panels is the fire resistance. A recently developed inorganic matrix is investigated for use in cases where fire and high temperature resistance are necessary. The focus of this dissertation is the development of a fireproof composite structural system. Sandwich panels made with polysialate matrices have an excellent potential for use in applications where exposure to high temperatures or fire is a concern. Commercial available sandwich panels will soften and lose nearly all of their compressive strength temperatures lower than 400°C. This dissertation consists of the state of the art, the experimental investigation and the analytical modeling. The state of the art covers the performance of existing high temperature composites, sandwich panels and reinforced concrete beams strengthened with Fiber Reinforced Polymers (FRP). The experimental part consists of four major components: (i) Development of a fireproof syntactic foam with maximum specific strength, (ii) Development of a lightweight syntactic foam based on polystyrene spheres, (iii) Development of the composite system for the skins. The variables are the skin thickness, modulus of elasticity of skin and high temperature resistance, and (iv) Experimental evaluation of the flexural behavior of sandwich panels. Analytical modeling consists of a model for the flexural behavior of lightweight sandwich panels, and a model for deflection calculations of reinforced concrete beams strengthened with FRP subjected to fatigue loading. The experimental and analytical results show that sandwich panels made with polysialate matrices and ceramic spheres do not lose their load bearing capability during severe fire exposure, where temperatures reach several

  3. Motor for High Temperature Applications (United States)

    Roopnarine (Inventor)


    A high temperature motor has a stator with poles formed by wire windings, and a rotor with magnetic poles on a rotor shaft positioned coaxially within the stator. The stator and rotor are built up from stacks of magnetic-alloy laminations. The stator windings are made of high temperature magnet wire insulated with a vitreous enamel film, and the wire windings are bonded together with ceramic binder. A thin-walled cylinder is positioned coaxially between the rotor and the stator to prevent debris from the stator windings from reaching the rotor. The stator windings are wound on wire spools made of ceramic, thereby avoiding need for mica insulation and epoxy/adhesive. The stator and rotor are encased in a stator housing with rear and front end caps, and rear and front bearings for the rotor shaft are mounted on external sides of the end caps to keep debris from the motor migrating into the bearings' races.

  4. High Temperature Heat Exchanger Project

    Energy Technology Data Exchange (ETDEWEB)

    Anthony E. Hechanova, Ph.D.


    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  5. The Design of Impact Test-Bed for High-Flow Water Medium Relief Valve

    Directory of Open Access Journals (Sweden)

    Junliang Chang


    Full Text Available Water medium hydraulic systems are widely used in coal mining machinery. As the power of hydraulic system becomes higher, the flow and pressure of water medium relief valve are also higher, and the flow may reach 2000 L/min. However, there is no relevant test-bed which could provide instantaneous high-pressure and high-flow to support the experiment for high-flow relief valve; consequently, this impact test-bed for high-flow water medium relief valve is designed to satisfy fast loading demand. Through building model, simulation analysis, and construction of an impact test-bed of high-flow water medium relief valve, the dynamic performance of high-flow water medium relief valve is detected. The setting pressure of relief valve, the accumulator volume and the filling fluid pressure, and the damping of cartridge valve can be changed, and the dynamic performance of high-flow water medium relief valve under different impact loads is detected. The results show that the designed impact test-bed of high-flow water medium relief valve could provide required high-pressure and high-flow emulsion for the tested water medium relief valve, and it could control the strength of impact load, which is an energy saving, high efficiency, and low cost method.

  6. Very High Temperature Sound Absorption Coating Project (United States)

    National Aeronautics and Space Administration — Phase I demonstrated experimentally a very high temperature acoustically absorbing coating for ducted acoustics applications. High temperature survivability at 3500...

  7. Temperature uniformity mapping in a high pressure high temperature reactor using a temperature sensitive indicator

    NARCIS (Netherlands)

    Grauwet, T.; Plancken, van der I.; Vervoort, L.; Matser, A.M.; Hendrickx, M.; Loey, van A.


    Recently, the first prototype ovomucoid-based pressure–temperature–time indicator (pTTI) for high pressure high temperature (HPHT) processing was described. However, for temperature uniformity mapping of high pressure (HP) vessels under HPHT sterilization conditions, this prototype needs to be optim

  8. Passivation of high temperature superconductors (United States)

    Vasquez, Richard P. (Inventor)


    The surface of high temperature superconductors such as YBa2Cu3O(7-x) are passivated by reacting the native Y, Ba and Cu metal ions with an anion such as sulfate or oxalate to form a surface film that is impervious to water and has a solubility in water of no more than 10(exp -3) M. The passivating treatment is preferably conducted by immersing the surface in dilute aqueous acid solution since more soluble species dissolve into the solution. The treatment does not degrade the superconducting properties of the bulk material.

  9. Hydrogen-rich gas production by steam gasification of char from biomass fast pyrolysis in a fixed-bed reactor: influence of temperature and steam on hydrogen yield and syngas composition. (United States)

    Yan, Feng; Luo, Si-yi; Hu, Zhi-quan; Xiao, Bo; Cheng, Gong


    Steam gasification experiments of biomass char were carried out in a fixed-bed reactor. The experiments were completed at bed temperature of 600-850 degrees C, a steam flow rate of 0-0.357 g/min/g of biomass char, and a reaction time of 15min. The aim of this study is to determine the effects of bed temperature and steam flow rate on syngas yield and its compositions. The results showed that both high gasification temperature and introduction of proper steam led to higher yield of dry gas and higher carbon conversion efficiency. However, excessive steam reduced gas yield and carbon conversion efficiency. The maximum dry gas yield was obtained at the gasification temperature of 850 degrees C and steam flow rate of 0.165 g/min/g biomass char.

  10. Reduced bed temperature at thermo-chemical conversion of difficult fuels; Saenkt baeddtemperatur vid termokemisk omvandling av svaara braenslen

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Haraldsson, Conny; Johansson, Andreas; Claesson, Frida; Baefver, Linda; Ryde, Daniel


    This work investigates the prospect of reducing the concentrations of alkali chlorides in the flue gas by lowering the temperature in the bottom zone of a fluidized bed (FB) furnace below the often used 850 deg C. The directive of a retention time of at least two seconds above 850 deg C is fulfilled by the raise of the flue gas temperature that follows the combustion of unburned gases at the point of injection of secondary and tertiary air, above the bottom bed zone. The aim of the present experiments is to determine the dependency between the temperature and the amount of alkali metals leaving the bottom bed for some selected waste and biomass fuels. The results are intended for plant owners as well as boiler manufacturers. The experiments were performed in an FB-reactor, which was externally heated to specific temperatures between 550 and 850 deg C. The reactor is made of a quartz glass tube with an inner diameter of 60 mm and a length of 1.2 m. The fluidized bed rests upon a porous plate of sintered quartz. The bed material used was 180 gram purified sea sand with particle sizes between 0.1 and 0.3 mm. The fluidizing gas was a mixture of nitrogen and air, introduced in the bottom of the reactor by mass flow controllers. At the outlet of the reactor, the flue gas was divided between conventional gas analyzers and an ICP-MS instrument. The gas flow to the ICP-MS instrument was cooled before a slip stream was sucked out via a capillary to a nebulizer from which the sample gas was led to the ICP-MS instrument. The function of the nebulizer is normally to form an aerosol of liquids, but here it was used solely as a pump. In addition, a known flow of krypton was added into the nebulizer to be used as an internal standard. The novel technique to measure the amount of alkali metals on-line from a batch fired FB-reactor has been shown to work in practice and to provide interesting results, which so far is qualitative only. Further development and calibration work is

  11. High Temperature Radio Frequency Loads

    CERN Document Server

    Federmann, S; Grudiev, A; Montesinos, E; Syratchev, I


    In the context of energy saving and recovery requirements the design of reliable and robust RF power loads which permit a high outlet temperature and high pressure of the cooling water is desirable. Cooling water arriving at the outlet withmore than 150 ◦C and high pressure has a higher value than water with 50 ◦C under low pressure. Conventional RF power loads containing dielectric and magnetic materials as well as sensitive ceramic windows usually do not permit going much higher than 90 ◦C. Here we present and discuss several design concepts for "metal only" RF high power loads. One concept is the application of magnetic steel corrugated waveguides near cutoff – this concept could find practical use above several GHz. Another solution are resonant structures made of steel to be installed in large waveguides for frequencies of 500 MHz or lower. Similar resonant structures above 100 MHz taking advantage of the rather high losses of normal steel may also be used in coaxial line geometries with large di...



    Ermuratschii V.V.; Gritsay M.A


    e paper presents a method of the approximate calculation of the non-stationary temperature field inside of thermal packed bed energy storages with feasible and latent heat. Applying thermoelectric models and computational methods in electrical engineering, the task of computing non-stationary heat transfer is resolved with respect to third type boundary conditions without applying differential equations of the heat transfer. For sub-volumes of the energy storage the method is executed iterati...

  13. High Temperature Superconductor Accelerator Magnets

    CERN Document Server

    AUTHOR|(CDS)2079328; de Rijk, Gijs; Dhalle, Marc


    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is based on ReBCO coated conductor, which is assembled into a $10kA$ class Roebel cable. A new and optimized Aligned Block layout is used, which takes advantage of the anisotropy of the conductor. This is achieved by providing local alignment of the Roebel cable in the coil windings with the magnetic field lines. A new Network Model capable of analyzing transient electro-magnetic and thermal phenomena in coated conductor cables and coils is developed. This model is necessary to solve critical issues in coated conductor ac...


    Directory of Open Access Journals (Sweden)

    Ermuratschii V.V.


    Full Text Available e paper presents a method of the approximate calculation of the non-stationary temperature field inside of thermal packed bed energy storages with feasible and latent heat. Applying thermoelectric models and computational methods in electrical engineering, the task of computing non-stationary heat transfer is resolved with respect to third type boundary conditions without applying differential equations of the heat transfer. For sub-volumes of the energy storage the method is executed iteratively in spatiotemporal domain. Single-body heating is modeled for each sub-volume, and modeling conditions are assumed to be identical for remained bod-ies, located in the same sub-volume. For each iteration step the boundary conditions will be represented by re-sults at the previous step. The fulfillment of the first law of thermodynamics for system “energy storage - body” is obtained by the iterative search of the mean temperature of the energy storage. Under variable boundary con-ditions the proposed method maybe applied to calculating temperature field inside of energy storages with packed beds consisted of solid material, liquid and phase-change material. The method may also be employed to compute transient, power and performance characteristics of packed bed energy storages.

  15. High Levels Of Bed Occupancy Associated With Increased Inpatient And Thirty-Day Hospital Mortality In Denmark

    DEFF Research Database (Denmark)

    Madsen, Flemming; Ladelund, Steen; Linneberg, Allan


    High bed occupancy rates have been considered a matter of reduced patient comfort and privacy and an indicator of high productivity for hospitals. Hospitals with bed occupancy rates of above 85 percent are generally considered to have bed shortages. Little attention has been paid to the impact...... of these shortages on patients' outcomes. We analyzed all 2.65 million admissions to Danish hospitals' departments of medicine in the period 1995-2012. We found that high bed occupancy rates were associated with a significant 9 percent increase in rates of in-hospital mortality and thirty-day mortality, compared...... to low bed occupancy rates. Being admitted to a hospital outside of normal working hours or on a weekend or holiday was also significantly associated with increased mortality. The health risks of bed shortages, including mortality, could be better documented as a priority health issue. Resources should...

  16. Faraday imaging at high temperatures (United States)

    Hackel, Lloyd A.; Reichert, Patrick


    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  17. High temperature control rod assembly

    Energy Technology Data Exchange (ETDEWEB)

    Vollman, Russell E. (Solana Beach, CA)


    A high temperature nuclear control rod assembly comprises a plurality of substantially cylindrical segments flexibly joined together in succession by ball joints. The segments are made of a high temperature graphite or carbon-carbon composite. The segment includes a hollow cylindrical sleeve which has an opening for receiving neutron-absorbing material in the form of pellets or compacted rings. The sleeve has a threaded sleeve bore and outer threaded surface. A cylindrical support post has a threaded shaft at one end which is threadably engaged with the sleeve bore to rigidly couple the support post to the sleeve. The other end of the post is formed with a ball portion. A hollow cylindrical collar has an inner threaded surface engageable with the outer threaded surface of the sleeve to rigidly couple the collar to the sleeve. the collar also has a socket portion which cooperates with the ball portion to flexibly connect segments together to form a ball and socket-type joint. In another embodiment, the segment comprises a support member which has a threaded shaft portion and a ball surface portion. The threaded shaft portion is engageable with an inner threaded surface of a ring for rigidly coupling the support member to the ring. The ring in turn has an outer surface at one end which is threadably engageably with a hollow cylindrical sleeve. The other end of the sleeve is formed with a socket portion for engagement with a ball portion of the support member. In yet another embodiment, a secondary rod is slidably inserted in a hollow channel through the center of the segment to provide additional strength. A method for controlling a nuclear reactor utilizing the control rod assembly is also included.

  18. Development of high temperature coal gas desulfurization systems -- An overview

    Energy Technology Data Exchange (ETDEWEB)

    Abbasian, J.; Slimane, R.B.; Lau, F.S.; Wangergow, J.R.; Zarnegar, M.K. [Inst. of Gas Technology, Des Plaines, IL (United States)


    Integrated Gasification Combined-Cycle (IGCC) processes are among the leading contenders for generation of electricity from coal in the 21st century. Coal gas desulfurization to sufficiently low levels at temperatures above 350 C is now recognized as crucial to efficient and economical utilization of coal in advanced IGCC processes. The implementation of hot coal gas desulfurization heavily relies on the development of regenerable sorbent materials that can efficiently remove H{sub 2}S (from several thousand ppmv levels down to a few ppmv) over a very large number of sulfidation/regeneration cycles. Over the last two decades, development of high temperature desulfurization sorbents has been focused on using various combinations of transition metal oxides as regenerable sorbents. The selection of suitable metal oxides is generally based on a number of requirements imposed by the IGCC process, which include favorable thermodynamic equilibria during sulfidation and regeneration, relatively high sulfidation and regeneration reactivities, good mechanical strength and structural stability, and environmental friendliness, all at a reasonably low cost. The desulfurization reactor can have a fixed-bed, a moving-bed, a transport reactor, or a bubbling fluidized-bed reactor design. Depending on process conditions and the application intended, each of these reactor configurations offers advantages, but also has limitations. The parameters guiding the choice of a reactor system include reactivity of the sorbent, crush strength and/or attrition resistance of the sorbent, absorption capacity of the sorbent, temperature distribution inside the reactors, and SO{sub 2} concentration in the regeneration product gas. This paper provides an overview of high temperature fuel gas desulfurization within the context of IGCC processes. The paper focuses on the studies related to the development of regenerable sorbents and addresses thermodynamic considerations, sulfidation kinetics

  19. The Metabolic Cost of a High Intensity Exercise Program During Bed Rest (United States)

    Hackney, Kyle; Everett, Meghan; Guined, Jamie; Cunningham, Daid


    Background: Given that disuse-related skeletal muscle atrophy may be exacerbated by an imbalance between energy intake and output, the amount of energy required to complete exercise countermeasures is an important consideration in the well being of subject health during bed rest and spaceflight. Objective: To evaluate the energy cost of a high intensity exercise program performed during short duration bed rest. Methods: 9 subjects (8 male and 1 female; 34.5 +/- 8.2 years) underwent 14 days of bed rest and exercise countermeasures. Exercise energy expenditure and excess post exercise oxygen consumption (EPOC) were collected once in each of 5 different exercise protocols (30 second, 2 minute and 4 minute intervals, continuous aerobic and a variety of resistance exercises) during bed rest. Body mass, basal metabolic rate (BMR), upper and lower leg muscle, subcutaneous, and intramuscular adipose tissue (IMAT) volumes were assessed before and at the end of bed rest. Results: There were no significant differences in body mass (pre: 75.1 +/- 10.5 kg; post: 75.2 +/- 10.1 kg), BMR (pre: 1649 +/- 216 kcal; post: 1657 +/- 177 kcal), muscle subcutaneous, or IMAT volumes (Table 2) after 14 days of bed rest and exercise. Body mass was maintained with an average daily intake of 2710 +/- 262 kcal (36.2 +/- 2.1 kcal/kg/day), while average daily energy expenditure was 2579 +/-311 kcal (34.5 +/- 3.6 kcal/kg/day). Exercise energy expenditure was significantly greater as a result of continuous aerobic exercise than all other exercise protocols.

  20. Isolation and identification of microorganisms from high temperature seaweed beds and study on the characteristics of thermo and salt tolerances%高温海藻床中微生物的分离鉴定及其耐热、耐盐特性研究

    Institute of Scientific and Technical Information of China (English)

    何培青; 许守英; 黄晓航; DEWI Seswita-Zilda; 张强


    [Objective] Microorganisms from high temperature seaweed beds on Kalianda Island of Indian Ocean were isolated, cultivated, and identified based on 16S rDNA sequences.Study on characteristics of thermo and salt tolerances of selected isolates were also carried on.[Methods] Samples of alga Sargasso sp., sediment and water from seaweed beds were collected.Using MGYTC medium, microorganisms from the samples were cultivated and purified at 55 ℃ and 30 ℃, respectively.Species identification was determined based on 16S rDNA sequences and phylogenetic tree was built afterwards.Effects of culture temperature and salinity on bacterial growth were determined.[Results] A total of 12 strains belonged to four classes and nine genuses were obtained, and the maximum similarities were higher than 98% with known species.Two strains belonged to different genus of Thermoactinomyceta-ceae, and two Bacillus strains obtained at 55 ℃ were thermophile.Laceyella sacchari and Bacillus thermoamylovorans can survive at the range of 0-90 salinity.Shewanella upenei, Shewanella algidipiscicola and Shewanella haliotis belonged to y-Proteobacteria could grow at the temperature of 30 ℃-55 ℃.[Conclusion] The strains obtained had features of thermo and salt tolerances, or adaptability to wide temperature range, which were expected to be new resources in biotechnology field.The isolates of Tepidibacter formicigenes, Exiguobacterium profundum and Vibrio diabolicus had been originally reported from the deep-sea hydrothermal area, suggesting the internal relations of marine hot spring system and deep-sea hydrothermal environment.%[目的]对印度洋卡利安达岛海洋热泉周边的高温海藻床中的微生物进行分离培养和16S rDNA种属鉴定,并研究其耐热和耐盐特性.[方法]采集海藻床中马尾藻、沉积物和海水样品,采用MGYTC培养基,分别于55℃和30℃对样品中的微生物进行培养和分离纯化;采用16S rDNA鉴定种属并构建进化树;研

  1. Temperature Dependent Residual Stress Models for Ultra-High-Temperature Ceramics on High Temperature Oxidation (United States)

    Wang, Ruzhuan; Li, Weiguo


    The strength of SiC-depleted layer of ultra-high-temperature ceramics on high temperature oxidation degrades seriously. The research for residual stresses developed within the SiC-depleted layer is important and necessary. In this work, the residual stress evolutions in the SiC-depleted layer and the unoxidized substrate in various stages of oxidation are studied by using the characterization models. The temperature and oxidation time dependent mechanical/thermal properties of each phase in SiC-depleted layer are considered in the models. The study shows that the SiC-depleted layer would suffer from large tensile stresses due to the great temperature changes and the formation of pores on high temperature oxidation. The stresses may lead to the cracking and even the delamination of the oxidation layer.

  2. Ash agglomeration during fluidized bed gasification of high sulphur content lignites

    Energy Technology Data Exchange (ETDEWEB)

    Marinov, V.; Marinov, S.P.; Lazarov, L.; Stefanova, M. (SRTI Energydesign, Sofia (Bulgaria))


    Intensive ash agglomeration has hampered the fluidized bed gasification of lignites from the Elhovo deposit (Bulgaria) containing 5.9 wt% sulphur in the dry state. Samples of slag and agglomerates from the pilot plant have been examined by means of chemical, X-ray analysis, IR spectroscopy and scanning electron microscopy. Pyrrhotite (FeS) and wustite (FeO) have been established in the agglomerates, where junctions between ash particles have been found to consist of magnetite, spinel and garnet grains. The chemical reactions leading to garnet formation have been studied. Centres of sintering and centres of melting during the ash agglomeration process have been distinguished. The pyrite product, an eutectic of FeS and FeO melting at 924[degree]C, is assumed to be responsible for the cessation of lignite gasification with steam and air under pressure at a bed temperature of 930[degree]. 11 refs., 3 figs., 6 tabs.

  3. Reduced Bed Temperature in FB-Boilers Burning Waste - part II; Saenkt baeddtemperatur i FB-pannor foer avfallsfoerbraenning - etapp 2

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Pettersson, Anita; Claesson, Frida; Johansson, Andreas; Gunnarsson, Anders; Gyllenhammar, Marianne; Victoren, Anders; Gustafsson, Goeran


    This project focuses on evaluating whether lowered bed temperature in FB-boilers for waste combustion gives operational benefits, such as reduced fouling in the convection pass. If so, this mode of operation could reduce the number of unplanned boiler outages, reduce the need for soot blowing, and extend the lifetime of the superheaters at unaltered steam temperature. The project is based on full-scale experiments performed at Ryaverket in Boraas. The plant has two waste-fired 20 MW{sub t} FB-boilers. The study is based on a comparison between operational data and measurement results from two different operating conditions of the boilers. In addition to the data that normally are logged by the control system, samples of fuel, ashes, particles, and deposits were taken and subsequently analyzed. The structure of the bed ash was altered by lowering the bed temperature. Under normal boiler operation, the bed ash contains many small agglomerates that disappeared when the bed temperature was lowered. Due to this, the sand consumption of the plant could be reduced by roughly 25 %. At lowered bed temperature, the concentration of chlorine increased in the bed ash and in the recycled sand while it decreased in the ashes from the cyclone and fabric filter. The concentration of HCl in the flue gas increased as the bed temperature was lowered. This is considered a consequence of less chlorine forming alkali chlorides. Moreover, the particle measurements showed that the amount of submicron particles decreased during lowered bed temperature, which also is an indication of less alkali chlorides in the flue gas. The deposit probes showed an approximate 20 % reduction of the fouling rate when the bed temperature was lowered from 876 to 714 deg C. The chlorine content also decreased in the deposits. For the deposit probes at 500 deg C, (corresponds to a steam temperature of 465 deg C) significant amounts of KCl were found in the deposits, even when the bed temperature was lowered

  4. Thermochemical process for seasonal storage of solar energy: characterization and modeling of a high-density reactive bed


    Michel, Benoit; Mazet, Nathalie; Mauran, Sylvain; Stitou, Driss; Jing XU


    International audience; This paper focuses on the characterization and modeling of a solid/gas thermochemical reaction between a porous reactive bed and moist air flowing through it. The aim is the optimization of both energy density and permeability of the reactive bed, in order to realize a high density thermochemical system for seasonal thermal storage for house heating application. Several samples with different implementation parameters (density, binder, diffuser, porous bed texture) hav...

  5. Reduced bed temperature at thermo-chemical conversion of difficult fuels; Saenkt baeddtemperatur vid termokemisk omvandling av svaara braenslen

    Energy Technology Data Exchange (ETDEWEB)

    Niklasson, Fredrik; Haraldsson, Conny; Johansson, Andreas; Claesson, Frida; Baefver, Linda; Ryde, Daniel


    This work investigates the prospect of reducing the concentrations of alkali chlorides in the flue gas by lowering the temperature in the bottom zone of a fluidized bed (FB) furnace below the often used 850 deg C. The directive of a retention time of at least two seconds above 850 deg C is fulfilled by the raise of the flue gas temperature that follows the combustion of unburned gases at the point of injection of secondary and tertiary air, above the bottom bed zone. The aim of the present experiments is to determine the dependency between the temperature and the amount of alkali metals leaving the bottom bed for some selected waste and biomass fuels. The results are intended for plant owners as well as boiler manufacturers. The experiments were performed in an FB-reactor, which was externally heated to specific temperatures between 550 and 850 deg C. The reactor is made of a quartz glass tube with an inner diameter of 60 mm and a length of 1.2 m. The fluidized bed rests upon a porous plate of sintered quartz. The bed material used was 180 gram purified sea sand with particle sizes between 0.1 and 0.3 mm. The fluidizing gas was a mixture of nitrogen and air, introduced in the bottom of the reactor by mass flow controllers. At the outlet of the reactor, the flue gas was divided between conventional gas analyzers and an ICP-MS instrument. The gas flow to the ICP-MS instrument was cooled before a slip stream was sucked out via a capillary to a nebulizer from which the sample gas was led to the ICP-MS instrument. The function of the nebulizer is normally to form an aerosol of liquids, but here it was used solely as a pump. In addition, a known flow of krypton was added into the nebulizer to be used as an internal standard. The novel technique to measure the amount of alkali metals on-line from a batch fired FB-reactor has been shown to work in practice and to provide interesting results, which so far is qualitative only. Further development and calibration work is

  6. High-temperature thermocouples and related methods (United States)

    Rempe, Joy L.; Knudson, Darrell L.; Condie, Keith G.; Wilkins, S. Curt


    A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

  7. High Temperature Superconducting Underground Cable

    Energy Technology Data Exchange (ETDEWEB)

    Farrell, Roger, A.


    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  8. High temperature suppression of dioxins. (United States)

    Zhan, Ming-Xiu; Chen, Tong; Fu, Jian-Ying; Lin, Xiao-Qing; Lu, Sheng-Yong; Li, Xiao-Dong; Yan, Jian-Hua; Buekens, Alfons


    Combined Sulphur-Nitrogen inhibitors, such as sewage sludge decomposition gases (SDG), thiourea and amidosulphonic acid have been observed to suppress the de novo synthesis of dioxins effectively. In this study, the inhibition of PCDD/Fs formation from model fly ash was investigated at unusually high temperatures (650 °C and 850 °C), well above the usual range of de novo tests (250-400 °C). At 650 °C it was found that SDG evolving from dried sewage sludge could suppress the formation of 2,3,7,8-substituted PCDD/Fs with high efficiency (90%), both in weight units and in I-TEQ units. Additionally, at 850 °C, three kinds of sulphur-amine or sulphur-ammonium compounds were tested to inhibit dioxins formation during laboratory-scale tests, simulating municipal solid waste incineration. The suppression efficiencies of PCDD/Fs formed through homogeneous gas phase reactions were all above 85% when 3 wt. % of thiourea (98.7%), aminosulphonic acid (96.0%) or ammonium thiosulphate (87.3%) was added. Differences in the ratio of PCDFs/PCDDs, in weight average chlorination level and in the congener distribution of the 17 toxic PCDD/Fs indicated that the three inhibitors tested followed distinct suppression pathways, possibly in relation to their different functional groups of nitrogen. Furthermore, thiourea reduced the (weight) average chlorinated level. In addition, the thermal decomposition of TUA was studied by means of thermogravimetry-fourier transform infrared spectroscopy (TG-FTIR) and the presence of SO2, SO3, NH3 and nitriles (N≡C bonds) was shown in the decomposition gases; these gaseous inhibitors might be the primary dioxins suppressants.

  9. High temperature power electronics for space (United States)

    Hammoud, Ahmad N.; Baumann, Eric D.; Myers, Ira T.; Overton, Eric


    A high temperature electronics program at NASA Lewis Research Center focuses on dielectric and insulating materials research, development and testing of high temperature power components, and integration of the developed components and devices into a demonstrable 200 C power system, such as inverter. An overview of the program and a description of the in-house high temperature facilities along with experimental data obtained on high temperature materials are presented.

  10. Characterization of fluidization regime in circulating fluidized bed reactor with high solid particle concentration using computational fluid dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Chalermsinsuwan, Benjapon; Thummakul, Theeranan; Piumsomboon, Pornpote [Chulalongkorn University, Bangkok (Thailand); Gidaspow, Dimitri [Armour College of Engineering, Chicago (United States)


    The hydrodynamics inside a high solid particle concentration circulating fluidized bed reactor was investigated using computational fluid dynamics simulation. Compared to a low solid particle reactor, all the conventional fluidization regimes were observed. In addition, two unconventional fluidization regimes, circulating-turbulent and dense suspension bypassing regimes, were found with only primary gas injection. The circulating-turbulent fluidization regime showed uniformly dense solid particle distribution in all the system directions, while the dense suspension bypassing fluidization regime exhibited the flow of solid particles at only one side system wall. Then, comprehensive fluidization regime clarification and mapping were evaluated using in-depth system parameters. In the circulating-turbulent fluidization regime, the total granular temperature was low compared to the adjacent fluidization regimes. In the dense suspension bypassing fluidization regime, the highest total granular temperature was obtained. The circulating-turbulent and dense suspension bypassing fluidization regimes are suitable for sorption and transportation applications, respectively.

  11. High Temperature Chemistry at NASA: Hot Topics (United States)

    Jacobson, Nathan S.


    High Temperature issues in aircraft engines Hot section: Ni and Co based Superalloys Oxidation and Corrosion (Durability) at high temperatures. Thermal protection system (TPS) and RCC (Reinforced Carbon-Carbon) on the Space Shuttle Orbiter. High temperatures in other worlds: Planets close to their stars.

  12. High temperature vapors science and technology

    CERN Document Server

    Hastie, John


    High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temp

  13. Comparison of the Efficiency of Moving- and Fixed-bed Bioreactors for Treatment of High-strength Synthetic Wastewater


    Rezaee, A.; S Jorfi; Cheshmeh Soltani, R. D


    A lab-scale Plexiglas cubic container as a pre-aeration reactor with total volume of 10 L, and two integrated bioreactors including a moving-bed bioreactor (MBBR) and a fixed-bed bioreactor with total volume of 30 L separately were used for experimental study. The main purpose was to compare the performance of moving-bed and fixed-bed reactors for degradation of high organic loading in synthetic wastewater. Varying organic loadings of 0.5 to 9 kg COD m3 d–1 were applied. Generally, the tot...

  14. Metal Hydrides for High-Temperature Power Generation

    Directory of Open Access Journals (Sweden)

    Ewa C. E. Rönnebro


    Full Text Available Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES applications. By using TES with solar technologies, heat can be stored from sun energy to be used later, which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT metal hydride operating reversibly at 600–800 °C to generate heat, as well as a low-temperature (LT hydride near room temperature that is used for hydrogen storage during sun hours until there is the need to produce electricity, such as during night time, a cloudy day or during peak hours. We proceeded from selecting a high-energy density HT-hydride based on performance characterization on gram-sized samples scaled up to kilogram quantities with retained performance. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a ~200-kWh/m3 bench-scale prototype was designed and fabricated, and we demonstrated the ability to meet or exceed all performance targets.

  15. Comparison of low shear, high shear, and fluid bed granulation during low dose tablet process development. (United States)

    Hausman, Debra S


    Three processing methods were compared to develop a low dose (0.1%) immediate release tablet. Similar formulations were used to evaluate low shear, high shear, and fluid bed granulation methods. For each granulation process, the drug was dissolved or suspended in the granulating fluid and sprayed into the granulator. Both water and methanol were evaluated as granulating fluids. The low shear granulation was performed in a Patterson-Kelley V-Blender with I-bar. The high shear granulation was performed in a GRAL (top entry impeller) and a Diosna (bottom mounted impeller). Fluid bed granulation was also performed using top-spray. Acceptable content uniformity was obtained using each technology. The type of granulator and granulating solvent affected the granulation particle size distributions and bulk/tap densities. However, the addition of extragranular microcrystalline cellulose minimized the effect of variable granulation properties and allowed similar tablets to be produced from each granulation process.

  16. High School Students’ Use of Sunscreen and Tanning Beds

    Centers for Disease Control (CDC) Podcasts


    This podcast is an interview with Corey Basch, EdD, MPH, assistant professor in the Department of Public Health at William Paterson University. Dr. Basch discusses her study on high school students’ use of sunscreen and tanning beds between 2001 and 2011.  Created: 8/20/2014 by Preventing Chronic Disease (PCD), National Center for Chronic Disease Prevention and Health Promotion (NCCDPHP).   Date Released: 8/20/2014.

  17. Is inversion based high resolution characterization of spatially heterogeneous river bed hydraulic conductivity needed and possible?

    Directory of Open Access Journals (Sweden)

    W. Kurtz


    Full Text Available River-aquifer exchange fluxes influence local and regional water balances and affect groundwater and river water quality and quantity. Unfortunately, river-aquifer exchange fluxes tend to be strongly spatially variable and it is an open research question to which degree river bed heterogeneity has to be represented in a~model in order to achieve reliable estimates of river-aquifer exchange fluxes. This research question is addressed in this paper with help of synthetic simulation experiments, which mimic the Limmat aquifer in Zurich (Switzerland, where river-aquifer exchange fluxes and groundwater management activities play an important role. The solution of the unsaturated-saturated subsurface hydrological flow problem including river-aquifer interaction is calculated for ten different synthetic realities where the strongly heterogeneous river bed hydraulic conductivities (L are perfectly known. Hydraulic head data (100 in the default scenario are sampled from the synthetic realities. In subsequent data assimilation experiments, where L is unknown now, the hydraulic head data are used as conditioning information, with help of the Ensemble Kalman Filter (EnKF. For each of the ten synthetic realities, four different ensembles of L are tested in the experiments with EnKF; one ensemble estimates high resolution L-fields with different L values for each element, and the other three ensembles estimate effective L values for 5, 3 or 2 zones. The calibration of higher resolution L-fields (i.e., fully heterogeneous or 5 zones gives better results than the calibration of L for only 3 or 2 zones in terms of reproduction of states, stream-aquifer exchange fluxes and parameters. Effective L for a limited number of zones cannot always reproduce the true states and fluxes well and results in biased estimates of net exchange fluxes between aquifer and stream. Also in case only 10 head data are used for conditioning, the high resolution L-fields outperform the

  18. Thermodynamics of High Temperature Plasmas

    Directory of Open Access Journals (Sweden)

    Ettore Minardi


    Full Text Available In this work we discuss how and to what extent the thermodynamic concepts and the thermodynamic formalism can be extended to the description of high temperature states of the plasma not necessarily associated with a Boltzmann distribution and with thermal equilibrium.The discussion is based on the “magnetic or electrostatic entropy concept”, an interpretative and predictive tool based on probability and information, defined in a suitably coarse-grained possibility space of all current density or of all electric charge density distributions under testable constraints, and whose variation properties are proven to be related under certain conditions to the equilibrium and the stability of the system. In the case of magnetic equilibrium the potentiality of the magnetic entropy concept is illustrated by comparing the predictions of the current density and pressure profiles with the observations in different tokamak machines and different tokamak regimes, as well as by showing how the equilibrium and the stability in devices as different as the reversed field pinch or the magnetic well are described by the variation properties of the same entropy functional applied to the different situations. In fact it emerges that the maximum of the entropy can be seen in these different cases as an optimization constraint for the minimum of the magnetic energy. The application of the entropy concept to the electrostatic processes shows in particular that the so-called reactive instabilities (non-dissipative, non-resonant instabilities with a marginal point admit a neighboring state with higher entropy and are therefore of special relevance from the point of view of the physical evolution of the system. In this case the thermodynamic formalism allows the introduction of the concept of “thermodynamic fluctuations” of the macroscopic charge density and provides a method for the calculation of the “thermodynamic” fluctuation levels both on the stable as

  19. Low temperature SO{sub 2} removal with solid sorbents in a circulating fluidized bed absorber. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.K.; Keener, T.C.


    A novel flue gas desulfurization technology has been developed at the University of Cincinnati incorporating a circulating fluidized bed absorber (CFBA) reactor with dry sorbent. The main features of CFBA are high sorbent/gas mixing ratios, excellent heat and mass transfer characteristics, and the ability to recycle partially utilized sorbent. Subsequently, higher SO{sub 2} removal efficiencies with higher overall sorbent utilization can be realized compared with other dry sorbent injection scrubber systems.

  20. High temperature superconducting fault current limiter

    Energy Technology Data Exchange (ETDEWEB)

    Hull, John R. (Hinsdale, IL)


    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  1. Design and Development of a High Efficiency CarbonGranular Bed Filter in Industrial Scale

    Institute of Scientific and Technical Information of China (English)

    张济宇; 旷戈; 林诚


    The new dust removal technical route using the carbon-granular bed filter, packed of carbon particles with appropriate grade derive from an online-process vibration sieve, to replace the traditional baggy filter had been developed successfully for capturing the micro-carbon dusts produced from pulverization of petroleum coke,and the green close loop of carbon materials is thus completed in the combined pulverizing and classifying system and pulverized carbon dust removal process. The high dust removal efficiency greater than 99%, low outlet dust concentration less than 100 mg-m-S, low pressure drop through dust filtration chamber less than 980 Pa, simple and easy design, and flexible and stable operation were achieved also with the carbon-granular bed filter in both bench and industrial scale operations.

  2. In Developping a Bench-Scale Circulating Fluidized Bed Combustor to Burn High Ash Brazilian Coal-Dolomites Mixtures (United States)

    Ramírez Behainne, Jhon Jairo; Hory, Rogério Ishikawa; Goldstein, Leonardo; Bernárdez Pécora, Araí Augusta

    This work considers some of the questions in burning high ash Brazilian coal-dolomite mixtures in a bench-scale circulating fluidized bed combustor (CFBC). Experimental tests were performed with the CE4500 coal from Santa Catarina State, in southern Brazil, with a Sauter mean diameter d p =43 μm. The coal particles were mixed with dolomite particles of d p = 111 μm and this fuel mixture was fed into the circulating fluidized reactor, previously loaded with quartz sand particles of d p =353 μm. This inert material was previously heated by the combustion of liquefied petroleum gas up to the ignition temperature of the fuel mixture. The CFBC unit has a 100mm internal diameter riser, 4.0m high, as well as a 62.8mm internal diameter downcomer. The loop has a cyclone, a sampling valve to collect particles and a 62.8mm internal diameter L-valve to recirculate the particles in the loop. A screw feeder with a rotation control system was used to feed the fuel mixture to the reactor. The operational conditions were monitored by pressure taps and thermocouples installed along the loop. A data acquisition system showed the main operational conditions to control. Experimental tests performed put in evidence the problems found during bed operation, with special attention to the solids feed device, to the L-valve operation, to particle size, solids inventory, fluidized gas velocity, fuel mixture and recirculated solids feeding positions.

  3. Deep Trek High Temperature Electronics Project

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Ohme


    This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

  4. High efficiency pollutant removal with the Moving-Bed Copper Oxide Process

    Energy Technology Data Exchange (ETDEWEB)

    Pennline, H.W.; Hoffman, J.S.; Yeh, J.T. [Dept. of Energy, Pittsburgh, PA (United States). Pittsburgh Energy Technology Center; Resnik, K.P.; Vore, P.A. [Gilbert Commonwealth, Inc., Pittsburgh, PA (United States)


    Dry, regenerable flue gas cleanup techniques that use a sorbent can have various advantages, such as simultaneous removal of pollutants, production of a salable by-product, and low costs when compared to commercially available scrubbing technology. Due to the temperature of reaction, the placement of the process into an advanced power system could actually increase the thermal efficiency of the plant. One such technique, the Moving-Bed Copper Oxide Process, is capable of simultaneously removing sulfur oxides and nitric oxides within the reactor system. A parametric study of the process was conducted on a life-cycle test system. All process steps, including absorption and regeneration, were integrated into this life-cycle test system so that continuous, long-term operation of the total process cold be experimentally evaluated. The effects of absorption temperature, sorbent and gas residence times, and inlet SO{sub 2} and NO{sub x} concentration on removal efficiencies and overall operational performance are discussed.

  5. High Temperature and Pressure Alkaline Electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank

    and oxygen with a new type of alkaline electrolysis cell at high temperatures and pressures. To perform measurements under high pressure and at elevated temperatures it was necessary to build a measurement system around an autoclave which could stand high temperatures up to 250 °C and pressures up to 200 bar...... as well as extremely caustic environments. Based on a literature study to identify resistant materials for these conditions, Inconel 600 was selected among the metals which are available for autoclave construction. An initial single atmosphere high temperature and pressure measurement setup was build...... comprising this autoclave. A second high temperature and pressure measurement setup was build based on experiences from the first setup in order to perform automatized measurements. The conductivity of aqueous KOH at elevated temperatures and high concentrations was investigated using the van der Pauw method...

  6. High-temperature protective coatings on superalloys

    Institute of Scientific and Technical Information of China (English)

    刘培生; 梁开明; 周宏余


    Protective coatings are essential for superalloys to serve as blades of gas turb ines at high temperatures, and they primarily include aluminide coating, MCrAlY overlay coating, thermal barrier coating and microcrystalline coating. In this paper, all these high-temperature coatings are reviewed as well as their preparing techniques. Based on the most application and the main failure way, the importance is then presented for further deepgoing study on the high-temperature oxidation law of aluminide coatings.

  7. High Temperature Heterojunction Bipolar Transistors (United States)


    2700 cmW/V-s at room temperature, a far higher value than ever found for GaN or AlGaN. Thus a GaN/ InGaN HEMT would be analogous to InP/InGaAs HEMTs...Spire’s ECR plasma source modif led as a crystal growth reactor. 8 The substrate for the film deposition is mounted on a sample holder which is...The three samples from the second growth run were also characterized. One sample was found to have a very even frosty white haze on it. The other

  8. A high temperature fuel element

    Energy Technology Data Exchange (ETDEWEB)

    Sekido, A.; Nakai, M.; Ninomiya, Y.


    A solid electrolyte which conducts electricity with heating by oxygen ions and operates at a temperature of 1,000C is used in the element. The cathode, besides the ionic conductivity in oxygen, has an electron conductivity. The anode has electron conductivity. Substances such as Bi203, into which oxides of alkaline earth metals are added, are used for making the cathode. The electrolyte consists of ZrO2 and Y2O3, to which CaO is added. WC, to which an H2 type fuel is fed, serves as the anode. The element has a long service life.

  9. Long-term and high resolution measurements of bed level changes in a temperate, microtidal coastal lagoon

    DEFF Research Database (Denmark)

    Andersen, Thorbjørn J.; Pejrup, Morten; Nielsen, Allan Aasbjerg


    This study presents the results of a long-term monitoring program of bed level changes measured during 8 yr at an intertidal mudflat in a microtidal, temperate coastal lagoon. Additionally, bed level measurements obtained at a 10-min temporal resolution at the same tidal flat and at the bed of a ...... are not seriously threatened by the expected sea level rise in the 21st century.......This study presents the results of a long-term monitoring program of bed level changes measured during 8 yr at an intertidal mudflat in a microtidal, temperate coastal lagoon. Additionally, bed level measurements obtained at a 10-min temporal resolution at the same tidal flat and at the bed...... of a nearby tidal channel are presented. Short-term changes in bed level are one or two orders of magnitude larger than the annual net-deposition rate, which shows that the environment is highly dynamic with respect to erosion, transport and deposition of fine-grained sediment. Some seasonality in the bed...

  10. High temperature phase equilibria and phase diagrams

    CERN Document Server

    Kuo, Chu-Kun; Yan, Dong-Sheng


    High temperature phase equilibria studies play an increasingly important role in materials science and engineering. It is especially significant in the research into the properties of the material and the ways in which they can be improved. This is achieved by observing equilibrium and by examining the phase relationships at high temperature. The study of high temperature phase diagrams of nonmetallic systems began in the early 1900s when silica and mineral systems containing silica were focussed upon. Since then technical ceramics emerged and more emphasis has been placed on high temperature

  11. High Temperature Capacitors for Venus Exploration Project (United States)

    National Aeronautics and Space Administration — In this SBIR program, TRS Technologies has developed several new dielectrics for high temperature applications including signal conditioning, filtering and energy...

  12. Advances in high temperature chemistry 1

    CERN Document Server

    Eyring, Leroy


    Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in

  13. Ultrasonic Sensors for High Temperature Applications (United States)

    Tittmann, Bernhard; Aslan, Mustafa


    Many processes take place under conditions other than ambient, and chief among these is high temperature. Examples of high temperature industrial processes are resin transfer molding, molten metal infiltration and rheocasting of composite metals alloys. The interaction of waves with viscous fluids is an additional complication adding to an already complicated problem of operating a sensor at high temperature for extended periods of time. This report attempts to provide an insight into the current state of the art of sensor techniques for in-situ high temperature monitoring.

  14. Alloys developed for high temperature applications (United States)

    Basuki, Eddy Agus; Prajitno, Djoko Hadi; Muhammad, Fadhli


    Alloys used for high temperatures applications require combinations of mechanical strength, microstructural stability and corrosion/oxidation resistance. Nickel base superalloys have been traditionally the prime materials utilized for hot section components of aircraft turbine engines. Nevertheless, due to their limited melting temperatures, alloys based on intermetallic compounds, such as TiAl base alloys, have emerged as high temperature materials and intensively developed with the main aim to replace nickel based superalloys. For applications in steam power plants operated at lower temperatures, ferritic high temperature alloys still attract high attention, and therefore, development of these alloys is in progress. This paper highlights the important metallurgical parameters of high temperature alloys and describes few efforts in the development of Fe-Ni-Al based alloys containing B2-(Fe,Ni)Al precipitates, oxide dispersion strengthening (ODS) ferritic steels and titanium aluminide based alloys include important protection system of aluminide coatings.

  15. Investigations into High Temperature Components and Packaging

    Energy Technology Data Exchange (ETDEWEB)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.


    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the

  16. High temperature skin friction measurement (United States)

    Tcheng, Ping; Holmes, Harlan K.; Supplee, Frank H., Jr.


    Skin friction measurement in the NASA Langley hypersonic propulsion facility is described. The sensor configuration utilized an existing balance, modified to provide thermal isolation and an increased standoff distance. For test run times of about 20 sec and ambient-air cooling of the test section and balance, the modified balance performed satisfactorily, even when it was subjected to acoustic and structural vibration. The balance is an inertially balanced closed-loop servo system where the current to a moving-coil motor needed to restore or null the output from the position sensor is a measure of the force or skin friction tending to displace the moving element. The accuracy of the sensor is directly affected by the position sensor in the feedback loop, in this case a linear-variable differential transformer which has proven to be influenced by temperature gradients.

  17. High Temperature Calcination - MACT Upgrade Equipment Pilot Plant Test

    Energy Technology Data Exchange (ETDEWEB)

    Richard D. Boardman; B. H. O& #39; Brien; N. R. Soelberg; S. O. Bates; R. A. Wood; C. St. Michel


    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste are stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Calcination at high-temperature conditions (600 C, with alumina nitrate and calcium nitrate chemical addition to the feed) is one of four options currently being considered by the Department of Energy for treatment of the remaining tank wastes. If calcination is selected for future processing of the sodium-bearing waste, it will be necessary to install new off-gas control equipment in the New Waste Calcining Facility (NWCF) to comply with the Maximum Achievable Control Technology (MACT) standards for hazardous waste combustors and incinerators. This will require, as a minimum, installing a carbon bed to reduce mercury emissions from their current level of up to 7,500 to <45 {micro}g/dscm, and a staged combustor to reduce unburned kerosene fuel in the off-gas discharge to <100 ppm CO and <10 ppm hydrocarbons. The staged combustor will also reduce NOx concentrations of about 35,000 ppm by 90-95%. A pilot-plant calcination test was completed in a newly constructed 15-cm diameter calciner vessel. The pilot-plant facility was equipped with a prototype MACT off-gas control system, including a highly efficient cyclone separator and off-gas quench/venturi scrubber for particulate removal, a staged combustor for unburned hydrocarbon and NOx destruction, and a packed activated carbon bed for mercury removal and residual chloride capture. Pilot-plant testing was performed during a 50-hour system operability test January 14-16, followed by a 100-hour high-temperature calcination pilot-plant calcination run January 19-23. Two flowsheet blends were tested: a 50-hour test with an aluminum-to-alkali metal molar ratio (AAR) of 2.25, and a 50-hour test with an AAR of 1.75. Results of the testing

  18. Corrosion Resistant Coatings for High Temperature Applications

    Energy Technology Data Exchange (ETDEWEB)

    Besman, T.M.; Cooley, K.M.; Haynes, J.A.; Lee, W.Y.; Vaubert, V.M.


    Efforts to increase efficiency of energy conversion devices have required their operation at ever higher temperatures. This will force the substitution of higher-temperature structural ceramics for lower temperature materials, largely metals. Yet, many of these ceramics will require protection from high temperature corrosion caused by combustion gases, atmospheric contaminants, or the operating medium. This paper discusses examples of the initial development of such coatings and materials for potential application in combustion, aluminum smelting, and other harsh environments.

  19. High-Temperature Passive Power Electronics (United States)


    In many future NASA missions - such as deep-space exploration, the National AeroSpace Plane, minisatellites, integrated engine electronics, and ion or arcjet thrusters - high-power electrical components and systems must operate reliably and efficiently in high-temperature environments. The high-temperature power electronics program at the NASA Lewis Research Center focuses on dielectric and insulating material research, the development and characterization of high-temperature components, and the integration of the developed components into a demonstrable 200 C power system - such as an inverter. NASA Lewis has developed high-temperature power components through collaborative efforts with the Air Force Wright Laboratory, Northrop Grumman, and the University of Wisconsin. Ceramic and film capacitors, molypermalloy powder inductors, and a coaxially wound transformer were designed, developed, and evaluated for high-temperature operation.

  20. Sludge Bed Granules’ Growth in the HUASB Reactor Treating High Strength Industrial Wastewater

    Directory of Open Access Journals (Sweden)

    Sinan Abood Habeeb


    Full Text Available The development of anaerobic sludge granules in a hybrid up-flow anaerobic sludge bed (HUASB reactor in terms of granular size and solids content was observed. After appropriate pre-treatment of the palm oil mill effluent (POME, it was continuously fed to the HUASB reactor under room temperature condition (27°C.  Particle size analysis and solids content examination were conducted for 196 days. A volatile solid ratio was ranging from 0.36 to 0.51 which was quite low, and granules particle size of less than 1 mm diameter was reported during the operating period. Results obtained in this study indicated that sludge bed development based on the sludge particle size distribution and the volatile solid ratio, was quite slow due to the bulk solids that entering the reactor resulting in certain inhibition of the anaerobes’ activity. It has been concluded that anaerobic wastewater treatment process in anaerobic reactors such as the HUASB reactor, can be significantly affected by the organic loading rate, hydraulic retention time applied to the reactor and the wastewater characteristics.

  1. High Temperature Rechargeable Battery Development Project (United States)

    National Aeronautics and Space Administration — This small business innovation research is intended to develop and proof the concept of a highly efficient, high temperature rechargeable battery for supporting...

  2. High Temperature Solid State Lithium Battery Project (United States)

    National Aeronautics and Space Administration — Reliable energy systems with high energy density capable of operating at high temperatures, pressures and radiation levels are needed for certain NASA missions....

  3. Lightweight, High-Temperature Radiator Panels Project (United States)

    National Aeronautics and Space Administration — Lightweight, high-temperature radiators are needed for future, high-efficiency power conversion systems for Nuclear Electric Propulsion (NEP). Creare has developed...

  4. A Road Towards High Temperature Superconductors (United States)


    AFRL-AFOSR-UK-TR-2013-0040 A Road Towards High Temperature Superconductors Guy Deutscher Tel Aviv University Research... Superconductors 5a. CONTRACT NUMBER FA8655-10-1-3011 5b. GRANT NUMBER Grant 10-3011 5c. PROGRAM ELEMENT NUMBER 61102F 6. AUTHOR(S...issue in trying to make useful high temperature superconductors is obviously to discover superconductivity at higher temperatures. But there is also

  5. Ceramic fibres for high temperature insulation

    Energy Technology Data Exchange (ETDEWEB)

    Padgett, G.C.


    Traditionally, refractory linings for high temperature plant and furnaces have comprised either brick or some form of concrete. In recent years, energy conservation has encouraged the greater use of high temperature insulation which is also available in either brick or a lightweight concrete. As an alternative, insulation can also be achieved using fibrous products or fibres combining low heat transfer with low heat capacity.

  6. Ecological observations of major Salicornia beds from highly saline coastal wetlands of India

    Digital Repository Service at National Institute of Oceanography (India)

    Jagtap, T.G.; Bhosale, S.H.; Nagle, V.L.

    Extensive Salicornia beds along the Gulf of Kutchchh (northwest) and Tamilnadu (southeast) coasts were investigated with respect to vegetative structure and ambient environmental conditions. The width of the beds varied from approximately 5 m...

  7. Removal of phenol by activated alumina bed in pulsed high-voltage electric field

    Institute of Scientific and Technical Information of China (English)

    ZHU Li-nan; MA Jun; YANG Shi-dong


    A new process for removing the pollutants in aqueous solution-activated alumina bed in pulsed high-voltage electric field was investigated for the removal of phenol under different conditions. The experimental results indicated the increase in removal rate with increasing applied voltage, increasing pH value of the solution, aeration, and adding Fe2+. The removal rate of phenol could reach 72.1 % when air aeration flow rate was 1200 ml/min, and 88.2 % when 0.05 mmol/L Fe2+ was added into the solution under the conditions of applied voltage 25 kV, initial phenol concentration of 5 mg/L, and initial pH value 5.5. The addition of sodium carbonate reduced the phenol removal rate. In the pulsed high-voltage electric field, local discharge occurred at the surface of activated alumina, which promoted phenol degradation in the thin water film. At the same time, the space-time distribution of gas-liquid phases was more uniform and the contact areas of the activated species generated from the discharge and the pollutant molecules were much wider due to the effect of the activated alumina bed. The synthetical effects of the pulsed high-voltage electric field and the activated alumina particles accelerated phenol degradation.

  8. Implementation of an artificial neural network as a PAT tool for the prediction of temperature distribution within a pharmaceutical fluidized bed granulator. (United States)

    Korteby, Yasmine; Mahdi, Yassine; Azizou, Amel; Daoud, Kamel; Regdon, Géza


    In this study, a novel in-line measurement technique of the air temperature distribution during a granulation process using a conical fluidized bed was designed and built for the purpose of measuring the temperature under the Process Analytical Technology (PAT) and introduced to predict the establishment of temperature profiles. Three sets of thermocouples were used, placed at different positions covering the whole operating range, connected to data acquisition measurement hardware, allowing an in-line acquisition and recording of temperatures every second. The measurements throughout the fluidized bed were performed in a steady state by spraying a solution of PVP onto a lactose monohydrate powder bed in order to make predictions of the temperature distribution and the hydrodynamics of the bed during the granulation process using Artificial Neural Networks (ANNs) and to establish the different temperature profiles for different process conditions through the precise predicted information by the constructed, trained, validated and tested neural network. The model's testing results showed a strong prediction capacity of the effects of process variables. Indeed, the predicted temperature values obtained with the ANN model were in good agreement with the values measured with in-line reference method and hence the method can have an application as a predictive control tool.

  9. A high temperature granulation process for ecological ash recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Sundqvist, Thomas


    This thesis is a summary of three papers dealing with new technologies for facilitating ecological biomass ash recirculation back to forest and farm lands. The present outtake of biomass for paper and energy production may be incompatible with a sustainable forestry. The cycle of nutrients contained in the biomass extracted must be closed by ash recirculation in an environmental compatible way. This implies stabilization of the loose ashes/rest-products to a product with low heavy metal contents, controlled leaching properties and a high spreadability. In the present work, two different techniques were evaluated for the possibilities to separate heavy metals from the nutrient elements by utilizing high process temperatures to vaporize the unwanted metals from the condensed bulk materials. The results indicated that direct in-situ separation in fluidized bed combustion systems is possible, but requires too high process temperatures to be practically attractive. On the other hand, the new proposed high temperature treatment method for granulated raw materials was found to significantly separate As, Cd and Pb, with separation efficiencies exceeding 90 % at optimal operating conditions. In addition, the results indicated that the treatment method could be used to significantly delay and control the leaching characteristics, as well as the content of products of incomplete combustion of the produced granules.

  10. Application of High Temperature Superconductors to Accelerators

    CERN Document Server

    Ballarino, A


    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  11. Soil application of ash produced by low-temperature fluidized bed gasification: effects on soil nutrient dynamics and crop response

    DEFF Research Database (Denmark)

    Müller-Stöver, Dorette Sophie; Ahrenfeldt, Jesper; Holm, Jens Kai


    Recycling of residual products of bioenergy conversion processes is important for adding value to the technologies and as a potential beneficial soil fertility amendment. In this study, two different ash materials originating from low temperature circulating fluidized bed (LT-CFB) gasification...... of either wheat straw (SA) or residue fibers mainly from citrus peels (CP) were tested regarding their potential to be used as fertilizer on agricultural soils. A soil incubation study, a greenhouse experiment with barley and faba bean, and an accompanying outdoor experiment with maize were carried out...... to investigate the effects of the ashes on soil microbiological and chemical properties and on the response of the three crops. The ash treatments were compared with a control treatment that received only nitrogen, magnesium, and sulphur (CO) and a fully fertilized control (COPK). Soil microbial parameters were...

  12. Reduction of Precursors of Chlorination By-products in Drinking Water Using Fluidized-bed Biofilm Reactor at Low Temperature

    Institute of Scientific and Technical Information of China (English)



    Objective To investigate the reduction of chlorination by-products (CBPs) precursors using the fluidized-bed biofilm reactor (FBBR). Methods Reduction of total organic carbon (TOC), ultraviolet absorbance (UV254), trihalomethane (THM)formation potential (THMFP), haloacetic acid (HAA) formation potential (HAAFP), and ammonia in FBBR were evaluated in detail. Results The reduction of TOC or UV254 was low, on average 12.6% and 4.7%, respectively, while the reduction of THMFP and HAAFP was significant. The reduction of ammonia was 30%-40% even below 3℃, however, it could quickly rise to over 50% above 3℃. Conclusions The FBBR effectively reduces CBPs and ammonia in drinking water even at low temperature and seems to be a very promising and competitive drinking water reactor for polluted surface source waters, especially in China.


    Institute of Scientific and Technical Information of China (English)


    To meet the demands of processing residue with high sulfur content, Fushun Research Institute of Petroleum and Petrochemicals (FRIPP) successfully developed the fixed-bed residue hydrotreating technology (S-RHT), which is suitable for treating high sulfur residue to produce diesel oil with low sulfur content. the hydrotreated 350 ℃+ residue is also a good feedstock for RFCC. Based on this technology, Maoming Petrochemical Company constructed the hydrotreating unit with a capacity of 2 Mt/a to treat high sulfur residue, in which loaded FZC series catalysts were developed by FRIPP. The unit was first put into commercial operation at the end of 1999. The commercial operation showed that the catalysts have good activities and the products meet the designed specifications.

  14. High-Resolution Adaptive Optics Test-Bed for Vision Science

    Energy Technology Data Exchange (ETDEWEB)

    Wilks, S C; Thomspon, C A; Olivier, S S; Bauman, B J; Barnes, T; Werner, J S


    We discuss the design and implementation of a low-cost, high-resolution adaptive optics test-bed for vision research. It is well known that high-order aberrations in the human eye reduce optical resolution and limit visual acuity. However, the effects of aberration-free eyesight on vision are only now beginning to be studied using adaptive optics to sense and correct the aberrations in the eye. We are developing a high-resolution adaptive optics system for this purpose using a Hamamatsu Parallel Aligned Nematic Liquid Crystal Spatial Light Modulator. Phase-wrapping is used to extend the effective stroke of the device, and the wavefront sensing and wavefront correction are done at different wavelengths. Issues associated with these techniques will be discussed.

  15. Sandia_HighTemperatureComponentEvaluation_2015

    Energy Technology Data Exchange (ETDEWEB)

    Cashion, Avery T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    The objective of this project is to perform independent evaluation of high temperature components to determine their suitability for use in high temperature geothermal tools. Development of high temperature components has been increasing rapidly due to demand from the high temperature oil and gas exploration and aerospace industries. Many of these new components are at the late prototype or first production stage of development and could benefit from third party evaluation of functionality and lifetime at elevated temperatures. In addition to independent testing of new components, this project recognizes that there is a paucity of commercial-off-the-shelf COTS components rated for geothermal temperatures. As such, high-temperature circuit designers often must dedicate considerable time and resources to determine if a component exists that they may be able to knead performance out of to meet their requirements. This project aids tool developers by characterization of select COTS component performances beyond published temperature specifications. The process for selecting components includes public announcements of project intent (e.g., FedBizOps), direct discussions with candidate manufacturers,and coordination with other DOE funded programs.

  16. Thermoelastic properties of minerals at high temperature

    Indian Academy of Sciences (India)

    Sanjay Upadhyay; Hem Chandra; Meenakashi Joshi; Deepika P Joshi


    The knowledge of elasticity of the minerals is useful for interpreting the structure and composition of the lower mantle and also in seismic studies. The purpose of the present study is to discuss a simple and straightforward method for evaluating thermoelastic properties of minerals at high temperatures. We have extended the Kumar’s formulation by taking into the account the concept of anharmonicity in minerals above the Debye temperature (D). In our present study, we have investigated the thermophysical properties of two minerals (pyrope-rich garnet and MgAl2O4) under high temperatures and calculated the second-order elastic constant () and bulk modulus (T) of the above minerals, in two cases first by taking Anderson–Gruneisen parameter (T) as temperature-independent and then by treating T as temperature-dependent parameter. The results obtained when T is temperature-dependent are in close agreement with experimental data.

  17. Runaway Criterion in Fixed Bed Catalytic Reactors with Radial Temperature Profile

    Institute of Scientific and Technical Information of China (English)

    吴鹏; 樊勇; 李绍芬


    The discrepancy between pseudo-homogeneous one-dimensional model and peeudo-homogeneous two-dimensional model is studied. It is found that there are great differences between two models. This paper compares the maximum and minimum values of the radial temperature in the hot spot in came that a single exothermic reaction is carried out, a correlation is obtlioed with peeudo-homogeneous one-dimensional model to describe the entire reactor behavier. A new runaway criterion, based on the occurrence of inflection in the hot spot locus, is developed for the case of pseudo-homogeneous two-dimensional model. This criterion predicts the maximum allowable temperature for safe operation and the regions of runaway, respectively. The calculated results show that, compared with the results based on pseudo-homogeneous one-dimensional model, runaway will easily occur when the radial temperature gradient has to be considered.

  18. Low to high temperature energy conversion system (United States)

    Miller, C. G. (Inventor)


    A method for converting heat energy from low temperature heat sources to higher temperature was developed. It consists of a decomposition chamber in which ammonia is decomposed into hydrogen and nitrogen by absorbing heat of decomposition from a low temperature energy source. A recombination reaction then takes place which increases the temperature of a fluid significantly. The system is of use for the efficient operation of compact or low capital investment turbine driven electrical generators, or in other applications, to enable chemical reactions that have a critical lower temperature to be used. The system also recovers heat energy from low temperature heat sources, such as solar collectors or geothermal sources, and converts it to high temperatures.

  19. Silicon Carbide Nanotube Oxidation at High Temperatures (United States)

    Ahlborg, Nadia; Zhu, Dongming


    Silicon Carbide Nanotubes (SiCNTs) have high mechanical strength and also have many potential functional applications. In this study, SiCNTs were investigated for use in strengthening high temperature silicate and oxide materials for high performance ceramic nanocomposites and environmental barrier coating bond coats. The high · temperature oxidation behavior of the nanotubes was of particular interest. The SiCNTs were synthesized by a direct reactive conversion process of multiwall carbon nanotubes and silicon at high temperature. Thermogravimetric analysis (TGA) was used to study the oxidation kinetics of SiCNTs at temperatures ranging from 800degC to1300degC. The specific oxidation mechanisms were also investigated.

  20. Symposium on high temperature and materials chemistry

    Energy Technology Data Exchange (ETDEWEB)


    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  1. Dimensionality of high temperature superconductivity in oxides (United States)

    Chu, C. W.


    Many models have been proposed to account for the high temperature superconductivity observed in oxide systems. Almost all of these models proposed are based on the uncoupled low dimensional carrier Cu-O layers of the oxides. Results of several experiments are presented and discussed. They suggest that the high temperature superconductivity observed cannot be strictly two- or one-dimensional, and that the environment between the Cu-O layers and the interlayer coupling play an important role in the occurrence of such high temperature superconductivity. A comment on the very short coherence length reported is also made.

  2. Aeronautical applications of high-temperature superconductors (United States)

    Turney, George E.; Luidens, Roger W.; Uherka, Kenneth; Hull, John


    The successful development of high-temperature superconductors (HTS) could have a major impact on future aeronautical propulsion and aeronautical flight vehicle systems. A preliminary examination of the potential application of HTS for aeronautics indicates that significant benefits may be realized through the development and implementation of these newly discovered materials. Applications of high-temperature superconductors (currently substantiated at 95 K) were envisioned for several classes of aeronautical systems, including subsonic and supersonic transports, hypersonic aircraft, V/STOL aircraft, rotorcraft, and solar, microwave and laser powered aircraft. Introduced and described are the particular applications and potential benefits of high-temperature superconductors as related to aeronautics and/or aeronautical systems.

  3. Aeronautical applications of high-temperature superconductors (United States)

    Turney, George E.; Luidens, Roger W.; Uherka, Kenneth; Hull, John


    The successful development of high-temperature superconductors (HTS) could have a major impact on future aeronautical propulsion and aeronautical flight vehicle systems. A preliminary examination of the potential application of HTS for aeronautics indicates that significant benefits may be realized through the development and implementation of these newly discovered materials. Applications of high-temperature superconductors (currently substantiated at 95 k) were envisioned for several classes of aeronautical systems, including subsonic and supersonic transports, hypersonic aircraft, V/STOL aircraft, rotorcraft, and solar, microwave and laser powered aircraft. Introduced and described are the particular applications and potential benefits of high-temperature superconductors as related to aeronautics and/or aeronautical systems.

  4. A high temperature seeding technique for particle image velocimetry (United States)

    Wernet, Mark P.; Hadley, Judith A.


    Non-intrusive measurements of gas velocities via particle image velocimetry (PIV) or laser Doppler velocimetry (LDV) requires entraining particles into the flow field. There are many techniques and materials available for seeding gas phase flows. However, when the flow temperatures exceed 200 °C, the available options for seed materials becomes limited. In high temperature applications refractory seed materials are required. The established technique for seeding flows with metal oxide powders is via fluidized beds by themselves or in combination with cyclone separators. These systems are fraught with problems which limit their ability to provide consistent, uniform flow seeding. In this work, we describe a technique for reliably introducing metal oxide particles into high temperature flows. The employment of pH stabilization techniques typically used to obtain stable dispersions in ceramic processing can provide a source of seed material for high temperature air flows. By pH stabilizing submicron alumina particles in ethanol, a stable dispersion is obtained which when atomized, produces a high quality aerosol. Commercial grade alumina is used with a moderate size distribution. The technique is not limited to alumina/ethanol and is also demonstrated with an alumina/H2O system. Other ceramic powders in other polar solvents can also be used once their point of zero charge (pHpzc) of the powder in the solvent has been determined. We present an example of the pH stabilized dispersions applied to a very challenging high temperature supersonic flow and a particle dynamics analysis across a shock.

  5. Development of high temperature capable piezoelectric sensors (United States)

    Suprock, Andrew D.; Tittmann, Bernhard R.


    The objective of the project was to investigate the influence of the temperature effect on ultrasonic transducers based on a comparison of the effects of high temperature conditions versus those of high temperature and irradiation on the transducer system. There was also a preliminary move towards the establishment of the means for optimizing the bulk single crystal transducer fabrication process in order to achieve peak efficiency and maximum effectiveness in both irradiated and non-irradiated high temperature applications. Optimization of the material components within the transducer will greatly increase non-destructive testing abilities for industry, structural health monitoring. Here is presented a progress report on the testing of several different piezoelectric materials under high temperature conditions. The viability of aluminum nitride (AlN) as a transducer material in high temperature conditions has been previously explored [1] and has been further tested to ensure reliability. Bistmuth Titanate (BiT) has also been tested and has displayed excellent effectiveness for high temperature application.

  6. Broadband, High-Temperature Ultrasonic Transducer (United States)

    Parker, F. Raymond; Winfree, William P.; Barrows, Danny A.


    Materials chosen for endurance at high temperatures and acoustic coupling and damping. Acoustic transducer designed to exhibit broad frequency response and to survive temperatures close to melting points of brazing alloys. Attached directly and continuously to hot object monitored ultrasonically: for example, it can be attached to relatively cool spot on workpiece during brazing for taking ultrasonic quality-control measurements.

  7. H{sub 2}S removal from coal gas at elevated temperature and pressure in fluidized bed with zinc titanate sorbents. 2. Sorbent durability

    Energy Technology Data Exchange (ETDEWEB)

    Mojtahedi, W.; Abbasian, J. [Enviropower Inc., Espoo (Finland)


    High-temperature high-pressure sulfur removal is considered as one of the key steps of the hot gas cleanup train of an IGCC process. Coal-derived gasifier gas contains sulfur gases (mainly H{sub 2}S) which are converted to SO{sub 2} when the gas is combusted in the gas turbine. Cyclic sulfidation/regeneration tests were carried out in a pressurized fluidized bed reactor to remove H{sub 2}S from a simulated coal gas to below 100 ppmv, using regenerable zinc titanate sorbents. The results, which were reported in part 1 of this paper, showed that the sorbent reactivity deteriorates in the cyclic process. In part 2, physical, chemical, and structural changes which the sorbents undergo in the cyclic tests are reported and discussed. The results of analyses conducted with fresh and used sorbents indicate that the loss of reactivity and sorbent deterioration is probably due to zinc migration to the surface of the sorbent particle during the high-temperature high-pressure cyclic process. 13 refs., 11 figs., 2 tabs.

  8. Growth kinetics of calcium fluoride at high supersaturation in a fluidized bed reactor. (United States)

    Jiang, K; Zhou, K G; Yang, Y C; Du, H


    Crystallization process in a fluidized bed reactor (FBR) has been regarded as an environmentally friendly technology for the removal and recovery of fluoride from industrial wastewater. The growth kinetics of calcium fluoride at high supersaturation was studied for design, control, and operation of an FBR. The main variables, including supersaturation, superficial velocity, pH value, and particle size of seed that influenced the crystal growth were investigated. Then, a growth model was used to predict the linear growth rate of calcium fluoride at a high influent concentration of fluoride. The pressure difference in the FBR was used as a feature to characterize the growth rate of calcium fluoride. The aggregation and adsorption between seeds and fine particles were proven to be a possible mechanism for growth of calcium fluoride.

  9. Measuring Moduli Of Elasticity At High Temperatures (United States)

    Wolfenden, Alan


    Shorter, squatter specimens and higher frequencies used in ultrasonic measurement technique. Improved version of piezo-electric ultrasonic composite oscillator technique used to measure moduli of elasticity of solid materials at high temperatures.

  10. Panel report on high temperature ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Nolet, T C [ed.


    Fundamental research is reported concerning high temperature ceramics for application in turbines, engines, batteries, gasifiers, MHD, fuel cells, heat exchangers, and hot wall combustors. Ceramics microstructure and behavior are included. (FS)

  11. High Temperature Self-Healing Metallic Composite (United States)

    Kutelia, E. R.; Bakhtiyarov, S. I.; Tsurtsumia, O. O.; Bakhtiyarov, A. S.; Eristavi, B.


    This work presents the possibility to realize the self healing mechanisms for heterogeneous architectural metal/ceramic high temperature sandwich thermal barrier coating systems on the surfaces refractory metals by analogy of wound healing in the skin.

  12. High Temperature Capacitors for Venus Exploration Project (United States)

    National Aeronautics and Space Administration — High temperature power electronics have become a vital aspect of future designs for power converters in spacecraft, battle zone electric power, satellite power...

  13. High Temperature Fiberoptic Thermal Imaging System Project (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  14. Silicon carbide, an emerging high temperature semiconductor (United States)

    Matus, Lawrence G.; Powell, J. Anthony


    In recent years, the aerospace propulsion and space power communities have expressed a growing need for electronic devices that are capable of sustained high temperature operation. Applications for high temperature electronic devices include development instrumentation within engines, engine control, and condition monitoring systems, and power conditioning and control systems for space platforms and satellites. Other earth-based applications include deep-well drilling instrumentation, nuclear reactor instrumentation and control, and automotive sensors. To meet the needs of these applications, the High Temperature Electronics Program at the Lewis Research Center is developing silicon carbide (SiC) as a high temperature semiconductor material. Research is focussed on developing the crystal growth, characterization, and device fabrication technologies necessary to produce a family of silicon carbide electronic devices and integrated sensors. The progress made in developing silicon carbide is presented, and the challenges that lie ahead are discussed.

  15. Application Fields of High-Temperature Superconductors


    Hott, Roland


    Potential application fields for cuprate high-temperature superconductors (HTS) and the status of respective projects are reviewed. The availability of a reliable and inexpensive cooling technique will be essential for a future broad acceptance of HTS applications.

  16. Novel High Temperature Strain Gauge Project (United States)

    National Aeronautics and Space Administration — Advanced high-temperature sensor technology and bonding methods are of great interests in designing and developing advanced future aircraft. Current state-of-the-art...

  17. PLA recycling by hydrolysis at high temperature (United States)

    Cristina, Annesini Maria; Rosaria, Augelletti; Sara, Frattari; Fausto, Gironi


    In this work the process of PLA hydrolysis at high temperature was studied, in order to evaluate the possibility of chemical recycling of this polymer bio-based. In particular, the possibility to obtain the monomer of lactic acid from PLA degradation was investigated. The results of some preliminary tests, performed in a laboratory batch reactor at high temperature, are presented: the experimental results show that the complete degradation of PLA can be obtained in relatively low reaction times.

  18. Samarium Ion Exchanged Montmorillonite for High Temperature Cumene Cracking Reaction (United States)

    Binitha, N. N.; Silija, P. P.; Suraj, V.; Yaakob, Z.; Sugunan, S.


    Montmorillonite clay is cation exchanged with samarium and its catalytic influence in cumene cracking reaction is investigated. Effect of exchange with sodium ions on further exchange with samarium ions is also noted. Acidity measurements are done using Temperature Programmed Desorption (TPD) of ammonia. The retention of basic structure is proved from FTIR spectra and XRD patterns. Elemental analysis result shows that samarium exchange has occurred, which is responsible for the higher catalytic activity. Surface area and pore volume remains more or less unaffected upon exchange. Thermogravimetric analysis indicates the enhanced thermal stability on exchanging. Cumene cracking reaction is carried out at atmospheric pressure in a fixed bed glass reactor at 673 K. The predominance of Brønsted acidity is confirmed from high selectivity to benzene.

  19. Samarium Ion Exchanged Montmorillonite for High Temperature Cumene Cracking Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Binitha, N N; Silija, P P; Yaakob, Z [Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, National University of Malaysia, 43600 UKM Bangi, Selangor (Malaysia); School of Materials Engineering, Universiti Malaysia Perlis, Taman Muhibah, 02600, Jejawi, Perlis (Malaysia); Suraj, V [Department of Applied Chemistry, CUSAT, Cochin 22, Kerala (India); Sugunan, S, E-mail: [National Institute of Technology, Calicut, Kerala (India)


    Montmorillonite clay is cation exchanged with samarium and its catalytic influence in cumene cracking reaction is investigated. Effect of exchange with sodium ions on further exchange with samarium ions is also noted. Acidity measurements are done using Temperature Programmed Desorption (TPD) of ammonia. The retention of basic structure is proved from FTIR spectra and XRD patterns. Elemental analysis result shows that samarium exchange has occurred, which is responsible for the higher catalytic activity. Surface area and pore volume remains more or less unaffected upon exchange. Thermogravimetric analysis indicates the enhanced thermal stability on exchanging. Cumene cracking reaction is carried out at atmospheric pressure in a fixed bed glass reactor at 673 K. The predominance of Broensted acidity is confirmed from high selectivity to benzene.

  20. High-temperature reactor developments in the Netherlands

    Energy Technology Data Exchange (ETDEWEB)

    Schram, R.P.C.; Cordfunke, E.H.P.; Heek, A.I. van


    The high-temperature reactor development in the Netherland is embedded in the WHITE reactor program, in which several Dutch research institutes and engineering companies participate. The activities within the WHITE program are focused on the development of a small scale HTS for combined heat and power generation. In 1995, design choices for a pebble bed reactor were made at ECN. The first concept HTR will gave a closed cycle helium turbine and a power level of 40 MWth. It is intended to make the market introduction of a commercially competitive HTR feasible. The design will be an optimization of the Peu-a-Peu (PAP) concept of KFA Juelich. Computer codes necessary for the evaluation of reactor physics aspects of this reactor are developed in cooperation with international partners. An evaluation of a 20 MWth PAP concept showed that the maximum fuel termmperature after depressurization does not exceed 1300 C. (orig.).

  1. Relativistic QED Plasma at Extremely High Temperature

    CERN Document Server

    Masood, Samina S


    Renormalization scheme of QED (Quantum Electrodynamics) at high temperatures is used to calculate the effective parameters of relativistic plasma in the early universe. Renormalization constants of QED play role of effective parameters of the theory and can be used to determine the collective behavior of the medium. We explicitly show that the dielectric constant, magnetic reluctivity, Debye length and the plasma frequency depend on temperature in the early universe. Propagation speed, refractive index, plasma frequency and Debye shielding length of a QED plasma are computed at extremely high temperatures in the early universe. We also found the favorable conditions for the relativistic plasma from this calculations.

  2. Melt processed high-temperature superconductors

    CERN Document Server


    The achievement of large critical currents is critical to the applications of high-temperature superconductors. Recent developments have shown that melt processing is suitable for producing high J c oxide superconductors. Using magnetic forces between such high J c oxide superconductors and magnets, a person could be levitated.This book has grown largely out of research works on melt processing of high-temperature superconductors conducted at ISTEC Superconductivity Research Laboratory. The chapters build on melt processing, microstructural characterization, fundamentals of flux pinning, criti

  3. Reduction of lateritic iron ore briquette using coal bed reductant by isothermal - temperature gradient method (United States)

    Zulhan, Zulfiadi; Himawan, David Mangatur; Dimyati, Arbi


    In this study, isothermal-temperature gradient method was used to separate iron and alumina in lateritic iron ore as an alternative technique. The lateritic iron ore was ground to obtain grain size of less than 200 mesh and agglomerated in the form of cylindrical briquette using a press machine. The iron oxide in the briquette was reduced by addition of coal so that all surface of the briquette was covered by the coal. The temperature profile for the reduction process of the briquette was divided into three stages: the first stage was isothermal at 1000°C, the second stage was temperature gradient at varies heating rate of 5, 6.67 and 8.33°C/minutes from 1000 to 1400°C, and the final stage was isothermal at 1400°C. The effect of dehydroxylation of lateritic iron ore was studied as well. Aluminum distribution inside and outside the briquette was analyzed by scanning electron microscope with energy dispersive spectroscopy (SEM-EDS). The analysis results showed that the aluminum content increased from 8.01% at the outside of the briquette to 13.12% in the inside of the briquette. On contrary, iron content is higher at the outside of the briquette compared to that in the inside. These phenomena indicated that aluminum tends to migrate into the center of the briquette while iron moves outward to the surface of briquette. Furthermore, iron metallization of 91.03% could be achieved in the case of without dehydroxylation treatment. With the dehydroxylation treatment, iron metallization degree was increased up to 95.27%.

  4. High Temperature, Wireless Seismometer Sensor for Venus (United States)

    Ponchak, George E.; Scardelletti, Maximilian C.; Taylor, Brandt; Beard, Steve; Meredith, Roger D.; Beheim, Glenn M.; Hunter Gary W.; Kiefer, Walter S.


    Space agency mission plans state the need to measure the seismic activity on Venus. Because of the high temperature on Venus (462? C average surface temperature) and the difficulty in placing and wiring multiple sensors using robots, a high temperature, wireless sensor using a wide bandgap semiconductor is an attractive option. This paper presents the description and proof of concept measurements of a high temperature, wireless seismometer sensor for Venus. A variation in inductance of a coil caused by the movement of an aluminum probe held in the coil and attached to a balanced leaf-spring seismometer causes a variation of 700 Hz in the transmitted signal from the oscillator/sensor system at 426? C. This result indicates that the concept may be used on Venus.

  5. High-temperature granulites and supercontinents

    Institute of Scientific and Technical Information of China (English)

    J.L.R. Touret; M. Santosh; J.M. Huizenga


    The formation of continents involves a combination of magmatic and metamorphic processes. These processes become indistinguishable at the crust-mantle interface, where the pressure-temperature (P-T) conditions of (ultra) high-temperature granulites and magmatic rocks are similar. Continents grow laterally, by magmatic activity above oceanic subduction zones (high-pressure metamorphic setting), and vertically by accumulation of mantle-derived magmas at the base of the crust (high-temperature metamorphic setting). Both events are separated from each other in time; the vertical accretion post-dating lateral growth by several tens of millions of years. Fluid inclusion data indicate that during the high-temperature metamorphic episode the granulite lower crust is invaded by large amounts of low H2O-activity fluids including high-density CO2 and concentrated saline solutions (brines). These fluids are expelled from the lower crust to higher crustal levels at the end of the high-grade metamorphic event. The final amalgamation of supercontinents corresponds to episodes of ultra-high temperature metamorphism involving large-scale accumulation of these low-water activity fluids in the lower crust. This accumulation causes tectonic instability, which together with the heat input from the sub-continental lithospheric mantle, leads to the disruption of supercontinents. Thus, the fragmentation of a supercontinent is already programmed at the time of its amalgamation.

  6. High-temperature granulites and supercontinents

    Directory of Open Access Journals (Sweden)

    J.L.R. Touret


    Full Text Available The formation of continents involves a combination of magmatic and metamorphic processes. These processes become indistinguishable at the crust-mantle interface, where the pressure-temperature (P-T conditions of (ultra high-temperature granulites and magmatic rocks are similar. Continents grow laterally, by magmatic activity above oceanic subduction zones (high-pressure metamorphic setting, and vertically by accumulation of mantle-derived magmas at the base of the crust (high-temperature metamorphic setting. Both events are separated from each other in time; the vertical accretion postdating lateral growth by several tens of millions of years. Fluid inclusion data indicate that during the high-temperature metamorphic episode the granulite lower crust is invaded by large amounts of low H2O-activity fluids including high-density CO2 and concentrated saline solutions (brines. These fluids are expelled from the lower crust to higher crustal levels at the end of the high-grade metamorphic event. The final amalgamation of supercontinents corresponds to episodes of ultra-high temperature metamorphism involving large-scale accumulation of these low-water activity fluids in the lower crust. This accumulation causes tectonic instability, which together with the heat input from the sub-continental lithospheric mantle, leads to the disruption of supercontinents. Thus, the fragmentation of a supercontinent is already programmed at the time of its amalgamation.

  7. Structure and composition of biofilm communities in a moving bed biofilm reactor for nitritation-anammox at low temperatures. (United States)

    Persson, Frank; Sultana, Razia; Suarez, Marco; Hermansson, Malte; Plaza, Elzbieta; Wilén, Britt-Marie


    It is a challenge to apply anaerobic ammonium oxidation (anammox) for nitrogen removal from wastewater at low temperatures. Maintenance of anammox- and aerobic ammonia oxidizing bacteria (AOB) and suppression of nitrite oxidizing bacteria (NOB) are key issues. In this work, a nitritation-anammox moving bed biofilm pilot reactor was operated at 19-10°C for 300 d. Nitrogen removal was decreasing, but stable, at 19-13°C. At 10°C removal became unstable. Quantitative PCR, fluorescence in situ hybridization and gene sequencing showed that no major microbial community changes were observed with decreased temperature. Anammox bacteria dominated the biofilm (0.9-1.2 × 10(14) 16S rRNA copies m(-2)). Most anammox bacteria were similar to Brocadia sp. 40, but another smaller Brocadia population was present near the biofilm-water interface, where also the AOB community (Nitrosomonas) was concentrated in thin layers (1.8-5.3 × 10(12) amoA copies m(-2)). NOB (Nitrobacter, Nitrospira) were always present at low concentrations (<1.3 × 10(11) 16S rRNA copies m(-2)).

  8. High-entropy alloys as high-temperature thermoelectric materials (United States)

    Shafeie, Samrand; Guo, Sheng; Hu, Qiang; Fahlquist, Henrik; Erhart, Paul; Palmqvist, Anders


    Thermoelectric (TE) generators that efficiently recycle a large portion of waste heat will be an important complementary energy technology in the future. While many efficient TE materials exist in the lower temperature region, few are efficient at high temperatures. Here, we present the high temperature properties of high-entropy alloys (HEAs), as a potential new class of high temperature TE materials. We show that their TE properties can be controlled significantly by changing the valence electron concentration (VEC) of the system with appropriate substitutional elements. Both the electrical and thermal transport properties in this system were found to decrease with a lower VEC number. Overall, the large microstructural complexity and lower average VEC in these types of alloys can potentially be used to lower both the total and the lattice thermal conductivity. These findings highlight the possibility to exploit HEAs as a new class of future high temperature TE materials.

  9. High-entropy alloys as high-temperature thermoelectric materials

    Energy Technology Data Exchange (ETDEWEB)

    Shafeie, Samrand [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Guo, Sheng, E-mail: [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Hu, Qiang [Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330029 (China); Fahlquist, Henrik [Bruker AXS Nordic AB, 17067 Solna (Sweden); Erhart, Paul [Department of Applied Physics, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Palmqvist, Anders, E-mail: [Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden)


    Thermoelectric (TE) generators that efficiently recycle a large portion of waste heat will be an important complementary energy technology in the future. While many efficient TE materials exist in the lower temperature region, few are efficient at high temperatures. Here, we present the high temperature properties of high-entropy alloys (HEAs), as a potential new class of high temperature TE materials. We show that their TE properties can be controlled significantly by changing the valence electron concentration (VEC) of the system with appropriate substitutional elements. Both the electrical and thermal transport properties in this system were found to decrease with a lower VEC number. Overall, the large microstructural complexity and lower average VEC in these types of alloys can potentially be used to lower both the total and the lattice thermal conductivity. These findings highlight the possibility to exploit HEAs as a new class of future high temperature TE materials.

  10. High-temperature superconducting conductors and cables

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, D.E.; Maley, M.P.; Boulaevskii, L.; Willis, J.O.; Coulter, J.Y.; Ullmann, J.L.; Cho, Jin; Fleshler, S.


    This is the final report of a 3-year LDRD project at LANL. High-temperature superconductivity (HTS) promises more efficient and powerful electrical devices such as motors, generators, and power transmission cables; however this depends on developing HTS conductors that sustain high current densities J{sub c} in high magnetic fields at temperatures near liq. N2`s bp. Our early work concentrated on Cu oxides but at present, long wire and tape conductors can be best made from BSCCO compounds with high J{sub c} at low temperatures, but which are degraded severely at temperatures of interest. This problem is associated with thermally activated motion of magnetic flux lines in BSCCO. Reducing these dc losses at higher temperatures will require a high density of microscopic defects that will pin flux lines and inhibit their motion. Recently it was shown that optimum defects can be produced by small tracks formed by passage of energetic heavy ions. Such defects result when Bi is bombarded with high energy protons. The longer range of protons in matter suggests the possibility of application to tape conductors. AC losses are a major limitation in many applications of superconductivity such as power transmission. The improved pinning of flux lines reduces ac losses, but optimization also involves other factors. Measuring and characterizing these losses with respect to material parameters and conductor design is essential to successful development of ac devices.

  11. High Temperature VARTM of Phenylethynyl Terminated Imides (United States)

    Ghose, Sayata; Watson, Kent A.; Cano, Roberto J.; Britton, Sean M.; Jensen, Brian J.; Connell, John W.; Herring, Helen M.; Linberry, Quentin J.


    LaRC phenylethynyl terminated imide (PETI) resins were processed into composites using high temperature vacuum assisted resin transfer molding (VARTM). Although initial runs yielded composites with high void content, process modifications reduced voids to <3%. Photomicrographs were taken and void contents and T(sub g)s of the panels were determined.

  12. Reactive Plasticizers for High Temperature Quinoxaline Thermoplastics (United States)


    involves essentially two steps, consolidation of boardy prepreg into sheet stock and thermoforming the sheet stock into structural components. A...problem associated with the fabrication process is the high temperatures required in both the consolidation and thermoforming operations. High processing

  13. Equivalent materials simulation experimental study on bed separations developing and mining subsidence in constant humidity and constant temperature conditions

    Institute of Scientific and Technical Information of China (English)

    FU Zhi-liang; WANG Su-hua; GAO Yan-fa


    A new experiment was made on the developing of bed separations and mining subsidence from Tangshan T2192 working face by equivalent materials simulation.The overburden deformation and the developing of bed separations with working face advancing was simulated by a new model.The results show that the maximum value of bed separations moved forward gradually along with the working face advancing; the maximum value of bed separations is 0.31~0.50 times of mining thickness.The key strata have a great influence upon surface subsidence during the overburden movement process.The mechanics parameters of new experiment are fitted with results in fields perfectly.

  14. Equivalent materials simulation experimental study on bed separations developing and mining subsidence in constant humidity and constant temperature conditions

    Institute of Scientific and Technical Information of China (English)

    FU Zhi-liang; WANG Su-hua; GAO Yan-fa


    A new experiment was made on the developing of bed separations and mining subsidence from Tangshan T2192 working face by equivalent materials simulation. The overburden deformation and the developing of bed separations with working face advanc-ing was simulated by a new model. The results show that the maximum value of bed separations moved forward gradually along with the working face advancing; the maxi-mum value of bed separations is 0.31 ~0.50 times of mining thickness. The key strata have a great influence upon surface subsidence during the overburden movement process. The mechanics parameters of new experiment are fitted with results in fields perfectly.

  15. High resolution field study of sediment dynamics on a strongly heterogeneous bed (United States)

    Bailly Du Bois, P.; Blanpain, O.; Lafite, R.; Cugier, P.; Lunven, M.


    Extensive field measurements have been carried out at several stations in a macrotidal inner continental shelf in the English Channel (around 25 m depth) during spring tide period. The strong tidal current measured (up to 1.6 m.s-1) allowed sediment dynamics on a bed characterised by a mixture of size with coarse grains to be dominant. Data acquired in such hydro-sedimentary conditions are scarce. A new instrument, the DYnamic Sediment Profile Imagery (DySPI) system, was specifically conceived and implemented in-situ to observe and measure, with a high temporal resolution, the dynamics of a strongly heterogeneous mixture of particles in a grain-size scale. The data collected covered: 1) grain size range (side scan sonar, video observations, Shipeck grab samples, DySPI images) and vertical sorting (stratigraphic sampling by divers) of sediment cover, 2) hydrodynamic features (acoustic Doppler velocimeter, acoustic Doppler profiler), 3) suspended load nature and dynamics (optical backscatter, chlorophyll fluorometer, particle size analyser, Niskin bottles, scanning electron microscopy), 4) sand and gravel bedload transport estimates (DySPI image processing), 5) transfer dynamics of fine grains within a coarse matrix and their depth of penetration (radionuclides measurements in stratigraphic samples). The four stations present different grain size vertical sorting from a quasi-permanent armouring to a homogenous distribution. The sediment cover condition is directly linked to hydrodynamic capacity and sediment availability. Fine grain ratio within deep sediment layers (up to 10 cm) is higher when the bed armouring is durable. However, fine sediments are not permanently depth trapped: deep layers are composed of few years-old radionuclide tracers fixed on fine grains and a vertical mixing coefficient has been evaluated for each sediment cover. Fine grain dynamics within a coarse matrix is inversely proportional to the robustness of the armour layer. For current

  16. Fluidized-bed calciner with combustion nozzle and shroud (United States)

    Wielang, Joseph A.; Palmer, William B.; Kerr, William B.


    A nozzle employed as a burner within a fluidized bed is coaxially enclosed within a tubular shroud that extends beyond the nozzle length into the fluidized bed. The open-ended shroud portion beyond the nozzle end provides an antechamber for mixture and combustion of atomized fuel with an oxygen-containing gas. The arrangement provides improved combustion efficiency and excludes bed particles from the high-velocity, high-temperature portions of the flame to reduce particle attrition.

  17. Effects of High Temperature on Collector Coatings (United States)

    Lowery, J. R.


    Report reveals electroplated black chrome is good coating for concentrating collectors in which temperatures are in the 650 degrees-800 degrees F (340 degrees - 430 degrees C) range. Black chrome thermal emittance is low and solar-absorption properties are not seriously degraded at high temperatures. Black coatings are used to increase absorption of solar energy by base metal while decreasing emission of infrared energy. Coatings are intended to improve efficiency of solar collectors.

  18. Ultra High Temperature Ceramics for aerospace applications


    Jankowiak, A.; Justin, J.F.


    Après relecture une erreur est apparue dans le document et doit être retiré; International audience; The Ultra High Temperature Ceramics (UHTCs) are of great interest for different engineering sectors and notably the aerospace industry. Indeed, hypersonic flights, re-entry vehicles, propulsion applications and so on, require new materials that can perform in oxidizing or corrosive atmospheres at temperatures higher than 2000°C and sometimes, for long life-time. To fulfil these requirements, U...

  19. Bed Agglomeration During the Steam Gasification of a High Lignin Corn Stover Simultaneous Saccharification and Fermentation (SSF) Digester Residue

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Daniel T.; Taasevigen, Danny J.; Gerber, Mark A.; Gray, Michel J.; Fernandez, Carlos A.; Saraf, Laxmikant; Garcia-Perez, Manuel; Wolcott, Michael P.


    This research investigates the bed agglomeration phenomena during the steam gasification of a high lignin residue produced from the simultaneous saccharification and fermentation (SSF) of corn stover in a bubbling fluidized bed. The studies were conducted at 895°C using alumina as bed material. Biomass was fed at 1.5 kg/hr, while steam was fed to give a velocity equal to 2.5 times the minimum fluidization velocity, with a steam/carbon ratio of 0.9. The pelletized feedstock was co-fed with a cooling nitrogen stream to mitigate feed line plugging issues. Tar production was high at 50.3 g/Nm3, and the fraction of C10+ compounds was greater than that seen in the gasification of traditional lignocellulosic feedstocks. Carbon closures over 94 % were achieved for all experiments. Bed agglomeration was found to be problematic, indicated by pressure drop increases observed below the bed and upstream of the feed line. Two size categories of solids were recovered from the reactor, +60 mesh and -60 mesh. After a 2.75-hour experiment, 61.7 wt % was recovered as -60 mesh particles and 38.2 wt% of the recovered reactor solids were +60 mesh. A sizeable percentage, 31.8 wt%, was +20 mesh. The -60 mesh particles were mainly formed by the initial bed material (Al2O3). Almost 50 wt. % of the + 20 mesh particles was found to be formed by organics. The unreacted carbon remaining in the reactor resulted in a low conversion rate to product gas. ICP-AES, SEM, SEM-EDS, and XRD confirmed that the large agglomerates (+ 20 mesh) were not encapsulated bed material but rather un-gasified feedstock pellets with sand particles attached to it.

  20. Low Temperature Heating and High Temperature Cooling in Buildings

    DEFF Research Database (Denmark)

    Kazanci, Ongun Berk

    , a single-family house designed for plus-energy targets and equipped with a radiant water-based floor heating and cooling system was studied by means of full-scale measurements, dynamic building simulations and thermodynamic evaluation tools. Thermal indoor environment and energy performance of the house...... performance of heating and cooling systems for achieving the same thermal indoor environment. The results show that it is crucial to minimize the heating and cooling demands in the design phase since these demands determine the terminal units and heat sources and sinks that could be used. Low temperature...... heating and high temperature cooling systems (a radiant water-based floor heating and cooling system in this study) proved to be superior to compared systems, evaluated with different system analysis tools; energy, exergy, and entransy. Radiant systems should be coupled to appropriate heating and cooling...

  1. High throughput production of double emulsions using packed bed premix emulsification

    NARCIS (Netherlands)

    Sahin, S.; Sawalha, H.I.M.; Schroen, C.G.P.H.


    We explored the potential of packed bed premix emulsification for homogenizing coarse food grade W/O/W emulsions, prepared with sunflower oil. Using packed beds with different glass bead sizes (30–90 µm) at different applied pressures (200–600 kPa), emulsions with reasonably uniform droplet size (sp

  2. CFD Analysis of the Fuel Temperature in High Temperature Gas-Cooled Reactors

    Energy Technology Data Exchange (ETDEWEB)

    In, W. K.; Chun, T. H.; Lee, W. J.; Chang, J. H. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    High temperature gas-cooled reactors (HTGR) have received a renewed interest as potential sources for future energy needs, particularly for a hydrogen production. Among the HTGRs, the pebble bed reactor (PBR) and a prismatic modular reactor (PMR) are considered as the nuclear heat source in Korea's nuclear hydrogen development and demonstration project. PBR uses coated fuel particles embedded in spherical graphite fuel pebbles. The fuel pebbles flow down through the core during an operation. PMR uses graphite fuel blocks which contain cylindrical fuel compacts consisting of the fuel particles. The fuel blocks also contain coolant passages and locations for absorber and control material. The maximum fuel temperature in the core hot spot is one of the important design parameters for both PBR and PMR. The objective of this study is to predict the fuel temperature distributions in PBR and PMR using a computational fluid dynamics(CFD) code, CFX-5. The reference reactor designs used in this analysis are PBMR400 and GT-MHR600.

  3. Low toxicity high temperature PMR polyimide (United States)

    Pater, Ruth H. (Inventor)


    In-situ polymerization of monomer reactants (PMR) type polyimides constitute an important class of ultra high performance composite matrix resins. PMR-15 is the best known and most widely used PMR polyimide. An object of the present invention is to provide a substantially improved high temperature PMR-15 system that exhibits better processability, toughness, and thermo-oxidative stability than PMR-15, as well as having a low toxicity. Another object is to provide new PMR polyimides that are useful as adhesives, moldings, and composite matrices. By the present invention, a new PMR polyimide comprises a mixture of the following compounds: 3,4'-oxydianiline (3,4'-ODA), NE, and BTDE which are then treated with heat. This PMR was designated LaRC-RP46 and has a broader processing window, better reproducibility of high quality composite parts, better elevated temperature mechanical properties, and higher retention of mechanical properties at an elevated temperature, particularly, at 371 C.

  4. High resolution ice thickness, bed topography, and roughness of a land terminating section of the western Greenland Ice Sheet

    DEFF Research Database (Denmark)

    Lindback, K.; Pettersson, R.; Doyle, S. H.

    the spectral roughness. We see a strong correlation of low roughness values with the ice flow direction; this makes it important to assess the direction of the radar profiles in relation to the flow direction when calculating effective subglacial roughness for an area. Low roughness values and high surface......We present ice thickness and bed topography maps with high spatial resolution (250-500 m) of a large land terminating section of the western Greenland Ice Sheet. The maps cover the Isunnguata Sermia, Russell, and Leverett outlet glaciers and their catchment areas up to an elevation of ~1,700 m...... above sea level. The bed topography shows an intricate subglacial trough system, resembling the landscape in the proglacial area. We also calculate the hydraulic potential to get a proxy of the subglacial routing of water in the area. To analyse the geomorphological conditions of the bed, we calculated...

  5. Pt-catalyzed ozonation of aqueous phenol solution using high-gravity rotating packed bed. (United States)

    Chang, Chia-Chi; Chiu, Chun-Yu; Chang, Ching-Yuan; Chang, Chiung-Fen; Chen, Yi-Hung; Ji, Dar-Ren; Tseng, Jyi-Yeong; Yu, Yue-Hwa


    In this study, a high-gravity rotating packed bed (HGRPB or HG) was used as a catalytic ozonation (Cat-OZ) reactor to decompose phenol. The operation of HGRPB system was carried out in a semi-batch apparatus which combines two major parts, namely the rotating packed bed (RPB) and photo-reactor (PR). The high rotating speed of RPB can give a high volumetric gas-liquid mass transfer coefficient with one or two orders of magnitude higher than those in the conventional packed beds. The platinum-containing catalyst (Dash 220N, Pt/gamma-Al(2)O(3)) and activated alumina (gamma-Al(2)O(3)) were packed in the RPB respectively to adsorb molecular ozone and the target pollutant of phenol on the surface to catalyze the oxidation of phenol. An ultra violet (UV) lamp (applicable wavelength lambda=200-280 nm) was installed in the PR to enhance the self-decomposition of molecular ozone in water to form high reactive radical species. Different combinations of advanced oxidation processes (AOPs) with the HGRPB for the degradation of phenol were tested. These included high-gravity OZ (HG-OZ), HG catalytic OZ (HG-Cat-OZ), HG photolysis OZ (HG-UV-OZ) and HG-Cat-OZ with UV (HG-Cat-UV-OZ). The decomposition efficiency of total organic compound (eta(TOC)) of HG-UV-OZ with power of UV (P(UV)) of 16W is 54% at applied dosage of ozone per volume sample m(A,in)=1200 mg L(-1) (reaction time t=20 min), while that of HG-OZ without the UV irradiation is 24%. After 80 min oxidation (m(A,in)=4800 mg L(-1)), the eta(TOC) of HG-UV-OZ is as high as 94% compared to 82% of HG-OZ process. The values of eta(TOC) for HG-Cat-OZ process with m(S)=42 g are 56% and 87% at m(A,in)=1200 and 4800 mg L(-1), respectively. By increasing the catalyst mass to 77 g, the eta(TOC) for the HG-Cat-OZ process reaches 71% and 90% at m(A,in)=1200 and 4800 mg L(-1), respectively. The introduction of Pt/gamma-Al(2)O(3) as well as UV irradiation in the HG-OZ process can enhance the eta(TOC) of phenol significantly, while gamma

  6. High temperature and pressure alkaline electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank; Chatzichristodoulou, Christodoulos; Mogensen, Mogens Bjerg


    and pressures. Two measurement systems were built to perform measurements under high pressures and at elevated temperatures of up to 95 bar and 250 °C, respectively. The conductivity of aqueous KOH and aqueous KOH immobilized in a porous SrTiO3 structure were investigated at elevated temperatures and high...... the operational temperature and pressure to produce pressurized hydrogen at high rate (m3 H2·h-1·m-2 cell area) and high electrical efficiency. This work describes an exploratory technical study of the possibility to produce hydrogen and oxygen with a new type of alkaline electrolysis cell at high temperatures...... concentrations of the electrolyte using the van der Pauw method in combination with electrochemical impedance spectroscopy (EIS). Conductivity values as high as 2.9 S cm-1 for 45 wt% KOH aqueous KOH and 0.84 S cm-1 for the immobilized KOH of the same concentration were measured at 200 °C. Porous SrTiO3 was used...

  7. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chang Oh; Eung Kim; Richard Schultz; Mike Patterson; Davie Petti


    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R&D) that will be critical to the success of the NGNP, primarily in the areas of: • High temperature gas reactor fuels behavior • High temperature materials qualification • Design methods development and validation • Hydrogen production technologies • Energy conversion. This paper presents current R&D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs.

  8. High temperature superconductivity the road to higher critical temperature

    CERN Document Server

    Uchida, Shin-ichi


    This book presents an overview of material-specific factors that influence Tc and give rise to diverse Tc values for copper oxides and iron-based high- Tc superconductors on the basis of more than 25 years of experimental data, to most of which the author has made important contributions. The book then explains why both compounds are distinct from others with similar crystal structure and whether or not one can enhance Tc, which in turn gives a hint on the unresolved pairing mechanism. This is an unprecedented new approach to the problem of high-temperature superconductivity and thus will be inspiring to both specialists and non-specialists interested in this field.   Readers will receive in-depth information on the past, present, and future of high-temperature superconductors, along with special, updated information on what the real highest Tc values are and particularly on the possibility of enhancing Tc for each member material, which is important for application. At this time, the highest Tc has not been...

  9. High temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters...... of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept...

  10. Materials for high-temperature fuel cells

    CERN Document Server

    Jiang, San Ping; Lu, Max


    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in High-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in high-temperature fuel cells with emphasis on the most important solid oxide fuel cells. A related book will cover key mater

  11. Metallic Membranes for High Temperature Hydrogen Separation

    DEFF Research Database (Denmark)

    Ma, Y.H.; Catalano, Jacopo; Guazzone, Federico


    Composite palladium membranes have extensively been studied in laboratories and, more recently, in small pilot industrial applications for the high temperature separation of hydrogen from reactant mixtures such as water-gas shift (WGS) reaction or methane steam reforming (MSR). Composite Pd...... than 1000, respectively. This chapter describes in detail composite Pd-based membrane preparation methods, which consist of the grading of the support and the deposition of the dense metal layer, their performances, and their applications in catalytic membrane reactors (CMRs) at high temperatures (400...

  12. High Temperature Protonic Conductors by Melt Growth (United States)


    ceramic materials of BaCe1 -xNdxO3-a and Ba3(CaNb2)O9 that exhibit high temperature protonic conductance and superior mechanical properties at elevated...TEM). The mechanical behavior BaCe1 -xNdxO3-a (x=0 to 0.2) and Ba3(CaNb2)O9 ceramics in the elastic, brittle and plastic regime will be studied...spatial variations of compositions in BaCe1 -xNdxO3-a and Ba3(CaNb2)O9 following high temperature wet atmosphere treatment will be measured using a

  13. Additive Manufacturing of Advanced High Temperature Masking Fixtures for EBPVD TBC Coating

    Energy Technology Data Exchange (ETDEWEB)

    List, III, Frederick Alyious [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Feuerstein, Albert [Praxair Surface Technologies, Inc., (United States); Dehoff, Ryan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kirka, Michael [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Carver, Keith [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)


    The purpose of this Manufacturing Demonstration Facility (MDF) technical collaboration project between Praxair Surface Technologies, Inc. (PST) and Oak Ridge National Laboratory (ORNL) was to develop an additive manufacturing process to fabricate next generation high temperature masking fixtures for coating of turbine airfoils with ceramic Thermal Barrier Coatings (TBC) by the Electron Beam Physical Vapor Deposition (EBPVD) process. Typical masking fixtures are sophisticated designs and require complex part manipulation in order to achieve the desired coating distribution. Fixtures are typically fabricated from high temperature nickel (Ni) based superalloys. The fixtures are fabricated from conventional processes by welding of thin sheet material into a complex geometry, to decrease the weight load for the manipulator and to reduce the thermal mass of the fixture. Recent attempts have been made in order to fabricate the fixtures through casting, but thin walled sections are difficult to cast and have high scrap rates. This project focused on understanding the potential for fabricating high temperature Ni based superalloy fixtures through additive manufacturing. Two different deposition processes; electron beam melting (EBM) and laser powder bed fusion were evaluated to determine the ideal processing route of these materials. Two different high temperature materials were evaluated. The high temperature materials evaluated were Inconel 718 and another Ni base alloy, designated throughout the remainder of this document as Alloy X, as the alloy composition is sensitive. Inconel 718 is a more widely utilized material for additive manufacturing although it is not currently the material utilized for current fixtures. Alloy X is the alloy currently used for the fixtures, but is not a commercially available alloy for additive manufacturing. Praxair determined it was possible to build the fixture using laser powder bed technology from Inconel 718. ORNL fabricated the fixture

  14. High rate biological nutrient removal from high strength wastewater using anaerobic-circulating fluidized bed bioreactor (A-CFBBR). (United States)

    Andalib, Mehran; Nakhla, George; Zhu, Jesse


    Biological nutrient removal (BNR) from high strength wastewater was investigated using a newly developed integrated anaerobic fluidized bed (AF) with circulating fluidized bed bioreactor henceforth called A-CFBBR. The A-CFBBR showed 99.7%COD removal, 84% nitrogen removal, with a very low sludge yield of 0.017 g VSS/g COD while treating a synthetic wastewater containing 10,700 mg COD/L and 250 mg NH(3)-N/L over a period of 6 months. The system was operated at an organic loading rate (OLR) of 35 kg COD/m(3)(AF) d and nitrogen loading rate (NLR) of 1.1 kg N/m(3)(CFBBR) d at a hydraulic retention time (HRT) of less than 12 h in the A-CFBBR. Microbial communities analysis using DGGE confirmed the presence of both AOBs and NOBs in the riser and downer. Pseudomonas putida and Pseudomonas fluorescence were the dominant denitrifiers present in the downer. Methanogenic activity was accomplished by a microbial mixture of archaea and bacteria in the anaerobic column.

  15. High-temperature MAS-NMR at high spinning speeds. (United States)

    Kirchhain, Holger; Holzinger, Julian; Mainka, Adrian; Spörhase, Andreas; Venkatachalam, Sabarinathan; Wixforth, Achim; van Wüllen, Leo


    A low cost version to enable high temperature MAS NMR experiments at temperatures of up to 700°C and spinning speeds of up to 10kHz is presented. The method relies on inductive heating using a metal coated rotor insert. The metal coating is accomplished via a two step process involving physical vapor deposition and galvanization.

  16. Responses of the bed bug, Cimex lectularius, to temperature extremes and dehydration: levels of tolerance, rapid cold hardening and expression of heat shock proteins. (United States)

    Benoit, J B; Lopez-Martinez, G; Teets, N M; Phillips, S A; Denlinger, D L


    This study of the bed bug, Cimex lectularius, examines tolerance of adult females to extremes in temperature and loss of body water. Although the supercooling point (SCP) of the bed bugs was approximately -20 degrees C, all were killed by a direct 1 h exposure to -16 degrees C. Thus, this species cannot tolerate freezing and is killed at temperatures well above its SCP. Neither cold acclimation at 4 degrees C for 2 weeks nor dehydration (15% loss of water content) enhanced cold tolerance. However, bed bugs have the capacity for rapid cold hardening, i.e. a 1-h exposure to 0 degrees C improved their subsequent tolerance of -14 and -16 degrees C. In response to heat stress, fewer than 20% of the bugs survived a 1-h exposure to 46 degrees C, and nearly all were killed at 48 degrees C. Dehydration, heat acclimation at 30 degrees C for 2 weeks and rapid heat hardening at 37 degrees C for 1 h all failed to improve heat tolerance. Expression of the mRNAs encoding two heat shock proteins (Hsps), Hsp70 and Hsp90, was elevated in response to heat stress, cold stress and during dehydration and rehydration. The response of Hsp90 was more pronounced than that of Hsp70 during dehydration and rehydration. Our results define the tolerance limits for bed bugs to these commonly encountered stresses of temperature and low humidity and indicate a role for Hsps in responding to these stresses.

  17. The influence of fibrous bed bulk density on the bed properties

    Directory of Open Access Journals (Sweden)

    Šećerov-Sokolović Radmila M.


    Full Text Available The mean properties of seven different fibrous materials and the properties of their different bed bulk densities were investigated. The morphology of the surface, size and geometry were measured by optical microscopy. The bed porosity was measured by the weighing method. The experimental bed permeability, in a high range of bulk density, was calculated from the values of the sanitary water pressure drop at a constant temperature of 15°C, since the data followed Darcy's law. The Reynolds number for a fibrous bed was calculated using a relation from the literature. The Reynolds number was less than 1 for all ranges of fluid velocity. Three empirical relations for fibrous bed permeability were used and compared with the experimental data. It was determined that the empirical data depended on the fiber diameter and fraction of solid in the bed. The relative error linearly increased with increasing fiber diameter.

  18. High Temperature Mechanisms for Venus Exploration (United States)

    Ji, Jerri; Narine, Roop; Kumar, Nishant; Singh, Sase; Gorevan, Steven

    Future Venus missions, including New Frontiers Venus In-Situ Explorer and three Flagship Missions - Venus Geophysical Network, Venus Mobile Explorer and Venus Surface Sample Return all focus on searching for evidence of past climate change both on the surface and in the atmospheric composition as well as in the interior dynamics of the planet. In order to achieve these goals and objectives, many key technologies need to be developed for the Venus extreme environment. These key technologies include sample acquisition systems and other high-temperature mechanisms and mobility systems capable of extended operation when directly exposed to the Venus surface or lower atmosphere environment. Honeybee Robotics has developed two types of high temperature motors, the materials and components in both motors were selected based on the requirement to survive temperatures above a minimum of 460° C, at earth atmosphere. The prototype Switched Reluctance Motor (SRM) has been operated non-continuously for over 20 hours at Venus-like conditions (460° C temperature, mostly CO2 gas environment) and it remains functional. A drilling system, actuated by two SRMs was tested in Venus-like conditions, 460° C temperature and mostly CO2 gas environment, for more than 15 hours. The drill successfully completed three tests by drilling into chalk up to 6 inches deep in each test. A first generation Brushless DC (BLDC) Motor and high temperature resolver were also tested and the feasibility of the designs was demonstrated by the extended operation of both devices under Venus-like condition. Further development of the BLDC motor and resolver continues and these devices will, ultimately, be integrated into the development of a high temperature sample acquisition scoop and high temperature joint (awarded SBIR Phase II in October, 2007). Both the SR and BLDC motors will undergo extensive testing at Venus temperature and pressure (TRL6) and are expected to be mission ready before the next New

  19. Combined photolysis and catalytic ozonation of dimethyl phthalate in a high-gravity rotating packed bed. (United States)

    Chang, Chia-Chi; Chiu, Chun-Yu; Chang, Ching-Yuan; Chang, Chiung-Fen; Chen, Yi-Hung; Ji, Dar-Ren; Yu, Yue-Hwa; Chiang, Pen-Chi


    In this study, a high-gravity rotating packed bed (HGRPB) was used as a catalytic ozonation reactor to decompose dimethyl phthalate (DMP), an endocrine disrupting chemical commonly encountered. The HGRPB is an effective gas-liquid mixing equipment which can enhance the ozone mass transfer coefficient. Platinum-containing catalyst (Pt/-Al2O3) of Dash 220N and ultra violet (UV) lamp were combined in the high-gravity ozonation (HG-OZ) system to enhance the self-decomposition of molecular ozone in liquid to form highly reactive radical species. Different combinations of HG-OZ with Dash 220N and UV for the degradation of DMP were tested. These include HG-OZ, HG catalytic OZ (HG-Pt-OZ), HG photolysis OZ (HG-UV-OZ) and HG-UV-Pt-OZ. The result indicated that all the above four ozonation processes result in significant decomposition of DMP and mineralization of total organic carbon (TOC) at the applied ozone dosage per volume of liquid sample of 1.2gL(-1). The UV and Pt/gamma-Al2O3 combined in HG-OZ can enhance the TOC mineralization efficiency (eta(TOC)) to 56% (via HG-UV-OZ) and 57% (via HG-Pt-OZ), respectively, while only 45% with ozone only. The process of HG-UV-Pt-OZ offers the highest eta(TOC) of about 68%.

  20. High temperature reactors for cogeneration applications

    Energy Technology Data Exchange (ETDEWEB)

    Verfondern, Karl [Forschungszentrum Juelich (Germany). IEK-6; Allelein, Hans-Josef [Forschungszentrum Juelich (Germany). IEK-6; RWTH Aachen (Germany). Lehrstuhl fuer Reaktorsicherheit und -technik (LRST)


    There is a large potential for nuclear energy also in the non-electric heat market. Many industrial sectors have a high demand for process heat and steam at various levels of temperature and pressure to be provided for desalination of seawater, district heating, or chemical processes. The future generation of nuclear plants will be capable to enter the wide field of cogeneration of heat and power (CHP), to reduce waste heat and to increase efficiency. This requires an adjustment to multiple needs of the customers in terms of size and application. All Generation-IV concepts proposed are designed for coolant outlet temperatures above 500 C, which allow applications in the low and medium temperature range. A VHTR would even be able to cover the whole temperature range up to approx. 1 000 C.

  1. On-wafer high temperature characterization system (United States)

    Teodorescu, L.; ǎghici, F., Dr; Rusu, I.; Brezeanu, G.


    In this work a on-wafer high temperature characterization system for wide bandgap semiconductor devices and circuits has been designed, implemented and tested. The proposed system can perform the wafer temperature adjustment in a large domain, from the room temperature up to 3000C with a resolution better than +/-0.50C. In order to obtain both low-noise measurements and low EMI, the heating element of the wafer chuck is supplied in two ways: one is from a DC linear power supply connected to the mains electricity, another one is from a second DC unit powered by batteries. An original temperature control algorithm, different from classical PID, is used to modify the power applied to the chuck.

  2. High-temperature borate crystal chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Bubnova, Rimma S. [Russian Academy of Sciences, St. Petersburg (Russian Federation). Grebenshchikov Institute of Silicate Chemistry; Saint Petersburg State Univ. (Russian Federation). Dept. of Crystallography; Filatov, Stanislav K. [Saint Petersburg State Univ. (Russian Federation). Dept. of Crystallography


    The paper presents a brief review of the present state of high-temperature borate crystal chemistry. This review summarizes the results of high- and low-temperature single crystal X-ray diffraction studies for more than 10 borate structures and high-temperature powder Xray diffraction data for about 65 borates. Thermal behavior of their crystal structures, thermal expansion, polymorphic transitions and their relationship to borate glasses are presented. These studies allow to formulate the basic principles of high-temperature borate crystal chemistry and to reveal the regularities of thermal behavior of borates. On heating, the BO{sub 3} and BO{sub 4} polyhedra and rigid groups consisting of these polyhedra, practically maintain their configuration and size, but they are able to rotate like hinges exhibiting highly anisotropic thermal expansion, including linear negative expansion. Based on these results, we generalize the term 'rigid group' and render thermal vibrations as the key ingredient for the self-assembly of borate rigid groups. (orig.)

  3. High-Temperature Capacitor Polymer Films (United States)

    Tan, Daniel; Zhang, Lili; Chen, Qin; Irwin, Patricia


    Film capacitor technology has been under development for over half a century to meet various applications such as direct-current link capacitors for transportation, converters/inverters for power electronics, controls for deep well drilling of oil and gas, direct energy weapons for military use, and high-frequency coupling circuitry. The biaxially oriented polypropylene film capacitor remains the state-of-the-art technology; however, it is not able to meet increasing demand for high-temperature (>125°C) applications. A number of dielectric materials capable of operating at high temperatures (>140°C) have attracted investigation, and their modifications are being pursued to achieve higher volumetric efficiency as well. This paper highlights the status of polymer dielectric film development and its feasibility for capacitor applications. High-temperature polymers such as polyetherimide (PEI), polyimide, and polyetheretherketone were the focus of our studies. PEI film was found to be the preferred choice for high-temperature film capacitor development due to its thermal stability, dielectric properties, and scalability.

  4. High-Temperature Shape Memory Polymers (United States)

    Yoonessi, Mitra; Weiss, Robert A.


    physical conformation changes when exposed to an external stimulus, such as a change in temperature. Such materials have a permanent shape, but can be reshaped above a critical temperature and fixed into a temporary shape when cooled under stress to below the critical temperature. When reheated above the critical temperature (Tc, also sometimes called the triggering or switching temperature), the materials revert to the permanent shape. The current innovation involves a chemically treated (sulfonated, carboxylated, phosphonated, or other polar function group), high-temperature, semicrystalline thermoplastic poly(ether ether ketone) (Tg .140 C, Tm = 340 C) mix containing organometallic complexes (Zn++, Li+, or other metal, ammonium, or phosphonium salts), or high-temperature ionic liquids (e.g. hexafluorosilicate salt with 1-propyl-3- methyl imidazolium, Tm = 210 C) to form a network where dipolar or ionic interactions between the polymer and the low-molecular-weight or inorganic compound forms a complex that provides a physical crosslink. Hereafter, these compounds will be referred to as "additives". The polymer is semicrystalline, and the high-melt-point crystals provide a temporary crosslink that acts as a permanent crosslink just so long as the melting temperature is not exceeded. In this example case, the melting point is .340 C, and the shape memory critical temperature is between 150 and 250 C. PEEK is an engineering thermoplastic with a high Young fs modulus, nominally 3.6 GPa. An important aspect of the invention is the control of the PEEK functionalization (in this example, the sulfonation degree), and the thermal properties (i.e. melting point) of the additive, which determines the switching temperature. Because the compound is thermoplastic, it can be formed into the "permanent" shape by conventional plastics processing operations. In addition, the compound may be covalently cross - linked after forming the permanent shape by S-PEEK by applying ionizing

  5. High temperature fatigue behaviour of intermetallics

    Indian Academy of Sciences (India)

    K Bhanu Sankara Rao


    There would be considerable benefits in developing new structural materials where high use temperatures and strength coupled with low density are minimum capabilities. Nickel and titanium aluminides exhibit considerable potential for near-term application in various branches of modern industry due to the number of property advantages they possess including low density, high melting temperature, high thermal conductivity, and excellent environmental resistance, and their amenability for significant improvment in creep and fatigue resistance through alloying. Reliability of intermetallics when used as engineering materials has not yet been fully established. Ductility and fracture toughness at room and intermediate temperatures continue to be lower than the desired values for production implementation. In this paper, progress made towards improving strain-controlled fatigue resistance of nickel and titanium aluminides is outlined. The effects of manufacturing processes and micro alloying on low cycle fatigue behaviour of NiAl are addressed. The effects of microstructure, temperature of testing, section thickness, brittle to ductile transition temperature, mean stress and environment on fatigue behaviour of same -TiAl alloys are discussed.

  6. Bimodular high temperature planar oxygen gas sensor

    Directory of Open Access Journals (Sweden)

    Xiangcheng eSun


    Full Text Available A bimodular planar O2 sensor was fabricated using NiO nanoparticles (NPs thin film coated yttria-stabilized zirconia (YSZ substrate. The thin film was prepared by radio frequency (r.f. magnetron sputtering of NiO on YSZ substrate, followed by high temperature sintering. The surface morphology of NiO nanoparticles film was characterized by atomic force microscopy (AFM and scanning electron microscopy (SEM. X-ray diffraction (XRD patterns of NiO NPs thin film before and after high temperature O2 sensing demonstrated that the sensing material possesses a good chemical and structure stability. The oxygen detection experiments were performed at 500 °C, 600 °C and 800 °C using the as-prepared bimodular O2 sensor under both potentiometric and resistance modules. For the potentiometric module, a linear relationship between electromotive force (EMF output of the sensor and the logarithm of O2 concentration was observed at each operating temperature, following the Nernst law. For the resistance module, the logarithm of electrical conductivity was proportional to the logarithm of oxygen concentration at each operating temperature, in good agreement with literature report. In addition, this bimodular sensor shows sensitive, reproducible and reversible response to oxygen under both sensing modules. Integration of two sensing modules into one sensor could greatly enrich the information output and would open a new venue in the development of high temperature gas sensors.

  7. High Accuracy, Miniature Pressure Sensor for Very High Temperatures Project (United States)

    National Aeronautics and Space Administration — SiWave proposes to develop a compact, low-cost MEMS-based pressure sensor for very high temperatures and low pressures in hypersonic wind tunnels. Most currently...

  8. H{sub 2}S removal from coal gas at elevated temperature and pressure in fluidized bed with zinc titanate sorbents. 1. Cyclic tests

    Energy Technology Data Exchange (ETDEWEB)

    Mojtahedi, W.; Abbasian, J. [Enviropower Inc., Espoo (Finland)


    Simplified integrated gasification combined cycle (IGCC) processes are considered to be among the most efficient and environmentally acceptable technologies for power generation from coal. In such processes the coal is gasified at pressure and the coal gas is cleaned and combusted in a gas turbine. Coal gas cleanup at elevated pressure and temperature in the IGCC processes offers advantages in higher power generation efficiency and simpler plant configuration. Regenerable mixed metal oxide sorbents are the prime candidates for removal of hydrogen sulfide (the main pollutant) from the hot coal gas in the simplified IGCC processes. In this paper, the results of cyclic sulfidation/regeneration tests conducted with two zinc titanate sorbents are presented and discussed. These tests were carried out at high pressure and temperature (20 bar, 550-650{degree}C) in a bench-scale fluidized-bed reactor. The results indicate that the reactivity of both sorbents towards H{sub 2}S gradually decline in cyclic sulfidation/regeneration tests. 20 refs., 11 figs., 4 tabs.

  9. Gravimeter using high-temperature superconductor bearing.

    Energy Technology Data Exchange (ETDEWEB)

    Hull, J. R.


    We have developed a sensitive gravimeter concept that uses an extremely low-friction bearing based on a permanent magnet (PM) levitated over a high-temperature superconductor (HTS). A mass is attached to the PM by means of a cantilevered beam, and the combination of PM and HTS forms a bearing platform that has low resistance to rotational motion but high resistance to horizontal, vertical, or tilting motion. The combination acts as a low-loss torsional pendulum that can be operated in any orientation. Gravity acts on the cantilevered beam and attached mass, accelerating them. Variations in gravity can be detected by time-of-flight acceleration, or by a control coil or electrode that would keep the mass stationary. Calculations suggest that the HTS gravimeter would be as sensitive as present-day superconducting gravimeters that need cooling to liquid helium temperatures, but the HTS gravimeter needs cooling only to liquid nitrogen temperatures.

  10. Effective Thermal Conductivity of Adsorbent Packed Beds (United States)

    Mori, Hideo; Hamamoto, Yoshinori; Yoshida, Suguru

    The effective thermal conductivity of adsorbent packed beds of granular zeolite 13X and granular silica gel A in the presence of stagnant steam or air was measured under different conditions of the adsorbent bed temperature, particle size and filler-gas pressure. The measured effective thermal conductivity showed to become smaller with decreasing particle size or decreasing pressure, but it was nearly independent of the bed temperature. When steam was the filler-gas, the rise in the thermal conductivity of the adsorbent particles due to steam adsorption led to the increase in the effective thermal conductivity of the bed, and this effect was not negligible at high steam pressure for the bed of large particle size. It was found that both the predictions of the effective thermal conductivity by the Hayashi et al.'s model and the Bauer-Schlünder model generally agreed well with the measurements, by considering the particle thermal conductivity rise due to steam adsorption. The thermal conductivity of a consolidated bed of granular zeolite 13X was also measured, and it was found to be much larger than that of the packed bed especially at lower pressure. The above prediction models underestimated the effective thermal conductivity of the consolidated bed.

  11. High-temperature carbidization of carboniferous rocks (United States)

    Goldin, B. A.; Grass, V. E.; Nadutkin, A. V.; Nazarova, L. Yu.


    Processes of thermal metamorphism of carboniferous rocks have been studied experimentally. The conditions of high-temperature interaction of shungite carbon with components of the contained rocks, leading to formation of carbide compounds, have been determined. The results of this investigation contribute to the works on searching for new raw material for prospective material production.

  12. 10.3 High-temperature Instrumentation (United States)

    Piazza, Anthony


    This viewgraph presentation describes high temperature instrumentation development from 1960-1970, 1980-1990 and 2000-present. The contents include: 1) Background; 2) Objective; 3) Application and Sensor; 4) Attachment Techniques; 5) Evaluation/Characterization Testing; and 6) Future testing.

  13. Anharmonic phonons and high-temperature superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Crespi, V.H.; Cohen, M.L. (Department of Physics, University of California at Berkeley, and Materials Sciences Division, Lawrence Berkeley Laboratory, Berkeley, California 94720 (United States))


    We examine a simple model of anharmonic phonons with application to the superconducting isotope effect. Linear and quadratic electron-phonon coupling are considered for various model potentials. The results of the model calculations are compared with the high-temperature superconductors La[sub 2[minus][ital x

  14. Nuclear and Quark Matter at High Temperature

    CERN Document Server

    Biro, T S; Schram, Z


    We review important ideas on nuclear and quark matter description on the basis of high- temperature field theory concepts, like resummation, dimensional reduction, interaction scale separation and spectral function modification in media. Statistical and thermodynamical concepts are spotted in the light of these methods concentrating on the - partially still open - problems of the hadronization process.

  15. Analysis of iron oxidation at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Slattery, J.C.; Peng, K.Y.; Gadalla, A.M.; Gadalla, N. [Texas A and M Univ., College Station, TX (United States). Dept. of Chemical Engineering


    A new theory for the high-temperature oxidation of iron is proposed, in which the rate-limiting step is ternary diffusion of ferric, ferrous, and oxygen ions in the iron oxides that are formed. The predictions of this theory are compared with previously published experimental data. The only thermodynamic information required is a phase diagram.

  16. Dynamics of Gauge Fields at High Temperature

    NARCIS (Netherlands)

    Nauta, B.J.


    An effective description of dynamical Bose fields is provided by the classical (high-temperature) limit of thermal field theory. The main subject of this thesis is to improve the ensuing classical field theory, that is, to include the dominant quantum corrections and to add counter terms for the Ray

  17. High Temperature Corrosion in Biomass Incineration Plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Gotthjælp, K.


    The aim of the project is to study the role of ash deposits in high temperature corrosion of superheater materials in biomass and refuse fire combined heat and power plants. The project has included the two main activities: a) A chemical characterisation of ash deposits collected from a major...

  18. Enamel for high-temperature superalloys (United States)

    Levin, H.; Lent, W. E.


    Desired optical and high temperature enamel properties are obtained with glasses prepared from the system Li2O-ZrO2-nSiO2. Molar compositions range from n=4 to n=1.3, to which are added minor amounts in varying combinations of alumina, alkali fluorides, boric oxide, alkali oxides, and akaline earth oxides.

  19. Solar-driven high temperature radiant cooling

    Institute of Scientific and Technical Information of China (English)

    SONG ZhaoPei; WANG RuZhu; ZHAI XiaoQiang


    Solar energy is widely used as one of the most important renewable energy. In addition to the growing applications of solar PV and solar water heater, solar cooling is also considered very valuable and the related researches are developing fast because of the synchronism between solar irradiance and building cooling load. Current studies mainly focus on the high temperature solar collector technique and heat-driven cooling technique, while little concern has been paid to the transport process of cooling power. In this paper, the high temperature radiant cooling is studied as an alternative way for transporting cooling power, and the performance of the combination of radiant ceiling and solar cooling is also studied. From simulation and theoretical analysis results, high temperature radiant cooling terminal shows better cooling power transportation ability against conventional air-conditioning terminal, and its thermal comfort is improved. Experiment results indicate that radiant cooling can enhance the chiller's COP (Coefficient of Performance) by 17% and cooling power regeneration by 50%.According to analysis in this paper, high temperature radiant cooling is proved to be suitable for solar cooling system, and out work can serve as a reference for later system design and promotion.

  20. Defluidization in fluidized bed gasifiers using high-alkali content fuels

    DEFF Research Database (Denmark)

    Narayan, Vikas; Jensen, Peter Arendt; Henriksen, Ulrik Birk


    major concern in thermal conversion of biomass encountered in fluidized beds is bed agglomeration, which may result in de-fluidization, leading to unscheduled downtime and additional costs. Biomass fuels, especially herbaceous plants, often contain significant amounts of silicon, potassium...... using strawas a fuel. It was seen that in sand þ KCl agglomerates, the sand particles were bound by KCl melts. Onlyvery limited chemical reaction was observed between KCl and the sand particles and no presence of silicate melts in the agglomerates. For sand þ K2CO3 mixtures and for LTCFB bed material...

  1. High-pressure-high-temperature treatment of natural diamonds

    CERN Document Server

    Royen, J V


    The results are reported of high-pressure-high-temperature (HPHT) treatment experiments on natural diamonds of different origins and with different impurity contents. The diamonds are annealed in a temperature range up to 2000 sup o C at stabilizing pressures up to 7 GPa. The evolution is studied of different defects in the diamond crystal lattice. The influence of substitutional nitrogen atoms, plastic deformation and the combination of these is discussed. Diamonds are characterized at room and liquid nitrogen temperature using UV-visible spectrophotometry, Fourier transform infrared spectrophotometry and photoluminescence spectrometry. The economic implications of diamond HPHT treatments are discussed.

  2. The Evolution of High Temperature Gas Sensors.

    Energy Technology Data Exchange (ETDEWEB)

    Garzon, F. H. (Fernando H.); Brosha, E. L. (Eric L.); Mukundan, R. (Rangachary)


    Gas sensor technology based on high temperature solid electrolytes is maturing rapidly. Recent advances in metal oxide catalysis and thin film materials science has enabled the design of new electrochemical sensors. We have demonstrated prototype amperometric oxygen sensors, nernstian potentiometric oxygen sensors that operate in high sulfur environments, and hydrocarbon and carbon monoxide sensing mixed potentials sensors. Many of these devices exhibit part per million sensitivities, response times on the order of seconds and excellent long-term stability.

  3. Application of active disturbance rejection control in bed temperature control of circulating fluidized bed boiler%自抗扰控制在循环流化床锅炉床温控制中的应用

    Institute of Scientific and Technical Information of China (English)

    马晓勇; 吴宏艳


    床温是循环流化床锅炉燃烧控制系统中的一个重要指标.它的稳定与否直接影响着锅炉的燃烧效率和污染物排放速率.在燃烧过程中,它具有时变性、大惯性和大滞后的特点.针对这一问题将自抗扰控制算法应用于循环流化床锅炉床温控制,并将仿真结果与PID控制方法的仿真结果进行了比较.研究表明:ADRC在超调量、调节时间上均优于常规PID方法,在各种工况以及增加外扰情况下,该自抗扰控制方案具有良好的鲁棒性和抗干扰能力,解决了该系统时变、大延迟的控制难点.%The bed temperature is an important parameter for a CFB (circulating fluidized bed) boiler. Wheather it is stable or not directly influences the boiler overall efficiency and the rate of pollutants emission. At the same time, the bed temperature control system is an uncertain system with large inertia and lag. Directing against the problems, the active disturbance rejection control (ADRC) was used to bed temperature control in a circulating fluidized bed boiler ( CFBB). The simulation results were compared with those obtained by using PID control method. It was found that the overshooting and regulation time duration of the ADRC are superior to those of the convention PID method under various operating conditions and with an increase of disturbance from the outside, the ADRC presents a good robustness and disturbance-resistant capability, thus solved the difficulties in controlling the time variation and long time delay of the system.

  4. High efficiency chlorine removal from polyvinyl chloride (PVC) pyrolysis with a gas-liquid fluidized bed reactor. (United States)

    Yuan, G; Chen, D; Yin, L; Wang, Z; Zhao, L; Wang, J Y


    In this research a gas-liquid fluidized bed reactor was developed for removing chlorine (Cl) from polyvinyl chloride (PVC) to favor its pyrolysis treatment. In order to efficiently remove Cl within a limited time before extensive generation of hydrocarbon products, the gas-liquid fluidized bed reactor was running at 280-320 °C, where hot N2 was used as fluidizing gas to fluidize the molten polymer, letting the molten polymer contact well with N2 to release Cl in form of HCl. Experimental results showed that dechlorination efficiency is mainly temperature dependent and 300 °C is a proper reaction temperature for efficient dechlorination within a limited time duration and for prevention of extensive pyrolysis; under this temperature 99.5% of Cl removal efficiency can be obtained within reaction time around 1 min after melting is completed as the flow rate of N2 gas was set around 0.47-0.85 Nm(3) kg(-1) for the molten PVC. Larger N2 flow rate and additives in PVC would enhance HCl release but did not change the final dechlorination efficiency; and excessive N2 flow rate should be avoided for prevention of polymer entrainment. HCl is emitted from PVC granules or scraps at the mean time they started to melt and the melting stage should be taken into consideration when design the gas-liquid fluidized bed reactor for dechlorination.

  5. Effect of Distributor Design on Gas-Liquid Distribution in Monolithic Bed at High Gas/Liquid Ratios

    Institute of Scientific and Technical Information of China (English)

    周媛; AL-DAHHAN Muthanna; DUDUKOVIC Milorad; 刘辉


    Experiments were carried out to investigate the liquid flow distribution at high gas/liquid ratios in a cold model monolith bed of a 0.048 m diameter with 62 cells per cm2.Three types of distributor for the liquid distribu-tion were used to evaluate their distribution performance.Local liquid saturation in individual channels was meas-ured using 16 single-point optical fiber probes mounted inside the channels.The results indicate that 1) The optical fiber probe technique can measure phase distribution in the monolith bed;2) Liquid saturation distribution along the radial direction of the monolith bed is not uniform and the extent of non-uniformity depends on the distributor de-sign and phase velocities;and 3) The tube array distributor provides superior liquid distribution performance over the showerhead and nozzle distributors.

  6. High temperature internal friction measurements of 3YTZP zirconia polycrystals. High temperature background and creep


    Simas, P.; Castillo-Rodríguez, Miguel; Nó, M. L.; De-Bernardi, S.; Gómez-García, D.; Domínguez-Rodríguez, Alejandro; San Juan, J.


    This work focuses on the high-temperature mechanic properties of a 3 mol % yttria zirconia polycrystals (3YTZP), fabricated by hot-pressureless sintering. Systematic measurements of mechanical loss as a function of temperature and frequency were performed. An analytical method, based on the generalised Maxwell rheological model, has been used to analyse the high temperature internal friction background (HTB). This method has been previously applied to intermetallic compounds...

  7. Effect of process temperature on morphology of CNTs grown in a vertically fluidized bed reactor with Fe{sub 2}O{sub 3}/Al{sub 2}O{sub 3} catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Shukrullah, Shazia, E-mail:; Mohamed, Norani Muti, E-mail:; Shaharun, Maizatul Shima, E-mail: [Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 31750 Tronoh, Perak (Malaysia)


    Carbon nanotubes (CNTs) are one of the most researched materials due to their exceptional mechanical and electrical properties. Among the various techniques, catalytic chemical vapor deposition in a fluidized bed reactor is the most promising technique for bulk production of CNTs. To meet the demand of good quality along with the bulk production of CNTs, the effect of reaction temperature on the micro structures, morphology, diameter, quality and quantity of CNTs was investigated in these studies. CNTs were synthesized at process temperature ranging from 700-850°C by catalytic decomposition of C{sub 2}H{sub 4} on Fe{sub 2}O{sub 3}/Al{sub 2}O{sub 3} catalyst a vertical fluidized bed reactor. The microstructures of the grown CNTs at different reaction temperatures were investigated by using scanning electron microscope. The results of this study depicted a positive correlation between the average diameter of CNTs and reaction temperature. Narrow diameters (35∼40 nm) of CNTs with fewer defects were found at the low and mild temperatures, in particular 800°C. At this temperature, a dynamic equilibrium between the rate of C{sub 2}H{sub 4} decomposition and CNTs quantity was found due to maximum carbon diffusion over catalyst. The CNTs produced with Fe{sub 2}O{sub 3}/Al{sub 2}O{sub 3} catalyst wer e also exhibiting high quality with relatively small mean outer diameter and fewer surface defects.

  8. High temperature superconductors applications in telecommunications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, A.A.; Li, J.; Zhang, M.F. [Prairie View A& M Univ., Texas (United States)


    The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T{sub c} superconductors.

  9. High temperature superconductors applications in telecommunications (United States)

    Kumar, A. Anil; Li, Jiang; Zhang, Ming Fang


    The purpose of this paper is twofold: (1) to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and (2) to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices - obvious advantages versus practical difficulties - needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models - a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B) - shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance - conductivity, surface resistance and attenuation constant - will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T

  10. Bed disturbance via foraging fish increases bedload transport during subsequent high flows and is controlled by fish size and species (United States)

    Pledger, A. G.; Rice, S. P.; Millett, J.


    Benthic foraging by fish can modify the nature and rates of fine sediment accrual and the structure and topography of coarse-grained fluvial substrates, with the potential to alter bed material characteristics, particle entrainment thresholds, and bedload transport fluxes. However, knowledge of what controls the nature, extent, and intensity of benthic foraging and the consequent influence of these controls on geomorphic impact remain rudimentary. An ex-situ experiment utilising Barbel Barbus barbus and Chub Leuciscus cephalus extended previous work by considering the role of fish size and species as controls of sediment disturbance by foraging and the implications for bed material characteristics and bedload transport. In a laboratory flume, changes in bed microtopography and structure were measured when a water-worked bed of 5.6-22.6 mm gravels was exposed to four size classes of Barbel (4-5″, 5-6″, 6-8″, 8-10″ in length) and a single size class of Chub (8-10″). In line with other studies that have investigated animal size as a control of zoogeomorphic agency, increasing the size of Barbel had a significant effect on measured disturbance and transport metrics. Specifically, the area of disturbed substrate, foraging depth, and the fish's impact on microtopographic roughness and imbrication all increased as a function of fish size. In a comparison of the foraging effects of like-sized Barbel and Chub, 8-10″ in length, Barbel foraged a larger area of the test bed and had a greater impact on microtopographic roughness and sediment structure. Relative to water-worked beds that were not foraged, bed conditioning by both species was associated with increased bedload transport during the subsequent application of high flows. However, the bedload flux after foraging by Barbel, which is a specialist benthivore, was 150% higher than that following foraging by Chub, which feed opportunistically from the bed, and the total transported mass of sediment was 98

  11. High-temperature sapphire optical sensor fiber coatings (United States)

    Desu, Seshu B.; Claus, Richard O.; Raheem, Ruby; Murphy, Kent A.


    Advanced coal-fired power generation systems, such as pressurized fluidized-bed combustors and integrated gasifier-combined cycles, may provide cost effective future alternatives for power generation, improve our utilization of coal resources, and decrease our dependence upon oil and gas. When coal is burned or converted to combustible gas to produce energy, mineral matter and chemical compounds are released as solid and gaseous contaminants. The control of contaminants is mandatory to prevent pollution as well as degradation of equipment in advanced power generation. To eliminate the need for expensive heat recovery equipment and to avoid efficiency losses it is desirable to develop a technology capable of cleaning the hot gas. For this technology the removal of particle contaminants is of major concern. Several prototype high temperature particle filters have been developed, including ceramic candle filters, ceramic bag filters, and ceramic cross-flow (CXF) filters. Ceramic candle filters are rigid, tubular filters typically made by bonding silicon carbide or alumina-silica grains with clay bonding materials and perhaps including alumina-silica fibers. Ceramic bag filters are flexible and are made from long ceramic fibers such as alumina-silica. CXF filters are rigid filters made of stacks of individual lamina through which the dirty and clean gases flow in cross-wise directions. CXF filters are advantageous for hot gas cleanup applications since they offer a large effective filter surface per unit volume. The relatively small size of the filters allows the pressurized vessel containing them to be small, thus reducing potential equipment costs. CXF filters have shown promise but have experienced degradation at normal operational high temperatures (close to 1173K) and high pressures (up to 24 bars). Observed degradation modes include delamination of the individual tile layers, cracking at either the tile-torid interface or at the mounting flange, or plugging of

  12. Comments on theories of high temperature superconductivity

    Directory of Open Access Journals (Sweden)

    T. M. Rice


    Full Text Available   The recently discovered MgB2 superconductors have a record transition temperature for a BCS superconductor due to the high vibration frequencies associated with its light elements. The transition temperatures in the cuprate family of superconductors are much higher but these do not fit the BCS paradigm. The most promising microscopic origin for their many anomalous properties lies in magnetic pairing described by the RVB (Resonant Valence Bond ansatz. However a comprehensive theoretical description of the key anomalous properties of the cuprates remains to be an open challenge.

  13. Optically transparent high temperature shape memory polymers. (United States)

    Xiao, Xinli; Qiu, Xueying; Kong, Deyan; Zhang, Wenbo; Liu, Yanju; Leng, Jinsong


    Optically transparent shape memory polymers (SMPs) have potential in advanced optoelectronic and other common shape memory applications, and here optically transparent shape memory polyimide is reported for the first time. The polyimide possesses a glass transition temperature (Tg) of 171 °C, higher than the Tg of other transparent SMPs reported, and the influence of molecular structure on Tg is discussed. The 120 μm thick polyimide film exhibits transmittance higher than 81% in 450-800 nm, and the possible mechanism of its high transparency is analyzed, which will benefit further research on other transparent high temperature SMPs. The transparent polyimide showed excellent thermomechanical properties and shape memory performances, and retained high optical transparency after many shape memory cycles.

  14. The metallurgy of high temperature alloys (United States)

    Tien, J. K.; Purushothaman, S.


    Nickel-base, cobalt-base, and high nickel and chromium iron-base alloys are dissected, and their microstructural and chemical components are assessed with respect to the various functions expected of high temperature structural materials. These functions include the maintenance of mechanical integrity over the strain-rate spectrum from creep resistance through fatigue crack growth resistance, and such alloy stability expectations as microstructural coarsening resistance, phase instability resistance and oxidation and corrosion resistance. Special attention will be given to the perennial conflict and trade-off between strength, ductility and corrosion and oxidation resistance. The newest developments in the constitution of high temperature alloys will also be discussed, including aspects relating to materials conservation.


    Energy Technology Data Exchange (ETDEWEB)

    Jantzen, C; Michael Williams, M


    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  16. Preliminary study of a radiantly heated fluidized bed for the production of high purity silicon (United States)

    Levenspiel, O.; Larson, M.; Zhang, G. T.; Ouyang, F.


    The preparation of very pure silicon from silane (SIH4) using radiant heating of the hot silicon particles of a fluidized bed is discussed. The fraction of electrical energy supplied to the heater which is actually absorbed by the particles and the heat transfer coefficient between the hot bed and the cool distributor plate were investigated. The experimental design is presented and the results of the study are summarized.

  17. High temperature sensors for exhaust diagnosis

    Energy Technology Data Exchange (ETDEWEB)

    Svenningstorp, Henrik


    One of the largest problems that we will have to deal with on this planet this millennium is to stop the pollution of our environment. In many of the ongoing works to reduce toxic emissions, gas sensors capable of enduring rough environments and high temperatures, would be a great tool. The different applications where sensors like this would be useful vary between everything from online measurement in the paper industry and food industry to measurement in the exhaust pipe of a car. In my project we have tested Schottky diodes and MlSiCFET sensor as gas sensors operating at high temperatures. The measurement condition in the exhaust pipe of a car is extremely tough, not only is the temperature high and the different gases quite harmful, there are also a lot of particles that can affect the sensors in an undesirable way. In my project we have been testing Schottky diodes and MlSiCFET sensors based on SiC as high temperature sensors, both in the laboratory with simulated exhaust and after a real engine. In this thesis we conclude that these sensors can work in the hostile environment of an engines exhaust. It is shown that when measuring in a gas mixture with a fixed I below one, where the I-value is controlled by the O{sub 2} concentration, a sensor with a catalytic gate metal as sensitive material respond more to the increased O{sub 2} concentration than the increased HC concentration when varying the two correspondingly. A number of different sensors have been tested in simulated exhaust towards NO{sub x}. It was shown that resistivity changes in the thin gate metal influenced the gas response. Tests have been performed where sensors were a part of a SCR system with promising results concerning NH{sub 3} sensitivity. With a working temperature of 300 deg C there is no contamination of the metal surface.

  18. Highly enantioselective esterification of racemic ibuprofen in a packed bed reactor using immobilised Rhizomucor miehei lipase. (United States)

    Sánchez; Valero; Lafuente; Solà


    A systematic study of the enantioselective resolution of ibuprofen by commercial Rhizomucor miehei lipase (Lipozyme(R) IM20) has been carried out using isooctane as solvent and butanol as esterificating agent. The main variables controlling the process (temperature, ibuprofen concentration, ratio butanol:ibuprofen) have been studied using an orthogonal full factorial experimental design, in which the selected objective function was enantioselectivity. This strategy has resulted in a polynomial function that describes the process. By optimizing this function, optimal conditions for carrying out the esterification of racemic ibuprofen have been determined. Under these conditions, enantiomeric excess and total conversion values were 93.8% and 49.9%, respectively, and the enantioselectivity was 113 after 112 h of reaction. These conditions have been considered in the design of a continuous reactor to scale up the process. The esterification of ibuprofen was properly described by pseudo first-order kinetics. Thus, a packed bed reactor operating as a plug-flow reactor (PFR) is the most appropriate in terms of minimizing the residence time compared with a continuous stirred tank reactor (CSTR) to achieve the same final conversion. This reactor shows a similar behavior in terms of enantioselectivity, enantiomeric excess, and conversion when compared with batch reactors. A residence-time distribution (RTD) shows that the flow model is essentially a plug flow with a slight nonsymmetrical axial dispersion (Peclet number = 43), which was also corroborated by the model of CSTR in series. The stability of the system (up to 100 h) and the possibility of reutilization of the enzyme (up to four times) lead to consider this reactor as a suitable configuration for scale up of the process.

  19. Quench in high temperature superconductor magnets

    CERN Document Server

    Schwartz, J


    High field superconducting magnets using high temperature superconductors are being developed for high energy physics, nuclear magnetic resonance and energy storage applications. Although the conductor technology has progressed to the point where such large magnets can be readily envisioned, quench protection remains a key challenge. It is well-established that quench propagation in HTS magnets is very slow and this brings new challenges that must be addressed. In this paper, these challenges are discussed and potential solutions, driven by new technologies such as optical fiber based sensors and thermally conducting electrical insulators, are reviewed.

  20. High Temperature Polymer Electrolyte Fuel Cells

    DEFF Research Database (Denmark)

    Fleige, Michael

    This thesis presents the development and application of electrochemical half-cell setups to study the catalytic reactions taking place in High Temperature Polymer Electrolyte Fuel Cells (HTPEM-FCs): (i) a pressurized electrochemical cell with integrated magnetically coupled rotating disk electrode...... (RDE) and (ii) a gas diffusion electrode (GDE) setup designed for experiments in conc. H3PO4. The pressurized cell is demonstrated by tests on polycrystalline platinum electrodes up to 150 ºC. Functionality of the RDE system is proved studying the oxygen reduction reaction (ORR) at temperatures up...... to 140 ºC and oxygen pressures up to ~100 bar at room temperature. The GDE cell is successfully tested at 130 ºC by means of direct oxidation of methanol and ethanol, respectively. In the second part of the thesis, the emphasis is put on the ORR in H3PO4 with particular focus on the mass transport...

  1. Thermoelectric properties by high temperature annealing (United States)

    Ren, Zhifeng (Inventor); Chen, Gang (Inventor); Kumar, Shankar (Inventor); Lee, Hohyun (Inventor)


    The present invention generally provides methods of improving thermoelectric properties of alloys by subjecting them to one or more high temperature annealing steps, performed at temperatures at which the alloys exhibit a mixed solid/liquid phase, followed by cooling steps. For example, in one aspect, such a method of the invention can include subjecting an alloy sample to a temperature that is sufficiently elevated to cause partial melting of at least some of the grains. The sample can then be cooled so as to solidify the melted grain portions such that each solidified grain portion exhibits an average chemical composition, characterized by a relative concentration of elements forming the alloy, that is different than that of the remainder of the grain.

  2. Temperature effects on nitrogen cycling and nitrate removal-production efficiency in bed form-induced hyporheic zones (United States)

    Zheng, Lizhi; Cardenas, M. Bayani; Wang, Lichun


    Hyporheic flow in aquatic sediment controls solute and heat transport thereby mediating the fate of nutrients and contaminants, dissolved oxygen, and temperature in the hyporheic zone (HZ). We conducted a series of numerical simulations of hyporheic processes within a dune with different uniform temperatures, coupling turbulent open channel fluid flow, porous fluid flow, and reactive solute transport to study the temperature dependence of nitrogen source/sink functionality and its efficiency. Two cases were considered: a polluted stream and a pristine stream. Sensitivity analysis was performed to investigate the influence of stream water [NO3-]/[NH4+]. The simulations showed that in both cases warmer temperatures resulted in shallower denitrification zones and oxic-anoxic zone boundaries, but the trend of net denitrification rate and nitrate removal or production efficiency of the HZ for these two cases differed. For both cases, at high [NO3-]/[NH4+], the HZ functioned as a NO3- sink with the nitrate removal efficiency increasing with temperature. But at low [NO3-]/[NH4+] for the polluted stream, the HZ is a NO3- sink at low temperature but then switches to a NO3- source at warmer temperatures. For the pristine stream case, the HZ was always a NO3- source, with the NO3- production efficiency increasing monotonically with temperature. In addition, although the interfacial fluid flux expectedly increased with increasing temperature due to decreasing fluid viscosity, the total nitrate flux into the HZ did not follow this trend. This is because when HZ nitrification is high, uniformly elevated [NO3-] lowers dispersive fluxes into the HZ. We found that there are numerous confounding and interacting factors that combined to lead to the final temperature dependence of N transformation reaction rates. Although the temperature effect on the rate constant can be considered as the dominant factor, simply using the Arrhenius equation to predict the reaction rate would lead to


    Energy Technology Data Exchange (ETDEWEB)

    Duignan, M; Charles Nash, C; Timothy Punch, T


    A principal role of the DOE Savannah River Site is to safely dispose of a large volume of liquid nuclear waste held in many storage tanks. An in-tank ion exchange unit is being considered for cesium removal to accelerate waste processing. This unit is planned to have a relatively high bed height to diameter ratio (10:1). Complicating the design is the need to cool the ion exchange media; therefore, the ion exchange column will have a central cooling core making the flow path annular. To separate cesium from waste the media being considered is made of resorcinol formaldehyde resin deposited on spherical plastic beads and is a substitute for a previously tested resin made of crystalline silicotitanate. This spherical media not only has an advantage of being mechanically robust, but, unlike its predecessor, it is also reusable, that is, loaded cesium can be removed through elution and regeneration. Resin regeneration leads to more efficient operation and less spent resin waste, but its hydraulic performance in the planned ion exchange column was unknown. Moreover, the recycling process of this spherical resorcinol formaldehyde causes its volume to significantly shrink and swell. To determine the spherical media's hydraulic demand a linearly scaled column was designed and tested. The waste simulant used was prototypic of the wastes' viscosity and density. This paper discusses the hydraulic performance of the media that will be used to assist in the design of a full-scale unit.

  4. Pulse Radiolysis at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Christensen, H.; Sehested, Knud


    A set-up enabling pulse radiolysis measurements at high temperatures (up to 320°C) and high pressures (up to 140 bar) has been constructed in collaboration between Risö National Laboratory and Studsvik Energiteknik. The cell has been used for experiments with aqueous solutions with the purpose...

  5. Electrochemical high-temperature gas sensors (United States)

    Saruhan, B.; Stranzenbach, M.; Yüce, A.; Gönüllü, Y.


    Combustion produced common air pollutant, NOx associates with greenhouse effects. Its high temperature detection is essential for protection of nature. Component-integration capable high-temperature sensors enable the control of combustion products. The requirements are quantitative detection of total NOx and high selectivity at temperatures above 500°C. This study reports various approaches to detect NO and NO2 selectively under lean and humid conditions at temperatures from 300°C to 800°C. All tested electrochemical sensors were fabricated in planar design to enable componentintegration. We suggest first an impedance-metric gas sensor for total NOx-detection consisting of NiO- or NiCr2O4-SE and PYSZ-electrolyte. The electrolyte-layer is about 200μm thickness and constructed of quasi-single crystalline columns. The sensing-electrode (SE) is magnetron sputtered thin-layers of NiO or NiCr2O4. Sensor sensitivity for detection of total NOx has been measured by applying impedance analysis. The cross-sensitivity to other emission gases such as CO, CO2, CH4 and oxygen (5 vol.%) has been determined under 0-1000ppm NO. Sensor maintains its high sensitivity at temperatures up to 550°C and 600°C, depending on the sensing-electrode. NiO-SE yields better selectivity to NO in the presence of oxygen and have shorter response times comparing to NiCr2O4-SE. For higher temperature NO2-sensing capability, a resistive DC-sensor having Al-doped TiO2-sensing layers has been employed. Sensor-sensitivity towards NO2 and cross-sensitivity to CO has been determined in the presence of H2O at temperatures 600°C and 800°C. NO2 concentrations varying from 25 to 100ppm and CO concentrations from 25 to 75ppm can be detected. By nano-tubular structuring of TiO2, NO2 sensitivity of the sensor was increased.

  6. High temperature deformation of silicon steel

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Calvillo, Pablo, E-mail: [CTM - Technologic Centre, Materials Technology Area, Manresa, Cataluna (Spain); Department of Materials Science and Metallurgical Engineering, Universidad Politecnica de Cataluna, Barcelona (Spain); Houbaert, Yvan, E-mail: [Department of Materials Science and Engineering, University of Ghent (Belgium); Petrov, Roumen, E-mail: [Department of Materials Science and Engineering, University of Ghent (Belgium); Kestens, Leo, E-mail: [Department of Materials Science and Engineering, University of Ghent (Belgium); Colas, Rafael, E-mail: [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico)


    The microstructure and texture development during high temperature plane strain compression of 2% in weight silicon steel was studied. The tests were carried out at a constant strain rate of 5 s{sup -1} with reductions of 25, 35 and 75% at temperatures varying from 800 to 1100 Degree-Sign C. The changes in microstructure and texture were studied by means of scanning electron microscopy and electron backscattered diffraction. The microstructure close to the surface of the samples was equiaxed, which is attributed to the shear caused by friction, whereas that at the centre of the specimens was made of a mixture of elongated and fine equiaxed grains, the last ones attributed to the action of dynamic recovery followed by recrystallization. It was found that the volume fraction of these equiaxed grains augmented as reduction and temperature increased; a 0.7 volume fraction was accomplished with a 75% reduction at 1100 Degree-Sign C. The texture of the equiaxed and elongated grains was found to vary with the increase of deformation and temperature, as the {gamma}-fibre tends to disappear and the {alpha}-fibre to increase towards the higher temperature range. -- Highlights: Black-Right-Pointing-Pointer The plastic deformation of a silicon containing steel is studied by plane strain compression. Black-Right-Pointing-Pointer Equiaxed and elongated grains develop in different regions of the sample due to recrystallization. Black-Right-Pointing-Pointer Texture, by EBSD, is revealed to be similar in either type of grains.

  7. Energy storage via high temperature superconductivity (SMES)

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, R. [Tampere Univ. of Technology (Finland)


    The technology concerning high temperature superconductors (HTS) is matured to enabling different kind of prototype applications including SMES. Nowadays when speaking about HTS systems, attention is focused on the operating temperature of 20-30 K, where the critical current and flux density are fairly close to 4.2 K values. In addition by defining the ratio of the energy content of a novel HTS magnetic system and the required power to keep the system at the desired temperature, the optimum settles to the above mentioned temperature range. In the frame of these viewpoints a 5 kJ HTS SMES system has been designed and tested at Tampere University of Technology with a coil manufactured by American Superconductor (AMSC). The HTS magnet has inside and outside diameters of 252 mm and 317 mm, respectively and axial length of 66 mm. It operates at 160 A and carries a total of 160 kA-turns to store the required amount of energy. The effective magnetic inductance is 0.4 H and the peak axial field is 1.7 T. The magnet is cooled to the operating temperature of 20 K with a two stage Gifford-McMahon type cryocooler with a cooling power of 60 W at 77 K and 8 W at 20 K. The magnetic system has been demonstrated to compensate a short term loss of power of a sensitive consumer

  8. Adsorption behavior of pesticide methomyl on activated carbon in a high gravity rotating packed bed reactor. (United States)

    Chang, Chiung-Fen; Lee, Shu-Chi


    High gravity rotating packed bed (HGRPB) reactor possesses the property of high mass transfer rate, which is expected to promote the adsorption rate for the process. In this study, HGRPB has been applied on adsorption removal of methomyl from solution, adopting the adsorbent of activated carbon F400. The influence of operating parameters of HGRPB on mass transfer such as the rotating speed (N(R)), the flow rate of solution (F(L)) and initial concentration of methomyl (C(b0)) were examined. The traditionally internal mass transfer models combined with Freundlich isotherm were used to predict the surface and effective diffusion coefficients. In addition, the results have also been compared with those obtained from the traditional basket stirred batch reactor (BBR). The results showed that the larger values of N(R) and F(L) enhanced the effective intraparticle diffusion and provided more accessible adsorption sites so as to result in lower equilibrium concentration in HGRPB system when compared to SBR system. The results of adsorption kinetics demonstrated that surface and effective diffusions were both significantly greater in HGRPB system instead of BBR system. Furthermore, the values of Bi(S) also manifested less internal mass transfer resistance in HGRPB system. The contribution ratio (R(F)) of the surface to pore diffusion mass transport showed that the larger contribution resulted from the surface diffusion in HGRPB system. Therefore, the results reasonably led to the conclusion that when the HGRPB system applied on the adsorption of methomyl on F400, the lower equilibrium concentration and faster internal mass transfer can be obtained so as to highly possess great potential to match the gradually stricter environmental standard.

  9. High Temperature Phenomena in Shock Waves

    CERN Document Server


    The high temperatures generated in gases by shock waves give rise to physical and chemical phenomena such as molecular vibrational excitation, dissociation, ionization, chemical reactions and inherently related radiation. In continuum regime, these processes start from the wave front, so that generally the gaseous media behind shock waves may be in a thermodynamic and chemical non-equilibrium state. This book presents the state of knowledge of these phenomena. Thus, the thermodynamic properties of high temperature gases, including the plasma state are described, as well as the kinetics of the various chemical phenomena cited above. Numerous results of measurement and computation of vibrational relaxation times, dissociation and reaction rate constants are given, and various ionization and radiative mechanisms and processes are presented. The coupling between these different phenomena is taken into account as well as their interaction with the flow-field. Particular points such as the case of rarefied flows an...

  10. High temperature superconductors for magnetic suspension applications (United States)

    Mcmichael, C. K.; Cooley, R. S.; Chen, Q. Y.; Ma, K. B.; Lamb, M. A.; Meng, R. L.; Chu, C. W.; Chu, W. K.


    High temperature superconductors (HTS) hold the promise for applications in magnetic levitation bearings, vibration damping, and torque coupling. Traditional magnetic suspension systems require active feedback and vibration controls in which power consumption and low frequency vibration are among the major engineering concerns. HTS materials have been demonstrated to be an enabling approach towards such problems due to their flux trapping properties. In our laboratory at TCSUH, we have been conducting a series of experiments to explore various mechanical applications using HTS. We have constructed a 30 lb. model flywheel levitated by a hybrid superconducting magnetic bearing (HSMB). We are also developing a levitated and vibration-dampled platform for high precision instrumentation. These applications would be ideal for space usages where ambient temperature is adequate for HTS to operate properly under greatly reduced cryogenic requirements. We will give a general overview of these potential applications and discuss the operating principles of the HTS devices we have developed.

  11. High temperature superconductor materials and applications (United States)

    Doane, George B., III. (Editor); Banks, Curtis; Golben, John


    One of the areas concerned itself with the investigation of the phenomena involved in formulating and making in the laboratory new and better superconductor material with enhanced values of critical current and temperature. Of special interest were the chemistry, physical processes, and environment required to attain these enhanced desirable characteristics. The other area concerned itself with producing high temperature superconducting thin films by pulsed laser deposition techniques. Such films are potentially very useful in the detection of very low power signals. To perform this research high vacuum is required. In the course of this effort, older vacuum chambers were maintained and used. In addition, a new facility is being brought on line. This latter activity has been replete with the usual problems of bringing a new facility into service. Some of the problems are covered in the main body of this report.

  12. High temperature alloys: their exploitable potential

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, J.B.; Merz, M.; Nihoul, J.; Ward, J. (eds.) (Commission of the European Communities, Petten (Netherlands). Joint Nuclear Research Center; NET-TEAM, Garching (DE))


    This book is the proceedings of a conference dealing with fundamental and technical aspects of the applications of high temperature alloys. It is split into five sections which cover the opening session of the conference and four further sessions covering: the theoretical and practical limits for HT alloys; the potential for development in alloys and processing; engineering considerations; the future outlook. The different sessions each included a number of invited papers followed by a series of posters and were concluded by a presentation of a 'synthesis' by a session rapporteur and general discussion. This structure is retained in the proceedings, including the discussion points in those cases where the authors have provided written answers to the questions raised. This book will be of interest to metallurgists, materials scientists, physicists and research workers in high temperature materials.

  13. High Temperature Perforating System for Geothermal Applications

    Energy Technology Data Exchange (ETDEWEB)

    Smart, Moises E. [Schlumberger Technology Corporation, Sugar Land, TX (United States)


    The objective of this project is to develop a perforating system consisting of all the explosive components and hardware, capable of reliable performance in high temperatures geothermal wells (>200 ºC). In this light we will focused on engineering development of these components, characterization of the explosive raw powder and developing the internal infrastructure to increase the production of the explosive from laboratory scale to industrial scale.

  14. Technological evolution of high temperature superconductors


    White, Jordan R.


    Approved for public release; distribution is unlimited High temperature superconducting (HTS) cables are currently being used in the commercial energy industry primarily for demonstration purposes and to evaluate the feasibility of large-scale implementation into the electric grid. While still in the evaluation stage, the U.S. Navy is finding the test results promising and is investigating its potential use for future electric ships to supply power to electric propulsion motors and possibl...

  15. High Temperature Superconducting Maglev Measurement System


    Wang, Jia-Su; Wang, Su-Yu


    Three high temperature superconducting (HTS) Maglev measurement systems were successfully developed in the Applied Superconductivity Laboratory (ASCLab) of Southwest Jiaotong University, P. R. China. These systems include liquid nitrogen vessel, Permanent Magnet Guideway (PMG), data collection and processing, mechanical drive and Autocontrol features. This chapter described the three different measuring systems along with their theory of operations and workflow. The SCML-01 HTS Maglev measure...

  16. Development of High-Temperature Strain Gages. (United States)


    lengths the article is either dipped in a slip (finely divided tend to require a support for the grid, while shorter coating material suspended in a...liquid) or the lengths require too many loops to achieve the slip is sprayed onto the article , followed in both cases by high-temperature fusion. An...Electrochemistry. Electrical Instruments. Magnetic Measurements. Dielectrics. Metrology. Photometry and Colorimetry. Refractometry . Photographic Research

  17. Intermetallic-based high-temperature materials

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.


    The intermetallic-based alloys for high-temperature applications are introduced. General characteristics of intermetallics are followed by identification of nickel and iron aluminides as the most practical alloys for commercial applications. An overview of the alloy compositions, melting processes, and mechanical properties for nickel and iron aluminizes are presented. The current applications and commercial producers of nickel and iron aluminides are given. A brief description of the future prospects of intermetallic-based alloys is also given.

  18. Intermetallic-Based High-Temperature Materials

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.


    The intermetallic-based alloys for high-temperature applications are introduced. General characteristics of intermetallics are followed by identification of nickel and iron aluminides as the most practical alloys for commercial applications. An overview of the alloy compositions, melting processes, and mechanical properties for nickel and iron aluminizes are presented. The current applications and commercial producers of nickel and iron aluminizes are given. A brief description of the future prospects of intermetallic-based alloys is also given.

  19. Hydrogen dominant metallic alloys: high temperature superconductors? (United States)

    Ashcroft, N W


    The arguments suggesting that metallic hydrogen, either as a monatomic or paired metal, should be a candidate for high temperature superconductivity are shown to apply with comparable weight to alloys of metallic hydrogen where hydrogen is a dominant constituent, for example, in the dense group IVa hydrides. The attainment of metallic states should be well within current capabilities of diamond anvil cells, but at pressures considerably lower than may be necessary for hydrogen.

  20. On quark number susceptibilities at high temperatures

    CERN Document Server

    Bazavov, A; Hegde, P; Karsch, F; Miao, C; Mukherjee, Swagato; Petreczky, P; Schmidt, C; Velytsky, A


    We calculated second and fourth order quark number susceptibilities for 2+1 flavor QCD in the high temperature region using two improved staggered fermion formulations. The calculations are performed at several lattice spacing and we show that in the continuum limit the two formulations give consistent results. We compare our continuum extrapolated results on quark number susceptibilities with recent weak coupling calculations, and find that these cannot simultaneously explain the lattice results for second and fourth order quark number susceptibilities.

  1. High temperature mechanical properties of iron aluminides

    Directory of Open Access Journals (Sweden)

    Morris, D. G.


    Full Text Available Considerable attention has been given to the iron aluminide family of intermetallics over the past years since they offer considerable potential as engineering materials for intermediate to high temperature applications, particularly in cases where extreme oxidation or corrosion resistance is required. Despite efforts at alloy development, however, high temperature strength remains low and creep resistance poor. Reasons for the poor high-temperature strength of iron aluminides will be discussed, based on the ordered crystal structure, the dislocation structure found in the material, and the mechanisms of dislocation pinning operating. Alternative ways of improving high temperature strength by microstructural modification and the inclusion of second phase particles will also be considered.

    Durante los últimos años se ha prestado mucha atención a la familia de intermetálicos Fe-Al, puesto que estos constituyen un considerable potencial como materiales de ingeniería en aplicaciones a temperaturas intermedias o altas, sobre todo en casos donde se necesita alta resistencia a la oxidación o corrosión. A pesar del considerable esfuerzo desarrollado para obtener aleaciones con mejores propiedades, su resistencia mecánica a alta temperatura no es muy elevada. Se discutirán los aspectos que contribuyen a la baja resistencia mecánica a temperatura elevada en función de la estructura de dislocaciones y los mecanismos de anclaje que operan en este intermetálico. Se considerarán, también, maneras alternativas para mejorar la resistencia a temperatura elevada mediante la modificación de la microestructura y la incorporación de partículas de segunda fase.

  2. The effect of temperature and flow rate on the clarification of the aqueous stevia-extract in a fixed-bed column with zeolites

    Directory of Open Access Journals (Sweden)

    Mantovaneli I. C. C.


    Full Text Available Stevia is being used as a sweetener due to its low calorific value and its taste, which is very similar to that of sucrose. After extraction from dried leaves, stevia extract is dark in colour so needs to be clarified for better acceptance by consumers. Adsorption is one of the most important processes in this clarification. In this work the clarification of extract stevia extract in fixed-bed columns with calcium zeolites was studied. Two temperatures (10ºC and 30ºC and six different flow rates (2, 5, 9, 12, 16 and 19 mL/min were studied. The results showed that the mass-transfer coeffcient increases with an increase in flow rate and the length of unused bed reaches a maximum at 9 mL/min for both temperatures. The fit of the Thomas model with the breakthrough data was not very good.

  3. On-line temperature control of fluidized bed incinerator using fuzzy algorithm; Fuzzu seigyo donyu ni yoru ryudosogata shokyakuro unten no jidoka

    Energy Technology Data Exchange (ETDEWEB)

    Okayasu, S.; Kuratani, T.; Imai, H. [Ajinomoto Co. Inc., Tokyo (Japan)


    Automatic control of incinerators for their stable operation has been desired for the preservation of the environment in the factory. An on-line fuzzy control system has been successfully introduced for temperature control of the fluidized bed of incinerator for industrial wastes. In this case, manual control can be applied to the plant instead of a PID control system, because of the complexity of the waste materials and the large delay in detection of the temperature change in the fluidized bed sand. On the basis of analyzing the dynamic performance of the process and the know-how of skilled operators, membership functions and fuzzy control rules are selected, then determined carefully for the system. Introduction of the system resulted in almost the same performance as manual control. Subsequently the operators are freed from manual operation in the control room for an hour. 6 refs., 5 figs., 4 tabs.

  4. Current trends in high temperature design

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, D.L. (Illinois Univ., Urbana, IL (United States). Dept. of Mechanical Engineering)


    A review of high temperature design guidelines has been carried out in preparation for designing a solar storage module for the Freedom Spacelab. Three major guidelines, N47, R5 and RCC-MR form the basis of the survey. The main issues with current, mature design in the power industry appear to be adequately covered by these guidelines. A significant finding is that long established models of material damage have survived the test of time very well. A new design regime referred to as Very High Temperature Design (VHTD) is identified. The characteristics of this regime are changing material properties which require some changes in philosophy in drafting of future codes, particularly in regard to definitions of yield strengths and other design allowables. Finally, there is some discussion of the more general use of the stress/strain plane, e.g. isochronous curves, for representation of very complex material constitutive behaviour. A concept called the 'Relaxation Locus', which summarizes essential local constrained component behavior, is introduced and its application to high temperature design problems is discussed briefly. (author).

  5. High temperature inorganic membranes for separating hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Fain, D.E.; Roettger, G.E. [Oak Ridge K-25 Site, TN (United States)


    Effort has continued to accumulate data on the transport of gases over the temperature range from room temperature to 275{degrees}C with inorganic membranes having a range of pore radii from approximately 0.25 nm to 3 mn. An experimental alumina membrane having an estimated mean pore radius of 0.25 nm has been fabricated and tested. Extensive testing of this membrane indicated that the separation factor for helium and carbon tetrafluoride at 250{degrees}C was 59 and the extrapolated high temperature separation factor was 1,193. For safety reasons, earlier flow measurements concentrated on helium, carbon dioxide, and carbon tetrafluoride. New data have been acquired with hydrogen to verify the agreement with the other gases. During the measurements with hydrogen, it was noted that a considerable amount of moisture was present in the test gas. The source of this moisture and its effect on permeance was examined. Improvements were implemented to the flow test system to minimize the water content of the hydrogen test gas, and subsequent flow measurements have shown excellent results with hydrogen. The extrapolation of separation factors as a function of temperature continues to show promise as a means of using the hard sphere model to determine the pore size of membranes. The temperature dependence of helium transport through membranes appears to be considerably greater than other gases for the smallest pore sizes. The effort to extend temperature dependence to the hard sphere model continues to be delayed, primarily because of a lack of adequate adsorption data.

  6. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed only electromagnets. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  7. The NDT methods under high temperature service environment

    Directory of Open Access Journals (Sweden)

    Zhang Zhen-guo


    Full Text Available Concerning the detective requirement of the equipment under high temperature running status, this paper summarizes the technical characteristics and related applications of several non-destructive testing methods(NDT, such as thermal infrared imaging technology in high temperature, ultrasonic testing technique in high temperature, pulsed eddy current technology in high temperature and magnetic powder flaw detection technology in high temperature, penetration testing technique in high temperature and indirect visual detection in high temperature and on-line monitoring system in high temperature.

  8. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed electromagnets only. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  9. Intensification of interfacial mass, heat & momentum transfer in high-G fluidized beds in vortex chambers : experimental & theoretical study of potential applications


    Eliaers, Philippe


    Vortex chambers can be used for the generation of rotating fluidized beds. High-G operation allows eliminating many of the limitations faced in conventional fluidized beds. In particular, interfacial transfer of mass, heat and momentum can be significantly intensified. This opens perspectives for increasing the efficiency of some existing fluidized bed processes, but also for developing novel processing routes. Two processes were studied in this context: 1. Biomass drying is frequently carrie...

  10. Precipitation Hardenable High Temperature Shape Memory Alloy (United States)

    Noebe, Ronald Dean (Inventor); Draper, Susan L. (Inventor); Nathal, Michael V. (Inventor); Crombie, Edwin A. (Inventor)


    A composition of the invention is a high temperature shape memory alloy having high work output, and is made from (Ni+Pt+Y),Ti(100-x) wherein x is present in a total amount of 49-55 atomic % Pt is present in a total amount of 10-30 atomic %, Y is one or more of Au, Pd. and Cu and is present in a total amount of 0 to 10 atomic %. The alloy has a matrix phase wherein the total concentration of Ni, Pt, and the one or more of Pd. Au, and Cu is greater than 50 atomic %.

  11. High Temperature Sensing Systems--Characteristics of Rechargeable Batteries at High Temperature--



     High temperature discharge characteristics were measured at 100℃ for commercial available Nickel Cadmium and Nickel Metal Hydride rechargeable batteries. A Nickel Cadmium battery has superior dis­charge characteristics than a Nickel Metal Hydride battery. A life cycle of rechargeable battery can be esti­mated by measuring an internal resistance of the battery during charge at room temperature.

  12. LHDAC setup for high temperature and high pressure studies

    Energy Technology Data Exchange (ETDEWEB)

    Patel, Nishant N., E-mail:; Meenakshi, S., E-mail:; Sharma, Surinder M., E-mail: [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)


    A ytterbium fibre laser (λ = 1.07 μm) based laser heated diamond anvil cell (LHDAC) facility has been recently set up at HP and SRPD, BARC for simultaneous high temperature and high pressure investigation of material properties. Synthesis of GaN was carried out at pressure of ∼9 GPa and temperature of ∼1925 K in a Mao-Bell type diamond anvil cell (DAC) using the LHDAC facility. The retrieved sample has been characterized using our laboratory based micro Raman setup.

  13. Filtration and dust cake experiment by ceramic candle filter in high temperature conditions

    Energy Technology Data Exchange (ETDEWEB)

    Chung, J.D.; Hwang, T.W.; Park, S.J. [Hoseo University, Asan (Republic of Korea)


    Particulate collection at high temperature and high pressure (HTHP) is important in an advanced coal power generation system not only to improve the thermal efficiency of the system, but also to prevent the gas turbine from erosion and to meet the emission limits of the effluent gas. The specifications for particulate collection in those systems such as Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) require absolutely high collection efficiency and reliability. Advanced cyclone, granular bed filter, electrostatic precipitator, and ceramic filter have been developed for particulate collection in the advanced coal power generation system. However, rigid ceramic filters and granular bed filters among them show the best potential. The problems experienced of these systems on performance, materials, and mechanical design were investigated. Ceramic candle filters have the best potential for IGCC at this moment because they have nearly the highest efficiency compared with other filtering systems and have accumulated many reliable design data from many field experiences. The purpose of this study was to investigate the efficiency of ceramic filters and stability of material against high temperature and longterm operation condition by applying fly ash on the surface of the filter and relation of pressure drop and dust cake thickness. Experimental conditions were 50 hours at 450{sup o}C, 650{sup o}C and 850{sup o}C.

  14. Process heat cogeneration using a high temperature reactor

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Gustavo, E-mail: [Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, Ocoyoacac, Edo. De Mexico 52750 (Mexico); Instituto Politécnico Nacional, Unidad Profesional Adolfo Lopez Mateos, Ed. 9, Lindavista, D.F. 07300 (Mexico); Ramirez, Ramon [Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, Ocoyoacac, Edo. De Mexico 52750 (Mexico); Valle, Edmundo del [Instituto Politécnico Nacional, Unidad Profesional Adolfo Lopez Mateos, Ed. 9, Lindavista, D.F. 07300 (Mexico); Castillo, Rogelio [Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, Ocoyoacac, Edo. De Mexico 52750 (Mexico)


    Highlights: • HTR feasibility for process heat cogeneration is assessed. • A cogeneration coupling for HTR is proposed and process heat cost is evaluated. • A CCGT process heat cogeneration set up is also assessed. • Technical comparison between both sources of cogeneration is performed. • Economical competitiveness of the HTR for process heat cogeneration is analyzed. - Abstract: High temperature nuclear reactors offer the possibility to generate process heat that could be used in the oil industry, particularly in refineries for gasoline production. These technologies are still under development and none of them has shown how this can be possible and what will be the penalty in electricity generation to have this additional product and if the cost of this subproduct will be competitive with other alternatives. The current study assesses the likeliness of generating process heat from Pebble Bed Modular Reactor to be used for a refinery showing different plant balances and alternatives to produce and use that process heat. An actual practical example is presented to demonstrate the cogeneration viability using the fact that the PBMR is a modular small reactor where the cycle configuration to transport the heat of the reactor to the process plant plays an important role in the cycle efficiency and in the plant economics. The results of this study show that the PBMR would be most competitive when capital discount rates are low (5%), carbon prices are high (>30 US$/ton), and competing natural gas prices are at least 8 US$/mmBTU.

  15. High Temperature Materials for Chemical Propulsion Applications (United States)

    Elam, Sandra; Hickman, Robert; O'Dell, Scott


    Radiation or passively cooled thrust chambers are used for a variety of chemical propulsion functions including apogee insertion, reaction control for launch vehicles, and primary propulsion for planetary spacecraft. The performance of these thrust chambers is limited by the operating temperature of available materials. Improved oxidation resistance and increased operating temperatures can be achieved with the use of thermal barrier coatings such as zirconium oxide (ZrO2) and hafnium oxide (HfO2). However, previous attempts to include these materials showed cracking and spalling of the oxide layer due to poor bonding. Current research at NASA's Marshall Space Flight Center (MSFC) has generated unique, high temperature material options for in-space thruster designs that are capable of up to 2500 C operating temperatures. The research is focused on fabrication technologies to form low cost Iridium,qF_.henium (Ir/Re) components with a ceramic hot wall created as an integral, functionally graded material (FGM). The goal of this effort is to further de?celop proven technologies for embedding a protective ceramic coating within the Ir/Re liner to form a robust functional gradient material. Current work includes the fabrication and testing of subscale samples to evaluate tensile, creep, thermal cyclic/oxidation, and thermophysical material properties. Larger test articles have also being fabricated and hot-fire tested to demonstrate the materials in prototype thrusters at 1O0 lbf thrust levels.

  16. A High-Performance Vacuum Cleaner for Bed Bug Sampling: A Useful Tool for Medical Entomology. (United States)

    Bérenger, Jean-Michel; Almeras, Lionel; Leulmi, Hamza; Parola, Philippe


    Arthropods can be captured by two modes: a passive mode using traps or an active mode mainly based on the use of mouth or powered aspirators. These apparatuses are useful tools for collecting large numbers of crawling, flying, resting, or jumping arthropod specimens, particularly small specimens, such as mosquitoes or sandflies, for laboratory experiments or breeding. Different aspirator models are used to collect various arthropod specimens. However, to our knowledge, no specific system is currently available for the reliable sampling of live bed bugs in the field. Thus, we described a new system based on a classic autonomous house aspirator that requires few modifications for the collecting bed bugs. The low weight and size of this apparatus is advantageous, and it provides for rapid and secure bed bug sampling for medical entomology purposes.

  17. Conformal Properties in High Temperature QCD

    CERN Document Server

    Ishikawa, K -I; Nakayama, Yu; Yoshie, T


    We investigate the properties of quarks and gluons above the chiral phase transition temperature $T_c,$ using the RG improved gauge action and the Wilson quark action with two degenerate quarks mainly on a $32^3\\times 16$ lattice. In the one-loop perturbation theory, the thermal ensemble is dominated by the gauge configurations with effectively $Z(3)$ center twisted boundary conditions, making the thermal expectation value of the spatial Polyakov loop take a non-trivial $Z(3)$ center. This is in agreement with our lattice simulation of high temperature QCD. We further observe that the temporal propagator of massless quarks at extremely high temperature $\\beta=100.0 \\, (T \\simeq10^{58} T_c)$ remarkably agrees with the temporal propagator of free quarks with the $Z(3)$ twisted boundary condition for $t/L_t \\geq 0.2$, but differs from that with the $Z(3)$ trivial boundary condition. As we increase the mass of quarks $m_q$, we find that the thermal ensemble continues to be dominated by the $Z(3)$ twisted gauge fi...

  18. The NASA high temperature superconductivity program (United States)

    Sokoloski, Martin M.; Romanofsky, Robert R.


    It has been recognized from the onset that high temperature superconductivity held great promise for major advances across a broad range of NASA interests. The current effort is organized around four key areas: communications and data, sensors and cryogenics, propulsion and power, and space materials technology. Recently, laser ablated YBa2Cu3O(7-x) films on LaAIO produced far superior RF characteristics when compared to metallic films on the same substrate. This achievement has enabled a number of unique microwave device applications, such as low insertion loss phase shifters and high Q filters. Melt texturing and melt quenched techniques are being used to produce bulk materials with optimized magnetic properties. These yttrium enriched materials possess enhanced flux pinning characteristics and will lead to prototype cryocooler bearings. Significant progress has also occurred in bolometer and current lead technology. Studies are being conducted to evaluate the effect of high temperature superconducting materials on the performance and life of high power magneto-plasma-dynamic thrusters. Extended studies were also performed to evaluate the benefit of superconducting magnetic energy storage for LEO space station, lunar and Mars mission applications. The project direction and level of effort of the program are also described.

  19. High Temperature Battery for Drilling Applications

    Energy Technology Data Exchange (ETDEWEB)

    Josip Caja


    In this project rechargeable cells based on the high temperature electrochemical system Na/beta''-alumina/S(IV) in AlCl3/NaCl were developed for application as an autonomous power source in oil/gas deep drilling wells. The cells operate in the temperature range from 150 C to 250 C. A prototype DD size cell was designed and built based on the results of finite element analysis and vibration testing. The cell consisted of stainless steel case serving as anode compartment with cathode compartment installed in it and a seal closing the cell. Critical element in cell design and fabrication was hermetically sealing the cell. The seal had to be leak tight, thermally and vibration stable and compatible with electrode materials. Cathode compartment was built of beta''-alumina tube which served as an electrolyte, separator and cathode compartment.

  20. Fast pyrolysis of biomass at high temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna

    content affected the char yield stronger than the heating rates and differences in the plant cell wall compounds between 600 and 3000K s-1. The heat treatment temperature affected more the herbaceous biomass char yield compared with wood. The differences in the char yield for particle size fractions...... pyrolysis at high temperatures plays a significant role in the overall combustion process since the biomass type, the reaction kinetics and heat transfer rates during pyrolysis influence the volatile gas release. The solid residue yield and its properties in suspension firing, including particle size...... to investigate the effects of operating parameters and biomass types on yields of char and soot, their chemistry and morphology as well as their reactivity using thermogravimetric analysis. The experimental study was focused on the influence of a wide range of operating parameters including heat treatment...

  1. Permanent magnets composed of high temperature superconductors (United States)

    Weinstein, Roy; Chen, In-Gann; Liu, Jay; Lau, Kwong


    A study of persistent, trapped magnetic field has been pursued with high-temperature superconducting (HTS) materials. The main effort is to study the feasibility of utilization of HTS to fabricate magnets for various devices. The trapped field, when not in saturation, is proportional to the applied field. Thus, it should be possible to replicate complicated field configurations with melt-textured YBa2Cu3O7 (MT-Y123) material, bypassing the need for HTS wires. Presently, materials have been developed from which magnets of 1.5 T, at 77 K, can be fabricated. Much higher field is available at lower operating temperature. Stability of a few percent per year is readily attainable. Results of studies on prototype motors and minimagnets are reported.

  2. High Temperature Resistant Exhaust Valve Spindle

    DEFF Research Database (Denmark)

    Bihlet, Uffe Ditlev

    the alloy development work, extensive microstructure quantification was performed, the results of which validated the predictive thermodynamical calculations. The heat treatment results showed that a relation exists between the solution treated microstructure and the mechanical properties. This lead......Transport by ship remains the most economical and environmentally friendly mode of transport with a very low weight specific CO2 footprint. Further increase of the fuel efficiency of large ships will results in a higher internal engine temperature. To allow this without compromising the reliability...... of the engine, new high temperature alloys are required for a specific engine component, the exhaust valve spindle. Two alloys are used for an exhaust valve spindle; one for the bottom of the spindle, and one for the spindle seat. Being placed in the exhaust gas stream, combustion products such as V2O5 and Na2...

  3. High-temperature insulation; Hochtemperatur-Waermeisolierung

    Energy Technology Data Exchange (ETDEWEB)

    Fuehres, M.


    For high-temperature insulations of industrial plants in the temperature range above 800 C preferably fibrous insulating materials are used. For this purpose ceramic fibres are more and more used. Apart from energy conservation possibilities up to 50% ceramic fibre products are characterized by a large field of the most different applications compared to conventional fire-resistant materials such as stone and compounds. The properties, production and the field of application are gone into in detail. (BWI) [Deutsch] In der Hochtemperaturisolierung industrieller Anlagen werden im Temperaturbereich oberhalb von 800 C bevorzugt faserfoermige Daemmstoffe eingesetzt. In zunehmendem Masse werden hierzu Keramikfasern eingesetzt. Neben den Einsparmoeglichkeiten im Energieverbrauch von bis zu 50% gegenueber konventionellen feuerfesten Werkstoffen wie Steinen und Massen zeichnen sich Keramikfaser-Produkte durch eine breite Palette vielfaeltigster Einsatzmoeglichkeiten aus. Es wird ausfuehrlich auf Eigenschaften, Herstellung und Einsatzmoeglichkeiten eingegangen. (BWI)

  4. Graphite thermal expansion reference for high temperature (United States)

    Gaal, P. S.


    The design requirements of the aerospace and high-temperature nuclear reactor industries necessitate reliable thermal expansion data for graphite and other carbonaceous materials. The feasibility of an acceptable reference for calibration of expansion measuring systems that operate in carbon-rich atmospheres at temperatures ranging to 2500 C is the prime subject of this work. Present-day graphite technology provides acceptable materials for stable, reproducible references, as reflected by some of the candidate materials. The repeatability for a single specimen in a given expansion measuring system was found to be plus or minus 1%, while the combined results of several tests made on a number of samples fell within a plus or minus 2.5% band.

  5. Creep resistant high temperature martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.


    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, copper, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around C.

  6. Variations in pore characteristics in high volatile bituminous coals: Implications for coal bed gas content (United States)

    Mastalerz, Maria; Drobniak, A.; Strapoc, D.; Solano-Acosta, W.; Rupp, J.


    The Seelyville Coal Member of the Linton Formation (Pennsylvanian) in Indiana was studied to: 1) understand variations in pore characteristics within a coal seam at a single location and compare these variations with changes occurring between the same coal at different locations, 2) elaborate on the influence of mineral-matter and maceral composition on mesopore and micropore characteristics, and 3) discuss implications of these variations for coal bed gas content. The coal is high volatile bituminous rank with R0 ranging from 0.57% to 0.60%. BET specific surface areas (determined by nitrogen adsorption) of the coals samples studied range from 1.8 to 22.9??m2/g, BJH adsorption mesopore volumes from 0.0041 to 0.0339??cm3/g, and micropore volumes (determined by carbon dioxide adsorption) from 0.0315 to 0.0540??cm3/g. The coals that had the largest specific surface areas and largest mesopore volumes occur at the shallowest depths, whereas the smallest values for these two parameters occur in the deepest coals. Micropore volumes, in contrast, are not depth-dependent. In the coal samples examined for this study, mineral-matter content influenced both specific surface area as well as mesopore and micropore volumes. It is especially clear in the case of micropores, where an increase in mineral-matter content parallels the decrease of micropore volume of the coal. No obvious relationships were observed between the total vitrinite content and pore characteristics but, after splitting vitrinite into individual macerals, we see that collotelinite influences both meso- and micropore volume positively, whereas collodetrinite contributes to the reduction of mesopore and micropore volumes. There are large variations in gas content within a single coal at a single location. Because of this variability, the entire thickness of the coal must be desorbed in order to determine gas content reliably and to accurately calculate the level of gas saturation. ?? 2008 Elsevier B.V. All

  7. High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Turnquist, Norman [GE Global Research, Munchen (Germany); Qi, Xuele [GE Global Research, Munchen (Germany); Raminosoa, Tsarafidy [GE Global Research, Munchen (Germany); Salas, Ken [GE Global Research, Munchen (Germany); Samudrala, Omprakash [GE Global Research, Munchen (Germany); Shah, Manoj [GE Global Research, Munchen (Germany); Van Dam, Jeremy [GE Global Research, Munchen (Germany); Yin, Weijun [GE Global Research, Munchen (Germany); Zia, Jalal [GE Global Research, Munchen (Germany)


    This report summarizes the progress made during the April 01, 2010 – December 30, 2013 period under Cooperative Agreement DE-EE0002752 for the U.S. Department of Energy entitled “High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems.” The overall objective of this program is to advance the technology for well fluids lifting systems to meet the foreseeable pressure, temperature, and longevity needs of the Enhanced Geothermal Systems (EGS) industry for the coming ten years. In this program, lifting system requirements for EGS wells were established via consultation with industry experts and site visits. A number of artificial lift technologies were evaluated with regard to their applicability to EGS applications; it was determined that a system based on electric submersible pump (ESP) technology was best suited to EGS. Technical barriers were identified and a component-level technology development program was undertaken to address each barrier, with the most challenging being the development of a power-dense, small diameter motor that can operate reliably in a 300°C environment for up to three years. Some of the targeted individual component technologies include permanent magnet motor construction, high-temperature insulation, dielectrics, bearings, seals, thrust washers, and pump impellers/diffusers. Advances were also made in thermal management of electric motors. In addition to the overall system design for a full-scale EGS application, a subscale prototype was designed and fabricated. Like the full-scale design, the subscale prototype features a novel “flow-through-the-bore” permanent magnet electric motor that combines the use of high temperature materials with an internal cooling scheme that limits peak internal temperatures to <330°C. While the full-scale high-volume multi-stage pump is designed to lift up to 80 kg/s of process water, the subscale prototype is based on a production design that can pump 20 kg/s and has been modified

  8. High temperature polymer electrolyte membrane fuel cell

    Institute of Scientific and Technical Information of China (English)

    K.Scott; M. Mamlouk


    One of the major issues limiting the introduction of polymer electrolyte membrane fuel cells (PEMFCs) is the low temperature of operation which makes platinum-based anode catalysts susceptible to poisoning by the trace amount of CO, inevitably present in reformed fuel. In order to alleviate the problem of CO poisoning and improve the power density of the cell, operating at temperature above 100 ℃ is preferred. Nafion(R) -type perfluorosulfonated polymers have been typically used for PEMFC. However, the conductivity of Nafion(R) -type polymers is not high enough to be used for fuel cell operations at higher temperature ( > 90 ℃) and atmospheric pressure because they dehydrate under these condition.An additional problem which faces the introduction of PEMFC technology is that of supplying or storing hydrogen for cell operation,especially for vehicular applications. Consequently the use of alternative fuels such as methanol and ethanol is of interest, especially if this can be used directly in the fuel cell, without reformation to hydrogen. A limitation of the direct use of alcohol is the lower activity of oxidation in comparison to hydrogen, which means that power densities are considerably lower. Hence to improve activity and power output higher temperatures of operation are preferable. To achieve this goal, requires a new polymer electrolyte membrane which exhibits stability and high conductivity in the absence of liquid water.Experimental data on a polybenzimidazole based PEMFC were presented. A simple steady-state isothermal model of the fuel cell is also used to aid in fuel cell performance optimisation. The governing equations involve the coupling of kinetic, ohmic and mass transport. This paper also considers the advances made in the performance of direct methanol and solid polymer electrolyte fuel cells and considers their limitations in relation to the source and type of fuels to be used.

  9. Diamond based detectors for high temperature, high radiation environments (United States)

    Metcalfe, A.; Fern, G. R.; Hobson, P. R.; Smith, D. R.; Lefeuvre, G.; Saenger, R.


    Single crystal CVD diamond has many desirable properties as a radiation detector; exceptional radiation hardness and physical hardness, chemical inertness, low Z (close to human tissue, good for dosimetry and transmission mode applications), wide bandgap (high temperature operation with low noise and solar blind), an intrinsic pathway to fast neutron detection through the 12C(n,α)9Be reaction. This combination of radiation hardness, temperature tolerance and ability to detect mixed radiation types with a single sensor makes diamond particularly attractive as a detector material for harsh environments such as nuclear power station monitoring (fission and fusion) and oil well logging. Effective exploitation of these properties requires the development of a metallisation scheme to give contacts that remain stable over extended periods at elevated temperatures (up to 250°C in this instance). Due to the cost of the primary detector material, computational modelling is essential to best utilise the available processing methods for optimising sensor response through geometry and conversion media configurations and to fully interpret experimental data. Monte Carlo simulations of our diamond based sensor have been developed, using MCNP6 and FLUKA2011, assessing the sensor performance in terms of spectral response and overall efficiency as a function of the detector and converter geometry. Sensors with varying metallisation schemes for high temperature operation have been fabricated at Brunel University London and by Micron Semiconductor Limited. These sensors have been tested under a varied set of conditions including irradiation with fast neutrons and alpha particles at high temperatures. The presented study indicates that viable metallisation schemes for high temperature contacts have been successfully developed and the modelling results, supported by preliminary experimental data from partners, indicate that the simulations provide a reasonable representation of

  10. Electromagnetic losses in a three-phase high temperature superconducting cable determined by calorimetric measurements

    DEFF Research Database (Denmark)

    Traeholt, C.; Veje, E.; Tønnesen, Ole


    A 10 m long high temperature superconducting (HTS) cable conductor was placed in a plane three-phase arrangement. The test-bed enabled us to study the conductor losses for different separations between the phases. The superconductor was fixed symmetrically in the centre, whilst the two outer conv...... a calorimetric technique where the temperature increase in the flowing LN2 was measured with a set of thermo-couples. Results indicate that the total AC loss increases significantly when the separation between the conductors is reduced....

  11. Investigation of the influence of heated catalyst feeding system on the intensity of temperature-dependent chemical reaction in the fluidized bed apparatus (United States)

    Soloveva, O. V.; Solovyev, S. A.


    A mathematical model was developed and a numerical study of operation parameters of the fluidized bed apparatus for temperature-dependent processes was performed. Fields of catalyst concentration and temperature fields were obtained. The circulation flow analysis was carried out. The effect of the influence of heated catalyst feeder on the efficiency of apparatus heating was analyzed. The change of the circulating gas flows and catalyst structures due to changes in the heated catalyst feeder was shown. The influence of the catalyst fractional composition on the efficiency of apparatus heating was studied.

  12. High temperature flat plate solar collector

    Energy Technology Data Exchange (ETDEWEB)

    Hozumi, S.; Aso, S.; Ebisu, K.; Uchino, H.


    Improvements in the efficiency of collectors are of great importance for extending the utilization of solar energy for heating and cooling in homes. A highly efficient collector makes the system size small and decreases the system cost effectively. From the view of the amount of energy collected, the efficient collector has a multiple effect, not only because of the high increase in instantaneous efficiency, but also because of the large usable intensity range of the insolation. On the basis of a functional analysis for a flat collector, the materials and parameters were selected and optimized, and a new high temperature flat collector was designed. The collector has 2 panes. The first pane is low iron glass and the second pane is a thin film of fluorinated ethylene-propylene copolymer. The overall solar transmittance for the two panes is 0.89. The collecting panel and its water paths were formed by means of welding and hydraulic expansion. The selective absorbing surface consists of colored stainless steel whose absorption characteristic is 0.89 and emission characteristic is 0.16. The thermal insulator preventing backward heatloss consists of double layers of urethane foam and glass wool. Furthermore, the sustained method for the second pane is contrived so as to prevent water condensation on the panes and excessive elevation of the absorber temperature during no load heating.

  13. High-temperature superconductors make major progress

    CERN Multimedia

    CERN Bulletin


    This month's Nature Materials featured an important breakthrough for high-temperature superconductors. A new method has been found for processing Bi-2212 high-temperature superconducting round wire in order to drastically increase its critical current density. The result confirms that this conductor is a serious candidate for future very-high-field magnets.   This image shows the cross-section of two Bi-2212 wires. The bottom wire has less leakage and void porosity due to a heat treatment done at an overpressure of 100 bar - about 100 times the pressure used to produce the top wire (image from [Nature Materials, Vol. 13 (2014), 10.1038/nmat3887]). The workhorse for building superconducting accelerator magnets has been, so far, the Niobium-Titanium (Nb-Ti) alloy superconductor. But with Nb-Ti having reached its full potential, other conductors must be used to operate in higher magnetic fields beyond those reached with the LHC magnets. Today, the intermetallic Niobium-Tin (Nb3Sn) is th...

  14. Symmetry Non-restoration at High Temperature

    CERN Document Server

    Rius, N


    We discuss the (non)-restoration of global and local symmetries at high temperature. First, we analyze a two-scalar model with $Z_2 \\times Z_2$ symmetry using the exact renormalization group. We conclude that inverse symmetry breaking is possible in this kind of models within the perturbative regime. Regarding local symmetries, we consider the $SU(2) \\otimes U(1)$ gauge symmetry and focus on the case of a strongly interacting scalar sector. Employing a model-independent chiral Lagrangian we find indications of symmetry restoration.

  15. High temperature quark localization by Polyakov loops

    CERN Document Server

    Kovacs, Tamas G; Bruckmann, Falk; Schierenberg, Sebastian


    We study the low eigenmodes of the overlap and staggered Dirac operator at high temperature. We show that the recently found localized quark modes obeying Poisson statistics are connected to physical gauge field objects with their size and density scaling in the continuum limit. The localized modes are also strongly correlated with large fluctuations of the Polyakov loop. Based on that we construct a random matrix model of the low Dirac modes inspired by dimensional reduction. Our model reproduces the Poisson to random matrix transition seen in the lattice Dirac spectrum.

  16. Robust high temperature oxygen sensor electrodes

    DEFF Research Database (Denmark)

    Lund, Anders

    Platinum is the most widely used material in high temperature oxygen sensor electrodes. However, platinum is expensive and the platinum electrode may, under certain conditions, suffer from poisoning, which is detrimental for an oxygen sensor. The objective of this thesis is to evaluate electrode ......-based electrodes and one porous electrode based on the perovskite-structured strontium and vanadiumdoped lanthanum chromium oxide (LSCV) were investigated. The porous electrodes were applied on yttrium-stabilised zirconium oxide (YSZ) substrates in a collaboration with the company PBI...

  17. High temperature decomposition of hydrogen peroxide (United States)

    Parrish, Clyde F. (Inventor)


    Nitric oxide (NO) is oxidized into nitrogen dioxide (NO.sub.2) by the high temperature decomposition of a hydrogen peroxide solution to produce the oxidative free radicals, hydroxyl and hydroperoxyl. The hydrogen peroxide solution is impinged upon a heated surface in a stream of nitric oxide where it decomposes to produce the oxidative free radicals. Because the decomposition of the hydrogen peroxide solution occurs within the stream of the nitric oxide, rapid gas-phase oxidation of nitric oxide into nitrogen dioxide occurs.

  18. High Temperature Materials Laboratory third annual report

    Energy Technology Data Exchange (ETDEWEB)

    Tennery, V.J.; Foust, F.M.


    The High Temperature Materials Laboratory has completed its third year of operation as a designated DOE User Facility at the Oak Ridge National Laboratory. Growth of the user program is evidenced by the number of outside institutions who have executed user agreements since the facility began operation in 1987. A total of 88 nonproprietary agreements (40 university and 48 industry) and 20 proprietary agreements (1 university, 19 industry) are now in effect. Sixty-eight nonproprietary research proposals (39 from university, 28 from industry, and 1 other government facility) and 8 proprietary proposals were considered during this reporting period. Research projects active in FY 1990 are summarized.

  19. High Temperature Sodium Thermal Convection Test Loop

    Institute of Scientific and Technical Information of China (English)


    A project for the evaluation of compatibility characteristic of structural materials used in China experimental fast reactor(CEFR) has been in operation. The conditions which these structural materials contact with liquid sodium in reactor can be simulated by the tests in high temperature sodium thermal convection test loop. The main aims of designing and constructing the thermal convection test loop is for the corrosion test of CEFR materials, and the objective is to obtain the corrosion data of domestic materials.The main features of the test loop are shown in Fig.1. The primary components of the loop

  20. Applications of bulk high-temperature superconductors (United States)

    Hull, J. R.

    The development of high-temperature superconductors (HTS's) can be broadly generalized into thin-film electronics, wire applications, and bulk applications. We consider bulk HTS's to include sintered or crystallized forms that do not take the geometry of filaments or tapes, and we discuss major applications for these materials. For the most part applications may be realized with the HTS's cooled to 77 K, and the properties of the bulk HTS's are often already sufficient for commercial use. A non-exhaustive list of applications for bulk HTS's includes trapped field magnets, hysteresis motors, magnetic shielding, current leads, and magnetic bearings. These applications are briefly discussed in this paper.

  1. Aerospace applications of high temperature superconductivity (United States)

    Heinen, V. O.; Connolly, D. J.


    Space application of high temperature superconducting (HTS) materials may occur before most terrestrial applications because of the passive cooling possibilities in space and because of the economic feasibility of introducing an expensive new technology which has a significant system benefit in space. NASA Lewis Research Center has an ongoing program to develop space technology capitalizing on the potential benefit of HTS materials. The applications being pursued include space communications, power and propulsion systems, and magnetic bearings. In addition, NASA Lewis is pursuing materials research to improve the performance of HTS materials for space applications.

  2. High-resolution ice thickness and bed topography of a land-terminating section of the Greenland Ice Sheet

    DEFF Research Database (Denmark)

    Lindbäck, K.; Pettersson, R.; Doyle, S. H.;


    . The covered area is one of the most studied regions of the Greenland Ice Sheet with studies of mass balance, dynamics, and supraglacial lakes, and our combined dataset can be valuable for detailed studies of ice sheet dynamics and hydrology. The compiled datasets of ground-based and airborne radar surveys......We present ice thickness and bed topography maps with high spatial resolution (250 to 500 m) of a and-terminating section of the Greenland Ice Sheet derived from combined ground-based and airborne radar surveys. The data have a total area of ~12000 km2 and cover the whole ablation area...... of the outlet glaciers of Isunnguata Sermia, Russell, Leverett, Ørkendalen and Isorlersuup up to the long-term mass balance equilibrium line altitude at ~1600 m above sea level. The bed topography shows highly variable subglacial trough systems, and the trough of the Isunnguata Sermia Glacier is over...

  3. High-temperature superconducting current leads (United States)

    Hull, J. R.


    The use of high-temperature superconductors (HTSs) for current leads to deliver power to devices at liquid helium temperature is near commercial realization. The use of HTSs in this application has the potential to reduce refrigeration requirements and helium boiloff to values significantly lower than the theoretical best achievable with conventional leads. Considerable advantage is achieved by operating these leads with an intermediate temperature heat sink. The HTS part of the lead can be made from pressed and sintered powder. Powder-in-tube fabrication is also possible, however, the normal metal part of the lead acts as a thermal short and cannot provide much stabilization without increasing the refrigeration required. Lead stability favors designs with low current density. Such leads can be manufactured with today's technology, and lower refrigeration results from the same allowable burnout time. Higher current densities result in lower boiloff for the same lead length, but bumout times can be very short. In comparing experiment to theory, the density of helium vapor needs to be accounted for in calculating the expected boiloff. For very low-loss leads, two-dimensional heat transfer and the state of the dewar near the leads may play a dominant role in lead performance.

  4. High-Temperature Ceramic Matrix Composite with High Corrosion Resistance (United States)


    dioxide as an amorphous silica or −α cristobalite covers the carbide particles which to a great extent prevents it from subsequent oxidation...especially due to formation of cristobalite . The character of oxidation isotherms for SiC transformation to SiO2 fits parabolic dependence on time which...MoSi2 high-temperature oxidation takes place in two stages: the first one is formation of MoO3 and cristobalite (SiO2) at temperatures lower than the

  5. High power densities from high-temperature material interactions

    Energy Technology Data Exchange (ETDEWEB)

    Morris, J.F.


    Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs) offer important and unique advantages in terrestrial and space energy processing. And they are well suited to serve together synergistically. TEC and MFHPs operate through working-fluid vaporization, condensation cycles that accept great thermal power densities at high temperatures. TEC and MFHPs have apparently simple, isolated performance mechanisms that are somewhat similar. And they also have obviously difficult, complected material problems that again are somewhat similar. Intensive investigation reveals that aspects of their operating cycles and material problems tend to merge: high-temperature material effects determine the level and lifetime of performance. Simplified equations verify the preceding statement for TEC and MFHPs. Material properties and interactions exert primary influences on operational effectiveness. And thermophysicochemical stabilities dictate operating temperatures which regulate the thermoemissive currents of TEC and the vaporization flow rates of MFHPs. Major high-temperature material problems of TEC and MFHPs have been solved. These solutions lead to productive, cost-effective applications of current TEC and MFHPs - and point to significant improvements with anticipated technological gains.

  6. High point for CERN and high-temperature superconductors

    CERN Multimedia


    Amalia Ballarino is named the Superconductor Industry Person of the year 2006. Amalia Ballarino showing a tape of high-superconducting material used for the LHC current leads.The CERN project leader for the high-temperature superconducting current leads for the LHC, Amalia Ballarino, has received the award for "Superconductor Industry Person of the Year". This award, the most prestigious international award in the development and commercialization of superconductors, is presented by the leading industry newsletter "Superconductor Week". Amalia Ballarino was selected from dozens of nominations from around the world by a panel of recognized leading experts in superconductivity. "It is a great honour for me," says Amalia Ballarino. "It has been many years of hard work, and it’s a great satisfaction to see that the work has been completed successfully." Amalia Ballarino has been working on high-temperature superconducting materials sin...

  7. Fluidized bed calciner apparatus (United States)

    Owen, Thomas J.; Klem, Jr., Michael J.; Cash, Robert J.


    An apparatus for remotely calcining a slurry or solution feed stream of toxic or hazardous material, such as ammonium diurante slurry or uranyl nitrate solution, is disclosed. The calcining apparatus includes a vertical substantially cylindrical inner shell disposed in a vertical substantially cylindrical outer shell, in which inner shell is disposed a fluidized bed comprising the feed stream material to be calcined and spherical beads to aid in heat transfer. Extending through the outer and inner shells is a feed nozzle for delivering feed material or a cleaning chemical to the beads. Disposed in and extending across the lower portion of the inner shell and upstream of the fluidized bed is a support member for supporting the fluidized bed, the support member having uniform slots for directing uniform gas flow to the fluidized bed from a fluidizing gas orifice disposed upstream of the support member. Disposed in the lower portion of the inner shell are a plurality of internal electric resistance heaters for heating the fluidized bed. Disposed circumferentially about the outside length of the inner shell are a plurality of external heaters for heating the inner shell thereby heating the fluidized bed. Further, connected to the internal and external heaters is a means for maintaining the fluidized bed temperature to within plus or minus approximately C. of a predetermined bed temperature. Disposed about the external heaters is the outer shell for providing radiative heat reflection back to the inner shell.

  8. High dietary sodium chloride causes further protein loss during head-down tilt bed rest (HDBR) (United States)

    Buehlmeier, Judith; Frings-Meuthen, Petra; Baecker, Natalie; Stehle, Peter; Heer, Martina

    Human spaceflight is associated with a loss of body protein most likely caused by muscle degradation. Additionally astronauts tend towards a high dietary intake of sodium chloride (NaCl), which has recently been shown to induce low grade metabolic acidosis (Frings-Meuthen et al. JBMR, Epub 2007). In several patterns, e.g. chronical renal failure, metabolic acidosis is associated with protein catabolism. We therefore hypothesized that high dietary intake of NaCl enforces protein losses in HDBR, a model for physiological changes in microgravity (µG). Eight healthy male subjects (mean age 26.25 ± 3.5; mean body weight: 78.5 ± 4.1 kg) participated in a 14-day bed rest study in the metabolic ward of the DLR - Institute of Aerospace Medicine, Cologne, Germany. The study was carried out in a cross over design, consisting of two phases, each lasting 22 days (5 days adaptation, 14 days 6° HDBR and 3 days recovery). Both study phases were identical with respect to environmental conditions and study protocol. Subjects received an individually tailored, weight-maintaining diet containing 1.3 g protein/kg/day. The diet was identical in both study phases with the exception of NaClintake: Every subject received a low NaCl diet (0.7 mmol/kg/day) in one phase and a high NaCl diet (7.7 mmol/kg/day) in another one. Blood gas for analysis of acid-base balance was implemented at days 4 and 5 of adaptation, days 2, 5, 7, 10, 12, 14 of HDBR and days 2, 3 of recovery. Continuous urine collection started on the first day in the metabolic ward to analyze nitrogen excretion. Nitrogen balance was calculated from the difference between protein intake and urinary nitrogen excretion, determined by use of chemiluminescence (Grimble et al. JPEN, 1988). Plasma pH did not change significantly (p=0.285), but plasma bicarbonate and base excess decreased (p=0.0175; p=0.0093) with high NaCl intake in HDBR compared to the low NaCl diet. Nitrogen balance in HDBR was negative, as expected in

  9. High-Temperature Ionization in Protoplanetary Disks

    CERN Document Server

    Desch, Steven J


    We calculate the abundances of electrons and ions in the hot (> 500 K), dusty parts of protoplanetary disks, treating for the first time the effects of thermionic and ion emission from the dust grains. High-temperature ionization modeling has involved simply assuming that alkali elements such as potassium occur as gas-phase atoms and are collisionally ionized following the Saha equation. We show that the Saha equation often does not hold, because free charges are produced by thermionic and ion emission and destroyed when they stick to grain surfaces. This means the ionization state depends not on the first ionization potential of the alkali atoms, but rather on the grains' work functions. The charged species' abundances typically rise abruptly above about 800 K, with little qualitative dependence on the work function, gas density, or dust-to-gas mass ratio. Applying our results, we find that protoplanetary disks' dead zone, where high diffusivities stifle magnetorotational turbulence, has its inner edge locat...

  10. Apparatus for accurately measuring high temperatures (United States)

    Smith, D.D.

    The present invention is a thermometer used for measuring furnace temperatures in the range of about 1800/sup 0/ to 2700/sup 0/C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  11. Thermomechanics of composite structures under high temperatures

    CERN Document Server

    Dimitrienko, Yu I


    This pioneering book presents new models for the thermomechanical behavior of composite materials and structures taking into account internal physico-chemical transformations such as thermodecomposition, sublimation and melting at high temperatures (up to 3000 K). It is of great importance for the design of new thermostable materials and for the investigation of reliability and fire safety of composite structures. It also supports the investigation of interaction of composites with laser irradiation and the design of heat-shield systems. Structural methods are presented for calculating the effective mechanical and thermal properties of matrices, fibres and unidirectional, reinforced by dispersed particles and textile composites, in terms of properties of their constituent phases. Useful calculation methods are developed for characteristics such as the rate of thermomechanical erosion of composites under high-speed flow and the heat deformation of composites with account of chemical shrinkage. The author expan...

  12. Cast Aluminum Alloy for High Temperature Applications (United States)

    Lee, Jonathan A.


    Originally developed by NASA as high performance piston alloys to meet U.S. automotive legislation requiring low exhaust emission, the novel NASA alloys now offer dramatic increase in tensile strength for many other applications at elevated temperatures from 450 F (232 C) to about 750 F (400 C). It is an ideal low cost material for cast automotive components such as pistons, cylinder heads, cylinder liners, connecting rods, turbo chargers, impellers, actuators, brake calipers and rotors. It can be very economically produced from conventional permanent mold, sand casting or investment casting, with silicon content ranging from 6% to 18%. At high silicon levels, the alloy exhibits excellent dimensional stability, surface hardness and wear resistant properties.

  13. Filter unit for use at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Ciliberti, D.F.; Lippert, T.E.


    A filtering unit for the filtering of particulates from a particulate-containing high temperature gas stream is described comprising a ceramic, tubular filter element, having a closed bottom and side walls and an open top at the upper region thereof, disposed in an aperture in a tube sheet. The walls of the tube sheet about the aperature have an inwardly extending flange thereon, with the open top of the ceramic, tubular filter element adjacent one surface of the tube sheet where filtered gases are discharged, and the closed bottom and side walls exposed to the area of the opposite surface of the tube sheet where a particulate-containing high temperature gas stream to be filtered is present. A ceramic spiral spring is provided at an end of the ceramic, tubular filter element to bias the upper region of the ceramic, tubular filter element into contact with the flange so as to seal the ceramic, tubular filter element to the flange on the tube sheet.

  14. Influences of relative humidities and temperatures on the collection of C2-C5 aliphatic hydrocarbons with multi-bed (Tenax TA, Carbograph 1TD, Carboxen 1003) sorbent tube method (United States)

    Ho, Steven Sai Hang; Chow, Judith C.; Watson, John G.; Wang, Liqin; Qu, Linli; Dai, Wenting; Huang, Yu; Cao, Junji


    Volatile organic compounds (VOCs) are measured with sorbent tubes followed by thermal desorption (TD) analysis. Water vapor in the atmosphere affects sampling breakthrough and results in low collection efficiency. This paper reports the effect of relative humidity (RH) and temperature on the collection of 57 ozone precursors with a multi-bed tube composed of three different strengths of adsorbents (Tenax TA, Carbograph 1 TD, and Carboxen 1003). Unacceptable breakthrough values for volatile C2-C5 aliphatic compounds were observed under high (>60%) RHs. The breakthrough volumes (BV) for C2 aliphatic compounds were reduced 13-22 fold under 90% RH. Dry-purge with inert helium gas removes excessive water content before the TD analysis but also causes a maximum of 40% loss of target analytes. Condensation is another pathway for water retention. The tube temperature should be regulated at 5-10 °C above the air temperature to minimize condensation under RHs >30%.

  15. High density and high temperature plasmas in Large Helical Device (United States)

    Komori, Akio


    Recently a new confinement regime called Super Dense Core (SDC) mode was discovered in Large Helical Device (LHD). An extremely high density core region with more than ~ 1 × 1021 m-3 is obtained with the formation of an Internal Diffusion Barrier (IDB). The density gradient at the IDB is very high and the particle confinement in the core region is ~ 0.2 s. It is expected, for the future reactor, that the IDB-SDC mode has a possibility to achieve the self-ignition condition with lower temperature than expected before. Conventional approaches to increase the temperature have also been tried in LHD. For the ion heating, the perpendicular neutral beam injection effectively increased the ion temperature up to 5.6 keV with the formation of the internal transport barrier (ITB). In the electron heating experiments with 77 GHz gyrotrons, the highest electron temperature more than 15 keV was achieved, where plasmas are in the neoclassical regime.

  16. High density and high temperature plasmas in Large Helical Device

    Energy Technology Data Exchange (ETDEWEB)

    Komori, Akio, E-mail: [National Institute for Fusion Science, 322-6 Oroshi, Toki, Gifu 509-5292 (Japan)


    Recently a new confinement regime called Super Dense Core (SDC) mode was discovered in Large Helical Device (LHD). An extremely high density core region with more than {approx} 1 x 10{sup 21} m{sup -3} is obtained with the formation of an Internal Diffusion Barrier (IDB). The density gradient at the IDB is very high and the particle confinement in the core region is {approx} 0.2 s. It is expected, for the future reactor, that the IDB-SDC mode has a possibility to achieve the self-ignition condition with lower temperature than expected before. Conventional approaches to increase the temperature have also been tried in LHD. For the ion heating, the perpendicular neutral beam injection effectively increased the ion temperature up to 5.6 keV with the formation of the internal transport barrier (ITB). In the electron heating experiments with 77 GHz gyrotrons, the highest electron temperature more than 15 keV was achieved, where plasmas are in the neoclassical regime.

  17. High Intensity Exercise Countermeasures does not Prevent Orthostatic Intolerance Following Prolonged Bed Rest (United States)

    Platts, Steven H.; Stenger, Michael B.; Ploutz-Snyder, Lori L.; Lee, Stuart M. C.


    Approximately 20% of Space Shuttle astronauts became presyncopal during operational stand and 80deg head-up tilt tests, and the prevalence of orthostatic intolerance increases after longer missions. Greater than 60% of the US astronauts participating in Mir and early International Space Station missions experienced presyncope during post-flight tilt tests, perhaps related to limitations of the exercise hardware that prevented high intensity exercise training until later ISS missions. The objective of this study was to determine whether an intense resistive and aerobic exercise countermeasure program designed to prevent cardiovascular and musculoskeletal deconditioning during 70 d of bed rest (BR), a space flight analog, would protect against post-BR orthostatic intolerance. METHODS Twenty-six subjects were randomly assigned to one of three groups: non-exercise controls (n=11) or one of two exercise groups (ExA, n=8; ExB, n=7). Both ExA and ExB groups performed the same resistive and aerobic exercise countermeasures during BR, but one exercise group received testosterone supplementation while the other received a placebo during BR in a double-blinded fashion. On 3 d/wk, subjects performed lower body resistive exercise and 30 min of continuous aerobic exercise (=75% max heart rate). On the other 3 d/wk, subjects performed only highintensity, interval-style aerobic exercise. Orthostatic intolerance was assessed using a 15-min 80? head-up tilt test performed 2 d (BR-2) before and on the last day of BR (BR70). Plasma volume was measured using carbon monoxide rebreathing on BR-3 and before rising on the first recovery day (BR+0). The code for the exercise groups has not been broken, and results are reported here without group identification. RESULTS Only one subject became presyncopal during tilt testing on BR-2, but 7 of 11 (63%) controls, 3 of 8 (38%) ExA, and 4 of 7 (57%) ExB subjects were presyncopal on BR70. Survival analysis of post-BR tilt tests revealed no

  18. Knife grid size reduction to pre-process packed beds of high- and low-moisture switchgrass. (United States)

    Igathinathane, C; Womac, A R; Sokhansanj, S; Narayan, S


    A linear knife grid device was developed for first-stage size reduction of high- and low-moisture switchgrass (Panicum virgatum L.), a tough, fibrous perennial grass being considered as a feedstock for bioenergy. The size reduction is by a shearing action accomplished by forcing a thick packed bed of biomass against a grid of sharp knives. The system is used commercially for slicing forages for drying or feed mixing. No performance data or engineering equations are available in published literature to optimize the machine and the process for biomass size reductions. Tests of a linear knife grid with switchgrass quantified the combined effect of shearing stresses, packed bed consolidation, and frictional resistance to flow through a knife grid. A universal test machine (UTM) measured load-displacement of switchgrass at two moisture contents: 51%, and 9% wet basis; three knife grid spacings: 25.4, 50.8, and 101.6mm; and three packed bed depths: 50.8, 101.6, and 152.4mm. Results showed that peak load, ultimate shear stress, and cutting energy values varied inversely with knife grid spacing and directly with packed bed depth (except ultimate shear stress). Mean ultimate shear stresses of high- and low-moisture switchgrass were 0.68+/-0.24, and 0.41+/-0.21 MPa, mass-based cutting energy values were 4.50+/-4.43, and 3.64+/-3.31 MJ/dry Mg, and cutting energy based on new surface area, calculated from packed-circle theory, were 4.12+/-2.06, and 2.53+/-0.45 kJ/m2, respectively. The differences between high- and low-moisture switchgrass were significant (P<0.05), such that high-moisture switchgrass required increased shear stress and cutting energy. Reduced knife grid spacing and increased packed bed depths required increased cutting energy. Overall, knife grid cutting energy was much less than energy values published for rotary equipment. A minimum knife grid spacing of 25.4mm appears to be a practical lower limit, considering the high ram force that would be needed for

  19. Analog Exercise Hardware to Implement a High Intensity Exercise Program During Bed Rest (United States)

    Loerch, Linda; Newby, Nate; Sinka, Joe; Ploutz-Snyder, Lori


    To evaluate novel countermeasure protocols in a spaceflight analog setting before validation on the International Space Station, NASA’s Human Research Program is sponsoring a multi-investigator bed rest campaign that uses a combination of commercial and custom-made exercise training hardware to conduct daily resistance and aerobic exercise protocols. These devices include the stand alone zero-gravity locomotion simulator, horizontal squat device, Lode commercial supine cycle ergometer, Cybex commercial prone leg curl machine, and Quantum Fitness commercial horizontal leg press. This paper will describe these pieces of hardware that are used to support current bed rest studies at NASA’s Flight Analog Research Unit in Galveston, Texas, USA.

  20. High pressure/high temperature thermogravimetric apparatus. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Calo, J.M.; Suuberg, E.M.


    The purpose of this instrumentation grant was to acquire a state-of-the-art, high pressure, high temperature thermogravimetric apparatus (HP/HT TGA) system for the study of the interactions between gases and carbonaceous solids for the purpose of solving problems related to coal utilization and applications of carbon materials. The instrument that we identified for this purpose was manufactured by DMT (Deutsche Montan Technologies)--Institute of Cokemaking and Coal Chemistry of Essen, Germany. Particular features of note include: Two reactors: a standard TGA reactor, capable of 1100 C at 100 bar; and a high temperature (HT) reactor, capable of operation at 1600 C and 100 bar; A steam generator capable of generating steam to 100 bar; Flow controllers and gas mixing system for up to three reaction gases, plus a separate circuit for steam, and another for purge gas; and An automated software system for data acquisition and control. The HP/TP DMT-TGA apparatus was purchased in 1996 and installed and commissioned during the summer of 1996. The apparatus was located in Room 128 of the Prince Engineering Building at Brown University. A hydrogen alarm and vent system were added for safety considerations. The system has been interfaced to an Ametek quadruple mass spectrometer (MA 100), pumped by a Varian V250 turbomolecular pump, as provided for in the original proposed. With this capability, a number of gas phase species of interest can be monitored in a near-simultaneous fashion. The MS can be used in a few different modes. During high pressure, steady-state gasification experiments, it is used to sample, measure, and monitor the reactant/product gases. It can also be used to monitor gas phase species during nonisothermal temperature programmed reaction (TPR) or temperature programmed desorption (TPD) experiments.

  1. Materials for High-Temperature Catalytic Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ersson, Anders


    Catalytic combustion is an environmentally friendly technique to combust fuels in e.g. gas turbines. Introducing a catalyst into the combustion chamber of a gas turbine allows combustion outside the normal flammability limits. Hence, the adiabatic flame temperature may be lowered below the threshold temperature for thermal NO{sub X} formation while maintaining a stable combustion. However, several challenges are connected to the application of catalytic combustion in gas turbines. The first part of this thesis reviews the use of catalytic combustion in gas turbines. The influence of the fuel has been studied and compared over different catalyst materials. The material section is divided into two parts. The first concerns bimetallic palladium catalysts. These catalysts showed a more stable activity compared to their pure palladium counterparts for methane combustion. This was verified both by using an annular reactor at ambient pressure and a pilot-scale reactor at elevated pressures and flows closely resembling the ones found in a gas turbine combustor. The second part concerns high-temperature materials, which may be used either as active or washcoat materials. A novel group of materials for catalysis, i.e. garnets, has been synthesised and tested in combustion of methane, a low-heating value gas and diesel fuel. The garnets showed some interesting abilities especially for combustion of low-heating value, LHV, gas. Two other materials were also studied, i.e. spinels and hexa aluminates, both showed very promising thermal stability and the substituted hexa aluminates also showed a good catalytic activity. Finally, deactivation of the catalyst materials was studied. In this part the sulphur poisoning of palladium, platinum and the above-mentioned complex metal oxides has been studied for combustion of a LHV gas. Platinum and surprisingly the garnet were least deactivated. Palladium was severely affected for methane combustion while the other washcoat materials were

  2. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Fain, D.E.; Roettger, G.E. [Oak Ridge K-25 Site, TN (United States)


    Ceramic gas separation membranes can provide very high separation factors if the pore size is sufficiently small to separate gas molecules by molecular sieving and if oversized pores are adequately limited. Ceramic membranes typically have some pores that are substantially larger than the mean pore size and that should be regarded as defects. To assess the effects of such defects on the performance of ceramic membranes, a simple mathematical model has been developed to describe flow through a gas separation membrane that has a primary mode of flow through very small pores but that has a secondary mode of flow through undesirably large pores. This model permits separation factors to be calculated for a specified gas pair as a function of the molecular weights and molecular diameters of the gases, the membrane pore diameter, and the diameter and number of defects. This model will be described, and key results from the model will be presented. The separation factors of the authors membranes continue to be determined using a permeance test system that measures flows of pure gases through a membrane at temperatures up to 275{degrees}C. A primary goal of this project for FY 1996 is to develop a mixed gas separation system for measuring the separation efficiency of membranes at higher temperatures. Performance criteria have been established for the planned mixed gas separation system and design of the system has been completed. The test system is designed to measure the separation efficiency of membranes at temperatures up to 600{degrees}C and pressures up to 100 psi by separating the constituents of a gas mixture containing hydrogen. The system will accommodate the authors typical experimental membrane that is tubular and has a diameter of about 9 mm and a length of about 23 cm. The design of the new test system and its expected performance will be discussed.

  3. Potential aerospace applications of high temperature superconductors (United States)

    Selim, Raouf


    The recent discovery of High Temperature Superconductors (HTS) with superconducting transition temperature, T(sub c), above the boiling point of liquid nitrogen has opened the door for using these materials in new and practical applications. These materials have zero resistance to electric current, have the capability of carrying large currents and as such have the potential to be used in high magnetic field applications. One of the space applications that can use superconductors is electromagnetic launch of payloads to low-earth-orbit. An electromagnetic gun-type launcher can be used in small payload systems that are launched at very high velocity, while sled-type magnetically levitated launcher can be used to launch larger payloads at smaller velocities. Both types of launchers are being studied by NASA and the aerospace industry. The use of superconductors will be essential in any of these types of launchers in order to produce the large magnetic fields required to obtain large thrust forces. Low Temperature Superconductor (LTS) technology is mature enough and can be easily integrated in such systems. As for the HTS, many leading companies are currently producing HTS coils and magnets that potentially can be mass-produced for these launchers. It seems that designing and building a small-scale electromagnetic launcher is the next logical step toward seriously considering this method for launching payloads into low-earth-orbit. A second potential application is the use of HTS to build sensitive portable devices for the use in Non Destructive Evaluation (NDE). Superconducting Quantum Interference Devices (SQUID's) are the most sensitive instruments for measuring changes in magnetic flux. By using HTS in SQUID's, one will be able to design a portable unit that uses liquid nitrogen or a cryocooler pump to explore the use of gradiometers or magnetometers to detect deep cracks or corrosion in structures. A third use is the replacement of Infra-Red (IR) sensor leads on

  4. High-temperature superconducting undulator magnets (United States)

    Kesgin, Ibrahim; Kasa, Matthew; Ivanyushenkov, Yury; Welp, Ulrich


    This paper presents test results on a prototype superconducting undulator magnet fabricated using 15% Zr-doped rare-earth barium copper oxide high temperature superconducting (HTS) tapes. On an 11-pole magnet we demonstrate an engineering current density, J e, of more than 2.1 kA mm‑2 at 4.2 K, a value that is 40% higher than reached in comparable devices wound with NbTi-wire, which is used in all currently operating superconducting undulators. A novel winding scheme enabling the continuous winding of tape-shaped conductors into the intricate undulator magnets as well as a partial interlayer insulation procedure were essential in reaching this advance in performance. Currently, there are rapid advances in the performance of HTS; therefore, achieving even higher current densities in an undulator structure or/and operating it at temperatures higher than 4.2 K will be possible, which would substantially simplify the cryogenic design and reduce overall costs.

  5. A highly efficient polyampholyte hydrogel sorbent based fixed-bed process for heavy metal removal in actual industrial effluent. (United States)

    Zhou, Guiyin; Luo, Jinming; Liu, Chengbin; Chu, Lin; Ma, Jianhong; Tang, Yanhong; Zeng, Zebing; Luo, Shenglian


    High sorption capacity, high sorption rate, and fast separation and regeneration for qualified sorbents used in removing heavy metals from wastewater are urgently needed. In this study, a polyampholyte hydrogel was well designed and prepared via a simple radical polymerization procedure. Due to the remarkable mechanical strength, the three-dimensional polyampholyte hydrogel could be fast separated, easily regenerated and highly reused. The sorption capacities were as high as 216.1 mg/g for Pb(II) and 153.8 mg/g for Cd(II) owing to the existence of the large number of active groups. The adsorption could be conducted in a wide pH range of 3-6 and the equilibrium fast reached in 30 min due to its excellent water penetration for highly accessible to metal ions. The fixed-bed column sorption results indicated that the polyampholyte hydrogel was particularly effective in removing Pb(II) and Cd(II) from actual industrial effluent to meet the regulatory requirements. The treatment volumes of actual smelting effluent using one fixed bed column were as high as 684 bed volumes (BV) (7736 mL) for Pb(II) and 200 BV (2262 mL) for Cd(II). Furthermore, the treatment volumes of actual smelting effluent using tandem three columns reached 924 BV (31,351 mL) for Pb(II) and 250 BV (8483 mL) for Cd(II), producing only 4 BV (136 mL) eluent. Compared with the traditional high density slurry (HDS) process with large amount of sludge, the proposed process would be expected to produce only a small amount of sludge. When the treatment volume was controlled below 209.3 BV (7103 mL), all metal ions in the actual industrial effluent could be effectively removed (hydrogel sorbents for the removal of heavy metal ions from practical wastewater.

  6. Electrode Kinetics in High Temperature Fuel Cells

    DEFF Research Database (Denmark)

    Bay, Lasse


    The O_2 reduction on Pt electrode with an yttria stabilized zirconia (YSZ) electrolyte is examined with potential step, voltammetry and impedance measurements. Inductive hysteresis are observed in all cases, indicating an activation-deactivation process for the electrode reaction. The same is found...... when the electrolyte is Gd doped ceria. The activation is generated by current passage. The time constant for the hysteresis is large considering the high operating temperatures, 800- 1000^oC. For the activation process potential steps give two time constants 10^2s and 10^3s for an anodic current, 10...... treated by modelling. The phenomenological model proposed can explain the principal behaviour of the inductive hysteresis. The activation process has first order dependence of the current density and the deactivation first order with respect to the activation.AFM pictures of the electrode...

  7. High temperature and pressure electrochemical test station

    DEFF Research Database (Denmark)

    Chatzichristodoulou, Christodoulos; Allebrod, Frank; Mogensen, Mogens Bjerg


    An electrochemical test station capable of operating at pressures up to 100 bars and temperatures up to 400 ◦C has been established. It enables control of the partial pressures and mass flow of O2, N2, H2, CO2, and H2O in a single or dual environment arrangement, measurements with highly corrosive...... media, as well as localized sampling of gas evolved at the electrodes for gas analysis. A number of safety and engineering design challenges have been addressed. Furthermore, we present a series of electrochemical cell holders that have been constructed in order to accommodate different types of cells...... and facilitate different types of electrochemical measurements. Selected examples of materials and electrochemical cells examined in the test station are provided, ranging from the evaluation of the ionic conductivity of liquid electrolytic solutions immobilized in mesoporous ceramic structures...

  8. High temperature chemically resistant polymer concrete (United States)

    Sugama, T.; Kukacka, L.E.

    High temperature chemically resistant, non-aqueous polymer concrete composites consist of about 12 to 20% by weight of a water-insoluble polymer binder. The binder is polymerized in situ from a liquid vinyl-type monomer or mixture of vinyl containing monomers such as triallylcyanurate, styrene, acrylonitrile, acrylamide, methacrylamide, methyl-methacrylate, trimethylolpropane trimethacrylate and divinyl benzene. About 5 to 40% by weight of a reactive inorganic filler selected from the group consisting of tricalcium silicate and dicalcium silicate and mixtures containing less than 2% free lime, and about 48 to 83% by weight of silica sand/ and a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide, other orgaic peroxides and combinations to initiate polymerization of the monomer in the presence of the inorganic filers are used.

  9. Turbine vane with high temperature capable skins

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, Jay A [Oviedo, FL


    A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

  10. On Silicides in High Temperature Titanium Alloys

    Directory of Open Access Journals (Sweden)

    C. Ramachandra


    Full Text Available High temperature titanium alloys like IMI 685 contain small amounts of silicon (~ 0.25 wt. per cent to improve creep resistance. Different types of silicides, namely Ti5Si3 (TiZr5Si3(S1 and (TiZr6 Si3 (S2, have been observed to precipitate in various silicon-bearing titanium alloys depending upon their composition and heat treatment. The precipitation of silicides, their orientation relationship with the matrix in different alloys, and the beneficial influence of thermo-mechanical treatment on the distribution of silicides have been pointed out. The effect of silicides on mechanical properties and fracture of the commercial alloy IMI 685 is also indicated.

  11. High temperature superconductivity space experiment (HTSSE) (United States)

    Ritter, J. C.; Nisenoff, M.; Price, G.; Wolf, S. A.


    An experiment dealing with high-temperature superconducting devices and components in space is discussed. A variety of devices (primarily passive microwave and millimeter-wave components) has been procured and will be integrated with a cryogenic refrigerating and data acquisition system to form the space package, which will be launched in late 1992. This space experiment is expected to demonstrate that this technology is sufficiently robust to survive the space environment and that the technology has the potential to improve the operation of space systems significantly. The devices for the initial launch have been evaluated electrically, thermally, and mechanically, and will be integrated into the final space package early in 1991. The performance of the devices is summarized, and some potential applications of this technology in space systems are outlined.

  12. Chemical stability of high-temperature superconductors (United States)

    Bansal, Narottam P.


    A review of the available studies on the chemical stability of the high temperature superconductors (HTS) in various environments was made. The La(1.8)Ba(0.2)CuO4 HTS is unstable in the presence of H2O, CO2, and CO. The YBa2Cu3O(7-x) superconductor is highly susceptible to degradation in different environments, especially water. The La(2-x)Ba(x)CuO4 and Bi-Sr-Ca-Cu-O HTS are relatively less reactive than the YBa2Cu3O(7-x). Processing of YBa2Cu3O(7-x) HTS in purified oxygen, rather than in air, using high purity noncarbon containing starting materials is recommended. Exposure of this HTS to the ambient atmosphere should also be avoided at all stages during processing and storage. Devices and components made out of these oxide superconductors would have to be protected with an impermeable coating of a polymer, glass, or metal to avoid deterioration during use.


    Energy Technology Data Exchange (ETDEWEB)

    Pint, B.A.; Zhang, Y.; Haynes, J.A.; Wright, I.G.


    In order to determine the potential benefits and limitations of aluminide coatings, coatings made by chemical vapor deposition (CVD) on Fe- and Ni-base alloy substrates are being evaluated in various high-temperature environments. Testing of coatings on representative ferritic (Fe-9Cr-1Mo) and austenitic (type 304L stainless steel) alloys has found that high frequency thermal cycling (1h cycle time) can significantly degrade the coating. Based on comparison with similar specimens with no thermal cycling or a longer cycle time (100h), this degradation was not due to Al loss from the coating but most likely because of the thermal expansion mismatch between the coating and the substrate. Several coated Ni-base alloys were tested in a high pressure (20atm) steam-CO2 environment for the ZEST (zero-emission steam turbine) program. Coated specimens showed less mass loss than the uncoated specimens after 1000h at 900 C and preliminary characterization examined the post-test coating structure and extent of attack.

  14. Assessment of high-temperature battery systems

    Energy Technology Data Exchange (ETDEWEB)

    Sen, R K


    Three classes of high-temperature batteries are being developed internationally with transportation and stationary energy storage applications in mind: sodium/sulfur, lithium/metal sulfide, and sodium/metal chloride. Most attention is being given to the sodium/sulfur system. The Office of Energy Storage and Distribution (OESD) and the Office of Transportation Systems (OTS) of the US Department of Energy (DOE) are actively supporting the development of this battery system. It is anticipated that pilot-scale production facilities for sodium/sulfur batteries will be in operation in the next couple of years. The lithium/metal sulfide and the sodium/metal chloride systems are not receiving the same level of attention as the sodium/sulfur battery. Both of these systems are in an earlier stage of development than sodium/sulfur. OTS and OESD are supporting work on the lithium/iron sulfide battery in collaboration with the Electric Power Research Institute (EPRI); the work is being carried out at Argonne National Laboratory (ANL). The sodium/metal chloride battery, the newest member of the group, is being developed by a Consortium of South African and British companies. Very little DOE funds are presently allocated for research on this battery. The purpose of this assessment is to evaluate the present status of the three technologies and to identify for each technology a prioritized list of R and D issues. Finally, the assessment includes recommendations to DOE for a proposed high-temperature battery research and development program. 18 figs., 21 tabs.


    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi


    The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for this project. The modifications include better and more accurate sampling technique, addition of a digital recorder to monitor temperature and pressure inside the VLE cell, and a new technique for remote sensing of the liquid level in the cell. VLE data measurements for three binary systems, tetralin-quinoline, benzene--ethylbenzene and ethylbenzene--quinoline, have been completed. The temperature ranges of data measurements were 325 C to 370 C for the first system, 180 C to 300 C for the second system, and 225 C to 380 C for the third system. The smoothed data were found to be fairly well behaved when subjected to thermodynamic consistency tests. SETARAM C-80 calorimeter was used for incremental enthalpy and heat capacity measurements for benzene--ethylbenzene binary liquid mixtures. Data were measured from 30 C to 285 C for liquid mixtures covering the entire composition range. An apparatus has been designed for simultaneous measurement of excess volume and incremental enthalpy of liquid mixtures at temperatures from 30 C to 300 C. The apparatus has been tested and is ready for data measurements. A flow apparatus for measurement of heat of mixing of liquid mixtures at high temperatures has also been designed, and is currently being tested and calibrated.

  16. Mechanical behavior of high strength ceramic fibers at high temperatures (United States)

    Tressler, R. E.; Pysher, D. J.


    The mechanical behavior of commercially available and developmental ceramic fibers, both oxide and nonoxide, has been experimentally studied at expected use temperatures. In addition, these properties have been compared to results from the literature. Tensile strengths were measured for three SiC-based and three oxide ceramic fibers for temperatures from 25 C to 1400 C. The SiC-based fibers were stronger but less stiff than the oxide fibers at room temperature and retained more of both strength and stiffness to high temperatures. Extensive creep and creep-rupture experiments have been performed on those fibers from this group which had the best strengths above 1200 C in both single filament tests and tests of fiber bundles. The creep rates for the oxides are on the order of two orders of magnitude faster than the polymer derived nonoxide fibers. The most creep resistant filaments available are single crystal c-axis sapphire filaments. Large diameter CVD fabricated SiC fibers are the most creep and rupture resistant nonoxide polycrystalline fibers tested to date.

  17. High Temperature Integrated Thermoelectric Ststem and Materials

    Energy Technology Data Exchange (ETDEWEB)

    Mike S. H. Chu


    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits

  18. Potential approaches to improve gasification of high water content biomass rich in cellulose in dual fluidized bed

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Li; Xu, Guangwen [State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing (China); Suda, Toshiyuki [Research Laboratory, IHI Corporation, Ltd., Yokohama (Japan); Murakami, Takahiro [National Institute of Advanced Science and Technology, Tsukuba (Japan)


    Biomass containing water of 30-65 wt.% and rich in cellulose, such as various grounds of drinking materials and the lees of spirit and vinegar, is not suitable for biological digestion, and the thermal conversion approach has to be applied to its conversion into bioenergy. The authors have recently worked on converting such biomass into middle heating-value gas via dual fluidized bed gasification (DFBG) integrated with various process intensification technologies. This article is devoted to highlighting those technical ways, including the choice of the superior technical deployment for a DFBG system, the impregnation of Ca onto fuel in fuel drying, the integration of gas cleaning with fuel gasification via two-stage DFBG (T-DFBG), and the decoupling of fuel drying/pyrolysis and char gasification via the decoupled DFBG (D-DFBG). The attained results demonstrated that the superior deployment of bed combination for the DFBG should be a bubbling/turbulent fluidized bed gasifier integrated with a pneumatic riser combustor. In terms of improving efficiency of fuel conversion into combustible gas and suppressing tar generation during gasification, the impregnation of Ca onto fuel exhibited distinctively high upgrading effect, while both the T-DFBG and D-DFBG were also demonstrated to be effective to a certain degree. (author)

  19. High Molecular Weight Polybenzimidazole Membranes for High Temperature PEMFC

    DEFF Research Database (Denmark)

    Yang, Jingshuai; Cleemann, Lars Nilausen; Steenberg, T.;


    High temperature operation of proton exchange membrane fuel cells under ambient pressure has been achieved by using phosphoric acid doped polybenzimidazole (PBI) membranes. To optimize the membrane and fuel cells, high performance polymers were synthesized of molecular weights from 30 to 94 k...... showed enhanced chemical stability towards radical attacks under the Fenton test, reduced volume swelling upon the acid doping and improved mechanical strength at acid doping levels of as high as about 11 mol H3PO4 per molar repeat polymer unit. The PBI‐78kDa/10.8PA membrane, for example, exhibited...... tensile strength of 30.3 MPa at room temperature or 7.3 MPa at 130 °C and a proton conductivity of 0.14 S cm–1 at 160 °C. Fuel cell tests with H2 and air at 160 °C showed high open circuit voltage, power density and a low degradation rate of 1.5 μV h–1 at a constant load of 300 mA cm–2....

  20. Assessment of microelectronics packaging for high temperature, high reliability applications

    Energy Technology Data Exchange (ETDEWEB)

    Uribe, F.


    This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

  1. An Experimental Test Facility to Support Development of the Fluoride Salt Cooled High Temperature Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Yoder Jr, Graydon L [ORNL; Aaron, Adam M [ORNL; Cunningham, Richard Burns [University of Tennessee, Knoxville (UTK); Fugate, David L [ORNL; Holcomb, David Eugene [ORNL; Kisner, Roger A [ORNL; Peretz, Fred J [ORNL; Robb, Kevin R [ORNL; Wilgen, John B [ORNL; Wilson, Dane F [ORNL


    The need for high-temperature (greater than 600 C) energy exchange and delivery systems is significantly increasing as the world strives to improve energy efficiency and develop alternatives to petroleum-based fuels. Liquid fluoride salts are one of the few energy transport fluids that have the capability of operating at high temperatures in combination with low system pressures. The Fluoride Salt-Cooled High-Temperature Reactor design uses fluoride salt to remove core heat and interface with a power conversion system. Although a significant amount of experimentation has been performed with these salts, specific aspects of this reactor concept will require experimental confirmation during the development process. The experimental facility described here has been constructed to support the development of the Fluoride Salt Cooled High Temperature Reactor concept. The facility is capable of operating at up to 700 C and incorporates a centrifugal pump to circulate FLiNaK salt through a removable test section. A unique inductive heating technique is used to apply heat to the test section, allowing heat transfer testing to be performed. An air-cooled heat exchanger removes added heat. Supporting loop infrastructure includes a pressure control system; trace heating system; and a complement of instrumentation to measure salt flow, temperatures, and pressures around the loop. The initial experiment is aimed at measuring fluoride salt heat transfer inside a heated pebble bed similar to that used for the core of the pebble bed advanced high-temperature reactor. This document describes the details of the loop design, auxiliary systems used to support the facility, the inductive heating system, and facility capabilities.

  2. Crystal structures at high pressures and temperatures (United States)

    Caldwell, Wendel Alexander


    The diamond anvil cell (DAC) is a unique instrument that can generate pressures equivalent to those inside planetary interiors (pressures on the order of 1 million atmospheres) under sustained conditions. When combined with a bright source of collimated x-rays, the DAC can be used to probe the structure of materials in-situ at ultra-high pressures. An understanding of the high-pressure structure of materials is important in determining what types of processes may take place in the Earth at great depths. Motivated by previous studies showing that xenon becomes metallic at pressures above ˜1 megabar (100 GPa), we examined the stable structures and reactivity of xenon at pressures approaching that of the core-mantle boundary in the Earth. Our findings indicate the transformation of xenon from face-centered cubic (fcc) to hexagonal close-packed (hcp) structures is kinetically hindered at room temperature, with the equilibrium fcc--hcp phase boundary at 21 (+/-3) gigapascals, a pressure lower than was previously thought. Additionally, we find no tendency on the part of xenon to form a metal alloy with iron or platinum to at least 100 to 150 gigapascals, making it unlikely that the Earth's core serves as a reservoir for primordial xenon. Measurements of the compressibility of natural (Mg.75,Fe .25)2SiO4 gamma-spinel at pressures of the Earth's transition zone yield a pressure derivative of the bulk modulus K0 ' = 6.3 (+/-0.3). As gamma-spinel is considered to be a dominant mineral phase of the transition-zone of the Earth's mantle (400--670 km depth), the relatively high value of K0' for gamma-spinel may help explain the rapid increase with depth of seismic velocities through the transition zone. The thermodynamics, mechanisms and kinetics of pressure-induced amorphization are not well understood. We report here new studies indicating little or no entropy difference between the crystalline and glassy states of Ca(OH) 2 (portlandite). Additional work on the pressure

  3. High temperature superconductors in electromagnetic applications

    CERN Document Server

    Richens, P E


    powder-in-tube and dip-coated, have been made using a novel single loop tensometer that enables the insertion of a reasonably long length of conductor into the bore of a high-field magnet. The design, construction, and characterization of a High Temperature Superconducting (HTS) magnet is described. The design stage has involved the development of computer software for the calculation of the critical current of a solenoid wound from anisotropic HTS conductor. This calculation can be performed for a variety of problems including those involving magnetic materials such as iron by the incorporation of finite element electromagnetic analysis software. This has enabled the optimization of the magnet's performance. The HTS magnet is wound from 190 m of silver-matrix Bi sub 2 Sr sub 2 Ca sub 2 Cu sub 3 O sub 1 sub 0 powder-in-tube tape conductor supplied by Intermagnetics General Corporation. The dimensions are 70 mm bore and 70 mm length, and it consists of 728 turns. Iron end-plates were utilized in order to reduc...

  4. High-Temperature Shape Memory Alloys (United States)

    Biffi, C. A.; Tuissi, A.


    In this paper, an experimental study of laser micro-processing on a Cu-Zr-based shape memory alloy (SMA), which is suitable for high-temperature (HT) applications, is discussed. A first evaluation of the interaction between a laser beam and Zr50Cu28Ni7Co15 HT SMA is highlighted. Single laser pulses at various levels of power and pulse duration were applied to evaluate their effect on the sample surfaces. Blind and through microholes were produced with sizes on the order of a few hundreds of microns; the results were characterized from the morphological viewpoint using a scanning electron microscope. The high beam quality allows the holes to be created with good circularity and little melted material around the hole periphery. An analysis of the chemical composition was performed using energy dispersive spectroscopy, revealing that compositional changes were limited, while important oxidation occurred on the hole surfaces. Additionally, laser micro-cutting tests were also proposed to evaluate the cut edge morphology and dimensions. The main result of this paper concerned the good behavior of the material upon interaction with the laser beam, which suggests that microfeatures can be successfully produced in this alloy.

  5. High temperature superconductors at optimal doping

    Directory of Open Access Journals (Sweden)

    W. E. Pickett


    Full Text Available   Intensive study of the high temperature superconductors has been ongoing for two decades. A great deal of this effort has been devoted to the underdoped regime, where the new and difficult physics of the doped Mott insulator has met extra complications including bilayer coupling/splitting, shadow bands, and hot spots. While these complications continue to unfold, in this short overview the focus is moved to the region of actual high-Tc, that of optimal doping. The focus here also is not on the superconducting state itself, but primarily on the characteristics of the normal state from which the superconducting instability arises, and even these can be given only a broad-brush description. A reminder is given of two issues,(i why the “optimal Tc” varies,for n-layered systems it increases for n up to 3, then decreases for a given n, Tc increases according to the ‘basis’ atom in the order Bi, Tl, Hg (ii how does pressure, or a particular uniaxial strain, increase Tc when the zero-strain system is already optimally doped?

  6. The experimental investigation on the performance of a low temperature waste heat-driven multi-bed desiccant dehumidifier (MBDD) and minimization of entropy generation

    KAUST Repository

    Myat, Aung


    We present the experimental investigation on the performance of multi-bed desiccant dehumidification system (MBDD) using a thermodynamic framework with an entropy generation analysis. The cyclic steady state performance of adsorption-desorption processes at the assorted heat source temperatures, and typical ambient humidity conditions was carried out. MBDD unit uses type-RD silica gel pore surface area with of 720 m 2/g. It has a nominal diameter range of 0.4 to 0. 7 mm. The key advantages of MBDD are: (i) it has no moving parts rendering less maintenance, (ii) energy-efficient means of dehumidification by adsorption process with low temperature heat source as compared to the conventional methods, (iii) although it is a pecked bed desiccant, a laminar chamber is employed by arranging the V-shaped configuration of heat exchangers and (iv) it is environmental friendly with the low-carbon footprint. Entropy generation analysis was performed at the assorted heat source temperatures to investigate the performance of MBDD. By conducting the entropy minimization, it is now able to locate the optimal operating conditions of the system while the specific entropy generation is found to be minimal. This analysis shows that the minimization of entropy generation in the dehumidification cycle leads to the maximization of COP in the MBDD and thus, higher delivery of useful effects at the same input resources. © 2011 Elsevier Ltd. All rights reserved.

  7. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor.

    Directory of Open Access Journals (Sweden)

    Trevor James Morgan

    Full Text Available A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water. The amounts of char (organic fraction and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. The reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis and high

  8. Fast Pyrolysis Behavior of Banagrass as a Function of Temperature and Volatiles Residence Time in a Fluidized Bed Reactor. (United States)

    Morgan, Trevor James; Turn, Scott Q; George, Anthe


    A reactor was designed and commissioned to study the fast pyrolysis behavior of banagrass as a function of temperature and volatiles residence time. Four temperatures between 400 and 600°C were examined as well as four residence times between ~1.0 and 10 seconds. Pyrolysis product distributions of bio-oil, char and permanent gases were determined at each reaction condition. The elemental composition of the bio-oils and chars was also assessed. The greatest bio-oil yield was recorded when working at 450°C with a volatiles residence time of 1.4 s, ~37 wt% relative to the dry ash free feedstock (excluding pyrolysis water). The amounts of char (organic fraction) and permanent gases under these conditions are ~4 wt% and 8 wt% respectively. The bio-oil yield stated above is for 'dry' bio-oil after rotary evaporation to remove solvent, which results in volatiles and pyrolysis water being removed from the bio-oil. The material removed during drying accounts for the remainder of the pyrolysis products. The 'dry' bio-oil produced under these conditions contains ~56 wt% carbon which is ~40 wt% of the carbon present in the feedstock. The oxygen content of the 450°C, 1.4 s 'dry' bio-oil is ~38 wt%, which accounts for ~33 wt% of the oxygen in the feedstock. At higher temperature or longer residence time less bio-oil and char is recovered and more gas and light volatiles are produced. Increasing the temperature has a more significant effect on product yields and composition than increasing the volatiles residence time. At 600°C and a volatiles residence time of 1.2 seconds the bio-oil yield is ~21 wt% of the daf feedstock, with a carbon content of 64 wt% of the bio-oil. The bio-oil yield from banagrass is significantly lower than from woody biomass or grasses such as switchgrass or miscanthus, but is similar to barley straw. The reason for the low bio-oil yield from banagrass is thought to be related to its high ash content (8.5 wt% dry basis) and high concentration of alkali

  9. Geochemistry of Aluminum in High Temperature Brines

    Energy Technology Data Exchange (ETDEWEB)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.


    The objective ofthis research is to provide quantitative data on the equilibrium and thermodynamic properties of aluminum minerals required to model changes in permeability and brine chemistry associated with fluid/rock interactions in the recharge, reservoir, and discharge zones of active geothermal systems. This requires a precise knowledge of the thermodynamics and speciation of aluminum in aqueous brines, spanning the temperature and fluid composition rangesencountered in active systems. The empirical and semi-empirical treatments of the solubility/hydrolysis experimental results on single aluminum mineral phases form the basis for the ultimate investigation of the behavior of complex aluminosilicate minerals. The principal objective in FY 1998 was to complete the solubility measurements on boehmite (AIOOH) inNaC1 media( 1 .O and 5.0 molal ionic strength, IOO-250°C). However, additional measurements were also made on boehmite solubility in pure NaOH solutions in order to bolster the database for fitting in-house isopiestic data on this system. Preliminary kinetic Measurements of the dissolution/precipitation of boehmite was also carried out, although these were also not planned in the earlier objective. The 1999 objectives are to incorporate these treatments into existing codes used by the geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

  10. High Temperature Oxidation and Corrosion Properties of High Entropy Superalloys

    Directory of Open Access Journals (Sweden)

    Te-Kang Tsao


    Full Text Available The present work investigates the high temperature oxidation and corrosion behaviour of high entropy superalloys (HESA. A high content of various solutes in HESA leads to formation of complex oxides, however the Cr and Al activities of HESA are sufficient to promote protective chromia or alumina formation on the surface. By comparing the oxidation and corrosion resistances of a Ni-based superalloy—CM247LC, Al2O3-forming HESA can possess comparable oxidation resistance at 1100 °C, and Cr2O3-forming HESA can exhibit superior resistance against hot corrosion at 900 °C. This work has demonstrated the potential of HESA to maintain surface stability in oxidizing and corrosive environments.

  11. High pressure study of high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Souliou, Sofia-Michaela


    The current thesis studies experimentally the effect of high external pressure on high-T{sub c} superconductors. The structure and lattice dynamics of several members of the high-T{sub c} cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T{sub c} superconductor YBa{sub 2}Cu{sub 3}O{sub 6+x} have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa{sub 2}Cu{sub 3}O{sub 6.55} samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa{sub 2}Cu{sub 4}O{sub 8}. A clear renormalization of some of the Raman phonons is seen below T{sub c} as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B{sub 1g}-like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa{sub 2}Cu{sub 3}O{sub 6+x}. At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group

  12. Rheological assessment of nanofluids at high pressure high temperature (United States)

    Kanjirakat, Anoop; Sadr, Reza


    High pressure high temperature (HPHT) fluids are commonly encountered in industry, for example in cooling and/or lubrications applications. Nanofluids, engineered suspensions of nano-sized particles dispersed in a base fluid, have shown prospective as industrial cooling fluids due to their enhanced rheological and heat transfer properties. Nanofluids can be potentially utilized in oil industry for drilling fluids and for high pressure water jet cooling/lubrication in machining. In present work rheological characteristics of oil based nanofluids are investigated at HPHT condition. Nanofluids used in this study are prepared by dispersing commercially available SiO2 nanoparticles (~20 nm) in a mineral oil. The basefluid and nanofluids with two concentrations, namely 1%, and 2%, by volume, are considered in this investigation. The rheological characteristics of base fluid and the nanofluids are measured using an industrial HPHT viscometer. Viscosity values of the nanofluids are measured at pressures of 100 kPa to 42 MPa and temperatures ranging from 25°C to 140°C. The viscosity values of both nanofluids as well as basefluid are observed to have increased with the increase in pressure. Funded by Qatar National Research Fund (NPRP 08-574-2-239).

  13. Material Control and Accounting Design Considerations for High-Temperature Gas Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Trond Bjornard; John Hockert


    The subject of this report is domestic safeguards and security by design (2SBD) for high-temperature gas reactors, focusing on material control and accountability (MC&A). The motivation for the report is to provide 2SBD support to the Next Generation Nuclear Plant (NGNP) project, which was launched by Congress in 2005. This introductory section will provide some background on the NGNP project and an overview of the 2SBD concept. The remaining chapters focus specifically on design aspects of the candidate high-temperature gas reactors (HTGRs) relevant to MC&A, Nuclear Regulatory Commission (NRC) requirements, and proposed MC&A approaches for the two major HTGR reactor types: pebble bed and prismatic. Of the prismatic type, two candidates are under consideration: (1) GA's GT-MHR (Gas Turbine-Modular Helium Reactor), and (2) the Modular High-Temperature Reactor (M-HTR), a derivative of Areva's Antares reactor. The future of the pebble-bed modular reactor (PBMR) for NGNP is uncertain, as the PBMR consortium partners (Westinghouse, PBMR [Pty] and The Shaw Group) were unable to agree on the path forward for NGNP during 2010. However, during the technology assessment of the conceptual design phase (Phase 1) of the NGNP project, AREVA provided design information and technology assessment of their pebble bed fueled plant design called the HTR-Module concept. AREVA does not intend to pursue this design for NGNP, preferring instead a modular reactor based on the prismatic Antares concept. Since MC&A relevant design information is available for both pebble concepts, the pebble-bed HTGRs considered in this report are: (1) Westinghouse PBMR; and (2) AREVA HTR-Module. The DOE Office of Nuclear Energy (DOE-NE) sponsors the Fuel Cycle Research and Development program (FCR&D), which contains an element specifically focused on the domestic (or state) aspects of SBD. This Material Protection, Control and Accountancy Technology (MPACT) program supports the present work

  14. High-temperature high-pressure gas cleanup with ceramic bag filters. Draft final report

    Energy Technology Data Exchange (ETDEWEB)

    Shackleton, M.; Chang, R.; Sawyer, J.; Kuby, W.; Turner-Tamiyasu, E.


    Advanced processes designed for the efficient use of coal in the production of energy will benefit from, or even depend upon, highly efficient, economical, high-temperature removal systems for fine particulates. In the case of pressurized fluidized-bed combustion (PFBC), the hot gas cleanup device must operate at approximately 1600/sup 0/F. Existing commercial filter systems are temperature limited due to the filter material, but ceramic fibers intended for refractory insulation offer the promise of a practical high-temperature filter media if they can be incorporated into a design which combines filter performance with acceptable durability. The current work was initiated to further develop and demonstrate on a larger-scale basis, a ceramic fiber filtration system for application to coal-fired PFBC's. The development effort centered around the need to replace the knit metal wire scrim, used in earlier designs as support for the fine fiber ceramic mat filtration medium, with a corrosion-resistant material. This led to the selection of woven ceramic cloth for support of the mat layer. Because of the substantial difference in strength and other material properties between the metal and ceramic cloth, tests were necessary to optimize the filter; pulse parameters such as pulse duration, pulse pressure, and pulse injection orifice size; woven cloth mesh configuration; the technique for clamping the bag to the support; and similar structural, fluid, and control parameters. The demonstration effort included both tests to prove this concept in a real application and a systems analysis to show commercial feasibility of the ceramic filtration approach for hot gas cleanup in PFBC's. 12 references, 57 figures, 23 tables.

  15. Laser Brazing of High Temperature Braze Alloy (United States)

    Gao, Y. P.; Seaman, R. F.; McQuillan, T. J.; Martiens, R. F.


    The Space Shuttle Main Engine (SSME) consists of 1080 conical tubes, which are furnace brazed themselves, manifolds, and surrounding structural jacket making almost four miles of braze joints. Subsequent furnace braze cycles are performed due to localized braze voids between the coolant tubes. SSME nozzle experiences extremely high heat flux (180 mW/sq m) during hot fire. Braze voids between coolant tubes may result in hot combustion gas escape causing jacket bulges. The nozzle can be disqualified for flight or result in mission failure if the braze voids exceed the limits. Localized braze processes were considered to eliminate braze voids, however, damage to the parent materials often prohibited use of such process. Being the only manned flight reusable rocket engine, it has stringent requirement on the braze process. Poor braze quality or damage to the parent materials limits the nozzle service life. The objective of this study was to develop a laser brazing process to provide quality, localized braze joints without adverse affect on the parent materials. Gold (Au-Cu-Ni-Pd-Mn) based high temperature braze alloys were used in both powder and wire form. Thin section iron base superalloy A286 tube was used as substrate materials. Different Laser Systems including CO2 (10.6 micrometers, 1kW), ND:YAG (1.06 micrometers, 4kW). and direct diode laser (808nm. 150W) were investigated for brazing process. The laser process variables including wavelength. laser power, travel speed and angle of inclination were optimized according to bead geometry and braze alloy wetting at minimum heat input level, The properties of laser brazing were compared to that of furnace brazing. Microhardness profiles were used for braze joint property comparison between laser and furnace brazing. The cooling rate of laser brazing was compared to furnace brazing based on secondary dendritic arm spacing, Both optical and Scanning Electron Microscope (SEM) were used to evaluate the microstructures of


    Energy Technology Data Exchange (ETDEWEB)

    Hemrick, James Gordon [ORNL; Smith, Jeffrey D [ORNL; O' Hara, Kelley [University of Missouri, Rolla; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.


    A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new

  17. Analytic Models of High-Temperature Hohlraums

    Energy Technology Data Exchange (ETDEWEB)

    Stygar, W.A.; Olson, R.E.; Spielman, R.B.; Leeper, R.J.


    A unified set of high-temperature-hohlraum models has been developed. For a simple hohlraum, P{sub s} = [A{sub s}+(1{minus}{alpha}{sub W})A{sub W}+A{sub H}]{sigma}T{sub R}{sup 4} + (4V{sigma}/c)(dT{sub R}{sup r}/dt) where P{sub S} is the total power radiated by the source, A{sub s} is the source area, A{sub W} is the area of the cavity wall excluding the source and holes in the wall, A{sub H} is the area of the holes, {sigma} is the Stefan-Boltzmann constant, T{sub R} is the radiation brightness temperature, V is the hohlraum volume, and c is the speed of light. The wall albedo {alpha}{sub W} {triple_bond} (T{sub W}/T{sub R}){sup 4} where T{sub W} is the brightness temperature of area A{sub W}. The net power radiated by the source P{sub N} = P{sub S}-A{sub S}{sigma}T{sub R}{sup 4}, which suggests that for laser-driven hohlraums the conversion efficiency {eta}{sub CE} be defined as P{sub N}/P{sub LASER}. The characteristic time required to change T{sub R}{sup 4} in response to a change in P{sub N} is 4V/C[(l{minus}{alpha}{sub W})A{sub W}+A{sub H}]. Using this model, T{sub R}, {alpha}{sub W}, and {eta}{sub CE} can be expressed in terms of quantities directly measurable in a hohlraum experiment. For a steady-state hohlraum that encloses a convex capsule, P{sub N} = {l_brace}(1{minus}{alpha}{sub W})A{sub W}+A{sub H}+[(1{minus}{alpha}{sub C})(A{sub S}+A{sub W}{alpha}{sub W})A{sub C}/A{sub T}]{r_brace}{sigma}T{sub RC}{sup 4} where {alpha}{sub C} is the capsule albedo, A{sub C} is the capsule area, A{sub T} {triple_bond} (A{sub S}+A{sub W}+A{sub H}), and T{sub RC} is the brightness temperature of the radiation that drives the capsule. According to this relation, the capsule-coupling efficiency of the baseline National-Ignition-Facility (NIF) hohlraum is 15% higher than predicted by previous analytic expressions. A model of a hohlraum that encloses a z pinch is also presented.

  18. Model for high rate gas flows in deformable and reactive porous beds

    Energy Technology Data Exchange (ETDEWEB)

    Weston, A M


    This report presents the development of a one dimensional planar Lagrange hydrodynamic computer model which describes the processes preceding detonation. The model treats gas flow, deflagration, and compaction in a porous bed of reactive material. The early part of deflagration to detonation experiment with porous HMX is simulated. Sensitivity of the simulation calculation to ignition and burn rate parameters is illustrated and discussed. The effects of changing the mean particle size of the porous material are investigated. There is widespread interest in runaway reaction hazards that may be associated with porosity in propellant and explosive materials. Experimentally, such reactions are initiated and observed in long, thick walled hollow tubes, filled with a granular porous bed of reactive material. We will present comparisons with an experiment on porous HMX to illustrate details of the model and to point out what we believe are important features of the observed phenomenon. A geometric finite element cell is devised that allows gas to flow through a compacting matrix. The experimental simulation considers the DDT process from initial squib burn through the onset of general matrix deflagration (convective burning), to the development of a fully dense compaction wave. While this simulation did not calculate turnover to detonation, it did illustrate that the transition occurred as soon as the compaction wave became fully dense. It is shown that deflagration and gas permeation lags compaction at the time of transition. This suggests that the actual transition involves an additional compaction dependent process. 18 references, 20 figures, 3 tables.

  19. Measuring Specific Heats at High Temperatures (United States)

    Vandersande, Jan W.; Zoltan, Andrew; Wood, Charles


    Flash apparatus for measuring thermal diffusivities at temperatures from 300 to 1,000 degrees C modified; measures specific heats of samples to accuracy of 4 to 5 percent. Specific heat and thermal diffusivity of sample measured. Xenon flash emits pulse of radiation, absorbed by sputtered graphite coating on sample. Sample temperature measured with thermocouple, and temperature rise due to pulse measured by InSb detector.

  20. High Temperature Electrical Insulation Materials for Space Applications Project (United States)

    National Aeronautics and Space Administration — NASA's future space science missions cannot be realized without the state of the art high temperature insulation materials of which higher working temperature, high...

  1. High-temperature archeointensity measurements from Mesopotamia (United States)

    Gallet, Yves; Le Goff, Maxime


    We present new archeointensity results obtained from 127 potsherds and baked brick fragments dated from the last four millennia BC which were collected from different Syrian archeological excavations. High temperature magnetization measurements were carried out using a laboratory-built triaxial vibrating sample magnetometer (Triaxe), and ancient field intensity determinations were derived from the experimental procedure described by Le Goff and Gallet [Le Goff and Gallet. Earth Planet. Sci. Lett. 229 (2004) 31-43]. As some of the studied samples were previously analyzed using the classical Thellier and Thellier [Thellier and Thellier . Ann. Geophys. 15 (1959) 285-376] method revised by Coe [Coe. J. Geophys. Res. 72 (1967) 3247-3262], a comparison of the results is made from the two methods. The differences both at the fragment and site levels are mostly within ± 5%, which strengthens the validity of the experimental procedure developed for the Triaxe. The new data help to better constrain the geomagnetic field intensity variations in Mesopotamia during archeological times, with the probable occurrence of an archeomagnetic jerk around 2800-2600 BC.

  2. Development of Strengthened Bundle High Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Lue, J.W.; Lubell, M.S. [Oak Ridge National Lab., TN (United States); Demko, J.A. [Oak Ridge Inst. for Science and Education, TN (United States); Tomsic, M. [Plastronic, Inc., Troy, OH (United States); Sinha, U. [Southwire Company, Carollton, GA (United States)


    In the process of developing high temperature superconducting (HTS) transmission cables, it was found that mechanical strength of the superconducting tape is the most crucial property that needs to be improved. It is also desirable to increase the current carrying capacity of the conductor so that fewer layers are needed to make the kilo-amp class cables required for electric utility usage. A process has been developed by encapsulating a stack of Bi-2223/Ag tapes with a silver or non-silver sheath to form a strengthened bundle superconductor. This process was applied to HTS tapes made by the Continuous Tube Forming and Filling (CTFF) technique pursued by Plastronic Inc. and HTS tapes obtained from other manufacturers. Conductors with a bundle of 2 to 6 HTS tapes have been made. The bundled conductor is greatly strengthened by the non-silver sheath. No superconductor degradation as compared to the sum of the original critical currents of the individual tapes was seen on the finished conductors.

  3. High temperature bacterial leaching: HIOX project

    Energy Technology Data Exchange (ETDEWEB)

    Morin, D.; D' Hugues, P.; Bonney, C. F.; Norris, P.; Shwab, W.; Sundkvist, J-E.; Bridges, P. [Bureau de Recherhes Geologiques et Minieres, Orleans (France)


    The HIOX project was designed to investigate the use of thermophilic bacterial cultures for the leaching of chalcopyrite (CuFeS{sub 2}, the natural source of copper). Beyond bacterial leaching, the study also encompassed the downstream processing steps in an effort to develop a new method for the recovery of copper in an economical and environmentally-friendly process. Using the HIOX process copper recovery was increased to better than 90 per cent within 5 days with a 12 per cent solids culture, although some potentially limiting factors such as foam generation, nutrient concentrations and mixing/aeration efficiency were also identified. The study resulted in the establishment of a mass balance based on a simplified flowsheet of the process. Techno-economic evaluation carried out at three sites indicated technical feasibility using relatively conventional equipment and capital and operating costs in ranges that suggest that bioleaching with high temperature bacteria is an attractive alternative for the treatment of chalcopyrite concentrate. 5 tabs.

  4. Electronic phase separation and high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kivelson, S.A. [Univ. of California, Los Angeles, CA (United States). Dept. of Physics; Emery, V.J. [Brookhaven National Lab., Upton, NY (United States)


    The authors review the extensive evidence from model calculations that neutral holes in an antiferromagnet separate into hole-rich and hole-poor phases. All known solvable limits of models of holes in a Heisenberg antiferromagnet exhibit this behavior. The authors show that when the phase separation is frustrated by the introduction of long-range Coulomb interactions, the typical consequence is either a modulated (charge density wave) state or a superconducting phase. The authors then review some of the strong experimental evidence supporting an electronically-driven phase separation of the holes in the cuprate superconductors and the related Ni oxides. Finally, the authors argue that frustrated phase separation in these materials can account for many of the anomalous normal state properties of the high temperature superconductors and provide the mechanism of superconductivity. In particular, it is shown that the T-linear resistivity of the normal state is a paraconductivity associated with a novel composite pairing, although the ordered superconducting state is more conventional.

  5. Spin injection into high temperature superconductor

    CERN Document Server

    Severac, C H L


    DELTA M versus pulse length was measured. It showed two regions: above 100 mu s DELTA M is the same for both magnetic and non-magnetic material and can be attributed to heating. Below 100 mu s, DELTA M is only significant for the CMR samples. This is attributed to the injection of highly spin polarised carriers that are believed to reduce the order parameter over the whole sample, and hence l sub C and the magnetic moment of the sample. As part of a search for colossal magneto-resistance (CMR) materials with Curie temperature below the superconducting transition of YBCO, we made an investigation of the magnetic and electrical characteristics of Chromium doped LCMO. We found that the conduction mechanism which depends on the orbital order via the double-exchange mechanism, is decoupled from the ferromagnetic behaviour, which is related to spin order. Work on the injection of dc-current from half metallic CMR material into YBa sub 2 Cu sub 3 O sub 7 sub - subdelta (YBCO) showed a shift and a compression in the ...

  6. High temperature superconductivity induced by incipient magnetism (United States)

    Weger, M.; Pereg, Y.


    We consider the BCS gap equation, with an attractive interaction λ with an upper cutoff ω 0 and lower cutoff ω 1, and a repulsive interaction μ with cutoffΓ. We consider parameters such that a superconducting solution does not exist. We add a repulsive interaction ν eith cutoff ω1 ( ω1 < ω0), and show that this repulsive interaction (that we attribute to incipient magnetism) induces a superconducting state possessing a high transition temperature. In this state, the gap function Δ(ɛ) oscillates as function of ɛ, with a period of order ω 0. We also find solutions antisymmetric in energy [ Δ( ɛ) = - Δ(- ɛ) ], which turn out to be almost degenerate with the normal, symmetric ones. We discuss the physical implications of this model. Our model thus combines a low frequency repulsion due to antiferromagnetic interactions, with excitonic attraction at intermediate frequencies, and ordinary Coulomb repulsion above that. All frequency ranges, and coupling strengths, are comparable with the bandwidth.

  7. Turbulent Flow past High Temperature Surfaces (United States)

    Mehmedagic, Igbal; Thangam, Siva; Carlucci, Pasquale; Buckley, Liam; Carlucci, Donald


    Flow over high-temperature surfaces subject to wall heating is analyzed with applications to projectile design. In this study, computations are performed using an anisotropic Reynolds-stress model to study flow past surfaces that are subject to radiative flux. The model utilizes a phenomenological treatment of the energy spectrum and diffusivities of momentum and heat to include the effects of wall heat transfer and radiative exchange. The radiative transport is modeled using Eddington approximation including the weighted effect of nongrayness of the fluid. The time-averaged equations of motion and energy are solved using the modeled form of transport equations for the turbulence kinetic energy and the scalar form of turbulence dissipation with an efficient finite-volume algorithm. The model is applied for available test cases to validate its predictive capabilities for capturing the effects of wall heat transfer. Computational results are compared with experimental data available in the literature. Applications involving the design of projectiles are summarized. Funded in part by U.S. Army, ARDEC.

  8. High-temperature spreading kinetics of metals

    Energy Technology Data Exchange (ETDEWEB)

    Rauch, N.


    In this PhD work a drop transfer setup combined with high speed photography has been used to analyze the spreading of Ag on polished polycrystalline Mo and single crystalline Mo (110) and (100) substrates. The objective of this work was to unveil the basic phenomena controlling spreading in metal-metal systems. The observed spreading kinetics were compared with current theories of low and high temperature spreading such as a molecular kinetic model and a fluid flow model. Analyses of the data reveal that the molecular model does describe the fastest velocity data well for all the investigated systems. Therefore, the energy which is dissipated during the spreading process is a dissipation at the triple line rather than dissipation due to the viscosity in the liquid. A comparison of the determined free activation energy for wetting of {delta}G95{approx}145kJ/mol with literature values allows the statement that the rate determining step seems to be a surface diffusion of the Ag atoms along the triple line. In order to investigate possible ridge formation, due to local atomic diffusion of atoms of the substrate at the triple during the spreading process, grooving experiments of the polycrystalline Mo were performed to calculate the surface diffusities that will control ridge evolution. The analyses of this work showed that a ridge formation at the fastest reported wetting velocities was not possible if there is no initial perturbation for a ridge. If there was an initial perturbation for a ridge the ridge had to be much smaller than 1 nm in order to be able to move with the liquid font. Therefore ridge formation does not influence the spreading kinetics for the studied system and the chosen conditions. SEM, AFM and TEM investigations of the triple line showed that ridge formation does also not occur at the end of the wetting experiment when the drop is close to equilibrium and the wetting velocity is slow. (orig.)

  9. Thermoelectric Powered High Temperature Wireless Sensing (United States)

    Kucukkomurler, Ahmet

    This study describes use of a thermoelectric power converter to transform waste heat into electrical energy to power an RF receiver and transmitter, for use in harsh environment wireless temperature sensing and telemetry. The sensing and transmitting module employs a DS-1820 low power digital temperature sensor to perform temperature to voltage conversion, an ATX-34 RF transmitter, an ARX-34 RF receiver module, and a PIC16f84A microcontroller to synchronize data communication between them. The unit has been tested in a laboratory environment, and promising results have been obtained for an actual automotive wireless under hood temperature sensing and telemetry implementation.

  10. Vortices in high-performance high-temperature superconductors (United States)

    Kwok, Wai-Kwong; Welp, Ulrich; Glatz, Andreas; Koshelev, Alexei E.; Kihlstrom, Karen J.; Crabtree, George W.


    The behavior of vortex matter in high-temperature superconductors (HTS) controls the entire electromagnetic response of the material, including its current carrying capacity. Here, we review the basic concepts of vortex pinning and its application to a complex mixed pinning landscape to enhance the critical current and to reduce its anisotropy. We focus on recent scientific advances that have resulted in large enhancements of the in-field critical current in state-of-the-art second generation (2G) YBCO coated conductors and on the prospect of an isotropic, high-critical current superconductor in the iron-based superconductors. Lastly, we discuss an emerging new paradigm of critical current by design—a drive to achieve a quantitative correlation between the observed critical current density and mesoscale mixed pinning landscapes by using realistic input parameters in an innovative and powerful large-scale time dependent Ginzburg-Landau approach to simulating vortex dynamics.

  11. Vortices in high-performance high-temperature superconductors. (United States)

    Kwok, Wai-Kwong; Welp, Ulrich; Glatz, Andreas; Koshelev, Alexei E; Kihlstrom, Karen J; Crabtree, George W


    The behavior of vortex matter in high-temperature superconductors (HTS) controls the entire electromagnetic response of the material, including its current carrying capacity. Here, we review the basic concepts of vortex pinning and its application to a complex mixed pinning landscape to enhance the critical current and to reduce its anisotropy. We focus on recent scientific advances that have resulted in large enhancements of the in-field critical current in state-of-the-art second generation (2G) YBCO coated conductors and on the prospect of an isotropic, high-critical current superconductor in the iron-based superconductors. Lastly, we discuss an emerging new paradigm of critical current by design-a drive to achieve a quantitative correlation between the observed critical current density and mesoscale mixed pinning landscapes by using realistic input parameters in an innovative and powerful large-scale time dependent Ginzburg-Landau approach to simulating vortex dynamics.

  12. High performance internal reforming unit for high temperature fuel cells (United States)

    Ma, Zhiwen; Venkataraman, Ramakrishnan; Novacco, Lawrence J.


    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  13. Transfer Function Modeling Method of Bed Temperature Based on Swarm Intelligence Algorithm in Circulating Fluidized Bed Boiler%循环流化床锅炉床温的传递函数智能建模方法

    Institute of Scientific and Technical Information of China (English)

    王利杰; 孙明; 程希; 殷立国; 孙剑


    通过研究循环流化床锅炉燃烧系统的机理和非参数建模方法,基于对循环流化态燃烧机理的认知,给出模型辨识的数据选择标准;挖掘机组运行的历史数据,提出了利用群体智能寻优算法进行燃料量与床温之间传递函数的参数辨识方法,并给出了快速仿真的公式以及一类单输入单输出系统的辨识结果和验证方法。所建立的传递函数模型完全能够表征具体某台循环流化床锅炉热工特性,为后续的控制逻辑和控制器的优化提供了数学依据。%This paper summarized two methods which include mechanism and non-parametric modeling in the cir-culating fluidized bed ( CFB) boiler's combustion system. Based on the understanding of combustion principle of circulating fluidized state, the criterion of data selection was given. By mining the historical datas of unit operation, a method of identifying undetermined parameters of the transfer function between fuel and bed temperature using the swarm intelligence optimizing algorithms was presented. Then, the rapid simulation formulas of thermal process and identification result and validation method of a class of single-input single-output system were given. Transfer func-tion which was established by this method can entirely represent the thermal characteristics of CFB boiler and pro-vide a mathematical basis for subsequent control logic or parameter's optimization of controller.

  14. Critical Temperature Characteristics of Layered High-Temperature Superconductor Under Pressure

    Institute of Scientific and Technical Information of China (English)

    LIANG Fang-Ying


    We consider a Ginzburg-Landau modified model of layered high-temperature superconductor under pres-sure. We have theoretically studied the relation between the pressure and the temperature of layered high-temperature superconductor. If the pressure is not a constant, we have a relation of quadratic equation between the pressure and the temperature of layered high-temperature superconductor. In a special case, we find the critical temperature decreases with further increasing pressure. In another special case, the critical temperature increases with further increasing pressure.

  15. Porosity Effect in the Core Thermal Hydraulics for Ultra High Temperature Gas-cooled Reactor

    Directory of Open Access Journals (Sweden)

    Motoo Fumizawa


    Full Text Available This study presents an experimental method of porosity evaluation and a predictive thermal-hydraulic analysis with packed spheres in a nuclear reactor core. The porosity experiments were carried out in both a fully shaken state with the closest possible packing and in a state of non-vibration. The predictive analysis considering the fixed porosity value was applied as a design condition for an Ultra High Temperature Reactor Experiment (UHTREX. The thermal-hydraulic computer code was developed and identified as PEBTEMP. The highest outlet coolant temperature of 1316 oC was achieved in the case of an UHTREX at Los Alamos Scientific Laboratory, which was a small scale UHTR. In the present study, the fuel was changed to a pebble type, a porous media. In order to compare the present pebble bed reactor and UHTREX, a calculation based on HTGR-GT300 was carried out in similar conditions with UHTREX; in other words, with an inlet coolant temperature of 871oC, system pressure of 3.45 MPa and power density of 1.3 w/cm3. As a result, the fuel temperature in the present pebble bed reactor showed an extremely lower value compared to that of UHTREX.

  16. Multi-Scale Porous Ultra High Temperature Ceramics (United States)


    Final 3. DATES COVERED (From - To) 28-Mar-2013 - 27-Sep-2015 4. TITLE AND SUBTITLE Multi-Scale Porous Ultra High Temperature Ceramics summarizes the main outcomes of research to develop multi-scale porosity Ultra High Temperature Ceramic materials. Processing conditions 15. SUBJECT TERMS Ultra High Temperature Ceramics , Colloidal Powder Processing, Multi-scale Porous Materials, Lattice Monte

  17. Structural integrity and life extension of high-temperature components

    Institute of Scientific and Technical Information of China (English)

    WANG Chun; SHEN Shi-ming


    Four different topics for high-temperature components, namely the development of the assessment codes for the structural integrity of high-temperature components, the application of continuous damage mechanics and probabilistic damage mode on the life assessment of high-temperature components, the life extension for high-tem perature components and a proposed strategy for remanufacturing of high-temperature components were discussed in this paper. These topics should provide some important insights for the design and re-design of high- temperature components.

  18. Evaluation of proposed German safety criteria for high-temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Barsell, A.W.


    This work reviews proposed safety criteria prepared by the German Bundesministerium des Innern (BMI) for future licensing of gas-cooled high-temperature reactor (HTR) concepts in the Federal Republic of Germany. Comparison is made with US General Design Criteria (GDCs) in 10CFR50 Appendix A and with German light water reactor (LWR) criteria. Implications for the HTR design relative to the US design and safety approach are indicated. Both inherent characteristics and design features of the steam cycle, gas turbine, and process heat concepts are taken into account as well as generic design options such as a pebble bed or prismatic core.

  19. Characteristics and utilisation of high-temperature (HTHP) filter dusts from pfb gasification of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Ranta, J. [VTT Energy, Espoo (Finland)


    The aim of the study was to survey characteristics, utilisation and possible environmental impacts of solid wastes, i.e., in case of biomass, mainly high-temperature filter ash (HTHP) from pressurised fluidised-bed gasification (PFBG). The aim is to utilise solid wastes (slag, filter dust, additives) from biomass gasification instead of dumping. One alternative is recycling to the soil as liming material or fertiliser. It is expected that the ash recycled to forest soils changes the environment less than non-recycled ash. (orig.) 3 refs.

  20. Effect of high sodium intake during 14 days of bed-rest on acid-base balance (United States)

    Frings, P.; Baecker, N.; Heer, M.

    Lowering mechanical load like in microgravity is the dominant stimulus leading to bone loss However high dietary sodium intake is also considered as a risk factor for osteoporosis and thereby might exacerbate the microgravity induced bone loss In a metabolic balance non bed-rest study we have recently shown that a very high sodium intake leads to an increased bone resorption most likely because of a mild metabolic acidosis Frings et al FASEB J 19 5 A1345 2005 To test if mild metabolic acidosis also occurs during immobilization we examined the effect of increased dietary sodium on bone metabolism and acid-base balance in eight healthy male test subjects mean age 26 25 pm 3 49 years body weight 77 98 pm 4 34 kg in our metabolic ward during a 14-day head-down tilt HDT bed-rest study The study was designed as a randomized crossover study with two study periods Each period was divided into three parts 4 ambulatory days with 200 mmol sodium intake 14 days of bed-rest with either 550 mmol or 50 mmol sodium intake and 3 recovery days with 200 mmol sodium intake The sodium intake was altered by variations in dietary sodium chloride content Blood pH P CO2 and P O2 were analyzed in fasting morning fingertip blood samples several times during the entire study Bicarbonate HCO 3 - and base excess BE were calculated according to the Henderson-Hasselbach equation Preliminary results in the acid-base balance from the first study period 4 subjects with 550 mmol and 4 subjects with 50 mmol sodium intake strongly

  1. High-rate hydrogenotrophic denitrification in a fluidized-bed biofilm reactor using solid-polymer-electrolyte membrane electrode (SPEME). (United States)

    Komori, M; Sakakibara, Y


    A fluidized-bed biofilm reactor equipped with a Solid-Polymer-Electrolyte Membrane Electrode (SPEME) cell was developed in order to enhance hydrogenotrophic denitrification of groundwater. Porous cubes made of polyvinylalcohol (PVA) were used as a biofilm carrier and continuous treatments using synthetic groundwater were carried out for 105 days. Electric current was changed step-wise from 0.4 to 4.0 A. Experimental results showed that efficient production and dissolution of hydrogen were achieved by application of electric current as well as high-rate denitrification simultaneously. Denitrification rates of nitrite increased with the increase of electric current. Overall denitrification rates attained to about 90 mg-N/L/h, which was 3 to 9 times as high as those reported in former studies. Supplying electric current of about two times of stoichiometric equivalent to the cell considered necessary for complete denitrification. Water quality in effluent was very stable and electrolytic voltage was low around 3 V. In addition, simple and secure operation was demonstrated over the experiment. From these results, it was concluded that the present fluidized-bed biofilm reactor equipped with a SPEME cell could be very feasible for high-rate hydrogenotrophic denitrification of ground water.

  2. Evaluation by respirometry of the loading capacity of a high rate vermicompost bed for treating sewage sludge. (United States)

    Clarke, William P; Taylor, Michael; Cossins, Rowan


    This study examines high rate vermicomposting of sewage sludge using high stocking densities of earthworms. To examine the loading capacity, two vermicompost beds were established in identical 0.84 m diameter reactors, one loaded at an average rate of 10 kg-wet-sludge-mixture m(-2) day(-1) (0.5 kg-carbon m(-2) day(-1)), the other loaded at 20 kg-wet-sludge-mixture m(-2) day(-1) (1 kg-carbon m(-2) day(-1)). The sludge mixture was from a commercial vermicomposting company (Vermitech) and contained 80-90% sludge and 10-20% green waste and clay. The beds were operated in fed-batch mode for 38 days, and then monitored for a further 12 days without any further sludge loading. Earthworms (Eisenia fetida) were added once or twice weekly over the 38 days loading period to gradually decrease the ratio of sludge loading rate to total earthworm biomass. By adding earthworm incrementally, the feeding rate ranged from 3.9 to 1.25 kg-wet-sludge kg-earthworm(-1) day(-1) for the full load experiment and 2-0.62 kg-wet-sludge kg-earthworm(-1) day(-1) for the half load experiment. The extent of degradation was estimated by fitting a 1st order model to the CO2 production rate from the beds. Based on the 1st order model, 53+/-20% (95% CI) and 68+/-4% of the organic carbon was converted to CO2 -C in the full load and half load experiments respectively. The CO2 production rate in the half load experiment became stable and repeatable when the total earthworm biomass reached 5.4 kg, corresponding to a feed rate of 1.04 kg-wet-sludge-mixture kg-earthworm(-1) day(-1). In contrast, the rate of CO2 production was still climbing and traces of methane were evident in the full load experiment at the end of the 38 day loading period. The experiments indicate that high rate vermicomposting beds are sustainable providing the feeding rate does not exceed approximately 1 kg-wet-sludge kg-earthworm(-1) day(-1).

  3. Ultra-High Temperature Distributed Wireless Sensors

    Energy Technology Data Exchange (ETDEWEB)

    May, Russell; Rumpf, Raymond; Coggin, John; Davis, Williams; Yang, Taeyoung; O' Donnell, Alan; Bresnahan, Peter


    Research was conducted towards the development of a passive wireless sensor for measurement of temperature in coal gasifiers and coal-fired boiler plants. Approaches investigated included metamaterial sensors based on guided mode resonance filters, and temperature-sensitive antennas that modulate the frequency of incident radio waves as they are re-radiated by the antenna. In the guided mode resonant filter metamaterial approach, temperature is encoded as changes in the sharpness of the filter response, which changes with temperature because the dielectric loss of the guided mode resonance filter is temperature-dependent. In the mechanically modulated antenna approach, the resonant frequency of a vibrating cantilever beam attached to the antenna changes with temperature. The vibration of the beam perturbs the electrical impedance of the antenna, so that incident radio waves are phase modulated at a frequency equal to the resonant frequency of the vibrating beam. Since the beam resonant frequency depends on temperature, a Doppler radar can be used to remotely measure the temperature of the antenna. Laboratory testing of the guided mode resonance filter failed to produce the spectral response predicted by simulations. It was concluded that the spectral response was dominated by spectral reflections of radio waves incident on the filter. Laboratory testing of the mechanically modulated antenna demonstrated that the device frequency shifted incident radio waves, and that the frequency of the re-radiated waves varied linearly with temperature. Radio wave propagation tests in the convection pass of a small research boiler plant identified a spectral window between 10 and 13 GHz for low loss propagation of radio waves in the interior of the boiler.

  4. NOvel Refractory Materials for High Alkali, High Temperature Environments

    Energy Technology Data Exchange (ETDEWEB)

    Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)


    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  5. Fusion reactors-high temperature electrolysis (HTE)

    Energy Technology Data Exchange (ETDEWEB)

    Fillo, J.A. (ed.)


    Results of a study to identify and develop a reference design for synfuel production based on fusion reactors are given. The most promising option for hydrogen production was high-temperature electrolysis (HTE). The main findings of this study are: 1. HTE has the highest potential efficiency for production of synfuels from fusion; a fusion to hydrogen energy efficiency of about 70% appears possible with 1800/sup 0/C HTE units and 60% power cycle efficiency; an efficiency of about 50% possible with 1400/sup 0/C HTE units and 40% power cycle efficiency. 2. Relative to thermochemical or direct decomposition methods HTE technology is in a more advanced state of development, 3. Thermochemical or direct decomposition methods must have lower unit process or capital costs if they are to be more attractive than HTE. 4. While design efforts are required, HTE units offer the potential to be quickly run in reverse as fuel cells to produce electricity for restart of Tokamaks and/or provide spinning reserve for a grid system. 5. Because of the short timescale of the study, no detailed economic evaluation could be carried out.A comparison of costs could be made by employing certain assumptions. For example, if the fusion reactor-electrolyzer capital installation is $400/(KW(T) ($1000/KW(E) equivalent), the H/sub 2/ energy production cost for a high efficiency (about 70 %) fusion-HTE system is on the same order of magnitude as a coal based SNG plant based on 1976 dollars. 6. The present reference design indicates that a 2000 MW(th) fusion reactor could produce as much at 364 x 10/sup 6/ scf/day of hydrogen which is equivalent in heating value to 20,000 barrels/day of gasoline. This would fuel about 500,000 autos based on average driving patterns. 7. A factor of three reduction in coal feed (tons/day) could be achieved for syngas production if hydrogen from a fusion-HTE system were used to gasify coal, as compared to a conventional syngas plant using coal-derived hydrogen.

  6. Rock bed heat accumulators. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Riaz, M.


    The principal objectives of the research program on rock bed heat accumulators (or RBHA) are: (1) to investigate the technical and economic feasibility of storing large amounts of thermal energy (in the tens of MWt range) at high temperature (up to 500/sup 0/C) over extended periods of time (up to 6 months) using native earth or rock materials; (2) to conduct studies to establish the performance characteristics of large rock bed heat accumulators at various power and temperature levels compatible with thermal conversion systems; and (3) to assess the materials and environmental problems associated with the operation of such large heat accumulators. Results of the study indicate that rock bed heat accumulators for seasonal storage are both technically and economically feasible, and hence could be exploited in various applications in which storage plays an essential role such as solar power and total energy systems, district and cogeneration heating systems.

  7. High-Temperature, High-Concentration Solar Thermoelectric Generators (United States)

    Warren, Emily; Baranowski, Lauryn; Olsen, Michele; Ndione, Paul; Netter, Judy; Goodrich, Alan; Gray, Matthew; Parilla, Philip; Ginley, David; Toberer, Eric


    Solar thermoelectric generators (STEGs) powered with concentrated solar energy have potential for use as primary energy converters or as topping-cycles for more conventional concentrated solar power (CSP) technologies. Modeling based on current record modules from JPL suggests thermoelectric efficiencies of 18 % could be experimentally expected with a temperature gradient of 1000 - 100°C. Integrating these state-of-the-art TEGs with a concentrating solar receiver requires simultaneous optimization of optical, thermal, and thermoelectric systems. This talk will discuss the modeling, design, and experimental testing of STEG devices under concentrated sunlight. We have developed a model that combines thermal circuit modeling with optical ray tracing to design selective absorber coatings and cavities to minimize radiation losses from the system. We have fabricated selective absorber coatings and demonstrated that these selective absorber films can minimize blackbody radiation losses at high temperature and are stable after thermal cycling to 1000°C. On-sun testing of STEG devices and thermal simulators is ongoing and preliminary results will be discussed.

  8. Extreme Environment High Temperature Communication Systems Project (United States)

    National Aeronautics and Space Administration — The purpose of this project is to develop and demonstrate a communications system capable of operation at extreme temperatures and pressures in hostile and corrosive...

  9. High Temperature Acoustic Noise Reduction Materials Project (United States)

    National Aeronautics and Space Administration — The proposed innovation is to use combustion synthesis techniques to manufacture ceramic-based acoustic liners capable of withstanding temperatures up to 2500?C....

  10. High temperature cement raw meal flowability

    DEFF Research Database (Denmark)

    Maarup, Claus; Hjuler, Klaus; Dam-Johansen, Kim


    The flowability of cement raw meal is investigated at temperatures up to 850°C in a specially designed monoaxial shear tester. Consolidation stresses of 0.94, 1.87 and 2.79kPa are applied. The results show that the flowability is reduced as temperature is increased above 550°C, indicated by incre......The flowability of cement raw meal is investigated at temperatures up to 850°C in a specially designed monoaxial shear tester. Consolidation stresses of 0.94, 1.87 and 2.79kPa are applied. The results show that the flowability is reduced as temperature is increased above 550°C, indicated...


    Directory of Open Access Journals (Sweden)

    A. N. Krutilin


    Full Text Available The results of investigations of physical-mechanical characteristics of cast iron slugs, received by semicontinuos way of casting, at temperatures from 850 up to 1100^ С are given. 

  12. Brittle Materials Design, High Temperature Gas Turbine (United States)


    74R 75P1 Si3Nu Density ASTM C373 -56 Green Strength 3 Point MOR L = 1-1/8" Mold Shrinkage Direct Measurement Viscosity ASTM D1238-73...Spiral Flow ASTM D3123-72 Test conditions Material temperature = 200 F Die temperature = 90 F Injection Pressure 1750 psi One Piece Stator be approximately ASTM #5 (approximately 0.060 mm average characteristic length). A gauge can yield meaningful data by averaging the

  13. High Temperature Reactive Thermoplastic Aromatic Polyimides (United States)


    temperatures and isothermal aging studies of the polymer, as well as, Dr. E. G. Jones for mass spectra TGA analysis . iii AFWAL-TR-80-4013 TABLE OF CONTENTS...after 200 hours (Figure 6). Mass spectra TGA analysis was carried out on polymer VIIIb from room temperature to 900’C using a 4.2°C/minute heating rate

  14. Inelastic deformation and damage at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Krempl, E.


    Combined experimental and theoretical investigations into the inelastic deformation and damage behavior of engineering alloys at elevated temperatures are being pursued. The analysis of previously performed strain rate change and relaxation tests on modified 9Cr-1Mo steel showed the need for inclusion of a recovery of state term in the growth laws for the state variables of the viscoplasticity theory based on overstress (VBO). Recovery of state terms were introduced and the experimental results were satisfactorily simulated. The finite deformation theory of VBO has been developed further to include a convected derivative rationale for the choice of the objective stress rate. The reversing direct current voltage drop measurements during low cycle fatigue at elevated temperature were improved. A passive filter bank and new positioning devices for the coils were installed. Tests at 650{degrees}C and lasting several days showed excessive, uncontrollable temperature changes. It was decided to drop the test temperature to 538{degrees}C which is close to the operating temperature of Type 304 Stainless Steel. The temperature fluctuations in torsion tests were within {plus minus}3{degrees}C which was considered satisfactory. Testing will continue at 538{degrees}C.

  15. Inelastic deformation and damage at high temperature (United States)

    Krempl, E.


    Combined experimental and theoretical investigations into the inelastic deformation and damage behavior of engineering alloys at elevated temperatures are being pursued. The analysis of previously performed strain rate change and relaxation tests on modified 9Cr-1Mo steel showed the need for inclusion of a recovery of state term in the growth laws for the state variables of the viscoplasticity theory based on overstress (VBO). Recovery of state terms were introduced and the experimental results were satisfactorily simulated. The finite deformation theory of VBO has been developed further to include a convected derivative rationale for the choice of the objective stress rate. The reversing direct current voltage drop measurements during low cycle fatigue at elevated temperature were improved. A passive filter bank and new positioning devices for the coils were installed. Tests at 650 C and lasting several days showed excessive, uncontrollable temperature changes. It was decided to drop the test temperature to 538 C which is close to the operating temperature of type 304 stainless steel. The temperature fluctuations in torsion tests were within +/- 3 C which was considered satisfactory.


    Institute of Scientific and Technical Information of China (English)


    In the past half century China has developed and formed her own system of high temperature materials for power, automobile and aero-engine industries in the temperature range from 550 ℃ to 1 100 ℃. These high temperature materials include heat-resisting steels, iron-base, nickel-iron-base and nickel-base superalloys. Some achievements in high temperature strength study, new technologies and new alloy development are also discussed.

  17. Bed Topography of Store Glacier and Fjord, Greenland from High-Resolution Gravity Data and Multi-Beam Echo Sounding (United States)

    An, L.; Rignot, E. J.; Muto, A.; Morlighem, M.; Kemp, C.


    Store Glacier is a major west Greenland outlet tidewater glacier draining an area of 30,000 square km into Uummannaq Fjord, and flowing at a speed of 4.8 km per year at its terminus. The bed topography of the glacier is poorly known and the fjord bathymetry was partially surveyed for the first time in August 2012. In this study, we present a new approach for the inference of the glacier bed topography, ice thickness and sea floor bathymetry using high-resolution airborne gravity data combined with other data. In August 2012, we acquired a 250 m spacing grid of free-air gravity data at a speed of 50 knots with accuracy at sub-milligal level much higher accuracy than NASA Operation IceBridge (OIB) gravity campaign with approximate 5.2 km resolution at 290 knots flying speed. In August 2012 and 2013, we used multi-beam echo sounding to survey the sea floor bathymetry in front of the glacier, extending to the calving face of the glacier. Inland, we combined radar-derived ice thickness with ice motion vectors to reconstruct the bed topography at a high resolution. Using a 3D inversion of the gravity data, we reconstruct seamless bed topography across the ice front boundary that matches interior data and sea floor bathymetry, and provides information about sediment thickness beneath and in front of the glacier. Comparison of the results with prior maps reveals vast differences. IBCAO3 bathymetry suggests an ice front grounded at sea level while the measured ice front is grounded 550 m below sea level. The seamless topography obtained across the grounding line reveals the presence of a previously unknown sill, which explains why the glacier has been so stable in the last 50 years. The results have important impacts on the interpretation of the glacier stability, and sensitivity to thermal forcing from the ocean and surface melt. This work was conducted at UCI under a contract with the Gordon and Betty More Foundation and with NASA.

  18. [Genesis study of omphacite at high pressure and high temperature]. (United States)

    Xiao, Ben-Fu; Yi, Li; Wang, Duo-Jun; Xie, Chao; Tang, Xue-Wu; Liu, Lei; Cui, Yue-Ju


    The melting and recrystallizing experiments of alkali basalt powder and mixture of pure oxides mixed as stoichiometry were performed at 3 GPa and 1 200 degrees C. Electronic microprobe analysis and Raman spectra showed that the recrystallized products were omphacites, the FWHM (full width at half maximum) of the Raman peak was narrow and its shape was sharp, which is attributed to the stable Si-O tetrahedral structure and the high degree of order in omphacite. Based on the results of previous studies, the influencing factors of omphacite genesis and its primary magma were discussed. The results showed that the formation of omphacite could be affected by many factors, such as the composition of parent rocks, the concentration of fluid in the system and the conditions of pressure and temperature. This result could support some experimental evidences on the genesis studies of omphacite and eclogite.

  19. Design of High Field Solenoids made of High Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Bartalesi, Antonio; /Pisa U.


    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  20. Validation of SCALE for High Temperature Gas-Cooled Reactors Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ilas, Germina [ORNL; Ilas, Dan [ORNL; Kelly, Ryan P [ORNL; Sunny, Eva E [ORNL


    This report documents verification and validation studies carried out to assess the performance of the SCALE code system methods and nuclear data for modeling and analysis of High Temperature Gas-Cooled Reactor (HTGR) configurations. Validation data were available from the International Handbook of Evaluated Reactor Physics Benchmark Experiments (IRPhE Handbook), prepared by the International Reactor Physics Experiment Evaluation Project, for two different HTGR designs: prismatic and pebble bed. SCALE models have been developed for HTTR, a prismatic fuel design reactor operated in Japan and HTR-10, a pebble bed reactor operated in China. The models were based on benchmark specifications included in the 2009, 2010, and 2011 releases of the IRPhE Handbook. SCALE models for the HTR-PROTEUS pebble bed configuration at the PROTEUS critical facility in Switzerland have also been developed, based on benchmark specifications included in a 2009 IRPhE draft benchmark. The development of the SCALE models has involved a series of investigations to identify particular issues associated with modeling the physics of HTGRs and to understand and quantify the effect of particular modeling assumptions on calculation-to-experiment comparisons.


    Energy Technology Data Exchange (ETDEWEB)

    Hemrick, James Gordon [ORNL; Smith, Jeffrey D [ORNL; O' Hara, Kelley [University of Missouri, Rolla; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.


    A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new

  2. Thermodynamic evaluation of supercritical oxy-type power plant with high-temperature three-end membrane for air separation (United States)

    Kotowicz, Janusz; Balicki, Adrian; Michalski, Sebastian


    Among the technologies which allow to reduce greenhouse gas emissions, mainly of carbon dioxide, special attention deserves the idea of `zero-emission' technology based on boilers working in oxy-combustion technology. In the paper a thermodynamic analysis of supercritical power plant fed by lignite was made. Power plant consists of: 600 MW steam power unit with live steam parameters of 650 °C/30 MPa and reheated steam parameters of 670 °C/6 MPa; circulating fluidized bed boiler working in oxy-combustion technology; air separation unit and installation of the carbon dioxide compression. Air separation unit is based on high temperature membrane working in three-end technology. Models of steam cycle, circulation fluidized bed boiler, air separation unit and carbon capture installation were made using commercial software. After integration of these models the net electricity generation efficiency as a function of the degree of oxygen recovery in high temperature membrane was analyzed.

  3. Thermodynamic evaluation of supercritical oxy-type power plant with high-temperature three-end membrane for air separation

    Directory of Open Access Journals (Sweden)

    Kotowicz Janusz


    Full Text Available Among the technologies which allow to reduce greenhouse gas emissions, mainly of carbon dioxide, special attention deserves the idea of ‘zero-emission’ technology based on boilers working in oxy-combustion technology. In the paper a thermodynamic analysis of supercritical power plant fed by lignite was made. Power plant consists of: 600 MW steam power unit with live steam parameters of 650 °C/30 MPa and reheated steam parameters of 670 °C/6 MPa; circulating fluidized bed boiler working in oxy-combustion technology; air separation unit and installation of the carbon dioxide compression. Air separation unit is based on high temperature membrane working in three-end technology. Models of steam cycle, circulation fluidized bed boiler, air separation unit and carbon capture installation were made using commercial software. After integration of these models the net electricity generation efficiency as a function of the degree of oxygen recovery in high temperature membrane was analyzed.

  4. High-temperature responses of North American cacti

    Energy Technology Data Exchange (ETDEWEB)

    Smith, S.D.; Didden-Zopfy, B.; Nobel, P.S.


    High-temperature tolerances of 14 species of North American cacti were investigated. A reduction in the proportion of chlorenchyma cells taking up a vital stain (neutral red) and reduced nocturnal acid accumulation were used as indicators of high-temperature damage. All species tolerated relatively high tissue temperatures, the mean maximum tolerance being 64/sup 0/C, with an absolute maximum of 69/sup 0/ for two species of ferocactus. Such tissue tolerances to high temperature may be unsurpassed in vascular plants. Morphological features can affect tissue temperatures. Specifically, thin-stemmed species such as the cylindropuntias attain lower maximum temperatures under identical microclimatic conditions than do more massive species; they also tend to be less tolerant of high-temperature stress. Stem diameter changes of three species of columnar ceriod cacti along a Sonoran Desert latitudinal transect were previously attributed to adaptation to progressively colder temperatures northward. Such changes can also be interpreted as a morphological adaptation to high temperatures, particularly in the southern Sonoran Desert. Interspecific differences in high-temperature tolerance may account for distributional differences among other species. Acclimation of high-temperature tolerances in response to increasing day/night air temperatures was observed in all 14 species, especially at higher growh temperatures. From 40/sup 0/ day/30/sup 0/ night to 50/sup 0//40/sup 0/, the tolerable tissue temperatures increased an average of 6/sup 0/. Half-times for the acclimation shifts were 1-3d. Although cacti attain extremely high tissue temperatures in desert habitats, tolerance of high temperatures and pronounced acclimation potential allow them to occur in some of the hottest habitats in North America.

  5. Coal-fired power plants and the causes of high temperature corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Oakey, J.E.; Simms, N.J. [British Coal Corporation, Coal Technology Development Div., Cheltenham, Glos (United Kingdom); Tomkings, A.B. [ERA Technology Ltd., Leatherhead, Surrey (United Kingdom)


    The heat exchangers in all types of coal-fired power plant operate in aggressive, high temperature environments where high temperature corrosion can severely limit their service lives. The extent of this corrosion is governed by the combined effects of the operating conditions of the heat exchanger and the presence of corrosive species released from the coal during operation. This paper reviews the coal-related factors, such as ash deposition, which influence the operating environments of heat exchangers in three types of coal-fired power plant - conventional pulverized coal boilers, fluidized bed boilers and coal gasification systems. The effects on the performance of the materials used for these heat exchangers are then compared. (au) 35 refs.

  6. Metallic substrates for high temperature superconductors (United States)

    Truchan, Thomas G.; Miller, Dean J.; Goretta, Kenneth C.; Balachandran, Uthamalingam; Foley, Robert


    A biaxially textured face-centered cubic metal article having grain boundaries with misorientation angles greater than about limited to less than about 1%. A laminate article is also disclosed having a metal substrate first rolled to at least about 95% thickness reduction followed by a first annealing at a temperature less than about C. Then a second rolling operation of not greater than about 6% thickness reduction is provided, followed by a second annealing at a temperature greater than about C. A method of forming the metal and laminate articles is also disclosed.

  7. Experimental Study on Coal Multi-generation in Dual Fluidized Beds

    Institute of Scientific and Technical Information of China (English)

    Fan Xiaoxu; Lu Qinggang; Na Yongjie; Liu Qi


    An atmospheric test system of dual fluidized beds for coal multi-generation was built. One bubbling fluidized bed is for gasification and a circulating fluidized bed for combustion. The two beds are combined with two valves:one valve to send high temperature ash from combustion bed to the gasification bed and another valve to send char and ash from gasification bed to combustion bed. Experiments on Shenhua coal multi-generation were made at temperatures from 1112 K to 1191 K in the dual fluidized beds. The temperatures of the combustor are stable and the char combustion efficiency is about 98%. Increasing air/coal ratio to the fluidized bed leads to the increase of temperature and gasification efficiency. The maximum gasification efficiency is 36.7% and the calorific value of fuel gas is 10.7 MJ/Nm3. The tar yield in this work is 1.5%, much lower than that of pyrolysis.Carbon conversion efficiency to fuel gas and flue gas is about 90%.

  8. High temperature structural, polymeric foams from high internal emulsion polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Hoisington, M.A.; Duke, J.R.; Apen, P.G.


    In 1982, a high internal phase emulsion (HIPE) polymerization process to manufacture microcellular, polymeric foam systems was patented by Unilever. This patent discloses a polymerization process that occurs in a water-in-oil emulsion in which the water represents at least 76% of the emulsion by volume. The oil phase consists of vinyl monomers such as styrene and acrylates that are crosslinked by divinyl monomers during polymerization. After polymerization and drying to remove the water phase, the result is a crosslinked polymer foam with an open cell microstructure that is homogeneous throughout in terms of morphology, density, and mechanical properties. Since 1982, numerous patents have examined various HIPE polymerized foam processing techniques and applications that include absorbents for body fluids, cleaning materials, and ion exchange systems. All the published HIPE polymerized foams have concentrated on materials for low temperature applications. Copolymerization of styrene with maleic anhydride and N-substituted maleimides to produce heat resistant thermoplastics has been studied extensively. These investigations have shown that styrene will free radically copolymerize with N-substituted maleimides to create an alternating thermoplastic copolymer with a Tg of approximately 200{degrees}C. However, there are many difficulties in attempting the maleimide styrene copolymerization in a HIPE such as lower polymerization temperatures, maleimide solubility difficulties in both styrene and water, and difficulty obtaining a stable HIPE with a styrene/maleimide oil phase. This work describes the preparation of copolymer foams from N-ethylmaleimide and Bis(3-ethyl-5-methyl-4-maleimide-phenyl)methane with styrene based monomers and crosslinking agents.

  9. Fluidized-bed denitrification of mining water tolerates high nickel concentrations. (United States)

    Zou, G; Papirio, S; van Hullebusch, E D; Puhakka, J A


    This study revealed that fluidized-bed denitrifying cultures tolerated soluble Ni concentrations up to 500 mg/L at 7-8 and 22°C. From 10 to 40 mg/L of feed Ni, denitrification resulted in complete nitrate and nitrite removal. The concomitant reduction of 30 mg/L of sulfate produced 10 mg/L of sulfide that precipitated nickel, resulting in soluble effluent Ni below 22 mg/L. At this stage, Dechloromonas species were the dominant denitrifying bacteria. From 60 to 500 mg/L of feed Ni, nickel remained in solution due to the inhibition of sulfate reduction. At soluble 60 mg/L of Ni, denitrification was partially inhibited prior to recover after 34 days of enrichment by other Ni-tolerant species (including Delftia, Zoogloea and Azospira) that supported Dechloromonas. Subsequently, the FBR cultures completely removed nitrate even at 500 mg/L of Ni. Visual Minteq speciation model predicted the formation of NiS, NiCO3 and Ni3(PO4)2, whilst only Ni3(PO4)2 was detected by XRD.

  10. Control and experimental characterization of a methanol reformer for a 350 W high temperature polymer electrolyte membrane fuel cell system

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen; Sahlin, Simon Lennart


    This work presents a control strategy for controlling the methanol reformer temperature of a 350 W high temperature polymer electrolyte membrane fuel cell system, by using a cascade control structure for reliable system operation. The primary states affecting the methanol catalyst bed temperature...... is the water and methanol mixture fuel flow and the burner fuel/air ratio and combined flow. An experimental setup is presented capable of testing the methanol reformer used in the Serenergy H3 350 Mobile Battery Charger; a high temperature polymer electrolyte membrane (HTPEM) fuel cell system....... The experimental system consists of a fuel evaporator utilizing the high temperature waste gas from the cathode air cooled 45 cell HTPEM fuel cell stack. The fuel cells used are BASF P1000 MEAs which use phosphoric acid doped polybenzimidazole membranes. The resulting reformate gas output of the reformer system...

  11. Cryogenic deformation of high temperature superconductive composite structures

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, Peter R. (Groton, MA); Michels, William (Brookline, MA); Bingert, John F. (Jemez Springs, NM)


    An improvement in a process of preparing a composite high temperature oxide superconductive wire is provided and involves conducting at least one cross-sectional reduction step in the processing preparation of the wire at sub-ambient temperatures.

  12. Advancement of High Temperature Black Liquor Gasification Technology

    Energy Technology Data Exchange (ETDEWEB)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz


    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the

  13. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Adcock, K.D.; Fain, D.E.; James, D.L.; Powell, L.E.; Raj, T.; Roettger, G.E.; Sutton, T.G. [East Tennessee Technology Park, Oak Ridge, TN (United States)


    The separative performance of the authors` ceramic membranes has been determined in the past using a permeance test system that measured flows of pure gases through a membrane at temperatures up to 275 C. From these data, the separation factor was determined for a particular gas pair from the ratio of the pure gas specific flows. An important project goal this year has been to build a Mixed Gas Separation System (MGSS) for measuring the separation efficiencies of membranes at higher temperatures and using mixed gases. The MGSS test system has been built, and initial operation has been achieved. The MGSS is capable of measuring the separation efficiency of membranes at temperatures up to 600 C and pressures up to 100 psi using a binary gas mixture such as hydrogen/methane. The mixed gas is fed into a tubular membrane at pressures up to 100 psi, and the membrane separates the feed gas mixture into a permeate stream and a raffinate stream. The test membrane is sealed in a stainless steel holder that is mounted in a split tube furnace to permit membrane separations to be evaluated at temperatures up to 600 C. The compositions of the three gas streams are measured by a gas chromatograph equipped with thermal conductivity detectors. The test system also measures the temperatures and pressures of all three gas streams as well as the flow rate of the feed stream. These data taken over a range of flows and pressures permit the separation efficiency to be determined as a function of the operating conditions. A mathematical model of the separation has been developed that permits the data to be reduced and the separation factor for the membrane to be determined.

  14. High temperature superconductor cable concepts for fusion magnets

    CERN Document Server



    Three concepts of high temperature superconductor cables carrying kA currents (RACC, CORC and TSTC) are investigated, optimized and evaluated in the scope of their applicability as conductor in fusion magnets. The magnetic field and temperature dependence of the cables is measured; the thermal expansion and conductivity of structure, insulation and filling materials are investigated. High temperature superconductor winding packs for fusion magnets are calculated and compared with corresponding low temperature superconductor cases.

  15. Adsorptive Removal of Trichloroethylene in Water by Crop Residue Biochars Pyrolyzed at Contrasting Temperatures: Continuous Fixed-Bed Experiments

    Directory of Open Access Journals (Sweden)

    Ming Zhang


    Full Text Available Biochar (BC has attracted great attention as an alternative sorbent to activated carbon (AC. Objective of this study was to determine trichloroethylene (TCE removal by soybean stover BC pyrolyzed at 300 (BC300 and 700°C (BC700 in continuous fixed-bed column. Columns packed with BC300, BC700, and AC reached breakthrough time in 1.1, 27.0, and 50.7 h, respectively. BC700 had higher TCE adsorption capacity than BC300 due to its higher surface area, nonpolarity, and aromaticity. The sorption capacities of AC (774.0 mg g−1 and BC700 (515.1 mg g−1 were 21.6 and 14.4 times higher than that of BC300 (35.9 mg g−1. The lower desorption rate of TCE from BC300 than BC700 and AC may be attributed to the strong binding/partition of TCE to the noncarbonized part of BC. Thomas model also adequately described the adsorption data indicating interphase mass transfer. Overall, AC showed best efficiency for removing TCE from water in column experiments. However, although sorption and desorption capabilities of BC700 were a little lower than AC, it is still a good alternative for AC to remove organic contaminants such as TCE from water due to its cost-effectiveness.

  16. Double Bag VARTM for High Temperature Composites Project (United States)

    National Aeronautics and Space Administration — Cost and size are limiting factors in efforts to produce high strength, high stiffness, and high temperature composite parts. To address these issues, new processes...

  17. Vibrational relaxation in very high temperature nitrogen (United States)

    Hansen, C. Frederick


    Vibrational relaxation of N2 molecules is considered at temperatures up to 40,000 K in gas mixtures that contain electrons as well as heavy collision partners. The theory of vibrational relaxation due to N2-N2 collisions is fit to experimental data to 10,000 K by choice of the shape of the intermolecular potential and size of the collision cross section. These values are then used to extrapolate the theory to 40,000 K.

  18. High Temperature LFMR in Yttrium Doped Perovskite Manganites

    Institute of Scientific and Technical Information of China (English)

    盛晓波; 童林夙; 林萍华; 杨石强; 储成林; 翟亚


    Porous ceramic samples of Y doped perovskite manganites were prepared. In these samples, the transition from high temperature paramagnetic insulator to low temperature ferromagnetic metal as well as the low field magnetoresistance (LFMR) effect at the low temperature is similar to that in dense samples. Opposite to that in dense samples, LFMR effect in porous sample is observed at the high temperature close to the peak of MR-T curves. The results suggest that the high temperature LFMR effect and the applicable colossal magnetoresistance (CMR) materials could be obtained by controlling the microstructures of this class of perovskite manganites.


    Energy Technology Data Exchange (ETDEWEB)

    M. G. McKellar; E. A. Harvego; A. M. Gandrik


    An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

  20. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods


    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).