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Sample records for bed egsb reactor

  1. CFD simulation of an expanded granular sludge bed (EGSB) reactor for biohydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xu; Ding, Jie; Ren, Nan-Qi; Liu, Bing-Feng; Guo, Wan-Qian [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, 202 Haihe Road, Nangang District, Harbin, Heilongjiang 150090 (China)

    2009-12-15

    Understanding how a bioreactor functions is a necessary precursor for successful reactor design and operation. This paper describes a two-dimensional computational fluid dynamics simulation of three-phase gas-liquid-solid flow in an expanded granular sludge bed (EGSB) reactor used for biohydrogen production. An Eulerian-Eulerian model was formulated to simulate reaction zone hydrodynamics in an EGSB reactor with various hydraulic retention times (HRT). The three-phase system displayed a very heterogeneous flow pattern especially at long HRTs. The core-annulus structure developed may lead to back-mixing and internal circulation behavior, which in turn gives poor velocity distribution. The force balance between the solid and gas phases is a particular illustration of the importance of the interphase rules in determining the efficiency of biohydrogen production. The nature of gas bubble formation influences velocity distribution and hence sludge particle movement. The model demonstrates a qualitative relationship between hydrodynamics and biohydrogen production, implying that controlling hydraulic retention time is a critical factor in biohydrogen-production. (author)

  2. Three controllable factors of steady operation of EGSB reactor

    Institute of Scientific and Technical Information of China (English)

    LI Hui-li; LU Bing-nan; LI Fang

    2008-01-01

    The bench- scale EGSB (expanded granular sludge bed) reactor was operated to study the effect of sludge loading rate, pH value and nutrient element on the operation of the EGSB reactor and the control rule of these factors. Continuous flow was used to treat synthetic wastewater containing dextrose and beer, and the temperature of reactor was controlled at mesophiles temperature (33 ℃). The experimental results demonstrated trolled by adding sodium bicarbonate, the proper additive quantity was 1000-1200 mg/L; the additive quantity wastewater with 400-5000 mg/L COD concentration. The COD removal efficiency was over 85%. The operation of the EGSB reactor was steady and the EGSB reactor had strong anti-shock load ability.

  3. Comparison of bioaugmented EGSB and GAC–FBB reactors and their combination with aerobic SBR for the abatement of chlorophenols

    OpenAIRE

    Puyol, Daniel; Monsalve, Víctor Manuel; Sanchís, Sonia; Sanz, José Luis; Fernández Mohedano, Ángel; Rodríguez, Juan José

    2015-01-01

    The biological abatement of 2,4,6-trichlorophenol (246TCP) and its chlorinated degradation byproducts using anaerobic and aerobic biological reactors coupled in series has been studied. The performance of an anaerobic fluidized bed biofilm reactor (FBBR) and expanded granular sludge bed (EGSB) reactors bioaugmented with Desulfitobacterium strains was compared within a wide range of 246TCP loading rates. The bioaugmentation of an EGSB reactor with Desulfitobacterium strains enhanced the chloro...

  4. Comparison of UASB and EGSB reactors performance, for treatment of raw and deoiled palm oil mill effluent (POME)

    International Nuclear Information System (INIS)

    Anaerobic digestion of palm oil mill effluent (POME) and deoiled POME was investigated both in batch assays and continuous reactor experiments using up-flow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors. The methane potential determined from batch assays of POME and deoiled POME was 503 and 610 mL-CH4/gVS-added, respectively. For the treatment of POME in continuously fed reactors, both in UASB and EGSB reactors more than 90% COD removal could be obtained, at HRT of 5 days, corresponding to OLR of 5.8 gVS/(L-reactor.d). Similar methane yields of 436-438 mL-CH4/gVS-added were obtained for UASB and EGSB respectively. However, for treatment of deoiled POME, both UASB and EGSB reactors could operate at lower OLR of 2.6 gVS/(L-reactor.d), with the methane yield of 600 and 555 mL-CH4/gVS-added for UASB and EGSB, respectively. The higher methane yield achieved from the deoiled POME was attributed to lower portion of biofibers which are more recalcitrant compared the rest of organic matter in POME. The UASB reactor was found to be more stable than EGSB reactor under the same OLR, as could be seen from lower VFA concentration, especially propionic acid, compared to the EGSB reactor.

  5. Anaerobic Treatment of Palm Oil Mill Effluent in Pilot-Scale Anaerobic EGSB Reactor

    OpenAIRE

    2015-01-01

    Large volumes of untreated palm oil mill effluent (POME) pose threat to aquatic environment due to the presence of very high organic content. The present investigation involved two pilot-scale anaerobic expanded granular sludge bed (EGSB) reactors, continuously operated for 1 year to treat POME. Setting HRT at 9.8 d, the anaerobic EGSB reactors reduced COD from 71179 mg/L to 12341 mg/L and recycled half of sludge by a dissolved air flotation (DAF). The average effluent COD was 3587 mg/L with ...

  6. Biogas production from potato-juice, a by-product from potato-starch processing, in upflow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors

    DEFF Research Database (Denmark)

    Fang, Cheng; Boe, Kanokwan; Angelidaki, Irini

    2011-01-01

    In this study, the utilization of potato-juice, the organic by-product from potato-starch processing, for biogas production was investigated in batch assay and in high rate anaerobic reactors. The maximum methane potential of the potato-juice determined by batch assay was 470mL-CH4/g......VS-added. Anaerobic digestion of potato-juice in an EGSB reactor could obtain a methane yield of 380mL-CH4/gVS-added at the organic loading rate of 3.2gCOD/(L-reactor.d). In a UASB reactor, higher organic loading rate of 5.1gCOD/(L-reactor.d) could be tolerated, however, it resulted in a lower methane yield of 240m......L-CH4/gVS-added. The treatment of reactor effluent was also investigated. By acidification with sulfuric acid to pH lower than 5, almost 100% of the ammonia content in the effluent could be retained during the successive up-concentration process step. The reactor effluent could be up...

  7. Anaerobic Treatment of Palm Oil Mill Effluent in Pilot-Scale Anaerobic EGSB Reactor.

    Science.gov (United States)

    Wang, Jin; Mahmood, Qaisar; Qiu, Jiang-Ping; Li, Yin-Sheng; Chang, Yoon-Seong; Li, Xu-Dong

    2015-01-01

    Large volumes of untreated palm oil mill effluent (POME) pose threat to aquatic environment due to the presence of very high organic content. The present investigation involved two pilot-scale anaerobic expanded granular sludge bed (EGSB) reactors, continuously operated for 1 year to treat POME. Setting HRT at 9.8 d, the anaerobic EGSB reactors reduced COD from 71179 mg/L to 12341 mg/L and recycled half of sludge by a dissolved air flotation (DAF). The average effluent COD was 3587 mg/L with the consistent COD removal efficiency of 94.89%. Adding cationic polymer (PAM) dose of 30 mg/L to DAF unit and recycling its half of sludge caused granulation of anaerobic sludge. Bacilli and small coccid bacteria were the dominant microbial species of the reactor. The reactor produced 27.65 m(3) of biogas per m(3) of POME which was utilized for electricity generation. PMID:26167485

  8. Comparison of UASB and EGSB reactors performance, for treatment of raw and deoiled palm oil mill effluent (POME)

    DEFF Research Database (Denmark)

    Fang, Cheng; O-Thong, Sompong; Boe, Kanokwan;

    2011-01-01

    Anaerobic digestion of palm oil mill effluent (POME) and deoiled POME was investigated both in batch assays and continuous reactor experiments using up-flow anaerobic sludge blanket (UASB) and expanded granular sludge bed (EGSB) reactors. The methane potential determined from batch assays of POME...

  9. Kinetics of municipal sewage degradation in EGSB and UASB reactors at 10 ℃

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Kinetics of municipal sewage degradation in Expanded Granular Sludge Bed(EGSB)and Up-flow Anaerobic Sludge Blanket(UASB)reactors at 10℃ were investigated via continuous experimental equipments.The results indicated that the whole reaction process can be simulated by the first-order dynamic equation model.Dynamic parameters such as k,Vmax and Ks of UASB in hydrolysis acidification stage were 1.08 d-1,2.8 d-1 and 372 mg/L comparing to those of 1.18 d-1,3.5 d-1 and 112 mg/L in the methanogenesis stage respecti...

  10. The operation of two EGSB reactors under the application of different loads of oxytetracycline and florfenicol.

    Science.gov (United States)

    Londoño, Yudy Andrea; Rodríguez, Diana Catalina; Peñuela, Gustavo

    2012-01-01

    This study evaluated the effect of the antibiotics oxytetracycline (OTC) and florfenicol (FLO) on the operation of two EGSB (expanded granular sludge bed) reactors. The experiment was conducted for 210 d in reactor R1 and 245 d in reactor R2. The reactors were inoculated with granular sludge from a upflow anaerobic sludge blanket (UASB) reactor on a local dairy farm. The sludge had an average pellet size of 2.35 mm, good sedimentability and a high percentage of organic material. The antibiotic tolerance and the inhibitory action on the bacterial population were different for each antibiotic studied. The results showed a more severe inhibitory effect on microorganisms that were in contact with increases in loads of FLO than those that were in contact with increasing loads of OTC, a condition reflected in the chemical oxygen demand (COD) removal efficiency. PMID:23109573

  11. Anaerobic Treatment of Palm Oil Mill Effluent in Pilot-Scale Anaerobic EGSB Reactor

    Directory of Open Access Journals (Sweden)

    Jin Wang

    2015-01-01

    Full Text Available Large volumes of untreated palm oil mill effluent (POME pose threat to aquatic environment due to the presence of very high organic content. The present investigation involved two pilot-scale anaerobic expanded granular sludge bed (EGSB reactors, continuously operated for 1 year to treat POME. Setting HRT at 9.8 d, the anaerobic EGSB reactors reduced COD from 71179 mg/L to 12341 mg/L and recycled half of sludge by a dissolved air flotation (DAF. The average effluent COD was 3587 mg/L with the consistent COD removal efficiency of 94.89%. Adding cationic polymer (PAM dose of 30 mg/L to DAF unit and recycling its half of sludge caused granulation of anaerobic sludge. Bacilli and small coccid bacteria were the dominant microbial species of the reactor. The reactor produced 27.65 m3 of biogas per m3 of POME which was utilized for electricity generation.

  12. Startup and operation of anaerobic EGSB reactor treating palm oil mill effluent

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yejian; YAN Li; CHI Lina; LONG Xiuhua; MEI Zhijian; ZHANG Zhenjia

    2008-01-01

    A bench-scale expanded granular sludge bed (EGSB) reactor was applied to the treatment of palm oil mill ettluent (POME).The reactor had been operated continuously at 35℃ for 514 d,with organic loading rate (OLR) increased from 1.45 to 17.5 kg COD/(m3·d).The results showed that the EGSB reactor had good performance in terms of COD removal on the one hand,high COD removal of 91% Was obtained at two days’ of hydraulic retention time (HRT),and the highest OLR of 17.5 kg COD/(m3·d).On the other hand,only 46% COD in raw POME Was transformed into biogas in which the methane content was about 70% (v/v).A 30-d intermittent experiment indicated that the maximum transformation potential of organic matter in raw POME into methane Was 56%.Volatile fatty acid (VFA) accumulation was observed in the later operation stage,and this Was settled by supplementing trace metal elements.On the whole,the system exhibited good stability in terms of acidity and alkalinity.Finally, the operational problems inherent in the laboratory scale experiment and the corresponding countermeasures were also discussed.

  13. Hydrogen energy recovery from high strength organic wastewater with ethanol type fermentation using acidogenic EGSB reactor

    Institute of Scientific and Technical Information of China (English)

    REN Nan-qi; GUO Wan-qian; WANG Xiang-jing; ZHANG Lu-si

    2005-01-01

    A lab-scale expanded granular sludge bed (EGSB) reactor was employed to evaluate the feasibility of the hydrogen energy recovery potential from high strength organic wastewater. The results showed that a maxioperation. At the acidogenic phase, COD removal rate was stable at about 15%. In the steady operation peri od, the main liquid end products were ethanol and acetic acid, which represented ethanol type fermentation. Among the liquid end products, the concentration percentage of ethanol and acetic acid amounted to 69.5% ~89.8% and the concentration percentage of ethanol took prominent about 51.7% ~ 59.1%, which is better than the utilization of substrate for the methanogenic bacteria. An ethanol type fermentation pathway was suggested in the operation of enlarged industrial continuous hydrogen bio-producing reactors.

  14. The start-up of biohydrogen-producing process by bioaugmentation in the EGSB reactor

    Institute of Scientific and Technical Information of China (English)

    Wang Xiangjing; Ren Nanqi; Xiang Wensheng; Guo Wanqian

    2006-01-01

    Expanded granular sludge bed (EGSB) reactor and bioaugmentation were employed to investigate biohydrogen production with molasses wastewater. The start-up experiments consisted of two stages. In the first stage (0~24d) seeded with activated sludge, the butyric acid type-fermentation formed when the initial expanding rate, organic loading rate (OLR), the initial redox potential (ORP) and hydraulic retention time (HRT) were 10%, 10.0 kg COD/(m3·d), - 215 mV and 6.7 h, respectively. At the beginning of the second stage on day 25, the novel hydrogen-producing fermentative bacterial strain B49 (AF481148 in EMBL) were inoculated into the reactor under the condition of OLR 16. 0 kg COD/(m3·d), ORP and HRT about - 139 mV and 6.7 h, respectively, and then the reaction system transformed to ethanol-type fermentation gradually with the increase in OLR. When OLR, ORP and HRT were about 94.3 kg COD/(m3·d), -250 mV and 1.7 h, respectively, the system achieved the maximum hydrogen-producing rate of 282.6 mL H2/L reactor· h and hydrogen percentage of 51%~53% in the biogas.

  15. Influence of Chemical Oxygen Demand Concentrations on Anaerobi Ammonium Oxidation by Granular Sludge From EGSB Reactor

    Institute of Scientific and Technical Information of China (English)

    JING KANG; JIAN-LONG WANG

    2006-01-01

    Objective To investigate the effect of chemical oxygen demand (COD) concentrations on the anaerobic ammonium oxidation (ANAMMOX). Methods An Expanded Granular Sludge Bed (EGSB) reactor was used to cultivate the granular sludge and to perform the ANAMMOX reaction in the bench scale experiment. NH4+-N and NO2--N were measured by usingcolorimetric method. NO3--N was analyzed by using the UV spectrophotometric method. COD measurement was based on digestion with potassium dichromate in concentrated sulphuric acid. Results When the COD concentrations in the reactors were 0 mg/L, 200 mg/L, 350 mg/L, and 550 mg/L, respectively, the NH4+-N removal efficiency was 12.5%, 14.2%, 14.3%, and 23.7%; the removal amount of NO2--N was almost the same; the nitrate removal efficiency was 16.8%, 94.5%, 86.6%, and 84.2% and TN removal efficiency was 16.3%, 50.7%, 46.9%, and 50.4%, moreover, the COD removal efficiency concentrations have a significant influence on anaerobic ammonium oxidation by granular sludge.

  16. Bio-hydrogen production in an EGSB reactor under mesophilic, thermophilic and hyperthermophilic conditions

    OpenAIRE

    Abreu, A. A.; Danko, Anthony S.; Alves, M. M.

    2007-01-01

    Mesophilic, thermophilic and hyperthermophilic bio-hydrogen production with an expanded granular sludge blanket (EGSB) fed with glucose and arabinose, without methane production, was demonstrated. Homoacetogenesis was observed on reactor when operated under mesophilic (37ºC) conditions but not under thermophilic (55ºC) and hyper-thermophilic conditions (70ºC). It was also found that under thermophilic and hyper-thermophilic conditions glucose is preferentially consumed than ara...

  17. Influence of the organic loading rate on the performance and the granular sludge characteristics of an EGSB reactor used for treating traditional Chinese medicine wastewater.

    Science.gov (United States)

    Li, Weiguang; Su, Chengyuan; Liu, Xingzhe; Zhang, Lei

    2014-01-01

    The effects of the organic loading rate (OLR) on the performance and the granular sludge characteristics of an expanded granular sludge bed (EGSB) reactor used for treating real traditional Chinese medicine (TCM) wastewater were investigated. Over 90% of the COD removal by the EGSB reactor was observed at the OLRs of 4 to 13 kg COD/(m(3) day). However, increasing the OLR to 20 kg COD/(m(3) day) by reducing the hydraulic retention time (HRT 6 h) reduced the COD removal efficiency to 78%. The volatile fatty acid (VFA) concentration was 512.22 mg/L, resulting in an accumulation of VFAs, and propionic acid was the main acidification product, accounting for 66.51% of the total VFAs. When the OLR increased from 10 to 20 kg COD/(m(3) day), the average size of the granule sludge decreased from 469 to 258 μm. There was an obvious reduction in the concentration of Ca(2+) and Mg(2+) in the granular sludge. The visible humic acid-like peak was identified in the three-dimensional excitation-emission matrix (EEM) fluorescence spectra of the soluble microbial products (SMPs). The fatty acid bond, amide II bond, amide III bond, and C-H bond bending were also observed in the Fourier transform infrared (FTIR) spectra of the SMPs. Methanobacterium formicicum, Methanococcus, and Bacteria populations exhibited significant shifts, and these changes were accompanied by an increase in VFA production. The results indicated that a short HRT and high OLR in the EGSB reactor caused the accumulation of polysaccharides, protein, and VFAs, thereby inhibiting the activity of methanogenic bacteria and causing granular sludge corruption. PMID:24677060

  18. Anaerobic biodegradability of mixtures of pesticides in an expanded granular sludge bed reactor.

    Science.gov (United States)

    Monsalvo, V M; Garcia-Mancha, N; Puyol, D; Mohedano, A F; Rodriguez, J J

    2014-01-01

    The biodegradability and toxicity of three commercial pesticides containing 2-methyl-4-chlorophenoxyacetic acid (MCPA), imidacloprid and dimethoate were evaluated individually, and a complex mixture of these pesticides was treated in an expanded granular sludge bed (EGSB) reactor. MCPA was partially biodegraded, while imidacloprid and dimethoate remained almost unaltered during the individual biodegradability tests. Cyclohexanone was identified as the major solvent in the dimethoate-bearing insecticide, which was completely removed regardless of the presence of other pesticides. The analysis of the inhibition over the acetoclastic methanogenesis showed IC(50) (half maximal inhibitory concentration) values of 474 and 367 mg/L for imidacloprid and dimethoate, respectively. The effect on the methanogenesis was negligible in the case of MCPA and cyclohexanone. Pesticides caused a dramatic decrease of the EGSB reactor performance. After 30 d acclimation, the EGSB reactor achieved a stable chemical oxygen demand (COD) removal efficiency and methane production of around 85% and 0.9 g CH(4)-COD/g COD, respectively, for MCPA, imidacloprid, dimethoate and cyclohexanone feed concentrations of 57, 20, 25 and 27 mg/L, respectively. The presence of complex pesticide mixtures led to synergistic/antagonistic responses, reducing the MCPA biodegradation and improving the removal of the insecticides' active ingredients, which were completely removed in the EGSB reactor. PMID:24552724

  19. Application of sequential expanded granular sludge bed reactors for biodegradation of acetate, benzoate, terephtalate and p-toluate in purified terephtalic acid production wastewater.

    Science.gov (United States)

    Lee, Y S; Han, G B

    2016-01-01

    The anaerobic degradation of four major constituents from purified terephtalic acid production wastewater in sequential two expanded granular sludge bed (EGSB) reactors was studied. The performance of the system was evaluated in terms of chemical oxygen demand (COD) removal efficiencies, methane production, stability, granular sludge adaptability as well as reversion of bacterial inhibition. With volumetric loading rates of 1.9-25 kg-COD m(-3) d(-1) and terephtalate and p-toluate of 584-821 mg L(-1), average removal efficiencies of 97.6% and 75.2% were achieved in the EGSB reactors, respectively. In these conditions, gas production reached a total methane production rate of 0.33 L g-COD(-1) in the two-stage EGSB reactor system. The disturbance of the EGSB reactors was observed at a feed concentration above around 6.9 g-COD L(-1) because of higher influent COD concentration compared to other experiments. PMID:26513246

  20. Fixed bed nuclear reactor concept

    International Nuclear Information System (INIS)

    Full text: The fixed bed nuclear reactor (FBNR) is essentially a pressurized light water reactor (PWR) having spherical fuel elements constituting a suspended reactor core at its lowest bed porosity. The core is movable thus under any adverse condition, the fuel elements can leave the reactor core naturally through the force of gravity and fall into the passively cooled fuel chamber or leave the reactor all together entering the spent fuel pool. It is a small and modular reactor being simple in design. Its spent fuel is in such a convenient form and size that may be utilized directly as the source for irradiation and applications in agriculture and industry. This feature results in a positive impact on waste management and environmental protection. The principle features of the proposed reactor are that the concept is polyvalent, simple in design, may operate either as fixed or fluidized bed, have the core suspended contributing to inherent safety, passive cooling features of the reactor. The reactor is modular and has integrated primary system utilizing either water, supercritical steam or helium gas as its coolant. Some of the advantages of the proposed reactor are being modular, low environmental impact, exclusion of severe accidents, short construction period, flexible adaptation to demand, excellent load following characteristics, and competitive economics. The characteristics of the Fluidized Bed Nuclear Reactor (FBNR) concept may be analyzed under the light of the requirements set for the IV generation nuclear reactors. It is shown that FBNR meet the goals of (1) Providing sustainable energy generation that meets clean air objectives and promotes long-term availability of systems and effective fuel utilization for worldwide energy production, (2) Minimize and manage their nuclear waste and notably reduce the long term stewardship burden in the future, thereby improving protection for the public health and the environment, (3) Excel in safety and reliability

  1. Pebble bed modular reactor (PBMR)

    International Nuclear Information System (INIS)

    In 1993, the pebble bed modular reactor (PBMR) was identified by ESKOM, the electric utility of South Africa, as a leading option for the installation of new generating capacity to their electric grid. This innovative nuclear power plant incorporates a closed cycle primary coolant system utilizing helium to transport heat energy directly from the modular pebble bed reactor to a recuperative power conversion unit with a single-shaft turbine/compressor/generator. This replacement of the steam cycle that is common in present nuclear power plants (NPP) with a direct gas cycle provides the benefits of simplification and a substantial increase in overall system efficiency with the attendant lowering of capital and operational costs. Although the historical development of this plant is interrelated to other types of high temperature gas cooled reactors (HTGRs), the principle focus herein is on the pebble bed (spherical) fuel element type reactor. The long-term development of this reactor type began in Germany by the KFA Nuclear Research Center (now FZJ). Two pebble bed plants were constructed in Germany, the 46 MW(th)/15 MW(e) Arbeitsgemeinshaft Versuchsreaktor (AVR) and the 750 MW(th)/296 MW(e) thorium high temperature reactor (THTR-300). Basically, these steam/electric plants validated the temperature and fission product retention capabilities of the ceramic (TRISO) coated fuel particle and the safety characteristics of the HTGR. Most notable of the operational achievements was with the AVR in sustaining longterm operation at an average core outlet temperature of 950 deg. C, and in demonstration of safety such as extended loss of forced cooling on the core. More details on the AVR and THTR-300 plants are provided The next evolution of the pebble bed plant began in the early 1980s with development of the modular reactor. This small reactor added the unique characteristic of being able to cool the core entirely by passive heat transfer mechanisms following postulated

  2. Reactor vessel for pebble beds

    International Nuclear Information System (INIS)

    The wall and the bottom of the vessel for the gas-cooled pebble-bed reactor consist of numerous blocks of graphite or carbon rock piled up. They are held together by an exterior cylindrical or polygonal ring and supported by a foundation. The blocks form coherent sectors resp. annular sectors with well-defined separating lines. At high temperatures or load change operation these sectors behave like monolithic blocks expanding heely and contracting again, the center of the vessel remaining fixed. The forces causing the compression result from the own weight of the sectors and the weight of the pebble bed. This motion is supported by the convex arrangement of the opposite surfaces of the sectors and the supporting walls and by roller bearings. The bottom of the vessel may be designed funnel-shaped, in this way facilitating the removal of spheres. (DG)

  3. EMERGING TECHNOLOGY BULLETIN: SPOUTED BED REACTOR

    Science.gov (United States)

    The Spouted Bed Reactor (SBR) technology utilizes the unique attributes of the "spouting " fluidization regime, which can provide heat transfer rates comparable to traditional fluid beds, while providing robust circulation of highly heterogeneous solids, concurrent with very agg...

  4. Fixed bed suspended core nuclear reactor concept

    International Nuclear Information System (INIS)

    The fixed bed nuclear reactor (FBNR) is essentially a pressurized light water reactor having spherical fuel elements constituting a suspended reactor core at its lowest bed porosity. The principle features of the proposed reactor are that the concept is polyvalent, simple in design, may operate either as fixed or fluidized bed, have the core suspended contributing to inherent safety, passive cooling features of the reactor. The reactor is modular and has an integrated primary system utilizing either water, supercritical steam or helium gas as its coolant. Some of the advantages of the proposed reactor are being modular, low environmental impact, exclusion of severe accidents, short construction period, flexible adaptation to demand, excellent load following characteristics, and competitive economics. (orig.)

  5. FBR and RBR particle bed space reactors

    International Nuclear Information System (INIS)

    Compact, high-performance nuclear reactor designs based on High-Temperature Gas Reactors (HTGRs) particulate fuel are investigated. The large surface area available with the small-diameter (approx. 500 microns) particulate fuel allows very high power densities (MW's/liter), small temperature differences between fuel and coolant (approx. 100K), high coolant-outlet temperatures (1500 to 30000K, depending on design), and fast reactor startup (approx. 2 to 3 seconds). Two reactor concepts are developed - the Fixed Bed Reactor (FBR), where the fuel particles are packed into a thin annular bed between two porous cylindrical drums, and the Rotating Bed Reactor (RBR), where the fuel particles are held inside a cold rotating (typically approx. 500 rpm) porous cylindrical drum. The FBR can operate steady-state in the closed-cycle He-cooled mode or in the open-cycle H2-cooled mode. The RBR will operate only in the open-cycle H2-cooled mode

  6. Fluidized-Bed Silane-Decomposition Reactor

    Science.gov (United States)

    Iya, Sridhar K.

    1991-01-01

    Fluidized-bed pyrolysis reactor produces high-purity polycrystalline silicon from silane or halosilane via efficient heterogeneous deposition of silicon on silicon seed particles. Formation of silicon dust via homogeneous decomposition of silane minimized, and deposition of silicon on wall of reactor effectively eliminated. Silicon used to construct solar cells and other semiconductor products.

  7. Feasibility of expanded granular sludge bed reactors for the anaerobic treatment of low-strength soluble wastewaters.

    Science.gov (United States)

    Kato, M T; Field, J A; Versteeg, P; Lettinga, G

    1994-08-01

    The application of the expanded granular sludge bed (EGSB) reactor for the anaerobic treatment of low-strength soluble wastewaters using ethanol as a model substrate was investigated in laboratory-scale reactors at 30oC. Chemical oxygen demand (COD) removal efficiency was above 80% at organic loading rates up to12 g COD/L . d with influent concentrations as low as 100 to 200 mg COD/L. These results demonstrate the suitability of the EGBS reactor for the anaerobic treatment of low-strength wastewaters. The high treatment performance can be attributed to the intense mixing regime obtained by high hydraulic and organic loads. Good mixing of the bulk liquid phase for the substrate-biomass contact and adequate expansion of the substrate-biomass contact and adequate expansion of the sludge bed for the degassing were obtained when the liquid upflow velocity (V(up)) was greater than 2.5 m/h. Under such conditions, an extremely low apparent K(s) value for acetoclastic methanogenesis of 9.8 mg COD/L was observed. The presence of dissolved oxygen in the wastewater had no detrimental effect on the treatment performance. Sludge piston flotation from pockets of biogas accumulating under the sludge bed occurred at V(up) lower than 2.5 m/h due to poor bed expansion. This problem is expected only in small diameter laboratory-scale reactors. A. more important restriction of the EGSB reactor was the sludge washout occurring at V(up) higher than 5.5 m/h and which was intensified at organic loads higher than 7 g COD/L. d due to buoyancy forces from the gas production. To achieve an equilibrium between the mixing intensity and the sludge hold-up, the operation should be limited to an organic loading rate of 7 g COD/L d. and to a liquid up-flow velocity between 2.5 and 5.5 m/h (c) 1994 John Wiley & Sons, Inc. PMID:18618781

  8. Stability of expanded granular sludge bed process for terylene artificial silk printing and dyeing wastewater treatment

    Institute of Scientific and Technical Information of China (English)

    GUAN Bao-hong

    2005-01-01

    Terylene artificial silk printing and dyeing wastewater(TPD wastewater), containing averaged 710 mg/L terephthalic acid(TA) as the main carbon source and the character pollutant, was subjected to expanded granular sludge bed(EGSB) process. The stability of theEGSB process was firstly conducted by laboratory experiment. TA ionization was the predominated factor influencing the acid-base balance of the system. High concentration of TA in wastewater resulted in sufficient buffering capacity to neutralize the volatile fatty acids(VFA)generated from substrate degradation and provided strong base for anaerobic system to resist the pH decrease below 6.5. VFA and UFA caused almost no inhibition on the anaerobic process and biogas production except that pH was below 6.35 and VFA was at its maximum value. Along with the granulating of the activated sludge, the efficiency of organic removal and production rate of biogas increased gradually and became more stable. After start-up, the efficiency of COD removal increased to 57%-64%, pH stabilized in a range of 7.99-8.04, and production rate of biogas was relatively high and stable. Sludge granulating, suitable influent of pH and loading were responsible for the EGSB stability. The variation of VFA concentration only resulted in neglectable rebound of pH, and the inhibition from VFA could be ignored in EGSB. The EGSB reactor was stable for TPD wastewater treatment.

  9. Thermal regeneration in fix-bed reactors

    International Nuclear Information System (INIS)

    The thermal behaviour of a catalytic reactor with regeneration, from a simplified model is studied. Plug-flow is postulated to the reactor and a two-phase model for simulating heat transfer between the bed and the gas is used, disregarding the conduction terms. The computational results for an exothermal catalytic reaction are presented. The effect of the duration of the period and the inlet temperature of the gas in the bed temperature profiles is studied, as well as the evolution since the functioning until the steady state. (E.G.)

  10. The integration of methanogenesis with denitrification and anaerobic ammonium oxidation in an expanded granular sludge bed reactor

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The integration of methanogenesis with denitrification and anaerobic ammonium oxidation(ANAMMOX) was studied in an expanded granular sludge bed(EGSB) reactor in this work. Experimental results from the continuous treatment of wastewater with nitrite and ammonium, which lasted for 107 days, demonstrated that wastewater with high nitrite and ammonium could be anaerobically treated in an expanded granular sludge bed reactor. More than 91% to 97% of COD were removed at up to about 3.9 g COD/(L@d) of COD volumetric loading rate. More than 97% to 100% of nitrite was denitrified at up to about 0.8g NO2-N/(L@d), which is 16 times higher than that in a conventional activated sludge system with nitrification/denitrification(0.05g N/((L@d). No dissimilatory reduction of nitrite to ammonium occurred in the process. However, maximum of about 40% ammonium was found to be lost. Batch tests of 15 days with sludge from the reactor showed that 100% of nitrite was denitrified completely, and about 3% of ammonium was removed when only ammonium (34.3 mg/L) and nitrite(34.3 mg/L) were added into the sludge suspension medium. Furthermore, about 15% of ammonium amounts were lost with organic COD addition. It suggested that the methanogenesis in the system could enhance ANAMMOX because of intermediate hydrogen produced during methanogenesis.

  11. Thorium utilization in a pebble bed reactor

    International Nuclear Information System (INIS)

    Thorium reserves in the earth's crust are much more than those of uranium, which today measure about 1.5 million tonnes of reasonably assured resources, plus 3 million tonnes of estimated additional resources. These large amount of thorium reserves, also available in Turkey encourages to focus on the utilization of thorium. The most remarkable applications of the use of thorium have been in high temperature reactors. The high temperature pebble bed reactor, which has been chosen as the basis for this study, is a close approximation of the thorium utilizing German reactor THTR. Pebble bed reactors have some unique features which are suitable to burn thorium. (i) The fuel is loaded in the form of coated particles, which are embedded in the graphite matrix of the fuel pebbles, allowing exceptionally high heavy metal burnups; and (ii) the continuous (on-line) fuel loading allows a high utilization factor. The criticality search of the pebble bed reactor is computed by the use of the SCALE4.4 code, CSASIX and KENOVa modules. And the in-core fuel management is computed via SCALE4.4 code, ORIGEN-S module

  12. Pebble Bed Reactor Dust Production Model

    International Nuclear Information System (INIS)

    The operation of pebble bed reactors, including fuel circulation, can generate graphite dust, which in turn could be a concern for internal components; and to the near field in the remote event of a break in the coolant circuits. The design of the reactor system must, therefore, take the dust into account and the operation must include contingencies for dust removal and for mitigation of potential releases. Such planning requires a proper assessment of the dust inventory. This paper presents a predictive model of dust generation in an operating pebble bed with recirculating fuel. In this preliminary work the production model is based on the use of the assumption of proportionality between the dust production and the normal force and distance traveled. The model developed in this work uses the slip distances and the inter-pebble forces computed by the authors PEBBLES. The code, based on the discrete element method, simulates the relevant static and kinetic friction interactions between the pebbles as well as the recirculation of the pebbles through the reactor vessel. The interaction between pebbles and walls of the reactor vat is treated using the same approach. The amount of dust produced is proportional to the wear coefficient for adhesive wear (taken from literature) and to the slip volume, the product of the contact area and the slip distance. The paper will compare the predicted volume with the measured production rates. The simulation tallies the dust production based on the location of creation. Two peak production zones from intra pebble forces are predicted within the bed. The first zone is located near the pebble inlet chute due to the speed of the dropping pebbles. The second peak zone occurs lower in the reactor with increased pebble contact force due to the weight of supported pebbles. This paper presents the first use of a Discrete Element Method simulation of pebble bed dust production

  13. Hydrodynamics of multi-phase packed bed micro-reactors

    NARCIS (Netherlands)

    Márquez Luzardo, N.M.

    2010-01-01

    Why to use packed bed micro-reactors for catalyst testing? Miniaturized packed bed reactors have a large surface-to-volume ratio at the reactor and particle level that favors the heat- and mass-transfer processes at all scales (intra-particle, inter-phase and inter-particle or reactor level). If the

  14. Mechanics of the pebble bed reactor

    International Nuclear Information System (INIS)

    In a survey, the quite different type of problems which arise for the reactor designer from the mechanics of the pebble bed are demonstrated by examples. It becomes clear why the apparently simple system of a static heap of pebbles of the same diameter is such a complex problem, so that even after research and development work extending over three decades, it cannot be regarded as completely solved. (orig.)

  15. Method and apparatus for a combination moving bed thermal treatment reactor and moving bed filter

    Science.gov (United States)

    Badger, Phillip C.; Dunn, Jr., Kenneth J.

    2015-09-01

    A moving bed gasification/thermal treatment reactor includes a geometry in which moving bed reactor particles serve as both a moving bed filter and a heat carrier to provide thermal energy for thermal treatment reactions, such that the moving bed filter and the heat carrier are one and the same to remove solid particulates or droplets generated by thermal treatment processes or injected into the moving bed filter from other sources.

  16. A fluidized-bed reactor for silane pyrolysis

    Science.gov (United States)

    Iya, S.

    1984-01-01

    The silane decomposition in a fluidized bed reactor was studied. The process feasibility and operating windows were determined. Long duration tests were conducted and silicon purity was demonstrated. A high purity linear was installed in the fluid bed reactor; the FBR product was melted and single crystallized. Product purity improvements are noted.

  17. Status of the pebble bed modular reactor

    International Nuclear Information System (INIS)

    Eskom is the South African state electricity utility, with an installed capacity of 38397 MW at the end of 1996 (some 98% of all national generating assets). It is largely coal-based with a small proportion (5%) nuclear. As part of Eskom's long-term planning process, investigations have been made into new power generation options. On reconsidering the nuclear option, Eskom identified two key issues: cost and public acceptance. It was considered that both of these were driven by the safety issues related to potential accidents and the only way to obtain competitive costs with nuclear power was to remove the potential (however remote) for accidents with significant off-site consequences. The only reactor type that was seen to meet this safety standard was the pebble bed modular reactor (PBMR). This paper discusses the PBMR project history, plant performance and design, its benefits, safety features, and current status. It concludes that the PBMR will provide South Africa with a competitive option for coastal generation and, internationally, it will be highly competitive with virtually all other generation options. (author)

  18. The fixed bed nuclear reactor concept

    International Nuclear Information System (INIS)

    The core of a water moderated Fixed Bed Nuclear Reactor (FBNR), possessing, for instance, an electrical power of 40 MW, consists of 1.35 million fuel pellets (9.5 t) with a diameter of 1.5 cm each. The low enriched uranium fuel is made of TRISO type microspheres used in the HTGR, embedded in a graphite matrix and cladded by a shell of 1 mm SiC. Under any thinkable operational condition the fuel temperature will be below 400 C whereas its stability limit is at about 1600 C. The first characteristic of the FBNR is, therefore, its robust fuel under relatively 'cold' operating conditions and - due to the outer SiC - shell layer - the freedom from any hydrogen production. To operate the reactor the fuel pellets are pumped by a flow of water from below into the core regions where they form a stable fixed bed of about 4 cubic meter and become critical for energy production heating the outlet water to about 330 C (at 160 bar) which feeds a steam generator. The new safety feature is now the following: In case of any abnormity (e.g. external power failure, overheating etc.) the circulating pump stops and - due to gravity - the fuel pellets fall automatically out of the core region into a helical 'fuel chamber' underneath the core where their decay heat is transferred passively by natural circulation to a water tank housing the fuel chamber. The safety principle, applied here, is: The loss of an active component (circulating pump) induces a self-controlled, passively working shut-down manoeuvre accompanied by a foolproof decay heat removal without any emergency power system or any human interaction. The fuel chamber is sealed and is transported as the only reactor component to and from the reactor site. There is no possibility to irradiate fertile fuel, too. For a long-life core (larger than a 10 years cycle time) the fuel can either be poisoned by gadolinium-oxide or by a piston type core limiter adjusting the height and controlling thereby the number of the fuel pellets in

  19. Study of reactivity of fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    The reactor physics calculations of a 19 module Fluidized Bed Nuclear Reactor using Leopard and Odog codes are performed. The behaviour of the reactor was studied by calculating the reactivity of the reactor as a function of the parameters governing the operational and accidental conditions of the reactor. The effects of temperature, pressure, and vapor generation in the core on the reactivity are calculated. Also the start up behaviour of the reactor is analyzed. For the purpose of the study of a prototype research reactor, the calculations on a one module reactor have been performed. (Author)

  20. Comparison of packed bed and fluidized bed membrane reactors for methane reforming

    OpenAIRE

    Gallucci, Fausto; Sint Annaland, van, Martin; Kuipers, J.A.M.

    2009-01-01

    In this work the performance of different membrane reactor concepts, both fluidized bed and packed bed membrane reactors, have been compared for the reforming of methane for the production of ultra-pure hydrogen. Using detailed theoretical models, the required membrane area to reach a given conversion and the prevailing temperature profiles have been compared. The extent of mass and heat transfer limitations in the different reactors have been evaluated, and strategies to decrease (or avoid) ...

  1. Fluidized bed nuclear reactor as a IV generation reactor

    International Nuclear Information System (INIS)

    The object of this paper is to analyze the characteristics of the Fluidized Bed Nuclear Reactor (FBNR) concept under the light of the requirements set for the IV generation nuclear reactors. It is seen that FBNR generally meets the goals of providing sustainable energy generation that meets clean air objectives and promotes long-term availability of systems and effective fuel utilization for worldwide energy production; minimize and manage their nuclear waste and notably reduce the long term stewardship burden in the future, thereby improving protection for the public health and the environment; increase the assurance that it is a very unattractive and least desirable route for diversion or theft of weapons-usable materials; excel in safety and reliability; have a very low likelihood and degree of reactor core damage; eliminate the need for offsite emergency response; have a clear life-cycle cost advantage over other energy sources; have a level of financial risk comparable to other energy projects. The other advantages of the proposed design are being modular, low environmental impact, exclusion of severe accidents, short construction period, flexible adaptation to demand, excellent load following characteristics, and competitive economics. (author)

  2. Multiscale Analysis of Pebble Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hans Gougar; Woo Yoon; Abderrafi Ougouag

    2010-10-01

    – The PEBBED code was developed at the Idaho National Laboratory for design and analysis of pebble-bed high temperature reactors. The diffusion-depletion-pebble-mixing algorithm of the original PEBBED code was enhanced through coupling with the THERMIX-KONVEK code for thermal fluid analysis and by the COMBINE code for online cross section generation. The COMBINE code solves the B-1 or B-3 approximations to the transport equation for neutron slowing down and resonance interactions in a homogeneous medium with simple corrections for shadowing and thermal self-shielding. The number densities of materials within specified regions of the core are averaged and transferred to COMBINE from PEBBED for updating during the burnup iteration. The simple treatment of self-shielding in previous versions of COMBINE led to inaccurate results for cross sections and unsatisfactory core performance calculations. A new version of COMBINE has been developed that treats all levels of heterogeneity using the 1D transport code ANISN. In a 3-stage calculation, slowing down is performed in 167 groups for each homogeneous subregion (kernel, particle layers, graphite shell, control rod absorber annulus, etc.) Particles in a local average pebble are homogenized using ANISN then passed to the next (pebble) stage. A 1D transport solution is again performed over the pebble geometry and the homogenized pebble cross sections are passed to a 1-d radial model of a wedge of the pebble bed core. This wedge may also include homogeneous reflector regions and a control rod region composed of annuli of different absorbing regions. Radial leakage effects are therefore captured with discrete ordinates transport while axial and azimuthal effects are captured with a transverse buckling term. In this paper, results of various PBR models will be compared with comparable models from literature. Performance of the code will be assessed.

  3. An energy amplifier fluidized bed nuclear reactor concept

    International Nuclear Information System (INIS)

    The concept of a fluidized bed nuclear reactor driven by an energy amplifier system is described. The reactor has promising characteristics of inherent safety and passive cooling. The reactor can easily operate with any desired spectrum in order to be a plutonium burner or have it operate with thorium fuel cycle. (orig.)

  4. A Pebble Bed Reactor cross section methodology

    International Nuclear Information System (INIS)

    A method is presented for the evaluation of microscopic cross sections for the Pebble Bed Reactor (PBR) neutron diffusion computational models during convergence to an equilibrium (asymptotic) fuel cycle. This method considers the isotopics within a core spectral zone and the leakages from such a zone as they arise during reactor operation. The randomness of the spatial distribution of fuel grains within the fuel pebbles and that of the fuel and moderator pebbles within the core, the double heterogeneity of the fuel, and the indeterminate burnup of the spectral zones all pose a unique challenge for the computation of the local microscopic cross sections. As prior knowledge of the equilibrium composition and leakage is not available, it is necessary to repeatedly re-compute the group constants with updated zone information. A method is presented to account for local spectral zone composition and leakage effects without resorting to frequent spectrum code calls. Fine group data are pre-computed for a range of isotopic states. Microscopic cross sections and zone nuclide number densities are used to construct fine group macroscopic cross sections, which, together with fission spectra, flux modulation factors, and zone buckling, are used in the solution of the slowing down balance to generate a new or updated spectrum. The microscopic cross-sections are then re-collapsed with the new spectrum for the local spectral zone. This technique is named the Spectral History Correction (SHC) method. It is found that this method accurately recalculates local broad group microscopic cross sections. Significant improvement in the core eigenvalue, flux, and power peaking factor is observed when the local cross sections are corrected for the effects of the spectral zone composition and leakage in two-dimensional PBR test problems.

  5. Survey of dust production in pebble bed reactor cores

    International Nuclear Information System (INIS)

    Highlights: → We review potential sources of the graphite dust found in the German pebble bed reactors. → Available literature on graphite wear coefficients in pebble bed core-like conditions is reviewed. → Limited conclusions and remaining open questions are discussed. - Abstract: Graphite dust produced via mechanical wear from the pebbles in a pebble bed reactor is an area of concern for licensing. Both the German pebble bed reactors produced graphite dust that contained activated elements. These activation products constitute an additional source term of radiation and must be taken under consideration during the conduct of accident analysis of the design. This paper discusses the available literature on graphite dust production and measurements in pebble bed reactors. Limited data is available on the graphite dust produced from the AVR and THTR-300 pebble bed reactors. Experiments that have been performed on wear of graphite in pebble-bed-like conditions are reviewed. The calculation of contact forces, which are a key driving mechanism for dust in the reactor, are also included. In addition, prior graphite dust predictions are examined, and future areas of research are identified.

  6. COMPUTATIONAL MODELING OF CIRCULATING FLUIDIZED BED REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Ibrahim, Essam A

    2013-01-09

    Details of numerical simulations of two-phase gas-solid turbulent flow in the riser section of Circulating Fluidized Bed Reactor (CFBR) using Computational Fluid Dynamics (CFD) technique are reported. Two CFBR riser configurations are considered and modeled. Each of these two riser models consist of inlet, exit, connecting elbows and a main pipe. Both riser configurations are cylindrical and have the same diameter but differ in their inlet lengths and main pipe height to enable investigation of riser geometrical scaling effects. In addition, two types of solid particles are exploited in the solid phase of the two-phase gas-solid riser flow simulations to study the influence of solid loading ratio on flow patterns. The gaseous phase in the two-phase flow is represented by standard atmospheric air. The CFD-based FLUENT software is employed to obtain steady state and transient solutions for flow modulations in the riser. The physical dimensions, types and numbers of computation meshes, and solution methodology utilized in the present work are stated. Flow parameters, such as static and dynamic pressure, species velocity, and volume fractions are monitored and analyzed. The differences in the computational results between the two models, under steady and transient conditions, are compared, contrasted, and discussed.

  7. Hydrodynamics of multi-phase packed bed micro-reactors

    OpenAIRE

    Márquez Luzardo, N.M.

    2010-01-01

    Why to use packed bed micro-reactors for catalyst testing? Miniaturized packed bed reactors have a large surface-to-volume ratio at the reactor and particle level that favors the heat- and mass-transfer processes at all scales (intra-particle, inter-phase and inter-particle or reactor level). If the mass-transfer processes are fast in respect to the reaction-rate, then the reaction-rate is under kinetic control over the entire range of conversion and it is possible to measure intrinsic kineti...

  8. JPL in-house fluidized-bed reactor research

    Science.gov (United States)

    Rohatgi, N. K.

    1984-01-01

    Fluidized bed reactor research techniques for fabrication of quartz linears was reviewed. Silane pyrolysis was employed in this fabrication study. Metallic contaminant levels in the silicon particles were below levels detectable by emission spectroscopy.

  9. Feedback linearizing control of a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Aoufoussi, H.; Perrier, M.; Chaouki, J.; Chavarie, C.; Dochain, D. (Ecole Polytechnique de Montreal, Montreal, PQ (Canada). Dept. de Genie Chimique)

    1992-04-01

    A linearized technique has been applied to temperature control for a fluidized bed reactor. A nonlinear antiwindup mechanism for the reset action is used. Simulation tests show that the controller provides good setpoint tracking. 24 refs.; 11 figs.; 4 tabs.

  10. Deleterious Thermal Effects Due To Randomized Flow Paths in Pebble Bed, and Particle Bed Style Reactors

    Science.gov (United States)

    Moran, Robert P.

    2013-01-01

    A review of literature associated with Pebble Bed and Particle Bed reactor core research has revealed a systemic problem inherent to reactor core concepts which utilize randomized rather than structured coolant channel flow paths. For both the Pebble Bed and Particle Bed Reactor designs; case studies reveal that for indeterminate reasons, regions within the core would suffer from excessive heating leading to thermal runaway and localized fuel melting. A thermal Computational Fluid Dynamics model was utilized to verify that In both the Pebble Bed and Particle Bed Reactor concepts randomized coolant channel pathways combined with localized high temperature regions would work together to resist the flow of coolant diverting it away from where it is needed the most to cooler less resistive pathways where it is needed the least. In other words given the choice via randomized coolant pathways the reactor coolant will take the path of least resistance, and hot zones offer the highest resistance. Having identified the relationship between randomized coolant channel pathways and localized fuel melting it is now safe to assume that other reactor concepts that utilize randomized coolant pathways such as the foam core reactor are also susceptible to this phenomenon.

  11. Nonlinear dynamics and control of a recycle fixed bed reactor

    OpenAIRE

    Recke, Bodil; Jørgensen, Sten Bay

    1997-01-01

    The purpose of this paper is twofold. Primarily to describe the dynamic behaviour that can be observed in a fixed bed reactor with recycle of unconverted reactant. Secondly to describe the possibilities of model reduction in order to facilitate control design. Reactant recycle has been shown to introduce periodic solution to the fixed bed reactor, a phenomenon which is not seen for the system without the recycle, at least not within the Peclet number range investigated in the present work. Th...

  12. A Spouted Bed Reactor Monitoring System for Particulate Nuclear Fuel

    International Nuclear Information System (INIS)

    Conversion and coating of particle nuclear fuel is performed in spouted (fluidized) bed reactors. The reactor must be capable of operating at temperatures up to 2000 C in inert, flammable, and coating gas environments. The spouted bed reactor geometry is defined by a graphite retort with a 2.5 inch inside diameter, conical section with a 60o included angle, and a 4 mm gas inlet orifice diameter through which particles are removed from the reactor at the completion of each run. The particles may range from 200 (micro)m to 2 mm in diameter. Maintaining optimal gas flow rates slightly above the minimum spouting velocity throughout the duration of each run is complicated by the variation of particle size and density as conversion and/or coating reactions proceed in addition to gas composition and temperature variations. In order to achieve uniform particle coating, prevent agglomeration of the particle bed, and monitor the reaction progress, a spouted bed monitoring system was developed. The monitoring system includes a high-sensitivity, low-response time differential pressure transducer paired with a signal processing, data acquisition, and process control unit which allows for real-time monitoring and control of the spouted bed reactor. The pressure transducer is mounted upstream of the spouted bed reactor gas inlet. The gas flow into the reactor induces motion of the particles in the bed and prevents the particles from draining from the reactor due to gravitational forces. Pressure fluctuations in the gas inlet stream are generated as the particles in the bed interact with the entering gas stream. The pressure fluctuations are produced by bulk movement of the bed, generation and movement of gas bubbles through the bed, and the individual motion of particles and particle subsets in the bed. The pressure fluctuations propagate upstream to the pressure transducer where they can be monitored. Pressure fluctuation, mean differential pressure, gas flow rate, reactor

  13. A Spouted Bed Reactor Monitoring System for Particulate Nuclear Fuel

    Energy Technology Data Exchange (ETDEWEB)

    D. S. Wendt; R. L. Bewley; W. E. Windes

    2007-06-01

    Conversion and coating of particle nuclear fuel is performed in spouted (fluidized) bed reactors. The reactor must be capable of operating at temperatures up to 2000°C in inert, flammable, and coating gas environments. The spouted bed reactor geometry is defined by a graphite retort with a 2.5 inch inside diameter, conical section with a 60° included angle, and a 4 mm gas inlet orifice diameter through which particles are removed from the reactor at the completion of each run. The particles may range from 200 µm to 2 mm in diameter. Maintaining optimal gas flow rates slightly above the minimum spouting velocity throughout the duration of each run is complicated by the variation of particle size and density as conversion and/or coating reactions proceed in addition to gas composition and temperature variations. In order to achieve uniform particle coating, prevent agglomeration of the particle bed, and monitor the reaction progress, a spouted bed monitoring system was developed. The monitoring system includes a high-sensitivity, low-response time differential pressure transducer paired with a signal processing, data acquisition, and process control unit which allows for real-time monitoring and control of the spouted bed reactor. The pressure transducer is mounted upstream of the spouted bed reactor gas inlet. The gas flow into the reactor induces motion of the particles in the bed and prevents the particles from draining from the reactor due to gravitational forces. Pressure fluctuations in the gas inlet stream are generated as the particles in the bed interact with the entering gas stream. The pressure fluctuations are produced by bulk movement of the bed, generation and movement of gas bubbles through the bed, and the individual motion of particles and particle subsets in the bed. The pressure fluctuations propagate upstream to the pressure transducer where they can be monitored. Pressure fluctuation, mean differential pressure, gas flow rate, reactor

  14. Granular Dynamics in Pebble Bed Reactor Cores

    Science.gov (United States)

    Laufer, Michael Robert

    This study focused on developing a better understanding of granular dynamics in pebble bed reactor cores through experimental work and computer simulations. The work completed includes analysis of pebble motion data from three scaled experiments based on the annular core of the Pebble Bed Fluoride Salt-Cooled High- Temperature Reactor (PB-FHR). The experiments are accompanied by the development of a new discrete element simulation code, GRECO, which is designed to offer a simple user interface and simplified two-dimensional system that can be used for iterative purposes in the preliminary phases of core design. The results of this study are focused on the PB-FHR, but can easily be extended for gas-cooled reactor designs. Experimental results are presented for three Pebble Recirculation Experiments (PREX). PREX 2 and 3.0 are conventional gravity-dominated granular systems based on the annular PB-FHR core design for a 900 MWth commercial prototype plant and a 16 MWth test reactor, respectively. Detailed results are presented for the pebble velocity field, mixing at the radial zone interfaces, and pebble residence times. A new Monte Carlo algorithm was developed to study the residence time distributions of pebbles in different radial zones. These dry experiments demonstrated the basic viability of radial pebble zoning in cores with diverging geometry before pebbles reach the active core. Results are also presented from PREX 3.1, a scaled facility that uses simulant materials to evaluate the impact of coupled fluid drag forces on the granular dynamics in the PB-FHR core. PREX 3.1 was used to collect first of a kind pebble motion data in a multidimensional porous media flow field. Pebble motion data were collected for a range of axial and cross fluid flow configurations where the drag forces range from half the buoyancy force up to ten times greater than the buoyancy force. Detailed analysis is presented for the pebble velocity field, mixing behavior, and residence time

  15. Pebble Bed Reactor review update. Fiscal year 1979 annual report

    International Nuclear Information System (INIS)

    Updated information is presented on the Pebble Bed Reactor (PBR) concept being developed in the Federal Republic of Germany for electricity generation and process heat applications. Information is presented concerning nuclear analysis and core performance, fuel cycle evaluation, reactor internals, and safety and availability

  16. Pebble Bed Reactor review update. Fiscal year 1979 annual report

    Energy Technology Data Exchange (ETDEWEB)

    1980-01-01

    Updated information is presented on the Pebble Bed Reactor (PBR) concept being developed in the Federal Republic of Germany for electricity generation and process heat applications. Information is presented concerning nuclear analysis and core performance, fuel cycle evaluation, reactor internals, and safety and availability.

  17. Biological Phosphorus Removal in a Moving Bed Biofilm Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Helness, Herman

    2007-09-15

    The scope of this study was to investigate use of the moving bed biofilm reactor (MBBR) process for biological phosphorus removal. The goal has been to describe the operating conditions required for biological phosphorus and nitrogen removal in a MBBR operated as a sequencing batch reactor (SBR), and determine dimensioning criteria for such a process

  18. Hydrodynamic Reaction Model of a Spouted Bed Electrolytic Reactor

    Science.gov (United States)

    Alireza Shirvanian, Pezhman; Calo, Joseph

    2002-08-01

    An Eulerian model is presented that has been developed to describe the hydrodynamics, mass transfer, and metal ion reduction mass transfer in a cylindrical, spouted bed electrolytic reactor. Appropriate boundary conditions are derived from kinetic theory and reaction kinetics for the hydrodynamics and mass transfer and reaction on the cathodic conical bottom of the reactor, respectively. This study was undertaken as a part of a project focused on the development of a Spouted Bed Electrolytic Reactor (SBER) for metals recovery. The results presented here include the effect of particle loading, inlet jet velocity, Solution pH, and temperature on void fraction distribution, pressure drop, particles recirculation rate, and metal recovery rate.

  19. Water desalination by a fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    The great need for potable water in the world motivated the International Atomic Energy Agency (IAEA) to study the feasibility of nuclear seawater desalination. The consensus reached is that nuclear desalination is technically feasible, though cost and social acceptability are recognized as major problems to overcome. Here an inherently safe reactor with reduced cost is proposed to overcome these barriers. The reactor is a simple small modular nuclear reactor based on fluidized bed concept with passive cooling characteristics. (orig.)

  20. Absorber rod for pebble-bed reactor

    International Nuclear Information System (INIS)

    The absorber rod that can be moved into the pebble bed from the top reflector is enclosed by a cladding tube which, if it is completely moved down, ends above the pebble bed and is open at the bottom. Through the cladding tube the absorber rod is cooled with gas. The cladding tube consists of e.g. boron steel. If the absorber rod is drawn it takes along the cladding tube which is moved into the guide tube like a telescope. The rigidity of that part of the absorber rod projecting from the pebble bed is thus guaranteed. (DG)

  1. Computational fluid dynamic modeling of fluidized-bed polymerization reactors

    Energy Technology Data Exchange (ETDEWEB)

    Rokkam, Ram [Iowa State Univ., Ames, IA (United States)

    2012-01-01

    Polyethylene is one of the most widely used plastics, and over 60 million tons are produced worldwide every year. Polyethylene is obtained by the catalytic polymerization of ethylene in gas and liquid phase reactors. The gas phase processes are more advantageous, and use fluidized-bed reactors for production of polyethylene. Since they operate so close to the melting point of the polymer, agglomeration is an operational concern in all slurry and gas polymerization processes. Electrostatics and hot spot formation are the main factors that contribute to agglomeration in gas-phase processes. Electrostatic charges in gas phase polymerization fluidized bed reactors are known to influence the bed hydrodynamics, particle elutriation, bubble size, bubble shape etc. Accumulation of electrostatic charges in the fluidized-bed can lead to operational issues. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the dynamics of a fluidized-bed. The multi-fluid CFD model for gas-particle flow is based on the kinetic theory of granular flows closures. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer, polymer fines) phase. The combined CFD model is first verified using simple test cases, validated with experiments and applied to a pilot-scale polymerization fluidized-bed reactor. The CFD model reproduced qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments. For the scale up of fluidized bed reactor, filtered models are developed and implemented on pilot scale reactor.

  2. Reactor modeling and physicochemical properties characterization for a polyethylene fluidized bed reactor

    OpenAIRE

    F. A. N. Fernandes; L. M. F. LONA BATISTA

    1999-01-01

    A new steady state model for the fluidized bed reactor and a physicochemical characterization model were developed for the simulation of polyethylene production using gas-phase technology. The association of these models was done in order to predict the characteristics of the polymer produced in the fluidized bed reactor (molecular weight, polydispersity, melt index, and other characteristics) throughout the reactor and also to predict the growth of the polymer particle.

  3. Reactor modeling and physicochemical properties characterization for a polyethylene fluidized bed reactor

    Directory of Open Access Journals (Sweden)

    FERNANDES F. A. N.

    1999-01-01

    Full Text Available A new steady state model for the fluidized bed reactor and a physicochemical characterization model were developed for the simulation of polyethylene production using gas-phase technology. The association of these models was done in order to predict the characteristics of the polymer produced in the fluidized bed reactor (molecular weight, polydispersity, melt index, and other characteristics throughout the reactor and also to predict the growth of the polymer particle.

  4. Effect of bed configuration on pebble flow uniformity and stagnation in the pebble bed reactor

    International Nuclear Information System (INIS)

    Highlights: • Pebble flow uniformity and stagnation characteristics are very important for HTR-PM. • Arc- and brachistochrone-shaped configuration effects are studied by DEM simulation. • Best bed configurations with uniform flow and no stagnated pebbles are suggested. • Detailed quantified characteristics of bed configuration effects are shown for explanation. - Abstract: Pebble flow uniformity and stagnation characteristics are very important for the design of pebble bed high temperature gas-cooled reactor. Pebble flows inside some specifically designed contraction configurations of pebble bed are studied by discrete element method. The results show the characteristics of stagnation rates, recycling rates, radial distribution of pebble velocity and residence time. It is demonstrated clearly that the bed with a brachistochrone-shaped configuration achieves optimum levels of flow uniformity and recycling rate concentration, and almost no pebbles are stagnated in the bed. Moreover, the optimum choice among the arc-shaped bed configurations is demonstrated too. Detailed information shows the quantified characteristics of bed configuration effects on flow uniformity. In addition, a good design of the pebble bed configuration is suggested

  5. Propylene polymerization in a circulating slugging fluidized bed reactor

    OpenAIRE

    Putten, van, J.P.M.

    2004-01-01

    The work presented in this thesis is concerned with research on the riser of a circulating fluidized bed system for olefin polymerization. In the riser section, fluidization takes place in the transporting slugging mode and polymer particles are produced in the riser in a non-isothermal way. Properties of the polymerization reaction and of the hydrodynamics were studied and their behavior with respect to conditions in the reactor were described. A reactor model was constructed that accurately...

  6. Automation of a fixed-bed continuous–flow reactor

    OpenAIRE

    Alcántara, R.; Canoira, L.; R. Conde; Fernández-Sánchez, J. M.; Navarro, A.

    1994-01-01

    This paper describes the design and operation of a laboratory plant with a fixed-bed continuous-flow reactor, fully automated and controlled from a personal computer. The automated variables include two gas flows, one liquid flow, six temperatures, two pressures, one circulation of a cooling liquid, and 10 electrovalves. An adaptive-predictive control system was used. The chemical process chosen to run the automated reactor was the conversion of methanol to gasoline over a ZSM-5 catalyst. Thi...

  7. DEGRADATION OF AROMATIC COMPOUNDS USING MOVING BED BIOFILM REACTORS

    Directory of Open Access Journals (Sweden)

    B. Ayati, H. Ganjidoust, M. Mir Fattah

    2007-04-01

    Full Text Available For biological treatment of water, there are many different biofilm systems in use. Examples of them are trickling filters, rotating biological contactors, fixed media submerged biofilters, granular media biofilters and fluidized bed reactors. They all have their advantages and disadvantages. Hence, the Moving Bed Biofilm Reactor process was developed in Norway in the late 1980s and early 1990s to adopt the best features of the activated sludge process as well as those of the biofilter processes, without including the worst. Two cylindrical moving bed biofilm reactors were used in this study working in upflow stream conditions. Experiments have been done in aerobic batch flow regime. Laboratory experiments were conducted at room temperature (23–28C and synthetic wastewater comprising a composition of phenol and hydroquinone in each reactor as the main organic constituents, plus balanced nutrients and alkalinity were used to feed the reactor. The ratio of influent to effluent COD was determined at different retention times. The results indicated that the removal efficiency of each selected compound is affected by the detention time. At low phenol and hydroquinone concentration (from 700 to 1000 mg/L maximum removal efficiency (over 80 % was obtained. By further increasing in COD loading rate up to 3000 mg/L, a decrease in COD removal rate was occurred. In the reactor containing pyrogallol in COD of 1500 mg/L, the removal rate decreased to 10 percent because of its toxicity for microorganisms.

  8. Circulating fluidized bed biological reactor for nutrients removal

    Institute of Scientific and Technical Information of China (English)

    Yubo CUI; Hongbo LIU; Chunxue BAI

    2008-01-01

    A new biological nitrogen removal process, which is named herein "The circulating fluidized bed bio-reactor (CFBBR)", was developed for simultaneous removal of nitrogen and organic matter. This process was composed of an anaerobic bed (Riser), aerobic bed (Downer) and connecting device. Influent and nitrified liquid from the aerobic bed enters the anaerobic bed from the bottom of the anaerobic bed, completing the removal of nitrogen and organic matter. The system performance under the conditions of different inflow loadings and nitrified liquid recirculation rates ranging from 200% to 600% was examined. From a technical and economic point of view, the optimum nitrified liquid recirculation rate was 400%. With a shortest total retention time of 2.5 h (0.8 h in the anaerobic bed and 1.5 h in the aerobic bed) and a nitrified liquid recir-culation rate of 400% based on the intluent flow rate, the average removal efficiencies of total nitrogen (TN) and sol-uble chemical oxygen demand (SCOD) were found to be 88% and 95%, respectively. The average effluent concentra-tions of TN and SCOD were 3.5 mg/L and 16 mg/L, respectively. The volatile suspended solid (VSS) concentra-tion, nitrification rate and denitrification rate in the system were less than 1.0 g/L, 0.026-0.1 g NH4+-N/g VSS.d, and 0.016-0.074 g NOx--N/g VSS.d, respectively.

  9. Lagrangian Approach to Study Catalytic Fluidized Bed Reactors

    Science.gov (United States)

    Madi, Hossein; Hossein Madi Team; Marcelo Kaufman Rechulski Collaboration; Christian Ludwig Collaboration; Tilman Schildhauer Collaboration

    2013-03-01

    Lagrangian approach of fluidized bed reactors is a method, which simulates the movement of catalyst particles (caused by the fluidization) by changing the gas composition around them. Application of such an investigation is in the analysis of the state of catalysts and surface reactions under quasi-operando conditions. The hydrodynamics of catalyst particles within a fluidized bed reactor was studied to improve a Lagrangian approach. A fluidized bed methanation employed in the production of Synthetic Natural Gas from wood was chosen as the case study. The Lagrangian perspective was modified and improved to include different particle circulation patterns, which were investigated through this study. Experiments were designed to evaluate the concepts of the model. The results indicate that the setup is able to perform the designed experiments and a good agreement between the simulation and the experimental results were observed. It has been shown that fluidized bed reactors, as opposed to fixed beds, can be used to avoid the deactivation of the methanation catalyst due to carbon deposits. Carbon deposition on the catalysts tested with the Lagrangian approach was investigated by temperature programmed oxidation (TPO) analysis of ex-situ catalyst samples. This investigation was done to identify the effects of particles velocity and their circulation patterns on the amount and type of deposited carbon on the catalyst surface. Ecole Polytechnique Federale de Lausanne(EPFL), Paul Scherrer Institute (PSI)

  10. The Performance of Structured Packings in Trickle-Bed Reactors

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, W.P.M. van

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  11. The performance of structured packings in trickle-bed reactors.

    NARCIS (Netherlands)

    Frank, M.J.W.; Kuipers, J.A.M.; Versteeg, G.F.; Swaaij, van W.P.M.

    1999-01-01

    An experimental study was carried out to investigate whether the use of structured packings might improve the mass transfer characteristics and the catalyst effectiveness of a trickle-bed reactor. Therefore, the performances of a structured packing, consisting of KATAPAK elements, and a dumped packi

  12. Nonlinear dynamics and control of a recycle fixed bed reactor

    DEFF Research Database (Denmark)

    Recke, Bodil; Jørgensen, Sten Bay

    1997-01-01

    The purpose of this paper is twofold. Primarily to describe the dynamic behaviour that can be observed in a fixed bed reactor with recycle of unconverted reactant. Secondly to describe the possibilities of model reduction in order to facilitate control design. Reactant recycle has been shown to...

  13. Dicyclopentadiene Hydrogenation in Trickle Bed Reactor under Forced Periodic Control

    Czech Academy of Sciences Publication Activity Database

    Skála, D.; Hanika, Jiří

    2008-01-01

    Roč. 62, č. 2 (2008), s. 215-218. ISSN 1336-7242 R&D Projects: GA MPO(CZ) FT-TA/039 Institutional research plan: CEZ:AV0Z40720504 Keywords : periodic control * trickle-bed reactor * dicyclopentadiene Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  14. Combustion of Corn Straw in a Fluidized-Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Durda, Tomáš

    Prague : Institute of Chemical Process Fundamental of the CAS, v. v. i, 2015 - (Bendová, M.; Wagner, Z.), s. 22-23 ISBN 978-80-86186-70-2. [Bažant Postgraduate Conference 2015. Prague (CZ)] Institutional support: RVO:67985858 Keywords : fluidized-bed reactor * combustion processes * corn straw Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  15. Trickle Bed Reactor Operation under Forced Liquid Feed Rate Modulation

    Czech Academy of Sciences Publication Activity Database

    Hanika, Jiří; Jiřičný, Vladimír; Karnetová, P.; Kolena, J.; Lederer, J.; Skála, D.; Staněk, Vladimír; Tukač, V.

    2007-01-01

    Roč. 13, č. 4 (2007), s. 192-198. ISSN 1451-9372 R&D Projects: GA MPO(CZ) FT-TA/039 Institutional research plan: CEZ:AV0Z40720504 Keywords : trickle-bed reactor * period * feed rate Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  16. Theoretical study of a solar fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Bizarro, P.; Le Palec, G.; Daguenet, M. (Laboratoire de Thermodynamique et Energetique, Universite de Perpignan (France))

    1984-01-01

    The authors calculate numerically the temperature and concentration profiles in a catalytic packed bed reactor submitted to concentrated solar radiation. They examine the co-current case (gas circulates in the direction of heat flow) as well as the counter-current case (gas circulates in the opposite direction) and study the influence of various parameters on the chemical reaction rate.

  17. Dynamic stability of a fluidized-bed nuclear reactor

    International Nuclear Information System (INIS)

    Recent advances in the study of a fluidized-bed nuclear reactor's stability, due to short and long time transients, are discussed. The point-kinetic model, which considers flux variation in the axial direction, is applied to study short time transients, and the theory of bifurcation is used for long time transients. Numerical results are presented for both transients. The preliminary results indicate that this concept of a nuclear reactor has a behavior similar to that of a conventional reactor regarding its dynamic stability

  18. Study on transient of fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    The point kinetic equations for a Fluidized-Bed Nuclear Reactor are solved by the method of Hansen. Due to the time varying nature of the reactor volume, the equations have a non-conventional formulation (moving boundary problem), but the method of solution preserves its asymptotic convergence and efficiency characteristics under this formulation. A one dimensional and linearized thermal hydraulics feedback model was coupled to the point kinetic equations in order to obtain a more realistic representation of the reactor power. The resulting equations are solved by the Euler explicit method. (author)

  19. In-core fuel management for pebble-bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Milian Perez, Daniel; Rodriguez Garcia, Lorena; Garcia Hernandez, Carlos; Milian Lorenzo, Daniel, E-mail: dperez@instec.cu, E-mail: cgh@instec.cu, E-mail: dmilian@instec.cu [Higher Institute of Technologies and Applied Sciences, Havana (Cuba); Velasco, Abanades, E-mail: abanades@etsii.upm.es [Department of Simulation of Thermo Energy Systems, Polytechnic University of Madrid (Spain)

    2013-07-01

    In this paper a calculation procedure to reduce the power peak in the core of a Very High Temperature pebble bed Reactor is presented. This procedure combines the fuel depletion and the neutronic behavior of the fuel in the reactor core, modeling once-through-then-out cycles as well as cycles in which pebbles are recirculated through the core an arbitrary number of times, obtaining the asymptotic fuel-loading pattern. The procedure consists in several coupled computational codes, which are used iteratively until convergence is reached. The utilization of the MCNPX 2.6e, as one of these computational codes, is validated through the calculation of benchmarks announced by IAEA (IAEA-TECDOC-1249, 2001). To complete the verification of the calculation procedure a base case described in (Annals of Nuclear Energy 29 (2002) 1345-1364), was performed. The procedure has been applied to a model of Pebble Bed Modular Reactor (200 MW) design. (author)

  20. High power density reactors based on direct cooled particle beds

    International Nuclear Information System (INIS)

    Reactors based on direct cooled HTGR type particle fuel are described. The small diameter particle fuel is packed between concentric porous cylinders to make annular fuel elements, with the inlet coolant gas flowing inwards. Hot exit gas flows out long the central channel of each element. Because of the very large heat transfer area in the packed beds, power densities in particle bed reactors (PBR's) are extremely high resulting in compact, lightweight systems. Coolant exit temperatures are high, because of the ceramic fuel temperature capabilities, and the reactors can be ramped to full power and temperature very rapidly. PBR systems can generate very high burst power levels using open cycle hydrogen coolant, or high continuous powers using closed cycle helium coolant. PBR technology is described and development requirements assessed. 12 figs

  1. Pellet bed reactor for multi-modal space power

    International Nuclear Information System (INIS)

    A review of forthcoming space power needs for both civil and military missions indicates that power requirements will be in tens of megawatts. It is envisioned that the electrical power requirements will be two-fold; long-duration low power will be needed for station keeping, communications and/or surveillance, while short-duration high power will be required for pulsed power devices. These power characteristics led to authors to propose a multi-modal space power reactor using a pellet bed design. Characteristics desired for such a multi-megawatt reactor power source are the following: standby, alert and pulsed power modes; high thermal output heat source (around 1000 MWt peak power); long lifetime standby power (10-30 yrs); high temperature output (1500-1750 K); rapid burst power transition; high reliability (>95%); and meets stringent safety requirements. The proposed pellet bed reactor concept is designed to satisfy these characteristics

  2. Pebble Bed Reactor: core physics and fuel cycle analysis

    International Nuclear Information System (INIS)

    The Pebble Bed Reactor is a gas-cooled, graphite-moderated high-temperature reactor that is continuously fueled with small spherical fuel elements. The projected performance was studied over a broad range of reactor applicability. Calculations were done for a burner on a throwaway cycle, a converter with recycle, a prebreeder and breeder. The thorium fuel cycle was considered using low, medium (denatured), and highly enriched uranium. The base calculations were carried out for electrical energy generation in a 1200 MW/sub e/ plant. A steady-state, continuous-fueling model was developed and one- and two-dimensional calculations were used to characterize performance. Treating a single point in time effects considerable savings in computer time as opposed to following a long reactor history, permitting evaluation of reactor performance over a broad range of design parameters and operating modes

  3. Rotating bed reactor for CLC: Bed characteristics dependencies on internal gas mixing

    International Nuclear Information System (INIS)

    Highlights: • A mathematical model for the rotating CLC reactor has been developed. • The model reflects the gas distribution in the reactor during CLC operation. • Radial dispersion in the rotating bed is the main cause for internal gas mixing. • The model can be used to optimize the reactor design and particle characteristics. - Abstract: A newly designed continuous lab-scale rotating bed reactor for chemical looping combustion using CuO/Al2O3 oxygen carrier spheres and methane as fuel gives around 90% CH4 conversion and >90% CO2 capture efficiency based on converted methane at 800 °C. However, from a series of experiments using a broad range of operating conditions potential CO2 purities only in the range 20–65% were yielded, mostly due to nitrogen slip from the air side of the reactor into the effluent CO2 stream. A mathematical model was developed intending to understand the air-mixing phenomena. The model clearly reflects the gas slippage tendencies observed when varying the process conditions such as rotation frequency, gas flow and the flow if inert gas in the two sectors dividing the air and fuel side of the reactor. Based on the results, it is believed that significant improvements can be made to reduce gas mixing in future modified and scaled-up reactor versions

  4. Biodenitrification of gaseous diffusion plant aqueous wastes: stirred bed reactor

    International Nuclear Information System (INIS)

    Approximately 30 kilograms of nitrates per day are discarded in the raffinates (acid wastes) of the Portsmouth Gaseous Diffusion Plant's X-705 Uranium Recovery and Decontamination Facility. A biodenitrification process employing continuous-flow, stirred-bed reactors has been successfully used to remove nitrates from similar acid wastes at the Oak Ridge Y-12 Plant. Laboratory studies have been made at Portsmouth to characterize the X-705 raffinates and to test the stirred-bed biodenitrification process on such raffinates. Raffinates which had been previously characterized were pumped through continuous-flow, stirred-bed, laboratory-scale reactors. Tests were conducted over a period of 146 days and involved variations in composition, mixing requirements, and the fate of several metal ions in the raffinates. Tests results show that 20 weight percent nitrates were reduced to a target nitrate effluent concentration of 100 μg/ml with a 99.64 percent efficiency. However, the average denitrification rate achieved was only 33% of that demonstrated with the Y-12 stirred-bed system. These low rates were probably due to the toxic effects of heavy metal ions on the denitrifying bacteria. Also, most of the uranium in the raffinate feed remained in the biomass and calcite, which collected in the reactor. This could cause criticality problems. For these reasons, it was decided not to make use of the stirred-bed bioreactor at Portsmouth. Instead, the biodenitrification installation now planned will use fluidized bed columns whose performance will be the subject of a subsequent report

  5. Starter culture production in fluidized bed reactor with a flocculent strain ofL. plantarum

    OpenAIRE

    Barreto, M.T.O.; Melo, E. P.; Carrondo, M J T

    1989-01-01

    A lactic starter culture of a flocculentLactobacillus plantarum was produced in a fluidized bed reactor with higher cell volumetric productivities than in a continuous stirred tank reactor. The fluidized bed reactor was operated at optimised parameters obtained in batch reactor performed with and without pH control.

  6. Waste tyre pyrolysis: modelling of a moving bed reactor.

    Science.gov (United States)

    Aylón, E; Fernández-Colino, A; Murillo, R; Grasa, G; Navarro, M V; García, T; Mastral, A M

    2010-12-01

    This paper describes the development of a new model for waste tyre pyrolysis in a moving bed reactor. This model comprises three different sub-models: a kinetic sub-model that predicts solid conversion in terms of reaction time and temperature, a heat transfer sub-model that calculates the temperature profile inside the particle and the energy flux from the surroundings to the tyre particles and, finally, a hydrodynamic model that predicts the solid flow pattern inside the reactor. These three sub-models have been integrated in order to develop a comprehensive reactor model. Experimental results were obtained in a continuous moving bed reactor and used to validate model predictions, with good approximation achieved between the experimental and simulated results. In addition, a parametric study of the model was carried out, which showed that tyre particle heating is clearly faster than average particle residence time inside the reactor. Therefore, this fast particle heating together with fast reaction kinetics enables total solid conversion to be achieved in this system in accordance with the predictive model. PMID:20510597

  7. TREATMENT OF POME BY PILOT PLANT ANAEROBIC FLUIDISED BED REACTOR

    OpenAIRE

    Abdullah Al-Mamun; Azni Idris

    2010-01-01

    A pilot scale anaerobic fluidised bed reactor (AnFBR) of 2000 L capacity was studied to determine its performance to treat palm oil mill effluent (POME). The pilot plant was operated at ambient temperature with diluted POME as substrate. It took 17 days for the start-up of the reactor with pre-seeded sand media. The AnFBR was capable to remove a large portion of organics at relatively shorter retention time. Maximum and minimum COD removal efficiency of 85% and 65% were attained at a ...

  8. Thorium and plutonium utilisation in pebble-bed modular reactor

    International Nuclear Information System (INIS)

    Thorium and plutonium utilisation in a high temperature gas-cooled pebble-bed reactor is investigated with the aim to predict the economic value of vast thorium reserves in Turkey. A pebble-bed reactor of the type designed by PBMR Pty. of South Africa is taken as the investigated system. The equilibrium core of a PBMR is considered and neutronics analyses of such a core are performed through the use of the SCALE-4.4 computer code system KENOV.a module. Various cross-section libraries are used to calculate the criticality of the core. Burn-up calculations of the core are performed by coupling the KENOV.a module with the ORIGEN-S module. Calculations are carried out for various U-Th, U-Pu-Th and U-Pu combinations. The results are preliminary in nature and the work is currently proceeding as planned. (author)

  9. Pebble bed reactor with a feeding device for absorber materials

    International Nuclear Information System (INIS)

    Description of a second shutdown device for pebble bed reactors with small absorber pebbles, which, if required, can be let off a storage tank and regularly trickle through a dispersion cone into the pebble bed. In the normal state the storage tank is in a low position with its outlet being obstructed by absorber pebbles filling a cylinder in which slides a piston which is firmly connected with the storage tank. By giving pressure over a line a piston in a pneumatic cylinder can be moved which lifts the storage tank. The cylinder is emptied by lifting the piston and the outlet is released. The level of the storage tank is measured by means of a probe. The whole device is installed in the prestressed concrets ceiling of the reactor. The device is proposed to be set into motion for a short moment from time to time in order to prove its operatability. (orig.)

  10. Cleaning of porous filters in fossilized bed reactors

    International Nuclear Information System (INIS)

    In this report are established the optimum working conditions of a filter cleaning system by blow back. For this purpose it was determined in the first place the blow back air rate necessary to have a good cleaning. The reasons for which it was not possible until now to control the pressure in a fluidized bed calcination reactor are analyzed and a criteria is established to calculate the optimum floe necessary to clean efficiently a porous by this procedures. (Author)

  11. Development of the Packed Bed Reactor ISS Flight Experiment

    Science.gov (United States)

    Patton, Martin O.; Bruzas, Anthony E.; Rame, Enrique; Motil, Brian J.

    2012-01-01

    Packed bed reactors are compact, require minimum power and maintenance to operate, and are highly reliable. These features make this technology a leading candidate as a potential unit operation in support of long duration human space exploration. On earth, this type of reactor accounts for approximately 80% of all the reactors used in the chemical process industry today. Development of this technology for space exploration is truly crosscutting with many other potential applications (e.g., in-situ chemical processing of planetary materials and transport of nutrients through soil). NASA is developing an ISS experiment to address this technology with particular focus on water reclamation and air revitalization. Earlier research and development efforts funded by NASA have resulted in two hydrodynamic models which require validation with appropriate instrumentation in an extended microgravity environment. The first model developed by Motil et al., (2003) is based on a modified Ergun equation. This model was demonstrated at moderate gas and liquid flow rates, but extension to the lower flow rates expected in many advanced life support systems must be validated. The other model, developed by Guo et al., (2004) is based on Darcy s (1856) law for two-phase flow. This model has been validated for a narrow range of flow parameters indirectly (without full instrumentation) and included test points where the flow was not fully developed. The flight experiment presented will be designed with removable test sections to test the hydrodynamic models. The experiment will provide flexibility to test additional beds with different types of packing in the future. One initial test bed is based on the VRA (Volatile Removal Assembly), a packed bed reactor currently on ISS whose behavior in micro-gravity is not fully understood. Improving the performance of this system through an accurate model will increase our ability to purify water in the space environment.

  12. Fluidization Characteristics of a Prototype Fluidized Bed Reactor

    Directory of Open Access Journals (Sweden)

    F. ABERUAGBA

    2005-01-01

    Full Text Available The fluidization characteristics of a prototype-fluidized bed laboratory reactor were understudied in order to investigate the suitable conditions at which the dehydrogenation reaction of butane could be carried out. To achieve this, a reactor with an effective volume of 1100ml was fabricated and coupled with temperature and pressure accessories.Zeolites were obtained from the market and clay obtained from different sources and pre-treated was used as catalyst. Airflow at high velocity between 3000-7000ml/hr was used as the fluidising medium to obtain the bed characteristics while butane gas was used to obtain the dehydrogenation kinetics.The temperature of the reactor system was varied between 353K and 413K while maintaining constant pressure of 1.5 105 N/m2 through a manifold gauge and a constant catalyst weight. Various methods such as pressure fluctuations, visual observations, and bed expansion were used to determine the transition velocity at which fluidization begins. It was observed that this depends on factors such as mean particle size, particle size distribution, and column diameter.The minimum fluidizing velocity obtained for zeolite was 0.0133m/s and 0.0102m/s for treated clay materials both for a particle size of 250μm. The conversion of butane over the catalysts showed an increase in both cases with a maximum at 0.9813 at 413K. This decreases as the reaction progresses.

  13. Neutronic features of pebble-bed reactors for transmutation applications

    International Nuclear Information System (INIS)

    Pebble-bed reactors offer very appealing characteristics for radioactivity confinement and for withstanding thermal transients. Besides that, pebble-bed reactors have a peculiar degree of freedom in the radius of the active core of the pebble (where the fuel is located) as compared to the outer radius of the pebble, which has a coating of pure graphite. By varying the aforementioned radius, very different types of neutron spectra can be formed, which in turn gives very different values of the average cross sections that govern the isotopic composition evolution, and particularly the elimination of the most relevant transuranics. Preliminary conclusions of this work show that there is a very broad design window for exploiting the transmutation capabilities of pebble-bed reactors in a scenario of inherent safety features. A 99,9% elimination of Pu-239 associated to a 99% elimination of Pu-240 and Pu-241 can be reached, with some increment of the Pu-242 contents (which is extremely long-lived, less radio-toxic and decays into the natural nuclide U-238). Am and Cm are also transmuted to a significant level, although some residual higher A actinides will remain. (authors)

  14. Gas Reactor International Cooperative Program: German Pebble Bed Reactor Technology review update

    International Nuclear Information System (INIS)

    This report provides a review of the German pebble bed reactor technology, and updates the information provided in the Gas Reactor International Cooperative Program Interim Report COO-4057-6, German Pebble Bed Reactor Design and Technology Review, dated September 1978. Most of the updated information is for the PNP-500 and the HHT-Prototype plants. The PNP-500 is a 500 MW(t) multi-purpose demonstration plant for coal conversion applications. The HHT-Prototype is a 1640 MWt reactor designed to produce 675 MWe of electricity using a direct cycle gas turbine. The report provides a description and evaluation of the overall plant and the nuclear reactor for both the PNP-500 and HHT-Prototype. A description and evaluation of the primary system components is presented for the process heat and gas turbine applications

  15. Performance analysis of 233U for fixed bed nuclear reactors

    International Nuclear Information System (INIS)

    Criticality and burn up behavior of the Fixed Bed Nuclear Reactor (FBNR) are investigated for the mixed fuel 233UO2/ThO2 as an alternative to low enriched 235UO2 fuel. CERMET fuel with a zirconium matrix and cladding has been used throughout the study. The main results of the study can be summarized as follows: Reactor criticality is already achieved by ∝2% 233UO2 with the mixed 233UO2/ThO2 fuel. At higher 233U fractions, reactor criticality rises rapidly and exceeds keff > 1.5 already by 9% 233UO2. With 100% 233UO2, start up criticality can reach keff = 2.0975. Time dependent reactor criticality keff and fuel burn up have been investigated for two different mixed fuel 233UO2/ThO2 compositions, namely: 4% 233UO2 + 96% ThO2 for a reactor power of 40 MWel (120 MWth) and 9% 233UO2 + 91% ThO2 for a reactor power of 70 MWel (210 MWth). Sufficient reactor criticality (keff > 1.06) for continuous operation without fuel change can be sustained during ∝ 5 and 12 years with 4% and 9% 233UO2 fractions in the mixed fuel, leading to burn ups of ∝ 36000 and > 105000 MWD/t, respectively. Thorium based fuel produces no prolific uranium. Plutonium production remains negligible. (orig.)

  16. Nuclear Safeguards Considerations For The Pebble Bed Modular Reactor (PBMR)

    Energy Technology Data Exchange (ETDEWEB)

    Phillip Casey Durst; David Beddingfield; Brian Boyer; Robert Bean; Michael Collins; Michael Ehinger; David Hanks; David L. Moses; Lee Refalo

    2009-10-01

    High temperature reactors (HTRs) have been considered since the 1940s, and have been constructed and demonstrated in the United Kingdom (Dragon), United States (Peach Bottom and Fort Saint Vrain), Japan (HTTR), Germany (AVR and THTR-300), and have been the subject of conceptual studies in Russia (VGM). The attraction to these reactors is that they can use a variety of reactor fuels, including abundant thorium, which upon reprocessing of the spent fuel can produce fissile U-233. Hence, they could extend the stocks of available uranium, provided the fuel is reprocessed. Another attractive attribute is that HTRs typically operate at a much higher temperature than conventional light water reactors (LWRs), because of the use of pyrolytic carbon and silicon carbide coated (TRISO) fuel particles embedded in ceramic graphite. Rather than simply discharge most of the unused heat from the working fluid in the power plant to the environment, engineers have been designing reactors for 40 years to recover this heat and make it available for district heating or chemical conversion plants. Demonstrating high-temperature nuclear energy conversion was the purpose behind Fort Saint Vrain in the United States, THTR-300 in Germany, HTTR in Japan, and HTR-10 and HTR-PM, being built in China. This resulted in nuclear reactors at least 30% or more thermodynamically efficient than conventional LWRs, especially if the waste heat can be effectively utilized in chemical processing plants. A modern variant of high temperature reactors is the Pebble Bed Modular Reactor (PBMR). Originally developed in the United States and Germany, it is now being redesigned and marketed by the Republic of South Africa and China. The team examined historical high temperature and high temperature gas reactors (HTR and HTGR) and reviewed safeguards considerations for this reactor. The following is a preliminary report on this topic prepared under the ASA-100 Advanced Safeguards Project in support of the NNSA Next

  17. Pellet bed reactor concepts for nuclear propulsion applications

    Energy Technology Data Exchange (ETDEWEB)

    El-Genk, M.S.; Morley, N.J.; Pelaccio, D.G.; Juhasz, A. [Univ of New Mexico, Albuquerque, NM (United States)

    1994-11-01

    Pellet bed reactor (PeBR) concepts have been developed for nuclear thermal and nuclear electric propulsion, and bimodal applications. This annular core, fast spectrum reactor offers many desirable design and safety features. These features include high-power density, small reactor size, full retention of fission products, passive decay heat removal, redundancy in reactor control, negative temperature reactivity feedback, ground testing of the fully assembled reactor using electric heating and nonnuclear fuel elements, and the option of fueling on the launch pad or fueling and refueling in orbit. In addition to these features, the concepts for nuclear electric propulsion and for bimodal power and thermal propulsion have no single point failure. The average power density in the reactor for nuclear thermal propulsion ranges from 2.2 to 3.3 MW/I and for a 15-MWe nuclear electric propulsion system the total power system specific mass is about 3.3 kg/kWe. The bimodal-PeBR system concepts offer specific impulse in excess of 650 s, tens of Newtons of thrust, and total system specific power ranging from 11 to 21.9 We/kg at the 10- and 40-kWe levels, respectively. 35 refs.

  18. Coating particles by chemical vapor deposition in fluidized bed reactors

    International Nuclear Information System (INIS)

    A technique to deposit a thin, adherent, uniformly dispersed coating onto the individual particles in a batch of granular or powdered material is described. We have been able to apply successfully a number of coatings to a variety of particulate materials using a fluidized-bed chemical vapor deposition (CVD) technique. By means of this technique we used tri-isobutylaluminum to apply adherent coatings of aluminum on powdered mica and powdered nickel. The powdered mica was also coated with titanium in a fluidized bed reactor in which titanium precursors were generated in situ by the reaction between HCl and metallic titanium. Post treatment of the titanium coated mica with ammonia produced agglomerates coated with TiN. These systems demonstrate the potential utility of the fluidized bed reactor for depositing a variety of coatings onto metallic and non-metallic dispersed materials. Preparation of such coated powders is likely to be valuable in a variety of industrial applications, such as the manufacture of composite structures. (orig.)

  19. Gas reactor international cooperative program interim report. Pebble bed reactor fuel cycle evaluation

    International Nuclear Information System (INIS)

    Nuclear fuel cycles were evaluated for the Pebble Bed Gas Cooled Reactor under development in the Federal Republic of Germany. The basic fuel cycle specified for the HTR-K and PNP is well qualified and will meet the requirements of these reactors. Twenty alternate fuel cycles are described, including high-conversion cycles, net-breeding cycles, and proliferation-resistant cycles. High-conversion cycles, which have a high probability of being successfully developed, promise a significant improvement in resource utilization. Proliferation-resistant cycles, also with a high probability of successful development, compare very favorably with those for other types of reactors. Most of the advanced cycles could be adapted to first-generation pebble bed reactors with no significant modifications

  20. Computational Fluid Dynamics Simulation of Fluidized Bed Polymerization Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Rong Fan

    2006-08-09

    Fluidized beds (FB) reactors are widely used in the polymerization industry due to their superior heat- and mass-transfer characteristics. Nevertheless, problems associated with local overheating of polymer particles and excessive agglomeration leading to FB reactors defluidization still persist and limit the range of operating temperatures that can be safely achieved in plant-scale reactors. Many people have been worked on the modeling of FB polymerization reactors, and quite a few models are available in the open literature, such as the well-mixed model developed by McAuley, Talbot, and Harris (1994), the constant bubble size model (Choi and Ray, 1985) and the heterogeneous three phase model (Fernandes and Lona, 2002). Most these research works focus on the kinetic aspects, but from industrial viewpoint, the behavior of FB reactors should be modeled by considering the particle and fluid dynamics in the reactor. Computational fluid dynamics (CFD) is a powerful tool for understanding the effect of fluid dynamics on chemical reactor performance. For single-phase flows, CFD models for turbulent reacting flows are now well understood and routinely applied to investigate complex flows with detailed chemistry. For multiphase flows, the state-of-the-art in CFD models is changing rapidly and it is now possible to predict reasonably well the flow characteristics of gas-solid FB reactors with mono-dispersed, non-cohesive solids. This thesis is organized into seven chapters. In Chapter 2, an overview of fluidized bed polymerization reactors is given, and a simplified two-site kinetic mechanism are discussed. Some basic theories used in our work are given in detail in Chapter 3. First, the governing equations and other constitutive equations for the multi-fluid model are summarized, and the kinetic theory for describing the solid stress tensor is discussed. The detailed derivation of DQMOM for the population balance equation is given as the second section. In this section

  1. TREATMENT OF POME BY PILOT PLANT ANAEROBIC FLUIDISED BED REACTOR

    Directory of Open Access Journals (Sweden)

    Abdullah Al-Mamun

    2010-09-01

    Full Text Available A pilot scale anaerobic fluidised bed reactor (AnFBR of 2000 L capacity was studied to determine its performance to treat palm oil mill effluent (POME. The pilot plant was operated at ambient temperature with diluted POME as substrate. It took 17 days for the start-up of the reactor with pre-seeded sand media. The AnFBR was capable to remove a large portion of organics at relatively shorter retention time. Maximum and minimum COD removal efficiency of 85% and 65% were attained at a loading rate of 4.0 and 13.8 kgCOD/m3.d. BOD and TSS removal rates varied within the range of 64% - 91% and 68% - 89%, respectively. The AnFBR exhibited low sludge production with lower sludge volume indices (SVI. Maximum and minimum effluent indices for the effluent were 35 mL/g and 11 mL/g, respectively. Low SVI values indicated that, anaerobic fluidised bed reactors generate less sludge with fast settling properties. Promising performance at ambient temperature and for detention time shorter than the present practices supported the possibility of AnFBR to treat POME to meet the new requirement set by the DOE Malaysia.

  2. Pellet bed reactor concept for nuclear electric propulsion

    International Nuclear Information System (INIS)

    For Nuclear Electric Propulsion (NEP) applications, gas cooled nuclear reactors with dynamic energy conversion systems offer high specific power and low total mass. This paper describes the Pellet Bed Reactor (PeBR) concept for potential NEP missions to Mars. The helium cooled, 75--80 MWt PeBR, consists of a single annular fuel region filled with a randomly packed bed of spherical fuel pellets, is designed for multiple starts, and offers unique safety and operation features. Each fuel pellet, about 8--10 mm in diameter, is composed of hundreds of TRISO type fuel microspheres embedded in a graphite matrix for a full retention of fission products. To eliminate the likelihood of a single-point failure, the annular core of the PeBR is divided into three 120 degree sectors. Each sector is self contained and separate and capable of operating and being cooled on its own and in cooperation with either one or two other sectors. Each sector is coupled to a separate, 5 MWe Closed Brayton Cycle (CBC) energy conversion unit and is subcritical for safe handling and launching. In the event of a failure of the cooling system of a core sector, the reactor power level may be reduced, allowing adjacent sectors to convect the heat away using their own cooling system, thus maintaining reactor operation. Also, due to the absence of an internal core structure in the PeBR core, fueling of the reactor can easily be performed either at the launch facility or in orbit, and refueling can be accomplished in orbit as needed to extend the power system lifetime

  3. Modularity of the MIT Pebble Bed Reactor for use by the commercial power industry

    OpenAIRE

    Hanlon-Hyssong, Jaime E.

    2008-01-01

    CIVINS The Modular Pebble Bed Reactor is a small high temperature helium cooled reactor that is being considered for both electric power and hydrogen production. Pebble bed reactors are being developed in South Africa, China and the US. To make smaller 120 Mwe reactors economically competitive with larger 1500 Mwe traditional light water reactors changes in the way these plants are built are needed. Economies of production need to be sufficiently large to compete with economies of sca...

  4. BIODEGRADATION OF AROMATIC AMINE COMPOUNDS USING MOVING BED BIOFILM REACTORS

    Directory of Open Access Journals (Sweden)

    M. Delnavaz ، B. Ayati ، H. Ganjidoust

    2008-10-01

    Full Text Available Three moving bed biofilm reactors were used to treat synthesized wastewater of aromatic amine compounds including aniline, para-diaminobenzene and para-aminophenol that are found in many industrial wastewaters. The reactors with cylindrical shape had an internal diameter and an effective depth of 10 and 60 cm, respectively. The reactors were filled with light expanded clay aggregate as carriers and operated in an aerobic batch and continuous conditions. Evaluation of the reactors' efficiency was done at different retention time of 8, 24, 48 and 72 h with an influent COD from 100 to 3500 mg/L (filling ratio of 50%. The maximum obtained removal efficiencies were 90% (influent COD=2000 mg/L, 87% (influent COD=1000 mg/L and 75% (influent COD=750 mg/L for aniline, para-diaminobenzene and para-aminophenol, respectively. In the study of decrease in filling ratio from 50 to 30 percent, 6% decrease for both para-diaminobenzene and para-aminophenol and 7% increase for aniline degradation were obtained. The removal efficiency was decreased to about 10% after 15 days of continuous loading for each of the above three substrates. In the shock loading test, initially the COD removal rate was decreased in all reactors, but after about 10 days, it has been approached to the previous values. Finally, biodegradability of aromatic amines has been proved by nuclear magnetic resonance system.

  5. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids

    Directory of Open Access Journals (Sweden)

    Ajay Bansal

    2010-10-01

    Full Text Available Hydrodynamic studies of trickle bed reactors (TBRs are essential for the design and prediction of their performance. The hydrodynamic characteristics involving pressure drop and dynamic liquid saturation are greatly affected by the physical properties of the liquids. In the present study experiments have been carried out in a concurrent downflow air - liquid trickle bed reactor to investigate the dynamic liquid saturation and pressure drop for the water (non-foaming and 3% polyethylene glycol and 4% polyethylene glycol foaming liquids in the gas continuous regime (GCF and foaming pulsing regime (FP. In the GCF regime the dynamic liquid saturation was found to increase with increase in liquid flow rate for non-foaming and foaming liquids. While for 3% and 4% polyethylene glycol solutions the severe foaming was observed in the high interaction regime and the regime is referred to as foaming pulsing (FP regime. The decrease in dynamic liquid saturation followed by a sharp rise in the pressure drop was observed during transition from gas GCF to FP regime. However in the FP regime, a dip in the dynamic liquid saturation was observed. The pressure drop for foaming liquids is observed to be manifolds higher compared to non-foaming liquid in the GCF regime. ©2010 BCREC UNDIP. All rights reserved(Received: 16th January 2010, Revised: 10th February 2010, Accepted: 21st Feberuary 2010[How to Cite: R. Gupta, A. Bansal. (2010. Hydrodynamic Studies on a Trickle Bed Reactor for Foaming Liquids. Bulletin of Chemical Reaction Engineering & Catalysis, 5 (1: 31-37. doi:10.9767/bcrec.5.1.775.31-37][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.5.1.775.31-37 ][Cited by: Scopus 1 |

  6. Experimental and theoretical investigation of anaerobic fluidized bed biofilm reactors

    Directory of Open Access Journals (Sweden)

    M. Fuentes

    2009-09-01

    Full Text Available This work presents an experimental and theoretical investigation of anaerobic fluidized bed reactors (AFBRs. The bioreactors are modeled as dynamic three-phase systems. Biochemical transformations are assumed to occur only in the fluidized bed zone. The biofilm process model is coupled to the system hydrodynamic model through the biofilm detachment rate; which is assumed to be a first-order function of the energy dissipation parameter and a second order function of biofilm thickness. Non-active biomass is considered to be particulate material subject to hydrolysis. The model includes the anaerobic conversion for complex substrate degradation and kinetic parameters selected from the literature. The experimental set-up consisted of two mesophilic (36±1ºC lab-scale AFBRs (R1 and R2 loaded with sand as inert support for biofilm development. The reactor start-up policy was based on gradual increments in the organic loading rate (OLR, over a four month period. Step-type disturbances were applied on the inlet (glucose and acetic acid substrate concentration (chemical oxygen demand (COD from 0.85 to 2.66 g L-1 and on the feed flow rate (from 3.2 up to 6.0 L d-1 considering the maximum efficiency as the reactor loading rate switching. The predicted and measured responses of the total and soluble COD, volatile fatty acid (VFA concentrations, biogas production rate and pH were investigated. Regarding hydrodynamic and fluidization aspects, variations of the bed expansion due to disturbances in the inlet flow rate and the biofilm growth were measured. As rate coefficients for the biofilm detachment model, empirical values of 3.73⋅10(4 and 0.75⋅10(4 s² kg-1 m-1 for R1 and R2, respectively, were estimated.

  7. Characterization of Biofilm in 200W Fluidized Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Michelle H.; Saurey, Sabrina D.; Lee, Brady D.; Parker, Kent E.; Eisenhauer, Emalee ER; Cordova, Elsa A.; Golovich, Elizabeth C.

    2014-09-29

    Contaminated groundwater beneath the 200 West Area at the Hanford Site in Southeast Washington is currently being treated using a pump and treat system to remove organics, inorganics, radionuclides, and metals. A granular activated carbon-based fluidized bed reactor (FBR) has been added to remove nitrate, hexavalent chromium and carbon tetrachloride. Initial analytical results indicated the microorganisms effectively reduced many of the contaminants to less than cleanup levels. However shortly thereafter operational upsets of the FBR include carbon carry over, over production of microbial extracellular polymeric substance (biofilm) materials, and over production of hydrogen sulfide. As a result detailed investigations were undertaken to understand the functional diversity and activity of the microbial community present in the FBR over time. Molecular analyses including terminal restriction fragment length polymorphism analysis, quantitative polymerase chain reaction and fluorescent in situ hybridization analyses were performed on the microbial community extracted from the biofilm within the bed and from the inoculum, to determine functional dynamics of the FBR bed over time and following operational changes. Findings from these analyses indicated: 1) the microbial community within the bed was completely different than community used for inoculation, and was likely from the groundwater; 2) analyses early in the testing showed an FBR community dominated by a few Curvibacter and Flavobacterium species; 3) the final sample taken indicated that the microbial community in the FBR bed had become more diverse; and 4) qPCR analyses indicated that bacteria involved in nitrogen cycling, including denitrifiers and anaerobic ammonia oxidizing bacteria, were dominant in the bed. These results indicate that molecular tools can be powerful for determining functional diversity within FBR type reactors. Coupled with micronutrient, influent and effluent chemistry evaluations, a more

  8. PEBBED ANALYSIS OF HOT SPOTS IN PEBBLE-BED REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Abderrafi M. Ougouag; Hans D. Gougar; William K. Terry; Frederik Reitsma; Wessel Joubert

    2005-09-01

    The Idaho National Laboratory’s PEBBED code and simple probability considerations are used to estimate the likelihood and consequences of the accumulation of highly reactive pebbles in the region of peak power in a pebble-bed reactor. The PEBBED code is briefly described, and the logic of the probability calculations is presented in detail. The results of the calculations appear to show that hot-spot formation produces only moderate increases in peak accident temperatures, and no increases at all in normal operating temperatures.

  9. Glucose isomerization in simulated moving bed reactor by Glucose isomerase

    Directory of Open Access Journals (Sweden)

    Eduardo Alberto Borges da Silva

    2006-05-01

    Full Text Available Studies were carried out on the production of high-fructose syrup by Simulated Moving Bed (SMB technology. A mathematical model and numerical methodology were used to predict the behavior and performance of the simulated moving bed reactors and to verify some important aspects for application of this technology in the isomerization process. The developed algorithm used the strategy that considered equivalences between simulated moving bed reactors and true moving bed reactors. The kinetic parameters of the enzymatic reaction were obtained experimentally using discontinuous reactors by the Lineweaver-Burk technique. Mass transfer effects in the reaction conversion using the immobilized enzyme glucose isomerase were investigated. In the SMB reactive system, the operational variable flow rate of feed stream was evaluated to determine its influence on system performance. Results showed that there were some flow rate values at which greater purities could be obtained.Neste trabalho a tecnologia de Leito Móvel Simulado (LMS reativo é aplicada no processo de isomerização da glicose visando à produção de xarope concentrado de frutose. É apresentada a modelagem matemática e uma metodologia numérica para predizer o comportamento e o desempenho de unidades reativas de leito móvel simulado para verificar alguns aspectos importantes para o emprego desta tecnologia no processo de isomerização. O algoritmo desenvolvido utiliza a abordagem que considera as equivalências entre as unidades reativas de leito móvel simulado e leito móvel verdadeiro. Parâmetros cinéticos da reação enzimática são obtidos experimentalmente usando reatores em batelada pela técnica Lineweaver-Burk. Efeitos da transferência de massa na conversão de reação usando a enzima imobilizada glicose isomerase são verificados. No sistema reativo de LMS, a variável operacional vazão da corrente de alimentação é avaliada para conhecer o efeito de sua influência no

  10. Computational prediction of dust production in pebble bed reactors

    International Nuclear Information System (INIS)

    Highlights: ► Finite element analysis of frictional contact. ► Plasticity taken into account for nuclear graphite at room temperature. ► Prediction of order of magnitude for dust loading in PBRs. ► Archard wear model for wear mass calculations. - Abstract: This paper describes the computational modeling and simulation of graphite pebbles in frictional contacts as anticipated in a pebble bed reactor. For the high temperature gas-cooled reactor, the potential dust generation from frictional contact at the surface of pebbles and the subsequent lift-off and transport of dust and absorbed fission products are of safety concern at elevated temperatures under an air ingress accident. The aim of this work is to perform a computational study to estimate the quantity of the nuclear grade graphite dust produces from a typical anticipated configuration.

  11. Fast Pyrolysis of Agricultural Wastes in a Fluidized Bed Reactor

    Science.gov (United States)

    Wang, X. H.; Chen, H. P.; Yang, H. P.; Dai, X. M.; Zhang, S. H.

    Solid biomass can be converted into liquid fuel through fast pyrolysis, which is convenient to be stored and transported with potential to be used as a fossil oil substitute. In China, agricultural wastes are the main biomass materials, whose pyrolysis process has not been researched adequately compared to forestry wastes. As the representative agricultural wastes in China, peanut shell and maize stalk were involved in this paper and pine wood sawdust was considered for comparing the different pyrolysis behaviors of agricultural wastes and forestry wastes. Fast pyrolysis experiments were carried out in a bench-scale fluidized-bed reactor. The bio-oil yieldsof peanut shell and maize stalk were obviously lower than that ofpine sawdust. Compared with pine sawdust, the char yields of peanut shell and maize stalk were higher but the heating value of uncondensable gaswas lower. This means that the bio-oil cost will be higher for agricultural wastes if taking the conventional pyrolysis technique. And the characteristic and component analysis resultsof bio-oil revealed that the quality of bio-oil from agricultural wastes, especially maize stalk, was worse than that from pine wood. Therefore, it is important to take some methods to improve the quality of bio-oilfrom agricultural wastes, which should promote the exploitation of Chinese biomass resources through fast pyrolysis in afluidized bed reactor.

  12. Studies on air ingress for pebble bed reactors

    International Nuclear Information System (INIS)

    A loss-of-coolant accident (LOCA) has been considered a critical event for helium-cooled pebbled bed reactors. Following helium depressurization, it is anticipated that unless countermeasures are taken air will enter the core through the break and then by molecular diffusion and ultimately by natural convection leading to oxidation of the in-core graphite structure and graphite pebbles. Thus, without any mitigating features a LOCA will lead to an air ingress event. The INEEL is studying such an event with two well-respected light water reactor transient response codes: RELAP5/ATHENA and MELCOR. To study the degree of graphite oxidation occurring due to an air ingress event, a MELCOR model of a reference pebble bed design was constructed. A modified version of MELCOR developed at INEEL, which includes graphite oxidation capabilities, and molecular diffusion of air into helium was used for these calculations. Results show that the lower reflector graphite consumes all of the oxygen before reaching the core. The results also show a long time delay between the time that the depressurization phase of the accident is over and the time that natural circulation air through the core occurs. (author)

  13. Improving hydrolysis of food waste in a leach bed reactor

    International Nuclear Information System (INIS)

    Highlights: • This paper assesses leaching of food waste in a two phase digestion system. • Leaching is assessed with and without an upflow anaerobic sludge blanket (UASB). • Without the UASB, low pH reduces hydrolysis, while increased flows increase leaching. • Inclusion of the UASB increases pH to optimal levels and greatly improves leaching. • The optimal conditions are suggested as low flow with connection to the UASB. - Abstract: This paper examines the rate of degradation of food waste in a leach bed reactor (LBR) under four different operating conditions. The effects of leachate recirculation at a low and high flow rate are examined with and without connection to an upflow anaerobic sludge blanket (UASB). Two dilution rates of the effective volume of the leach bed reactors were investigated: 1 and 6 dilutions per LBR per day. The increase in dilution rate from 1 to 6 improved the destruction of volatile solids without connection to the UASB. However connection to the UASB greatly improved the destruction of volatile solids (by almost 60%) at the low recirculation rate of 1 dilution per day. The increase in volatile solids destruction with connection to the UASB was attributed to an increase in leachate pH and buffering capacity provided by recirculated effluent from the UASB to the leach beds. The destruction of volatile solids for both the low and high dilution rates was similar with connection to the UASB, giving 82% and 88% volatile solids destruction respectively. This suggests that the most efficient leaching condition is 1 dilution per day with connection to the UASB

  14. Semi-dry flue gas desulfurization using Ca(OH)2 in a fluidized bed reactor with bed materials

    International Nuclear Information System (INIS)

    The main objective of present work is to reduce sulfur dioxide emission from power plant for the environment protection. The fluidized bed (FB) was used as the reactor with bed materials in a new semi-dry flue gas desulfurization (FGD) process to achieve high desulfurization efficiency (>98%). Fine powder of Ca(OH)2 as sorbent and water were continuously fed separately to the bed reactor where bed materials (2 mm glass beads) were fluidized vigorously with flue gas (flow 720 Nm3/ hr) using bench scale plant of stainless steel column. We have investigated different effects of water injection flow rate, Ca/ S molar ratio and weight of bed materials on SO2 removal. The increments in the Ca/ S molar ratio and water injection flow rate have been resulted higher desulfurization efficiency with certain disadvantages such as higher sorbent cost and lower temperature of the treated flue gas, respectively. (author)

  15. Gas Reactor International Cooperative Program. Interim report. Safety and licensing evaluaion of German Pebble Bed Reactor concepts

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The Pebble Bed Gas Cooled Reactor, as developed in the Federal Republic of Germany, was reviewed from a United States Safety and Licensing perspective. The primary concepts considered were the steam cycle electric generating pebble bed (HTR-K) and the process heat pebble bed (PNP), although generic consideration of the direct cycle gas turbine pebble bed (HHT) was included. The study examines potential U.S. licensing issues and offers some suggestions as to required development areas.

  16. Effects of Spatial Variations in Packing Fraction on Reactor Physics Parameters in Pebble-Bed Reactors

    International Nuclear Information System (INIS)

    The well-known spatial variation of packing fraction near the outer boundary of a pebble-bed reactor core is cited. The ramifications of this variation are explored with the MCNP computer code. It is found that the variation has negligible effects on the global reactor physics parameters extracted from the MCNP calculations for use in analysis by diffusion-theory codes, but for local reaction rates the effects of the variation are naturally important. Included is some preliminary work in using first-order perturbation theory for estimating the effect of the spatial variation of packing fraction on the core eigenvalue and the fision density distribution

  17. Effects of Spatial Variations in Packing Fraction of Reactor Physics Parameters in Pebble-Bed Reactors

    International Nuclear Information System (INIS)

    The well-known spatial variation of packing fraction near the outer boundary of a pebble-bed reactor core is cited. The ramifications of this variation are explored with the MCNP computer code. It is found that the variation has negligible effects on the global reactor physics parameters extracted from the MCNP calculations for use in analysis by diffusion-theory codes, but for local reaction rates the effects of the variation are naturally important. Included is some preliminary work in using first-order perturbation theory for estimating the effect of the spatial variation of packing fraction on the core eigenvalue and the fission density distribution

  18. Effects of Spatial Variations in Packing Fraction on Reactor Physics Parameters in Pebble-Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    William K. Terry; A. M. Ougouag; Farzad Rahnema; Michael Scott McKinley

    2003-04-01

    The well-known spatial variation of packing fraction near the outer boundary of a pebble-bed reactor core is cited. The ramifications of this variation are explored with the MCNP computer code. It is found that the variation has negligible effects on the global reactor physics parameters extracted from the MCNP calculations for use in analysis by diffusion-theory codes, but for local reaction rates the effects of the variation are naturally important. Included is some preliminary work in using first-order perturbation theory for estimating the effect of the spatial variation of packing fraction on the core eigenvalue and the fision density distribution.

  19. Catalytic Pyrolysis of Oak via Pyroprobe and Bench Scale, Packed Bed Pyrolysis Reactors

    Science.gov (United States)

    The pyrolytic conversion of oak sawdust at 500°C in flowing He over eight proprietary catalysts is described and compared to the control bed material, quartz sand. The reactions were conducted and compared in two reactors, an analytical, ug-scale pyroprobe reactor and a bench, g-scale packed bed re...

  20. Celebrating 40 years anaerobic sludge bed reactors for industrial wastewater treatment

    NARCIS (Netherlands)

    Van Lier, J.B.; Van der Zee, F.P.; Frijters, C.T.M.J.; Ersahin, M.E.

    2015-01-01

    In the last 40 years, anaerobic sludge bed reactor technology evolved from localized lab-scale trials to worldwide successful implementations at a variety of industries. High-rate sludge bed reactors are characterized by a very small foot print and high applicable volumetric loading rates. Best perf

  1. Pebble bed reactor with one-zone core

    International Nuclear Information System (INIS)

    The claim deals with measures to differentiate the flow rate and to remove spherical fuel elements in the core of a pebble bed reactor. Hence the vertical rate of the fuel elements in the border region is for example twice as much as in the centre. A central funnel-shaped outlet on the floor of the core container over which a conical body is placed with its peak pointing upwards, or also the forming of several outlets can be used to adjust to a certain exit rate for the fuel elements. The main target of the invention is a radially extensively constant coolant outlet temperature at the outlet of the core which determines the effectiveness of the connected heat exchanger and thus contributes to economy. (orig./PW)

  2. Thermofluid effect on energy storage in fluidized bed reactor

    Science.gov (United States)

    Mahfoudi, Nadjiba; El Ganaoui, Mohammed; Moummi, Abdelhafid

    2016-05-01

    The development of innovative systems of heat storage is imperative to improve the efficiency of the existing systems used in the thermal solar energy applications. Several techniques were developed and realized in this context. The technology of the sand fluidized bed (sandTES) offers a promising alternative to the current state-of-the-art of the heat storage systems, such as fixed bed using a storage materials, as sand, ceramic, and stones, etc. Indeed, the use of the fluidization technique allows an effective heat transfer to the solid particles. With the sand, an important capacity of storage is obtained by an economic and ecological material [N. Mahfoudi, A. Moummi, M. El Ganaoui, Appl. Mech. Mater. 621, 214 (2014); N. Mahfoudi, A. Khachkouch, A. Moummi B. Benhaoua, M. El Ganaoui, Mech. Ind. 16, 411 (2015); N. Mahfoudi, A. Moummi, M. El Ganaoui, F. Mnasri, K.M. Aboudou, 3e Colloque internationale Francophone d"énergétique et mécanique, Comores, 2014, p. 91]. This paper presents a CFD simulation of the hydrodynamics and the thermal transient behavior of a fluidized bed reactor of sand, to determine the characteristics of storage. The simulation shows a symmetry breaking that occurs and gave way to chaotic transient generation of bubble formation after 3 s. Furthermore, the predicted average temperature of the solid phase (sand) increases gradually versus the time with a gain of 1 °C in an interval of 10 s. Contribution to the topical issue "Materials for Energy Harvesting, Conversion and Storage (ICOME 2015) - Elected submissions", edited by Jean-Michel Nunzi, Rachid Bennacer and Mohammed El Ganaoui

  3. Continuous thermophilic biohydrogen production in packed bed reactor

    International Nuclear Information System (INIS)

    Highlights: • Continuous H2 production in whole cell immobilized system was compared with CSTR. • Suitability of environment friendly support matrix for immobilization of whole cells was explored. • Pack bed reactor showed higher stability as compared to CSTR at lower HRTs. • Flow cytometry study showed the influence of recycle ratio on viability of cells. • Novel approach to find out the effect of NADH/NAD+ ratio during H2 production. - Abstract: The present research work deals with the performance of packed bed reactor for continuous H2 production using cane molasses as a carbon source. Maximum H2 production rate of 1.7 L L−1 h−1 was observed at a dilution rate and recycle ratio of 0.8 h−1 and 0.6, respectively which was corresponding to the lowest NADH/NAD+ ratio. This suggests that the utilization of NADH pool for H2 and metabolite production might lead to decrement in NADH/NAD+ ratio. Thus NADH/NAD+ ratio show inverse relation with hydrogen production. The substrate degradation kinetics was investigated as a function of flow rate considering the external film diffusion model. At a flow rate of 245 mL h−1, the contribution of external film mass transfer coefficient and first order substrate degradation constant were 55.4% and 44.6% respectively. Recycle ratio of 0.6 improved the hydrogen production rates by 9%. The viable cell count was directly proportional to the recycle ratio (within the range 0.1–0.6). Taguchi design showed the significant influence of the feed pH on continuous H2 production followed by dilution rate and recycle ratio. Thus environmentally friendly and cheaper solid matrix like coconut coir could be efficiently used for thermophilic continuous hydrogen production

  4. Transmutation of plutonium in pebble bed type high temperature reactors

    International Nuclear Information System (INIS)

    The pebble bed type High Temperature Reactor (HTR) has been studied as a uranium-free burner of reactor grade plutonium. In a parametric study, the plutonium loading per pebble as well as the type and size of the coated particles (CPs) have been varied to determine the plutonium consumption, the final plutonium burnup, the k∞ and the temperature coefficients as a function of burnup. The plutonium loading per pebble is bounded between 1 and 3 gr Pu per pebble. The upper limit is imposed by the maximal allowable fast fluence for the CPs. A higher plutonium loading requires a longer irradiation time to reach a desired burnup, so that the CPs are exposed to a higher fast fluence. The lower limit is determined by the temperature coefficients, which become less negative with increasing moderator-actinide ratio. A burnup of about 600 MWd/kgHM can be reached. With the HTR's high efficiency of 40%, a plutonium supply of 1520 kg/GWea is achieved. The discharges of plutonium and minor actinides are then 450 and 110 kg/GWea, respectively. (author)

  5. Moving bed biofilm reactor technology: process applications, design, and performance.

    Science.gov (United States)

    McQuarrie, James P; Boltz, Joshua P

    2011-06-01

    The moving bed biofilm reactor (MBBR) can operate as a 2- (anoxic) or 3-(aerobic) phase system with buoyant free-moving plastic biofilm carriers. These systems can be used for municipal and industrial wastewater treatment, aquaculture, potable water denitrification, and, in roughing, secondary, tertiary, and sidestream applications. The system includes a submerged biofilm reactor and liquid-solids separation unit. The MBBR process benefits include the following: (1) capacity to meet treatment objectives similar to activated sludge systems with respect to carbon-oxidation and nitrogen removal, but requires a smaller tank volume than a clarifier-coupled activated sludge system; (2) biomass retention is clarifier-independent and solids loading to the liquid-solids separation unit is reduced significantly when compared with activated sludge systems; (3) the MBBR is a continuous-flow process that does not require a special operational cycle for biofilm thickness, L(F), control (e.g., biologically active filter backwashing); and (4) liquid-solids separation can be achieved with a variety of processes, including conventional and compact high-rate processes. Information related to system design is fragmented and poorly documented. This paper seeks to address this issue by summarizing state-of-the art MBBR design procedures and providing the reader with an overview of some commercially available systems and their components. PMID:21751715

  6. Solid particle mixing in a continuously operated fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wittmann, K.; Wippern, D.; Schlingmann, H.; Helmrich, H.; Schuegerl, K.

    1983-01-01

    In a bench-scale fluidized bed reactor, 20 cm in dia., residence time distribution of solid particles (d/sub p/ = 137 ..mu..m) were measured by the radionuclide technique sodium carbonate (/sup 24/Na/sub 2/CO/sub 3/) in the absence and in the presence of the chemical reaction sodium bicarbonate (2NaHCO/sub 3/) ..-->.. Na/sub 2/CO/sub 3/ + CO/sub 2/ + H/sub 2/O. The residence time distributions were evaluated by a backflow cascade model by nonlinear optimization. The radial and longitudinal concentration profiles of NaHCO/sub 3/ in the emulsion phase of the reactor were measured during steady-state operation. The solid is well-mixed. The connection of the measured bubble properties with the longitudinal solid dispersion coefficient and the use of the Haines-King-Woodburn model allows one to calculate the solid dispersion coefficient in the bubble-free emulsion phase. 6 figures, 5 tables.

  7. Neutronic modeling of pebble bed reactors in APOLLO2

    International Nuclear Information System (INIS)

    In this thesis we develop a new iterative homogenization technique for pebble bed reactors, based on a 'macro-stochastic' transport approximation in the collision probability method. A model has been developed to deal with the stochastic distribution of pebbles with different burnup in the core, considering spectral differences in homogenization and depletion calculations. This is generally not done in the codes presently used for pebble bed analyses, where a pebble with average isotopic composition is considered to perform the cell calculation. Also an iterative core calculation scheme has been set up, where the low-order RZ SN full-core calculation computes the entering currents in the spectrum zones subdividing the core. These currents, together with the core keff, are then used as surface source in the fine-group heterogeneous calculation of the multi-pebble geometries. The developed method has been verified using reference Monte Carlo simulations of a simplified PBMR- 400 model. The pebbles in this model are individually positioned and have different randomly assigned burnup values. The APOLLO2 developed method matches the reference core keff within ± 100 pcm, with relative differences on the production shape factors within ± 4%, and maximum discrepancy of 3% at the hotspot. Moreover, the first criticality experiment of the HTR-10 reactor was used to perform a first validation of the developed model. The computed critical number of pebbles to be loaded in the core is very close to the experimental value of 16890, only 77 pebbles less. A method to calculate the equilibrium reactor state was also developed and applied to analyze the simplified PBMR-400 model loaded with different fuel types (UO2, Pu, Pu + MA). The potential of the APOLLO2 method to compute different fluxes for the different pebble types of a multi-pebble geometry was used to evaluate the bias committed by the average composition pebble approximation. Thanks to a 'compensation of error', this

  8. The fluidized bed reactor with a prepolymerization system and its influence on polymer physicochemical characteristics

    OpenAIRE

    F. A. N. Fernandes; L. M. F. Lona

    2003-01-01

    This work addresses the influence of a prepolymerization system on the behavior of the fluidized bed reactor used for polyethylene production. Its influence on the polymer's physicochemical characteristics and production was also studied. The results indicate that the use of prepolymerized catalyst particles results in milder temperatures in the fluidized bed reactor, thus avoiding the formation of hot spots, melting of the polymer particle and reactor shutdown. Productivity can be enhanced d...

  9. Pebble Bed Reactor Plant screening evaluation. Volume 1. Overall plant and reactor system

    International Nuclear Information System (INIS)

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW/sub t/ Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. Volume 1 reports the overall plant and reactor system. Core scoping studies were performed which evaluated the effects of annular and cyclindrical core configurations, radial blanket zones, burnup, and ball heavy metal loadings. The reactor system, including the PCRV, was investigated for both the annular and cylindrical core configurations

  10. Steady-state thermal-hydraulic of pebble bed blanket on hybrid reactor

    International Nuclear Information System (INIS)

    This paper gives thermal-hydraulic studies of pebble bed blanket on Hybrid Reactor. The concept of whole pebble bed blanket and the cooling methods are presented. The thermal-hydraulic characteristics of pebble bed are summarized. The theoretical model and code for solving heat transfer and flowing are presented. By using this code the calculation and analysis of thermal hydraulic of pebble bed Blanket of Hybrid Reactor are also given. In order to improve the flexibility, safety and economy, the authors select pebble beds not only to breed Tritium, but also to breed fission material and to multiply neutron. 5 MPa Helium is used as coolant and 0.05 MPa-0.1 MPa Helium is used as Purge gas. The heat transfer mechanisms of pebble bed are very complicated which include conduction, convection and radiation. In order to study the thermal-hydraulic of the bed, the authors just simply consider it as homogeneous and continuous binary phase medium as that used in the porous medium at the condition that the size of the bed is much greater than that of the balls. The coolant or the purge gas flowing through the bed is just considered existing a cooling source in the bed. It also significantly influences the effective conductivity's of the bed. Porous fraction, the main factor of the bed depends on the geometry position and parameters. From this model, one can obtain the thermal-hydraulic governing equations of the bed

  11. Sorption-enhanced steam methane reforming in fluidized bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Johnsen, Kim

    2006-10-15

    Hydrogen is considered to be an important potential energy carrier; however, its advantages are unlikely to be realized unless efficient means can be found to produce it without generation of CO{sub 2}. Sorption-enhanced steam methane reforming (SE-SMR) represent a novel, energy-efficient hydrogen production route with in situ CO{sub 2} capture, shifting the reforming and water gas shift reactions beyond their conventional thermodynamic limits. The use of fluidized bed reactors for SE-SMR has been investigated. Arctic dolomite, a calcium-based natural sorbent, was chosen as the primary CO{sub 2}-acceptor in this study due to high absorption capacity, relatively high reaction rate and low cost. An experimental investigation was conducted in a bubbling fluidized bed reactor of diameter 0.1 m, which was operated cyclically and batch wise, alternating between reforming/carbonation conditions and higher-temperature calcination conditions. Hydrogen concentrations of >98 mole% on a dry basis were reached at 600 C and 1 atm, for superficial gas velocities in the range of {approx}0.03-0.1 m/s. Multiple reforming-regeneration cycles showed that the hydrogen concentration remained at {approx}98 mole% after four cycles. The total production time was reduced with an increasing number of cycles due to loss of CO{sub 2}-uptake capacity of the dolomite, but the reaction rates of steam reforming and carbonation seemed to be unaffected for the conditions investigated. A modified shrinking core model was applied for deriving carbonation kinetics of Arctic dolomite, using experimental data from a novel thermo gravimetric reactor. An apparent activation energy of 32.6 kj/mole was found from parameter fitting, which is in good agreement with previous reported results. The derived rate expression was able to predict experimental conversion up to {approx}30% very well, whereas the prediction of higher conversion levels was poorer. However, the residence time of sorbent in a continuous

  12. Stable hydrogen production by methane steam reforming in a two zone fluidized bed reactor: Experimental assessment

    Science.gov (United States)

    Pérez-Moreno, L.; Soler, J.; Herguido, J.; Menéndez, M.

    2013-12-01

    The Two Zone Fluidized Bed Reactor concept is proposed for hydrogen production via the steam reforming of methane (SRM) including integrated catalyst regeneration. In order to study the effect of the contact mode, the oxidative SRM has been carried out over a Ni/Al2O3 catalyst using a fixed bed reactor (fBR), a conventional fluidized-bed reactor (FBR) and the proposed two-zone fluidized bed reactor (TZFBR). The technical feasibility of these reactors has been studied experimentally, investigating their performance (CH4 conversion, CO and H2 selectivity, and H2 global yield) and stability under different operating conditions. Coke generation in the process has been verified by several techniques. A stable performance was obtained in the TZFBR, where coke formation was counteracted with continuous catalyst regeneration. The viability of the TZFBR for carrying out this process with a valuable global yield to hydrogen is demonstrated.

  13. Nitrification of industrial and domestic saline wastewaters in moving bed biofilm reactor and sequencing batch reactor

    International Nuclear Information System (INIS)

    Nitrification of saline wastewaters was investigated in bench-scale moving-bed biofilm reactors (MBBR). Wastewater from a chemical industry and domestic sewage, both treated by the activated sludge process, were fed to moving-bed reactors. The industrial wastewater contained 8000 mg Cl-/L and the salinity of the treated sewage was gradually increased until that level. Residual substances present in the treated industrial wastewater had a strong inhibitory effect on the nitrification process. Assays to determine inhibitory effects were performed with the industrial wastewater, which was submitted to ozonation and carbon adsorption pretreatments. The latter treatment was effective for dissolved organic carbon (DOC) removal and improved nitrification efficiency. Nitrification percentage of the treated domestic sewage was higher than 90% for all tested chloride concentrations up to 8000 mg/L. Results obtained in a sequencing batch reactor (SBR) were consistent with those attained in the MBBR systems, allowing tertiary nitrification and providing adequate conditions for adaptation of nitrifying microorganisms even under stressing and inhibitory conditions.

  14. Pebble bed modular reactor - The first Generation IV reactor to be constructed

    Energy Technology Data Exchange (ETDEWEB)

    Ion, S. [British Nuclear Fuels plc, Warrington (United Kingdom); Nicholls, D. [ESKOM, Sandton, Johannesburg (South Africa); Matzie, R. [Westinghouse Electric Company, Windsor, CT (United States); Matzner, D. [Pebble Bed Modular Reactor (Pty) Ltd, Centurion (South Africa)

    2004-02-01

    Substantial interest has been generated in advanced reactors over the past few years. This interest is motivated by the view that new nuclear power reactors will be needed to provide low carbon generation of electricity and possibly hydrogen to support the future growth in demand for both of these commodities. Some governments feel that substantially different designs will be needed to satisfy the desires for public perception, improved safety, proliferation resistance, reduced waste and competitive economics. This has motivated the creation of the Generation IV Nuclear Energy Systems programme in which ten countries have agreed on a framework for international cooperation in research for advanced reactors. Six designs have been selected for continued evaluation, with the objective of deployment by 2030. One of these designs is the very high temperature reactor (VHTR), which is a thermal neutron spectrum system with a helium-cooled core utilising carbon-based fuel. The pebble bed modular reactor (PBMR), being developed in South Africa through a worldwide international collaborative effort led by Eskom, the national utility, will represent a key milestone on the way to achievement of the VHTR design objectives, but in the much nearer term. This paper outlines the design objectives, safety approach and design details of the PBMR, which is already at a very advanced stage of development. (author)

  15. Thermal-hydraulic transient analysis of a packed particle bed reactor fuel element

    OpenAIRE

    Casey, William Emerson

    1990-01-01

    Title as it appears in the M.I.T. Graduate List, Jun. 4, 1990: Transient thermal-hydraulic analysis of a packed particle bed reactor fuel element A model which describes the thermal-hydraulic behavior of a packed particle bed reactor fuel element is developed and compared to a reference standard. The model represents a step toward a thermal-hydraulic module for a real-time, autonomous reactor powder controller. The general configuration of the fuel element is a bed of small (diameter about...

  16. The fission power of a conceptual fluidised bed thermal nuclear reactor

    International Nuclear Information System (INIS)

    The fluidised bed thermal nuclear reactor investigated in this paper is an innovative reactor design in which 1 mm diameter TRISO-coated fuel particles are fluidised by helium gas coolant in a 2,5 m diameter and 6 m high cylindrical bed. The coolant flow rate provides part of the reactivity control mechanism. The TRISO-coated particles have an enriched uranium oxide kernel surrounded by layers of porous carbon, pyrolytic carbon and silicon carbide. This paper presents detailed transient modelling results of this conceptual fluidised bed thermal nuclear reactor obtained using the FETCH nuclear criticality model. Previous work has provided evidence to suggest that such a reactor can be dynamically stable for low power outputs of ∝20 MWt. This work focuses on a reactor with a much higher thermal output of 100 MWt. To simulate the fluidised bed reactor the FETCH model has been used to solve the neutron transport equation in full-phase space, coupled to multi-phase gas-particle fluid dynamics. The main difficulty in modelling such a reactor is that its reactivity is a sensitive function of the fuel particle distribution inside the inner fluidised bed reactor cavity. This fuel particle distribution varies chaotically with time which is the root cause of the reactor's power variability. (orig.)

  17. Raising distillate selectivity and catalyst life time in Fischer-Tropsch synthesis by using a novel dual-bed reactor

    International Nuclear Information System (INIS)

    In a novel dual bed reactor Fischer-Tropsch synthesis was studied by using two diff rent cobalt catalysts. An alkali-promoted cobalt catalyst was used in the first bed of a fixed-bed reactor followed by a Raiment promoted cobalt catalyst in the second bed. The activity, product selectivity and accelerated deactivation of the system were assessed and compared with a conventional single bed reactor system. The methane selectivity in the dual-bed reactor was about 18.9% less compared to that of the single-bed reactor. The C5+ selectivity for the dual-bed reactor was 10.9% higher than that of the single-bed reactor. Accelerated deactivation of the catalysts in the dual-bed reactor was 42% lower than that of the single-bed reactor. It was revealed that the amount of catalysts activity recovery after regeneration at 400degC in the dual-bed system is higher than that of the single-bed system

  18. Sustainability and the Fixed Bed Nuclear Reactor (FBNR

    Directory of Open Access Journals (Sweden)

    Farhang Sefidvash

    2012-08-01

    Full Text Available Sustainability as a multifaceted and holistic concept is analyzed. Sustainability involves human relationship with elements such as natural environment, economy, power, governance, education and technology with the ultimate purpose of carrying forward an ever-advancing civilization. The Fixed Bed Nuclear Reactor (FBNR is an innovative, small, simple in design, inherently safe, non-proliferating, and environmentally friendly concept that its deployment can generate energy in a sustainable manner contributing to the prosperity of humanity. The development of FBNR will provide electricity as well as desalinated water through a simple but advanced technology for the developing, as well as developed countries. FBNR is environmentally friendly due to its inherent safety and the convenience of using its spent fuel as the source of radiation for irradiation purposes in agriculture, industry, and medicine. Politically, if a ping pong game brought peace between China and USA, a program of development of FBNR supported by the peace loving international community can become a more mature means to bring peace among certain apparently hostile nations who crave sustainable energy, desalinated water and simple advanced technology.

  19. Packed bed reactor treatment of liquid hazardous and mixed wastes

    International Nuclear Information System (INIS)

    We are developing thermal-based packed bed reactor (PBR) technology as an alternative to incineration for treatment of hazardous organic liquid wastes. The waste streams targeted by this technology are machining fluids contaminated with chlorocarbons and/or chlorofluorocarbons and low levels of plutonium or tritium The PBR offers several distinct advantages including simplistic design, rugged construction, ambient pressure processing, economical operations, as well as ease of scalability and maintainability. In this paper, we provide a description of the apparatus as well as test results using prepared mixtures of machining oils/emulsions with trichloroethylene (TCE), carbon tetrachloride (CCl4), trichloroethane (TCA), and Freon TF. The current treatment system is configured as a two stage device with the PBR (1st stage) coupled to a silent discharge plasma (SDP) cell. The SDP serves as a second stage for further treatment of the gaseous effluent from the PBR. One of the primary advantages of this two stage system is that its suitability for closed loop operation where radioactive components are well contained and even CO2 is not released to the environment

  20. Gas reactor international cooperative program interim report: German Pebble Bed Reactor design and technology review

    International Nuclear Information System (INIS)

    This report describes and evaluates several gas-cooled reactor plant concepts under development within the Federal Republic of Germany (FRG). The concepts, based upon the use of a proven Pebble Bed Reactor (PBR) fuel element design, include nuclear heat generation for chemical processes and electrical power generation. Processes under consideration for the nuclear process heat plant (PNP) include hydrogasification of coal, steam gasification of coal, combined process, and long-distance chemical heat transportation. The electric plant emphasized in the report is the steam turbine cycle (HTR-K), although the gas turbine cycle (HHT) is also discussed. The study is a detailed description and evaluation of the nuclear portion of the various plants. The general conclusions are that the PBR technology is sound and that the HTR-K and PNP plant concepts appear to be achievable through appropriate continuing development programs, most of which are either under way or planned

  1. Modeling-based optimization of a fixed-bed industrial reactor for oxidative dehydrogenation of propane

    Institute of Scientific and Technical Information of China (English)

    Ali Darvishi; Razieh Davand; Farhad Khorasheh; Moslem Fattahi

    2016-01-01

    An industrial scale propylene production via oxidative dehydrogenation of propane (ODHP) in multi-tubular re-actors was modeled. Multi-tubular fixed-bed reactor used for ODHP process, employing 10000 of smal diameter tubes immersed in a shel through a proper coolant flows. Herein, a theory-based pseudo-homogeneous model to describe the operation of a fixed bed reactor for the ODHP to correspondence olefin over V2O5/γ-Al2O3 catalyst was presented. Steady state one dimensional model has been developed to identify the operation parameters and to describe the propane and oxygen conversions, gas process and coolant temperatures, as well as other pa-rameters affecting the reactor performance such as pressure. Furthermore, the applied model showed that a double-bed multitubular reactor with intermediate air injection scheme was superior to a single-bed design due to the increasing of propylene selectivity while operating under lower oxygen partial pressures resulting in propane conversion of about 37.3%. The optimized length of the reactor needed to reach 100%conversion of the oxygen was theoretically determined. For the single-bed reactor the optimized length of 11.96 m including 0.5 m of inert section at the entrance region and for the double-bed reactor design the optimized lengths of 5.72 m for the first and 7.32 m for the second reactor were calculated. Ultimately, the use of a distributed oxygen feed with limited number of injection points indicated a significant improvement on the reactor performance in terms of propane conversion and propylene selectivity. Besides, this concept could overcome the reactor run-away temperature problem and enabled operations at the wider range of conditions to obtain enhanced propyl-ene production in an industrial scale reactor.

  2. Proliferation Resistant Fuel for Pebble Bed Modular Reactors

    International Nuclear Information System (INIS)

    Proliferation of nuclear weapons produced with power reactors plutonium has always been amajor problem of the nuclear energy industry. This includes the PebbleBed Modular Reactor(PBMR), which is a specific design of a GenIV High-Temperature Reactor (HTR), mainly due to its online refueling feature, which may be misused for the production of weapons gradeplutonium. A promising approach toward preventing the proliferation of power reactorplutoniumis to denaturate the plutonium by increasing the ratio of 238Pu to total Pu in the spentfuel(1). The 238Pu isotope is characterized by a high heat rate (approximately 567 W/kg) due to thealpha decay of the 238Pu with half-life of 87.74 yr, in addition to its high spontaneous fissionneutron emission, which is higher than that of 240Pu. Thus, the presence of 238Pu in Pu considerably complicates the design and construction of nuclear weapons based on Pu, owing tothese characteristics of 238Pu. Recent papers(2,3) show that a Pu mixture is proliferation resistant given that the weight ratio of 238Pu to Pu is larger than 6%. In this paper we have studied afeasible technique for ensuring that the 238Pu to Pu ratio, in the Pu produced in PBMR, is larger than 6% during the entire fuel cycle. Contamination of the spent fuel with 238Pu may be achieved by doping the nuclear fuel witheither 241Am or 237Np(4-13). The 238Pu isotope is obtained from both 241Am and 237Np by a neutron-capture reaction and the subsequent decay of the reaction products(13).The 237Np isotopeis by itself a potential weapons grade material. However, its large critical mass of 57±4 kg(14) andthe difficulty of extracting it from irradiated fuel elements make it impractical for weapons purposes. On the other hand, the critical mass of 241Am is smaller, i.e. 34 to 45 kg. However, withdecay heat production of 114W/kg, the critical mass becomes a heat source of 3.9 to 5.1 KW,which makes 241Am unsuitable for weapons applications(3). As a result, it is a non

  3. Treatment of domestic wastewater in an up-flow anaerobic sludge blanket reactor followed by moving bed biofilm reactor

    NARCIS (Netherlands)

    Tawfik, A.; El-Gohary, F.; Temmink, B.G.

    2010-01-01

    The performance of a laboratory-scale sewage treatment system composed of an up-flow anaerobic sludge blanket (UASB) reactor and a moving bed biofilm reactor (MBBR) at a temperature of (22-35 A degrees C) was evaluated. The entire treatment system was operated at different hydraulic retention times

  4. The fluidized bed reactor with a prepolymerization system and its influence on polymer physicochemical characteristics

    Directory of Open Access Journals (Sweden)

    Fernandes F.A.N.

    2003-01-01

    Full Text Available This work addresses the influence of a prepolymerization system on the behavior of the fluidized bed reactor used for polyethylene production. Its influence on the polymer's physicochemical characteristics and production was also studied. The results indicate that the use of prepolymerized catalyst particles results in milder temperatures in the fluidized bed reactor, thus avoiding the formation of hot spots, melting of the polymer particle and reactor shutdown. Productivity can be enhanced depending on the operational conditions used in the prepolymerization reactor.

  5. Fluidized bed as a solid precursor delivery system in a chemical vapor deposition reactor

    OpenAIRE

    Vahlas, Constantin; Caussat, Brigitte; Senocq, François; Gladfelter, Wayne L.; Sarantopoulos, Christos; Toro, David; Moersch, Tyler

    2005-01-01

    Chemical vapor deposition (CVD) using precursors that are solids at operating temperatures and pressures, presents challenges due to their relatively low vapor pressures. In addition, the sublimation rates of solid state precursors in fixed bed reactors vary with particle and bed morphology. In a recent patent application, the use of fluidized bed (FB) technology has been proposed to provide high, reliable, and reproducible flux of such precursors in CVD processes. In the present contribution...

  6. Complex nonlinear behaviour of a fixed bed reactor with reactant recycle

    DEFF Research Database (Denmark)

    Recke, Bodil; Jørgensen, Sten Bay

    The fixed bed reactor with reactant recycle investigated in this paper can exhibit periodic solutions. These solutions bifurcate from the steady state in a Hopf bifurcation. The Hopf bifurcation encountered at the lowest value of the inlet concentration turns the steady state unstable and marks the......,that the dynamic behaviour of a fixed bed reactor with reactant recycle is much more complex than previously reported....

  7. A novel approach for harnessing biofilm communities in moving bed biofilm reactors for industrial wastewater treatment

    OpenAIRE

    Lemire, Joe A.; Marc A Demeter; Iain George; Howard Ceri; Turner, Raymond J.

    2015-01-01

    Moving bed biofilm reactors (MBBRs) are an effective biotechnology for treating industrial wastewater. Biomass retention on moving bed biofilm reactor (MBBR) carriers (biofilm support materials), allows for the ease-of-operation and high treatment capacity of MBBR systems. Optimization of MBBR systems has largely focused on aspects of carrier design, while little attention has been paid to enhancing strategies for harnessing microbial biomass. Previously, our research group demonstrated that ...

  8. Development of a trickle bed reactor of electro-Fenton process for wastewater treatment

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Yangming [Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 401122 (China); School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Liu, Hong, E-mail: liuhong@cigit.ac.cn [Key Laboratory of Reservoir Aquatic Environment, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 401122 (China); Shen, Zhemin, E-mail: zmshen@sjtu.edu.cn [School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Wang, Wenhua [School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2013-10-15

    Highlights: • An electrochemical trickle bed reactor was composed of C-PTFE-coated graphite chips. • The trickle bed reactor had a high H{sub 2}O{sub 2} production rate in a dilute electrolyte. • An azo dye was effectively decomposed by the electro-Fenton process in the reactor. -- Abstract: To avoid electrolyte leakage and gas bubbles in the electro-Fenton (E-Fenton) reactors using a gas diffusion cathode, we developed a trickle bed cathode by coating a layer composed of carbon black and polytetrafluoroethylene (C-PTFE) onto graphite chips instead of carbon cloth. The trickle bed cathode was optimized by single-factor and orthogonal experiments, in which carbon black, PTFE, and a surfactant were considered as the determinant of the performance of graphite chips. In the reactor assembled by the trickle bed cathode, H{sub 2}O{sub 2} was generated with a current of 0.3 A and a current efficiency of 60%. This performance was attributed to the fine distribution of electrolyte and air, as well as the effective oxygen transfer from the gas phase to the electrolyte–cathode interface. In terms of H{sub 2}O{sub 2} generation and current efficiency, the developed trickle bed reactor had a performance comparable to that of the conventional E-Fenton reactor using a gas diffusion cathode. Further, 123 mg L{sup −1} of reactive brilliant red X-3B in aqueous solution was decomposed in the optimized trickle bed reactor as E-Fenton reactor. The decolorization ratio reached 97% within 20 min, and the mineralization reached 87% within 3 h.

  9. Production of specific-structured lipids by enzymatic interesterification in a pilot continuous enzyme bed reactor

    DEFF Research Database (Denmark)

    Xu, Xuebing; Balchen, Steen; Høy, Carl-Erik; Adler-Nissen, Jens

    1998-01-01

    , water dependence, production efficiency and other basic features of the process were performed. The extent of acyl migration (defined as a side reaction) occurring in the present enzyme bed reactor was compared to that in a pilot batch reactor. The continuous enzyme bed reactor was better than the batch......Production of specific-structured lipids (interesterified lipids with a specific structure) by enzymatic interesterification was carried out in a continuous enzyme bed pilot scale reactor. Commercial immobilized lipase (Lipozyme IM) was used and investigations of acyl migration, pressure drop...... reactor in minimizing acyl migration. Generally the former produced about one fourth the acyl migration produced by the latter at a similar extent of incorporation. Pressure drop and production efficiency were evaluated in order to obtain a suitable yield in one reaction step. High incorporation was...

  10. Design of particle bed reactors for the space nuclear thermal propulsion program

    Energy Technology Data Exchange (ETDEWEB)

    Ludewig, H.; Powell, J.R.; Todosow, M.; Maise, G.; Barletta, R.; Schweitzer, D.G. [Brookhaven National Lab., Upton, NY (United States)

    1996-02-01

    This paper describes the design for the Particle Bed Reactor (PBR) that was considered for the Space Nuclear Thermal Propulsion (SNTP) Program. The methods of analysis and their validation are outlined first. Monte Carlo methods were used for the physics analysis, several new algorithms were developed for the fluid dynamics, heat transfer and transient analysis; and commercial codes were used for the stress analysis. We carried out a critical experiment, prototypic of the PBR to validate the reactor physics; blowdown experiments with beds of prototypic dimensions were undertaken to validate the power-extraction capabilities from particle beds. In addition, materials and mechanical design concepts for the fuel elements were experimentally validated. (author).

  11. Model description and kinetic parameter analysis of MTBE biodegradation in a packed bed reactor

    DEFF Research Database (Denmark)

    Waul, Christopher Kevin; Arvin, Erik; Schmidt, Jens Ejbye

    2008-01-01

    A dynamic modeling approach was used to estimate in-situ model parameters, which describe the degradation of methyl tert-butyl ether (MTBE) in a laboratory packed bed reactor. The measured dynamic response of MTBE pulses injected at the reactor's inlet was analyzed by least squares and parameter ...

  12. Discharge Characteristics of Series Surface/Packed-Bed Discharge Reactor Diven by Bipolar Pulsed Power

    Science.gov (United States)

    Hu, Jian; Jiang, Nan; Li, Jie; Shang, Kefeng; Lu, Na; Wu, Yan; Mizuno, Akira

    2016-03-01

    The discharge characteristics of the series surface/packed-bed discharge (SSPBD) reactor driven by bipolar pulse power were systemically investigated in this study. In order to evaluate the advantages of the SSPBD reactor, it was compared with traditional surface discharge (SD) reactor and packed-bed discharge (PBD) reactor in terms of the discharge voltage, discharge current, and ozone formation. The SSPBD reactor exhibited a faster rising time and lower tail voltage than the SD and PBD reactors. The distribution of the active species generated in different discharge regions of the SSPBD reactor was analyzed by optical emission spectra and ozone analysis. It was found that the packed-bed discharge region (3.5 mg/L), rather than the surface discharge region (1.3 mg/L) in the SSPBD reactor played a more important role in ozone generation. The optical emission spectroscopy analysis indicated that more intense peaks of the active species (e.g. N2 and OI) in the optical emission spectra were observed in the packed-bed region. supported by National Natural Science Foundation of China (No. 51177007), the Joint Funds of National Natural Science Foundation of China (No. U1462105), and Dalian University of Technology Fundamental Research Fund of China (No. DUT15RC(3)030)

  13. Metal supplementation to anaerobic granular sludge bed reactors: an environmental engineering approach

    NARCIS (Netherlands)

    Gonzalez Fermoso, F.

    2008-01-01

    The objective of this research is the optimization of essential metal dosing in upflow anaerobic sludge bed (UASB) reactors used for methanogenic wastewater treatment. Optimization of essential metal dosing in UASB reactors is a compromise between achieving the maximal biological activity of the bio

  14. Dispersed plug flow model for upflow anaerobic sludge bed reactors with focus on granular sludge dynamics

    NARCIS (Netherlands)

    Kalyuzhnyi, S.V.; Fedorovich, V.V.; Lens, P.N.L.

    2006-01-01

    A new approach to model upflow anaerobic sludge bed (UASB)-reactors, referred to as a one-dimensional dispersed plug flow model, was developed. This model focusses on the granular sludge dynamics along the reactor height, based on the balance between dispersion, sedimentation and convection using on

  15. Conceptual design of a fluidized bed nuclear reactor: statics, dynamics and safety-related aspects

    NARCIS (Netherlands)

    Agung, A.

    2007-01-01

    In this thesis a conceptual design of an innovative high temperature reactor based on the fluidization principle (FLUBER) is proposed. The reactor should satisfy the following requirements: (a) modular and low power, (b)) large shutdown margin, (c) able to produce power when the bed of particles exp

  16. Computational and experimental prediction of dust production in pebble bed reactors, Part II

    International Nuclear Information System (INIS)

    Highlights: • Custom-built high temperature, high pressure tribometer is designed. • Two different wear phenomena at high temperatures are observed. • Experimental wear results for graphite are presented. • The graphite wear dust production in a typical Pebble Bed Reactor is predicted. -- Abstract: This paper is the continuation of Part I, which describes the high temperature and high pressure helium environment wear tests of graphite–graphite in frictional contact. In the present work, it has been attempted to simulate a Pebble Bed Reactor core environment as compared to Part I. The experimental apparatus, which is a custom-designed tribometer, is capable of performing wear tests at PBR relevant higher temperatures and pressures under a helium environment. This environment facilitates prediction of wear mass loss of graphite as dust particulates from the pebble bed. The experimental results of high temperature helium environment are used to anticipate the amount of wear mass produced in a pebble bed nuclear reactor

  17. Temperature response to reactant concentration perturbations in a packed-bed reactor

    International Nuclear Information System (INIS)

    Unsteady-state operations are known to enhance the performance of some packed-bed reactor systems. However, negative effects of this type of operation should not be neglected. Temperature excursions developed during transients may accelerate some deactivation mechanisms, reducing catalyst lifetime and selectivity. Temperature response to perturbations in reactant concentration was studied for CO oxidation over Pt/Al2O3, in a packed-bed reactor. Experiments were conducted in the CO concentration range for which multiple steady states are observed. Temperature and concentration profiles in the packed-bed reactor at steady state were found to depend on the dynamic history of the reactor prior to the steady-state condition. (author)

  18. Metal supplementation to anaerobic granular sludge bed reactors: an environmental engineering approach

    OpenAIRE

    Gonzalez Fermoso, F.

    2008-01-01

    The objective of this research is the optimization of essential metal dosing in upflow anaerobic sludge bed (UASB) reactors used for methanogenic wastewater treatment. Optimization of essential metal dosing in UASB reactors is a compromise between achieving the maximal biological activity of the biomass present in the reactor, while minimizing the costs of the supplied metal and the metal losses into the environment. The fate of metals in the anaerobic granular sludge is studied. The boundary...

  19. The study on fuel effect in discharge pipe of pebble bed reactor

    International Nuclear Information System (INIS)

    The simulation method of fuel loading in discharge pipe of pebble bed reactor is introduced. As an exemplary application case, the effect of fuel elements in the discharge pipe on reactor physics and thermohydraulic properties is calculated and analysed by CHTRP code in HTR-10 MW. The calculation gives the power and temperature distribution in the area of the discharge pipe, very useful for further analysis of reactor physics and safety

  20. Beneficiation of pulverized coal combustion fly ash in fluidised bed reactors

    Energy Technology Data Exchange (ETDEWEB)

    Cammarota, A.; Chirone, R.; Solimene, R.; Urciuolo, M. [Istituto di Ricerche sulla Combustione - C.N.R., P.le V. Tecchio 80, 80125 Napoli (Italy)

    2008-07-15

    The paper addresses the thermal treatment of pulverized coal combustion fly ash belonging to the group C of Geldart powder classification in unconventional configurations of fluidised bed reactors. A sound-assisted fluidised bed combustor operated at 850 and 750 C, and a fluidised bed combustor characterized by a conical geometry, operated at 850 C, are the two lab-scale reactors tested. Combustion experiments have been carried out at different air excesses, ranging between 10% and 170%, and in the case of the conical fluidization column with different bed inventory. Both tested configurations have been proved to be efficient to reduce the carbon content initially present in the fly ash of 11%{sub w}, to a very low level, generally smaller than 1%{sub w}. Both the fly ash residence time in the reactor and the air excess strongly influenced the reactor performance. Residence times of 3-4 min and 10-60 min have been estimated for experiments carried out with the sound-assisted fluidised bed combustor and with the conical fluidised bed combustor, respectively. Regarding the possibility of a concurrent reduction of unburned carbon in the ash and of a particle size separation of the beneficiated material, on the basis of the obtained experimental data, the sound-assisted fluidised bed combustor is not able to separate the broad particle size distribution of the fly ash in different outlet solid streams. The use of a conical fluidised bed combustor is promising to realize an efficient separation of the inlet broad particle size distribution of the fly ash fed to the reactor into narrower outlet solid streams extracted from different locations: combustor exit, top and bottom of the bed. In this framework a hydrodynamic characterization of binary mixtures in a conical fluidised bed column carried out at ambient and high temperature (850 C) has demonstrated that the operating conditions of the conical fluidised bed combustor can be chosen on the basis of a compromise

  1. Elemental mercury vapor capture by powdered activated carbon in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Fabrizio Scala; Riccardo Chirone; Amedeo Lancia [Istituto di Ricerche sulla Combustione - CNR, Napoli (Italy)

    2011-06-15

    A bubbling fluidized bed of inert material was used to increase the activated carbon residence time in the reaction zone and to improve its performance for mercury vapor capture. Elemental mercury capture experiments were conducted at 100{sup o}C in a purposely designed 65 mm ID lab-scale pyrex reactor, that could be operated both in the fluidized bed and in the entrained bed configurations. Commercial powdered activated carbon was pneumatically injected in the reactor and mercury concentration at the outlet was monitored continuously. Experiments were carried out at different inert particle sizes, bed masses, fluidization velocities and carbon feed rates. Experimental results showed that the presence of a bubbling fluidized bed led to an increase of the mercury capture efficiency and, in turn, of the activated carbon utilization. This was explained by the enhanced activated carbon loading and gas-solid contact time that establishes in the reaction zone, because of the large surface area available for activated carbon adhesion/deposition in the fluidized bed. Transient mercury concentration profiles at the bed outlet during the runs were used to discriminate between the controlling phenomena in the process. Experimental data have been analyzed in the light of a phenomenological framework that takes into account the presence of both free and adhered carbon in the reactor as well as mercury saturation of the adsorbent. 14 refs., 7 figs.

  2. Modeling of realistic pebble bed reactor geometries using the Serpent Monte Carlo code

    International Nuclear Information System (INIS)

    Highlights: • The explicit stochastic geometry model in Serpent is documented. • A pebble bed criticality benchmark was calculated demonstrating the geometry model. • Stochastic pebble configurations were obtained from discrete element simulations. • Results deviate from experiments but are in line with example calculations. - Abstract: This paper documents the models available in Serpent for high temperature reactor (HTR) calculations. It is supplemented by a calculation example of ASTRA critical pebble bed experiments. In the pebble bed reactor modeling, different methods have been used to model the double heterogeneity problem occurring in pebble bed reactor calculations. A solution was sought to avoid unphysical simplifications in the pebble bed modeling and the stochastic geometry modeling features available in the Monte Carlo code Serpent were applied for exact placement of pebbles and fuel particles. Randomly packed pebble beds were produced in discrete element method (DEM) simulations and fuel particles were positioned randomly inside the pebbles. Pebbles and particles are located using a Cartesian search mesh, which provides necessary computational efficiency. Serpent uses Woodcock delta-tracking which provides efficient neutron tracking in the complicated geometries. This detailed pebble bed modeling approach was tested by calculating the ASTRA criticality benchmark experiment done at the Kurchatov Institute in 2004. The calculation results are in line with the sample calculations provided with the benchmark documentation. The material library selected for the calculations has a major effect on the results. The difference in graphite absorption cross section is considered the cause of this result. The model added in Serpent is very efficient with a calculation time slightly higher than with a regular lattice approximation. It is demonstrated that Serpent can be used for pebble bed reactor calculations with minimal geometric approximations as it

  3. Numerical Simulation of Accident Scenario in High Temperature Gas Cooled (Pebble Bed) Nuclear Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Peter, Geoffrey J. [Oregon Institute of Technology - Portland Center, Portland (United States)

    2012-03-15

    The accident scenario resulting from blockages due to the retention of dust in the coolant gas or from the rupture of one or more fuel particles used in the High Temperature Gas Cooled (Pebble Bed) Nuclear Reactors is considered in this paper. The next generation of Advanced High Temperature Reactors (AHTR), are considered for nuclear power production, and for high-temperature hydrogen production using nuclear reactors to reduce the carbon footprint. Blockages can cause LOCA variations in flow and heat transfer that may lead to hot spots within the bed that could compromise reactor safety. Therefore, it is important to know the void fraction distribution and the interstitial velocity field in the packed bed. The blockage for this numerical study simulated a region with significantly lower void than that in the rest of the bed. Finite difference technique solved the simplified continuity, momentum, and energy equations. Any meaningful outcome of the solution depended largely upon the validity of the boundary conditions. Among them, the inlet and outlet velocity profiles required special attention. Thus, a close approximation to these profiles obtained from an experimental set-up established the boundary conditions. This paper presents the development of the elliptic-partial equation for a bed of a bed of pebbles, and the solution procedure. The paper also discusses velocity and temperature profiles obtained from both numerical and experimental set-up, with and without effect of blockage. Based on the studies it is evident that knowledge of LOCA velocity and temperature distribution within the fuel element in a Pebble Bed Nuclear Reactor or AHTR is essential for reactor safety.

  4. Modeling for Anaerobic Fixed-Bed Biofilm Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Liu, B. Y. M.; Pfeffer, J. T.

    1989-06-01

    The specific objectives of this research were: 1. to develop an equilibrium model for chemical aspects of anaerobic reactors; 2. to modify the equilibrium model for non-equilibrium conditions; 3. to incorporate the existing biofilm models into the models above to study the biological and chemical behavior of the fixed-film anaerobic reactors; 4. to experimentally verify the validity of these models; 5. to investigate the biomass-holding ability of difference packing materials for establishing reactor design criteria.

  5. Thermal-hydraulic analysis techniques for axisymmetric pebble bed nuclear reactor cores. [PEBBLE code

    Energy Technology Data Exchange (ETDEWEB)

    Stroh, K.R.

    1979-03-01

    The pebble bed reactor's cylindrical core volume contains a random bed of small, spherical fuel-moderator elements. These graphite spheres, containing a central region of dispersed coated-particle fissile and fertile material, are cooled by high pressure helium flowing through the connected interstitial voids. A mathematical model and numerical solution technique have been developed which allow calculation of macroscopic values of thermal-hydraulic variables in an axisymmetric pebble bed nuclear reactor core. The computer program PEBBLE is based on a mathematical model which treats the bed macroscopically as a generating, conducting porous medium. The steady-state model uses a nonlinear Forchheimer-type relation between the coolant pressure gradient and mass flux, with newly derived coefficients for the linear and quadratic resistance terms. The remaining equations in the model make use of mass continuity, and thermal energy balances for the solid and fluid phases.

  6. Thermal denitrification of evaporators concentrates in reactor with fluidized bed

    International Nuclear Information System (INIS)

    As part of the treatments of liquid wastes coming from the Marcoule reprocessing plant, the study of a thermal denitrification process for evaporator concentrates has been chosen by the CEA/CEN Cadarache: the fluidized-bed calcination. This work presents the study of a calcination pilot-plant for wastes with a very high sodium nitrate content. After a reactional analysis carried out in a thermobalance on samples which are representative of the fluidized-bed compounds, the perfecting of many of the plant parameters - such as the solution injection system - was carried out on a scale-model at first. Then, it was verified on the pilot-plant, and some experiments have been carried out. A mathematical model for the particle growth inside the fluidized-bed is proposed. (author). 179 refs., 65 figs., 23 tabs

  7. Pebble bed reactor fiscal year 1980: review summary report

    International Nuclear Information System (INIS)

    Information on high-temperature reactor development is presented concerning reactor operating experience; core performance assessment; core control and shutdown; reflector and core support; maintenance and availability; safety aspects of PBR and prismatic comparison; PCRV dimensions; and fuel reprocessing cost estimate

  8. Styrene recovery from polystyrene by flash pyrolysis in a conical spouted bed reactor.

    Science.gov (United States)

    Artetxe, Maite; Lopez, Gartzen; Amutio, Maider; Barbarias, Itsaso; Arregi, Aitor; Aguado, Roberto; Bilbao, Javier; Olazar, Martin

    2015-11-01

    Continuous pyrolysis of polystyrene has been studied in a conical spouted bed reactor with the main aim of enhancing styrene monomer recovery. Thermal degradation in a thermogravimetric analyser was conducted as a preliminary study in order to apply this information in the pyrolysis in the conical spouted bed reactor. The effects of temperature and gas flow rate in the conical spouted bed reactor on product yield and composition have been determined in the 450-600°C range by using a spouting velocity from 1.25 to 3.5 times the minimum one. Styrene yield is strongly influenced by both temperature and gas flow rate, with the maximum yield being 70.6 wt% at 500°C and a gas velocity twice the minimum one. PMID:26077230

  9. Carbon Shale Combustion in the Fluidized Bed Reactor

    OpenAIRE

    Olek Małgorzata; Kandefer Stanisław; Kaniowski Wiesław; Żukowski Witold; Baron Jerzy

    2014-01-01

    The purpose of this article is to present the possibilities of coal shale combustion in furnaces with bubbling fluidized bed. Coal shale can be autothermally combusted in the fluidized bed, despite the low calorie value and high ash content of fuel. Established concentrations of CO (500 ppm) and VOC (30 mg/m3) have indicated a high conversion degree of combustible material during combustion process. Average concentrations of SO2 and NOx in the flue gas were higher than this received from the ...

  10. Thermo-catalytic pyrolysis of waste polyethylene bottles in a packed bed reactor with different bed materials and catalysts

    International Nuclear Information System (INIS)

    Highlights: • Thermo-catalytic pyrolysis of waste polyethylene bottles was investigated. • The highest yield of liquid (82%) was obtained over a cement powder bed. • Acidic catalysts narrowed the carbon chain length of the paraffins to C10–C28. • Combination of cement bed with HBeta catalyst gave the highest yield of liquid. • Significant yield of aromatics was obtained mainly naphthalene and D-limonene. - Abstract: Plastic waste is an increasing economic and environmental problem as such there is a great need to process this waste and reduce its environmental impact. In this work, the pyrolysis of high density polyethylene (HDPE) waste products was investigated using both thermal and catalytic cracking techniques. The experimental work was carried out using packed bed reactor operating under an inert atmosphere at 450 °C. Different reactor bed materials, including sand, cement and white clay were used to enhance the thermal cracking of HDPE. In addition, the catalytic effect of sodium hydroxide, HUSY and HBeta zeolite catalysts on the degradation of HDPE waste was also investigated. The reactor beds were found to significantly alter the yield as well as the product composition. Products such as paraffins (⩽C44), olefins (⩽C22), aromatics (⩽C14) and alcohols (C16 and C17) were obtained at varying rates. The highest yield of liquid (82%) was obtained over a cement powder bed with a paraffin yield of 58%. The yield of paraffins and olefins followed separate paths, for paraffins it was found to increase in the order or Cement > White clay > Silica Sand, whereas for the olefins it was in the reverse order Silica Sand > White clay > Cement. The results obtained in this work exhibited a higher P/O ratio than expected, where the amount of generated paraffins was greater than 60% in most cases. Less olefin was generated as a consequence. This indicates that the product generated is more suited to be used as a fuel rather than as a chemical feedstock. The

  11. Energy recovery by gasification of agricultural and forestry wastes in fluidized bed reactors and in moving bed reactors with internal recycle of pyrolysis gas; process development and reactor modelling. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Aarsen, F.G. van den; Susanto, H.; Beenackers, A.A.C.M.; Swaaij, W.P.M. van

    1986-01-01

    A modified co-current moving gasifier bed has been developed which substantially reduces product gas tar content compared to conventional down draft gasifiers and allows for a better scale-up of the reactor. These improvements have been realized by installing an ejector in the air inlet which sucks the pyrolysis gases into the gasifying air stream and allows for subsequent combustion of the pyrolysis products in a separate combustor. In relation to the modelling of a fluidized bed biomass gasifier, we studied the fast pyrolysis of beech wood particles and the char-carbondioxide gasification kinetics in a bench scale fluidized bed reactor. A 30 cm diameter fluidized bed biomass gasifier has been constructed and the reactor performance on wood and rice husks has been studied. Those experiments (at 50 kg biomass/hr) revealed that a good gas quality is produced if the reactor is operated above 800/sup 0/ C, in the co-current mode (bottomfeed). Ongoing research is on mass transfer and flow behaviour in the fluidized bed reactor; a mathematical model of the fluidized bed gasifier is under development.

  12. Modular Pebble-Bed Reactor Project: Laboratory-Directed Research and Development Program FY 2002 Annual Report

    Energy Technology Data Exchange (ETDEWEB)

    Petti, David Andrew; Dolan, Thomas James; Miller, Gregory Kent; Moore, Richard Leroy; Terry, William Knox; Ougouag, Abderrafi Mohammed-El-Ami; Oh, Chang H; Gougar, Hans D

    2002-11-01

    This report documents the results of our research in FY-02 on pebble-bed reactor technology under our Laboratory Directed Research and Development (LDRD) project entitled the Modular Pebble-Bed Reactor. The MPBR is an advanced reactor concept that can meet the energy and environmental needs of future generations under DOE’s Generation IV initiative. Our work is focused in three areas: neutronics, core design and fuel cycle; reactor safety and thermal hydraulics; and fuel performance.

  13. Batch Tests To Determine Activity Distribution and Kinetic Parameters for Acetate Utilization in Expanded-Bed Anaerobic Reactors

    OpenAIRE

    Fox, Peter; Suidan, Makram T.

    1990-01-01

    Batch tests to measure maximum acetate utilization rates were used to determine the distribution of acetate utilizers in expanded-bed sand and expanded-bed granular activated carbon (GAC) reactors. The reactors were fed a mixture of acetate and 3-ethylphenol, and they contained the same predominant aceticlastic methanogen, Methanothrix sp. Batch tests were performed both on the entire reactor contents and with media removed from the reactors. Results indicated that activity was evenly distrib...

  14. Very High Temperature Reactor (VHTR) Deep Burn Core and Fuel Analysis -- Complete Design Selection for the Pebble Bed Reactor

    Energy Technology Data Exchange (ETDEWEB)

    B. Boer; A. M. Ougouag

    2010-09-01

    The Deep-Burn (DB) concept focuses on the destruction of transuranic nuclides from used light water reactor fuel. These transuranic nuclides are incorporated into TRISO coated fuel particles and used in gas-cooled reactors with the aim of a fractional fuel burnup of 60 to 70% in fissions per initial metal atom (FIMA). This high performance is expected through the use of multiple recirculation passes of the fuel in pebble form without any physical or chemical changes between passes. In particular, the concept does not call for reprocessing of the fuel between passes. In principle, the DB pebble bed concept employs the same reactor designs as the presently envisioned low-enriched uranium core designs, such as the 400 MWth Pebble Bed Modular Reactor (PBMR-400). Although it has been shown in the previous Fiscal Year (2009) that a PuO2 fueled pebble bed reactor concept is viable, achieving a high fuel burnup, while remaining within safety-imposed prescribed operational limits for fuel temperature, power peaking and temperature reactivity feedback coefficients for the entire temperature range, is challenging. The presence of the isotopes 239-Pu, 240-Pu and 241-Pu that have resonances in the thermal energy range significantly modifies the neutron thermal energy spectrum as compared to a ”standard,” UO2-fueled core. Therefore, the DB pebble bed core exhibits a relatively hard neutron energy spectrum. However, regions within the pebble bed that are near the graphite reflectors experience a locally softer spectrum. This can lead to power and temperature peaking in these regions. Furthermore, a shift of the thermal energy spectrum with increasing temperature can lead to increased absorption in the resonances of the fissile Pu isotopes. This can lead to a positive temperature reactivity coefficient for the graphite moderator under certain operating conditions. The effort of this task in FY 2010 has focused on the optimization of the core to maximize the pebble discharge

  15. Investigation of Anaerobic Fluidized Bed Reactor Aerobic Mov-ing Bed Bio Reactor (AFBR/MMBR System for Treatment of Currant Wastewater

    Directory of Open Access Journals (Sweden)

    Jalil Jafari

    2013-08-01

    Full Text Available Background: Anaerobic treatment methods are more suitable for the treatment of concentrated wastewater streams, offer lower operating costs, the production of usable biogas product. The aim of this study was to investigate the performance of an Anaerobic Fluidized Bed Reactor (AFBR-Aerobic Moving Bed Bio Reactor (MBBR in series arrangement to treat Currant wastewater.Methods: The bed materials of AFBR were cylindrical particles made of PVC with a diameter of 2-2.3 mm, particle density of 1250 kg/m3.The volume of all bed materials was 1.7 liter which expanded to 2.46 liters in fluidized situation. In MBBR, support media was composed of 1.5 liters Bee-Cell 2000 having porosity of 87% and specific surface area of 650m2/m3.Results: When system operated at 35 ºC, chemical oxygen demand (COD removal efficiencies were achieved to 98% and 81.6% for organic loading rates (OLR of 9.4 and 24.2 g COD/l.d, and hydraulic retention times (HRT of 48 and 18 h, in average COD concentration feeding of 18.4 g/l, respectively.Conclusion: The contribution of AFBR in total COD removal efficiency at an organic loading rate (OLR of 9.4 g COD/l.d was 95%, and gradually decreased to 76.5% in OLR of 24.2 g COD/l.d. Also with increasing in organic loading rate the contribution of aerobic reactor in removing COD gradually decreased. In this system, the anaerobic reactor played the most important role in the removal of COD, and the aerobic MBBR was actually needed to polish the anaerobic treated wastewate

  16. Burnup performance of OTTO cycle pebble bed reactors with ROX fuel

    International Nuclear Information System (INIS)

    Highlights: • A 300 MWt Small Pebble Bed Reactor with Rock-like oxide fuel is proposed. • Using ROX fuel can achieve high discharged burnup of spent fuel. • High geological stability can be expected in direct disposal of the spent ROX fuel. • The Pebble Bed Reactor with ROX fuel can be critical at steady state operation. • All the reactor designs have a negative temperature coefficient. - Abstract: A pebble bed high-temperature gas-cooled reactor (PBR) with rock-like oxide (ROX) fuel was designed to achieve high discharged burnup and improve the integrity of the spent fuel in geological disposal. The MCPBR code with a JENDL-4.0 library, which developed the analysis of the Once-Through-Then-Out (OTTO) cycle in PBR, was used to perform the criticality and burnup analysis. Burnup calculations for eight cases were carried out for both ROX fuel and a UO2 fuel reactor with different heavy-metal loading conditions. The effective multiplication factor of all cases approximately equalled unity in the equilibrium condition. The ROX fuel reactor showed lower FIFA than the UO2 fuel reactor at the same heavy-metal loading, about 5–15%. However, the power peaking factor and maximum power per fuel ball in the ROX fuel core were lower than that of UO2 fuel core. This effect makes it possible to compensate for the lower-FIFA disadvantage in a ROX fuel core. All reactor designs had a negative temperature coefficient that is needed for the passive safety features of a pebble bed reactor

  17. JPL in-house fluidized bed reactor research

    Science.gov (United States)

    Rohatgi, N. K.

    1985-01-01

    The progress in the in-house program on the silane fluidized-bed system is reported. A seed-particle cleaning procedure was developed to obtain material purity near the level required to produce a semiconductor-grade product. The liner-seal design was consistently proven to withstand heating/cooling cycles in all of the experimental runs.

  18. Styrene biofiltration in a trickle-bed reactor

    Directory of Open Access Journals (Sweden)

    V. Novak

    2008-04-01

    Full Text Available The biological treatment of styrene waste gas in a trickle-bed filter (TBF was investigated. The bioreactor consisted of a two-part glass cylinder (ID 150 mm filled with 25 mm polypropylene Pall rings serving as packing material. The bed height was 1m. Although the laboratory temperature was maintained at 22 ºC, the water temperature in the trickle-bed filter was slightly lower (about 18 ºC.The main aim of our study was to observe the effect of empty-bed residence time (EBRT on bioreactor performance at a constant pollutant concentration over an extended time period. The bioreactor was inoculated with a mixed microbial consortium isolated from a styrene-degrading biofilter that had been running for the previous two years. After three weeks of acclimation period, the bioreactor was loaded with styrene (100 mg.m-3. EBRT was in the range of 53 s to 13 s. A maximum elimination capacity (EC of 11.3 gC.m-3.h-1 was reached at an organic loading (OL rate of 18.6 gC.m-3.h-1.

  19. Gasification of Coal and PET in Fluidized Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Pohořelý, Michael; Vosecký, Martin; Kameníková, Petra; Punčochář, Miroslav; Skoblia, Sergej; Staf, M.; Vošta, J.; Koutský, B.; Svoboda, Karel

    2006-01-01

    Roč. 85, 17-18 (2006), s. 2458-2468. ISSN 0016-2361 R&D Projects: GA ČR(CZ) GA104/04/0829 Institutional research plan: CEZ:AV0Z40720504 Keywords : fludized bed * gasification * plastic waste Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.358, year: 2006

  20. Air gasification of rice husk in bubbling fluidized bed reactor with bed heating by conventional charcoal.

    Science.gov (United States)

    Makwana, J P; Joshi, Asim Kumar; Athawale, Gaurav; Singh, Dharminder; Mohanty, Pravakar

    2015-02-01

    An experimental study of air gasification of rice husk was conducted in a bench-scale fluidized bed gasifier (FBG) having 210 mm diameter and 1600 mm height. Heating of sand bed material was performed using conventional charcoal fuel. Different operating conditions like bed temperature, feeding rate and equivalence ratio (ER) varied in the range of 750-850 °C, 25-31.3 kg/h, and 0.3-0.38, respectively. Flow rate of air was kept constant (37 m(3)/h) during FBG experiments. The carbon conversion efficiencies (CCE), cold gas efficiency, and thermal efficiency were evaluated, where maximum CCE was found as 91%. By increasing ER, the carbon conversion efficiency was decreased. Drastic reduction in electric consumption for initial heating of gasifier bed with charcoal compared to ceramic heater was ∼45%. Hence rice husk is found as a potential candidate to use directly (without any processing) in FBG as an alternative renewable energy source from agricultural field. PMID:25446789

  1. Modeling of a fluidized bed reactor for the ethylene-propylene copolymerization

    Directory of Open Access Journals (Sweden)

    Juan Guillermo Cadavid Estrada

    2010-04-01

    Full Text Available A mathematical model for the ethylene - propylene copolymerization with a Ziegler - Natta catalyst in a gas phase fludized bed reactor is presented. The model includes a two active site kinetic model with spontaneous transfer reactions and site deactivation. Also, it is studied and simulated the growth of a polymeric particle which is exposed to an outside atmosphere (monomers concentrations and temperature that represent the emulsion phase conditions of the reactor. Particle growth model is the basis for the study of the sizes distribution into the reactor. Two phase model of Kunii-Levenspiel is the basis for the modelling and simulation of the fluid bed reactor, the models developed consider two extreme cases for the gas mixed grade in emulsion phase (perfectly mixed and plug flow. The solution of the models includes mass (for the two monomers and energy balances, coupled with the particle growth and residence time distribution models.

  2. Transuranics elimination in an optimised pebble-bed sub-critical reactor

    International Nuclear Information System (INIS)

    In a nuclear energy economy the nuclear waste is a big burden to its further development and deployment. The possibility of eliminating the long-term part of the waste presents an appealing opportunity to the sustainability and acceptance of a better and cleaner source of energy. It is shown that the proposed pebble-bed transmutator has suitable characteristics to transmute most of the isotopes that contribute to the long-term radioactivity. This proposed reactor presents also inherent safety characteristics, which is a necessary element in a new reactor design to be accepted by the society. Throughout this paper, we will characterise the new reactor concept, and present some of the neutronics and safety characteristics of an accelerator driven pebble-bed reactor, (ADS) for transuranics elimination. (author)

  3. Simultaneous nitrification-denitrification and phosphorus removal in a fixed bed sequencing batch reactor (FBSBR)

    Energy Technology Data Exchange (ETDEWEB)

    Rahimi, Yousef, E-mail: you.rahimi@gmail.com [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Torabian, Ali, E-mail: atorabi@ut.ac.ir [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Mehrdadi, Naser, E-mail: mehrdadi@ut.ac.ir [Department of Civil and Environmental Engineering, Graduate Faculty of Environment, University of Tehran, No. 25 Qods St., Enghelab Ave, Tehran (Iran, Islamic Republic of); Shahmoradi, Behzad, E-mail: bshahmorady@gmail.com [Department of Environmental Science, University of Mysore, MGM-06 Mysore (India)

    2011-01-30

    Research highlights: {yields} Sludge production in FSBR reactor is 20-30% less than SBR reactor. {yields} FSBR reactor showed more nutrient removal rate than SBR reactor. {yields} FSBR reactor showed less VSS/TSS ratio than SBR reactor. - Abstract: Biological nutrient removal (BNR) was investigated in a fixed bed sequencing batch reactor (FBSBR) in which instead of activated sludge polypropylene carriers were used. The FBSBR performance on carbon and nitrogen removal at different loading rates was significant. COD, TN, and phosphorus removal efficiencies were at range of 90-96%, 60-88%, and 76-90% respectively while these values at SBR reactor were 85-95%, 38-60%, and 20-79% respectively. These results show that the simultaneous nitrification-denitrification (SND) is significantly higher than conventional SBR reactor. The higher total phosphorus (TP) removal in FBSBR correlates with oxygen gradient in biofilm layer. The influence of fixed media on biomass production yield was assessed by monitoring the MLSS concentrations versus COD removal for both reactors and results revealed that the sludge production yield (Y{sub obs}) is significantly less in FBSBR reactors compared with SBR reactor. The FBSBR was more efficient in SND and phosphorus removal. Moreover, it produced less excess sludge but higher in nutrient content and stabilization ratio (less VSS/TSS ratio).

  4. Simultaneous nitrification-denitrification and phosphorus removal in a fixed bed sequencing batch reactor (FBSBR)

    International Nuclear Information System (INIS)

    Research highlights: → Sludge production in FSBR reactor is 20-30% less than SBR reactor. → FSBR reactor showed more nutrient removal rate than SBR reactor. → FSBR reactor showed less VSS/TSS ratio than SBR reactor. - Abstract: Biological nutrient removal (BNR) was investigated in a fixed bed sequencing batch reactor (FBSBR) in which instead of activated sludge polypropylene carriers were used. The FBSBR performance on carbon and nitrogen removal at different loading rates was significant. COD, TN, and phosphorus removal efficiencies were at range of 90-96%, 60-88%, and 76-90% respectively while these values at SBR reactor were 85-95%, 38-60%, and 20-79% respectively. These results show that the simultaneous nitrification-denitrification (SND) is significantly higher than conventional SBR reactor. The higher total phosphorus (TP) removal in FBSBR correlates with oxygen gradient in biofilm layer. The influence of fixed media on biomass production yield was assessed by monitoring the MLSS concentrations versus COD removal for both reactors and results revealed that the sludge production yield (Yobs) is significantly less in FBSBR reactors compared with SBR reactor. The FBSBR was more efficient in SND and phosphorus removal. Moreover, it produced less excess sludge but higher in nutrient content and stabilization ratio (less VSS/TSS ratio).

  5. Role of Moving Bed Biofilm Reactor and Sequencing Batch Reactor in Biological Degradation of Formaldehyde Wastewater

    Directory of Open Access Journals (Sweden)

    B. Ayati

    2011-10-01

    Full Text Available Nowadays formaldehyde is used as raw material in many industries. It has also disinfection applications in some public places. Due to its toxicity for microorganisms, chemical or anaerobic biological methods are applied for treating wastewater containing formaldehyde.In this research, formaldehyde removal efficiencies of aerobic biological treatment systems including moving bed biofilm (MMBR and sequencing batch reactors (SBR were investigated. During all experiments, the efficiency of SBR was more than MBBR, but the difference was not significant statistically. According to the results, the best efficiencies were obtained for influent formaldehyde COD of 200 mg/L in MBBR and SBR which were 93% and 99.4%, respectively. The systems were also capable to treat higher formaldehyde concentrations (up to 2500 mg/L with lower removal efficiency. The reaction kinetics followed the Stover-Kincannon second order model. The gram-positive and gram-negative bacillus and coccus as well as the gram-positive binary bacillus were found to be the most dominant species. The results of 13C-NMR analysis have shown that formaldehyde and urea were converted into N-{[(aminocarbonyl amino] methyl}urea and the residual formaldehyde was polymerized at room temperature.

  6. Fluidized bed reactor for polyethylene production. The influence of polyethylene prepolymerization

    Directory of Open Access Journals (Sweden)

    F.A.N. Fernandes

    2000-06-01

    Full Text Available This work addresses the influence of the prepolymerization of the catalyst particle on the fluidized bed reactor for polyethylene production. The influence of prepolymerization on the temperature and concentration gradients throughout the reactor was studied. The results obtained through simulations confirm industrial observations of the advantages of prepolymerization and extend these observation, showing the viable operational conditions for different superficial gas velocities and gas feeding temperatures as a function of the degree of prepolymerization.

  7. Design of a power conversion system for an indirect cycle, helium cooled pebble bed reactor system

    International Nuclear Information System (INIS)

    A design is presented for the turbomachinery for an indirect cycle, closed, helium cooled modular pebble bed reactor system. The design makes use of current technology and will operate with an overall efficiency of 45%. The design uses an intermediate heat exchanger which isolated the reactor cycle from the turbomachinery. This design excludes radioactive fission products from the turbomachinery. This minimizes the probability of an air ingress accident and greatly simplifies maintenance. (author)

  8. Influence of dissolved oxygen in nitrification kinetics in a circulating bed reactor

    OpenAIRE

    V. Lazarova; R. Nogueira; J. Manem; Melo, L. F.

    1997-01-01

    The influence of dissolved oxygen concentration in nitrification kinetics was studied in a new biofilm reactor, the circulating bed reactor (CBR). The study was carried out partly at laboratory scale with synthetic water containing inorganic carbon and nitrogen compounds, and partly at pilot scale for secondary and tertiary nitrification of municipal wastewater. The experimental results showed that, either the ammonia or the oxygen concentration could be limiting for the nitrification rate...

  9. Generic Investigations on Transport Theory Modelling of High Temperature Reactors of Pebble Bed Type

    OpenAIRE

    Sureda Sureda, Antonio Jaime

    2008-01-01

    The GRS (Gesellschaft fuer Anlagen und Reaktorsicherheit = Company for Plant and Reactor Safety) maintains and further develops the code system DORT-TD/HERMIX-DIREKT, which is a complex tool for the simulation of coupled neutronics/thermal-hydraulics transients and accident scenarios of high-temperature gas cooled reactors of pebble bed type. With this tool, GRS takes part in the international benchmark activity "OECD/NEA PBMR400 Transient Benchmark”, which aims at the simulation of transient...

  10. Chemical Looping Reactor System Design : Double Loop Circulating Fluidized Bed (DLCFB)

    OpenAIRE

    Bischi, Aldo

    2012-01-01

    Chemical looping combustion (CLC) is continuously gaining more importance among the carbon capture and storage (CCS) technologies. It is an unmixed combustion process which takes place in two steps. An effective way to realize CLC is to use two interconnected fluidized beds and a metallic powder circulating among them, acting as oxygen carrier. The metallic powder oxidizes at high temperature in one of the two reactors, the air reactor (AR). It reacts in a highly exothermic reaction with the ...

  11. Fluidized bed reactor for polyethylene production. The influence of polyethylene prepolymerization

    OpenAIRE

    Fernandes F.A.N.; Lona L.M.F.

    2000-01-01

    This work addresses the influence of the prepolymerization of the catalyst particle on the fluidized bed reactor for polyethylene production. The influence of prepolymerization on the temperature and concentration gradients throughout the reactor was studied. The results obtained through simulations confirm industrial observations of the advantages of prepolymerization and extend these observation, showing the viable operational conditions for different superficial gas velocities and gas feed...

  12. Simulation for Supporting Scale-Up of a Fluidized Bed Reactor for Advanced Water Oxidation

    OpenAIRE

    Farhana Tisa; Abdul Aziz Abdul Raman; Wan Mohd Ashri Wan Daud

    2014-01-01

    Simulation of fluidized bed reactor (FBR) was accomplished for treating wastewater using Fenton reaction, which is an advanced oxidation process (AOP). The simulation was performed to determine characteristics of FBR performance, concentration profile of the contaminants, and various prominent hydrodynamic properties (e.g., Reynolds number, velocity, and pressure) in the reactor. Simulation was implemented for 2.8 L working volume using hydrodynamic correlations, continuous equation, and simp...

  13. Carbon Shale Combustion in the Fluidized Bed Reactor

    Directory of Open Access Journals (Sweden)

    Olek Małgorzata

    2014-06-01

    Full Text Available The purpose of this article is to present the possibilities of coal shale combustion in furnaces with bubbling fluidized bed. Coal shale can be autothermally combusted in the fluidized bed, despite the low calorie value and high ash content of fuel. Established concentrations of CO (500 ppm and VOC (30 mg/m3 have indicated a high conversion degree of combustible material during combustion process. Average concentrations of SO2 and NOx in the flue gas were higher than this received from the combustion of high quality hard coal, 600 ppm and 500 ppm, respectively. Optional reduction of SO2 and NOx emission may require the installation of flue gas desulphurization and de-NOx systems.

  14. Experimental, kinetic and numerical modeling of hydrogen production by catalytic reforming of crude ethanol over a commercial catalyst in packed bed tubular reactor and packed bed membrane reactor

    International Nuclear Information System (INIS)

    The demand for hydrogen energy has increased tremendously in recent years essentially because of the increase in the word energy consumption as well as recent developments in fuel cell technologies. The energy information administration has projected that world energy consumption will increase by 59% over the next two decades, from 1999 to 2020, in which the largest share is still dominated by fossil fuels (oil, natural gas and coal). Carbon dioxide (CO2) emissions resulting from the combustion of these fossil fuels currently are estimated to account for three-fourth of human-caused CO2 emissions worldwide. Greenhouse gas emission, including CO2, should be limited, as recommended at the Kyoto Conference, Japan, in December 1997. In this regard, hydrogen (H2) has a significant future potential as an alternative fuel that can solve the problems of CO2 emissions as well as the emissions of other air contaminants. One of the techniques to produce hydrogen is by reforming of hydrocarbons or biomass. Crude ethanol (a form of biomass, which essentially is fermentation broth) is easy to produce, is free of sulphur, has low toxicity, and is also safe to handle, transport and store. In addition, crude ethanol consists of oxygenated hydrocarbons, such as ethanol, lactic acid, glycerol, and maltose. These oxygenated hydrocarbons can be reformed completely to H2 and CO2, the latter of which could be separated from H2 by membrane technology. This provides for CO2 capture for eventual storage or destruction. In the case of using crude ethanol, this will result in negative CO2, emissions. In this paper, we conducted experimental work on production of hydrogen by the catalytic reforming of crude ethanol over a commercial promoted Ni-based catalyst in a packed bed tubular reactor as well as a packed bed membrane reactor. As well, a rigorous numerical model was developed to simulate this process in both the catalytic packed bed tubular reactor and packed bed membrane reactor. The

  15. Mathematical model of processes of reactor with gasified fluidized bed

    International Nuclear Information System (INIS)

    An original scheme of steam generator with gasifying fluidized bed has been presented as a possible solution for reconstruction of furnace with pulverized burning of coal. The method is effective when applied in combination with desulfurization for the purpose of reducing the CO2 emissions level. A mathematical model has been developed, which determines the correlation primary (fluidizing) and (burning out) secondary air with sufficient for the practice accuracy

  16. Sludge combustion in fluidized bed reactors at laboratory scale

    International Nuclear Information System (INIS)

    The combustion of a dried sewage sludge in laboratory scale fluidized bed has been studied in Naples by the Istituto di ricerche sulla combustione (Irc) in the framework of a National project named Thermal Process with Energy Recovery to be used in laboratory and pre-pilot scale apparatus. The attention has been focused on emissions of unreacted carbon as elutriated fines, on the emissions of pollutant gases and on the assessment of the inventory of fly- and bottom ashes. The combustion behaviour of sewage sludge has been compared with those of a market available Tyre Derived Fuel (TDF) and a biomass from Mediterranean area (Robinia Pseudoacacia) and with that of a South African bituminous coal. Stationary combustion tests were carried out at 8500 C by feeding particles in the size range 0-1 mm into a bed of silica sand without any sorbent addition. The fluidized bed combustor has been operated, at a superficial gas velocity of 0.4 m/s and different excesses of air ranging between 14 and 98%. Relatively high combustion efficiency, larger than 98.9% has been obtained in experiments carried out with sewage sludge and excess of air larger than 20%. These values, are comparable with those obtained in previously experimental activity carried out under similar operative conditions with a South Africa Bituminous coal (97-98%). It is larger than those obtained by using a Tyre Derived Fuel (89-90%) and the Robinia Pseudoacacia Biomass (93-93%). The relative importance of carbon fines elutriation, CO emissions and volatile bypassing the bed in determining the loss of combustion efficiency has been evaluated for the different fuels tested

  17. Control rod for a pebble bed nuclear reactor

    International Nuclear Information System (INIS)

    In order to leave the density of the pebble bed unchanged when the control rod is driven in and out, the tip of the control rod is provided with moving parts in the form of conical hemispheres or spoons. These parts move close to the control rod when it is driven in and spread out due to the effect of gravity when it is driven out. This loosens the heap of pebble shaped operating elements again. (DG)

  18. Gasification of wood in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, L.C. de; Marti, T.; Frankenhaeuser, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    A first series of gasification experiments with our fluidized bed gasifier was performed using clean sawdust as fuel. The installation and the analytical systems were tested in a parametric study in which gasification temperature and equivalence ratio were varied. The data acquired will serve to establish the differences between the gasification of clean wood and the gasification of Altholz (scrapwood) and wood/plastics mixtures. (author) 1 fig., 3 tabs., 5 refs.

  19. Deposition reactors for solar grade silicon: A comparative thermal analysis of a Siemens reactor and a fluidized bed reactor

    Science.gov (United States)

    Ramos, A.; Filtvedt, W. O.; Lindholm, D.; Ramachandran, P. A.; Rodríguez, A.; del Cañizo, C.

    2015-12-01

    Polysilicon production costs contribute approximately to 25-33% of the overall cost of the solar panels and a similar fraction of the total energy invested in their fabrication. Understanding the energy losses and the behaviour of process temperature is an essential requirement as one moves forward to design and build large scale polysilicon manufacturing plants. In this paper we present thermal models for two processes for poly production, viz., the Siemens process using trichlorosilane (TCS) as precursor and the fluid bed process using silane (monosilane, MS). We validate the models with some experimental measurements on prototype laboratory reactors relating the temperature profiles to product quality. A model sensitivity analysis is also performed, and the effects of some key parameters such as reactor wall emissivity and gas distributor temperature, on temperature distribution and product quality are examined. The information presented in this paper is useful for further understanding of the strengths and weaknesses of both deposition technologies, and will help in optimal temperature profiling of these systems aiming at lowering production costs without compromising the solar cell quality.

  20. COMPARISON OF PHENOL REMOVAL IN ANAEROBIC FLUIDIZED BED REACTORS WITH SAND AND GAC MEDIA

    Directory of Open Access Journals (Sweden)

    A.R. Yazdanbakhsh; A.R. Mesdaghinia; A. Torabian; M. Shariat

    1997-08-01

    Full Text Available In this study two identical anaerobic completely mixed fluidized bed reactors with GAC and sand media were employed for COD & phenol removal. At loading rate of 1.6 g phenol L-1d-1, the efficiency of phenol removal in GAC & sand reactors were 97.7% & 74%, respectively. At high loading rate of phenol (6.09 g phenol I: 1d1 the efficiency of phenol removal in GAC reactor was better than 95%. In GAC reactor, the main mechanism for phenol removal at steady state condition was biological process; this was concluded through balance of gas production and COD removal. Better efficiency of GAC reactor comparing with sand reactor was because of resistance to fluctuations, higher surface for biomass growth and adsorption capacity of activated carbon.

  1. A Pebble-Bed Breed-and-Burn Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Greenspan, Ehud [Univ. of California, Berkeley, CA (United States)

    2016-03-31

    The primary objective of this project is to use three-dimensional fuel shuffling in order to reduce the minimum peak radiation damage of ~550 dpa present Breed-and-Burn (B&B) fast nuclear reactor cores designs (they feature 2-D fuel shuffling) call for to as close as possible to the presently accepted value of 200 dpa thereby enabling earlier commercialization of B&B reactors which could make substantial contribution to energy sustainability and economic stability without need for fuel recycling. Another objective is increasing the average discharge burnup for the same peak discharge burnup thereby (1) increasing the fuel utilization of 2-D shuffled B&B reactors and (2) reducing the reprocessing capacity required to support a given capacity of FRs that are to recycle fuel.

  2. A Pebble-Bed Breed-and-Burn Reactor

    International Nuclear Information System (INIS)

    The primary objective of this project is to use three-dimensional fuel shuffling in order to reduce the minimum peak radiation damage of ~550 dpa present Breed-and-Burn (B&B) fast nuclear reactor cores designs (they feature 2-D fuel shuffling) call for to as close as possible to the presently accepted value of 200 dpa thereby enabling earlier commercialization of B&B reactors which could make substantial contribution to energy sustainability and economic stability without need for fuel recycling. Another objective is increasing the average discharge burnup for the same peak discharge burnup thereby (1) increasing the fuel utilization of 2-D shuffled B&B reactors and (2) reducing the reprocessing capacity required to support a given capacity of FRs that are to recycle fuel.

  3. Proposal for an international experimental pebble bed reactor - HTR2008-58174

    International Nuclear Information System (INIS)

    HTRs, both prismatic block fuelled and pebble fuelled, feature a number of uniquely beneficial characteristics that will be discussed in this paper. In this paper the construction of an international experimental pebble bed reactor is proposed, possible experiments suggested and an invitation extended to interested partners for co-operation in the project. Experimental verification by nuclear regulators in order to facilitate licensing and the development of a new generation of reactors create a strong need for such a reactor. Suggested experiments include: Optimized incineration of waste Pu in a pebble bed reactor: The capability to incineration pure reactor grade plutonium by means of ultra high burn-up in pebble bed reactors will be presented at this conference in the track on fuel and fuel cycles. This will enable incineration of the global stockpile of separated reactor grade Pu within a relatively short time span. Testing of fuel sphere geometries, aimed at improving neutron moderation and a decrease in fuel temperatures. Th/Pu fuel cycles: Previous HTR programs demonstrated the viability of a Th-232 fuel-cycle, using highly enriched uranium (HEU) as driver material. However, considerations favoring proliferation resistance limit the enrichment level of uranium in commercial reactors to 20 %, thereby lowering the isotopic efficiency. Therefore, Pu driver material should be developed to replace the HEU component. Instead of deploying a (Th, Pu)O fuel concept, the proposal is to use the unique capability offered by pebble bed reactors in deploying separate Th- and Pu-containing pebbles, which can be cycled differently. Testing of carbon-fiber-carbon (CFC) structures for in-core or near-core applications, such as guide tubes for reserve shutdown systems, thus creating the possibility to safely shutdown reactors with increased diameter. Development of very high temperature reactor components for process heat applications. Advanced decay heat removal systems e

  4. Method for loading, operating, and unloading a ball-bed nuclear reactor

    International Nuclear Information System (INIS)

    This patent describes a method of operating a ball-bed nuclear reactor with fuel element balls. Some have a fissionable material content different from that of others of the balls. It consists of: initially partly filling a reactor core with fuel balls of sufficient fissionable material content for establishing criticality and a desired level of power production at the completion of the partial filling and then, without any further filling of the reactor cavern, starting reactor operation; thereafter without any removal of fuel balls from the reactor cavern, filling fuel balls continually or in groups at relatively short intervals into the reactor cavern during increasing burning up of the fuel balls already, for compensation of the diminishing fissionable material content of the reactor core constituted by the fuel balls until a final total quantity of filling is reached; after the final filling quantity is reached and burning up has occurred, shutting down the reactor, cooling it off, releasing the pressure in the cavern, and thereafter unloading all the fuel balls from the reactor cavern, unloading being begun when the reactor is shut down and being completed before the reactor is restarted

  5. CFD-DEM simulation of a conceptual gas-cooled fluidized bed nuclear reactor

    Energy Technology Data Exchange (ETDEWEB)

    Almeida, Lucilla C.; Su, Jian, E-mail: lucillalmeida@gmail.com, E-mail: sujian@nuclear.ufrj.br [Coordenacao dos Programas de Pos-Graduacao (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil). Programa de Engenharia Nuclear; Aguirre, Joao, E-mail: aguirre@rocky-dem.com [Engineering Simulation and Scientific Software (ESSS), Rio de Janeiro, RJ (Brazil)

    2015-07-01

    Several conceptual designs of the fluidized-bed nuclear reactor have been proposed due to its many advantages over conventional nuclear reactors such as PWRs and BWRs. Amongst their characteristics, the enhanced heat transfer and mixing enables a more uniform temperature distribution, reducing the risk of hot-spot and excessive fuel temperature, in addition to resulting in a higher burnup of the fuel. Furthermore, the relationship between the bed height and reactor neutronics turns the coolant flow rate control into a power production mechanism. Moreover, the possibility of removing the fuel by gravity from the movable core in case of a loss-of-cooling accident increases its safety. High-accuracy modeling of particles and coolant flow in fluidized bed reactors is needed to evaluate reliably the thermal-hydraulic efficiency and safety margin. The two-way coupling between solid and fluid can account for high-fidelity solid-solid interaction and reasonable accuracy in fluid calculation and fluid-solid interaction. In the CFD-DEM model, the particles are modeled as a discrete phase, following the DEM approach, whereas the fluid flow is treated as a continuous phase, described by the averaged Navier-Stokes equations on a computational cell scale. In this work, the coupling methodology between Fluent and Rocky is described. The numerical approach was applied to the simulation of a bubbling fluidized bed and the results were compared to experimental data and showed good agreement. (author)

  6. Titanium-based coatings on copper by chemical vapor deposition in fluidized bed reactors

    International Nuclear Information System (INIS)

    Titanium, TiN and TiOx coatings were deposited on copper and Cu-Ni alloys by chemical vapor deposition in fluidized bed reactors. These coatings provide the copper with a tenfold increase in corrosion resistance in chloride aqueous environments, as determined by a.c. impedance studies. (orig.)

  7. ANALYSIS OF AN AEROBIC FLUIDIZED BED REACTOR DEGRADING MTBE AND BTEX AT REDUCED EBCTS

    Science.gov (United States)

    The purpose of this study was to investigate the biodegradation of MTBE and BTEX using a fluidized bed reactor (FBR) with granular activated carbon (GAC) as a biological attachment medium. Batch experiments were run to analyze the MTBE and TBA degradation kinetics of the culture ...

  8. Renewable lower reflector structure for a high temperature pebble bed reactor

    International Nuclear Information System (INIS)

    The description is given of a renewable lower reflector structure for a high temperature pebble bed reactor of the type comprising a cylindrical or prismatic graphite vessel wrapped in concrete and terminating at its lower end with a conical or pyramidal bottom fitted with a central aperture allowing the pebbles to be discharged by gravity. This structure includes a bed of several layers of protective graphite pebbles on the bottom and, fitted vertically so as to be removable along the centre line of the central aperture through the reflector and the concrete, a graphite block drilled in its centre to allow the discharge of the fuel pebbles and the protective pebbles. The graphite block rises above the level of the central aperture by an extent corresponding to the thickness of the bed when the reactor is working

  9. Entropy generation minimization for a packed bed reactor in nuclear hydrogen production

    International Nuclear Information System (INIS)

    The thermochemical copper-chlorine (Cu-Cl) cycle is a promising method to produce hydrogen with nuclear energy. In this paper, the fluid flow and heat transfer processes are examined for a packed bed chemical reactor in the Cu-Cl cycle. The heat transfer rate is predicted by a heat-momentum analogy for external flow over a particle, using the friction factor and Reynolds number. The Nusselt number correlation compares well against three prior methods to predict the Nusselt number in a packed bed (for various combinations of the void fraction, Reynolds and Prandtl numbers). The analysis is extended to minimize the entropy generation due to heat transfer and fluid flow irreversibilities in the packed bed reactor. (author)

  10. The modular pebble bed high temperature gas reactor

    International Nuclear Information System (INIS)

    Modular High Temperature Reactor power plants are characterized by the fact that standardized reactor units - modules -, each with a thermal power rating of 200-250 MW, can be interconnected to yield power plants in a broad power range. Provided that modular power plants are competitive, there is a variety of applications, e.g.: principal initial applications in the generation of electricity for a wide range of utility grid and plant sizes; co-generation of process steam and electricity, or district heat and electricity, for industrial or municipal consumers; and, in the long term, direct use of nuclear heat for process purposes e.g. gasifying coal, reforming methane etc. An essential condition for reasonably low capital costs is a simple design, taking into account the inherent safety features of small HTR's, e.g. the elimination of separate, redundant cooling systems for decay heat removal. Moreover, the safety concept must be simple, in order to minimize the engineering effort for the nuclear licensing procedure. Further, key reactor safety features should be convincingly demonstrated by full-scale test at an affordable cost, to provide a basis for standardized licensing of replicated reactors (the License-By-Test approach). In addition, the systems and structures within the nuclear envelope must be isolated such that the non-nuclear portion of the plant can be constructed as conventional power plant systems and structures. The Modular HTGR is designed to meet these conditions for safe, economical nuclear power

  11. CFD Simulation of Pilot HDS Trickle-Bed Reactor

    OpenAIRE

    Tukač, V.

    2012-01-01

    The goal of this study is to compare experimental measurement obtained by RTD method with result of computational model. The goal of this work is to evaluate influence of dilution extent on operation of pilot test reactor and to forecast interaction between intrinsic reaction kinetic, hydrodynamics and mass transfer.

  12. Chlorination of commercial molybdenite concentrate in a fluidized bed reactor

    Science.gov (United States)

    Nair, K. U.; Sathiyamoorthy, D.; Bose, D. K.; Sundaresan, M.; Gupta, C. K.

    1987-06-01

    Studies on recovery of molybdenum from commercial grade molybdenite using the technique of fluidized bed chlorination in the presence of oxygen are presented. Molybdenum recovery above 99 pct at a chlorine utilization efficiency of 84 pct has been achieved for a fluidizing gas flow-rate of 3 L/min of the gases Cl2, O2, and N2 mixed in the proportion of 2∶5∶23, respectively, at 300 °C. The investigations on kinetics showed that the overall oxychlorination reaction is controlled by chemical reaction and is of first order with respect to particle surface area.

  13. Conversion enhancement of tubular fixed-bed reactor for Fischer-Tropsch synthesis using static mixer

    Institute of Scientific and Technical Information of China (English)

    Phavanee Narataruksa; Sabaithip Tungkamani; Karn Pana-Suppamassadu; Phongsak Keeratiwintakorn; Siriluck Nivitchanyong; Piyapong Hunpinyo; Hussanai Sukkathanyawat; Prayut Jiamrittiwong; Visarut Nopparat

    2012-01-01

    Recently,Fischer-Tropsch synthesis (FTS) has become an interesting technology because of its potential role in producing biofuels via Biomassto-Liquids (BTL) processes.In Fischer-Tropsch (FT) section,biomass-derived syngas,mainly composed of a mixture of carbon monoxide (CO)and hydrogen (H2),is converted into various forms of hydrocarbon products over a catalyst at specified temperature and pressure.Fixed-bed reactors are typically used for these processes as conventional FT reactors.The fixed-bed or packed-bed type reactor has its drawbacks,which are heat transfer limitation,i.e.a hot spot problem involved highly exothermic characteristics of FT reaction,and mass transfer limitation due to the condensation of liquid hydrocarbon products occurred on catalyst surface.This work is initiated to develop a new chemical reactor design in which a better distribution of gaseous reactants and hydrocarbon products could be achieved,and led to higher throughput and conversion.The main goal of the research is the enhancement of a fixed-bed reactor,focusing on the application of KenicsTM static mixer insertion in the tubular packed-bed reactor.Two FTS experiments were carried out using two reactors i.e.,with and without static mixer insertion within catalytic beds.The modeled syngas used was a mixed gas composed of H2/CO in 2 ∶ 1 molar ratio that was fed at the rate of 30 mL(STP)·min-1 (GHSV ≈ 136 mL·g-1cat·h-1) into the fixed Ru supported aluminum catalyst bed of weight 13.3 g.The reaction was carried out at 180 ℃ and atmospheric pressure continuously for 36 h for both experiments.Both transient and steady-state conversions (in terms of time on stream) were reported.The results revealed that the steady-state CO conversion for the case using the static mixer was approximately 3.5 times higher than that of the case without static mixer.In both cases,the values of chain growth probability of hydrocarbon products (α) for Fischer-Tropsch synthesis were 0.92 and 0.89 for

  14. Biodegradation of pharmaceuticals in hospital wastewater by staged Moving Bed Biofilm Reactors (MBBR)

    DEFF Research Database (Denmark)

    Escola Casas, Monica; Chhetri, Ravi Kumar; Ooi, Gordon Tze Hoong;

    2015-01-01

    Hospital wastewater contributes a significant input of pharmaceuticals into municipal wastewater. The combination of suspended activated sludge and biofilm processes, as stand-alone or as hybrid process (hybrid biofilm and activated sludge system (Hybas™)) has been suggested as a possible solution...... for hospital wastewater treatment. To investigate the potential of such a hybrid system for the removal of pharmaceuticals in hospital wastewater a pilot plant consisting of a series of one activated sludge reactor, two Hybas™ reactors and one moving bed biofilm reactor (MBBR) has been established and...

  15. Magnetically stabilized bed reactor for selective hydrogenation of olefins in reformate with amorphous nickel alloy catalyst

    Institute of Scientific and Technical Information of China (English)

    Xuhong; Mu; Enze; Min

    2007-01-01

    A magnetically stabilized bed (MSB) reactor for selective hydrogenation of olefins in reformate was developed by combining the advantages of MSB and amorphous nickel alloy catalyst. The effects of operating conditions, such as temperature, pressure, liquid space velocity, hydrogen-to-oil ratio, and magnetic field intensity on the reaction were studied. A mathematical model of MSB reactor for hydrogenation of olefins in reformate was established. A reforming flow scheme with a post-hydrogenation MSB reactor was proposed. Finally, MSB hydrogenation was compared with clay treatment and conventional post-hydrogenation.

  16. Breakthrough of toluene vapours in granular activated carbon filled packed bed reactor

    International Nuclear Information System (INIS)

    The objective of this research was to determine the toluene removal efficiency and breakthrough time using commercially available coconut shell-based granular activated carbon in packed bed reactor. To study the effect of toluene removal and break point time of the granular activated carbon (GAC), the parameters studied were bed lengths (2, 3, and 4 cm), concentrations (5, 10, and 15 mg l-1) and flow rates (20, 40, and 60 ml/min). The maximum percentage removal of 90% was achieved and the maximum carbon capacity for 5 mg l-1 of toluene, 60 ml/min flow rate and 3 cm bed length shows 607.14 mg/g. The results of dynamic adsorption in a packed bed were consistent with those of equilibrium adsorption by gravimetric method. The breakthrough time and quantity shows that GAC with appropriate surface area can be utilized for air cleaning filters. The result shows that the physisorption plays main role in toluene removal.

  17. The importance of the AVR pebble-bed reactor for the future of nuclear power

    Energy Technology Data Exchange (ETDEWEB)

    Pohl, P. [Arbeitsgemeinschaft Versuchsreaktor AVR GmbH, Postfach 1160, 52412 Juelich (Germany)

    2006-07-01

    The AVR pebble-bed high temperature gas-cooled reactor (HTGR) at Juelich (Germany)) operated from 1967 to 1988 and was certainly the most important HTGR project of the past. The reactor was the mass test bed for all development steps of HTGR pebble fuel. Some early fuel charges failed under high temperature conditions and contaminated the reactor. An accurate pebble measurement (Cs 137) allowed to clean the core from unwanted pebbles after 1981. The coolant activity went down and remained very low for the remaining reactor operation. A melt-wire experiment in 1986 revealed max. coolant temperatures of >1280 deg. C and fuel temperatures of >1350 deg. C, explained by under-estimated bypasses. The fuel still in the core achieved high burn-ups and showed under the extreme temperature conditions excellent fission product retention. Thus, the AVR operation qualified the HTGR fuel, and an average discharge burn-up of 112% fifa revealed an excellent fuel economy of the pebble-bed reactor. Furthermore, the AVR operation offers many meaningful data for code-to-experiment comparisons. (authors)

  18. Chromate reduction by Arthrobacter CR47 in biofilm packed bed reactors

    International Nuclear Information System (INIS)

    Bacterial strain Cr47 was isolated from a landfarming process soil sample. It was identified, by 16s rDNA sequencing, as Arthrobacter sp. The time course of the Cr(VI) reduction was monitored in batch operated packed bed biofilm reactors (12mL void volume) and in recirculating packed bed biofilm reactors (100 mL void volume) inoculated with bacterial strain Cr47. The reduction was evaluated with, 30 mg L-1 Cr(VI) laboratory solutions prepared with K2Cr2O7 and enriched with glucose-minimal medium, and with 30 mg L-1 Cr(VI) industrial model solutions prepared with chrome plating waste waters enriched with sucrose-minimal medium. Under batch mode the reduction reaction by the biofilm seemed to fit well an exponential-decay model with a first order kinetic parameter of 0.071 mg(L h)-1 Cr(VI). In the recirculating reactor, monitored after 4 weeks from inoculation and fed with laboratory solutions the removal rate was 0.79 mg(L h)-1. In the reactor fed with the industrial model solutions the maximum Cr(VI) removal rate attained was 0.49 mg(L h)-1. Artrobacter sp. packed bed biofilm reactors achieved Cr(VI) reduction rates comparable to other aerobic and anaerobic fixed film bioreactors previously reported

  19. Development of research reactor simulator and its application to dynamic test-bed

    International Nuclear Information System (INIS)

    We developed a real-time simulator for 'High-flux Advanced Neutron Application ReactOr (HANARO), and the Jordan Research and Training Reactor (JRTR). The main purpose of this simulator is operator training, but we modified this simulator into a dynamic test-bed (DTB) to test the functions and dynamic control performance of reactor regulating system (RRS) in HANARO or JRTR before installation. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The software includes a mathematical model that implements plant dynamics in real-time, an instructor station module that manages user instructions, and a human machine interface module. The developed research reactor simulators are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by actual RRS cabinet, and was interfaced using a hard-wired and network-based interface. RRS cabinet generates control signals for reactor power control based on the various feedback signals from DTB, and the DTB runs plant dynamics based on the RRS control signals. Thus the Hardware-In-the-Loop Simulation between RRS and the emulated plant (DTB) has been implemented and tested in this configuration. The test result shows that the developed DTB and actual RRS cabinet works together simultaneously resulting in quite good dynamic control performances. (author)

  20. Fluidized-bed atomic layer deposition reactor for the synthesis of core-shell nanoparticles

    International Nuclear Information System (INIS)

    The design of a fluidized bed atomic layer deposition (ALD) reactor is described in detail. The reactor consists of three parts that have all been placed in one protective cabinet: precursor dosing, reactor, and residual gas treatment section. In the precursor dosing section, the chemicals needed for the ALD reaction are injected into the carrier gas using different methods for different precursors. The reactor section is designed in such a way that a homogeneous fluidized bed can be obtained with a constant, actively controlled, reactor pressure. Furthermore, no filters are required inside the reactor chamber, minimizing the risk of pressure increase due to fouling. The residual gas treatment section consists of a decomposition furnace to remove residual precursor and a particle filter and is installed to protect the pump. In order to demonstrate the performance of the reactor, SiO2 particles have been coated with TiO2 using tetrakis-dimethylamino titanium (TDMAT) and H2O as precursors. Experiments with varying pulse times show that saturated growth can be obtained with TDMAT pulse times larger than 600 s. Analysis of the powder with High-Angle Annular Dark-Field Scanning Transmission Electron Microscopy (HAADF-STEM) and energy dispersive X-ray spectroscopy confirmed that after 50 cycles, all SiO2 particles were coated with a 1.6 nm homogenous shell of TiO2

  1. Fluidized-bed and fixed-bed reactor testing of methane chemical looping combustion with MgO-promoted hematite

    International Nuclear Information System (INIS)

    Highlights: • Mg-promoted hematite showed better performance than hematite for methane CLC. • Stable reaction performance was observed during cyclic CH4 CLC fluidized bed tests. • Attrition resistance was better than that with standard FCC catalysts. • 5 wt% MgO increased both the oxygen capacity and reaction rates for CH4 CLC. • Possible mechanisms for the CH4 CLC OC performance enhancement are presented. - Abstract: In this study MgO-promoted Fe2O3 hematite oxygen carriers were synthesized from various Mg sources and evaluated for methane chemical looping combustion. Particles suitable for fluidized bed flow reactor studies were prepared in the lab. Cyclic CLC tests conducted in the fluidized bed with MgO promoted hematite showed better performance than that with hematite. Attrition resistance of laboratory prepared MgO promoted hematite was excellent. Reactivity and stability of the oxygen carrier materials were also tested in the thermogravimetric analyzer and bench-scale reactors. Scanning electron microscopy and energy-dispersive X-ray spectroscopy, and X-ray diffraction were used to study the morphology and elemental compositions present in the hematite and promoted hematite oxygen carriers prior to and following the multi-cycle chemical looping reaction. The incorporation of 5 wt% MgO led to an increased reaction rate and an increase in oxygen utilized as compared to the pure hematite oxygen carrier. Possible reasons for the promotion effect by MgO were evaluated. These studies reveal that the best performing oxygen carrier was the 5 wt% MgO/Fe2O3 which exhibited no observed degradation in the kinetics and conversion performance in the methane step over 15 reduction and oxidation cycles. The Mg promoted oxygen carrier also showed reduced coke formation as compared to the pure hematite carrier

  2. Rotary Bed Reactor for Chemical-Looping Combustion with Carbon Capture. Part 1: Reactor Design and Model Development

    KAUST Repository

    Zhao, Zhenlong

    2013-01-17

    Chemical-looping combustion (CLC) is a novel and promising technology for power generation with inherent CO2 capture. Currently, almost all of the research has been focused on developing CLC-based interconnected fluidized-bed reactors. In this two-part series, a new rotary reactor concept for gas-fueled CLC is proposed and analyzed. In part 1, the detailed configuration of the rotary reactor is described. In the reactor, a solid wheel rotates between the fuel and air streams at the reactor inlet and exit. Two purging sectors are used to avoid the mixing between the fuel stream and the air stream. The rotary wheel consists of a large number of channels with copper oxide coated on the inner surface of the channels. The support material is boron nitride, which has high specific heat and thermal conductivity. Gas flows through the reactor at elevated pressure, and it is heated to a high temperature by fuel combustion. Typical design parameters for a thermal capacity of 1 MW have been proposed, and a simplified model is developed to predict the performances of the reactor. The potential drawbacks of the rotary reactor are also discussed. © 2012 American Chemical Society.

  3. Mathematical simulation of hazardous ion retention from radioactive waste in fixed bed reactor

    International Nuclear Information System (INIS)

    Reactor design for fluid-solid, noncatalytic reaction depends on the prediction of the performance of the reactor kinetically. The most mathematical models used to handle fixed bed reactor in which the solid bed constitute one of the reactants, while a second reactant is in the fluid phase are complex and difficult to handle. A new mathematical model which easier to handle has been developed to describe the system under investigation. The model was examined theoretically and experimentally. A column backed with chelating cloth filter to separate radionuclide form radioactive waste solution is used as a practical application for the model. Comparison of the model predictions with the experimental results gives satisfactory agreement at most of the process stages

  4. Development of an Internally Circulating Fluidized Bed Membrane Reactor for Hydrogen Production from Natural Gas

    Institute of Scientific and Technical Information of China (English)

    XIE Dong-lai; GRACE John R; LIM C Jim

    2006-01-01

    An innovative Internally Circulating Fluidized Bed Membrane Reactor (ICFBMR) was designed and operated for ultra-pure hydrogen production from natural gas. The reactor includes internal catalyst solids circulation for conveying heat between a reforming zone and an oxidation zone. In the reforming zone, catalyst particles are transported upwards by reactant gas where steam reforming reactions are taking place and hydrogen is permeating through the membrane surfaces. Air is injected into the oxidation zone to generate heat which is carried by catalyst particles to the reforming zone supporting the endothermic steam reforming reaction. The technology development process is introduced: cold model test,pilot plant and industrial demonstration unit. The process flow diagram and key components of each unit are described.The ICFBMR process has the potential to provide improved performance relative to conventional SMR fixed-bed tubular reactors.

  5. Improved performance of parallel surface/packed-bed discharge reactor for indoor VOCs decomposition: optimization of the reactor structure

    Science.gov (United States)

    Jiang, Nan; Hui, Chun-Xue; Li, Jie; Lu, Na; Shang, Ke-Feng; Wu, Yan; Mizuno, Akira

    2015-10-01

    The purpose of this paper is to develop a high-efficiency air-cleaning system for volatile organic compounds (VOCs) existing in the workshop of a chemical factory. A novel parallel surface/packed-bed discharge (PSPBD) reactor, which utilized a combination of surface discharge (SD) plasma with packed-bed discharge (PBD) plasma, was designed and employed for VOCs removal in a closed vessel. In order to optimize the structure of the PSPBD reactor, the discharge characteristic, benzene removal efficiency, and energy yield were compared for different discharge lengths, quartz tube diameters, shapes of external high-voltage electrode, packed-bed discharge gaps, and packing pellet sizes, respectively. In the circulation test, 52.8% of benzene was removed and the energy yield achieved 0.79 mg kJ-1 after a 210 min discharge treatment in the PSPBD reactor, which was 10.3% and 0.18 mg kJ-1 higher, respectively, than in the SD reactor, 21.8% and 0.34 mg kJ-1 higher, respectively, than in the PBD reactor at 53 J l-1. The improved performance in benzene removal and energy yield can be attributed to the plasma chemistry effect of the sequential processing in the PSPBD reactor. The VOCs mineralization and organic intermediates generated during discharge treatment were followed by CO x selectivity and FT-IR analyses. The experimental results indicate that the PSPBD plasma process is an effective and energy-efficient approach for VOCs removal in an indoor environment.

  6. Treatment of domestic wastewater in an up-flow anaerobic sludge blanket reactor followed by moving bed biofilm reactor

    OpenAIRE

    Tawfik, A.; El-Gohary, F.; Temmink, B.G.

    2010-01-01

    The performance of a laboratory-scale sewage treatment system composed of an up-flow anaerobic sludge blanket (UASB) reactor and a moving bed biofilm reactor (MBBR) at a temperature of (22-35 A degrees C) was evaluated. The entire treatment system was operated at different hydraulic retention times (HRT's) of 13.3, 10 and 5.0 h. An overall reduction of 80-86% for CODtotal; 51-73% for CODcolloidal and 20-55% for CODsoluble was found at a total HRT of 5-10 h, respectively. By prolonging the HRT...

  7. Tests of candidate materials for particle bed reactors

    International Nuclear Information System (INIS)

    Rhenium metal hot frits and zirconium carbide-coated fuel particles appear suitable for use in flowing hydrogen to at least 2000 K, based on previous tests. Recent tests on alternate candidate cooled particle and frit materials are described. Silicon carbide-coated particles began to react with rhenium frit material at 1600 K, forming a molten silicide at 2000 K. Silicon carbide was extensively attacked by hydrogen at 2066 K for 30 minutes, losing 3.25% of its weight. Vitrous carbon was also rapidly attacked by hydrogen at 2123 K, losing 10% of its weight in two minutes. Long term material tests on candidate materials for closed cycle helium cooled particle bed fuel elements are also described. Surface imperfections were found on the surface of pyrocarbon-coated fuel particles after ninety days exposure to flowing (∼500 ppM) impure helium at 1143 K. The imperfections were superficial and did not affect particle strength

  8. Cleaning of porous filters in fossilized bed reactors; Estudio de limpieza de filtros porosos en reactores de lecho fluidizado

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigo Otero, A.; Sancho Rod, J.

    1965-07-01

    In this report are established the optimum working conditions of a filter cleaning system by blow back. For this purpose it was determined in the first place the blow back air rate necessary to have a good cleaning. The reasons for which it was not possible until now to control the pressure in a fluidized bed calcination reactor are analyzed and a criteria is established to calculate the optimum floe necessary to clean efficiently a porous by this procedures. (Author)

  9. Comparison of waste water treatment between completely mixed and fluidised bed reactor; development and structure of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Toman, M.; Mejac, B.

    1988-08-01

    The aerobic biological treatment of waste water from production of semisynthetic antibiotics in a completely mixed reactor and in a fluidised bed reactor was studied. The formation and development of new biomass on the sand of a fluidised bed was observed, so that differences in the structure of organisms of the concomitant biocenosis could be detected. In a fluidised bed reactor the same quality of treatednwater was gained on account of a 4-5 times higher volumetric and hydraulic loading as it was the case with a conventional activated sludge plant. The biocenosis of the fluidised bed was abundant in individua and species. The biofilm of the sand depended on substrate degradation rate as well as on rubbing among the sand particles. An optimal biofilm developed on the sand of a fluidised bed reactor 10 to 15 days after the experiment had began, and that condition remained unchanged as the experiment continued.

  10. CORE ANALYSIS, DESIGN AND OPTIMIZATION OF A DEEP-BURN PEBBLE BED REACTOR

    Energy Technology Data Exchange (ETDEWEB)

    B. Boer; A. M. Ougouag

    2010-05-01

    Achieving a high burnup in the Deep-Burn pebble bed reactor design, while remaining within the limits for fuel temperature, power peaking and temperature reactivity feedback, is challenging. The high content of Pu and Minor Actinides in the Deep-Burn fuel significantly impacts the thermal neutron energy spectrum. This can result in power and temperature peaking in the pebble bed core in locally thermalized regions near the graphite reflectors. Furthermore, the interplay of the Pu resonances of the neutron absorption cross sections at low-lying energies can lead to a positive temperature reactivity coefficient for the graphite moderator at certain operating conditions. To investigate the aforementioned effects a code system using existing codes has been developed for neutronic, thermal-hydraulic and fuel depletion analysis of Deep-Burn pebble bed reactors. A core analysis of a Deep-Burn Pebble Bed Modular Reactor (400 MWth) design has been performed for two Deep-Burn fuel types and possible improvements of the design with regard to power peaking and temperature reactivity feedback are identified.

  11. Sludge Bed Granules’ Growth in the HUASB Reactor Treating High Strength Industrial Wastewater

    Directory of Open Access Journals (Sweden)

    Sinan Abood Habeeb

    2014-12-01

    Full Text Available The development of anaerobic sludge granules in a hybrid up-flow anaerobic sludge bed (HUASB reactor in terms of granular size and solids content was observed. After appropriate pre-treatment of the palm oil mill effluent (POME, it was continuously fed to the HUASB reactor under room temperature condition (27°C.  Particle size analysis and solids content examination were conducted for 196 days. A volatile solid ratio was ranging from 0.36 to 0.51 which was quite low, and granules particle size of less than 1 mm diameter was reported during the operating period. Results obtained in this study indicated that sludge bed development based on the sludge particle size distribution and the volatile solid ratio, was quite slow due to the bulk solids that entering the reactor resulting in certain inhibition of the anaerobes’ activity. It has been concluded that anaerobic wastewater treatment process in anaerobic reactors such as the HUASB reactor, can be significantly affected by the organic loading rate, hydraulic retention time applied to the reactor and the wastewater characteristics.

  12. Synthesis gas and zinc production in a noncatalytic packed-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Ebrahimi, A.A.; Ebrahim, H.A.; Jamshidi, E.; Faramarzi, A.H. [Department of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran (Iran, Islamic Republic of)

    2010-12-15

    A noncatalytic packed-bed reactor has been constructed for management of the reduction of ZnO by methane, which leads to co-production of synthesis gas and zinc. The reactor consisted of a simple vertical pipe filled with ZnO pellets. These pellets underwent reaction with a pure methane flow. Experimental tests were conducted in the temperature range 860-995 C at atmospheric pressure in an electrically heated reactor. The results showed complete chemical conversion of methane to synthesis gas in the aforementioned temperature range. In addition, analysis of the product solids indicated that the collected solids in the outlet of the reactor were entirely zinc. The maximum methane flow rates (149-744 mL min{sup -1}) were adjusted to ensure complete chemical conversion of methane. These adjustments were performed for different bed heights at various operating temperatures. Analysis of the product gases revealed high quality synthesis gas production without the influence of methane cracking or other undesired side reactions in the experimental tests. Finally, the governing partial differential equations of the reactor modeling were solved by the finite element method. Consequently, the gaseous profiles along the reactor and the breakthrough curves were predicted and compared with the experimental tests. (Copyright copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  13. Experimental and computational investigation of flow of pebbles in a pebble bed nuclear reactor

    Science.gov (United States)

    Khane, Vaibhav B.

    The Pebble Bed Reactor (PBR) is a 4th generation nuclear reactor which is conceptually similar to moving bed reactors used in the chemical and petrochemical industries. In a PBR core, nuclear fuel in the form of pebbles moves slowly under the influence of gravity. Due to the dynamic nature of the core, a thorough understanding about slow and dense granular flow of pebbles is required from both a reactor safety and performance evaluation point of view. In this dissertation, a new integrated experimental and computational study of granular flow in a PBR has been performed. Continuous pebble re-circulation experimental set-up, mimicking flow of pebbles in a PBR, is designed and developed. Experimental investigation of the flow of pebbles in a mimicked test reactor was carried out for the first time using non-invasive radioactive particle tracking (RPT) and residence time distribution (RTD) techniques to measure the pebble trajectory, velocity, overall/zonal residence times, flow patterns etc. The tracer trajectory length and overall/zonal residence time is found to increase with change in pebble's initial seeding position from the center towards the wall of the test reactor. Overall and zonal average velocities of pebbles are found to decrease from the center towards the wall. Discrete element method (DEM) based simulations of test reactor geometry were also carried out using commercial code EDEM(TM) and simulation results were validated using the obtained benchmark experimental data. In addition, EDEM(TM) based parametric sensitivity study of interaction properties was carried out which suggests that static friction characteristics play an important role from a packed/pebble beds structural characterization point of view. To make the RPT technique viable for practical applications and to enhance its accuracy, a novel and dynamic technique for RPT calibration was designed and developed. Preliminary feasibility results suggest that it can be implemented as a non

  14. Effect of non-uniform porosity distribution on thermalhydraulics in a pebble bed reactor

    International Nuclear Information System (INIS)

    In pebble bed reactors, the porosity profile shows strong fluctuations near the wall. These changes in fuel density affect local power density, coolant velocity, and temperature distribution. This paper describes the pebFoam code, capable of calculating pebble bed thermohydraulics including non-uniform porosity distributions for arbitrary geometries, and investigates the changes in velocity, pressure drop, and helium and pebble temperatures when using a nonuniform porosity distribution instead of a uniform distribution. Results show only minor changes in temperature profiles and pressure drop for full power steady state calculations, though the velocity profile shows a clear increase in velocity near the wall. (author)

  15. Optimization of OTTO Fuel Management in Pebble-Bed Reactors Using Particle Swarm Algorithm

    International Nuclear Information System (INIS)

    Pebble-Bed nuclear reactors feature highly flexible in-core fuel management capabilities due to on-line fueling and thermo-mechanical robust fuel design. Fuel pebbles with various fissile and fertile materials can be loaded into the reactor core at different rates. The fuel pebbles may be recirculated in the core several times until reaching their target burnup, or reach their target burnup in single pass through the core (OTTO- Once-Through-Then-Out fueling Scheme). Pebble-bed reactors have relatively efficient neutron economy since they operate with low excess reactivity and hence minimize the use of neutron poisons and control rods. Moreover, the fuel pebble robust design permits high burnup levels (up to 140000 MWD/THM). The flexibility of the fuel management operations allows enhancing fuel utilization. Traditionally fuel cycle design decisions were made using expert opinions and parametric studies. In this work, we have used the Particle Swarm Optimization (PSO) algorithm to optimize fuel utilization of pebble-bed reactors running OTTO fuel management. Optimization was carried out also for cores with Th232 as fertile material. Preliminary calculations were performed for a large core with 2 radial fuel loading zones. Results of the optimal fuel utilization performed for cores with UO2 fuel and cores with (Th- U)O2. Future work will include optimization of cores fuelled with separate seed (U) and blanket (Th) fuel pebbles and with advanced modular core configuration, like the PBMR400

  16. Effect of wall structure on pebble stagnation behavior in pebble bed reactor

    International Nuclear Information System (INIS)

    Highlights: • DEM study of wall structure role in preventing near wall crystallization is carried out. • Suggestions on pebble’s kinematic parameters and wall structure design are provided. • Triangle is better than arc and sawtooth shapes for wall structure design. • Wall structure size should be close to the scale of pebble diameter. • Suitable intervals can prevent crystallization without significantly increasing the flow resistance. - Abstract: Crystallization of pebbles in pebble bed is a crucial problem in high temperature gas-cooled pebble-bed reactors. This phenomenon usually happens along the internal surface and leads to a large number of stagnated pebbles, which poses a threat to reactor safety. In real reactor engineering, wall structures have been utilized to avoid this problem. This article verifies the crystallization phenomenon through DEM (discrete element method) simulation, and explains how wall structures work in preventing crystallization. Moreover, several kinematic parameters have been adopted to evaluate wall structures with different shapes, sizes and intervals. Detailed information shows the impact of wall structure on flow field in pebble bed. Lastly, the preferred characteristics of an effective wall structure are suggested for reactor engineering

  17. Heat-transfer characteristics of flowing and stationary particle-bed-type fusion-reactor blankets

    International Nuclear Information System (INIS)

    The heat-transfer characteristics of flowing and stationary packed-particle beds have recently become of interest in connection with conceptual designs of fusion reactor blankets. A detailed literature survey has shown that the processes taking place in such beds are not fully understood despite their widespread use in the chemical industry and other engineering disciplines for more than five decades. In this study, two experimental investigations were pursued. In the first, a heat-transfer loop was constructed through which glass microspheres were allowed to flow by rgravity at controlled rates through an electrically heated stainless steel tubular test section. In the second, an annular packed bed was constructed in which heat was applied through the outer wall by electric heating of a stainless steel tube. Cooling occurred at the inner wall of the annular bed by flowing air through the central tube. A second air stream was allowed to flow through the voids of the packed bed. An error-minimization technique was utilized in order to obtain the two-dimensional one-parameter effective conductivity for the bed by comparing the experimental and theoretically predicted temperature profiles. Experiments were conducted for various modified Reynolds numbers less than ten

  18. Heat-transfer characteristics of flowing and stationary particle-bed-type fusion-reactor blankets

    Energy Technology Data Exchange (ETDEWEB)

    Nietert, R.E.

    1983-02-01

    The heat-transfer characteristics of flowing and stationary packed-particle beds have recently become of interest in connection with conceptual designs of fusion reactor blankets. A detailed literature survey has shown that the processes taking place in such beds are not fully understood despite their widespread use in the chemical industry and other engineering disciplines for more than five decades. In this study, two experimental investigations were pursued. In the first, a heat-transfer loop was constructed through which glass microspheres were allowed to flow by rgravity at controlled rates through an electrically heated stainless steel tubular test section. In the second, an annular packed bed was constructed in which heat was applied through the outer wall by electric heating of a stainless steel tube. Cooling occurred at the inner wall of the annular bed by flowing air through the central tube. A second air stream was allowed to flow through the voids of the packed bed. An error-minimization technique was utilized in order to obtain the two-dimensional one-parameter effective conductivity for the bed by comparing the experimental and theoretically predicted temperature profiles. Experiments were conducted for various modified Reynolds numbers less than ten.

  19. Pebble Bed Reactors Design Optimization Methods and their Application to the Pebble Bed Fluoride Salt Cooled High Temperature Reactor (PB-FHR)

    Science.gov (United States)

    Cisneros, Anselmo Tomas, Jr.

    The Fluoride salt cooled High temperature Reactor (FHR) is a class of advanced nuclear reactors that combine the robust coated particle fuel form from high temperature gas cooled reactors, direct reactor auxillary cooling system (DRACS) passive decay removal of liquid metal fast reactors, and the transparent, high volumetric heat capacitance liquid fluoride salt working fluids---flibe (33%7Li2F-67%BeF)---from molten salt reactors. This combination of fuel and coolant enables FHRs to operate in a high-temperature low-pressure design space that has beneficial safety and economic implications. In 2012, UC Berkeley was charged with developing a pre-conceptual design of a commercial prototype FHR---the Pebble Bed- Fluoride Salt Cooled High Temperature Reactor (PB-FHR)---as part of the Nuclear Energy University Programs' (NEUP) integrated research project. The Mark 1 design of the PB-FHR (Mk1 PB-FHR) is 236 MWt flibe cooled pebble bed nuclear heat source that drives an open-air Brayton combine-cycle power conversion system. The PB-FHR's pebble bed consists of a 19.8% enriched uranium fuel core surrounded by an inert graphite pebble reflector that shields the outer solid graphite reflector, core barrel and reactor vessel. The fuel reaches an average burnup of 178000 MWt-d/MT. The Mk1 PB-FHR exhibits strong negative temperature reactivity feedback from the fuel, graphite moderator and the flibe coolant but a small positive temperature reactivity feedback of the inner reflector and from the outer graphite pebble reflector. A novel neutronics and depletion methodology---the multiple burnup state methodology was developed for an accurate and efficient search for the equilibrium composition of an arbitrary continuously refueled pebble bed reactor core. The Burnup Equilibrium Analysis Utility (BEAU) computer program was developed to implement this methodology. BEAU was successfully benchmarked against published results generated with existing equilibrium depletion codes VSOP

  20. Pressurizing Behavior on Ingress of Coolant into Pebble Bed of Blanket of Fusion DEMO Reactor

    International Nuclear Information System (INIS)

    Solid breeder blankets are being developed as candidate blankets for the Fusion DEMO reactor in Japan. JAEA is performing the development of the water cooled and helium cooled solid breeder blankets. The blanket utilizes ceramic breeder pebbles and multiplier pebbles beds cooled by high pressure water or high pressure helium in the cooling tubes placed in the blanket box structure. In the development of the blanket, it is very important to incorporate the safety technology as well as the performance improvement on tritium production and energy conversion. In the safety design and technology, coolant ingress in the blanket box structure is one of the most important events as the initiators. Especially the thermal hydraulics in the pebble bed in the case of the high pressure coolant ingress is very important to evaluate the pressure propagation and coolant flow behavior. This paper presents the preliminary results of the pressure loss characteristics by the coolant ingress in the pebble bed. Experiments have been performed by using alumina pebble bed (4 litter maximum volume of the pebble bed) and nitrogen gas to simulate the helium coolant ingress into breeder and multiplier pebble beds. Reservoir tank of 10 liter is filled with 1.0 MPa nitrogen. The nitrogen gas is released at the bottom part of the alumina pebble bed whose upper part is open to the atmosphere. The pressure change in the pebble bed is measured to identify the pressure loss. The measured values are compared with the predicted values by Ergun's equation, which is the correlation equation on pressure loss of the flow through porous medium. By the results of the experiments with no constraint on the alumina pebble bed, it was clarified that the measured value agreed in the lower flow rate. However, in the higher flow rate where the pressure loss is high, the measured value is about half of the predicted value. The differences between the measured values and the predicted values will be discussed from

  1. CO2 Absorption in a Lab-Scale Fixed Solid Bed Reactor: Modelling and Experimental Tests

    Directory of Open Access Journals (Sweden)

    Roberto Gabbrielli

    2004-09-01

    Full Text Available The CO2 absorption in a lab-scale fixed solid bed reactor filled with different solid sorbents has been studied under different operative conditions regarding temperature (20-200°C and input gas composition (N2, O2, CO2, H2O at 1bar pressure. The gas leaving the reactor has been analysed to measure the CO2 and O2 concentrations and, consequently, to evaluate the overall CO2 removal efficiency. In order to study the influence of solid sorbent type (i.e. CaO, coal bottom ash, limestone and blast furnace slag and of mass and heat transfer processes on CO2 removal efficiency, a one-dimensional time dependent mathematical model of the reactor, which may be considered a Plug Flow Reactor, has been developed. The quality of the model has been confirmed using the experimental results.

  2. Modeling of reaction kinetics in bubbling fluidized bed biomass gasification reactor

    Energy Technology Data Exchange (ETDEWEB)

    Thapa, R.K.; Halvorsen, B.M. [Telemark University College, Kjolnes ring 56, P.O. Box 203, 3901 Porsgrunn (Norway); Pfeifer, C. [University of Natural Resources and Life Sciences, Vienna (Austria)

    2013-07-01

    Bubbling fluidized beds are widely used as biomass gasification reactors as at the biomass gasification plant in Gussing, Austria. The reactor in the plant is a dual circulating bubbling fluidized bed gasification reactor. The plant produces 2MW electricity and 4.5MW heat from the gasification of biomass. Wood chips as biomass and olivine particles as hot bed materials are fluidized with high temperature steam in the reactor. As a result, biomass undergoes endothermic chemical reaction to produce a mixture of combustible gases in addition to some carbon-dioxide (CO2). The combustible gases are mainly hydrogen (H2), carbon monoxide (CO) and methane (CH4). The gas is used to produce electricity and heat via utilization in a gas engine. Alternatively, the gas is further processed for gaseous or liquid fuels, but still on the process of development level. Composition and quality of the gas determine the efficiency of the reactor. A computational model has been developed for the study of reaction kinetics in the gasification rector. The simulation is performed using commercial software Barracuda virtual reactor, VR15. Eulerian-Lagrangian approach in coupling of gas-solid flow has been implemented. Fluid phase is treated with an Eulerian formulation. Discrete phase is treated with a Lagrangian formulation. Particle-particle and particle-wall interactions and inter-phase heat and mass transfer have been taken into account. Series of simulations have been performed to study model prediction of the gas composition. The composition is compared with data from the gasifier at the CHP plant in Güssing, Austria. The model prediction of the composition of gases has good agreements with the result of the operating plant.

  3. Neutronic simulation of a pebble bed reactor considering its double heterogeneous nature

    International Nuclear Information System (INIS)

    Highlights: ► A new model is successfully developed for a pebble bed reactor simulation. ► In the model, the double heterogeneous nature is considered using MCNP5 code. ► The initial and full core criticality, control rod worth, etc. are calculated to validate it. ► Results confirm the capability of Monte Carlo codes in modeling complex geometries. - Abstract: In pebble bed reactors, the core is filled with thousands of graphite and fuel pebbles. Fuel pebbles in these reactors consist of TRISO particles, which are embedded in a graphite matrix stochastically. The reactor core is also stochastically filled with pebbles. These two stochastic geometries comprise the so-called double heterogeneous nature of this type of reactor. In this paper, a pebble bed reactor, the HTR-10, is used to demonstrate a treatment of this double heterogeneity using the MCNP5 Monte Carlo code and MATLAB programming. In this technique, TRISO particles are modeled in a pebble using the expanded FILL and LATTICE features of MCNP5. MATLAB is used to generate random numbers which represent the location of pebbles in the core. Centers of pebbles are generated stochastically and uniformly and then transferred into the MCNP5 input file as the centers of spherical surfaces. In this model, there is no approximation to the actual geometry. In other words, the double heterogeneous nature is preserved while truncating neither the pebbles in the core nor the particles in the pebble matrix. Finally, to validate the model, benchmark problems of IAEA are used. Very good agreement with experimental results is observed.

  4. Development of Research Reactor Simulator and Its Application to Dynamic Test-bed

    Energy Technology Data Exchange (ETDEWEB)

    Kwon, Kee Choon; Park, Jae Chang; Lee, Seung Wook; Bang, Dane; Bae, Sung Won [KAERI, Daejeon (Korea, Republic of)

    2014-08-15

    We developed HANARO and the Jordan Research and Training Reactor (JRTR) real-time simulator for operating staff training. The main purpose of this simulator is operator training, but we modified this simulator as a dynamic test-bed to test the reactor regulating system in HANARO or JRTR before installation. The simulator configuration is divided into hardware and software. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The simulator software is divided into three major parts: a mathematical modeling module, which executes the plant dynamic modeling program in real-time, an instructor station module that manages user instructions, and a human machine interface (HMI) module. The developed research reactors are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by a hardware controller and the simulator and target controller were interfaced with a hard-wired and network-based interface.

  5. Development of Research Reactor Simulator and Its Application to Dynamic Test-bed

    International Nuclear Information System (INIS)

    We developed HANARO and the Jordan Research and Training Reactor (JRTR) real-time simulator for operating staff training. The main purpose of this simulator is operator training, but we modified this simulator as a dynamic test-bed to test the reactor regulating system in HANARO or JRTR before installation. The simulator configuration is divided into hardware and software. The simulator hardware consists of a host computer, 6 operator stations, a network switch, and a large display panel. The simulator software is divided into three major parts: a mathematical modeling module, which executes the plant dynamic modeling program in real-time, an instructor station module that manages user instructions, and a human machine interface (HMI) module. The developed research reactors are installed in the Korea Atomic Energy Research Institute nuclear training center for reactor operator training. To use the simulator as a dynamic test-bed, the reactor regulating system modeling software of the simulator was replaced by a hardware controller and the simulator and target controller were interfaced with a hard-wired and network-based interface

  6. Flow distribution of pebble bed high temperature gas cooled reactors using Large Eddy Simulation

    International Nuclear Information System (INIS)

    The simulation of complex three-dimensional gas flow through the gaps of the spherical fuel elements (fuel pebbles) of Pebble Bed Modulator Reactor is performed. This will help in understanding the highly three-dimensional, complex flow phenomena in pebble bed caused by flow curvature. The flow of this type has distinctive features, which strongly affect the boundary layer behavior. The transition from a laminar to turbulent flow around this curved flow occurs at different Reynolds (Re) numbers. Noncircular curved flows as in the pebble-bed situation need to be investigated. In this study, Large Eddy Simulation (LES) is used in modeling the turbulence to overcome the shortcoming of the Reynolds Average Navier-Stokes approach. (author)

  7. Study on neutron diffusion and time dependence heat ina fluidized bed nuclear reactor

    International Nuclear Information System (INIS)

    The purpose of this work is to model the neutron diffusion and heat transfer for a Fluidized Bed Nuclear Reactor and its solution by Laplace Transform Technique with numerical inversion using Fourier Series. Also Gaussian quadrature and residues techniques were applied for numerical inversion. The neutron transport, diffusion, and point Kinetic equation for this nuclear reactor concept are developed. A matricial and Taylor Series methods are proposed for the solution of the point Kinetic equation which is a time scale problem of Stiff type

  8. Performance of Anammox granular sludge bed reactor started up with nitrifying granular sludge

    Institute of Scientific and Technical Information of China (English)

    ZHENG Ping; LIN Feng-mei; HU Bao-lan; CHEN Jian-song

    2004-01-01

    The anaerobic ammonia oxidation(Anammox) granular sludge bed reactor was started up successfully withnitrifying granular sludge. During the operation, the nitrifying granular sludge was gradually converted into Anammoxgranular sludge with good settling property and high conversion activity. The Anammox reactor worked well with theshortest HRT of 2.43 h. Under the condition that HRT was 6.39 h and influent concentration of ammonia and nitritewas 10 mmol/L, the removal of ammonia and nitrite was 97.17% and 100.00%, respectively. Corresponding

  9. Rotating-bed reactor as a power source for EM gun applications

    International Nuclear Information System (INIS)

    Electromagnetic gun applications of the Rotating Bed Reactor (RBR) are examined. The RBR is a compact (approx. 1 m3), (up to several thousand MW(th)), high-power reactor concept, capable of producing a high-temperature (up to approx. 3000K) gas stream with a MHD generator coupled to it, the RBR can generate electric power (up to approx. 1000 MW(e)) in the pulsed or cw modes. Three EM gun applications are investigated: a rail gun thruster for orbit transfer, a rapid-fire EM gun for point defense, and a direct ground-to-space launch. The RBR appears suitable for all applications

  10. In-core fuel management optimization of a Very High Temperature pebble-bed Reactor

    International Nuclear Information System (INIS)

    A new calculation procedure was developed to reduce the power peak in the core of a Very High Temperature pebble-bed Reactor. The procedure consists in several coupled computational codes, which are used iteratively until convergence is reached. This procedure combines the fuel depletion and the neutronic behavior of the fuel in the reactor core, modeling once-through-then-out cycles as well as cycles in which pebbles are recirculated through the core an arbitrary number of times, obtaining the asymptotic fuel-loading pattern directly, without any intermediate loading pattern. (Author)

  11. Rotating-bed reactor as a power source for EM gun applications

    Energy Technology Data Exchange (ETDEWEB)

    Powell, J.; Botts, T.; Stickley, C.M.; Meth, S.

    1980-01-01

    Electromagnetic gun applications of the Rotating Bed Reactor (RBR) are examined. The RBR is a compact (approx. 1 m/sup 3/), (up to several thousand MW(th)), high-power reactor concept, capable of producing a high-temperature (up to approx. 300/sup 0/K) gas stream with a MHD generator coupled to it, the RBR can generate electric power (up to approx. 1000 MW(e)) in the pulsed or cw modes. Three EM gun applications are investigated: a rail gun thruster for orbit transfer, a rapid-fire EM gun for point defense, and a direct ground-to-space launch. The RBR appears suitable for all applications.

  12. Synthesis of dimethyl carbonate from methyl carbamate and methanol using a Fixed-Bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, D. [Zaozhuang University, College of Chemistry, Chemical Engineering and Materials Science, Zaozhuang (China); Zhang, X. [Zaozhuang University, College of Chemistry, Chemical Engineering and Materials Science, Zaozhuang (China); Chinese Academy of Sciences, Institute of Coal Chemistry, State Key Laboratory of Coal Conversion, Taiyuan (China); Wei, W.; Sun, Y. [Chinese Academy of Sciences, Institute of Coal Chemistry, State Key Laboratory of Coal Conversion, Taiyuan (China)

    2012-12-15

    Several mixed oxide catalysts were prepared by coprecipitation for dimethyl carbonate (DMC) synthesis from methyl carbamate and methanol. During the batch process, the DMC yield was below 35 %. In order to minimize the unfavorable thermodynamic equilibrium and side reactions for the DMC synthesis, a fixed-bed reactor was designed. A maximum DMC yield of {proportional_to} 73 % could be realized over a ZnO-Al{sub 2}O{sub 3} catalyst. The effects of reaction conditions for this type of reactor were investigated in detail. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  13. Modeling of sorption enhanced steam methane reforming in an adiabatic fixed bed reactor

    OpenAIRE

    Fernández García, José Ramón; Abanades García, Juan Carlos; Murillo Villuendas, Ramón

    2012-01-01

    Sorption enhanced methane reforming (SER), employing a CaO-based solid as a high temperature CO2 sorbent, is generally considered to be a promising route for H2 production. In this paper we present a dynamic pseudo-homogeneous model to describe the operation of a packed bed reactor in which the SER reaction is carried out under adiabatic conditions. This reactor can be implemented according to several process schemes, including a novel Ca/Cu looping process for hydrogen generation with inhere...

  14. Microstructure of multicrystalline silicon seeded by polysilicon chips and fluidized bed reactor granules

    Science.gov (United States)

    Ekstrøm, K. E.; Stokkan, G.; Autruffe, A.; Søndenå, R.; Dalaker, H.; Arnberg, L.; Di Sabatino, M.

    2016-05-01

    Multicrystalline silicon displays a considerable smaller average grain size and reduced dislocation generation when being seeded by polycrystalline silicon chips or fluidized bed reactor silicon granules. A simple texture analysis shows how the initially random grain structure of the seeds develops a weak preference for near- and near- oriented grains upwards in the ingot. Closer investigations reveal a considerable coarsening of the initial microstructure of the seeds during the directional solidification process, especially for small fluidized bed reactor granules. The irregular shape of polysilicon chips allows for melt penetration into the seeding structure and potential indentation effects that may account for the increased dislocation generation observed in this case. The increased generation may, however, also be related to a higher ratio of ∑27 grain boundaries.

  15. Autonomous multi-purpose floating power system with a compact static pebble bed reactor

    International Nuclear Information System (INIS)

    The paper introduces a new concept of an autonomous multipurpose system with a compact static-bed pebble bed reactor as a power source. The system is envisioned as a small floating power complex in which a compact high-efficiency nuclear system provides the source of energy for a variety of industrial processes. It offers the near-term (with a conventional power source) and long-term (with a compact high-efficiency nuclear system) technologies for a low cost electricity/potable water supply compared to traditional systems for regions where local communities are isolated and do not have extensive industrial infrastructure and distribution networks. The complex can be quickly installed anywhere following demands and needs of local communities - coastal regions and islands. The reactor design and system layout, balance-of-plant evaluations, performance characteristics and deployment strategies are discussed. (authors)

  16. Regulation of the pebble flow in a pebble-bed reactor

    International Nuclear Information System (INIS)

    The cylindrical core tank of the pebble bed reactor has a funnel-shaped outlet at its bottom end with one single discharge tube. The cylindrical part of the pebble bed has a height-to-diameter ratio of 0.5. In order to achieve an approximately constant vertical velocity of the OTTO program in the Juelich AVR and the Uentrop THTR reactors, respectively, there is a small cone mounted on supports in the outlet. Its tip is pointed upward and its largest diameter has a distance to the wall of the funnel sufficient to accommodate the diameter of the spheres. At high powers the outlet and the cone are built up of graphite blocks. They are equipped with numerous vertical channels for coolant passage. The cone may also be a rotationally symmetrical body with a rhombic longitudinal section which rests upon the outlet on radial bars. (orig./PW)

  17. Drying kinetics characteristic of Indonesia lignite coal (IBC) using lab scale fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Kang, TaeJin; Jeon, DoMan; Namkung, Hueon; Jang, DongHa; Jeon, Youngshin; Kim, Hyungtaek [Ajou Univ., Suwon (Korea, Republic of). Div. of Energy Systems Research

    2013-07-01

    Recent instability of energy market arouse a lot of interest about coal which has a tremendous amount of proven coal reserves worldwide. South Korea hold the second rank by importing 80 million tons of coal in 2007 following by Japan. Among various coals, there is disused coal. It's called Low Rank Coal (LRC). Drying process has to be preceded before being utilized as power plant. In this study, drying kinetics of LRC is induced by using a fixed bed reactor. The drying kinetics was deduced from particle size, the inlet gas temperature, the drying time, the gas velocity, and the L/D ratio. The consideration on Reynold's number was taken for correction of gas velocity, particle size, and the L/D ratio was taken for correction packing height of coal. It can be found that active drying of free water and phase boundary reaction is suitable mechanism through the fixed bed reactor experiments.

  18. Autonomous multi-purpose floating power system with a compact static pebble bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Tsvetkov, Pavel; Vierow, Karen; Peddicord, Kenneth; Ragusa, Jean; McDeavitt, Sean; Poston, John Sr.; Shao, Lin; Willems, Greg [Department of Nuclear Engineering, Texas A and M University, College Station, Texas (United States)

    2008-07-01

    The paper introduces a new concept of an autonomous multipurpose system with a compact static-bed pebble bed reactor as a power source. The system is envisioned as a small floating power complex in which a compact high-efficiency nuclear system provides the source of energy for a variety of industrial processes. It offers the near-term (with a conventional power source) and long-term (with a compact high-efficiency nuclear system) technologies for a low cost electricity/potable water supply compared to traditional systems for regions where local communities are isolated and do not have extensive industrial infrastructure and distribution networks. The complex can be quickly installed anywhere following demands and needs of local communities - coastal regions and islands. The reactor design and system layout, balance-of-plant evaluations, performance characteristics and deployment strategies are discussed. (authors)

  19. Characteristics of convective heat transport in a packed pebble-bed reactor

    International Nuclear Information System (INIS)

    Highlights: • A fast-response heat transfer probe has been developed and used in this work. • Heat transport has been quantified in terms of local heat transfer coefficients. • The method of the electrically heated single sphere in packing has been applied. • The heat transfer coefficient increases from the center to the wall of packed bed. • This work advancing the knowledge of heat transport in the studied packed bed. - Abstract: Obtaining more precise results and a better understanding of the heat transport mechanism in the dynamic core of packed pebble-bed reactors is needed because this mechanism poses extreme challenges to the reliable design and efficient operation of these reactors. This mechanism can be quantified in terms of a solid-to-gas convective heat transfer coefficient. Therefore, in this work, the local convective heat transfer coefficients and their radial profiles were measured experimentally in a separate effect pilot-plant scale and cold-flow experimental setup of 0.3 m in diameter, using a sophisticated noninvasive heat transfer probe of spherical type. The effect of gas velocity on the heat transfer coefficient was investigated over a wide range of Reynolds numbers of practical importance. The experimental investigations of this work include various radial locations along the height of the bed. It was found that an increase in coolant gas flow velocity causes an increase in the heat transfer coefficient and that effect of the gas flow rate varies from laminar to turbulent flow regimes at all radial positions of the studied packed pebble-bed reactor. The results show that the local heat transfer coefficient increases from the bed center to the wall due to the change in the bed structure, and hence, in the flow pattern of the coolant gas. The findings clearly indicate that one value of an overall heat transfer coefficient cannot represent the local heat transfer coefficients within the bed; therefore, correlations are needed to

  20. Ozo-Dyes mixture degradation in a fixed bed biofilm reactor packed with volcanic porous rock

    International Nuclear Information System (INIS)

    Textile industries discharge great amounts of dyes and dyeing-process auxiliaries, which pollute streams and water bodies. Several dyes, especially the ones containing the azo group, can cause harmful effects to different organisms including humans. Through bacterial and mammalian tests, azo dyes or their derived aromatic amines have shown cell genotoxicity. The purpose of this work was to evaluate the effect of air flow rate on azo-dyes mixture biodegradation by a microbial community immobilized in a packed bed reactor. (Author)

  1. Ozo-Dyes mixture degradation in a fixed bed biofilm reactor packed with volcanic porous rock

    Energy Technology Data Exchange (ETDEWEB)

    Contreras-Blancas, E.; Cobos-Vasconcelos, D. de los; Juarez-Ramirez, C.; Poggi-Varaldo, H. M.; Ruiz-Ordaz, N.; Galindez-Mayer, J.

    2009-07-01

    Textile industries discharge great amounts of dyes and dyeing-process auxiliaries, which pollute streams and water bodies. Several dyes, especially the ones containing the azo group, can cause harmful effects to different organisms including humans. Through bacterial and mammalian tests, azo dyes or their derived aromatic amines have shown cell genotoxicity. The purpose of this work was to evaluate the effect of air flow rate on azo-dyes mixture biodegradation by a microbial community immobilized in a packed bed reactor. (Author)

  2. Medium voltage direct current (MVDC) converter for pebble bed modular reactor (PBMR) / Hendrik de Villiers Pretorius

    OpenAIRE

    Pretorius, Hendrik de Villiers

    2004-01-01

    Nuclear and renewable energy systems will probably be used more and more extensively in future due to high environmental demands regarding pollution and exhaustion of the world's gas and coal reserves. Because most types of renewable energy systems do not supply electric power at line frequency and voltage a converter is used to connect these sources to the existing power system. The Pebble Bed Modular Reactor (PBMR) is a nuclear power plant currently using a 50 Hz synchrono...

  3. Mathematical modeling of municipal solid waste plasma gasification in a fixed-bed melting reactor

    OpenAIRE

    Zhang, Qinglin

    2011-01-01

    The increasing yield of municipal solid waste (MSW) is one of the main by-products of modern society. Among various MSW treatment methods, plasma gasification in a fixed-bed melting reactor (PGM) is a new technology, which may provide an efficient and environmental friendly solution for problems related to MSW disposals. General objectives of this work are to develop mathematical models for the PGM process, and using these models to analyze the characteristics of this new technology. In this ...

  4. Evaluation of Heavy Metal Removal from Wastewater in a Modified Packed Bed Biofilm Reactor

    OpenAIRE

    Shohreh Azizi; Ilunga Kamika; Memory Tekere

    2016-01-01

    For the effective application of a modified packed bed biofilm reactor (PBBR) in wastewater industrial practice, it is essential to distinguish the tolerance of the system for heavy metals removal. The industrial contamination of wastewater from various sources (e.g. Zn, Cu, Cd and Ni) was studied to assess the impacts on a PBBR. This biological system was examined by evaluating the tolerance of different strengths of composite heavy metals at the optimum hydraulic retention time (HRT) of 2 h...

  5. Cleaning of porous filters in fluidized bed reactors. Use of one ejector for various filters

    International Nuclear Information System (INIS)

    Tests to know the efficiency of a porous filters cleaning system by blow-back that uses on ejector for each set of simultaneously cleaned filters were carried out. A Calculation method to obtain the optimum ejector for this system was shown, taking n=2, as optimum number of working for the fluidized bed reactors belonging to the Pilot plant of the Materials Division at JEN. That is two filters for each ejector. (Author)

  6. Performance assessment of a packed bed microstructured reactor - heat exchanger for methanol synthesis from syngas

    OpenAIRE

    Bakhtiary-Davijany, Hamidreza

    2010-01-01

    About 25% of the world’s proven natural gas reserves are located offshore with no present economic feasibility to be produced, shipped and sold. Utilization of these resources calls for developing new technologies, which enable conversion of “remote natural gas” to transportable fuels and chemicals at lower production capacities. On this context, investigation of compact methanol synthesis from synthesis gas over Cu based catalysts in a multi-slit Integrated Micro Packed Bed Reactor-Heat Exch...

  7. Operation of a steam hydro-gasifier in a fluidized bed reactor

    OpenAIRE

    Park, Chan Seung; Norbeck, Joseph N.

    2008-01-01

    Carbonaceous material, which can comprise municipal waste, biomass, wood, coal, or a natural or synthetic polymer, is converted to a stream of methane and carbon monoxide rich gas by heating the carbonaceous material in a fluidized bed reactor using hydrogen, as fluidizing medium, and using steam, under reducing conditions at a temperature and pressure sufficient to generate a stream of methane and carbon monoxide rich gas but at a temperature low enough and/or at a pressure high enough to en...

  8. CFD Model of HDS Catalyst Tests in Trickle-Bed Reactor

    Czech Academy of Sciences Publication Activity Database

    Tukač, V.; Prokešová, A.; Hanika, Jiří; Zbuzek, M.; Kubička, D.

    Prague : Orgit, 2014, s. 85. ISBN 978-80-02-02555-9. [International Congress of Chemical and Process Engineering /21./ - CHISA 2014 and Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction /17./ - PRES 2014. Prague (CZ), 23.08.2014-27.08.2014] Grant ostatní: GA MPO FR-TI3/084 Institutional support: RVO:67985858 Keywords : CFD model solution * reactor bed * catalyst activity tests Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  9. Production of Polygalacturonases by Aspergillus section Nigri Strains in a Fixed Bed Reactor

    OpenAIRE

    Marília Maciel; Cristiane Ottoni; Cledir Santos; Nelson Lima; Keila Moreira; Cristina Souza-Motta

    2013-01-01

    Polygalacturonases (PG) are pectinolytic enzymes that have technological, functional and biological applications in food processing, fruit ripening and plant-fungus interactions, respectively. In the present, study a microtitre plate methodology was used for rapid screening of 61 isolates of fungi from Aspergillus section Nigri to assess production of endo- and exo-PG. Studies of scale-up were carried out in a fixed bed reactor operated under different parameters using the best producer strai...

  10. Nuclear thermal propulsion engine based on particle bed reactor using light water steam as a propellant

    International Nuclear Information System (INIS)

    In this paper the possibility of configuring a water cooled Nuclear Thermal Propulsion (NTP) rocket, based on a Particle Bed Reactor (PBR) is investigated. This rocket will be used to operate on water obtained from near earth objects. The conclusions reached in this paper indicate that it is possible to configure a PBR based NTP rocket to operate on water and meet the mission requirements envisioned for it. No insurmountable technology issues have been identified

  11. Eulerian-Lagrangian simulation of a bubbling fluidized bed reactor: Assessment of drag force correlations

    Directory of Open Access Journals (Sweden)

    Ku Xiao-Ke

    2012-01-01

    Full Text Available An Eulerian-Lagrangian approach is developed within the OpenFOAM framework to investigate the effects of three well-known inter-phase drag force correlations on the fluidization behavior in a bubbling fluidized bed reactor. The results show a strong dependency on the restitution coefficient and the friction coefficient and no occurrence of bubbling and slugging for the ideal-collision case. The mean pressure drops predicted by the three models agree quite well with each other.

  12. Thermal-hydraulics numerical analyses of Pebble Bed Advanced High Temperature Reactor hot channel

    International Nuclear Information System (INIS)

    Background: The thermal hydraulics behavior of the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) hot channel was studied. Purpose: We aim to analyze the thermal-hydraulics behavior of the PB-AHTR, such as pressure drop, temperature distribution of coolant and pebble bed as well as thermal removal capacity in the condition of loss of partial coolant. Methods: We used a modified FLUENT code which was coupled with a local non-equilibrium porous media model by introducing a User Defined Scalar (UDS) in the calculation domain of the reactor core and subjoining different resistance terms (Ergun and KTA) to calculate the temperature of coolant, solid phase of pebble bed and pebble center in the core. Results: Computational results showed that the resistance factor has great influence on pressure drop and velocity distribution, but less impact on the temperature of coolant, solid phase of pebble bed and pebble center. We also confirmed the heat removal capacity of the PB-AHTR in the condition of nominal and loss of partial coolant conditions. Conclusion: The numerical analyses results can provide a useful proposal to optimize the design of PB-AHTR. (authors)

  13. Coupling of RMC and CFX for analysis of Pebble Bed-Advanced High Temperature Reactor core

    International Nuclear Information System (INIS)

    Highlights: ► The CFD code CFX is used for whole pebble bed reactor core calculation. ► The Monte Carlo Code RMC and CFX are used for the coupling of neutronics and T-H. ► Coupled calculations for steady-state problem can reach stable results. ► Increasing the number of neutron histories is effective to improve accuracy. - Abstract: This paper introduces a steady-state coupled calculation method using the Monte Carlo Code RMC (Reactor Monte Carlo) and the Computational Fluid Dynamic (CFD) code CFX for the analysis of a Pebble Bed-Advanced High Temperature Reactor (PB-AHTR) core. The RMC code is used for neutronics calculation while CFX is used for Thermal-Hydraulics (T-H) calculation. The porous media model is used in CFX modeling to simulate the pebble bed structure in PB-AHTR. The CFX model has also been validated against the RELAP5-3D model developed in the previous research. The script language PERL is used as a development tool to manipulate and control the entire coupled calculation. This research gives the conclusion that the steady-state coupled calculation using RMC and CFX is feasible and can obtain stable results within a few iterations. However, due to the statistical errors of Monte Carlo method, the fluctuation of results still occurs. For the purpose of improving the accuracy, the paper applies and discusses two methods, of which increasing the number of neutron histories is an effective method.

  14. Theoretical and experimental studies of fixed-bed coal gasification reactors. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Joseph, B.; Bhattacharya, A.; Salam, L.; Dudukovic, M.P.

    1983-09-01

    A laboratory fixed-bed gasification reactor was designed and built with the objective of collecting operational data for model validation and parameter estimation. The reactor consists of a 4 inch stainless steel tube filled with coal or char. Air and steam is fed at one end of the reactor and the dynamic progress of gasification in the coal or char bed is observed through thermocouples mounted at various radial and axial locations. Product gas compositions are also monitored as a function of time. Results of gasification runs using Wyoming coal are included in this report. In parallel with the experimental study, a two-dimensional model of moving bed gasifiers was developed, coded into a computer program and tested. This model was used to study the laboratory gasifier by setting the coal feed rate equal to zero. The model is based on prior work on steady state and dynamic modeling done at Washington University and published elsewhere in the literature. Comparisons are made between model predictions and experimental results. These are also included in this report. 23 references, 18 figures, 6 tables.

  15. Advanced Core Design And Fuel Management For Pebble-Bed Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Hans D. Gougar; Abderrafi M. Ougouag; William K. Terry

    2004-10-01

    A method for designing and optimizing recirculating pebble-bed reactor cores is presented. At the heart of the method is a new reactor physics computer code, PEBBED, which accurately and efficiently computes the neutronic and material properties of the asymptotic (equilibrium) fuel cycle. This core state is shown to be unique for a given core geometry, power level, discharge burnup, and fuel circulation policy. Fuel circulation in the pebble-bed can be described in terms of a few well?defined parameters and expressed as a recirculation matrix. The implementation of a few heat?transfer relations suitable for high-temperature gas-cooled reactors allows for the rapid estimation of thermal properties critical for safe operation. Thus, modeling and design optimization of a given pebble-bed core can be performed quickly and efficiently via the manipulation of a limited number key parameters. Automation of the optimization process is achieved by manipulation of these parameters using a genetic algorithm. The end result is an economical, passively safe, proliferation-resistant nuclear power plant.

  16. Synthesis of Linear Alkylbenzene in a Novel Liquid-Solid Circulating Moving Bed Reactor

    Institute of Scientific and Technical Information of China (English)

    韩明汉; 徐聪; 崔哲; 金涌

    2004-01-01

    For the alkylation of benzene with long-chain olefins, using Hβ zeolite catalyst as replacement of HF or A1Cl3 has the advantages of no corrosion, less environmental pollution, and much more 2-phenyl isomer, which has the highest biodegradability and solubility, and better detergent properties among the related isomers. The characterization of the coke shows that the deactivation of catalyst is caused by the jam of bulkier molecules, such as naphthalene, indane and linear alkylbenzenes, which are too big to move quickly in the intracrystalline pores of catalyst. The deactivated catalyst can be regenerated by benzene washing at higher temperature. To make the processes of reaction and regeneration continuous, a novel moving bed reactor is developed. Comparing with the processes with fixed bed reactors, the processes in this work have the advantages of continuous operation, low temperature, low pressure, low mole ratio of benzene to olefins, and high weight hourly space velocity.Keywords t3 zeolite, alkylation, linear alkylbenzene, moving bed reactor

  17. Magnesium hydroxide – expanded graphite composite pellets for a packed bed reactor chemical heat pump

    International Nuclear Information System (INIS)

    The chemical heat pump is a promising technology for the recovery of waste heat from industrial processes or cogeneration systems. It can be used for storing the surplus heat during low demand periods and release it for shaving the peaks of heat demand, with a benefit for the overall system efficiency. In this work, a packed bed reactor chemical heat pump based on the dehydration and hydration of magnesium hydroxide has been investigated. Due to its high thermal conductivity, expanded graphite was mixed with magnesium hydroxide to enhance heat transfer. The composite material, named EM, was developed and tested experimentally in order to understand the effects of expanded graphite on the chemical reactions occurring in the packed bed reactor. -- Highlights: • An expanded graphite/Mg(OH)2 composite was developed for a packed bed reactor chemical heat pump. • The expanded graphite/Mg(OH)2 composite (EM) was compressed in figure of pellets. • Higher reaction rates were observed for the dehydration and hydration of EM pellets. • EM pellets showed better performance in terms of heat storage and heat output. • EM pellets were able to withstand repetitive cyclic reactions without significant failures

  18. Treatment of oilfield wastewater in moving bed biofilm reactors using a novel suspended ceramic biocarrier

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Zhiyong, E-mail: bluemanner@163.com [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China); Lu, Mang [School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi Province (China); Huang, Wenhui [School of Energy Resources, China University of Geosciences, Beijing 100083 (China); Xu, Xiaochun [School of Geosciences and Resources, China University of Geosciences, Beijing 100083 (China)

    2011-11-30

    Highlights: Black-Right-Pointing-Pointer We invented a novel suspended ceramic carrier. Black-Right-Pointing-Pointer The suspended ceramic carrier is modified with sepiolite. Black-Right-Pointing-Pointer The carriers were used in MBBR to remediate wastewater. - Abstract: In this study, a novel suspended ceramic carrier was prepared, which has high strength, optimum density (close to water), and high porosity. Two different carriers, unmodified and sepiolite-modified suspended ceramic carriers were used to feed two moving bed biofilm reactors (MBBRs) with a filling fraction of 50% to treat oilfield produced water. The hydraulic retention time (HRT) was varied from 36 to 10 h. The results, during a monitoring period of 190 days, showed that removal efficiency of chemical oxygen demand was the highest in reactor 3 filled with the sepiolite-modified carriers, followed by reactor 2 filled with the unmodified carriers, with the lowest in reactor 1 (activated sludge reactor), at an HRT of 10 h. Similar trends were found in the removal efficiencies of ammonia nitrogen and polycyclic aromatic hydrocarbons. Reactor 3 was more shock resistant than reactors 2 and 1. The results indicate that the suspended ceramic carrier is an excellent MBBR carrier.

  19. Treatment of oilfield wastewater in moving bed biofilm reactors using a novel suspended ceramic biocarrier

    International Nuclear Information System (INIS)

    Highlights: ► We invented a novel suspended ceramic carrier. ► The suspended ceramic carrier is modified with sepiolite. ► The carriers were used in MBBR to remediate wastewater. - Abstract: In this study, a novel suspended ceramic carrier was prepared, which has high strength, optimum density (close to water), and high porosity. Two different carriers, unmodified and sepiolite-modified suspended ceramic carriers were used to feed two moving bed biofilm reactors (MBBRs) with a filling fraction of 50% to treat oilfield produced water. The hydraulic retention time (HRT) was varied from 36 to 10 h. The results, during a monitoring period of 190 days, showed that removal efficiency of chemical oxygen demand was the highest in reactor 3 filled with the sepiolite-modified carriers, followed by reactor 2 filled with the unmodified carriers, with the lowest in reactor 1 (activated sludge reactor), at an HRT of 10 h. Similar trends were found in the removal efficiencies of ammonia nitrogen and polycyclic aromatic hydrocarbons. Reactor 3 was more shock resistant than reactors 2 and 1. The results indicate that the suspended ceramic carrier is an excellent MBBR carrier.

  20. Fluidized bed coupled rotary reactor for nanoparticles coating via atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Chen-Long; Liu, Xiao; Chen, Rong, E-mail: rongchen@mail.hust.edu.cn, E-mail: bshan@mail.hust.edu.cn [State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei 430074 (China); Shan, Bin, E-mail: rongchen@mail.hust.edu.cn, E-mail: bshan@mail.hust.edu.cn [State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan, Hubei 430074 (China)

    2015-07-15

    A fluidized bed coupled rotary reactor has been designed for coating on nanoparticles (NPs) via atomic layer deposition. It consists of five major parts: reaction chamber, dosing and fluidizing section, pumping section, rotary manipulator components, as well as a double-layer cartridge for the storage of particles. In the deposition procedure, continuous fluidization of particles enlarges and homogenizes the void fraction in the particle bed, while rotation enhances the gas-solid interactions to stabilize fluidization. The particle cartridge presented here enables both the fluidization and rotation acting on the particle bed, demonstrated by the analysis of pressure drop. Moreover, enlarged interstitials and intense gas–solid contact under sufficient fluidizing velocity and proper rotation speed facilitate the precursor delivery throughout the particle bed and consequently provide a fast coating process. The cartridge can ensure precursors flowing through the particle bed exclusively to achieve high utilization without static exposure operation. By optimizing superficial gas velocities and rotation speeds, minimum pulse time for complete coating has been shortened in experiment, and in situ mass spectrometry showed the precursor usage can reach 90%. Inductively coupled plasma-optical emission spectroscopy results suggested a saturated growth of nanoscale Al{sub 2}O{sub 3} films on spherical SiO{sub 2} NPs. Finally, the uniformity and composition of the shells were characterized by high angle annular dark field-transmission electron microscopy and energy dispersive X-ray spectroscopy.

  1. Investigation of Multiphase Flow in a Packed Bed Reactor Under Microgravity Conditions

    Science.gov (United States)

    Lian, Yongsheng; Motil, Brian; Rame, Enrique

    2016-01-01

    In this paper we study the two-phase flow phenomena in a packed bed reactor using an integrated experimental and numerical method. The cylindrical bed is filled with uniformly sized spheres. In the experiment water and air are injected into the bed simultaneously. The pressure distribution along the bed will be measured. The numerical simulation is based on a two-phase flow solver which solves the Navier-Stokes equations on Cartesian grids. A novel coupled level set and moment of fluid method is used to construct the interface. A sequential method is used to position spheres in the cylinder. Preliminary experimental results showed that the tested flow rates resulted in pulse flow. The numerical simulation revealed that air bubbles could merge into larger bubbles and also could break up into smaller bubbles to pass through the pores in the bed. Preliminary results showed that flow passed through regions where the porosity is high. Comparison between the experimental and numerical results in terms of pressure distributions at different flow injection rates will be conducted. Comparison of flow phenomena under terrestrial gravity and microgravity will be made.

  2. Fluidized bed coupled rotary reactor for nanoparticles coating via atomic layer deposition

    International Nuclear Information System (INIS)

    A fluidized bed coupled rotary reactor has been designed for coating on nanoparticles (NPs) via atomic layer deposition. It consists of five major parts: reaction chamber, dosing and fluidizing section, pumping section, rotary manipulator components, as well as a double-layer cartridge for the storage of particles. In the deposition procedure, continuous fluidization of particles enlarges and homogenizes the void fraction in the particle bed, while rotation enhances the gas-solid interactions to stabilize fluidization. The particle cartridge presented here enables both the fluidization and rotation acting on the particle bed, demonstrated by the analysis of pressure drop. Moreover, enlarged interstitials and intense gas–solid contact under sufficient fluidizing velocity and proper rotation speed facilitate the precursor delivery throughout the particle bed and consequently provide a fast coating process. The cartridge can ensure precursors flowing through the particle bed exclusively to achieve high utilization without static exposure operation. By optimizing superficial gas velocities and rotation speeds, minimum pulse time for complete coating has been shortened in experiment, and in situ mass spectrometry showed the precursor usage can reach 90%. Inductively coupled plasma-optical emission spectroscopy results suggested a saturated growth of nanoscale Al2O3 films on spherical SiO2 NPs. Finally, the uniformity and composition of the shells were characterized by high angle annular dark field-transmission electron microscopy and energy dispersive X-ray spectroscopy

  3. Methane combustion by moving bed fuel reactor with Fe2O3/Al2O3 oxygen carriers

    International Nuclear Information System (INIS)

    Highlights: • Moving bed reactor employed to methane combustion using iron-based oxygen carrier. • Fe2O3/Al2O3 oxygen carriers was prepared and provided with applicable performance. • Carbon formation was enhanced with increased retention time at 900 °C. • Full CH4 conversion was reached without carbon formation by moving bed operation. • FeO and FeAl2O4 were formed in the reacted oxygen carriers out of the reactor. - Abstract: Fe2O3/Al2O3 composite oxygen carriers were prepared for chemical looping combustion (CLC) with methane in a lab-scale moving bed fuel reactor provided with reasonable crush strength, reactivity and recyclability. Carbon formation was observed during the combustion process in the empty bed at 900 °C through methane decomposition reaction, and was enhanced for experiments conducted with increased retention time. Carbon formation was obviously reduced for experiments conducted in the moving bed fuel reactor with oxygen carrier-to-fuel ratio (ϕ) higher than 1.14. The oxygen carriers that moving out of the moving bed reactor were composed of mainly FeO and FeAl2O4, characterized by X-ray diffraction (XRD) analysis. The formation of FeO and FeAl2O4 indicated that further utilization of oxygen in iron-based oxygen carriers can be achieved by moving bed operation

  4. Experimental and modeling study of sulfur dioxide oxidation in packed-bed tubular reactor

    Directory of Open Access Journals (Sweden)

    Hanen NOURI

    2013-08-01

    Full Text Available The conversion of sulfur dioxide into sulfur trioxide is a reaction which interests not only the industry of sulfuric acid production but also the processes of pollution control of certain gas effluents containing SO2. This exothermic reaction needs a very good control of temperature, that's why it is led in the industry in a multistage converter with intermediate heat exchangers. Microreactors represent a good alternative for such reaction due to their intensification of mass and heat transfer and enhancement of temperature control. In this study, this reaction was conducted in a stainless steel tubular (4mm ID packed bed reactor using particles of vanadium pentoxide as catalyst at atmospheric pressure. Experiments were performed with different inlet SO2 concentration in 3-9% range and reaction temperature between 685-833K. We noticed that the conversion decreases with the amount of SO2 and increases with the temperature until an optimum, above this value the conversion drop according to the shape of the equilibrium curve. Controlling rate mechanism is studied by varying temperature. Pseudohomogeneous perfect plug flow is used to describe this small tubular reactor. Numerical simulations with MATLAB were performed to validate the experimental results. Good agreement between the model predictions and the experimental results is achieved. Fluid flow description inside the packed bed reactor was performed by using the free fluid and porous media flow model. This model was solved by the commercial software COMSOL Multiphysics. Velocity profile inside the reactor is theoretically obtained.

  5. Dynamics and transient stability of a pebble bed reactor during start up

    Energy Technology Data Exchange (ETDEWEB)

    Miles, B.; Pain, C.C.; Eaton, M.D.; Ziver, A.K.; Goddard, A.J.H. [Applied Modelling and Computation Group, Imperial College of Science, Technology and Medicine, Dept. of Earth Science and Engineering, London (United Kingdom); Oliveira, C.R.E. de [Nuclear and Radiological Engineering and Medical Physics Program, The George W Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA (United States)

    2005-07-01

    A design of a modular pebble bed reactor (PBR) is being developed for construction in South Africa. The design of this PBR is simulated in the FETCH nuclear criticality model. FETCH solves the neutron transport equations coupled to fluid dynamics and has been used in simulations of fluidized bed reactors. In the neutronics module of FETCH steady state neutronic calculations are performed to obtain the starting conditions for the subsequent calculation of transient behaviour. These include fuel temperature and control rod position. Neutron flux and the initial surplus reactivity are also calculated. Each step change in a simulated start-up is initiated by an excess reactivity which produces more severe transients than would be encountered in normal operation. The variations of several parameters with time are recorded, for example, temperature at various points in the reactor, temperature of the hottest pebble and fission rate. Spatial profiles are recorded at regular time intervals, including temperatures, power density, gas velocity and gas pressure. The stability of the reactor is demonstrated.

  6. Optimized Core Design and Fuel Management of a Pebble-Bed Type Nuclear Reactor

    International Nuclear Information System (INIS)

    The Very High Temperature Reactor (VHTR) has been selected by the international Generation IV research initiative as one of the six most promising nuclear reactor concepts that are expected to enter service in the second half of the 21st century. The VHTR is characterized by a high plant efficiency and a high fuel discharge burnup level. More specifically, the (pebble-bed type) High Temperature Reactor (HTR) is known for its inherently safe characteristics, coming from a negative temperature reactivity feedback, a low power density and a large thermal inertia of the core. The core of a pebble-bed reactor consists of graphite spheres (pebbles) that form a randomly packed porous bed, which is cooled by high pressure helium. The pebbles contain thousands of fuel particles, which are coated with several pyrocarbon and silicon carbon layers that are designed to contain the fission products that are formed during operation of the reactor. The inherent safety concept has been demonstrated in small pebble-bed reactors in practice, but an increase in the reactor size and power is required for cost-effective power production. An increase of the power density in order to increase the helium coolant outlet temperature is attractive with regard to the efficiency and possible process heat applications. However, this increase leads in general to higher fuel temperatures, which could lead to a consequent increase of the fuel coating failure probability. This thesis deals with the pebble-bed type VHTR that aims at an increased coolant outlet temperature of 1000 degrees C and beyond. For the simulation of the neutronic and thermal-hydraulic behavior of the reactor the DALTON-THERMIX coupled code system has been developed and has been validated against experiments performed in the AVR and HTR-10 reactors. An analysis of the 400 MWth Pebble Bed Modular Reactor (PBMR) design shows that the inherent safety concept that has been demonstrated in practice in the smaller AVR and HTR-10

  7. A Safe Solution to World Energy Supply - the Very High Temperature Pebble Bed Reactor

    International Nuclear Information System (INIS)

    For the energy hungry world there is a solution which has the potential to resolve most of the present energy needs, with almost zero pollution and high thermal efficiency. The Very High Temperature Reactor (VHTR) can produce Hydrogen for automotive needs to replace the polluting gas and oil; it can produce electricity at very high efficiency with almost no pollution, and provide clean process heat for the industry and the energy needed for desalination plants to provide fresh water. In the present study it is shown that choosing the Pebble Bed concept for the VHTR is not only a very effective way to supply all the energy needs, it is also one of the safest nuclear reactor concept. Depending on the fuel cycle chosen, it is possible to reduce significantly the TRU waste normally produced in light water reactors and thus further reduce the environmental concerns of long living FP. A conceptual 600MWt High Temperature Pebble Bed reactor is proposed, and its safety characteristics are analyzed by simulating various hypothetical accidents, using the DSNP simulation system

  8. Conceptual design study of Pebble Bed Type High Temperature Gas-cooled Reactor with annular core structure

    International Nuclear Information System (INIS)

    This report presents the Conceptual Design Study of Pebble Bed Type High Temperature Gas-cooled Reactor with Annular Core Structure. From this study, it is made clear that the thermal power of the Pebble Bed Type Reactor can be increased to 500MW through introducing the annular core structure without losing the inherent safe characteristics (in the coolant depressurization accident, the fuel temperature does not exceed the temperature where the fuel defect begins.) This thermal power is two times higher than the inherent safe Pebble Bed Type High temperature Gas-cooled Reactor (MHTGR) designed in West Germany. From this result, it is foreseen that the ratio of the plant cost to the reactor power is reduced and the economy of the plant operation is improved. The reactor performances e.g. fuel burnup and fuel temperature are maintained in same level of the MHTGR. (author)

  9. Gas Reactor International Cooperative program. Pebble bed reactor plant: screening evaluation. Volume 2. Conceptual balance of plant design

    International Nuclear Information System (INIS)

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW(t) Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. This volume describes the conceptual balance-of-plant (BOP) design and was prepared by United Engineers and Constructors, Inc. of Philadelphia, Pennsylvania. The major emphasis of the BOP study was a preliminary design of an overall plant to provide a basis for future studies

  10. Phenol degradation in an anaerobic fluidized bed reactor packed with low density support materials

    Directory of Open Access Journals (Sweden)

    G. P. Sancinetti

    2012-03-01

    Full Text Available The objective of this research was to study phenol degradation in anaerobic fluidized bed reactors (AFBR packed with polymeric particulate supports (polystyrene - PS, polyethylene terephthalate - PET, and polyvinyl chloride - PVC. The reactors were operated with a hydraulic retention time (HRT of 24 h. The influent phenol concentration in the AFBR varied from 100 to 400 mg L-1, resulting in phenol removal efficiencies of ~100%. The formation of extracellular polymeric substances yielded better results with the PVC particles; however, deformations in these particles proved detrimental to reactor operation. PS was found to be the best support for biomass attachment in an AFBR for phenol removal. The AFBR loaded with PS was operated to analyze the performance and stability for phenol removal at feed concentrations ranging from 50 to 500 mg L-1. The phenol removal efficiency ranged from 90-100%.

  11. Advanced pebble bed high temperature reactor with central graphite column for future applications

    International Nuclear Information System (INIS)

    Design evaluations of the advanced pebble bed high temperature reactor, AHTR, with central graphite column are given. This reactor, as a nuclear heat source, is suitable for coal refinement as well as for electricity generation with closed gas turbine primary helium circuit. With this design of the central graphite column, it is possible to limit the core temperatures under the required value of about 1600deg C in case of accident conditions, even with higher thermal power and higher core inlet and outlet temperatures. The designs of core internals are described. The after heat removal system is integrated in the prestressed concrete reactor pressure vessel, which is based on the principals of natural convection. Research work is being carried out, whereby the sphencal fuel elements are coated with a layer of silicon carbide, to improve the corrosion resistance as well as the effectiveness of the fission products barrier. (orig.)

  12. Las degradation in a fluidized bed reactor and phylogenetic characterization of the biofilm

    Directory of Open Access Journals (Sweden)

    L. L. Oliveira

    2013-09-01

    Full Text Available A fluidized bed reactor was used to study the degradation of the surfactant linear alkylbenzene sulfonate (LAS. The reactor was inoculated with anaerobic sludge and was fed with a synthetic substrate supplemented with LAS in increasing concentrations (8.2 to 45.8 mg l-1. The removal efficiency of 93% was obtained after 270 days of operation. Subsequently, 16S rRNA gene sequencing and phylogenetic analysis of the sample at the last stage of the reactor operation recovered 105 clones belonging to the domain Bacteria. These clones represented a variety of phyla with significant homology to Bacteroidetes (40%, Proteobacteria (42%, Verrucomicrobia (4%, Acidobacteria (3%, Firmicutes (2%, and Gemmatimonadetes (1%. A small fraction of the clones (8% was not related to any phylum. Such phyla variety indicated the role of microbial consortia in degrading the surfactant LAS.

  13. Elimination of weapons grade plutonium via burning in a Particle Bed Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Powell, J.R.; Ludewig, H.; Maise, G.; Todosow, M.

    1993-08-01

    An initial assessment of a concept for burning weapons grade plutonium based on the Particle Bed Reactor (PBR) is described. The high power density/flux level achievable with the PBR make it an attractive candidate for this application. The PBR based plutonium burner concept also possesses a number of safety and economic benefits relative to other reactor based Pu-burner approaches including a safeguards advantages, a low inventory of radionuclides, and high integrity, coated fuel particles which can withstand extremely high temperatures while retaining virtually all fission products. In addition the reactor also possesses a number of ``engineered safety features,`` which, along with the use of high temperature capable materials further enhance its safety characteristics.

  14. Neutronics and thermal-hydraulics analyses of the pellet bed reactor for nuclear thermal propulsion

    Energy Technology Data Exchange (ETDEWEB)

    Morley, N.J.; El-Genk, S. [Univ. of New Mexico, Albuquerque, NM (United States)

    1995-01-01

    Neutronics and thermal-hydraulics design and analyses of the pellet bed reactor for nuclear thermal propulsion are performed based on consideration of reactor criticality, passive decay heat removal, maximum fuel temperature, and subcriticality during a water flooding accident. Besides calculating the dimensions of the reactor core to satisfy the excess reactivity requirement at the beginning-of-mission of 1.25 $ (K{sub eff} of 1.01), the TWODANT discrete ordinates code is used to estimate the radial and axial fission power density profiles in the core. These power profiles are used in the nuclear propulsion thermal-hydraulic analysis model (NUTHAM-S) to determine the two-dimensional steady-state temperature, pressure, and flow fields in the core and optimize the orificing in the hot frit to avoid hot spots in the core at full-power operation.

  15. Sequential UASB and dual media packed-bed reactors for domestic wastewater treatment - experiment and simulation.

    Science.gov (United States)

    Rodríguez-Gómez, Raúl; Renman, Gunno

    2016-01-01

    A wastewater treatment system composed of an upflow anaerobic sludge blanket (UASB) reactor followed by a packed-bed reactor (PBR) filled with Sorbulite(®) and Polonite(®) filter material was tested in a laboratory bench-scale experiment. The system was operated for 50 weeks and achieved very efficient total phosphorus (P) removal (99%), 7-day biochemical oxygen demand removal (99%) and pathogenic bacteria reduction (99%). However, total nitrogen was only moderately reduced in the system (40%). A model focusing on simulation of organic material, solids and size of granules was then implemented and validated for the UASB reactor. Good agreement between the simulated and measured results demonstrated the capacity of the model to predict the behaviour of solids and chemical oxygen demand, which is critical for successful P removal and recovery in the PBR. PMID:27332842

  16. Neutronics and thermal-hydraulics analyses of the pellet bed reactor for nuclear thermal propulsion

    International Nuclear Information System (INIS)

    Neutronics and thermal-hydraulics design and analyses of the pellet bed reactor for nuclear thermal propulsion are performed based on consideration of reactor criticality, passive decay heat removal, maximum fuel temperature, and subcriticality during a water flooding accident. Besides calculating the dimensions of the reactor core to satisfy the excess reactivity requirement at the beginning-of-mission of 1.25 $ (Keff of 1.01), the TWODANT discrete ordinates code is used to estimate the radial and axial fission power density profiles in the core. These power profiles are used in the nuclear propulsion thermal-hydraulic analysis model (NUTHAM-S) to determine the two-dimensional steady-state temperature, pressure, and flow fields in the core and optimize the orificing in the hot frit to avoid hot spots in the core at full-power operation

  17. Plutonium and minor actinide utilisation in a pebble-bed high temperature reactor

    International Nuclear Information System (INIS)

    This paper contains results of the analysis of the pebble-bed high temperature gas-cooled PUMA reactor loaded with plutonium and minor actinide (Pu/MA) fuel. Starting from knowledge and experience gained in the Euratom FP5 projects HTR-N and HTR-N1, this study aims at demonstrating the potential of high temperature reactors to utilize or transmute Pu/MA fuel. The work has been performed within the Euratom FP6 project PUMA. A number of different fuel types and fuel configurations have been analyzed and compared with respect to incineration performance and safety-related reactor parameters. The results show the excellent plutonium and minor actinide burning capabilities of the high temperature reactor. The largest degree of incineration is attained in the case of an HTR fuelled by pure plutonium fuel as it remains critical at very deep burnup of the discharged pebbles. Addition of minor actinides to the fuel leads to decrease of the achievable discharge burnup and therefore smaller fraction of actinides incinerated during reactor operation. The inert-matrix fuel design improves the transmutation performance of the reactor, while the 'wallpaper' fuel does not have advantage over the standard fuel design in this respect. After 100 years of decay following the fuel discharge, the total amount of actinides remains almost unchanged for all of the fuel types considered. Among the plutonium isotopes, only the amount of Pu-241 is reduced significantly due to its relatively short half-life. (authors)

  18. Plutonium and minor actinide utilisation in a pebble-bed high temperature reactor

    Energy Technology Data Exchange (ETDEWEB)

    Petrov, B. Y.; Kuijper, J. C.; Oppe, J.; De Haas, J. B. M. [Nuclear Research and Consultancy Group, Westerduinweg 3, 1755 ZG Petten (Netherlands)

    2012-07-01

    This paper contains results of the analysis of the pebble-bed high temperature gas-cooled PUMA reactor loaded with plutonium and minor actinide (Pu/MA) fuel. Starting from knowledge and experience gained in the Euratom FP5 projects HTR-N and HTR-N1, this study aims at demonstrating the potential of high temperature reactors to utilize or transmute Pu/MA fuel. The work has been performed within the Euratom FP6 project PUMA. A number of different fuel types and fuel configurations have been analyzed and compared with respect to incineration performance and safety-related reactor parameters. The results show the excellent plutonium and minor actinide burning capabilities of the high temperature reactor. The largest degree of incineration is attained in the case of an HTR fuelled by pure plutonium fuel as it remains critical at very deep burnup of the discharged pebbles. Addition of minor actinides to the fuel leads to decrease of the achievable discharge burnup and therefore smaller fraction of actinides incinerated during reactor operation. The inert-matrix fuel design improves the transmutation performance of the reactor, while the 'wallpaper' fuel does not have advantage over the standard fuel design in this respect. After 100 years of decay following the fuel discharge, the total amount of actinides remains almost unchanged for all of the fuel types considered. Among the plutonium isotopes, only the amount of Pu-241 is reduced significantly due to its relatively short half-life. (authors)

  19. Effect of sulfide concentration on the location of the metal precipitates in inversed fluidized bed reactors

    International Nuclear Information System (INIS)

    Highlights: → Sulfide concentration governs the location of metal precipitates in sulfate reducing bioreactors. → High dissolved sulfide induces metal precipitation in the bulk liquid as fines. → Low dissolved sulfide concentrations yield local supersaturation and thus metal precipitation in the biofilm. -- Abstract: The effect of the sulfide concentration on the location of the metal precipitates within sulfate-reducing inversed fluidized bed (IFB) reactors was evaluated. Two mesophilic IFB reactors were operated for over 100 days at the same operational conditions, but with different chemical oxygen demand (COD) to SO42- ratio (5 and 1, respectively). After a start up phase, 10 mg/L of Cu, Pb, Cd and Zn each were added to the influent. The sulfide concentration in one IFB reactor reached 648 mg/L, while it reached only 59 mg/L in the other one. In the high sulfide IFB reactor, the precipitated metals were mainly located in the bulk liquid (as fines), whereas in the low sulfide IFB reactor the metal preciptiates were mainly present in the biofilm. The latter can be explained by local supersaturation due to sulfide production in the biofilm. This paper demonstrates that the sulfide concentration needs to be controlled in sulfate reducing IFB reactors to steer the location of the metal precipitates for recovery.

  20. Experimental and modelling study of drinking water hydrogenotrophic denitrification in packed-bed reactors

    International Nuclear Information System (INIS)

    The aim of this work was to study hydrogenotrophic denitrification in packed-bed reactors under draw-fill and continuous operation. Three bench-scale packed-bed reactors with gravel in different sizes (mean diameter 1.75, 2.41 and 4.03 mm) as support media were used, in order to study the effect of particle size on reactors performance. The maximum denitrification rate achieved under draw-fill operation was 4.4 g NO3--N/ld for the filter with gravel of 2.41 mm. This gravel size was chosen to perform experiments under continuous operation. Feed NO3--N concentrations and hydraulic loadings (HL) ranged between 20-200 mg/l and 5.7-22.8 m3/m2 d, respectively. A comparison between the two operating modes showed that, for low HL the draw-fill operation achieved higher denitrification rates, while for high HL and intermediate feed concentrations (40-60 mg NO3--N/l) the continuous operation achieved higher denitrification rates (4.67-5.65 g/ld). Finally, experiments with three filters in series (with gravels of 4.03, 2.41 and 1.75 mm mean diameter) were also performed under continuous operation. The maximum denitrification rate achieved was 6.2 g NO3--N/ld for feed concentration of 340 mg/l and HL of 11.5 m3/m2 d. A model, which describes denitrification in packed-bed reactors, was also developed. The model predicts the concentration profiles of NO3--N along filter height, in draw-fill as well as in continuous operation, satisfactorily.

  1. Pebble bed reactors simulation using MCNP: The Chinese HTR-10 reactor

    Directory of Open Access Journals (Sweden)

    SA Hosseini

    2013-09-01

    Full Text Available   Given the role of Gas-Graphite reactors as the fourth generation reactors and their recently renewed importance, in 2002 the IAEA proposed a set of Benchmarking problems. In this work, we propose a model both efficient in time and resources and exact to simulate the HTR-10 reactor using MCNP-4C code. During the present work, all of the pressing factors in PBM reactor design such as the inter-pebble leakage, fuel particle distribution and fuel pebble packing fraction effects have been taken into account to obtain an exact and easy to run model. Finally, the comparison between the results of the present work and other calculations made at INEEL proves the exactness of the proposed model.

  2. Temperature transients of a fusion-fission ITER pebble bed reactor in loss of coolant accident

    International Nuclear Information System (INIS)

    In this preliminary scoping study, post-accident temperature transients of several fusion-fission designs utilizing ITER-FEAT-like parameters and fission pebble bed fuel technology are examined using a 1-D cylindrical MATLAB heat transfer code along with conventional fission decay heat approximations. Scenarios studied include systems with no additional passive safety features to systems with melting reflectors designed to increase emissivity after reaching a specified temperature. Results show that for a total fission power of ∼1400-2800 MW, two of the realistic variants investigated are passively safe. The crucial time, defined as the time when either any structural part of the fusion-fission tokamak reaches melting point, or when the pebble fuel reaches 1873 K, ranges from 5.7 to 76 h for the unsafe configurations. Additionally, it is illustrated that, fundamentally, the LOCA characteristics of pure fission pebble beds and fusion-fission pebble beds are different. Namely, the former depends on the pebble fuel's large thermal capacity, along with external radiation and natural convective cooling, while the latter depends significantly more on the tokamak's sizeable total internal heat capacity. This difference originates from the fusion-fission reactor's conflicting goal of having to minimize heat transfer to the magnets during normal operation. These results are discussed in the context of overall fusion-fission reactor design and safety

  3. Pyrolysis of municipal sewage sludges in a slowly heating and gas sweeping fixed-bed reactor

    International Nuclear Information System (INIS)

    Highlights: • A fixed-bed reactor with sweeping gas was used to mitigate secondary reactions. • The pyrolysis products reflected the original structures of sludge compositions. • The slow pyrolysis produced high yields of liquid. • The oxygen-containing and nitrogenated compounds were the main liquid products. • The gas and liquid yields correlated with the volatile matter contents in the sludges. - Abstract: The pyrolysis of three municipal sewage sludges was carried out using a slowly heating and gas sweeping fixed-bed reactor in the temperature range between 300 °C and 700 °C. The study was aimed to characterize the gaseous and liquid products derived from three different sewage sludges and mainly to discuss the varieties of sewage sludges on the yields and compositions of the gaseous and liquid products. The pyrolysis in this reactor was observed to produce high yields of liquid (above 40 wt.% at 700 °C) that contained high proportions of oxygen-containing compounds and nitrogenated compounds, with minor monoaromatics and aliphatic compounds. The gas and liquid yields correlated with the volatile matter contents in the sludges. For all three sewage sludges, the oxygenated compounds were the principal liquid compounds which could be produced at a low temperature of 300 °C, while more of nitrogenated compounds and other compounds were formed at 700 °C depending on the varieties of sewage sludges

  4. Ethanol fermentation in a magnetically fluidized bed reactor with immobilized Saccharomyces cerevisiae in magnetic particles.

    Science.gov (United States)

    Liu, Chun-Zhao; Wang, Feng; Ou-Yang, Fan

    2009-01-01

    Ethanol fermentation by immobilized Saccharomyces cerevisiae cells in magnetic particles was successfully carried out in a magnetically stabilized fluidized bed reactor (MSFBR). These immobilized magnetic particles solidified in a 2 % CaCl(2) solution were stable and had high ethanol fermentation activity. The performance of ethanol fermentation of glucose in the MSFBR was affected by initial particle loading rate, feed sugar concentration and dilution rate. The ethanol theoretical yield, productivity and concentration reached 95.3%, 26.7 g/L h and 66 g/L, respectively, at a particle loading rate of 41% and a feed dilution rate of 0.4 h(-1) with a glucose concentration of 150 g/L when the magnetic field intensity was kept in the range of 85-120 Oe. In order to use this developed MSFBR system for ethanol production from cheap raw materials, cane molasses was used as the main fermentation substrate for continuous ethanol fermentation with the immobilized S. cerevisiae cells in the reactor system. Molasses gave comparative ethanol productivity in comparison with glucose in the MSFBR, and the higher ethanol production was observed in the MSFBR than in a fluidized bed reactor (FBR) without a magnetic field. PMID:18760598

  5. Degradation of Benzene by Using a Silent-Packed Bed Hybrid Discharge Plasma Reactor

    Institute of Scientific and Technical Information of China (English)

    姜楠; 鲁娜; 李杰; 吴彦

    2012-01-01

    In this work, a novel gas phase silent-packed bed hybrid discharge plasma reactor has been proposed, and its ability to control a simulative gas stream containing 240 ppm benzene is experimentally investigated. In order to optimize the geometry of the reactor, the benzene conversion rate and energy yield (EY) were compared for various inner electrode diameters and quartz tube shapes and sizes. In addition, benzene removal efficiency in different discharge regions was qualitatively analyzed and the gas parameter (space velocity) was systematically studied. It has been found that silent-packed bed hybrid discharge plasma reactor can effectively decompose benzene. Benzene removal proved to achieve an optimum value of 60% with a characteristic energy density of 255 J/L in this paper with a 6 mm bolt high-voltage electrode and a 13 mm quartz tube. The optimal space velocity was 188.1 h^-1, which resulted in moderate energy yield and removal efficiency. Reaction by-products such as hydroquinone, heptanoic acid, 4-nitrocatechol, phenol and 4-phenoxy-phenol were identified by mean of GC-MS. In addition, based on these organic by-products, a benzene destruction pathway was proposed.

  6. Remediation of trichloroethylene by bio-precipitated and encapsulated palladium nanoparticles in a fixed bed reactor.

    Science.gov (United States)

    Hennebel, Tom; Verhagen, Pieter; Simoen, Henri; De Gusseme, Bart; Vlaeminck, Siegfried E; Boon, Nico; Verstraete, Willy

    2009-08-01

    Trichloroethylene is a toxic and recalcitrant groundwater pollutant. Palladium nanoparticles bio-precipitated on Shewanella oneidensis were encapsulated in polyurethane, polyacrylamide, alginate, silica or coated on zeolites. The reactivity of these bio-Pd beads and zeolites was tested in batch experiments and trichloroethylene dechlorination followed first order reaction kinetics. The calculated k-values of the encapsulated catalysts were a factor of six lower compared to non-encapsulated bio-Pd. Bio-Pd, used as a catalyst, was able to dechlorinate 100 mgL(-1) trichloroethylene within a time period of 1h. The main reaction product was ethane; yet small levels of chlorinated intermediates were detected. Subsequently polyurethane cubes empowered with bio-Pd were implemented in a fixed bed reactor for the treatment of water containing trichloroethylene. The influent recycle configuration resulted in a cumulative removal of 98% after 22 h. The same reactor in a flow through configuration achieved removal rates up to 1059 mg trichloroethylene g Pd(-1)d(-1). This work showed that fixed bed reactors with bio-Pd polyurethane cubes can be instrumental for remediation of water contaminated with trichloroethylene. PMID:19560796

  7. Degradation of Benzene by Using a Silent-Packed Bed Hybrid Discharge Plasma Reactor

    Science.gov (United States)

    Jiang, Nan; Lu, Na; Li, Jie; Wu, Yan

    2012-02-01

    In this work, a novel gas phase silent-packed bed hybrid discharge plasma reactor has been proposed, and its ability to control a simulative gas stream containing 240 ppm benzene is experimentally investigated. In order to optimize the geometry of the reactor, the benzene conversion rate and energy yield (EY) were compared for various inner electrode diameters and quartz tube shapes and sizes. In addition, benzene removal efficiency in different discharge regions was qualitatively analyzed and the gas parameter (space velocity) was systematically studied. It has been found that silent-packed bed hybrid discharge plasma reactor can effectively decompose benzene. Benzene removal proved to achieve an optimum value of 60% with a characteristic energy density of 255 J/L in this paper with a 6 mm bolt high-voltage electrode and a 13 mm quartz tube. The optimal space velocity was 188.1 h-1, which resulted in moderate energy yield and removal efficiency. Reaction by-products such as hydroquinone, heptanoic acid, 4-nitrocatechol, phenol and 4-phenoxy-phenol were identified by mean of GC-MS. In addition, based on these organic by-products, a benzene destruction pathway was proposed.

  8. Production of Polygalacturonases by Aspergillus section Nigri Strains in a Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Marília Maciel

    2013-01-01

    Full Text Available Polygalacturonases (PG are pectinolytic enzymes that have technological, functional and biological applications in food processing, fruit ripening and plant-fungus interactions, respectively. In the present, a microtitre plate methodology was used for rapid screening of 61 isolates of fungi from Aspergillus section Nigri to assess production of endo- and exo-PG. Studies of scale-up were carried out in a fixed bed reactor operated under different parameters using the best producer strain immobilised in orange peels. Four experiments were conducted under the following conditions: the immobilised cells without aeration; immobilised cells with aeration; immobilised cells with aeration and added pectin; and free cells with aeration. The fermentation was performed for 168 h with removal of sample every 24 h. Aspergillus niger strain URM 5162 showed the highest PG production. The results obtained indicated that the maximum endo- and exo-PG activities (1.18 U·mL−1 and 4.11 U·mL−1, respectively were obtained when the reactor was operating without aeration. The microtitre plate method is a simple way to screen fungal isolates for PG activity detection. The fixed bed reactor with orange peel support and using A. niger URM 5162 is a promising process for PG production at the industrial level.

  9. A Photocatalytic Active Adsorbent for Gas Cleaning in a Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Peter Pucher

    2008-01-01

    Full Text Available Efficient photocatalysis for gas cleaning purposes requires a large accessible, illuminated active surface in a simple and compact reactor. Conventional concepts use powdered catalysts, which are nontransparent. Hence a uniform distribution of light is difficult to be attained. Our approach is based on a coarse granular, UV-A light transparent, and highly porous adsorbent that can be used in a simple fixed bed reactor. A novel sol-gel process with rapid micro mixing is used to coat a porous silica substrate with TiO2-based nanoparticles. The resulting material posses a high adsorption capacity and a photocatalytic activity under UV-A illumination (PCAA = photocatalytic active adsorbent. Its photocatalytic performance was studied on the oxidation of trichloroethylene (TCE in a fixed bed reactor setup in continuous and discontinuous operation modes. Continuous operation resulted in a higher conversion rate due to less slip while discontinuous operation is superior for a total oxidation to CO2 due to a user-defined longer residence time.

  10. Comparative evaluation of pebble-bed and prismatic fueled high-temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Kasten, P.R.; Bartine, D.E.

    1981-01-01

    A comparative evaluation has been performed of the HTGR and the Federal Republic of Germany's Pebble Bed Reactor (PBR) for potential commercial applications in the US. The evaluation considered two reactor sizes (1000 and 3000 MW(t)) and three process applications (steam cycle, direct cycle, and process heat, with outlet coolant temperatures of 750, 850, and 950/sup 0/C, respectively). The primary criterion for the comparison was the levelized (15-year) cost of producing electricity or process heat. Emphasis was placed on the cost impact of differences between the prismatic-type HTGR core, which requires periodic refuelings during reactor shutdowns, and the pebble bed PBR core, which is refueled continuously during reactor operations. Detailed studies of key technical issues using reference HTGR and PBR designs revealed that two cost components contributing to the levelized power costs are higher for the PBR: capital costs and operation and maintenance costs. A third cost component, associated with nonavailability penalties, tended to be higher for the PBR except for the process heat application, for which there is a large uncertainty in the HTGR nonavailability penalty at the 950/sup 0/C outlet coolant temperature. A fourth cost component, fuel cycle costs, is lower for the PBR, but not sufficiently lower to offset the capital cost component. Thus the HTGR appears to be slightly superior to the PBR in economic performance. Because of the advanced development of the HTGR concept, large HTGRs could also be commercialized in the US with lower R and D costs and shorter lead times than could large PBRs. It is recommended that the US gas-cooled thermal reactor program continue giving primary support to the HTGR, while also maintaining its cooperative PBR program with FRG.

  11. Comparative evaluation of pebble-bed and prismatic fueled high-temperature gas-cooled reactors

    International Nuclear Information System (INIS)

    A comparative evaluation has been performed of the HTGR and the Federal Republic of Germany's Pebble Bed Reactor (PBR) for potential commercial applications in the US. The evaluation considered two reactor sizes [1000 and 3000 MW(t)] and three process applications (steam cycle, direct cycle, and process heat, with outlet coolant temperatures of 750, 850, and 9500C, respectively). The primary criterion for the comparison was the levelized (15-year) cost of producing electricity or process heat. Emphasis was placed on the cost impact of differences between the prismatic-type HTGR core, which requires periodic refuelings during reactor shutdowns, and the pebble bed PBR core, which is refueled continuously during reactor operations. Detailed studies of key technical issues using reference HTGR and PBR designs revealed that two cost components contributing to the levelized power costs are higher for the PBR: capital costs and operation and maintenance costs. A third cost component, associated with nonavailability penalties, tended to be higher for the PBR except for the process heat application, for which there is a large uncertainty in the HTGR nonavailability penalty at the 9500C outlet coolant temperature. A fourth cost component, fuel cycle costs, is lower for the PBR, but not sufficiently lower to offset the capital cost component. Thus the HTGR appears to be slightly superior to the PBR in economic performance. Because of the advanced development of the HTGR concept, large HTGRs could also be commercialized in the US with lower R and D costs and shorter lead times than could large PBRs. It is recommended that the US gas-cooled thermal reactor program continue giving primary support to the HTGR, while also maintaining its cooperative PBR program with FRG

  12. Development of a thermal–hydraulic analysis code for the Pebble Bed Water-cooled Reactor

    International Nuclear Information System (INIS)

    Highlights: ► Main design features of the PBWR were put forward. ► Thermal–hydraullics analysis code for the PBWR was developed and verified. ► Key thermal–hydraullics parameters were calculated in normal operation. ► The PBWR has a great pressure loss but an excellent heat transfer characteristic. ► Maximum fuel temperature and MDNBR are in conformity with safety criterion. - Abstract: The Pebble Bed Water-cooled Reactor (PBWR) is a water-moderated water-cooled pebble bed reactor in which millions of tristructural-isotropic (TRISO) coated micro-fuel elements (MFE) pile in each assembly. Light water is used as coolant that flows from bottom to top in the assembly while the moderator water flows in the reverse direction out of the assembly. Steady-state thermal–hydraullic analysis code for the PBWR will provide a set of thermal hydraulic parameters of the primary loop so that heat transported out of the core can match with the heat generated by the core for a safe operation of the reactor. The key parameters of the core including the void fraction, pressure drop, heat transfer coefficients, the temperature distribution and the Departure from Nucleate Boiling Ratio (DNBR) is calculated for the core in normal operation. The code can calculate for liquid region, water-steam two phase region and superheated steam region. The results show that the maximum fuel temperature is much lower than the design limitation and the flow distribution can meet the cooling requirement in the reactor core. As a new type of nuclear reactor, the main design features with a sufficient safety margin were also put forward in this paper.

  13. Conformal nanocoating of zirconia nanoparticles by atomic layer deposition in a fluidized bed reactor

    Science.gov (United States)

    Hakim, Luis F.; George, Steven M.; Weimer, Alan W.

    2005-07-01

    Primary zirconia nanoparticles were conformally coated with alumina ultrathin films using atomic layer deposition (ALD) in a fluidized bed reactor. Alternating doses of trimethylaluminium and water vapour were performed to deposit Al2O3 nanolayers on the surface of 26 nm zirconia nanoparticles. Transmission Fourier transform infrared spectroscopy was performed ex situ. Bulk Al2O3 vibrational modes were observed for coated particles after 50 and 70 cycles. Coated nanoparticles were also examined with transmission electron microscopy, high-resolution field emission scanning electron microscopy and energy dispersive spectroscopy. Analysis revealed highly conformal and uniform alumina nanofilms throughout the surface of zirconia nanoparticles. The particle size distribution and surface area of the nanoparticles are not affected by the coating process. Primary nanoparticles are coated individually despite their high aggregation tendency during fluidization. The dynamic aggregation behaviour of zirconia nanoparticles in the fluidized bed plays a key role in the individual coating of nanoparticles.

  14. Fast pyrolysis of rape seed in a well-swept fixed-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Onay, O.; Beis, S.H.; Kockar, O.M. [Department of Chemical Engineering, Anadolu University, 26470, Eskisehir (Turkey)

    2001-04-01

    Fixed-bed fast pyrolysis experiments have been conducted on a sample of rape seed to determine particularly the effects of pyrolysis temperature, particle size, heating rate and sweep gas flow rate on the pyrolysis yields and their chemical compositions. The maximum oil yield of 68% was obtained at the final pyrolysis temperature of 550C, particle size range of 0.6-0.85 mm, with a heating rate of 300C min{sup -1} and a sweep gas flow rate of 100 cm{sup 3} min{sup -1} (N{sub 2}) in a well-swept fixed-bed reactor. Chromatographic and spectroscopic studies on the pyrolytic oil showed that the oil obtained from rape seed can be used as a renewable fuel and chemical feedstock.

  15. Effects of operating conditions on the removal of heavy metals by zeolite in fixed bed reactors

    International Nuclear Information System (INIS)

    This work investigates the effects of flow rate (5-15 Bed Volumes/h), particle size (0.8-1.7 mm), concentration (0.005-0.02 N) and Na+-enrichment of natural clinoptilolite on the removal efficiency of Pb2+, Cu2+, Fe3+ and Cr3+ in aqueous solutions. Ion exchange is performed in an upflow fixed bed reactor. The removal efficiency is increased with decreasing flow rate, particle size and concentration and is improved by a factor of 2-10, depending on the specific metal. The modification of the natural sample is favorable, leading to an increase of removal efficiency by 32-100%. For the experimental conditions examined, removal efficiency order is the following: Pb2+>Cr3+>Fe3+≥Cu2+. Finally, the operation is influenced by the studied parameters, following the order: concentration>volumetric flow rate>particle size>modification of the material

  16. Pebble bed modular reactor safeguards: developing new approaches and implementing safeguards by design

    Energy Technology Data Exchange (ETDEWEB)

    Beyer, Brian David [Los Alamos National Laboratory; Beddingfield, David H [Los Alamos National Laboratory; Durst, Philip [INL; Bean, Robert [INL

    2010-01-01

    The design of the Pebble Bed Modular Reactor (PBMR) does not fit or seem appropriate to the IAEA safeguards approach under the categories of light water reactor (LWR), on-load refueled reactor (OLR, i.e. CANDU), or Other (prismatic HTGR) because the fuel is in a bulk form, rather than discrete items. Because the nuclear fuel is a collection of nuclear material inserted in tennis-ball sized spheres containing structural and moderating material and a PBMR core will contain a bulk load on the order of 500,000 spheres, it could be classified as a 'Bulk-Fuel Reactor.' Hence, the IAEA should develop unique safeguards criteria. In a multi-lab DOE study, it was found that an optimized blend of: (i) developing techniques to verify the plutonium content in spent fuel pebbles, (ii) improving burn-up computer codes for PBMR spent fuel to provide better understanding of the core and spent fuel makeup, and (iii) utilizing bulk verification techniques for PBMR spent fuel storage bins should be combined with the historic IAEA and South African approaches of containment and surveillance to verify and maintain continuity of knowledge of PBMR fuel. For all of these techniques to work the design of the reactor will need to accommodate safeguards and material accountancy measures to a far greater extent than has thus far been the case. The implementation of Safeguards-by-Design as the PBMR design progresses provides an approach to meets these safeguards and accountancy needs.

  17. COMPARISON OF UASB AND FLUIDIZED-BED REACTORS FOR SULFATE REDUCTION

    Directory of Open Access Journals (Sweden)

    S. M. Bertolino

    2015-03-01

    Full Text Available Abstract Reactor hydrodynamics is important for sulfidogenesis because sulfate reduction bacteria (SRB do not granulate easily. In this work, the sulfate reduction performance of two continuous anaerobic bioreactors was investigated: (i an upflow anaerobic sludge blanket (UASB reactor and (ii a fluidized bed reactor (FBR. Organic loading, sulfate reduction, and COD removal were the main parameters monitored during lactate and glycerol degradation. The UASB reactor with biomass recirculation showed a specific sulfate reduction rate of 0.089±0.014 g.gSSV-1.d-1 (89% reduction, whereas values twice as high were achieved in the FBR treating either lactate (0.200±0.017 g.gSSV-1.d-1 or glycerol (0.178±0.010 g.gSSV-1.d-1. Sulfate reduction with pure glycerol produced a smaller residual COD (1700 mg.L-1 than that produced with lactate (2500 mg.L-1 at the same COD.sulfate-1 mass ratio. It was estimated that 50% of glycerol degradation was due to sulfate reduction and 50% to fermentation, which was supported by the presence of butyrate in the FBR effluent. The UASB reactor was unable to produce effluents with sulfate concentrations below 250 mg.L-1 due to poor mixing conditions, whereas the FBR consistently ensured residual sulfate concentrations below such a value.

  18. Anaerobic tapered fluidized bed reactor for starch wastewater treatment and modeling using multilayer perceptron neural network

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Anaerobic treatability of synthetic sago wastewater was investigated in a laboratory anaerobic tapered fluidized bed reactor (ATFBR) with a mesoporous granular activated carbon (GAC) as a support material. The experimental protocol was defined to examine the effect of the maximum organic loading rate (OLR), hydraulic retention time (HRT), the efficiency of the reactor and to report on its steady-state performance. The reactor was subjected to a steady-state operation over a range of OLR up to 85.44 kg COD/(m3·d). The COD removal efficiency was found to be 92% in the reactor while the biogas produced in the digester reached 25.38 m3/(m3·d) of the reactor. With the increase of OLR from 83.7 kg COD/(m3·d), the COD removal efficiency decreases. Also an artificial neural network (ANN) model using multilayer perceptron (MLP) has been developed for a system of two input variable and five output dependent variables. For the training of the input-output data, the experimental values obtained have been used. The output parameters predicted have been found to be much closer to the corresponding experimental ones and the model was validated for 30% of the untrained data. The mean square error (MSE) was found to be only 0.0146.

  19. A comparative study of the circulating and fixed bed reactors running. Application to the isobutyric acid oxy-dehydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Bechara, R.; Lakraa, M.; Vanhove, D.; Pietrzyk, S. [Ecole Nationale Superieure de Chimie de Lille, 59 - Villeneuve d`Ascq (France); Hecquet, G. [Societe Nationale Elf-Aquitaine (France)

    1995-12-31

    This work deals with the study of the catalytic oxy-dehydrogenation process of the isobutyric acid in methacrylic acid on a Fe-Cs-P-O catalyst. The reaction has been carried out on two facilities: a circulating bed pilot reactor and a bench-scale packed bed reactor. Although there are considerable differences between the two reactors, a comparison has been established. When the reaction is carried out in the circulating bed reactor, an important ratio of carbonaceous species remain adsorbed at the catalyst surface. A more extensive analysis of the catalyst surface suggest that the main part of this adsorbed phase is probably methacrylic acid. (O.M.). 8 refs., 1 fig., 1 tab.

  20. A CFD approach on the effect of particle size on char entrainment in bubbling fluidised bed reactors

    International Nuclear Information System (INIS)

    The fluid - particle interaction inside a 41.7 mg s-1 fluidised bed reactor is modelled. Three char particles of sizes 500 μm, 250 μm, and 100 μm are injected into the fluidised bed and the momentum transport from the fluidising gas and fluidised sand is modelled. Due to the fluidising conditions and reactor design the char particles will either be entrained from the reactor or remain inside the bubbling bed. The particle size is the factor that differentiates the particle motion inside the reactor and their efficient entrainment out of it. A 3-Dimensional simulation has been performed with a completele revised momentum transport model for bubble three-phase flow according to the literature as an extension to the commercial finite volume code FLUENT 6.2.

  1. Fission Product Transport and Source Terms in HTRs: Experience from AVR Pebble Bed Reactor

    Directory of Open Access Journals (Sweden)

    Rainer Moormann

    2008-01-01

    Full Text Available Fission products deposited in the coolant circuit outside of the active core play a dominant role in source term estimations for advanced small pebble bed HTRs, particularly in design basis accidents (DBA. The deposited fission products may be released in depressurization accidents because present pebble bed HTR concepts abstain from a gas tight containment. Contamination of the circuit also hinders maintenance work. Experiments, performed from 1972 to 88 on the AVR, an experimental pebble bed HTR, allow for a deeper insight into fission product transport behavior. The activity deposition per coolant pass was lower than expected and was influenced by fission product chemistry and by presence of carbonaceous dust. The latter lead also to inconsistencies between Cs plate out experiments in laboratory and in AVR. The deposition behavior of Ag was in line with present models. Dust as activity carrier is of safety relevance because of its mobility and of its sorption capability for fission products. All metal surfaces in pebble bed reactors were covered by a carbonaceous dust layer. Dust in AVR was produced by abrasion in amounts of about 5 kg/y. Additional dust sources in AVR were ours oil ingress and peeling of fuel element surfaces due to an air ingress. Dust has a size of about 1  m, consists mainly of graphite, is partly remobilized by flow perturbations, and deposits with time constants of 1 to 2 hours. In future reactors, an efficient filtering via a gas tight containment is required because accidents with fast depressurizations induce dust mobilization. Enhanced core temperatures in normal operation as in AVR and broken fuel pebbles have to be considered, as inflammable dust concentrations in the gas phase.

  2. Applicability of fluidized bed reactor in recalcitrant compound degradation through advanced oxidation processes: a review.

    Science.gov (United States)

    Tisa, Farhana; Abdul Raman, Abdul Aziz; Wan Daud, Wan Mohd Ashri

    2014-12-15

    Treatment of industrial waste water (e.g. textile waste water, phenol waste water, pharmaceutical etc) faces limitation in conventional treatment procedures. Advanced oxidation processes (AOPs) do not suffer from the limits of conventional treatment processes and consequently degrade toxic pollutants more efficiently. Complexity is faced in eradicating the restrictions of AOPs such as sludge formation, toxic intermediates formation and high requirement for oxidants. Increased mass-transfer in AOPs is an alternate solution to this problem. AOPs combined with Fluidized bed reactor (FBR) can be a potential choice compared to fixed bed or moving bed reactor, as AOP catalysts life-span last for only maximum of 5-10 cycles. Hence, FBR-AOPs require lesser operational and maintenance cost by reducing material resources. The time required for AOP can be minimized using FBR and also treatable working volume can be increased. FBR-AOP can process from 1 to 10 L of volume which is 10 times more than simple batch reaction. The mass transfer is higher thus the reaction time is lesser. For having increased mass transfer sludge production can be successfully avoided. The review study suggests that, optimum particle size, catalyst to reactor volume ratio, catalyst diameter and liquid or gas velocity is required for efficient FBR-AOP systems. However, FBR-AOPs are still under lab-scale investigation and for industrial application cost study is needed. Cost of FBR-AOPs highly depends on energy density needed and the mechanism of degradation of the pollutant. The cost of waste water treatment containing azo dyes was found to be US$ 50 to US$ 500 per 1000 gallons where, the cost for treating phenol water was US$ 50 to US$ 800 per 1000 gallons. The analysis for FBR-AOP costs has been found to depend on the targeted pollutant, degradation mechanism (zero order, 1st order and 2nd order) and energy consumptions by the AOPs. PMID:25190594

  3. Preliminary safety analysis of a thorium high-conversion pebble bed reactor

    International Nuclear Information System (INIS)

    An inherently safe thorium High-Conversion Pebble Bed Reactor would combine the inherent safety characteristics of the Pebble Bed Reactor with the favourable waste characteristics and resource availability of the thorium fuel cycle. Previous work by the authors showed that high conversion ratio's can be achieved within a thorium Pebble Bed Reactor (PBR) at a practical operating regime. The thorium PBR core design consists of a cylindrical core with a central driver zone surrounded by a breeder zone. The breeder pebbles have a 30 g heavy metal (HM) loading to enhance conversion of Th-232 into U-233, while the driver pebbles (10 w% U-233) contain a lower metal loading to enhance fission. In previous studies, thorium PBR designs were presented for three core diameters, using a 7.5 g heavy metal (HM) loading for the driver pebbles. The current paper investigates the safety of these thorium PBR designs in terms of reactivity coefficients and possible reactivity insertion due to water ingress. Early results indicated that the values of the reactivity coefficients for the three designs with 7.5 g HM loading per driver pebble were rather small and the possible reactivity insertion due to water ingress was very large. Therefore, also a lower HM loading per driver pebble (4 g) was investigated to reduce the impact of water ingress, since the core becomes less under-moderated. For the three core diameters investigated, it is shown that reducing the metal loading in the driver pebbles to 4 g is indeed advantageous in terms of safety, water ingress leads to a smaller reactivity increase but also the reactivity coefficients become stronger negative. Secondly, the breeding performance of the cores with a 4 g driver pebble HM loading improves. On the downside, the driver pebble residence times become shorter, which could increase fuel reprocessing costs. Fuel pebbles would have to be recycled at an increased rate, which might be more challenging from a practical perspective

  4. Electrical Capacitance Volume Tomography for the Packed Bed Reactor ISS Flight Experiment

    Science.gov (United States)

    Marashdeh, Qussai; Motil, Brian; Wang, Aining; Liang-Shih, Fan

    2013-01-01

    Fixed packed bed reactors are compact, require minimum power and maintenance to operate, and are highly reliable. These features make this technology a highly desirable unit operation for long duration life support systems in space. NASA is developing an ISS experiment to address this technology with particular focus on water reclamation and air revitalization. Earlier research and development efforts funded by NASA have resulted in two hydrodynamic models which require validation with appropriate instrumentation in an extended microgravity environment. To validate these models, the instantaneous distribution of the gas and liquid phases must be measured.Electrical Capacitance Volume Tomography (ECVT) is a non-invasive imaging technology recently developed for multi-phase flow applications. It is based on distributing flexible capacitance plates on the peripheral of a flow column and collecting real-time measurements of inter-electrode capacitances. Capacitance measurements here are directly related to dielectric constant distribution, a physical property that is also related to material distribution in the imaging domain. Reconstruction algorithms are employed to map volume images of dielectric distribution in the imaging domain, which is in turn related to phase distribution. ECVT is suitable for imaging interacting materials of different dielectric constants, typical in multi-phase flow systems. ECVT is being used extensively for measuring flow variables in various gas-liquid and gas-solid flow systems. Recent application of ECVT include flows in risers and exit regions of circulating fluidized beds, gas-liquid and gas-solid bubble columns, trickle beds, and slurry bubble columns. ECVT is also used to validate flow models and CFD simulations. The technology is uniquely qualified for imaging phase concentrations in packed bed reactors for the ISS flight experiments as it exhibits favorable features of compact size, low profile sensors, high imaging speed, and

  5. Approach to development of high flux research reactor with pebble-bed core

    International Nuclear Information System (INIS)

    Full text: The research nuclear reactor of a basin-type IRT with the designed power of 1 MW was put into operation in 'Sosny' settlement not far from Minsk-city in the Republic of Belarus in 1962. In 1971 after its modernization the power was increased up to 4 MW and maximum density of neutron flux in the core was: Thermal 5·1013 neutr./cm2.s Fast (E>0.8 MeV) 2·1013 neutr./cm2.s The reactor has been used for carrying out investigations in the field of solid-state physics, radiation construction materials, radiobiology, gaseous chemically reacting coolants and others. After the Chernobyl NPP accident, in the former USSR the requirements on safety of nuclear reactors have become sufficiently stricter. As to some parameters these requirements became the same as for reactors of nuclear power plants. In this connection the reactor in 'Sosny' settlement did not answer these new requirements by a number of performances such as seismicity of building, efficiency of control and protection system, corrosion in the reactor vessel and others, and it was shutdown in 1987 and its decommissioning was performed during 1988-1999. At the Joint Institute of Power and Nuclear Research -'SOSNY' have been carried out investigations on feasibility of creation of the research reactor with pebble-bed core. The concept of such reactor supposes using the following technical approaches: - Using as fuel the brought sphere micro fuel elements with the diameter of 500-750 mkm to an industrial level; - Organization of reactor operation in the regime with minimum possible fueling with 235U; - Implementation of hydraulic loading - unloading of micro fuel elements with the frequency of one or several days. Physical calculations of the core were carried out with the help of MCU-RFFI program based on the Monte-Carlo method. Two configurations of the pebble-bed core in the high flux reactor have been considered. The first configuration is the core with a neutron trap and an annular fuel layer formed

  6. Computer-aided modeling framework – a generic modeling template for catalytic membrane fixed bed reactors

    DEFF Research Database (Denmark)

    Fedorova, Marina; Sin, Gürkan; Gani, Rafiqul

    2013-01-01

    This work focuses on development of computer-aided modeling framework. The framework is a knowledge-based system that is built on a generic modeling language and structured based on workflows for different general modeling tasks. The overall objective of this work is to support the model develope...... catalytic membrane fixed bed models is developed. The application of the modeling template is highlighted with a case study related to the modeling of a catalytic membrane reactor coupling dehydrogenation of ethylbenzene with hydrogenation of nitrobenzene....

  7. Hot waste-to-energy flue gas treatment using an integrated fluidised bed reactor

    International Nuclear Information System (INIS)

    This paper describes an innovative process to increase superheated steam temperatures in waste-to-energy (WTE) plants. This solution is mainly characterised by a fluidised bed reactor in which hot flue gas is treated both chemically and mechanically. This approach, together with gas recirculation, increases the energy conversion efficiency, and raises the superheated steam temperature without decreasing the useful life of the superheater. This paper presents new experimental data obtained from the test facility installed at the Hera S.p.A. WTE plant in Forli, Italy; discusses changes that can be implemented to increase the duration of experimental testing; offers suggestions for the design of an industrial solution

  8. Enzymatic interesterification of butterfat with rapeseed oil in a continuous packed bed reactor

    DEFF Research Database (Denmark)

    Rønne, Torben Harald; Yang, Tiankui; Mu, Huiling;

    2005-01-01

    further studies in a continuous packed bed reactor. TL IM gave a fast reaction and had almost reached equilibrium with a residence time of 30 min, whereas RM IM required 60 min. The effect of reaction temperature was more pronounced for RM IM. TL IM showed little effect on the interesterification degree...... when the temperature was raised from 60 degrees C to 90 degrees C, whereas RM IM had a positive effect when the temperature was increased from 40 degrees C to 80 degrees C. Even though TL IM is an sn-1,3 specific lipase, small changes in the sn-2 position of the triacylglycerol could be seen. The...

  9. Intensification of Pyrolysis Gasoline Hydrogenation in Pilot Trickle-Bed Reactor with Periodic Modulated Feed Rate

    Czech Academy of Sciences Publication Activity Database

    Tukač, V.; Handlová, M.; Chyba, V.; Lederer, J.; Kolena, J.; Kubička, D.; Hanika, Jiří; Jiřičný, Vladimír; Stavárek, Petr

    Praha: Process Engineering Publisher, 2008, s. 71-s. 72. ISBN 978-80-02-02048-6. [18th International Congress of Chemical and Process Engineering CHISA 2008. Praha (CZ), 24.08.2008-28.08.2008] R&D Projects: GA MPO FT-TA/039 Grant ostatní: CYCLOP(XE) G1RD/CT2000/00225 Institutional research plan: CEZ:AV0Z40720504 Keywords : pyrolysis gasoline * trickle-bed reactor * hydrogenation Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  10. Processing of uranium oxide powders in a fluidized-bed reactor. I. Experimental

    International Nuclear Information System (INIS)

    The oxidation of UN powders was carried out in a spout-type fluidized-bed reactor in gas mixtures of oxygen and argon, and over the temperature range of 200-500 deg. C. The rate of the conversion from UN to U3O8 powders was measured using gas chromatography and found to be dependent on temperature, partial pressure of oxygen and gas flowrate. The solid reactants and products were analyzed using SEM and XRD. Based on the experimental results, the conversion process was explained by the crackling core model

  11. Processing of uranium oxide powders in a fluidized-bed reactor. I. Experimental

    Science.gov (United States)

    Cho, W. D.; Han, Man-Hee; Bronson, Mark C.; Zundelevich, Yury

    2002-10-01

    The oxidation of UN powders was carried out in a spout-type fluidized-bed reactor in gas mixtures of oxygen and argon, and over the temperature range of 200-500 °C. The rate of the conversion from UN to U 3O 8 powders was measured using gas chromatography and found to be dependent on temperature, partial pressure of oxygen and gas flowrate. The solid reactants and products were analyzed using SEM and XRD. Based on the experimental results, the conversion process was explained by the crackling core model.

  12. DECARBONATION AND ATTRITION OF CALCITE IN A PLASMA SPOUTED BED REACTOR

    OpenAIRE

    G. Flamant; Chraibi, M. (Mohamede); Vallbona, G.; Bertrand, C

    1990-01-01

    The mechanical power and the thermal energy for the processing of calcite are the main part of the energy consumption in cement industry. Experimental results about particle size reduction and calcination of CaCO3 in a plasma spouted bed reactor are presented in this paper. The main parameter seems to be the specific enthalpy of the plasma jet, it ranges between 3 kWh.m-3 20 kWh.m-3. The variations of the attrition rate, decomposition rate and particle size distribution are discussed.

  13. The pebble bed high temperature reactor as a source of nuclear process heat. Vol. 2

    International Nuclear Information System (INIS)

    A theoretical analysis is given for a series of 8 different variants of the pebble-bed reactor in the 'once through' fuel management scheme. The comparison gives some insight into the parametric sensitivities and into the development potential of this type. The thorium/U-233 recycling fuel cycle allows to increase the conversion ratio up to the range between 0.90 and 0.95. The feasibility for a changeover between different fuel cycles under full power operation. - The study is complemented by a review of the relevant previous investigations. (orig.)

  14. Packed bed reactor for degradation of simulated cyanide-containing wastewater

    OpenAIRE

    Kumar, Virender; Kumar, Vijay; Bhalla, Tek Chand

    2014-01-01

    The discharge of cyanide-containing effluents into the environment contaminates water bodies and soil. Effective methods of treatment which can detoxify cyanide are the need of the hour. The aim of the present study is to develop a bioreactor for complete degradation of cyanide using immobilized cells of Serratia marcescens RL2b. Alginate-entrapped cells of S. marcescens RL2b were used for complete degradation of cyanide in a packed bed reactor (PBR). Cells grown in minimal salt medium (pH 6....

  15. Continuous thorium biosorption--dynamic study for critical bed depth determination in a fixed-bed reactor.

    Science.gov (United States)

    Picardo, Marta Cristina; Ferreira, Ana Cristina de Melo; da Costa, Antonio Carlos Augusto

    2009-01-01

    The objective of the work was to evaluate the biosorption of thorium by the seaweed Sargassum filipendula in a dynamic system. Different bed depths were tested with the purpose of evaluating the critical bed depth for total uptake of the radioactive element. Several bed depths were tested, ranging from 5.0 to 40.0 cm. Bed depths tested presented distinct capacities to accumulate thorium. An increase in biosorption efficiency was observed with an increase in bed depth. The 30.0 cm bed produced an effluent still containing detectable levels of thorium. The critical bed depth suitable for a complete removal of thorium by S.filipendula biomass was equal to 40.0 cm. PMID:18614355

  16. PEBBLE: a two-dimensional steady-state pebble bed reactor thermal hydraulics code

    International Nuclear Information System (INIS)

    This report documents the local implementation of the PEBBLE code to treat the two-dimensional steady-state pebble bed reactor thermal hydraulics problem. This code is implemented as a module of a computation system used for reactor core history calculations. Given power density data, the geometric description in (RZ), and basic heat removal conditions and thermal properties, the coolant properties, flow conditions, and temperature distributions in the pebble fuel elements are predicted. The calculation is oriented to the continuous fueling, steady state condition with consideration of the effect of the high energy neutron flux exposure and temperature history on the thermal conductivity. The coolant flow conditions are calculated for the same geometry as used in the neutronics calculation, power density and fluence data being used directly, and temperature results are made available for subsequent use

  17. Inhibition and recovery of nitrification in treating real coal gasification wastewater with moving bed biofilm reactor

    Institute of Scientific and Technical Information of China (English)

    Huiqiang Li; Hongjun Han; Maoan Du; Wei Wang

    2011-01-01

    Moving bed biofilm reactor (MBBR) was used to treat real coal gasification wastewater.Nitrification of the MBBR was inhibited almost completely during start-up period.Sudden increase of influent total NH3 concentration was the main factor inducing nitrification inhibition.Increasing DO concentration in the bulk liquid (from 2 to 3 mg/L) had little effect on nitrification recovery.Nitrification of the MBBR recovered partially by the addition of nitrifying sludge into the reactor and almost ceased within 5 days.Nitrification ratio of the MBBR achieved 65% within 12 days by increasing dilute ratio of the influent wastewater with tap water.The ratio of nitrification decreased to 25% when infiuent COD concentration increased from 650 to 1000 mg/L after nitrification recovery and recovered 70%for another 4 days.

  18. Fission product release out of the core of a pebble bed reactor in core heatup accidents

    International Nuclear Information System (INIS)

    This report presents the analysis of fission product release from the core of a pebble-bed high temperature reactor during hypothetical accidents. First the models describing fission product transport are discussed, and on the basis of these models a computer code is developped. This code includes the diffusion of fission products from particles and through the graphite, and the sorption of metallic fission product elements on graphite as well as the plateout of metallic fission product elements in the top- and bottom reflectors. In addition a review of the necessary empirical input data is given. Then the cesium release of a single fuel element at high temperatures is calculated, and the results are compared with experimental data. Furthermore calculations of the fission product release from the core of a 500 MW(th) high temperature reactor during core heatup accidents are made, and the influence of the most important parameters is described. (orig.)

  19. PEBBLE: a two-dimensional steady-state pebble bed reactor thermal hydraulics code

    Energy Technology Data Exchange (ETDEWEB)

    Vondy, D.R.

    1981-09-01

    This report documents the local implementation of the PEBBLE code to treat the two-dimensional steady-state pebble bed reactor thermal hydraulics problem. This code is implemented as a module of a computation system used for reactor core history calculations. Given power density data, the geometric description in (RZ), and basic heat removal conditions and thermal properties, the coolant properties, flow conditions, and temperature distributions in the pebble fuel elements are predicted. The calculation is oriented to the continuous fueling, steady state condition with consideration of the effect of the high energy neutron flux exposure and temperature history on the thermal conductivity. The coolant flow conditions are calculated for the same geometry as used in the neutronics calculation, power density and fluence data being used directly, and temperature results are made available for subsequent use.

  20. Fast pyrolysis of eucalyptus waste in a conical spouted bed reactor.

    Science.gov (United States)

    Amutio, Maider; Lopez, Gartzen; Alvarez, Jon; Olazar, Martin; Bilbao, Javier

    2015-10-01

    The fast pyrolysis of a forestry sector waste composed of Eucalyptus globulus wood, bark and leaves has been studied in a continuous bench-scale conical spouted bed reactor plant at 500°C. A high bio-oil yield of 75.4 wt.% has been obtained, which is explained by the suitable features of this reactor for biomass fast pyrolysis. Gas and bio-oil compositions have been determined by chromatographic techniques, and the char has also been characterized. The bio-oil has a water content of 35 wt.%, and phenols and ketones are the main organic compounds, with a concentration of 26 and 10 wt.%, respectively. In addition, a kinetic study has been carried out in thermobalance using a model of three independent and parallel reactions that allows quantifying this forestry waste's content of hemicellulose, cellulose and lignin. PMID:26203554

  1. Biodegradation kinetics during different start up of the anaerobic tapered fluidized bed reactor

    Directory of Open Access Journals (Sweden)

    Rangasamy Parthiban

    2011-10-01

    Full Text Available Kinetic study for different start up conditions of the anaerobic digestion of wastewater derived from the sago processingfrom tubers of tapioca (Mannihot utillisema is discussed. The experiment is carried out with synthetic waste water usinga tapered fluidized bed reactor. Mesoporous granulated activated carbon is used as a bacterial support. The kinetic modelfollows half order kinetics for substrate utilization and for methane formation and it exhibits an order of 0.20 during thestart up of the reactor without acclimatization. For the remaining start up with acclimatized sludge, kinetic parameters areexpressed in terms of Langmuir-Hinshelwood kinetics for the substrate utilization. The methane formation kinetics followsan order of the reaction as 0.30. The values of the kinetic constants are in the range of 0.13–0.21.

  2. Particle bed reactor propulsion vehicle performance and characteristics as an orbital transfer rocket

    International Nuclear Information System (INIS)

    The particle bed reactor designed for 100 to 300 MW power output using hydrogen as a coolant is capable of specific impulses up to 1000 seconds as a nuclear rocket. A single space shuttle compatible vehicle can perform extensive missions from LEO to 3 times GEO and return with multi-ton payloads. The use of hydrogen to directly cool particulate reactor fuel results in a compact, lightweight rocket vehicle, whose duration of usefulness is dependent only upon hydrogen resupply availability. The LEO to GEO mission had a payload capability of 15.4 metric tons with 3.4 meters of shuttle bay. To increase the volume limitation of the shuttle bay, the use of ammonia in the initial boost phase from LEO is used to give greater payload volume with a small decrease in payload mass, 8.7 meters and 12.7 m-tons. 5 refs., 15 figs

  3. Process for fuelling a pebble bed reactor and device for carrying out this process

    International Nuclear Information System (INIS)

    In a process for fuelling the inside of the pebble bed reactor with pellet fuel elements, these are supplied from above through a gravity device and are distributed radially, where the gravity device has a central gravity tube. So that the expense of the device, particularly the number of gravity tubes can be reduced, all fuel elements are introduced into the inside of the reactor only through the central gravity tube and the speed of fall of the fuel elements is varied, so that when they impinge on the surface of the cone which forms during fuelling, very probably they either remain in the centre or are deflected radially, corresponding to the selected speed of fall. (orig.)

  4. Gas Reactor International Cooperative program. Pebble bed reactor plant: screening evaluation. Volume 3. Appendix A. Equipment list

    International Nuclear Information System (INIS)

    This report consists of three volumes which describe the design concepts and screening evaluation for a 3000 MW(t) Pebble Bed Reactor Multiplex Plant (PBR-MX). The Multiplex plant produces both electricity and transportable chemical energy via the thermochemical pipeline (TCP). The evaluation was limited to a direct cycle plant which has the steam generators and steam reformers in the primary circuit. Volume 1 reports the overall plant and reactor system and was prepared by the General Electric Company. Core scoping studies were performed which evaluated the effects of annular and cylindrical core configurations, radial blanket zones, burnup, and ball heavy metal loadings. The reactor system, including the PCRV, was investigated for both the annular and cylindrical core configurations. Volume 3 is an Appendix containing the equipment list for the plant and was also prepared by United Engineers and Constructors, Inc. It tabulates the major components of the plant and describes each in terms of quantity, type, orientation, etc., to provide a basis for cost estimation

  5. Preliminary neutronic design of high burnup OTTO cycle pebble bed reactor

    International Nuclear Information System (INIS)

    The pebble bed type High Temperature Gas-cooled Reactor (HTGR) is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR) which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO) cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor design in general, is improving the nuclear fuel utilization which is shown by attaining a higher burnup value. This study performed a preliminary neutronic design study of a 200 MWt OTTO cycle PBR with high burnup while fulfilling the safety criteria of the PBR design.The safety criteria of the design was represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. The maximum burnup value was also limited by the tested maximum burnup value which maintained the integrity of the pebble fuel. Parametric surveys were performed to obtain the optimized parameters used in this study, which are the fuel enrichment, per-pebble heavy metal (HM) loading, and the average axial speed of the fuel. An optimum design with burnup value of 131.1 MWd/Kg-HM was achieved in this study which is much higher compare to the burnup of the reference design HTR-MODUL and a previously proposed OTTO-cycle PBR design. This optimum design uses 17% U-235 enrichment with 4 g HM-loading per fuel pebble. (author)

  6. Preliminary Neutronic Design of High Burnup OTTO Cycle Pebble Bed Reactor

    Directory of Open Access Journals (Sweden)

    T. Setiadipura

    2015-04-01

    Full Text Available The pebble bed type High Temperature Gas-cooled Reactor (HTGR is among the interesting nuclear reactor designs in terms of safety and flexibility for co-generation applications. In addition, the strong inherent safety characteristics of the pebble bed reactor (PBR which is based on natural mechanisms improve the simplicity of the PBR design, in particular for the Once-Through-Then-Out (OTTO cycle PBR design. One of the important challenges of the OTTO cycle PBR design, and nuclear reactor design in general, is improving the nuclear fuel utilization which is shown by attaining a higher burnup value. This study performed a preliminary neutronic design study of a 200 MWt OTTO cycle PBR with high burnup while fulfilling the safety criteria of the PBR design.The safety criteria of the design was represented by the per-fuel-pebble maximum power generation of 4.5 kW/pebble. The maximum burnup value was also limited by the tested maximum burnup value which maintained the integrity of the pebble fuel. Parametric surveys were performed to obtain the optimized parameters used in this study, which are the fuel enrichment, per-pebble heavy metal (HM loading, and the average axial speed of the fuel. An optimum design with burnup value of 131.1 MWd/Kg-HM was achieved in this study which is much higher compare to the burnup of the reference design HTR-MODUL and a previously proposed OTTO-cycle PBR design. This optimum design uses 17% U-235 enrichment with 4 g HM-loading per fuel pebble

  7. Catalytic stepwise nitrate hydrogenation in batch-recycle fixed-bed reactors

    International Nuclear Information System (INIS)

    Pd (1.0 wt.%)-Cu (0.3 wt.%) bimetallic and Pd (1.0 wt.%) monometallic catalysts were synthesized by means of incipient-wetness impregnation technique and deposited on alumina spheres (dp = 1.7 mm). The prepared catalysts were tested at T = 298 K and p(H2) = 1.0 bar in the integrated process of catalytic liquid-phase hydrogenation of aqueous nitrate solutions, in which the denitration step was carried out consecutively in separate, single-flow fixed-bed reactor units operating in a batch-recycle mode. In the first reactor packed with a Pd-Cu bimetallic catalyst, nitrate ions were transformed to nitrites at pH 12.5 with a selectivity as high as 93%; the rest was found in the form of ammonium ions. Liquid-phase nitrite hydrogenation to nitrogen in the second reactor unit packed with a Pd monometallic catalyst was conducted at low pH values of 3.7 and 4.5, respectively. Although these values are well below the pHpzc of examined catalyst (6.1), which assured that the nitrite reduction was carried out over a positively charged catalyst surface, up to 15% (23% in the presence of 5.0 g/l NaCl in the solution) of initial nitrite content was converted to undesired ammonium ions. Since a negligible amount of these species (below 0.5 mg/l) was produced at identical operating conditions over a powdered Pd/γ-Al2O3 catalyst, it is believed that the enhanced production of ammonium ions observed in the second fixed-bed reactor is due to the build-up of pH gradients in liquid-filled pores of spherical catalyst particles. Both Pd-Cu bimetallic and Pd monometallic catalysts were chemically resistant in the investigated range of pH values

  8. Degradation of TCE using sequential anaerobic biofilm and aerobic immobilized bed reactor

    Science.gov (United States)

    Chapatwala, Kirit D.; Babu, G. R. V.; Baresi, Larry; Trunzo, Richard M.

    1995-01-01

    Bacteria capable of degrading trichloroethylene (TCE) were isolated from contaminated wastewaters and soil sites. The aerobic cultures were identified as Pseudomonas aeruginosa (four species) and Pseudomonas fluorescens. The optimal conditions for the growth of aerobic cultures were determined. The minimal inhibitory concentration values of TCE for Pseudomonas sps. were also determined. The aerobic cells were immobilized in calcium alginate in the form of beads. Degradation of TCE by the anaerobic and dichloroethylene (DCE) by aerobic cultures was studied using dual reactors - anaerobic biofilm and aerobic immobilized bed reactor. The minimal mineral salt (MMS) medium saturated with TCE was pumped at the rate of 1 ml per hour into the anaerobic reactor. The MMS medium saturated with DCE and supplemented with xylenes and toluene (3 ppm each) was pumped at the rate of 1 ml per hour into the fluidized air-uplift-type reactor containing the immobilized aerobic cells. The concentrations of TCE and DCE and the metabolites formed during their degradation by the anaerobic and aerobic cultures were monitored by GC. The preliminary study suggests that the anaerobic and aerobic cultures of our isolates can degrade TCE and DCE.

  9. Space nuclear power studies in France. - A new concept of particle bed reactor

    International Nuclear Information System (INIS)

    A cooperative program about space nuclear turboelectric space power systems was initiated in 1982 by both the Centre National d'Etudes Spatiales (CNES) and the Commissariat a l'Energie Atomique (CEA) agencies of the French government, with a view to assessing the feasibility, the lead time and the cost for the development of nuclear space power systems relevant to the power range of 20 to 400 kWe. The effort on conceptual studies recently shifted towards low power systems (20 kWe). In order to widely cover the range of possible technologies for the 20-kWe space power systems, and to assess the impact of the reactor concept (liquid metal versus gas cooled) and of the relevant operating temperature upon the system performances, a set of three reference turboelectric systems were selected for comparison. Those considered for both extreme bounds of the explored range of maximum heat source temperature (970 K and 1470 K), use a liquid metal cooled reactor (sodium or Nak and lithium respectively) and the basic features of the 200 kWe system. In addition to both liquid metal cooled systems, a third system using a gas cooled epithermal particle bed reactor, to drive a direct cycle conversion system with a turbine inlet temperature of 1120 K is being investigated; this system is intended to make full use of the heat resisting materials and of the techniques, which have been developed for the high temperature gas cooled reactors

  10. Synthesis of Petroleum Sulfonate Surfactant with Ultra-Low Interfacial Tension in Rotating Packed Bed Reactor

    Institute of Scientific and Technical Information of China (English)

    Weng Zhan; Zhang Pengyuan; Chu Guangwen; Zou Haikui; Jimmy Yun; Chen Jianfeng

    2015-01-01

    Petroleum sulfonate is one of the most important surfactants used in surfactant lfooding for enhanced oil recov-ery, which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor (STR) or in a falling-iflm reactor (FFR). The synthesis of petroleum sulfonate with ultra-low interfacial tension from viscous petroleum fractions was carried out in a rotating packed bed (RPB) reactor using dilute liquid sulfur trioxide as the sulfonating agent in this study. The effects of various experimental conditions on components content and oil-water interfacial tension (IFT) were investigated. Under the optimum conditions, the active matter content could reach up to 50.3% and the IFT could be equal to 4.7×10−3 mN/m. Compared with the traditional reactor, the active matter content is by 14.12% higher in the RPB as compared to that obtained in the STR. The uneven change of the test oil droplets during the IFT measurement was also dis-cussed. The increase of heavy components content not only can eliminate the contraction phenomenon, but also can reduce the IFT to a minimum. This can be conducive to explaining the reason for producing IFT and the preparation of proper for-mulations for practical application.

  11. Acacia: A small scale power plant with pebble bed cartridge reactor and indirect Brayton cycle

    International Nuclear Information System (INIS)

    For markets other than large-scale electricity production a 60 MWth, 23 MWe (max.) nuclear plant design with an indirect Brayton cycle is proposed for application on the short to medium term. The reactor will be cooled by helium, whereas for the secondary cycle nitrogen is proposed as a heat carrier. In this way, a conventional air based gas turbine can be applied, while at the same time excluding the scenario of air ingress in the reactor core through a heat exchanger leak. Two variations of cycle design will be discussed: co-generation and maximized electricity production. The cogeneration mode will be elaborated for the application of seawater desalination. The reactor core geometry is annular with a central graphite reflector region, creating an optimal location for burnable poison. Optimization calculations on burnable poison distribution show that burnup of fuel and poison are balancing each other into a fairly constant reactivity behaviour during the entire core lifetime. Also, the two most important safety transient scenarios for pebble bed reactors, Pressurised and Depressurised Loss Of Forced Cooling, will be discussed. It will be shown that the maximum fuel temperatures will stay below the level where fuel damage starts for any point in time. (author)

  12. Simulation of the pebble bed modular reactor natural air convection passive heat removal system

    International Nuclear Information System (INIS)

    Cooling of the Pebble Bed Nuclear Reactor under evaluation in South Africa is primarily effected by the flow of helium through the cavity which contains the nuclear fuel. However, apart from this, a certain amount of heat flows from the reactor cavity, through the graphite barrel and reactor vessel to the containment building and ultimately to the environment During normal operation this passive heat loss represents approximately 1MW for a 100MW reactor and constitutes an undesirable loss of power. In the event of a shutdown or loss of main coolant, however, this passive heat removal is relied upon to remove the decay heat from the core. A study was initiated to simulate the process of this heat removal to provide an indication of the maximum vessel temperature and power transfers after shutdown. However, there is a lack of precise data indicating values for thermal conductivity, heat transfer coefficients, heat capacities or even densities. This paper describes the assumptions made and the manner in which these data were estimated so as to provide what is hoped to be a reasonably accurate estimate of the behaviour of the passive heat removal process. (author)

  13. Mathematical Modeling and Simulation of the Dehydrogenation of Ethyl Benzene to Form Styrene Using Steady-State Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Zaidon M. Shakoor

    2013-05-01

    Full Text Available In this research, two models are developed to simulate the steady state fixed bed reactor used for styrene production by ethylbenzene dehydrogenation. The first is one-dimensional model, considered axial gradient only while the second is two-dimensional model considered axial and radial gradients for same variables.The developed mathematical models consisted of nonlinear simultaneous equations in multiple dependent variables. A complete description of the reactor bed involves partial, ordinary differential and algebraic equations (PDEs, ODEs and AEs describing the temperatures, concentrations and pressure drop across the reactor was given. The model equations are solved by finite differences method. The reactor models were coded with Mat lab 6.5 program and various numerical techniques were used to obtain the desired solution.The simulation data for both models were validated with industrial reactor results with a very good concordance.

  14. Suspended-Bed Reactor preliminary design, 233U--232Th cycle. Final report (revised)

    International Nuclear Information System (INIS)

    The preliminary design Suspended-Bed Reactor is described. Coated particles about 2 mm in diameter are used as the fuel. The coatings consist of three layers: (1) low density pyrolytic graphite, 70 μ thick, (2) silicon carbide pressure vessel, 30 μ thick, and (3) ZrC layer, 50 μ thick, to protect the pressure vessel from moisture and oxygen. The fuel kernel can be either uranium-thorium dicarbide or metal. The coated particles are suspended by helium gas (coolant) in a cluster of pressurized tubes. The upward flow of helium fluidizes the coated particles. As the flow rate increases, the bed of particles is lifted upward to the core section. The particles are restrained at the upper end of the core by a suitable screen. The overall particle density in the core is just enough for criticality condition. Should the helium flow cease, the bed in the core section will collapse, and the particles will flow downward into the section where the increased physical spacings among the tubes brings about a safe shutdown. By immersing this section of the tubes in a large graphite block to serve as a heat sink, dissipation of decay heat becomes manageable. This eliminates the need for emergency core cooling systems

  15. Production and optimization of biodiesel using mixed immobilized biocatalysts in packed bed reactor.

    Science.gov (United States)

    Bakkiyaraj, S; Syed, Mahin Basha; Devanesan, M G; Thangavelu, Viruthagiri

    2016-05-01

    Vegetable oils are used as raw materials for biodiesel production using transesterification reaction. Several methods for the production of biodiesel were developed using chemical (alkali and acidic compounds) and biological catalysts (lipases). Biodiesel production catalyzed by lipases is energy and cost-saving processes and is carried out at normal temperature and pressure. The need for an efficient method for screening larger number of variables has led to the adoption of statistical experimental design. In the present study, packed bed reactor was designed to study with mixed immobilized biocatalysts to have higher productivity under optimum conditions. Contrary to the single-step acyl migration mechanism, a two-step stepwise reaction mechanism involving immobilized Candida rugosa lipase and immobilized Rhizopus oryzae cells was employed for the present work. This method was chosen because enzymatic hydrolysis followed by esterification can tolerate high free fatty acid containing oils. The effects of flow rate and bed height on biodiesel yield were studied using two factors five-level central composite design (CCD) and response surface methodology (RSM). Maximum biodiesel yield of 85 and 81 % was obtained for jatropha oil and karanja oil with the optimum bed height and optimum flow rate of 32.6 cm and 1.35 L/h, and 32.6 cm and 1.36 L/h, respectively. PMID:25940482

  16. Synthesis of a nanosilica supported CO2 sorbent in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Highlights: • CaO coating at atmospheric pressure is applied on silica nanoparticles in a fluidized bed. • Atmospheric pressure would facilitate scaling-up of the process. • The conditions for the coating process at atmospheric pressure are discussed. • The CO2 sorbent capacity is demonstrated by TGA in carbonation/calcination. • STEM-EDX shows the presence of CaO on the surface of the nanoparticles. - Abstract: CaO has been deposited on a nanosilica powder matrix by a procedure based on atomic layer deposition (ALD) in a fluidized bed reactor at atmospheric pressure following a potentially scalable process. In previous works ALD in gas fluidized bed has been mostly performed under reduced pressure, which hampers scaling-up the production technology. The material synthesized in the present work is tested as CO2 solid sorbent at calcium looping conditions. Multicyclic thermogravimetric analysis (TGA) shows that the nanosilica support stabilizes the capture capacity of CaO. EDX-STEM analysis illustrates the presence of Ca well distributed on the surface of the SiO2 nanoparticles

  17. Simulation of gas-solid fluidized bed reactor for F-T synthesis

    Institute of Scientific and Technical Information of China (English)

    CAI Jin; LI Tao; SUN Qi-wen; YING Wei-yong; FANG Ding-ye

    2009-01-01

    Using the lumping method, OH4, O3H8, O10H22, and C22H44 were chosen as the model products, and CO as the key component. The mathematical model of a gas-solid fluidized bed reactor was established based on some hypotheses. The consumption kinetic model of CO was investigated, and the parameters were estimated by Universal Global Optimization with the Marquardt method. Residual error distribution and a statistical test show that the intrinsic kinetic models are reliable and acceptable. A model of carbon chain growth probability was established in terms of experiments. Coupled with the Ander-son- Schulz-Flory (ASF) distribution, the amount of specific product could be obtained. Large- scale cold model experiments were conducted to investigate the distribution of the gas (solid) phase and determine the function of the voidage with the location of the catalytic bed. The change tendencies of the components in the catalytic bed at different temperatures were computed and figured out. The calculated value computed by the model established for the Fe-based F-T synthesis catalyst fit the experimental value very well under the same operating conditions, and all the absolute values of the relative deviations are less than 5%.

  18. Characteristic Studies of Micron Zinc Particle Hydrolysis in a Fixed Bed Reactor

    Directory of Open Access Journals (Sweden)

    Lv Ming

    2015-09-01

    Full Text Available Zinc fuel is considered as a kind of promising energy sources for marine propeller. As one of the key steps for zinc marine energy power system, zinc hydrolysis process had been studied experimentally in a fixed bed reactor. In this study, we focus on the characteristics of micron zinc particle hydrolysis. The experimental results suggested that the steam inner diffusion is the controlling step of accumulative zinc particles hydrolysis reaction at a relative lower temperature and a relative higher water partial pressure. In other conditions, the chemical reaction kinetics was the controlling step. And two kinds of chemical reaction kinetics appeared in experiments: the surface reaction and the gas-gas reaction. The latter one occurs usually for larger zinc particles and high reaction temperature. Temperature seems to be one of the most important parameters for the dividing of different reaction mechanisms. Several parameters of the hydrolysis process including heating rate, water partial pressure, the particle size and temperature were also studied in this paper. Results show that the initial reaction temperature of zinc hydrolysis in fixed bed is about 410°C. And the initial reaction temperature increases as the heating rate increases and as the water partial pressure decreases. The total hydrogen yield increases as the heating rate decreases, as the water partial pressure increases, as the zinc particle size decreases, and as the reaction temperature increases. A hydrogen yield of more than 81.5% was obtained in the fixed bed experiments.

  19. Enrichment and isotope separation of tritium between hydrogen and liquid water in trikle bed reactor

    International Nuclear Information System (INIS)

    The tritium produced by ternary fission within pent fuel will be in most part as HTO form in aqueous effluents of the reprocessing plant. Its decharge to the environment will prove detrimental and studies have been undertaken to develop techniques to confine it and process it. For confining tritium in small volumes of aqueous effluents, a special study has been achieved using the ELEX process which should be adapted for use in the design of reprocessing plant. This process is a combination of water electrolysis and tritium exchange between hydrogen and liquid water in contre - courant trikle bed reactor in presence of platined hydrophobic catalyst. Experiments carried out have enabled : demonstration of the effectiveness of platined hydrophobic catalyst in isotope exchange and separation reaction of tritium between hydrogen and liquid water. Development of a pretreatment method of aqueous effluents that have to be detriliated to eliminate impurities which would be detrimental to the ELEX process system by accumulating in the electrolyser and being absorbed in the exchange column. To check hydrodynamical functionment for contre-courant flow system water-hydrogen in trikle bed reactor

  20. Mechanism analysis of quasi-static dense pebble flow in pebble bed reactor using phenomenological approach

    International Nuclear Information System (INIS)

    Highlights: ► We introduced four basic forms of phenomenological method for pebble flow. ► We discussed the physical nature of the quasi-static pebble flow. ► We verified the applicability of the discrete element method. ► We investigated the parameter effects on quasi-static pebble flow. - Abstract: By means of the four basic forms of the phenomenological method, experimental results have intuitionally disclosed the physical mechanism from various views of the quasi-static pebble flow in a pebble bed reactor and successfully verified the availability of the discrete element method, on which the parameter effects have been investigated, including different base cone angle and different friction coefficient. The flow fields under different parameters have been discussed. On the basis of these researches, a framework of the general understanding of pebble flow mechanism has been drawn; many essential problems are discussed, including the interpretation of the quasi-static pebble flow, force analysis inside the pebble packing, propagation and distribution of the voids, internal equilibrium arches, competition mechanism, internal collapse, self-organization, equivalent shear force, equivalent normal force, the physical process of stagnant zone's influence on the overall flow field, and so on. All of these are very helpful to understand the physical mechanism of the quasi-static pebble flow in a pebble bed reactor.

  1. High temperature CO2 capture using calcium oxide sorbent in a fixed-bed reactor.

    Science.gov (United States)

    Dou, Binlin; Song, Yongchen; Liu, Yingguang; Feng, Cong

    2010-11-15

    The gas-solid reaction and breakthrough curve of CO(2) capture using calcium oxide sorbent at high temperature in a fixed-bed reactor are of great importance, and being influenced by a number of factors makes the characterization and prediction of these a difficult problem. In this study, the operating parameters on reaction between solid sorbent and CO(2) gas at high temperature were investigated. The results of the breakthrough curves showed that calcium oxide sorbent in the fixed-bed reactor was capable of reducing the CO(2) level to near zero level with the steam of 10 vol%, and the sorbent in CaO mixed with MgO of 40 wt% had extremely low capacity for CO(2) capture at 550°C. Calcium oxide sorbent after reaction can be easily regenerated at 900°C by pure N(2) flow. The experimental data were analyzed by shrinking core model, and the results showed reaction rates of both fresh and regeneration sorbents with CO(2) were controlled by a combination of the surface chemical reaction and diffusion of product layer. PMID:20724072

  2. Thermal-hydraulic analysis of the pellet bed reactor for nuclear thermal propulsion

    Energy Technology Data Exchange (ETDEWEB)

    Morley, N.J. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, NM 87131-1341 (United States)); El-Genk, M.S. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, NM 87131-1341 (United States))

    1994-09-01

    A two-dimensional steady-state thermal-hydraulics analysis of the pellet bed reactor for nuclear thermal propulsion is performed using the NUTHAM- S thermal-hydraulic code. The effects of axial heat and momentum transfers on the temperature and flow fields in the core are investigated. In addition, the porosity profile in the hot frit is optimized to avoid the development of a hot spot in the reactor core. Finally, a sensitivity analysis is performed using the optimized hot frit porosity profile to determine the effects of varying the propellant and core parameters on the peak fuel temperature and pressure drop across the core. These parameters include the inlet temperature and mass flow rate of the hydrogen propellant, average porosity of the core bed, the porosity of the hot frit, and local hot frit blockage. The peak temperature of the fuel is shown not to exceed its melting point as a result of changing any of these parameters from the base case, with the exception of hot frit blockage greater than 60% over a 0.12m axial segment of the hot frit. ((orig.))

  3. Determination of the enzyme reaction rate in a differential fixed-bed reactor: a case study

    Directory of Open Access Journals (Sweden)

    Baruque Filho E.A.

    2001-01-01

    Full Text Available The reaction rate of starch hydrolysis catalyzed by a glucoamylase covalently bound to chitin particles was measured in a Differential Fixed-Bed Reactor (DFBR. Under selected test conditions the initial reaction rate may represent biocatalyst activity. Some aspects which influence measurement of the initial reaction rate of an immobilized enzyme were studied: the amount of desorbed enzyme and its hydrolytic activity, the extent of pore blockage of the biocatalyst caused by substrate solution impurities and the internal and external diffusional mass transfer effects. The results showed that the enzyme glucoamylase was firmly bound to the support, as indicated by the very low amount of desorbed protein found in the recirculating liquid. Although this protein was very active, its contribution to the overall reaction rate was negligible. It was observed that the biocatalyst pores were susceptible to being blocked by the impurities of the starch solution. This latter effect was accumulative, increasing with the number of sequential experiments carried out. When the substrate solution was filtered before use, very reliable determinations of immobilized enzyme reaction rates could be performed in the DFBR. External and internal diffusional resistences usually play a significant role in fixed-bed reactors. However, for the experimental system studied, internal mass transfer effects were not significant, and it was possible to select an operational condition (recirculation flow rate value that minimized the external diffusional limitations.

  4. Modular pebble-bed reactor reforming plant design for process heat

    International Nuclear Information System (INIS)

    This report describes a preliminary design study of a Modular Pebble-Bed Reactor System Reforming (MPB-R) Plant. The system uses one pressure vessel for the reactor and a second pressure vessel for the components, i.e., reformer, steam generator and coolant circulator. The two vessels are connected by coaxial pipes in an arrangement known as the side-by-side (SBS). The goal of the study is to gain an understanding of this particular system and to identify any technical issues that must be resolved for its application to a modular reformer plant. The basic conditions for the MPB-R were selected in common with those of the current study of the MRS-R in-line prismatic fuel concept, specifically, the module core power of 250 MWt, average core power density of 4.1 w/cc, low enriched uranium (LEU) fuel with a 235U content of 20% homogeneously mixed with thorium, and a target burnup of 80,000 MWD/MT. Study results include the pebble-bed core neutronics and thermal-hydraulic calculations. Core characteristics for both the once-through-then-out (OTTO) and recirculation of fuel sphere refueling schemes were developed. The plant heat balance was calculated with 55% of core power allotted to the reformer

  5. Immobilized glucose oxidase--catalase and their deactivation in a differential-bed loop reactor.

    Science.gov (United States)

    Prenosil, J E

    1979-01-01

    Glucose oxidase containing catalase was immobilized with a copolymer of phenylenediamine and glutaraldehyde on pumice and titania carrier to study the enzymatic oxidation of glucose in a differential-bed loop reactor. The reaction rate was found to be first order with respect to the concentration of limiting oxygen substrate, suggesting a strong external mass-transfer resistance for all the flow rates used. The partial pressure of oxygen was varied from 21.3 up to 202.6 kPa. The use of a differential-bed loop reactor for the determination of the active enzyme concentration in the catalyst with negligible internal pore diffusion resistance is shown. Catalyst deactivation was studied, especially with respect to the presence of catalase. It is believed that the hydrogen peroxide formed in the oxidation reaction deactivates catalase first; if an excess of catalase is present, the deactivation of glucose oxidase remains small. The mathematical model subsequently developed adequately describes the experimental results. PMID:427262

  6. Removal of CO2 in a multistage fluidized bed reactor by diethanol amine impregnated activated carbon.

    Science.gov (United States)

    Das, Dipa; Samal, Debi Prasad; Meikap, Bhim C

    2016-07-28

    To mitigate the emission of carbon dioxide (CO2), we have developed and designed a four-stage fluidized bed reactor. There is a counter current exchange between solid adsorbent and gas flow. In this present investigation diethanol amine (DEA) impregnated activated carbon made from green coconut shell was used as adsorbent. This type of adsorbent not only adsorbs CO2 due to the presence of pore but also chemically reacts with CO2 and form secondary zwitterions. Sampling and analysis of CO2 was performed using Orsat apparatus. The effect of initial CO2 concentration, gas velocity, solid rate, weir height etc. on removal efficiency of CO2 have been investigated and presented. The percentage removal of CO2 has been found close to 80% under low gas flow rate (0.188 m/s), high solid flow rate (4.12 kg/h) and weir height of 50 mm. From this result it has been found out that multistage fluidized bed reactor may be a suitable equipment for removal of CO2 from flue gas. PMID:27163861

  7. Modelisation of Nitrification under Inhibited Environment by Moving Bed Bio-Film Reactor Technique

    Directory of Open Access Journals (Sweden)

    Pham T.H. Duc

    2010-01-01

    Full Text Available Problem statement: Nitrification by Moving Bed Biofilm Reactor (MBBR involves physical, chemical and biological processes to remove toxic ammonia for aquaculture that are governed by a variety of parameters, like substrate and dissolved oxygen concentrations, organic matters, temperature, pH, alkalinity and turbulence level, which impact negatively or positively on nitrification kinetics. Approach: The situation becomes more serious as the reaction rate is inhibited by low ammonium concentration and high salinity. That problems usually occur in treatment systems of aquatic breeding hatcheries. Results: In this study, experiments have been conducted to evaluate the impact of salinity on nitrification rate through kinetic constant (k and reaction order (n based on general equation v = kCn. Moving bed biofilm reactor was operated continuously at same initial amounts of nitrogen and Phosphorus very low (oligotrophic conditions. Firstly, over view the impact of salinity on kinetic rate to modeling that effect k and n to modelisation that affects and obtained the impact of salinity content in the reaction medium (X and the acclimatization phase (Y on the kinetic constant (k = 0.097 e (-0.0003Yƒ{0.0346X and on the kinetic order (n = (0.0002Y-0.0195 X-0.009Y + 1.2382. Conclusion/Recommendations: Results from kinetic analysis allowed the prediction of the reaction rate and reaction yield with rather high accuracy, helping the design and operation of a biofilter under practical conditions.

  8. METHODS FOR MODELING THE PACKING OF FUEL ELEMENTS IN PEBBLE BED REACTORS

    Energy Technology Data Exchange (ETDEWEB)

    Abderrafi M. Ougouag; Joshua J. Cogliati; Jan-Leen Kloosterman

    2005-09-01

    Two methods for the modeling of the packing of pebbles in the pebble bed reactors are presented and compared. The first method is based on random generation of potential centers for the pebbles, followed by rejection of points that are not compatible with the geometric constraint of no (or limited) pebbles overlap. The second method models the actual physical packing process, accounting for the dynamic of pebbles as they are dropped onto the pebble bed and as they settle therein. A simplification in the latter model is the assumption of a starting point with very dilute packing followed by settling. The results from the two models are compared and the properties of the second model and the dependence of its results on many of the modeling parameters are presented. The first model (with no overlap allowed) has been implemented into a code to compute Dancoff factors. The second model will soon be implemented into that same code and will also be used to model flow of pebbles in a reactor and core densification in the simulation of earthquakes. Both methods reproduce experimental values well, with the latter displaying a high level of fidelity.

  9. High temperature CO2 capture using calcium oxide sorbent in a fixed-bed reactor

    International Nuclear Information System (INIS)

    The gas-solid reaction and breakthrough curve of CO2 capture using calcium oxide sorbent at high temperature in a fixed-bed reactor are of great importance, and being influenced by a number of factors makes the characterization and prediction of these a difficult problem. In this study, the operating parameters on reaction between solid sorbent and CO2 gas at high temperature were investigated. The results of the breakthrough curves showed that calcium oxide sorbent in the fixed-bed reactor was capable of reducing the CO2 level to near zero level with the steam of 10 vol%, and the sorbent in CaO mixed with MgO of 40 wt% had extremely low capacity for CO2 capture at 550 deg. C. Calcium oxide sorbent after reaction can be easily regenerated at 900 deg. C by pure N2 flow. The experimental data were analyzed by shrinking core model, and the results showed reaction rates of both fresh and regeneration sorbents with CO2 were controlled by a combination of the surface chemical reaction and diffusion of product layer.

  10. Safeguards Challenges for Pebble-Bed Reactors (PBRs):Peoples Republic of China (PRC)

    Energy Technology Data Exchange (ETDEWEB)

    Forsberg, Charles W. [Massachusetts Institute of Technology (MIT); Moses, David Lewis [ORNL

    2009-11-01

    The Peoples Republic of China (PRC) is operating the HTR-10 pebble-bed reactor (PBR) and is in the process of building a prototype PBR plant with two modular reactors (250-MW(t) per reactor) feeding steam to a single turbine-generator. It is likely to be the first modular hightemperature reactor to be ready for commercial deployment in the world because it is a highpriority project for the PRC. The plant design features multiple modular reactors feeding steam to a single turbine generator where the number of modules determines the plant output. The design and commercialization strategy are based on PRC strengths: (1) a rapidly growing electric market that will support low-cost mass production of modular reactor units and (2) a balance of plant system based on economics of scale that uses the same mass-produced turbine-generator systems used in PRC coal plants. If successful, in addition to supplying the PRC market, this strategy could enable China to be the leading exporter of nuclear reactors to developing countries. The modular characteristics of the reactor match much of the need elsewhere in the world. PBRs have major safety advantages and a radically different fuel. The fuel, not the plant systems, is the primary safety system to prevent and mitigate the release of radionuclides under accident conditions. The fuel consists of small (6-cm) pebbles (spheres) containing coatedparticle fuel in a graphitized carbon matrix. The fuel loading per pebble is small (~9 grams of low-enriched uranium) and hundreds of thousands of pebbles are required to fuel a nuclear plant. The uranium concentration in the fuel is an order of magnitude less than in traditional nuclear fuels. These characteristics make the fuel significantly less attractive for illicit use (weapons production or dirty bomb); but, its unusual physical form may require changes in the tools used for safeguards. This report describes PBRs, what is different, and the safeguards challenges. A series of

  11. Partial oxidation of Raffinate II and other mixtures of n-Butane and n-Butenes to maleic anhydride in a fixed-bed reactor

    OpenAIRE

    Brandstädter, Willi Michael

    2008-01-01

    The utilisation of the C4 streams of steamcrackers by converting raffinate II to maleic anhydride was studied. The oxidation reactions were investigated in a laboratory-scale fixed-bed reactor to determine reaction kinetics. The effects of pore diffusional resistance were investigated and explained. A two-dimensional pseudo-homogeneous reactor model was used for the simulation of a production-scale fixed-bed reactor. A flow scheme of the reactor section including a recycle was proposed.

  12. Progress in the Development of the Modular Pebble-Bed Advanced High Temperature Reactor

    International Nuclear Information System (INIS)

    This review article summarizes recent progress by students and faculty at U.C. Berkeley working on the development of the Pebble-Bed Advanced High Temperature Reactor (PB-AHTR). The 410-MWe PBAHTR is a liquid salt cooled reactor that operates at near atmospheric pressure and high power density (20 to 30 MW/m3, compared to 4.8 MW/m3 for helium cooled reactors). Operating with a core inlet temperature of 600 deg. C and outlet temperature of 704 deg. C, the PB-AHTR uses well understood materials of construction including Alloy 800H with Hastelloy N cladding for the reactor vessel and primary loop components, and graphite for core and reflector structures. Recent work by the NE 170 senior design class has developed physical arrangements for the major reactor and power conversion components, along with the structural design for the reactor building and turbine hall featuring seismic base isolation, design for aircraft crash protection, shielding analysis, and design of a multiple-zone ventilation and containment system to provide effective control of radioactive and chemical contamination. The resulting total building volume is 260 m3/MWe, compared to 343 m3/MWe to 486 m3/MWe for current large (1150 to 1600 MWe) LWR designs. These results suggest the potential for significant reductions in construction time and cost. Neutronics studies have verified the capability to design the PB-AHTR with negative fuel and coolant temperature reactivity coefficients, for both LEU and deep-burn TRU fuels. Depletion analysis was also performed to identify optimal core designs to maximize fuel utilization. The additional moderation provided by the coolant simplifies design to achieve optimal moderation, and the spent fuel volume is approximately half that of helium cooled reactors. In collaboration with the Czech Nuclear Research Institute, initial zero-power critical tests were performed to validate PB-AHTR neutronics models. Liquid salts are unique among candidate reactor coolants due

  13. Pore Scale Thermal Hydraulics Investigations of Molten Salt Cooled Pebble Bed High Temperature Reactor with BCC and FCC Configurations

    Directory of Open Access Journals (Sweden)

    Shixiong Song

    2014-01-01

    CFD results and empirical correlations’ predictions of pressure drop and local Nusselt numbers. Local pebble surface temperature distributions in several default conditions are investigated. Thermal removal capacities of molten salt are confirmed in the case of nominal condition; the pebble surface temperature under the condition of local power distortion shows the tolerance of pebble in extreme neutron dose exposure. The numerical experiments of local pebble insufficient cooling indicate that in the molten salt cooled pebble bed reactor, the pebble surface temperature is not very sensitive to loss of partial coolant. The methods and results of this paper would be useful for optimum designs and safety analysis of molten salt cooled pebble bed reactors.

  14. Process development and modeling of fluidized-bed reactor with coimmobilized biocatalyst for fuel ethanol production

    Science.gov (United States)

    Sun, May Yongmei

    This research focuses on two steps of commercial fuel ethanol production processes: the hydrolysis starch process and the fermentation process. The goal of this research is to evaluate the performance of co-immobilized biocatalysts in a fluidized bed reactor with emphasis on economic and engineering aspects and to develop a predictive mathematical model for this system. The productivity of an FBR is higher than productivity of a traditional batch reactor or CSTR. Fluidized beds offer great advantages over packed beds for immobilized cells when small particles are used or when the reactant feed contains suspended solids. Plugging problems, excessive pressure drops (and thus attrition), or crushing risks may be avoided. No mechanical stirring is required as mixing occurs due to the natural turbulence in the fluidized process. Both enzyme and microorganism are immobilized in one catalyst bead which is called co-immobilization. Inside this biocatalyst matrix, starch is hydrolyzed by the enzyme glucoamylase to form glucose and then converted to ethanol and carbon dioxide by microorganisms. Two biocatalysts were evaluated: (1) co-immobilized yeast strain Saccharomyces cerevisiae and glucoamylase. (2) co-immobilized Zymomonas mobilis and glucoamylase. A co-immobilized biocatalyst accomplishes the simultaneous saccharification and fermentation (SSF process). When compared to a two-step process involving separate saccharification and fermentation stages, the SSF process has productivity values twice that given by the pre-saccharified process when the time required for pre-saccharification (15--25 h) was taken into account. The SSF process should also save capital cost. The information about productivity, fermentation yield, concentration profiles along the bed, ethanol inhibition, et al., was obtained from the experimental data. For the yeast system, experimental results showed that: no apparent decrease of productivity occurred after two and half months, the productivity

  15. Modeling phosphorus removal and recovery from anaerobic digester supernatant through struvite crystallization in a fluidized bed reactor.

    Science.gov (United States)

    Rahaman, Md Saifur; Mavinic, Donald S; Meikleham, Alexandra; Ellis, Naoko

    2014-03-15

    The cost associated with the disposal of phosphate-rich sludge, the stringent regulations to limit phosphate discharge into aquatic environments, and resource shortages resulting from limited phosphorus rock reserves, have diverted attention to phosphorus recovery in the form of struvite (MAP: MgNH4PO4·6H2O) crystals, which can essentially be used as a slow release fertilizer. Fluidized-bed crystallization is one of the most efficient unit processes used in struvite crystallization from wastewater. In this study, a comprehensive mathematical model, incorporating solution thermodynamics, struvite precipitation kinetics and reactor hydrodynamics, was developed to illustrate phosphorus depletion through struvite crystal growth in a continuous, fluidized-bed crystallizer. A thermodynamic equilibrium model for struvite precipitation was linked to the fluidized-bed reactor model. While the equilibrium model provided information on supersaturation generation, the reactor model captured the dynamic behavior of the crystal growth processes, as well as the effect of the reactor hydrodynamics on the overall process performance. The model was then used for performance evaluation of the reactor, in terms of removal efficiencies of struvite constituent species (Mg, NH4 and PO4), and the average product crystal sizes. The model also determined the variation of species concentration of struvite within the crystal bed height. The species concentrations at two extreme ends (inlet and outlet) were used to evaluate the reactor performance. The model predictions provided a reasonably good fit with the experimental results for PO4-P, NH4-N and Mg removals. Predicated average crystal sizes also matched fairly well with the experimental observations. Therefore, this model can be used as a tool for performance evaluation and process optimization of struvite crystallization in a fluidized-bed reactor. PMID:24384559

  16. Alkylation of Benzene with Propylene in a Flow-Through Membrane Reactor and Fixed-Bed Reactor: Preliminary Results

    Directory of Open Access Journals (Sweden)

    Sibele Pergher

    2012-05-01

    Full Text Available Benzene alkylation with propylene was studied in the gas phase using a catalytic membrane reactor and a fixed-bed reactor in the temperature range of 200–300 °C and with a weight hourly space velocity (WHSV of 51 h−1. β-zeolite was prepared by hydrothermal synthesis using silica, aluminum metal and TEAOH as precursors. The membrane’s XRD patterns showed good crystallinity for the β-zeolite film, while scanning electron microscopy SEM results indicated that its random polycrystalline film was approximately 1 μm thick. The powders’ specific area was determined to be 400 m2×g−1 by N2 adsorption/desorption, and the TPD results indicated an overall acidity of 3.4 mmol NH3×g−1. Relative to the powdered catalyst, the catalytic membrane showed good activity and product selectivity for cumene.

  17. Flow distribution of pebble bed high temperature gas cooled reactors using large eddy simulation

    International Nuclear Information System (INIS)

    A High Temperature Gas-cooled Reactor (HTGR) is one of the renewed reactor designs to play a role in nuclear power generation. This reactor design concepts is currently under consideration and development worldwide. Since the HTGR concept offers inherent safety, has a very flexible fuel cycle with capability to achieve high burnup levels, and provides good thermal efficiency of power plant, it can be considered for further development and improvement as a reactor concept of generation IV. The combination of coated particle fuel, inert helium gas as coolant and graphite moderated reactor makes it possible to operate at high temperature yielding a high efficiency. In this study the simulation of turbulent transport for the gas through the gaps of the spherical fuel elements (fuel pebbles) will be performed. This will help in understanding the highly three-dimensional, complex flow phenomena in pebble bed caused by flow curvature. Under these conditions, heat transfer in both laminar and turbulent flows varies noticeably around curved surfaces. Curved flows would be present in the presence of contiguous curved surfaces. In the case of a laminar flow and of an appreciable effect of thermogravitional forces, the Nusselt (Nu) number depends significantly on the curvature shape of the surface. It changes with order of 10 times. The flow passages through the gap between the fuel balls have concave and convex configurations. Here the action of the centrifugal forces manifests itself differently on convex and concave parts of the flow path (suppression or stimulation of turbulence). The flow of this type has distinctive features. In such flow there is a pressure gradient, which strongly affects the boundary layer behavior. The transition from a laminar to turbulent flow around this curved flow occurs at deferent Reynolds (Re) numbers. Consequently, noncircular curved flows as in the pebble-bed situation, in detailed local sense, is interesting to be investigated. To the

  18. 3D DEM simulation and analysis of void fraction distribution in a pebble bed high temperature reactor

    International Nuclear Information System (INIS)

    Highlights: • We show a detailed analysis of void fraction (VF) in HTR-10 of China using DEM. • Radial distribution (RD) of VF is uniform in the core and oscillated near the wall. • Axial distribution (AD) is linearly varied along height due to effect of gravity. • Steady RD of VF in the conical base is Gaussian-like, larger than packing bed. • Joint linear and normal distribution of VF is analyzed and explained. - Abstract: The current work analyzes the radial and axial distributions of void fraction of a pebble bed high temperature reactor. A three-dimensional pebble bed corresponding to our test facility of pebble bed type gas-cooled high temperature reactor (HTR-10) in Tsinghua University is simulated via discrete element method, and the radial and axial void fraction profiles are calculated. It validates the oscillating characteristics of radial void fraction near the wall. Detailed calculations show the differences of void fraction profiles between the stationary packing bed and the dynamically discharging bed. Based on the vertically and circumferentially averaged radial distribution and horizontally averaged axial distribution of void fraction, a fully three-dimensional analytical distribution of void fraction throughout the bed is established. The results show the combined effects of gravity and void variation in the pebble bed caused by the pebble discharging. It indicates the linearly increased packing effect caused by gravity in the vertical (axial) direction and the normal distribution of void in the horizontal (radial) direction by pebble drainage. These two effects coexist in the conical base of the bed whereas only the former effect exists in the cylindrical volume of the bed

  19. High temperature gas-cooled pebble bed reactor steady state thermal-hydraulics analyses based on CFD method

    International Nuclear Information System (INIS)

    Background: Based on general purpose CFD code Fluent, the PBMR-400 full load nominal condition thermal-hydraulics performance was studied by applying local thermal non-equilibrium porous media model. Purpose: In thermal hydraulics study of the gas cooled pebble bed reactor, the core of the reactor can be treated as macroscopic porous media with strong inner heat source, and the original Fluent code can not handle it properly. Methods: By introducing a UDS in the calculation domain of the reactor core and subjoining a new resistance term, we develop a non-equilibrium porous media model which can give an accurate description of the core of the pebble bed. The mesh of CFD code is finer than that of the traditional pebble bed reactor thermal hydraulics analysis code such as THERMIX and TINTE, thus more information about coolant velocity fields, temperature field and solid phase temperature field can be acquired. Results: The nominal condition calculation results of the CFD code are compared to those of the well-established thermal-hydraulic code THERMIX and TINTE, and show a good consistency. Conclusion: The extended local thermal non-equilibrium model can be used to analyse thermal-hydraulics of high temperature pebble bed type reactor. (authors)

  20. Simulation and control of water-gas shift packed bed reactor with inter-stage cooling

    Science.gov (United States)

    Saw, S. Z.; Nandong, J.

    2016-03-01

    Water-Gas Shift Reaction (WGSR) has become one of the well-known pathways for H2 production in industries. The issue with WGSR is that it is kinetically favored at high temperatures but thermodynamically favored at low temperatures, thus requiring careful consideration in the control design in order to ensure that the temperature used does not deactivate the catalyst. This paper studies the effect of a reactor arrangement with an inter-stage cooling implemented in the packed bed reactor to look at its effect on outlet temperature. A mathematical model is developed based on one-dimensional heat and mass transfers which incorporate the intra-particle effects. It is shown that the placement of the inter-stage cooling and the outlet temperature exiting the inter-stage cooling have strong influence on the reaction conversion. Several control strategies are explored for the process. It is shown that a feedback- feedforward control strategy using Multi-scale Control (MSC) is effective to regulate the reactor temperature profile which is critical to maintaining the catalysts activity.

  1. Denitrification of groundwater using PHBV blends in packed bed reactors and the microbial diversity.

    Science.gov (United States)

    Chu, Libing; Wang, Jianlong

    2016-07-01

    In the present study, three kinds of biopolymers, PHBV, PHBV/starch and PHBV/bamboo powder (BP) blends were used as carbon source and biofilm carriers for denitrification in packed bed reactors to remove nitrate from groundwater. Results showed that a fast start-up was obtained in bioreactors filled with both PHBV/Starch and PHBV/BP blends without external inocula and it took more than 3 month for PHBV reactor to reach the same loading rate. The PHBV/BP packed reactor exhibited a better nitrate removal efficiency (87.4 ± 7.0%) and less adverse effects in nitrite accumulation and DOC release (below 0.5 mg NO2N L(-1) and 10.5 mg DOC L(-1) in the effluent) during stable operation. Pyrosequencing analysis demonstrated that bacteria belonging to genus Clostridium in phylum Firmicus, which play the primary role in degrading the biopolymers, are the most dominant (33-15% of the sequences). The predominant species in all samples is related to Clostridium crotonatovorans. All the identified 11 genera of denitrifying bacteria affiliated with phylum Proteobacteria and constituted 30-55% in the representative sequences. The PHBV/BP blend is economically attractive carbon source with good denitrification performance. PMID:27145420

  2. Dual susbstrate limitations in upflow packed-bed biofilm reactors - a theoretical study

    Energy Technology Data Exchange (ETDEWEB)

    Beg, A.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Dept. of Chemical Engineering; Hassan, M.M. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Dept. of Chemical Engineering; Chaudhry, M.A.S. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Dept. of Chemical Engineering

    1997-01-01

    The performance of an upflow packed-bed biofilm reactor has been analyzed under dual substrate limitation conditions. The numerical solution of the proposed equations defining the system has been obtained for a wide range of operating conditions for a case of practical significance involving glucose and oxygen as dual substrates. The results show that the inlet glucose concentration defines the limiting substrate at a position near the inlet of the reactor. For inlet glucose concentrations up to 300 mg/l, glucose acts as the limiting substrate. However, for inlet concentrations of 400 mg/l of glucose or higher, oxygen assumes the role of the limiting substrate at that position. For all other positions in the reactor, glucose acts as the limiting substrate, irrespective of its inlet concentration. Extensive computations were performed in order to define regions where glucose, oxygen or both are limiting. The predicted results have been found to be in agreement with the theoretical criteria, proposed in the literature, of determining the limiting substrate. (orig.)

  3. Effect of hydraulic retention time on metal precipitation in sulfate reducing inverse fluidized bed reactors

    KAUST Repository

    Villa-Gómez, Denys Kristalia

    2014-02-13

    BACKGROUND: Metal sulfide recovery in sulfate reducing bioreactors is a challenge due to the formation of small precipitates with poor settling properties. The size of the metal sulfide precipitates with the change in operational parameters such as pH, sulfide concentration and reactor configuration has been previously studied. The effect of the hydraulic retention time (HRT) on the metal precipitate characteristics such as particle size for settling has not yet been addressed. RESULTS: The change in size of the metal (Cu, Zn, Pb and Cd) sulfide precipitates as a function of the HRT was studied in two sulfate reducing inversed fluidized bed (IFB) reactors operating at different chemical oxygen demand concentrations to produce high and low sulfide concentrations. The decrease of the HRT from 24 to 9h in both IFB reactors affected the contact time of the precipitates formed, thus making differences in aggregation and particle growth regardless of the differences in sulfide concentration. Further HRT decrease to 4.5h affected the sulfate reducing activity for sulfide production and hence, the supersaturation level and solid phase speciation. Metal sulfide precipitates affected the sulfate reducing activity and community in the biofilm, probably because of the stronger local supersaturation causing metal sulfides accumulation in the biofilm. CONCLUSIONS: This study shows that the HRT is an important factor determining the size and thus the settling rate of the metal sulfides formed in bioreactors.

  4. Fluidized Bed Membrane Reactors for Ultra Pure H₂ Production-A Step forward towards Commercialization.

    Science.gov (United States)

    Helmi, Arash; Fernandez, Ekain; Melendez, Jon; Pacheco Tanaka, David Alfredo; Gallucci, Fausto; van Sint Annaland, Martin

    2016-01-01

    In this research the performance of a fluidized bed membrane reactor for high temperature water gas shift and its long term stability was investigated to provide a proof-of-concept of the new system at lab scale. A demonstration unit with a capacity of 1 Nm³/h of ultra-pure H₂ was designed, built and operated over 900 h of continuous work. Firstly, the performance of the membranes were investigated at different inlet gas compositions and at different temperatures and H₂ partial pressure differences. The membranes showed very high H₂ fluxes (3.89 × 10(-6) mol·m(-2)·Pa(-1)·s(-1) at 400 °C and 1 atm pressure difference) with a H₂/N₂ ideal perm-selectivity (up to 21,000 when integrating five membranes in the module) beyond the DOE 2015 targets. Monitoring the performance of the membranes and the reactor confirmed a very stable performance of the unit for continuous high temperature water gas shift under bubbling fluidization conditions. Several experiments were carried out at different temperatures, pressures and various inlet compositions to determine the optimum operating window for the reactor. The obtained results showed high hydrogen recovery factors, and very low CO concentrations at the permeate side (in average <10 ppm), so that the produced hydrogen can be directly fed to a low temperature PEM fuel cell. PMID:27007361

  5. Anaerobic treatment of wastewater containing methanol in upflow anaerobic sludge bed (UASB) reactor

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The direct conversion of methanol into methane is the main process in anaerobic treatment of methanol containing wastewater.However,acetic acid can also be produced from methanol theoretically,which may probably result in an abrupt pH drop and deteriorate the anaerobic process.Therefore,it is interesting to know what would really happen in an anaerobic reactor treating methanol wastewater.In this study,an up-flow anaerobic sludge bed (UASB) reactor treating methanol wastewater was operated.The chemical oxygen demand (COD),acetic acid and pH of the effluent were monitored at different loadings and influent alkalinity.The results showed that the anaerobic reactor could be operated steadily at as low as 119 mg/L of influent alkalinity and high organic loading rate with no obvious pH drops.Volatile fatty acids accumulation was not observed even at strong shock loadings.The microorganisms in the sludge at the end of the test became homogeneous in morphology,which were mainly spherical or spheroidal in shape.

  6. Simultaneous Coproduction of Hydrogen and Ethanol in Anaerobic Packed-Bed Reactors

    Directory of Open Access Journals (Sweden)

    Cristiane Marques dos Reis

    2014-01-01

    Full Text Available This study evaluated the use of an anaerobic packed-bed reactor for hydrogen production at different hydraulic retention times (HRT (1–8 h. Two reactors filled with expanded clay and fed with glucose (3136–3875 mg L−1 were operated at different total upflow velocities: 0.30 cm s−1 (R030 and 0.60 cm s−1 (R060. The effluent pH of the reactors was maintained between 4 and 5 by adding NaHCO3 and HCl solutions. It was observed a maximum hydrogen production rate of 0.92 L H2 h−1 L−1 in R030 at HRT of 1 h. Furthermore, the highest hydrogen yield of 2.39 mol H2 mol−1 glucose was obtained in R060. No clear trend was observed by doubling the upflow velocities at this experiment. High ethanol production was also observed, indicating that the ethanol-pathway prevailed throughout the experiment.

  7. Pebble bed modular reactors versus other generation technologies. Costs and challenges for South Africa

    International Nuclear Information System (INIS)

    South Africa is Africa's major economy, with plans to double its electricity generation capacity by 2026. South Africa has spent almost two decades developing a nuclear reactor known as a Pebble Bed Modular Reactor (PBMR), which could provide substantial benefits to the electricity grid but was recently mothballed due to high costs. This work estimates the lifecycle financial costs of South African PBMRs, then compares these costs to those of five other generation options: coal, nuclear as pressurized water reactors (PWRs), wind, and solar as photovoltaics (PV) or concentrating solar power (CSP). Each technology is evaluated with low, base case, and high assumptions for capital costs, construction time, and interest rates. Decommissioning costs, project lifetime, capacity factors, and sensitivity to carbon price are also considered. PBMR could be cost competitive with coal under certain low cost conditions, even without a carbon price. However, international lending practices and other factors suggest that a high capital cost, high interest rate nuclear plant is likely to be competing with a low capital cost, low interest rate coal plant in a market where cost recovery is challenging. PBMR could potentially become more competitive if low rate international loans were available to nuclear projects or became unavailable to coal projects. (author)

  8. CFD analysis of hot spot formation through a fixed bed reactor of Fischer-Tropsch synthesis

    Directory of Open Access Journals (Sweden)

    Hamed Aligolzadeh

    2015-12-01

    Full Text Available One of the interesting methods for conversion of synthesis gas to heavy hydrocarbons is Fischer–Tropsch process. The process has some bottlenecks, such as hot spot formation and low degree of conversion. In this work, computational fluid dynamics technique was used to simulate conversion of synthetic gas and product distribution. Also, hot spot formation in the catalytic fixed-bed reactor was investigated in several runs. Simulation results indicated that hot spot formation occurred more likely in the early and middle part of reactor due to high reaction rates. Based on the simulation results, the temperature of hot spots increased with increase in the inlet temperature as well as pressure. Among the many CFD runs conducted, it is found that the optimal temperature and pressure for Fischer–Tropsch synthesis are 565 K and 20 bar, respectively. As it seems that the reactor shall work very well under optimal conditions, the reaction rates and catalyst duration would simultaneously be maximum .

  9. Improved Performances of a Fluidized Bed Photo reactor by a Microscale Illumination System

    International Nuclear Information System (INIS)

    The performances of a gas-solid two-dimensional fluidized bed reactor in photo catalytic selective oxidation reactions, irradiated with traditional UV lamps or with a microscale illumination system based on UV emitting diodes (UV A-LEDs), have been compared. In the photo catalytic oxidative dehydrogenation of cyclohexane to benzene on MoOx/TiO2-A12O3 catalyst the use of UV A-LEDs modules allowed to achieve a cyclohexane conversion and benzene yield higher than those obtained with traditional UV lamps. The better performances with UV A-LEDs are due to the UV A-LEDs small dimensions and small-angle emittance, which allow photons beam be directed towards the photo reactor windows, reducing the dispersion outside of photo reactor or the optical path length. As a consequence, the effectively illuminated mass of catalyst is greater. We have found that this illumination system is efficient for photo-oxidative dehydrogenation of cyclohexane to cyclohexene on sulphated MoOx-A12O3 and ethanol to acetaldehyde on VOx/TiO2.

  10. Optimization of a radially cooled pebble bed reactor - HTR2008-58117

    International Nuclear Information System (INIS)

    By altering the coolant flow direction in a pebble bed reactor from axial to radial, the pressure drop can be reduced tremendously. In this case the coolant flows from the outer reflector through the pebble bed and finally to flow paths in the inner reflector. As a consequence, the fuel temperatures are elevated due to the reduced heat transfer of the coolant. However, the power profile and pebble size in a radially cooled pebble bed reactor can be optimized to achieve lower fuel temperatures than current axially cooled designs, while the low pressure drop can be maintained. The radial power profile in the core can be altered by adopting multi-pass fuel management using several radial fuel zones in the core. The optimal power profile yielding a flat temperature profile is derived analytically and is approximated by radial fuel zoning. In this case, the pebbles pass through the outer region of the core first and each consecutive pass is located in a fuel zone closer to the inner reflector. Thereby, the resulting radial distribution of the fissile material in the core is influenced and the temperature profile is close to optimal. The fuel temperature in the pebbles can be further reduced by reducing the standard pebble diameter from 6 cm to a value as low as I cm. An analytical investigation is used to demonstrate the effects on the fuel temperature and pressure drop for both radial and axial cooling. Finally, two-dimensional numerical calculations were performed, using codes for neutronics, thermal-hydraulics and fuel depletion analysis, in order to validate the results for the optimized design that were obtained from the analytical investigations. It was found that for a radially cooled design with an optimized power profile and reduced pebble diameter (below 3.5 cm) both a reduction in the pressure drop (Δp = -2.6 bar), which increases the reactor efficiency with several percent, and a reduction in the maximum fuel temperature (ΔT = -50 deg. C) can be achieved

  11. Criticality and burn up evolutions of the Fixed Bed Nuclear Reactor with alternative fuels

    International Nuclear Information System (INIS)

    Time evolution of criticality and burn-up grades of the Fixed Bed Nuclear Reactor (FBNR) are investigated for alternative fuels. These are: (1) low enriched uranium, (2) weapon grade plutonium, (3) reactor grade plutonium, and (4) minor actinides in the spent fuel of light water reactors (LWRs). The criticality calculations are conducted with SCALE 5.1 using S8-P3 approximation in 238 neutron energy groups with 90 groups in thermal energy region. The main results of the study can be summarized as follows: (1)Low enriched uranium (UO2): FBNR with an enrichment grade of 9% and 19% will start with keff = 1.2744 and keff = 1.36 and can operate ∼8 and >15 years with the same fuel charge, where criticality drops to keff = 1.06 and a burn-up grade of 54 000 and >110 000 MW.D/t can be attained. (2)Weapon grade plutonium: Such a high quality nuclear fuel suggests to be mixed with thorium. Second series of criticality calculations are conducted with fuel compositions made of thoria (ThO2) and weapon grade PuO2, where PuO2 component has been varied from 1% to 100%. Criticality with keff > 1.0 is achieved by ∼2.5% PuO2. At 4% PuO2, the reactor criticality will become satisfactory (keff = 1.1121), rapidly increasing with more PuO2. A reasonable mixture will by around 20% PuO2 and 80% ThO2 with a keff = 1.2864. This mixed fuel would allow full power reactor operation for >20 years and burn-up grade can reach 136 000 MW.D/t. (3)Reactor grade plutonium: Third series of criticality calculations are conducted with fuel compositions made of thoria and reactor grade PuO2, where PuO2 is varied from 1% to 100%. Reactor becomes critical by ∼8% PuO2 content. One can achieve keff = 1.2670 by 35% PuO2 and would allow full power reactor operation also for >20 years and burn-up grade can reach 123 000 MW.D/t. (4)Minor actinides in the spent fuel of LWRs: Fourth series of criticality calculations are conducted with fuel compositions made of thoria and MAO2, where MAO2 is varied from 1

  12. Chemical looping reactor system design double loop circulating fluidized bed (DLCFB)

    Energy Technology Data Exchange (ETDEWEB)

    Bischi, Aldo

    2012-05-15

    Chemical looping combustion (CLC) is continuously gaining more importance among the carbon capture and storage (CCS) technologies. It is an unmixed combustion process which takes place in two steps. An effective way to realize CLC is to use two interconnected fluidized beds and a metallic powder circulating among them, acting as oxygen carrier. The metallic powder oxidizes at high temperature in one of the two reactors, the air reactor (AR). It reacts in a highly exothermic reaction with the oxygen of the injected fluidising air. Afterwards the particles are sent to the other reactor where the fuel is injected, the fuel reactor (FR). There, they transport heat and oxygen necessary for the reaction with the injected fuel to take place. At high temperatures, the particle's oxygen reacts with the fuel producing Co2 and steam, and the particles are ready to start the loop again. The overall reaction, the sum of the enthalpy changes of the oxygen carrier oxidation and reduction reactions, is the same as for the conventional combustion. Two are the key features, which make CLC promising both for costs and capture efficiency. First, the high inherent irreversibility of the conventional combustion is avoided because the energy is utilized stepwise. Second, the Co2 is intrinsically separated within the process; so there is in principle no need either of extra carbon capture devices or of expensive air separation units to produce oxygen for oxy-combustion. A lot of effort is taking place worldwide on the development of new chemical looping oxygen carrier particles, reactor systems and processes. The current work is focused on the reactor system: a new design is presented, for the construction of an atmospheric 150kWth prototype working with gaseous fuel and possibly with inexpensive oxygen carriers derived from industrial by-products or natural minerals. It consists of two circulating fluidized beds capable to operate in fast fluidization regime; this will increase the

  13. Biodegradation of benzotriazoles and hydroxy-benzothiazole in wastewater by activated sludge and moving bed biofilm reactor systems

    OpenAIRE

    Mazioti, Aikaterini A.; Stasinakis, Athanasios S.; Pantazi, Ypapanti; Andersen, Henrik Rasmus

    2015-01-01

    Two laboratory scale fully aerated continuous flow wastewater treatment systems were used to compare the removal of five benzotriazoles and one benzothiazole by suspended and attached growth biomass. The Activated Sludge system was operated under low organic loading conditions. The Moving Bed Biofilm Reactor (MBBR) system consisted of two serially connected reactors filled with K3-biocarriers. It was either operated under low or high organic loading conditions. Target compounds were removed p...

  14. Attached biomass growth and substrate utilization rate in a moving bed biofilm reactor

    Directory of Open Access Journals (Sweden)

    J. J. Marques

    2008-12-01

    Full Text Available A moving bed bioreactor containing cubes of polyether foam immersed in a synthetic wastewater (an aqueous mixture of meat extract, yeast extract, dextrose, meat peptone, ammonium chloride, potassium chloride, sodium chloride, sodium bicarbonate, potassium mono-hydrogen-phosphate and magnesium sulphate was used to evaluate bacterial growth and biomass yield parameters based on Monod's equation. The wastewater was supplied in the bottom of the equipment flowing ascending in parallel with a diffused air current that provided the mixing of the reactor content. Suspended and attached biomass concentration was measured through gravimetric methods. Good agreement was found between experimental kinetic parameters values and those obtained by other researchers. The only significant difference was the high global biomass content about 2 times the values obtained in conventional processes, providing high performance with volumetric loading rates up to 5.5 kg COD/m³/d.

  15. Biodegradation of pharmaceuticals from hospital wastewater in staged Moving Bed Biofilm Reactors (MBBR)

    DEFF Research Database (Denmark)

    Escola, Monica; Kumar Chhetri, Ravi; Ooi, Gordon;

    2015-01-01

    Hospital wastewater may represent an important source of pharmaceuticals into wastewater treatment plants, which are usually inefficient for complete pharmaceuticals removal. Consequently, on-site treatment of hospital wastewater has been suggested. MBBRs (Moving Bed Biofilm Reactors) rely on...... pharmaceuticals from hospital wastewater. A pilot MBBR line consisting of three tanks in series containing AnoxKaldnes™ K5 carriers was installed to treat a fraction of the wastewater from the oncology department of Aarhus University Hospital. Two sampling campaigns were conducted to study the removal of...... wastewater treatment. In both experiments, the first tank was observed to conduct the main part of the pharmaceuticals removal, matching the general parameters data. Overall, the MBBR was shown to treat hospital wastewater efficiently. However, for removal of recalcitrant pharmaceuticals, a polishing...

  16. Microbiological and chemical approaches to degradation of mecoprop in a Moving-Bed Biofilm-Reactor

    DEFF Research Database (Denmark)

    Escola, Monica; Tue Kjærgaard Nielsen, Tue; Hansen, Lars Hestbjerg;

    Micro-pollutants are ubiquitous in wastewater effluents. Therefore, in-situ treatments of highly polluted water or polishing treatments after classical wastewater treatment have been proposed as a solution. Moving Bed Biofilm-Reactors (MBBRs) are a recent-developed biofilm technology for wastewater...... degradation and biofilm communities. This study wanted to answer howfocussed on the response of the microbial communities respond to the presence of micro-pollutants in different concentrations. To do this, MBBR chips, grown and used for wastewater effluent polishing, were exposed to the same real wastewater...... recalcitrant compounds. For all these reasonsThus, MBBRs are pointed as a valuable tool for the elimination of micro-pollutants. Several studies have focused in on describing degradation processes in biofilm by quantifying the loss of micro-pollutants over time. This can be helpful foraid optimizing...

  17. Axial dispersion in packed bed reactors involving viscoinelastic and viscoelastic non-Newtonian fluids.

    Science.gov (United States)

    Gupta, Renu; Bansal, Ajay

    2013-08-01

    Axial dispersion is an important parameter in the performance of packed bed reactors. A lot of fluids exhibit non-Newtonian behaviour but the effect of rheological parameters on axial dispersion is not available in literature. The effect of rheology on axial dispersion has been analysed for viscoinelastic and viscoelastic non-Newtonian fluids. Aqueous solutions of carboxymethyl cellulose and polyacrylamide have been chosen to represent viscoinelastic and viscoelastic liquid-phases. Axial dispersion has been measured in terms of BoL number. The single parameter axial dispersion model has been applied to analyse RTD response curve. The BoL numbers were observed to increase with increase in liquid flow rate and consistency index 'K' for viscoinelastic as well as viscoelastic fluids. Bodenstein correlation for Newtonian fluids proposed has been modified to account for the effect of fluid rheology. Further, Weissenberg number is introduced to quantify the effect of viscoelasticity. PMID:23138641

  18. Neutronic behavior of Thorium based fuel cycles in a pebble bed reactor

    International Nuclear Information System (INIS)

    Thorium is a potentially valuable energy source since it is about three to four times as abundant as Uranium. It is also a widely distributed natural resource readily accessible in many countries. Therefore, Thorium fuels can complement Uranium fuels and ensure long term sustainability of nuclear power. This paper shows the main advantages of the use of a Pebble Bed critical nuclear reactor using a variety of fuel cycles with Thorium (Th+U233, Th+Pu239 and Th+U). the parameters related to the neutronic behavior like deep burn, nuclear fuel breeding, Minor Actinide stockpile, power density profiles and other are used to compare the fuel cycles. also a thermo mechanical study of the irradiated TRISO fuel particle is presented. (Author)

  19. Fluidized bed bio reactor sewage treatment system and wastewater quality at Kudankulam

    International Nuclear Information System (INIS)

    With the availability of fresh water becoming exiguous in certain coastal belts, it has become imperative to manage water resources in a resourceful and judicious manner. The focus has also shifted to minimum or zero tolerance from existing waste treatment plants so as not to contaminate or pollute the already shrinking drinking water resources. Many of the modern waste treatment approaches are already aiming at zero discharge with a view to conserving the ecological balance and to protect the rich bio diversity, flora and fauna. This paper describes one such domestic sewage treatment system called fluidized bed bio reactor operating in the residential colony and plant site area of Kudankulam Nuclear Power Project. Wastewater quality of the resulting effluent water is also discussed. (author)

  20. Biodegradation of TBP in a packed bed reactor using pseudomonas pseudoalcaligenes

    International Nuclear Information System (INIS)

    Tributyl phosphate (TBP), is an organophosphorus compound widely used as a solvent for the extraction of uranium and plutonium, from other radionuclides, in nuclear fuel processing. Several strains from contaminated sites were isolated and screened for their ability to degrade this organophosphorus compound. The most active strain identified as Pseudomonas pseudoalcaligenes could degrade 290μM of TBP and utilized it as a sole source of carbon and energy. Agarose immobilized cell systems were developed for the biodegradation of TBP. A packed bed reactor was constructed and operated for biological TBP removal. Degradation rates for repeated operations increased for successive batches indicating that cells grow better and get adapted to the reaction conditions over time. (author)

  1. Conceptual design of a passively safe thorium breeder Pebble Bed Reactor

    International Nuclear Information System (INIS)

    Highlights: • This work proposes three possible designs for a thorium Pebble Bed Reactor. • A high-conversion PBR (CR > 0.96), passively safe and within practical constraints. • A thorium breeder PBR (220 cm core) in practical regime, but not passively safe. • A passively safe breeder, requiring higher fuel reprocessing and recycling rates. - Abstract: More sustainable nuclear power generation might be achieved by combining the passive safety and high temperature applications of the Pebble Bed Reactor (PBR) design with the resource availability and favourable waste characteristics of the thorium fuel cycle. It has already been known that breeding can be achieved with the thorium fuel cycle inside a Pebble Bed Reactor if reprocessing is performed. This is also demonstrated in this work for a cylindrical core with a central driver zone, with 3 g heavy metal pebbles for enhanced fission, surrounded by a breeder zone containing 30 g thorium pebbles, for enhanced conversion. The main question of the present work is whether it is also possible to combine passive safety and breeding, within a practical operating regime, inside a thorium Pebble Bed Reactor. Therefore, the influence of several fuel design, core design and operational parameters upon the conversion ratio and passive safety is evaluated. A Depressurized Loss of Forced Cooling (DLOFC) is considered the worst safety scenario that can occur within a PBR. So, the response to a DLOFC with and without scram is evaluated for several breeder PBR designs using a coupled DALTON/THERMIX code scheme. With scram it is purely a heat transfer problem (THERMIX) demonstrating the decay heat removal capability of the design. In case control rods cannot be inserted, the temperature feedback of the core should also be able to counterbalance the reactivity insertion by the decaying xenon without fuel temperatures exceeding 1600 °C. Results show that high conversion ratios (CR > 0.96) and passive safety can be combined in

  2. Apparatus, components and operating methods for circulating fluidized bed transport gasifiers and reactors

    Energy Technology Data Exchange (ETDEWEB)

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2015-02-24

    The improvements proposed in this invention provide a reliable apparatus and method to gasify low rank coals in a class of pressurized circulating fluidized bed reactors termed "transport gasifier." The embodiments overcome a number of operability and reliability problems with existing gasifiers. The systems and methods address issues related to distribution of gasification agent without the use of internals, management of heat release to avoid any agglomeration and clinker formation, specific design of bends to withstand the highly erosive environment due to high solid particles circulation rates, design of a standpipe cyclone to withstand high temperature gasification environment, compact design of seal-leg that can handle high mass solids flux, design of nozzles that eliminate plugging, uniform aeration of large diameter Standpipe, oxidant injection at the cyclone exits to effectively modulate gasifier exit temperature and reduction in overall height of the gasifier with a modified non-mechanical valve.

  3. Study of moving bed biofilm reactor in diethyl phthalate and diallyl phthalate removal from synthetic wastewater.

    Science.gov (United States)

    Ahmadi, Ehsan; Gholami, Mitra; Farzadkia, Mahdi; Nabizadeh, Ramin; Azari, Ali

    2015-05-01

    Phthalic acid esters have received significant attention over the last few years since they are considered as priority pollutants. In this study, effects of different operation conditions including hydraulic retention time, phthalates loading rates and aeration rate on process performance of moving bed biofilm reactor (MBBR) for removing diethyl phthalate (DEP) and diallyl phthalate (DAP) from synthetic wastewater was evaluated. In optimum conditions, 94.96% and 93.85% removal efficiency were achieved for DEP and DAP, respectively. Moreover, MBBR achieved to remove more than 92% of COD for both phthalates. The results showed that DEP had a higher biodegradation rate compared to DAP, according to the selected parameters such as half saturation constant, overall reaction rate and maximum specific growth rate. The Grau second order model found as the best model for predicting MBBR performance due to its high correlation coefficients and more conformity of its kinetic coefficients to the results. PMID:25727760

  4. Kinetic modelling of tyre pyrolysis in a conical spouted bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Olazar, Martin; Lopez, Gartzen; Arabiourrutia, Miriam; Elordi, Gorka; Aguado, Roberto; Bilbao, Javier [University of the Basque Country, Faculty of Science and Technology, Department of Chemical Engineering, P.O. Box 644, E48080 Bilbao (Spain)

    2008-01-15

    A novel kinetic model has been proposed for the thermal pyrolysis of tyres. The model is based on a reaction scheme that considers an intermediate lump and parallel reactions for the formation of the different product lumps. Seven lumps have been taken, which are gas (C{sub 4}), non-aromatic liquid (C{sub 5}-C), aromatics (C), tar (C{sub 11+}), char (low grade carbon black), intermediate and the original tyre. The kinetic data have been obtained in a pilot plant provided with a conical spouted bed reactor. The inert gas used is nitrogen and the temperature has been varied from 425 to 610 C. Discontinuous runs have been carried out for obtaining the kinetic data, and the product stream has been analysed on-line at different reaction times, thereby monitoring the evolution with time of mass fraction of the different components. The kinetic model gives reasonable predictions for lump yields. (author)

  5. Catalytic hydrotreating of middle distillates blends in a fixed-bed pilot reactor

    Energy Technology Data Exchange (ETDEWEB)

    Marroquin-Sanchez, G.; Ancheyta-Juarez, J. [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 DF Mexico (Mexico)

    2001-02-01

    An experimental study was conducted in a fixed-bed pilot reactor in order to evaluate the effect of catalytic hydrotreating on diesel quality by using feedstocks prepared with different amounts of straight run gas oil, kerosene and jet fuel streams. Experiments were carried out at constant reaction pressure and hydrogen-to-oil ratio of 5.3MPa and 356.2mlml{sup -1}, respectively. The effect of reaction temperature and liquid hourly space velocity were studied in the range of 613-633K and 1.5-2.0h{sup -1}, over a commercial Ni-Mo/{gamma}-Al{sub 2}O{sub 3} catalyst. The experimental information showed that diesel specifications could be reached through single stage hydrotreating of these blends at moderate hydrotreating operating conditions.

  6. Yield optimization in a cycled trickle-bed reactor: ethanol catalytic oxidation as a case study

    Energy Technology Data Exchange (ETDEWEB)

    Ayude, A.; Haure, P. [INTEMA, CONICET, Mar del Plata (Argentina); Cassanello, M. [Universidad de Buenos Aires, PINMATE, Departamento de Industrias, FCEyN, Buenos Aires (Argentina); Martinez, O. [Departamento de Ingenieria Quimica, FI-UNLP-CINDECA, La Plata (Argentina)

    2012-05-15

    The effect of slow ON-OFF liquid flow modulation on the yield of consecutive reactions is investigated for oxidation of aqueous ethanol solutions using a 0.5 % Pd/Al{sub 2}O{sub 3} commercial catalyst in a laboratory trickle-bed reactor. Experiments with modulated liquid flow rate (MLFR) were performed under the same hydrodynamic conditions (degree of wetting, liquid holdup) as experiments with constant liquid flow rate (CLFR). Thus, the impact of the duration of wet and dry cycles as well as the period can be independently investigated. Depending on cycling conditions, acetaldehyde or acetic acid production is favored with MLFR compared to CLFR. Results suggest both the opportunity and challenge of finding a way to tune the cycling parameters for producing the most appropriate product. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Effect of packing fraction variations on reactivity in pebble-bed reactor

    International Nuclear Information System (INIS)

    The pebble-bed reactor (PBR) core consists of large number of randomly packed spherical fuel elements. The effect of fuel element packing density variations on multiplication factor in a typical PBR is studied using WIMS code. It is observed that at normal conditions the k-eff increases with packing fraction. Effects of secondary coolant ingress (water or molten lead) in the core at accidental conditions are studied at various packing densities. The effect of water ingress on reactivity depends strongly on water density and packing fraction and is prevailingly positive, while the lead ingress reduces multiplication factor regardless of lead effective density and packing fraction. Both effects are stronger at lower packing fractions. (author)

  8. Pyro-hydrolysis treatment technology of the ion exchange resin by pebble-bed pyrolysis reactor

    International Nuclear Information System (INIS)

    Treatment method of spent ion-exchange resin and sludge for sub surface disposal, such as from reactor water clean-up system and from fuel pool cooling cleanup system, is unestablished even now. However, such technology is essential task because increasing the volume of these wastes from decommissioning is unavoidable problem. Due to the solutions, NGK INSULATORS, LTD (NGK) has successfully developed and confirmed that pyro-hydrolysis can treat these waste. This treatment technology, which is based on pebble-bed pyrolyser in nitrogen atmosphere by NUKEM Technologies GmbH, has been improved with superheated steam. This report describes that overview, characteristic and examination result of the treatment technology for such resins with pyro-hydrolysis. (author)

  9. Catalytic Partial Oxidation of Methane with Air to Syngas in a Pilot-Plant-Scale Spouted Bed Reactor

    Institute of Scientific and Technical Information of China (English)

    魏伟胜; 徐建; 方大伟; 鲍晓军

    2003-01-01

    On the basis of hydrodynamic and scaling-up studies, a pilot-plant-scale thermal spouted bed reactor (50 mm in ID and 1500 mm in height) was designed and fabricated by scaling-down cold simulators. It was tested for making syngas via catalytic partial oxidation (CPO) of methane by air. The effects of various operating conditions such as operating pressure and temperature, feed composition, and gas flowrate etc. on the CPO process were investigated. CH4 conversion of 92.20% and selectivity of 92.3% and 83.30/0 to CO and H2, respectively, were achieved at the pressure of 2.1 MPa. It was found that when the spouted bed reactor was operated within the stable spouting flow regime, the temperature profiles along the bed axis were much more uniform than those operated within the fixed-bed regime. The CH4 conversion and syngas selectivity were found to be close to thermodynamic equilibrium limits. The results of the present investigation showed that spouted bed could be considered as a potential type of chemical reactor for the CPO process of methane.

  10. Impact of free ammonia on anammox rates (anoxic ammonium oxidation) in a moving bed biofilm reactor.

    Science.gov (United States)

    Jaroszynski, L W; Cicek, N; Sparling, R; Oleszkiewicz, J A

    2012-06-01

    Using a bench scale moving bed bioreactor (MBBR), the effect of free ammonia (FA, NH(3), the un-ionized form of ammonium NH(4)(+)) concentration on anoxic ammonium oxidation (anammox) was evaluated based on the volumetric nitrogen removal rate (NRR). Although, a detailed microbial analysis was not conducted, the major NRR observed was assumed to be by anammox, based on the nitrogen conversion ratios of nitrite to ammonium and nitrate to ammonium. Since the concentration of free ammonia as a proportion of the total ammonia concentration is pH-dependent, the impact of changing the operating pH from 6.9 to 8.2, was investigated under constant nitrogen loading conditions during continuous reactor operation. Furthermore, the effect of sudden nitrogen load changes was investigated under constant pH conditions. Batch tests were conducted to determine the immediate response of the anammox consortium to shifts in pH and FA concentrations. It was found that FA was inhibiting NRR at concentrations exceeding 2 mg N L(-1). In the pH range 7-8, the decrease in anammox activity was independent of pH and related only to the concentration of FA. Nitrite concentrations of up to 120 mg N L(-1) did not negatively affect NRR for up to 3.5 h. It was concluded that a stable NRR in a moving bed biofilm reactor depended on maintaining FA concentrations below 2 mg N L(-1) when the pH was maintained between 7 and 8. PMID:22483855

  11. Prototype studies on the nondestructive online burnup determination for the modular pebble bed reactors

    International Nuclear Information System (INIS)

    Highlights: • Prototype study of online burnup measurement for HTR proves its feasibility. • Calibration and its correction of burnup assay device is discussed and verified. • Analysis of simulated gamma spectra shows good performance of spectra-unfolding method. - Abstract: The online fuel pebble burnup determination in future modular pebble bed reactor is implemented by measuring nondestructively the activity of the monitoring nuclide Cs-137 with HPGe detector on a pebble-by-pebble basis. Based on a full size prototype the feasibility is investigated. The prototype was first tested by using double sources to show that a precision of 2.8% (1σ) can be achieved in the determination of the Cs-137 net counting rate. Then, the relationship between the Cs-137 activity and the net counting rate recorded in the HPGe detector is calibrated with a standard Cs-137 source contained in the center of a graphite sphere with the same dimension as a real fuel pebble. Because the self attenuation of the calibration source differs with a fuel pebble, a correction factor of 1.07 ± 0.02 (p = 0.95) to the calibration is derived by using the efficiency transfer method. Last, by analyzing the spectra generated with KORIGEN software followed by Monte Carlo simulation, it is predicted that the relative standard deviation of the Cs-137 net counting rate can be still controlled below 3.5% despite of the presence of all the interfering peaks. The results demonstrate the feasibility of utilizing HPGe gamma spectrometry in the online determination of the pebble burnup in future modular pebble bed reactors

  12. A novel approach for harnessing biofilm communities in moving bed biofilm reactors for industrial wastewater treatment

    Directory of Open Access Journals (Sweden)

    Joe A. Lemire

    2015-10-01

    Full Text Available Moving bed biofilm reactors (MBBRs are an effective biotechnology for treating industrial wastewater. Biomass retention on moving bed biofilm reactor (MBBR carriers (biofilm support materials, allows for the ease-of-operation and high treatment capacity of MBBR systems. Optimization of MBBR systems has largely focused on aspects of carrier design, while little attention has been paid to enhancing strategies for harnessing microbial biomass. Previously, our research group demonstrated that mixed-species biofilms can be harvested from an industrial wastewater inoculum [oil sands process water (OSPW] using the Calgary Biofilm Device (CBD. Moreover, the resultant biofilm communities had the capacity to degrade organic toxins (naphthenic acids—NAs that are found in OSPW. Therefore, we hypothesized that harnessing microbial communities from industrial wastewater, as biofilms, on MBBR carriers may be an effective method to bioremediate industrial wastewater.Here, we detail our methodology adapting the workflow employed for using the CBD, to generate inoculant carriers to seed an MBBR.In this study, OSPW-derived biofilm communities were successfully grown, and their efficacy evaluated, on commercially available MBBR carriers affixed within a modified CBD system. The resultant biofilms demonstrated the capacity to transfer biomass to recipient carriers within a scaled MBBR. Moreover, MBBR systems inoculated in this manner were fully active 2 days post-inoculation, and readily degraded a select population of NAs. Together, these findings suggest that harnessing microbial communities on carriers affixed within a modified CBD system may represent a facile and rapid method for obtaining functional inoculants for use in wastewater MBBR treatment systems.

  13. Development of Monte Carlo-based pebble bed reactor fuel management code

    International Nuclear Information System (INIS)

    Highlights: • A new Monte Carlo-based fuel management code for OTTO cycle pebble bed reactor was developed. • The double-heterogeneity was modeled using statistical method in MVP-BURN code. • The code can perform analysis of equilibrium and non-equilibrium phase. • Code-to-code comparisons for Once-Through-Then-Out case were investigated. • Ability of the code to accommodate the void cavity was confirmed. - Abstract: A fuel management code for pebble bed reactors (PBRs) based on the Monte Carlo method has been developed in this study. The code, named Monte Carlo burnup analysis code for PBR (MCPBR), enables a simulation of the Once-Through-Then-Out (OTTO) cycle of a PBR from the running-in phase to the equilibrium condition. In MCPBR, a burnup calculation based on a continuous-energy Monte Carlo code, MVP-BURN, is coupled with an additional utility code to be able to simulate the OTTO cycle of PBR. MCPBR has several advantages in modeling PBRs, namely its Monte Carlo neutron transport modeling, its capability of explicitly modeling the double heterogeneity of the PBR core, and its ability to model different axial fuel speeds in the PBR core. Analysis at the equilibrium condition of the simplified PBR was used as the validation test of MCPBR. The calculation results of the code were compared with the results of diffusion-based fuel management PBR codes, namely the VSOP and PEBBED codes. Using JENDL-4.0 nuclide library, MCPBR gave a 4.15% and 3.32% lower keff value compared to VSOP and PEBBED, respectively. While using JENDL-3.3, MCPBR gave a 2.22% and 3.11% higher keff value compared to VSOP and PEBBED, respectively. The ability of MCPBR to analyze neutron transport in the top void of the PBR core and its effects was also confirmed

  14. Fast oxidative pyrolysis of sugar cane straw in a fluidized bed reactor

    International Nuclear Information System (INIS)

    This study focuses on the technical viability evaluation of the fast pyrolysis of sugar cane straw for its energy use. By means of this thermochemical process, the sugar cane straw is converted into bio-fuels (biochar, bio-oil) and non-condensable gases. The bio-fuels obtained could be used as fuel or as raw material in the chemical industry. The fast pyrolysis of sugar cane straw has been developed in a fluidized bed reactor. In order to improve this process to obtain high bio-oil yield, the influence of the operational conditions (equivalence ratio and temperature) on the product yields and on their characteristics was evaluated. The product yields of bio-oil and char were up to 35.5 wt.% and 48.2 wt.% respectively. The maximum bio-oil yield was achieved at temperature and equivalence ratio conditions of 470 °C and 0.14. The bio-oil obtained has low oxygen content (38.48 wt.% dry basis), very low water content, and a lower heating value of 22.95 MJ/kg. The gas chromatographic analyses allowed the identification of oxygenated compounds and heterocyclic aromatic hydrocarbons. The bio-oil pH ranged between 3.14 and 3.57 due to the presence of acid organic compounds. The char obtained has a high fixed carbon and volatile matter content. Its HHV value is 13.54 MJ/kg. -- Highlights: • Pyrolysis of sugar cane straw was studied in a fluidized bed reactor. • The product yields were evaluated. • The composition of the liquid and solid products obtained was analyzed. This is an environmentally friendly use for this waste

  15. Attrition resistant catalyst for dimethyl ether synthesis in fluidized-bed reactor

    Institute of Scientific and Technical Information of China (English)

    Li-hua TENG

    2008-01-01

    Fluidized-bed reactor is a candidate for dimethyi ether(DME)synthesis from syngas because of its excellent heat removal capability.In Order to improve the attrition resistance of catalyst,an amount of silica sol as binder was added to the catalyst composed of methanol synthesis component CuO/ZnO/Al2O3 and methanol dehydration component HZSM-5,which was prepared by coprecipitation and shaped by spray drying to get spherical particles.The effect of silica sol on the catalytic activity was investigated in a fixed-bed flow microreactor.Based on the experiment results,silica sol in the range of 0~20wt% had small effect on the catalytie activity.Generally,the CO conversion and DME yield decreased with the increase in concen.tration of silica sol,while the attrition resistance of catalysts increased with increasing silica sol,indicating that it was feasible to improve the attrition resistance without greatly sacrificing the activity of catalyst.In addition,the characterizations of catalysts were carried out using Brunauer-Emmett-Teller(BET),X-ray powder diffraction(XRD)and temperature programmed reduction (TPR).

  16. Computational simulation of the biomass gasification process in a fluidized bed reactor

    International Nuclear Information System (INIS)

    In an agro-industrial country as Cuba many residues of cultivation like the rice and the cane of sugar take place, besides the forest residues in wooded extensions. Is an interesting application for all this biomass, the gasification technology, by its high efficiency and its positive environmental impact. The computer simulation appears like a useful tool in the researches of parameters of operation of a gas- emitting, because it reduces the number of experiments to realise and the cost of the researches. In the work the importance of the application of the computer simulation is emphasized to anticipate the hydrodynamic behavior of fluidized bed and of the process of combustion of the biomass for different residues and different conditions of operation. A model using CFD for the simulation of the process of combustion in a gas- emitting of biomass sets out of fluidized bed, the hydrodynamic parameters of the multiphasic flow from the elaboration of a computer simulator that allows to form and to vary the geometry of the reactor, as well as the influence of the variation of magnitudes are characterized such as: speed, diameter of the sand and equivalent reason. Experimental results in cylindrical channels appear, to complete the study of the computer simulation realised in 2D. (author)

  17. Heat-transfer characteristics of flowing and stationary particle-bed-type fusion-reactor blankets

    International Nuclear Information System (INIS)

    The following five appendices are included: (1) physical properties of materials, (2) thermal entrance length Nusselt number variations, (3) stationary particle bed temperature variations, (4) falling bed experimental data and calculations, and (5) stationary bed experimental data and calculations

  18. Heat-transfer characteristics of flowing and stationary particle-bed-type fusion-reactor blankets

    Energy Technology Data Exchange (ETDEWEB)

    Nietert, R.E.

    1983-02-01

    The following five appendices are included: (1) physical properties of materials, (2) thermal entrance length Nusselt number variations, (3) stationary particle bed temperature variations, (4) falling bed experimental data and calculations, and (5) stationary bed experimental data and calculations. (MOW)

  19. A study on evaluation of pebble flow velocity with modification of the kinematic model for pebble bed reactor

    International Nuclear Information System (INIS)

    Highlights: ► A modified kinematic method is proposed for analysis of pebble flow velocity. ► Experiments are performed to derive the coefficients and to verify the results. ► The method and result can be used for the advanced analysis of pebble bed reactor. - Abstract: A pebble bed reactor is filled by a large number of pebbles, which are randomly piled up in the core region. During the process of fuel loading and extraction, the pebbles flow downward through the core. The basic physics of the dense granular flow such as pebble flow is not fully understood; hence, the dynamic core of the pebble bed reactor has been a subject of concern among designers and regulators. The kinematic model is one of the representative models for the reconstruction of the granular flow velocity, however, it is noted that there are some limitations in the reconstruction ability. In this study, a modified kinematic model was proposed to enhance the reconstruction ability of the pebble velocity profile. Pebble flow experiments were performed to derive the coefficients needed for the modified kinematic model and to verify the reconstruction ability and the applicability of the proposed method in the annular core. The modified kinematic model can contribute to accurate velocity evaluation as well as large applicability for the specific core types such as an annular core. Also, the results can be used for reference data in the design of a pebble bed reactor

  20. Production of Carbon Nanotubes over Pre-reduced LaCoO3 Using Fluidized-bed Reactor

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Carbon nanotubes were synthesized on a large scale by the catalytic decomposition of hydrocarbons over pre-reduced LaCoO3 using a fluidized-bed reactor. Reaction parameters such as reduction temperature, reduction time and reaction temperature were discussed.

  1. Transformation of carbon tetrachloride in an anaerobic packed-bed reactor without addition of another electron donor

    NARCIS (Netherlands)

    Best, J.H. de; Hunneman, P.; Doddema, H.J.; Janssen, D.B.; Harder, W.

    1999-01-01

    Carbon tetrachloride (52 μM) was biodegraded for more than 72% in an anaerobic packed-bed reactor without addition of an external electron donor. The chloride mass balance demonstrated that all carbon tetrachloride transformed was completely dechlorinated. Chloroform and dichloromethane were sometim

  2. Fluidized-bed reactor modeling for production of silicon by silane pyrolysis

    Science.gov (United States)

    Dudukovic, M. P.; Ramachandran, P. A.; Lai, S.

    1986-01-01

    An ideal backmixed reactor model (CSTR) and a fluidized bed bubbling reactor model (FBBR) were developed for silane pyrolysis. Silane decomposition is assumed to occur via two pathways: homogeneous decomposition and heterogeneous chemical vapor deposition (CVD). Both models account for homogeneous and heterogeneous silane decomposition, homogeneous nucleation, coagulation and growth by diffusion of fines, scavenging of fines by large particles, elutriation of fines and CVD growth of large seed particles. At present the models do not account for attrition. The preliminary comparison of the model predictions with experimental results shows reasonable agreement. The CSTR model with no adjustable parameter yields a lower bound on fines formed and upper estimate on production rates. The FBBR model overpredicts the formation of fines but could be matched to experimental data by adjusting the unkown jet emulsion exchange efficients. The models clearly indicate that in order to suppress the formation of fines (smoke) good gas-solid contacting in the grid region must be achieved and the formation of the bubbles suppressed.

  3. Aerobic moving bed biofilm reactor treating thermomechanical pulping whitewater under thermophilic conditions.

    Science.gov (United States)

    Jahren, Sigrun J; Rintala, Jukka A; Odegaard, Hallvard

    2002-02-01

    The continuously operated laboratory scale Kaldnes moving bed biofilm reactor (MBBR) was used for thermophilic (55 degrees C) aerobic treatment of TMP whitewater. In the MBBR, the biomass is grown on carrier elements that move along with the water in the reactor. Inoculation with mesophilic activated sludge gave 60-65% SCOD removal from the first day onwards. During the 107 days of experiment, the 60-65% SCOD removals were achieved at organic loading rates of 2.5-3.5 kg SCODm(-3) d(-1), the highest loading rates applied during the run and HRT of 13-22h. Carbohydrates, which contributed to 50-60% of the influent SCOD. were removed by 90-95%, while less than 15% of the lignin-like material (30-35% of SCODin) was removed. The sludge yield was 0.23g VSSg SCOD(-1)removed. The results show that the aerobic biofilm process can be successfully operated under thermophilic conditions. PMID:11848344

  4. Simulation for Supporting Scale-Up of a Fluidized Bed Reactor for Advanced Water Oxidation

    Directory of Open Access Journals (Sweden)

    Farhana Tisa

    2014-01-01

    Full Text Available Simulation of fluidized bed reactor (FBR was accomplished for treating wastewater using Fenton reaction, which is an advanced oxidation process (AOP. The simulation was performed to determine characteristics of FBR performance, concentration profile of the contaminants, and various prominent hydrodynamic properties (e.g., Reynolds number, velocity, and pressure in the reactor. Simulation was implemented for 2.8 L working volume using hydrodynamic correlations, continuous equation, and simplified kinetic information for phenols degradation as a model. The simulation shows that, by using Fe3+ and Fe2+ mixtures as catalyst, TOC degradation up to 45% was achieved for contaminant range of 40–90 mg/L within 60 min. The concentration profiles and hydrodynamic characteristics were also generated. A subsequent scale-up study was also conducted using similitude method. The analysis shows that up to 10 L working volume, the models developed are applicable. The study proves that, using appropriate modeling and simulation, data can be predicted for designing and operating FBR for wastewater treatment.

  5. Simulation for supporting scale-up of a fluidized bed reactor for advanced water oxidation.

    Science.gov (United States)

    Tisa, Farhana; Raman, Abdul Aziz Abdul; Daud, Wan Mohd Ashri Wan

    2014-01-01

    Simulation of fluidized bed reactor (FBR) was accomplished for treating wastewater using Fenton reaction, which is an advanced oxidation process (AOP). The simulation was performed to determine characteristics of FBR performance, concentration profile of the contaminants, and various prominent hydrodynamic properties (e.g., Reynolds number, velocity, and pressure) in the reactor. Simulation was implemented for 2.8 L working volume using hydrodynamic correlations, continuous equation, and simplified kinetic information for phenols degradation as a model. The simulation shows that, by using Fe(3+) and Fe(2+) mixtures as catalyst, TOC degradation up to 45% was achieved for contaminant range of 40-90 mg/L within 60 min. The concentration profiles and hydrodynamic characteristics were also generated. A subsequent scale-up study was also conducted using similitude method. The analysis shows that up to 10 L working volume, the models developed are applicable. The study proves that, using appropriate modeling and simulation, data can be predicted for designing and operating FBR for wastewater treatment. PMID:25309949

  6. Valorisation of waste tyre by pyrolysis in a moving bed reactor

    International Nuclear Information System (INIS)

    The aim of this work is to assess the behaviour of a moving bed reactor, based on a screw transporter design, in waste tyre pyrolysis under several experimental conditions. Waste tyre represents a significant problem in developed countries and it is necessary to develop new technology that could easily process big amounts of this potentially raw material. In this work, the influence of the main pyrolysis process variables (temperature, solid residence time, mass flow rate and inert gas flow) has been studied by a thorough analysis of product yields and properties. It has been found that regardless the process operational parameters, a total waste tyre devolatilisation is achieved, producing a pyrolytic carbon black with a volatile matter content under 5 wt.%. In addition, it has been proven that, in the range studied, the most influencing process variables are temperature and solid mass flow rate, mainly because both variables modify the gas residence time inside the reactor. In addition, it has been found that the modification of these variables affects to the chemical properties of the products. This fact is mainly associated to the different cracking reaction of the primary pyrolysis products.

  7. Biohydrogen production from cassava wastewater in an anaerobic fluidized bed reactor

    Directory of Open Access Journals (Sweden)

    N. C. S. Amorim

    2014-09-01

    Full Text Available The effect of hydraulic retention time (HRT and organic loading rate (OLR on biological hydrogen production was assessed using an anaerobic fluidized bed reactor fed with cassava wastewater. The HRT of this reactor ranged from 8 to 1 h (28 to 161 kg COD/m³-d. The inoculum was obtained from a facultative pond sludge derived from swine wastewater treatment. The effluent pH was approximately 5.00, while the influent chemical oxygen demand (COD measured 4000 mg COD/L. The hydrogen yield production increased from 0.13 to 1.91 mol H2/mol glucose as the HRT decreased from 8 to 2 h. The hydrogen production rate significantly increased from 0.20 to 2.04 L/h/L when the HRT decreased from 8 to 1 h. The main soluble metabolites were ethanol (1.87-100%, acetic acid (0.00-84.80%, butyric acid (0.00-66.78% and propionic acid (0.00-50.14%. Overall, we conclude that the best hydrogen yield production was obtained at an HRT of 2 h.

  8. Evaluation of Heavy Metal Removal from Wastewater in a Modified Packed Bed Biofilm Reactor.

    Science.gov (United States)

    Azizi, Shohreh; Kamika, Ilunga; Tekere, Memory

    2016-01-01

    For the effective application of a modified packed bed biofilm reactor (PBBR) in wastewater industrial practice, it is essential to distinguish the tolerance of the system for heavy metals removal. The industrial contamination of wastewater from various sources (e.g. Zn, Cu, Cd and Ni) was studied to assess the impacts on a PBBR. This biological system was examined by evaluating the tolerance of different strengths of composite heavy metals at the optimum hydraulic retention time (HRT) of 2 hours. The heavy metal content of the wastewater outlet stream was then compared to the source material. Different biomass concentrations in the reactor were assessed. The results show that the system can efficiently treat 20 (mg/l) concentrations of combined heavy metals at an optimum HRT condition (2 hours), while above this strength there should be a substantially negative impact on treatment efficiency. Average organic reduction, in terms of the chemical oxygen demand (COD) of the system, is reduced above the tolerance limits for heavy metals as mentioned above. The PBBR biological system, in the presence of high surface area carrier media and a high microbial population to the tune of 10 000 (mg/l), is capable of removing the industrial contamination in wastewater. PMID:27186636

  9. Evaluation of Heavy Metal Removal from Wastewater in a Modified Packed Bed Biofilm Reactor.

    Directory of Open Access Journals (Sweden)

    Shohreh Azizi

    Full Text Available For the effective application of a modified packed bed biofilm reactor (PBBR in wastewater industrial practice, it is essential to distinguish the tolerance of the system for heavy metals removal. The industrial contamination of wastewater from various sources (e.g. Zn, Cu, Cd and Ni was studied to assess the impacts on a PBBR. This biological system was examined by evaluating the tolerance of different strengths of composite heavy metals at the optimum hydraulic retention time (HRT of 2 hours. The heavy metal content of the wastewater outlet stream was then compared to the source material. Different biomass concentrations in the reactor were assessed. The results show that the system can efficiently treat 20 (mg/l concentrations of combined heavy metals at an optimum HRT condition (2 hours, while above this strength there should be a substantially negative impact on treatment efficiency. Average organic reduction, in terms of the chemical oxygen demand (COD of the system, is reduced above the tolerance limits for heavy metals as mentioned above. The PBBR biological system, in the presence of high surface area carrier media and a high microbial population to the tune of 10 000 (mg/l, is capable of removing the industrial contamination in wastewater.

  10. A particle-bed gas-cooled fast reactor core design for waste minimization

    International Nuclear Information System (INIS)

    The issue of waste minimization in advanced reactor systems has been investigated using the Particle-Bed Gas-cooled Fast Reactor (PB-GCFR) design being developed and funded under the U.S. Department of Energy Nuclear Energy Research Initiative (USDOE NERI) Programme. Results indicate that for the given core power density and constraint on the maximum TRU enrichment allowable, the lowest amount of radio-toxic transuranics to be processed and hence sent to the repository is obtained for long-life core designs. Calculations were additionally done to investigate long-life core designs using LWR spent fuel TRU and recycle TRU, and different feed, matrix and reflector materials. The recycled TRU and LWR spent TRU fuels give similar core behaviours, because of the fast spectrum environment which does not significantly degrade the TRU composition. Using light elements as reflector material was found to be unattractive because of power peaking problems and large reactivity swings. The application of a lead reflector gave the longest cycle length and lowest TRU processing requirement. Materials compatibility and performance issues require additional investigation. (author)

  11. Removal of toxic metals from aqueous effluents by electrodeposition in a spouted bed electrochemical reactor.

    Science.gov (United States)

    Martins, Rosimeire; Britto-Costa, Pedro H; Ruotolo, Luís Augusto M

    2012-06-01

    This work investigates the removal of metal ions from synthetic aqueous effluents using a spouted bed electrochemical reactor whose cathode was composed of 1.0 mm copper particles. Using a Box-Behnken factorial design, the effects of current (I), electrode thickness (L), draught distance (d) and support electrolyte concentration (C(s)) on current efficiency (CE), space-time yield (Y) and energy consumption (EC) were analysed. The results were statistically analysed and the effect of each variable was evaluated using the surface response methodology. The results showed that C(s) is the most important variable to consider in the process optimization. A current of 8.0 A can be applied in order to obtain high Y and CE with an acceptable EC. Electrode thicknesses greater than 1.3 cm are not recommended because the irregular potential distribution leads to a Y drop owing to the low CE observed for this condition. The draught distance does not have statistical significance; therefore, the particle circulation rate is not important in this kind of electrochemical reactor. PMID:22856281

  12. Development of a 3D multigroup program for Dancoff factor calculation in pebble bed reactors

    International Nuclear Information System (INIS)

    Highlights: • Development of a 3D Monte Carlo based code for pebble bed reactors. • Dancoff sensitivity to clad, moderator and fuel cross sections is considered. • Sensitivity of Dancoff to number of energy groups is considered. • Sensitivity of Dancoff to number of fuel and their arrangement is considered. • Excellent agreements vs. MCNP code. - Abstract: The evaluation of multigroup constants in reactor calculations depends on several parameters. One of these parameters is the Dancoff factor which is used for calculating the resonance integral and flux depression in the resonance region in heterogeneous systems. In the current paper, a computer program (MCDAN-3D) is developed for calculating three dimensional black and gray Dancoff coefficients, based on Monte Carlo, escape probability and neutron free flight methods. The developed program is capable to calculate the Dancoff factor for an arbitrary arrangement of fuel and moderator pebbles. Moreover this program can simulate fuels with homogeneous and heterogeneous compositions. It might generate the position of Triso particles in fuel pebbles randomly as well. It could calculate the black and gray Dancoff coefficients since fuel region might have different cross sections. Finally, the effects of clad and moderator are considered and the sensitivity of Dancoff factor with fuels arrangement variation, number of TRISO particles and neutron energy has been studied

  13. Evaluation of the effectiveness factor along immobilized enzyme fixed-bed reactors: design of a reactor with naringinase covalently immobilized into glycophase-coated porous glass

    Energy Technology Data Exchange (ETDEWEB)

    Manjon, A.; Iborra, J.L.; Gomez, J.L.; Gomez, E.; Bastida, J.; Bodalo, A.

    1987-09-01

    A design equation is presented for packed-bed reactors containing immobilized enzymes in spherical porous particles with internal diffusion effects and obeying reversible one-intermediate Michaelis-Menten kinetics. The equation is also able to explain irreversible and competitive product inhibition kinetics. It allows the axial substrate profiles to be calculated and the dependence of the effectiveness factor along the reactor length to be continuously evaluated. The design equation was applied to explain the behavior of naringinase immobilized in Glycophase-coated porous glass operating in a packed-bed reactor and hydrolyzing both p-nitrophenyl-alpha-L-rhamnoside and naringin. The theoretically predicted results were found to fit well with experimentally measured values. (Refs. 28).

  14. Fast pyrolysis of Miscanthus sinensis in fluidized bed reactors: Characteristics of product yields and biocrude oil quality

    International Nuclear Information System (INIS)

    In the present work, fast pyrolysis of Miscanthus sinensis was performed and the product yields and properties of the resulting biocrude oil were determined for varying reactor configurations and pyrolysis temperatures. Two types of reactors (rectangular and cylindrical fluidized beds) were adopted, and pyrolysis temperature was increased from 400 °C to 550 °C. Based on the results, it was found that the reaction temperature greatly influenced the product yield and the characteristics of biocrude oil. The highest yield of biocrude oil for the rectangular reactor was 48.9 wt.%, produced at 500 °C, and the highest yield for the cylindrical reactor was 50.01 wt.%, produced at 450 °C. Additionally, the biocrude oil yield in the rectangular reactor sharply decreased when reaction temperature was increased to 550 °C, while only a slight decrease was observed in the cylindrical reactor. From GC/MS analysis, biocrude oil was found to contain various chemical components, such as nonaromatic ketones, furans, sugars, lignin-derived phenols, guaiacols and syringols. In particular, the sugar content of the biocrude oil produced in rectangular reactor (2.11–9.35 wt.%) was generally lower than that produced in the cylindrical reactor (7.93–10.79 wt.%). - Highlights: • Fast pyrolysis of Miscanthus sinensis was performed in two fluidized bed reactors to obtain biocrude oil. • The yield and characteristics of the biocrude oil were scrutinized with changing reaction temperature and reactor type. • The reaction temperature was found to be the most influencing parameter for the fast pyrolysis reaction. • The different heating rate caused by reactor type has an effect on the final product yield and characteristics

  15. Hydrodynamic analysis of a three-fluidized bed reactor cold flow model for chemical looping hydrogen generation. Pressure characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Xue, Zhipeng; Xiang, Wenguo; Chen, Shiyi; Wang, Dong [Southeast Univ., Nanjing (China). School of Energy and Environment

    2013-07-01

    Chemical looping hydrogen generation (CLHG) can produce pure hydrogen with inherent separation of CO{sub 2} from fossils fuel. The process involves a metal oxide, as an oxygen carrier, such as iron oxide. The CLHG system consists of three reactors: a fuel reactor (FR), a steam reactor (SR) and an air reactor (AR). In the FR, the fuel gases react with iron oxides (hematite Fe{sub 2}O{sub 3}, magnetite Fe{sub 3}O{sub 4}, wuestite FeO), generating reduced iron oxides (FeO or even Fe), and with full conversion of gaseous fuels, pure CO{sub 2} can be obtained after cooling the flue gas from the fuel reactor; in the SR, FeO and Fe reacts with steam to generate magnetite (Fe{sub 3}O{sub 4}) and H{sub 2}, the latter representing the final target product of the process; in the AR, the magnetite is oxidized back to hematite which is used in another cycle. A cold flow model of three-fluidized bed for CLHG corresponding to 50 KW hot units has been built. A major novelty of this facility is the compact fuel reactor, which integrates a bubble and a fast fluidized bed to avoid the incomplete conversion of the fuel gas caused by the thermodynamics equilibrium. In order to study the pressure characteristics and the solids concentration of the system, especially in the fuel reactor, the gas velocity of three reactors, gas flow of L-type value, total solids inventory (TSI) and the secondary air of fuel reactor were varied. Results show that the pressure and the solids concentration are strongly influenced by the fluidizing-gas velocity of three reactors. Moreover, the entrainment of the upper part of fuel reactor increases as the total solids inventory increases, and the operating range of the FR can be changed by introducing secondary air or increasing the total solids inventory.

  16. Biodiesel production in a magnetically-stabilized, fluidized bed reactor with an immobilized lipase in magnetic chitosan microspheres.

    Science.gov (United States)

    Zhou, Gui-Xiong; Chen, Guan-Yi; Yan, Bei-Bei

    2014-01-01

    Biodiesel production by immobilized Rhizopus oryzae lipase in magnetic chitosan microspheres (MCMs) was carried out using soybean oil and methanol in a magnetically-stabilized, fluidized bed reactor (MSFBR). The maximum content of methyl ester in the reaction mixture reached 91.3 (w/v) at a fluid flow rate of 25 ml/min and a magnetic field intensity of 150 Oe. In addition, the MCMs-immobilized lipase in the reactor showed excellent reusability, retaining 82 % productivity even after six batches, which was much better than that in a conventional fluidized bed reactor. These results suggested that a MSFRB using MCMs-immobilized lipase is a promising method for biodiesel production. PMID:24062133

  17. An analysis of the thermal behaviour of pebble-bed nuclear reactors in the case of emergencies

    International Nuclear Information System (INIS)

    In this paper, the performance of pebble-bed nuclear reactors under very severe emergencies will be analysed. Calculated hypotheses take into consideration total failure of decay heat removal systems and any other active equipment, including electric power supply. It has been shown that pebble temperatures will remain well below safety limits if the reactor design embodies a core catcher with a passive cooling reservoir and a pebble draining system which would be naturally activated by a lack of a power supply. Although these features apply to any pebble-bed reactor, particular attention is paid to accelerator-driven sub-critical assemblies, where reactivity noise produced pebble quivering has a practical negligible effect. (authors)

  18. Sustainability of thorium-uranium in pebble-bed fluoride salt-cooled high temperature reactor

    Directory of Open Access Journals (Sweden)

    Zhu Guifeng

    2016-01-01

    Full Text Available Sustainability of thorium fuel in a Pebble-Bed Fluoride salt-cooled High temperature Reactor (PB-FHR is investigated to find the feasible region of high discharge burnup and negative Flibe (2LiF-BeF2 salt Temperature Reactivity Coefficient (TRC. Dispersion fuel or pellet fuel with SiC cladding and SiC matrix is used to replace the tristructural-isotropic (TRISO coated particle system for increasing fuel loading and decreasing excessive moderation. To analyze the neutronic characteristics, an equilibrium calculation method of thorium fuel self-sustainability is developed. We have compared two refueling schemes (mixing flow pattern and directional flow pattern and two kinds of reflector materials (SiC and graphite. This method found that the feasible region of breeding and negative Flibe TRC is between 20 vol% and 62 vol% fuel loading in the fuel. A discharge burnup could be achieved up to about 200 MWd/kgHM. The case with directional flow pattern and SiC reflector showed superior burnup characteristics but the worst radial power peak factor, while the case with mixing flow pattern and SiC reflector, which was the best tradeoff between discharge burnup and radial power peak factor, could provide burnup of 140 MWd/kgHM and about 1.4 radial power peak factor with 50 vol% dispersion fuel. In addition, Flibe salt displays good neutron properties as a coolant of quasi-fast reactors due to the strong 9Be(n,2n reaction and low neutron absorption of 6Li (even at 1000 ppm in fast spectrum. Preliminary thermal hydraulic calculation shows good safety margin. The greatest challenge of this reactor may be the decades irradiation time of the pebble fuel.

  19. Simultaneous denitrification and anaerobic digestion in GRAnular Bed Baffled Reactor (GRABBR)

    International Nuclear Information System (INIS)

    This study elucidates the characteristics of compartmentalised anaerobic system seeded with UASB granules, called GRAanular Bed Baffled Reactor (GRABBR), for combined denitrification and anaerobic digestion processes. The reactor was used for the treatment of glucose enriched synthetic wastewater with various nitrate concentrations. The study was carried out with a 10 litre working volume GRABBR divided into 5 equal compartments operating at organic loading rate (OLR) of 20 kg COD/m3.d with a hydraulic retention time (HRT) of 6 hours. At these conditions, phase separation (between acidogenesis and methanogenesis) was created in the system and then the effect of varying nitrate concentrations (50-200 mg/l NO3-N) in the acidogenic zone (i.e. first compartment) was studied. Due to its unique compartmentalised design, denitrification was the major pathway for nitrate reduction with no noticeable dissimilatory nitrate reduction to ammonia (DNRA). More than 84% of all added nitrates were removed in the acidogenic zone, showing that acidogens possess high denitrifying capabilities. The denitrification rate increased with increase in nitrate concentration, with maximum value estimated as 175 mg NO3-N/l.h at influent nitrate concentration of 200 mg/l NO3-N in the acidogenic zone. Although nitrate addition resulted in lower methane production, COD removal efficiencies improved by up to 8% when compared with the reactor performance before nitrate addition. Furthermore, the alkalinity produced during denitrification improved the stability of the system by controlling the decrease in pH resulting from acidogenesis. The system encouraged simultaneous denitrification and anaerobic digestion in a single unit by accommodating denitrifiers in the early compartments and allowing methanogenesis to flourish in the downstream compartments of the system, thus minimising inhibition to methane producing bacteria by nitrates. (author)

  20. A combined upflow anaerobic sludge bed, aerobic, and anoxic fixed-bed reactor system for removing tetramethylammonium hydroxide and nitrogen from light-emitting diode wastewater.

    Science.gov (United States)

    Lin, Han-Lin; Chen, Sheng-Kun; Huang, Yu-Wen; Chen, Wei-Cheng; Chien, Wei-Cheng; Cheng, Sheng-Shung

    2016-06-01

    A laboratory study using a combined upflow anaerobic sludge bed (UASB) and aerobic and anoxic fixed-bed reactor system was undertaken to explore its capability for removing tetramethylammonium hydroxide (TMAH) and nitrogen from light-emitting diode wastewater. When the organic loading rate was maintained at 0.26-0.65 kg TMAH m(-3 )d(-1), the UASB reactor removed 70-100% of TMAH through methanogenesis. When the [Formula: see text] -N loading rate was maintained at 0.73-1.4 kg [Formula: see text]-N m(-3 )d(-1), the aerobic reactor oxidized 31-59% of [Formula: see text]-N to [Formula: see text]-N through nitritation. When the nitrogen loading rate was maintained at 0.42-0.75 kg N m(-3 )d(-1), the anoxic reactor removed 27-63% of nitrogen through anammox. The performance data of the combined reactor system agreed well with the stoichiometric relationships of methanogenesis, nitritation, and anammox. The batch studies showed that a higher initial TMAH concentration of up to 2520 mg L(-1) gave a higher methanogenic activity of up to 16 mL CH4 g(-1) VSS d(-1). An increase in the initial TMAH concentration of up to 500 mg L(-1) gradually decreased the activity of ammonia-oxidizing bacteria; whereas an increase in the initial TMAH concentration of up to 47 mg L(-1) imposed a marked inhibiting effect on the activity of anammox bacteria. PMID:26583577

  1. Transient modelling of sulphur-iodine cycle thermochemical hydrogen generation coupled to pebble bed modular reactor

    International Nuclear Information System (INIS)

    A transient control volume model of the sulphur iodine (S-I) and Westinghouse hybrid sulphur (HyS) cycles is presented. These cycles are some of the leading candidates for hydrogen generation using a high temperature heat source. The control volume models presented here are based on a heat and mass balance in each reaction chamber coupled to the relevant reaction kinetics. The chemical kinetics expressions are extracted from a relevant literature review. Two assumptions regarding reaction chamber pressure are identified, namely a constant pressure condition and a differential form of ideal gas law. The HyS model is based on an application of the Nernst equation. This application of the Nernst equation suggests that in the HyS cycle the hydrogen generation rate is directly proportional to the SO2 production rate. The observed chemical kinetic response time of the sulphuric acid decomposition section is on the order of 30 seconds, whereas the response time of the hydrogen iodide decomposition section is on the order of 500 seconds. It is concluded that the decomposition of hydrogen iodide (HI) is the rate limiting step of the entire S-I cycle. High temperature nuclear reactors are ideal candidates for use as a driving heat source for both the S-I and HyS cycle. The pebble bed modular reactor is a type of very high temperature reactor (VHTR ) suitable for nuclear hydrogen generation. A methodology for coupling of the S-I or HyS cycle to a pebble bed modular reactor (PBMR) via an intermediate heat exchanger (IHX) is developed. A 2-D THERMIX heat transfer model of a PBMR-268 is presented, and this model is coupled to a point kinetics model. The point kinetics model was developed to meet the same specifications as the RELAP5 point kinetics module. A steady-state integration of the S-I and HyS cycle models to the PBMR 268 heat transfer model is performed. The integration assumes that 100% of the heat energy from the PBMR-268 is deposited into the chemical plant via the

  2. Modelling of a fluidized bed carbonator reactor to capture CO{sub 2} from a combustion flue gas

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, M.; Rodriguez, N.; Grasa, G.; Abanades, J.C. [CSIC, Oviedo (Spain)

    2009-03-15

    In recent years several processes incorporating a carbonation-calcination loop in an interconnected fluidized bed reactor have been proposed as a way to capture CO{sub 2} from flue gases. This paper is a first approximation to the modelling of a fluidized bed carbonator reactor. In this reactor the flue gas comes into contact with an active bed composed of particles with very different activities, depending on their residence time in the bed and in the carbonation-calcination loop. The model combines the residence time distribution functions with existing knowledge about sorbent deactivation rates and sorbent reactivity. The fluid dynamics of the solids (CSTR) and gases (PF) in the carbonator are based on simple assumptions. The carbonation rates are modelled defining a characteristic time for the transition between a fast reaction regime to a regime with a zero reaction rate. On the basis of these assumptions the model is able to predict the CO{sub 2} capture efficiency for the flue gas depending on the operating and design conditions. Operating windows with high capture efficiencies are discussed, as well as those conditions where only modest capture efficiencies are possible.

  3. A CFD approach on simulation of hydrogen production from steam reforming of glycerol in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Dou, Binlin; Song, Yongchen [School of Energy and Power Engineering, Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116023 (China)

    2010-10-15

    Hydrogen production from steam reforming of glycerol in a fluidized bed reactor has been simulated using a CFD method by an additional transport equation with a kinetic term. The Eulerian-Eulerian two-fluid approach was adopted to simulate hydrodynamics of fluidization, and chemical reactions were modelled by laminar finite-rate model. The bed expansion and pressure drop were predicted for different inlet gas velocities. The results showed that the flow system exhibited a more heterogeneous structure, and the core-annulus structure of gas-solid flow led to back-mixing and internal circulation behaviour, and thus gave a poor velocity distribution. This suggests the bed should be agitated to maintain satisfactory fluidizing conditions. Glycerol conversion and H{sub 2} production were decreased with increasing inlet gas velocity. The increase in the value of steam to carbon molar ratio increases the conversion of glycerol and H{sub 2} selectivity. H{sub 2} concentrations in the bed were uneven and increased downstream and high concentrations of H{sub 2} production were also found on walls. The model demonstrated a relationship between hydrodynamics and hydrogen production, implying that the residence time and steam to carbon molar ratio are important parameters. The CFD simulation will provide helpful data to design and operate a bench scale catalytic fluidized bed reactor. (author)

  4. Co-Fuelling of Peat with Meat and Bone Meal in a Pilot Scale Bubbling Bed Reactor

    Directory of Open Access Journals (Sweden)

    Markku Orjala

    2010-07-01

    Full Text Available Co-combustion performance trials of Meat and Bone Meal (MBM and peat were conducted using a bubbling fluidized bed (BFB reactor. In the combustion performance trials the effects of the co-combustion of MBM and peat on flue gas emissions, bed fluidization, ash agglomeration tendency in the bed and the composition and quality of the ash were studied. MBM was mixed with peat at 6 levels between 15% and 100%. Emissions were predominantly below regulatory limits. CO concentrations in the flue gas only exceeded the 100 mg/m3 limit upon combustion of pure MBM. SO2 emissions were found to be over the limit of 50 mg/m3, while in all trials NOx emissions were below the limit of 300 mg/m3. The HCl content of the flue gases was found to vary near the limit of 30 mg/m3. VOCs however were within their limits. The problem of bed agglomeration was avoided when the bed temperature was about 850 °C and only 20% MBM was co-combusted. This study indicates that a pilot scale BFB reactor can, under optimum conditions, be operated within emission limits when MBM is used as a co-fuel with peat. This can provide a basis for further scale-up development work in industrial scale BFB applications.

  5. ANAEROBIC/AEROBIC BIODEGRADATION OF PENTACHLOROPHENOL USING GAC FLUIDIXED BED REACTORS: OPTIMIZATION OF THE EMPTY BED CONTACT TIME

    Science.gov (United States)

    An integrated reactor system has been developed to remediate pentachlorophenol (PCP) containing wastes using sequential anaerobic and aerobic biodegradation. Anaerobically, PCP was degraded to approximately equimolar concentrations (>99%) of chlorophenol (CP) in a granular activa...

  6. Co-gasification of meat and bone meal with coal in a fluidised bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    E. Cascarosa; L. Gasco; G. Gea; J.L. Sanchez; J. Arauzo [Universidad de Zaragoza (Spain). Thermochemical Processes Group

    2011-08-15

    After the Bovine Spongiform Encephalopathy illness appeared, the meat and bone meat (MBM) produced from animal residues became an important waste. In spite of being a possible fuel due to its heating value (around 21.4 MJ/kg), an important fraction of the meat and bone meal is being sent to landfills. The aim of this work is to evaluate the co-gasification of low percentages of meat and bone meal with coal in a fluidised bed reactor as a potential waste management alternative. The effect of the bed temperature (800-900{sup o}C), the equivalence ratio (0.25-0.35) and the percentage of MBM in the solid fed (0-1 wt.%) on the co-gasification product yields and properties is evaluated. The results show the addition of 1 wt.% of MBM in a coal gasification process increases the gas and the liquid yield and decreases the solid yield at 900{sup o}C and 0.35 of temperature and equivalence ratio operational conditions. At operational conditions of 900{sup o}C and equivalence ratio of 0.35, the specific yield to gas (y{sub gas}) increases from 3.18 m{sup 3}(STP)/kg to 4.47 m{sup 3}(STP)/kg. The gas energy yield decreased 24.1% and the lower heating value of the gas decreases from 3.36 MJ/m{sup 3}(STP) to 2.16 MJ/m{sup 3}(STP). The concentration of the main gas components (H{sub 2}, CO and CO{sub 2}) hardly varies with the addition of MBM, however the light hydrocarbon concentrations decrease and the H{sub 2}S concentration increases at the higher temperature (900{sup o}C). 32 refs., 9 figs., 7 tabs.

  7. Supplemental Report on Nuclear Safeguards Considerations for the Pebble Bed Modular Reactor (PBMR)

    International Nuclear Information System (INIS)

    Recent reports by Department of Energy National Laboratories have discussed safeguards considerations for the low enriched uranium (LEU) fueled Pebble Bed Modular Reactor (PBMR) and the need for bulk accountancy of the plutonium in used fuel. These reports fail to account effectively for the degree of plutonium dilution in the graphitized-carbon pebbles that is sufficient to meet the International Atomic Energy Agency's (IAEA's) 'provisional' guidelines for termination of safeguards on 'measured discards.' The thrust of this finding is not to terminate safeguards but to limit the need for specific accountancy of plutonium in stored used fuel. While the residual uranium in the used fuel may not be judged sufficiently diluted to meet the IAEA provisional guidelines for termination of safeguards, the estimated quantities of 232U and 236U in the used fuel at the target burn-up of ∼91 GWD/MT exceed specification limits for reprocessed uranium (ASTM C787) and will require extensive blending with either natural uranium or uranium enrichment tails to dilute the 236U content to fall within specification thus making the PBMR used fuel less desirable for commercial reprocessing and reuse than that from light water reactors. Also the PBMR specific activity of reprocessed uranium isotopic mixture and its A2 values for effective dose limit if released in a dispersible form during a transportation accident are more limiting than the equivalent values for light water reactor spent fuel at 55 GWD/MT without accounting for the presence of the principal carry-over fission product (99Tc) and any possible plutonium contamination that may be present from attempted covert reprocessing. Thus, the potentially recoverable uranium from PBMR used fuel carries reactivity penalties and radiological penalties likely greater than those for reprocessed uranium from light water reactors. These factors impact the economics of reprocessing, but a more significant consideration is that reprocessing

  8. A preliminary conceptual design for a 150 MWth pebble bed reactor core using the VSOP94 code package

    International Nuclear Information System (INIS)

    Recently, the hydrogen production using heat source of the high-temperature gas-cooled reactor (HTGR) has been attracting worldwide attention. Since the domestic neutronic design codes for the LWR core design were judged not to be applicable to design of the HTGRs, the VSOP94 code system for the core designs of pebble bed type HTGRs was installed in order to be used in the HTGR design until the domestic code system would be developed. After the VSOP94 was verified against a benchmark calculation for the PRROTEUS experiment, the preliminary conceptual design for a hypothetical bed reator with 150 MWth was performed using the VSOP94

  9. Production of specifically structured lipids by enzymatic interesterification in a pilot enzyme bed reactor: process optimization by response surface methodology

    DEFF Research Database (Denmark)

    Xu, Xuebing; Mu, Huiling; Høy, Carl-Erik; Adler-Nissen, Jens

    1999-01-01

    Pilot production of specifically structured lipids by Lipozyme IM-catalyzed interesterification was carried out in a continuous enzyme bed reactor without the use of solvent. Medium chain triacylglycerols and oleic acid were used as model substrates. Response surface methodology was applied to...... not identical for the sequential experiments in the same enzyme bed due to the deactivation of the Lipozyme IM. Therefore, the results were normalized based on enzyme deactivation models. Well-fitting quadratic models were obtained after normalizing the data for the incorporation of oleic acid and the...

  10. The effective thermal conductivity in packed beds of spheres especially in the core of a high temperature reactor

    International Nuclear Information System (INIS)

    Cell and quasihomogeneous models for determining of the effective thermal conductivity in packed beds are compared and their evidence is investigated by own experimental data both in the high and low temperature range under consideration of the stationary fluid. The quasihomogeneous model is extended to packed beds with spheres of relatively low thermal conductivity. The void radiation heat transfer is considered theoretically and is determined experimentally. Simplified formulas are presented for the computation of the effective thermal conductivity on the core of a high temperature reactor within a temperature range of 25000C. (orig.)

  11. An experimental study of the partial oxidation of ethane to ethylene in a shallow fluidized bed reactor

    OpenAIRE

    DANICA BRZIC; DESISLAVA AHCHIEVA; MIRKO PEGLOW; STEFAN HEINRICH

    2007-01-01

    The partial catalytic oxidation of ethane to ethylene was investigated experimentally in a shallow fluidized bed. The performaces of two catalyst types, pure g‑Al2O3 and V2O5/ g-Al2O3 particles 1.8 mm in diameter, were analyzed. A pilot fluidized bed reactor with rectangular cross-section of 100mm´100mm was used. The experiments were carried out under atmospheric pressure in a dilute system under oxygen excess conditions. V2O5/g-Al2O3 showed good catalytic performances regarding ethylene sele...

  12. On the evaluation of pebble bed reactor critical experiments using the PEBBED code

    International Nuclear Information System (INIS)

    The PEBBED pebble bed reactor fuel management code under development at the Idaho National Laboratory is designed for rapid design and analysis of pebble bed high temperature reactors (PBRs). Embedded within the code are the THERMIX-KONVEK thermal fluid solver and the COMBINE-7 spectrum generation code for inline cross section homogenization. Because 1D symmetry can be found at each stage of core heterogeneity; spherical at TRISO and pebble levels, and cylindrical at the control rod and core levels, the 1-D transport capability of ANISN is assumed to be sufficient in most cases for generating flux solutions for cross section homogenization. Furthermore, it is fast enough to be executed during the analysis or the equilibrium core. Multi-group diffusion-based design codes such as PEBBED and VSOP are not expected to yield the accuracy and resolution of continuous energy Monte Carlo codes for evaluation of critical experiments. Nonetheless, if the preparation of multigroup cross sections can adequately capture the physics of the mixing of PBR fuel elements and leakage from the core, reasonable results may be obtained. In this paper, results of the application of PEBBED to two critical experiments (HTR Proteus and HTR-10) and associated computational models are presented. The embedded 1-D transport solver is shown to capture the double heterogeneity of the pebble fuel in unit cell calculations. Eigenvalue calculations of a whole core are more challenging, particularly if the boron concentration is uncertain. The sensitivity of major safety parameters to variations in modeling assumptions, however, is shown to be minimal. The embedded transport solver can also be used to obtain control rod worths but only with adjustment of the local spectrum. Results are compared to those of other codes as well as Core 4 of the HTR-Proteus experiment which contains partially inserted rods. They indicate the need for a reference solution to adjust the radius of the graphite in the

  13. On the evaluation of pebble bed reactor critical experiments using the PEBBED code

    Energy Technology Data Exchange (ETDEWEB)

    Hans D. Gougar; R. Sonat Sen

    2001-10-01

    The PEBBED pebble bed reactor fuel management code under development at the Idaho National Laboratory is designed for rapid design and analysis of pebble bed high temperature reactors (PBRs). Embedded within the code are the THERMIX-KONVEK thermal fluid solver and the COMBINE-7 spectrum generation code for inline cross section homogenization. Because 1D symmetry can be found at each stage of core heterogeneity; spherical at TRISO and pebble levels, and cylindrical at the control rod and core levels, the 1-D transport capability of ANISN is assumed to be sufficient in most cases for generating flux solutions for cross section homogenization. Furthermore, it is fast enough to be executed during the analysis or the equilibrium core. Multi-group diffusion-based design codes such as PEBBED and VSOP are not expected to yield the accuracy and resolution of continuous energy Monte Carlo codes for evaluation of critical experiments. Nonetheless, if the preparation of multigroup cross sections can adequately capture the physics of the mixing of PBR fuel elements and leakage from the core, reasonable results may be obtained. In this paper, results of the application of PEBBED to two critical experiments (HTR Proteus and HTR-10) and associated computational models are presented. The embedded 1-D transport solver is shown to capture the double heterogeneity of the pebble fuel in unit cell calculations. Eigenvalue calculations of a whole core are more challenging, particularly if the boron concentration is uncertain. The sensitivity of major safety parameters to variations in modeling assumptions, however, is shown to be minimal. The embedded transport solver can also be used to obtain control rod worths but only with adjustment of the local spectrum. Results are compared to those of other codes as well as Core 4 of the HTR-Proteus experiment which contains partially inserted rods. They indicate the need for a reference solution to adjust the radius of the graphite in the

  14. Color removal from textile dyebath effluents in a zeolite fixed bed reactor: Determination of optimum process conditions using Taguchi method

    International Nuclear Information System (INIS)

    Taguchi method was applied as an experimental design to determine optimum conditions for color removal from textile dyebath house effluents in a zeolite fixed bed reactor. After the parameters were determined to treat real textile wastewater, adsorption experiments were carried out. The breakthrough curves for adsorption studies were constructed under different conditions by plotting the normalized effluent color intensity (C/C0) versus time (min) or bed volumes (BV). The chosen experimental parameters and their ranges are: HTAB concentration (Chtab), 1-7.5 g L-1; HTAB feeding flowrate (Qhtab), 0.015-0.075 L min-1; textile wastewater flowrate (Qdye), 0.025-0.050 L min-1 and zeolite bed height (Hbed), 25-50 cm, respectively. Mixed orthogonal array L16 (42 x 22) for experimental plan and the larger the better response category were selected to determine the optimum conditions. The optimum conditions were found to be as follows: HTAB concentration (Chtab) = 1 g L-1, HTAB feeding flowrate (Qhtab) = 0.015 L min-1, textile wastewater flowrate (Qdye) = 0.025 L min-1 and bed height (Hbed) = 50 cm. Under these conditions, the treated wastewater volume reached a maximum while the bed volumes (BV) were about 217. While HTAB concentration, g L-1 (A); zeolite bed height, cm (D) and wastewater flowrate, L min-1 (C) were found to be significant parameters, respectively, whereas, HTAB flowrate, L min-1 (B) was found to be an insignificant parameter

  15. Temperature and time influence on the waste plastics pyrolysis in the fixed bed reactor

    Directory of Open Access Journals (Sweden)

    Papuga Saša V.

    2016-01-01

    Full Text Available Pyrolysis as a technique of chemical recycling of plastic materials is causing an increasing level of interest as an environmentally and economically acceptable option for the processing of waste materials. Studies of these processes are carried out under different experimental conditions, in different types of reactors and with different raw materials, which makes the comparison of different processes and the direct application of process parameters quite complex. This paper presents the results of investigation of the influence of temperature in the range of 450°C to 525°C, on the yield of the process of pyrolysis of waste plastics mixture, composed of 45% polypropylene, 35% low density polyethylene and 25% high density polyethylene. Also, this paper presents results of the investigation of the effect of the reaction, atintervals of 30-90 [min], on the yield of pyrolysis of the mentioned waste plastics mixture. Research was conducted in a fixed bed pilot reactor, which was developed for this purpose. The results of the research show that at a temperature of 500°C, complete conversion of raw materials was achieved, for a period of 45 [min], with a maximum yield of the pyrolysis oil of 32.80%, yield of the gaseous products of 65.75% and the solid remains of 1.46%. Afurther increase of temperature increases the yield of gaseous products, at the expense of reducing the yield of pyrolysis oil. Obtained pyrolysis oil has a high calorific value of 45.96 [MJ/kg], and in this regard has potential applications as an alternative fuel.

  16. Experimental investigation of fluidized-bed reactor performance for oxidative coupling of methane

    Institute of Scientific and Technical Information of China (English)

    S.Ja(s)o; R.Schom(a)cker; G.Wozny; S.Sadjadi; H.R.Godini; U.Simon; S.Arndt; O.G(o)rke; A.Berthold; H.Arellano-Garcia; H.Schubert

    2012-01-01

    Performance of the oxidative coupling of methane in fluidized-bed reactor was experimentally investigated using Mn-Na2WO4/SiO2,La2O3/CaO and La2O3-SrO/CaO catalysts.These catalysts were found to be stable,especially Mn-Na2WO4/SiO2 catalyst.The effect of sodium content of this catalyst was analyzed and the challenge of catalyst agglomeration was addressed using proper catalyst composition of 2%Mn-2.2%Na2WO4/SiO2.For other two catalysts,the effect of Lanthanum-Strontium content was analyzed and 10%La2O3-20%SrO/CaO catalyst was found to provide higher ethylene yield than La2O3/CaO catalyst.Furthermore,the effect of operating parameters such as temperature and methane to oxygen ratio were also reviewed.The highest ethylene and ethane (C2) yield was achieved with the lowest methane to oxygen ratio around 2.40.5% selectivity to ethylene and ethane and 41% methane conversion were achieved over La2O3-SrO/CaO catalyst while over Mn-Na2WO4/SiO2 catalyst,40% and 48% were recorded,respectively.Moreover,the consecutive effects of nitrogen dilution,ethylene to ethane production ratio and other performance indicators on the down-stream process units were qualitatively discussed and Mn-Na2WO4/SiO2 catalyst showed a better performance in the reactor and process scale analysis.

  17. Effect of hydrogen combustion reaction on the dehydrogenation of ethane in a fixed-bed catalytic membrane reactor

    Institute of Scientific and Technical Information of China (English)

    Masoud Hasany; Mohammad Malakootikhah; Vahid Rahmanian; Soheila Yaghmaei

    2015-01-01

    A two-dimensional non-isothermal mathematical model has been developed for the ethane dehydrogenation reaction in a fixed-bed catalytic membrane reactor. Since ethane dehydrogenation is an equilibrium reaction, removal of produced hydrogen by the membrane shifts the thermodynamic equilibrium to ethylene production. For further displacement of the dehydrogenation reaction, oxidative dehydrogenation method has been used. Since ethane dehydrogenation is an endothermic reaction, the energy produced by the oxidative dehydrogena-tion method is consumed by the dehydrogenation reaction. The results show that the oxidative dehydrogenation method generated a substantial improvement in the reactor performance in terms of high conversions and significant energy saving. It was also established that the sweep gas velocity in the shell side of the reactor is one of the most important factors in the effectiveness of the reactor.

  18. Lewis Research Center's coal-fired, pressurized, fluidized-bed reactor test facility

    Science.gov (United States)

    Kobak, J. A.; Rollbuhler, R. J.

    1981-01-01

    A 200-kilowatt-thermal, pressurized, fluidized-bed (PFB) reactor, research test facility was designed, constructed, and operated as part of a NASA-funded project to assess and evaluate the effect of PFB hot-gas effluent on aircraft turbine engine materials that might have applications in stationary-power-plant turbogenerators. Some of the techniques and components developed for this PFB system are described. One of the more important items was the development of a two-in-one, gas-solids separator that removed 95+ percent of the solids in 1600 F to 1900 F gases. Another was a coal and sorbent feed and mixing system for injecting the fuel into the pressurized combustor. Also important were the controls and data-acquisition systems that enabled one person to operate the entire facility. The solid, liquid, and gas sub-systems all had problems that were solved over the 2-year operating time of the facility, which culminated in a 400-hour, hot-gas, turbine test.

  19. Gas Turbine High Temperature Gas (Helium) Reactor Using Pebble Bed Fuel Derived from Spent Fuel

    International Nuclear Information System (INIS)

    Project goals: Build on the $1B investment spent during the NGNP Project for the only true Inherently Safe Small Modular Reactor Design – the only SMR design that can make this claim due to negative temperature coefficient of reactivity - no containment required – less construction cost. NPMC in Partnership with Pebble Bed Modular Group, a fully owned subsidiary of Eskom, RSA to Factory Build Complete Plant in Modular Sections at Factory Site in Oswego, NY for transport to site by rail or shipping for world wide export. NPMC will provide Project and Construction Management of all new builds from plant sites through construction, commissioning and startup using local labor. License and Construct ion of spent fuel processing facility in both NY and South Africa using Proven Technology. Ultimate goals of project: 1. Award of the 2013 US DOE Innovative SMR $452M cost share grant for US NRC License Certification 2.Build Full Scale Demonstration Plant at Koeburg, RSA with World Bank Funding managed by NPMC in collaboration with our legal firm, Haynes and Boone LLP 3. Take Plant Orders Immediately (10% Down Payment) 4. Form Strategic Alliance with Domestic and/or International Utility

  20. Gasification of refuse derived fuel in a fixed bed reactor for syngas production

    International Nuclear Information System (INIS)

    Steam gasification of two different refuse derived fuels (RDFs), differing slightly in composition as well as thermal stability, was carried out in a fixed-bed reactor at atmospheric pressure. The proximate and ultimate analyses reveal that carbon and hydrogen are the major components in RDFs. The thermal analysis indicates the presence of cellulose and plastic based materials in RDFs. H2 and CO are found to be the major products, along with CO2 and hydrocarbons resulting from gasification of RDFs. The effect of gasification temperature on H2 and CO selectivities was studied, and the optimum temperature for better H2 and CO selectivity was determined to be 725 deg. C. The calorific value of product gas produced at lower gasification temperature is significantly higher than that of gas produced at higher process temperature. Also, the composition of RDF plays an important role in distribution of products gas. The RDF with more C and H content is found to produce more amounts of CO and H2 under similar experimental conditions. The steam/waste ratio showed a notable effect on the selectivity of syngas as well as calorific value of the resulting product gas. The flow rate of carrier gas did not show any significant effect on products yield or their distribution

  1. Packed-bed reactor/silent-discharge plasma design data report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    In 1992, Congress passed the Federal Facility Compliance Act requiring the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). The DOE Albuquerque Operations Office (AL) currently does not have adequate systems to treat the mixed wastes generated and stored at the nine DOE-AL sites. In response to the need for mixed-waste treatment capacity, DOE-AL organized a Treatment Selection Team under the Mixed-Waste Treatment Program (MWTP) to match mixed wastes with treatment options and develop a strategy for treatment of its mixed waste. The strategy developed by the Treatment Selection Team, as described in the AL Mixed-Waste Treatment Plan (DOE 1994), is to use available off-site commercial treatment facilities for all wastes that can be successfully and cost-effectively treated by such facilities. Where no appropriate commercial treatment facilities exist, mobile treatment units (MTUs) would be developed to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste must not only address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. The packed-bed reactor/silent discharge plasma was chosen as a potential candidate for the treatment of the mixed wastes. The process is described.

  2. Ethanol production during semi-continuous syngas fermentation in a trickle bed reactor using Clostridium ragsdalei.

    Science.gov (United States)

    Devarapalli, Mamatha; Atiyeh, Hasan K; Phillips, John R; Lewis, Randy S; Huhnke, Raymond L

    2016-06-01

    An efficient syngas fermentation bioreactor provides a mass transfer capability that matches the intrinsic kinetics of the microorganism to obtain high gas conversion efficiency and productivity. In this study, mass transfer and gas utilization efficiencies of a trickle bed reactor during syngas fermentation by Clostridium ragsdalei were evaluated at various gas and liquid flow rates. Fermentations were performed using a syngas mixture of 38% CO, 28.5% CO2, 28.5% H2 and 5% N2, by volume. Results showed that increasing the gas flow rate from 2.3 to 4.6sccm increased the CO uptake rate by 76% and decreased the H2 uptake rate by 51% up to Run R6. Biofilm formation after R6 increased cells activity with over threefold increase in H2 uptake rate. At 1662h, the final ethanol and acetic acid concentrations were 5.7 and 12.3g/L, respectively, at 200ml/min of liquid flow rate and 4.6sccm gas flow rate. PMID:26950756

  3. Nutrients recovery by struvite formation from wastewater in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lee, C.W. [Civil and Environmental Engineering, Kyungnam Univ., Masan (Korea); Kwon, H.B. [Dept. of Materials Science Engineering, Kyungnam Univ., Masan (Korea); Kim, Y.J.; Jeon, H.P. [Graduate student, Civil and Environmental Engineering, Kyungnam Univ. (Korea)

    2005-07-01

    Nutrient removal and recovery from wastewater is being challenged to avoid eutrophication problems, and the discharge standards have also been tightened by water regulations. Therefore, this study was undertaken to recover the nutrients from both synthetic wastewater and swine wastewater in a fluidized bed reactor (FBR). The operational parameters were changed to find out the optimum conditions for struvite formation. The most suitable pH was identified around pH 9. When the molar ratio of magnesium as Mg: P was 2:1 in the FBR, the removal efficiency of NH{sub 4}-N and PO{sub 4}-P was 79 and 90%, respectively. The seed material was effective to form struvite in the condition of 30g dosage. Struvite crystallization in reaction was completed in 20 minutes. The growth of struvite crystals was confirmed by the analysis of XRD, FT-IR and TG-DTA. In addition, the struvite was successfully recovered when the optimum conditions were applied to the swine wastewater. (orig.)

  4. Packed-bed reactor/silent-discharge plasma design data report

    International Nuclear Information System (INIS)

    In 1992, Congress passed the Federal Facility Compliance Act requiring the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). The DOE Albuquerque Operations Office (AL) currently does not have adequate systems to treat the mixed wastes generated and stored at the nine DOE-AL sites. In response to the need for mixed-waste treatment capacity, DOE-AL organized a Treatment Selection Team under the Mixed-Waste Treatment Program (MWTP) to match mixed wastes with treatment options and develop a strategy for treatment of its mixed waste. The strategy developed by the Treatment Selection Team, as described in the AL Mixed-Waste Treatment Plan (DOE 1994), is to use available off-site commercial treatment facilities for all wastes that can be successfully and cost-effectively treated by such facilities. Where no appropriate commercial treatment facilities exist, mobile treatment units (MTUs) would be developed to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste must not only address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. The packed-bed reactor/silent discharge plasma was chosen as a potential candidate for the treatment of the mixed wastes. The process is described

  5. High-rate wastewater treatment combining a moving bed biofilm reactor and enhanced particle separation.

    Science.gov (United States)

    Helness, H; Melin, E; Ulgenes, Y; Järvinen, P; Rasmussen, V; Odegaard, H

    2005-01-01

    Many cities around the world are looking for compact wastewater treatment alternatives since space for treatment plants is becoming scarce. In this paper development of a new compact, high-rate treatment concept with results from experiments in lab-scale and pilot-scale are presented. The idea behind the treatment concept is that coagulation/floc separation may be used to separate suspended and colloidal matter (resulting in > 70% organic matter removal in normal wastewater) while a high-rate biofilm process (based on Moving Bed biofilm reactors) may be used for removing low molecular weight, easily biodegradable, soluble organic matter. By using flotation for floc/biomass separation, the total residence time for a plant according to this concept will normally be cationic polymer combined with iron is used as coagulant at low dosages (i.e. 1-2 mg polymer/l, 5-10 mg Fe/l) resulting in low sludge production (compared to conventional chemical treatment) and sufficient P-removal. PMID:16459783

  6. Immobilised native plant cysteine proteases: packed-bed reactor for white wine protein stabilisation.

    Science.gov (United States)

    Benucci, Ilaria; Lombardelli, Claudio; Liburdi, Katia; Acciaro, Giuseppe; Zappino, Matteo; Esti, Marco

    2016-02-01

    This research presents a feasibility study of using a continuous packed-bed reactor (PBR), containing immobilised native plant cysteine proteases, as a specific and mild alternative technique relative to the usual bentonite fining for white wine protein stabilisation. The operational parameters for a PBR containing immobilised bromelain (PBR-br) or immobilised papain (PBR-pa) were optimised using model wine fortified with synthetic substrate (Bz-Phe-Val-Arg-pNA). The effectiveness of PBR-br, both in terms of hazing potential and total protein decrease, was significantly higher than PBR-pa, in all the seven unfined, white wines used. Among the wines tested, Sauvignon Blanc, given its total protein content as well as its very high intrinsic instability, was selected as a control wine to evaluate the effect of the treatment on wine as to its soluble protein profile, phenolic composition, mineral component, and sensory properties. The treatment in a PBR containing immobilised bromelain appeared effective in decreasing both wine hazing potential and total protein amount, while it did not significantly affect the phenol compounds, the mineral component nor the sensory quality of wine. The enzymatic treatment in PBR was shown to be a specific and mild technique for use as an alternative to bentonite fining for white wine protein stabilisation. PMID:27162393

  7. Tar Production from Biomass Pyrolysis in a Fluidized Bed Reactor: A Novel Turbulent Multiphase Flow Formulation

    Science.gov (United States)

    Bellan, J.; Lathouwers, D.

    2000-01-01

    A novel multiphase flow model is presented for describing the pyrolysis of biomass in a 'bubbling' fluidized bed reactor. The mixture of biomass and sand in a gaseous flow is conceptualized as a particulate phase composed of two classes interacting with the carrier gaseous flow. The solid biomass is composed of three initial species: cellulose, hemicellulose and lignin. From each of these initial species, two new solid species originate during pyrolysis: an 'active' species and a char, thus totaling seven solid-biomass species. The gas phase is composed of the original carrier gas (steam), tar and gas; the last two species originate from the volumetric pyrolysis reaction. The conservation equations are derived from the Boltzmann equations through ensemble averaging. Stresses in the gaseous phase are the sum of the Newtonian and Reynolds (turbulent) contributions. The particulate phase stresses are the sum of collisional and Reynolds contributions. Heat transfer between phases, and heat transfer between classes in the particulate phase is modeled, the last resulting from collisions between sand and biomass. Closure of the equations must be performed by modeling the Reynolds stresses for both phases. The results of a simplified version (first step) of the model are presented.

  8. Synthesis of biodiesel from waste cooking oil using immobilized lipase in fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yingming [School of Environment and Urban Construction, Wuhan University of Science and Engineering, Wuhan 430073 (China)]|[Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640 (China); Xiao, Bo [School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Chang, Jie; Fu, Yan [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China); Lv, Pengmei; Wang, Xuewei [Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640 (China)

    2009-03-15

    Waste cooking oil (WCO) is the residue from the kitchen, restaurants, food factories and even human and animal waste which not only harm people's health but also causes environmental pollution. The production of biodiesel from waste cooking oil to partially substitute petroleum diesel is one of the measures for solving the twin problems of environment pollution and energy shortage. In this project, synthesis of biodiesel was catalyzed by immobilized Candida lipase in a three-step fixed bed reactor. The reaction solution was a mixture of WCO, water, methanol and solvent (hexane). The main product was biodiesel consisted of fatty acid methyl ester (FAME), of which methyl oleate was the main component. Effects of lipase, solvent, water, and temperature and flow of the reaction mixture on the synthesis of biodiesel were analyzed. The results indicate that a 91.08% of FAME can be achieved in the end product under optimum conditions. Most of the chemical and physical characters of the biodiesel were superior to the standards for 0diesel (GB/T 19147) and biodiesel (DIN V51606 and ASTM D-6751). (author)

  9. Synthesis of biodiesel from waste cooking oil using immobilized lipase in fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chen Yingming [School of Environment and Urban Construction, Wuhan University of Science and Engineering, Wuhan 430073 (China); Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640 (China); Xiao Bo [School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Chang Jie [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China)], E-mail: changjie@scut.edu.cn; Fu Yan [School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641 (China); Lv Pengmei; Wang Xuewei [Guangzhou Institute of Energy Conversion, Chinese Academy of Science, Guangzhou 510640 (China)

    2009-03-15

    Waste cooking oil (WCO) is the residue from the kitchen, restaurants, food factories and even human and animal waste which not only harm people's health but also causes environmental pollution. The production of biodiesel from waste cooking oil to partially substitute petroleum diesel is one of the measures for solving the twin problems of environment pollution and energy shortage. In this project, synthesis of biodiesel was catalyzed by immobilized Candida lipase in a three-step fixed bed reactor. The reaction solution was a mixture of WCO, water, methanol and solvent (hexane). The main product was biodiesel consisted of fatty acid methyl ester (FAME), of which methyl oleate was the main component. Effects of lipase, solvent, water, and temperature and flow of the reaction mixture on the synthesis of biodiesel were analyzed. The results indicate that a 91.08% of FAME can be achieved in the end product under optimum conditions. Most of the chemical and physical characters of the biodiesel were superior to the standards for 0 diesel (GB/T 19147) and biodiesel (DIN V51606 and ASTM D-6751)

  10. Utilization of water clarifier sludge for copper removal in a liquid fluidized-bed reactor

    International Nuclear Information System (INIS)

    A method was used to investigate the potential for using water clarifier sludge to remove copper in a fluidized-bed reactor (FBR). This study was conducted to evaluate the removal of copper in an aquatic system without prior treatment. Chemical analyses of water clarifier sludge through inductively coupled plasma-atomic emission spectrophotometry indicated that silicon, aluminum and iron oxides made up more than 84% of this average composition, similar to the composition of clay. The experimental results indicated that the copper removal efficiency was highly dependent on the pH. pH values also influence the character of the water clarifier sludge. After the copper was adsorbed by the water clarifier sludge, the pH of the solution was slightly increased. In the FBR, the copper removal efficiency reached 90% when the initial copper concentration was 20 mg/L, the pH was 4 and the operating time was 60 min. In addition, copper precipitation occured on the surface of clarifier sludge when the initial copper concentration was 20 mg/L and the pH was 7.0. The kinetics of copper ion adsorption at pH 5 showed that 94% copper ion was removed in 60 min and the adsorption equilibrium was attained in 5 h. The mechanisms of adsorption of copper ions on water clarifier sludge including the formation of surface complexation and surface precipitate

  11. Evaluation of Anaerobic Fluidized Bed Reactor for treating Sugar mill effluent - a Case Study

    Directory of Open Access Journals (Sweden)

    R. Mathiyazhagan

    2014-07-01

    Full Text Available Anaerobic treatment processes are credible options for providing sustainable treatment to biodegradable waste streams. The Anaerobic Fluidized Bed Reactor (AFBR is an evolving process that requires waste specific design methodologies based on kinetics of the specific process. The research was precisely an experimental study on AFBR having23.56 litres of effective volume to evaluate its treatment performance and gas recovery in terms of Chemical Oxygen Demand (COD, Hydraulic Retention Time(HRTand Organic Loading Rate (OLR. The synthetic sugar influent COD was variedfrom 1500 to 4000 mg/lit. The OLR for the operating flow rates were ranged from 1.36 to 28.8 Kg COD/m3 .day for HRT varied from 3.2 to 24 hrs. The maximum COD removal efficiency is 90.06 at an operating OLR of 3.42 Kg COD/m3 .day. The maximum biogas yield was observed at 0.28 m 3 /kg COD removed.

  12. Characterization of immobilized enzymes in polyurethane foams in a dynamic bed reactor.

    Science.gov (United States)

    Hu, Z C; Korus, R A; Stormo, K E

    1993-06-01

    beta-D-Galactosidase (E 3.2.1.23) from Aspergillus oryzae was immobilized with polyurethane foam (PUF). Among several immobilization methods attempted in this work, the immobilized enzyme preparation by in-situ co-polymerization between enzyme and prepolymer HYPOL 3000 showed the highest activity. The intrinsic kinetics of PUF-immobilized enzyme was determined in a dynamic bed reactor, used to increase transport rates. The immobilization mechanism in PUF was studied by measurements of immobilized enzyme kinetics and by using scanning electron microscopy combined with immuno-gold labeling techniques. The results showed that immobilization was predominantly by covalent bonding between primary amino groups of beta-D-galactosidase and isocyanate groups of the prepolymers. Entrapment in the PUF micropores assisted the immobilization of enzymes, and adsorption on the surface of macropores was not important for immobilization. The bicinchoninic acid method was applied for the determination of PUF loading capacity and specific enzyme activity and used to determine enzyme deactivation during immobilization. PMID:7763711

  13. Recovery of energy and iron from oily sludge pyrolysis in a fluidized bed reactor.

    Science.gov (United States)

    Qin, Linbo; Han, Jun; He, Xiang; Zhan, Yiqiu; Yu, Fei

    2015-05-01

    In the steel industry, about 0.86 ton of oily sludge is produced for every 1000 tons of rolling steel. Due to the adverse impact on human health and the environment, oily sludge is designated as a hazardous waste in the Resource Conservation and Recovery Act (RCRT). In this paper, the pyrolysis treatment of oily sludge is studied in a fluidized bed reactor at a temperature range of 400-600 °C. During oily sludge pyrolysis, a maximum oil yield of 59.2% and a minimum energy loss of 19.0% are achieved at 500 °C. The energy consumption of treating 1 kg oily sludge is only 2.4-2.9 MJ. At the same time, the energy of produced oil, gas and solid residue are 20.8, 6.32, and 0.83 MJ, respectively. In particular, it is found that the solid residue contains more than 42% iron oxide, which can be used as the raw material for iron production. Thus, the simultaneous recovery of energy and iron from oil sludge by pyrolysis is feasible. PMID:25728916

  14. Combined production and purification of hydrogen from methanol using steam iron process in fixed bed reactor

    Science.gov (United States)

    Campo, R.; Durán, P.; Plou, J.; Herguido, J.; Peña, J. A.

    2013-11-01

    A research work is being conducted to study the combined production and purification of hydrogen by means of redox processes departing from biomass fast pyrolysis oils (bio-oils). To achieve that goal, methanol has been used as featured material because it is the most representative compound of the alcoholic fraction of bio-oils. The study has been carried out in a fixed bed reactor where methanol decomposes in H2 and CO when gets in contact with a reactive solid based in an iron oxide at temperatures above 600 °C. During the first stage of the “steam-iron” process, reactive gases reduce the iron oxide to metallic iron. Afterward, in a following step, the previously reduced iron is reoxidized by steam producing a high purity hydrogen stream. Although coke deposition does exist during the reducing stage, this behaves as inert during the reoxidation process. Coke inert role has been corroborated by GC, SEM and TEM techniques, showing that carbon deposits were constituted by ordered structures (carbon nanotubes). The determination of the hydrogen production along successive cycles allowed the evaluation of the effect of temperature and alternating reactive atmospheres on the stability of the solid, as well as the optimum conditions for such purpose.

  15. Catalytic pyrolysis of miscanthus × giganteus in a spouted bed reactor.

    Science.gov (United States)

    Du, Shoucheng; Sun, Yijia; Gamliel, David P; Valla, Julia A; Bollas, George M

    2014-10-01

    A conical spouted bed reactor was designed and tested for fast catalytic pyrolysis of miscanthus × giganteus over Zeolite Socony Mobil-5 (ZSM-5) catalyst, in the temperature range of 400-600 °C and catalyst to biomass ratios 1:1-5:1. The effect of operating conditions on the lumped product distribution, bio-oil selectivity and gas composition was investigated. In particular, it was shown that higher temperature favors the production of gas and bio-oil aromatics and results in lower solid and liquid yields. Higher catalyst to biomass ratios increased the gas yield, at the expense of liquid and solid products, while enhancing aromatic selectivity. The separate catalytic effects of ZSM-5 catalyst and its Al2O3 support were studied. The support contributes to increased coke/char formation, due to the uncontrolled spatial distribution and activity of its alumina sites. The presence of ZSM-5 zeolite in the catalyst enhanced the production of aromatics due to its proper pore size distribution and activity. PMID:25058293

  16. Synthesis of biodiesel from waste cooking oil using immobilized lipase in fixed bed reactor

    International Nuclear Information System (INIS)

    Waste cooking oil (WCO) is the residue from the kitchen, restaurants, food factories and even human and animal waste which not only harm people's health but also causes environmental pollution. The production of biodiesel from waste cooking oil to partially substitute petroleum diesel is one of the measures for solving the twin problems of environment pollution and energy shortage. In this project, synthesis of biodiesel was catalyzed by immobilized Candida lipase in a three-step fixed bed reactor. The reaction solution was a mixture of WCO, water, methanol and solvent (hexane). The main product was biodiesel consisted of fatty acid methyl ester (FAME), of which methyl oleate was the main component. Effects of lipase, solvent, water, and temperature and flow of the reaction mixture on the synthesis of biodiesel were analyzed. The results indicate that a 91.08% of FAME can be achieved in the end product under optimum conditions. Most of the chemical and physical characters of the biodiesel were superior to the standards for 0 diesel (GB/T 19147) and biodiesel (DIN V51606 and ASTM D-6751)

  17. A novel semidry flue gas desulfurization process with the magnetically fluidized bed reactor

    International Nuclear Information System (INIS)

    The magnetically fluidized bed (MFB) was used as the reactor in a novel semidry flue gas desulfurization (FGD) process to achieve high desulfurization efficiency. Experiments in a laboratory-scale apparatus were conducted to reveal the effects of approach to adiabatic saturation temperature, Ca/S molar ratio and applied magnetic field intensity on SO2 removal. Results showed that SO2 removal efficiency can be obviously enhanced by decreasing approach to adiabatic saturation temperature, increasing Ca/S molar ratio, or increasing applied magnetic field intensity. At a magnetic field intensity of 300 Oe and a Ca/S molar ratio of 1.0, the desulfurization efficiency (excluding desulfurization efficiency in the fabric filter) was over 80%, while spent sorbent appeared in the form of dry powder. With the SEM, XRD and EDX research, it can be found that the increase of DC magnetic field intensity can make the surface morphology on the surface of the ferromagnetic particles loose and enhance the oxidation of S(IV), hence reducing the liquid phase mass transfer resistance of the slurry droplets and increasing desulfurization reaction rate, respectively. Therefore, the desulfurization efficiency increased obviously with the increase of DC field intensity.

  18. Measurement of liquid holdup and axial dispersion in trickle bed reactors using radiotracer technique

    International Nuclear Information System (INIS)

    The holdup and axial dispersion of aqueous phase has been measured in trickle bed reactors as a function of liquid and gas flow rates using radioisotope tracer technique. Experiments were carried out in the glass column of inner diameter of 15.2x10-2 m column for air-water system using three different types of packings i.e. non-porous glass beads, porous catalyst of tablet and extrudate shape. The range of liquid and gas flow rates used were 8.3x10-5 - 3.3x1--4 m3/s and 0 - 6.67x10-4 m3/s, respectively. Residence time distributions of liquid phase and gas phase were measured and mean residence times were determined. The values of liquid holdup were calculated from the measured mean residence times. It was observed that the liquid holdup increases with increase in liquid flow rates and was independent of increase in gas flow rates used in the study. Two-parameter axial dispersion model was used to simulate measured residence time distribution data and values of mean residence time and Peclet number were obtained. It was observed that the values of Peclet number increases with increase in liquid flow rate for glass beads and tablets and remains almost constant for extrudates. The values of mean residence time obtained from model simulation were found to be in good agreement with the values measured experimentally. (author)

  19. Carbon coated (carbonous) catalyst in ebullated bed reactor for production of oxygenated chemicals from syngas/CO2

    International Nuclear Information System (INIS)

    This report summarizes the work completed under DOE's Support of Advanced Fuel Research program, Contract No. DE-FG26-99FT40681. The contract period was October 2000 through September 2002. This R and D program investigated the modification of the mechanical strength of catalyst extrudates using Hydrocarbon Technologies, Inc. (HTI) carbon-coated catalyst technology so that the ebullated bed technology can be utilized to produce valuable oxygenated chemicals from syngas/CO2 efficiently and economically. Exothermic chemical reactions benefit from the temperature control and freedom from catalyst fouling provided by the ebullated bed reactor technology. The carbon-coated extrudates prepared using these procedures had sufficient attrition resistance and surface area for use in ebullated bed operation. The low cost of carbon coating makes the carbon-coated catalysts highly competitive in the market of catalyst extrudates

  20. Design of a Novel Fluidized Bed Reactor To Enhance Sorbent Performance in CO2 Capture Systems Using CaO

    OpenAIRE

    Diego de Paz, María Elena; Arias Rozada, Borja; Grasa, Gemma; Abanades García, Juan Carlos

    2014-01-01

    This work deals with the modeling and design of a novel bubbling fluidized bed reactor that aims to improve the CO2 carrying capacity of CaO particles in CO2 capture systems by calcium looping (CaL). Inside the new reactor (the recarbonator) the particles that arrive from the carbonator of the CaL system react with a concentrated stream of CO2, thereby increasing their carbonate content up to a certain value, which can be predicted by means of the model proposed. The recarbonator model presen...

  1. Bisphenol A removal by a Pseudomonas aeruginosa immobilized on granular activated carbon and operating in a fluidized bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Mita, Luigi [National Laboratory on Endocrine Disruptors, National Institute of Biostructures and Biosystems (INBB), Via P. Castellino, 111, 80131 Naples (Italy); Institute of Genetic and Biophysics “ABT”, Via P. Castellino, 111, 80131 Naples Italy (Italy); Grumiro, Laura [National Laboratory on Endocrine Disruptors, National Institute of Biostructures and Biosystems (INBB), Via P. Castellino, 111, 80131 Naples (Italy); Rossi, Sergio [Institute of Genetic and Biophysics “ABT”, Via P. Castellino, 111, 80131 Naples Italy (Italy); Bianco, Carmen; Defez, Roberto [Institute of Biosciences and BioResources, Via P. Castellino, 111, 80131 Naples (Italy); Gallo, Pasquale [Dipartimento di Chimica, Istituto Zooprofilattico Sperimentale del Mezzogiorno, Via della Salute 2, 80055 Portici, Naples (Italy); Mita, Damiano Gustavo, E-mail: mita@igb.cnr.it [National Laboratory on Endocrine Disruptors, National Institute of Biostructures and Biosystems (INBB), Via P. Castellino, 111, 80131 Naples (Italy); Institute of Genetic and Biophysics “ABT”, Via P. Castellino, 111, 80131 Naples Italy (Italy); Diano, Nadia [National Laboratory on Endocrine Disruptors, National Institute of Biostructures and Biosystems (INBB), Via P. Castellino, 111, 80131 Naples (Italy); Department of Experimental Medicine, Second University of Naples, Via S.M. di Costantinopoli, 16, 80138 Naples Italy (Italy)

    2015-06-30

    Highlights: • A fluidized bed reactor, filled with a Pseudomonas aeruginosa immobilized on GAC, has been used for BPA removal. • BPA removal resulted from a biological activated carbon (BAC) process. • Equations describing the results have been indicated. • BPA removal was analyzed as a function of time and biofilm reuse. - Abstract: Serratia rubidiae, Pseudomonas aeruginosa and Escherichia coli K12 have been studied for their ability of Bisphenol A removal from aqueous systems and biofilm formation on activated granule carbon. Mathematical equations for biodegradation process have been elaborated and discussed. P. aeruginosa was found the best strain to be employed in the process of Bisphenol A removal. The yield in BPA removal of a P. aeruginosa biofilm grown on GAC and operating in a fluidized bed reactor has been evaluated. The results confirm the usefulness in using biological activated carbon (BAC process) to remove phenol compounds from aqueous systems.

  2. Bisphenol A removal by a Pseudomonas aeruginosa immobilized on granular activated carbon and operating in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Highlights: • A fluidized bed reactor, filled with a Pseudomonas aeruginosa immobilized on GAC, has been used for BPA removal. • BPA removal resulted from a biological activated carbon (BAC) process. • Equations describing the results have been indicated. • BPA removal was analyzed as a function of time and biofilm reuse. - Abstract: Serratia rubidiae, Pseudomonas aeruginosa and Escherichia coli K12 have been studied for their ability of Bisphenol A removal from aqueous systems and biofilm formation on activated granule carbon. Mathematical equations for biodegradation process have been elaborated and discussed. P. aeruginosa was found the best strain to be employed in the process of Bisphenol A removal. The yield in BPA removal of a P. aeruginosa biofilm grown on GAC and operating in a fluidized bed reactor has been evaluated. The results confirm the usefulness in using biological activated carbon (BAC process) to remove phenol compounds from aqueous systems

  3. Electrical conductivity as a state indicator for the start-up period of anaerobic fixed-bed reactors.

    Science.gov (United States)

    Robles, A; Latrille, E; Ribes, J; Bernet, N; Steyer, J P

    2016-01-01

    The aim of this work was to analyse the applicability of electrical conductivity sensors for on-line monitoring the start-up period of an anaerobic fixed-bed reactor. The evolution of bicarbonate concentration and methane production rate was analysed. Strong linear relationships between electrical conductivity and both bicarbonate concentration and methane production rate were observed. On-line estimations of the studied parameters were carried out in a new start-up period by applying simple linear regression models, which resulted in a good concordance between both observed and predicted values. Electrical conductivity sensors were therefore identified as an interesting method for monitoring the start-up period of anaerobic fixed-bed reactors due to its reliability, robustness, easy operation, low cost, and minimum maintenance compared with the currently used sensors. PMID:27148733

  4. Green synthesis of isopropyl myristate in novel single phase medium Part II: Packed bed reactor (PBR studies

    Directory of Open Access Journals (Sweden)

    Rajeshkumar N. Vadgama

    2015-12-01

    Full Text Available Isopropyl myristate is a useful functional molecule responding to the requirements of numerous fields of application in cosmetic, pharmaceutical and food industry. In the present work, lipase-catalyzed production of isopropyl myristate by esterification of myristic acid with isopropyl alcohol (molar ratio of 1:15 in the homogenous reaction medium was performed on a bench-scale packed bed reactors, in order to obtain suitable reaction performance data for upscaling. An immobilized lipase B from Candida antartica was used as the biocatalyst based on our previous study. The process intensification resulted in a clean and green synthesis process comprising a series of packed bed reactors of immobilized enzyme and water dehydrant. In addition, use of the single phase reaction system facilitates efficient recovery of the product with no effluent generated and recyclability of unreacted substrates. The single phase reaction system coupled with a continuous operating bioreactor ensures a stable operational life for the enzyme.

  5. Phenomenological method investigation of pebble flow dynamics in two-dimensional two-region pebble-bed reactor

    International Nuclear Information System (INIS)

    By means of the four basic forms of the phenomenological method, the experimental research was carried out according to the principle of similarity criterion to simulate 2D pebble flow dynamics of high-temperature gas-cooled reactor. The result indicates that the test with circulating pebble-loading mode obviously presents better the situation in the real pebble bed reactor. The pebble flow dynamics spreads from bottom to top and from middle to sides. The movement of pebbles in central region is faster than that in annulus region and has no laminar characteristics performance. The mixed zone exists between central region and annulus region, and the distinct stagnant zone also exists at pebble bed bottom corner. (authors)

  6. Nitritation and denitritation of ammonium-rich wastewater using fluidized-bed biofilm reactors

    International Nuclear Information System (INIS)

    Fluidized-bed biofilm nitritation and denitritation reactors (FBBNR and FBBDR) were operated to eliminate the high concentrations of nitrogen by nitritation and denitritation process. The dissolved oxygen (DO) concentration was varied from 1.5 to 2.5 g/m3 at the top of the reactor throughout the experiment. NH4-N conversion and NO2-N accumulation in the nitritation reactor effluent was over 90 and 65%, respectively. The average NH4-N removal efficiency was 99.2 and 90.1% at the NLR of 0.9 and 1.2 kg NH4-N/m3 day, respectively. Increasing the NLR from 1.1 to 1.2 kg NH4-N/m3 day decreased the NH4-N elimination approximately two-fold while NH4-N conversion to NO2-N differences were negligible. The NO2-N/NOx-N ratios corresponded to 0.74, 0.73, 0.72, and 0.69, respectively, indicating the occurrence of partial nitrification. An average free ammonia concentration in the FBBNR was high enough to inhibit nitrite oxidizers selectively, and it seems to be a determining factor for NO2-N accumulation in the process. In the FBBDR, the NOx-N (NO2-N + NO3-N) concentrations supplied were between 227 and 330 mg N/l (NLR was between 0.08 and 0.4 kg/m3 day) and the influent flow was increased as long as the total nitrogen removal was close to 90%. The NO2-N and NO3-N concentrations in the effluent were 3.0 and 0.9 mg/l at 0.08 kg/m3 day loading rate. About 98% removal of NOx-N was achieved at the lowest NLR in the FBBDR. The FBBDR exhibited high nitrogen removal up to the NLR of 0.25 kg/m3 day. The NOx-N effluent concentration never exceeded 15 mg/l. The total nitrogen removal efficiency in the FBBRs was higher than 93% at 21 ± 1 deg. C

  7. Reactivity control system of a passively safe thorium breeder pebble bed reactor

    International Nuclear Information System (INIS)

    Highlights: • A worth of over 15,000 pcm ensures achieving long-term cold shutdown in thorium PBR. • Control rod worth in side reflector is insufficient due to low-power breeder zone. • 20 control rods, just outside the driver zone, can achieve long-term cold shutdown. • BF3 gas can be inserted for reactor shutdown, but only in case of emergency. • Perturbation theory accurately predicts absorber gas worth for many concentrations. - Abstract: This work investigates the neutronic design of the reactivity control system for a 100 MWth passively safe thorium breeder pebble bed reactor (PBR), a conceptual design introduced previously by the authors. The thorium PBR consists of a central driver zone of 100 cm radius, surrounded by a breeder zone with 300 cm outer radius. The fissile content of the breeder zone is low, leading to low fluxes in the radial reflector region. Therefore, a significant decrease of the control rod worth at this position is anticipated. The reactivity worth of control rods in the side reflector and at alternative in-core positions is calculated using different techniques, being 2D neutron diffusion, perturbation theory and more accurate 3D Monte Carlo models. Sensitivity coefficients from perturbation theory provide a first indication of effective control rod positions, while the 2D diffusion models provide an upper limit on the reactivity worth achievable at a certain radial position due to the homogeneous spreading of the absorber material over the azimuthal domain. Three dimensional forward calculations, e.g. in KENO, are needed for an accurate calculation of the total control rod worth. The two dimensional homogeneous calculations indicate that the reactivity worth in the radial reflector is by far insufficient to achieve cold reactor shutdown, which requires a control rod worth of over 15 000 pcm. Three dimensional heterogeneous KENO calculations show that placing 20 control rods just outside the driver channel, between 100 cm and

  8. Particle-bed gas-cooled fast reactor (PB-GCFR) design. Project final technical report (Sept 2001 - Aug 2003)

    International Nuclear Information System (INIS)

    The objective of this project is to develop a conceptual design of a particle-bed, gas-cooled fast reactor (PB-GCFR) core that meets the advanced reactor concept and enhanced proliferation-resistant goals of the US Department of Energy's NERI program. The key innovation of this project is the application of a fast neutron spectrum environment to enhance both the passive safety and transmutation characteristics of the advanced particle-bed and pebble-bed reactor designs. The PB-GCFR design is expected to produce a high-efficiency system with a low unit cost. It is anticipated that the fast neutron spectrum would permit small-sized units (∼ 150 MWe) that can be built quickly and packaged into modular units, and whose production can be readily expanded as the demand grows. Such a system could be deployed globally. The goals of this two-year project are as follows: (1) design a reactor core that meets the future needs of the nuclear industry, by being passively safe with reduced need for engineered safety systems. This will entail an innovative core design incorporating new fuel form and type; (2) employ a proliferation-resistant fuel design and fuel cycle. This will be supported by a long-life core design that is refueled infrequently, and hence, reduces the potential for fuel diversion; (3) incorporate design features that permit use of the system as an efficient transmuter that could be employed for burning separated plutonium fuel or recycled LWR transuranic fuel, should the need arise; and (4) evaluate the fuel cycle for waste minimization and for the possibility of direct fuel disposal. The application of particle-bed fuel provides the promise of extremely high burnup and fission-product protection barriers that may permit direct disposal

  9. PORE-SCALE SIMULATION OF FLUID FLOW IN PACKED-BED REACTORS VIA RIGID-BODY SIMULATIONS AND CFD

    OpenAIRE

    Icardi, Matteo; Marchisio, Daniele,; Boccardo, Gianluca

    2014-01-01

    The problem of fluid flow in porous media is of paramount importance in the process, oil and metallurgical industries, since it is involved in the extraction of minerals and oil, in aquifer dynamics, as well as chemical reactions carried out in fixed bed catalytic reactors. Its CFD simulation is particularly interesting, as it offers the possibility of reducing the extent of costly experimental investigations, but presents a number of technical challenges. One of the main issues is the genera...

  10. The preliminary analysis on the steady-state and kinetic features of the molten salt pebble-bed reactor

    International Nuclear Information System (INIS)

    A novel design concept of molten salt pebble-bed reactor with an ultra-simplified integral primary circuit called 'Nuclear Hot Spring' has been proposed, featured by horizontal coolant flow in a deep pool pebble-bed reactor, providing 'natural safety' features with natural circulation under full power operation and less expensive primary circuit arrangement. In this work, the steady-state physical properties of the equilibrium state of the molten salt pebble-bed reactor are calculated by using the VSOP code, and the steady-state thermo-hydraulic analysis is carried out based on the approximation of absolutely horizontal flow of the coolant through the core. A new concept of 2-dimensional, both axial and radial, multi-pass on-line fuelling scheme is presented. The result reveals that the radial multi-pass scheme provides more flattened power distribution and safer temperature distribution than the one-pass scheme. A parametric analysis is made corresponding to different pebble diameters, the key parameter of the core resistance and the temperature at the pebble center. It is verified that within a wide range of pebble diameters, the maximum pebble center temperatures are far below the safety limit of the fuel, and the core resistance is considerably less than the buoyant force, indicating that the natural circulation under full power operation is achievable and the ultra-simplified integral primary circuit without any pump is possible. For the kinetic properties, it is verified that the negative temperature coefficient is achieved in sufficient under-moderated condition through the preliminary analysis on the temperature coefficients of fuel, coolant and moderator. The requirement of reactivity compensation at the shutdown stages of the operation period is calculated for the further studies on the reactivity control. The molten salt pebble-bed reactor with horizontal coolant flow can provide enhanced safety and economical features. (authors)

  11. Functionalization of polymers using an atmospheric plasma jet in a fluidized bed reactor and the impact on SLM-processes

    OpenAIRE

    Sachs, Marius; Schmitt, Adeliene; Peukert, Wolfgang; Wirth, Karl-Ernst

    2014-01-01

    In order to improve thermoplastics (e.g. Polyamide, Polypropylene and Polyethylene) for Selective Laser Beam Melting (SLM) processes a new approach to functionalize temperature sensitive polymer powders in a large scale is investigated. This is achieved by combining an atmospheric pressure plasma jet and a fluidized bed reactor. Using pressurized air as the plasma gas, radicals like OH* are created. The functionalization leads to an increase of the hydrophilicity of the treated polymer powder...

  12. Conceptual process design of a CaO/Ca(OH)2 thermochemical energy storage system using fluidized bed reactors

    International Nuclear Information System (INIS)

    This paper analyses a thermochemical energy storage process using a CaO/Ca(OH)2 chemical loop. A single circulating fluidized bed reactor is proposed to carry out the hydration-dehydration alternating reactions. During the energy discharge step, steam is fed to the reactor and used as a fluidizing gas and as a reactant with the CaO coming from a silo, enabling heat to be recovered at a sufficiently high temperature (around 743 K) from the hydration reaction taking place in the fluidized bed. During the dehydration of Ca(OH)2 (energy charging step), heat (i.e. from a concentrated solar field) is stored in thermochemical form as CaO by using steam as a fluidizing gas. A basic process integration scheme for a reference case with a power output of 100 MWt is analysed in this work, by solving the mass and energy balances during charging and discharging steps and by calculating the volume of the silos and characteristic dimensions of the fluidized bed reactor. The effective energy storage densities of the CaO silo is shown to be over 260 kWh/m3 with reasonable activities of the solids when storing CaO solids in the silo at around 813 K. - Highlights: • Novel process concept using CaO/Ca(OH)2 cycle for thermochemical energy storage . • Design of a circulating fluidized bed reactor coupled with low cost solid storage silos. • Reaction under steam at 743–813 K for both hydration/dehydration shown to be effective. • Εnergy storage density over 260 kWh/m3 for solids with increment in conversion of 0.6

  13. The effects of temperatures on the pebble flow in a pebble bed high temperature reactor

    International Nuclear Information System (INIS)

    The core of a pebble bed high temperature reactor (PBHTR) moves during operation, a feature which leads to better fuel economy (online refueling with no burnable poisons) and lower fuel stress. The pebbles are loaded at the top and trickle to the bottom of the core after which the burnup of each is measured. The pebbles that are not fully burned are recirculated through the core until the target burnup is achieved. The flow pattern of the pebbles through the core is of importance for core simulations because it couples the burnup distribution to the core temperature and power profiles, especially in cores with two or more radial burnup 'zones '. The pebble velocity profile is a strong function of the core geometry and the friction between the pebbles and the surrounding structures (other pebbles or graphite reflector blocks). The friction coefficient for graphite in a helium environment is inversely related to the temperature. The Thorium High Temperature Reactor (THTR) operated in Germany between 1983 and 1989. It featured a two-zone core, an inner core (IC) and outer core (OC), with different fuel mixtures loaded in each zone. The rate at which the IC was refueled relative to the OC in THTR was designed to be 0.56. During its operation, however, this ratio was measured to be 0.76, suggesting the pebbles in the inner core traveled faster than expected. It has been postulated that the positive feedback effect between inner core temperature, burnup, and pebble flow was underestimated in THTR. Because of the power shape, the center of the core in a typical cylindrical PBHTR operates at a higher temperature than the region next to the side reflector. The friction between pebbles in the IC is lower than that in the OC, perhaps causing a higher relative flow rate and lower average burnup, which in turn yield a higher local power density. Furthermore, the pebbles in the center region have higher velocities than the pebbles next to the side reflector due to the

  14. Integrated detoxification methodology of hazardous phenolic wastewaters in environmentally based trickle-bed reactors: Experimental investigation and CFD simulation

    International Nuclear Information System (INIS)

    Centralized environmental regulations require the use of efficient detoxification technologies for the secure disposal of hazardous wastewaters. Guided by federal directives, existing plants need reengineering activities and careful analysis to improve their overall effectiveness and to become environmentally friendly. Here, we illustrate the application of an integrated methodology which encompasses the experimental investigation of catalytic wet air oxidation and CFD simulation of trickle-bed reactors. As long as trickle-bed reactors are determined by the flow environment coupled with chemical kinetics, first, on the optimization of prominent numerical solution parameters, the CFD model was validated with experimental data taken from a trickle bed pilot plant specifically designed for the catalytic wet oxidation of phenolic wastewaters. Second, several experimental and computational runs were carried out under unsteady-state operation to evaluate the dynamic performance addressing the TOC concentration and temperature profiles. CFD computations of total organic carbon conversion were found to agree better with experimental data at lower temperatures. Finally, the comparison of test data with simulation results demonstrated that this integrated framework was able to describe the mineralization of organic matter in trickle beds and the validated consequence model can be exploited to promote cleaner remediation technologies of contaminated waters.

  15. Integrated detoxification methodology of hazardous phenolic wastewaters in environmentally based trickle-bed reactors: Experimental investigation and CFD simulation

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Rodrigo J.G., E-mail: rodrigo@eq.uc.pt [Centro de Investigacao em Engenharia dos Processos Quimicos e Produtos da Floresta (CIEPQPF), GERSE - Group on Environmental, Reaction and Separation Engineering, Department of Chemical Engineering, University of Coimbra, Rua Silvio Lima, Polo II - Pinhal de Marrocos, 3030-790 Coimbra (Portugal); Almeida, Teresa S.A.; Quinta-Ferreira, Rosa M. [Centro de Investigacao em Engenharia dos Processos Quimicos e Produtos da Floresta (CIEPQPF), GERSE - Group on Environmental, Reaction and Separation Engineering, Department of Chemical Engineering, University of Coimbra, Rua Silvio Lima, Polo II - Pinhal de Marrocos, 3030-790 Coimbra (Portugal)

    2011-05-15

    Centralized environmental regulations require the use of efficient detoxification technologies for the secure disposal of hazardous wastewaters. Guided by federal directives, existing plants need reengineering activities and careful analysis to improve their overall effectiveness and to become environmentally friendly. Here, we illustrate the application of an integrated methodology which encompasses the experimental investigation of catalytic wet air oxidation and CFD simulation of trickle-bed reactors. As long as trickle-bed reactors are determined by the flow environment coupled with chemical kinetics, first, on the optimization of prominent numerical solution parameters, the CFD model was validated with experimental data taken from a trickle bed pilot plant specifically designed for the catalytic wet oxidation of phenolic wastewaters. Second, several experimental and computational runs were carried out under unsteady-state operation to evaluate the dynamic performance addressing the TOC concentration and temperature profiles. CFD computations of total organic carbon conversion were found to agree better with experimental data at lower temperatures. Finally, the comparison of test data with simulation results demonstrated that this integrated framework was able to describe the mineralization of organic matter in trickle beds and the validated consequence model can be exploited to promote cleaner remediation technologies of contaminated waters.

  16. Integrated detoxification methodology of hazardous phenolic wastewaters in environmentally based trickle-bed reactors: Experimental investigation and CFD simulation.

    Science.gov (United States)

    Lopes, Rodrigo J G; Almeida, Teresa S A; Quinta-Ferreira, Rosa M

    2011-05-15

    Centralized environmental regulations require the use of efficient detoxification technologies for the secure disposal of hazardous wastewaters. Guided by federal directives, existing plants need reengineering activities and careful analysis to improve their overall effectiveness and to become environmentally friendly. Here, we illustrate the application of an integrated methodology which encompasses the experimental investigation of catalytic wet air oxidation and CFD simulation of trickle-bed reactors. As long as trickle-bed reactors are determined by the flow environment coupled with chemical kinetics, first, on the optimization of prominent numerical solution parameters, the CFD model was validated with experimental data taken from a trickle bed pilot plant specifically designed for the catalytic wet oxidation of phenolic wastewaters. Second, several experimental and computational runs were carried out under unsteady-state operation to evaluate the dynamic performance addressing the TOC concentration and temperature profiles. CFD computations of total organic carbon conversion were found to agree better with experimental data at lower temperatures. Finally, the comparison of test data with simulation results demonstrated that this integrated framework was able to describe the mineralization of organic matter in trickle beds and the validated consequence model can be exploited to promote cleaner remediation technologies of contaminated waters. PMID:21377790

  17. The development and use of a laboratory scale reactor to study aspects of gasification in an air blown fluidised bed

    Energy Technology Data Exchange (ETDEWEB)

    Cousins, A.; Zhuo, Y.; Reed, G.P.; Paterson, N.; Dugwell, D.R.; Kandiyoti, R. [Imperial College London, London (United Kingdom). Dept of Chemical Engineering

    2006-07-01

    A laboratory scale reactor has been used to study aspects of air blown, spouted bed gasifiers. The effects of operating conditions on the release of fuel-N has been studied using both coal and sewage sludge. The work has clarified the reactions involved and shown that steam has an important effect on the formation of NH{sub 3} from both volatile-N and char-N. The HCN concentration depends strongly on the residence time at temperature and on the presence (and depth) of a char bed. Trace element results indicate that bed temperatures above 900{sup o}C enhanced depletion of Ba, Pb and Zn from the bed residue and their enrichment in the fines. Mercury and selenium were released and their subsequent capture required low temperature filters operating below 120{sup o}C. The reactor was modified to enable char samples to be prepared and collected under controlled conditions. Results show the decreasing reactivity of the char with increasing temperature, time, pressure and particle size. There appears to be an initial decrease in reactivity during pyrolysis and a further longer- term decrease caused by graphitisation. 10 refs., 8 figs., 6 tabs.

  18. Calcium oxide/carbon dioxide reactivity in a packed bed reactor of a chemical heat pump for high-temperature gas reactors

    International Nuclear Information System (INIS)

    The thermal performance of a chemical heat pump that uses a calcium oxide/carbon dioxide reaction system was discussed as a heat storage system for utilizing heat output from high temperature gas reactors (HTGR). Calcium oxide/carbon dioxide reactivity for the heat pump was measured using a packed bed reactor containing 1.0 kg of reactant. The reactor was capable of storing heat at 900 deg. C by decarbonation of calcium carbonate and generating up to 997 deg. C by carbonation of calcium oxide. The amount of stored heat in the reactor was 800-900 kJ kg-1. The output temperature of the reactor could be controlled by regulating the carbonation pressure. The thermal storage performance of the reactor was superior to that of conventional sensible heat storage systems. A heat pump using this CaO/CO2 reactor is expected to contribute to thermal load leveling and to realize highly efficient utilization of HTGR output due to the high heat storage density and high-quality temperature output of the heat pump

  19. Effect of various sources of organic carbon and high nitrite and nitrate concentrations on the selection of denitrifying bacteria. II. Continuous cultures in packed bed reactors.

    Science.gov (United States)

    Błaszczyk, M

    1983-01-01

    The effect of different organic compounds, nitrites and nitrates at the concentration of 1,000 mg N/l on the quantitative and strain-specific selection of denitrifying bacteria was determined in anaerobic packed bed reactors. Both the source of carbon and nitrogen form influenced strain specificity and the frequency of occurrence of denitrifying bacteria. The frequency of denitrifying bacteria within packed bed reactor ranged in different media from 11% (glucose and nitrates) to 100% (methanol and ethanol with nitrates). A single species selection was observed in the presence of nitrites within packed bed reactor: Pseudomonas aeruginosa in medium with acetate. Pseudomonas stutzeri in medium with ethanol, Pseudomonas mendocina in medium with methanol and Pseudomonas fluorescens in medium with glucose. When nitrates were present in packed bed reactor, the dominating bacteria were: P. stutzeri in medium with acetate, P. fluorescens in medium with ethanol, Paracoccus denitrificans in medium with methanol and Alcaligenes faecalis in medium with glucose. PMID:6194668

  20. Unidimensional heat transfer analysis of elephant grass and sugar cane bagasse slow pyrolysis in a fixed bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Mesa-Perez, J.M.; Cortez, L.A.B. [Faculdade de Engenharia Agricola-FEAGRI/UNICAMP, Cidade Universitaria ' Zeferino Vaz' , Barao Geraldo, CP 6011, 13084-971, Campinas SP (Brazil); Rocha, J.D.; Olivares-Gomez, E. [Nucleo Interdisciplinar de Planejamento Energetico, NIPE/UNICAMP, Cidade Universitaria ' Zeferino Vaz' , Barao Geraldo, CP 6086, 13084-971, Campinas SP (Brazil); Brossard-Perez, L.E. [Faculdad de Ingenieria Quimica, Universidade de Oriente Sede Mella, ave, Las Americas sn, Ampliacion de Terraza, Santiago de Cuba, CP 90 600 (Cuba)

    2005-02-25

    Elephant grass (Pennicetum purpureum) and sugar cane bagasse slow pyrolysis experiments was carried out in a fixed bed reactor. A 20-cm internal diameter and 12-cm-long reactor was used. Particulate biomass filled up the reactor volume. Biomass was loaded into the reactor and heated in the axial direction using an electrical resistance located at the reactor's bottom. In order to control the temperature variation during the biomass pyrolysis process, four thermocouples were installed inside of the reactor. The remain residual mass was constant approximately after 73 min of heating; the running was stopped and remain carbonised; material was manually removed from the reactor. The residue formed three layer of biomass visually different described in detail here. Proximate analysis and higher heating value (HHV) tests were carried out to the material in each layer. Mass loss against time was recorded during experiments. The results indicated that the carbonisation ratio decreases in time because the carbon layer has low thermal conductivity and it does not permit proper heat transfer to the upper layer of biomass. It means that technology that avoids high-temperature gradients during the pyrolysis of bulk-dispersed biomass could avoid the problems described before.