WorldWideScience

Sample records for battery charging

  1. Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems

    Science.gov (United States)

    Tuffner, Francis K.; Kintner-Meyer, Michael C. W.; Hammerstrom, Donald J.; Pratt, Richard M.

    2012-05-22

    Battery charging control methods, electric vehicle charging methods, battery charging apparatuses and rechargeable battery systems. According to one aspect, a battery charging control method includes accessing information regarding a presence of at least one of a surplus and a deficiency of electrical energy upon an electrical power distribution system at a plurality of different moments in time, and using the information, controlling an adjustment of an amount of the electrical energy provided from the electrical power distribution system to a rechargeable battery to charge the rechargeable battery.

  2. Modular Battery Charge Controller

    Science.gov (United States)

    Button, Robert; Gonzalez, Marcelo

    2009-01-01

    A new approach to masterless, distributed, digital-charge control for batteries requiring charge control has been developed and implemented. This approach is required in battery chemistries that need cell-level charge control for safety and is characterized by the use of one controller per cell, resulting in redundant sensors for critical components, such as voltage, temperature, and current. The charge controllers in a given battery interact in a masterless fashion for the purpose of cell balancing, charge control, and state-of-charge estimation. This makes the battery system invariably fault-tolerant. The solution to the single-fault failure, due to the use of a single charge controller (CC), was solved by implementing one CC per cell and linking them via an isolated communication bus [e.g., controller area network (CAN)] in a masterless fashion so that the failure of one or more CCs will not impact the remaining functional CCs. Each micro-controller-based CC digitizes the cell voltage (V(sub cell)), two cell temperatures, and the voltage across the switch (V); the latter variable is used in conjunction with V(sub cell) to estimate the bypass current for a given bypass resistor. Furthermore, CC1 digitizes the battery current (I1) and battery voltage (V(sub batt) and CC5 digitizes a second battery current (I2). As a result, redundant readings are taken for temperature, battery current, and battery voltage through the summation of the individual cell voltages given that each CC knows the voltage of the other cells. For the purpose of cell balancing, each CC periodically and independently transmits its cell voltage and stores the received cell voltage of the other cells in an array. The position in the array depends on the identifier (ID) of the transmitting CC. After eight cell voltage receptions, the array is checked to see if one or more cells did not transmit. If one or more transmissions are missing, the missing cell(s) is (are) eliminated from cell

  3. Battery charging stations

    Energy Technology Data Exchange (ETDEWEB)

    Bergey, M.

    1997-12-01

    This paper discusses the concept of battery charging stations (BCSs), designed to service rural owners of battery power sources. Many such power sources now are transported to urban areas for recharging. A BCS provides the opportunity to locate these facilities closer to the user, is often powered by renewable sources, or hybrid systems, takes advantage of economies of scale, and has the potential to provide lower cost of service, better service, and better cost recovery than other rural electrification programs. Typical systems discussed can service 200 to 1200 people, and consist of stations powered by photovoltaics, wind/PV, wind/diesel, or diesel only. Examples of installed systems are presented, followed by cost figures, economic analysis, and typical system design and performance numbers.

  4. 29 CFR 1926.441 - Batteries and battery charging.

    Science.gov (United States)

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Batteries and battery charging. 1926.441 Section 1926.441... for Special Equipment § 1926.441 Batteries and battery charging. (a) General requirements—(1... areas. (2) Ventilation shall be provided to ensure diffusion of the gases from the battery and...

  5. Batteries: Charging ahead rationally

    Science.gov (United States)

    Freunberger, Stefan A.

    2016-06-01

    Redox mediators facilitate the oxidation of the highly insulating discharge product in metal–oxygen batteries during recharge and offer opportunities to achieve high reversible capacities. Now a design principle for selecting redox mediators that can recharge the batteries more efficiently is suggested.

  6. Alternator control for battery charging

    Science.gov (United States)

    Brunstetter, Craig A.; Jaye, John R.; Tallarek, Glen E.; Adams, Joseph B.

    2015-07-14

    In accordance with an aspect of the present disclosure, an electrical system for an automotive vehicle has an electrical generating machine and a battery. A set point voltage, which sets an output voltage of the electrical generating machine, is set by an electronic control unit (ECU). The ECU selects one of a plurality of control modes for controlling the alternator based on an operating state of the vehicle as determined from vehicle operating parameters. The ECU selects a range for the set point voltage based on the selected control mode and then sets the set point voltage within the range based on feedback parameters for that control mode. In an aspect, the control modes include a trickle charge mode and battery charge current is the feedback parameter and the ECU controls the set point voltage within the range to maintain a predetermined battery charge current.

  7. Battery Charge Equalizer with Transformer Array

    Science.gov (United States)

    Davies, Francis

    2013-01-01

    High-power batteries generally consist of a series connection of many cells or cell banks. In order to maintain high performance over battery life, it is desirable to keep the state of charge of all the cell banks equal. A method provides individual charging for battery cells in a large, high-voltage battery array with a minimum number of transformers while maintaining reasonable efficiency. This is designed to augment a simple highcurrent charger that supplies the main charge energy. The innovation will form part of a larger battery charge system. It consists of a transformer array connected to the battery array through rectification and filtering circuits. The transformer array is connected to a drive circuit and a timing and control circuit that allow individual battery cells or cell banks to be charged. The timing circuit and control circuit connect to a charge controller that uses battery instrumentation to determine which battery bank to charge. It is important to note that the innovation can charge an individual cell bank at the same time that the main battery charger is charging the high-voltage battery. The fact that the battery cell banks are at a non-zero voltage, and that they are all at similar voltages, can be used to allow charging of individual cell banks. A set of transformers can be connected with secondary windings in series to make weighted sums of the voltages on the primaries.

  8. Battery charging in float vs. cycling environments

    Energy Technology Data Exchange (ETDEWEB)

    COREY,GARTH P.

    2000-04-20

    In lead-acid battery systems, cycling systems are often managed using float management strategies. There are many differences in battery management strategies for a float environment and battery management strategies for a cycling environment. To complicate matters further, in many cycling environments, such as off-grid domestic power systems, there is usually not an available charging source capable of efficiently equalizing a lead-acid battery let alone bring it to a full state of charge. Typically, rules for battery management which have worked quite well in a floating environment have been routinely applied to cycling batteries without full appreciation of what the cycling battery really needs to reach a full state of charge and to maintain a high state of health. For example, charge target voltages for batteries that are regularly deep cycled in off-grid power sources are the same as voltages applied to stand-by systems following a discharge event. In other charging operations equalization charge requirements are frequently ignored or incorrectly applied in cycled systems which frequently leads to premature capacity loss. The cause of this serious problem: the application of float battery management strategies to cycling battery systems. This paper describes the outcomes to be expected when managing cycling batteries with float strategies and discusses the techniques and benefits for the use of cycling battery management strategies.

  9. Control Algorithms Charge Batteries Faster

    Science.gov (United States)

    2012-01-01

    On March 29, 2011, NASA s Mercury Surface, Space Environment, Geochemistry and Ranging (MESSENGER) spacecraft beamed a milestone image to Earth: the first photo of Mercury taken from orbit around the solar system s innermost planet. (MESSENGER is also the first spacecraft to orbit Mercury.) Like most of NASA s deep space probes, MESSENGER is enabled by a complex power system that allows its science instruments and communications to function continuously as it travels millions of miles from Earth. "Typically, there isn't one particular power source that can support the entire mission," says Linda Taylor, electrical engineer in Glenn Research Center s Power Systems Analysis Branch. "If you have solar arrays and you are in orbit, at some point you re going to be in eclipse." Because of this, Taylor explains, spacecraft like MESSENGER feature hybrid power systems. MESSENGER is powered by a two-panel solar array coupled with a nickel hydrogen battery. The solar arrays provide energy to the probe and charge the battery; when the spacecraft s orbit carries it behind Mercury and out of the Sun s light, the spacecraft switches to battery power to continue operations. Typically, hybrid systems with multiple power inputs and a battery acting alternately as storage and a power source require multiple converters to handle the power flow between the devices, Taylor says. (Power converters change the qualities of electrical energy, such as from alternating current to direct current, or between different levels of voltage or frequency.) This contributes to a pair of major concerns for spacecraft design. "Weight and size are big drivers for any space application," Taylor says, noting that every pound added to a space vehicle incurs significant costs. For an innovative solution to managing power flows in a lightweight, cost-effective manner, NASA turned to a private industry partner.

  10. 30 CFR 77.1106 - Battery-charging stations; ventilation.

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Battery-charging stations; ventilation. 77.1106... COAL MINES Fire Protection § 77.1106 Battery-charging stations; ventilation. Battery-charging stations shall be located in well-ventilated areas. Battery-charging stations shall be equipped with...

  11. 46 CFR 112.55-10 - Storage battery charging.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Storage battery charging. 112.55-10 Section 112.55-10... AND POWER SYSTEMS Storage Battery Installation § 112.55-10 Storage battery charging. (a) Each storage battery installation for emergency lighting and power, and starting batteries for an emergency diesel...

  12. Photovoltaic battery charging experience in the Philippines

    Energy Technology Data Exchange (ETDEWEB)

    Navarro, S.T. Jr.

    1997-12-01

    With the turn of the century, people in remote areas still live without electricity. Conventional electrification will hardly reach the remaining 50% of the population of the Philippines in remote areas. With photovoltaic technology, the delivery of electricity to remote areas can be sustainable. Malalison island was chosen as a project site for electrification using photovoltaic technology. With the fragile balance of ecology and seasonal income in this island, the PV electrification proved to be a better option than conventional fossil based electrification. The Solar Battery Charging Station (SBCS) was used to suit the economic and geographical condition of the island. Results showed that the system can charge as many as three batteries in a day for an average fee of $0.54 per battery. Charging is measured by an ampere-hour counter to determine the exact amount of charge the battery received. The system was highly accepted by the local residents and the demand easily outgrew the system within four months. A technical, economic and social evaluation was done. A recovery period of seven years and five months is expected when competed with the conventional battery charging in the mainland. The technical, economic, institutional and social risks faced by the project were analyzed. Statistics showed that there is a potential of 920,000 households that can benefit from PV electrification in the Philippines. The data and experiences gained in this study are valuable in designing SBCS for remote unelectrified communities in the Philippines and other developing countries.

  13. WIND DRIVEN MOBILE CHARGING OF AUTOMOBILE BATTERY

    Directory of Open Access Journals (Sweden)

    SUDHIR KUMAR SINHA

    2011-01-01

    Full Text Available This paper deals with implementation of mobile wind driven generator technology to produce electricity in charging of two wheeler (12V automobile battery. The use of PWM methodology with pulse charging method at a constant rate has been adopted for this purpose. The low speed PMSG driven by wind at speed of 15/40 km/hour has been used to eliminate gear box to achieve high efficiency. The output of three phase bridge rectifier is fed to boost converter which provides pulses of constant current to the battery.

  14. Improving battery charging with solar panels

    Science.gov (United States)

    Boico, Florent Michael

    Recent technological developments in thin-film photovoltaics, such as amorphous silicon and hybrid dye sensitized photovoltaic (PV) cells are leading to new generations of portable solar arrays. These new arrays are lightweight, durable, flexible, and have been reported to achieve power efficiencies of up to 10%. Already, commercial-off-the-shelf arrays exist that have panels embedded in fabric that can be folded to dimensions of less than 12" x 12", yet are able to produce up to 50Watts of power at 12V. These new products make solar power available to various types of applications. In particular, military applications are emerging to give soldier a source of power that can always be at reach. In parallel with these developments, NiMH and Li-ion batteries are increasingly being used to power various equipment. Currently, the military is field testing solar charging of its batteries with portable solar arrays. However, so far, all known charge control algorithm have failed as they commonly falsely detect overcharge at random times in the charging and leave the battery partially charged. The goal of our research is to investigate the origins of failure in existing charge control algorithms and to propose adequate algorithms that would improve the battery charging. Additionally, ways to optimize the generated photovoltaic power is critical for portable solar application as the energy produced is limited. It is known that the use of a DC-DC converter between the solar panel and the load allows optimization of the power delivered by the solar panel when "Maximum Power Point Tracking" is utilized. Therefore we are developing new solutions that address the specific problem of Maximum Power Point Tracking for modular solar panels.

  15. Study on sources of charging lead acid batteries

    Science.gov (United States)

    Diniş, C. M.; Popa, G. N.; Iagăr, A.

    2015-06-01

    The paper presents the general characteristics of lead acid batteries and two charging methods of these batteries. For charging of lead batteries was used an intelligent power source K 8012 (from Velleman). The power source allows fixing the level of the battery voltage and battery capacity. The intelligent power source uses the joint method (at constant current and, then, at constant voltage) and warning that indicates different situations in the charging process. Other method of charging presented in the paper is at constant voltage using a stabilized power source. In the paper experimental measurements were carried out using data acquisition card SER 10 BIT (from Conrad) for charging/ discharging of a lead acid battery 12V/9Ah (using an intelligent power source) and charging of another high capacity lead acid battery 12V/47Ah/390 A (using a stabilized power source). At the discharging of the lead acid batteries it were used automotive lamps as electric loads.

  16. Fast charging of lead/acid batteries

    Energy Technology Data Exchange (ETDEWEB)

    Calasanzio, D. (FIAMM SpA, Montecchio Maggiore (Italy)); Maja, M. (Polytechnical Univ., Turin (Italy). Dept. of Materials Science and Chemical Engineering); Spinelli, P. (Polytechnical Univ., Turin (Italy). Dept. of Materials Science and Chemical Engineering)

    1993-10-15

    A key point in the development of storage batteries for electric vehicles (EVs) is the possibility for fast recharging. It is widely recognized that the lead/acid system represents an excellent candidate for EVs because of the low cost, durability, and expectance of improvements in the near future. The viability of the lead/acid battery for EV applications would be greatly enhanced if fast recharging could be applied to the system without shortening its life. The present paper reports the results obtained by simulating the charging behaviour with a mathematical model that is capable of predicting the behaviour of nonconventional lead/acid cells both on discharge and recharge. The effects of important parameters such as plate dimensions, acid distribution, and porosity of the active mass are taken into account. The data obtained with the simulation are compared with results got from fast-recharge testing of commercial batteries. (orig.)

  17. PIC BASED SOLAR CHARGING CONTROLLER FOR BATTERY

    Directory of Open Access Journals (Sweden)

    Mrs Jaya N. Ingole

    2012-02-01

    Full Text Available Solar resource is unlimited the government is trying to implement the use of Solar panels as an energy source in rural and sub urban areas for lighting the street lights, but the battery used to store the power gets affected due to overcharge & discharges. This paper presents the use of PIC16F72 based solar charger controller for controlling the overcharging and discharging of a solar cell. It works by continuously optimizing the interface between the solar array and battery. First, the variable supply is fixed at 12.8V dc—the voltage of a fully charged battery— and linked to the battery point of the circuit. Cut Off of battery from load voltage is 10.8 volt. A PIC16F72 for small size and inbuilt analog inputs is used to determine voltage level of battery and solar panel..It also describes how the disadvantages of analog circuit are overcome by this controller. The flow chart is also provided.

  18. Charge Efficiency Tests of Lead/Acid Batteries

    Science.gov (United States)

    Rowlette, J. J.

    1984-01-01

    Current, voltage, and gas evolution measured during charge/discharge cycles. Series of standarized tests for evaluating charging efficiency of lead/acid storage batteries described in report. Purpose of tests to provide information for design of battery charger that allows maximum recharge efficiency for electric-vehicle batteries consistent with other operating parameters, such as range, water loss, and cycle life.

  19. Operation Strategy of EV Battery Charging and Swapping Station

    Institute of Scientific and Technical Information of China (English)

    Zhuo Peng; Li Zhang; Ku-An Lu; Jun-Peng Hu; Si Liu

    2014-01-01

    An operation strategy of the electric vehicle (EV) battery charging and swapping station is proposed in the paper. The strategy is established based on comprehensively consideration of the EV charging behaviors and the possible mutual actions between battery charging and swapping. Three energy management strategies can be used in the station:charging period shifting, energy exchange between EVs, and energy supporting from surplus swapping batteries. Then an optimization model which minimizes the total energy management costs of the station is built. The Monte Carlo simulation is applied to analyze the characteristics of the EV battery charging load, and a heuristic algorithm is used to solve the strategy providing the relevant information of EVs and the battery charging and swapping station. The operation strategy can efficiently reduce battery charging during the high electricity price periods and make more reasonable use of the resources. Simulations prove the feasibility and rationality of the strategy.

  20. Battery Management Systems: Accurate State-of-Charge Indication for Battery-Powered Applications

    NARCIS (Netherlands)

    Pop, V.; Bergveld, H.J.; Danilov, D.; Regtien, P.P.L.; Notten, P.H.L.

    2008-01-01

    Battery Management Systems – Universal State-of-Charge indication for portable applications describes the field of State-of-Charge (SoC) indication for rechargeable batteries. With the emergence of battery-powered devices with an increasing number of power-hungry features, accurately estimating the

  1. Efficiency of Pm-147 direct charge radioisotope battery

    Energy Technology Data Exchange (ETDEWEB)

    Kavetskiy, A.; Yakubova, G.; Yousaf, S.M. [TRACE Photonics Inc, 1680 West Polk Avenue, Charleston, IL 61920 (United States); Bower, K., E-mail: kbower@tracephotonics.co [TRACE Photonics Inc, 1680 West Polk Avenue, Charleston, IL 61920 (United States); Robertson, J.D.; Garnov, A. [Department of Chemistry and University of Missouri Research Reactor, 1513 Research Park Drive, Columbia, MO 65211 (United States)

    2011-05-15

    A theoretical analysis is presented here of the efficiency of direct charge radioisotope batteries based on the efficiency of the radioactive source, the system geometry, electrostatic repulsion of beta particles from the collector, the secondary electron emission, and backscattered beta particles from the collector. Efficiency of various design batteries using Pm-147 sources was experimentally measured and found to be in good agreement with calculations. The present approach can be used for predicting the efficiency for different designs of direct charge radioisotope batteries.

  2. Impact of Fast Charging on Life of EV Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, Jeremy; Wood, Eric; Burton, Evan; Smith, Kandler; Pesaran, Ahmad A.

    2015-05-03

    Utilization of public charging infrastructure is heavily dependent on user-specific travel behavior. The availability of fast chargers can positively affect the utility of battery electric vehicles, even given infrequent use. Estimated utilization rates do not appear frequent enough to significantly impact battery life. Battery thermal management systems are critical in mitigating dangerous thermal conditions on long distance tours with multiple fast charge events.

  3. Study of Emergency Power Based on Solar Battery Charging

    OpenAIRE

    Wang Lei; Zhu Mengfu; Chen Ping; Deng Cheng; Liu Zhimeng; Wang Yanan

    2016-01-01

    To study an emergency power based on solar battery charging. Based on the electric-generation principle of solar panel, solar energy is changed into electrical energy. Through voltage conversion circuit and filter circuit, electrical energy is stored in the energy storage battery. The emergency power realizes the conversion from solar energy to electrical energy. The battery control unit has the function of PWM (Pulse-Width Modulation) charging, overcharging protection, over-discharging prote...

  4. Electrochemical model based charge optimization for lithium-ion batteries

    Science.gov (United States)

    Pramanik, Sourav; Anwar, Sohel

    2016-05-01

    In this paper, we propose the design of a novel optimal strategy for charging the lithium-ion battery based on electrochemical battery model that is aimed at improved performance. A performance index that aims at minimizing the charging effort along with a minimum deviation from the rated maximum thresholds for cell temperature and charging current has been defined. The method proposed in this paper aims at achieving a faster charging rate while maintaining safe limits for various battery parameters. Safe operation of the battery is achieved by including the battery bulk temperature as a control component in the performance index which is of critical importance for electric vehicles. Another important aspect of the performance objective proposed here is the efficiency of the algorithm that would allow higher charging rates without compromising the internal electrochemical kinetics of the battery which would prevent abusive conditions, thereby improving the long term durability. A more realistic model, based on battery electro-chemistry has been used for the design of the optimal algorithm as opposed to the conventional equivalent circuit models. To solve the optimization problem, Pontryagins principle has been used which is very effective for constrained optimization problems with both state and input constraints. Simulation results show that the proposed optimal charging algorithm is capable of shortening the charging time of a lithium ion cell while maintaining the temperature constraint when compared with the standard constant current charging. The designed method also maintains the internal states within limits that can avoid abusive operating conditions.

  5. Battery-powered transport systems. Possible methods of automatically charging drive batteries

    Energy Technology Data Exchange (ETDEWEB)

    1981-03-01

    In modern driverless transport systems, not only easy maintenance of the drive battery is important but also automatic charging during times of standstill. Some systems are presented; one system is pointed out in particular in which 100 batteries can be charged at the same time.

  6. Review on Electric Vehicle, Battery Charger, Charging Station and Standards

    Directory of Open Access Journals (Sweden)

    Afida Ayob

    2014-01-01

    Full Text Available Electric vehicles are a new and upcoming technology in the transportation and power sector that have many benefits in terms of economic and environmental. This study presents a comprehensive review and evaluation of various types of electric vehicles and its associated equipment in particular battery charger and charging station. A comparison is made on the commercial and prototype electric vehicles in terms of electric range, battery size, charger power and charging time. The various types of charging stations and standards used for charging electric vehicles have been outlined and the impact of electric vehicle charging on utility distribution system is also discussed.

  7. Charging performance of automotive batteries - An underestimated factor influencing lifetime and reliable battery operation

    Energy Technology Data Exchange (ETDEWEB)

    Sauer, Dirk Uwe; Blanke, Holger; Thele, Marc; Bohlen, Oliver; Schiffer, Julia; Gerschler, Jochen Bernhard [Electrochemical Energy Conversion and Storage Systems Group, Institute for Power Electronics and Electrical Drives (ISEA), RWTH Aachen University, Jaegerstrasse 17/19, D-52066 Aachen (Germany); Karden, Eckhard; Fricke, Birger [Ford Research and Advanced Engineering Europe, Aachen (Germany); Kaiser, Rudi [Fraunhofer Institute for Solar Energy Systems ISE, Freiburg (Germany)

    2007-05-25

    Dynamic charge acceptance and charge acceptance under constant voltage charging conditions are for two reasons essential for lead-acid battery operation: energy efficiency in applications with limited charging time (e.g. PV systems or regenerative braking in vehicles) and avoidance of accelerated ageing due to sulphation. Laboratory tests often use charge regimes which are beneficial for the battery life, but which differ significantly from the operating conditions in the field. Lead-acid batteries in applications with limited charging time and partial-state-of-charge operation are rarely fully charged due to their limited charge acceptance. Therefore, they suffer from sulphation and early capacity loss. However, when appropriate charging strategies are applied most of the lost capacity and thus performance for the user may be recovered. The paper presents several aspects of charging regimes and charge acceptance. Theoretical and experimental investigations show that temperature is the most critical parameter. Full charging within short times can be achieved only at elevated temperatures. A strong dependency of the charge acceptance during charging pulses on the pre-treatment of the battery can be observed, which is not yet fully understood. But these effects have a significant impact on the fuel efficiency of micro-hybrid electric vehicles. (author)

  8. Results of cycling with battery charging management; Resultats de cyclage avec gestion de charge au niveau batterie

    Energy Technology Data Exchange (ETDEWEB)

    Verniolle, J.; Fernandez, C. [European Space Research and Technology Centre, Noordwijk (Netherlands)

    1996-12-31

    In order to investigate the charging mode of an in-series assembly of lithium-carbon battery cells, a test has been performed on 5 commercial cells (18650) of 0.95 Ah nominal capacity. Results show that it is possible to cycle the cells at 80% of their output capacities during more than 2000 cycles. The management of the battery consists in maintaining a constant battery voltage as soon as a cell reaches its limit voltage during constant current charging. The initial dispersion of cells has been maintained practically constant during the cycling and the charge state of all cells has decreased progressively. (J.S.)

  9. Research on Battery Charging-Discharging in New Energy Systems

    Directory of Open Access Journals (Sweden)

    Che Yanbo

    2013-07-01

    Full Text Available As an energy storage component, the battery plays increasingly important role in new energy industry. Charging and discharging system is the vital part of the application of the battery, but the charge and discharge are always designed separately and carried by different part in the traditional application. Additionally, most battery discharge mode and method are always simplified which cannot ensure to meet the demand of power utilization. In the actual energy storage system, the design of the energy converter, which make the power storage and supply as a whole and the design of the charge and discharge method, will play an important role in efficient utilization of the battery system. As a part of the new energy system, the study makes battery and the charging and discharging system as a whole to store energy, which can store and release electric energy high efficiently according to the system state and control the bidirectional flow of energy precisely. Using TMS320F2812 as the control core, the system which integrates charging and discharging with battery monitoring can achieve the bidirectional Buck/Boost power control. It can achieve three-stage charging and selective discharging of the battery. Due to the influence of the diode reverse recovery time, current oscillation will appear. In order to eliminate the oscillation, we can set the circuit to work in critical conduction mode. The experimental result shows that the system can achieve the charging and discharging control of lead-acid battery and increase the battery life time further.

  10. Review on Electric Vehicle, Battery Charger, Charging Station and Standards

    OpenAIRE

    Afida Ayob; Wan Mohd Faizal Wan Mahmood; Azah Mohamed Mohd Zamri Che Wanik; MohdFadzil Mohd Siam; Saharuddin Sulaiman; Abu Hanifah Azit; Mohamed Azrin Mohamed Ali

    2014-01-01

    Electric vehicles are a new and upcoming technology in the transportation and power sector that have many benefits in terms of economic and environmental. This study presents a comprehensive review and evaluation of various types of electric vehicles and its associated equipment in particular battery charger and charging station. A comparison is made on the commercial and prototype electric vehicles in terms of electric range, battery size, charger power and charging time. The various types o...

  11. A NOVEL CHARGE AND DISCHARGE EQUALIZATION SCHEME FOR BATTERY STRINGS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A novel charge/discharge equalization scheme is proposed in thispaper. According to the states of batteries, two equalizing methods are adopted for equalization during different charging and discharging phases. A switched capacitor is utilized during high rate charging and discharging. During the later period of charging and discharging, an auxiliary low power DC/DC converter and the inherent switch modules of a control/monitor unit are used. So it is very simple and efficient. With the developed equalizer, the lifetime of a series battery string can be extended.

  12. Study of Emergency Power Based on Solar Battery Charging

    Directory of Open Access Journals (Sweden)

    Wang Lei

    2016-01-01

    Full Text Available To study an emergency power based on solar battery charging. Based on the electric-generation principle of solar panel, solar energy is changed into electrical energy. Through voltage conversion circuit and filter circuit, electrical energy is stored in the energy storage battery. The emergency power realizes the conversion from solar energy to electrical energy. The battery control unit has the function of PWM (Pulse-Width Modulation charging, overcharging protection, over-discharging protection and over-current protection. It also realizes the fast and safe charging of energy storage battery. The emergency power could provide both 12V AC power for emergency equipment such as miniature PSA oxygen concentrator and 5V USB for electronic equipment (mobile phone, GPS device, rechargeable light, etc..

  13. Influence of plug-in hybrid electric vehicle charging strategies on charging and battery degradation costs

    International Nuclear Information System (INIS)

    The profitability of plug-in hybrid electric vehicles (PHEVs) is significantly influenced by battery aging and electricity costs. Therefore a simulation model for PHEVs in the distribution grid is presented which allows to compare the influence of different charging strategies on these costs. The simulation is based on real-world driving behavior and European Energy Exchange (EEX) intraday prices for obtaining representative results. The analysis of comprehensive lithium-ion battery aging tests performed within this study shows that especially high battery states of charge (SOCs) decrease battery lifetime, whereas the cycling of batteries at medium SOCs only has a minor contribution to aging. Charging strategies that take into account the previously mentioned effects are introduced, and the SOC distributions and cycle loads of the vehicle battery are investigated. It can be shown that appropriate charging strategies significantly increase battery lifetime and reduce charging costs at the same time. Possible savings due to lifetime extension of the vehicle battery are approximately two times higher than revenues due to energy trading. The findings of this work indicate that car manufacturers and energy/mobility providers have to make efforts for developing intelligent charging strategies to reduce mobility costs and thus foster the introduction of electric mobility. - Highlights: ► Modeling of PHEVs based on real-world driving behavior and electricity prices. ► Consideration of battery degradation for the calculation of mobility costs. ► Smart charging decreases battery degradation and electricity costs simultaneously. ► Reduction of battery degradation costs is around two times higher than reduction of electricity costs.

  14. Adaptive coordinated control of engine speed and battery charging voltage

    Institute of Scientific and Technical Information of China (English)

    Jiangyan ZHANG; Xiaohong JIAO

    2008-01-01

    In this paper, the control problem of auxiliary power unit (APU) for hybrid electric vehicles is investigated. An adaptive controller is provided to achieve the coordinated control between the engine speed and the battery charging voltage. The proposed adaptive coordinated control laws for the throttle angle of the engine and the voltage of the power-converter can guarantee not only the asymptotic tracking performance of the engine speed and the regulation of the battery charging voltage, but also the robust stability of the closed loop system under external load changes. Simulation results are given to verify the performance of the proposed adaptive controller.

  15. Management of deep brain stimulator battery failure: battery estimators, charge density, and importance of clinical symptoms.

    Directory of Open Access Journals (Sweden)

    Kaihan Fakhar

    Full Text Available OBJECTIVE: We aimed in this investigation to study deep brain stimulation (DBS battery drain with special attention directed toward patient symptoms prior to and following battery replacement. BACKGROUND: Previously our group developed web-based calculators and smart phone applications to estimate DBS battery life (http://mdc.mbi.ufl.edu/surgery/dbs-battery-estimator. METHODS: A cohort of 320 patients undergoing DBS battery replacement from 2002-2012 were included in an IRB approved study. Statistical analysis was performed using SPSS 20.0 (IBM, Armonk, NY. RESULTS: The mean charge density for treatment of Parkinson's disease was 7.2 µC/cm(2/phase (SD = 3.82, for dystonia was 17.5 µC/cm(2/phase (SD = 8.53, for essential tremor was 8.3 µC/cm(2/phase (SD = 4.85, and for OCD was 18.0 µC/cm(2/phase (SD = 4.35. There was a significant relationship between charge density and battery life (r = -.59, p<.001, as well as total power and battery life (r = -.64, p<.001. The UF estimator (r = .67, p<.001 and the Medtronic helpline (r = .74, p<.001 predictions of battery life were significantly positively associated with actual battery life. Battery status indicators on Soletra and Kinetra were poor predictors of battery life. In 38 cases, the symptoms improved following a battery change, suggesting that the neurostimulator was likely responsible for symptom worsening. For these cases, both the UF estimator and the Medtronic helpline were significantly correlated with battery life (r = .65 and r = .70, respectively, both p<.001. CONCLUSIONS: Battery estimations, charge density, total power and clinical symptoms were important factors. The observation of clinical worsening that was rescued following neurostimulator replacement reinforces the notion that changes in clinical symptoms can be associated with battery drain.

  16. Support vector based battery state of charge estimator

    Science.gov (United States)

    Hansen, Terry; Wang, Chia-Jiu

    This paper investigates the use of a support vector machine (SVM) to estimate the state-of-charge (SOC) of a large-scale lithium-ion-polymer (LiP) battery pack. The SOC of a battery cannot be measured directly and must be estimated from measurable battery parameters such as current and voltage. The coulomb counting SOC estimator has been used in many applications but it has many drawbacks [S. Piller, M. Perrin, Methods for state-of-charge determination and their application, J. Power Sources 96 (2001) 113-120]. The proposed SVM based solution not only removes the drawbacks of the coulomb counting SOC estimator but also produces accurate SOC estimates, using industry standard US06 [V.H. Johnson, A.A. Pesaran, T. Sack, Temperature-dependent battery models for high-power lithium-ion batteries, in: Presented at the 17th Annual Electric Vehicle Symposium Montreal, Canada, October 15-18, 2000. The paper is downloadable at website http://www.nrel.gov/docs/fy01osti/28716.pdf] aggressive driving cycle test procedures. The proposed SOC estimator extracts support vectors from a battery operation history then uses only these support vectors to estimate SOC, resulting in minimal computation load and suitable for real-time embedded system applications.

  17. State of charge estimation in Ni-MH rechargeable batteries

    Energy Technology Data Exchange (ETDEWEB)

    Milocco, R.H. [Grupo Control Automatico y Sistemas (GCAyS), Depto. Electrotecnia, Facultad de Ingenieria, Universidad Nacional del Comahue, Buenos Aires 1400, 8300 Neuquen (Argentina); Castro, B.E. [Instituto de Investigaciones Fisicoquimicas Teoricas y Aplicadas (INIFTA), Universidad Nacional de La Plata, Suc 4, CC16 (1900), La Plata (Argentina)

    2009-10-20

    In this work we estimate the state of charge (SOC) of Ni-MH rechargeable batteries using the Kalman filter based on a simplified electrochemical model. First, we derive the complete electrochemical model of the battery which includes diffusional processes and kinetic reactions in both Ni and MH electrodes. The full model is further reduced in a cascade of two parts, a linear time invariant dynamical sub-model followed by a static nonlinearity. Both parts are identified using the current and potential measured at the terminals of the battery with a simple 1-D minimization procedure. The inverse of the static nonlinearity together with a Kalman filter provide the SOC estimation as a linear estimation problem. Experimental results with commercial batteries are provided to illustrate the estimation procedure and to show the performance. (author)

  18. Design and Comparative Study of Three Photovoltaic Battery Charge Control Algorithms in MATLAB/SIMULINK Environment

    Directory of Open Access Journals (Sweden)

    Ankur Bhattacharjee

    2012-09-01

    Full Text Available This paper contains the design of a three stagesolar battery charge controller and a comparativestudy of this charge control technique with threeconventional solar battery charge controltechniques such as 1. Constant Current (CCcharging, 2. Two stage constant current constantvoltage (CC-CV charging technique. Theanalysis and the comparative study of theaforesaid charging techniques are done inMATLAB/SIMULINK environment. Here thepractical data used to simulate the charge controlalgorithms are based on a 12Volts 7Ah Sealedlead acid battery.

  19. Modeling charge polarization voltage for large lithium-ion batteries in electric vehicles

    OpenAIRE

    Yan Jiang; Caiping Zhang; Weige Zhang; Wei Shi; Qiujiang Liu

    2013-01-01

    Purpose: Polarization voltage of the lithium-ion battery is an important parameter that has direct influence on battery performance. The paper aims to analyze the impedance characteristics of the lithium-ion battery based on EIS data. Design/methodology/approach: The effects of currents, initial SOC of the battery on charge polarization voltage are investigated, which is approximately linear function of charge current. The change of charge polarization voltage is also analyzed with the gradie...

  20. Experiments Study on Charge Technology of Lead-Acid Electric Vehicle Batteries

    Institute of Scientific and Technical Information of China (English)

    LI Wen; ZHANG Cheng-ning

    2008-01-01

    The basic theory of the fast charge and several charge methods are introduced. In order to heighten charge efficiency of valve-regulated lead-acid battery and shorten the charge time, five charge methods are investigated with experiments done on the Digatron BNT 400-050 test bench. Battery current, terminal voltage, capacity, energy and terminal pole temperature during battery experiment were recorded, and corresponding curves were depicted. Battery capacity-time ratio, energy efficiency and energy-temperature ratio are put forward to be the appraising criteria of lead-acid battery on electric vehicle (EV). According to the appraising criteria and the battery curves, multistage-current/negative-pulse charge method is recommended to charge lead-acid EV battery.

  1. Design and Comparative Study of Three Photovoltaic Battery Charge Control Algorithms in MATLAB/SIMULINK Environment

    OpenAIRE

    Ankur Bhattacharjee

    2012-01-01

    This paper contains the design of a three stage solar battery charge controller and a comparative study of this charge control technique with three conventional solar battery charge control techniques such as 1. Constant Current (CC) charging, 2. Two stage constant current constant voltage (CC-CV) charging technique. The analysis and the comparative study of the aforesaid charging techniques are done in MATLAB/SIMULINK environment. Here the practical data used to simulate the charge control a...

  2. Motion charged battery as sustainable flexible-power-unit.

    Science.gov (United States)

    Wang, Sihong; Lin, Zong-Hong; Niu, Simiao; Lin, Long; Xie, Yannan; Pradel, Ken C; Wang, Zhong Lin

    2013-12-23

    Energy harvesting and storage are the two most important energy technologies developed for portable, sustainable, and self-sufficient power sources for mobile electronic systems. However, both have limitations for providing stable direct-current (DC) with an infinite lifetime. Herein, we integrated a triboelectric nanogenerator (TENG)-based mechanical energy harvester with Li-ion-battery (LIB)-based energy storage as a single device for demonstrating a flexible self-charging power unit (SCPU), which allows a battery to be charged directly by ambient mechanical motion. This physical integration enables a new operation mode of the SCPU: the "sustainable mode", in which the LIB stores the TENG-generated electricity while it is driving an external load. With the LIB being replenished by the ambient mechanical energy, the SCPU can keep providing a constant voltage to the load by utilizing the stable difference between the battery's intrinsic electrode potentials. This study will impact the traditional trends of battery research and advance the development of the self-powered systems. PMID:24266595

  3. Fast Charging and Smart Charging Tests for Electric Vehicles Batteries Using Renewable Energy

    Directory of Open Access Journals (Sweden)

    Forero Camacho Oscar Mauricio

    2016-01-01

    Full Text Available Electric Vehicles (EV technologies are still relatively new and under strong development. Although some standardized solutions are being promoted and becoming a new trend, there is an outstanding need for common platforms and sharing of knowledge and core technologies. This paper presents the development of a test platform, including three Li-ion batteries designed for EV applications, and three associated bi-directional power converters, for testing impacts on different advanced loadings of EV batteries. Different charging algorithms/profiles have been tested, including constant current and power, and forced and pulsed power. The aim of the tests has been to study the impact of smart charging and fast charging on the power system, on the battery state of health and degradation, and to find out the limitations of the batteries for a Smart Grid. The paper outlines the advantages and disadvantages of both tests in terms of regulation of the aggregated local power, power capacity and the power exchange with the grid. The smart charging tests performed have demonstrated that even with a simple control algorithm, without any forecasting, it is possible to provide the required charging and at the same time the power system services, reducing the peak power and the energy losses in the power connection line of the power exchange with the national grid.

  4. Li-Ion Battery Charging with a Buck-Boost Power Converter for a Solar Powered Battery Management System

    OpenAIRE

    Chien-Wei Ma; Jaw-Kuen Shiau

    2013-01-01

    This paper analyzes and simulates the Li-ion battery charging process for a solar powered battery management system. The battery is charged using a non-inverting synchronous buck-boost DC/DC power converter. The system operates in buck, buck-boost, or boost mode, according to the supply voltage conditions from the solar panels. Rapid changes in atmospheric conditions or sunlight incident angle cause supply voltage variations. This study develops an electrochemical-based equivalent circuit mod...

  5. Model Predictive Control-Based Fast Charging for Vehicular Batteries

    Directory of Open Access Journals (Sweden)

    Zhibin Song

    2011-08-01

    Full Text Available Battery fast charging is one of the most significant and difficult techniques affecting the commercialization of electric vehicles (EVs. In this paper, we propose a fast charge framework based on model predictive control, with the aim of simultaneously reducing the charge duration, which represents the out-of-service time of vehicles, and the increase in temperature, which represents safety and energy efficiency during the charge process. The RC model is employed to predict the future State of Charge (SOC. A single mode lumped-parameter thermal model and a neural network trained by real experimental data are also applied to predict the future temperature in simulations and experiments respectively. A genetic algorithm is then applied to find the best charge sequence under a specified fitness function, which consists of two objectives: minimizing the charging duration and minimizing the increase in temperature. Both simulation and experiment demonstrate that the Pareto front of the proposed method dominates that of the most popular constant current constant voltage (CCCV charge method.

  6. Estimator for Charge Acceptance of Lead Acid Batteries Estimateur d’acceptance de charge des batteries Pb-acide

    Directory of Open Access Journals (Sweden)

    Christen U.

    2012-08-01

    Full Text Available A phenomenological model of lead acid batteries is developed that is then used to construct an estimator for short term charge acceptance. Conceptually, the model is based on a partial differential equation that is discretized for tractability. With observers for the battery current and state of charge, the prediction of the internal states is improved. Since the model is essentially linear, the short term prediction can be implemented in closed form, thus without the need for computationally intensive prediction simulations at each sampling instant. The only nonlinearity, the dependence on temperature, can be incorporated in a linear parameter-varying model. Un modèle phénoménologique des batteries plomb-acide est développé et utilisé pour réaliser un estimateur d’acceptance de charge à court terme. Conceptuellement, le modèle est basé sur une équation différentielle partielle qui est discrétisée pour simplifier. La prédiction des états du modèle est améliorée par l’utilisation d’observateurs du courant et de la charge de la batterie. Comme le modèle est essentiellement linéaire, la prédiction à court terme peut être formulée en forme close. Il n’est donc plus nécessaire d’avoir recours à des simulations complexes à chaque instant d’échantillonnage. La seule dépendance non-linéaire, celle à la température, peut être incorporée dans un modèle linéaire à paramètre variable.

  7. Handbook of secondary storage batteries and charge regulators in photovoltaic systems. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1981-08-01

    Solar photovoltaic systems often require battery subsystems to store reserve electrical energy for times of zero insolation. This handbook is designed to help the system designer make optimum choices of battery type, battery size and charge control circuits. Typical battery performance characteristics are summarized for four types of lead-acid batteries: pure lead, lead-calcium and lead-antimony pasted flat plate and lead-antimony tubular positive types. Similar data is also provided for pocket plate nickel cadmium batteries. Economics play a significant role in battery selection. Relative costs of each battery type are summarized under a variety of operating regimes expected for solar PV installations.

  8. Modeling of the charge acceptance of lead-acid batteries

    Energy Technology Data Exchange (ETDEWEB)

    Thele, M.; Schiffer, J.; Sauer, D.U. [Electrochemical Energy Conversion and Storage Systems Group, Institute for Power Electronics and Electrical Drives (ISEA), RWTH Aachen University, Jaegerstrasse 17-19, D-52066 Aachen (Germany); Karden, E.; Surewaard, E. [Ford Research Center Aachen, Aachen (Germany)

    2007-05-25

    This paper presents a model for flooded and VRLA batteries that is parameterized by impedance spectroscopy and includes the overcharging effects to allow charge-acceptance simulations (e.g. for regenerative-braking drive-cycle profiles). The full dynamic behavior and the short-term charge/discharge history is taken into account. This is achieved by a detailed modeling of the sulfate crystal growth and modeling of the internal gas recombination cycle. The model is applicable in the full realistic temperature and current range of automotive applications. For model validation, several load profiles (covering the dynamics and the current range appearing in electrically assisted or hybrid cars) are examined and the charge-acceptance limiting effects are elaborately discussed. The validation measurements have been performed for different types of lead-acid batteries (flooded and VRLA). The model is therefore an important tool for the development of automotive power nets, but it also allows to analyze different charging strategies and energy gains which can be achieved during regenerative-braking. (author)

  9. Method and apparatus for smart battery charging including a plurality of controllers each monitoring input variables

    Science.gov (United States)

    Hammerstrom, Donald J.

    2013-10-15

    A method for managing the charging and discharging of batteries wherein at least one battery is connected to a battery charger, the battery charger is connected to a power supply. A plurality of controllers in communication with one and another are provided, each of the controllers monitoring a subset of input variables. A set of charging constraints may then generated for each controller as a function of the subset of input variables. A set of objectives for each controller may also be generated. A preferred charge rate for each controller is generated as a function of either the set of objectives, the charging constraints, or both, using an algorithm that accounts for each of the preferred charge rates for each of the controllers and/or that does not violate any of the charging constraints. A current flow between the battery and the battery charger is then provided at the actual charge rate.

  10. Design and Comparative Study of Three Photovoltaic Battery Charge Control Algorithms in MATLAB/SIMULINK Environment

    Directory of Open Access Journals (Sweden)

    Ankur Bhattacharjee

    2012-09-01

    Full Text Available This paper contains the design of a three stage solar battery charge controller and a comparative study of this charge control technique with three conventional solar battery charge control techniques such as 1. Constant Current (CC charging, 2. Two stage constant current constant voltage (CC-CV charging technique. The analysis and the comparative study of the aforesaid charging techniques are done in MATLAB/SIMULINK environment. Here the practical data used to simulate the charge control algorithms are based on a 12Volts 7Ah Sealed lead acid battery.

  11. Selection of charge methods for lithium ion batteries by considering diffusion induced stress and charge time

    Science.gov (United States)

    Lu, Bo; Song, Yicheng; Zhang, Junqian

    2016-07-01

    This article demonstrates the design of charging strategies for lithium ion batteries with considering the balance between diffusion induced stress and total charge time for two- and three-stage charge methods. For the two-stage galvanostatic-potentiostatic charge method the low mechanical stress can be achieved without increasing total charge time by switching the galvanostatic to the potentiostatic at the time moment when the lithium concentration at the surface of particles reaches the limit cbarsurf = 0 . A three-stage method, which consists of an initial galvanostatic stage of high current, a galvanostatic stage of low current and a potentiostatic ending stage, is suggested. Employing the initial galvanostatic stage of high current is helpful not only in accelerating the charge process, but also in controlling the mechanical stress once the electrical current and time duration of the initial galvanostatic stage are properly designed.

  12. Application of Genetic Neural Network in Power Battery Charging State-of-Charge Estimation

    Directory of Open Access Journals (Sweden)

    Yongqin Zhou

    2011-03-01

    Full Text Available With global non-renewable resources and environmental issues becoming more apparent, the development of new energy vehicles have become the trend of auto industry. Hybrid vehicle becomes the key development of new energy vehicles with its long distance, low pollution, low fuel consumption characteristics and so on. The battery performances directly influence the quality of the whole vehicle performance. Considering the importance of the battery state of charge (SOC estimation and the nonlinear relationship between the battery SOC and the external characteristic, genetic algorithm (GA and back propagation (BP neural network are proposed. Because of the strong global search capability of the genetic algorithm and the generalization ability of BP neural network, the hybrid vehicle Ni-MH power battery GA-BP charging model is designed. In this approach, the network training speed is superior to the traditional BP network. According to the real-time data of the batteries, the optimal solution can be concluded in a short time and with high estimation precision.

  13. Rating batteries for initial capacity, charging parameters and cycle life in the photovoltaic application

    Energy Technology Data Exchange (ETDEWEB)

    Harrington, S.R. [Ktech Corp., Albuquerque, NM (United States); Hund, T.D. [Sandia National Labs., Albuquerque, NM (United States)

    1995-11-01

    Stand-alone photovoltaic (PV) systems typically depend on battery storage to supply power to the load when there is cloudy weather or no sun. Reliable operation of the load is often dependent on battery performance. This paper presents test procedures for lead-acid batteries which identify initial battery preparation, battery capacity after preparation, charge regulation set-points, and cycle life based on the operational characteristics of PV systems.

  14. Solar photovoltaic charging of high voltage nickel metal hydride batteries using DC power conversion

    Science.gov (United States)

    Kelly, Nelson A.; Gibson, Thomas L.

    There are an increasing number of vehicle choices available that utilize batteries and electric motors to reduce tailpipe emissions and increase fuel economy. The eventual production of electricity and hydrogen in a renewable fashion, such as using solar energy, can achieve the long-term vision of having no tailpipe environmental impact, as well as eliminating the dependence of the transportation sector on dwindling supplies of petroleum for its energy. In this report we will demonstrate the solar-powered charging of the high-voltage nickel-metal hydride (NiMH) battery used in the GM 2-mode hybrid system. In previous studies we have used low-voltage solar modules to produce hydrogen via the electrolysis of water and to directly charge lithium-ion battery modules. Our strategy in the present work was to boost low-voltage PV voltage to over 300 V using DC-DC converters in order to charge the high-voltage NiMH battery, and to regulate the battery charging using software to program the electronic control unit supplied with the battery pack. A protocol for high-voltage battery charging was developed, and the solar to battery charging efficiency was measured under a variety of conditions. We believe this is the first time such high-voltage batteries have been charged using solar energy in order to prove the concept of efficient, solar-powered charging for battery-electric vehicles.

  15. Method of estimating the State-of-Charge and of the use time left of a rechageable battery, and apparatus for executing such a method

    OpenAIRE

    Bergveld, Hendrik Johannes; Pop, Valer; Notten, Petrus Henricus Laurentius

    2006-01-01

    Disclosed is a method of estimating the state-of-charge of a rechargeable battery, taking into account the factors battery spread and ageing. The method comprises the steps of: determining the starting state-of-charge of the battery by measuring the voltage across the battery and converting this measured value into a state-of-charge value; charging the battery; integrating the charge current and determining the accumulated charge during charging of the battery and adding said value to the sta...

  16. Modeling charge polarization voltage for large lithium-ion batteries in electric vehicles

    Directory of Open Access Journals (Sweden)

    Yan Jiang

    2013-06-01

    Full Text Available Purpose: Polarization voltage of the lithium-ion battery is an important parameter that has direct influence on battery performance. The paper aims to analyze the impedance characteristics of the lithium-ion battery based on EIS data. Design/methodology/approach: The effects of currents, initial SOC of the battery on charge polarization voltage are investigated, which is approximately linear function of charge current. The change of charge polarization voltage is also analyzed with the gradient analytical method in the SOC domain. The charge polarization model with two RC networks is presented, and parts of model parameters like Ohmic resistance and charge transfer impedance are estimated by both EIS method and battery constant current testing method. Findings: This paper reveals that the Ohmic resistance accounts for much contribution to battery total polarization compared to charge transfer impedance. Practical implications: Experimental results demonstrate the efficacy of the model with the proposed identification method, which provides the foundation for battery charging optimization. Originality/value: The paper analyzed the impedance characteristics of the lithium-ion battery based on EIS data, presented a charge polarization model with two RC networks, and estimated parameters like Ohmic resistance and charge transfer impedance.

  17. Optimization of Charging Current and SOH Estimation for Lead Acid Batteries

    Directory of Open Access Journals (Sweden)

    Amin Rezaei Pish Robat

    2012-02-01

    Full Text Available In this paper a new model-based approach is used to optimize the charging current of lead acid batteries for use in hybrid electric. The used model is a dynamical nonlinear model and so steepest descent, as a nonlinear optimization technique, is used to design the desired current profile. To verify the results, Unscented Kalman Filter is used to estimate battery capacity as a criterion of the state of health of the battery. Simulation results show that in comparison with multi level charging current, the proposed approach improves the state of health of the battery, up to 2.5% in the first 100 charge/discharge cycle

  18. Extended Kalman Filter with a Fuzzy Method for Accurate Battery Pack State of Charge Estimation

    OpenAIRE

    Saeed Sepasi; Leon R. Roose; Marc M. Matsuura

    2015-01-01

    As the world moves toward greenhouse gas reduction, there is increasingly active work around Li-ion chemistry-based batteries as an energy source for electric vehicles (EVs), hybrid electric vehicles (HEVs) and smart grids. In these applications, the battery management system (BMS) requires an accurate online estimation of the state of charge (SOC) in a battery pack. This estimation is difficult, especially after substantial battery aging. In order to address this problem, this paper utilizes...

  19. FY14 Milestone: Simulated Impacts of Life-Like Fast Charging on BEV Batteries (Management Publication)

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, J.; Wood, E.; Burton, E.; Smith, K.; Pesaran, A.

    2014-09-01

    Fast charging is attractive to battery electric vehicle (BEV) drivers for its ability to enable long-distance travel and quickly recharge depleted batteries on short notice. However, such aggressive charging and the sustained vehicle operation that results could lead to excessive battery temperatures and degradation. Properly assessing the consequences of fast charging requires accounting for disparate cycling, heating, and aging of individual cells in large BEV packs when subjected to realistic travel patterns, usage of fast chargers, and climates over long durations (i.e., years). The U.S. Department of Energy's Vehicle Technologies Office has supported NREL's development of BLAST-V 'the Battery Lifetime Analysis and Simulation Tool for Vehicles' to create a tool capable of accounting for all of these factors. The authors present on the findings of applying this tool to realistic fast charge scenarios. The effects of different travel patterns, climates, battery sizes, battery thermal management systems, and other factors on battery performance and degradation are presented. The primary challenge for BEV batteries operated in the presence of fast charging is controlling maximum battery temperature, which can be achieved with active battery cooling systems.

  20. Process for ending the charging process of a battery. Verfahren zur Beendigung des Ladevorganges einer Akkumulatorenbatterie

    Energy Technology Data Exchange (ETDEWEB)

    Steinig, W.; Obstfelder, I.; Naegler, R.J.

    1986-09-11

    The invention concerns a process for ending the charging process of a battery to be charged with falling current and with a stabilised voltage, in which the value of current is measured at given time intervals and the difference between two successive measurements is formed as a criterion for switching off. According to the invention, on reaching or dropping below a given positive minimum difference (which is not zero) between two results, a pulse is stored and when two pulses are stored in sequence, the charging process is ended. The proposal of the invention achieves reliable switching off of the charging current on reaching the end of charging, without exceeding the end point of the charging process. In particular, the charging current does not have to pass through a minimum, so that batteries which do not have this characteristic can be safely switched off after the charging process has ended. There is therefore a completely correct charge of new and old batteries and correct charging of batteries which have been discharged too far. The possibly damaging post-charge and the socalled compensation charge are omitted, so that the life of the battery can be considerably extended.

  1. Efficiently photo-charging lithium-ion battery by perovskite solar cell

    OpenAIRE

    Xu, Jiantie; Chen, Yonghua; Dai, Liming

    2015-01-01

    Electric vehicles using lithium-ion battery pack(s) for propulsion have recently attracted a great deal of interest. The large-scale practical application of battery electric vehicles may not be realized unless lithium-ion batteries with self-charging suppliers will be developed. Solar cells offer an attractive option for directly photo-charging lithium-ion batteries. Here we demonstrate the use of perovskite solar cell packs with four single CH3NH3PbI3 based solar cells connected in series f...

  2. Efficiently photo-charging lithium-ion battery by perovskite solar cell.

    Science.gov (United States)

    Xu, Jiantie; Chen, Yonghua; Dai, Liming

    2015-08-27

    Electric vehicles using lithium-ion battery pack(s) for propulsion have recently attracted a great deal of interest. The large-scale practical application of battery electric vehicles may not be realized unless lithium-ion batteries with self-charging suppliers will be developed. Solar cells offer an attractive option for directly photo-charging lithium-ion batteries. Here we demonstrate the use of perovskite solar cell packs with four single CH3NH3PbI3 based solar cells connected in series for directly photo-charging lithium-ion batteries assembled with a LiFePO4 cathode and a Li4Ti5O12 anode. Our device shows a high overall photo-electric conversion and storage efficiency of 7.80% and excellent cycling stability, which outperforms other reported lithium-ion batteries, lithium-air batteries, flow batteries and super-capacitors integrated with a photo-charging component. The newly developed self-chargeable units based on integrated perovskite solar cells and lithium-ion batteries hold promise for various potential applications.

  3. Efficiently photo-charging lithium-ion battery by perovskite solar cell.

    Science.gov (United States)

    Xu, Jiantie; Chen, Yonghua; Dai, Liming

    2015-01-01

    Electric vehicles using lithium-ion battery pack(s) for propulsion have recently attracted a great deal of interest. The large-scale practical application of battery electric vehicles may not be realized unless lithium-ion batteries with self-charging suppliers will be developed. Solar cells offer an attractive option for directly photo-charging lithium-ion batteries. Here we demonstrate the use of perovskite solar cell packs with four single CH3NH3PbI3 based solar cells connected in series for directly photo-charging lithium-ion batteries assembled with a LiFePO4 cathode and a Li4Ti5O12 anode. Our device shows a high overall photo-electric conversion and storage efficiency of 7.80% and excellent cycling stability, which outperforms other reported lithium-ion batteries, lithium-air batteries, flow batteries and super-capacitors integrated with a photo-charging component. The newly developed self-chargeable units based on integrated perovskite solar cells and lithium-ion batteries hold promise for various potential applications. PMID:26311589

  4. Electric and hybrid vehicles charge efficiency tests of ESB EV-106 lead acid batteries

    Science.gov (United States)

    Rowlette, J. J.

    1981-01-01

    Charge efficiencies were determined by measurements made under widely differing conditions of temperature, charge procedure, and battery age. The measurements were used to optimize charge procedures and to evaluate the concept of a modified, coulometric state of charge indicator. Charge efficiency determinations were made by measuring gassing rates and oxygen fractions. A novel, positive displacement gas flow meter which proved to be both simple and highly accurate is described and illustrated.

  5. Management of Deep Brain Stimulator Battery Failure: Battery Estimators, Charge Density, and Importance of Clinical Symptoms

    OpenAIRE

    Kaihan Fakhar; Erin Hastings; Butson, Christopher R.; Foote, Kelly D.; Pam Zeilman; Okun, Michael S.

    2013-01-01

    OBJECTIVE: We aimed in this investigation to study deep brain stimulation (DBS) battery drain with special attention directed toward patient symptoms prior to and following battery replacement. BACKGROUND: Previously our group developed web-based calculators and smart phone applications to estimate DBS battery life (http://mdc.mbi.ufl.edu/surgery/dbs-battery-estimator). METHODS: A cohort of 320 patients undergoing DBS battery replacement from 2002-2012 were included in an IRB approved study. ...

  6. Management of Deep Brain Stimulator Battery Failure: Battery Estimators, Charge Density, and Importance of Clinical Symptoms

    OpenAIRE

    Fakhar, Kaihan; Hastings, Erin; Butson, Christopher R.; Foote, Kelly D.; Zeilman, Pam; Okun, Michael S.

    2013-01-01

    Objective We aimed in this investigation to study deep brain stimulation (DBS) battery drain with special attention directed toward patient symptoms prior to and following battery replacement. Background Previously our group developed web-based calculators and smart phone applications to estimate DBS battery life (http://mdc.mbi.ufl.edu/surgery/dbs-battery-estimator). Methods A cohort of 320 patients undergoing DBS battery replacement from 2002–2012 were included in an IRB approved study. Sta...

  7. Study on the Optimal Charging Strategy for Lithium-Ion Batteries Used in Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Shuo Zhang

    2014-10-01

    Full Text Available The charging method of lithium-ion batteries used in electric vehicles (EVs significantly affects its commercial application. This paper aims to make three contributions to the existing literature. (1 In order to achieve an efficient charging strategy for lithium-ion batteries with shorter charging time and lower charring loss, the trade-off problem between charging loss and charging time has been analyzed in details through the dynamic programing (DP optimization algorithm; (2 To reduce the computation time consumed during the optimization process, we have proposed a database based optimization approach. After off-line calculation, the simulation results can be applied to on-line charge; (3 The novel database-based DP method is proposed and the simulation results illustrate that this method can effectively find the suboptimal charging strategies under a certain balance between the charging loss and charging time.

  8. Estimation of State of Charge of Lead Acid Battery using Radial Basis Function

    OpenAIRE

    Sauradip, M; Sinha, SK; K Muthukumar

    2001-01-01

    A Radial Basis Function based learning system method has been proposed for estimation of State of Charge (SOC) of Lead Acid Battery. Coulomb metric method is used for SOC estimation with correction factor computed by Radial Basis Function Method. Radial basis function based technique is used for learning battery performance variation with time and other parameters. Experimental results are included.

  9. Thermal Behavior of Prismatic Lithium-Ion Battery during Rapid Charge and Discharge Cycles

    Science.gov (United States)

    Araki, Takuto; Wakahara, Kenji; Fukuda, Kenichi; Ohmori, Yositake; Nakayama, Masato; Onda, Kazuo

    The temperature of secondary batteries may increase above allowable limits and deteriorate its performance, during rapid charge and discharge cycles. Therefore, assessing thermal behavior of battery is essential. On the other hand, rectangular parallelepiped shape batteries are supposedly going to be used more commonly for cars and electrical devices because of their better space efficiency. Then, we constructed a two dimensional Cartesian coordinates battery thermal behavior model for a prismatic lithium-ion secondary battery during rapid charge and discharge cycles. It was extended from one dimensional cylindrical coordinates model, which had been developed and experimentally verified. As parameters of the numerical model, battery heat source factors such as overpotential resistance, entropy change, heat transfer coefficient and heat capacity have been measured. The radiation thermometer was used for obtaining battery surface temperature variance and distributions. Battery temperature generally increases as charge and discharge cycle proceeds, nevertheless temperature drops were observed at begging of low rate charge cycle and vicinity of SOC=0.8 in discharge cycle. Our modified model could predict these phenomena and agreed well with experimental results. Then the reliability of our numerical model and measuring techniques of heat source factors are confirmed each other.

  10. Lithium-ion Battery Charging System using Constant-Current Method with Fuzzy Logic Based ATmega16

    OpenAIRE

    Rossi Passarella; Ahmad Fali Oklilas; Tarida Mathilda

    2014-01-01

    In this charging system, constant-current charging technique keeps the current flow into the battery on its maximum range of 2A. The use of fuzzy logic control of this charging system is to control the value of PWM. PWM is controlling the value of current flowing to the battery during the charging process. The current value into the battery depends on the value of battery voltage and also its temperature. The cutoff system will occur if the temperature of the battery reaches its maximum range

  11. Lithium-ion Battery Charging System using Constant-Current Method with Fuzzy Logic Based ATmega16

    Directory of Open Access Journals (Sweden)

    Rossi Passarella

    2014-10-01

    Full Text Available In this charging system, constant-current charging technique keeps the current flow into the battery on its maximum range of 2A. The use of fuzzy logic control of this charging system is to control the value of PWM. PWM is controlling the value of current flowing to the battery during the charging process. The current value into the battery depends on the value of battery voltage and also its temperature. The cutoff system will occur if the temperature of the battery reaches its maximum range

  12. Modelling Inductive Charging of Battery Electric Vehicles using an Agent-Based Approach

    Directory of Open Access Journals (Sweden)

    Zain Ul Abedin

    2014-09-01

    Full Text Available The introduction of battery electric vehicles (BEVs could help to reduce dependence on fossil fuels and emissions from transportation and as such increase energy security and foster sustainable use of energy resources. However a major barrier to the introduction of BEVs is their limited battery capacity and long charging durations. To address these issues of BEVs several solutions are proposed such as battery swapping and fast charging stations. However apart from these stationary modes of charging, recently a new mode of charging has been introduced which is called inductive charging. This allows charging of BEVs as they drive along roads without the need of plugs, using induction. But it is unclear, if and how such technology could be utilized best. In order to investigate the possible impact of the introduction of such inductive charging infrastructure, its potential and its optimal placement, a framework for simulating BEVs using a multi-agent transport simulation was used. This framework was extended by an inductive charging module and initial test runs were performed. In this paper we present the simulation results of these preliminary tests together with analysis which suggests that battery sizes of BEVs could be reduced even if inductive charging technology is implemented only at a small number of high traffic volume links. The paper also demonstrates that our model can effectively support policy and decision making for deploying inductive charging infrastructure.

  13. Effects of Electric Vehicle Fast Charging on Battery Life and Vehicle Performance

    Energy Technology Data Exchange (ETDEWEB)

    Matthew Shirk; Jeffrey Wishart

    2015-04-01

    As part of the U.S. Department of Energy’s Advanced Vehicle Testing Activity, four new 2012 Nissan Leaf battery electric vehicles were instrumented with data loggers and operated over a fixed on-road test cycle. Each vehicle was operated over the test route, and charged twice daily. Two vehicles were charged exclusively by AC level 2 EVSE, while two were exclusively DC fast charged with a 50 kW charger. The vehicles were performance tested on a closed test track when new, and after accumulation of 50,000 miles. The traction battery packs were removed and laboratory tested when the vehicles were new, and at 10,000-mile intervals. Battery tests include constant-current discharge capacity, electric vehicle pulse power characterization test, and low peak power tests. The on-road testing was carried out through 70,000 miles, at which point the final battery tests were performed. The data collected over 70,000 miles of driving, charging, and rest are analyzed, including the resulting thermal conditions and power and cycle demands placed upon the battery. Battery performance metrics including capacity, internal resistance, and power capability obtained from laboratory testing throughout the test program are analyzed. Results are compared within and between the two groups of vehicles. Specifically, the impacts on battery performance, as measured by laboratory testing, are explored as they relate to battery usage and variations in conditions encountered, with a primary focus on effects due to the differences between AC level 2 and DC fast charging. The contrast between battery performance degradation and the effect on vehicle performance is also explored.

  14. Lithium-ion Battery Charge Methodologies Observed with Portable Electronic Equipment

    Science.gov (United States)

    Jeevarajan, Judith

    2009-01-01

    Commercial lithium-ion batteries in portable electronic equipment has been used by NASA for space applications since 1999. First battery that was certified for flight and flown for Shuttle use was the Canon BP 927 (2.7 Ah) battery pack. Since then, numerous portable equipment with li-ion batteries have been certified and flown and remain on-orbit for crew usage. Laptops (two generations with third one being worked on now) Camcorder Camera PDA 2 versions (second one being li-ion polymer cells) Satellite Phone Due to expense and time, certified batteries are used with different equipment with the help of adapters or by working with the manufacturer of the equipment to build the appropriate battery compartment and connector. Certified and dedicated chargers are available on Shuttle and on the ISS for safe charging.

  15. Demand Profile Study of Battery Electric Vehicle under Different Charging Options

    DEFF Research Database (Denmark)

    Marra, Francesco; Yang, Guang Ya; Træholt, Chresten;

    2012-01-01

    An increased research on electric vehicles (EV) and plug-in hybrid electric vehicles (PHEV) deals with their flexible use in electric power grids. Several research projects on smart grids and electric mobility are now looking into realistic models representing the behavior of an EV during charging......, including nonlinearities. In this work, modeling, simulation and testing of the demand profile of a battery-EV are conducted. Realistic work conditions for a lithium-ion EV battery and battery charger are considered as the base for the modeling. Simulation results show that EV charging generates different...... demand profiles into the grid, depending on the applied charging option. Moreover, a linear region for the control of EV chargers is identified in the range of 20-90% state-of-charge (SOC). Experiments validate the proposed model....

  16. Discrete carbon nanotubes increase lead acid battery charge acceptance and performance

    Science.gov (United States)

    Swogger, Steven W.; Everill, Paul; Dubey, D. P.; Sugumaran, Nanjan

    2014-09-01

    Performance demands placed upon lead acid batteries have outgrown the technology's ability to deliver. These demands, typically leading to Negative Active Material (NAM) failure, include: short, high-current surges; prolonged, minimal, overvoltage charging; repeated, Ah deficit charging; and frequent deep discharges. Research shows these failure mechanisms are attenuated by inclusion of carbon allotropes into the NAM. Addition of significant quantities of carbon, however, produces detrimental changes in paste rheology, leading to lowered industrial throughput. Additionally, capacity, cold-cranking performance, and other battery metrics are negatively affected at high carbon loads. Presented here is Molecular Rebar® Lead Negative, a new battery additive comprising discrete carbon nanotubes (dCNT) which uniformly disperse within battery pastes during mixing. NS40ZL batteries containing dCNT show enhanced charge acceptance, reserve capacity, and cold-cranking performance, decreased risk of polarization, and no detrimental changes to paste properties, when compared to dCNT-free controls. This work focuses on the dCNT as NAM additives only, but early-stage research is underway to test their functionality as a PAM additive. Batteries infused with Molecular Rebar® Lead Negative address the needs of modern lead acid battery applications, produce none of the detrimental side effects associated with carbon additives, and require no change to existing production lines.

  17. Solar battery charging; Sonne in den Akku laden

    Energy Technology Data Exchange (ETDEWEB)

    Frey, Martin

    2012-01-30

    Swiss battery producer Leclanche intends serial production of lithium ion cells for storage of renewable energy. A production facility at Kehl, Germany, is currently under construction. Schueco International KG is one of the first customers.

  18. Impact of Fast Charging on Life of EV Batteries; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, Jeremy; Wood, Eric; Burton, Evan; Smith, Kandler; Pesaran, Ahmad

    2015-05-03

    Installation of fast charging infrastructure is considered by many as one of potential solutions to increase the utility and range of electric vehicles (EVs). This is expected to reduce the range anxiety of drivers of EVs and thus increase their market penetration. Level 1 and 2 charging in homes and workplaces is expected to contribute to the majority of miles driven by EVs. However, a small percentage of urban driving and most of inter-city driving could be only achieved by a fast-charging network. DC fast charging at 50 kW, 100 kW, 120 kW compared to level 1 (3.3 kW) and level 2 (6.6 kW) results in high-current charging that can adversely impact the life of the battery. In the last couple of years, we have investigated the impact of higher current rates in batteries and potential of higher temperatures and thus lower service life. Using mathematical models, we investigated the temperature increase of batteries due to higher heat generation during fast charge and have found that this could lead to higher temperatures. We compared our models with data from other national laboratories both for fine-tuning and calibration. We found that the incremental temperature rise of batteries during 1C to 3C fast charging may reduce the practical life of the batteries by less than 10% over 10 to 15 years of vehicle ownership. We also found that thermal management of batteries is needed for fast charging to prevent high temperature excursions leading to unsafe conditions.

  19. State of charge monitoring methods for vanadium redox flow battery control

    Science.gov (United States)

    Skyllas-Kazacos, Maria; Kazacos, Michael

    2011-10-01

    During operation of redox flow batteries, differential transfer of ions and electrolyte across the membrane and gassing side reactions during charging, can lead to an imbalance between the two half-cells that results in loss of capacity. This capacity loss can be corrected by either simple remixing of the two solutions, or by chemical or electrochemical rebalancing. In order to develop automated electrolyte management systems therefore, the state-of-charge of each half-cell electrolyte needs to be known. In this study, two state-of-charge monitoring methods are investigated for use in the vanadium redox flow battery. The first method utilizes conductivity measurements to independently measure the state-of-charge of each half-cell electrolyte. The second method is based on spectrophotometric principles and uses the different colours of the charged and discharged anolyte and catholyte to monitor system balance and state-of charge of each half-cell of the VRB during operation.

  20. A new method of modeling and state of charge estimation of the battery

    Science.gov (United States)

    Liu, Congzhi; Liu, Weiqun; Wang, Lingyan; Hu, Guangdi; Ma, Luping; Ren, Bingyu

    2016-07-01

    Accurately estimating the State of Charge (SOC) of the battery is the basis of Battery Management System (BMS). This paper has introduced a new modeling and state estimation method for the lithium battery system, which utilizes the fractional order theories. Firstly, a fractional order model based on the PNGV (Partnership for a New Generation of Vehicle) model is proposed after analyzing the impedance characteristics of the lithium battery and compared with the integer order model. With the observability of the discrete non-linear model of the battery confirmed, the method of the state observer based on the extended fractional Kalman filter (EFKF) and the least square identification method of battery parameters are studied. Then, it has been applied successfully to estimate the battery SOC using the measured battery current and voltage. Finally, a standard HPPC (Hybrid Pulse Power Characteristic) test is used for parameter identification and several experimental validations are investigated on a ternary manganese-nickel-cobalt lithium battery pack with a nominal capacity of 24 Ah which consists of ten Sony commercial cells (US18650GR G7) in parallels. The results demonstrate the effectiveness of the fractional order model and the estimation method.

  1. Extended Kalman Filter with a Fuzzy Method for Accurate Battery Pack State of Charge Estimation

    Directory of Open Access Journals (Sweden)

    Saeed Sepasi

    2015-06-01

    Full Text Available As the world moves toward greenhouse gas reduction, there is increasingly active work around Li-ion chemistry-based batteries as an energy source for electric vehicles (EVs, hybrid electric vehicles (HEVs and smart grids. In these applications, the battery management system (BMS requires an accurate online estimation of the state of charge (SOC in a battery pack. This estimation is difficult, especially after substantial battery aging. In order to address this problem, this paper utilizes SOC estimation of Li-ion battery packs using a fuzzy-improved extended Kalman filter (fuzzy-IEKF for Li-ion cells, regardless of their age. The proposed approach introduces a fuzzy method with a new class and associated membership function that determines an approximate initial value applied to SOC estimation. Subsequently, the EKF method is used by considering the single unit model for the battery pack to estimate the SOC for following periods of battery use. This approach uses an adaptive model algorithm to update the model for each single cell in the battery pack. To verify the accuracy of the estimation method, tests are done on a LiFePO4 aged battery pack consisting of 120 cells connected in series with a nominal voltage of 432 V.

  2. Critical Role of Redox Mediator in Suppressing Charging Instabilities of Lithium-Oxygen Batteries.

    Science.gov (United States)

    Liang, Zhuojian; Lu, Yi-Chun

    2016-06-22

    Redox mediators have been widely applied to reduce the charge overpotentials of lithium-oxygen (Li-O2) batteries. Here, we reveal the critical role of redox mediator in suppressing the charging instability of Li-O2 batteries. Using high temporal resolution online electrochemical mass spectrometry, we show that charging with redox mediators (using lithium bromide as a model system) significantly reduces parasitic gas evolution and improves oxygen recovery efficiency. Using redox mediator transforms the charge reactions from electrochemical pathways to chemical pathways, which unexpectedly bypasses the formation of highly reactive intermediates upon electro-oxidation of lithium peroxide (Li2O2). Such transformation reduces self-amplifying degradation reactions of electrode and electrolyte in Li-O2 cells. We further show that the improved stability associated with the redox mediator is much more pronounced at higher charging rates, owing to fast charge-transfer kinetics of the redox mediator. Together, we show that employing redox mediator not only reduces the charge overpotential but also suppresses side reactions of Li-O2 cells with improved charging rate. Our work demonstrates that transforming electro-oxidation of Li2O2 to chemical oxidation of Li2O2 is a promising strategy to simultaneously mitigate charging side reactions and achieve low overpotential for the Li-O2 batteries. PMID:27228413

  3. A new battery-charging method suggested by molecular dynamics simulations

    CERN Document Server

    Hamad, Ibrahim Abou; Wipf, D; Rikvold, P A; 10.1039/b920970k

    2010-01-01

    Based on large-scale molecular dynamics simulations, we propose a new charging method that should be capable of charging a Lithium-ion battery in a fraction of the time needed when using traditional methods. This charging method uses an additional applied oscillatory electric field. Our simulation results show that this charging method offers a great reduction in the average intercalation time for Li+ ions, which dominates the charging time. The oscillating field not only increases the diffusion rate of Li+ ions in the electrolyte but, more importantly, also enhances intercalation by lowering the corresponding overall energy barrier.

  4. Fast Charging Battery Buses for the Electrification of Urban Public Transport : A Feasibility Study Focusing on Charging Infrastructure and Energy Storage Requirements

    OpenAIRE

    Matthias Rogge; Sebastian Wollny; Dirk Uwe Sauer

    2015-01-01

    The electrification of public transport bus networks can be carried out utilizing different technological solutions, like trolley, battery or fuel cell buses. The purpose of this paper is to analyze how and to what extent existing bus networks can be electrified with fast charging battery buses. The so called opportunity chargers use mainly the regular dwell time at the stops to charge their batteries. This results in a strong linkage between the vehicle scheduling and the infrastructure plan...

  5. An Electric taxi fleet charging system using second life electric car batteries simulation and economical approach

    OpenAIRE

    Canals Casals, Lluc; Amante García, Beatriz

    2013-01-01

    The industrial car manufacturers see in the high battery price an im-portant obstacle for an electric vehicle mass selling, thus mass production. There-fore, in order to find some cost relieves and better selling opportunities, they look and push forward to find profitable second battery uses. This study presents a sim-ulation and an economical approach for an electric taxi fleet charging system, us-ing these “old” electric car batteries, implemented in the city of Barcelona. The simulation w...

  6. Electric vehicle battery charging algorithm using PMSM windings and an inverter as an active rectifier

    DEFF Research Database (Denmark)

    Zaja, Mario; Oprea, Matei-lon; Suárez, Carlos Gómez;

    2014-01-01

    the battery gets discharged below the peak of the grid voltage, typically if the vehicle has not been used for a longer period of time. To avoid high currents that could damage the battery, a voltage suppression mode is introduced for safe depleted battery charging. This paper proposes and analyzes......A major setback for large scale electric vehicle market expansion compared to their internal combustion competitors consists in their high price and low driving range. One way of reducing the cost, dimensions and mass of electric vehicles is to eliminate the dedicated AC/DC converter used...

  7. A new state of charge determination method for battery management system

    Institute of Scientific and Technical Information of China (English)

    ZHU Chun-bo 朱春波; WANG Tie-cheng 王铁成; HURLEY W G

    2004-01-01

    State of Charge (SOC) determination is an increasingly important issue in battery technology. In addition to the immediate display of the remaining battery capacity to the user, precise knowledge of SOC exerts additional control over the charging/discharging process which in turn reduces the risk of over-voltage and gassing, which degrade the chemical composition of the electrolyte and plates. This paper describes a new approach to SOC determination for the lead-acid battery management system by combining Ah-balance with an EMF estimation algorithm, which predicts the battery' s EMF value while it is under load. The EMF estimation algorithm is based on an equivalent-circuit representation of the battery, with the parameters determined from a pulse test performed on the battery and a curve-fitting algorithm by means of least-square regression. The whole battery cycle is classified into seven states where the SOC is estimated with the Ah-balance method and the proposed EMF based algorithm. Laboratory tests and results are described in detail in the paper.

  8. Kalman filtering state of charge estimation for battery management system based on a stochastic fuzzy neural network battery model

    International Nuclear Information System (INIS)

    Highlights: ► A novel extended Kalman Filtering SOC estimation method based on a stochastic fuzzy neural network (SFNN) battery model is proposed. ► The SFNN which has filtering effect on noisy input can model the battery nonlinear dynamic with high accuracy. ► A robust parameter learning algorithm for SFNN is studied so that the parameters can converge to its true value with noisy data. ► The maximum SOC estimation error based on the proposed method is 0.6%. - Abstract: Extended Kalman filtering is an intelligent and optimal means for estimating the state of a dynamic system. In order to use extended Kalman filtering to estimate the state of charge (SOC), we require a mathematical model that can accurately capture the dynamics of battery pack. In this paper, we propose a stochastic fuzzy neural network (SFNN) instead of the traditional neural network that has filtering effect on noisy input to model the battery nonlinear dynamic. Then, the paper studies the extended Kalman filtering SOC estimation method based on a SFNN model. The modeling test is realized on an 80 Ah Ni/MH battery pack and the Federal Urban Driving Schedule (FUDS) cycle is used to verify the SOC estimation method. The maximum SOC estimation error is 0.6% compared with the real SOC obtained from the discharging test.

  9. Computational models of an inductive power transfer system for electric vehicle battery charge

    Science.gov (United States)

    Anele, A. O.; Hamam, Y.; Chassagne, L.; Linares, J.; Alayli, Y.; Djouani, K.

    2015-09-01

    One of the issues to be solved for electric vehicles (EVs) to become a success is the technical solution of its charging system. In this paper, computational models of an inductive power transfer (IPT) system for EV battery charge are presented. Based on the fundamental principles behind IPT systems, 3 kW single phase and 22 kW three phase IPT systems for Renault ZOE are designed in MATLAB/Simulink. The results obtained based on the technical specifications of the lithium-ion battery and charger type of Renault ZOE show that the models are able to provide the total voltage required by the battery. Also, considering the charging time for each IPT model, they are capable of delivering the electricity needed to power the ZOE. In conclusion, this study shows that the designed computational IPT models may be employed as a support structure needed to effectively power any viable EV.

  10. 锂电池充电技术综述%Review of lithium battery charging technology

    Institute of Scientific and Technical Information of China (English)

    何秋生; 徐磊; 吴雪雪

    2013-01-01

    在二次锂电池问世以来,凭借其循环寿命长、比能量高等优良的性能被应用在生产生活的各个领域.充电作为锂电池使用过程中最重要的一环,直接影响着电池的寿命及循环性能.在锂电池最佳充电曲线的基础上,分析了锂电池的各种不同充电方法,比较各自的充电速度、应用范围、电池寿命和循环性能等特性,最后提出了今后研究的方向.%The rechargeable lithium battery with the advantages of long cycle life,high energy density and other excellent performance has been widely used since its development in 1970s.As one of the most important process,charging directly affects the battery life and cycling performance.On the basis of the best lithium battery charging curve,the performance of various lithium battery charging methods was analyzed.Finally,the future investigation on lithium battery charging technology was discussed.

  11. Experimental research on charging characteristics of a pressure-controlled VRLA battery in high-temperature environments

    Institute of Scientific and Technical Information of China (English)

    Hua ZHU; Jin-jun TAN; Zhang-lu XU; Ji-sen XU

    2009-01-01

    Valve-regulated-lead-acid (VRLA) battery charging performed in high-temperature environments is extremely risky under overcharge conditions, and may lead to a subsequent thermal runaway. A new pressure-controlled charging method was adopted and the charging characteristics of the pressure-controlled VRLA battery in high-temperature environments were ex-perimentally studied. The concept was tested in a large temperature gradient to obtain more details about the effects of users' accustomed charging and discharging modes on battery capacity.' The premature capacity loss (PCL) phenomenon under high temperature exposure was analyzed. The results showed that the capacity loss could be recovered by charging using a large current.

  12. Charge pump DC-DC converter comprising solid state batteries

    NARCIS (Netherlands)

    Reefman, D.; Roozeboom, F.; Notten, P.H.L.; Klootwijk, J.H.

    2013-01-01

    An electronic device is provided which comprises a DC-DC converter. The DC-DC converter comprises at least one solid-state rechargeable battery (B1, B2) for storing energy for the DC-DC conversion and an output capacitor (C2).

  13. Intetrated State-of-Charge Circuit for Reschargeable Batteries

    NARCIS (Netherlands)

    Velner, J.

    2008-01-01

    The aim of this work is to create a low power system that can measure positive and negative voltages varying in magnitude from 100 μV to 100 mV with a relative accuracy of 1% or better. These voltages correspond to a current flow to or from a battery powering a DECT IC. Since these currents are quas

  14. Optimal battery charging, Part I: Minimizing time-to-charge, energy loss, and temperature rise for OCV-resistance battery model

    Science.gov (United States)

    Abdollahi, A.; Han, X.; Avvari, G. V.; Raghunathan, N.; Balasingam, B.; Pattipati, K. R.; Bar-Shalom, Y.

    2016-01-01

    In this paper we present a closed-form solution to the problem of optimally charging a Li-ion battery. A combination of three cost functions is considered as the objective function: time-to-charge (TTC), energy losses (EL), and a temperature rise index (TRI). First, we consider the cost function of the optimization problem as a weighted sum of TTC and EL. We show that the optimal charging strategy in this case is the well-known Constant Current-Constant Voltage (CC-CV) policy with the value of the current in the CC stage being a function of the ratio of weighting on TTC and EL and of the resistance of the battery. Then, we extend the cost function to a weighted sum of TTC, EL and TRI and derive an analytical solution for the problem. It is shown that the analytical solution can be approximated by a CC-CV with the value of current in the CC stage being a function of ratio of weighting on TTC and EL, resistance of the battery and the effective thermal resistance.

  15. Charge-discharge characteristics of nickel/zinc battery with polymer hydrogel electrolyte

    Science.gov (United States)

    Iwakura, Chiaki; Murakami, Hiroki; Nohara, Shinji; Furukawa, Naoji; Inoue, Hiroshi

    A new nickel/zinc (Ni/Zn) battery was assembled by using polymer hydrogel electrolyte prepared from cross-linked potassium poly(acrylate) and KOH aqueous solution, and its charge-discharge characteristics were investigated. The experimental Ni/Zn cell with the polymer hydrogel electrolyte exhibited well-defined charge-discharge curves and remarkably improved charge-discharge cycle performance, compared to that with a KOH aqueous solution. Moreover, it was found that dendritic growth hardly occurred on the zinc electrode surface during charge-discharge cycles in the polymer hydrogel electrolyte. These results indicate that the polymer hydrogel electrolyte can successfully be used in Ni/Zn batteries as an electrolyte with excellent performance.

  16. A Symmetric Organic - Based Nonaqueous Redox Flow Battery and Its State of Charge Diagnostics by FTIR

    Energy Technology Data Exchange (ETDEWEB)

    Duan, Wentao; Vemuri, Venkata Rama Ses; Milshtein, Jarrod D.; Laramie, Sydney; Dmello, Rylan D.; Huang, Jinhua; Zhang, Lu; Hu, Dehong; Vijayakumar, M.; Wang, Wei; Liu, Jun; Darling, Robert E.; Thompson, Levi; Smith, Kyle C.; Moore, Jeffrey S.; Brushett, Fikile; Wei, Xiaoliang

    2016-03-10

    Redox flow batteries have shown outstanding promise for grid-scale energy storage to promote utilization of renewable energy and improve grid stability. Nonaqueous battery systems can potentially achieve high energy density because of their broad voltage window. In this paper, we report a new organic redox-active material for use in a nonaqueous redox flow battery, 2-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (PTIO) that has high solubility (>2.6 M) in organic solvents. PTIO exhibits electrochemically reversible disproportionation reactions and thus can serve as both anolyte and catholyte redox materials in a symmetric flow cell. The PTIO flow battery has a moderate cell voltage of ~1.7 V and shows good cyclability under both cyclic voltammetry and flow cell conditions. Moreover, we demonstrate that FTIR can offer accurate estimation of the PTIO concentration in electrolytes and determine the state of charge of the PTIO flow cell, which suggests FTIR potentially as a powerful online battery status sensor. This study is expected to inspire more insights in this under-addressed area of state of charge analysis aiming at operational safety and reliability of flow batteries.

  17. Photovoltaic battery & charge controller market & applications survey. An evaluation of the photovoltaic system market for 1995

    Energy Technology Data Exchange (ETDEWEB)

    Hammond, R.L.; Turpin, J.F.; Corey, G.P. [and others

    1996-12-01

    Under the sponsorship of the Department of Energy, Office of Utility Technologies, the Battery Analysis and Evaluation Department and the Photovoltaic System Assistance Center of Sandia National Laboratories (SNL) initiated a U.S. industry-wide PV Energy Storage System Survey. Arizona State University (ASU) was contracted by SNL in June 1995 to conduct the survey. The survey included three separate segments tailored to: (a) PV system integrators, (b) battery manufacturers, and (c) PV charge controller manufacturers. The overall purpose of the survey was to: (a) quantify the market for batteries shipped with (or for) PV systems in 1995, (b) quantify the PV market segments by battery type and application for PV batteries, (c) characterize and quantify the charge controllers used in PV systems, (d) characterize the operating environment for energy storage components in PV systems, and (e) estimate the PV battery market for the year 2000. All three segments of the survey were mailed in January 1996. This report discusses the purpose, methodology, results, and conclusions of the survey.

  18. State of Charge Estimation of Lithium-Ion Batteries Using an Adaptive Cubature Kalman Filter

    Directory of Open Access Journals (Sweden)

    Bizhong Xia

    2015-06-01

    Full Text Available Accurate state of charge (SOC estimation is of great significance for a lithium-ion battery to ensure its safe operation and to prevent it from over-charging or over-discharging. However, it is difficult to get an accurate value of SOC since it is an inner sate of a battery cell, which cannot be directly measured. This paper presents an Adaptive Cubature Kalman filter (ACKF-based SOC estimation algorithm for lithium-ion batteries in electric vehicles. Firstly, the lithium-ion battery is modeled using the second-order resistor-capacitor (RC equivalent circuit and parameters of the battery model are determined by the forgetting factor least-squares method. Then, the Adaptive Cubature Kalman filter for battery SOC estimation is introduced and the estimated process is presented. Finally, two typical driving cycles, including the Dynamic Stress Test (DST and New European Driving Cycle (NEDC are applied to evaluate the performance of the proposed method by comparing with the traditional extended Kalman filter (EKF and cubature Kalman filter (CKF algorithms. Experimental results show that the ACKF algorithm has better performance in terms of SOC estimation accuracy, convergence to different initial SOC errors and robustness against voltage measurement noise as compared with the traditional EKF and CKF algorithms.

  19. State of Charge Estimation Using the Extended Kalman Filter for Battery Management Systems Based on the ARX Battery Model

    Directory of Open Access Journals (Sweden)

    Hongjie Wu

    2013-01-01

    Full Text Available State of charge (SOC is a critical factor to guarantee that a battery system is operating in a safe and reliable manner. Many uncertainties and noises, such as fluctuating current, sensor measurement accuracy and bias, temperature effects, calibration errors or even sensor failure, etc. pose a challenge to the accurate estimation of SOC in real applications. This paper adds two contributions to the existing literature. First, the auto regressive exogenous (ARX model is proposed here to simulate the battery nonlinear dynamics. Due to its discrete form and ease of implemention, this straightforward approach could be more suitable for real applications. Second, its order selection principle and parameter identification method is illustrated in detail in this paper. The hybrid pulse power characterization (HPPC cycles are implemented on the 60AH LiFePO4 battery module for the model identification and validation. Based on the proposed ARX model, SOC estimation is pursued using the extended Kalman filter. Evaluation of the adaptability of the battery models and robustness of the SOC estimation algorithm are also verified. The results indicate that the SOC estimation method using the Kalman filter based on the ARX model shows great performance. It increases the model output voltage accuracy, thereby having the potential to be used in real applications, such as EVs and HEVs.

  20. Prediction Model of Battery State of Charge and Control Parameter Optimization for Electric Vehicle

    Directory of Open Access Journals (Sweden)

    Bambang Wahono

    2015-07-01

    Full Text Available This paper presents the construction of a battery state of charge (SOC prediction model and the optimization method of the said model to appropriately control the number of parameters in compliance with the SOC as the battery output objectives. Research Centre for Electrical Power and Mechatronics, Indonesian Institute of Sciences has tested its electric vehicle research prototype on the road, monitoring its voltage, current, temperature, time, vehicle velocity, motor speed, and SOC during the operation. Using this experimental data, the prediction model of battery SOC was built. Stepwise method considering multicollinearity was able to efficiently develops the battery prediction model that describes the multiple control parameters in relation to the characteristic values such as SOC. It was demonstrated that particle swarm optimization (PSO succesfully and efficiently calculated optimal control parameters to optimize evaluation item such as SOC based on the model.

  1. Comparative study of a small size wind generation system efficiency for battery charging

    Directory of Open Access Journals (Sweden)

    Mayouf Messaoud

    2013-01-01

    Full Text Available This paper presents an energetic comparison between two control strategies of a small size wind generation system for battery charging. The output voltage of the direct drive PMSG is connected to the battery through a switch mode rectifier. A DC-DC boost converter is used to regulate the battery bank current in order to achieve maximum power from the wind. A maximum powertracking algorithm calculates the current command that corresponds to maximum power output of the turbine. The DC-DC converter uses this current to calculate the duty cycle witch is necessary to control the pulse width modulated (PWM active switching device (IGPT. The system overview and modeling are presented including characteristics of wind turbine, generator, batteries, power converter, control system, and supervisory system. A simulation of the system is performed using MATLAB/SIMULINK.

  2. Molecular ion battery: a rechargeable system without using any elemental ions as a charge carrier

    Science.gov (United States)

    Yao, Masaru; Sano, Hikaru; Ando, Hisanori; Kiyobayashi, Tetsu

    2015-06-01

    Is it possible to exceed the lithium redox potential in electrochemical systems? It seems impossible to exceed the lithium potential because the redox potential of the elemental lithium is the lowest among all the elements, which contributes to the high voltage characteristics of the widely used lithium ion battery. However, it should be possible when we use a molecule-based ion which is not reduced even at the lithium potential in principle. Here we propose a new model system using a molecular electrolyte salt with polymer-based active materials in order to verify whether a molecular ion species serves as a charge carrier. Although the potential of the negative-electrode is not yet lower than that of lithium at present, this study reveals that a molecular ion can work as a charge carrier in a battery and the system is certainly a molecular ion-based “rocking chair” type battery.

  3. Battery State-of-Charge and Parameter Estimation Algorithm Based on Kalman Filter

    DEFF Research Database (Denmark)

    Dragicevic, Tomislav; Sucic, Stjepan; Guerrero, Josep M.

    2013-01-01

    such as the actual state of charge (SOC) and state of health (SOH). Therefore, a modern battery management systems (BMSs) should incorporate functions that accommodate real time tracking of these nonlinearities. For that purpose, Kalman filter based algorithms emerged as a convenient solution due to their ability...

  4. Battery system and method for sensing and balancing the charge state of battery cells

    Science.gov (United States)

    Davies, Francis J. (Inventor)

    2012-01-01

    A battery system utilizes a plurality of transformers interconnected with the battery cells. The transformers each have at least one transformer core operable for magnetization in at least a first magnetic state with a magnetic flux in a first direction and a second magnetic state with a magnetic flux in a second direction. The transformer cores retain the first magnetic state and the second magnetic state without current flow through said plurality of transformers. Circuitry is utilized for switching a selected transformer core between the first and second magnetic states to sense voltage and/or balance particular cells or particular banks of cells.

  5. Simulation of the current distribution in lead-acid batteries to investigate the dynamic charge acceptance in flooded SLI batteries

    Energy Technology Data Exchange (ETDEWEB)

    Kowal, Julia; Schulte, Dominik; Sauer, Dirk Uwe [Electrochemical Energy Conversion and Storage Systems Group, Institute for Power Electronics and Electrical Drives (ISEA), RWTH Aachen University, 52066 Aachen (Germany); Karden, Eckhard [Ford Research and Advanced Engineering Europe, Aachen (Germany)

    2009-06-01

    Measurements show that the dynamic charge acceptance (DCA) of flooded SLI lead-acid batteries during micro-cycling in conventional and micro-hybrid vehicles is strongly dependent on the short-term history, such as previous charge or discharge, current rate, lowest state of charge in the last 24 h and more. Factors of 10 have been reported. Inhomogeneous current distribution, especially as a result of acid stratification, has been suggested to explain the DCA variability. This hypothesis was investigated by simulation of a two-dimensional macrohomogeneous model. It provides a spatial resolution of three elements in horizontal direction in each electrode and three elements in vertical direction. For an existing set of parameters, different current profiles were analyzed with regard to the current distribution during charging and discharging. In these simulations, a strong impact of the short-term history on current, charge and acid density distribution was found as well as a strong influence of micro-cycles on both charge distribution and acid stratification. (author)

  6. Design Considerations for Wireless Charging Systems with an Analysis of Batteries

    Directory of Open Access Journals (Sweden)

    Zhenshi Wang

    2015-09-01

    Full Text Available Three criteria, including charging time, effective charging capacity and charging energy efficiency, are introduced to evaluate the CC (constant current and CC/CV (constant current/constant voltage charging strategies. Because the CC strategy presents a better performance and most resonant topologies have the CC characteristic, the CC strategy is more suitable for the design of wireless charging systems than the CC/CV strategy. Then, the state space model of the receiver is built to study the system dynamic characteristics, and the design of nonuse output filter capacitors is proposed, which can improve the system power density and avoid the drop in efficiency caused by capacitor degradation. At last, an electrochemical impedance spectrum (EIS based analysis method is introduced to validate that the design without output filter capacitors has no effects on the battery characteristics when the charging frequency is higher than 460 Hz. A prototype is fabricated to verify our research results.

  7. Ionic liquid based lithium battery electrolytes: charge carriers and interactions derived by density functional theory calculations.

    Science.gov (United States)

    Angenendt, Knut; Johansson, Patrik

    2011-06-23

    The solvation of lithium salts in ionic liquids (ILs) leads to the creation of a lithium ion carrying species quite different from those found in traditional nonaqueous lithium battery electrolytes. The most striking differences are that these species are composed only of ions and in general negatively charged. In many IL-based electrolytes, the dominant species are triplets, and the charge, stability, and size of the triplets have a large impact on the total ion conductivity, the lithium ion mobility, and also the lithium ion delivery at the electrode. As an inherent advantage, the triplets can be altered by selecting lithium salts and ionic liquids with different anions. Thus, within certain limits, the lithium ion carrying species can even be tailored toward distinct important properties for battery application. Here, we show by DFT calculations that the resulting charge carrying species from combinations of ionic liquids and lithium salts and also some resulting electrolyte properties can be predicted. PMID:21591707

  8. Plug-in hybrid electric vehicle charge pattern optimization for energy cost and battery longevity

    Science.gov (United States)

    Bashash, Saeid; Moura, Scott J.; Forman, Joel C.; Fathy, Hosam K.

    This paper examines the problem of optimizing the charge pattern of a plug-in hybrid electric vehicle (PHEV), defined as the timing and rate with which the PHEV obtains electricity from the power grid. The optimization goal is to simultaneously minimize (i) the total cost of fuel and electricity and (ii) the total battery health degradation over a 24-h naturalistic drive cycle. The first objective is calculated for a previously-developed stochastic optimal PHEV power management strategy, whereas the second objective is evaluated through an electrochemistry-based model of anode-side resistive film formation in lithium-ion batteries. The paper shows that these two objectives are conflicting, and trades them off using a non-dominated sorting genetic algorithm. As a result, a Pareto front of optimal charge patterns is obtained. The effects of electricity price and trip schedule on the optimal Pareto points and the PHEV charge patterns are analyzed and discussed.

  9. ESTIMATION METHOD ON THE BATTERY STATE OF CHARGE FOR HYBRID ELECTRIC VEHICLE

    Institute of Scientific and Technical Information of China (English)

    QIANG Jiaxi; AO Guoqiang; YANG Lin

    2008-01-01

    A combined algorithm for battery state of charge (SOC) estimation is proposed to solve the critical issue of hybrid electric vehicle (HEV). To obtain a more accurate SOC, both coulomb-accumulation and battery resistance-capacitor (RC) model are weighted combined to compensate the deficiencies of individual methods. In order to solve the key issue of coulomb-accumulation, the battery thermal model is used. Based on the principle of energy conservation, the heat generated from battery charge and discharge process is converted into the equivalent electricity to calculate charge and discharge efficiency under variable current. The extended Kalman filter (EKF) as a closed loop algorithm is applied to estimate the parameters of resistance-capacitor model. The input variables do not increase much computing difficulty. The proposed combined algorithm is implemented by adjusting the weighting factor of coulomb- accumulation and resistance-capacitor model. In the end, four different methods including Ah-efficiency, Ah-Equip, RC-SOC and Combined-SOC are compared in federal testing procedure (FTP) drive cycle. The experiment results show that the proposed method has good robustness and high accuracy which is suitable for HEV application.

  10. Adaptive unscented Kalman filtering for state of charge estimation of a lithium-ion battery for electric vehicles

    International Nuclear Information System (INIS)

    An accurate battery State of Charge estimation is of great significance for battery electric vehicles and hybrid electric vehicles. This paper presents an adaptive unscented Kalman filtering method to estimate State of Charge of a lithium-ion battery for battery electric vehicles. The adaptive adjustment of the noise covariances in the State of Charge estimation process is implemented by an idea of covariance matching in the unscented Kalman filter context. Experimental results indicate that the adaptive unscented Kalman filter-based algorithm has a good performance in estimating the battery State of Charge. A comparison with the adaptive extended Kalman filter, extended Kalman filter, and unscented Kalman filter-based algorithms shows that the proposed State of Charge estimation method has a better accuracy. -- Highlights: → Adaptive unscented Kalman filtering is proposed to estimate State of Charge of a lithium-ion battery for electric vehicles. → The proposed method has a good performance in estimating the battery State of Charge. → A comparison with three other Kalman filtering algorithms shows that the proposed method has a better accuracy.

  11. State of charge modeling of lithium-ion batteries using dual exponential functions

    Science.gov (United States)

    Kuo, Ting-Jung; Lee, Kung-Yen; Huang, Chien-Kang; Chen, Jau-Horng; Chiu, Wei-Li; Huang, Chih-Fang; Wu, Shuen-De

    2016-05-01

    A mathematical model is developed by fitting the discharging curve of LiFePO4 batteries and used to investigate the relationship between the state of charge and the closed-circuit voltage. The proposed mathematical model consists of dual exponential terms and a constant term which can fit the characteristics of dual equivalent RC circuits closely, representing a LiFePO4 battery. One exponential term presents the stable discharging behavior and the other one presents the unstable discharging behavior and the constant term presents the cut-off voltage.

  12. Fast Charging Battery Buses for the Electrification of Urban Public Transport—A Feasibility Study Focusing on Charging Infrastructure and Energy Storage Requirements

    Directory of Open Access Journals (Sweden)

    Matthias Rogge

    2015-05-01

    Full Text Available The electrification of public transport bus networks can be carried out utilizing different technological solutions, like trolley, battery or fuel cell buses. The purpose of this paper is to analyze how and to what extent existing bus networks can be electrified with fast charging battery buses. The so called opportunity chargers use mainly the regular dwell time at the stops to charge their batteries. This results in a strong linkage between the vehicle scheduling and the infrastructure planning. The analysis is based on real-world data of the bus network in Muenster, a mid-sized city in Germany. The outcomes underline the necessity to focus on entire vehicle schedules instead on individual trips. The tradeoff between required battery capacity and charging power is explained in detail. Furthermore, the impact on the electricity grid is discussed based on the load profiles of a selected charging station and a combined load profile of the entire network.

  13. Effect of extreme temperatures on battery charging and performance of electric vehicles

    Science.gov (United States)

    Lindgren, Juuso; Lund, Peter D.

    2016-10-01

    Extreme temperatures pose several limitations to electric vehicle (EV) performance and charging. To investigate these effects, we combine a hybrid artificial neural network-empirical Li-ion battery model with a lumped capacitance EV thermal model to study how temperature will affect the performance of an EV fleet. We find that at -10 °C, the self-weighted mean battery charging power (SWMCP) decreases by 15% compared to standard 20 °C temperature. Active battery thermal management (BTM) during parking can improve SWMCP for individual vehicles, especially if vehicles are charged both at home and at workplace; the median SWMCP is increased by over 30%. Efficiency (km/kWh) of the vehicle fleet is maximized when ambient temperature is close to 20 °C. At low (-10 °C) and high (+40 °C) ambient temperatures, cabin preconditioning and BTM during parking can improve the median efficiency by 8% and 9%, respectively. At -10 °C, preconditioning and BTM during parking can also improve the fleet SOC by 3-6%-units, but this also introduces a "base" load of around 140 W per vehicle. Finally, we observe that the utility of the fleet can be increased by 5%-units by adding 3.6 kW chargers to workplaces, but further improved charging infrastructure would bring little additional benefit.

  14. System and Battery Charge Control for PV-Powered AC Lighting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Kern, G.

    1999-04-01

    This report reviews a number of issues specific to stand-alone AC lighting systems. A review of AC lighting technology is presented, which discusses the advantages and disadvantages of various lamps. The best lamps for small lighting systems are compact fluorescent. The best lamps for intermediate-size systems are high- or low-pressure sodium. Specifications for battery charging and load control are provided with the goal of achieving lamp lifetimes on the order of 16,000 to 24,000 hours and battery lifetimes of 4 to 5 years. A rough estimate of the potential domestic and global markets for stand-alone AC lighting systems is presented. DC current injection tests were performed on high-pressure sodium lamps and the test results are presented. Finally, a prototype system was designed and a prototype system controller (with battery charger and DC/AC inverter) was developed and built.

  15. Electrochemical-acoustic time of flight: in operando correlation of physical dynamics with battery charge and health

    Energy Technology Data Exchange (ETDEWEB)

    Hsieh, AG; Bhadra, S; Hertzberg, BJ; Gjeltema, PJ; Goy, A; Fleischer, JW; Steingart, DA

    2015-01-01

    We demonstrate that a simple acoustic time-of-flight experiment can measure the state of charge and state of health of almost any closed battery. An acoustic conservation law model describing the state of charge of a standard battery is proposed, and experimental acoustic results verify the simulated trends; furthermore, a framework relating changes in sound speed, via density and modulus changes, to state of charge and state of health within a battery is discussed. Regardless of the chemistry, the distribution of density within a battery must change as a function of state of charge and, along with density, the bulk moduli of the anode and cathode changes as well. The shifts in density and modulus also change the acoustic attenuation in a battery. Experimental results indicating both state-of-charge determination and irreversible physical changes are presented for two of the most ubiquitous batteries in the world, the lithium-ion 18650 and the alkaline LR6 (AA). Overall, a one-or two-point acoustic measurement can be related to the interaction of a pressure wave at multiple discrete interfaces within a battery, which in turn provides insights into state of charge, state of health, and mechanical evolution/degradation.

  16. System dynamic model and charging control of lead-acid battery for stand-alone solar PV system

    KAUST Repository

    Huang, B.J.

    2010-05-01

    The lead-acid battery which is widely used in stand-alone solar system is easily damaged by a poor charging control which causes overcharging. The battery charging control is thus usually designed to stop charging after the overcharge point. This will reduce the storage energy capacity and reduce the service time in electricity supply. The design of charging control system however requires a good understanding of the system dynamic behaviour of the battery first. In the present study, a first-order system dynamics model of lead-acid battery at different operating points near the overcharge voltage was derived experimentally, from which a charging control system based on PI algorithm was developed using PWM charging technique. The feedback control system for battery charging after the overcharge point (14 V) was designed to compromise between the set-point response and the disturbance rejection. The experimental results show that the control system can suppress the battery voltage overshoot within 0.1 V when the solar irradiation is suddenly changed from 337 to 843 W/m2. A long-term outdoor test for a solar LED lighting system shows that the battery voltage never exceeded 14.1 V for the set point 14 V and the control system can prevent the battery from overcharging. The test result also indicates that the control system is able to increase the charged energy by 78%, as compared to the case that the charging stops after the overcharge point (14 V). © 2010 Elsevier Ltd. All rights reserved.

  17. Lithium-ion batteries: Evaluation study of different charging methodologies based on aging process

    International Nuclear Information System (INIS)

    Highlights: • Different charging methodologies have been tested and analyzed. • Battery impedance representation using the Randle’s equivalent circuit. • Investigate the impact of the charging methodology on the battery’s lifetime. • An extended analysis to select the proper charging method that can be used to design an enhanced charging system. - Abstract: In this paper, high power 7 A h LiFePO4-based cells (LFP) have been used to investigate the impact of the charging methodology on the battery’s lifetime. Three charging techniques have been used: Constant Current (CC), Constant Current–Constant Voltage (CC–CV) and Constant Current–Constant Voltage with Negative Pulse (CC–CVNP). A comparative study between these techniques is presented in this research. For this purpose, a characterization of the batteries has been performed using capacity test and electrochemical impedance spectroscopy (EIS). As expected the obtained results showed that the battery’s aging rate depends on the charging methodology. Indeed, it has been shown that a combination of low amplitude and fewest number of negative pulses has a positive effect on battery’s capacity fading. From the impedance measurements, the results have demonstrated that the CC–CVNP technique with low amplitude and fewest number of negative pulses is more effective than the other techniques in reducing the concentration polarization resistance and the diffusion time constant. This research has provided an extended analysis to select the proper charging methodology that can be used to design an enhanced charging system

  18. Evaluation of Model Based State of Charge Estimation Methods for Lithium-Ion Batteries

    Directory of Open Access Journals (Sweden)

    Zhongyue Zou

    2014-08-01

    Full Text Available Four model-based State of Charge (SOC estimation methods for lithium-ion (Li-ion batteries are studied and evaluated in this paper. Different from existing literatures, this work evaluates different aspects of the SOC estimation, such as the estimation error distribution, the estimation rise time, the estimation time consumption, etc. The equivalent model of the battery is introduced and the state function of the model is deduced. The four model-based SOC estimation methods are analyzed first. Simulations and experiments are then established to evaluate the four methods. The urban dynamometer driving schedule (UDDS current profiles are applied to simulate the drive situations of an electrified vehicle, and a genetic algorithm is utilized to identify the model parameters to find the optimal parameters of the model of the Li-ion battery. The simulations with and without disturbance are carried out and the results are analyzed. A battery test workbench is established and a Li-ion battery is applied to test the hardware in a loop experiment. Experimental results are plotted and analyzed according to the four aspects to evaluate the four model-based SOC estimation methods.

  19. Inline state of health estimation of lithium-ion batteries using state of charge calculation

    Science.gov (United States)

    Sepasi, Saeed; Ghorbani, Reza; Liaw, Bor Yann

    2015-12-01

    The determination of state-of-health (SOH) and state-of-charge (SOC) is challenging and remains as an active research area in academia and industry due to its importance for Li-ion battery applications. The estimation process poses more challenges after substantial battery aging. This paper presents an inline SOH and SOC estimation method for Li-ion battery packs, specifically for those based on LiFePO4 chemistry. This new hybridized SOC and SOH estimator can be used for battery packs. Inline estimated model parameters were used in a compounded SOC + SOH estimator consisting of the SOC calculation based on coulomb counting method as an expedient approach and an SOH observer using an extended Kalman filter (EKF) technique for calibrating the estimates from the coulomb counting method. The algorithm's low SOC and SOH estimation error, fast response time, and less-demanding computational requirement make it practical for on-board estimations. The simulation and experimental results, along with the test bed structure, are presented to validate the proposed methodology on a single cell and a 3S1P LiFePO4 battery pack.

  20. Small wind generators for battery charging in Peru and Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Dunnett, S. [Intermediate Technology Development Group, Rugby (United Kingdom)

    2000-07-01

    The Intermediate Technology Development Group (ITDG) have developed a small wind generator (SWG) intended primarily for battery charging in Peru and Sri Lanka. The project is funded mainly by the Department for International Development (DfID) and aims to provide rural households and communities who do not have access to mains electricity with a form of electrification. This paper reports on progress to date and is correct at the time of going to press, but subsequent changes to specifications may occur. (Author)

  1. Device and Method for Continuously Equalizing the Charge State of Lithium Ion Battery Cells

    Science.gov (United States)

    Schwartz, Paul D. (Inventor); Martin, Mark N. (Inventor); Roufberg, Lewis M. (Inventor)

    2015-01-01

    A method of equalizing charge states of individual cells in a battery includes measuring a previous cell voltage for each cell, measuring a previous shunt current for each cell, calculating, based on the previous cell voltage and the previous shunt current, an adjusted cell voltage for each cell, determining a lowest adjusted cell voltage from among the calculated adjusted cell voltages, and calculating a new shunt current for each cell.

  2. Vehicle trajectory optimization for hybrid vehicles taking into account battery state-of-charge

    OpenAIRE

    MENSING, Felicitas; TRIGUI, Rochdi; Bideaux, Eric

    2012-01-01

    Hybrid vehicles are found to be one solution to reduce fuel consumption in the transportation sector. Eco-driving is a concept that is immediately applicable by drivers to improve the efficiency of their vehicle. In this work the potential of eco-driving for hybrid drive train vehicles is discussed. The operation of hybrid vehicles is strongly dependent on their energy management and therefore on battery state-of-charge. Here, the velocity trajectory will be optimized taking into account b...

  3. Optimal charging method for lithium ion batteries using a universal voltage protocol accommodating aging

    Science.gov (United States)

    Guo, Zhen; Liaw, Bor Yann; Qiu, Xinping; Gao, Lanlan; Zhang, Changshui

    2015-01-01

    An effective optimum charging technique for lithium ion batteries using a universal voltage protocol (UVP) that can accommodate cell aging is presented here. This charging method demands less learning to varying state-of-health (SOH) conditions with potential to improve charging efficiency and cycle life. The simplicity of UVP makes the implementation easier than the conventional constant current-constant voltage (CC-CV)-based methods. Here, the mathematical formulation, optimization targets (e.g. minimal time) and constraints (terminal voltages and other instrumental and cell electrochemistry-limited ones) are explained from the protocol design considerations. An equivalent circuit model was used and its parameters derived from the analysis of test data, which could yield a nonlinear varying current profile (VCP) by simulation and a genetic algorithm-based optimization. Both UVP and VCP were used in the validation to illustrate better charging efficiency and capacity retention, which showed a much improved cycle life.

  4. Reducing capacity fade in vanadium redox flow batteries by altering charging and discharging currents

    Science.gov (United States)

    Agar, Ertan; Benjamin, A.; Dennison, C. R.; Chen, D.; Hickner, M. A.; Kumbur, E. C.

    2014-01-01

    In this study, the operation of a vanadium redox flow battery (VRFB) under asymmetric current conditions (i.e., different current densities during charge and discharge) was investigated as a technique to reduce its capacity loss. Two different membrane types (a convection-dominated membrane and a diffusion-dominated membrane) were analyzed. In these analyses, the charging current density was varied while the discharging current was held constant. For both membranes, it was found that increasing the charging current decreases the net convective crossover of vanadium ions, which reduces the capacity loss of the battery. When the tested membranes were compared, the improvement in capacity retention was found to be larger for the diffusion-dominated membrane (12.4%) as compared to the convection-dominated membrane (7.1%). The higher capacity retention in the diffusion-dominated membrane was attributed to the reduction in the cycling time (and hence, suppressed contribution of diffusion) due to the increased charging current. While asymmetric current operation helps reduce capacity loss, it comes at the expense of a reduction in the voltage efficiencies. Increasing the charging current was found to increase the ohmic losses, which lead to a decrease of 6% and 4.3% in the voltage efficiencies of the convection-dominated and diffusion-dominated membranes, respectively.

  5. Numerical analyses on optimizing a heat pipe thermal management system for lithium-ion batteries during fast charging

    International Nuclear Information System (INIS)

    Thermal management is crucial for the operation of electric vehicles because lithium ion batteries are vulnerable to excessive heat generation during fast charging or other severe scenarios. In this work, an optimized heat pipe thermal management system (HPTMS) is proposed for fast charging lithium ion battery cell/pack. A numerical model is developed and comprehensively validated with experimental results. This model is then employed to investigate the thermal performance of the HPTMS under steady state and transient conditions. It is found that a cylinder vortex generator placed in front of the heat pipe condensers in the coolant stream improves the temperature uniformity. The uses of cooper heat spreaders and cooling fins greatly improve the performance of the thermal management system. Experiments and transient simulations of heat pipe thermal management system integrated with batteries prove that the improved HPTMS is capable for thermal management of batteries during fast charging. The air-cooled HPTMS is infeasible for thermal management of batteries during fast charging at the pack level due to the limitation of low specific heat capacity. - Highlights: • We develop a numerical model for optimizing a heat pipe thermal management system for fast charging batteries. • The numerical model is comprehensively validated with experimental data. • A cylinder vortex generator is placed at the inlet of the cooling stream to improve the temperature uniformity. • We validate the effectiveness of the optimized system with integration of prismatic batteries

  6. Structural and Electrochemical Investigation during the First Charging Cycles of Silicon Microwire Array Anodes for High Capacity Lithium Ion Batteries

    OpenAIRE

    Helmut Föll; Jürgen Carstensen; Enrique Quiroga-González

    2013-01-01

    Silicon microwire arrays embedded in Cu present exceptional performance as anode material in Li ion batteries. The processes occurring during the first charging cycles of batteries with this anode are essential for good performance. This paper sheds light on the electrochemical and structural properties of the anodes during the first charging cycles. Scanning Electron Microscopy, X-ray diffractommetry, and fast Fourier transformation impedance spectroscopy are used for the characterization. I...

  7. Estimation of State of Charge of a Lithium-Ion Battery Pack for Electric Vehicles Using an Adaptive Luenberger Observer

    OpenAIRE

    Yuan Zou; Fengchun Sun; Xiaosong Hu

    2010-01-01

    In order to safely and efficiently use the power as well as to extend the lifetime of the traction battery pack, accurate estimation of State of Charge (SoC) is very important and necessary. This paper presents an adaptive observer-based technique for estimating SoC of a lithium-ion battery pack used in an electric vehicle (EV). The RC equivalent circuit model in ADVISOR is applied to simulate the lithium-ion battery pack. The parameters of the battery model as a function of SoC, are identifi...

  8. Model for charge/discharge-rate-dependent plastic flow in amorphous battery materials

    Science.gov (United States)

    Khosrownejad, S. M.; Curtin, W. A.

    2016-09-01

    Plastic flow is an important mechanism for relaxing stresses that develop due to swelling/shrinkage during charging/discharging of battery materials. Amorphous high-storage-capacity Li-Si has lower flow stresses than crystalline materials but there is evidence that the plastic flow stress depends on the conditions of charging and discharging, indicating important non-equilibrium aspects to the flow behavior. Here, a mechanistically-based constitutive model for rate-dependent plastic flow in amorphous materials, such as LixSi alloys, during charging and discharging is developed based on two physical concepts: (i) excess energy is stored in the material during electrochemical charging and discharging due to the inability of the amorphous material to fully relax during the charging/discharging process and (ii) this excess energy reduces the barriers for plastic flow processes and thus reduces the applied stresses necessary to cause plastic flow. The plastic flow stress is thus a competition between the time scales of charging/discharging and the time scales of glassy relaxation. The two concepts, as well as other aspects of the model, are validated using molecular simulations on a model Li-Si system. The model is applied to examine the plastic flow behavior of typical specimen geometries due to combined charging/discharging and stress history, and the results generally rationalize experimental observations.

  9. State of Charge Estimation Based on Microscopic Driving Parameters for Electric Vehicle's Battery

    Directory of Open Access Journals (Sweden)

    Enjian Yao

    2013-01-01

    Full Text Available Recently, battery-powered electric vehicle (EV has received wide attention due to less pollution during use, low noise, and high energy efficiency and is highly expected to improve urban air quality and then mitigate energy and environmental pressure. However, the widespread use of EV is still hindered by limited battery capacity and relatively short cruising range. This paper aims to propose a state of charge (SOC estimation method for EV’s battery necessary for route planning and dynamic route guidance, which can help EV drivers to search for the optimal energy-efficient routes and to reduce the risk of running out of electricity before arriving at the destination or charging station. Firstly, by analyzing the variation characteristics of power consumption rate with initial SOC and microscopic driving parameters (instantaneous speed and acceleration, a set of energy consumption rate models are established according to different operation modes. Then, the SOC estimation model is proposed based on the presented EV power consumption model. Finally, by comparing the estimated SOC with the measured SOC, the proposed SOC estimation method is proved to be highly accurate and effective, which can be well used in EV route planning and navigation systems.

  10. Fuzzy modelling for the state-of-charge estimation of lead-acid batteries

    Science.gov (United States)

    Burgos, Claudio; Sáez, Doris; Orchard, Marcos E.; Cárdenas, Roberto

    2015-01-01

    This paper introduces a novel fuzzy model based structure for the characterisation of discharge processes in lead-acid batteries. This structure is based on a fuzzy model that characterises the relationship between the battery open-circuit voltage (Voc), the state of charge (SoC), and the discharge current. The model is identified and validated using experimental data that is obtained from an experimental system designed to test battery banks with several charge/discharge profiles. For model identification purposes, two standard experimental tests are implemented; one of these tests is used to identify the Voc-SoC curve, while the other helps to identify additional parameters of the model. The estimation of SoC is performed using an Extended Kalman Filter (EKF) with a state transition equation that is based on the proposed fuzzy model. Performance of the proposed estimation framework is compared with other parametric approaches that are inspired on electrical equivalents; e.g., Thevenin, Plett, and Copetti.

  11. Charging operation with high energy efficiency for electric vehicle valve-regulated lead-acid battery system

    Energy Technology Data Exchange (ETDEWEB)

    Ikeya, Tomohiko; Mita, Yuichi; Ishihara, Kaoru [Central Research Inst. of Electric Power Industry (CRIEPI), Komae Res. Lab., Lithium Battery Project, Tokyo (Japan); Sawada, Nobuyuki [Hokkaido Electric Power Co., Sapporo (Japan); Takagi, Sakae; Murakami, Jun-ichi [Tohoku Electric Power Co. Inc., Sendai (Japan); Kobayashi, Kazuyuki [Tokyo Electric Power Co., Yokohama (Japan); Sakabe, Tetsuya [Chubu Electric Power Co., Nagoya (Japan); Kousaka, Eiichi [Hokuriku Electric Power Co., Toyama (Japan); Yoshioka, Haruki [The Kansai Electric Power Co., Osaka (Japan); Kato, Satoru [The Chugoku Electric Power Co., Hiroshima (Japan); Yamashita, Masanori [Shikoku Research Inst. Inc., Takamatsu (Japan); Narisoko, Hayato [The Okinawa Electric Power Co., Naha (Japan); Nishiyama, Kazuo [The Central Electric Power Council, Tokyo (Japan); Adachi, Kazuyuki [Kyushu Electric Power Co., Fukuoka (Japan)

    2000-12-01

    A new, high-energy-efficiency charging operation with as little amount of overcharge as possible is proposed to improve the energy efficiency and the cycle life for an EV valve-regulated lead-acid battery. Under this operation, the EV battery system is charged with 105% of amount of the preceding discharge five out of six times and once with 115% in order that it is fully charged. The cycle lives were estimated using a valve-regulated lead-acid battery system of 12 modules connected in series, by SFUDS79 pattern discharging and measurement of the amount of discharge every 50 cycles. Three-step constant current charging with 115% of amount of the preceding discharge required more than 5 h with the final charging step of more than 210 min, with coulomb efficiency of only 87% and energy efficiency of 74%. On the other hand, under the high-energy-efficiency charging operation, three-step charging with 105% shortens the final charging time to 132 min. It was completed in less than 4 h with coulomb and energy efficiency of 95% and 84%, respectively. This operation increased the energy efficiency from 74% to 83% on average in six charging, and extended the cycle life by about 30% to more than 400 cycles. Decreasing the amount of charge by as much as possible suppressed the corrosion of the grids in the positive plate and the heat evolution in batteries due to shortening of the final charging step. Although the high-energy-efficiency charging operation led to the accumulation of inactive PbSO{sub 4} at the upper part of the negative plate, possibly due to the decreasing amount of overcharge, this operation could prolong the cycle life. Full charging once every six times is though to be effective in suppressing degradation caused by the accumulation of inactive PbSO{sub 4} in the negative plate due to the shortage of charge. (orig.)

  12. State-Of-Charge Estimation of Li-Ion Battery Using Extended Kalman Filter

    Directory of Open Access Journals (Sweden)

    Feng Jin

    2013-07-01

    Full Text Available The Li-ion battery is studied base on its equivalent circuit PNGV model. The model parameters are identified by HPPC test. The discrete state space equation is established according to the model. The basic theory of extended Kalman filter algorithm is studied and then the filtering algorithm is set up under the noisy environments. Finally, a kind of electric car is used for testing under the UDDS driving condition. The difference between the simulation value using extended Kalman filter under the noisy environment and the theoretical value is compared. The result indicated that the extended Kalman filter keeps an excellent precision in state of charge estimation of Li-ion battery and performs well when disturbance happens.

  13. An adaptive Kalman filtering based State of Charge combined estimator for electric vehicle battery pack

    International Nuclear Information System (INIS)

    Ah counting is not a satisfactory method for the estimation of the State of Charge (SOC) of a battery, as the initial SOC and coulombic efficiency are difficult to measure. To address this issue, a new SOC estimation method, denoted as 'AEKFAh', is proposed. This method uses the adaptive Kalman filtering method which can avoid filtering divergence resulting from uncertainty to correct for the initial value used in the Ah counting method. A Ni/MH battery test procedure, consisting of 8.08 continuous Federal Urban Driving Schedule (FUDS) cycles, is carried out to verify the method. The SOC estimation error is 2.4% when compared with the real SOC obtained from a discharge test. This compares favorably with an estimation error of 11.4% when using Ah counting.

  14. On the aggregate grid load imposed by battery health-conscious charging of plug-in hybrid electric vehicles

    Science.gov (United States)

    Bashash, Saeid; Moura, Scott J.; Fathy, Hosam K.

    2011-10-01

    This article examines the problem of estimating the aggregate load imposed on the power grid by the battery health-conscious charging of plug-in hybrid electric vehicles (PHEVs). The article begins by generating a set of representative daily trips using (i) the National Household Travel Survey (NHTS) and (ii) a Markov chain model of both federal and naturalistic drive cycles. A multi-objective optimizer then uses each of these trips, together with PHEV powertrain and battery degradation models, to optimize both PHEV daily energy cost and battery degradation. The optimizer achieves this by varying (i) the amounts of charge obtained from the grid by each PHEV, and (ii) the timing of this charging. The article finally computes aggregate PHEV power demand by accumulating the charge patterns optimized for individual PHEV trips. The results of this aggregation process show a peak PHEV load in the early morning (between 5.00 and 6.00 a.m.), with approximately half of all PHEVs charging simultaneously. The ability to charge at work introduces smaller additional peaks in the aggregate load pattern. The article concludes by exploring the sensitivity of these results to the relative weighting of the two optimization objectives (energy cost and battery health), battery size, and electricity price.

  15. Technical and legal considerations and solutions in the area of battery charging for electric vehicles

    Science.gov (United States)

    Juda, Z.

    2016-09-01

    The issue of protecting health of residents of urbanized areas from the effect of excessive particulate matter and toxic components of car exhaust gases imposes the need of introduction of clean electric vehicles to the market. The increasing market availability of electric vehicles, especially in the segment of short-range (neighborhood) vehicles is followed by development of new and advanced infrastructure solutions. This also applies to the increasingly popular hybrid vehicles PHEV (Plug-in Hybrid Electric Vehicles). However, problems with the existing designs are primarily associated with limited driving range on a single battery charge, the density of charging stations in urban and suburban area, energy system efficiency due to increased electricity demand and the unification of solutions for charging stations, on-board chargers and the necessary accessories. Technical solutions are dependent on many factors, including the type and size of battery in the vehicle and access to power grid with increased load capacity. The article discusses the legal and technical actions outlined in the above directions. It shows the available and planned solutions in this area.

  16. Study on battery state of charge correct algorithm of electric vehicle

    Institute of Scientific and Technical Information of China (English)

    KAN Ping; QIAN Lijun

    2012-01-01

    State of Charge (SOC) is used to adjust the initialization SOC value so as to make electric vehicle simulation results close to real vehicle performance. This paper firstly analyses the battery SOC correct algorithm, then uses ADVISOR which is a electric vehicle simulation software to simulate a hybrid electric car with three different cases of no SOC correct, linear SOC correct and zero delta SOC correct, as well as makes the compare and analysis for those simulation results. In the end, an overall conclusion to SOC correct algorithm is given.

  17. Polymer–Graphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Song, Zhiping; Xu, Terrence (Tianren); Gordin, Mikhail; Jiang, Yingbing; Bae, In-Tae; Xiao, Qiangfeng; Zhan, Hui; Liu, Jun; Wang, Donghai

    2012-05-09

    Electroactive polymers are a new generation of 'green' cathode materials for rechargeable lithium batteries. We have developed nanocomposites combining graphene with two promising polymer cathode materials, poly(anthraquinonyl sulfide) and polyimide, to improve their high-rate performance. The polymer-graphene nanocomposites were synthesized through a simple in-situ polymerization in the presence of graphene sheets. The highly dispersed graphene sheets in the nanocomposite drastically enhanced the electronic conductivity and allowed the electrochemical activity of the polymer cathode to be efficiently utilized. This allows for ultrafast charging and discharging - the composite can deliver more than 100 mAh/g within just a few seconds.

  18. Approximation to the Modelling of Charge and Discharge Processes in Electrochemical Batteries by Integral Equations

    International Nuclear Information System (INIS)

    A new way for the modelling of the charge and discharge processes in electrochemical batteries based on the use of integral equations is presented. The proposed method models the charge curves by the so called fractional or cumulative integrals of a certain objective function f(t) that must be sought. The charge figures can be easily fitted by breaking down this objective function as the addition of two different Lorentz type functions: the first one is associated to the own charge process and the second one to the overcharge process. The method allows calculating the starting voltage for overcharge as the intersection between both functions. The curve fitting of this model to different experimental charge curves, by using the Marquart algorithm, has shown very accurate results. In the case of discharge curves, two possible methods for modelling purposes are suggested, well by using the same kind of integral equations, well by the simple subtraction of an objective function f(t) from a constant value VOD. Many other aspects for the study and analysis of this method in order to improve its results in further developments are also discussed. (Author) 10 refs

  19. Influence of state of charge in lead-acid batteries operating in PV systems; Comportamiento no repetitivo de las baterias de plomo-acido operando en sistemas FV.

    Energy Technology Data Exchange (ETDEWEB)

    Vela, N.; Chenlo, F.

    2004-07-01

    Correct determination of the overcharge cut-off voltage is a key point for both the optimal operation and maximum life-time of batteries in photovoltaic (PV) systems. This work presents the results of analysing the influence on charge voltage of different operation conditions, mainly current rate, temperature and state of charge (SOC). From the results obtained we have observed that voltage evolution during a charge process depends on its activation degree of the battery. The battery activation is reached when battery was previously fully charged. So, we can conclude that variation of the charge voltage with time as function of starting point (fully charged or fully discharged) together with current rate and temperature should be taking into account in the battery SOC determination and in the design of charge controllers. (Author)

  20. Fast Charge Battery Electric Transit Bus In-Use Fleet Evaluation: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Prohaska, Robert; Eudy, Leslie; Kelly, Kenneth

    2016-05-06

    The focus of this interim fleet evaluation is to characterize and evaluate the operating behavior of Foothill Transit's fast charge battery electric buses (BEBs). Future research will compare the BEBs' performance to conventional vehicles. In an effort to better understand the impacts of drive cycle characteristics on advanced vehicle technologies, researchers at the National Renewable Energy Laboratory analyzed over 148,000 km of in-use operational data, including driving and charging events. This analysis provides an unbiased evaluation of advanced vehicle technologies in real-world operation demonstrating the importance of understanding the effects of road grade and heating, ventilating and air conditioning requirements when deploying electric vehicles. The results of this analysis show that the Proterra BE35 demonstrated an operating energy efficiency of 1.34 kWh/km over the data reporting period.

  1. A Wearable Wireless Energy Link for Thin-Film Batteries Charging

    Directory of Open Access Journals (Sweden)

    Giuseppina Monti

    2016-01-01

    Full Text Available A wireless charger for low capacity thin-film batteries is presented. The proposed device consists of a nonradiative wireless resonant energy link and a power management unit. Experimental data referring to a prototype operating in the ISM band centered at 434 MHz are presented and discussed. In more detail, in order to facilitate the integration into wearable accessories (such as handbags or suitcases, the prototype of the wireless energy link was implemented by exploiting a magnetic coupling between two planar resonators fabricated by using a conductive fabric on a layer of leather. From experimental data, it is demonstrated that, at 434 MHz, the RF-to-RF power transfer efficiency of the link is approximately 69.3%. As for the performance of the system as a whole, when an RF power of 7.5 dBm is provided at the input port, a total efficiency of about 29.7% is obtained. Finally, experiments performed for calculating the charging time for a low capacity thin-film battery demonstrated that, for RF input power higher than 6 dBm, the time necessary for recharging the battery is lower than 50 minutes.

  2. Multi-functional Converter with Integrated Motor Control, Battery Charging and Active Module Balancing for Electric Vehicular Application

    DEFF Research Database (Denmark)

    Mathe, Laszlo; Schaltz, Erik; Teodorescu, Remus;

    2014-01-01

    In order to reduce the fuel consumption and the acoustical noise generated by refuse lorries, electrification of the waste compactor unit is a very promising solution. For the electrical energy storage Lithium-Sulfur (Li-S) battery technology has been selected with potential for reducing the cost...... used successfully in HVDC/FACTS and large drive applications. In this paper the use of MMC for a battery driven waste compactor unit addressed with integrated functionality including: motor driver, battery charge and active balancing is presented. The challenges addressed here are related to the design...

  3. A New State of Charge Estimation Method for LiFePO4 Battery Packs Used in Robots

    OpenAIRE

    Han-Pang Huang; Ming-Hui Chang; Shu-Wei Chang

    2013-01-01

    The accurate state of charge (SOC) estimation of the LiFePO4 battery packs used in robot applications is required for better battery life cycle, performance, reliability, and economic issues. In this paper, a new SOC estimation method, “Modified ECE + EKF”, is proposed. The method is the combination of the modified Equivalent Coulombic Efficiency (ECE) method and the Extended Kalman Filter (EKF) method. It is based on the zero-state hysteresis battery model, and adopts the EKF method to corre...

  4. Design construction and analysis of solar ridge concentrator photovoltaic (PV) system to improve battery charging performance.

    Science.gov (United States)

    Narasimman, Kalaiselvan; Selvarasan, Iniyan

    2016-05-01

    A ridge concentrator photovoltaic system for a 10W multi-crystalline solar panel was designed with the concentration ratios of 1X and 2X. The ray tracing model of ridge concentrator photovoltaic system was carried out using Trace-Pro simulation. The optimum tilt angle for the concentrator PV system throughout the year was computed. The electrical parameters of the 3 panels were analyzed. The effect of temperature on the electrical performance of the panel was also studied. The reduction of voltage due to increasing panel temperature was managed by MPES type Charge controller. Glass reflector with reflectivity 0.95 was chosen as the ridge wall for the concentrator system. The maximum power outputs for the 1X and 2X panel reached were 9W and 10.5W with glass reflector. The percentage of power improvement for 1X and 2X concentrations were 22.3% and 45.8% respectively. The 2X concentrated panel connected battery takes lower time to charge compared with normal panel connected battery.

  5. Design construction and analysis of solar ridge concentrator photovoltaic (PV) system to improve battery charging performance.

    Science.gov (United States)

    Narasimman, Kalaiselvan; Selvarasan, Iniyan

    2016-05-01

    A ridge concentrator photovoltaic system for a 10W multi-crystalline solar panel was designed with the concentration ratios of 1X and 2X. The ray tracing model of ridge concentrator photovoltaic system was carried out using Trace-Pro simulation. The optimum tilt angle for the concentrator PV system throughout the year was computed. The electrical parameters of the 3 panels were analyzed. The effect of temperature on the electrical performance of the panel was also studied. The reduction of voltage due to increasing panel temperature was managed by MPES type Charge controller. Glass reflector with reflectivity 0.95 was chosen as the ridge wall for the concentrator system. The maximum power outputs for the 1X and 2X panel reached were 9W and 10.5W with glass reflector. The percentage of power improvement for 1X and 2X concentrations were 22.3% and 45.8% respectively. The 2X concentrated panel connected battery takes lower time to charge compared with normal panel connected battery. PMID:26852396

  6. Using Atmospheric Pressure Tendency to Optimise Battery Charging in Off-Grid Hybrid Wind-Diesel Systems for Telecoms

    Directory of Open Access Journals (Sweden)

    Stephen Daniels

    2013-06-01

    Full Text Available Off grid telecom base stations in developing nations are powered by diesel generators. They are typically oversized and run at a fraction of their rated load for most of their operating lifetime. Running generators at partial load is inefficient and, over time, physically damages the engine. A hybrid configuration uses a battery bank, which powers the telecoms’ load for a portion of the time. The generator only operates when the battery bank needs to be charged. Adding a wind turbine further reduces the generator run hours and saves fuel. The generator is oblivious to the current wind conditions, which leads to simultaneous generator-wind power production. As the batteries become charged by the generator, the wind turbine controller is forced to dump surplus power as heat through a resistive load. This paper details how the relationship between barometric pressure and wind speed can be used to add intelligence to the battery charger. A Simulink model of the system is developed to test the different battery charging configurations. This paper demonstrates that if the battery charger is aware of upcoming wind conditions, it will provide modest fuel savings and reduce generator run hours in small-scale hybrid energy systems.

  7. Estimation of State of Charge of a Lithium-Ion Battery Pack for Electric Vehicles Using an Adaptive Luenberger Observer

    Directory of Open Access Journals (Sweden)

    Yuan Zou

    2010-09-01

    Full Text Available In order to safely and efficiently use the power as well as to extend the lifetime of the traction battery pack, accurate estimation of State of Charge (SoC is very important and necessary. This paper presents an adaptive observer-based technique for estimating SoC of a lithium-ion battery pack used in an electric vehicle (EV. The RC equivalent circuit model in ADVISOR is applied to simulate the lithium-ion battery pack. The parameters of the battery model as a function of SoC, are identified and optimized using the numerically nonlinear least squares algorithm, based on an experimental data set. By means of the optimized model, an adaptive Luenberger observer is built to estimate online the SoC of the lithium-ion battery pack. The observer gain is adaptively adjusted using a stochastic gradient approach so as to reduce the error between the estimated battery output voltage and the filtered battery terminal voltage measurement. Validation results show that the proposed technique can accurately estimate SoC of the lithium-ion battery pack without a heavy computational load.

  8. Modeling of the cranking and charging processes of conventional valve regulated lead acid (VRLA) batteries in micro-hybrid applications

    Science.gov (United States)

    Gou, Jun; Lee, Anson; Pyko, Jan

    2014-10-01

    The cranking and charging processes of a VRLA battery during stop-start cycling in micro-hybrid applications were simulated by one dimensional mathematical modeling, to study the formation and distribution of lead sulfate across the cell and analyze the resulting effect on battery aging. The battery focused on in this study represents a conventional VRLA battery without any carbon additives in the electrodes or carbon-based electrodes. The modeling results were validated against experimental data and used to analyze the "sulfation" of negative electrodes - the common failure mode of lead acid batteries under high-rate partial state of charge (HRPSoC) cycling. The analyses were based on two aging mechanisms proposed in previous studies and the predictions showed consistency with the previous teardown observations that the sulfate formed at the negative interface is more difficult to be converted back than anywhere else in the electrodes. The impact of cranking pulses during stop-start cycling on current density and the corresponding sulfate layer production was estimated. The effects of some critical design parameters on sulfate formation, distribution and aging over cycling were investigated, which provided guidelines for developing models and designing of VRLA batteries in micro-hybrid applications.

  9. Estimation of State of Charge for Two Types of Lithium-Ion Batteries by Nonlinear Predictive Filter for Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Yin Hua

    2015-04-01

    Full Text Available Estimation of state of charge (SOC is of great importance for lithium-ion (Li-ion batteries used in electric vehicles. This paper presents a state of charge estimation method using nonlinear predictive filter (NPF and evaluates the proposed method on the lithium-ion batteries with different chemistries. Contrary to most conventional filters which usually assume a zero mean white Gaussian process noise, the advantage of NPF is that the process noise in NPF is treated as an unknown model error and determined as a part of the solution without any prior assumption, and it can take any statistical distribution form, which improves the estimation accuracy. In consideration of the model accuracy and computational complexity, a first-order equivalent circuit model is applied to characterize the battery behavior. The experimental test is conducted on the LiCoO2 and LiFePO4 battery cells to validate the proposed method. The results show that the NPF method is able to accurately estimate the battery SOC and has good robust performance to the different initial states for both cells. Furthermore, the comparison study between NPF and well-established extended Kalman filter for battery SOC estimation indicates that the proposed NPF method has better estimation accuracy and converges faster.

  10. In-Use Fleet Evaluation of Fast-Charge Battery Electric Transit Buses

    Energy Technology Data Exchange (ETDEWEB)

    Prohaska, Robert; Kelly, Kenneth; Eudy; Leslie

    2016-06-27

    With support from the U.S. Department of Energy's Vehicle Technologies Office, the National Renewable Energy Laboratory (NREL) conducts real-world performance evaluations of advanced medium- and heavy-duty fleet vehicles. Evaluation results can help vehicle manufacturers fine-tune their designs and assist fleet managers in selecting fuel-efficient, low-emission vehicles that meet their economic and operational goals. In 2015, NREL launched an in-service evaluation of 12 battery electric buses (BEBs) compared to conventional compressed natural gas (CNG) buses operated by Foothill Transit in West Covina, California. The study aims to improve understanding of the overall usage and effectiveness of fast-charge BEBs and associated charging infrastructure in transit operation. To date, NREL researchers have analyzed more than 148,000 km of in-use operational data, including driving and charging events. Foothill Transit purchased the BEBs with grant funding from the Federal Transit Administration's Transit Investments for Greenhouse Gas and Energy Reduction Program.

  11. State-of-charge estimation in lithium-ion batteries: A particle filter approach

    Science.gov (United States)

    Tulsyan, Aditya; Tsai, Yiting; Gopaluni, R. Bhushan; Braatz, Richard D.

    2016-11-01

    The dynamics of lithium-ion batteries are complex and are often approximated by models consisting of partial differential equations (PDEs) relating the internal ionic concentrations and potentials. The Pseudo two-dimensional model (P2D) is one model that performs sufficiently accurately under various operating conditions and battery chemistries. Despite its widespread use for prediction, this model is too complex for standard estimation and control applications. This article presents an original algorithm for state-of-charge estimation using the P2D model. Partial differential equations are discretized using implicit stable algorithms and reformulated into a nonlinear state-space model. This discrete, high-dimensional model (consisting of tens to hundreds of states) contains implicit, nonlinear algebraic equations. The uncertainty in the model is characterized by additive Gaussian noise. By exploiting the special structure of the pseudo two-dimensional model, a novel particle filter algorithm that sweeps in time and spatial coordinates independently is developed. This algorithm circumvents the degeneracy problems associated with high-dimensional state estimation and avoids the repetitive solution of implicit equations by defining a 'tether' particle. The approach is illustrated through extensive simulations.

  12. An Assessment of Grid-Charged Inverter-Battery Systems for Domestic Applications in Ghana

    Directory of Open Access Journals (Sweden)

    David A. Quansah

    2016-01-01

    Full Text Available Ghana, like many African countries, is currently facing power supply shortage, which has led to load shedding. To minimize the impact of the power crisis, options such as diesel and petrol generators, grid-charged battery-inverter systems (GBIS, and solar PV with battery storage (SPVS have been used in residential and nonresidential contexts. In this paper, we develop analytical models to conduct a technical and economic comparison of GBIS and SPVS systems. Using average electricity tariff of $0.186 for residential sector (excluding lifeline customers we show that although initial cost of SPVS is higher, it costs 30% less than GBIS. We also show that losses associated with the GBIS are as high as 42% when viewed from a systems perspective and that some of its costs are externalized. We conclude by commending the Ghana Government’s initiative of rolling out 200,000 residential rooftop solar systems and recommend an increase in system capacities as well as a similar programme for nonresidential facilities.

  13. The lightest organic radical cation for charge storage in redox flow batteries

    Science.gov (United States)

    Huang, Jinhua; Pan, Baofei; Duan, Wentao; Wei, Xiaoliang; Assary, Rajeev S.; Su, Liang; Brushett, Fikile R.; Cheng, Lei; Liao, Chen; Ferrandon, Magali S.; Wang, Wei; Zhang, Zhengcheng; Burrell, Anthony K.; Curtiss, Larry A.; Shkrob, Ilya A.; Moore, Jeffrey S.; Zhang, Lu

    2016-08-01

    In advanced electrical grids of the future, electrochemically rechargeable fluids of high energy density will capture the power generated from intermittent sources like solar and wind. To meet this outstanding technological demand there is a need to understand the fundamental limits and interplay of electrochemical potential, stability, and solubility in low-weight redox-active molecules. By generating a combinatorial set of 1,4-dimethoxybenzene derivatives with different arrangements of substituents, we discovered a minimalistic structure that combines exceptional long-term stability in its oxidized form and a record-breaking intrinsic capacity of 161 mAh/g. The nonaqueous redox flow battery has been demonstrated that uses this molecule as a catholyte material and operated stably for 100 charge/discharge cycles. The observed stability trends are rationalized by mechanistic considerations of the reaction pathways.

  14. The lightest organic radical cation for charge storage in redox flow batteries.

    Science.gov (United States)

    Huang, Jinhua; Pan, Baofei; Duan, Wentao; Wei, Xiaoliang; Assary, Rajeev S; Su, Liang; Brushett, Fikile R; Cheng, Lei; Liao, Chen; Ferrandon, Magali S; Wang, Wei; Zhang, Zhengcheng; Burrell, Anthony K; Curtiss, Larry A; Shkrob, Ilya A; Moore, Jeffrey S; Zhang, Lu

    2016-01-01

    In advanced electrical grids of the future, electrochemically rechargeable fluids of high energy density will capture the power generated from intermittent sources like solar and wind. To meet this outstanding technological demand there is a need to understand the fundamental limits and interplay of electrochemical potential, stability, and solubility in low-weight redox-active molecules. By generating a combinatorial set of 1,4-dimethoxybenzene derivatives with different arrangements of substituents, we discovered a minimalistic structure that combines exceptional long-term stability in its oxidized form and a record-breaking intrinsic capacity of 161 mAh/g. The nonaqueous redox flow battery has been demonstrated that uses this molecule as a catholyte material and operated stably for 100 charge/discharge cycles. The observed stability trends are rationalized by mechanistic considerations of the reaction pathways. PMID:27558638

  15. Space Charge Layer Effect in Solid State Ion Conductors and Lithium Batteries: Principle and Perspective.

    Science.gov (United States)

    Chen, Cheng; Guo, Xiangxin

    2016-01-01

    The space charge layer (SCL) effects were initially developed to explain the anomalous conductivity enhancement in composite ionic conductors. They were further extended to qualitatively as well as quantitatively understand the interfacial phenomena in many other ionic-conducting systems. Especially in nanometre-scale systems, the SCL effects could be used to manipulate the conductivity and construct artificial conductors. Recently, existence of such effects either at the electrolyte/cathode interface or at the interfaces inside the composite electrode in all solid state lithium batteries (ASSLB) has attracted attention. Therefore, in this article, the principle of SCL on basis of defect chemistry is first presented. The SCL effects on the carrier transport and storage in typical conducting systems are reviewed. For ASSLB, the relevant effects reported so far are also reviewed. Finally, the perspective of interface engineer related to SCL in ASSLB is addressed.

  16. The lightest organic radical cation for charge storage in redox flow batteries

    Science.gov (United States)

    Huang, Jinhua; Pan, Baofei; Duan, Wentao; Wei, Xiaoliang; Assary, Rajeev S.; Su, Liang; Brushett, Fikile R.; Cheng, Lei; Liao, Chen; Ferrandon, Magali S.; Wang, Wei; Zhang, Zhengcheng; Burrell, Anthony K.; Curtiss, Larry A.; Shkrob, Ilya A.; Moore, Jeffrey S.; Zhang, Lu

    2016-01-01

    In advanced electrical grids of the future, electrochemically rechargeable fluids of high energy density will capture the power generated from intermittent sources like solar and wind. To meet this outstanding technological demand there is a need to understand the fundamental limits and interplay of electrochemical potential, stability, and solubility in low-weight redox-active molecules. By generating a combinatorial set of 1,4-dimethoxybenzene derivatives with different arrangements of substituents, we discovered a minimalistic structure that combines exceptional long-term stability in its oxidized form and a record-breaking intrinsic capacity of 161 mAh/g. The nonaqueous redox flow battery has been demonstrated that uses this molecule as a catholyte material and operated stably for 100 charge/discharge cycles. The observed stability trends are rationalized by mechanistic considerations of the reaction pathways. PMID:27558638

  17. Fast charging technique for high power LiFePO4 batteries: A mechanistic analysis of aging

    Science.gov (United States)

    Anseán, D.; Dubarry, M.; Devie, A.; Liaw, B. Y.; García, V. M.; Viera, J. C.; González, M.

    2016-07-01

    One of the major issues hampering the acceptance of electric vehicles (EVs) is the anxiety associated with long charging time. Hence, the ability to fast charging lithium-ion battery (LIB) systems is gaining notable interest. However, fast charging is not tolerated by all LIB chemistries because it affects battery functionality and accelerates its aging processes. Here, we investigate the long-term effects of multistage fast charging on a commercial high power LiFePO4-based cell and compare it to another cell tested under standard charging. Coupling incremental capacity (IC) and IC peak area analysis together with mechanistic model simulations ('Alawa' toolbox with harvested half-cell data), we quantify the degradation modes that cause aging of the tested cells. The results show that the proposed fast charging technique caused similar aging effects as standard charging. The degradation is caused by a linear loss of lithium inventory, coupled with a less degree of linear loss of active material on the negative electrode. This study validates fast charging as a feasible mean of operation for this particular LIB chemistry and cell architecture. It also illustrates the benefits of a mechanistic approach to understand cell degradation on commercial cells.

  18. 电动汽车蓄电池的充电方法和充电设备%Charging equipment and method of electric vehicle battery

    Institute of Scientific and Technical Information of China (English)

    李俄收; 朱会田; 吴文民

    2009-01-01

    电动汽车常用的蓄电池有铅酸蓄电池、镉镍电池、氢镍电池、锂离子电池等,由于它们的结构及充电特性不同,充电时的方法也各异,这些蓄电池使用的充电设备可以是车载式、非车载式,也可以是接触式和感应式的.%Batteries of electric vehicles are commonly used lead-acid battery, Ni-Cd battery, Ni-MH battery, lithium-ion battery and so on. As a result of their construction and charging characteristics are different, methods of charging are different. Charging equipments of these batteries may take different form of vehicle-mounted, non-vehicle-mounted,contacted and the induction.

  19. A New Battery Energy Storage Charging/Discharging Scheme for Wind Power Producers in Real-Time Markets

    Directory of Open Access Journals (Sweden)

    Minh Y Nguyen

    2012-12-01

    Full Text Available Under a deregulated environment, wind power producers are subject to many regulation costs due to the intermittence of natural resources and the accuracy limits of existing prediction tools. This paper addresses the operation (charging/discharging problem of battery energy storage installed in a wind generation system in order to improve the value of wind power in the real-time market. Depending on the prediction of market prices and the probabilistic information of wind generation, wind power producers can schedule the battery energy storage for the next day in order to maximize the profit. In addition, by taking into account the expenses of using batteries, the proposed charging/discharging scheme is able to avoid the detrimental operation of battery energy storage which can lead to a significant reduction of battery lifetime, i.e., uneconomical operation. The problem is formulated in a dynamic programming framework and solved by a dynamic programming backward algorithm. The proposed scheme is then applied to the study cases, and the results of simulation show its effectiveness.

  20. Extended Kalman filter method for state of charge estimation of vanadium redox flow battery using thermal-dependent electrical model

    Science.gov (United States)

    Xiong, Binyu; Zhao, Jiyun; Wei, Zhongbao; Skyllas-Kazacos, Maria

    2014-09-01

    State of charge (SOC) estimation is a key issue for battery management since an accurate estimation method can ensure safe operation and prevent the over-charge/discharge of a battery. Traditionally, open circuit voltage (OCV) method is utilized to estimate the stack SOC and one open flow cell is needed in each battery stack [1,2]. In this paper, an alternative method, extended Kalman filter (EKF) method, is proposed for SOC estimation for VRBs. By measuring the stack terminal voltages and applied currents, SOC can be predicted with a state estimator instead of an additional open circuit flow cell. To implement EKF estimator, an electrical model is required for battery analysis. A thermal-dependent electrical circuit model is proposed to describe the charge/discharge characteristics of the VRB. Two scenarios are tested for the robustness of the EKF. For the lab testing scenarios, the filtered stack voltage tracks the experimental data despite the model errors. For the online operation, the simulated temperature rise is observed and the maximum SOC error is within 5.5%. It is concluded that EKF method is capable of accurately predicting SOC using stack terminal voltages and applied currents in the absence of an open flow cell for OCV measurement.

  1. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  2. Kalman filter for onboard state of charge estimation and peak power capability analysis of lithium-ion batteries

    Science.gov (United States)

    Dong, Guangzhong; Wei, Jingwen; Chen, Zonghai

    2016-10-01

    To evaluate the continuous and instantaneous load capability of a battery, this paper describes a joint estimator for state-of-charge (SOC) and state-of-function (SOF) of lithium-ion batteries (LIB) based on Kalman filter (KF). The SOC is a widely used index for remain useful capacity left in a battery. The SOF represents the peak power capability of the battery. It can be determined by real-time SOC estimation and terminal voltage prediction, which can be derived from impedance parameters. However, the open-circuit-voltage (OCV) of LiFePO4 is highly nonlinear with SOC, which leads to the difficulties in SOC estimation. To solve these problems, this paper proposed an onboard SOC estimation method. Firstly, a simplified linearized equivalent-circuit-model is developed to simulate the dynamic characteristics of a battery, where the OCV is regarded as a linearized function of SOC. Then, the system states are estimated based on the KF. Besides, the factors that influence peak power capability are analyzed according to statistical data. Finally, the performance of the proposed methodology is demonstrated by experiments conducted on a LiFePO4 LIBs under different operating currents and temperatures. Experimental results indicate that the proposed approach is suitable for battery onboard SOC and SOF estimation.

  3. Design and simulation of a fast-charging station for plug-in hybrid electric vehicle (PHEV) batteries

    Science.gov (United States)

    de Leon, Nathalie Pulmones

    2011-12-01

    With the increasing interest in green technologies in transportation, plug-in hybrid electric vehicles (PHEV) have proven to be the best short-term solution to minimize greenhouse gas emissions. Despite such interest, conventional vehicle drivers are still reluctant in using such a new technology, mainly because of the long duration (4-8 hours) required to charge PHEV batteries with the currently existing Level I and II chargers. For this reason, Level III fast-charging stations capable of reducing the charging duration to 10-15 minutes are being considered. The present thesis focuses on the design of a fast-charging station that uses, in addition to the electrical grid, two stationary energy storage devices: a flywheel energy storage and a supercapacitor. The power electronic converters used for the interface of the energy sources with the charging station are designed. The design also focuses on the energy management that will minimize the PHEV battery charging duration as well as the duration required to recharge the energy storage devices. For this reason, an algorithm that minimizes durations along with its mathematical formulation is proposed, and its application in fast charging environment will be illustrated by means of two scenarios.

  4. A zero dimensional model of lithium-sulfur batteries during charge and discharge.

    Science.gov (United States)

    Marinescu, Monica; Zhang, Teng; Offer, Gregory J

    2016-01-01

    Lithium-sulfur cells present an attractive alternative to Li-ion batteries due to their large energy density, safety, and possible low cost. Their successful commercialisation is dependent on improving their performance, but also on acquiring sufficient understanding of the underlying mechanisms to allow for the development of predictive models for operational cells. To address the latter, we present a zero dimensional model that predicts many of the features observed in the behaviour of a lithium-sulfur cell during charge and discharge. The model accounts for two electrochemical reactions via the Nernst formulation, power limitations through Butler-Volmer kinetics, and precipitation/dissolution of one species, including nucleation. It is shown that the flat shape of the low voltage plateau typical of the lithium-sulfur cell discharge is caused by precipitation. During charge, it is predicted that the dissolution can act as a bottleneck, because for large enough currents the amount that dissolves becomes limited. This results in reduced charge capacity and an earlier onset of the high plateau reaction, such that the two voltage plateaus merge. By including these effects, the model improves on the existing zero dimensional models, while requiring considerably fewer input parameters and computational resources than one dimensional models. The model also predicts that, due to precipitation, the customary way of experimentally obtaining the open circuit voltage from a low rate discharge might not be suitable for lithium-sulfur. This model can provide the basis for mechanistic studies, identification of dominant effects in a real cell, predictions of operational behaviour under realistic loads, and control algorithms for applications. PMID:26618508

  5. A zero dimensional model of lithium-sulfur batteries during charge and discharge.

    Science.gov (United States)

    Marinescu, Monica; Zhang, Teng; Offer, Gregory J

    2016-01-01

    Lithium-sulfur cells present an attractive alternative to Li-ion batteries due to their large energy density, safety, and possible low cost. Their successful commercialisation is dependent on improving their performance, but also on acquiring sufficient understanding of the underlying mechanisms to allow for the development of predictive models for operational cells. To address the latter, we present a zero dimensional model that predicts many of the features observed in the behaviour of a lithium-sulfur cell during charge and discharge. The model accounts for two electrochemical reactions via the Nernst formulation, power limitations through Butler-Volmer kinetics, and precipitation/dissolution of one species, including nucleation. It is shown that the flat shape of the low voltage plateau typical of the lithium-sulfur cell discharge is caused by precipitation. During charge, it is predicted that the dissolution can act as a bottleneck, because for large enough currents the amount that dissolves becomes limited. This results in reduced charge capacity and an earlier onset of the high plateau reaction, such that the two voltage plateaus merge. By including these effects, the model improves on the existing zero dimensional models, while requiring considerably fewer input parameters and computational resources than one dimensional models. The model also predicts that, due to precipitation, the customary way of experimentally obtaining the open circuit voltage from a low rate discharge might not be suitable for lithium-sulfur. This model can provide the basis for mechanistic studies, identification of dominant effects in a real cell, predictions of operational behaviour under realistic loads, and control algorithms for applications.

  6. A data-driven based adaptive state of charge estimator of lithium-ion polymer battery used in electric vehicles

    International Nuclear Information System (INIS)

    Highlights: • A lumped parameter battery model against different battery aging levels is proposed. • The RLS based method is used to identify the parameter of battery model in real-time. • A data-driven based adaptive SoC estimator is developed by RLS and AEKF algorithm. • The robustness of the SoC estimator against varying loading profiles is evaluated. • The robustness of the SoC estimator against different aging levels is evaluated. - Abstract: An accurate State of Charge (SoC) estimation method is one of the most significant and difficult techniques to promote the commercialization of electric vehicles. The paper attempts to make three contributions. (1) Through the recursive least square algorithm based identification method, the parameter of the lumped parameter battery model can be updated at each sampling interval with the real-time measurement of battery current and voltage, which is called the data-driven method. Note that the battery model has been improved with a simple electrochemical equation for describing the open circuit voltage against different aging levels and SoC. (2) Through the real-time updating technique of model parameter, a data-driven based adaptive SoC estimator is established with an adaptive extended Kalman filter. It has the potential to overcome the estimation error against battery degradation and varied operating environments. (3) The approach has been verified by different loading profiles of various health states of Lithium-ion polymer battery (LiPB) cells. The results indicate that the maximum estimation errors of voltage and SoC are less than 1% and 1.5% respectively

  7. State of Charge Balancing Control of a Multi-Functional Battery Energy Storage System Based on a 11-Level Cascaded Multilevel PWM Converter

    DEFF Research Database (Denmark)

    Wang, Songcen; Teodorescu, Remus; Máthé, Lászlo;

    2015-01-01

    This paper focuses on modeling and SOC (State of Charge) balancing control of lithium-ion battery energy storage system based on cascaded multilevel converter for both grid integration and electric vehicle propulsion applications. The equivalent electrical circuit model of lithium-ion battery...... module is established based on the relationship between SOC (State of Charge) and OCV (Open Circuit Voltage) which is obtained from the battery charge and discharge test curves. A hierarchical control structure is proposed to realize different operating modes. The decoupled current control scheme...

  8. 电池梯次利用储能装置在电动汽车充换电站中的应用%Application of Battery Cascade Utilization Device in EV Battery Charging and Swapping Station

    Institute of Scientific and Technical Information of China (English)

    王泽众; 李家辉

    2012-01-01

    针对电动汽车充换电站中动力电池的梯次利用问题,设计了电池梯次利用储能站,将充换电站中即将报废的电池用于储能放电,以降低电动汽车动力电池的使用成本.介绍了电池梯次利用储能站结构、电能控制系统以及储能控制策略,可以实现电动汽车充换电站动力电池的梯次利用、对电网负荷进行峰谷调节并作为充换电站的应急和后备电源.%Aiming at the application of battery cascade utilization in EV ( electric vehicle) battery charging and swapping station, this paper design battery cascade utilization storage station. In order to decreasing the battery cost, it utilizes the reject battery of battery charging and swapping station to storage and discharge electric energy. This paper introduces the battery cascade utilization device construction, control system and electric storage control strategy. It can implement the battery cascade utilization, regulate power grid peak and valley and be emergency power of the battery charging and swapping station.

  9. Dynamic Electrochemical Impedance Spectroscopy of a Three-Electrode Lithium-Ion Battery during Pulse Charge and Discharge

    International Nuclear Information System (INIS)

    Highlights: • Dynamic EIS is performed on a three-electrode pouch cell; • Charge transfer resistance during insertion is generally larger than that during deinsertion due to the surface concentration change; • An inductive behavior is revealed at low frequencies due to the violation of stationary condition in DEIS measurement; • Electrochemical models of a single active particle in both time and frequency domain are developed. • The model predicts a positive correlation between the lower frequency limit and the DC current. - Abstract: The dynamic electrochemical impedance spectroscopy (DEIS) of a three-electrode pouch type lithium-ion battery is measured using a series of sine wave perturbations super-imposed on pulse charge and discharge. The DEIS reveals noticeable differences between charge and discharge at frequencies corresponding to the charge transfer reaction. The charge transfer resistance during intercalation is generally found to be larger than that during deintercalation for the battery chemistry in this study. This result is mainly attributed to the decreased Li ion concentration in the electrolyte during intercalation. At low frequencies, an abnormal inductive behavior is also observed. Such abnormality is found to result from the violation of stationary condition, i.e. the state of the battery under pulse charge or discharge deviates significantly from its initial condition for the perturbation of low frequencies. To analytically define the stationary condition, we develop electrochemical models of a single active particle in both time and frequency domain, which describes the transport of lithium ions in both active particle and electrolyte phase and the interfacial charge transfer reactions at their interface. The lower frequency limit is a key parameter to ensure a quasistationary state during the DEIS measurement. An explicit formulation of the stationary condition predicts a positive correlation between the lower frequency limit and

  10. A New State of Charge Estimation Method for LiFePO4 Battery Packs Used in Robots

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-04-15

    The accurate state of charge (SOC) estimation of the LiFePO4 battery packs used in robot applications is required for better battery life cycle, performance, reliability, and economic issues. In this paper, a new SOC estimation method, ''Modified ECE + EKF'', is proposed. The method is the combination of the modified Equivalent Coulombic Efficiency (ECE) method and the Extended Kalman Filter (EKF) method. It is based on the zero-state hysteresis battery model, and adopts the EKF method to correct the initial value used in the Ah counting method. Experimental results show that the proposed technique is superior to the traditional techniques, such as ECE + EKF and ECE + Unscented Kalman Filter (UKF), and the accuracy of estimation is within 1%.

  11. A New State of Charge Estimation Method for LiFePO4 Battery Packs Used in Robots

    Directory of Open Access Journals (Sweden)

    Han-Pang Huang

    2013-04-01

    Full Text Available The accurate state of charge (SOC estimation of the LiFePO4 battery packs used in robot applications is required for better battery life cycle, performance, reliability, and economic issues. In this paper, a new SOC estimation method, “Modified ECE + EKF”, is proposed. The method is the combination of the modified Equivalent Coulombic Efficiency (ECE method and the Extended Kalman Filter (EKF method. It is based on the zero-state hysteresis battery model, and adopts the EKF method to correct the initial value used in the Ah counting method. Experimental results show that the proposed technique is superior to the traditional techniques, such as ECE + EKF and ECE + Unscented Kalman Filter (UKF, and the accuracy of estimation is within 1%.

  12. Effects of state of charge on the degradation of LiFePO4/graphite batteries during accelerated storage test

    International Nuclear Information System (INIS)

    Highlights: • Degradation of LiFePO4/graphite batteries under different state of charge at 55 °C is investigate. • Side reactions caused by self-discharge are the main reason for performance fade during storage. • The detailed degradation mechanism is proven by post-mortem analysis. • Increased electrode resistance in LiFePO4 cathode suggests that side reactions also happen at positive electrode. - Abstract: In this paper, the degradation of LiFePO4/graphite batteries during 10 months of storage under different temperatures and states of charge (SOCs) is studied. The effects of SOC during storage process are systematically investigated using electrochemical methods and post-mortem analysis. The results show that at elevated temperature of 55 °C, higher stored SOC results in more significant increase in bulk resistance (Rb) and charge-transfer resistance (Rct) of full battery, whereas the rate-discharge capability of stored battery is unchanged. The side reactions at the electrode/electrolyte interface caused by self-discharge are the main reasons for the performance fading during storage. For LiFePO4 cathode, long-time storage does not influence the framework structure under various SOCs. The existence of little irreversible capacity loss and impedance increase indicates that side reactions also occur at the positive electrode. For graphite anode, only a little capacity loss is found upon storage. There is a significant increase in impedance and a small amount of Fe deposition on graphite anode after storage at 100% SOC and 55 °C. The lithium ion loss arises from side reactions taking place at the graphite anode, which is responsible for the capacity degradation of battery during the storage process. XPS analysis confirms that a deposit layer composed of Li2CO3 and LiF is formed on the surface of anode

  13. Role of electrical resistance of electrodes in modeling of discharging and charging of flooded lead-acid batteries

    Science.gov (United States)

    Gandhi, K. S.

    2015-03-01

    Electrical resistance of both the electrodes of a lead-acid battery increases during discharge due to formation of lead sulfate, an insulator. Work of Metzendorf [1] shows that resistance increases sharply at about 65% conversion of active materials, and battery stops discharging once this critical conversion is reached. However, these aspects are not incorporated into existing mathematical models. Present work uses the results of Metzendorf [1], and develops a model that includes the effect of variable resistance. Further, it uses a reasonable expression to account for the decrease in active area during discharge instead of the empirical equations of previous work. The model's predictions are compared with observations of Cugnet et al. [2]. The model is as successful as the non-mechanistic models existing in literature. Inclusion of variation in resistance of electrodes in the model is important if one of the electrodes is a limiting reactant. If active materials are stoichiometrically balanced, resistance of electrodes can be very large at the end of discharge but has only a minor effect on charging of batteries. The model points to the significance of electrical conductivity of electrodes in the charging of deep discharged batteries.

  14. Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy

    Science.gov (United States)

    Liu, Xiaosong; Wang, Dongdong; Liu, Gao; Srinivasan, Venkat; Liu, Zhi; Hussain, Zahid; Yang, Wanli

    2013-10-01

    Developing high-performance batteries relies on material breakthroughs. During the past few years, various in situ characterization tools have been developed and have become indispensible in studying and the eventual optimization of battery materials. However, soft X-ray spectroscopy, one of the most sensitive probes of electronic states, has been mainly limited to ex situ experiments for battery research. Here we achieve in situ and operando soft X-ray absorption spectroscopy of lithium-ion battery cathodes. Taking advantage of the elemental, chemical and surface sensitivities of soft X-rays, we discover distinct lithium-ion and electron dynamics in Li(Co1/3Ni1/3Mn1/3)O2 and LiFePO4 cathodes in polymer electrolytes. The contrast between the two systems and the relaxation effect in LiFePO4 is attributed to a phase transformation mechanism, and the mesoscale morphology and charge conductivity of the electrodes. These discoveries demonstrate feasibility and power of in situ soft X-ray spectroscopy for studying integrated and dynamic effects in batteries.

  15. Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy

    Science.gov (United States)

    Liu, Xiaosong; Wang, Dongdong; Liu, Gao; Srinivasan, Venkat; Liu, Zhi; Hussain, Zahid; Yang, Wanli

    2013-01-01

    Developing high-performance batteries relies on material breakthroughs. During the past few years, various in situ characterization tools have been developed and have become indispensible in studying and the eventual optimization of battery materials. However, soft X-ray spectroscopy, one of the most sensitive probes of electronic states, has been mainly limited to ex situ experiments for battery research. Here we achieve in situ and operando soft X-ray absorption spectroscopy of lithium-ion battery cathodes. Taking advantage of the elemental, chemical and surface sensitivities of soft X-rays, we discover distinct lithium-ion and electron dynamics in Li(Co1/3Ni1/3Mn1/3)O2 and LiFePO4 cathodes in polymer electrolytes. The contrast between the two systems and the relaxation effect in LiFePO4 is attributed to a phase transformation mechanism, and the mesoscale morphology and charge conductivity of the electrodes. These discoveries demonstrate feasibility and power of in situ soft X-ray spectroscopy for studying integrated and dynamic effects in batteries. PMID:24100759

  16. Robust Online State of Charge Estimation of Lithium-Ion Battery Pack Based on Error Sensitivity Analysis

    Directory of Open Access Journals (Sweden)

    Ting Zhao

    2015-01-01

    Full Text Available Accurate and reliable state of charge (SOC estimation is a key enabling technique for large format lithium-ion battery pack due to its vital role in battery safety and effective management. This paper tries to make three contributions to existing literatures through robust algorithms. (1 Observer based SOC estimation error model is established, where the crucial parameters on SOC estimation accuracy are determined by quantitative analysis, being a basis for parameters update. (2 The estimation method for a battery pack in which the inconsistency of cells is taken into consideration is proposed, ensuring all batteries’ SOC ranging from 0 to 1, effectively avoiding the battery overcharged/overdischarged. Online estimation of the parameters is also presented in this paper. (3 The SOC estimation accuracy of the battery pack is verified using the hardware-in-loop simulation platform. The experimental results at various dynamic test conditions, temperatures, and initial SOC difference between two cells demonstrate the efficacy of the proposed method.

  17. Vertical distribution of overpotentials and irreversible charge losses in lithium ion battery electrodes.

    Science.gov (United States)

    Klink, Stefan; Schuhmann, Wolfgang; La Mantia, Fabio

    2014-08-01

    Porous lithium ion battery electrodes are characterized using a vertical distribution of cross-currents. In an appropriate simplification, this distribution can be described by a transmission line model (TLM) consisting of infinitely thin electrode layers. To investigate the vertical distribution of currents, overpotentials, and irreversible charge losses in a porous graphite electrode in situ, a multi-layered working electrode (MWE) was developed as the experimental analogue of a TLM. In this MWE, each layer is in ionic contact but electrically insulated from the other layers by a porous separator. It was found that the negative graphite electrodes get lithiated and delithiated stage-by-stage and layer-by-layer. Several mass-transport- as well as non-mass-transport-limited processes could be identified. Local current densities can reach double the average, especially on the outermost layer at the beginning of each intercalation stage. Furthermore, graphite particles close to the counter electrode act as "electrochemical sieve" reducing the impurities present in the electrolyte such as water.

  18. A New Battery Energy Storage Charging/Discharging Scheme for Wind Power Producers in Real-Time Markets

    OpenAIRE

    Minh Y Nguyen; Dinh Hung Nguyen; Yong Tae Yoon

    2012-01-01

    Under a deregulated environment, wind power producers are subject to many regulation costs due to the intermittence of natural resources and the accuracy limits of existing prediction tools. This paper addresses the operation (charging/discharging) problem of battery energy storage installed in a wind generation system in order to improve the value of wind power in the real-time market. Depending on the prediction of market prices and the probabilistic information of wind generation, wind pow...

  19. Negative plates for dry-charged lead storage batteries. [higher charging capacity when impregnated with tannin solution

    Energy Technology Data Exchange (ETDEWEB)

    Fiedler, V.; Malikova, V.; Weber, H.

    1970-09-15

    Impregnation of negative plates with acid solutions of sulfomethylated tannins was found to improve the charging properties at low temperatures. Methods for synthesizing tannins are described. Charging capacity at 0/sup 0/ was 7.3A. (RWR)

  20. Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential

    OpenAIRE

    Jian Zhang; Yubao Zhao; Xiao Zhao; Zhaolin Liu; Wei Chen

    2014-01-01

    Developing efficient catalyst for oxygen evolution reaction (OER) is essential for rechargeable Li-O2 battery. In our present work, porous LaNiO3 nanocubes were employed as electrocatalyst in Li-O2 battery cell. The as-prepared battery showed excellent charging performance with significantly reduced overpotential (3.40 V). The synergistic effect of porous structure, large specific surface area and high electrocatalytic activity of porous LaNiO3 nanocubes ensured the Li-O2 battery with enchanc...

  1. 蓄电池容量均衡方法概述%Review on Battery Charge Equalization

    Institute of Scientific and Technical Information of China (English)

    董博; 李永东

    2011-01-01

    蓄电池由于其储能时间长,价格低等特点在电动车、新能源发电等领域得到了广泛应用。但蓄电池单体电压、容量较小,为了满足增大蓄电池容量的要求,一般将蓄电池单体串联使用,但由于单体的个体差异,在长时间使用后会导致单体的容量各不相同,对整个电池组的效率产生严重的影响。因此对蓄电池组各单体的容量均衡就非常重要.是保证蓄电池长期、有效运行的关键技术。文中将对现有的各种蓄电池均衡技术进行介绍,并指出各种方法的优缺点。%Battery is used widely in EV and renewable energy generation because of its long-time storage and low price. However, the voltage and energy of a cell are very low. In order to increase storage energy, cells are usually used in series connection. For the difference among cells, state of charge will be different after a long time use, which could decrease the efficiency of battery pack. Therefore, the battery charge equalization is very important. A review on battery charge equalization is described, bringing forward the advantage and disadvantage of each method.

  2. Micro-hybrid electric vehicle application of valve-regulated lead-acid batteries in absorbent glass mat technology: Testing a partial-state-of-charge operation strategy

    Science.gov (United States)

    Schaeck, S.; Stoermer, A. O.; Hockgeiger, E.

    The BMW Group has launched two micro-hybrid functions in high volume models in order to contribute to reduction of fuel consumption in modern passenger cars. Both the brake energy regeneration (BER) and the auto-start-stop function (ASSF) are based on the conventional 14 V vehicle electrical system and current series components with only little modifications. An intelligent control algorithm of the alternator enables recuperative charging in braking and coasting phases, known as BER. By switching off the internal combustion engine at a vehicle standstill the idling fuel consumption is effectively reduced by ASSF. By reason of economy and package a lead-acid battery is used as electrochemical energy storage device. The BMW Group assembles valve-regulated lead-acid (VRLA) batteries in absorbent glass mat (AGM) technology in the micro-hybrid electrical power system since special challenges arise for the batteries. By field data analysis a lower average state-of-charge (SOC) due to partial state-of-charge (PSOC) operation and a higher cycling rate due to BER and ASSF are confirmed in this article. Similar to a design of experiment (DOE) like method we present a long-term lab investigation. Two types of 90 Ah VRLA AGM batteries are operated with a test bench profile that simulates the micro-hybrid vehicle electrical system under varying conditions. The main attention of this lab testing is focused on capacity loss and charge acceptance over cycle life. These effects are put into context with periodically refresh charging the batteries in order to prevent accelerated battery aging due to hard sulfation. We demonstrate the positive effect of refresh chargings concerning preservation of battery charge acceptance. Furthermore, we observe moderate capacity loss over 90 full cycles both at 25 °C and at 3 °C battery temperature.

  3. Dynamic data-driven identification of battery state-of-charge via symbolic analysis of input–output pairs

    International Nuclear Information System (INIS)

    Highlights: • Symbolic Time Series Analysis (STSA) has been used for low-complexity feature extraction. • Discrete wavelet transformation (DWT) has been used for data segmentation. • Algorithms have been validated on experimental data of pairs of current and voltage data from a lead-acid battery. - Abstract: This paper presents a dynamic data-driven method of pattern classification for identification of the state-of-charge (SOC) parameter in battery systems for diverse applications (e.g., plug-in electric vehicles and hybrid locomotives). The underlying theory is built upon the concept of symbolic dynamics, which represents the behavior of battery system dynamics at different levels of SOC as probabilistic finite state automata (PFSA). In the proposed method, (finite-length) blocks of battery data are selected via wavelet-based segmentation from the time series of synchronized input–output (i.e., current–voltage) pairs in the respective two-dimensional space. Then, symbol strings are generated from the segmented time series pairs in the sense of maximum entropy partitioning and a special class of PFSA, called the D-Markov machine, is constructed to extract the features of the battery system dynamics for pattern classification. To deal with the uncertainties due to the (finite-length) approximation of symbol sequences, combinations of (a priori) Dirichlet and (a posteriori) multinomial distributions are respectively adopted in the training and testing phases of pattern classification. The proposed concept of pattern classification has been validated on (approximately periodic) experimental data that have been acquired from a commercial-scale lead-acid battery

  4. Multi-step constant-current charging method for electric vehicle, valve-regulated, lead/acid batteries during night time for load-levelling

    Energy Technology Data Exchange (ETDEWEB)

    Ikeya, Tomohiko; Mita, Yuichi; Ishihara, Kaoru [Central Research Inst. of Electric Power Industry, Tokyo (Japan); Sawada, Nobuyuki [Hokkaido Electric Power, Sapporo (Japan); Takagi, Sakae; Murakami, Jun-ichi [Tohoku Electric Power, Sendai (Japan); Kobayashi, Kazuyuki [Tokyo Electric Power, Yokohama (Japan); Sakabe, Tetsuya [Chubu Electric Power, Nagoya (Japan); Kousaka, Eiichi [Hokuriku Electric Power, Toyama (Japan); Yoshioka, Haruki [The Kansai Electric Power, Osaka (Japan); Kato, Satoru [The Chugoku Electric Power, Hiroshima (Japan); Yamashita, Masanori [Shikoku Research Inst., Takamatsu (Japan); Narisoko, Hayato [The Okinawa Electric Power, Naha (Japan); Nishiyama, Kazuo [The Central Electric Power Council, Tokyo (Japan); Adachi, Kazuyuki [Kyushu Electric Power, Fukuoka (Japan)

    1998-09-01

    For the popularization of electric vehicles (EVs), the conditions for charging EV batteries with available current patterns should allow complete charging in a short time, i.e., less than 5 to 8 h. Therefore, in this study, a new charging condition is investigated for the EV valve-regulated lead/acid battery system, which should allow complete charging of EV battery systems with multi-step constant currents in a much shorter time with longer cycle life and higher energy efficiency compared with two-step constant-current charging. Although a high magnitude of the first current in the two-step constant-current method prolongs cycle life by suppressing the softening of positive active material, too large a charging current magnitude degrades cells due to excess internal evolution of heat. A charging current magnitude of approximately 0.5 C is expected to prolong cycle life further. Three-step charging could also increase the magnitude of charging current in the first step without shortening cycle life. Four-or six-step constant-current methods could shorten the charging time to less than 5 h, as well as yield higher energy efficiency and enhanced cycle life of over 400 cycles compared with two-step charging with the first step current of 0.5 C. Investigation of the degradation mechanism of the batteries revealed that the conditions of multi-step constant-current charging suppressed softening of positive active material and sulfation of negative active material, but, unfortunately, advanced the corrosion of the grids in the positive plates. By adopting improved grids and cooling of the battery system, the multistep constant-current method may enhance the cycle life. (orig.)

  5. Elucidating the Performance Limitations of Lithium-ion Batteries due to Species and Charge Transport through Five Characteristic Parameters

    Science.gov (United States)

    Jiang, Fangming; Peng, Peng

    2016-01-01

    Underutilization due to performance limitations imposed by species and charge transports is one of the key issues that persist with various lithium-ion batteries. To elucidate the relevant mechanisms, two groups of characteristic parameters were proposed. The first group contains three characteristic time parameters, namely: (1) te, which characterizes the Li-ion transport rate in the electrolyte phase, (2) ts, characterizing the lithium diffusion rate in the solid active materials, and (3) tc, describing the local Li-ion depletion rate in electrolyte phase at the electrolyte/electrode interface due to electrochemical reactions. The second group contains two electric resistance parameters: Re and Rs, which represent respectively, the equivalent ionic transport resistance and the effective electronic transport resistance in the electrode. Electrochemical modeling and simulations to the discharge process of LiCoO2 cells reveal that: (1) if te, ts and tc are on the same order of magnitude, the species transports may not cause any performance limitations to the battery; (2) the underlying mechanisms of performance limitations due to thick electrode, high-rate operation, and large-sized active material particles as well as effects of charge transports are revealed. The findings may be used as quantitative guidelines in the development and design of more advanced Li-ion batteries. PMID:27599870

  6. Janus Solid-Liquid Interface Enabling Ultrahigh Charging and Discharging Rate for Advanced Lithium-Ion Batteries.

    Science.gov (United States)

    Zheng, Jiaxin; Hou, Yuyang; Duan, Yandong; Song, Xiaohe; Wei, Yi; Liu, Tongchao; Hu, Jiangtao; Guo, Hua; Zhuo, Zengqing; Liu, Lili; Chang, Zheng; Wang, Xiaowei; Zherebetskyy, Danylo; Fang, Yanyan; Lin, Yuan; Xu, Kang; Wang, Lin-Wang; Wu, Yuping; Pan, Feng

    2015-09-01

    LiFePO4 has long been held as one of the most promising battery cathode for its high energy storage capacity. Meanwhile, although extensive studies have been conducted on the interfacial chemistries in Li-ion batteries,1-3 little is known on the atomic level about the solid-liquid interface of LiFePO4/electrolyte. Here, we report battery cathode consisted with nanosized LiFePO4 particles in aqueous electrolyte with an high charging and discharging rate of 600 C (3600/600 = 6 s charge time, 1 C = 170 mAh g(-1)) reaching 72 mAh g(-1) energy storage (42% of the theoretical capacity). By contrast, the accessible capacity sharply decreases to 20 mAh g(-1) at 200 C in organic electrolyte. After a comprehensive electrochemistry tests and ab initio calculations of the LiFePO4-H2O and LiFePO4-EC (ethylene carbonate) systems, we identified the transient formation of a Janus hydrated interface in the LiFePO4-H2O system, where the truncated symmetry of solid LiFePO4 surface is compensated by the chemisorbed H2O molecules, forming a half-solid (LiFePO4) and half-liquid (H2O) amphiphilic coordination environment that eases the Li desolvation process near the surface, which makes a fast Li-ion transport across the solid/liquid interfaces possible. PMID:26305572

  7. Improved reversibility in lithium-oxygen battery: Understanding elementary reactions and surface charge engineering of metal alloy catalyst

    Science.gov (United States)

    Kim, Byung Gon; Kim, Hyung-Jin; Back, Seoin; Nam, Kwan Woo; Jung, Yousung; Han, Young-Kyu; Choi, Jang Wook

    2014-02-01

    Most Li-O2 batteries suffer from sluggish kinetics during oxygen evolution reactions (OERs). To overcome this drawback, we take the lesson from other catalysis researches that showed improved catalytic activities by employing metal alloy catalysts. Such research effort has led us to find Pt3Co nanoparticles as an effective OER catalyst in Li-O2 batteries. The superior catalytic activity was reflected in the substantially decreased overpotentials and improved cycling/rate performance compared to those of other catalysts. Density functional theory calculations suggested that the low OER overpotentials are associated with the reduced adsorption strength of LiO2 on the outermost Pt catalytic sites. Also, the alloy catalyst generates amorphous Li2O2 conformally coated around the catalyst and thus facilitates easier decomposition and higher reversibility. This investigation conveys an important message that understanding elementary reactions and surface charge engineering of air-catalysts are one of the most effective approaches in resolving the chronic sluggish charging kinetics in Li-O2 batteries.

  8. Elucidating the Performance Limitations of Lithium-ion Batteries due to Species and Charge Transport through Five Characteristic Parameters.

    Science.gov (United States)

    Jiang, Fangming; Peng, Peng

    2016-01-01

    Underutilization due to performance limitations imposed by species and charge transports is one of the key issues that persist with various lithium-ion batteries. To elucidate the relevant mechanisms, two groups of characteristic parameters were proposed. The first group contains three characteristic time parameters, namely: (1) te, which characterizes the Li-ion transport rate in the electrolyte phase, (2) ts, characterizing the lithium diffusion rate in the solid active materials, and (3) tc, describing the local Li-ion depletion rate in electrolyte phase at the electrolyte/electrode interface due to electrochemical reactions. The second group contains two electric resistance parameters: Re and Rs, which represent respectively, the equivalent ionic transport resistance and the effective electronic transport resistance in the electrode. Electrochemical modeling and simulations to the discharge process of LiCoO2 cells reveal that: (1) if te, ts and tc are on the same order of magnitude, the species transports may not cause any performance limitations to the battery; (2) the underlying mechanisms of performance limitations due to thick electrode, high-rate operation, and large-sized active material particles as well as effects of charge transports are revealed. The findings may be used as quantitative guidelines in the development and design of more advanced Li-ion batteries. PMID:27599870

  9. Porous Perovskite LaNiO3 Nanocubes as Cathode Catalysts for Li-O2 Batteries with Low Charge Potential

    Science.gov (United States)

    Zhang, Jian; Zhao, Yubao; Zhao, Xiao; Liu, Zhaolin; Chen, Wei

    2014-08-01

    Developing efficient catalyst for oxygen evolution reaction (OER) is essential for rechargeable Li-O2 battery. In our present work, porous LaNiO3 nanocubes were employed as electrocatalyst in Li-O2 battery cell. The as-prepared battery showed excellent charging performance with significantly reduced overpotential (3.40 V). The synergistic effect of porous structure, large specific surface area and high electrocatalytic activity of porous LaNiO3 nanocubes ensured the Li-O2 battery with enchanced capacity and good cycle stability. Furthermore, it was found that the lithium anode corrosion and cathode passivation were responsible for the capacity fading of Li-O2 battery. Our results indicated that porous LaNiO3 nanocubes represent a promising cathode catalyst for Li-O2 battery.

  10. Direct Solar Charging of an Organic-Inorganic, Stable, and Aqueous Alkaline Redox Flow Battery with a Hematite Photoanode.

    Science.gov (United States)

    Wedege, Kristina; Azevedo, João; Khataee, Amirreza; Bentien, Anders; Mendes, Adélio

    2016-06-13

    The intermittent nature of the sunlight and its increasing contribution to electricity generation is fostering the energy storage research. Direct solar charging of an auspicious type of redox flow battery could make solar energy directly and efficiently dispatchable. The first solar aqueous alkaline redox flow battery using low cost and environmentally safe materials is demonstrated. The electrolytes consist of the redox couples ferrocyanide and anthraquinone-2,7-disulphonate in sodium hydroxide solution, yielding a standard cell potential of 0.74 V. Photovoltage enhancement strategies are demonstrated for the ferrocyanide-hematite junction by employing an annealing treatment and growing a layer of a conductive polyaniline polymer on the electrode surface, which decreases electron-hole recombination. PMID:27151516

  11. Optimization of the cycle life performance of VRLA batteries, working under high rate, partial state of charge (HRPSOC) conditions

    Science.gov (United States)

    Fernández, M.; Trinidad, F.; Valenciano, J.; Sánchez, A.

    On hybrid vehicle applications, batteries must work in a rather low state of charge (SOC), in order to be able to recover as much of the regenerative braking energy as possible. Usually SOC values around 60% are used, which promotes the development of new unexpected failure modes not previously found, mainly associated with heavy sulphation of the negative plates. In order to try to optimise the cycle life performance to the point of making these batteries a real alternative for the application of hybrid vehicles, a series of tests have been undertaken, aimed to optimise the key parameters that from previous experience are known to determine life duration in high rate low state of charge (HRPSOC) conditions. Previous works have been focused on trying to determine the optimum composition of positive and negative active material, concerning paste density in the positive, and additives in negative. In order to overcome the deleterious effect of heavy sulphation in negative plates on cycle life, the use of conductivity enhancers additives such as graphite has been proposed. The objective of this project is to optimize the performance of the glass microfiber separators, in order to maintain a high degree of compression in the group, as well as to avoid acid stratification and development of short circuits along the battery life. To do this, different glass microfiber separators with inert additives, as well as different fiber composition have been tested. Results obtained up to now, indicate a remarkable good performance of the VRLA batteries with the new separators containing very fine fiberglass and silica fillers as an additive.

  12. VRLA铅酸蓄电池充电技术与内阻测量%Research on Charging Technology and Internal Resistance Testing of Lead-Acid Battery

    Institute of Scientific and Technical Information of China (English)

    李琳; 颜湘武

    2012-01-01

    研究了铅酸蓄电池的反应原理和特点,充电过程中的极化现象,分析了蓄电池常规充电、快速充电、智能充电的原理和特点,阐述了蓄电池内阻的不同测量方法。%This paper researches on the reaction principle and characteristics of lead-acid batteries, and the polarization phenomenon of the battery charging process, analyzs the principles and characteristics of conventional charging, fast char ging, intelligent charging methods of lead-acid batteries, finally descrihs different measurement methods of the internal re sistance in the process of charging.

  13. The correlation of the properties of pyrrolidinium-based ionic liquid electrolytes with the discharge-charge performances of rechargeable Li-O2 batteries

    Science.gov (United States)

    Li, Yu; Zhang, Zhonglin; Duan, Donghong; Sun, Yanbo; Wei, Guoqiang; Hao, Xiaogang; Liu, Shibin; Han, Yunxia; Meng, Weijuan

    2016-10-01

    Pyrrolidinium-based ionic liquids (ILs), such as PYR13TFSI, PYR14TFSI, and PYR1(2O1)TFSI, exhibit high thermal and electrochemical stability with wide electrochemical windows as electrolytes for application to rechargeable Li-O2 batteries. In this work, several fundamental properties of three ILs are measured: the ionic conductivity, oxygen solubility, and oxygen diffusion coefficient. The oxygen electro-reduction kinetics is characterized using cyclic voltammetry. The performances of Li-O2 batteries with these IL electrolytes are also investigated using electrochemical impedance spectroscopy and galvanostatic discharge-charge tests. The results demonstrate that the PYR1(2O1)TFSI electrolyte battery has a higher first-discharge voltage than the PYR13TFSI electrolyte and PYR14TFSI electrolyte batteries. Both PYR13TFSI- and PYR1(2O1)TFSI-based batteries exhibit higher first-discharge capacities and better cycling stabilities than the PYR14TFSI-based battery for 30 cycles. A theoretical analysis of the experimental results shows that the diffusion coefficient and solubility of oxygen in the electrolyte remarkably affect the discharge capacity and cycling stability of the batteries. Particularly, the oxygen diffusion coefficient of the IL electrolyte can effectively facilitate the electrochemical oxygen electro-reduction reaction and oxygen concentration distribution in the catalyst layers of air electrodes. The oxygen diffusion coefficient and oxygen solubility improvements of IL electrolytes can enhance the discharge-charge performances of Li-O2 batteries.

  14. Numerical simulation of gas diffusion effects on charge/discharge characteristics of a solid oxide redox flow battery

    Science.gov (United States)

    Ohmori, Hiroko; Uratani, Syoichi; Iwai, Hiroshi

    2012-06-01

    Fundamental characteristics of a solid oxide redox flow battery consisting of solid oxide electrochemical cell (SOEC) and redox metal were studied by a gas-diffusion based time-dependent 1-D numerical simulation taking both the electrochemical and redox reactions into account. Close attention was paid to the distributions of the participating gas species and their effects on the charge/discharge performance. The volume expansion/reduction of the porous metal associated with the redox reaction was modeled as decrease/increase in local porosity. The numerical results for charge/discharge operation qualitatively showed the time-dependent distributions of the related physical quantities such as the gas concentrations, the active reaction region in the redox metal, and its local porosity. It was found that, to ensure effective redox reaction throughout the operation, the gas diffusion in the redox metal should be carefully designed.

  15. A Combined State of Charge Estimation Method for Lithium-Ion Batteries Used in a Wide Ambient Temperature Range

    Directory of Open Access Journals (Sweden)

    Fei Feng

    2014-05-01

    Full Text Available Ambient temperature is a significant factor that influences the characteristics of lithium-ion batteries, which can produce adverse effects on state of charge (SOC estimation. In this paper, an integrated SOC algorithm that combines an advanced ampere-hour counting (Adv Ah method and multistate open-circuit voltage (multi OCV method, denoted as “Adv Ah + multi OCV”, is proposed. Ah counting is a simple and general method for estimating SOC. However, the available capacity and coulombic efficiency in this method are influenced by the operating states of batteries, such as temperature and current, thereby causing SOC estimation errors. To address this problem, an enhanced Ah counting method that can alter the available capacity and coulombic efficiency according to temperature is proposed during the SOC calculation. Moreover, the battery SOCs between different temperatures can be mutually converted in accordance with the capacity loss. To compensate for the accumulating errors in Ah counting caused by the low precision of current sensors and lack of accurate initial SOC, the OCV method is used for calibration and as a complement. Given the variation of available capacities at different temperatures, rated/non-rated OCV–SOCs are established to estimate the initial SOCs in accordance with the Ah counting SOCs. Two dynamic tests, namely, constant- and alternated-temperature tests, are employed to verify the combined method at different temperatures. The results indicate that our method can provide effective and accurate SOC estimation at different ambient temperatures.

  16. Trace H2 O2 -Assisted High-Capacity Tungsten Oxide Electrochromic Batteries with Ultrafast Charging in Seconds.

    Science.gov (United States)

    Zhao, Jinxiong; Tian, Yuyu; Wang, Zhen; Cong, Shan; Zhou, Di; Zhang, Qingzhu; Yang, Mei; Zhang, Weikun; Geng, Fengxia; Zhao, Zhigang

    2016-06-13

    A recent technological trend in the field of electrochemical energy storage is to integrate energy storage and electrochromism functions in one smart device, which can establish efficient user-device interactions based on a friendly human-readable output. This type of newly born energy storage technology has drawn tremendous attention. However, there is still plenty of room for technological and material innovation, which would allow advancement of the research field. A prototype Al-tungsten oxide electrochromic battery with interactive color-changing behavior is reported. With the assistance of trace amount of H2 O2 , the battery exhibits a specific capacity almost seven times that for the reported electrochromic batteries, up to 429 mAh g(-1) . Fast decoloration of the reduced tungsten oxide affords a very quick charging time of only eight seconds, which possibly comes from an intricate combination of structure and valence state changes of tungsten oxide. This unique combination of features may further advance the development of smart energy storage devices with suitability for user-device interactions.

  17. An Adaptive Gain Nonlinear Observer for State of Charge Estimation of Lithium-Ion Batteries in Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Yong Tian

    2014-09-01

    Full Text Available The state of charge (SOC is important for the safety and reliability of battery operation since it indicates the remaining capacity of a battery. However, it is difficult to get an accurate value of SOC, because the SOC cannot be directly measured by a sensor. In this paper, an adaptive gain nonlinear observer (AGNO for SOC estimation of lithium-ion batteries (LIBs in electric vehicles (EVs is proposed. The second-order resistor–capacitor (2RC equivalent circuit model is used to simulate the dynamic behaviors of a LIB, based on which the state equations are derived to design the AGNO for SOC estimation. The model parameters are identified using the exponential-function fitting method. The sixth-order polynomial function is used to describe the highly nonlinear relationship between the open circuit voltage (OCV and the SOC. The convergence of the proposed AGNO is proved using the Lyapunov stability theory. Two typical driving cycles, including the New European Driving Cycle (NEDC and Federal Urban Driving Schedule (FUDS are adopted to evaluate the performance of the AGNO by comparing with the unscented Kalman filter (UKF algorithm. The experimental results show that the AGNO has better performance than the UKF algorithm in terms of reducing the computation cost, improving the estimation accuracy and enhancing the convergence ability.

  18. Car battery quick charging technology analysis%车用蓄电池快速充电技术分析

    Institute of Scientific and Technical Information of China (English)

    刘文东; 郝宏波; 刘巍巍

    2014-01-01

    本文通过对当前动力电池优缺点的分析,提出我国应该增加投资力度,引进国外已经攻克蓄电池缺点的最新研究成果,并通过我国科技工作者的技术攻关,解决驱动汽车的动力电池充电时间长、使用寿命短,消费者不满意的问题。于此同时,也不放弃对其他种类的电力汽车的研究。%In this paper,through the analysis of the advantages and disadvantages of the current power bat-tery, put forward our country should increase the intensity of investment, the latest research results in the introduction of foreign has overcome the shortcomings of the battery,and through technical research scien-tist of China, to solve the power of battery powered cars, the charging time is long, short service life, consumers are not satisfied with the problem. In the meantime, the study also don't give up on other kinds of electric car.

  19. Battery Safety Basics

    Science.gov (United States)

    Roy, Ken

    2010-01-01

    Batteries commonly used in flashlights and other household devices produce hydrogen gas as a product of zinc electrode corrosion. The amount of gas produced is affected by the batteries' design and charge rate. Dangerous levels of hydrogen gas can be released if battery types are mixed, batteries are damaged, batteries are of different ages, or…

  20. Research on ISFLA-Based Optimal Control Strategy for the Coordinated Charging of EV Battery Swap Station

    Directory of Open Access Journals (Sweden)

    Xueliang Huang

    2013-01-01

    Full Text Available As an important component of the smart grid, electric vehicles (EVs could be a good measure against energy shortages and environmental pollution. A main way of energy supply to EVs is to swap battery from the swap station. Based on the characteristics of EV battery swap station, the coordinated charging optimal control strategy is investigated to smooth the load fluctuation. Shuffled frog leaping algorithm (SFLA is an optimization method inspired by the memetic evolution of a group of frogs when seeking food. An improved shuffled frog leaping algorithm (ISFLA with the reflecting method to deal with the boundary constraint is proposed to obtain the solution of the optimal control strategy for coordinated charging. Based on the daily load of a certain area, the numerical simulations including the comparison of PSO and ISFLA are carried out and the results show that the presented ISFLA can effectively lower the peak-valley difference and smooth the load profile with the faster convergence rate and higher convergence precision.

  1. Structural and Electrochemical Investigation during the First Charging Cycles of Silicon Microwire Array Anodes for High Capacity Lithium Ion Batteries

    Directory of Open Access Journals (Sweden)

    Helmut Föll

    2013-02-01

    Full Text Available Silicon microwire arrays embedded in Cu present exceptional performance as anode material in Li ion batteries. The processes occurring during the first charging cycles of batteries with this anode are essential for good performance. This paper sheds light on the electrochemical and structural properties of the anodes during the first charging cycles. Scanning Electron Microscopy, X-ray diffractommetry, and fast Fourier transformation impedance spectroscopy are used for the characterization. It was found that crystalline phases with high Li content are obtained after the first lithiation cycle, while for the second lithiation just crystalline phases with less Li are observable, indicating that the lithiated wires become amorphous upon cycling. The formation of a solid electrolyte interface of around 250 nm during the first lithiation cycle is evidenced, and is considered a necessary component for the good cycling performance of the wires. Analog to voltammetric techniques, impedance spectroscopy is confirmed as a powerful tool to identify the formation of the different Si-Li phases.

  2. New Technology for USB Battery Charging and Testing Method%最新USB充电技术与测试

    Institute of Scientific and Technical Information of China (English)

    魏明

    2011-01-01

    The USB2.0 spec does not take into account the applications that portable devices charging their batteries on an USB port,but such applications are becoming more and more popular.This paper describes the main content of the battery charging specification version 1.2 which is latest issued by USB-IF.Then,it gives a brief introduction of the related test specifications and introduces the key items and difficult contents during the tests based on the test experience.%USB2.0规范并没有考虑到使用USB接口为便携式设备的电池进行充电的需求,而这样的应用需求却越来越多。本文首先介绍USB-IF最新颁布的电池充电规范v1.2版本的主要内容;然后对其相关测试规范做简单介绍;最后结合测试经验,对测试中的重点项目和难点内容进行说明。

  3. Implementation of RTOS on STM32F4 Microcontroller to Control Parallel Boost for Photovoltaic Battery Charging Application

    Directory of Open Access Journals (Sweden)

    EkaPrasetyono

    2015-12-01

    Full Text Available The DC-DC converter is operated with pulse width modulation (PWM and controlled by modifying duty cycle. The PWM is easy developed on microcontroller system, but the problem become complex when some control algorithm implemented to determine duty cycle value. Multitasking is needed to handle sensor, control algorithm and user interface system. This paper discusses the application of Real Time Operating System (RTOS to handle multitasking process on STM32F407 ARM Cortex M4 microcontroller to control parallel boost converter with load sharing algorithm for photovoltaic (PV battery charging application. The first OS task is to run MPPT to get maximum energy from PV. This first OS task is implemented to control the first boost converter. Then, The second OS task to run fuzzy logic controller to control battery charging current with load sharing energy. This second OS task is task implemented to control second boost converter. The measurement of current and voltage of both converter side, display and user interface system also handled with OS task. As the result, each designed task could run well with recommended OS task priority for MPPT and Fuzzy is IRQ task and for TFT_LCD_displayosPriorityAboveNormal.

  4. Dossier Car Batteries. Charging for a breakthrough; Dossier Autoaccu's. Opladen voor een doorbraak

    Energy Technology Data Exchange (ETDEWEB)

    Scholtens, B.

    2012-02-03

    The use of lithium batteries has exploded over the past 20 years. They are mainly used in electronic devices such as mobile phones, laptops and cameras. The use in electric vehicles is the next step. For a breakthrough, however, lithium batteries are required that can store more power. [Dutch] Het gebruik van lithiumbatterijen is de afgelopen 20 jaren explosief gestegen. Ze worden met name gebruikt in elektronische apparatuur, zoals mobiele telefoons, laptops en camera's. De toepassing in elektrische auto's is de volgende stap. Voor een doorbraak zijn echter lithiumaccu's vereist die meer stroom kunnen opslaan.

  5. Cell-level battery charge/discharge protection system. [electronic control techniques

    Science.gov (United States)

    Donovan, R. L.; Imamura, M. S.

    1977-01-01

    The paper describes three design approaches to individual cell monitoring and control for sealed secondary battery cells. One technique involves a modular strap-on single cell protector which contains all the electronics required for monitoring cell voltage, responding to external commands, and forming a bypass circuit for the cell. A second technique, the multiplexed cell protector, uses common circuitry to monitor and control each cell in a battery pack. The third technique, the computerized cell protector, by replacing the hard-wired logic of the multiplexed cell protector with a microprocessor, achieves greatest control flexibility and inherent computational capability with a minimum parts count implementation.

  6. A Study of Fuel Economy Improvement in a Plug-in Hybrid Electric Vehicle using Engine on/off and Battery Charging Power Control Based on Driver Characteristics

    Directory of Open Access Journals (Sweden)

    Seulgi Lee

    2015-09-01

    Full Text Available In this study, driving data for various types of drivers are collected using a VIDE (virtual integrated driving environment, and a driver model is developed. To represent the driver tendencies quantitatively, the DDA (degree of driver aggression is proposed based on fuzzy logic. DDA has a 0-1 value; the closer the DDA is to one, the more aggressive the driver. Using the DDA, an engine on/off and battery charging power control algorithm are developed to improve the fuel economy of a power-split-type plug-in hybrid electric vehicle. The engine on/off control reduces the frequent engine on/off caused by aggressive driving, whereas the battery charging power control maintains the battery state of charge (SOC by operating the engine according to the DDA. It is found that the proposed control algorithm improves fuel economy by 17.3% compared to the existing control for an aggressive driver.

  7. On-line parameter, state-of-charge and aging estimation of Li-ion batteries

    NARCIS (Netherlands)

    Rosca, B.; Kessels, J.T.B.A.; Bergveld, H.J.; Bosch, P.P.J. van den

    2012-01-01

    This paper presents an on-line model identification method for Li-ion battery parameters that combines high accuracy and low computational complexity. Experimental results show that modeling errors are smaller than 1% throughout the feasible operating range. The identified model is used in a state o

  8. A Real-Time Joint Estimator for Model Parameters and State of Charge of Lithium-Ion Batteries in Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Jianping Gao

    2015-08-01

    Full Text Available Accurate state of charge (SoC estimation of batteries plays an important role in promoting the commercialization of electric vehicles. The main work to be done in accurately determining battery SoC can be summarized in three parts. (1 In view of the model-based SoC estimation flow diagram, the n-order resistance-capacitance (RC battery model is proposed and expected to accurately simulate the battery’s major time-variable, nonlinear characteristics. Then, the mathematical equations for model parameter identification and SoC estimation of this model are constructed. (2 The Akaike information criterion is used to determine an optimal tradeoff between battery model complexity and prediction precision for the n-order RC battery model. Results from a comparative analysis show that the first-order RC battery model is thought to be the best based on the Akaike information criterion (AIC values. (3 The real-time joint estimator for the model parameter and SoC is constructed, and the application based on two battery types indicates that the proposed SoC estimator is a closed-loop identification system where the model parameter identification and SoC estimation are corrected mutually, adaptively and simultaneously according to the observer values. The maximum SoC estimation error is less than 1% for both battery types, even against the inaccurate initial SoC.

  9. Estimation of the charge quantity from solar cell to battery; Taiyo denchi ni yoru chikudenchi eno juden yosoku

    Energy Technology Data Exchange (ETDEWEB)

    Tsutsumi, K.; Nishitani, M. [Daiichi University, College of Technology, Kagoshima (Japan)

    1996-10-27

    In performing an experiment of running a small electric vehicle by installing solar cells in it and by charging the storage battery at a specific voltage, an estimation was made on the charge quantity to the battery for each solar altitude and inclination of a module at different hours. The solar altitude was determined at Daiichi University, College of Technology, according to the month and the time of day from a formula using day-declination and time equation of a chronological table of science. The quantity of global solar radiation was determined by resolving the solar radiation into its direct and diffuse components on the basis of the extra-terrestrial solar radiation quantity with the change in radius vector taken into consideration; and then, the global solar radiation on the inclined face was obtained from the angle of inclination and incidence. On the roof of a Daiichi University building, solar cell modules were installed facing north and south at 0{degree}, 30{degree}, 45{degree}, 60{degree} and 90{degree} each, so that a short-circuit current was measured for each differently inclined angle. As a result of the experiment, shown in an regression formula is a relation between the temperature conversion value of the maximum output of the solar cell at the standard temperature of 25{degree}C and the quantity of solar radiation on the inclined surface. Consequently, it enabled the prediction of a charging quantity, in the case of running a small vehicle with solar cells installed, from the quantity of solar radiation on the inclined surface in the clear weather. 2 refs., 4 figs., 2 tabs.

  10. An Electric taxi fleet charged by second use batteries: not just economic profit

    OpenAIRE

    Canals Casals, Lluc; Amante García, Beatriz

    2013-01-01

    The road transport sector is the second biggest CO2 emissions contributor after energy generation. In urban environments, its impact is increased due to the worse combustion engine driving efficiency. It is thought that electric mobility might bring some relief to big cities’ polluted air. At the same time, car manufacturers are searching for second battery applications in order to reduce its manufacture cost and make electric cars achievable for most people. This paper seeks to a...

  11. State-Of-Charge Estimation of Li-Ion Battery Using Extended Kalman Filter

    OpenAIRE

    Feng Jin; He Yong-ling

    2013-01-01

    The Li-ion battery is studied base on its equivalent circuit PNGV model. The model parameters are identified by HPPC test. The discrete state space equation is established according to the model. The basic theory of extended Kalman filter algorithm is studied and then the filtering algorithm is set up under the noisy environments. Finally, a kind of electric car is used for testing under the UDDS driving condition. The difference between the simulation value using extended Kalman filter under...

  12. Effect of binder polymer structures used in composite cathodes on interfacial charge transfer processes in lithium polymer batteries

    Energy Technology Data Exchange (ETDEWEB)

    Seki, Shiro; Tabata, Seiichiro [Yokohama National University (Japan). Dept. of Chemistry and Biotechnology; Matsui, Shohei [DAISO Co. Ltd., Amagasaki (Japan); Watanabe, Masayoshi [Yokohama National University (Japan). Dept. of Chemistry and Biotechnology; CREST JST, Yokohama (Japan)

    2004-11-30

    The effect of binder polymer structures used in composite cathodes on the interfacial charge transfer processes in lithium polymer batteries (LPB) has been studied in detail. A cross-linked comb-copolymer, consisting of ethylene oxide (EO), 2-(2-methoxyethoxy)ethyl glycidyl ether (MEEGE), and allyl glycidyl ether (AGE), was used as a solid polymer electrolyte (SPE). LiCoO{sub 2} composite cathodes were fabricated using binder comb-copolymers, consisting of EO and MEEGE with different compositions. Ionic conductivity of the SPE, and the interfacial charge transfer processes between the SPE and metallic lithium and between the SPE and the composite cathode at several cathode potentials versus Li/Li{sup +}, were electrochemically explored. With increasing MEEGE composition in the binder copolymers, the interfacial resistances between the SPE and the composite cathode appreciably decreased. As the result, discharge capacity of the LPB also enhanced with increasing the MEEGE composition. The introduction of the branched-side-chains to the polymer backbone to the binder polymers for the composite cathodes caused to facilitate the interfacial charge transport processes, while the introduction had also been found to be very effective in terms of the enhancement of ionic conductivity of SPE. (author)

  13. Effect of binder polymer structures used in composite cathodes on interfacial charge transfer processes in lithium polymer batteries

    International Nuclear Information System (INIS)

    The effect of binder polymer structures used in composite cathodes on the interfacial charge transfer processes in lithium polymer batteries (LPB) has been studied in detail. A cross-linked comb-copolymer, consisting of ethylene oxide (EO), 2-(2-methoxyethoxy)ethyl glycidyl ether (MEEGE), and allyl glycidyl ether (AGE), was used as a solid polymer electrolyte (SPE). LiCoO2 composite cathodes were fabricated using binder comb-copolymers, consisting of EO and MEEGE with different compositions. Ionic conductivity of the SPE, and the interfacial charge transfer processes between the SPE and metallic lithium and between the SPE and the composite cathode at several cathode potentials versus Li/Li+, were electrochemically explored. With increasing MEEGE composition in the binder copolymers, the interfacial resistances between the SPE and the composite cathode appreciably decreased. As the result, discharge capacity of the LPB also enhanced with increasing the MEEGE composition. The introduction of the branched-side-chains to the polymer backbone to the binder polymers for the composite cathodes caused to facilitate the interfacial charge transport processes, while the introduction had also been found to be very effective in terms of the enhancement of ionic conductivity of SPE

  14. Evaluation of Lithium-Ion Battery Equivalent Circuit Models for State of Charge Estimation by an Experimental Approach

    Directory of Open Access Journals (Sweden)

    Jinxin Fan

    2011-03-01

    Full Text Available To improve the use of lithium-ion batteries in electric vehicle (EV applications, evaluations and comparisons of different equivalent circuit models are presented in this paper. Based on an analysis of the traditional lithium-ion battery equivalent circuit models such as the Rint, RC, Thevenin and PNGV models, an improved Thevenin model, named dual polarization (DP model, is put forward by adding an extra RC to simulate the electrochemical polarization and concentration polarization separately. The model parameters are identified with a genetic algorithm, which is used to find the optimal time constant of the model, and the experimental data from a Hybrid Pulse Power Characterization (HPPC test on a LiMn2O4 battery module. Evaluations on the five models are carried out from the point of view of the dynamic performance and the state of charge (SoC estimation. The dynamic performances of the five models are obtained by conducting the Dynamic Stress Test (DST and the accuracy of SoC estimation with the Robust Extended Kalman Filter (REKF approach is determined by performing a Federal Urban Driving Schedules (FUDS experiment. By comparison, the DP model has the best dynamic performance and provides the most accurate SoC estimation. Finally, sensitivity of the different SoC initial values is investigated based on the accuracy of SoC estimation with the REKF approach based on the DP model. It is clear that the errors resulting from the SoC initial value are significantly reduced and the true SoC is convergent within an acceptable error.

  15. Assessing carbon-based anodes for lithium-ion batteries: a universal description of charge-transfer binding.

    Science.gov (United States)

    Liu, Yuanyue; Wang, Y Morris; Yakobson, Boris I; Wood, Brandon C

    2014-07-11

    Many key performance characteristics of carbon-based lithium-ion battery anodes are largely determined by the strength of binding between lithium (Li) and sp(2) carbon (C), which can vary significantly with subtle changes in substrate structure, chemistry, and morphology. Here, we use density functional theory calculations to investigate the interactions of Li with a wide variety of sp(2) C substrates, including pristine, defective, and strained graphene, planar C clusters, nanotubes, C edges, and multilayer stacks. In almost all cases, we find a universal linear relation between the Li-C binding energy and the work required to fill previously unoccupied electronic states within the substrate. This suggests that Li capacity is predominantly determined by two key factors-namely, intrinsic quantum capacitance limitations and the absolute placement of the Fermi level. This simple descriptor allows for straightforward prediction of the Li-C binding energy and related battery characteristics in candidate C materials based solely on the substrate electronic structure. It further suggests specific guidelines for designing more effective C-based anodes. The method should be broadly applicable to charge-transfer adsorption on planar substrates, and provides a phenomenological connection to established principles in supercapacitor and catalyst design. PMID:25062244

  16. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery part I: Bridging mass transport and charge transfer with redox cycle kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Jin, XF; Zhao, X; Huang, K

    2015-04-15

    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JIVIAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H-2/H2O-concentration across various components of the battery are also systematically investigated. (C) 2015 Elsevier B.V. All rights reserved.

  17. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery. part I: Bridging mass transport and charge transfer with redox cycle kinetics

    Science.gov (United States)

    Jin, Xinfang; Zhao, Xuan; Huang, Kevin

    2015-04-01

    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JMAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H2/H2O-concentration across various components of the battery are also systematically investigated.

  18. Joint Estimation of the Electric Vehicle Power Battery State of Charge Based on the Least Squares Method and the Kalman Filter Algorithm

    Directory of Open Access Journals (Sweden)

    Xiangwei Guo

    2016-02-01

    Full Text Available An estimation of the power battery state of charge (SOC is related to the energy management, the battery cycle life and the use cost of electric vehicles. When a lithium-ion power battery is used in an electric vehicle, the SOC displays a very strong time-dependent nonlinearity under the influence of random factors, such as the working conditions and the environment. Hence, research on estimating the SOC of a power battery for an electric vehicle is of great theoretical significance and application value. In this paper, according to the dynamic response of the power battery terminal voltage during a discharging process, the second-order RC circuit is first used as the equivalent model of the power battery. Subsequently, on the basis of this model, the least squares method (LS with a forgetting factor and the adaptive unscented Kalman filter (AUKF algorithm are used jointly in the estimation of the power battery SOC. Simulation experiments show that the joint estimation algorithm proposed in this paper has higher precision and convergence of the initial value error than a single AUKF algorithm.

  19. Thailand's solar white elephants: an analysis of 15 yr of solar battery charging programmes in northern Thailand

    International Nuclear Information System (INIS)

    The use of decentralised renewable energy technologies to provide rural electrification in developing countries has been a common topic of analysis and policy debate for more than two decades. Unfortunately, a lack of empirical evidence about the field performance of these technologies is a significant barrier to making sound policy decisions about them. Compounded by minimal information sharing between stakeholders, this situation has frequently allowed duplication of inefficient policies. This issue is addressed here by providing empirical evidence gathered from field visits and interviews about the largest government subsidised solar battery charging programme in the world. This analysis highlights the different policies of departments responsible and discusses them with specific attention to their technical, social and economic components. Field study results from over 50 villages in the north of Thailand suggest about 60 per cent of these systems are no longer operational. Many of the technical failures observed are attributed to social factors, as well as flawed implementation strategies

  20. The relationship between coefficient of restitution and state of charge of zinc alkaline primary LR6 batteries

    Energy Technology Data Exchange (ETDEWEB)

    Bhadra, S; Hertzberg, BJ; Hsieh, AG; Croft, M; Gallaway, JW; Van Tassell, BJ; Chamoun, M; Erdonmez, C; Zhong, Z; Sholklapper, T; Steingart, DA

    2015-01-01

    The coefficient of restitution of alkaline batteries has been shown to increase as a function of depth of discharge. In this work, using non-destructive mechanical testing, the change in coefficient of restitution is compared to in situ energy-dispersive X-ray diffraction data to determine the cause of the macroscopic change in coefficient of restitution. The increase in coefficient of restitution correlates to the formation of a percolation pathway of ZnO within the anode of the cell, and the coefficient of restitution levels off at a value of 0.66 +/- 0.02 at 50% state of charge when the anode has densified into porous ZnO solid. Of note is the sensitivity of coefficient of restitution to the amount of ZnO formation that rivals the sensitivity of in situ energy-dispersive X-ray diffraction.

  1. In situ monitoring of discharge/charge processes in Li-O2 batteries by electrochemical impedance spectroscopy

    Science.gov (United States)

    Landa-Medrano, Imanol; Ruiz de Larramendi, Idoia; Ortiz-Vitoriano, Nagore; Pinedo, Ricardo; Ignacio Ruiz de Larramendi, José; Rojo, Teófilo

    2014-03-01

    Gaining insight into the reaction mechanisms underway during charge and discharge in Li-air batteries is essential to allow the target development of improved power and performance devices. This work reports the in situ monitoring of Li-air cells by electrochemical impedance spectroscopy and, for the first time, the development of an electrochemical model allowing the identification and attribution of the processes involved. The voltage at which each reaction product forms has been identified, including Li2O2 or Li2CO3 during discharge, together with the delithiation of the outer part of Li2O2 and oxidation reactions and electrolyte decomposition. The developed model can be used as a valuable tool for the optimisation of composition and structure of the air electrode through the investigation of the resistance associated with each process.

  2. Cost-effectiveness of plug-in hybrid electric vehicle battery capacity and charging infrastructure investment for reducing US gasoline consumption

    International Nuclear Information System (INIS)

    Federal electric vehicle (EV) policies in the United States currently include vehicle purchase subsidies linked to EV battery capacity and subsidies for installing charging stations. We assess the cost-effectiveness of increased battery capacity vs. nondomestic charging infrastructure installation for plug-in hybrid electric vehicles as alternate methods to reduce gasoline consumption for cars, trucks, and SUVs in the US. We find across a wide range of scenarios that the least-cost solution is for more drivers to switch to low-capacity plug-in hybrid electric vehicles (short electric range with gasoline backup for long trips) or gasoline-powered hybrid electric vehicles. If more gasoline savings are needed per vehicle, nondomestic charging infrastructure installation is substantially more expensive than increased battery capacity per gallon saved, and both approaches have higher costs than US oil premium estimates. Cost effectiveness of all subsidies are lower under a binding fuel economy standard. Comparison of results to the structure of current federal subsidies shows that policy is not aligned with fuel savings potential, and we discuss issues and alternatives. - Highlights: ► We compare cost of PHEV batteries vs. charging infrastructure per gallon of gasoline saved. ► The lowest cost solution is to switch more drivers to low-capacity PHEVs and HEVs. ► If more gasoline savings is needed, batteries offer a better value than chargers. ► Extra batteries and chargers are both more costly per gal than oil premium estimates. ► Current subsidies are misaligned with fuel savings. We discuss alternatives.

  3. In situ X-ray near-edge absorption spectroscopy investigation of the state of charge of all-vanadium redox flow batteries.

    Science.gov (United States)

    Jia, Chuankun; Liu, Qi; Sun, Cheng-Jun; Yang, Fan; Ren, Yang; Heald, Steve M; Liu, Yadong; Li, Zhe-Fei; Lu, Wenquan; Xie, Jian

    2014-10-22

    Synchrotron-based in situ X-ray near-edge absorption spectroscopy (XANES) has been used to study the valence state evolution of the vanadium ion for both the catholyte and anolyte in all-vanadium redox flow batteries (VRB) under realistic cycling conditions. The results indicate that, when using the widely used charge-discharge profile during the first charge process (charging the VRB cell to 1.65 V under a constant current mode), the vanadium ion valence did not reach V(V) in the catholyte and did not reach V(II) in the anolyte. Consequently, the state of charge (SOC) for the VRB cell was only 82%, far below the desired 100% SOC. Thus, such incompletely charged mix electrolytes results in not only wasting the electrolytes but also decreasing the cell performance in the following cycles. On the basis of our study, we proposed a new charge-discharge profile (first charged at a constant current mode up to 1.65 V and then continuously charged at a constant voltage mode until the capacity was close to the theoretical value) for the first charge process that achieved 100% SOC after the initial charge process. Utilizing this new charge-discharge profile, the theoretical charge capacity and the full utilization of electrolytes has been achieved, thus having a significant impact on the cost reduction of the electrolytes in VRB. PMID:25191695

  4. In situ X-ray near-edge absorption spectroscopy investigation of the state of charge of all-vanadium redox flow batteries.

    Science.gov (United States)

    Jia, Chuankun; Liu, Qi; Sun, Cheng-Jun; Yang, Fan; Ren, Yang; Heald, Steve M; Liu, Yadong; Li, Zhe-Fei; Lu, Wenquan; Xie, Jian

    2014-10-22

    Synchrotron-based in situ X-ray near-edge absorption spectroscopy (XANES) has been used to study the valence state evolution of the vanadium ion for both the catholyte and anolyte in all-vanadium redox flow batteries (VRB) under realistic cycling conditions. The results indicate that, when using the widely used charge-discharge profile during the first charge process (charging the VRB cell to 1.65 V under a constant current mode), the vanadium ion valence did not reach V(V) in the catholyte and did not reach V(II) in the anolyte. Consequently, the state of charge (SOC) for the VRB cell was only 82%, far below the desired 100% SOC. Thus, such incompletely charged mix electrolytes results in not only wasting the electrolytes but also decreasing the cell performance in the following cycles. On the basis of our study, we proposed a new charge-discharge profile (first charged at a constant current mode up to 1.65 V and then continuously charged at a constant voltage mode until the capacity was close to the theoretical value) for the first charge process that achieved 100% SOC after the initial charge process. Utilizing this new charge-discharge profile, the theoretical charge capacity and the full utilization of electrolytes has been achieved, thus having a significant impact on the cost reduction of the electrolytes in VRB.

  5. Design of Charging and Discharging Circuit for Batteries%一种蓄电池充放电电路的设计

    Institute of Scientific and Technical Information of China (English)

    张大为; 张凯; 万道军; 毕涛

    2014-01-01

    Using the principle of capacitor filter stabilizing voltage circuit, main circuit of battery charging and discharging are designed, and control circuit is designed by using of relay switch principle to realize the choice of different charging voltage. In order to strengthen the safety of the battery in charging and discharging circuit, a protection circuit of voltage limiting and current limiting is designed. According to the basic principle, properties, methods of battery charging and discharging, a kind of simple, practical charge and discharge circuit is designed, which has the excellent reversibility and stability.%应用电容滤波稳压电路原理设计蓄电池充放电主电路,再应用继电器开关原理设计出控制电路,实现不同充电电压的选择。为了加强蓄电池充放电电路的安全性能,设计出一种限压、限流的保护电路。根据蓄电池充放电的基本原理、特性、方法等,设计出一种简易、实用的充放电电路,具有良好的可逆性和稳定性。

  6. Influence of memory effect on the state-of-charge estimation of large-format Li-ion batteries based on LiFePO4 cathode

    Science.gov (United States)

    Shi, Wei; Wang, Jiulin; Zheng, Jianming; Jiang, Jiuchun; Viswanathan, Vilayanur; Zhang, Ji-Guang

    2016-04-01

    In this work, we systematically investigated the influence of the memory effect of LiFePO4 cathodes in large-format full batteries. The electrochemical performance of the electrodes used in these batteries was also investigated separately in half-cells to reveal their intrinsic properties. We noticed that the memory effect of LiFePO4/graphite cells depends not only on the maximum state of charge reached during the memory writing process, but is also affected by the depth of discharge reached during the memory writing process. In addition, the voltage deviation in a LiFePO4/graphite full battery is more complex than in a LiFePO4/Li half-cell, especially for a large-format battery, which exhibits a significant current variation in the region near its terminals. Therefore, the memory effect should be taken into account in advanced battery management systems to further extend the long-term cycling stabilities of Li-ion batteries using LiFePO4 cathodes.

  7. Comparison of Nonlinear Filtering Methods for Estimating the State of Charge of Li4Ti5O12 Lithium-Ion Battery

    Directory of Open Access Journals (Sweden)

    Jianping Gao

    2015-01-01

    Full Text Available Accurate state of charge (SoC estimation is of great significance for the lithium-ion battery to ensure its safety operation and to prevent it from overcharging or overdischarging. To achieve reliable SoC estimation for Li4Ti5O12 lithium-ion battery cell, three filtering methods have been compared and evaluated. A main contribution of this study is that a general three-step model-based battery SoC estimation scheme has been proposed. It includes the processes of battery data measurement, parametric modeling, and model-based SoC estimation. With the proposed general scheme, multiple types of model-based SoC estimators have been developed and evaluated for battery management system application. The detailed comparisons on three advanced adaptive filter techniques, which include extend Kalman filter, unscented Kalman filter, and adaptive extend Kalman filter (AEKF, have been implemented with a Li4Ti5O12 lithium-ion battery. The experimental results indicate that the proposed model-based SoC estimation approach with AEKF algorithm, which uses the covariance matching technique, performs well with good accuracy and robustness; the mean absolute error of the SoC estimation is within 1% especially with big SoC initial error.

  8. Monitoring and control system for the charging of batteries in photovoltaic applications; Sistema para monitorizar y controlar la carga de baterias en aplicaciones fotovoltaicas

    Energy Technology Data Exchange (ETDEWEB)

    Ortega S, Cesar A; Pacheco A, Maria Jojutla; Orozco V, Jaime A; Cristin V, Miguel A [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2004-07-01

    The appropriate monitoring and control of the charging of lead-acid (LAB) batteries is an increasing necessity in an industry that demands systems with low maintenance costs and high availability. The problem of extending the batteries useful life becomes more complex when the batteries are charged through photovoltaic panels. The purpose of the present article is to offer the description of the system for monitoring and control for the charging of batteries developed at the Instituto de Investigaciones Electricas (IIE). This system performs a continuous monitoring of the charging state of the battery and of the main operation parameters. With the extracted information of the data, the fine tuning algorithm control can be made. The data are acquired in a personal computer through a serial connection. Once stored, they are presented to the user in a graphical way so that they can be analyzed. [Spanish] El adecuado monitoreo y control de carga de baterias plomo-acido (BPA) es una necesidad creciente en una industria que demanda sistemas con bajos costos de mantenimiento y alta disponibilidad. El problema de extender la vida util de las baterias se vuelve mas complejo cuando las baterias son cargadas a traves de paneles fotovoltaicos. La intencion del presente articulo es ofrecer la descripcion del sistema para monitoreo y control de carga de baterias desarrollado en el Instituto de Investigaciones Electricas (IIE). Este sistema realiza un monitoreo continuo del estado de carga de la bateria y de los principales parametros de operacion. Con la informacion extraida de los datos, se puede hacer la sintonizacion fina del algoritmo de control. Los datos se adquieren en una computadora personal a traves de un enlace serial. Una vez almacenados, se presentan al usuario de manera grafica para que puedan ser analizados.

  9. The reaction current distribution in battery electrode materials revealed by XPS-based state-of-charge mapping.

    Science.gov (United States)

    Pearse, Alexander J; Gillette, Eleanor; Lee, Sang Bok; Rubloff, Gary W

    2016-07-28

    Morphologically complex electrochemical systems such as composite or nanostructured lithium ion battery electrodes exhibit spatially inhomogeneous internal current distributions, particularly when driven at high total currents, due to resistances in the electrodes and electrolyte, distributions of diffusion path lengths, and nonlinear current-voltage characteristics. Measuring and controlling these distributions is interesting from both an engineering standpoint, as nonhomogenous currents lead to lower utilization of electrode material, as well as from a fundamental standpoint, as comparisons between theory and experiment are relatively scarce. Here we describe a new approach using a deliberately simple model battery electrode to examine the current distribution in a electrode material limited by poor electronic conductivity. We utilize quantitative spatially resolved X-ray photoelectron spectroscopy to measure the spatial distribution of the state-of-charge of a V2O5 model electrode as a proxy measure for the current distribution on electrodes discharged at varying current densities. We show that the current at the electrode-electrolyte interface falls off with distance from the current collector, and that the current distribution is a strong function of total current. We compare the observed distributions with a simple analytical model which reproduces the dependence of the distribution on total current, but fails to predict the correct length scale. A more complete numerical simulation suggests that dynamic changes in the electronic conductivity of the V2O5 concurrent with lithium insertion may contribute to the differences between theory and experiment. Our observations should help inform design criteria for future electrode architectures. PMID:27357533

  10. Explicit formulae for the internal stress in spherical particles of active material within lithium ion battery cathodes during charging and discharging

    International Nuclear Information System (INIS)

    Highlights: • Closed form expression proposed for Li ion concentration in a spherical particle. • This solution for fast (dis)charging depends explicitly on time and radius. • Explicit internal stress solution derived further is useful in design calculations. - Abstract: The fundamental process underlying the operation of lithium ion batteries is the diffusion of charge-carrying ions through the electrolyte that separates the anode from the cathode, and the reversible insertion of lithium ions into the host material’s crystal structure (intercalation and de-intercalation). Alongside the principal electrochemical consequences of this process, mechanical phenomena that accompany (de)intercalation are of fundamental significance for deformation and fragmentation of the active materials, since it is these phenomena that ultimately determine the battery structural integrity and durability. This article presents a sequentially coupled analytical treatment of the transient diffusion and stress analysis (eigenstrain) problem related to the lithiation and de-lithiation processes at the level of an individual spherical secondary particle of active material. Explicit closed form approximate solutions are derived for the stresses that arise within the particles during fast charging. They provide a firm basis for the assessment of the charging conditions influence on the internal stress states and the effects on battery damage, mechanical integrity and durability

  11. Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy

    OpenAIRE

    Gorlin, Y.; Patel, M.U.M.; Freiberg, A; He, Q.; Piana, M.; Tromp, M.; Gasteiger, H.A.

    2016-01-01

    Replacement of conventional cars with battery electric vehicles (BEVs) offers an opportunity to significantly reduce future carbon dioxide emissions. One possible way to facilitate widespread acceptance of BEVs is to replace the lithium-ion batteries used in existing BEVs with a lithium-sulfur battery, which operates using a cheap and abundant raw material with a high specific energy density. These significant theoretical advantages of lithium-sulfur batteries over the lithium-ion technology ...

  12. Effect of prestress on the stability of electrode-electrolyte interfaces during charging in lithium batteries

    Science.gov (United States)

    Natsiavas, P. P.; Weinberg, K.; Rosato, D.; Ortiz, M.

    2016-10-01

    We formulate a model of the growth of electrode-electrolyte interfaces in lithium batteries in the presence of an elastic prestress. The model accounts for the kinetics of Li+ transport through a solid electrolyte and, within the interface, for the kinetics of Li+ adsorption by the anode, electrostatics, and the elastic field. We specifically account for the effect of the elastic field through an asymptotic analysis of a nearly flat interface between two semi-infinite elastic bodies. We use the model as a basis for assessing the effect of prestress on the stability of planar growth and the potential of prestress as a means of suppressing the formation of deleterious dendrites. We present a linear stability analysis that results in explicit analytical expressions for the dependence of growth rates, and of the critical unstable wavelength for the interfacial roughening, on the state of prestress and on fundamental parameters such as surface diffusivities, surface energy, deposition kinetics, and elastic moduli. Finally, we examine the model in the light of experimental observations concerned with the effect of applied pressure on a lithium/dioxolane-dimethoxy ethane electrolyte systems. With reasonable choices of parameters and some calibration, the model accounts for the observation that a modest applied pressure indeed results in a substantial reduction in the roughening of the lithium surface during cycling.

  13. A method for state-of-charge estimation of LiFePO4 batteries based on a dual-circuit state observer

    Science.gov (United States)

    Tang, Xiaopeng; Wang, Yujie; Chen, Zonghai

    2015-11-01

    Estimation of state-of-charge (SOC) is a key criterion to evaluate the battery management system (BMS). Due to the flat open-circuit voltage (OCV)-SOC curve of LiFePO4 batteries, it is a great challenge to estimate the SOC accurately. Here we present a dual-circuit state observer for SOC estimation of LiFePO4 batteries. It is a combination of an open loop based current integrator and a proportional-integral (PI) based state observer. We also employed an easy but practical drifting current corrector to restrain the influence of the drifting current. The experiment results show that error of the estimated SOC is less than 2.5% by the proposed method when the initial SOC is unknown. We proved that with no matrix operations, the proposed method is lighted-weighted and high efficient, which is suitable for embedded systems.

  14. Estimation method of state-of-charge for lithium-ion battery used in hybrid electric vehicles based on variable structure extended kalman filter

    Science.gov (United States)

    Sun, Yong; Ma, Zilin; Tang, Gongyou; Chen, Zheng; Zhang, Nong

    2016-03-01

    Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery, the predicted performance of power battery, especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV. However, the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected. A variable structure extended kalman filter(VSEKF)-based estimation method, which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition, is presented. First, the general lower-order battery equivalent circuit model(GLM), which includes column accumulation model, open circuit voltage model and the SOC output model, is established, and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data. Next, a VSEKF estimation method of SOC, which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method, is executed with different adaptive weighting coefficients, which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes. According to the experimental analysis, the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV. The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method. In Summary, the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system, which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method. The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.

  15. Estimation Method of State-of-Charge For Lithium-ion Battery Used in Hybrid Electric Vehicles Based on Variable Structure Extended Kalman Filter

    Institute of Scientific and Technical Information of China (English)

    SUN Yong; MA Zilin; TANG Gongyou; CHEN Zheng; ZHANG Nong

    2016-01-01

    Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery, the predicted performance of power battery, especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV. However, the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected. A variable structure extended kalman filter(VSEKF)-based estimation method, which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition, is presented. First, the general lower-order battery equivalent circuit model(GLM), which includes column accumulation model, open circuit voltage model and the SOC output model, is established, and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data. Next, a VSEKF estimation method of SOC, which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method, is executed with different adaptive weighting coefficients, which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes. According to the experimental analysis, the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV. The error rate of SOC estimation with the VSEKF method is focused in the range of 5%to 10%comparing with the range of 20%to 30%using the EKF method and the Ah integration method. In Summary, the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system, which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method. The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.

  16. Estimation method of state-of-charge for lithium-ion battery used in hybrid electric vehicles based on variable structure extended kalman filter

    Science.gov (United States)

    Sun, Yong; Ma, Zilin; Tang, Gongyou; Chen, Zheng; Zhang, Nong

    2016-07-01

    Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery, the predicted performance of power battery, especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV. However, the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected. A variable structure extended kalman filter(VSEKF)-based estimation method, which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition, is presented. First, the general lower-order battery equivalent circuit model(GLM), which includes column accumulation model, open circuit voltage model and the SOC output model, is established, and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data. Next, a VSEKF estimation method of SOC, which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method, is executed with different adaptive weighting coefficients, which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes. According to the experimental analysis, the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV. The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method. In Summary, the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system, which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method. The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.

  17. Characterisation of charge and discharge behaviour of lithium ion batteries with olivine based cathode active material

    Energy Technology Data Exchange (ETDEWEB)

    Roscher, Michael A.; Sauer, Dirk Uwe [RWTH Aachen University, Electrochemical Energy Conversion and Storage Systems Group, Institute for Power Electronics and Electrical Drives (ISEA), 52066 Aachen (Germany); Vetter, Jens [BMW Group, 80788 Muenchen (Germany)

    2009-06-15

    This paper gives insight to the physical processes taking part during the two-phase transition in lithium intercalation compounds. The behaviour of olivine based electrodes is in the special focus of this work. These electrodes exhibit phase juxtaposition within the electrode particles over a wide state of charge (SOC) range. Measurements were made to explore effects related to the formation of distinct phase sequences within the particles. Asymmetric charge characteristics, a load history dependency of the internal resistance and a voltage effect related to the disappearance of certain phase regions (the later on called vanishing phase effect) were identified. Moreover, these measurements give evidence to the existence of stable phase regions inside the electrode active material. An intuitive model is given to visualize the phase regions within spherical olivine particles. Therefore an analytical approach is developed in order to take the geometry of the particles, the ion permeability as well as the size distribution of the particles in consideration. According to the developed approach and the obtained measurement results, an enhanced cell equivalent electrical circuit is evaluated, considering phase shell development effects. (author)

  18. Effects of state of charge on the degradation of LiFePO{sub 4}/graphite batteries during accelerated storage test

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Yong [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); He, Yan-Bing; Qian, Kun [Engineering Laboratory for Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Li, Baohua, E-mail: libh@mail.sz.tsinghua.edu.cn [Engineering Laboratory for Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Wang, Xindong [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Li, Jianling, E-mail: lijianling@ustb.edu.cn [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Miao, Cui; Kang, Feiyu [Engineering Laboratory for Next Generation Power and Energy Storage Batteries, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China)

    2015-08-05

    Highlights: • Degradation of LiFePO{sub 4}/graphite batteries under different state of charge at 55 °C is investigate. • Side reactions caused by self-discharge are the main reason for performance fade during storage. • The detailed degradation mechanism is proven by post-mortem analysis. • Increased electrode resistance in LiFePO{sub 4} cathode suggests that side reactions also happen at positive electrode. - Abstract: In this paper, the degradation of LiFePO{sub 4}/graphite batteries during 10 months of storage under different temperatures and states of charge (SOCs) is studied. The effects of SOC during storage process are systematically investigated using electrochemical methods and post-mortem analysis. The results show that at elevated temperature of 55 °C, higher stored SOC results in more significant increase in bulk resistance (R{sub b}) and charge-transfer resistance (R{sub ct}) of full battery, whereas the rate-discharge capability of stored battery is unchanged. The side reactions at the electrode/electrolyte interface caused by self-discharge are the main reasons for the performance fading during storage. For LiFePO{sub 4} cathode, long-time storage does not influence the framework structure under various SOCs. The existence of little irreversible capacity loss and impedance increase indicates that side reactions also occur at the positive electrode. For graphite anode, only a little capacity loss is found upon storage. There is a significant increase in impedance and a small amount of Fe deposition on graphite anode after storage at 100% SOC and 55 °C. The lithium ion loss arises from side reactions taking place at the graphite anode, which is responsible for the capacity degradation of battery during the storage process. XPS analysis confirms that a deposit layer composed of Li{sub 2}CO{sub 3} and LiF is formed on the surface of anode.

  19. A data-driven adaptive state of charge and power capability joint estimator of lithium-ion polymer battery used in electric vehicles

    International Nuclear Information System (INIS)

    An accurate SoC (state of charge) and SoP (state of power capability) joint estimator is the most significant techniques for electric vehicles. This paper makes two contributions to the existing literature. (1) A data-driven parameter identification method has been proposed for accurately capturing the real-time characteristic of the battery through the recursive least square algorithm, where the parameter of the battery model is updated with the real-time measurements of battery current and voltage at each sampling interval. (2) An adaptive extended Kalman filter algorithm based multi-state joint estimator has been developed in accordance with the relationship of the battery SoC and its power capability. Note that the SoC and SoP can be predicted accurately against the degradation and various operating environments of the battery through the data-driven parameter identification method. The robustness of the proposed data-driven joint estimator has been verified by different degradation states of lithium-ion polymer battery cells. The result indicates that the estimation errors of voltage and SoC are less than 1% even if given a large erroneous initial state of joint estimator, which makes the SoP estimate more accurate and reliable for the electric vehicles application. - Highlights: • A data-driven parameter identification method is developed by RLS algorithm. • An adaptive multi-state joint estimator of the battery is developed by AEKF algorithm. • A data-driven SoC and SoP joint estimator is developed with the real-time measurement. • Robustness of the joint estimator is verified by different aging states of LiPB cells

  20. Online Estimation of Model Parameters and State of Charge of LiFePO4 Batteries Using a Novel Open-Circuit Voltage at Various Ambient Temperatures

    Directory of Open Access Journals (Sweden)

    Fei Feng

    2015-04-01

    Full Text Available This study describes an online estimation of the model parameters and state of charge (SOC of lithium iron phosphate batteries in electric vehicles. A widely used SOC estimator is based on the dynamic battery model with predeterminate parameters. However, model parameter variances that follow with their varied operation temperatures can result in errors in estimating battery SOC. To address this problem, a battery online parameter estimator is presented based on an equivalent circuit model using an adaptive joint extended Kalman filter algorithm. Simulations based on actual data are established to verify accuracy and stability in the regression of model parameters. Experiments are also performed to prove that the proposed estimator exhibits good reliability and adaptability under different loading profiles with various temperatures. In addition, open-circuit voltage (OCV is used to estimate SOC in the proposed algorithm. However, the OCV based on the proposed online identification includes a part of concentration polarization and hysteresis, which is defined as parametric identification-based OCV (OCVPI. Considering the temperature factor, a novel OCV–SOC relationship map is established by using OCVPI under various temperatures. Finally, a validating experiment is conducted based on the consecutive loading profiles. Results indicate that our method is effective and adaptable when a battery operates at different ambient temperatures.

  1. State of charge estimation of Li-ion batteries in an electric vehicle based on a radial-basis-function neural network

    Institute of Scientific and Technical Information of China (English)

    Bi Jun; Shao Sai; Guan Wei; Wang Lu

    2012-01-01

    The on-line estimation of the state of charge (SOC) of the batteries is important for the reliable running of the pure electric vehicle in practice.Because a nonlinear feature exists in the batteries and the radial-basis-function neural network (RBF NN) has good characteristics to solve the nonlinear problem,a practical method for the SOC estimation of batteries based on the RBF NN with a small number of input variables and a simplified structure is proposed.Firstly,in this paper,the model of on-line SOC estimation with the RBF NN is set.Secondly,four important factors for estimating the SOC are confirmed based on the contribution analysis method,which simplifies the input variables of the RBF NN and enhances the real-time performance of estimation.Finally,the pure electric buses with LiFePO4Li-ion batteries running during the period of the 2010 Shanghai World Expo are considered as the experimental object.The performance of the SOC estimation is validated and evaluated by the battery data from the electric vehicle.

  2. Challenges and requirements of charge state monitoring of lithium ion batteries; Anforderungen und Herausforderungen bei der Zustandsbestimmung von Lithium-Ionen Batterien

    Energy Technology Data Exchange (ETDEWEB)

    Sauer, Dirk Uwe; Gerschler, Jochen B.; Sinhuber, Philipp [RWTH Aachen (Germany). ISEA

    2010-07-01

    Lithium-Ion batteries are a keystone for electro mobility concepts. Energy and power density as well as cycle lifetimes are superior to all other currently commercially available rechargeable battery technologies. However, generalised statements are difficult because of a large variety of different electrode materials and electrolyte which are used in commercial products. A special feature of all materials is the fact, that no standard side reaction is available which can take up surplus charging current without destroying the battery cell. If a cell is overcharged, the surplus current goes right away into an ageing process and may result in a disintegration of the electrode materials and finally in a thermal runaway of the cells. The huge variety in material combinations as well as the missing side reaction have a strong impact on the determination of the state of function. Algorithms and concepts need to be adapted in every single case to the specific properties of the used materials. Further more, the performance of the battery system is determined by the weakest cell in the battery system. Therefore supervision and an analysis of each cell are necessary. (orig.)

  3. Study on Charging Load Modeling and Coordinated Charging of Electric Vehicles Under Battery Swapping Modes%换电模式下电动汽车电池充电负荷建模与有序充电研究

    Institute of Scientific and Technical Information of China (English)

    罗卓伟; 胡泽春; 宋永华; 徐智威; 贾龙

    2012-01-01

    为了建立换电模式下电动汽车电池充电负荷及优化模型,对2种电动汽车换电模式即充换电模式和集中充电统一配送模式的结构、运营流程进行了分析.在满足用户换电需求的约束下,基于分时电价机制,提出考虑2种换电方式的以总充电费用最小为目标的第1阶段优化模型.第2阶段优化以第1阶段求取的最小充电费用为总充电费用的上限,以日负荷曲线波动最小为目标.以中国2020年充电负荷为例进行计算,对不同类型电动汽车采用不同的换电方式,并将换电模式与充电模式的充电负荷进行比较.计算结果表明,换电模式下无序充电情景峰荷较充电模式时增加较小,有序充电情景电网峰荷将不会增加,所提出的换电模式下有序充电模型能够有效减少充电费用及日负荷曲线波动.%To build the charging load calculation and optimization model under the battery swapping modes of electric vehicles (Evs), the structure and operation of two kinds of battery swapping modes, I.e. charging-swapping modes and centralized charging unified distribution modes, were analyzed. Then taken the constrains of satisfying the battery swapping needs of customers, the first stage coordinated charging formulation considering both the battery swap modes to minimize charging cost based on the time of use (TOU) power price mechanism were proposed. The peak load obtained from the first stage were set as the upper bound of the second stage optimization. In the second stage, the objective is to smooth the daily load curve fluctuation. Case studies calculate the charging loads of Evs in the year of 2020 in China, different kinds of battery swapping modes were matched for different kinds of Evs. The results were compared with those of the plug-in charging mode. The calculation results show that, the peak load under battery swapping modes increases less than the plug-in modes in the uncoordinated charging scenario

  4. Optimal Conditions for Fast Charging and Long Cycling Stability of Silicon Microwire Anodes for Lithium Ion Batteries, and Comparison with the Performance of Other Si Anode Concepts

    OpenAIRE

    Enrique Quiroga-González; Jürgen Carstensen; Helmut Föll

    2013-01-01

    Cycling tests under various conditions have been performed for lithium ion battery anodes made from free-standing silicon microwires embedded at one end in a copper current collector. Optimum charging/discharging conditions have been found for which the anode shows negligible fading (< 0.001%) over 80 cycles; an outstanding result for this kind of anodes. Several performance parameters of the anode have been compared to the ones of other Si anode concepts, showing that especially the capacity...

  5. Alkaline battery operational methodology

    Energy Technology Data Exchange (ETDEWEB)

    Sholklapper, Tal; Gallaway, Joshua; Steingart, Daniel; Ingale, Nilesh; Nyce, Michael

    2016-08-16

    Methods of using specific operational charge and discharge parameters to extend the life of alkaline batteries are disclosed. The methods can be used with any commercial primary or secondary alkaline battery, as well as with newer alkaline battery designs, including batteries with flowing electrolyte. The methods include cycling batteries within a narrow operating voltage window, with minimum and maximum cut-off voltages that are set based on battery characteristics and environmental conditions. The narrow voltage window decreases available capacity but allows the batteries to be cycled for hundreds or thousands of times.

  6. Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy

    OpenAIRE

    Liu, Xiaosong; Wang, Dongdong; Liu, Gao; Srinivasan, Venkat; Liu, Zhi; Hussain, Zahid; Yang, Wanli

    2013-01-01

    Developing high-performance batteries relies on material breakthroughs. During the past few years, various in situ characterization tools have been developed and have become indispensible in studying and the eventual optimization of battery materials. However, soft X-ray spectroscopy, one of the most sensitive probes of electronic states, has been mainly limited to ex situ experiments for battery research. Here we achieve in situ and operando soft X-ray absorption spectroscopy of lithium-ion ...

  7. Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy

    NARCIS (Netherlands)

    Y. Gorlin; M.U.M. Patel; A. Freiberg; Q. He; M. Piana; M. Tromp; H.A. Gasteiger

    2016-01-01

    Replacement of conventional cars with battery electric vehicles (BEVs) offers an opportunity to significantly reduce future carbon dioxide emissions. One possible way to facilitate widespread acceptance of BEVs is to replace the lithium-ion batteries used in existing BEVs with a lithium-sulfur batte

  8. Research on Shift Gating Equalization Charging System for Power Battery Pack%动力电池组移位选通均衡充电方案设计

    Institute of Scientific and Technical Information of China (English)

    陈曦; 何志杰

    2015-01-01

    This paper presents a shift gating equalization charging system for power battery pack. Each cell is equipped with a gating charging module in this system. In order to make an equalization charging for power battery pack, battery management system control gating charging module,increasing the charging current of the battery which is charging slowly,accelerating the charging speed. Gating charging module using the shift gating control mode, this control circuit structure is simple and easy to expand. Experiments show that using this system, when charging is completed the battery terminal voltage difference is only 50mV and no overcharging, the power battery pack achieving an equalization charging purposes.%提出了一种动力电池组移位选通均衡充电系统,该系统为每节电池配备一个选通充电模块。电池管理系统通过控制选通充电模块,增大充电慢的电池的充电电流,加快其充电速度,实现动力电池组的均衡充电。选通充电模块采用移位选通的控制方式,使控制电路结构简单,便于扩展。实验表明,采用该系统,充电结束时电池端电压仅相差50 mV且没有过充电,达到电池组均衡充电的目的。

  9. Online Identification with Reliability Criterion and State of Charge Estimation Based on a Fuzzy Adaptive Extended Kalman Filter for Lithium-Ion Batteries

    Directory of Open Access Journals (Sweden)

    Zhongwei Deng

    2016-06-01

    Full Text Available In the field of state of charge (SOC estimation, the Kalman filter has been widely used for many years, although its performance strongly depends on the accuracy of the battery model as well as the noise covariance. The Kalman gain determines the confidence coefficient of the battery model by adjusting the weight of open circuit voltage (OCV correction, and has a strong correlation with the measurement noise covariance (R. In this paper, the online identification method is applied to acquire the real model parameters under different operation conditions. A criterion based on the OCV error is proposed to evaluate the reliability of online parameters. Besides, the equivalent circuit model produces an intrinsic model error which is dependent on the load current, and the property that a high battery current or a large current change induces a large model error can be observed. Based on the above prior knowledge, a fuzzy model is established to compensate the model error through updating R. Combining the positive strategy (i.e., online identification and negative strategy (i.e., fuzzy model, a more reliable and robust SOC estimation algorithm is proposed. The experiment results verify the proposed reliability criterion and SOC estimation method under various conditions for LiFePO4 batteries.

  10. Online state of charge and model parameters estimation of the LiFePO4 battery in electric vehicles using multiple adaptive forgetting factors recursive least-squares

    Science.gov (United States)

    Duong, Van-Huan; Bastawrous, Hany Ayad; Lim, KaiChin; See, Khay Wai; Zhang, Peng; Dou, Shi Xue

    2015-11-01

    This paper deals with the contradiction between simplicity and accuracy of the LiFePO4 battery states estimation in the electric vehicles (EVs) battery management system (BMS). State of charge (SOC) and state of health (SOH) are normally obtained from estimating the open circuit voltage (OCV) and the internal resistance of the equivalent electrical circuit model of the battery, respectively. The difficulties of the parameters estimation arise from their complicated variations and different dynamics which require sophisticated algorithms to simultaneously estimate multiple parameters. This, however, demands heavy computation resources. In this paper, we propose a novel technique which employs a simplified model and multiple adaptive forgetting factors recursive least-squares (MAFF-RLS) estimation to provide capability to accurately capture the real-time variations and the different dynamics of the parameters whilst the simplicity in computation is still retained. The validity of the proposed method is verified through two standard driving cycles, namely Urban Dynamometer Driving Schedule and the New European Driving Cycle. The proposed method yields experimental results that not only estimated the SOC with an absolute error of less than 2.8% but also characterized the battery model parameters accurately.

  11. On the complex ageing characteristics of high-power LiFePO4/graphite battery cells cycled with high charge and discharge currents

    DEFF Research Database (Denmark)

    Groot, Jens; Swierczynski, Maciej Jozef; Stroe, Ana-Irina;

    2015-01-01

    Li-ion batteries are known to undergo complex ageing processes, where the operating conditions have a profound and non-linear effect on both calendar life and cycle life. This is especially a challenge for the automotive industry, where the requirements on product lifetime and reliability...... are demanding. The aim of the present work is to quantify the ageing in terms of capacity fade and impedance growth as a function of operating conditions typical to high-power automotive applications; high charge and discharge rate, elevated temperatures and wide state-of-charge windows. The cycle life of 34...... power-optimised LiFePO4/graphite cells was quantified by testing with charge and discharge rates between 1 and 4C-rate, temperatures between +23o C and +53o C, and a depth-of-discharge of either 100% or 60%. Although all cells show similar ageing pattern in general, the cycle life...

  12. Research of multi-stage charging method for on-board lithium battery of electric vehicles%电动汽车车载锂电池分段充电策略研究

    Institute of Scientific and Technical Information of China (English)

    陈超; 谢瑞; 何湘宁

    2011-01-01

    为了实现电动汽车(EV)车载锂电池快速充、放电,研究了电动汽车锂电池分段充电策略,给出了充电拓扑图.通过监控电池端电压和电流,采用了恒流、恒压和涓流3种充电方式结合的方法,控制功率变换器对电池进行智能充电.实验结果表明,利用分段充电方法可以在30 min内使电池端压达到额定值,并通过恒压充电使电池迅速得以充满.该研究为提高车载电池充电效率、缩短充电时间和保证充电安全奠定了基础.%In order to achieve the fast charging and discharging of the on-board lithium battery of electric vehicles (EV), the multi-stage charging method of the EV lithium battery was investigated and the charging circuit topology was presented. The method combined three charging methods ( constant-current method, constant-voltage method and low-current method) was used to control a power converter by monitoring the battery voltage and current for intelligent fast charging. The experimental results indicate that the battery voltage can reach the rated value in 30 minutes as being charged by the system, then the battery will soon be fully charged by using the constant-voltage method. The research lays the foundation for the improvement of the charging efficiency and the charging security of the on-board batteries.

  13. Comparisons of Modeling and State of Charge Estimation for Lithium-Ion Battery Based on Fractional Order and Integral Order Methods

    Directory of Open Access Journals (Sweden)

    Renxin Xiao

    2016-03-01

    Full Text Available In order to properly manage lithium-ion batteries of electric vehicles (EVs, it is essential to build the battery model and estimate the state of charge (SOC. In this paper, the fractional order forms of Thevenin and partnership for a new generation of vehicles (PNGV models are built, of which the model parameters including the fractional orders and the corresponding resistance and capacitance values are simultaneously identified based on genetic algorithm (GA. The relationships between different model parameters and SOC are established and analyzed. The calculation precisions of the fractional order model (FOM and integral order model (IOM are validated and compared under hybrid test cycles. Finally, extended Kalman filter (EKF is employed to estimate the SOC based on different models. The results prove that the FOMs can simulate the output voltage more accurately and the fractional order EKF (FOEKF can estimate the SOC more precisely under dynamic conditions.

  14. Online model-based estimation of state-of-charge and open-circuit voltage of lithium-ion batteries in electric vehicles

    International Nuclear Information System (INIS)

    This paper presents a method to estimate the state-of-charge (SOC) of a lithium-ion battery, based on an online identification of its open-circuit voltage (OCV), according to the battery’s intrinsic relationship between the SOC and the OCV for application in electric vehicles. Firstly an equivalent circuit model with n RC networks is employed modeling the polarization characteristic and the dynamic behavior of the lithium-ion battery, the corresponding equations are built to describe its electric behavior and a recursive function is deduced for the online identification of the OCV, which is implemented by a recursive least squares (RLS) algorithm with an optimal forgetting factor. The models with different RC networks are evaluated based on the terminal voltage comparisons between the model-based simulation and the experiment. Then the OCV-SOC lookup table is built based on the experimental data performed by a linear interpolation of the battery voltages at the same SOC during two consecutive discharge and charge cycles. Finally a verifying experiment is carried out based on nine Urban Dynamometer Driving Schedules. It indicates that the proposed method can ensure an acceptable accuracy of SOC estimation for online application with a maximum error being less than 5.0%. -- Highlights: ► An equivalent circuit model with n RC networks is built for lithium-ion batteries. ► A recursive function is deduced for the online estimation of the model parameters like OCV and RO. ► The relationship between SOC and OCV is built with a linear interpolation method by experiments. ► The experiments show the online model-based SOC estimation is reasonable with enough accuracy.

  15. Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications

    OpenAIRE

    Prada, Eric; Di Domenico, D.; Creff, Yann; Bernard, J; Sauvant-Moynot, Valérie; Huet, François

    2012-01-01

    Derived from the Pseudo Two-Dimensional mathematical structure, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed in this paper. Embedding the porous electrode theory, this model integrates the main design parameters of Li-ion systems and its partial differential equations mathematical structure makes it a promising candidate for battery management system (BMS) applications and comprehensive aging investigations. Based on a modified Single-...

  16. 钒液流电池建模及充放电效率分析%Vanadium redox flow battery modeling and charge-discharge efficiency analysis

    Institute of Scientific and Technical Information of China (English)

    沈洁; 李广凯; 侯耀飞; 滕松; 贾超

    2013-01-01

    The energy storage plays an important role in wind power systems and solar photovoltaic power generation system.As a new energy storage battery,the vanadium redox flow battery (VRB)'s advantages and successful example demonstrate its broad prospects in storage marker.The operating principle of VRB was introduced.Through studying stack voltage,state of charge,intemal loss and dynamic response,VRB simulation model was set up.The constant current mode for VRB was studied in detail.At the end,the factors which influenced the charging and discharging efficiency of battery energy storage were analyzed qualitatively and quantitatively.What's more,the optimal charging-discharging current was obtained.%储能系统是风力发电系统和太阳能光伏发电系统的重要组成部分,钒液流电池(VRB)作为一种新型储能电池,其优势及成功范例充分展示了它在储能市场的广阔前景.介绍了钒液流电池的工作原理,通过研究VRB的堆栈电压、荷电状态SOC、内部损耗和动态响应,构建了VRB仿真系统模型.详细研究了VRB恒电流充放电模式,定性、定量地分析了影响钒液流电池储能充放电效率的因素,并得出了最优充电电流.

  17. JPL's electric and hybrid vehicles project: Project activities and preliminary test results. [power conditioning and battery charge efficiency

    Science.gov (United States)

    Barber, T. A.

    1980-01-01

    Efforts to achieve a 100 mile urban range, to reduce petroleum usage 40% to 70%, and to commercialize battery technology are discussed with emphasis on an all plastic body, four passenger car that is flywheel assisted and battery powered, and on an all metal body, four passenger car with front wheel drive and front motor. For the near term case, a parallel hybrid in which the electric motor and the internal combustion engine may directly power the drive wheels, is preferred to a series design. A five passenger car in which the electric motor and the gasoline engine both feed into the same transmission is discussed. Upgraded demonstration vehicles were tested using advanced lead acid, nickel zinc, nickel iron, and zinc chloride batteries to determine maximum acceleration, constant speed, and battery behavior. The near term batteries demonstrated significant improvement relative to current lead acid batteries. The increase in range was due to improved energy density, and ampere hour capacity, with relatively 1 small weight and volume differences.

  18. A Study of Fuel Economy Improvement in a Plug-in Hybrid Electric Vehicle using Engine on/off and Battery Charging Power Control Based on Driver Characteristics

    OpenAIRE

    Seulgi Lee; Jingyu Choi; Kiyun Jeong; Hyunsoo Kim

    2015-01-01

    In this study, driving data for various types of drivers are collected using a VIDE (virtual integrated driving environment), and a driver model is developed. To represent the driver tendencies quantitatively, the DDA (degree of driver aggression) is proposed based on fuzzy logic. DDA has a 0-1 value; the closer the DDA is to one, the more aggressive the driver. Using the DDA, an engine on/off and battery charging power control algorithm are developed to improve the fuel economy of a power-s...

  19. 镍氢电容电池快速充电系统%The quick charge system of Ni-MH capacitor battery

    Institute of Scientific and Technical Information of China (English)

    李家淦; 邹黎; 陈君霞

    2012-01-01

    To realize electric bus's quick charge,which choose Ni-MH capacitor battery as its power system in Zibo,the quick charge system was designed.Matlab/Simulink was used to measure the power grid harmonic content,and voltage controller method was selected as charging terminate parameters according to the Ni-MH capacitor battery's short-time large current charge characteristics.Eventually,the electric bus's quick charge through the field experiment was realized.%为实现以镍氢电容电池为动力系统的电动大巴车的快速充电设计了快速充电系统.通过Matlab/Simulink对网侧谐波含量进行电气仿真,并根据镍氢电容电池的短时大电流充电特性,选取电压控制法作为充电终止参数,实现电动大巴车的快速充电.

  20. Battery Cell Balancing System and Method

    Science.gov (United States)

    Davies, Francis J. (Inventor)

    2014-01-01

    A battery cell balancing system is operable to utilize a relatively small number of transformers interconnected with a battery having a plurality of battery cells to selectively charge the battery cells. Windings of the transformers are simultaneously driven with a plurality of waveforms whereupon selected battery cells or groups of cells are selected and charged. A transformer drive circuit is operable to selectively vary the waveforms to thereby vary a weighted voltage associated with each of the battery cells.

  1. Optimal Conditions for Fast Charging and Long Cycling Stability of Silicon Microwire Anodes for Lithium Ion Batteries, and Comparison with the Performance of Other Si Anode Concepts

    Directory of Open Access Journals (Sweden)

    Enrique Quiroga-González

    2013-10-01

    Full Text Available Cycling tests under various conditions have been performed for lithium ion battery anodes made from free-standing silicon microwires embedded at one end in a copper current collector. Optimum charging/discharging conditions have been found for which the anode shows negligible fading (< 0.001% over 80 cycles; an outstanding result for this kind of anodes. Several performance parameters of the anode have been compared to the ones of other Si anode concepts, showing that especially the capacity as well as the rates of charge flow per nominal area of anode are the highest for the present anode. With regard to applications, the specific parameters per area are more important than the specific gravimetric parameters like the gravimetric capacity, which is good for comparing the capacity between materials but not enough for comparing between anodes.

  2. 电动汽车充换电示范站中的有序充放电措施%Orderly Charge and Discharge Measures for the Battery Charging and Swapping Demonstration Stations

    Institute of Scientific and Technical Information of China (English)

    李红梅

    2013-01-01

    With the substantial increase in ownership of electric vehicles in the future, uncontrolled charge for the electric vehicles will have a significant impact on the power grid. The measures of orderly charge and discharge for the battery charging and swapping demonstration stations are introduced in Shandong province from such two aspects as vehicle to grid (V2G) system and the operations management system. In the V2G system, an intelligent bi-directional charge and discharge equipment is designed and the peak-valley price based control systems of charge and discharge and the station monitoring systems are developed. In the operations management system, the methods of battery echelon utilization and the life cycle management are proposed and the structures, working principles and technological means of both the metering and billing system and the fast battery switching system are introduced.%未来,随着电动汽车在数量上的增加,电动汽车的充电将对电网产生很大的影响.从车辆并网系统和有序充放电运营管理系统2个方面介绍了省级电动汽车充换电示范站中的有序充放电措施;在车辆并网系统方面,设计了双向智能充放电装置,探讨了基于峰谷电价的充放电控制系统和充换电监控系统;在运营管理方面,提出了电池梯次利用和全寿命周期管理方法,并阐述了有利于有序充放电的计量计费管理系统和电池快速更换系统的结构、原理和实现手段.

  3. Portable Battery Charger Berbasis Sel Surya

    Directory of Open Access Journals (Sweden)

    Budhi Anto

    2014-04-01

    Full Text Available A type of solar battery charger is introduced in this paper. This equipment functions as a medium size rechargeable battery that is needed to move culinary merchants and coastal fishermen living in area which is not supplied by electrical networks. The equipment consists of solar module mounted onto portable mechanical construction, a 12-V 7.5-Ah lead acid battery and charge controller. Solar module charges the battery through charge controller and then the battery can be discharged to power on electric lamps for lightening culinary wagon or fisherman’s boat at night. Charge controller charges the battery with float charging which is implemented by maintaining 13.5 Volt between battery terminals and limiting the charging current to 1.5 Amperes. Charge controller circuit is based on adjustable linear voltage regulator LM338. The battery is of sealed lead acid type. This type of battery is maintenance free and more hygiene than other types of lead acid battery. The field experiment of charging the baterry of 50% residual capacity from 8 am to 4 pm under sunny weather shows that the solar module has charged the battery to its full capacity under battery safe charging conditions.Keywords: portable solar battery charger, float charging, LM338

  4. 电动公交充换电站的优化运行研究%Research on Optimal Operation of Battery Swapping and Charging Station for Electric Buses

    Institute of Scientific and Technical Information of China (English)

    阳岳希; 胡泽春; 宋永华

    2012-01-01

    The optimal operation of battery swapping and charging station for electric bus involves many processes, such as bus service, battery swapping, battery charging, and so on. The daily battery swapping demand was quantitatively analyzed based on factors including the operating pattern and electricity consumption characteristics of electric buses. The optimal battery swapping order was determined for equal battery usage and charging convenience. A two-stage and a bi-objective mathematic optimization models for battery recharging with minimize charging cost as the primary objective were established, and the smoothing of the charging load curve was also considered. Other factors that have influences on optimal charging schedule such as the starting time, reserved battery number for uncertainties were analyzed. Case study results show that the proposed method can Feduce daily charging cost substantially and mitigate the impacts of charging load on the grid.%公交车充换电站的优化运行涉及公交运营、电池更换和电池充电等多个方面.考虑公交车的运行规律和耗电特性等因素,定量分析了车辆的日换电需求,并基于均衡使用电池和有利于电池充电的原则,推导了电池优化更换的顺序.以充电成本最小为首要目标,综合考虑平滑充电负荷曲线,分别建立了两阶段和双目标优化充电模型.对优化充电的起始时间、备用电池数量等因素对优化结果的影响进行了分析.算例仿真结果表明,该方法可有效降低充电成本和充电负荷对电网的影响.

  5. Microspheric Na2Ti3O7 consisting of tiny nanotubes: an anode material for sodium-ion batteries with ultrafast charge-discharge rates

    Science.gov (United States)

    Wang, Wei; Yu, Chengjun; Lin, Zheshuai; Hou, Jungang; Zhu, Hongmin; Jiao, Shuqiang

    2012-12-01

    Conventionally, rechargeable batteries with a fast charge-discharge rate, while being able to be implemented in large-scale applications with low prices, are critical for new energy storage systems. In this work, first-principles simulations were employed to theoretically investigate the insertion of sodium into the Na2Ti3O7 structure. The result discovered that the theoretical capacity of Na2Ti3O7 was 311 mA h g-1. Furthermore, a microspheric Na2Ti3O7 material consisting of tiny nanotubes of ca. 8 nm in outside diameter and a few hundred nanometers in length has been synthesized. The galvanostatic charge-discharge measurements, using the as-prepared Na2Ti3O7 nanotubes as a working electrode with a voltage range of 0.01-2.5 V vs. Na+/Na, disclosed that a high capacity was maintained even under an ultrafast charge-discharge rate. At a current density of 354 mA g-1, the discharge capacity was maintained at 108 mA h g-1 over 100 cycles. Even at a very large current density of 3540 mA g-1, the discharge capacity was still 85 mA h g-1. HRTEM analysis and electrochemical tests proved that sodium ions could not only intercalate into the Na2Ti3O7 crystal, but could also be stored in the intracavity of the nanotubes. All of the results disclose that the as-prepared Na2Ti3O7 nanotubes are able to be used as anode materials in large-scale applications for rechargeable sodium-ion batteries at low cost while maintaining excellent performance.

  6. Modeling and intelligent charge of storage batteries for wind energy electric vehicles%风能电动汽车储能电池的建模与智能充电

    Institute of Scientific and Technical Information of China (English)

    易芳; 易灵芝

    2012-01-01

    分析了锂电池的结构特点和非线性的数学模型以及充电形式,在Matlab/Simulink中建立了锂电池的非线性仿真模型,采用模糊控制跟踪最大可接受充电电流,通过仿真,验证了锂电池的非线性模型的正确性,在最大可接受充电电流下,锂电池的输出电压和荷电状态(SOC)值缓慢上升到期望值,实现了智能充电.%The structural features of lithium battery,intelligent charge model and its nonlinear mathematic model were researched,by means of Mattab/Simulink,a nonlinear model of lithium battery was established,and a fuzzy control was applied to track the maximum charging current.The Simulink results verified the correctness of the proposed nonlinear model of lithium battery.At the acceptable maximum charging current,the output voltage and state of charge (SOC) of the battery slowly rise to expectation,and the intelligent charging is achieved.

  7. Variation of stress with charging rate due to strain-rate sensitivity of silicon electrodes of Li-ion batteries

    OpenAIRE

    Pharr, Matt Mathews; Suo, Zhigang; Vlassak, Joost J.

    2014-01-01

    Silicon is a promising anode material for lithium-ion batteries due to its enormous theoretical energy density. Fracture during electrochemical cycling has limited the practical viability of silicon electrodes, but recent studies indicate that fracture can be prevented by taking advantage of lithiation-induced plasticity. In this paper, we provide experimental insight into the nature of plasticity in amorphous LixSi thin films. To do so, we vary the rate of lithiation of amorphous silicon thi...

  8. Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li-O2 battery charging.

    Science.gov (United States)

    Gittleson, Forrest S; Ryu, Won-Hee; Schwab, Mark; Tong, Xiao; Taylor, André D

    2016-05-01

    Rechargeable Li-O2 and Li-air batteries require electrode and electrolyte materials that synergistically promote long-term cell operation. In this study, we investigate the role of noble metals Pt and Pd as catalysts in the Li-O2 oxidation process and their compatibility with dimethyl sulfoxide (DMSO) based electrolytes. We identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products. PMID:27111589

  9. Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Xiang, Hongfa; Shi, Pengcheng; Bhattacharya, Priyanka; Chen, Xilin; Mei, Donghai; Bowden, Mark E.; Zheng, Jianming; Zhang, Jiguang; Xu, Wu

    2016-06-30

    Rechargeable lithium (Li) metal batteries with conventional LiPF6-carbonate electrolytes have been reported to fail quickly at charging current densities of about 1.0 mA cm-2 and above. In this work, we demonstrate the rapid charging capability of the Li||LiNi0.8Co0.15Al0.05O2 (NCA) cells enabled by a dual-salt electrolyte of LiTFSI-LiBOB in a carbonate solvent mixture. It is found that the thickness of solid electrolyte interphase (SEI) layer on Li metal anode largely increases with increasing charging current density. However, the cells using the LiTFSI-LiBOB dual-salt electrolyte significantly outperforms those using the LiPF6 electrolyte at high charging current densities. At the charging current density of 1.50 mA cm-2, the Li||NCA cells with the dual-salt electrolyte can still deliver a discharge capacity of 131 mAh g-1 and a capacity retention of 80% after 100 cycles, while those with the LiPF6 electrolyte start to show fast capacity fading after the 30th cycle and only exhibit a low capacity of 25 mAh g-1 and a low retention of 15% after 100 cycles. The reasons for the good chargeability and cycling stability of the cells using LiTFSI-LiBOB dual-salt electrolyte can be attributed to the good film-formation ability of the electrolyte on lithium metal anode and the highly conductive nature of the sulfur-rich interphase layer.

  10. Formation of Li3O4 nano particles in the discharge products of non-aqueous lithium-oxygen batteries leads to lower charge overvoltage.

    Science.gov (United States)

    Shi, L; Xu, A; Zhao, T S

    2015-11-28

    Density functional theory calculations are made for bulk thermodynamic properties and surface energies of Li2O2, a primary discharge product, and Li3O4, a possible byproduct in the discharge products, of the non-aqueous lithium-oxygen batteries. Results show that the standard formation Gibbs free energy of bulk Li3O4 is marginally higher than that of Li2O2, but the surface energy of Li3O4 is much lower. Low surface energy results in both lowered nucleation energy and formation Gibbs free energy in the nanometer regime, allowing the Li3O4 nano particles to nucleate ahead of Li2O2 during the discharge process and to exist stably when particle sizes are smaller than about 40 nm. The scanning transmission electron microscopy (STEM) image of Li3O4 crystals is simulated and compared with the measured STEM image of the discharge product particles. The consistency between the simulated and measured STEM images suggests that the Li3O4 phase can exist stably as a discharge product. The energy profile of the oxygen evolution reaction (OER) occurring on the most abundant surfaces of Li3O4 is also calculated. The predicted overpotential for the OER on the {0001} surface (0.30 V) shows a good agreement with experimental data. The presence of more electronically conductive Li3O4 nano particles in the primary discharge product Li2O2 tends to decrease the charge overvoltage of the batteries, explaining why the lower voltage area (oxygen pressure or a decrease in temperature enhances the stability of the Li3O4 phase and increase the proportion of the Li3O4 phase in the discharge products, consequently leading to a lower overall charge overvoltage. PMID:26486991

  11. Enhanced charging capability of lithium metal batteries based on lithium bis(trifluoromethanesulfonyl)imide-lithium bis(oxalato)borate dual-salt electrolytes

    Science.gov (United States)

    Xiang, Hongfa; Shi, Pengcheng; Bhattacharya, Priyanka; Chen, Xilin; Mei, Donghai; Bowden, Mark E.; Zheng, Jianming; Zhang, Ji-Guang; Xu, Wu

    2016-06-01

    Rechargeable lithium (Li) metal batteries with conventional LiPF6-carbonate electrolytes have been reported to fail quickly at charging current densities of about 1.0 mA cm-2 and above. In this work, we demonstrate the rapid charging capability of Li||LiNi0.8Co0.15Al0.05O2 (NCA) cells can be enabled by a dual-salt electrolyte of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium bis(oxalato)borate (LiBOB) in a carbonate solvent mixture. The cells using the LiTFSI-LiBOB dual-salt electrolyte significantly outperform those using the LiPF6 electrolyte at high charging current densities. At the charging current density of 1.50 mA cm-2, the Li||NCA cells with the dual-salt electrolyte can still deliver a discharge capacity of 131 mAh g-1 and a capacity retention of 80% after 100 cycles. The Li||NCA cells with the LiPF6 electrolyte start to show fast capacity fading after the 30th cycle and only exhibit a low capacity of 25 mAh g-1 and a low retention of 15% after 100 cycles. The reasons for the good chargeability and cycling stability of the cells using the LiTFSI-LiBOB dual-salt electrolyte can be attributed to the good film-formation ability of the electrolyte on the Li metal anode and the highly conductive nature of the sulfur-rich interphase layer.

  12. Multistep Charge Method by Charge Arrays

    Science.gov (United States)

    Segami, Go; Kusawake, Hiroaki; Shimizu, Yasuhiro; Iwasa, Minoru; Kibe, Koichi

    2008-09-01

    We studied reduction of the size and weight of the Power Control Unit (PCU). In this study, we specifically examined the weight of the Battery Charge Regulator (BCR), which accounts for half of the PCU weight for a low earth orbit (LEO) satellite. We found a multistep charge method by charge arrays and adopted a similar method for GEO satellites, thereby enabling the BCR reduction. We found the possibility of reducing the size and weight of PCU through more detailed design than that for a conventional PCU.BCRC1R1batterySAPower Control UnitBCRC1R1batterySAPower UnitHowever, this method decreases the state of charge (SOC) of the battery. Battery tests, a battery simulator test, and numerical analysis were used to evaluate the SOC decrease. We also studied effects of this method on the battery lifetime. The multistep charge method by charge arrays enabled charging to the same level of SOC as the conventional constant current/ constant voltage (CC/CV) charge method for a LEO satellite.

  13. Electric-vehicle batteries

    Science.gov (United States)

    Oman, Henry; Gross, Sid

    1995-02-01

    Electric vehicles that can't reach trolley wires need batteries. In the early 1900's electric cars disappeared when owners found that replacing the car's worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today's electric cars are still propelled by lead-acid batteries. General Motors in their prototype Impact, for example, used starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon's new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda traveled 260 km on a single charge of its zinc-bromine battery. A German 3.5-ton postal truck traveled 300 km with a single charge in its 650-kg (146 Wh/kg) zinc-air battery. Its top speed was 110 km per hour.

  14. A Phenomenological Model of Bulk Force in a Li-Ion Battery Pack and Its Application to State of Charge Estimation

    Energy Technology Data Exchange (ETDEWEB)

    Mohan, S; Kim, Y; Siegel, JB; Samad, NA; Stefanopoulou, AG

    2014-09-19

    A phenomenological model of the bulk force exerted by a lithium ion cell during various charge, discharge, and temperature operating conditions is developed. The measured and modeled force resembles the carbon expansion behavior associated with the phase changes during intercalation, as there are ranges of state of charge (SOC) with a gradual force increase and ranges of SOC with very small change in force. The model includes the influence of temperature on the observed force capturing the underlying thermal expansion phenomena. Moreover the model is capable of describing the changes in force during thermal transients, when internal battery heating due to high C-rates or rapid changes in the ambient temperature, which create a mismatch in the temperature of the cell and the holding fixture. It is finally shown that the bulk force model can be very useful for a more accurate and robust SOC estimation based on fusing information from voltage and force (or pressure) measurements. (C) The Author(s) 2014. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email oa@electrochem.org. All rights reserved.

  15. Measuring the state of charge of the electrolyte solution in a vanadium redox flow battery using a four-pole cell device

    Science.gov (United States)

    Ngamsai, Kittima; Arpornwichanop, Amornchai

    2015-12-01

    The decrease in the efficiency and capacity of a vanadium redox flow battery (VRB) caused by an electrolyte imbalance is an important impediment to its long-term operation. Knowing the state of charge (SOC) of an electrolyte solution can quantify the level of the electrolyte imbalance in the VRB. In this study, a four-pole cell device is devised and employed to predict the SOC. The proposed method directly measures the ionic resistance of the electrolyte solution and is sufficiently precise to be applied in real-time mode. Experimental studies on the effects of the operating current on the four-pole cell and the concentrations of vanadium and sulfuric acid in the electrolyte solution are carried out. The results show that the four-pole cell method can be utilized to measure the electrolyte SOC. The concentrations of vanadium and sulfuric acid in the electrolyte solution affect the ionic resistance of the solution. Regarding the capacity and efficiency of the VRB system, the results indicate that the electrical charge is determined from the concentration of vanadium and that the cell voltage depends on the concentration of sulfuric acid in the electrolyte solution. The decreased vanadium concentration and increased sulfuric acid concentration improves the cell voltage efficiency.

  16. Battery testing for photovoltaic applications

    Energy Technology Data Exchange (ETDEWEB)

    Hund, T.

    1996-11-01

    Battery testing for photovoltaic (PV) applications is funded at Sandia under the Department of Energy`s (DOE) Photovoltaic Balance of Systems (BOS) Program. The goal of the PV BOS program is to improve PV system component design, operation, reliability, and to reduce overall life-cycle costs. The Sandia battery testing program consists of: (1) PV battery and charge controller market survey, (2) battery performance and life-cycle testing, (3) PV charge controller development, and (4) system field testing. Test results from this work have identified market size and trends, PV battery test procedures, application guidelines, and needed hardware improvements.

  17. Design of acid-lead battery stage-of-charge detection system based on refractive index detection technology

    Science.gov (United States)

    Chen, Junyao; Yang, Kecheng; Xia, Min; Li, Lei; Zeng, Xianjiang

    2015-10-01

    Based on optical total reflection critical Angle method, we have designed a refractive index measurement system. It adopted a divergent light source and a CCD camera as the occurrence and receiver of the signal. The divergent light source sent out a bunch of tapered beam, exposure to the interface of optical medium and sulfuric acid solution. Light intensity reflected from the interface could be detected by the CCD camera and then sent to the embedded system. In the DSP embedded system, we could obtain the critical edge position through the light intensity distribution curve and converted it to critical angle. Through experiment, we concluded the relation between liquid refractive index and the critical angle edge position. In this system, the detecting precision of the refractive index of sulfuric acid solution reached 10-4. Finally, through the conversion of the refractive index and density, we achieved high accuracy online measurement of electrolyte density in lead-acid battery.

  18. 动力锂电池变电阻均衡充电方法研究%Research on Variable Resistance Equalizing Charge method of Power Lithium-ion Battery

    Institute of Scientific and Technical Information of China (English)

    徐磊; 何秋生; 孙志毅; 李晓云

    2014-01-01

    To solve the inconsistency of voltage between individual battery cells of electric car lithium-ion battery pack,a new variable resistance equalizing charge method is put forward in this paper. Firstly,the cause of the in-consistency voltage of inter-cell is analyzed;digital variable resistance and simulation model of variable resistor are designed. Secondly,lithium battery model and variable resistance module are designed. Finally, the equalization charge simulation is finished in Matlab/Simulink software. The value of equalization resistance is set according to the battery terminal voltage. The result shows that the voltage error between individual battery cells could be limited to less than 0. 3 mV,and the method may reduce effectively the inconsistency between individual battery cells and prolongs battery life.%针对动力锂电池组中单体电池之间电压不一致性,提出一种变电阻均衡充电方法。在分析了单体电池间电压不一致性的原因、设计数字可变电阻器和可变电阻仿真模型的基础上,采用Matlab/Simulink软件对可变电阻均衡充电进行仿真,根据电池端电压大小调节均衡电阻值。结果表明变电阻均衡控制可使电压误差控制在0.3 mV以内,有效的减小单体电池之间的不一致性、延长电池的使用寿命。

  19. A Comparative Study Based on the Least Square Parameter Identification Method for State of Charge Estimation of a LiFePO4 Battery Pack Using Three Model-Based Algorithms for Electric Vehicles

    Directory of Open Access Journals (Sweden)

    Taimoor Zahid

    2016-09-01

    Full Text Available Battery energy storage management for electric vehicles (EV and hybrid EV is the most critical and enabling technology since the dawn of electric vehicle commercialization. A battery system is a complex electrochemical phenomenon whose performance degrades with age and the existence of varying material design. Moreover, it is very tedious and computationally very complex to monitor and control the internal state of a battery’s electrochemical systems. For Thevenin battery model we established a state-space model which had the advantage of simplicity and could be easily implemented and then applied the least square method to identify the battery model parameters. However, accurate state of charge (SoC estimation of a battery, which depends not only on the battery model but also on highly accurate and efficient algorithms, is considered one of the most vital and critical issue for the energy management and power distribution control of EV. In this paper three different estimation methods, i.e., extended Kalman filter (EKF, particle filter (PF and unscented Kalman Filter (UKF, are presented to estimate the SoC of LiFePO4 batteries for an electric vehicle. Battery’s experimental data, current and voltage, are analyzed to identify the Thevenin equivalent model parameters. Using different open circuit voltages the SoC is estimated and compared with respect to the estimation accuracy and initialization error recovery. The experimental results showed that these online SoC estimation methods in combination with different open circuit voltage-state of charge (OCV-SoC curves can effectively limit the error, thus guaranteeing the accuracy and robustness.

  20. 焦炉顶装改捣固后工艺及焦炭质量对比%Comparison of the process and coke quality for modifying top charging coke oven battery to stamp charging

    Institute of Scientific and Technical Information of China (English)

    马力辉

    2015-01-01

    This paper introduces the change of process and coke quality after modifying the 4. 3m top charging coke oven battery to stamp charging. After the modification, the coke yield has almost remained same as before,while the coke strength at cold and hot conditions has increased,and the coke screening has been improved,the metallurgical coke rate could be increased by 2. 5%,coke nut yield has been reduced by 1. 5%,and coke breeze yield has been reduced by 0. 5%.%介绍了4.3m焦炉顶装改造为捣固生产后工艺和焦炭质量的变化,由顶装改造为捣固生产后,产量基本保持不变,焦炭的冷热态强度提高,焦炭筛分改善,冶金焦率可以提高2.5%,焦丁产率降低1.5%,焦末产率降低0.5%。

  1. Research on the Optimized 3-stage Charging Strategy for the Storage Battery in Stand-alone Photovoltaic System%独立光伏系统蓄电池优化三段式充电策略研究

    Institute of Scientific and Technical Information of China (English)

    蔡晓峰; 张鸿博; 黄伟; 赵慧光

    2012-01-01

    To improve the charging efficiency and the lifetime of the storage battery in the stand-alone photovoltaic system, the charging algorithm of storage battery is studied. In consideration of the photovoltaic system is easily to be impacted by the environment, and the power generated is unstable, the reason caused failure of implementing 3-stage charging by using PI algorithm is analyzed, thus the charging strategy combining maximum power point tracking (MPPT) and 3-stage charging is proposed. PI constant current, constant current charging and the switching criteria of MPPT charging are researched emphatically. The result of Matlab simulation verifies the correctness of the algorithm.%为了提高独立光伏系统蓄电池的充电效率和使用寿命,对蓄电池充电算法进行了研究.考虑到光伏系统受环境影响较大、发电功率不稳定等因素,分析了直接利用PI算法实现三段式充电失败的原因,提出了将最大功率点跟踪(MPPT)与三段式充电相结合的充电策略.重点研究了PI恒流、恒压充电与MPPT充电的切换判据.Matlab仿真结果证明了该算法的正确性.

  2. Battery control system for hybrid vehicle and method for controlling a hybrid vehicle battery

    Science.gov (United States)

    Bockelmann, Thomas R.; Hope, Mark E.; Zou, Zhanjiang; Kang, Xiaosong

    2009-02-10

    A battery control system for hybrid vehicle includes a hybrid powertrain battery, a vehicle accessory battery, and a prime mover driven generator adapted to charge the vehicle accessory battery. A detecting arrangement is configured to monitor the vehicle accessory battery's state of charge. A controller is configured to activate the prime mover to drive the generator and recharge the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a first predetermined level, or transfer electrical power from the hybrid powertrain battery to the vehicle accessory battery in response to the vehicle accessory battery's state of charge falling below a second predetermined level. The invention further includes a method for controlling a hybrid vehicle powertrain system.

  3. Performance Simulation Of Photovoltaic System Battery

    Directory of Open Access Journals (Sweden)

    O. A. Babatunde

    2014-09-01

    Full Text Available Solar energy, despite being inexhaustible, has a major shortcoming; it is intermittent. As a result, there's a need for it to be stored for later use. The widely used energy storage in photovoltaic system applications is the lead-acid battery and the knowledge of its state-of-charge (SOC is important in effecting efficient control and energy management. However, SOC cannot be measured while the battery is connected to the system. This study adjusts and validates two estimation models: battery state-of-charge model using ampere-hour counting method and battery charge voltage model. For the battery state-of-charge model, the SOC is estimated by integrating the charge/discharge current over time while the battery charge voltage characteristic response is modelled by using the equation-fit method which expresses the battery charge voltage variations by a 5th order polynomial in terms of the state-of-charge and current. These models are realized using the MATLAB program. The battery charge voltage model is corrected for errors which may result from reduced charge voltage due to variation of solar radiation using the battery state-of-charge model. Moreover, the starting SOC needed in the state-of-charge model is estimated using the charge voltage model. The accuracies of the models are verified using various laboratory experiments.

  4. 46 CFR 169.668 - Batteries.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Batteries. 169.668 Section 169.668 Shipping COAST GUARD... § 169.668 Batteries. (a) Each battery must be in a location that allows the gas generated in charging to... this section, a battery must not be located in the same compartment with a gasoline tank or...

  5. Atomic Batteries: Energy from Radioactivity

    OpenAIRE

    Kumar, Suhas

    2015-01-01

    With alternate, sustainable, natural sources of energy being sought after, there is new interest in energy from radioactivity, including natural and waste radioactive materials. A study of various atomic batteries is presented with perspectives of development and comparisons of performance parameters and cost. We discuss radioisotope thermal generators, indirect conversion batteries, direct conversion batteries, and direct charge batteries. We qualitatively describe their principles of operat...

  6. High energy density aluminum battery

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Gilbert M.; Paranthaman, Mariappan Parans; Dai, Sheng; Dudney, Nancy J.; Manthiram, Arumugan; McIntyre, Timothy J.; Sun, Xiao-Guang; Liu, Hansan

    2016-10-11

    Compositions and methods of making are provided for a high energy density aluminum battery. The battery comprises an anode comprising aluminum metal. The battery further comprises a cathode comprising a material capable of intercalating aluminum or lithium ions during a discharge cycle and deintercalating the aluminum or lithium ions during a charge cycle. The battery further comprises an electrolyte capable of supporting reversible deposition and stripping of aluminum at the anode, and reversible intercalation and deintercalation of aluminum or lithium at the cathode.

  7. A Review of Approaches for the Design of Li-Ion BMS Estimation Functions Revue de différentes approches pour l’estimation de l’état de charge de batteries Li-ion

    Directory of Open Access Journals (Sweden)

    Di Domenico D.

    2013-02-01

    Full Text Available This paper aims at comparing different approaches for the estimation of the state of charge of lithium-ion batteries. The main advantages as well as the critical points of the considered techniques are analyzed, highlighting the impact of the cell model precision and complexity on the estimator performance. Among others, the electrical equivalent circuit based technique is selected for further development. The results of a complete procedure from the cell characterization to the online estimation are illustrated. The experimental tests based on the data collected on batteries testing facilities of IFP Energies nouvelles show that the proposed strategy allows a satisfying state of charge real time estimation. Cet article vise à comparer différentes approches pour l’estimation de l’état de charge pour les batteries Li-ion. Les principaux avantages ainsi que les points critiques des différentes techniques sont analysés, en soulignant l’impact de la complexité et de la précision du modèle sur les performances de l’estimateur. La procédure complète, allant de la caractérisation de la cellule jusqu’à l’estimation en ligne de l’état de charge, est présentée pour la modélisation par circuit électrique équivalent. Les tests expérimentaux sur la base des données acquises au laboratoire batteries d’IFP Energies nouvelles montrent que cette stratégie permet d’obtenir un estimateur en temps réel de l’état de charge présentant de bonnes performances.

  8. Charge/discharge characteristics of the coal-tar pitch carbon as negative electrode in Li-ion batteries

    Science.gov (United States)

    Kim, Jung-Sik

    The charge/discharge characteristics were studied for the coal-tar pitch-based carbon (CTPC), which was pyrolyzed under the condition to form anisotropic mesophase pitch and then heat treated at temperatures ranging from 500 to 1300°C in N 2 atmosphere. As the heat treatment temperature increased, the reversible capacity for the CTPC increased progressively up to 1000°C, while the irreversible capacity decreased continuously. Carbons synthesized through the extraction of anisotropic mesophases showed higher reversible and lower irreversible capacities than the directly pyrolyzed ones.

  9. Battery model for electrical power system energy balance

    Science.gov (United States)

    Hafen, D. P.

    1983-01-01

    A model to simulate nickel-cadmium battery performance and response in a spacecraft electrical power system energy balance calculation was developed. The voltage of the battery is given as a function of temperature, operating depth-of-charge (DOD), and battery state-of-charge. Also accounted for is charge inefficiency. A battery is modeled by analysis of the results of a multiparameter battery cycling test at various temperatures and DOD's.

  10. Button batteries

    Science.gov (United States)

    Swallowing batteries ... These devices use button batteries: Calculators Cameras Hearing aids Penlights Watches ... If a person puts the battery up their nose and breathes it further in, ... problems Cough Pneumonia (if the battery goes unnoticed) ...

  11. Characterization of lead (Ⅱ)-containing activated carbon and its excellent performance of extending lead-acid battery cycle life for high-rate partial-state-of-charge operation

    Science.gov (United States)

    Tong, Pengyang; Zhao, Ruirui; Zhang, Rongbo; Yi, Fenyun; Shi, Guang; Li, Aiju; Chen, Hongyu

    2015-07-01

    In this work, lead (Ⅱ)-containing activated carbon (Pb@C) is prepared as the additive of negative active mass (NAM), aiming to enhance the electrochemical characteristics of the lead-acid battery. The characters of the Pb@C materials and their electrochemical properties are characterized by XRD, SEM, back-scattering electron image (BESI) and electrochemical methods. The lead (Ⅱ) ions disperse well in the carbon bulk of the obtained Pb@C materials as observed, and these materials exhibit remarkable higher specific capacitance and higher hydrogen evolution over-potential compared with original carbons. Many 2 V lead-acid batteries are assembled manually in our lab, and then the batteries are disassembled after formation and high-rate-partial-state-of-charge (HRPSoC) cycling. Results manifest that the Pb@C additives exhibit high affinity to lead and act as a porous-skeleton in the formation process as well as under HRPSoC cycling conditions, leading to the small and fine formation of PbSO4 particles and accordingly higher active material utilization rate more than 50%, better cycling performance and charging acceptance. Besides, excellent cycle performances of these batteries have great relationship with the dazzling hydrogen evolution performance of Pb@C materials. A possible working mechanism is also proposed based on the testing data in this paper.

  12. 新型充放电均衡一体化电池管理系统研究%New battery management system of integrated charging and discharging balance

    Institute of Scientific and Technical Information of China (English)

    王占国; 文锋; 盛大双; 李索宇

    2012-01-01

    电动汽车串联动力电池组的不一致问题,使得成组电池在容量利用、使用寿命及安全等方面的性能远不及单体电池.分析了电动汽车动力锂电池组不一致产生的原因,以及现有均衡方案存在的问题.提出了一种基于SOC的新型充放电均衡一体化电池管理系统(BMS)方案,并依据车载在线均衡要求设计了均衡硬件电路.实车验证表明,通过均衡模块作用整组电池的可用容量提高了 1.2%,降低了电动汽车电池的使用和维护成本.%Battery's inconsistency of power battery pack connected in series can cause the group battery far inferior to single cell on available capacity, service life and security. The reasons of the battery pack inconsistency are analyzed in this paper. The issues of the traditional battery equalization are also addressed. A new battery management system (BMS) which integrates charging and discharging balance based on the SOC balanced strategy is proposed. And the online balancing hardware circuit is designed according to the vehicle requirement. The experimental results demonstrate that the available capacity of the battery pack is increased by 1.2% with the proposed BMS, the application and maintenance cost is reduced. Therefore it provides the technical support for the development of electric vehicles.

  13. 光电致变色池和光伏打自充电电池%Photoelectrochromic Cell and Photovoltaic Self-charging Battery

    Institute of Scientific and Technical Information of China (English)

    关英勋; 关伟; 陈忠林; 房大维

    2004-01-01

      光电致变色池是一种利用光电化学反应的新型有机/无机杂化型变色器件,它的特点是以太阳光为能源,且具极强的可控性。本文介绍了光电致变色池及由其衍生出的光伏打自充电电池的器件结构、工作原理和当前的研究现状以及未来可能的研究方向。%  The photoelectrochromic cell is a new kind of organic-inorganic hybrid chromoic device driven by the photoelectrochemical mechanism. It is self-powered by solar irradiation and can be controlled easily. In this paper, the device structure, the mechanism, the state of the art of the photoelectrochromic cell and photovoltaic self-charging battery are introduced. The possible method of research and development has also been mentioned.

  14. Fuzzy Sliding Mode Observer with Grey Prediction for the Estimation of the State-of-Charge of a Lithium-Ion Battery

    Directory of Open Access Journals (Sweden)

    Daehyun Kim

    2015-11-01

    Full Text Available We propose a state-of-charge (SOC estimation method for Li-ion batteries that combines a fuzzy sliding mode observer (FSMO with grey prediction. Unlike the existing methods based on a conventional first-order sliding mode observer (SMO and an adaptive gain SMO, the proposed method eliminates chattering in SOC estimation. In this method, which uses a fuzzy inference system, the gains of the SMO are adjusted according to the predicted future error and present estimation error of the terminal voltage. To forecast the future error value, a one-step-ahead terminal voltage prediction is obtained using a grey predictor. The proposed estimation method is validated through two types of discharge tests (a pulse discharge test and a random discharge test. The SOC estimation results are compared to the results of the conventional first-order SMO-based and the adaptive gain SMO-based methods. The experimental results show that the proposed method not only reduces chattering, but also improves estimation accuracy.

  15. Research on typical design scheme of charging/battery swap infrastructure for electric vehicle%电动汽车充换电设施典型设计方案研究

    Institute of Scientific and Technical Information of China (English)

    许庆强; 寇英刚; 马建伟; 闫安心; 江明

    2015-01-01

    为规范充换电设施建设规模和站体布置,研究了电动汽车充换电设施标准化问题,提出了典型设计方案。阐述了典型设计方案编制原则,给出了服务对象具体参数和典型设计方案分类,举例对充电站典型设计方案进行分析研究,包括总平面布置、充电设备、供配电系统、二次系统、土建、消防等内容,并从电池架充电、分箱充电机选型及组柜、换电设备设计、换电监控、电池检测维护等五方面详细阐述换电系统设计方案。提供了所有典型设计方案的配置情况。该典型设计方案可用于统一设备类别和选型,有效控制充换电设施工程造价,也为后续充换电设施运行维护取费标准作好准备,已成功用于指导国家电网公司系统各单位编制充换电设施项目建设方案。%For limiting the construction scale and the layout of charging/battery swap infrastructure, standardization schemes of electric vehicle charging/battery swap infrastructure are researched, and then typical design schemes are raised. Firstly, the typical design scheme compiling principle is described, and specific parameters of serviced electric vehicle and the classification of typical design scheme are provided. On the basis, a typical scheme, including general layout, charging equipment, power supply and distribution system, second order system, civil engineering, fire control, etc., is used as an example for detailedly researching and analyzing the typical design schemes. The design scheme of battery swap system is elaborated in detail, in which charging battery frame, box charger selection and set cabinet, design of battery swap device, battery swap monitoring, battery detection and maintenance are involved. At last, the configuration of typical design schemes is provided. The proposed typical design schemes can be used for unifying the category and selection of equipment and determining the operation

  16. Technical Progress Report for PEPCO: Turbo-Z Battery Charging System. Calendar Quarter Ending March 31, 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-04-01

    The project is proceeding at a rapid pace now. The software is in development for the control board and the test stand. Portions of the writing and debugging of this software have been in conjunction with the hardware development. The software now interfaces with all the measurement instruments and displays the measurements on the screen, and it saves the measurements to a disc file. There is still cleanup work to do on the display items. Work must still be imparted to the code to control a charging sequence while taking measurements of the results. The test stand hardware has received a good development effort this quarter. The timer-counter board is working in the computer. This board paces the measurement cycle and times the discharge pulse (whine circuit). The thermocouple multiplexer is scanning at the same time the analog to digital converter is taking measurements. We have made a good number of hardware modifications to solve problems revealed while writing the software. The power factor correction for the charger power section is still in development. The engineers have found additional sources for the PFC chips, and they have obtained more technical data sheets and acquired samples. The control board schematics are complete, and the software is far along in the development phase. The functions of the control board have been detailed. The control board must next be integrated with the power supply unit. The next phase of development will concentrate on integrating the components together. At this time, the final debugging of the hardware and software will begin. Additionally, the capacitive coupler development is proceeding. The annual DARPA/DoT Advanced Transportation review will be held on May 16, 1999. We expect to learn the status of our project proposal during this conference. Should we more forward, UL has agreed to help us determine the design requirements of the complete charging system at their EV testing facility, prior to manufacturing. This

  17. 电瓶车充电停车智能管理系统%Car battery charging intelligent parking management system

    Institute of Scientific and Technical Information of China (English)

    陈玲君

    2015-01-01

    随着科技的发展,自动化的东西不断进入到我们的生活中。本系统以ATMEL公司单片机AT89S52为控制核心,另有红外遥控器、红外解码器、矩阵键盘电路、液晶显示电路部分、步进电机驱动电路等构成辅助电路。利用按键来进行密码输入、密码重置,同时在液晶屏上显示密码正确与否,从而判断是否开锁;同时能够用红外遥控来进行密码输入来控制步进电机开锁。如需充电可激活连接本车位充电线,车位将给电瓶车自动充电并实时显示电量。整个系统通过键盘和红外遥控器来控制密码输入和控制,液晶屏LCD1602时时显示自行车停车位。%With the development of science and technology,automation of things coming into our life.This system based on ATMEL single chip AT89S52 as the control core,and the infrared remote control,infrared decoder,matrix keyboard circuit,liquid crystal display circuit,driving circuit of stepping motor and an auxiliary circuit.To enter the password,password reset using the key,at the same time in the LCD screen to display the password is correct or not,in order to determine whether the lock;at the same time can use infrared remote control to enter the password to unlock the stepper motor control.For charging can activate the parking spaces will be charging line,to the car battery charging automatically and real-time display of power. The whole system to control the password input and control by keyboard and infrared remote control, liquid crystal screen display bicycle parking spaces at the LCD1602.

  18. 典型蓄电池的建模与荷电状态估算的对比研究%Comparison study on model and state of charge estimation of typical battery

    Institute of Scientific and Technical Information of China (English)

    吴红斌; 顾缃; 赵波; 朱承治

    2014-01-01

    研究不同蓄电池荷电状态(state of charge, SOC)的变化特征有助于在实际应用过程中对蓄电池类型进行选择。基于铅酸电池、磷酸铁锂电池、全钒液流电池3种典型蓄电池模型,采用电池容量修正过的改进安时计量法和改进安时-卡尔曼预测法( Ah-Kal法),对各电池在不同充放电模式下,用MATLAB软件编程得到两种估算方法下的SOC变化曲线。通过SOC对比曲线可以发现铅酸电池的自放电较严重,循环寿命短;磷酸铁锂电池可迅速提供大功率;而全钒液流电池适合作为长期大容量储能支持。同时,改进安时计量法和Ah-Kal的估算结果基本相同,验证了Ah-Kal法的正确性。%It is helpful to make the reasonable choice on types of battery in actual application through studying on state of charge (SOC) of the different batteries.Based on the models of Lead-acid battery, LiFePO4Li-ion battery and Vanadium Redox Flow battery(VRB), the SOC of each battery was estimated through the improved Ah count-ing method and the method of combined improved Ah counting-Kalman filtering(Ah-kal method).Under the differ-ent charging or discharging modes, it obtained the curves of SOC with MATLAB software.It can be found that the Lead-acid battery has the serious self-discharge and short cycle life, the LiFePO4Li-ion battery could supply rapidly high power, and VRB has the large-capacity energy storage support for long-term.With the simulation results, it validates that the improved Ah counting method and Ah-Kal method have almost equal result .And it verifies the correctness of the Ah-Kal method.

  19. 微电网中电动汽车充电模式与换电模式的运行优化%Operation Optimization of Electric Vehicles in Battery Swapping Mode and Direct Charging Mode in Microgrid

    Institute of Scientific and Technical Information of China (English)

    张晓波; 张保会; 董梁; 关哲; 管俊; 谢芮芮

    2016-01-01

    在已知风光出力,且电网实行分时电价的前提下,分别使用充电模式和换电模式调用充电汽车蓄电池储能。充电模式以微网内燃料费用最低和外网购电费用最低为优化目标,换电模式在上述优化目标基础上增加充电购电成本最低优化目标,使用混合整数规划 CPLEX软件求解了该优化目标下的充电汽车储放能控制策略,并给出了优化运行结果。结果表明该优化方案有利于降低微网运营者的运行费用,而采用换电模式给充电汽车充电更能发挥充电汽车蓄电池逢电价高储能、逢电价低放能的作用,提高了微网的运行经济性。%On the premise of known output power of wind power and photovoltaic and time-of-use electricity price implemented in the grid,electric vehicles energy storage battery is used in the battery swapping mode and the direct charging mode.The optimization obj ective is minimum fuel cost and power cost purchased from an external grid in the direct charging mode.For the battery swapping mode,minimum recharging cost is added as the optimization obj ective on the basis of the above-mentioned optimization obj ective in battery swapping mode.The optimization obj ectives are verified using CPLEX software,the results showing that the optimization program will help reduce the operating cost of the microgrid operator.The battery swapping mode is better than the direct charging mode for using battery discharging energy when energy price is high and charging when energy price is low,thus improving the operational economy of the microgrid.

  20. Portable Battery Charger Berbasis Sel Surya

    OpenAIRE

    Budhi Anto; Edy Hamdani; Rizki Abdullah

    2014-01-01

    A type of solar battery charger is introduced in this paper. This equipment functions as a medium size rechargeable battery that is needed to move culinary merchants and coastal fishermen living in area which is not supplied by electrical networks. The equipment consists of solar module mounted onto portable mechanical construction, a 12-V 7.5-Ah lead acid battery and charge controller. Solar module charges the battery through charge controller and then the battery can be discharged to power ...

  1. Energy Transferring Dynamic Equalization for Battery Packs

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The equivalent circuit model of battery and the analytic model of series battery uniformities are setup. The analysis shows that it is the key to maintain small voltage difference between cells in order to improve uniformities. Therefore a new technique combining low voltage difference, big current charging and bi-directional charge equalizer system is put forward and designed. The test shows that the energy transferring dynamic equalization system betters the series battery uniformities and protection during charging and discharging, improves the battery performance and extends the use life of series battery.

  2. 电动汽车铅酸电池脉冲快速充电系统设计%Design of the Pulse-type Fast Speed Charging System of Lead-Acid Battery for Electric Car

    Institute of Scientific and Technical Information of China (English)

    段朝伟; 张雷; 刘刚

    2013-01-01

    为了缩短电动汽车铅酸电池的充电时间,提高能量接受率,基于带放电电流脉宽调制技术,设计了汽车电池脉冲快速充电系统.该系统采用嵌入式控制和上位机监控相结合的方式,软硬设计合理,性能可靠.试验数据分析表明,该系统有效缓解了电池的极化现象,缩短了汽车铅酸电池的充电时间,提高了电池能量接受率.系统具有广泛的应用前景.%In order to shorten the charging time of the lead-acid battery for electric car,and improve the energy acceptance rate,based on current pulse width modulation technology with discharging,the pulse type fast speed charging system of the battery for electric car has been designed.By adopting embedded control and combining with host computer monitoring,the system is designed reasonably in hardware and software and offers reliable performance.The analysis of test data indicates that this system effectively alleviates the polarization phenomenon of battery,shortens the charging time of the lead-acid battery,and enhances the energy acceptance rate.The system possesses broad applicable prospects.

  3. Batteries: Overview of Battery Cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as

  4. Batteries: Overview of Battery Cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as

  5. 铅酸电池的不一致性与均衡充电的研究%Research on the Inequality of Lead Acid Batteries and Equalizing Charge

    Institute of Scientific and Technical Information of China (English)

    麻友良; 陈全世

    2001-01-01

    由于应用于电动汽车的铅酸电池的性能参数的不一致性而导致使用过程中其性能参数差别扩大,是电池使用寿命短并造成电动汽车性能下降的重要因素。本文分析了电池性能差别扩大的原因以及各种不同均衡方法的可用性,提出了切合实际的均衡充电定义,并以试验结果予以验证。%In EVs the batteries' capability parameters demonstrate an inequality. What is more, the inequality becomes more and more serious with the use of batteries. This is an important factor which leads to batteries' shortened life-span and the reduced energy using rate and poorer performance of EVs. This paper has analyzed the features and practicability of different equalizing charging methods.With the analysis ,a practical equalizing charge is proposed, which has been proved to be effective by experiments.

  6. 煤矿井下单轨吊车蓄电池智能充电系统设计%Intelligent Charging System Design of Monorail Hoist Battery in Coal Mine

    Institute of Scientific and Technical Information of China (English)

    石晓艳; 李振璧

    2012-01-01

    In view of the inadequacies of current battery charger, one intelligent charging system of monorail hoist battery based on variable voltage intermittent fast charging method is designed. The system is integrated in hoist sharing one ARM CPU with the whole machine. It is worth of market popularization with the advantages of low cost, high efficiency and effectively postponing battery service time.%针对煤矿井下蓄电池充电系统的不足,设计了基于改进型变电压间歇快速充电法的蓄电池单轨吊车智能充电系统。该充电系统集成于机车内,与整机控制系统共享一块ARM芯片,经试验验证,具有成本低、效率高、能有效延长蓄电池使用寿命等优点。

  7. 核电厂铅酸蓄电池充放电方式分析%The Analysis for Selection of the Lead-acid Battery Charging and Discharging Method

    Institute of Scientific and Technical Information of China (English)

    刘宇; 李波; 孔凡华

    2015-01-01

    蓄电池作为直流系统的最后一道保护屏障,其运行状况、性能是直流系统安全稳定运行的决定性因素,而充放电试验是验证蓄电池运行状况的基本方法.文章以某核电铅酸蓄电池为例,着重介绍了铅酸蓄电池在不同工况下的充放电方式.通过查阅相关文献、调查研究并结合现场实际情况,对不同工况下蓄电池的充放电方式进行了确认;同时对不同充放电方式的适用范围及其优缺点进行了分析,为铅酸蓄电池组设计了合理的充放电方式选用方法,为铅酸蓄电池的安全稳定运行打下了坚实的基础.%The operation of battery,as the last barrier of DC system,determines the stable op-eration of the DC system. Capacity test is the basic way to verify the battery performance. This article takes the lead-acid battery of Fuqing Nuclear Power Plant as example,shows the different charging and discharging modes. The charging and discharging modes under different conditions are confirmed depending on relevant literature,investigation and the actual situation. The advantages and disadvantages of different charging and discharging modes,and also the scope of application are discussed in this paper. Areasonable charging and discharging method forlead-acid batteries is selected,which laid a solid foundation for the safe and stable operation of lead-acid battery.

  8. Role of Li2O2@Li2CO3 Interfaces on Charge Transport in Nonaqueous Li−Air Batteries

    DEFF Research Database (Denmark)

    Mekonnen, Yedilfana Setarge; García Lastra, Juan Maria; Hummelshøj, Jens S.;

    2015-01-01

    vacancies accumulate at the peroxide part of the interface during charge, reducing the coherent electron transport by two to three orders of magnitude compared with pristine Li2O2. During discharge, Li2O2@Li2CO3 interfaces may, however, provide an alternative in-plane channel for fast electron polaron...... battery. Here we apply density functional theory with the Hubbard U correction (DFT+U) and nonequilibrium Green’s function (NEGF) methods to investigate the role of Li2O2@Li2CO3 interface layers on the ionic and electronic transport properties at the oxygen electrode. We show that, for example, lithium...... hopping that could improve the electronic conductivity and ultimately increase the practical capacity in nonaqueous Li−O2 batteries....

  9. 循环充放电条件下锂离子电池的温度模拟%Simulation on the Temperature of Lithium-Ion Battery during Charge-Discharge Cycling

    Institute of Scientific and Technical Information of China (English)

    孙秋娟; 王青松; 平平; 赵学娟

    2014-01-01

    锂离子电池在充放电过程中产生的热量主要为两部分,即因电化学反应而产生的可逆热和由极化产生的不可逆热。若电池内部温度达到82℃以上时,钴酸锂电池材料将发生热分解,引发一系列不可控化学反应,释放出大量的反应热。本论文在可逆热和不可逆热的基础上,耦合电池材料分解热,采用有限元技术,模拟锂离子电池在充放电过程中不同对流条件以及不同外界温度下电池内部温度的变化,为揭示锂离子电池热失控机制提供理论依据。%The heat generation for lithium-ion batteries is composed of the reversible heat caused by the electrochemical reaction and the irreversible heat due to polarization during charge-discharge cycling. The materials of cobalt acid lithium battery begin to decompose once the internal temperature of the battery reached 82oC. A series of uncontrolled chemical reactions are triggered, resulting in releasing a large amount of heat. With the aid of finite element technology, the reversible, irreversible heat and the decomposition heat are both considered in this work to simulate the internal temperature variation of lithium-ion batteries under different cooling conditions and ambient temperatures, which can provide theoretical basis to disclose the thermal runaway mechanism for this kind of battery.

  10. 全钒液流电池电化学建模与充放电分析%Electrochemical model of all vanadium redox flow battery and its charge/discharge analysis

    Institute of Scientific and Technical Information of China (English)

    周文源; 袁越; 傅质馨; 惠东; 杨凯

    2013-01-01

    全钒氧化还原液流电池凭借它的诸多优势,在电力系统中的应用潜力巨大,前景广阔,然而目前尚未有较为统一的仿真模型.以钒电池的电化学原理为基础,推导了以钒电池荷电容量和初始离子浓度为参量的电压方程,通过三组实际系统对仿真模型进行了验证.在此模型基础上,仿真分析对比了钒电池常见的恒功率和恒电流的充放电方法的各项效率指标.%With various advantages,all vanadium redox flow battery is a promising technology in power system.However,the simulation model of vanadium redox battery has not yet been united.Based on the electrochemical principal,the voltage function with the initial ion concentrations and the state of charge as parameters was deduced.The proposed model was then verified by comparing the simulations results with measured data taking from three different actual systems.Moreover,simulations of the constant power charging and constant current charging methods were taking out and their efficiencies were analyzed.

  11. Research on Intermittent-Positive and Negative Pulse Fast Charging of Lithiumion Battery%间歇-正负脉冲蓄电池快速充电方法的研究∗

    Institute of Scientific and Technical Information of China (English)

    吴铁洲; 白婷; 胡丽平; 李子龙

    2014-01-01

    One of the key issues currently affecting charging speed of lithium ion battery is how to eliminate or re-duce the polarization in the charging process. More widely using in fast charge battery of traditional fast charging method is the multi-stage constant current pulse charging method which takes method of positive pulse,stop charging and other ways to reduce or eliminate the polarization effect to improve the charging speed in a certain extent,but the result is not satisfied. This paper proposes the intermittent-positive and negative pulse charging method using al-ternately charge and discharge to reduce or eliminate the polarization phenomenon. Gassing point voltage and polari-zation voltage are used to monitor the polarization status of storage battery. And then,two fuzzy controllers identify the positive and negative pulsed width for the intermittent positive and negative pulse method. According to the ex-perimental results,comparing with traditional multi-stage constant current pulse charging method using stop charging mode,the charging time,charging efficiency and average temperature rise,are improved by about 33.3%,5.1%, 57.1%,respectively.%目前影响锂离子电池充电速度的关键问题之一是如何消除或减小充电过程中的极化现象。传统的快速充电法中使用比较广泛的是多阶恒流脉冲充电法,主要采用正脉冲、停充等方式来减小或消除极化效应,在一定程度上提高了充电速度,但效果不够理想。提出的间歇-正负脉冲充电法,首先依据析气点电压和极化电压监测蓄电池极化状况,然后采用两种模糊控制器,分别确定间歇-正负脉冲充电法中的正负脉冲宽度,采用交替充电和放电减少或消除充电过程中的极化现象。实验证明,间歇-正负脉冲充电方法比传统的采用停充方式的多阶恒流脉冲充电法充电速度提高了33.3%,充电效率提高了5.1%,温升降低了57%。

  12. 大电流电动汽车电池充电电流电压反馈系统设计%High-current Electric Vehicle Battery Charging System’s Current and Voltage Sampling Circuit Design

    Institute of Scientific and Technical Information of China (English)

    章旦旸; 秦会斌

    2015-01-01

    针对电动汽车厂家研发了电动汽车电池充电系统,设计了一种大电流低电压电池充电系统。系统采用了PIC16F877A单片机作为电子控制单元核心,对规格为50 A、3.7 V的电池组进行充电。重点对电流电压采样电路进行了设计和研究。通过建立采样电路的仿真模型。并用实际电压电流数据对本采样系统进行了验证。实验证明,系统提出的电流电压采样具有较高的精度、线性度,且能满足长期稳定运行的实际需求。%For electric car manufacturers, an electric vehicle battery charging system is developed in the paper, which is a high-current low-voltage battery charging system. The system uses a PIC16F877A micro controller as the core of the electronic control unit to charge the 50 A, 3.7 V rechargeable battery packs. The paper focuses on the current and voltage sampling circuit design and research, as well as sampling circuit simulation. Actual voltage and current data of the sampling system is showed to verify the validity. Experiments show that both current and voltage sampling system can work with a good linearity and precision, and can also satisfy the need of long-term stable operation.

  13. 移动式电动汽车充换电的服务理念及其实施%Mobile Battery Charging/Swapping Service for Electric Vehicles and Its Implementation

    Institute of Scientific and Technical Information of China (English)

    周瑾; 杨冠群; 唐国春

    2014-01-01

    电动汽车未来大规模发展需要众多公共充电设施的支持,但是出于地面场地的限制,以及大规模充电对配电网可能带来的冲击,极大地限制了固定式充电设施的布设。为了克服这些困难,提出一种全新的设想方案,即建立移动式电动汽车充换电系统,并分析了这一系统相对于固定式充电设施的优势,以及它从技术角度的可行性。%The massive development of electric vehicles in near future demands numerous public charging infrastructure’s backup. However, the restriction of ground space and the possible impacts of large-scale charging behavior on distribution network, significantly confine the installment of fixable charging infrastructure. In order to overcome these difficulties, a novel conjecture scheme-establish-ment of a mobile battery charging/swapping system for electric vehicles is presented. Furthermore, the advantages of the novel system over fixable charging infrastructure and the feasibility of implementation from the point of view of technology is analyzed.

  14. Aproximation to the Modelling of Charge and Discharge Processes in Electrochemical Batteries by Integral Equation; Aproximacion al Modelo de los Procesos de Carga y Descarga en Baterias Electroquimicas mediante Ecuaciones Integrales

    Energy Technology Data Exchange (ETDEWEB)

    Balenzategui, J. L. [Ciemat, Madrid (Spain)

    2000-07-01

    A new way for the modelling of the charge and discharge processes in electrochemical batteries based on the use of integral equations is presented. The proposed method models the charge curves by by the so called fractional or cumulative integrals of a certain objective function f(t) that must be sought. The charge figures can be easily fitted by breaking down this objective function as the addition of two different Lorentz-type functions: the first one is associated to the own charge process and the second one to the overcharge process. The method allows calculating the starting voltage for overcharge as the intersection between both functions. The curve fitting of this model to different experimental charge curves, by using the Marquardt algorithm, has shown very accurate results. In the case of discharge curves, two possible methods for modelling purposes are suggested, well by using the same kind of integral equations, well by the simple subtraction of an objective function f(t) from a constant value V{sub o}D. Many other aspects for the study and analysis of this method in order to improve its results in further developments are also discussed. (Author) 10 refs.

  15. 电动公交车换电站--电池充电站优化规划%Optimal Planning of Battery Charging and Exchange Stations for Electric Vehicles

    Institute of Scientific and Technical Information of China (English)

    钱斌; 石东源; 谢平平; 朱林

    2014-01-01

    充电设施的规划与建设是解决电动汽车发展瓶颈的重要问题。电动汽车在公共交通领域发展迅速,并广泛采用换电模式。文中充分考虑了电动公交汽车换电电量需求和充换电行为,提出了一种换电站-电池充电站建设模式,并给出了相应的优化规划方法。该方法首先使用近邻传播聚类算法对换电需求点进行空间聚类,以确定电池充电站的站址和规模,并利用化石燃料与电能的热值关系,将当前柴油公交车日消耗能量折算成电能以确定换电电量需求。然后,利用排队论方法对电池充电站内的工作情形进行建模,提出以拒绝服务率为主要约束,以综合建设成本最小为目标的优化模型。最后,以某城市实际统计数据为例给出了该市公交汽车换电站、电池充电站以及其充电设备、换电设备、电池的规划方案,为电动公交车充、换电站的实际规划提供参考。%The planning and deployment of electric vehicle battery charging devices is an important problem in tackling the bottleneck of electric vehicles.Although the charging mode is widely preferred,the exchange mode is still popular with public transport.A battery charging-exchange station construction mode is proposed along with the corresponding optimal planning strategy by taking the electric bus demand into consideration.The affinity propagation clustering algorithm is used to determine the sizing and siting of the battery charging stations.In order to identify the bus electricity demand,daily fuel consumption is converted into equivalent electricity usage.The queuing theory is put forward to model the daily management of battery charging stations.After that,a minimum construction cost optimization model is built with the service denying rate as the major constraint.Finally,actual statistics of a city are taken as an example to determine the quantity of charge/exchange devices and

  16. Microfluidic redox battery.

    Science.gov (United States)

    Lee, Jin Wook; Goulet, Marc-Antoni; Kjeang, Erik

    2013-07-01

    A miniaturized microfluidic battery is proposed, which is the first membraneless redox battery demonstrated to date. This unique concept capitalizes on dual-pass flow-through porous electrodes combined with stratified, co-laminar flow to generate electrical power on-chip. The fluidic design is symmetric to allow for both charging and discharging operations in forward, reverse, and recirculation modes. The proof-of-concept device fabricated using low-cost materials integrated in a microfluidic chip is shown to produce competitive power levels when operated on a vanadium redox electrolyte. A complete charge/discharge cycle is performed to demonstrate its operation as a rechargeable battery, which is an important step towards providing sustainable power to lab-on-a-chip and microelectronic applications. PMID:23712370

  17. Microfluidic redox battery.

    Science.gov (United States)

    Lee, Jin Wook; Goulet, Marc-Antoni; Kjeang, Erik

    2013-07-01

    A miniaturized microfluidic battery is proposed, which is the first membraneless redox battery demonstrated to date. This unique concept capitalizes on dual-pass flow-through porous electrodes combined with stratified, co-laminar flow to generate electrical power on-chip. The fluidic design is symmetric to allow for both charging and discharging operations in forward, reverse, and recirculation modes. The proof-of-concept device fabricated using low-cost materials integrated in a microfluidic chip is shown to produce competitive power levels when operated on a vanadium redox electrolyte. A complete charge/discharge cycle is performed to demonstrate its operation as a rechargeable battery, which is an important step towards providing sustainable power to lab-on-a-chip and microelectronic applications.

  18. Battery Modeling

    OpenAIRE

    Jongerden, M.R.; Haverkort, B.R.

    2008-01-01

    The use of mobile devices is often limited by the capacity of the employed batteries. The battery lifetime determines how long one can use a device. Battery modeling can help to predict, and possibly extend this lifetime. Many different battery models have been developed over the years. However, with these models one can only compute lifetimes for specific discharge profiles, and not for workloads in general. In this paper, we give an overview of the different battery models that are availabl...

  19. In operando monitoring of the state of charge and species distribution in zinc air batteries using X-ray tomography and model-based simulations.

    Science.gov (United States)

    Arlt, Tobias; Schröder, Daniel; Krewer, Ulrike; Manke, Ingo

    2014-10-28

    A novel combination of in operando X-ray tomography and model-based analysis of zinc air batteries is introduced. Using this approach the correlation between the three-dimensional morphological properties of the electrode - on the one hand - and the electrochemical properties of the battery - on the other hand is revealed. In detail, chemical dissolution of zinc particles and the electrode volume were investigated non-destructively during battery operation by X-ray tomography (applying a spatial resolution of 9 μm), while simulation yielded cell potentials of each electrode and allows for the prediction of long-term operation behavior. Furthermore, the analysis of individual zinc particles revealed an electrochemical dissolution process that can be explained using an adapted shrinking-core model. PMID:25220061

  20. 钒液流电池在不同温度下的充放电特性%Charge-discharge Characteristics of Vanadium Redox Flow Battery at various temperatures

    Institute of Scientific and Technical Information of China (English)

    田戈; 贾明波; 李娟; 张中洋

    2014-01-01

    Influence of the temperature on the polarization curve, cyclic efficiency, charge-discharge capacity and self-discharge performance of vanadium redox flow battery was studied in temperature range 15℃~35℃ by using a 10-cell stack, and the mechanism was analyzed. The results show that, in the process of temperature rising, the current efficiency decreases, and voltage efficiency, charge-discharge capacity and self-discharge rate all gradually increase. In order to ensure stable operation of the vanadium battery, the temperature should be strictly controlled in the actual application.%利用10电池电堆考查了在15~35℃范围内温度对钒电池极化曲线、循环效率、充放电容量以及自放电性能的影响,并进行了机理分析,测试结果表明,在温度逐渐升高的过程中,除电流效率逐渐降低外,电压效率、充放电容量、自放电速率均逐渐升高,在实际应用过程中,应严格对温度进行控制以保证钒电池系统的稳定运行。

  1. International Space Station Lithium-Ion Battery

    Science.gov (United States)

    Dalton, Penni J.; Balcer, Sonia

    2016-01-01

    The International Space Station (ISS) Electric Power System (EPS) currently uses Nickel-Hydrogen (Ni-H2) batteries to store electrical energy. The batteries are charged during insolation and discharged during eclipse. The Ni-H2 batteries are designed to operate at a 35 depth of discharge (DOD) maximum during normal operation in a Low Earth Orbit. Since the oldest of the 48 Ni-H2 battery Orbital Replacement Units (ORUs) has been cycling since September 2006, these batteries are now approaching their end of useful life. In 2010, the ISS Program began the development of Lithium-Ion (Li-ion) batteries to replace the Ni-H2 batteries and concurrently funded a Li-ion cell life testing project. This paper will include an overview of the ISS Li-Ion battery system architecture and the progress of the Li-ion battery design and development.

  2. A self-charging power unit by integration of a textile triboelectric nanogenerator and a flexible lithium-ion battery for wearable electronics.

    Science.gov (United States)

    Pu, Xiong; Li, Linxuan; Song, Huanqiao; Du, Chunhua; Zhao, Zhengfu; Jiang, Chunyan; Cao, Guozhong; Hu, Weiguo; Wang, Zhong Lin

    2015-04-17

    A novel integrated power unit realizes both energy harvesting and energy storage by a textile triboelectric nanogenerator (TENG)-cloth and a flexible lithium-ion battery (LIB) belt, respectively. The mechanical energy of daily human motion is converted into electricity by the TENG-cloth, sustaining the energy of the LIB belt to power wearable smart electronics. PMID:25736078

  3. Charge Localization in the Lithium Iron Phosphate Li3Fe2(PO4)3at High Voltages in Lithium-Ion Batteries

    DEFF Research Database (Denmark)

    Younesi, Reza; Christiansen, Ane Sælland; Loftager, Simon;

    2015-01-01

    Possible changes in the oxidation state of the oxygen ion in the lithium iron phosphate Li3Fe2(PO4)3 at high voltages in lithium-ion (Li-ion) batteries are studied using experimental and computational analysis. Results obtained from synchrotron-based hard X-ray photoelectron spectroscopy...

  4. A Reading of the Technology Guide of EV Charging and Battery Swap Facility Connected to Power Grid%电动汽车充换电设施接入电网技术规范解读

    Institute of Scientific and Technical Information of China (English)

    薛振宇; 李敬如; 杨卫红

    2014-01-01

    以支持新能源产业发展为指导思想,以满足电动汽车充电需求为基本目标,从电压等级选择、用户等级确定、接入点选择、供电电源配置、无功补偿及设备选型和电能质量要求等方面,解读电动汽车充换电设施接入电网的技术原则,为指导规划设计、规范运行管理、保障充换电设施及时可靠、合理有序的接入提供重要依据。%Taking supporting the development of new energy industry as the guiding ideology and satisfying the demand of EV charging as purpose, a detailed reading about the technical principle of the EV charging and battery swap facility connected to power grid is given. A series of items, including the selection of voltage level, the confirmation of user grade, point of common coupling selection, the configuration of power supply, reactive power compensation, electrical equipment selection and the demand of power quality, are unscrambled in detail. The guide plays an important role in guiding the distribution network planning and operation management, which could ensure that the EV charging and battery swap facility connected to the power grid reliably and orderly.

  5. Performance of the Lester battery charger in electric vehicles

    Science.gov (United States)

    Vivian, H. C.; Bryant, J. A.

    1984-01-01

    Tests are performed on an improved battery charger. The primary purpose of the testing is to develop test methodologies for battery charger evaluation. Tests are developed to characterize the charger in terms of its charge algorithm and to assess the effects of battery initial state of charge and temperature on charger and battery efficiency. Tests show this charger to be a considerable improvement in the state of the art for electric vehicle chargers.

  6. Paintable Battery

    OpenAIRE

    Singh, Neelam; Galande, Charudatta; Miranda, Andrea; Mathkar, Akshay; Gao, Wei; Reddy, Arava Leela Mohana; Vlad, Alexandru; Ajayan, Pulickel M.

    2012-01-01

    If the components of a battery, including electrodes, separator, electrolyte and the current collectors can be designed as paints and applied sequentially to build a complete battery, on any arbitrary surface, it would have significant impact on the design, implementation and integration of energy storage devices. Here, we establish a paradigm change in battery assembly by fabricating rechargeable Li-ion batteries solely by multi-step spray painting of its components on a variety of materials...

  7. The Extravehicular Maneuvering Unit's New Long Life Battery and Lithium Ion Battery Charger

    Science.gov (United States)

    Russell, Samuel P.; Elder, Mark A.; Williams, Anthony G.; Dembeck, Jacob

    2010-01-01

    The Long Life (Lithium Ion) Battery is designed to replace the current Extravehicular Mobility Unit Silver/Zinc Increased Capacity Battery, which is used to provide power to the Primary Life Support Subsystem during Extravehicular Activities. The Charger is designed to charge, discharge, and condition the battery either in a charger-strapped configuration or in a suit-mounted configuration. This paper will provide an overview of the capabilities and systems engineering development approach for both the battery and the charger

  8. Ensure the electric power system's durability through battery monitoring

    OpenAIRE

    Andersson, Jonas

    2015-01-01

    Battery monitoring is used to acquire information about battery conditions. It’s a regular technology that most of us uses on daily bases. The charge gauge in a cellphone, consisting of bars which indicate the degree of charge left in the battery is an example. Battery monitoring gives the cellphone user information about the battery. The background to the thesis work is that this technology is requested for vehicles because empty or broken batteries are one of the most common causes for invo...

  9. Will Your Battery Survive a World With Fast Chargers?

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, J. S.; Wood, E.

    2015-05-04

    Fast charging is attractive to battery electric vehicle (BEV) drivers for its ability to enable long-distance travel and quickly recharge depleted batteries on short notice. However, such aggressive charging and the sustained vehicle operation that result could lead to excessive battery temperatures and degradation. Properly assessing the consequences of fast charging requires accounting for disparate cycling, heating, and aging of individual cells in large BEV packs when subjected to realistic travel patterns, usage of fast chargers, and climates over long durations (i.e., years). The U.S. Department of Energy's Vehicle Technologies Office has supported the National Renewable Energy Laboratory's development of BLAST-V-the Battery Lifetime Analysis and Simulation Tool for Vehicles-to create a tool capable of accounting for all of these factors. We present on the findings of applying this tool to realistic fast charge scenarios. The effects of different travel patterns, climates, battery sizes, battery thermal management systems, and other factors on battery performance and degradation are presented. We find that the impact of realistic fast charging on battery degradation is minimal for most drivers, due to the low frequency of use. However, in the absence of active battery cooling systems, a driver's desired utilization of a BEV and fast charging infrastructure can result in unsafe peak battery temperatures. We find that active battery cooling systems can control peak battery temperatures to safe limits while allowing the desired use of the vehicle.

  10. 基于Reflex TM充电策略的锂离子电池充电器设计%Design of lithium-ion battery charger based on Reflex TM charging strategy

    Institute of Scientific and Technical Information of China (English)

    汤天浩; 郑晓龙; 范辉

    2015-01-01

    为实现动力锂离子电池的高效快速充电,采用非耗散型的Reflex TM充电方法,消除充电过程中的极化现象,在分析改变充电电流参数对充电过程的优化作用基础上,提出一种变流变频充电控制策略。设计双向DC-DC变换器及其控制电路,实现可变流变频的Reflex TM充电策略。通过改变正负脉冲幅值和占空比等实验,验证其可行性和有效性。%To achieve the high-efficient and fast charge of a power lithium-ion battery,a non-dissipative charging method called as Reflex TM is adopted to remove the polarization phenomenon in the charging process. Based on the analysis of the optimization function of different charging current parameters on the charging process,the variable-current and variable-frequency control strategy is presented,and then a bi-directional DC-DC converter and its control circuit are designed to implement the strategy. The feasibility and availability of the strategy is proved through the experiment where the positive and negative pulse am-plitudes and the duty-cycle are changed.

  11. Dry cell battery poisoning

    Science.gov (United States)

    Batteries - dry cell ... Acidic dry cell batteries contain: Manganese dioxide Ammonium chloride Alkaline dry cell batteries contain: Sodium hydroxide Potassium hydroxide Lithium dioxide dry cell batteries ...

  12. 电动汽车用镍氢电池剩余电量估计方法研究%Research on state of charge estimation method with Ni-MH battery for electric vehicle

    Institute of Scientific and Technical Information of China (English)

    王丽君; 李萌

    2015-01-01

    The state of charge(SOC)prediction has important effect on battery management system of electric vehicle. To predict the SOC accurately and in real⁃time,the management system takes Ni⁃MH battery pack as research object. The com⁃bined method of ampere hour(Ah)accumulation and open circuit voltage(OCV)is used to predict battery pack SOC. The model validity and algorithm are verified by FPGA. The experimental results show that the proposed method has simply structure,lower cost and high prediction accuracy. It is helpful to improve scientific research efficiency and reduce development cycle.%电池剩余容量预测在电动汽车电池管理系统中占有重要的位置。为准确实时地预测电动汽车动力电池组荷电状态(SOC),以镍氢电池组为研究对象,采用安时累积法与开路电压法相结合对电池组SOC进行预测,通过FPGA对模型及算法的有效性进行验证。实验结果表明该研究方法结构简单,成本相对较低,且预测精度相对较高,有助于提高科研效率并缩短产品研发周期。

  13. Design of control system for battery charge regulator in aerospace industry%航天用蓄电池充电调节器的控制系统设计

    Institute of Scientific and Technical Information of China (English)

    贾鹏宇; 郑琼林; 李艳; 张国帅; 万成安

    2012-01-01

    提出了基于Superbuck电路拓扑的航天用电源控制器(Power Conditioning Unit,PCU)中蓄电池充电调节器(Battery Charge Regulator,BCR)的控制系统设计方法,简述了PCU的基本构成和控制区域划分基本原理,分析了BCR在PCU系统中的运行模式,根据其运行特点,对以4阶Superbuck电路为拓扑的BCR进行了建模,给出了占空比控制的多个变量的传递函数表达式,依此设计了三环并列控制的蓄电池充电调节器,并给出了BCR分别在恒压输出,恒流输出,自稳定输入母线工况下的仿真和实验结果,验证了设计的正确性.%A design of Battery Charge Regulator (BCR) control system based on the Superbuck circuit topology in aerospace' Power Conditioning Unit (PCU) is presented. Structure and the basic control concept of PCU are summarized, and operation mode of BCR is analyzed in detail. Averaged modeling is applied to obtain the BCR model under direct duty-ration control and the transfer functions are listed. According to these, a three-loop controlled BCR is designed. The simulation and experiment results listed at last verify the validity of the design.

  14. Lithium-ion battery diagnostic and prognostic techniques

    Science.gov (United States)

    Singh, Harmohan N.

    2009-11-03

    Embodiments provide a method and a system for determining cell imbalance condition of a multi-cell battery including a plurality of cell strings. To determine a cell imbalance condition, a charge current is applied to the battery and is monitored during charging. The charging time for each cell string is determined based on the monitor of the charge current. A charge time difference of any two cell strings in the battery is used to determine the cell imbalance condition by comparing with a predetermined acceptable charge time difference for the cell strings.

  15. The Intelligent lithium Battery Charge System Design Based on BQ24610%基于BQ24610的智能锂电池充电系统设计

    Institute of Scientific and Technical Information of China (English)

    刘晓梅; 刘丹丹; 魏立峰; 王庆辉

    2013-01-01

    BQ24610 is a more advanced separate battery charger IC switch mode of lithium ion battery power supply application to 28 v to 5 v input voltage by TI company.Based on molecular sieve oxygen concentrator portable power management design requirements,through a series of chip principles,performance,analysis and discussion of parameter settings, and ifnal y we use BQ24610 power management chip as part of the main control chip,combined with some peripheral circuit to achieve the automatic selection of power supply design,the internal loop compensation,internal soft-start,dynamic power management(DPM),the precise charge current and voltage regulation,pre-charge,charge termination,adapter current regulation and charge status monitoring. Final y the design is made of experimental board,after repeated testing,the test results to achieve the desired performance.%BQ24610是TI公司推出的一款比较先进的,面向5V至28V电压输入的锂离子电池供电应用开关模式独立电池充电器IC。基于便携式分子筛制氧机的电源管理的设计需求,经过对一系列芯片原理、性能、参数设置的分析讨论,最后我们选用BQ24610芯片作为该电源管理部分的主控制芯片,结合部分外围电路,实现该设计的电源的自动选择、内部回路补偿、内部软启动、动态电源管理(DPM)、精确的充电电流与电压调节、预充电、充电终止、适配器电流调节以及充电状态监控等功能。最后把该设计制成实验板,经过反复调试,测试结果实现了预期性能指标。

  16. Battery selection for space experiments

    Science.gov (United States)

    Francisco, David R.

    1992-10-01

    This paper will delineate the criteria required for the selection of batteries as a power source for space experiments. Four basic types of batteries will be explored, lead acid, silver zinc, alkaline manganese and nickel cadmium. A detailed description of the lead acid and silver zinc cells while a brief exploration of the alkaline manganese and nickel cadmium will be given. The factors involved in battery selection such as packaging, energy density, discharge voltage regulation, and cost will be thoroughly examined. The pros and cons of each battery type will be explored. Actual laboratory test data acquired for the lead acid and silver zinc cell will be discussed. This data will include discharging under various temperature conditions, after three months of storage and with different types of loads. A description of the required maintenance for each type of battery will be investigated. The lifetime and number of charge/discharge cycles will be discussed.

  17. Diphenyl disulfide as a new bifunctional film-forming additive for high-voltage LiCoO2/graphite battery charged to 4.4 V

    Science.gov (United States)

    Zhao, Minkai; Zuo, Xiaoxi; Ma, Xiangdong; Xiao, Xin; Yu, Le; Nan, Junmin

    2016-08-01

    Diphenyl disulfide (DPDS) is evaluated as a new bifunctional electrolyte additive to improve the high-voltage performance of LiCoO2/graphite batteries. With the addition of DPDS in the electrolyte, the cell with 2.0 wt% DPDS exhibits enhanced performance in the normal voltage range of 3.0 V-4.2 V. In particular, when the cut-off potential is increased from 4.2 V to 4.4 V, the cell with 1.0 wt% DPDS also exhibits improved discharge capacity and cycle performance. Linear sweep voltammetry and cyclic voltammetry indicate that the DPDS can be reduced prior to the solvent and that the oxidative decomposition of the electrolyte can also be suppressed. In addition, X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy analyses demonstrate that the solid electrolyte interface (SEI) film is produced primarily on the graphite anode via the decomposition of DPDS at normal voltage and that the SEI films induced by DPDS can be formed simultaneously on the two electrodes at higher potentials. It is hypothesized that these compact SEI films covering the electrode surface provide protection for the LiCoO2 and graphite materials and accordingly improve the cyclic performance of battery in the voltage range of 3.0 V-4.4 V.

  18. Used batteries - REMINDER

    CERN Multimedia

    2006-01-01

    With colder weather drawing in, it is quite likely that older car batteries will fail. On this subject, the Safety Commission wishes to remind everyone that CERN is not responsible for the disposal of used batteries from private vehicles. So please refrain from abandoning them on pavements or around or inside buildings. Used batteries can be disposed of safely, free-of-charge and without any damage to the environment at waste disposal sites (déchetteries) close to CERN in both France (Ain and Haute-Savoie) and in the Canton of Geneva in Switzerland (Cheneviers). Since the average car battery lasts a number of years, this only represents a small effort on your part over the whole lifetime of your vehicle. Most people don't need reminding that car batteries contain concentrated sulphuric acid, which can cause severe burns. Despite this, we frequently find them casually dumped in scrap metal bins! For more information, please contact R. Magnier/SC-GS 160879 We all have a responsibility for safety and th...

  19. Level Control System Improvement of Coal Charging Car for a 6m Coke Oven Battery%6m焦炉装煤车料位控制系统改进

    Institute of Scientific and Technical Information of China (English)

    来志强; 陈欣; 苏艳斌; 王志明; 董晓琳

    2011-01-01

    The 6m coke oven battery is a key equipment of the coking plant of Anyang Iron and Steel Inc. It produces cokes to supply directly to the 2800m3 blast furnace. The technical indicators of its coking chamber have great effect on the coke quality. The improvement of the level control system in the silo for the coal charging car will achieve the accurate control of coal charging volume to ensure the steady production of high-quality cokes.%6m焦炉是安钢焦化厂的重点设备,生产的焦炭直接供2800m3高炉,焦炉炭化室装煤技术指标是否合格对焦炭质量影响很大。通过改进装煤车料仓料位控制系统,达到了准确控制装煤量的目的,保障了优质焦炭的稳定生产。

  20. 基于线性优化的电动汽车换电站最优充放电策略%An Optimal Charging/Discharging Strategy for Electric Vehicle Battery Swapping Stations Based on Linear Optimization

    Institute of Scientific and Technical Information of China (English)

    孙伟卿; 王承民; 曾平良; 张焰

    2014-01-01

    The charging and discharging activities of electric vehicles (EV) can exert significant effects on the safety and economy of power system operation.This paper first compares and analyzes three most common EV battery charging modes. Then,based on the time-of-use (TOU) pricing mechanism,the operation and arbitration modes of electric vehicle battery swapping stations (EVBSS) are analyzed,and the benefit function of the EVBSS is proposed.Then,based on definite simplified on assumptions,taking the maximum operating income of EVBSS as the objective function,a linear programming model for EVBSS optimal charge/discharge strategy is established and solved.Finally,it is verified at two different energy pricings.Case study shows that the optimization model proposed is simple and effective.The work of this paper can help EVBSS operators gain maximum economic benefits and give evidence for grid management departments on EVBSS management and dispatching.%电动汽车的充放电行为会对电网运行的安全性和经济性产生重要影响。文中首先比较和分析3种常用充电模式的特点与适用场合。其次,基于分时电价机制,分析电动汽车换电站的运营与盈利模式,并以此为依据建立换电站的收益函数。然后,基于一定的简化和假设条件,以换电站运营收益最大化为目标函数,兼顾各类运营约束条件,建立换电站最优充放电策略的线性优化模型。最后,以2种电价定价方式验证建立的模型。算例表明,文中提出的优化模型简单有效,所得研究结果可以帮助电动汽车换电站运营方获得最大经济收益,同时也可以为电网管理部门对换电站的管理与调度提供依据。

  1. Automotive Battery Modelling and Management

    Directory of Open Access Journals (Sweden)

    N. M. Hammad

    2014-06-01

    Full Text Available The estimation of vehicle battery performance is typically addressed by testing the battery under specific operation conditions by using a model to represent the test results. Approaches for representing test results range from simple statistical models to neural networks to complex, physics-based models. Basing the model on test data could be problematical when testing becomes impractical with many years life time tests. So, real time estimation of battery performance, an important problem in automotive applications, falls into this area. In vehicles it is important to know the state of charge of the batteries in order to prevent vehicle stranding and to ensure that the full range of the vehicle operation is exploited. In this paper, several battery models have studied including analytical, electrical circuits, stochastic and electro- chemical models. Valve Regulated Lead Acid “VRLA” battery has been modelled using electric circuit technique. This model is considered in the proposed Battery Monitoring System “BMS”. The proposed BMS includes data acquisition, data analysis and prediction of battery performance under a hypothetical future loads. Based on these criteria, a microprocessor based BMS prototype had been built and tested in automotive Lab,. The tests show promising results that can be used in industrial applications

  2. Solar Charged Stand Alone Inverter

    Directory of Open Access Journals (Sweden)

    M.Vasugi

    2014-07-01

    Full Text Available This paper deals with solar powered stand alone inverter which converts the variable dc output of a photovoltaic solar panel into ac that can be fed to loads. Stand alone inverters are used in systems where the inverter get its energy from batteries charged by photo voltaic arrays. A charge controller limits the rate at which electric current is added to or drawn from electric batteries. This charge discharge controller is needed to prevent the battery from being overcharged or discharged thus prolonging its life. The charge/discharge control is necessary in order to achieve safety and increase the capacity of the battery. The project has been tested according its operational purposes. Maximum power rating of the experimented solar charge controller is 100W according battery capacities. Cost effective solar charge controller has been designed and implemented to have efficient system and much longer battery lifetime. The dc output is given to inverter and then it is supplied to loads. This method is very cheap and cost effective.

  3. Charger for NiMH batteries based on buck DC/DC converter

    OpenAIRE

    Lapčević Vladimir

    2014-01-01

    In this paper is presented charger for NiMH battery types AA. Charger is realized by Buck DC/DC converter and microcontroller. Microcontroller controls the work of Buck DC/DC converter by pulse width modulation and by measuring the current of battery charging. The current of charging is held constant by power electronics, and the time of charging is set by the user dependent of capacity of the battery. Standard battery chargers enable the recharge of NiMH b...

  4. Effects of iron phthalocyanine on the inner pressure of MH/Ni battery

    Institute of Scientific and Technical Information of China (English)

    WANG Fang; WU Feng

    2004-01-01

    Effects of iron phthalocyanine (FePc) on the inner pressure of MH/Ni batteries during charging were examined. Experimental results show that the battery with appropriate quantity of FePc displays a much lower inner pressure under charging and overcharging than the battery without FePc, especially the battery with 1 mg FePc exhibits the slowest increasing speed of inner pressure and the best charging efficiency and overchargeability.

  5. Reusable Energy and Power Sources: Rechargeable Batteries

    Science.gov (United States)

    Hsiung, Steve C.; Ritz, John M.

    2007-01-01

    Rechargeable batteries are very popular within consumer electronics. If one uses a cell phone or portable electric tool, she/he understands the need to have a reliable product and the need to remember to use the recharging systems that follow a cycle of charge/discharge. Rechargeable batteries are being called "green" energy sources. They are a…

  6. An averaging battery model for a lead-acid battery operating in an electric car

    Science.gov (United States)

    Bozek, J. M.

    1979-01-01

    A battery model is developed based on time averaging the current or power, and is shown to be an effective means of predicting the performance of a lead acid battery. The effectiveness of this battery model was tested on battery discharge profiles expected during the operation of an electric vehicle following the various SAE J227a driving schedules. The averaging model predicts the performance of a battery that is periodically charged (regenerated) if the regeneration energy is assumed to be converted to retrievable electrochemical energy on a one-to-one basis.

  7. Towards a thermally regenerative all-copper redox flow battery

    OpenAIRE

    Peljo, Pekka; Lloyd, David; Nguyet, Doan; Majaneva, Marko; Kontturi, Kyosti

    2014-01-01

    An all-copper redox flow battery based on strong complexation of Cu+ with acetonitrile is demonstrated, exhibiting reasonable battery performance. More interestingly, the battery can be charged by heat sources of 100 degrees C, by distilling off the acetonitrile. This destabilizes the Cu+ complex, leading to recovery of the starting materials.

  8. 钒电池正极电解液荷电状态的原位监测%In situ monitoring of state of charge for positive electrolyte of vanadium battery

    Institute of Scientific and Technical Information of China (English)

    管勇; 秦野; 任爽; 刘建国; 严川伟

    2009-01-01

    建立了一种原位监测钒电池正极电解液荷电状态SOC(State of Charge)的方法.通过测定钒电池正极电解液的氧化还原电位值ORP_a(Oxidation Reduction Potential),利用ORP_a值与In(1/SOC_a-1)在SOC_a(正极电解液荷电状态)为(0,100%)的开区间内呈线性关系这一规律.建立了ORP_a-SOC_a关系方程,并对该方程进行温度修正.采用修正方程计算所得的SOC_a值与电位滴定法测得的SOC_a值比较.误差小于±1.50%,可实现正极电解液荷电状态的原位监测.%A method of in situ monitoring of SOC (State of Charge) for positive electrolyte in vanadium battery was presented, in which a temperature amended linear equation of oxidation reduction potential of positive electrolyte (ORP_a) with state of charge of positive electrolyte (SOC_a) was founded. The results show that the values of ORP_a are keeping linear with the values of In (1/SOC_a-1)in (0, 100%) region. There shows less than ± 1.50% error between the SOC_a calculated by the ORP_a-SOC_a equation and mensurated by potentiometric titration analysis. Thus, the presented method can be realized in situ monitoring of SOC_a.

  9. Performance of the Lester battery charger in electric vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Vivian, H.C.; Bryant, J.A.

    1984-04-15

    Tests were performed on an improved battery charger manufactured by Lester Electrical of Nebraska, Inc. This charger was installed in a South Coast Technology Rabbit No. 4, which was equipped with lead-acid batteries produced by ESB Company. The primary purpose of the testing was to develop test methodologies for battery charger evaluation. To this end tests were developed to characterize the charger in terms of its charge algorithm and to assess the effects of battery initial state of charge and temperature on charger and battery efficiency. Tests showed this charger to be a considerable improvement in the state of the art for electric vehicle chargers.

  10. 动力锂电池组充放电智能管理系统%Intelligent management system for lithium-ion power battery pack charging and discharging

    Institute of Scientific and Technical Information of China (English)

    陈渊睿; 伍堂顺; 毛建一

    2009-01-01

    In this article, it proposes a new intelligent management system for lithium-ion power battery pack charging and discharging, which is composed of multi-cell Li-ion battery pack analog front ends ISL9216 and ISL9217, 8-bit microcontroller ATmega32, serial 14-bit ADCs MAX1033 and 1-wire digital thermometer DS18B20. It is successful in achieving several significant functions in this pack, which is combined with 14 series connected cells, such as over current protection, short circuit protection, single cell voltage and temperature monitoring, pack cycle account and cell balancing, etc. Compared to previous methods, it has a few outstanding advantages, for instance, higher resolution, less cost, smaller size, faster reaction and simpler circuitry, etc.%提出了一种全新的动力锂电池组充放电智能管理系统,以ISL9216、ISL9217为模拟前端(AFE),ATmega32为控制芯片,MAX1033为辅助锂电池电压采集IC,DS18820为单节锂电池温度传感器,成功地实现了一个14节锂电池串联动力锂电池组的充放电过电流保护和放电时短路电流保护,充放电循环次数记录,单节锂电池电压监测,电池组温度监测以及高达200 mA平衡电流的快速电量平衡等功能,具有体积小,成本低,精度高,反应快,电路简洁等优点.

  11. Synthesis and charge-discharge properties of LiF-NiO composite as a cathode material for Li-ion batteries

    Science.gov (United States)

    Tomita, Yasumasa; Nasu, Hiromasa; Izumi, Yusuke; Arai, Juichi; Otsuka, Satoshi; Yamane, Yohei; Yamada, Koji; Kohno, Yoshiumi; Kobayashi, Kenkichiro

    2016-10-01

    LiF-NiO composites in a molar ratio of 1:1 are synthesized by the mechanical milling of equal amounts of LiF and NiO for 12-144 h. The synthesized composites are investigated by XRD, charge-discharge measurements, and XPS. The XRD peaks of NiO broaden with an increase in the milling time, while those of LiF disappear. Rietveld analysis shows that the LiF-NiO composites prepared by milling for more than 72 h form a solid solution and that the arrangement of Li+ and Ni2+ ions in them is disordered. The LiF and NiO samples milled individually do not exhibit a noticeable discharge capacity, while the composites show a large one. Further, the discharge capacity of the LiF-NiO composites increases with the milling time, with the composite prepared by milling for 144 h exhibiting a discharge capacity of 216 mA h g-1 and an average voltage of 3.53 V at 0.05 C for voltages of 2.0-5.0 V. The XPS data suggest that the Ni ions are probably oxidized and reduced repeatedly during the charge-discharge process and that the Ni2+ ions are partially oxidized to Ni3+ ions during charging to 5.0 V.

  12. Carbon-enhanced VRLA batteries.

    Energy Technology Data Exchange (ETDEWEB)

    Enos, David George; Hund, Thomas D.; Shane, Rod (East Penn Manufacturing, Lyon Station, PA)

    2010-10-01

    The addition of certain forms of carbon to the negative plate in valve regulated lead acid (VRLA) batteries has been demonstrated to increase the cycle life of such batteries by an order of magnitude or more under high-rate, partial-state-of-charge operation. Such performance will provide a significant impact, and in some cases it will be an enabling feature for applications including hybrid electric vehicles, utility ancillary regulation services, wind farm energy smoothing, and solar photovoltaic energy smoothing. There is a critical need to understnd how the carbon interacts with the negative plate and achieves the aforementioned benefits at a fundamental level. Such an understanding will not only enable the performance of such batteries to be optimzied, but also to explore the feasibility of applying this technology to other battery chemistries. In partnership with the East Penn Manufacturing, Sandia will investigate the electrochemical function of the carbon and possibly identify improvements to its anti-sulfation properties. Shiomi, et al. (1997) discovered that the addition of carbon to the negative active material (NAM) substantially reduced PbSO{sub 4} accumulation in high rate, partial state of charge (HRPSoC) cycling applications. This improved performance with a minimal cost. Cycling applications that were uneconomical for traditional VRLA batteries are viable for the carbon enhanced VRLA. The overall goal of this work is to quantitatively define the role that carbon plays in the electrochemistry of a VRLA battery.

  13. Preparation of a Rechargeable Battery Using Waste Protein from the Fish Scales

    International Nuclear Information System (INIS)

    The electrochemical redox reactions of the oxytocin and fish scale protein which are mainly collagen were exploited for the preparation of a rechargeable protein battery named as fish scale battery. This battery was found to depend upon the concentration of oxidizing and reducing agents, voltage of the charger and the time for charging. Some of these parameters were optimized using a single cell of this battery and some others were optimized by using five cell battery. The five cell protein battery gives a maximum and stable voltage of 8500 millivolt. The way of charging and theoretical aspects of the battery is also discussed in this communication. (author)

  14. Solar Battery Charger in CMOS 0.25 um Technology

    OpenAIRE

    Tao Wang; Chang-Ching Huang; Tian-Jen Wang

    2014-01-01

    A solar cell powered Li-ion battery charger in CMOS 0.25um is proposed. The solar battery charger consists of a DC/DC boost converter and a battery charger. The voltage generated by a solar cell is up converted from 0.65V to 1.8V, which is used as the VDD of the battery charger.  In this way, the solar battery charger automatically converts solar energy to electricity and stores it directly to a Li-ion rechargeable battery. In this system, a super capacitor is needed as a charge buffer betwee...

  15. Efficient and powerful batteries for driverless transportation systems

    Energy Technology Data Exchange (ETDEWEB)

    1986-11-01

    In driverless transportation systems batteries are playing an essential role. The capacitive operation or cycling of driverless systems require the use of different battery systems. Energy supply concepts have to be based on the perspective functional descriptions. The required data comprise full details on discharging processes (temporal current flows), intermediate and complete charging, ambient temperature ranges (which determine the type of battery to be used), and the minimum discharge voltage. Data on the exchange of batteries as well as on the maximum weight and volume of batteries complete the list of data. Any systems evaluation of the batteries to be used has to take account of the operating conditions.

  16. Research on the fast charging of VRLA

    Directory of Open Access Journals (Sweden)

    Xiao Qing

    2012-11-01

    Full Text Available VRLA can be the energy storing device of the HEV (Hybrid Electric Vehicle, photovoltaic system and so on. The most important factor that restricts the improvement of these fields is the service lifetime of the battery cannot reach the expectation. In the charging process, traditional charging method has serious polarization phenomenon. It will decrease its service life. Aimed at the purpose of reducing the polarization phenomenon, this paper proposed the changing current depolarization pulse charging method which is combining the dynamic model of the battery on the basis of analyzing the existential issues in the pulse charging method. By building the hardware circuit to achieve the function and verify their feasibility. The results indicate that, compared with pulse charging method, the new method makes battery fully charged in shorter time obviously and the temperature of batteries rise more slowly.

  17. A LiFePO4 battery pack capacity estimation approach considering in-parallel cell safety in electric vehicles

    International Nuclear Information System (INIS)

    Highlights: • Find the influence of in-parallel battery cell variations on battery pack capacity. • Redefine the battery module capacity with considering ANY battery cell safety. • Discuss the safety end-of-charge voltage for an aged in-parallel battery module. • Build an algorithm for battery pack capacity estimation with the charge curve. • Bench tests are used to verify the validity of the proposed algorithm. - Abstract: In electric vehicles (EVs), several battery cells are connected in parallel to establish a battery module. The safety of the battery module is influenced by inconsistent battery cell performance which causes uneven currents flowing through internal in-parallel battery cells. A battery cell model is developed based on the Matlab–Simscape platform and validated by tests. The battery cell model is used to construct simulation models for analyzing the effect of battery cell inconsistency on the performance of an in-parallel battery module. Simulation results indicate that the state-of-charge (SOC) of a battery module cannot characterize the SOC of ALL the internal battery cells in the battery module. When the battery management system (BMS) controls the end-of-charge (EOC) time according to the SOC of a battery module, some internal battery cells are over-charged. To guarantee the safety of ALL battery cells through the whole battery life, a safety EOC voltage of the battery module should be set according to the number of battery cells in the battery module and the applied charge current. Simulations reveal that the SOC of the “normal battery module” is related to its charge voltage when aged battery module is charged to the EOC voltage. Then, a function describing their relationship is established. Both the capacity and the charge voltage shift are estimated by comparing the measured voltage-to-capacity curve with the standard one provided by the manufactory. A battery pack capacity estimation method is proposed according to the SOC

  18. Prediction of Retained Capacity and EODV of Li-ion Batteries in LEO Spacecraft Batteries

    CERN Document Server

    Ramakrishnan, S; Jeyakumar, A Ebenezer

    2010-01-01

    In resent years ANN is widely reported for modeling in different areas of science including electro chemistry. This includes modeling of different technological batteries such as lead acid battery, Nickel cadmium batteries etc. Lithium ion batteries are advance battery technology which satisfy most of the space mission requirements. Low earth orbit (LEO)space craft batteries undergo large number of charge discharge cycles (about 25000 cycles)compared to other ground level or space applications. This study is indented to develop ANN model for about 25000 cycles, cycled under various temperature, Depth Of Discharge (DOD) settings with constant charge voltage limit to predict the retained capacity and End of Discharge Voltage (EODV). To extract firm conclusion and distinguish the capability of ANN method, the predicted values are compared with experimental result by statistical method and Bland Altman plot.

  19. Direct Observation of Active Material Concentration Gradients and Crystallinity Breakdown in LiFePO4 Electrodes During Charge/Discharge Cycling of Lithium Batteries

    OpenAIRE

    Roberts, Matthew R.; Madsen, Alex; Nicklin, Chris; Rawle, Jonathan; Palmer, M.; Owen, John R.; Hector, Andrew L.

    2014-01-01

    The phase changes that occur during discharge of an electrode comprised of LiFePO4, carbon, and PTFE binder have been studied in lithium half cells by using X-ray diffraction measurements in reflection geometry. Differences in the state of charge between the front and the back of LiFePO4 electrodes have been visualized. By modifying the X-ray incident angle the depth of penetration of the X-ray beam into the electrode was altered, allowing for the examination of any concentration gradients th...

  20. Optimization of a Vanadium Redox Flow Battery with Hydrogen generation

    OpenAIRE

    Wrang, Daniel

    2016-01-01

    We consider the modelling and optimal control of energy storage systems, in this study a Vanadium Redox Flow Battery. Such a battery can be introduced in the electrical grid to be charged when demand is low and discharged when demand is high, increasing the overall efficiency of the network while reducing costs and emission of greenhouse gases. The model of the battery proposed in this study is less complex than the majority of models on batteries and energy storage systems found in literatur...

  1. Cooperation behavior between heterogeneous cations in hybrid batteries.

    Science.gov (United States)

    Zhang, Hanping; Wu, Xin; Yang, Tao; Liang, Shanshan; Yang, Xiaojian

    2013-11-01

    A cooperative behavior of Zn(2+) and Li(+) to conduct charges in a Zn-LiFePO4 battery is disclosed. When Li(+) dissolves into the electrolyte, Zn(2+) would deposit, and vice versa. In light of this cooperative behavior, the battery can be viewed as a super hybrid system, which combines the strong points of Zn-air battery, lithium-ion battery and redox-flow cell. PMID:24042332

  2. Separator Material Chosen for MH/Ni Battery

    Institute of Scientific and Technical Information of China (English)

    Xu Shaoping; Ma Yijun; Liang Wanlong; Liu Dong; Jia Chunming

    2004-01-01

    The properties of MH/Ni batteries using different separator were studied.And then an idea for choosing separator for high-power MH/Ni battery was provided.Using the separator with grafting treatment, the storage characteristic, charge retention characteristic and anti-soft-short characteristic of high-power MH/Ni battery are improved.Wetlaid and spunfibre material meet different properties requirement of battery.

  3. Batteries used to power implantable biomedical devices

    International Nuclear Information System (INIS)

    Battery systems have been developed that provide years of service for implantable medical devices. The primary systems utilize lithium metal anodes with cathode systems including iodine, manganese oxide, carbon monofluoride, silver vanadium oxide and hybrid cathodes. Secondary lithium ion batteries have also been developed for medical applications where the batteries are charged while remaining implanted. While the specific performance requirements of the devices vary, some general requirements are common. These include high safety, reliability and volumetric energy density, long service life, and state of discharge indication. Successful development and implementation of these battery types has helped enable implanted biomedical devices and their treatment of human disease.

  4. Batteries used to Power Implantable Biomedical Devices

    Science.gov (United States)

    Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

    2012-01-01

    Battery systems have been developed that provide years of service for implantable medical devices. The primary systems utilize lithium metal anodes with cathode systems including iodine, manganese oxide, carbon monofluoride, silver vanadium oxide and hybrid cathodes. Secondary lithium ion batteries have also been developed for medical applications where the batteries are charged while remaining implanted. While the specific performance requirements of the devices vary, some general requirements are common. These include high safety, reliability and volumetric energy density, long service life, and state of discharge indication. Successful development and implementation of these battery types has helped enable implanted biomedical devices and their treatment of human disease. PMID:24179249

  5. Batteries used to Power Implantable Biomedical Devices.

    Science.gov (United States)

    Bock, David C; Marschilok, Amy C; Takeuchi, Kenneth J; Takeuchi, Esther S

    2012-12-01

    Battery systems have been developed that provide years of service for implantable medical devices. The primary systems utilize lithium metal anodes with cathode systems including iodine, manganese oxide, carbon monofluoride, silver vanadium oxide and hybrid cathodes. Secondary lithium ion batteries have also been developed for medical applications where the batteries are charged while remaining implanted. While the specific performance requirements of the devices vary, some general requirements are common. These include high safety, reliability and volumetric energy density, long service life, and state of discharge indication. Successful development and implementation of these battery types has helped enable implanted biomedical devices and their treatment of human disease.

  6. USED BATTERIES-REMINDER

    CERN Multimedia

    2002-01-01

    Note from the TIS Division: Although it is not an obligation for CERN to collect, store and dispose of used batteries from private vehicles, they are often found abandoned on the site and even in the scrap metal bins. As well as being very dangerous (they contain sulphuric acid which is highly corrosive), this practise costs CERN a non-negligible amount of money to dispose of them safely. The disposal of used batteries in the host state could not be simpler, there are 'déchetteries' in neighbouring France at Saint-Genis, Gaillard and Annemasse as well as in other communes. In Geneva Canton the centre de traitement des déchets spéciaux, at Cheneviers on the river Rhône a few kilometers from CERN, will dispose of your batterie free of charge. So we ask you to use a little common sense and to help protect the environnement from the lead and acid in these batteries and even more important, to avoid the possibility of a colleague being seriously injured. It doesn't take m...

  7. Fuzzy Control of a Lead Acid Battery Charger

    Directory of Open Access Journals (Sweden)

    A. DAOUD

    2005-03-01

    Full Text Available In this paper, an alternative battery charging control technique based on fuzzy logic for photovoltaic (PV applications is presented. A PV module is connected to a buck type DC/DC power converter and a microcontroller based unit is used to control the lead acid battery charging voltage. The fuzzy control is used due to the simplicity of implementation, robustness and independence from the complex mathematical representation of the battery. The usefulness of this control method is confirmed by experiments.

  8. 钒液流电池的建模与充放电控制特性%Researching on vanadium redox flow battery modeling and charge-discharge characteristics

    Institute of Scientific and Technical Information of China (English)

    丁明; 陈中; 林根德

    2011-01-01

    随着风电场、光伏电站并网穿透功率的不断增加,风电场、光伏电站输出功率随机波动性给电网的安全运行带来了一系列影响,储能技术平滑风电场、光伏电站输出功率波动是有效手段之一,因此对储能媒介建模及充放电控制方式的深入研究至关重要.钒液流电池作为一种新型储能电池,具有功率密度和能量密度独立控制、充放电循环寿命长、动态响应快、维护简单等优点,适合于可再生能源发电系统应用.研究钒液流电池(VRB)的充放电模型、电池可用能量预测、荷电状态SOC及充放电输出特性,构建10 kW/h VRB仿真系统模型,详细研究VRB的恒功率、恒电流充放电模式和充放电效率,并讨论应用于独立光伏发电系统的VRB优化充电方式.%With the increasing penetration of grid-connected wind power generation and PV system, the output fluctuation of wind power and PV system brings many effects on the safe operation of power system. Smoothing the output fluctuation with energy storage system is an effective method. Vanadium Redox Flow Battery (VRB) as a new type energy storage system has many advantages, such as the decoupling control of the power and capacity, long life, fast response and low maintenance requirements, which make it suitable for renewable sources generation systems. Base on the study of VRB charge-discharge model, remaining energy prediction,state of charge (SOC) and the output characteristics, a 10 kW/h VRB simulation model is set up in this paper. The constant power mode and the constant current mode are studied in detail as well as the charge-discharge efficiency. At the end, an optimization charging method for VRB system in a stand-alone PV system is proposed, and the simulation results are given.

  9. Effects of compatibility of polymer binders with solvate ionic liquid electrolytes on discharge and charge reactions of lithium-sulfur batteries

    Science.gov (United States)

    Nakazawa, Toshitada; Ikoma, Ai; Kido, Ryosuke; Ueno, Kazuhide; Dokko, Kaoru; Watanabe, Masayoshi

    2016-03-01

    Electrochemical reactions in Li-S cells with a solvate ionic liquid (SIL) electrolyte composed of tetraglyme (G4) and Li[TFSA] (TFSA: bis(trifluoromethanesulfonyl)amide) are studied. The sulfur cathode (S cathode) comprises sulfur, carbon powder, and a polymer binder. Poly(ethylene oxide) (PEO) and poly(vinyl alcohol) (PVA-x) with different degrees of saponification (x%) are used as binders to prepare the composite cathodes. For the Li-S cell containing PEO binder, lithium polysulfides (Li2Sm, 2 ≤ m ≤ 8), reaction intermediates of the S cathode, dissolve into the electrolyte, and Li2Sm acts as a redox shuttle in the Li-S cell. In contrast, in the Li-S cell with PVA-x binder, the dissolution of Li2Sm is suppressed, leading to high columbic efficiencies during charge-discharge cycles. The compatibility of the PVA-x binder with the SIL electrolyte changes depending on the degree of saponification. Decreasing the degree of saponification leads to increased electrolyte uptake by the PVA-x binder, increasing the charge and discharge capacities of Li-S cell. The rate capability of Li-S cell is also enhanced by the partial swelling of the PVA-x binder. The enhanced performance of Li-S cell containing PVA-x is attributed to the lowering of resistance of Li+ ion transport in the composite cathode.

  10. Experimental research on charging characteristics of a solar photovoltaic system by the pressure-control method

    Institute of Scientific and Technical Information of China (English)

    Hua ZHU; Zhang-lu XU; Zi-juan CAO

    2011-01-01

    The charging characteristics of the valve-regulated lead acid (VRLA) battery driven by solar energy were experimentally studied through the pressure-control method in this paper. The aims of the research were to increase charging efficiency to make the most of solar energy and to improve charging quality to prolong life of battery. The charging process of a 12 V 12 A.h VRLA battery has been tested under the mode of a stand-alone photovoltaic (PV) system. Results show that the pressure-control method can effectively control PV charging of the VRLA battery and make the best of PV cells through the maximum power point tracking (MPPT). The damage of VRLA battery by excess oxygen accumulation can be avoided through the inner pressure control of VRLA battery. Parameters such as solar radiation intensity, charging power, inner pressure of the battery, and charging current and voltage during the charging process were measured and analyzed.

  11. 电动汽车充换电站动力电池全寿命周期在线检测管理系统%The whole life cycle on-line detection and management system of power battery in the electric vehicle charging and exchanging station

    Institute of Scientific and Technical Information of China (English)

    连湛伟; 石欣; 克潇; 徐鹏

    2014-01-01

    In order to improve the assessment accuracy of power battery health degree, this paper provides an assessment arithmetic based on power battery life cycle characteristic parameter for power battery box (group). Starting with the safe use and accurate assessment of power battery, concerning the SOC arithmetic and SOH test methods of power battery, it leads to the design concept of on-line monitoring supervision system for power battery life cycle;with the power battery nominal data as basis, it tests the power battery based on its daily charging/switching and discharging data, to conduct unified management of power battery with hidden danger during testing and make battery maintain/servicing plan. The assessment result shows that with battery box (group) as analyzing/managing object, assessing battery box with corresponding strategies according to power battery electrical features, we can assess the current health condition of power battery relatively accurately, and forecast the use tendency of power battery, thus achieving the goal of improving the security of power battery use, prolonging its serving life and reducing the operating costs.%为了提高对动力电池健康程度评估的准确性,针对动力电池(组),给出一种基于动力电池的全寿命周期特征参数的评估算法。以动力电池的安全使用和准确评估为切入点,关注动力电池SOC的算法与动力电池SOH的检测方式,引出动力电池全生命周期在线监测管理系统的设计思想。以动力电池标称数据为基础,基于动力电池日常充电/换电、放电数据对动力电池进行检测,对检测中发现的隐患的动力电池统一调度,并制定电池维护/检修计划。评估结果表明,以电池箱(组)为分析/管理对象,根据动力电池的电气特征量采用对应策略对电池箱进行评估,可较为准确的评估动力电池当前的健康状态。且可预测出动力电池的使用趋势,从而

  12. 电动汽车充换电站动力电池全寿命周期在线检测管理系统%The whole life cycle on-line detection and management system of power battery in the electric vehicle charging and exchanging station

    Institute of Scientific and Technical Information of China (English)

    连湛伟; 石欣; 克潇; 徐鹏

    2014-01-01

    为了提高对动力电池健康程度评估的准确性,针对动力电池(组),给出一种基于动力电池的全寿命周期特征参数的评估算法。以动力电池的安全使用和准确评估为切入点,关注动力电池SOC的算法与动力电池SOH的检测方式,引出动力电池全生命周期在线监测管理系统的设计思想。以动力电池标称数据为基础,基于动力电池日常充电/换电、放电数据对动力电池进行检测,对检测中发现的隐患的动力电池统一调度,并制定电池维护/检修计划。评估结果表明,以电池箱(组)为分析/管理对象,根据动力电池的电气特征量采用对应策略对电池箱进行评估,可较为准确的评估动力电池当前的健康状态。且可预测出动力电池的使用趋势,从而达到“提高动力电池使用的安全性,延长电池的使用生命,减少运营成本”的目的。%In order to improve the assessment accuracy of power battery health degree, this paper provides an assessment arithmetic based on power battery life cycle characteristic parameter for power battery box (group). Starting with the safe use and accurate assessment of power battery, concerning the SOC arithmetic and SOH test methods of power battery, it leads to the design concept of on-line monitoring supervision system for power battery life cycle;with the power battery nominal data as basis, it tests the power battery based on its daily charging/switching and discharging data, to conduct unified management of power battery with hidden danger during testing and make battery maintain/servicing plan. The assessment result shows that with battery box (group) as analyzing/managing object, assessing battery box with corresponding strategies according to power battery electrical features, we can assess the current health condition of power battery relatively accurately, and forecast the use tendency of power battery, thus achieving the goal

  13. Requirements for future automotive batteries - a snapshot

    Science.gov (United States)

    Karden, Eckhard; Shinn, Paul; Bostock, Paul; Cunningham, James; Schoultz, Evan; Kok, Daniel

    Introduction of new fuel economy, performance, safety, and comfort features in future automobiles will bring up many new, power-hungry electrical systems. As a consequence, demands on automotive batteries will grow substantially, e.g. regarding reliability, energy throughput (shallow-cycle life), charge acceptance, and high-rate partial state-of-charge (HRPSOC) operation. As higher voltage levels are mostly not an economically feasible alternative for the short term, the existing 14 V electrical system will have to fulfil these new demands, utilizing advanced 12 V energy storage devices. The well-established lead-acid battery technology is expected to keep playing a key role in this application. Compared to traditional starting-lighting-ignition (SLI) batteries, significant technological progress has been achieved or can be expected, which improve both performance and service life. System integration of the storage device into the vehicle will become increasingly important. Battery monitoring systems (BMS) are expected to become a commodity, penetrating the automotive volume market from both highly equipped premium cars and dedicated fuel-economy vehicles (e.g. stop/start). Battery monitoring systems will allow for more aggressive battery operating strategies, at the same time improving the reliability of the power supply system. Where a single lead-acid battery cannot fulfil the increasing demands, dual-storage systems may form a cost-efficient extension. They consist either of two lead-acid batteries or of a lead-acid battery plus another storage device.

  14. Heat tolerance of automotive lead-acid batteries

    Science.gov (United States)

    Albers, Joern

    Starter batteries have to withstand a quite large temperature range. In Europe, the battery temperature can be -30 °C in winter and may even exceed +60 °C in summer. In most modern cars, there is not much space left in the engine compartment to install the battery. So the mean battery temperature may be higher than it was some decades ago. In some car models, the battery is located in the passenger or luggage compartment, where ambient temperatures are more moderate. Temperature effects are discussed in detail. The consequences of high heat impact into the lead-acid battery may vary for different battery technologies: While grid corrosion is often a dominant factor for flooded lead-acid batteries, water loss may be an additional influence factor for valve-regulated lead-acid batteries. A model was set up that considers external and internal parameters to estimate the water loss of AGM batteries. Even under hot climate conditions, AGM batteries were found to be highly durable and superior to flooded batteries in many cases. Considering the real battery temperature for adjustment of charging voltage, negative effects can be reduced. Especially in micro-hybrid applications, AGM batteries cope with additional requirements much better than flooded batteries, and show less sensitivity to high temperatures than suspected sometimes.

  15. Optimized batteries for cars with dual electrical architecture

    Science.gov (United States)

    Douady, J. P.; Pascon, C.; Dugast, A.; Fossati, G.

    During recent years, the increase in car electrical equipment has led to many problems with traditional starter batteries (such as cranking failure due to flat batteries, battery cycling etc.). The main causes of these problems are the double function of the automotive battery (starter and service functions) and the difficulties in designing batteries well adapted to these two functions. In order to solve these problems a new concept — the dual-concept — has been developed with two separate batteries: one battery is dedicated to the starter function and the other is dedicated to the service function. Only one alternator charges the two batteries with a separation device between the two electrical circuits. The starter battery is located in the engine compartment while the service battery is located at the rear of the car. From the analysis of new requirements, battery designs have been optimized regarding the two types of functions: (i) a small battery with high specific power for the starting function; for this function a flooded battery with lead-calcium alloy grids and thin plates is proposed; (ii) for the service function, modified sealed gas-recombinant batteries with cycling and deep-discharge ability have been developed. The various advantages of the dual-concept are studied in terms of starting reliability, battery weight, and voltage supply. The operating conditions of the system and several dual electrical architectures have also been studied in the laboratory and the car. The feasibility of the concept is proved.

  16. 基于蓄电池三段式充电的小型风光互补控制系统的设计与仿真%Design and Simulation for Small Wind and Solar Control Systems Based on Three—Stage Battery Charging

    Institute of Scientific and Technical Information of China (English)

    汪楚锟; 谢利理; 雒名佳

    2012-01-01

    基于太阳能光伏发电和风力发电的特点,给出了新颖的最大功率点跟踪控制策略;研究了蓄电池在各个充电方式下的特点,给出一种三段式充电控制策略,设计了一种新型风光互补控制系统,经matlab仿真验证,本系统可靠稳定,降低了成本,并实现了蓄电池的高效、快速、无损充电,使得充电曲线尽可能地逼近最佳充电曲线,提高了蓄电池使用效率,并利用双闭环PID控制实现了蓄电池的恒压限流充电.%A novel maximum power point tracking control strategy is proposed based on characteristics of photovoltaic and wind power generation. And a new three —stage charging strategy of battery is given to research the different charging mode. The simulation results prove that the system is reliable and stable, less—cost and non — destructive charge. The charging curve seems more approximate the best possible charging curve. Using double —loop PID control can achieve constant voltage battery current limiting.

  17. Automatic Battery Swap System for Home Robots

    Directory of Open Access Journals (Sweden)

    Juan Wu

    2012-12-01

    Full Text Available This paper presents the design and implementation of an automatic battery swap system for the prolonged activities of home robots. A battery swap station is proposed to implement battery off‐line recharging and on‐line exchanging functions. It consists of a loading and unloading mechanism, a shifting mechanism, a locking device and a shell. The home robot is a palm‐sized wheeled robot with an onboard camera and a removable battery case in the front. It communicates with the battery swap station wirelessly through ZigBee. The influences of battery case deflection and robot docking deflection on the battery swap operations have been investigated. The experimental results show that it takes an average time of 84.2s to complete the battery swap operations. The home robot does not have to wait several hours for the batteries to be fully charged. The proposed battery swap system is proved to be efficient in home robot applications that need the robots to work continuously over a long period.

  18. Cascade redox flow battery systems

    Energy Technology Data Exchange (ETDEWEB)

    Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

    2014-07-22

    A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

  19. Analysis of reaction and transport processes in zinc air batteries

    CERN Document Server

    Schröder, Daniel

    2016-01-01

    This book contains a novel combination of experimental and model-based investigations, elucidating the complex processes inside zinc air batteries. The work presented helps to answer which battery composition and which air-composition should be adjusted to maintain stable and efficient charge/discharge cycling. In detail, electrochemical investigations and X-ray transmission tomography are applied on button cell zinc air batteries and in-house set-ups. Moreover, model-based investigations of the battery anode and the impact of relative humidity, active operation, carbon dioxide and oxygen on zinc air battery operation are presented. The techniques used in this work complement each other well and yield an unprecedented understanding of zinc air batteries. The methods applied are adaptable and can potentially be applied to gain further understanding of other metal air batteries. Contents Introduction on Zinc Air Batteries Characterizing Reaction and Transport Processes Identifying Factors for Long-Term Stable O...

  20. Prismatic sealed nickel-cadmium batteries utilizing fiber structured electrodes. II - Applications as a maintenance free aircraft battery

    Science.gov (United States)

    Anderman, Menahem; Benczur-Urmossy, Gabor; Haschka, Friedrich

    Test data on prismatic sealed Ni-Cd batteries utilizing fiber structured electrodes (sealed FNC) is discussed. It is shown that, under a voltage limited charging scheme, the charge acceptance of the sealed FNC battery is far superior to that of the standard vented aircraft Ni-Cd batteries. This results in the sealed FNC battery maintaining its capacity over several thousand cycles without any need for electrical conditioning or water topping. APU start data demonstrate superior power capabilities over existing technologies. Performance at low temperature is presented. Abuse test results reveal a safe fail mechanism even under severe electrical abuse.

  1. Influence of Battery/Ultracapacitor Energy-Storage Sizing on Battery Lifetime in a Fuel Cell Hybrid Electric Vehicle

    DEFF Research Database (Denmark)

    Schaltz, Erik; Rasmussen, Peter Omand; Khaligh, Alireza

    2009-01-01

    Combining high-energy-density batteries and high-power-density ultracapacitors in fuel cell hybrid electric vehicles (FCHEVs) results in a high-performance, highly efficient, low-size, and light system. Often, the battery is rated with respect to its energy requirement to reduce its volume and mass......, the battery, and the ultracapacitors, are proposed. A charging strategy, which charges the energy-storage devices due to the conditions of the FCHEV, is also proposed. The analysis provides recommendations on the design of the battery and the ultracapacitor energy-storage systems for FCHEVs....

  2. Memel's Batteries

    Directory of Open Access Journals (Sweden)

    Alexander F. Mitrofanov

    2015-12-01

    Full Text Available The article describes the history and equipment of the coastal and antiaircraft artillery batteries of German Navy (Kriegsmarine constructed in Memel area before and during the World War. There is given the brief description of the Soviet Navy stationed in the area in the postwar years.

  3. Advanced Battery Manufacturing (VA)

    Energy Technology Data Exchange (ETDEWEB)

    Stratton, Jeremy

    2012-09-30

    LiFeBATT has concentrated its recent testing and evaluation on the safety of its batteries. There appears to be a good margin of safety with respect to overheating of the cells and the cases being utilized for the batteries are specifically designed to dissipate any heat built up during charging. This aspect of LiFeBATT’s products will be even more fully investigated, and assuming ongoing positive results, it will become a major component of marketing efforts for the batteries. LiFeBATT has continued to receive prismatic 20 Amp hour cells from Taiwan. Further testing continues to indicate significant advantages over the previously available 15 Ah cells. Battery packs are being assembled with battery management systems in the Danville facility. Comprehensive tests are underway at Sandia National Laboratory to provide further documentation of the advantages of these 20 Ah cells. The company is pursuing its work with Hybrid Vehicles of Danville to critically evaluate the 20 Ah cells in a hybrid, armored vehicle being developed for military and security applications. Results have been even more encouraging than they were initially. LiFeBATT is expanding its work with several OEM customers to build a worldwide distribution network. These customers include a major automotive consulting group in the U.K., an Australian maker of luxury off-road campers, and a number of makers of E-bikes and scooters. LiFeBATT continues to explore the possibility of working with nations that are woefully short of infrastructure. Negotiations are underway with Siemens to jointly develop a system for using photovoltaic generation and battery storage to supply electricity to communities that are not currently served adequately. The IDA has continued to monitor the progress of LiFeBATT’s work to ensure that all funds are being expended wisely and that matching funds will be generated as promised. The company has also remained current on all obligations for repayment of an IDA loan and lease

  4. Lead batteries. 1977-June 1980 (citations from the Engineering Index Data Base). Report for 1977-June 1980

    Energy Technology Data Exchange (ETDEWEB)

    Cavagnaro, D.M.

    1980-07-01

    Worldwide research on lead battery components, charging, corrosion, and testing is cited. The majority of studies concern battery use in electric vehicles. Studies on lead recovery from battery scrap and air pollution at battery factories are also included. (This updated bibliography contains 155 citations, 40 of which are new entries to the previous edition.)

  5. Electrolytes for rechargeable lithium batteries

    International Nuclear Information System (INIS)

    There is growing interest in high specific energy lithium rechargeable batteries with improved discharge/charge cycles. Some of the promising battery systems under development are Li/CoO2, Li/V2O5 and Li/MnO2. A major factor that controls the specific performance of these batteries is the electrolyte. Recent advances made in the liquid electrolyte area for lithium high energy cathode systems are reviewed. Experimental work on the processing of solid thin film polymer electrolytes using plasticizers such as polyethylene glycol dimethoxy ether (PEGDME) and the properties such as conductivity and differential scanning calorimetry of polymer film electrolytes are presented. The advantages and the disadvantages of polymer thin film electrolytes are discussed

  6. State of health detection for Lithium ion batteries in photovoltaic system

    International Nuclear Information System (INIS)

    Highlights: ► DC resistances of batteries. ► Fuzzy logic inference. ► SOH detection for battery. - Abstract: In many photovoltaic systems, rechargeable batteries are required to even out irregularities in solar irradiation. However, the health conditions of the batteries are crucial for the reliability of the overall system. In this paper, the equivalent DC resistances of Lithium ion battery cells of various health conditions during charging under different temperatures have been collected and the relationships between equivalent DC resistance, health condition and working temperature have been identified. The equivalent DC resistance can easily be obtained during the charging period of a battery by switching off the charging current periodically for a very short duration of time. A simple and effective battery charger with state of health (SOH) detection for Lithium ion battery cell has been developed based on the identified equivalent DC resistance. Experimental results are included to demonstrate the effectiveness of the proposed SOH determination scheme.

  7. Prospect of MH-Ni Batteries Development

    Institute of Scientific and Technical Information of China (English)

    Xu Shaoping; Xing Zhiqiang; Liang Wanlong; Ma Yijun

    2004-01-01

    The development trend and promising application prospects of high-power MH-Ni battery were reviewed by studying and comparing the current high-power batteries research area.High-power MH-Ni batiery has good performlife with 500 ~ 1000 times, abundant material resource, especially abundant rare earth resource in China, high-rate discharging, rapid charging, good safety as well as no pollution, etc., which is regarded as the most promising storage battery for electric vehicles.The performance of high power MH-Ni battery can be brought into play fully and ensure electric vehicles performance if it is equipped with appropriate chargers, controlling system and electric motors.Facing opportunities and challenges, MH-Ni battery has promising application prospects on hybrid electric automobile, electric bicycle and a variety of small sized electric vehicles by improving its technology constantly and developing market actively.

  8. Battery selection for Space Shuttle experiments

    Science.gov (United States)

    Francisco, David R.

    1993-04-01

    This paper will delineate the criteria required for the selection of batteries as a power source for space experiments. Four basic types of batteries will be explored, lead acid, silver zinc, alkaline manganese, and nickel cadmium. A detailed description of the lead acid and silver zinc cells and a brief exploration of the alkaline manganese and nickel cadmium will be given. The factors involved in battery selection such as packaging, energy density, discharge voltage regulation, and cost will be thoroughly examined. The pros and cons of each battery type will be explored. Actual laboratory test data acquired for the lead acid and silver zinc cell will be discussed. This data will include discharging under various temperature conditions, after three months of storage, and with different types of loads. The lifetime and number of charge/discharge cycles will also be discussed. A description of the required maintenance for each type of battery will be investigated.

  9. Performance Simulation Of Photovoltaic System Battery

    OpenAIRE

    O. A. Babatunde; M. B. Shitta

    2014-01-01

    Solar energy, despite being inexhaustible, has a major shortcoming; it is intermittent. As a result, there's a need for it to be stored for later use. The widely used energy storage in photovoltaic system applications is the lead-acid battery and the knowledge of its state-of-charge (SOC) is important in effecting efficient control and energy management. However, SOC cannot be measured while the battery is connected to the system. This study adjusts and validates two estimation models: batter...

  10. Batteries for Electric Vehicles

    Science.gov (United States)

    Conover, R. A.

    1985-01-01

    Report summarizes results of test on "near-term" electrochemical batteries - (batteries approaching commercial production). Nickel/iron, nickel/zinc, and advanced lead/acid batteries included in tests and compared with conventional lead/acid batteries. Batteries operated in electric vehicles at constant speed and repetitive schedule of accerlerating, coasting, and braking.

  11. Complete Charging for Piezoelectric Energy Harvesting System

    Institute of Scientific and Technical Information of China (English)

    樊康旗; 徐春辉; 王卫东

    2014-01-01

    Under an in-phase assumption, the complete charging for an energy harvesting system is studied, which consists of a piezoelectric energy harvester (PEH), a bridge rectifier, a filter capacitor, a switch, a controller and a rechargeable battery. For the transient charging, the results indicate that the voltage across the filter capacitor increases as the charging proceeds, which is consistent with that reported in the literature. However, a new finding shows that the charging rate and energy harvesting efficiency decrease over time after their respective peak values are acquired. For the steady-state charging, the results reveal that the energy harvesting efficiency can be adjusted by altering the critical charging voltage that controls the transition of the system. The optimal energy harvesting efficiency is limited by the optimal efficiency of the transient charging. Finally, the relationship between the critical charging voltage and the equivalent resistance of the controller and rechargeable battery is established explicitly.

  12. Battery Management Systems in Electric and Hybrid Vehicles

    Directory of Open Access Journals (Sweden)

    Michael Pecht

    2011-10-01

    Full Text Available The battery management system (BMS is a critical component of electric and hybrid electric vehicles. The purpose of the BMS is to guarantee safe and reliable battery operation. To maintain the safety and reliability of the battery, state monitoring and evaluation, charge control, and cell balancing are functionalities that have been implemented in BMS. As an electrochemical product, a battery acts differently under different operational and environmental conditions. The uncertainty of a battery’s performance poses a challenge to the implementation of these functions. This paper addresses concerns for current BMSs. State evaluation of a battery, including state of charge, state of health, and state of life, is a critical task for a BMS. Through reviewing the latest methodologies for the state evaluation of batteries, the future challenges for BMSs are presented and possible solutions are proposed as well.

  13. Advances in understanding mechanisms underpinning lithium-air batteries

    Science.gov (United States)

    Aurbach, Doron; McCloskey, Bryan D.; Nazar, Linda F.; Bruce, Peter G.

    2016-09-01

    The rechargeable lithium-air battery has the highest theoretical specific energy of any rechargeable battery and could transform energy storage if a practical device could be realized. At the fundamental level, little was known about the reactions and processes that take place in the battery, representing a significant barrier to progress. Here, we review recent advances in understanding the chemistry and electrochemistry that govern the operation of the lithium-air battery, especially the reactions at the cathode. The mechanisms of O2 reduction to Li2O2 on discharge and the reverse process on charge are discussed in detail, as are their consequences for the rate and capacity of the battery. The various parasitic reactions involving the cathode and electrolyte during discharge and charge are also considered. We also provide views on understanding the stability of the cathode and electrolyte and examine design principles for better lithium-air batteries.

  14. Innovation Meets Performance Demands of Advanced Lithium-ion Batteries

    Energy Technology Data Exchange (ETDEWEB)

    2016-06-01

    Advancements in high capacity and low density battery technologies have led to a growing need for battery materials with greater charge capacity and therefore stability. NREL's developments in ALD and molecular layer MLD allow for thin film coatings to battery composite electrodes, which can improve battery lifespan, high charge capacity, and stability. Silicon, one of the best high-energy anode materials for Li-ion batteries, can experience capacity fade from volumetric expansion. Using MLD to examine how surface modification could stabilize silicon anode material in Li-ion batteries, researchers discovered a new reaction precursor that leads to a flexible surface coating that accommodates volumetric expansion of silicon electrodes.

  15. Advances in understanding mechanisms underpinning lithium–air batteries

    Science.gov (United States)

    Aurbach, Doron; McCloskey, Bryan D.; Nazar, Linda F.; Bruce, Peter G.

    2016-09-01

    The rechargeable lithium–air battery has the highest theoretical specific energy of any rechargeable battery and could transform energy storage if a practical device could be realized. At the fundamental level, little was known about the reactions and processes that take place in the battery, representing a significant barrier to progress. Here, we review recent advances in understanding the chemistry and electrochemistry that govern the operation of the lithium–air battery, especially the reactions at the cathode. The mechanisms of O2 reduction to Li2O2 on discharge and the reverse process on charge are discussed in detail, as are their consequences for the rate and capacity of the battery. The various parasitic reactions involving the cathode and electrolyte during discharge and charge are also considered. We also provide views on understanding the stability of the cathode and electrolyte and examine design principles for better lithium–air batteries.

  16. Optimization of batteries for plug-in hybrid electric vehicles

    Science.gov (United States)

    English, Jeffrey Robb

    This thesis presents a method to quickly determine the optimal battery for an electric vehicle given a set of vehicle characteristics and desired performance metrics. The model is based on four independent design variables: cell count, cell capacity, state-of-charge window, and battery chemistry. Performance is measured in seven categories: cost, all-electric range, maximum speed, acceleration, battery lifetime, lifetime greenhouse gas emissions, and charging time. The performance of each battery is weighted according to a user-defined objective function to determine its overall fitness. The model is informed by a series of battery tests performed on scaled-down battery samples. Seven battery chemistries were tested for capacity at different discharge rates, maximum output power at different charge levels, and performance in a real-world automotive duty cycle. The results of these tests enable a prediction of the performance of the battery in an automobile. Testing was performed at both room temperature and low temperature to investigate the effects of battery temperature on operation. The testing highlighted differences in behavior between lithium, nickel, and lead based batteries. Battery performance decreased with temperature across all samples with the largest effect on nickel-based chemistries. Output power also decreased with lead acid batteries being the least affected by temperature. Lithium-ion batteries were found to be highly efficient (>95%) under a vehicular duty cycle; nickel and lead batteries have greater losses. Low temperatures hindered battery performance and resulted in accelerated failure in several samples. Lead acid, lead tin, and lithium nickel alloy batteries were unable to complete the low temperature testing regime without losing significant capacity and power capability. This is a concern for their applicability in electric vehicles intended for cold climates which have to maintain battery temperature during long periods of inactivity

  17. A nanoview of battery operation

    DEFF Research Database (Denmark)

    Schougaard, Steen Brian

    2016-01-01

    The redox-active materials in lithium-ion batteries have relatively poor electronic and ionic conduction and may experience stress from charge-discharge volume changes, so their formulation into structures with nanosized features is highly desirable. On page 566 of this issue, Lim et al. (1......) characterize individual nanoparticles of the positive electrode material LiFePO4 during charging and discharging. This “in operando” technique ensures that all particles experience the same voltage. The current and lithium concentration are then inferred for individual particles via the change in Fe oxidation...

  18. Environmental consequences of the use of batteries in low carbon systems: The impact of battery production

    International Nuclear Information System (INIS)

    Highlights: ► Lithium based batteries show the most significant GHG and metal depletion impacts. ► Nickel metal hydride batteries perform worst in terms of cumulative energy demand. ► Charge and discharge cycles will have significant effect on the environmental impact. ► Limited data on the life cycle impacts of some types of batteries is available. - Abstract: Adoption of small scale micro-generation is sometimes coupled with the use of batteries in order to overcome daily variability in the supply and demand of energy. For example, photovoltaic cells and small wind turbines can be coupled with energy storage systems such as batteries. When used effectively with renewable energy production, batteries can increase the versatility of an energy system by providing energy storage that enables the systems to satisfy the highly variable electrical load of an individual dwelling, therefore changing usage patterns on the national grid. A significant shift towards electric or hybrid cars would also increase the number of batteries required. However, batteries can be inefficient and comprise of materials that have high environmental and energy impacts. In addition, some materials, such as lithium, are scarce natural resources. As a result, the overall impact of increasing our reliance on such “sustainable or “low carbon” systems may in fact have an additional detrimental impact. This paper reviews the currently available data and calculated and highlights the impact of the production of several types of battery in terms of energy, raw materials and greenhouse gases. The impact of the production of batteries is examined and presented in order that future studies may be able to include the impact of batteries more easily within any system. It is shown that lithium based batteries have the most significant impact in many environmental areas in terms of production. As the use phases of batteries are extremely variable within different situations this has not been

  19. Redox reactions with empirical potentials: Atomistic battery discharge simulations

    OpenAIRE

    Dapp, Wolf B.; Müser, Martin H.

    2013-01-01

    Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a whole microscopically. Our focus lies on phenomena occurring at the electrode-electrolyte interface which are not easily studied with other methods. We use the redox split-charge equilibration (redoxSQE) method that assigns a discrete ionization state to each ...

  20. Upscaling Approaches for Nonlinear Processes in Lithium-Ion Batteries

    OpenAIRE

    Taralova, Vasilena

    2015-01-01

    Lithium-ion batteries are broadly used nowadays in all kinds of portable electronics, such as laptops, cell phones, tablets, e-book readers, digital cameras, etc. They are preferred to other types of rechargeable batteries due to their superior characteristics, such as light weight and high energy density, no memory effect, and a big number of charge/discharge cycles. The high demand and applicability of Li-ion batteries naturally give rise to the unceasing necessity of developing better batt...

  1. Battery Cell Voltage Sensing and Balancing Using Addressable Transformers

    Science.gov (United States)

    Davies, Francis

    2009-01-01

    A document discusses the use of saturating transformers in a matrix arrangement to address individual cells in a high voltage battery. This arrangement is able to monitor and charge individual cells while limiting the complexity of circuitry in the battery. The arrangement has inherent galvanic isolation, low cell leakage currents, and allows a single bad cell in a battery of several hundred cells to be easily spotted.

  2. Sodium-Oxygen Battery: Steps Toward Reality.

    Science.gov (United States)

    Landa-Medrano, Imanol; Li, Chunmei; Ortiz-Vitoriano, Nagore; Ruiz de Larramendi, Idoia; Carrasco, Javier; Rojo, Teófilo

    2016-04-01

    Rechargeable metal-oxygen batteries are receiving significant interest as a possible alternative to current state of the art lithium ion batteries due to their potential to provide higher gravimetric energies, giving significantly lighter or longer-lasting batteries. Recent advances suggest that the Na-O2 battery, in many ways analogous to Li-O2 yet based on the reversible formation of sodium superoxide (NaO2), has many advantages such as a low charge overpotential (∼100 mV) resulting in improved efficiency. In this Perspective, we discuss the current state of knowledge in Na-O2 battery technology, with an emphasis on the latest experimental studies, as well as theoretical models. We offer special focus on the principle outstanding challenges and issues and address the advantages/disadvantages of the technology when compared with Li-O2 batteries as well as other state-of-the-art battery technologies. We finish by detailing the direction required to make Na-O2 batteries both commercially and technologically viable. PMID:26961215

  3. Computer formation of sealed lead/acid batteries

    Science.gov (United States)

    Mills, John A.

    The desire of many companies to enter the growing market of valve-regulated batteries (also known as sealed lead/acid) requires a higher level of control in virtually all the stages of manufacture. Formation charging and charge conditioning is a particular case in point. Whether the valve-regulated battery is of the starved-electrolyte or gelled-electrolyte type, the final stages of formation and charge conditioning require careful attention to control the cell voltage. Charge rates that exceed the oxygen-recombination rate will cause excess gassing and thus reduce the available electrolyte. This, in turn, reduces battery life and, in the case of gelled-electrolyte batteries, causes improper cracking of the gell and concomitant reduction in capacity, performance and life. Valve-regulated batteries require charging equipment that can automatically regulate charge/discharge current and voltage. Given the requirement for multiple steps of battery conditioning, computer control provides a totally effective way to control the voltage, current, time, ampere hours and charge/discharge functions without operator assistance.

  4. Nickel cadmium battery evaluation, modeling, and application in an electric vehicle

    Science.gov (United States)

    Lynch, William Alfred

    A battery testing facility was set up in the battery evaluation laboratory. This system includes a set of current regulators which were fabricated in the UMASS. Lowell labs and a PC based data acquisition system. Batteries were charged or discharged at any rate within system ratings, and data including battery voltage, current, temperature and impedance were stored by a PC. STM5.140 type nickel-cadmium electric vehicle batteries were subjected to various test procedures using the battery testing facility. The results from these tests were used to determine battery characteristics. An electrical component battery model was also developed using the test data. The validity of the battery model was verified through experimental testing, and it was found to be accurate. Additionally, improved battery charging algorithms were developed which resulted in significant improvements in battery efficiency. Electric car operation with STM5.140 type of batteries was evaluated. Realistic road test data were analyzed experimentally and using the battery model. No battery abuse was found under EV driving conditions. The performance of the STM5.140 battery under abuse conditions was evaluated and it was found that it performs reasonably well under all abuse conditions tested. The model and test methodologies may be incorporated into complete electric vehicle models in order to assist in the design and operation of current and future electric vehicles.

  5. Lithium-Ion Battery Cell-Balancing Algorithm for Battery Management System Based on Real-Time Outlier Detection

    OpenAIRE

    Changhao Piao; Zhaoguang Wang; Ju Cao; Wei Zhang; Sheng Lu

    2015-01-01

    A novel cell-balancing algorithm which was used for cell balancing of battery management system (BMS) was proposed in this paper. Cell balancing algorithm is a key technology for lithium-ion battery pack in the electric vehicle field. The distance-based outlier detection algorithm adopted two characteristic parameters (voltage and state of charge) to calculate each cell’s abnormal value and then identified the unbalanced cells. The abnormal and normal type of battery cells were acquired by on...

  6. Battery prices and capacity sensitivity: Electric drive vehicles

    DEFF Research Database (Denmark)

    Juul, Nina

    2012-01-01

    the next decade or two. These vehicles can provide some of the flexibility needed in the power system, in terms of both flexible demand and electricity storage. However, what are the batteries worth to the power system? And does the value depend on battery capacity? This article presents an analysis...... of the integrated power and transport system, focusing on the sensitivity of the power system configuration according to battery capacity and price of the electric drive vehicle. The value of different battery capacities is estimated, given that the batteries are used for both driving and storage. Likewise......, the prices at which the electric drive vehicles become of interest to the power system are found. Smart charge, including the opportunity to discharge (vehicle-to-grid) is used in all scenarios. Analyses show that the marginal benefits decrease the larger the battery. For very high battery prices, large...

  7. Cell overcharge testing inside sodium metal halide battery

    Science.gov (United States)

    Frutschy, Kris; Chatwin, Troy; Bull, Roger

    2015-09-01

    Testing was conducted to measure electrical performance and safety of the General Electric Durathon™ E620 battery module (600 V class 20 kWh) during cell overcharge. Data gathered from this test was consistent with SAE Electric Vehicle Battery Abuse Testing specification J2464 [1]. After cell overcharge failure and 24 A current flow for additional 60 minutes, battery was then discharged at 7.5 KW average power to 12% state of charge (SOC) and recharged back to 100% SOC. This overcharging test was performed on two cells. No hydrogen chloride (HCl) gas was detected during front cell (B1) test, and small amount (6.2 ppm peak) was measured outside the battery after center cell (F13) overcharge. An additional overcharge test was performed per UL Standard 1973 - Batteries for Use in Light Electric Rail (LER) Applications and Stationary Applications[2]. With the battery at 11% SOC and 280 °C float temperature, an individual cell near the front (D1) was deliberately imbalanced by charging it to 62% SOC. The battery was then recharged to 100% SOC. In all three tests, the battery cell pack was stable and individual cell failure did not propagate to other cells. Battery discharge performance, charge performance, and electrical isolation were normal after all three tests.

  8. Perancangan Solar Charge Controller dan Inverter pada Aplikasi Solar Panel Berbasis Atmega8535 secara Software

    OpenAIRE

    Larasati, Devi

    2015-01-01

    The purpose of this final project is to apply the codevision AVR ATMega 8535 to process the data on the storage accumulator battery charging current from the solar panels. Value current is processed in the microcontroller is in the current detection using current sensor ACS-712. To prevent backflow from batteries to solar panels when the solar panel voltage is less than accumulator battery voltage, current flows from the solar panels through solar charge controller to the battery before. C...

  9. High energy density battery based on complex hydrides

    Science.gov (United States)

    Zidan, Ragaiy

    2016-04-26

    A battery and process of operating a battery system is provided using high hydrogen capacity complex hydrides in an organic non-aqueous solvent that allows the transport of hydride ions such as AlH.sub.4.sup.- and metal ions during respective discharging and charging steps.

  10. Reinforced Positive Filler Paste For Lead/Acid Batteries

    Science.gov (United States)

    Edwards, Dean B.; Rippel, Wally E.

    1991-01-01

    Lead-coated glass fibers extend battery life. Mixture of lead-coated glass fibers and positive paste form pellets of active material between grid wires of positive battery electrode. Fibers contribute to charge capacity, electrical conductivity, and mechanical stability of electrode.

  11. Battery, especially for portable devices, has an anode containing silicon

    NARCIS (Netherlands)

    Kan, S.Y.

    2002-01-01

    The anode (2) contains silicon. A battery with a silicon-containing anode is claimed. An Independent claim is also included for a method used to make the battery, comprising the doping of a silicon substrate (1) with charge capacity-increasing material (preferably boron, phosphorous or arsenic), etc

  12. 46 CFR 129.350 - Batteries-general.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Batteries-general. 129.350 Section 129.350 Shipping... INSTALLATIONS Power Sources and Distribution Systems § 129.350 Batteries—general. (a) Wherever a battery is charged, there must be natural or induced ventilation to dissipate the gases generated. (b) Each...

  13. 46 CFR 183.350 - Batteries-general.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 7 2010-10-01 2010-10-01 false Batteries-general. 183.350 Section 183.350 Shipping...) ELECTRICAL INSTALLATION Power Sources and Distribution Systems § 183.350 Batteries—general. (a) Where provisions are made for charging batteries, there must be natural or induced ventilation sufficient...

  14. 46 CFR 120.350 - Batteries-general.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Batteries-general. 120.350 Section 120.350 Shipping... and Distribution Systems § 120.350 Batteries—general. (a) Where provisions are made for charging batteries, there must be natural or induced ventilation sufficient to dissipate the gases generated....

  15. How Things Work: What is the Secret of "Maintenance-Free" Car Batteries?

    Science.gov (United States)

    Crane, H. Richard, Ed.

    1985-01-01

    Explains "maintenance free" car batteries which do not involve any changes in principles from traditional car batteries (which require the addition of distilled water). The newer systems have reduced water loss to near zero by improvements in the batteries themselves and in the electrical systems which charge them. (JN)

  16. Thermal behavior simulation of Ni/MH battery

    Institute of Scientific and Technical Information of China (English)

    LI DaHe; YANG Kai; CHEN Shi; WU Feng

    2009-01-01

    Thermal behavior of overcharged Ni/MH battery is studied with microcalorimeter. The battery Is in-stalled in a special device in a microcslorimeter with a quartz frequency thermometer. Quantity of heat and heat capacity of the battery charged at different state of charge (SOC) st different rates are meas-ured by the microcalorimeter. Based on a series of aseumputions, heat transfer equation is set up. Ex-pression of heat generation is attained by curve fitting instead of theoretical calculation. Thermal model is used to simulate thermal behavior of the battery in charging period, results of calculation and expe-riment match very well. The temperature distribution is non-uniform because the poor conductivity limits the heat transfer during charging process. It is difficult to greatly improve the heat conductivity of the battery because it is related to materials inside the battery including electrodes, separators and so on. Therefore, high rate charge should be avoided in actual use. It may cause some damage to the battery.

  17. Characterization testing of a 40 Ahr bipolar nickel hydrogen battery

    Science.gov (United States)

    Brewer, Jeffrey C.; Manzo, Michelle A.; Gahn, Randall F.

    1989-01-01

    In a continuing effort to develop NiH2 bipolar technology to a point where it can be used efficiently in space flight, testing of a second 40 Ahr, 10-cell bipolar battery has begun. This battery has undergone extensive characterization testing to determine the effects of such operating parameters as charge and discharge rates, temperature, and pressure. The fundamental design of this actively cooled bipolar battery is the same as the first battery. Most of the individual components, however, are from different manufacturers. Different testing procedures as well as certain unique battery characteristics make it difficult to directly compare the two sets of results. In general, the performance of this battery throughout characterization produced expected results. The main differences seen between the first and second batteries occurred during the high-rate discharge portion of the test matrix. The first battery also had poor high-rate discharge results, although better than those of the second battery. Minor changes were made to the battery frame design used for the first battery in an attempt to allow better gas access to the reaction sites for the second build and hopefully improve performance. The changes, however, did not improve the performance of the second battery and could have possibly contributed to the poorer performance that was observed. There are other component differences that could have contributed to the poorer performance of the second battery. The H2 electrode in the second battery was constructed with a Goretex backing which could have limited the high-rate current flow. The gas screen in the second battery had a larger mesh which again could have limited the high-rate current flow. Small scale 2 x 2 batteries are being tested to evaluate the effects of the component variations.

  18. Materials for Lithium Batteries Prepared via Mechanochemical Route

    Institute of Scientific and Technical Information of China (English)

    N.V.Kosova

    2007-01-01

    1 Results Nanostructured materials are currently of interest for lithium-ion batteries due to relevant demands for high-rate performance batteries and the aspect of structural stability (reversibility) under charge-discharge processes.Decreasing of particle size facilitates the reducing of diffuse paths for lithium ions as compared with micron-sized materials and the increasing of surface contact between electrode and electrolyte leading to acceleration of ionic transport and of charge-discharge process...

  19. Collecting battery data with Open Battery

    OpenAIRE

    Jones, Gareth L.; Harrison, Peter G.

    2012-01-01

    In this paper we present Open Battery, a tool for collecting data on mobile phone battery usage, describe the data we have collected so far and make some observations. We then introduce the fluid queue model which we hope may prove a useful tool in future work to describe mobile phone battery traces.

  20. A Thermal Runaway Simulation on a Lithium Titanate Battery and the Battery Module

    Directory of Open Access Journals (Sweden)

    Man Chen

    2015-01-01

    Full Text Available Based on the electrochemical and thermal model, a coupled electro-thermal runaway model was developed and implemented using finite element methods. The thermal decomposition reactions when the battery temperature exceeds the material decomposition temperature were embedded into the model. The temperature variations of a lithium titanate battery during a series of charge-discharge cycles under different current rates were simulated. The results of temperature and heat generation rate demonstrate that the greater the current, the faster the battery temperature is rising. Furthermore, the thermal influence of the overheated cell on surrounding batteries in the module was simulated, and the variation of temperature and heat generation during thermal runaway was obtained. It was found that the overheated cell can induce thermal runaway in other adjacent cells within 3 mm distance in the battery module if the accumulated heat is not dissipated rapidly.

  1. Directly connected series coupled HTPEM fuel cell stacks to a Li-ion battery DC bus for a fuel cell electrical vehicle

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Ashworth, Leanne; Remón, Ian Natanael;

    2008-01-01

    The work presented in this paper examines the use of pure hydrogen fuelled high temperature polymer electrolyte membrane (HTPEM) fuel cell stacks in an electrical car, charging a Li-ion battery pack. The car is equipped with two branches of two series coupled 1 kW fuel cell stacks which...... are connected directly parallel to the battery pack during operation. This enables efficient charging of the batteries for increased driving range. With no power electronics used, the fuel cell stacks follow the battery pack voltage, and charge the batteries passively. This saves the electrical and economical...... losses related to these components and their added system complexity. The new car battery pack consists of 23 Li-ion battery cells and the charging and discharging are monitored by a battery management system (BMS) which ensures safe operating conditions for the batteries. The direct connection...

  2. A Thermal Runaway Simulation on a Lithium Titanate Battery and the Battery Module

    OpenAIRE

    Man Chen; Qiujuan Sun; Yongqi Li; Ke Wu; Bangjin Liu; Peng Peng; Qingsong Wang

    2015-01-01

    Based on the electrochemical and thermal model, a coupled electro-thermal runaway model was developed and implemented using finite element methods. The thermal decomposition reactions when the battery temperature exceeds the material decomposition temperature were embedded into the model. The temperature variations of a lithium titanate battery during a series of charge-discharge cycles under different current rates were simulated. The results of temperature and heat generation rate demonstra...

  3. Battery charger for solar cells; Chargeur de batterie pour cellules solaires

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2004-09-01

    The main drawback of solar energy concerns its availability and its intensity variations due to the changes in the clouds cover. For a maximum availability, a photovoltaic power supplies must be connected to a battery. Such an association requires a particular circuit for the management of the battery charging and of the energy conversion whatever the lighting conditions. This article describes the scheme of such a circuit. (J.S.)

  4. Online Parameter Estimation of the Ni-MH Batteries Based on Statistical Methods

    Directory of Open Access Journals (Sweden)

    Gai-hui Lei

    2010-02-01

    Full Text Available Based on the application of the power batteries, this paper uses a statistical method to estimate the internal resistance and open-circuit voltage of Ni-MH battery. Battery status is monitored and simulated by battery pack test bench. Through using ideal battery model and fitting the data of measured voltage and current, the battery internal resistance and open-circuit voltage are estimated. The average relative error between battery statistic internal resistance and pulse internal resistance is less than 15% in different state of charge. Relative error is influenced by dispersion and symmetry of charge or discharge current. Average of absolute error in open-circuit voltage is about 5% respectively. The results show that it is feasible and accurate to estimate the parameters of Ni-MH battery by using statistical method.

  5. Surface Modification for Metal Hydride Electrode of Ni/MH Battery

    Institute of Scientific and Technical Information of China (English)

    YANG Kai; WU Feng; LI Li; CHEN Shi

    2005-01-01

    A novel method was applied to the surface modification of the metal hydride (MH) electrode of the Ni/MH battery. The electrode was plated with a thin silver film by using plasma technology and its effect on the performance of the Ni/MH battery was examined. Charge-discharge test proved that the battery with modified electrode exhibits a better high-rate dischargeability and chargeability than the battery with untreated electrode. The battery with modified electrode exhibits satisfactory durability. After 500 cycles, the capacities of the batteries with modified and unmodified electrode are 90.1% and 82.3% of their original capacities. The inner pressure test shows that the battery with modified electrode displays a much lower inner gas pressure on charging. The experimental results demonstrate that this method is an effective way for the surface modification of the electrode of the Ni/MH battery.

  6. Second life battery energy storage system for enhancing renewable energy grid integration

    DEFF Research Database (Denmark)

    Koch-Ciobotaru, C.; Saez-de-Ibarra, A.; Martinez-Laserna, E.;

    2015-01-01

    must be explored especially that large battery energy storage systems are still expensive solutions. Thus, in order to make battery investment economic viable, the use of second life batteries is investigated in the present work. This paper proposes a method for determining firstly, the optimal rating...... of a second life battery energy storage system (SLBESS) and secondly, to obtain the power exchange and battery state of charge profiles during the operation. These will constitute the cycling patterns for testing batteries and studying the ageing effect of this specific application. Real data from the Spanish...

  7. Lithium Ion Batteries

    Science.gov (United States)

    1997-01-01

    Lithium ion batteries, which use a new battery chemistry, are being developed under cooperative agreements between Lockheed Martin, Ultralife Battery, and the NASA Lewis Research Center. The unit cells are made in flat (prismatic) shapes that can be connected in series and parallel to achieve desired voltages and capacities. These batteries will soon be marketed to commercial original-equipment manufacturers and thereafter will be available for military and space use. Current NiCd batteries offer about 35 W-hr/kg compared with 110 W-hr/kg for current lithium ion batteries. Our ultimate target for these batteries is 200 W-hr/kg.

  8. Assembly and performance of hybrid-VRLA cells and batteries

    OpenAIRE

    Martha, SK; Hariprakash, B; Gaffoor, SA; Ambalavanan, S; Shukla, AK

    2005-01-01

    Several commercial-grade hybrid-VRLA and AGM-VRLA cells and batteries have been assembled and tested under varying charge-discharge rates in a temperature range between 50 and -40 degrees C. Impedance studies on hybrid-VRLA and AGM-VRLA cells have been conducted to reflect on their resistive and capacitive values. A linear relationship is found to exist between logarithmic state-of-charge values and ohmic impedance of batteries. In general, hybrid-VRLA cells and batteries perform better than ...

  9. Hierarchically structured materials for lithium batteries

    International Nuclear Information System (INIS)

    The lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles, including solely battery powered vehicles, plug-in hybrid electric vehicles, and hybrid electric vehicles. With the increasing demand for devices of high-energy densities (>500 Wh kg−1), new energy storage systems, such as lithium–oxygen (Li–O2) batteries and other emerging systems beyond the conventional LIB, have attracted worldwide interest for both transportation and grid energy storage applications in recent years. It is well known that the electrochemical performance of these energy storage systems depends not only on the composition of the materials, but also on the structure of the electrode materials used in the batteries. Although the desired performance characteristics of batteries often have conflicting requirements with the micro/nano-structure of electrodes, hierarchically designed electrodes can be tailored to satisfy these conflicting requirements. This work will review hierarchically structured materials that have been successfully used in LIB and Li–O2 batteries. Our goal is to elucidate (1) how to realize the full potential of energy materials through the manipulation of morphologies, and (2) how the hierarchical structure benefits the charge transport, promotes the interfacial properties and prolongs the electrode stability and battery lifetime. (paper)

  10. The Shortest Path Problems in Battery-Electric Vehicle Dispatching with Battery Renewal

    Directory of Open Access Journals (Sweden)

    Minfang Huang

    2016-06-01

    Full Text Available Electric vehicles play a key role for developing an eco-sustainable transport system. One critical component of an electric vehicle is its battery, which can be quickly charged or exchanged before it runs out. The problem of electric vehicle dispatching falls into the category of the shortest path problem with resource renewal. In this paper, we study the shortest path problems in (1 electric transit bus scheduling and (2 electric truck routing with time windows. In these applications, a fully-charged battery allows running a limited operational distance, and the battery before depletion needs to be quickly charged or exchanged with a fully-charged one at a battery management facility. The limited distance and battery renewal result in a shortest path problem with resource renewal. We develop a label-correcting algorithm with state space relaxation to find optimal solutions. In the computational experiments, real-world road geometry data are used to generate realistic travel distances, and other types of data are obtained from the real world or randomly generated. The computational results show that the label-correcting algorithm performs very well.

  11. Submerged AUV Charging Station

    Science.gov (United States)

    Jones, Jack A.; Chao, Yi; Curtin, Thomas

    2014-01-01

    Autonomous Underwater Vehicles (AUVs) are becoming increasingly important for military surveillance and mine detection. Most AUVs are battery powered and have limited lifetimes of a few days to a few weeks. This greatly limits the distance that AUVs can travel underwater. Using a series of submerged AUV charging stations, AUVs could travel a limited distance to the next charging station, recharge its batteries, and continue to the next charging station, thus traveling great distances in a relatively short time, similar to the Old West “Pony Express.” One solution is to use temperature differences at various depths in the ocean to produce electricity, which is then stored in a submerged battery. It is preferred to have the upper buoy submerged a reasonable distance below the surface, so as not to be seen from above and not to be inadvertently destroyed by storms or ocean going vessels. In a previous invention, a phase change material (PCM) is melted (expanded) at warm temperatures, for example, 15 °C, and frozen (contracted) at cooler temperatures, for example, 8 °C. Tubes containing the PCM, which could be paraffin such as pentadecane, would be inserted into a container filled with hydraulic oil. When the PCM is melted (expanded), it pushes the oil out into a container that is pressurized to about 3,000 psi (approx equals 20.7 MPa). When a valve is opened, the high-pressure oil passes through a hydraulic motor, which turns a generator and charges a battery. The low-pressure oil is finally reabsorbed into the PCM canister when the PCM tubes are frozen (contracted). Some of the electricity produced could be used to control an external bladder or a motor to the tether line, such that depth cycling is continued for a very long period of time. Alternatively, after the electricity is generated by the hydraulic motor, the exiting low-pressure oil from the hydraulic motor could be vented directly to an external bladder on the AUV, such that filling of the bladder

  12. Exploring the Model Design Space for Battery Health Management

    Science.gov (United States)

    Saha, Bhaskar; Quach, Cuong Chi; Goebel, Kai Frank

    2011-01-01

    Battery Health Management (BHM) is a core enabling technology for the success and widespread adoption of the emerging electric vehicles of today. Although battery chemistries have been studied in detail in literature, an accurate run-time battery life prediction algorithm has eluded us. Current reliability-based techniques are insufficient to manage the use of such batteries when they are an active power source with frequently varying loads in uncertain environments. The amount of usable charge of a battery for a given discharge profile is not only dependent on the starting state-of-charge (SOC), but also other factors like battery health and the discharge or load profile imposed. This paper presents a Particle Filter (PF) based BHM framework with plug-and-play modules for battery models and uncertainty management. The batteries are modeled at three different levels of granularity with associated uncertainty distributions, encoding the basic electrochemical processes of a Lithium-polymer battery. The effects of different choices in the model design space are explored in the context of prediction performance in an electric unmanned aerial vehicle (UAV) application with emulated flight profiles.

  13. Solar-rechargeable battery based on photoelectrochemical water oxidation: Solar water battery.

    Science.gov (United States)

    Kim, Gonu; Oh, Misol; Park, Yiseul

    2016-01-01

    As an alternative to the photoelectrochemical water splitting for use in the fuel cells used to generate electrical power, this study set out to develop a solar energy rechargeable battery system based on photoelectrochemical water oxidation. We refer to this design as a "solar water battery". The solar water battery integrates a photoelectrochemical cell and battery into a single device. It uses a water oxidation reaction to simultaneously convert and store solar energy. With the solar water battery, light striking the photoelectrode causes the water to be photo-oxidized, thus charging the battery. During the discharge process, the solar water battery reduces oxygen to water with a high coulombic efficiency (>90%) and a high average output voltage (0.6 V). Because the reduction potential of oxygen is more positive [E(0) (O2/H2O) = 1.23 V vs. NHE] than common catholytes (e.g., iodide, sulfur), a high discharge voltage is produced. The solar water battery also exhibits a superior storage ability, maintaining 99% of its specific discharge capacitance after 10 h of storage, without any evidence of self-discharge. The optimization of the cell design and configuration, taking the presence of oxygen in the cell into account, was critical to achieving an efficient photocharge/discharge. PMID:27629362

  14. Solar-rechargeable battery based on photoelectrochemical water oxidation: Solar water battery.

    Science.gov (United States)

    Kim, Gonu; Oh, Misol; Park, Yiseul

    2016-01-01

    As an alternative to the photoelectrochemical water splitting for use in the fuel cells used to generate electrical power, this study set out to develop a solar energy rechargeable battery system based on photoelectrochemical water oxidation. We refer to this design as a "solar water battery". The solar water battery integrates a photoelectrochemical cell and battery into a single device. It uses a water oxidation reaction to simultaneously convert and store solar energy. With the solar water battery, light striking the photoelectrode causes the water to be photo-oxidized, thus charging the battery. During the discharge process, the solar water battery reduces oxygen to water with a high coulombic efficiency (>90%) and a high average output voltage (0.6 V). Because the reduction potential of oxygen is more positive [E(0) (O2/H2O) = 1.23 V vs. NHE] than common catholytes (e.g., iodide, sulfur), a high discharge voltage is produced. The solar water battery also exhibits a superior storage ability, maintaining 99% of its specific discharge capacitance after 10 h of storage, without any evidence of self-discharge. The optimization of the cell design and configuration, taking the presence of oxygen in the cell into account, was critical to achieving an efficient photocharge/discharge.

  15. Parameter Analysis Method for Lithium-ion Battery Circuit Model and State of Charge Estimation%锂电池模型参数估计与荷电状态估算研究

    Institute of Scientific and Technical Information of China (English)

    张东华; 马燕; 陈思琪; 朱国荣; 陈伟

    2015-01-01

    Data of 45Ah LiFePO4 Li-ion battery characteristics was collected and analyzed.The mathematical relationship between battery voltage, current and model parameters under the z domain was established respectively in the Thevenin and PNGV model, which were two kinds of practical circuits.The theory of least square method for the multivariate linear regression was used to estimate parameters of the models in the MATLAB environment.Parameters estimation results of the two models at 25℃temperature were obtained.Finally, the model accuracy was verified; and steps about two models of lithium battery suitable for SOC estimation were designed.The simulation of lithium battery SOC estimation shows that PNGV model accuracy is higher, more suitable for the actual battery modeling system.%采集了一款45Ah磷酸铁锂电池特性数据,分别在戴维南和PNGV两种实用电路模型中推导建立了z域下电池电压、电流,以及模型参数间的数学关系。采用最小二乘法多元线性回归理论,在Matlab环境下对模型参数进行了估算,得到两种模型在25℃温度下的参数估算结果,并对模型精度进行了验证,设计了适用于两种电池模型的锂电池SOC估算步骤,根据仿真得到的锂电池SOC估算情况分析得到PNGV模型精度更高,更适合用于实际电池建模系统中。

  16. ENEL current knowledge on power batteries and relevant applications

    Energy Technology Data Exchange (ETDEWEB)

    Buonarota, A.; Menga, P. [ENEL (Italy)

    1995-10-01

    Activities carried out within ENEL CRE (Electrical Research Centre) in co-operation with CESI (Centro Elettrotecnico Sperimentale Italiano) concerning lead-acid batteries have provided a lot of knowledge allowing a more accurate battery dimensioning in connection with expected services, as well as the adoption of operating modalities capable of leading to a higher system reliability. A large part of this knowledge can potentially be transferred, already in short terms, to actual applications. In particular, the latter concern: the battery state of health diagnostics; an estimate of its state of charge; the optimum battery dimensioning in the system in connection with the expected service; the adoption of innovating recharging modalities; correct installation and use of VRLA batteries; the development level of innovating-type batteries. In the following, for each of these aspects, the available knowledge and the possible market applications, that can immediately or within short be put into practice are summarized.

  17. Repurposing of Batteries from Electric Vehicles

    Energy Technology Data Exchange (ETDEWEB)

    Viswanathan, Vilayanur V.; Kintner-Meyer, Michael CW

    2015-06-11

    Energy storage for stationary use is gaining traction both at the grid scale and distributed level. As renewable energy generation increases, energy storage is needed to compensate for the volatility of renewable over various time scales. This requires energy storage that is tailored for various energy to power (E/P) ratios. Other applications for energy storage include peak shaving, time shifting, load leveling, VAR control, frequency regulation, spinning reserves and other ancillary applications. While the need for energy storage for stationary applications is obvious, the regulations that determine the economic value of adding storage are at various stages of development. This has created a reluctance on the part of energy storage manufacturers to develop a suite of storage systems that can address the myriad of applications associated with stationary applications. Deployment of battery energy storage systems in the transportation sector is ahead of the curve with respect to the stationary space. Batteries, along with battery management systems (BMS) have been deployed for hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs). HEVs have now been deployed for 12 years, while PHEVs for 8 and EVs for 4 years. Some of the batteries are approaching end of life within the vehicle, and are ready to be taken off for recycling and disposal. Performance within a vehicle is non-negotiable in terms of miles traveled per charge, resulting in the batteries retaining a significant portion of their life. For stationary applications, the remaining energy and power of the battery can still be used by grouping together a few of these batteries. This enables getting the most of these batteries, while ensuring that performance is not compromised in either the automotive or stationary applications. This work summarizes the opportunities for such re-purposing of automotive batteries, along with the advantages and limitations

  18. Development of power storage system. Review of development for advanced battery technique in Yuasa Battery Co. , Ltd

    Energy Technology Data Exchange (ETDEWEB)

    1988-07-01

    Yuasa Battery Co., Ltd. selected the ceramic battery (Na/S) for power storage to establish the basic technique, to enlarge the capacity and to develop the 50kW/400kWh battery system. The ceramic battery is one where Na and S are combined and the beta alumina, that is, a special solid hydrolyte is utilized as the Na ion conductor. The battery system under development consists of 1120 batteries in which each nominal capacity is 540Wh, and which are connected to series and parallel and is put in a insulating electric furnace. The 76-77% energy efficiency in the constant power charging and discharging per every 8 hours specified, was established at the initial test of NO. 1 50kW/400kW power system. Other tests are conducting. (1 fig, 1 tab, 2 photo)

  19. Energy storage mechanism for hybrid battery

    Science.gov (United States)

    Feng, Jun; Chernova, Natasha; Omenya, Fredrick; Rastogi, Alok; Whittingham, Stanley

    Many devices require both high energy and high power density, and lithium ion batteries and super-capacitors cannot separately always meet the requirements. In this work, we study the operating mechanism of a hybrid battery, which combines the best properties of batteries and supercapacitors. We analyze the lithium ion storage mechanism using XRD, Raman, TEM and electrochemical measurements. The model system studied combines a non-intercalating carbon black anode with a LiFePO4 cathode. At 50% state of charge, XRD data for LiFePO4 cathode material shows a mixture of LiFePO4 and FePO4, indicating battery reaction. On the other hand, the activated carbon remains structurally unchanged. We also discuss the impact of a range of activated carbon/ LiFePO4 (AC/LFP) ratios. From cyclic voltammetry and charge/discharge results, the system exhibits battery-domain characteristics when the AC/ LFP ratio is below one, but showing more supercapacitor-domain traits when the ratio is higher. Besides, the systems have higher rate capacity at AC/LFP ratio around four as compared to one. This research is supported by NSF under Award Number 1318202.

  20. Ultrafast all-polymer paper-based batteries.

    Science.gov (United States)

    Nyström, Gustav; Razaq, Aamir; Strømme, Maria; Nyholm, Leif; Mihranyan, Albert

    2009-10-01

    Conducting polymers for battery applications have been subject to numerous investigations during the last two decades. However, the functional charging rates and the cycling stabilities have so far been found to be insufficient for practical applications. These shortcomings can, at least partially, be explained by the fact that thick layers of the conducting polymers have been used to obtain sufficient capacities of the batteries. In the present letter, we introduce a novel nanostructured high-surface area electrode material for energy storage applications composed of cellulose fibers of algal origin individually coated with a 50 nm thin layer of polypyrrole. Our results show the hitherto highest reported charge capacities and charging rates for an all polymer paper-based battery. The composite conductive paper material is shown to have a specific surface area of 80 m(2) g(-1) and batteries based on this material can be charged with currents as high as 600 mA cm(-2) with only 6% loss in capacity over 100 subsequent charge and discharge cycles. The aqueous-based batteries, which are entirely based on cellulose and polypyrrole and exhibit charge capacities between 25 and 33 mAh g(-1) or 38-50 mAh g(-1) per weight of the active material, open up new possibilities for the production of environmentally friendly, cost efficient, up-scalable and lightweight energy storage systems. PMID:19739594

  1. The Science of Battery Degradation

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, John P. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics; El Gabaly Marquez, Farid [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics; McCarty, Kevin [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics; Sugar, Joshua Daniel [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics; Talin, Alec A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics; Fenton, Kyle R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Design and Development; Nagasubramanian, Ganesan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Design and Development; Harris, Charles Thomas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Nanosystems Synthesis/Analysis; Jungjohann, Katherine Leigh [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Nanosystems Synthesis/Analysis; Hayden, Carl C. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Combustion Chemistry Dept.; Kliewer, Christopher Jesse [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Combustion Chemistry Dept.; Hudak, Nicholas S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Research and Development; Leung, Kevin [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Nanostructure Physics; McDaniel, Anthony H. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Hydrogen and Combustion Technology; Tenney, Craig M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Chemical and Biological Systems; Zavadil, Kevin R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Materials Lab.

    2015-01-01

    This report documents work that was performed under the Laboratory Directed Research and Development project, Science of Battery Degradation. The focus of this work was on the creation of new experimental and theoretical approaches to understand atomistic mechanisms of degradation in battery electrodes that result in loss of electrical energy storage capacity. Several unique approaches were developed during the course of the project, including the invention of a technique based on ultramicrotoming to cross-section commercial scale battery electrodes, the demonstration of scanning transmission x-ray microscopy (STXM) to probe lithium transport mechanisms within Li-ion battery electrodes, the creation of in-situ liquid cells to observe electrochemical reactions in real-time using both transmission electron microscopy (TEM) and STXM, the creation of an in-situ optical cell utilizing Raman spectroscopy and the application of the cell for analyzing redox flow batteries, the invention of an approach for performing ab initio simulation of electrochemical reactions under potential control and its application for the study of electrolyte degradation, and the development of an electrochemical entropy technique combined with x-ray based structural measurements for understanding origins of battery degradation. These approaches led to a number of scientific discoveries. Using STXM we learned that lithium iron phosphate battery cathodes display unexpected behavior during lithiation wherein lithium transport is controlled by nucleation of a lithiated phase, leading to high heterogeneity in lithium content at each particle and a surprising invariance of local current density with the overall electrode charging current. We discovered using in-situ transmission electron microscopy that there is a size limit to lithiation of silicon anode particles above which particle fracture controls electrode degradation. From electrochemical entropy measurements, we discovered that entropy

  2. The Science of Battery Degradation.

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, John P; Fenton, Kyle R [Sandia National Laboratories, Albuquerque, NM; El Gabaly Marquez, Farid; Harris, Charles Thomas [Sandia National Laboratories, Albuquerque, NM; Hayden, Carl C.; Hudak, Nicholas [Sandia National Laboratories, Albuquerque, NM; Jungjohann, Katherine Leigh [Sandia National Laboratories, Albuquerque, NM; Kliewer, Christopher Jesse; Leung, Kevin [Sandia National Laboratories, Albuquerque, NM; McDaniel, Anthony H.; Nagasubramanian, Ganesan [Sandia National Laboratories, Albuquerque, NM; Sugar, Joshua Daniel; Talin, Albert Alec; Tenney, Craig M [Sandia National Laboratories, Albuquerque, NM; Zavadil, Kevin R. [Sandia National Laboratories, Albuquerque, NM

    2015-01-01

    This report documents work that was performed under the Laboratory Directed Research and Development project, Science of Battery Degradation. The focus of this work was on the creation of new experimental and theoretical approaches to understand atomistic mechanisms of degradation in battery electrodes that result in loss of electrical energy storage capacity. Several unique approaches were developed during the course of the project, including the invention of a technique based on ultramicrotoming to cross-section commercial scale battery electrodes, the demonstration of scanning transmission x-ray microscopy (STXM) to probe lithium transport mechanisms within Li-ion battery electrodes, the creation of in-situ liquid cells to observe electrochemical reactions in real-time using both transmission electron microscopy (TEM) and STXM, the creation of an in-situ optical cell utilizing Raman spectroscopy and the application of the cell for analyzing redox flow batteries, the invention of an approach for performing ab initio simulation of electrochemical reactions under potential control and its application for the study of electrolyte degradation, and the development of an electrochemical entropy technique combined with x-ray based structural measurements for understanding origins of battery degradation. These approaches led to a number of scientific discoveries. Using STXM we learned that lithium iron phosphate battery cathodes display unexpected behavior during lithiation wherein lithium transport is controlled by nucleation of a lithiated phase, leading to high heterogeneity in lithium content at each particle and a surprising invariance of local current density with the overall electrode charging current. We discovered using in-situ transmission electron microscopy that there is a size limit to lithiation of silicon anode particles above which particle fracture controls electrode degradation. From electrochemical entropy measurements, we discovered that entropy

  3. New secondary batteries utilizing electronically conductive polymer cathodes

    Science.gov (United States)

    Martin, Charles R.; White, Ralph E.

    1989-01-01

    The objectives of this project are to characterize the transport properties in electronically conductive polymers and to assess the utility of these films as cathodes in lithium/polymer secondary batteries. During this research period, progress has been made in a literature survey of the historical background, methods of preparation, the physical and chemical properties, and potential technological applications of polythiophene. Progress has also been made in the characterization of polypyrrole flat films and fibrillar films. Cyclic voltammetry and potential step chronocoulometry were used to gain information on peak currents and potentials switching reaction rates, charge capacity, and charge retention. Battery charge/discharge studies were also performed.

  4. PV Charging System for Remote Area Operations

    Energy Technology Data Exchange (ETDEWEB)

    Ilsemann, Frederick; Thompson, Roger

    2008-07-31

    The objective of this project is to provide the public with a study of new as well existing technology to recharge batteries used in the field. A new product(s) will also be built based upon the information ascertained. American Electric Vehicles, Inc. (AEV) developed systems and methods suitable for charging state-of-the-art lithium-ion batteries in remote locations under both ideal and cloudy weather conditions. Conceptual designs are described for existing and next generation technology, particularly as regards solar cells, peak power trackers and batteries. Prototype system tests are reported.

  5. Thermal convection in a liquid metal battery

    Science.gov (United States)

    Shen, Yuxin; Zikanov, Oleg

    2016-08-01

    Generation of thermal convection flow in the liquid metal battery, a device recently proposed as a promising solution for the problem of the short-term energy storage, is analyzed using a numerical model. It is found that convection caused by Joule heating of electrolyte during charging or discharging is virtually unavoidable. It exists in laboratory prototypes larger than a few centimeters in size and should become much stronger in larger-scale batteries. The phenomenon needs further investigation in view of its positive (enhanced mixing of reactants) and negative (loss of efficiency and possible disruption of operation due to the flow-induced deformation of the electrolyte layer) effects.

  6. Metal pad instabilities in liquid metal batteries

    CERN Document Server

    Zikanov, Oleg

    2015-01-01

    A mechanical analogy is used to analyze the interaction between the magnetic field, electric current and deformation of interfaces in liquid metal batteries. It is found that, during charging or discharging, a sufficiently large battery is prone to instabilities of two types. One is similar to the metal pad instability known for aluminum reduction cells. Another type is new. It is related to the destabilizing effect of the Lorentz force formed by the azimuthal magnetic field induced by the base current and the current perturbations caused by the local variations of the thickness of the electrolyte layer.

  7. Thermal convection in a liquid metal battery

    CERN Document Server

    Shen, Yuxin

    2015-01-01

    Generation of thermal convection flow in the liquid metal battery, a device recently proposed as a promising solution for the problem of the short-term energy storage, is analyzed using a numerical model. It is found that convection caused by Joule heating of electrolyte during charging or discharging is virtually unavoidable. It exists in laboratory prototypes larger than a few cm in size and should become much stronger in larger-scale batteries. The phenomenon needs further investigation in view of its positive (enhanced mixing of reactants) and negative (loss of efficiency and possible disruption of operation due to the flow-induced deformation of the electrolyte layer) effects.

  8. Rechargeable batteries applications handbook

    CERN Document Server

    1998-01-01

    Represents the first widely available compendium of the information needed by those design professionals responsible for using rechargeable batteries. This handbook introduces the most common forms of rechargeable batteries, including their history, the basic chemistry that governs their operation, and common design approaches. The introduction also exposes reader to common battery design terms and concepts.Two sections of the handbook provide performance information on two principal types of rechargeable batteries commonly found in consumer and industrial products: sealed nickel-cad

  9. Battery systems engineering

    CERN Document Server

    Rahn, Christopher D

    2012-01-01

    A complete all-in-one reference on the important interdisciplinary topic of Battery Systems Engineering Focusing on the interdisciplinary area of battery systems engineering, this book provides the background, models, solution techniques, and systems theory that are necessary for the development of advanced battery management systems. It covers the topic from the perspective of basic electrochemistry as well as systems engineering topics and provides a basis for battery modeling for system engineering of electric and hybrid electric vehicle platforms. This original

  10. Battery Review Board

    Science.gov (United States)

    Vaughn, Chester

    1993-01-01

    The topics covered are presented in viewgraph form: NASA Battery Review Board Charter; membership, board chronology; background; statement of problem; summary of problems with 50 AH standard Ni-Cd; activities for near term programs utilizing conventional Ni-Cd; present projects scheduled to use NASA standard Ni-Cd; other near-term NASA programs requiring secondary batteries; recommended direction for future programs; future cell/battery procurement strategy; and the NASA Battery Program.

  11. Performance Modeling of a Vanadium Redox Flow Battery during Discharging

    International Nuclear Information System (INIS)

    A two-dimensional quasi-steady-state model is presented to simulate coupled mass-species-charge transfer and electrochemical reactions in all vanadium redox flow battery. Emphasis is located on examining the influences of applied current density, initial vanadium concentration, initial acid concentration and electrolyte flow rate on overpotentials in both electrodes, ohmic loss in electrolyte phase as well as battery discharging voltage. It is indicated that overpotential in negative electrode is the dominant factor causing the loss of battery discharging voltage at relatively lower or higher state of charge, while ohmic loss in electrolyte phase is dominant when discharging at moderate state of charge. Increasing initial vanadium concentration, the battery discharging voltage is significantly increased due to the reduced overpotentials in both electrodes. With the increase in initial acid concentration, the battery discharging voltage is also obviously increased because of increased open circuit voltage and decreased ohmic loss in electrolyte phase. As the electrolyte flow rate increases, the total discharging time is extended due to the retarded concentration polarization and the battery discharging voltage is obviously increased at lower state of charge

  12. Solar-rechargeable battery based on photoelectrochemical water oxidation: Solar water battery

    Science.gov (United States)

    Kim, Gonu; Oh, Misol; Park, Yiseul

    2016-09-01

    As an alternative to the photoelectrochemical water splitting for use in the fuel cells used to generate electrical power, this study set out to develop a solar energy rechargeable battery system based on photoelectrochemical water oxidation. We refer to this design as a “solar water battery”. The solar water battery integrates a photoelectrochemical cell and battery into a single device. It uses a water oxidation reaction to simultaneously convert and store solar energy. With the solar water battery, light striking the photoelectrode causes the water to be photo-oxidized, thus charging the battery. During the discharge process, the solar water battery reduces oxygen to water with a high coulombic efficiency (>90%) and a high average output voltage (0.6 V). Because the reduction potential of oxygen is more positive [E0 (O2/H2O) = 1.23 V vs. NHE] than common catholytes (e.g., iodide, sulfur), a high discharge voltage is produced. The solar water battery also exhibits a superior storage ability, maintaining 99% of its specific discharge capacitance after 10 h of storage, without any evidence of self-discharge. The optimization of the cell design and configuration, taking the presence of oxygen in the cell into account, was critical to achieving an efficient photocharge/discharge.

  13. Electric Vehicle Battery Challenge

    Science.gov (United States)

    Roman, Harry T.

    2014-01-01

    A serious drawback to electric vehicles [batteries only] is the idle time needed to recharge their batteries. In this challenge, students can develop ideas and concepts for battery change-out at automotive service stations. Such a capability would extend the range of electric vehicles.

  14. Data pieces-based parameter identification for lithium-ion battery

    Science.gov (United States)

    Gao, Wei; Zou, Yuan; Sun, Fengchun; Hu, Xiaosong; Yu, Yang; Feng, Sen

    2016-10-01

    Battery characteristics vary with temperature and aging, it is necessary to identify battery parameters periodically for electric vehicles to ensure reliable State-of-Charge (SoC) estimation, battery equalization and safe operation. Aiming for on-board applications, this paper proposes a data pieces-based parameter identification (DPPI) method to identify comprehensive battery parameters including capacity, OCV (open circuit voltage)-Ah relationship and impedance-Ah relationship simultaneously only based on battery operation data. First a vehicle field test was conducted and battery operation data was recorded, then the DPPI method is elaborated based on vehicle test data, parameters of all 97 cells of the battery package are identified and compared. To evaluate the adaptability of the proposed DPPI method, it is used to identify battery parameters of different aging levels and different temperatures based on battery aging experiment data. Then a concept of "OCV-Ah aging database" is proposed, based on which battery capacity can be identified even though the battery was never fully charged or discharged. Finally, to further examine the effectiveness of the identified battery parameters, they are used to perform SoC estimation for the test vehicle with adaptive extended Kalman filter (AEKF). The result shows good accuracy and reliability.

  15. Use of calorimetry for end of charge determination

    Science.gov (United States)

    Johnson, Chris J.

    1994-01-01

    To perform heat flow measurements on batteries, it is necessary to consider the following requirements: establish thermal neutral potential; identify inefficient charging; understand self discharge mechanisms; and provide accurate voltage/temperature data. A discussion is provided in viewgraph format.

  16. The experimental study of lead acid batteries for an electric hybrid drive stand

    Directory of Open Access Journals (Sweden)

    Emilian Lefter

    2008-05-01

    Full Text Available The paper aims to document a number of experimental tests conducted on some VRLA batteries. A montage scheme is proposed to monitor the behaviour of the batteries on charging and discharging. The results are presented of the measurements of the battery parameters, of the voltage in the open circuit (OCV, as well as the internal impedance, after a process of charging. Based on the catalogue data, the Peukert coefficient and the Peukert capacity are determined, which are used to determine the discharge depth of the batteries tested for the partial discharge. The schema used for discharging ispresented, and also a number of conclusions regarding the testing conditions.

  17. Use of Super-Capacitor to Enhance Charging Performance of Stand-Alone Solar PV System

    KAUST Repository

    Huang, B. J.

    2011-01-01

    Introduction: The battery charging performance in a stand-alone solar PV system affects the PV system efficiency and the load operating time. The New Energy Center of National Taiwan University has been devoted to the development of a PWM charging technique to continue charging the lead-acid battery after the overcharge point to increase the battery storage capacity by more than 10%. The present study intends to use the super-capacitor to further increase the charge capacity before the overcharge point of the battery. The super-capacitor is connected in parallel to the lead-acid battery. This will reduce the overall charging impedance during the charge and increase the charging current, especially in sunny weather. A system dynamics model of the lead-acid battery and super-capacitor was derived and the control system simulation was carried out to predict the charging performance for various weathers. It shows that the overall battery impedance decreases and charging power increases with increasing solar radiation. An outdoor comparative test for two identical PV systems with and without supercapacitor was carried out. The use of super-capacitor is shown to be able to increase the lead-acid charging capacity by more than 25% at sunny weather and 10% in cloudy weather. © Springer-Verlag Berlin Heidelberg 2011.

  18. System for electric power generation with photovoltaic solar modules for charging the batteries of an electric wheelchair; Sistema de geracao de energia eletrica com modulos solares fotovoltaicos para o carregamento de baterias de uma cadeira de rodas eletrica

    Energy Technology Data Exchange (ETDEWEB)

    Mesquita, Rafael Pimenta; Souza, Teofilo Miguel de [Universidade Estadual Paulista (UNESP), Guaratinguta, SP (Brazil). Fac. de Engenharia. Dept. de Engenharia Eletrica], Emails: pimentamesquita@gmail.com, teofilo@feg.unesp.br

    2006-07-01

    Renewable energy is all kind of energy produced from a natural source that not diminish because its utilization is 'renewable'. More and more renewable energy resources are used, because they offer multiple advantages such as the energy output facility in small scale and because they are entirely compatible with the environment. The renewable energy used in this project is the photovoltaic solar energy, obtained by the direct conversion of the solar energy in electric energy through the use of solar cells, that can be of several kinds, being the most common of silicon. The main advantage of photovoltaic system is the generation of clean electric energy, or either, generates energy without emitting pollutant and without destroying the environment, moreover is an inexhaustible source of energy. The main disadvantage is, nowadays, the high cost and its low efficiency, so to continue developing it is necessary establish capable mechanisms to make it possible. The search of these mechanisms of incentive becomes-itself a lot important, because the renewable energy and not conventional do not produce a financial return to the investor properly said, but brings lots of benefits to the community, the society and to the environment. This project has the purpose of create an electric energy generation system through solar photovoltaic modules to carry batteries of a motorized wheelchair. An electric wheelchair is moved by electric motors of direct current that are feed by batteries, permitting a medium autonomy of 10 km by load. The batteries are recharged by a battery supplier. This operation should be carried out daily in a space of 6 to 8 hours. According to the Demographic Census realized in 2000 carried out by the IBGE, Brazil has around 1.416.060 physical deficient, which 861.196 are men and 554.864 are women. From a request of a user of electric wheelchair the idea of this project was shown up. The user complained that he stayed a long time carrying his seat

  19. Degradation analysis of nickel/metal hydride battery and its electrodes materials

    Institute of Scientific and Technical Information of China (English)

    李丽; 吴锋; 杨凯

    2004-01-01

    The results indicate that during charge and discharge, the expansion of Ni(OH)2 crystal, pulverization of MH alloy particles and falling off from current collector are identified as the main causes for deterioration of Ni/MH batteries. Meanwhile, the contact resistance of inner battery increases due to the deterioration of the negative and positive electrode, and these changes lead to increasing battery body temperature and damaging its electrode and separator. The fibre's expansion and hole's diminishment of battery's separator after degradation will affect the electrochemical performance and cycle life of Ni/MH batteries.

  20. A low-cost lead-acid battery with high specific-energy

    Indian Academy of Sciences (India)

    S K Martha; B Hariprakash; S A Gaffoor; D C Trivedi; A K Shukla

    2006-01-01

    Lightweight grids for lead-acid battery grids have been prepared from acrylonitrile butadiene styrene (ABS) copolymer followed by coating with lead. Subsequently, the grids have been electrochemically coated with a conductive and corrosion-resistant layer of polyaniline. These grids are about 75% lighter than those employed in conventional lead-acid batteries. Commercial-grade 6V/3.5Ah (C20-rate) lead-acid batteries have been assembled and characterized employing positive and negative plates constituting these grids. The specific energy of such a lead-acid battery is about 50 Wh/kg. The batteries can withstand fast charge-discharge duty cycles.

  1. Methods and systems for thermodynamic evaluation of battery state of health

    Energy Technology Data Exchange (ETDEWEB)

    Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

    2014-12-02

    Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

  2. ETK's experience in the application of VRLA batteries

    Energy Technology Data Exchange (ETDEWEB)

    Klaric, I. [Ericsson Nikola Tesla d.d., Zagreb (Croatia)

    2000-07-01

    This paper presents the experience of the company Ericsson Nikola Tesla (ETK) in the application of VRLA batteries. After a short comment on conventional lead acid batteries, the paper explains the reasons for introduction of VRLA batteries and presents our experience considering their quality, performance, hydrogen evolution, safety, service life etc. Stress is put on some internal and external factors which affect useful life, such as positive grid corrosion, ambient temperature and charging voltage. ETK also gained experience in relation to adaptation of some UPS systems to VRLA batteries. The article concludes with the list of important advantages and disadvantages of VRLA batteries compared with the flooded ones. (orig.)

  3. Safety characteristics of non-lithium battery systems. Final report for period ending FY84

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, R.M.; Bis, R.F.

    1984-07-01

    A study was conducted to determine the safety characteristics for both primary and secondary non-lithium battery systems. Of particular interest was the behavior of these battery systems when subjected to the electrical and thermal-abuse testing procedures of NAVSEAINST 9310.1A (i.e., short circuit, forced overdischarge, and incineration). Also included are the safety/hazard characteristics associated with charging primary batteries and overcharging secondary batteries. This report also summarizes the manufacture, electrical performance, failure mechanisms, self-discharge, and applications for twenty-two primary and nineteen secondary battery systems.

  4. Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, J.

    2014-12-01

    The deployment and use of lithium-ion batteries in automotive and stationary energy storage applications must be optimized to justify their high up-front costs. Given that batteries degrade with use and storage, such optimizations must evaluate many years of operation. As the degradation mechanisms are sensitive to temperature, state-of-charge histories, current levels, and cycle depth and frequency, it is important to model both the battery and the application to a high level of detail to ensure battery response is accurately predicted. To address these issues, the National Renewable Energy Laboratory has developed the Battery Lifetime Analysis and Simulation Tool (BLAST) suite of tools. This suite of tools pairs NREL's high-fidelity battery degradation model with a battery electrical and thermal performance model, application-specific electrical and thermal performance models of the larger system (e.g., an electric vehicle), application-specific system use data (e.g., vehicle travel patterns and driving data), and historic climate data from cities across the United States. This provides highly realistic, long-term predictions of battery response and thereby enables quantitative comparisons of varied battery use strategies.

  5. Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation

    Energy Technology Data Exchange (ETDEWEB)

    Neubauer, J. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2014-12-01

    The deployment and use of lithium-ion (Li-ion) batteries in automotive and stationary energy storage applications must be optimized to justify their high up-front costs. Given that batteries degrade with use and storage, such optimizations must evaluate many years of operation. As the degradation mechanisms are sensitive to temperature, state-of-charge (SOC) histories, current levels, and cycle depth and frequency, it is important to model both the battery and the application to a high level of detail to ensure battery response is accurately predicted. To address these issues, the National Renewable Energy Laboratory (NREL) has developed the Battery Lifetime Analysis and Simulation Tool (BLAST) suite. This suite of tools pairs NREL’s high-fidelity battery degradation model with a battery electrical and thermal performance model, application-specific electrical and thermal performance models of the larger system (e.g., an electric vehicle), application-specific system use data (e.g., vehicle travel patterns and driving data), and historic climate data from cities across the United States. This provides highly realistic long-term predictions of battery response and thereby enables quantitative comparisons of varied battery use strategies.

  6. Alkaline quinone flow battery.

    Science.gov (United States)

    Lin, Kaixiang; Chen, Qing; Gerhardt, Michael R; Tong, Liuchuan; Kim, Sang Bok; Eisenach, Louise; Valle, Alvaro W; Hardee, David; Gordon, Roy G; Aziz, Michael J; Marshak, Michael P

    2015-09-25

    Storage of photovoltaic and wind electricity in batteries could solve the mismatch problem between the intermittent supply of these renewable resources and variable demand. Flow batteries permit more economical long-duration discharge than solid-electrode batteries by using liquid electrolytes stored outside of the battery. We report an alkaline flow battery based on redox-active organic molecules that are composed entirely of Earth-abundant elements and are nontoxic, nonflammable, and safe for use in residential and commercial environments. The battery operates efficiently with high power density near room temperature. These results demonstrate the stability and performance of redox-active organic molecules in alkaline flow batteries, potentially enabling cost-effective stationary storage of renewable energy. PMID:26404834

  7. Powering up the future: radical polymers for battery applications.

    Science.gov (United States)

    Janoschka, Tobias; Hager, Martin D; Schubert, Ulrich S

    2012-12-18

    Our society's dependency on portable electric energy, i.e., rechargeable batteries, which permit power consumption at any place and in any time, will eventually culminate in resource wars on limited commodities like lithium, cobalt, and rare earth metals. The substitution of conventional metals as means of electric charge storage by organic and polymeric materials, which may ultimately be derived from renewable resources, appears to be the only feasible way out. In this context, the novel class of organic radical batteries (ORBs) excelling in rate capability (i.e., charging speed) and cycling stability (>1000 cycles) sets new standards in battery research. This review examines stable nitroxide radical bearing polymers, their processing to battery systems, and their promising performance. PMID:23238940

  8. Simulations of Plug-in Hybrid Vehicles Using Advanced Lithium Batteries and Ultracapacitors on Various Driving Cycles

    OpenAIRE

    Burke, Andy; Zhao, Hengbing

    2010-01-01

    The use of ultracapacitors in plug-in hybrid vehicles (PHEVs) with high energy density lithium-ion and zinc-air batteries is studied. Simulations were performed for various driving cycles with the PHEVs operating in the charge depleting and charge sustaining modes. The effects of the load leveling of the power demand from the batteries using the ultracapacitors are evident. The average and the peak currents from the batteries are lower by a factor of 2-3.

  9. Metal Hydrides for Rechargeable Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Valoeen, Lars Ole

    2000-03-01

    Rechargeable battery systems are paramount in the power supply of modern electronic and electromechanical equipment. For the time being, the most promising secondary battery systems for the future are the lithium-ion and the nickel metal hydride (NiMH) batteries. In this thesis, metal hydrides and their properties are described with the aim of characterizing and improving those. The thesis has a special focus on the AB{sub 5} type hydrogen storage alloys, where A is a rare earth metal like lanthanum, or more commonly misch metal, which is a mixture of rare earth metals, mainly lanthanum, cerium, neodymium and praseodymium. B is a transition metal, mainly nickel, commonly with additions of aluminium, cobalt, and manganese. The misch metal composition was found to be very important for the geometry of the unit cell in AB{sub 5} type alloys, and consequently the equilibrium pressure of hydrogen in these types of alloys. The A site substitution of lanthanum by misch metal did not decrease the surface catalytic properties of AB{sub 5} type alloys. B-site substitution of nickel with other transition elements, however, substantially reduced the catalytic activity of the alloy. If the internal pressure within the electrochemical test cell was increased using inert argon gas, a considerable increase in the high rate charge/discharge performance of LaNi{sub 5} was observed. An increased internal pressure would enable the utilisation of alloys with a high hydrogen equivalent pressure in batteries. Such alloys often have favourable kinetics and high hydrogen diffusion rates and thus have a potential for improving the high current discharge rates in metal hydride batteries. The kinetic properties of metal hydride electrodes were found to improve throughout their lifetime. The activation properties were found highly dependent on the charge/discharge current. Fewer charge/discharge cycles were needed to activate the electrodes if a small current was used instead of a higher

  10. Electrochemical accumulators batteries; Accumulateurs electrochimiques batteries

    Energy Technology Data Exchange (ETDEWEB)

    Ansart, F.; Castillo, S.; Laberty- Robert, C.; Pellizon-Birelli, M. [Universite Paul Sabatier, Lab. de Chimie des Materiaux Inorganiques et Energetiques, CIRIMAT, UMR CNRS 5085, 31 - Toulouse (France)] [and others

    2000-07-01

    It is necessary to storage the electric power in batteries to join the production and the utilization. In this domain progresses are done every days in the technics and also in the available materials. These technical days present the state of the art in this domain. Many papers were presented during these two days giving the research programs and recent results on the following subjects: the lithium batteries, the electrolytes performances and behaviour, lead accumulators, economic analysis of the electrochemical storage market, the batteries applied to the transportation sector and the telephones. (A.L.B.)

  11. Minimizing heat loss in DC networks using batteries

    CERN Document Server

    Zocca, Alessandro

    2016-01-01

    Electricity transmission networks dissipate a non-negligible fraction of the power they transport due to the heat loss in the transmission lines. In this work we explore how the transport of energy can be more efficient by adding to the network multiple batteries that can coordinate their operations. Such batteries can both charge using the current excess in the network or discharge to meet the network current demand. Either way, the presence of batteries in the network can be leveraged to mitigate the intrinsic uncertainty in the power generation and demand and, hence, transport the energy more efficiently through the network. We consider a resistive DC network with stochastic external current injections or consumptions and show how the expected total heat loss depends on the network structure and on the batteries operations. Furthermore, in the case where the external currents are modeled by Ornstein-Uhlenbeck processes, we derive the dynamical optimal control for the batteries over a finite time interval.

  12. Economic evaluation of a photovoltaic (PV) power generation system with battery; Battery wo heiyoshita taiyoko hatsuden system no keizaiseihyoka

    Energy Technology Data Exchange (ETDEWEB)

    Tomikura, S.; Kaya, Y. [Keio University, Tokyo (Japan)

    1997-01-30

    To improve the correlation characteristics between unstable output of PV system and demand, and to improve its economical value, use of battery was investigated. In this study, at first, solution of constrained optimization problem was derived in the case when the demand and PV output were defined by the continuous function, to obtain the break-even cost of PV system. To investigate the charge from PV in daytime or the charge from base power source at night, peak, middle and base power sources were considered. Finally, break-even cost of the PV system with battery was calculated as a trial using a multiple time zone model having PV and usual three power sources. As a result, the difference ranging from 25000 to 29000 yen in the break-even costs between PV and PV with battery was provided, which was considered to be a pure increase of the value using battery. 10 refs., 7 figs., 1 tab.

  13. An iterative computation method for interpreting and extending an analytical battery model

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Battery models are of great importance to develop portable computing systems, for whether the design of low power hardware architecture or the design of battery-aware scheduling policies. In this paper, we present a physically justified iterative computing method to illustrate the discharge, recovery and charge process of Li/Li-ion batteries. The discharge and recovery processes correspond well to an existing accurate analytical battery model: R-V-W's analytical model, and thus interpret this model algorithmically. Our method can also extend R-V-W's model easily to accommodate the charge process. The work will help the system designers to grasp the characteristics of R-V-W's battery model and also, enable to predict the battery behavior in the charge process in a uniform way as the discharge process and the recovery process. Experiments are performed to show the accuracy of the extended model by comparing the predicted charge times with those derived from the DUALFOIL simulations.Various profiles with different combinations of battery modes were tested. The experimental results show that the extended battery model preserves high accuracy in predicting the charge behavior.

  14. Electric Peugeot to have new nickel-iron batteries

    Science.gov (United States)

    1984-09-01

    Four articles, one from Austria and three from France, announce the introduction of a new electric automobile. The new car is a French made Peugeot. A feasible electric car is made possible by the development of a new nickel-iron battery. The new battery is smaller and lighter in weight. Specifications are given and discussed along with the working range and charge efficiency data.

  15. Modeling and Optimal Control of a Redox Flow Battery

    OpenAIRE

    Wrang, Daniel; Faulwasser, Timm; Billeter, Julien; Amstutz, Véronique; Vrubel, Heron; Battistel, Alberto; Girault, Hubert; Bonvin, Dominique

    2016-01-01

    Vanadium Redox Flow Batteries (VRFB) can be used as energy storage device, for example to account for wind or solar power fluctuations. In VRFBs charge is stored in two tanks containing two different vanadium solutions. This approach decouples the storage capacity and the power supply which is dependent only on the number and size of the cells [1]. A control specific model of a VRFB is proposed, which captures the essential dynamic properties of the battery while ignoring all fluid mechanica...

  16. Response of a spin valve to a spin battery

    OpenAIRE

    Pham, Khuôn-Viêt

    2016-01-01

    It is shown that spin valves under suitable symmetry conditions exhibit an ON-OFF response to a spin battery, and are therefore perfect spin transistors. While a spin valve driven by a charge battery displays the usual GMR (Giant Magneto-Resistance), this means that a pure spin current or pure spin accumulation can generate an infinite magnetoresistance (IMR). Magnetic tunnel junctions as well as CPP (current perpendicular to plane) or CIP (current in plane) metallic trilayers are discussed.

  17. Battery, especially for portable devices, has an anode containing silicon

    OpenAIRE

    S. Y. Kan

    2002-01-01

    The anode (2) contains silicon. A battery with a silicon-containing anode is claimed. An Independent claim is also included for a method used to make the battery, comprising the doping of a silicon substrate (1) with charge capacity-increasing material (preferably boron, phosphorous or arsenic), etching the doped substrate layer in order to increase its porosity, and applying a cathode (3) in the form of a lithium oxide compound onto the resulting anode and applying an electrolyte (4) to the ...

  18. Pulse-Based Fast Battery IoT Charger Using Dynamic Frequency and Duty Control Techniques Based on Multi-Sensing of Polarization Curve

    OpenAIRE

    Meng Di Yin; Jeonghun Cho; Daejin Park

    2016-01-01

    The pulse-based charging method for battery cells has been recognized as a fast and efficient way to overcome the shortcoming of a slow charging time in distributed battery cells, which is regarded as a connection of cells such as the Internet of Things (IoT). The pulse frequency for controlling the battery charge duration is dynamically controlled within a certain range in order to inject the maximum charge current into the battery cells. The optimal frequency is determined in order to minim...

  19. Rapid charge-discharge property of Li4Ti5O12-TiO2 nanosheet and nanotube composites as anode material for power lithium-ion batteries.

    Science.gov (United States)

    Yi, Ting-Feng; Fang, Zi-Kui; Xie, Ying; Zhu, Yan-Rong; Yang, Shuang-Yuan

    2014-11-26

    Well-defined Li4Ti5O12-TiO2 nanosheet and nanotube composites have been synthesized by a solvothermal process. The combination of in situ generated rutile-TiO2 in Li4Ti5O12 nanosheets or nanotubes is favorable for reducing the electrode polarization, and Li4Ti5O12-TiO2 nanocomposites show faster lithium insertion/extraction kinetics than that of pristine Li4Ti5O12 during cycling. Li4Ti5O12-TiO2 electrodes also display lower charge-transfer resistance and higher lithium diffusion coefficients than pristine Li4Ti5O12. Therefore, Li4Ti5O12-TiO2 electrodes display lower charge-transfer resistance and higher lithium diffusion coefficients. This reveals that the in situ TiO2 modification improves the electronic conductivity and electrochemical activity of the electrode in the local environment, resulting in its relatively higher capacity at high charge-discharge rate. Li4Ti5O12-TiO2 nanocomposite with a Li/Ti ratio of 3.8:5 exhibits the lowest charge-transfer resistance and the highest lithium diffusion coefficient among all samples, and it shows a much improved rate capability and specific capacity in comparison with pristine Li4Ti5O12 when charging and discharging at a 10 C rate. The improved high-rate capability, cycling stability, and fast charge-discharge performance of Li4Ti5O12-TiO2 nanocomposites can be ascribed to the improvement of electrochemical reversibility, lithium ion diffusion, and conductivity by in situ TiO2 modification. PMID:25330170

  20. Rapid charge-discharge property of Li4Ti5O12-TiO2 nanosheet and nanotube composites as anode material for power lithium-ion batteries.

    Science.gov (United States)

    Yi, Ting-Feng; Fang, Zi-Kui; Xie, Ying; Zhu, Yan-Rong; Yang, Shuang-Yuan

    2014-11-26

    Well-defined Li4Ti5O12-TiO2 nanosheet and nanotube composites have been synthesized by a solvothermal process. The combination of in situ generated rutile-TiO2 in Li4Ti5O12 nanosheets or nanotubes is favorable for reducing the electrode polarization, and Li4Ti5O12-TiO2 nanocomposites show faster lithium insertion/extraction kinetics than that of pristine Li4Ti5O12 during cycling. Li4Ti5O12-TiO2 electrodes also display lower charge-transfer resistance and higher lithium diffusion coefficients than pristine Li4Ti5O12. Therefore, Li4Ti5O12-TiO2 electrodes display lower charge-transfer resistance and higher lithium diffusion coefficients. This reveals that the in situ TiO2 modification improves the electronic conductivity and electrochemical activity of the electrode in the local environment, resulting in its relatively higher capacity at high charge-discharge rate. Li4Ti5O12-TiO2 nanocomposite with a Li/Ti ratio of 3.8:5 exhibits the lowest charge-transfer resistance and the highest lithium diffusion coefficient among all samples, and it shows a much improved rate capability and specific capacity in comparison with pristine Li4Ti5O12 when charging and discharging at a 10 C rate. The improved high-rate capability, cycling stability, and fast charge-discharge performance of Li4Ti5O12-TiO2 nanocomposites can be ascribed to the improvement of electrochemical reversibility, lithium ion diffusion, and conductivity by in situ TiO2 modification.

  1. Lifetime Improvement by Battery Scheduling

    NARCIS (Netherlands)

    Jongerden, Marijn R.; Haverkort, Boudewijn R.; Schmitt, Jens B.

    2012-01-01

    The use of mobile devices is often limited by the lifetime of their batteries. For devices that have multiple batteries or that have the option to connect an extra battery, battery scheduling, thereby exploiting the recovery properties of the batteries, can help to extend the system lifetime. Due to

  2. Lifetime improvement by battery scheduling

    NARCIS (Netherlands)

    Jongerden, Marijn R.; Haverkort, Boudewijn R.

    2011-01-01

    The use of mobile devices is often limited by the lifetime of its battery. For devices that have multiple batteries or that have the option to connect an extra battery, battery scheduling, thereby exploiting the recovery properties of the batteries, can help to extend the system lifetime. Due to t

  3. Smart battery charger for electric mobility in smart grids

    OpenAIRE

    Monteiro, Vítor Duarte Fernandes; João C. Ferreira; João L Afonso

    2012-01-01

    In this paper is presented the development of a smart batteries charger for Electric Vehicles (EVs) and Plug-in Hybrid Electric Vehicles (PHEVs), aiming their integration in Smart Grids. The batteries charging process is controlled by an appropriate control algorithm, aiming to preserve the batteries lifespan. The main features of the equipment are the mitigation of the power quality degradation and the bidirectional operation, as Grid-to-Vehicle (G2V) and as Vehicle-to-Grid (V2G). During the...

  4. Charging up for the future of plug-in hybrids and range extenders. An exploration of options for increased battery utilisation; Opladen voor de toekomst van plug-in hybrides en range extenders. Een verkenning naar mogelijkheden voor vergroten van het elektrische gebruik

    Energy Technology Data Exchange (ETDEWEB)

    Van Essen, H.; Schroten, A.; Aarnink, S.

    2013-05-15

    If the full potential of plug-in hybrids and electric cars with a range extender is to be usefully exploited, it is important that these vehicles be used in battery mode as much as possible. This means that users' charging and driving behaviour needs to be positively influenced. This can be achieved through suitably designed financial incentives on the part of employers and government, further expansion of battery-charging infrastructure, and transferring knowledge on driving style. Improved driving and charging behaviour will lead to lower effective fuel consumption, reduced CO2 emissions and improved air quality. These are some of the results of this study in which it is examined how the performance of plug-in hybrids and cars with a range extender can be improved. It is the first study to look into the factors governing practical usage of such vehicles and the options available to the various parties to improve that usage. To this end a literature study was carried out and interviews were held with employers, leasing companies, trade associations, government agencies and other parties [Dutch] Om het potentieel van plug-in hybrides en elektrische auto's met een range extender te benutten is het van belang dat deze auto's zoveel mogelijk elektrisch worden gereden. Hiervoor is het nodig om het oplaad- en rijgedrag van de gebruikers positief te beïnvloeden. Dit kan door het geven van slimme financiële prikkels door werkgevers en overheid, het verder uitbreiden van de laadinfrastructuur en kennisoverdracht over rijgedrag. Een verbeterd rij- en laadgedrag zorgt voor een lager brandstofpraktijkverbruik, minder CO2-uitstoot en een betere luchtkwaliteit. Dit staat onder meer in de studie 'Opladen voor de toekomst van plug-in hybrides en range extenders' van CE Delft, waarin op verzoek van de Nederlandse importeurs van Toyota en Opel is onderzocht hoe het elektrisch gebruik kan worden verbeterd. Hierin is voor het eerst gekeken naar de factoren

  5. Performance requirements of automotive batteries for future car electrical systems

    Science.gov (United States)

    Friedrich, R.; Richter, G.

    The further increase in the number of power-consuming functions which has been announced for future vehicle electrical systems, and in particular the effects of new starting systems on battery performance, requires a further optimization of the lead acid system coupled with effective energy management, and enhanced battery operating conditions. In the face of these increased requirements, there are proven benefits to splitting the functions of a single SLI battery between two separate, special-purpose batteries, each of which are optimized, for high power output and for high energy throughput, respectively. This will bring about a marked improvement in weight, reliability, and state of charge (SOC). The development of special design starter and service batteries is almost completed and will lead to new products with a high standard of reliability. The design of the power-optimized lead acid accumulator is particularly suitable for further development as the battery for a 42/36 V electrical system. This is intended to improve the efficiency of the generator and the various power-consuming functions and to improve start/stop operation thereby bringing about a marked reduction in the fuel consumption of passenger cars. This improvement can also be assisted by a charge management system used in conjunction with battery status monitoring.

  6. CO2 emissions associated with electric vehicle charging: The impact of electricity generation mix, charging infrastructure availability and vehicle type

    Energy Technology Data Exchange (ETDEWEB)

    McLaren, Joyce; Miller, John; O’Shaughnessy, Eric; Wood, Eric; Shapiro, Evan

    2016-06-01

    The emission reduction benefits of EVs are dependent on the time and location of charging. An analysis of battery electric and plug-in hybrid vehicles under four charging scenarios and five electricity grid profiles shows that CO2 emissions are highly dependent on the percentage of fossil fuels in the grid mix. Availability of workplace charging generally results in lower emissions, while restricting charging to off-peak hours results in higher total emissions.

  7. Valve-regulated lead-acid batteries

    Science.gov (United States)

    Berndt, D.

    Valve-regulated lead-acid (VRLA) batteries with gelled electrolyte appeared as a niche market during the 1950s. During the 1970s, when glass-fiber felts became available as a further method to immobilize the electrolyte, the market for VRLA batteries expanded rapidly. The immobilized electrolyte offers a number of obvious advantages including the internal oxygen cycle which accommodates the overcharging current without chemical change within the cell. It also suppresses acid stratification and thus opens new fields of application. VRLA batteries, however, cannot be made completely sealed, but require a valve for gas escape, since hydrogen evolution and grid corrosion are unavoidable secondary reactions. These reactions result in water loss, and also must be balanced in order to ensure proper charging of both electrodes. Both secondary reactions have significant activation energies, and can reduce the service life of VRLA batteries, operated at elevated temperature. This effect can be aggravated by the comparatively high heat generation caused by the internal oxygen cycle during overcharging. Temperature control of VRLA batteries, therefore, is important in many applications.

  8. Multi-temperature state-dependent equivalent circuit discharge model for lithium-sulfur batteries

    DEFF Research Database (Denmark)

    Propp, Karsten; Marinescu, Monica; Auger, Daniel J.;

    2016-01-01

    Lithium-sulfur (Li-S) batteries are described extensively in the literature, but existing computational models aimed at scientific understanding are too complex for use in applications such as battery management. Computationally simple models are vital for exploitation. This paper proposes a non......-linear state-of-charge dependent Li-S equivalent circuit network (ECN) model for a Li-S cell under discharge. Li-S batteries are fundamentally different to Li-ion batteries, and require chemistry-specific models. A new Li-S model is obtained using a ‘behavioural’ interpretation of the ECN model; as Li...... pulse profile at four temperatures from 10 °C to 50 °C, giving linearized ECN parameters for a range of states-of-charge, currents and temperatures. These are used to create a nonlinear polynomial-based battery model suitable for use in a battery management system. When the model is used to predict...

  9. Preparation and Characterization of Cathode Materials for Lithium-Oxygen Batteries

    DEFF Research Database (Denmark)

    Storm, Mie Møller

    A possible future battery type is the Li-air battery which theoretically has the potential of reaching gravimetric energy densities close to those of gasoline. The Li-airbattery is discharged by the reaction of Li-ions and oxygen, drawn from the air, reacting at the battery cathode to form Li2O2....... The type of cathode material affects the battery discharge capacity and charging potential and with a carbon based cathode many questions are still unanswered. The focus of this Ph.D. project has been the synthesis of reduced graphene oxide as well as the investigation of the effect of reduced graphene...... the discharge capacity of the battery as well as the charging potential. In situ X-ray diffraction studies on carbon black cathodes in a capillary battery showed the formation of crystalline Li2O2 on the first discharge cycle, the intensity of Li2O2 on the second discharge cycle was however diminished...

  10. SOC EKF Estimation based on a Second-order LiFePO4 Battery Model

    Directory of Open Access Journals (Sweden)

    Zheng Zhu

    2013-08-01

    Full Text Available An accurate battery State of Charge (SOC estimation has great significance in improving battery life and vehicle performance. An improved second-order battery model is proposed in this paper through quantities of LiFePO4 battery experiments. The parameters of the model were acquired by the HPPC composite pulse condition under different temperature, charging and discharging rates, SOC. Based on the model, battery SOC is estimated by Extended Kalman Filter (EKF. Comparison of three different pulse conditions shows that the average error of SOC estimation of this algorithm is about 4.2%. The improved model is able to reflect the dynamic performance of batteries suitably, and the SOC estimation algorithm is provided with higher accuracy and better dynamic adaptability.

  11. The UltraBattery-A new battery design for a new beginning in hybrid electric vehicle energy storage

    Science.gov (United States)

    Cooper, A.; Furakawa, J.; Lam, L.; Kellaway, M.

    The UltraBattery, developed by CSIRO Energy Technology in Australia, is a hybrid energy storage device which combines an asymmetric super-capacitor and a lead-acid battery in single unit cells. This takes the best from both technologies without the need for extra, expensive electronic controls. The capacitor enhances the power and lifespan of the lead-acid battery as it acts as a buffer during high-rate discharging and charging, thus enabling it to provide and absorb charge rapidly during vehicle acceleration and braking. The initial performance of the prototype UltraBatteries was evaluated according to the US FreedomCAR targets and was shown to meet or exceed these in terms of power, available energy, cold cranking and self-discharge set for both minimum and maximum power-assist hybrid electric vehicles (HEVs). Other laboratory cycling tests showed a fourfold improvement over previous state-of-the-art lead-acid batteries under the RHOLAB test profile and better life than commercial nickel/metal hydride (NiMH) cells used in a Honda Insight when tested under the EUCAR HEV profile. As a result of this work, a set of twelve 12 V modules was built by The Furukawa Battery Co., Ltd. in Japan and were fitted into a Honda Insight instead of the NiMH battery by Provector Ltd. The battery pack was fitted with full monitoring and control capabilities and the car was tested at Millbrook Proving Ground under a General Motors road test simulation cycle for an initial target of 50 000 miles which was extended to 100 000 miles. This was completed on 15th January 2008 without any battery problems. Furthermore, the whole test was completed without the need for any conditioning or equalisation of the battery pack.

  12. A Desalination Battery

    KAUST Repository

    Pasta, Mauro

    2012-02-08

    Water desalination is an important approach to provide fresh water around the world, although its high energy consumption, and thus high cost, call for new, efficient technology. Here, we demonstrate the novel concept of a "desalination battery", which operates by performing cycles in reverse on our previously reported mixing entropy battery. Rather than generating electricity from salinity differences, as in mixing entropy batteries, desalination batteries use an electrical energy input to extract sodium and chloride ions from seawater and to generate fresh water. The desalination battery is comprised by a Na 2-xMn 5O 10 nanorod positive electrode and Ag/AgCl negative electrode. Here, we demonstrate an energy consumption of 0.29 Wh l -1 for the removal of 25% salt using this novel desalination battery, which is promising when compared to reverse osmosis (∼ 0.2 Wh l -1), the most efficient technique presently available. © 2012 American Chemical Society.

  13. Lithium ion battery production

    International Nuclear Information System (INIS)

    Highlights: ► Sustainable battery manufacturing focus on more efficient methods and recycling. ► Temperature control and battery management system increase battery lifetime. ► Focus on increasing battery performance at low- and high temperatures. ► Production capacity of 100 MWh equals the need of 3000 full-electric cars. - Abstract: Recently, new materials and chemistry for lithium ion batteries have been developed. There is a great emphasis on electrification in the transport sector replacing part of motor powered engines with battery powered applications. There are plans both to increase energy efficiency and to reduce the overall need for consumption of non-renewable liquid fuels. Even more significant applications are dependent on energy storage. Materials needed for battery applications require specially made high quality products. Diminishing amounts of easily minable metal ores increase the consumption of separation and purification energy and chemicals. The metals are likely to be increasingly difficult to process. Iron, manganese, lead, zinc, lithium, aluminium, and nickel are still relatively abundant but many metals like cobalt and rare earths are becoming limited resources more rapidly. The global capacity of industrial-scale production of larger lithium ion battery cells may become a limiting factor in the near future if plans for even partial electrification of vehicles or energy storage visions are realized. The energy capacity needed is huge and one has to be reminded that in terms of cars for example production of 100 MWh equals the need of 3000 full-electric cars. Consequently annual production capacity of 106 cars requires 100 factories each with a 300 MWh capacity. Present day lithium ion batteries have limitations but significant improvements have been achieved recently . The main challenges of lithium ion batteries are related to material deterioration, operating temperatures, energy and power output, and lifetime. Increased lifetime

  14. Lithium battery management system

    Science.gov (United States)

    Dougherty, Thomas J.

    2012-05-08

    Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

  15. Polyoxometalate flow battery

    Science.gov (United States)

    Anderson, Travis M.; Pratt, Harry D.

    2016-03-15

    Flow batteries including an electrolyte of a polyoxometalate material are disclosed herein. In a general embodiment, the flow battery includes an electrochemical cell including an anode portion, a cathode portion and a separator disposed between the anode portion and the cathode portion. Each of the anode portion and the cathode portion comprises a polyoxometalate material. The flow battery further includes an anode electrode disposed in the anode portion and a cathode electrode disposed in the cathode portion.

  16. Nanotubes for Battery Applications

    OpenAIRE

    Nordlinder, Sara

    2005-01-01

    Nanomaterials have attracted great interest in recent years, and are now also being considered for battery applications. Reducing the particle size of some electrode materials can increase battery performance considerably, especially with regard to capacity, power and rate capability. This thesis presents a study focused on the performance of such a material, vanadium oxide nanotubes, as cathode material for rechargeable lithium batteries. These nanotubes were synthesized by a sol-gel process...

  17. Intelligent battery energy management and control for vehicle-to-grid via cloud computing network

    International Nuclear Information System (INIS)

    Highlights: • The intelligent battery energy management substantially reduces the interactions of PEV with parking lots. • The intelligent battery energy management improves the energy efficiency. • The intelligent battery energy management predicts the road load demand for vehicles. - Abstract: Plug-in Electric Vehicles (PEVs) provide new opportunities to reduce fuel consumption and exhaust emission. PEVs need to draw and store energy from an electrical grid to supply propulsive energy for the vehicle. As a result, it is important to know when PEVs batteries are available for charging and discharging. Furthermore, battery energy management and control is imperative for PEVs as the vehicle operation and even the safety of passengers depend on the battery system. Thus, scheduling the grid power electricity with parking lots would be needed for efficient charging and discharging of PEV batteries. This paper aims to propose a new intelligent battery energy management and control scheduling service charging that utilize Cloud computing networks. The proposed intelligent vehicle-to-grid scheduling service offers the computational scalability required to make decisions necessary to allow PEVs battery energy management systems to operate efficiently when the number of PEVs and charging devices are large. Experimental analyses of the proposed scheduling service as compared to a traditional scheduling service are conducted through simulations. The results show that the proposed intelligent battery energy management scheduling service substantially reduces the required number of interactions of PEV with parking lots and grid as well as predicting the load demand calculated in advance with regards to their limitations. Also it shows that the intelligent scheduling service charging using Cloud computing network is more efficient than the traditional scheduling service network for battery energy management and control

  18. N-phenylmaleimide as a New Ploymerizable Additive for Overcharge Protection of Lithium-ion Batteries

    Institute of Scientific and Technical Information of China (English)

    B.Wang; Q.Xia; Y.P.Wu

    2007-01-01

    1 Results In persuit of better safety controls of lithium batteries,much efforts has been focused on the development of the internal and self-actuating overcharge protection additives.We report a novel electropolymerizable electrolyte additive for overcharge protection of lithium batteries. Electrochemical properties and overcharge behavior of NPM as a new polymerizable electrolyte additive for overcharge protection of lithium ion batteries are studied by cyclic voltammetry,charge-discharge measurements...

  19. Method for Load Sharing and Power Management in a Hybrid PV/Battery Source Islanded Microgrid

    DEFF Research Database (Denmark)

    Karimi, Yaser; Oraee, Hashem; Guerrero, Josep M.;

    2016-01-01

    This paper presents a decentralized load sharing and power management method for an islanded microgrid composed of PV units, battery units and hybrid PV/battery units. The proposed method performs all the necessary tasks such as load sharing among the units, battery charging and discharging and PV...... power curtailment with no need to any communication among the units. The proposed method is validated experimentally....

  20. Inexpensive method for producing macroporous silicon particulates (MPSPs) with pyrolyzed polyacrylonitrile for lithium ion batteries

    OpenAIRE

    Thakur, Madhuri; Sinsabaugh, Steven L.; Isaacson, Mark J.; Michael S Wong; Biswal, Sibani Lisa

    2012-01-01

    One of the most exciting areas in lithium ion batteries is engineering structured silicon anodes. These new materials promise to lead the next generation of batteries with significantly higher reversible charge capacity than current technologies. One drawback of these materials is that their production involves costly processing steps, limiting their application in commercial lithium ion batteries. In this report we present an inexpensive method for synthesizing macroporous silicon particulat...