WorldWideScience

Sample records for basin volume vi

  1. Underground Test Area Subproject Phase I Data Analysis Task. Volume VI - Groundwater Flow Model Documentation Package

    Energy Technology Data Exchange (ETDEWEB)

    None

    1996-11-01

    Volume VI of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the groundwater flow model data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.

  2. Integrating model of the Project Independence Evaluation System. Volume VI. Data documentation. Part II

    Energy Technology Data Exchange (ETDEWEB)

    Allen, B J

    1979-02-01

    This documentation describes the PIES Integrating Model as it existed on January 1, 1978. This Volume VI of six volumes is data documentation, containing the standard table data used for the Administrator's Report at the beginning of 1978, along with the primary data sources and the office responsible. It also contains a copy of a PIES Integrating Model Report with a description of its content. Following an overview chapter, Chapter II, Supply and Demand Data Tables and Sources for the Mid-range Scenario for Target Years 1985 and 1990, data on demand, price, and elasticity; coal; imports; oil and gas; refineries; synthetics, shale, and solar/geothermal; transportation; and utilities are presented. The following data on alternate scenarios are discussed: low and high demand; low and high oil and gas supply; refinery and oil and gas data assuming a 5% annual increase in real world oil prices. Chapter IV describes the solution output obtained from an execution of PIES.

  3. Monitoring and Evaluation of Smolt Migration in the Columbia River Basin : Volume VI : Evaluation of the 2000 Predictions of the Run-Timing of Wild Migrant Chinook Salmon and Steelhead Trout, and Hatchery Sockeye Salmon in the Snake River Basin, and Combined Wild Hatchery Salminids Migrating to Rock Island and McNary Dams using Program RealTime.

    Energy Technology Data Exchange (ETDEWEB)

    Burgess, Caitlin

    1998-07-01

    Program RealTime provided tracking and forecasting of the 2000 in season outmigration via the internet for stocks of wild PIT-tagged spring/summer chinook salmon. These stocks were ESUs from nineteen release sites above Lower Granite dam, including Bear Valley Creek, Big Creek, Camas Creek (new), Cape Horn Creek, Catherine Creek, Elk Creek, Herd Creek, Imnaha River, Johnson Creek (new), Lake Creek, Loon Creek, Lostine River, Marsh Creek, Minam River, East Fork Salmon River (new), South Fork Salmon River, Secesh River, Sulfur Creek and Valley Creek. Forecasts were also provided for two stocks of hatchery-reared PIT-tagged summer-run sockeye salmon, from Redfish Lake and Alturas Lake (new); for a subpopulation of the PIT-tagged wild Snake River fall subyearling chinook salmon; for all wild Snake River PIT-tagged spring/summer yearling chinook salmon (new) and steelhead trout (new)detected at Lower Granite Dam during the 2000 outmigration. The 2000 RealTime project began making forecasts for combined wild- and hatchery-reared runs-at-large of subyearling and yearling chinook, coho, and sockeye salmon, and steelhead trout migrating to Rock Island and McNary Dams on the mid-Columbia River and the mainstem Columbia River. Due to the new (in 1999-2000) Snake River basin hatchery protocol of releasing unmarked hatchery-reared fish, the RealTime forecasting project no longer makes run-timing forecasts for wild Snake River runs-at-large using FPC passage indices, as it has done for the previous three years (1997-1999). The season-wide measure of Program RealTime performance, the mean absolute difference (MAD) between in-season predictions and true (observed) passage percentiles, improved relative to previous years for nearly all stocks. The average season-wide MAD of all (nineteen) spring/summer yearling chinook salmon ESUs dropped from 5.7% in 1999 to 4.5% in 2000. The 2000 MAD for the hatchery-reared Redfish Lake sockeye salmon ESU was the lowest recorded, at 6.0%, down

  4. Volume of Contamination Poured in Ariguanabo Basin, Artemisa Province, Cuba

    Directory of Open Access Journals (Sweden)

    Barbara Liz Miravet Sanchez

    2016-11-01

    Full Text Available In the Ariguanabo basin were identified and characterized a total of 88 contamination points (66 are populated centers, 14 associated to the centers of breeding of pigs and eight are production and service centers, many of which don’t have treatment of their residual waters. The values of the chemical oxygen demand (QOD, the biochemical oxygen demand (BOD5, the total phosphorus (Pt and the total solids (TS of 14 selected point of contamination amply exceed the established limits in the NC-27-2012. The populated centers with the biggest values of BOD5, QOD, nitrogen (Nt and Pt and the breeding of pigs centers responsible for 46 % of DBO5, 38 % of DQO and more than 95 % of the TS and grease are the fundamental contribution of contamination in the basin. The risk of contamination of the underground waters is very high, even more when the biggest number of points (61% is located in areas with high and extremely high grade of intrinsic vulnerability of the aquifer and the volume of contamination in the basin has come increasing in the last years.

  5. Columbia River Basin Seasonal Volumes and Statistics, 1928-1989. 1990 Level Modified Streamflows Computed Seasonal Volumes 61-Year Statistics.

    Energy Technology Data Exchange (ETDEWEB)

    A.G. Crook Company

    1993-04-01

    This report was prepared by the A.G. Crook Company, under contract to Bonneville Power Administration, and provides statistics of seasonal volumes and streamflow for 28 selected sites in the Columbia River Basin.

  6. Application of Chromium Stable Isotopes to the Evaluation of Cr(VI) Contamination in Groundwater and Rock Leachates from Central Euboea, the Assopos Basin and Thebes Valley (Greece)

    Science.gov (United States)

    Frei, R.; Frei, K. M.; Economou-Eliopoulos, M.; Atsarou, C.; Koilakos, D.

    2014-12-01

    In order to identify the source(s) of toxic Cr(VI) prevalent in drinking and irrigation waters of Central Euboea (CE), the Assopos Basin (AB) and the Thebes Valley (TV;Greece), we have analyzed stable Cr isotopes, together with major and trace elements in porous, karstic and ultramafic mélange-hosted aquifers and groundwaters, ultramafic rocks from the hinterlands and soil samples from cultivated sites of this region. In addition we complemented our data with experimentally produced water leachates of rocks and soils. Mg/Ca ratios >1 in much of the water samples indicate the influence of ultramafic rocks which dominate the geology on the geochemical composition of the groundwaters. Elevated Cr(VI) concentrations in experimental soil leachates, compared to those in rock pulp leachates, can be potentially explained by the presence of larger amounts of Fe(II) and lower amounts of Mn(IV) in the country rocks. Factor analysis on the 17 water samples from TV indicates a strong relationship between Na, Cl-, and Cr(VI), and also points to an aversion of Cr(VI) to nitrates (fertilizer-sewage sourced) and its independency from Mg and SiO2. Assuming that redox processes produce significant Cr isotope fractionation (groundwater δ53Cr values range between +0.62 and +1.99‰), the compilation of the analytical data suggests that the dominant cause of Cr isotope fractionation is post-mobilization reduction of Cr(VI). However, the lack of a clear negative relationship between Cr(VI) concentrations and δ53Cr values may reflect that other processes complicate this interpretation. The variation in δ53Cr values, together with the results from the experimentally produced ultramafic rock pulp leachates, imply initial oxidative mobilization of Cr(VI) from the ultramafic host rocks, followed by reductive processes, as the main reason for the toxicity of the groundwaters. Using a Rayleigh distillation model and different fractionation factors of Cr(VI) reduction valid for aqueous Fe

  7. Background Study of Intact Stability Standards for Dynamically Supported Craft. Volume I - VI. Categorized Bibliographies.

    Science.gov (United States)

    1979-04-01

    Important to Program to Program I - ,.upporting Material REFERENCE EVAI.UATION AND SUBJEI ICT INDEX U) C01Q 4) H a Hal UL0 U .J [,1 -i4 L) I-4 I.,.-4 H...1111 iit eIIIi * I.C.eil vu ’ ict I tes 1 1, I% . l / 1 . ASIJ I 10-tI10 it) 1. Retiumuk-.i : yott Kimm aua iv; t . I .e Serf I o I I Lilt ACVS. VI "A...o -Ist I c . ofI l’tlztI o o i1 MAY o I Sbt i ps" , liv 1ll r - elt . SNAREVtA I AA , May 196 . Set’ BOLIt N(u. n (18. tfiOt*RN~FR "Flid-DlYth,1i~t c

  8. Water resources data, Texas water year 1998, volume 3. Colorado River basin, Lavaca River basin, Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Andrews, F.L.; Barbie, D.L.

    1999-01-01

    Water-resources data for the 1998 water year for Texas are presented in four volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 3 contains records for water discharge at 126 gaging stations; stage only at 3 gaging stations; stage and contents at 15 lakes and reservoirs; water quality at 62 gaging stations; and data for 35 partial-record stations comprised of 8 flood-hydrograph, 14 low-flow, and 18 creststage, and 5 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  9. Water resources data, Texas water year 1998, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, Trinity River Basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Andrews, F.L.; Barbie, D.L.

    1999-01-01

    Water-resources data for the 1998 water year for Texas are presented in four volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 112 gaging stations; stage only at 5 gaging stations; stage and contents at 33 lakes and reservoirs; water quality at 65 gaging stations; and data for 12 partial-record stations comprised of 7 flood-hydrograph, 2 low-flow, and 3 crest-stage stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  10. Integrating model of the Project Independence Evaluation System. Volume VI. Data documentation. Part I

    Energy Technology Data Exchange (ETDEWEB)

    Allen, B J

    1979-02-01

    This documentation describes the PIES Integrating Model as it existed on January 1, 1978. This volume contains two chapters. In Chapter I, Overview, the following subjects are briefly described: supply data, EIA projection series and scenarios, demand data and assumptions, and supply assumptions - oil and gas availabilities. Chapter II contains supply and demand data tables and sources used by the PIES Integrating Model for the mid-range scenario target years 1985 and 1990. Tabulated information is presented for demand, price, and elasticity data; coal data; imports data; oil and gas data; refineries data; synthetics, shale, and solar/geothermal data; transportation data; and utilities data.

  11. II-VI semiconductor compounds

    CERN Document Server

    1993-01-01

    For condensed matter physicists and electronic engineers, this volume deals with aspects of II-VI semiconductor compounds. Areas covered include devices and applications of II-VI compounds; Co-based II-IV semi-magnetic semiconductors; and electronic structure of strained II-VI superlattices.

  12. Water resources data Texas water year 2002, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2003-01-01

    Water-resources data for the 2002 water year for Texas are presented in six volumes and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 63 gaging stations; stage only at 3 gaging stations; stage and contents at 34 lakes and reservoirs; water quality at 35 gaging stations; and data for 8 partial-record stations comprised of 6 flood-hydrograph and 2 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  13. Water resources data Texas water year 2000, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Barbie, D.L.

    2001-01-01

    Water-resources data for the 2000 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 68 gaging stations; stage only at 3 gaging stations; stage and contents at 37 lakes and reservoirs; water quality at 39 gaging stations; and data for 9 partial-record stations comprised of 6 flood-hydrograph and 3 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  14. Water resources data Texas water year 2001, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2002-01-01

    Water-resources data for the 2001 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 68 gaging stations; stage only at 3 gaging stations; stage and contents at 30 lakes and reservoirs; water quality at 40 gaging stations; and data for 12 partial-record stations comprised of 6 flood-hydrograph and 6 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  15. Water resources data Texas water year 1999, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Barbie, D.L.; Jones, R.E.

    2000-01-01

    Water-resources data for the 1999 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 71 gaging stations; stage only at 3 gaging stations; stage and contents at 23 lakes and reservoirs; water quality at 47 gaging stations; and data for 9 partial-record stations comprised of 6 flood-hydrograph and 3 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  16. Water resources data Texas water year 2003, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2004-01-01

    Water-resources data for the 2003 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 72 gaging stations; stage only at 3 gaging stations; stage and contents at 35 lakes and reservoirs; water quality at 28 gaging stations; and data for 9 partial-record stations comprised of 6 flood-hydrograph and 3 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  17. Water resources data Texas, water year 2004, volume 1. Arkansas River basin, Red River basin, Sabine River basin, Neches River basin, and intervening coastal basins

    Science.gov (United States)

    Long, Susan C. Aragon; Reece, Brian D.; Eames, Deanna R.

    2005-01-01

    Water-resources data for the 2004 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 1 contains records for water discharge at 72 gaging stations; stage only at 3 gaging stations; elevation at 29 lakes and reservoirs; content at 6 lakes and reservoirs; and water quality at 26 gaging stations. Also included are data for 9 partial-record stations comprised of 6 flood-hydrograph and 3 low-flow stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  18. Empirical models to predict the volumes of debris flows generated by recently burned basins in the western U.S.

    Science.gov (United States)

    Gartner, J.E.; Cannon, S.H.; Santi, P.M.; deWolfe, V.G.

    2008-01-01

    Recently burned basins frequently produce debris flows in response to moderate-to-severe rainfall. Post-fire hazard assessments of debris flows are most useful when they predict the volume of material that may flow out of a burned basin. This study develops a set of empirically-based models that predict potential volumes of wildfire-related debris flows in different regions and geologic settings. The models were developed using data from 53 recently burned basins in Colorado, Utah and California. The volumes of debris flows in these basins were determined by either measuring the volume of material eroded from the channels, or by estimating the amount of material removed from debris retention basins. For each basin, independent variables thought to affect the volume of the debris flow were determined. These variables include measures of basin morphology, basin areas burned at different severities, soil material properties, rock type, and rainfall amounts and intensities for storms triggering debris flows. Using these data, multiple regression analyses were used to create separate predictive models for volumes of debris flows generated by burned basins in six separate regions or settings, including the western U.S., southern California, the Rocky Mountain region, and basins underlain by sedimentary, metamorphic and granitic rocks. An evaluation of these models indicated that the best model (the Western U.S. model) explains 83% of the variability in the volumes of the debris flows, and includes variables that describe the basin area with slopes greater than or equal to 30%, the basin area burned at moderate and high severity, and total storm rainfall. This model was independently validated by comparing volumes of debris flows reported in the literature, to volumes estimated using the model. Eighty-seven percent of the reported volumes were within two residual standard errors of the volumes predicted using the model. This model is an improvement over previous models in

  19. Water Resources Data. Ohio - Water Year 1992. Volume 1. Ohio River Basin excluding project data

    Energy Technology Data Exchange (ETDEWEB)

    H.L. Shindel; J.H. Klingler; J.P. Mangus; L.E. Trimble

    1993-03-01

    Water-resources data for the 1992 water year for Ohio consist of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and water levels and water quality of ground-water wells. This report, in two volumes, contains records for water discharge at 121 gaging stations, 336 wells, and 72 partial-record sites; and water levels at 312 observation wells. Also included are data from miscellaneous sites. Additional water data were collected at various sites not involved in the systematic data-collection program and are published as miscellaneous measurements and analyses. These data represent that part of the National Water Data System collected by the US Geological Survey and cooperating State and Federal agencies in Ohio. Volume 1 covers the central and southern parts of Ohio, emphasizing the Ohio River Basin. (See Order Number DE95010451 for Volume 2 covering the northern part of Ohio.)

  20. Effects of Time, Heat, and Oxygen on K Basin Sludge Agglomeration, Strength, and Solids Volume

    Energy Technology Data Exchange (ETDEWEB)

    Delegard, Calvin H.; Sinkov, Sergey I.; Schmidt, Andrew J.; Daniel, Richard C.; Burns, Carolyn A.

    2011-01-04

    Sludge disposition will be managed in two phases under the K Basin Sludge Treatment Project. The first phase is to retrieve the sludge that currently resides in engineered containers in the K West (KW) Basin pool at ~10 to 18°C. The second phase is to retrieve the sludge from interim storage in the sludge transport and storage containers (STSCs) and treat and package it in preparation for eventual shipment to the Waste Isolation Pilot Plant. The work described in this report was conducted to gain insight into how sludge may change during long-term containerized storage in the STSCs. To accelerate potential physical and chemical changes, the tests were performed at temperatures and oxygen partial pressures significantly greater than those expected in the T Plant canyon cells where the STSCs will be stored. Tests were conducted to determine the effects of 50°C oxygenated water exposure on settled quiescent uraninite (UO2) slurry and a full simulant of KW containerized sludge to determine the effects of oxygen and heat on the composition and mechanical properties of sludge. Shear-strength measurements by vane rheometry also were conducted for UO2 slurry, mixtures of UO2 and metaschoepite (UO3•2H2O), and for simulated KW containerized sludge. The results from these tests and related previous tests are compared to determine whether the settled solids in the K Basin sludge materials change in volume because of oxidation of UO2 by dissolved atmospheric oxygen to form metaschoepite. The test results also are compared to determine if heating or other factors alter sludge volumes and to determine the effects of sludge composition and settling times on sludge shear strength. It has been estimated that the sludge volume will increase with time because of a uranium metal → uraninite → metaschoepite oxidation sequence. This increase could increase the number of containers required for storage and increase overall costs of sludge management activities. However, the volume

  1. The Department of Energy`s Rocky Flats Plant: A guide to record series useful for health-related research. Volume VI, workplace and environmental monitoring

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-01

    This is the sixth in a series of seven volumes which constitute a guide to records of the Rocky Flats Plant useful for conducting health-related research. The primary purpose of Volume VI is to describe record series pertaining to workplace and environmental monitoring activities at the Department of Energy`s (DOE) Rocky Flats Plant, now named the Rocky Flats Environmental Technology Site, near Denver, Colorado. History Associates Incorporated (HAI) prepared this guide as part of its work as the support services contractor for DOE`s Epidemiologic Records Inventory Project. This introduction briefly describes the Epidemiologic Records Inventory Project and HAI`s role in the project, provides a history of workplace and environmental monitoring practices at Rocky Flats, and identifies organizations contributing to workplace and environmental monitoring policies and activities. Other topics include the scope and arrangement of this volume and the organization to contact for access to these records. Comprehensive introductory and background information is available in Volume I. Other volumes in the guide pertain to administrative and general subjects, facilities and equipment, production and materials handling, waste management, and employee health. In addition, HAI has produced a subject-specific guide, titled The September 1957 Rocky Flats Fire. A Guide to Record Series of the Department of Energy and Its Contractors, which researchers should consult for further information about records related to this incident.

  2. Interpretation of a 3D Seismic-Reflection Volume in the Basin and Range, Hawthorne, Nevada

    Science.gov (United States)

    Louie, J. N.; Kell, A. M.; Pullammanappallil, S.; Oldow, J. S.; Sabin, A.; Lazaro, M.

    2009-12-01

    A collaborative effort by the Great Basin Center for Geothermal Energy at the University of Nevada, Reno, and Optim Inc. of Reno has interpreted a 3d seismic data set recorded by the U.S. Navy Geothermal Programs Office (GPO) at the Hawthorne Army Depot, Nevada. The 3d survey incorporated about 20 NNW-striking lines covering an area of approximately 3 by 10 km. The survey covered an alluvial area below the eastern flank of the Wassuk Range. In the reflection volume the most prominent events are interpreted to be the base of Quaternary alluvium, the Quaternary Wassuk Range-front normal fault zone, and sequences of intercalated Tertiary volcanic flows and sediments. Such a data set is rare in the Basin and Range. Our interpretation reveals structural and stratigraphic details that form a basis for rapid development of the geothermal-energy resources underlying the Depot. We interpret a map of the time-elevation of the Wassuk Range fault and its associated splays and basin-ward step faults. The range-front fault is the deepest, and its isochron map provides essentially a map of "economic basement" under the prospect area. There are three faults that are the most readily picked through vertical sections. The fault reflections show an uncertainty in the time-depth that we can interpret for them of 50 to 200 ms, due to the over-migrated appearance of the processing contractor’s prestack time-migrated data set. Proper assessment of velocities for mitigating the migration artifacts through prestack depth migration is not possible from this data set alone, as the offsets are not long enough for sufficiently deep velocity tomography. The three faults we interpreted appear as gradients in potential-field maps. In addition, the southern boundary of a major Tertiary graben may be seen within the volume as the northward termination of the strong reflections from older Tertiary volcanics. Using a transparent volume view across the survey gives a view of the volcanics in full

  3. Computational Studies of Hard Disks: Contact Percolation, Fragility, Frictional Families and Basin Volumes

    Science.gov (United States)

    Shen, Tianqi

    This thesis presents four computational and theoretical studies of the structural, mechanical, and vibrational properties of purely repulsive disks, dimer-, and ellipse-shaped particles with and without friction. The first study investigated the formation of interparticle contact networks below jamming onset at packing fraction φJ, where the pressure of the system becomes nonzero. We generated ensembles of static packings of frictionless disks over a range of packing fraction. We find that the network of interparticle contacts forms a system spanning cluster at a critical packing fraction φP missing contacts relative to the isostatic value N0c We show that the probability Pm(micro) to obtain a static packing with m missing contacts at micro can be expressed as a power series in micro. Using Pm(micro), we find that the average contact number versus micro agrees quantitatively with that from simulations of the Cundall-Strack model for frictional disks. In the final project, we performed calculations of the structure of the basin volumes of mechanically stable packings in configuration space as a function packing fraction. Using the basin volumes, we show that the probability to obtain a given MS packing depends strongly on the packing fraction of the initial configuration.

  4. Strategic Requirements for the Army to the Year 2000. Volume VI. East Asia and the Western Pacific Basin.

    Science.gov (United States)

    1982-11-01

    polluted Japan with a left-wing blue collar labor movement, and a I greater dependence than ever on South Asian food and raw materials, particularly...1979) discusses the relative merits for the purpose of Darwin, Cockburn Sound, Surabaya, Penang , and Singapore. To that list might be added Guam, North... waters , and off-shore resources. Put it also seems clear that the Communist side wants to achieve these ends with the minimum use of force. They have other

  5. Water resources data Texas water year 2001, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2002-01-01

    Water-resources data for the 2001 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 77 gaging stations; stage only at 4 gaging stations; stage and contents at 5 lakes and reservoirs; water quality at 27 gaging stations; and data for 23 partial-record stations comprised of 3 flood-hydrograph, 8 low-flow, 4 crest-stage, and 3 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  6. Water resources data Texas water year 2003, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2004-01-01

    Water-resources data for the 2003 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 84 gaging stations; stage only at 6 gaging stations; stage and contents at 6 lakes and reservoirs; water quality at 28 gaging stations; and data for 18 partial-record stations comprised of 1 flood-hydrograph, 10 low-flow, 4 crest-stage, and 3 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  7. Water resources data Texas water year 1999, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Barbie, D.L.; Jones, R.E.

    2000-01-01

    Water-resources data for the 1999 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 76 gaging stations; stage only at 1 gaging stations; stage and contents at 4 lakes and reservoirs; water quality at 38 gaging stations; and data for 30 partial-record stations comprised of 3 flood-hydrograph, 14 low-flow, and 8 crest-stage, and 5 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  8. Water resources data Texas water year 2002, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, Susan C.

    2003-01-01

    Water-resources data for the 2002 water year for Texas are presented in six volumes and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 82 gaging stations; stage only at 6 gaging stations; stage and contents at 8 lakes and reservoirs; water quality at 25 gaging stations; and data for 30 partial-record stations comprised of 2 flood-hydrograph, 6 low-flow, 4 crest-stage, and 18 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  9. Water resources data Texas water year 2000, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Gandara, S.C.; Gibbons, W.J.; Barbie, D.L.

    2001-01-01

    Water-resources data for the 2000 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 71 gaging stations; stage only at 4 gaging stations; stage and contents at 4 lakes and reservoirs; water quality at 29 gaging stations; and data for 23 partial-record stations comprised of 3 flood-hydrograph, 10 low-flow, 6 crest-stage, and 4 miscellaneous stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  10. Water resources data Texas, water year 2004, volume 5. Guadalupe River basin, Nueces River basin, Rio Grande basin, and intervening coastal basins

    Science.gov (United States)

    Long, Susan C. Aragon; Reece, Brian D.; Eames, Deanna R.

    2005-01-01

    Water-resources data for the 2004 water year for Texas are presented in six volumes, and consist of records of stage, discharge, and water quality of streams and canals; stage, contents, and water-quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 5 contains records for water discharge at 86 gaging stations; stage only at 5 gaging stations; elevation at 3 lakes and reservoirs; content at 4 lakes and reservoirs;and water quality at 24 gaging stations. Also included are data for 16 partial-record stations comprised of 1 flood-hydrograph, 11 low-flow, and 4 crest-stage stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations. Additional water data were collected at various sites, not part of the systematic data-collection program, and are published as miscellaneous measurements. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating Federal, State, and local agencies in Texas. Records for a few pertinent stations in the bordering States also are included.

  11. Mucopolysaccharidosis VI

    Directory of Open Access Journals (Sweden)

    Harmatz Paul

    2010-04-01

    Full Text Available Abstract Mucopolysaccharidosis VI (MPS VI is a lysosomal storage disease with progressive multisystem involvement, associated with a deficiency of arylsulfatase B leading to the accumulation of dermatan sulfate. Birth prevalence is between 1 in 43,261 and 1 in 1,505,160 live births. The disorder shows a wide spectrum of symptoms from slowly to rapidly progressing forms. The characteristic skeletal dysplasia includes short stature, dysostosis multiplex and degenerative joint disease. Rapidly progressing forms may have onset from birth, elevated urinary glycosaminoglycans (generally >100 μg/mg creatinine, severe dysostosis multiplex, short stature, and death before the 2nd or 3rd decades. A more slowly progressing form has been described as having later onset, mildly elevated glycosaminoglycans (generally ARSB gene, located in chromosome 5 (5q13-5q14. Over 130 ARSB mutations have been reported, causing absent or reduced arylsulfatase B (N-acetylgalactosamine 4-sulfatase activity and interrupted dermatan sulfate and chondroitin sulfate degradation. Diagnosis generally requires evidence of clinical phenotype, arylsulfatase B enzyme activity ®, clinical management was limited to supportive care and hematopoietic stem cell transplantation. Galsulfase is now widely available and is a specific therapy providing improved endurance with an acceptable safety profile. Prognosis is variable depending on the age of onset, rate of disease progression, age at initiation of ERT and on the quality of the medical care provided.

  12. Precipitation Frequency for Ohio River Basin, USA - NOAA Atlas 14 Volume 2

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This GIS grid atlas contains precipitation frequency estimates for the Ohio River Basin and Surrounding states is based on precipitation data collected between...

  13. H-Area Seepage Basins Groundwater Monitoring Report: Volume 1, Third and Fourth quarters 1994

    Energy Technology Data Exchange (ETDEWEB)

    Chase, J.A.

    1994-03-01

    Isoconcentration/isocactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units during the second half of 1994. Geologic cross sections indicate both the extent and depth of contamination of the primary contaminants in all of the hydrostratigraphic units during the second half of 1994. Water-level maps indicate that the groundwater flow rates and directions at the H-Area Seepage Basins have remained relatively constant since the basins ceased to be active in 1988.

  14. Methodologies for Assessing the Cumulative Environmental Effects of Hydroelectric Development of Fish and Wildlife in the Columbia River Basin, Volume 1, Recommendations, 1987 Final Report.

    Energy Technology Data Exchange (ETDEWEB)

    Stull, Elizabeth Ann

    1987-07-01

    This volume is the first of a two-part set addressing methods for assessing the cumulative effects of hydropower development on fish and wildlife in the Columbia River Basin. Species and habitats potentially affected by cumulative impacts are identified for the basin, and the most significant effects of hydropower development are presented. Then, current methods for measuring and assessing single-project effects are reviewed, followed by a review of methodologies with potential for use in assessing the cumulative effects associated with multiple projects. Finally, two new approaches for cumulative effects assessment are discussed in detail. Overall, this report identifies and reviews the concepts, factors, and methods necessary for understanding and conducting a cumulative effects assessment in the Columbia River Basin. Volume 2 will present a detailed procedural handbook for performing a cumulative assessment using the integrated tabular methodology introduced in this volume. 308 refs., 18 figs., 10 tabs.

  15. GIS (Geographic Information Systems) based calculation on hydrocarbon generated volume: Amazon Basin example; O uso de SIG no calculo de hidrocarbonetos gerados: exemplo da Bacia do Amazonas

    Energy Technology Data Exchange (ETDEWEB)

    Pedrinha, Saulo; Simoes, Leonardo; Goncalves, Felix T.T.; Carneiro, Jason T.G. [Petroleum Geoscience Technology Ltda. (PGT), Rio de Janeiro, RJ (Brazil)

    2008-07-01

    The calculation of the volume of hydrocarbons generated from a particular source rock a sedimentary basin provides numerical data that help to better describe the petroleum system, and evaluate its potential. Among the various methodologies developed for calculating the volume of oil there is a proposal by Schmoker (1994), which has the advantage to take into account the occurrence of the source rock area in the basin, and the spatial variations in the main geological parameters. Using the tools of a GIS, through the manipulation of georeferred maps, it is possible to calculate the volume of oil generated in a way that would be virtually impossible by using punctual data, only. Even the discretiation maps in minors areas allows, via attribute table in the GIS, the application of a Monte Carlo simulation, which allows to incorporate all the uncertainties related to the input data in the calculation, obtaining distributions of volumes associated with various parts of the final map being integrated throughout the basin. Isopac and maturation maps (Gonzaga et al., 2000), along with TOC data from Barreirinha formation, Amazon Basin, have been scanned and georeferred and, once in the GIS database, were treated in order to spatially distribute the geological properties of the source rock. Then, such maps were handled in accordance with Schmoker (1994) method, leading to a map of mass and distribution of oil generated in the basin at the regional scale. (author)

  16. F-Area Seepage Basins groundwater monitoring report -- third and fourth quarters 1993. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    Butler, C.T.

    1994-03-01

    During the second half of 1993, the groundwater at the F-Area Seepage Basins (FASB) was monitored in compliance with Module 3, Section C, of South Carolina Hazardous Waste Permit SC1-890-008-989, effective November 2, 1992. The monitoring well network is composed of 87 FSB wells screened in the three hydrostratigraphic units that make up the uppermost aquifer beneath the FASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the F-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. Beginning in the first quarter of 1993, the standard for comparison became the SCDHEC Groundwater Protection Standard (GWPS) specified in the approved F-Area Seepage Basins Part B permit. Currently and historically, gross alpha, nitrate, nonvolatile beta, and tritium are among the primary constituents to exceed standards. Numerous other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the FASB during the second half of 1993, notably aluminum, iodine-129, and zinc. The elevated constituents are found primarily in Aquifer Zone 2B{sub 2} and Aquifer Zone 2B{sub 1} wells. However, several Aquifer Unit 2A wells also contain elevated levels of constituents. Isoconcentration/isoactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units. Water-level maps indicate that the groundwater flow rates and directions at the FASB have remained relatively constant since the basins ceased to be active in 1988.

  17. Global Spent Fuel Logistics Systems Study (GSFLS). Volume 4. Pacific basin spent fuel logistics system

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-06-01

    This report summarizes the conceptual framework for a Pacific Basin Spent Fuel Logistics System (PBSFLS); and preliminarily describes programatic steps that might be taken to implement such a system. The PBSFLS concept is described in terms of its technical and institutional components. The preferred PBSFLS concept embodies the rationale of emplacing a fuel cycle system which can adjust to the technical and institutional non-proliferation solutions as they are developed and accepted by nations. The concept is structured on the basis of initially implementing a regional spent fuel storage and transportation system which can technically and institutionally accommodate downstream needs for energy recovery and long-term waste management solutions.

  18. Environmental status of the Lake Michigan region. Volume 14. Birds of the Lake Michigan drainage basin

    Energy Technology Data Exchange (ETDEWEB)

    Wallace, G.J.

    1977-07-01

    This report characterizes the bird life found in 100 counties of the four states peripheral to Lake Michigan. It discusses major habitats (the Lake Michigan shoreline, inland lakes, rivers and streams, marshes, fields and open spaces, and woodlots) and associates specific birds with habitats according to preferences for space and food. It also discusses the special attributes of state parks and lakeshores, refuges and sanctuaries, and other special areas which are attractive to avifauna. Patterns of historical occurrence and abundance, and the influence of pesticides and pollution, disease, and hunting pressure are explored to place present occurrence in a modern perspective. Migration patterns are discussed to explain increases and decreases which occur in nonresident avifauna of the Basin. The distribution and habits of birds that occur regularly in the Basin are described in an annotated list; a more complete list is presented in a table which encapsulates data for rapid and convenient reference. Separate sections deal with extinct, extirpated, and introduced species, and with endangered, threatened, and declining species.

  19. Tsunami waves generated by submarine landslides of variable volume: analytical solutions for a basin of variable depth

    Directory of Open Access Journals (Sweden)

    I. Didenkulova

    2010-11-01

    Full Text Available Tsunami wave generation by submarine landslides of a variable volume in a basin of variable depth is studied within the shallow-water theory. The problem of landslide induced tsunami wave generation and propagation is studied analytically for two specific convex bottom profiles (h ~ x4/3 and h ~ x4. In these cases the basic equations can be reduced to the constant-coefficient wave equation with the forcing determined by the landslide motion. For certain conditions on the landslide characteristics (speed and volume per unit cross-section the wave field can be described explicitly. It is represented by one forced wave propagating with the speed of the landslide and following its offshore direction, and two free waves propagating in opposite directions with the wave celerity. For the case of a near-resonant motion of the landslide along the power bottom profile h ~ xγ the dynamics of the waves propagating offshore is studied using the asymptotic approach. If the landslide is moving in the fully resonant regime the explicit formula for the amplitude of the wave can be derived. It is demonstrated that generally tsunami wave amplitude varies non-monotonically with distance.

  20. F-area seepage basins groundwater monitoring report. Volume 1. First and second quarters 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    Groundwater at the F-Area Seepage Basins (FASB) is monitored in compliance with Module 111, Section C, of South Carolina Hazardous Waste Permit SCl-890-008-989, effective November 2, 1992. The monitoring well network is composed of 86 FSB wells and well HSB 85A. These wells are screened in the three hydrostratigraphic Units that make up the uppermost aquifer beneath the FASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the F-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1900. Data from 9 FSL wells are included in this report only to provide additional information for this area; the FSL wells are not part of Permit SCl-890-008-989. Monitoring results are compared to the SCDHEC Groundwater Protection Standard (GWPS), which is specified in the approved F-Area Seepage Basins Part B permit (November 1992). Historically and currently, gross alpha, nitrate, nonvolatile beta, and tritium are among the primary constituents to exceed standards. Numerous other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the FASB during the first half of 1995, notably aluminum, iodine-129, pH, strontium-90, and zinc. The elevated constituents are found primarily in Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1}, (Barnwell/McBean) wells. However, several Aquifer Unit IIA (Congaree) wells also contain elevated levels of constituents. Isoconcentration/isoactivity maps included in this report indicate both the concentration/activity and extent of the primary contaminants in each of the three hydrostratigraphic units. Geologic cross sections indicate both the extent and depth of contamination of the primary contaminants in all of the hydrostratigraphic units during the first half of 1995.

  1. Soil Properties Database of Spanish Soils. Volume VI.- Andalucia (a): Jaen, Cordoba, Sevilla and Huelva; Base de Datos de Propiedades Edafologicas de los Suelos Espanoles. Volumen VI.- Andalucia (a): Jaen, Cordoba, Sevilla y Huelva

    Energy Technology Data Exchange (ETDEWEB)

    Trueba, C.; Millan, R.; Schmid, T.; Lago, C. [Ciemat. Madrid (Spain); Roquero, C.; Magister, M. [UPM. Madrid (Spain)

    1999-05-01

    The soil vulnerability determines the sensitivity of the soil after an accidental radioactive contamination due to Cs-137 and Sr-90. The Department de Impacto Ambiental de la Energia of CIEMAT is carrying out an assessment of the radiological vulnerability of the different Spanish soils found on the Iberian Peninsula. This requires the knowledge of the soil properties for the various types of existing soils. In order to achieve this aim, a bibliographical compilation of soil profiles has been made to characterize the different soil types and create a database of their properties. Depending on the year of publication and the type of documentary source, the information compiled from the available bibliography is very heterogeneous. Therefore, an important effort has been made to normalize and process the information prior to its incorporation to the database. This volume presents the criteria applied to normalize and process the data as well as the soil properties of the various soil types belonging to the provinces of Jaen, Cordoba, Sevilla and Huelva of the Comunidad Autonoma de Andalucia. (Author) 67 refs.

  2. Water Resources Data Ohio: Water year 1994. Volume 1, Ohio River Basin excluding Project Data

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS) in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synoptic sites, and partial-record sit -aid (4) water-level data for observation wells. Locations of lake-and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures 8a through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two or three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.

  3. An initial abstraction and constant loss model, and methods for estimating unit hydrographs, peak streamflows, and flood volumes for urban basins in Missouri

    Science.gov (United States)

    Huizinga, Richard J.

    2014-01-01

    Streamflow data, basin characteristics, and rainfall data from 39 streamflow-gaging stations for urban areas in and adjacent to Missouri were used by the U.S. Geological Survey in cooperation with the Metropolitan Sewer District of St. Louis to develop an initial abstraction and constant loss model (a time-distributed basin-loss model) and a gamma unit hydrograph (GUH) for urban areas in Missouri. Study-specific methods to determine peak streamflow and flood volume for a given rainfall event also were developed.

  4. Water resources data, Ohio: Water year 1991. Volume 1, Ohio River Basin excluding project data

    Energy Technology Data Exchange (ETDEWEB)

    Shindel, H.L.; Klingler, J.H.; Mangus, J.P.; Trimble, L.E.

    1992-03-01

    Water-resources data for the 1991 water year for Ohio consist of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and water levels and water quality of ground-water wells. This report, in two volumes, contains records for water discharge at 131 gaging stations, 378 wells, and 74 partial-record sites; and water levels at 431 observation wells. Also included are data from miscellaneous sites. Additional water data were collected at various sites not involved in the systematic data-collection program and are published as miscellaneous measurements and analyses. These data represent that part of the National Water Data System collected by the US Geological Survey and cooperating State and Federal agencies in Ohio.

  5. Water resources data, Ohio: Water year 1991. Volume 2, St. Lawrence River Basin: Statewide project data

    Energy Technology Data Exchange (ETDEWEB)

    Shindel, H.L.; Klingler, J.H.; Mangus, J.P.; Trimble, L.E.

    1992-03-01

    The Water Resources Division of the US Geological Survey (USGS), in cooperation with State agencies, obtains a large amount of data pertaining to the water resources of Ohio each water year. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, the data are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for 131 streamflow-gaging stations, 95 miscellaneous sites; (2) stage and content records for 5 streams, lakes, and reservoirs; (3) water-quality for 40 streamflow-gaging stations, 378 wells, and 74 partial-record sites; and (4) water levels for 431 observation wells.

  6. Potential use of geothermal resources in the Snake River Basin: an environmental overview. Volume I

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, S.G.; Russell, B.F.; Sullivan, J.F. (eds.)

    1979-09-01

    Environmental baseline data for the Snake River Plain known geothermal resource areas (KGRAs) are evaluated for geothermal development. The objective is to achieve a sound data base prior to geothermal development. These KGRAs are: Vulcan Hot Springs, Crane Creek, Castle Creek, Bruneau, Mountain Home, Raft River, Island Park, and Yellowstone. Air quality, meteorology, hydrology, water quality, soils, land use, geology, subsidence, seismicity, terrestrial and aquatic ecology, demography, socioeconomics, and heritage resources are analyzed. This program includes a summary of environmental concerns related to geothermal development in each of the KGRAs, an annotated bibliography of reference materials (Volume II), detailed reports on the various program elements for each of the KGRAs, a program plan identifying future research needs, and a comprehensive data file.

  7. Cu vi parolas Esperante?

    Institute of Scientific and Technical Information of China (English)

    Andrzej; Pettyn

    1999-01-01

    LA DEKA LECIONOKiom da mono vi bezonas?—Barbara:Mi foriras aeti ion pormani.u vi deziras ion de mi?—Sinjoro Petro(la edzo de Barbara):Aetu por mi skatolon da cigaredoj aǔeble...aetu por mi du skatolojn dacigaredoj kaj unu skatolon da alume-toj.—B:Bone.u vi ankoraǔ deziras ion?—P:Ne,dankon.Estasio.u vihavas monon?

  8. Projections of Demand for Waterborne Transportation, Ohio River Basin, 1980, 1990, 2000, 2020, 2040. Volume 8. Group VI. Chemicals & Chemical Fertilizers.

    Science.gov (United States)

    1980-12-01

    yields essential for profitable crop production. Because different crops and soils require different quantities and blends of nutrients...distri- bution of such other products as petroleum refining and related industries, plastic products, natural gas and crude oil extraction , and...Inks, printing Orange oil Le.,mon oil Citrus oils , nec. Peppermint oil Spearmint oil Cedarwood oil , clove oil and nutmeg oil Source: Prepared by

  9. Cu vi parolas Esperante?

    Institute of Scientific and Technical Information of China (English)

    Andrzej; Pettyn

    2000-01-01

    LA DEKKVARA LEOIONOMi havas por vi surprizon—Barbara:Bonan matenon!—Petro:Bonan matenon,mia kara!—B Mi havas pot vi surprizon.—P:Viiam havas pot mi surprizojn.—B:Sed hodiaǔ mi parolas treserioze."Okaze de via naskitago ak-

  10. Geochemical constraints on the origin and volume of gas in the New Albany Shale (Devonian-Mississippian), eastern Illinois Basin

    Science.gov (United States)

    Strapoc, D.; Mastalerz, Maria; Schimmelmann, A.; Drobniak, A.; Hasenmueller, N.R.

    2010-01-01

    This study involved analyses of kerogen petrography, gas desorption, geochemistry, microporosity, and mesoporosity of the New Albany Shale (Devonian-Mississippian) in the eastern part of the Illinois Basin. Specifically, detailed core analysis from two locations, one in Owen County, Indiana, and one in Pike County, Indiana, has been conducted. The gas content in the locations studied was primarily dependent on total organic carbon content and the micropore volume of the shales. Gas origin was assessed using stable isotope geochemistry. Measured and modeled vitrinite reflectance values were compared. Depth of burial and formation water salinity dictated different dominant origins of the gas in place in the two locations studied in detail. The shallower Owen County location (415-433 m [1362-1421 ft] deep) contained significant additions of microbial methane, whereas the Pike County location (832-860 m [2730-2822 ft] deep) was characterized exclusively by thermogenic gas. Despite differences in the gas origin, the total gas in both locations was similar, reaching up to 2.1 cm3/g (66 scf/ton). Lower thermogenic gas content in the shallower location (lower maturity and higher loss of gas related to uplift and leakage via relaxed fractures) was compensated for by the additional generation of microbial methane, which was stimulated by an influx of glacial melt water, inducing brine dilution and microbial inoculation. The characteristics of the shale of the Maquoketa Group (Ordovician) in the Pike County location are briefly discussed to provide a comparison to the New Albany Shale. Copyright ??2010. The American Association of Petroleum Geologists. All rights reserved.

  11. Solar Pilot Plant, Phase I. Preliminary design report. Volume VI. Electrical power generation; master control subsystems; balance of plant CDRL item 2

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-05-01

    The Honeywell electrical power generation subsystem centers on a General Electric dual admission, triple extraction turbine generator sized to the output requirements of the Pilot Plant. The turbine receives steam from the receiver subsystem and/or the thermal storage subsystem and supplies those subsystems with feedwater. The turbine condensor is wet cooled. The plant control system consists of a coordinated digital master and subsystem digital/analog controls. The remainder of the plant, work spaces, maintenance areas, roads, and reception area are laid out to provide maximum convenience compatible with utility and safety. Most of the activities are housed in a complex around the base of the receiver tower. This volume contains a description of the relationship of the electrical power generation subsystem to the rest of the plant, the design methodology and evolution, the interface integration and control, and the operation and maintenance procedures.

  12. Environmental status of the Lake Michigan region. Volume 16. Amphibians and reptiles of the Lake Michigan drainage basin

    Energy Technology Data Exchange (ETDEWEB)

    Pentecost, E.D.; Vogt, R.C.

    1976-07-01

    The focus of this report is on regional distribution of the herpetofauna of the Lake Michigan Drainage Basin. The introduction includes a brief discussion of plant communities and their associated herpetofauna, and the importance of hibernacula and migration routes. Some aspects of the status, distribution, habitat, and life history of the amphibians and reptiles of the Basin are described in an annotated checklist. Special attention is given to uncommon and endangered species. Species range is shown on distribution maps.

  13. Vi, de civiliserede

    DEFF Research Database (Denmark)

    Nyemann, Dorthe

    2016-01-01

    Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?......Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?...

  14. Assessment of retention basin volume and outlet capacity in urban stormwater drainage systems with respect to water quality

    Indian Academy of Sciences (India)

    Mehmet A Yurdusev; Ahmet A Kumanlioğlu; Bekir Solmaz

    2005-12-01

    The quality of river water or other surface waters is detrimentally affected by the contaminants carried by the rainfall runoff in urban areas. The control of pollution moved by rainfall runoff is achieved by installing outlets and small retention basins in stormwater collection systems, thereby allowing only a certain amount of rainfall water to overflow and leading the remaining to treatment plants. This study analyses the effect of concentration time on surface water pollution caused by rainfall runoff. For this purpose, a linear -curve is assumed for the flow hydrograph arising from the collection system, based on parameters of rainfall considered and the catchment area. An independent code is developed to analyse such a system and this is applied to an urban area using nine-year single-discrete rainfall records of Izmir Station, Turkey. The system is capable of tackling situations where there is only a basin or a basin with outlet.

  15. Riparian Cottonwood Ecosystems and Regulated Flows in Kootenai and Yakima Sub-Basins : Volume II Yakima (Overview, Report, Appendices).

    Energy Technology Data Exchange (ETDEWEB)

    Jamieson, Bob; Braatne, Jeffrey H.

    2001-10-01

    Riparian vegetation and especially cottonwood and willow plant communities are dependent on normative flows and especially, spring freshette, to provide conditions for recruitment. These plant communities therefore share much in common with a range of fish species that require natural flow conditions to stimulate reproduction. We applied tools and techniques developed in other areas to assess riparian vegetation in two very different sub-basins within the Columbia Basin. Our objectives were to: Document the historic impact of human activity on alluvial floodplain areas in both sub-basins; Provide an analysis of the impacts of flow regulation on riparian vegetation in two systems with very different flow regulation systems; Demonstrate that altered spring flows will, in fact, result in recruitment to cottonwood stands, given other land uses impacts on each river and the limitations imposed by other flow requirements; and Assess the applicability of remote sensing tools for documenting the distribution and health of cottonwood stands and riparian vegetation that can be used in other sub-basins.

  16. Riparian Cottonwood Ecosystems and Regulated Flows in Kootenai and Yakima Sub-Basins : Volume III (Overview and Tools).

    Energy Technology Data Exchange (ETDEWEB)

    Jamieson, Bob; Braatne, Jeffrey H.

    2001-10-01

    Riparian vegetation and especially cottonwood and willow plant communities are dependent on normative flows and especially, spring freshette, to provide conditions for recruitment. These plant communities therefore share much in common with a range of fish species that require natural flow conditions to stimulate reproduction. We applied tools and techniques developed in other areas to assess riparian vegetation in two very different sub-basins within the Columbia Basin. Our objectives were to: Document the historic impact of human activity on alluvial floodplain areas in both sub-basins; Provide an analysis of the impacts of flow regulation on riparian vegetation in two systems with very different flow regulation systems; Demonstrate that altered spring flows will, in fact, result in recruitment to cottonwood stands, given other land uses impacts on each river and the limitations imposed by other flow requirements; and Assess the applicability of remote sensing tools for documenting the distribution and health of cottonwood stands and riparian vegetation that can be used in other sub-basins.

  17. Journal of Undergraduate Research, Volume VI, 2006

    Energy Technology Data Exchange (ETDEWEB)

    Faletra, P.; Schuetz, A.; Cherkerzian, D.; Clark, T.

    2006-01-01

    Students who conducted research at DOE National Laboratories during 2005 were invited to include their research abstracts, and for a select few, their completed research papers in this Journal. This Journal is direct evidence of students collaborating with their mentors. Fields in which these students worked include: Biology; Chemistry; Computer Science; Engineering; Environmental Science; General Sciences; Materials Sciences; Medical and Health Sciences; Nuclear Sciences; Physics; and Science Policy.

  18. Deburring: an annotated bibliography. Volume VI

    Energy Technology Data Exchange (ETDEWEB)

    Gillespie, L.K.

    1980-07-01

    An annotated summary of 138 articles and publications on burrs, burr prevention and deburring is presented. Thirty-seven deburring processes are listed. Entries cited include English, Russian, French, Japanese, and German language articles. Entries are indexed by deburring processes, author, and language. Indexes also indicate which references discuss equipment and tooling, how to use a proces economics, burr properties, and how to design to minimize burr problems. Research studies are identified as are the materials deburred.

  19. Forensic Journal, Volume VI, January 1984.

    Science.gov (United States)

    Forensic Journal, 1984

    1984-01-01

    While covering various English language forensics activities in Japan, this special journal issue is heavily devoted to debate. The 22 articles in the journal are divided into five sections as follows: (1) general information on the Japan English Forensics Association (JEFA); (2) debate, including reports on debate tournaments around the world, a…

  20. Engineering Test Satellite VI (ETS-VI)

    Science.gov (United States)

    Horii, M.; Funakawa, K.

    1991-01-01

    The Engineering Test Satellite-VI (ETS-VI) is being developed as the third Japanese three-axis stabilized engineering test satellite to establish the 2-ton geostationary operational satellite bus system and to demonstrate the high performance satellite communication technology for future operational satellites. The satellite is expected to be stationed at 154 deg east latitude. It will be launched from the Tanegashima Space Center in Japan by a type H-II launch vehicle. The Deep Space Network (DSN) will support the prelaunch compatibility test, data interface verification testing, and launch rehersals. The DSN primary support period is from launch through the final AEF plus 1 hour. Contingency support is from final AEF plus 1 hour until launch plus 1 month. The coverage will consist of all the 26-m antennas as prime and the 34-m antennas at Madrid and Canberra as backup. Maximum support will consist of two 8-hour tracks per station for a 7-day period, plus the contingency support, if required. Information is given in tabular form for DSN support, telemetry, command, and tracking support responsibility.

  1. Protostars and Planets VI

    Science.gov (United States)

    Beuther, Henrik; Klessen, Ralf S.; Dullemond, Cornelis P.; Henning, Thomas

    star and planet formation. They are used by students to dive into new topics, and they are much valued by experienced researchers as a comprehensive overview of the field with all its interactions. We hope that you will enjoy reading (and learning from) this book as much as we do. The organization of the Protostars and Planets conference was carried out in close collaboration between the Max Planck Institute for Astronomy and the Center for Astronomy of the University Heidelberg, with generous support from the German Science Foundation. This volume is a product of effort and care by many people. First and foremost, we want to acknowledge the 250 contributing authors, as it is only due to their expertise and knowledge that such a comprehensive review compendium in all its depth and breadth is possible. The Protostars and Planets VI conference and this volume was a major undertaking, with support and contributions by many people and institutions. We like to thank the members of the Scientific Advisory Committee who selected the 38 teams and chapters out of more than 120 submitted proposals. Similarly, we are grateful to the reviewers, who provided valuable input and help to the chapter authors. The book would also not have been possible without the great support of Renée Dotson and other staff from USRA’s Lunar and Planetary Institute, who handled the detailed processing of all manuscripts and the production of the book, and of Allyson Carter and other staff from the University of Arizona Press. We are also grateful to Richard Binzel, the General Editor of the Space Science Series, for his constant support during the long process, from the original concept to this final product. Finally, we would like to express a very special thank you to the entire conference local organizing committee, and in particular, Carmen Cuevas and Natali Jurina, for their great commitment to the project and for a very fruitful and enjoyable collaboration.

  2. Projections of Demand for Waterborne Transportation, Ohio River Basin, 1980, 1990, 2000, 2020, 2040. Volume 5. Group III. Crude Petroleum.

    Science.gov (United States)

    1980-12-01

    Petroleum Administration for Defense District II (PADD II), which includes major crude oil production areas in the Ohio fiver Basin, reported an excess of...the total disappearance of local movements. This occurred partly because of the decrease in crude oil production in the PSAs, but mostly because of...Production, on the other hand, decreased rapidly and steadily throughout the period. In 1976, crude oil production in the study area was estimated at only 48

  3. KENO-VI Primer: A Primer for Criticality Calculations with SCALE/KENO-VI Using GeeWiz

    Energy Technology Data Exchange (ETDEWEB)

    Bowman, Stephen M [ORNL

    2008-09-01

    The SCALE (Standardized Computer Analyses for Licensing Evaluation) computer software system developed at Oak Ridge National Laboratory is widely used and accepted around the world for criticality safety analyses. The well-known KENO-VI three-dimensional Monte Carlo criticality computer code is one of the primary criticality safety analysis tools in SCALE. The KENO-VI primer is designed to help a new user understand and use the SCALE/KENO-VI Monte Carlo code for nuclear criticality safety analyses. It assumes that the user has a college education in a technical field. There is no assumption of familiarity with Monte Carlo codes in general or with SCALE/KENO-VI in particular. The primer is designed to teach by example, with each example illustrating two or three features of SCALE/KENO-VI that are useful in criticality analyses. The primer is based on SCALE 6, which includes the Graphically Enhanced Editing Wizard (GeeWiz) Windows user interface. Each example uses GeeWiz to provide the framework for preparing input data and viewing output results. Starting with a Quickstart section, the primer gives an overview of the basic requirements for SCALE/KENO-VI input and allows the user to quickly run a simple criticality problem with SCALE/KENO-VI. The sections that follow Quickstart include a list of basic objectives at the beginning that identifies the goal of the section and the individual SCALE/KENO-VI features that are covered in detail in the sample problems in that section. Upon completion of the primer, a new user should be comfortable using GeeWiz to set up criticality problems in SCALE/KENO-VI. The primer provides a starting point for the criticality safety analyst who uses SCALE/KENO-VI. Complete descriptions are provided in the SCALE/KENO-VI manual. Although the primer is self-contained, it is intended as a companion volume to the SCALE/KENO-VI documentation. (The SCALE manual is provided on the SCALE installation DVD.) The primer provides specific examples of

  4. Energy development in the Southwest: problems of water, fish, and wildlife in the Upper Colorado River Basin. Volume I

    Energy Technology Data Exchange (ETDEWEB)

    Spofford, W.O. Jr.; Parker, A.L.; Kneese, A.V. (eds.)

    1980-01-01

    This two-volume set is based primarily on an RFF forum held in Albuquerque, New Mexico, in October 1976. Most of the papers in the book were presented at this forum. All of them were revised and updated after the forum; some were partly or even wholly rewritten. Some of the papers depend directly on research results reported in others, and therefore major revisions were necessary to integrate these papers. Two new papers were added after the forum was held, as was the appendix and five new discussions. This volume, Vol. I, contains the introductory chapter, 6 other papers (chapters), and an appendix; a separate abstract was prepared for each.

  5. Energy development in the Southwest: problems of water, fish, and wildlife in the Upper Colorado River Basin. Volume II

    Energy Technology Data Exchange (ETDEWEB)

    Spofford, W.O. Jr.; Parker, A.L.; Kneese, A.V. (eds.)

    1980-01-01

    The two-volume set is based primarily on an RFF forum held in Albuquerque, New Mexico, in October 1976. Most of the papers in the book were presented at this forum. All of them were revised and updated after the forum; some were partly or even wholly rewritten. Some of the papers depend directly on research results reported in others, and therefore major revisions were necessary to integrate these papers. Two new papers were added after the forum was held, as was the appendix, and five new discussions. This volume, Vol. II, contains the 10 other papers (chapters) of the set; a separate abstract was prepared for each.

  6. Estimating the Effect of Urban Growth on Annual Runoff Volume Using GIS in the Erbil Sub-Basin of the Kurdistan Region of Iraq

    Directory of Open Access Journals (Sweden)

    Hasan Mohammed Hameed

    2017-02-01

    Full Text Available The growth and spread of impervious surfaces within urbanizing catchment areas pose signiificant threats to the quality of natural and built-up environments. Impervious surfaces prevent water infiltration into the soil, resulting in increased runoff generation. The Erbil Sub-basin was selected because the impervious cover is increasing rapidly and is affecting the hydrological condition of the watershed. The overall aim of this study is to examine the impact of urban growth and other changes in land use on runoff response during the study period of 1984 to 2014. The study describes long-term hydrologic responses within the rapidly developing catchment area of Erbil city, in the Kurdistan Region of Iraq. Data from six rainfall stations in and around the Erbil Sub-basin were used. A Digital Elevation Model (DEM was also used to extract the distribution of the drainage network. Historical levels of urban growth and the corresponding impervious areas, as well as land use/land cover changes were mapped from 1984 to 2014 using a temporal satellite image (Landsat to determine land use/land cover changes. Land use/land cover was combined with a hydrological model (SCS-CN to estimate the volume of runoff from the watershed. The study indicates that the urbanization of the watershed has increased the impervious land cover by 71% for the period from 1984 to 2004 and by 51% from 2004 to 2014. The volume of runoff was 85% higher in 2014 as compared to 1984 due to the increase in the impervious surface area; this is attributed to urban growth. The study also points out that the slope of the watershed in the Erbil sub-basin should be taken into account in surface runoff estimation as the upstream part of the watershed has a high gradient and the land is almost barren with very little vegetation cover; this causes an increase in the velocity of the flow and increases the risk of flooding in Erbil city.

  7. Learning to Be Drier in the Southern Murray-Darling Basin: Setting the Scene for This Research Volume

    Science.gov (United States)

    Golding, Barry; Campbell, Coral

    2009-01-01

    In this article, the authors set the scene for this research volume. They sought to emphasize and broaden their interest and concern about their "Learning to be drier" theme in this edition to the 77 per cent of Australians who live within 50 km of the Australian coast, the majority of whom also live in major cities and urban complexes.…

  8. Enhanced recovery of unconventional gas. Volume II. The program. [Tight gas basins; Devonian shale; coal seams; geopressured aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Kuuskraa, V.A.; Brashear, J.P.; Doscher, T.M.; Elkins, L.E.

    1978-10-01

    This study was conducted to assist public decision-makers in selecting among many choices to obtain new gas supplies by addressing 2 questions: 1) how severe is the need for additional future supplies of natural gas, and what is the economic potential of providing part of future supply through enhanced recovery from unconventional natural gas resources. The study also serves to assist the DOE in designing a cost-effective R and D program to stimulate industry to recover this unconventional gas and to produce it sooner. Tight gas basins, Devonian shale, methane from coal seams, and methane from geopressured aquifers are considered. It is concluded that unconventional sources, already providing about 1 Tcf per year, could provide from 3 to 4 Tcf in 1985 and from 6 to 8 Tcf in 1990 (at $1.75 and $3.00 per Mcf, respectively). However, even with these additions to supply, gas supply is projected to remain below 1977 usage levels. (DLC)

  9. Smolt Monitoring Program, Volume II, Migrational Characteristics of Columbia Basin Salmon and Steelhead Trout, 1986 Annual Report.

    Energy Technology Data Exchange (ETDEWEB)

    Fish Passage Center

    1987-02-01

    Smolt Monitoring Program Annual Report, 1986, Volume I, describes the results of travel time monitoring and other migrational characteristics of yearling and sub-yearling chinook salmon (Oncorhynchus tshawytscha), sockeye salmon (Oncorhynchus nerka), and steelhead trout (Salmo gairdneri). This volume presents the data from Fish Passage Center freeze brands used in the analysis of travel time for Lewiston, Lower Granite, Lower Monumental, Rock Island, McNary, and John Day dams. Summary of data collection procedures and explanation of data listings are presented in conjunction with the mark recapture data. Data for marked fish not presented in this report will be provided upon request. Daily catch statistics (by species), flow, and sample parameters for the smolt monitoring sites, Clearwater, Lewiston, Lower Granite, Lower Monumental, Rock Island, McNary, John Day, and Bonneville also will be provided upon request.

  10. Potential use of geothermal resources in the Snake River Basin: an environmental overview. Volume II. Annotated bibliography

    Energy Technology Data Exchange (ETDEWEB)

    Spencer, S.G.; Russell, B.F.; Sullivan, J.F. (eds.)

    1979-09-01

    This volume is a partially annotated bibliography of reference materials pertaining to the seven KGRA's. The bibliography is divided into sections by program element as follows: terrestrial ecology, aquatic ecology, heritage resources, socioeconomics and demography, geology, geothermal, soils, hydrology and water quality, seismicity, and subsidence. Cross-referencing is available for those references which are applicable to specific KGRA's. (MHR)

  11. Dicaesium tetrachloridodioxidoplutonate(VI

    Directory of Open Access Journals (Sweden)

    Marianne P. Wilkerson

    2008-01-01

    Full Text Available The anion of the title complex, Cs2[PuCl4O2], adopts a pseudo-octahedral geometry (2/m crystallographic site symmetry with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetrachloridodioxidoplutonate(VI anion. Principal bond lengths include Pu—O = 1.752 (3 Å and Pu—Cl = 2.6648 (8 Å.

  12. Wadter Resources Data Ohio: Water year 1994. Volume 2, St. Lawrence River Basin and Statewide Project Data

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS), in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synaptic sites, and partial-record sites; and (4) water-level data for observation wells. Locations of lake- and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures ga through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two to three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.

  13. Integrative method in lithofacies characteristics and 3D velocity volume of the Permian igneous rocks in H area, Tarim Basin

    Institute of Scientific and Technical Information of China (English)

    Yang Haijun; Liu Yongfu; Xie Huiwen; Xu Yongzhong; Sun Qi; Wang Shuangshuang

    2013-01-01

    This paper introduces horizon control,seismic control,logging control and facies control methods through the application of the least squares fitting of logging curves,seismic inversion and facies-controlled techniques.Based on the microgeology and thin section analyses,the lithology,lithofacies and periods of the Permian igneous rocks are described in detail.The seismic inversion and facies-controlled techniques were used to find the distribution characteristics of the igneous rocks and the 3D velocity volume.The least squares fitting of the logging curves overcome the problem that the work area is short of density logging data.Through analysis of thin sections,the lithofacies can be classified into eruption airfall subfacies,eruption pyroclastic flow subfacies and eruption facies.

  14. Monitoring instream turbidity to estimate continuous suspended-sediment loads and yields and clay-water volumes in the upper North Santiam River Basin, Oregon, 1998-2000

    Science.gov (United States)

    Uhrich, Mark A.; Bragg, Heather M.

    2003-01-01

    Three real-time, instream water-quality and turbidity-monitoring sites were established in October 1998 in the upper North Santiam River Basin on the North Santiam River, the Breitenbush River, and Blowout Creek, the main tributary inputs to Detroit Lake, a large, controlled reservoir that extends from river mile 61 to 70. Suspended-sediment samples were collected biweekly to monthly at each station. Rating curves provided estimated suspended-sediment concentration in 30-minute increments from log transformations of the instream turbidity monitoring data. Turbidity was found to be a better surrogate than discharge for estimating suspended-sediment concentration. Daily and annual mean suspended-sediment loads were estimated using the estimated suspended-sediment concentrations and corresponding streamflow data. A laboratory method for estimating persistent (residual) turbidity from separate turbidity samples was developed. Turbidity was measured over time for each sample. Turbidity decay curves were derived as the suspended sediment settled. Each curve was used to estimate a turbidity value for a given settling time. Medium to fine clay particle (size clay particle persistent turbidity for each site. The monitored instream 30-minute turbidity values were converted to a calculated persistent turbidity value that would have resulted after 8.5 hours of settling in the laboratory. Persistent turbidities of 10 NTU and above were tabulated for each site. (Water of 10 NTU and above can interfere with or damage treatment filters and result in intake closures at drinking-water facilities.) A method was developed that used the persistent turbidity experiments, turbidity decay curves, and stream discharge to estimate the volume of water containing suspended clay that entered Detroit Lake from the three main tributaries. 'Suspended-clay water' was defined as water having a value of at least 10 NTU after settling the required 8.5 hours. The suspended-clay concentrations of 10

  15. ViFiLite Project

    Data.gov (United States)

    National Aeronautics and Space Administration — ViFiLite is a wireless infrastructure that utilizes the advantages of a V-band technology in supporting data gathering for structural health monitoring as well as...

  16. The annual mean sketches and climatological variability of the volume and heat transports through the inter-basin passages:A study based on 1 400-year spin up of MOM4p1

    Institute of Scientific and Technical Information of China (English)

    ZHU Yaohua; WEI Zexun; WANG Yonggang; GUAN Yuping; WANG Xinyi

    2014-01-01

    The annual mean volume and heat transport sketches through the inter-basin passages and transoceanic sections have been constructed based on 1 400-year spin up results of the MOM4p1. The spin up starts from a state of rest, driven by the monthly climatological mean force from the NOAA World Ocean Atlas (1994). The volume transport sketch reveals the northward transport throughout the Pacific and southward trans-port at all latitudes in the Atlantic. The annual mean strength of the Pacific-Arctic-Atlantic through flow is 0.63×106 m3/s in the Bering Strait. The majority of the northward volume transport in the southern Pacific turns into the Indonesian through flow (ITF) and joins the Indian Ocean equatorial current, which subse-quently flows out southward from the Mozambique Channel, with its majority superimposed on the Ant-arctic Circumpolar Current (ACC). This anti-cyclonic circulation around Australia has a strength of 11×106 m3/s according to the model-produced result. The atmospheric fresh water transport, known as P-E+R (pre-cipitation minus evaporation plus runoff ), constructs a complement to the horizontal volume transport of the ocean. The annual mean heat transport sketch exhibits a northward heat transport in the Atlantic and poleward heat transport in the global ocean. The surface heat flux acts as a complement to the horizontal heat transport of the ocean. The climatological volume transports describe the most important features through the inter-basin passages and in the associated basins, including:the positive P-E+R in the Arctic substantially strengthening the East Greenland Current in summer;semiannual variability of the volume transport in the Drake Passage and the southern Atlantic-Indian Ocean passage;and annual transport vari-ability of the ITF intensifying in the boreal summer. The climatological heat transports show heat storage in July and heat deficit in January in the Arctic;heat storage in January and heat deficit in July in the

  17. Recueil des legislations linguistiques dans le monde. Tome VI: La Colombie, les Etats-Unis, le Mexique, Porto Rico at les traites internationaux (Record of World Language-Related Legislation. Volume VI: Colombia, the United States, Mexico, Puerto Rico, and International Treaties).

    Science.gov (United States)

    Leclerc, Jacques, Ed.; Maurais, Jacques, Ed.

    The volume is one of a series of six listing language-related legislation around the world. It contains the texts, in French, of laws of Colombia, the United States federal and some state governments (California, Florida, Louisiana, Maine, Massachusetts, Minnesota, and New York), Mexico, and Puerto Rico, and those relating to international…

  18. Cr(VI) occurrence and geochemistry in water from public-supply wells in California

    Science.gov (United States)

    Izbicki, John; Wright, Michael; Seymour, Whitney A.; McCleskey, R. Blaine; Fram, Miranda S.; Belitz, Kenneth; Esser, Bradley K.

    2015-01-01

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment-Priority Basin Project (GAMA-PBP) ranged from less than the study reporting limit of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of wells. Cr(VI) data collected for regulatory purposes overestimated Cr(VI) occurrence compared to spatially-distributed GAMA-PBP data. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and at higher concentrations in alkaline (pH ≥ 8), oxic water; and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that can mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.

  19. Chromium (VI) adsorption on boehmite

    Energy Technology Data Exchange (ETDEWEB)

    Granados-Correa, F. [Instituto Nacional de Investigaciones Nucleares, Apartado Postal 18-1027 Col., Escandon, Delegacion Miguel Hidalgo, C.P. 11801 Mexico, D.F. (Mexico)], E-mail: fgc@nuclear.inin.mx; Jimenez-Becerril, J. [Instituto Nacional de Investigaciones Nucleares, Apartado Postal 18-1027 Col., Escandon, Delegacion Miguel Hidalgo, C.P. 11801 Mexico, D.F. (Mexico)

    2009-03-15

    Boehmite was synthesized and characterized in order to study the adsorption behavior and the removal of Cr(VI) ions from aqueous solutions as a function of contact time, initial pH solution, amount of adsorbent and initial metal ion concentration, using batch technique. Adsorption data of Cr(VI) on the boehmite were analyzed according to Freundlich, Langmuir and Dubinin-Radushkevich (D-R) adsorption models. Thermodynamic parameters for the adsorption system were determinated at 293, 303, 313 and 323 K temperatures. The kinetic values and thermodynamic parameters from the adsorption process show that the Cr(VI) ions adsorption on boehmite is an endothermic and spontaneous process. These results show that the boehmite could be considered as a potential adsorbent for chromium ions in aqueous solutions.

  20. Monitoring and Evaluation of Smolt Migration in the Columbia Basin : Volume II : Evaluation of the 1996 Predictions of the Run-Timing of Wild Migrant Subyearling Chinook in the Snake River Basin using Program RealTime.

    Energy Technology Data Exchange (ETDEWEB)

    Skalski, John R.; Townsend, Richard L.; Yasuda, Dean

    1998-07-01

    This project was initiated in 1991 in response to the Endangered Species Act (ESA) listings in the Snake River Basin of the Columbia River Basin. Primary objectives and management implications of this project include: (1)to address the need for further synthesis of historical tagging and other biological information to improve understanding and identify future research and analysis needs; (2)to assist in the development of improved monitoring capabilities, statistical methodologies and software tools to aid management in optimizing operational and fish passage strategies to maximize the protection and survival of listed threatened and endangered Snake River salmon populations and other listed and nonlisted stocks in the Columbia River Basin; (3)to design better analysis tools for evaluation programs; and (4)to provide statistical support to the Bonneville Power Administration and the Northwest fisheries community.

  1. Monitoring and Evaluation of Smolt Migration in the Columbia River Basin ; Volume 1 ; Evaluation of the 1995 Predictions of the Run-Timing of Wild Migrant Subyearling Chinook in the Snake River Basin Using Program RealTime.

    Energy Technology Data Exchange (ETDEWEB)

    Townsend, Richard L.

    1997-06-01

    This project was initiated in response to the Endangered Species Act (ESA) listings in the Snake River Basin of the Columbia River Basin. Primary objectives and management implications of the project include: (1) to address the need for further synthesis of historical tagging and other biological information to improve understanding and to help identify future research and analysis needs; (2) to assist in the development of improved monitoring capabilities, statistical methodologies and software tools to assist in optimizing operational and fish passage strategies to maximize the protection and survival of listed threatened and endangered Snake River salmon populations and other listed and nonlisted stocks in the Columbia River Basin; and (3) to design better analysis tools for evaluation programs; and (4) to provide statistical support to the Bonneville Power Administration and the Northwest fisheries community.

  2. Natural frequency of regular basins

    Science.gov (United States)

    Tjandra, Sugih S.; Pudjaprasetya, S. R.

    2014-03-01

    Similar to the vibration of a guitar string or an elastic membrane, water waves in an enclosed basin undergo standing oscillatory waves, also known as seiches. The resonant (eigen) periods of seiches are determined by water depth and geometry of the basin. For regular basins, explicit formulas are available. Resonance occurs when the dominant frequency of external force matches the eigen frequency of the basin. In this paper, we implement the conservative finite volume scheme to 2D shallow water equation to simulate resonance in closed basins. Further, we would like to use this scheme and utilizing energy spectra of the recorded signal to extract resonant periods of arbitrary basins. But here we first test the procedure for getting resonant periods of a square closed basin. The numerical resonant periods that we obtain are comparable with those from analytical formulas.

  3. Vi har brug for skammere

    DEFF Research Database (Denmark)

    Holm, Claus

    2007-01-01

    Skammen er en væsentlig ingrediens i opdragelsen af børn, men det overser vi, for skam er et fyord i den pædagogiske verden. Interview med børnebogsforfatteren Lene Kaaberbøl om, hvorfor skam gør os menneskelige....

  4. VI Tallinna arhitektuuritriennaal / Leonhard Lapin

    Index Scriptorium Estoniae

    Lapin, Leonhard, 1947-

    2005-01-01

    15.-17. IX Tallinnas Niguliste kirikus toimuval VI Tallinna arhitektuuritriennaalil esinevad inglise arhitektuurikriitik Peter Davey, šveitsi arhitekt Peter Zumthor, soome arhitekt Juha Leviskä, eesti arhitekt Vilen Künnapu, eesti kunstiajaloolane Juhan Maiste jt. Külastatakse KUMU, tutvutab autor Pekka Vapaavuori

  5. Design and Analysis of Salmonid Tagging Studies in the Columbia Basin, Volume VI; Assessment of Season-Wide Survival of Snake River Yearling Chinook Salmon, 1994-1996 Technical Report.

    Energy Technology Data Exchange (ETDEWEB)

    Skalski, John R.; Perez-Comas, Jose A. (University of Washington, School of Fisheries, Fisheries Research Institute, Seattle, WA); Smith, Steven G. (National Marine Fisheries Service, Northwest Fisheries Science Center, Seattle, WA)

    1998-06-01

    Project 8910700, Epidemiological Survival Methods, was developed to provide statistical guidance on design and analysis of PIT-tag (Passive Integrated Transponder) survival studies to the Northwest fisheries community.

  6. Hvad skal vi med et naturhistorisk museum?

    DEFF Research Database (Denmark)

    Kjærgaard, Peter C.

    2016-01-01

    I Danmark har vi nationale museer for kunsten, kulturen og naturen. Vi er i fuld gang med at lave et nyt, stort supermuseum for naturhistorien. Hvad skal vi egentlig med det? Efter et år på posten som direktør for Statens Naturhistoriske Museum gør Peter C. Kjærgaard status med en personlig...

  7. Vi serology in screening of typhoid carriers: improved specificity by detection of Vi antibodies by counterimmunoelectrophoresis.

    OpenAIRE

    Chau, P. Y.; Tsang, R S

    1982-01-01

    A purified soluble Vi antigen was used in counterimmunoelectrophoresis (CIE), passive haemagglutination (HA) and solid phase radio-immunoassay (SPRIA) for detection of serum Vi antibody. Serum Vi antibody was detected in 13 of 14 chronic typhoid carriers by both CIE and HA. SPRIA studies showed that Vi antibodies in sera of these carriers were mainly of the IgG class. Successful treatment with amoxycillin in one carrier, who initially showed a positive Vi test, resulted in a reversion in 6 mo...

  8. Environmental Status of the Lake Michigan Region Volume 11. Natural Areas of the Lake Michigan Drainage Basin and Endangered or Threatened Plant and Animal Species

    Energy Technology Data Exchange (ETDEWEB)

    Stearns, Forest [Argonne National Lab. (ANL), Argonne, IL (United States); Lindsley, Diane [Argonne National Lab. (ANL), Argonne, IL (United States)

    1977-09-01

    The accelerating encroachment of human activity on the natural landscape has made many citizens appreciate the need to save representative biotic communities before urbanization and technologically induced change eliminate such communities. Active programs in natural-area preservation a.re now in progress in the four basin states; these programs have strong public support and legislative mandate. Local, state, and federal agencies and private individuals have taken an active interest in protecting select areas as samples of the biotic communities and natural features of the Basin. Most natural areas described in this report have been dedicated or reserved in some fashion. Other areas are being added by the basin states each year. The maintenance of natural communities is closely linked to the preservation of endangered and threatened species of plants and animals which would cease to survive as isolated populations. Under federal regulations, certain plants and animals are listed as endange~ ed or threatened in the Basin. As individual state lists are prepared and investigations proceed, it is probable that many more threatened species will be found.

  9. Environmental status of the Lake Michigan region. Volume II. Natural areas of the Lake Michigan drainage basin and endangered or threatened plant and animal species

    Energy Technology Data Exchange (ETDEWEB)

    Stearns, F.; Lindsley, D.

    1977-09-01

    The accelerating encroachment of human activity on the natural landscape has made many citizens appreciate the need to save representative biotic communities before urbanization and technologically induced change eliminate such communities. Active programs in natural-area preservation are now in progress in the four basin states; these programs have strong public support and legislative mandate. Local, state, and federal agencies and private individuals have taken an active interest in protecting select areas as samples of the biotic communities and natural features of the Basin. Most natural areas described in this report have been dedicated or reserved in some fashion. Other areas are being added by the basin states each year. The maintenance of natural communities is closely linked to the preservation of endangered and threatened species of plants and animals which would cease to survive as isolated populations. Under federal regulations, certain plants and animals are listed as endangered or threatened in the Basin. As individual state lists are prepared and investigations proceed, it is probable that many more threatened species will be found.

  10. Riparian Cottonwood Ecosystems and Regulated Flows in Kootenai and Yakima Sub-Basins : Volume I Kootenai River (Overview, Report and Appendices).

    Energy Technology Data Exchange (ETDEWEB)

    Jamieson, Bob; Braatne, Jeffrey H.

    2001-10-01

    Riparian vegetation and especially cottonwood and willow plant communities are dependent on normative flows and especially, spring freshette, to provide conditions for recruitment. These plant communities therefore share much in common with a range of fish species that require natural flow conditions to stimulate reproduction. We applied tools and techniques developed in other areas to assess riparian vegetation in two very different sub-basins within the Columbia Basin. Our objectives were to: Document the historic impact of human activity on alluvial floodplain areas in both sub-basins; Provide an analysis of the impacts of flow regulation on riparian vegetation in two systems with very different flow regulation systems; Demonstrate that altered spring flows will, in fact, result in recruitment to cottonwood stands, given other land uses impacts on each river and the limitations imposed by other flow requirements; and Assess the applicability of remote sensing tools for documenting the distribution and health of cottonwood stands and riparian vegetation that can be used in other sub-basins.

  11. Vi mangler endnu et panel

    DEFF Research Database (Denmark)

    Ritter, Thomas

    2016-01-01

    Vi mangler højtuddannede værdiskabere, som transformerer gode idéer og teknologier til indtjening og velstand. Først i mødet med markedet afgøres fremtiden. Troels Lund Poulsen bør nedsætte et kommercialiseringspanel, der byder ind med løsninger, hvordan Danmark bliver et land ikke kun med gode i...

  12. Louisiana Coastal Area, Louisiana. Freshwater Diversion to Barataria and Breton Sound Basins. Feasibility Study. Volume 1. Draft Main Report. Draft Environmental Impact Statement.

    Science.gov (United States)

    1984-09-01

    nickel, selenium , zinc, nitrogen, phosphorus, hydrocarbons, and fecal coliform bacteria in Barataria and Breton Sound Basins, primarly in the upper...Loutiian,1 is stable and has the potential to increase; however, .subnormal clutch i ;e and poor egg hatchability are inhibiting population growth. There Is...proposed EIS-132 sites would likely result in increased mean concentrations of cadmium, mercury, nickel, selenium , zinc, nitrogen, phosphorus, and

  13. Analytical results for 35 mine-waste tailings cores and six bed-sediment samples, and an estimate of the volume of contaminated material at Buckeye meadow on upper Basin Creek, northern Jefferson County, Montana

    Science.gov (United States)

    Fey, D.L.; Church, S.E.; Finney, C.J.

    1999-01-01

    Metal-mining related wastes in the Boulder River basin study area in northern Jefferson County, Montana have been implicated in their detrimental effects on water quality with regard to acidgeneration and toxic-metal solubilization. Flotation-mill tailings in the meadow below the Buckeye mine, hereafter referred to as the Buckeye mill-tailings site, have been identified as significant contributors to water quality degradation of Basin Creek, Montana. Basin Creek is one of three tributaries to the Boulder River in the study area; bed sediments and waters draining from the Buckeye mine have also been implicated. Geochemical analysis of 35 tailings cores and six bed-sediment samples was undertaken to determine the concentrations of Ag, As, Cd, Cu, Pb,and Zn present in these materials. These elements are environmentally significant, in that they can be toxic to fish and/or the invertebrate organisms that constitute their food. A suite of one-inch cores of dispersed flotation-mill tailings and underlying premining material was taken from a large, flat area north of Basin Creek near the site of the Buckeye mine. Thirty-five core samples were taken and divided into 204 subsamples. The samples were analyzed by ICP-AES (inductively coupled plasma-atomic emission spectroscopy) using a mixed-acid digestion. Results of the core analyses show that the elements listed above are present at moderate to very high concentrations (arsenic to 63,000 ppm, silver to 290 ppm, cadmium to 370 ppm, copper to 4,800 ppm, lead to 93,000 ppm, and zinc to 23,000 ppm). Volume calculations indicate that an estimated 8,400 metric tons of contaminated material are present at the site. Six bed-sediment samples were also subjected to the mixed-acid total digestion, and a warm (50oC) 2M HCl-1% H2O2 leach and analyzed by ICP-AES. Results indicate that bed sediments of Basin Creek are only slightly impacted by past mining above the Buckeye-Enterprise complex, moderately impacted at the upper (eastern

  14. Removal of aqueous chromate [Cr(VI)] through photocatalysis by using TiO2-coated silica granules.

    Science.gov (United States)

    Saeki, Kazutoshi; Kadono, Mayumi; Nabeshima, Akiko

    2010-01-01

    The aim of this study was to determine the optimal conditions for the treatment of chromate [Cr(VI)]- contaminated water by UV photocatalysis using synthesized TiO(2)-coated silica granules (phi 1.7-4.0 mm) containing 12.4% of TiO(2) in a batch method. The effect of the volume of the solution on Cr(VI) removal was investigated in the photocatalysis process by using 10 g of TiO(2)-coated silica granules in water samples with a constant initial Cr(VI) concentration of 5 mg L(-1). In a 10-mL solution, Cr(VI) concentrations were observed to decrease below the detection limit (photocatalysis process to remove Cr(VI) using 10 g of TiO(2)-coated granules did not fluctuate with the solution volume for samples with a constant initial Cr(VI) concentration. The lower the initial pH of the solution, the greater was the amount of Cr(VI) removed from the solution. The addition of chloride ions to the solutions accelerated the removal of Cr(VI) by UV photocatalysis. Ten grams of TiO(2)-coated silica granules were repeatedly used to the 300-min treatment of the Cr(VI) solution (10 mL, 6 mg L(-1)) till seven cycles. After four cycles of UV photocatalysis, Cr(VI) was completely removed from all the solutions. After the fifth cycle, the Cr(VI) removal capacity of the UV photocatalysis process decreased with the repeated use of the catalyst.

  15. VI. Fünfter Aufzug

    OpenAIRE

    2014-01-01

    1. Erstes Bild (VI) a) Einleitung Demaenetus und Argirippus treten mit Philaenium aus dem Haus und beginnen ein Gelage auf offener Straße (nicht im Innern, durch eine offene Tür für den Zuschauer sichtbar: so Weise, Ussing, Kunst 1919, 156, Webster 1970, 237): siehe 941. Der frivole senex besteht auf Zärtlichkeiten der Hetäre, verlangt sogar von seinem Sohn, sich als heiter gestimmter Zechkumpane zu gerieren. Dieser erkennt Demaenetus’ Rechte an. Der Dialog pointiert nicht nur Demaenetus’ Wan...

  16. 29 CFR 1915.1026 - Chromium (VI).

    Science.gov (United States)

    2010-07-01

    ... system dysfunction; any history of asthma, dermatitis, skin ulceration, or nasal septum perforation; and... is present or is likely to be present from skin or eye contact with chromium (VI), the employer shall... cleaned in a manner that minimizes skin or eye contact with chromium (VI) and effectively prevents...

  17. 29 CFR 1926.1126 - Chromium (VI).

    Science.gov (United States)

    2010-07-01

    ... system dysfunction; any history of asthma, dermatitis, skin ulceration, or nasal septum perforation; and... is present or is likely to be present from skin or eye contact with chromium (VI), the employer shall... cleaned in a manner that minimizes skin or eye contact with chromium (VI) and effectively prevents...

  18. Precision engineering center. 1988 Annual report, Volume VI

    Energy Technology Data Exchange (ETDEWEB)

    Dow, T. [ed.; Fornaro, R.; Keltie, R.; Paesler, M. [and others

    1988-12-01

    To reverse the downward trend in the balance of trade, American companies must concentrate on increasing research into new products, boosting productivity, and improving manufacturing processes. The Precision Engineering Center at North Carolina State University is a multidisciplinary research and graduate education program dedicated to providing the new technology necessary to respond to this challenge. One extremely demanding manufacturing area is the fabrication and assembly of optical systems. These systems are at the heart of such consumer products as cameras, lenses, copy machines, laser bar-code scanners, VCRs, and compact audio discs - products that the Japanese and other East Asian countries are building dominance. A second critical area is the fabrication of VLSI and ULSI circuits. The tolerances required to produce the next generation of components for such systems have created the need for new approaches - approaches that could either make or break America`s competitive position. This report contains individual reports on research projects grouped into three broad areas: measurement and actuation; real-time control; precision fabrication. Separate abstracts for these articles have been indexed into the energy database.

  19. World Energy Data System (WENDS). Volume VI. International agreement profiles

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-06-01

    The World Energy Data System contains organized data on those countries and international organizations that may have critical impact on world energy. The international agreement profiles in WENDS are all energy-related and are organized by energy technology. These are: coal; conservation; fusion; geothermal; nuclear fission; oil, gas, and shale; solar, wind, and ocean thermal; and other (cooperation in electrical power equipment acquisition, energy, energy research, etc.). The agreement profiles are accessible by energy technology and alphabetically by country.

  20. Wilderness Study Report : Volume VI : Kenai National Moose Range

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — In order to conform to the Wilderness Act of 1964, a study was conducted by the Bureau of Sport Fisheries and Wildlife personnel to ascertain which of the Kenai...

  1. Census Report: Volume VI, 1987 through 1992. Sanitized Version.

    Science.gov (United States)

    2007-11-02

    0599 GUERNSEY, JEFFREY S 0754 GUERRA , PAUL 0599 GUIDA, RICHARD A 0599 GUITERREZ, EDUARDO 0599 GUNDERSON, ALLAN W 0599 (TTTJ’M"N ,Tr’Frr y L - 0638...PATTERSON, JOHN E 0837 PATTON, TERRY R 0903 PAYNE, DEBORAH N 0972 PAYNE, WILLIAM R 0978* PAZ , EDWARD L 0978* PEACE, BOBBY J 0599 PEAKE, DARRELL D 0975

  2. Semiconductors. Subvol. A. New data and updates for I-VII, III-V, III-VI and IV-VI compounds

    Energy Technology Data Exchange (ETDEWEB)

    Roessler, U (ed.) [Regensburg Univ. (Germany). Inst. fuer Theoretische Physik; Dietl, T.; Dobrowolski, W.; Story, T. [Polish Academy of Sciences, Warszawa (Poland). Lab. for Cryogenic and Spintronic Research; Fernandes da Silva, E.C. [Universidade de Sao Paulo, SP (Brazil). Lab. de Novos Materiais Semiconductores; Hoenerlage, B. [IPCMS/GONLO, 67 - Strasbourg (France); Meyer, B.K. [Giessen Univ. (Germany). 1. Physikalisches Inst.

    2008-07-01

    The Landolt-Boernstein subvolumes III/44A and III/44B update the existing 8 volumes III/41 about Semiconductors and contain new Data and Updates for I-VII, III-V, III-VI, IV, VI and II-VI Compounds. The text, tables figures and references are provided in self-contained document files, each one dedicated to a substance and property. The first subvolume III/44A contains a ''Systematics of Semiconductor Properties'', which should help the non-specialist user to understand the meaning of the material parameters. Hyperlinked lists of substances and properties lead directly to the documents and make the electronic version an easy-to-use source of semiconductor data. In the new updates III/44A and III/44B, links to existing material in III/41 or to related documents for a specific substance are also included. (orig.)

  3. Econophys-Kolkata VI Conference

    CERN Document Server

    Chakrabarti, Bikas; Chakraborti, Anirban; Ghosh, Asim

    2013-01-01

    The primary goal of the book is to present the ideas and research findings of active researchers such as physicists, economists, mathematicians and financial engineers working in the field of “Econophysics,” who have undertaken the task of modeling and analyzing systemic risk, network dynamics and other topics. Of primary interest in these studies is the aspect of systemic risk, which has long been identified as a potential scenario in which financial institutions trigger a dangerous contagion mechanism, spreading from the financial economy to the real economy. This type of risk, long confined to the monetary market, has spread considerably in the recent past, culminating in the subprime crisis of 2008. As such, understanding and controlling systemic risk has become an extremely important societal and economic challenge. The Econophys-Kolkata VI conference proceedings are dedicated to addressing a number of key issues involved. Several leading researchers in these fields report on their recent work and al...

  4. Anaerobic bio-removal of uranium (VI) and chromium (VI): Comparison of microbial community structure

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Monica [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Faleiro, Maria Leonor [IBB - Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Chaves, Sandra; Tenreiro, Rogerio [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biodiversidade, Genomica Integrativa e Funcional (BioFIG), Campus de FCUL, Campo Grande 1749-016 Lisboa (Portugal); Santos, Erika [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, Maria Clara, E-mail: mcorada@ualg.pt [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2010-04-15

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L{sup -1} U(VI) and 99% of 13 mg L{sup -1} Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  5. Anaerobic bio-removal of uranium (VI) and chromium (VI): comparison of microbial community structure.

    Science.gov (United States)

    Martins, Mónica; Faleiro, Maria Leonor; Chaves, Sandra; Tenreiro, Rogério; Santos, Erika; Costa, Maria Clara

    2010-04-15

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L(-1) U(VI) and 99% of 13 mg L(-1) Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  6. Method of water purification from chromium (VI with the presence of microorganisms

    Directory of Open Access Journals (Sweden)

    Олена Георгіївна Горшкова

    2015-09-01

    Full Text Available The high efficiency of water purification from chromium (VI by the polyfunctional bacterial suspension consisted of the association of non-pathogenic bacteria strains of the genus Pseudomonas: P. fluorescens ONU328, P. maltophilia ONU329, P. cepacia ONU327 in a volume ratio of 1:1:1 is experimentally confirmed. The method allows in the presence of hydrogen peroxide and calcium chloride to purify contaminated water from chromium (VI with concentration up to 70 mg/dm3 to values of concentration smaller than the maximum allowable concentration

  7. ViSIT: Visitor Survey Information Tool

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — ViSIT is an interactive web tool created by USGS to visualize the data collected as part of the National Wildlife Refuge Visitor Survey. The national survey was...

  8. 77 FR 52116 - Title VI; Final Circular

    Science.gov (United States)

    2012-08-28

    .... Department of Justice advised Federal agencies in late 2001, ``although Sandoval foreclosed private judicial.... Recipients will be required to submit, with the Title VI Program, a copy of the Board resolution,...

  9. Rheology of water ices V and VI

    Science.gov (United States)

    Durham, W.B.; Stern, L.A.; Kirby, S.H.

    1996-01-01

    We have measured the mechanical strength (??) of pure water ices V and VI under steady state deformation conditions. Constant displacement rate compressional tests were conducted in a gas apparatus at confining pressures from 400 250 K. Ices V and VI are thus Theologically distinct but by coincidence have approximately the same strength under the conditions chosen for these experiments. To avoid misidentification, these tests are therefore accompanied by careful observations of the occurrences and characteristics of phase changes. One sample each of ice V and VI was quenched at pressure to metastably retain the high-pressure phase and the acquired deformation microstructures; X ray diffraction analysis of these samples confirmed the phase identification. Surface replicas of the deformed and quenched samples suggest that ice V probably deforms largely by dislocation creep, while ice VI deforms by a more complicated process involving substantial grain size reduction through recrystallization.

  10. Design and Analysis of Salmonid Tagging Studies in the Columbia Basin, Volume XVI; Alternative Designs for Future Adult PIT-Tag Detection Studies, 2000 Technical Report.

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Comas, Jose A.; Skalski, John R. (University of Washington, School of Fisheries, Seattle, WA)

    2000-09-25

    In the advent of the installation of a PIT-tag interrogation system in the Cascades Island fish ladder at Bonneville Dam (BON), and other CRB dams, this overview describes in general terms what can and cannot be estimated under seven different scenarios of adult PIT-tag detection capabilities in the CRB. Moreover, this overview attempted to identify minimal adult PIT-tag detection configurations required by the ten threatened Columbia River Basin (CRB) chinook and steelhead ESUs. A minimal adult PIT-tag detection configuration will require the installation of adult PIT-tag detection facilities at Bonneville Dam and another dam above BON. Thus, the Snake River spring/summer and fall chinook salmon, and the Snake River steelhead will require a minimum of three dams with adult PIT-tag detection capabilities to guarantee estimates of ''ocean survival'' and at least of one independent, in-river returning adult survival (e.g., adult PIT-tag detection facilities at BON and LGR dams and at any other intermediary dam such as IHR). The Upper Columbia River spring chinook salmon and steelhead will also require a minimum of three dams with adult PIT-tag detection capabilities: BON and two other dams on the BON-WEL reach. The current CRB dam system configuration and BPA's and COE's commitment to install adult PIT-tag detectors only in major CRB projects will not allow the estimation of an ''ocean survival'' and of any in-river adult survival for the Lower Columbia River chinook salmon and steelhead. The Middle Columbia River steelhead ESU will require a minimum of two dams with adult PIT-tag detection capabilities: BON and another upstream dam on the BON-McN reach. Finally, in spite of their importance in terms of releases, PIT-tag survival studies for the Upper Willamette chinook and Upper Willamette steelhead ESUs cannot be perform with the current CRB dam system configuration and PIT-tag detection capabilities.

  11. 鄂尔多斯盆地致密油水平井体积压裂优化设计%Optimization design for volume fracturing of horizontal wells in tight oil reservoir of Ordos Basin

    Institute of Scientific and Technical Information of China (English)

    白晓虎; 齐银; 陆红军; 段鹏辉; 顾燕凌; 吴甫让

    2015-01-01

    鄂尔多斯盆地长7致密油储层致密、油藏低压。储层天然微裂缝发育程度和岩石脆性评价表明,盆地致密油储层物性对水平井分段体积压裂具有良好的适应性。以提高水平井多段压裂井网形式和布缝的匹配性为目的,优化了与注采井网相适配的施工参数,结果表明,实现体积压裂的排量为4~8 m3/min,单段砂量40~80 m3,入地液量300~700 m3,并形成了“低黏液体造缝、高黏液体携砂、组合粒径支撑剂、不同排量注入”的混合压裂设计模式。矿场井下微地震监测对比了体积压裂与常规压裂对裂缝扩展形态的影响,结果显示致密储层采用体积压裂的改造体积和复杂指数是常规压裂的2倍左右,且与井网适配性良好。通过开展致密油开发矿场先导性试验,水平井单井初期产量达到8~10 t/d,第1年累计产油量达2000 t左右,且无裂缝性见水井,证明对于鄂尔多斯盆地的致密油开发,采用水平井五点井网+混合水体积压裂可以获得较高的单井产量和良好的开发效益。该项技术对其他油田的非常规储层开发有一定的借鉴意义。%Chang 7 tight oil reservoir of Ordos Basin features tight and low-pressure reservoir. It is shown from natural microfracture development degree and rock brittleness assessment of the reservoir that, properties of tight oil reservoir of the basin are highly adaptable to segmented volume fracturing of horizontal wells. The construction parameters which match with lfood pattern are optimized for the purpose of improving compatibility between multi-segment fracturing pattern form and fracture distribution of horizontal wells, and results indicate that volume fracturing is realized by displacement between 4 m3/min to 8m3/min, single-segment sand amount between 40 m3 to 80 m3, and buried liquid amount between 300 m3 to 700 m3. The mixed fracturing design mode of fracture formation by low

  12. Derfor elsker og hader vi positiv psykologi

    DEFF Research Database (Denmark)

    Mehlsen, Camilla

    2010-01-01

    Hvorfor er positiv psykologi så populært? Er positiv psykologi ved at blive en religion? Asterisk har mødt tre fremtrædende forskere, der forklarer, hvorfor vi elsker og hader positiv psykolog.......Hvorfor er positiv psykologi så populært? Er positiv psykologi ved at blive en religion? Asterisk har mødt tre fremtrædende forskere, der forklarer, hvorfor vi elsker og hader positiv psykolog....

  13. SaVi: satellite constellation visualization

    CERN Document Server

    Wood, Lloyd

    2012-01-01

    SaVi, a program for visualizing satellite orbits, movement, and coverage, is maintained at the University of Surrey. This tool has been used for research in academic papers, and by industry companies designing and intending to deploy satellite constellations. It has also proven useful for demonstrating aspects of satellite constellations and their geometry, coverage and movement for educational and teaching purposes. SaVi is introduced and described briefly here.

  14. Screen-printed sensor for batch and flow injection potentiometric chromium(VI) monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Moreno, Raul A.; Gismera, M.J.; Sevilla, M.T.; Procopio, Jesus R. [Facultad de Ciencias, Universidad Autonoma de Madrid, Departamento de Quimica Analitica y Analisis Instrumental, Madrid (Spain)

    2010-05-15

    A disposable screen-printed electrode was designed and evaluated for direct detection of chromium(VI) in batch and flow analysis. The carbon screen-printed electrode was modified with a graphite-epoxy composite. The optimal graphite-epoxy matrix contains 37.5% graphite powder, 12.5% diphenylcarbohydrazide, a selective compound for chromium(VI), and 50% epoxy resin. The principal analytical parameters of the potentiometric response in batch and flow analysis were optimized and calculated. The screen-printed sensor exhibits a response time of 20 {+-} 1 s. In flow analysis, the analytical frequency of sampling is 70 injections per hour using 0.1 M NaNO{sub 3} solution at pH 3 as the carrier, a flow rate of 2.5 mL.min{sup -1}, and an injection sample volume of 0.50 mL. The sensor shows potentiometric responses that are very selective for chromium(VI) ions and optimal detection limits in both static mode (2.1 x 10{sup -7} M) and online analysis (9.4 x 10{sup -7} M). The disposable potentiometric sensor was employed to determine toxicity levels of chromium(VI) in mineral, tap, and river waters by flow-injection potentiometry and batch potentiometry. Chromium(VI) determination was also carried out with successful results in leachates from municipal solid waste landfills. (orig.)

  15. Characterization of Amoeba proteus myosin VI immunoanalog.

    Science.gov (United States)

    Dominik, Magdalena; Kłopocka, Wanda; Pomorski, Paweł; Kocik, Elzbieta; Redowicz, Maria Jolanta

    2005-07-01

    Amoeba proteus, the highly motile free-living unicellular organism, has been widely used as a model to study cell motility. However, molecular mechanisms underlying its unique locomotion and intracellular actin-based-only trafficking remain poorly understood. A search for myosin motors responsible for vesicular transport in these giant cells resulted in detection of 130-kDa protein interacting with several polyclonal antibodies against different tail regions of human and chicken myosin VI. This protein was binding to actin in the ATP-dependent manner, and immunoprecipitated with anti-myosin VI antibodies. In order to characterize its possible functions in vivo, its cellular distribution and colocalization with actin filaments and dynamin II during migration and pinocytosis were examined. In migrating amoebae, myosin VI immunoanalog localized to vesicular structures, particularly within the perinuclear and sub-plasma membrane areas, and colocalized with dynamin II immunoanalog and actin filaments. The colocalization was even more evident in pinocytotic cells as proteins concentrated within pinocytotic pseudopodia. Moreover, dynamin II and myosin VI immunoanalogs cosedimented with actin filaments, and were found on the same isolated vesicles. Blocking endogenous myosin VI immunoanalog with anti-myosin VI antibodies inhibited the rate of pseudopodia protrusion (about 19% decrease) and uroidal retraction (about 28% decrease) but did not affect cell morphology and the manner of cell migration. Treatment with anti-human dynamin II antibodies led to changes in directionality of amebae migration and affected the rate of only uroidal translocation (about 30% inhibition). These results indicate that myosin VI immunoanalog is expressed in protist Amoeba proteus and may be involved in vesicle translocation and cell locomotion.

  16. Duration of Vi antibodies in participants vaccinated with Typhim Vi (Typhoid Vi polysaccharide vaccine) in an area not endemic for typhoid fever.

    Science.gov (United States)

    Froeschle, James E; Decker, Michael D

    2010-02-10

    After a single injection of Typhim Vi (typhoid Vi polysaccharide vaccine), serum antibody concentrations were monitored for 3 years in 37 adults who resided where typhoid fever was not endemic. Anti-Vi antibody concentrations declined progressively during the study, to levels that support the current US recommendation for revaccination every 2 years.

  17. Singular Instantons and Painlevé VI

    Science.gov (United States)

    Muñiz Manasliski, Richard

    2016-06-01

    We consider a two parameter family of instantons, which is studied in [Sadun L., Comm. Math. Phys. 163 (1994), 257-291], invariant under the irreducible action of SU_2 on S^4, but which are not globally defined. We will see that these instantons produce solutions to a one parameter family of Painlevé VI equations (P_VI}) and we will give an explicit expression of the map between instantons and solutions to P_{VI}. The solutions are algebraic only for that values of the parameters which correspond to the instantons that can be extended to all of S^4. This work is a generalization of [Muñiz Manasliski R., Contemp. Math., Vol. 434, Amer. Math. Soc., Providence, RI, 2007, 215-222] and [Muñiz Manasliski R., J. Geom. Phys. 59 (2009), 1036-1047, arXiv:1602.07221], where instantons without singularities are studied.

  18. Vi er blevet gode til at budgettere(!?!)

    DEFF Research Database (Denmark)

    Kreiner, Kristian

    2015-01-01

    På det seneste har rektor haft anledning til at fortælle os, at vi på CBS er blevet gode til at budgettere. Men hvad det vil sige at være god til at budgettere? Og hvad bliver disse nye færdigheder så brugt til?......På det seneste har rektor haft anledning til at fortælle os, at vi på CBS er blevet gode til at budgettere. Men hvad det vil sige at være god til at budgettere? Og hvad bliver disse nye færdigheder så brugt til?...

  19. Seroprevalence of anti Vi antibodies and immunogenicity of Typhim Vi vaccine in children.

    Science.gov (United States)

    Gupta, Divya; Faridi, M M A; Aggarwal, Anju; Kaur, Iqbal

    2008-01-01

    This prospective study was carried out on 250 children between 6 months to 5 years of age to determine seroprevalence of anti Vi antibodies and to measure seroresponse and percent seroconversion to TyphimVi polysaccharide vaccine in children 2-5 years of age. Fifty children each were enrolled between 6 to 12 months of age (Group A), between 1- 2 years of age(Group B), between 2-3 years of age (Group C), between 3-4 years of age (Group D) and between 4-5 years of age (Group E). Anti-Vi antibody baseline titres were determined in all children. Children in Groups C to E were vaccinated with Typhim Vi vaccine. Baseline and postvaccination antibody titres were determined by ELISA. Test sera which had antibody levels >1 microg/ml were scored as seropositive. Of 250 children, 3 had base line anti-Vi antibodies >1 microg/ml. Following immunization overall seroconversion rate was 77.5% with 65.3%, 78.2% and 88% children showing seroconversion in Groups C, D and E respectively. Seroconversion was significantly more in Group E children compared to Group C (p=0.0148). There were no significant adverse reactions following vaccination. The study highlights very low prevalence of baseline anti Vi antibodies in children between 6 months and less than 5 years of age and shows high immunogenicity and safety of Typhim Vi polysaccharide vaccine in children 2-5 years of age.

  20. Design and Analysis of Salmonid Tagging Studies in the Columbia Basin, Volume I; Assessment of Temporal Trends in Daily Survival Estimates of Spring Chinook, 1994-1996 Technical Report.

    Energy Technology Data Exchange (ETDEWEB)

    Skalski, John R.; Perez-Comas, Jose A.; Lady, Jim

    1998-10-01

    This report if the first of a series of reports produced by the University of Washington for the Bonneville Power Administration under the title ''The Design and Analysis of Salmonid Tagging Studies in the Columbia Basin'', with the purpose of offering new and alternative methods to analyzing data from tagging studies in the Columbia Basin.

  1. Breckinridge Project, initial effort. Report VI. Project Management Plan

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-01

    Report VI presents a comprehensive plan for the management of the Breckinridge Project. For the purpose of this report, the project work is divided into five major project phases: Development, Engineering, Procurement, Construction, and Operations. The results of the Development Phase (Initial Effort) of the project are discussed in Section 1.0. This phase of the project was performed under a Cooperative Agreement with US Department of Energy and has produced 43 volumes of documentation. Fifteen volumes contain information of proprietary nature for patented processes and are therefore classified as Limited Access; however, twenty-eight volumes are not classified and are suitable for public dissemination. This Project Management Plan is a volume of the unclassified documentation. The other twenty-seven volumes contain comprehensive data on technical, financial, and environmental aspects of the project. Each of the four remaining project phases is presented starting with the extensive planning that will be performed and continuing through to the execution and completion of each phase. The major roles of the Operator, Ashland Synthetic Fuels, Inc. (ASFI), and the Managing Contractor are defined. Although a contract has not yet been executed with a Managing Contractor, the procedures, controls, organization and management philosophy of Bechtel Petroleum, Inc., are presented in this report as being representative of those used by contractors in the business of performing the engineering, procurement, and construction of projects of this size and complexity. The organizational structures of the Operator and the Managing Contractor are described, with designation of key project team personnel by job description and organization charts. Provisions for cost, schedule, and material control are described.

  2. Assessing Potential Conservation and Restoration Areas of Freshwater Fish Fauna in the Indian River Basins

    Science.gov (United States)

    Bhatt, Jay P.; Manish, Kumar; Mehta, Rajender; Pandit, Maharaj K.

    2016-05-01

    Conservation efforts globally are skewed toward terrestrial ecosystems. To date, conservation of aquatic ecosystems, in particular fish fauna, is largely neglected. We provide a country-wide assessment of Indian river ecosystems in order to identify and prioritize areas for protection and restoration of freshwater fish fauna. Using various biodiversity and anthropogenic attributes, coupled with tools of ecological modeling, we delineated areas for fish fauna conservation and restoration in the 20 major river basins of India. To do this, we used prioritization analyses and reserve selection algorithms to derive conservation value index (CVI) and vulnerability index (VI) of the river basins. CVI was estimated using endemicity, rarity, conservation value, and taxonomic singularity, while VI was estimated using a disturbance index derived from percent geographic area of the basin under human settlements, human population density, predominant land use, and total number of exotic fish species in each basin. The two indices, CVI and VI, were converted into geo-referenced maps, and each map was super-imposed onto species richness and forest cover maps, respectively. After superimposition, areas with high CVI and low VI shade intensities were delineated for conservation, while areas with high CVI and high VI shade intensities were demarcated for restoration. In view of the importance of freshwater fish for human livelihoods and consumption, and ecosystems of India's rivers, we call for urgent attention to the conservation of their fish fauna along with restoration of their degraded habitats.

  3. Hvem er vi? Hvem er de?

    DEFF Research Database (Denmark)

    Kryger, Niels

    2016-01-01

    Kommentaren tager afsæt i initiativer i de pædagogiske faglige foreninger i Europa EERA) og i Norden (NERA) og argumenterer for at det er forpligtelse for os som nordiske og europæiske pædagogiske forskere at gå op imod de stadigt mere ekskluderende vi-konstruktioner, som er blevet formuleret i f...

  4. O vi in the local interstellar medium

    CERN Document Server

    Barstow, M A; Welsh, B Y; Lallement, R; Preval, J K Barstow A E Forbes And S

    2010-01-01

    We report the results of a search for O VI absorption in the spectra of 80 hot DA white dwarfs observed by the FUSE satellite. We have carried out a detailed analysis of the radial velocities of interstellar and (where present) stellar absorption lines for the entire sample of stars. In approximately 35% of cases (where photospheric material is detected), the velocity differences between the interstellar and photospheric components were beneath the resolution of the FUSE spectrographs. Therefore, in 65% of these stars the interstellar and photospheric contributions could be separated and the nature of the O VI component unambiguously determined. Furthermore, in other examples, where the spectra were of a high signal-to-noise, no photospheric material was found and any O VI detected was assumed to be interstellar. Building on the earlier work of Oegerle et al. (2005) and Savage & Lehner (2006), we have increased the number of detections of interstellar O VI and, for the first time, compared their locations...

  5. 29 CFR 1910.1026 - Chromium (VI).

    Science.gov (United States)

    2010-07-01

    ... activity involving chromium cannot release dusts, fumes, or mists of chromium (VI) in concentrations at or... currents that prevent the LEVs from performing efficiently. The use of fans has a similar effect. Industry... and positioning of cross drafts, fans, doors, windows, partitions and process equipment that...

  6. The exploration of potassium ferrate(VI) as a disinfectant/coagulant in water and wastewater treatment.

    Science.gov (United States)

    Jiang, Jia-Qian; Wang, S; Panagoulopoulos, A

    2006-04-01

    This paper aims to explore potassium ferrate(VI) (K2FeO4) as an alternative water treatment chemical for both drinking water and wastewater treatment. The performance of potassium ferrate(VI) was evaluated in comparison with that of sodium hypochlorite (NaOCl) and that of NaOCl plus ferric sulphate (FS) or alum (AS). The dosages of ferrate(VI), NaOCl and FS/AS and sample pH values were varied in order to investigate the effects of these factors on the treatment performance. The study demonstrates that in drinking water treatment, ferrate(VI) can remove 10-20% more UV(254)-abs and DOC than FS for the same dose compared for natural pH range (6 and 8). The THMFP was reduced to less than 100 microg l(-1) by ferrate(VI) at a low dose. In addition to this, ferrate(VI) can achieve the disinfection targets (>6 log10 inactivation of Escherichia coliform (E. coli)) at a very low dose (6 mg l(-1) as Fe) and over wide working pH in comparison with chlorination (10 mg l(-1) as Cl2) plus coagulation (FS, 4 mg l(-1) as Fe). In wastewater treatment, ferrate(VI) can reduce 30% more COD, and kill 3log10 more bacteria compared to AS and FS at a similar or even smaller dose. Also, potassium ferrate(VI) can produce less sludge volume and remove more pollutants, which could make sludge treatment easier.

  7. Basin stability in delayed dynamics

    Science.gov (United States)

    Leng, Siyang; Lin, Wei; Kurths, Jürgen

    2016-02-01

    Basin stability (BS) is a universal concept for complex systems studies, which focuses on the volume of the basin of attraction instead of the traditional linearization-based approach. It has a lot of applications in real-world systems especially in dynamical systems with a phenomenon of multi-stability, which is even more ubiquitous in delayed dynamics such as the firing neurons, the climatological processes, and the power grids. Due to the infinite dimensional property of the space for the initial values, how to properly define the basin’s volume for delayed dynamics remains a fundamental problem. We propose here a technique which projects the infinite dimensional initial state space to a finite-dimensional Euclidean space by expanding the initial function along with different orthogonal or nonorthogonal basis. A generalized concept of basin’s volume in delayed dynamics and a highly practicable calculating algorithm with a cross-validation procedure are provided to numerically estimate the basin of attraction in delayed dynamics. We show potential applicabilities of this approach by applying it to study several representative systems of biological or/and physical significance, including the delayed Hopfield neuronal model with multistability and delayed complex networks with synchronization dynamics.

  8. Final Technical Report -- GEO-VI - USGEO

    Energy Technology Data Exchange (ETDEWEB)

    Hirsch, Leonard

    2009-11-30

    Representatives of US earth observations departments and agencies, other participating governments, NGOs and civil society participated in the Sixth Plenary Meeting of the Group on Earth Observations (GEO-VI), hosted by the United States in Washington, DC on November 17 and 18, 2009. The meeting was held in the Atrium Ballroom of the Ronald Reagan International Trade Center. Exhibitions of international Earth observation technology and programs were held concurrently in the same venue. A number of GEO committee meetings and side events were held in conjunction with the GEO-VI Plenary, including the GEO-IGOS Symposium on Earth observation science and applications, the GEOSS in the Americas Forum on Coastal Zones, and separate meetings of the GEO Communities of Practice on Carbon, Health, and Air Quality.

  9. CPE OF URANIUM (VI USING IONIC LIQUID

    Directory of Open Access Journals (Sweden)

    SANAA NAÏT-TAHAR

    2016-07-01

    Full Text Available Cloud point extraction (CPE was used to extract uranium (VI from an aqueous solution in acetate media. The methodology used is based on the formation of uranyl-ionic liquid (I complexes and uranyl-D2EHPA soluble in a micellar phase of non-ionic surfactant (Triton X-100. The uranium (VI complexes are then extracted into the surfactant-rich phase at ambient temperature. The ionic liquid (IL used as a chelating agent was synthesized and characterized in this study. It is composed of N-butyl N’-triethoxy methyl imidazolium cation and diethylhexylphosphate (D2EHPA-H as anion. The effect of the IL on the extraction efficiency was studied in presence and in absence of IL’s cation in acetate medium.

  10. Proceedings of Minnowbrook Workshops I to VI

    Science.gov (United States)

    2012-01-01

    This DVD collection includes the complete proceedings of Minnowbrook Workshops I through VI. Titles include Minnowbrook I - 1993 Workshop on End-Stage Boundary Layer Transition (NASA/CP-2007-214667, CASI ID 20070038942), Minnowbrook II - 1997 Workshop on Boundary Layer Transition in Turbomachines (NASA/CP-1998-206958, CASI ID 19980206205), Minnowbrook III - 2000 Workshop on Boundary Layer Transition and Unsteady Aspects of Turbomachinery Flow (NASA/CP-2001-210888, CASI ID 20020067662), Minnowbrook IV - 2003 Workshop on Transition and Unsteady Aspects of Turbomachinery Flows (NASA TM-2004-212913, CASI ID 20040121174), Minnowbrook V - 2006 Workshop on Unsteady Flows in Turbomachinery (NASA/CP-2006-214484, CASI ID 20070024781), and Minnowbrook VI - 2009 Workshop on Flow Physics and Control for Internal and External Aerodynamics (NACA/CP-2010-216112, CASI ID 20100018557).

  11. Skal vi fodre svin med humanister?

    DEFF Research Database (Denmark)

    Holm, Claus

    2005-01-01

    Også i 2015 vil mange humanistiske akademikere være arbejdsløse eller lavt lønnede. Samtidig vil antallet af læger og tandlæger, ingeniører og jurister være for lavt. Hvorfor er vi så dårlige til at planlægge uddannelser? Adjungeret professor Nils Groes, DPU, mener, uddannelsessystemets uvidenhed...

  12. Prospek pengembangan industri perkulitan pada pelita VI

    Directory of Open Access Journals (Sweden)

    D Karyadi

    1995-06-01

    Full Text Available The leather industry is one of the strong competitive industry, as it comes from renewable natural resources. Therefore, the leather industry has good prospect to develop at the Pelita VI to be the industrial products export competitive. To develop leather industry and leather products should be given closed attention and well managed, especially concerning raw material supply, quality and leather waste treatment.

  13. Development of Vi conjugate - a new generation of typhoid vaccine.

    Science.gov (United States)

    Szu, Shousun Chen

    2013-11-01

    Typhoid fever remains to be a serious disease burden worldwide with an estimated annual incidence about 20 million. The licensed vaccines showed moderate protections and have multiple deficiencies. Most important of all, none of the licensed typhoid vaccines demonstrated protection for children under 5 years old. These limitations impeded successful implementation of typhoid vaccination programs. To improve immunogenicity Vi was conjugated to rEPA, a recombinant exoprotein A from Pseudomonas aeruginosa. Vi-rEPA showed higher and longer lasting anti-Vi IgG in adults and children than Vi alone in high endemic areas. In school-age children and adults, the immunity persisted more than 8 years. In a double-blind, placebo-controlled and randomized efficacy trial in 2- to 5-year-old children, Vi-rEPA conferred 89% protective efficacy against typhoid fever and the protection lasted at least 4 years. When given concomitantly with infant routine vaccines, Vi-rEPA was safe, immunogenic and showed no interference with the routine vaccines. Vi conjugate vaccine was also attempted and successfully demonstrated by several other laboratories and manufactures. Using either rEPA or different carrier proteins, such as diphtheria or tetanus toxoid, recombinant diphtheria toxin (CRM197), the Vi conjugates synthesized was significantly more immunogenic than Vi alone. Recently, two Vi-tetanus toxoid conjugates were licensed in India for all ages, starts as young as 3 month old. This new generation of typhoid vaccine opens up a new era for typhoid prevention and elimination.

  14. Assessing Potential Conservation and Restoration Areas of Freshwater Fish Fauna in the Indian River Basins.

    Science.gov (United States)

    Bhatt, Jay P; Manish, Kumar; Mehta, Rajender; Pandit, Maharaj K

    2016-05-01

    Conservation efforts globally are skewed toward terrestrial ecosystems. To date, conservation of aquatic ecosystems, in particular fish fauna, is largely neglected. We provide a country-wide assessment of Indian river ecosystems in order to identify and prioritize areas for protection and restoration of freshwater fish fauna. Using various biodiversity and anthropogenic attributes, coupled with tools of ecological modeling, we delineated areas for fish fauna conservation and restoration in the 20 major river basins of India. To do this, we used prioritization analyses and reserve selection algorithms to derive conservation value index (CVI) and vulnerability index (VI) of the river basins. CVI was estimated using endemicity, rarity, conservation value, and taxonomic singularity, while VI was estimated using a disturbance index derived from percent geographic area of the basin under human settlements, human population density, predominant land use, and total number of exotic fish species in each basin. The two indices, CVI and VI, were converted into geo-referenced maps, and each map was super-imposed onto species richness and forest cover maps, respectively. After superimposition, areas with high CVI and low VI shade intensities were delineated for conservation, while areas with high CVI and high VI shade intensities were demarcated for restoration. In view of the importance of freshwater fish for human livelihoods and consumption, and ecosystems of India's rivers, we call for urgent attention to the conservation of their fish fauna along with restoration of their degraded habitats.

  15. Precise positioning of myosin VI on endocytic vesicles in vivo.

    Directory of Open Access Journals (Sweden)

    David Altman

    2007-08-01

    Full Text Available Myosin VI has been studied in both a monomeric and a dimeric form in vitro. Because the functional characteristics of the motor are dramatically different for these two forms, it is important to understand whether myosin VI heavy chains are brought together on endocytic vesicles. We have used fluorescence anisotropy measurements to detect fluorescence resonance energy transfer between identical fluorophores (homoFRET resulting from myosin VI heavy chains being brought into close proximity. We observed that, when associated with clathrin-mediated endocytic vesicles, myosin VI heavy chains are precisely positioned to bring their tail domains in close proximity. Our data show that on endocytic vesicles, myosin VI heavy chains are brought together in an orientation that previous in vitro studies have shown causes dimerization of the motor. Our results are therefore consistent with vesicle-associated myosin VI existing as a processive dimer, capable of its known trafficking function.

  16. Speciation of Cr(III) and Cr(VI) after column solid phase extraction on Amberlite XAD-2010.

    Science.gov (United States)

    Bulut, V N; Duran, C; Tufekci, M; Elci, L; Soylak, M

    2007-05-08

    A speciation procedure for Cr(III) and Cr(VI) based on column solid phase extraction on Amberlite XAD-2010 and flame atomic absorption spectrometry combination. Cr(VI) was quantitatively recovered on Amberlite XAD-2010 resin at pH range of 2.0-3.0 as its diethyldithiocarbamate complex, while the recoveries of Cr(III) was below 5%. The influences of the various parameters including amounts of the reagents, eluent type and its volume, sample volume, etc., on the quantitative recoveries were examined. The interference of matrix and coexistent elements for method were studied. The detection limit (corresponding to three times the standard deviation of the blank) and the enrichment factor for Cr(VI) were found to be 1.28 microg/L and 25, respectively. To verify the accuracy of the method, drinking water certified reference material (CRM-TMDW-500) was analyzed and the results obtained were in good agreement with the certified value. The proposed method has been successfully applied to the speciation of Cr(III) and Cr(VI) in water samples and preconcentration of total chromium in environmental samples.

  17. DBC solvent extraction of U(VI) from thiocyanate medium

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The extraction behavior of uranium(VI) from thiocyanate medium with dibenzo-18-crown-6 (DBC) in nitrobenzene and the effects of alkali cations on the extraction were investigated. The results showed that the uranium (VI) can be effectively extracted in the presence of potassium cation, uranium (VI) is extracted as complex anionic species UO2(SCN)-3, and the stoichiometry of the extracted complex is KUO2(SCN)32DBC(o).

  18. Oral–Facial–Digital Syndrome type VI with self mutilations

    Directory of Open Access Journals (Sweden)

    Rabah M. Shawky

    2014-10-01

    Full Text Available We report the case of a 2.5 year old female, 2nd in order of birth of 1st cousin consanguineous marriage, with the typical features of Oral–Facial–Digital Syndrome type VI (OFDS VI including midline pseudo cleft upper lip, sublingual nodule, molar tooth sign by MRI brain, bilateral mesoaxial polydactyly (hexadactyly, and developmental delay. The patient had self mutilations which was not reported before in OFDS VI except once.

  19. Farvel til globaliseringen som vi kendte den

    DEFF Research Database (Denmark)

    Böss, Michael

    2009-01-01

    Vi er endt med en krise, som rækker langt ud over det globale monetære system, fordi den ideologiske ortodoksi, der skabte den, har ført til udflytning af millioner af arbejdspladser, tæring af nationalstaternes sammenhængskraft og overgreb på naturen. Kronikken refererer bl.a. til John Maynard K...... Keynes og en artikel af økonomen Robert Skidelsky i The American Prospect. Udgivelsesdato: 12. januar 2009...

  20. ViSC Social Competence Program.

    Science.gov (United States)

    Strohmeier, Dagmar; Hoffmann, Christine; Schiller, Eva-Maria; Stefanek, Elisabeth; Spiel, Christiane

    2012-01-01

    The ViSC Social Competence Program has been implemented in Austrian schools within the scope of a national strategy plan, Together Against Violence. The program is a primary preventive program designed for grades 5 to 8. The prevention of aggression and bullying is defined as a school development task, and the initial implementation of the program lasts one school year. The program consists of universal and specific actions that are implemented through in-school teacher training and a class project for students. The program was evaluated with a randomized intervention control group design. Data were collected from teachers and students. Results suggest that the program reduces aggression in schools.

  1. Difluoridodioxido(1,10-phenanthrolinemolybdenum(VI

    Directory of Open Access Journals (Sweden)

    Wenju Wang

    2009-09-01

    Full Text Available The title compound, [MoF2O2(C12H8N2], has non-crystallographic mirror symmetry. The MoVI atom shows a distorted octahedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C—H...O and C—H...F hydrogen-bonding contacts and π–π interactions [centroid–centroid distance = 3.662 (1 Å] connect the complex molecules into a three-dimensional supramolecular framework.

  2. Semiconductors A(III)B(VI): Translation

    Science.gov (United States)

    Akhundov, G. A.; Abdullaev, G. B.; Guseynov, G. D.; Mekhtiyev, R. F.; Aliyeva, M. Kh.

    1993-11-01

    Semiconductors A(III) B(VI) crystallize in laminated or chain structures and contain nine valence electrons in each molecule. Connection in the layers and the chains is predominantly covalent, and Van der Waal between the layers and the chains. Calculated data of the energy spectrum of these compounds are absent, and the available experimental studies are insufficient for understanding of the zone structures. We have obtained and studied single crystals of GaS, GaSe, GaTe, InSe, and TiSe.

  3. Environmental survey of Region VI, Haltenbanken, 2009; Miljoeundersoekelse i Region VI, Haltenbanken, 2009

    Energy Technology Data Exchange (ETDEWEB)

    Holm, May-Helen; Cochrane, Sabine; Mannvik, Hans-Petter; Wasbotten, Ingar Halvorsen

    2010-07-01

    There has been an environmental investigation in Region VI Halten Bank. This report presents the results of the chemical and biological assays performed on samples from a total of 316 stations in 16 fields and 15 regional stations. A status of environmental conditions in the region is given at the end of the report. (AG)

  4. Environmental Survey in Region VI, Haltenbanken, 2009. Summary report; Miljoeundersoekelse i Region VI, Haltenbanken, 2009. Sammendragsrapport

    Energy Technology Data Exchange (ETDEWEB)

    Mannvik, Hans-Petter; Wasbotten, Ingar Halvorsen

    2010-07-01

    An environmental survey of Region VI, Haltenbanken, has been carried out. This report presents the results from the analyses carried out on samples from a total of 316 stations at 16 fields and 15 regional stations. A status of the environmental conditions in the region is given at the end of the report. (Author)

  5. Vi lider af prætraumatisk stress

    DEFF Research Database (Denmark)

    Hansen, Brian Benjamin

    2009-01-01

    Vi lider af prætraumatisk stress. Vi vil nemlig nå det hele og presser konstant nye aftaler ind i vores kalender. Det eneste, der hjælper, er at ’gøre intet’ – men kan man overhovedet det? Udgivelsesdato: 30.09.09......Vi lider af prætraumatisk stress. Vi vil nemlig nå det hele og presser konstant nye aftaler ind i vores kalender. Det eneste, der hjælper, er at ’gøre intet’ – men kan man overhovedet det? Udgivelsesdato: 30.09.09...

  6. Extractive removal of chromium (VI) from industrial waste solution.

    Science.gov (United States)

    Agrawal, Archana; Pal, Chandana; Sahu, K K

    2008-11-30

    Extractive removal of Cr (VI) was carried out from chloride solutions using cyanex 923 mixed with kerosene. The efficiency of this extractant was studied under various experimental conditions, such as concentration of different mineral acids in the aqueous phase, concentration of cyanex 923 and Cr (VI) present in the initial aqueous feed, temperature and time of extraction, organic to aqueous (O/A) phase ratio. Percentage Cr (VI) extraction decreases with the increase in temperature at varying concentration of cyanex 923. The interference of the impurities usually associated with Cr (VI) such as Cr (III), Cu, Ni, Fe (II), Zn, Chloride and sulphate, etc., were examined under the optimized conditions and only Zn was found to interfere. Under the optimum experimental conditions 98.6-99.9% of Cr (VI) was extracted in 3-5 min at O/A of 2 with the initial feed concentration of 1g/L of Cr (VI). The extracted Cr (VI) was quantitatively stripped with 1M NaOH and the organic phase obtained after the stripping of Cr (VI) was washed with dilute HCl solution to neutralize any NaOH trapped/adhered to the solvent and then with distilled water. This regenerated solvent was reused in succeeding extraction of chromium (VI). Finally a few experiments were performed with the synthetic effluent from an electroplating industry.

  7. Immunogenicity of a new Salmonella Typhi Vi polysaccharide vaccine--vax-TyVi--in Cuban school children and teenagers.

    Science.gov (United States)

    Azze, Rolando Felipe Ochoa; Rodríguez, Juan Carlos Martínez; Iniesta, Mónica Ginebra; Marchena, Xenia Rosa Ferriol; Alfonso, Vivian María Rodríguez; Padrón, Franklin Tomás Sotolongo

    2003-06-20

    A randomized, controlled, double blind study was carried out in Cuban children and teenagers aged 9-13 years to evaluate the immunogenicity of vax-TyVi-Salmonella Typhi Vi polysaccharide vaccine-with respect control vaccines. Serum samples were taken before and 21 days after the immunization, and ELISA was used for the determination of antibodies to Vi polysaccharide. Subjects who received vax-TyVi and TYPHIM Vi (Pasteur-Mérieux) showed seroconversion rates of 85.61 and 78.36%, respectively. The geometric mean titer (GMT) values for Vi antibodies induced after vaccination were 6.27 microg/ml (5.40-7.38 microg/ml) and 5.97 microg/ml (5.01-7.10 microg/ml), respectively. In contrast, subjects receiving the tetanus toxoid vaccine showed 0% seroconversion.

  8. Boletin de Informacion Educativa, Ano VI, No. 10/11 (Educational Information Bulletin, Volume VI, No. 10/11).

    Science.gov (United States)

    Ministerio de Educacion y Cultura, Santa Fe (Argentina). Centro de Documentacion e Informacion Educativa de la Provincia de Santa Fe.

    This information bulletin is published by the Documentation and Educational Information Center in the Argentine province of Santa Fe. The bulletin reports on educational developments in the province and abroad, educational problems, statistics, legislation, documentation and information techniques, and information from international organizations.…

  9. Boletin Estadistico de la Educacion: Ano VI, No. 1 (Statistical Bulletin on Education: Volume VI, No. 1).

    Science.gov (United States)

    Ministerio de Educacion, Guatemala City (Guatemala). Oficina de Planeamiento Integral de la Educacion.

    This booklet presents statistics concerning primary education in Guatemala. The first section covers enrollment, considering such factors as type of school and location. Other sections provide statistics on teachers, their locations, the number of schools, enrollment in terms of students repeating grades or leaving school, students advancing out…

  10. Statistical design of experiments as a tool for optimizing the batch conditions to Cr(VI) biosorption on Araucaria angustifolia wastes.

    Science.gov (United States)

    Brasil, Jorge L; Ev, Ricardo R; Milcharek, Caroline D; Martins, Lucas C; Pavan, Flavio A; dos Santos, Araci A; Dias, Silvio L P; Dupont, Jairton; Zapata Noreña, Caciano P; Lima, Eder C

    2006-05-20

    In order to reduce the total number of experiments for achieving the best conditions for Cr(VI) uptake using Araucaria angustifolia (named pinhão) wastes as a biosorbent, three statistical design of experiments were carried out. A full 2(4) factorial design with two blocks and two central points (20 experiments) was experimented (pH, initial metallic ion concentration-C(o), biosorbent concentration-X and time of contact-t), showing that all the factors were significant; besides, several interactions among the factors were also significant. These results led to the performance of a Box-Behnken surface analysis design with three factors (X, C(o) and t) and three central points and just one block (15 experiments). The performance of these two statistical designs of experiments led to the best conditions for Cr(VI) biosorption on the pinhão wastes using a batch system, where: pH 2.0; C(o) = 1200 mg l(-1) Cr(VI); X = 1.5 g l(-1) of biosorbent; t = 8 h. The maximum Cr(VI) uptake in these conditions was 125 mg g(-1). After evaluating the best Cr(VI) biosorption conditions on pinhão wastes, a new Box-Behnken surface analysis design was employed in order to verify the effects of three concomitant ions (Cl(-), NO(3)(-) and PO(4)(3-)) on the biosorption of Cr(VI) as a dichromate on the biosorbent (15 experiments). These results showed that the tested anions did not show any significant effect on the Cr(VI) uptake by pinhão wastes. In order to evaluate the pinhão wastes as a biosorbent in dynamic system, a glass column was fulfilled with pinhão wastes (4.00 g) as biosorbent, and it was fed with 25.0 mg l(-1) Cr(VI) at pH 2.0 and 2.5 ml min(-1). The breakpoint was attained when concentrations of effluent of the column attained the value of 0.05 mg l(-1) Cr(VI) using 5550 ml of the metallic ion solution. In these conditions, the biosorbent was able to remove completely Cr(VI) from aqueous solution with a ratio of Cr(VI) effluent volume/biosorbent volume of 252.3.

  11. FINAL REPORT FOR THE REDUCTION OF CHROME (VI) TO CHROME (III) IN THE SECONDARY WASTE STREAM OF THE EFFLUENT TREATMENT FACILITY

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN JB; GUTHRIE MD

    2008-08-29

    This report documents the laboratory results of RPP-PLAN-35958, Test Plan for the Effluent Treatment Facility to Reduce Chrome (VI) to Chrome (III) in the Secondary Waste Stream With the exception of the electrochemical corrosion scans, all work was carried out at the Center for Laboratory Science (CLS) located at the Columbia Basin College. This document summarizes the work carried out at CLS and includes the electrochemical scans and associated corrosion rates for 304 and 316L stainless steel.

  12. Volume Entropy

    CERN Document Server

    Astuti, Valerio; Rovelli, Carlo

    2016-01-01

    Building on a technical result by Brunnemann and Rideout on the spectrum of the Volume operator in Loop Quantum Gravity, we show that the dimension of the space of the quadrivalent states --with finite-volume individual nodes-- describing a region with total volume smaller than $V$, has \\emph{finite} dimension, bounded by $V \\log V$. This allows us to introduce the notion of "volume entropy": the von Neumann entropy associated to the measurement of volume.

  13. Infrared and millimeter waves v.15 millimeter components and techniques, pt.VI

    CERN Document Server

    Button, Kenneth J

    1986-01-01

    Infrared and Millimeter Waves, Volume 15: Millimeter Components and Techniques, Part VI is concerned with millimeter-wave guided propagation and integrated circuits. This book covers low-noise receiver technology for near-millimeter wavelengths; dielectric image-line antennas; EHF satellite communications (SATCOM) terminal antennas; and semiconductor antennas for millimeter-wave integrated circuits. A scanning airborne radiometer for 30 and 90 GHz and a self-oscillating mixer are also described. This monograph is comprised of six chapters and begins with a discussion on the design of low-n

  14. The ViP2P Platform: XML Views in P2P

    CERN Document Server

    Karanasos, Konstantinos; Manolescu, Ioana; Zoupanos, Spyros

    2011-01-01

    The growing volumes of XML data sources on the Web or produced by enterprises, organizations etc. raise many performance challenges for data management applications. In this work, we are concerned with the distributed, peer-to-peer management of large corpora of XML documents, based on distributed hash table (or DHT, in short) overlay networks. We present ViP2P (standing for Views in Peer-to-Peer), a distributed platform for sharing XML documents based on a structured P2P network infrastructure (DHT). At the core of ViP2P stand distributed materialized XML views, defined by arbitrary XML queries, filled in with data published anywhere in the network, and exploited to efficiently answer queries issued by any network peer. ViP2P allows user queries to be evaluated over XML documents published by peers in two modes. First, a long-running subscription mode, when a query can be registered in the system and receive answers incrementally when and if published data matches the query. Second, queries can also be asked...

  15. ViSlang: A system for interpreted domain-specific languages for scientific visualization

    KAUST Repository

    Rautek, Peter

    2014-12-31

    Researchers from many domains use scientific visualization in their daily practice. Existing implementations of algorithms usually come with a graphical user interface (high-level interface), or as software library or source code (low-level interface). In this paper we present a system that integrates domain-specific languages (DSLs) and facilitates the creation of new DSLs. DSLs provide an effective interface for domain scientists avoiding the difficulties involved with low-level interfaces and at the same time offering more flexibility than high-level interfaces. We describe the design and implementation of ViSlang, an interpreted language specifically tailored for scientific visualization. A major contribution of our design is the extensibility of the ViSlang language. Novel DSLs that are tailored to the problems of the domain can be created and integrated into ViSlang. We show that our approach can be added to existing user interfaces to increase the flexibility for expert users on demand, but at the same time does not interfere with the user experience of novice users. To demonstrate the flexibility of our approach we present new DSLs for volume processing, querying and visualization. We report the implementation effort for new DSLs and compare our approach with Matlab and Python implementations in terms of run-time performance.

  16. Equations of state of ice VI and ice VII at high pressure and high temperature.

    Science.gov (United States)

    Bezacier, Lucile; Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Hervé; Hanfland, Michael; Daniel, Isabelle

    2014-09-14

    High-pressure H2O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H2O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V0 = 14.17(2) cm(3) mol(-1), K0 = 14.05(23) GPa, and α0 = 14.6(14) × 10(-5) K(-1) for ice VI and V0 = 12.49(1) cm(3) mol(-1), K0 = 20.15(16) GPa, and α0 = 11.6(5) × 10(-5) K(-1) for ice VII.

  17. Geological evolution and analysis of confirmed or suspected gas hydrate localities: Volume 10, Basin analysis, formation and stability of gas hydrates of the Aleutian Trench and the Bering Sea

    Energy Technology Data Exchange (ETDEWEB)

    Krason, J.; Ciesnik, M.

    1987-01-01

    Four major areas with inferred gas hydrates are the subject of this study. Two of these areas, the Navarin and the Norton Basins, are located within the Bering Sea shelf, whereas the remaining areas of the Atka Basin in the central Aleutian Trench system and the eastern Aleutian Trench represent a huge region of the Aleutian Trench-Arc system. All four areas are geologically diverse and complex. Particularly the structural features of the accretionary wedge north of the Aleutian Trench still remain the subjects of scientific debates. Prior to this study, suggested presence of the gas hydrates in the four areas was based on seismic evidence, i.e., presence of bottom simulating reflectors (BSRs). Although the disclosure of the BSRs is often difficult, particularly under the structural conditions of the Navarin and Norton basins, it can be concluded that the identified BSRs are mostly represented by relatively weak and discontinuous reflectors. Under thermal and pressure conditions favorable for gas hydrate formation, the relative scarcity of the BSRs can be attributed to insufficient gas supply to the potential gas hydrate zone. Hydrocarbon gas in sediment may have biogenic, thermogenic or mixed origin. In the four studied areas, basin analysis revealed limited biogenic hydrocarbon generation. The migration of the thermogenically derived gases is probably diminished considerably due to the widespread diagenetic processes in diatomaceous strata. The latter processes resulted in the formation of the diagenetic horizons. The identified gas hydrate-related BSRs seem to be located in the areas of increased biogenic methanogenesis and faults acting as the pathways for thermogenic hydrocarbons.

  18. On Restoring Sedimentary Basins for Post-Depositional Deformation - Paleozoic Basins of the Central Andes

    Science.gov (United States)

    Bahlburg, H.

    2015-12-01

    The reconstruction and interpretation of sedimentary basins incorporated into folded and thrusted mountain belts is strongly limited by the style and intensity of shortening. This problem is exacerbated if deformation is polyphasic as is the case for the Paleozoic basins in the central Andes. Some of these have been deformed by folding and thrusting during at least 3 events in the Late Ordovician, the Late Paleozoic and Cenozoic. A realistic reconstruction of the original basin dimensions and geometries from outcrops and maps appears to be almost impossible. We present results of a stepwise reconstruction of the Paleozoic basins of the central Andes by restoring basin areas and fills accounting for crustal shortening. The structurally most prominent feature of the central Andes is the Bolivian Orocline which accomodated shortening in the last 45 Ma on the order of between 300 and 500 km. In a first step basins were restored by accounting for Cenozoic rotation and shortening by deconvolving the basins using an enhanced version of the oroclinal bending model of Ariagada et al. (2008). Results were then restored stepwise for older deformation. Constraints on these subsequent steps are significantly poorer as values of shortening can be derived only from folds and thusts apparent in outcrops. The amount of shortening accomodated on unexposed and therefore unknown thrusts can not be quantified and is a significant source of error very likely leading to an underestimation of the amount of shortening. Accepting these limitations, basin restoration results in an increase in basin area by ≥100%. The volumes of stratigraphically controlled basin fills can now be redistributed over the wider, restored area, translating into smaller rates of accumulation and hence required subsidence. The restored rates conform to those of equivalent modern basin settings and permit a more realistic and actualistic analysis of subsidence drivers and the respective tectonic framework.

  19. A dynamic analysis of water footprint of Jinghe River basin

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Water footprint in a region is defined as the volume of water needed for the production of goods and services consumed by the local people. Ecosystem services are a kind of important services, so ecological water use is one necessary component in water footprint. Water footprint is divided into green water footprint and blue water footprint but the former one is often ignored. In this paper water footprint includes blue water needed by agricultural irrigation, industrial and domestic water demand, and green water needed by crops, economic forests, livestock products, forestlands and grasslands. The study calculates the footprint of the Jinghe River basin in 1990,1995, 2000 and 2005 with quarto methods. Results of research show that water footprints reached 164.1 × 108m3, 175.69×108m3 and 178.45×108m3 respectively in 1990, 1995 and 2000 including that of ecological water use, but reached 77.68×108m3, 94.24×108m3, 92.92×108m3 and 111.36×108m3 respectively excluding that of ecological water use. Green water footprint is much more than blue water footprint: thereby, green water plays an important role in economic development and ecological construction. The dynamic change of water footprints stows that blue water use increases rapidly and that the ecological water use is occupied by economic and domestic water use. The change also shows that water use is transferred from primary industry to secondary industry. In primary industry, it is transferred from crops farming to forestry and animal agriculture. The factors impelling the change include development anticipation on economy, government policies, readjustment of the industrial structure, population growth, the raise of urbanization level, and structural change of consumption, low level of water-saving and poor ability of waste water treatment. With blue water use per unit, green water use per unit, blue water use structure and green water use structure, we analyzed the difference of the six ecological

  20. Kandinsky's "Composition VI": Heideggerian Poetry in Noah's Ark

    Science.gov (United States)

    Hall, Joshua M.

    2012-01-01

    The author will begin his investigation of Wassily Kandinsky's painting "Composition VI" with Kandinsky's own commentary on the painting. He will then turn to the analysis of Kandinsky and the "Compositions" in John Sallis's book "Shades." Using this analysis as his point of departure, the author will consider how "Composition VI" resonates with…

  1. Vi I typing phage for generalized transduction of Salmonella typhi.

    OpenAIRE

    Cerquetti, M C; Hooke, A M

    1993-01-01

    Salmonella typhi Vi typing phages were used to transduce temperature-sensitive (Ts) mutants of Salmonella typhi. Antibiotic resistance and Ts+ markers were transduced at high frequency (> 10(-4) per virulent phage). Several markers were cotransduced by phage Vi I, suggesting that it may be useful for mapping studies of the S. typhi genome.

  2. Claude Lévi-Strauss est mort…

    Directory of Open Access Journals (Sweden)

    Claude Dubar

    2009-11-01

    Full Text Available Ce mardi 3 novembre 2009 est jour de deuil dans la communauté des sciences humaines et sociales du monde entier et au-delà. Claude Lévi-Strauss vient de mourir alors qu’il allait avoir 101 ans. Il fut un des plus grands esprits du XXe siècle, à la fois anthropologue, philosophe, écrivain et humaniste. Il fait partie de ceux qui parvinrent à révolutionner la conception du temps des penseurs évolutionnistes occidentaux enfermés dans une pensée « progressiste » du temps issue de la philosophie d...

  3. Photovoltaic effects in II-VI heterojunctions

    Energy Technology Data Exchange (ETDEWEB)

    Bube, R.H.

    1977-01-01

    Photovoltaic effects have been investigated in II-VI heterojunctions prepared by close-space vapor transport, vacuum evaporation, spray pyrolysis and sputtering. Solar efficiencies of about 8% have been measured for the following systems: (a) n-CdS film deposited on single crystal p-CdTe by vacuum evaporation, (b) n-ZnCdS film deposited on single crystal p-CdTe by spray pyrolysis, and (c) n-Indium-Tin Oxide film deposited on single crystal p-CdTe by sputtering in an inert atmosphere. Open-circuit voltages greater than 0.8 V have been measured in heterojunctions of type (b) and (c), as well as in CdTe p-n homojunctions produced by ion implantation.

  4. Six-fold Coordinated Carbon Dioxide VI

    Energy Technology Data Exchange (ETDEWEB)

    Iota, V; Yoo, C; Klepeis, J; Jenei, Z

    2006-03-01

    Under standard conditions, carbon dioxide (CO{sub 2}) is a simple molecular gas and an important atmospheric constituent while silicon dioxide (SiO{sub 2}) is a covalent solid, and represents one of the fundamental minerals of the planet. The remarkable dissimilarity between these two group IV oxides is diminished at higher pressures and temperatures as CO{sub 2} transforms to a series of solid phases, from simple molecular to a fully covalent extended-solid V, structurally analogous to SiO{sub 2} tridymite. Here, we present the discovery of a new extended-solid phase of carbon dioxide (CO{sub 2}): a six-fold coordinated stishovite-like phase VI, obtained by isothermal compression of associated CO{sub 2}-II above 50GPa at 530-650K. Together with the previously reported CO{sub 2}-V and a-carbonia, this new extended phase indicates a fundamental similarity between CO{sub 2}--a prototypical molecular solid, and SiO{sub 2}--one of Earth's fundamental building blocks. The phase diagram suggests a limited stability domain for molecular CO{sub 2}-I, and proposes that the conversion to extended-network solids above 40-50 GPa occurs via intermediate phases II, III, and IV. The crystal structure of phase VI suggests strong disorder along the caxis in stishovite-like P4{sub 2}/mnm, with carbon atoms manifesting an average six-fold coordination within the framework of sp{sup 3} hybridization.

  5. Tolerance and bioaccumulation of U(VI) by Bacillus mojavensis and its solid phase preconcentration by Bacillus mojavensis immobilized multiwalled carbon nanotube.

    Science.gov (United States)

    Özdemir, Sadin; Oduncu, M Kadir; Kilinc, Ersin; Soylak, Mustafa

    2017-02-01

    In this study, uranium(VI) tolerance and bioaccumulation were investigated by using thermo -tolerant Bacillus mojavensis. The level of U(VI) was measured by UV-VIS spectrophotometry. The minimum inhibition concentration (MIC) value of U(VI) was experimented. Bacterial growth was not affected in the presence of 1.0 and 2.5 mg/L U(VI) at 36 h and the growth was partially affected in the presence of 5 mg/L U(VI) at 24 h. What was obtained from this study is that there was diversity in the various periods of the growth phases of metal bioaccumulation capacity, which was shown by B. mojavensis. The maximum bioaccumulation capacities were found to be 12.8, 22.7, and 48.2 mg/g dried bacteria, at 24th hours at concentration of 1.0, 2.5 and 5 mg/L U(VI), respectively. In addition to these, U(VI) has been preconcentrated on B. mojavensis immobilized MWCNT. Several factors such as pH, flow rate of solution, amount of biosorbent and support materials, eluent type, concentration and volume, the matrix interference effect on retention have been studied, and extraction conditions were optimized. Preconcentration factor was achieved as 60. Under the optimized conditions, the limit of detection (LOD) and quantification (LOQ) were calculated as 0.74 and 2.47 μg/L. The biosorption capacity of immobilized B. mojavensis was calculated for U(VI) as 25.8 mg/g. The results demonstrated that the immobilized biosorbent column could be reused at least 30 cycles of biosorption and desorption with the higher than 95% recovery. FT-IR and SEM analysis were performed to understand the surface properties of B. mojavensis.

  6. Electrochemical alkaline Fe(VI) water purification and remediation.

    Science.gov (United States)

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  7. Monitoring and Evaluation of Smolt Migration in the Columbia Basin : Volume XVI : Survival and Transportation Effects for Migrating Snake River Hatchery Chinook Salmon and Steelhead: Historical Estimates from 1996-2003.

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, Rebecca A.; Skalski, John R.

    2007-12-07

    In 2005, the University of Washington developed a new statistical model to analyze the combined juvenile and adult detection histories of PIT-tagged salmon migrating through the Federal Columbia River Power System (FCRPS). This model, implemented by software Program ROSTER (River-Ocean Survival and Transportation Effects Routine), has been used to estimate survival and transportation effects on large temporal and spatial scales for PIT-tagged hatchery spring and summer Chinook salmon and steelhead released in the Snake River Basin from 1996 to 2003. Those results are reported here. Annual estimates of the smolt-to-adult return ratio (SAR), juvenile inriver survival from Lower Granite to Bonneville, the ocean return probability from Bonneville to Bonneville, and adult upriver survival from Bonneville to Lower Granite are reported. Annual estimates of transport-inriver (T/I) ratios and differential post-Bonneville mortality (D) are reported on both a systemwide basis, incorporating all transport dams analyzed, and a dam-specific basis. Transportation effects are estimated only for dams where at least 5,000 tagged smolts were transported from a given upstream release group. Because few tagged hatchery steelhead were transported in these years, no transportation effects are estimated for steelhead. Performance measures include age-1-ocean adult returns for steelhead, but not for Chinook salmon. Annual estimates of SAR from Lower Granite back to Lower Granite averaged 0.71% with a standard error (SE) of 0.18% for spring Chinook salmon from the Snake River Basin for tagged groups released from 1996 through 2003, omitting age-1-ocean (jack) returns. For summer Chinook salmon from the Snake River Basin, the estimates of annual SAR averaged 1.15% (SE=0.31%). Only for the release years 1999 and 2000 did the Chinook SAR approach the target value of 2%, identified by the NPCC as the minimum SAR necessary for recovery. Annual estimates of SAR for hatchery steelhead from the

  8. Effects of Surface Treatment of Activated Carbon on Its Surface and Cr(VI) Adsorption Characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Park, Soo Jin; Jang, Yu Sin [Advanced Materials Division., Korea Research Institute of Chimical Technology, Taejon (Korea)

    2001-04-01

    In this work, the effect of surface treatments on activated carbons (ACs) has been studied in the context of gas and liquid adsorption behaviors. The chemical solutions used in this experiment were 35% sodium hydroxide, and these were used for the acidic and basic treatments, respectively. The surface properties have been determined by pH, acid-base values, and FT-IR. The adsorption isotherms of Cr(VI) ion on activated carbons have been studied with the 5 mg/l concentration at ambient temperature. N{sub 2} adsorption isotherm characteristics, which include the specific surface area, micro pore volume, and microporosity, were determined by BET and Boer's-plot methods. In case of the acidic treatment of activated carbons, it was observed that the adsorption of Cr(VI) ion was more effective due to the increase acid value (or acidic functional group) of activated carbon surfaces. However, the basic treatment on activated carbons was caused no significant effects, probably due to the decreased specific surface area and total pore volume. 27 refs., 7 figs., 4 tabs.

  9. Defective collagen VI α6 chain expression in the skeletal muscle of patients with collagen VI-related myopathies

    Science.gov (United States)

    Tagliavini, F.; Pellegrini, C.; Sardone, F.; Squarzoni, S.; Paulsson, M.; Wagener, R.; Gualandi, F.; Trabanelli, C.; Ferlini, A.; Merlini, L.; Santi, S.; Maraldi, N.M.; Faldini, C.; Sabatelli, P.

    2014-01-01

    Collagen VI is a non-fibrillar collagen present in the extracellular matrix (ECM) as a complex polymer; the mainly expressed form is composed of α1, α2 and α3 chains; mutations in genes encoding these chains cause myopathies known as Ullrich congenital muscular dystrophy (UCMD), Bethlem myopathy (BM) and myosclerosis myopathy (MM). The collagen VI α6 chain is a recently identified component of the ECM of the human skeletal muscle. Here we report that the α6 chain was dramatically reduced in skeletal muscle and muscle cell cultures of genetically characterized UCMD, BM and MM patients, independently of the clinical phenotype, the gene involved and the effect of the mutation on the expression of the “classical” α1α2α3 heterotrimer. By contrast, the collagen VI α6 chain was normally expressed or increased in the muscle of patients affected by other forms of muscular dystrophy, the overexpression matching with areas of increased fibrosis. In vitro treatment with TGF-β1, a potent collagen inducer, promoted the collagen VI α6 chain deposition in the ECM of normal muscle cells, whereas, in cultures derived from collagen VI-related myopathy patients, the collagen VI α6 chain failed to develop a network outside the cells and accumulated in the endoplasmic reticulum. The defect of the α6 chain points to a contribution to the pathogenesis of collagen VI-related disorders. PMID:24907562

  10. Column study of chromium(VI) adsorption from electroplating industry by coconut coir pith

    Energy Technology Data Exchange (ETDEWEB)

    Suksabye, Parinda [Joint Graduate School of Energy and Environment, King Mongkut' s University of Technology Thonburi, 91 Pracha-Utit Road, Bangmod, Thungkru, Bangkok 10140 (Thailand); Thiravetyan, Paitip [Division of Biotechnology, School of Bioresources and Technology, King Mongkut' s University of Technology Thonburi, 83 Moo.8 Thakham, Bangkhuntien, Bangkok 10150 (Thailand)], E-mail: paitip.thi@kmutt.ac.th; Nakbanpote, Woranan [Pilot Plant Development and Training Institute, King Mongkut' s University of Technology Thonburi, 83 Moo.8 Thakham, Bangkhuntien, Bangkok 10150 (Thailand)

    2008-12-15

    The removal of Cr(VI) from electroplating wastewater by coir pith was investigated in a fixed-bed column. The experiments were conducted to study the effect of important parameters such as bed depth (40-60 cm) and flow rate (10-30 ml min{sup -1}). At 0.05 C{sub t}/C{sub 0}, the breakthrough volume increased as flow rate decreased or a bed depth increased due to an increase in empty bed contact time (EBCT). The bed depth service time model (BDST) fit well with the experimental data in the initial region of the breakthrough curve, while the simulation of the whole curve using non-linear regression analysis was effective using the Thomas model. The adsorption capacity estimated from the BDST model was reduced with increasing flow rate, which was 16.40 mg cm{sup -3} or 137.91 mg Cr(VI) g{sup -1} coir pith for the flow rates of 10 ml min{sup -1} and 14.05 mg cm{sup -3} or 118.20 mg Cr(VI) g{sup -1} coir pith for the flow rates of 30 ml min{sup -1}. At the highest bed depth (60 cm) and the lowest flow rate (10 ml min{sup -1}), the maximum adsorption reached 201.47 mg Cr(VI) g{sup -1} adsorbent according to the Thomas model. The column was regenerated by eluting chromium using 2 M HNO{sub 3} after adsorption studies. The desorption of Cr(III) in each of three cycles was about 67-70%. The desorption of Cr(III) in each cycle did not reach 100% due to the fact that Cr(V) was present through the reduction of Cr(VI), and was still in coir pith, possibly bound to glucose in the cellulose part of coir pith. Therefore, the Cr(V) complex cannot be desorbed in solution. The evidence of Cr(V) signal was observed in coir pith, {alpha}-cellulose and holocellulose extracted from coir pith using electron spin resonance (ESR)

  11. Column study of chromium(VI) adsorption from electroplating industry by coconut coir pith.

    Science.gov (United States)

    Suksabye, Parinda; Thiravetyan, Paitip; Nakbanpote, Woranan

    2008-12-15

    The removal of Cr(VI) from electroplating wastewater by coir pith was investigated in a fixed-bed column. The experiments were conducted to study the effect of important parameters such as bed depth (40-60cm) and flow rate (10-30ml min(-1)). At 0.05 C(t)/C(0), the breakthrough volume increased as flow rate decreased or a bed depth increased due to an increase in empty bed contact time (EBCT). The bed depth service time model (BDST) fit well with the experimental data in the initial region of the breakthrough curve, while the simulation of the whole curve using non-linear regression analysis was effective using the Thomas model. The adsorption capacity estimated from the BDST model was reduced with increasing flow rate, which was 16.40mg cm(-3) or 137.91mg Cr(VI)g(-1) coir pith for the flow rates of 10ml min(-1) and 14.05mg cm(-3) or 118.20mg Cr(VI)g(-1) coir pith for the flow rates of 30ml min(-1). At the highest bed depth (60cm) and the lowest flow rate (10mlmin(-1)), the maximum adsorption reached 201.47mg Cr(VI)g(-1) adsorbent according to the Thomas model. The column was regenerated by eluting chromium using 2M HNO(3) after adsorption studies. The desorption of Cr(III) in each of three cycles was about 67-70%. The desorption of Cr(III) in each cycle did not reach 100% due to the fact that Cr(V) was present through the reduction of Cr(VI), and was still in coir pith, possibly bound to glucose in the cellulose part of coir pith. Therefore, the Cr(V) complex cannot be desorbed in solution. The evidence of Cr(V) signal was observed in coir pith, alpha-cellulose and holocellulose extracted from coir pith using electron spin resonance (ESR).

  12. Vi behøver innovation

    DEFF Research Database (Denmark)

    McAloone, Tim C.

    2007-01-01

    . Især hvad angår vores forbrugsmønstre. Her er der behov for at kongeriget Danmark med sine 13 ton CO2-emission pr. person om året lytter. I landet hvor kraftvarmeproduk­tion, vindturbiner og industrial ecology i form af Kalundborg eksperimentet blev født, bør vi ikke også ride på denne nye miljøbølge......? Den amerikanske videnskabsmand Jeremy Rifkin beskriver i sin seneste bog, The European Dream, hvordan europæisk energipolitik, -forskning, -udvikling og relateret industri kan hjælpe os til at bremse vores for øjeblikket eksponentielt stigende CO2-produktion - og hvordan vores globaliseringstankegang...... rent faktisk kan fremme denne indsats. Den eneste udfordring er, at nogen skal igangsætte en økonomisk/industriel revolution, for at drømmen går i opfyldelse. Hvem skal tage ansvar for at sætte denne revolution i gang, og hvordan skal den opnås? Rifkin's patentløsning er inspirerende. Den er kort...

  13. Elliptic Schlesinger system and Painleve VI

    Energy Technology Data Exchange (ETDEWEB)

    Chernyakov, Yu [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Levin, A M [Institute of Oceanology, Moscow (Russian Federation); Olshanetsky, M [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Zotov, A [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation)

    2006-09-29

    We consider an elliptic generalization of the Schlesinger system (ESS) with positions of marked points on an elliptic curve and its modular parameter as independent variables (the parameters in the moduli space of the complex structure). This system was originally discovered by Takasaki (hep-th/9711095) in the quasi-classical limit of the SL(N) vertex model. Our derivation is purely classical. ESS is defined as a symplectic quotient of the space of connections of bundles of degree 1 over the elliptic curves with marked points. The ESS is a non-autonomous Hamiltonian system with pairwise commuting Hamiltonians. The system is bi-Hamiltonian with respect to the linear and introduced here quadratic Poisson brackets. The latter are the multi-colour form of the Sklyanin-Feigin-Odesski classical algebras. The ESS is the monodromy independence condition on the complex structure for the linear systems related to the flat bundle. The case of four points for a special initial data is reduced to the Painleve VI equation in the form of the Zhukovsky-Volterra gyrostat, proposed in our previous paper.

  14. Research in collegiate mathematics education VI

    CERN Document Server

    Selden, Annie; Harel, Guershon; Hauk, Shandy

    2006-01-01

    The sixth volume of Research in Collegiate Mathematics Education presents state-of-the-art research on understanding, teaching, and learning mathematics at the postsecondary level. The articles advance our understanding of collegiate mathematics education while being readable by a wide audience of mathematicians interested in issues affecting their own students. This is a collection of useful and informative research regarding the ways our students think about and learn mathematics. The volume opens with studies on students' experiences with calculus reform and on the effects of concept-based

  15. A new MoVI Schiff base complex: methanol[N′-(3-methoxy-2-oxidobenzylidenebenzohydrazidato]dioxidomolybdenum(VI

    Directory of Open Access Journals (Sweden)

    Iran Sheikhshoaie

    2011-07-01

    Full Text Available In the title benzilidene Schiff base molybdenum(VI complex, [Mo(C15H12N2O3O2(CH3OH], the MoVI ion is coordinated by two oxide O atoms and by two O atoms and one N atom of the tridentate N′-(3-methoxy-2-oxidobenzylidenebenzohydrazidate (L Schiff base ligand. The methanol O atom completes the distorted octahedral configuration of the MoVI atom. Strong O—H...N hydrogen bonds form a C(5 chain around a 21 screw axis. Weak C—H—O hydrogen bonds are also present.

  16. Development of a System-Wide Program, Volume II : Stepwise Implementation of a Predation Index, Predator Control Fisheries and Evaluation Plan in the Columbia River Basin, 1992 Annual Report.

    Energy Technology Data Exchange (ETDEWEB)

    Ward, David L.; Nigro, Anthony A. (Oregon Department of Fish and Wildlife); Willis, Charles F. (S.P. Cramer and Associates., Gresham, OR)

    1994-06-01

    The authors report their results of studies to determine the extent to which northern squawfish predation on juvenile salmonids is a problem in the Columbia River Basin, and to evaluate how effectively fisheries can be used to control northern squawfish populations and reduce juvenile salmonid losses to predation. These studies were initiated as part of a basinwide program to control northern squawfish predation and reduce mortality of juvenile salmonids on their migration to the ocean. Three papers are included in this report. They are entitled: (1) Development of a Systemwide Predator Control Program: Indexing and Fisheries Evaluation; (2) Economic, Social and Legal Feasibility of Commercial Sport, and Bounty Fisheries on Northern Squawfish; (3) Columbia River Ecosystem Model (CREM): Modeling Approach for Evaluation of Control of Northern Squawfish Populations using Fisheries Exploitation.

  17. Solvent extraction of nitric acid,uranium(VI) and thorium(IV) by N,N,N',N'-tetrahexylsuccinylamide

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    A new kind of diamideN,N,N',N'-tetrahexylsuccinylamide (THSA)wassynthesized,characterized and used for the extraction of HNO3,U(VI) and Th(IV)in a diluent composed of 0.5 volume fraction1,2,4-trimethy benzene(TMB) and 0.5 volume fraction kerosene(OK).Extraction distribution coefficients of U(VI) and Th(IV) as functionsof aqueous nitric acid concentration, extractant concentration,temperature and salting-out agent (LiNO3) have been studied, and it is found that THSA as an extractant is superior to TBP for extraction ofU(VI) and Th(IV).Back extraction was also studied.At low acidity, themain adduct of THSA and HNO3 is HNO3.THSA.THSA.(HNO3)2 and THSA.(HNO3)3 are also found at high acidity.The compositions of extracted species, apparent equilibrium constants and enthalpies ofextraction reactions have also been calculated.

  18. Monitoring and Evaluation of Smolt Migration in the Columbia Basin : Volume XVI : Survival and Transportation Effects for Migrating Snake River Hatchery Chinook Salmon and Steelhead: Historical Estimates from 1996-2003.

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, Rebecca A.; Skalski, John R.

    2007-12-07

    In 2005, the University of Washington developed a new statistical model to analyze the combined juvenile and adult detection histories of PIT-tagged salmon migrating through the Federal Columbia River Power System (FCRPS). This model, implemented by software Program ROSTER (River-Ocean Survival and Transportation Effects Routine), has been used to estimate survival and transportation effects on large temporal and spatial scales for PIT-tagged hatchery spring and summer Chinook salmon and steelhead released in the Snake River Basin from 1996 to 2003. Those results are reported here. Annual estimates of the smolt-to-adult return ratio (SAR), juvenile inriver survival from Lower Granite to Bonneville, the ocean return probability from Bonneville to Bonneville, and adult upriver survival from Bonneville to Lower Granite are reported. Annual estimates of transport-inriver (T/I) ratios and differential post-Bonneville mortality (D) are reported on both a systemwide basis, incorporating all transport dams analyzed, and a dam-specific basis. Transportation effects are estimated only for dams where at least 5,000 tagged smolts were transported from a given upstream release group. Because few tagged hatchery steelhead were transported in these years, no transportation effects are estimated for steelhead. Performance measures include age-1-ocean adult returns for steelhead, but not for Chinook salmon. Annual estimates of SAR from Lower Granite back to Lower Granite averaged 0.71% with a standard error (SE) of 0.18% for spring Chinook salmon from the Snake River Basin for tagged groups released from 1996 through 2003, omitting age-1-ocean (jack) returns. For summer Chinook salmon from the Snake River Basin, the estimates of annual SAR averaged 1.15% (SE=0.31%). Only for the release years 1999 and 2000 did the Chinook SAR approach the target value of 2%, identified by the NPCC as the minimum SAR necessary for recovery. Annual estimates of SAR for hatchery steelhead from the

  19. Experience with Salmonella typhi Vi capsular polysaccharide vaccine.

    Science.gov (United States)

    Hessel, L; Debois, H; Fletcher, M; Dumas, R

    1999-09-01

    Typhoid fever remains an important health threat in many parts of the world, with an estimated 16 million cases and 600,000 deaths occurring each year. The emergence of Salmonella typhi strains multiply resistant to antibiotics has complicated the treatment of this disease. Field experience of 8 years shows that a vaccine composed of purified Vi capsular polysaccharide of Salmonella typhi, given as a single intramuscular or deep subcutaneous injection, has consistent immunogenicity and efficacy. Side effects, based on reports since 1989, are infrequent and mild. Furthermore, the Vi vaccine may be administered simultaneously with other common "travel" vaccines, at two different sites of injection, without affecting immunogenicity and tolerability. This review presents an update of the development and clinical experience with the Salmonella typhi Vi polysaccharide vaccine (Typhim Vi; Pasteur Mérieux Connaught, France).

  20. BIOSORPTION OF CR (VI BY RESTING CELLS OF ASPERGILLUS SP.

    Directory of Open Access Journals (Sweden)

    M. Sen , M. Ghosh Dastidar

    2007-01-01

    Full Text Available Biosorption of Cr(VI from aqueous solution was studied in a batch bioreactor using the resting cells of filamentous fungal biomass (Aspergillus sp. isolated from industrial wastewaters. The specific Cr(VI removal (mg/g of dried biomass decreased with increase in pH and increased with increase in initial Cr(VI concentration, upto 500 mg/L. By increasing biomass concentration from 2.4 to 5.2 g/L, the specific metal removal remained almost constant. The studies carried out by using the resting cells from various stages of growth indicated maximum Cr(VI removal of 34.8 mg/g using the biomass from the beginning of the stationary phase. The adsorption equilibrium constants Qº (42.9 mg/g and b (0.0091/mg were obtained from the Langmuir adsorption isotherm model.

  1. Mechanism of uranium (VI) removal by two anaerobic bacterial communities

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Monica [Centro de Ciencias do Mar, Universidade do Algarve, FCT-DQF (edificio 8), Campus de Gambelas, 8005-139 Faro (Portugal); Faleiro, Maria Leonor [IBB - Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, FCT, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, Ana M. Rosa da [Centro de Investigacao em Quimica do Algarve, Universidade do Algarve, FCT, DQF, Campus de Gambelas, 8005-139 Faro (Portugal); Chaves, Sandra; Tenreiro, Rogerio [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biodiversidade, Genomica Integrativa e Funcional (BioFIG), Campus de FCUL, Campo Grande, 1749-016 Lisboa (Portugal); Matos, Antonio Pedro [Servico de Anatomia Patologica, Hospital Curry Cabral, Lisboa (Portugal); Costa, Maria Clara, E-mail: mcorada@ualg.pt [Centro de Ciencias do Mar, Universidade do Algarve, FCT-DQF (edificio 8), Campus de Gambelas, 8005-139 Faro (Portugal)

    2010-12-15

    The mechanism of uranium (VI) removal by two anaerobic bacterial consortia, recovered from an uncontaminated site (consortium A) and other from an uranium mine (consortium U), was investigated. The highest efficiency of U (VI) removal by both consortia (97%) occurred at room temperature and at pH 7.2. Furthermore, it was found that U (VI) removal by consortium A occurred by enzymatic reduction and bioaccumulation, while the enzymatic process was the only mechanism involved in metal removal by consortium U. FTIR analysis suggested that after U (VI) reduction, U (IV) could be bound to carboxyl, phosphate and amide groups of bacterial cells. Phylogenetic analysis of 16S rRNA showed that community A was mainly composed by bacteria closely related to Sporotalea genus and Rhodocyclaceae family, while community U was mainly composed by bacteria related to Clostridium genus and Rhodocyclaceae family.

  2. ALTERATION OF U(VI)-PHASES UNDER OXIDIZING CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    A.P. Deditius; S. Utsunomiya; R.C. Ewing

    2006-02-21

    Uranium-(VI) phases are the primary alteration products of the UO{sub 2} in spent nuclear fuel and the UO{sub 2+x}, in natural uranium deposits. The U(VI)-phases generally form sheet structures of edge-sharing UO{sub 2}{sup 2+} polyhedra. The complexity of these structures offers numerous possibilities for coupled-substitutions of trace metals and radionuclides. The incorporation of radionuclides into U(VI)-structures provides a potential barrier to their release and transport in a geologic repository that experiences oxidizing conditions. In this study, we have used natural samples of UO{sub 2+x}, to study the U(VI)-phases that form during alteration and to determine the fate of the associated trace elements.

  3. Plan of propagation and communication experiments using ETS-VI

    Science.gov (United States)

    Ohmori, Shingo

    1988-01-01

    In 1992, an Engineering Test Satellite VI is scheduled to be launched by an H-II rocket. The missions of ETS-VI are to establish basic technologies of inter-satellite communications using millimeter waves and optical beams and fix satellite communications using multibeam antenna on board the satellite. Several kinds of frequency bands will be used for the communications missions. However, these frequencies can be used for propagation experiments.

  4. Recent Advances in Pharmaceutical Sciences VI

    OpenAIRE

    2016-01-01

    This E-book is the sixth volume of a series that compiles contributions from different areas of the multidisciplinary field of Pharmaceutical Sciences, particularly phisical chemistry, food science, toxicology, botany, biochemistry and molecular biology, preventive medicine and public health, pharmacology, physiology, microbiology, and parasitology.

  5. Study of Mo (VI Removal from Aqueous Solution: Application of Different Mathematical Models to Continuous Biosorption Data

    Directory of Open Access Journals (Sweden)

    Fatemeh Kafshgari

    2013-01-01

    Full Text Available Molybdenum (VI biosorption process was investigated by marine algae Cystoseria indica pretreated with 0.1 M CaCl2 solution in a packed bed column. The biosorbent was characterized by FTIR, BET and SEM analyses. The results showed that Mo (VI ions should be chelated with the hydroxyl, carboxyl and amine groups of the biomass. The effects of inlet metal concentration and flow rate on biosorption process were investigated and the experimental breakthrough curves were obtained. Results showed that the maximum biosorption capacity of Ca-pretreated C. indica for Mo (VI was found to be 18.32 mg/g at optimum flow rate of (1.4 mL/min. The controlled-rate step shifted from external to internal mass transfer limitations, as the flow rate increased. Also, it was observed that the breakthrough and exhaustion time decreased from 17.14 hr to 9.05 hr and from 0.006 h to 0.002 hr respectively, with the increase of flow rate from 0.7 to 2.1 ML/min. The increase in the initial concentration of Mo (VI solution from 30 to 95 ml min-1 increases the adsorption capacity from 18.32 to 30.19 mg/g and decreases the percentage of Mo (VI removal from 61 to 38%. Also, the treated volume was the greatest (1.42 L at the lowest inlet concentration. Column data obtained under different conditions were described using the Thomas, Yoon and Nelson, Yan and Belter models. The breakthrough curve predictions by Belter model were found to be very satisfactory.

  6. THE DIAGNOSTIC O VI ABSORPTION LINE IN DIFFUSE PLASMAS: COMPARISON OF NON-EQUILIBRIUM IONIZATION STRUCTURE SIMULATIONS TO FUSE DATA

    Energy Technology Data Exchange (ETDEWEB)

    De Avillez, Miguel A. [Department of Mathematics, University of Evora, R. Romao Ramalho 59, 7000 Evora (Portugal); Breitschwerdt, Dieter [Zentrum fuer Astronomie und Astrophysik, Technische Universitaet Berlin, Hardenbergstrasse 36, D-10623 Berlin (Germany)

    2012-12-20

    The nature of the interstellar O VI in the Galactic disk is studied by means of a multi-fluid hydrodynamical approximation, tracing the detailed time-dependent evolution of the ionization structure of the plasma. Our focus is to explore the signature of any non-equilibrium ionization condition present in the interstellar medium using the diagnostic O VI ion. A detailed comparison between the simulations and FUSE data is carried out by taking lines of sight (LOS) measurements through the simulated Galactic disk, covering an extent of 4 kpc from different vantage points. The simulation results bear a striking resemblance with the observations: (1) the N(O VI) distribution with distance and angle fall within the minimum and maximum values of the FUSE data; (2) the column density dispersion with distance is constant for all the LOS, showing a mild decrease at large distances; (3) O VI has a clumpy distribution along the LOS; and (4) the time-averaged midplane density for distances >400 pc has a value of (1.3-1.4) Multiplication-Sign 10{sup -8} cm{sup -3}. The highest concentration of O VI by mass occurs in the thermally stable (10{sup 3.9} K < T {<=} 10{sup 4.2} K; 20%) and unstable (10{sup 4.2} K < T < 10{sup 5} K; 50%) regimes, both well below its peak temperature in collisional ionization equilibrium, with the corresponding volume filling factors oscillating with time between 8%-20% and 4%-5%, respectively. These results may also be relevant for intergalactic metal absorption systems at high redshifts.

  7. Study of Mo (VI) removal from aqueous solution: application of different mathematical models to continuous biosorption data.

    Science.gov (United States)

    Kafshgari, Fatemeh; Keshtkar, Ali Reza; Mousavian, Mohammad Ali

    2013-01-25

    Molybdenum (VI) biosorption process was investigated by marine algae Cystoseria indica pretreated with 0.1 M CaCl2 solution in a packed bed column. The biosorbent was characterized by FTIR, BET and SEM analyses. The results showed that Mo (VI) ions should be chelated with the hydroxyl, carboxyl and amine groups of the biomass. The effects of inlet metal concentration and flow rate on biosorption process were investigated and the experimental breakthrough curves were obtained. Results showed that the maximum biosorption capacity of Ca-pretreated C. indica for Mo (VI) was found to be 18.32 mg/g at optimum flow rate of (1.4 mL/min). The controlled-rate step shifted from external to internal mass transfer limitations, as the flow rate increased. Also, it was observed that the breakthrough and exhaustion time decreased from 17.14 hr to 9.05 hr and from 0.006 h to 0.002 hr respectively, with the increase of flow rate from 0.7 to 2.1 ML/min. The increase in the initial concentration of Mo (VI) solution from 30 to 95 ml min-1 increases the adsorption capacity from 18.32 to 30.19 mg/g and decreases the percentage of Mo (VI) removal from 61 to 38%. Also, the treated volume was the greatest (1.42 L) at the lowest inlet concentration. Column data obtained under different conditions were described using the Thomas, Yoon and Nelson, Yan and Belter models. The breakthrough curve predictions by Belter model were found to be very satisfactory.

  8. Study of Mo (VI removal from aqueous solution: application of different mathematical models to continuous biosorption data

    Directory of Open Access Journals (Sweden)

    Kafshgari Fatemeh

    2013-01-01

    Full Text Available Abstract Molybdenum (VI biosorption process was investigated by marine algae Cystoseria indica pretreated with 0.1 M CaCl2 solution in a packed bed column. The biosorbent was characterized by FTIR, BET and SEM analyses. The results showed that Mo (VI ions should be chelated with the hydroxyl, carboxyl and amine groups of the biomass. The effects of inlet metal concentration and flow rate on biosorption process were investigated and the experimental breakthrough curves were obtained. Results showed that the maximum biosorption capacity of Ca-pretreated C. indica for Mo (VI was found to be 18.32 mg/g at optimum flow rate of (1.4 mL/min. The controlled-rate step shifted from external to internal mass transfer limitations, as the flow rate increased. Also, it was observed that the breakthrough and exhaustion time decreased from 17.14 hr to 9.05 hr and from 0.006 h to 0.002 hr respectively, with the increase of flow rate from 0.7 to 2.1 ML/min. The increase in the initial concentration of Mo (VI solution from 30 to 95 ml min-1 increases the adsorption capacity from 18.32 to 30.19 mg/g and decreases the percentage of Mo (VI removal from 61 to 38%. Also, the treated volume was the greatest (1.42 L at the lowest inlet concentration. Column data obtained under different conditions were described using the Thomas, Yoon and Nelson, Yan and Belter models. The breakthrough curve predictions by Belter model were found to be very satisfactory.

  9. Vi har intet lært - hvornår lærer vi det?

    DEFF Research Database (Denmark)

    Sodemann, Morten

    2016-01-01

    WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en kerneakti......WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en...

  10. Progress in Ultrafast Intense Laser Science VI

    CERN Document Server

    Yamanouchi, Kaoru; Bandrauk, André D

    2010-01-01

    The PUILS series delivers up-to-date reviews of progress in Ultrafast Intense Laser Science, a newly emerging interdisciplinary research field spanning atomic and molecular physics, molecular science, and optical science, which has been stimulated by the recent developments in ultrafast laser technologies. Each volume compiles peer-reviewed articles authored by researchers at the forefront of each their own subfields of UILS. Every chapter opens with an overview of the topics to be discussed, so that researchers unfamiliar to the subfield, as well as graduate students, can grasp the importance and attractions of the research topic at hand; these are followed by reports of cutting-edge discoveries. This sixth volume covers a broad range of topics from this interdisciplinary research field, focusing on responses of molecules to ultrashort intense laser pulses, generation and characterization of attosecond pulses and high-order harmonics, and filamentation and laser-plasma interaction.

  11. Price-volume multifractal analysis and its application in Chinese stock markets

    Science.gov (United States)

    Yuan, Ying; Zhuang, Xin-tian; Liu, Zhi-ying

    2012-06-01

    An empirical research on Chinese stock markets is conducted using statistical tools. First, the multifractality of stock price return series, ri(ri=ln(Pt+1)-ln(Pt)) and trading volume variation series, vi(vi=ln(Vt+1)-ln(Vt)) is confirmed using multifractal detrended fluctuation analysis. Furthermore, a multifractal detrended cross-correlation analysis between stock price return and trading volume variation in Chinese stock markets is also conducted. It is shown that the cross relationship between them is also found to be multifractal. Second, the cross-correlation between stock price Pi and trading volume Vi is empirically studied using cross-correlation function and detrended cross-correlation analysis. It is found that both Shanghai stock market and Shenzhen stock market show pronounced long-range cross-correlations between stock price and trading volume. Third, a composite index R based on price and trading volume is introduced. Compared with stock price return series ri and trading volume variation series vi, R variation series not only remain the characteristics of original series but also demonstrate the relative correlation between stock price and trading volume. Finally, we analyze the multifractal characteristics of R variation series before and after three financial events in China (namely, Price Limits, Reform of Non-tradable Shares and financial crisis in 2008) in the whole period of sample to study the changes of stock market fluctuation and financial risk. It is found that the empirical results verified the validity of R.

  12. Uranium(VI) reduction by iron(II) monosulfide mackinawite.

    Science.gov (United States)

    Hyun, Sung Pil; Davis, James A; Sun, Kai; Hayes, Kim F

    2012-03-20

    Reaction of aqueous uranium(VI) with iron(II) monosulfide mackinawite in an O(2) and CO(2) free model system was studied by batch uptake measurements, equilibrium modeling, and L(III) edge U X-ray absorption spectroscopy (XAS). Batch uptake measurements showed that U(VI) removal was almost complete over the wide pH range between 5 and 11 at the initial U(VI) concentration of 5 × 10(-5) M. Extraction by a carbonate/bicarbonate solution indicated that most of the U(VI) removed from solution was reduced to nonextractable U(IV). Equilibrium modeling using Visual MINTEQ suggested that U was in equilibrium with uraninite under the experimental conditions. X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopy showed that the U(IV) phase associated with mackinawite was uraninite. Oxidation experiments with dissolved O(2) were performed by injecting air into the sealed reaction bottles containing mackinawite samples reacted with U(VI). Dissolved U measurement and XAS confirmed that the uraninite formed from the U(VI) reduction by mackinawite did not oxidize or dissolve under the experimental conditions. This study shows that redox reactions between U(VI) and mackinawite may occur to a significant extent, implying an important role of the ferrous sulfide mineral in the redox cycling of U under sulfate reducing conditions. This study also shows that the presence of mackinawite protects uraninite from oxidation by dissolved O(2). The findings of this study suggest that uraninite formation by abiotic reduction by the iron sulfide mineral under low temperature conditions is an important process in the redistribution and sequestration of U in the subsurface environments at U contaminated sites.

  13. Molecular evolution of type VI intermediate filament proteins

    Directory of Open Access Journals (Sweden)

    Vincent Michel

    2007-09-01

    Full Text Available Abstract Background Tanabin, transitin and nestin are type VI intermediate filament (IF proteins that are developmentally regulated in frogs, birds and mammals, respectively. Tanabin is expressed in the growth cones of embryonic vertebrate neurons, whereas transitin and nestin are found in myogenic and neurogenic cells. Another type VI IF protein, synemin, is expressed in undifferentiated and mature muscle cells of birds and mammals. In addition to an IF-typical α-helical core domain, type VI IF proteins are characterized by a long C-terminal tail often containing distinct repeated motifs. The molecular evolution of type VI IF proteins remains poorly studied. Results To examine the evolutionary history of type VI IF proteins, sequence comparisons, BLAST searches, synteny studies and phylogenic analyses were performed. This study provides new evidence that tanabin, transitin and nestin are indeed orthologous type VI IF proteins. It demonstrates that tanabin, transitin and nestin genes share intron positions and sequence identities, have a similar chromosomal context and display closely related positions in phylogenic analyses. Despite this homology, fast evolution rates of their C-terminal extremity have caused the appearance of repeated motifs with distinct biological activities. In particular, our in silico and in vitro analyses of their tail domain have shown that (avian transitin, but not (mammalian nestin, contains a repeat domain displaying nucleotide hydrolysis activity. Conclusion These analyses of the evolutionary history of the IF proteins fit with a model in which type VI IFs form a branch distinct from NF proteins and are composed of two major proteins: synemin and nestin orthologs. Rapid evolution of the C-terminal extremity of nestin orthologs could be responsible for their divergent functions.

  14. Monitoring and Evaluation of Smolt Migration in the Columbia Basin : Volume XVIII: Survival and Transportation Effects of Migrating Snake River Wild Chinook Salmon and Steelhead: Historical Estimates From 1996-2004 and Comparison to Hatchery Results. Draft.

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, Rebecca A.; Skalski, John R.; Broms, Kristin

    2008-12-03

    The combined juvenile and adult detection histories of PIT-tagged wild salmonids migrating through the Federal Columbia River Power System (FCRPS) were analyzed using the ROSTER (River-Ocean Survival and Transportation Effects Routine) statistical release-recapture model. This model, implemented by software Program ROSTER, was used to estimate survival on large temporal and spatial scales for PIT-tagged wild spring and summer Chinook salmon and steelhead released in the Snake River Basin upstream of Lower Granite Dam from 1996 to 2004. In addition, annual results from wild salmonids were compared with results from hatchery salmonids, which were presented in a previous report in this series (Buchanan, R. A., Skalski, J. R., Lady, J. L., Westhagen, P., Griswold, J., and Smith, S. 2007, 'Survival and Transportation Effects for Migrating Snake River Hatchery Chinook Salmon and Steelhead: Historical Estimates from 1996-2003', Technical report, Bonneville Power Administration, Project 1991-051-00). These results are reported here. Annual estimates of the smolt-to-adult return ratio (SAR), juvenile inriver survival from Lower Granite to Bonneville, the ocean return probability from Bonneville to Bonneville, and adult upriver survival from Bonneville to Lower Granite are reported. Annual estimates of transport-inriver (T/I) ratios and differential post-Bonneville mortality (D) are reported on a dam-specific basis for release years with sufficient numbers of wild PIT-tagged smolts transported. Transportation effects are estimated only for dams where at least 1,000 tagged wild smolts were transported from a given upstream release group. Because few wild Chinook salmon and steelhead tagged upstream of Lower Granite Dam were transported before the 2003 release year, T/I and D were estimated only for the 2003 and 2004 release years. Performance measures include age-1-ocean adult returns for steelhead, but not for Chinook salmon. Spring and summer Chinook salmon

  15. Monitoring and Evaluation of Smolt Migration in the Columbia Basin : Volume XVIII: Survival and Transportation Effects of Migrating Snake River Wild Chinook Salmon and Steelhead: Historical Estimates From 1996-2004 and Comparison to Hatchery Results. Draft.

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, Rebecca A.; Skalski, John R.; Broms, Kristin

    2008-12-03

    The combined juvenile and adult detection histories of PIT-tagged wild salmonids migrating through the Federal Columbia River Power System (FCRPS) were analyzed using the ROSTER (River-Ocean Survival and Transportation Effects Routine) statistical release-recapture model. This model, implemented by software Program ROSTER, was used to estimate survival on large temporal and spatial scales for PIT-tagged wild spring and summer Chinook salmon and steelhead released in the Snake River Basin upstream of Lower Granite Dam from 1996 to 2004. In addition, annual results from wild salmonids were compared with results from hatchery salmonids, which were presented in a previous report in this series (Buchanan, R. A., Skalski, J. R., Lady, J. L., Westhagen, P., Griswold, J., and Smith, S. 2007, 'Survival and Transportation Effects for Migrating Snake River Hatchery Chinook Salmon and Steelhead: Historical Estimates from 1996-2003', Technical report, Bonneville Power Administration, Project 1991-051-00). These results are reported here. Annual estimates of the smolt-to-adult return ratio (SAR), juvenile inriver survival from Lower Granite to Bonneville, the ocean return probability from Bonneville to Bonneville, and adult upriver survival from Bonneville to Lower Granite are reported. Annual estimates of transport-inriver (T/I) ratios and differential post-Bonneville mortality (D) are reported on a dam-specific basis for release years with sufficient numbers of wild PIT-tagged smolts transported. Transportation effects are estimated only for dams where at least 1,000 tagged wild smolts were transported from a given upstream release group. Because few wild Chinook salmon and steelhead tagged upstream of Lower Granite Dam were transported before the 2003 release year, T/I and D were estimated only for the 2003 and 2004 release years. Performance measures include age-1-ocean adult returns for steelhead, but not for Chinook salmon. Spring and summer Chinook salmon

  16. Immunohistochemical expression of type VI collagen in superficial fibromatoses.

    Science.gov (United States)

    Magro, G; Colombatti, A; Lanzafame, S

    1995-10-01

    The expression of type VI collagen was studied immunohistochemically in 26 cases of superficial fibromatoses (palmar, plantar and penile) using an immunoperoxidase method for light microscopic visualization. The polyclonal antibody against type VI collagen used in this study was isolated from human placenta and its specifity was tested by immunoblotting assay. All cases consisted of multiple nodules showing a variable degree of cellularity and fibrosis. Depending on the predominant histological appearance of these nodules, each case was assigned to the three following phases: proliferative, involutional and residual. Morphologically normal palmar and plantar aponeuroses were included as controls. Immunohistochemical findings showed that type VI collagen was present as longitudinal thin fibers in normal palmar and plantar aponeuroses. A differential expression of this collagen was found in the different stages of superficial fibromatoses. Type VI collagen was markedly expressed as a distinct fibrillar network in the extracellular matrix (ECM) surrounding proliferating stromal cells in proliferative and involutional phases. Its expression completely disappeared from the connective tissue undergoing fibrotic transformation during involutional and residual phases. The results of the present study suggest that type VI collagen is an extracellular marker of stromal tissue proliferation and is involved in the early phases of tissue remodelling occurring in the superficial fibromatoses.

  17. Treatment of combined sewer overflows using ferrate (VI).

    Science.gov (United States)

    Gandhi, Rohan; Ray, Ajay K; Sharma, Virender K; Nakhla, George

    2014-11-01

    This paper presents the results of a study conducted on the treatment of combined sewer overflows using ferrate (VI) [Fe (VI)]. At a Fe (VI) dose of 0.24 mg/L, total chemical oxygen demand (TCOD), soluble chemical oxygen demand (SCOD), total biochemical oxygen demand (TBOD5), soluble biochemical oxygen demand (SBOD5), total suspended solids (TSS), volatile suspended solids (VSS), total phosphorus (TP), total nitrogen (TN), and soluble TN removal efficiencies of 71, 75, 69, 68, 72, 83, 64, 38, and 36%, respectively, were achieved. Kinetic studies revealed that a contact time of only 15 minutes is sufficient to achieve secondary effluent criteria. An innovative technique of using primary sludge (PS) and thickened waste activated sludge as a source for the in situ synthesis of ferrate was developed. A comparative study of treatment efficiencies achieved by Fe (VI) generated from different sources was done. At 0.1 mg/L dose of Fe (VI) synthesized from PS, TCOD, SCOD, TSS, VSS, TP, and TN removal efficiencies of 60, 62, 63, 67, 30, and 25%, respectively, were achieved.

  18. Biosorption of aqueous chromium(VI) by Tamarindus indica seeds.

    Science.gov (United States)

    Agarwal, G S; Bhuptawat, Hitendra Kumar; Chaudhari, Sanjeev

    2006-05-01

    The effectiveness of low cost agro-based materials namely, Tamarindus indica seed (TS), crushed coconut shell (CS), almond shell (AS), ground nut shell (GS) and walnut shell (WS) were evaluated for Cr(VI) removal. Batch test indicated that hexavalent chromium sorption capacity (q(e)) followed the sequence q(e)(TS) > q(e)(WS) > q(e)(AS) > q(e)(GS) > q(e)(CS). Due to high sorptive capacity, tamarind seed was selected for detailed sorption studies. Sorption kinetic data followed first order reversible kinetic fit model for all the sorbents. The equilibrium conditions were achieved within 150 min under the mixing conditions employed. Sorption equilibria exhibited better fit to Freundlich isotherms (R>0.92) than Langmuir isotherm (R approximately = 0.87). Hexavalent chromium sorption by TS decreased with increase in pH, and slightly reduced with increase in ionic strength. Cr(VI) removal by TS seems to be mainly by chemisorption. Desorption of Cr(VI) from Cr(VI) laden TS was quite less by distilled water and HCl. Whereas with NaOH, maximum desorption achieved was about 15.3%. When TS was used in downflow column mode, Cr(VI) removal was quite good but head loss increased as the run progressed and was stopped after 200 h.

  19. Cr(VI) uptake mechanism of Bacillus cereus.

    Science.gov (United States)

    Chen, Zhi; Huang, Zhipeng; Cheng, Yangjian; Pan, Danmei; Pan, Xiaohong; Yu, Meijuan; Pan, Zhiyun; Lin, Zhang; Guan, Xiong; Wu, Ziyu

    2012-04-01

    In this study, we investigated the Cr(VI) uptake mechanism in an indigenous Cr(VI)-tolerant bacterial strain -Bacillus cereus through batch and microscopic experiments. We found that both the cells and the supernatant collected from B. cereus cultivation could reduce Cr(VI). The valence state analysis revealed the complete transformation from Cr(VI) into Cr(III) by living B. cereus. Further X-ray absorption fine structure and Fourier transform infrared analyses showed that the reduced Cr(III) was coordinated with carboxyl and amido functional groups from either the cells or supernatant. Scanning electron microscopy and atomic force microscopy observation showed that noticeable Cr(III) precipitates were accumulated on bacterial surfaces. However, Cr(III) could also be detected in bacterial inner portions by using transmission electron microscopy thin section analysis coupled with energy dispersive X-ray spectroscopy. Through quantitative analysis of chromium distribution, we determined the binding ratio of Cr(III) in supernatant, cell debris and cytoplasm as 22%, 54% and 24%, respectively. Finally, we further discussed the role of bacterium-origin soluble organic molecules to the remediation of Cr(VI) pollutants.

  20. Advanced Workflows for Fluid Transfer in Faulted Basins

    Directory of Open Access Journals (Sweden)

    Thibaut Muriel

    2014-07-01

    Full Text Available The traditional 3D basin modeling workflow is made of the following steps: construction of present day basin architecture, reconstruction of the structural evolution through time, together with fluid flow simulation and heat transfers. In this case, the forward simulation is limited to basin architecture, mainly controlled by erosion, sedimentation and vertical compaction. The tectonic deformation is limited to vertical slip along faults. Fault properties are modeled as vertical shear zones along which rock permeability is adjusted to enhance fluid flow or prevent flow to escape. For basins having experienced a more complex tectonic history, this approach is over-simplified. It fails in understanding and representing fluid flow paths due to structural evolution of the basin. This impacts overpressure build-up, and petroleum resources location. Over the past years, a new 3D basin forward code has been developed in IFP Energies nouvelles that is based on a cell centered finite volume discretization which preserves mass on an unstructured grid and describes the various changes in geometry and topology of a basin through time. At the same time, 3D restoration tools based on geomechanical principles of strain minimization were made available that offer a structural scenario at a discrete number of deformation stages of the basin. In this paper, we present workflows integrating these different innovative tools on complex faulted basin architectures where complex means moderate lateral as well as vertical deformation coupled with dynamic fault property modeling. Two synthetic case studies inspired by real basins have been used to illustrate how to apply the workflow, where the difficulties in the workflows are, and what the added value is compared with previous basin modeling approaches.

  1. Modeling Fluid Flow in Faulted Basins

    Directory of Open Access Journals (Sweden)

    Faille I.

    2014-07-01

    Full Text Available This paper presents a basin simulator designed to better take faults into account, either as conduits or as barriers to fluid flow. It computes hydrocarbon generation, fluid flow and heat transfer on the 4D (space and time geometry obtained by 3D volume restoration. Contrary to classical basin simulators, this calculator does not require a structured mesh based on vertical pillars nor a multi-block structure associated to the fault network. The mesh follows the sediments during the evolution of the basin. It deforms continuously with respect to time to account for sedimentation, erosion, compaction and kinematic displacements. The simulation domain is structured in layers, in order to handle properly the corresponding heterogeneities and to follow the sedimentation processes (thickening of the layers. In each layer, the mesh is unstructured: it may include several types of cells such as tetrahedra, hexahedra, pyramid, prism, etc. However, a mesh composed mainly of hexahedra is preferred as they are well suited to the layered structure of the basin. Faults are handled as internal boundaries across which the mesh is non-matching. Different models are proposed for fault behavior such as impervious fault, flow across fault or conductive fault. The calculator is based on a cell centered Finite Volume discretisation, which ensures conservation of physical quantities (mass of fluid, heat at a discrete level and which accounts properly for heterogeneities. The numerical scheme handles the non matching meshes and guaranties appropriate connection of cells across faults. Results on a synthetic basin demonstrate the capabilities of this new simulator.

  2. Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report

    Energy Technology Data Exchange (ETDEWEB)

    John F. Stolz

    2011-06-15

    A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory

  3. Characterizing particle-scale equilibrium adsorption and kinetics of uranium(VI) desorption from U-contaminated sediments

    Science.gov (United States)

    Stoliker, Deborah L.; Liu, Chongxuan; Kent, Douglas B.; Zachara, John M.

    2013-01-01

    Rates of U(VI) release from individual dry-sieved size fractions of a field-aggregated, field-contaminated composite sediment from the seasonally saturated lower vadose zone of the Hanford 300-Area were examined in flow-through reactors to maintain quasi-constant chemical conditions. The principal source of variability in equilibrium U(VI) adsorption properties of the various size fractions was the impact of variable chemistry on adsorption. This source of variability was represented using surface complexation models (SCMs) with different stoichiometric coefficients with respect to hydrogen ion and carbonate concentrations for the different size fractions. A reactive transport model incorporating equilibrium expressions for cation exchange and calcite dissolution, along with rate expressions for aerobic respiration and silica dissolution, described the temporal evolution of solute concentrations observed during the flow-through reactor experiments. Kinetic U(VI) desorption was well described using a multirate SCM with an assumed lognormal distribution for the mass-transfer rate coefficients. The estimated mean and standard deviation of the rate coefficients were the same for all <2 mm size fractions but differed for the 2–8 mm size fraction. Micropore volumes, assessed using t-plots to analyze N2 desorption data, were also the same for all dry-sieved <2 mm size fractions, indicating a link between micropore volumes and mass-transfer rate properties. Pore volumes for dry-sieved size fractions exceeded values for the corresponding wet-sieved fractions. We hypothesize that repeated field wetting and drying cycles lead to the formation of aggregates and/or coatings containing (micro)pore networks which provided an additional mass-transfer resistance over that associated with individual particles. The 2–8 mm fraction exhibited a larger average and standard deviation in the distribution of mass-transfer rate coefficients, possibly caused by the abundance of

  4. THE SIGNIFICANT FLASH FLOODS IN VIȘEU RIVER BASIN, ROMANIA. CAUSES AND EFFECTS ON THE FLOODPLAIN

    Directory of Open Access Journals (Sweden)

    SIMA A.

    2015-03-01

    Full Text Available Vișeu’s river basin location and morphometry has offered, over the course of time, favourable conditions to the formation of different types of floods. Their increase over the last time due to climate change and chaotic anthropic activities has led to visible changes of the morphology of the floodplain. The present paper analyses the genetic factors, the significant floods and in particular, the impact of these floods on the floodplain of Vișeu river and its main tributaries, Ruscova, Vaser and Țâșla.

  5. Phase transitions in Group III-V and II-VI semiconductors at high pressure

    Science.gov (United States)

    Yu, S. C.; Liu, C. Y.; Spain, I. L.; Skelton, E. F.

    1979-01-01

    The structures and transition pressures of Group III-V and II-VI semiconductors and of a pseudobinary system (Ga/x/In/1-x/Sb) have been investigated. Results indicate that GaP, InSb, GaSb, GaAs and possible AlP assume Metallic structures at high pressures; a tetragonal, beta-Sn-like structure is adopted by only InSb and GaSb. The rocksalt phase is preferred in InP, InAs, AlSb, ZnO and ZnS. The model of Van Vechten (1973) gives transition pressures which are in good agreement with measured values, but must be refined to account for the occurrence of the ionic rocksalt structure in some compounds. In addition, discrepancies between the theoretical scaling values for volume changes at the semiconductor-to-metal transitions are observed.

  6. Painlev\\'e VI connection problem and monodromy of c=1 conformal blocks

    CERN Document Server

    Iorgov, N; Tykhyy, Yu

    2013-01-01

    Generic c=1 four-point conformal blocks on the Riemann sphere can be seen as the coefficients of Fourier expansion of the tau function of Painlev\\'e VI equation with respect to one of its integration constants. Based on this relation, we show that c=1 fusion matrix essentially coincides with the connection coefficient relating tau function asymptotics at different critical points. Explicit formulas for both quantities are obtained by solving certain functional relations which follow from the tau function expansions. The final result does not involve integration and is given by a ratio of two products of Barnes G-functions with arguments expressed in terms of conformal dimensions/monodromy data. It turns out to be closely related to the volume of hyperbolic tetrahedron.

  7. Interface control of electronic and optical properties in IV-VI and II-VI core/shell colloidal quantum dots: a review.

    Science.gov (United States)

    Jang, Youngjin; Shapiro, Arthur; Isarov, Maya; Rubin-Brusilovski, Anna; Safran, Aron; Budniak, Adam K; Horani, Faris; Dehnel, Joanna; Sashchiuk, Aldona; Lifshitz, Efrat

    2017-01-17

    Semiconductor colloidal quantum dots (CQDs) have attracted vast scientific and technological interest throughout the past three decades, due to the unique tuneability of their optoelectronic properties by variation of size and composition. However, the nanoscale size brings about a large surface-to-bulk volume ratio, where exterior surfaces have a pronounced influence on the chemical stability and on the physical properties of the semiconductor. Therefore, numerous approaches have been developed to gain efficient surface passivation, including a coverage by organic or inorganic molecular surfactants as well as the formation of core/shell heterostructures (a semiconductor core epitaxially covered by another semiconductor shell). This review focuses on special designs of core/shell heterostructures from the IV-VI and II-VI semiconductor compounds, and on synthetic approaches and characterization of the optical properties. Experimental observations revealed the formation of core/shell structures with type-I or quasi-type-II band alignment between the core and shell constituents. Theoretical calculations of the electronic band structures, which were also confirmed by experimental work, exposed surplus electronic tuning (beyond the radial diameter) with adaptation of the composition and control of the interface properties. The studies also considered strain effects that are created between two different semiconductors. It was disclosed experimentally and theoretically that the strain can be released via the formation of alloys at the core-shell interface. Overall, the core/shell and core/alloyed-shell heterostructures showed enhancement in luminescence quantum efficiency with respect to that of pure cores, extended lifetime, uniformity in size and in many cases good chemical sustainability under ambient conditions.

  8. 夏季加拿大海盆海冰边缘区声体积后向散射强度研究%Study on volume backscattering strength in summer marginal ice zone of Canada Basin

    Institute of Scientific and Technical Information of China (English)

    刘洪宁; 吕连港; 刘娜; 杨光兵; 姜莹; 杨春梅; 刘宗伟; 林丽娜

    2015-01-01

    Volume backscatter strength (Sv)is a key parameter for acoustic transmission.Study on volume back-scattering strength in marginal ice zone (MIZ)in the Arctic plays an important role in the knowledge of the Arctic acoustic environment.Based on the investigation during the Sixth Chinese National Arctic Research Expedition in summer 2014,the characteristics of backscatter strength in MIZ are analyzed.The results show that Sv under the open water (ice concentration less than 15%)is significantly higher than that in seawater under the packed ice (ice concentration more than 50%).Ice melt causes increasing of opaque creatures and suspended sediment,and leads to increase of Sv.According to the characteristics of low Sv under the packed ice,the proposal about the parameters of LADCP setting is given.%声信号的体积后向散射强度是声传播过程中一个关键的参数。海冰边缘区的声体积后向散射强度研究对深入认识北极声场环境有着十分重要的意义。本文利用中国第六次北极科学考察获取的数据资料研究了海冰边缘区声体积后向散射强度特性。结果表明:加拿大海盆海冰边缘区是声体积后向散射强度的明显过渡区。无冰海面(海冰密集度小于15%)海洋深层水的声体积后向散射强度明显大于密集海冰区域的海水(海冰密集度大于50%)。讨论了声体积后向散射强度与海冰融化之间的关系,造成融冰区声体积后向散射强度增大的原因是水下悬浮泥沙、浮游生物等悬浮物质增加。根据海冰密集海域的海水后向散射强度弱的特点,对北极下放式声学多普勒测流仪(LADCP)观测的设置提出建议。

  9. Apollonius de Perge, Coniques tome 4, livres VI et VII

    CERN Document Server

    Rashed, Roshdi

    2009-01-01

    Book VI of the Konika is essentially devoted to the question of the identity and similarity of two conic sections, or two parts of conic sections. In Book VII Apollonius deals with the various relationships between the lengths of diameters and conjugate diameters. The results are applied to the exposition of a number of problems, as well as to some problems which Apollonius indicates will be demonstrated and solved in Book VIII, which was lost in Antiquity. Books VI and VII have only survived in an Arabic translation, and are presented here in a critical edition, together with a faithful trans

  10. GIS Analysis of Size Relationships between Drainage Basins and Alluvial Fans

    Science.gov (United States)

    Wright, S. N.; Scuderi, L. A.; Weissmann, G. S.; Hartley, A. J.

    2014-12-01

    Imagery from the global database of modern sedimentary basins compiled by Weissman et al. (2010) allows us to test whether a size relationship between drainage basin area and distributive fluvial system (DFS) area exists. We are testing this hypothesis using a combination of SRTM-based digital elevation models and Landsat satellite imagery in ArcGIS. Sedimentary basins are delineated by preforming a Gaussian smoothing on the DEM, followed by optimal edge detection through application of a modified Canny edge detector. The pour points defining the link between contributing hydrologic basins and these sedimentary basins are then located by generating a stream network in ArcGIS and intersecting the stream network arcs with the sedimentary basin polygons. From these pour points we delineate the adjacent contributing drainage basin using the watershed tool in ArcGIS. We manually digitize the boundary and geometry of the DFS identified for each drainage basin, using the higher resolution imagery found on Google Earth for visual confirmation if the scale or resolution of the Landsat imagery requires it. We then extract drainage basins and DFS polygon parameters and calculate areal extents in order to evaluate whether such a size relationship exists within basins, regionally across several basins, or across different basin types (e.g., endorheic vs exhoreic). A limitation of this approach is that we cannot evaluate sediment volumes, only aerial coverage. Results from this study may provide a better understanding of extrabasinal processes that control DFS shape and size.

  11. VI Latin American Congress on Biomedical Engineering

    CERN Document Server

    Hadad, Alejandro

    2015-01-01

    This volume presents the proceedings of the CLAIB 2014, held in Paraná, Entre Ríos, Argentina 29, 30 & 31 October 2014. The proceedings, presented by the Regional Council of Biomedical Engineering for Latin America (CORAL) offer research findings, experiences and activities between institutions and universities to develop Bioengineering, Biomedical Engineering and related sciences. The conferences of the American Congress of Biomedical Engineering are sponsored by the International Federation for Medical and Biological Engineering (IFMBE), Society for Engineering in Biology and Medicine (EMBS) and the Pan American Health Organization (PAHO), among other organizations and international agencies and bringing together scientists, academics and biomedical engineers in Latin America and other continents in an environment conducive to exchange and professional growth. The Topics include: - Bioinformatics and Computational Biology - Bioinstrumentation; Sensors, Micro and Nano Technologies - Biomaterials, Tissu...

  12. Reserves in western basins

    Energy Technology Data Exchange (ETDEWEB)

    Caldwell, R.H.; Cotton, B.W. [Scotia Group, Dallas, TX (United States)

    1995-04-01

    The objective of this project is to investigate the reserves potential of tight gas reservoirs in three Rocky Mountain basins: the Greater Green River (GGRB), Uinta and Piceance basins. The basins contain vast gas resources that have been estimated in the thousands of Tcf hosted in low permeability clastic reservoirs. This study documents the productive characteristics of these tight reservoirs, requantifies gas in place resources, and characterizes the reserves potential of each basin. The purpose of this work is to promote understanding of the resource and to encourage its exploitation by private industry. At this point in time, the GGRB work has been completed and a final report published. Work is well underway in the Uinta and Piceance basins which are being handled concurrently, with reports on these basins being scheduled for the middle of this year. Since the GGRB portion of the project has been completed, this presentation win focus upon that basin. A key conclusion of this study was the subdivision of the resource, based upon economic and technological considerations, into groupings that have distinct properties with regard to potential for future producibility, economics and risk profile.

  13. GEOCHEMICAL MODELING OF F AREA SEEPAGE BASIN COMPOSITION AND VARIABILITY

    Energy Technology Data Exchange (ETDEWEB)

    Millings, M.; Denham, M.; Looney, B.

    2012-05-08

    affecting basin chemistry and variability included: (1) the nature or chemistry of the waste streams, (2) the open system of the basins, and (3) duration of discharge of the waste stream types. Mixing models of the archetype waste streams indicated that the overall basin system would likely remain acidic much of the time. Only an extended periods of predominantly alkaline waste discharge (e.g., >70% alkaline waste) would dramatically alter the average pH of wastewater entering the basins. Short term and long term variability were evaluated by performing multiple stepwise modeling runs to calculate the oscillation of bulk chemistry in the basins in response to short term variations in waste stream chemistry. Short term (1/2 month and 1 month) oscillations in the waste stream types only affected the chemistry in Basin 1; little variation was observed in Basin 2 and 3. As the largest basin, Basin 3 is considered the primary source to the groundwater. Modeling showed that the fluctuation in chemistry of the waste streams is not directly representative of the source term to the groundwater (i.e. Basin 3). The sequence of receiving basins and the large volume of water in Basin 3 'smooth' or nullify the short term variability in waste stream composition. As part of this study, a technically-based 'charge-balanced' nominal source term chemistry was developed for Basin 3 for a narrow range of pH (2.7 to 3.4). An example is also provided of how these data could be used to quantify uncertainty over the long term variations in waste stream chemistry and hence, Basin 3 chemistry.

  14. The transition from complex crater to peak-ring basin on Mercury: New observations from MESSENGER flyby data and constraints on basin formation models

    Science.gov (United States)

    Baker, David M. H.; Head, James W.; Schon, Samuel C.; Ernst, Carolyn M.; Prockter, Louise M.; Murchie, Scott L.; Denevi, Brett W.; Solomon, Sean C.; Strom, Robert G.

    2011-12-01

    suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. The relationship between impact-melt production and peak-ring formation is strengthened further by agreement between power laws fit to ratios of ring diameter to rim-crest diameter for peak-ring basins and protobasins and the power-law relation between the dimension of a melt cavity and the crater diameter. More detailed examination of Mercury's peak-ring basins awaits the planned insertion of the MESSENGER spacecraft into orbit about Mercury in 2011.

  15. Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization.

    Science.gov (United States)

    Cao, Bin; Ahmed, Bulbul; Kennedy, David W; Wang, Zheming; Shi, Liang; Marshall, Matthew J; Fredrickson, Jim K; Isern, Nancy G; Majors, Paul D; Beyenal, Haluk

    2011-07-01

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.

  16. Cultural Resources Survey, Harry S. Truman Dam and Reservoir Project, Missouri. Volume 4. The Archeological Survey

    Science.gov (United States)

    1983-02-01

    River Sac River Pomme de Terre River Grand River Deepwater Creek Tebo Creek IO. ABBTHACT (T-tmUmn mm f<mrmm «M» M n««»«t««y aarf Idtullr...hematite, ceramics, and projectile points. Volume VI consists of an interpretation of the Euro-American settlement of the lower Pomme de Terre River...valley. Volume VI1 is a study of the re- sults of preliminary testing at several sites in the lower Pomme de Terre River valley

  17. A hydrologic analysis for the infiltration basins planned on Jeju Island, Korea

    Science.gov (United States)

    Lee, S.; Kang, T.; Lee, J.; Kang, S.

    2010-12-01

    Urban development is a cause of expansion of impervious area. It reduces infiltration of rain water and may increase runoff volume from storms. Infiltration basins can be a method to receive storm water and to let the water move into the soil. The contents of the study include a hydrologic analysis on a site and an evaluation of the capacity of infiltration basins planned on the site. Most region of Jeju Island, Korea is highly pervious. Three infiltration basins were designed on the area of the Jeju English Education City. To evaluate adequacy of the capacities of the infiltration basins, infiltration rates were measured and storm water runoff was simulated. Infiltration rates on the surface of the reserved land for infiltration basins were measured by a standard double ring infiltrometer or a small infiltrometer. A FORTRAN version of SWMM was modified to incorporate the infiltration basin and the basic equations of the infiltration basin are same as those of the infiltration trench used in MIDUSS. The code modified was used to simulate storm runoff from watersheds, infiltration from the infiltration basins, and reservoir routing of the infiltration basins. The saturated hydraulic conductivities on the reserved sites were measured by 0.0068, 0.0038, and 0.00017 cm/sec. The return period of the design rainfall is fifty years. The following results were obtained from a hydrologic analysis on the watersheds and the infiltration basins to be built. The two infiltration basins with higher infiltration rates have adequate capacities to infiltrate the total water inflow to the basins. Some water, however releases from the other infiltration basin and the capacity of the basin is not sufficient to infiltrate the total runoff after the land use change. A channel is needed in which the water released from the less pervious basin flows. The hydrologic analysis method of the study can be used for capacity evaluation of future infiltration basins on highly pervious areas in

  18. Group IB Organometallic Chemistry XXXIV: Thermal behavior and chemical reactivity of tetranuclear Me2N-substituted diarylpropenylcopper-copper anion (Vi2Cu4X2) and mixed diarylpropenyl/organocopper (Vi2Cu4R2) compounds

    NARCIS (Netherlands)

    Koten, G. van; Hoedt, R.W.M. ten; Noltes, J.G.

    1980-01-01

    Thermal decomposition of configurationally pure 1, 2-diarylpropenylcopper compounds Z-Vi{2}CU{4}Br{2} and Z-Vi{2}Cu{4}R{2} [Vi @? (2-Me{2}NC{6}H{4})C@?C(Me)-(C{6}H{4}Me-4), R @? 2-Me{2}NC{6}H{4} or 4-MeC{6}H{4}C@?C] predominantly results in the formation of ViH. In contrast, only dimers (ViVi) were

  19. Adsorption Properties of Bentonite with In Situ Immobilized Polyaniline Towards Anionic Forms of Cr(VI, Mo(VI, W(VI, V(V

    Directory of Open Access Journals (Sweden)

    Kateryna RYABCHENKO

    2016-05-01

    Full Text Available A new composite material bentonite-PANI was synthesized by in situ immobilization of polyaniline (PANI on the surface of natural mineral bentonite. It was established as a result of the modification of bentonite a surface area and an interlayer distance of mineral decrease and particles of bentonite transformed of irregular shape with different porosity on irregularly shaped particles of smaller size. It has been found that the total Cr(VI ions extraction took place under the acid conditions (pH=1 – 2 and W(VI ions have been well adsorbed in the pH range from 1 to 8 by the composite bentonite-PANI unlike the initial mineral. Whereas adsorption of oxo anions of V(V and Mo(VI made up some 50%. It is proved that the in situ immobilization of bentonite by polyaniline leads to increasing the value of adsorption capacity towards the investigated ions compared with the initial mineral. It was established that the adsorption properties of the synthesized composite with respect to the studied oxo ions were worse than the adsorption properties of composite vermiculite-PANI, similar to the composite Sokyryntsyy clinoptilolite-PANI and better than composites of polyaniline with Podilskyy saponite and Karelian shungite.DOI: http://dx.doi.org/10.5755/j01.ms.22.2.6976

  20. Cumulative Reactant Species Index for Volumes I-V of the Compilation of Data Relevant to Gas Lasers. Volume VI.

    Science.gov (United States)

    1979-09-01

    cross section (relative) 2027 ICt Electron affinity 214, 1161 Extinction coefficient for continuous absorption 702, 2032 12 Electron affinity 214, 1161...864 On Ne, high-energy production of free electrons 1622 On W, elt -ctron yields from surface 865 On Xe, high-energy ionization 1624 On He, high-energy

  1. Subsurface structure and the stress state of Utopia basin, Mars

    Science.gov (United States)

    Searls, Mindi Lea

    Topography and gravity data from recent Mars' space missions are used to analyze the subsurface structure of the Utopia basin, focusing on the volume and density of fill that causes the shallowness of the basin. Using the assumption that the initial isostatic state of Utopia was similar to that of the Hellas basin allows for construction of a thin-shell elastic model of Utopia that facilitates investigation of its interior configuration. A system of equations was developed that allows a solution for the original basin shape, the amount of fill within Utopia basin, the amount of flexure due to the fill material, the total vertical load and the horizontal load potential. The presence of apparently ancient impact craters within the Utopia basin indicates that the majority of the material within Utopia was deposited early in Mars' history when the elastic lithosphere of Mars was (presumably) relatively thin (shell model also allows us to calculate the stress field due to the flexure/membrane strains. The stress results indicate that the radial tectonic features seen in the Utopia region are not due solely to deformation of the elastic lithosphere. However, a more rigorous finite element analysis of the basin mechanics predicts a zone of observed radial faults for large elastic thicknesses. This model also predicts a region of strike-slip faulting just outside of the basin where concentric reverse faults are located. The inclusion of global compressional stresses due to the Tharsis load, global cooling, and/ or global climate changes could effectively increase the zone of predicted radial faults within the basin as well as shift the faulting style outside of the basin from strike-slip to the observed concentric faults.

  2. [Degradation of BPA in aqueous solution by interaction of photocatalytic oxidation and ferrate (VI) oxidation].

    Science.gov (United States)

    Li, Cong; Gao, Nai-Yun; Zhang, Ke-Jia

    2009-03-15

    The degradation of bispehnol A (BPA) in aqueous suspension by interaction of photocatalytic oxidation and ferrate (VI) oxidation was investigated under different conditions. The results indicate that the formation of Fe (V) and Fe (IV) is in the photoreduction of Fe (VI) by electron (e(cb)-) on the surface of TiO2. The oxidation efficiency of the photocatalytic oxidation in the presence of Fe (VI) is much greater than that without Fe (VI). In addition, the decomposition of Fe (VI) under different conditions was also investigated. The results indicate that the Fe (VI) reduction is enhanced by photocatalytic oxidation and the adsorption capacity of Fe (VI) at TiO2 surface decreases with pH increase. When the photocatalytic oxidation is used to degrade BPA, Fe (VI) could increase the degradation rate about 2.5 times.

  3. Tulare Basin protection plan

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The Tulare Basin Protection Plan has been initiated by The Nature Conservancy to elucidate the problems and opportunities of natural diversity protection....

  4. Mitigation : Closed Basin Project

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The upcoming meeting on waterfowl mitigation for the Closed Basin Project will have several people talk about possible changes to the waterfowl mitigation program. A...

  5. California Air Basins

    Data.gov (United States)

    California Department of Resources — Air ResourcesCalifornia Air Resources BoardThe following datasets are from the California Air Resources Board: * arb_california_airbasins - California Air BasinsThe...

  6. Watershed Planning Basins

    Data.gov (United States)

    Vermont Center for Geographic Information — The Watershed Planning Basin layer is part of a larger dataset contains administrative boundaries for Vermont's Agency of Natural Resources. The dataset includes...

  7. Social Set Visualizer (SoSeVi) II

    DEFF Research Database (Denmark)

    Flesch, Benjamin; Vatrapu, Ravi

    2016-01-01

    This paper reports the second iteration of the Social Set Visualizer (SoSeVi), a set theoretical visual analytics dashboard of big social data. In order to further demonstrate its usefulness in large-scale visual analytics tasks of individual and collective behavior of actors in social networks...

  8. Protective activity of Vi capsular polysaccharide vaccine against typhoid fever.

    Science.gov (United States)

    Klugman, K P; Gilbertson, I T; Koornhof, H J; Robbins, J B; Schneerson, R; Schulz, D; Cadoz, M; Armand, J

    1987-11-21

    The protective efficacy against typhoid fever of a single intramuscular injection of 25 micrograms of the Vi capsular polysaccharide (CPS) was assessed in a randomised double-blind controlled trial. Vaccination of 11,384 children was followed by 21 months' surveillance. 47 blood-culture-proven cases of typhoid occurred in children who received meningococcal A + C CPS vaccine and 19 cases in those vaccinated with Vi CPS. Protective efficacy was 60% calculated from the day of vaccination and 64% from 6 weeks after vaccination. Surveillance also included 11,691 unvaccinated children; 173 cases occurred in this group. Protective efficacy in relation to the unvaccinated group was 77.4% and 81.0% after 21 months, calculated immediately and 6 weeks after vaccination, respectively. Vaccination was associated with minimum local side-effects, and an increase in anti-Vi antibodies occurred, as measured by radioimmunoassay and enzyme-linked immunosorbent assay. Antibody levels remained significantly raised at 6 and 12 months post vaccination. Vi CPS is thus a safe and effective means of typhoid vaccination.

  9. Paisaje del viñedo: patrimonio y recurso

    Directory of Open Access Journals (Sweden)

    Luis Vicente Elías

    2008-01-01

    Full Text Available La propuesta de que el paisaje del viñedo sea el complemento a la visita a la bodega, siendo esta el eje del turismo del vino, es el objetivo de este trabajo. Repasando los conceptos variables de patrimonio, llegamos al paisaje del viñedo como recurso, formando parte del patrimonio natural. Pero este no se puede desvincular de los otros aspectos patrimoniales, por lo que la cultura tradicional es el soporte de la tipología de paisaje que queremos proponer y que va contrastar con los nuevos paisajes del viñedo que surgen de las recientes técnicas en los cultivos y de la actual vitivicultura, emparejada con una moderna “cultura del vino”. El análisis de las diversas normativas, que salvaguardan el paisaje y la comprobación del escaso valor legal del paisaje del viñedo, es otro puntal de este trabajo que trata de unir paisaje con cultura tradicional como recursos del Turismo del Vino, integrados en las Rutas del Vino.

  10. Osteogenesis Imperfecta Type VI in Individuals from Northern Canada.

    Science.gov (United States)

    Ward, Leanne; Bardai, Ghalib; Moffatt, Pierre; Al-Jallad, Hadil; Trejo, Pamela; Glorieux, Francis H; Rauch, Frank

    2016-06-01

    Osteogenesis imperfecta (OI) type VI is a recessively inherited form of OI that is caused by mutations in SERPINF1, the gene coding for pigment-epithelium derived factor (PEDF). Here, we report on two apparently unrelated children with OI type VI who had the same unusual homozygous variant in intron 6 of SERPINF1 (c.787-10C>G). This variant created a novel splice site that led to the in-frame addition of three amino acids to PEDF (p.Lys262_Ile263insLeuSerGln). Western blotting showed that skin fibroblasts with this mutation produced PEDF but failed to secrete it. Both children were treated with intravenous bisphosphonates, but the treatment of Individual 1 was switched to subcutaneous injections of denosumab (dose 1 mg per kg body weight, repeated every 3 months). An iliac bone sample obtained after 5 denosumab injections (and 3 months after the last injection) showed no change in the increased osteoid parameters that are typical of OI type VI, but the number of osteoclasts in trabecular bone was markedly increased. This suggests that the effect of denosumab on osteoclast suppression is of shorter duration in children with OI type VI than what has previously been reported on adults with osteoporosis.

  11. 77 FR 64399 - Order of Succession for HUD Region VI

    Science.gov (United States)

    2012-10-19

    ..., Community Planning and Development. 5. Lubbock Field Office Order of Succession a. Senior Management Analyst... URBAN DEVELOPMENT Order of Succession for HUD Region VI AGENCY: Office of Field Policy and Management, HUD. ACTION: Notice of Order of Succession. SUMMARY: In this notice, the Assistant Deputy...

  12. As duas naturezas de Lévi-Strauss

    Directory of Open Access Journals (Sweden)

    Philippe Descola

    2011-11-01

    Full Text Available Aborda-se aqui a complexidade do status do par conceitual natureza e cultura no pensamento de Lévi-Strauss. Ao mesmo tempo ferramenta de análise, cena filosófica dos primórdios e antinomia a superar, revisita-se os diferentes usos e significados na obra de Lévi-Strauss do conceito de natureza e sua relação com o de cultura. Mostra-se como é possível reconhecer na obra de Lévi-Strauss dois conceitos de natureza: por um lado, uma natureza que se opõe à cultura num programa científico formulado em termos classicamente dualistas e, por outro, uma teoria do conhecimento decididamente monista que considera o espírito como parte e produto desse mesmo mundo. Argumenta-se que se o dualismo entre cultura e natureza fundou o pensamento estruturalista de Lévi-Strauss, é na própria obra deste que encontramos os argumentos e meios de superá-lo. A vocação do estruturalismo na antropologia de hoje, no entanto, é de ir mais longe neste caminho do que foi o próprio fundador.

  13. Removal of Cr(VI) from groundwater by Fe(0)

    Science.gov (United States)

    Gao, Yanjiao; Liu, Rui

    2016-12-01

    This research was conducted to investigate the treatment of hexavalent chromium (Cr(VI)) by iron powder (Fe(0)) columns of simulated permeable reactive barriers with and without calcium carbonate (CaCO3). Two columns filled with Fe(0) were used as Cr(VI) removal equipment running at a flow velocity of 10 ml/min at room temperature. After 200 days running of the two columns, the results showed that Fe(0) was an effective material for Cr(VI) reduction with an average removal rate of above 84.6%. The performance of Column 2 with CaCO3 was better than Column 1 without CaCO3 in terms of average Cr(VI) removal rate. The presence of CaCO3 buffered the increasing pH caused by Fe(0) corrosion in Column 2 and enhanced the removal rate of Column 2. Scanning Electron Microscopy (SEM) images of Fe(0) in the three stages of running of the two columns illustrated that the coat layer of Column 1 was a little thicker than that of Column 2. Energy-dispersive spectrometry (EDS) results showed that the surface of Fe(0) of Column 2 contained more chromium elements. Raman spectroscopy found that all iron oxide was generated on the Fe(0) surface of Column 1 and Column 2 and chromium class objects were only detected on Fe(0) surface in Column 2.

  14. Uranium(VI) solubility in carbonate-free WIPP brine

    Energy Technology Data Exchange (ETDEWEB)

    Lucchini, J.F.; Borkowski, M.; Richmann, M.K.; Reed, D.T. [Los Alamos National Lab. (LANL), Carlsbad, NM (United States). Earth and Environmental Sciences Div.

    2013-08-01

    The solubility of uranium(VI) was determined in WIPP-relevant brines as a function of pC{sub H+} and ionic strength, in the absence of carbonate. Carbonate concentration was below 2 x 10{sup -5} M, measured using the gas chromatography method. In the absence of carbonate, the uranium(VI) solubilities were about x 10{sup -6} M in GWB at pC{sub H+} {>=} 7 and about 10{sup -8}-10{sup -7} M in ERDA-6 brine at pC{sub H+} {>=} 8. Solubility of uranium(VI) was also measured in NaCl media at the same levels as in ERDA-6 brine. The data established a uranium solubility that was 10-100 times lower than published results from Diaz-Arocas and Grambow, and they are in good agreement with modeling results and other literature data. In the absence of carbonate, hydrolysis was the main complexation and precipitation mechanisms for uranium(VI) solubility at high ionic strength and pC{sub H+} {>=} 7. However, the effect of borate complexation was noticeable at pC{sub H+} {proportional_to} 8-9. (orig.)

  15. Phonemicization for the Generation of Vi-syllable

    Directory of Open Access Journals (Sweden)

    José Antonio Radilla-Ávila

    2012-05-01

    Full Text Available This work presents the application of linguistic rules for the creation of vi-syllables of phrases written in the Spanish language in order to increase the believability of the labial synchronization in virtual characters. Especially, we describe the implementation of the phonological transcription and Syllabication as part of Phonemicization's process.

  16. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Haitao [Univ. of California, Berkeley, CA (United States)

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This methodis first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  17. AM(VI) partitioning studies. FY14 final report

    Energy Technology Data Exchange (ETDEWEB)

    Mincher, Bruce J. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-10-01

    The use of higher oxidation states of americium in partitioning from the lanthanides is under continued investigation by the sigma team. This is based on the hypothesis that Am(VI) can be produced and remain stable in irradiated first cycle raffinate solution long enough to perform solvent extraction for separations. The stability of Am(VI) to autoreduction was measured using millimolar americium concentrations in a 1-cm cell with a Cary 6000 UV/Vis spectrophotometer for data acquisition. At millimolar americium concentrations, Am(VI) is stable enough against its own autoreduction for separations purposes. A second major accomplishment during FY14 was the hot test. Americium oxidation and extraction was performed using a centrifugal contactor-based test bed consisting of an extraction stage and two stripping stages. Sixty-three percent americium extraction was obtained in one extraction stage, in agreement with batch contacts. Promising electrochemical oxidation results have also been obtained, using terpyridine ligand derivatized electrodes for binding of Am(III). Approximately 50 % of the Am(III) was oxidized to Am(V) over the course of 1 hour. It is believed that this is the first demonstration of the electrolytic oxidation of americium in a non-complexing solution. Finally, an initial investigation of Am(VI) extraction using diethylhexylbutyramide (DEHBA) was performed.

  18. Coherent Beam Combining Element for Five 150-W Fiber Lasers by Volume Bragg Gratings in PTR Glass

    Science.gov (United States)

    2011-08-03

    glasses,” Glass Science and Technology 75 C1 (2002) 73-90. 8. O.M. Efimov , L.B. Glebov, V.I. Smirnov, and L.N. Glebova, “Process for production of...high efficiency volume diffractive elements in photo-thermo-refractive glass,” U.S. Patent 6,586,141 (2003). 9. O.M. Efimov , L.B. Glebov, and V.I

  19. Collagen VI microfibril formation is abolished by an {alpha}2(VI) von Willebrand factor type A domain mutation in a patient with Ullrich congenital muscular dystrophy.

    Science.gov (United States)

    Tooley, Leona D; Zamurs, Laura K; Beecher, Nicola; Baker, Naomi L; Peat, Rachel A; Adams, Naomi E; Bateman, John F; North, Kathryn N; Baldock, Clair; Lamandé, Shireen R

    2010-10-22

    Collagen VI is an extracellular protein that most often contains the three genetically distinct polypeptide chains, α1(VI), α2(VI), and α3(VI), although three recently identified chains, α4(VI), α5(VI), and α6(VI), may replace α3(VI) in some situations. Each chain has a triple helix flanked by N- and C-terminal globular domains that share homology with the von Willebrand factor type A (VWA) domains. During biosynthesis, the three chains come together to form triple helical monomers, which then assemble into dimers and tetramers. Tetramers are secreted from the cell and align end-to-end to form microfibrils. The precise molecular mechanisms responsible for assembly are unclear. Mutations in the three collagen VI genes can disrupt collagen VI biosynthesis and matrix organization and are the cause of the inherited disorders Bethlem myopathy and Ullrich congenital muscular dystrophy. We have identified a Ullrich congenital muscular dystrophy patient with compound heterozygous mutations in α2(VI). The first mutation causes skipping of exon 24, and the mRNA is degraded by nonsense-mediated decay. The second mutation is a two-amino acid deletion in the C1 VWA domain. Recombinant C1 domains containing the deletion are insoluble and retained intracellularly, indicating that the mutation has detrimental effects on domain folding and structure. Despite this, mutant α2(VI) chains retain the ability to associate into monomers, dimers, and tetramers. However, we show that secreted mutant tetramers containing structurally abnormal C1 VWA domains are unable to associate further into microfibrils, directly demonstrating the critical importance of a correctly folded α2(VI) C1 domain in microfibril formation.

  20. K Basin Hazard Analysis

    Energy Technology Data Exchange (ETDEWEB)

    PECH, S.H.

    2000-08-23

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Final Safety Analysis Report. This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  1. K Basins Hazard Analysis

    Energy Technology Data Exchange (ETDEWEB)

    WEBB, R.H.

    1999-12-29

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Safety Analysis Report (HNF-SD-WM-SAR-062, Rev.4). This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  2. Solid-Phase Extraction of Trace Amounts of Uranium(VI in Environmental Water Samples Using an Extractant-Impregnated Resin Followed by Detection with UV-Vis Spectrophotometry

    Directory of Open Access Journals (Sweden)

    Ahmad Hosseini-Bandegharaei

    2013-01-01

    Full Text Available A stable extractant-impregnated resin (EIR containing Chrome Azurol B was prepared using Amberlite XAD-2010 as a porous polymeric support. The new EIR was employed for trace separation and preconcentration of U(VI ion followed by spectrophotometric determination with the arsenazo III procedure. CAB/XAD-2010 exhibited excellent selectivity for U(VI ion over coexisting ions. Experimental parameters including pH, contact time, shaking speed, and ionic strength were investigated by batch extraction methods. Maximum sorption of U(VI ions occurred at pH 4.3–6.9. The capacity of EIR was found to be 0.632 mmol·g−1. Equilibrium was reached in 25 min and the loading half-time, t1/2, was less than 6 min. The equilibrium adsorption isotherm of U(VI was fitted with the Langmuir adsorption model. In addition, a column packed with CAB/XAD-2010 was used for column-mode separation and preconcentration of U(VI ion. For the optimization of the dynamic procedure, effects of sample volume, sample and eluent flow rate, eluent concentration, and its volume were investigated. The preconcentration factors for U(VI were found out to be 160. But, for convenience, a preconcentration factor of 150 was utilized for the column-mode preconcentration. The dynamic procedure gave a detection limit of 5.0×10-10 mol·L−1 (0.12 μg·L−1 for U(VI ion. The proposed dynamic method showed good performance in analyzing environmental water samples.

  3. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Directory of Open Access Journals (Sweden)

    Peter J Hart

    Full Text Available Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  4. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Science.gov (United States)

    Hart, Peter J; O'Shaughnessy, Colette M; Siggins, Matthew K; Bobat, Saeeda; Kingsley, Robert A; Goulding, David A; Crump, John A; Reyburn, Hugh; Micoli, Francesca; Dougan, Gordon; Cunningham, Adam F; MacLennan, Calman A

    2016-01-01

    Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  5. SOME ASPECTS OF HYDROLOGICAL RISK MANIFESTATION IN JIJIA BASIN

    Directory of Open Access Journals (Sweden)

    D. BURUIANĂ

    2012-03-01

    Full Text Available Jijia river basin surface geographically fits in Moldavian Plateau, Plain of Moldavia subunit. Being lowered by 200 to 300 m compared to adjacent subunits, it appears as a depression with altitudes between 270-300 m.Through its position in the extra-Carpathian region, away from the influence of oceanic air masses, but wide open to the action of air masses of eastern, north-eastern and northern continental origin, Jijia basin receives precipitations which vary according to the average altitude differing from the northern to the southern part of the basin (564 mm in north, 529.4 mm in Iasi. A characteristic phenomenon to the climate is represented by the torrential rains in the hot season, under the form of rain showers with great intensity, fact that influences the drainage of basin rivers. Jijia hydrographic basin is characterized by frequent and sharp variations of flow volumes and levels which lead to floods and flooding throughout the basin. The high waters generally occur between March and June, when approximately 70% of the annual stock is transported. The paper analyzes the main causes and consequences of flooding in the studied area, also identifying some structural and non-structural measures of flood protection applied by authorities in Jijia hydrographic basin. As a case study, the flood recorded in Dorohoi in June 28-29, 2010 is presented.

  6. Paul Scherrer Institute Scientific and Technical Report 1999. Volume VI: Large Research Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Foroughi, Fereydoun; Bercher, Renate; Buechli, Carmen; Meyer, Rosa [eds.

    2000-07-01

    The department GFA (Grossforschungsanlagen, Large Research Facilities) has been established in October 1998. Its main duty is operation, maintenance and development of the PSI accelerators, the spallation neutron source and the beam transport systems for pions and muons. A large effort of this group concerns the planning and co-ordination of new projects like e.g. the assembly of the synchrotron light source (SLS), design studies of a new proton therapy facility, the ultracold neutron source and a new intensive secondary beam line for low energy muons. A large fraction of this report is devoted to research especially in the field of materials Science. The studies include large scale molecular dynamics computer simulations on the elastic and plastic behavior of nanostructured metals, complemented by experimental mechanical testing using micro-indentation and miniaturized tensile testing, as well as microstructural characterisation and strain field mapping of metallic coatings and thin ceramic layers, the latter done with synchrotron radiation.

  7. Metabonomics Approach to Biomarker Discovery, Volume VI: Dose and Time Response of Liver Toxicant

    Science.gov (United States)

    2009-05-01

    and pattern recognition analysis of the biochemical processes associated with the progression of and recovery from nephrotoxic lesions in the rat ...selected target-organ in a rat animal model that may occur within the warfighter prior to inducing a reduction in health or operational performance...markers of toxic effects induced by the cholestatic agent alpha-naphthylisothiocyanate (ANIT) in rats that may be extrapolated to identifying

  8. Wind energy conversion. Volume VI. Nonlinear response of wind turbine rotor

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, I.

    1978-09-01

    The nonlinear equations of motor for a rigid rotor restrained by three flexible springs representing, respectively, the flapping, lagging, and feathering motions are derived using Lagrange's equations, for arbitrary angular rotations. These are reduced to a consistent set of nonlinear equations using nonlinear terms up to third order. The complete analysis is divided into three parts, A, B, and C. Part A consists of forced response of two-degree flapping-lagging rotor under the excitation of pure gravitational field (i.e., no aerodynamic forces). In Part B, the effect of aerodynamic forces on the dynamic response of two-degree flapping-lagging rotor is investigated. In Part C, the effect of third degree of motion, feathering, is considered.

  9. Paul Scherrer Institute Scientific Report 1998. Volume VI: Large Research Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Guenter; Bercher, Renate; Buechli, Carmen; Foroughi, Fereydoun; Meyer, Rosa [eds.

    1999-09-01

    The department GFA (Grossforschungsanlagen, Large Research Facilities) has been established in October 1998 and its main duty is operation, maintenance and development of the PSI accelerators, the spallation neutron source and the beam transport systems for pions and muons. A large effort of this group concerns the planning and co-ordination of the assembly of the Swiss Light Source (SLS). (author) figs., tabs., refs.

  10. PROCEEDINGS OF RIKEN BNL RESEARCH CENTER, VOLUME 37, RHIC SPIN COLLABORATION MEETING VI (PART 2).

    Energy Technology Data Exchange (ETDEWEB)

    BLAND, L.; SAITO, N.

    2001-11-15

    The second part of the sixth RHIC Spin Collaboration (RSC) meeting was held on November 15, 2001 at Brookhaven National Laboratory. Previous meetings have elaborated on the new generation of proton spin-structure studies (e.g. gluon polarization and flavor separation of q and {bar q} polarizations via real W{sup {+-}} production) enabled by studying polarized proton collisions at energies and momentum transfers where perturbative QCD models are expected to be applicable. The focus of this meeting was on many of the experimental issues that must be resolved to achieve these physics goals. This summary is written with the benefit of hindsight following the completion of the first-ever run of a polarized proton collider. This first run can be considered as a successfully completed milestone of the RHIC Spin Collaboration. Other milestones remain important. Long term machine items were identified in Waldo Mackay's talk, the most important being the completion of the spin rotator magnets that will be installed in 2002 to allow the flexible orientation of the proton beam polarization at the PHENM and STAR experiments. At the meeting Waldo discussed a stronger partial snake magnet for the AGS as a means of producing highly polarized proton beams to inject into RHIC. Developments subsequent to this meeting suggest that a superconducting helical dipole magnet may be feasible for the AGS, and is likely to be needed to achieve the 70% beam polarization in RHIC. Longer term items were also presented, including potential increases in luminosity by the addition of electron cooling to RHIC and the possibility of increasing the collision energy by {approx}20% by replacement of the DX magnets. These items could be considered for a second generation of RHIC spin experiments. The other topics covered at the meeting were related to polarimetry and to the absolute calibration of the proton beam polarization in RHIC. These topics were divided into short- and long-term solutions to polarimetry issues. George Igo led a discussion about the addition of a Coulomb-Nuclear Interference (CNI) polarimeter to the AGS prior to FY2003 RHIC operations. The experience from the first RHIC spin run reinforces the need for reducing the time needed to complete polarization measurements in the AGS, and illustrated the importance of polarization measurements at different energies in the RHIC injectors. Progress continues to be made on the completion of a CNI polarimeter for the AGS prior to the FY2003 run.

  11. Paul Scherrer Institute Scientific and Technical Report 2001. Volume VI: Large Research Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Bercher, R.; Buechli, C.; Zumkeller, L. (eds.)

    2002-03-01

    While the main effort in the past ten years was directed towards increasing the beam current from 100 to 2000 {mu}A and installation of additional user facilities like SINQ to satisfy new needs, we are now concentrating on stable operation at these high beam intensities. Unfortunately, 'stable operation' is not clearly defined. A few years ago, the accelerator physicists considered 80% beam on time excellent but the users complained about poor performance. Today we achieve a yearly mean beam on time of almost 90% at 1.7 mA and we have achieved 95% to 98% of the scheduled beam time for periods of weeks. These numbers seem to be satisfactory for the users. Despite this achievement, we try hard to further reduce the number of serious and long breakdowns, which are the main cause of the reduced yearly mean availability. Furthermore, breakdowns that necessitate long repair times are extremely detrimental for many experiments, which have only been allocated a few days of beam time. As a result of our discussions, we launched a number of activities, which include design and construction of improved power supplies, intensifying preventive maintenance, procuring vital spare parts, and reducing repair times through careful preparation. In addition, we were given permission to strengthen the accelerator staff with highly qualified physicists in order to study and solve several pending problems. We are aware that the planned measures will by no means be fast and will require considerable financial and personnel support. A long-standing issue concerning the improvement of the machine performance is the replacement of the aluminum cavities in the main ring accelerator by new high power copper cavities. The studies and tests on a model cavity are finished and we have ordered a prototype cavity, which will arrive in fall 2002 and be installed in the ring after a rigorous test phase in 2004. A list of scientific publications in 2000 is also provided.

  12. BASIC Simulation Programs; Volumes V and VI. Social Studies, Teacher Assistance.

    Science.gov (United States)

    Digital Equipment Corp., Maynard, MA.

    Five computer programs which teach concepts and processes related to social studies (in the main, economics) are presented. The subjects of the programs are the distinction between balance of trade and balance of payments; installment buying, loan payments, and savings accounts; flow of goods, services, and money between business and the consumer;…

  13. Food and Nutrition. Volume II. Units VI-VIII: Fruit, Fats, Vegetables, Legumes, Grains, Meats.

    Science.gov (United States)

    Honse, Elizabeth Linsenbardt

    These instructional materials are intended as a guide for the instructor of a secondary home economics course in food and nutrition. Topics covered in the three units are time, energy, and resource management; selection, care, preparation, and storage of food (seven lessons on dairy foods; fats and oils; cereals and breads; fruits and vegetables;…

  14. PROCEEDINGS OF RIKEN BNL RESEARCH CENTER, RHIC SPIN COLLABORATION MEETING VI, VOLUME 36.

    Energy Technology Data Exchange (ETDEWEB)

    BLAND,L.; SAITO,N.

    2001-10-10

    The sixth meeting of the RHIC Spin Collaboration (RSC) took place on October 1, 2001 at Brookhaven National Laboratory. RHIC is now in its second year of operation for physics production and the first polarized proton collision run at {radical}s=200 GeV is expected to start in eight weeks. The RSC has developed a plan for this coming run through two previous meetings, RHIC Spin Physics III (August 3, 2000) and IV (October 13-14, 2000). We requested the following: two weeks of polarized proton studies in AGS, three weeks of polarized collider commissioning, and five weeks of polarized proton physics run. As a result, we have obtained all we asked and the above plans are implemented in the current operation schedule. The focus of the present meeting was to bring all involved in the RHIC Spin activities up-to-date on the progress of machine development, theory issues, and experimental issues. This meeting was right after the Program Advisory Committee (PAC) meeting and it started with the comments on the PAC discussion by Gerry Bunce, who was informed about the PAC deliberations by Tom Kirk. The PAC was fully supportive to complete the proposed spin program within the currently available budget for RHIC run 2 operations. Gerry further explained the expected luminosity to be {integral} Ldt = 0.5 pb{sup -1} per week, reflecting the current machine status. The introductory session also had a talk from Werner Vogelsang that reviewed the progress in perturbative QCD theory focused on spin effects.

  15. Paul Scherrer Institute Scientific and Technical Report 2000. Volume VI: Large Research Facilities

    Energy Technology Data Exchange (ETDEWEB)

    Foroughi, Fereydoun; Bercher, Renate; Buechli, Carmen; Zumkeller, Lotty [eds.

    2001-07-01

    The PSI Department Large Research Facilities (GFA) joins the efforts to provide an excellent research environment to Swiss and foreign research groups on the experimental facilities driven by our high intensity proton accelerator complex. Its divisions care for the running, maintenance and enhancement of the accelerator complex, the primary proton beamlines, the targets and the secondary beams as well as the neutron spallation source SINQ. The division for technical support and coordination provides for technical support to the research facility complementary to the basic logistic available from the department for logistics and marketing. Besides running the facilities, the staff of the department is also involved in theoretical and experimental research projects. Some of them address basic scientific questions mainly concerning the properties of micro- or nanostructured materials: experiments as well as large scale computer simulations of molecular dynamics were performed to investigate nonclassical materials properties. Others are related to improvements or extensions of the capabilities of our facilities. We also report on intriguing results from applications of the neutron capture radiography, the prompt gamma activation method and the isotope production facility at SINQ.

  16. The Aquitaine basin

    Energy Technology Data Exchange (ETDEWEB)

    Biteau, J.-J.; Le Marrec, A.; Le Vot, M.; Masset, J.-M.

    2006-07-01

    The Aquitaine Basin is located in the southwest of France, between the Gironde Arch in the north and the Pyrenean Mountain Chain in the south. It is a triangular-shaped domain, extending over 35000km{sup 2}. From north to south, six main geological provinces can be identified: (1) the Medoc Platform located south of the Gironde Arch; (2) the Parentis sub-basin; (3) the Landes Saddle; (4) the North Aquitaine Platform; (5) the foreland of the Pyrenees (also known as the Adour, Arzacq and Comminges sub-basins); and (6) the Pyrenean fold-and-thrust belt. Only the Parentis sub-basin, the foreland of the Pyrenean Chain and a minor part of the fold-and-thrust belt itself are proven hydrocarbon provinces. The Aquitaine Basin, in turn, is subdivided into four sub-basins - the Parentis, Adour-Arzacq, Tarbes and Comminges areas. The lozenge shape of these depocentres is related to the Hercynian tectonic framework of the Palaeozoic basement, reactivated during Early Cretaceous rifting. This rift phase aborted at the end of the Albian (prior to the development of an oceanic crust) in response to the beginning of the subduction of the Iberian plate under the European plate. During the Upper Cretaceous, continued subduction led to the creation of northwards-migrating flexural basins. In the Eocene, a paroxysmal phase of compression was responsible for the uplift of the Pyrenean Mountain Chain and for the thin-skinned deformation of the foreland basin. The resulting structuration is limited to the south by the internal core of the chain and to the north by the leading edge of the fold-and-thrust belt, where the Lacq and Meillon gas fields are located. Four main petroleum provinces have been exploited since the Second World War: (1) the oil-prone Parentis sub-basin and (2) salt ridges surrounding the Arzacq and Tarbes sub-basins; and (3) the gas-prone southern Arzacq sub-basin (including the external Pyrenean fold-and-thrust belt and the proximal foreland sub-basin) and (4

  17. Solid phase extraction of chromium(VI) from aqueous solutions by adsorption of its diphenylcarbazide complex on an Amberlite XAD-4 resin column.

    Science.gov (United States)

    Rajesh, N; Jalan, Rohit Kumar; Hotwany, Pinky

    2008-02-11

    A method has been developed for the solid phase extraction of chromium(VI) based on the adsorption of its diphenylcarbazide complex on an Amberlite XAD-4 resin column. The influence of acidity, stability of the column, sample volume, flow rate and interfering ions were studied in detail. The adsorbed complex could be eluted using acetone-sulfuric acid mixture and the concentration of chromium was determined using visible spectrophotometry. A detection limit of 6 microg L(-1) could be achieved. A preconcentration factor of 27 could be obtained for 400 mL sample volume. The validity of the method was checked in spiked water samples and electroplating wastewater.

  18. Persistence of antibody titres three years after vaccination with Vi polysaccharide vaccine against typhoid fever.

    Science.gov (United States)

    Tacket, C O; Levine, M M; Robbins, J B

    1988-08-01

    After a single injection of purified Vi polysaccharide vaccine against typhoid fever, serum titres were followed in student volunteers by passive haemagglutination assay and by radioimmunoassay. Elevated Vi antibody titres were still present after 36 months. This preliminary study should be followed by further investigations on the extent and duration of protection provided by Vi vaccine, and on volunteers in endemic areas.

  19. Annexin VI is attached to transverse-tubule membranes in isolated skeletal muscle triads.

    Science.gov (United States)

    Barrientos, G; Hidalgo, C

    2002-07-15

    Annexin VI is a 68-kDa protein of the Annexin family, a group of Ca2+-dependent phospholipid-binding proteins widely distributed in mammalian tissues including skeletal muscle. We investigated a) which membrane system contributes Annexin VI to skeletal muscle triads, and b) whether Annexin VI removal affects triad integrity or function. Annexin VI was present in isolated triads and transverse tubules but not in heavy sarcoplasmic reticulum vesicles, indicating that Annexin VI binds to either free or triad-attached transverse tubules. Extraction with EGTA of Annexin VI from triads did not alter their migration as a single band in sucrose density gradients or their ouabain binding-site density, indicating that triad integrity does not require Annexin VI. Caffeine-induced Ca2+ release kinetics and Ca2+ uptake rates were likewise not affected by Annexin VI removal from triads, suggesting that Annexin VI is not involved in these functions. Annexin VI purified from rabbit skeletal muscle displayed Ca2+-dependent binding to liposomes containing phosphatidylinositol 4,5-bisphosphate and phosphatidylcholine. Binding saturated at 1/20 molar ratio phosphatidylinositol 4,5-bisphosphate/phosphatidylcholine and was optimal at free [Ca2+] > or = 20 mM. Extraction of Annexin VI from triads did not affect the generation of phosphatidylinositol 4-phosphate, phosphatidylinositol 4,5-bisphosphate, or phosphatidic acid by endogenous lipid kinases, suggesting that despite its capacity to bind to negatively charged phospholipids, Annexin VI does not affect the kinase activities responsible for their generation.

  20. Contribution of Extracellular Polymeric Substances from Shewanella sp. HRCR-1 Biofilms to U(VI) Immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Bin; Ahmed, B.; Kennedy, David W.; Wang, Zheming; Shi, Liang; Marshall, Matthew J.; Fredrickson, Jim K.; Isern, Nancy G.; Majors, Paul D.; Beyenal, Haluk

    2011-06-05

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) in U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells without EPS, we showed that i) bEPS from Shewanella sp. HRCR-1 biofilms contributed significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; ii) bEPS could be considered as a functional extension of the cells for U(VI) immobilization and they likely play more important roles at initial U(VI) concentrations; and iii) U(VI) reduction efficiency was found to be dependent upon initial U(VI) concentration and the efficiency decreased at lower concentrations. To quantify relative contribution of sorption and reduction in U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(V). We found that, when in reduced form, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated reactivity of laEPS while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, might facilitate U(VI) reduction.

  1. Effect of Phosphate on U(VI) Sorption to Montmorillonite: Ternary Complexation and Precipitation Barriers

    Energy Technology Data Exchange (ETDEWEB)

    Troyer, Lyndsay D.; Maillot, Fabien; Wang, Zheming; Wang, Zimeng; Mehta, Vrajesh; Giammar, Daniel; Catalano, Jeffrey G.

    2016-02-15

    Phosphate addition is a potential treatment method to lower the solubility of U(VI) in soil and groundwater systems by causing U(VI) phosphate precipitation as well as enhancing adsorption. Previous work has shown that iron oxide surfaces may facilitate the nucleation of U(VI) phosphate minerals and, that under weakly acidic conditions, phosphate also enhances U(VI) adsorption to such phases. Like iron oxides, clays are important reactive phases in the subsurface but little is known about the interaction of U(VI) and phosphate with these minerals. The effect of aqueous phosphate on U(VI) binding to Wyoming montmorillonite (SWy-2) in air-equilibrated systems was investigated. Equilibrium U(VI) uptake to montmorillonite was determined at pH 4, 6 and 8 at discrete initial phosphate concentrations between 0 and 100 μM. The observed behavior of U(VI) indicates a transition from adsorption to precipitation with increasing total uranium and phosphate concentrations at all pH values. At the highest phosphate concentration examined at each pH value, a barrier to U(VI) phosphate nucleation is observed. At lower concentrations, phosphate has no effect on macroscopic U(VI) adsorption. To assess the mechanisms of U(VI)-phosphate interactions on smectite surfaces, U(VI) speciation was investigated under selected conditions using laser-induced fluorescence spectroscopy (LIFS) and extended X-ray absorption fine-structure (EXAFS) spectroscopy. Samples above the precipitation threshold display EXAFS and LIFS spectral signatures consistent with the autunite family of U(VI) phosphate minerals. However, at lower U(VI) concentrations, changes in LIFS spectra upon phosphate addition suggest that U(VI)-phosphate ternary surface complexes form on the montmorillonite surface at pH 4 and 6 despite the lack of a macroscopic effect on adsorption. The speciation of solid-associated U(VI) below the precipitation threshold at pH 8 is dominated by U(VI)-carbonate surface complexes. This work

  2. Effect of phosphate on U(VI) sorption to montmorillonite: Ternary complexation and precipitation barriers

    Science.gov (United States)

    Troyer, Lyndsay D.; Maillot, Fabien; Wang, Zheming; Wang, Zimeng; Mehta, Vrajesh S.; Giammar, Daniel E.; Catalano, Jeffrey G.

    2016-02-01

    Phosphate addition is a potential treatment method to lower the solubility of U(VI) in soil and groundwater systems by causing U(VI) phosphate precipitation as well as enhancing adsorption. Previous work has shown that iron oxide surfaces may facilitate the nucleation of U(VI) phosphate minerals and, that under weakly acidic conditions, phosphate also enhances U(VI) adsorption to such phases. Like iron oxides, clays are important reactive phases in the subsurface but little is known about the interaction of U(VI) and phosphate with these minerals. The effect of aqueous phosphate on U(VI) binding to Wyoming montmorillonite (SWy-2) in air-equilibrated systems was investigated. Equilibrium U(VI) uptake to montmorillonite was determined at pH 4, 6 and 8 at discrete initial phosphate concentrations between 0 and 100 μM. The observed behavior of U(VI) indicates a transition from adsorption to precipitation with increasing total uranium and phosphate concentrations at all pH values. At the highest phosphate concentration examined at each pH value, a barrier to U(VI) phosphate nucleation is observed. At lower concentrations, phosphate has no effect on macroscopic U(VI) adsorption. To assess the mechanisms of U(VI)-phosphate interactions on smectite surfaces, U(VI) speciation was investigated under selected conditions using laser-induced fluorescence spectroscopy (LIFS) and extended X-ray absorption fine-structure (EXAFS) spectroscopy. Samples above the precipitation threshold display EXAFS and LIFS spectral signatures consistent with the autunite family of U(VI) phosphate minerals. However, at lower U(VI) concentrations, changes in LIFS spectra upon phosphate addition suggest that U(VI)-phosphate ternary surface complexes form on the montmorillonite surface at pH 4 and 6 despite the lack of a macroscopic effect on adsorption. The speciation of solid-associated U(VI) below the precipitation threshold at pH 8 is dominated by U(VI)-carbonate surface complexes. This work

  3. OREDA offshore and onshore reliability data volume 1 - topside equipment

    CERN Document Server

    OREDA

    2015-01-01

    This handbook presents high quality reliability data for offshore equipment collected during phase VI to IX (project period 2000 – 2009) of the OREDA project. The intention of the handbook is to provide both quantitative and qualitative information as a basis for Performance Forecasting or RAMS (Reliability, Availability, Maintainability and Safety) analyses. Volume 1 is about Topside Equipment. Compared to earlier editions, there are only minor changes in the reliability data presentation. To obtain a reasonable population for presenting reliability data for topside equipment in the 2015 edition, some data from phases VI and VII already issued in the previous 2009 handbook (5th edition) have also been included. The 2015 topside volume is divided into two parts. Part I describes the OREDA project, different data collection phases and the estimation procedures used to generate the data tables presented in Part II of the handbook. Topside data are in general not covering the whole lifetime of equipment, but ...

  4. The involvement of ATP sulfurylase in Se(VI) and Cr(VI) reduction processes in the fission yeast Schizosaccharomyces pombe.

    Science.gov (United States)

    Raspor, P; Fujs, S; Banszky, L; Maraz, A; Batic, M

    2003-11-01

    The response of Schizosaccharomyces pombe towards the oxyanions selenate [Se(VI)] and dichromate [Cr(VI)] was investigated in order to establish the involvement of the yeast ATP sulfurylase in their reduction. An ATP sulfurylase-defective/selenate-resistant mutant of S. pombe (B-579 Se(R) -2) and an ATP sulfurylase-active/selenate-sensitive strain of S. pombe (B-579 Se(S)) were included in this study. The inhibitory effect of Se(VI) and Cr(VI) oxyanions on growth and bioaccumulation was measured. The sensitive strain showed natural sensitivity to selenate while the resistant mutant tolerated a 100-fold higher concentration of selenate. These results indicate that selenate toxicity to microorganisms is connected with the reduction of selenate to selenite. Both strains showed similar sensitivity to Cr(VI) and in this study there was no evidence that ATP sulfurylase participates in the reduction process of Cr(VI).

  5. Ética e profética nas Mitológicas de Lévi-Strauss

    Directory of Open Access Journals (Sweden)

    Renato Sztutman

    2009-06-01

    Full Text Available Este artigo intenta extrair das Mitológicas de Claude Lévi-Strauss uma ética e uma filosofia política (em princípio, ameríndias. Busca-se aqui a um só tempo responder e estender a provocação de Pierre Clastres, para quem a análise estrutural não teria se ocupado de tamanhas questões. Para realizar esta discussão, o foco será dado em duas obras de Lévi-Strauss: As origens dos modos à mesa, o terceiro volume das Mitológicas, e História de lince, a última das "pequenas mitológicas". Se a primeira finda com um excurso sobre a "moral dos mitos", a segunda principia com uma reflexão sobre a capacidade da mitologia de fornecer leituras da história, por exemplo, o "encontro" com o mundo europeu. Essas leituras, de sua parte, devem estar na base do que a literatura etnológica recente reconheceu como movimentos proféticos.This article focus Claude Lévi-Strauss' reflection on amerindian ethic and political thought. We suggest that we could read many passages of Mythologiques as if they contained sorts of replies as well as developments of some of Pierre Clastres' provocations and critics directed to structuralism. We will analyse particularly two books: Les origines des manières à table, Mythologiques' third volume, and Histoire de lynx, the last of the petites mythologiques. The first one ends with an interesting reflection on the "mythical moralism", while the second one starts with the problem of how amerindian mythologies can offer interpretations of history, interpretations of the "encounter" with europeans, for instance. These, we suppose, must be on the basis of what ethnological recent literature called "prophetic movements".

  6. Ultrasound-assisted cloud point extraction for speciation and indirect spectrophotometric determination of chromium(III) and (VI) in water samples

    Science.gov (United States)

    Hashemi, Mahdi; Daryanavard, Seyed Mosayeb

    Ultrasound-assisted cloud point extraction (UACPE) procedure was developed for speciation and indirect spectrophotometric determination of chromium(III) and (VI) in environmental water samples. The method is based on the reduction of Cr(VI) by iodide in acidic media and subsequently formation of I3- anion. The I3- formed can further react with cetyltrimethylammonium bromide (CTAB) and induce its clouding due to formation of an ion-association complex. The formed complex was separated from solution and dissolved in ethanol for spectrophotometric measurement. Cerium(IV) ammonium sulphate was chosen as an oxidizing reagent for pre-oxidation step of Cr(III) to Cr(VI) species before the addition of iodide to the system, up to chromium in trivalent can be determined by the procedure. Experimental parameters for both spectrophotometric reaction and extraction procedure have been optimized. Under optimized conditions Cr(VI) can be determined in the range 20-400 ng mL-1 (R2 = 0.999). Detection limit, preconcentration factor and relative standard deviation were 12 ng mL-1, 20.0 and 2.2% (n = 5), respectively with 10 mL sample volumes. The proposed method has been successfully applied for determination of chromium(V) in spiked water, synthetic seawater and electroplating wastewater samples with average recoveries of 100.1, 99.4 and 99.1%, respectively.

  7. Ultratrace Determination of Cr(VI) and Pb(II) by Microsample Injection System Flame Atomic Spectroscopy in Drinking Water and Treated and Untreated Industrial Effluents

    Science.gov (United States)

    Baig, Jameel Ahmed; Kazi, Tasneem Gul; Elci, Latif; Afridi, Hassan Imran; Khan, Muhammad Irfan; Naseer, Hafiz Muhammad

    2013-01-01

    Simple and robust analytical procedures were developed for hexavalent chromium (Cr(VI)) and lead (Pb(II)) by dispersive liquid-liquid microextraction (DLLME) using microsample injection system coupled with flame atomic absorption spectrophotometry (MIS-FAAS). For the current study, ammonium pyrrolidine dithiocarbamate (APDC), carbon tetrachloride, and ethanol were used as chelating agent, extraction solvent, and disperser solvent, respectively. The effective variables of developed method have been optimized and studied in detail. The limit of detection of Cr(VI) and Pb(II) were 0.037 and 0.054 µg/L, respectively. The enrichment factors in both cases were 400 with 40 mL of initial volumes. The relative standard deviations (RSDs, n = 6) were DLLME were estimated by the analysis of Cr(VI) and Pb(II) in industrial effluent wastewater by standard addition method (recoveries >96%). The proposed method was successfully applied to the determination of Cr(VI) and Pb(II) at ultratrace levels in natural drinking water and industrial effluents wastewater of Denizli. Moreover, the proposed method was compared with the literature reported method. PMID:24163779

  8. Water Temperature Controls in Arctic Basins

    Science.gov (United States)

    Neilson, B. T.; King, T.; Schmadel, N. M.; Heavilin, J.; Overbeck, L. D.; Kane, D. L.

    2015-12-01

    Understanding the dynamics of heat transfer mechanisms in arctic rivers is critical for forecasting the effects of climate change on river temperatures. Building on the collection of key data and a dynamic river temperature model that accounts for heat fluxes found important in temperate climates, we were able to identify portions of an arctic basin and hydrologic conditions for which heat flux dynamics differ from those found in temperate systems. During the open water season, similarities in heat flux influences include dominant shortwave radiation, greater surface exchanges than bed exchanges and greater influences of lateral inflows in the lower order portions of the basin. Differing from temperate systems, the heat flux contribution of net longwave radiation is consistently negative and both latent heat and bed friction are negligible. Despite these differences, accounting for the bulk lateral inflows from the basin resulted in accurate predictions during higher flows. Under lower flow conditions, however, lateral inflows were limited and resulting temperature predictions were poor. Work in a temperate system demonstrated that spatial variability in hydraulics influencing stream residence times are necessary for accurate river temperature predictions. Because heat fluxes at the air-water interface become increasingly dominant at low flows and these fluxes are sensitive to parameters representing the water surface area to volume ratio, similar to temperate systems, we expect that high-resolution representations of stream geometry and hydraulics are important both for accurate flux and residence time estimates. Furthermore, given the highly dynamic nature of flows in arctic basins, we anticipate that detailed information regarding spatially variable hydraulic characteristics (e.g., channel width, depth, and velocity) is critical for accurate predictions in low arctic rivers through a large range of flow conditions. Upon identifying key processes controlling

  9. The Vi conjugate typhoid vaccine is safe, elicits protective levels of IgG anti-Vi, and is compatible with routine infant vaccines.

    Science.gov (United States)

    Thiem, Vu Dinh; Lin, Feng-Ying C; Canh, Do Gia; Son, Nguyen Hong; Anh, Dang Duc; Mao, Nguyen Duc; Chu, Chiayung; Hunt, Steven W; Robbins, John B; Schneerson, Rachel; Szu, Shousun C

    2011-05-01

    Typhoid fever remains a serious problem in developing countries. Current vaccines are licensed for individuals who are 5 years old or older. A conjugate of the capsular polysaccharide (CP) of Salmonella enterica serovar Typhi (Vi) bound to recombinant exoprotein A of Pseudomonas aeruginosa (Vi-rEPA) enhanced Vi immunogenicity and protected 2- to 5-year-olds in Vietnam. In this study, Vi-rEPA was evaluated for use in infants. A total of 301 full-term Vietnamese infants received Expanded Program on Immunization (EPI) vaccines alone or with Vi-rEPA or Haemophilus influenzae type b-tetanus toxoid conjugate (Hib-TT) at 2, 4, and 6 months and Vi-rEPA or Hib-TT alone at 12 months. Infants were visited 6, 24, and 48 h after each injection to monitor adverse reactions. Maternal, cord, and infant sera were assayed for IgG anti-Vi and for IgG antibodies to Hib CP and the diphtheria, tetanus, and pertussis toxins at 7, 12, and 13 months. No vaccine-related serious adverse reactions occurred. In the Vi-rEPA group, the IgG anti-Vi geometric mean (GM) increased from the cord level of 0.66 to 17.4 enzyme-linked immunosorbent assay units (EU) at 7 months, declined to 4.76 EU at 12 months, and increased to 50.1 EU 1 month after the 4th dose (95% of infants had levels of ≥ 3.5 EU, the estimated protective level). Controls had no increase of the IgG anti-Vi GM. Infants with cord anti-Vi levels of <3.5 EU responded with significantly higher IgG anti-Vi levels than those with levels of ≥ 3.5 EU. Anti-diphtheria, -tetanus, and -pertussis toxin levels were similar in all groups. Vi-rEPA was safe, induced protective anti-Vi levels, and was compatible with EPI vaccines, and it can be used in infants. High cord IgG anti-Vi levels partially suppressed infant responses to Vi-rEPA.

  10. Recent Developments of Ferrate (VI) Salts as Cathode Meterial in High Capacity Batteries%铁(VI)酸盐正极材料的研究进展

    Institute of Scientific and Technical Information of China (English)

    袁中直; 周震涛; 李伟善

    2002-01-01

      The ferrate (VI) salts that have Fe element in an unusual VI valence state may be one of the best choices of high-energy batteries' cathode material, because ferrates (VI) are capable of the three-electron reduction, their reduction and decomposition products are nontoxic and environment-benign. One and a half century after the K2FeO4 synthesis, the chemistry and electrochemistry remains relatively unknown because of the incorrect knowledge of ferrates (VI) instability. The studies of ferrates (VI) used as cathode have been renewed recently. Many achievements have been made after the Israeli scientist Dr. Stuart Licht published their results on Science magazine that the alkaline ferrate (VI)/Zn batteries can provide 50% higher capacity than conventional alkaline batteries. In this article, the reasons of ferrate (VI) salts’ instability, methods of avoiding ferrate (VI) salts' decomposition and influences of some modifiers such as SrTiO3, Co2O3,MnO2,In2O3,KMnO4, (CFx)n on electrochemical characteristics of ferrate (VI) cathode are reviewed.%  铁(VI)酸盐中的Fe具有不寻常的高价态+6价,可以进行3电子还原放电反应,其还原产物及分解产物无毒无害,具有新一代“绿色电池”的重要特征。铁(VI)酸盐合成一个半世纪以来,由于认为它不稳定至今其化学和电化学性质并不很清楚。直到1999年以色列科学家Licht博士在Science上发表研究结果表明铁(VI)酸盐/Zn电池可以获得比常规碱性电池多50%的容量,铁(VI)酸盐高能电池才又引起深入的研究。本文综述了近年来铁(VI)酸盐作为高能电池正极活性物质的研究进展,包括改善铁(VI)酸盐稳定性的方法、掺杂修饰(如SrTiO3, Co2O3,MnO2,In2O3,KMnO4,(CFx)n等)等改善铁(VI)酸盐正极电化学性能的技术等。

  11. Immunization with the conjugate vaccine Vi-CRM₁₉₇ against Salmonella typhi induces Vi-specific mucosal and systemic immune responses in mice.

    Science.gov (United States)

    Fiorino, Fabio; Ciabattini, Annalisa; Rondini, Simona; Pozzi, Gianni; Martin, Laura B; Medaglini, Donata

    2012-09-21

    Typhoid fever is a public health problem, especially among young children in developing countries. To address this need, a glycoconjugate vaccine Vi-CRM₁₉₇, composed of the polysaccharide antigen Vi covalently conjugated to the non-toxic mutant of diphtheria toxin CRM₁₉₇, is under development. Here, we assessed the antibody and cellular responses, both local and systemic, following subcutaneous injection of Vi-CRM₁₉₇. The glycoconjugate elicited Vi-specific serum IgG titers significantly higher than unconjugated Vi, with prevalence of IgG1 that persisted for at least 60 days after immunization. Vi-specific IgG, but not IgA, were present in intestinal washes. Lymphocytes proliferation after restimulation with Vi-CRM₁₉₇ was observed in spleen and mesenteric lymph nodes. These data confirm the immunogenicity of Vi-CRM₁₉₇ and demonstrate that the vaccine-specific antibody and cellular immune responses are present also in the intestinal tract, thus strengthening the suitability of Vi-CRM₁₉₇ as a promising candidate vaccine against Salmonella Typhi.

  12. Petroleum prospectivity of the Canada Basin, Arctic Ocean

    Science.gov (United States)

    Grantz, A.; Hart, P.E.

    2012-01-01

    Reconnaissance seismic reflection data indicate that Canada Basin is a >700,000 sq. km. remnant of the Amerasia Basin of the Arctic Ocean that lies south of the Alpha-Mendeleev Large Igneous Province, which was constructed across the northern part of the Amerasia Basin between about 127 and 89-83.5 Ma. Canada Basin was filled by Early Jurassic to Holocene detritus from the Beaufort-Mackenzie Deltaic System, which drains the northern third of interior North America, with sizable contributions from Alaska and Northwest Canada. The basin contains roughly 5 or 6 million cubic km of sediment. Three fourths or more of this volume generates low amplitude seismic reflections, interpreted to represent hemipelagic deposits, which contain lenses to extensive interbeds of moderate amplitude reflections interpreted to represent unconfined turbidite and amalgamated channel deposits.Extrapolation from Arctic Alaska and Northwest Canada suggests that three fourths of the section in Canada Basin is correlative with stratigraphic sequences in these areas that contain intervals of hydrocarbon source rocks. In addition, worldwide heat flow averages suggest that about two thirds of Canada Basin lies in the oil or gas windows. Structural, stratigraphic and combined structural and stratigraphic features of local to regional occurrence offer exploration targets in Canada Basin, and at least one of these contains bright spots. However, deep water (to almost 4000 m), remoteness from harbors and markets, and thick accumulations of seasonal to permanent sea ice (until its possible removal by global warming later this century) will require the discovery of very large deposits for commercial success in most parts of Canada Basin. ?? 2011 Elsevier Ltd.

  13. Equations for estimating timber volume in the region of the River Basin of Ituxi, Lábrea, Amazon, Brazil Equações para estimativa de volume de madeira para a região da bacia do Rio Ituxi, Lábrea, AM

    Directory of Open Access Journals (Sweden)

    Fabio Thaines

    2010-12-01

    Full Text Available

    To quantify the stock of commercial timber in forests demands efficient methods, making possible to estimate efficiently and accurately the present and future timber volume. The aim of this work was to  adjust the mathematical models used to estimate timber volume, allowing the determination of the timber potential of a region with greater accuracy and lower cost. The study was conducted at Lábrea, State of  Amazonas, Brazil in an area of 6,000 ha, inserted in the Project Forest Management Seringal Iracema II. The forest is predominantly dense with emergent trees, also with the occurrence of open forest with bamboo and palms. For the process of adjusting the models to estimate the volume of commercial timber, 141 trees of commercial species were cubed by Smalian method. The equations developed for the Forest Management Project Seringal Iracema II are valid for diameters between 50 cm and 140 cm and for forests with similar structure; to standing trees due to its simplicity and accuracy, the best equation was Kopezki-Gehrardt (V = - 0.6870 + 0.00103 d²; for felling trees or for studies of biomass and carbon stock, the equation indicated is Schumacher-Hall (LnV = -9.5452 + 2.12837 Ln (d + 0.72209Ln (h.

    doi: 10.4336/2010.pfb.30.64.283

    A necessidade de quantificação do estoque de matéria-prima florestal, em floresta nativa, conduz para a busca de métodos eficientes de estimativa do volume de madeira, que possibilitem quantificar o estoque presente e futuro de maneira eficiente e precisa. O objetivo desse trabalho foi ajustar modelos matemáticos, para estimativa de volume comercial de madeira, permitindo a determinação do potencial madeireiro de uma região, com maior precisão e menor custo. O estudo foi realizado no Município de Lábrea, AM, em uma área de 6 mil ha, inserida no Projeto de Manejo Florestal Seringal Iracema II. A floresta é predominantemente densa com árvores emergentes, também com ocorrência de Foresta

  14. Water quality performance of a batch-type stormwater detention basin.

    Science.gov (United States)

    Middleton, John R; Barrett, Michael E

    2008-02-01

    The objective of this research was to modify an extended detention basin to provide batch treatment of stormwater runoff. An automated valve/controller was developed and placed on the outlet of a detention basin in Austin, Texas, which allowed the water quality volume to be retained in the basin for a preset length of time. The influent and effluent of the modified basin were monitored for total suspended solids (TSS), nutrients, chemical oxygen demand (COD), and total and dissolved metals. Statistically significant removal of total metals, COD, total nitrogen, total phosphorus, and TSS was observed, with a discharge event mean TSS concentration of 7 mg/L and a TSS removal efficiency of 91%. The modified basin has substantially better pollutant removal than conventional extended detention basins and is comparable with that of Austin sand filters, which are a common structural stormwater treatment system in the Austin area. The valve also can be used to isolate hazardous material spills.

  15. The capsular polysaccharide Vi from Salmonella Typhi is a B1b antigen

    Science.gov (United States)

    Marshall, Jennifer L.; Flores-Langarica, Adriana; Kingsley, Robert A.; Hitchcock, Jessica R.; Ross, Ewan A.; Lopez-Macias, Constantino; Lakey, Jeremy; Martin, Laura B.; Toellner, Kai-Michael; MacLennan, Calman A.; MacLennan, Ian C; Henderson, Ian R.; Dougan, Gordon; Cunningham, Adam F.

    2012-01-01

    Vaccination with purified capsular polysaccharide Vi antigen from Salmonella Typhi can protect against typhoid fever, although the mechanism for its efficacy is not clearly established. Here, we have characterised the B cell response to this vaccine in wild-type and T cell-deficient mice. We show that immunization with Typhim Vi rapidly induces proliferation in B1b peritoneal cells, but not in B1a cells or marginal zone (MZ) B cells. This induction of B1b proliferation is concomitant with the detection of splenic Vi-specific antibody secreting cells and protective antibody and Rag1-deficient B1b cell chimeras generated by adoptive transfer induced specific antibody after Vi immunization. Furthermore, antibody derived from peritoneal B cells is sufficient to confer protection against Salmonella that express Vi antigen. Expression of Vi by Salmonella during infection did not inhibit the development of early antibody responses to non-Vi antigens. Despite this, the protection conferred by immunization of mice with porin proteins from Salmonella, which induce antibody-mediated protection, was reduced after infection with Vi-expressing Salmonella, although protection was not totally abrogated. This work therefore suggests that in mice, B1b cells contribute to the protection induced by Vi antigen and targeting non-Vi antigens as sub-unit vaccines may offer an attractive strategy to augment current Vi-based vaccine strategies. PMID:23162127

  16. The capsular polysaccharide Vi from Salmonella typhi is a B1b antigen.

    Science.gov (United States)

    Marshall, Jennifer L; Flores-Langarica, Adriana; Kingsley, Robert A; Hitchcock, Jessica R; Ross, Ewan A; López-Macías, Constantino; Lakey, Jeremy; Martin, Laura B; Toellner, Kai-Michael; MacLennan, Calman A; MacLennan, Ian C; Henderson, Ian R; Dougan, Gordon; Cunningham, Adam F

    2012-12-15

    Vaccination with purified capsular polysaccharide Vi Ag from Salmonella typhi can protect against typhoid fever, although the mechanism for its efficacy is not clearly established. In this study, we have characterized the B cell response to this vaccine in wild-type and T cell-deficient mice. We show that immunization with typhoid Vi polysaccharide vaccine rapidly induces proliferation in B1b peritoneal cells, but not in B1a cells or marginal zone B cells. This induction of B1b proliferation is concomitant with the detection of splenic Vi-specific Ab-secreting cells and protective Ab in Rag1-deficient B1b cell chimeras generated by adoptive transfer-induced specific Ab after Vi immunization. Furthermore, Ab derived from peritoneal B cells is sufficient to confer protection against Salmonella that express Vi Ag. Expression of Vi by Salmonella during infection did not inhibit the development of early Ab responses to non-Vi Ags. Despite this, the protection conferred by immunization of mice with porin proteins from Salmonella, which induce Ab-mediated protection, was reduced postinfection with Vi-expressing Salmonella, although protection was not totally abrogated. This work therefore suggests that, in mice, B1b cells contribute to the protection induced by Vi Ag, and targeting non-Vi Ags as subunit vaccines may offer an attractive strategy to augment current Vi-based vaccine strategies.

  17. The distribution and kinematics of interstellar O VI in the Milky Way

    Science.gov (United States)

    Sarma, R.; Pathak, A.; Murthy, Jayant; Sarma, J. K.

    2017-02-01

    We present the results of a survey of interstellar O VI absorption in the Milky Way (MW) towards 69 stars in the Large Magellanic Cloud obtained with the Far Ultraviolet Spectroscopic Explorer (FUSE). The integrated MW O VI column densities log N(O VI) are in the range from 13.68 to 14.73 with a mean of 14.26_{-0.09}^{+0.07} atoms cm-2. The O VI exponential scale height is found to be 2.28 ± 1.06 kpc. The O VI column density correlates with the Doppler parameter b. The O VI velocity dispersion ranges from 14.0 to 91.6 with an average value of 62.7 km s-1. These high values of the velocity dispersion reveal the effect of turbulence, multiple velocity components and collision on broad O VI profiles. There is a significant variation of the O VI column density on all scales studied (0.0025°-6.35°). The smallest scale for which O VI column density variations has been found is Δθ ˜ 9 arcsec. A comparison of the O VI velocity profiles with Fe II indicates the presence of intermediate-velocity cloud and/or high-velocity cloud components in the O VI absorption.

  18. Assessment of undiscovered oil and gas resources of the North Sakhalin Basin Province, Russia, 2011

    Science.gov (United States)

    Klett, T.R.; Schenk, Christopher J.; Wandrey, Craig J.; Charpentier, Ronald R.; Brownfield, Michael E.; Pitman, Janet K.; Pollastro, Richard M.; Cook, Troy A.; Tennyson, Marilyn E.

    2011-01-01

    Using a geology-based assessment methodology, the U.S. Geological Survey estimated volumes of undiscovered, technically recoverable, conventional petroleum resources for the North Sakhalin Basin Province of Russia. The mean volumes were estimated at 5.3 billion barrels of crude oil, 43.8 trillion cubic feet of natural gas, and 0.8 billion barrels of natural gas liquids.

  19. Vi-CRM 197 as a new conjugate vaccine against Salmonella Typhi.

    Science.gov (United States)

    Micoli, F; Rondini, S; Pisoni, I; Proietti, D; Berti, F; Costantino, P; Rappuoli, R; Szu, S; Saul, A; Martin, L B

    2011-01-17

    An efficacious, low cost vaccine against typhoid fever, especially for young children, would make a major impact on disease burden in developing countries. The virulence capsular polysaccharide of Salmonella Typhi (Vi) coupled to recombinant mutant Pseudomonas aeruginosa exoprotein A (Vi-rEPA) has been shown to be highly efficacious. We investigated the use of carrier proteins included in infant vaccines, standardized the conjugation process and developed key assays required for routine lot release at production scale. Vi from a BSL1 organism, Citrobacter freundii, strain WR7011, was used as an alternative to Vi from S. Typhi. We showed that Vi conjugated to CRM(197), a non-toxic mutant of diphtheria toxin, widely used in commercial vaccines, was produced at high yield. Vi-CRM(197) proved immunogenic in animal studies, even without adjuvant. Thus, Vi-CRM(197) appears to be a suitable candidate for the development of a commercially viable, effective typhoid vaccine for developing countries.

  20. Sorption behavior of U(VI), 234U(VI) and 238U(VI) onto fracture-filling clays in Beishan granite, Gansu: Application to selecting the site of high-level radwaste repository in China

    Institute of Scientific and Technical Information of China (English)

    MIN; Maozhong; LUO; Xingzhang; WANG; Ju; JIN; Yuanxin; WAN

    2005-01-01

    The first results of sorption experiments of U(VI), 234U(VI) and 238U(VI) onto original (unpurified) fracture-filling clays from No.1 monzonitic granite intrusion, Beishan area, Gansu Province, China are reported. The monzonitic granite intrusion is a potential location for a high-level radwaste (HLW) repository in China. The present experimental results show that the maximum U(VI) sorption reached 92% at near-neutral Ph and the distribution coefficient (Kd) was 1226 Ml/g. A high sorption capacity of the fracture-filling clays in host rock on radioactive elements is necessary for HLW deep geological disposal repository. No preferential sorption of 234U onto the clays was found. Finally, the sorption of U(VI) onto the clays was also modeled using a surface complexation model.

  1. Plan of advanced satellite communications experiment using ETS-VI

    Science.gov (United States)

    Shiomi, Tadashi

    1988-01-01

    Communications Research Laboratory (CRL, Ministry of Posts and Telecommunications, Japan) has been engaged in development of three advanced satellite communication payloads aiming at experiments by Japan's 2-ton class Engineering Test Satellite VI (ETS-VI) which is to be launched in H-II rocket by NASDA in August 1992. CRL's three experimental systems are: (1) S-band inter-satellite communications; (2) millimeter-wave inter-satellite and personal-satellite communications; and (3) optical inter-satellite communications. CRL develops experimental optical communication system with telescope of 75 mm diameter which has gimbal mirror beam pointing/tracking mechanism. The onboard system has fundamental optical communication functions with laser diode transmitter of wavelength 0.83 micron, laser beam point-ahead mechanism, receiver of wavelength 0.51 micron, modulation/demodulation subsystem, and so on.

  2. Upper Limits on O VI Emission from Voyager Observations

    Indian Academy of Sciences (India)

    Jayant Murthy

    2002-03-01

    We have examined 426 Voyager fields distributed across the sky for O VI ( 1032/1038 Å) emission from the Galactic diffuse interstellar medium. No such emission was detected in any of our observed fields. Our most constraining limit was a 90% confidence upper limit of 2600 photons cm-2 sr-1 s-1 on the doublet emission in the direction (l, b) = (117.3, 50.6). Combining this with an absorption line measurement in nearly the same direction allows us to place an upper limit of 0.01 cm-3 on the electron density of the hot gas in this direction. We have placed 90% confidence upper limits of less than or equal to 10,000 photons cm-2 sr-1 s-1 on the O VI emission in 16 of our 426 observations.

  3. A spectroscopic study of uranium(VI) interaction with magnetite

    Energy Technology Data Exchange (ETDEWEB)

    El Aamrani, S. [Chemical Engineering Department, Universitat Politecnica de Catalunya (UPC), ETSEIB-UPC H4, Diagonal 647, 08028 Barcelona (Spain); Gimenez, J. [Chemical Engineering Department, Universitat Politecnica de Catalunya (UPC), ETSEIB-UPC H4, Diagonal 647, 08028 Barcelona (Spain)]. E-mail: francisco.javier.gimenez@upc.edu; Rovira, M. [Chemical Engineering Department, Universitat Politecnica de Catalunya (UPC), ETSEIB-UPC H4, Diagonal 647, 08028 Barcelona (Spain); CTM Centre Tecnologic, Avda. Bases de Manresa 1, Manresa (Spain); Seco, F. [CTM Centre Tecnologic, Avda. Bases de Manresa 1, Manresa (Spain); Grive, M. [ENVIROS Spain SL, Passeig de Rubi 29-31, Valldoreix (Spain); Bruno, J. [ENVIROS Spain SL, Passeig de Rubi 29-31, Valldoreix (Spain); Duro, L. [ENVIROS Spain SL, Passeig de Rubi 29-31, Valldoreix (Spain); Pablo, J. de [Chemical Engineering Department, Universitat Politecnica de Catalunya (UPC), ETSEIB-UPC H4, Diagonal 647, 08028 Barcelona (Spain); CTM Centre Tecnologic, Avda. Bases de Manresa 1, Manresa (Spain)

    2007-08-31

    The uranium sorbed onto commercial magnetite has been characterized by using two different spectroscopic techniques such as X-ray photoelectron spectroscopy (XPS), and extended X-ray absorption fine structure (EXAFS). Magnetite samples have been put in contact with uranium(VI) solutions in conditions in which a high uranium uptake is expected. After several days, the magnetite surface has been analysed by XPS and EXAFS. The XPS results obtained are not conclusive regarding the uranium oxidation state in the magnetite surface. On the other hand, the results obtained with the EXAFS technique show that the uranium-magnetite sample spectrum has characteristics from both the UO{sub 2} and schoepite spectra, e.g. a relatively high coordination number of equatorial oxygens and two axial oxygens, respectively. These results would indicate that the uranium sorbed onto magnetite would be a mixture of uranium(IV) and uranium(VI)

  4. Structural and Electronic Properties of IV-VI Semiconductor Nanodots

    Science.gov (United States)

    Leitsmann, Roman; Bechstedt, Friedhelm

    2008-03-01

    The characterization of nanostructure properties versus dimension and surface passivation is of increasing importance for the nanotechnology. Especially the stoichiometry, geometry, and the electronic states of IV-VI semiconductor nanodots are of special interest [1,2]. We use ab initio methods to calculate structural and electronic properties of colloidal IV-VI semiconductor nanodots as a function of the dot diameter. A method to passivate the non-directional dangling bonds at the nanodot surfaces is derived and used to study the confinement effect on the HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) states. In addition we take the influence of relativistic (spin-orbit coupling -- SOC ) and excitonic effects into account. While the SOC leads to a considerable decrease of the HOMO-LUMO gap, excitonic effects play a minor role. [1] JACS 128, 10337 (2006) [2] JACS 129, 11354 (2007)

  5. The Spy VI child: a newly discovered Neandertal infant.

    Science.gov (United States)

    Crevecoeur, Isabelle; Bayle, Priscilla; Rougier, Hélène; Maureille, Bruno; Higham, Thomas; van der Plicht, Johannes; De Clerck, Nora; Semal, Patrick

    2010-12-01

    Spy cave (Jemeppe-sur-Sambre, Belgium) is reputed for the two adult Neandertal individuals discovered in situ in 1886. Recent reassessment of the Spy collections has allowed direct radiocarbon dating of these individuals. The sorting of all of the faunal collections has also led to the discovery of the remains of a Neandertal child, Spy VI. This individual is represented by two mandibular corpus fragments. The left fragment is the most complete and both sides preserve the mental foramen. Four deciduous teeth are associated with these mandibular remains: three incisors and one canine. The lower left canine (Spy 645a) conjoins with the corresponding alveolar socket in the left part of the mandible. Following extant standards, the developmental stage of the preserved teeth indicate an age at death of about one and a half years. In addition to performing a classical morphometric comparative study of the mandible and teeth, we have evaluated the dental tissue proportions using high-resolution microtomographic techniques. Our results show that Spy VI generally falls within the Neandertal range of variation. However, this specimen also exhibits particular traits, notably in the dental internal structural organization, which reveals that variation in the immature Neandertal variation is larger than what was variation currently represented by the available fossil record. These observations demonstrate the need for investigating the frequency and expression of immature Neandertal traits in fossil anterior teeth, as well as their temporal and geographic variation. Direct radiocarbon dating of the Spy VI specimen has been conducted in two different laboratories. The results of Spy VI confirm the age previously determined for the two adults, making the Spy Neandertal remains the youngest ever directly dated in northwest Europe.

  6. The new geographic information system in ETVA VI.PE.

    Science.gov (United States)

    Xagoraris, Zafiris; Soulis, George

    2016-08-01

    ETVA VI.PE. S.A. is a member of the Piraeus Bank Group of Companies and its activities include designing, developing, exploiting and managing Industrial Areas throughout Greece. Inside ETVA VI.PE.'s thirty-one Industrial Parks there are currently 2,500 manufacturing companies established, with 40,000 employees and € 2.5 billion of invested funds. In each one of the industrial areas ETVA VI.PE guarantees the companies industrial lots of land (sites) with propitious building codes and complete infrastructure networks of water supply, sewerage, paved roads, power supply, communications, cleansing services, etc. The development of Geographical Information System for ETVA VI.PE.'s Industrial Parks started at the beginning of 1992 and consists of three subsystems: Cadastre, that manages the information for the land acquisition of Industrial Areas; Street Layout - Sites, that manages the sites sold to manufacturing companies; Networks, that manages the infrastructure networks (roads, water supply, sewerage etc). The mapping of each Industrial Park is made incorporating state-of-the-art photogrammetric, cartographic and surveying methods and techniques. Passing through the phases of initial design (hybrid GIS) and system upgrade (integrated Gis solution with spatial database), the system is currently operating on a new upgrade (integrated gIS solution with spatial database) that includes redesigning and merging the system's database schemas, along with the creation of central security policies, and the development of a new web GIS application for advanced data entry, highly customisable and standard reports, and dynamic interactive maps. The new GIS bring the company to advanced levels of productivity and introduce the new era for decision making and business management.

  7. ENDF-201: ENDF/B-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    Rose, P.F. [comp.

    1991-10-01

    Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on ``tapes.`` Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the ``tape`` number. These evaluations have been released without restrictions on their distribution or use.

  8. ENDF-201: ENDF/B-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    Rose, P.F. (comp.)

    1991-10-01

    Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on tapes.'' Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the tape'' number. These evaluations have been released without restrictions on their distribution or use.

  9. Sculture di Ravenna fra V e VI secolo

    OpenAIRE

    Alessandro Ruggieri

    2012-01-01

    La scultura a Ravenna nei secoli V e VI testimonia il legame con l’Oriente. Ravenna fu prima capitale dell’impero romano d’Occidente. Successivamente fu conquistata da Teodorico e a seguito della guerra greco-gotica tornò sotto il controllo dell’impero romano con capitale Costantinopoli. La scultura riflette questo legame grazie all’importazione di manufatti. Ravenna nell’altomedioevo accolse le tendenze artistiche costantinopolitane rielaborandole verso indirizzi inediti che permettono di at...

  10. Vi har brug for en ny værdipolitik

    DEFF Research Database (Denmark)

    Böss, Michael

    2010-01-01

    Den stærke fokusering på udlændingespørgsmålet har bidraget til at forarme et politisk klima, som i forvejen lider under mangel på visioner. Derved har vi undladt at tage hul på en nødvendig og mere dybtgående værdipolitisk debat om, hvad der sker med det danske samfund og dets værdigrundlag....

  11. Stark Broadening in Compact Stars: Xe VI Lines

    Indian Academy of Sciences (India)

    Milan S. Dimitrijević; Zoran Simić; Andjelka Kovačević; Aleksandar Valjarević; Sylvie Sahal-Bréchot

    2015-12-01

    We will consider Stark broadening of non hydrogenic spectral lines in the impact approximation in compact stars: pre-white dwarf and white dwarf atmospheres. In order to show an example, Stark broadening parameters have been calculated, using the impact semiclassical perturbation approach for four Xe VI spectral lines. Obtained results have been used to demonstrate the influence of Stark broadening in DA and DB white dwarf atmospheres.

  12. Modifed Great Basin Extent (Buffered)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Two different great basin perimeter files were intersected and dissolved using ArcGIS 10.2.2 to create the outer perimeter of the great basin for use modeling...

  13. VI-14, a novel flavonoid derivative, inhibits migration and invasion of human breast cancer cells

    Energy Technology Data Exchange (ETDEWEB)

    Li, Fanni; Li, Chenglin; Zhang, Haiwei; Lu, Zhijian [State Key Laboratory of Natural Medicines, Jiangsu Key Laboratory of Carcinogenesis and Intervention, China Pharmaceutical University, 24 Tongjiaxiang, Nanjing 210009 (China); Li, Zhiyu; You, Qidong [Department of Medicinal Chemistry, China Pharmaceutical University, Nanjing 210009 (China); Lu, Na [State Key Laboratory of Natural Medicines, Jiangsu Key Laboratory of Carcinogenesis and Intervention, China Pharmaceutical University, 24 Tongjiaxiang, Nanjing 210009 (China); Guo, Qinglong, E-mail: anticancer_drug@yahoo.com.cn [State Key Laboratory of Natural Medicines, Jiangsu Key Laboratory of Carcinogenesis and Intervention, China Pharmaceutical University, 24 Tongjiaxiang, Nanjing 210009 (China)

    2012-06-01

    It has been well characterized that flavonoids possess pronounced anticancer potentials including anti-angiogenesis, anti-metastasis, and pro-apoptosis. Herein, we report, for the first time, that VI-14, a novel flavonoid derivative, possesses anti-cancer properties. The purpose of this study is to investigate the anti-migration and anti-invasion activities of VI-14 in breast cancer cells. Our data indicate that VI-14 inhibits adhesion, migration and invasion of MDA-MB-231 and MDA-MB-435 human breast cancer cells. MDA-MB-231 cells treated with VI-14 display reduced activities and expressions of ECM degradation-associated proteins including matrix metalloproteinase 2 (MMP-2) and 9 (MMP-9) at both the protein and mRNA levels. Meanwhile, VI-14 treatment induces an up-regulated expression of tissue inhibitor of metalloproteinase 1 (TIMP-1) and 2 (TIMP-2) in MDA-MB-231 cells. Western blotting results show that phosphorylation levels of critical components of the MAPK signaling pathway, including ERK, JNK and P38, are dramatically decreased in VI-14-treated MDA-MB-231 cells. Furthermore, treatment of VI-14 significantly decreases the nuclear levels and the binding ability of nuclear factor-kappa B (NF-κB) and activator protein-1 (AP-1). Taken together, our data suggest that VI-14 treatment suppresses migration and motility of breast cancer cells, and VI-14 may be a potential compound for cancer therapy. Highlights: ► We report for the first time that VI-14 possesses anti-cancer properties. ► VI-14 weakens the adhesion, migration and invasion of human breast cancer cells. ► VI-14 decreases the activities and expressions of MMP-2/9. ► VI-14 suppresses the phosphorylation levels of the MAPK signaling pathway. ► VI-14 decreases the nuclear levels and the binding ability of NF-κB and AP-1.

  14. Basin Hopping Graph

    DEFF Research Database (Denmark)

    Kucharik, Marcel; Hofacker, Ivo; Stadler, Peter

    2014-01-01

    Motivation RNA folding is a complicated kinetic process. The minimum free energy structure provides only a static view of the most stable conformational state of the system. It is insufficient to give detailed insights into the dynamic behavior of RNAs. A sufficiently sophisticated analysis...... of the folding free energy landscape, however, can provide the relevant information. Results We introduce the basin hopping graph (BHG) as a novel coarse-grained model of folding landscapes. Each vertex of the BHG is a local minimum, which represents the corresponding basin in the landscape. Its edges connect...

  15. Thermal detoxification and bloating of chromium(VI) with bentonite

    Energy Technology Data Exchange (ETDEWEB)

    Wei, Y.-L., E-mail: yulin@thu.edu.t [Department of Environmental Science and Engineering, Tunghai University, Taichung 40704, Taiwan (China); Hsieh, H.-F.; Peng, Y.-S.; Yang, J.-C. [Department of Environmental Science and Engineering, Tunghai University, Taichung 40704, Taiwan (China); Paul Wang, H. [Department of Environmental Engineering, National Cheng Kung University, Tainan 70101, Taiwan (China); Sustainable Environmental Research Center, National Cheng Kung University, Tainan 70101, Taiwan (China); Lin, C.-Y.; Shih, W.-L.; Hsu, C.-C. [Department of Environmental Science and Engineering, Tunghai University, Taichung 40704, Taiwan (China)

    2010-07-21

    This study stabilizes and bloats Cr(VI)-sorbed bentonite by heating at high temperature. Cr leaching decreases with increasing temperatures. Heating the sample at 1100 {sup o}C results in a non-detectable Cr concentration in the leachate, equivalent to a Cr leaching percent less than 0.001% (i.e., Cr TCLP concentration <0.018 mg of Cr L{sup -1} of leachate). Morphology observed with a scanning electron microscopy indicates the occurrence of sintering of the sample heated at 1100 {sup o}C. The heated samples also show the occurrence of a vesicant process at 1100 {sup o}C. X-ray absorption spectroscopy results indicate that heating at 500 {sup o}C for 4 h can convert approximately 87% Cr(VI) into Cr(III) that is negligibly toxic; Cr{sub 2}O{sub 3} was detected to be the most abundant Cr species. After heating at higher temperatures, namely 900-1100 {sup o}C, almost all doped Cr(VI) is reduced to Cr(III) as inferred from the height of the pre-edge peak of XANES spectra and/or from XANES simulation.

  16. Implementation of MP_Lite for the VI Architecture

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Weiyi [Iowa State Univ., Ames, IA (United States)

    2001-01-01

    MP_Lite is a light weight message-passing library designed to deliver the maximum performance to applications in a portable and user friendly manner. The Virtual Interface (VI) architecture is a user-level communication protocol that bypasses the operating system to provide much better performance than traditional network architectures. By combining the high efficiency of MP_Lite and high performance of the VI architecture, they are able to implement a high performance message-passing library that has much lower latency and better throughput. The design and implementation of MP_Lite for M-VIA, which is a modular implementation of the VI architecture on Linux, is discussed in this thesis. By using the eager protocol for sending short messages, MP_Lite M-VIA has much lower latency on both Fast Ethernet and Gigabit Ethernet. The handshake protocol and RDMA mechanism provides double the throughput that MPICH can deliver for long messages. MP_Lite M-VIA also has the ability to channel-bonding multiple network interface cards to increase the potential bandwidth between nodes. Using multiple Fast Ethernet cards can double or even triple the maximum throughput without increasing the cost of a PC cluster greatly.

  17. FUSE Observations of O VI Overlying the Scutum Supershell

    CERN Document Server

    Sterling, N C; Richter, P; Fabian, D; Sembach, K R

    2001-01-01

    We present Far Ultraviolet Spectroscopic Explorer observations of the B0 III star HD 177989 ($l = 17.8^{rm \\o}, b = -11.9^{\\rm o}, d$ = 4.9 kpc). This line of sight passes through the high latitude outflow from the Scutum Supershell (GS 018-04+44), a structure that lies at a kinematic distance of ~ 3.5 kpc, and spans ~ 5$^{\\rm o}$ in diameter. The O VI $\\lambda$1031.93 line is compared with STIS observations of Si IV, C IV, and N V to examine the ionizing mechanisms responsible for producing the high ion absorption, as well as to study the processes by which gas is expelled into the halo. The O VI profile spans a similar velocity range as the other highly ionized atoms, from -70 to +80 km/s. Component fits reveal very broad absorption at the kinematic velocity of the Scutum shell, which differs from the narrow Si IV, C IV, and N V components, suggesting that these other species occupy a more confined region. It is possible that the O VI is present in hot gas from the shell interior that is diffusing into the ...

  18. Chemical filtration of Cr (VI) with electrospun chitosan nanofiber membranes.

    Science.gov (United States)

    Li, Lei; Li, Yanxiang; Yang, Chuanfang

    2016-04-20

    Chitosan nanofibers (average diameter of 75nm) were electrospun on polyester (PET) scrim to form composite nanofiber membranes with controlled pore size. The membranes were then stacked as a membrane bed for chemical filtration of Cr (VI) of 1-5mg/L. The performance of the bed with respect to loading capacity at breakthrough, bed saturation and utilization efficiency were carefully investigated. The results showed that while these three parameters were dependent on pH, flow rate, flow distribution and packed pattern of the membrane, the latter two were less affected by feed Cr (VI) concentration and bed length. The maximum bed loading capacity for 1mg/L Cr (VI) filtration at breakthrough was found to be 16.5mg-chromium/g-chitosan, higher than the static adsorption capacity of 11.0mg-chromium/g-chitosan using nanofiber mats, indicating the membranes' better potential for dynamic adsorption. The minimum bed length required to avoid breakthrough was determined to be three layers of stacked membranes with nanofiber deposition density of 1g/m(2) by applying bed depth service time (BDST) model.

  19. Implementation of MP{_}Lite for the VI Architecture

    Energy Technology Data Exchange (ETDEWEB)

    Weiyi Chen

    2002-12-31

    MP{_}Lite is a light weight message-passing library designed to deliver the maximum performance to applications in a portable and user friendly manner. The Virtual Interface (VI) architecture is a user-level communication protocol that bypasses the operating system to provide much better performance than traditional network architectures. By combining the high efficiency of MP{_}Lite and high performance of the VI architecture, they are able to implement a high performance message-passing library that has much lower latency and better throughput. The design and implementation of MP{_}Lite for M-VIA, which is a modular implementation of the VI architecture on Linux, is discussed in this thesis. By using the eager protocol for sending short messages, MP{_}Lite M-VIA has much lower latency on both Fast Ethernet and Gigabit Ethernet. The handshake protocol and RDMA mechanism provides double the throughput that MPICH can deliver for long messages. MP{_}Lite M-VIA also has the ability to channel-bonding multiple network interface cards to increase the potential bandwidth between nodes. Using multiple Fast Ethernet cards can double or even triple the maximum throughput without increasing the cost of a PC cluster greatly.

  20. Group ib organometallic chemistry. XXXIV. Thermal behaviour and chemical reactivity of tetranuclear Me2N-substituted diarypropenylcopper-copper anion (Vi2Cu4X2) and mixed diarylpropenyl/organocopper (Vi2Cu4R2) compounds

    NARCIS (Netherlands)

    Hoedt, R.W.M. ten; Koten, G. van; Noltes, J.G.

    1980-01-01

    Thermal decomposition of configurationally pure 1,2-diarylpropenylcopper compounds Z-Vi2CU4Br2 and Z-Vi2Cu4R2 [Vi = (2-Me2NC6H4)C=C(Me)-(C6H4Me-4), R = 2-Me2NC6H4 or 4-MeC6H4CC] predominantly results in the formation of ViH. In contrast, only dimers (ViVi) were formed on thermolysis of (Z-ViCu2OTf)η

  1. Evaluation of volume vascularization index and flow index: a phantom study.

    NARCIS (Netherlands)

    Schulten-Wijman, M.J.; Struijk, P.C.; Brezinka, C.; Jong, N De; Steegers, E.A.P.

    2008-01-01

    OBJECTIVES: Three-dimensional (3D) power Doppler ultrasonography provides indices to quantify moving blood within a volume of interest (e.g. ovary, endometrium, tumor or placenta). The purpose of this study was to determine the influence of ultrasound instrument settings on vascularization index (VI

  2. Bibliography, geophysical data locations, and well core listings for the Mississippi Interior Salt Basin

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-05-01

    To date, comprehensive basin analysis and petroleum system modeling studies have not been performed on any of the basins in the northeastern Gulf of Mexico. Of these basins, the Mississippi Interior Salt Basin has been selected for study because it is the most petroliferous basin in the northeastern Gulf of Mexico, small- and medium-size companies are drilling the majority of the exploration wells. These companies do not have the resources to perform basin analysis or petroleum system modeling research studies nor do they have the resources to undertake elaborate information searches through the volumes of publicly available data at the universities, geological surveys, and regulatory agencies in the region. The Advanced Geologic Basin Analysis Program of the US Department of Energy provides an avenue for studying and evaluating sedimentary basins. This program is designed to improve the efficiency of the discovery of the nation`s remaining undiscovered oil resources by providing improved access to information available in the public domain and by increasing the amount of public information on domestic basins. This report provides the information obtained from Year 1 of this study of the Mississippi Interior Salt Basin. The work during Year 1 focused on inventorying the data files and records of the major information repositories in the northeastern Gulf of Mexico and making these inventories easily accessible in an electronic format.

  3. Kinetics of reductive stripping of Np(VI) by acetohydroxamic acid from 30%TBP/kerosene to nitrate medium using a high-speed stirred cell

    Energy Technology Data Exchange (ETDEWEB)

    Li, Chuanbo; Yan, Taihong; Zuo, Chen; Zheng, Weifang [China Institute of Atomic Energy, Beijing (China)

    2015-07-01

    The kinetics of reductive stripping of Np(VI) by Acetohydroxamic Acid from 30%TBP/kerosene was investigated using a high-speed stirred cell designed by ourselves. The phase separator for sampling was simple and powerful. The interfacial areas of different stirring speeds were determined by microphotograph method at 21 C before the experiments. The effects of the different parameters as well as temperature were investigated systemically. The results showed that, at 21 C the rate equation is -d[Np(VI)]/dt = k(S/V)[Np(VI)]{sup 0.78}[AHA]{sup 0.46}[HNO{sub 3}]{sup -0.20} - k'(S/V)[Np(V)]{sup 2.87}, where k = (8.7 ± 0.7) x 10{sup -7}(mol/L){sup -0.04} ms{sup -1}, k' = 1.1 ± 0.2(mol/L){sup -2.87} ms{sup -1}, as c[HNO{sub 3}] <=1.0 mol/L, -d[Np(VI)]/dt = k(S/V)[Np(VI)]{sup 0.78}[AHA]{sup 0.46}[HNO{sub 3}]{sup -1.42} - k'(S/V)[Np(V)]{sup 2.87}, where k = (3.2 ± 0.3) x 10{sup -7} (mol/L){sup 1.18} ms{sup -1}, k' = 1.1 ± 0.2(mol/L){sup -2.87} ms{sup -1} as c[HNO{sub 3}] > = 1.0 mol/L, and S is the interfacial area, V the organic phase volume. The reductive stripping process is controlled by chemical reactions (kinetics regime) taking place at the interface. The apparent activation energy is 13.5 ± 0.2 kJ/mol.

  4. Mucopolysaccharidosis VI in cats - clarification regarding genetic testing.

    Science.gov (United States)

    Lyons, Leslie A; Grahn, Robert A; Genova, Francesca; Beccaglia, Michela; Hopwood, John J; Longeri, Maria

    2016-07-02

    The release of new DNA-based diagnostic tools has increased tremendously in companion animals. Over 70 different DNA variants are now known for the cat, including DNA variants in disease-associated genes and genes causing aesthetically interesting traits. The impact genetic tests have on animal breeding and health management is significant because of the ability to control the breeding of domestic cats, especially breed cats. If used properly, genetic testing can prevent the production of diseased animals, causing the reduction of the frequency of the causal variant in the population, and, potentially, the eventual eradication of the disease. However, testing of some identified DNA variants may be unwarranted and cause undo strife within the cat breeding community and unnecessary reduction of gene pools and availability of breeding animals. Testing for mucopolysaccharidosis Type VI (MPS VI) in cats, specifically the genetic testing of the L476P (c.1427T>C) and the D520N (c.1558G>A) variants in arylsulfatase B (ARSB), has come under scrutiny. No health problems are associated with the D520N (c.1558G>A) variant, however, breeders that obtain positive results for this variant are speculating as to possible correlation with health concerns. Birman cats already have a markedly reduced gene pool and have a high frequency of the MPS VI D520N variant. Further reduction of the gene pool by eliminating cats that are heterozygous or homozygous for only the MPS VI D520N variant could lead to more inbreeding depression effects on the breed population. Herein is debated the genetic testing of the MPS VI D520N variant in cats. Surveys from different laboratories suggest the L476P (c.1427T>C) disease-associated variant should be monitored in the cat breed populations, particularly breeds with Siamese derivations and outcrosses. However, the D520N has no evidence of association with disease in cats and testing is not recommended in the absence of L476P genotyping. Selection

  5. Flow injection solid phase extraction electrothermal atomic absorption spectrometry for the determination of Cr(VI) by selective separation and preconcentration on a lab-made hybrid mesoporous solid microcolumn

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Manuela; Stripeikis, Jorge [Laboratorio de Analisis de Trazas, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, INQUIMAE, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, (1428) Buenos Aires (Argentina); Tudino, Mabel [Laboratorio de Analisis de Trazas, Departamento de Quimica Inorganica, Analitica y Quimica Fisica, INQUIMAE, Universidad de Buenos Aires, Pabellon 2, Ciudad Universitaria, (1428) Buenos Aires (Argentina)], E-mail: tudino@qi.fcen.uba.ar

    2009-06-15

    A lab-made hybrid mesoporous solid was employed in a flow injection solid phase extraction electrothermal atomic absorption spectrometric (FI-SPE-ETAAS) system for the selective retention of Cr(VI). The solid was prepared by co-condensation of sodium tetraethylortosilicate and 3-aminopropyltriethoxysilane by sol-gel methodology and one-pot synthesis and characterized by Fourier transform infrared spectroscopy, X ray diffraction spectroscopy, and scanning electronic microscopy. Adsorption capacities at different pH values of both, Cr(VI) and Cr(III), were also measured in order to obtain the optimum retention for Cr(VI) with no interference of Cr(III). The maximum capacity of adsorption (4.35 mmol g{sup -} {sup 1}) was observed for pH values between 2-3, whilst Cr(III) was found to remain in solution (adsorption capacity = 0.007 mmol g{sup -} {sup 1}). Then, a microcolumn (bed volume: 7.9 {mu}L) was filled with the solid and inserted in the FI-ETAAS system for analytical purposes. Since the analyte was strongly retained by the filling in the anionic form, 0.1 mol L{sup -} {sup 1} hydroxylammonium chloride in 1 mol L{sup -} {sup 1} hydrochloric acid was selected as eluent due to its redox characteristics. In this way, the sorbed Cr(VI) was easily released in the cationic form. The enrichment factor (EF) was found as a compromise between sensitivity and sample throughput and a value of 27 was obtained under optimized conditions: pH 2, sample loading 2 mL min{sup -} {sup 1} (60 s), elution flow rate 0.5 ml min{sup -} {sup 1} (eluent volume: 75 {mu}L). Under optimized conditions the limit of detection for Cr(VI) was 1.2 ng L{sup -} {sup 1}, the precision, expressed as RSD was 2.5%, the sample throughput 21/h, and the microcolumn lifetime was over 300 adsorption/desorption cycles. Cr(III) determination was also performed by simply measuring its concentration at the end of the column and after Cr(VI) retention by the mesoporous solid. Applications of the methodology to

  6. Single-basined choice

    NARCIS (Netherlands)

    Bossert, W.; Peters, H.J.M.

    2013-01-01

    Single-basined preferences generalize single-dipped preferences by allowing for multiple worst elements. These preferences have played an important role in areas such as voting, strategy-proofness and matching problems. We examine the notion of single-basinedness in a choice-theoretic setting. In co

  7. Photophysical Properties of II-VI Semiconductor Nanocrystals

    Science.gov (United States)

    Gong, Ke

    As it is well known, semiconductor nanocrystals (also called quantum dots, QDs) are being actively pursued for use in many different types of luminescent optical materials. These materials include the active media for luminescence downconversion in artificial lighting, lasers, luminescent solar concentrators and many other applications. Chapter 1 gives general introduction of QDs, which describe the basic physical properties and optical properties. Based on the experimental spectroscopic study, a semiquantitative method-effective mass model is employed to give theoretical prediction and guide. The following chapters will talks about several topics respectively. A predictive understanding of the radiative lifetimes is therefore a starting point for the understanding of the use of QDs for these applications. Absorption intensities and radiative lifetimes are fundamental properties of any luminescent material. Meantime, achievement of high efficiency with high working temperature and heterostructure fabrication with manipulation of lattice strain are not easy and need systematic investigation. To make accurate connections between extinction coefficients and radiative recombination rates, chapter 2 will consider three closely related aspects of the size dependent spectroscopy of II-VI QDs. First, it will consider the existing literature on cadmium selenide (CdSe) QD absorption spectra and extinction coefficients. From these results and fine structure considerations Boltzmann weighted radiative lifetimes are calculated. These lifetimes are compared to values measured on very high quality CdSe and CdSe coated with zinc selenide (ZnSe) shells. Second, analogous literature data are analyzed for cadmium telluride (CdTe) nanocrystals and compared to lifetimes measured for very high quality QDs. Furthermore, studies of the absorption and excitation spectra and measured radiative lifetimes for CdTe/CdSe Type-II core/shell QDs are reported. These results are also analyzed in

  8. Renormalized Volume

    CERN Document Server

    Gover, A Rod

    2016-01-01

    For any conformally compact manifold with hypersurface boundary we define a canonical renormalized volume functional and compute an explicit, holographic formula for the corresponding anomaly. For the special case of asymptotically Einstein manifolds, our method recovers the known results. The anomaly does not depend on any particular choice of regulator, but the coefficients of divergences do. We give explicit formulae for these divergences valid for any choice of regulating hypersurface; these should be relevant to recent studies of quantum corrections to entanglement entropies. The anomaly is expressed as a conformally invariant integral of a local Q-curvature that generalizes the Branson Q-curvature by including data of the embedding. In each dimension this canonically defines a higher dimensional generalization of the Willmore energy/rigid string action. We show that the variation of these energy functionals is exactly the obstruction to solving a singular Yamabe type problem with boundary data along the...

  9. Sediment Transportation Induced by Deep-Seated Landslides in a Debris Flow Basin in Taiwan

    Science.gov (United States)

    Lin, Meei Ling; Chen, Te Wei; Chen, Yong Sheng; Sin Jhuang, Han

    2016-04-01

    Typhoon Morakot brought huge amount of rainfall to the southern Taiwan in 2009 and caused severe landslides and debris flow hazard. After Typhoon Morakot, it was found that the volume of sediment transported by the debris flow and its effects on the affected area were much more significant compared to previous case history, which may due to the huge amount of rainfall causing significant deep-seated landslides in the basin. In this study, the effects and tendency of the sediment transportation in a river basin following deep-seated landslides caused by typhoon Morakot were evaluated. We used LiDAR, DEM, and aerial photo to identify characteristics of deep-seated landslides in a debris flow river basin, KSDF079 in Liuoguey District, Kaohsiung City, Taiwan. Eight deep-seated landslides were identified in the basin. To estimate the potential landslide volume associated with the deep-seated landslides, the stability analysis was conducted to locate the critical sliding surface, and the potential landside volume was estimated based on the estimation equation proposed by the International Geotechnical Societies' UNESCO Working Party on World Landslide Inventory (WP/WLI, 1990). The total potential landslide volume of the eight deep-seated landslides in KSDF079 basin was about 28,906,856 m3. Topographic analysis was performed by using DEM before and LiDAR derived DEM after typhoon Morakot to calculate the landslide volume transported. The result of erosion volume and deposition volume lead to a run out volume of 5,832,433 m3. The results appeared to consist well with the field condition and aerial photo. Comparing the potential landslide volume and run out volume of eight deep-seated landslides, it was found that the remaining potential landslide volume was about 80%. Field investigation and topographic analysis of the KSDF079 debris flow revealed that a significant amount of sediment deposition remained in the river channel ranging from the middle to the downstream

  10. Immunological evaluation of Vi capsular polysaccharide of Salmonella enterica subsp. Typhi vaccine by serum bactericidal assay.

    Science.gov (United States)

    Ahmadi, H; Tabaraie, B; Maleknia, S; Shapouri, R; Nejati, M; Pour Mirza Gholi, F; Hedayati, M; Sadati, M; Zahednia, S; Sharifat Salmani, A

    2013-02-01

    Salmonella enterica subsp. Typhi (S. Typhi) Vi antigen capsular polysaccharide (Vi-CPS) is a licensed vaccine against typhoid fever. As there is no animal model for S. Typhi fever to evaluate the protective efficacy of the Vi-CPS vaccine, a serum bactericidal assay (SBA) is the recommended 'gold standard' to evaluate its potency. Vi-CPS was extracted from S. Typhi Ty6S (CSBPI-B191) using a modified Gotschlich method. Purified Vi-CPS (50 µg) was injected intramuscularly into three groups of five rabbits; group 2 received an additional booster dose of 50 µg Vi-CPS on day 15 and group 3 received two additional boosters on days 15 and 30. The sera obtained from each group were tested by SBA on days 0, 15, 30 and 45. The anti-Vi-CPS titres for groups 1, 2 and 3 on days 15, 30 and 45 were 4, 16 and 16; 4, 32 and 32; and 16, 64 and 64, respectively. Thus, Vi-CPS was shown to be a potent immunogen, as even one dose could induce an efficient bactericidal effect against S. Typhi. Although Vi-CPS is a reliable vaccine, sometimes depolymerization during purification can affect its potency, which can be resolved through a potency test. As the passive haemagglutination test recommended by the World Health Organization does not indicate vaccine potency, we recommend using an SBA to evaluate the bactericidal ability of Vi-CPS.

  11. Microstructural analyses of Cr(VI) speciation in chromite ore processing Residue (COPR)

    Energy Technology Data Exchange (ETDEWEB)

    CHRYSOCHOOU, MARIA; FAKRA, SIRINE C .; Marcus, Matthew A.; Moon, Deok Hyun; Dermatas, Dimitris

    2010-03-01

    The speciation and distribution of Cr(VI) in the solid phase was investigated for two types of chromite ore processing residue (COPR) found at two deposition sites in the United States: gray-black (GB) granular and hard brown (HB) cemented COPR. COPR chemistry and mineralogy were investigated using micro-X-ray absorption spectroscopy and micro-X-ray diffraction, complemented by laboratory analyses. GB COPR contained 30percent of its total Cr(VI) (6000 mg/kg) as large crystals(>20 ?m diameter) of a previously unreported Na-rich analog of calcium aluminum chromate hydrates. These Cr(VI)-rich phases are thought to be vulnerable to reductive and pH treatments. More than 50percent of the Cr(VI) was located within nodules, not easily accessible to dissolved reductants, and bound to Fe-rich hydrogarnet, hydrotalcite, and possibly brucite. These phases are stable over a large pH range, thus harder to dissolve. Brownmilleritewasalso likely associated with physical entrapment of Cr(VI) in the interior of nodules. HB COPR contained no Cr(VI)-rich phases; all Cr(VI) was diffuse within the nodules and absent from the cementing matrix, with hydrogarnet and hydrotalcite being the main Cr(VI) binding phases. Treatment ofHBCOPRis challenging in terms of dissolving the acidity-resistant, inaccessible Cr(VI) compounds; the same applies to ~;;50percent of Cr(VI) in GB COPR.

  12. Silicon nanoparticles (SiNp) alleviate chromium (VI) phytotoxicity in Pisum sativum (L.) seedlings.

    Science.gov (United States)

    Tripathi, Durgesh Kumar; Singh, Vijay Pratap; Prasad, Sheo Mohan; Chauhan, Devendra Kumar; Dubey, Nawal Kishore

    2015-11-01

    The present study was aimed to investigate the effect of silicon nanoparticles (SiNp) against Cr (VI) phytotoxicity in pea seedlings. Results show that Cr(VI, 100 μM) significantly (P < 0.05) declined growth of pea which was accompanied by the enhanced level of Cr. Additionally, photosynthetic pigments and chlorophyll fluorescence parameters like F(v)/F(m), F(v)/F0 and qP were decreased while NPQ significantly (P < 0.05) increased under Cr(VI) treatment. Superoxide radical, hydrogen peroxide and malondialdehyde (MDA-lipid peroxidation) contents were enhanced by Cr(VI). Activities of antioxidant enzymes like superoxide dismutase and ascorbate peroxidase were increased by Cr (VI) while activities of catalase, glutathione reductase and dehydroascorbate reductase were inhibited significantly (P < 0.05). Micro and macronutrients also show decreasing trends (except S) under Cr(VI) treatment. However, addition of SiNp together with Cr(VI) protects pea seedlings against Cr(VI) phytotoxicity hence improved growth was noticed. In conclusion, the results of this study show that Cr(VI) causes negative impact on pea seedlings, however; SiNp protects pea seedlings against Cr(VI) phytotoxicity by reducing Cr accumulation and oxidative stress, and up-regulating antioxidant defense system and nutrient elements.

  13. Dynamics of microbial community during bioremediation of phenanthrene and chromium(VI)-contaminated soil microcosms.

    Science.gov (United States)

    Ibarrolaza, Agustín; Coppotelli, Bibiana M; Del Panno, María T; Donati, Edgardo R; Morelli, Irma S

    2009-02-01

    The combined effect of phenanthrene and Cr(VI) on soil microbial activity, community composition and on the efficiency of bioremediation processes has been studied. Biometer flask systems and soil microcosm systems contaminated with 2,000 mg of phenanthrene per kg of dry soil and different Cr(VI) concentrations were investigated. Temperature, soil moisture and oxygen availability were controlled to support bioremediation. Cr(VI) inhibited the phenanthrene mineralization (CO(2) production) and cultivable PAH degrading bacteria at levels of 500-2,600 mg kg(-1). In the bioremediation experiments in soil microcosms the degradation of phenanthrene, the dehydrogenase activity and the increase in PAH degrading bacteria counts were retarded by the presence of Cr(VI) at all studied concentrations (25, 50 and 100 mg kg(-1)). These negative effects did not show a correlation with Cr(VI) concentration. Whereas the presence of Cr(VI) had a negative effect on the phenanthrene elimination rate, co-contamination with phenanthrene reduced the residual Cr(VI) concentration in the water exchangeable Cr(VI) fraction (WEF) in comparison with the soil microcosm contaminated only with Cr(VI). Clear differences were found between the denaturing gradient gel electrophoresis (DGGE) patterns of each soil microcosm, showing that the presence of different Cr(VI) concentrations did modulate the community response to phenanthrene and caused perdurable changes in the structure of the microbial soil community.

  14. Mitigation measures for chromium-VI contaminated groundwater - The role of endophytic bacteria in rhizofiltration.

    Science.gov (United States)

    Dimitroula, Helen; Syranidou, Evdokia; Manousaki, Eleni; Nikolaidis, Nikolaos P; Karatzas, George P; Kalogerakis, Nicolas

    2015-01-08

    A constructed wetland pilot with Juncus acutus L. plants was investigated for its rhizofiltration efficiency in treating Cr(VI)-contaminated groundwater. Measurements of Cr(VI) and total Cr were performed to estimate the rate of removal. In addition, Cr concentration in plant tissues was measured and the role of endophytic bacteria on plant's tolerance to Cr(VI) toxicity was investigated. The results support that J. acutus is able to rhizofiltrate Cr(VI) from contaminated water with up to 140μg/L while Cr content analysis in plant tissues revealed that the majority of Cr was accumulated by the plants. Moreover, two leaf (Acidovorax sp. strain U3 and Ralstonia sp. strain U36) isolated endophytic bacteria were found to tolerated 100mg/L Cr(VI) while nine root isolates showed resistance to 500mg/L Cr(VI). The endophytic bacteria Pseudomonas sp. strain R16 and Ochrobactrum sp. strain R24 were chosen for Cr(VI) reduction assays. All four strains exhibited a strong potential to reduce Cr(VI) to Cr(III) aerobically. Among them Pseudomonas sp. strain R16 was found able to completely reduced 100mg/L Cr(VI) after 150h of incubation. These results suggest that J. acutus is an excellent choice for CWs whose function is the removal of Cr(VI) from contaminated groundwater for subsequent use in crop irrigation.

  15. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data.

  16. Assessment of undiscovered oil and gas resources of the Dnieper-Donets Basin Province and Pripyat Basin Province, Russia, Ukraine, and Belarus, 2010

    Science.gov (United States)

    Klett, T.R.

    2011-01-01

    The U.S. Geological Survey, using a geology-based assessment methodology, estimated mean volumes of technically recoverable, conventional, undiscovered petroleum resources at 84 million barrels of crude oil, 4.7 trillion cubic feet of natural gas, and 130 million barrels of natural gas liquids for the Dnieper-Donets Basin Province and 39 million barrels of crude oil, 48 billion cubic feet of natural gas, and 1 million barrels of natural gas liquids for the Pripyat Basin Province. The assessments are part of a program to estimate these resources for priority basins throughout the world.

  17. Geology and hydrocarbon potential of the Oued Mya basin, Algeria

    Energy Technology Data Exchange (ETDEWEB)

    Benamrane, O.; Messaoudi, M.; Messelles, H. (Sonatrach Division Exploration, Algiers (Algeria))

    1993-09-01

    The Oued Mya hydrocarbon system is located in the Sahara basin. It is one of the best producing basins in Algeria, along with the Ghadames and Illizi basins. The stratigraphic section consists of Paleozoic and Mesozoic, and is about 5000 m thick. This intracratonic basin is limited to the north by the Toughourt saddle, and to the west and east it is flanked by regional arches, Allal-Tilghemt and Amguid-Hassi Messaoud, which culminate in the super giant Hassi Messaoud and Hassi R'mel hydrocarbon accumulations, respectively, producing oil from the Cambrian sands and gas from the Trissic sands. The primary source rock in this basin is lower Silurian shale, with an average thickness of 50 m and a total organic carbon of 6% (14% in some cases). Results of maturation modeling indicate that the lower Silurian source is in the oil window. The Ordovician shales are also source rocks, but in a second order. Clastic reservoirs are in the Trissic sequence, which is mainly fluvial deposits with complex alluvial channels, and the main target in the basin. Clastic reservoirs in the lower Devonian section have a good hydrocarbon potential east of the basin through a southwest-northwest orientation. The Late Trissic-Early Jurassic evaporites that overlie the Triassic clastic interval and extend over the entire Oued Mya basin, are considered to be a super-seal evaporite package, which consists predominantly of anhydrite and halite. For paleozoic targets, a large number of potential seals exist within the stratigraphic column. This super seal does not present oil dismigration possibilities. We can infer that a large amount of the oil generated by the Silurian source rock from the beginning of Cretaceous until now still is not discovered and significantly greater volumes could be trapped within structure closures and mixed or stratigraphic traps related to the fluvial Triassic sandstones, marine Devonian sands, and Cambrian-Ordovician reservoirs.

  18. Frontier petroleum basins of Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Keith, J.F. Jr.; Perez, V.E.

    1989-03-01

    The frontier basins of Colombia with hydrocarbon potential are numerous, have varying geological histories, and are in different stages of exploration development. In this paper, sedimentary or structural basins are classified as frontier petroleum basins if commercial discoveries of hydrocarbons are lacking, if the basin has not attained a high degree of exploration development, or if a new play concept has been perceived or developed for a portion of a mature exploration basin. Using these criteria for classification, the authors discuss the Cauca-Patia Choco-Pacifico, and Lower Magdalena basin complexes; the Cordillera Oriental foreland basin; and the Cesar-Rancheria, Sabana, and Amazonas basins. A comprehensive geological and structural setting of each of these frontier basins will be presented. The depositional and tectonic evolution of the basins will be highlighted, and the play concepts for each will be inventoried, catalogued, and categorized as to whether they are theoretical or established. The discussion of the available plays in each of these basins will include the main play concept elements of reservoirs traps, seals, source rocks, maturation, and timing. When detailed data permit, the reservoir and trap geometry will be presented.

  19. Importance of c-Type cytochromes for U(VI reduction by Geobacter sulfurreducens

    Directory of Open Access Journals (Sweden)

    Leang Ching

    2007-03-01

    Full Text Available Abstract Background In order to study the mechanism of U(VI reduction, the effect of deleting c-type cytochrome genes on the capacity of Geobacter sulfurreducens to reduce U(VI with acetate serving as the electron donor was investigated. Results The ability of several c-type cytochrome deficient mutants to reduce U(VI was lower than that of the wild type strain. Elimination of two confirmed outer membrane cytochromes and two putative outer membrane cytochromes significantly decreased (ca. 50–60% the ability of G. sulfurreducens to reduce U(VI. Involvement in U(VI reduction did not appear to be a general property of outer membrane cytochromes, as elimination of two other confirmed outer membrane cytochromes, OmcB and OmcC, had very little impact on U(VI reduction. Among the periplasmic cytochromes, only MacA, proposed to transfer electrons from the inner membrane to the periplasm, appeared to play a significant role in U(VI reduction. A subpopulation of both wild type and U(VI reduction-impaired cells, 24–30%, accumulated amorphous uranium in the periplasm. Comparison of uranium-accumulating cells demonstrated a similar amount of periplasmic uranium accumulation in U(VI reduction-impaired and wild type G. sulfurreducens. Assessment of the ability of the various suspensions to reduce Fe(III revealed no correlation between the impact of cytochrome deletion on U(VI reduction and reduction of Fe(III hydroxide and chelated Fe(III. Conclusion This study indicates that c-type cytochromes are involved in U(VI reduction by Geobacter sulfurreducens. The data provide new evidence for extracellular uranium reduction by G. sulfurreducens but do not rule out the possibility of periplasmic uranium reduction. Occurrence of U(VI reduction at the cell surface is supported by the significant impact of elimination of outer membrane cytochromes on U(VI reduction and the lack of correlation between periplasmic uranium accumulation and the capacity for uranium

  20. Hanford spent nuclear fuel project recommended path forward, volume III: Alternatives and path forward evaluation supporting documentation

    Energy Technology Data Exchange (ETDEWEB)

    Fulton, J.C.

    1994-10-01

    Volume I of the Hanford Spent Nuclear Fuel Project - Recommended Path Forward constitutes an aggressive series of projects to construct and operate systems and facilities to safely retrieve, package, transport, process, and store K Basins fuel and sludge. Volume II provided a comparative evaluation of four Alternatives for the Path Forward and an evaluation for the Recommended Path Forward. Although Volume II contained extensive appendices, six supporting documents have been compiled in Volume III to provide additional background for Volume II.

  1. Removal of Cr(VI) by zero-valent, iron-encapsulated alginate beads

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xue Song; Tang, Yu Jun; Chen, Li Fang; Li, Fei Yan; Wan, Wen Ya; Tan, Ye Bin [Department of Chemical Engineering, Huaihai Institute of Technology, Jiangsu (China)

    2010-03-15

    Zero-valent, iron-encapsulated alginate beads were synthesized and were applied for the removal of Cr(VI) from aqueous solutions. The effects of several important parameters including solution pH, contact time, initial concentration and reaction temperature on Cr(VI) removal levels were investigated in batch studies. An initial solution pH of 1.0 was seen to be most favorable for Cr(VI) removal. The removal process was quick and almost 80% of the removal was attained within 60 min. The kinetic data followed the second-order equation well. The Cr(VI) removal was almost reaction temperature-independent and decreased with an increase in Cr(VI) initial concentration. The removal of Cr(VI) by iron-encapsulated alginate beads was found to be significantly higher than that of non-encapsulated alginate beads. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  2. Summary of the planning, management, and evaluation process for the Geothermal Program Review VI conference

    Energy Technology Data Exchange (ETDEWEB)

    1988-10-01

    The purpose of this document is to present an overview of the planning, facilitation, and evaluation process used to conduct the Geothermal Program Review VI (PR VI) conference. This document was also prepared to highlight lessons learned from PR VI and, by utilizing the evaluation summaries and recommendations, be used as a planning tool for PR VII. The conference, entitled Beyond Goals and Objectives,'' was sponsored by the US Department of Energy's (DOE) Geothermal Technology Division (GTD), PR VI was held in San Francisco, California on April 19--21, 1988 and was attended by 127 participants. PR VI was held in conjunction with the National Geothermal Association's (NGA) Industry Round Table. This document presents a brief summary of the activities, responsibilities, and resources for implementing the PR VI meeting and provides recommendations, checklists, and a proposed schedule for assisting in planning PR VII.

  3. Remediation of Cr(VI)-Contaminated Soil Using the Acidified Hydrazine Hydrate.

    Science.gov (United States)

    Ma, Yameng; Li, Fangfang; Jiang, Yuling; Yang, Weihua; Lv, Lv; Xue, Haotian; Wang, Yangyang

    2016-09-01

    Acidified hydrazine hydrate was used to remediate Cr(VI)-contaminated soil. The content of water-soluble Cr(VI) in contaminated soil was 4977.53 mg/kg. The optimal initial pH of hydrazine hydrate solution, soil to solution ratio and molar ratio of Cr(VI) to hydrazine hydrate for remediation of Cr(VI)-contaminated soil were 5.0, 3:1 and 1:3, respectively. Over 99.50 % of water-soluble Cr(VI) in the contaminated soil was reduced at the optimal condition within 30 min. The remediated soil can keep stable within 4 months. Meanwhile the total phosphorus increased from 0.47 to 4.29 g/kg, indicating that using of acidified hydrazine hydrate is an effective method to remediate Cr(VI)-contaminated soil.

  4. Bioreduction of U(VI) in the presence of phosphate

    Science.gov (United States)

    Boyanov, M. I.; Mishra, B.; Latta, D. E.; Rui, X.; Kwon, M.-J.; Fletcher, K. E.; Loeffler, F. E.; O'Loughlin, E. J.; Kemner, K. M.

    2012-04-01

    Phosphate/phosphoryl moieties are ubiquitous in biological and environmental systems and can potentially affect the speciation of uranium during natural attenuation or stimulated bioremediation processes. The reactivity between U(VI) and phosphate has been studied extensively, but the significant influence of phosphate groups on the formation of reduced U(IV) species has only recently been recognized. We will compare and contrast the bioreduction of dissolved and solid-phase U(VI) by Gram-positive and Gram-negative metal-reducing bacteria (Shewanella, Anaeromyxobacter, Geobacter, and Desulfitobacterium) in the presence and absence of phosphate, from the perspective of solid-phase U speciation as determined by U L-edge x-ray absorption spectroscopy (XANES and EXAFS). In all cases examined, the presence of phosphate at concentrations of P/U > 1 led to the formation of reduced, inner-sphere complexed U(IV)-phosphate species that prevented the lowest-solubility U(IV) mineral uraninite (UO2) from forming over at least several months. In the absence of phosphate, nanoparticulate uraninite or complexed non-uraninite U(IV) species were observed (depending on the system and conditions), suggesting that the interplay between the chemical conditions at the location of electron transfer to U(VI) control the U(IV) product and subsequently the stability of reduced U. The importance of non-uraninite U(IV) species will be discussed in the context of their predominance in biostimulated sediments from the Oak Ridge field site in the United States.

  5. MONTHLY AVERAGE FLOW IN RÂUL NEGRU HYDROGRAPHIC BASIN

    Directory of Open Access Journals (Sweden)

    VIGH MELINDA

    2014-03-01

    Full Text Available Râul Negru hydrographic basin represents a well individualised and relatively homogenous physical-geographical unity from Braşov Depression. The flow is controlled by six hydrometric stations placed on the main collector and on two of the most powerful tributaries. Our analysis period is represented by the last 25 years (1988 - 2012 and it’s acceptable for make pertinent conclusions. The maximum discharge month is April, that it’s placed in the high flow period: March – June. Minimum discharges appear in November - because of the lack of pluvial precipitations; in January because of high solid precipitations and because of water volume retention in ice. Extreme discharge frequencies vary according to their position: in the mountain area – small basin surface; into a depression – high basin surface. Variation coefficients point out very similar variation principles, showing a relative homogeneity of flow processes.

  6. Adsorption of Chromium(VI) from Aqueous Solutions by Coffee Polyphenol-Formaldehyde/Acetaldehyde Resins

    OpenAIRE

    2013-01-01

    Removal of chromium(VI) from wastewater is essential as it is toxic. Thus, removal of chromium(VI) was performed using coffee polyphenol-formaldehyde/acetaldehyde resins as adsorbents. Adsorbent resins were prepared by condensation of decaffeinated coffee powder with formaldehyde/acetaldehyde and used for the removal of Cr(VI) ions from aqueous solutions. A simple and sensitive solid phase extraction procedure was applied for the determination of chromium at trace levels by spectroscopic meth...

  7. Determination of thoracic and inhalable fraction of sulfuric acid(VI) in workplace air

    OpenAIRE

    Małgorzata Szewczyńska; Małgorzata Pośniak; Emilia Pągowska

    2016-01-01

    Background: The article presents the results of the determination of the inhalable and thoracic fraction of sulfuric acid(VI) in 3 workplaces producing or processing this chemical. Material and Methods: To collect thoracic fractions of sulfuric acid(VI) Parallel Particle Impactor (PPI) was used. To isolate inhalable fraction of sulfuric acid(VI) from the air we used a sampler developed at the Institute of Occupational Medicine (IOM), United Kingdom. Parallel Particle Impactor and IOM samplers...

  8. Adsorption of chromium ion (VI) by acid activated carbon

    OpenAIRE

    A. A. Attia; Khedr,S. A.; Elkholy,S. A.

    2010-01-01

    The activated carbon produced from olive stones was chemically activated using sulfuric acid, (OS-S), and utilized as an adsorbent for the removal of Cr(VI) from aqueous solution in the concentration range 4-50 mg/L. Adsorption experiments were carried out in a batch process and various experimental parameters such as effect of contact time, initial chromium ion concentration, carbon dosage, and pH on percentage removal have been studied. Adsorption results obtained for activated carbon (OS-S...

  9. A uranium (VI) complex: Synthesis, structural and thermal kinetic analysis

    Science.gov (United States)

    Goel, Nidhi

    2016-08-01

    A new complex [UO2(2,6-DNP)2phen] (1) (2,6-DNP = 2,6-dinitrophenol, phen = 1,10-phenanthroline) was synthesized, and identified by elemental analysis, IR, Powder XRD and single crystal X-ray crystallography. Crystal structure provides the abundant information's about the bonding and geometry around the U(VI) metal center. The thermal decomposition was studied by TG-DSC, and the kinetics of thermolysis was investigated by applying model fitting as well as isoconversional methods. Explosion delay measurement (De) was also evaluated to determine the response of this complex under the condition of rapid heating.

  10. Hvordan finder vi den gode jordbærsmag?

    DEFF Research Database (Denmark)

    Bech, Anne Catharina; Nielsen, Stig F.

    1997-01-01

    I denne artikel vil vi forsøge at belyse "jordbærsmag" fra forskellige synsvinkler, og komme med forslag til metoder der kan anvendes til at øge vores viden på området, således at det fremover bliver muligt at forsyne det danske marked med jordbær med gode smagsegenskaber. Ofte anvendes begrebet ......, hvad bærrerne skal anvendes til. Derudover kan forhold som tilgængelighed, årstid, pris og emballage spille ind....

  11. In-orbit RF test of an Intelsat VI spacecraft

    Science.gov (United States)

    Rosell, Gunnar E. G.; Teixeira, Basilio; Olimpiew, Alexandre; Petterson, Bengt A.; Sanders, Stewart B.

    An account is given of the RF in-orbit test (IOT) conducted to verify the performance of Intelsat VI's antennas and transponders, as well as its telemetry, command, and ranging subsystems. Attention is given to novel measurement methods developed and implemented at the Intelsat IOT station in Fucino, Italy; these encompass synthesized digital spectrum analyzers, fast frequency-switching synthesizers, and dual-pulse generator controls. The IOT measurements obtained for the Intelsat 602 spacecraft are found to be in good agreement with prelaunch data.

  12. SAVANNAH RIVER SITE R REACTOR DISASSEMBLY BASIN IN SITU DECOMMISSIONING

    Energy Technology Data Exchange (ETDEWEB)

    Langton, C.; Blankenship, J.; Griffin, W.; Serrato, M.

    2009-12-03

    The US DOE concept for facility in-situ decommissioning (ISD) is to physically stabilize and isolate in tact, structurally sound facilities that are no longer needed for their original purpose of, i.e., generating (reactor facilities), processing(isotope separation facilities) or storing radioactive materials. The 105-R Disassembly Basin is the first SRS reactor facility to undergo the in-situ decommissioning (ISD) process. This ISD process complies with the105-R Disassembly Basin project strategy as outlined in the Engineering Evaluation/Cost Analysis for the Grouting of the R-Reactor Disassembly Basin at the Savannah River Site and includes: (1) Managing residual water by solidification in-place or evaporation at another facility; (2) Filling the below grade portion of the basin with cementitious materials to physically stabilize the basin and prevent collapse of the final cap - Sludge and debris in the bottom few feet of the basin will be encapsulated between the basin floor and overlying fill material to isolate if from the environment; (3) Demolishing the above grade portion of the structure and relocating the resulting debris to another location or disposing of the debris in-place; and (4) Capping the basin area with a concrete slab which is part of an engineered cap to prevent inadvertent intrusion. The estimated total grout volume to fill the 105-R Reactor Disassembly Basin is 24,424 cubic meters or 31,945 cubic yards. Portland cement-based structural fill materials were design and tested for the reactor ISD project and a placement strategy for stabilizing the basin was developed. Based on structural engineering analyses and work flow considerations, the recommended maximum lift height is 5 feet with 24 hours between lifts. Pertinent data and information related to the SRS 105-R-Reactor Disassembly Basin in-situ decommissioning include: regulatory documentation, residual water management, area preparation activities, technology needs, fill material designs

  13. Cr(VI) reduction by gluconolactone and hydrogen peroxide, the reaction products of fungal glucose oxidase: Cooperative interaction with organic acids in the biotransformation of Cr(VI).

    Science.gov (United States)

    Romo-Rodríguez, Pamela; Acevedo-Aguilar, Francisco Javier; Lopez-Torres, Adolfo; Wrobel, Kazimierz; Wrobel, Katarzyna; Gutiérrez-Corona, J Félix

    2015-09-01

    The Cr(VI) reducing capability of growing cells of the environmental A. tubingensis Ed8 strain is remarkably efficient compared to reference strains A. niger FGSC322 and A. tubingensis NRRL593. Extracellular glucose oxidase (GOX) activity levels were clearly higher in colonies developed in solid medium and in concentrated extracts of the spent medium of liquid cultures of the Ed8 strain in comparison with the reference strains. In addition, concentrated extracts of the spent medium of A. tubingensis Ed8, but not those of the reference strains, exhibited the ability to reduce Cr(VI). In line with this observation, it was found that A. niger purified GOX is capable of mediating the conversion of Cr(VI) to Cr(III) in a reaction dependent on the presence of glucose that is stimulated by organic acids. Furthermore, it was found that a decrease in Cr(VI) may occur in the absence of the GOX enzyme, as long as the reaction products gluconolactone and hydrogen peroxide are present; this conversion of Cr(VI) is stimulated by organic acids in a reaction that generates hydroxyl radicals, which may involve the formation of an intermediate peroxichromate(V) complex. These findings indicated that fungal glucose oxidase acts an indirect chromate reductase through the formation of Cr(VI) reducing molecules, which interact cooperatively with other fungal metabolites in the biotransformation of Cr(VI).

  14. Cr(VI) Adsorption on Red Mud Modified by Lanthanum: Performance, Kinetics and Mechanisms

    Science.gov (United States)

    Cui, You-Wei; Li, Jie; Du, Zhao-Fu; Peng, Yong-Zhen

    2016-01-01

    Water pollution caused by the highly toxic metal hexavalent chromium (Cr(VI)) creates significant human health and ecological risks. In this study, a novel adsorbent was used to treat Cr(VI)-containing wastewater; the adsorbent was prepared using red mud (RM) generated from the alumina production industry and the rare earth element lanthanum. This study explored adsorption performance, kinetics, and mechanisms. Results showed that the adsorption kinetics of the RM modified by lanthanum (La-RM), followed the pseudo-second-order model, with a rapid adsorption rate. Cr(VI) adsorption was positively associated with the absorbent dose, pH, temperature, and initial Cr(VI) concentration; coexisting anions had little impact. The maximum Cr(VI) adsorption capacity was 17.35 mg/g. Cr(VI) adsorption on La-RM was a mono-layer adsorption pattern, following the Langmuir isotherm model. Thermodynamic parameters showed the adsorption was spontaneous and endothermic. The adsorption of Cr(VI) on La-RM occurred as a result of LaOCl formation on the RM surface, which in turn further reacted with Cr(VI) in the wastewater. This study highlighted a method for converting industrial waste into a valuable material for wastewater treatment. The novel absorbent could be used as a potential adsorbent for treating Cr(VI)-contaminating wastewater, due to its cost-effectiveness and high adsorption capability. PMID:27658113

  15. The distribution and kinematics of interstellar O~{\\small VI} in the Milky Way}

    CERN Document Server

    Sarma, Rathin; Murthy, Jayanta; Sarma, Jayanta K

    2016-01-01

    We present the results of a survey of interstellar O~{\\small VI} absorption in the Milky Way (MW) towards {69} stars in the Large Magellanic Cloud (LMC) obtained with the \\textit{Far Ultraviolet Spectroscopic Explorer (FUSE)}. The integrated MW O~{\\small VI} column densities log N(O~{\\small VI}) are in the range from 13.68 to 14.73 with a mean of {14.26$_{-0.09}^{+0.07}$} atoms cm$^{-2}$. The O~{\\small VI} exponential scale height is found to be {2.28$\\pm$1.06} kpc. The O~{\\small VI} column density correlates with the Doppler parameter $\\it b$. The O~{\\small VI} velocity dispersion ranges from {14.0 to 91.6 with an average value of 62.7 km s$^{-1}$}. These high values of velocity dispersion reveal the effect of turbulence, multiple velocity components and collision on broad O~{\\small VI} profiles. There is a significant variation of O~{\\small VI} column density on all scales studied {(0.0025$\\degr$ - 6.35$\\degr$)}. The smallest scale for which O~{\\small VI} column density variations has been found is {$\\bigtr...

  16. Identification of Type VI Collagen Synthesizing Cells in Human Diabetic Glomerulosclerosis Using Renal Biopsy Sections

    Directory of Open Access Journals (Sweden)

    Mohammed Shawkat Razzaque

    1997-01-01

    Full Text Available Although the role of extracellular matrices in the development of glomerulosclerosis has been discussed widely, the cellular origin of type VI collagen in diabetic nephropathy (DN has remained relatively unexplored. This study reports the distribution and cellular origin of type VI collagen in DN. Type VI collagen‐specific oligonucleotide probes and monoclonal antibody were used to assess the relative expression of mRNA for \\alpha1 (VI chain and its translated protein in paraffin‐embedded renal biopsy sections of DN. By immunohistochemistry, compared to the control, increased deposition of type VI collagen was noted in the diffuse and nodular lesions of diabetic glomeruli. For cellular localization of type VI collagen mRNA, paraffin‐embedded renal sections of the control and DN were hybridized in situ with digoxigenin (Dig‐labeled antisense oligo‐DNA probe complementary to a part of \\alpha1 (VI mRNA. In comparison to the control kidney sections, increased numbers of intraglomerular cells (both mesangial and epithelial cells were positive for α1 (VI mRNA in renal biopsy sections of DN. From the results, we conclude that overexpression of type VI collagen by intraglomerular cells with its increased deposition might significantly contribute to the glomerulosclerosis found in DN.

  17. Cr(VI) Adsorption on Red Mud Modified by Lanthanum: Performance, Kinetics and Mechanisms.

    Science.gov (United States)

    Cui, You-Wei; Li, Jie; Du, Zhao-Fu; Peng, Yong-Zhen

    Water pollution caused by the highly toxic metal hexavalent chromium (Cr(VI)) creates significant human health and ecological risks. In this study, a novel adsorbent was used to treat Cr(VI)-containing wastewater; the adsorbent was prepared using red mud (RM) generated from the alumina production industry and the rare earth element lanthanum. This study explored adsorption performance, kinetics, and mechanisms. Results showed that the adsorption kinetics of the RM modified by lanthanum (La-RM), followed the pseudo-second-order model, with a rapid adsorption rate. Cr(VI) adsorption was positively associated with the absorbent dose, pH, temperature, and initial Cr(VI) concentration; coexisting anions had little impact. The maximum Cr(VI) adsorption capacity was 17.35 mg/g. Cr(VI) adsorption on La-RM was a mono-layer adsorption pattern, following the Langmuir isotherm model. Thermodynamic parameters showed the adsorption was spontaneous and endothermic. The adsorption of Cr(VI) on La-RM occurred as a result of LaOCl formation on the RM surface, which in turn further reacted with Cr(VI) in the wastewater. This study highlighted a method for converting industrial waste into a valuable material for wastewater treatment. The novel absorbent could be used as a potential adsorbent for treating Cr(VI)-contaminating wastewater, due to its cost-effectiveness and high adsorption capability.

  18. [Efficacy and side effects following immunization with Salmonella typhi Vi capsular polysaccharide vaccine].

    Science.gov (United States)

    Wang, Z G; Zhou, W Z; Shi, J

    1997-02-01

    Efficacy and side effects following the immunization with Salmonella typhi Vi capsular polysaccharide vaccine (Vi) were assessed. The diluted solution (DS) of Vi was used as placebo. A total number of 777 children and adults were observed for side effect response. Mild and moderate fever appeared 16.93% and 0.05% in Vi group, 15.01% and 0.03% in DS group, respectively (statistically significant). Two cases with mild local reaction were observed in Vi group. A total number of 81,506 vaccinees were investigated on the efficacy of Vi vaccine, using positive blood culture of Salmonolla typhi as a diagnostic criterion. The protective rate and index of vaccine were 71.35% and 3.49% respectively. If 2 cases of positive Widal's test were included in, the protective rate would come up to 78.17% with a protective index 4.85. Clinical data showed that fever seen in the cases in Vi group was much lower than that of DS group. The systematic and local reaction of Vi vaccine were mild. The vaccine is safe and has high protective rate. It can also decrease the degree of fever with only one single dose as primary immunization. We believe Vi vaccine may serve as a vaccine of new generation to be promoted.

  19. Myosin VI regulates actin structure specialization through conserved cargo-binding domain sites.

    Directory of Open Access Journals (Sweden)

    Mamiko Isaji

    Full Text Available Actin structures are often stable, remaining unchanged in organization for the lifetime of a differentiated cell. Little is known about stable actin structure formation, organization, or maintenance. During Drosophila spermatid individualization, long-lived actin cones mediate cellular remodeling. Myosin VI is necessary for building the dense meshwork at the cones' fronts. We test several ideas for myosin VI's mechanism of action using domain deletions or site-specific mutations of myosin VI. The head (motor and globular tail (cargo-binding domains were both needed for localization at the cone front and dense meshwork formation. Several conserved partner-binding sites in the globular tail previously identified in vertebrate myosin VI were critical for function in cones. Localization and promotion of proper actin organization were separable properties of myosin VI. A vertebrate myosin VI was able to localize and function, indicating that functional properties are conserved. Our data eliminate several models for myosin VI's mechanism of action and suggest its role is controlling organization and action of actin assembly regulators through interactions at conserved sites. The Drosophila orthologues of interaction partners previously identified for vertebrate myosin VI are likely not required, indicating novel partners mediate this effect. These data demonstrate that generating an organized and functional actin structure in this cell requires multiple activities coordinated by myosin VI.

  20. Microbial culture dynamics and chromium (VI) removal in packed-column microcosm reactors.

    Science.gov (United States)

    Molokwane, Pulane E; Nkhalambayausi-Chirwa, Evans M

    2009-01-01

    Microbial Cr(VI) reduction in groundwater aquifer media was investigated in microcosm reactors extracted from Cr(VI) contaminated sites in South Africa. The reactors were operated under an influent Cr(VI) concentration of 40 mg/L to simulate the current Cr(VI) level at the contaminated site. Near complete Cr(VI) removal was observed in microcosm reactors inoculated with Cr(VI) reducing bacteria from dried activated sludge collected from a treatment plant receiving periodic loadings of Cr(VI). The best performance was observed under low hydraulic loading (flow rate, Q=0.310 cm(3)/hr). Microbial culture characterisation results showed a change in culture composition after 17 days of reactor operation, indicating Bacillus and Lysinibacillus species as the most dominant organisms in reactors that reduced Cr(VI). The predominance of Bacillus and Lysinibacillus species was either due to resilience against toxicity or adaptation to the changing conditions in the reactor. This research was the initial step towards the development of an in situ bioremediation process to contain the spread of a Cr(VI) plume in a groundwater aquifer at contaminated site in Brits, South Africa. South Africa holds about 72% percent of the world's chromium resources, the majority of which is mined in the North Eastern region of the country formally known as Transvaal.

  1. Transient groundwater chemistry near a river: Effects on U(VI) transport in laboratory column experiments

    Science.gov (United States)

    Yin, Jun; Haggerty, Roy; Stoliker, Deborah L.; Kent, Douglas B.; Istok, Jonathan D.; Greskowiak, Janek; Zachara, John M.

    2011-01-01

    In the 300 Area of a U(VI)-contaminated aquifer at Hanford, Washington, USA, inorganic carbon and major cations, which have large impacts on U(VI) transport, change on an hourly and seasonal basis near the Columbia River. Batch and column experiments were conducted to investigate the factors controlling U(VI) adsorption/desorption by changing chemical conditions over time. Low alkalinity and low Ca concentrations (Columbia River water) enhanced adsorption and reduced aqueous concentrations. Conversely, high alkalinity and high Ca concentrations (Hanford groundwater) reduced adsorption and increased aqueous concentrations of U(VI). An equilibrium surface complexation model calibrated using laboratory batch experiments accounted for the decrease in U(VI) adsorption observed with increasing (bi)carbonate concentrations and other aqueous chemical conditions. In the column experiment, alternating pulses of river and groundwater caused swings in aqueous U(VI) concentration. A multispecies multirate surface complexation reactive transport model simulated most of the major U(VI) changes in two column experiments. The modeling results also indicated that U(VI) transport in the studied sediment could be simulated by using a single kinetic rate without loss of accuracy in the simulations. Moreover, the capability of the model to predict U(VI) transport in Hanford groundwater under transient chemical conditions depends significantly on the knowledge of real-time change of local groundwater chemistry.

  2. Chromium(VI) transport and fate in unsaturated zone and aquifer: 3D Sandbox results.

    Science.gov (United States)

    Zhao, Xingmin; Sobecky, Patricia A; Zhao, Lanpo; Crawford, Patrice; Li, Mingtang

    2016-04-01

    The simulation of Cr(VI) behavior in an unsaturated zone and aquifer, using a 3D experimental set-up were performed to illustrate the distribution, transport and transformation of Cr(VI), and further to reveal the potential harm of Cr(VI) after entering the groundwater. The result indicated that chromium(VI) was transported in the vertical direction, meanwhile, was transported in the horizontal direction under the influence of groundwater flow. The direction and distance away from the pollution source zone had great effect on the chromium(VI) concentration. At the sampling sites near the pollution source zone, there was a sudden increase of chromium(VI) concentration. The concentration of chromium(III) concentration in some random effluent samples was not detected. Chromium had not only transported but also had fraction and specie transformation in the unsaturated zone and aquifer. The relative concentration of residue fraction chromium was decreased with time. The content of Fe-Mn oxide fraction chromium was increased with time. The relative content of exchangeable and carbonate-bound fraction chromium was lower and the content variations were not obvious. Chromium(VI) (91-98%) was first reduced to chromium(III) rapidly. The oxidation reaction occurred later and the relative content of chromium(VI) was increased again. The presence of manganese oxides under favorable soil conditions can promote the reoxidation of Cr(III) to Cr(VI).

  3. Quorum regulatory small RNAs repress type VI secretion in Vibrio cholerae.

    Science.gov (United States)

    Shao, Yi; Bassler, Bonnie L

    2014-06-01

    Type VI secretion is critical for Vibrio cholerae to successfully combat phagocytic eukaryotes and to survive in the presence of competing bacterial species. V. cholerae type VI secretion system genes are encoded in one large and two small clusters. In V. cholerae, type VI secretion is controlled by quorum sensing, the cell-cell communication process that enables bacteria to orchestrate group behaviours. The quorum-sensing response regulator LuxO represses type VI secretion genes at low cell density and the quorum-sensing regulator HapR activates type VI secretion genes at high cell density. We demonstrate that the quorum regulatory small RNAs (Qrr sRNAs) that function between LuxO and HapR in the quorum-sensing cascade are required for these regulatory effects. The Qrr sRNAs control type VI secretion via two mechanisms: they repress expression of the large type VI secretion system cluster through base pairing and they repress HapR, the activator of the two small type VI secretion clusters. This regulatory arrangement ensures that the large cluster encoding many components of the secretory machine is expressed prior to the two small clusters that encode the secreted effectors. Qrr sRNA-dependent regulation of the type VI secretion system is conserved in pandemic and non-pandemic V. cholerae strains.

  4. Deep RNA profiling identified CLOCK and molecular clock genes as pathophysiological signatures in collagen VI myopathy.

    Science.gov (United States)

    Scotton, Chiara; Bovolenta, Matteo; Schwartz, Elena; Falzarano, Maria Sofia; Martoni, Elena; Passarelli, Chiara; Armaroli, Annarita; Osman, Hana; Rodolico, Carmelo; Messina, Sonia; Pegoraro, Elena; D'Amico, Adele; Bertini, Enrico; Gualandi, Francesca; Neri, Marcella; Selvatici, Rita; Boffi, Patrizia; Maioli, Maria Antonietta; Lochmüller, Hanns; Straub, Volker; Bushby, Katherine; Castrignanò, Tiziana; Pesole, Graziano; Sabatelli, Patrizia; Merlini, Luciano; Braghetta, Paola; Bonaldo, Paolo; Bernardi, Paolo; Foley, Reghan; Cirak, Sebahattin; Zaharieva, Irina; Muntoni, Francesco; Capitanio, Daniele; Gelfi, Cecilia; Kotelnikova, Ekaterina; Yuryev, Anton; Lebowitz, Michael; Zhang, Xiping; Hodge, Brian A; Esser, Karyn A; Ferlini, Alessandra

    2016-04-15

    Collagen VI myopathies are genetic disorders caused by mutations in collagen 6 A1, A2 and A3 genes, ranging from the severe Ullrich congenital muscular dystrophy to the milder Bethlem myopathy, which is recapitulated by collagen-VI-null (Col6a1(-/-)) mice. Abnormalities in mitochondria and autophagic pathway have been proposed as pathogenic causes of collagen VI myopathies, but the link between collagen VI defects and these metabolic circuits remains unknown. To unravel the expression profiling perturbation in muscles with collagen VI myopathies, we performed a deep RNA profiling in both Col6a1(-/-)mice and patients with collagen VI pathology. The interactome map identified common pathways suggesting a previously undetected connection between circadian genes and collagen VI pathology. Intriguingly, Bmal1(-/-)(also known as Arntl) mice, a well-characterized model displaying arrhythmic circadian rhythms, showed profound deregulation of the collagen VI pathway and of autophagy-related genes. The involvement of circadian rhythms in collagen VI myopathies is new and links autophagy and mitochondrial abnormalities. It also opens new avenues for therapies of hereditary myopathies to modulate the molecular clock or potential gene-environment interactions that might modify muscle damage pathogenesis.

  5. Synthesis of novel aminated cellulose microsphere adsorbent for efficient Cr(VI) removal

    Science.gov (United States)

    Yu, Tianlin; Liu, Siqi; Xu, Min; Peng, Jing; Li, Jiuqiang; Zhai, Maolin

    2016-08-01

    A novel aminated cellulose microsphere adsorbent (CVN) was successfully prepared by radiation-induced graft polymerization of vinylbenzyl chloride (VBC) onto cellulose microsphere (CMS), followed by amination. Micro-FTIR, XPS and SEM confirmed the structure of CVN. The adsorption behavior of Cr(VI) onto CVN from solution was well fitted by the pseudo-second order kinetic model. The isothermal adsorption of Cr(VI) was observed at pH 4.68 with adsorption capacity of 129 mg/g in accordance with Langmuir thermal model, and the removal of Cr(VI) from solution could be 91% at a low amount (20 mg) of adsorbent. The best pH for adsorption of Cr(VI) was nearly 3.08, and with the increasing of temperature, the adsorption capacity of Cr(VI) increased. XPS analysis confirmed the adsorption mechanism of Cr(VI) was ion-exchange mechanism, while common co-ions such as Na+, Mg2+, Cu2+, Ca2+, Zn2+, Ni2+, Cl-, NO3- has no significant effect on the adsorption capacity of Cr(VI), and the Cr(VI) removal of 80% still could be obtained compared with that of fresh CVN adsorbent. Finally, spent CVN could be regenerated under 2 mol/L NaCl. The work indicated that aminated cellulose adsorbent could be prepared successfully by radiation-induced grafting and amination and CVN is a promising bio-adsorbent in the removing Cr(VI) from waste water.

  6. Geology and hydrocarbon occurrences in the Ghadames Basin, Algeria, Tunisia, Libya

    Energy Technology Data Exchange (ETDEWEB)

    Echikh, K. [Petroleum Exploration Consulting Ltd., London (United Kingdom)

    1998-12-31

    The Ghadames Basin is a large intra-cratonic basin, covering portions of Algeria, Tunisia and Libya. The three countries are independently conducting petroleum exploration in their portions of the basin, using different play concepts and consequently obtaining different exploration results. This paper presents the first published basin-wide view of petroleum stratigraphy and play types. Some 700 exploratory wells have been drilled in the basin, resulting in the discovery of at least 150 oil pools with 9500 MMBO (million barrels of oil) in place. Most wells were located in the structurally higher parts of the basin, with deeper portions being less explored because of shifting dune conditions and an expectation of reservoir thinning into the basin centre. Silurian and Devonian source rocks occur across large parts of the basin and have generated volumes of hydrocarbon orders of magnitude above those discovered. The numerous structural phases (Taconic, Caledonian, Hercynian and Austrian) that have affected the basin have had important implications for depocentre migration, structural style, and for patterns of trap formation, alteration and destruction. (author)

  7. The Neuquén basin, Argentina: A case study in sequence stratigraphy and basin dynamics

    Institute of Scientific and Technical Information of China (English)

    Alberto C. Riccardi

    2006-01-01

    @@ As stated in one of the contributions to this volume, the Neuquen Basin-covering more than 160,000 km2 between c. 32° and 42° S and 68° and 71° W, and containing a Meso-zoic-Cenozoic sedimentary succession at least 7 km thick-is perhaps one of the most thoroughly prospected areas in Argentina. Its geological study goes back to the 19th Century, and shows an exponential increase throughout the 20th, when it became the main source of Argentine oil and gas production.

  8. The Historical Flood Of July 2008 From Vaser River Basin, Romania. Causes, Effects And Flood Control Actions

    Directory of Open Access Journals (Sweden)

    Sima Andrei

    2015-10-01

    Full Text Available Floods is an experience perceived by society as unexpected, unexplainable and traumatizing and nowadays a threat to humanity more than ever. Among the natural phenomena which negatively affect human activities, floods are the ones which usually have the most significant consequences. The research, evaluations and statistics related to these phenomena do not reveal the drama and serious consequences that come with floods. It was proven that the increase of these extreme hydrological phenomena it is closely related to the anthropic activities from the area. Vaser basin is the most significant sub-basin of Vișeu river basin, contributing with 28% from the total flow of Vișeu river. Having a strong touristic and economic potential, the basin is often threatened by flash floods which usually have devastating effects. During July 2008 there was recorded the most significant flood from the history of hydrometric activity that led to substantial damage and death among locals. The present paper aims to analyze this historical flood, identifying the causes, effects, as well as the methods to control this extreme hydric phenomenon.

  9. On halide derivatives of rare-earth metal(III) oxidomolybdates(VI) and -tungstates(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Schleid, Thomas; Hartenbach, Ingo [Stuttgart Univ. (Germany). Inst. for Inorganic Chemistry

    2016-11-01

    Halide derivatives of rare-earth metal(III) oxidomolybdates(VI) have been investigated comprehensively over the last decade comprising the halogens fluorine, chlorine, and bromine. Iodide-containing compounds are so far unknown. The simple composition REXMoO{sub 4} (RE=rare-earth element, X=halogen) is realized for X=F almost throughout the complete lanthanide series as well as for yttrium. While ytterbium and lutetium do not form any fluoride derivative, for lanthanum, only a fluoride-deprived compound with the formula La{sub 3}FMo{sub 4}O{sub 16} is realized. Moreover, molybdenum-rich compounds with the formula REXMo{sub 2}O{sub 7} are also known for yttrium and the smaller lanthanoids. For X=Cl the composition REClMoO{sub 4} is known for yttrium and the whole lanthanide series, although, four different structure types were identified. Almost the same holds for X=Br, however, only two different structure types are realized in this class of compounds. In the case of halide derivatives of rare-earth metal(III) oxidotungstates(VI) the composition REXWO{sub 4} is found for chlorides and bromides only, so far. Due to the similar size of Mo{sup 6+} and W{sup 6+} cations, the structures found for the tungstates are basically the same as for the molybdates. With the larger lanthanides, the representatives for both chloride and bromide derivates exhibit similar structural motifs as seen in the molybdates, however, the crystal structure cannot be determined reliably. In case of the smaller lanthanoids, the chloride derivatives are isostructural with the respective molybdates, although the existence ranges differ slightly. The same is true for rare-earth metal(III) bromide oxidotungstates(VI).

  10. Assessment of undiscovered oil and gas resources of the West Siberian Basin Province, Russia, 2010

    Science.gov (United States)

    Klett, T.R.

    2011-01-01

    The U.S. Geological Survey, using a geology-based assessment methodology, estimated mean volumes of technically recoverable, conventional, undiscovered petroleum resources at 8 billion barrels of crude oil, 670 trillion cubic feet of natural gas, and 21 billion barrels of natural gas liquids for the West Siberian Basin Province in Russia as part of a program to estimate petroleum resources for priority basins throughout the world.

  11. Nuclear proliferation and civilian nuclear power: report of the Nonproliferation Alternative Systems Assessment Program. Volume 1. Program summary

    Energy Technology Data Exchange (ETDEWEB)

    1979-12-01

    This report summarizes the Nonproliferation Alternative Systems Assessment Program (NASAP): its background, its studies, and its results. This introductory chapter traces the growth of the issue of nuclear weapons proliferation and the organization and objectives of NASAP. Chapter 2 summarizes the program's assessments, findings and recommendations. Each of Volumes II-VII reports on an individual assessment (Volume II: Proliferation Resistance; Volume III: Resources and Fuel Cycle Facilities; Volume IV: Commercial Potential; Volume V: Economics and Systems Analysis; Volume VI: Safety and Environmental Considerations for Licensing; Volume VII: International Perspectives). Volume VIII (Advanced Concepts) presents a combined assessment of several less fully developed concepts, and Volume IX (Reactor and Fuel Cycle Descriptions) provides detailed descriptions of the reactor and fuel-cycle systems studied by NASAP.

  12. A study of low-cost adsorbent materials for removing Cr(VI from aqueous waste effluent Estudio de materiales adsorbentes de bajo costo para remover Cr(VI de efluentes acuosos

    Directory of Open Access Journals (Sweden)

    Castillo Serna Elianna

    2011-05-01

    Full Text Available  

    The present paper shows very high potential for two types of solid (a commercial alumina and material obtained by composting, i.e. matured compost on Cr(VI adsorption/elimination in aqueous solution using a concentration range close to those previously detected in waste-water from Colombian industries. Both had important properties for eliminating Cr(VI, the compost being more important as it represents low-cost material. Optimal conditions for chromium adsorption on alumina and compost were established. Initial Cr(VI alumina concentration was 10 mgL-1, with 100 mL/g volume of solution per adsorbent mass, pH=2.0, 1 hour equilibrium time and 150 rpm stirring. For compost, initial Cr(VI concentration was = 3 mg L-1, 50 mL/g volume of solution per adsorbent mass, pH=2.5, 3 hour equilibrium time and 150 rpm stirring. The experiments showed that compost adsorption properties could be enhanced by adding small quantities of alumina. Compost could thus be chosen as a promising material for use in bioremediation chromium-containing waste water in a management programme for using solid waste in for minimising environmental impact.

     

     

    Adsorption of chromium ion (VI by acid activated carbon

    Directory of Open Access Journals (Sweden)

    A. A. Attia

    2010-03-01

    Full Text Available The activated carbon produced from olive stones was chemically activated using sulfuric acid, (OS-S, and utilized as an adsorbent for the removal of Cr(VI from aqueous solution in the concentration range 4-50 mg/L. Adsorption experiments were carried out in a batch process and various experimental parameters such as effect of contact time, initial chromium ion concentration, carbon dosage, and pH on percentage removal have been studied. Adsorption results obtained for activated carbon (OS-S were compared with the acid-treated commercial activated carbon (CAC-S. The optimum efficiency shows that the Cr(VI uptake being attained at pH 1.5. The equilibrium adsorption data was better fitted to the Langmuir adsorption model. The results of kinetic models showed that the pseudo-first-order kinetic model was found to correlate the experimental data well. It was concluded that activated carbon produced from olive stones (OS-S has an efficient adsorption capacity compared to (CAC-S sample.

  13. Large area radiation detectors based on II VI thin films

    Science.gov (United States)

    Quevedo-Lopez, Manuel

    2015-03-01

    The development of low temperature device technologies that have enabled flexible displays also present opportunities for flexible electronics and flexible integrated systems. Of particular interest are possible applications in flexible, low metal content, sensor systems for unattended ground sensors, smart medical bandages, electronic ID tags for geo-location, conformal antennas, neutron/gamma-ray/x-ray detectors, etc. In this talk, our efforts to develop novel CMOS integration schemes, circuits, memory, sensors as well as novel contacts, dielectrics and semiconductors for flexible electronics are presented. In particular, in this presentation we discuss fundamental materials properties including crystalline structure, interfacial reactions, doping, etc. defining performance and reliability of II-VI-based radiation sensors. We investigate the optimal thickness of a semiconductor diode for thin-film solid state thermal neutron detectors. Besides II-VI materials, we also evaluated several diode materials, Si, CdTe,GaAs, C (diamond), and ZnO, and two neutron converter materials,10B and 6LiF. We determine the minimum semiconductor thickness needed to achieve maximum neutron detection efficiency. By keeping the semiconductor thickness to a minimum, gamma rejection is kept as high as possible. In this way, we optimize detector performance for different thin-film semiconductor materials.

  14. vi-Strauss, Caduveo Body Painting and the Readymade

    DEFF Research Database (Denmark)

    Wiseman, Boris Nicholas Daniel

    2008-01-01

    of various forms of avant-garde art, from Duchamp's readymades, to Anthony Caro's abstract sculptures and assemblages by the Nouveau Réaliste artist Arman.  Although these forms of art would no doubt constitute, for Lévi-Strauss, instances of what he calls, pejoratively, an ‘academism of the signifier', I......The aim of this article is to explore some convergences between aesthetics and the anthropology of art, two disciplines often thought of as incompatible or mutually exclusive. Its impetus is the conviction that we have much to gain by a more systematic and concerted attempt at constituting an ethno...... will argue here that Lévi-Strauss's own theorisation of the relations between nature, culture and art enables us to see them, in at least one of their dimensions, as prime examples of the fulfilling of the mytho-poetic function. What I will place, here, at the core of mytho-poetic function, following a view...

  15. Recent Advances in Treatment Approaches of Mucopolysaccharidosis VI.

    Science.gov (United States)

    Giugliani, Roberto; Carvalho, Clarissa Gutiérrez; Herber, Silvani; de Camargo Pinto, Louise Lapagesse

    2011-06-01

    Mucopolysaccharidosis VI is caused by accumulation of the glycosaminoglycan dermatan sulfate in all tissues due to decreased activity of the enzyme arylsulfatase B. Patients exhibit multisystemic signs and symptoms in a chronic and progressive manner, especially with changes in the skeleton, cardiopulmonary system, cornea, skin, liver, spleen and meninges. Patients usually have normal intelligence. In the past, treatment of mucopolysaccharidoses was limited to palliative medical care. The outcome for affected patients improved with the introduction of new technologies as hematopoietic stem cell transplantation, relegated to specific situations after enzyme replacement therapy (ERT) became available. The specific ERT for MPS VI, galsulfase (Naglazyme®, Biomarin Pharmaceutical) was approved in 2005 by FDA and in 2006 by EMEA, and three clinical studies including 56 patients have evaluated the efficacy and safety. Long-term follow up data with patients treated up to 5 years showed that ERT is well tolerated and associated with sustained improvements in the patients' clinical condition. Intrathecal ERT may be considered in situations of high neurosurgical risk but still it is experimental in humans, as is intra-articular ERT. It is possible that the full impact of this therapy will only be demonstrated when patients are identified and treated soon after birth, as it was shown that early introduction of ERT produced immune tolerance and improved enzyme effectiveness in the cat model. New insights on the pathophysiology of MPS disorders are leading to alternative therapeutic approaches, as gene therapy, inflammatory response modulators and substrate reduction therapy.

  16. Geothermal Program Review VI: proceedings. Beyond goals and objectives

    Energy Technology Data Exchange (ETDEWEB)

    1988-01-01

    Program Review VI was comprised of six sessions, including an opening session, four technical sessions that addressed each of the major DOE research areas, and a session on special issues. The technical sessions were on Hydrothermal, Hot Dry Rock, Geopressured and Magma resources. Presenters in the technical sessions discussed their R and D activities within the context of specific GTD Programmatic Objectives for that technology, their progress toward achieving those objectives, and the value of those achievements to industry. The ''Special Issues'' presentations addressed several topics such as the interactions between government and industry on geothermal energy R and D; the origin and basis for the programmatic objectives analytical computer model; and international marketing opportunities for US geothermal equipment and services. The unique aspect of Program Review VI was that it was held in conjunction with the National Geothermal Association's Industry Round Table on Federal R and D. The Round Table provided a forum for open and lively discussions between industry and government researchers and gave industry an opportunity to convey their needs and perspectives on DOE's research programs. These discussions also provided valuable information to DOE regarding industry's priorities and directions.

  17. PRoViScout: a planetary scouting rover demonstrator

    Science.gov (United States)

    Paar, Gerhard; Woods, Mark; Gimkiewicz, Christiane; Labrosse, Frédéric; Medina, Alberto; Tyler, Laurence; Barnes, David P.; Fritz, Gerald; Kapellos, Konstantinos

    2012-01-01

    Mobile systems exploring Planetary surfaces in future will require more autonomy than today. The EU FP7-SPACE Project ProViScout (2010-2012) establishes the building blocks of such autonomous exploration systems in terms of robotics vision by a decision-based combination of navigation and scientific target selection, and integrates them into a framework ready for and exposed to field demonstration. The PRoViScout on-board system consists of mission management components such as an Executive, a Mars Mission On-Board Planner and Scheduler, a Science Assessment Module, and Navigation & Vision Processing modules. The platform hardware consists of the rover with the sensors and pointing devices. We report on the major building blocks and their functions & interfaces, emphasizing on the computer vision parts such as image acquisition (using a novel zoomed 3D-Time-of-Flight & RGB camera), mapping from 3D-TOF data, panoramic image & stereo reconstruction, hazard and slope maps, visual odometry and the recognition of potential scientifically interesting targets.

  18. Exploring Co-Authorship in 2 Henry VI

    Directory of Open Access Journals (Sweden)

    Darren Freebury-Jones

    2016-03-01

    Full Text Available The article explores the possibility extended by Hugh Craig and Arthur Kinney that 2 Henry VI is a collaborative play. Passages attributed to Peele and Shakespeare in Titus Andronicus were tested for ‘rare’ tetragrams (i.e. instances which occur less than five times in plays first performed between 1580-1600 in order to gain an insight into authorial borrowing and self-borrowing. In this respect, the article combines Martin Mueller’s work on tetragrams plus (four plus word sequences in ‘Shakespeare His Contemporaries’, with that of Ian Lancashire’s studies on authors’ working memories. The same methodology was also applied to passages attributed to Shakespeare and his co-author in Edward III. In particular, this study tests Act 3 of 2 Henry VI, which is considered Shakespeare’s primary contribution by Craig and Kinney, against the remainder of the play, in order to examine whether shared verbal parallels signify associative groupings at the forefront of Shakespeare’s mind as he composed the play, or whether these parallels indicate separate authorial cognitive processes.

  19. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    Energy Technology Data Exchange (ETDEWEB)

    Lucchini, Jean-francois [Los Alamos National Laboratory; Khaing, Hnin [Los Alamos National Laboratory; Reed, Donald T [Los Alamos National Laboratory

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  1. Removal of Cr(VI Species from Aqueous Solution by Different Nanoporous Materials

    Directory of Open Access Journals (Sweden)

    Mohammad Ghashghaee

    2016-10-01

    Full Text Available Background: The removal of toxic metals from sewage and wastewaters is one of the most important concerns in the twenty first century. The removal of poisonous Cr(VI from aqueous solution by different low-cost available nanoporous adsorbents was investigated in the present study. Methods: Fumed silica, bentonite (BN, hydrotalcite (HT, MCM-41, Na-Y, mordenite (MOR and SAPO-34 were used at different adsorbent-to-metal ion ratios. Two predominant species of Cr were considered including chromate and hydrogen chromate ions. Results: Both HT and Na-Y adsorbed the toxic bichromate ions more favorably than other sorbents. Overall, the efficiency of the Cr removal followed the sequence of HT > SAPO-34 > MOR > MCM-41 > Na-Y > silica > BN. Because of its surface chemistry, HT with an uptake of 65.2 mg/g showed the highest toxic abatement among the seven adsorbents investigated under the acidic conditions, followed by the microporous materials SAPO-34 and MOR with uptakes of 41.2 and 41.0 mg/g, respectively. Conclusion: Both HT and Na-Y adsorbed the toxic bichromate ions more favorably than other sorbents. The high pore volume and the apparent surface area of a non-functionalized MCM-41 were not effective in the adsorption of Cr compounds. Overall, HT was the best choice owing to its appropriate surface chemistry with respect to the Cr oxygenates.

  2. Automated determination of uranium(VI) at ultra trace levels exploiting flow techniques and spectrophotometric detection using a liquid waveguide capillary cell.

    Science.gov (United States)

    Avivar, Jessica; Ferrer, Laura; Casas, Montserrat; Cerdà, Víctor

    2010-05-01

    Rapid and fully automated multisyringe flow-injection analysis (MSFIA) with a multi-pumping flow system (MPFS) coupled to a long path-length liquid waveguide capillary cell (LWCC) is proposed for the determination of uranium(VI) at ultra trace levels. On-line separation and pre-concentration of uranium is carried out by means of a TRU resin. After elution, uranium(VI) is spectrophotometrically detected after reaction with arsenazo-III. Combination of the MSFIA and MPFS techniques with the TRU-resin enables the analysis to be performed in a short time, using large sample volumes and achieving high selectivity and sensitivity levels. A detection limit of 12.6 ng L(-1) (ppt) is reached for a 100-mL sample volume. The versatility of the proposed method also enables pre-concentration of variable sample volumes, enabling application of the analysis to a wide concentration range. Reproducibility of better than 5% and a resin durability of 40 injections should be emphasized. The developed method was successfully applied to different types of environmental sample matrices with recoveries between 95 and 108%.

  3. Development of a new Cr(VI)-biosorbent from agricultural biowaste.

    Science.gov (United States)

    Park, Donghee; Lim, Seong-Rin; Yun, Yeoung-Sang; Park, Jong Moon

    2008-12-01

    Among useless but abundant agricultural biowastes such as banana skin, green tea waste, oak leaf, walnut shell, peanut shell and rice husk, in this study, banana skin was screened as the most efficient biomaterial to remove toxic Cr(VI) from aqueous solution. X-ray photoelectron spectroscopy (XPS) study revealed that the mechanism of Cr(VI) biosorption by banana skin was its complete reduction into Cr(III) in both aqueous and solid phases and partial binding of the reduced-Cr(III), in the range of pH 1.5-4 tested. One gram of banana skin could reduce 249.6 (+/-4.2)mg of Cr(VI) at initial pH 1.5. Namely, Cr(VI)-reducing capacity of banana skin was four times higher than that of a common chemical Cr(VI)-reductant, FeSO(4).7H(2)O. To diminish undesirable/serious organic leaching from the biomaterial and to enhance removal efficiency of total Cr, its powder was immobilized within Ca-alginate bead. The developed Cr(VI)-biosorbent could completely reduce toxic Cr(VI) to less toxic Cr(III) and could remove almost of the reduced-Cr(III) from aqueous phase. On the basis of removal mechanisms of Cr(VI) and total Cr by the Cr(VI)-biosorbent, a kinetic model was derived and could be successfully used to predict their removal behaviors in aqueous phase. In conclusion, our Cr(VI)-biosorbent must be a potent candidate to substitute for chemical reductants as well as adsorbents for treating Cr(VI)-bearing wastewaters.

  4. Intracontinental basins and strong earthquakes

    Institute of Scientific and Technical Information of China (English)

    邓起东; 高孟潭; 赵新平; 吴建春

    2004-01-01

    The September 17, 1303 Hongtong M=8 earthquake occurred in Linfen basin of Shanxi down-faulted basin zone. It is the first recorded M=8 earthquake since the Chinese historical seismic records had started and is a great earthquake occurring in the active intracontinental basin. We had held a Meeting of the 700th Anniversary of the 1303 Hongtong M=8 Earthquake in Shanxi and a Symposium on Intracontinental Basins and Strong Earthquakes in Taiyuan City of Shanxi Province on September 17~18, 2003. The articles presented on the symposium discussed the relationships between active intracontinental basins of different properties, developed in different regions, including tensional graben and semi-graben basins in tensile tectonic regions, compression-depression basins and foreland basins in compressive tectonic regions and pull-apart basins in strike-slip tectonic zones, and strong earthquakes in China. In this article we make a brief summary of some problems. The articles published in this special issue are a part of the articles presented on the symposium.

  5. Basin Depth Control on the Autogenic Timescale of Fluviodeltaic Systems

    Science.gov (United States)

    Carlson, B.; Kim, W.; Piliouras, A.

    2013-12-01

    ABSTRACT Autogenic processes are inherent processes in sediment transport that influence landscape building and leave distinct signatures in the sedimentary record. It is of great interest to understand autogenic processes in order to decouple internal processes from external controls, such as tectonics or climate change. Here we present results from a series of delta-building experiments to determine the variability of the fluviodeltaic autogenic timescale in response to varying basin water depth. This internal timescale was measured as the time that is required for the delta topset to be reworked through a full cycle of storage and release of sediment. The topset aggrades by fluvial sedimentation until it reaches a maximum slope, at which point a large amount of sediment starts to release, typically resulting in strong channelization. This is followed by a period of avulsions, lateral migration, and backfilling of channels on the topset. These storage and release events are repeated. We used time-lapse images to track shoreline positions and observe changes in progradation rate. The changes in topset topography were also used to determine storage and release duration. The experimental results indicate that the autogenic timescales generally increase with increasing basin water depth. These observations may be explained by the amount of time required to build a lobe with an area large enough to trigger a switch from a lobe-building release event to a backfilling storage event. Individual lobes show a similar surface area regardless of basin depth in the experiments. Deeper basin depth simply requires a larger volume to be filled within this area, thus more time to complete one autogenic process. However, when channel depth is significantly smaller than basin depth, e.g., in very deep basins, stochastic variability in sediment transport and channel lateral mobility outweighs the autogenic cyclicity. This study suggests that internal dynamics and its stratigraphic

  6. Ultratrace Determination of Cr(VI and Pb(II by Microsample Injection System Flame Atomic Spectroscopy in Drinking Water and Treated and Untreated Industrial Effluents

    Directory of Open Access Journals (Sweden)

    Jameel Ahmed Baig

    2013-01-01

    Full Text Available Simple and robust analytical procedures were developed for hexavalent chromium (Cr(VI and lead (Pb(II by dispersive liquid-liquid microextraction (DLLME using microsample injection system coupled with flame atomic absorption spectrophotometry (MIS-FAAS. For the current study, ammonium pyrrolidine dithiocarbamate (APDC, carbon tetrachloride, and ethanol were used as chelating agent, extraction solvent, and disperser solvent, respectively. The effective variables of developed method have been optimized and studied in detail. The limit of detection of Cr(VI and Pb(II were 0.037 and 0.054 µg/L, respectively. The enrichment factors in both cases were 400 with 40 mL of initial volumes. The relative standard deviations (RSDs, were 96%. The proposed method was successfully applied to the determination of Cr(VI and Pb(II at ultratrace levels in natural drinking water and industrial effluents wastewater of Denizli. Moreover, the proposed method was compared with the literature reported method.

  7. The role of nanopores on U(VI) sorption and redox behavior in U(VI)-contaminated subsurface sediments

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Huifang; Roden, Eric E.; Kemner, Kenneth M.; Jung, Hun-Bok; Konishi, Hiromi; Boyanov, Maxim; Sun, Yubing; Mishra, Bhoopesh

    2013-10-16

    Most reactive surfaces in clay-dominated sediments are present within nanopores (pores of nm dimension). The behavior of geological fluids and minerals in nanopores is significantly different from those in normal non-nanoporous environments. The effect of nanopore surfaces on U(VI) sorption/desorption and reduction is likely to be significant in clay-rich subsurface environments. Our research results from both model nanopore system and natural sediments from both model system (synthetic nanopore alumina) and sediments from the ORNL Field Research Center prove that U(VI) sorption on nanopore surfaces can be greatly enhanced by nanopore confinement environments. The results from the project provide advanced mechanistic, quantitative information on the physiochemical controls on uranium sorption and redox behavior in subsurface sediments. The influence of nanopore surfaces on coupled uranium sorption/desorption and reduction processes is significant in virtually all subsurface environments, because most reactive surfaces are in fact nanopore surfaces. The results will enhance transfer of our laboratory-based research to a major field research initiative where reductive uranium immobilization is being investigated. Our results will also provide the basic science for developing in-situ colloidal barrier of nanoporous alumina in support of environmental remediation and long term stewardship of DOE sites.

  8. Pseudoglaucoma em mucopolissacaridose tipo VI: relato de caso Pseudo-glaucoma in type VI mucopolysaccharidosis: case report

    Directory of Open Access Journals (Sweden)

    Miguel Gustavo Rosa da Rocha Canêdo

    2006-12-01

    Full Text Available Os autores relatam um caso de mucopolissacaridose tipo VI em paciente de 19 anos, diagnosticada por meio de exame genético-clínico, demonstrando várias manifestações sistêmicas, incluindo alterações oftalmológicas como: opacidade corneal, aumento da pressão intra-ocular e aumento importante da espessura corneal. Discutem-se os achados característicos sindrômicos e a influência da espessura corneal na alteração da pressão intra-ocular podendo levar a tratamentos antiglaucomatosos desnecessários.The authors report a case of a 19-year-old patient presenting with type VI mucopolysaccharidosis, diagnosed by genetic-clinical examination, demonstrating several systemic manifestations, including ocular disorders such as: corneal opacity, elevated intra-ocular pressure and increase of corneal thickness. The authors discuss the characteristic syndromic findings and the influence of corneal thickness associated with an increase in intraocular pressure leading to unnecessary antiglaucomatous treatment.

  9. A Salmonella Typhimurium-Typhi genomic chimera: a model to study Vi polysaccharide capsule function in vivo.

    Directory of Open Access Journals (Sweden)

    Angela M Jansen

    2011-07-01

    Full Text Available The Vi capsular polysaccharide is a virulence-associated factor expressed by Salmonella enterica serotype Typhi but absent from virtually all other Salmonella serotypes. In order to study this determinant in vivo, we characterised a Vi-positive S. Typhimurium (C5.507 Vi(+, harbouring the Salmonella pathogenicity island (SPI-7, which encodes the Vi locus. S. Typhimurium C5.507 Vi(+ colonised and persisted in mice at similar levels compared to the parent strain, S. Typhimurium C5. However, the innate immune response to infection with C5.507 Vi(+ and SGB1, an isogenic derivative not expressing Vi, differed markedly. Infection with C5.507 Vi(+ resulted in a significant reduction in cellular trafficking of innate immune cells, including PMN and NK cells, compared to SGB1 Vi(- infected animals. C5.507 Vi(+ infection stimulated reduced numbers of TNF-α, MIP-2 and perforin producing cells compared to SGB1 Vi(-. The modulating effect associated with Vi was not observed in MyD88(-/- and was reduced in TLR4(-/- mice. The presence of the Vi capsule also correlated with induction of the anti-inflammatory cytokine IL-10 in vivo, a factor that impacted on chemotaxis and the activation of immune cells in vitro.

  10. Forensic investigation of a chromium(VI) groundwater plume in Thiva, Greece

    Energy Technology Data Exchange (ETDEWEB)

    Panagiotakis, I. [National Technical Univ. of Athens, Zografou (Greece); Dermatas, D. [National Technical Univ. of Athens, Zografou (Greece); Vatseris, C. [Intergeo-Environmental Technology Ltd., Thessaloniki (Greece); Chrysochoou, M. [Univ. of Connecticut, Storrs, CT (United States); Papassiopi, N. [National Technical Univ. of Athens, Zografou (Greece); Xenidis, A. [National Technical Univ. of Athens, Zografou (Greece); Vaxevanidou, K. [National Technical Univ. of Athens, Zografou (Greece)

    2015-01-01

    We conducted a forensic investigation with the aim of decoupling the contribution of geogenic and anthropogenic Cr(VI) sources in the wider area of Thiva. Groundwater and topsoil samples were collected from two Cr(VI) groundwater plumes of 160 μg/L and 75 μg/L. A series of evidence support the view that the origin of Cr(VI) detected in groundwater is mainly geogenic. These are: (a) the presence of Cr in topsoil of the wider area, (b) the moderate Cr(VI) groundwater concentrations, (c) the high Ni levels within the Cr(VI) plumes, (d) the predominance of Mn(IV), which is a prerequisite for Cr(III) oxidation to Cr(VI), and (e) the absence of co-contaminants. This study also revealed that, although both Cr(VI) plumes are clearly of geogenic origin, the plume with the elevated Cr(VI) values, in the north of Thiva town, exhibits also an anthropogenic component, which can potentially be attributed to the alkaline environment associated with the old uncontrolled landfill of Thiva and the industrial cluster located in this area.

  11. [Safety and immunogenecity of a vaccine of polyssacharide Vi from Salmonella typhi in Cuban youths].

    Science.gov (United States)

    Azze, Rolando Felipe Ochoa; Suárez, Idalia Morelia Baró; Rodríguez, Juan Carlos Martínez; Sosa, Mayelin Mirabal; del Río, Marlene Isabel Armesto; Alvarez, Francisco Domínguez

    2003-01-01

    A randomized, controlled and double-blind study was conducted in young adults aged 18-20 aimed at evaluating the reactogenecity and immunogenecity of vaz-TyVi, a vaccine of polyssacharide Vi from Salmonella typhi. They were distributed into 3 groups: immunized with a dose of Vax-TyVi (Finlay Institute), TYPHIM Vi (Pasteur-Mérieux) or vax-TET (tetanic toxoid). Serum samples were taken before and 21 days after immunization. The immunogenecity was evaluated in 323 volunteers by an indirect ELISA. The seroconversion of those receiving vax-TyVi was 81.97% and 65.05 % for TYPHIM Vi. The postvaccine mean geometric titers were 7.41 U/mL (5.92-9.27 U/mL) and 5.41 U/mL (4.35-6.72 U/mL), respectively. The seroconversion with vax-TET was 0%. The reactogenecity of both polysaccharide vaccines was low. It was concluded that the immunogenecity of vax-TyVi was not lower than that of TYPHIM Vi and that its reactogenecity was similar.

  12. 78 FR 34575 - Safety Zone; Bay Swim VI, Presque Isle Bay, Erie, PA

    Science.gov (United States)

    2013-06-10

    ... FR Federal Register NPRM Notice of Proposed Rulemaking TFR Temporary Final Rule A. Regulatory History... SECURITY Coast Guard 33 CFR Part 165 RIN 1625-AA00 Safety Zone; Bay Swim VI, Presque Isle Bay, Erie, PA... portion of Presque Isle bay during the Bay Swim VI swimming event. This temporary safety zone is...

  13. Hipparcos red stars in the HpV_{T2} and VI_C systems

    CERN Document Server

    Platais, I; Jorissen, A; Makarov, V V; Berdnikov, L N; Samus, N N; Evans, T L; Lebzelter, T; Sperauskas, J

    2003-01-01

    For Hipparcos M, S, and C spectral type stars, we provide calibrated instantaneous (epoch) Cousins $V-I$ color indices using newly derived $HpV_{T2}$ photometry. Three new sets of ground-based Cousins $VI$ data have been obtained for more than 170 carbon and red M giants. These datasets in combination with the published sources of $VI$ photometry served to obtain the calibration curves linking Hipparcos/Tycho $Hp-V_{T2}$ with the Cousins $V-I$ index. In total, 321 carbon stars and 4464 M- and S-type stars have new $V-I$ indices. The standard error of the mean $V-I$ is about 0.1 mag or better down to $Hp\\approx9$ although it deteriorates rapidly at fainter magnitudes. These $V-I$ indices can be used to verify the published Hipparcos $V-I$ color indices. Thus, we have identified a handful of new cases where, instead of the real target, a random field star has been observed. A considerable fraction of the DMSA/C and DMSA/V solutions for red stars appear not to be warranted. Most likely such spurious solutions ma...

  14. Oxidation of Sulfonamides in Aqueous Solution by UV-TiO2-Fe(VI).

    Science.gov (United States)

    Ma, Yan; Zhang, Kejia; Li, Cong; Zhang, Tuqiao; Gao, Naiyun

    2015-01-01

    The photocatalytic degradation of sulfonamides in aqueous TiO2 suspension under UV irradiation has been investigated using potassium ferrate as electron acceptors. The results showed that the stability of Fe(VI) is dependent on pH significantly, and the stability reduces obviously in the presence of UV-TiO2. The experiments indicated that Fe(VI) could effectively scavenge the conduction band electrons from the surface of TiO2. The photocatalytic oxidation of sulfonamides with Fe(VI) was found to be much faster than that without Fe(VI). The SD, SM, and SMX concentration was greatly reduced by 89.2%, 83.4%, and 82.0%, respectively, after 10 min with UV-TiO2-Fe(VI), comparing to 65.2%, 66.0%, and 71.9%, respectively, with Fe(VI) only in the dark and 71.3%, 72.7%, and 76.0%, respectively, with UV-TiO2. The pH value of solution significantly influenced the sulfonamides degradation in UV-TiO2-Fe(VI) system. The degradation amount of sulfonamides after 10 min was a maximum at pH 7. The intermediate products of sulfonamides oxidation by UV-TiO2-Fe(VI) were analysed by LC-HESI-MS-MS and the results suggested that a majority of sulfonamides turned into large-molecule products without complete mineralization.

  15. Drying Effects on Corrosion Properties of Cr(VI) and Cr(III) Treated Electrogalvanized Steel

    NARCIS (Netherlands)

    Zhang, X.; Van den Bos, C.; Sloof, W.G.; Hovestad, A.; Terryn, H.; De Wit, J.H.W.

    2006-01-01

    Drying effects on corrosion performance of Cr(VI)- and Cr(III)-treated electro-galvanized steel have been studied in NaCl solution using potentiodynamic measurements and electrochemical impedance spectroscopy (EIS). The Cr(VI) and the Cr(III) treated specimens were dried at three different temperatu

  16. Effectiveness of Vi capsular polysaccharide typhoid vaccine among children: a cluster randomized trial in Karachi, Pakistan

    NARCIS (Netherlands)

    Khan, M.I.; Soofi, S.B.; Ochiai, R.L.; Habib, M.A.; Sahito, S.M.; Nizami, S.Q.; Acosta, C.J.; Clemens, J.D.; Bhutta, Z.A.; Group, D.T.K.V.E.S.

    2012-01-01

    BACKGROUND: Typhoid fever is endemic in Karachi, with an incidence among children ranging from 170 to 450 per 100,000 child-years. Vaccination strategies are important for prevention, and the Vi capsular polysaccharide (ViCPS) vaccine has been shown to be effective in reducing the burden of typhoid

  17. Adsorption of Cr(VI) from synthetic solutions and electroplating wastewaters on amorphous aluminium oxide.

    Science.gov (United States)

    Alvarez-Ayuso, E; García-Sánchez, A; Querol, X

    2007-04-02

    The adsorption behaviour of amorphous aluminium oxide was studied with respect to Cr(VI) in order to consider its application to purify electroplating wastewaters. A batch method was employed using Cr(VI) concentrations ranged from 10 to 200mg/l. The Langmuir model was found to describe the adsorption process well, offering a maximum adsorption capacity of 78.1mg/g. The effect of ionic strength (0-0.1M KNO(3)), pH (3-9) and competitive solutes (molar ratio [Cr(VI)]/[SO(4)(2-)]=1 and 100) on the retention process was evaluated. Cr(VI) adsorption on amorphous aluminium oxide appeared to be dependent on ionic strength with a more pronounced effect in acid conditions. Conversely, adsorption was not affected by pH in acid medium, but decreased when pH sifted to alkaline values. The presence of SO(4)(2-) greatly reduced Cr(VI) removal across the entire pH range when both solutes were present in similar concentrations. Amorphous aluminium oxide also showed a high adsorption capacity when used in the purification of Cr(VI) electroplating wastewaters. The adsorbent doses required to attain more than 90% of Cr(VI) removal varied between 1 and 5 g/l depending on Cr(VI) concentration in wastewaters.

  18. 40 CFR Appendix Vi to Part 86 - Vehicle and Engine Components

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Vehicle and Engine Components VI Appendix VI to Part 86 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS.... (2) Cooling system. a. Coolant. b. Thermostat. c. Filter. (3) Lubrication. a. Oil filter....

  19. Inhibition of nitrate reduction by chromium (VI) in anaerobic soil microcosms

    Energy Technology Data Exchange (ETDEWEB)

    Kourtev, P. S.; Nakatsu, C. H.; Konopka, Allan

    2009-10-01

    Chromium (VI) is often found as a co-contaminant at sites polluted with organic compounds. We used microcosms amended with glucose or protein, nitrate and increasing concentrations of chromium to study nitrate reduction in Cr(VI) polluted soils. Organic carbon stimulated bacterial activity, but the addition of Cr(VI) caused a lag and then slower rates 5 of CO2 accumulation. Nitrate reduction only occurred after Cr(VI) had been reduced. Bacterial activity was again inhibited when Cr(VI) was added a second time; thus not all Cr-sensitive bacteria were removed in the first phase. Glucose and protein selected for relatively similar bacterial communities, as assayed by PCR-DGGE of the 16S rRNA gene; this selection was modified by the addition of 10 Cr(VI). Cr-resistant bacteria isolated from microcosms were closely related to members of Bacillus, Enterococcus and Propionibacterium sp. Our results indicate that carbon utilization and nitrate reduction in these soils in the presence of Cr(VI) are contingent upon the reduction of the added heavy metal by a limited subset of the bacterial community. The amount of Cr(VI) required to inhibit nitrate reduction was 10-fold less than for aerobic catabolism of the same 15 substrate. We hypothesize that the resistance level of a microbial process is directly related to the diversity of microbes capable of conducting it.

  20. Modelling Cr(VI) removal by a combined carbon-activated sludge system

    Energy Technology Data Exchange (ETDEWEB)

    Orozco, A. Micaela Ferro [Centro de Investigacion y Desarrollo en Criotecnologia de Alimentos (CIDCA), CONICET, Fac. de Cs. Exactas, UNLP. 47 y 116 (B1900AJJ), La Plata (Argentina); Contreras, Edgardo M. [Centro de Investigacion y Desarrollo en Criotecnologia de Alimentos (CIDCA), CONICET, Fac. de Cs. Exactas, UNLP. 47 y 116 (B1900AJJ), La Plata (Argentina)], E-mail: econtrer@quimica.unlp.edu.ar; Zaritzky, Noemi E. [Centro de Investigacion y Desarrollo en Criotecnologia de Alimentos (CIDCA), CONICET, Fac. de Cs. Exactas, UNLP. 47 y 116 (B1900AJJ), La Plata (Argentina); Fac. de Ingenieria, UNLP. 47 y 1 (B1900AJJ), La Plata (Argentina)

    2008-01-15

    The combined carbon-activated sludge process has been proposed as an alternative to protect the biomass against toxic substances in wastewaters; however, the information about the effect of powdered-activated carbon (PAC) addition in activated sludge reactors for the treatment of wastewaters containing Cr(VI) is limited. The objectives of the present study were: (a) to evaluate the removal of hexavalent chromium by (i) activated sludge microorganisms in aerobic batch reactors, (ii) powdered-activated carbon, and (iii) the combined action of powdered-activated carbon and biomass; (b) to propose mathematical models that interpret the experimental results. Different Cr(VI) removal systems were tested: (S1) biomass (activated sludge), (S2) PAC, and (S3) the combined activated carbon-biomass system. A Monod-based mathematical model was used to describe the kinetics of Cr(VI) removal in the system S1. A first-order kinetics with respect to Cr(VI) and PAC respectively, was proposed to model the removal of Cr(VI) in the system S2. Cr(VI) removal in the combined carbon-biomass system (S3) was faster than both Cr(VI) removal using PAC or activated sludge individually. Results showed that the removal of Cr(VI) using the activated carbon-biomass system (S3) was adequately described by combining the kinetic equations proposed for the systems S1 and S2.

  1. Inhibition of corrosion of zinc by Cr(VI)and Cr(III) treatments

    NARCIS (Netherlands)

    Zhang, X.; Bos, C. van den; Hovestad, A.; Terryn, H.; Wit, J.H.W. de

    2007-01-01

    The corrosion behavior of Cr(VI) and Cr(III) treated zinc has been studied using scanning Kelvin probe (SKP), potentiodynamic polarization and elctrochemical impedance spectroscopy (EIS). The Volta potentials measured on the Cr(VI) or the CR(III)-A treated zinc area by SKP in a humid chamber are mor

  2. Cr(VI) and Cr(III)-Based Conversion Coatings on Zinc

    NARCIS (Netherlands)

    Zhang, X.

    2005-01-01

    With the aims of understanding the protective mechanism of chromate conversion coatings and developing alternatives to chromate treatments, the physical natures and corrosion properties of Cr(VI) and Cr(III) treated zinc have been investigated in this work. The Cr(VI) treatments were carried out in

  3. Chromium(VI) reduction by catechol(amine)s results in DNA cleavage in vitro

    DEFF Research Database (Denmark)

    Pattison, D I; Davies, Michael Jonathan; Levina, A;

    2001-01-01

    ) or 4-tert-butylcatechol (5) do not damage DNA. The Cr(VI)/catechol(amine) reactions have been studied at low added H(2)O(2) concentrations, which lead to enhanced DNA cleavage with 1 and induce DNA cleavage with 4. The Cr(V) and organic intermediates generated by the reactions of Cr(VI) with 1 or 4...

  4. 77 FR 27081 - II-VI, Incorporated, Infrared Optics-Saxonburg Division, Saxonburg, Pennsylvania; Notice of...

    Science.gov (United States)

    2012-05-08

    ... was published in the Federal Register on February 14, 2012 (77 FR 8281). The workers were engaged in... Employment and Training Administration II-VI, Incorporated, Infrared Optics--Saxonburg Division, Saxonburg... former workers of II-VI, Incorporated, Infrared Optics--Saxonburg Division, Saxonburg,...

  5. Thermodynamic Insight into the Solvation and Complexation Behavior of U(VI) in Ionic Liquid: Binding of CMPO with U(VI) Studied by Optical Spectroscopy and Calorimetry.

    Science.gov (United States)

    Wu, Qi; Sun, Taoxiang; Meng, Xianghai; Chen, Jing; Xu, Chao

    2017-03-06

    The complexation of U(VI) with octylphenyl-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO, denoted as L) in ionic liquid (IL) C4mimNTf2 was investigated by UV-vis absorption spectrophotometry and isothermal titration calorimetry. Spectro-photometric titration suggests that three successive complexes, UO2Lj(2+) (j = 1-3), formed both in "dry" (water content U(VI) is much stronger, with stability constants of the respective complexes more than 1 order of magnitude higher than that in wet IL. Energetically, the complexation of U(VI) with CMPO in dry IL is mainly driven by negative enthalpies. In contrast, the complexation in wet IL is overwhelmingly driven by highly positive entropies as a result of the release of a large amount of water molecules from the solvation sphere of U(VI). Moreover, comparisons between the fitted absorption spectra of complexes in wet IL and that of extractive samples from solvent extraction have identified the speciation involved in the extraction of U(VI) by CMPO in ionic liquid. The results from this study not only offer a thermodynamic insight into the complexation behavior of U(VI) with CMPO in IL but also provide valuable information for understanding the extraction behavior in the corresponding solvent extraction system.

  6. Chromium(VI) Bioremoval by Pseudomonas Bacteria: Role of Microbial Exudates for Natural Attenuation and Biotreatment of Cr(VI) Contamination

    Energy Technology Data Exchange (ETDEWEB)

    N Mercan Dogan; C Kantar; S Gulcan; C Dodge; B Coskun Yilmaz; M Ali Mazmanci

    2011-12-31

    Laboratory batch and column experiments were conducted to investigate the role of microbial exudates, e.g., exopolymeric substance (EPS) and alginic acid, on microbial Cr(VI) reduction by two different Pseudomonas strains (P. putida P18 and P. aeuroginosa P16) as a method for treating subsurface environment contaminated with Cr(VI). Our results indicate that microbial exudates significantly enhanced microbial Cr(VI) reduction rates by forming less toxic and highly soluble organo-Cr(III) complexes despite the fact Cr(III) has a very low solubility under the experimental conditions studied (e.g., pH 7). The formation of soluble organo-Cr(III) complexes led to the protection of the cells and chromate reductases from inactivation. In systems with no organic ligands, soluble organo-Cr(III) end products were formed between Cr(III) and the EPS directly released by bacteria due to cell lysis. Our results also provide evidence that cell lysis played an important role in microbial Cr(VI) reduction by Pseudomonas bacteria due to the release of constitutive reductases that intracellularly and/or extracellularly catalyzed the reduction of Cr(VI) to Cr(III). The overall results highlight the need for incorporation of the release and formation of organo-Cr(III) complexes into reactive transport models to more accurately design and monitor in situ microbial remediation techniques for the treatment of subsurface systems contaminated with Cr(VI).

  7. Chromium(VI) bioremoval by pseudomonas bacteria: role of microbial exudates for natural attenuation and biotreatment of Cr(VI) contamination

    Energy Technology Data Exchange (ETDEWEB)

    Dogan, N.M.; Dodge, C.; Kantar, C.; Gulcan, S.; Yilmaz, B.C.; Mazmanci, M.A.

    2011-02-14

    Laboratory batch and column experiments were conducted to investigate the role of microbial exudates, e.g., exopolymeric substance (EPS) and alginic acid, on microbial Cr(VI) reduction by two different Pseudomonas strains (P. putida P18 and P. aeuroginosa P16) as a method for treating subsurface environment contaminated with Cr(VI). Our results indicate that microbial exudates significantly enhanced microbial Cr(VI) reduction rates by forming less toxic and highly soluble organo-Cr(III) complexes despite the fact Cr(III) has a very low solubility under the experimental conditions studied (e.g., pH 7). The formation of soluble organo-Cr(III) complexes led to the protection of the cells and chromate reductases from inactivation. In systems with no organic ligands, soluble organo-Cr(III) end products were formed between Cr(III) and the EPS directly released by bacteria due to cell lysis. Our results also provide evidence that cell lysis played an important role in microbial Cr(VI) reduction by Pseudomonas bacteria due to the release of constitutive reductases that intracellularly and/or extracellularly catalyzed the reduction of Cr(VI) to Cr(III). The overall results highlight the need for incorporation of the release and formation of organo-Cr(III) complexes into reactive transport models to more accurately design and monitor in situ microbial remediation techniques for the treatment of subsurface systems contaminated with Cr(VI).

  8. Morphometric analysis of the Marmara Sea river basins, Turkey

    Science.gov (United States)

    Elbaşı, Emre; Ozdemir, Hasan

    2014-05-01

    (GIS). This study shows that morphometric analysis of the basins in regional level are very important to understand general morphological characteristics of the basins. In this case, tectonic and lithological conditions of the basins have greatly affected the morphometric characteristics of the north and south basins of the Marmara Sea. References Abrahams, AD. 1984. Channel Networks: A Geomorphological Perspective. Water Resources Research, Volume 20, Issue 2, pages 161-188. Horton, R.E. 1932. Drainage basin characteristics. Trans Am Geophys Union 13:350-361. Keller, E.A., Pinter, N. 2002. Active Tectonics Earthquakes, Uplift, and Landscape, Second Edition, Prentice Hall, New Jersey. Ozdemir H., Bird D. 2009. Evaluation of morphometric parameters of drainage networks derived from topographic maps and DEM in point of floods, Environmental Geology, vol.56, pp.1405-1415. Schumm, S.A. 1956. Evolution of drainage systems and slopes in badlands at Perth Amboy, New Jersey. Geol Soc Am Bull 67:597-646. Strahler, A.N. 1957. Quantitative geomorphology of drainage and channel networks. In: Chow YT (ed) Handbook of appliecl hydrology. Me Graw Hill Book Company, New York. Verstappen, H.Th. 1983. Applied geomorphology. ITC, Enschede.

  9. Impact of the uranium (VI) speciation in mineralised urines on its extraction by calix[6]arene bearing hydroxamic groups used in chromatography columns.

    Science.gov (United States)

    Baghdadi, S; Bouvier-Capely, C; Ritt, A; Peroux, A; Fevrier, L; Rebiere, F; Agarande, M; Cote, G

    2015-11-01

    Actinides determination in urine samples is part of the analyses performed to monitor internal contamination in case of an accident or a terrorist attack involving nuclear matter. Mineralisation is the first step of any of these analyses. It aims at reducing the sample volume and at destroying all organic compounds present. The mineralisation protocol is usually based on a wet ashing step, followed by actinides co-precipitation and a furnace ashing step, before redissolution and the quantification of the actinides by the appropriate techniques. Amongst the existing methods to perform the actinides co-precipitation, alkali-earth (typically calcium) precipitation is widely used. In the present work, the extraction of uranium(VI), plutonium(IV) and americium(III) from the redissolution solutions (called "mineralised urines") on calix[6]arene columns bearing hydroxamic groups was investigated as such an extraction is a necessary step before their determination by ICP-MS or alpha spectrometry. Difficulties were encountered in the transfer of uranium(VI) from raw to mineralised urines, with yield of transfer ranging between 0% and 85%, compared to about 90% for Pu and Am, depending on the starting raw urines. To understand the origin of such a difficulty, the speciation of uranium (VI) in mineralised urines was investigated by computer simulation using the MEDUSA software and the associated HYDRA database, compiled with recently published data. These calculations showed that the presence of phosphates in the "mineralised urines" leads to the formation of strong uranyl-phosphate complexes (such as UO2HPO4) which compete with the uranium (VI) extraction by the calix[6]arene bearing hydroxamic groups. The extraction constant of uranium (VI) by calix[6]arene bearing hydroxamic groups was determined in a 0.04 mol L(-1) sodium nitrate solution (logK=4.86±0.03) and implemented in an extraction model taking into account the speciation in the aqueous phase. This model allowed to

  10. Removal of Cr(VI from aqueous solution using Bacillus subtilis, Pseudomonas aeruginosa and Enterobacter cloacae

    Directory of Open Access Journals (Sweden)

    P. Sethuraman,

    2010-06-01

    Full Text Available The objective of this study is to investigate the removal efficiency of Cr(VI by Bacillus subtilis, Pseudomonas aeruginosa and Enterobacter cloacae from aqueous solution under different process conditions. Batch mode experiments were carried out as a function of solution pH, biosorbent dosage, Cr(VI concentration and contact time.The FT-IR spectra and SEM analysis of the biosorbent were recorded to analyse the number and position of the functional groups available for the binding of Cr(VI ions and to study the morphology of biosorbent. The batch isothermal equilibrium data were analyzed with Freundlich and Langmuir isotherm models. The kinetic models were examined with pseudo first order and pseudo second order kinetics. The results revealed that the Cr(VI is considerably adsorbed on bacterial biomass and it could be an economical method for the removal of Cr(VI from aqueous solution.

  11. Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

    Science.gov (United States)

    Philips , Elizabeth J.P.; Landa, Edward R.; Lovely, Derek R.

    1995-01-01

    A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranuum-contaminated soils. Bicarbonate (100 mM) extracted 20–94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism,Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils.

  12. Modeling Hand-Over-Hand and Inchworm Steps in Myosin VI

    Science.gov (United States)

    Jack, Amanda; Lowe, Ian; Tehver, Riina

    Myosin VI is a molecular motor protein that moves along actin filaments to transport cargo within a cell. There is much experimental evidence that the myosin VI dimer moves ``hand-over-hand'' along actin; however, recent experiments suggest that the protein can also move via an ``inchworm'' mechanism. We created a mechanochemical kinetic model to predict myosin VI's behavior under different ATP, ADP, and force conditions, taking these alternative mechanisms into account. Our model's calculations agree well with experimental results and can also be used to predict myosin VI's behavior outside experimentally tested regimes, such as under forward force. We also predict an optimized motor function for the protein around physiological (-2 pN) load and anchoring under -3 pN load. By using our model to predict myosin VI's response to environmental change, we can gain insight into the behavior of a protein that can be difficult to observe experimentally.

  13. Synthesis of Graphene Oxide by Oxidation of Graphite with Ferrate(VI) Compounds: Myth or Reality?

    Science.gov (United States)

    Sofer, Zdeněk; Luxa, Jan; Jankovský, Ondřej; Sedmidubský, David; Bystroň, Tomáš; Pumera, Martin

    2016-09-19

    It is well established that graphene oxide can be prepared by the oxidation of graphite using permanganate or chlorate in an acidic environment. Recently, however, the synthesis of graphene oxide using potassium ferrate(VI) ions has been reported. Herein, we critically replicate and evaluate this new ferrate(VI) oxidation method. In addition, we test the use of potassium ferrate(VI) for the synthesis of graphene oxide under various experimental routes. The synthesized materials are analyzed by a number of analytical methods in order to confirm or disprove the possibility of synthesizing graphene oxide by the ferrate(VI) oxidation route. Our results confirm the unsuitability of using ferrate(VI) for the oxidation of graphite on graphene oxide because of its high instability in an acidic environment and low oxidation power in neutral and alkaline environments.

  14. Cathodic reduction of hexavalent chromium [Cr(VI)] coupled with electricity generation in microbial fuel cells.

    Science.gov (United States)

    Wang, Gang; Huang, Liping; Zhang, Yifeng

    2008-11-01

    A novel approach to Cr(VI)-contaminated wastewater treatment was investigated using microbial fuel cell technologies in fed-batch mode. By using synthetic Cr(VI)-containing wastewater as catholyte and anaerobic microorganisms as anodic biocatalyst, Cr(VI) at 100 mg/l was completely removed during 150 h (initial pH 2). The maximum power density of 150 mW/m(2) (0.04 mA/cm(2)) and the maximum open circuit voltage of 0.91 V were generated with Cr(VI) at 200 mg/l as electron acceptor. This work verifies the possibility of simultaneous electricity production and cathodic Cr(VI) reduction.

  15. Single-step synthesis of magnetic chitosan composites and application for chromate (Cr(VI)) removal

    Institute of Scientific and Technical Information of China (English)

    杨卫春; 唐琼芝; 董舒宇; 柴立元; 王海鹰

    2016-01-01

    Magnetic chitosan composites (Fe3O4@chitosan) were synthesized in one single-step, characterized and applied in Cr(VI) removal from water. With the increase of loading proportion of chitosan, Cr(VI) adsorption capacity of Fe3O4@chitosan composites increased from 10.771 to 21.040 mg/g. The optimum adsorption capacities of Cr(VI) on Fe3O4@chitosan-3 were found in a pH range of 3.0−5.0. Kinetic study results show that the adsorption process follows pseudo-second-order model, indicating that the rate-limiting step in the adsorption of Cr(VI) involves chemisorptions. Moreover, FT-IR spectra analysis confirms that the amine and hydroxyl groups of chitosan are predominantly responsible for binding. Results from this work demonstrate that the prepared Fe3O4@chitosan composites possess great potential in Cr(VI) removal from contaminated water.

  16. VI International Workshop on Nature Inspired Cooperative Strategies for Optimization

    CERN Document Server

    Otero, Fernando; Masegosa, Antonio

    2014-01-01

    Biological and other natural processes have always been a source of inspiration for computer science and information technology. Many emerging problem solving techniques integrate advanced evolution and cooperation strategies, encompassing a range of spatio-temporal scales for visionary conceptualization of evolutionary computation. This book is a collection of research works presented in the VI International Workshop on Nature Inspired Cooperative Strategies for Optimization (NICSO) held in Canterbury, UK. Previous editions of NICSO were held in Granada, Spain (2006 & 2010), Acireale, Italy (2007), Tenerife, Spain (2008), and Cluj-Napoca, Romania (2011). NICSO 2013 and this book provides a place where state-of-the-art research, latest ideas and emerging areas of nature inspired cooperative strategies for problem solving are vigorously discussed and exchanged among the scientific community. The breadth and variety of articles in this book report on nature inspired methods and applications such as Swarm In...

  17. CFD Simulation of the NREL Phase VI Rotor

    CERN Document Server

    Song, Yang

    2014-01-01

    The simulation of the turbulent and potentially separating flow around a rotating, twisted, and tapered airfoil is a challenging task for CFD simulations. This paper describes CFD simulations of the NREL Phase VI turbine that was experimentally characterized in the 24.4m x 36.6m NREL/NASA Ames wind tunnel (Hand et al., 2001). All computations in this article are performed on the experimental base configuration of 0o yaw angle, 3o tip pitch angle, and a rotation rate of 72 rpm. The significance of specific mesh resolution regions to the accuracy of the CFD prediction is discussed. The ability of CFD to capture bulk quantities, such as the shaft torque, and the detailed flow characteristics, such as the surface pressure distributions, are explored for different inlet wind speeds. Finally, the significant three-dimensionality of the boundary layer flow is demonstrated.

  18. Hvor mange kan vi byde velkommen til Verden?

    DEFF Research Database (Denmark)

    Nørgaard, Jørgen

    2011-01-01

    Verdens befolkningstal på nu 7 milliarder er naturligvis en af de væsentlige årsager til de menneskeskabte miljøproblemer, vi står overfor. Alligevel har det længe været et tabu at inddrage befolkningsudviklingen i miljødebatten. Men hvis den globale miljøbelastning skal minimeres betragteligt, s...... gør befolkningsreduktion til en af de billigste og mest nænsomme veje til redning af klimaet og miljøet. Det kræver dog at miljøorganisationerne tør tale dette afgørende emne....

  19. Quantum Painleve-Calogero correspondence for Painleve VI

    Energy Technology Data Exchange (ETDEWEB)

    Zabrodin, A. [National Research University Higher School of Economics, 20 Myasnitskaya Ulitsa, Moscow 101000 (Russian Federation); Institute of Biochemical Physics, Kosygina str. 4, 119991 Moscow (Russian Federation); ITEP, Bol. Cheremushkinskaya str. 25, 117259 Moscow (Russian Federation); Zotov, A. [ITEP, Bol. Cheremushkinskaya str. 25, 117259 Moscow (Russian Federation)

    2012-07-15

    This paper is a continuation of our previous paper where the Painleve-Calogero correspondence has been extended to auxiliary linear problems associated with Painleve equations. We have proved, for the first five equations from the Painleve list, that one of the linear problems can be recast in the form of the non-stationary Schroedinger equation whose Hamiltonian is a natural quantization of the classical Calogero-like Hamiltonian for the corresponding Painleve equation. In the present paper we establish the quantum Painleve-Calogero correspondence for the most general case, the Painleve VI equation. We also show how the desired special gauge and the needed choice of variables can be derived starting from the corresponding Schlesinger system with rational spectral parameter.

  20. Tetrapyridinium μ-oxido-di-μ-sulfato-bis[chloridodioxidomolybdate(VI

    Directory of Open Access Journals (Sweden)

    José A. Fernandes

    2010-08-01

    Full Text Available The title salt, (C5H6N4[Mo2Cl2O5(SO42], comprises four pyridinium cations for each [(MoClO22(μ-O(μ-SO42]4− anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetraanionic bimetallic molybdenum(VI cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non-polymeric compound with terminal oxide, sulfate and halide ligands bonded to the same metal. The hydrogen bonds connecting the pyridinium cations to the molybdenum clusters are diverse, varying from strong and directional interactions to bifurcated bonds with a subsequent loss of directionality.

  1. Dioxidobis{2-[(E-p-tolyliminomethyl]phenolato}molybdenum(VI

    Directory of Open Access Journals (Sweden)

    Mehdi Hatefi

    2010-09-01

    Full Text Available The asymmetric unit of the title compound, [Mo(C14H12NO2O2], comprises half of the complex with the full molecule generated by the application of twofold symmetry. The MoVI atom is surrounded by two oxide O atoms and the two sets of N,O-donor atoms of the bidentate Schiff base ligands. The resulting N2O4 donor set defines a distorted octahedral coordination geometry. Intermolecular C—H...O contacts link molecules into chains along the b axis. The crystal structure is further stabilized by intermolecular π–π interactions [ring centroid–centroid distance = 3.724 (6 Å].

  2. Claude Lévi-Strauss vu par Philippe Descola

    OpenAIRE

    DESCOLA, Philippe; Kirsch, Marc

    2010-01-01

    Philippe Descola. Pourriez-vous présenter le paysage de l’anthropologie française et la place qu’y occupe Claude Lévi-Strauss ? Avant la guerre l’anthropologie française était surtout le fait d’anthropologues de cabinet – armchair anthropologists, comme on disait en Angleterre. Dans cette période, des hommes seuls comme Mauss ou Lévy-Bruhl en France, Frazer ou Tylor en Angleterre, maîtrisaient des masses considérables de données qu’ils essayaient d’organiser pour résoudre un problème ou expl...

  3. vi-Strauss nos 90 voltas ao passado

    Directory of Open Access Journals (Sweden)

    Lévi-Strauss Claude

    1998-01-01

    Full Text Available Este artigo responde às críticas formuladas por Christian Delacampagne e Bernard Traimond em "A Polêmica Sartre/Lévi-Strauss Revisitada. Nas Raízes das Ciências Sociais de Hoje", publicado em Les Temps Modernes 596 (novembro-dezembro de 1997. Para fazê-lo, recorda inicialmente o caráter relativo da oposição entre "sociedades frias" e "sociedades quentes". Em seguida, refuta a tese de que Maurice Merleau-Ponty, sob a capa de um elogio, teria dirigido críticas veladas ao autor. Finalmente, reconhecendo o afastamento da antropologia de hoje em face das posições do autor, admite, sem se pronunciar sobre o valor desse movimento, que temas de ar sartriano ressurgem nos antropólogos contemporâneos.

  4. Faraday effect in III-VI layer compounds

    Energy Technology Data Exchange (ETDEWEB)

    Gavaleshko, N.P.; Lyakhovich, A.N.; Vatamanyuk, P.P.; Savchuk, A.I. (Chernovitskij Gosudarstvennyj Univ. (Ukrainian SSR))

    1982-10-01

    The Faraday effect is investigated in fields up to 20 T and at temperatures from 77 to 300 K applied to the layer semiconductors GaS, GaSe, and InSe. As an example applicable to the InSe crystals, it is shown possible to separate the direct and indirect forbidden transitions both contributing to the Faraday rotation (FR). The oscillatory nature of the FR spectrum at lower temperatures is proved to be due to the exciton contribution. This is the original report about the FR observed in the depth of the fundamental absorption of InSe crystals. The linearity of the FR in the magnetic field is shown to hold for all the compounds under consideration up to 20 T. The observed data are analyzed in order to estimate some band and exciton parameters of the III-VI semiconductors.

  5. Mechanical Behaviour of Materials Volume II Fracture Mechanics and Damage

    CERN Document Server

    François, Dominique; Zaoui, André

    2013-01-01

    Designing new structural materials, extending lifetimes and guarding against fracture in service are among the preoccupations of engineers, and to deal with these they need to have command of the mechanics of material behaviour. This ought to reflect in the training of students. In this respect, the first volume of this work deals with elastic, elastoplastic, elastoviscoplastic and viscoelastic behaviours; this second volume continues with fracture mechanics and damage, and with contact mechanics, friction and wear. As in Volume I, the treatment links the active mechanisms on the microscopic scale and the laws of macroscopic behaviour. Chapter I is an introduction to the various damage phenomena. Chapter II gives the essential of fracture mechanics. Chapter III is devoted to brittle fracture, chapter IV to ductile fracture and chapter V to the brittle-ductile transition. Chapter VI is a survey of fatigue damage. Chapter VII is devoted to hydogen embrittlement and to environment assisted cracking, chapter VIII...

  6. 76 FR 56982 - Announcement of Federal Underground Injection Control (UIC) Class VI Program for Carbon Dioxide (CO2

    Science.gov (United States)

    2011-09-15

    ... (UIC) Class VI Program for Carbon Dioxide (CO 2 ) Geologic Sequestration (GS) Wells AGENCY... establishment of a Federal Underground Injection Control (UIC) Class VI Program for Carbon Dioxide (CO...

  7. Investigation of U(VI) adsorption in quartz-chlorite mineral mixtures.

    Science.gov (United States)

    Wang, Zheming; Zachara, John M; Shang, Jianying; Jeon, Choong; Liu, Juan; Liu, Chongxuan

    2014-07-15

    A batch and cryogenic laser-induced time-resolved luminescence spectroscopy investigation of U(VI) adsorbed on quartz-chlorite mixtures with variable mass ratios have been performed under field-relevant uranium concentrations (5×10(-7) M and 5×10(-6) M) in pH 8.1 synthetic groundwater. The U(VI) adsorption Kd values steadily increased as the mass fraction of chlorite increased, indicating preferential sorption to chlorite. For all mineral mixtures, U(VI) adsorption Kd values were lower than that calculated from the assumption of component additivity possibly caused by surface modifications stemming from chlorite dissolution; The largest deviation occurred when the mass fractions of the two minerals were equal. U(VI) adsorbed on quartz and chlorite displayed characteristic individual luminescence spectra that were not affected by mineral mixing. The spectra of U(VI) adsorbed within the mixtures could be simulated by one surface U(VI) species on quartz and two on chlorite. The luminescence intensity decreased in a nonlinear manner as the adsorbed U(VI) concentration increased with increasing chlorite mass fraction-likely due to ill-defined luminescence quenching by both structural Fe/Cr in chlorite, and trace amounts of solubilized and reprecipitated Fe/Cr in the aqueous phase. However, the fractional spectral intensities of U(VI) adsorbed on quartz and chlorite followed the same trend of fractional adsorbed U(VI) concentration in each mineral phase with approximate linear correlations, offering a method to estimate of U(VI) concentration distribution between the mineral components with luminescence spectroscopy.

  8. BIOADSORPTION USING COMPOST: AN ALTERNATIVE FOR REMOVAL OF CHROMIUM (VI FROM AQUEOUS SOLUTIONS

    Directory of Open Access Journals (Sweden)

    Claudia Vargas,

    2012-05-01

    Full Text Available The removal of Cr(VI from aqueous solutions was studied using a compost generated from carnation flowers waste. The highest percentage of removal achieved (ca. 99 % was obtained at pH 2.0, using a 10 mg L-1 of Cr(VI solution, a dose of 10 g L-1 of compost, and with an equilibrium time of 3 hours. Under these conditions, the kinetics and adsorption isotherm were examined varying the initial Cr(VI concentration from 15 to 200 mg L-1. The maximum sorption capacity at equilibrium (Qm, from the Langmuir model, was found to be 6.25 mg g-1. The evaluation of Cr(VI removal at pH 2.0 showed a second order kinetics and showed that the process mechanism can be modeled by the “adsorption-coupled reduction” hypothesis. Also, the monitoring of Cr(VI and total Cr in aqueous solutions showed that Cr(VI and total Cr were removed from solution, and that part of the Cr(III was retained on the compost. According to the results, the removal of Cr(VI with the assayed compost can be explained by the following steps: (i adsorption of Cr(VI species onto compost, (ii Cr(VI reduction to Cr(III, and (iii adsorption of part of Cr(III on the compost. Thus, this study suggests that the carnation flower waste compost can be used as a remediation system for water contaminated with Cr(VI.

  9. Integrated Ecogenomics Study for Bioremediation of Cr(VI) at Hanford 100H Area

    Energy Technology Data Exchange (ETDEWEB)

    Chakraborty, Romy; Chakraborty, Romy

    2008-08-12

    Hexavalent chromium is a widespread contaminant found in groundwater. In order to stimulate microbially mediated Cr(VI)-reduction, a poly-lactate compound was injected into Cr(VI)-contaminated aquifers at site 100H at Hanford. Investigation of bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products revealed a stimulation of Pseudomonas, Desulfovibrio and Geobacter species amongst others. Enrichment of these organisms coincided with continued Cr(VI) depletion. Functional gene-array analysis of DNA from monitoring well indicated high abundance of genes involved in nitrate-reduction, sulfate-reduction, iron-reduction, methanogenesis, chromium tolerance/reduction. Clone-library data revealed Psedomonas was the dominant genus in these samples. Based on above results, we conducted lab investigations to study the dominant anaerobic culturable microbial populations present at this site and their role in Cr(VI)-reduction. Enrichments using defined anaerobic media resulted in isolation of an iron-reducing, a sulfate-reducing and a nitrate-reducing isolate among several others. Preliminary 16S rDNA sequence analysis identified the isolates as Geobacter metallireducens, Pseudomonas stutzeri and Desulfovibrio vulgaris species respectively. The Pseudomonas isolate utilized acetate, lactate, glycerol and pyruvate as alternative carbon sources, and reduced Cr(VI). Anaerobic washed cell suspension of strain HLN reduced almost 95?M Cr(VI) within 4 hr. Further, with 100?M Cr(VI) as sole electron-acceptor, cells grew to 4.05 x 107 /ml over 24 h after an initial lag, demonstrating direct enzymatic Cr(VI) reduction coupled to growth. These results demonstrate that Cr(VI)-immobilization at Hanford 100H site could be mediated by direct microbial metabolism in addition to indirect chemical reduction of Cr(VI) by end-products of microbial activity.

  10. Settleability and characteristics of ferrate(VI)-induced particles in advanced wastewater treatment.

    Science.gov (United States)

    Zheng, Lei; Deng, Yang

    2016-04-15

    Ferrate(VI) as an emerging water treatment agent has recently recaptured interests for advanced wastewater treatment. A large number of studies were published to report ferrate(VI)-driven oxidation for various water contaminants. In contrast, very few efforts were made to characterize ferrate(VI) resultant particles in water and wastewater. In this study, jar tests were performed to examine the settleability and characteristics of ferrate(VI)-induced iron oxide particles, particularly the non-settable fraction of these particles, after ferrate(VI) reduction in a biologically treated municipal wastewater. The particle settleability was evaluated through the measurement of turbidity and particulate iron concentration in the supernatant with the settling time. Results showed that a majority of ferrate(VI)-induced iron oxide aggregates remained suspended and caused an increased turbidity. For example, at a Fe(VI) dose of 5.0 mg/L and pH 7.50, 82% of the added iron remained in the supernatant and the turbidity was 8.97 NTU against the untreated sample turbidity (2.33 NTU) after 72-h settling. The poor settling property of these particles suggested that coagulation and flocculation did not perform well in the ferrate(VI) treatment. Particle size analysis and transmission electron microscopy (TEM) revealed that nano-scale particles were produced after ferrate(VI) decomposition, and gradually aggregated to form micro-scale larger particles in the secondary effluent. Zeta potentials of the non-settable ferrate(VI) resultant aggregates varied between -7.36 and -8.01 mV at pH 7.50 during the 72-h settling. The negative surface charges made the aggregates to be relatively stable in the wastewater matrix.

  11. Mechanism of Cr(VI) adsorption by coir pith studied by ESR and adsorption kinetic.

    Science.gov (United States)

    Suksabye, Parinda; Nakajima, Akira; Thiravetyan, Paitip; Baba, Yoshinari; Nakbanpote, Woranan

    2009-01-30

    The oxidation state of chromium in coir pith after Cr(VI) adsorption from aqueous solution was investigated using electron spin resonance (ESR). To elucidate the mechanism of chromium adsorption on coir pith, the adsorption studies of Cr(VI) onto lignin, alpha-cellulose and holocellulose extracted from coir pith were also studied. ESR signals of Cr(V) and Cr(III) were observed in coir pith adsorbed Cr(VI) at solution pH 2, while ESR spectra of lignin extracted from coir pith revealed only the Cr(III) signal. In addition, ESR signal of Cr(V) was observed in alpha-cellulose and holocellulose extracted from coir pith adsorbed Cr(VI). These results confirmed that lignin in coir pith reduced Cr(VI) to Cr(III) while alpha-cellulose and holocellulose extracted from coir pith reduced Cr(VI) to Cr(V). The Cr(V) signal exhibited in ESR of alpha-cellulose and holocellulose might be bound with glucose in cellulose part of coir pith. In addition, xylose which is main in pentosan part of coir pith, indicated that it is involved in form complex with Cr(V) on coir pith. The adsorption kinetic of Cr(VI) from aqueous solution on coir pith was also investigated and described well with pseudo second order model. ESR and desorption experiments confirmed that Cr(VI), Cr(V) and Cr(III), exist in coir pith after Cr(VI) adsorption. The desorption data indicated that the percentage of Cr(VI), Cr(V) and Cr(III) in coir pith were 15.63%, 12.89% and 71.48%, respectively.

  12. Mechanism of Cr(VI) adsorption by coir pith studied by ESR and adsorption kinetic

    Energy Technology Data Exchange (ETDEWEB)

    Suksabye, Parinda [Joint Graduate School of Energy and Environment, King Mongkut' s University of Technology Thonburi, 91 Pracha-Utit Road, Bangmod, Thungkru, Bangkok 10140 (Thailand); Nakajima, Akira [Division of Chemistry, Department of Medical Science, Faculty of Medicine, University of Miyazaki, Kiyotake, Miyazaki 889 1692 (Japan); Thiravetyan, Paitip [Division of Biotechnology, School of Bioresources and Technology, King Mongkut' s University of Technology Thonburi, 83 Moo.8 Thakham, Bangkhuntien, Bangkok 10150 (Thailand)], E-mail: paitip.thi@kmutt.ac.th; Baba, Yoshinari [Department of applied Chemistry, Faculty of Technology, University of Miyazaki, Gakuen-Kibabadai, Miyazaki 889 2192 (Japan); Nakbanpote, Woranan [Pilot Plant Development and Training Institute, King Mongkut' s University of Technology Thonburi, 83 Moo.8 Thakham, Bangkhuntien, Bangkok 10150 (Thailand)

    2009-01-30

    The oxidation state of chromium in coir pith after Cr(VI) adsorption from aqueous solution was investigated using electron spin resonance (ESR). To elucidate the mechanism of chromium adsorption on coir pith, the adsorption studies of Cr(VI) onto lignin, {alpha}-cellulose and holocellulose extracted from coir pith were also studied. ESR signals of Cr(V) and Cr(III) were observed in coir pith adsorbed Cr(VI) at solution pH 2, while ESR spectra of lignin extracted from coir pith revealed only the Cr(III) signal. In addition, ESR signal of Cr(V) was observed in {alpha}-cellulose and holocellulose extracted from coir pith adsorbed Cr(VI). These results confirmed that lignin in coir pith reduced Cr(VI) to Cr(III) while {alpha}-cellulose and holocellulose extracted from coir pith reduced Cr(VI) to Cr(V). The Cr(V) signal exhibited in ESR of {alpha}-cellulose and holocellulose might be bound with glucose in cellulose part of coir pith. In addition, xylose which is main in pentosan part of coir pith, indicated that it is involved in form complex with Cr(V) on coir pith. The adsorption kinetic of Cr(VI) from aqueous solution on coir pith was also investigated and described well with pseudo second order model. ESR and desorption experiments confirmed that Cr(VI), Cr(V) and Cr(III), exist in coir pith after Cr(VI) adsorption. The desorption data indicated that the percentage of Cr(VI), Cr(V) and Cr(III) in coir pith were 15.63%, 12.89% and 71.48%, respectively.

  13. Estancia Basin dynamic water budget.

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Richard P.

    2004-09-01

    The Estancia Basin lies about 30 miles to the east of Albuquerque, NM. It is a closed basin in terms of surface water and is somewhat isolated in terms of groundwater. Historically, the primary natural outlet for both surface water and groundwater has been evaporation from the salt lakes in the southeastern portion of the basin. There are no significant watercourses that flow into this basin and groundwater recharge is minimal. During the 20th Century, agriculture grew to become the major user of groundwater in the basin. Significant declines in groundwater levels have accompanied this agricultural use. Domestic and municipal use of the basin groundwater is increasing as Albuquerque population continues to spill eastward into the basin, but this use is projected to be less than 1% of agricultural use well into the 21st Century. This Water Budget model keeps track of the water balance within the basin. The model considers the amount of water entering the basin and leaving the basin. Since there is no significant surface water component within this basin, the balance of water in the groundwater aquifer constitutes the primary component of this balance. Inflow is based on assumptions for recharge made by earlier researchers. Outflow from the basin is the summation of the depletion from all basin water uses. The model user can control future water use within the basin via slider bars that set values for population growth, water system per-capita use, agricultural acreage, and the types of agricultural diversion. The user can also adjust recharge and natural discharge within the limits of uncertainty for those parameters. The model runs for 100 years beginning in 1940 and ending in 2040. During the first 55 years model results can be compared to historical data and estimates of groundwater use. The last 45 years are predictive. The model was calibrated to match to New Mexico Office of State Engineer (NMOSE) estimates of aquifer storage during the historical period by

  14. Estimate of the Geothermal Energy Resource in the Major Sedimentary Basins in the United States (Presentation)

    Energy Technology Data Exchange (ETDEWEB)

    Esposito, A.; Porro, C.; Augustine, C.; Roberts, B.

    2012-09-01

    Because most sedimentary basins have been explored for oil and gas, well logs, temperatures at depth, and reservoir properties such as depth to basement and formation thickness are well known. The availability of this data reduces exploration risk and allows development of geologic exploration models for each basin. This study estimates the magnitude of recoverable geothermal energy from 15 major known U.S. sedimentary basins and ranks these basins relative to their potential. The total available thermal resource for each basin was estimated using the volumetric heat-in-place method originally proposed by (Muffler, 1979). A qualitative recovery factor was determined for each basin based on data on flow volume, hydrothermal recharge, and vertical and horizontal permeability. Total sedimentary thickness maps, stratigraphic columns, cross sections, and temperature gradient information was gathered for each basin from published articles, USGS reports, and state geological survey reports. When published data were insufficient, thermal gradients and reservoir properties were derived from oil and gas well logs obtained on oil and gas commission databases. Basin stratigraphy, structural history, and groundwater circulation patterns were studied in order to develop a model that estimates resource size, temperature distribution, and a probable quantitative recovery factor.

  15. Heavy Oil and Natural Bitumen Resources in Geological Basins of the World

    Science.gov (United States)

    Meyer, Richard F.; Attanasi, E.D.; Freeman, P.A.

    2007-01-01

    Heavy oil and natural bitumen are oils set apart by their high viscosity (resistance to flow) and high density (low API gravity). These attributes reflect the invariable presence of up to 50 weight percent asphaltenes, very high molecular weight hydrocarbon molecules incorporating many heteroatoms in their lattices. Almost all heavy oil and natural bitumen are alteration products of conventional oil. Total resources of heavy oil in known accumulations are 3,396 billion barrels of original oil in place, of which 30 billion barrels are included as prospective additional oil. The total natural bitumen resource in known accumulations amounts to 5,505 billion barrels of oil originally in place, which includes 993 billion barrels as prospective additional oil. This resource is distributed in 192 basins containing heavy oil and 89 basins with natural bitumen. Of the nine basic Klemme basin types, some with subdivisions, the most prolific by far for known heavy oil and natural bitumen volumes are continental multicyclic basins, either basins on the craton margin or closed basins along convergent plate margins. The former includes 47 percent of the natural bitumen, the latter 47 percent of the heavy oil and 46 percent of the natural bitumen. Little if any heavy oil occurs in fore-arc basins, and natural bitumen does not occur in either fore-arc or delta basins.

  16. USING SRTM TO QUANTIFY SIZE PARAMETERS AND SPATIAL DISTRIBUTION OF ENDORHEIC BASINS IN SOUTHERN SOUTH AMERICA

    Directory of Open Access Journals (Sweden)

    Ralf Hesse

    2008-08-01

    Full Text Available The SRTM data set is the highest resolution DEM with global or continental coverage. It is therefore theDEM of choice for continental-scale geomorphological mapping and quantitative analysis. In this study,SRTM data are used for the identification and characterisation of endorheic basins in southern SouthAmerica (south of 19°S. The results show the feasibility of continental-scale quantitative geomorphologybased on SRTM data and provide insights into the distribution of closed basins. The largest endorheicbasin is located in the Puna region and consists of several interconnected sub-basins. This basin accountsfor 38.6 % (7877 km3 of the total volume of the endorheic basins identified in this study. Analyses of thegeographic distribution show a narrow longitudinal distribution between 64.5 and 71.5° W and a multimodallatitudinal distribution which is characterised by two groups of basins at 22.5–27.5°S and 37.5–50.0° Sand an almost complete absence of basins between 27.5 and 37.5° S. Problems and sources ofmisinterpretation arising from data quality and resolution are discussed. Further research, targeting in particularthe genesis and potential for paleoenvironmental reconstruction of closed basins in southern Argentina, iscalled for.

  17. A Physically Based Runoff Model Analysis of the Querétaro River Basin

    Directory of Open Access Journals (Sweden)

    Carlos Javier Villa Alvarado

    2014-01-01

    Full Text Available Today the knowledge of physical parameters of a basin is essential to know adequately the rainfall-runoff process; it is well known that the specific characteristics of each basin such as temperature, geographical location, and elevation above sea level affect the maximum discharge and the basin time response. In this paper a physically based model has been applied, to analyze water balance by evaluating the volume rainfall-runoff using SHETRAN and hydrometric data measurements in 2003. The results have been compared with five ETp different methodologies in the Querétaro river basin in central Mexico. With these results the main effort of the authorities should be directed to better control of land-use changes and to working permanently in the analysis of the related parameters, which will have a similar behavior to changes currently being introduced and presented in observed values in this basin. This methodology can be a strong base for sustainable water management in a basin, the prognosis and effect of land-use changes, and availability of water and also can be used to determine application of known basin parameters, basically depending on land-use, land-use changes, and climatological database to determine the water balance in a basin.

  18. Regulation of a viral proteinase by a peptide and DNA in one-dimensional space: I. binding to DNA AND to hexon of the precursor to protein VI, pVI, of human adenovirus.

    Science.gov (United States)

    Graziano, Vito; McGrath, William J; Suomalainen, Maarit; Greber, Urs F; Freimuth, Paul; Blainey, Paul C; Luo, Guobin; Xie, X Sunney; Mangel, Walter F

    2013-01-18

    The precursor to adenovirus protein VI, pVI, is a multifunctional protein with different roles early and late in virus infection. Here, we focus on two roles late in infection, binding of pVI to DNA and to the major capsid protein hexon. pVI bound to DNA as a monomer independent of DNA sequence with an apparent equilibrium dissociation constant, K(d)((app)), of 46 nm. Bound to double-stranded DNA, one molecule of pVI occluded 8 bp. Upon the binding of pVI to DNA, three sodium ions were displaced from the DNA. A ΔG(0)(0) of -4.54 kcal/mol for the nonelectrostatic free energy of binding indicated that a substantial component of the binding free energy resulted from nonspecific interactions between pVI and DNA. The proteolytically processed, mature form of pVI, protein VI, also bound to DNA; its K(d)((app)) was much higher, 307 nm. The binding assays were performed in 1 mm MgCl(2) because in the absence of magnesium, the binding to pVI or protein VI to DNA was too tight to determine a K(d)((app)). Three molecules of pVI bound to one molecule of the hexon trimer with an equilibrium dissociation constant K(d)((app)) of 1.1 nm.

  19. GRACE captures basin mass dynamic changes in China based on a multi-basin inversion method

    Science.gov (United States)

    Yi, Shuang; Wang, Qiuyu; Sun, Wenke

    2016-04-01

    Complex landform, miscellaneous climate and enormous population have enriched China with geophysical phenomena ranging from water depletion in the underground to glaciers retreat on the high mountains and have aroused large scientific interests. This paper, utilizing gravity observations 2003-2014 from the Gravity Recovery and Climate Experiment (GRACE), intends to make a comprehensive estimation of mass status in 16 drainage basins in the whole region. We proposed a multi-basin inversion method, which is featured by resistance to the stripe noise and ability to alleviate signal attenuation due to truncation and smoothing of GRACE data. The results show both positive and negative trends: there is a tremendous mass accumulation spreading from the Tibetan plateau (12.2 ± 0.6 Gt/yr) to the Yangtze River (7.6 ± 1.3 Gt/yr), and further to the southeast coastal areas, which is suggested to involve an increase in the ground water storage, lake and reservoir water volume and likely materials flowed in by tectonic process; a mass loss is occurring in Huang-Huai-Hai-Liao River Basin (-10.5 ± 0.8 Gt/yr), as well as the Brahmaputra-Nujiang-Lancang River Basin (-15.0 ± 0.9 Gt/yr) and Tienshan Mountain (-4.1 ± 0.3 Gt/yr), which is a result of groundwater pumping and glacier melting. The groundwater depletion area is well consistent with the distribution of land subsidence in North China. In the end, we find intensified precipitation can alter the local water supply and GRACE is proficient to capture this dynamics, which could be instructive for the South-to-North Water Diversion - one China's giant hydrologic project.

  20. Utilities and offsites design baseline. Outside Battery Limits Facility 6000 tpd SRC-I Demonstration Plant. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    None

    1984-05-25

    As part of the overall Solvent Refined Coal (SRC-1) project baseline being prepared by International Coal Refining Company (ICRC), the RUST Engineering Company is providing necessary input for the Outside Battery Limits (OSBL) Facilities. The project baseline is comprised of: design baseline - technical definition of work; schedule baseline - detailed and management level 1 schedules; and cost baseline - estimates and cost/manpower plan. The design baseline (technical definition) for the OSBL Facilities has been completed and is presented in Volumes I, II, III, IV, V and VI. The OSBL technical definition is based on, and compatible with, the ICRC defined statement of work, design basis memorandum, master project procedures, process and mechanical design criteria, and baseline guidance documents. The design basis memorandum is included in Paragraph 1.3 of Volume I. The baseline design data is presented in 6 volumes. Volume I contains the introduction section and utility systems data through steam and feedwater. Volume II continues with utility systems data through fuel system, and contains the interconnecting systems and utility system integration information. Volume III contains the offsites data through water and waste treatment. Volume IV continues with offsites data, including site development and buildings, and contains raw materials and product handling and storage information. Volume V contains wastewater treatment and solid wastes landfill systems developed by Catalytic, Inc. to supplement the information contained in Volume III. Volume VI contains proprietary information of Resources Conservation Company related to the evaporator/crystallizer system of the wastewater treatment area.

  1. Tetrapotassium cis-dioxido-trans-bis(sulfato-kappa O)sulfato(kappa O-2,O ')molybdate(VI)

    DEFF Research Database (Denmark)

    Schäffer, Susan Jeanne Cline; Berg, Rolf W.

    2008-01-01

    The title compound, K-4[(MoO2)-O-VI(SO4)(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [(MoO2)-O-VI(SO4)(3)](4-) anions, with the Mo-VI atom, both oxide ligands, and the S atom and both ligating O atoms...

  2. Meteorological, stream-discharge, and water-quality data for 1986 through 1991 from two small basins in central Nevada

    Energy Technology Data Exchange (ETDEWEB)

    McKinley, P.W.; Oliver, T.A.

    1994-04-01

    The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, is investigating the volcanic tuffs of Yucca Mountain, Nevada, for their suitability as storage sites for nuclear waste. Two small basins, measuring less than 2 square miles, were studied to determine the volume of precipitation available for recharge to the ground water. The semiarid 3 Springs Basin is located to the east of Kawich Peak in the Kawich Range east of Tonopah, Nevada. Stewart Basin is a subalpine drainage basin north of Arc Dome in the Toiyabe Range north of Tonopah, Nevada. This publication presents the meteorological, stream-discharge, and water-quality data collected during the study. Meteorological data collected include air temperature, soil temperature, solar radiation, and relative humidity. Stream-discharge data were collected from the surface-water outlet of each basin. Water-quality data are chemical analyses of water samples collected from surface- and ground-water sources. Data were collected throughout the two basins. Each basin has a meteorological station located in the lower and upper reaches of the basin. Hydrologic records include stream-discharge and water-quality data from the lower meteorological site and water-quality data from springs within the basins. Meteorological data are available from the lower sites from the winter of 1986 through the fall of 1991. Periods of data collection were shorter for additional sites in the basin.

  3. Large scale groundwater flow and hexavalent chromium transport modeling under current and future climatic conditions: the case of Asopos River Basin.

    Science.gov (United States)

    Dokou, Zoi; Karagiorgi, Vasiliki; Karatzas, George P; Nikolaidis, Nikolaos P; Kalogerakis, Nicolas

    2016-03-01

    In recent years, high concentrations of hexavalent chromium, Cr(VI), have been observed in the groundwater system of the Asopos River Basin, raising public concern regarding the quality of drinking and irrigation water. The work described herein focuses on the development of a groundwater flow and Cr(VI) transport model using hydrologic, geologic, and water quality data collected from various sources. An important dataset for this goal comprised an extensive time series of Cr(VI) concentrations at various locations that provided an indication of areas of high concentration and also served as model calibration locations. Two main sources of Cr(VI) contamination were considered in the area: anthropogenic contamination originating from Cr-rich industrial wastes buried or injected into the aquifer and geogenic contamination from the leaching process of ophiolitic rocks. The aquifer's response under climatic change scenario A2 was also investigated for the next two decades. Under this scenario, it is expected that rainfall, and thus infiltration, will decrease by 7.7 % during the winter and 15 % during the summer periods. The results for two sub-scenarios (linear and variable precipitation reduction) that were implemented based on A2 show that the impact on the study aquifer is moderate, resulting in a mean level decrease less than 1 m in both cases. The drier climatic conditions resulted in higher Cr(VI) concentrations, especially around the industrial areas.

  4. Luminescence dating of ancient Darhad basin, Mongolia

    Science.gov (United States)

    Cheul Kim, Jin; Yi, Sangheon; Lim, Jaesoo; Kim, Ju-Yong

    2016-04-01

    . Thus, age control on existing 14C ages from this site is limited, chronological interpretation based on the 14C ages is still incomplete in Hodon outcrop sediments. OSL (Optically Stimulated Luminescence) is an alternative method for dating to overcome the problems associated with 14C methods. OSL has been extensively used for dating arctic sediments (Thomas et al., 2006; more). Previous optical ages on Darhad paleolake sediments obtained using IRSL (Infrared-stimulated luminescence) on feldspars (Gillespie et al., 2008; Batbaatar et al., 2009). Feldspar has much brighter luminescence than quartz, while the OSL signal of feldspars bleaches at least one order of magnitude slower than the OSL signal of quartz (Godfrey-Smith et al., 1988; Huntly and Lamothe, 2001; Mauz and Bungenstock, 2007; Kim et al., 2012). In glaciofluvial, glaciolacustrine environments, inadequate bleaching of the OSL signal is known to be a potential problem of burial ages (Thomas et al., 2006). OSL dating of permafrost deposits may also involve uncertainty about the inhomogeneous radiation field surrounding the dosimeter and the absorption of ionizing energy alternately by water and ice in a not-constant pore volume (Haeberli et al., 2003). In this study, we test the applicability of quartz OSL dating for the uppermost paleolake sediments in the Hodon outcrop of the Darhad basin. The OSL results were systematically compared with additional radiocarbon ages from wood fragments to conclude the reliability of the OSL dates and to construct intensive chronology for Late-Pleistocene Darhad paleolake. To evaluate the time of recent expansion of the paleolake, the northern piedmont (Talyn outcrop) of the basin was dated by OSL.

  5. Influence of soil minerals on chromium(VI reduction by sulfide under anoxic conditions

    Directory of Open Access Journals (Sweden)

    Kim Chulsung

    2007-04-01

    Full Text Available Abstract The effects of soil minerals on chromate (CrVIO42-, noted as Cr(VI reduction by sulfide were investigated in the pH range of 7.67 to 9.07 under the anoxic condition. The examined minerals included montmorillonite (Swy-2, illite (IMt-2, kaolinite (KGa-2, aluminum oxide (γ-Al2O3, titanium oxide (TiO2, P-25, primarily anatase, and silica (SiO2. Based on their effects on Cr(VI reduction, these minerals were categorized into three groups: (i minerals catalyzing Cr(VI reduction – illite; (ii minerals with no effect – Al2O3; and (iii minerals inhibiting Cr(VI reduction- kaolinite, montmorillonite, SiO2 and TiO2 . The catalysis of illite was attributed primarily to the low concentration of iron solubilized from the mineral, which could accelerate Cr(VI reduction by shuttling electrons from sulfide to Cr(VI. Additionally, elemental sulfur produced as the primary product of sulfide oxidation could further catalyze Cr(VI reduction in the heterogeneous system. Previous studies have shown that adsorption of sulfide onto elemental sulfur nanoparticles could greatly increase sulfide reactivity towards Cr(VI reduction. Consequently, the observed rate constant, kobs, increased with increasing amounts of both iron solubilized from illite and elemental sulfur produced during the reaction. The catalysis of iron, however, was found to be blocked by phenanthroline, a strong complexing agent for ferrous iron. In this case, the overall reaction rate at the initial stage of reaction was pseudo first order with respect to Cr(VI, i.e., the reaction kinetics was similar to that in the homogeneous system, because elemental sulfur exerted no effect at the initial stage prior to accumulation of elemental sulfur nanoparticles. In the suspension of kaolinite, which belonged to group (iii, an inhibitive effect to Cr(VI reduction was observed and subsequently examined in more details. The inhibition was due to the sorption of elemental sulfur onto kaolinite, which

  6. Multinary I-III-VI2 and I2-II-IV-VI4 Semiconductor Nanostructures for Photocatalytic Applications.

    Science.gov (United States)

    Regulacio, Michelle D; Han, Ming-Yong

    2016-03-15

    are the multinary chalcogenide semiconductors (MCSs), which include the ternary I-III-VI2 semiconductors (e.g., AgGaS2, CuInS2, and CuInSe2) and the quaternary I2-II-IV-VI4 semiconductors (e.g., Cu2ZnGeS4, Cu2ZnSnS4, and Ag2ZnSnS4). These inorganic compounds consist of environmentally benign elemental components, exhibit excellent light-harvesting properties, and possess band gap energies that are well-suited for solar photon absorption. Moreover, the band structures of these materials can be conveniently modified through alloying to boost their ability to harvest visible photons. In this Account, we provide a summary of recent research on the use of ternary I-III-VI2 and quaternary I2-II-IV-VI4 semiconductor nanostructures for light-induced photocatalytic applications, with focus on hydrogen production and organic dye degradation. We include a review of the solution-based methods that have been employed to prepare multinary chalcogenide semiconductor nanostructures of varying compositions, sizes, shapes, and crystal structures, which are factors that are known to have significant influence on the photocatalytic activity of semiconductor photocatalysts. The enhancement of photocatalytic performance through creation of hybrid nanoscale architectures is also presented. Lastly, views on the current challenges and future directions are discussed in the concluding section.

  7. Simultaneous determination of chromium(III) and chromium(VI) in aqueous solutions by ion chromatography and chemiluminescence detection

    DEFF Research Database (Denmark)

    Gammelgaard, Bente; Jøns, O; Nielsen, B

    1992-01-01

    A method for the simultaneous determination of chromium(iii) and chromium(vi) in a flow system based on chemiluminescence was developed. A Dionex cation-exchange guard column was used to separate chromium(iii) from chromium(vi), and chromium(vi) was reduced by potassium sulfite, whereupon both...

  8. Hydroclimatological Aspects of the Extreme 2011 Assiniboine River Basin Flood

    Science.gov (United States)

    Brimelow, J.; Szeto, K.; Bonsal, B. R.; Hanesiak, J.; Kochtubajda, B.; Stewart, R. E.

    2014-12-01

    In the spring and early summer of 2011, the Assiniboine River Basin in Canada experienced an extreme flood that was unprecedented in terms of duration and volume of water. The flood had significant socioeconomic impacts and caused over one billion dollars in damage. Contrary to what one might expect for such an extreme flood, individual precipitation events before and during the 2011 flood were not extreme; instead, it was the cumulative impact and timing of precipitation events going back to the summer of 2010 that played a key role in the 2011 flood. The summer and fall of 2010 were exceptionally wet, resulting in soil moisture levels being much above normal at the time of freeze up. This was followed by above-average precipitation during the winter of 2010-2011, and record-breaking basin-averaged snow-water equivalent values in March and April 2011. Abnormally cold temperatures in March delayed the spring melt by about two weeks, with the result that the above-average seasonal melt freshet occurred close to the onset of abnormally heavy rains in May and June. The large-scale atmospheric flow during May and June 2011 favoured increased cyclone activity over the central and northern U.S., which produced an anomalously large number of heavy rainfall events over the basin. All of these factors combined to generate extreme surface runoff and flooding. We used JRA-55 reanalysis data to quantify the relative importance of snowmelt, soil moisture and spring precipitation in contributing to the unprecedented flood and to demonstrate how the 2011 flood was unique compared to previous floods in the basin. Data and research from this study can be used to validate and improve flood forecasting techniques over this important basin; our findings also raise important questions regarding the impact of climate change on basins that experience pluvial and nival flooding.

  9. K-Basins design guidelines

    Energy Technology Data Exchange (ETDEWEB)

    Roe, N.R.; Mills, W.C.

    1995-06-01

    The purpose of the design guidelines is to enable SNF and K Basin personnel to complete fuel and sludge removal, and basin water mitigation by providing engineering guidance for equipment design for the fuel basin, facility modifications (upgrades), remote tools, and new processes. It is not intended to be a purchase order reference for vendors. The document identifies materials, methods, and components that work at K Basins; it also Provides design input and a technical review process to facilitate project interfaces with operations in K Basins. This document is intended to compliment other engineering documentation used at K Basins and throughout the Spent Nuclear Fuel Project. Significant provisions, which are incorporated, include portions of the following: General Design Criteria (DOE 1989), Standard Engineering Practices (WHC-CM-6-1), Engineering Practices Guidelines (WHC 1994b), Hanford Plant Standards (DOE-RL 1989), Safety Analysis Manual (WHC-CM-4-46), and Radiological Design Guide (WHC 1994f). Documents (requirements) essential to the engineering design projects at K Basins are referenced in the guidelines.

  10. A novel polymer inclusion membrane applied in chromium (VI) separation from aqueous solutions.

    Science.gov (United States)

    Gherasim, Cristina-Veronica; Bourceanu, Gelu; Olariu, Romeo-Iulian; Arsene, Cecilia

    2011-12-15

    In the present work, we analyze the transport properties of a novel polymer inclusion membrane (PIM) containing a poly-vinyl chloride (PVC) polymer matrix and the organic anion exchanger Aliquat 336 as a specific carrier, without addition of plasticizers. The study was specifically focused on the transport properties of Cr(VI) in conditions simulating industrial wastewaters. We analyzed the impact of several parameters on the Cr(VI) transport process such as: the carrier content of the PIM, the pH, and the phases' composition. We concluded that efficient transport processes occur through a PIM containing 40% Aliquat 336/60% PVC (w/w). The process is very fast and efficient for solutions of initial Cr(VI) concentration smaller than 10(-3)mol/L, in which nearly all of Cr(VI) is removed within 3h. The performed experiments prove that Cr(VI) transport through the membrane is a facilitated counter-transport process. The obtained results sustain that this novel non-plasticized membrane possesses enhanced transport properties towards other liquid membranes and plasticized PIMs previously reported as used for Cr(VI) transport. Additionally, it possesses an excellent reliability and a high selectivity for Cr(VI) from mixtures with other metal ions and anions existing in the real industrial effluents. The PIM characterization highlights the plasticizing role of the carrier Aliquat 336.

  11. Removal of chromium(VI) from aqueous solutions by polymer inclusion membranes.

    Science.gov (United States)

    Kozlowski, Cezary A; Walkowiak, Wladyslaw

    2002-11-01

    The transport through polymer inclusion membranes (PIMs) was found as the effective and selective method of chromium(VI) anions removal from chloride acidic aqueous solutions. The optimal PIMs content was as follows: 41 wt% of cellulose triacetate as the support, 23 wt% of tri-n-octylamine as the ionic carrier, and 36 wt% of o-nitrophenyl pentyl ether as the plasticizer. The results obtained show a linear decrease of permeability coefficient and initial flux values with source phase pH increase. Also linear decrease of initial flux in log-log scale with chromium(VI) concentration increase was observed. Value of slope of this relationship was found to be 0.96 which indicates a first order of chromium(VI) reaction with tri-n-octylamine at membrane/aqueous source interface. Transport of chromium(VI) through PIMs reduces the concentration of chromium(VI) in source aqueous phase from 1.0 to 0.0028 ppm, which is below permissible limit in drinking water in Poland. Competitive transport of chromium(VI), cadmium(II), zinc(II), and iron(III) from acidic aqueous solution across PIMs was found to be efficient for chromium(VI) (99%), and cadmium(II) (99%).

  12. Adsorption of Chromium(VI from Aqueous Solutions by Coffee Polyphenol-Formaldehyde/Acetaldehyde Resins

    Directory of Open Access Journals (Sweden)

    Khudbudin Mulani

    2013-01-01

    Full Text Available Removal of chromium(VI from wastewater is essential as it is toxic. Thus, removal of chromium(VI was performed using coffee polyphenol-formaldehyde/acetaldehyde resins as adsorbents. Adsorbent resins were prepared by condensation of decaffeinated coffee powder with formaldehyde/acetaldehyde and used for the removal of Cr(VI ions from aqueous solutions. A simple and sensitive solid phase extraction procedure was applied for the determination of chromium at trace levels by spectroscopic method using 1,5-diphenylcarbazide reagent. The adsorption of Cr(VI on the coffee polyphenol-formaldehyde/acetaldehyde resins was monitored by FTIR and EDX analysis. The metal adsorption parameters such as contact time, pH, Cr(VI ion concentration, and adsorbent dose were investigated. For Cr(VI, the maximum adsorption capacity of coffee polyphenol-formaldehyde resins was 98% at pH 2. The experimental results showed that Cr(VI bound strongly with coffee polyphenol-formaldehyde/acetaldehyde resins and utilization of resins could be improved greatly by reuse.

  13. Bioaccumulation of U(VI) by Sulfolobus acidocaldarius under moderate acidic conditions

    Energy Technology Data Exchange (ETDEWEB)

    Reitz, T.; Merroun, M.L.; Rossberg, A.; Steudtner, R.; Selenska-Pobell, S. [Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany). Inst. of Radiochemistry

    2011-07-01

    U(VI) accumulation by the acidothermophilic archaeon Sulfolobus acidocaldarius at a moderate acidic pH of 4.5 was investigated. This pH value is relevant for some heavy metal and uranium polluted environments where populations of S. acidocaldarius were found to persist. We demonstrate that U(VI) is rapidly complexed by the archaeal cells. A combination of X-ray absorption spectroscopy and time-resolved laser-induced fluorescence spectroscopy revealed that at pH 4.5 organic phosphate and carboxylic groups are involved in the U(VI) complexation. These results are in contrast to those published for most bacteria which at this pH precipitate U(VI) mainly in inorganic uranyl phosphate phases. As demonstrated by TEM only a limited part of the added U(VI) was biomineralized extracellularly in the case of the studied archaeon. Most of the U(VI) accumulates were localized in a form of intracellular deposits which were associated with the inner side of the cytoplasma membrane. Observed differences in U(VI) bioaccumulation between the studied archaeon and bacteria can be explained by the significant differences in their cell wall structures as well as by their different physiological characteristics. (orig.)

  14. Myosin VI contributes to synaptic transmission and development at the Drosophila neuromuscular junction

    Directory of Open Access Journals (Sweden)

    Campbell Shelagh

    2011-07-01

    Full Text Available Abstract Background Myosin VI, encoded by jaguar (jar in Drosophila melanogaster, is a unique member of the myosin superfamily of actin-based motor proteins. Myosin VI is the only myosin known to move towards the minus or pointed ends of actin filaments. Although Myosin VI has been implicated in numerous cellular processes as both an anchor and a transporter, little is known about the role of Myosin VI in the nervous system. We previously recovered jar in a screen for genes that modify neuromuscular junction (NMJ development and here we report on the genetic analysis of Myosin VI in synaptic development and function using loss of function jar alleles. Results Our experiments on Drosophila third instar larvae revealed decreased locomotor activity, a decrease in NMJ length, a reduction in synaptic bouton number, and altered synaptic vesicle localization in jar mutants. Furthermore, our studies of synaptic transmission revealed alterations in both basal synaptic transmission and short-term plasticity at the jar mutant neuromuscular synapse. Conclusions Altogether these findings indicate that Myosin VI is important for proper synaptic function and morphology. Myosin VI may be functioning as an anchor to tether vesicles to the bouton periphery and, thereby, participating in the regulation of synaptic vesicle mobilization during synaptic transmission.

  15. O vi Emission from the Supernovae-regulated Interstellar Medium: Simulation versus Observation

    Science.gov (United States)

    Li, Miao; Bryan, Greg L.; Ostriker, Jeremiah P.

    2017-01-01

    The O vi λλ1032, 1038 Å doublet emission traces collisionally ionized gas with T≈ {10}5.5 K, where the cooling curve peaks for metal-enriched plasma. This warm-hot phase is usually not well-resolved in numerical simulations of the multiphase interstellar medium (ISM), but can be responsible for a significant fraction of the emitted energy. Comparing simulated O vi emission to observations is therefore a valuable test of whether simulations predict reasonable cooling rates from this phase. We calculate O vi λ1032 Å emission, assuming collisional ionization equilibrium, for our small-box simulations of the stratified ISM regulated by supernovae. We find that the agreement is very good for our solar neighborhood model, both in terms of emission flux and mean O vi density seen in absorption. We explore runs with higher surface densities and find that, in our simulations, the O vi emission from the disk scales roughly linearly with the star formation rate. Observations of O vi emission are rare for external galaxies, but our results do not show obvious inconsistency with the existing data. Assuming the solar metallicity, O vi emission from the galaxy disk in our simulations accounts for roughly 0.5% of supernovae heating.

  16. Reduction and removal of Cr(VI) from aqueous solutions using modified byproducts of beer production.

    Science.gov (United States)

    Cui, Haojie; Fu, Minglai; Yu, Shen; Wang, Ming Kuang

    2011-02-28

    Biosorption, as an effective and low-cost technology treating industrial wastewaters containing Cr(VI), has become a significant concern worldwide. In this work, acid-modified byproducts of beer production (BBP) were used to remove Cr(VI) from aqueous solutions. Removal of Cr(VI) increases as the pH is decreased from 4.0 to 1.5, but the maximum of total Cr removal is obtained in a pH range from 2.0 to 2.5. Nearly 60% of the initial Cr(VI) (100 mg L(-1)) was adsorbed or reduced to Cr(III) within the first 10 min at pH 2.0. The Cr(VI) removal capability of acid-modified BBP materials was almost completely retained after regenerating with acid. FT-IR and XPS spectra revealed that carboxylate and carboxyl groups on the surface of modified BBP materials play a major role in Cr(VI) binding and reduction, whereas amide and other groups play a minor role in the Cr(VI) removal process.

  17. Cr(VI) reduction at rutile-catalyzed cathode in microbial fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Li, Yan; Lu, Anhuai; Ding, Hongrui; Yan, Yunhua; Wang, Changqiu; Zen, Cuiping; Wang, Xin [The Key Laboratory of Orogenic Belts and Crustal Evolution, School of Earth and Space Sciences, Peking University, Beijing 100871 (China); Jin, Song [MWH Americas, 3665 JFK Parkway, Suite 206, Fort Collins, CO 80525 (United States); Department of Civil and Architectural Engineering, University of Wyoming, Laramie, WY 82071 (United States)

    2009-07-15

    Cathodic reduction of hexavalent chromium (Cr(VI)) and simultaneous power generation were successfully achieved in a microbial fuel cell (MFC) containing a novel rutile-coated cathode. The selected rutile was previously characterized to be sensitive to visible light and capable of both non-photo- and photocatalysis. In the MFCs containing rutile-coated cathode, Cr(VI) was rapidly reduced in the cathode chamber in presence and absence of light irradiation; and the rate of Cr(VI) reduction under light irradiation was substantially higher than that in the dark. Under light irradiation, 97% of Cr(VI) (initial concentration 26 mg/L) was reduced within 26 h, which was 1.6 x faster than that in the dark controls in which only background non-photocatalysis occurred. The maximal potential generated under light irradiation was 0.80 vs. 0.55 V in the dark controls. These results indicate that photocatalysis at the rutile-coated cathode in the MFCs might have lowered the cathodic overpotential, and enhanced electron transfer from the cathode to Cr(VI) for its reduction. In addition, photoexcited electrons generated during the cathode photocatalysis might also have contributed to the higher Cr(VI) reduction rates when under light irradiation. This work assessed natural rutile as a novel cathodic catalyst for MFCs in power generation; particularly it extended the practical merits of conventional MFCs to cathodic reduction of environmental contaminants such as Cr(VI). (author)

  18. Hydrogeology of the Socorro and La Jencia basins, Socorro County, New Mexico

    Science.gov (United States)

    Anderholm, Scott K.

    1987-01-01

    The Socorro and La Jencia Basins are located in central Socorro County, New Mexico. The principal aquifer system in the Socorro and La Jencia Basins consists of, in descending order, the shallow aquifer, the Popotosa confining bed, and the Popotosa aquifer. The minor aquifer systems, which are dominant along the basin margins, are the Socorro volcanics aquifer system and the Mesozoic-Paleozoic aquifer system. On the east side of the Socorro Basin, water enters the principal aquifer system from the Mesozoic-Paleozoic aquifer system. On the west side of the Socorro Basin, groundwater flows from the principal aquifer system in La Jencia Basin eastward to the principal aquifer system in the Socorro Basin. The volume of this flow is limited by the permeability of the minor aquifer systems and the Popotosa confining bed. A water budget indicates that if no change in groundwater storage occurs in the Socorro Basin, groundwater inflow to the basin is about 53,000 acre-feet per year greater than groundwater outflow. Dissolution of gypsum, calcite, and dolomite seems to control water quality in the Mesozoic-Paleozoic aquifer. Water with a chloride concentration of as much as 1,000 milligrams per liter and a specific conductance of as much as 6,700 microsiemens per centimeter at 25 C is present in the northern and southern parts of the Socorro Basin. These large chloride concentrations may indicate upward movement of water from deeper in the basin in these areas. The water with the large chloride concentration in the southern part of the basin also may be caused by leakage of geothermal waters along the Capitan Lineament. In the central part of the Socorro Basin, infiltration of excess irrigation water and inflow of groundwater from the basin margins control water quality. In this area, specific conductance generally is less than 1,000 microsiemens per centimeter. Water in La Jencia Basin generally is of the calcium sodium bicarbonate type with specific conductance less than

  19. Long-term diffusion of U(VI) in bentonite: Dependence on density.

    Science.gov (United States)

    Joseph, Claudia; Mibus, Jens; Trepte, Paul; Müller, Christa; Brendler, Vinzenz; Park, Dan M; Jiao, Yongqin; Kersting, Annie B; Zavarin, Mavrik

    2017-01-01

    As a contribution to the safety assessment of nuclear waste repositories, U(VI) diffusion through the potential buffer material MX-80 bentonite was investigated at three clay dry densities over six years. Synthetic MX-80 model pore water was used as background electrolyte. Speciation calculations showed that Ca2UO2(CO3)3(aq) was the main U(VI) species. The in- and out-diffusion of U(VI) was investigated separately. U(VI) diffused about 3mm, 1.5mm, and 1mm into the clay plug at ρ=1.3, 1.6, and 1.9g/cm(3), respectively. No through-diffusion of the U(VI) tracer was observed. However, leaching of natural uranium contained in the clay occurred and uranium was detected in all receiving reservoirs. As expected, the effective and apparent diffusion coefficients, De and Da, decreased with increasing dry density. The Da values for the out-diffusion of natural U(VI) were in good agreement with previously determined values. Surprisingly, Da values for the in-diffusion of U(VI) were about two orders of magnitude lower than values obtained in short-term in-diffusion experiments reported in the literature. Some potential reasons for this behavior that were evaluated are changes of the U(VI) speciation within the clay (precipitation, reduction) or changes of the clay porosity and pore connectivity with time. By applying Archie's law and the extended Archie's law, it was estimated that a significantly smaller effective porosity must be present for the long-term in-diffusion of U(VI). The results suggest that long-term studies of key transport phenomena may reveal additional processes that can directly impact long-term repository safety assessments.

  20. Mechanical investigation of U(VI) on pyrrhotite by batch, EXAFS and modeling techniques.

    Science.gov (United States)

    Liu, Haibo; Zhu, Yuke; Xu, Bin; Li, Ping; Sun, Yubing; Chen, Tianhu

    2017-01-15

    The interaction mechanism of U(VI) on pyrrhotite was demonstrated by batch, spectroscopic and modeling techniques. Pyrite was selected as control group in this study. The removal of U(VI) on pyrite and pyrrhotite significantly decreased with increasing ionic strength from 0.001 to 0.1mol/L at pH 2.0-6.0, whereas the no effect of ionic strength was observed at pH >6.0. The maximum removal capacity of U(VI) on pyrite and pyrrhotite calculated from Langmuir model was 10.20 and 21.34mgg(-1) at pH 4.0 and 333K, respectively. The XPS analysis indicated the U(VI) was primarily adsorbed on pyrrhotite and pyrite and then approximately 15.5 and 9.8% of U(VI) were reduced to U(IV) by pyrrhotite and pyrite after 20 days, respectively. Based on the XANES analysis, the adsorption edge of uranium-containing pyrrhotite located between U(IV)O2(s) and U(VI)O2(2+) spectra. The EXAFS analysis demonstrated the inner-sphere surface complexation of U(VI) on pyrrhotite due to the occurrence of U-S shell, whereas the U-U shell revealed the reductive co-precipitates of U(VI) on pyrrhotite/pyrite with increasing reaction times. The surface complexation modeling showed that outer- and inner-surface complexation dominated the U(VI) removal at pH5.0, respectively. The findings presented herein play a crucial role in the removal of radionuclides on iron sulfide in environmental cleanup applications.

  1. The role of intracellular zinc in chromium(VI)-induced oxidative stress, DNA damage and apoptosis.

    Science.gov (United States)

    Rudolf, Emil; Cervinka, Miroslav

    2006-09-25

    Several studies have demonstrated that zinc is required for the optimal functioning of the skin. Changes in intracellular zinc concentrations have been associated with both improved protection of skin cells against various noxious factors as well as with increased susceptibility to external stress. Still, little is known about the role of intracellular zinc in hexavalent chromium (Cr(VI))-induced skin injury. To address this question, the effects of zinc deficiency or supplementation on Cr(VI)-induced cytotoxicity, oxidative stress, DNA injury and cell death were investigated in human diploid dermal fibroblasts during 48 h. Zinc levels in fibroblasts were manipulated by pretreatment of cells with 100 microM ZnSO4 and 4 or 25 microM zinc chelator TPEN. Cr(VI) (50, 10 and 1 microM) was found to produce time- and dose-dependent cytotoxicity resulting in oxidative stress, suppression of antioxidant systems and activation of p53-dependent apoptosis which is reported for the first time in this model in relation to environmental Cr(VI). Increased intracellular zinc partially attenuated Cr(VI)-induced cytotoxicity, oxidative stress and apoptosis by enhancing cellular antioxidant systems while inhibiting Cr(VI)-dependent apoptosis by preventing the activation of caspase-3. Decreased intracellular zinc enhanced cytotoxic effects of all the tested Cr(VI) concentrations, leading to rapid loss of cell membrane integrity and nuclear dispersion--hallmarks of necrosis. These new findings suggest that Cr(VI) as a model environmental toxin may damage in deeper regions residing skin fibroblasts whose susceptibility to such toxin depends among others on their intracellular Zn levels. Further investigation of the impact of Zn status on skin cells as well as any other cell populations exposed to Cr(VI) or other heavy metals is warranted.

  2. Unique lipid anchor attaches Vi antigen capsule to the surface of Salmonella enterica serovar Typhi.

    Science.gov (United States)

    Liston, Sean D; Ovchinnikova, Olga G; Whitfield, Chris

    2016-06-14

    Polysaccharide capsules are surface structures that are critical for the virulence of many Gram-negative pathogenic bacteria. Salmonella enterica serovar Typhi is the etiological agent of typhoid fever. It produces a capsular polysaccharide known as "Vi antigen," which is composed of nonstoichiometrically O-acetylated α-1,4-linked N-acetylgalactosaminuronic acid residues. This glycan is a component of currently available vaccines. The genetic locus for Vi antigen production is also present in soil bacteria belonging to the genus Achromobacter Vi antigen assembly follows a widespread general strategy with a characteristic glycan export step involving an ATP-binding cassette transporter. However, Vi antigen producers lack the enzymes that build the conserved terminal glycolipid characterizing other capsules using this method. Achromobacter species possess a Vi antigen-specific depolymerase enzyme missing in S enterica Typhi, and we exploited this enzyme to isolate acylated Vi antigen termini. Mass spectrometry analysis revealed a reducing terminal N-acetylhexosamine residue modified with two β-hydroxyl acyl chains. This terminal structure resembles one half of lipid A, the hydrophobic portion of bacterial lipopolysaccharides. The VexE protein encoded in the Vi antigen biosynthesis locus shares similarity with LpxL, an acyltransferase from lipid A biosynthesis. In the absence of VexE, Vi antigen is produced, but its physical properties are altered, its export is impaired, and a Vi capsule structure is not assembled on the cell surface. The structure of the lipidated terminus dictates a unique assembly mechanism and has potential implications in pathogenesis and vaccine production.

  3. Assessment of Cr(VI-induced cytotoxicity and genotoxicity using high content analysis.

    Directory of Open Access Journals (Sweden)

    Chad M Thompson

    Full Text Available Oral exposure to high concentrations of hexavalent chromium [Cr(VI] induces intestinal redox changes, villus cytotoxicity, crypt hyperplasia, and intestinal tumors in mice. To assess the effects of Cr(VI in a cell model relevant to the intestine, undifferentiated (proliferating and differentiated (confluent Caco-2 cells were treated with Cr(VI, hydrogen peroxide or rotenone for 2-24 hours. DNA damage was then assessed by nuclear staining intensity of 8-hydroxydeoxyguanosine (8-OHdG and phosphorylated histone variant H2AX (γ-H2AX measured by high content analysis methods. In undifferentiated Caco-2, all three chemicals increased 8-OHdG and γ-H2AX staining at cytotoxic concentrations, whereas only 8-OHdG was elevated at non-cytotoxic concentrations at 24 hr. Differentiated Caco-2 were more resistant to cytotoxicity and DNA damage than undifferentiated cells, and there were no changes in apoptotic markers p53 or annexin-V. However, Cr(VI induced a dose-dependent translocation of the unfolded protein response transcription factor ATF6 into the nucleus. Micronucleus (MN formation was assessed in CHO-K1 and A549 cell lines. Cr(VI increased MN frequency in CHO-K1 only at highly cytotoxic concentrations. Relative to the positive control Mitomycin-C, Cr(VI only slightly increased MN frequency in A549 at mildly cytotoxic concentrations. The results demonstrate that Cr(VI genotoxicity correlates with cytotoxic concentrations, and that H2AX phosphorylation occurs at higher concentrations than oxidative DNA damage in proliferating Caco-2 cells. The findings suggest that in vitro genotoxicity of Cr(VI is primarily oxidative in nature at low concentrations. Implications for in vivo intestinal toxicity of Cr(VI will be discussed.

  4. Assessment of Cr(VI)-Induced Cytotoxicity and Genotoxicity Using High Content Analysis

    Science.gov (United States)

    Thompson, Chad M.; Fedorov, Yuriy; Brown, Daniel D.; Suh, Mina; Proctor, Deborah M.; Kuriakose, Liz; Haws, Laurie C.; Harris, Mark A.

    2012-01-01

    Oral exposure to high concentrations of hexavalent chromium [Cr(VI)] induces intestinal redox changes, villus cytotoxicity, crypt hyperplasia, and intestinal tumors in mice. To assess the effects of Cr(VI) in a cell model relevant to the intestine, undifferentiated (proliferating) and differentiated (confluent) Caco-2 cells were treated with Cr(VI), hydrogen peroxide or rotenone for 2–24 hours. DNA damage was then assessed by nuclear staining intensity of 8-hydroxydeoxyguanosine (8-OHdG) and phosphorylated histone variant H2AX (γ-H2AX) measured by high content analysis methods. In undifferentiated Caco-2, all three chemicals increased 8-OHdG and γ-H2AX staining at cytotoxic concentrations, whereas only 8-OHdG was elevated at non-cytotoxic concentrations at 24 hr. Differentiated Caco-2 were more resistant to cytotoxicity and DNA damage than undifferentiated cells, and there were no changes in apoptotic markers p53 or annexin-V. However, Cr(VI) induced a dose-dependent translocation of the unfolded protein response transcription factor ATF6 into the nucleus. Micronucleus (MN) formation was assessed in CHO-K1 and A549 cell lines. Cr(VI) increased MN frequency in CHO-K1 only at highly cytotoxic concentrations. Relative to the positive control Mitomycin-C, Cr(VI) only slightly increased MN frequency in A549 at mildly cytotoxic concentrations. The results demonstrate that Cr(VI) genotoxicity correlates with cytotoxic concentrations, and that H2AX phosphorylation occurs at higher concentrations than oxidative DNA damage in proliferating Caco-2 cells. The findings suggest that in vitro genotoxicity of Cr(VI) is primarily oxidative in nature at low concentrations. Implications for in vivo intestinal toxicity of Cr(VI) will be discussed. PMID:22905163

  5. Ex-situ bioremediation of U(VI from contaminated mine water using Acidithiobacillus ferrooxidans strains

    Directory of Open Access Journals (Sweden)

    Maria eRomero-Gonzalez

    2016-05-01

    Full Text Available The ex-situ bioremoval of U(VI from contaminated water using Acidithiobacillus ferrooxidans strain 8455 and 13538 was studied under a range of pH and uranium concentrations. The effect of pH on the growth of bacteria was evaluated across the range 1.5 – 4.5 pH units. The respiration rate of At. ferrooxidans at different U(VI concentrations was quantified as a measure of the rate of metabolic activity over time using an oxygen electrode. The biosorption process was quantified using a uranyl nitrate solution, U-spiked growth media and U-contaminated mine water. The results showed that both strains of At. ferrooxidans are able to remove U(VI from solution at pH 2.5 – 4.5, exhibiting a buffering capacity at pH 3.5. The respiration rate of the micro-organism was affected at U(VI concentration of 30 mg L-1. The kinetics of the sorption fitted a pseudo-first order equation, and depended on the concentration of U(VI. The KD obtained from the biosorption experiments indicated that strain 8455 is more efficient for the removal of U(VI. A bioreactor designed to treat a solution of 100 mg U(VI L-1 removed at least 50% of the U(VI in water. The study demonstrated that At. ferrooxidans can be used for the ex-situ bioremediation of U(VI contaminated mine water.

  6. Geologic Basin Boundaries (Basins_GHGRP) GIS Layer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This is a coverage shapefile of geologic basin boundaries which are used by EPA's Greenhouse Gas Reporting Program. For onshore production, the "facility" includes...

  7. The Amazon basin in transition.

    Science.gov (United States)

    Davidson, Eric A; de Araújo, Alessandro C; Artaxo, Paulo; Balch, Jennifer K; Brown, I Foster; C Bustamante, Mercedes M; Coe, Michael T; DeFries, Ruth S; Keller, Michael; Longo, Marcos; Munger, J William; Schroeder, Wilfrid; Soares-Filho, Britaldo S; Souza, Carlos M; Wofsy, Steven C

    2012-01-18

    Agricultural expansion and climate variability have become important agents of disturbance in the Amazon basin. Recent studies have demonstrated considerable resilience of Amazonian forests to moderate annual drought, but they also show that interactions between deforestation, fire and drought potentially lead to losses of carbon storage and changes in regional precipitation patterns and river discharge. Although the basin-wide impacts of land use and drought may not yet surpass the magnitude of natural variability of hydrologic and biogeochemical cycles, there are some signs of a transition to a disturbance-dominated regime. These signs include changing energy and water cycles in the southern and eastern portions of the Amazon basin.

  8. Correcting basin-scale snowfall in a mountainous basin using a distributed snowmelt model and remote sensing data

    Directory of Open Access Journals (Sweden)

    M. Shrestha

    2013-09-01

    Full Text Available Adequate estimation of the spatial distribution of snowfall is critical in hydrologic modeling. However, this is a well-known problem in estimating basin-scale snowfall, especially in mountainous basins with data scarcity. This study focuses on correction and estimation of this spatial distribution, which considers topographic effects within the basin. A method is proposed that optimizes an altitude-based snowfall correction factor (Cfsnow. This is done through multi-objective calibration of a spatially distributed, multilayer energy and water balance-based snowmelt model (WEB-DHM-S with observed discharge and remotely sensed snow cover data from the Moderate Resolution Imaging Spectroradiometer (MODIS. The Shuffled Complex Evolution – University of Arizona automatic search algorithm is used to obtain the optimal value of Cfsnow for minimum cumulative error in discharge and snow cover simulations. Discharge error is quantified by Nash–Sutcliffe efficiency and relative volume deviation, and snow cover error was estimated by pixel-by-pixel analysis. The study region is the heavily snow-fed Yagisawa Basin of the Upper Tone River in northeast Japan. First, the system was applied to one snow season (2002–2003, obtaining an optimized Cfsnow of 0.0007 m−1. For validation purposes, the optimized Cfsnow was implemented to correct snowfall in 2004, 2002 and 2001. Overall, the system was effective, implying improvements in correlation of simulated vs. observed discharge and snow cover. The 4 yr mean of basin-average snowfall for the corrected spatial snowfall distribution was 1160 mm (780 mm before correction. Execution of sensitivity runs against other model input and parameters indicated that Cfsnow could be affected by uncertainty in shortwave radiation and setting of the threshold air temperature parameter. Our approach is suitable to correct snowfall and estimate its distribution in poorly-gauged basins, where elevation dependence of snowfall

  9. Correcting basin-scale snowfall in a mountainous basin using a distributed snowmelt model and remote-sensing data

    Science.gov (United States)

    Shrestha, M.; Wang, L.; Koike, T.; Tsutsui, H.; Xue, Y.; Hirabayashi, Y.

    2014-02-01

    Adequate estimation of the spatial distribution of snowfall is critical in hydrologic modelling. However, this is a well-known problem in estimating basin-scale snowfall, especially in mountainous basins with data scarcity. This study focuses on correction and estimation of this spatial distribution, which considers topographic effects within the basin. A method is proposed that optimises an altitude-based snowfall correction factor (Cfsnow). This is done through multi-objective calibration of a spatially distributed, multilayer energy and water balance-based snowmelt model (WEB-DHM-S) with observed discharge and remotely sensed snow cover data from the Moderate Resolution Imaging Spectroradiometer (MODIS). The Shuffled Complex Evolution-University of Arizona (SCE-UA) automatic search algorithm is used to obtain the optimal value of Cfsnow for minimum cumulative error in discharge and snow cover simulations. Discharge error is quantified by Nash-Sutcliffe efficiency and relative volume deviation, and snow cover error was estimated by pixel-by-pixel analysis. The study region is the heavily snow-fed Yagisawa Basin of the Upper Tone River in northeast Japan. First, the system was applied to one snow season (2002-2003), obtaining an optimised Cfsnow of 0.0007 m-1. For validation purposes, the optimised Cfsnow was implemented to correct snowfall in 2004, 2002 and 2001. Overall, the system was effective, implying improvements in correlation of simulated versus observed discharge and snow cover. The 4 yr mean of basin-average snowfall for the corrected spatial snowfall distribution was 1160 mm (780 mm before correction). Execution of sensitivity runs against other model input and parameters indicated that Cfsnow could be affected by uncertainty in shortwave radiation and setting of the threshold air temperature parameter. Our approach is suitable to correct snowfall and estimate its distribution in poorly gauged basins, where elevation dependence of snowfall amount is

  10. Correcting basin-scale snowfall in a mountainous basin using a distributed snowmelt model and remote sensing data

    Science.gov (United States)

    Shrestha, M.; Wang, L.; Koike, T.; Tsutsui, H.; Xue, Y.; Hirabayashi, Y.

    2013-09-01

    Adequate estimation of the spatial distribution of snowfall is critical in hydrologic modeling. However, this is a well-known problem in estimating basin-scale snowfall, especially in mountainous basins with data scarcity. This study focuses on correction and estimation of this spatial distribution, which considers topographic effects within the basin. A method is proposed that optimizes an altitude-based snowfall correction factor (Cfsnow). This is done through multi-objective calibration of a spatially distributed, multilayer energy and water balance-based snowmelt model (WEB-DHM-S) with observed discharge and remotely sensed snow cover data from the Moderate Resolution Imaging Spectroradiometer (MODIS). The Shuffled Complex Evolution - University of Arizona automatic search algorithm is used to obtain the optimal value of Cfsnow for minimum cumulative error in discharge and snow cover simulations. Discharge error is quantified by Nash-Sutcliffe efficiency and relative volume deviation, and snow cover error was estimated by pixel-by-pixel analysis. The study region is the heavily snow-fed Yagisawa Basin of the Upper Tone River in northeast Japan. First, the system was applied to one snow season (2002-2003), obtaining an optimized Cfsnow of 0.0007 m-1. For validation purposes, the optimized Cfsnow was implemented to correct snowfall in 2004, 2002 and 2001. Overall, the system was effective, implying improvements in correlation of simulated vs. observed discharge and snow cover. The 4 yr mean of basin-average snowfall for the corrected spatial snowfall distribution was 1160 mm (780 mm before correction). Execution of sensitivity runs against other model input and parameters indicated that Cfsnow could be affected by uncertainty in shortwave radiation and setting of the threshold air temperature parameter. Our approach is suitable to correct snowfall and estimate its distribution in poorly-gauged basins, where elevation dependence of snowfall amount is strong.

  11. Characterization of U(VI) reduction in contaminated sediments with slow-degrading electron donor source

    Science.gov (United States)

    Wu, W.; Watson, D. B.; Zhang, G.; Mehlhorn, T.; Lowe, K.; Earles, J.; Phillips, J.; Kelly, S. D.; Boyanov, M.; Kemner, K. M.; Schadt, C.; Criddle, C. S.; Jardine, P. M.; Brooks, S. C.

    2011-12-01

    In order to select sustainable, high efficiency and cost effective electron donor source, oleate and emulsified vegetable oil (EVO) were tested uranium (VI) reduction in comparison with ethanol in microcosms using uranium contaminated sediments and groundwater from the US DOE Oak Ridge Integrated Field Research Challenge (ORIFRC) site. The effect of initial sulfate concentration on U(VI) reduction was also tested. Both oleate and EVO were effective electron donor sources for U(VI) reduction. Accumulation of acetate as a major product and the removal of aqueous U(VI) were observed and were associated with sulfate reduction. Both oleate and EVO supported U(VI) reduction but at slower rates with a comparable but slightly lower extent of reduction than ethanol. X-ray absorption near-edge spectroscopy (XANES) analysis confirmed reduction of U(VI) to U(IV). The extent of U(VI) reduction in solid phase was negatively influenced by aqueous calcium concentration. The majority of electrons of the three substrates were consumed by sulfate reduction, Fe(III) reduction, and methanogenesis. Initial U(VI) concentration in the aqueous phase increased with increased sulfate concentration (1 versus 5 mM), likely due to U(VI) desorption from the solid phase. At the higher initial sulfate concentration more U(VI) was reduced and fewer electrons were used in methanogenesis. Analysis of bacterial and archeal populations using 16S rRNA gene libraries showed a significant increase in Deltaproteobacteria after biostimulation. The microbial community structures developed with oleate and EVO were significantly distinct from those developed with ethanol. Bacteria similar to Desulforegula spp. was predominant for oleate and EVO degradation but were not observed in ethanol-amended microcosms. Known U(VI)-reducing bacteria in the microcosms amended with the three electron donor sources included iron(III) reducing Geobacter spp. but in lower abundances than sulfate-reducing Desulfovibrio spp. The

  12. Status report on the National Research Council`s BEIR VI study

    Energy Technology Data Exchange (ETDEWEB)

    Douple, E.

    1995-10-01

    The objectives of the committee on Biological Radiation Effects of Ionizing Radiation VI (BEIR) are to : assist the EPA in phase I by collecting and evaluating information on ongoing studies and results of studies published since the BEIR VI report of 1988 on the health effects of exposure to radon progeny; to perform a full scale reassessment of the health effects if a phase II study is warranted on the basis of phase I results. The BEIR VI working groups consists of miner data sets and analysis; residential studies; smoking and nonsmoking interactions; exposure and dosimetry; cellular and molecular studies; risk models and uncertainties; and animal studies.

  13. Sorption of chromium (VI) by Mg/Fe hydrotalcite type compunds

    Science.gov (United States)

    García-Sosa, I.; Cabral-Prieto, A.; Nava, N.; Navarrete, J.; Olguín, M. T.; Escobar, Luis; López-Castañares, R.; Olea-Cardoso, O.

    2015-06-01

    The synthesis by co-precipitation and characterization by X-ray diffraction, Raman and Mössbauer spectroscopies of Mg-Fe-hydrotalcite compounds, and their sorption capacities for Cr(VI) in aqueous media were carried out. The average sorption capacity of Cr(VI) for the non-thermal treated samples was of 6.2 mg/g. The ferrihydrite was omnipresent in all prepared hydrotalcite samples. A brief discussion is made on the role of both the hydrotalcite and ferrihydrite for removing such amount of Cr(VI).

  14. Sorption of chromium (VI) by Mg/Fe hydrotalcite type compunds

    Energy Technology Data Exchange (ETDEWEB)

    García-Sosa, I., E-mail: irma.garcia@inin.gob.mx; Cabral-Prieto, A., E-mail: agustin.cabral@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Nava, N., E-mail: tnava@imp.mx; Navarrete, J. [Instituto Mexicano del Petróleo (Mexico); Olguín, M. T., E-mail: teresa.olguin@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Escobar, Luis, E-mail: luis.escobar@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Física (Mexico); López-Castañares, R., E-mail: rlc@anuies.mx; Olea-Cardoso, O., E-mail: olc@anuies.mx [Universidad Autónoma del Edo. de México, Facultad de Química (Mexico)

    2015-06-15

    The synthesis by co-precipitation and characterization by X-ray diffraction, Raman and Mössbauer spectroscopies of Mg-Fe-hydrotalcite compounds, and their sorption capacities for Cr(VI) in aqueous media were carried out. The average sorption capacity of Cr(VI) for the non-thermal treated samples was of 6.2 mg/g. The ferrihydrite was omnipresent in all prepared hydrotalcite samples. A brief discussion is made on the role of both the hydrotalcite and ferrihydrite for removing such amount of Cr(VI)

  15. Multi-crystalline II-VI based multijunction solar cells and modules

    Energy Technology Data Exchange (ETDEWEB)

    Hardin, Brian E.; Connor, Stephen T.; Groves, James R.; Peters, Craig H.

    2015-06-30

    Multi-crystalline group II-VI solar cells and methods for fabrication of same are disclosed herein. A multi-crystalline group II-VI solar cell includes a first photovoltaic sub-cell comprising silicon, a tunnel junction, and a multi-crystalline second photovoltaic sub-cell. A plurality of the multi-crystalline group II-VI solar cells can be interconnected to form low cost, high throughput flat panel, low light concentration, and/or medium light concentration photovoltaic modules or devices.

  16. Proposed adsorption-diffusion model for characterizing chromium(VI) removal using dried water hyacinth roots

    Energy Technology Data Exchange (ETDEWEB)

    Sarkar, Debasish; Mukherjee, Paramartha; Bandyopadhyay, Amitava [Department of Chemical Engineering, University of Calcutta, Kolkata (India); Das, Sudip Kumar [Department of Chemical Technology, University of Calcutta, Kolkata (India)

    2010-08-15

    Experiments have been carried out to characterize the adsorption of chromium(VI) in the aqueous phase onto dried roots of water hyacinth. Results revealed a very high degree of removal efficiency ({proportional_to}100%). Theoretical analyzes are also made for describing the sorption and diffusion processes. The effective pore diffusivity of chromium(VI) in the water hyacinth roots is determined by a suitable global optimization technique. The depth of penetration, on the other hand, has been estimated for various initial concentrations of chromium(VI). Theoretically predicted concentration profiles are in excellent agreement with the experimental values. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  17. vi and Vim Editors Pocket Reference Support for every text editing task

    CERN Document Server

    Robbins, Arnold

    2011-01-01

    Many Unix, Linux, and Mac OS X geeks enjoy using the powerful, platform-agnostic text editors vi and Vim, but there are far too many commands for anyone to remember. Author Arnold Robbins has chosen the most valuable commands for vi, Vim, and vi's main clones-vile, elvis, and nvi-and packed them into this easy-to-browse pocket reference. You'll find commands for all kinds of editing tasks, such as programming, modifying system files, and writing and marking up articles. This second edition includes: Command-line optionsvi commands and set optionsInput mode shortcutsSubstitution and regular e

  18. Thermoelectric properties of IV–VI-based heterostructures and superlattices

    Energy Technology Data Exchange (ETDEWEB)

    Borges, P.D., E-mail: pabloborges@ufv.br [Instituto de Ciências Exatas e Tec., Universidade Federal de Viçosa, Rio Paranaíba, MG (Brazil); Department of Physics, Texas State University, San Marcos, TX 78666 (United States); Petersen, J.E.; Scolfaro, L. [Department of Physics, Texas State University, San Marcos, TX 78666 (United States); Leite Alves, H.W. [Departamento de Ciências Naturais, Universidade Federal de São João Del Rei, Caixa Postal 110, São João Del Rei 36300-000, MG (Brazil); Myers, T.H. [Department of Physics, Texas State University, San Marcos, TX 78666 (United States)

    2015-07-15

    Doping in a manner that introduces anisotropy in order to reduce thermal conductivity is a significant focus in thermoelectric research today. By solving the semiclassical Boltzmann transport equations in the constant scattering time (τ) approximation, in conjunction with ab initio electronic structure calculations, within Density Functional Theory, we compare the Seebeck coefficient (S) and figure of merit (ZT) of bulk PbTe to PbTe/SnTe/PbTe heterostructures and PbTe doping superlattices (SLs) with periodically doped planes. Bismuth and Thallium were used as the n- and p-type impurities, respectively. The effects of carrier concentration are considered via chemical potential variation in a rigid band approximation. The impurity bands near the Fermi level in the electronic structure of PbTe SLs are of Tl s- and Bi p-character, and this feature is independent of the doping concentration or the distance between impurity planes. We observe the impurity bands to have a metallic nature in the directions perpendicular to the doping planes, yet no improvement on the values of ZT is found when compared to bulk PbTe. For the PbTe/SnTe/PbTe heterostructures, the calculated S presents good agreement with recent experimental data, and an anisotropic behavior is observed for low carrier concentrations (n<10{sup 18} cm{sup −3}). A large value of ZT{sub ||} (parallel to the growth direction) of 3.0 is predicted for n=4.7×10{sup 18} cm{sup −3} and T=700 K, whereas ZT{sub p} (perpendicular to the growth direction) is found to peak at 1.5 for n=1.7×10{sup 17} cm{sup −3}. Both electrical conductivity enhancement and thermal conductivity reduction are analyzed. - Graphical abstract: Figure of merit for PbTe/SnTe/PbTe heterostructure along the [0 0 1] direction, P.D. Borges, J.E. Petersen, L. Scolfaro, H.W. Leite Alves, T.H. Myers, Improved thermoelectric properties of IV–VI-based heterostructures and superlattices. - Highlights: • Thermoelectric properties of IV–VI

  19. Ovarian volume throughout life

    DEFF Research Database (Denmark)

    Kelsey, Thomas W; Dodwell, Sarah K; Wilkinson, A Graham

    2013-01-01

    cancer. To date there is no normative model of ovarian volume throughout life. By searching the published literature for ovarian volume in healthy females, and using our own data from multiple sources (combined n=59,994) we have generated and robustly validated the first model of ovarian volume from...... to about 2.8 mL (95% CI 2.7-2.9 mL) at the menopause and smaller volumes thereafter. Our model allows us to generate normal values and ranges for ovarian volume throughout life. This is the first validated normative model of ovarian volume from conception to old age; it will be of use in the diagnosis...

  20. Vi capsular polysaccharide-protein conjugates for prevention of typhoid fever. Preparation, characterization, and immunogenicity in laboratory animals.

    Science.gov (United States)

    Szu, S C; Stone, A L; Robbins, J D; Schneerson, R; Robbins, J B

    1987-11-01

    The Vi has proven to be a protective antigen in two double masked, controlled clinical trials in areas with high rates of typhoid fever (approximately 1% per annum). In both studies the protective efficacy of the Vi was approximately 70%. Approximately 75% of subjects in these areas responded with a fourfold or greater rise of serum Vi antibodies. In contrast, the Vi elicited a fourfold or greater rise in 95-100% of young adults in France and the United States. Methods were devised, therefore, to synthesize Vi-protein conjugates in order to both enhance the antibody response and confer T-dependent properties to the Vi (and theoretically increase its protective action in populations at high risk for typhoid fever). We settled on a method that used the heterobifunctional crosslinking reagent, N-succinimidyl-3-(2-pyridyldithio)-propionate (SPDP), to bind thiol derivatives of the Vi to proteins. This synthetic scheme was reproducible, provided high yields of Vi-protein conjugates, and was applicable to several medically relevant proteins such as diphtheria and tetanus toxoids. The resultant conjugates were more immunogenic in mice and juvenile Rhesus monkeys than the Vi alone. In contrast to the T-independent properties of the Vi, conjugates of this polysaccharide with several medically relevant proteins induced booster responses in mice and in juvenile Rhesus monkeys. Clinical studies with Vi-protein conjugates are planned. This scheme is also applicable to synthesize protein conjugates with other polysaccharides that have carboxyl functions.

  1. Remediation of Cr(VI) contaminated soil using long-duration sodium thiosulfate supported by micro–nano networks

    Energy Technology Data Exchange (ETDEWEB)

    He, Lulu [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China); Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Wang, Min; Zhang, Guilong [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Qiu, Guannan [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Cai, Dongqing, E-mail: dqcai@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Wu, Zhengyan, E-mail: zywu@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Zhang, Xin, E-mail: xinzhang@ahau.edu.cn [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China)

    2015-08-30

    Highlights: • This work aims to develop a long-duration remediation agent (LRA). • LRA was obtained using Na{sub 2}S{sub 2}O{sub 3} supported by attapulgite (ATP) micro–nano networks. • ATP micro–nano networks was induced by high-energy electron beam irradiation. • LRA can effectively control the migration of Cr(VI) and reducing Cr(VI) to Cr(III). • LRA displayed high performance on the remediation of heavy metal contaminated soil. - Abstract: In this work, a long-duration remediation agent (LRA) on hexavalent chromium (Cr(VI)) was developed using sodium thiosulfate (ST) supported by attapulgite (ATP) micro–nano networks induced through high-energy electron beam (HEEB) irradiation. The ATP networks could effectively reduce the leaching amount of Cr(VI) in soil. More importantly, the ATP networks could significantly control the leaching behavior of ST, and then prolong the duration and increase the reduction efficiency of ST on Cr(VI). As a result, LRA displayed high performance on controlling the migration of Cr(VI) and reducing Cr(VI) to Cr(III). Additionally, pot experiment indicated that LRA could effectively decrease the absorbed amount of Cr(VI) in corn, and reduce the inhibition effect of Cr(VI) on the growth of corn. Therefore, this work could provide a facile approach to remediate the Cr(VI)-contaminated soil and lower the harmful effect of Cr(VI) on crop.

  2. Trip report Rainwater Basin Nebraska

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This report is a summary a trip to Rainwater Basin Wetland Management District in 1991, and focuses on the hydrology and soil habitat types. It is part of the...

  3. Allegheny County Basin Outlines Map

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — This basins dataset was created to initiate regional watershed approaches with respect to sewer rehabilitation. If viewing this description on the Western...

  4. Impact of Climate Change on Hydrologic Extremes in the Upper Basin of the Yellow River Basin of China

    Directory of Open Access Journals (Sweden)

    Jun Wang

    2016-01-01

    Full Text Available To reveal the revolution law of hydrologic extremes in the next 50 years and analyze the impact of climate change on hydrologic extremes, the following main works were carried on: firstly, the long duration (15 d, 30 d, and 60 d rainfall extremes according to observed time-series and forecast time-series by dynamical climate model product (BCC-CSM-1.1 were deduced, respectively, on the basis that the quantitative estimation of the impact of climate change on rainfall extremes was conducted; secondly, the SWAT model was used to deduce design flood with the input of design rainfall for the next 50 years. On this basis, quantitative estimation of the impact of climate change on long duration flood volume extremes was conducted. It indicates that (1 the value of long duration rainfall extremes for given probabilities (1%, 2%, 5%, and 10% of the Tangnaihai basin will rise with slight increasing rate from 1% to 6% in the next 50 years and (2 long duration flood volume extremes of given probabilities of the Tangnaihai basin will rise with slight increasing rate from 1% to 6% in the next 50 years. The conclusions may provide technical supports for basin level planning of flood control and hydropower production.

  5. DERİ SANAYİ ATIK SULARINDAN KROM (VI) İYONUNUN ADSORBSİYONU - REMOVAL OF CHROMIUM (VI) ION FROM LEATHER WASTEWATERS BY ADSORPTION

    OpenAIRE

    Canlı, Murat; Abalı, Yüksel; Öztekin, Banu; Şirin, Kamil

    2015-01-01

    DERİ SANAYİ ATIK SULARINDAN KROM (VI) İYONUNUN ADSORBSİYONUSon yıllarda atık suların arıtılmasında alternatif arıtım yöntemleri geliştirilmektedir. Atık sulardaki ağır metalleri gidermek için kullanılan yöntemlerden birisi de ağır metallerin adsorpsiyonudur. Bir ağır metal olan Cr(VI), su kirliliğine ve canlı bünyesinde toksik etkiye neden olur. Bu çalışmada klinoptilolit, asit ile aktive edilmiş klinoptilolit gibi doğal adsorbanlar kullanılarak Cr(VI) iyonunun adsorpsiyonu ve deri atık suyun...

  6. Mellya-Tamak VI Settlement of Chiyalik Culture

    Directory of Open Access Journals (Sweden)

    Kazakov Evgenii P.

    2016-06-01

    Full Text Available The authors publish the fi ndings of the digs on Mellya-Tamak VI temporary settlement belonging to the Chiyalik archaeological culture – one of the most comprehensively studied settlements in this complex of sites. Besides proper Chiyalik materials, some artefacts of Mesolithic-Neolithic, Early Iron Age (Pyany Bor culture and Early Middle Ages (Kushnarenkovo culture have been identifi ed here. The Chiyalik stage is represented by debris of a summer camp, with its surface structures, hearths, stones from wall cladding and household pits. The life time of the Chiyalik settlement on the Mellya-Tamak dune can be dated within the thirteenth-fourteenth centuries, as suggested by the authors based on some fi nds of glass beads with overlaid linear-undulate paste threads and the ceramic complex. As a result of years of research, the authors conclude that the Chiyalik sites were left by the Uralic Ugrians, who were part of the Golden Horde population and were undergoing the process of Islamization and Turkization.

  7. II-VI wide band gap semiconductors under hydrostatic pressure

    Science.gov (United States)

    Baquero, R.; Decoss, R.; Olguin, D.

    1993-08-01

    We set an analytical expression for the gap as a function of hydrostatic deformation, E(sub g)(epsilon), by diagonalizing in Gamma the corresponding empirical tight-binding Hamiltonian (ETBH). In the ETBH we use the well known d(exp -2) Harrison scaling law (HSL) to adjust the TB parameter (TBP) to the changes in interatomic distances. We do not consider cation-anion charge transfer. We calculate E(sub g)(epsilon) for wide band gap II-VI semiconductors with zincblende crystal structure for deformations under pressure up to -5 percent. Results are in good agreement with experiment for the compounds of lower ionicity but deviate as the ionicity of the compound increases. This is due to the neglect of charge transfer which should be included self-consistently. Within the approximation we always find a positive second derivative of E(sub g)(epsilon) with respect to epsilon, independent of the material. Furthermore, the inclusion of deviations from HSL appear to be unimportant to this problem.

  8. Speedup and fracturing of George VI Ice Shelf, Antarctic Peninsula

    Directory of Open Access Journals (Sweden)

    T. O. Holt

    2013-05-01

    Full Text Available George VI Ice Shelf (GVIIS is located on the Antarctic Peninsula, a region where several ice shelves have undergone rapid breakup in response to atmospheric and oceanic warming. We use a combination of optical (Landsat, radar (ERS 1/2 SAR and laser altimetry (GLAS datasets to examine the response of GVIIS to environmental change and to offer an assessment on its future stability. The spatial and structural changes of GVIIS (ca. 1973 to ca. 2010 are mapped and surface velocities are calculated at different time periods (InSAR and optical feature tracking from 1989 to 2009 to document changes in the ice shelf's flow regime. Surface elevation changes are recorded between 2003 and 2008 using repeat track ICESat acquisitions. We note an increase in fracture extent and distribution at the south ice front, ice-shelf acceleration towards both the north and south ice fronts and spatially varied negative surface elevation change throughout, with greater variations observed towards the central and southern regions of the ice shelf. We propose that whilst GVIIS is in no imminent danger of collapse, it is vulnerable to ongoing atmospheric and oceanic warming and is more susceptible to breakup along its southern margin in ice preconditioned for further retreat.

  9. Mucopolysaccharidosis VI in a Siamese/short-haired European cat.

    Science.gov (United States)

    Macrì, B; Marino, F; Mazzullo, G; Trusso, A; De Maria, R; Amedeo, S; Divari, S; Castagnaro, M

    2002-10-01

    A 3-year-old Siamese/short-haired European cat was referred for clinical disease characterized by dwarfism, facial dysmorphia, paralysis, small and curled ears, corneal clouding and large areas of alopecia. X-ray examination showed multiple bone dysplasia. On the basis of clinical features a form of mucopolysaccharidosis was suspected. The cat, killed at the owner's request, presented several severe skeletal deformities such as long caudal limbs, enlarged thorax with sunken breastbone, vertebral ankylosis in many spinal segments and visceral involvement. Histologically, the cat showed diffuse vacuolization and enlargement of cells in cartilage, bone and visceral organs. Ultrastructurally, membrane-bound vacuoles were filled with fibrillar and fluffy-material or concentrically whorled lamellae. Arylsulphatase B activity was 3.24 nm/mg/h in the affected cat and 30.6 in a normal age-matched control (NC). The L-iduronidase activity was slightly increased. Quantitation of total glycosaminoglycans (GAGs) revealed a 4.5-fold increase in the affected cat as compared with NC, while electrophoretic run of specific GAGs [chondroitin sulphate (CA); hyaluronan (HA); heparan sulphate (HS); dermatan sulphate (DS); keratan sulphate (KS)] performed on a cellulose acetate sheet, showed a striking increase in the DS band. On densitometric analysis of the electrophoretic run stained with Alcian Blue 8GX, the absorption of DS was eight-fold increased as compared with NC. The clinical and morphological features, and the biochemical findings, were consistent with the diagnosis of feline mucopolysaccharidosis VI.

  10. Assessment of potential shale gas and shale oil resources of the Norte Basin, Uruguay, 2011

    Science.gov (United States)

    Schenk, Christopher J.; Kirschbaum, Mark A.; Charpentier, Ronald R.; Cook, Troy; Klett, Timothy R.; Gautier, Donald L.; Pollastro, Richard M.; Weaver, Jean N.; Brownfield, Michael

    2011-01-01

    Using a performance-based geological assessment methodology, the U.S. Geological Survey estimated mean volumes of 13.4 trillion cubic feet of potential technically recoverable shale gas and 0.5 billion barrels of technically recoverable shale oil resources in the Norte Basin of Uruguay.

  11. Transactions on Petri Nets and Other Models of Concurrency VI

    DEFF Research Database (Denmark)

    The sixth volume of ToPNoC includes revised versions of selected papers from workshops and tutorials held at the 32nd International Conference on Application and Theory of Petri Nets and Concurrency. It also contains a special section on Networks, Protocols, and Services, as well as a contributed...... paper submitted through the regular submission track of ToPNoC. The 14 papers cover a diverse range of topics including model checking and system verification, synthesis, foundational work on specific classes of Petri nets, and innovative applications of Petri nets and other models of concurrency. Thus...... this volume gives a good view of ongoing concurrent systems and Petri nets research....

  12. Performance of a 'Transitioned' Infiltration Basin Part 2: Nitrogen and Phosphorus Removals.

    Science.gov (United States)

    Natarajan, Poornima; Davis, Allen P

    2016-04-01

    Infiltration basins have been widely used for stormwater runoff management. However, their longevity could be compromised over time, up to the point of operational failure. This research study showed that a 'failed' infiltration basin can 'transition' into a wetpond/wetland-like practice and provide water quality benefits. Performance evaluation over three years showed that the transitioned infiltration basin reduced the discharge event mean concentrations of total phosphorus (TP), dissolved phosphorus (DP), particulate phosphorus (PP), NOx-N (nitrate+nitrite), total Kjeldahl nitrogen (TKN), organic-N (ON), and total nitrogen (TN) during most storm events. Exports of TP, DP, ON, and TKN masses were observed only during the coldest periods. The cumulative mass removals were 61% TP, 53% DP, 63% PP, 79% NOx-N, 51% TKN, 45% ON, and 64% TN. The dry-weather nutrient concentrations combined with the environmental conditions at the transitioned basin indicated that sedimentation, adsorption, denitrification, and volume reduction were the removal mechanisms.

  13. Estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyVi® en ratones

    Directory of Open Access Journals (Sweden)

    Juan Carlos Ramírez

    2006-08-01

    Full Text Available Salmonella enterica serovar Typhi es un microorganismo que provoca más de 16 millones de casos de fiebre tifoidea con aproximadamente 600 000 muertes al año en todo el mundo. Dentro de las vacunas antitifoídicas la de polisacárido capsular Vi ha encontrado, gracias a sus incuestionables ventajas, una gran aceptación entre productores y consumidores. El presente trabajo aborda el estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyViâ en ratones. El estudio estuvo conformado por un grupo control no inoculado y un segundo grupo que recibió 0,05 mL de la vacuna por vía intramuscular. Se tomaron muestras de sangre a los -3, 7, 14, 21, 28, 42, 56 y 84 días. La actividad de anticuerpos IgG antipolisacárido Vi de los sueros individuales fue determinada por ELISA. Los datos fueron analizados por grupo y por sexo y se calculó el porcentaje de seroconversión, considerándose respondedor aquel animal que al menos aumentara en cuatro veces su título inicial. La respuesta de anticuerpos inducida por la vacuna mostró un aumento notable de los títulos de IgG antipolisacárido Vi en el grupo vacunado (100% de seroconversión, mientras que el grupo control no incrementó sus niveles mínimos iniciales (0% de respondedores. Aunque más dispersa, la respuesta de anticuerpos antiVi fue significativamente mayor en las hembras que en los machos.

  14. Quantum chemistry study of uranium(VI), neptunium(V), and plutonium(IV,VI) complexes with preorganized tetradentate phenanthrolineamide ligands.

    Science.gov (United States)

    Xiao, Cheng-Liang; Wu, Qun-Yan; Wang, Cong-Zhi; Zhao, Yu-Liang; Chai, Zhi-Fang; Shi, Wei-Qun

    2014-10-20

    The preorganized tetradentate 2,9-diamido-1,10-phenanthroline ligand with hard-soft donors combined in the same molecule has been found to possess high selectivity toward actinides in an acidic aqueous solution. In this work, density functional theory (DFT) coupled with the quasi-relativistic small-core pseudopotential method was used to investigate the structures, bonding nature, and thermodynamic behavior of uranium(VI), neptunium(V), and plutonium(IV,VI) with phenanthrolineamides. Theoretical optimization shows that Et-Tol-DAPhen and Et-Et-DAPhen ligands are both coordinated with actinides in a tetradentate chelating mode through two N donors of the phenanthroline moiety and two O donors of the amide moieties. It is found that [AnO2L(NO3)](n+) (An = U(VI), Np(V), Pu(VI); n = 0, 1) and PuL(NO3)4 are the main 1:1 complexes. With respect to 1:2 complexes, the reaction [Pu(H2O)9](4+)(aq) + 2L(org) + 2NO3(-)(aq) → [PuL2(NO3)2](2+)(org) + 9H2O(aq) might be another probable extraction mechanism for Pu(IV). From the viewpoint of energy, the phenanthrolineamides extract actinides in the order of Pu(IV) > U(VI) > Pu(VI) > Np(V), which agrees well with the experimental results. Additionally, all of the thermodynamic reactions are more energetically favorable for the Et-Tol-DAPhen ligand than the Et-Et-DAPhen ligand, indicating that substitution of one ethyl group with one tolyl group can enhance the complexation abilities toward actinide cations (anomalous aryl strengthening).

  15. Mean nuclear volume

    DEFF Research Database (Denmark)

    Mogensen, O.; Sørensen, Flemming Brandt; Bichel, P.

    1999-01-01

    We evaluated the following nine parameters with respect to their prognostic value in females with endometrial cancer: four stereologic parameters [mean nuclear volume (MNV), nuclear volume fraction, nuclear index and mitotic index], the immunohistochemical expression of cancer antigen (CA125...

  16. 77 FR 45653 - Yakima River Basin Conservation Advisory Group; Yakima River Basin Water Enhancement Project...

    Science.gov (United States)

    2012-08-01

    ... Bureau of Reclamation Yakima River Basin Conservation Advisory Group; Yakima River Basin Water... on the structure, implementation, and oversight of the Yakima River Basin Water Conservation Program... of the Water Conservation Program, including the applicable water conservation guidelines of...

  17. Study of reduction of chromium (VI by calcium polysulfide using spectrophotometric method

    Directory of Open Access Journals (Sweden)

    Batukhan Tatykaev

    2013-05-01

    Full Text Available The paper presents  the results of the study on reduction  of  Cr2O72-   to   Cr3 +  by aqueous solution of calcium polysulfide  using spectrophotometric method. Concentrations  of Cr (VI were determined on the basis of the absorption spectrum at the wavelength range 350 - 372 nm. The change of the concentration of Cr (VI during on reduction by calcium polysulfide has been shown.  The influence of pH on the rate of reducing of Cr (VI to Cr (III was considered: the rate of reducing of hexavalent chromium decreases with increasing pH. The data obtained show that recycling Cr (VI in industrial scale potentially effective at  the pH = 5.

  18. Derivative spectrophotometric determination of uranium (VI using diacetyl monoxime isonicotinoyl hydrazone (DMIH

    Directory of Open Access Journals (Sweden)

    ChandraSekhar Reddy Gadikota

    2011-08-01

    Full Text Available Uranium (VI forms a yellow coloured water soluble complex with diacetyl monoxime isonicotinoyl hydrazone (DMIH reagent in acidic buffer of pH 3.25 with ?max at 364 nm. The molar absorptivity and sandell’s sensitivity are 1.63 X 10 4 L.mol -1.cm-1 and 0.00307692 µg/cm 2, respectively. The Beer’s law validity range is 1.19–14.28 µg/mL. Uranium (VI forms (M:L 1:1 complex with DMIH and stability constant of the complex is 4.928 X 106 .The derivative spectrophotometric determination of U (VI was carried out by measuring peak height method. The developed derivative spectrophotometric method was employed for the determination of uranium (VI in rock and synthetic samples. The effect of various diverse ions was also studied.

  19. EXPERIMENTAL INVESTIGATION ON CHROMIUM(VI REMOVAL FROM AQUEOUS SOLUTION USING ACTIVATED CARBON RESORCINOL FORMALDEHYDE XEROGELS

    Directory of Open Access Journals (Sweden)

    Eghe A. Oyedoh

    2016-10-01

    Full Text Available The adsorption of chromium(VI metal ion in aqueous solutions by activated carbon resorcinol formaldehyde xerogels (ACRF was investigated. The results showed that pore structure, surface area and the adsorbent surface chemistry are important factors in the control of the adsorption of chromium(VI metal ions. The isotherm parameters were obtained from plots of the isotherms and from the application of Langmuir and Freundlich Isotherms. Based on regression analysis, the Langmuir isotherm model was the best fit. The maximum adsorption capacity of ACRF for chromium (VI was 241.9 mg/g. The pseudo-second-order kinetic model was the best fit to the experimental data for the adsorption of chromium metal ions by activated carbon resorcinol formaldehyde xerogels. The thermodynamics of Cr(VI ions adsorption onto ACRF was a spontaneous and endothermic process.

  20. Tüür, Erkki-Sven: Architectonics VI. Passion. Illusion / Guy S. Rickards

    Index Scriptorium Estoniae

    Rickards, Guy S.

    1996-01-01

    Uuest heliplaadist "Tüür, Erkki-Sven: Architectonics VI. Passion. Illusion. Crystallisatio. Requiem. Estonian Philharmonic Chamber Choir, Tallinn Chamber Orchestra, Tõnu Kaljuste. ECM New Series 449 459-2 (64 minutes: DDD)

  1. Biosorption of Cr(VI from Aqueous Solution Using Murraya koenigii (Curry tree Stems

    Directory of Open Access Journals (Sweden)

    Selvaraj Suresh

    2016-12-01

    Full Text Available In the present work, the sorption capacity of Murraya Koenigii Stems (MKST, an agricultural waste, is identified for the removal of Cr(VI from aqueous solution and the effect of different process parameters likes pH and adsorbent dosage were studied. pH 1 is observed to be the optimum pH for Cr(VI sorption onto the biosorbent. The equilibrium data of Cr(VI sorption fit well with the Langmuir model with a monolayer sorption capacity of 12.25 mg/g. The results show that the metal ion interacts strongly with the biosorbent and can be effectively used in the removal of Cr(VI from aqueous solution. DOI: http://dx.doi.org/10.17807/orbital.v0i0.867

  2. Removal of Cr(VI from Aqueous Environments Using Micelle-Clay Adsorption

    Directory of Open Access Journals (Sweden)

    Mohannad Qurie

    2013-01-01

    Full Text Available Removal of Cr(VI from aqueous solutions under different conditions was investigated using either clay (montmorillonite or micelle-clay complex, the last obtained by adsorbing critical micelle concentration of octadecyltrimethylammonium ions onto montmorillonite. Batch experiments showed the effects of contact time, adsorbent dosage, and pH on the removal efficiency of Cr(VI from aqueous solutions. Langmuir adsorption isotherm fitted the experimental data giving significant results. Filtration experiments using columns filled with micelle-clay complex mixed with sand were performed to assess Cr(VI removal efficiency under continuous flow at different pH values. The micelle-clay complex used in this study was capable of removing Cr(VI from aqueous solutions without any prior acidification of the sample. Results demonstrated that the removal effectiveness reached nearly 100% when using optimal conditions for both batch and continuous flow techniques.

  3. Involvement of myosin VI immunoanalog in pinocytosis and phagocytosis in Amoeba proteus.

    Science.gov (United States)

    Sobczak, Magdalena; Wasik, Anna; Kłopocka, Wanda; Redowicz, Maria Jolanta

    2008-12-01

    Recently, we found a 130-kDa myosin VI immunoanalog in amoeba, which bound to actin in an ATP-sensitive manner and in migrating amoebae colocalized to filamentous actin and dynamin II-containing vesicular structures. To further characterize this protein, we assessed its involvement in amoeba pinocytosis and phagocytosis. Confocal immunofluorescence microscopy and electron microscopy of immunogold-stained cells revealed that, in pinocytotic and phagocytotic amoebae, the myosin VI immunoanalog was visible throughout the cells, including pinocytotic channels and pinocytotic vesicles as well as phagosomes and emerging phagocytic cups. Blocking endogenous protein with anti-porcine myosin VI antibody (introduced into cells by means of microinjection) caused severe defects in pinocytosis and phagocytosis. In comparison with control cells, the treated amoebae formed ~75% less pinocytotic channels and phagocytosed ~65% less Tetrahymena cells. These data indicate that the myosin VI immunoanalog has an important role in pinocytosis and phagocytosis in Amoeba proteus (Pal.).

  4. Prevalence and genetic analysis of phenotypically Vi- negative Salmonella typhi isolates in children from Kathmandu, Nepal.

    Science.gov (United States)

    Pulickal, Anoop S; Callaghan, Martin J; Kelly, Dominic F; Maskey, Mitu; Mahat, Sandeep; Hamaluba, Mainga; Dongol, Sabina; Adhikari, Neelam; Thorson, Stephen; Basynat, Buddha; Murdoch, David R; Farrar, Jeremy J; Pollard, Andrew J

    2013-08-01

    The Vi capsular polysaccharide (ViPS) protects Salmonella enterica subspecies enterica serotype Typhi (S.Typhi) in vivo by multiple mechanisms. Recent microbiological reports from typhoid endemic countries suggest that acapsulate S.Typhi may occur in nature and contribute to clinical typhoid fever that is indistinguishable from disease caused by capsulate strains. The prevalence and genetic basis of ViPS-negative S.Typhi isolates in children from Kathmandu, Nepal, were tested in 68 isolates. Although 5.9% of isolates tested negative for capsular expression by slide agglutination tests, a novel multiplex PCR assay and individual PCR analyses demonstrated the presence of all 14 genes responsible for the synthesis, transportation and regulation of the ViPS. These data suggest that phenotypically acapsulate S.Typhi may not have a genetic basis for the same.

  5. Adsorption studies on fruits of Gular (Ficus glomerata): Removal of Cr(VI) from synthetic wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Rifaqat A.K., E-mail: rakrao1@rediffmail.com [Environmental Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, UP (India); Rehman, Fouzia [Environmental Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, UP (India)

    2010-09-15

    The adsorption of Cr(VI) was studied in batch system using fruits of Ficus glomerata as adsorbent. The effect of temperature, pH, initial Cr(VI) concentration and time was investigated. Scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) was used to investigate surface morphology and active functional groups present on the adsorbent surface. Thermodynamic parameters like free energy change ({Delta}G{sup 0}), enthalpy ({Delta}H{sup 0}) and entropy ({Delta}S{sup 0}) indicate the spontaneous, endothermic and increased randomness nature of Cr(VI) adsorption. Equilibrium data were fitted well with Langmuir isotherm at 50 deg. C. The magnitude of mean free energy indicates chemical nature of adsorption. The breakthrough and exhaustive capacities were found to be 5 and 23.1 mg g{sup -1} respectively. The applicability of the adsorbent has been demonstrated by removing Cr(VI) from electroplating wastewater.

  6. Reduction of Health Risks Due to Chromium(VI)Using Mesquite: A Potential Cr Phytoremediator

    Energy Technology Data Exchange (ETDEWEB)

    Gardea-Torresdey, Jorge L.; Aldrich, Mary V.; Peralta-Videa, Jose R.; Parsons, Jason G.

    2004-03-29

    Chromium is a transition metal extensively used in industry. Cr mining and industrial operations account for chromium wastes at Superfund sites in the United States. A study was performed to investigate the possibility of using mesquite (Prosopis spp.), which is an indigenous desert plant species, to remove Cr from contaminated sites. In this study, mesquite plants were grown in an agar-based medium containing 75 mg L-1 and 125 mg L-1 of Cr(VI). The Cr content of leaf tissue (992 mg kg-1 of dry weight, from 125 mg L-1 of Cr(VI)) indicated that mesquite could be classified as a chromium hyperaccumulator. X-ray absorption spectroscopy (XAS) studies performed to experimental samples showed that mesquite roots absorbed some of the supplied Cr(VI). However, the data analyses of plant tissues demonstrated that the absorbed Cr(VI) was fully reduced to Cr(III) in the leaf tissue.

  7. Solvent extraction of the ion-pairs of chromium(VI) and molybdenum(VI) with trioctylmethylammonium chloride and benzyldimethylcetylammonium chloride.

    Science.gov (United States)

    Ohashi, K; Shikina, K; Nagatsu, H; Ito, I; Yamamoto, K

    1984-11-01

    The number of capriquat molecules per chromium(VI) atom in the chromate-capriquat ion-association complex has been found to be between one and two. The distribution ratio in the extraction of chromium(VI) with capriquat is dependent on the dielectric constant of the organic solvent, with a minimum at a dielectric constant of about 8. The absorption spectra of the ion-pair extracted into cyclohexane, carbon tetrachloride, benzene and n-butanol are very similar to that of chromate in aqueous solution. The absorption spectra of the chromium(VI)-capriquat extracts in these organic solvents gradually change to an absorption spectrum similar to that of HCrO(4)(-) in aqueous solution. Chromium(VI)-capriquat extracted into chloroform and 1,2-dichloroethane gives absorption spectra similar to that of HCrO(4)(-)in aqueous medium. The chromium(VI)-capriquat species extracted into 1,2-dichloroethane may be (Q(+))(2).CrO(4)(2-)(H(2)O)(n). In contrast, chromium(VI) is extracted with capriquat into the other organic solvents from ammoniacal medium as a mixture of (Q(+))(2).CrO(4)(2-)(H(2)O)(n) and Q(+).NH(4)(+).CrO(4)(2-)(H(2)O)(n). The spectral change is ascribed to the change of the extracted species from (Q(+))(2).CrO(4)(2-)(H(2)O)(n) and Q(+)NH(4)(+).CrO(4)(-)(H(2)O)(n) to Q(+).HCrO(4)(2-)(H(2)O)(n-1). The chromium(VI)-zephiramine species extracted is formulated as (Q(+), NH(4)(+))(2)CrO(4)(2-)(H(2)O)(n).(Q(+).Cl(-))(m). Molybdenum(VI) is extracted with capriquat into the same organic solvents as a mixture of (Q(+))(2).MoO(4)(2-)(H(2)O)(n) and Q(+).NH(4)(+).MoO(4)(2-).(H(2)O)(n).

  8. Quantification of denudation of Iberian basins, the erosional signal of continental scale capture processes

    Science.gov (United States)

    Antón, Loreto; Muñoz Martín, Alfonso; De Vicente, Gerardo

    2016-04-01

    In central and northern Iberia, the development of the present-day drainage network was related to the opening of formerly closed fluvial systems developed within the ancient Cenozoic basins. The lowering of base level, induced by tectonic activity, fluvial capture or eustatic or climate variability, was transmitted upstream along fluvial channels in the form of erosional waves. For the main foreland basins in Iberia (Duero, Tajo and Ebro Basins) the opening of an outward drainage system leads to high incision and denudation rates, within intrabasinal areas. These processes had main influence in the evolution of the Iberian topography, since the late Cenozoic. Although, key questions on the timing and processes involved in the basin opening, as well as the influence of tectonics on it, remain open. Signals of this change in drainage conditions are still preserved in some areas, and can be analyzed by the study of longitudinal profile shapes, and by the analysis of the present topography and the spatial distribution of surface erosion associated to the exorheic history of the basins. The analysis of the denudation processes for these main basins, through the reconstruction of the former (Late Miocene) sedimentary infill, provides a quantification of the sediment fluxes in response to the drainage opening. Maps of denudation are performed for the different basins, and an integrated analysis of erosional volumes and spatial distribution of dissection are approach in terms of timing, tectonic influences and the fluvial response to the captures. The analyses of the longitudinal river profiles and the erosional patterns and volumes within the main Iberian Basins, seems to highlight important questions about the different response of the studied catchments, which may help to understand the processes and timing involved in the post Neogene drainage, and the topographic evolution of the former internally drained central Iberia.

  9. A volume law for specification of linear channel storage for estimation of large floods

    Science.gov (United States)

    Zhang, Shangyou; Cordery, Ian; Sharma, Ashish

    2000-02-01

    A method of estimating large floods using a linear storage-routing approach is presented. The differences between the proposed approach and those traditionally used are (1) that the flood producing properties of basins are represented by a linear system, (2) the storage parameters of the distributed model are determined using a volume law which, unlike other storage-routing models, accounts for the distribution of storage in natural basins, and (3) the basin outflow hydrograph is determined analytically and expressed in a succinct mathematical form. The single model parameter is estimated from observed data without direct fitting, unlike most traditionally used methods. The model was tested by showing it could reproduce observed large floods on a number of basins. This paper compares the proposed approach with a traditionally used storage routing approach using observed flood data from the Hacking River basin in New South Wales, Australia. Results confirm the usefulness of the proposed approach for estimation of large floods.

  10. Proteome of Geobacter sulfurreducens in the presence of U(VI).

    Science.gov (United States)

    Orellana, Roberto; Hixson, Kim K; Murphy, Sean; Mester, Tünde; Sharma, Manju L; Lipton, Mary S; Lovley, Derek R

    2014-12-01

    Geobacter species often play an important role in the in situ bioremediation of uranium-contaminated groundwater, but little is known about how these microbes avoid uranium toxicity. To evaluate this further, the proteome of Geobacter sulfurreducens exposed to 100 µM U(VI) acetate was compared to control cells not exposed to U(VI). Of the 1363 proteins detected from these cultures, 203 proteins had higher abundance during exposure to U(VI) compared with the control cells and 148 proteins had lower abundance. U(VI)-exposed cultures expressed lower levels of proteins involved in growth, protein and amino acid biosynthesis, as well as key central metabolism enzymes as a result of the deleterious effect of U(VI) on the growth of G. sulfurreducens. In contrast, proteins involved in detoxification, such as several efflux pumps belonging to the RND (resistance-nodulation-cell division) family, and membrane protection, and other proteins, such as chaperones and proteins involved in secretion systems, were found in higher abundance in cells exposed to U(VI). Exposing G. sulfurreducens to U(VI) resulted in a higher abundance of many proteins associated with the oxidative stress response, such as superoxide dismutase and superoxide reductase. A strain in which the gene for superoxide dismutase was deleted grew more slowly than the WT strain in the presence of U(VI), but not in its absence. The results suggested that there is no specific mechanism for uranium detoxification. Rather, multiple general stress responses are induced, which presumably enable Geobacter species to tolerate high uranium concentrations.

  11. New low cost sorbents for Cr(VI – batch and column experiments

    Directory of Open Access Journals (Sweden)

    Šillerová H.

    2013-04-01

    Full Text Available The use of agricultural byproducts and industrial biowaste materials has been shown to be an attractive technique for removing Cr(VI from contaminated waste waters. In this study, used brewers draff, peat moss, sawdust, grape stalks and husks were investigated as novel biosorbents for Cr(VI. The material was tested in two different modifications. The material was dried, cut and sieved and part of it was subjected to acid (2 M H2SO4 and alkali (0.5 M NaOH pre-treatments to remove starch, proteins and sugars. Fourier transform infrared rays analysis on solid phase (FTIR-ATR was used to determine the main functional groups that might control the metal uptake. Batch experiments were performed at different pH values (3, 4.5, 6 and at various initial concentration of Cr(VI (25–2012;250 mg L−1. Two equilibrium empirical models, Langmuir and Freundlich, were used to describe Cr(VI adsorption. In order to identify possible reduction processes, ion exchange separation on the AG1-X8 resin was used to separate the anionic Cr(VI and the reduced cationic Cr(III from the aqueous phase after biosorption. As expected, Cr(VI removal was pH-dependent and fitted well both the Langmuir and Freundlich isotherm models. The ion exchange separation showed that Cr(VI reduction had occurred in the solution during biosorption. The efficiency of draff as a biosorbent was comparable (or even higher to highly organic materials (e.g., composted peat showing its potential application for Cr(VI decontamination.

  12. Upscaling of U(VI) Desorption and Transport Using Decimeter-Scale Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Derrick

    2015-01-28

    Experimental work was used to validate modeling studies and develop multicontinuum models of U(VI) transport in a contaminated aquifer. At the bench scale, it has been shown that U(VI) desorption is rate-limited and that rates are dependent on the bicarbonate concentration. Two decimeter-scale experiments were conducted in order to help establish rigorous upscaling approaches that could be tested at the tracer test and plume scales.

  13. Upscaling of U(VI) Desorption and Transport Using Decimeter-Scale Tanks

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Derrick [Colorado School of Mines, Golden, CO (United States)

    2014-12-22

    Experimental work was used to validate modeling studies and develop multicontinuum models of U(VI) transport in a contaminated aquifer. At the bench scale, it has been shown that U(VI) desorption is rate-limited and that rates are dependent on the bicarbonate concentration. Two decimeter-scale experiments were conducted in order to help establish rigorous upscaling approaches that could be tested at the tracer test and plume scales.

  14. CHROMIUM (VI ADSORPTION ONTO ACTIVATED KRAFT LIGNIN PRODUCED FROM ALFA GRASS (STIPA TENACISSIMA

    Directory of Open Access Journals (Sweden)

    Nassima Tazrouti

    2009-05-01

    Full Text Available Activated lignin having a surface area of 1023 m2 g-1 has been prepared from sulfate lignin that was treated by 30% H2O2 and carbonized at 300 °C in order to test the chromium (VI adsorption from aqueous solution. The influence of contact time, pH, initial concentrations of adsorbent and adsorbate, and temperature on the adsorption capacity were investi-gated. The maximum removal of Cr(VI was found to be 92.36 % at pH=2 and a contact time of 80 min. Optimal concentration of lignin and Cr(VI were found to be 3.8 g L-1 and 180 mg L-1, respectively. The adsorption kinetics data fitted well with a pseudo-second-order equation, and the rate of removal of chromium was found to speed up with increasing temperature. Activation energy for the adsorption process was found to be 18.19 kJ mol-1. The Langmuir and Freundlich adsorption isotherm models were applied to describe the isotherm and isotherm constants for the adsorption of Cr (VI on lignin. These constants and correlation coefficients of the isotherm models were calculated and compared. Results indicated that Cr (VI uptake could be described by the Langmuir adsorption model. The maximum adsorption capacity (qm of Cr (VI on lignin was 75.75 mg g-1 at 40°C. The dimensionless equilibrium parameter (RL signified a favorable adsorption of Cr (VI on lignin and was found to be between 0.0601 and 0.818 (0VI from waste water.

  15. IV-VI semiconductor growth on silicon substrates and new mid-infrared laser fabrication methods

    Science.gov (United States)

    McCann; Chao; Sachar; McAlister; Li; Fang; Wu; Namjou

    1999-09-01

    This paper reviews results from research conducted at the University of Oklahoma on the development of new IV-VI semiconductor (lead salt) epitaxial growth and laser fabrication procedures that can ultimately lead to dramatic increases in mid-IR laser operating temperatures. Work has focused on growth of IV-VI semiconductor laser structures on silicon substrates using buffer layers that contain BaF2. Recent experiments show that it is possible to obtain high crystalline quality IV-VI semiconductor layer structures on (111)-oriented silicon substrates using molecular beam epitaxy (MBE) or on (100)-oriented silicon using a combination of MBE and liquid phase epitaxy (LPE). Experimental data for IV-VI semiconductor layer structures grown on silicon substrates including crystalline quality information as determined by high resolution X-ray diffraction (HRXRD) measurements and absorption edge information as determined by Fourier transform infrared (FTIR) transmission measurements are presented. Results show that these materials can be used to fabricate lasers that cover the 3 microns (3333 cm-1) to 16 microns (625 cm-1) spectral range. Removal of IV-VI semiconductor laser structures from the silicon growth substrate by dissolving BaF2 buffer layers with water is also demonstrated. This allows epitaxially-grown laser structures to be sandwiched between two heat sinks with a minimum of thermally resistive IV-VI semiconductor material. Theoretical modeling predicts that IV-VI lasers fabricated this way will have maximum continuous wave (cw) operating temperatures at least 60 degrees higher than those of IV-VI lasers fabricated on PbSe or PbTe substrates.

  16. Formation of stable uranium(VI) colloidal nanoparticles in conditions relevant to radioactive waste disposal.

    Science.gov (United States)

    Bots, Pieter; Morris, Katherine; Hibberd, Rosemary; Law, Gareth T W; Mosselmans, J Frederick W; Brown, Andy P; Doutch, James; Smith, Andrew J; Shaw, Samuel

    2014-12-09

    The favored pathway for disposal of higher activity radioactive wastes is via deep geological disposal. Many geological disposal facility designs include cement in their engineering design. Over the long term, interaction of groundwater with the cement and waste will form a plume of a hyperalkaline leachate (pH 10-13), and the behavior of radionuclides needs to be constrained under these extreme conditions to minimize the environmental hazard from the wastes. For uranium, a key component of many radioactive wastes, thermodynamic modeling predicts that, at high pH, U(VI) solubility will be very low (nM or lower) and controlled by equilibrium with solid phase alkali and alkaline-earth uranates. However, the formation of U(VI) colloids could potentially enhance the mobility of U(VI) under these conditions, and characterizing the potential for formation and medium-term stability of U(VI) colloids is important in underpinning our understanding of U behavior in waste disposal. Reflecting this, we applied conventional geochemical and microscopy techniques combined with synchrotron based in situ and ex situ X-ray techniques (small-angle X-ray scattering and X-ray adsorption spectroscopy (XAS)) to characterize colloidal U(VI) nanoparticles in a synthetic cement leachate (pH > 13) containing 4.2-252 μM U(VI). The results show that in cement leachates with 42 μM U(VI), colloids formed within hours and remained stable for several years. The colloids consisted of 1.5-1.8 nm nanoparticles with a proportion forming 20-60 nm aggregates. Using XAS and electron microscopy, we were able to determine that the colloidal nanoparticles had a clarkeite (sodium-uranate)-type crystallographic structure. The presented results have clear and hitherto unrecognized implications for the mobility of U(VI) in cementitious environments, in particular those associated with the geological disposal of nuclear waste.

  17. Syringomyelia in mucopolysaccharidosis type VI (Maroteaux-Lamy syndrome): imaging findings following bone marrow transplantation

    Energy Technology Data Exchange (ETDEWEB)

    Hite, S.H. [Department of Radiology, Box 292, University of Minnesota Hospital and Clinic, 420 Delaware Street SE, Minneapolis, MN 55455 (United States); Krivit, W. [Department of Pediatrics and Institute for Human Genetics, University of Minnesota Hospital and Clinic, Minneapolis, MN (United States); Haines, S.J. [Department of Neurological Surgery, University of Minnesota Hospital and Clinic, Minneapolis, MN (United States); Whitley, C.B. [Department of Pediatrics and Institute for Human Genetics, University of Minnesota Hospital and Clinic, Minneapolis, MN (United States)

    1997-09-01

    We present the imaging findings in a patient with mucopolysaccharidosis (MPS) type VI (Maroteaux-Lamy syndrome) who developed holocord syringomyelia. This represents the only reported case of syrinx formation in a child with MPS VI. Clinical, neurologic and spinal magnetic resonance imaging findings are presented. The patient has maintained a stable clinical and neurologic course over the period following allogeneic bone marrow transplant. (orig.). With 3 figs.

  18. Applications of Ferrate(VI) to Wastewater Reclamation and Water Treatment

    Science.gov (United States)

    Kim, H.; Choi, H.; Lee, K.; Nam, J.; Kim, I.

    2010-12-01

    The estimated amount of water resources is about 63 billion cubic meters in Korea. However, due to the lack of precipitation during the dry season, natural flows are not enough for the water supply. In addition, since the lack of water affects water quality, environmental problems are occurred in natural and social systems. In this study, we investigated the application feasibility of ferrate(VI) systems to water and wastewater treatment. And we'd like to suggest an alternative solution for conservation and efficient reuse of the limited water resources. In the research area of environmental applications, a primary interest has been focused to the power of ferrate(VI) systems in the decomposition of pollutants in wastewater and industrial effluents due to its potential use as a strong, relatively non-toxic, and oxidizing agent for diverse environmental contaminants. Also ferrate(VI) has additional advantages as a very efficient coagulant and a sorbent of pollutants. We have analysed and compared several ferrate(VI) manufacturing processes, especially focused on the electro chemical methods(Fig. 1). And we have investigated the applications of the manufactured ferrate(VI) in our own laboratory and the commercial ferrate(VI) to decomposition of persistent organic pollutants in water. Under optimal conditions, the removal efficiencies of 2-chlorophenol and benzothiophene were above 90%(Fig. 2). The ferrate system(VI) is promising and can be one of the most efficient alternatives among the advanced oxidation processes(AOPs) for degradation of persistent organic pollutants, and is an innovative technology for the wastewater reclamation, water reusing systems, and water treatment systems. Fig 1. Comparison of Electro-Chemical Ferrate(VI) manufacturing Processes Fig 2. Degradation of 2-Chlorophenol and Bezothiophene by Ferrate. (Experimental Conditions : 2-CP = 3ppm, BT = 5ppm, NaClO4 = 0.05M)

  19. Vi ved for lidt om danske børn, der er opvokset med specifikke sprogforstyrrelser

    DEFF Research Database (Denmark)

    Jensen de Lopez, Kristine

    2008-01-01

    Et barn, der lider af sprogforstyrrelser, føler sig ofte svigtet af omverdenen. I Danmark har vi hidtil ikke haft mulighed for at hjælpe, men nu er basale redskaber under udvikling......Et barn, der lider af sprogforstyrrelser, føler sig ofte svigtet af omverdenen. I Danmark har vi hidtil ikke haft mulighed for at hjælpe, men nu er basale redskaber under udvikling...

  20. Localization and mobility of synaptic vesicles in Myosin VI mutants of Drosophila.

    Directory of Open Access Journals (Sweden)

    Marta Kisiel

    Full Text Available BACKGROUND: At the Drosophila neuromuscular junction (NMJ, synaptic vesicles are mobile; however, the mechanisms that regulate vesicle traffic at the nerve terminal are not fully understood. Myosin VI has been shown to be important for proper synaptic physiology and morphology at the NMJ, likely by functioning as a vesicle tether. Here we investigate vesicle dynamics in Myosin VI mutants of Drosophila. RESULTS: In Drosophila, Myosin VI is encoded by the gene, jaguar (jar. To visualize active vesicle cycling we used FM dye loading and compared loss of function alleles of jar with controls. These studies revealed a differential distribution of vesicles at the jar mutant nerve terminal, with the newly endocytosed vesicles observed throughout the mutant boutons in contrast to the peripheral localization visualized at control NMJs. This finding is consistent with a role for Myosin VI in restraining vesicle mobility at the synapse to ensure proper localization. To further investigate regulation of vesicle dynamics by Myosin VI, FRAP analysis was used to analyze movement of GFP-labeled synaptic vesicles within individual boutons. FRAP revealed that synaptic vesicles are moving more freely in the jar mutant boutons, indicated by changes in initial bleach depth and rapid recovery of fluorescence following photobleaching. CONCLUSION: This data provides insights into the role for Myosin VI in mediating synaptic vesicle dynamics at the nerve terminal. We observed mislocalization of actively cycling vesicles and an apparent increase in vesicle mobility when Myosin VI levels are reduced. These observations support the notion that a major function of Myosin VI in the nerve terminal is tethering synaptic vesicles to proper sub-cellular location within the bouton.