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Sample records for base metal refinery

  1. Effective Recovery of Vanadium from Oil Refinery Waste into Vanadium-Based Metal-Organic Frameworks.

    Science.gov (United States)

    Zhan, Guowu; Ng, Wei Cheng; Lin, Wenlin Yvonne; Koh, Shin Nuo; Wang, Chi-Hwa

    2018-03-06

    Carbon black waste, an oil refinery waste, contains a high concentration of vanadium(V) leftover from the processing of crude oil. For the sake of environmental sustainability, it is therefore of interest to recover the vanadium as useful products instead of disposing of it. In this work, V was recovered in the form of vanadium-based metal-organic frameworks (V-MOFs) via a novel pathway by using the leaching solution of carbon black waste instead of commercially available vanadium chemicals. Two different types of V-MOFs with high levels of crystallinity and phase purity were fabricated in very high yields (>98%) based on a coordination modulation method. The V-MOFs exhibited well-defined and controlled shapes such as nanofibers (length: > 10 μm) and nanorods (length: ∼270 nm). Furthermore, the V-MOFs showed high catalytic activities for the oxidation of benzyl alcohol to benzaldehyde, indicating the strong potential of the waste-derived V-MOFs in catalysis applications. Overall, our work offers a green synthesis pathway for the preparation of V-MOFs by using heavy metals of industrial waste as the metal source.

  2. A retrospective analysis of nickel exposure data at a South African base metal refinery.

    Science.gov (United States)

    Young, Monica M; Van Der Merwe, Cornelius J; Linde, Stefan J L; Du Plessis, Johan L

    2018-03-01

    This study aimed to analyze historical soluble nickel exposure data from a South African base metal refinery and to identify trends in the soluble nickel exposure from 1981 until 2014 in the electrowinning department. Exposure data were presented in an exposure matrix, which described exposure profiles for both area and personal exposures inside two tankhouses. Exposure data were standardized by converting total nickel aerosol concentrations to inhalable nickel concentrations (correction factor 3.0). One-way analyses of variances (ANOVA) were conducted to identify significant differences in log-transformed area and personal exposures from 1982 until 2014, and the trends were assessed with linear regression. Differences were evaluated in area exposure between sections inside the tankhouses, i.e., East, West, and Center bays and in personal exposure between occupations, i.e., cell workers, crane drivers, and supervisors. Area exposure in Tankhouse 1 declined significantly (p ≤ 0.0001) between 1982 and 1986 with a factor of 29. However, after 1986 no significant downward trend in area exposure was evident in Tankhouse 1. Personal exposures in Tankhouse 1 significantly (p ≤ 0.0001) decreased with a factor of three between 1991 and 2014. No significant trends were evident in area and personal exposure in Tankhouse 2. Downward exposure trends were evident in Tankhouse 1 and may be ascribed to the implementation of various control measures and process changes, e.g., increasing polypropylene bead load. Limited data were available for Tankhouse 2, therefore, no trend in exposure could be established. Retrospective analyses may be used to identify trends and anomalies in exposure which might not have been identified during daily exposure monitoring.

  3. Metal leaching from refinery waste hydroprocessing catalyst.

    Science.gov (United States)

    Marafi, Meena; Rana, Mohan S

    2018-05-18

    The present study aims to develop an eco-friendly methodology for the recovery of nickel (Ni), molybdenum (Mo), and vanadium (V) from the refinery waste spent hydroprocessing catalyst. The proposed process has two stages: the first stage is to separate alumina, while the second stage involves the separation of metal compounds. The effectiveness of leaching agents, such as NH 4 OH, (NH 4 ) 2 CO 3 , and (NH 4 ) 2 S 2 O 8 , for the extraction of Mo, V, Ni, and Al from the refinery spent catalyst has been reported as a function of reagent concentration (0.5 to 2.0 molar), leaching time (1 to 6 h), and temperature (35 to 60°C). The optimal leaching conditions were achieved to obtain the maximum recovery of Mo, Ni, and V metals. The effect of the mixture of multi-ammonium salts on the metal extraction was also studied, which showed an adverse effect for Ni and V, while marginal improvement was observed for Mo leaching. The ammonium salts can form soluble metal complexes, in which stability or solubility depends on the nature of ammonium salt and the reaction conditions. The extracted metals and support can be reused to synthesize a fresh hydroprocessing catalyst. The process will reduce the refinery waste and recover the expensive metals. Therefore, the process is not only important from an environmental point of view but also vital from an economic perspective.

  4. Assessment of dermal exposure and skin condition of workers exposed to nickel at a South African base metal refinery.

    Science.gov (United States)

    Du Plessis, Johannes L; Eloff, Frederik C; Badenhorst, Casper J; Olivier, Johretha; Laubscher, Petrus J; Van Aarde, Michiel N; Franken, Anja

    2010-01-01

    The objectives of this study were to assess dermal exposure of cell workers to nickel at a South African base metal refinery and to characterize their skin condition by measuring the skin hydration and trans epidermal water loss (TEWL) indices. The skin hydration index of the index finger, palm, neck, and forehead was measured before, during and at the end of the shift. The TEWL index was measured before and at the end of the shift. Dermal exposure samples were collected with Ghostwipes from the index finger and palm of the dominant hand, before, during, and at the end of the shift. Neck and forehead samples were collected before and at the end of the shift. Wipe samples of various surfaces in the workplace were also collected. Wipes were analyzed for nickel according to NIOSH method 9102, using inductively coupled plasma-atomic emission spectrometry. Hydration indices measured on the hands decreased significantly during the shift, but recovered to normal levels by the end of the shift. TEWL indices for the index finger and palm of the hands are indicative of a low barrier function even before commencement of the shift, which further deteriorated significantly during the shift. During the shift, substantial nickel skin loading occurred on the index finger and palm of the hand. Levels on the neck and forehead were much lower. Various workplace surfaces, which workers come into contact with, were also contaminated with nickel. The skin condition and high levels of nickel on the skin were most probably caused by inadequate chemical protection provided by protective gloves. Although, the permeability of nickel through intact skin is considered to be low, a decreased barrier function of dehydrated or slightly damaged skin will increase its permeability for nickel. The ethnicity of these exposed workers may contribute significantly toward the low incidence of allergic contact dermatitis observed. Several measures to lower dermal exposure to nickel are also recommended.

  5. Urinary excretion of platinum from South African precious metals refinery workers.

    Science.gov (United States)

    Linde, Stephanus J L; Franken, Anja; du Plessis, Johannes L

    2018-03-30

    Urinary platinum (Pt) excretion is a reliable biomarker for occupational Pt exposure and has been previously reported for precious metals refinery workers in Europe but not for South Africa, the world's largest producer of Pt. This study aimed to quantify the urinary Pt excretion of South African precious metals refinery workers. Spot urine samples were collected from 40 workers (directly and indirectly exposed to Pt) at two South African precious metals refineries on three consecutive mornings prior to their shifts. Urine samples were analysed for Pt using inductively coupled plasma-mass spectrometry and were corrected for creatinine content. The urinary Pt excretion of workers did not differ significantly between sampling days. Urinary Pt excretions ranged from work area (P=0.0006; η 2 =0.567) and the number of years workers were employed at the refineries (P=0.003; η 2 =0.261) influenced their urinary Pt excretion according to effect size analyses. Directly exposed workers had significantly higher urinary Pt excretion compared with indirectly exposed workers (P=0.007). The urinary Pt excretion of South African precious metals refinery workers reported in this study is comparable with that of seven other studies conducted in precious metals refineries and automotive catalyst plants in Europe. The Pt body burden of workers is predominantly determined by their work area, years of employment in the refineries and whether they are directly or indirectly exposed to Pt. © Article author(s) (or their employer(s) unless otherwise stated in the text of the article) 2018. All rights reserved. No commercial use is permitted unless otherwise expressly granted.

  6. Refinery scheduling

    Energy Technology Data Exchange (ETDEWEB)

    Magalhaes, Marcus V.; Fraga, Eder T. [PETROBRAS, Rio de Janeiro, RJ (Brazil); Shah, Nilay [Imperial College, London (United Kingdom)

    2004-07-01

    This work addresses the refinery scheduling problem using mathematical programming techniques. The solution adopted was to decompose the entire refinery model into a crude oil scheduling and a product scheduling problem. The envelope for the crude oil scheduling problem is composed of a terminal, a pipeline and the crude area of a refinery, including the crude distillation units. The solution method adopted includes a decomposition technique based on the topology of the system. The envelope for the product scheduling comprises all tanks, process units and products found in a refinery. Once crude scheduling decisions are Also available the product scheduling is solved using a rolling horizon algorithm. All models were tested with real data from PETROBRAS' REFAP refinery, located in Canoas, Southern Brazil. (author)

  7. Nature's refineriesMetals and metalloids in arc volcanoes

    Science.gov (United States)

    Henley, R.W.; Berger, Byron R.

    2013-01-01

    Chemical data for fumaroles and for atmospheric gas and ash plumes from active arc volcanoes provide glimpses of the rates of release of metal and metalloids, such as Tl and Cd, from shallow and mid-crust magmas. Data from copper deposits formed in ancient volcanoes at depths of up to about 1500 m in the fractures below paleo-fumaroles, and at around 2000–4000 m in association with sub-volcanic intrusions (porphyry copper deposits) provide evidence of sub-surface deposition of Cu–Au–Ag–Mo and a range of other minor elements including Te, Se, As and Sb. These deposits, or ‘sinks’, of metals consistently record sustained histories of magmatic gas streaming through volcanic systems interspersed by continuing intrusive and eruptive activity. Here we integrate data from ancient and modern volcanic systems and show that the fluxes of metals and metalloids are controlled by a) the maintenance of fracture permeability in the stressed crust below volcanoes and b) the chemical processes that are triggered as magmatic gas, initially undersaturated with metals and metalloids, expands from lithostatic to very low pressure conditions through fracture arrays. The recognition of gas streaming may also account for the phenomenon of ‘excess degassing’, and defines an integral, but generally understated, component of active volcanic systems – a volcanic gas core – that is likely to be integral to the progression of eruptions to Plinean state.Destabilization of solvated molecular metal and metalloid species in magmatic gas mixtures and changes in their redox state are triggered, as it expands to the surface by abrupt pressure drops, or throttles' in the fracture array that guides expansion to the surface. The electronically harder, low electronegativity metals, such as copper and iron, deposit rapidly in response to expansion followed more slowly by arsenic with antimony as sulfosalts. Heavy, large radius, softer elements such as bismuth, lead, and thallium

  8. Characterizing exposures to airborne metals and nanoparticle emissions in a refinery.

    Science.gov (United States)

    Miller, Arthur; Drake, Pamela L; Hintz, Patrick; Habjan, Matt

    2010-07-01

    An air quality survey was conducted at a precious metals refinery in order to evaluate worker exposures to airborne metals and to provide detailed characterization of the aerosols. Two areas within the refinery were characterized: a furnace room and an electro-refining area. In line with standard survey practices, both personal and area air filter samples were collected on 37-mm filters and analyzed for metals by inductively coupled plasma-atomic emission spectroscopy. In addition to the standard sampling, measurements were conducted using other tools, designed to provide enhanced characterization of the workplace aerosols. The number concentration and number-weighted particle size distribution of airborne particles were measured with a fast mobility particle sizer (FMPS). Custom-designed software was used to correlate particle concentration data with spatial location data to generate contour maps of particle number concentrations in the work areas. Short-term samples were collected in areas of localized high concentrations and analyzed using transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) to determine particle morphology and elemental chemistry. Analysis of filter samples indicated that all of the workers were exposed to levels of silver above the Occupational Safety and Health Administration permissible exposure limit of 0.01 mg m(-3) even though the localized ventilation was functioning. Measurements with the FMPS indicated that particle number concentrations near the furnace increased up to 1000-fold above the baseline during the pouring of molten metal. Spatial mapping revealed localized elevated particle concentrations near the furnaces and plumes of particles rising into the stairwells and traveling to the upper work areas. Results of TEM/EDS analyses confirmed the high number of nanoparticles measured by the FMPS and indicated the aerosols were rich in metals including silver, lead, antimony, selenium, and zinc. Results of

  9. Heavy metals in allotment gardens close to an oil refinery in Plock

    International Nuclear Information System (INIS)

    Mikuta, W.; Indeka, L.

    1997-01-01

    In the period 1984-1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Plock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfail (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust. 41 refs., 1 fig., 7 tabs

  10. Heavy metals in allotment gardens close to an oil refinery in Plock

    Energy Technology Data Exchange (ETDEWEB)

    Mikuta, W.; Indeka, L. [Warsaw Agricultural University, Warsaw (Poland). Dept. of Environmental Protection, Faculty of Horticulture

    1997-05-01

    In the period 1984-1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Plock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfail (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust. 41 refs., 1 fig., 7 tabs.

  11. Reduction of heavy metals in refinery waste sludge using em treatment

    International Nuclear Information System (INIS)

    Ahmad, J.; Ahmad, F.; Saleemi, A.R.; Ahmad, I.

    2005-01-01

    This paper presents the efforts of National Cleaner Production Center (NCPC) and Attock Refinery Limited (ARL) Rawalpindi, to address the problem of refinery solid waste. A trial project was designed to treat and convert 1.7 m ton to oil sludge into environmental friendly residue (compost) under anaerobic conditions. The residue can be treated as bio fertilizer for agricultural purpose. The trial on bio remediation (anaerobic) of oily sludge of ARL, Rawalpindi within its premises using EM technology was successfully completed with the collaboration of effective microorganism research organization (EMRO), NCPC and ARL between 29th October to 10th December, 2002. The effective microorganisms transformed the undiluted oily sludge from ARL into bioactive sludge; which may be called as bio sludge. For heavy metal breakdown the trial data shows that Ba has been reduced by 85% in the EM. Treated oily sludge as compared to original ARL sludge, and Pb, Fe, Zn and Ni have been reduced by about 50% in the treated bio sludge. The contents of As, Cr, Cu and Mn showed no change. The residue obtained can be used as a bio fertilizer. (author)

  12. Airborne concentrations of metals and total dust during solid catalyst loading and unloading operations at a petroleum refinery.

    Science.gov (United States)

    Lewis, Ryan C; Gaffney, Shannon H; Le, Matthew H; Unice, Ken M; Paustenbach, Dennis J

    2012-09-01

    Workers handle catalysts extensively at petroleum refineries throughout the world each year; however, little information is available regarding the airborne concentrations and plausible exposures during this type of work. In this paper, we evaluated the airborne concentrations of 15 metals and total dust generated during solid catalyst loading and unloading operations at one of the largest petroleum refineries in the world using historical industrial hygiene samples collected between 1989 and 2006. The total dust and metals, which included aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, molybdenum, nickel, platinum, silicon, silver, vanadium, and zinc, were evaluated in relation to the handling of four different types of solid catalysts associated with three major types of catalytic processes. Consideration was given to the known components of the solid catalysts and any metals that were likely deposited onto them during use. A total of 180 analytical results were included in this analysis, representing 13 personal and 54 area samples. Of the long-term personal samples, airborne concentrations of metals ranged from refinery and perhaps other modern refineries during the timeframe examined. Copyright © 2011 Elsevier GmbH. All rights reserved.

  13. Assessment of refinery effluents and receiving waters using biologically-based effect methods

    International Nuclear Information System (INIS)

    2012-01-01

    Within the EU it is apparent that the regulatory focus on the use of biologically-based effects methods in the assessment of refinery effluents and receiving waters has increased in the past decade. This has been reflected in a recent refinery survey which revealed an increased use of such methods for assessing the quality of refinery effluents and their receiving waters. This report provides an overview of recent techniques used for this purpose. Several case studies provided by CONCAWE member companies describe the application of biological methods to effluent discharge assessment and surface water monitoring. The case studies show that when biological methods are applied to refinery effluents and receiving waters they raise different questions compared with those obtained using physical and chemical methods. Although direct measurement of the toxicity of effluent and receiving to aquatic organisms is the most cited technique, more recent efforts include tests that also address the persistence of effluent toxicity once discharged into the receiving water. Similarly, ecological monitoring of receiving waters can identify effects of effluent inputs arising from species interactions and other secondary effects that would not always be apparent from the results of biological tests conducted on single aquatic organisms. In light of recent and proposed regulatory developments the objectives of this report are therefore to: Discuss the application of biologically-based effects methods (including ecological monitoring) to refinery discharges and receiving waters; Assess the implications of such methods for future regulation of refinery discharges; and Provide guidance on good practice that can be used by refineries and the downstream oil industry to carry out and interpret data obtained using biologically-based effects methods. While the emphasis is on the toxic effects of effluents, other properties will also be covered because of their interdependency in determining

  14. Assessment of refinery effluents and receiving waters using biologically-based effect methods

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-01-15

    Within the EU it is apparent that the regulatory focus on the use of biologically-based effects methods in the assessment of refinery effluents and receiving waters has increased in the past decade. This has been reflected in a recent refinery survey which revealed an increased use of such methods for assessing the quality of refinery effluents and their receiving waters. This report provides an overview of recent techniques used for this purpose. Several case studies provided by CONCAWE member companies describe the application of biological methods to effluent discharge assessment and surface water monitoring. The case studies show that when biological methods are applied to refinery effluents and receiving waters they raise different questions compared with those obtained using physical and chemical methods. Although direct measurement of the toxicity of effluent and receiving to aquatic organisms is the most cited technique, more recent efforts include tests that also address the persistence of effluent toxicity once discharged into the receiving water. Similarly, ecological monitoring of receiving waters can identify effects of effluent inputs arising from species interactions and other secondary effects that would not always be apparent from the results of biological tests conducted on single aquatic organisms. In light of recent and proposed regulatory developments the objectives of this report are therefore to: Discuss the application of biologically-based effects methods (including ecological monitoring) to refinery discharges and receiving waters; Assess the implications of such methods for future regulation of refinery discharges; and Provide guidance on good practice that can be used by refineries and the downstream oil industry to carry out and interpret data obtained using biologically-based effects methods. While the emphasis is on the toxic effects of effluents, other properties will also be covered because of their interdependency in determining

  15. Emergency Response Program Designing Based On Case Study ERP Regulations In Ilam Gas Refinery

    Directory of Open Access Journals (Sweden)

    Mehdi Tahmasbi

    2015-08-01

    Full Text Available The study of Emergency response plan designing is one of the most important prevention approaches in crisis management. This study aims to design emergency response plan based on case study ERP regulations in Ilam gas refinery. On the basis of risk assessment and identification techniques such as HAZOP and FMEA in Ilam gas refinery the risks have been prioritized and then according to this prioritization the design of possible scenarios which have the highest rate of occurrence and the highest level of damage has been separated. Possible scenarios were simulated with PHAST software. Then emergency response program has been designed for the special mode or similar cases. According to the internal emergency response plan for Ilam gas refinery and predictable conditions of the process special instructions should be considered at the time of the incident to suffer the least damage on people and environment in the shortest time possible.

  16. A dynamic, efficient, and flexible metal HAP standard for petroleum refinery FCCs

    Energy Technology Data Exchange (ETDEWEB)

    Rao, P. [Pennsylvania State Univ., University Park, PA (United States)

    2000-07-01

    The Petroleum Refinery Maximum Achievable Control Technology (MACT) II standards were recently announced by the United States Environmental Protection Agency. The standards are designed to control hazardous air pollutants (HAPs) from fluid catalytic cracking (FCC), catalytic reforming and sulfur recovery units. The major role of feed quality in determining emissions of heavy metals, sulfur oxides (SOx) and nitrous oxides from FCC vents were discussed. The impact of FCC feed quality on carbon dioxide emissions was also examined. Some potential loopholes in the SOx new source performance standard for FCCs were also identified. This paper also outlined regulatory issues that occur when pollutant emission rates vary with raw material or fuel quantity. When input qualities vary, the format of emission standards take on special meaning. In particular, proportional control standards perform poorly resulting in environmentally damaged inputs. Precautions should be taken in profit-induced moves to avoid lower quality inputs, particularly at this time for setting new directions for a cleaner environment. 22 refs., 2 tabs., 10 figs.

  17. Fate of heavy metals in vertical subsurface flow constructed wetlands treating secondary treated petroleum refinery wastewater in Kaduna, Nigeria.

    Science.gov (United States)

    Mustapha, Hassana Ibrahim; van Bruggen, J J A; Lens, P N L

    2018-01-02

    This study examined the performance of pilot-scale vertical subsurface flow constructed wetlands (VSF-CWs) planted with three indigenous plants, i.e. Typha latifolia, Cyperus alternifolius, and Cynodon dactylon, in removing heavy metals from secondary treated refinery wastewater under tropical conditions. The T. latifolia-planted VSF-CW had the best heavy metal removal performance, followed by the Cyperus alternifolius-planted VSF-CW and then the Cynodon dactylon-planted VSF-CW. The data indicated that Cu, Cr, Zn, Pb, Cd, and Fe were accumulated in the plants at all the three VSF-CWs. However, the accumulation of the heavy metals in the plants accounted for only a rather small fraction (0.09-16%) of the overall heavy metal removal by the wetlands. The plant roots accumulated the highest amount of heavy metals, followed by the leaves, and then the stem. Cr and Fe were mainly retained in the roots of T. latifolia, Cyperus alternifolius, and Cynodon dactylon (TF < 1), meaning that Cr and Fe were only partially transported to the leaves of these plants. This study showed that VSF-CWs planted with T. latifolia, Cyperus Alternifolius, and Cynodon dactylon can be used for the large-scale removal of heavy metals from secondary refinery wastewater.

  18. Assessment of Heavy and Trace Metals in Surface Soil Nearby an Oil Refinery, Saudi Arabia, Using Geoaccumulation and Pollution Indices.

    Science.gov (United States)

    Alshahri, Fatimh; El-Taher, A

    2018-04-30

    The present study deals with the measurement of heavy and trace metals in the soils of Ras Tanura city nearby one of the oldest and largest oil refineries located on Arabian Gulf, eastern Saudi Arabia. Metals were analyzed in 34 surface soil samples using plasma atomic emission spectrometer (ICPE-9820). The result showed that the mean values of the metals concentrations were in the order: Cd > Mo > Tb > Ce > Hf > Eu > Yb > U > Sm > Rb > Cr > Ni > Pb > Sc > Cs > Zn > Lu > Co. The mean values of Cd (39.9 mg/kg), Mo (13.2 mg/kg), Eu (4.01 mg/kg), Hf (6.09 mg/kg), Tb (8.23 mg/kg), and Yb (3.88) in soil samples were higher than the background values in soil and the world average. The obtained results indicated to elevated levels of Cd and Mo in most samples, with mean concentrations exceeded the background levels by 113 times for Cd and 5 times for Mo. Pollution index (PI) and Geoaccumulation (I geo ) for each metal were calculated to assess the metal contamination level of surface soil in the study area. The assessment results of PI and I geo revealed a significant pollution by Cd, Mo, Eu, Hf, Tb, and Yb in most of sampling sites nearby Ras Tanura refinery.

  19. Key outcomes from risk based assessment of pressure equipment in refineries

    International Nuclear Information System (INIS)

    Firth, D.; Lichti, K.; Hill, T.; Thomas, C.; Widrig, J.; Simmonds, G.; Karstensen, A.

    2012-01-01

    Risk based assessment (RBA) has become the best industry practice for management of pressure equipment reliability. Application of RBA programs significantly reduces risk and gives opportunity to optimize inspection programs and produce long term financial benefits. Quest Integrity Group have implemented risk based inspection programs n a variety of industries including ammonia, methanol, geothermal power, :combined cycle power, gas turbines, gas production facilities and refineries. This paper outlines the semi quantitative RBA procedures that have been followed and lists some of the specific technical outcomes. Advanced inspection and life assessment methods used in support of RBI in refineries ire discussed. Piping in refineries is a key risk issue and it is not uncommon for piping failures to result in major incidents. Specific inspection programs are available to monitor differing damage processes such as flow assisted corrosion, hydrogen damage and corrosion under insulation. During assessment it s often found that numerous pipes have never been inspected especially underground smaller diameter pipes which are frequently considered to be un-piggable using conventional technologies and difficult to inspect. Advanced high accuracy flexible miniaturized ultrasonic intelligent pigging combined with fitness for service assessment such as Invista TM is recommended for inspection of critical pipelines which previously have been un-piggable. The processing of crude oil from a range of sources can result in significant variations in the levels of contaminants such as chlorides and sulfides. Major failures have occurred as a result of very rapid increases in corrosion rates in hydrotreating processes due to rapid changes in chemistry. The outcome of the assessment of plants that have potentially high and variable levels of contaminants often results in a review the process chemistry, how it is monitored and development of a detailed corrosion monitoring program. Fired

  20. Treatment of Mineral Oil Refinery Wastewater in Microbial Fuel Cells Using Ionic Liquid Based Separators

    Directory of Open Access Journals (Sweden)

    Hasna Addi

    2018-03-01

    Full Text Available Microbial fuel cells (MFCs are an environmentally friendly technology that can recover electricity directly from several wastes at ambient temperatures. This work explores the use of mineral oil refinery wastewater as feedstock in single-chamber air-cathode MFC devices. A polymer inclusion membrane based on the ionic liquid methyltrioctylammonium chloride, [MTOA+][Cl−], at a concentration of 70% w/w, was used as separator, showing a good efficiency in power production and chemical oxygen demand (COD removal. The power and the chemical oxygen demand removal reached values of 45 mW/m3 and over 80%, respectively. The evolution of other parameters of the wastewater including nitrites, phosphates and sulphates were also studied. Kjeldahl nitrogen and sulphates were significantly reduced during MFC operation. The results show that mineral oil refinery wastewater can be used as feedstock in air breathing cathode-microbial fuel cells based on polymer ionic liquid inclusion membranes. This configuration could represent a good alternative for wastewater depuration while producing energy during the process.

  1. Gasoline from biomass through refinery-friendly carbohydrate-based bio-oil produced by ketalization.

    Science.gov (United States)

    Batalha, Nuno; da Silva, Alessandra V; de Souza, Matheus O; da Costa, Bruna M C; Gomes, Elisa S; Silva, Thiago C; Barros, Thalita G; Gonçalves, Maria L A; Caramão, Elina B; dos Santos, Luciana R M; Almeida, Marlon B B; de Souza, Rodrigo O M A; Lam, Yiu L; Carvalho, Nakédia M F; Miranda, Leandro S M; Pereira, Marcelo M

    2014-06-01

    The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Refinery profitability

    International Nuclear Information System (INIS)

    Tobin, G.

    1998-01-01

    Recently there has been considerable shutting down of oil refinery capacity in response to the increasing pressures on profitability. This article examines the situation and the industry's response to it, including the drive for mergers, disposal of fuel oil, downsizing of workforces and strategic alliances. Future trends and their implications are also discussed. (UK)

  3. Ground based measurements of SO2 and NO2 emissions from the oil refinery 'la Teja' in Montevideo city

    International Nuclear Information System (INIS)

    Frins, Erna; Casaballe, Nicolas; Osorio, Matias; Arismendi, Federico; Ibrahim, Ossama; Wagner, Thomas; Platt, Ulrich

    2011-01-01

    We present preliminary results of ground based measurements of SO 2 and NO 2 emissions from 'La Teja' oil refinery located in the northern part of Montevideo Bay. Our study is part of a long term effort to localize and monitor relevant emission sources in the city area of Montevideo. These measurements were performed with a Miniature Multi AXis Differential Optical Absorption Spectrometry (MiniMAX-DOAS) instrument, which is basically a temperature controlled medium-resolution spectrometer (∼ 0.5 nm) equipped with a small telescope and a stepper motor allowing automatic scans in one dimension. We present a discussion about the evolution and transformation of both above species in the atmosphere. Our observation site was approximately 1.9 km away from the oil refinery and we were able to perform vertical and horizontal scans of the plume emitted (during our measurements) almost horizontally from its stacks. The maximum value of the SO 2 slant column density (SCD) was found to be ∼ 4x10 17 molec cm -2 directly over the oil refinery, decreasing as the plume disperses. In contrast, the NO 2 SCD peaks at ∼ 1x10 16 molec cm -2 directly over the source and increases continuously as the plume disperses. The SO 2 flux measured immediately downwind of the refinery was found to be about 1200 kg h -1 (±40% uncertainty).

  4. Metal recovery from spent refinery catalysts by means of biotechnological strategies

    International Nuclear Information System (INIS)

    Beolchini, F.; Fonti, V.; Ferella, F.; Veglio, F.

    2010-01-01

    A bioleaching study aimed at recovering metals from hazardous spent hydroprocessing catalysts was carried out. The exhaust catalyst was rich in nickel (4.5 mg/g), vanadium (9.4 mg/g) and molybdenum (4.4 mg/g). Involved microorganisms were iron/sulphur oxidizing bacteria. Investigated factors were elemental sulphur addition, ferrous iron addition and actions contrasting a possible metal toxicity (either adding powdered activated charcoal or simulating a cross current process by means of periodical filtration). Ferrous iron resulted to be essential for metal extraction: nickel and vanadium extraction yields were 83% and 90%, respectively, while about 50% with no iron. The observed values for molybdenum extraction yields were not as high as Ni and V ones (the highest values were around 30-40%). The investigated actions aimed at contrasting a possible metal toxicity resulted not to be effective; in contrast, sequential filtration of the liquor leach had a significant negative effect on metals extraction. Nickel and vanadium dissolution kinetics resulted to be significantly faster than molybdenum dissolution ones. Furthermore, a simple first order kinetic model was successfully fitted to experimental data. All the observed results supported the important role of the indirect mechanism in bioleaching of LC-Finer catalysts.

  5. Metal recovery from spent refinery catalysts by means of biotechnological strategies

    Energy Technology Data Exchange (ETDEWEB)

    Beolchini, F., E-mail: f.beolchini@univpm.it [Department of Marine Sciences, Polytechnic University of Marche, Via Brecce Bianche, 60131 Ancona (Italy); Fonti, V. [Department of Marine Sciences, Polytechnic University of Marche, Via Brecce Bianche, 60131 Ancona (Italy); Ferella, F.; Veglio, F. [Department of Chemistry, Chemical Engineering and Materials, University of L' Aquila, Monteluco di Roio, 67040 L' Aquila (Italy)

    2010-06-15

    A bioleaching study aimed at recovering metals from hazardous spent hydroprocessing catalysts was carried out. The exhaust catalyst was rich in nickel (4.5 mg/g), vanadium (9.4 mg/g) and molybdenum (4.4 mg/g). Involved microorganisms were iron/sulphur oxidizing bacteria. Investigated factors were elemental sulphur addition, ferrous iron addition and actions contrasting a possible metal toxicity (either adding powdered activated charcoal or simulating a cross current process by means of periodical filtration). Ferrous iron resulted to be essential for metal extraction: nickel and vanadium extraction yields were 83% and 90%, respectively, while about 50% with no iron. The observed values for molybdenum extraction yields were not as high as Ni and V ones (the highest values were around 30-40%). The investigated actions aimed at contrasting a possible metal toxicity resulted not to be effective; in contrast, sequential filtration of the liquor leach had a significant negative effect on metals extraction. Nickel and vanadium dissolution kinetics resulted to be significantly faster than molybdenum dissolution ones. Furthermore, a simple first order kinetic model was successfully fitted to experimental data. All the observed results supported the important role of the indirect mechanism in bioleaching of LC-Finer catalysts.

  6. Environmental performance of an innovative waste refinery based on enzymatic treatment

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2011-01-01

    for virgin material and saving fossil resources. In this paper a life-cycle assessment of a pilot-scale waste refinery for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials......Decrease of fossil fuel dependence and global warming mitigation has become increasingly important issues during the last decades. With respect to waste management higher recycling rates for valuable materials as well as energy recovery from waste streams could play a significant role substituting......) from the waste. The waste refinery was compared to alternative treatments such as incineration, bioreactor landfill and mechanical-biological treatment followed by utilization of the RDF (refuse-derived fuel) for energy. The performance of the waste refinery turned out to be comparable...

  7. Bioleaching of metals from spent refinery petroleum catalyst using moderately thermophilic bacteria: effect of particle size.

    Science.gov (United States)

    Srichandan, Haragobinda; Singh, Sradhanjali; Pathak, Ashish; Kim, Dong-Jin; Lee, Seoung-Won; Heyes, Graeme

    2014-01-01

    The present work investigated the leaching potential of moderately thermophilic bacteria in the recovery of metals from spent petroleum catalyst of varying particle sizes. The batch bioleaching experiments were conducted by employing a mixed consortium of moderate thermophilic bacteria at 45°C and by using five different particle sizes (from 45 to >2000 μm) of acetone-washed spent catalyst. The elemental mapping by FESEM confirmed the presence of Al, Ni, V and Mo along with sulfur in the spent catalyst. During bioleaching, Ni (92-97%) and V (81-91%) were leached in higher concentrations, whereas leaching yields of Al (23-38%) were found to be lowest in all particle sizes investigated. Decreasing the particle size from >2000 μm to 45-106 μm caused an increase in leaching yields of metals during initial hours. However, the final metals leaching yields were almost independent of particle sizes of catalyst. Leaching kinetics was observed to follow the diffusion-controlled model showing the linearity more close than the chemical control. The results of the present study suggested that bioleaching using moderate thermophilic bacteria was highly effective in removing the metals from spent catalyst. Moreover, bioleaching can be conducted using spent catalyst of higher particle size (>2000 μm), thus saving the grinding cost and making process attractive for larger scale application.

  8. A METHODOLOGY BASED ON AN ECOLOGICAL ECONOMY APPROACH FOR THE INTEGRATING MANAGEMENT OF THE SULPHUROUS WATER IN AN OIL REFINERY

    Directory of Open Access Journals (Sweden)

    Gabriel Orlando Lobelles Sardiñas

    2016-10-01

    Full Text Available Despite the current highly stringent international standards regulating the contaminating emissions to the environment, the Oil refinery of Cienfuegos is still generating liquid and gaseous emissions contaminating the environment. The construction of new units as part of the Refinery expansion leads to an increase of these emissions due to the lack of technologies for the reutilization of the sulphurous water. The objective of this paper is to propose a methodology for the integral management of the sulphurous residual water in the oil refining process, including the evaluation and selection of the most feasible technological variant to minimize the sulphur contamination of water and the resulting emissions during the process. The methodology is based on the ecological economy tools, allowing a comprehensible evaluation of six technological variants at the refinery of Cienfuegos. The Life Cycle Assessment was applied (ACV by its Spanish acronym, by means of the software SimaPro 7.1. It was evaluated through the Eco Speed Method, to minimize the possible uncertainty. An economic evaluation was performed, taking into account the external costs for a more comprehensive analysis, enabling, along with the ecological indicators, the selection of the best technological variant, achieving a methodology based on a comprehensive evaluation, and as a positive impact, the implementation of the chosen variant (V5, 98.27% of the process water was recovered, as well as the sulphur that recovered from 94 to 99.8 %, reducing the emissions from 12 200 to 120 mg/Nm3 as SO2.

  9. Oil refineries

    International Nuclear Information System (INIS)

    Boehmer, S.; Winter, B.

    2001-01-01

    In refineries in particular attention is paid to the minimization of the generation of waste. Therefor catalysts in many processes are regenerated, absorbents are recycled and oily by-products are re-refined or used as fuels. This study discusses the origin and utilization of by-products from the oil industry. The processing of crude oils causes by-products and waste resulting from the crude oil itself or from cleaning measures for water pre-treatment, effluent treatment and flue gas treatment. (author)

  10. Fuzzy-based Prioritization of Health, Safety, and Environmental Risks: The Case of a Large Gas Refinery

    Directory of Open Access Journals (Sweden)

    Auob Mirsaeidi

    2017-01-01

    Full Text Available The main objective of this study was to develop a fuzzy–based framework for the prioritization of health, safety and environment related risks posed against employees, working conditions, and process equipment in large gas refineries. The First Refinery at Pars Special Economic Energy Zone in South of Iran was taken as a case study. For this purpose, health, safety and environment related risks were determined based on the three criteria of impact severity, occurrence probability, and detect-ability using a questionnaire of 33 identified failures. The values obtained were processed by a so-called ‘contribution coefficient’. The results were then subjected to fuzzification and fuzzy rules were defined to calculate the risk level indices as the model outputs, which was then employed to facilitate the management decision-making process by prioritizing the management options. The prioritization values were then classified in six categories in the order of risk severity. Results revealed that failure in a combustion furnace had the highest rank while failure in the slug catcher ranked the lowest among the risk sources. It was also found that about 0.4% of the identified risks prioritized as “intolerable”, 79% as “major”, 20% as “tolerable”, and 0.7% as “minor”. Thus, most of the risks (more than 79% associated with the refinery has the potential of significant risks. The results indicated that the risk of the pollutant emissions from the combustion furnaces is the highest. Exposures to harmful physical, chemical, psychological, and ergonomic substances are the other risks, respectively.

  11. Maximizing petrochemicals from refineries

    Energy Technology Data Exchange (ETDEWEB)

    Glover, B.; Foley, T.; Frey, S. [UOP, Des Plaines, IL (United States)

    2007-07-01

    New fuel quality requirements and high growth rates for petrochemicals are providing both challenges and opportunities for refineries. A key challenge in refineries today is to improve of the value of the products from the FCC unit. In particular, light FCC naphtha and LCO are prime candidates for improved utilization. Processing options have been developed focusing on new opportunities for these traditional fuel components. The Total Petrochemicals/UOP Olefin Cracking Process cracks C4-C8 olefins to produce propylene and ethylene. This process can be integrated into FCC units running at all severity levels to produce valuable light olefins while reducing the olefin content of the light FCC naphtha. Integration of the Olefin Cracking Process with an FCC unit can be accomplished to allow a range of operating modes which can accommodate changing demand for propylene, cracked naphtha and alkylate. Other processes developed by UOP allow for upgrading LCO into a range of products including petrochemical grade xylenes, benzene, high cetane diesel and low sulfur high octane gasoline. Various processing options are available which allow the products from LCO conversion to be adjusted based on the needs and opportunities of an individual refinery, as well as the external petrochemical demand cycles. This presentation will examine recent refining and petrochemical trends and highlight new process technologies that can be used to generate additional revenue from petrochemical production while addressing evolving clean fuel demands. (orig.)

  12. Determination of arsenic in petroleum refinery streams by electrothermal atomic absorption spectrometry after multivariate optimization based on Doehlert design

    Science.gov (United States)

    Cassella, Ricardo J.; de Sant'Ana, Otoniel D.; Santelli, Ricardo E.

    2002-12-01

    This paper reports the development of a methodology for the determination of arsenic in petroleum refinery aqueous streams containing large amounts of unknown volatile organic compounds, employing electrothermal atomic absorption spectrometry with polarized Zeeman-effect background correction. In order to make the procedure applicable, the influence of chemical modification and the drying step was examined. Also, pyrolysis and atomization temperatures and the amount of nitric acid added to the sample were optimized using a multivariate approach based on Doehlert matrix. Obtained results indicate that, in this kind of sample, arsenic must be determined by standard addition procedure with a careful control of the drying step temperature and ramp pattern. In order to evaluate the accuracy of the procedure, a test was performed in six spiked samples of petroleum refinery aqueous streams and the relative errors verified in the analysis of such samples (added As between 12.5 and 190 μg l -1) ranged from -7.2 to +16.7%. The detection limit and the relative standard deviation were also calculated and the values are 68 pg and 7.5% (at 12.5 μg l -1 level), respectively.

  13. Determination of arsenic in petroleum refinery streams by electrothermal atomic absorption spectrometry after multivariate optimization based on Doehlert design

    International Nuclear Information System (INIS)

    Cassella, Ricardo J.; Sant'Ana, Otoniel D. de; Santelli, Ricardo E.

    2002-01-01

    This paper reports the development of a methodology for the determination of arsenic in petroleum refinery aqueous streams containing large amounts of unknown volatile organic compounds, employing electrothermal atomic absorption spectrometry with polarized Zeeman-effect background correction. In order to make the procedure applicable, the influence of chemical modification and the drying step was examined. Also, pyrolysis and atomization temperatures and the amount of nitric acid added to the sample were optimized using a multivariate approach based on Doehlert matrix. Obtained results indicate that, in this kind of sample, arsenic must be determined by standard addition procedure with a careful control of the drying step temperature and ramp pattern. In order to evaluate the accuracy of the procedure, a test was performed in six spiked samples of petroleum refinery aqueous streams and the relative errors verified in the analysis of such samples (added As between 12.5 and 190 μg l -1 ) ranged from -7.2 to +16.7%. The detection limit and the relative standard deviation were also calculated and the values are 68 pg and 7.5% (at 12.5 μg l -1 level), respectively

  14. Development of a health effects based priority ranking system for air emissions reductions from oil refineries in Canada

    International Nuclear Information System (INIS)

    McColl, S.; Gower, S.; Hicks, J.; Shortreed, J.; Craig, L.

    2004-01-01

    This paper presents the concept and methodologies behind the development of a health effects priority ranking tool for the reduction of air emissions from oil refineries. The Health Effects Indicators Decision Index- Versions 2 (Heidi II) was designed to assist policy makers in prioritizing air emissions reductions on the basis of estimated risk to human health. Inputs include facility level rankings of potential health impacts associated with carcinogenic air toxics, non-carcinogenic air toxics and criteria air contaminants for each of the 20 refineries in Canada. Rankings of estimated health impacts are presented on predicted incidence of health effects. Heidi II considers site-specific annual pollutant emission data, ambient air concentrations associated with releases and concentration response functions for various types of health effects. Additional data includes location specific background air concentrations, site-specific population densities, and the baseline incidence of different health effects endpoints, such as cancer, non-cancer illnesses and cardiorespiratory illnesses and death. Air pollutants include the 29 air toxics reported annually in Environment Canada's National Pollutant Release Inventory. Three health impact ranking outputs are provided for each facility: ranking of pollutants based on predicted number of annual cases of health effects; ranking of pollutants based on simplified Disability Adjusted Life Years (DALYs); and ranking of pollutants based on more complex DALYs that consider types of cancer, systemic disease or types of cardiopulmonary health effects. Rankings rely on rough statistical estimates of predicted incidence rates for health endpoints. The models used to calculate rankings can provide useful guidance by comparing estimated health impacts. Heidi II has demonstrated that it is possible to develop a consistent and objective approach for ranking priority reductions of air emissions. Heidi II requires numerous types and

  15. Energy use in petroleum refineries

    Energy Technology Data Exchange (ETDEWEB)

    Haynes, V.O.

    1976-09-01

    Refining petroleum accounts for about 4 percent of the total energy consumed in the United States and about 15 percent of all industrial consumption. The kinds of energy used and the manner in which energy is used are discussed on a process-by-process basis. Emphasis is placed on existing processes to identify and quantify process and equipment substitutions which might significantly conserve energy. General industry and process information is given and estimates of potential savings are made. A few research and development opportunities are identified and nontechnical factors are discussed. Nearly one-half the energy consumed by refineries is obtained from by-product refinery gas and coke, and about one-third is supplied by natural gas. On a regional basis, refineries were found to vary by a factor of two in the amount of energy used to refine a unit of crude oil. Refineries in regions traditionally abundant in inexpensive natural gas were found to use relatively more natural gas and energy. About 36 percent of the energy used by petroleum refineries is consumed in the distillation units to separate the refinery streams into their basic components. Including energy for manufacturing hydrogen, about 24 percent of the total is used for cracking of the heavier components. Most of the remainder is used for reforming, hydrogen treating, and alkylation, distributed about 11, 17, and 6 percent respectively. Potential energy savings discussed in this report total 61 x 10/sup 13/ Btu/yr based on 1974 capacities, a figure which represents about 20 percent of the energy consumed to refine petroleum.

  16. Effects of alumina refinery wastewater and signature metal constituents at the upper thermal tolerance of: 1. The tropical diatom Nitzschia closterium

    International Nuclear Information System (INIS)

    Harford, A.J.; Hogan, A.C.; Tsang, J.J.; Parry, D.L.; Negri, A.P.; Adams, M.S.; Stauber, J.L.; Dam, R.A. van

    2011-01-01

    Research highlights: → Methodology to assess relevant toxicants to a tropical marine diatom are described. → Thermal sensitivity of N. closterium was close to the regional annual maximum SST. → First to derive EC50s for Al, Ga and V in N. closterium under tropical conditions. → N. closterium is one of the most sensitive organisms to Al reported to-date. → Environmental chemistry shows that the discharge is a low risk to this species. - Abstract: Ecotoxicological studies, using the tropical marine diatom, Nitzschia closterium (72-h growth rate), were undertaken to assess potential issues relating to the discharge from an alumina refinery in northern Australia. The studies assessed: (i) the species' upper thermal tolerance; (ii) the effects of three signature metals, aluminium (Al), vanadium (V) and gallium (Ga) (at 32 o C); and (iii) the effects of wastewater (at 27 and 32 o C). The critical thermal maximum and median inhibition temperature for N. closterium were 32.7 o C and 33.1 o C, respectively. Single metal toxicity tests found that N. closterium was more sensitive to Al compared to Ga and V, with IC 50 s (95% confidence limits) of 190 (140-280), 19,640 (11,600-25,200) and 42,000 (32,770-56,000) μg L -1 , respectively. The undiluted wastewater samples were of low toxicity to N. closterium (IC 50 s > 100% wastewater). Environmental chemistry data suggested that the key metals and discharge are a very low risk to this species.

  17. Bio-refinery approach for spent coffee grounds valorization.

    Science.gov (United States)

    Mata, Teresa M; Martins, António A; Caetano, Nídia S

    2018-01-01

    Although normally seen as a problem, current policies and strategic plans concur that if adequately managed, waste can be a source of the most interesting and valuable products, among which metals, oils and fats, lignin, cellulose and hemicelluloses, tannins, antioxidants, caffeine, polyphenols, pigments, flavonoids, through recycling, compound recovery or energy valorization, following the waste hierarchy. Besides contributing to more sustainable and circular economies, those products also have high commercial value when compared to the ones obtained by currently used waste treatment methods. In this paper, it is shown how the bio-refinery framework can be used to obtain high value products from organic waste. With spent coffee grounds as a case study, a sequential process is used to obtain first the most valuable, and then other products, allowing proper valorization of residues and increased sustainability of the whole process. Challenges facing full development and implementation of waste based bio-refineries are highlighted. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Integrated refinery waste management

    Energy Technology Data Exchange (ETDEWEB)

    Shieh, Y -S [ETG Environmental, Inc., Blue Bell, PA (US); Sheehan, W J [Separation and Recovery Systems, Inc., Irvine, CA (US)

    1992-01-01

    In response to the RCRA land ban regulations and TC rule promulgated by the U.S. Federal Environmental Protection Agency (EPA) in 1988-1990, an Integrated Refinery Waste Management (IRWM) program has been developed to provide cost-effective solutions to petroleum industry customers. The goal of IRWM is to provide technology based remediation treatment services to manage sludges and wastewaters generated from the oil refining processes, soils contaminated with petroleum distillates and groundwater contaminated with fuels. Resource recovery, volume reduction and waste minimization are the primary choices to mitigate environmental problems. Oil recovery has been performed through phase separation (such as centrifugation and filtration) and heating of heavy oils. Volume reduction is achieved by dewatering systems such as centrifuges and filter presses, and low temperature thermal treatment. Waste minimization can be accomplished by bioremediation and resource recovery through a cement kiln. (Author).

  19. Presenting a Model Based on Fuzzy Application to Optimize the Time of IBS Projects in Gas Refineries

    Directory of Open Access Journals (Sweden)

    Naderpour Abbas

    2017-01-01

    Full Text Available Nowadays, the construction industry has started to embrace IBS as a method of attaining better construction quality and productivity and reducing risks related to occupational safety and health. The built of pre-fabricated component in factories reduces many problems related to lack of purposing uncertainty in scheduling calculation and time management of projects. In the case of using IBS method for managing time in projects, former studies such as Allan Tay’s research, indicates that this method can save up at least 29% of overall completion period versus the conventional method. But beside mentioned advantages of this technical method, the projects could be optimized more and more in scheduling calculations. This issue is critical in gas refineries, since special parameters such as risk of spreading poison H2S gas and mandatory of performing projects in short time period events such as maintenance overhauls demands to perform projects in optimum time. Custom scheduling calculation of project planning uses the Critical Path Method (CPM as a tool for Planning Project’s activities. The researches of this paper’s authors indicated that Fuzzy Critical Path Method (FCPM is the best technique to manage the uncertainty in project scheduling and can save up the construction project’s time versus the custom methods. This paper aims to present a model based on fuzzy application in CPM calculations to optimize the time of Industrial Building System.

  20. Present day engines pollutant emissions: proposed model for refinery bases impact; Emissions de polluants des moteurs actuels: modelisation de l'impact des bases de raffinage

    Energy Technology Data Exchange (ETDEWEB)

    Hochart, N.; Jeuland, N.; Montagne, X. [Institut Francais du Petrole (IFP), Div. Techniques d' Applications Energetiques, 92 - Rueil-Malmaison (France); Raux, S. [Institut Francais du Petrole (IFP), Div. Techniques d' Applications Energetiques, Centre d' Etudes et de Developpement Industriel, Rene Navarre, 69 - Vernaison (France); Belot, G.; Cahill, B. [PSA-Peugiot-Citroen, 92 - La Garenne-Colombes (France); Faucon, R.; Petit, A. [Renault, 91 - Lardy (France); Michon, S. [Renault Trucks Powertrain, 69 - Saint Priest (France)

    2003-07-01

    Air quality improvement, especially in urban areas, is one of the major concerns for the coming years. For this reason, car manufacturers, equipment manufacturers and refiners have explored development issues to comply with increasingly severe anti-pollution requirements. In such a context, the identification of the most promising improvement options is essential. A research program, carried out by IFP (Institut francais du petrole), and supported by the French Ministry of Industry, PSA-Peugeot-Citroen, Renault and RVI (Renault Vehicules Industriels), has been built to study this point. It is based on a 4-year program with different steps focused on new engine technologies which will be available in the next 20 years in order to answer to more and more severe pollutant and CO{sub 2} emissions regulations. This program is divided into three main parts: the first one for Diesel car engines, the second for Diesel truck engines and the third for spark ignition engines. The aim of the work reported here is to characterize the effect of fuel formulation on pollutant emissions and engine tuning for different engine technologies. The originality of this study is to use refinery bases as parameters and not conventional physical or chemical parameters. The tested fuels have been chosen in order to represent the major refinery bases expected to be produced in the near future. These results, expressed with linear correlations between fuel composition and pollutant emissions, will help to give a new orientation to refinery tool. The engines presented in this publication are, for spark ignition engines, an EuroII lean-burn engine (Honda VTEC which equips the Honda Civic) and an EuroIII 1.8 l stoichiometric-running Renault engine which equips the Laguna vehicles, and, for diesel engines, an EuroII Renault Laguna 2.2 l indirect injection diesel engine and an EuroII RVI truck engine. For the fuel formulation, an original approach is proposed: while the classical studies are based

  1. Predicting refinery effluent toxicity on the basis of hydrocarbon composition determined by GCxGC analysis

    Energy Technology Data Exchange (ETDEWEB)

    Whale, G. [and others

    2013-04-15

    A high resolution analytical method for determining hydrocarbon blocks in petroleum products by comprehensive two-dimensional gas chromatography (GCxGC) was used for the analysis of petroleum hydrocarbons extracted from refinery effluents. From 105 CONCAWE refineries in Europe 111 refinery effluents were collected in the period June 2008 to March 2009 (CONCAWE, 2010). The effluents were analysed for metals, standard effluent parameters (including Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), oil in water (OiW), GCxGC speciated hydrocarbons, BTEX (Benzene, Toluene, Ethylbenzene, and Xylenes) and volatile organic compounds. This report describes the subsequent analysis of the GCxGC data, as described in hydrocarbon blocks, and uses the PETROTOX model, to predict the environmental toxicity (i.e. ecotoxicity) of the discharged effluents. A further analysis was undertaken to address the potential environmental impact of these predicted effects initially using default dilution factors and then,when necessary site specific factors. The report describes all the methods used to arrive at the predictions, and shows that for the majority of refinery effluents direct toxicity effects in the effluents are not anticipated. Furthermore, when applying either the EU Risk Assessment Technical Guidance Document (TGD) default dilution factors or site specific dilution factors, none of the refineries are predicted to exerting either acute or chronic toxicity to organisms in the receiving aquatic environment, based on their hydrocarbon composition present in the effluent samples.

  2. Isolation, identification, and environmental adaptability of heavy-metal-resistant bacteria from ramie rhizosphere soil around mine refinery

    OpenAIRE

    Jiang, Jie; Pan, Chaohu; Xiao, Aiping; Yang, Xiai; Zhang, Guimin

    2017-01-01

    Six bacteria strains from heavy-metal-polluted ramie rhizosphere soil were isolated through Cd2+ stress, which were numbered as JJ1, JJ2, JJ10, JJ11, JJ15, and JJ18. Sequence alignment and phylogenic analysis showed that strain JJ1 belonged to Pseudomonas, strain JJ2 belonged to Cupriavidus, strains JJ11 and JJ15 belonged to Bacillus, and strains JJ10 and JJ18 belonged to Acinetobacter. The tolerance capability of all the strains was the trend of Pb2+?>?Zn2+?>?Cu2+?>?Cd2+, the maximum toleran...

  3. Complexity index indicates refinery capability, value

    International Nuclear Information System (INIS)

    Johnston, D.

    1996-01-01

    Refinery size usually is measured in terms of distillation capacity. Relative size, however, can be measured using refinery complexity--a concept developed by W.L. Nelson in the 1960s. Nelson developed the complexity index to quantify the relative cost of components that make up a refinery. It is a pure cost index that provides a relative measure of the construction costs of a particular refinery based on its crude and upgrading capacity. The Nelson index compares the costs of various upgrading units--such as a fluid catalytic cracking (FCC) unit or a catalytic reformer--to the cost of a crude distillation unit. Computation of the index is an attempt to quantify the relative cost of a refinery based on the added cost of various upgrading units and the relative upgrading capacity. A review of complexity calculations, and an explanation of how indices have changed, provide a simple means of determining the complexity of single refineries or refining regions. The impact of complexity on product slate is also examined in this paper

  4. Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

    Energy Technology Data Exchange (ETDEWEB)

    Shoucheng, Wen [Yangtze Univ., HuBei Jingzhou (China)

    2014-02-15

    Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%.

  5. Petroleum Refinery Effluents Treatment by Advanced Oxidation Process with Methanol

    International Nuclear Information System (INIS)

    Shoucheng, Wen

    2014-01-01

    Petroleum refinery effluents are waste originating from industries primarily engaged in refining crude oil. It is a very complex compound of various oily wastes, water, heavy metals and so on. Conventional processes are unable to effectively remove the chemical oxygen demand (COD) of petroleum refinery effluents. Supercritical water oxidation (SCWO) was proposed to treat petroleum refinery effluents. In this paper, methanol was used to investigate co-oxidative effect of methanol on petroleum refinery effluents treatment. The results indicated that supercritical water oxidation is an effective process for petroleum refinery effluents treatment. Adding methanol caused an increase in COD removal. When reaction temperature is 440 .deg. C, residence time is 20 min, OE is 0.5 and initial COD is 40000 mg/L, and COD removal increases 8.5%

  6. Refractory metal based superalloys

    International Nuclear Information System (INIS)

    Alonso, Paula R.; Vicente, Eduardo E.; Rubiolo, Gerardo H.

    1999-01-01

    Refractory metals are looked as promising materials for primary circuits in fission reactors and even as fusion reactor components. Indeed, superalloys could be developed which take advantage of their high temperature properties together with the benefits of a two- phase (intermetallic compound-refractory metal matrix) coherent structure. In 1993, researchers of the Office National d'Etudes et de Recherches Aerospatiales of France reported the observation of such a coherent structure in the Ta-Ti-Zr-Al-Nb-Mo system although the exact composition is not reported. The intermetallic compound would be Ti 2 AlMo based. However, the formation of this compound and its possible coexistence with a disordered bcc phase in the ternary system Ti-Al-Mo is a controversial subject in the related literature. In this work we develop a technique to obtain homogeneous alloys samples with 50 Ti-25 Al-25 Mo composition. The resulting specimens were characterized by optical and electronic metallography (SEM), microprobe composition measurements (EPMA) and X-ray diffraction (XRD) analyses. The results show the evidence for a bcc (A2→B2) ordering reaction in the Ti-Al-Mo system in the 50 Ti-25 Al-25 Mo composition. (author)

  7. New horizontal and vertical mass transfer coefficient equation formulations applied to a refinery data base

    International Nuclear Information System (INIS)

    Hellums, L.J.; Fine, D.G.; DeCoursey, S.S.; Cronic, K.A.

    1984-01-01

    The American Petroleum Institute (API) has collected a large tracer data base representing the best field data on atmospheric dispersion performed up to 1982. Twelve of these tracer programs (Hanford 67, Green Glow, Prairie Grass, NRTS, TMI, Ocean Breeze, Dry Gulch, St. Louis, Rancho Seco, Paramount, Karlsruhe, Goodyear) were brought into Phillips Petroleum Company for Gaussian plume formulation using an optimal least squares procedure. The horizontal diffusion and the vertical diffusion were manipulated in an optimal fashion in the Gaussian plume formulation to give a best fit of calculated to experimental (field observations) data important conclusions from the many observations in this work are: 1. Field measured Turner stability when used with Pasquill-Gifford curves does not choose horizontal and vertical dispersion rates representative of true atmospheric turbulence in most cases, 2. Individual stabilities are required rather than assuming one stability for both dispersion rates, and 3. Horizontal diffusion is a function of downwind distance, crosswind distance, and stability for dispersion downwind of building complexes with considerable ground roughness

  8. The miraculously saved refineries

    International Nuclear Information System (INIS)

    Cosnard, D.

    2005-01-01

    During 20 years, refining has been the weak link of the petroleum industry. This sector has always suffered from a chronical overcapacity. Today, on the contrary, there is a lack of facilities and shortage is threatening. The Reichstett refinery (Alsace, France) is the smallest French refinery. It has been several times threatened with closure but today, thanks to the increasing demand, it works at full capacity. This short paper summarizes the history of this facility and its social and environmental impact in the region. (J.S.)

  9. Manganese Fractionation Using a Sequential Extraction Method to Evaluate Welders' Shielded Metal Arc Welding Exposures During Construction Projects in Oil Refineries.

    Science.gov (United States)

    Hanley, Kevin W; Andrews, Ronnee; Bertke, Steven; Ashley, Kevin

    2015-01-01

    The National Institute for Occupational Safety and Health has conducted an occupational exposure assessment study of manganese (Mn) in welding fume of construction workers rebuilding tanks, piping, and process equipment at two oil refineries. The objective of this study was to evaluate exposures to different Mn fractions using a sequential extraction procedure. Seventy-two worker-days were monitored for either total or respirable Mn during stick welding and associated activities both within and outside of confined spaces. The samples were analyzed using an experimental method to separate different Mn fractions by valence states based on selective chemical solubility. The full-shift total particulate Mn time-weighted average (TWA) breathing zone concentrations ranged from 0.013-29 for soluble Mn in a mild ammonium acetate solution; from 0.26-250 for Mn(0,2+) in acetic acid; from non-detectable (ND) - 350 for Mn(3+,4+) in hydroxylamine-hydrochloride; and from ND - 39 micrograms per cubic meter (μg/m(3)) for insoluble Mn fractions in hydrochloric and nitric acid. The summation of all Mn fractions in total particulate TWA ranged from 0.52-470 μg/m(3). The range of respirable particulate Mn TWA concentrations were from 0.20-28 for soluble Mn; from 1.4-270 for Mn(0,2+); from 0.49-150 for Mn(3+,4+); from ND - 100 for insoluble Mn; and from 2.0-490 μg/m(3) for Mn (sum of fractions). For all jobs combined, total particulate TWA GM concentrations of the Mn(sum) were 99 (GSD = 3.35) and 8.7 (GSD = 3.54) μg/m(3) for workers inside and outside of confined spaces; respirable Mn also showed much higher levels for welders within confined spaces. Regardless of particle size and confined space work status, Mn(0,2+) fraction was the most abundant followed by Mn(3+,4+) fraction, typically >50% and ∼30-40% of Mn(sum), respectively. Eighteen welders' exposures exceeded the ACGIH Threshold Limit Values for total Mn (100 μg/m(3)) and 25 exceeded the recently adopted respirable

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  11. Zirconium based bulk metallic glasses

    International Nuclear Information System (INIS)

    Dey, G.K.; Neogy, S.; Savalia, R.T.; Tewari, R.; Srivastava, D.; Banerjee, S.

    2006-01-01

    Metallic glasses have come into prominence in recent times because their nanocrystalline atomic arrangement imparts many useful and unusual properties to these metallic solids. In this study, bulk glasses have been obtained in Zr based multicomponent alloy by induction melting these alloys in silica crucibles and casting these in form of rods 3 and 6 mm in diameter in a copper mould

  12. Yugoslavian Petroleum Refinery development program

    International Nuclear Information System (INIS)

    Ocic, Ozren

    1999-01-01

    This paper shows the analysis of the world petroleum industry development, being an important factor in planning the development of the Yugoslav petroleum industry and Pancevo Petroleum Refinery, as well. Then Yugoslav petroleum industry development is analysed, including the appropriate balances of crude oil production and crude oil products consumption. The way of realizing the basic targets are also proposed. Likewise, the analysis of the condition within West European refineries has been conducted, from the aspects of technology, energy consumption and environmental protection and the same analysis for Pancevo Petroleum Refinery has been presented, too. The analysis of the condition within the refineries in the European Union countries and comparing it with the condition within Pancevo Petroleum Refinery, makes it mainly possible to recognize the development programmes which should be realized in order that Pancevo Petroleum Refinery could reach the refining level of the EU countries. (Original)

  13. Refinery plugging by residual oil gellant chemicals in crude : understanding and preventing the problem through new oil gellant chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, R.S.; Cheng, A.; Tamayo, C.; Funkhouser, G.P. [Halliburton, Calgary, AB (Canada); Stemler, P. [Petro-Canada Oil and Gas, Inc., Calgary, AB (Canada); Lemieux, A. [Omnicon Consultants Inc., Edmonton, AB (Canada)

    2004-07-01

    Phosphate ester oil gellants are the most prevalent oil gellant technology in use by service companies. However, in 1995, they were found to be responsible for plugging distillation trays at 3 refineries across Canada including Imperial Oil's Strathcona refinery in Edmonton, Petro-Canada's refinery in Oakville, Ontario and Chevron's refinery in Burnaby, British Columbia. Since 1998, additional fouling has occurred in Canada, and in 2002, fouling was detected at a refinery in Pennsylvania while processing Canadian sweet, light crude. Since refiners pay a high cost for unscheduled refinery shutdowns, much effort has gone into solving this problem and to maintain the value of Canadian sweet, light crude. Studies by the Canadian Crude Quality Technical Association (CCQTA) have shown that phosphate esters begin to decompose through hydrolysis of the ester linkage at approximately 240 degrees. Gases cool as they move up the tower through distillation trays. Trays in the temperature range of 230 to 290 degrees C produce most of the volatile phosphorous compounds that condense out of the gas phase and cause plugging, thereby reducing the efficiency of distillation. Phosphate esters are often used with a metal crosslinker such as ferric iron or aluminium to gel hydrocarbons for use as a fracturing fluid. This paper described the advantages of existing ferric iron-crosslinked phosphate ester oil gels over the older, alternative oil gellant chemistries. Carbon dioxide-miscible, gelled hydrocarbon fracturing fluids provide better well stimulation by avoiding capillary pressure effects associated with water-based fluids. The fluid properties of the new phosphonate ester system were compared to those of a conventional phosphate ester system. Field tests from two fracturing treatments were also presented. Plugging did not occur with the new phosphonate ester treatment. 6 refs., 1 tab., 12 figs.

  14. Kvanefjeld refinery pilot plant operations

    International Nuclear Information System (INIS)

    Krebs, Damien; Furfaro, Domenic

    2016-01-01

    Greenland Minerals and Energy is a junior project development company which is listed on the Australian Stock Exchange (asx:GGG). It is developing the Kvanefjeld rare earth and uranium project located in the southern tip of Greenland. The project has completed a Feasibility Study and is currently in the permitting phase. Last year was a busy time for the company as it completed a Feasibility Study, a mining licence application (draft submitted in December 2015) and pilot plant operations. Beneficiation pilot plant operations were completed at GTK in Finland in April 2015. This pilot plant treated approximately 30 tonnes of ore to producing almost 2 tonnes of rare earth mineral concentrate. Later in the year a hydrometallurgical pilot plant was performed which mimicked the Refinery process. This pilot plant was performed at Outotec’s Pori Research laboratories in Finland from September till October 2015. The pilot plant treated approximately 200 kilograms of concentrate over 4 split operating campaigns. Each campaign was performed to focus on the performance of a specific part of the refinery flowsheet. This allowed for full operating focus on a single unit operation to ensure that it was operating correctly. The pilot plant operations were quite successful with no major issues with the flowsheet identified through continuous operation. Some fine tuning of conditions was required to ensure adequate removal of impurities was performed with recycle streams incorporated. Overall the leach extractions observed in the pilot plant exceeded the design assumptions in the Feasibility Study. These programs were partially funded by the EURARE program. The EURARE program aims to encourage the sustainable development of European based rare earth projects. This has the goal of allowing Europe to become less reliant on importation of these key raw materials. The professionalism and performance of both GTK and Outotec contributed significantly to the success of the pilot plant

  15. Valve automation in Indian refinery; Armaturenautomatisierung in indischer Raffinerie

    Energy Technology Data Exchange (ETDEWEB)

    Herbstritt, M. [AUMA Riester GmbH und Co. KG, Muellheim (Germany)

    2006-12-15

    The Mahul refinery near Mumbai is the third largest site of its kind in India. It is operated by BPCL, Bharat Petroleum Corporation Ltd. During the last few months, the refinery was extended. A plant for manufacturing motor lubricants was built, together with a tank farm for the products (LOBS = lube oil base stock). In April 2006 the new plant sections were put into operation. This article deals with the valve automation for this project. (orig.)

  16. Public relations: a re-examination of definition, role, and function based on community relations of the Standard Oil (Indiana) refinery at Sugar Creek, MO

    Energy Technology Data Exchange (ETDEWEB)

    Kruckeberg, D.A.

    1985-01-01

    This study describes public relations as it is commonly practiced today as: a vocation utilizing persuasive communication to obtain a vested nonmarketing goal on behalf of a represented client. It argues that public relation is better defined and practiced as: the active attempt to restore/maintain a sense of community. To illustrate what this dissertation advocates, a case study is used. Probably no organization had designed a community relations program with the specific and express purpose of fostering a sense of community, at least to the extent this dissertation calls for. However, the Standard Oil Company (Indiana) refinery at Sugar Creek, MO, has done this sufficiently to merit study. Based on the findings of the case study, which covers a 75-year period of time, specific recommendations are made in practicing public relations as advocated in this dissertation: the active attempt to restore/maintain a sense of community. The theoretical basis comes from the writings of the Chicago School of Social Thought. It is demonstrated that the Chicago School can provide an excellent theoretical basis to provide insight into public relations practice from a perspective that eliminates the problems that now exist in the role and function of public relations.

  17. Amorphous metal based nanoelectromechanical switch

    KAUST Repository

    Mayet, Abdulilah M.; Smith, Casey; Hussain, Muhammad Mustafa

    2013-01-01

    Nanoelectromechanical (NEM) switch is an interesting ultra-low power option which can operate in the harsh environment and can be a complementary element in complex digital circuitry. Although significant advancement is happening in this field, report on ultra-low voltage (pull-in) switch which offers high switching speed and area efficiency is yet to be made. One key challenge to achieve such characteristics is to fabricate nano-scale switches with amorphous metal so the shape and dimensional integrity are maintained to achieve the desired performance. Therefore, we report a tungsten alloy based amorphous metal with fabrication process development of laterally actuated dual gated NEM switches with 100 nm width and 200 nm air-gap to result in <5 volts of actuation voltage (Vpull-in). © 2013 IEEE.

  18. Amorphous metal based nanoelectromechanical switch

    KAUST Repository

    Mayet, Abdulilah M.

    2013-04-01

    Nanoelectromechanical (NEM) switch is an interesting ultra-low power option which can operate in the harsh environment and can be a complementary element in complex digital circuitry. Although significant advancement is happening in this field, report on ultra-low voltage (pull-in) switch which offers high switching speed and area efficiency is yet to be made. One key challenge to achieve such characteristics is to fabricate nano-scale switches with amorphous metal so the shape and dimensional integrity are maintained to achieve the desired performance. Therefore, we report a tungsten alloy based amorphous metal with fabrication process development of laterally actuated dual gated NEM switches with 100 nm width and 200 nm air-gap to result in <5 volts of actuation voltage (Vpull-in). © 2013 IEEE.

  19. Ranking environmental liabilities at a petroleum refinery

    International Nuclear Information System (INIS)

    Lupo, M.

    1995-01-01

    A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results

  20. An estimation of cogeneration potential by using refinery residuals in Mexico

    International Nuclear Information System (INIS)

    Marin-Sanchez, J.E.; Rodriguez-Toral, M.A.

    2007-01-01

    Electric power generation in Mexico is mainly based on fossil fuels, specifically heavy fuel oil, although the use of natural gas combined cycles (NGCC) is becoming increasingly important. This is the main destination that has promoted growing imports of natural gas, currently accounting for about 20% of the total national annual consumption. Available crude oil is becoming heavier; thus refineries should be able to process it, and to handle greater quantities of refinery residuals. If all refinery residuals are used in cogeneration plants serving petroleum refineries, the high heat/power ratio of refinery needs, leads to the availability of appreciable quantities of electricity that can be exported to the public utility. Thus, in a global perspective, Mexican imports of natural gas may be reduced by cogeneration using refinery residuals. This is not the authors' idea; in fact, PEMEX, the national oil company, has been entitled by the Mexican congress to sell its power leftovers to The Federal Electricity Commission (CFE) in order to use cogeneration in the way described for the years to come. A systematic way of determining the cogeneration potential by using refinery residuals from Mexican refineries is presented here, taking into account residual quantities and composition, from a national perspective, considering expected scenarios for Maya crude content going to local refineries in the years to come. Among different available technologies for cogeneration using refinery residuals, it is believed that the integrated gasification combined cycle (IGCC) would be the best option. Thus, considering IGCC plants supplying heat and power to refineries where it is projected to have refinery residuals for cogeneration, the expected electric power that can be sent to the public utility is quantified, along with the natural gas imports mitigation that may be attained. This in turn would contribute to a necessary fuel diversification policy balancing energy, economy and

  1. Benchmarking of refinery emissions performance : Executive summary

    International Nuclear Information System (INIS)

    2003-07-01

    This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, carbon monoxide, particulate, volatile organic compounds, ammonia and benzene. For each refinery in Canada, benchmark emissions were developed. Several factors can explain differences in Canadian and American refinery emission performance. 4 tabs., 7 figs

  2. Speciation in Metal Toxicity and Metal-Based Therapeutics

    Directory of Open Access Journals (Sweden)

    Douglas M. Templeton

    2015-04-01

    Full Text Available Metallic elements, ions and compounds produce varying degrees of toxicity in organisms with which they come into contact. Metal speciation is critical to understanding these adverse effects; the adjectives “heavy” and “toxic” are not helpful in describing the biological properties of individual elements, but detailed chemical structures are. As a broad generalization, the metallic form of an element is inert, and the ionic salts are the species that show more significant bioavailability. Yet the salts and other chelates of a metal ion can give rise to quite different toxicities, as exemplified by a range of carcinogenic potential for various nickel species. Another important distinction comes when a metallic element is organified, increasing its lipophilicity and hence its ability to penetrate the blood brain barrier, as is seen, for example, with organic mercury and tin species. Some metallic elements, such as gold and platinum, are themselves useful therapeutic agents in some forms, while other species of the same element can be toxic, thus focusing attention on species interconversions in evaluating metal-based drugs. The therapeutic use of metal-chelating agents introduces new species of the target metal in vivo, and this can affect not only its desired detoxification, but also introduce a potential for further mechanisms of toxicity. Examples of therapeutic iron chelator species are discussed in this context, as well as the more recent aspects of development of chelation therapy for uranium exposure.

  3. Risk analysis of the sea desalination plant at the 5th refinery of south ...

    African Journals Online (AJOL)

    In this study, hazards in the desalination unit of a gas refinery in Asaluyeh, south of Iran was evaluated, using the PHA-PRO6 software, for which recommendations were made to avoid potential risks involved. Based on 8-years history of the refinery operation, maintenance records, accidents, safety vulnerabilities of the plant ...

  4. The Implementation and Maintenance of a Behavioral Safety Process in a Petroleum Refinery

    Science.gov (United States)

    Myers, Wanda V.; McSween, Terry E.; Medina, Rixio E.; Rost, Kristen; Alvero, Alicia M.

    2010-01-01

    A values-centered and team-based behavioral safety process was implemented in a petroleum oil refinery. Employee teams defined the refinery's safety values and related practices, which were used to guide the process design and implementation. The process included (a) a safety assessment; (b) the clarification of safety-related values and related…

  5. Refineries in Europe under pressure

    International Nuclear Information System (INIS)

    Widdershoven, C.

    2008-01-01

    Current oil price developments and the economic and financial crisis are leading to a negative situation for the European refining sector. Analysts expect that a number of European oil refineries will lower their production in the coming months as a result of decreased petrol demand. [mk] [nl

  6. Bio refinery: towards a Biomass-based Sustainable Economy; Biorrefineria: hacia una economia sostenible basada en la biomasa

    Energy Technology Data Exchange (ETDEWEB)

    Ballesteros Perdices, M.

    2010-07-01

    At present, biomass is converted into energy in separate installations that have little capacity to obtain many products (ethanol, fatty acid esters, heat, electricity, etc) and that do not take advantage of all the economic potential offered by biomass. The future development of biomass as an energy source will be based on a single installation where all the fractions and byproducts of the biomass will be used to produce a large range of products: energy, bio fuels, chemicals and biomaterials. (Author) 1 refs.

  7. Thermodynamic simulation and evaluation of sugar refinery evaporators using a steady state modelling approach

    International Nuclear Information System (INIS)

    Lewis, A.E.; Khodabocus, F.; Dhokun, V.; Khalife, M.

    2010-01-01

    In a sugar refinery, the juice is concentrated through evaporation, with the objective of concentrating the juice to syrup as rapidly as possible. Because the heat of vaporization of water is relatively high, the evaporation process can be highly energy intensive, and therefore the economical use of steam is important in the refinery. This paper reports on the development of a simulation model for the evaporation sections of two Mauritian sugar refineries. The first objective was to use the simulation model to carry out an energy balance over the evaporators in order to assess the economy of steam usage over the refinery. The second objective was to examine to what extent a fundamental steady state model, based on thermodynamics (not kinetics) was capable of predicting the material and energy flows in two operating sugar refineries and thereby to evaluate the applicability of the modelling framework. The simulation model was validated using historical data as well as data from the plant DCS system. The simulation results generally correlated well with the measured values, except for one of the evaporators on one refinery. Some suggestions were made as to the cause of the discrepancy. On balance, it was found that both refineries are extremely efficient in terms of steam and equipment usage and that there is not much scope for energy optimisation within the present configuration - nor for much spare steam capacity for an additional refinery. It was also shown that steady state process simulation, using thermodynamic models, can generate a very useful representation of a working refinery. Besides being able to use the model to 'benchmark' the operation and thus evaluate its performance as a whole as well as across individual units, it could also be used to evaluate refinery performance across refineries, nationally as well as globally.

  8. Treatment and disposal of refinery sludges: Indian scenario.

    Science.gov (United States)

    Bhattacharyya, J K; Shekdar, A V

    2003-06-01

    Crude oil is a major source of energy and feedstock for petrochemicals. Oily sludge, bio-sludge and chemical sludge are the major sludges generated from the processes and effluent treatment plants of the refineries engaged in crude oil refining operations. Refineries in India generate about 28,220 tons of sludge per annum. Various types of pollutants like phenols, heavy metals, etc. are present in the sludges and they are treated as hazardous waste. Oily sludge, which is generated in much higher amount compared to other sludges, contains phenol (90-100 mg/kg), nickel (17-25 mg/kg), chromium (27-80 mg/kg), zinc (7-80 mg/kg), manganese (19-24 mg/kg), cadmium (0.8-2 mg/kg), copper (32-120 mg/kg) and lead (0.001-0.12 mg/ kg). Uncontrolled disposal practices of sludges in India cause degradation of environmental and depreciation of aesthetic quality. Environmental impact due to improper sludge management has also been identified. Salient features of various treatment and disposal practices have been discussed. Findings of a case study undertaken by the authors for Numaligarh Refinery in India have been presented. Various system alternatives have been identified for waste management in Numaligarh Refinery. A ranking exercise has been carried out to evaluate the alternatives and select the appropriate one. A detailed design of the selected waste management system has been presented.

  9. Knowledge-based metals & materials

    OpenAIRE

    Sasson, Amir

    2011-01-01

    This study presents the Norwegian metal and material industry (defined as all metal and material related firms located in Norway, regardless of ownership) and evaluates the industry according to the underlying dimensions of a global knowledge hub - cluster attractiveness, education attractiveness, talent attractiveness, R&D and innovation attractiveness, ownership attractiveness, environmental attractiveness and cluster dynamics.

  10. Prioritizing Improvable Human Capital Processes in Esfahan Oil Refinery Company Based on PCF and by IPA approach

    Directory of Open Access Journals (Sweden)

    Reza Behmanesh

    2012-06-01

    Full Text Available Development and management of human capital is an important task because it affects the performance of organization and hence the process improvements. However, it is necessary to deploy performance evaluation to prioritize improvable processes due to limited human resource, time and equipments. The objective of this research is to evaluate performance of the developed and managed human capital based upon the predetermined key performance indicators of American Productivity and Quality Center (APQC and to prioritize processes by Importance-Performance Analysis (IPA approach. As a case study, Esfahan Oil Refining Company (EORC has been studied. In order to analyze hypotheses, the state of human resource has been determined through data extracting among the best practice industries, and hence the strengths and weaknesses of the EORC have been identified. Finally, fuzzy numbers have been assigned to the Key Performance Indicators (KPIs and then the processes have been measured using the average value of its related KPIs. Consequently, the importance of the developed and managed human capital processes could be determined using the five points Likert spectrum. The reliability of the questionnaire has been determined by the Cronbach's Alpha of higher than 0.7, which is satisfactory. Findings imply that 10 out of 35 HCM processes in needs of improvement are prioritized as managing employee performance managing employee relations managing employee orientation and deployment developing and managing employee metrics developing and training employees managing employee communication managing human resource information systems (HRIS managing and maintaining employee data managing employee inquiry process and developing and managing time and attendance.

  11. Enterprise Integration of Management and Automation in a Refinery

    Science.gov (United States)

    Wang, Chengen

    Traditionally, problems in a petroleum refinery were separately modeled and solved with respect to disciplines. The segregated implementations of various disciplinary technologies resulted in considerable barriers impeding the pursuit of global optimal performance. It is recognized that enterprise-wide integration of the managerial and automation systems is of fundamental significance for refineries to promptly respond to global market requirements. In this paper, the technical implementations are disciplinarily categorized into managerial and automatic systems. Then, typical managerial and automatic implementations in a refinery are depicted to give an insight perception of the heterogeneous data sources manipulated by these systems. Finally, an integration approach based on data reconciliation techniques is proposed to link up the heterogeneous data sources.

  12. Effects of alumina refinery wastewater and signature metal constituents at the upper thermal tolerance of: 2. The early life stages of the coral Acropora tenuis

    International Nuclear Information System (INIS)

    Negri, Andrew P.; Harford, Andrew J.; Parry, David L.; Dam, Rick A. van

    2011-01-01

    Research highlights: →Methodology to assess relevant toxicants to sensitive early life histories of coral. → Explored the thermal sensitivity of fertilisation and larval metamorphosis in a coral. → First study to identify IC 50 s for Al, Ga and V in corals (at summer temperature). → First study to test the effects of an alumina outfall wastewater on coral. → Found additive effects of wastewater and high SST on fertilisation and metamorphosis. - Abstract: The success of early life history transitions of the coral Acropora tenuis were used as endpoints to evaluate thermal stress and the effects of wastewater discharged to a tropical marine environment. The studies assessed the effects of: (i) temperature; (ii) three signature metals of the wastewater, aluminium (Al), vanadium (V) and gallium (Ga); and (iii) the wastewater (at 27 o C and 32 o C) on fertilisation and larval metamorphosis. The median inhibition temperatures for fertilisation and metamorphosis were 32.8 o C and 33.0 o C, respectively. Fertilisation IC 50 s for Al, V and Ga were 2997, 2884 and 3430 μg L -1 , respectively. Metamorphosis IC 50 s for Al, V and Ga were 1945, 675 and 3566 μg L -1 , respectively. The wastewater only affected fertilisation and metamorphosis at moderate concentrations (IC 50 s = 63% and 67%, v/v, respectively, at 27 o C), posing a low risk to this species in the field. The effects of wastewater and temperature on fertilisation and metamorphosis were additive.

  13. Metallic Nanostructures Based on DNA Nanoshapes

    Directory of Open Access Journals (Sweden)

    Boxuan Shen

    2016-08-01

    Full Text Available Metallic nanostructures have inspired extensive research over several decades, particularly within the field of nanoelectronics and increasingly in plasmonics. Due to the limitations of conventional lithography methods, the development of bottom-up fabricated metallic nanostructures has become more and more in demand. The remarkable development of DNA-based nanostructures has provided many successful methods and realizations for these needs, such as chemical DNA metallization via seeding or ionization, as well as DNA-guided lithography and casting of metallic nanoparticles by DNA molds. These methods offer high resolution, versatility and throughput and could enable the fabrication of arbitrarily-shaped structures with a 10-nm feature size, thus bringing novel applications into view. In this review, we cover the evolution of DNA-based metallic nanostructures, starting from the metallized double-stranded DNA for electronics and progress to sophisticated plasmonic structures based on DNA origami objects.

  14. Metal detector technology data base

    Energy Technology Data Exchange (ETDEWEB)

    Porter, L.K.; Gallo, L.R.; Murray, D.W.

    1990-08-01

    The tests described in this report were conducted to obtain information on the effects target characteristics have on portal type metal detector response. A second purpose of the tests was to determine the effect of detector type and settings on the detection of the targets. Although in some cases comparison performance of different types and makes of metal detectors is found herein, that is not the primary purpose of the report. Further, because of the many variables that affect metal detector performance, the information presented can be used only in a general way. The results of these tests can show general trends in metal detection, but do little for making accurate predictions as to metal detector response to a target with a complex shape such as a handgun. The shape of an object and its specific metal content (both type and treatment) can have a significant influence on detection. Thus it should not be surprising that levels of detection for a small 100g stainless steel handgun are considerably different than for detection of the 100g stainless steel right circular cylinder that was used in these tests. 7 figs., 1 tab.

  15. Laser-based additive manufacturing of metals

    CSIR Research Space (South Africa)

    Kumar, S

    2010-11-01

    Full Text Available For making metallic products through Additive Manufacturing (AM) processes, laser-based systems play very significant roles. Laser-based processes such as Selective Laser Melting (SLM) and Laser Engineered Net Shaping (LENS) are dominating processes...

  16. Bioenergy, material, and nutrients recovery from household waste: Advanced material, substance, energy, and cost flow analysis of a waste refinery process

    International Nuclear Information System (INIS)

    Tonini, Davide; Dorini, Gianluca; Astrup, Thomas Fruergaard

    2014-01-01

    Highlights: • We modeled material, substance, energy, and cost flows of a waste refinery process. • Ca. 56% of 1 Mg dry waste input can be recovered as bioliquid yielding 6.2 GJ biogas. • Nutrients and carbon recovery in the bioliquid was estimated to 81–89%. • The biogenic carbon in the input waste was 63% of total carbon based on 14 C analyses. • The quality of the digestate may be critical with respect to use on land. - Abstract: Energy, materials, and resource recovery from mixed household waste may contribute to reductions in fossil fuel and resource consumption. For this purpose, legislation has been enforced to promote energy recovery and recycling. Potential solutions for separating biogenic and recyclable materials are offered by waste refineries where a bioliquid is produced from enzymatic treatment of mixed waste. In this study, potential flows of materials, energy, and substances within a waste refinery were investigated by combining sampling, analyses, and modeling. Existing material, substance, and energy flow analysis was further advanced by development of a mathematical optimization model for determination of the theoretical recovery potential. The results highlighted that the waste refinery may recover ca. 56% of the dry matter input as bioliquid, yielding 6.2 GJ biogas-energy. The potential for nitrogen, phosphorous, potassium, and biogenic carbon recovery was estimated to be between 81% and 89% of the input. Biogenic and fossil carbon in the mixed household waste input was determined to 63% and 37% of total carbon based on 14 C analyses. Additional recovery of metals and plastic was possible based on further process optimization. A challenge for the process may be digestate quality, as digestate may represent an emission pathway when applied on land. Considering the potential variability of local revenues for energy outputs, the costs for the waste refinery solution appeared comparable with alternatives such as direct incineration

  17. Retrofitting refinery and petrochemical plants

    Energy Technology Data Exchange (ETDEWEB)

    Kesler, M.G.

    1988-06-01

    This article focuses on process improvements as the best way to reduce plant energy use. The emphasis on process revamp is well justified, as an energy profile for a typical refinery shows. The diagram shows that 60% of the total heat losses are in water and air cooling. Most of this heat loss results from condensing and cooling in fractionators and recycle systems, intermediate product cooling, and condensing of turbine steam. These losses, of mostly low-level heat, are tied to the basic approach previously used for the process design of existing refineries. Despite the progress to date, there is growing evidence that these heat losses can be further reduced economically by about 20-30% in most refineries and petrochemical plants. One way to reduce the losses is to increase recovery of low-level heat by improved heat exchange, which has been the subject of most publications on plant energy conservation. A better way, presented here, is to develop new process schemes that require less air/water cooling. One useful concept in developing new schemes is to concentrate on heat losses, rather than heat input, as an easier measure of proposed improvements. By an overall heat balance, eliminating a unit of energy loss is equivalent to saving a unit of heat input somewhere in the plant.

  18. Joint refinery selenium treatability study

    International Nuclear Information System (INIS)

    Meyer, C.L.; Folwarkow, S.

    1993-01-01

    The San Francisco Regional Water Quality Control Board recently established mass limits on discharges of selenium to the San Francisco Bay from several petroleum refineries. The refineries had been working independently to develop control strategies, including both source control and treatment options, for removal of selenium from their discharges. By January 1992, over fifty different combinations of treatment technologies, wastewater streams, and pretreatment steps had been investigated to determine their effectiveness and feasibility as selenium removal processes. No treatment process studied could achieve the required mass limits without serious negative environmental consequences, such as generation of large amounts of hazardous sludge. To better facilitate the development of a feasible selenium treatment process, the six Bay Area refineries shared results of their studies and identified several technologies that, with further work, could be developed further. This additional work is currently being carried out as part of a joint selenium treatability study sponsored by the Western States Petroleum Association. A review of the previous source control and treatment studies, along with a description of the current treatability studies will be discussed

  19. Assessment of the effect of effluent discharge from coffee refineries ...

    African Journals Online (AJOL)

    The ecohydrological quality of water resource of Ethiopia is declining at an alarming rate, resulting in severe environmental degradation. This study finds out the effects of effluent discharge from intensive coffee refineries on river water quality based on physicochemical parameters and benthos assemblages as biological ...

  20. Model Based Metal Transfer Control

    DEFF Research Database (Denmark)

    Thomsen, Jesper Sandberg

    2006-01-01

    In pulsed gas metal arc welding (pulsed GMAW) current pulses are used for detaching drops at the tip of the electrode. To obtain a high weld quality one drop should be detached for every pulse, and moreover, the amount of energy used for detachment should be kept at a minimum. Thus, each pulse must...

  1. Superfund Record of Decision (EPA Region 2): Sinclair Refinery, Allegany County, Wellsville, NY. (Second remedial action), September 1991. Final report

    International Nuclear Information System (INIS)

    1991-01-01

    The Sinclair Refinery site is a former refinery in Wellsville, Allegany County, New York. The site is composed of a 90-acre refinery area, 10-acre landfill area, and 14-acre offsite tank farm. From 1901 to 1958, the site was used to process Pennsylvania grade crude oil until a fire in 1958 halted operations. Currently, some private companies and the State University of New York occupy the site. A 1981 site inspection revealed that debris from the eroding landfill area has washed into and contaminated the Genesee River. The ROD addresses OU2, remediation of the remaining contaminated areas at the site located within the 90-acre refinery area and the offsite tank farm including the contaminated ground water beneath the refinery. The primary contaminants of concern affecting the soil and ground water are VOCs including benzene and xylenes, semi-volatile compounds including naphthalene and nitrobenzene, and metals including arsenic and lead. The selected remedial action for the site is included

  2. The prospects for refinery profitability

    Energy Technology Data Exchange (ETDEWEB)

    Weale, G. [European Energy Services, London (United Kingdom)

    1997-05-01

    The outlook for the European refining industry is assessed. The conclusion reached is that the industry is struggling for its existence. Over time, an unsatisfactory balance has grown between refinery capacity and market volumes. High exit barriers have prevented capacity being considerably lower than it is. In the future, a typical integrated oil company might be content to confine itself to retailing oil products without having to refine them. Given the reduction in gasoline demand in particular, it can be expected that 20-25% of capacity will be sold off in the next 15 years and much of it will be closed. (Author)

  3. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    Science.gov (United States)

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  4. Bioremediation of petroleum refinery effluent by Planococcus ...

    African Journals Online (AJOL)

    In the present investigation, Planococcus halophilus was screened for hydrocarbon degradation and bioremediation of refinery effluent. The test organism, P. halophilus, showed the capability to utilize kerosene as carbon source in minimal medium. Biological treatment of the refinery effluent with P. halophilus reduced the ...

  5. Aspects of petrochemistry in a fuels refinery

    Energy Technology Data Exchange (ETDEWEB)

    Esser, J.; Mielicke, C.J.; Maier, T. [MIRO - Mineraloelraffinerie Oberrhein GmbH und Co. KG, Karlsruhe (Germany)

    2007-07-01

    Classical links between refinery and petrochemical downstream operations are light naphtha, C2-C4-Olefins and various aromatic compounds. Additionally long chain paraffines from dewaxing or even heavy residues can be interesting starting materials for petrochemistry. Some aspects of these links between refining and petrochemistry as well as their impact on refinery operation and product pools are discussed. (orig.)

  6. Thermodynamic data-base for metal fluorides

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Jae Hyung; Lee, Byung Gik; Kang, Young Ho and others

    2001-05-01

    This study is aimed at collecting useful data of thermodynamic properties of various metal fluorides. Many thermodynamic data for metal fluorides are needed for the effective development, but no report of data-base was published. Accordingly, the objective of this report is to rearrange systematically the existing thermodynamic data based on metal fluorides and is to use it as basic data for the development of pyrochemical process. The physicochemical properties of various metal fluorides and metals were collected from literature and such existing data base as HSC code, TAPP code, FACT code, JANAF table, NEA data-base, CRC handbook. As major contents of the thermodynamic data-base, the physicochemical properties such as formation energy, viscosity, density, vapor pressure, etc. were collected. Especially, some phase diagrams of eutectic molten fluorides are plotted and thermodynamic data of liquid metals are also compiled. In the future, the technical report is to be used as basic data for the development of the pyrochemical process which is being carried out as a long-term nuclear R and D project.

  7. Thermodynamic data-base for metal fluorides

    International Nuclear Information System (INIS)

    Yoo, Jae Hyung; Lee, Byung Gik; Kang, Young Ho and others

    2001-05-01

    This study is aimed at collecting useful data of thermodynamic properties of various metal fluorides. Many thermodynamic data for metal fluorides are needed for the effective development, but no report of data-base was published. Accordingly, the objective of this report is to rearrange systematically the existing thermodynamic data based on metal fluorides and is to use it as basic data for the development of pyrochemical process. The physicochemical properties of various metal fluorides and metals were collected from literature and such existing data base as HSC code, TAPP code, FACT code, JANAF table, NEA data-base, CRC handbook. As major contents of the thermodynamic data-base, the physicochemical properties such as formation energy, viscosity, density, vapor pressure, etc. were collected. Especially, some phase diagrams of eutectic molten fluorides are plotted and thermodynamic data of liquid metals are also compiled. In the future, the technical report is to be used as basic data for the development of the pyrochemical process which is being carried out as a long-term nuclear R and D project

  8. Treating refinery wastewaters in microbial fuel cells using separator electrode assembly or spaced electrode configurations

    KAUST Repository

    Zhang, Fang; Ahn, Yongtae; Logan, Bruce E.

    2014-01-01

    The effectiveness of refinery wastewater (RW) treatment using air-cathode, microbial fuel cells (MFCs) was examined relative to previous tests based on completely anaerobic microbial electrolysis cells (MECs). MFCs were configured with separator

  9. Allowance Allocation and CO2 intensity of the EU15 and Norwegian refineries

    International Nuclear Information System (INIS)

    Nilsson, Kristina; Zetterberg, Lars; Aahman, Markus

    2005-02-01

    On 1 January 2005, the European Union Emission Trading Scheme (EU ETS) was launched. The launch has been preceded by an allocation process in each of the Member States. The main objective of this study was to analyse the allocation in relation to CO 2 efficiency for the mineral oil refining sector. A CO 2 intensity index for mineral oil refineries has been defined and calculated for the refineries within the EU15 and Norway. The IVL CO 2 intensity index is based both on the Solomon Energy Intensity Index (EII), an assumed fuel mix, and process-specific emissions. Due to uncertainties in input data, the determined values for the individual refineries are quite uncertain. However, the regional values can be used to identify trends. It was concluded that there are substantial differences in the CO 2 intensity between refineries within different regions/countries in the EU and these differences have not been considered in the allocation process. Only a few countries have mentioned energy efficiency or reduction potential due to CO 2 intensity of fuels used. Only one country (Denmark) has explicitly given a benchmark that will be used for allocation to new mineral oil refineries. The allocation has generally been based on historic emissions, which will result in refineries with historically higher emissions being allocated larger amounts than refineries with historically lower emissions. This might be favourable for refineries that recently have performed emission-reducing measures but might be less favourable for refineries that during a long time period have implemented emission-reducing measures

  10. Allowance Allocation and CO{sub 2} intensity of the EU15 and Norwegian refineries

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Kristina; Zetterberg, Lars; Aahman, Markus

    2005-02-01

    On 1 January 2005, the European Union Emission Trading Scheme (EU ETS) was launched. The launch has been preceded by an allocation process in each of the Member States. The main objective of this study was to analyse the allocation in relation to CO{sub 2} efficiency for the mineral oil refining sector. A CO{sub 2} intensity index for mineral oil refineries has been defined and calculated for the refineries within the EU15 and Norway. The IVL CO{sub 2} intensity index is based both on the Solomon Energy Intensity Index (EII), an assumed fuel mix, and process-specific emissions. Due to uncertainties in input data, the determined values for the individual refineries are quite uncertain. However, the regional values can be used to identify trends. It was concluded that there are substantial differences in the CO{sub 2} intensity between refineries within different regions/countries in the EU and these differences have not been considered in the allocation process. Only a few countries have mentioned energy efficiency or reduction potential due to CO{sub 2} intensity of fuels used. Only one country (Denmark) has explicitly given a benchmark that will be used for allocation to new mineral oil refineries. The allocation has generally been based on historic emissions, which will result in refineries with historically higher emissions being allocated larger amounts than refineries with historically lower emissions. This might be favourable for refineries that recently have performed emission-reducing measures but might be less favourable for refineries that during a long time period have implemented emission-reducing measures.

  11. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    Energy Technology Data Exchange (ETDEWEB)

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

  12. Hazard evaluation of soil contaminants from an abandoned oil refinery site with chemical and biological assays

    International Nuclear Information System (INIS)

    Ramanathan, A.; Yates, C.W.; Burks, S.L.

    1993-01-01

    The phytotoxic characteristics of soil and leachates of soil from an abandoned oil refinery site were evaluated with rice (Oryza sativa L.) seed germinations and root elongation assays. Toxicity of soil leachates to aquatic animals was determined with acute and martial chronic toxicity tests with Ceriodaphnia dubia, fathead minnows, and Microtox reg-sign. Soil samples from uncontaminated (control) and selected contaminated areas within the old refinery were extracted with Toxic Characteristics Leachate Procedure (TCLP), an aqueous procedure and a supercritical carbon dioxide method. Aqueous extracts of soil from the oil leaded gasoline storage area exhibited greatest effects in all tests. Aqueous extracts from this site also caused a significant reduction in rice root development. Supercritical carbon dioxide extraction proved to be a quick and non-toxic procedure for isolating non-polar organics for assay with aquatic toxicity tests. Subsequent supercritical extracts collected in solvent can help characterize the class of toxicants through HPLC and Gas Chromatography. The toxic constituents were characterized with a Toxicity Identification/Toxicity Reduction Evaluation protocol to fractionate the contaminants into conventional non-polar organics, weak acids, base-neutrals, or heavy metals for subsequent analysis

  13. Energy saving in refineries and petrochemical complexes

    Energy Technology Data Exchange (ETDEWEB)

    Verde, L

    1975-01-01

    Possible measures applicable in the design of refineries and petrochemical complexes, to effect energy savings were investigated. This was not limited to the single process unit problems, on the contrary the attention is mainly addressed to the identification of the interrelations between different units, emphasizing possible integrations. Particularly, the optimization of the pressure levels and number of the utility networks for steam distribution inside plant facilities, is considered, in order to maximize heat recovery in the process units, and electric power production in the central steampower generation plant. A computer program of general application, based on profitability evaluation at various fuel oil prices and different project configurations, has been developed for these purposes. The general measures applicable within certain limits are then briefly examined. The task of the process engineer is discussed in the perspective of the ''energy saving'' goal.

  14. Precious-metal-base advanced materials

    International Nuclear Information System (INIS)

    Nowicki, T.; Carbonnaux, C.

    1993-01-01

    Precious metals constitute also the base of several advanced materials used in the industry in hundreds of metric tons. Platinum alloys have been used as structural materials for equipments in the glass industry. The essential reason for this is the excellent resistance of platinum alloys to oxidation and electrolytical corrosion in molten glasses at temperatures as high as 1200-1500 C. The major drawback is a weak creep resistance. The unique way for significant improvement of platinum base materials creep resistance is a strengthening by an oxide dispersion (ODS). In the case of CLAL's patented ''Plativer'' materials, 0.05 wt% of Y 2 O 3 is incorporated within the alloy matrix by the flame spraying process. Further improvement of platinum base materials is related, in the authors opinion, to the development of precious metals base intermetallics. Another interesting applications of precious metals are silver base electrical contacts. They are in fact silver matrix composites containing varying amounts of well-dispersed particles of constituents such as CdO, SnO 2 , Ni, WC or C. In the case of such materials, particular properties are required and tested : resistance to arc erosion, resistance to welding and contact resistance. Many other technically fascinating precious metals base materials exist: brazing alloys for assembling metals, superconductors and ceramics; dental materials including magnetic biocompatible alloys; silver composites for superconductor wire jackets. The observation of current evolution indicates very clearly that precious metals cannot be replaced by common metals because of their unique characteristics due to their atomic level properties

  15. Base Metal Co-Fired Multilayer Piezoelectrics

    Directory of Open Access Journals (Sweden)

    Lisheng Gao

    2016-03-01

    Full Text Available Piezoelectrics have been widely used in different kinds of applications, from the automobile industry to consumer electronics. The novel multilayer piezoelectrics, which are inspired by multilayer ceramic capacitors, not only minimize the size of the functional parts, but also maximize energy efficiency. Development of multilayer piezoelectric devices is at a significant crossroads on the way to achieving low costs, high efficiency, and excellent reliability. Concerning the costs of manufacturing multilayer piezoelectrics, the trend is to replace the costly noble metal internal electrodes with base metal materials. This paper discusses the materials development of metal co-firing and the progress of integrating current base metal chemistries. There are some significant considerations in metal co-firing multilayer piezoelectrics: retaining stoichiometry with volatile Pb and alkaline elements in ceramics, the selection of appropriate sintering agents to lower the sintering temperature with minimum impact on piezoelectric performance, and designing effective binder formulation for low pO2 burnout to prevent oxidation of Ni and Cu base metal.

  16. Base metals in the new economic environment

    International Nuclear Information System (INIS)

    Lennon, J.

    2002-01-01

    The focus of this paper was on the demand side of the base metals industry. It is expected that in the next decade more than 50 per cent of global demand growth will come from China and other countries of the former Eastern block. Following the large decline in base metals demand in 2001, it is expected that a large growth in metals supply will be needed over the next decade and there is a real possibility that the mining industry will struggle to meet demand growth. While industry performance is usually driven by economic growth and its impact on metals demand, analysts realize that every cycle is different and it can be easily affected by unpredicted, economic and geopolitical events. The author suggests that the while next few years will be a period of slower growth in the traditional consuming countries, this will be offset by the significant rise in the importance of China and the possible resurgence in demand growth in the Former Soviet Union and Eastern Europe. The paper presented a brief historical overview of the different growth phases for metals over the past 50 years. Strong metal demand in the 1990s was driven by the telecommunications and computer revolutions. Stainless steel/nickel, zinc/galvanized applications and aluminium were used to save on maintenance costs and to improve energy efficiency. The paper also discussed the shifting pattern of copper and aluminium demand by decade. 2 tabs., 7 figs

  17. Separation and Molecular Identification of Resistant Bacteria to Lead from Behbahan Bidboland Gas Refinery Wastewater (Iran)

    OpenAIRE

    Azam Mehrbakhsh; Monir Doudi; Hossein Motamedi

    2016-01-01

    Heavy metals are one of the pollution sources in environment. The pollution due to these metals is the problem that could have negative impact on water. Human is faced with these poisons effects due to occupational reasons. The lead is regarded as heavy metal whose industrial applications cause environmental pollution in high rate.The aim of this project was Separation and Molecular Identification of Resistant Bacteria to Lead from Behbahan Bidboland Gas Refinery Wastewater (Iran). For thi...

  18. Analysis of standard and innovative methods for allocating upstream and refinery GHG emissions to oil products

    International Nuclear Information System (INIS)

    Moretti, Christian; Moro, Alberto; Edwards, Robert; Rocco, Matteo Vincenzo; Colombo, Emanuela

    2017-01-01

    Highlights: •Traditional and innovative methods for allocating emissions at refinery level are reviewed. •Added value has been introduced as a novel allocation method. •Hydrogen-based consistency test has been introduced to validate the allocation methods. •Consistent allocation methods assign negative refinery emissions to heavy products. -- Abstract: Alternative fuel policies need accurate and transparent methods to find the embedded carbon intensity of individual refinery products. This study investigates different ways of allocating greenhouse gases emissions deriving from refining and upstream crude oil supply. Allocation methods based on mass, energy content, economic value and, innovatively, added-value, are compared with the marginal refining emissions calculated by CONCAWE’s linear-programming model to the average EU refinery, which has been adopted as reference in EU legislation. Beside the most important transportation fuels (gasoline, diesel, kerosene/jet fuel and heavy fuel oil), the analysis extends to petroleum coke and refinery hydrogen. Moreover, novel criteria, based on the implications due to hydrogen usage by each fuel pathway, have been introduced to test the consistency of the analyzed approaches. It is found that only two economic-based allocation methods are consistent with the introduced criteria. These two methods also give negative refinery emissions for heavy products, which is coherent with the marginal emissions calculated through the CONCAWE refinery model. The recommended allocation methods are transparent and use only publicly available statistical data, so they may be useful not only for future EU legislation, but also in jurisdictions where a representative refinery model is not available.

  19. Former Soviet refineries face modernization, restructuring

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans

  20. Pt-based Bi-metallic Monolith Catalysts for Partial Upgrading of Microalgae Oil

    Energy Technology Data Exchange (ETDEWEB)

    Lawal, Adeniyi [Stevens Inst. of Technology, Hoboken, NJ (United States); Manganaro, James [Anasyn LLC, Princeton, NJ (United States); Goodall, Brian [Valicor Renewables LLC, Dexter, MI (United States); Farrauto, Robert [Columbia Univ., New York, NY (United States)

    2015-03-24

    Valicor’s proprietary wet extraction process in conjunction with thermochemical pre-treatment was performed on algal biomass from two different algae strains, Nannochloropsis Salina (N.S.) and Chlorella to produce algae oils. Polar lipids such as phospholipids were hydrolyzed, and metals and metalloids, known catalyst poisons, were separated into the aqueous phase, creating an attractive “pre-refined” oil for hydrodeoxygenation (HDO) upgrading by Stevens. Oil content and oil extraction efficiency of approximately 30 and 90% respectively were achieved. At Stevens, we formulated a Pt-based bi-metallic catalyst which was demonstrated to be effective in the hydro-treating of the algae oils to produce ‘green’ diesel. The bi-metallic catalyst was wash-coated on a monolith, and in conjunction with a high throughput high pressure (pilot plant) reactor system, was used in hydrotreating algae oils from N.S. and Chlorella. Mixtures of these algae oils and refinery light atmospheric gas oil (LAGO) supplied by our petroleum refiner partner, Marathon Petroleum Corporation, were co-processed in the pilot plant reactor system using the Pt-based bi-metallic monolith catalyst. A 26 wt% N.S. algae oil/74 wt % LAGO mixture hydrotreated in the reactor system was subjected to the ASTM D975 Diesel Fuel Specification Test and it met all the important requirements, including a cetane index of 50.5. An elemental oxygen analysis performed by an independent and reputable lab reported an oxygen content of trace to none found. The successful co-processing of a mixture of algae oil and LAGO will enable integration of algae oil as a refinery feedstock which is one of the goals of DOE-BETO. We have presented experimental data that show that our precious metal-based catalysts consume less hydrogen than the conventional hydrotreating catalyst NiMo Precious metal catalysts favor the hydrodecarbonylation/hydrodecarboxylation route of HDO over the dehydration route preferred by base metal

  1. Inefficiency of Malaysian palm oil refineries and the impact of different factors on its inefficiency

    Directory of Open Access Journals (Sweden)

    Zahra Shahverdi

    2015-09-01

    Full Text Available This study aimed to analyze changes in the inefficiency of Malaysian palm oil refineries using DEA window analysis method over the period 1996 to 2009. We investigated the effects of different factors on inefficiency of Malaysian palm oil refineries. Based on empirical results, the effect of all factors such as vertical integration, types of ownership, foreign investment, location, experience, and liberalization on inefficiency of refineries was significant. Experience, liberalization, and joint venture between private and public sectors showed an increase in efficiency, while joint venture between local and foreign investment and vertical integration increased refineries’ inefficiency. However, palm oil refineries which were located in the states of Sabah and Sarawak were less technically inefficient than those located in peninsular Malaysia.

  2. Treatment of petroleum refinery wastewater using a sequential anaerobic-aerobic moving-bed biofilm reactor system based on suspended ceramsite.

    Science.gov (United States)

    Lu, Mang; Gu, Li-Peng; Xu, Wen-Hao

    2013-01-01

    In this study, a novel suspended ceramsite was prepared, which has high strength, optimum density (close to water), and high porosity. The ceramsite was used to feed a moving-bed biofilm reactor (MBBR) system with an anaerobic-aerobic (A/O) arrangement to treat petroleum refinery wastewater for simultaneous removal of chemical oxygen demand (COD) and ammonium. The hydraulic retention time (HRT) of the anaerobic-aerobic MBBR system was varied from 72 to 18 h. The anaerobic-aerobic system had a strong tolerance to shock loading. Compared with the professional emission standard of China, the effluent concentrations of COD and NH3-N in the system could satisfy grade I at HRTs of 72 and 36 h, and grade II at HRT of 18 h. The average sludge yield of the anaerobic reactor was estimated to be 0.0575 g suspended solid/g CODremoved. This work demonstrated that the anaerobic-aerobic MBBR system using the suspended ceramsite as bio-carrier could be applied to achieving high wastewater treatment efficiency.

  3. Green ultrasound-assisted extraction of carotenoids based on the bio-refinery concept using sunflower oil as an alternative solvent.

    Science.gov (United States)

    Li, Ying; Fabiano-Tixier, Anne Sylvie; Tomao, Valérie; Cravotto, Giancarlo; Chemat, Farid

    2013-01-01

    A green, inexpensive and easy-to-use method for carotenoids extraction from fresh carrots assisted by ultrasound was designed in this work. Sunflower oil was applied as a substitute to organic solvents in this green ultrasound-assisted extraction (UAE): a process which is in line with green extraction and bio-refinery concepts. The processing procedure of this original UAE was first compared with conventional solvent extraction (CSE) using hexane as solvent. Moreover, the UAE optimal conditions for the subsequent comparison were optimized using response surface methodology (RSM) and ultra performance liquid chromatography--diode array detector--mass spectroscopy (UPLC-DAD-MS). The results showed that the UAE using sunflower as solvent has obtained its highest β-carotene yield (334.75 mg/l) in 20 min only, while CSE using hexane as solvent obtained a similar yield (321.35 mg/l) in 60 min. The green UAE performed under optimal extraction conditions (carrot to oil ratio of 2:10, ultrasonic intensity of 22.5 W cm(-2), temperature of 40 °C and sonication time of 20 min) gave the best yield of β-carotene. Copyright © 2012 Elsevier B.V. All rights reserved.

  4. Thulium-based bulk metallic glass

    International Nuclear Information System (INIS)

    Yu, H. B.; Yu, P.; Wang, W. H.; Bai, H. Y.

    2008-01-01

    We report the formation and properties of a thulium-based bulk metallic glass (BMG). Compared with other known rare-earth (RE) based BMGs, Tm-based BMGs show features of excellent glass formation ability, considerable higher elastic modulus, smaller Poisson's ratio, high mechanical strength, and intrinsic brittleness. The reasons for the different properties between the Tm-based and other RE-based BMGs are discussed. It is expected that the Tm-based glasses with the unique properties are appropriate candidates for studying some important issues in BMGs

  5. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

    2016-04-25

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

  6. Mazeikiai refinery woes deepen on all fronts

    Index Scriptorium Estoniae

    2007-01-01

    Leedu rahandusminister teatas, et riigieelarvet mõjutavad probleemid Mazeikiai tehasega, mis on Leedu suurim maksumaksja. Lisa: Russian oil company to build refinery. Surgutneftegaz teatas plaanist ehitada naftatöötlustehas Peterburi lähedale

  7. Refinery siting workbook: appendices A and B

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  8. The refinery industry within the Mediterranean area

    International Nuclear Information System (INIS)

    1999-01-01

    During the period 1997-1998 Ome (Observatorie Mediterraneen de l'Energie) within a working group which was formed by the experts among the associated companies, has carried on an analysis on the prospects of refinery industry in the Mediterranean area in view of 2010. The aim of this study was to make clear, to the different operators, the consequences of the political choices in investments on refinery industry in the context of the progressive liberalization of the sector [it

  9. Improving profitability in a grassroots refinery

    Energy Technology Data Exchange (ETDEWEB)

    Coombs, T. [Star Petroleum Refining Co. Ltd. (Thailand); Kennedy, P.; Bhargava, S. [KBC Process Technology Ltd. (United Kingdom)

    1999-05-01

    Actions taken to maximise profit at the Star Refinery in Thailand are described. The company made good use of the Profit Improvement Programme (PIP) (which specialises in refinery economics) and the way in which PIP addressed the problem and the benefits derived therefrom is the nub of this paper. The efforts appear to have been more than satisfactory from the aspect of increasing profit margins. (UK)

  10. Current situation of oil refinery in Bulgaria

    Science.gov (United States)

    Vershkova, Elena; Petkova, Petinka; Grinkevich, Anastasia

    2016-09-01

    This article deals with the classification approach for oil refineries in international practices. Criteria of refinery estimation group, including its financial status estimation, have been investigated. The analysis object is “Lukoil Neftochim Bourgas” AD (LNCHB) activity. This company is a leading enterprise in Bulgaria. The analysis of LNCHB operating: energy intensity index; index of operating costs and return on investment index have been performed.

  11. The rise and fall of refineries

    International Nuclear Information System (INIS)

    Chretien, D.

    2002-01-01

    This paper described the rise and fall of refineries in Montreal. Well before Calgary, Montreal was the hub of activity for oil refineries because Montreal was the principle consuming market for petroleum products in Canada. The location was good, particularly since the soil was clay which helped prevent soil infiltration of petroleum. The first refinery in Montreal was constructed in 1916 by Esso, followed by Texaco in 1921 and Gulf in 1931. Initially oil was shipped by boat to the Port of Montreal from Saudi Arabia. Later, the petroleum came mostly from Venezuela. At the beginning of the 1980s many refineries were closed because they became obsolete and upgrading them would have been too costly. Only 3 refineries remain in Quebec, of which 2 are in Montreal. They are owned by Shell and PetroCanada. The third refinery in Quebec is in St-Romuald and is owned by UltraMar. One of the major contributing factors to the decline of the refining industry in Montreal was the decision in 1984 by former Prime Minister Trudeau to force Canadian provinces to purchase their petroleum from Alberta. This caused the petrochemical industry to locate in Sarnia in Ontario, leaving the Montreal refining centre to become obsolete. 3 figs

  12. Chemoelectronic circuits based on metal nanoparticles

    Science.gov (United States)

    Yan, Yong; Warren, Scott C.; Fuller, Patrick; Grzybowski, Bartosz A.

    2016-07-01

    To develop electronic devices with novel functionalities and applications, various non-silicon-based materials are currently being explored. Nanoparticles have unique characteristics due to their small size, which can impart functions that are distinct from those of their bulk counterparts. The use of semiconductor nanoparticles has already led to improvements in the efficiency of solar cells, the processability of transistors and the sensitivity of photodetectors, and the optical and catalytic properties of metal nanoparticles have led to similar advances in plasmonics and energy conversion. However, metals screen electric fields and this has, so far, prevented their use in the design of all-metal nanoparticle circuitry. Here, we show that simple electronic circuits can be made exclusively from metal nanoparticles functionalized with charged organic ligands. In these materials, electronic currents are controlled by the ionic gradients of mobile counterions surrounding the ‘jammed’ nanoparticles. The nanoparticle-based electronic elements of the circuitry can be interfaced with metal nanoparticles capable of sensing various environmental changes (humidity, gas, the presence of various cations), creating electronic devices in which metal nanoparticles sense, process and ultimately report chemical signals. Because the constituent nanoparticles combine electronic and chemical sensing functions, we term these systems ‘chemoelectronic’. The circuits have switching times comparable to those of polymer electronics, selectively transduce parts-per-trillion chemical changes into electrical signals, perform logic operations, consume little power (on the scale of microwatts), and are mechanically flexible. They are also ‘green’, in the sense that they comprise non-toxic nanoparticles cast at room temperature from alcohol solutions.

  13. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    Energy Technology Data Exchange (ETDEWEB)

    Goldberg, Marshall [MRG and Associates, Nevada City, CA (United States)

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  14. Catalytic hydrotreatment of refinery waste

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The object of the project is to produce liquid hydrocarbons by the catalytic hydroprocessing of solid refinery wastes (hard pitches) in order to improve the profitability of deep conversion processes and reduce the excess production of heavy fuels. The project was mostly carried out on the ASVAHL demonstration platform site, at Solaize, and hard pitches were produced primarily by deasphalting of atmospheric or vacuum distillation residues. The project includes two experimental phases and an economic evaluation study phase. In phase 1, two granular catalysts were used to transform pitch into standard low sulphur fuel oil: a continuously moving bed, with demetallation and conversion catalyst; a fixed bed, with hydrorefining catalyst. In phase 2 of the project, it was proven that a hydrotreatment process using a finely dispersed catalyst in the feedstock, can, under realistic operating conditions, transform with goods yields hard pitch into distillates that can be refined through standard methods. In phase 3 of the project, it was shown that the economics of such processes are tightly linked to the price differential between white and black oil products, which is expected to increase in the future. Furthermore, the evolution of environmental constraints will impel the use of such methods, thus avoiding the coproduction of polluting solid residues.

  15. Bioremediation at a petroleum refinery

    International Nuclear Information System (INIS)

    Carson, A.W.; Jarvis, J.; Richardson, K.E.

    1994-01-01

    This paper presents a summary of three projects at the Mobil Refinery in Torrance, California where bioremediation technologies were successfully employed for the remediation of hydrocarbon contaminated soil. The three projects represent variations of implementation of bioremediation, both in-situ and ex-situ. Soil from all of the projects was considered non-hazardous designated waste under the California Code of Regulations, Title 23, section 2522. The projects were permitted and cleanup requirements were defined with the Los Angeles Regional Water Quality Control Board. In all of the projects, different methods were used for supplying water, oxygen, and nutrients to the hydrocarbon degrading bacteria to stimulate growth. The Stormwater Retention Basin Project utilized in-situ mechanical mixing of soils to supply solid nutrients and oxygen, and a self-propelled irrigation system to supply water. The Tank Farm Lake project used an in-situ active bioventing technology to introduce oxygen, moisture, and vapor phase nutrients. The Tank 1340X247 project was an ex-situ bioventing remediation project using a drip irrigation system to supply water and dissolved nutrients, and a vapor extraction system to provide oxygen

  16. Refinery boom in Southeast Asia

    International Nuclear Information System (INIS)

    Gruson, J.F.; Virondaud, C.

    1996-01-01

    The Asia demand for oil is increasing dramatically, particularly in the non OECD countries, which represent, today more than 15 % of the world oil market. The expected economic growth in these areas should contribute to a rise in oil demand by about 5.4 per year and hence to a significant increase of this share to 25 % in 2010; virtually a large part of this evolution will come from the transportation sector. The proceeding investments of the regional, refining industry are very high (some evaluations come to around 140 billion of dollars), all the more the protection of the environment takes an increasing significant place. Accordingly the most important challenge to be taken up by these countries will be to mobilize long term fundings to develop and adapt the capabilities of the refineries to meet the growth of gasoline and gas oil demand. The contribution of private operators or capital will be necessary, but will depend strongly on refining margin improvement and on progress of free market areas announced by several countries. (authors)

  17. Advanced purification of petroleum refinery wastewater by catalytic vacuum distillation.

    Science.gov (United States)

    Yan, Long; Ma, Hongzhu; Wang, Bo; Mao, Wei; Chen, Yashao

    2010-06-15

    In our work, a new process, catalytic vacuum distillation (CVD) was utilized for purification of petroleum refinery wastewater that was characteristic of high chemical oxygen demand (COD) and salinity. Moreover, various common promoters, like FeCl(3), kaolin, H(2)SO(4) and NaOH were investigated to improve the purification efficiency of CVD. Here, the purification efficiency was estimated by COD testing, electrolytic conductivity, UV-vis spectrum, gas chromatography-mass spectrometry (GC-MS) and pH value. The results showed that NaOH promoted CVD displayed higher efficiency in purification of refinery wastewater than other systems, where the pellucid effluents with low salinity and high COD removal efficiency (99%) were obtained after treatment, and the corresponding pH values of effluents varied from 7 to 9. Furthermore, environment estimation was also tested and the results showed that the effluent had no influence on plant growth. Thus, based on satisfied removal efficiency of COD and salinity achieved simultaneously, NaOH promoted CVD process is an effective approach to purify petroleum refinery wastewater. Copyright 2010 Elsevier B.V. All rights reserved.

  18. Economics and the refinery's CO2 emissions allocation problem

    International Nuclear Information System (INIS)

    Pierru, A.

    2007-01-01

    The establishment of a market for CO 2 emission rights in Europe leads oil-refining companies to add a cost associated with carbon emissions to the objective function of linear programming models used to manage refineries. These models may be used to compute the marginal contribution of each finished product to the CO 2 emissions of the refinery. Babusiaux (Oil. Gas Sci. Technol., 58, 2003, 685-692) has shown that, under some conditions, this marginal contribution is a relevant means of allocating the carbon emissions of the refinery. Thus, it can be used in a well-to-wheel Life Cycle Assessment. In fact, this result holds if the demand equations are the only binding constraints with a non-zero right-hand side coefficient. This is not the case for short-run models with fixed capacity. Then, allocating CO 2 emissions on a marginal basis tends to over-value (or undervalue) the total volume of emissions. In order to extend the existing methodology, we discuss two distinct solutions to this problem, inspired by economic theory: adapting either the Aumann-Shapley cost sharing method (Values of non-atomic games, 1974, Princeton University Press) or the Ramsey pricing formula (Econ. J., 37, 1927, 47-61; J. Econ. Theory, 3, 1971, 219-240). We compare these two solutions, with a strong argument in favour of Ramsey prices, based on the determination of the optimal environmental tax rate to which imported finished products should be subject. (author)

  19. Assessment of accidental refinery wastewater discharge: a case study

    Energy Technology Data Exchange (ETDEWEB)

    Bandyopadhyay, Amitava [University of Calcutta, Department of Chemical Engineering, Kolkata (India)

    2011-04-15

    The physicochemical qualities of an accidental discharge of refinery liquid waste, water, and soil sediment of that effluent-receiving water body (canal) were investigated. Analyses of the discharge, qualities of water, and sediment of the canal showed high parametric concentrations. Investigations revealed that the discharge took place form the spent caustic that was generated from the caustic wash tower of Fluidized Catalytic Cracker of the refinery. A simple but realistic model was suggested for the remediation of sediments of the canal with an estimated cost of about US $1.86 million. Recommendations were made to prevent such discharges and to revise thoroughly the Indian effluent discharge standards in force for petroleum oil refinery. Subsequently, revised standards were notified under Indian guidelines. Interestingly, cyanide besides many other parameters was introduced into these standards. Furthermore, Volatile Organic Compound (VOC) was also stipulated as an emission parameter from the waste water treatment plants. Concentration- and mass-based standards thus promulgated were stricter than the existing standards. (orig.)

  20. Utilization of the BR-SIPP systems (Integrated Refinery Scheduling System) at the PETROBRAS Capuava refinery; Utilizacao do sistema BR-SIPP - Sistema Integrado de Programacao de Producao PETROBRAS na refinaria de Capuava

    Energy Technology Data Exchange (ETDEWEB)

    Joly, Marcel [PETROBRAS, Maua, SP (Brazil). Refinaria de Capuava (RECAP). Gerencia de Otimizacao]. E-mail: joly@petrobras.com.br; Hassimotto, Marcelo Kenji [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Solucoes de Negocios de Logistica e Planejamento]. E-mail: kenji@petrobras.com.br; Magalhaes, Marcus Vinicius de Oliveira [PETROBRAS, Rio de Janeiro, RJ (Brazil). Gerencia de Otimizacao]. E-mail: vinicius@petrobras.com.br

    2007-04-15

    The BR-SIPP is a production scheduling decision support tool for refineries. It is integrated into the Corporate Inventory, Movements and Quality Data Base and is based on events simulation technology for the elaboration and analysis of scheduling scenarios. Its utilization at the Capuava Refinery allows the production programming team to analyze and anticipate difficulties and opportunities, thereby being able to make viable a potential integration of management and people directly involved with the refinery scheduling information, such as planning, logistics and commercial areas. (author)

  1. Pursuing the pre-combustion CCS route in oil refineries – The impact on fired heaters

    International Nuclear Information System (INIS)

    Weydahl, Torleif; Jamaluddin, Jamal; Seljeskog, Morten; Anantharaman, Rahul

    2013-01-01

    Highlights: ► The aim is to approach Carbon Capture and Storage (CCS) to refinery fired heaters. ► An identical simplified burner configuration is applied where refinery fuel is replaced with hydrogen. ► Initial simulations indicate that hydrogen replacement do not alter heater operation in a negative way. ► Despite the higher flame temperature in the hydrogen case, the NO x emissions are not higher. ► The prompt-NO mechanism contributes significantly in the refinery fuel case. -- Abstract: The work presented in this paper investigates the effect of replacing refinery fuel gas in the radiant section burners of a fired heater with hydrogen. The aim is to approach pre-combustion CCS to refinery fired heaters by identifying the impact on heat-, flow- and radiation distribution in the lower radiant section of the fired heater when simply switching refinery gas with hydrogen at equivalent power using the same burner geometrics. Additionally the formation of NO x is considered. The investigations are performed using a conventional Reynolds Average Navier Stokes (RANS), Computational Fluid Dynamics (CFD) approach using detailed reaction kinetics consisting of 325 elementary reactions and 53 species. Simplified and generalized furnace and burner geometries are used in the present work. The results show that approximately the same average wall heat flux density is achieved when the refinery fuel is replaced by hydrogen. However, the distribution of heat on the inner surfaces changes. The hydrogen case has, as expected, a higher flame temperature than the base case, nevertheless, the nitric oxide (NO x ) emissions are comparable to base case emissions. Several indications point in the direction of a significant contribution to the base case emissions from the less temperature dependent prompt-NO mechanism, which obviously is not contributing to the hydrogen case emissions.

  2. Computational chemistry and metal-based radiopharmaceuticals

    International Nuclear Information System (INIS)

    Neves, M.; Fausto, R.

    1998-01-01

    Computer-assisted techniques have found extensive use in the design of organic pharmaceuticals but have not been widely applied on metal complexes, particularly on radiopharmaceuticals. Some examples of computer generated structures of complexes of In, Ga and Tc with N, S, O and P donor ligands are referred. Besides parameters directly related with molecular geometries, molecular properties of the predicted structures, as ionic charges or dipole moments, are considered to be related with biodistribution studies. The structure of a series of oxo neutral Tc-biguanide complexes are predicted by molecular mechanics calculations, and their interactions with water molecules or peptide chains correlated with experimental data of partition coefficients and percentage of human protein binding. The results stress the interest of using molecular modelling to predict molecular properties of metal-based radiopharmaceuticals, which can be successfully correlated with results of in vitro studies. (author)

  3. Monitoring coastal pollution associated with the largest oil refinery complex of Venezuela

    Directory of Open Access Journals (Sweden)

    Aldo Croquer

    2016-06-01

    Full Text Available This study evaluated pollution levels in water and sediments of Península de Paraguaná and related these levels with benthic macrofauna along a coastal area where the largest Venezuelan oil refineries have operated over the past 60 years. For this, the concentration of heavy metals, of hydrocarbon compounds and the community structure of the macrobenthos were examined at 20 sites distributed along 40 km of coastline for six consecutive years, which included windy and calm seasons. The spatial variability of organic and inorganic compounds showed considerably high coastal pollution along the study area, across both years and seasons. The southern sites, closest to the refineries, had consistently higher concentrations of heavy metals and organic compounds in water and sediments when compared to those in the north. The benthic community was dominated by polychaetes at all sites, seasons and years, and their abundance and distribution were significantly correlated with physical and chemical characteristics of the sediments. Sites close to the oil refineries were consistently dominated by families known to tolerate xenobiotics, such as Capitellidae and Spionidae. The results from this study highlight the importance of continuing long-term environmental monitoring programs to assess the impact of effluent discharge and spill events from the oil refineries that operate in the western coast of Paraguaná, Venezuela.

  4. Eldorado Port Hope refinery - uranium production (1933-1951)

    International Nuclear Information System (INIS)

    Arsenault, J.E.

    2008-01-01

    Since the discovery of pitchblende in 1930 by Gilbert LaBine at Great Bear Lake (GBL), North West Territories, uranium has played a central role in the growth of the Canadian mining sector and it in turn has propelled the country into it's present position as the world's top uranium producer. The rich ore mined there was used originally by Eldorado Gold Mines Limited to build a business based on the extraction of radium, which was selling at $70,000 a gram at the time, and silver which was present in the ore in commercial amounts. The mine site on GBL became known as Port Radium. In 1933 Eldorado brought a refinery on-line at Port Hope, Ontario nearly 4,000 miles away from the mine, and began to produce radium, silver and uranium products. Initially uranium played a minor role in the business and the products were sold into the ceramics industry to manufacture a variety of crockery with long-lasting colours. In addition, there were sales and loans of uranium products to research laboratories that were exploring nuclear energy for possible use in weapons and power generation, as the potential for this was clearly understood from 1939 onwards. These laboratories included the National Research Council (George Laurence), Columbia University (Enrico Fermi) and International Chemical Industries (J.P. Baxter). With the beginning of World War II the radium business suffered from poor sales and by 1940 the mine was closed but the refinery continued operation, using accumulated stockpiles. By 1942 uranium had become a strategic material, the mine was reopened, and the refinery began to produce large quantities of uranium oxide destined for The Manhattan Project. As events unfolded Eldorado was unable to produce sufficient ore from GBL so that a large quantity of ore from the Belgian Congo was also processed at Port Hope. Ultimately, as a result of the efforts of this enterprise, World War II was finally ended by use of atomic weapons. After World War II the refinery

  5. Eldorado Port Hope refinery - uranium production (1933-1951)

    Energy Technology Data Exchange (ETDEWEB)

    Arsenault, J.E

    2008-03-15

    Since the discovery of pitchblende in 1930 by Gilbert LaBine at Great Bear Lake (GBL), North West Territories, uranium has played a central role in the growth of the Canadian mining sector and it in turn has propelled the country into it's present position as the world's top uranium producer. The rich ore mined there was used originally by Eldorado Gold Mines Limited to build a business based on the extraction of radium, which was selling at $70,000 a gram at the time, and silver which was present in the ore in commercial amounts. The mine site on GBL became known as Port Radium. In 1933 Eldorado brought a refinery on-line at Port Hope, Ontario nearly 4,000 miles away from the mine, and began to produce radium, silver and uranium products. Initially uranium played a minor role in the business and the products were sold into the ceramics industry to manufacture a variety of crockery with long-lasting colours. In addition, there were sales and loans of uranium products to research laboratories that were exploring nuclear energy for possible use in weapons and power generation, as the potential for this was clearly understood from 1939 onwards. These laboratories included the National Research Council (George Laurence), Columbia University (Enrico Fermi) and International Chemical Industries (J.P. Baxter). With the beginning of World War II the radium business suffered from poor sales and by 1940 the mine was closed but the refinery continued operation, using accumulated stockpiles. By 1942 uranium had become a strategic material, the mine was reopened, and the refinery began to produce large quantities of uranium oxide destined for The Manhattan Project. As events unfolded Eldorado was unable to produce sufficient ore from GBL so that a large quantity of ore from the Belgian Congo was also processed at Port Hope. Ultimately, as a result of the efforts of this enterprise, World War II was finally ended by use of atomic weapons. After World War II the

  6. Benzene exposure in a Japanese petroleum refinery.

    Science.gov (United States)

    Kawai, T; Yamaoka, K; Uchida, Y; Ikeda, M

    1990-07-01

    Time-weighted average (TWA) intensity of exposure of workers to benzene vapor during a shift was monitored by diffusive sampling technique in a Japanese petroleum refinery. The subjects monitored (83 in total) included refinery operators, laboratory personnel and tanker-loading workers. The results showed that the time-weighted average exposures are well below 1 ppm in most cases. The highest exposure was recorded in 1 case involved in bulk loading of tanker ships, in which exposure of over 1 ppm might take place depending on operational conditions. The observation was generally in agreement with levels previously reported.

  7. Base metal dehydrogenation of amine-boranes

    Science.gov (United States)

    Blacquiere, Johanna Marie [Ottawa, CA; Keaton, Richard Jeffrey [Pearland, TX; Baker, Ralph Thomas [Los Alamos, NM

    2009-06-09

    A method of dehydrogenating an amine-borane having the formula R.sup.1H.sub.2N--BH.sub.2R.sup.2 using base metal catalyst. The method generates hydrogen and produces at least one of a [R.sup.1HN--BHR.sup.2].sub.m oligomer and a [R.sup.1N--BR.sup.2].sub.n oligomer. The method of dehydrogenating amine-boranes may be used to generate H.sub.2 for portable power sources, such as, but not limited to, fuel cells.

  8. Energy demand analysis of Port-Harcourt refinery, Nigeria and its policy implications

    International Nuclear Information System (INIS)

    Jesuleye, O.A.; Siyanbola, W.O.; Sanni, S.A.; Ilori, M.O.

    2007-01-01

    This paper analyses energy demand of Port-Harcourt refinery, Nigeria, based on information obtained from its annual publications, backed-up by spot interviews. The analytical approach adopted for the study involves the calculation of energy intensities to determine the refinery's annual energy demand for various energy types considered from 1989 to 2004. The results showed that the actual energy demand per year for processing crude oil into refined products, exceeded, in varying degrees the stipulated refinery standard of 4 barrels of oil equivalent (BOE) per 100 BOE. It varied from 4.28-8.58 BOE per 100 BOE. In terms of energy demand efficiency, this implies very poor performance of the refinery during the 16-year period under investigation. The excess demand which translates to an average daily wastage of about 2005 BOE is estimated to be $56,196 (US Dollars) based on the 2003 OPEC basket price of $28.0213 per barrel. Lack of optimal fuel utilization-mix and non-compliance with the Turn-Around-Maintenance schedules were attributed to the refinery's inefficient energy demand pattern

  9. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  10. Chemical Sensors Based on Metal Oxide Nanostructures

    Science.gov (United States)

    Hunter, Gary W.; Xu, Jennifer C.; Evans, Laura J.; VanderWal, Randy L.; Berger, Gordon M.; Kulis, Mike J.; Liu, Chung-Chiun

    2006-01-01

    This paper is an overview of sensor development based on metal oxide nanostructures. While nanostructures such as nanorods show significan t potential as enabling materials for chemical sensors, a number of s ignificant technical challenges remain. The major issues addressed in this work revolve around the ability to make workable sensors. This paper discusses efforts to address three technical barriers related t o the application of nanostructures into sensor systems: 1) Improving contact of the nanostructured materials with electrodes in a microse nsor structure; 2) Controling nanostructure crystallinity to allow co ntrol of the detection mechanism; and 3) Widening the range of gases that can be detected by using different nanostructured materials. It is concluded that while this work demonstrates useful tools for furt her development, these are just the beginning steps towards realizati on of repeatable, controlled sensor systems using oxide based nanostr uctures.

  11. Integrated pollution control for oil refinery complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kiperstok, A. [Bahia Univ., Salvador, BA (Brazil); Sharratt, P.N. [Manchester Univ. (United Kingdom). Inst. of Science and Technology

    1993-12-31

    Improving environmental performance of oil refineries is a complex task. Emission limits, operating constraints, available technologies, operating techniques, and local environment sensitivity must all be considered. This work describes efforts to build an interactive software to deal with this problem. 8 refs., 5 figs.

  12. Integrated pollution control for oil refinery complexes

    Energy Technology Data Exchange (ETDEWEB)

    Kiperstok, A [Bahia Univ., Salvador, BA (Brazil); Sharratt, P N [Manchester Univ. (United Kingdom). Inst. of Science and Technology

    1994-12-31

    Improving environmental performance of oil refineries is a complex task. Emission limits, operating constraints, available technologies, operating techniques, and local environment sensitivity must all be considered. This work describes efforts to build an interactive software to deal with this problem. 8 refs., 5 figs.

  13. Refinery siting workbook: appendices C to O

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  14. Efficient waveguide coupler based on metal materials

    Science.gov (United States)

    Wu, Wenjun; Yang, Junbo; Chang, Shengli; Zhang, Jingjing; Lu, Huanyu

    2015-10-01

    Because of the diffraction limit of light, the scale of optical element stays in the order of wavelength, which makes the interface optics and nano-electronic components cannot be directly matched, thus the development of photonics technology encounters a bottleneck. In order to solve the problem that coupling of light into the subwavelength waveguide, this paper proposes a model of coupler based on metal materials. By using Surface Plasmon Polaritons (SPPs) wave, incident light can be efficiently coupled into waveguide of diameter less than 100 nm. This paper mainly aims at near infrared wave band, and tests a variety of the combination of metal materials, and by changing the structural parameters to get the maximum coupling efficiency. This structure splits the plane incident light with wavelength of 864 nm, the width of 600 nm into two uniform beams, and separately coupled into the waveguide layer whose width is only about 80 nm, and the highest coupling efficiency can reach above 95%. Using SPPs structure will be an effective method to break through the diffraction limit and implement photonics device high-performance miniaturization. We can further compress the light into small scale fiber or waveguide by using the metal coupler, and to save the space to hold more fiber or waveguide layer, so that we can greatly improve the capacity of optical communication. In addition, high-performance miniaturization of the optical transmission medium can improve the integration of optical devices, also provide a feasible solution for the photon computer research and development in the future.

  15. Analysis of snow-cap pollution for air quality assessment in the vicinity of an oil refinery.

    Science.gov (United States)

    Krastinyte, Viktorija; Baltrenaite, Edita; Lietuvninkas, Arvydas

    2013-01-01

    Snow-cap can be used as a simple and effective indicator of industrial air pollution. In this study snow-cap samples were collected from 11 sites located in the vicinity of an oil refinery in Mazeikiai, a region in the north-west of Lithuania, in the winter of 2011. Analysis of snowmelt water and snow-dust was used to determine anthropogenic pollutants such as: sulphates and chlorides, nitrites, nitrates, ammonium nitrogen, total carbon, total nitrogen; heavy metals: lead (Pb), copper (Cu), chromium (Cr), cadmium (Cd). Concentrations of heavy metals in snow-dust were detected thousands of times higher than those in the snowmelt water. In this study, analysis of heavy metal concentration was conducted considering different distances and the wind direction within the impact zone of the oil refinery. The sequence of heavy metals according to their mean concentrations in the snow-dust samples was the following: Pb > Cr > Cu > Cd. Heavy metals highly correlated among each other. The load of snow-dust was evaluated to determine the pollution level in the study area. The highest daily load of snow-dust was 45.81 +/- 12.35 mg/m2 in the north-western direction from the oil refinery. According to classification of the daily load of snow-dust a lower than medium-risk level of pollution was determined in the vicinity of the oil refinery.

  16. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, Michael [Gas Technology Inst., Des Plaines, IL (United States); Marker, Terry [Gas Technology Inst., Des Plaines, IL (United States); Ortiz-Toral, Pedro [Gas Technology Inst., Des Plaines, IL (United States); Linck, Martin [Gas Technology Inst., Des Plaines, IL (United States); Felix, Larry [Gas Technology Inst., Des Plaines, IL (United States); Wangerow, Jim [Gas Technology Inst., Des Plaines, IL (United States); Swanson, Dan [Gas Technology Inst., Des Plaines, IL (United States); McLeod, Celeste [CRI Catalyst, Houston, TX (United States); Del Paggio, Alan [CRI Catalyst, Houston, TX (United States); Urade, Vikrant [CRI Catalyst, Houston, TX (United States); Rao, Madhusudhan [CRI Catalyst, Houston, TX (United States); Narasimhan, Laxmi [CRI Catalyst, Houston, TX (United States); Gephart, John [Johnson Timber, Hayward, WI (United States); Starr, Jack [Cargill, Wayzata, MN (United States); Hahn, John [Cargill, Wayzata, MN (United States); Stover, Daniel [Cargill, Wayzata, MN (United States); Parrish, Martin [Valero, San Antonio, TX (United States); Maxey, Carl [Valero, San Antonio, TX (United States); Shonnard, David [MTU, Friedrichshafen (Germany); Handler, Robert [MTU, Friedrichshafen (Germany); Fan, Jiquig [MTU, Friedrichshafen (Germany)

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  17. The life and times of a western refinery

    International Nuclear Information System (INIS)

    Thomas, W.

    1998-01-01

    An historical account is given of the discovery of oil by Imperial Oil Ltd., at Leduc in 1947, and the opening of a refinery in Edmonton in 1948. The discovery at Leduc was the first major strike to be made in western Canada, but Imperial Oil did not have a refinery at the site to process the new found crude. Given the economic constraints of the postwar era, Imperial Oil decided to dismantle and move an idle and virtually brand-new refinery located at Whitehorse, Yukon. It took 10 months to reassemble the refinery at its newly prepared site at Edmonton. Regular expansions and improvements helped to ensure that the refinery kept up with the advances in technology and market demand. By the early 1970s, small refineries were becoming uneconomical as distribution of products by pipelines became possible. In 1976 Imperial Oil spent more than $300 million to consolidate its four Prairie refineries, those in Calgary, Winnipeg, Regina and Edmonton, into one large facility at the Edmonton site. The role that the refinery plays in today's community and the effort that Imperial Oil makes to comply with stringent environmental regulations were described. Today, the refinery is producing 165,000 barrels a day of fuels and lubricants and another 20,000 barrels of asphalt. The refinery supplies more than 200 different products to customers across Canada, with unit costs which are amongst the lowest of North American refineries. figs

  18. Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

    Energy Technology Data Exchange (ETDEWEB)

    Altman, D.J.; Hazen, T.C.; Tien, A.J. [Westinghouse Savannah River Co., Aiken, SC (United States). Savannah River Technology Center; Worsztynowicz, A.; Ulfig, K. [Inst. for Ecology of Industrial Areas, Katowice (Poland)

    1997-05-10

    The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH`s, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass.

  19. Test plan, the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon. Revision 1

    International Nuclear Information System (INIS)

    Altman, D.J.; Hazen, T.C.; Tien, A.J.

    1997-01-01

    The overall objective of the bioremediation project is to provide a cost effective bioremediation demonstration of petroleum contaminated soil at the Czechowice Oil Refinery. Additional objectives include training of personnel, and transfer of this technology by example to Poland, and the Risk Abatement Center for Central and Eastern Europe (RACE). The goal of the remediation is to reduce the risk of PAH compounds in soil and provide a green zone (grassy area) adjacent to the site boundary. Initial project discussions with the Czechowice Oil Refinery resulted in helping the refinery find an immediate cost effective solution for the dense organic sludge in the lagoons. They found that when mixed with other waste materials, the sludge could be sold as a fuel source to local cement kilns. Thus the waste was incinerated and provided a revenue stream for the refinery to cleanup the lagoon. This allowed the bioremediation project to focus on remediation of contaminated soil that unusable as fuel, less recalcitrant and easier to handle and remediate. The assessment identified 19 compounds at the refinery that represented significant risk and would require remediation. These compounds consisted of metals, PAH's, and BTEX. The contaminated soil to be remediated in the bioremediation demonstration contains only PAH (BTEX and metals are not significantly above background concentrations). The final biopile design consists of (1) dewatering and clearing lagoon A to clean clay, (2) adding a 20 cm layer of dolomite with pipes for drainage, leachate collection, air injection, and pH adjustment, (3) adding a 1.1 m layer of contaminated soil mixed with wood chips to improve permeability, and (4) completing the surface with 20 cm of top soil planted with grass

  20. Production planning and scheduling in refinery industry

    International Nuclear Information System (INIS)

    Persson, Jan.

    1999-01-01

    In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis

  1. Production planning and scheduling in refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Jan

    1999-07-01

    In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis.

  2. Production planning and scheduling in refinery industry

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Jan

    1999-06-01

    In this thesis we consider production planning and scheduling in refinery industry, in particular we study the planning and scheduling at the Nynaes AB refinery and at the Scanraff AB refinery. The purpose is to contribute to the development and the use of optimization models to support efficient decision making. We identify various decision problems concerning the aggregated production planning, the shipment planning, the scheduling of operation modes, and the utilization of pipes and tanks; and we discuss the potential to successfully apply optimization models on these problems. We formulate a mixed integer linear programming model for the scheduling of operation modes at Nynaes. The model concerns decisions about which mode of operation to use at a particular point in time in order to minimize costs of changing modes and costs of keeping inventories, given demands for products. We derive several types of valid inequalities for this mathematical problem and show how these inequalities can improve the lower bound obtained from the linear programming relaxation of the problem. We also show how the valid inequalities can be used to improve the performance of a branch and bound solution approach. Further, a tabu search heuristic is developed for the scheduling problem. The solution methods are tested on data provided by the Nynaes refinery, and the performance of the methods are discussed. We present several extensions of the proposed model, and illustrate how the model can be used to support both operational and strategic decision making at the refinery. 66 refs, 6 figs, 32 tabs. Also published as: Dissertation from the International Graduate School of Management and Industrial Engineering, No 25, Licenciate Thesis

  3. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler

  4. Yearly refinery construction indexes listed for 68 years

    International Nuclear Information System (INIS)

    Farrar, G.

    1996-01-01

    Yearly values are presented for the Nelson-Farrar refinery inflation cost index since 1926. They are based on 1946 as 100, since that was the date of index inception. Values from 1926 to 1945 were back calculated. Data are presented on indexed cost of materials, labor, and miscellaneous equipment for 1926 through 1994. A second table of itemized refining cost indexes for the years 1954, 1972, 1992--1994, and the first eight months of 1995 is also presented. This table subdivides materials, labor, and equipment into component costs

  5. Transformation of the Czech refinery and petrochemical

    International Nuclear Information System (INIS)

    Junek, V.

    1995-01-01

    The petrochemical and chemical industries in former Czechoslovakia in the period after World War II was built up with a purpose to create a complex whose individual subjects would be closely interlinked from the point of view of their production programmes. The separation of Slovakia as an independent state has disrupted some of these links. In spite of that the petrochemical and chemical industries are nowadays the most prosperous branches of economy of the Czech Republic. The governmental proposal for the reorganizing of the refinery and petrochemical complex elaborated in connection with the resolution of the Governmental Privatization Commission of November 6 1994 proposed the formation of a holding company Unipetrol in the way of merging Chemopetrol and Kaucuk with a new joint stock company Unipetrol established for this purpose by the National Property Fund. The updated proposal offers formation of the holding organization Unipetrol in a substantially simpler, from the point of view of time, organization and financing less demanding manner. This proposal is based on the following principles: respecting the approved privatization projects, the solution must not have influence on the rights and position of natural and juristic persons who became shareholders in accordance with the privatization projects already approved, the influence of the state on decisions of the holding and its daughter companies will be maintained with regard to the security of the state and supplying the strategically important subjects with fuels in situation of a crisis, the share of the business subjects in the shares of the holding will be such that it would enable them from the very beginning to participate effectively and not only formally in the decisions. 2 figs

  6. Saccharide-based Approach to Green Metallic Nanostructure Synthesis

    DEFF Research Database (Denmark)

    Engelbrekt, Christian; Sørensen, Karsten Holm; Jensen, Palle Skovhus

    A green approach to solution synthesis of metallic nanoparticles has been developed using harmless and bioapplicable chemicals as well as moderate temperatures. Metal precursors are reduced by glucose/buffers and sterically stabilized by starch. The saccharide based procedure is highly diverse pr...... producing specifically a wide range of spherical, anisotropic, metallic, semi - conductor and core-shell nanostructures....

  7. Economical characteristics of base types of minerals. 1. Metallic minerals

    International Nuclear Information System (INIS)

    Khasanov, A.Kh.

    1990-01-01

    Metallic minerals is raw materials base of black and colour metallurgy. In this article of book author describes the group of black metals (iron, manganese, chromium), group of tempers (titanium, vanadium, nickel, cobalt, molybdenum, tungsten), colour metals (copper, lead, zinc, aluminium, tin, mercury, antimony, bismuth) and etc.

  8. Challenges and technological opportunities for the oil refining industry: A Brazilian refinery case

    International Nuclear Information System (INIS)

    Castelo Branco, David A.; Gomes, Gabriel L.; Szklo, Alexandre S.

    2010-01-01

    The worldwide oil refining industry currently faces strong challenges related to uncertainties about future feedstock and characteristics of oil products. These challenges favor two main strategies for the sector: the first strategy is increasing refinery complexity and versatility; the second is integrating the refining and petrochemical industries, adding value to the crude oil while guaranteeing market share to premium oil products. Both strategies aim at increasing production of highly specified oil products, simultaneously reducing the environmental impacts of the refining industry. This paper analyses the case of a Brazilian refinery, Gabriel Passos Refinery (REGAP), by proposing additional investments to alter and/or expand its current production scheme. All the proposed options present relatively low investment rates of return. However, investments in a hydrocracking based configuration with a gasification unit providing hydrogen and power can further improve the operational profitability, due to reduced natural gas consumption.

  9. Current status of vegetation of six PETROBRAS refineries; Status dos fragmentos de vegetacao em seis refinarias da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Basbaum, Marcos Andre; Bonafini, Fabio Loureiro; Porciano, Patricia Pereira [SEEBLA, Servicos de Engenharia Emilio Baumgart Ltda., Rio de Janeiro, RJ (Brazil); Torggler, Bianca Felippe; Fernandes, Renato [PETROBRAS, Rio de Janeiro, RJ (Brazil). Engenharia; Vieira, Elisa Diniz Reis [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Most of refineries from PETROBRAS have significant vegetation areas within their limits. The purpose of this study was to develop a preliminary assessment study of the vegetation fragments on six refineries, including the quantification of permanent preservation areas (Brazilian environmental law requirement). Besides that, the authors propose potential recovery areas and some reforestation techniques. The methodology was based on Rapid Ecological Assessment, that consists on the selection of target areas by image analysis (satellite or aerial photos) and expedite fieldwork - three days on each refinery. The main features of vegetation, like phytophysiognomy and successional stage were obtained, and registered on a specific form developed to be used at fieldwork. The results achieved show that 44,7% of the areas from these six refineries were occupied by vegetation. The most representative categories of vegetation were Atlantic forest fragments and mangroves, as well as to permanent preservation areas. (author)

  10. Refinery evaluation of optical imaging to locate fugitive emissions.

    Science.gov (United States)

    Robinson, Donald R; Luke-Boone, Ronke; Aggarwal, Vineet; Harris, Buzz; Anderson, Eric; Ranum, David; Kulp, Thomas J; Armstrong, Karla; Sommers, Ricky; McRae, Thomas G; Ritter, Karin; Siegell, Jeffrey H; Van Pelt, Doug; Smylie, Mike

    2007-07-01

    Fugitive emissions account for approximately 50% of total hydrocarbon emissions from process plants. Federal and state regulations aiming at controlling these emissions require refineries and petrochemical plants in the United States to implement a Leak Detection and Repair Program (LDAR). The current regulatory work practice, U.S. Environment Protection Agency Method 21, requires designated components to be monitored individually at regular intervals. The annual costs of these LDAR programs in a typical refinery can exceed US$1,000,000. Previous studies have shown that a majority of controllable fugitive emissions come from a very small fraction of components. The Smart LDAR program aims to find cost-effective methods to monitor and reduce emissions from these large leakers. Optical gas imaging has been identified as one such technology that can help achieve this objective. This paper discusses a refinery evaluation of an instrument based on backscatter absorption gas imaging technology. This portable camera allows an operator to scan components more quickly and image gas leaks in real time. During the evaluation, the instrument was able to identify leaking components that were the source of 97% of the total mass emissions from leaks detected. More than 27,000 components were monitored. This was achieved in far less time than it would have taken using Method 21. In addition, the instrument was able to find leaks from components that are not required to be monitored by the current LDAR regulations. The technology principles and the parameters that affect instrument performance are also discussed in the paper.

  11. Unraveling Dutch citizens' perceptions on the bio-based economy : The case of bioplastics, bio-jetfuels and small-scale bio-refineries

    NARCIS (Netherlands)

    Lynch, Durwin H J; Klaassen, Pim; Broerse, Jacqueline E W

    2017-01-01

    Little is known about how citizens perceive the transition towards a bio-based economy (BBE), despite the fact that they are one of the most important actors in this transition. Citizens' perceptions of bio-based innovations can support policy-makers to improve the quality of decision-making and the

  12. 40 CFR 80.94 - Requirements for gasoline produced at foreign refineries.

    Science.gov (United States)

    2010-07-01

    ... inspection or audit if a baseline petition has not been approved, and any work papers related to refinery... foreign refineries. 80.94 Section 80.94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... for gasoline produced at foreign refineries. (a) Definitions. (1) A foreign refinery is a refinery...

  13. Application of Ozone MBBR Process in Refinery Wastewater Treatment

    Science.gov (United States)

    Lin, Wang

    2018-01-01

    Moving Bed Biofilm Reactor (MBBR) is a kind of sewage treatment technology based on fluidized bed. At the same time, it can also be regarded as an efficient new reactor between active sludge method and the biological membrane method. The application of ozone MBBR process in refinery wastewater treatment is mainly studied. The key point is to design the ozone +MBBR combined process based on MBBR process. The ozone +MBBR process is used to analyze the treatment of concentrated water COD discharged from the refinery wastewater treatment plant. The experimental results show that the average removal rate of COD is 46.0%~67.3% in the treatment of reverse osmosis concentrated water by ozone MBBR process, and the effluent can meet the relevant standard requirements. Compared with the traditional process, the ozone MBBR process is more flexible. The investment of this process is mainly ozone generator, blower and so on. The prices of these items are relatively inexpensive, and these costs can be offset by the excess investment in traditional activated sludge processes. At the same time, ozone MBBR process has obvious advantages in water quality, stability and other aspects.

  14. The acid refinery wastes in environment

    International Nuclear Information System (INIS)

    Samesova, D.; Ladomersky, J.; Hroncova, E.

    2003-01-01

    The aim of our paper is to assign ways and means of the pollution extension from the old landfills of the petrochemical sludges. In the past the sludges were deposited in sludge landfills. Nowadays remediation of the landfills is a key problem. We analyse condition of the refinery sludges latching. We found out the meaning influences of leachate time, temperature, concentration and liquid kind. (authors)

  15. Opportunities for Biorenewables in Oil Refineries

    Energy Technology Data Exchange (ETDEWEB)

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  16. First refinery opened in Kyrgyz Republic

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    The first oil refinery in the Kyrgyz Republic was opened on 5 October 1996 in Jalalabad in a ceremony attended by the President of the Central Asian country, Askar Akaev. The 10,000 barrels of oil per day (bopd) modular refinery has been financed by the Canadian oil junior, Kyrgoil Corporation, which has also formed a joint venture with the national oil company, Kyrgyzneft, to redevelop where viable the 628 underperforming oil wells in the Kyrgyz Republic sector of the Fergana Basin. The opening is the first significant milestone in a programme initiated by Akaev to develop the oil production industry in the Kyrgyz Republic. Currently the country imports more than 50,000 barrels of oil equivalent per day, mostly from Kazakhstan. In the year ending March 1996, 110 million was spent on imports of fuel products, an amount that exceeds the trade deficit over the same period. Built in only eight months, the Pound 12 million refinery will gradually be brought to full capacity. By January, it is expected that more than 5,000 barrels of gasoline, diesel and fuel oil will be produced every day. Although there is some crude oil in storage, the ramping of production is tied into the programme of workovers of the existing wells. There are no current plans to import crude, although most of the infrastructure is in place should it become necessary. (author)

  17. Amoco/Environmental Protection Agency Pollution Prevention Project, Yorktown refinery. Refinery release inventory. Final report

    International Nuclear Information System (INIS)

    Klee, H.; Kizier, G.J.; Baloo, S.; Hockman, E.L.; Couzens-Roberts, C.

    1992-07-01

    The report volume summarizes physical data obtained during a 2-year pollution prevention study of Amoco Oil Company's Yorktown Virginia Refinery. The study was jointly sponsored as a cooperative effort of Amoco Corporation and the United States Environmental Protection Agency. A multi-media sampling program was used to identify potential pollution sources within the Refinery. Sampling and analysis included air, surface water, groundwater, and solid waste data. Public perceptions about environmental issues of concern in the vicinity of the Refinery were also surveyed. The inventory showed that nearly 99 percent of the releases were airborne at the facility. Most of the remainder involved land disposal of solid wastes. Specific sources of major pollutants are identified

  18. Toward effective ecological risk-management of refinery corrective action

    International Nuclear Information System (INIS)

    Metzger, B.H.; Rury, P.M.; Turton, D.; Archibald, B.; Clark, J.; Cura, J.

    1995-01-01

    Cleanup of complex industrial sites, such as refineries, requires risk-based decision tools to ensure that environmentally protective remediation is consistent with current and future land use. However, conventional ecological risk assessment approaches are not well suited for complex industrial sites. Site risk assessments focus on hypothetical chemical risk assuming diverse and undisturbed ecosystems, rather than industrial and disturbed area conditions. In addition, they offer little guidance as to how to make timely and effective risk management decisions. An innovative methodology is proposed to assist industry and regulatory risk managers with rapid EcoRisk reconnaissance and cost-effective remedial decision-making at complex industrial sites. Phase 1 comprises a three-step risk screening of areas of ecological concern at the site, which integrates habitat quality characteristics and potential chemical hazards. It yields an ordering of areas as follows: areas of no significant risk; areas of potentially significant risk; and areas of likely significant risk. A decision rule is then applied to determine appropriate risk management action, including: no action; additional study; and remedial or management action. In Phase 2, additional study is conducted for areas that exhibit potentially significant risk so as to facilitate risk management. This methodology is currently being applied at the 1,300 acre, former Exxon Bayway Refinery in New Jersey

  19. Cathodic Protection Design Algorithms for Refineries Aboveground Storage Tanks

    Directory of Open Access Journals (Sweden)

    Kosay Abdul sattar Majbor

    2017-12-01

    Full Text Available Storage tanks condition and integrity is maintained by joint application of coating and cathodic protection. Iraq southern region rich in oil and petroleum product refineries need and use plenty of aboveground storage tanks. Iraq went through conflicts over the past thirty five years resulting in holding the oil industry infrastructure behind regarding maintenance and modernization. The primary concern in this work is the design and implementation of cathodic protection systems for the aboveground storage tanks farm in the oil industry. Storage tank external base area and tank internal surface area are to be protected against corrosion using impressed current and sacrificial anode cathodic protection systems. Interactive versatile computer programs are developed to provide the necessary system parameters data including the anode requirements, composition, rating, configuration, etc. Microsoft-Excel datasheet and Visual Basic.Net developed software were used throughout the study in the design of both cathodic protection systems. The case study considered in this work is the eleven aboveground storage tanks farm situated in al-Shauiba refinery in southern IRAQ. The designed cathodic protection systems are to be installed and monitored realistically in the near future. Both systems were designed for a life span of (15-30 years, and all their parameters were within the internationally accepted standards.

  20. The Optimization-Based Design and Synthesis of Water Network for Water Management in an Industrial Process: Refinery Effluent Treatment Plant

    DEFF Research Database (Denmark)

    Sueviriyapan, Natthapong; Siemanond, Kitipat; Quaglia, Alberto

    2014-01-01

    The increasing awareness of the sustainability of water resources has become an important issue. Many process industries contribute to high water consumption and wastewater generation. Problems in industrial water management include the processing of complex contaminants in wastewater, selection...... of wastewater treatment technologies, as well as water allocation, limited reuse, and recycling strategies. Therefore, a water and wastewater treatment network design requires the integration of both economic and environmental perspectives. The aim of this work was to modify and develop a generic model......-based synthesis process for a water/wastewater treatment network design problem utilizing the framework of Quaglia et al. (2013) in order to effectively design, synthesize, and optimize an industrial water management problem using different scenarios (both existing and retrofit system design). The model...

  1. Solid waste management : a case study of National Refinery Limited

    Energy Technology Data Exchange (ETDEWEB)

    Syed, A.H.; Syed, Z.R. [National Refinery Ltd., Karachi (Pakistan); NED Univ. of Engineering and Technology, Karachi (Pakistan)

    2000-07-01

    A study was conducted to quantify and classify the waste generated at the National Refinery Limited (NRL). This refinery, located in Karachi, Pakistan, produces naphtha, motor gasoline, diesel, kerosene and lubricating oils and much more. Various units such as crude oil storage, thermal cracking, catalytic cracking and others were surveyed to assess the source and nature of the pollution. It was found that the major contributor to air pollution was the sulfur released through the burning of fuel oil during day-to-day operations. It was determined that approximately 2000 metric tons of solid waste were produced each day, along with 0.55 million gallons of waste water. In addition, sulfur, carbon dioxide, carbon monoxide and nitrogen dioxide were also released in the atmosphere. The solid waste was composed of municipal waste, sludges from the API and other discarded materials. The authors then proceeded to determine the heavy metals contents in samples obtained from combined sludge dumping areas on the premises. The sludges contained sulfur (0-1.26 wt per cent), lead (0-0.156 wt per cent), iron (0.01-3.4 wt per cent), chromium (0-0.159 per cent), copper (0-0.05 wt per cent), cadmium (0-0.0034 wt per cent), nickel (0-0.168 wt per cent), and manganese (0.0015-0.0776 wt per cent). It was recommended that hazardous and non-hazardous wastes be segregated, that a separate feasibility study be undertaken to determine the best possible course of action to dispose of solid waste, and that government guidelines be established on the same topic. 5 refs., 4 tabs.

  2. Electron beam welding of the dissimilar Zr-based bulk metallic glass and Ti metal

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jonghyun [Department of Material Science, Kumamoto University, Kumamoto 860-8555 (Japan)], E-mail: joindoc@kumamoto-u.ac.jp; Kawamura, Y. [Department of Material Science, Kumamoto University, Kumamoto 860-8555 (Japan)

    2007-04-15

    We successfully welded 3 mm thick Zr{sub 41}Be{sub 23}Ti{sub 14}Cu{sub 12}Ni{sub 10} bulk metallic glass plate to Ti metal by electron beam welding with a beam irradiated 0.4 mm on the BMG side of the interface. There was no crystallization or defects in the weld because changes in the chemical composition of the weld metal were prevented. Bending showed that the welded sample had a higher strength than the Ti base metal. The interface had a 10 {mu}m thick interdiffusion layer of Zr and Ti.

  3. Tactical Garbage to Energy Refinery

    Science.gov (United States)

    2009-10-01

    Petroleum based Pyrolysis to bio-oil Biodiesel (fluid .6) Fuel cells, PEMs generators * Bio-based Gasification to energy Methane (gas .97) Liquid fuel for...Biotechnol. 2007, 108, 67-93. 9. Patzek, T.W. Thermodynamics of the Corn -Ethanol Biofuel Cycle. Curr. Rev. Plant Sci. 2004,23,519-567 10. Canes, M.E

  4. Life-cycle assessment of a waste refinery process for enzymatic treatment of municipal solid waste

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2012-01-01

    for the enzymatic treatment of municipal solid waste (MSW) is presented. The refinery produced a liquid (liquefied organic materials and paper) and a solid fraction (non-degradable materials) from the initial waste. A number of scenarios for the energy utilization of the two outputs were assessed. Co......Decrease of fossil fuel dependence and resource saving has become increasingly important in recent years. From this perspective, higher recycling rates for valuable materials (e.g. metals) as well as energy recovery from waste streams could play a significant role substituting for virgin material...... production and saving fossil resources. This is especially important with respect to residual waste (i.e. the remains after source-separation and separate collection) which in Denmark is typically incinerated. In this paper, a life-cycle assessment and energy balance of a pilot-scale waste refinery...

  5. Surface/structure functionalization of copper-based catalysts by metal-support and/or metal-metal interactions

    Science.gov (United States)

    Konsolakis, Michalis; Ioakeimidis, Zisis

    2014-11-01

    Cu-based catalysts have recently attracted great attention both in catalysis and electro-catalysis fields due to their excellent catalytic performance and low cost. Given that their performance is determined, to a great extent, by Cu sites local environment, considerable efforts have been devoted on the strategic modifications of the electronic and structural properties of Cu sites. In this regard, the feasibility of tuning the local structure of Cu entities by means of metal-support or metal-metal interactions is investigated. More specifically, the physicochemical properties of Cu entities are modified by employing: (i) different oxides (CeO2, La2O3, Sm2O3), or (ii) ceria-based mixed oxides (Ce1-xSmxOδ) as supporting carriers, and (iii) a second metal (Cobalt) adjacent to Cu (bimetallic Cu-Co/CeO2). A characterization study, involving BET, XRD, TPR, and XPS, reveal that significant modifications on structural, redox and electronic properties of Cu sites can be induced by adopting either different oxide carriers or bimetallic complexes. Fundamental insights into the tuning of Cu local environment by metal-support or metal-metal interactions are provided, paving the way for real-life industrial applications.

  6. Evaluation of treatment efficiency of processes for petroleum refinery`s wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Kee, Kean Chin [National Univ. of Singapore, Kent Ridge (Singapore). Dept. of Civil Engineering

    1993-12-31

    Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and extended aeration system. The use of extended aeration biological system proved to be an improvement but not a solution yet in such kind of treatment. 2 refs., 2 tabs.

  7. Evaluation of treatment efficiency of processes for petroleum refinery`s wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Kee, Kean Chin [National Univ. of Singapore, Kent Ridge (Singapore). Dept. of Civil Engineering

    1994-12-31

    Processes used in the treatment of a petroleum refinery wastewater included initial API oil separator to be followed by dissolved air flotation and extended aeration system. The use of extended aeration biological system proved to be an improvement but not a solution yet in such kind of treatment. 2 refs., 2 tabs.

  8. Competitive strategy to provide technology and basic designs for the construction of new refineries premium of the PETROBRAS; Estrategia competitiva para prover tecnologias e projetos basicos para a construcao de novas refinarias premium da PETROBRAS

    Energy Technology Data Exchange (ETDEWEB)

    Claudia, Baptista M.L.A.; Adalberto, Barbalho S [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)

    2012-07-01

    Nowadays, there are major incentives for the construction of new refineries in Brazil: the increase of the local market and the discovery of huge oil reserves in the southeastern Atlantic coast of Brazil. In this scenario, PETROBRAS decided to construct two new refineries, Premium I and II, with a total refining capacity of 900.000 BPSD. The refineries will be designed to process a mix of Brazilian national crudes. The main objects of this ambitious project are to produce high quality diesel and jet fuel from an elevated nitrogen content feedstock, minimizing capital expenditure and schedule. Both refineries will have the same flow scheme with a target to maximize Middle distillate production for the European and local markets. In order to assure that the refinery scheme and the technologies selected will provide the best Net Present Value (NPV), it was decided to perform a Design Competition process to select the company to provide the basic design for all Premium refineries. As the concepts behind a Design Competition were new for PETROBRAS a rigorous process was developed and followed, which entailed contracting three benchmark companies with outstanding knowledge and experience in hydroprocessing to provide independent conceptual studies for a 300.000 BPSD refinery called Premium II. The vision was to utilize the same refinery scheme in the construction of the Premium I refinery which will have two identical trains processing 300.000 BPD. The awarded company was selected based on technical and economic evaluations, supported by state of the art hydroprocessing technologies, block flow diagram optimization and heat integration. This strategy allowed PETROBRAS to acquire the best refinery scheme and process designs for the PREMIUM refineries. The present paper discusses the design competition process, the refinery scheme adopted and the results achieved. (author)

  9. Microfluidic paper-based analytical device for particulate metals.

    Science.gov (United States)

    Mentele, Mallory M; Cunningham, Josephine; Koehler, Kirsten; Volckens, John; Henry, Charles S

    2012-05-15

    A microfluidic paper-based analytical device (μPAD) fabricated by wax printing was designed to assess occupational exposure to metal-containing aerosols. This method employs rapid digestion of particulate metals using microliters of acid added directly to a punch taken from an air sampling filter. Punches were then placed on a μPAD, and digested metals were transported to detection reservoirs upon addition of water. These reservoirs contained reagents for colorimetric detection of Fe, Cu, and Ni. Dried buffer components were used to set the optimal pH in each detection reservoir, while precomplexation agents were deposited in the channels between the sample and detection zones to minimize interferences from competing metals. Metal concentrations were quantified from color intensity images using a scanner in conjunction with image processing software. Reproducible, log-linear calibration curves were generated for each metal, with method detection limits ranging from 1.0 to 1.5 μg for each metal (i.e., total mass present on the μPAD). Finally, a standard incineration ash sample was aerosolized, collected on filters, and analyzed for the three metals of interest. Analysis of this collected aerosol sample using a μPAD showed good correlation with known amounts of the metals present in the sample. This technology can provide rapid assessment of particulate metal concentrations at or below current regulatory limits and at dramatically reduced cost.

  10. Profitability diagnosis of refinery and improvement proposal; Seiyusho no shueki shindan to kaizen teian

    Energy Technology Data Exchange (ETDEWEB)

    Aoyama, H.

    2000-07-01

    Based on consulting service RPS-J under joint operation of Nikki, UOP LLC of U.S.A. and Nikki Universal, approaching ways applied for profitability improvement and improvement proposal for refineries and analyzing techniques used for resolution of process bottlenecks were described. In RPS-J, themes of (1) energy saving, (2) quality upgrading, (3) improvement of disintegrating ratio, (4) reduction of give-away, (5) improvement of equipment operation ratio, (6) reduction of maintenance cost, (7) effective utilization of catalysts, are considered for profitability improvement fields. Procedures from idea excavation for profitability improvement to realization of profitability improvement are carried out in the order of, (1) Grasping of the present state, (2) Excavation of improving items and selection, (3) Quantitative evaluation of draft profitability improvement plan and focusing, (4) Profitability improvement by operation improvement, (5) Profitability improvement by minor improvement, (6) Profitability improvement in middle- and long-term vision, (7) Final focusing by feasibility study. Afterwards, examination to economically solve bottlenecks of critical facilities, examination on bottlenecks of distillation tower and refining tower and utility analysis are carried out. RPS-J was already applied to 4 refineries including Muroran Refinery and Negishi Refinery of Nisseki Mitsubishi, and profitability improvement themes were found to improve profitability of 50 to 150 cents per barrel. (NEDO)

  11. Poland petroleum refinery sludge lagoon demonstration project

    International Nuclear Information System (INIS)

    Altman, D.J.

    2000-01-01

    The US Department of Energy and the Institute for Ecology of Industrial Area have been working together to develop mutually beneficial, cost-effective environmental remediation technologies such as the demonstration of bioremediation techniques for the clean up of acidic petroleum sludge impacted soils at an oil refinery in southern Poland. After an expedited site characterization, treatability study, and a risk assessment study, a remediation strategy was devised. The waste material was composed primarily of high molecular weight paraffinic and polynuclear aromatic hydrocarbons. A biopile design which employed a combination of passive and active aeration in conjunction with nutrient and surfactant application as used to increase the biodegradation of the contaminants of concern

  12. 40 CFR 80.1141 - Small refinery exemption.

    Science.gov (United States)

    2010-07-01

    .... (a)(1) Gasoline produced at a refinery by a refiner, or foreign refiner (as defined at § 80.1165(a... effective beginning on January 1 of the following calendar year, at which point the gasoline produced at... from the calculation of its Renewable Volume Obligation (under § 80.1107(a)) gasoline from any refinery...

  13. environmental impact of illegal refineries on the vegetation

    African Journals Online (AJOL)

    Dr. O. M. Adesope

    impact of illegal oil refineries in the Niger Delta, Nigeria, the floristic composition of the fresh water swamp forest at refining sites in two river systems and a brackish ... ecosystem of Rivers State, five species of Mangroves and two species of ... Visual observation was made along the Rivers to identify illegal refinery stations.

  14. Two refineries running crude; third to restart by September

    International Nuclear Information System (INIS)

    Tippee, B.

    1993-01-01

    Kuwait's downstream oil and gas industry, which sustained less damage than the country's oil field infrastructure during the Iraqi occupation of the 1990-91, has nearly completed reconstruction. Two of three refineries have resumed operations, one of them at reduced crude distillation rates. And state-owned Kuwait National Petroleum Co. hopes to put the other refinery, Shuaiba, back on stream in September, although not at preinvasion throughput rates. Major reconstruction will be complete by year end, with crude oil distillation capacity at 650,000 b/sd. Preinvasion crude capacities of Kuwait's refineries totaled 840,000 b/d. The article describes an overview of the recovery; the status of the Mina Abdulla processing plant, the Mina Al-Ahmadi refinery, and the Shuaiba refinery; modernization plans, and plans for petrochemicals

  15. CARBON-CONTAINING COMPOSITES BASED ON METALS

    Directory of Open Access Journals (Sweden)

    VAGANOV V. E.

    2015-10-01

    Full Text Available Problem statement Among the developed technologies metal-composites production,a special place takes powder metallurgy, having fundamental differences from conventionally used foundry technologies. The main advantages of this technology are: the possibility of sensitive control, the structure and phase composition of the starting components, and ultimately the possibility of obtaining of bulk material in nanostructured state with a minimum of processing steps. The potential reinforcers metals include micro and nano-sized oxides, carbides, nitrides, whiskers. The special position is occupied with carbon nanostructures (CNS: С60 fullerenes, single-layer and multi-layer nanotubes, onions (spherical "bulbs", nano-diamonds and graphite,their properties are being intensively studied in recent years. These objects have a high thermal and electrical conductivity values, superelasticity, and have a strength approximate to the theoretical value, which can provide an obtaining composite nanomaterial with a unique set of physical and mechanical properties. In creation of a metal matrix composite nanomaterials (CM, reinforced by various CNS, a special attention should be given to mechanical activation processes (MA already at the stage of preparation of the starting components affecting the structure, phase composition and properties of aluminum-matrix composites. Purpose. To investigate the influence of mechanical activation on the structure and phase composition of aluminum-matrix composites. Conclusion. The results of the study of the structure and phase composition of the initial and mechanically activated powders and bulk-modified metal-composites are shown, depending on the type and concentration of modifying varieties CNS, regimes of MA and parameters of compaction. The study is conducted of tribological properties of Al-CNS OF nanostructured materials.

  16. Reformulated gasoline: Costs and refinery impacts

    International Nuclear Information System (INIS)

    Hadder, G.R.

    1994-02-01

    Studies of reformulated gasoline (RFG) costs and refinery impacts have been performed with the Oak Ridge National Laboratory Refinery Yield Model (ORNL-RYM), a linear program which has been updated to blend gasolines to satisfy emissions constraints defined by preliminary complex emissions models. Policy makers may use the reformulation cost knee (the point at which costs start to rise sharply for incremental emissions control) to set emissions reduction targets, giving due consideration to the differences between model representations and actual refining operations. ORNL-RYM estimates that the reformulation cost knee for the US East Coast (PADD I) is about 15.2 cents per gallon with a 30 percent reduction of volatile organic compounds (VOCs). The estimated cost knee for the US Gulf Coast (PADD III) is about 5.5 cents per gallon with a VOC reduction of 35 percent. Reid vapor pressure (RVP) reduction is the dominant VOC reduction mechanism. Even with anti-dumping constraints, conventional gasoline appears to be an important sink which permits RFG to be blended with lower aromatics and sulfur contents in PADD III. In addition to the potentially large sensitivity of RFG production to different emissions models, RFG production is sensitive to the non-exhaust VOC share assumption for a particular VOC model. ORNL-RYM has also been used to estimate the sensitivity of RFG production to the cost of capital; to the RVP requirements for conventional gasoline; and to the percentage of RFG produced in a refining region

  17. The base metal of the oxide-coated cathode

    International Nuclear Information System (INIS)

    Poret, F.; Roquais, J.M.

    2005-01-01

    The oxide-coated cathode has been the most widely used electron emitter in vacuum electronic devices. From one manufacturing company to another the emissive oxide is either a double-Ba, Sr-or a triple-Ba, Sr, Ca-oxide, having always the same respective compositions. Conversely, the base metal composition is very often proprietary because of its importance in the cathode emission performances. The present paper aims at explaining the operation of the base metal through a review. After a brief introduction, the notion of activator is detailed along with their diffusivities and their associated interfacial compounds. Then, the different cathode life models are described prior to few comments on the composition choice of a base metal. Finally, the specificities of the RCA/Thomson 'bimetal' base metal are presented with a discussion on the optimized composition choice illustrated by a long-term life-test of five different melts

  18. Fracture toughness measurements of WC-based hard metals

    International Nuclear Information System (INIS)

    Prakash, L.; Albert, B.

    1983-01-01

    The fracture toughness of WC-based cemented carbides was determined by different methods. The values obtained are dependent on the procedure of measurement. Each method thoughness of hard metals mutually. (orig.) [de

  19. Becoming a refinery leader by changing operations to match new product quality regulations

    Energy Technology Data Exchange (ETDEWEB)

    Mendez, Maryro P. [KBC Advanced Technologies, Surrey (United Kingdom)

    2012-07-01

    Global environmental concerns have forced the automotive and oil industries to increase efficiency and reduce emissions, which has led to the tightening of fuels specifications around the world. The implementation of ultra-low sulphur transport fuels has become a worldwide trend with growing momentum. Compliance with these standards requires the refiner to make decisions in advance of the implementation date. Therefore, in order to make changes on time, refiners are currently assessing options and changes required to comply with regulations by 2016. Similar regulations have been implemented in Europe already and KBC has the methodology and experience to assess the existing refinery configuration, unit capability and facility infrastructure to provide the basis for decision making. This paper focus on KBC's methodology which looks at the molecular management needed to produce the low levels of sulfur and toxic required in today's refined products. A key element to the study is the use of Petro-SIM for development of a representative detailed non-linear model, of the refinery which has been used to test ideas and configurations and help confirm the Refinery LP development activities. Using a Petro-SIM representation, KBC is able to make an assessment of the impact of imposing Tier 3 gasoline (sulphur to < 10 ppm) on the refinery, examining critical blending constraints, unused stream qualities and quantities and likely type and scale of capital investment that would be required while optimising unit operations and maximising margins. This paper illustrates KBC's current thinking based on studies done to date to review clean fuels and Tier 3 specifications options for specific refinery configurations. (author)

  20. Exploration of the catalytic use of alkali metal bases

    OpenAIRE

    Bao, Wei

    2017-01-01

    This PhD thesis project was concerned with the use of alkali metal amide Brønsted bases and alkali metal alkoxide Lewis bases in (asymmetric) catalysis. The first chapter deals with formal allylic C(sp3)–H bond activation of aromatic and functionalized alkenes for subsequent C–C and C–H bond formations. The second chapter is focused on C(sp3)–Si bond activation of fluorinated pro-nucleophiles in view of C–C bond formations. In the first chapter, a screening of various metal amides...

  1. Transition-Metal-Free Biomolecule-Based Flexible Asymmetric Supercapacitors.

    Science.gov (United States)

    Yang, Yun; Wang, Hua; Hao, Rui; Guo, Lin

    2016-09-01

    A transition-metal-free asymmetric supercapacitor (ASC) is successfully fabricated based on an earth-abundant biomass derived redox-active biomolecule, named lawsone. Such an ASC exhibits comparable or even higher energy densities than most of the recently reported transition-metal-based ASCs, and this green ASC generation from renewable resources is promising for addressing current issues of electronic hazard processing, high cost, and unsustainability. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Effect of Novi Sad oil refinery bombardment and fires on soil properties in Vojvodina province

    International Nuclear Information System (INIS)

    Sekulic, P.; Ralev, J.; Zeremski-Skoric, T.

    2002-01-01

    The bombing of the Novi Sad Oil Refinery in 1999 has lead to soil pollution by the products of burning oil and oil derivatives. These products were first carried by winds to the Rimski Sancevi Experiment Field of the Institute of Field and Vegetable Crops (located in the vicinity of the Novi Sad Oil Refinery), where they entered the soil via precipitation. Later, they spread to the city of Novi Sad, its vicinity, and the whole of the Vojvodina province, contaminating the soil. In the present study, we examined the extent to which this soil had been polluted. In 1999, we began to study the level of soil contamination at the Institute's Experiment Field at Rimski Sancevi. In 2000, we carried out the same kind of study in and around the city of Novi Sad, while in 2001 we expanded the study to the whole of Vojvodina. The studies' findings show that the soil reaction has not changed and that the levels of heavy metals in the soil have not exceeded the maximum tolerable concentration (MTC). The presence of PAHs at various concentrations was detected, however. This presence is a result of the fires at the Novi Sad Oil Refinery. (author)

  3. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  6. A new kind of metal detector based on chaotic oscillator

    Science.gov (United States)

    Hu, Wenjing

    2017-12-01

    The sensitivity of a metal detector greatly depends on the identification ability to weak signals from the probe. In order to improve the sensitivity of metal detectors, this paper applies the Duffing chaotic oscillator to metal detectors based on its characteristic which is very sensitive to weak periodic signals. To make a suitable Duffing system for detectors, this paper computes two Lyapunov characteristics exponents of the Duffing oscillator, which help to obtain the threshold of the Duffing system in the critical state accurately and give quantitative criteria for chaos. Meanwhile, a corresponding simulation model of the chaotic oscillator is made by the Simulink tool box of Matlab. Simulation results shows that Duffing oscillator is very sensitive to sinusoidal signals in high frequency cases. And experimental results show that the measurable diameter of metal particles is about 1.5mm. It indicates that this new method can feasibly and effectively improve the metal detector sensitivity.

  7. Metallic ion release from biocompatible cobalt-based alloy

    Directory of Open Access Journals (Sweden)

    Dimić Ivana D.

    2014-01-01

    Full Text Available Metallic biomaterials, which are mainly used for the damaged hard tissue replacements, are materials with high strength, excellent toughness and good wear resistance. The disadvantages of metals as implant materials are their susceptibility to corrosion, the elastic modulus mismatch between metals and human hard tissues, relatively high density and metallic ion release which can cause serious health problems. The aim of this study was to examine metallic ion release from Co-Cr-Mo alloy in artificial saliva. In that purpose, alloy samples were immersed into artificial saliva with different pH values (4.0, 5.5 and 7.5. After a certain immersion period (1, 3 and 6 weeks the concentrations of released ions were determined using Inductively Coupled Plasma - Mass Spectrophotometer (ICP-MS. The research findings were used in order to define the dependence between the concentration of released metallic ions, artificial saliva pH values and immersion time. The determined released metallic ions concentrations were compared with literature data in order to describe and better understand the phenomenon of metallic ion release from the biocompatible cobalt-based alloy. [Projekat Ministarstva nauke Republike Srbije, br. III 46010 i br. ON 174004

  8. CARBON ACCOUNTING INITIATIVES: CASE STUDY OF A PETROLEUM REFINERY IN MALAYSIA TO PREPARE FOR FUTURE CARBON MARKET

    Directory of Open Access Journals (Sweden)

    AMANDA H.L. CHEE

    2010-06-01

    Full Text Available Petroleum refining process produces a large amount of atmospheric pollutants including greenhouse gases which are attributed to global warming. The international community inevitably addressed the global warming issue by introducing a market-based mechanism known as Emission Trading Systems (ETS under the Kyoto Protocol which imposes binding limits to developed nations using three flexibility mechanisms, including the Clean Development Mechanism (CDM. This case study was carried out in a petroleum refinery in Malaysia to explore the possibility for the refinery to participate in CDM. Information was collected through observatory field survey at the refinery and documentation review. Results show that the current monitoring tool using indirect calculation of fuel consumption provides a comprehensive coverage of emission sources but the reporting frequency should be increased for data accuracy. An accounting system was then created to predict the emissions gap of the refinery with reference to the baseline-year set by the Kyoto Protocol. It was concluded that the refinery showed promising potential to participate in CDM to benefit from technology transfer by selling their ‘credits’ to Annex I countries despite the uncertainty on the impact of the carbon market in a Non-Annex I country.

  9. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

    Directory of Open Access Journals (Sweden)

    Ruihong Yang

    2016-04-01

    Full Text Available Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na2SO4 additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography–mass spectrometry (GC–MS used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet–visible spectroscopy (UV–VIS absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

  10. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater.

    Science.gov (United States)

    Yang, Ruihong; Zhu, Jianzhong; Li, Yingliu; Zhang, Hui

    2016-04-29

    Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na₂SO₄ additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography-mass spectrometry (GC-MS) used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet-visible spectroscopy (UV-VIS) absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

  11. Structure and properties of transition metal-metalloid glasses based on refractory metals

    International Nuclear Information System (INIS)

    Johnson, W.L.; Williams, A.R.

    1979-01-01

    The structure and properties of several new transition metal-metalloid (TM/sub 1-x/M/sub x/) metallic glasses based on refractory transition metals (e.g. Mo, W, Ru etc.) have been systemically investigated as a function of composition. The structure of the alloys has been investigated by x-ray diffraction methods and measurements of superconducting properties, electrical resistivity, density, hardness, and mechanical behavior were made. These data are used in developing a novel description of the structure of TM/sub 1-x/M/sub x/ glasses. The experimental evidence suggests that an ideal amorphous phase forms at a specific composition x/sub c/ and that this phase has a well defined atomic short range order. For metallic glasses having x x/sub c/. This novel picture can explain the variation of many properties of these glasses with metalloid concentration

  12. Treatment of Tehran refinery wastewater using rotating biological contactor

    Energy Technology Data Exchange (ETDEWEB)

    Ghazi, Masoud; Mirsajadi, Hassan; Ganjidoust, Hossien [Tarbeyat Modarres Univ., Teheran (Iran, Islamic Republic of). Environmental Engineering Dept.

    1993-12-31

    Tehran Refinery is a large plant which produces several petroleum products. The wastewaters are generated from several different refinery processes and units. Because of the wastewaters uniqueness they need to be treated in each specific plant. Currently, an activated sludge system is the main biological wastewater treatment process in Tehran refinery plant. A study was initiated in order to find a more suitable and reliable process which can produce a better treated effluent which might, in case the process be successful, be reused for irrigation lands. 5 refs., 5 figs.

  13. Api Energia IGCC plant is fully integrated with refinery

    Energy Technology Data Exchange (ETDEWEB)

    Del Bravo, R. [api Energia, Rome (Italy); Trifilo, R. [ABB Sadelmi, Milan (Italy); Chiantore, P.V. [api anonima petroli Italiania Spa, Rome (Italy); Starace, F. [ABB Power Generation, Baden (Switzerland); O`Keefe, L.F. [Texico, White Plains (United States)

    1998-06-01

    The api Energia integrated gasification combined cycle (IGCC) plant being built at Falconara Marittima, on Italy`s Adriatic coast, is one of the three IGCC plants under construction in Italy following the liberalization of the electricity production sector. The plant will take 59.2 t/h of high sulphur heavy oil produced by the Falconara refinery, convert it to syngas and use the gas to generate 280 MW of electricity, plus steam and other gases for use in the refinery. The IGCC plant will be highly integrated into the refining process, with a large number of interchanges between the IGCC unit and the rest of the refinery. (author)

  14. Treatment of Tehran refinery wastewater using rotating biological contactor

    Energy Technology Data Exchange (ETDEWEB)

    Ghazi, Masoud; Mirsajadi, Hassan; Ganjidoust, Hossien [Tarbeyat Modarres Univ., Teheran (Iran, Islamic Republic of). Environmental Engineering Dept.

    1994-12-31

    Tehran Refinery is a large plant which produces several petroleum products. The wastewaters are generated from several different refinery processes and units. Because of the wastewaters uniqueness they need to be treated in each specific plant. Currently, an activated sludge system is the main biological wastewater treatment process in Tehran refinery plant. A study was initiated in order to find a more suitable and reliable process which can produce a better treated effluent which might, in case the process be successful, be reused for irrigation lands. 5 refs., 5 figs.

  15. Refinery expansion and upgrading: Trends and needs

    International Nuclear Information System (INIS)

    Sloan, D.E.

    1993-01-01

    Much of the world's reserves of heavy, high sulfur crude oil are located in the western hemisphere. One may look from north to south and find these types of crudes. in Canada, there are the vast deposits of tar sands and other heavy oils. In the United States we find heavy, high sulfur crude in California's San joaquin Valley, the Rockies' shale oil deposits and in other areas. Moving south, Mexico's Maya crude is well known to refiners, as are the heavy crudes of Venezuela's Orinoco Belt. On the other hand, many refineries outside the United States are limited in their ability to handle heavy, high sulfur crudes either because of metallurgy or processing configurations

  16. Electrometallurgy of copper refinery anode slimes

    Science.gov (United States)

    Scott, J. D.

    1990-08-01

    High-selenium copper refinery anode slimes form two separate and dynamically evolving series of compounds with increasing electrolysis time. In one, silver is progressively added to non-stoichiometric copper selenides, both those originally present in the anode and those formed subsequently in the slime layer, and in the other, silver-poor copper selenides undergo a dis-continuous crystallographic sequence of anodic-oxidative transformations. The silver-to-selenium molar ratio in the as-cast anode and the current density of electrorefining can be used to construct predominance diagrams for both series and, thus, to predict the final bulk “mineralogy” of the slimes. Although totally incorrect in detail, these bulk data are sufficiently accurate to provide explanations for several processing problems which have been experienced by Kidd Creek Division, Falconbridge Ltd., in its commercial tankhouse. They form the basis for a computer model which predicts final cathode quality from chemical analyses of smelter feed.

  17. All-Metallic Vertical Transistors Based on Stacked Dirac Materials

    OpenAIRE

    Wang, Yangyang; Ni, Zeyuan; Liu, Qihang; Quhe, Ruge; Zheng, Jiaxin; Ye, Meng; Yu, Dapeng; Shi, Junjie; Yang, Jinbo; Lu, Jing

    2014-01-01

    It is an ongoing pursuit to use metal as a channel material in a field effect transistor. All metallic transistor can be fabricated from pristine semimetallic Dirac materials (such as graphene, silicene, and germanene), but the on/off current ratio is very low. In a vertical heterostructure composed by two Dirac materials, the Dirac cones of the two materials survive the weak interlayer van der Waals interaction based on density functional theory method, and electron transport from the Dirac ...

  18. Model for managing water in oil refineries based in Strategic Choice Approach; Modelo para gerenciamento de aguas em refinarias de petroleo atraves do 'Strategic Choice Approach'

    Energy Technology Data Exchange (ETDEWEB)

    Sobral, Marcos Felipe Falcao; Morais, Danielle Costa [Universidade Federal de Pernambuco (UFPE), Recife, PE (Brazil)

    2008-07-01

    Like all natural resources, the water has more space on the staff of debates in the business because of the scenarios current and future trends that point to the high costs related to its capitation, use and disposal. As an essential input in various industrial activities, in special way in the process of refining oil, the correct management of water resources becomes a challenge ahead is to be observed in the actions of these strategic industries. So there is needs to structure the problem before solve it, considering the various uncertainties related to decision environmental, it is evident the need a method to assist policy makers in the generation of alternatives for water management in these enterprises. Thus, this work aims to propose a model for managing water in oil refineries, using the Strategic Choice Approach. (author)

  19. Evaluation of wetlands designed to transfer and transform selected metals in an aqueous matrix

    International Nuclear Information System (INIS)

    Hawkins, W.B.; Gillespie, W.B. Jr.; Rodgers, J.H. Jr.

    1995-01-01

    Constructed wetlands can be used as an alternative to traditional wastewater treatment. Two wetlands were constructed at a Louisiana petroleum refinery and were used to study transfers and transformations of selected metals (Zn, Pb, and Cu) in a refinery effluent. In order to optimize metal removal from the aqueous matrix and subsequently decrease metal bioavailability, the hydroperiod, hydrosoil, and vegetation were specifically selected and incorporated into the wetland design. To test the metal removal efficiency of the constructed wetlands, refinery effluent was amended with 4 mg Zn/L as ZnCl 2 for 150 d. From influent to effluent, average total recoverable and soluble zinc concentrations decreased by 41 and 72%, respectively. Toxicity tests (7 d) using Ceriodaphnia dubia and Pimephales promelas illustrated a decrease in zinc bioavailability. Average C. dubia survival increased from 0--73% as a result of wetland treatment; for P. promelas, the increase in average survival was 37--94%. Based upon this field experiment, constructed wetlands can be specifically designed for zinc removal and concomitant decreases in toxicity

  20. Surface plasmons based terahertz modulator consisting of silicon-air-metal-dielectric-metal layers

    Science.gov (United States)

    Wang, Wei; Yang, Dongxiao; Qian, Zhenhai

    2018-05-01

    An optically controlled modulator of the terahertz wave, which is composed of a metal-dielectric-metal structure etched with circular loop arrays on both the metal layers and a photoexcited silicon wafer separated by an air layer, is proposed. Simulation results based on experimentally measured complex permittivities predict that modification of complex permittivity of the silicon wafer through excitation laser leads to a significant tuning of transmission characteristics of the modulator, forming the modulation depths of 59.62% and 96.64% based on localized surface plasmon peak and propagating surface plasmon peak, respectively. The influences of the complex permittivity of the silicon wafer and the thicknesses of both the air layer and the silicon wafer are numerically studied for better understanding the modulation mechanism. This study proposes a feasible methodology to design an optically controlled terahertz modulator with large modulation depth, high speed and suitable insertion loss, which is useful for terahertz applications in the future.

  1. Graphite-based extinguishants for liquid metal fires

    International Nuclear Information System (INIS)

    Simpson, J.M.; Gardener, N.J.L.

    1987-01-01

    Effective extinguishants for liquid alkali metal fires must be provided for all LMFBRs. Traditional sodium salt based extinguishants have disadvantages. An intercalation compound of graphite was identified as a possible alternative. Following successful tests on fires of up to 25 m 2 area the graphite based extinguishant has been introduced by the UKAEA at Dounreay. (author)

  2. Artificial tongue based on metal-biomolecule coordination polymer nanoparticles.

    Science.gov (United States)

    Pu, Fang; Ran, Xiang; Ren, Jinsong; Qu, Xiaogang

    2016-02-25

    We construct an array-based recognition system (the so-called artificial tongue) through the self-assembly of nucleotides, dyes and lanthanide ions. Metal ions are selected as model analytes for verifying its discrimination ability. The work provides valuable insights into the application and development of biomolecule-based materials.

  3. Metal hydride-based thermal energy storage systems

    Science.gov (United States)

    Vajo, John J.; Fang, Zhigang

    2017-10-03

    The invention provides a thermal energy storage system comprising a metal-containing first material with a thermal energy storage density of about 1300 kJ/kg to about 2200 kJ/kg based on hydrogenation; a metal-containing second material with a thermal energy storage density of about 200 kJ/kg to about 1000 kJ/kg based on hydrogenation; and a hydrogen conduit for reversibly transporting hydrogen between the first material and the second material. At a temperature of 20.degree. C. and in 1 hour, at least 90% of the metal is converted to the hydride. At a temperature of 0.degree. C. and in 1 hour, at least 90% of the metal hydride is converted to the metal and hydrogen. The disclosed metal hydride materials have a combination of thermodynamic energy storage densities and kinetic power capabilities that previously have not been demonstrated. This performance enables practical use of thermal energy storage systems for electric vehicle heating and cooling.

  4. Integration : OPEC is now in 35 foreign refineries

    International Nuclear Information System (INIS)

    Terzian, P.

    1994-01-01

    Seven countries from OPEC own now share holdings in 35 foreign refineries. By this process of downstream reintegration, these countries hope to reach a better stability of crude oil prices. (Author). 3 tabs

  5. Influence of ownership capital structure of Refinery's operation and development

    International Nuclear Information System (INIS)

    Hadzhi-Mishev, Dimitar

    1999-01-01

    Refineries are part of the energetic infrastructure of one country. Their significance is dependent on the geographic country position (whether it has sea exit or not), and on structure of primary energy spends in the country. According these facts, country's attitude to the refineries on its territory could be different. The possibility of ownership structure transformation in refineries and necessary legislation in the energetic sector of the state, needed for transformation realization are analyzed in this paper. Essential conditions for transformation fulfilling are protection 'mechanisms for domestic production in crude oil economy, manners of crude oil products price defining, and manners of excise determination and payment. As a function of these conditions, the conditions under which transformation of ownership structure in refineries is possible, as well as their influence on the operation and development of this part of energetic structure in transition country are defined in this paper. (Original)

  6. Assessment of the effect of effluent discharge from coffee refineries ...

    African Journals Online (AJOL)

    Admin

    2Department of Environmental Health, Jimma University, Jimma, Ethiopia. ... cherries, transport them hydraulically through the pulping ..... Table 2. Interaction effects of effluent discharges by coffee refineries on physical characteristics between.

  7. Characterization of oily sludge from a Tehran oil refinery.

    Science.gov (United States)

    Heidarzadeh, Nima; Gitipour, Saeid; Abdoli, Mohammad Ali

    2010-10-01

    In this study, oily sludge samples generated from a Tehran oil refinery (Pond I) were evaluated for their contamination levels and to propose an adequate remediation technique for the wastes. A simple, random, sampling method was used to collect the samples. The samples were analyzed to measure Total petroleum hydrocarbon (TPH), polyaromatic hydrocarbon (PAH) and heavy metal concentrations in the sludge. Statistical analysis showed that seven samples were adequate to assess the sludge with respect to TPH analyses. The mean concentration of TPHs in the samples was 265,600 mg kg⁻¹. A composite sample prepared from a mix of the seven samples was used to determine the sludge's additional characteristics. Composite sample analysis showed that there were no detectable amounts of PAHs in the sludge. In addition, mean concentrations of the selected heavy metals Ni, Pb, Cd and Zn were 2700, 850, 100, 6100 mg kg⁻¹, respectively. To assess the sludge contamination level, the results from the analysis above were compared with soil clean-up levels. Due to a lack of national standards for soil clean-up levels in Iran, sludge pollutant concentrations were compared with standards set in developed countries. According to these standards, the sludge was highly polluted with petroleum hydrocarbons. The results indicated that incineration, biological treatment and solidification/stabilization treatments would be the most appropriate methods for treatment of the sludges. In the case of solidification/stabilization, due to the high organic content of the sludge, it is recommended to use organophilic clays prior to treatment of the wastes.

  8. Plasmonic modulator based on thin metal-semiconductor-metal waveguide with gain core

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Malureanu, Radu; Lavrinenko, Andrei

    2013-01-01

    We focus on plasmonic modulators with a gain core to be implemented as active nanodevices in photonic integrated circuits. In particular, we analyze metal–semiconductor–metal (MSM) waveguides with InGaAsP-based active material layers. A MSM waveguide enables high field localization and therefore...

  9. Biomaterial based novel polyurethane adhesives for wood to wood and metal to metal bonding

    Directory of Open Access Journals (Sweden)

    Mitesh Ramanlal Patel

    2009-01-01

    Full Text Available Polyurethane adhesives made from synthetic chemicals are non-biodegradable, costly and difficult to find raw materials from local market. To avoid solid pollution problem, cost effectiveness and easy availability of raw materials, biomaterials based polyurethane adhesives are used in current industrial interest. Direct use of castor oil in polyurethane adhesive gives limited hardness. Modification on active sites of castor oil to utilize double bond of unsaturated fatty acid and carboxyl group yields new modified or activated polyols, which can be utilized for polyurethane adhesive formulation. In view of this, we have synthesized polyurethane adhesives from polyester polyols, castor oil based polyols and epoxy based polyols with Isocyanate adducts based on castor oil and trimethylolpropane. To study the effects of polyurethane adhesive strength (i.e. lap shear strength on wood-to-wood and metal-to-metal bonding through various types of polyols, cross-linking density, isocyanate adducts and also to compare adhesive strength between wood to wood and metal to metal surface. These polyols and polyurethanes were characterized through GPC, NMR and IR-spectroscopy, gel and surface drying time. Thermal stability of PU adhesives was determined under the effect of cross-linking density (NCO/OH ratio. The NCO/OH ratio (1.5 was optimized for adhesives as the higher NCO/OH ratio (2.0 increasing cross-linking density and decreases adhesion. Lower NCO/OH ratio (1.0 provideslow cross-linking density and low strength of adhesives.

  10. Opportunities and challenges at the interface between petrochemistry and refinery. Preprints

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, S.; Leitner, W.; Lercher, J.A.; Nees, F.; Perego, C.; Rupp, M.; Santacesaria. E. (eds.)

    2007-07-01

    Within the DGMK/SCI-Conference 'Opportunities and Challenges at the Interface between Petrochemistry and refinery' between 10th and 12th October, 2007, in Hamburg (Federal Republic of Germany) the following lectures were held: (a) Maximizing petrochemicals from refineries (B. Glover, T. Foley, S. Frey); (b) Opportunities and challenges at the interface between petrochemistry and refinery - the OMV view (J. Lichtscheidl); (c) Aspects of petrochemistry in a fuels refinery (J. Essler, J. Mielicke, T. Maier); (d) Enhanced propylene production in FCC by novel catalytic materials (C.P. Kelkar, D. Harris, M. Xu, J. Fu); (e) Retrofit of an MTBE-unit to ETBE (A. Rix, U. Peters); (f) Opportunities and challenges at the interface between petrochemistry and refinery - The BASF perspectives (H.-J. Blankertz); (g) Light olefins - challenges from new production routes? (H. Zimmermann); (h) Conversion of heavy aromatic hydrocarbons to valuable synthetic feed for steamcrackers (A. Cesana, L. Dalloro, F. Rivetti, R. Buzzoni, R. Bignazzi); (i) C{sub 4} olefin/paraffin separation over the metal organic framework material Cu{sub 3}BTC{sub 2} (S. Kunz, O. Tangermann, M. Hartmann); (j) Glycerol tertiary butyl ethers via etherification of glycerol with isobutene (A. Behr); (k) Biorefineries: From concepts to reality? (K. Wagemann); (l) Modern concepts in reactor and separation technologies (D. Agar); (m) Innovative reactive distillation process for the production of the MTBE substitute isooctane from isobutene (M. Chalakova, R. Kaur, H. Freund, S. Mahajani, K. Sundmacher); (n) Supported ionic liquid phase (SILP) systems - novel fixed bed reactor concepts for homogeneous catalysis (A. Riisager, R. Fehrmann, M. Haumann, M. Jakuttis, J. Joni, P. Wasserscheid); (o) Selective oxidations to industrial intermediates (S. Schunck); (p) Perspectives of industrial realization for propane oxidative dehydrogenation over chromium oxide catalysts (A.L. Lapidus, N.A. Gaidai, Yu. A. Agafonov, M

  11. Optimal Renewable Energy Integration into Refinery with CO2 Emissions Consideration: An Economic Feasibility Study

    Science.gov (United States)

    Alnifro, M.; Taqvi, S. T.; Ahmad, M. S.; Bensaida, K.; Elkamel, A.

    2017-08-01

    With increasing global energy demand and declining energy return on energy invested (EROEI) of crude oil, global energy consumption by the O&G industry has increased drastically over the past few years. In addition, this energy increase has led to an increase GHG emissions, resulting in adverse environmental effects. On the other hand, electricity generation through renewable resources have become relatively cost competitive to fossil based energy sources in a much ‘cleaner’ way. In this study, renewable energy is integrated optimally into a refinery considering costs and CO2 emissions. Using Aspen HYSYS, a refinery in the Middle East was simulated to estimate the energy demand by different processing units. An LP problem was formulated based on existing solar energy systems and wind potential in the region. The multi-objective function, minimizing cost as well as CO2 emissions, was solved using GAMS to determine optimal energy distribution from each energy source to units within the refinery. Additionally, an economic feasibility study was carried out to determine the viability of renewable energy technology project implementation to overcome energy requirement of the refinery. Electricity generation through all renewable energy sources considered (i.e. solar PV, solar CSP and wind) were found feasible based on their low levelized cost of electricity (LCOE). The payback period for a Solar CSP project, with an annual capacity of about 411 GWh and a lifetime of 30 years, was found to be 10 years. In contrast, the payback period for Solar PV and Wind were calculated to be 7 and 6 years, respectively. This opens up possibilities for integrating renewables into the refining sector as well as optimizing multiple energy carrier systems within the crude oil industry

  12. Thermal behaviors of liquid La-based bulk metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, D. W.; Wang, X. D., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn; Lou, H. B.; Cao, Q. P.; Jiang, J. Z., E-mail: wangxd@zju.edu.cn, E-mail: jiangjz@zju.edu.cn [International Center for New-Structured Materials (ICNSM), Laboratory of New-Structured Materials, State Key Laboratory of Silicon Materials, and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Wang, L. W. [Institute of Materials Science and Engineering, Lanzhou University, Lanzhou 730000 (China); Zhang, D. X. [State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027 (China)

    2014-12-14

    Thermal behaviors of liquid La-based bulk metallic glasses have been measured by using the dilatometer with a self-sealed sample cell. It is demonstrated that the strong glass forming liquid not only has the small thermal expansion coefficient but also shows the slow variation rate. Moreover, the strong glass former has relatively dense atomic packing and also small density change in the liquid state. The results suggest that the high glass forming ability of La-based metallic glasses would be closely related to the slow atomic rearrangements in liquid melts.

  13. Taking inventory on VOC releases from Amoco's Yorktown refinery

    International Nuclear Information System (INIS)

    Klee, H.H. Jr.; Schmitt, R.E.; Harrass, M.C.; Podar, M.K.

    1996-01-01

    Amoco's Yorktown, Virginia, refinery is a 35-year-old, 53,000 bbl/day facility that manufacturers gasoline, heating oil, liquid petroleum gas, sulfur, and coke. In a cooperative and voluntary effort, Amoco Corporation and the US Environmental Protection Agency conducted a joint project to study pollution prevention opportunities at an operating industrial facility. Source reduction efforts--key to pollution prevention strategies--require knowledge of specific sources of releases. However, data on releases from individual process units are limited in favor of data to monitor existing end-of-pipe pollution control requirements. The study's sampling program sought to portray the distribution of releases within the refinery, their management within the refinery, and ultimate releases leaving the refinery. Subsequent tests of blowdown stack and fugitive emissions further improved total release estimates. The initial study estimated that the refinery generates about 25,000 metric tons (t)/year of potential pollutants. Of these, about half are released from the refinery as airborne, waterborne, or land-disposed releases. Airborne releases comprise the majority of releases by mass, about 12,000 t/year. Most of the airborne releases are volatile organic compound hydrocarbons. The inventory sampling project and subsequent work identified differences with Toxic Release Inventory (TRI) values and standard emission factors (AP-42). The inventory and other data provided an opportunity to consider options for, and limitations of, specific pollution prevention or source reduction strategies

  14. Assessment of Petroleum Leakage in Groundwater of the Abadan Refinery

    Directory of Open Access Journals (Sweden)

    Seyed Reza Shadizadeh

    2010-06-01

    Full Text Available Knowledge of petroleum leakage at oil refineries is vital for environmental study of water and soil pollution. Abadan Refinery is located between the Arvandrud and Bahmanshir rivers in the highly populated area of Abadan city. These rivers supply domestic, industrial, and agricultural water toAbadancity. During the war betweenIranandIraq, enormous volumes of oil and petroleum products leaked from storage tanks and pipelines at Abadan Refinery into the surrounding environment. The resulting pollution is a serious threat and a growing environmental concern for the region. In this work, twenty boreholes were dug to investigate petroleum leaks into the surrounding area both during and after the war. The thickness of petroleum floating on underground waters at the refinery was measured by sampling underground water over a period of one year along with measuring the piezometric heads of groundwater monitoring wells. Also, groundwater movement pattern at Abadan Refinery was determined by measuring the water table in each well over the same period. The results of sampling indicate that oil leaks were observed in just two wells; namely, wells No.3 and No.11. The results also show that the greatest portion of the oil spill in underground layers at Abadan Refinery was absorbed into clay soil.

  15. Production and properties of light-metal base amorphous alloys

    International Nuclear Information System (INIS)

    Inoue, Akihisa; Masumoto, Tsuyoshi

    1993-01-01

    Light-metal base alloys with high specific strength and good corrosion resistance were produced through amorphization of Al and Mg-based alloys. The amorphous phase is formed in rapidly solidified Al-TM-Ln and Mg-TM-Ln (TM=transition metal, Ln=lanthanide metal) alloys. The highest tensile strength (σ f ) reaches 1,330 MPa for the Al base and 830 MPa for the Mg base. Furthermore, the Mg-based alloys have a large glass-forming capacity which enables to produce an amorphous phase by a metallic mold casting method. The extrusion of the Al-based amorphous powders at temperatures above crystallization temperature caused the formation of high strength materials with finely mixed structure consisting of dispersed intermetallic compounds in an Al matrix. The highest values of σ f and fatigue limit are as high as 940 and 313 MPa, respectively, at room temperature and 520 and 165 MPa at 473 K. The extruded Al-Ni-Mm alloy has already been used as machine parts and subsequent further development as practical materials is expected by taking these advantages

  16. Antimicrobial resistance challenged with metal-based antimicrobial macromolecules.

    Science.gov (United States)

    Abd-El-Aziz, Alaa S; Agatemor, Christian; Etkin, Nola

    2017-02-01

    Antimicrobial resistance threatens the achievements of science and medicine, as it deactivates conventional antimicrobial therapeutics. Scientists respond to the threat by developing new antimicrobial platforms to prevent and treat infections from these resistant strains. Metal-based antimicrobial macromolecules are emerging as an alternative to conventional platforms because they combine multiple mechanisms of action into one platform due to the distinctive properties of metals. For example, metals interact with intracellular proteins and enzymes, and catalyse various intracellular processes. The macromolecular architecture offers a means to enhance antimicrobial activity since several antimicrobial moieties can be conjugated to the scaffold. Further, these macromolecules can be fabricated into antimicrobial materials for contact-killing medical implants, fabrics, and devices. As volatilization or leaching out of the antimicrobial moieties from the macromolecular scaffold is reduced, these medical implants, fabrics, and devices can retain their antimicrobial activity over an extended period. Recent advances demonstrate the potential of metal-based antimicrobial macromolecules as effective platforms that prevent and treat infections from resistant strains. In this review these advances are thoroughly discussed within the context of examples of metal-based antimicrobial macromolecules, their mechanisms of action and biocompatibility. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Materials And Carbon Flow In A Waste Refinery Process Using Enzymes

    DEFF Research Database (Denmark)

    Tonini, Davide; Woods, M.; Astrup, Thomas

    2011-01-01

    Recovery of resources from mixed Municipal Solid Waste (MSW) is a crucial aspect of waste management practices. In this paper the materials and carbon flows of an innovative waste refinery process using enzymes are presented. Through enzymatic treatment the process produces two main streams from...... the initial mixed MSW: a bioslurry (liquefied paper and organics) and a solid fraction (non-degradable materials). The discussion is based on the performance of the process in separating recyclables and recovery Cbiogenic as well as nutrients from the input MSW. The results of MFA and SFA illustrate...... that the waste refinery has great potential for resource recovery: about 100% of the Cbiogenic and up to 90% of N and P can potentially be recovered in the bioslurry and returned to land after anaerobic digestion. Recovery of ferrous and non-ferrous material is estimated double compared to recovering the same...

  18. Charge transport in metal oxide nanocrystal-based materials

    Science.gov (United States)

    Runnerstrom, Evan Lars

    There is probably no class of materials more varied, more widely used, or more ubiquitous than metal oxides. Depending on their composition, metal oxides can exhibit almost any number of properties. Of particular interest are the ways in which charge is transported in metal oxides: devices such as displays, touch screens, and smart windows rely on the ability of certain metal oxides to conduct electricity while maintaining visible transparency. Smart windows, fuel cells, and other electrochemical devices additionally rely on efficient transport of ionic charge in and around metal oxides. Colloidal synthesis has enabled metal oxide nanocrystals to emerge as a relatively new but highly tunable class of materials. Certain metal oxide nanocrystals, particularly highly doped metal oxides, have been enjoying rapid development in the last decade. As in myriad other materials systems, structure dictates the properties of metal oxide nanocrystals, but a full understanding of how nanocrystal synthesis, the processing of nanocrystal-based materials, and the structure of nanocrystals relate to the resulting properties of nanocrystal-based materials is still nascent. Gaining a fundamental understanding of and control over these structure-property relationships is crucial to developing a holistic understanding of metal oxide nanocrystals. The unique ability to tune metal oxide nanocrystals by changing composition through the introduction of dopants or by changing size and shape affords a way to study the interplay between structure, processing, and properties. This overall goal of this work is to chemically synthesize colloidal metal oxide nanocrystals, process them into useful materials, characterize charge transport in materials based on colloidal metal oxide nanocrystals, and develop ways to manipulate charge transport. In particular, this dissertation characterizes how the charge transport properties of metal oxide nanocrystal-based materials depend on their processing and

  19. Spintronic materials and devices based on antiferromagnetic metals

    OpenAIRE

    Wang, Y.Y.; Song, C.; Zhang, J.Y.; Pan, F.

    2017-01-01

    In this paper, we review our recent experimental developments on antiferromagnet (AFM) spintronics mainly comprising Mn-based noncollinear AFM metals. IrMn-based tunnel junctions and Hall devices have been investigated to explore the manipulation of AFM moments by magnetic fields, ferromagnetic materials and electric fields. Room-temperature tunneling anisotropic magnetoresistance based on IrMn as well as FeMn has been successfully achieved, and electrical control of the AFM exchange spring i...

  20. DFT study on metal-mediated uracil base pair complexes

    Directory of Open Access Journals (Sweden)

    Ayhan Üngördü

    2017-11-01

    Full Text Available The most stable of metal-mediated uracil base pair complexes were determined. Method was used density functional theory, B3LYP. The calculations of systems containing C, H, N, O were described by 6-311++G(d,p and cc-PVTZ basis sets and LANL2DZ and SDD basis sets was used for transition metals. Then Egap values of complexes were calculated and the electrical conductivity of the complexes for single nanowires was studied by band theory. Metal-mediated uracil base pair complexes which will be used as conductive wires in nanotechnology were predicted. In nanoworld, this study is expected to show a way for practical applications.

  1. WATER PINCH TECHNOLOGY APPLICATION TO MINIMIZE SULPHUROUS WASTEWATER IN AN OIL REFINERY

    Directory of Open Access Journals (Sweden)

    Gabriel Orlando Lobelles Sardiñas

    2017-01-01

    Full Text Available In oil refining industries there is a high water consumption, which influences the high production costs and impacts the environment due to the discharge of their wastes. It is known that there are no technological conditions for the reuse of industrial water at the oil refineries, based on hydroskimming processes. The objective of this study is to implement the process integration methodology, Water Pinch, to a sour water stripper unit, as a unitary process of an oil refinery, to minimize the amount of sulphurous waste water and reduce contamination of the bay that receives these wastes. The technology is applied to evaluate the volume of sulphurous wastewater generated in the Cienfuegos oil refinery. This technology allows identifying opportunities for recovery and reuse of water, based on concentration ranges of contaminants. To achieve this purpose, a sour water stripper tower was assessed with the help of Water Pinch software, which provided an optimized distribution network, as a proposed technological improvement. This facilitated to recover and reuse 667 757, 28 m3 of water per year, and 1 035 023, 78 CUC were saved, at the same time the amount of polluting effluents decreased in approximately 2 % of non-reusable treated water.

  2. Halide based MBE of crystalline metals and oxides

    Energy Technology Data Exchange (ETDEWEB)

    Greenlee, Jordan D.; Calley, W. Laws; Henderson, Walter; Doolittle, W. Alan [Georgia Institute of Technology, School of Electrical and Computer Engineering, Atlanta, Georgia (United States)

    2012-02-15

    A halide based growth chemistry has been demonstrated which can deliver a range of transition metals using low to moderate effusion cell temperatures (30-700 C) even for high melting point metals. Previously, growth with transition metal species required difficult to control electron beam or impurity inducing metal organic sources. Both crystalline oxide and metal films exhibiting excellent crystal quality are grown using this halide-based growth chemistry. Films are grown using a plasma assisted Molecular Beam Epitaxy (MBE) system with metal-chloride precursors. Crystalline niobium, cobalt, iron, and nickel were grown using this chemistry but the technology can be generalized to almost any metal for which a chloride precursor is available. Additionally, the oxides LiNbO{sub 3} and LiNbO{sub 2} were grown with films exhibiting X-ray diffraction (XRD) rocking curve full-widths at half maximum of 150 and 190 arcseconds respectively. LiNbO{sub 2} films demonstrate a memristive response due to the rapid movement of lithium in the layered crystal structure. The rapid movement of lithium ions in LiNbO{sub 2} memristors is characterized using impedance spectroscopy measurements. The impedance spectroscopy measurements suggest an ionic current of.1 mA for a small drive voltage of 5 mV AC or equivalently an ionic current density of {proportional_to}87 A/cm{sup 2}. This high ionic current density coupled with low charge transfer resistance of {proportional_to}16.5 {omega} and a high relaxation frequency (6.6 MHz) makes this single crystal material appealing for battery applications in addition to memristors. (copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. A transparent electrode based on a metal nanotrough network.

    Science.gov (United States)

    Wu, Hui; Kong, Desheng; Ruan, Zhichao; Hsu, Po-Chun; Wang, Shuang; Yu, Zongfu; Carney, Thomas J; Hu, Liangbing; Fan, Shanhui; Cui, Yi

    2013-06-01

    Transparent conducting electrodes are essential components for numerous flexible optoelectronic devices, including touch screens and interactive electronics. Thin films of indium tin oxide-the prototypical transparent electrode material-demonstrate excellent electronic performances, but film brittleness, low infrared transmittance and low abundance limit suitability for certain industrial applications. Alternatives to indium tin oxide have recently been reported and include conducting polymers, carbon nanotubes and graphene. However, although flexibility is greatly improved, the optoelectronic performance of these carbon-based materials is limited by low conductivity. Other examples include metal nanowire-based electrodes, which can achieve sheet resistances of less than 10Ω □(-1) at 90% transmission because of the high conductivity of the metals. To achieve these performances, however, metal nanowires must be defect-free, have conductivities close to their values in bulk, be as long as possible to minimize the number of wire-to-wire junctions, and exhibit small junction resistance. Here, we present a facile fabrication process that allows us to satisfy all these requirements and fabricate a new kind of transparent conducting electrode that exhibits both superior optoelectronic performances (sheet resistance of ~2Ω □(-1) at 90% transmission) and remarkable mechanical flexibility under both stretching and bending stresses. The electrode is composed of a free-standing metallic nanotrough network and is produced with a process involving electrospinning and metal deposition. We demonstrate the practical suitability of our transparent conducting electrode by fabricating a flexible touch-screen device and a transparent conducting tape.

  4. Schiff base transition metal complexes for Suzuki–Miyaura cross

    Indian Academy of Sciences (India)

    Schiff base ligand and its complex with iron (Fe), cobalt (Co), nickel (Ni) and copper (Cu) ions were synthesized using 4-aminoacetophenone and salicylaldehyde and characterized. FTIR spectrum shows that bidentate coordination of metal ions with ligand where O, N are electron donating sites of azomethine group.

  5. Indicator minerals as guides to base metal sulphide mineralisation ...

    Indian Academy of Sciences (India)

    Zn-bearing minerals that act as indicator minerals for base metal sulphide mineralization from the Proterozoic Betul Belt,central India with special emphasis on their genetic significance have been discussed.Sulphide mineralisation is hosted by the felsic volcanic rocks and has similarities with volcanic-hosted massive ...

  6. Hydrometallurgical Approach for Leaching of Metals from Copper Rich Side Stream Originating from Base Metal Production

    Directory of Open Access Journals (Sweden)

    Udit Surya Mohanty

    2018-01-01

    Full Text Available Pyrometallurgical metal production results in side streams, such as dusts and slags, which are carriers of metals, though commonly containing lower metal concentrations compared to the main process stream. In order to improve the circular economy of metals, selective leaching of copper from an intermediate raw material originating from primary base metal production plant was investigated. The raw material investigated was rich in Cu (12.5%, Ni (2.6%, Zn (1.6%, and Fe (23.6% with the particle size D80 of 124 µm. The main compounds present were nickel ferrite (NiFe2O4, fayalite (Fe2SiO4, cuprite (Cu2O, and metallic copper. Leaching was studied in 16 different solutions. The results revealed that copper phases could be dissolved with high yield (>90% and selectivity towards nickel (Cu/Ni > 7 already at room temperature with the following solutions: 0.5 M HCl, 1.5 M HCl, 4 M NaOH, and 2 M HNO3. A concentration of 4 M NaOH provided a superior selectivity between Cu/Ni (340 and Cu/Zn (51. In addition, 1–2 M HNO3 and 0.5 M HCl solutions were shown to result in high Pb dissolution (>98%. Consequently, 0.5 M HCl leaching is suggested to provide a low temperature, low chemical consumption method for selective copper removal from the investigated side stream, resulting in PLS (pregnant leach solution which is a rich in Cu and lead free residue, also rich in Ni and Fe.

  7. South Africa's refineries: waiting for Maduna

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    A definitive energy policy from the new Energy Minister, Penuell Maduna, is awaited by the petroleum industry in South Africa. Some of the complexities of the South African oil market and past legacies which make the task of producing a policy difficult, are examined here. They include the allegations made initially in 1994 that oil refineries are illegally repatriating profits by paying too much for imported products. Accusations of this transfer pricing have resurfaced in the light of recent figures published by the South African Petroleum Industry Association (SAPIA) which show that the oil industry's profitability is not as high as some had presumed. However, compelling evidence for the allegations has not appeared and it is unlikely that the foreign investors in SAPIA would endanger their operations in this way. SAPIA members are key investors in the national infrastructure and make large tax contributions much needed by the treasury. In its turn, SAPIA is unhappy about the continuation of the payment of large taxpayer funded subsidies to the privatised Sasol, the South African synthetic fuel company, seeing as anti-competitive and having negative implications for the national economy. For its part Sasol argues its entitlement to the same tariff protection enjoyed by 80% of local manufacturing industries in South Africa. Some government action has been taken to reduce the subsidies though. The oil companies in SAPIA require clarity on future energy policy and deregulation before committing themselves to further heavy capital investment and Sasol also requires an end to the present uncertainties. (UK)

  8. Catalytic hydrotreatment of refinery waste: Demonstration project

    Energy Technology Data Exchange (ETDEWEB)

    1989-01-01

    The object of this project and report is to produce liquid hydrocarbons by the catalytic hydroprocessing of solid refinery wastes (hard pitches) in order to improve the profitability of deep conversion processes and reduce the excess production of heavy fuels. The project was mostly carried out on the ASVAHL demonstration platform site, at Solaize, and hard pitches were produced primarily by deasphalting of atmospheric or vacuum distillation residues. The project includes two experimental phases and an economic evaluation study phase. In Phase 1, two granular catalysts were used to transform pitch into standard low sulfur fuel oil: a continuously moving bed, with demetallation and conversion catalyst; a fixed bed, with hydrorefining catalyst. In Phase 2 of the project, it was proven that a hydrotreatment process using a finely dispersed catalyst in the feedstock, can, under realistic operating conditions, transform with good yields hard pitch into distillates that can be refined through standard methods. In Phase 3 of the project, it was shown that the economics of such processes are tightly linked to the price differential between white'' and black'' oil products, which is expected to increase in the future. Furthermore, the evolution of environmental constraints will impel the use of such methods, thus avoiding the coproduction of polluting solid residues. 11 figs., 1 tab.

  9. Lymphohematopoietic cancer mortality and morbidity of workers in a refinery/petrochemical complex in Korea.

    Science.gov (United States)

    Koh, Dong-Hee; Kim, Tae-Woo; Yoon, Yong-Hoon; Shin, Kyung-Seok; Yoo, Seung-Won

    2011-03-01

    The purpose of this retrospective cohort study was to investigate the relationship between exposure of Korean workers to petrochemicals in the refinery/petrochemical industry and lymphohematopoietic cancers. The cohort consisted of 8,866 male workers who had worked from the 1960s to 2007 at one refinery and six petrochemical companies located in a refinery/petrochemical complex in Korea that produce benzene or use benzene as a raw material. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for 1992-2007 and 1997-2005 based on the death rate and cancer incidence rate of the Korean male population according to job title (production, maintenance, laboratory, and office workers). The overall mortality and most cause-specific mortalities were lower among these workers than those of the general Korean population. Increased SMRs were observed for leukemia (4/1.45; SMR 2.77, 95% CI: 0.75-7.09) and lymphohematopoietic cancers (5/2.51; SMR 2, 95% CI: 0.65-4.66) in production workers, and increased SIRs were also observed in leukemia (3/1.34; SIR 2.24, 95% CI: 0.46-6.54) and lymphohematopoietic cancers (5/3.39; SIR 1.47, 95% CI: 0.48-3.44) in production workers, but the results were not statistically significant. The results showed a potential relationship between leukemia and lymphohematopoietic cancers and exposure to benzene in refinery/petrochemical complex workers. This study yielded limited results due to a short observational period; therefore, a follow-up study must be performed to elucidate the relationship between petrochemical exposure and cancer rates.

  10. Chemical sensors based on molecularly modified metallic nanoparticles

    International Nuclear Information System (INIS)

    Haick, Hossam

    2007-01-01

    This paper presents a concise, although admittedly non-exhaustive, didactic review of some of the main concepts and approaches related to the use of molecularly modified metal nanoparticles in or as chemical sensors. This paper attempts to pull together different views and terminologies used in sensors based on molecularly modified metal nanoparticles, including those established upon electrochemical, optical, surface Plasmon resonance, piezoelectric and electrical transduction approaches. Finally, this paper discusses briefly the main advantages and disadvantages of each of the presented class of sensors. (review article)

  11. Additively manufactured metallic porous biomaterials based on minimal surfaces

    DEFF Research Database (Denmark)

    Bobbert, F. S. L.; Lietaert, K.; Eftekhari, Ali Akbar

    2017-01-01

    Porous biomaterials that simultaneously mimic the topological, mechanical, and mass transport properties of bone are in great demand but are rarely found in the literature. In this study, we rationally designed and additively manufactured (AM) porous metallic biomaterials based on four different...... of bone properties is feasible, biomaterials that could simultaneously mimic all or most of the relevant bone properties are rare. We used rational design and additive manufacturing to develop porous metallic biomaterials that exhibit an interesting combination of topological, mechanical, and mass...

  12. Energy reversible switching from amorphous metal based nanoelectromechanical switch

    KAUST Repository

    Mayet, Abdulilah M.; Smith, Casey; Hussain, Muhammad Mustafa

    2013-01-01

    We report observation of energy reversible switching from amorphous metal based nanoelectromechanical (NEM) switch. For ultra-low power electronics, NEM switches can be used as a complementary switching element in many nanoelectronic system applications. Its inherent zero power consumption because of mechanical detachment is an attractive feature. However, its operating voltage needs to be in the realm of 1 volt or lower. Appropriate design and lower Young's modulus can contribute achieving lower operating voltage. Therefore, we have developed amorphous metal with low Young's modulus and in this paper reporting the energy reversible switching from a laterally actuated double electrode NEM switch. © 2013 IEEE.

  13. Energy reversible switching from amorphous metal based nanoelectromechanical switch

    KAUST Repository

    Mayet, Abdulilah M.

    2013-08-01

    We report observation of energy reversible switching from amorphous metal based nanoelectromechanical (NEM) switch. For ultra-low power electronics, NEM switches can be used as a complementary switching element in many nanoelectronic system applications. Its inherent zero power consumption because of mechanical detachment is an attractive feature. However, its operating voltage needs to be in the realm of 1 volt or lower. Appropriate design and lower Young\\'s modulus can contribute achieving lower operating voltage. Therefore, we have developed amorphous metal with low Young\\'s modulus and in this paper reporting the energy reversible switching from a laterally actuated double electrode NEM switch. © 2013 IEEE.

  14. Multi-media pollution prevention: A case study of a refinery

    International Nuclear Information System (INIS)

    Schmitt, R.E.; Podar, M.K.

    1994-01-01

    In late 1989, Amoco Corporation and the United States Environmental Protection Agency began a voluntary, joint project to study pollution prevention opportunities at an industrial facility. Amoco proposed use of its refinery at Yorktown, Virginia, to conduct a multi-media assessment of releases to the environment, then to develop and evaluate options to reduce these releases. A Workgroup composed of state, federal, and Amoco representatives provided oversight to the Project. Monthly Workgroup meetings provided Project oversight, a forum for presentations on different Project components, and an opportunity for informal discussion of different viewpoints about environmental management. The Workgroup identified four objectives for this study: (1) Inventory refinery releases to the environment to define their chemical type, quantity, source, and medium of release; (2) develop options to reduce selected releases identified, as well as rank and prioritize the options based on a variety of criteria and perspectives; (3) identify and evaluate factors as technical, legislative, regulatory, institutional, permitting, and economic, that impede or encourage pollution prevention; and (4) enhance participates' knowledge of refinery and regulatory systems

  15. Metal hydrides based high energy density thermal battery

    International Nuclear Information System (INIS)

    Fang, Zhigang Zak; Zhou, Chengshang; Fan, Peng; Udell, Kent S.; Bowman, Robert C.; Vajo, John J.; Purewal, Justin J.; Kekelia, Bidzina

    2015-01-01

    Highlights: • The principle of the thermal battery using advanced metal hydrides was demonstrated. • The thermal battery used MgH 2 and TiMnV as a working pair. • High energy density can be achieved by the use of MgH 2 to store thermal energy. - Abstract: A concept of thermal battery based on advanced metal hydrides was studied for heating and cooling of cabins in electric vehicles. The system utilized a pair of thermodynamically matched metal hydrides as energy storage media. The pair of hydrides that was identified and developed was: (1) catalyzed MgH 2 as the high temperature hydride material, due to its high energy density and enhanced kinetics; and (2) TiV 0.62 Mn 1.5 alloy as the matching low temperature hydride. Further, a proof-of-concept prototype was built and tested, demonstrating the potential of the system as HVAC for transportation vehicles

  16. Quantum-based Atomistic Simulation of Transition Metals

    International Nuclear Information System (INIS)

    Moriarty, J A; Benedict, L X; Glosli, J N; Hood, R Q; Orlikowski, D A; Patel, M V; Soderlind, P; Streitz, F H; Tang, M; Yang, L H

    2005-01-01

    First-principles generalized pseudopotential theory (GPT) provides a fundamental basis for transferable multi-ion interatomic potentials in d-electron transition metals within density-functional quantum mechanics. In mid-period bcc metals, where multi-ion angular forces are important to structural properties, simplified model GPT or MGPT potentials have been developed based on canonical d bands to allow analytic forms and large-scale atomistic simulations. Robust, advanced-generation MGPT potentials have now been obtained for Ta and Mo and successfully applied to a wide range of structural, thermodynamic, defect and mechanical properties at both ambient and extreme conditions of pressure and temperature. Recent algorithm improvements have also led to a more general matrix representation of MGPT beyond canonical bands allowing increased accuracy and extension to f-electron actinide metals, an order of magnitude increase in computational speed, and the current development of temperature-dependent potentials

  17. Towards Flexible Transparent Electrodes Based on Carbon and Metallic Materials

    Directory of Open Access Journals (Sweden)

    Minghui Luo

    2017-01-01

    Full Text Available Flexible transparent electrodes (FTEs with high stability and scalability are in high demand for the extremely widespread applications in flexible optoelectronic devices. Traditionally, thin films of indium thin oxide (ITO served the role of FTEs, but film brittleness and scarcity of materials limit its further application. This review provides a summary of recent advances in emerging transparent electrodes and related flexible devices (e.g., touch panels, organic light-emitting diodes, sensors, supercapacitors, and solar cells. Mainly focusing on the FTEs based on carbon nanomaterials (e.g., carbon nanotubes and graphene and metal materials (e.g., metal grid and metal nanowires, we discuss the fabrication techniques, the performance improvement, and the representative applications of these highly transparent and flexible electrodes. Finally, the challenges and prospects of flexible transparent electrodes will be summarized.

  18. Terahertz wave manipulation with metamaterials based on metal and graphene

    DEFF Research Database (Denmark)

    Andryieuski, Andrei; Malureanu, Radu; Zalkovskij, Maksim

    2013-01-01

    response. In this presentation we overview our results on theory, fabrication and characterization of metal and graphene based metamaterials for the THz range. We show that the multiple layers of structured graphene can form a hyperbolic dispersion medium lens able to resolve the subwavelength features [2......]. We analyze the limitations and demonstrate numerically and experimentally the chiral and nonchiral thin-film metamaterial based polarization converters [3–5] and graphene total absorbers for THz radiation [6]....

  19. Enzymatic biosensors based on the use of metal oxide nanoparticles

    International Nuclear Information System (INIS)

    Shi, Xinhao; Gu, Wei; Li, Bingyu; Chen, Ningning; Zhao, Kai; Xian, Yuezhong

    2014-01-01

    Over the past decades, various techniques have been developed to obtain materials at a nanoscale level to design biosensors with high sensitivity, selectivity and efficiency. Metal oxide nanoparticles (MONPs) are of particular interests and have received much attention because of their unique physical, chemical and catalytic properties. This review summarizes the progress made in enzymatic biosensors based on the use of MONPs. Synthetic methods, strategies for immobilization, and the functions of MONPs in enzymatic biosensing systems are reviewed and discussed. The article is subdivided into sections on enzymatic biosensors based on (a) zinc oxide nanoparticles, (b) titanium oxide nanoparticles, (c) iron oxide nanoparticles, and (d) other metal oxide nanoparticles. While substantial advances have been made in MONPs-based enzymatic biosensors, their applications to real samples still lie ahead because issues such as reproducibility and sensor stability have to be solved. (author)

  20. Planning and scheduling for petroleum refineries using mathematical programming

    Directory of Open Access Journals (Sweden)

    Joly M.

    2002-01-01

    Full Text Available The objective of this paper is the development and solution of nonlinear and mixed-integer (MIP optimization models for real-world planning and scheduling problems in petroleum refineries. Firstly, we present a nonlinear planning model that represents a general refinery topology and allows implementation of nonlinear process models as well as blending relations. The optimization model is able to define new operating points, thus increasing the production of the more valuable products and simultaneously satisfying all specification constraints. The second part addresses scheduling problems in oil refineries, which are formulated as MIP optimization models and rely on both continuous and discrete time representations. Three practical applications closely related to the current refinery scenario are presented. The first one addresses the problem of crude oil inventory management of a refinery that receives several types of crude oil delivered exclusively by a single oil pipeline. Subsequently, two optimization models intended to define the optimal production policy, inventory control and distribution are proposed and solved for the fuel oil and asphalt plant. Finally, the planning model of Moro et al. (1998 is extended in order to sequence decisions at the scheduling level in the liquefied petroleum gas (LPG area for maximization of the production of petrochemical-grade propane and product delivery.

  1. Selective fluorescence sensors for detection of nitroaniline and metal Ions based on ligand-based luminescent metal-organic frameworks

    International Nuclear Information System (INIS)

    Yu, Zongchao; Wang, Fengqin; Lin, Xiangyi; Wang, Chengmiao; Fu, Yiyuan; Wang, Xiaojun; Zhao, Yongnan; Li, Guodong

    2015-01-01

    Metal-organic frameworks (MOFs) are porous crystalline materials with high potential for applications in fluorescence sensors. In this work, two solvent-induced Zn(II)–based metal-organic frameworks, Zn_3L_3(DMF)_2 (1) and Zn_3L_3(DMA)_2(H_2O)_3 (2) (L=4,4′-stilbenedicarboxylic acid), were investigated as selective sensing materials for detection of nitroaromatic compounds and metal ions. The sensing experiments show that 1 and 2 both exhibit selective fluorescence quenching toward nitroaniline with a low detection limit. In addition, 1 exhibits high selectivity for detection of Fe"3"+ and Al"3"+ by significant fluorescence quenching or enhancement effect. While for 2, it only exhibits significant fluorescence quenching effect for Fe"3"+. The results indicate that 1 and 2 are both promising fluorescence sensors for detecting and recognizing nitroaniline and metal ions with high sensitivity and selectivity. - Graphical abstract: Two MOFs have been selected as the fluorescence sensing materials for selectively sensing mitroaromatic compounds and metal ions. The high selectivity makes them promising fluorescence sensors for detecting and recognizing nitroaniline and Fe"3"+ or Al"3"+.

  2. MgNiO-based metal-semiconductor- metal ultraviolet photodetector

    International Nuclear Information System (INIS)

    Zhao Yanmin; Zhang Jiying; Jiang Dayong; Shan Chongxin; Zhang Zhenzhong; Yao Bin; Zhao Dongxu; Shen Dezhen

    2009-01-01

    In this study, we report the growth of Mg x Ni 1-x O thin films on quartz substrates by electron beam evaporation. The absorption edge shows a blue shift from 340 nm to 260 nm with increase in the Mg content from 0.2 to 0.8. A metal-semiconductor-metal structured photodetector is fabricated from the Mg 0.2 Ni 0.8 O film. At a bias of 5 V, the dark current of the photodetector is about 70 nA. The maximum responsivity is about 147.3 μA W -1 at 320 nm. In addition, the ultraviolet (UV) (320 nm) to visible (400 nm) rejection ratio is nearly two orders of magnitude. Based on these results, it is proposed that Mg x Ni 1-x O is a potential candidate for application in UV photodetectors. (fast track communication)

  3. Use of various acute, sublethal and early life-stage tests to evaluate the toxicity of refinery effluents

    International Nuclear Information System (INIS)

    Sherry, J.; Scott, B.; Dutka, B.

    1997-01-01

    The toxicities of effluents from three Ontario, Canada, refineries were assessed with microbes, plants, invertebrates, and fish. Acute toxicity was assessed by the Microtox test, an assay based on electron transport activity in submitochondrial particles, and Daphnia magna (water flea); growth of Selenastrum capricornutum (alga); growth of Lemna minor (aquatic plant); germination of Lactuca sativa (nonaquatic plant); survival, growth, and maturation of Panagrellus redivivus (nematode); and genotoxicity in the SOS-Chromotest. Only the Microtox test and the submitochondrial particle test detected acute toxicity in the effluent samples. Reduced survival and sublethal responses were caused by some effluents, but not all effluents were toxic, and none caused a response in all of the tests applied. The results suggest that the effluent treatment systems used at Ontario refineries have largely eliminated acute toxicity to the organisms in their test battery. Although reduced survival and sublethal effects were detected in some of the effluents, the effects were minor. Some of the tests provided evidence, albeit weak, of variations in the responses of the test organisms to a temporal series of effluent samples. Not unexpectedly, there were also minor differences in the responses of the tests to effluents from the three refineries. The fathead minnow test seems to be a sensitive indicator of the sublethal toxicity of Ontario refinery effluents

  4. Infrared plasmonic nano-lasers based on Metal Insulator Metal waveguides

    NARCIS (Netherlands)

    Hill, M.T.

    2010-01-01

    We will present our latest results on metal-insulator-metal waveguide devices, in particular reducing the dimensions of devices and distributed feedback lasers. Also we will examine potential useful applications for metal nano-lasers.

  5. Operational planning of refineries; Planejamento operacional de refinarias

    Energy Technology Data Exchange (ETDEWEB)

    Sinay, Maria Cristina Fogliatti de [Instituto Militar de Engenharia (IME), Rio de Janeiro, RJ (Brazil); Bueno, Catia [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2004-07-01

    The activities integration that compose the petroleum logistic chain makes more complex its planning which is normally done in a joined level, using operation research models in order to find optimized solutions. When this integrated planning is repassed to the companies and its constitutes parts (mainly refinery) uncertainness are generated about the solution that will be adopted in case of new restrictions appear. Then, the purpose of this work is propose a procedure that is capable to adequate and specifies optimized solutions presented by corporative model to refinery operations, using 'What-if' and deterministic simulation technique with optimization. To achieve this objective will be analysed typical activities in refineries and basic principles to their operational planning. (author)

  6. Fitting partially upgraded oils into pipelines and refinery markets

    International Nuclear Information System (INIS)

    Flaherty, G.

    2000-01-01

    The logistics of transporting partially upgraded crudes in feeder and trunk pipeline systems is discussed. Logistic alternatives are evaluated against economic drivers for partial upgrading, and the impact of crude transportation logistics on the quality of crude that reaches refinery gates is assessed. The potential advantages of partial upgrading in the field are reviewed (including reduction of diluent required to meet pipeline density and viscosity specifications, cost and availability of diluent, limitations in diluent transportation infrastructure, increased chemical stability, increased attractiveness to refineries, shortage of refinery coking capacity, higher market value). The pros and cons of various upgrading processes, and the implications of each for producers and refiners are explained. The advantages of moving to large common streams, as opposed to the concept of 'boutique' crudes, are stressed as the surest way for producers to realize the maximum value of partially upgraded crudes

  7. Liquid metal-based reconfigurable and stretchable photolithography

    International Nuclear Information System (INIS)

    Kim, Daeyoung; Yoo, Jun Hyeon; Lee, Jeong-Bong

    2016-01-01

    Conventional ultraviolet (UV) lithography typically uses a photomask made of a fused silica plate covered with a layer of UV opaque material such as chromium. The photomask has passive binary patterns of UV opaque and UV transparent regions and the pattern is unalterable. We report a novel real-time dynamically reconfigurable photomask technology using a liquid metal (as a UV opaque material) filled in polydimethylsiloxane (PDMS, as a UV transparent material) microfluidic channels. We found that the gallium-based liquid metal (e.g. Galinstan ® ) is opaque in broad spectrum of light in the wavelength from 325 nm to 850 nm while the PDMS is highly transparent in this wide range of spectrum. We made both bright field and dark field microfluidic photomasks and transferred various patterns onto a positive photoresist. A 7-segment display microfluidic channel photomask was also fabricated and decimal numerals (from ‘0’ to ‘9’) were patterned with one photomask by dynamically reconfiguring decimal numeral shapes with on-demand injection and withdrawal of the liquid metal in specific segment microfluidic channels in the photomask. In addition, utilizing mechanical flexibility of the PDMS and the liquid metal, reconfiguration of the patterns in a microfluidic photomask under stretching was successfully tested. (paper)

  8. Magnetic properties of fcc Ni-based transition metal alloy

    Czech Academy of Sciences Publication Activity Database

    Kudrnovský, Josef; Drchal, Václav

    2009-01-01

    Roč. 100, č. 9 (2009), s. 1193-1196 ISSN 1862-5282 R&D Projects: GA MŠk OC 150; GA AV ČR IAA100100616 Institutional research plan: CEZ:AV0Z10100520 Keywords : transition metal alloys * Ni-based * pair exchange interactions * Curie temperatures * renormalized RPA Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.862, year: 2009

  9. Molecularly Imprinted Polymer/Metal Organic Framework Based Chemical Sensors

    Directory of Open Access Journals (Sweden)

    Zhenzhong Guo

    2016-10-01

    Full Text Available The present review describes recent advances in the concept of molecular imprinting using metal organic frameworks (MOF for development of chemical sensors. Two main strategies regarding the fabrication, performance and applications of recent sensors based on molecularly imprinted polymers associated with MOF are presented: molecularly imprinted MOF films and molecularly imprinted core-shell nanoparticles using MOF as core. The associated transduction modes are also discussed. A brief conclusion and future expectations are described herein.

  10. Development of a thermodynamic data base for selected heavy metals

    International Nuclear Information System (INIS)

    Hageman, Sven; Scharge, Tina; Willms, Thomas

    2015-07-01

    The report on the development of a thermodynamic data base for selected heavy metals covers the description of experimental methods, the thermodynamic model for chromate, the thermodynamic model for dichromate, the thermodynamic model for manganese (II), the thermodynamic model for cobalt, the thermodynamic model for nickel, the thermodynamic model for copper (I), the thermodynamic model for copper(II), the thermodynamic model for mercury (0) and mercury (I), the thermodynamic model for mercury (III), the thermodynamic model for arsenate.

  11. GRAPHENE BASED METAL AND METAL OXIDE NANOCOMPOSITES: SYNTHESIS, PROPERTIES AND THEIR APPLICATIONS

    KAUST Repository

    Khan, Mujeeb

    2015-06-11

    Graphene, an atomically thin two-dimensional carbonaceous material, has attracted tremendous attention in the scientific community, due to its exceptional electronic, electrical, and mechanical properties. Indeed, with the recent explosion of methods for a large-scale synthesis of graphene, the number of publications related to graphene and other graphene based materials have increased exponentially. Particularly the easy preparation of graphene like materials, such as, highly reduced graphene oxide (HRG) via reduction of graphite oxide (GO), offers a wide range of possibilities for the preparation of graphene based inorganic nanocomposites by the incorporation of various functional nanomaterials for a variety of applications. In this review, we discuss the current development of graphene based metal and metal oxide nanocomposites, with a detailed account of their synthesis and properties. Specifically, much attention has been given to their wide range of applications in various fields, including, electronics, electrochemical and electrical fields. Overall, by the inclusion of various references, this review covers in detail aspects of the graphene-based inorganic nanocomposites.

  12. GRAPHENE BASED METAL AND METAL OXIDE NANOCOMPOSITES: SYNTHESIS, PROPERTIES AND THEIR APPLICATIONS

    KAUST Repository

    Khan, Mujeeb; Tahir, Muhammad Nawaz; Adil, Syed F; Khan, Hadayat Ullah; Siddiqui, Rafiq H; Al-Warthan, Abdulrahman Abdullah; Tremel, Wolfgang

    2015-01-01

    Graphene, an atomically thin two-dimensional carbonaceous material, has attracted tremendous attention in the scientific community, due to its exceptional electronic, electrical, and mechanical properties. Indeed, with the recent explosion of methods for a large-scale synthesis of graphene, the number of publications related to graphene and other graphene based materials have increased exponentially. Particularly the easy preparation of graphene like materials, such as, highly reduced graphene oxide (HRG) via reduction of graphite oxide (GO), offers a wide range of possibilities for the preparation of graphene based inorganic nanocomposites by the incorporation of various functional nanomaterials for a variety of applications. In this review, we discuss the current development of graphene based metal and metal oxide nanocomposites, with a detailed account of their synthesis and properties. Specifically, much attention has been given to their wide range of applications in various fields, including, electronics, electrochemical and electrical fields. Overall, by the inclusion of various references, this review covers in detail aspects of the graphene-based inorganic nanocomposites.

  13. Hydrogen storage evaluation based on investigations of the catalytic properties of metal/metal oxides in electrospun carbon fibers

    Energy Technology Data Exchange (ETDEWEB)

    Im, Ji Sun; Lee, Young-Seak [Department of Fine Chemical Engineering and Chemistry, Chungnam National University, Daejeon 305-764 (Korea); Park, Soo-Jin [Department of Chemistry, Inha University, Incheon 402-751 (Korea); Kim, Taejin [Core Technology Research Center for Fuel Cell, Jeollabuk-do 561-844 (Korea)

    2009-05-15

    In order to investigate the catalytic capacity of metals and metal oxides based on electrospun carbon fibers for improving hydrogen storage, electrospinning and heat treatments were carried out to obtain metal/metal oxide-embedded carbon fibers. Although the fibers were treated with the same activation procedure, they had different pore structures, due to the nature of the metal oxide. When comparing the catalytic capacity of metal and metal oxide, metal exhibits better performance as a catalyst for the improvement of hydrogen storage, when considering the hydrogen storage system. When a metal oxide with an m.p. lower than the temperature of heat treatment was used, the metal oxide was changed to metal during the heat treatment, developing a micropore structure. The activation process produced a high specific surface area of up to 2900 m{sup 2}/g and a pore volume of up to 2.5 cc/g. The amount of hydrogen adsorption reached approximately 3 wt% at 100 bar and room temperature. (author)

  14. Ashland outlines $261 million in refinery unit construction

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that Ashland Petroleum Co. has spelled out $261 million in projects completed, under way, or planned to produce cleaner fuel and further reduce emissions at two U.S. refineries. The company: Started up at $13 million pollution control system at its 213,400 b/cd Catlettsburg, Ky., plant. Started construction on six projects at its 67,100 b/cd St. Paul Park, Minn., refinery that will cost about $114 million and enable the plant to produce cleaner burning diesel fuel and further reduce emissions

  15. 40 CFR 80.1238 - How is a refinery's or importer's average benzene concentration determined?

    Science.gov (United States)

    2010-07-01

    ... concentration determined? (a) The average benzene concentration of gasoline produced at a refinery or imported... percent benzene). i = Individual batch of gasoline produced at the refinery or imported during the applicable averaging period. n = Total number of batches of gasoline produced at the refinery or imported...

  16. 40 CFR 80.596 - How is a refinery motor vehicle diesel fuel volume baseline calculated?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 16 2010-07-01 2010-07-01 false How is a refinery motor vehicle diesel... Requirements § 80.596 How is a refinery motor vehicle diesel fuel volume baseline calculated? (a) For purposes of this subpart, a refinery's motor vehicle diesel fuel volume baseline is calculated using the...

  17. 77 FR 56421 - Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...

    Science.gov (United States)

    2012-09-12

    ... Parts 9 and 60 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum...-9672-3] RIN 2060-AN72 Standards of Performance for Petroleum Refineries; Standards of Performance for Petroleum Refineries for Which Construction, Reconstruction, or Modification Commenced After May 14, 2007...

  18. Brazing of Cu with Pd-based metallic glass filler

    Energy Technology Data Exchange (ETDEWEB)

    Terajima, Takeshi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan)], E-mail: terajima@jwri.osaka-u.ac.jp; Nakata, Kazuhiro [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan); Matsumoto, Yuji [Materials and Structures Laboratory, Tokyo Institute of Technology (Japan); Zhang, Wei; Kimura, Hisamichi; Inoue, Akihisa [Institute for Materials Research, Tohoku University (Japan)

    2008-02-25

    Metallic glass has several unique properties, including high mechanical strength, small solidification shrinkage, small elastic modulus and supercooling state, all of which are well suited as a residual stress buffer for metal and ceramic joining. In the present preliminary study, we demonstrated brazing of Cu rods with Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} metallic glass filler. The brazing was carried out at 873 K for 1 min in a vacuum atmosphere (1 x 10{sup -3} Pa), and then the specimens were quenched at the rate of 30 K/s by blowing He. The metallic glass brazing of Cu using Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} filler was successful, with the exception that several voids remained in the filler. According to micro-focused X-ray diffraction, no diffraction patterns were observed at both the center of the Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} filler and the Cu/Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} interface. The result showed that the Cu specimens were joined with Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} filler in the glassy state. The tensile fracture strength of the brazed specimens ranged from 20 to 250 MPa. The crack extension from the voids in the Pd{sub 40}Cu{sub 30}Ni{sub 10}P{sub 20} filler may have caused the results to be uneven and very low compared to the strength of Pd-based bulk metallic glass.

  19. Theoretical bases on thermal stability of layered metallic systems

    International Nuclear Information System (INIS)

    Kadyrzhanov, K.K.; Rusakov, V.S.; Turkebaev, T.Eh.; Zhankadamova, A.M.; Ensebaeva, M.Z.

    2003-01-01

    The paper is dedicated to implementation of the theoretical bases for layered metallic systems thermal stabilization. The theory is based on the stabilization mechanism expense of the intermediate two-phase field formation. As parameters of calculated model are coefficients of mutual diffusion and inclusions sizes of generated phases in two-phase fields. The stabilization time dependence for beryllium-iron (Be (1.1 μm)-Fe(5.5 μm)) layered system from iron and beryllium diffusion coefficients, and inclusions sizes is shown as an example. Conclusion about possible mechanisms change at transition from microscopic consideration to the nano-crystal physics level is given

  20. Metal-composite adhesion based on diazonium chemistry.

    Science.gov (United States)

    Oweis, Yara; Alageel, Omar; Kozak, Paige; Abdallah, Mohamed-Nur; Retrouvey, Jean-Marc; Cerruti, Marta; Tamimi, Faleh

    2017-11-01

    Composite resins do not adhere well to dental alloys. This weak bond can result in failure at the composite-metal interface in fixed dental prostheses and orthodontic brackets. The aim of this study was to develop a new adhesive, based on diazonium chemistry, to facilitate chemical bonding between dental alloys and composite resin. Samples of two types of dental alloys, stainless steel and cobalt chromium were primed with a diazonium layer in order to create a surface coating favorable for composite adhesion. Untreated metal samples served as controls. The surface chemical composition of the treated and untreated samples was analyzed by X-ray photoelectron spectroscopy (XPS) and the tensile strength of the bond with composite resin was measured. The diazonium adhesive was also tested for shear bond strength between stainless steel orthodontic brackets and teeth. XPS confirmed the presence of a diazonium coating on the treated metals. The coating significantly increased the tensile and shear bond strengths by three and four folds respectively between the treated alloys and composite resin. diazonium chemistry can be used to develop composite adhesives for dental alloys. Diazonium adhesion can effectively achieve a strong chemical bond between dental alloys and composite resin. This technology can be used for composite repair of fractured crowns, for crown cementation with resin based cements, and for bracket bonding. Copyright © 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  1. Welding of Zr-based bulk metallic glasses

    International Nuclear Information System (INIS)

    Elahi, M.

    2010-01-01

    Recently, many bulk metallic glass (BMG) materials with high specific strength, hardness and superior corrosion resistance have been developed and the maximum thickness of some Zr-based BMGs have reached several tenths of millimeters. Nevertheless, homogeneous glassy BMGs are not thick enough to be used for structural applications. In order to extend the engineering applications of BMG materials, BMG welding technologies needed to be developed. Specifically, the welding technologies of dissimilar materials such as BMG materials to crystalline alloys are to be developed. The functional use of the specific properties of each material in dissimilar material combination provides flexible design possibilities for products. In this project electron beam welding is employed to join BMG with BMG of different composition as well as with different crystalline materials (i.e. Hastealoy C-276, Inconel-625 and pure Ti metal). Defects free weld joint was achieved in BMG-BMG welding. Some cracks were produced in melt zone of BMG-Ti and BMG-Hastealoy C-276 welding while at joint they fuse properly with BMG. Inconel-625 could not properly weld with BMG. In all cases, hardness of melt zone was found to be higher than the base metals and the heat affected zone (HAZ). (author)

  2. High pressure die casting of Fe-based metallic glass

    Science.gov (United States)

    Ramasamy, Parthiban; Szabo, Attila; Borzel, Stefan; Eckert, Jürgen; Stoica, Mihai; Bárdos, András

    2016-01-01

    Soft ferromagnetic Fe-based bulk metallic glass key-shaped specimens with a maximum and minimum width of 25.4 and 5 mm, respectively, were successfully produced using a high pressure die casting (HPDC) method, The influence of die material, alloy temperature and flow rate on the microstructure, thermal stability and soft ferromagnetic properties has been studied. The results suggest that a steel die in which the molten metal flows at low rate and high temperature can be used to produce completely glassy samples. This can be attributed to the laminar filling of the mold and to a lower heat transfer coefficient, which avoids the skin effect in the steel mold. In addition, magnetic measurements reveal that the amorphous structure of the material is maintained throughout the key-shaped samples. Although it is difficult to control the flow and cooling rate of the molten metal in the corners of the key due to different cross sections, this can be overcome by proper tool geometry. The present results confirm that HPDC is a suitable method for the casting of Fe-based bulk glassy alloys even with complex geometries for a broad range of applications. PMID:27725780

  3. High pressure die casting of Fe-based metallic glass.

    Science.gov (United States)

    Ramasamy, Parthiban; Szabo, Attila; Borzel, Stefan; Eckert, Jürgen; Stoica, Mihai; Bárdos, András

    2016-10-11

    Soft ferromagnetic Fe-based bulk metallic glass key-shaped specimens with a maximum and minimum width of 25.4 and 5 mm, respectively, were successfully produced using a high pressure die casting (HPDC) method, The influence of die material, alloy temperature and flow rate on the microstructure, thermal stability and soft ferromagnetic properties has been studied. The results suggest that a steel die in which the molten metal flows at low rate and high temperature can be used to produce completely glassy samples. This can be attributed to the laminar filling of the mold and to a lower heat transfer coefficient, which avoids the skin effect in the steel mold. In addition, magnetic measurements reveal that the amorphous structure of the material is maintained throughout the key-shaped samples. Although it is difficult to control the flow and cooling rate of the molten metal in the corners of the key due to different cross sections, this can be overcome by proper tool geometry. The present results confirm that HPDC is a suitable method for the casting of Fe-based bulk glassy alloys even with complex geometries for a broad range of applications.

  4. High pressure die casting of Fe-based metallic glass

    Science.gov (United States)

    Ramasamy, Parthiban; Szabo, Attila; Borzel, Stefan; Eckert, Jürgen; Stoica, Mihai; Bárdos, András

    2016-10-01

    Soft ferromagnetic Fe-based bulk metallic glass key-shaped specimens with a maximum and minimum width of 25.4 and 5 mm, respectively, were successfully produced using a high pressure die casting (HPDC) method, The influence of die material, alloy temperature and flow rate on the microstructure, thermal stability and soft ferromagnetic properties has been studied. The results suggest that a steel die in which the molten metal flows at low rate and high temperature can be used to produce completely glassy samples. This can be attributed to the laminar filling of the mold and to a lower heat transfer coefficient, which avoids the skin effect in the steel mold. In addition, magnetic measurements reveal that the amorphous structure of the material is maintained throughout the key-shaped samples. Although it is difficult to control the flow and cooling rate of the molten metal in the corners of the key due to different cross sections, this can be overcome by proper tool geometry. The present results confirm that HPDC is a suitable method for the casting of Fe-based bulk glassy alloys even with complex geometries for a broad range of applications.

  5. Heavy metals contamination and their risk assessment around the abandoned base metals and Au-Ag mines in Korea

    Science.gov (United States)

    Chon, Hyo-Taek

    2017-04-01

    Heavy metals contamination in the areas of abandoned Au-Ag and base metal mines in Korea was investigated in order to assess the level of metal pollution, and to draw general summaries about the fate of toxic heavy metals in different environments. Efforts have been made to compare the level of heavy metals, chemical forms, and plant uptake of heavy metals in each mine site. In the base-metals mine areas, significant levels of Cd, Cu, Pb and Zn were found in mine dump soils developed over mine waste materials and tailings. Leafy vegetables tend to accumulate heavy metals(in particular, Cd and Zn) higher than other crop plants, and high metal concentrations in rice crops may affect the local residents' health. In the Au-Ag mining areas, arsenic would be the most characteristic contaminant in the nearby environment. Arsenic and heavy metals were found to be mainly associated with sulfide gangue minerals, and the mobility of these metals would be enhanced by the effect of continuing weathering and oxidation. According to the sequential extraction of metals in soils, most heavy metals were identified as non-residual chemical forms, and those are very susceptible to the change of ambient conditions of a nearby environment. The concept of pollution index(PI) of soils gives important information on the extent and degree of multi-element contamination, and can be applied to the evaluation of mine soils before their agricultural use and remediation. The risk assessment process comprising exposure assessment, dose-response assessment, and risk characterization was discussed, and the results of non-cancer risk of As, Cd, and Zn, and those of cancer risk of As were suggested.

  6. Metal shell technology based upon hollow jet instability

    International Nuclear Information System (INIS)

    Kendall, J.M.; Lee, M.C.; Wang, T.G.

    1982-01-01

    Spherical shells of submillimeter size are sought as ICF targets. Such shells must be dimensionally precise, smooth, of high strength, and composed of a high atomic number material. We describe a technology for the production of shells based upon the hydrodynamic instability of an annular jet of molten metal. We have produced shells in the 0.7--2.0 mm size range using tin as a test material. Specimens exhibit good sphericity, fair concentricity, and excellent finish over most of the surface. Work involving a gold--lead--antimony alloy is in progress. Droplets of this are amorphous and possess superior surface finish. The flow of tin models that of the alloy well; experiments on both metals show that the technique holds considerable promise

  7. Silicon-based metallic micro grid for electron field emission

    International Nuclear Information System (INIS)

    Kim, Jaehong; Jeon, Seok-Gy; Kim, Jung-Il; Kim, Geun-Ju; Heo, Duchang; Shin, Dong Hoon; Sun, Yuning; Lee, Cheol Jin

    2012-01-01

    A micro-scale metal grid based on a silicon frame for application to electron field emission devices is introduced and experimentally demonstrated. A silicon lattice containing aperture holes with an area of 80 × 80 µm 2 and a thickness of 10 µm is precisely manufactured by dry etching the silicon on one side of a double-polished silicon wafer and by wet etching the opposite side. Because a silicon lattice is more rigid than a pure metal lattice, a thin layer of Au/Ti deposited on the silicon lattice for voltage application can be more resistant to the geometric stress caused by the applied electric field. The micro-fabrication process, the images of the fabricated grid with 88% geometric transparency and the surface profile measurement after thermal feasibility testing up to 700 °C are presented. (paper)

  8. Metal nanoparticle film-based room temperature Coulomb transistor.

    Science.gov (United States)

    Willing, Svenja; Lehmann, Hauke; Volkmann, Mirjam; Klinke, Christian

    2017-07-01

    Single-electron transistors would represent an approach to developing less power-consuming microelectronic devices if room temperature operation and industry-compatible fabrication were possible. We present a concept based on stripes of small, self-assembled, colloidal, metal nanoparticles on a back-gate device architecture, which leads to well-defined and well-controllable transistor characteristics. This Coulomb transistor has three main advantages. By using the scalable Langmuir-Blodgett method, we combine high-quality chemically synthesized metal nanoparticles with standard lithography techniques. The resulting transistors show on/off ratios above 90%, reliable and sinusoidal Coulomb oscillations, and room temperature operation. Furthermore, this concept allows for versatile tuning of the device properties such as Coulomb energy gap and threshold voltage, as well as period, position, and strength of the oscillations.

  9. Metal nanoparticle film–based room temperature Coulomb transistor

    Science.gov (United States)

    Willing, Svenja; Lehmann, Hauke; Volkmann, Mirjam; Klinke, Christian

    2017-01-01

    Single-electron transistors would represent an approach to developing less power–consuming microelectronic devices if room temperature operation and industry-compatible fabrication were possible. We present a concept based on stripes of small, self-assembled, colloidal, metal nanoparticles on a back-gate device architecture, which leads to well-defined and well-controllable transistor characteristics. This Coulomb transistor has three main advantages. By using the scalable Langmuir-Blodgett method, we combine high-quality chemically synthesized metal nanoparticles with standard lithography techniques. The resulting transistors show on/off ratios above 90%, reliable and sinusoidal Coulomb oscillations, and room temperature operation. Furthermore, this concept allows for versatile tuning of the device properties such as Coulomb energy gap and threshold voltage, as well as period, position, and strength of the oscillations. PMID:28740864

  10. Colored cool colorants based on rare earth metal ions

    Energy Technology Data Exchange (ETDEWEB)

    Sreeram, Kalarical Janardhanan; Aby, Cheruvathoor Poulose; Nair, Balachandran Unni; Ramasami, Thirumalachari [Chemical Laboratory, Central Leather Research Institute, Council of Scientific and Industrial Research, Adyar, Chennai 600 020 (India)

    2008-11-15

    Colored pigments with high near infrared reflectance and not based on toxic metal ions like cadmium, lead and cobalt are being sought as cool colorants. Through appropriate doping two pigments Ce-Pr-Mo and Ce-Pr-Fe have been developed to offer a reddish brown and reddish orange color, respectively. These pigments have been characterized and found to be highly crystalline with an average size of 300 nm. A shift in band gap energy from 2.21 to 2.18 eV has been observed when Li{sub 2}CO{sub 3} was used as a mineralizer. Scanning electron microscope-energy dispersive X-ray analysis (SEM-EDAX) measurement indicate a uniform grind shape and distribution of metal ion, with over 65% reflectance in the NIR region, these pigments can well serve as cool colorants. (author)

  11. Metal-mediated DNA base pairing: alternatives to hydrogen-bonded Watson-Crick base pairs.

    Science.gov (United States)

    Takezawa, Yusuke; Shionoya, Mitsuhiko

    2012-12-18

    With its capacity to store and transfer the genetic information within a sequence of monomers, DNA forms its central role in chemical evolution through replication and amplification. This elegant behavior is largely based on highly specific molecular recognition between nucleobases through the specific hydrogen bonds in the Watson-Crick base pairing system. While the native base pairs have been amazingly sophisticated through the long history of evolution, synthetic chemists have devoted considerable efforts to create alternative base pairing systems in recent decades. Most of these new systems were designed based on the shape complementarity of the pairs or the rearrangement of hydrogen-bonding patterns. We wondered whether metal coordination could serve as an alternative driving force for DNA base pairing and why hydrogen bonding was selected on Earth in the course of molecular evolution. Therefore, we envisioned an alternative design strategy: we replaced hydrogen bonding with another important scheme in biological systems, metal-coordination bonding. In this Account, we provide an overview of the chemistry of metal-mediated base pairing including basic concepts, molecular design, characteristic structures and properties, and possible applications of DNA-based molecular systems. We describe several examples of artificial metal-mediated base pairs, such as Cu(2+)-mediated hydroxypyridone base pair, H-Cu(2+)-H (where H denotes a hydroxypyridone-bearing nucleoside), developed by us and other researchers. To design the metallo-base pairs we carefully chose appropriate combinations of ligand-bearing nucleosides and metal ions. As expected from their stronger bonding through metal coordination, DNA duplexes possessing metallo-base pairs exhibited higher thermal stability than natural hydrogen-bonded DNAs. Furthermore, we could also use metal-mediated base pairs to construct or induce other high-order structures. These features could lead to metal-responsive functional

  12. Metal-organic frameworks based membranes for liquid separation.

    Science.gov (United States)

    Li, Xin; Liu, Yuxin; Wang, Jing; Gascon, Jorge; Li, Jiansheng; Van der Bruggen, Bart

    2017-11-27

    Metal-organic frameworks (MOFs) represent a fascinating class of solid crystalline materials which can be self-assembled in a straightforward manner by the coordination of metal ions or clusters with organic ligands. Owing to their intrinsic porous characteristics, unique chemical versatility and abundant functionalities, MOFs have received substantial attention for diverse industrial applications, including membrane separation. Exciting research activities ranging from fabrication strategies to separation applications of MOF-based membranes have appeared. Inspired by the marvelous achievements of MOF-based membranes in gas separations, liquid separations are also being explored for the purpose of constructing continuous MOFs membranes or MOF-based mixed matrix membranes. Although these are in an emerging stage of vigorous development, most efforts are directed towards improving the liquid separation efficiency with well-designed MOF-based membranes. Therefore, as an increasing trend in membrane separation, the field of MOF-based membranes for liquid separation is highlighted in this review. The criteria for judicious selection of MOFs in fabricating MOF-based membranes are given. Special attention is paid to rational design strategies for MOF-based membranes, along with the latest application progress in the area of liquid separations, such as pervaporation, water treatment, and organic solvent nanofiltration. Moreover, some attractive dual-function applications of MOF-based membranes in the removal of micropollutants, degradation, and antibacterial activity are also reviewed. Finally, we define the remaining challenges and future opportunities in this field. This Tutorial Review provides an overview and outlook for MOF-based membranes for liquid separations. Further development of MOF-based membranes for liquid separation must consider the demands of strict separation standards and environmental safety for industrial application.

  13. [The bonding mechanisms of base metals for metal-ceramic crown microstructure analysis of bonding agent and gold bond between porcelain and base metals].

    Science.gov (United States)

    Wang, C C; Hsu, C S

    1996-06-01

    The use of base metal alloys for porcelain fused to a metal crown and bridges has increased recently because of lower price, high hardness, high tensile strength and high elastic modulus. The addition of beryllium to base metal alloys increased fluidity and improved casting fitness. Beryllium also controlled surface oxidation and bonding strength. The bonding agent and gold bonding agent also affected the bonding strength between porcelain and metal alloys. Four commercially available ceramic base alloys were studied (two alloys contained beryllium element, another two did not). The purpose of this investigation was to study the microstructure between porcelain matrix, bonding agent and alloy matrix interfaces. A scanning electron micro-probe analyzer and energy dispersive X-ray spectroscopy (EDXS) were used to study the distribution of elements (Ni, Cr, Mo, Cu, O, Si, Sn, Al) in four base alloys. The following results were obtained: 1. The thickness of the oxidized layer of Rexillium III alloy and Unitbond alloy (contained beryllium) was thinner than Unibond alloy and Wiron 88 alloy (no beryllium). 2. The thickness of the oxidized layer of alloys in air (10 minutes and 30 minutes) was thinner in Unitbond (2.45 microns and 3.80 microns) and thicker in Wiron 88 (4.39 microns and 5.96 microns). 3. The thickness of the oxidized layer occurring for a duration of ten minutes (in vaccum) showed that the Rexillium III alloy was the thinnest (1.93 microns), and Wiron 88 alloy was the thickest (2.30 microns). But in thirty minutes (vacuum), Unitbond alloy was the thinnest (3.37 microns), and Wiron 88 alloy was the thickest (5.51 microns). 4. The intensity of Cr elements was increased obviously near the interface between Unitbond alloy, Wiron 88 alloy (no beryllium) and oxidized layer, but the intensity of Ni and Mo elements was slightly increased. The intensity of Cr element was not increased markedly between Rexillium III alloy, Unitbond alloy (beryllium) and oxidized

  14. Metal-directed topological diversity of three fluorescent metal-organic frameworks based on a new tetracarboxylate strut

    KAUST Repository

    Lou, Xinhua

    2013-01-01

    Three d- or p-block metal ions based metal-organic frameworks (MOFs) were isolated by employing a new tetracarboxylate linker, featuring unusual flu, self-interpenetrated lvt and new (3,5)-c topological nets, respectively. Interesting photoluminescent properties of these solid-state materials were also observed. © 2013 The Royal Society of Chemistry.

  15. Ionic behavior of organic-inorganic metal halide perovskite based metal-oxide-semiconductor capacitors.

    Science.gov (United States)

    Wang, Yucheng; Zhang, Yuming; Pang, Tiqiang; Xu, Jie; Hu, Ziyang; Zhu, Yuejin; Tang, Xiaoyan; Luan, Suzhen; Jia, Renxu

    2017-05-24

    Organic-inorganic metal halide perovskites are promising semiconductors for optoelectronic applications. Despite the achievements in device performance, the electrical properties of perovskites have stagnated. Ion migration is speculated to be the main contributing factor for the many unusual electrical phenomena in perovskite-based devices. Here, to understand the intrinsic electrical behavior of perovskites, we constructed metal-oxide-semiconductor (MOS) capacitors based on perovskite films and performed capacitance-voltage (C-V) and current-voltage (I-V) measurements of the capacitors. The results provide direct evidence for the mixed ionic-electronic transport behavior within perovskite films. In the dark, there is electrical hysteresis in both the C-V and I-V curves because the mobile negative ions take part in charge transport despite frequency modulation. However, under illumination, the large amount of photoexcited free carriers screens the influence of the mobile ions with a low concentration, which is responsible for the normal C-V properties. Validation of ion migration for the gate-control ability of MOS capacitors is also helpful for the investigation of perovskite MOS transistors and other gate-control photovoltaic devices.

  16. HERA an HTR for use in a refinery

    International Nuclear Information System (INIS)

    Chaubernard, P.

    1977-01-01

    It is shown that it was technically possible to use a High Temperature Reactor to provide a large part of the energy (process heat, steam, electricity) consumed in a refinery. Nevertheless, economic calculations have lead to a prime cost of spared crude oil twice the existing price

  17. Study theorizes use of geothermal sources for energy in refineries

    NARCIS (Netherlands)

    Golombok, M.; Beintema, K.

    2008-01-01

    Geothermal sources for direct heating can theoretically serve as an alternative source of high-temperature heat in processing plants. Cutting CO2 emissions from a refinery requires reducing the amount of fuel burned. Heat obtained from geothermal energy is more efficiently used for directly powering

  18. Occupational health experience with a contractor uranium refinery

    International Nuclear Information System (INIS)

    Heatherton, R.C.

    1975-01-01

    This paper presents information related to the occupational exposure of workers in uranium refinery operations at the Feed Materials Production Center since 1958. Included are: a brief history of the FMPC; a description of the operations and the principal sources of exposure; airborne uranium, urinary excretion, in vivo monitoring and tissue analysis data; and some observations regarding the exposure and health status of employees

  19. A strategic review of the petroleum refinery industry sector

    International Nuclear Information System (INIS)

    1999-10-01

    The report studies the environmental performance of the U.K. petroleum refinery industry sector with reference to world-wide best practice and describes the five most practical strategic options for emission reduction in the context of projected technology, cost, demand, capacity and legislation. (author)

  20. Environmental impact of illegal refineries on the vegetation of the ...

    African Journals Online (AJOL)

    ... aesthetic scenery of the forest, regeneration of plant species and destruction of wildlife habitat, disruption of water cycle and loss of medicinal plant species. Youth empowerment, through vocational training and environmental education can ameliorate the situation. Keywords: Environmental degradation, Illegal Refineries, ...

  1. Spectrophotometric study of some metal ions using some Schiff's bases

    International Nuclear Information System (INIS)

    Elnager, Nawal Mohomed Ibrahim

    2000-05-01

    In this work two schiff bases namely N,N Bis(benzoyl acetone)-o-phenylene diamine (NNBBPD) and N,N Bis(benzoyl acetone)-isopropylene diamine (NNBBAID) were prepared by direct coupling of benzoyl acetone with o-phenylene and isopropylene diamine respectively. The two reagents were identified by IR spectra, thin layer chromatography (TLC) and determination of the percentage of nitrogen contents (N%). It is found that the two reagents form coloured chelates with Fe (II), Fe (III), Cu (II), U (VI), Ni (II) and Co (II). The two reagents were used for the determination of Fe (II), Fe (III) and U (VI). The formulate of these metal ion complexes were obtained using continuous variations, mole ratio and slope ratio methods. Effect of two micelles, namely sodium n-dodecyl sulphate (SDS) and hexadecyl pyridinum broinide monohydrate (HPB) on metal ion complexes were studied. It is found that both of them increase the solubility and the absorbances of the metal ion complexes with variable effects of the absorption maxima. Calibration curves for Fe (II), Fe (II) and U (VI) were obtained in optimum conditions of pH and micelles solutions. (Author)

  2. Metal hydrides based high energy density thermal battery

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Zhigang Zak, E-mail: zak.fang@utah.edu [Department of Metallurgical Engineering, The University of Utah, 135 South 1460 East, Room 412, Salt Lake City, UT 84112-0114 (United States); Zhou, Chengshang; Fan, Peng [Department of Metallurgical Engineering, The University of Utah, 135 South 1460 East, Room 412, Salt Lake City, UT 84112-0114 (United States); Udell, Kent S. [Department of Metallurgical Engineering, The University of Utah, 50 S. Central Campus Dr., Room 2110, Salt Lake City, UT 84112-0114 (United States); Bowman, Robert C. [Department of Metallurgical Engineering, The University of Utah, 135 South 1460 East, Room 412, Salt Lake City, UT 84112-0114 (United States); Vajo, John J.; Purewal, Justin J. [HRL Laboratories, LLC, 3011 Malibu Canyon Road, Malibu, CA 90265 (United States); Kekelia, Bidzina [Department of Metallurgical Engineering, The University of Utah, 50 S. Central Campus Dr., Room 2110, Salt Lake City, UT 84112-0114 (United States)

    2015-10-05

    Highlights: • The principle of the thermal battery using advanced metal hydrides was demonstrated. • The thermal battery used MgH{sub 2} and TiMnV as a working pair. • High energy density can be achieved by the use of MgH{sub 2} to store thermal energy. - Abstract: A concept of thermal battery based on advanced metal hydrides was studied for heating and cooling of cabins in electric vehicles. The system utilized a pair of thermodynamically matched metal hydrides as energy storage media. The pair of hydrides that was identified and developed was: (1) catalyzed MgH{sub 2} as the high temperature hydride material, due to its high energy density and enhanced kinetics; and (2) TiV{sub 0.62}Mn{sub 1.5} alloy as the matching low temperature hydride. Further, a proof-of-concept prototype was built and tested, demonstrating the potential of the system as HVAC for transportation vehicles.

  3. Metallic molybdenum disulfide nanosheet-based electrochemical actuators

    Science.gov (United States)

    Acerce, Muharrem; Akdoğan, E. Koray; Chhowalla, Manish

    2017-09-01

    Actuators that convert electrical energy to mechanical energy are useful in a wide variety of electromechanical systems and in robotics, with applications such as steerable catheters, adaptive wings for aircraft and drag-reducing wind turbines. Actuation systems can be based on various stimuli, such as heat, solvent adsorption/desorption, or electrochemical action (in systems such as carbon nanotube electrodes, graphite electrodes, polymer electrodes and metals). Here we demonstrate that the dynamic expansion and contraction of electrode films formed by restacking chemically exfoliated nanosheets of two-dimensional metallic molybdenum disulfide (MoS2) on thin plastic substrates can generate substantial mechanical forces. These films are capable of lifting masses that are more than 150 times that of the electrode over several millimetres and for hundreds of cycles. Specifically, the MoS2 films are able to generate mechanical stresses of about 17 megapascals—higher than mammalian muscle (about 0.3 megapascals) and comparable to ceramic piezoelectric actuators (about 40 megapascals)—and strains of about 0.6 per cent, operating at frequencies up to 1 hertz. The actuation performance is attributed to the high electrical conductivity of the metallic 1T phase of MoS2 nanosheets, the elastic modulus of restacked MoS2 layers (2 to 4 gigapascals) and fast proton diffusion between the nanosheets. These results could lead to new electrochemical actuators for high-strain and high-frequency applications.

  4. Evaluating the performance of an integrated CALPUFF-MM5 modeling system for predicting SO{sub 2} emission from a refinery

    Energy Technology Data Exchange (ETDEWEB)

    Abdul-Wahab, Sabah Ahmed [Sultan Qaboos University, Department of Mechanical and Industrial Engineering, College of Engineering, Muscat (Oman); Ali, Sappurd [National Engineering and Scientific Commission (NESCOM), Islamabad (Pakistan); Sardar, Sabir; Irfan, Naseem [Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad (Pakistan); Al-Damkhi, Ali [Public Authority for Applied Education and Training (PAAET), Department of Environmental Sciences College of Health Sciences, Salmiyah (Kuwait)

    2011-12-15

    Oil refineries are one of the proven sources of environmental pollution as they emit more than 100 chemicals into the atmosphere including sulfur dioxide (SO{sub 2}). The dispersion patterns of SO{sub 2} from emissions of Sohar refinery was simulated by employing California Puff (CALPUFF) model integrated with state of the art meteorological Mesoscale Model (MM5). The results of this simulation were used to quantify the ground level concentrations of SO{sub 2} in and around the refinery. The evaluation of the CALPUFF and MM5 modeling system was carried out by comparing the estimated results with that of observed data of the same area. The predicted concentrations of SO{sub 2} agreed well with the observed data, with minor differences in magnitudes. In addition, the ambient air quality of the area was checked by comparing the model results with the regulatory limits for SO{sub 2} set by the Ministry of Environment and Climate Affairs (MECA) in Oman. From the analysis of results, it was found that the concentration of SO{sub 2} in the nearby communities of Sohar refinery is well within the regulatory limits specified by MECA. Based on these results, it was concluded that no health risk, due to SO{sub 2} emissions, is present in areas adjacent to the refinery. (orig.)

  5. Market survey on products from the Tema Oil Refinery carried out as part of the feasibility study on the Tema Oil Refinery expansion project. Export trade information

    International Nuclear Information System (INIS)

    Anon.

    1991-10-01

    The Tema Oil Refinery (TOR), which was commissioned in 1963, is a simple hydroskimming plant which processes crude oil into LPG, gasoline, kerosene, gasoil, and fuel oil. It is the only petroleum refinery in Ghana. Over the years some of the equipment in the refinery has deteriorated or become obsolete necessitating major rehabilitation. A feasibility study is investigating the modernization and expansion of the refinery to meet projected market demands until the year 2005. The report presents the results of a market survey done on products from TOR

  6. Oil refinery dusts: morphological and size analysis by TEM.

    Science.gov (United States)

    Sielicki, Przemysław; Janik, Helena; Guzman, Agnieszka; Broniszewski, Mieczysław; Namieśnik, Jacek

    2011-03-01

    The objectives of this work were to develop a means of sampling atmospheric dusts on the premises of an oil refinery for electron microscopic study to carry out preliminary morphological analyses and to compare these dusts with those collected at sites beyond the refinery limits. Carbon and collodion membranes were used as a support for collection of dust particles straight on transmission electron microscopy (TEM) grids. Micrographs of the dust particles were taken at magnifications from ×4,000 to ×80,000 with a Tesla BS500 transmission electron microscope. Four parameters were defined on the basis of the micrographs: surface area, Feret diameter, circumference, and shape coefficient. The micrographs and literature data were used to classify the atmospheric dusts into six groups: particles with an irregular shape and rounded edges; particles with an irregular shape and sharp edges; soot and its aggregates; spherical particles; singly occurring, ultrafine dust particles; and particles not allocated to any of the previous five groups. The types of dusts found in all the samples were similar, although differences did exist between the various morphological parameters. Dust particles with the largest Feret diameter were present in sample 3 (mean, 0.739 μm)-these were collected near the refinery's effluent treatment plant. The particles with the smallest diameter were found in the sample that had been intended to be a reference sample for the remaining results (mean, 0.326 μm). The dust particles collected in the refinery had larger mean Feret diameters, even 100% larger, than those collected beyond it. Particles with diameters from 0.1 to 0.2 μm made up the most numerous group in all the samples collected in the refinery.

  7. Oil refinery dusts: morphological and size analysis by TEM

    Energy Technology Data Exchange (ETDEWEB)

    Sielicki, Przemyslaw; Janik, Helena; Guzman, Agnieszka [Gdansk University of Technology, Department of Polymer Technology, Chemical Faculty, Gdansk (Poland); Broniszewski, Mieczyslaw [Environmental Protection Office, Lotos Group, Gdansk (Poland); Namiesnik, Jacek [Gdansk University of Technology, Department of Analytical Chemistry, Chemical Faculty, Gdansk (Poland)

    2011-03-15

    The objectives of this work were to develop a means of sampling atmospheric dusts on the premises of an oil refinery for electron microscopic study to carry out preliminary morphological analyses and to compare these dusts with those collected at sites beyond the refinery limits. Carbon and collodion membranes were used as a support for collection of dust particles straight on transmission electron microscopy (TEM) grids. Micrographs of the dust particles were taken at magnifications from x 4,000 to x 80,000 with a Tesla BS500 transmission electron microscope. Four parameters were defined on the basis of the micrographs: surface area, Feret diameter, circumference, and shape coefficient. The micrographs and literature data were used to classify the atmospheric dusts into six groups: particles with an irregular shape and rounded edges; particles with an irregular shape and sharp edges; soot and its aggregates; spherical particles; singly occurring, ultrafine dust particles; and particles not allocated to any of the previous five groups. The types of dusts found in all the samples were similar, although differences did exist between the various morphological parameters. Dust particles with the largest Feret diameter were present in sample 3 (mean, 0.739 {mu}m) - these were collected near the refinery's effluent treatment plant. The particles with the smallest diameter were found in the sample that had been intended to be a reference sample for the remaining results (mean, 0.326 {mu}m). The dust particles collected in the refinery had larger mean Feret diameters, even 100% larger, than those collected beyond it. Particles with diameters from 0.1 to 0.2 {mu}m made up the most numerous group in all the samples collected in the refinery. (orig.)

  8. Chitosan based metallic nanocomposite scaffolds as antimicrobial wound dressings.

    Science.gov (United States)

    Mohandas, Annapoorna; Deepthi, S; Biswas, Raja; Jayakumar, R

    2018-09-01

    Chitosan based nanocomposite scaffolds have attracted wider applications in medicine, in the area of drug delivery, tissue engineering and wound healing. Chitosan matrix incorporated with nanometallic components has immense potential in the area of wound dressings due to its antimicrobial properties. This review focuses on the different combinations of Chitosan metal nanocomposites such as Chitosan/nAg, Chitosan/nAu, Chitosan/nCu, Chitosan/nZnO and Chitosan/nTiO 2 towards enhancement of healing or infection control with special reference to the antimicrobial mechanism of action and toxicity.

  9. Benchmarking of refinery CO2 emissions. The CWT methodology provides a way forward

    Energy Technology Data Exchange (ETDEWEB)

    Larive, J.F. [CONCAWE, Brussels (Belgium)

    2009-10-01

    The EU Greenhouse Gas Emissions Trading Scheme foresees a number of mechanisms for distributing emission allowances amongst market players. For those economic sectors exposed to international competition, a portion of the required allowances will be distributed free of charge. In order to do this in an equitable manner, the amount of free allowances will be based on a sectoral benchmark representing best practice in the sector. In cooperation with Solomon Associates, CONCAWE has developed the so-called Complexity Weighted Tonne (CWT) methodology which provides a common and balanced basis for comparing the performance of refineries.

  10. The Shell gasification technology offers clean solutions for refineries and utility companies

    Energy Technology Data Exchange (ETDEWEB)

    Vlaswinkel, E.E.; Posthuma, S.A.; Zuideveld, P.L. [Shell International Oil Products BV, Amsterdam (Netherlands)

    1997-12-31

    Shell has developed two dedicated gasification technologies, the Shell Gasification Process (SGP) for gaseous and liquid feed stocks and the Shell Coal Gasification Process (SCGP) for coal, lignite and petroleum coke. These processes are described. One of the most recent applications of SGP is the PER+ Shell Refinery project in the Netherlands which is nearly completed. A 250 MWe coal gasification combined cycle plant based on SCGP has recently been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). These two projects are discussed.

  11. Spintronic materials and devices based on antiferromagnetic metals

    Directory of Open Access Journals (Sweden)

    Y.Y. Wang

    2017-04-01

    Full Text Available In this paper, we review our recent experimental developments on antiferromagnet (AFM spintronics mainly comprising Mn-based noncollinear AFM metals. IrMn-based tunnel junctions and Hall devices have been investigated to explore the manipulation of AFM moments by magnetic fields, ferromagnetic materials and electric fields. Room-temperature tunneling anisotropic magnetoresistance based on IrMn as well as FeMn has been successfully achieved, and electrical control of the AFM exchange spring is realized by adopting ionic liquid. In addition, promising spin-orbit effects in AFM as well as spin transfer via AFM spin waves reported by different groups have also been reviewed, indicating that the AFM can serve as an efficient spin current source. To explore the crucial role of AFM acting as efficient generators, transmitters, and detectors of spin currents is an emerging topic in the field of magnetism today. AFM metals are now ready to join the rapidly developing fields of basic and applied spintronics, enriching this area of solid-state physics and microelectronics.

  12. Deactivation and regeneration of refinery catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E.

    1979-08-01

    A discussion covers the mechanisms of catalyst aging, poisoning, coke deposition, and metals deposition; feedstock pretreatment to extend catalyst life; the effects of operating conditions; the effects of catalyst composition and structure on its stability; nonchemical deactivation processes; and methods of catalyst regeneration, including coke burn-off and solvent extraction.

  13. A resonant force sensor based on ionic polymer metal composites

    International Nuclear Information System (INIS)

    Bonomo, Claudia; Fortuna, Luigi; Giannone, Pietro; Graziani, Salvatore; Strazzeri, Salvatore

    2008-01-01

    In this paper a novel force sensor, based on ionic polymer metal composites (IPMCs), is presented. The system has DC sensing capabilities and is able to work in the range of a few millinewtons. IPMCs are emerging materials used to realize motion actuators and sensors. An IPMC strip is activated in a beam fixed/simply-supported configuration. The beam is tightened at the simply-supported end by a force. This influences the natural resonant frequency of the beam; the value of the resonant frequency is used in the proposed system to estimate the force applied in the axial direction. The performance of the system based on the IPMC material has proved to be comparable with that of sensors based on other sensing mechanisms. This suggests the possibility of using this class of polymeric devices to realize PMEMS (plastic micro electrical mechanical systems) sensors

  14. A resonant force sensor based on ionic polymer metal composites

    Science.gov (United States)

    Bonomo, Claudia; Fortuna, Luigi; Giannone, Pietro; Graziani, Salvatore; Strazzeri, Salvatore

    2008-02-01

    In this paper a novel force sensor, based on ionic polymer metal composites (IPMCs), is presented. The system has DC sensing capabilities and is able to work in the range of a few millinewtons. IPMCs are emerging materials used to realize motion actuators and sensors. An IPMC strip is activated in a beam fixed/simply-supported configuration. The beam is tightened at the simply-supported end by a force. This influences the natural resonant frequency of the beam; the value of the resonant frequency is used in the proposed system to estimate the force applied in the axial direction. The performance of the system based on the IPMC material has proved to be comparable with that of sensors based on other sensing mechanisms. This suggests the possibility of using this class of polymeric devices to realize PMEMS (plastic micro electrical mechanical systems) sensors.

  15. Oil refining in a CO2 constrained world: Effects of carbon pricing on refineries globally

    International Nuclear Information System (INIS)

    Abdul-Manan, Amir F.N.; Arfaj, Abdullah; Babiker, Hassan

    2017-01-01

    Six aggregated refinery linear programming (LP) models were developed to represent actual refineries in North America, Latin America, Europe (including the CIS), Middle East, Asia (excluding China) and China. The models were used to conduct regional comparative assessments and to evaluate the effects of carbon pricing on refinery operations globally. We found that the average refinery energy efficiencies for the regions were estimated to range from 92.2% to 95.2%. The well-to-refinery gate carbon intensities for gasoline, diesel and jet fuels were estimated to be 17.1 (16.4–19.4), 13.3 (12.5–14.2) and 10.1 (9.6–10.8) gCO2eq/MJ, respectively. If refineries are forced to at least meet the 2014 regional volume demands for oil products, pricing CO 2 would not have an impact on either refinery productions, efficiency or emissions. If refineries are allowed to re-optimize production slates to reduce CO 2 emissions, refineries would opt to increase gasoline yield at the expense of diesel. This is counter intuitive since gasoline has a higher carbon intensity than diesel. The refinery bias against dieselization creates a supply preference toward a less efficient transportation end use. Here, we argue that if carbon pricing is not administered properly, this can lead to emissions leakage from refineries to the road transport sector. - Highlights: • Investigate actual refinery productions in 6 regions globally. • Refineries already operate at the most efficient levels. • Complex refineries tolerate higher CO 2 prices better. • Carbon pricing induces bias against dieselization. • Identify potential emissions leakage.

  16. MgNiO-based metal-semiconductor- metal ultraviolet photodetector

    Energy Technology Data Exchange (ETDEWEB)

    Zhao Yanmin; Zhang Jiying; Jiang Dayong; Shan Chongxin; Zhang Zhenzhong; Yao Bin; Zhao Dongxu; Shen Dezhen, E-mail: zhangjy53@yahoo.com.c [Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033 (China)

    2009-05-07

    In this study, we report the growth of Mg{sub x}Ni{sub 1-x}O thin films on quartz substrates by electron beam evaporation. The absorption edge shows a blue shift from 340 nm to 260 nm with increase in the Mg content from 0.2 to 0.8. A metal-semiconductor-metal structured photodetector is fabricated from the Mg{sub 0.2}Ni{sub 0.8}O film. At a bias of 5 V, the dark current of the photodetector is about 70 nA. The maximum responsivity is about 147.3 {mu}A W{sup -1} at 320 nm. In addition, the ultraviolet (UV) (320 nm) to visible (400 nm) rejection ratio is nearly two orders of magnitude. Based on these results, it is proposed that Mg{sub x}Ni{sub 1-x}O is a potential candidate for application in UV photodetectors. (fast track communication)

  17. Repair procedure used in removing corroded pits in the distillation towers of the Getulio Vargas Refinery Unit 2100

    Energy Technology Data Exchange (ETDEWEB)

    Lordelos, H.M.; Santin, J.L.

    1977-07-01

    A description is given of the corrosion pits on ASTM A240, Type 405 steel cladded to carbon steel plates used in Petroleo Brasileiro S.A.'s Getulio Vargas Refinery Unit 2100 distillation towers; the repair procedure used, including sand blasting of the corroded surfaces, grinding of the pits, and welding of those pits whose depth was above a maximum limit, and the use of liquid penetrant to check the repairs made; and hydrostatic testing of the T2201 catalytic cracking unit, which used also cladded metals and on which the pits were much smaller in size and number than those on the distillation units.

  18. Multifunctional methacrylate-based coatings for glass and metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Pospiech, Doris, E-mail: pospiech@ipfdd.de [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Jehnichen, Dieter [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Starke, Sandra; Müller, Felix [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Technische Universität Dresden, Organic Chemistry of Polymers, Dresden (Germany); Bünker, Tobias [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Wollenberg, Anne [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Technische Universität Dresden, Organic Chemistry of Polymers, Dresden (Germany); Häußler, Liane; Simon, Frank; Grundke, Karina; Oertel, Ulrich [Leibniz-Institut für Polymerforschung Dresden e. V., Dresden (Germany); Opitz, Michael; Kruspe, Rainer [IDUS Biologisch Analytisches Umweltlabor GmbH, Ottendorf-Okrilla (Germany)

    2017-03-31

    Highlights: • New methacrylate-based copolymers synthesized by free radical polymerization. • Comonomer AAMA was able to complex Cu (II) ions in solvent annealing procedure. • Coatings had efficient anti-biofouling efficacy. - Abstract: In order to prevent freshwater biofouling glass and metal surfaces were coated with novel transparent methacrylate-based copolymers. The multifunctionality of the copolymers, such as adhesion to the substrate, surface polarity, mechanical long-term stability in water, and ability to form metal complexes was inserted by the choice of suitable comonomers. The monomer 2-acetoacetoxy ethyl methacrylate (AAMA) was used as complexing unit to produce copper(II) complexes in the coating’s upper surface layer. The semifluorinated monomer 1H,1H,2H,2H-perfluorodecyl methacrylate was employed to adjust the surface polarity and wettability. Comprehensive surface characterization techniques, such as X-ray photoelectron spectroscopy (XPS) and contact angle measurements showed that surface compositions and properties can be easily adjusted by varying the concentrations of the comonomers. The formation of copper(II) complexes along the copolymer chains and their stability against washing out with plenty of water was proven by XPS. Copolymers containing semifluorinated comonomers significantly inhibited the growth of Achnanthidium species. Copolymers with copper-loaded AAMA-sequences were able to reduce both the growth of Achnanthidium spec. and Staphylococcus aureus.

  19. Multifunctional methacrylate-based coatings for glass and metal surfaces

    International Nuclear Information System (INIS)

    Pospiech, Doris; Jehnichen, Dieter; Starke, Sandra; Müller, Felix; Bünker, Tobias; Wollenberg, Anne; Häußler, Liane; Simon, Frank; Grundke, Karina; Oertel, Ulrich; Opitz, Michael; Kruspe, Rainer

    2017-01-01

    Highlights: • New methacrylate-based copolymers synthesized by free radical polymerization. • Comonomer AAMA was able to complex Cu (II) ions in solvent annealing procedure. • Coatings had efficient anti-biofouling efficacy. - Abstract: In order to prevent freshwater biofouling glass and metal surfaces were coated with novel transparent methacrylate-based copolymers. The multifunctionality of the copolymers, such as adhesion to the substrate, surface polarity, mechanical long-term stability in water, and ability to form metal complexes was inserted by the choice of suitable comonomers. The monomer 2-acetoacetoxy ethyl methacrylate (AAMA) was used as complexing unit to produce copper(II) complexes in the coating’s upper surface layer. The semifluorinated monomer 1H,1H,2H,2H-perfluorodecyl methacrylate was employed to adjust the surface polarity and wettability. Comprehensive surface characterization techniques, such as X-ray photoelectron spectroscopy (XPS) and contact angle measurements showed that surface compositions and properties can be easily adjusted by varying the concentrations of the comonomers. The formation of copper(II) complexes along the copolymer chains and their stability against washing out with plenty of water was proven by XPS. Copolymers containing semifluorinated comonomers significantly inhibited the growth of Achnanthidium species. Copolymers with copper-loaded AAMA-sequences were able to reduce both the growth of Achnanthidium spec. and Staphylococcus aureus.

  20. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  1. Feasibility Study on 3-D Printing of Metallic Structural Materials with Robotized Laser-Based Metal Additive Manufacturing

    Science.gov (United States)

    Ding, Yaoyu; Kovacevic, Radovan

    2016-07-01

    Metallic structural materials continue to open new avenues in achieving exotic mechanical properties that are naturally unavailable. They hold great potential in developing novel products in diverse industries such as the automotive, aerospace, biomedical, oil and gas, and defense. Currently, the use of metallic structural materials in industry is still limited because of difficulties in their manufacturing. This article studied the feasibility of printing metallic structural materials with robotized laser-based metal additive manufacturing (RLMAM). In this study, two metallic structural materials characterized by an enlarged positive Poisson's ratio and a negative Poisson's ratio were designed and simulated, respectively. An RLMAM system developed at the Research Center for Advanced Manufacturing of Southern Methodist University was used to print them. The results of the tensile tests indicated that the printed samples successfully achieved the corresponding mechanical properties.

  2. Assessment and control design for steam vent noise in an oil refinery.

    Science.gov (United States)

    Monazzam, Mohammad Reza; Golmohammadi, Rostam; Nourollahi, Maryam; Momen Bellah Fard, Samaneh

    2011-06-13

    Noise is one of the most important harmful agents in work environment. Noise pollution in oil refinery industries is related to workers' health. This study aimed to determine the overall noise pollution of an oil refinery operation and its frequency analysis to determine the control plan for a vent noise in these industries. This experimental study performed in control unit of Tehran Oil Refinery in 2008. To determine the noise distributions, environmental noise measurements were carried out by lattice method according to basic information and technical process. The sound pressure level and frequency distribution was measured for each study sources subject separately was performed individually. According to the vent's specification, the measured steam noise characteristics reviewed and compared to the theoretical results of steam noise estimation. Eventually, a double expansion muffler was designed. Data analysis and graphical design were carried out using Excel software. The results of environmental noise measurements indicated that the level of sound pressure was above the national permitted level (85 dB (A)). The Mean level of sound pressure of the studied steam jet was 90.3 dB (L). The results of noise frequency analysis for the steam vents showed that the dominant frequency was 4000 Hz. To obtain 17 dB noise reductions, a double chamber aluminum muffler with 500 mm length and 200 mm diameter consisting pipe drilled was designed. The characteristics of steam vent noise were separated from other sources, a double expansion muffler was designed using a new method based on the level of steam noise, and principle sound frequency, a double expansion muffler was designed.

  3. Evaluation the Phytoremediation of Oil-contaminated Soils Around Isfahan Oil Refinery

    Directory of Open Access Journals (Sweden)

    Farida Iraji-Asiabadi

    2016-07-01

    Full Text Available Petroleum compounds are pollutants that most commonly occur in soils around oil refineries and that often find their ways into groundwater resources. Phytoremediation is a cost-effective alternative to physicochemical methods for oil-contaminated soil remediation, where feasible. In this study, a greenhouse experiment was conducted to evaluate the phytoremediation of oil-contaminated soils around Isfahan Oil Refinery. Four different plants (namely, sorghum, barley, agropyron, and festuca were initially evaluated in terms of their germinability in both contaminated and control (non-contaminated soils. Sorghum and barley (recording the highest germinability values were chosen as the species for use in the phytoremediation experiments. Shoot and root dry weights, total and oil-degrading bacteria counts, microbial activity, and total concentrations of petroleum hydrocarbons (TPHs were determined at harvest 120 days after planting. A significant difference was observed in the bacterial counts (total and oil-degrading bacteria between the planted soils and the control. In contaminated soils, a higher microbial activity was observed in the rhizosphere of the sorghum soil than in that of barley. TPHs concentration decreased by 52%‒64% after 120 days in contaminated soil in which sorghum and barley had been cultivated. This represented an improvement of 30% compared to the contaminated soil without plants. Based on the results obtained, sorghum and barley may be recommended for the removal of petro-contaminants in areas close to Isfahan Oil Refinery. Nevertheless, caution must be taken as such cultivated lands may need to be protected against grazing animals.

  4. Control valves for critical applications in refineries; Stellventile bei kritischen Prozessbedingungen in Raffinerien

    Energy Technology Data Exchange (ETDEWEB)

    Kiesbauer, J. [Samson AG, Frankfurt am Main (Germany)

    2001-09-01

    In refineries, the process media flowing through valves are primarily liquids. With liquids, critical operating conditions caused by cavitation or flashing may occur. Symptoms are, for instance, increased noise emission, erosion of valve and pipe components or low-frequency mechanical vibration in the valve and the connected pipeline. Under these conditions, in particular, neglecting details can result in negative influences on the plant performance and the costs of ownership. Unfortunately, it is a common practice nowadays to select control valves in a ''quick and dirty'' fashion, because the phases of planning, bidding and order processing are connected with significant pressures of cost and time. This article presents the basic principles underlying the above problems and shows how to eliminate them based on practical examples from refineries. Moreover, a new throttling element is introduced, which is especially suited to the reduction of noise emission produced by cavitation. This new throttling element is implemented in refineries with increasing success. (orig.) [German] In Raffinerien werden Stellgeraete oft mit Fluessigkeiten durchstroemt. Dadurch koennen sich kritische Betriebszustaende als Folge von Kavitation oder Flashing ergeben. Dies aeussert sich z. B. in erhoehter Schallemission, in Erosion an Ventil- und Rohrleitungsbauteilen oder in niederfrequenten mechanischen Vibrationen im Ventil und der angeschlossenen Rohrleitung. Werden solche Einfluesse nicht von Anfang an richtig erfasst und ernst genommen, dann kann sich dies aeusserst negativ auf die Anlagen- und Prozesszuverlaessigkeit auswirken, verbunden mit deutlich erhoehten ''costs of ownership''. Leider ist es gerade heutzutage ueblich, Stellventile ''quick and dirty'' auszulegen, weil die Phasen der Planung, des Angebots und der Bestellung einem sehr starken Zeit- und Kostendruck unterliegen. Dieser Beitrag stellt die wesentlichen

  5. Effects of work-related stress on work ability index among refinery workers.

    Science.gov (United States)

    Habibi, Ehsanollah; Dehghan, Habibollah; Safari, Shahram; Mahaki, Behzad; Hassanzadeh, Akbar

    2014-01-01

    Work-related stress is one of the basic problems in industrial also top 10 work-related health problems and it is increasingly implicated in the development a number of problems such as cardiovascular disease, musculoskeletal diseases, early retirement to employees. On the other hand, early retirement to employees from the workplace has increased on the problems of today's industries. Hereof, improving work ability is one of the most effective ways to enhance the ability and preventing disability and early retirement. The aim of This study is determine the relationship between job stress score and work ability index (WAI) at the refinery workers. This is a cross-sectional study in which 171 workers from a refinery in isfahan in 2012 who were working in different occupational groups participated. Based on appropriate assignment sampling, 33 office workers, 69 operational workers, and 69 maintenance workers, respectively, were invited to participate in this study. Two questionnaires including work related-stress and WAI were filled in. Finally, the information was analyzed using the SPSS-20 and statistic tests namely, analysis of covariance Kruskal-Wallis test. Pearson correlation coefficient, ANOVA and t-test. Data analysis revealed that 86% and 14% of participants had moderate and severe stress respectively. Average score of stress and standard deviation was 158.7 ± 17.3 that was in extreme stress range. Average score and standard deviation of WAI questionnaire were 37.18 and 3.86 respectively. That placed in a good range. Pearson correlation coefficient showed that WAI score had significant reversed relationship with a score of stress. According to the results, mean stress score among refinery worker was high and one fator that affect work abiity was high stress, hence training on communication skills and safe working environment in order to decreses stress, enhance the work ability of workers.

  6. Biostimulation of indigenous microbial community for bioremediation of petroleum refinery sludge.

    Directory of Open Access Journals (Sweden)

    Jayeeta Sarkar

    2016-09-01

    Full Text Available Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched high total petroleum hydrocarbon (TPH, oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days with nitrate amendment. Preferred utilization of both higher- (>C30 and middle- chain (C20-30 length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis (DGGE and community level physiological profiling (CLPP analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA, methanogenesis (mcrA, denitrification (nirS and narG and N2 fixation (nifH were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members e.g., Azovibrio, Pseudoxanthomonas and Commamonadaceae members was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources.

  7. Biostimulation of Indigenous Microbial Community for Bioremediation of Petroleum Refinery Sludge

    Science.gov (United States)

    Sarkar, Jayeeta; Kazy, Sufia K.; Gupta, Abhishek; Dutta, Avishek; Mohapatra, Balaram; Roy, Ajoy; Bera, Paramita; Mitra, Adinpunya; Sar, Pinaki

    2016-01-01

    Nutrient deficiency severely impairs the catabolic activity of indigenous microorganisms in hydrocarbon rich environments (HREs) and limits the rate of intrinsic bioremediation. The present study aimed to characterize the microbial community in refinery waste and evaluate the scope for biostimulation based in situ bioremediation. Samples recovered from the wastewater lagoon of Guwahati refinery revealed a hydrocarbon enriched [high total petroleum hydrocarbon (TPH)], oxygen-, moisture-limited, reducing environment. Intrinsic biodegradation ability of the indigenous microorganisms was enhanced significantly (>80% reduction in TPH by 90 days) with nitrate amendment. Preferred utilization of both higher- (>C30) and middle- chain (C20-30) length hydrocarbons were evident from GC-MS analysis. Denaturing gradient gel electrophoresis and community level physiological profiling analyses indicated distinct shift in community’s composition and metabolic abilities following nitrogen (N) amendment. High throughput deep sequencing of 16S rRNA gene showed that the native community was mainly composed of hydrocarbon degrading, syntrophic, methanogenic, nitrate/iron/sulfur reducing facultative anaerobic bacteria and archaebacteria, affiliated to γ- and δ-Proteobacteria and Euryarchaeota respectively. Genes for aerobic and anaerobic alkane metabolism (alkB and bssA), methanogenesis (mcrA), denitrification (nirS and narG) and N2 fixation (nifH) were detected. Concomitant to hydrocarbon degradation, lowering of dissolve O2 and increase in oxidation-reduction potential (ORP) marked with an enrichment of N2 fixing, nitrate reducing aerobic/facultative anaerobic members [e.g., Azovibrio, Pseudoxanthomonas and Comamonadaceae members] was evident in N amended microcosm. This study highlighted that indigenous community of refinery sludge was intrinsically diverse, yet appreciable rate of in situ bioremediation could be achieved by supplying adequate N sources. PMID:27708623

  8. Laser spot welding of cobalt-based amorphous metal foils

    International Nuclear Information System (INIS)

    Runchev, Dobre; Dorn, Lutc; Jaferi, Seifolah; Purbst, Detler

    1997-01-01

    The results concerning weldability of amorphous alloy (VAC 6025F) in shape of foils and the quality of laser-spot welded joints are presented in this paper. The aim of the research was the production of a high quality welding joint, by preserving the amorphous structure. The quality of the joint was tested by shear strength analysis and microhardness measuring. The metallographic studies were made by using optical microscope and SEM. The results show that (1) overlapped Co based amorphous metals foils can be welded with high-quality by a pulsed Nd: YAG-Laser, but only within a very narrow laser parameter window; (2) the laser welded spots show comparably high strength as the basic material; (3) the structure of the welded spot remains amorphous, so that the same characteristics as the base material can be achieved. (author)

  9. Biomedical application of hierarchically built structures based on metal oxides

    Science.gov (United States)

    Korovin, M. S.; Fomenko, A. N.

    2017-12-01

    Nowadays, the use of hierarchically built structures in biology and medicine arouses much interest. The aim of this work is to review and summarize the available literature data about hierarchically organized structures in biomedical application. Nanoparticles can serve as an example of such structures. Medicine holds a special place among various application methods of similar systems. Special attention is paid to inorganic nanoparticles based on different metal oxides and hydroxides, such as iron, zinc, copper, and aluminum. Our investigations show that low-dimensional nanostructures based on aluminum oxides and hydroxides have an inhibitory effect on tumor cells and possess an antimicrobial activity. At the same time, it is obvious that the large-scale use of nanoparticles by humans needs to thoroughly study their properties. Special attention should be paid to the study of nanoparticle interaction with living biological objects. The numerous data show that there is no clear understanding of interaction mechanisms between nanoparticles and various cell types.

  10. Ultramicrosensors based on transition metal hexacyanoferrates for scanning electrochemical microscopy

    Directory of Open Access Journals (Sweden)

    Maria A. Komkova

    2013-10-01

    Full Text Available We report here a way for improving the stability of ultramicroelectrodes (UME based on hexacyanoferrate-modified metals for the detection of hydrogen peroxide. The most stable sensors were obtained by electrochemical deposition of six layers of hexacyanoferrates (HCF, more specifically, an alternating pattern of three layers of Prussian Blue and three layers of Ni–HCF. The microelectrodes modified with mixed layers were continuously monitored in 1 mM hydrogen peroxide and proved to be stable for more than 5 h under these conditions. The mixed layer microelectrodes exhibited a stability which is five times as high as the stability of conventional Prussian Blue-modified UMEs. The sensitivity of the mixed layer sensor was 0.32 A·M−1·cm−2, and the detection limit was 10 µM. The mixed layer-based UMEs were used as sensors in scanning electrochemical microscopy (SECM experiments for imaging of hydrogen peroxide evolution.

  11. Graphene oxide-based flexible metal–insulator–metal capacitors

    International Nuclear Information System (INIS)

    Bag, A; Hota, M K; Mallik, S; Maiti, C K

    2013-01-01

    This work explores the fabrication of graphene oxide (GO)-based metal–insulator–metal (MIM) capacitors on flexible polyethylene terephthalate (PET) substrates. Electrical properties are studied in detail. A high capacitance density of ∼4 fF µm −2 measured at 1 MHz and permittivity of ∼6 have been obtained. A low voltage coefficient of capacitance, VCC-α, and a low dielectric loss tangent indicate the potential of GO-based MIM capacitors for RF applications. The constant voltage stressing study has shown a high reliability against degradation up to a projected period of 10 years. Degradation in capacitance of the devices on flexible substrates has been studied by bending radius down to 1 cm even up to 6000 times of repeated bending. (paper)

  12. Computer model for refinery operations with emphasis on jet fuel production. Volume 3: Detailed systems and programming documentation

    Science.gov (United States)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    The FORTRAN computing program predicts flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuels of varying end point and hydrogen content specifications. The program has a provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

  13. Memory phenomenon in a lanthanum based bulk metallic glass

    International Nuclear Information System (INIS)

    Zhou, Ye; Huang, Wei Min; Zhao, Yong; Ding, Zhen; Li, Yan; Tor, Shu Beng; Liu, Erjia

    2016-01-01

    In this paper, we experimentally investigate two memory phenomena in a lanthanum based bulk metallic glass (BMG). While the temperature memory effect (TME) is not found by differential scanning calorimeter (DSC) test, shape recovery is observed in samples indented at both low and high temperatures. In terms of shape memory related characteristics, this BMG shares some features of shape memory alloys (SMAs) due to its metal nature, and some other features of shape memory polymers (SMPs) owing to its glassy–rubbery transition. The formation of protrusion in the polished sample after heating to super-cooled liquid region (SCLR) indicates that surface tension is not a necessarily positive contributor for shape recovery. Release of internal elastic stress is concluded as the major player. Although the amorphous nature of BMGs enables for storing appreciable amount of internal elastic stress upon deformation, without the presence of cross-linker as in typical SMPs, the shape recovery in BMGs is rather limited. - Highlights: • Experimental investigation of shape recovery in BMG. • Surface tension is not the major reason for shape recovery in BMG. • Release of internal stress is the major contributor for shape recovery. • Comparison of shape memory features of BMG with other shape memory materials.

  14. Process for recovering uranium and other base metals

    International Nuclear Information System (INIS)

    Jan, R. J-J.

    1979-01-01

    Uranium and other base metals are leached from their ores with aqueous solutions containing bicarbonate ions that have been generated or reconstituted by converting other non-bicarbonate anions into bicarbonate ions. The conversion is most conveniently effected by contacting solutions containing SO 4 - and Cl - ions with a basic anion exchange resin so that the SO 4 - and Cl - ions are converted into or exhanged for HCO 3 - ions. CO 2 may be dissolved in the solution so it is present during the exhange. The resin is preferably in bicarbonate form prior to contact and CO 2 partial pressure is adjusted so that the resin is not fouled by depositing metal precipitates. In-situ uranium mining is conducted by circulating such solutions through the ore deposit. Oxidizing agents are included in the injected lixiviant. The leaching strength of the circulating bicarbonate lixiviant is maintained by converting the anions generated during leaching or above-ground recovery processes into HCO 3 - ions. The resin may conveniently be eluted and reformed intermittently

  15. Process for recovering uranium and other base metals

    International Nuclear Information System (INIS)

    Jan, R.J.

    1981-01-01

    Uranium and other base metals are leached from their ores with aqueous solutions containing bicarbonate ions that have been generated or reconstituted by converting other non-bicarbonate anions into bicarbonate ions. The conversion is most conveniently effected by contacting solutions containing SO 4 -- and C1 - ions with a basic anion exchange resin so that the SO 4 -- and Cl - ions are converted into or exchanged for HCO 3 - ions. CO 2 may be dissolved in the solution so it is present during the exchange. The resin is preferably in bicarbonate form prior to contact and CO 2 partial pressure is adjusted so that the resin is not fouled by depositing metal precipitates. In-situ uranium mining is conducted by circulating such solutions through the ore deposit. Oxidizing agents are included in the injected lixiviant. The leaching strength of the circulating bicarbonate lixiviant is maintained by converting the anions generated during leaching or above-ground recovery processes into HCO 3 - ions. The resin may conveniently be eluted and performed intermittently. (author)

  16. Welding of CuZr-based metallic glasses on air

    International Nuclear Information System (INIS)

    Batalha, W.; Gargarella, P.; Kiminami, C.S.

    2016-01-01

    Metallic glass alloys have been studied aiming at its exceptional mechanical properties. This alloys processing's requires high cooling rates, which diminishes the sample's size. There by welding these samples without the loss of amorphous structure is a good alternative. The DEMa group has developed a technique based on Joule effect heating. By applying pressure and electric current, reaching temperatures of super cold liquids (the temperature between crystallizing and vitric transition), the vitric metal has it’s viscosity reduced and sample binding occur. The objective of this paper was to weld samples of cylindrical geometry of 2 and 3 mm in diameter and 4 mm in length of the compositions Cu46Zr42Al7Y5 and (Cu47Zr45Al8)98Y2. The process was done using 2 copper electrodes under(over) argon flux. The samples were later analysed by microscopy, differential scanning calorimetry and X ray diffraction. The results showed that this kind of welding process is possible since crystal formation on the welding region did not occur and there were no faults like cracks or porosity. (author)

  17. Compact-Morphology-based poly-metallic Nodule Delineation.

    Science.gov (United States)

    Schoening, Timm; Jones, Daniel O B; Greinert, Jens

    2017-10-17

    Poly-metallic nodules are a marine resource considered for deep sea mining. Assessing nodule abundance is of interest for mining companies and to monitor potential environmental impact. Optical seafloor imaging allows quantifying poly-metallic nodule abundance at spatial scales from centimetres to square kilometres. Towed cameras and diving robots acquire high-resolution imagery that allow detecting individual nodules and measure their sizes. Spatial abundance statistics can be computed from these size measurements, providing e.g. seafloor coverage in percent and the nodule size distribution. Detecting nodules requires segmentation of nodule pixels from pixels showing sediment background. Semi-supervised pattern recognition has been proposed to automate this task. Existing nodule segmentation algorithms employ machine learning that trains a classifier to segment the nodules in a high-dimensional feature space. Here, a rapid nodule segmentation algorithm is presented. It omits computation-intense feature-based classification and employs image processing only. It exploits a nodule compactness heuristic to delineate individual nodules. Complex machine learning methods are avoided to keep the algorithm simple and fast. The algorithm has successfully been applied to different image datasets. These data sets were acquired by different cameras, camera platforms and in varying illumination conditions. Their successful analysis shows the broad applicability of the proposed method.

  18. Evaluation of different finish line designs in base metal alloys

    Directory of Open Access Journals (Sweden)

    Aghandeh R

    1999-06-01

    Full Text Available This investigation was performed according to the widespread application of base metal alloys"nand few articles published about the marginal integrity of restorations fabricated by these metals."nThree standard dies of a maxillary first premolar were prepared with a flat shoulder finish line in buccal"naspect and chamfer in palatal. One of them left with no change. On the buccal aspect of the second and"nthird dies 135?and 1607 bevel were added respectively"nUsing dual wax technique, nine wax patterns were formed on each die and casting procedure of selected"nnon precious alloy was performed by centrifugal method. Marginal gaps of each copping seated on dies"nwere measured by scanning electron microscope (SEM with X500 magnification. Measurements were"ndone on three areas of marked dies on buccal aspect. Measurement son palatal aspect was done on"nmarked midpalatal point as control."nResults and statistical analysis showed no significant difference among marginal gaps in lingual aspect."nBut on the buccal aspect there were statistically significant differences among the groups (P<0.001. Flat"nshoulder had the best marginal integrity (mean 4 micron. Shoulder with 160' bevel had the most marginal"ngap (mean 26.5 micron and shoulder with 1357 bevel was between two other groups (mean 15.7 micron.

  19. Memory phenomenon in a lanthanum based bulk metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, Ye [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore); Huang, Wei Min, E-mail: mwmhuang@ntu.edu.sg [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore); Zhao, Yong [School of Chemistry and Chemical Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013 (China); Ding, Zhen [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore); Li, Yan [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Tor, Shu Beng; Liu, Erjia [School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798 (Singapore)

    2016-07-05

    In this paper, we experimentally investigate two memory phenomena in a lanthanum based bulk metallic glass (BMG). While the temperature memory effect (TME) is not found by differential scanning calorimeter (DSC) test, shape recovery is observed in samples indented at both low and high temperatures. In terms of shape memory related characteristics, this BMG shares some features of shape memory alloys (SMAs) due to its metal nature, and some other features of shape memory polymers (SMPs) owing to its glassy–rubbery transition. The formation of protrusion in the polished sample after heating to super-cooled liquid region (SCLR) indicates that surface tension is not a necessarily positive contributor for shape recovery. Release of internal elastic stress is concluded as the major player. Although the amorphous nature of BMGs enables for storing appreciable amount of internal elastic stress upon deformation, without the presence of cross-linker as in typical SMPs, the shape recovery in BMGs is rather limited. - Highlights: • Experimental investigation of shape recovery in BMG. • Surface tension is not the major reason for shape recovery in BMG. • Release of internal stress is the major contributor for shape recovery. • Comparison of shape memory features of BMG with other shape memory materials.

  20. Multifunctional methacrylate-based coatings for glass and metal surfaces

    Science.gov (United States)

    Pospiech, Doris; Jehnichen, Dieter; Starke, Sandra; Müller, Felix; Bünker, Tobias; Wollenberg, Anne; Häußler, Liane; Simon, Frank; Grundke, Karina; Oertel, Ulrich; Opitz, Michael; Kruspe, Rainer

    2017-03-01

    In order to prevent freshwater biofouling glass and metal surfaces were coated with novel transparent methacrylate-based copolymers. The multifunctionality of the copolymers, such as adhesion to the substrate, surface polarity, mechanical long-term stability in water, and ability to form metal complexes was inserted by the choice of suitable comonomers. The monomer 2-acetoacetoxy ethyl methacrylate (AAMA) was used as complexing unit to produce copper(II) complexes in the coating's upper surface layer. The semifluorinated monomer 1H,1H,2H,2H-perfluorodecyl methacrylate was employed to adjust the surface polarity and wettability. Comprehensive surface characterization techniques, such as X-ray photoelectron spectroscopy (XPS) and contact angle measurements showed that surface compositions and properties can be easily adjusted by varying the concentrations of the comonomers. The formation of copper(II) complexes along the copolymer chains and their stability against washing out with plenty of water was proven by XPS. Copolymers containing semifluorinated comonomers significantly inhibited the growth of Achnanthidium species. Copolymers with copper-loaded AAMA-sequences were able to reduce both the growth of Achnanthidium spec. and Staphylococcus aureus.

  1. Process for recovering uranium and other base metals

    International Nuclear Information System (INIS)

    Jan, R.J.

    1984-01-01

    Uranium and other base metals are leached from their ores with aqueous solutions containing bicarbonate ions that have been generated or reconstituted by converting other non-bicarbonate anions into bicarbonate ions. The conversion is most conveniently effected by contacting solutions containing SO 4 2- and Cl - ions with a basic anion exchange resin so that the SO 4 2- and Cl - ions are converted into or exchanged for HCO 3 - ions. CO 2 may be dissolved in the solution so it is present during the exchange. The resin is preferably in bicarbonate form prior to contact and CO 2 partial pressure is adjusted so that the resin is not fouled by depositing metal precipitates. In-situ uranium mining is conducted by circulating such solutions through the ore deposit. Oxidizing agents are included in the injected lixiviant. The leaching strength of the circulating bicarbonate lixiviant is maintained by converting the anions generated during leaching or above-ground recovery processes into HCO 3 - ions. The resin may conveniently be eluted and reformed intermittently

  2. Designing biocompatible Ti-based metallic glasses for implant applications

    International Nuclear Information System (INIS)

    Calin, Mariana; Gebert, Annett; Ghinea, Andreea Cosmina; Gostin, Petre Flaviu; Abdi, Somayeh; Mickel, Christine; Eckert, Jürgen

    2013-01-01

    Ti-based metallic glasses show high potential for implant applications; they overcome in several crucial respects their well-established biocompatible crystalline counterparts, e.g. improved corrosion properties, higher fracture strength and wear resistance, increased elastic strain range and lower Young's modulus. However, some of the elements required for glass formation (e.g. Cu, Ni) are harmful for the human body. We critically reviewed the biological safety and glass forming tendency in Ti of 27 elements. This can be used as a basis for the future designing of novel amorphous Ti-based implant alloys entirely free of harmful additions. In this paper, two first alloys were developed: Ti 75 Zr 10 Si 15 and Ti 60 Nb 15 Zr 10 Si 15 . The overheating temperature of the melt before casting can be used as the controlling parameter to produce fully amorphous materials or bcc-Ti-phase reinforced metallic glass nano-composites. The beneficial effect of Nb addition on the glass-formation and amorphous phase stability was assessed by X-ray diffraction, transmission electron microscopy and differential scanning calorimetry. Crystallization and mechanical behavior of ribbons are influenced by the amount and distribution of the nano-scaled bcc phase existing in the as-cast state. Their electrochemical stability in Ringer's solution at 310 K was found to be significantly better than that of commercial Ti-based biomaterials; no indication for pitting corrosion was recorded. Highlights: ► Link between biocompatibility and glass-forming ability of alloying additions in Ti ► Selection of Ti–Zr–Si and Ti–Zr–Nb–Si glass-forming alloys ► Two novel glassy alloys were developed: Ti 75 Zr 10 Si 15 and Ti 60 Nb 15 Zr 10 Si 15. ► Glass-formation, thermal stability, corrosion and mechanical behavior were studied. ► Assessing the suitability for orthopedic applications.

  3. Redox switching and oxygen evolution at oxidized metal and metal oxide electrodes: iron in base.

    Science.gov (United States)

    Lyons, Michael E G; Doyle, Richard L; Brandon, Michael P

    2011-12-28

    Outstanding issues regarding the film formation, redox switching characteristics and the oxygen evolution reaction (OER) electrocatalytic behaviour of multicycled iron oxyhydroxide films in aqueous alkaline solution have been revisited. The oxide is grown using a repetitive potential multicycling technique, and the mechanism of the latter hydrous oxide formation process has been discussed. A duplex layer model of the oxide/solution interphase region is proposed. The acid/base behaviour of the hydrous oxide and the microdispersed nature of the latter material has been emphasised. The hydrous oxide is considered as a porous assembly of interlinked octahedrally coordinated anionic metal oxyhydroxide surfaquo complexes which form an open network structure. The latter contains considerable quantities of water molecules which facilitate hydroxide ion discharge at the metal site during active oxygen evolution, and also charge compensating cations. The dynamics of redox switching has been quantified via analysis of the cyclic voltammetry response as a function of potential sweep rate using the Laviron-Aoki electron hopping diffusion model by analogy with redox polymer modified electrodes. Steady state Tafel plot analysis has been used to elucidate the kinetics and mechanism of oxygen evolution. Tafel slope values of ca. 60 mV dec(-1) and ca. 120 mV dec(-1) are found at low and high overpotentials respectively, whereas the reaction order with respect to hydroxide ion activity changes from ca. 3/2 to ca. 1 as the potential is increased. These observations are rationalised in terms of a kinetic scheme involving Temkin adsorption and the rate determining formation of a physisorbed hydrogen peroxide intermediate on the oxide surface. The dual Tafel slope behaviour is ascribed to the potential dependence of the surface coverage of adsorbed intermediates.

  4. Resistive switching in ZrO{sub 2} based metal-oxide-metal structures

    Energy Technology Data Exchange (ETDEWEB)

    Kaerkkaenen, Irina

    2014-07-01

    detail for 20 nm thick ZrO{sub 2} films grown by an ozone based ALD process and integrated into Pt/ZrO{sub 2}/Ti/Pt cells while the thickness of the electrochemically active electrode (Ti) was varied from 0 nm to 40 nm. Cells with a thin EAE (<20 nm Ti) exhibited a UP-type RS behavior, while cells with thick EAE (>20 nm Ti) showed BP switching characteristics at a lower current compliance as the UP switching cells. A detailed structural analysis of the ozone grown ZrO{sub 2} films revealed a polycrystalline structure of columnar shaped grains with a meta-stable cubic-tetragonal ZrO{sub 2} phase. In the second part of the thesis an empirical model for the polarity dependence of the RS in the ALD ZrO{sub 2} based devices as a function of the EAE thickness was suggested. The model assumed a columnar shaped microstructure and certain impurity content for the ZrO{sub 2} films. In addition, the results of current-voltage behavior, temperature dependency of the resistance states and impedance spectroscopy (IS) measurements of different devices in different RS states were considered. Impedance spectroscopy measurements of UP and BP type switching devices with the same ZrO{sub 2} films but with different EAE thicknesses were carried out for the states prior to electroforming (pristine), after RS into the ON-state and after RS into the OFF-state. The different devices in their pristine states exhibited nearly identical IS characteristics while the ON and OFF states of the UP and BP devices revealed pronounced differences. In the model, the UP switching in ZrO{sub 2} based devices with thin EAE was described as a result of a noncomplete local reduction of the grain boundary cores, which might gave rise to a hard thermal breakdown and the formation of metallic like conduction paths. On the contrary, the suggested idea for BP switching of ZrO{sub 2} based devices with thick EAE based on the formation of local semiconducting oxygen depleted ZrO{sub 2-x} filament-like regions along

  5. Resistive switching in ZrO2 based metal-oxide-metal structures

    International Nuclear Information System (INIS)

    Kaerkkaenen, Irina

    2014-01-01

    The goal of this work is a deeper understanding of the influence of the (i) metal-oxide-metal (MOM) layer stacks configuration, (ii) the oxide films microstructure, (iii) and their defect structure on the appearance of different switching modes, i.e. unipolar (UP) and bipolar (BP). The first part deals with the fabrication of ZrO 2 thin films by an industrial compatible atomic layer deposition (ALD) process, the chemical, structural and morphological characterization of the films, the growth of ZrO 2 /TiO 2 bilayers, the integration of the layers into metal-oxide-metal (MOM) devices and the electrical characterization with focus on the RS behavior. In the second part the effect of the device structure, in particular the thickness of the electrochemical active electrode (EAE) and the ZrO 2 film morphology, on the RS switching polarity of Pt/ZrO 2 /(EAE) cells is discussed. ZrO 2 films and ZrO 2 /TiO 2 bilayers were grown by ALD and were carefully structurally and electrically characterized. The ZrO 2 films grown from Zr[N(CH 3 )C 2 H 5 ] 4 (TEMA-Zr) at 240 C were polycrystalline with a mixture of cubic/tetragonal phases. ALD/H 2 O-ZrO 2 films exhibited a random oriented polycrystalline structure, whereas the ALD/O 3 -ZrO 2 films consisted of preferably oriented cubic shaped grains. Pt/ZrO 2 /Ti/Pt structures with a Ti top electrode (TE) thickness of 5 to 20 nm showed unipolar type RS behavior, while by increasing the Ti TE thickness a gradual change of switching polarity from unipolar to bipolar with a completely bipolar type RS behavior for a Ti TE thickness of 40 nm is found. The switching in Pt/ZrO 2 /TiO 2 /Ti/Pt devices was unipolar, comparable to Pt/ZrO 2 /Ti/Pt cells. In contrast, bilayers with the reverse structure, Pt/TiO 2 /ZrO 2 /Ti/Pt, showed non-switching behavior. The effect of the cells stack structure on the polarity of the RS behavior was studied in detail for 20 nm thick ZrO 2 films grown by an ozone based ALD process and integrated into Pt/ZrO 2

  6. Enrichment and characterization of hydrocarbon-degrading bacteria from petroleum refinery waste as potent bioaugmentation agent for in situ bioremediation.

    Science.gov (United States)

    Sarkar, Poulomi; Roy, Ajoy; Pal, Siddhartha; Mohapatra, Balaram; Kazy, Sufia K; Maiti, Mrinal K; Sar, Pinaki

    2017-10-01

    Intrinsic biodegradation potential of bacteria from petroleum refinery waste was investigated through isolation of cultivable strains and their characterization. Pseudomonas and Bacillus spp. populated the normal cultivable taxa while prolonged enrichment with hydrocarbons and crude oil yielded hydrocarbonoclastic bacteria of genera Burkholderia, Enterobacter, Kocuria, Pandoraea, etc. Strains isolated through enrichment showed assemblages of superior metabolic properties: utilization of aliphatic (C6-C22) and polyaromatic compounds, anaerobic growth with multiple terminal electron acceptors and higher biosurfactant production. Biodegradation of dodecane was studied thoroughly by GC-MS along with detection of gene encoding alkane hydroxylase (alkB). Microcosms bioaugmented with Enterobacter, Pandoraea and Burkholderia strains showed efficient biodegradation (98% TPH removal) well fitted in first order kinetic model with low rate constants and decreased half-life. This study proves that catabolically efficient bacteria resides naturally in complex petroleum refinery wastes and those can be useful for bioaugmentation based bioremediation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Pemex to acquire interest in Shell Texas refinery

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper reports that Petroleos Mexicanos and Shell Oil Co. have signed a memorandum of understanding to form a joint refining venture involving Shell's 225,000 b/d Deer Park, Tex., refinery. Under the agreement, Mexico's state owned oil company is to purchase a 50% interest in the refinery, and Shell is to sell Pemex unleaded gasoline on a long term basis. Under the venture, Shell and Pemex plan to add undisclosed conversion and upgrading units tailored to process heavy Mexican crude. The revamp will allow Pemex to place more than 100,000 b/d of Mayan heavy crude on the U.S. market. Mayan accounts for 70% of Mexico's crude oil exports. In turn, Shell will sell Pemex as much as 45,000 b/d of unleaded gasoline to help meet Mexico's rapidly growing demand

  8. Refinery production planning and scheduling: the refining core business

    Directory of Open Access Journals (Sweden)

    M. Joly

    2012-06-01

    Full Text Available Intelligent production planning and scheduling are of paramount importance to ensure refinery profitability, logistic reliability and safety at the local and corporate levels. In Brazil, such activities play a particularly critical role, since the Brazilian downstream model is moving towards a demand-driven model rather than a supply-driven one. Moreover, new and specialized non-linear constraints are continuously being incorporated into these large-scale problems: increases in oil prices implying the need for processing poor quality crudes, increasing demand and new demand patterns for petroleum products, new stringent environmental regulations related to clean fuels and start-up of new production technologies embedded into more complex refining schemes. This paper aims at clarifying the central role of refinery planning and scheduling activities in the Petrobras refining business. Major past and present results are outlined and corporate long-term strategies to deal with present and future challenges are presented.

  9. Application of PIMS Software in Monthly Planning of Refinery Production

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refining production such as optimized selection of crude and feedstocks, optimized selection of production scale and processing scheme, identification of bottlenecks and their mitigation,optimized selection of turnaround time and optimized selection of operating regime, which have increased the economic benefits of refining enterprises. With the further development and improvement of models the PIMS software will play an increasingly important role in formulating monthly plans of refining operations and production management at refineries. This article also explores the problems existing in refinery monthly planning, and has made recommendations on developing and improving models and reporting system, enhancement of basic data acquisition, model maintenance personnel and staff training.

  10. Commercial Implementation of Model-Based Manufacturing of Nanostructured Metals

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, Terry C. [Los Alamos National Laboratory

    2012-07-24

    Computational modeling is an essential tool for commercial production of nanostructured metals. Strength is limited by imperfections at the high strength levels that are achievable in nanostructured metals. Processing to achieve homogeneity at the micro- and nano-scales is critical. Manufacturing of nanostructured metals is intrinsically a multi-scale problem. Manufacturing of nanostructured metal products requires computer control, monitoring and modeling. Large scale manufacturing of bulk nanostructured metals by Severe Plastic Deformation is a multi-scale problem. Computational modeling at all scales is essential. Multiple scales of modeling must be integrated to predict and control nanostructural, microstructural, macrostructural product characteristics and production processes.

  11. Microstructure-Based Counterfeit Detection in Metal Part Manufacturing

    Science.gov (United States)

    Dachowicz, Adam; Chaduvula, Siva Chaitanya; Atallah, Mikhail; Panchal, Jitesh H.

    2017-11-01

    Counterfeiting in metal part manufacturing has become a major global concern. Although significant effort has been made in detecting the implementation of such counterfeits, modern approaches suffer from high expense during production, invasiveness during manufacture, and unreliability in practice if parts are damaged during use. In this paper, a practical microstructure-based counterfeit detection methodology is proposed, which draws on inherent randomness present in the microstructure as a result of the manufacturing process. An optical Physically Unclonable Function (PUF) protocol is developed which takes a micrograph as input and outputs a compact, unique string representation of the micrograph. The uniqueness of the outputs and their robustness to moderate wear and tear is demonstrated by application of the methodology to brass samples. The protocol is shown to have good discriminatory power even between samples manufactured in the same batch, and runs on the order of several seconds per part on inexpensive machines.

  12. A metal-based inhibitor of NEDD8-activating enzyme.

    Directory of Open Access Journals (Sweden)

    Hai-Jing Zhong

    Full Text Available A cyclometallated rhodium(III complex [Rh(ppy(2(dppz](+ (1 (where ppy=2-phenylpyridine and dppz=dipyrido[3,2-a:2',3'-c]phenazine dipyridophenazine has been prepared and identified as an inhibitor of NEDD8-activating enzyme (NAE. The complex inhibited NAE activity in cell-free and cell-based assays, and suppressed the CRL-regulated substrate degradation and NF-κB activation in human cancer cells with potency comparable to known NAE inhibitor MLN4924. Molecular modeling analysis suggested that the overall binding mode of 1 within the binding pocket of the APPBP1/UBA3 heterodimer resembled that for MLN4924. Complex 1 is the first metal complex reported to suppress the NEDDylation pathway via inhibition of the NEDD8-activating enzyme.

  13. Development of a metal-based composite actuator

    Science.gov (United States)

    Asanuma, Hiroshi; Haga, Osamu; Ishii, Toshio; Kurihara, Haruki; Ohira, Junichiro; Hakoda, Genji

    2000-06-01

    This paper describes a basic concept and elemental developments to realize a metal based composite actuator to be used for smart structures. In this study, CFRP prepreg was laminated on aluminum plate to develop an actuator and this laminate could perform unidirectional actuation. SiC continuous fiber/Al composite thin plate could also be used for form a modified type of actuator instead of using CFRP. As sensors to be embedded in this actuator, the following ones wee developed. (1) A pre-notched optical fiber filament could be embedded in aluminum matrix without fracture by the interphase forming/bonding method with copper insert and could be fractured in it at the notch, which enabled forming of an optical interference type strain sensor. (2) Nickel wire could be uniformly oxidized and embedded in aluminum matrix without fracture, which could successfully work as a temperature sensor and a strain sensor.

  14. Radioisotope techniques for problem-solving on refineries

    International Nuclear Information System (INIS)

    Charlton, J.S.; Webb, M.

    1994-01-01

    Increasingly, refineries worldwide are recognizing the value of radioisotope technology in studying the operation of on-line plant. Using case studies, this paper illustrates the versatility of radioisotope techniques in a wide range of investigations: the density-profiling of distillation columns; the investigation of leaks on feed/effluent exchangers; on-line flowrate measurement; underground leakage detection. The economic benefits deriving from radioisotope applications are indicated

  15. Legitimacy in Green: Pollution vs. Profit in Canadian Oil Refineries

    Directory of Open Access Journals (Sweden)

    Vanessa Magness

    2007-06-01

    light of changing societal expectations have created an external environment that encourages the development of new technologies that promote cost efficiencies and good environmental performance simultaneously.  Russo and Fouts (1997 argued that industries subject to rapid technological advance are well suited to respond to these changes in the external environment. The findings of this paper suggest that the petroleum refinery sector of the oil and gas industry may be meeting the challenge of the environmental movement.

  16. SPARO - A system for process analysis of refinery operations

    Energy Technology Data Exchange (ETDEWEB)

    Kesler, M.G.; Graham, J.; Weissbrod, J.

    1987-01-01

    SPARO is a customized process simulator for the PC, designed to review as well as to guide operations of hydrocarbon processing units. It can be applied to: gas plants or refinery gas recovery units; crude/vacuum towers with associated heat exchange; light ends units, such as reforming, alkylation and isomerization; fractionation and heat exchange units of Ethylene plants; aromatics and styrene units, and others. The main uses of SPARO are discussed in this paper.

  17. POSSIBILITIES OF CARBON DIOXIDE FIXATION BY MICROALGAE IN REFINERY

    OpenAIRE

    Šingliar, Michal; Mikulec, Jozef; Kušnir, Patrik; Polakovičova, Gabriela

    2013-01-01

    Capture and sequestration of carbon dioxide is one of the most critical challenges today for businesses and governments worldwide. Thousands of emitting power plants and industries worldwide face this costly challenge – reduce the CO2 emissions or pay penalties. One possibility for carbon dioxide sequestration is its fixation in microalgae. Microalgae can sequester CO2 from flue gases emitted from fossil fuel-fired refinery plants and units, thereby reducing emissions of a major greenhouse ga...

  18. A Novel Transporting System Model for Oil Refinery

    OpenAIRE

    Razman M. Tahar; Waleed K. Abduljabbar

    2010-01-01

    Problem statement: Oil refineries are widely used to store various liquids and gases. Petroleum products are in high demand. Oil companies have abundant resources of petroleum products in pipelines and storage tanks. Approach: Included are storage tanks at retail gasoline station, home heating oil tanks, lubricant storage at automotive service facilities, propane tanks in all sorts of application, and oil company terminals across the world. The aim of this study is to present a model by which...

  19. Hydrogen management in the MiRO refinery

    Energy Technology Data Exchange (ETDEWEB)

    Neumann, G. [Mineraloelraffinerie Oberrhein GmbH und Co. KG, Karlsruhe (Germany)

    2010-12-30

    The importance of hydrogen in refineries has increased over the last 20 years as new regulations affecting gasoline and diesel composition have been implemented throughout Europe and in an environment of increasingly stringent clean fuel regulations, decreasing heavy fuel oil demand and increasing heavy more sour crude supply. In Germany, the introduction of sulphur free gasoline and diesel with less than 10ppm sulphur(Auto Oil Program) and light home fuel oil with less than 50ppm this year were the last link in a long chain of environmental regulations, which had a considerable effect on the hydrogen demand in refineries. In the complex MiRO-refinery with a large FCC- and Coker-Unit for atmospheric residue conversion and a total throughput of more than 15 Mio.T/ a and more than 14 Mio.T/a crude oils of different origin from high sulphur, bituminous crudes to medium, low sulphur crudes for calcinate-production from green coke the only source of hydrogen for a long time was catalytic reforming. The only chance of balancing the hydrogen production and consumption was to improve the existing catalytic reforming and the optimisation of hydrogen recovery from waste or purge streams and the hydrogen network of the refinery. In 2007 a new hydrogen plant via steam reforming of natural gas went on stream. The main reason for this step was the shrinking market for gasoline in the last ten years and the blending of bio-ethanol into the gasoline pool, which released reforming capacities and the demand for octane. Another important issue is the production planning taking into account the potentials of hydrogen production via catalytic and steam reforming and the hydrogen consumption via desulphurisation and the saturation of olefins and (poly-)aromatics of the main product streams, gasoline, diesel and light home fuel oil. (orig.)

  20. Global Warming Potential Of A Waste Refinery Using Enzymatic Treatment

    DEFF Research Database (Denmark)

    Tonini, Davide; Astrup, Thomas

    2010-01-01

    and fossil resources. This is especially important with respect to the residual waste (i.e. the remains after source-separation and separate collection) which is typically incinerated or landfilled. In this paper the energy and Global Warming performance of a pilot-scale waste refinery for the enzymatic...... plants and utilization of the liquid fraction for biogas production turned out to be the best options with respect to energy and Global Warming performance....

  1. US refineries lament lack of final CAA rules

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    Bush administration spokesman appeared unconvinced about the extent of the U.S. refining industry's problems at a Senate energy committee hearing. This paper reports that the oversight hearing examined various challenges facing refiners. Roger Beach, president of Unocal Refining and Marketing Division, testified for the National Petroleum Refiners Association, of which he is chairman. Beach the refineries still do not know what final Clean Air Act (CAA) amendments regulations will be, and state rules are changing, too

  2. Oxidation behaviour of Zr-based bulk metallic glasses

    International Nuclear Information System (INIS)

    Wang, Bin

    2011-01-01

    The Zr-based bulk metallic glasses, developed since the late 1980's, have very interesting mechanical properties, which can be considered for many applications including working under oxidizing atmosphere conditions at high temperatures. It is therefore interesting to study their oxidation resistance and to characterize the oxide scale formed on alloys surface. The fundamental objective of this thesis is to enhance the understanding of the role of various thermodynamic and chemistry parameters on the oxidation behaviour of the Zr-based bulk metallic glasses at high temperature under dry air, to determine the residual stresses in the oxide layer, in comparison with their crystalline alloys with the same chemical composition after an annealing treatment. The oxidation kinetics of these glasses and the crystalline structure of oxide scale ZrO 2 depend on the temperature and the oxidation duration: for short periods of oxidation or at a temperature below Tg, the kinetics follows a parabolic law, whereas, if the sample is oxidized at T ≥ Tg, the kinetics can be divided into two parts. The crystalline counterparts are oxidized by a parabolic rule whatever the temperature; for long oxidation duration at a temperature close to Tg, the kinetics becomes more complex because of the crystallisation of the glasses during the oxidation tests. Also the crystalline structure of the oxide layers depends on the oxidation temperature: the oxide layer consists only in tetragonal Zirconia at T ≤ Tg, while monoclinic Zirconia was formed at higher temperature. The mechanism of the formation of the oxide scale is due to both the interior diffusion of Oxygen ions and the external diffusion of Zirconium ions. However the diffusion of Zirconium ions slows gradually during the crystallisation process of the glass matrix. When the crystallisation is completed, the formation of Zirconia is controlled by only the internal diffusion of oxygen ions. The corresponding residual stresses

  3. Analysis and control of odors from petroleum refineries

    International Nuclear Information System (INIS)

    O'Brien, M.A.; Duffee, R.A.; Ostojic, N.

    1992-01-01

    This paper presents a proven approach used to effectively solve odor problems associated with atmospheric emissions from petroleum refineries. A systematic evaluation is first conducted to identify all emissions with the potential for off-site odor impacts. Sampling is then conducted and dynamic dilution olfactometry is used to quantify the odor emission rates of each source. Community odor surveys are performed simultaneously with the source sampling to quantitatively document the downwind odor impacts. Atmospheric dispersion modeling specifically designed for odor is then used to predict instantaneous odor occurrences at various receptor sites under meteorological conditions not actually encountered during the field study. The findings make it possible to rank sources by their odor emission rates and potential for odor impacts in the community. It is then possible to determine how much odor reduction is required to bring the present odor impacts of the individual sources to an acceptable level under worst-case meteorological conditions. Once the degree of control required is determined, control alternatives are selected and evaluated. Case histories have been selected to illustrate the application of this approach at petroleum refineries. They provide descriptions of odor assessment and abatement studies conducted specifically for refinery effluent treatment plant sources as well as process unit emission sources. The sources identified as needing control and the odor abatement measures taken are discussed

  4. Continues treatment of oily sludge at Colombian refineries

    International Nuclear Information System (INIS)

    Echeverria, Victor; Monsalve, Gladys; Vidales, Humberto

    2002-01-01

    The Colombian Petroleum institute - ICP, the research and development branch of Ecopetrol has developed a unique technological package used to treat oily sludge in a continuous way. The sludge comes from a refinery with 220000 barrels of crude per day load, located in the Middle Madgalena River Valley in Colombia. The technological package allows for a) the recovery of the hydrocarbon contained in oily wastes (up to 50%) b) the elimination of the oil contained in solid using a biodegradation process and, c) the availability economically and technically feasible solution to handle oily sludge generated in the refinery. The oily treated in this process come from maintenance of refinery's equipment and also from the physical chemical separation process at the industrial wastewater treatment plant. Oily sludge is a complex system where light and heavy oils, contaminated water and contaminated solids coexist in the form of direct, inverse and multiple emulsions. The comprehensive technological package allows the treatment of oily sludge in a cost effective way. ICP technological package developed includes technologies combining mechanical, thermal, chemical and electrostatic dehydration techniques and stimulated and intensive bioremediation to decontamination of solids saturated with residual oil. This technological package brings a solution to old environmental problem caused by the inappropriate final disposal of oily wastes such as storage in ponds, marshes and open pits: Nowadays wastes generated are treated in a continuous process that is environmentally friendly and economically profitable

  5. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    Energy Technology Data Exchange (ETDEWEB)

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  6. Treatment of Refinery Waste Water Using Environmental Friendly Adsorbent

    Science.gov (United States)

    Devi, M. Geetha; Al-Moshrafi, Samira Mohammed Khamis; Al Hudaifi, Alaa; Al Aisari, Buthaina Hamood

    2017-12-01

    This research evaluates the effectiveness of activated carbon prepared from walnut shell in the removal of pollutants from refinery waste water by adsorption technique. A series of batch experiments were carried out by varying the effluent solution pH, stirring time, stirring speed and adsorbent dosage in the reduction of pollutants from refinery effluent. Characterization of the adsorbent was performed using Scanning Electron Microscopy (SEM), Brunauer Emmett and Teller (BET) isotherm and Fourier Transform Infrared (FTIR) Spectroscopy. The best quality activated carbon was obtained with a particle size of 0.75 µm, activation temperature of 800 °C and activation time 24 h. The maximum BET surface area obtained was 165.2653 m2/g. The experimental results demonstrates that the highest percentage reduction in COD was 79%, using 0.6 g walnut shell powder at an optimum stirring speed of 100 rpm, at pH 6 and 120 min of contact time. The outcome of the result shows that walnut shell carbon is a potentially useful adsorbent for the removal of pollutants from refinery waste water.

  7. Where to implement local biotech innovations? A framework for multi-scale socio-economic and environmental impact assessment of Green Bio-Refineries

    DEFF Research Database (Denmark)

    Cong, Ronggang; Stefaniak, Irena; Madsen, Bjarne

    2017-01-01

    Green Bio-Refineries (GBRs) have economic and environmental potentials through changing land use from cereals to grass production and provision of grass-based protein feed for livestock production and other valuable byproducts. However, the potentials are dependent on local conditions of the GBRs...

  8. Test-beds for molecular electronics: metal-molecules-metal junctions based on Hg electrodes.

    Science.gov (United States)

    Simeone, Felice Carlo; Rampi, Maria Anita

    2010-01-01

    Junctions based on mesoscopic Hg electrodes are used to characterize the electrical properties of the organic molecules organized in self-assembled monolayers (SAMs). The junctions M-SAM//SAM-Hg are formed by one electrode based on metals (M) such as Hg, Ag, Au, covered by a SAM, and by a second electrode always formed by a Hg drop carrying also a SAM. The electrodes, brought together by using a micromanipulator, sandwich SAMs of different nature at the contact area (approximately = 0.7 microm2). The high versatility of the system allows a series of both electrical and electrochemical junctions to be assembled and characterized: (i) The compliant nature of the Hg electrodes allows incorporation into the junction and measurement of the electrical behavior of a large number of molecular systems and correlation of their electronic structure to the electrical behavior; (ii) by functionalizing both electrodes with SAMs exposing different functional groups, X and Y, it is possible to compare the rate of electron transfer through different X...Y molecular interactions; (iii) when the junction incorporates one of the electrode formed by a semitransparent film of Au, it allows electrical measurements under irradiation of the sandwiched SAMs. In this case the junction behaves as a photoswitch; iv) incorporation of redox centres with low lying, easily reachable energy levels, provides electron stations as indicated by the hopping mechanism dominating the current flow; (v) electrochemical junctions incorporating redox centres by both covalent and electrostatic interactions permit control of the potential of the electrodes with respect to that of the redox state by means of an external reference electrode. Both these junctions show an electrical behavior similar to that of conventional diodes, even though the mechanism generating the current flow is different. These systems, demonstrating high mechanical stability and reproducibility, easy assembly, and a wide variety of

  9. Optimization of water network in petroleum refinery; Otimizacao de redes de agua em refinarias de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Debora C.; Souza, Selene M.A. Guelli Ulson de; Souza, Antonio A. Ulson de [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil)

    2004-07-01

    The petroleum refineries have shown high water's consuming that creates high costs and damages the hydric resources. However, the industrial sector, especially the petroleum industry, has been looking for alternatives that minimizing the impact caused by to use these natural resources. Currently, methodologies of controlling the pollution on the source have been appearing how a strong tendency and the reuse and/or recycle of wastewater can be emphasized. The optimization by mathematical programming, together with engineering know-how, is one of the great tendency in process integration technology developed. The present work presents one optimization mathematical model that objectifies to reduce the water's consuming and/or operational costs. The model is based in chemical species and mass conservation equation. This work presents the solution of one case found in literature that broach one petroleum refinery's network of water. This network is composed of six operations and three regenerative processes, and there are four keys contaminants. The water's consuming was minimized first and next the minimum cost in the minimum consume was broached. The results found were enough satisfactory and presented reductions up to 76% in the water consume and approximately 65% in the operational costs. (author)

  10. Determination of levels nd interfaces in oil refinery fractioning towers, with neutron retrodispersion

    International Nuclear Information System (INIS)

    Diaz, F; Henriquez, P; Vega, P

    2003-01-01

    In the petrochemical industry and, especially, in oil refineries measurement and the control of levels and interfaces in tanks, fractioning towers and processing equipment, in general, are extremely important for managing and knowing about the different fluids that are processed in the plants. Usually there is on-line instrumentation at the plant's critical points, like floaters, external glass columns and, even, gamma radiation sources through the transmission system. A problem arises with the need for a system that can rapidly and non destructively measure levels and interfaces, outside the system to be inspected and verify the functioning of the on-line instrumentation and in places where there is no instrumentation. This work presents a methodology based on the retrodispersion of neutrons that have been used in 3 breakdown towers at the Petrox Oil Refinery, Region VIII in Chile, to identify levels and interfaces in different points in order to verify the functioning of a gamma level meter, glass column meters and to observe on site and in real time the variations in level and interfaces when carrying out different operations that will modify the values in the towers. The set of instruments used include a 1010 GBq Americium-Beryllium source and a measuring system consisting of a BF 3 (boron trifluoride) detector and its electronically related Model 2241 from Ludlum Instruments. The set is placed in a geometry that permits precise measurements (Cw)

  11. Optimization of petroleum refinery effluent treatment in a UASB reactor using response surface methodology

    International Nuclear Information System (INIS)

    Rastegar, S.O.; Mousavi, S.M.; Shojaosadati, S.A.; Sheibani, S.

    2011-01-01

    Highlights: ► A UASB was successfully used for treatment of petroleum refinery effluent. ► Response surface methodology was applied to design and analysis of experiments. ► System was modeled between efficient factors include HRT, influent COD and V up . ► UASB was able to remove about 76.3% influent COD at optimum conditions. - Abstract: An upflow anaerobic sludge blanket (UASB) bioreactor was successfully used for the treatment of petroleum refinery effluent. Before optimization, chemical oxygen demand (COD) removal was 81% at a constant organic loading rate (OLR) of 0.4 kg/m 3 d and a hydraulic retention time (HRT) of 48 h. The rate of biogas production was 559 mL/h at an HRT of 40 h and an influent COD of 1000 mg/L. Response surface methodology (RSM) was applied to predict the behaviors of influent COD, upflow velocity (V up ) and HRT in the bioreactor. RSM showed that the best models for COD removal and biogas production rate were the reduced quadratic and cubic models, respectively. The optimum region, identified based on two critical responses, was an influent COD of 630 mg/L, a V up of 0.27 m/h, and an HRT of 21.4 h. This resulted in a 76.3% COD removal efficiency and a 0.25 L biogas/L feed d biogas production rate.

  12. Hydroisomerization of different refinery naphtha streams by using a beta zeolite catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Ramos, Maria Jesus; de Lucas, Antonio; Jimenez, Vicente; Sanchez, Paula; Valverde, Jose Luis [Departamento de Ingenieria Quimica, Facultad de Ciencias Quimicas, Universidad de Castilla-La Mancha, Avd. Camilo Jose Cela s/n, 13071 Ciudad Real (Spain)

    2008-08-15

    In this work, the evaluation of a catalyst based on beta zeolite agglomerated with bentonite in the hydroisomerization of three feeds obtained by distillation of refinery naphtha streams provided by the petroleum company REPSOL-YPF was considered. These refinery naphthas were different in composition, being constituted mostly by different proportions of paraffin, aromatic and naphthenic compounds. The highest overall paraffin conversion value was obtained with that naphtha with the highest content in linear paraffins. As the classical hydroisomerization mechanism predicts, linear alkanes were transformed into branched isomers. Thus, the relation between branched isomers and linear paraffins (iC6/nC6, iC7/nC7 and iC8/nC8) was higher in the products than in the feed. The presence of the aromatic compounds (benzene and toluene) was detected in the three feeds. In all cases, a complete benzene conversion, leading to naphthenic compounds formation, was reached. Long-term tests showed that, regardless of the type of naphtha fed to the reactor, the research octane number of the products remained practically constant. (author)

  13. Enhanced treatment of refinery soils with open-system slurry reactors

    International Nuclear Information System (INIS)

    Blackburn, J.W.; Lee, M.K.; Horn, W.C.

    1995-01-01

    Refinery site cleanups of residual hydrocarbons arising from long-term operations have become a concern. Because contaminated soil has been generated over many years from spills of many types of materials, it is often difficult to identify the actual spilled material. Because many of these materials are weathered, the less degradable fractions can predominate, creating a challenge for bioremedial process solutions. Open-system slurry reactors were run with an aged refinery soil after a 6-month period of field bioremediation in which 23% TPH removal resulted. The open system (a system where the liquid medium was replaced daily and the solids were retained in the reactor for 2 weeks) achieved 60 to 80% total petroleum hydrocarbon (TPH) removal based on the initial, prefield bioremediation soil concentration. A process concept twice as effective as other bioremediation schemes has been devised that takes advantage of the formation and removal of small black particulate solids in an open or continuous slurry reactor configuration. These small black particles are chemically or biologically produced in the open system and with their small size and low density are easily elutriated from the bioreactor as the liquid medium is changed. A statistically designed experiment has determined optimal values of nutrients, temperature, and mixing

  14. Discrete event simulation for petroleum transfers involving harbors, refineries and pipelines

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Marcella S.R.; Lueders, Ricardo; Delgado, Myriam R.B.S. [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil)

    2009-07-01

    Nowadays a great effort has been spent by companies to improve their logistics in terms of programming of events that affect production and distribution of products. In this case, simulation can be a valuable tool for evaluating different behaviors. The objective of this work is to build a discrete event simulation model for scheduling of operational activities in complexes containing one harbor and two refineries interconnected by a pipeline infrastructure. The model was developed in Arena package, based on three sub-models that control pier allocation, loading of tanks, and transfers to refineries through pipelines. Preliminary results obtained for a given control policy, show that profit can be calculated by taking into account many parameters such as oil costs on ships, pier using, over-stay of ships and interface costs. Such problem has already been considered in the literature but using different strategies. All these factors should be considered in a real-world operation where decision making tools are necessary to obtain high returns. (author)

  15. Management and analysis of data from petroleum refinery wastewater treatment plants

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, D T [Wastewater, Technology Centre, Burlington, ON (Canada); Grammas, J [SOHO, Lima, OH (USA)

    1989-01-01

    Current efforts to monitor trace contaminants in treated oil refinery wastewaters increase the need to implement systematic, clear, and consistent procedures for reporting and presenting all monitoring data. The ability to interpret trace contaminant data which is to be collected by the governments of the U.S. and Canada for regulations development will rely on information about operating procedures and the efficiency of removal of conventional pollutants. An overview is provided of the main issues which must be addressed in managing and analyzing data from wastewater treatment facilities. The objectives of enviromental data management and analysis are discussed from the point of view of both the plant operator or owner and the regulatory authority. Based on the examination of the 1985 records of flow and phenol concentrations from seven Canadian petroleum refineries, recommendations are made for improving existing databases. In analyzing environmental data to transform raw data into information, exploratory data analysis techniques should be used by engineers or operators who do not have formal statistical training. These methods employ simple statistical summaries and graphical data displays. The paper concludes with a brief discussion about future trends in environmental data management and analysis. 15 refs., 5 figs., 2 tabs.

  16. Effect of metal selection and porcelain firing on the marginal accuracy of titanium-based metal ceramic restorations.

    Science.gov (United States)

    Shokry, Tamer E; Attia, Mazen; Mosleh, Ihab; Elhosary, Mohamed; Hamza, Tamer; Shen, Chiayi

    2010-01-01

    Titanium is the most biocompatible metal used for dental casting; however, there is concern about its marginal accuracy after porcelain application since this aspect has direct influence on marginal fit. The purpose of this study was to determine the effect that metal selection and the porcelain firing procedure have on the marginal accuracy of metal ceramic prostheses. Cast CP Ti, milled CP Ti, cast Ti-6Al-7Nb, and cast Ni-Cr copings (n=5) were fired with compatible porcelains (Triceram for titanium-based metals and VITA VMK 95 for Ni-Cr alloy). The Ni-Cr alloy fired with its porcelain served as the control. Photographs of metal copings placed on a master die were made. Marginal discrepancy was determined on the photographs using an image processing program at 8 predetermined locations before airborne-particle abrasion for porcelain application, after firing of the opaque layer, and after firing of the dentin layer. Repeated-measures 2-way ANOVA was used to investigate the effect of metal selection and firing stage, and paired t tests were used to determine the effect of each firing stage within each material group (alpha=.05). ANOVA showed that both metal selection and firing stage significantly influenced the measured marginal discrepancy (Pcast Ti-6Al-7Nb alloy (P=.003). Titanium copings fabricated by CAD/CAM demonstrated the least marginal discrepancy among all groups, while the base metal (Ni-Cr) groups exhibited the most discrepancy of all groups tested. Copyright 2010 The Editorial Council of the Journal of Prosthetic Dentistry. Published by Mosby, Inc. All rights reserved.

  17. Nanofluid based on self-nanoencapsulated metal/metal alloys phase change materials with tuneable crystallisation temperature.

    Science.gov (United States)

    Navarrete, Nuria; Gimeno-Furio, Alexandra; Mondragon, Rosa; Hernandez, Leonor; Cabedo, Luis; Cordoncillo, Eloisa; Julia, J Enrique

    2017-12-14

    Nanofluids using nanoencapsulated Phase Change Materials (nePCM) allow increments in both the thermal conductivity and heat capacity of the base fluid. Incremented heat capacity is produced by the melting enthalpy of the nanoparticles core. In this work two important advances in this nanofluid type are proposed and experimentally tested. It is firstly shown that metal and metal alloy nanoparticles can be used as self-encapsulated nePCM using the metal oxide layer that forms naturally in most commercial synthesis processes as encapsulation. In line with this, Sn/SnOx nanoparticles morphology, size and thermal properties were studied by testing the suitability and performance of encapsulation at high temperatures and thermal cycling using a commercial thermal oil (Therminol 66) as the base fluid. Secondly, a mechanism to control the supercooling effect of this nePCM type based on non-eutectic alloys was developed.

  18. Biocompatibility study on Ni-free Ti-based and Zr-based bulk metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Li, T.H. [Institute of Material Science and Engineering, National Central University, Taoyuan, Taiwan (China); Wong, P.C. [Department of Biomedical Engineering, National Yang-Ming University, Taipei, Taiwan (China); Chang, S.F. [Department of Mechanical Engineering, National Central University, Taoyuan, Taiwan (China); Tsai, P.H. [Institute of Material Science and Engineering, National Central University, Taoyuan, Taiwan (China); Jang, J.S.C., E-mail: jscjang@ncu.edu.tw [Institute of Material Science and Engineering, National Central University, Taoyuan, Taiwan (China); Department of Mechanical Engineering, National Central University, Taoyuan, Taiwan (China); Huang, J.C. [Department of Materials and Optoelectronic Science, National Sun Yat-Sen University, Kaohsiung, Taiwan (China)

    2017-06-01

    Safety and reliability are crucial issues for medical instruments and implants. In the past few decays, bulk metallic glasses (BMGs) have drawn attentions due to their superior mechanical properties, good corrosion resistance, antibacterial and good biocompatibility. However, most Zr-based and Ti-based BMGs contain Ni as an important element which is prone to human allergy problem. In this study, the Ni-free Ti-based and Zr-based BMGs, Ti{sub 40}Zr{sub 10}Cu{sub 36}Pd{sub 14}, and Zr{sub 48}Cu{sub 36}Al{sub 8}Ag{sub 8}, were selected for systematical evaluation of their biocompatibility. Several biocompatibility tests, co-cultural with L929 murine fibroblast cell line, were carried out on these two BMGs, as well as the comparison samples of Ti6Al4V and pure Cu. The results in terms of cellular adhesion, cytotoxicity, and metallic ion release affection reveal that the Ti{sub 40}Zr{sub 10}Cu{sub 36}Pd{sub 14} BMG and Ti6Al4V exhibit the optimum biocompatibility; cells still being attached on the petri dish with good adhesion and exhibiting the spindle shape after direct contact test. Furthermore, the Ti{sub 40}Zr{sub 10}Cu{sub 36}Pd{sub 14} BMG showed very low Cu ion release level, in agreement with the MTT results. Based on the current findings, it is believed that Ni-free Ti-based BMG can act as an ideal candidate for medical implant. - Highlight: • Ni-free bulk metallic glass is promising material for medical implants. • Ni-free Ti-based BMG presents similar cellular adhesion as Ti6Al4V. • Ni-free Ti-based BMG shows less cytotoxicity, and metallic ion release than Ti6Al4V.

  19. Economic forces push down selling prices of U.S. refineries

    International Nuclear Information System (INIS)

    Anon.

    1996-01-01

    Recent data on US refinery sales reveal that selling prices have continued to decline in the 1990s. Reasons for this decrease include increased plant investments to meet regulatory requirements, excess refining capacity, increased imports of refined products, and reduced margins. While these expenditures enable a refinery to continue operating, they do not make the refinery more profitable or valuable. Other factors contributing to reduced selling prices of US refineries are: declining local crude production; unstable crude costs; increased energy conservation; growing competition from alternative fuels

  20. Phenomenological modeling of nonlinear holograms based on metallic geometric metasurfaces.

    Science.gov (United States)

    Ye, Weimin; Li, Xin; Liu, Juan; Zhang, Shuang

    2016-10-31

    Benefiting from efficient local phase and amplitude control at the subwavelength scale, metasurfaces offer a new platform for computer generated holography with high spatial resolution. Three-dimensional and high efficient holograms have been realized by metasurfaces constituted by subwavelength meta-atoms with spatially varying geometries or orientations. Metasurfaces have been recently extended to the nonlinear optical regime to generate holographic images in harmonic generation waves. Thus far, there has been no vector field simulation of nonlinear metasurface holograms because of the tremendous computational challenge in numerically calculating the collective nonlinear responses of the large number of different subwavelength meta-atoms in a hologram. Here, we propose a general phenomenological method to model nonlinear metasurface holograms based on the assumption that every meta-atom could be described by a localized nonlinear polarizability tensor. Applied to geometric nonlinear metasurfaces, we numerically model the holographic images formed by the second-harmonic waves of different spins. We show that, in contrast to the metasurface holograms operating in the linear optical regime, the wavelength of incident fundamental light should be slightly detuned from the fundamental resonant wavelength to optimize the efficiency and quality of nonlinear holographic images. The proposed modeling provides a general method to simulate nonlinear optical devices based on metallic metasurfaces.

  1. Novel thiosalicylate-based ionic liquids for heavy metal extractions

    Energy Technology Data Exchange (ETDEWEB)

    Leyma, Raphlin; Platzer, Sonja [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Jirsa, Franz [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Department of Zoology, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg (South Africa); Kandioller, Wolfgang, E-mail: wolfgang.kandioller@univie.ac.at [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria); Krachler, Regina; Keppler, Bernhard K. [Institute of Inorganic Chemistry, Faculty of Chemistry, University of Vienna, Waehringer Str. 42, A-1090 Vienna (Austria)

    2016-08-15

    Highlights: • Six thiosalicylate-based ammonium and phosphonium ionic liquids (ILs) were newly synthesized. • ILs showed good extraction of cadmium, copper, and zinc. • Phosphonium ILs showed better extraction efficiencies than their ammonium counterparts. - Abstract: This study aims to develop novel ammonium and phosphonium ionic liquids (ILs) with thiosalicylate (TS) derivatives as anions and evaluate their extracting efficiencies towards heavy metals in aqueous solutions. Six ILs were synthesized, characterized, and investigated for their extracting efficacies for cadmium, copper, and zinc. Liquid-liquid extractions of Cu, Zn, or Cd with ILs after 1–24 h using model solutions (pH 7; 0.1 M CaCl{sub 2}) were assessed using flame atomic absorption spectroscopy (F-AAS). Phosphonium-based ILs trihexyltetradecylphosphonium 2-(propylthio)benzoate [P{sub 66614}][PTB] and 2-(benzylthio)benzoate [P{sub 66614}][BTB] showed best extraction efficiency for copper and cadmium, respectively and zinc was extracted to a high degree by [P{sub 66614}][BTB] exclusively.

  2. The mineral base and productive capacities of metals and non-metals of Kosovo

    Science.gov (United States)

    Rizaj, M.; Beqiri, E.; McBow, I.; O'Brien, E. Z.; Kongoli, F.

    2008-08-01

    All historical periods of Kosovo—Ilirik, Roman, Medieval, Turkish, and former Yugoslavian—are linked with the intensive development of mining and metallurgy. This activity influenced and still is influencing the overall position of Kosovo as a country. For example, according to a 2006 World Bank report as well as other studies, Kosovo has potential lignite resources (geological reserves) of about 1.5 billion tonnes, which are ranked fifth in the world in importance. Other significant Kosovan mineral resources include lead, zinc, gold, silver, bauxite, and uranium, and rare metals accompanying those minerals, including indium, cadmium, thallium, gallium, and bismuth. These rare metals are of particular importance in developing advanced industrial technologies. Kosovo also has reserves of high-quality non-metals, including magnesite, quartz grit, bentonite, argil, talc, and asbestos. No database exists for these non-metal reserves, and further research and studies are needed.

  3. Surface/structure functionalization of copper-based catalysts by metal-support and/or metal–metal interactions

    Energy Technology Data Exchange (ETDEWEB)

    Konsolakis, Michalis, E-mail: mkonsol@science.tuc.gr [School of Production Engineering and Management, Technical University of Crete, GR-73100 Chania, Crete (Greece); Ioakeimidis, Zisis [Department of Mechanical Engineering, University of Western Macedonia, Bakola and Sialvera, GR-50100 Kozani (Greece)

    2014-11-30

    Highlights: • The surface chemistry of Cu-based catalysts is adjusted by metal-support or metal–metal interactions. • Three series of catalysts, i.e., Cu/REOs, Cu/Ce{sub 1−x}Sm{sub x}O{sub δ} and Cu–Co/CeO{sub 2} were prepared. • The local structure of Cu sites is remarkably affected by support or active phase modification. • Useful insights toward the fundamental understanding of Cu-catalyzed reactions are provided. - Abstract: Cu-based catalysts have recently attracted great attention both in catalysis and electro-catalysis fields due to their excellent catalytic performance and low cost. Given that their performance is determined, to a great extent, by Cu sites local environment, considerable efforts have been devoted on the strategic modifications of the electronic and structural properties of Cu sites. In this regard, the feasibility of tuning the local structure of Cu entities by means of metal-support or metal–metal interactions is investigated. More specifically, the physicochemical properties of Cu entities are modified by employing: (i) different oxides (CeO{sub 2}, La{sub 2}O{sub 3}, Sm{sub 2}O{sub 3}), or (ii) ceria-based mixed oxides (Ce{sub 1−x}Sm{sub x}O{sub δ}) as supporting carriers, and (iii) a second metal (Cobalt) adjacent to Cu (bimetallic Cu–Co/CeO{sub 2}). A characterization study, involving BET, XRD, TPR, and XPS, reveal that significant modifications on structural, redox and electronic properties of Cu sites can be induced by adopting either different oxide carriers or bimetallic complexes. Fundamental insights into the tuning of Cu local environment by metal-support or metal–metal interactions are provided, paving the way for real-life industrial applications.

  4. Metal Phosphides and Phosphates-based Electrodes for Electrochemical Supercapacitors.

    Science.gov (United States)

    Li, Xin; Elshahawy, Abdelnaby M; Guan, Cao; Wang, John

    2017-10-01

    Phosphorus compounds, such as metal phosphides and phosphates have shown excellent performances and great potential in electrochemical energy storage, which are demonstrated by research works published in recent years. Some of these metal phosphides and phosphates and their hybrids compare favorably with transition metal oxides/hydroxides, which have been studied extensively as a class of electrode materials for supercapacitor applications, where they have limitations in terms of electrical and ion conductivity and device stability. To be specific, metal phosphides have both metalloid characteristics and good electric conductivity. For metal phosphates, the open-framework structures with large channels and cavities endow them with good ion conductivity and charge storage capacity. In this review, we present the recent progress on metal phosphides and phosphates, by focusing on their advantages/disadvantages and potential applications as a new class of electrode materials in supercapacitors. The synthesis methods to prepare these metal phosphides/phosphates are looked into, together with the scientific insights involved, as they strongly affect the electrochemical energy storage performance. Particular attentions are paid to those hybrid-type materials, where strong synergistic effects exist. In the summary, the future perspectives and challenges for the metal phosphides, phosphates and hybrid-types are proposed and discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Environmental aspects of the closing of the cooling system of an oil refinery; Aspectos ambiental do fechamento do sistema de refrigeracao de uma refinaria de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Camaz, Fernando Ribeiro [PETROBRAS, Duque de Caxias, RJ (Brazil). Refinaria de Duque de Caxias (REDUC); Amaral, Sergio Pinto [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Lab. de Tecnologia, Gestao de Negocios e Meio Ambiente (LATEC)

    2008-07-01

    The objective of the present paper was the evaluation, analysis and statistical treatment of the behavior of the pollutant load of the Duque de Caxias Refinery. It was analyzed the oil and grease, nitrogen and metals levels in the effluent discharged in the Iguacu River through the Refrigeration Basin , and after to the Guanabara Bay, according to data of the reports of the PROCON-WATER, correspondents to the environmental agency, FEEMA, in the period of the research, from 1998 to 2006. The environmental aspects and impacts of the closing of the cooling system, action of the Term of Commitment of Environmental Adjustment (TCAA), with their multiple variables involved in a socioeconomic and environmental process dynamic. The studies demonstrated great reduction in the consumption of water resources and in the pollutant load discharged. Besides the environmental earnings and the reduction of costs, the refinery provided important economical, social, environmental and image earnings for PETROBRAS, as an environmental responsible company. (author)

  6. Defining a metal-based waste form for IFR pyroprocessing wastes

    International Nuclear Information System (INIS)

    McDeavitt, S.M.; Park, J.Y.; Ackerman, J.P.

    1994-01-01

    Pyrochemical electrorefining to recover actinides from metal nuclear fuel is a key element of the Integral Fast Reactor (IFR) fuel cycle. The process separates the radioactive fission products from the long-lived actinides in a molten LiCl-KCl salt, and it generates a lower waste volume with significantly less long-term toxicity as compared to spent nuclear fuel. The process waste forms include a mineral-based waste form that will contain fission products removed from an electrolyte salt and a metal-based waste form that will contain metallic fission products and the fuel cladding and process materials. Two concepts for the metal-based waste form are being investigated: (1) encapsulating the metal constituents in a Cu-Al alloy and (2) alloying the metal constituents into a uniform stainless steel-based waste form. Results are given from our recent studies of these two concepts

  7. New transparent conductive metal based on polymer composite

    Energy Technology Data Exchange (ETDEWEB)

    Keshavarz Hedayati, Mehdi; Jamali, Mohammad [Nanochemistry and Nanoengineering, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University, Kiel (Germany); Strunkus, Thomas; Zaporochentko, Vladimir; Faupel, Franz [Multicomponent Materials, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University, Kiel (Germany); Elbahri, Mady [Nanochemistry and Nanoengineering, Institute for Materials Science, Faculty of Engineering, Christian-Albrechts-University, Kiel (Germany); Helmholtz-Zentrum Geesthacht GmbH, Institute of Polymer Research, Nanochemistry and Nanoengineering (Germany)

    2011-07-01

    Currently great efforts are made to develop new kind of transparent conductors (TCs) to replace ITO. In this regard different materials and composites have been proposed and studied including conductive polymers, carbon nanotubes (CNTs), metal grids, and random networks of metallic nanowires. But so far none of them could be used as a replacing material, since either they are either fragile and brittle or their electrical conductivity is below the typical ITO. Thin metallic films due to their high electrical conductivity could be one of the best replacing materials for ITO, however their poor transparency makes their application as TCs limited. Here we design and fabricate a new polymeric composite coating which enhances the transparency of the thin metal film up to 100% relative to the initial value while having a high electrical conductivity of typical metals. Therefore our proposed device has a great potential to be used as new transparent conductor.

  8. Gas turbine application in power plants of Mexican refineries; Aplicacion de turbinas de gas en plantas de fuerza de refinerias mexicanas

    Energy Technology Data Exchange (ETDEWEB)

    Alcaraz Calderon, A. M.; Rodriguez Martinez, H.; Garcia Paredes, Job; Morales Guillen, Magdalena; Manzanares Papayanapolous, Emilio [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: malcaraz@iie.org.mx; jhrm@iie.org.mx; jgarcia@iie.org.mx; mmmg@iie.org.mx; emp@iie.org.mx

    2010-11-15

    This article presents an overview of the application to have the gas turbine power generation systems, electric and steam for Mexican refineries. First there is a general description of the gas turbines and heat recovery (system components CHP) and CHP schemes are based on gas turbines capable of use in Mexican refineries. Subsequently referred to the characteristics of energy consumption (steam and electricity) from Mexican refineries and performs a technical analysis of CHP schemes based on gas turbines from the point of view of rates Q/W, power efficiencies and combined concluded that by their nature are very useful for refinery and gives some recommendations for improved implementation. [Spanish] En este articulo se presenta una vision general de la aplicacion que tienen las turbinas de gas en sistemas de generacion de energia electrica y vapor para refinerias mexicanas. Primeramente se da una descripcion general de las turbinas de gas y recuperadores de calor (componentes principales del sistema de cogeneracion) y se muestran los esquemas de cogeneracion basados en turbinas de gas susceptibles de utilizar en refinerias mexicanas. Posteriormente se mencionan las caracteristicas de consumos energeticos (vapor y energia electrica) de las refinerias mexicanas y se realiza un analisis tecnico de los esquemas de cogeneracion basado en turbinas de gas desde el punto de vista de tasas Q/W, eficiencias electricas y combinadas, concluyendose que por sus caracteristicas son muy utiles para refinerias y se dan algunas recomendaciones para su mejor aplicacion.

  9. A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

    OpenAIRE

    Yang, Ruihong; ZHU, Jianzhong; Li, Yingliu; Zhang, Hui

    2016-01-01

    Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to b...

  10. Ni-BaTiO3-Based Base-Metal Electrode (BME) Ceramic Capacitors for Space Applications

    Science.gov (United States)

    Liu, Donhang; Fetter, Lula; Meinhold, Bruce

    2015-01-01

    A multi-layer ceramic capacitor (MLCC) is a high-temperature (1350C typical) co-fired ceramic monolithic that is composed of many layers of alternately stacked oxide-based dielectric and internal metal electrodes. To make the dielectric layers insulating and the metal electrode layers conducting, only highly oxidation-resistant precious metals, such as platinum, palladium, and silver, can be used for the co-firing of insulating MLCCs in a regular air atmosphere. MLCCs made with precious metals as internal electrodes and terminations are called precious-metal electrode (PME) capacitors. Currently, all military and space-level applications only address the use of PME capacitors.

  11. Applications of Open Source GMAW-Based Metal 3-D Printing

    OpenAIRE

    Yuenyong Nilsiam; Paul G. Sanders; Joshua M. Pearce

    2018-01-01

    The metal 3-D printing market is currently dominated by high-end applications, which make it inaccessible for small and medium enterprises, fab labs, and individual makers who are interested in the ability to prototype and additively manufacture final products in metal. Recent progress led to low-cost open-source metal 3-D printers using a gas metal arc welding (GMAW)-based print head. This reduced the cost of metal 3-D printers into the range of desktop prosumer polymer 3-D printers. Consequ...

  12. Friction and wear of some ferrous-base metallic glasses

    Science.gov (United States)

    Miyoshi, K.; Buckley, D. H.

    1984-01-01

    Sliding friction experiments, X-ray photoelectron spectroscopy (XPS) analysis, and electron microscopy and diffraction studies were conducted with ferrous base metallic glasses (amorphous alloys) in contact with aluminium oxide at temperatures to 750 C in a vacuum. Sliding friction experiments were also conducted in argon and air atmospheres. The results of the investigation indicate that the coefficient of friction increases with increasing temperature to 350 C in vacuum. The increase in friction is due to an increase in adhesion resulting from surface segregation of boric oxide and/or silicon oxide to the surface of the foil. Above 500 C the coefficient of friction decreased rapidly. The decrease correlates with the segregation of boron nitride to the surface. Contaminants can come from the bulk of the material to the surface upon heating and impart boric oxide and/or silicon oxide at 350 C and boron nitride above 500 C. The segregation of contaminants is responsible for the friction behavior. The amorphous alloys have superior wear resistance to crystalline 304 stainless steel. The relative concentrations of the various constituents at the surfaces of the amorphous alloys are very different from the nominal bulk compositions.

  13. Knowledge Based Cloud FE Simulation of Sheet Metal Forming Processes.

    Science.gov (United States)

    Zhou, Du; Yuan, Xi; Gao, Haoxiang; Wang, Ailing; Liu, Jun; El Fakir, Omer; Politis, Denis J; Wang, Liliang; Lin, Jianguo

    2016-12-13

    The use of Finite Element (FE) simulation software to adequately predict the outcome of sheet metal forming processes is crucial to enhancing the efficiency and lowering the development time of such processes, whilst reducing costs involved in trial-and-error prototyping. Recent focus on the substitution of steel components with aluminum alloy alternatives in the automotive and aerospace sectors has increased the need to simulate the forming behavior of such alloys for ever more complex component geometries. However these alloys, and in particular their high strength variants, exhibit limited formability at room temperature, and high temperature manufacturing technologies have been developed to form them. Consequently, advanced constitutive models are required to reflect the associated temperature and strain rate effects. Simulating such behavior is computationally very expensive using conventional FE simulation techniques. This paper presents a novel Knowledge Based Cloud FE (KBC-FE) simulation technique that combines advanced material and friction models with conventional FE simulations in an efficient manner thus enhancing the capability of commercial simulation software packages. The application of these methods is demonstrated through two example case studies, namely: the prediction of a material's forming limit under hot stamping conditions, and the tool life prediction under multi-cycle loading conditions.

  14. Milling of Nanoparticles Reinforced Al-Based Metal Matrix Composites

    Directory of Open Access Journals (Sweden)

    Alokesh Pramanik

    2018-03-01

    Full Text Available This study investigated the face milling of nanoparticles reinforced Al-based metal matrix composites (nano-MMCs using a single insert milling tool. The effects of feed and speed on machined surfaces in terms of surface roughness, surface profile, surface appearance, chip surface, chip ratio, machining forces, and force signals were analyzed. It was found that surface roughness of machined surfaces increased with the increase of feed up to the speed of 60 mm/min. However, at the higher speed (100–140 mm/min, the variation of surface roughness was minor with the increase of feed. The machined surfaces contained the marks of cutting tools, lobes of material flow in layers, pits and craters. The chip ratio increased with the increase of feed at all speeds. The top chip surfaces were full of wrinkles in all cases, though the bottom surfaces carried the evidence of friction, adhesion, and deformed material layers. The effect of feed on machining forces was evident at all speeds. The machining speed was found not to affect machining forces noticeably at a lower feed, but those decreased with the increase of speed for the high feed scenario.

  15. Porous silicon based anode material formed using metal reduction

    Science.gov (United States)

    Anguchamy, Yogesh Kumar; Masarapu, Charan; Deng, Haixia; Han, Yongbong; Venkatachalam, Subramanian; Kumar, Sujeet; Lopez, Herman A.

    2015-09-22

    A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m.sup.2/g to about 200 m.sup.2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm.sup.2 to about 3.5 mg/cm.sup.2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.

  16. Laser assisted anticancer activity of benzimidazole based metal organic nanoparticles.

    Science.gov (United States)

    Praveen, P A; Ramesh Babu, R; Balaji, P; Murugadas, A; Akbarsha, M A

    2018-03-01

    Recent studies showed that the photothermal therapy can be effectively used for the targeted cancerous cells destruction. Hence, in the present study, benzimidazole based metal organic complex nanoparticles, dichloro cobalt(II) bis-benzimidazole (Co-BMZ) and dichloro copper(II) bis-benzimidazole (Cu-BMZ), were synthesized by reprecipitation method and their anti-cancer activity by means of photothermal effect has been studied. Transmission electron microscopy analysis shows that the particle size of Cu-BMZ is ∼100 nm and Co-BMZ is in the range between 100 and 400 nm. Zeta potential analysis ensures the stability of the synthesized nanoparticles. It is found that the nonlinear absorption of the nanoparticles increases with increase in laser power intensity. Phototoxicity of human lung cancer (A549) and the normal mouse embryonic fibroblast (NIH-3T3) cells was studied using a 650 nm laser. Even though both the cell lines were affected by laser irradiation, A549 cells show higher cell destruction and lower IC 50 values than the normal cells. Docking studies were used to analyse the interaction site and the results showed that the Cu-BMZ molecules have higher dock score than the Co-BMZ molecules. The obtained results indicate that Cu-BMZ samples have lesser particle size, higher nonlinear absorption and higher interaction energy than the Co-BMZ samples. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. A Fundamental Approach to Developing Aluminium based Bulk Amorphous Alloys based on Stable Liquid Metal Structures and Electronic Equilibrium - 154041

    Science.gov (United States)

    2017-03-28

    AFRL-AFOSR-JP-TR-2017-0027 A Fundamental Approach to Developing Aluminium -based Bulk Amorphous Alloys based on Stable Liquid-Metal Structures and...to 16 Dec 2016 4.  TITLE AND SUBTITLE A Fundamental Approach to Developing Aluminium -based Bulk Amorphous Alloys based on Stable Liquid-Metal...Air Force Research Laboratory for accurately predicting compositions of new amorphous alloys specifically based on aluminium with properties superior

  18. Optical hydrogen sensors based on metal-hydrides

    Science.gov (United States)

    Slaman, M.; Westerwaal, R.; Schreuders, H.; Dam, B.

    2012-06-01

    For many hydrogen related applications it is preferred to use optical hydrogen sensors above electrical systems. Optical sensors reduce the risk of ignition by spark formation and are less sensitive to electrical interference. Currently palladium and palladium alloys are used for most hydrogen sensors since they are well known for their hydrogen dissociation and absorption properties at relatively low temperatures. The disadvantages of palladium in sensors are the low optical response upon hydrogen loading, the cross sensitivity for oxygen and carbon, the limited detection range and the formation of micro-cracks after some hydrogen absorption/desorption cycles. In contrast to Pd, we find that the use of magnesium or rear earth bases metal-hydrides in optical hydrogen sensors allow tuning of the detection levels over a broad pressure range, while maintaining a high optical response. We demonstrate a stable detection layer for detecting hydrogen below 10% of the lower explosion limit in an oxygen rich environment. This detection layer is deposited at the bare end of a glass fiber as a micro-mirror and is covered with a thin layer of palladium. The palladium layer promotes the hydrogen uptake at room temperature and acts as a hydrogen selective membrane. To protect the sensor for a long time in air a final layer of a hydrophobic fluorine based coating is applied. Such a sensor can be used for example as safety detector in automotive applications. We find that this type of fiber optic hydrogen sensor is also suitable for hydrogen detection in liquids. As example we demonstrate a sensor for detecting a broad range of concentrations in transformer oil. Such a sensor can signal a warning when sparks inside a high voltage power transformer decompose the transformer oil over a long period.

  19. Bioremediation of wastewater from edible oil refinery factory using oleaginous microalga Desmodesmus sp. S1.

    Science.gov (United States)

    Mar, Cho Cho; Fan, Yong; Li, Fu-Li; Hu, Guang-Rong

    2016-12-01

    Edible oil industry produced massive wastewater, which requires extensive treatment to remove pungent smell, high phosphate, carbon oxygen demand (COD), and metal ions prior to discharge. Traditional anaerobic and aerobic digestion could mainly reduce COD of the wastewater from oil refinery factories (WEORF). In this study, a robust oleaginous microalga Desmodesmus sp. S1 was adapted to grow in WEORF. The biomass and lipid content of Desmodesmus sp. S1 cultivated in the WEORF supplemented with sodium nitrate were 5.62 g·L(-1) and 14.49%, whereas those in the WEORF without adding nitrate were 2.98 g·L(-1) and 21.95%. More than 82% of the COD and 53% of total phosphorous were removed by Desmodesmus sp. S1. In addition, metal ions, including ferric, aluminum, manganese and zinc were also diminished significantly in the WEORF after microalgal growth, and pungent smell vanished as well. In comparison with the cells grown in BG-11 medium, the cilia-like bulges and wrinkles on the cell surface of Desmodesmus sp. S1 grown in WEORF became out of order, and more polyunsaturated fatty acids were detected due to stress derived from the wastewater. The study suggests that growing microalgae in WEORF can be applied for the dual roles of nutrient removal and biofuel feedstock production.

  20. Plasmonic reflectors and high-Q nano-cavities based on coupled metal-insulator-metal waveguides

    Directory of Open Access Journals (Sweden)

    Jing Chen

    2012-03-01

    Full Text Available Based on the contra-directional coupling, a composite structure consisting of two coupled metal-insulator-metal (MIM waveguides is proposed to act as an attractive plasmonic reflector. By introducing a defect into one of the MIM waveguides, we show that such a composite structure can be operated as a plasmonic nanocavity with a high quality factor. Both symmetric and anti-symmetric cavity modes are supported in the plasmonic cavity, and their resonance frequencies can be tuned by controlling the defect width. The present structures could have a significant impact for potential applications such as surface plasmon mirrors, filters and solid-state cavity quantum electrodynamics.

  1. Nano-structured noble metal catalysts based on hexametallate architecture for the reforming of hydrocarbon fuels

    Science.gov (United States)

    Gardner, Todd H.

    2015-09-15

    Nano-structured noble metal catalysts based on hexametallate lattices, of a spinel block type, and which are resistant to carbon deposition and metal sulfide formation are provided. The catalysts are designed for the reforming of hydrocarbon fuels to synthesis gas. The hexametallate lattices are doped with noble metals (Au, Pt, Rh, Ru) which are atomically dispersed as isolated sites throughout the lattice and take the place of hexametallate metal ions such as Cr, Ga, In, and/or Nb. Mirror cations in the crystal lattice are selected from alkali metals, alkaline earth metals, and the lanthanide metals, so as to reduce the acidity of the catalyst crystal lattice and enhance the desorption of carbon deposit forming moieties such as aromatics. The catalysts can be used at temperatures as high as 1000.degree. C. and pressures up to 30 atmospheres. A method for producing these catalysts and applications of their use also is provided.

  2. High pressure and microwave based synthesis of transition metal pnictides

    Energy Technology Data Exchange (ETDEWEB)

    Pobel, Roman Rupert

    2016-04-11

    The goal of this thesis was to explore the possibilities of synthetic methods that are not very common in current transition metal pnictide research. The substitution of the Ca-site in CaFe{sub 2}As{sub 2} with rare earth elements such as Pr the has been reported to induce superconductivity. However, some inconsistencies in the data suggested a non-intrinsic origin of the observed diamagnetic signal. Furthermore a solubility limit of 13% was found when prepared in an electrical furnace thus leaving a huge part of the physical phase diagram inaccessible. A high pressure/high temperature synthesis was developed to allow access to the whole doping range and an in-depth characterization of this compound was carried out. During the experiments concerning the high pressure synthesis of Ca{sub 1-x}Pr{sub x}Fe{sub 2}As{sub 2} the new ternary iron arsenide CaFe{sub 5}As{sub 3} was identified and classified as a member of the Ca{sub n(n+1)/2}(Fe{sub 1-x}M{sub x}){sub (2+3n)}M'{sub n(n-1)/2}As{sub (n+1)(n+2)/2} (n = 1-3; M =Nb, Pd, Pt; M' = □, Pd, Pt) family. The complete solid solution Ca{sub 1-x}Pr{sub x}Fe{sub 5}As{sub 3} (O ≤ x ≤ 1) was prepared and physically characterized. Furthermore, several useful techniques were developed to aid in future high pressure based investigations of transition metal pnictides. The second part of this thesis concerns a completely different, but equally promising synthetic approach. Microwave based synthesis is a well-established technique in many solution based fields, such as organic, medicinal or nano chemistry. For solid state and materials research several parameters and particularities have to be considered. But when successful, it allows for the reduction of reaction time by several orders of magnitude. It has very rarely been applied in the preparation of pnictides and on1y once in the context of pnictide superconductor research. The possibilities of this method were explored and employed in the preparation of several

  3. High temperature degradation in power plants and refineries

    Directory of Open Access Journals (Sweden)

    Furtado Heloisa Cunha

    2004-01-01

    Full Text Available Thermal power plants and refineries around the world share many of the same problems, namely aging equipment, high costs of replacement, and the need to produce more efficiently while being increasingly concerned with issues of safety and reliability. For equipment operating at high temperature, there are many different mechanisms of degradation, some of which interact, and the rate of accumulation of damage is not simple to predict. The paper discusses the mechanisms of degradation at high temperature and methods of assessment of such damage and of the remaining safe life for operation.

  4. Capital vs. service contract at Conoco Humber Refinery

    International Nuclear Information System (INIS)

    Threlfall, Peter; Sperring, Simon

    1999-01-01

    The value of outsourcing for water treatment is illustrated through experience at the Conoco Humber refinery. A point was reached where the quality of water at the plant was so poor that demineralized water was brought to the site by tanker. The paper describes how and why it was decided to design, build, operate and maintain an outsourced system. It points out how the newer technologies can be environmentally friendly and, at the same time, reduce operating and maintenance costs, optimise manpower and cut management costs. (UK)

  5. Microbial enhanced separation of oil from a petroleum refinery sludge.

    Science.gov (United States)

    Joseph, P J; Joseph, Ammini

    2009-01-15

    Petroleum refineries around the world have adopted different technological options to manage the solid wastes generated during the refining process and stocking of crude oil. These include physical, chemical and biological treatment methods. In this investigation bacterial mediated oil separation is effected. Two strains of Bacillus were isolated from petroleum-contaminated soils, and inoculated into slurry of sludge, and sludge-sand combinations. The bacteria could effect the separation of oil so as to form a floating scum within 48h with an efficiency of 97% at < or =5% level of sludge in the sludge-sand mixture. The activity was traced to the production of biosurfactants by bacteria.

  6. Bivalent metal-based MIL-53 analogues: Synthesis, properties and application

    International Nuclear Information System (INIS)

    Liu, Yongxin; Liu, Dan; Wang, Cheng

    2015-01-01

    Trivalent metal-based MIL-53 (Al 3+ , Cr 3+ , Fe 3+ , In 3+ ) compounds are interesting metal–organic frameworks (MOFs) with breathing effect and are promising gas sorption materials. Replacing bridging μ 2 -OH group by neutral ligands such as pyridine N-oxide and its derivatives (PNOs), the trivalent metal-based MIL-53 analogous structures could be extended to bivalent metal systems. The introduction of PNOs and bivalent metal elements endows the frameworks with new structural features and physical and chemical properties. This minireview summarizes the recent development of bivalent metal-based MIL-53 analogues (Mn 2+ , Co 2+ , Ni 2+ ), typically, focusing on the synthetic strategies and potential applications based on our own works and literatures. We present the synthetic strategy to achieve structures evolution from single-ligand-walled to double-ligand-walled channel. Properties and application of these new materials in a wide range of potential areas are discussed including thermal stability, gas adsorption, magnetism and liquid-phase separation. Promising directions of this research field are also highlighted. - Graphical abstract: The recent development of bivalent metal-based MIL-53 analogues (Mn 2+ , Co 2+ , Ni 2+ ) on their synthetic strategies, properties and potential applications was reviewed. - Highlights: • Structure features of bivalent metal-based MIL-53 analogues are illustrated. • Important properties and application are presented. • Host–guest interactions are main impetus for liquid-phase separation. • Promising directions of bivalent metal-based MIL-53 analogues are highlighted

  7. 40 CFR 80.1280 - How are refinery benzene baselines calculated?

    Science.gov (United States)

    2010-07-01

    ... benzene). i = Individual batch of gasoline produced at the refinery from January 1, 2004 through December 31, 2005. n = Total number of batches of gasoline produced at the refinery from January 1, 2004... PROGRAMS (CONTINUED) REGULATION OF FUELS AND FUEL ADDITIVES Gasoline Benzene Averaging, Banking and Trading...

  8. Sounding pollution and the refinery environmental risks; A poluicao sonora e os riscos ambientais das refinarias

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This chapter gives a general overview on the effects of the sound pollution, the principal pollutants emitted by the oil refineries, control actions for the sound waves emissions, the minimization actions, the risk concepts and evaluation, the risk perception and the accidents in refineries.

  9. Environmental nickel exposure from oil refinery emissions: a case study in Ecuador.

    Science.gov (United States)

    Harari, Raúl; Harari, Florencia; Forastiere, Francesco

    2016-01-01

    Nickel is a strong skin and respiratory sensitizer and a recognized carcinogen. Oil refineries are important sources of atmospheric emissions of toxic pollutants, including nickel. Populations residing close to oil refineries are at potential risk. The aim of this study was to evaluate the exposure to nickel in a population living close to the largest oil refinery in Ecuador, located in the city of Esmeraldas. We recruited 47 workers from the oil refinery as well as 195 students from 4 different schools close to the plant and 94 students from another school 25 km far from the industry. Urinary nickel concentrations were used to assess the exposure to nickel. Students from the school next to the oil refinery showed the highest urinary nickel concentrations while workers from the refinery showed the lowest concentrations. Median nickel concentrations were > 2µg/L in all study groups. The populations living close to the oil refineries are potentially exposed to nickel from atmospheric emissions. Further studies investigating nickel-related health effects in the population residing close to the refinery of Esmeralda are needed.

  10. 76 FR 64943 - Proposed Cercla Administrative Cost Recovery Settlement; ACM Smelter and Refinery Site, Located...

    Science.gov (United States)

    2011-10-19

    ... Settlement; ACM Smelter and Refinery Site, Located in Cascade County, MT AGENCY: Environmental Protection... projected future response costs concerning the ACM Smelter and Refinery NPL Site (Site), Operable Unit 1..., Helena, MT 59626. Mr. Sturn can be reached at (406) 457-5027. Comments should reference the ACM Smelter...

  11. 40 CFR 73.90 - Allowance allocations for small diesel refineries.

    Science.gov (United States)

    2010-07-01

    ... refineries. 73.90 Section 73.90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) SULFUR DIOXIDE ALLOWANCE SYSTEM Small Diesel Refineries § 73.90 Allowance allocations... application for certification, submitted to the address in § 73.13 of this chapter, shall include the...

  12. 76 FR 42052 - National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries

    Science.gov (United States)

    2011-07-18

    ...-AO55 National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries AGENCY... the National Emission Standards for Hazardous Air Pollutants From Petroleum Refineries. EPA is now... signed a final rule amending the National Emission Standards for Hazardous Air Pollutants From Petroleum...

  13. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    Energy Technology Data Exchange (ETDEWEB)

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  14. A plasmonic modulator based on metal-insulator-metal waveguide with barium titanate core

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Lavrinenko, Andrei

    2013-01-01

    We design a plasmonic modulator which can be utilized as a compact active device in photonic integrated circuits. The active material, barium titanate (BaTiO3), is sandwiched between metal plates and changes its refractive index under applied voltage. Some degree of switching of ferroelectric...

  15. Phase transformations and thermodynamics of aluminum-based metallic glasses

    Science.gov (United States)

    Gao, Changhua (Michael)

    This thesis examines the thermodynamics and associated kinetics and phase transformations of the glass forming Al-Ni-Gd and Al-Fe-Gd systems. In order to fully understand the unique glass forming ability (GFA) of Al-based metallic glasses, the ternary Al-Fe-Gd and Al-Ni-Gd systems in their Al-rich corners were examined experimentally to assist in a thermodynamic assessment. The solid-state phase equilibria are determined using XRD and TEM-EDS techniques. While this work basically confirms the solid-state equilibria in Al-Fe-Gd reported previously, the ternary phase in Al-Ni-Gd system has been identified to be Al15Ni3Gd2 rather than Al16Ni 3Gd reported in the literature. DTA analysis of 24 alloys in the Al-Fe-Gd system and 42 alloys in the Al-Ni-Gd system have yielded critical temperatures pertaining to the solid-liquid transition. Based on these data and information from the literature, a self-consistent thermodynamic database for these systems has been developed using the CALPHAD technique. Parameters describing the Gibbs free energy for various phases of the Al-Gd, Al-Fe-Gd and Al-Ni-Gd systems are manually optimized in this study. Once constructed, the database is used to calculate driving forces for nucleation of crystalline phases which can qualitatively explain the phase formation sequence during crystallization at low temperatures. It was also confirmed that alloy compositions with the lowest Gibbs free energy difference between the equilibrium state and undercooled liquid state exhibit better GFA than other chemistries. Based on 250°C isothermal devitrification phase transformations of 17 Al-Ni-Gd alloys, a phase formation sequence map is constructed. Fcc-Al nanocrystals are formed first in most of the alloys studied, but eutectic crystallization of a metastable phase and fcc-Al is also observed. Addition of Al or Ni promotes fcc-Al phase formation, while increasing Gd suppresses it. The continuous heating DSC scans revealed that crystallization in Al

  16. Conservation and reuse of water in Brazilian petroleum refineries; Conservacao e reuso de agua em refinarias de petroleo no Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Pombo, Felipe Ramalho; Magrini, Alessandra; Szklo, Alexandre Salem [Universidade Federal do Rio de Janeiro (PPE/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Programa de Planejamento Energetico], Emails: frpombo@ppe.ufrj.br, ale@ppe.ufrj.br, szklo@ppe.ufrj.br

    2010-07-01

    This paper views to present the main technologies for effluent treatment of petroleum refineries having as target the reuse. An analysis of international and Brazilian experiences of water reuse in petroleum refineries is performed viewing to support the proposition of recommendations for Brazilian refineries.

  17. A Model Based Approach to Increase the Part Accuracy in Robot Based Incremental Sheet Metal Forming

    International Nuclear Information System (INIS)

    Meier, Horst; Laurischkat, Roman; Zhu Junhong

    2011-01-01

    One main influence on the dimensional accuracy in robot based incremental sheet metal forming results from the compliance of the involved robot structures. Compared to conventional machine tools the low stiffness of the robot's kinematic results in a significant deviation of the planned tool path and therefore in a shape of insufficient quality. To predict and compensate these deviations offline, a model based approach, consisting of a finite element approach, to simulate the sheet forming, and a multi body system, modeling the compliant robot structure, has been developed. This paper describes the implementation and experimental verification of the multi body system model and its included compensation method.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  19. Enhanced photoelectrochemical activity in all-oxide heterojunction devices based on correlated "metallic" oxides.

    Science.gov (United States)

    Apgar, Brent A; Lee, Sungki; Schroeder, Lauren E; Martin, Lane W

    2013-11-20

    n-n Schottky, n-n ohmic, and p-n Schottky heterojunctions based on TiO2 /correlated "metallic" oxide couples exhibit strong solar-light absorption driven by the unique electronic structure of the "metallic" oxides. Photovoltaic and photocatalytic responses are driven by hot electron injection from the "metallic" oxide into the TiO2 , enabling new modalities of operation for energy systems. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Solution chemistry and separation of metal ions in leached solution

    International Nuclear Information System (INIS)

    Shibata, J.

    1991-01-01

    The method to presume a dissolved state of metal ions in an aqueous solution and the technology to separate and concentrate metal ions in a leached solution are described in this paper. It is very important for the separation of metal ions to know the dissolved state of metal ions. If we know the composition of an aqueous solution and the stability constants of metal-ligand complexes, we can calculate and estimate the concentration of each species in the solution. Then, we can decide the policy to separate and concentrate metal ions. There are several methods for separation and purification; hydroxide precipitation method, sulfide precipitation method, solvent extraction method and ion exchange resin method. Solvent extraction has been used in purification processes of copper refinery, uranium refinery, platinum metal refinery and rare earth metal refinery. Fundamental process of solvent extraction, a kind of commercial extractants, a way of determining a suitable extractant and an equipment are discussed. Finally, it will be emphasized how the separation of rare earths is improved in solvent extraction. (author) 21 figs., 8 tabs., 8 refs

  1. Oil-refinery and automotive emissions of rare earth elements

    International Nuclear Information System (INIS)

    Kitto, M.E.; Gordon, G.E.; Anderson, D.L.; Olmez, I.

    1991-01-01

    The concentration pattern of rare-earth elements (REEs) in emissions from oil refineries and newer-model automobiles shows a distortion from the crustal abundance pattern. The REEs arise from the zeolite cracking catalysts used in petroleum refining and emission-control substrates used in automobile catalytic converters, respectively. Ten petroleum cracking catalysts from four countries and 12 catalytic converters from five automobile manufacturers were characterized for their REE content. The cracking catalysts are highly enriched in light REEs, whereas the automobile catalysts are enriched primarily in Ce. Incorporation of zeolite catalysts into refined oil provides new atmospheric elemental signatures for tracing emissions from refineries and oil-fired power plants on a regional scale. Though both have enhanced La/REE ratios, emissions from these two sources can be distinguished by their La/V ratios. Although REE demand by the petroleum industry has dropped considerably in recent years, automobile catalytic converters containing REEs are expected to increase dramatically as more stringent emission regulations are adopted in Europe, Japan and the US

  2. Effect of adoption of gas turbine in oil refinery

    Energy Technology Data Exchange (ETDEWEB)

    Tamai, Hiroto

    1988-08-01

    With progress in energy saving, and increase in automation in facilities, the dependence on electric power increases relative steam power. Further in order to reduce the production cost, the adoption of gas turbine combined cycle system, mainly aimed at power generation, is considered to be most suitable. This adoption, accompanied with the utilization of refinery offgas, dresults in a reduction in unit power generation cost, by increasing the ratio of domestic power generation. The gas turbine using deethanizing tower offgas as main fuel and butane as auxillary fuel, the combined cycle system, where steam produced from the turbine waste heat boiler drives the existing back pressure turbine, was constituted. The generator is 118 kVA in capacity. Against the maximum power demand being 16,500 kWh in the oil refinery, the obtainment of 11,000 kWh by the gas turbine and 2,500 kWh by the back pressure turbine was assured, with a considerable lowering in power to be purchased. (7 figs, 1 tab, 1 ref)

  3. Biodegradation of oil refinery wastes under OPA and CERCLA

    International Nuclear Information System (INIS)

    Banipal, B.S.; Myers, J.M.; Fisher, C.W.

    1995-01-01

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the full-scale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach in the evaluation of using biodegradation as a treatment method to achieve site-specific clean-up including pilot scale biodegradation operations is included in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that the site-specific cleanup criteria can be attained within a proposed project time. Also presented are degradation rates and half-lives for PAHs for which cleanup criteria has been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other investigators (API 1987)

  4. The regulation of uranium refineries and conversion facilities in Canada

    International Nuclear Information System (INIS)

    Didyk, J.P.

    1986-04-01

    The nuclear regulatory process as it applies to uranium refineries and conversion facilities in Canada is reviewed. In the early 1980s, Eldorado Resources Limited proposed to construct and operate new facilities for refining yellowcake and for the production of uranium hexafluoride (UF 6 ). These projects were subject to regulation by the Atomic Energy Control Board (AECB). A description of the AECB's comprehensive licensing process covering all stages of siting, construction, operation and eventual decommissioning of nuclear facilities is traced as it was applied to the Eldorado projects. The AECB's concern with occupational health and safety, with public health and safety and with the protection of the environment in so far as it affects public health and safety is emphasized. Some regulatory difficulties encountered during the project's development which led to opening up the licensing process to public input and closer coordination of regulatory activities with other provincial and federal regulatory agencies are described. The Board's regulatory operational compliance program for uranium refineries and conversion facilities is summarized

  5. Improving secondary clarifier performance at the Oakville Oil Refinery

    International Nuclear Information System (INIS)

    Edwards, S.M.; Bagley, D.M.

    2002-01-01

    The purpose of this study was threefold: to investigate the relationship between settleability and the physical properties of activated sludge, to correlate settleability and key operational parameters such as chemical oxygen demand (COD) concentration at the aeration basin inlet and to determine potential operational improvements to the Oakville Oil Refinery Wastewater Treatment Plant. Nine separate sets of stirred sludge-settling tests were conducted over a six-month period to measure settleability. The stirred sludge volume index (SSVI), the zone settling constants, and the Zheng-Bagley compression constants were determined. State point analyses were conducted to determine the maximum solids flux of the clarifiers. The concentrations of Al, Mn, Mg, Fe, Ca, Na, and K were determined to identify potential correlations to settling characteristics. Extracellular polymeric substances were extracted from the sludge and analyzed for the same reason. The performance of the clarifiers was highly variable during the period examined. As the refinery process flows and effluent streams changed, influent COD increased, from an average of 180mg/L to 600mg/L. Concurrently the settleability of the sludge decreased from excellent (SSVI = 68mL/g) to very poor (150mL/g), perhaps as the result of under aeration. State point analyses indicated that the clarifiers are under-sized for process upsets of this magnitude. (author)

  6. Improving secondary clarifier performance at the Oakville Oil Refinery

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, S.M.; Bagley, D.M. [Univ. of Toronto, Dept. of Civil Engineering, Toronto, Ontario (Canada)

    2002-06-15

    The purpose of this study was threefold: to investigate the relationship between settleability and the physical properties of activated sludge, to correlate settleability and key operational parameters such as chemical oxygen demand (COD) concentration at the aeration basin inlet and to determine potential operational improvements to the Oakville Oil Refinery Wastewater Treatment Plant. Nine separate sets of stirred sludge-settling tests were conducted over a six-month period to measure settleability. The stirred sludge volume index (SSVI), the zone settling constants, and the Zheng-Bagley compression constants were determined. State point analyses were conducted to determine the maximum solids flux of the clarifiers. The concentrations of Al, Mn, Mg, Fe, Ca, Na, and K were determined to identify potential correlations to settling characteristics. Extracellular polymeric substances were extracted from the sludge and analyzed for the same reason. The performance of the clarifiers was highly variable during the period examined. As the refinery process flows and effluent streams changed, influent COD increased, from an average of 180mg/L to 600mg/L. Concurrently the settleability of the sludge decreased from excellent (SSVI = 68mL/g) to very poor (150mL/g), perhaps as the result of under aeration. State point analyses indicated that the clarifiers are under-sized for process upsets of this magnitude. (author)

  7. Electrochemical removal of phenol from oil refinery wastewater.

    Science.gov (United States)

    Abdelwahab, O; Amin, N K; El-Ashtoukhy, E-S Z

    2009-04-30

    This study explores the possibility of using electrocoagulation to remove phenol from oil refinery waste effluent using a cell with horizontally oriented aluminum cathode and a horizontal aluminum screen anode. The removal of phenol was investigated in terms of various parameters namely: pH, operating time, current density, initial phenol concentration and addition of NaCl. Removal of phenol during electrocoagulation was due to combined effect of sweep coagulation and adsorption. The results showed that, at high current density and solution pH 7, remarkable removal of 97% of phenol after 2h can be achieved. The rate of electrocoagulation was observed to increase as the phenol concentration decreases; the maximum removal rate was attained at 30 mg L(-1) phenol concentration. For a given current density using an array of closely packed Al screens as anode was found to be more effective than single screen anode, the percentage phenol removal was found to increase with increasing the number of screens per array. After 2h of electrocoagulation, 94.5% of initial phenol concentration was removed from the petroleum refinery wastewater. Energy consumption and aluminum Electrode consumption were calculated per gram of phenol removed. The present study shows that, electrocoagulation of phenol using aluminum electrodes is a promising process.

  8. [Occupational accidents in an oil refinery in Brazil].

    Science.gov (United States)

    Souza, Carlos Augusto Vaz de; Freitas, Carlos Machado de

    2002-10-01

    Work in oil refineries involves the risk of minor to major accidents. National data show the impact of accidents on this industry. A study was carried out to describe accident profile and evaluate the adequacy of accident reporting system. Data on all accidents reported in an oil refinery in the state of Rio de Janeiro for the year 1997 were organized and analyzed. The study population consisted of 153 injury cases, 83 hired and 69 contracted workers. The variables were: type of accident, operation mode and position of the worker injured. Among hired workers, minor accidents predominated (54.2%) and they occurred during regular operation activities (62.9%). Among contracted workers, there also predominated minor accidents (75.5%) in a higher percentage, but they occurred mainly during maintenance activities (96.8%). The study results showed that there is a predominance of accidents in lower hierarchy workers, and these accidents occur mainly during maintenance activities. There is a need to improve the company's accident reporting system and accident investigation procedures.

  9. Biodegradation of oil refinery wastes under OPA and CERCLA

    Energy Technology Data Exchange (ETDEWEB)

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M. [Ecology and Environment, Inc., Dallas, TX (United States)] [and others

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

  10. Plasmonic nano-sensor based on metal-dielectric-metal waveguide with the octagonal cavity ring

    Science.gov (United States)

    Ghorbani, Saeed; Dashti, Mohammad Ali; Jabbari, Masoud

    2018-06-01

    In this paper, a refractive index plasmonic sensor including a waveguide of metal–insulator–metal with side coupled octagonal cavity ring has been suggested. The sensory and transmission feature of the structure has been analyzed numerically using Finite Element Method numerical solution. The effect of coupling distance and changing the width of metal–insulator–metal waveguide and refractive index of the dielectric located inside octagonal cavity—which are the effective factors in determining the sensory feature—have been examined so completely that the results of the numerical simulation show a linear relation between the resonance wavelength and refractive index of the liquid/gas dielectric material inside the octagonal cavity ring. High sensitivity of the sensor in the resonance wavelength, simplicity and a compact geometry are the advantages of the refractive plasmonic sensor advised which make that possible to use it for designing high performance nano-sensor and bio-sensing devices.

  11. A new high-κ Al2O3 based metal-insulator-metal antifuse

    Science.gov (United States)

    Tian, Min; Zhong, Huicai; Li, Li; Wang, Zhigang

    2018-06-01

    In this paper, a new metal-insulator-metal (MIM) antifuse was fabricated with the high κ Al2O3 deposited by atomic layer deposition (ALD) as the dielectric. On this high κ antifuse structure, the very low on-state resistance was obtained under certain programming conditions. It is the first time that the antifuse on-state resistance has been found decreasing along with the increase of dielectric film thickness, which is attributed to a large current overshoot during breakdown. For the device with a dielectric thickness of 12 nm, very large overshoot current (∼60 mA) was observed and extremely low on-state resistance (∼10 Ω) was achieved.

  12. New technique for producing the alloys based on transition metals

    International Nuclear Information System (INIS)

    Dolukhanyan, S.K.; Aleksanyan, A.G.; Shekhtman, V.Sh.; Mantashyan, A.A.; Mayilyan, D.G.; Ter-Galstyan, O.P.

    2007-01-01

    In principle new technique was elaborated for obtaining the alloys of refractory metals by their hydrides compacting and following dehydrogenation. The elaborated technique is described. The conditions of alloys formation from different hydrides of appropriate metals was investigated in detail. The influence of the process parameters such as: chemical peculiarities, composition of source hydrides, phase transformation during dehydrogenation, etc. on the alloys formation were established. The binary and tertiary alloys of α and ω phases: Ti 0 .8Zr 0 .8; Ti 0 .66Zr 0 .33; Ti 0 .3Zr 0 .8; Ti 0 .2Zr 0 .8; Ti 0 .8Hf 0 .2; Ti 0 .6Hf 0 .4Ti 0 .66Zr 0 .23Hf 0 .11; etc were recieved. Using elaborated special hydride cycle, an earlier unknown effective process for formation of alloys of transition metals was realized. The dependence of final alloy structure on the composition of initial mixture and hydrogen content in source hydrides was established

  13. [Analisys of work-related accidents and incidents in an oil refinery in Rio de Janeiro].

    Science.gov (United States)

    de Souza, Carlos Augusto Vaz; de Freitas, Carlos Machado

    2003-01-01

    Accidents in the chemical industry can have serious consequences for workers, communities, and the environment and are thus highly relevant to public health. This article is the result of an occupational surveillance project involving several public institutions. We analyze 800 work-related accidents that resulted in injuries, environmental damage, or loss of production in 1997 in an oil refinery located in Rio de Janeiro, Brazil. The methodology was based on managerial and organizational approaches to accident investigation, with the European Union reporting system as the reference. The results highlight various limitations in the process of reporting and investigating accidents, as well as a certain hierarchy of accidents, with more attention given to accidents involving loss of production and less to those resulting in injuries, particularly among outsourced workers.

  14. Leak detection in a high-pressure heat exchanger system in a refinery using radiotracer technique

    International Nuclear Information System (INIS)

    Samantray, J.S.; Sunil Goswami; Sharma, V.K.; Jayashree Biswal; Pant, H.J.

    2014-01-01

    A radiotracer investigation was carried out in a diesel hydrotreater (DHDT) unit in a refinery for leak detection in a breech-lock heat exchanger system. The main objectives of the study were to identify the leaking heat exchanger in a system with six heat exchangers and estimate the leak rate. Bromine-82 as dibromobiphenyl was selected and used as radiotracer for the investigation. The radiotracer was instantaneously injected into the suction end of the feed pump line to the heat exchanger of the DHDT unit. The movement of the tracer was measured at strategically selected locations using NaI(Tl) scintillation detectors. Based upon the results of the radiotracer investigation, it was found that out of six heat exchangers, exchanger E-1F was leaking. (author)

  15. Characterization of hydrocarbon pollutant burdens in petrochemical and refinery process streams

    Energy Technology Data Exchange (ETDEWEB)

    Clements, L D; Cheng, S W

    1982-01-01

    The paper describes techniques which provide for both qualitative and quantitative identification of major components in a process stream. The techniques and instrumentation have been deliberately chosen so as to be within the technical and financial reach of all but the smallest company laboratory. The sample preparation steps consist of an initial series of extractions which isolate compounds into organic acid, base, and neutral compounds and a totally water soluble phase. Each fraction is then concentrated and subjected to thin-layer chromatography, gas chromatography, infrared spectroscopy or ultraviolet spectroscopy as appropriate. Results are given for laboratory samples, one a mixture of aniline, phenol, benzoic acid, m-nitrobenzaldehyde, 1-butanol, 2-hexanone, nonane, and cyclohexane, and the other a mixture of benzene, ethylbenzene, and styrene. Also, a qualitative analysis of a petroleum refinery desalter water is presented.

  16. Metal-on-Metal Total Hip Resurfacing Arthroplasty: An Evidence-Based Analysis.

    Science.gov (United States)

    2006-01-01

    The objective of this review was to assess the safety and effectiveness of metal on metal (MOM) hip resurfacing arthroplasty for young patients compared with that of total hip replacement (THR) in the same population. Total hip replacement has proved to be very effective for late middle-aged and elderly patients with severe degenerative diseases of the hips. As indications for THR began to include younger patients and those with a more active life style, the longevity of the implant became a concern. Evidence suggests that these patients experience relatively higher rates of early implant failure and the need for revision. The Swedish hip registry, for example, has demonstrated a survival rate in excess of 80% at 20 years for those aged over 65 years, whereas this figure was 33% by 16 years in those aged under 55 years. Hip resurfacing arthroplasty is a bone-conserving alternative to THR that restores normal joint biomechanics and load transfer. The technique has been used around the world for more than 10 years, specifically in the United Kingdom and other European countries. Metal-on-metal hip resurfacing arthroplasty is an alternative procedure to conventional THR in younger patients. Hip resurfacing arthroplasty is less invasive than THR and addresses the problem of preserving femoral bone stock at the initial operation. This means that future hip revisions are possible with THR if the initial MOM arthroplasty becomes less effective with time in these younger patients. The procedure involves the removal and replacement of the surface of the femoral head with a hollow metal hemisphere, which fits into a metal acetabular cup. Hip resurfacing arthroplasty is a technically more demanding procedure than is conventional THR. In hip resurfacing, the femoral head is retained, which makes it much more difficult to access the acetabular cup. However, hip resurfacing arthroplasty has several advantages over a conventional THR with a small (28 mm) ball. First, the large

  17. Gallium-Based Room-Temperature Liquid Metals: Actuation and Manipulation of Droplets and Flows

    Directory of Open Access Journals (Sweden)

    Leily Majidi

    2017-08-01

    Full Text Available Gallium-based room-temperature liquid metals possess extremely valuable properties, such as low toxicity, low vapor pressure, and high thermal and electrical conductivity enabling them to become suitable substitutes for mercury and beyond in wide range of applications. When exposed to air, a native oxide layer forms on the surface of gallium-based liquid metals which mechanically stabilizes the liquid. By removing or reconstructing the oxide skin, shape and state of liquid metal droplets and flows can be manipulated/actuated desirably. This can occur manually or in the presence/absence of a magnetic/electric field. These methods lead to numerous useful applications such as soft electronics, reconfigurable devices, and soft robots. In this mini-review, we summarize the most recent progresses achieved on liquid metal droplet generation and actuation of gallium-based liquid metals with/without an external force.

  18. Stereoselective assembly of amino acid-based metal-biomolecule nanofibers.

    Science.gov (United States)

    Wu, Hong; Tian, Chunyong; Zhang, Yufei; Yang, Chen; Zhang, Songping; Jiang, Zhongyi

    2015-04-14

    A series of amino acid-based metal-biomolecule nanofibers are fabricated through a coordination-directed assembly process. The chirality and carbon chain length of the amino acids exert a pronounced influence on the assembly process. This study may be extended to design diverse kinds of 1-D metal-biomolecule frameworks (MBioFs).

  19. Spectral, biological screening of metal chelates of chalcone based Schiff bases of N-(3-aminopropyl) imidazole.

    Science.gov (United States)

    Kalanithi, M; Rajarajan, M; Tharmaraj, P; Sheela, C D

    2012-02-15

    Tridentate chelate complexes of Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized from the chalcone based ligands 2-[1-(3-(1H-imidazol-1-yl)propylimino)-3-(phenylallyl)]phenol(HL(1)), 2-[1-(3-(1H-imidazol-1-yl)propylimino)-3-p-tolylallyl]phenol(HL(2)), 2-[1-(3-(1H-imidazol-1-yl)propylimino)-3-4-nitrophenylallyl]phenol(HL(3)). Microanalytical data, UV-vis spectrophotometric method, magnetic susceptibility measurements, IR, 1H NMR, Mass, and EPR techniques were used to characterize the structure of chelates. The electronic absorption spectra and magnetic susceptibility measurements suggest a distorted square planar geometry for the copper(II) ion. The other metal complexes show distorted tetrahedral geometry. The coordination of the ligands with metal(II) ions was further confirmed by solution fluorescence spectrum. The antimicrobial activity of the ligands and metal(II) complexes against the species Pseudomonas aeruginosa, Escherichia coli, Staphylococcus aureus, Bacillus subtilis, Candida albigans and Aspergillus niger has been carried out and compared. The electrochemical behavior of copper(II) complex is studied by cyclic voltammetry. Copyright © 2011 Elsevier B.V. All rights reserved.

  20. Thin metal films in resistivity-based chemical sensing

    Czech Academy of Sciences Publication Activity Database

    Podešva, Pavel; Foret, František

    2013-01-01

    Roč. 9, č. 4 (2013), s. 642-652 ISSN 1573-4110 R&D Projects: GA ČR(CZ) GAP301/11/2055 Institutional support: RVO:68081715 Keywords : voltohmmetric sensing * chemiresistor * thin metal film * gas sensing Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 1.194, year: 2013

  1. Simulated BRDF based on measured surface topography of metal

    Science.gov (United States)

    Yang, Haiyue; Haist, Tobias; Gronle, Marc; Osten, Wolfgang

    2017-06-01

    The radiative reflective properties of a calibration standard rough surface were simulated by ray tracing and the Finite-difference time-domain (FDTD) method. The simulation results have been used to compute the reflectance distribution functions (BRDF) of metal surfaces and have been compared with experimental measurements. The experimental and simulated results are in good agreement.

  2. High-temperature performance of a new nickel-based filler metal for power generation application

    Energy Technology Data Exchange (ETDEWEB)

    Shingledecker, J.; Coleman, K. [Electric Power Research Institute, Charlotte, NC (United States); Siefert, J.; Tanzosh, J. [Babcok and Wilcox Research Center, Barberton, OH (United States); Newell, W. [Euroweld, Mooresville, NC (United States)

    2010-07-01

    A new nickel-based weld filler metal, EPRI P87, has been developed as a superior alternative to ERNiCr-3 for use in dissimilar metal welds (DMW) between ferritic and austenitic materials. EPRI P87 has a low coefficient of thermal expansion more closely matching alloys such as Grade 91 and 92 than other available filler metals. Additionally, the size of the carbon denuded region adjacent to the weld in the heat-affected-zone is minimized/eliminated by proper control of weld metal composition. In this work the high-temperature mechanical behavior of DMWs utilizing EPRI P87 (GTAW and GMAW processes) was characterized through tensile and long-term creep-rupture testing. Microstructure analysis was also conducted on tested specimens to evaluate the HAZ regions and failure modes. Performance of the weld metal and welded joints is discussed and compared with ERNiCr-3 and typical 9%Cr-MoV filler metals. (orig.)

  3. Novel Base Metal-Palladium Catalytic Diesel Filter Coating with NO2 Reducing Properties

    DEFF Research Database (Denmark)

    Johansen, K.; Dahl, S.; Mogensen, G.

    2007-01-01

    A novel alternative base metal/palladium coat has been developed that has limited NO2 formation and which even removes NO2 in a wide temperature range.Soot combustion, HC conversion and CO conversion properties are comparable to current platinum based solutions but the coating has a more attracti...... solutions. Furthermore, durability results from base metal/Pd coated DPFs installed on operating taxis and related tests cycle data is given....

  4. Vacuum-based surface modification of organic and metallic substrates

    Science.gov (United States)

    Torres, Jessica

    Surface physico-chemical properties play an important role in the development and performance of materials in different applications. Consequently, understanding the chemical and physical processes involved during surface modification strategies is of great scientific and technological importance. This dissertation presents results from the surface modification of polymers, organic films and metallic substrates with reactive species, with the intent of simulating important modification processes and elucidating surface property changes of materials under different environments. The reactions of thermally evaporated copper and titanium with halogenated polytetrafluoroethylene (PTFE) and polyvinyl chloride (PVC) are used to contrast the interaction of metals with polymers. Results indicate that reactive metallization is thermodynamically favored when the metal-halogen bond strength is greater than the carbon-halogen bond strength. X-ray post-metallization treatment results in an increase in metal-halide bond formation due to the production of volatile halogen species in the polymer that react with the metallic overlayer. The reactions of atomic oxygen (AO) and atomic chlorine with polyethylene (PE) and self-assembled monolayers (SAMs) films were followed to ascertain the role of radical species during plasma-induced polymer surface modification. The reactions of AO with X-ray modified SAMs are initially the dominated by the incorporation of new oxygen containing functionality at the vacuum/film interface, leading to the production of volatile carbon containing species such as CO2 that erodes the hydrocarbon film. The reaction of atomic chlorine species with hydrocarbon SAMs, reveals that chlorination introduces C-Cl and C-Cl2 functionalities without erosion. A comparison of the reactions of AO and atomic chlorine with PE reveal a maximum incorporation of the corresponding C-O and C-Cl functionalities at the polymer surface. A novel method to prepare phosphorous

  5. Flexible supercapacitor electrodes based on real metal-like cellulose papers.

    Science.gov (United States)

    Ko, Yongmin; Kwon, Minseong; Bae, Wan Ki; Lee, Byeongyong; Lee, Seung Woo; Cho, Jinhan

    2017-09-14

    The effective implantation of conductive and charge storage materials into flexible frames has been strongly demanded for the development of flexible supercapacitors. Here, we introduce metallic cellulose paper-based supercapacitor electrodes with excellent energy storage performance by minimizing the contact resistance between neighboring metal and/or metal oxide nanoparticles using an assembly approach, called ligand-mediated layer-by-layer assembly. This approach can convert the insulating paper to the highly porous metallic paper with large surface areas that can function as current collectors and nanoparticle reservoirs for supercapacitor electrodes. Moreover, we demonstrate that the alternating structure design of the metal and pseudocapacitive nanoparticles on the metallic papers can remarkably increase the areal capacitance and rate capability with a notable decrease in the internal resistance. The maximum power and energy density of the metallic paper-based supercapacitors are estimated to be 15.1 mW cm -2 and 267.3 μWh cm -2 , respectively, substantially outperforming the performance of conventional paper or textile-type supercapacitors.With ligand-mediated layer-by-layer assembly between metal nanoparticles and small organic molecules, the authors prepare metallic paper electrodes for supercapacitors with high power and energy densities. This approach could be extended to various electrodes for portable/wearable electronics.

  6. Bipolar resistive switching in graphene oxide based metal insulator metal structure for non-volatile memory applications

    Science.gov (United States)

    Singh, Rakesh; Kumar, Ravi; Kumar, Anil; Kashyap, Rajesh; Kumar, Mukesh; Kumar, Dinesh

    2018-05-01

    Graphene oxide based devices have attracted much attention recently because of their possible application in next generation electronic devices. In this study, bipolar resistive switching characteristics of graphene oxide based metal insulator metal structure were investigated for nonvolatile memories. The graphene oxide was prepared by the conventional Hummer's method and deposited on ITO coated glass by spin-coating technique. The dominant mechanism of resistive switching is the formation and rupture of the conductive filament inside the graphene oxide. The conduction mechanism for low and high resistance states are dominated by two mechanism the ohmic conduction and space charge limited current (SCLC) mechanism, respectively. Atomic Force Microscopy, X-ray diffraction, Cyclic-Voltammetry were conducted to observe the morphology, structure and behavior of the material. The fabricated device with Al/GO/ITO structure exhibited reliable bipolar resistive switching with set & reset voltage of -2.3 V and 3V respectively.

  7. Systems and Methods for Fabricating Structures Including Metallic Glass-Based Materials Using Low Pressure Casting

    Science.gov (United States)

    Hofmann, Douglas C. (Inventor); Kennett, Andrew (Inventor)

    2018-01-01

    Systems and methods to fabricate objects including metallic glass-based materials using low-pressure casting techniques are described. In one embodiment, a method of fabricating an object that includes a metallic glass-based material includes: introducing molten alloy into a mold cavity defined by a mold using a low enough pressure such that the molten alloy does not conform to features of the mold cavity that are smaller than 100 microns; and cooling the molten alloy such that it solidifies, the solid including a metallic glass-based material.

  8. Carbon based secondary compounds do not provide protection against heavy metal road pollutants in epiphytic macrolichens.

    Science.gov (United States)

    Gauslaa, Yngvar; Yemets, Olena A; Asplund, Johan; Solhaug, Knut Asbjørn

    2016-01-15

    Lichens are useful monitoring organisms for heavy metal pollution. They are high in carbon based secondary compounds (CBSCs) among which some may chelate heavy metals and thus increase metal accumulation. This study quantifies CBSCs in four epiphytic lichens transplanted for 6months on stands along transects from a highway in southern Norway to search for relationships between concentrations of heavy metals and CBSCs along a gradient in heavy metal pollutants. Viability parameters and concentrations of 21 elements including nutrients and heavy metals in these lichen samples were reported in a separate paper. Medullary CBSCs in fruticose lichens (Ramalina farinacea, Usnea dasypoga) were reduced in the most polluted sites, but not in foliose ones (Parmelia sulcata, Lobaria pulmonaria), whereas cortical CBSC did not change with distance from the road in any species. Strong positive correlations only occurred between the major medullary compound stictic acid present in L. pulmonaria and most heavy metals, consistent with a chelating role of stictic acid, but not of other studied CBSCs or in other species. However, heavy metal chelating did not protect L. pulmonaria against damage because this species experienced the strongest reduction in viability in the polluted sites. CBSCs with an accumulation potential for heavy metals should be quantified in lichen biomonitoring studies of heavy metals because they, like stictic acid, could overshadow pollutant inputs in some species rendering biomonitoring data less useful. In the two fruticose lichen species, CBSCs decreased with increasing heavy metal concentration, probably because heavy metal exposure impaired secondary metabolism. Thus, we found no support for a heavy metal protection role of any CBSCs in studied epiphytic lichens. No intraspecific relationships occurred between CBSCs versus N or C/N-ratio. Interspecifically, medullary CBSCs decreased and cortical CBSCs increased with increasing C/N-ratio. Copyright © 2015

  9. Influence of S. mutans on base-metal dental casting alloy toxicity.

    Science.gov (United States)

    McGinley, E L; Dowling, A H; Moran, G P; Fleming, G J P

    2013-01-01

    We have highlighted that exposure of base-metal dental casting alloys to the acidogenic bacterium Streptococcus mutans significantly increases cellular toxicity following exposure to immortalized human TR146 oral keratinocytes. With Inductively Coupled Plasma-Mass Spectrometry (ICP-MS), S. mutans-treated nickel-based (Ni-based) and cobalt-chromium-based (Co-Cr-based) dental casting alloys were shown to leach elevated levels of metal ions compared with untreated dental casting alloys. We targeted several biological parameters: cell morphology, viable cell counts, cell metabolic activity, cell toxicity, and inflammatory cytokine expression. S. mutans-treated dental casting alloys disrupted cell morphology, elicited significantly decreased viable cell counts (p casting alloys induced elevated levels of cellular toxicity compared with S. mutans-treated Co-Cr-based dental casting alloys. While our findings indicated that the exacerbated release of metal ions from S. mutans-treated base-metal dental casting alloys was the likely result of the pH reduction during S. mutans growth, the exact nature of mechanisms leading to accelerated dissolution of alloy-discs is not yet fully understood. Given the predominance of S. mutans oral carriage and the exacerbated cytotoxicity observed in TR146 cells following exposure to S. mutans-treated base-metal dental casting alloys, the implications for the long-term stability of base-metal dental restorations in the oral cavity are a cause for concern.

  10. Zirconia- versus metal-based, implant-supported abutments and crowns

    DEFF Research Database (Denmark)

    Hosseini, Mandana

    , the selection of restoration materials should be based on proper optical characteristics in addition to biocompatibility and sufficient strength of materials. Abutments and crowns based on zirconia are one of the most recent alternatives to metal abutments and metal-ceramic crowns. To date, only few comparative...... and to estimate long-term biomechanical results of zirconia-based versus metal-based restorations. The aim of study I was to analyse the mode of fracture and number of cyclic loadings until veneering fracture of zirconia-based all-ceramic restorations compared to metal-ceramic restorations. The aim of study II...... was to test the reliability and validity of six aesthetic parameters used at the Copenhagen Dental School to assess the aesthetic outcome of implant-supported restorations. The aims of study III and IV were to compare the influence of different abutment and crown materials on biological, biomechanical...

  11. Accumulation of Heavy Metals in Soil and Kiwifruit of Planting Base in Western Hunan Province, China

    Directory of Open Access Journals (Sweden)

    WANG Ren-cai

    2017-05-01

    Full Text Available The heavy metals accumulation in soil and kiwi fruit plant in Western Hunan Province main kiwifruit planting base were analyzed, such as As, Pb, Hg, Cd, Cr. The results showed that the accumulation of heavy metals in soil of 6 kiwifruit planting areas were not obvious. The contents of heavy metals in most of areas of Western Hunan Province were below the national standard, except one area where the soil contents of cadmium (4.900 mg·kg-1, mercury (0.634 mg·kg-1were exceeded. At the same time, the comprehensive pollution index of heavy metals was less than 0.7 in these areas. There were 5 bases with no pollution of heavy metal, all which the kiwifruit could be safely produced in line with the requirements of the green kiwifruit planting base soil standards. At these areas, the contents of various heavy metals(except cadmium and mercurywere small in the branches and leaves of kiwifruit; kiwifruit had a very well capacity to absorb the cadmium when the cadmium content of its branches reached 12.73%. The heavy metal contents of the kiwifruit in the 6 regions, which belonging to the pollutionfree green fruits, were below or far lower than the national standard. According to the comprehensive analysis, the soil condition of the main cultivated land in Western Hunan Province was good, and the fruit had no heavy metal residues.

  12. Poultry litter-based activated carbon for removing heavy metal ions in water.

    Science.gov (United States)

    Guo, Mingxin; Qiu, Guannan; Song, Weiping

    2010-02-01

    Utilization of poultry litter as a precursor material to manufacture activated carbon for treating heavy metal-contaminated water is a value-added strategy for recycling the organic waste. Batch adsorption experiments were conducted to investigate kinetics, isotherms, and capacity of poultry litter-based activated carbon for removing heavy metal ions in water. It was revealed that poultry litter-based activated carbon possessed significantly higher adsorption affinity and capacity for heavy metals than commercial activated carbons derived from bituminous coal and coconut shell. Adsorption of metal ions onto poultry litter-based carbon was rapid and followed Sigmoidal Chapman patterns as a function of contact time. Adsorption isotherms could be described by different models such as Langmuir and Freundlich equations, depending on the metal species and the coexistence of other metal ions. Potentially 404 mmol of Cu2+, 945 mmol of Pb2+, 236 mmol of Zn2+, and 250-300 mmol of Cd2+ would be adsorbed per kg of poultry litter-derived activated carbon. Releases of nutrients and metal ions from litter-derived carbon did not pose secondary water contamination risks. The study suggests that poultry litter can be utilized as a precursor material for economically manufacturing granular activated carbon that is to be used in wastewater treatment for removing heavy metals.

  13. Bio-Refineries Bioprocess Technologies for Waste-Water Treatment, Energy and Product Valorization

    Science.gov (United States)

    Keith Cowan, A.

    2010-04-01

    Increasing pressure is being exerted on communities and nations to source energy from forms other than fossil fuels. Also, potable water is becoming a scarce resource in many parts of the world, and there remains a large divide in the demand and utilization of plant products derived from genetically modified organisms (GMOs) and non-GMOs. The most extensive user and manager of terrestrial ecosystems is agriculture which is also the de facto steward of natural resources. As stated by Miller (2008) no other industry or institution comes close to the comparative advantage held for this vital responsibility while simultaneously providing food, fiber, and other biology-based products, including energy. Since modern commercial agriculture is transitioning from the production of bulk commodities to the provision of standardized products and specific-attribute raw materials for differentiated markets, we can argue that processes such as mass cultivation of microalgae and the concept of bio-refineries be seen as part of a `new' agronomy. EBRU is currently exploring the integration of bioprocess technologies using microalgae as biocatalysts to achieve waste-water treatment, water polishing and endocrine disruptor (EDC) removal, sustainable energy production, and exploitation of the resultant biomass in agriculture as foliar fertilizer and seed coatings, and for commercial extraction of bulk commodities such as bio-oils and lecithin. This presentation will address efforts to establish a fully operational solar-driven microalgae bio-refinery for use not only in waste remediation but to transform waste and biomass to energy, fuels, and other useful materials (valorisation), with particular focus on environmental quality and sustainability goals.

  14. Optimization of petroleum refinery effluent treatment in a UASB reactor using response surface methodology

    Energy Technology Data Exchange (ETDEWEB)

    Rastegar, S.O. [Biotechnology Group, Chemical Engineering Department, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Mousavi, S.M., E-mail: mousavi_m@modares.ac.ir [Biotechnology Group, Chemical Engineering Department, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Shojaosadati, S.A. [Biotechnology Group, Chemical Engineering Department, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Sheibani, S. [R and T Management Department, National Iranian Oil Refining and Distribution Company, Tehran (Iran, Islamic Republic of)

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer A UASB was successfully used for treatment of petroleum refinery effluent. Black-Right-Pointing-Pointer Response surface methodology was applied to design and analysis of experiments. Black-Right-Pointing-Pointer System was modeled between efficient factors include HRT, influent COD and V{sub up}. Black-Right-Pointing-Pointer UASB was able to remove about 76.3% influent COD at optimum conditions. - Abstract: An upflow anaerobic sludge blanket (UASB) bioreactor was successfully used for the treatment of petroleum refinery effluent. Before optimization, chemical oxygen demand (COD) removal was 81% at a constant organic loading rate (OLR) of 0.4 kg/m{sup 3} d and a hydraulic retention time (HRT) of 48 h. The rate of biogas production was 559 mL/h at an HRT of 40 h and an influent COD of 1000 mg/L. Response surface methodology (RSM) was applied to predict the behaviors of influent COD, upflow velocity (V{sub up}) and HRT in the bioreactor. RSM showed that the best models for COD removal and biogas production rate were the reduced quadratic and cubic models, respectively. The optimum region, identified based on two critical responses, was an influent COD of 630 mg/L, a V{sub up} of 0.27 m/h, and an HRT of 21.4 h. This resulted in a 76.3% COD removal efficiency and a 0.25 L biogas/L feed d biogas production rate.

  15. Identification of genes and pathways related to phenol degradation in metagenomic libraries from petroleum refinery wastewater.

    Directory of Open Access Journals (Sweden)

    Cynthia C Silva

    Full Text Available Two fosmid libraries, totaling 13,200 clones, were obtained from bioreactor sludge of petroleum refinery wastewater treatment system. The library screening based on PCR and biological activity assays revealed more than 400 positive clones for phenol degradation. From these, 100 clones were randomly selected for pyrosequencing in order to evaluate the genetic potential of the microorganisms present in wastewater treatment plant for biodegradation, focusing mainly on novel genes and pathways of phenol and aromatic compound degradation. The sequence analysis of selected clones yielded 129,635 reads at an estimated 17-fold coverage. The phylogenetic analysis showed Burkholderiales and Rhodocyclales as the most abundant orders among the selected fosmid clones. The MG-RAST analysis revealed a broad metabolic profile with important functions for wastewater treatment, including metabolism of aromatic compounds, nitrogen, sulphur and phosphorus. The predicted 2,276 proteins included phenol hydroxylases and cathecol 2,3- dioxygenases, involved in the catabolism of aromatic compounds, such as phenol, byphenol, benzoate and phenylpropanoid. The sequencing of one fosmid insert of 33 kb unraveled the gene that permitted the host, Escherichia coli EPI300, to grow in the presence of aromatic compounds. Additionally, the comparison of the whole fosmid sequence against bacterial genomes deposited in GenBank showed that about 90% of sequence showed no identity to known sequences of Proteobacteria deposited in the NCBI database. This study surveyed the functional potential of fosmid clones for aromatic compound degradation and contributed to our knowledge of the biodegradative capacity and pathways of microbial assemblages present in refinery wastewater treatment system.

  16. Techno-Economic Evaluation of Technologies to Mitigate Greenhouse Gas Emissions at North American Refineries.

    Science.gov (United States)

    Motazedi, Kavan; Abella, Jessica P; Bergerson, Joule A

    2017-02-07

    A petroleum refinery model, Petroleum Refinery Life-cycle Inventory Model (PRELIM), that estimates energy use and CO 2 emissions was modified to evaluate the environmental and economic performance of a set of technologies to reduce CO 2 emissions at refineries. Cogeneration of heat and power (CHP), carbon capture at fluid catalytic cracker (FCC) and steam methane reformer (SMR) units, and alternative hydrogen production technologies were considered in the analysis. The results indicate that a 3-44% reduction in total annual refinery CO 2 emissions (2-24% reductions in the CO 2 emissions on a per barrel of crude oil processed) can be achieved in a medium conversion refinery that processes a typical U.S. crude slate obtained by using the technologies considered. A sensitivity analysis of the quality of input crude to a refinery, refinery configuration, and prices of natural gas and electricity revealed how the magnitude of possible CO 2 emissions reductions and the economic performance of the mitigation technologies can vary under different conditions. The analysis can help inform decision making related to investment decisions and CO 2 emissions policy in the refining sector.

  17. Combined analysis of job and task benzene air exposures among workers at four US refinery operations.

    Science.gov (United States)

    Burns, Amanda; Shin, Jennifer Mi; Unice, Ken M; Gaffney, Shannon H; Kreider, Marisa L; Gelatt, Richard H; Panko, Julie M

    2017-03-01

    Workplace air samples analyzed for benzene at four US refineries from 1976 to 2007 were pooled into a single dataset to characterize similarities and differences between job titles, tasks and refineries, and to provide a robust dataset for exposure reconstruction. Approximately 12,000 non-task (>180 min) personal samples associated with 50 job titles and 4000 task (job titles and task codes across all four refineries, and (5) our analysis of variance (ANOVA) of the distribution of benzene air concentrations for select jobs/tasks across all four refineries. The jobs and tasks most frequently sampled included those with highest potential contact with refinery product streams containing benzene, which reflected the targeted sampling approach utilized by the facility industrial hygienists. Task and non-task data were analyzed to identify and account for significant differences within job-area, task-job, and task-area categories. This analysis demonstrated that in general, areas with benzene containing process streams were associated with greater benzene air concentrations compared to areas with process streams containing little to no benzene. For several job titles and tasks analyzed, there was a statistically significant decrease in benzene air concentration after 1990. This study provides a job and task-focused analysis of occupational exposure to benzene during refinery operations, and it should be useful for reconstructing refinery workers' exposures to benzene over the past 30 years.

  18. Commercial production of metal hafnium and hafnium-based products

    International Nuclear Information System (INIS)

    Negodin, D.A.; Shtutsa, M.G.; Akhtonov, S.G.; Il'enko, E.V.; Kobyzev, A.M.

    2012-01-01

    Hafnium possesses a unique complex of physical and chemical properties which allow the application of products on its basis in various industries. Joint Stock Company 'Chepetsky Mechanical Plant' is the single enterprise which produces hafnium on the territory of Russia. The manufacture of metal hafnium with the total content of zirconium and hafnium, at least, 99,8 % of weights is developed at the present time at Joint Stock Company CHMZ. The weight of melted hafnium ingots is up to 1 ton. Manufacture of wide range of products from hafnium is implemented. The plates from a hafnium with thickness of 0.60 mm which are used for emergency control cartridges of VVER-440 reactors are the most critical product. It is shown that ingots and products obtained from metal hafnium correspond to the Russian and international standards for reactor materials in chemical composition, mechanical and corrosion properties.

  19. Wetting of refractory metals with copper base alloys

    International Nuclear Information System (INIS)

    Anikeev, E.F.; Kostikov, V.I.; Chepelenko, V.N.; Batov, V.M.

    1978-01-01

    The effect is studied of phosphorus upon the wetting of molybdenum, niobium and tantalum by an alloy of the system copper-silver (10%) as a function of contact time and phosphorus concentration. Experiments have been conducted in vacuum of 5x10 -4 mm Hg at 900 deg C. It is established that the introduction of phosphorus into a copper-silver alloy improves the wetting of molybdenum, niobium and tantalum. Formation of intermetallic compounds on the alloy-refractory metal interface can be avoided by adjusting the time of contact of the solder with molybdenum, niobium and tantalum. As a solder with 2.9% phosphorus spreads well over copper, it is suggested to use said solder for brazing copper and the investigated refractory metals in items intended for service at temperatures of up to 600 deg C

  20. Structural study of Zr-based metallic glasses

    International Nuclear Information System (INIS)

    Matsubara, E.; Ichitsubo, T.; Saida, J.; Kohara, S.; Ohsumi, H.

    2007-01-01

    Structures of Zr 70 Ni 20 Al 10 , Zr 70 Cu 20 Al 10 , Zr 70 Cu 30 and Zr 70 Ni 30 amorphous alloys were analyzed by high-energy X-ray diffraction. The relatively stable Zr 2 Cu amorphous alloy shows a local atom arrangement different from the Zr 2 Cu crystalline phase. By contrast, the less stable Zr 70 Ni 30 amorphous alloy has a structure similar to Zr 2 Ni. In the Zr 70 Cu 20 Al 10 metallic glass, Zr-Al nearest neighbor pairs are introduced in the amorphous structure. In the Zr 70 Ni 20 Al 10 metallic glass, the strong correlation between Zr-Ni pairs is drastically modified by the formation of Zr-Al pairs. The presence of Zr-Al pairs in the ternary alloys suppresses the crystallization and stabilizes the glassy state

  1. Trophic transfer of metal-based nanoparticles in aquatic environments

    DEFF Research Database (Denmark)

    Tangaa, Stine Rosendal; Selck, Henriette; Winther-Nielsen, Margrethe

    2016-01-01

    Metal-containing engineered nanoparticles (Me-ENPs) are used in a wide range of products including inks, plastics, personal care products, clothing and electronic devices. The release of Me-ENPs has been demonstrated from some products, and thus, particles are likely to enter the aquatic environm......Metal-containing engineered nanoparticles (Me-ENPs) are used in a wide range of products including inks, plastics, personal care products, clothing and electronic devices. The release of Me-ENPs has been demonstrated from some products, and thus, particles are likely to enter the aquatic...... environment where they have been shown to be taken up by a variety of species. Therefore, there is a possibility that Me-ENPs will enter and pass through aquatic food webs, but research on this topic is limited. In this tutorial review, we discuss the factors contributing to trophic transfer of Me......-ENPs, and where this information is scarce, we utilize the existing literature on aqueous metal trophic transfer as a potential starting point for greater mechanistic insight and for setting directions for future studies. We identify four key factors affecting trophic transfer of Me-ENPs: (1) environmental...

  2. Facile preparation of superhydrophobic surfaces based on metal oxide nanoparticles

    Science.gov (United States)

    Bao, Xue-Mei; Cui, Jin-Feng; Sun, Han-Xue; Liang, Wei-Dong; Zhu, Zhao-Qi; An, Jin; Yang, Bao-Ping; La, Pei-Qing; Li, An

    2014-06-01

    A novel method for fabrication of superhydrophobic surfaces was developed by facile coating various metal oxide nanoparticles, including ZnO, Al2O3 and Fe3O4, on various substrates followed by treatment with polydimethylsiloxane (PDMS) via chemical vapor deposition (CVD) method. Using ZnO nanoparticles as a model, the changes in the surface chemical composition and crystalline structures of the metal oxide nanoparticles by PDMS treatment were investigated by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The results show that the combination of the improved surface roughness generated from of the nanoparticles aggregation with the low surface-energy of silicon-coating originated from the thermal pyrolysis of PDMS would be responsible for the surface superhydrophobicity. By a simple dip-coating method, we show that the metal oxide nanoparticles can be easily coated onto the surfaces of various textural and dimensional substrates, including glass slide, paper, fabric or sponge, for preparation of superhydrophobic surfaces for different purpose. The present strategy may provide an inexpensive and new route to surperhydrophobic surfaces, which would be of technological significance for various practical applications especially for separation of oils or organic contaminates from water.

  3. Facile preparation of superhydrophobic surfaces based on metal oxide nanoparticles

    International Nuclear Information System (INIS)

    Bao, Xue-Mei; Cui, Jin-Feng; Sun, Han-Xue; Liang, Wei-Dong; Zhu, Zhao-Qi; An, Jin; Yang, Bao-Ping; La, Pei-Qing; Li, An

    2014-01-01

    A novel method for fabrication of superhydrophobic surfaces was developed by facile coating various metal oxide nanoparticles, including ZnO, Al 2 O 3 and Fe 3 O 4 , on various substrates followed by treatment with polydimethylsiloxane (PDMS) via chemical vapor deposition (CVD) method. Using ZnO nanoparticles as a model, the changes in the surface chemical composition and crystalline structures of the metal oxide nanoparticles by PDMS treatment were investigated by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The results show that the combination of the improved surface roughness generated from of the nanoparticles aggregation with the low surface-energy of silicon-coating originated from the thermal pyrolysis of PDMS would be responsible for the surface superhydrophobicity. By a simple dip-coating method, we show that the metal oxide nanoparticles can be easily coated onto the surfaces of various textural and dimensional substrates, including glass slide, paper, fabric or sponge, for preparation of superhydrophobic surfaces for different purpose. The present strategy may provide an inexpensive and new route to surperhydrophobic surfaces, which would be of technological significance for various practical applications especially for separation of oils or organic contaminates from water.

  4. Facile preparation of superhydrophobic surfaces based on metal oxide nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Bao, Xue-Mei; Cui, Jin-Feng; Sun, Han-Xue; Liang, Wei-Dong; Zhu, Zhao-Qi; An, Jin; Yang, Bao-Ping; La, Pei-Qing; Li, An, E-mail: lian2010@lut.cn

    2014-06-01

    A novel method for fabrication of superhydrophobic surfaces was developed by facile coating various metal oxide nanoparticles, including ZnO, Al{sub 2}O{sub 3} and Fe{sub 3}O{sub 4}, on various substrates followed by treatment with polydimethylsiloxane (PDMS) via chemical vapor deposition (CVD) method. Using ZnO nanoparticles as a model, the changes in the surface chemical composition and crystalline structures of the metal oxide nanoparticles by PDMS treatment were investigated by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) analysis. The results show that the combination of the improved surface roughness generated from of the nanoparticles aggregation with the low surface-energy of silicon-coating originated from the thermal pyrolysis of PDMS would be responsible for the surface superhydrophobicity. By a simple dip-coating method, we show that the metal oxide nanoparticles can be easily coated onto the surfaces of various textural and dimensional substrates, including glass slide, paper, fabric or sponge, for preparation of superhydrophobic surfaces for different purpose. The present strategy may provide an inexpensive and new route to surperhydrophobic surfaces, which would be of technological significance for various practical applications especially for separation of oils or organic contaminates from water.

  5. Evaluating Heavy Metal Stress Levels in Rice Based on Remote Sensing Phenology.

    Science.gov (United States)

    Liu, Tianjiao; Liu, Xiangnan; Liu, Meiling; Wu, Ling

    2018-03-14

    Heavy metal pollution of croplands is a major environmental problem worldwide. Methods for accurately and quickly monitoring heavy metal stress have important practical significance. Many studies have explored heavy metal stress in rice in relation to physiological function or physiological factors, but few studies have considered phenology, which can be sensitive to heavy metal stress. In this study, we used an integrated Normalized Difference Vegetation Index (NDVI) time-series image set to extract remote sensing phenology. A phenological indicator relatively sensitive to heavy metal stress was chosen from the obtained phenological periods and phenological parameters. The Dry Weight of Roots (WRT), which directly affected by heavy metal stress, was simulated by the World Food Study (WOFOST) model; then, a feature space based on the phenological indicator and WRT was established for monitoring heavy metal stress. The results indicated that the feature space can distinguish the heavy metal stress levels in rice, with accuracy greater than 95% for distinguishing the severe stress level. This finding provides scientific evidence for combining rice phenology and physiological characteristics in time and space, and the method is useful to monitor heavy metal stress in rice.

  6. Wear behaviour of Zr-based in situ bulk metallic glass matrix ...

    Indian Academy of Sciences (India)

    based bulk metallic glass (BMG) and its in situ BMG matrix composites with diameter of 3 mm were fabricated by conventional Cu-mould casting method and ... The composites showed lower friction coefficient and wear rate than the pure BMG.

  7. A constitutive model of nanocrystalline metals based on competing grain boundary and grain interior deformation mechanisms

    KAUST Repository

    Gurses, Ercan; El Sayed, Tamer S.

    2011-01-01

    In this work, a viscoplastic constitutive model for nanocrystalline metals is presented. The model is based on competing grain boundary and grain interior deformation mechanisms. In particular, inelastic deformations caused by grain boundary

  8. Liquid alkali metals and alkali-based alloys as electron-ion plasmas

    International Nuclear Information System (INIS)

    Tosi, M.P.

    1981-06-01

    The article reviews the theory of thermodynamic and structural properties of liquid alkali metals and alkali-based alloys, within the framework of linear screening theory for the electron-ion interactions. (author)

  9. PHYSICAL BASES OF SYSTEMS CREATION FOR MAGNETIC-IMPULSIVE ATTRACTION OF THIN-WALLED SHEET METALS

    Directory of Open Access Journals (Sweden)

    Y. Batygin

    2009-01-01

    Full Text Available The work is dedicated to the physical base of systems creating for the thin-walled sheet metals magnetic pulse attraction. Some practical realization models of the author’s suggestions are represented.

  10. Development of Low Density CaMg-A1-Based Bulk Metallic Glasses (Preprint)

    National Research Council Canada - National Science Library

    Senkov, O. N; Scott, J. M; Miracle, D. B

    2006-01-01

    Low density Ca-Mg-Al-based bulk metallic glasses containing additionally Cu and Zn, were produced by a copper mold casting method as wedge-shaped samples with thicknesses varying from 0.5 mm to 10 rom...

  11. Wear behaviour of Zr-based in situ bulk metallic glass matrix ...

    Indian Academy of Sciences (India)

    based bulk metallic glasses; in situ composites; ductile phase; wear behaviours. 1. Introduction ... crystalline alloys [2], which led to an abnormal phenomenon that the wear ... of BMGs does not follow the empirical Archard's wear equa- tion which ...

  12. Reliability Modeling Development and Its Applications for Ceramic Capacitors with Base-Metal Electrodes (BMEs)

    Science.gov (United States)

    Liu, Donhang

    2014-01-01

    This presentation includes a summary of NEPP-funded deliverables for the Base-Metal Electrodes (BMEs) capacitor task, development of a general reliability model for BME capacitors, and a summary and future work.

  13. Cancer incidence and mortality among temporary maintenance workers in a refinery/petrochemical complex in Korea

    Science.gov (United States)

    Koh, Dong-Hee; Chung, Eun-Kyo; Jang, Jae-Kil; Lee, Hye-Eun; Ryu, Hyang-Woo; Yoo, Kye-Mook; Kim, Eun-A; Kim, Kyoo-Sang

    2014-01-01

    Background: Petrochemical plant maintenance workers are exposed to various carcinogens such as benzene and metal fumes. In Korea, maintenance operations in petrochemical plants are typically performed by temporary employees hired as contract workers. Objectives: The purpose of this retrospective study was to evaluate cancer risk in temporary maintenance workers in a refinery/petrochemical complex in Korea. Methods: Subjects consisted of 14 698 male workers registered in a regional petrochemical plant maintenance workers union during 2002–2007. Cancer mortality and incidence were identified by linking with the nationwide death and cancer registries during 2002–2007 and 2002–2005, respectively. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for each cancer. Results: Increased SMR 3.61 (six cases, 95% CI: 1.32–7.87) and SIR 3.18 (five cases, 95% CI: 1.03–7.42) were observed in oral and pharyngeal cancers. Conclusion: Our findings may suggest a potential association between oral and pharyngeal cancers and temporary maintenance jobs in the petrochemical industry. Future studies should include a longer follow-up period and a quantitative exposure assessment. PMID:24999849

  14. Nickel, vanadium, and lead as indicators of sediment contamination of marina, refinery, and shipyard areas.

    Science.gov (United States)

    Pereira, Thayane Lúcia; Wallner-Kersanach, Mônica; Costa, Luiza Dy Fonseca; Costa, Daniel Pereira; Baisch, Paulo Roberto Martins

    2018-01-01

    Metallic elements found in the aquatic environment may originate in areas where petroleum is refined and vessels are maintained and repaired. This study aims to assess contamination caused by nickel (Ni), lead (Pb), and vanadium (V) in sediment of the Lagoa dos Patos estuary (RS, Brazil) and to evaluate them as indicators of areas under the influence of petroleum products and antifouling paints. Surface sediments were collected in summer and in winter in areas of marinas, shipyards, refinery, and a control station. High Pb and V concentrations in shipyards and at the Yacht Club showed that some organisms may be affected by toxicity. High Pb results of the index of geoaccumulation (Igeo) were found at the Yacht Club and shipyards. Al, Ni, and V had similar distribution in the sediment in both seasons. Ni and V had high relation in winter at the Yacht Club and at the Santos Shipyard, thus suggesting that these elements come mainly from petroleum products. The same happened to the relations between Pb and V, as well as Pb and Ni at the Santos Shipyard. These elements are employed as useful tools as indicators to identify places with moderate to high localized anthropogenic inputs of petroleum derivatives and antifouling paints.

  15. Multivariate approach to assessing ecotoxicity on abandoned oil refinery environments: Study site description

    International Nuclear Information System (INIS)

    Lochmiller, R.L.; Yates, G.W.

    1993-01-01

    Ecology risk assessment requires a clear understanding of how complex mixtures of environmental contaminants impact terrestrial ecosystems. This assessment process could be more universally applied to terrestrial ecosystems with better defined assay systems for evaluating impacts of exposure on organisms, populations, and communities. The authors objective was to define and assess the efficacy of a battery of assays incorporating both standard biological toxicity test and in situ biomonitors for evaluating ecological risks on terrestrial environments contaminated with complex mixtures of petrochemicals on a 160 acre abandoned oil refinery in central Oklahoma. Three suspected contaminated and three uncontaminated reference sites were selected for intensive study. Habitat on each study site is representative of disturbed tall-grass prairie and supports dense, diverse small mammal communities. Soil samples were subjected to aqueous extraction and resulting leachates analyzed for heavy metals, selected ions, and organics. Analytical results support their initial assessment that toxic study sites were contaminated with complex mixtures including lead, zinc, arsenic, chloride, sulfate, potassium, and complex mixtures of polar and non-polar organics

  16. Metal recovery from high-grade WEEE

    DEFF Research Database (Denmark)

    Bigum, Marianne; Brogaard, Line Kai-Sørensen; Christensen, Thomas Højlund

    2012-01-01

    . The modeled metallurgical treatment facility included a Kaldo plant, a converter aisle, an anode refinery and a precious metal refinery. The metallurgic treatment showed significant environmental savings when credited the environmental load from avoided production of the same amount of metals by mining...... and refining of ore. The resource recovery per tonne of high-grade WEEE ranged from 2 g of palladium to 386 kg of iron. Quantified in terms of person-equivalents the recovery of palladium, gold, silver, nickel and copper constituted the major environmental benefit of the recovery of metals from WEEE....... These benefits are most likely underestimated in the model, since we did not find adequate data to include all the burdens from mining and refining of ore; burdens that are avoided when metals are recovered from WEEE. The processes connected to the pre-treatment of WEEE were found to have little environmental...

  17. Corrosion resistance of high performance stainless steels in cooling water and other refinery environments

    International Nuclear Information System (INIS)

    Kovach, C.W.; Redmerski, L.S.

    1984-01-01

    The recent successful introduction of high performance stainless steels as tubing for seawater cooled electric utility condensers suggests that these alloys can also provide useful service in refinery heat exchanger applications. Since many of these applications involve higher temperature exposure than steam condensers, a study was conducted to evaluate crevice corrsion resistance over a range of cooling water temperature and chloride concentrations, and also to evaluate general corrosion resistance in some strong chemical and refinery environments. These stainless steels display excellent crevice corrosion resistance as well as good resistance to a variety of chemical environments that may be encountered in refinery, petrochemical and chemical plant service

  18. Multi objective multi refinery optimization with environmental and catastrophic failure effects objectives

    Science.gov (United States)

    Khogeer, Ahmed Sirag

    2005-11-01

    Petroleum refining is a capital-intensive business. With stringent environmental regulations on the processing industry and declining refining margins, political instability, increased risk of war and terrorist attacks in which refineries and fuel transportation grids may be targeted, higher pressures are exerted on refiners to optimize performance and find the best combination of feed and processes to produce salable products that meet stricter product specifications, while at the same time meeting refinery supply commitments and of course making profit. This is done through multi objective optimization. For corporate refining companies and at the national level, Intea-Refinery and Inter-Refinery optimization is the second step in optimizing the operation of the whole refining chain as a single system. Most refinery-wide optimization methods do not cover multiple objectives such as minimizing environmental impact, avoiding catastrophic failures, or enhancing product spec upgrade effects. This work starts by carrying out a refinery-wide, single objective optimization, and then moves to multi objective-single refinery optimization. The last step is multi objective-multi refinery optimization, the objectives of which are analysis of the effects of economic, environmental, product spec, strategic, and catastrophic failure. Simulation runs were carried out using both MATLAB and ASPEN PIMS utilizing nonlinear techniques to solve the optimization problem. The results addressed the need to debottleneck some refineries or transportation media in order to meet the demand for essential products under partial or total failure scenarios. They also addressed how importing some high spec products can help recover some of the losses and what is needed in order to accomplish this. In addition, the results showed nonlinear relations among local and global objectives for some refineries. The results demonstrate that refineries can have a local multi objective optimum that does not

  19. Microstructure and chemical analysis of Hf-based high-k dielectric layers in metal-insulator-metal capacitors

    Energy Technology Data Exchange (ETDEWEB)

    Thangadurai, P. [Department of Materials Engineering, Technion - Israel Institute of Technology, Haifa 32000 (Israel); Mikhelashvili, V.; Eisenstein, G. [Department of Electrical Engineering, Technion - Israel Institute of Technology, Haifa 32000 (Israel); Kaplan, W.D., E-mail: kaplan@tx.technion.ac.i [Department of Materials Engineering, Technion - Israel Institute of Technology, Haifa 32000 (Israel)

    2010-05-31

    The microstructure and chemistry of the high-k gate dielectric significantly influences the performance of metal-insulator-metal (MIM) and metal-oxide-semiconductor devices. In particular, the local structure, chemistry, and inter-layer mixing are important phenomena to be understood. In the present study, high resolution and analytical transmission electron microscopy are combined to study the local structure, morphology, and chemistry in MIM capacitors containing a Hf-based high-k dielectric. The gate dielectric, bottom and gate electrodes were deposited on p-type Si(100) wafers by electron beam evaporation. Four chemically distinguishable sub-layers were identified within the dielectric stack. One is an unintentionally formed 4.0 nm thick interfacial layer of Ta{sub 2}O{sub 5} at the interface between the Ta electrode and the dielectric. The other three layers are based on HfN{sub x}O{sub y} and HfTiO{sub y}, and intermixing between the nearby sub-layers including deposited SiO{sub 2}. Hf-rich clusters were found in the HfN{sub x}O{sub y} layer adjacent to the Ta{sub 2}O{sub 5} layer.

  20. Aerobic degradation of petroleum refinery wastewater in sequential batch reactor.

    Science.gov (United States)

    Thakur, Chandrakant; Srivastava, Vimal C; Mall, Indra D

    2014-01-01

    The aim of the present work was to study the effect of various parameters affecting the treatment of raw petroleum refinery wastewater (PRW) having chemical oxygen demand (COD) of 350 mg L(-1) and total organic carbon (TOC) of 70 mg L(-1) in sequential batch reactor (SBR). Effect of hydraulic retention time (HRT) was studied in instantaneous fill condition. Maximum COD and TOC removal efficiencies were found to be 80% and 84%, respectively, for fill phase of 2 h and react phase of 2 h with fraction of SBR being filled with raw PRW in each cycle being 0.4. Effect of parameters was studied in terms of settling characteristic of treated slurry. Kinetics of treatment process has been studied. FTIR and UV-visible analysis of PRW before and after treatment have been performed so as to understand the degradation mechanism.

  1. Phenol oxidation of petrol refinery wastewater catalyzed by Laccase

    International Nuclear Information System (INIS)

    Vargas, Maria Carolina; Ramirez, Nubia E.

    2002-01-01

    Laccase has been obtained through two different production systems, the first using Pleurotus ostreatus in solid-state fermentation, the second one using Trametes versicolor in submerged culture. Different substrates (by products from yeast, flour and beverage industries) have been evaluated in both systems. Maximum laccase yield with Pleurotus ostreatus (25 u/ml) was obtained in a wheat bran medium. The maximum enzyme concentration level using Trametes versicolor (25 u/ml) was achieved in a submerged system, containing 10% vinasse, 4,5% wheat bran and 0,2% molasses per liter of waste. Culture filtrate extracted from Pleurotus ostreatus was used to remove phenol from wastewater. The enzymatic treatment is effective over a wide pH and temperature range. The Laccase treatment has been successfully used to dephenolize industrial petrol refinery wastewater. The advantage of Laccase dephenolization is that this enzyme uses molecular oxygen as an oxidant

  2. Cleaning up gasoline will increase refinery hydrogen demand

    International Nuclear Information System (INIS)

    Pretorius, E.B.; Muan, A.

    1992-01-01

    This paper reports that hydrogen needs will increase two to five times as the world turns its attention to cleaning up engine exhaust. The subject of fuel trends and hydrogen needs at Foster Wheeler USA Corp.'s Hydrogen Plant Conference, June 2--4, in Orlando was addressed. The conference was attended by more than 100 people from 12 different countries. Drawing on knowledge from over 1 billion scfd of total installed hydrogen plant capacity, Foster Wheeler experts presented papers in the fields of steam reforming, partial oxidation (with all feedstocks, from natural gas to resids and coal), and steam reformer design. Other industry specialists gave papers on refinery balances, markets, coal feedstocks, utility systems, and components for hydrogen plants

  3. BTEX biodegradation by bacteria from effluents of petroleum refinery.

    Science.gov (United States)

    Mazzeo, Dânia Elisa Christofoletti; Levy, Carlos Emílio; de Angelis, Dejanira de Franceschi; Marin-Morales, Maria Aparecida

    2010-09-15

    Groundwater contamination with benzene, toluene, ethylbenzene and xylene (BTEX) has been increasing, thus requiring an urgent development of methodologies that are able to remove or minimize the damages these compounds can cause to the environment. The biodegradation process using microorganisms has been regarded as an efficient technology to treat places contaminated with hydrocarbons, since they are able to biotransform and/or biodegrade target pollutants. To prove the efficiency of this process, besides chemical analysis, the use of biological assessments has been indicated. This work identified and selected BTEX-biodegrading microorganisms present in effluents from petroleum refinery, and evaluated the efficiency of microorganism biodegradation process for reducing genotoxic and mutagenic BTEX damage through two test-systems: Allium cepa and hepatoma tissue culture (HTC) cells. Five different non-biodegraded BTEX concentrations were evaluated in relation to biodegraded concentrations. The biodegradation process was performed in a BOD Trak Apparatus (HACH) for 20 days, using microorganisms pre-selected through enrichment. Although the biodegradation usually occurs by a consortium of different microorganisms, the consortium in this study was composed exclusively of five bacteria species and the bacteria Pseudomonas putida was held responsible for the BTEX biodegradation. The chemical analyses showed that BTEX was reduced in the biodegraded concentrations. The results obtained with genotoxicity assays, carried out with both A. cepa and HTC cells, showed that the biodegradation process was able to decrease the genotoxic damages of BTEX. By mutagenic tests, we observed a decrease in damage only to the A. cepa organism. Although no decrease in mutagenicity was observed for HTC cells, no increase of this effect after the biodegradation process was observed either. The application of pre-selected bacteria in biodegradation processes can represent a reliable and

  4. Vacuum spark breakdown model based on exploding metal wire phenomena

    International Nuclear Information System (INIS)

    Haaland, J.

    1984-06-01

    Spark source mass spectra (SSMS) indicates that ions are extracted from an expanding and decaying plasma. The intensity distribution shows no dependance on vaporization properties of individual elements which indicates explosive vapour formation. This seems further to be a requirement for bridging a vacuum gap. A model including plasma ejection from a superheated anode spot by a process similar to that of an exploding metal wire is proposed. The appearance of hot plasma points in low inductance vacuum sparks can then be explained as exploding micro particles ejected from a final central anode spot. The phenomenological model is compared with available experimental results from literature, but no extensive quantification is attempted

  5. Nanopatterned bulk metallic glass-based biomaterials modulate macrophage polarization.

    Science.gov (United States)

    Shayan, Mahdis; Padmanabhan, Jagannath; Morris, Aaron H; Cheung, Bettina; Smith, Ryan; Schroers, Jan; Kyriakides, Themis R

    2018-06-01

    Polarization of macrophages by chemical, topographical and mechanical cues presents a robust strategy for designing immunomodulatory biomaterials. Here, we studied the ability of nanopatterned bulk metallic glasses (BMGs), a new class of metallic biomaterials, to modulate murine macrophage polarization. Cytokine/chemokine analysis of IL-4 or IFNγ/LPS-stimulated macrophages showed that the secretion of TNF-α, IL-1α, IL-12, CCL-2 and CXCL1 was significantly reduced after 24-hour culture on BMGs with 55 nm nanorod arrays (BMG-55). Additionally, under these conditions, macrophages increased phagocytic potential and exhibited decreased cell area with multiple actin protrusions. These in vitro findings suggest that nanopatterning can modulate biochemical cues such as IFNγ/LPS. In vivo evaluation of the subcutaneous host response at 2 weeks demonstrated that the ratio of Arg-1 to iNOS increased in macrophages adjacent to BMG-55 implants, suggesting modulation of polarization. In addition, macrophage fusion and fibrous capsule thickness decreased and the number and size of blood vessels increased, which is consistent with changes in macrophage responses. Our study demonstrates that nanopatterning of BMG implants is a promising technique to selectively polarize macrophages to modulate the immune response, and also presents an effective tool to study mechanisms of macrophage polarization and function. Implanted biomaterials elicit a complex series of tissue and cellular responses, termed the foreign body response (FBR), that can be influenced by the polarization state of macrophages. Surface topography can influence polarization, which is broadly characterized as either inflammatory or repair-like. The latter has been linked to improved outcomes of the FBR. However, the impact of topography on macrophage polarization is not fully understood, in part, due to a lack of high moduli biomaterials that can be reproducibly processed at the nanoscale. Here, we studied

  6. Electrochemical characterization of Zr-based thin film metallic glass in hydrochloric aqueous solution

    International Nuclear Information System (INIS)

    Chuang, Ching-Yen; Liao, Yi-Chia; Lee, Jyh-Wei; Li, Chia-Lin; Chu, Jinn P.; Duh, Jenq-Gong

    2013-01-01

    Recently thin film metallic glass represents a class of promising engineering materials for structural applications. In this work, the Zr-based thin film metallic glass (TFMG) was fabricated on the Si and AISI 420 substrates using a Zr–Cu–Ni–Al alloy and pure Zr metal targets by a pulsed DC magnetron sputtering system. The chemical compositions, crystalline structures, microstructures and corrosion behavior in hydrochloric (HCl) aqueous solutions of Zr-based TFMGs were investigated. The results showed that the surface morphologies of Zr-based TFMG were very smooth. A compact and dense structure without columnar structure was observed. The amorphous structure of Zr-based TFMG was characterized by the X-ray diffractometer and transmission electron microscopy analyses. After the potentiodynamic polarization test, the better corrosion resistance was achieved for the Zr-based TFMG coated AISI 420 in 1 mM HCl aqueous solution. Based on the surface morphologies and chemical analysis results of the corroded surfaces, the pitting, crevice corrosion and filiform corrosion were found. The corrosion mechanisms of the Zr-based TFMG were discussed in this work. - Highlights: ► Zr-based thin film metallic glass with amorphous structure. ► Better corrosion resistance of Zr-based thin film metallic glass observed. ► Pitting, crevice and filiform corrosion reactions revealed. ► The Cu-rich corrosion products found in the pit. ► Nanowire and flaky corrosion products formed adjacent to the filiform corrosion path

  7. Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making

    Science.gov (United States)

    Kumta, Prashant N.; Kadakia, Karan Sandeep; Datta, Moni Kanchan; Velikokhatnyi, Oleg

    2017-02-07

    The invention provides electro-catalyst compositions for an anode electrode of a proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.

  8. The development of PC-based real time ultrasonic metal thickness inspection system

    International Nuclear Information System (INIS)

    Suhairy Sani; Mohd Hanif Md Saad; Mohamad Pauzi Ismail; Ab Razak Hamzah; Abd Nassir Ibrahim; Amri Amin Abas

    2006-01-01

    This paper discusses the development of a PC-Based Real Time Ultrasonic Thickness Measurement system (UTMS) for metallic components such as pipes, pressure vessels and metal slabs. Metal thickness measurement for these components is crucial in industrial plants with dangerous environment, such as in oil and gas industry. From the measured metal thickness, a number of deductions could be made, for example the state and the rate of corrosion propagation inside a pipe or pressure vessel, etc. One of the most widely used methods in assessing metal thickness in industry is through the use of Ultrasonic technology. The benefits of using UTMS lies in the flexibility of data analysis, which includes signal processing, feature extraction, visualization capability and intelligent diagnosis. Data can be acquired in real-time and stored for future usage and application. The system was developed as a standalone computer software using Microsoft Visual-BASIC 6. (Author)

  9. Logic circuits based on individual semiconducting and metallic carbon-nanotube devices

    International Nuclear Information System (INIS)

    Ryu, Hyeyeon; Kaelblein, Daniel; Ante, Frederik; Zschieschang, Ute; Kern, Klaus; Klauk, Hagen; Weitz, R Thomas; Schmidt, Oliver G

    2010-01-01

    Nanoscale transistors employing an individual semiconducting carbon nanotube as the channel hold great potential for logic circuits with large integration densities that can be manufactured on glass or plastic substrates. Carbon nanotubes are usually produced as a mixture of semiconducting and metallic nanotubes. Since only semiconducting nanotubes yield transistors, the metallic nanotubes are typically not utilized. However, integrated circuits often require not only transistors, but also resistive load devices. Here we show that many of the metallic carbon nanotubes that are deposited on the substrate along with the semiconducting nanotubes can be conveniently utilized as load resistors with favorable characteristics for the design of integrated circuits. We also demonstrate the fabrication of arrays of transistors and resistors, each based on an individual semiconducting or metallic carbon nanotube, and their integration on glass substrates into logic circuits with switching frequencies of up to 500 kHz using a custom-designed metal interconnect layer.

  10. Theoretical and experimental investigation of wear characteristics of aluminum based metal matrix composites using RSM

    International Nuclear Information System (INIS)

    Selvi, S.; Rajasekar, E.

    2015-01-01

    The tribological properties such as wear rate, hardness of the aluminum-fly ash composite synthesized by stir casting were investigated by varying the weight % of fly ash from 5 to 20 with constant weight % of zinc and magnesium metal powder. A mathematical model was developed to predict the wear rate of aluminum metal matrix composites and the adequacy of the model was verified using analysis of variance. Scanning electron microscopy was used for the microstructure analysis which showed a uniform distribution of fly ash in the metal matrix. Energy - dispersive X-ray spectroscopy was used for the elemental analysis or chemical characterization of a sample. The results showed that addition of fly ash to aluminum based metal matrix improved both the mechanical and tribological properties of the composites. The fly ash particles improved the wear resistance of the metal matrix composites because the hardness of the samples taken increased as the fly ash content was increased.

  11. The Survey and Measurement of Ni, Pb, Cu, Mn, Zn, Cd and V Content in Green Vegetables of South Area of Tehran Refinery

    International Nuclear Information System (INIS)

    Kazemzadeh Khoyi, J.; Noori, A. S.; Pourang, N.; Alizadeh, M.; Ghoreishi, H.; Padash, A.

    2013-01-01

    Oil pollution is one of the most critical soil and water pollutant. Areas which are subjected to oil industry may have this kind of pollution by different ways such as extraction, transformation and refining. The example of these areas is south east of Tehran refinery which is surrounded by agricultural fields and are subjected by pollution via Tehran refinery, oil transforming lines, waste water and industrial activities. Since the crops from this area is providing the needs of neighbor cities like Tehran, to realize their oil pollution, the content of some heavy metals like Ni, V, Cu, Cd, Zn, Pb and Mn has been measured. The results analyzed by analytical method include SPSS and MVSP. Finally the relation between elements and pollution has been recognized. The result of this survey showed the high heavy metal content in most plants which were higher than similar research. Onion had the highest amount of most heavy metals. Ni and Pd content were high in plants which are indicator of oil pollution.

  12. Structural study of Zr-based metallic glasses

    Energy Technology Data Exchange (ETDEWEB)

    Matsubara, E. [Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan)]. E-mail: e.matsubara@materials.mbox.media.kyoto-u.ac.jp; Ichitsubo, T. [Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan); Saida, J. [Center of Interdisciplinary Research, Tohoku University, Sendai 980-8578 (Japan); Kohara, S. [JASRI, SPring-8, Sayo-gun, Hyogo 679-5198 (Japan); Ohsumi, H. [JASRI, SPring-8, Sayo-gun, Hyogo 679-5198 (Japan)

    2007-05-31

    Structures of Zr{sub 70}Ni{sub 20}Al{sub 10}, Zr{sub 70}Cu{sub 20}Al{sub 10}, Zr{sub 70}Cu{sub 30} and Zr{sub 70}Ni{sub 30} amorphous alloys were analyzed by high-energy X-ray diffraction. The relatively stable Zr{sub 2}Cu amorphous alloy shows a local atom arrangement different from the Zr{sub 2}Cu crystalline phase. By contrast, the less stable Zr{sub 70}Ni{sub 30} amorphous alloy has a structure similar to Zr{sub 2}Ni. In the Zr{sub 70}Cu{sub 20}Al{sub 10} metallic glass, Zr-Al nearest neighbor pairs are introduced in the amorphous structure. In the Zr{sub 70}Ni{sub 20}Al{sub 10} metallic glass, the strong correlation between Zr-Ni pairs is drastically modified by the formation of Zr-Al pairs. The presence of Zr-Al pairs in the ternary alloys suppresses the crystallization and stabilizes the glassy state.

  13. Immobilisation of heavy metal in cement-based solidification/stabilisation: A review

    International Nuclear Information System (INIS)

    Chen, Q.Y.; Tyrer, M.; Hills, C.D.; Yang, X.M.; Carey, P.

    2009-01-01

    Heavy metal-bearing waste usually needs solidification/stabilization (s/s) prior to landfill to lower the leaching rate. Cement is the most adaptable binder currently available for the immobilisation of heavy metals. The selection of cements and operating parameters depends upon an understanding of chemistry of the system. This paper discusses interactions of heavy metals and cement phases in the solidification/stabilisation process. It provides a clarification of heavy metal effects on cement hydration. According to the decomposition rate of minerals, heavy metals accelerate the hydration of tricalcium silicate (C 3 S) and Portland cement, although they retard the precipitation of portlandite due to the reduction of pH resulted from hydrolyses of heavy metal ions. The chemical mechanism relevant to the accelerating effect of heavy metals is considered to be H + attacks on cement phases and the precipitation of calcium heavy metal double hydroxides, which consumes calcium ions and then promotes the decomposition of C 3 S. In this work, molecular models of calcium silicate hydrate gel are presented based on the examination of 29 Si solid-state magic angle spinning/nuclear magnetic resonance (MAS/NMR). This paper also reviews immobilisation mechanisms of heavy metals in hydrated cement matrices, focusing on the sorption, precipitation and chemical incorporation of cement hydration products. It is concluded that further research on the phase development during cement hydration in the presence of heavy metals and thermodynamic modelling is needed to improve effectiveness of cement-based s/s and extend this waste management technique

  14. Mobilization and attenuation of metals downstream from a base-metal mining site in the Matra Mountains, northeastern Hungary

    Science.gov (United States)

    Odor, L.; Wanty, R.B.; Horvath, I.; Fugedi, U.; ,

    1999-01-01

    Regional geochemical baseline values have been established for Hungary by the use of low-density stream-sediment surveys of flood-plain deposits of large drainage basins and of the fine fraction of stream sediments. The baseline values and anomaly thresholds thus produced helped to evaluate the importance of high toxic element concentrations found in soils in a valley downstream of a polymetallic vein-type base-metal mine. Erosion of the mine dumps and flotation dump, losses of metals during filtering, storage and transportation, human neglects, and operational breakdowns, have all contributed to the contamination of a small catchment basin in a procession of releases of solid waste. The sulfide-rich waste material weathers to a yellow color; this layer of 'yellow sand' blankets a narrow strip of the floodplain of Toka Creek in the valley near the town of Gyongyosoroszi. Contamination was spread out in the valley by floods. Metals present in the yellow sand include Pb, As, Cd, Cu, Zn, and Sb. Exposure of the local population to these metals may occur through inhalation of airborne particulates or by ingestion of these metals that are taken up by crops grown in the valley. To evaluate the areal extent and depth of the contamination, active stream sediment, flood-plain deposits, lake or reservoir sediments, soils, and surface water were sampled along the erosion pathways downstream of the mine and dumps. The flood-plain profile was sampled in detail to see the vertical distribution of elements and to relate the metal concentrations to the sedimentation and contamination histories of the flood plain. Downward migration of mobile Zn and Cd from the contaminated upper layers under supergene conditions is observed, while vertical migration of Pb, As, Hg and Sb appears to be insignificant. Soil profiles of 137Cs which originated from above-ground atomic bomb tests and the Chernobyl accident, provide good evidence that the upper 30-40 cm of the flood-plain sections, which

  15. Metal artifact reduction algorithm based on model images and spatial information

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Jay [Institute of Radiological Science, Central Taiwan University of Science and Technology, Taichung, Taiwan (China); Shih, Cheng-Ting [Department of Biomedical Engineering and Environmental Sciences, National Tsing-Hua University, Hsinchu, Taiwan (China); Chang, Shu-Jun [Health Physics Division, Institute of Nuclear Energy Research, Taoyuan, Taiwan (China); Huang, Tzung-Chi [Department of Biomedical Imaging and Radiological Science, China Medical University, Taichung, Taiwan (China); Sun, Jing-Yi [Institute of Radiological Science, Central Taiwan University of Science and Technology, Taichung, Taiwan (China); Wu, Tung-Hsin, E-mail: tung@ym.edu.tw [Department of Biomedical Imaging and Radiological Sciences, National Yang-Ming University, No.155, Sec. 2, Linong Street, Taipei 112, Taiwan (China)

    2011-10-01

    Computed tomography (CT) has become one of the most favorable choices for diagnosis of trauma. However, high-density metal implants can induce metal artifacts in CT images, compromising image quality. In this study, we proposed a model-based metal artifact reduction (MAR) algorithm. First, we built a model image using the k-means clustering technique with spatial information and calculated the difference between the original image and the model image. Then, the projection data of these two images were combined using an exponential weighting function. At last, the corrected image was reconstructed using the filter back-projection algorithm. Two metal-artifact contaminated images were studied. For the cylindrical water phantom image, the metal artifact was effectively removed. The mean CT number of water was improved from -28.95{+-}97.97 to -4.76{+-}4.28. For the clinical pelvic CT image, the dark band and the metal line were removed, and the continuity and uniformity of the soft tissue were recovered as well. These results indicate that the proposed MAR algorithm is useful for reducing metal artifact and could improve the diagnostic value of metal-artifact contaminated CT images.

  16. Spectral CT metal artifact reduction with an optimization-based reconstruction algorithm

    Science.gov (United States)

    Gilat Schmidt, Taly; Barber, Rina F.; Sidky, Emil Y.

    2017-03-01

    Metal objects cause artifacts in computed tomography (CT) images. This work investigated the feasibility of a spectral CT method to reduce metal artifacts. Spectral CT acquisition combined with optimization-based reconstruction is proposed to reduce artifacts by modeling the physical effects that cause metal artifacts and by providing the flexibility to selectively remove corrupted spectral measurements in the spectral-sinogram space. The proposed Constrained `One-Step' Spectral CT Image Reconstruction (cOSSCIR) algorithm directly estimates the basis material maps while enforcing convex constraints. The incorporation of constraints on the reconstructed basis material maps is expected to mitigate undersampling effects that occur when corrupted data is excluded from reconstruction. The feasibility of the cOSSCIR algorithm to reduce metal artifacts was investigated through simulations of a pelvis phantom. The cOSSCIR algorithm was investigated with and without the use of a third basis material representing metal. The effects of excluding data corrupted by metal were also investigated. The results demonstrated that the proposed cOSSCIR algorithm reduced metal artifacts and improved CT number accuracy. For example, CT number error in a bright shading artifact region was reduced from 403 HU in the reference filtered backprojection reconstruction to 33 HU using the proposed algorithm in simulation. In the dark shading regions, the error was reduced from 1141 HU to 25 HU. Of the investigated approaches, decomposing the data into three basis material maps and excluding the corrupted data demonstrated the greatest reduction in metal artifacts.

  17. More evidence of unpublished industry studies of lead smelter/refinery workers

    Science.gov (United States)

    2015-01-01

    Background Lead smelter/refinery workers in the US have had significant exposure to lead and are an important occupational group to study to understand the health effects of chronic lead exposure in adults. Recent research found evidence that studies of lead smelter/refinery workers have been conducted but not published. This paper presents further evidence for this contention. Objectives To present further evidence of industry conducted, unpublished epidemiologic studies of lead smelter/refinery workers and health outcomes. Methods Historical research relying on primary sources such as internal industry documents and published studies. Results ASARCO smelter/refinery workers were studied in the early 1980s and found to have increased risk of lung cancer and stroke in one study, but not in another. Conclusions Because occupational lead exposure is an on-going concern for US and overseas workers, all epidemiologic studies should be made available to evaluate and update occupational health and safety standards. PMID:26070220

  18. Implication of coastal refineries to the ecology of the Gulf of Kachchh

    Digital Repository Service at National Institute of Oceanography (India)

    Zingde, M.D.; Anand, N.M.

    bank of the Gulf of Kachchh. An assessment of probable impact of establishment of these refineries to the rich biodiversity of the Gulf and suggestions to minimise these impacts have been made in this paper....

  19. Detection of impurities in fluid flowing in refinery pipeline or oil production operations using nuclear techniques

    International Nuclear Information System (INIS)

    1981-01-01

    Chlorine (from salt water) and sulphur are determined in crude oil in a well head conduit or refined product in a petroleum refinery by bombardment with neutrons and measuring the gamma rays emitted by neutron capture reactions. (U.K.)

  20. Applications of Open Source GMAW-Based Metal 3-D Printing

    Directory of Open Access Journals (Sweden)

    Yuenyong Nilsiam

    2018-03-01

    Full Text Available The metal 3-D printing market is currently dominated by high-end applications, which make it inaccessible for small and medium enterprises, fab labs, and individual makers who are interested in the ability to prototype and additively manufacture final products in metal. Recent progress led to low-cost open-source metal 3-D printers using a gas metal arc welding (GMAW-based print head. This reduced the cost of metal 3-D printers into the range of desktop prosumer polymer 3-D printers. Consequent research established good material properties of metal 3-D printed parts with readily-available weld filler wire, reusable substrates, thermal and stress properties, toolpath planning, bead-width control, mechanical properties, and support for overhangs. These previous works showed that GMAW-based metal 3-D printing has a good adhesion between layers and is not porous inside the printed parts, but they did not proceed far enough to demonstrate applications. In this study, the utility of the GMAW approach to 3-D printing is investigated using a low-cost open-source metal 3-D printer and a converted Computer Numerical Control router machine to make useful parts over a range of applications including: fixing an existing part by adding a 3-D metal feature, creating a product using the substrate as part of the component, 3-D printing in high resolution of useful objects, near net objects, and making an integrated product using a combination of steel and polymer 3-D printing. The results show that GMAW-based 3-D printing is capable of distributed manufacturing of useful products for a wide variety of applications for sustainable development.

  1. Zn isotope study of atmospheric emissions and dry depositions within a 5 km radius of a Pb-Zn refinery

    Science.gov (United States)

    Mattielli, Nadine; Petit, Jérôme C. J.; Deboudt, Karine; Flament, Pascal; Perdrix, Esperanza; Taillez, Aurélien; Rimetz-Planchon, Juliette; Weis, Dominique

    The present paper examines the use of zinc isotopes as tracers of atmospheric sources and focuses on the potential fractionation of Zn isotopes through anthropogenic processes. In order to do so, Zn isotopic ratios are measured in enriched ores and airborne particles associated with pyrometallurgical activities of one of the major Pb-Zn refineries in France. Supporting the isotopic investigation, this paper also compares morphological and chemical characteristics of Zn particles collected on dry deposition plates ("environmental samples") placed within a 5 km radius of the smelter, with those of Zn particles collected inside the plant ("process samples"), i.e. dust collected from the main exhaust system of the plant. To ensure a constant isotopic "supply", the refinery processed a specific set of ores during the sampling campaigns, as agreed with the executive staff of the plant. Enriched ores and dust produced by the successive Zn extraction steps show strong isotope fractionation (from -0.66 to +0.22‰) mainly related to evaporation processes within the blast furnaces. Dust from the main chimney displays a δ 66Zn value of -0.67‰. Application of the Rayleigh equation to evaluate the fractionation factor associated with the Zn vapor produced after a free evaporation gives a range of αore/vapor from 1.0004 to 1.0008. The dry deposits, collected on plates downwind of the refinery, display δ 66Zn variations of up to +0.7‰. However, it is to be noted that between 190 and 1250 m from the main chimney of the refinery, the dry deposits show a high level of large (>10 μm) Zn, S, Fe and O bearing aggregates characterized by positive δ 66Zn values (+0.02 to +0.19‰). These airborne particles probably derive from the re-suspension of slag heaps and local emissions from the working-units. In contrast, from 1720 to 4560 m, the dry deposits are comprised of small (PM10) particles, including spherical Zn-bearing aggregates, showing negative δ 66Zn values (-0.52 to -0

  2. Chemical composition of individual aerosol particles from working areas in a nickel refinery.

    Science.gov (United States)

    Höflich, B L; Wentzel, M; Ortner, H M; Weinbruch, S; Skogstad, A; Hetland, S; Thomassen, Y; Chaschin, V P; Nieboer, E

    2000-06-01

    Individual aerosol particles (n = 1170) collected at work stations in a nickel refinery were analyzed by wavelength-dispersive electron-probe microanalysis. By placing arbitrary restrictions on the contents of sulfur and silicon, the particles could be divided into four main groups. Scanning electron images indicated that most of the particles examined were relatively small (refinery intermediates. The implications of the findings for aerosol speciation measurements, toxicological studies and interpretation of adverse health effects are explored.

  3. Material resources, energy, and nutrient recovery from waste: are waste refineries the solution for the future?

    DEFF Research Database (Denmark)

    Tonini, Davide; Martinez-Sanchez, Veronica; Astrup, Thomas Fruergaard

    2013-01-01

    Waste refineries focusing on multiple outputs of material resources, energy carriers, and nutrients may potentially provide more sustainable utilization of waste resources than traditional waste technologies. This consequential life cycle assessment (LCA) evaluated the environmental performance....... Overall, the waste refinery provided global warming (GW) savings comparable with efficient incineration, MBT, and bioreactor landfilling technologies. The main environmental benefits from waste refining were a potential for improved phosphorus recovery (about 85%) and increased electricity production (by...

  4. The genesis of the base metal ore deposit from Herja

    Directory of Open Access Journals (Sweden)

    Gheorghe Damian

    2003-04-01

    Full Text Available The Herja ore deposit is one of the most known of the Baia Mare Neogene metallogenetic district and is associated with a complex stock of Pannonian age. The hydrothermal alterations associated with the mineralizations are represented by: the propylitization, the argillization, the phyllic and potassic alteration. The monoascenedant character of the mineralizations is predominant. The magmatic intrusions have been sequential placed and have represented the heat, metals and hydrothermal solutions source. In the first stages of mineralization the hydrothermal solutions contain predominantly magmatic water and in the final stages the water is of connate and meteoric origin. According to the structural magmatic control, to the mineralogical composition and to the hydrothermal alterations, the Herja ore deposits are of a low sulphidation epithermal systems type.

  5. Fe-based bulk metallic glasses used for magnetic shielding

    Energy Technology Data Exchange (ETDEWEB)

    Serban, Va; Codrean, C; UTu, D [Politehnica University of Timisoara, Depart for Materials Science and Welding, 1, M. Viteazu Bvd., 300222, Timisoara (Romania); ErcuTa, A, E-mail: serban@mec.upt.r [West University of Timisoara, Faculty of Physics, 4, Vasile Parvan Bdv., Timisoara 300223 (Romania)

    2009-01-01

    The casting in complex shapes (tubular) and the main magnetic properties of bulk metallic glasses (BMG) alloys from the ferromagnetic Fe-Cr-Ni-Ga-P-Si-C system, with a small addition of Ni (3%) were studied. Samples as rods and sockets having the thickness up to 1 mm were obtained from master alloys by melt injection by low cooling rates into a Cu mold and annealed in order to ensure adequate magnetic requirements. The structure was examined by X-ray diffraction (XRD) and the basic magnetic properties (coercivity, magnetic remanence, initial susceptibility, etc.) were determined by conventional low frequency induction method. The experimental investigations on producing of BMG ferromagnetic alloys with 3% Ni show the possibility to obtain magnetic shields of complex shape with satisfactory magnetic properties. The presence of Ni does not affect the glass forming ability, but reduce the shielding capacity.

  6. Antimicrobial, thermoanalytical and viscometric studies of metal based schiff base polymer

    International Nuclear Information System (INIS)

    Mughal, M.A.; Mughal, A.

    2013-01-01

    This study examines the synthesis, characterization, viscosity, thermal behavior and antimicrobial studies of copper(II) and nickel(II), complexes of a synthesized monomer 5,5-methylene bis(2-pyridinecarboxaldehyde) (MBPC) and a Schiff base polymer poly-5,5-methylene bis (2-pyridinecarboxaldehyde) 1,3-propylenedimine (PMBPCPR). The monomer, polymeric ligand and poly metal complexes (PMBPCPRCu) and (PMBPCPRNi) were characterized by C.H.N analysis, FT-IR, UV - Vis spectroscopy, viscometery thermogravimetric (TGA) and differential thermogravimetry (DTA). The monomer MBPC was prepared by the reaction of 2-pyridinecarboxaldehyde with 1, 3, 5-trioxane in the presence of acetic acid and sulphuric acid. The polymeric ligand was prepared by polycondensation of monomer with 1,3-propylenediamine. The biological studies of compounds revealed that they possessed significant antibacterial and antifungal properties, against Micrococcus flavus, Staphylococcus aureus, Bacillus Cirroflgellosus, Shigella flexneri, Escherichia Coli, Candida albicans, Aspergillus flavus, and A. Niger. (author)

  7. Considerably improved photovoltaic performance of carbon nanotube-based solar cells using metal oxide layers.

    Science.gov (United States)

    Wang, Feijiu; Kozawa, Daichi; Miyauchi, Yuhei; Hiraoka, Kazushi; Mouri, Shinichiro; Ohno, Yutaka; Matsuda, Kazunari

    2015-02-18

    Carbon nanotube-based solar cells have been extensively studied from the perspective of potential application. Here we demonstrated a significant improvement of the carbon nanotube solar cells by the use of metal oxide layers for efficient carrier transport. The metal oxides also serve as an antireflection layer and an efficient carrier dopant, leading to a reduction in the loss of the incident solar light and an increase in the photocurrent, respectively. As a consequence, the photovoltaic performance of both p-single-walled carbon nanotube (SWNT)/n-Si and n-SWNT/p-Si heterojunction solar cells using MoOx and ZnO layers is improved, resulting in very high photovoltaic conversion efficiencies of 17.0 and 4.0%, respectively. These findings regarding the use of metal oxides as multifunctional layers suggest that metal oxide layers could improve the performance of various electronic devices based on carbon nanotubes.

  8. Considerably improved photovoltaic performance of carbon nanotube-based solar cells using metal oxide layers

    Science.gov (United States)

    Wang, Feijiu; Kozawa, Daichi; Miyauchi, Yuhei; Hiraoka, Kazushi; Mouri, Shinichiro; Ohno, Yutaka; Matsuda, Kazunari

    2015-02-01

    Carbon nanotube-based solar cells have been extensively studied from the perspective of potential application. Here we demonstrated a significant improvement of the carbon nanotube solar cells by the use of metal oxide layers for efficient carrier transport. The metal oxides also serve as an antireflection layer and an efficient carrier dopant, leading to a reduction in the loss of the incident solar light and an increase in the photocurrent, respectively. As a consequence, the photovoltaic performance of both p-single-walled carbon nanotube (SWNT)/n-Si and n-SWNT/p-Si heterojunction solar cells using MoOx and ZnO layers is improved, resulting in very high photovoltaic conversion efficiencies of 17.0 and 4.0%, respectively. These findings regarding the use of metal oxides as multifunctional layers suggest that metal oxide layers could improve the performance of various electronic devices based on carbon nanotubes.

  9. The life of some metallic uranium based fuel elements; Duree de vie de quelques combustibles a base d'uranium metal

    Energy Technology Data Exchange (ETDEWEB)

    Stohr, J A; Englander, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1958-07-01

    Description of some theoretical and experimental data concerning the design and most economic preparation of metallic uranium based fuel elements, which are intended to produce an energy of 3 kW days/g of uranium in a thermal reactor, at a sufficiently high mean temperature. Experimental results obtained by testing by analogy or by actually trying out fuel elements obtained by alloying uranium with other metals in proportions such that the resistance to deformation of the alloy produced is much higher than that of pure metallic uranium and that the thermal utilisation factor is only slightly different from that of the uranium. (author) [French] Description de quelques donnees theoriques et experimentales concernant la conception et la preparation la plus economique d'elements combustibles a base d'uranium metallique naturel, destines a degager dans un reacteur thermique une energie de l'ordre de 3 kWj/g d'uranium a une temperature moyenne suffisamment elevee. Resultats experimentaux acquis par tests analogiques ou reels sur combustibles obtenus par alliage de l'uranium avec des elements metalliques en proportions telles que la resistance a la deformation soit bien superieure a celle de l'uranium metal pur et que le facteur propre d'utilisation thermique n ne soit que peu affecte. (auteur)

  10. The energy efficiency of crude oil refining in Brazil: A Brazilian refinery plant case

    International Nuclear Information System (INIS)

    Lima, Romulo S. de; Schaeffer, Roberto

    2011-01-01

    This article evaluates energy efficiency in Brazilian crude oil refining in comparison with the crude oil refining in the United States between 1930 and 2008. It aims to show that increased refinery complexity reduces the energy consumption of products of high value added. Moreover, the article shows that improvements in energy efficiency result in higher quality products and increased processing of oil. A Brazilian refinery with a capacity of 157,000 barrels per day (kbpd) was modernized in 2008 at a cost of US $1.3 billion. As a result, its capacity increased by 17%, from 157 to 189 kbpd. Its complexity index also rose from 3.2 to 6.8, allowing an improvement in the EII (energy intensity index) from 110% to 93%. In relation to the crude oil processed before being modernized, energy consumption fell from 0.75 to 0.52 MBtu (million British thermal units) per barrel processed. These proceedings show that increases in complexity reduce the energy consumed in the production of final products with high value added, such as gasoline, diesel and jet fuel. -- Highlights: → Increased refinery complexity reduces the energy consumption of products of high value added. → Improvements in refinery energy efficiency result in higher quality products and increased processing of oil. → Brazilian refineries were not affected significantly in the 2008 crisis, such as the US refineries, due to many factors. → The EII of Brazilian refining presents real opportunities for gains through changes in the profile of energy consumed.

  11. Opportunities and challenges at the interface between petrochemistry and refinery. The BASF perspective

    Energy Technology Data Exchange (ETDEWEB)

    Blankertz, H.J. [BASF AG, Ludwigshafen (Germany)

    2007-07-01

    The author of the contribution under consideration reports on the BASF perspective according to opportunities and challenges at the interface between petrochemistry and refinery. This contribution is divided into the following chapters: (a) Overview BASF-Group; (b) Overview BASF Petrochemicals; (c) The refinery-chemistry interface; (d) Main focus refineries; (e) Interface challenges and opportunities; (f) What can BASF do for refineries. BASF employs the Verbund concept, a system that combines production with energy needs in an intelligent way. The idea is to reduce of primary energy carriers both in terms of raw materials and for power and steam generation. The authors describes the petrochemicals of BASF AG (Ludwigshafen, Federal Republic of Germany), the raw material development, evolution of thermal steamcracking and crackerproducts. Major feedstock source of the European petrochemical industry are streams out of refineries which can't be used for transportation fuels. The gap between propylene demand and production out of steam crackers has to be closed by propylene out for FCC's. Demand for aromatics (xylenes and benzene, and to a lesser extent toluene) needs to be filled in by aromatics out of refineries. Market drivers for the refining industry are lowering crude costs, growing clean products, increasing capacity and enhancing E and P integration. BASF has various business with the oil und refining industry and provides solutions for oil field chemicals, process chemicals and performance additives. The author explains which kind of products and services BASF provides for refiners.

  12. Fixed-base recycling of contaminated metals in the commercial market

    International Nuclear Information System (INIS)

    Loiselle, V.

    1993-01-01

    Since the establishment of the first fixed-base commercial decontamination facility in 1982, commercial processors have cleaned and recycled more than 120 million lb of metals for productive reuse. This represents enough metal to duplicate the Eiffel Tower eight times. This paper examines the economic conditions that led to the foundation of this industry and the types of decontamination technology that have been successfully employed by the processors

  13. Enhancing Skin Permeation of Biphenylacetic Acid (BPA) Using Salt Formation with Organic and Alkali Metal Bases

    OpenAIRE

    PAWAR, Vijay; NAIK, Prashant; GIRIDHAR, Rajani; YADAV, Mange Ram

    2014-01-01

    In the present study, a series of organic and alkali metal salts of biphenylacetic acid (BPA) have been prepared and evaluated in vitro for percutaneous drug delivery. The physicochemical properties of BPA salts were determined using solubility measurements, DSC, and IR. The DSC thermogram and FTIR spectra confirmed the salt formation with organic and alkali metal bases. Among the series, salts with organic amines (ethanolamine, diethanolamine, triethanol-amine, and diethylamine) had lowered ...

  14. A Study of Complexation-ability of Neutral Schiff Bases to Some Metal Cations

    OpenAIRE

    Topal, Giray; Tümerdem, Recep; Basaran, Ismet; Gümüş, Arzu; Cakir, Umit

    2007-01-01

    The constants of the extraction equilibrium and the distribution for dichloromethane as an organic solvent having low dielectric constant of metal cations with chiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), ohydroxybenzaldehydene-( S)-2-amino-3-phenyl-propanol (II), benzaldehydene-(S)-2- amino-3-methylbutanol (III) with anionic dyes [4-(2-pyridylazo)-resorcinol mono sodium monohydrate (NaPar), sodium picrat (NaPic) and potassium picrat (KPic)] and some heavy metal chlor...

  15. Zr-based conversion coatings for multi-metal substrates

    NARCIS (Netherlands)

    Cerezo Palacios, J.M.

    2015-01-01

    In this PhD work, a new surface treatment based on the application of Zr-based conversion coatings by immersion in a Cu containing Zr-based conversion solution was investigated as a replacement of the traditional phosphating process for the automotive industry. Nowadays most of the cars are made of

  16. The effect of metal artefact reduction on CT-based attenuation correction for PET imaging in the vicinity of metallic hip implants : a phantom study

    NARCIS (Netherlands)

    Harnish, Roy; Prevrhal, Sven; Alavi, Abass; Zaidi, Habib; Lang, Thomas F.

    To determine if metal artefact reduction (MAR) combined with a priori knowledge of prosthesis material composition can be applied to obtain CT-based attenuation maps with sufficient accuracy for quantitative assessment of F-18-fluorodeoxyglucose uptake in lesions near metallic prostheses. A custom

  17. Effect of Microstructure on Hydrogen Diffusion in Weld and API X52 Pipeline Steel Base Metals under Cathodic Protection

    Directory of Open Access Journals (Sweden)

    R. C. Souza

    2017-01-01

    Full Text Available The aim of this research was to evaluate the influence of microstructure on hydrogen permeation of weld and API X52 base metal under cathodic protection. The microstructures analyzed were of the API X52, as received, quenched, and annealed, and the welded zone. The test was performed in base metal (BM, quenched base metal (QBM, annealed base metal (ABM, and weld metal (WM. Hydrogen permeation flows were evaluated using electrochemical tests in a Devanathan cell. The potentiodynamic polarization curves were carried out to evaluate the corrosion resistance of each microstructure. All tests were carried out in synthetic soil solutions NS4 and NS4 + sodium thiosulfate at 25°C. The sodium thiosulfate was used to simulate sulfate reduction bacteria (SRB. Through polarization, assays established that the microstructure does not influence the corrosion resistance. The permeation tests showed that weld metal had lower hydrogen flow than base metal as received, quenched, and annealed.

  18. Polymer waveguide couplers based on metal nanoparticle–polymer nanocomposites

    International Nuclear Information System (INIS)

    Signoretto, M; Suárez, I; Chirvony, V S; Martínez-Pastor, J; Abargues, R; Rodríguez-Cantó, P J

    2015-01-01

    In this work Au nanoparticles (AuNPs) are incorporated into poly(methyl methacrylate) (PMMA) waveguides to develop optical couplers that are compatible with planar organic polymer photonics. A method for growing AuNPs (of 10 to 100 nm in size) inside the commercially available Novolak resist is proposed with the intention of tuning the plasmon resonance and the absorption/scattering efficiencies inside the patterned structures. The refractive index of the MNP–Novolak nanocomposite (MNPs: noble metal nanoparticles) is carefully analysed both experimentally and numerically in order to find the appropriate fabrication conditions (filling factor and growth time) to optimize the scattering cross section at a desired wavelength. Then the nanocomposite is patterned inside a PMMA waveguide to exploit its scattering properties to couple and guide a normal incident laser light beam along the polymer. In this way, light coupling is experimentally demonstrated in a broad wavelength range (404–780 nm). Due to the elliptical shape of the MNPs the nanocomposite demonstrates a birefringence, which enhances the coupling to the TE mode up to efficiencies of around 1%. (paper)

  19. Advanced Gradient Based Optimization Techniques Applied on Sheet Metal Forming

    International Nuclear Information System (INIS)

    Endelt, Benny; Nielsen, Karl Brian

    2005-01-01

    The computational-costs for finite element simulations of general sheet metal forming processes are considerable, especially measured in time. In combination with optimization, the performance of the optimization algorithm is crucial for the overall performance of the system, i.e. the optimization algorithm should gain as much information about the system in each iteration as possible. Least-square formulation of the object function is widely applied for solution of inverse problems, due to the superior performance of this formulation.In this work focus will be on small problems which are defined as problems with less than 1000 design parameters; as the majority of real life optimization and inverse problems, represented in literature, can be characterized as small problems, typically with less than 20 design parameters.We will show that the least square formulation is well suited for two classes of inverse problems; identification of constitutive parameters and process optimization.The scalability and robustness of the approach are illustrated through a number of process optimizations and inverse material characterization problems; tube hydro forming, two step hydro forming, flexible aluminum tubes, inverse identification of material parameters

  20. Simplified Technique for Incorporating a Metal Mesh into Record Bases for Mandibular Implant Overdentures.

    Science.gov (United States)

    Godoy, Antonio; Siegel, Sharon C

    2015-12-01

    Mandibular implant-retained overdentures have become the standard of care for patients with mandibular complete edentulism. As part of the treatment, the mandibular implant-retained overdenture may require a metal mesh framework to be incorporated to strengthen the denture and avoid fracture of the prosthesis. Integrating the metal mesh framework as part of the acrylic record base and wax occlusion rim before the jaw relation procedure will avoid the distortion of the record base and will minimize the chances of processing errors. A simplified method to incorporate the mesh into the record base and occlusion rim is presented in this technique article. © 2015 by the American College of Prosthodontists.