WorldWideScience

Sample records for base bulges thermodynamic

  1. Galactic bulges

    CERN Document Server

    Peletier, Reynier; Gadotti, Dimitri

    2016-01-01

    This book consists of invited reviews on Galactic Bulges written by experts in the field. A central point of the book is that, while in the standard picture of galaxy formation a significant amount of the baryonic mass is expected to reside in classical bulges, the question what is the fraction of galaxies with no classical bulges in the local Universe has remained open. The most spectacular example of a galaxy with no significant classical bulge is the Milky Way. The reviews of this book attempt to clarify the role of the various types of bulges during the mass build-up of galaxies, based on morphology, kinematics, and stellar populations, and connecting their properties at low and high redshifts. The observed properties are compared with the predictions of the theoretical models, accounting for the many physical processes leading to the central mass concentration and their destruction in galaxies. This book serves as an entry point for PhD students and non-specialists and as a reference work for researchers...

  2. Kinetics of bulge bases in small RNAs and the effect of pressure on it.

    Science.gov (United States)

    Kumar, Pradeep; Lehmann, Jean; Libchaber, Albert

    2012-01-01

    Due to their self-catalytic properties, small RNAs with bulge bases are hypothesized to be primordial molecules which could form elementary translation systems. Using molecular dynamics simulations, we study the binding propensity of small RNAs by calculating the free energy barrier corresponding to the looped out conformations of bulge bases, which presumably act as the binding sites for ligands in these small RNAs. We find that base flipping kinetics can proceed at atmospheric pressure but with a very small propensity. Furthermore, the free energy barrier associated with base flipping depends on the stacking with neighboring bases. Next, we studied the base flipping kinetics with pressure. We find that the free energy associated with base looping out increases monotonically as the pressure is increased. Furthermore, we calculate the mean first-passage time of conformational looping out of the bulge base using the diffusion of reaction coordinate associated with the base flipping on the underlying free energy surface. We find that the mean first-passage time associated with bulge looping out increases slowly upon increasing pressures P up to 2000 atm but changes dramatically for P>2000 atm. Finally, we discuss our results in the light of the role of hydration shell of water around RNA. Our results are relevant for the RNA world hypothesis. PMID:22916118

  3. Bulge Formation

    CERN Document Server

    Combes, F

    1999-01-01

    The currently discussed theories of bulge formation are reviewed, including the primordial scenario, where bulges form rapidly and then accrete disks, the secular scenario, where bulges are formed by dynamical evolution of disks through bars and galaxy interactions, and some combinations of both, where formation of bulges and disks are more continuous and interleaved. The various scenarios make specific predictions about the relative masses, angular momenta, colours, metallicities of bulges relative to disks, and the bulge-to-disk ratio as a function of time. Dynamical processes relevant to the formation of bulges (bar instabilities, mergers) are described and tested against observed statistics. Current data suggest a dynamical feedback from gravitational instabilities in bulge and disk formation. It is very difficult to discriminate between the various scenarios from surveys at z=0 only, and observations at high redshift are presently the best hope for large progress.

  4. Polar-bulge galaxies

    CERN Document Server

    Reshetnikov, V P; Mosenkov, A V; Sotnikova, N Ya; Bizyaev, D V

    2015-01-01

    Based on SDSS data, we have selected a sample of nine edge-on spiral galaxies with bulges whose major axes show a high inclination to the disk plane. Such objects are called polar-bulge galaxies. They are similar in their morphology to polar-ring galaxies, but the central objects in them have small size and low luminosity. We have performed a photometric analysis of the galaxies in the g and r bands and determined the main characteristics of their bulges and disks. We show that the disks of such galaxies are typical for the disks of spiral galaxies of late morphological types. The integrated characteristics of their bulges are similar to the parameters of normal bulges. The stellar disks of polar-bulge galaxies often show large-scale warps, which can be explained by their interaction with neighboring galaxies or external accretion from outside.

  5. Development of a thermodynamic data base for selected heavy metals

    International Nuclear Information System (INIS)

    The report on the development of a thermodynamic data base for selected heavy metals covers the description of experimental methods, the thermodynamic model for chromate, the thermodynamic model for dichromate, the thermodynamic model for manganese (II), the thermodynamic model for cobalt, the thermodynamic model for nickel, the thermodynamic model for copper (I), the thermodynamic model for copper(II), the thermodynamic model for mercury (0) and mercury (I), the thermodynamic model for mercury (III), the thermodynamic model for arsenate.

  6. The contrasting structures of mismatched DNA sequences containing looped-out bases (bulges) and multiple mismatches (bubbles).

    Science.gov (United States)

    Bhattacharyya, A; Lilley, D M

    1989-09-12

    We have studied the structure and reactivities of two kinds of mismatched DNA sequences--unopposed bases, or bulges, and multiple mismatched pairs of bases. These were generated in a constant sequence environment, in relatively long DNA fragments, using a technique based on heteroduplex formation between sequences cloned into single-stranded M13 phage. The mismatched sequences were studied from two points of view, viz 1. The mobility of the fragments on gel electrophoresis in polyacrylamide was studied in order to examine possible bending of the DNA due to the presence of the mismatch defect. Such bending would constitute a global effect on the conformation of the molecule. 2. Sequences in and around the mismatches were studied using enzyme and chemical probes of DNA structure. This would reveal more local structural effects of the mismatched sequences. We observed that the structures of the bulges and the multiple mismatches appear to be fundamentally different. The bulged sequences exhibited a large gel retardation, consistent with a significant bending of the DNA at the bulge, and whose magnitude depends on the number of mismatched bases. The larger bulges were sensitive to cleavage by single-strand specific nucleases, and modified by diethyl pyrocarbonate (adenines) or osmium tetroxide (thymines) in a non-uniform way, suggesting that the bulges have a precise structure that leads to exposure of some, but not all, of the bases. In contrast the multiple mismatches ('bubbles') cause very much less bending of the DNA fragment in which they occur, and uniform patterns of chemical reactivity along the length of the mismatched sequences, suggesting a less well defined, and possibly flexible, structure. The precise structure of the bulges suggests that such features may be especially significant for recognition by proteins.

  7. Redshift Evolution in Black Hole-Bulge Relations: Testing CIV-based Black Hole Masses

    CERN Document Server

    Greene, Jenny E; Ludwig, Randi R

    2009-01-01

    We re-examine claims of redshift evolution in black hole-bulge scaling relations based on lensed quasars. In particular, we refine the black hole mass estimates using measurements of Balmer lines from near-infrared spectroscopy obtained with Triplespec at Apache Point Observatory. In support of previous work, we find a large scatter between Balmer and UV line widths, both MgII 2796, 2803 and CIV 1548, 1550. There is tentative evidence that CIII] 1909, despite being a blend of multiple transitions, may correlate well with MgII, although a larger sample is needed for a real calibration. Most importantly, we find no systematic changes in the estimated BH masses for the lensed sample based on Balmer lines, providing additional support to the interpretation that black holes were overly massive compared to their host galaxies at high redshift.

  8. Biomechanical analysis of cancerous and normal cells based on bulge generation in a microfluidic device.

    Science.gov (United States)

    Kim, Yu Chang; Park, Sang-Jin; Park, Je-Kyun

    2008-10-01

    This paper presents a new biomechanical analysis method for discrimination between cancerous and normal cells through compression by poly(dimethylsiloxane) (PDMS) membrane deflection in a microfluidic device. When a cell is compressed, cellular membrane will expand and then small bulges will appear on the peripheral cell membrane beyond the allowable strain. It is well known that the amount of F-actin in cancer cells is less than that of normal cells and bulges occur at the sites where cytoskeleton becomes detached from the membrane bilayer. Accordingly, we have demonstrated the difference of the bulge generation between breast cancer cells (MCF7) and normal cells (MCF10A). After excessive deformation, the bulges generated in MCF7 cells were not evenly distributed on the cell periphery. Contrary to this, the bulges of MCF10A cells showed an even distribution. In addition, the morphologies of bulges of MCF7 and MCF10A cells looked swollen protrusion and tubular protrusion, respectively. Peripheral strains at the moment of the bulge generation were also 72% in MCF7 and 46% in MCF10A. The results show that the bulge generation can be correlated with the cytoskeleton quantity inside the cell, providing the first step of a new biomechanical approach. PMID:18810292

  9. Thermodynamics

    CERN Document Server

    Fermi, Enrico

    1956-01-01

    Indisputably, this is a modern classic of science. Based on a course of lectures delivered by the author at Columbia University, the text is elementary in treatment and remarkable for its clarity and organization. Although it is assumed that the reader is familiar with the fundamental facts of thermometry and calorimetry, no advanced mathematics beyond calculus is assumed.Partial contents: thermodynamic systems, the first law of thermodynamics (application, adiabatic transformations), the second law of thermodynamics (Carnot cycle, absolute thermodynamic temperature, thermal engines), the entr

  10. Thermodynamic data-base for metal fluorides

    International Nuclear Information System (INIS)

    This study is aimed at collecting useful data of thermodynamic properties of various metal fluorides. Many thermodynamic data for metal fluorides are needed for the effective development, but no report of data-base was published. Accordingly, the objective of this report is to rearrange systematically the existing thermodynamic data based on metal fluorides and is to use it as basic data for the development of pyrochemical process. The physicochemical properties of various metal fluorides and metals were collected from literature and such existing data base as HSC code, TAPP code, FACT code, JANAF table, NEA data-base, CRC handbook. As major contents of the thermodynamic data-base, the physicochemical properties such as formation energy, viscosity, density, vapor pressure, etc. were collected. Especially, some phase diagrams of eutectic molten fluorides are plotted and thermodynamic data of liquid metals are also compiled. In the future, the technical report is to be used as basic data for the development of the pyrochemical process which is being carried out as a long-term nuclear R and D project

  11. Thermodynamic data-base for metal fluorides

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Jae Hyung; Lee, Byung Gik; Kang, Young Ho and others

    2001-05-01

    This study is aimed at collecting useful data of thermodynamic properties of various metal fluorides. Many thermodynamic data for metal fluorides are needed for the effective development, but no report of data-base was published. Accordingly, the objective of this report is to rearrange systematically the existing thermodynamic data based on metal fluorides and is to use it as basic data for the development of pyrochemical process. The physicochemical properties of various metal fluorides and metals were collected from literature and such existing data base as HSC code, TAPP code, FACT code, JANAF table, NEA data-base, CRC handbook. As major contents of the thermodynamic data-base, the physicochemical properties such as formation energy, viscosity, density, vapor pressure, etc. were collected. Especially, some phase diagrams of eutectic molten fluorides are plotted and thermodynamic data of liquid metals are also compiled. In the future, the technical report is to be used as basic data for the development of the pyrochemical process which is being carried out as a long-term nuclear R and D project.

  12. Composition of the Galactic bulge

    CERN Document Server

    McWilliam, A; William, Andrew Mc

    2003-01-01

    We present detailed abundance results for 9 Galactic bulge stars in Baade's Window, based on HIRES (R=45,000--60,000) spectra taken with the Keck I telescope. The alpha elements show non-uniform enhancements relative to the Solar neighborhood trends: Mg and Si are enhanced in all our bulge stars by $\\sim$0.5--0.3 dex, showing a slight decrease with increasing [Fe/H]. Oxygen is enhanced in most bulge stars, similar to the Galactic halo, but the [O/Fe] ratios suddenly decline beginning at [Fe/H]=$-$0.5 dex, with a slope consistent with no oxygen production in the bulge for [Fe/H]$\\geq

  13. Black Hole Thermodynamics Based on Unitary Evolutions

    CERN Document Server

    Feng, Yu-Lei

    2015-01-01

    In this paper, we try to construct black hole thermodynamics based on the fact that, the formation and evaporation of a black hole can be described by quantum unitary evolutions. First, we show that the Bekenstein-Hawking entropy $S_{BH}$ cannot be a Boltzmann or thermal entropy. To confirm this statement, we show that the original black hole's "first law" cannot be treated as the first law of thermodynamics formally, due to some missing metric perturbations caused by matter. Then, by including those (quantum) metric perturbations, we show that the black hole formation and evaporation can be described in a unitary manner effectively, through a quantum channel between the exterior and interior of the event horizon. In this way, the paradoxes of information loss and firewall can be resolved effectively. Finally, we show that black hole thermodynamics can be constructed in an ordinary way, by constructing statistical mechanics.

  14. Black hole thermodynamics based on unitary evolutions

    Science.gov (United States)

    Feng, Yu-Lei; Chen, Yi-Xin

    2015-10-01

    In this paper, we try to construct black hole thermodynamics based on the fact that the formation and evaporation of a black hole can be described by quantum unitary evolutions. First, we show that the Bekenstein-Hawking entropy SBH may not be a Boltzmann or thermal entropy. To confirm this statement, we show that the original black hole's ‘first law’ may not simply be treated as the first law of thermodynamics formally, due to some missing metric perturbations caused by matter. Then, by including those (quantum) metric perturbations, we show that the black hole formation and evaporation can be described effectively in a unitary manner, through a quantum channel between the exterior and interior of the event horizon. In this way, the paradoxes of information loss and firewall can be resolved effectively. Finally, we show that black hole thermodynamics can be constructed in an ordinary way, by constructing statistical mechanics.

  15. Fracture prediction in hydraulic bulging of AISI 304 austenitic steel sheets based on a modified ductile fracture criterion

    Science.gov (United States)

    Xu, Y.; Song, H. W.; Zhang, S. H.; Cheng, M.

    2011-08-01

    The demand for weight reduction in modern vehicle construction has resulted in an increase in the application of hydroforming processes for the manufacture of automotive lightweight components. This trend led to the research of evaluation on formability of the sheet or tube hydroforming to be noted, particularly the prediction of fracture. In this study, a new proposed approach based on damage theory for fracture prediction considering the deformation history was introduced. And the modified ductile fracture criterion was applied to predict the failure for hydraulic bulging of AISI 304 austenitic steel sheets. The material parameters in terms of the function of strain rate in the failure criterion were determined from the equivalent fracture strains corresponding tensile tests under different stress conditions. Then, in the finite element simulation the effect of strain rates and their distribution as well during practical sheet metal forming process was considered. The hydraulic bulging tests were carried out to identify the fracture behavior predicted from FE analysis. A comparison between the prediction and experimental results showed that the proposed approach with a modified ductile fracture criteria can give better fracture predictions than traditional ways.

  16. Distances of the bulge globular clusters Terzan 5, Liller 1, UKS 1 and Terzan 4 based on HST NICMOS photometry

    CERN Document Server

    Ortolani, S; Bica, E; Zoccali, M; Renzini, A

    2007-01-01

    A large number of pulsars and X-rays sources are detected in globular clusters. To understand the structure and content of these clusters, accurate distances are required. We derive the distances of Terzan 5, Liller 1 and UKS 1 using as a reference a recent distance determination of NGC 6528, based on HST/NICMOS and NTT/SOFI infrared photometry. The distance of the metal-poor cluster Terzan 4 was derived from a comparison with M92 in NICMOS bands. Distances of the metal-rich clusters are obtained by comparison of the Horizontal Branch (HB) level of the clusters, relative to the reddening line passing through the HB of NGC 6528. We use methods based on NICMOS bands and transformations to J and H magnitudes with different assumptions. Liller~1 and Terzan~4 are found to be at the central bulge distance, UKS~1 is beyond the Galactic center, while Terzan 5 is closer to the Sun than the other four clusters. The distance of Terzan 5 is of paramount importance, given the impact of its population of 21 pulsars, which ...

  17. Thermodynamics

    CERN Document Server

    Solanki, Arun

    2008-01-01

    The comprehension of the laws which govern any material system is greatly facilitated by considering the energy and entropy of the system in various states of which it is capable. As in the case of simply mechanics systems, the performance of mechanical work, the function which expresses the capability of the system for this kind of action also plays the leading part in the theory of equilibrium. The present book is written to explain the basic concepts, theories and equilibrium concerning thermodynamics of fluids and stationary systems, geometrical representation of thermodynamic properties

  18. Globular Clusters in the Galactic Bulge

    Science.gov (United States)

    Bica, E.; Ortolani, S.; Barbuy, B.

    2016-06-01

    A view of the Galactic bulge by means of their globular clusters is fundamental for a deep understanding of its formation and evolution. Connections between the globular cluster and field star properties in terms of kinematics, orbits, chemical abundances, and ages should shed light on different stellar population components. Based on spatial distribution and metallicity, we define a probable best list of bulge clusters, containing 43 entries. Future work on newly discovered objects, mostly from the VVV survey, is suggested. These candidates might alleviate the issue of missing clusters on the far side of the bulge. We discuss the reddening law affecting the cluster distances towards the centre of the Galaxy, and conclude that the most suitable total-to-selective absorption value appears to be R V=3.2, in agreement with recent analyses. An update of elemental abundances for bulge clusters is provided.

  19. Development of a thermodynamic data base for selected heavy metals; Entwicklung einer thermodynamischen Datenbasis fuer ausgewaehlte Schwermetalle

    Energy Technology Data Exchange (ETDEWEB)

    Hageman, Sven; Scharge, Tina; Willms, Thomas

    2015-07-15

    The report on the development of a thermodynamic data base for selected heavy metals covers the description of experimental methods, the thermodynamic model for chromate, the thermodynamic model for dichromate, the thermodynamic model for manganese (II), the thermodynamic model for cobalt, the thermodynamic model for nickel, the thermodynamic model for copper (I), the thermodynamic model for copper(II), the thermodynamic model for mercury (0) and mercury (I), the thermodynamic model for mercury (III), the thermodynamic model for arsenate.

  20. Modern Thermodynamics Based on the Extended Carnot Theorem

    CERN Document Server

    Wang, Jitao

    2012-01-01

    "Modern Thermodynamics- Based on the Extended Carnot Theorem" provides comprehensive definitions and mathematical expressions of both classical and modern thermodynamics. The goal is to develop the fundamental theory on an extended Carnot theorem without incorporating any extraneous assumptions. In particular, it offers a fundamental thermodynamic and calculational methodology for the synthesis of low-pressure diamonds. It also discusses many "abnormal phenomena", such as spiral reactions, cyclic reactions, chemical oscillations, low-pressure carat-size diamond growth, biological systems, and more. The book is intended for chemists and physicists working in thermodynamics, chemical thermodynamics, phase diagrams, biochemistry and complex systems, as well as graduate students in these fields. Jitao Wang is a professor emeritus at Fudan University, Shanghai, China.

  1. Secular- and merger-built bulges in barred galaxies

    CERN Document Server

    Mendez-Abreu, J; Corsini, E M; Aguerri, J A L

    2014-01-01

    (Abridged) We study the incidence, as well as the nature, of composite bulges in a sample of 10 face-on barred galaxies to constrain the formation and evolutionary processes of the central regions of disk galaxies. We analyze the morphological, photometric, and kinematic properties of each bulge. Then, by using a case-by-case analysis we identify composite bulges and classify every component into a classical or pseudobulge. In addition, bar-related boxy/peanut (B/P) structures were also identified and characterised. We find only three galaxies hosting a single-component bulge (two pseudobulges and one classical bulge). We find evidence of composite bulges coming in two main types based on their formation: secular-built and merger- and secular-built. We call secular-built to composite bulges made of entirely by structures associated with secular processes such as pseudo bulges, central disks, or B/P bulges. We find four composite bulges of this kind in our sample. On the other hand, merger- and secular-built b...

  2. Diagnostics of gas turbines based on changes in thermodynamics parameters

    Directory of Open Access Journals (Sweden)

    Hocko Marián

    2016-01-01

    Full Text Available This article is focused on solving the problems of determining the true state of gas turbine based on measured changes in thermodynamic parameters. Dependence between the real individual parts for gas turbines and changing the thermodynamic parameters were experimentally verified and confirmed on a small jet engine MPM-20 in the laboratory of the Department of Aviation Engineering at Technical University in Košice. The results of experiments confirm that the wear and tear of basic parts for gas turbines (turbo-compressor engines to effect the change of thermodynamic parameters of the engine.

  3. Pyroelectric Energy Harvesting: With Thermodynamic-Based Cycles

    Directory of Open Access Journals (Sweden)

    Saber Mohammadi

    2012-01-01

    Full Text Available This work deals with energy harvesting from temperature variations using ferroelectric materials as a microgenerator. The previous researches show that direct pyroelectric energy harvesting is not effective, whereas thermodynamic-based cycles give higher energy. Also, at different temperatures some thermodynamic cycles exhibit different behaviours. In this paper pyroelectric energy harvesting using Lenoir and Ericsson thermodynamic cycles has been studied numerically and the two cycles were compared with each other. The material used is the PMN-25 PT single crystal that is a very interesting material in the framework of energy harvesting and sensor applications.

  4. Diagnostics of gas turbines based on changes in thermodynamics parameters

    Science.gov (United States)

    Hocko, Marián; Klimko, Marek

    2016-03-01

    This article is focused on solving the problems of determining the true state of gas turbine based on measured changes in thermodynamic parameters. Dependence between the real individual parts for gas turbines and changing the thermodynamic parameters were experimentally verified and confirmed on a small jet engine MPM-20 in the laboratory of the Department of Aviation Engineering at Technical University in Košice. The results of experiments confirm that the wear and tear of basic parts for gas turbines (turbo-compressor engines) to effect the change of thermodynamic parameters of the engine.

  5. Modern thermodynamics - New concepts based on the second law of thermodynamics

    Institute of Scientific and Technical Information of China (English)

    Jitao Wang

    2009-01-01

    Thermodynamics is a core part of science.Nearly all scientists should have a basic knowledge of thermodynamics.Thermodynamics is a science of development,and is a viewpoint of scientific development in natural sciences.Achievement of thermodynamics has influence not only on natural sciences,but also on social sciences and philosophy.Fundamental concepts and definitions are very important for any discipline of science,so what is classical thermodynamics and what is modern thermodynamics have become the key points of puzzledom in thermodynamics.In this paper,after clarification of fundamental concept in thermodynamics,a complete basic modern classification of thermodynamics is naturally obtained.It is suggested that extended Carnot theorem and dissipation decrease theorem,together with the laws of thermodynamics,are the most fundamental theorems in thermodynamics discipline.Nondissipative thermodynamics is a new field besides equilibrium thermodynamics belonging to the equal part of the second law of thermodynamics.

  6. The formation of galaxy bulges: Spectrophotometric constraints

    Science.gov (United States)

    Prugniel, Ph.; Maubon, G.; Simien, F.

    2001-01-01

    (B)-type bulges and deviate from the Mg2, vs. sigma0, relation of elliptical galaxies. Based on observations collected at the Observatoire de Haute-Provence. Table 3 is presented in electronic form only at the CDS. Tables 1 and 2 are also available form at the CDS, Strasbourg, via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/366/68

  7. First law-based thermodynamic analysis on Kalina cycle

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Based on the first law of thermodynamics,and adopting the Peng-Robinson equation (P-R equation) as the basic equation for the properties of ammonia-water mixtures,a thermodynamic analysis on a single-stage distillation Kalina cycle is presented.A program to calculate the thermodynamic properties of ammoniawater mixtures,and that for calculating the performance of Kalina cycles,were developed,with which the heatwork conversion particulars of Kalina cycles were theoretically calculated.The influences on the cycle performance of key parameters,such as the pressure and temperature at the inlet of the turbine,the back pressure of the turbine,the concentration of the working solution,the concentration of the basic solution and the cycle multiplication ratio,were analyzed.

  8. Bulge Microlensing Optical Depth from EROS 2 observations

    CERN Document Server

    Afonso, C; Alard, C; Andersen, J; Ansari, R; Aubourg, E; Bareyre, P; Bauer, F; Beaulieu, J P; Blanc, G

    2003-01-01

    We present a measurement of the microlensing optical depth toward the Galactic bulge based on the analysis of 15 contiguous1 square degrees fields centered on (l=2.5 deg, b=-4.0 deg) and containing 1.42 million clump-giant stars (belonging to the extended clump area) monitored during almost three bulge seasons by EROS (Experience de Recherche d'Objets Sombres). We find a microlensing optical depth towards the bulge tau_bulge=0.94 +/- 0.29 10^-6 averaged over all fields, based on 16 microlensing events with clump giants as sources. This value is substantially below several other determinations by the MACHO and OGLE groups and is more in agreement with what is expected from axisymmetric and non-axisymmetric bulge models.

  9. Structural requirements for trans activation of human immunodeficiency virus type 1 long terminal repeat-directed gene expression by tat: importance of base pairing, loop sequence, and bulges in the tat-responsive sequence.

    OpenAIRE

    Roy, S.; Parkin, N T; Rosen, C; Itovitch, J; Sonenberg, N

    1990-01-01

    In order to elucidate the molecular mechanisms of action of the tat-responsive sequence, mutational analysis of the tat-responsive sequence was carried out. The most critical region comprised nucleotides +18 to +44 and included the 3-nucleotide bulge at positions +23 to +25, the loop sequence, and an intact stem. In addition, base pairing up to nucleotide +52 was required for the full magnitude of the trans-activation response. Single-nucleotide bulges at positions +5 to +17 were dispensable....

  10. The Chandra Galactic Bulge Survey

    NARCIS (Netherlands)

    Hynes, Robert I.; Jonker, P.G.; Bassa, C. G.; Dieball, A.; Greiss, S.; Maccarone, T. J.; Nelemans, G.; Steeghs, D.; Torres, M. A. P.; Britt, C. T.; Clem, J. L.; Gossen, L.; Grindlay, J. E.; Groot, P.J.; Kuiper, L.; Kuulkers, E.; Mendez, M.; Mikles, V. J.; Ratti, E. M.; Rea, N.; van Haaften, L.; Wijnands, R.; in't Zand, J. J. M.

    2011-01-01

    The Chandra Galactic Bulge Survey (CGBS) is a shallow but wide survey of two approximately 6x1 degree strips of the Galactic Bulge about a degree above and below the plane. The survey by design targets regions where extinction and crowding are manageable and optical counterparts are accessible to de

  11. The Chandra Galactic Bulge Survey

    NARCIS (Netherlands)

    Hynes, Robert I.; Jonker, P. G.; Bassa, C. G.; Nelemans, G.; Steeghs, D.; Torres, M. A. P.; Maccarone, T. J.; Greiss, S.; Clem, J.; Dieball, A.; Mikles, V. J.; Britt, C. T.; Gossen, L.; Collazzi, A. C.; Wijnands, R.; In't Zand, J. J. M.; Mendez, M.; Rea, N.; Kuulkers, E.; Ratti, E. M.; van Haaften, L. M.; Heinke, C.; Ozel, F.; Groot, P. J.; Verbunt, F.

    2012-01-01

    The Chandra Galactic Bulge Survey (GBS) is a shallow but wide survey of two approximately 6x1 degree strips of the Galactic Bulge about a degree above and below the plane. The survey by design targets regions where extinction and crowding are manageable and optical counterparts are accessible to det

  12. Thermodynamics-based models of transcriptional regulation with gene sequence.

    Science.gov (United States)

    Wang, Shuqiang; Shen, Yanyan; Hu, Jinxing

    2015-12-01

    Quantitative models of gene regulatory activity have the potential to improve our mechanistic understanding of transcriptional regulation. However, the few models available today have been based on simplistic assumptions about the sequences being modeled or heuristic approximations of the underlying regulatory mechanisms. In this work, we have developed a thermodynamics-based model to predict gene expression driven by any DNA sequence. The proposed model relies on a continuous time, differential equation description of transcriptional dynamics. The sequence features of the promoter are exploited to derive the binding affinity which is derived based on statistical molecular thermodynamics. Experimental results show that the proposed model can effectively identify the activity levels of transcription factors and the regulatory parameters. Comparing with the previous models, the proposed model can reveal more biological sense.

  13. Energy conservation technologies based on thermodynamic principles

    Energy Technology Data Exchange (ETDEWEB)

    Hirata, Masaru [Shibaura Institute of Technology of Technology, Tokyo (Japan)

    1996-12-31

    In order to reduce CO{sub 2} emission to prevent global warming, the most promising way for electric generation in the Northeast Asia is to introduce cogeneration and {open_quotes}repowering{close_quotes} technologies based on high temperature gas turbines fueled by natural gas. Especially the old type coal burning boiler-steam turbine plants should be retrofit by introducing gas turbines to become highly efficient combined cycle. Same technologies should be applied to the old garbage incineration plants and/or even to the nuclear power plants. The exhaust heat or steam should become much increased and it should be utilized as the process heat for industries or heat supply as the distinct heating or cooling for residential area. This paper introduces a brief survey of these new technologies.

  14. The Bulge of M31

    CERN Document Server

    Mould, Jeremy

    2013-01-01

    Bulges are not just elliptical subgalaxies situated in the centers of large spirals. It might seem that way from their ages and chemistry, but bulge kinematics have been known to be different since the first long slit spectra were obtained. M31 presents the best opportunity to investigate all the issues of the stellar populations of bulges. This review collects the array of probing data that has been accumulated in the last decade. But the intriguing question `how did it form like this ?' remains.

  15. 基于高温铸坯黏弹塑性的坯壳动态鼓肚研究%Research on Dynamic Bulging of Continuous Casting Slab Based on Elasto-viscoplastic Behavior of Metal at Elevated Temperature

    Institute of Scientific and Technical Information of China (English)

    韩培培; 任廷志

    2015-01-01

    基于高温铸坯材料黏弹塑性本构方程,建立了坯壳动态鼓肚数学模型。根据坯壳不同的初始状态与变形历史确定了两种边界条件。利用模型计算坯壳鼓肚变形,并与实测数据进行对比,验证了理论解的正确性以及模型的有效性。根据鞍钢工业板坯连铸机的设备工艺参数,分别计算了刚出结晶器的坯壳和远离结晶器的坯壳的鼓肚变形曲线,以及坯壳在固液交界面处的应变与应变速率。分析了铸坯坯壳在铸机扇形段内的鼓肚变形与应变变化规律,并讨论了辊间距、拉坯速度对坯壳鼓肚变形的影响。%Based on elasto-viscoplastic behavior of metal at elevated temperature,a mathematical model of dynamic bulging with the movement of the slab between two rolls was developed.According to different initial conditions and the deformation history of a solidified shell,two groups of boundary conditions were presented.Then,in order to check the validity of this mathematical model,the calcu-lated bulging profiles were compared with the measurements of bulging intensity and profiles on actual continuous casters.Then according to the casting parameters on different segments of an industrial caster in Ansteel company,the bulging of the solidified shell near mould and far from mould were ex-posed separately.In addition,the bulging features were analyzed including the bulging deflection,the bending moment acting on the solidified shell,the strain and the strain rate at the solid-liquid interface of the solidified shell.Finally,the bulging in a segment of the caster was calculated,and then the in-fluences of the casting parameters including roll pitch and casting speed were analyzed .

  16. Stellar populations of classical and pseudo-bulges for a sample of isolated spiral galaxies

    CERN Document Server

    Zhao, Yinghe

    2011-01-01

    In this paper we present the stellar population synthesis results for a sample of 75 bulges in isolated spiral Sb-Sc galaxies, using the spectroscopic data from the Sloan Digital Sky Survey and the STARLIGHT code. We find that both pseudo-bulges and classical bulges in our sample are predominantly composed of old stellar populations, with mean mass-weighted stellar age around 10 Gyr. While the stellar population of pseudo-bulges is, in general, younger than that of classical bulges, the difference is not significant, which indicates that it is hard to distinguish pseudo-bulges from classical bulges, at least for these isolated galaxies, only based on their stellar populations. Pseudo-bulges have star formation activities with relatively longer timescale than classical bulges, indicating that secular evolution is more important in this kind of systems. Our results also show that pseudo-bulges have a lower stellar velocity dispersion than their classical counterparts, which suggests that classical bulges are mo...

  17. Towards the big picture of the Milky Way bulge

    Directory of Open Access Journals (Sweden)

    Gonzalez O.A.

    2012-02-01

    Full Text Available Evidence has been growing in the last few years that the Bulge is very complex, with maybe two or more components partially overlapping in space, kinematics and metallicity. An extensive mapping of these properties is necessary to disentangle them. I present our results based on α-elements abundances for a total of 650 RGB stars in 4 fields along the major and minor axis of the Bulge. Results point towards a spatial homogeneity of α-element enhancement in the metal-poor regime and a population of alpha-poor metal-rich stars which disappears at high latitudes (b = −12. Bulge metal-poor alpha enhancement is also indistinguishable from the one of the thick disk. Further constrains on Bulge populations are provided by the Vista Variables in the Via Lactea survey (VVV from which I present our recent results in extinction, structure and photometric metallicities.

  18. Conformational thermodynamics of biomolecular complexes: The histogram-based method

    Science.gov (United States)

    Das, Amit; Sikdar, Samapan; Ghosh, Mahua; Chakrabarti, J.

    2015-09-01

    Conformational changes in biomacromolecules govern majority of biological processes. Complete characterization of conformational contributions to thermodynamics of complexation of biomacromolecules has been challenging. Although, advances in NMR relaxation experiments and several computational studies have revealed important aspects of conformational entropy changes, efficient and large-scale estimations still remain an intriguing facet. Recent histogram-based method (HBM) offers a simple yet rigorous route to estimate both conformational entropy and free energy changes from same set of histograms in an efficient manner. The HBM utilizes the power of histograms which can be generated as accurately as desired from an arbitrarily large sample space from atomistic simulation trajectories. Here we discuss some recent applications of the HBM, using dihedral angles of amino acid residues as conformational variables, which provide good measure of conformational thermodynamics of several protein-peptide complexes, obtained from NMR, metal-ion binding to an important metalloprotein, interfacial changes in protein-protein complex and insight to protein function, coupled with conformational changes. We conclude the paper with a few future directions worth pursuing.

  19. Thermodynamic and structural basis for electrochemical response of Cu–Zr based metallic glass

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chunzhi, E-mail: mse201109@126.com; Qiu, Nannan; Kong, Lingliang; Yang, Xiaodan; Li, Huiping

    2015-10-05

    Highlights: • Thermodynamic and structural basis for electrochemical response were proposed. • La improves the corrosion resistance by inhibition of the selective dissolution. • Corrosion of the MG responses well with thermodynamic and structural parameters. - Abstract: Cu–Zr based metallic glasses were prepared by hyperquenching strategy to explore the thermodynamic and structural basis for electrochemical response. The thermodynamic parameters and the local atomic structure were obtained. Corrosion resistance in seawater was investigated via potentiodynamic polarization curve. The results indicate that increasing thermodynamic parameter values improves the corrosion resistance. The topological instability represented by the nearest neighbor atomic distance yields same tendency as the corrosion resistance with La addition.

  20. Stability of black holes based on horizon thermodynamics

    Directory of Open Access Journals (Sweden)

    Meng-Sen Ma

    2015-12-01

    Full Text Available On the basis of horizon thermodynamics we study the thermodynamic stability of black holes constructed in general relativity and Gauss–Bonnet gravity. In the framework of horizon thermodynamics there are only five thermodynamic variables E, P, V, T, S. It is not necessary to consider concrete matter fields, which may contribute to the pressure of black hole thermodynamic system. In non-vacuum cases, we can derive the equation of state, P=P(V,T. According to the requirements of stable equilibrium in conventional thermodynamics, we start from these thermodynamic variables to calculate the heat capacity at constant pressure and Gibbs free energy and analyze the local and global thermodynamic stability of black holes. It is shown that P>0 is the necessary condition for black holes in general relativity to be thermodynamically stable, however this condition cannot be satisfied by many black holes in general relativity. For black hole in Gauss–Bonnet gravity negative pressure can be feasible, but only local stable black hole exists in this case.

  1. Stability of black holes based on horizon thermodynamics

    CERN Document Server

    Ma, Meng-Sen

    2015-01-01

    On the basis of horizon thermodynamics we study the thermodynamic stability of black holes constructed in general relativity and Gauss-Bonnet gravity. In the framework of horizon thermodynamics there are only five thermodynamic variables $E,P,V,T,S$. It is not necessary to consider concrete matter fields, which may contribute to the pressure of black hole thermodynamic system. In non-vacuum cases, we can derive the equation of state, $P=P(V,T)$. According to the requirements of stable equilibrium in conventional thermodynamics, we start from these thermodynamic variables to calculate the heat capacity at constant pressure and Gibbs free energy and analyze the local and global thermodynamic stability of black holes. It is shown that $P>0$ is the necessary condition for black holes in general relativity to be thermodynamically stable, however this condition cannot be satisfied by many black holes in general relativity. For black hole in Gauss-Bonnet gravity negative pressure can be feasible, but only local stab...

  2. Chemistry of the Galactic Bulge: New Results

    Science.gov (United States)

    Zoccali, Manuela; Hill, Vanessa; Barbuy, Beatriz; Lecureur, Aurelie; Minniti, Dante; Renzini, Alvio; Gonzalez, Oscar; Gómez, Ana; Ortolani, Sergio

    2009-06-01

    VLT-FLAMES observations provide by far the largest sample of high dispersion spectra of Bulge red giants available. Five years of work on these 900 spectra have yielded the abundances of different elements in the Milky Way Bulge, and new results on its formation. The results so far include the Bulge metallicity distribution, the Bulge metallicity gradient, the metallicity dependence on kinematics, the history of enrichment with alpha-elements, as well as the lithium abundance. The evidence collected on Milky Way Bulge chemical enrichment supports a rapid early formation scenario, and the metallicity gradient argues against formation via secular bar evolution.

  3. Discovery in the Galactic Bulge

    Science.gov (United States)

    Kohler, Susanna

    2015-11-01

    In our efforts to map our galaxys structure, one region has remained very difficult to probe: the galactic center. A new survey, however, uses infrared light to peer through the gas and dust in the galactic plane, searching for variable stars in the bulge of the galaxy. This study has discovered a population of very young stars in a thin disk in the galactic center, providing clues to the star formation history of the Milky Way over the last 100 million years.Obscured CenterThe center of the Milky Way is dominated by a region known as the galactic bulge. Efforts to better understand this region in particular, its star formation history have been hindered by the stars, gas, and dust of the galactic disk, which prevent us from viewing the galactic bulge at low latitudes in visible light.The positions of the 35 classical Cepheids discovered in VVV data, projected onto an image of the galactic plane. Click for a better look! The survey area is bounded by the blue lines, and the galactic bar is marked with a red curve. The bottom panel shows the position of the Cepheids overlaid on the VVV bulge extinction map. [Dkny et al. 2015]Infrared light, however, can be used to probe deeper through the dust than visible-light searches. A new survey called VISTA Variables in the Via Lactea (VVV) uses the VISTA telescope in Chile to search, in infrared, for variable stars in the inner part of the galaxy. The VVV survey area spans the Milky Way bulge and an adjacent section of the mid-plane where star formation activity is high.Led by Istvn Dkny, a researcher at the Millennium Institute of Astrophysics and the Pontifical Catholic University of Chile, a team has now used VVV data to specifically identify classical Cepheid variable stars in the bulge. Why? Cepheids are pulsating stars with a very useful relation between their periods and luminosities that allows them to be used as distance indicators. Moreover, classical Cepheids are indicators of young stellar populations which can

  4. FORMATION AND EVOLUTION OF THE GALACTIC BULGE

    Directory of Open Access Journals (Sweden)

    M. Zoccali

    2009-01-01

    Full Text Available Despite its importance as the only galactic spheroid fully resolved in stars, our knowledge of the Galacticbulge has been historically quite poor. This was mainly due to the stellar crowding, to the heavy interstellar absorption in the plane, and to the foreground disk contamination. However, in the last few years, with the use of near IR detectors, 8 meter class (or space based telescopes, and the advent of multi-object spectrographs, we have learnt how to minimize the above e ects. This paper reviews the basic properties (structural parameters, age, chemical content of the Galactic bulge, as determined in the last 4{5 years.

  5. Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review

    Directory of Open Access Journals (Sweden)

    Min Zhu

    2013-10-01

    Full Text Available Mg-based hydrides are one of the most promising hydrogen storage materials because of their relatively high storage capacity, abundance, and low cost. However, slow kinetics and stable thermodynamics hinder their practical application. In contrast to the substantial progress in the enhancement of the hydrogenation/dehydrogenation kinetics, thermodynamic tuning is still a great challenge for Mg-based alloys. At present, the main strategies to alter the thermodynamics of Mg/MgH2 are alloying, nanostructuring, and changing the reaction pathway. Using these approaches, thermodynamic tuning has been achieved to some extent, but it is still far from that required for practical application. In this article, we summarize the advantages and disadvantages of these strategies. Based on the current progress, finding reversible systems with high hydrogen capacity and effectively tailored reaction enthalpy offers a promising route for tuning the thermodynamics of Mg-based hydrogen storage alloys.

  6. Component Thermodynamical Selection Based Gene Expression Programming for Function Finding

    OpenAIRE

    Zhaolu Guo; Zhijian Wu; Xiaojian Dong; Kejun Zhang; Shenwen Wang; Yuanxiang Li

    2014-01-01

    Gene expression programming (GEP), improved genetic programming (GP), has become a popular tool for data mining. However, like other evolutionary algorithms, it tends to suffer from premature convergence and slow convergence rate when solving complex problems. In this paper, we propose an enhanced GEP algorithm, called CTSGEP, which is inspired by the principle of minimal free energy in thermodynamics. In CTSGEP, it employs a component thermodynamical selection (CTS) operator to quantitativel...

  7. Young stars in an old bulge: a natural outcome of internal evolution in the Milky Way

    CERN Document Server

    Ness, M; Bensby, T; Feltzing, S; Roskar, R; Cole, D R; Johnson, J A; Freeman, K

    2014-01-01

    The center of our disk galaxy, the Milky Way, is dominated by a boxy/peanut-shaped bulge. Numerous studies of the bulge based on stellar photometry have concluded that the bulge stars are exclusively old. The perceived lack of young stars in the bulge strongly constrains its likely formation scenarios, providing evidence that the bulge is a unique population that formed early and separately from the disk. However, recent studies of individual bulge stars using the microlensing technique have reported that they span a range of ages, emphasizing that the bulge may not be a monolithic structure. In this letter we demonstrate that the presence of young stars that are located predominantly near the plane is expected for a bulge that has formed from the disk via dynamical instabilities. Using an N-body+SPH simulation of a disk galaxy forming out of gas cooling inside a dark matter halo and forming stars, we find a qualitative agreement between our model and the observations of young metal-rich stars in the bulge. W...

  8. Thermodynamical properties of Zr-based bulk metallic glasses

    Science.gov (United States)

    Gaur, Jitendra; Mishra, R. K.

    2015-11-01

    The temperature dependence of Gibb's free energy difference (ΔG), entropy difference (ΔS) and enthalpy difference (ΔH) between the undercooled melt and the corresponding equilibrium solid phases of bulk metallic glass (BMG) forming melts has been proved to be very useful in the study of their thermodynamical behavior. The present study is made by calculating ΔG, ΔS and ΔH in the entire temperature range Tm (melting temperature) to Tg (glass transition temperature) for three Zr-based samples of BMGs: Zr57Cu15.4Ni12.6Al10Nb5, Zr41.2Ti13.8Ni10Cu12.5Be22.5 and Zr58.5Cu15.6Ni12.8Al10.3Nb2.8. The study is made on the basis of Taylor's series expansion and a comparative study is also performed between the present result and the result obtained in the framework of expansions proposed by earlier workers, and also with the experimental results. An attempt has also been made to study the glass forming ability for BMGs.

  9. Clumpy Disc and Bulge Formation

    CERN Document Server

    Perez, J; Tissera, P; Michel-Dansac, L

    2013-01-01

    We present a set of hydrodynamical/Nbody controlled simulations of isolated gas rich galaxies that self-consistently include SN feedback and a detailed chemical evolution model, both tested in cosmological simulations. The initial conditions are motivated by the observed star forming galaxies at z ~ 2-3. We find that the presence of a multiphase interstellar media in our models promotes the growth of disc instability favouring the formation of clumps which in general, are not easily disrupted on timescales compared to the migration time. We show that stellar clumps migrate towards the central region and contribute to form a classical-like bulge with a Sersic index, n > 2. Our physically-motivated Supernova feedback has a mild influence on clump survival and evolution, partially limiting the mass growth of clumps as the energy released per Supernova event is increased, with the consequent flattening of the bulge profile. This regulation does not prevent the building of a classical-like bulge even for the most ...

  10. Is neoclassical microeconomics formally valid? An approach based on an analogy with equilibrium thermodynamics

    Energy Technology Data Exchange (ETDEWEB)

    Sousa, Tania; Domingos, Tiago [Environment and Energy Section, DEM, Instituto Superior Tecnico, Avenida Rovisco Pais, 1, 1049-001 Lisboa (Portugal)

    2006-06-10

    The relation between Thermodynamics and Economics is a paramount issue in Ecological Economics. Two different levels can be distinguished when discussing it: formal and substantive. At the formal level, a mathematical framework is used to describe both thermodynamic and economic systems. At the substantive level, thermodynamic laws are applied to economic processes. In Ecological Economics, there is a widespread claim that neoclassical economics has the same mathematical formulation as classical mechanics and is therefore fundamentally flawed because: (1) utility does not obey a conservation law as energy does; (2) an equilibrium theory cannot be used to study irreversible processes. Here, we show that neoclassical economics is based on a wrong formulation of classical mechanics, being in fact formally analogous to equilibrium thermodynamics. The similarity between both formalisms, namely that they are both cases of constrained optimisation, is easily perceived when thermodynamics is looked upon using the Tisza-Callen axiomatisation. In this paper, we take the formal analogy between equilibrium thermodynamics and economic systems far enough to answer the formal criticisms, proving that the formalism of neoclassical economics has irreversibility embedded in it. However, the formal similarity between equilibrium thermodynamics and neoclassical microeconomics does not mean that economic models are in accordance with mass, energy and entropy balance equations. In fact, neoclassical theory suffers from flaws in the substantive integration with thermodynamic laws as has already been fully demonstrated by valuable work done by ecological economists in this field. (author)

  11. Stellar Populations of Late-Type Bulges at z=1 in the HUDF

    CERN Document Server

    Hathi, N P; Pasquali, A; Malhotra, S; Rhoads, J E; Pirzkal, N; Windhorst, R A; Xu, C

    2008-01-01

    We take advantage of the exceptional depth of the Hubble Ultra Deep Field (HUDF) images and the deep GRism ACS Program for Extragalactic Science (GRAPES) grism spectroscopy to explore the stellar populations of 34 bulges belonging to late-type galaxies at z=0.8-1.3. We selected these galaxies based on the presence of a noticeable Balmer break (at 4000 A) in their GRAPES spectra, and by visual inspection of the HUDF images. The narrow extraction of these GRAPES spectra around the galaxy center enable us to study the spectrum of the bulges in these late-type galaxies. The 4000 A break in the bulges spectra allows us to estimate the bulges redshifts and stellar ages. We first used the HUDF images to measure bulges color and Sersic index, and then we analyze the bulges spectra by fitting stellar population models. Our results show that, (1) the average age of late-type bulges in our sample is ~1.3 Gyr and stellar masses are in the range of log(M)=6.5-10 solar, (2) late-type bulges are younger and less massive com...

  12. Properties of Disks and Bulges of Spiral and Lenticular Galaxies in the Sloan Digital Sky Survey

    CERN Document Server

    Oohama, N; Fukugita, M; Yasuda, N; Nakamura, O

    2009-01-01

    A bulge-disk decomposition is made for 737 spiral and lenticular galaxies drawn from a SDSS galaxy sample for which morphological types are estimated. We carry out the bulge-disk decomposition using the growth curve fitting method. It is found that bulge properties, effective radius, effective surface brightness, and also absolute magnitude, change systematically with the morphological sequence; from early to late types, the size becomes somewhat larger, and surface brightness and luminosity fainter. In contrast disks are nearly universal, their properties remaining similar among disk galaxies irrespective of detailed morphologies from S0 to Sc. While these tendencies were often discussed in previous studies, the present study confirms them based on a large homogeneous magnitude-limited field galaxy sample with morphological types estimated. The systematic change of bulge-to-total luminosity ratio, $B/T$, along the morphological sequence is therefore not caused by disks but mostly by bulges. It is also shown ...

  13. Disk and Bulge Morphology of WFPC2 galaxies The HST Medium Deep Survey database

    CERN Document Server

    Ratnatunga, K U; Ostrander, E J; Ratnatunga, Kavan U.; Griffiths, Richard E.; Ostrander, Eric J.

    1999-01-01

    Quantitative morphological and structural parameters are estimated for galaxies detected in HST observations of WFPC2 survey fields. A modeling approach based on maximum likelihood has been developed for two-dimensional decomposition of faint under-sampled galaxy images into components of disk and bulge morphology. Decomposition can be achieved for images down to F814W (I) hour. We discuss details of the fitting procedure, and present the observed distributions of magnitude, color, effective half-light radius, disk and bulge axis ratios, bulge/(disk+bulge) flux ratio, bulge/disk half-light radius ratio and surface brightness. We also discuss the various selection limits on the measured parameters. The Medium Deep Survey catalogs and images of random pure parallel fields and other similar archival primary WFPC2 fields have been made available via the Internet with a searchable browser interface to the database at http://archive.stsci.edu/mds/

  14. Heading in the right direction: thermodynamics-based network analysis and pathway engineering.

    Science.gov (United States)

    Ataman, Meric; Hatzimanikatis, Vassily

    2015-12-01

    Thermodynamics-based network analysis through the introduction of thermodynamic constraints in metabolic models allows a deeper analysis of metabolism and guides pathway engineering. The number and the areas of applications of thermodynamics-based network analysis methods have been increasing in the last ten years. We review recent applications of these methods and we identify the areas that such analysis can contribute significantly, and the needs for future developments. We find that organisms with multiple compartments and extremophiles present challenges for modeling and thermodynamics-based flux analysis. The evolution of current and new methods must also address the issues of the multiple alternatives in flux directionalities and the uncertainties and partial information from analytical methods.

  15. A unified viscoplasticity constitutive model based on irreversible thermodynamics

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    A unified viscoplasticity constitutive model for metal materials is developed within the framework of irreversible thermodynamics, and an expression for the Helmholtz free energy function involving the parameters reflecting kinematic hardening and isotropic hardening is given. At the same time a non-associated flow potential function including the corresponding state variables is also given, from which the flow equation and the evolution equations of the internal state variables are derived. Thus, a general theoretical framework constructing a unified viscoplasticity constitutive model is given. Compared with the typical unified viscoplasticity constitutive models, the presented model evidently satisfies the irreversible thermodynamics laws. Moreover, this method not only provides a new theoretical foundation for further development of the unified viscoplasticity constitutive model, but also gives a new theoretical framework for the stress-strain analysis of more materials.

  16. A unified viscoplasticity constitutive model based on irreversible thermodynamics

    Institute of Scientific and Technical Information of China (English)

    LIU ChangChun; LV HeXiang; GUAN Ping

    2008-01-01

    A unified viscoplasticity constitutive model for metal materials is developed within the framework of irreversible thermodynamics, and an expression for the Helmholtz free energy function involving the parameters reflecting kinematic hardening and isotropic hardening is given. At the same time a non-associated flow potential function including the corresponding state variables is also given, from which the flow equation and the evolution equations of the internal state variables are derived. Thus, a general theoretical framework constructing a unified viscoplasticity con-stitutive model is given. Compared with the typical unified viscoplasticity constitu-tive models, the presented model evidently satisfies the irreversible thermody-namics laws. Moreover, this method not only provides a new theoretical foundation for further development of the unified viscoplasticity constitutive model, but also gives a new theoretical framework for the stress-strain analysis of more materials.

  17. Component Thermodynamical Selection Based Gene Expression Programming for Function Finding

    Directory of Open Access Journals (Sweden)

    Zhaolu Guo

    2014-01-01

    Full Text Available Gene expression programming (GEP, improved genetic programming (GP, has become a popular tool for data mining. However, like other evolutionary algorithms, it tends to suffer from premature convergence and slow convergence rate when solving complex problems. In this paper, we propose an enhanced GEP algorithm, called CTSGEP, which is inspired by the principle of minimal free energy in thermodynamics. In CTSGEP, it employs a component thermodynamical selection (CTS operator to quantitatively keep a balance between the selective pressure and the population diversity during the evolution process. Experiments are conducted on several benchmark datasets from the UCI machine learning repository. The results show that the performance of CTSGEP is better than the conventional GEP and some GEP variations.

  18. Mechanics, waves and thermodynamics an example-based approach

    CERN Document Server

    Jain, Sudhir Ranjan

    2016-01-01

    The principles of classical physics, though superseded in specific fields by such theories as quantum mechanics and general relativity, are still of great importance in a broad range of applications. The book presents fundamental concepts of classical physics in a coherent and logical manner. It discusses important topics including the mechanics of a single particle, kinetic theory, oscillations and waves. Topics including the kinetic theory of gases, thermodynamics and statistical mechanics are discussed, which are normally not present in the books on classical physics. The fundamental concepts of energy, momentum, mass and entropy are explained with examples. Discussion on concepts of thermodynamics is presented along with the simplified explanation on Caratheodory's axioms. It covers chapters on wave motion and statistical physics, useful for the graduate students. Each concept is supported with real-life applications on several concepts including impulse and collision, Bernoulli's equation, and friction.

  19. 3-Dimensional dynamics of the galactic bulge

    NARCIS (Netherlands)

    Soto Vicencio, Mario Humberto

    2010-01-01

    This thesis is part of a project which attempts to unveil the structure of the galactic bulge of our galaxy through the study of the kinematics of stars in low foreground extinction windows.Thus, in order to effectively constraint the phase-space distribution function of the galactic bulge, we have

  20. Thermodynamic modeling of the power plant based on the SOFC with internal steam reforming of methane

    International Nuclear Information System (INIS)

    Mathematical model based on the thermodynamic modeling of gaseous mixtures is developed for SOFC with internal steam reforming of methane. Macroscopic porous-electrode theory, including non-linear kinetics and gas-phase diffusion, is used to calculate the reforming reaction and the concentration polarization. Provided the data concerning properties and costs of materials the model is fit for wide range of parametric analysis of thermodynamic cycles including SOFC

  1. Duality, thermodynamics, and the linear programming problem in constraint-based models of metabolism

    OpenAIRE

    Warren, Patrick B.; Jones, Janette L.

    2007-01-01

    It is shown that the dual to the linear programming problem that arises in constraint-based models of metabolism can be given a thermodynamic interpretation in which the shadow prices are chemical potential analogues, and the objective is to minimise free energy consumption given a free energy drain corresponding to growth. The interpretation is distinct from conventional non-equilibrium thermodynamics, although it does satisfy a minimum entropy production principle. It can be used to motivat...

  2. Three thermodynamically-based parameterizations of the deceleration parameter

    CERN Document Server

    del Campo, Sergio; Herrera, Ramon; Pavon, Diego

    2012-01-01

    We propose, and constrain with the latest observational data, three model-independent parameterizations of the cosmic deceleration parameter $q(z)$. They are well behaved and stay finite at all redshifts. We construct them by fixing the value of $q$ at high redshift, $q(z \\gg 1) = 1/2$ (as demanded by cosmic structure formation), and at the far future, $q(z = -1) = -1$, and smoothly interpolating $q(z)$ between them. The fixed point at $z = -1$ is not arbitrarily chosen; it readily follows from the second law of thermodynamics. This fairly reduces the ample latitude in parameterizing $q(z)$.

  3. FAILURE ANALYSIS: WASTEWATER DRUM BULGING

    Energy Technology Data Exchange (ETDEWEB)

    Vormelker, P

    2008-09-15

    A 55 gallon wastewater drum lid was found to be bulged during storage in a remote area. Drum samples were obtained for analysis. The interior surface of these samples revealed blistering and holes in the epoxy phenolic drum liner and corrosion of the carbon steel drum. It is suspected that osmotic pressure drove permeation of the water through the epoxy phenolic coating which was weakened from exposure to low pH water. The coating failed at locations throughout the drum interior. Subsequent corrosion of the carbon steel released hydrogen which pressurized the drum causing deformation of the drum lid. Additional samples from other wastewater drums on the same pallet were also evaluated and limited corrosion was visible on the interior surfaces. It is suspected that, with time, the corrosion would have advanced to cause pressurization of these sealed drums.

  4. Comparison of Ablation Predictions for Carbonaceous Materials Using CEA and JANAF-Based Species Thermodynamics

    Science.gov (United States)

    Milos, Frank S.

    2011-01-01

    In most previous work at NASA Ames Research Center, ablation predictions for carbonaceous materials were obtained using a species thermodynamics database developed by Aerotherm Corporation. This database is derived mostly from the JANAF thermochemical tables. However, the CEA thermodynamics database, also used by NASA, is considered more up to date. In this work, the FIAT code was modified to use CEA-based curve fits for species thermodynamics, then analyses using both the JANAF and CEA thermodynamics were performed for carbon and carbon phenolic materials over a range of test conditions. The ablation predictions are comparable at lower heat fluxes where the dominant mechanism is carbon oxidation. However, the predictions begin to diverge in the sublimation regime, with the CEA model predicting lower recession. The disagreement is more significant for carbon phenolic than for carbon, and this difference is attributed to hydrocarbon species that may contribute to the ablation rate.

  5. Roles of the Amino Group of Purine Bases in the Thermodynamic Stability of DNA Base Pairing

    Directory of Open Access Journals (Sweden)

    Shu-ichi Nakano

    2014-08-01

    Full Text Available The energetic aspects of hydrogen-bonded base-pair interactions are important for the design of functional nucleotide analogs and for practical applications of oligonucleotides. The present study investigated the contribution of the 2-amino group of DNA purine bases to the thermodynamic stability of oligonucleotide duplexes under different salt and solvent conditions, using 2'-deoxyriboinosine (I and 2'-deoxyribo-2,6-diaminopurine (D as non-canonical nucleotides. The stability of DNA duplexes was changed by substitution of a single base pair in the following order: G•C > D•T ≈ I•C > A•T > G•T > I•T. The apparent stabilization energy due to the presence of the 2-amino group of G and D varied depending on the salt concentration, and decreased in the water-ethanol mixed solvent. The effects of salt concentration on the thermodynamics of DNA duplexes were found to be partially sequence-dependent, and the 2-amino group of the purine bases might have an influence on the binding of ions to DNA through the formation of a stable base-paired structure. Our results also showed that physiological salt conditions were energetically favorable for complementary base recognition, and conversely, low salt concentration media and ethanol-containing solvents were effective for low stringency oligonucleotide hybridization, in the context of conditions employed in this study.

  6. Bulges of disk galaxies at intermediate redshifts. I. Samples with and without bulges in the Groth Strip Survey

    CERN Document Server

    Dominguez-Palmero, L; Erwin, P; Prieto, M; Cristobal-Hornillos, D; Eliche-Moral, M C; Guzmán, R

    2008-01-01

    We aim to define a sample of intermediate-z disk galaxies harbouring central bulges, and a complementary sample of disk galaxies without measurable bulges. We intend to provide colour profiles for both samples, as well as measurements of nuclear, disk, and global colours, which may be used to constrain the relative ages of bulges and disks. We select a diameter-limited sample of galaxies in images from the HST/WFPC2 Groth Strip survey, which is divided into two subsamples of higher and lower inclination to assess the role of dust in the measures quantities. Mergers are visually identified and excluded. We take special care to control the pollution by ellipticals. The bulge sample is defined with a criterion based on nuclear surface brightness excess over the inward extrapolation of the exponential law fitted to the outer regions of the galaxies. We extract colour profiles on the semi-minor axis least affected by dust in the disk, and measure nuclear colours at 0.85 kpc from the centre over those profiles. Dis...

  7. Fluorine Abundances in the Milky Way Bulge

    CERN Document Server

    Cunha, K; Gibson, B K

    2008-01-01

    Fluorine (19F) abundances are derived in a sample of 6 bulge red giants in Baade's Window. These giants span a factor of 10 in metallicity and this is the first study to define the behavior of 19F with metallicity in the bulge. The bulge results show an increase in F/O with increasing oxygen. This trend overlaps what is found in the disk at comparable metallicities, with the most oxygen-rich bulge target extending the disk trend. The increase in F/O in the disk arises from 19F synthesis in both asymptotic giant branch (AGB) stars and metal-rich Wolf-Rayet (WR) stars through stellar winds. The lack of an s-process enhancement in the most fluorine-rich bulge giant in this study, suggests that WR stars represented a larger contribution than AGB stars to 19F production in the bulge when compared to the disk. If this result for fluorine is combined with the previously published overall decline in the O/Mg abundance ratios in metal-rich bulge stars, it suggests that WR winds played a role in shaping chemical evolut...

  8. Superplasticity and Superplastic Bulging Behavior of ZrO2/Ni Nanocomposite

    Institute of Scientific and Technical Information of China (English)

    DING Shui; LV Hongjun; ZHANG Kaifeng

    2011-01-01

    ZrO2/Ni nanocomposite was produced by pulse electrodeposition and its superplastic properties were investigated by the tensile and bulging tests. The as-deposited nickel matrix has a narrow grain size distribution with a mean grain size of 45 nm. A maximum elongation of 605% was observed at 723 K and a strain rate of 1.67 × 10-3s-1 by tensile test. Superplastic bulging tests were subsequently performed using dies with diameters of 1 mm and 5 mm respectively based on the optimal superplastic forming temperature. The effects of forming temperature and gas pressure on bulging process were experimentally investigated. The results indicated that ZrO2/Ni nanocomposite samples can be readily bulged at 723 K with H/d value (defined as dome apex height over the die diameter) larger than 0.5, indicating that the nanocomposite has good bulging ability. SEM and TEM were used to examine the microstructure of the as-deposited and bulged samples. The observations showed that significant grain coarsening occurs during superplastic bulging, and the microstructure is found to depend on the forming temperature.

  9. Thermodynamic calculations in the development of high-temperature Co–Re-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Gorr, Bronislava, E-mail: gorr@ifwt.mb.uni-siegen.de [University of Siegen, Institut für Werkstofftechnik, Siegen (Germany); Christ, Hans-Jürgen [University of Siegen, Institut für Werkstofftechnik, Siegen (Germany); Mukherji, Debashis; Rösler, Joachim [TU Braunschweig, Institut für Werkstoffe, Braunschweig (Germany)

    2014-01-05

    Highlights: • Phase diagram as a starting point for alloy development. • Design of pre-oxidation treatments by means of thermodynamic assessment. • Contribution of thermodynamic calculations to the general understanding of materials chemistry. -- Abstract: The experimental Co–Re-based alloys are being developed for high-temperature applications for service temperatures beyond 1100 °C. One of the main tasks of this research is to find the optimal chemical composition. Thermodynamic calculations are very helpful for composition selection and optimization. In this study, thermodynamic calculations were used to identify potential alloying elements and to determine suitable concentration ranges to improve properties, such as strength and oxidation resistance that are essential for high-temperature structural materials. The calculated ternary phase diagram of the Co–Re–Cr system was used to design the reference model alloy. Corrosion products formed under different atmospheric conditions were reliably predicted for a number of model Co–Re-based alloys. Pre-oxidation treatment, a common method used to improve the oxidation resistance of alloys in aggressive atmosphere, was successfully designed based on thermodynamic considerations.

  10. Thermodynamics of noncommutative geometry inspired black holes based on Maxwell-Boltzmann smeared mass distribution

    Science.gov (United States)

    Liang, Jun; Liu, Yan-Chun; Zhu, Qiao

    2014-02-01

    In order to further explore the effects of non-Gaussian smeared mass distribution on the thermodynamical properties of noncommutative black holes, we consider noncommutative black holes based on Maxwell-Boltzmann smeared mass distribution in (2+1)-dimensional spacetime. The thermodynamical properties of the black holes are investigated, including Hawking temperature, heat capacity, entropy and free energy. We find that multiple black holes with the same temperature do not exist, while there exists a possible decay of the noncommutative black hole based on Maxwell-Boltzmann smeared mass distribution into the rotating (commutative) BTZ black hole.

  11. Thermodynamics of noncommutative geometry inspired black holes based on Maxwell-Boltzmann smeared mass distribution

    International Nuclear Information System (INIS)

    In order to further explore the effects of non-Gaussian smeared mass distribution on the thermodynamical properties of noncommutative black holes, we consider noncommutative black holes based on Maxwell-Boltzmann smeared mass distribution in (2+1)-dimensional spacetime. The thermodynamical properties of the black holes are investigated, including Hawking temperature, heat capacity, entropy and free energy. We find that multiple black holes with the same temperature do not exist, while there exists a possible decay of the noncommutative black hole based on Maxwell-Boltzmann smeared mass distribution into the rotating (commutative) BTZ black hole. (authors)

  12. Comparing the properties of the X-shaped bulges of NGC 4710 and the Milky Way with MUSE

    Science.gov (United States)

    Gonzalez, O. A.; Gadotti, D. A.; Debattista, V. P.; Rejkuba, M.; Valenti, E.; Zoccali, M.; Coccato, L.; Minniti, D.; Ness, M.

    2016-06-01

    comprised of the oldest, most metal-poor stars, which is not part of the boxy-peanut bulge structure. Such a population is not observed in NGC 4710, but could be hidden in the integrated light we observed. Based on observations collected at the ESO La Silla-Paranal Observatory within MUSE science verification program 60.A-9307(A).

  13. Theoretical Models of the Galactic Bulge

    CERN Document Server

    Shen, Juntai

    2015-01-01

    Near infrared images from the COBE satellite presented the first clear evidence that our Milky Way galaxy contains a boxy shaped bulge. Recent years have witnessed a gradual paradigm shift in the formation and evolution of the Galactic bulge. Bulges were commonly believed to form in the dynamical violence of galaxy mergers. However, it has become increasingly clear that the main body of the Milky Way bulge is not a classical bulge made by previous major mergers, instead it appears to be a bar seen somewhat end-on. The Milky Way bar can form naturally from a precursor disk and thicken vertically by the internal firehose/buckling instability, giving rise to the boxy appearance. This picture is supported by many lines of evidence, including the asymmetric parallelogram shape, the strong cylindrical rotation (i.e., nearly constant rotation regardless of the height above the disk plane), the existence of an intriguing X-shaped structure in the bulge, and perhaps the metallicity gradients. We review the major theor...

  14. A Thermodynamic-Based Model to Predict the Fraction of Martensite in Steels

    Science.gov (United States)

    Huyan, Fei; Hedström, Peter; Höglund, Lars; Borgenstam, Annika

    2016-09-01

    A thermodynamic-based model to predict the fraction of martensite in steels with undercooling has been developed. The model utilizes the thermodynamic driving force to describe the transformation curve and it is able to predict the fraction of athermal martensite at quenching to different temperatures for low alloy steels. The only model parameter is a linear function of the martensite start temperature ( M s), and the model predicts that a steel with a higher M s has a lower difference between the martensite start and finish temperatures. When the present model is combined with a previously developed thermodynamic-based model for M s, the model predictions of the full martensite transformation curve with undercooling are in close agreement with literature data.

  15. A Thermodynamic-Based Model to Predict the Fraction of Martensite in Steels

    Science.gov (United States)

    Huyan, Fei; Hedström, Peter; Höglund, Lars; Borgenstam, Annika

    2016-06-01

    A thermodynamic-based model to predict the fraction of martensite in steels with undercooling has been developed. The model utilizes the thermodynamic driving force to describe the transformation curve and it is able to predict the fraction of athermal martensite at quenching to different temperatures for low alloy steels. The only model parameter is a linear function of the martensite start temperature (M s), and the model predicts that a steel with a higher M s has a lower difference between the martensite start and finish temperatures. When the present model is combined with a previously developed thermodynamic-based model for M s, the model predictions of the full martensite transformation curve with undercooling are in close agreement with literature data.

  16. Thermodynamic analysis of an HCCI engine based system running on natural gas

    International Nuclear Information System (INIS)

    Highlights: • A thermodynamic analysis of an HCCI based system has been carried out. • A thermodynamic model has been developed taking into account the gas composition resulting from the combustion process. • The specific heat of the working fluid is temperature dependent. - Abstract: This paper attempts to carry out a thermodynamic analysis of a system composed of a turbocharged HCCI engine, a mixer, a regenerator and a catalytic converter within the meaning of the first and the second law of thermodynamics. For this purpose, a thermodynamic model has been developed taking into account the gas composition resulting from the combustion process and the specific heat temperature dependency of the working fluid. The analysis aims in particular to examine the influence of the compressor pressure ratio, ambient temperature, equivalence ratio, engine speed and the compressor isentropic efficiency on the performance of the HCCI engine. Results show that thermal and exergetic efficiencies increase with increasing the compressor pressure ratio. However, the increase of the ambient temperature involves a decrease of the engine efficiencies. Furthermore, the variation of the equivalence ratio improves considerably both thermal and exergetic efficiencies. As expected, the increase of the engine speed enhances the engine performances. Finally, an exergy losses mapping of the system show that the maximum exergy losses occurs in the HCCI engine

  17. Thermodynamic properties of gadolinium in Ga-Sn and Ga-Zn eutectic based alloys

    Science.gov (United States)

    Maltsev, Dmitry S.; Volkovich, Vladimir A.; Yamshchikov, Leonid F.; Chukin, Andrey V.

    2016-09-01

    Thermodynamic properties of gadolinium in Ga-Sn and Ga-Zn eutectic based alloys were studied. Temperature dependences of gadolinium activity in the studied alloys were determined at 573-1073 K employing the EMF method. Solubility of gadolinium in the Ga-Sn and Ga-Zn alloys was measured at 462-1073 K using IMCs sedimentation method. Activity coefficients as well as partial and excess thermodynamic functions of gadolinium in the studied alloys were calculated on the basis of the obtained experimental data.

  18. PROPER MOTIONS IN THE GALACTIC BULGE: PLAUT'S WINDOW

    Directory of Open Access Journals (Sweden)

    K. Vieira

    2009-01-01

    Full Text Available A proper motion study of a eld of 20' x20' inside Plaut's low extinction window (l,b=(0 ;-8 , has been completed. Relative proper motions and photographic BV photometry have been derived for -21; 000 stars reaching to V - 20:5 mag, based on the astrometric reduction of 43 photographic plates, spanning over 21 years of epoch di erence. Proper motion errors are typically 1 mas yr-1. Cross-referencing with the 2MASS catalog yielded a sample of - 8700 stars, from which predominantly disk and bulge subsamples were selected photometrically from the JH color-magnitude diagram. The two samples exhibited di erent proper-motion distributions, with the disk displaying the expected re ex solar motion. Galactic rotation was also detected for stars between -2 and -3 kpc from us. The bulge sample, represented by red giants, has an intrinsic proper motion dispersion of (l; b = (3:39; 2:91 = (0:11; 0:09 mas yr-1, which is in good agreement with previous results. A mean distance of 6:37+0:87 -0:77 kpc has been estimated for the bulge sample, based on the observed K magnitude of the horizontal branch red clump. The metallicity [M=H] distribution was also obtained for a subsample of 60 bulge giants stars, based on calibrated photometric indices. The observed [M=H] shows a peak value at [M=H]-0:1 with an extended metal poor tail and around 30% of the stars with supersolar metallicity. No change in proper motion dispersion was observed as a function of [M=H]. We are currently in the process of obtaining CCD UBV RI photometry for the entire proper-motion sample of - 21; 000 stars.

  19. Development of Co-Cr-based longitudinal magnetic recording media:Thermodynamic consideration

    Institute of Scientific and Technical Information of China (English)

    QIN Gao-wu; K. Oikawa

    2004-01-01

    This paper reviews our recent work on development of Co-Cr-based longitudinal magnetic recording media through the point of view of thermodynamics. It focuses on our experimental finding on the miscibility gap in the fcc α-Co phase region of the Co-Cr binary system, and on the predictions on the improvements of magnetic properties of many Co-Cr-Z ternary systems by thermodynamic computing on the basis of the newly-assessed Co-Cr binary thermodynamic parameters. Good agreement in the phase separation behavior of many Co-Cr-Z (Z=Pt, Ta, Ge)alloy systems between the calculation and the experiments has been achieved, as discussed in detail in the full paper.By the same token, many other elements, such as Ir, P, B, Mo, Zr, Nb, have been predicted to improve the magnetic grain isolation of the potential Co-Cr-Z multicomponent magnetic recording media in the future.

  20. The Effectiveness of Problem-Based Learning on Teaching the First Law of Thermodynamics

    Science.gov (United States)

    Tatar, Erdal; Oktay, Munir

    2011-01-01

    Background: Problem-based learning (PBL) is a teaching approach working in cooperation with self-learning and involving research to solve real problems. The first law of thermodynamics states that energy can neither be created nor destroyed, but that energy is conserved. Students had difficulty learning or misconceptions about this law. This study…

  1. A thermodynamic perspective on food webs: Quantifying entropy production within detrital-based ecosystems

    NARCIS (Netherlands)

    Meysman, F.J.R.; Bruers, S.

    2007-01-01

    Because ecosystems fit so nicely the framework of a “dissipative system”, a better integration of thermodynamic and ecological perspectives could benefit the quantitative analysis of ecosystems. One obstacle is that traditional food web models are solely based upon the principles of mass and energy

  2. Continuum thermodynamics

    CERN Document Server

    Wilmanski, Krzysztof

    2008-01-01

    This book is a unique presentation of thermodynamic methods of construction of continuous models. It is based on a uniform approach following from the entropy inequality and using Lagrange multipliers as auxiliary quantities in its evaluation. It covers a wide range of models - ideal gases, thermoviscoelastic fluids, thermoelastic and thermoviscoelastic solids, plastic polycrystals, miscible and immiscible mixtures, and many others. The structure of phenomenological thermodynamics is justified by a systematic derivation from the Liouville equation, through the BBGKY-hierarchy-derived Boltzmann

  3. Thermodynamic analysis of regulation in metabolic networks using constraint-based modeling

    Directory of Open Access Journals (Sweden)

    Mahadevan Radhakrishnan

    2010-05-01

    Full Text Available Abstract Background Geobacter sulfurreducens is a member of the Geobacter species, which are capable of oxidation of organic waste coupled to the reduction of heavy metals and electrode with applications in bioremediation and bioenergy generation. While the metabolism of this organism has been studied through the development of a stoichiometry based genome-scale metabolic model, the associated regulatory network has not yet been well studied. In this manuscript, we report on the implementation of a thermodynamics based metabolic flux model for Geobacter sulfurreducens. We use this updated model to identify reactions that are subject to regulatory control in the metabolic network of G. sulfurreducens using thermodynamic variability analysis. Findings As a first step, we have validated the regulatory sites and bottleneck reactions predicted by the thermodynamic flux analysis in E. coli by evaluating the expression ranges of the corresponding genes. We then identified ten reactions in the metabolic network of G. sulfurreducens that are predicted to be candidates for regulation. We then compared the free energy ranges for these reactions with the corresponding gene expression fold changes under conditions of different environmental and genetic perturbations and show that the model predictions of regulation are consistent with data. In addition, we also identify reactions that operate close to equilibrium and show that the experimentally determined exchange coefficient (a measure of reversibility is significant for these reactions. Conclusions Application of the thermodynamic constraints resulted in identification of potential bottleneck reactions not only from the central metabolism but also from the nucleotide and amino acid subsystems, thereby showing the highly coupled nature of the thermodynamic constraints. In addition, thermodynamic variability analysis serves as a valuable tool in estimating the ranges of ΔrG' of every reaction in the model

  4. Nonlinear Local Bending Response and Bulging Factors for Longitudinal Cracks in Pressurized Cylindrical Shells

    Science.gov (United States)

    Rose, Cheryl A.; Young, Richard D.; Starnes, James H., Jr.

    1999-01-01

    Results of a geometrically nonlinear finite element parametric study to determine curvature correction factors or "bulging factors" that account for increased stresses due to curvature for longitudinal cracks in unstiffened pressurized cylindrical shells are presented. Geometric parameters varied in the study include the shell radius, the shell wall thickness, and the crack length. The major results are presented in graphs of the bulging factor as a function of the applied load and as a function of geometric parameters that include the shell radius, the shell thickness and the crack length. The computed bulging factors are compared with solutions based on linear shallow shell theory, and with semi-empirical solutions that approximately account for the nonlinear deformation in the vicinity of the crack. The effect of biaxial loads on the computed bulging factors is also discussed.

  5. Accounting for selection effects in the BH-bulge relations: No evidence for cosmological evolution

    CERN Document Server

    Schulze, Andreas

    2013-01-01

    The redshift evolution of the black hole - bulge relations is an essential observational constraint for models of black hole - galaxy coevolution. In addition to the observational challenges for these studies, conclusions are complicated by the influence of selection effects. We demonstrate that there is presently no statistical significant evidence for cosmological evolution in the black hole-bulge relations, once these selection effects are taken into account and corrected for. We present a fitting method, based on the bivariate distribution of black hole mass and galaxy property, that accounts for the selection function in the fitting and is therefore able to recover the intrinsic black hole - bulge relation unbiased. While prior knowledge is restricted to a minimum, we at least require knowledge of either the sample selection function and the mass dependence of the active fraction, or the spheroid distribution function and the intrinsic scatter in the black hole - bulge relation. We employed our fitting r...

  6. Thermodynamic properties and atomic structure of Ca-based liquid alloys

    Science.gov (United States)

    Poizeau, Sophie

    To identify the most promising positive electrodes for Ca-based liquid metal batteries, the thermodynamic properties of diverse Ca-based liquid alloys were investigated. The thermodynamic properties of Ca-Sb alloys were determined by emf measurements. It was found that Sb as positive electrode would provide the highest voltage for Ca-based liquid metal batteries (1 V). The price of such a battery would be competitive for the grid-scale energy storage market. The impact of Pb, a natural impurity of Sb, was predicted successfully and confirmed via electrochemical measurements. It was shown that the impact on the open circuit voltage would be minor. Indeed, the interaction between Ca and Sb was demonstrated to be much stronger than between Ca and Pb using thermodynamic modeling, which explains why the partial thermodynamic properties of Ca would not vary much with the addition of Pb to Sb. However, the usage of the positive electrode would be reduced, which would limit the interest of a Pb-Sb positive electrode. Throughout this work, the molecular interaction volume model (MIVM) was used for the first time for alloys with thermodynamic properties showing strong negative deviation from ideality. This model showed that systems such as Ca-Sb have strong short-range order: Ca is most stable when its first nearest neighbors are Sb. This is consistent with what the more traditional thermodynamic model, the regular association model, would predict. The advantages of the MIVM are the absence of assumption regarding the composition of an associate, and the reduced number of fitting parameters (2 instead of 5). Based on the parameters derived from the thermodynamic modeling using the MIVM, a new potential of mixing for liquid alloys was defined to compare the strength of interaction in different Ca-based alloys. Comparing this trend with the strength of interaction in the solid state of these systems (assessed by the energy of formation of the intermetallics), the systems with

  7. Impact of the terminal bulges of HIV-1 cTAR DNA on its stability and the destabilizing activity of the nucleocapsid protein NCp7.

    Science.gov (United States)

    Beltz, Hervé; Azoulay, Joel; Bernacchi, Serena; Clamme, Jean-Pierre; Ficheux, Damien; Roques, Bernard; Darlix, Jean-Luc; Mély, Yves

    2003-04-18

    Reverse transcription of HIV-1 genomic RNA to double-stranded DNA by reverse transcriptase (RT) is a critical step in HIV-1 replication. This process relies on two viral proteins, the RT enzyme and nucleocapsid protein NCp7 that has well documented nucleic acid chaperone properties. At the beginning of the linear DNA synthesis, the newly made minus-strand strong-stop DNA ((-)ssDNA) is transferred to the 3'end of the genomic RNA by means of an hybridization reaction between transactivation response element (TAR) RNA and cTAR DNA sequences. Since both TAR sequences exhibit stable hairpin structures, NCp7 needs to destabilize the TAR structures in order to chaperone their hybridization. To further characterize the relationships between TAR stability and NC-mediated destabilization, the role of the A(49) and G(52) bulged residues in cTAR DNA stability was investigated. The stability of cTAR and mutants where one or the two terminal bulges were replaced by base-pairs as well as the NCp7-mediated destabilization of these cTAR sequences were examined. Thermodynamic data indicate that the two bulges cooperatively destabilize cTAR by reducing the stacking interactions between the bases. This causes a free energy change of about 6.4 kcal/mol and seems to be critical for NC activity. Time-resolved fluorescence data of doubly labelled cTAR derivatives suggest that NC-mediated melting of cTAR ends propagates up to the 10C.A(44) mismatch or T(40) bulge. Fluorescence correlation spectroscopy using two-photon excitation was also used to monitor cTAR ends fraying by NC. Results show that NC causes a very significant increase of cTAR ends fraying, probably limited to the terminal base-pair in the case of cTAR mutants. Since the TAR RNA and cTAR DNA bulges or mismatches appear well conserved among all HIV-1 strains, the present data support the notion of a co-evolutionary relationship between TAR and NC activity. PMID:12684000

  8. The Black Hole - Bulge Mass Relation in Megamaser Host Galaxies

    CERN Document Server

    Läsker, Ronald; Seth, Anil; van de Ven, Glenn; Braatz, James A; Henkel, Christian; Lo, K Y

    2016-01-01

    We present HST images for nine megamaser disk galaxies with the primary goal of studying photometric BH-galaxy scaling relations. The megamaser disks provide the highest-precision extragalactic BH mass measurements, while our high-resolution HST imaging affords us the opportunity to decompose the complex nuclei of their late-type hosts in detail. Based on the morphologies and shapes of the galaxy nuclei, we argue that most of these galaxies' central regions contain secularly evolving components (pseudo-bulges), and in many cases we photometrically identify co-existing "classical" bulge components as well. Using these decompositions, we draw the following conclusions: (1) The megamaser BH masses span two orders of magnitude ($10^6$ -- $10^8 M_\\odot$) while the stellar mass of their spiral host galaxies are all $\\sim 10^{11} M_\\odot$ within a factor of three; (2) the BH masses at a given bulge mass or total stellar mass in the megamaser host spiral galaxies tend to be lower than expected, when compared to an ex...

  9. VERY METAL-POOR STARS IN THE OUTER GALACTIC BULGE FOUND BY THE APOGEE SURVEY

    Energy Technology Data Exchange (ETDEWEB)

    Garcia Perez, Ana E.; Majewski, Steven R.; Hearty, Fred R. [Department of Astronomy, University of Virginia, Charlottesville, VA 22904-4325 (United States); Cunha, Katia [Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Shetrone, Matthew [McDonald Observatory, University of Texas at Austin, Fort Davis, TX 79734 (United States); Johnson, Jennifer A.; Zasowski, Gail [Department of Astronomy, The Ohio State University, Columbus, OH 43210 (United States); Smith, Verne V.; Beers, Timothy C. [National Optical Astronomy Observatories, Tucson, AZ 85719 (United States); Schiavon, Ricardo P. [Gemini Observatory, 670 N. A' Ohoku Place, Hilo, HI 96720 (United States); Holtzman, Jon [Department of Astronomy, MSC 4500, New Mexico State University, P.O. Box 30001, Las Cruces, NM 88003 (United States); Nidever, David [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Allende Prieto, Carlos [Departamento de Astrofisica, Universidad de La Laguna, E-38206 La Laguna, Tenerife (Spain); Bizyaev, Dmitry; Ebelke, Garrett; Malanushenko, Elena; Malanushenko, Viktor [Apache Point Observatory, P.O. Box 59, Sunspot, NM 88349-0059 (United States); Eisenstein, Daniel J. [Harvard Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Frinchaboy, Peter M. [Department of Physics and Astronomy, Texas Christian University, 2800 South University Drive, Fort Worth, TX 76129 (United States); Girardi, Leo [Laboratorio Interinstitucional de e-Astronomia - LIneA, Rua Gal. Jose Cristino 77, Rio de Janeiro, RJ - 20921-400 (Brazil); and others

    2013-04-10

    Despite its importance for understanding the nature of early stellar generations and for constraining Galactic bulge formation models, at present little is known about the metal-poor stellar content of the central Milky Way. This is a consequence of the great distances involved and intervening dust obscuration, which challenge optical studies. However, the Apache Point Observatory Galactic Evolution Experiment (APOGEE), a wide-area, multifiber, high-resolution spectroscopic survey within Sloan Digital Sky Survey III, is exploring the chemistry of all Galactic stellar populations at infrared wavelengths, with particular emphasis on the disk and the bulge. An automated spectral analysis of data on 2403 giant stars in 12 fields in the bulge obtained during APOGEE commissioning yielded five stars with low metallicity ([Fe/H] {<=} -1.7), including two that are very metal-poor [Fe/H] {approx} -2.1 by bulge standards. Luminosity-based distance estimates place the 5 stars within the outer bulge, where 1246 of the other analyzed stars may reside. A manual reanalysis of the spectra verifies the low metallicities, and finds these stars to be enhanced in the {alpha}-elements O, Mg, and Si without significant {alpha}-pattern differences with other local halo or metal-weak thick-disk stars of similar metallicity, or even with other more metal-rich bulge stars. While neither the kinematics nor chemistry of these stars can yet definitively determine which, if any, are truly bulge members, rather than denizens of other populations co-located with the bulge, the newly identified stars reveal that the chemistry of metal-poor stars in the central Galaxy resembles that of metal-weak thick-disk stars at similar metallicity.

  10. The Demographics of galactic bulges in the SDSS database

    CERN Document Server

    Kim, Keunho; Jeong, Hyunjin; Aragon-Salamanca, Alfonso; Smith, Rory; Yi, Sukyoung K

    2016-01-01

    We present a new database of our two-dimensional bulge-disk decompositions for 14,233 galaxies drawn from SDSS DR12 in order to examine the properties of bulges residing in the local universe ($0.005 < z < 0.05$). We performed decompositions in $g$ and $r$ bands by utilizing the {\\sc{galfit}} software. The bulge colors and bulge-to-total ratios are found to be sensitive to the details in the decomposition technique, and hence we hereby provide full details of our method. The $g-r$ colors of bulges derived are almost constantly red regardless of bulge size except for the bulges in the low bulge-to-total ratio galaxies ($B/T_{\\rm r} \\lesssim 0.3$). Bulges exhibit similar scaling relations to those followed by elliptical galaxies, but the bulges in galaxies with lower bulge-to-total ratios clearly show a gradually larger departure in slope from the elliptical galaxy sequence. The scatters around the scaling relations are also larger for the bulges in galaxies with lower bulge-to-total ratios. Both the depa...

  11. Are there carbon stars in the Bulge ?

    OpenAIRE

    Ng, Y. K.

    1998-01-01

    The bulge carbon stars have been a mystery since their discovery, because they are about 2.5mag too faint to be regarded as genuine AGB stars, if located inside the metal-rich bulge (m-M=14.5mag). Part of the mystery can be solved if these carbon stars are related to the Sagittarius dwarf galaxy (SDG; m-M=17.0mag). They are in that case not old and metal-rich, but young, ~0.1 Gyr, with SMC-like metallicity. The sigma_RV=113+/-14 km/s radial velocity dispersion of the stars appears to be consi...

  12. Observations of planetary nebulae in the Galactic Bulge

    CERN Document Server

    Cuisinier, F; Köppen, J; Acker, A; Stenholm, B

    2000-01-01

    High quality spectrophotometric observations of 30 Planetary Nebulae in the Galactic Bulge have been made. Accurate reddenings, plasma parameters, and abundances of He,O,N,S,Ar,Cl are derived. We find the abundances of O,S,Ar in the Planetary Nebulae in the Galactic Bulge to be comparable with the abundances of the Planetary Nebulae in the Disk, high abundances being maybe slightly more frequent in the Bulge. The distribution of the N/O ratio does not present in the Galactic Bulge Planetary Nebulae the extension to high values that it presents in the Disk Planetary Nebulae. We interpret this as a signature of the greater age of Bulge Planetary Nebulae. We thus find the Bulge Planetary Nebulae to be an old population, slightly more metal-rich than the Disk Planetary Nebulae. The population of the Bulge Planetary Nebulae shows hence the same characteristics than the Bulge stellar population.

  13. THEREDA. Thermodynamic reference data base. Phase II. Release of thermodynamic data. Summary and final report; THEREDA. Thermodynamische Referenz-Datenbasis. Phase II. Freigabe thermodynamischer Daten. Zusammenfassung der Abschlussberichte

    Energy Technology Data Exchange (ETDEWEB)

    Altmaier, Marcus; Gaona, Xavier; Marquardt, Christian; Montoya, Vanessa [Karlsruher Institut fuer Technologie (KIT), Eggenstein-Leopoldshafen (Germany). Institut fuer Nukleare Entsorgung; Bok, Frank; Richter, Anke [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Inst. of Resource Ecology; Moog, Helge C.; Scharge, Tina [Gesellschaft fuer Anlagen- und Reaktorsicherheit mbH (GRS), Koeln (Germany); Voigt, Wolfgang [Technische Univ. Bergakademie Freiberg (Germany); Wilhelm, Stefan [AF Consult AG, Baden-Daettwil (Switzerland)

    2015-12-15

    The final report on the thermodynamic reference data base THEREDA covers the following issues: project management, quality management (Helmholtz-Zentrum Dresden-Rossendorf HZDR and GRS), data base interfaces, documentation, uranium (HZDR), other nuclides (Karlsruhe Institute for technology, KIT), data for cement minerals and their reaction products (AF-Consult, GRS), phosphate (GRS), systems with CO2 and carbonate at variable temperatures and pressure (Bergakademie Freiberg, TUBAF).

  14. Boltzmann-Equation Based Derivation of Balance Laws in Irreversible Thermodynamics

    OpenAIRE

    Hong, Liu; Yang, Zaibao; Zhu, Yi; Yong, Wen-An

    2014-01-01

    In this paper we propose a novel approach to construct macroscopic balance equations and constitutive equations describing various irreversible phenomena. It is based on the general principles of non-equilibrium thermodynamics and consists of four basic steps: picking suitable state variables, choosing a strictly concave entropy function, separating entropy fluxes and production rates properly, and determining a dissipation matrix. Our approach takes the advantage of both EIT and GENERIC form...

  15. Densities and Derived Thermodynamic Properties of Imidazolium-, Pyridinium-, Pyrrolidinium-, and Piperidinium-Based Ionic Liquids

    OpenAIRE

    Gardas, Ramesh L.; Costa, Henrique F.; Freire, Mara G.; Carvalho, Pedro J.; Marrucho, Isabel M.; Fonseca, Isabel M. A.; Ferreira, Abel G. M.; Coutinho, João A. P.

    2008-01-01

    In the present work, experimental density measurements are reported along with the derived thermodynamic properties, such as the isothermal compressibility (κT), the isobaric expansivity (αp), and the thermal pressure coefficient (γv) for imidazolium-, pyridinium-, pyrrolidinium-, and piperidinium-based ionic liquids (ILs), namely, 1-ethyl-3-methylimidazolium trifluoromethanesulfonate [C2mim][CF3SO3], 3-methyl-1-propylpyridinium bis(trifluoromethylsulfonyl)imide [C3mpy][NTf2], 1-methyl-1-prop...

  16. Bulge formation in disk galaxies with MOND

    CERN Document Server

    Combes, F

    2014-01-01

    The formation of galaxies and their various components can be stringent tests of dark matter models and of gravity theories. In the standard cold dark matter (CDM) model, spheroids are formed through mergers in a strongly hierarchical scenario, and also in the early universe through dynamical friction in clumpy galaxies. More secularly, pseudo-bulges are formed by the inner vertical resonance with bars. The high efficiency of bulge formation is in tension with observations in the local universe of a large amount of bulge-less spiral galaxies. In the present work, the formation of bulges in very gas-rich galaxies, as those in the early universe, is studied in the Milgrom's MOdified Newtonian Dynamics (MOND), through multi-grid simulations of the non-linear gravity, including the gas dissipation, star formation and feedback. Clumpy disks are rapidly formed, as in their Newtonian equivalent systems. However, the dynamical friction is not as efficient, in the absence of dark matter halos, and the clumps have no t...

  17. Thermodynamic data base needs for modeling studies of the Yucca Mountain project

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, C.E.A.; Silva, R.J. [Lawrence Livermore National Lab., CA (United States). Nuclear Chemistry Div.; Bucher, J.J. [Lawrence Berkeley Lab., CA (United States). Materials and Chemical Sciences Div.

    1996-07-12

    This document is the first in a series of documents outlining the thermodynamic data needs for performing geochemical modeling calculations in support of various waste package performance assessment activities for the Yucca Mountain Project. The documents are intended to identify and justify the critical thermodynamic data needs for the data base to be used with the models. The Thermodynamic Data Determinations task supplies data needed to resolve performance or design issues and the development of the data base will remain an iterative process as needs change or data improve. For example, data are needed to predict: (1) major ion groundwater chemistry and its evolution, (2) mineral stabilities and evolution, (3) engineered barrier near-field transport and retardation properties, (4) changes in geochemical conditions and processes, (5) solubilities, speciation and transport of waste radionuclides and (6) the dissolution of corrosion of construction and canister materials and the effect on groundwater chemistry and radionuclide solubilities and transport. The system is complex and interactive, and data need to be supplied in order to model the changes and their effect on other components of the system, e.g., temperature, pH and redox conditions (Eh). Through sensitivity and uncertainty analyses, the critical data and system parameters will be identified and the acceptable variations in them documented.

  18. Thermodynamic data base needs for modeling studies of the Yucca Mountain project

    International Nuclear Information System (INIS)

    This document is the first in a series of documents outlining the thermodynamic data needs for performing geochemical modeling calculations in support of various waste package performance assessment activities for the Yucca Mountain Project. The documents are intended to identify and justify the critical thermodynamic data needs for the data base to be used with the models. The Thermodynamic Data Determinations task supplies data needed to resolve performance or design issues and the development of the data base will remain an iterative process as needs change or data improve. For example, data are needed to predict: (1) major ion groundwater chemistry and its evolution, (2) mineral stabilities and evolution, (3) engineered barrier near-field transport and retardation properties, (4) changes in geochemical conditions and processes, (5) solubilities, speciation and transport of waste radionuclides and (6) the dissolution of corrosion of construction and canister materials and the effect on groundwater chemistry and radionuclide solubilities and transport. The system is complex and interactive, and data need to be supplied in order to model the changes and their effect on other components of the system, e.g., temperature, pH and redox conditions (Eh). Through sensitivity and uncertainty analyses, the critical data and system parameters will be identified and the acceptable variations in them documented

  19. One-dimensional tensile constitutive equation cannot be directly generalized to deal with two-dimensional bulging mechanical problems

    Institute of Scientific and Technical Information of China (English)

    SONG; Yuquan(宋玉泉); LIU; Shumei(刘术梅)

    2002-01-01

    Superplastic forming has been extensively applied to manufacture parts and components with complex shapes or high-precisions. However, superplastic formation is in multi-stress state. In a long time, uniaxial tensile constitutive equation has been directly generalized to deal with multi-stress state. Whether so doing is feasible or not needs to be proved in theory. This paper first summarizes the establishing processes of superplastic tensile and bulging constitutive equation with variable m, and, using the analytical expressions of equivalent stress ? and equivalent strain rateof free bulge based on the fundamentals of continuum medium plastic mechanics, derives the analytical expressions of optimum loading rules for superplastic free bulge. By comparing the quantitative results on typical superplastic alloy ZnAl22, it is shown that one-dimensional tensile constitutive equations cannot be directly generalized to deal with two-dimensional bulging quantitative mechanical problems; only superplastic bulging constitutive equation based on bulging stress state can be used to treat the quantitative mechanical problems of bulge.

  20. VizieR Online Data Catalog: SDSS bulge, disk and total stellar mass estimates (Mendel+, 2014)

    Science.gov (United States)

    Mendel, J. T.; Simard, L.; Palmer, M.; Ellison, S. L.; Patton, D. R.

    2014-01-01

    We present a catalog of bulge, disk, and total stellar mass estimates for ~660000 galaxies in the Legacy area of the Sloan Digital Sky Survey Data (SDSS) Release 7. These masses are based on a homogeneous catalog of g- and r-band photometry described by Simard et al. (2011, Cat. J/ApJS/196/11), which we extend here with bulge+disk and Sersic profile photometric decompositions in the SDSS u, i, and z bands. We discuss the methodology used to derive stellar masses from these data via fitting to broadband spectral energy distributions (SEDs), and show that the typical statistical uncertainty on total, bulge, and disk stellar mass is ~0.15 dex. Despite relatively small formal uncertainties, we argue that SED modeling assumptions, including the choice of synthesis model, extinction law, initial mass function, and details of stellar evolution likely contribute an additional 60% systematic uncertainty in any mass estimate based on broadband SED fitting. We discuss several approaches for identifying genuine bulge+disk systems based on both their statistical likelihood and an analysis of their one-dimensional surface-brightness profiles, and include these metrics in the catalogs. Estimates of the total, bulge and disk stellar masses for both normal and dust-free models and their uncertainties are made publicly available here. (4 data files).

  1. Characterizing the bending and flexibility induced by bulges in DNA duplexes

    Science.gov (United States)

    Schreck, John S.; Ouldridge, Thomas E.; Romano, Flavio; Louis, Ard A.; Doye, Jonathan P. K.

    2015-04-01

    Advances in DNA nanotechnology have stimulated the search for simple motifs that can be used to control the properties of DNA nanostructures. One such motif, which has been used extensively in structures such as polyhedral cages, two-dimensional arrays, and ribbons, is a bulged duplex, that is, two helical segments that connect at a bulge loop. We use a coarse-grained model of DNA to characterize such bulged duplexes. We find that this motif can adopt structures belonging to two main classes: one where the stacking of the helices at the center of the system is preserved, the geometry is roughly straight, and the bulge is on one side of the duplex and the other where the stacking at the center is broken, thus allowing this junction to act as a hinge and increasing flexibility. Small loops favor states where stacking at the center of the duplex is preserved, with loop bases either flipped out or incorporated into the duplex. Duplexes with longer loops show more of a tendency to unstack at the bulge and adopt an open structure. The unstacking probability, however, is highest for loops of intermediate lengths, when the rigidity of single-stranded DNA is significant and the loop resists compression. The properties of this basic structural motif clearly correlate with the structural behavior of certain nano-scale objects, where the enhanced flexibility associated with larger bulges has been used to tune the self-assembly product as well as the detailed geometry of the resulting nanostructures. We further demonstrate the role of bulges in determining the structure of a "Z-tile," a basic building block for nanostructures.

  2. The Demographics of Galactic Bulges in the SDSS Database

    Science.gov (United States)

    Kim, Keunho; Oh, Sree; Jeong, Hyunjin; Aragón-Salamanca, Alfonso; Smith, Rory; Yi, Sukyoung K.

    2016-07-01

    We present a new database of our two-dimensional bulge-disk decompositions for 14,233 galaxies drawn from Sloan Digital Sky Survey DR12 in order to examine the properties of bulges residing in the local universe (0.005 originate from the presence of young stars. The bulges in galaxies with low bulge-to-total ratios show signs of a frosting of young stars so substantial that their luminosity-weighted Balmer-line ages are as small as 1 Gyr in some cases. While bulges seem largely similar in optical properties to elliptical galaxies, they do show clear and systematic departures as a function of bulge-to-total ratio. The stellar properties and perhaps associated formation processes of bulges seem much more diverse than those of elliptical galaxies.

  3. Thermodynamic Spectrum of Solar Flares Based on SDO/EVE Observations: Techniques and First Results

    CERN Document Server

    Wang, Yuming; Zhang, Jie; Liu, Kai; Liu, Rui; Shen, Chenglong; Chamberlin, Phillip C

    2015-01-01

    SDO/EVE provide rich information of the thermodynamic processes of solar activities, particularly of solar flares. Here, we develop a method to construct thermodynamic spectrum (TDS) charts based on the EVE spectral lines. Reading from the charts, we are able to easily recognize if there is a late phase following a main phase of a flare, and able to learn the begin, peak and end times of the flare as well as the drift of the temperature, i.e., the cooling rate, of the heated plasma during the flare. Through four M-class flares of different types, we illustrate which thermodynamic information can be revealed from the TDS charts. Further, we investigate the TDS charts of all the flares greater than M5.0, and some interesting results are achieved. First, there are two distinct drift patterns, called Type I and Type II. For Type I flares, the enhanced emission drifts from high to low temperture, whereas for Type II flares, the drift is somewhat reversed, suggesting a more violent and durable heating during Type I...

  4. Thermodynamic Performance Evaluation of Gas Turbine Based on Tri-generation System

    Directory of Open Access Journals (Sweden)

    J. P. Yadav

    2013-02-01

    Full Text Available Thermodynamic analysis can be perfect tool for identifying the ways for improving the efficiency of fuel use, and determining the best configuration and equipment size for a Tri-generation plant. In this paper thermodynamic performance evaluation of gas turbine based on tri-generation system has been carried out. The operating parameter at inlet and outlet of each components involved in tri-generation system are determined. By using engineering equation solver (EES parameters like enthalpy, entropy, exergy; etc are determined. The system performance parameters (first law, second law efficiency and exergy are estimated with the help of these parameters. Parametric study has been done to investigate the effects of overall pressure ratio, turbine inlet temperature, and inlet air temperature on exergy destruction, first law efficiency, electrical to thermal energy ratio and second law efficiency of the components and overall system. The thermodynamic analysis shows the exergy destruction in combustion chamber and HRSG is significantly affected by the pressure ratio and TIT.

  5. Dephosphorization Thermodynamics of Crude Steel Using CaO-Based Flux

    Institute of Scientific and Technical Information of China (English)

    YANG Yin-dong; McKague A R; McLean A; Sommerville I D

    2003-01-01

    The experiments were carried out at 1 175-1 450 ℃ to study the phosphorus distribution ratio between molten CaO-based slags and carbon saturated hot metal. The phosphate capacity of the slags and the activity coefficient of PO2.5 were calculated from the phosphorus distribution ratio. The effect of addition of CaF2 and/or CaCl2 on the thermodynamic properties of slags was discussed. The correlation of optical basicity with phosphate capacity of slags was studied, and the dephosphorization ability of CaO-based fluxes with various additives was compared with the results from different studies.

  6. Red galaxies with pseudo-bulges in the SDSS: closer to disk galaxies or to classical bulges?

    CERN Document Server

    Ribeiro, B; Antón, S; Gomes, J M; Papaderos, P

    2015-01-01

    Pseudo-bulges are expected to markedly differ from classical, quasi-monolithically forming bulges in their star formation history (SFH) and chemical abundance patterns. To test this simple expectation, we carry out a comparative structural and spectral synthesis analysis of 106 red, massive galaxies issued from the SDSS, subdivided into bulgeless, pseudo-bulge and classical bulge galaxies according to their photometric characteristics, and further obeying a specific selection to minimize uncertainties in the analysis and ensure an unbiased derivation and comparison of SFHs. Our 2D photometry analysis suggests that disks underlying pseudo-bulges typically have larger exponential scale lengths than bulgeless galaxies, despite similar integral disk luminosities. Spectral synthesis models of the stellar emission within the 3" SDSS fiber aperture reveal a clear segregation of bulgeless and pseudo-bulge galaxies from classical bulges on the luminosity-weighted planes of age-metallicity and mass-metallicity, though ...

  7. Stochastic thermodynamics

    Science.gov (United States)

    Eichhorn, Ralf; Aurell, Erik

    2014-04-01

    'Stochastic thermodynamics as a conceptual framework combines the stochastic energetics approach introduced a decade ago by Sekimoto [1] with the idea that entropy can consistently be assigned to a single fluctuating trajectory [2]'. This quote, taken from Udo Seifert's [3] 2008 review, nicely summarizes the basic ideas behind stochastic thermodynamics: for small systems, driven by external forces and in contact with a heat bath at a well-defined temperature, stochastic energetics [4] defines the exchanged work and heat along a single fluctuating trajectory and connects them to changes in the internal (system) energy by an energy balance analogous to the first law of thermodynamics. Additionally, providing a consistent definition of trajectory-wise entropy production gives rise to second-law-like relations and forms the basis for a 'stochastic thermodynamics' along individual fluctuating trajectories. In order to construct meaningful concepts of work, heat and entropy production for single trajectories, their definitions are based on the stochastic equations of motion modeling the physical system of interest. Because of this, they are valid even for systems that are prevented from equilibrating with the thermal environment by external driving forces (or other sources of non-equilibrium). In that way, the central notions of equilibrium thermodynamics, such as heat, work and entropy, are consistently extended to the non-equilibrium realm. In the (non-equilibrium) ensemble, the trajectory-wise quantities acquire distributions. General statements derived within stochastic thermodynamics typically refer to properties of these distributions, and are valid in the non-equilibrium regime even beyond the linear response. The extension of statistical mechanics and of exact thermodynamic statements to the non-equilibrium realm has been discussed from the early days of statistical mechanics more than 100 years ago. This debate culminated in the development of linear response

  8. Are there carbon stars in the Bulge?

    CERN Document Server

    Ng, Y K

    1998-01-01

    The bulge carbon stars have been a mystery since their discovery, because they are about 2.5mag too faint to be regarded as genuine AGB stars, if located inside the metal-rich bulge (m-M=14.5mag). Part of the mystery can be solved if these carbon stars are related to the Sagittarius dwarf galaxy (SDG; m-M=17.0mag). They are in that case not old and metal-rich, but young, ~0.1 Gyr, with SMC-like metallicity. The sigma_RV=113+/-14 km/s radial velocity dispersion of the stars appears to be consistent with bulge membership. On the other hand, a similar velocity dispersion could be the result from an induced star formation event when the SDG crosses the galactic midplane. It is suggested that the carbon stars are tracers of such an event and that they therefore are located at distances related to the SDG. However, the majority of the carbon stars are not member of the SDG, nor are they similar to the C-stars which are member of the SDG. The radial velocities can be used to determine a possible membership to the SD...

  9. Manganese abundances in Galactic bulge red giants

    CERN Document Server

    Barbuy, B; Zoccali, M; Minniti, D; Renzini, A; Ortolani, S; Gomez, A; Trevisan, M; Dutra, N

    2013-01-01

    Manganese is mainly produced in type II SNe during explosive silicon burning, in incomplete Si-burning regions, and depends on several nucleosynthesis environment conditions, such as mass cut beween the matter ejected and falling back onto the remnant, electron and neutron excesses, mixing fallback, and explosion energy. Manganese is also produced in type Ia SNe. The aim of this work is the study of abundances of the iron-peak element Mn in 56 bulge giants, among which 13 are red clump stars. Four bulge fields along the minor axis are inspected. The study of abundances of Mn-over-Fe as a function of metallicity in the Galactic bulge may shed light on its production mechanisms. High-resolution spectra were obtained using the FLAMES+UVES spectrograph on the Very Large Telescope. The spectra were obtained within a program to observe 800 stars using the GIRAFFE spectrograph, together with the present UVES spectra. We aim at identifying the chemical evolution of manganese, as a function of metallicity, in the Gala...

  10. Mira variables in the Galactic bulge with OGLE-II data

    CERN Document Server

    Matsunaga, N; Nakada, Y

    2005-01-01

    We have extracted a total of 1968 Mira variables from the OGLE-II data base in the Galactic bulge region. Among them, 1960 are associated with 2MASS sources, and 1541 are further identified with MSX point sources. Their photometric properties are compared with those of Mira variables in the Large and Small Magellanic Clouds. We have found that mass-losing stars with circumstellar matter are reddened such that the colour dependence of the absorption coefficient is similar to that of interstellar matter. We also discuss the structure of the bulge. The surface number density of the bulge Mira variables is well correlated with the 2.2-micron surface brightness obtained by the COBE satellite. Using this relation, the total number of Mira variables in the bulge is estimated to be about 600,000. The logP-K relation of the Mira variables gives their space distribution which supports the well-known asymmetry of the bar-like bulge.

  11. Composite Bulges: The Coexistence of Classical Bulges and Disky Pseudobulges in S0 and Spiral Galaxies

    CERN Document Server

    Erwin, Peter; Fabricius, Maximilian; Thomas, Jens; Nowak, Nina; Rusli, Stephanie; Bender, Ralf; Beltran, Juan Carlos Vega; Beckman, John E

    2014-01-01

    We study nine S0-Sb galaxies with (photometric) bulges consisting of two distinct components. The outer component is a flattened, kinematically cool, disklike structure: a "disky pseudobulge". Embedded inside is a rounder, kinematically hot spheroid: a "classical bulge". This indicates that pseudobulges and classical bulges are not mutually exclusive: some galaxies have both. The disky pseudobulges almost always have an exponential disk (scale lengths = 125-870 pc, mean $\\sim 440$ pc) with disk-related subcomponents: nuclear rings, bars, and/or spiral arms. They constitute 11-59% of the galaxy stellar mass (mean PB/T = 0.33), with stellar masses $\\sim 7 \\times 10^{9}$-$9 \\times 10^{10} M_{\\odot}$. Classical-bulge components have Sersic indices of 0.9-2.2, effective radii of 25-430 pc and stellar masses of $5 \\times 10^{8}$-$3 \\times 10^{10} M_{\\odot}$ (usually < 10% of the galaxy's stellar mass; mean B/T = 0.06). The classical bulges show rotation, but are kinematically hotter than the disky pseudobulges. ...

  12. Thermodynamic contribution and nearest-neighbor parameters of pseudouridine-adenosine base pairs in oligoribonucleotides.

    Science.gov (United States)

    Hudson, Graham A; Bloomingdale, Richard J; Znosko, Brent M

    2013-11-01

    Pseudouridine (Ψ) is the most common noncanonical nucleotide present in naturally occurring RNA and serves a variety of roles in the cell, typically appearing where structural stability is crucial to function. Ψ residues are isomerized from native uridine residues by a class of highly conserved enzymes known as pseudouridine synthases. In order to quantify the thermodynamic impact of pseudouridylation on U-A base pairs, 24 oligoribonucleotides, 16 internal and eight terminal Ψ-A oligoribonucleotides, were thermodynamically characterized via optical melting experiments. The thermodynamic parameters derived from two-state fits were used to generate linearly independent parameters for use in secondary structure prediction algorithms using the nearest-neighbor model. On average, internally pseudouridylated duplexes were 1.7 kcal/mol more stable than their U-A counterparts, and terminally pseudouridylated duplexes were 1.0 kcal/mol more stable than their U-A equivalents. Due to the fact that Ψ-A pairs maintain the same Watson-Crick hydrogen bonding capabilities as the parent U-A pair in A-form RNA, the difference in stability due to pseudouridylation was attributed to two possible sources: the novel hydrogen bonding capabilities of the newly relocated imino group as well as the novel stacking interactions afforded by the electronic configuration of the Ψ residue. The newly derived nearest-neighbor parameters for Ψ-A base pairs may be used in conjunction with other nearest-neighbor parameters for accurately predicting the most likely secondary structure of A-form RNA containing Ψ-A base pairs.

  13. A Thermodynamic Approach to Predict Formation Enthalpies of Ternary Systems Based on Miedema's Model

    Science.gov (United States)

    Mousavi, Mahbubeh Sadat; Abbasi, Roozbeh; Kashani-Bozorg, Seyed Farshid

    2016-07-01

    A novel modification to the thermodynamic semi-empirical Miedema's model has been made in order to provide more precise estimations of formation enthalpy in ternary alloys. The original Miedema's model was modified for ternary systems based on surface concentration function revisions. The results predicted by the present model were found to be in excellent agreement with the available experimental data of over 150 ternary intermetallic compounds. The novel proposed model is capable of predicting formation enthalpies of ternary intermetallics with small discrepancies of ≤20 kJ/mol as well as providing reliable enthalpy variations.

  14. INDISIM-Paracoccus, an individual-based and thermodynamic model for a denitrifying bacterium.

    Science.gov (United States)

    Araujo Granda, Pablo; Gras, Anna; Ginovart, Marta; Moulton, Vincent

    2016-08-21

    We have developed an individual-based model for denitrifying bacteria. The model, called INDISIM-Paracoccus, embeds a thermodynamic model for bacterial yield prediction inside the individual-based model INDISIM, and is designed to simulate the bacterial cell population behavior and the product dynamics within the culture. The INDISIM-Paracoccus model assumes a culture medium containing succinate as a carbon source, ammonium as a nitrogen source and various electron acceptors such as oxygen, nitrate, nitrite, nitric oxide and nitrous oxide to simulate in continuous or batch culture the different nutrient-dependent cell growth kinetics of the bacterium Paracoccus denitrificans. The individuals in the model represent microbes and the individual-based model INDISIM gives the behavior-rules that they use for their nutrient uptake and reproduction cycle. Three previously described metabolic pathways for P. denitrificans were selected and translated into balanced chemical equations using a thermodynamic model. These stoichiometric reactions are an intracellular model for the individual behavior-rules for metabolic maintenance and biomass synthesis and result in the release of different nitrogen oxides to the medium. The model was implemented using the NetLogo platform and it provides an interactive tool to investigate the different steps of denitrification carried out by a denitrifying bacterium. The simulator can be obtained from the authors on request. PMID:27179457

  15. Methodology of Ni-base Superalloy Development for VHTR using Design of Experiments and Thermodynamic Calculation

    International Nuclear Information System (INIS)

    This work is concerning a methodology of Ni-base superalloy development for a very high temperature gas-cooled reactor(VHTR) using design of experiments(DOE) and thermodynamic calculations. Total 32 sets of the Ni-base superalloys with various chemical compositions were formulated based on a fractional factorial design of DOE, and the thermodynamic stability of topologically close-packed(TCP) phases of those alloys was calculated by using the THERMO-CALC software. From the statistical evaluation of the effect of the chemical composition on the formation of TCP phase up to a temperature of 950 .deg. C, which should be suppressed for prolonged service life when it used as the structural components of VHTR, 16 sets were selected for further calculation of the mechanical properties. Considering the yield and ultimate tensile strengths of the selected alloys estimated by using the JMATPRO software, the optimized chemical composition of the alloys for VHTR application, especially intermediate heat exchanger, was proposed for a succeeding experimental study

  16. Chemical evolution of the Galactic bulge as traced by microlensed dwarf and subgiant stars. IV. Two bulge populations

    CERN Document Server

    Bensby, T; Meléndez, J; Gould, A; Feltzing, S; Asplund, M; Johnson, J A; Lucatello, S; Yee, J C; Ramírez, I; Cohen, J G; Thompson, I; Gal-Yam, A; Sumi, T; Bond, I A

    2011-01-01

    [ABRIDGED] Based on high-resolution (R~42000 to 48000) and high signal-to-noise (S/N~50 to 150) spectra obtained with UVES/VLT, we present detailed elemental abundances (O, Na, Mg, Al, Si, Ca, Ti, Cr, Fe, Ni, Zn, Y, and Ba) and stellar ages for 26 microlensed dwarf and subgiant stars in the Galactic bulge. The analysis is based on equivalent width measurements and standard 1-D LTE MARCS model stellar atmospheres. We also present NLTE Li abundances based on line synthesis of the 7Li line at 670.8 nm. We show that the bulge metallicity distribution (MDF) is double-peaked; one peak at [Fe/H]= -0.6 and one at [Fe/H]=+0.3, and with a dearth of stars around solar metallicity. This is in contrast to the MDF derived from red giants in Baade's window, which peaks at this exact value. A simple significance test shows that it is extremely unlikely to have such a gap in the microlensed dwarf star MDF if the dwarf stars are drawn from the giant star MDF. To resolve this issue we discuss several possibilities, but we can n...

  17. Analysis of materials properties of niobium tube from the results of a virtual bulge test

    Science.gov (United States)

    Kim, H. S.; Sumption, Michael; Lim, H.; Collings, E. W.

    2012-06-01

    Hydroforming has been selected as a technique for the seamless fabrication of multicell superconducting radiofrequency (SRF) cavities. For the successful application of this technique to cavity fabrication, it is essential to understand deformation behavior of tubes under hydroforming conditions. Input to the finite-element modeling (FEM) which generally precedes the actual hydroforming process requires the constitutive properties of the tube material. This information may be obtained from the results of hydraulic bulge testing. The present paper provides an example of this activity. In order to verify the steps to be taken in analyzing future bulge-test data a circular argument recovers the original constitutive properties from the results of an FEM-based "virtual bulge test".

  18. Discovery of Five New R. Coronae Borealis Stars in the MACHO Galactic Bulge Database

    Energy Technology Data Exchange (ETDEWEB)

    Zaniewshi, A; Clayton, G C; Welch, D; Gordon, K D; Minniti, D; Cook, K

    2005-06-16

    We have identified five new R Coronae Borealis (RCB) stars in the Galactic bulge using the MACHO Project photometry database, raising the total number of known Galactic RCB stars to about 40. We have obtained spectra to confirm the identifications. The fact that four out of the five newly identified RCB stars are ''cool'' (T{sub eff} < 6000 K) rather than ''warm'' (T{sub eff} > 6000 K) suggests that the preponderance of warm RCB stars among the existing sample is a selection bias. These cool RCB stars are redder and fainter than their warm counterparts and may have been missed in surveys done with blue plates. Based on the number of new RCB stars discovered in the MACHO bulge fields, there may be {approx}250 RCB stars in the reddened ''exclusion'' zone toward the bulge.

  19. Orientation-specific cis complementation by bulge- and loop-mutated human immunodeficiency virus type 1 TAR RNAs.

    OpenAIRE

    Braddock, M; Powell, R; Sutton, J.; Kingsman, A J; Kingsman, S M

    1994-01-01

    Tat activates human immunodeficiency type 1 gene expression by binding to TAR RNA. TAR comprises a partially base paired stem and hexanucleotide loop with a tripyrimidine bulge in the upper stem. In vitro, Tat binds to the bulge and upper stem, with no requirement for the loop. However, in vivo, loop sequences are critical for activation, implying that a loop binding cellular factor may be involved in the activation pathway. Given that activation appears to be a two-component system comprisin...

  20. Red galaxies with pseudo-bulges in the SDSS: closer to disc galaxies or to classical bulges?

    Science.gov (United States)

    Ribeiro, B.; Lobo, C.; Antón, S.; Gomes, J. M.; Papaderos, P.

    2016-03-01

    Pseudo-bulges are expected to markedly differ from classical quasi-monolithically forming bulges in their star formation history (SFH) and chemical abundance patterns. To test this simple expectation, we carry out a comparative structural and spectral synthesis analysis of 106 red massive galaxies issued from the Sloan Digital Sky Survey (SDSS), sub-divided into bulgeless, pseudo-bulge and classical bulge galaxies according to their photometric characteristics, and further obeying a specific selection to minimize uncertainties in the analysis and ensure an unbiased derivation and comparison of SFHs. Our 2D photometry analysis suggests that discs underlying pseudo-bulges typically have larger exponential scalelengths than bulgeless galaxies, despite similar integral disc luminosities. Spectral synthesis models of the stellar emission within the 3-arcsec SDSS fibre aperture reveal a clear segregation of bulgeless and pseudo-bulge galaxies from classical bulges on the luminosity-weighted planes of age-metallicity and mass-metallicity, though a large dispersion is observed within the two former classes. The secular growth of pseudo-bulges is also reflected upon their cumulative stellar mass as a function of time, which is shallower than that for classical bulges. Such results suggest that the centres of bulgeless and pseudo-bulge galaxies substantially differ from those of bulgy galaxies with respect to their SFH and chemical enrichment history, which likely points to different formation/assembly mechanisms.

  1. An optimization method for gas refrigeration cycle based on the combination of both thermodynamics and entransy theory

    International Nuclear Information System (INIS)

    Highlights: • An optimization method for practical thermodynamic cycle is developed. • The entransy-based heat transfer analysis and thermodynamic analysis are combined. • Theoretical relation between system requirements and design parameters is derived. • The optimization problem can be converted into conditional extremum problem. • The proposed method provides several useful optimization criteria. - Abstract: A thermodynamic cycle usually consists of heat transfer processes in heat exchangers and heat-work conversion processes in compressors, expanders and/or turbines. This paper presents a new optimization method for effective improvement of thermodynamic cycle performance with the combination of entransy theory and thermodynamics. The heat transfer processes in a gas refrigeration cycle are analyzed by entransy theory and the heat-work conversion processes are analyzed by thermodynamics. The combination of these two analysis yields a mathematical relation directly connecting system requirements, e.g. cooling capacity rate and power consumption rate, with design parameters, e.g. heat transfer area of each heat exchanger and heat capacity rate of each working fluid, without introducing any intermediate variable. Based on this relation together with the conditional extremum method, we theoretically derive an optimization equation group. Simultaneously solving this equation group offers the optimal structural and operating parameters for every single gas refrigeration cycle and furthermore provides several useful optimization criteria for all the cycles. Finally, a practical gas refrigeration cycle is taken as an example to show the application and validity of the newly proposed optimization method

  2. Thermodynamic modeling of the La-Mg-Y system and Mg-based alloys database

    Institute of Scientific and Technical Information of China (English)

    DU Zhenmin; GUO Cuiping; LI Changrong; ZHANG Weijing

    2006-01-01

    As an example of the La-Mg-Y system, the method how to set up the thermodynamic model of individual phases was introduced in the process of thermodynamic optimization. The solution phases (liquid, body-centered cubic,face-centered cubic, hexagonal close-packed and double hexagonal close-packed) were modeled with the Redlich-Kister equation. The compound energy model has been used to describe the thermodynamic functions of the intermetallic compounds in the La-Mg-Y systems. The compounds Mg2Y, Mg24Y5, Mg12La, Mg17La2, Mg41La5, Mg3La and Mg2La in the La-Mg-Y system were treated as the formulae (Mg, Y)2(La,Mg, Y), Mg24(La,Mg, Y)4Y, Mg12(La, Y), Mg17(La, Y)2,Mg41(La,Y)5, Mg3(La,Mg,Y) and Mg2(La,Y), respectively. A model (La,Mg,Y)0.5(La,Mg,Y)0.5 was applied to describe the compound MgM formed by MgLa and MgY in order to cope with the order-disorder transition between body-centered cubic solution (A2) and MgM with CsCl-type structure (B2) in the La-Mg-Y system. The Gibbs energies of individual phases were optimized in the La-Mg, La-Y and La-Mg-Y systems by CALPHAD technique. The projection of the liquidus surfaces for the La-Mg-Y system was predicted. The Mg-based alloys database including 36 binary and 15 ternary systems formed by Mg, Al, Cu, Ni, Mn, Zn and rare earth elements was set up in SGTE standard.

  3. The effectiveness of problem-based learning on teaching the first law of thermodynamics

    Science.gov (United States)

    Tatar, Erdal; Oktay, Münir

    2011-11-01

    Background: Problem-based learning (PBL) is a teaching approach working in cooperation with self-learning and involving research to solve real problems. The first law of thermodynamics states that energy can neither be created nor destroyed, but that energy is conserved. Students had difficulty learning or misconceptions about this law. This study is related to the teaching of the first law of thermodynamics within a PBL environment. Purpose: This study examined the effectiveness of PBL on candidate science teachers' understanding of the first law of thermodynamics and their science process skills. This study also examined their opinions about PBL. Sample: The sample consists of 48 third-grade university students from the Department of Science Education in one of the public universities in Turkey. Design and methods: A one-group pretest-posttest experimental design was used. Data collection tools included the Achievement Test, Science Process Skill Test, Constructivist Learning Environment Survey and an interview with open-ended questions. Paired samples t-test was conducted to examine differences in pre/post tests. Results: The PBL approach has a positive effect on the students' learning abilities and science process skills. The students thought that the PBL environment supports effective and permanent learning, and self-learning planning skills. On the other hand, some students think that the limited time and unfamiliarity of the approach impede learning. Conclusions: The PBL is an active learning approach supporting students in the process of learning. But there are still many practical disadvantages that could reduce the effectiveness of the PBL. To prevent the alienation of the students, simple PBL activities should be applied from the primary school level. In order to overcome time limitations, education researchers should examine short-term and effective PBL activities.

  4. Searching for Bulges at the End of the Hubble Sequence

    CERN Document Server

    Böker, T; Van der Marel, R P; Boeker, Torsten; Stanek, Rebecca

    2003-01-01

    We investigate the stellar disk properties of a sample of 19 nearby spiral galaxies with low inclination and late Hubble type (Scd or later). We combine our high-resolution HST I-band observations with existing ground-based optical images to obtain surface brightness profiles that cover a high dynamic range of galactic radius. Most of these galaxies contain a nuclear star cluster, as discussed in a separate paper. The main goal of the present work is to constrain the properties of stellar bulges at these extremely late Hubble types. We find that the surface brightness profiles of the latest-type spirals are complex, with a wide range in shapes. We have sorted our sample in a sequence, starting with ``pure'' disk galaxies (approximately 30% of the sample). These galaxies have exponential stellar disks that extend inwards to within a few tens of pc from the nucleus, where the light from the nuclear cluster starts to dominate. They appear to be truly bulge-less systems. Progressing along the sequence, the galaxi...

  5. OGLE Atlas of Classical Novae I. Galactic Bulge Objects

    CERN Document Server

    Mroz, P; Poleski, R; Soszynski, I; Szymanski, M K; Pietrzynski, G; Wyrzykowski, L; Ulaczyk, K; Kozlowski, S; Pietrukowicz, P; Skowron, J

    2015-01-01

    Classical novae eruptions are possible sources of lithium formation and gamma-rays emission. The remnant systems of novae eruptions can also become Type Ia supernovae. The contribution of novae to these phenomena depends on nova rates that are not well established for the Galaxy. Here, we directly measure the Galactic bulge nova rate of $13.9 \\pm 2.6$ yr$^{-1}$. This measurement is much more accurate than any previous measurement of this kind thanks to multiple years of bulge monitoring by the OGLE survey. Our sample consists of 39 novae eruptions, $\\sim$1/3 of which are OGLE-based discoveries. The long-term monitoring allows us to not only measure the nova rate but also to study in detail the light curves of 39 eruptions and over 80 post-nova candidates. We measured orbital periods for 9 post-novae and 9 novae, in 14 cases we procured the first estimates. The OGLE survey is very sensitive to the frequently erupting recurrent novae. We did not found any object similar to M31 2008-12a, which erupts once a year...

  6. Proper Motions in the Galactic Bulge: Plaut's Window

    CERN Document Server

    Vieira, Katherine; Mendez, Rene A; Rich, R Michael; Girard, Terrence M; Korchagin, Vladimir I; van Altena, William; Majewski, Steven R; Bergh, Sidney van den

    2007-01-01

    A proper motion study of a field of 20' x 20' inside Plaut's low extinction window (l,b)=(0 deg,-8 deg), has been completed. Relative proper motions and photographic BV photometry have been derived for ~21,000 stars reaching to V~20.5 mag, based on the astrometric reduction of 43 photographic plates, spanning over 21 years of epoch difference. Proper motion errors are typically 1 mas/yr and field dependent systematics are below 0.2 mas/yr. Cross-referencing with the 2MASS catalog yielded a sample of ~8,700 stars, from which predominantly disk and bulge subsamples were selected photometrically from the JH color-magnitude diagram. The two samples exhibited different proper-motion distributions, with the disk displaying the expected reflex solar motion as a function of magnitude. Galactic rotation was also detected for stars between ~2 and ~3 kpc from us. The bulge sample, represented by red giants, has an intrinsic proper motion dispersion of (sigma_l,sigma_b)=(3.39, 2.91)+/-(0.11,0.09) mas/yr, which is in good...

  7. Stars and Planetary Nebulae in the Galactic Bulge

    CERN Document Server

    Cuisinier, F; Acker, A; Maciel, W J

    2000-01-01

    We compare the populations of Red Giant stars and Planetary Nebulae in the Galactic Bulge, in the light of recent determinations of their abundances patterns. We find both populations to be compatible. From the planetary nebulae, we find evidences that the Bulge did not form stars recently. The whole abundances pattern remains however puzzling, some elements favoring a quick evolution of the Galactic Bulge (Mg and Ti), and others a much slower one (He, O, Si, S, Ar and Ca).

  8. Developing and assessing research-based tools for teaching quantum mechanics and thermodynamics

    Science.gov (United States)

    Brown, Benjamin R.

    Research-based tools to educate college students in physics courses from introductory level to graduate level are essential for helping students with a diverse set of goals and backgrounds learn physics. This thesis explores issues related to student common difficulties with some topics in undergraduate quantum mechanics and thermodynamics courses. Student difficulties in learning quantum mechanics and thermodynamics are investigated by administering written tests and surveys to many classes and conducting individual interviews with a subset of students outside the class to unpack the cognitive mechanisms of the difficulties. The quantum mechanics research also focuses on using the research on student difficulties for the development and evaluation of a Quantum Interactive Learning Tutorial (QuILT) to help students learn about the time-dependence of expectation values using the context of Larmor precession of spin and evaluating the role of asking students to self-diagnose their mistakes on midterm examination on their performance on subsequent problem solving. The QuILT on Larmor precession of spin has both paper-pencil activities and a simulation component to help students learn these foundational issues in quantum mechanics. Preliminary evaluations suggest that the QuILT, which strives to help students build a robust knowledge structure of time-dependence of expectation values in quantum mechanics using a guided approach, is successful in helping students learn these topics in the junior-senior level quantum mechanics courses. The technique to help upper-level students in quantum mechanics courses effectively engage in the process of learning from their mistakes is also found to be effective. In particular, research shows that the self-diagnosis activity in upper-level quantum mechanics significantly helps students who are struggling and this activity can reduce the gap between the high and low achieving students on subsequent problem solving. Finally, a survey

  9. THERMODYNAMIC SPECTRUM OF SOLAR FLARES BASED ON SDO/EVE OBSERVATIONS: TECHNIQUES AND FIRST RESULTS

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yuming; Zhou, Zhenjun; Liu, Kai; Liu, Rui; Shen, Chenglong [CAS Key Laboratory of Geospace Environment, Department of Geophysics and Planetary Sciences, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhang, Jie [School of Physics, Astronomy and Computational Sciences, George Mason University, 4400 University Drive, MSN 6A2, Fairfax, VA 22030 (United States); Chamberlin, Phillip C., E-mail: ymwang@ustc.edu.cn [Solar Physics Laboratory, Heliophysics Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

    2016-03-15

    The Solar Dynamics Observatory (SDO)/EUV Variability Experiment (EVE) provides rich information on the thermodynamic processes of solar activities, particularly on solar flares. Here, we develop a method to construct thermodynamic spectrum (TDS) charts based on the EVE spectral lines. This tool could potentially be useful for extreme ultraviolet (EUV) astronomy to learn about the eruptive activities on distant astronomical objects. Through several cases, we illustrate what we can learn from the TDS charts. Furthermore, we apply the TDS method to 74 flares equal to or greater than the M5.0 class, and reach the following statistical results. First, EUV peaks are always behind the soft X-ray (SXR) peaks and stronger flares tend to have faster cooling rates. There is a power-law correlation between the peak delay times and the cooling rates, suggesting a coherent cooling process of flares from SXR to EUV emissions. Second, there are two distinct temperature drift patterns, called Type I and Type II. For Type I flares, the enhanced emission drifts from high to low temperature like a quadrilateral, whereas for Type II flares the drift pattern looks like a triangle. Statistical analysis suggests that Type II flares are more impulsive than Type I flares. Third, for late-phase flares, the peak intensity ratio of the late phase to the main phase is roughly correlated with the flare class, and the flares with a strong late phase are all confined. We believe that the re-deposition of the energy carried by a flux rope, which unsuccessfully erupts out, into thermal emissions is responsible for the strong late phase found in a confined flare. Furthermore, we show the signatures of the flare thermodynamic process in the chromosphere and transition region in the TDS charts. These results provide new clues to advance our understanding of the thermodynamic processes of solar flares and associated solar eruptions, e.g., coronal mass ejections.

  10. Trajectories of Cepheid variable stars in the Galactic nuclear bulge

    Science.gov (United States)

    Matsunaga, Noriyuki

    2012-06-01

    The central region of our Galaxy provides us with a good opportunity to study the evolution of galactic nuclei and bulges because we can observe various phenomena in detail at the proximity of 8 kpc. There is a hierarchical alignment of stellar systems with different sizes; from the extended bulge, the nuclear bulge, down to the compact cluster around the central supermassive blackhole. The nuclear bulge contains stars as young as a few Myr, and even hosts the ongoing star formation. These are in contrast to the more extended bulge which are dominated by old stars, ~10Gyr. It is considered that the star formation in the nuclear bulge is caused by fresh gas provided from the inner disk. In this picture, the nuclear bulge plays an important role as the interface between the gas supplier, the inner disk, and the galactic nucleus. Kinematics of young stars in the nuclear bulge is important to discuss the star forming process and the gas circulation in the Galactic Center. We here propose spectroscopic observations of Cepheid variable stars, ~25 Myr, which we recently discovered in the nuclear bulge. The spectra taken in this proposal will allow timely estimates of the systemic velocities of the variable stars.

  11. Which bulges are favoured by barred S0 galaxies?

    CERN Document Server

    Barway, Sudhanshu; Vaghmare, Kaustubh; Kembhavi, Ajit K

    2016-01-01

    S0 galaxies are known to host classical bulges with a broad range of size and mass, while some such S0s are barred and some not. The origin of the bars has remained as a long-standing problem -- what made bar formation possible in certain S0s? By analysing a large sample of S0s with classical bulges observed by the Spitzer space telescope, we find that most of our barred S0s host comparatively low-mass classical bulges, typically with bulge-to-total ratio ($B/T$) less than $0.5$; whereas S0s with more massive classical bulges than these do not host any bar. Furthermore, we find that amongst the barred S0s, there is a trend for the longer and massive bars to be associated with comparatively bigger and massive classical bulges -- possibly suggesting bar growth being facilitated by these classical bulges. In addition, we find that the bulge effective radius is always less than the bar effective radius --indicating an interesting synergy between the host classical bulge and bars being maintained while bar growth ...

  12. Kinematics and Composition of the Galactic Bulge: Recent Progress

    CERN Document Server

    Rich, R Michael; Reitzel, David B; Zhao, HongSheng; de Propris, Roberto

    2007-01-01

    We present recent results from a Keck study of the composition of the Galactic bulge, as well as results from the bulge Bulge Radial Velocity Assay (BRAVA). Culminating a 10 year investigation, Fulbright, McWilliam, & Rich (2006, 2007) solved the problem of deriving the iron abundance in the Galactic bulge, and find enhanced alpha element abundances, consistent with the earlier work of McWilliam & Rich (1994). We also report on a radial velocity survey of {\\sl 2MASS}-selected M giant stars in the Galactic bulge, observed with the CTIO 4m Hydra multi-object spectrograph. This program is to test dynamical models of the bulge and to search for and map any dynamically cold substructure in the Galactic bulge. We show initial results on fields at $-10^{\\circ} < l <+10^{\\circ}$ and $b=-4^{\\circ}$. We construct a longitude-velocity plot for the bulge stars and the model data, and find that contrary to previous studies, the bulge does not rotate as a solid body; from $-5^{\\circ}

  13. Ni-based Superalloy Development for VHTR - Methodology Using Design of Experiments and Thermodynamic Calculation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Woo; Kim, Dong Jin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-10-15

    In this work, to develop novel structural materials for the IHX of a VHTR, a more systematic methodology using the design of experiments (DOE) and thermodynamic calculations was proposed. For 32 sets of designs of Ni-Cr-Co-Mo alloys with minor elements of W and Ta, the mass fraction of TCP phases and mechanical properties were calculated, and finally the chemical composition was optimized for further experimental studies by applying the proposed . The highly efficient generation of electricity and the production of massive hydrogen are possible using a very high temperature gas-cooled reactor (VHTR) among generation IV nuclear power plants. The structural material for an intermediate heat exchanger (IHX) among numerous components should be endurable at high temperature of up to 950 .deg. C during long-term operation. Impurities inevitably introduced in helium as a coolant facilitate the material degradation by corrosion at high temperature. This work is concerning a methodology of Ni-Cr-Co-Mo based superalloy developed for VHTR using the design of experiments (DOE) and thermodynamic calculationsmethodology.

  14. An integrated optimization for organic Rankine cycle based on entransy theory and thermodynamics

    International Nuclear Information System (INIS)

    The organic Rankine cycle has been one of the essential heat-work conversion technologies nowadays. Lots of effectual optimization methods are focused on the promotion of the system efficiency, which are mainly relied on engineering experience and numerical simulations rather than theoretical analysis. A theoretical integrated optimization method was established based on the entransy theory and thermodynamics, with the ratio of the net power output to the ratio of the total thermal conductance to the thermal conductance in the condenser as the objective function. The system parameters besides the optimal pinch point temperature difference were obtained. The results show that the mass flow rate of the working fluid is inversely proportional to the evaporating temperature. An optimal evaporating temperature maximizes the net power output, and the maximal net power output corresponds to the maximal entransy loss and the change points of the heat source outlet temperature and the change rates for the entropy generation and the entransy dissipation. Moreover, the net power output and the total thermal conductance are inversely proportional to the pinch point temperature difference, contradicting with each other. Under the specified condition, the optimal operating parameters are ascertained, with the optimal pinch point temperature difference of 5 K. - Highlights: • We establish an integrated optimization model for organic Rankine cycle. • The model combines the entransy theory with thermodynamics. • The maximal net power output corresponds to the maximal entransy loss. • The pinch point temperature difference is optimized to be 5 K

  15. A Thermodynamically-consistent FBA-based Approach to Biogeochemical Reaction Modeling

    Science.gov (United States)

    Shapiro, B.; Jin, Q.

    2015-12-01

    Microbial rates are critical to understanding biogeochemical processes in natural environments. Recently, flux balance analysis (FBA) has been applied to predict microbial rates in aquifers and other settings. FBA is a genome-scale constraint-based modeling approach that computes metabolic rates and other phenotypes of microorganisms. This approach requires a prior knowledge of substrate uptake rates, which is not available for most natural microbes. Here we propose to constrain substrate uptake rates on the basis of microbial kinetics. Specifically, we calculate rates of respiration (and fermentation) using a revised Monod equation; this equation accounts for both the kinetics and thermodynamics of microbial catabolism. Substrate uptake rates are then computed from the rates of respiration, and applied to FBA to predict rates of microbial growth. We implemented this method by linking two software tools, PHREEQC and COBRA Toolbox. We applied this method to acetotrophic methanogenesis by Methanosarcina barkeri, and compared the simulation results to previous laboratory observations. The new method constrains acetate uptake by accounting for the kinetics and thermodynamics of methanogenesis, and predicted well the observations of previous experiments. In comparison, traditional methods of dynamic-FBA constrain acetate uptake on the basis of enzyme kinetics, and failed to reproduce the experimental results. These results show that microbial rate laws may provide a better constraint than enzyme kinetics for applying FBA to biogeochemical reaction modeling.

  16. Ni-based Superalloy Development for VHTR - Methodology Using Design of Experiments and Thermodynamic Calculation

    International Nuclear Information System (INIS)

    In this work, to develop novel structural materials for the IHX of a VHTR, a more systematic methodology using the design of experiments (DOE) and thermodynamic calculations was proposed. For 32 sets of designs of Ni-Cr-Co-Mo alloys with minor elements of W and Ta, the mass fraction of TCP phases and mechanical properties were calculated, and finally the chemical composition was optimized for further experimental studies by applying the proposed . The highly efficient generation of electricity and the production of massive hydrogen are possible using a very high temperature gas-cooled reactor (VHTR) among generation IV nuclear power plants. The structural material for an intermediate heat exchanger (IHX) among numerous components should be endurable at high temperature of up to 950 .deg. C during long-term operation. Impurities inevitably introduced in helium as a coolant facilitate the material degradation by corrosion at high temperature. This work is concerning a methodology of Ni-Cr-Co-Mo based superalloy developed for VHTR using the design of experiments (DOE) and thermodynamic calculationsmethodology

  17. Simulation of nonisothermal consolidation of saturated soils based on a thermodynamic model.

    Science.gov (United States)

    Zhang, Zhichao; Cheng, Xiaohui

    2013-01-01

    Based on the nonequilibrium thermodynamics, a thermo-hydro-mechanical coupling model for saturated soils is established, including a constitutive model without such concepts as yield surface and flow rule. An elastic potential energy density function is defined to derive a hyperelastic relation among the effective stress, the elastic strain, and the dry density. The classical linear non-equilibrium thermodynamic theory is employed to quantitatively describe the unrecoverable energy processes like the nonelastic deformation development in materials by the concepts of dissipative force and dissipative flow. In particular the granular fluctuation, which represents the kinetic energy fluctuation and elastic potential energy fluctuation at particulate scale caused by the irregular mutual movement between particles, is introduced in the model and described by the concept of granular entropy. Using this model, the nonisothermal consolidation of saturated clays under cyclic thermal loadings is simulated in this paper to validate the model. The results show that the nonisothermal consolidation is heavily OCR dependent and unrecoverable. PMID:23983623

  18. The GIRAFFE Inner Bulge Survey (GIBS) III. Metallicity distributions and kinematics of 26 Galactic bulge fields

    CERN Document Server

    Zoccali, M; Gonzalez, O A; Valenti, E; Rojas-Arriagada, A; Minniti, J; Rejkuba, M; Minniti, D; McWilliam, A; Babusiaux, C; Hill, V; Renzini, A

    2016-01-01

    Several recent studies have demonstrated that the Galactic bulge hosts two components with different mean metallicities, and possibly different spatial distribution and kinematics. As a consequence, both the metallicity distribution and the radial velocity of bulge stars vary across different line of sights. We present here the metallicity distribution function of red clump stars in 26 fields spread across a wide area of the bulge, with special emphasis on fields close to Galactic plane, at latitudes b=-2 and b=-1, that were not explored before. This paper includes new metallicities from a sample of about 5000 K giant stars, observed at spectral resolution R=6500, in the Calcium II Triplet region. They are the main dataset of the GIRAFFE Inner Bulge Survey. As part of the same survey we have previously published results for a sample of about 600 K giant stars, at latitude b=-4 , derived from higher resolution spectra (R=22,500). Results. The combined sample allows us to trace and characterize the metal poor a...

  19. Bulges of disk galaxies at intermediate redshifts. I. Samples with and without bulges in the Groth Strip Survey

    OpenAIRE

    L. Domínguez Palmero; M. Balcells; Erwin, P; Prieto, M.; Cristóbal Hornillos, D.; Eliche Moral, María del Carmen; Guzmán, R.

    2008-01-01

    Context. Analysis of bulges to redshifts of up to z∽1 have provided ambiguous results as to whether bulges as a class are old structures akin to elliptical galaxies or younger products of the evolution of their host disks. Aims. We aim to define a sample of intermediate-z disk galaxies harbouring central bulges, and a complementary sample of disk galaxies without measurable bulges. We intend to provide colour profiles for both samples, as well as measurements of nuclear, disk, and global colo...

  20. Solvation thermodynamics

    CERN Document Server

    Ben-Naim, Arieh

    1987-01-01

    This book deals with a subject that has been studied since the beginning of physical chemistry. Despite the thousands of articles and scores of books devoted to solvation thermodynamics, I feel that some fundamen­ tal and well-established concepts underlying the traditional approach to this subject are not satisfactory and need revision. The main reason for this need is that solvation thermodynamics has traditionally been treated in the context of classical (macroscopic) ther­ modynamics alone. However, solvation is inherently a molecular pro­ cess, dependent upon local rather than macroscopic properties of the system. Therefore, the starting point should be based on statistical mechanical methods. For many years it has been believed that certain thermodynamic quantities, such as the standard free energy (or enthalpy or entropy) of solution, may be used as measures of the corresponding functions of solvation of a given solute in a given solvent. I first challenged this notion in a paper published in 1978 b...

  1. Nitridation of Ni-based alloys: thermodynamics, kinetics, and deformation phenomena accompanying internal precipitation

    Institute of Scientific and Technical Information of China (English)

    Alexander A. Kodentsov; Jorma K. Kivilahti; Frans J.J. van Loo

    2006-01-01

    When a moderately stable phase is precipitated out during an internal reaction, the behaviour of the penetrating atoms within the diffusion zone can be interpreted based on thermodynamic considerations. Evidence for "up-hill" diffusion of the penetrating species through the matrix towards the precipitation front during the internal nitridation of Ni-Cr alloys at 1125℃ and 6000 bar of N2-pressure was predicted. Such behaviour of nitrogen is opposite to the boundary conditions in Wagner's description of internal reactions. A volume change associated with the precipitation reaction resulted in a stress gradient between the alloys surface and the internal nitridation front. Stress relief occurred mainly by transport of nickel to the gas/metal interface. Pipe diffusion-controlled creep is the dominant stress accommodation mechanism during nitriding of dilute Ni-Cr alloys at 700℃ under a flowing NH3 + H2 gas mixture.

  2. Modelling the spreading rate of controlled communicable epidemics through an entropy-based thermodynamic model

    CERN Document Server

    Wang, W B; Cao, Z M; Hu, R F

    2013-01-01

    A model based on a thermodynamic approach is proposed for predicting the dynamics of communicable epidemics in a city, when the epidemic is governed by controlling efforts of multiple scales so that an entropy is associated with the system. All the epidemic details are factored into a single parameter that is determined by maximizing the rate of entropy production. Despite the simplicity of the final model, it predicts the number of hospitalized cases with a reasonable accuracy, using the data of SARS of the year 2003, once the inflexion point characterizing the effect of multiple controlling efforts is known. This model is supposed to be of potential usefulness since epidemics such as avian influenza like H7H9 in China this year have the risk to become communicable among human beings.

  3. Thermodynamics of Imidazolium-Based Ionic Liquids Containing PF6 Anions.

    Science.gov (United States)

    Zaitsau, Dzmitry H; Yermalayeu, Andrei V; Emel'yanenko, Vladimir N; Butler, Simon; Schubert, Thomas; Verevkin, Sergey P

    2016-08-18

    Imidazolium-based ionic liquids (ILs) with PF6(-) anions are considered as low-cost solvents for separation processes, but they exhibit restricted thermal stabilities. Reliable measurements of vaporization thermodynamics by conventional methods have failed. In this work, we applied a quartz-crystal microbalance method to determine for the first time the absolute vapor pressures for the [Cnmim][PF6] family, with n = 2, 4, 6, 8, and 10, in the temperature range 403-461 K. An absence of decomposition of ILs in experimental conditions was determined by the attenuated total reflection-infrared spectroscopy. The consistency of the experimental results within the homologous series was established through enthalpy and entropy analyses of the liquid and gas phases as well as by molecular dynamics simulations. PMID:27462931

  4. Thermodynamic Properties of Hard-Sphere Fluid under Confined Condition Based on Bridge Density Function

    Institute of Scientific and Technical Information of China (English)

    周世琦

    2003-01-01

    Based on the functional integral procedure, a recently proposed bridge density function [J. Chem. Phys. 112 (2000) 8079] is developed to calculate global thermodynamic properties of non-uniform fluids. The resulting surface tension of a hard wall-hard sphere interface as a function of the bulk hard sphere fluid density is in good agreement with the available simulation data. The proposed numerical procedure from the approximation of non-uniform first=order direct correlation function to a non=uniform system with excess Helmholtz free energy is of fundamental importance for phase behaviour under the confined condition due to the fact that many available simple approximations in classical density functional theory are for non=uniform first=order direct correlation function.

  5. Thermodynamic Feasibility of Hydrogen-Rich Gas Production Supported by Iron Based Chemical Looping Process

    Directory of Open Access Journals (Sweden)

    Grzegorz Słowiński

    2016-01-01

    Full Text Available The continuously increasing oil prices as well as stronger environmental regulations regarding greenhouse emissions made the greatest economic powers search a new, price competitive, and environment friendly energy carrier, such as hydrogen. The world research activities in these terms focus on the development of integrated hydrogen and power generating technologies, particularly technologies of hydrogen production from various carbonaceous resources, like methane, coal, biomass, or waste, often combined with carbon dioxide capture. In the paper the thermodynamic analysis of the enhancement of hydrogen production in iron based chemical looping process is presented. In this method, iron oxide is first reduced to iron with a reducing agent, such as carbon oxide, hydrogen, or mixture of both gases (synthesis gas, and then, in the inverse reaction with steam, it is regenerated to iron oxide, and pure stream of hydrogen is produced.

  6. Thermodynamics of several lewis-acid-base stabilized transition metal alloys

    Science.gov (United States)

    Gibson, John K.; Brewer, Leo; Gingerich, Karl A.

    1984-11-01

    High-temperature (1425 to 2750 K) thermodynamic activities of one or both components of twenty-five binary alloys of a group IVB-VIB element (Ti, Zr, Hf, Nb, Ta, or W) with a platinum group element (Ru, Os, Ir, Pd, Pt, or Au) have been determined by equilibrating the alloy with the appropriate carbide and graphite, equilibrating with the nitride and nitrogen gas, or measuring the partial vapor pressure(s) thermogravimetrically or mass spectrometrically. The extraordinary stability of this class of transition metal alloy is attributed to a generalized Lewis-acid-base interaction involving valence d electrons, and the results of these investigations are interpreted within the context of this effect. Among the conclusions made are that a non-spherically-symmetrical crystal field significantly reduces the bonding effectiveness of certain valence d orbitals; the effect of the extent of derealization of these orbitals is also considered.

  7. A novel construction of thermodynamically compatible models and its correspondence with Boltzmann-equation-based moment-closure hierarchies

    Science.gov (United States)

    Hong, Liu; Yang, Zaibao; Zhu, Yi; Yong, Wen-An

    2015-12-01

    In this article, we propose a novel approach to construct macroscopic balance equations and constitutive equations describing various irreversible phenomena. It is based on the general principles of non-equilibrium thermodynamics and consists of four basic steps: picking suitable state variables, choosing a strictly concave entropy function, properly separating entropy fluxes and production rates, and determining a dissipation matrix. Our approach takes advantage of both extended irreversible thermodynamics and GENERIC formalisms and shows a direct correspondence with Levermore's moment-closure hierarchies for the Boltzmann equation. As a direct application, a new ten-moment model beyond the classical hierarchies is constructed and is shown to recover the Euler equations in the equilibrium state. These interesting results may put various macroscopic modeling approaches, starting from the general principles of non-equilibrium thermodynamics, on a solid microscopic foundation based on the Boltzmann equation.

  8. Bars rejuvenating bulges? Evidence from stellar population analysis

    CERN Document Server

    Coelho, Paula

    2011-01-01

    We obtained stellar ages and metallicities via spectrum fitting for a sample of 575 bulges with spectra available from the Sloan Digital Sky Survey. The structural properties of the galaxies have been studied in detail in Gadotti (2009b) and the sample contains 251 bulges in galaxies with bars. Using the whole sample, where galaxy stellar mass distributions for barred and unbarred galaxies are similar, we find that bulges in barred and unbarred galaxies occupy similar loci in the age vs. metallicity plane. However, the distribution of bulge ages in barred galaxies shows an excess of populations younger than ~ 4 Gyr, when compared to bulges in unbarred galaxies. Kolmogorov-Smirnov statistics confirm that the age distributions are different with a significance of 99.94%. If we select sub-samples for which the bulge stellar mass distributions are similar for barred and unbarred galaxies, this excess vanishes for galaxies with bulge mass log M < 10.1 M_Sun while for more massive galaxies we find a bimodal bulg...

  9. The Galactic Bulge The Stellar and Planetary Nebulae Populations

    CERN Document Server

    Cuisinier, F; Acker, A; Maciel, W J

    2001-01-01

    We compare abundances patterns in the Bulge for elements observed in stars and in planetary nebulae. Some alpha elements, like Mg and Ti, are overabundant respect to Fe, and others are not, like He, O, Si, S, Ar, Ca. The first ones favor a quick evolution of the Galactic Bulge, and the seconds a much slower one.

  10. Surface photometry of bulge dominated low surface brightness galaxies

    NARCIS (Netherlands)

    Beijersbergen, M; de Blok, WJG; van der Hulst, JM

    1999-01-01

    We present results of broad band BVRI observations of a sample of galaxies with a low surface brightness (LSB) disk and a bulge. These galaxies are well described as exponential disks and exponential bulges with no preferred value for either scale length or central surface brightness. The median B b

  11. Bulge-driven Fueling of Seed Black Holes

    CERN Document Server

    Park, KwangHo; Natarajan, Priyamvada; Bogdanović, Tamara; Wise, John H

    2015-01-01

    We examine radiation-regulated accretion onto intermediate-mass and massive black holes (BHs) embedded in a bulge component. Using spherically symmetric one-dimensional radiation-hydrodynamics simulations, we track the growth of BHs accreting from a cold, neutral gas reservoir with temperature T=10^4 K. We find that the accretion rate of BHs embedded in bulges is proportional to r_{B,eff}/r_B, where r_{B,eff} is the increased effective Bondi radius that includes the gravitational potential of the bulge, and r_B is the Bondi radius of the BH. The radiative feedback from the BH suppresses the cold accretion rate to ~1 percent of the Bondi rate when a bulge is not considered. However, we find that the BH fueling rate increases rapidly when the bulge mass M_bulge is greater than the critical value of 10^6 M_sun and is proportional to M_bulge. Since the critical bulge mass is independent of the central BH mass M_{BH}, the growth rate of BHs with masses of 10^2, 10^4, and 10^6 M_sun exhibits distinct dependencies o...

  12. Bulges and discs of spiral galaxies: edge-on perspective

    CERN Document Server

    Sotnikova, N Ya; Mosenkov, A V

    2010-01-01

    We present a sample of edge-on spiral galaxies both of early and late types.The sample consists of 175 galaxies in the Ks-filter, 169 galaxies in the H-filter and 165 galaxies in the J-filter. Bulge and disc decompositions of each galaxy image, taken from the Two Micron All Sky Survey (2MASS), were performed. We discuss several scaling relations for bulges and discs which indicate a tight link between their formation and evolution. We show that galaxies with bulges fitted by the Sersic index n=2 bulges (classical bulges). First of all, the distribution of the apparent bulge axis ratio q_b for the subsample with n=2 bulges seem to be oblate spheroids with moderate flattening. Secondly, the Photometric Plane of the sample bulges is not flat and has a prominent curvature towards small values of n. Thirdly, despite of the existence of a clear relation between the flattening of stellar discs h/z_0 and the relative mass of a spherical component, the distributions over both parameters are quite different for galaxie...

  13. The bulge luminosity for low-mass black holes

    CERN Document Server

    Jiang, Yanfei; Ho, Luis

    2011-01-01

    We study the scaling between bulge magnitude and central black hole (BH) mass in galaxies with virial BH masses 10^7 solar mass. Specfically, bulges span a much wider range of bulge luminosity, and on average the luminosity is larger, at fixed black hole mass. The trend holds both for the active galaxies from Bentz et al. and the inactive sample of Gultekin et al. and cannot be explained by differences in stellar populations, as it persists when we use dynamical bulge masses. Put another way, the ratio between bulge and BH mass is much larger than $\\sim 1000$ for our sample. This is consistent with recent suggestions that black hole mass does not scale with the pseudobulge luminosity. The low-mass scaling relations appear to flatten, consistent with predictions from Volonteri & Natarajan for massive seed BHs.

  14. lncRNATargets: A platform for lncRNA target prediction based on nucleic acid thermodynamics.

    Science.gov (United States)

    Hu, Ruifeng; Sun, Xiaobo

    2016-08-01

    Many studies have supported that long noncoding RNAs (lncRNAs) perform various functions in various critical biological processes. Advanced experimental and computational technologies allow access to more information on lncRNAs. Determining the functions and action mechanisms of these RNAs on a large scale is urgently needed. We provided lncRNATargets, which is a web-based platform for lncRNA target prediction based on nucleic acid thermodynamics. The nearest-neighbor (NN) model was used to calculate binging-free energy. The main principle of NN model for nucleic acid assumes that identity and orientation of neighbor base pairs determine stability of a given base pair. lncRNATargets features the following options: setting of a specific temperature that allow use not only for human but also for other animals or plants; processing all lncRNAs in high throughput without RNA size limitation that is superior to any other existing tool; and web-based, user-friendly interface, and colored result displays that allow easy access for nonskilled computer operators and provide better understanding of results. This technique could provide accurate calculation on the binding-free energy of lncRNA-target dimers to predict if these structures are well targeted together. lncRNATargets provides high accuracy calculations, and this user-friendly program is available for free at http://www.herbbol.org:8001/lrt/ . PMID:27306075

  15. A minimal dissipation type-based classification in irreversible thermodynamics and microeconomics

    Science.gov (United States)

    Tsirlin, A. M.; Kazakov, V.; Kolinko, N. A.

    2003-10-01

    We formulate the problem of finding classes of kinetic dependencies in irreversible thermodynamic and microeconomic systems for which minimal dissipation processes belong to the same type. We show that this problem is an inverse optimal control problem and solve it. The commonality of this problem in irreversible thermodynamics and microeconomics is emphasized.

  16. A Minimal Dissipation Type-Based Classification in Irreversible Thermodynamics and Microeconomics

    OpenAIRE

    A. M. Tsirlin; Valdimir Kazakov; N. A. Kolinko

    2003-01-01

    We formulate the problem of finding classes of kinetic dependencies in irreversible thermodynamic and microeconomic systems for which minimal dissipation processes belong to the same type. We show that this problem is an inverse optimal control problem and solve it. The commonality of this problem in irreversible thermodynamics and microeconomics is emphasized.

  17. A Practical and Fast Method To Predict the Thermodynamic Preference of ω-Transaminase-Based Transformations

    DEFF Research Database (Denmark)

    Meier, Robert J.; Gundersen, Maria T.; Woodley, John;

    2015-01-01

    A simple, easy-to-use, and fast approach method is proposed and validated that can predict whether a transaminase reaction is thermodynamically unfavourable. This allowed us to de-select, in the present case, at least 50% of the reactions because they were thermodynamically unfavourable as confir...

  18. A Practical and Fast Method To Predict the Thermodynamic Preference of omega-Transaminase-Based Transformations

    DEFF Research Database (Denmark)

    Meier, Robert J.; Gundersen Deslauriers, Maria; Woodley, John;

    2015-01-01

    A simple, easy-to-use, and fast approach method is proposed and validated that can predict whether a transaminase reaction is thermodynamically unfavourable. This allowed us to de-select, in the present case, at least 50% of the reactions because they were thermodynamically unfavourable as confir...

  19. Thermodynamically based solvent design for enzymatic saccharide acylation with hydroxycinnamic acids in non-conventional media.

    Science.gov (United States)

    Zeuner, Birgitte; Kontogeorgis, Georgios M; Riisager, Anders; Meyer, Anne S

    2012-02-15

    Enzyme-catalyzed synthesis has been widely studied with lipases (EC 3.1.1.3), but feruloyl esterases (FAEs; EC 3.1.1.73) may provide advantages such as higher substrate affinity and regioselectivity in the synthesis of hydroxycinnamate saccharide esters. These compounds are interesting because of their amphiphilicity and antioxidative potential. Synthetic reactions using mono- or disaccharides as one of the substrates may moreover direct new routes for biomass upgrading in the biorefinery. The paper reviews the available data for enzymatic hydroxycinnamate saccharide ester synthesis in organic solvent systems as well as other enzymatic hydroxycinnamate acylations in ionic liquid systems. The choice of solvent system is highly decisive for enzyme stability, selectivity, and reaction yields in these synthesis reactions. To increase the understanding of the reaction environment and to facilitate solvent screening as a crucial part of the reaction design, the review explores the use of activity coefficient models for describing these systems and - more importantly - the use of group contribution model UNIFAC and quantum chemistry based COSMO-RS for thermodynamic predictions and preliminary solvent screening. Surfactant-free microemulsions of a hydrocarbon, a polar alcohol, and water are interesting solvent systems because they accommodate different substrate and product solubilities and maintain enzyme stability. Ionic liquids may provide advantages as solvents in terms of increased substrate and product solubility, higher reactivity and selectivity, as well as tunable physicochemical properties, but their design should be carefully considered in relation to enzyme stability. The treatise shows that thermodynamic modeling tools for solvent design provide a new toolbox to design enzyme-catalyzed synthetic reactions from biomass sources. PMID:22154740

  20. Formulation based on artificial neural network of thermodynamic properties of ozone friendly refrigerant/absorbent couples

    International Nuclear Information System (INIS)

    This paper presents a new approach based on artificial neural networks (ANNs) to determine the properties of liquid and two phase boiling and condensing of two alternative refrigerant/absorbent couples (methanol/LiBr and methanol/LiCl). These couples do not cause ozone depletion and use in the absorption thermal systems (ATSs). ANNs are able to learn the key information patterns within multidimensional information domain. ANNs operate such as a 'black box' model, requiring no detailed information about the system. On the other hand, they learn the relationship between the input and the output. In order to train the neural network, limited experimental measurements were used as training data and test data. In this study, in input layer, there are temperatures in the range of 298-498 K, pressures (0.1-40 MPa) and concentrations of 2%, 7%, 12% of the couples; specific volume is in output layer. The back-propagation learning algorithm with three different variants, namely scaled conjugate gradient (SCG), Pola-Ribiere conjugate gradient (CGP), and Levenberg-Marquardt (LM), and logistic sigmoid transfer function were used in the network so that the best approach can find. The most suitable algorithm and neuron number in the hidden layer are found as SCG with 8 neurons. For this number level, after the training, it is found that maximum error is less than 3%, average error is about 1% and R2 value are 99.999%. As seen from the results obtained the thermodynamic equations for each pair by using the weights of network have been obviously predicted within acceptable errors. This paper shows that values predicted with ANN can be used to define the thermodynamic properties instead of approximate and complex analytic equations

  1. Thermodynamics and Kinetics of DNA Tile-Based Self-Assembly

    Science.gov (United States)

    Jiang, Shuoxing

    Deoxyribonucleic acid (DNA) has emerged as an attractive building material for creating complex architectures at the nanometer scale that simultaneously affords versatility and modularity. Particularly, the programmability of DNA enables the assembly of basic building units into increasingly complex, arbitrary shapes or patterns. With the expanding complexity and functionality of DNA toolboxes, a quantitative understanding of DNA self-assembly in terms of thermodynamics and kinetics, will provide researchers with more subtle design guidelines that facilitate more precise spatial and temporal control. This dissertation focuses on studying the physicochemical properties of DNA tile-based self-assembly process by recapitulating representative scenarios and intermediate states with unique assembly pathways. First, DNA double-helical tiles with increasing flexibility were designed to investigate the dimerization kinetics. The higher dimerization rates of more rigid tiles result from the opposing effects of higher activation energies and higher pre-exponential factors from the Arrhenius equation, where the pre-exponential factor dominates. Next, the thermodynamics and kinetics of single tile attachment to preformed "multitile" arrays were investigated to test the fundamental assumptions of tile assembly models. The results offer experimental evidences that double crossover tile attachment is determined by the electrostatic environment and the steric hindrance at the binding site. Finally, the assembly of double crossover tiles within a rhombic DNA origami frame was employed as the model system to investigate the competition between unseeded, facet and seeded nucleation. The results revealed that preference of nucleation types can be tuned by controlling the rate-limiting nucleation step. The works presented in this dissertation will be helpful for refining the DNA tile assembly model for future designs and simulations. Moreover, The works presented here could also be

  2. Computer Based Thermodynamic Properties of Ammonia-Water Mixture for the Analysis of Power and Refrigeration Cycles

    Directory of Open Access Journals (Sweden)

    Kausik Sadhukhan

    2012-06-01

    Full Text Available The thermodynamic analysis and optimization of combined power and refrigeration cycle as well as the improved vapour absorption refrigeration system necessitate the development of computer based thermodynamic properties of ammonia-water mixture. In this work, a computer code has been developed for the thermodynamic properties of ammonia water mixture for different pressures, temperatures and ammonia mass fraction concentration. This has been achieved by using some exact thermodynamic relations and some co-relations available in the literature. The computed results have been compared with the published experimental data and the agreement is found to be of good accuracy. The errors in the computed results for different thermodynamic properties are slightly more at comparatively high pressure and temperature. The maximum error is found to be with saturated liquid mixture entropy and its value is also less then 3.8% even at a high pressure of 34.47 bar.

  3. Finite Element Analysis of Bulge Forming of Laser Welding Dimple Jacket

    Directory of Open Access Journals (Sweden)

    Peisi ZHONG

    2015-11-01

    Full Text Available The stress-strain states of the model of laser welded dimple jacket is analyzed using ANSYS/LS-DYNA in order to determine the relation between bulging height and pressure and to achieve the controllability of pressure distension of the jacket. It is shown that in the same conditions, the bulging height increases with the increasing of the bulging pressure and the space of honeycomb. And it will decrease when the thickness of jacket plate changing larger. A table showing the relation between bulging height and pressure is obtained. An experiment using a test panel is conducted to certify the reliability of finite element analysis. It turns out that the data of finite element analysis is coincident with experimental data, which support finite element method based ANSYS/LS-DYNA can be an efficient way to research the laser welded dimple jacket. The relation table is useful as guidance for the fabrication process.DOI: http://dx.doi.org/10.5755/j01.ms.21.4.9704

  4. Light, Alpha, and Fe-Peak Element Abundances in the Galactic Bulge

    CERN Document Server

    Johnson, Christian I; Kobayashi, Chiaki; Kunder, Andrea; Koch, Andreas

    2014-01-01

    We present radial velocities and chemical abundances of O, Na, Mg, Al, Si, Ca, Cr, Fe, Co, Ni, and Cu for a sample of 156 red giant branch stars in two Galactic bulge fields centered near (l,b)=(+5.25,-3.02) and (0,-12). The (+5.25,-3.02) field also includes observations of the bulge globular cluster NGC 6553. The results are based on high resolution (R~20,000), high signal-to-noise (S/N>70) FLAMES-GIRAFFE spectra obtained through the ESO archive. However, we only selected a subset of the original observations that included spectra with both high S/N and that did not show strong TiO absorption bands. The present work extends previous analyses of this data set beyond Fe and the alpha-elements Mg, Si, Ca, and Ti. While we find reasonable agreement with past work, the data presented here indicate that the bulge may exhibit a different chemical composition than the local thick disk, especially at [Fe/H]>-0.5. In particular, the bulge [alpha/Fe] ratios may remain enhanced to a slightly higher [Fe/H] than the thick...

  5. The Kinematic Signature of Face-On Peanut-Shaped Bulges

    CERN Document Server

    Debattista, V P; Mayer, L; Moore, B; Debattista, Victor P.; Mayer, Lucio

    2005-01-01

    We present a kinematic diagnostic for peanut-shaped bulges in nearly face-on galaxies. The face-on view provides a novel perspective on peanuts which would allow study of their relation to bars and disks in greater detail than hitherto possible. The diagnostic is based on the fact that peanut shapes are associated with a flat density distribution in the vertical direction. We show that the kinematic signature corresponding to such a distribution is a minimum in the fourth-order Gauss-Hermite moment $s_4$. We demonstrate our method on $N$-body simulations of varying peanut strength, showing that strong peanuts can be recognized to inclinations $i \\simeq 30\\degrees$, regardless of the strength of the bar. We also consider compound systems in which a bulge is present in the initial conditions as may happen if bulges form at high redshift through mergers. We show that in this case, because the vertical structure of the bulge is not derived from that of the disk, that the signature of a peanut in $s_4$ is weakened...

  6. Thermodynamic study and modelling of iron-based melts for adequate prediction of modern ladle metallurgy processes

    Science.gov (United States)

    Zaitsev, A. I.; Rodionova, I. G.; Shaposhnikov, N. G.; Zemlyanko, O. A.; Karamisheva, N. A.

    2008-02-01

    The representation of iron-based melts as associated liquids have been developed basing on the detail experimental investigation and analysis of available data on their thermodynamic properties and phase equilibria. It has allowed, for the first time, to interpret adequately the reactivity of the earth metals in the iron-based melts and to predict with high precision the reactions of metal refinement and non-metallic inclusions modifying in modern ladle metallurgy.

  7. Surface thermodynamics

    International Nuclear Information System (INIS)

    Basic thermodynamics of a system consisting of two bulk phases with an interface. Solid surfaces: general. Discussion of experimental data on surface tension and related concepts. Adsorption thermodynamics in the Gibbsian scheme. Adsorption on inert solid adsorbents. Systems with electrical charges: chemistry and thermodynamics of imperfect crystals. Thermodynamics of charged surfaces. Simple models of charge transfer chemisorption. Adsorption heat and related concepts. Surface phase transitions

  8. A Connection Between Bulge Properties and the Bimodality of Galaxies

    CERN Document Server

    Drory, Niv

    2007-01-01

    The global colors of galaxies have recently been shown to follow bimodal distributions. Galaxies separate into a ``red sequence'', populated prototypically by early-type galaxies, and a ``blue cloud'', whose typical objects are late-type disk galaxies. Intermediate-type (Sa-Sbc) galaxies populate both regions. It has been suggested that this bimodality reflects the two-component nature of disk-bulge galaxies. However, it has now been established that there are two types of bulges: ``classical bulges'' that are dynamically hot systems resembling (little) ellipticals, and ``pseudobulges'', dynamically cold, flattened, disk-like structures that could not have formed via violent relaxation. Therefore thee question is whether at types Sa-Sbc, where both bulge types are found, the red-blue dichotomy separates galaxies at some value of disk-to-bulge ratio, $B/T$, or, whether it separates galaxies of different bulge type, irrespective of their $B/T$. We identify classical bulges and pseudobulges morphologically with ...

  9. The formation of the Galactic bulge of the Milky Way

    Directory of Open Access Journals (Sweden)

    Freeman K.

    2012-02-01

    Full Text Available We aim to determine if the bulge formed via mergers as predicted by Cold Dark Matter (CDM theory, or from disk instabilities, as suggested by its boxy shape, or both processes. We are observing about 28,000 bulge stars in fields that span longitudes of − 31 to + 26° and latitudes of − 5° to − 10°, targeting mostly red clump giants and we are measuring stellar velocities and chemical abundances. We have almost concluded our observations and have analysed data of 23,000 stars. We find a cylindrical rotation profile for the bulge which blends smoothly out into the disk and from the [Fe/H] results we find the bulge to be comprised of separate components, with an underlying slowly rotating metal poor subsample which we believe to be the inner halo stars and metal weak thick disk. We find only a small [Fe/H] gradient with latitude in the bulge, of − 0.07dex/kpc. This weak gradient does not necessarily support a merger origin for our bulge and the composite nature of the bulge is consistent with formation out of the thin disk as per instability formation models.

  10. On the importance of thermodynamic investigations for the re-assessment of selected ternary Fe-base systems

    Science.gov (United States)

    Presoly, P.; Bernhard, C.

    2016-07-01

    Reliable thermodynamic data are essential for the design and the production of new alloying systems. Particularly, the knowledge of the high-temperature phase transformations (TLiquid, TSolid, TPerit, Tγ→δ) are important for the solidification and the further processing. Investigations of selected commercial Dual-Phase, TRIP and high-Mn TWIP steels by DTA/DSC measurements show that the experimental results differ significantly from the calculation results of thermodynamic databases with respect to the phase transformation temperature and sequence. Based on these findings, it is very important to identify the defective subsystems of complex alloys in order to optimise the thermodynamic databases. In order to verify a quaternary system, e.g. the Fe-C-Si-Mn system, it is important to check the corresponding ternary subsystems. This was performed by DSC measurements of selected model alloys. By doing so, it was found that in Si- and Mn-alloyed Dual-Phase steels the thermodynamic description of the Fe-Si-Mn system is currently inadequate. This is a very important result, since all new designed steel grades for the automotive industry are based on a Fe-C-Si-Mn matrix.

  11. Thermodynamics and economics: Towards exergy-based indicators of sustainable development

    OpenAIRE

    Sylvie Ferrari; Stéphane Genoud; Jean-Baptiste Lesourd

    2001-01-01

    The main purpose of this paper is to define indicators of sustainable development which take into account the economic constraints imposed by the laws of thermodynamics. Firstly, a survey of some essential work about the relationships between economics and thermodynamics is proposed. Secondly, the exergy concept is introduced as a tool which describes irreversibility in production processes. Finally, an indicator of sustainable development which aims at taking into account energy savings at t...

  12. The Age of the Young Bulge-like Population in the Stellar System Terzan 5: Linking the Galactic Bulge to the High-z Universe

    Science.gov (United States)

    Ferraro, F. R.; Massari, D.; Dalessandro, E.; Lanzoni, B.; Origlia, L.; Rich, R. M.; Mucciarelli, A.

    2016-09-01

    The Galactic bulge is dominated by an old, metal-rich stellar population. The possible presence and the amount of a young (a few gigayears old) minor component is one of the major issues debated in the literature. Recently, the bulge stellar system Terzan 5 was found to harbor three sub-populations with iron content varying by more than one order of magnitude (from 0.2 up to two times the solar value), with chemical abundance patterns strikingly similar to those observed in bulge field stars. Here we report on the detection of two distinct main-sequence turnoff points in Terzan 5, providing the age of the two main stellar populations: 12 Gyr for the (dominant) sub-solar component and 4.5 Gyr for the component at super-solar metallicity. This discovery classifies Terzan 5 as a site in the Galactic bulge where multiple bursts of star formation occurred, thus suggesting a quite massive progenitor possibly resembling the giant clumps observed in star-forming galaxies at high redshifts. This connection opens a new route of investigation into the formation process and evolution of spheroids and their stellar content. Based on data obtained with (1) the ESA/NASA HST, under programs GO-14061, GO-12933, GO-10845, (2) the Very Large Telescope of the European Southern Observatory during the Science Verification of the camera MAD; (3) the W.M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California and NASA.

  13. Dynamic biogas upgrading based on the Sabatier process: thermodynamic and dynamic process simulation.

    Science.gov (United States)

    Jürgensen, Lars; Ehimen, Ehiaze Augustine; Born, Jens; Holm-Nielsen, Jens Bo

    2015-02-01

    This study aimed to investigate the feasibility of substitute natural gas (SNG) generation using biogas from anaerobic digestion and hydrogen from renewable energy systems. Using thermodynamic equilibrium analysis, kinetic reactor modeling and transient simulation, an integrated approach for the operation of a biogas-based Sabatier process was put forward, which was then verified using a lab scale heterogenous methanation reactor. The process simulation using a kinetic reactor model demonstrated the feasibility of the production of SNG at gas grid standards using a single reactor setup. The Wobbe index, CO2 content and calorific value were found to be controllable by the H2/CO2 ratio fed the methanation reactor. An optimal H2/CO2 ratio of 3.45-3.7 was seen to result in a product gas with high calorific value and Wobbe index. The dynamic reactor simulation verified that the process start-up was feasible within several minutes to facilitate surplus electricity use from renewable energy systems.

  14. Towards an evolutionary theory of the origin of life based on kinetics and thermodynamics.

    Science.gov (United States)

    Pascal, Robert; Pross, Addy; Sutherland, John D

    2013-11-01

    A sudden transition in a system from an inanimate state to the living state-defined on the basis of present day living organisms-would constitute a highly unlikely event hardly predictable from physical laws. From this uncontroversial idea, a self-consistent representation of the origin of life process is built up, which is based on the possibility of a series of intermediate stages. This approach requires a particular kind of stability for these stages-dynamic kinetic stability (DKS)-which is not usually observed in regular chemistry, and which is reflected in the persistence of entities capable of self-reproduction. The necessary connection of this kinetic behaviour with far-from-equilibrium thermodynamic conditions is emphasized and this leads to an evolutionary view for the origin of life in which multiplying entities must be associated with the dissipation of free energy. Any kind of entity involved in this process has to pay the energetic cost of irreversibility, but, by doing so, the contingent emergence of new functions is made feasible. The consequences of these views on the studies of processes by which life can emerge are inferred. PMID:24196781

  15. Thermodynamics of two-stroke engine based on periodically driven two-level system

    Science.gov (United States)

    Chvosta, Petr; Holubec, Viktor; Ryabov, Artem; Einax, Mario; Maass, Philipp

    2010-01-01

    We investigate a microscopic motor based on an externally driven two-level system. One cycle of the motor operation consists of two strokes. Within each stroke, the two energy levels are driven with a constant rate. The occupation probabilities of the two states evolve according to the Pauli rate equation and represent the delayed system's response to the external driving. We give the exact solution of the Pauli rate equation and discuss its thermodynamical consequences. In particular, we calculate the motor's efficiency, the power output, and the performance dependence on the control parameters. Secondly, we introduce an augmented stochastic process which reflects, at a given time, both the occupation probabilities for the two states and the time spent in the individual states during the previous evolution. Our exact calculation of the evolution operator for the augmented process allows one to discuss in detail the probability density for the work during the limit cycle. In the strongly irreversible regime, the density shows strong deviations from a Gaussian shape.

  16. An adaptive distance-based group contribution method for thermodynamic property prediction.

    Science.gov (United States)

    He, Tanjin; Li, Shuang; Chi, Yawei; Zhang, Hong-Bo; Wang, Zhi; Yang, Bin; He, Xin; You, Xiaoqing

    2016-09-14

    In the search for an accurate yet inexpensive method to predict thermodynamic properties of large hydrocarbon molecules, we have developed an automatic and adaptive distance-based group contribution (DBGC) method. The method characterizes the group interaction within a molecule with an exponential decay function of the group-to-group distance, defined as the number of bonds between the groups. A database containing the molecular bonding information and the standard enthalpy of formation (Hf,298K) for alkanes, alkenes, and their radicals at the M06-2X/def2-TZVP//B3LYP/6-31G(d) level of theory was constructed. Multiple linear regression (MLR) and artificial neural network (ANN) fitting were used to obtain the contributions from individual groups and group interactions for further predictions. Compared with the conventional group additivity (GA) method, the DBGC method predicts Hf,298K for alkanes more accurately using the same training sets. Particularly for some highly branched large hydrocarbons, the discrepancy with the literature data is smaller for the DBGC method than the conventional GA method. When extended to other molecular classes, including alkenes and radicals, the overall accuracy level of this new method is still satisfactory. PMID:27522953

  17. Towards an evolutionary theory of the origin of life based on kinetics and thermodynamics.

    Science.gov (United States)

    Pascal, Robert; Pross, Addy; Sutherland, John D

    2013-11-06

    A sudden transition in a system from an inanimate state to the living state-defined on the basis of present day living organisms-would constitute a highly unlikely event hardly predictable from physical laws. From this uncontroversial idea, a self-consistent representation of the origin of life process is built up, which is based on the possibility of a series of intermediate stages. This approach requires a particular kind of stability for these stages-dynamic kinetic stability (DKS)-which is not usually observed in regular chemistry, and which is reflected in the persistence of entities capable of self-reproduction. The necessary connection of this kinetic behaviour with far-from-equilibrium thermodynamic conditions is emphasized and this leads to an evolutionary view for the origin of life in which multiplying entities must be associated with the dissipation of free energy. Any kind of entity involved in this process has to pay the energetic cost of irreversibility, but, by doing so, the contingent emergence of new functions is made feasible. The consequences of these views on the studies of processes by which life can emerge are inferred.

  18. Origin of the scaling rule for fundamental living organisms based on thermodynamics.

    Science.gov (United States)

    Fujiwara, Noboru

    2003-06-01

    The regular relationships between metabolic energy and body mass M of unicellular organisms, poikilotherms and homeotherms were well known as general equations. The metabolic energy rate and the life span are proportional to M(0.75) and to M(0.25), respectively. As a result, the product of the metabolic energy rate and the life time, namely, life metabolic energy, is proportional to the mass of the living organism. The origin of the scaling rules for environmental organizing systems is as follows: (1) the scaling rules for internal energy, activation energy and free energy as a function of temperature and mass of a mole of molecules. (2) The majority of species of the living organisms have the same molecules such as polysaccharides, lipids, proteins and nucleic acids in nearly same the ratio. (3) The internal energy of reactants in living organisms is equilibrium with the internal energy of water. Then, the integrated metabolic energy over the synthesizing time depends on internal energy of water and is proportional to mass M, despite the synthesizing time of the system depending on reaction rate. The proportional constant is obtained based on the thermodynamics for fundamental living organisms such as unicellular organisms and plants. Information on the environmental organizing system is also discussed. PMID:12753932

  19. Thermodynamic Analysis of a Diesel Engine Integrated with a PCM Based Energy Storage System

    Directory of Open Access Journals (Sweden)

    R. Velraj

    2010-03-01

    Full Text Available This work describes the energy and exergy analysis of a diesel engine integrated with a PCM based energy storage system, and provides more realistic and meaningful assessment than the conventional energy analysis. Using actual system data, the assessments of energy and exergy saved, and energy and exergy efficiencies are done. The exergy saved in the overall system is quantified and illustrated using an exergy flow diagram. Also, energy and exergy flow diagrams are compared. It is observed through the analysis that 6.13% of the total energy of the fuel is saved using the TES system. From the exergy analysis, it is identified that only 0.47% of the chemical availability of the fuel is saved. The energy efficiency of the integrated system is found to be varying between 3.19% and 34.15%. In contrast, the exergy efficiency, which incorporates the second law of thermodynamics for the integrated system, ranges from 0.25% to 27.41%.

  20. Conceptual design of light integrated gasification fuel cell based on thermodynamic process simulation

    International Nuclear Information System (INIS)

    Highlights: • Light integrated gasification fuel cell (L-IGFC) power plant is proposed. • Dry gas desulfurization (DGD) is a key to increase the efficiency of the L-IGFC. • Atmospheric L-IGFC gives electrical efficiency over 46%LHV. • Pressurized operation of solid oxide fuel cell offers electrical efficiency of L-IGFC over 50%LHV. - Abstract: Integration of solid oxide fuel cell (SOFC) in coal gasification power plant technology would be one of the most promising technology in the coal utilization for power generation. The clean syngas from gas cleanup unit serves as fuel for SOFC in integrated gasification fuel cell power plant. The heat generated by SOFC can be utilized by heat recovery steam generator to drive steam turbine for electricity production. In this study, proposed plants consisting of coal gasifier and SOFC on the top of a steam turbine (ST), called light integrated gasification fuel cell (L-IGFC), are investigated thermodynamically by using Aspen Plus software to evaluate their performance. The analyses are based on the SOFC module considering ohmic, activation and concentration losses at a certain current density of the cell operating at the intermediate temperature. The influences of gas cleanup unit models were also investigated. The results indicated that the proposed atmospheric L-IGFC plant could achieve electrical efficiency in the range of 39–46.35% in lower heating value

  1. Material Based Structure Design: Numerical Analysis Thermodynamic Response of Thermal Pyrolytic Graphite /Al Sandwich Composites

    Science.gov (United States)

    Wang, Junxia; Yan, Shilin; Yu, Dingshan

    2016-06-01

    Amine-grafted multiwalled carbon nanotubes (MWCNTs) based thermally conductive adhesive (TCA) was studied in the previous paper and applied here in thermal pyrolytic graphite (TPG)/Al radiator due to its high thermal conductivity, toughness and cohesiveness. In this paper, in an attempt to confirm the application of TCA to TPG/Al sandwich radiator, the thermodynamic response in TPG/Al sandwich composites associated with key material properties and structural design was investigated using finite element simulation with commercial available ANSYS software. The induced thermal stress in TCA layer is substantial due to the thermal expansion mismatch between Al plate and TPG. The maximum thermal stress is located near the edge of TCA layer with the von Mises stress value of 4.02 MPa and the shear stress value of 1.66 MPa. The reasonable adjustment of physical-mechanical properties including thermal conductivity, thermal expansion, Young,s modulus and the thickness of TCA layer, Al plate and TPG are beneficial for reducing the temperature of the top surface of the upper skin and their effects on the reduction of thermal structural response in some ways. These findings will highlight the structural optimization of TPG/Al radiator for future application.

  2. The Impact of the Uncertainty in Single-Epoch Virial Black Hole Mass Estimates on the Observed Evolution of the Black Hole - Bulge Scaling Relations

    OpenAIRE

    SHEN Yue; Kelly, Brandon C.

    2009-01-01

    Recent observations of the black hole (BH) - bulge scaling relations usually report positive redshift evolution, with higher redshift galaxies harboring more massive BHs than expected from the local relations. All of these studies focus on broad line quasars with BH mass estimated from virial estimators based on single-epoch spectra. Since the sample selection is largely based on quasar luminosity, the cosmic scatter in the BH-bulge relation introduces a statistical bias leading to on average...

  3. Thermodynamics-based models for the magneto-mechanical response of magnetic shape memory alloys

    Science.gov (United States)

    LaMaster, Douglas H.

    toward this i-direction. The energy required to rotate these magnetization vectors is called the anisotropy energy. Because MSMAs have unusually high anisotropy energy requirements [4, 5], it can become more energetically favorable to reorient variants into ξi and align the magnetic easy axis with the applied magnetic field, rather than to rotate the magnetization vector in the i-direction, toward the hard axis. In this manner, an MSMA can experience the same response to magnetic field as it does to a compressive stress: variant reorientation. As variants reorient, the MSMA will compress in one direction and elongate in another direction, enabling their use as actuators. Additionally, magnetization vectors change direction as they align with the short length of the reorienting variant. As the internal magnetization changes, the MSMA can produce changes in the external magnetic field, which can induce a current within a surrounding coil. Utilizing this can lead to the design of either power harvesters or sensors. This work builds upon that of others, notably that of Kiefer and Lagoudas [6-9], to present several thermodynamic-based continuum models to predict the response of an MSMA to magneto-mechanical loading. The first model is 2D, and allows for any magneto-mechanical loading in two directions. The 2D model includes evolution rules for domain fractions, magnetization vector rotation, and variant reorientation. The next two models are 3D, and include evolution rules for domain wall motion and variant re- orientation. The first 3D model neglects magnetization vector rotation to present a simpler model that is less computationally intensive, while the second 3D model in- cludes all known mechanisms present in the microstructure to give a more generalized and complete model. These models are all more general than any other continuum, thermodynamics-based model in the literature. No other 2D continuum, thermodynamics-based model allows for general 2D magneto

  4. Polarization in microlensing towards the Galactic bulge

    CERN Document Server

    Ingrosso, G; De Paolis, F; Jetzer, Ph; Nucita, A A; Strafella, F; Zakharov, A F

    2012-01-01

    Gravitational microlensing, when finite size source effects are relevant, provides an unique tool for the study of source star stellar atmospheres through an enhancement of a characteristic polarization signal. This is due to the differential magnification induced during the crossing of the source star. In this paper we consider a specific set of reported highly magnified, both single and binary exoplanetary systems, microlensing events towards the Galactic bulge and evaluate the expected polarization signal. To this purpose, we consider several polarization models which apply to different types of source stars: hot, late type main sequence and cool giants. As a result we compute the polarization signal P,which goes up to P=0.04% for late type stars and up to a few percent for cool giants, depending on the underlying physical polarization processes and atmosphere model parameters. Given a I band magnitude at maximum magnification of about 12, and a typical duration of the polarization signal up to 1 day, we c...

  5. Non linear finite element simulation of complex bulge forming processes

    OpenAIRE

    Mac Donald, Bryan J

    2000-01-01

    Bulge forming is a manufacturing process that is becoming increasingly important as a technology that can be used to produce seamless, lightweight and near-net-shape industrial components. The process is being increasingly applied in the automotive and aerospace industries where the demands for increased structural strength and decreased vehicle weight make it a very attractive manufacturing method. This work is concerned with increasing knowledge of the deformation mechanisms during bulg...

  6. Orientation-specific cis complementation by bulge- and loop-mutated human immunodeficiency virus type 1 TAR RNAs.

    Science.gov (United States)

    Braddock, M; Powell, R; Sutton, J; Kingsman, A J; Kingsman, S M

    1994-12-01

    Tat activates human immunodeficiency type 1 gene expression by binding to TAR RNA. TAR comprises a partially base paired stem and hexanucleotide loop with a tripyrimidine bulge in the upper stem. In vitro, Tat binds to the bulge and upper stem, with no requirement for the loop. However, in vivo, loop sequences are critical for activation, implying that a loop binding cellular factor may be involved in the activation pathway. Given that activation appears to be a two-component system comprising a Tat-bulge interaction and a cellular factor-loop interaction, we considered that it might be possible to spatially separate the two components and retain activation. We have constructed a series of double TAR elements comprising various combinations of mutated TAR structures. Defective TARs with nucleotide substitutions in either the bulge or the loop complemented each other to give wild-type activation. However, the complementation was orientation specific, requiring the intact Tat binding site to reside on the 5'-proximal TAR. These data suggest that provided the wild-type orientation of the bulge and loop elements is retained, there is no requirement for them to coexist on the same TAR structure. PMID:7966633

  7. Chemical Evolution of the Galactic Bulge as Derived from High-Resolution Infrared Spectroscopy of K and M Red Giants

    CERN Document Server

    Cunha, K; Cunha, Katia; Smith, Verne V.

    2006-01-01

    We present chemical abundances in K and M red-giant members of the Galactic bulge derived from high-resolution infrared spectra obtained with the Phoenix spectrograph on Gemini-South. The elements studied are carbon, nitrogen, oxygen, sodium, titanium, and iron. The evolution of C and N abundances in the studied red-giants show that their oxygen abundances represent the original values with which the stars were born. Oxygen is a superior element for probing the timescale of bulge chemical enrichment via [O/Fe] versus [Fe/H]. The [O/Fe]-[Fe/H] relation in the bulge does not follow the disk relation, with [O/Fe] values falling above those of the disk. Titanium also behaves similarly to oxygen with respect to iron. Based on these elevated values of [O/Fe] and [Ti/Fe] extending to large Fe abundances, it is suggested that the bulge underwent a more rapid chemical enrichment than the halo. In addition, there are declines in both [O/Fe] and [Ti/Fe] in those bulge targets with the largest Fe abundances, signifying a...

  8. Application of fundamental aquatic chemistry to the safety case and the role of thermodynamic reference data bases

    Energy Technology Data Exchange (ETDEWEB)

    Altmaier, Marcus; Gaona, Xavier; Fellhauer, David; Geckeis, Horst [Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen (Germany). Inst. for Nuclear Waste Disposal

    2015-07-01

    All national and international programs developing a Nuclear Waste Disposal Safety Case have recognized the essential requirement of assessing aqueous (radionuclide) chemistry and establishing reliable thermodynamic databases. Long-term disposal of nuclear waste in deep underground repositories is the safest option to separate highly hazardous radionuclides from the environment. In order to predict the long-term performance of a repository for different evolution scenarios, the potentially relevant specific (geo)chemical systems are analyzed. This requires a detailed understanding of solubility, speciation and thermodynamics for all relevant components including radionuclides, and the availability of reliable thermodynamic data and databases as fundamental input for integral geochemical model calculations and hence PA. Radionuclide solubility and speciation strongly depend on chemical conditions (pH, E{sub h}, matrix electrolyte system and ionic strength) with additional factors like the presence of complexing ligands or temperature further impacting solution chemistry. As the fundamental chemical key processes are known and convincingly described by general laws of nature (→ solution thermodynamics), the long-term behavior of a repository system can be analyzed over geological timescales using geochemical tools. A key application of fundamental aquatic chemistry in the Safety Case is the determination of solubility limits (radionuclide source terms). Based upon fundamental chemical information (on solid phases, complexation reactions, activity coefficients, etc.), the maximum amount of radionuclides potentially dissolved in a given volume of solution and transported away from the repository, are quantified. A detailed understanding of radionuclide chemistry is also crucial for neighboring fields. For example, advanced mechanistic understanding and modeling of sorption processes at the solid liquid interphase, waste dissolution processes, secondary phase and

  9. Application of fundamental aquatic chemistry to the safety case and the role of thermodynamic reference data bases

    International Nuclear Information System (INIS)

    All national and international programs developing a Nuclear Waste Disposal Safety Case have recognized the essential requirement of assessing aqueous (radionuclide) chemistry and establishing reliable thermodynamic databases. Long-term disposal of nuclear waste in deep underground repositories is the safest option to separate highly hazardous radionuclides from the environment. In order to predict the long-term performance of a repository for different evolution scenarios, the potentially relevant specific (geo)chemical systems are analyzed. This requires a detailed understanding of solubility, speciation and thermodynamics for all relevant components including radionuclides, and the availability of reliable thermodynamic data and databases as fundamental input for integral geochemical model calculations and hence PA. Radionuclide solubility and speciation strongly depend on chemical conditions (pH, Eh, matrix electrolyte system and ionic strength) with additional factors like the presence of complexing ligands or temperature further impacting solution chemistry. As the fundamental chemical key processes are known and convincingly described by general laws of nature (→ solution thermodynamics), the long-term behavior of a repository system can be analyzed over geological timescales using geochemical tools. A key application of fundamental aquatic chemistry in the Safety Case is the determination of solubility limits (radionuclide source terms). Based upon fundamental chemical information (on solid phases, complexation reactions, activity coefficients, etc.), the maximum amount of radionuclides potentially dissolved in a given volume of solution and transported away from the repository, are quantified. A detailed understanding of radionuclide chemistry is also crucial for neighboring fields. For example, advanced mechanistic understanding and modeling of sorption processes at the solid liquid interphase, waste dissolution processes, secondary phase and solid

  10. Comparison of laser-based and monochromator-based thermodynamic temperature measurements

    International Nuclear Information System (INIS)

    In this work, we describe comparisons between a laser-based and a monochromator-based radiance responsivity calibration of a radiation thermometer. The spectral selection of the radiation thermometer is performed using a spectrally broad photopic-response filter which was selected to minimize effects of convolution differences due to the spectral width of the laser-and the monochromator-based sources. The photopic-response filter is physically thick, which should also reduce possible interference fringes which can be problematic in the laser-based calibrations. We compare the radiance responsivities obtained using the two approaches and also compare the blackbody temperatures determined using the detector/monochromator based and the gold-point based calibration methods

  11. Synthesis, thermodynamic properties and BSA interaction of a new Valen Shiff base derived from o-vanillin and trimethoprim

    International Nuclear Information System (INIS)

    Graphical abstract: A new single Valen Shiff base was synthesized and characterized. The thermodynamics properties of the Shiff base were investigated by microcalorimetry. In particular, the interaction between the synthetic Shiff base and BSA at four different temperatures has been investigated using fluorescence quenching method. - Highlights: • A new single Valen Shiff base was synthesized and characterized. • The thermodynamics properties of the Shiff base were investigated by microcalorimetry. • The interaction between the Shiff base and BSA has been investigated using fluorescence quenching method. - Abstract: A new Valen Shiff base (C22H24N4O5) was synthesized using equivalent moles of o-vanillin and trimethoprim. At 298.15 K, the standard molar enthalpy of formation of the new compound was estimated to be ΔfHmΘ [C22H24N4O5(s), 298.15 K] = −(696.92 ± 1.67) kJ mol−1 by microcalorimetry. In particular, the interaction between the Shiff base and bovine serum albumin (BSA) has been investigated. It was proved that the fluorescence quenching of BSA by Shiff base is a result of the formation of a Shiff base-BSA complex. Quenching constants were determined using the Sterns–Volmer equation to provide a measurement of the binding site between Shiff base and BSA. The thermodynamic parameters ΔG, ΔH, and ΔS of the system at different temperatures were calculated. What is more, the distance r between donor (Trp. 213) and acceptor (Shiff base) was obtained. Finally, synchronous fluorescence spectroscopy data has suggested the association between Shiff base and BSA changed the molecular conformation of BSA

  12. Synthesis, thermodynamic properties and BSA interaction of a new Valen Shiff base derived from o-vanillin and trimethoprim

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xu; Jiang, Jian-Hong; Xiao, Sheng-Xiong [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan Province (China); Gu, Hui-Wen, E-mail: gruyclewee@hnu.edu.cn [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan Province (China); Li, Chuan-Hua; Ye, Li-Juan; Li, Xia; He, Du-Gui; Yao, Fei-Hong [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan Province (China); Li, Qiang-Guo, E-mail: liqiangguo@163.com [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan Province (China)

    2014-01-10

    Graphical abstract: A new single Valen Shiff base was synthesized and characterized. The thermodynamics properties of the Shiff base were investigated by microcalorimetry. In particular, the interaction between the synthetic Shiff base and BSA at four different temperatures has been investigated using fluorescence quenching method. - Highlights: • A new single Valen Shiff base was synthesized and characterized. • The thermodynamics properties of the Shiff base were investigated by microcalorimetry. • The interaction between the Shiff base and BSA has been investigated using fluorescence quenching method. - Abstract: A new Valen Shiff base (C{sub 22}H{sub 24}N{sub 4}O{sub 5}) was synthesized using equivalent moles of o-vanillin and trimethoprim. At 298.15 K, the standard molar enthalpy of formation of the new compound was estimated to be Δ{sub f}H{sub m}{sup Θ} [C{sub 22}H{sub 24}N{sub 4}O{sub 5}(s), 298.15 K] = −(696.92 ± 1.67) kJ mol{sup −1} by microcalorimetry. In particular, the interaction between the Shiff base and bovine serum albumin (BSA) has been investigated. It was proved that the fluorescence quenching of BSA by Shiff base is a result of the formation of a Shiff base-BSA complex. Quenching constants were determined using the Sterns–Volmer equation to provide a measurement of the binding site between Shiff base and BSA. The thermodynamic parameters ΔG, ΔH, and ΔS of the system at different temperatures were calculated. What is more, the distance r between donor (Trp. 213) and acceptor (Shiff base) was obtained. Finally, synchronous fluorescence spectroscopy data has suggested the association between Shiff base and BSA changed the molecular conformation of BSA.

  13. Molecular thermodynamic modeling of ionic liquids using the perturbation-based linear Yukawa isotherm regularity

    Science.gov (United States)

    Sohrabi Mahboub, Mahdi; Farrokhpour, Hossein

    2016-06-01

    In this paper, we present the results of an extensive study on a novel approach to the molecular modeling of pure ionic liquids (ILs) that incorporates the perturbed thermodynamic linear Yukawa isotherm regularity (LYIR), which is derived based on an effective nearest neighboring pair attractive interaction of the Yukawa potential. The LYIR was used to model the densities of ILs up to high pressures (35 MPa) and in the temperature range 293.15 to 393.15 K. To use the LYIR for ILs, a simple molecular model was proposed to describe their molecular structure, in which they were considered as a liquid consisting of the ion pairs moving together in the fluid, and each ion pair was assumed to be a one-center spherical united atom. The ILs under consideration contained one of the IL cations [C2mim]+, [C4mim]+, [C7mim]+, [C8mim]+, [C3mpy]+, [C3mpip]+, [C3mpyr]+ or [C4mpyr]+, and one of the IL anions [BF4]-, [C(CN)3]-, [CF3SO4]- or [NTf2]-. The reliability and physical significance of the parameters as well as the proposed molecular model were tested by calculating the densities of pure imidazolium-, pyridinium-, piperidinium- and pyrrolidimium-based ILs. The results showed that the LYIR can be used to predict and reproduce the density of ILs in good agreement with the experimental data. In addition, the LYIR enabled us to determine the physical quantities, such as an effective Yukawa screening length, λ eff, the product of the effective energy well depth and the effective coordination number, (ɛ eff/k)z eff, the contribution of the non-reference thermal pressure and also the influence of the anionic and cationic structure on the λ eff parameter. The standard deviation of the IL densities predicted in this work is lower than those calculated by the one other important equation of state reported in the literature.

  14. Hiding its age: the case for a younger bulge

    CERN Document Server

    Haywood, M; Snaith, O; Calamida, A

    2016-01-01

    The determination of the age of the bulge has led to two contradictory results. On the one side, the color-magnitude diagrams in different bulge fields seem to indicate a uniformly old ($>$10 Gyr) population. On the other side, individual ages derived from dwarfs observed through microlensing events seem to indicate a large spread, from $\\sim$ 2 to $\\sim$ 13 Gyr. Because the bulge is now recognised as being mainly a boxy peanut-shaped bar, it is suggested that disk stars are one of its main constituents, and therefore also stars with ages significantly younger than 10 Gyr. Other arguments as well point to the fact that the bulge cannot be exclusively old, and in particular cannot be a burst population, as it is usually expected if the bulge was the fossil remnant of a merger phase in the early Galaxy. In the present study, we show that given the range of metallicities observed in the bulge, a uniformly old population would be reflected into a significant spread in color at the turn-off which is not observed. ...

  15. Chemodynamical analysis of bulge stars for simulated disc galaxies

    Science.gov (United States)

    Rahimi, A.; Kawata, D.; Brook, Chris B.; Gibson, Brad K.

    2010-01-01

    We analyse the kinematics and chemistry of the bulge stars of two simulated disc galaxies using our chemodynamical galaxy evolution code GCD+. First, we compare stars that are born inside the galaxy with those that are born outside the galaxy and are accreted into the centre of the galaxy. Stars that originate outside the bulge are accreted into it early in its formation within 3 Gyr so that these stars have high [α/Fe] as well as a high total energy reflecting their accretion to the centre of the galaxy. Therefore, higher total energy is a good indicator for finding accreted stars. The bulges of the simulated galaxies formed through multiple mergers separated by about a Gyr. Since [α/Fe] is sensitive to the first few Gyr of star formation history, stars that formed during mergers at different epochs show different [α/Fe]. We show that the [Mg/Fe] against star formation time relation can be very useful to identify a multiple merger bulge formation scenario, provided there is sufficiently good age information available. Our simulations also show that stars formed during one of the merger events retain a systematically prograde rotation at the final time. This demonstrates that the orbit of the ancient merger that helped to form the bulge could still remain in the kinematics of bulge stars.

  16. Chemical similarities between Galactic bulge and local thick disk red giant stars

    OpenAIRE

    Melendez, J.; Asplund, M.; Alves-Brito, A.; Cunha, K.; B. Barbuy; Bessell, M. S.; Chiappini, C.; Freeman, K. C.; Ramirez, I.; Smith, V.V.; Yong, D.

    2008-01-01

    The evolution of the Milky Way bulge and its relationship with the other Galactic populations is still poorly understood. The bulge has been suggested to be either a merger-driven classical bulge or the product of a dynamical instability of the inner disk. To probe the star formation history, the initial mass function and stellar nucleosynthesis of the bulge, we performed an elemental abundance analysis of bulge red giant stars. We also completed an identical study of local thin disk, thick d...

  17. Application of thermodynamics-based rate-dependent constitutive models of concrete in the seismic analysis of concrete dams

    Institute of Scientific and Technical Information of China (English)

    Leng Fei; Lin Gao

    2008-01-01

    This paper discusses the seismic analysis of concrete dams with consideration of material nonlinearity. Based on a consistent rate-dependent model and two thermodynamics-based models, two thermodynamics-based rate-dependent constitutive models were developed with consideration of the influence of the strain rate. They can describe the dynamic behavior of concrete and be applied to nonlinear seismic analysis of concrete dams taking into account the rate sensitivity of concrete. With the two models, a nonlinear analysis of the seismic response of the Koyna Gravity Dam and the Dagangshan Arch Dam was conducted. The results were compared with those of a linear elastic model and two rate-independent thermodynamics-based constitutive models, and the influences of constitutive models and strain rate on the seismic response of concrete dams were discussed. It can be concluded from the analysis that, during seismic response, the tensile stress is the control stress in the design and seismic safety evaluation of concrete dams. In different models, the plastic strain and plastic strain rate of concrete dams show a similar distribution. When the influence of the strain rate is considered, the maximum plastic strain and plastic strain rate decrease.

  18. Application of thermodynamics-based rate-dependent constitutive models of concrete in the seismic analysis of concrete dams

    Directory of Open Access Journals (Sweden)

    Fei LENG

    2008-09-01

    Full Text Available This paper discusses the seismic analysis of concrete dams with consideration of material nonlinearity. Based on a consistent rate-dependent model and two thermodynamics-based models, two thermodynamics-based rate-dependent constitutive models were developed with consideration of the influence of the strain rate. They can describe the dynamic behavior of concrete and be applied to nonlinear seismic analysis of concrete dams taking into account the rate sensitivity of concrete. With the two models, a nonlinear analysis of the seismic response of the Koyna Gravity Dam and the Dagangshan Arch Dam was conducted. The results were compared with those of a linear elastic model and two rate-independent thermodynamics-based constitutive models, and the influences of constitutive models and strain rate on the seismic response of concrete dams were discussed. It can be concluded from the analysis that, during seismic response, the tensile stress is the control stress in the design and seismic safety evaluation of concrete dams. In different models, the plastic strain and plastic strain rate of concrete dams show a similar distribution. When the influence of the strain rate is considered, the maximum plastic strain and plastic strain rate decrease.

  19. Extended thermodynamics

    CERN Document Server

    Müller, Ingo

    1993-01-01

    Physicists firmly believe that the differential equations of nature should be hyperbolic so as to exclude action at a distance; yet the equations of irreversible thermodynamics - those of Navier-Stokes and Fourier - are parabolic. This incompatibility between the expectation of physicists and the classical laws of thermodynamics has prompted the formulation of extended thermodynamics. After describing the motifs and early evolution of this new branch of irreversible thermodynamics, the authors apply the theory to mon-atomic gases, mixtures of gases, relativistic gases, and "gases" of phonons and photons. The discussion brings into perspective the various phenomena called second sound, such as heat propagation, propagation of shear stress and concentration, and the second sound in liquid helium. The formal mathematical structure of extended thermodynamics is exposed and the theory is shown to be fully compatible with the kinetic theory of gases. The study closes with the testing of extended thermodynamics thro...

  20. Accuracy Based Generation of Thermodynamic Properties for Light Water in RELAP5-3D

    Energy Technology Data Exchange (ETDEWEB)

    Cliff B. Davis

    2010-09-01

    RELAP5-3D interpolates to obtain thermodynamic properties for use in its internal calculations. The accuracy of the interpolation was determined for the original steam tables currently used by the code. This accuracy evaluation showed that the original steam tables are generally detailed enough to allow reasonably accurate interpolations in most areas needed for typical analyses of nuclear reactors cooled by light water. However, there were some regions in which the original steam tables were judged to not provide acceptable accurate results. Revised steam tables were created that used a finer thermodynamic mesh between 4 and 21 MPa and 530 and 640 K. The revised steam tables solved most of the problems observed with the original steam tables. The accuracies of the original and revised steam tables were compared throughout the thermodynamic grid.

  1. Influence of Kinetic and Thermodynamic Factors on the Glass-Forming Ability of Zirconium-Based Bulk Amorphous Alloys

    OpenAIRE

    Mukherjee, S.; Schroers, J.; Johnson, W. L.; Rhim, W. K.

    2005-01-01

    The time-temperature-transformation curves for three zirconium-based bulk amorphous alloys are measured to identify the primary factors influencing their glass-forming ability. The melt viscosity is found to have the most pronounced influence on the glass-forming ability compared to other thermodynamic factors. Surprisingly, it is found that the better glass former has a lower crystal-melt interfacial tension. This contradictory finding is explained by the icosahedral short-range order of the...

  2. Equilibrium thermodynamics

    CERN Document Server

    Oliveira, Mário J

    2013-01-01

    This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions.  These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Néel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This textbo...

  3. Pulsating variable stars in the MACHO bulge database: the semiregular variables

    Energy Technology Data Exchange (ETDEWEB)

    Minniti, D.; Alcock, C.; Allsman, R.A. [and others

    1997-11-01

    We review the pulsating stars contained in the top 24 fields of the MACHO bulge database, with special emphasis on the red semireg-ular stars. Based on period, amplitude and color cuts, we have selected a sample of 2000 semireguku variables with 15 < P < 100 days. Their period-luminosity relation is studied, as well ss their spatial distribution. We find that they follow the bar, unlike the RR Lyrae in these fields.

  4. Isotherm-Based Thermodynamic Models for Solute Activities of Organic Acids with Consideration of Partial Dissociation.

    Science.gov (United States)

    Nandy, Lucy; Ohm, Peter B; Dutcher, Cari S

    2016-06-23

    Organic acids make up a significant fraction of the organic mass in atmospheric aerosol particles. The calculation of gas-liquid-solid equilibrium partitioning of the organic acid is therefore critical for accurate determination of atmospheric aerosol physicochemical properties and processes such as new particle formation and activation to cloud condensation nuclei. Previously, an adsorption isotherm-based statistical thermodynamic model was developed for capturing solute concentration-activity relationships for multicomponent aqueous solutions over the entire concentration range (Dutcher et al. J. Phys. Chem. C/A 2011, 2012, 2013), with model parameters for energies of adsorption successfully related to dipole-dipole electrostatic forces in solute-solvent and solvent-solvent interactions for both electrolytes and organics (Ohm et al. J. Phys. Chem. A 2015). However, careful attention is needed for weakly dissociating semivolatile organic acids. Dicarboxylic acids, such as malonic acid and glutaric acid are treated here as a mixture of nondissociated organic solute (HA) and dissociated solute (H(+) + A(-)). It was found that the apparent dissociation was greater than that predicted by known dissociation constants alone, emphasizing the effect of dissociation on osmotic and activity coefficient predictions. To avoid additional parametrization from the mixture approach, an expression was used to relate the Debye-Hückel hard-core collision diameter to the adjustable solute-solvent intermolecular distance. An improved reference state treatment for electrolyte-organic aqueous mixtures, such as that observed here with partial dissociation, has also been proposed. This work results in predictive correlations for estimation of organic acid and water activities for which there is little or no activity data. PMID:27222917

  5. The Black Hole Mass-Bulge Luminosity Relationship for Active Galactic Nuclei From Reverberation Mapping and Hubble Space Telescope Imaging

    DEFF Research Database (Denmark)

    Bentz, Misty C.; Peterson, Bradley M.; Pogge, Richard W.;

    2009-01-01

    We investigate the relationship between black hole mass and bulge luminosity for active galactic nuclei (AGNs) with reverberation-based black hole mass measurements and bulge luminosities from two-dimensional decompositions of Hubble Space Telescope host galaxy images. We find that the slope...... of the relationship for AGNs is 0.76-0.85 with an uncertainty of ~0.1, somewhat shallower than the M BH vprop L 1.0±0.1 relationship that has been fit to nearby quiescent galaxies with dynamical black hole mass measurements. This difference is somewhat perplexing, as the AGN black hole masses include an overall...

  6. The Black Hole–Bulge Mass Relation in Megamaser Host Galaxies

    Science.gov (United States)

    Läsker, Ronald; Greene, Jenny E.; Seth, Anil; van de Ven, Glenn; Braatz, James A.; Henkel, Christian; Lo, K. Y.

    2016-07-01

    We present Hubble Space Telescope (HST) images for nine megamaser disk galaxies with the primary goal of studying photometric BH-galaxy scaling relations. The megamaser disks provide the highest-precision extragalactic BH mass measurements, while our high-resolution HST imaging affords us the opportunity to decompose the complex nuclei of their late-type hosts in detail. Based on the morphologies and shapes of the galaxy nuclei, we argue that most of these galaxies’ central regions contain secularly evolving components (pseudo-bulges), and in many cases we photometrically identify co-existing “classical” bulge components as well. Using these decompositions, we draw the following conclusions. (1) The megamaser BH masses span two orders of magnitude (106–{10}8 {M}ȯ ) while the stellar mass of their spiral host galaxies are all ˜ {10}11 {M}ȯ within a factor of three. (2) The BH masses at a given bulge mass or total stellar mass in the megamaser host spiral galaxies tend to be lower than expected when compared to an extrapolation of the BH-bulge relation based on early-type galaxies. (3) The observed large intrinsic scatter of BH masses in the megamaser host galaxies raises the question of whether scaling relations exist in spiral galaxies. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with program 12185.

  7. Thermodynamics of relation-based systems with applications in econophysics, sociophysics, and music

    Science.gov (United States)

    Gündüz, Güngör

    2012-10-01

    A methodology was developed to analyze relation-based systems evolving in time by using the fundamental concepts of thermodynamics. The behavior of such systems can be tracked from the scattering matrix which is actually a network of directed vectors (or pathways) connecting subsequent values, which characterize an event, such as the index values in stock markets. A system behaves in a rigid (elastic) way to an external effect and resists permanent deformation, or it behaves in a viscous (or soft) way and deforms in an irreversible way. It was shown in the past that a formula derived using the slope of paths gives a measure about the extent of viscoelastic behavior of relation-based systems Gündüz (2009) [5] Gündüz and Gündüz (2010) [6]. In this research the ‘work’ associated with ‘elastic’ component, and ‘heat’ associated with ‘viscous’ component were discussed and elaborated. In a simple two subsequent pathway system in a scattering diagram the first vector represents ‘the cause’ and the second ‘the effect’. By using work and heat energy relations that involve force and also storage and loss modulus terms, respectively, one can calculate the energy involved in relation-based systems. The modulus values can be found from the parallel and vertical components of the second vector with respect to the first vector. Once work-like and heat-like terms were determined the internal energy is also easily found from their summation. The parallel and vertical components can also be used to calculate the magnitude of torque and torque energy in the system. Three cases, (i) the behavior of the NASDAQ-100 index, (ii) a social revolt, and (iii) the structure of a melody were analyzed for their ‘work-like’, ‘heat-like’, and ‘torque-like’ energies in the course of their evolution. NASDAQ-100 exhibits highly dissipative behavior, and its work terms are very small but heat terms are of large magnitude. Its internal energy highly fluctuates

  8. Theoretical models for fluid thermodynamics based on the quasi-Gaussian entropy theory

    NARCIS (Netherlands)

    Amadei, Andrea

    1998-01-01

    Summary The theoretical modeling of fluid thermodynamics is one of the most challenging fields in physical chemistry. In fact the fluid behavior, except at very low density conditions, is still extremely difficult to be modeled from a statistical mechanical point of view, as for any realistic model

  9. Thermodynamics of noncommutative geometry inspired BTZ black hole based on Lorentzian smeared mass distribution

    Science.gov (United States)

    Liang, Jun; Liu, Bo

    2012-11-01

    A noncommutative BTZ black hole is constructed in three-dimensional anti-de Sitter space. In this black-hole model, the noncommutative smearing is obtained by replacing the point-like source term with a Lorentzian distribution. We mainly investigate the thermodynamical properties of this black hole, including Hawking temperature, entropy, heat capacity and free energy.

  10. Numerical Predictions of Damage and Failure in Carbon Fiber Reinforced Laminates Using a Thermodynamically-Based Work Potential Theory

    Science.gov (United States)

    Pineda, Evan Jorge; Waas, Anthony M.

    2013-01-01

    A thermodynamically-based work potential theory for modeling progressive damage and failure in fiber-reinforced laminates is presented. The current, multiple-internal state variable (ISV) formulation, referred to as enhanced Schapery theory (EST), utilizes separate ISVs for modeling the effects of damage and failure. Consistent characteristic lengths are introduced into the formulation to govern the evolution of the failure ISVs. Using the stationarity of the total work potential with respect to each ISV, a set of thermodynamically consistent evolution equations for the ISVs are derived. The theory is implemented into a commercial finite element code. The model is verified against experimental results from two laminated, T800/3900-2 panels containing a central notch and different fiber-orientation stacking sequences. Global load versus displacement, global load versus local strain gage data, and macroscopic failure paths obtained from the models are compared against the experimental results.

  11. Thermodynamic and kinetic study on interfacial reaction and diamond graphitization of Cu-Fe-based diamond composite

    Institute of Scientific and Technical Information of China (English)

    Li Wen-Sheng; Zhang Jie; Dong Hong-Feng; Chu Ke; Wang Shun-Cai; Liu Yi; Li Ya-Ming

    2013-01-01

    Cu-Fe based diamond composites used for saw-blade segments are directly fabricated by vacuum and pressureassisted sintering.The carbide forming elements Cr and Ti are added to improve interfacial bonding between diamond and the Cu-Fe matrix.The interfacial reactions between diamond/graphite and Cr or Ti,and diamond graphitization are investigated by thermodynamics/kinetics analyses and experimental methods.The results show that interfacial reactions and graphitization of diamond can automatically proceed thermodynamically.The Cr3C2,Cr7C3,Cr23C6,and TiC are formed at the interfaces of composites by reactions between diamond and Cr or Ti; diamond graphitization does not occur because of the kinetic difficulty at 1093 K under the pressure of 13 MPa.

  12. General thermodynamics

    CERN Document Server

    Olander, Donald

    2007-01-01

    The book’s methodology is unified, concise, and multidisciplinary, allowing students to understand how the principles of thermodynamics apply to all technical fields that touch upon this most fundamental of scientific theories. It also offers a rigorous approach to the quantitative aspects of thermodynamics, accompanied by clear explanations to help students transition smoothly from the physical concepts to their mathematical representations

  13. A Search for Novae in the Bulge of M31

    Science.gov (United States)

    Rector, T. A.; Jacoby, G. H.; Corbett, D. L.; Denham, M.; RBSE Nova Search Team

    1999-12-01

    We present the initial results of a program currently underway to search for nova in local group galaxies with the KPNO 0.9-meter telescope. The long-term goal is to accurately determine if the nova rate varies for galaxies of different Hubble type. Ciardullo et al. claim that nova rates are very similar when normalized to the total galaxy K-band luminosity. However, Della Valle et al. claim the rates are different by up to a factor of four, with early-type galaxies being deficient in novae. Here we present novae found from eighteen epochs of observations of the bulge of M31. The observations span from September 1995 to July 1999. The results presented here are part of an NSF-funded research-based science education program (RBSE) operated by NOAO, wherein middle- and high-school science students learn astronomy and inquiry-based learning skills by participating in actual research. The novae presented here were discovered by students participating in the RBSE program.

  14. The Large-Scale Extinction Map of the Galactic Bulge from the MACHO Project Photometry

    CERN Document Server

    Popowski, P; Becker, A; Popowski, Piotr; Cook, Kem; Becker, Andrew

    2003-01-01

    We present a (V-R)-based reddening map of about 43 square degrees of the Galactic bulge/bar. The map is constructed using template image photometry from the MACHO microlensing survey, contains 9717 resolution elements, and is based on (V-R)-color averages of the entire color-magnitude diagrams (CMDs) in 4 by 4 arc-minute tiles. The conversion from the observed color to the reddening follows from an assumption that CMDs of all bulge fields would look similar in the absence of extinction. Consequently, the difference in observed color between various fields originates from varying contribution of the disk extinction summed along different lines of sight. We check that our (V-R) colors correlate very well with visual extinction derived by Stanek in Baade's Window. We show that a dusty disk obeying a cosec|b| extinction law, E(V-R) = 0.0274 cosec|b|, provides a good approximation to the extinction toward the MACHO bulge/bar fields. The large-scale (V-R)-color and visual extinction map presented here will be made ...

  15. Molecular thermodynamic modeling of ionic liquids using the perturbation-based linear Yukawa isotherm regularity.

    Science.gov (United States)

    Sohrabi Mahboub, Mahdi; Farrokhpour, Hossein

    2016-06-15

    In this paper, we present the results of an extensive study on a novel approach to the molecular modeling of pure ionic liquids (ILs) that incorporates the perturbed thermodynamic linear Yukawa isotherm regularity (LYIR), which is derived based on an effective nearest neighboring pair attractive interaction of the Yukawa potential. The LYIR was used to model the densities of ILs up to high pressures (35 MPa) and in the temperature range 293.15 to 393.15 K. To use the LYIR for ILs, a simple molecular model was proposed to describe their molecular structure, in which they were considered as a liquid consisting of the ion pairs moving together in the fluid, and each ion pair was assumed to be a one-center spherical united atom. The ILs under consideration contained one of the IL cations [C2mim](+), [C4mim](+), [C7mim](+), [C8mim](+), [C3mpy](+), [C3mpip](+), [C3mpyr](+) or [C4mpyr](+), and one of the IL anions [BF4](-), [C(CN)3](-), [CF3SO4](-) or [NTf2](-). The reliability and physical significance of the parameters as well as the proposed molecular model were tested by calculating the densities of pure imidazolium-, pyridinium-, piperidinium- and pyrrolidimium-based ILs. The results showed that the LYIR can be used to predict and reproduce the density of ILs in good agreement with the experimental data. In addition, the LYIR enabled us to determine the physical quantities, such as an effective Yukawa screening length, λ eff, the product of the effective energy well depth and the effective coordination number, (ε eff/k)z eff, the contribution of the non-reference thermal pressure and also the influence of the anionic and cationic structure on the λ eff parameter. The standard deviation of the IL densities predicted in this work is lower than those calculated by the one other important equation of state reported in the literature. PMID:27157142

  16. Molecular thermodynamic modeling of ionic liquids using the perturbation-based linear Yukawa isotherm regularity

    Science.gov (United States)

    Sohrabi Mahboub, Mahdi; Farrokhpour, Hossein

    2016-06-01

    In this paper, we present the results of an extensive study on a novel approach to the molecular modeling of pure ionic liquids (ILs) that incorporates the perturbed thermodynamic linear Yukawa isotherm regularity (LYIR), which is derived based on an effective nearest neighboring pair attractive interaction of the Yukawa potential. The LYIR was used to model the densities of ILs up to high pressures (35 MPa) and in the temperature range 293.15 to 393.15 K. To use the LYIR for ILs, a simple molecular model was proposed to describe their molecular structure, in which they were considered as a liquid consisting of the ion pairs moving together in the fluid, and each ion pair was assumed to be a one-center spherical united atom. The ILs under consideration contained one of the IL cations [C2mim]+, [C4mim]+, [C7mim]+, [C8mim]+, [C3mpy]+, [C3mpip]+, [C3mpyr]+ or [C4mpyr]+, and one of the IL anions [BF4]‑, [C(CN)3]‑, [CF3SO4]‑ or [NTf2]‑. The reliability and physical significance of the parameters as well as the proposed molecular model were tested by calculating the densities of pure imidazolium-, pyridinium-, piperidinium- and pyrrolidimium-based ILs. The results showed that the LYIR can be used to predict and reproduce the density of ILs in good agreement with the experimental data. In addition, the LYIR enabled us to determine the physical quantities, such as an effective Yukawa screening length, λ eff, the product of the effective energy well depth and the effective coordination number, (ε eff/k)z eff, the contribution of the non-reference thermal pressure and also the influence of the anionic and cationic structure on the λ eff parameter. The standard deviation of the IL densities predicted in this work is lower than those calculated by the one other important equation of state reported in the literature.

  17. Investigation into the factors that influence inverse bulging effect during sheet hydro-mechanical deep drawing

    Directory of Open Access Journals (Sweden)

    Lang Lihui

    2015-01-01

    Full Text Available The factors that influence inverse bulging effect during sheet hydro-mechanical deep drawing are especially researched in this paper. According to the different inverse bulging process, two modes can be singled: the initial inverse bulging (IIB and the local inverse bulging (LIB. IIB includes two parameters: inverse bulging height ratio (HIb/t and inverse bulging pressure ratio (PIb/t. LIB is influenced by IIB and has a direct relationship with liquid chamber pressure in the forming process. The optimal inverse bulging parameters of hemispherical bottom cylindrical part and flat bottom cylindrical part are obtained by numerical simulation. Process parameters including the clearance between the punch and the blank holder and the blank holder entrance radius that have a large influence on inverse bulging effect are optimized, so as to make inverse bulging effect behave better in hydroforming process. Finally, the accuracy of the numerical simulation results was verified by experiments.

  18. Design of Ni-base superalloys and MCrAlY coatings from first-principles and computational thermodynamics

    Science.gov (United States)

    Liu, Xuan

    This thesis explores the thermodynamics of Ni-base superalloys and metallic coatings used in the protection of these alloys. First, a thermodynamic description of the Nb-Re binary system is developed by means of the CALculation of PHAse Diagrams (CALPHAD) method supplemented by first-principles calculations based on density functional theory (DFT) and experimental data in the literature. In addition to terminal solution phases in the Nb-Re system, there are two intermetallic phases, sigma (sigma) and chi (chi), all modeled with sublattice models. Special quasi-random structures (SQS) are employed to mimic the random mixing of the bcc, hcp, and fcc solid solution phases from first-principles. Finite temperature thermodynamic properties of end-members and dilute mixing in each sublattice of the complex sigma and chi phases are predicted from first-principles calculations and the Debye-Gruneisen model. The utility of the Debye-Gruneisen model is then investigated with respect to its fitting parameter known as the scaling factor, and it is found that the prediction of finite-temperature properties can be improved by modification of this factor. This scaling factor is studied using bcc, fcc, hcp systems and the Mg-Zn binary system due to the abundance of thermodynamic data. Predicted Debye temperatures (thetaD), using a calculated scaling factor, show good agreement with experiments and improvements over the scaling factor derived by Moruzzi et al. Finite-temperature thermodynamic properties of intermetallics are investigated to show the efficiency and improved accuracy of the calculated scaling factor. However, for the intermetallic Mg2Zn11, the Debye-Gruneisen model cannot account for anomalous lattice dynamics at low temperatures. The calculated scaling factor is then used throughout the present work for finite-temperature predictions. Another missing piece of the literature includes the thermodynamics of Al-Co-Cr-Ni bond coat system used in the protection of

  19. Advanced thermodynamics engineering

    CERN Document Server

    Annamalai, Kalyan; Jog, Milind A

    2011-01-01

    Thermolab Excel-Based Software for Thermodynamic Properties and Flame Temperatures of Fuels IntroductionImportance, Significance and LimitationsReview of ThermodynamicsMathematical BackgroundOverview of Microscopic/NanothermodynamicsSummaryAppendix: Stokes and Gauss Theorems First Law of ThermodynamicsZeroth LawFirst Law for a Closed SystemQuasi Equilibrium (QE) and Nonquasi-equilibrium (NQE) ProcessesEnthalpy and First LawAdiabatic Reversible Process for Ideal Gas with Constant Specific HeatsFirst Law for an Open SystemApplications of First Law for an Open SystemIntegral and Differential Form

  20. Fracture and springback on Double Bulge Tube Hydro-Forming

    Directory of Open Access Journals (Sweden)

    F. Djavanroodi

    2008-01-01

    Full Text Available This research aims to establish a basic understanding of Double Bulge Tube Hydro-Form processing of stainless steel deep drawn cups. The method is briefly reviewed by carrying out experimental tests and Finite element analysis. By measuring bulge height in both formed curves by Coordinate measuring machine (CMM and thickness variation specimen by Ulterasonic thickness measurment device (UTM, it has been shown that maximum thinness occured where the bending is maximized. A finite element model is constructed to simulate the Double Bulge Tube Hydro Forming process and asses the influence of friction cofficient, tube Material properties and springback. It has been shown that material hardening coefficient had the most significant influence on formability characteristics during double bulge tube hydroforming. Also it is shown that springback has significant effect on tolerances of formed tube. Finally fracture strain was estimated by analytical method and compared with simulation results, also fracture location was predicted on Double Bulge Tube Hydro-Forming (DBTHF by simulating the process.

  1. Cusps and Cores in the presence of galactic bulges

    CERN Document Server

    Del Popolo, Antonino

    2014-01-01

    In this paper, we study how the presence of bulge formation in galaxies influence their inner density profile, by means of an extended version of the Del Popolo (2009) semi-analytical model. As in Del Popolo (2009), the model takes into account the effect of baryons adiabatic contraction, ordered and random angular momentum, dynamical friction, and adds to the previous the effect of gas cooling, star formation, supernova feedback, and reionization. Our model shows that dwarf galaxies are bulgeless, in agreement with observations showing that the large majority of them has no stellar bulges, and are characterized by a flat profile well described by a Burkert profile. {We then studied the effect of a bulge, added to the {cored} DM halo, on the density profile}. In the case of a galaxy having a mass $10^{11} M_{\\odot}$ the inner density profile has a slope $\\alpha \\simeq 0.65$, for a bulge of $4.5 \\times 10^{9} M_{\\odot}$, while if bulge formation is not considered, the slope would be $\\alpha \\simeq 0.55$. If th...

  2. Bulge growth through disk instabilities in high-redshift galaxies

    CERN Document Server

    Bournaud, Frederic

    2015-01-01

    The role of disk instabilities, such as bars and spiral arms, and the associated resonances, in growing bulges in the inner regions of disk galaxies have long been studied in the low-redshift nearby Universe. There it has long been probed observationally, in particular through peanut-shaped bulges. This secular growth of bulges in modern disk galaxies is driven by weak, non-axisymmetric instabilities: it mostly produces pseudo-bulges at slow rates and with long star-formation timescales. Disk instabilities at high redshift (z>1) in moderate-mass to massive galaxies (10^10 to a few 10^11 Msun of stars) are very different from those found in modern spiral galaxies. High-redshift disks are globally unstable and fragment into giant clumps containing 10^8-10^9 Msun of gas and stars each, which results in highly irregular galaxy morphologies. The clumps and other features associated to the violent instability drive disk evolution and bulge growth through various mechanisms, on short timescales. The giant clumps can...

  3. Chemical abundances in a high-velocity RR Lyrae star near the bulge

    Science.gov (United States)

    Hansen, C. J.; Rich, R. M.; Koch, A.; Xu, S.; Kunder, A.; Ludwig, H.-G.

    2016-05-01

    Low-mass variable high-velocity stars are interesting study cases for many aspects of Galactic structure and evolution. Until recently, the only known high- or hyper-velocity stars were young stars thought to originate from the Galactic center. Wide-area surveys such as APOGEE and BRAVA have found several low-mass stars in the bulge with Galactic rest-frame velocities higher than 350 km s-1. In this study we present the first abundance analysis of a low-mass RR Lyrae star that is located close to the Galactic bulge, with a space motion of ~-400 km s-1. Using medium-resolution spectra, we derived abundances (including upper limits) of 11 elements. These allowed us to chemically tag the star and discuss its origin, although our derived abundances and metallicity, at [Fe/H] =-0.9 dex, do not point toward one unambiguous answer. Based on the chemical tagging, we cannot exclude that it originated in the bulge. However, its retrograde orbit and the derived abundances combined suggest that the star was accelerated from the outskirts of the inner (or even outer) halo during many-body interactions. Other possible origins include the bulge itself, or the star might have been stripped from a stellar cluster or the Sagittarius dwarf galaxy when it merged with the Milky Way. The data presented herein were obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California and the National Aeronautics and Space Administration. The Observatory was made possible by the generous financial support of the W. M. Keck Foundation.

  4. Determination of Cloud Thermodynamic Phase with Ground Based, Polarimetrically Sensitive, Passive Sky Radiometers

    Science.gov (United States)

    Knobelspiesse, K. D.; van Diedenhoven, B.; Marshak, A.; Dunagan, S. E.; Holben, B. N.; Slutsker, I.

    2015-12-01

    When observed from the ground, optically thick clouds minimally polarize light, while the linear polarization direction (angle) of optically thin clouds contains information about thermodynamic phase. For instruments such at the Cimel radiometers that comprise the AErosol RObotic NEtwork (AERONET), these properties can also be exploited to aid cloud optical property retrievals. Using vector radiative transfer simulations, we explore the conditions most favorable to cloud thermodynamic phase determination, then test with actual AERONET data. Results indicate that this technique may be appropriate for some, but not all, conditions, and motivate a deeper investigation about the polarization direction measurement capability of Cimel instruments, which to date have been primarily used to determine degree of polarization. Recent work explores these measurement issues using a newly installed instrument at the NASA Ames Research Center in Moffett Field, California.

  5. Mapping the Three-Dimensional "X-Shaped Structure" in Models of the Galactic Bulge

    CERN Document Server

    Li, Zhao-Yu

    2015-01-01

    Numerical simulations have shown that the X-shaped structure in the Milky Way bulge can naturally arise from the bar instability and buckling instability. To understand the influence of the buckling amplitude on the morphology of the X-shape, we analyze three self-consistent numerical simulations of barred galaxies with different buckling amplitudes (strong, intermediate and weak). We derive the three-dimensional density with an adaptive kernel smoothing technique. The face-on iso-density surfaces are all elliptical, while in the edge-on view, the morphology of buckled bars transitions with increasing radius, from a central boxy core to a peanut bulge and then to an extended thin bar. Based on these iso-density surfaces at different density levels, we find no clear evidence for a well-defined structure shaped like a letter X. The X-shaped structure is more peanut-like, whose visual perception is probably enhanced by the pinched inner concave iso-density contours. The peanut bulge can reproduce qualitatively t...

  6. The WFC3 Galactic Bulge Treasury Program: A First Look at Resolved Stellar Population Tools

    CERN Document Server

    Brown, Thomas M; Zoccali, Manuela; Renzini, Alvio; Ferguson, Henry C; Anderson, Jay; Smith, Ed; Bond, Howard E; Minniti, Dante; Valenti, Jeff A; Casertano, Stefano; Livio, Mario; Panagia, Nino; VandenBerg, Don A; Valenti, Elena

    2008-01-01

    [Abridged] When WFC3 is installed on HST, the community will have powerful new tools for investigating resolved stellar populations. The WFC3 Galactic Bulge Treasury program will obtain deep imaging on 4 low-extinction fields. These non-proprietary data will enable a variety of science investigations not possible with previous data sets. To aid in planning for the use of these data and for future proposals, we provide an introduction to the program, its photometric system, and the associated calibration effort. The observing strategy is based upon a new 5-band photometric system spanning the UV, optical, and near-infrared. With these broad bands, one can construct reddening-free indices of Teff and [Fe/H]. Besides the 4 bulge fields, the program will target 6 fields in well-studied star clusters, spanning a wide range of [Fe/H]. The cluster data serve to calibrate the indices, provide population templates, and correct the transformation of isochrones into the WFC3 photometric system. The bulge data will shed ...

  7. Nonlinear Local Bending Response and Bulging Factors for Longitudinal and Circumferential Cracks in Pressurized Cylindrical Shells

    Science.gov (United States)

    Young, Richard D.; Rose, Cheryl A.; Starnes, James H., Jr.

    2000-01-01

    Results of a geometrically nonlinear finite element parametric study to determine curvature correction factors or bulging factors that account for increased stresses due to curvature for longitudinal and circumferential cracks in unstiffened pressurized cylindrical shells are presented. Geometric parameters varied in the study include the shell radius, the shell wall thickness, and the crack length. The major results are presented in the form of contour plots of the bulging factor as a function of two nondimensional parameters: the shell curvature parameter, lambda, which is a function of the shell geometry, Poisson's ratio, and the crack length; and a loading parameter, eta, which is a function of the shell geometry, material properties, and the applied internal pressure. These plots identify the ranges of the shell curvature and loading parameters for which the effects of geometric nonlinearity are significant. Simple empirical expressions for the bulging factor are then derived from the numerical results and shown to predict accurately the nonlinear response of shells with longitudinal and circumferential cracks. The numerical results are also compared with analytical solutions based on linear shallow shell theory for thin shells, and with some other semi-empirical solutions from the literature, and limitations on the use of these other expressions are suggested.

  8. Chemical abundances in a high velocity RR Lyrae star near the bulge

    CERN Document Server

    Hansen, Camilla Juul; Koch, Andreas; Xu, Siyi; Kunder, Andrea; Ludwig, Hans-Guenter

    2016-01-01

    Low-mass, variable, high-velocity stars are interesting study cases for many aspects of Galactic structure and evolution. Until recently, the only known high- or hyper-velocity stars were young stars thought to originate from the Galactic centre. Wide-area surveys like APOGEE and BRAVA have found several low-mass stars in the bulge with Galactic rest-frame velocities larger than 350 km/s. In this study we present the first abundance analysis of a low-mass, RR Lyrae star, located close to the Galactic bulge, with a space motion of ~ -400 km/s. Using medium-resolution spectra, we derive abundances (including upper limits) of 11 elements. These allow us to chemically tag the star and discuss its origin, although our derived abundances and metallicity, at [Fe/H] =-0.9 dex, do not point toward one unambiguous answer. Based on the chemical tagging, we cannot exclude that it originated in the bulge. However, combining its retrograde orbit and the derived abundances suggests that the star was accelerated from the out...

  9. Bulge Growth and Quenching since z = 2.5 in CANDELS/3D-HST

    CERN Document Server

    Lang, Philipp; Somerville, Rachel; Schreiber, Natascha M Forster; Genzel, Reinhard; Bell, Eric F; Brammer, Gabe; Dekel, Avishai; Faber, Sandra M; Ferguson, Henry C; Grogin, Norman A; Kocevski, Dale D; Koekemoer, Anton M; Lutz, Dieter; McGrath, Elizabeth J; Momcheva, Ivelina; Nelson, Erica J; Primack, Joel R; Rosario, David J; Skelton, Rosalind E; Tacconi, Linda J; van Dokkum, Pieter G; Whitaker, Katherine E

    2014-01-01

    Exploiting the deep high-resolution imaging of all 5 CANDELS fields, and accurate redshift information provided by 3D-HST, we investigate the relation between structure and stellar populations for a mass-selected sample of 6764 galaxies above 10^10 Msun, spanning the redshift range 0.5 < z < 2.5. For the first time, we fit 2-dimensional models comprising a single Sersic fit and two-component (i.e., bulge + disk) decompositions not only to the H-band light distributions, but also to the stellar mass maps reconstructed from resolved stellar population modeling. We confirm that the increased bulge prominence among quiescent galaxies, as reported previously based on rest-optical observations, remains in place when considering the distributions of stellar mass. Moreover, we observe an increase of the typical Sersic index and bulge-to-total ratio (with median B/T reaching 40-50%) among star-forming galaxies above 10^11 Msun. Given that quenching for these most massive systems is likely to be imminent, our fin...

  10. Optical Gravitational Lensing Experiment. The Distance Scale Galactic Bulge - LMC - SMC

    CERN Document Server

    Udalski, A

    1998-01-01

    We analyze the mean luminosity of three samples of field RRab Lyr stars observed in the course of the OGLE microlensing experiment: 73 stars from the Galactic bulge and 110 and 128 stars from selected fields in the LMC and SMC, respectively. The fields are the same as in the recent distance determination to the Magellanic Clouds with the red clump stars method by Udalski et al (1998). We determine the relative distance scale d_{GB}:d_{LMC}:d_{SMC} equal to: (0.194+/-0.010):1.00:(1.30+/-0.08). We calibrate our RR Lyr distance scale with the recent calibration of Gould and Popowski (1998) based on statistical parallaxes. We obtain the following distance moduli to the Galactic bulge, LMC and SMC: m-M=14.53+/-0.15, m-M=18.09+/-0.16 and m-M=18.66+/-0.16 mag. We use the RR Lyr mean V-band luminosity at the Galactic bulge metallicity as the reference brightness and analyze the mean, I-band luminosity of the red clump stars in objects with different ages and metallicities. We add to our analysis the metal poor Carina...

  11. Dynamical evolution of a bulge in an N-body model of the Milky Way

    Directory of Open Access Journals (Sweden)

    Gerhard O.

    2012-02-01

    Full Text Available The detailed dynamical structure of the bulge in the Milky Way is currently under debate. Although kinematics of the bulge stars can be well reproduced by a boxy-bulge, the possible existence of a small embedded classical bulge can not be ruled out. We study the dynamical evolution of a small classical bulge in a model of the Milky Way using a self-consistent high resolution N-body simulation. Detailed kinematics and dynamical properties of such a bulge are presented.

  12. Theoretical models for fluid thermodynamics based on the quasi-Gaussian entropy theory

    OpenAIRE

    Amadei, Andrea

    1998-01-01

    Summary The theoretical modeling of fluid thermodynamics is one of the most challenging fields in physical chemistry. In fact the fluid behavior, except at very low density conditions, is still extremely difficult to be modeled from a statistical mechanical point of view, as for any realistic model Hamiltonian the configurational part of the partition function cannot be evaluated, i.e., the corresponding high dimensional integral is far too complex to be solved. Hence once a molecular Hamilto...

  13. Embodiment Analysis for Greenhouse Gas Emissions by Chinese Economy Based on Global Thermodynamic Potentials

    OpenAIRE

    Lijie Wang; Xiangyang Xu; Suping Peng; Bo Zhang

    2011-01-01

    This paper considers the Global Thermodynamic Potential (GTP) indicator to perform a unified assessment of greenhouse gas (GHG) emissions, and to systematically reveal the emission embodiment in the production, consumption, and international trade of the Chinese economy in 2007 as the most recent year available with input-output table and updated inventory data. The results show that the estimated total direct GHG emissions by the Chinese economy in 2007 amount to 10,657.5 Mt CO 2 -eq by the ...

  14. Practical thermodynamic quantities for aqueous vanadium- and iron-based flow batteries

    Science.gov (United States)

    Hudak, Nicholas S.

    2014-12-01

    A simple method for experimentally determining thermodynamic quantities for flow battery cell reactions is presented. Equilibrium cell potentials, temperature derivatives of cell potential (dE/dT), Gibbs free energies, and entropies are reported here for all-vanadium, iron-vanadium, and iron-chromium flow cells with state-of-the-art solution compositions. Proof is given that formal potentials and formal temperature coefficients can be used with modified forms of the Nernst Equation to quantify the thermodynamics of flow cell reactions as a function of state-of-charge. Such empirical quantities can be used in thermo-electrochemical models of flow batteries at the cell or system level. In most cases, the thermodynamic quantities measured here are significantly different from standard values reported and used previously in the literature. The data reported here are also useful in the selection of operating temperatures for flow battery systems. Because higher temperatures correspond to lower equilibrium cell potentials for the battery chemistries studied here, it can be beneficial to charge a cell at higher temperature and discharge at lower temperature. Proof-of-concept of improved voltage efficiency with the use of such non-isothermal cycling is given for the all-vanadium redox flow battery, and the effect is shown to be more pronounced at lower current densities.

  15. Near-Infrared Bulge-Disk Correlations of Lenticular Galaxies

    CERN Document Server

    Barway, Sudhanshu; Kembhavi, Ajit K; Mayya, Y D

    2008-01-01

    We consider the luminosity and environmental dependence of structural parameters of lenticular galaxies in the near-infrared K band. Using a two-dimensional galaxy image decomposition technique, we extract bulge and disk structural parameters for a sample of 36 lenticular galaxies observed by us in the K band. By combining data from the literature for field and cluster lenticulars with our data, we study correlations between parameters that characterise the bulge and the disk as a function of luminosity and environment. We find that scaling relations such as the Kormendy relation, photometric plane and other correlations involving bulge and disk parameters show a luminosity dependence. This dependence can be explained in terms of galaxy formation models in which faint lenticulars (M_T > -24.5) formed via secular formation processes that likely formed the pseudobulges of late-type disk galaxies, while brighter lenticulars (M_T < -24.5) formed through a different formation mechanism most likely involving maj...

  16. The lack of carbon stars in the Galactic bulge

    Institute of Scientific and Technical Information of China (English)

    Zhu Chun-Hua; Lv Guo-Liang; Wang Zhao-Jun; Zhang Jun

    2008-01-01

    In order to explain the lack of carbon stars in the Galactic bulge, we have made a detailed study of thermal pulseasymptotic giant branch (TP-AGB) stars by using a population synthesis code. The effects of the oxygen overabundance and the mass loss rate on the ratio of the number of carbon stars to that of oxygen stars in the Galactic bulge are discussed. We find that the oxygen overabundance which is about twice as large as that in the solar neighbourhood (close to the present observations) is insufficient to explain the rareness of carbon stars in the bulge. We suggest that the large mass loss rate may serve as a controlling factor in the ratio of the number of carbon stars to that of oxygen stars.

  17. Stellar populations in the bulges of isolated galaxies

    Science.gov (United States)

    Morelli, L.; Parmiggiani, M.; Corsini, E. M.; Costantin, L.; Dalla Bontà, E.; Méndez-Abreu, J.; Pizzella, A.

    2016-09-01

    We present photometry and long-slit spectroscopy for 12 S0 and spiral galaxies selected from the Catalogue of Isolated Galaxies. The structural parameters of the sample galaxies are derived from the Sloan Digital Sky Survey i-band images by performing a two-dimensional photometric decomposition of the surface brightness distribution. This is assumed to be the sum of the contribution of a Sérsic bulge, an exponential disc, and a Ferrers bar characterized by elliptical and concentric isophotes with constant ellipticity and position angles. The rotation curves and velocity dispersion profiles of the stellar component are measured from the spectra obtained along the major axis of galaxies. The radial profiles of the Hβ, Mg and Fe line-strength indices are derived too. Correlations between the central values of the Mg 2 and line-strength indices and the velocity dispersion are found. The mean age, total metallicity and total α/Fe enhancement of the stellar population in the centre and at the radius where the bulge gives the same contribution to the total surface brightness as the remaining components are obtained using stellar population models with variable element abundance ratios. We identify intermediate-age bulges with solar metallicity and old bulges with a large spread in metallicity. Most of the sample bulges display super-solar α/Fe enhancement, no gradient in age and negative gradients of metallicity and α/Fe enhancement. These findings support a formation scenario via dissipative collapse where environmental effects are remarkably less important than in the assembly of bulges of galaxies in groups and clusters.

  18. Atmospheric thermodynamics

    CERN Document Server

    Iribarne, J V

    1973-01-01

    The thermodynamics of the atmosphere is the subject of several chapters in most textbooks on dynamic meteorology, but there is no work in English to give the subject a specific and more extensive treatment. In writing the present textbook, we have tried to fill this rather remarkable gap in the literature related to atmospheric sciences. Our aim has been to provide students of meteorology with a book that can playa role similar to the textbooks on chemical thermodynamics for the chemists. This implies a previous knowledge of general thermodynamics, such as students acquire in general physics courses; therefore, although the basic principles are reviewed (in the first four chapters), they are only briefly discussed, and emphasis is laid on those topics that will be useful in later chapters, through their application to atmospheric problems. No attempt has been made to introduce the thermodynamics of irreversible processes; on the other hand, consideration of heterogeneous and open homogeneous systems permits a...

  19. The X-shaped Bulge of the Milky Way Revealed by WISE

    Science.gov (United States)

    Ness, Melissa; Lang, Dustin

    2016-07-01

    The Milky Way bulge has a boxy/peanut morphology and an X-shaped structure. This X-shape has been revealed by the “split in the red clump” from star counts along the line of sight toward the bulge, measured from photometric surveys. This boxy, X-shaped bulge morphology is not unique to the Milky Way and such bulges are observed in other barred spiral galaxies. N-body simulations show that boxy and X-shaped bulges are formed from the disk via dynamical instabilities. It has also been proposed that the Milky Way bulge is not X-shaped, but rather, the apparent split in the red clump stars is a consequence of different stellar populations, in an old classical spheroidal bulge. We present a Wide-Field Infrared Survey Explorer (WISE) image of the Milky Way bulge, produced by downsampling the publicly available “unWISE” coadds. The WISE image of the Milky Way bulge shows that the X-shaped nature of the Milky Way bulge is self-evident and irrefutable. The X-shape morphology of the bulge in itself and the fraction of bulge stars that comprise orbits within this structure has important implications for the formation history of the Milky Way, and, given the ubiquity of boxy X-shaped bulges, spiral galaxies in general.

  20. Chemodynamical analysis of bulge stars for simulated disc galaxies

    OpenAIRE

    A. Rahimi; Kawata, D.; Brook, Chris B.; Gibson, Brad K.

    2009-01-01

    We analyse the kinematics and chemistry of the bulge stars of two simulated disc galaxies using our chemodynamical galaxy evolution code GCD+. First we compare stars that are born inside the galaxy with those that are born outside the galaxy and are accreted into the centre of the galaxy. Stars that originate outside of the bulge are accreted into it early in its formation within 3 Gyrs so that these stars have high [alpha/Fe] as well as having a high total energy reflecting their accretion t...

  1. The lack of carbon stars in the Galactic bulge

    OpenAIRE

    Chunhua, Zhu; Guoliang, Lv; Zhaojun, Wang; Jun, Zhang

    2008-01-01

    In order to explain the lack of carbon stars in the Galactic bulge, we have made a detailed study of thermal pulse - asymptotic giant branch stars by using a population synthesis code. The effects of the oxygen overabundance and the mass loss rate on the ratio of the number of carbon stars to that of oxygen stars in the Galactic bulge are discussed. We find that the oxygen overabundance which is about twice as large as that in the solar neighbourhood (close to the present observations) is ins...

  2. Ongoing massive star formation in the bulge of M51

    OpenAIRE

    Lamers, H. J. G. L. M.; Panagia, N.; Scuderi, S.; Romaniello, M.; Spaans, M.; de Wit, W.J.M.; Krishner, R.

    2001-01-01

    We studied the HST-WFPC2 observations of the inner kpc of the interacting galaxy M51 in six bands from 2550 to 8140 Angstrom. The images show an oval shaped area ("bulge") of 11x16 arcsec or 450x650 pc around the nucleus, dominated by a smooth population of old stars with overimposed dust lanes. We found 30 bright point-like sources in the bulge of M51; many of these are bright in the UV. They are located in elongated "strings" which follow the general pattern of the dust lanes. The spectral ...

  3. Correspondence between cluster-ion and bulk solution thermodynamic properties: on the validity of the cluster-pair-based approximation.

    Science.gov (United States)

    Vlcek, Lukas; Chialvo, Ariel A; Simonson, J Michael

    2013-11-01

    Since the single-ion thermodynamic properties of bulk solutions are not directly accessible from experiments, extrapolations have been devised to estimate them from experimental measurements on small-clusters. Extrapolations based on the cluster-pair-based approximation (CPA) technique (Tissandier et al. J. Phys. Chem. A 1998, 102, 7787-7794) and its variants are currently considered one of the most reliable source of single-ion hydration thermodynamic data and have been used as a benchmark for the development of molecular and continuum solvation models. Despite its importance, the CPA has not been thoroughly tested and recent studies have indicated inconsistencies with molecular simulations. The present work challenges the key CPA assumptions that the hydration properties of single cations and anions in growing clusters rapidly converge to each other following a monotonous trend. Using a combination of simulation techniques to study the transition between alkali halide ions in small clusters and bulk solution, we show that this convergence is rather slow and involves a surprising change in trends, which can result in significant errors in the original estimated single-ion properties. When these cluster-size-dependent effects are taken into account, the inconsistencies between molecular models and experimental predictions disappear, and the value of the proton hydration enthalpy based on the CPA aligns with estimates based on other principles.

  4. Thermodynamic analysis of a low-temperature waste heat recovery system based on the concept of solar chimney

    International Nuclear Information System (INIS)

    Highlights: • A low grade waste heat recovery system based on the concept of solar chimney is proposed. • The effects of three key factors on the system performance are examined. • Thermodynamics analysis is to find a better way to utilize low grade heat source efficiently. - Abstract: The utilization of low-temperature waste heat draws more and more attention due to serious energy crisis nowadays. This paper proposes a low-temperature waste heat recovery system based on the concept of solar chimney. In the system, low-temperature waste heat is used to heat air to produce an air updraft in the chimney tower. The air updraft propels a turbine fixed at the base of the chimney tower to convert waste heat into electricity. The mathematical model of the system is established based on first law and second law of thermodynamics. Hot water is selected as the representative of low-temperature waste heat sources for researching. The heat source temperature, ambient air temperature and area of heat transfer are examined to evaluate their effects on the system performance such as velocity of updraft, mass flow rate of air, power output, conversion efficiency, and exergy efficiency. The velocity of air demonstrates a better stability than the mass flow rate of air and the pressure difference when temperature of heat source, ambient air temperature or area of heat transfer changes

  5. Constructor Theory of Thermodynamics

    CERN Document Server

    Marletto, Chiara

    2016-01-01

    The laws of thermodynamics, powerful for countless purposes, are not exact: both their phenomenological and their statistical-mechanical versions are valid only at 'macroscopic scales', which are never defined. Here I propose a new, exact and scale-independent formulation of the first and second laws of thermodynamics, using the principles and tools of the recently proposed constructor theory. Specifically, I improve upon the axiomatic formulations of thermodynamics (Carath\\'eodory, 1909; Lieb and Yngvason, 1999) by proposing an exact and more general formulation of 'adiabatic accessibility'. This work provides an exact distinction between work and heat; it reveals an unexpected connection between information theory and the first law of thermodynamics (not just the second); it resolves the clash between the irreversibility of the 'cycle'-based second law and time-reversal symmetric dynamical laws. It also achieves the long-sought unification of the axiomatic version of the second law with Kelvin's.

  6. Thermodynamic-based retention time predictions of endogenous steroids in comprehensive two-dimensional gas chromatography.

    Science.gov (United States)

    Silva, Aline C A; Ebrahimi-Najafadabi, Heshmatollah; McGinitie, Teague M; Casilli, Alessandro; Pereira, Henrique M G; Aquino Neto, Francisco R; Harynuk, James J

    2015-05-01

    This work evaluates the application of a thermodynamic model to comprehensive two-dimensional gas chromatography (GC × GC) coupled with time-of-flight mass spectrometry for anabolic agent investigation. Doping control deals with hundreds of drugs that are prohibited in sports. Drug discovery in biological matrices is a challenging task that requires powerful tools when one is faced with the rapidly changing designer drug landscape. In this work, a thermodynamic model developed for the prediction of both primary and secondary retention times in GC × GC has been applied to trimethylsilylated hydroxyl (O-TMS)- and methoxime-trimethylsilylated carbonyl (MO-TMS)-derivatized endogenous steroids. This model was previously demonstrated on a pneumatically modulated GC × GC system, and is applied for the first time to a thermally modulated GC × GC system. Preliminary one-dimensional experiments allowed the calculation of thermodynamic parameters (ΔH, ΔS, and ΔC p ) which were successfully applied for the prediction of the analytes' interactions with the stationary phases of both the first-dimension column and the second-dimension column. The model was able to predict both first-dimension and second-dimension retention times with high accuracy compared with the GC × GC experimental measurements. Maximum differences of -8.22 s in the first dimension and 0.4 s in the second dimension were encountered for the O-TMS derivatives of 11β-hydroxyandrosterone and 11-ketoetiocholanolone, respectively. For the MO-TMS derivatives, the largest discrepancies were from testosterone (9.65 ) for the first-dimension retention times and 11-keto-etiocholanolone (0.4 s) for the second-dimension retention times.

  7. Reconciling the Galactic Bulge Turnoff Age Discrepancy with Enhanced Helium Enrichment

    CERN Document Server

    Nataf, David M

    2011-01-01

    We show that the factor $\\sim$2 discrepancy between spectroscopic and photometric age determinations of the Galactic bulge main-sequence turnoff can be naturally explained by positing an elevated helium enrichment for the bulge relative to that assumed by standard isochrones. We obtain an upper bound on the helium enrichment parameter of the bulge $({\\Delta}Y/{\\Delta}Z)_{\\rm{Bulge}} \\lesssim 5.0$ given the requirement that the spectroscopic and photometric ages be consistent and the limiting condition of instantaneous star formation. The corresponding mean age for the bulge is $t_{\\rm{Bulge}} \\approx 10$ Gyr. We discuss phenomenological evidence that the bulge may have had a chemical evolution that is distinct from the solar neighborhood in this manner, and we make several testable predictions. Should this emerging picture of the bulge as helium-enhanced hold, it will require the development of new isochrones, new model atmospheres, and modified analysis and cosmological interpretation of the integrated light...

  8. Thermodynamic Stability of Structure H Hydrates Based on the Molecular Properties of Large Guest Molecules

    Directory of Open Access Journals (Sweden)

    Ryo Ohmura

    2012-02-01

    Full Text Available This paper report analyses of thermodynamic stability of structure-H clathrate hydrates formed with methane and large guest molecules in terms of their gas phase molecular sizes and molar masses for the selection of a large guest molecule providing better hydrate stability. We investigated the correlation among the gas phase molecular sizes, the molar masses of large molecule guest substances, and the equilibrium pressures. The results suggest that there exists a molecular-size value for the best stability. Also, at a given molecule size, better stability may be available when the large molecule guest substance has a larger molar mass.

  9. Thermal conductivity of tubular nanowire composites based on a thermodynamical model

    Science.gov (United States)

    Lebon, Georgy; Machrafi, Hatim

    2015-07-01

    A formula for the effective heat conductivity of a nanocomposite with cylindrical nanowire inclusions is derived. Both transversal and longitudinal heating along the wires are investigated. Several effects are examined: the volume fraction and sizes of the nanowires, the type of scattering at the particle-matrix interface and temperature. As illustration, silicon nanowires inclusions in a germanium matrix is considered; the results are shown to be in good agreement with other models and numerical solutions of the Boltzmann transport equation. Our main contribution consists of using extended irreversible thermodynamics to cope with the nano dimensions of the wires.

  10. What planetary nebulae tell us about helium and the CNO elements in Galactic bulge stars

    OpenAIRE

    Buell, James F.

    2012-01-01

    Thermally pulsing asymptotic giant branch (TP-AGB) models of bulge stars are calculated using a synthetic model. The goal is to infer typical progenitor masses and compositions by reproducing the typical chemical composition and central star masses of planetary nebulae (PNe) in the Galactic bulge. The AGB tip luminosity and the observation that the observed lack of bright carbon stars in the bulge are matched by the models. Five sets of galactic bulge PNe were analyzed to find typical abundan...

  11. Thermodynamical analysis of a quantum heat engine based on harmonic oscillators.

    Science.gov (United States)

    Insinga, Andrea; Andresen, Bjarne; Salamon, Peter

    2016-07-01

    Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time. PMID:27575089

  12. A micromechanics-based thermodynamic model for the domain switch in ferroelectric crystals

    Energy Technology Data Exchange (ETDEWEB)

    Li, W.F.; Weng, G.J

    2004-05-03

    In this work we take the view that domain switch in ferroelectric crystals is a thermodynamics-driven process. In this light we first consider the micromechanics of domain switch to derive the Gibbs free energy of the heterogeneous system and the corresponding thermodynamic driving force at a given level of switched domain concentration f{sub p}, applied stress {sigma}-bar{sub ij}, and applied electric field E-bar{sub i}. Then in conjunction with Miller and Weinreich's [Phys. Rev. 117 (1960) 1460] resistance force for the sidewise motion of 180 deg. domain walls, a kinetic equation is established to calculate the evolution of new domains under a reversed electric field for a BaTiO{sub 3} crystal. The calculated results show that, as the field increases, the switching process is initially rapid, and then becomes quite slow as it approaches the saturation state. The calculated polarization versus the electric field relation (P-E relation) is found to agree with the measured characteristics. The effect of porosity on the switching processes is also examined. It is found that, due to the lower level of Gibbs free energy in the presence of pores, a higher field is required to overcome the energy resistance of domain switch. On the other hand, due to the lower initial parent domain concentration, the level of electric field to cause a complete reversal of the domains decreases with porosity.

  13. Thermodynamical analysis of a quantum heat engine based on harmonic oscillators

    Science.gov (United States)

    Insinga, Andrea; Andresen, Bjarne; Salamon, Peter

    2016-07-01

    Many models of heat engines have been studied with the tools of finite-time thermodynamics and an ensemble of independent quantum systems as the working fluid. Because of their convenient analytical properties, harmonic oscillators are the most frequently used example of a quantum system. We analyze different thermodynamical aspects with the final aim of the optimization of the performance of the engine in terms of the mechanical power provided during a finite-time Otto cycle. The heat exchange mechanism between the working fluid and the thermal reservoirs is provided by the Lindblad formalism. We describe an analytical method to find the limit cycle and give conditions for a stable limit cycle to exist. We explore the power production landscape as the duration of the four branches of the cycle are varied for short times, intermediate times, and special frictionless times. For short times we find a periodic structure with atolls of purely dissipative operation surrounding islands of divergent behavior where, rather than tending to a limit cycle, the working fluid accumulates more and more energy. For frictionless times the periodic structure is gone and we come very close to the global optimal operation. The global optimum is found and interestingly comes with a particular value of the cycle time.

  14. Computational Thermodynamics and Kinetics-Based ICME Framework for High-Temperature Shape Memory Alloys

    Science.gov (United States)

    Arróyave, Raymundo; Talapatra, Anjana; Johnson, Luke; Singh, Navdeep; Ma, Ji; Karaman, Ibrahim

    2015-11-01

    Over the last decade, considerable interest in the development of High-Temperature Shape Memory Alloys (HTSMAs) for solid-state actuation has increased dramatically as key applications in the aerospace and automotive industry demand actuation temperatures well above those of conventional SMAs. Most of the research to date has focused on establishing the (forward) connections between chemistry, processing, (micro)structure, properties, and performance. Much less work has been dedicated to the development of frameworks capable of addressing the inverse problem of establishing necessary chemistry and processing schedules to achieve specific performance goals. Integrated Computational Materials Engineering (ICME) has emerged as a powerful framework to address this problem, although it has yet to be applied to the development of HTSMAs. In this paper, the contributions of computational thermodynamics and kinetics to ICME of HTSMAs are described. Some representative examples of the use of computational thermodynamics and kinetics to understand the phase stability and microstructural evolution in HTSMAs are discussed. Some very recent efforts at combining both to assist in the design of HTSMAs and limitations to the full implementation of ICME frameworks for HTSMA development are presented.

  15. New insights on the Galactic Bulge Initial Mass Function

    CERN Document Server

    Calamida, A; Casertano, S; Anderson, J; Cassisi, S; Gennaro, M; Cignoni, M; Brown, T M; Kains, N; Ferguson, H; Livio, M; Bond, H E; Buonanno, R; Clarkson, W; Ferraro, I; Pietrinferni, A; Salaris, M; Valenti, J

    2015-01-01

    We have derived the Galactic bulge initial mass function of the SWEEPS field down to 0.15 $M_{\\odot}$, using deep photometry collected with the Advanced Camera for Surveys on the Hubble Space Telescope. Observations at several epochs, spread over 9 years, allowed us to separate the disk and bulge stars down to very faint magnitudes, $F814W \\approx$ 26 mag, with a proper-motion accuracy better than 0.5 mas/yr (20 km/s). This allowed us to determine the initial mass function of the pure bulge component uncontaminated by disk stars for this low-reddening field in the Sagittarius window. In deriving the mass function, we took into account the presence of unresolved binaries, errors in photometry, distance modulus and reddening, as well as the metallicity dispersion and the uncertainties caused by adopting different theoretical color-temperature relations. We found that the Galactic bulge initial mass function can be fitted with two power laws with a break at $M \\sim$ 0.56 $M_{\\odot}$, the slope being steeper ($\\a...

  16. Ongoing massive star formation in the bulge of M51

    NARCIS (Netherlands)

    Lamers, HJGLM; Panagia, N; Scuderi, S; Romaniello, M; Spaans, M; Kirshner, R

    2002-01-01

    We present a study of Hubble Space Telescope Wide Field Planetary Camera 2 observations of the inner kiloparsec of the interacting galaxy M51 in six bands from 2550 to 8140 Angstrom. The images show an oval-shaped area (which we call the "bulge") of about 11" x 16", or 450 x 650 pc, around the nucle

  17. The Metallicity Distribution of the Milky Way Bulge

    Science.gov (United States)

    Ness, M.; Freeman, K.

    2016-06-01

    The Galactic bulge of the Milky Way is made up of stars with a broad range of metallicity, -3.0 function decreases as a function of height z from the plane and, more weakly, with galactic radius R GC. The most metal-rich stars in the inner Galaxy are concentrated to the plane and the more metal-poor stars are found predominantly further from the plane, with an overall vertical gradient in the mean of the metallicity distribution function of about - 0.45 dex kpc-1. This vertical gradient is believed to reflect the changing contribution with height of different populations in the innermost region of the Galaxy. The more metal-rich stars of the bulge are part of the boxy/peanut structure and comprise stars in orbits which trace out the underlying X-shape. There is still a lack of consensus on the origin of the metal-poor stars ([Fe/H] function of the bulge, and identifying if there is a unique bulge population which has formed separately from the disk and halo, has important consequences for identifying the relevant processes in the formation and evolution of the Milky Way.

  18. Type-Ia Supernova-driven Galactic Bulge Wind

    CERN Document Server

    Tang, Shikui; Mac Low, Mordecai-Mark; Joung, M Ryan

    2009-01-01

    Stellar feedback in galactic bulges plays an essential role in shaping the evolution of galaxies. To quantify this role and facilitate comparisons with X-ray observations, we conduct 3D hydrodynamical simulations with the adaptive mesh refinement code, FLASH, to investigate the physical properties of hot gas inside a galactic bulge, similar to that of our Galaxy or M31. We assume that the dynamical and thermal properties of the hot gas are dominated by mechanical energy input from SNe, primarily Type Ia, and mass injection from evolved stars as well as iron enrichment from SNe. We study the bulge-wide outflow as well as the SN heating on scales down to ~4 pc. An embedding scheme that is devised to plant individual SNR seeds, allows to examine, for the first time, the effect of sporadic SNe on the density, temperature, and iron ejecta distribution of the hot gas as well as the resultant X-ray morphology and spectrum. We find that the SNe produce a bulge wind with highly filamentary density structures and patch...

  19. METAL-POOR GLOBULAR CLUSTERS OF THE GALACTIC BULGE

    Directory of Open Access Journals (Sweden)

    B. Barbuy

    2009-01-01

    Full Text Available We are carrying studies on the metal-poor globular clusters of the Galactic bulge. These objects appear to be very old, and might be relics of the rst objects in the Galaxy. High resolution observations carried out with VLT-UVES, VLT-FLAMES and Gemini-PHOENIX are presented, and the abundance pattern of these globulars is studied.

  20. The disc origin of the Milky Way bulge

    CERN Document Server

    Di Matteo, P

    2016-01-01

    The Galactic bulge, that is the prominent out-of-plane over-density present in the inner few kiloparsecs of the Galaxy, is a complex structure, as the morphology, kinematics, chemistry and ages of its stars indicate. To understand the nature of its main components -- those at [Fe/H] >~ -1 dex -- it is necessary to make an inventory of the stellar populations of the Galactic disc(s), and of their borders : the chemistry of the disc at the solar vicinity, well known from detailed studies of stars over many years, is not representative of the whole disc. This finding, together with the recent revisions of the mass and sizes of the thin and thick discs, constitutes a major step in understanding the bulge complexity. N-body models of a boxy/peanut-shaped bulge formed from a thin disc through the intermediary of a bar have been successful in interpreting a number of global properties of the Galactic bulge, but they fail in reproducing the detailed chemo-kinematic relations satisfied by its components and their morp...

  1. The Bases of Chemical Thermodynamics, Volumes 1 and 2 by Michael Graetzel and Pierre Infelta

    Science.gov (United States)

    van Hecke, Gerald R.

    2001-09-01

    Universal Publishers: Parkland, FL, 2000. Vol. 1: 298 pp. ISBN 1-58112-772-3. 25.95. Vol. 2: 300 pp. ISBN 1-58112-771-5. 25.95. Rarely does one pick up a text and find in it so many of one's favorite pedagogical devices. Graetzel and Infelta was a treat to read. The text offers many new and clever derivations of the well-worn equations of chemical thermodynamics and for this reason alone the text should be on the bookshelf of every serious teacher of thermodynamics. The writing is easy to read: not terse, but carefully worded as a thermodynamics text should be. There are no fancy sidebars or tidbits, just a straightforward presentation of material that is frankly refreshing. A brief description of the text should come next, for it consist of two volumes. You find in Volume 1 introductory material, the laws of thermodynamics, auxiliary functions, molar and partial molar quantities, gases, and component phase equilibria; in Volume 2, the energetics of chemical reactions, chemical equilibria, properties of ideal and nonideal mixtures, and an introduction to statistical mechanics. The authors make careful definitions of those slippery concepts, systems, states, and extensive and intensive variables, and use those definitions to show how the thermodynamic state of a system can be described in a minimum number of variables. A pedagogical feature that makes a hit with me is the authors' disuse of deltas. They explicitly write Ufinal - Uinitial instead of just good old DU, which really tells a reader nothing. How much better our students would understand thermodynamics if we were to ban D 's remains to be seen. The authors are consistent in their disuse of D 's except for standard expressions such as DrG°. Entropy, every beginning student's random nightmare, is introduced by the concept of arrangements available to the system. The number of arrangements can be quantified by various permutation formulas. Thank the authors for sticking with arrangements that can be

  2. The X-shaped Bulge of the Milky Way revealed by WISE

    CERN Document Server

    Ness, Melissa

    2016-01-01

    The Milky Way bulge has a boxy/peanut morphology and an X-shaped structure. This X-shape has been revealed by the `split in the red clump' from star counts along the line of sight toward the bulge, measured from photometric surveys. This boxy, X-shaped bulge morphology is not unique to the Milky Way and such bulges are observed in other barred spiral galaxies. N-body simulations show that boxy and X-shaped bulges are formed from the disk via dynamical instabilities. It has also been proposed that the Milky Way bulge is not X-shaped, but rather, the apparent split in the red clump stars is a consequence of different stellar populations, in an old classical spheroidal bulge. We present a WISE image of the Milky Way bulge, produced by downsampling the publicly available "unWISE" coadds. The WISE image of the Milky Way bulge shows that the X-shaped nature of the Milky Way bulge is self-evident and irrefutable. The X-shape morphology of the bulge in itself and the fraction of bulge stars that comprise orbits withi...

  3. Thermodynamic Analysis of a Cascade Refrigeration System Based On Carbon Dioxide and Ammonia

    Directory of Open Access Journals (Sweden)

    Satyananda Tripathy

    2014-07-01

    Full Text Available Thermodynamic analysis of a cascade refrigeration system that uses carbon dioxide-ammonia (R744-R717 as refrigerant is presented in this paper to determine the optimum condensing temperature of the cascade condenser at given design parameters, to maximize the COP of the system. The design and operating parameters considered in this study include (1 condensing, sub cooling, evaporating and super heating temperatures in the ammonia (R717 high-temperature circuit, (2 temperature difference in the cascade heat exchanger, and (3 evaporating, superheating, condensing and sub cooling in the carbon dioxide (R744 low-temperature circuit. A multilinear regression analysis was employed in order to develop two useful correlations for maximum COP, and optimum condensing temperature.

  4. A set of molecular models based on quantum mechanical ab initio calculations and thermodynamic data

    CERN Document Server

    Eckl, Bernhard; Hasse, Hans

    2009-01-01

    A parameterization strategy for molecular models on the basis of force fields is proposed, which allows a rapid development of models for small molecules by using results from quantum mechanical (QM) ab initio calculations and thermodynamic data. The geometry of the molecular models is specified according to the atom positions determined by QM energy minimization. The electrostatic interactions are modeled by reducing the electron density distribution to point dipoles and point quadrupoles located in the center of mass of the molecules. Dispersive and repulsive interactions are described by Lennard-Jones sites, for which the parameters are iteratively optimized to experimental vapor-liquid equilibrium (VLE) data, i.e. vapor pressure, saturated liquid density, and enthalpy of vaporization of the considered substance. The proposed modeling strategy was applied to a sample set of ten molecules from different substance classes. New molecular models are presented for iso-butane, cyclohexane, formaldehyde, dimethyl...

  5. Thermodynamic modelling of Li–Sn liquid alloy based on Knudsen effusion mass spectrometric measurements

    Energy Technology Data Exchange (ETDEWEB)

    Bencze, L., E-mail: bencze@chem.elte.hu [Institute for Energy and Climate Research (IEK-2), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany); Eötvös Loránd University, Dept. of Physical Chemistry, H-1117 Budapest, Pázmány Péter sétány 1/A (Hungary); Henriques, D. [Institute for Energy and Climate Research (IEK-2), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany); Motalov, V. [Institute for Energy and Climate Research (IEK-2), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany); Department of Physics, Ivanovo State University of Chemistry and Technology, Sheremetevsky av.7, 153000 Ivanovo (Russian Federation); Markus, T. [Institute for Energy and Climate Research (IEK-2), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany)

    2014-09-01

    Highlights: • The experimental KEMS data fit well with the Redlich–Kister sub-regular solution model applied to Li–Sn melt. • The Redlich–Kister binary interaction L-parameters of the Li–Sn melt were provided in this work. • The experimental KEMS data fit well with the ideally associated mixture model, too. • The quantitative associate composition of the Li–Sn melt was given. • The thermodynamic properties of the associate-forming reactions were also provided. - Abstract: The mixing thermodynamic properties of liquid Li–Sn system, determined previously by Knudsen effusion mass spectrometry (KEMS), were successfully fitted to both Redlich–Kister (RK) sub-regular mixture and ideally associated mixture (IAMT) models. The RK binary interaction L parameters, as a function of temperature in the CALPHAD-type functional form, were obtained as follows: L{sup (0)}=-(108580±0.00171)+(16.4±1.6·10{sup -5})·T+(1.96496·10{sup -9}±2.03133·10{sup -6}) ·T·ln(T) L{sup (1)}=-(96600±4700)+(3.3±43.0)·T+(4.4±5.6)·T·ln(T) L{sup (2)}=-(64670±190)-(44.4±1.7)·T+(8.44±0.22)·T·ln(T) L{sup (3)}=-(20900±1500)-(29±14)·T+(4.3±1.8)·T·ln(T) The former literature data provided only qualitative information on possible liquid associates but no quantitative associate composition was given as a function of the sample composition and temperature. The experimental KEMS data in the composition range X{sub Li} = 0 to ∼0.7 fit well with the Li(l) + Sn(l) + LiSn(l) + LiSn{sub 2}(l) + Li{sub 2}Sn(l) associate model. At X{sub Li} > 0.7 no associate variations – including further associate variants such as Li{sub 4}Sn(l) etc. – could be fitted to the KEMS data. Nevertheless, in this work the Li(l) + Sn(l) + LiSn(l) + LiSn{sub 2}(l) + Li{sub 2}Sn(l) + Li{sub 4}Sn(l) + Li{sub 9}Sn(l) associate model was successfully fitted to the thermodynamic data of a selected literature study over the complete composition range. The thermodynamic data of the associate

  6. Thermodynamics-based design of microbial cell factories for anaerobic product formation.

    Science.gov (United States)

    Cueto-Rojas, Hugo F; van Maris, A J A; Wahl, S Aljoscha; Heijnen, J J

    2015-09-01

    The field of metabolic engineering has delivered new microbial cell factories and processes for the production of different compounds including biofuels, (di)carboxylic acids, alcohols, and amino acids. Most of these processes are aerobic, with few exceptions (e.g., alcoholic fermentation), and attention is focused on assembling a high-flux product pathway with a production limit usually set by the oxygen transfer rate. By contrast, anaerobic product synthesis offers significant benefits compared to aerobic systems: higher yields, less heat generation, reduced biomass production, and lower mechanical energy input, which can significantly reduce production costs. Using simple thermodynamic calculations, we demonstrate that many products can theoretically be produced under anaerobic conditions using several conventional and non-conventional substrates.

  7. A Thermodynamical Selection-Based Discrete Differential Evolution for the 0-1 Knapsack Problem

    Directory of Open Access Journals (Sweden)

    Zhaolu Guo

    2014-11-01

    Full Text Available Many problems in business and engineering can be modeled as 0-1 knapsack problems. However, the 0-1 knapsack problem is one of the classical NP-hard problems. Therefore, it is valuable to develop effective and efficient algorithms for solving 0-1 knapsack problems. Aiming at the drawbacks of the selection operator in the traditional differential evolution (DE, we present a novel discrete differential evolution (TDDE for solving 0-1 knapsack problem. In TDDE, an enhanced selection operator inspired by the principle of the minimal free energy in thermodynamics is employed, trying to balance the conflict between the selective pressure and the diversity of population to some degree. An experimental study is conducted on twenty 0-1 knapsack test instances. The comparison results show that TDDE can gain competitive performance on the majority of the test instances.

  8. Toposelective synthesis under thermodynamic control and bioactivities of topoisomers based on diethoxycarbonyl glycoluril derivatives

    Institute of Scientific and Technical Information of China (English)

    ZHOU Baohan; YIN Guodong; WANG Zhiguo; CHEN Yunfeng; WU Anxin; WAN Jian

    2006-01-01

    Six topoisomers consisting of diethoxycarbonyl glycoluril have been successfully synthesized in one-pot by using a "figure-of-seven" building block through anti-connectivity and syn-connectivity reactions, respectively. The structures of all six topoisomers were first determined by X-ray crystallography. The finding that (±) CT isomers are the dominant products under thermodynamic control can be explained by the calculated relative energies of the six topoisomers. That the (±) CT isomers have the lowest energy is most likely due to the additional intramolecular electrostatic interactions between -NO2 and -OMe groups. The biological activities of the topoisomers were primitively investigated and the results of bioassay showed that the six topoisomers possessed obvious difference of herbicidal activity.

  9. Kinetics and Thermodynamics of Watson-Crick Base Pairing Driven DNA Origami Dimerization.

    Science.gov (United States)

    Zenk, John; Tuntivate, Chanon; Schulman, Rebecca

    2016-03-16

    We investigate the kinetics and thermodynamics of DNA origami dimerization using flat rectangle origami components and different architectures of Watson-Crick complementary single-stranded DNA ("sticky end") linking strategies. We systematically vary the number of linkers, the length of the sticky ends on the linker, and linker architecture and measure the corresponding yields as well as forward and reverse reaction rate constants through fluorescence quenching assays. Yields were further verified using atomic force microscopy. We calculate values of H° and ΔS° for various interface designs and find nonlinear van't Hoff behavior, best described by two linear equations, suggesting distinct regimes of dimerization between those with and those without well-formed interfaces. We find that self-assembly reactions can be tuned by manipulating the interface architecture without suffering a loss in yield, even when yield is high, ∼75-80%. We show that the second-order forward reaction rate constant (k(on)) depends on both linker architecture and number of linkers used, with typical values on the order of 10(5)-10(6) (M·s)(-1), values that are similar to those of bimolecular association of small, complementary DNA strands. The k(on) values are generally non-Arrhenius, tending to increase with decreasing temperature. Finally, we use kinetic and thermodynamic information about the optimal linking architecture to extend the system to an infinite, two-component repeating lattice system and show that we can form micron-sized lattices, with well-formed structures up to 8 μm(2). PMID:26925853

  10. A combined thermodynamic cycle based on methanol dissociation for IC (internal combustion) engine exhaust heat recovery

    International Nuclear Information System (INIS)

    In this paper, a novel approach for exhaust heat recovery was proposed to improve IC (internal combustion) engine fuel efficiency and also to achieve the goal for direct usage of methanol as IC engine fuel. An open organic Rankine cycle system using methanol as working medium is coupled to IC engine exhaust pipe for exhaust heat recovery. In the bottom cycle, the working medium first undergoes dissociation and expansion processes, and is then directed back to IC engine as fuel. As the external bottom cycle and the IC engine main cycle are combined together, this scheme forms a combined thermodynamic cycle. Then, this concept was applied to a turbocharged engine, and the corresponding simulation models were built for both of the external bottom cycle and the IC engine main cycle. On this basis, the energy saving potential of this combined cycle was estimated by parametric analyses. Compared to the methanol vapor engine, IC engine in-cylinder efficiency has an increase of 1.4–2.1 percentage points under full load conditions, while the external bottom cycle can increase the fuel efficiency by 3.9–5.2 percentage points at the working pressure of 30 bar. The maximum improvement to the IC engine global fuel efficiency reaches 6.8 percentage points. - Highlights: • A combined thermodynamic cycle using methanol as working medium for IC engine exhaust heat recovery is proposed. • The external bottom cycle of exhaust heat recovery and IC engine working cycle are combined together. • IC engine fuel efficiency could be improved from both in-cylinder working cycle and external bottom cycle. • The maximum improvement to the IC engine global fuel efficiency reaches 6.8 percentage points at full load

  11. Evolution of Ti-Based Nonmetallic Inclusions During Solution Treatment of Maraging 250 Steel: Thermodynamic Calculations and Experimental Verification

    Science.gov (United States)

    Shmulevitsh, Mati; Pinkas, Malki; Weizman, Amir; Frage, Nachum

    2011-06-01

    The evolution of Ti-based nonmetallic inclusions in Maraging 250 steel, namely Ti(CxN1-x) and Ti4C2S2, was investigated experimentally. Their stability in austenite also was analyzed by a thermodynamic analysis of the Fe-Ni-Ti-C-N-S system. It was established that the total concentration of the inclusions decreases from 0.024 pct to 0.008 pct after treatment at 1453 K (1180 °C) for 3 hours. The Ti4C2S2 inclusions completely dissolve in austenite at 1523 K (1250 °C) during 1 hour of treatment. The composition of the carbonitride inclusions is shifted toward higher TiN contents when they dissolve in austenite. Nitrogen-enriched titanium carbonitride inclusions are stable in austenite and their fraction may be reduced only by controlling nitrogen content in the steel. The experimental observations are in good agreement with the results of the thermodynamic analysis.

  12. Thermodynamics of sodium dodecyl sulphate-salicylic acid based micellar systems and their potential use in fruits postharvest.

    Science.gov (United States)

    Cid, A; Morales, J; Mejuto, J C; Briz-Cid, N; Rial-Otero, R; Simal-Gándara, J

    2014-05-15

    Micellar systems have excellent food applications due to their capability to solubilise a large range of hydrophilic and hydrophobic substances. In this work, the mixed micelle formation between the ionic surfactant sodium dodecyl sulphate (SDS) and the phenolic acid salicylic acid have been studied at several temperatures in aqueous solution. The critical micelle concentration and the micellization degree were determined by conductometric techniques and the experimental data used to calculate several useful thermodynamic parameters, like standard free energy, enthalpy and entropy of micelle formation. Salicylic acid helps the micellization of SDS, both by increasing the additive concentration at a constant temperature and by increasing temperature at a constant concentration of additive. The formation of micelles of SDS in the presence of salicylic acid was a thermodynamically spontaneous process, and is also entropically controlled. Salicylic acid plays the role of a stabilizer, and gives a pathway to control the three-dimensional water matrix structure. The driving force of the micellization process is provided by the hydrophobic interactions. The isostructural temperature was found to be 307.5 K for the mixed micellar system. This article explores the use of SDS-salicylic acid based micellar systems for their potential use in fruits postharvest.

  13. Nonequilibrium thermodynamics of nucleation

    NARCIS (Netherlands)

    Schweizer, M.; Sagis, L.M.C.

    2014-01-01

    We present a novel approach to nucleation processes based on the GENERIC framework (general equation for the nonequilibrium reversible-irreversible coupling). Solely based on the GENERIC structure of time-evolution equations and thermodynamic consistency arguments of exchange processes between a met

  14. Chemical Abundances and Dust in Planetary Nebulae in the Galactic Bulge

    CERN Document Server

    Gutenkunst, S; Pottasch, S R; Sloan, G C; Houck, J R

    2008-01-01

    We present mid-infrared Spitzer spectra of eleven planetary nebulae in the Galactic Bulge. We derive argon, neon, sulfur, and oxygen abundances for them using mainly infrared line fluxes combined with some optical line fluxes from the literature. Due to the high extinction toward the Bulge, the infrared spectra allow us to determine abundances for certain elements more accurately that previously possible with optical data alone. Abundances of argon and sulfur (and in most cases neon and oxygen) in planetary nebulae in the Bulge give the abundances of the interstellar medium at the time their progenitor stars formed; thus these abundances give information about the formation and evolution of the Bulge. The abundances of Bulge planetary nebulae tend to be slightly higher than those in the Disk on average, but they do not follow the trend of the Disk planetary nebulae, thus confirming the difference between Bulge and Disk evolution. Additionally, the Bulge planetary nebulae show peculiar dust properties compared...

  15. Quantum Chemical Insight into the Interactions and Thermodynamics Present in Choline Chloride Based Deep Eutectic Solvents.

    Science.gov (United States)

    Wagle, Durgesh V; Deakyne, Carol A; Baker, Gary A

    2016-07-14

    We report quantum chemical calculations performed on three popular deep eutectic solvents (DESs) in order to elucidate the molecular interactions, charge transfer interactions, and thermodynamics associated with these systems. The DESs studied comprise 1:2 choline chloride/urea (reline), 1:2 choline chloride/ethylene glycol (ethaline), and 1:1 choline chloride/malonic acid (maloline). The excellent correlation between calculated and experimental vibrational spectra allowed for identification of dominant interactions in the DES systems. The DESs were found to be stabilized by both conventional hydrogen bonds and C-H···O/C-H···π interactions between the components. The hydrogen-bonding network established in the DES is clearly distinct from that which exists within the neat hydrogen-bond donor dimer. Charge decomposition analysis indicates significant charge transfer from choline and chloride to the hydrogen-bond donor with a higher contribution from the cation, and a density of states analysis confirms the direction of the charge transfer. Consequently, the sum of the bond orders of the choline-Cl(-) interactions in the DESs correlates directly with the melting temperatures of the DESs, a correlation that offers insight into the effect of the tuning of the choline-Cl(-) interactions by the hydrogen-bond donors on the physical properties of the DESs. Finally, the differences in the vibrational entropy changes upon DES formation are consistent with the trend in the overall entropy changes upon DES formation. PMID:27268431

  16. Comparison of traditional and enthalpy-based thermodynamics solvers in the polythermal ice sheet model SICOPOLIS

    CERN Document Server

    Greve, Ralf

    2015-01-01

    In order to model the thermal structure of polythermal ice sheets accurately, energy-conserving schemes and correct tracking of the cold-temperate transition surface (CTS) are necessary. We compare four different thermodynamics solvers in the ice sheet model SICOPOLIS (the previously available polythermal two-layer and cold-ice schemes and the newly implemented conventional and melting CTS one-layer enthalpy schemes) by running two scenarios of the EISMINT Phase 2 Simplified Geometry Experiments (Payne and others, 2000, J. Glaciol. 46, 227-238) with different set-ups. In terms of temperate ice layer thickness, CTS positioning and smoothness of temperature profiles across the CTS (a requirement for the assumed case of melting conditions), the polythermal two-layer scheme performs best, and thus its results are used as a reference against which the performance of the other schemes is tested. Both the cold-ice scheme and the conventional one-layer enthalpy scheme fail to produce a continuous temperature gradient...

  17. Thermodynamic and kinetic study of volatile compounds in biopolymer based dispersions.

    Science.gov (United States)

    Samavati, Vahid; Emam-Djomeh, Zahra; Mehdinia, Ali

    2014-01-01

    Partitioning and release of ethyl acetate and diacetyl from two matrices with a different composition was studied by applying static head space gas chromatography. Two matrices with a different composition have been developed: one containing carbohydrates (Tragacanth gum) and in the second one, called complex matrix, a lipid (oleic acid) was added. The roles of carbohydrate (Tragacanth gum) and lipid (oleic acid) on the retention of all the aroma compounds were pointed out. Changes in the composition of matrices exhibited a considerable effect on the thermodynamic component as expressed by the air/liquid partition coefficient (Ka/l) values at equilibrium (20 °C). The kinetic study of the release from these matrices had shown a decrease of the initial rate of release (Ri) by reference with water. The rheological properties of all matrices were investigated and the flow behaviour of all matrices was successfully modelled with power law and Ellis models and power law model was found as the better model to describe the flow behaviour of dispersions. PMID:24274543

  18. Solubilities and thermodynamic properties of CO2 in choline-chloride based deep eutectic solvents

    International Nuclear Information System (INIS)

    Highlights: • Solubilities of carbon dioxide in three deep eutectic solvents (DESs) have been reported. • The experimental data were reduced to Henry’s law constants. • The Gibbs free energy, enthalpy, and entropy changes were calculated. • Relationship between solubility and structure of DESs was developed. - Abstract: The solubilities of CO2 in three kinds of deep eutectic solvents, (choline chloride + phenol), (choline chloride + diethylene glycol) and (choline chloride + triethylene glycol), were determined at temperatures ranging from 293.15 K to 323.15 K under pressures up to 600.0 kPa using isochoric saturation method. The mole ratios of choline chloride to phenol were selected as 1:2, 1:3 and 1:4, the others as 1:3 and 1:4. Henry’s constants and thermodynamic properties such as standard Gibbs free energy, enthalpy, and entropy changes of CO2 solvation were calculated from the correlation of solubility data. Results revealed that the solubility of CO2 increased with increasing pressure and decreased with increasing temperature. The enthalpies of solution were negative at all conditions

  19. Determination of thermodynamic properties of aluminum based binary and ternary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Altıntas, Yemliha [Abdullah Gül University, Faculty of Engineering, Department of Materials Science and Nanotechnology, 38039, Kayseri (Turkey); Aksöz, Sezen [Nevşehir Hacı Bektaş Veli University, Faculty of Arts and Science, Department of Physics, 50300, Nevşehir (Turkey); Keşlioğlu, Kâzım, E-mail: kesli@erciyes.edu.tr [Erciyes University, Faculty of Science, Department of Physics, 38039, Kayseri (Turkey); Maraşlı, Necmettin [Yıldız Technical University, Faculty of Chemical and Metallurgical Engineering, Department of Metallurgical and Materials Engineering, 34210, Davutpaşa, İstanbul (Turkey)

    2015-11-15

    In the present work, the Gibbs–Thomson coefficient, solid–liquid and solid–solid interfacial energies and grain boundary energy of a solid Al solution in the Al–Cu–Si eutectic system were determined from the observed grain boundary groove shapes by measuring the thermal conductivity of the solid and liquid phases and temperature gradient. Some thermodynamic properties such as the enthalpy of fusion, entropy of fusion, the change of specific heat from liquid to solid and the electrical conductivity of solid phases at their melting temperature were also evaluated by using the measured values of relevant data for Al–Cu, Al–Si, Al–Mg, Al–Ni, Al–Ti, Al–Cu–Ag, Al–Cu–Si binary and ternary alloys. - Highlights: • The microstructure of the Al–Cu–Si eutectic alloy was observed through SEM. • The three eutectic phases (α-Al, Si, CuAl{sub 2}) have been determined by EDX analysis. • Solid–liquid and solid–solid interfacial energies of α-Al solution were determined. • ΔS{sub f},ΔH{sub M}, ΔC{sub P}, electrical conductivity of solid phases for solid Al solutions were determined. • G–T coefficient and grain boundary energy of solid Al solution were determined.

  20. Thermodynamic Model of a Very High Efficiency Power Plant based on a Biomass Gasifier, SOFCs, and a Gas Turbine

    Directory of Open Access Journals (Sweden)

    P V Aravind

    2012-07-01

    Full Text Available Thermodynamic calculations with a power plant based on a biomass gasifier, SOFCs and a gas turbine are presented. The SOFC anode off-gas which mainly consists of steam and carbon dioxides used as a gasifying agent leading to an allothermal gasification process for which heat is required. Implementation of heat pipes between the SOFC and the gasifier using two SOFC stacks and intercooling the fuel and the cathode streams in between them has shown to be a solution on one hand to drive the allothermal gasification process and on the other hand to cool down the SOFC. It is seen that this helps to reduce the exergy losses in the system significantly. With such a system, electrical efficiency around 73% is shown as achievable.

  1. Effects of surface charge on interfacial interactions related to membrane fouling in a submerged membrane bioreactor based on thermodynamic analysis.

    Science.gov (United States)

    Cai, Huihui; Fan, Hao; Zhao, Leihong; Hong, Huachang; Shen, Liguo; He, Yiming; Lin, Hongjun; Chen, Jianrong

    2016-03-01

    Effects of both membrane and sludge foulant surface zeta potentials on interfacial interactions between membrane and sludge foulant in different interaction scenarios were systematically investigated based on thermodynamic methods. Under conditions in this study, it was found that zeta potential had marginal effects on total interfacial interaction between two infinite planar surfaces, and the total interfacial interaction between foulant particles and membrane would be more repulsive with increase of absolute value of zeta potential. Adhesion of foulant particles on membrane surface should overcome an energy barrier. There exists a critical zeta potential below which energy barrier would disappear. Results also showed that rough surface membrane corresponded to significantly low strength of interfacial interactions. This study not only provided a series of methods to quantitatively assess the interfacial interactions between membrane and sludge foulants, but also reconciled the contradictory conclusions regarding effects of zeta potential in literature, giving important implications for membrane fouling mitigation.

  2. Effect of tube size on electromagnetic tube bulging

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The commercial finite code ANSYS was employed for the simulation of the electromagnetic tube bulging process. The finite element model and boundary conditions were thoroughly discussed. ANSYS/EMAG was used to model the time varying electromagnetic field in order to obtain the radial and axial magnetic pressure acting on the tube. The magnetic pressure was then used as boundary conditions to model the high velocity deformation of various length tube with ANSYS/LSDYNA. The time space distribution of magnetic pressure on various length tubes was presented. Effect of tube size on the distribution of radial magnetic pressure and axial magnetic pressure and high velocity deformation were discussed. According to the radial magnetic pressure ratio of tube end to tube center and corresponding dimensionless length ratio of tube to coil, the free electromagnetic tube bulging was studied in classification. The calculated results show good agreements with practice.

  3. The effect of massive disks on bulge isophotes

    Science.gov (United States)

    Monet, D. G.; Schechter, P. L.; Richstone, D. O.

    1981-04-01

    Massive disks produce flattened equipotentials. Unless the stars in a galaxy bulge are preferentially hotter in the z direction than in the plane, the isophotes will be at least as flat as the equipotentials. The comparison of two galaxy models having flat rotation curves with the available surface photometry for five external galaxies does not restrict the mass fraction which might reside in the disk. However, star counts in our own Galaxy indicate that unless the disk terminates close to the solar circle, no more than half the mass within that circle lies in the disk. The remaining half must lie either in the bulge or, more probably, in a third dark, round, dynamically distinct component.

  4. Bulging of cans containing plutonium residues. Summary report

    International Nuclear Information System (INIS)

    In 1994, two cans in the Lawrence Livermore National Laboratory Plutonium Facility were found to be bulging as a result of the generation of gases form the plutonium ash residues contained in the cans. This report describes the chronology of this discovery, the response actions that revealed other pressurized cans, the analysis of the causes, the short-term remedial action, a followup inspection of the short-term storage packages, and a review of proposed long-term remedial options

  5. Bulging of cans containing plutonium residues. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    Van Konynenburg, R.A.; Wood, D.H.; Condit, R.H.; Shikany, S.D.

    1996-03-01

    In 1994, two cans in the Lawrence Livermore National Laboratory Plutonium Facility were found to be bulging as a result of the generation of gases form the plutonium ash residues contained in the cans. This report describes the chronology of this discovery, the response actions that revealed other pressurized cans, the analysis of the causes, the short-term remedial action, a followup inspection of the short-term storage packages, and a review of proposed long-term remedial options.

  6. Research on bulging plate of scaler for horizontal pendulum tiltmeter

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhi-zhong; ZHU Hu; WU Jian

    2005-01-01

    @@ After the horizontal pendulum is used in ground-tilt measurement, its scaling has drawn great attentions from the people, because without a correct calibration of scale value, the observation is of little application significance. From the 1920's, quite a few scholars were engaged in the researches in this respect. And this question was satisfactorily solved until 1962 when Verbaandert (1962) invented the bulging plate, i.e., mercury-cup scaler.After further improvement, the V-M quartz horizontal pendulum tiltmeter was used globally in observation and great success was achieved (Melchior, 1966, 1978). In China, the quartz horizontal pendulum tiltmeter as well as the bulging-plate scaler were developed at the beginning of 1970's and then put into use after some improvements (ZHU and FENG, 1980). The successful observation by SQ quartz horizontal pendulum tiltmeter should be related not only to the excellent performance of horizontal pendulum, but also to its accurate calibration. The bulging plate plays an important role in calibration, because it is the critical component of scaler.

  7. Study of extremely reddened AGB stars in the Galactic bulge

    CERN Document Server

    Jiménez-Esteban, F M

    2015-01-01

    Context. Extremely reddened AGB stars lose mass at high rates of >10^-5 Msun/yr. This is the very last stage of AGB evolution, in which stars in the mass range 2.0--4.0 Msun (for solar metallicity) should have been converted to C stars already. The extremely reddened AGB stars in the Galactic bulge are however predominantly O-rich, implying that they might be either low-mass stars or stars at the upper end of the AGB mass range. Aims. To determine the mass range of the most reddened AGB stars in the Galactic bulge. Methods. Using Virtual Observatory tools, we constructed spectral energy distributions of a sample of 37 evolved stars in the Galactic bulge with extremely red IRAS colours. We fitted DUSTY models to the observational data to infer the bolometric fluxes. Applying individual corrections for interstellar extinction and adopting a common distance, we determined luminosities and mass-loss rates, and inferred the progenitor mass range from comparisons with AGB evolutionary models. Results. The observed ...

  8. ISO Mid-Infrared spectroscopy of Galactic Bulge AGB stars

    CERN Document Server

    Blommaert, J A D L; Okumura, K; Ganesh, S; Omont, A; Cami, J; Glass, I S; Habing, H J; Schultheis, M; Simon, G; Van Loon, J T; Blommaert, Joris A.D.L.; Groenewegen, Martin A.T.; Okumura, Koryo; Ganesh, Shashikiran; Omont, Alain; Cami, Jan; Glass, Ian S.; Habing, Harm J.; Schultheis, Mathias; Simon, Guy; Loon, Jacco Th. van

    2006-01-01

    To study the nature of Bulge AGB stars and in particular their circumstellar dust, we have analysed mid-infrared spectra obtained with the ISOCAM CVF spectrometer in three Bulge fields. The ISOCAM 5-16.5 micron CVF spectra were obtained as part of the ISOGAL infrared survey of the inner Galaxy. A classification of the shape of the 10 micron dust feature was made for each case. The spectra of the individual sources were modelled using a radiative transfer model. Different combinations of amorphous silicates and aluminium-oxide dust were used in the modelling. Spectra were obtained for 29 sources of which 26 are likely to be Bulge AGB stars. Our modelling shows that the stars suffer mass loss rates in the range of 10^{-8} - 5 x 10^{-7} Msun / yr, which is at the low end of the mass-loss rates experienced on the Thermally Pulsing AGB. The luminosities range from 1,700 to 7,700 Lsun as expected for a population of AGB stars with Minit of 1.5 - 2Msun. In agreement with the condensation sequence scenario, we find t...

  9. GAMA: Stellar Mass Assembly in Galaxy Bulges and Disks

    Science.gov (United States)

    Moffett, Amanda J.; Driver, Simon P.; Lange, Rebecca; Robotham, Aaron; Kelvin, Lee; GAMA Team

    2016-01-01

    The Galaxy And Mass Assembly (GAMA) survey has to date obtained spectra, redshifts, and 21-band multi-facility photometry for over 200,000 galaxies in five survey regions that total nearly 300 square degrees on sky. We consider here a low-redshift (zteam. In order to quantify the separate bulge and disk properties of these galaxies, we apply a large-scale automated procedure for fitting images with 2D, multi-component structure models, including evaluation of fit convergence using a grid of input parameter values for each galaxy. From this analysis, we calculate the total bulge and disk contributions to the local galaxy stellar mass budget and derive mass-size relations for both pure spheroid/disk systems and the separate bulge/disk components of multi-component galaxies. We further examine the fraction of total stellar mass assembled in spheroid and disk structures as a function of galaxy environment, where environment is quantified on multiple scales from membership in large-scale filaments to groups/clusters and down to local pairings. We then discuss the effect of environmental conditions on the mechanisms of stellar mass assembly, including the implied balance between merger accumulation and in situ mass growth in different environment regimes.

  10. The Structure of the Milky Way's Bar Outside the Bulge

    CERN Document Server

    Wegg, Christopher; Portail, Matthieu

    2015-01-01

    While it is incontrovertible that the inner Galaxy contains a bar, its structure near the Galactic plane has remained uncertain, where extinction from intervening dust is greatest. We investigate here the Galactic bar outside the bulge, the long bar, using red clump giant (RCG) stars from UKIDSS, 2MASS, VVV, and GLIMPSE. We match and combine these surveys to investigate a wide area in latitude and longitude, |b|<9deg and |l|<40deg. We find: (1) The bar extends to l~25deg at |b|~5deg from the Galactic plane, and to l~30deg at lower latitudes. (2) The long bar has an angle to the line-of-sight in the range (28-33)deg, consistent with studies of the bulge at |l|<10deg. (3) The scale-height of RCG stars smoothly transitions from the bulge to the thinner long bar. (4) There is evidence for two scale heights in the long bar. We find a ~180pc thin bar component reminiscent of the old thin disk near the sun, and a ~45pc super-thin bar component which exists predominantly towards the bar end. (5) Constructing...

  11. Discrete Thermodynamics of Lasers

    CERN Document Server

    Zilbergleyt, B

    2007-01-01

    The paper offers a discrete thermodynamic model of lasers. Laser is an open system; its equilibrium is based on a balance of two thermodynamic forces, one related to the incoming pumping power and another to the emitted light. The basic expression for such equilibrium is a logistic map, graphical solutions to which are pitchfork bifurcation diagrams. As pumping force increases, the relative populations on the ground and lasing branches tend to zero and unity correspondingly. An interesting feature of this model is the line spectrum of the up and down transitions between the branches beyond bifurcation point. Even in a simple case of 2-level laser with only 2 possible transition types (up and down), the spectra look like sets of the line packets, starting well before the population inversion. This effect is an independent confirmation of the Einstein's prohibition on practical realization of 2-level laser. Multilevel lasers may be approached by employing the idea of thermodynamic activity for the emitting atom...

  12. Application of the ruthenium and technetium thermodynamic data bases used in the EQ3/6 geochemical codes

    Energy Technology Data Exchange (ETDEWEB)

    Isherwood, D.

    1985-04-01

    Based on a critical review of the available thermodynamic data, computerized data bases for technetium and ruthenium were created for use with the EQ3/6 geochemical computer codes. The technetium data base contains thermodynamic data for 8 aqueous species and 15 solids; 26 aqueous species and 9 solids were included in the ruthenium data base. The EQ3NR code was used to calculate solubility limits for ruthenium (8 x 10{sup -16} M) in ground water from Yucca Mountain, a potential nuclear waste repository site near the Nevada Test Site (NTS). The code confirmed the essentially unlimited solubility of technetium in oxidizing conditions, such as those that are believed to exist in the unsaturated zone at Yucca Mountain and the Cambric Nuclear event site at the NTS. Ruthenium migration observed from the Cambric site was evaluated. The solubility limit for ruthenium (as the aqueous species RuO{sub 4}{sup -}) when constrained by RuO{sub 2} is approximately equal to the concentration of ruthenium found in the cavity ground water (i.e., 2.1 x 10{sup -11} vs 4.5 x 10{sup -11} M). Differences in ruthenium solubility limits between Yucca Mountain and Cambric are primarily due to differences in ground-water pH. Technetium solubility (3 x 10{sup -8} M) for moderately reducing conditions (Eh = -0.1 V) using the metastable oxide, TcO{sub 2}.2H{sub 2}O, as the solubility constraint is within the range of experimental values recently published in a study of technetium sorption on basalt. Previously published technetium solubilities of 10{sup -12} to 10{sup -16} M were apparently based on a technetium data base that did not include aqueous species other than TcO{sub 4}{sup -}. When TcO(OH){sub 2}{sup 0} is included in the data base, the calculated values are much closer to the experimental results. Eh-pH diagrams were also generated for a variety of conditions using the SOLUPLOT code.

  13. Application of the ruthenium and technetium thermodynamic data bases used in the EQ3/6 geochemical codes

    International Nuclear Information System (INIS)

    Based on a critical review of the available thermodynamic data, computerized data bases for technetium and ruthenium were created for use with the EQ3/6 geochemical computer codes. The technetium data base contains thermodynamic data for 8 aqueous species and 15 solids; 26 aqueous species and 9 solids were included in the ruthenium data base. The EQ3NR code was used to calculate solubility limits for ruthenium (8 x 10-16 M) in ground water from Yucca Mountain, a potential nuclear waste repository site near the Nevada Test Site (NTS). The code confirmed the essentially unlimited solubility of technetium in oxidizing conditions, such as those that are believed to exist in the unsaturated zone at Yucca Mountain and the Cambric Nuclear event site at the NTS. Ruthenium migration observed from the Cambric site was evaluated. The solubility limit for ruthenium (as the aqueous species RuO4-) when constrained by RuO2 is approximately equal to the concentration of ruthenium found in the cavity ground water (i.e., 2.1 x 10-11 vs 4.5 x 10-11 M). Differences in ruthenium solubility limits between Yucca Mountain and Cambric are primarily due to differences in ground-water pH. Technetium solubility (3 x 10-8 M) for moderately reducing conditions (Eh = -0.1 V) using the metastable oxide, TcO2.2H2O, as the solubility constraint is within the range of experimental values recently published in a study of technetium sorption on basalt. Previously published technetium solubilities of 10-12 to 10-16 M were apparently based on a technetium data base that did not include aqueous species other than TcO4-. When TcO(OH)20 is included in the data base, the calculated values are much closer to the experimental results. Eh-pH diagrams were also generated for a variety of conditions using the SOLUPLOT code

  14. Characterization of Friction Stir Welded Tubes by Means of Tube Bulge Test

    International Nuclear Information System (INIS)

    Mechanical properties of friction stir welded joints are generally evaluated by means of conventional tensile test. This testing method might provide insufficient information because maximum strain obtained in tensile test before necking is small; moreover, the application of tensile test is limited when the joint path is not linear or even when the welds are executed on curved surfaces. Therefore, in some cases, it would be preferable to obtain the joints properties from other testing methods. Tube bulge test can be a valid solution for testing circumferential or longitudinal welds executed on tubular workpieces. The present work investigates the mechanical properties and the formability of friction stir welded tubes by means of tube bulge tests. The experimental campaign was performed on tubular specimens having a thickness of 3 mm and an external diameter of 40 mm, obtained starting from two semi-tubes longitudinally friction stir welded. The first step, regarding the fabrication of tubes, was performed combining a conventional forming process and friction stir welding. Sheets in Al-Mg-Si-Cu alloy AA6060 T6 were adopted for this purpose. Plates having a dimension of 225x60 mm were bent (with a bending axis parallel to the main dimension) in order to obtain semi-tubes. A particular care was devoted to the fabrication of forming devices (punch and die) in order to minimize the springback effects. Semi-tubes were then friction stir welded by means of a CNC machine tool. Some preliminary tests were carried out by varying the welding parameters, namely feed rate and rotational speed. A very simple tool having flat shoulder and cylindrical pin was used. The second step of the research was based on testing the welded tubes by means of tube bulge test. A specific equipment having axial actuators with a conical shape was adopted for this study. Some analyses were carried out on the tubes bulged up to a certain pressure level. In particular, the burst pressure and the

  15. Characterization of Friction Stir Welded Tubes by Means of Tube Bulge Test

    Science.gov (United States)

    D'Urso, G.; Longo, M.; Giardini, C.

    2011-05-01

    Mechanical properties of friction stir welded joints are generally evaluated by means of conventional tensile test. This testing method might provide insufficient information because maximum strain obtained in tensile test before necking is small; moreover, the application of tensile test is limited when the joint path is not linear or even when the welds are executed on curved surfaces. Therefore, in some cases, it would be preferable to obtain the joints properties from other testing methods. Tube bulge test can be a valid solution for testing circumferential or longitudinal welds executed on tubular workpieces. The present work investigates the mechanical properties and the formability of friction stir welded tubes by means of tube bulge tests. The experimental campaign was performed on tubular specimens having a thickness of 3 mm and an external diameter of 40 mm, obtained starting from two semi-tubes longitudinally friction stir welded. The first step, regarding the fabrication of tubes, was performed combining a conventional forming process and friction stir welding. Sheets in Al-Mg-Si-Cu alloy AA6060 T6 were adopted for this purpose. Plates having a dimension of 225×60 mm were bent (with a bending axis parallel to the main dimension) in order to obtain semi-tubes. A particular care was devoted to the fabrication of forming devices (punch and die) in order to minimize the springback effects. Semi-tubes were then friction stir welded by means of a CNC machine tool. Some preliminary tests were carried out by varying the welding parameters, namely feed rate and rotational speed. A very simple tool having flat shoulder and cylindrical pin was used. The second step of the research was based on testing the welded tubes by means of tube bulge test. A specific equipment having axial actuators with a conical shape was adopted for this study. Some analyses were carried out on the tubes bulged up to a certain pressure level. In particular, the burst pressure and the

  16. Thermodynamic analysis of an integrated energy system based on compressed air energy storage (CAES) system and Kalina cycle

    International Nuclear Information System (INIS)

    Highlights: • An integrated energy system based on CAES and Kalina cycle is proposed. • The design and modeling of the CAES–KCS6 system are laid out. • The energy analysis and exergy analysis of the proposed system are carried out. • A parametric analysis is conducted to examine their effect on system performance. - Abstract: High penetration of renewable power sources into power system leads to significant challenge in balancing of power generation and consumption due to the highly erratic nature of renewable energies. Integrating the energy storage system (ESS) with power system can weaken these negative effects effectively. Compressed air energy storage (CAES) system as one of the grid-scale ESS technologies has grown rapidly in the past few years. However, the temperature of exhaust from low pressure turbine during discharge process is still high enough to utilize. An integrated energy system consisting of a CAES system and a Kalina cycle system 6 (KCS6) is proposed to recover this waste heat. The thermodynamic analyses including energy analysis and exergy analysis are evaluated by using steady-state mathematical model and thermodynamic laws. The second law efficiency of the proposed CAES–KCS6 system can be improved nearly 4% compared to that of the single conventional CAES system. Meanwhile, the parametric analysis is also carried out to evaluate the effects of some key parameters on system performance, such as the turbine inlet temperature (TIT), inlet pressure of low pressure turbine and the air storage cavern temperature. Results show that all of these parameters have positive effect on system exergy efficiency

  17. Embodiment Analysis for Greenhouse Gas Emissions by Chinese Economy Based on Global Thermodynamic Potentials

    Directory of Open Access Journals (Sweden)

    Lijie Wang

    2011-11-01

    Full Text Available This paper considers the Global Thermodynamic Potential (GTP indicator to perform a unified assessment of greenhouse gas (GHG emissions, and to systematically reveal the emission embodiment in the production, consumption, and international trade of the Chinese economy in 2007 as the most recent year available with input-output table and updated inventory data. The results show that the estimated total direct GHG emissions by the Chinese economy in 2007 amount to 10,657.5 Mt CO2-eq by the GTPs with 40.6% from CH4 emissions in magnitude of the same importance as CO2 emissions. The five sectors of Electric Power/Steam and Hot Water Production and Supply, Smelting and Pressing of Ferrous and Nonferrous Metals, Nonmetal Mineral Products, Agriculture, and Coal Mining and Dressing, are responsible for 83.3% of the total GHG emissions with different emission structures. The demands of coal and coal-electricity determine the structure of emission embodiment to an essential extent. The Construction sector holds the top GHG emissions embodied in both domestic production and domestic consumption. The GHG emission embodied in gross capital formation is more than those in other components of final demand characterized by extensive investment and limited household consumption. China is a net exporter of embodied GHG emissions, with a remarkable share of direct emission induced by international trade, such as textile products, industrial raw materials, and primary machinery and equipment products exports. The fractions of CH4 in the component of embodied GHG emissions in the final demand are much greater than those fractions calculated by the Global Warming Potentials, which highlight the importance of CH4 emissions for the case of China and indicate the essential effect of CH4 emissions on global climate change. To understand the full context to achieve GHG emission mitigation, this study provides a new insight to address China’s GHG emissions status and

  18. Fundamental Research in Engineering Education. Development of Concept Questions and Inquiry-Based Activities in Thermodynamics and Heat Transfer: An Example for Equilibrium vs. Steady-State

    Science.gov (United States)

    Vigeant, Margot; Prince, Michael; Nottis, Katharyn

    2011-01-01

    This study examines the use of inquiry-based instruction to promote the understanding of critical concepts in thermodynamics and heat transfer. Significant research shows that students frequently enter our courses with tightly held misconceptions about the physical world that are not effectively addressed through traditional instruction. Students'…

  19. CHARACTERIZATION OF A SAMPLE OF INTERMEDIATE-TYPE ACTIVE GALACTIC NUCLEI. II. HOST BULGE PROPERTIES AND BLACK HOLE MASS ESTIMATES

    Energy Technology Data Exchange (ETDEWEB)

    Benitez, Erika; Cruz-Gonzalez, Irene; Martinez, Benoni; Jimenez-Bailon, Elena [Instituto de Astronomia, Universidad Nacional Autonoma de Mexico, Apdo. Postal 70-264, Mexico D.F. 04510 (Mexico); Mendez-Abreu, Jairo; Lopez-Martin, Luis [Instituto de Astrofisica de Canarias, E-38200 La Laguna, Tenerife (Spain); Fuentes-Carrera, Isaura [Escuela Superior de Fisica y Matematicas, Instituto Politecnico Nacional (ESFM-IPN), U.P. Adolfo Lopez Mateos, Mexico D.F. 07730 (Mexico); Chavushyan, Vahram [Instituto Nacional de Astrofisica, Optica y Electronica, Apdo. Postal 51-216, 72000 Puebla (Mexico); Leon-Tavares, Jonathan, E-mail: erika@astro.unam.mx [Aalto University Metsaehovi Radio Observatory, Metsaehovintie 114, 02540 Kylmaelae (Finland)

    2013-02-15

    We present a study of the host bulge properties and their relations with the black hole mass for a sample of 10 intermediate-type active galactic nuclei (AGNs). Our sample consists mainly of early-type spirals, four of them hosting a bar. For 70{sup +10} {sub -17}% of the galaxies, we have been able to determine the type of the bulge, and find that these objects probably harbor a pseudobulge or a combination of classical bulge/pseudobulge, suggesting that pseudobulges might be frequent in intermediate-type AGNs. In our sample, 50% {+-} 14% of the objects show double-peaked emission lines. Therefore, narrow double-peaked emission lines seem to be frequent in galaxies harboring a pseudobulge or a combination of classical bulge/pseudobulge. Depending on the bulge type, we estimated the black hole mass using the corresponding M {sub BH}-{sigma}* relation and found them within a range of 5.69 {+-} 0.21 < log M {sup {sigma}}*{sub BH} < 8.09 {+-} 0.24. Comparing these M {sup {sigma}}*{sub BH} values with masses derived from the FWHM of H{beta} and the continuum luminosity at 5100 A from their SDSS-DR7 spectra (M {sub BH}), we find that 8 out of 10 (80{sup +7} {sub -17}%) galaxies have black hole masses that are compatible within a factor of 3. This result would support that M {sub BH} and M {sup {sigma}}*{sub BH} are the same for intermediate-type AGNs, as has been found for type 1 AGNs. However, when the type of the bulge is taken into account, only three out of the seven (43{sup +18} {sub -15}%) objects of the sample have their M {sup {sigma}}*{sub BH} and M {sub BH} compatible within 3{sigma} errors. We also find that estimations based on the M {sub BH}-{sigma}* relation for pseudobulges are not compatible in 50% {+-} 20% of the objects.

  20. Ecosystem thermodynamics

    International Nuclear Information System (INIS)

    Ecology is no more a descriptive and self-sufficient science. Many viewpoints are needed simultaneously to give a full coverage of such complex systems: ecosystems. These viewpoints come from physics, chemistry, and nuclear physics, without a new far from equilibrium thermodynamics and without new mathematical tools such as catastrophe theory, fractal theory, cybernetics and network theory, the development of ecosystem science would never have reached the point of today. Some ideas are presented about the importance that concept such as energy, entropy, exergy information and none equilibrium have in the analysis of processes taking place in ecosystems

  1. An Observational Guide to Identifying Pseudobulges and Classical Bulges in Disk Galaxies

    CERN Document Server

    Fisher, David B

    2015-01-01

    In this review our aim is to summarize the observed properties of pseudobulges and classical bulges. We utilize an empirical approach to studying the properties of bulges in disk galaxies, and restrict our analysis to statistical proper- ties. A clear bimodality is observed in a number of properties including morphology, structural properties, star formation, gas content & stellar population, and kinematics. As well as summarizing known methods to identify pseudobulges and classical bulges we also show new results, including absorption line indices that can be used to identify different bulge types. We conclude by summarizing those properties that isolate pseudobulges from classical bulges. Our intention is to describe a practical, easy to use, list of criteria for identifying bulge types.

  2. Keratin 15 promoter targets putative epithelial stem cells in the hair follicle bulge.

    Science.gov (United States)

    Liu, Yaping; Lyle, Stephen; Yang, Zaixin; Cotsarelis, George

    2003-11-01

    Putative epithelial stem cells in the hair follicle bulge are thought to play pivotal roles in the homeostasis, aging, and carcinogenesis of the cutaneous epithelium. Elucidating the role of bulge cells in these processes has been hampered by the lack of gene promoters that target this area with specificity. Here we describe the isolation of the mouse keratin 15 (K15) promoter and demonstrate its utility for preferentially targeting hair follicle bulge cells in adult K15/lacZ transgenic mice. We found that patterns of K15 expression and promoter activity changed with age and correlated with levels of differentiation within the cutaneous epithelium; less differentiated keratinocytes in the epidermis of the neonatal mouse and in the bulge area of the adult mouse preferentially expressed K15. These findings demonstrate the utility of the K15 promoter for targeting epithelial stem cells in the hair follicle bulge and set the stage for elucidating the role of bulge cells in skin biology.

  3. Effect of temperature on vacuum hot bulge forming of BT20 titanium alloy cylindrical workpiece

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Temperature is one of the key parameters for BT20 titanium alloy cylindrical workpiece manufactured by vacuum hot bulge forming. A two-dimensional nonlinear thermo-mechanical coupled FE model was established. Numerical simulation of vacuum hot bulge forming process of titanium alloy cylindrical workpiece was carried out using FE analysis software MSC Marc. The effects of temperature on vacuum hot bulge forming of BT20 titanium alloy cylindrical workpiece were analyzed by numerical simulation.The simulated results show that the Y-direction displacement and the equivalent plastic strain of the workpiece increase with increasing bulge temperature. The residual stress decreases with increasing bulge temperature. The optimal temperature range of BT20 titanium alloy during vacuum hot bulge forming is 750-850 ℃. The corresponding experiments were carried out. The simulated results agreed well with the experimental results.

  4. A Radiation-Hydrodynamical Model for Supermassive Black Hole-to-Bulge Mass Relation and Quasar Formation

    CERN Document Server

    Umemura, M

    2001-01-01

    As a potential mechanism to build up supermassive black holes (BHs) in a spheroidal system, we consider the radiation drag effect by bulge stars, which extracts angular momentum from interstellar gas and thus allows the gas to accrete onto the galactic center. With incorporating radiation hydrodynamical equation with simple stellar evolution, it is shown that the BH-to-bulge mass ratio, $f_{BH}$, is basically determined by a fundamental constant, that is, the energy conversion efficiency for nuclear fusion of hydrogen to helium, $\\epsilon=0.007$. More specifically, $f_{BH}$ is predicted to be $0.3\\epsilon -0.5\\epsilon$. Based on the present model for BH growth, a scenario for quasar formation is addressed in relation to ultraluminous infrared galaxies.

  5. A Hamiltonian approach to Thermodynamics

    CERN Document Server

    Baldiotti, M C; Molina, C

    2016-01-01

    In the present work we develop a strictly Hamiltonian approach to Thermodynamics. A thermodynamic description based on symplectic geometry is introduced, where all thermodynamic processes can be described within the framework of Analytic Mechanics. Our proposal is constructed ontop of a usual symplectic manifold, where phase space is even dimensional and one has well-defined Poisson brackets. The main idea is the introduction of an extended phase space where thermodynamic equations of state are realized as constraints. We are then able to apply the canonical transformation toolkit to thermodynamic problems. Throughout this development, Dirac's theory of constrained systems is extensively used. To illustrate the formalism, we consider paradigmatic examples, namely, the ideal, van der Waals and Clausius gases.

  6. An X-ray Spectroscopic Study of the Hot Interstellar Medium Toward the Galactic Bulge

    CERN Document Server

    Hagihara, Toshishige; Mitsuda, Kazuhisa; Takei, Yoh; Sakai, Kazuhiro; Yao, Yangsen; Wang, Q Daniel; McCammon, Dan

    2011-01-01

    We present a detailed spectroscopic study of the hot gas toward the Galactic bulge along the 4U 1820-303 sight line by a combination analysis of emission and absorption spectra. In addition to the absorption lines of OVII Kalpha, OVII Kbeta, OVIII Kalpha and NeIX Kalpha by Chandra LTGS as shown by previous works, Suzaku detected clearly the emission lines of OVII, OVIII, NeIX and NeX from the vicinity. We used simplified plasma models with constant temperature and density. Evaluation of the background and foreground emission was performed carefully, including stellar X-ray contribution based on the recent X-ray observational results and stellar distribution simulator. If we assume that one plasma component exists in front of 4U1820-303 and the other one at the back, the obtained temperatures are T= 1.7 +/- 0.2 MK for the front-side plasma and T=3.9(+0.4-0.3) MK for the backside. This scheme is consistent with a hot and thick ISM disk as suggested by the extragalactic source observations and an X-ray bulge aro...

  7. Discovery of RR Lyrae Stars in the Nuclear Bulge of the Milky Way

    CERN Document Server

    Minniti, D; Zoccali, M; Rejkuba, M; Gonzalez, O A; Valenti, E; Gran, F

    2016-01-01

    Galactic nuclei, like the one of the Milky Way, are extreme places with high stellar densities and, in most cases, hosting a supermassive black hole. One of the scenarios proposed for the formation of the Galactic nucleus is by merging of primordial globular clusters (Capuzzo-Dolcetta 1993). An implication of this model is that this region should host stars characteristically found in old Milky Way globular clusters. RR Lyrae stars are primary distance indicators, well known representatives of old and metal-poor stellar populations, and therefore regularly found in globular clusters. Here we report the discovery of a dozen RR Lyrae ab-type stars in the vicinity of the Galactic center, i.e. in the so-called nuclear stellar bulge of the Milky Way. This discovery provides the first direct observational evidence that the Galactic nuclear stellar bulge contains ancient stars (>10 Gyr old). Based on this we conclude that merging globular clusters likely contributed to building-up the high stellar density in the nuc...

  8. Bulge-disc decompositions and structural bimodality of Ursa Major cluster spiral galaxies

    Science.gov (United States)

    McDonald, Michael; Courteau, Stéphane; Tully, R. Brent

    2009-02-01

    We present bulge and disc (B/D) decompositions of existing K' surface brightness profiles for 65 Ursa Major (UMa) cluster spiral galaxies. This improves upon the disc-only fits of Tully et al. The 1996 disc fits were used by Tully & Verheijen for their discovery of the bimodality of structural parameters in the UMa cluster galaxies. It is shown that our new one-dimensional B/D decompositions yield disc structural parameters that differ only slightly from the basic fits of Tully et al. and evidence for structural bimodality of UMa galaxies is maintained. Our B/D software for the decomposition of one-dimensional surface brightness profiles of galaxies uses a non-linear minimization scheme to recover the best-fitting Sérsic bulge and the exponential disc while accounting for the possible presence of a compact nucleus and spiral arms and for the effects of seeing and disc truncations. In agreement with Tully & Verheijen, we find that the distribution of near-infrared disc central surface brightnesses is bimodal with an F-test confidence of 80 per cent. There is also strong evidence for a local minimum in the luminosity function at . A connection between the brightness bimodality and a dynamical bimodality, based on new HI linewidths, is identified. The B/D parameters are presented in Table 1.

  9. Variations of the selective extinction across the galactic bulge implications for the galactic bar

    CERN Document Server

    Wozniak, P R

    1995-01-01

    We propose a new method to investigate the coefficient of the selective extinction, based on two band photometry. This method uses red clump stars as a means to construct the reddening curve. We apply this method to the OGLE color-magnitude diagrams to investigate the variations of the selective extinction towards various parts of the Galactic bulge. We find that A_{_V}/E_{_{V-I}} coefficient is within the errors the same for l=\\pm 5\\deg OGLE fields. Therefore, the difference of \\sim 0.37\\;mag in the extinction adjusted apparent magnitude of the red clump stars in these fields (Stanek et al.~1994, 1995) cannot be assigned to a large-scale gradient of the selective extinction coefficient. This strengthens the implication of this difference as indicator of the presence of the bar in our Galaxy. However using present data we cannot entirely exclude the possibility of \\sim 0.2\\;mag/mag variations of the selective extinction coefficient on the large scales across the bulge.

  10. Characterizing liver capsule microstructure via in situ bulge test coupled with multiphoton imaging.

    Science.gov (United States)

    Jayyosi, C; Coret, M; Bruyère-Garnier, K

    2016-02-01

    The characterization of biological tissue at the microscopic scale is the starting point of many applications in tissue engineering and especially in the development of structurally based constitutive models. In the present study, focus is made on the liver capsule, the membrane encompassing hepatic parenchyma, which takes a huge part in liver mechanical properties. An in situ bulge test experiment under a multiphoton microscope has been developed to assess the microstructure changes that arise with biaxial loading. Multiphoton microscopy allows to observe the elastin and collagen fiber networks simultaneously. Thus a description of the microstructure organization of the capsule is given, characterizing the shapes, geometry and arrangement of fibers. The orientation of fibers is calculated and orientation distribution evolution with loading is given, in the case of an equibiaxial and two non equibiaxial loadings, thanks to a circular and elliptic set up of the bulge test. The local strain fields have also been computed, by the mean of a photobleaching grid, to get an idea of what the liver capsule might experience when subjected to internal pressure. Results show that strain fields present some heterogeneity due to anisotropy. Reorientation occurs in non equibiaxial loadings and involves fibers layers from the inner to the outer surface as expected. Although there is a fiber network rearrangement to accommodate with loading in the case of equibiaxial loading, there is no significant reorientation of the main fibers direction of the different layers.

  11. Constitutive modeling of a commercially pure titanium: validation using bulge tests

    Science.gov (United States)

    Revil-Baudard, Benoit; Massoni, Elisabeth

    2016-08-01

    In this paper, mechanical tests aimed at characterizing the plastic anisotropy of a commercially pure α-titanium sheet are presented. Hemispheric and elliptic bulge tests conducted to investigate the forming properties of the material are also reported. To model the particularities of the plastic response of the material the classical Hill [1] yield criterion, and Cazacu et al. [2] yield criterion are used. Identification of the material parameters involved in both criteria is based only on uniaxial test data, while their predictive capabilities are assessed through comparison with the bulge tests data. Both models reproduce qualitatively the experimental plastic strain distribution and the final thickness of the sheet. However, only Cazacu et al. [2] yield criterion, which accounts for both the anisotropy and tension-compression asymmetry of the material captures correctly plastic strain localization, in particular its directionality. Furthermore, it is shown that accounting for the strong tension-compression asymmetry in the model formulation improves numerical predictions regarding the mechanical behavior close to fracture of a commercially pure titanium alloy under sheet metal forming processes.

  12. On the kinematic separation of field and cluster stars across the bulge globular NGC 6528

    Energy Technology Data Exchange (ETDEWEB)

    Lagioia, E. P.; Bono, G.; Buonanno, R. [Dipartimento di Fisica, Università degli Studi di Roma-Tor Vergata, via della Ricerca Scientifica 1, I-00133 Roma (Italy); Milone, A. P. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston, ACT 2611 (Australia); Stetson, P. B. [Dominion Astrophysical Observatory, Herzberg Institute of Astrophysics, National Research Council, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Prada Moroni, P. G. [Dipartimento di Fisica, Università di Pisa, I-56127 Pisa (Italy); Dall' Ora, M. [INAF-Osservatorio Astronomico di Capodimonte, Salita Moiariello 16, I-80131 Napoli (Italy); Aparicio, A.; Monelli, M. [Instituto de Astrofìsica de Canarias, E-38200 La Laguna, Tenerife, Canary Islands (Spain); Calamida, A.; Ferraro, I.; Iannicola, G. [INAF-Osservatorio Astronomico di Roma, Via Frascati 33, I-00044 Monte Porzio Catone (Italy); Gilmozzi, R. [European Southern Observatory, Karl-Schwarzschild-Straße 2, D-85748 Garching (Germany); Matsunaga, N. [Kiso Observatory, Institute of Astronomy, School of Science, The University of Tokyo, 10762-30, Mitake, Kiso-machi, Kiso-gun, 3 Nagano 97-0101 (Japan); Walker, A., E-mail: eplagioia@roma2.infn.it [Cerro Tololo Inter-American Observatory, National Optical Astronomy Observatory, Casilla 603, La Serena (Chile)

    2014-02-10

    We present deep and precise multi-band photometry of the Galactic bulge globular cluster NGC 6528. The current data set includes optical and near-infrared images collected with ACS/WFC, WFC3/UVIS, and WFC3/IR on board the Hubble Space Telescope. The images cover a time interval of almost 10 yr, and we have been able to carry out a proper-motion separation between cluster and field stars. We performed a detailed comparison in the m {sub F814W}, m {sub F606W} – m {sub F814W} color-magnitude diagram with two empirical calibrators observed in the same bands. We found that NGC 6528 is coeval with and more metal-rich than 47 Tuc. Moreover, it appears older and more metal-poor than the super-metal-rich open cluster NGC 6791. The current evidence is supported by several diagnostics (red horizontal branch, red giant branch bump, shape of the sub-giant branch, slope of the main sequence) that are minimally affected by uncertainties in reddening and distance. We fit the optical observations with theoretical isochrones based on a scaled-solar chemical mixture and found an age of 11 ± 1 Gyr and an iron abundance slightly above solar ([Fe/H] = +0.20). The iron abundance and the old cluster age further support the recent spectroscopic findings suggesting a rapid chemical enrichment of the Galactic bulge.

  13. High-Resolution Mapping of Dust via Extinction in the M31 Bulge

    CERN Document Server

    Dong, Hui; Wang, Q D; Lauer, Tod R; Olsen, Knut A G; Saha, Abhijit; Dalcanton, Julianne J; Groves, Brent A

    2016-01-01

    We map the dust distribution in the central 180" (~680 pc) region of the M31 bulge, based on HST/WFC3 and ACS observations in ten bands from near-ultraviolet (2700 A) to near-infrared (1.5 micron). This large wavelength coverage gives us great leverage to detect not only dense dusty clumps, but also diffuse dusty molecular gas. We fit a pixel-by-pixel spectral energy distributions to construct a high-dynamic-range extinction map with unparalleled angular resolution (~0.5" , i.e., ~2 pc) and sensitivity (the extinction uncertainty, \\delta A_V~0.05). In particular, the data allow to directly fit the fractions of starlight obscured by individual dusty clumps, and hence their radial distances in the bulge. Most of these clumps seem to be located in a thin plane, which is tilted with respect to the M31 disk and appears face-on. We convert the extinction map into a dust mass surface density map and compare it with that derived from the dust emission as observed by Herschel . The dust masses in these two maps are co...

  14. Deformation Characterization of Friction-Stir-Welded Tubes by Hydraulic Bulge Testing

    Science.gov (United States)

    Pang, Q.; Hu, Z. L.; Pan, X.; Zuo, X. Q.

    2014-10-01

    In this article, the large-diameter thin-walled aluminum alloy tubes were produced using a hybrid process combining friction-stir welding (FSW) and spinning. For this novel process, rolled aluminum alloy sheets with a thickness about 2-3 times the wall thickness of target tube, were FSW to form cylinders, and then the cylinders were subjected to spinning to get thin-walled aluminum alloy tubes. Both experimental and simulation study were conducted to investigate the deformation characterization of the FSW tube during hydraulic bulge testing, and the stress and strain states and thickness distribution of the FSW tube were investigated. It was found that the common defects of FSW tube can be significantly improved by specific welding devices. The ductility of the tube is considerably improved with nearly two times higher bulge ratio than as-spun tube after annealing treatment at 300°C. But the annealed tube still shows a high nonuniform wall thickness distribution due to the inhomogeneous deformation characteristics. With increasing deformation of the tube, the gap between the hoop and axial stress for the weld and base metal (BM) decreases. However, the hoop and axial stress of the weld are always greater than those of the BM at the same pressure.

  15. The growth of discs and bulges during hierarchical galaxy formation - I. Fast evolution versus secular processes

    Science.gov (United States)

    Tonini, C.; Mutch, S. J.; Croton, D. J.; Wyithe, J. S. B.

    2016-07-01

    We present a theoretical model for the evolution of mass, angular momentum and size of galaxy discs and bulges, and we implement it into the semi-analytic galaxy formation code, Semi-Analytic Galaxy Evolution. The model follows both secular and violent evolutionary channels, including smooth accretion, disc instabilities, minor and major mergers. We find that the combination of our recipe with hierarchical clustering produces two distinct populations of bulges: merger-driven bulges, akin to classical bulges and ellipticals, and instability-driven bulges, akin to secular (or pseudo-)bulges. The model mostly reproduces the mass-size relation of gaseous and stellar discs, the evolution of the mass-size relation of ellipticals, the Faber-Jackson relation, and the magnitude-colour diagram of classical and secular bulges. The model predicts only a small overlap of merger-driven and instability-driven components in the same galaxy, and predicts different bulge types as a function of galaxy mass and disc fraction. Bulge type also affects the star formation rate and colour at a given luminosity. The model predicts a population of merger-driven red ellipticals that dominate both the low-mass and high-mass ends of the galaxy population, and span all dynamical ages; merger-driven bulges in disc galaxies are dynamically old and do not interfere with subsequent evolution of the star-forming component. Instability-driven bulges dominate the population at intermediate galaxy masses, especially thriving in massive discs. The model green valley is exclusively populated by instability-driven bulge hosts. Through the present implementation, the mass accretion history is perceivable in the galaxy structure, morphology and colours.

  16. Thermodynamic Considerations of Contamination by Alloying Elements of Remelted End-of-Life Nickel- and Cobalt-Based Superalloys

    Science.gov (United States)

    Lu, Xin; Matsubae, Kazuyo; Nakajima, Kenichi; Nakamura, Shinichiro; Nagasaka, Tetsuya

    2016-06-01

    Cobalt and nickel are high-value commodity metals and are mostly used in the form of highly alloyed materials. The alloying elements used may cause contamination problems during recycling. To ensure maximum resource efficiency, an understanding of the removability of these alloying elements and the controllability of some of the primary alloying elements is essential with respect to the recycling of end-of-life (EoL) nickel- and cobalt-based superalloys by remelting. In this study, the distribution behaviors of approximately 30 elements that are usually present in EoL nickel- and cobalt-based superalloys in the solvent metal (nickel, cobalt, or nickel-cobalt alloy), oxide slag, and gas phases during the remelting were quantitatively evaluated using a thermodynamic approach. The results showed that most of the alloying elements can be removed either in the slag phase or into the gas phase. However, the removal of copper, tin, arsenic, and antimony by remelting is difficult, and they remain as tramp elements during the recycling. On the other hand, the distribution tendencies of iron, molybdenum, and tungsten can be controlled by changing the remelting conditions. To increase the resource efficiency of recycling, preventing contamination by the tramp elements and identifying the alloying compositions of EoL superalloys are significantly essential, which will require the development of efficient prior alloy-sorting systems and advanced separation technologies.

  17. The growth of disks and bulges during hierarchical galaxy formation. I: fast evolution vs secular processes

    CERN Document Server

    Tonini, Chiara; Croton, Darren J; Wyithe, J Stuart B

    2016-01-01

    We present a theoretical model for the evolution of mass, angular momentum and size of galaxy disks and bulges, and we implement it into the semi-analytic galaxy formation code SAGE. The model follows both secular and violent evolutionary channels, including smooth accretion, disk instabilities, minor and major mergers. We find that the combination of our recipe with hierarchical clustering produces two distinct populations of bulges: merger-driven bulges, akin to classical bulges and ellipticals, and instability-driven bulges, akin to secular (or pseudo-)bulges. The model can successfully reproduce the mass-size relation of gaseous and stellar disks, the evolution of the mass-size relation of ellipticals, the Faber-Jackson relation, and the magnitude-colour diagram of classical and secular bulges. The model predicts only a small overlap of merger-driven and instability-driven components in the same galaxy, and predicts different bulge types as a function of galaxy mass and disk fraction. Bulge type also affe...

  18. Radio Detection Prospects for a Bulge Population of Millisecond Pulsars as Suggested by Fermi-LAT Observations of the Inner Galaxy

    Science.gov (United States)

    Calore, F.; Di Mauro, M.; Donato, F.; Hessels, J. W. T.; Weniger, C.

    2016-08-01

    The dense stellar environment of the Galactic center has been proposed to host a large population of as-yet undetected millisecond pulsars (MSPs). Recently, this hypothesis has found support in an analysis of gamma-rays detected using the Large Area Telescope onboard the Fermi satellite, which revealed an excess of diffuse GeV photons in the inner 15 deg about the Galactic center. The excess can be interpreted as the collective emission of thousands of MSPs in the Galactic bulge, with a spherical distribution strongly peaked toward the Galactic center. In order to fully establish the MSP interpretation, it is essential to find corroborating evidence in multi-wavelength searches, most notably through the detection of radio pulsations from individual bulge MSPs. Based on globular cluster observations and gamma-ray emission from the inner Galaxy, we investigate the prospects for detecting MSPs in the Galactic bulge. While previous pulsar surveys failed to identify this population, we demonstrate that upcoming large-area surveys of this region should lead to the detection of dozens of bulge MSPs. Additionally, we show that deep targeted searches of unassociated Fermi sources should be able to detect the first few MSPs in the bulge. The prospects for these deep searches are enhanced by a tentative gamma-ray/radio correlation that we infer from high-latitude gamma-ray MSPs. Such detections would constitute the first clear discoveries of field MSPs in the Galactic bulge, with far-reaching implications for gamma-ray observations, the formation history of the central Milky Way, and strategy optimization for future deep radio pulsar surveys.

  19. The structure of the Milky Way's bar outside the bulge

    Science.gov (United States)

    Wegg, Christopher; Gerhard, Ortwin; Portail, Matthieu

    2015-07-01

    While it is incontrovertible that the inner Galaxy contains a bar, its structure near the Galactic plane has remained uncertain, where extinction from intervening dust is greatest. We investigate here the Galactic bar outside the bulge, the long bar, using red clump giant (RCG) stars from United Kingdom Infrared Deep Sky Survey, Two Micron All Sky Survey, Vista Variables in the Via Lactea and Galactic Legacy Infrared Midplane Survey Extraordinaire. We match and combine these surveys to investigate a wide area in latitude and longitude, |b| ≤ 9° and |l| ≤ 40°. We find (i) the bar extends to l ˜ 25° at |b| ˜ 5° from the Galactic plane, and to l ˜ 30° at lower latitudes; (ii) the long bar has an angle to the line-of-sight in the range (28°-33°), consistent with studies of the bulge at |l| thin bar component reminiscent of the old thin disc near the Sun, and a ˜45 pc superthin bar components which exist predominantly towards the bar end; (v) constructing parametric models for the red clump magnitude distributions, we find a bar half-length of 5.0 ± 0.2 kpc for the two-component bar, and 4.6 ± 0.3 kpc for the thin bar component alone. We conclude that the Milky Way contains a central box/peanut bulge which is the vertical extension of a longer, flatter bar, similar as seen in both external galaxies and N-body models.

  20. Thermodynamic re-assessment of the Fe-AI-C system based on the Fe-rich experimental data

    Institute of Scientific and Technical Information of China (English)

    Lin LI; Shui-gen HUANG; Li WANG; Yan-lin HE; Jef VLEUGELS; Omer VAN DER BIEST

    2009-01-01

    The influence of C and A1 content on phase transformation temperatures, i.e., the A1 and A3 of Fe-rich alloys is investigated by dilatometric analysis. With the new set of experimental data, an updated thermodynamic description of the Fe-A1-C system is presented, by using the thermodynamic data of the Fe-C, Fe-Al and Al-C systems, as well as the parameters for the Fe-Al-C ternary system optimized in this study. The good compatibility of the thermodynamic parameters with experimental data is demonstrated by several calculated vertical sections. A well reproduced vertical section of the Fe-Mn-Si-Al-C system is also presented according to the thermodynamic description of the lower order systems.

  1. Validation of antifreeze properties of glutathione based on its thermodynamic characteristics and protection of baker's yeast during cryopreservation.

    Science.gov (United States)

    Zhang, Chao; Zhang, Hui; Wang, Li; Yao, Huiyuan

    2007-06-13

    The antifreeze ability of glutathione was evaluated on the basis of its thermodynamic characteristics and protection of baker's yeast during cryopreservation at -30 degrees C. The thermodynamic characteristics and protection of baker's yeast of glutathione were similar to those of known antifreeze proteins, such as carrot antifreeze protein and holly antifreeze protein. These properties included lowering the freezing point at about 0.20 degrees C non-colligatively, decreasing freezable water content, controlling the movement of free water for its strong hydrophilicity, and improving baker's yeast survival during the simulated processing of frozen dough. Therefore, glutathione was viewed to be an antifreeze protein like substance on the basis of its unique thermodynamic characteristics and protection of baker's yeast. The method combining thermodynamic characteristic analysis and protection evaluation is a new and simple way to screen new antifreeze proteins. PMID:17508758

  2. Effect of processing parameters on bulge-forming Polycarbonate parts

    Institute of Scientific and Technical Information of China (English)

    HOU Zhen-xiu; WU Jing; LIU Zhi; LI Xiao-dong; Z. R. Wang

    2007-01-01

    According to the data of the experiment made in mechauical tensile of Polycarbonate in high temperature, experiments were done to polycarbonate sheet by hot gas pressure bulge-forming. It was found that selecting and combination of the processing parameters were vital to the quality. In the experiments and numerical simulation with the software of DYNAFORM, the processing parameters have been studied. The results showed that the method of discontinuous pressure and pressure preservation advantage the forming; when temperature and pressure meet the forming conditions, the longer time of pressure preservation promotes sufficient forming.

  3. Free Bulging at Constant Pressure of Superplastic Sheet Metal

    Directory of Open Access Journals (Sweden)

    Costanzo Bellini

    2015-08-01

    Full Text Available This work intends to establish, by means of analytical modelling, a practical definition of the superplastic behaviour by using the results of the free bulging of sheet metal instead of the results of the traditional tensile test. In particular this paper analyses the superplastic flow of PbSn60 alloy and it focuses the attention on the value of H parameter corresponding to the maximum value of dt/dH, never considered in the literature. This parameter can represent a practical tool in industrial applications to establish the superplastic behaviour of a sheet metal.

  4. Signatures of bulge triaxiality from kinematics in Baade's window

    Science.gov (United States)

    Zhao, Hongsheng; Spergel, David N.; Rich, R. Michael

    1994-01-01

    We study a sample of 62 Baade's Window, (l,b) = (1, -4)deg, K giants that have published proper motions, radial velocity, and metallicity. Using R(sub 0) = 8 kpc, we construct the velocity ellipsoids, namely the 3x3 velocity dispersion tensors, for the metal rich stars ((Fe/H) greater than or equal to 0) and metal poor stars ((Fe/H) less than or equal to -0.2). After diagonalizing the tensor, we find a vertex deviation characteristic of a nonaxisymmetric system. Eigenvalues for the two velocity ellipsoids (sigma(sub 1), sigma(sub 2), sigma(sub 3)) are (126, 89, 65) +/- 13 km/s for the metal rich sample and (154, 77, 83) +/- 25 km/s for the metal poor sample with their long axes pointing to two nearly perpendicular directions (l(sub v), b(sub v)) = (-65 +/- 9 deg, +14 +/- 9 deg) and (l(sub v), b(sub v)) = (25 +/- 14 deg, -11 +/- 14 deg), respectively. The vertex deviations of the velocity ellipsoids cannot be consistently explained by any oblate model. We are able to reject the hypothesis that the metal poor and metal rich populations are drawn from the same distribution at better than the 97% confidence level. We populate orbits in a realistic bar potential with a Gaussian velocity distribution, allowing us to simulate and interpret observations. We conclude that the data are consistent with a triaxial bulge pointing towards (l,b) with l less than 0 deg and b = 0 deg as suggested by earlier work on gas dynamics and the observed light distribution. We also predict that low latitude (absolute value of b less than or equal to 4 deg) bulge fields should show the vertex deviation more strongly and would therefore be the best locations for future proper motion studies. In the classification scheme of Athanassoula et al. (1983) the metal rich stars appear to occupy the B-family orbits which rotate in the prograde sense in the rest frame and have boxy shapes that are aligned with and supporting the bar. The metal poor stars in the sample lag behind the metal rich bulge and

  5. Spectral descriptors for bulk metallic glasses based on the thermodynamics of competing crystalline phases

    Science.gov (United States)

    Perim, Eric; Lee, Dongwoo; Liu, Yanhui; Toher, Cormac; Gong, Pan; Li, Yanglin; Simmons, W. Neal; Levy, Ohad; Vlassak, Joost J.; Schroers, Jan; Curtarolo, Stefano

    2016-08-01

    Metallic glasses attract considerable interest due to their unique combination of superb properties and processability. Predicting their formation from known alloy parameters remains the major hindrance to the discovery of new systems. Here, we propose a descriptor based on the heuristics that structural and energetic `confusion' obstructs crystalline growth, and demonstrate its validity by experiments on two well-known glass-forming alloy systems. We then develop a robust model for predicting glass formation ability based on the geometrical and energetic features of crystalline phases calculated ab initio in the AFLOW framework. Our findings indicate that the formation of metallic glass phases could be much more common than currently thought, with more than 17% of binary alloy systems potential glass formers. Our approach pinpoints favourable compositions and demonstrates that smart descriptors, based solely on alloy properties available in online repositories, offer the sought-after key for accelerated discovery of metallic glasses.

  6. Thermodynamic properties of lanthanum in gallium-indium eutectic based alloys

    OpenAIRE

    Shchetinskiy, A. V.; Dedyukhin, A. S.; Volkovich, V. A.; Yamshchikov, L. F.; Maisheva, A. I.; Osipenko, A. G.; Kormilitsyn, M. V.

    2013-01-01

    Activity and activity coefficients of lanthanum were determined for the first time in gallium-indium eutectic based alloys in a wide temperature range employing electromotive force method. Activity of β-La and super cooled liquid lanthanum in Ga-In eutectic based alloys between 573 and 1073 K linearly depends on the reciprocal temperature: lgaβ-La(Ga-In)=5.660-15, 352T±0.093 lgaLa(Ga-In)=6.074-15,839T±0.093 Activity coefficients of β-La and super cooled liquid lanthanum in this system at 617-...

  7. Extinction maps toward the Milky Way bulge: Two-dimensional and three-dimensional tests with apogee

    Energy Technology Data Exchange (ETDEWEB)

    Schultheis, M. [Université de Nice Sophia-Antipolis, CNRS, Observatoire de Côte d' Azur, Laboratoire Lagrange, 06304 Nice Cedex 4 (France); Zasowski, G. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Allende Prieto, C. [Instituto de Astrofísica de Canarias, Calle Vía Láctea s/n, E-38205 La Laguna, Tenerife (Spain); Anders, F.; Chiappini, C. [Leibniz-Institut für Astrophysik Potsdam (AIP), D-14482 Potsdam (Germany); Beaton, R. L.; García Pérez, A. E.; Majewski, S. R. [Department of Astronomy, University of Virginia, Charlottesville, VA 22904 (United States); Beers, T. C. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Bizyaev, D. [Apache Point Observatory, Sunspot, NM 88349 (United States); Frinchaboy, P. M. [Department of Physics and Astronomy, Texas Christian University, TCU Box 298840, Fort Worth, TX 76129 (United States); Ge, J. [Astronomy Department, University of Florida, Gainesville, FL 32611 (United States); Hearty, F.; Schneider, D. P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Holtzman, J. [New Mexico State University, Las Cruces, NM 88003 (United States); Muna, D. [Department of Astronomy, The Ohio State University, Columbus, OH 43210 (United States); Nidever, D. [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Shetrone, M., E-mail: mathias.schultheis@oca.eu, E-mail: gail.zasowski@gmail.com [McDonald Observatory, The University of Texas at Austin, Austin, TX 78712 (United States)

    2014-07-01

    Galactic interstellar extinction maps are powerful and necessary tools for Milky Way structure and stellar population analyses, particularly toward the heavily reddened bulge and in the midplane. However, due to the difficulty of obtaining reliable extinction measures and distances for a large number of stars that are independent of these maps, tests of their accuracy and systematics have been limited. Our goal is to assess a variety of photometric stellar extinction estimates, including both two-dimensional and three-dimensional extinction maps, using independent extinction measures based on a large spectroscopic sample of stars toward the Milky Way bulge. We employ stellar atmospheric parameters derived from high-resolution H-band Apache Point Observatory Galactic Evolution Experiment (APOGEE) spectra, combined with theoretical stellar isochrones, to calculate line-of-sight extinction and distances for a sample of more than 2400 giants toward the Milky Way bulge. We compare these extinction values to those predicted by individual near-IR and near+mid-IR stellar colors, two-dimensional bulge extinction maps, and three-dimensional extinction maps. The long baseline, near+mid-IR stellar colors are, on average, the most accurate predictors of the APOGEE extinction estimates, and the two-dimensional and three-dimensional extinction maps derived from different stellar populations along different sightlines show varying degrees of reliability. We present the results of all of the comparisons and discuss reasons for the observed discrepancies. We also demonstrate how the particular stellar atmospheric models adopted can have a strong impact on this type of analysis, and discuss related caveats.

  8. Thermochromism, stability and thermodynamics of cobalt(II) complexes in newly synthesized nitrate based ionic liquid and its photostability.

    Science.gov (United States)

    Banić, Nemanja; Vraneš, Milan; Abramović, Biljana; Csanádi, János; Gadžurić, Slobodan

    2014-11-01

    In this work a 1-(2-hydroxyethyl)-3-methylimidazolium nitrate ionic liquid, [HO(CH2)2mim]NO3, has been synthesized in order to serve as a new thermochromic material upon addition of cobalt(II) ions. Spectrophotometric measurements of a series of cobalt(II) nitrate and cobalt(II) chloride solutions in [HO(CH2)2mim]NO3 at 298.15, 308.15, 318.15, 328.15, and 338.15 K, were performed. Based on the recorded spectra, the overall stability constants and thermodynamic parameters for the cobalt(II) associations with chloride and nitrate ions were calculated. The thermodynamic calculations suggest that thermochromism is not observed in the ionic medium due to a small entropy change during the replacement of nitrate with chloride ions in the co-ordination sphere of cobalt(II). The absence of the molecular solvent was also the reason for the lack of thermochromism. Thus, cobalt(II) solutions in [HO(CH2)2mim]NO3 and water mixtures were studied as a new and green medium that can be used for the auto-regulation of the light intensity and shade protection. The investigated system with water upon addition of cobalt(II) was found to be a far more efficient and responsive thermochromic medium for all of the studied systems up until now. The structure of [HO(CH2)2mim]NO3 was confirmed by both (1)H NMR and IR spectroscopy. Also, the efficiency of different advanced oxidation processes (UV-induced photolysis, UV/H2O2 photolysis, heterogeneous photocatalysis using TiO2 Degussa P25 and TiO2 with 7.24%, w/w Fe catalysts) for [HO(CH2)2mim]NO3 degradation were investigated. The reaction intermediates formed during the photo-oxidation process were identified using LC-ESI-MS/MS and (1)H NMR techniques. PMID:25192002

  9. Bars in Disk-Dominated and Bulge-Dominated Galaxies at z~0: New Insights from ~3600 SDSS Galaxies

    CERN Document Server

    Barazza, Fabio D; Marinova, Irina

    2007-01-01

    We present a study of large-scale bars in the local Universe, based on a large sample of ~3692 galaxies, with -18.5 60^{\\circ}$) systems, we find the following results. (1) The optical r-band fraction (f_opt-r) of barred galaxies, when averaged over the whole sample, is ~48%-52%. (2)~When galaxies are separated according to half light radius (r_e), or normalized r_e/R_24, which is a measure of the bulge-to-disk (B/D) ratio, a remarkable result is seen: f_opt-r rises sharply, from ~40% in galaxies that have small r_e/R_24 and visually appear to host prominent bulges, to ~70% for galaxies that have large r_e/R_24 and appear disk-dominated. (3)~f_opt-r rises for galaxies with bluer colors, lower masses, or fainter luminosities. (4) While hierarchical $\\Lambda$CDM models of galaxy evolution models fail to produce galaxies without classical bulges, our study finds that ~20% of disk galaxies appear to be ``quasi-bulgeless''. (5) After applying the same cutoffs in magnitude (M_V= 1.5 kpc), and bar ellipticity (e_bar...

  10. Thermodynamics of a post combustion hydrate-based carbon dioxide capture process

    International Nuclear Information System (INIS)

    Hydrates selectivity towards carbon dioxide is offering a promising route for carbon dioxide removal from flue gases. Hydrate-based CO2 capture process could substitute amine facilities widely implemented in gas treatment plants but suffering from oxidative degradation problems and high energy demand. In the framework of this thesis, we focus on phase equilibria that are involved in such process. Experimental dissociation conditions for clathrate hydrates of carbon dioxide and nitrogen, in the presence of some promoting molecules (Tetrahydrofuran, Tetrabutyl ammonium bromide and Tetrabutyl ammonium Fluoride ) are reported in the experimental section of this work. The data generated in this work along with literature data are compared to the model predictions. The developed model is based on the Cubic Plus Association (CPA) equation of state (EoS) for fluid phases combined to the van der Waals and Platteeuw's theory for the hydrate phase. (author)

  11. Thoria-based nuclear fuels thermophysical and thermodynamic properties, fabrication, reprocessing, and waste management

    CERN Document Server

    Bharadwaj, S R

    2013-01-01

    This book presents the state of the art on thermophysical and thermochemical properties, fabrication methodologies, irradiation behaviours, fuel reprocessing procedures, and aspects of waste management for oxide fuels in general and for thoria-based fuels in particular. The book covers all the essential features involved in the development of and working with nuclear technology. With the help of key databases, many of which were created by the authors, information is presented in the form of tables, figures, schematic diagrams and flow sheets, and photographs. This information will be useful for scientists and engineers working in the nuclear field, particularly for design and simulation, and for establishing the technology. One special feature is the inclusion of the latest information on thoria-based fuels, especially on the use of thorium in power generation, as it has less proliferation potential for nuclear weapons. Given its natural abundance, thorium offers a future alternative to uranium fuels in nuc...

  12. Acid Blue 25 adsorption on base treated Shorea dasyphylla sawdust: Kinetic,isotherm, thermodynamic and spectroscopic analysis

    Institute of Scientific and Technical Information of China (English)

    Megat Ahmad Kamal Megat Hanafiah; Wan Saime Wan Ngah; Shahira Hilwani Zolkafly; Lee Ching Teong; Zafri Azran Abdul Majid

    2012-01-01

    The potential of base treated Shorea dasyphylla (BTSD) sawdust for Acid Blue 25 (AB 25) adsorption was investigated in a batch adsorption process.Various physiochemical parameters such as pH,stirring rate,dosage,concentration,contact time and temperature were studied.The adsorbent was characterized with Fourier transform infrared spectrophotometer,scanning electron microscope and Brunauer,Emmett and Teller analysis.The optimum conditions for AB 25 adsorption were pH 2,stirring rate 500 r/min,adsorbent dosage 0.10 g and contact time 60 min.The pseudo second-order model showed the best conformity to the kinetic,data.The equilibrium adsorption of AB 25 was described by Freundlich and Langmuir,with the latter found to agree well with the isotherm model.The maximum monolayer adsorption capacity of BTSD was 24.39 mg/g at 300 K,estimated from the Langmuir model.Thermodynamic parameters such as Gibbs free energy,enthalpy and entropy were determined.It was found that AB 25 adsorption was spontaneous and exothermic.

  13. Thermodynamic and Structure Guided Design of Statin Based Inhibitors of 3-Hydroxy-3-Methylglutaryl Coenzyme A Reductase

    Energy Technology Data Exchange (ETDEWEB)

    Sarver, Ronald W.; Bills, Elizabeth; Bolton, Gary; Bratton, Larry D.; Caspers, Nicole L.; Dunbar, James B.; Harris, Melissa S.; Hutchings, Richard H.; Kennedy, Robert M.; Larsen, Scott D.; Pavlovsky, Alexander; Pfefferkorn, Jeffrey A.; Bainbridge, Graeme (Pfizer)

    2008-10-02

    Clinical studies have demonstrated that statins, 3-hydroxy-3-methylglutaryl coenzyme A reductase (HMGR) inhibitors, are effective at lowering mortality levels associated with cardiovascular disease; however, 2--7% of patients may experience statin-induced myalgia that limits compliance with a treatment regimen. High resolution crystal structures, thermodynamic binding parameters, and biochemical data were used to design statin inhibitors with improved HMGR affinity and therapeutic index relative to statin-induced myalgia. These studies facilitated the identification of imidazole 1 as a potent (IC{sub 50} = 7.9 nM) inhibitor with excellent hepatoselectivity (>1000-fold) and good in vivo efficacy. The binding of 1 to HMGR was found to be enthalpically driven with a {Delta}H of -17.7 kcal/M. Additionally, a second novel series of bicyclic pyrrole-based inhibitors was identified that induced order in a protein flap of HMGR. Similar ordering was detected in a substrate complex, but has not been reported in previous statin inhibitor complexes with HMGR.

  14. Computational Implementation of a Thermodynamically Based Work Potential Model For Progressive Microdamage and Transverse Cracking in Fiber-Reinforced Laminates

    Science.gov (United States)

    Pineda, Evan J.; Waas, Anthony M.; Bednarcyk, Brett A.; Collier, Craig S.

    2012-01-01

    A continuum-level, dual internal state variable, thermodynamically based, work potential model, Schapery Theory, is used capture the effects of two matrix damage mechanisms in a fiber-reinforced laminated composite: microdamage and transverse cracking. Matrix microdamage accrues primarily in the form of shear microcracks between the fibers of the composite. Whereas, larger transverse matrix cracks typically span the thickness of a lamina and run parallel to the fibers. Schapery Theory uses the energy potential required to advance structural changes, associated with the damage mechanisms, to govern damage growth through a set of internal state variables. These state variables are used to quantify the stiffness degradation resulting from damage growth. The transverse and shear stiffness of the lamina are related to the internal state variables through a set of measurable damage functions. Additionally, the damage variables for a given strain state can be calculated from a set of evolution equations. These evolution equations and damage functions are implemented into the finite element method and used to govern the constitutive response of the material points in the model. Additionally, an axial failure criterion is included in the model. The response of a center-notched, buffer strip-stiffened panel subjected to uniaxial tension is investigated and results are compared to experiment.

  15. Thermodynamic and kinetic investigation of a chemical reaction-based miniature heat pump

    OpenAIRE

    Flueckiger, Scott M.; Volle, Fabien; Garimella, S V; Mongia, Rajiv K.

    2012-01-01

    Representative reversible endothermic chemical reactions (paraldehyde depolymerization and 2-proponal dehydrogenation) are theoretically assessed for their use in a chemical heat pump design for compact thermal management applications. Equilibrium and dynamic simulations are undertaken to explore the operation of the heat pump which upgrades waste heat from near room temperature by approximately 20 in a minimized system volume. A model is developed based on system mass and energy balances cou...

  16. Thermodynamic Analysis of an Integrated Solar-based Chemical Reactor System for Hydrogen Production

    OpenAIRE

    YÜKSEL, Yunus Emre; Murat ÖZTÜRK

    2015-01-01

    The biggest advantage of the renewable energy based systems is that these energy systems are environmentally friendly, since they emit very few pollutants. The solar parabolic trough collector systems generate thermal energy by using solar radiation. These renewable energy systems are the most deployed type of the solar concentrating collectors. Especially, they are very suitable for middle-temperature solar power system applications. Storing of the solar energy is not a suitable way due to t...

  17. The nuclear bulge. I. K band observations of the central 30 PC

    Science.gov (United States)

    Philipp, S.; Zylka, R.; Mezger, P. G.; Duschl, W. J.; Herbst, T.; Tuffs, R. J.

    1999-08-01

    Out of ~ 500 individual source images we have constructed a mosaic map of the K band surface brightness in an area Delta alphax Delta delta ~ 650''x710'' (R_equiv ~ 15.8 pc for R_0 = 8.5 kpc) centered approximately on Sgr A*. An observing technique was used which allows us to recover an extended background emission. To separate sources from an unresolved background continuum we fitted Lorentzian distributions to the sources and find that about one half of an integrated, not dereddened K band flux density of 752 Jy is contributed by ~ 6*E(4) stars with flux densities S_K(') >~ 100 mu Jy and the remainder is contributed by an extended continuum provided by about 6*E(8) stars too weak to be observed as individual sources. We estimate that >~ 80% of the integrated flux density of the mosaic is contributed by stars in the Nuclear Bulge (NB; R 3 kpc). We determine the K band luminosity functions (KLF) of the mosaic and of subareas dominated by Nuclear Bulge, Galactic Bulge and Disk stars, respectively, and construct difference KLFs which relate to the specific stellar populations of these regions. The detection limit is S_K(') ~ 100 mu Jy, for the completeness limit we estimate S_K(') ~ 2 000 mu Jy. We find that the stellar population of the Nuclear Bulge contains considerably more bright stars (i.e. with reddened K band flux densities S_K(') >~ 5*E(3 mu ) Jy), most of which are probably early O stars, Giants and Supergiants. The stellar population of the Galactic Bulge on the other hand is dominated by stars which appear to be lower mass (Main Sequence (MS) stars. A model KLF constructed with a Salpeter Initial Mass Function (IMF) for stars of spectral type O9 or later (S_K(') masses ranging from 0.06 to 6 M_sun account for the unresolved continuum. Combining observed and model KLF we obtain a mosaic KLF which increases ~ S_K({') - 1} for 10(6) >~ S_K('/mu ) Jy >~ 10(3) and ~ S_K({') - 0.6} for 10(3) >~ S_K('/mu ) Jy >~ 3*E(-3) . For radii R relatively young generation

  18. Looking for imprints of the first stellar generations in metal-poor bulge field stars

    Science.gov (United States)

    Siqueira-Mello, C.; Chiappini, C.; Barbuy, B.; Freeman, K.; Ness, M.; Depagne, E.; Cantelli, E.; Pignatari, M.; Hirschi, R.; Frischknecht, U.; Meynet, G.; Maeder, A.

    2016-09-01

    Context. Efforts to look for signatures of the first stars have concentrated on metal-poor halo objects. However, the low end of the bulge metallicity distribution has been shown to host some of the oldest objects in the Milky Way and hence this Galactic component potentially offers interesting targets to look at imprints of the first stellar generations. As a pilot project, we selected bulge field stars already identified in the ARGOS survey as having [Fe/H] ≈-1 and oversolar [α/Fe] ratios, and we used FLAMES-UVES to obtain detailed abundances of key elements that are believed to reveal imprints of the first stellar generations. Aims: The main purpose of this study is to analyse selected ARGOS stars using new high-resolution (R ~ 45 000) and high-signal-to-noise (S/N> 100) spectra. We aim to derive their stellar parameters and elemental ratios, in particular the abundances of C, N, the α-elements O, Mg, Si, Ca, and Ti, the odd-Z elements Na and Al, the neutron-capture s-process dominated elements Y, Zr, La, and Ba, and the r-element Eu. Methods: High-resolution spectra of five field giant stars were obtained at the 8 m VLT UT2-Kueyen telescope with the UVES spectrograph in FLAMES-UVES configuration. Spectroscopic parameters were derived based on the excitation and ionization equilibrium of Fe i and Fe ii. The abundance analysis was performed with a MARCS LTE spherical model atmosphere grid and the Turbospectrum spectrum synthesis code. Results: We confirm that the analysed stars are moderately metal-poor (-1.04 ≤ [Fe/H] ≤-0.43), non-carbon-enhanced (non-CEMP) with [C/Fe] ≤ + 0.2, and α-enhanced. We find that our three most metal-poor stars are nitrogen enhanced. The α-enhancement suggests that these stars were formed from a gas enriched by core-collapse supernovae, and that the values are in agreement with results in the literature for bulge stars in the same metallicity range. No abundance anomalies (Na - O, Al - O, Al - Mg anti-correlations) were

  19. Electronic structures and thermodynamic stabilities of aluminum-based deuterides from first principles calculations

    Institute of Scientific and Technical Information of China (English)

    Ye Xiao-Qiu; Luo De-Li; Sang Ge; Ao Bing-Yun

    2011-01-01

    The alanates (complex aluminohydrides) have relatively high gravimetric hydrogen densities and are among the most promising solid-state hydrogen-storage materials. In this work, the electronic structures and the formation enthalpies of seven typical aluminum-based deuterides have been calculated by the plane-wave pseudopotential method,these being AID3, LiAID4, Li3AID6, BaAID5, Ba2AID7, LiMg(AID4)3 and LiMgAID6. The results show that all these compounds are large band gap insulators at 0 K with estimated band gaps from 2.31 eV in AID3 to 4.96 eV in LiMg(AID4)3. The band gaps are reduced when the coordination of Al varies from 4 to 6. Two peaks present in the valence bands are the common characteristics of aluminum-based deuterides containing AID4 subunits while three peaks are the common characteristics of those containing AID6 subunits. The electronic structures of these compounds are determined mainly by aluminum deuteride complexes (AID4 or AID6) and their mutual interactions. The predicted formation enthalpies are presented for the studied aluminum-based deuterides.

  20. Realistic Stellar Feedback & Bulge Formation in Clumpy Disks

    CERN Document Server

    Hopkins, Philip F; Murray, Norman; Quataert, Eliot; Hernquist, Lars

    2012-01-01

    We use numerical simulations of isolated galaxies to study the effects of realistic stellar feedback on the formation and evolution of giant star-forming gas 'clumps' in high-redshift, gas-rich galaxies. Such galactic disks are unstable to the formation of bound gas-rich clumps whose properties initially depend only on global disk properties, not the microphysics of feedback. In simulations without stellar feedback, clumps turn an order-unity fraction of their mass into stars and sink to the center, forming a large bulge and kicking most of the stars out into a much more extended stellar envelope. By contrast, stellar feedback disrupts even the most massive clumps after they turn ~10-20% of their mass into stars, in a timescale of ~10-100 Myr, ejecting some material into a super-wind and recycling the rest of the gas into the diffuse ISM. This suppresses the bulge formation rate by direct 'clump coalescence' by a factor of several. However, the galactic disks do undergo significant secular evolution in the ab...

  1. The Calcium Triplet metallicity calibration for galactic bulge stars

    CERN Document Server

    Vasquez, S; Hill, V; Gonzalez, O A; Saviane, I; Rejkuba, M; Battaglia, G

    2015-01-01

    We present a new calibration of the Calcium II Triplet equivalent widths versus [Fe/H], constructed upon K giant stars in the Galactic bulge. This calibration will be used to derive iron abundances for the targets of the GIBS survey, and in general it is especially suited for solar and supersolar metallicity giants, typical of external massive galaxies. About 150 bulge K giants were observed with the GIRAFFE spectrograph at VLT, both at resolution R~20,000 and at R~6,000. In the first case, the spectra allowed us to perform direct determination of Fe abundances from several unblended Fe lines, deriving what we call here high resolution [Fe/H] measurements. The low resolution spectra allowed us to measure equivalent widths of the two strongest lines of the near infrared Calcium II triplet at 8542 and 8662 A. By comparing the two measurements we derived a relation between Calcium equivalent widths and [Fe/H] that is linear over the metallicity range probed here, -1<[Fe/H]<+0.7. By adding a small second or...

  2. The metal content of the bulge globular cluster NGC 6528

    Science.gov (United States)

    Zoccali, M.; Barbuy, B.; Hill, V.; Ortolani, S.; Renzini, A.; Bica, E.; Momany, Y.; Pasquini, L.; Minniti, D.; Rich, R. M.

    2004-08-01

    High resolution spectra of five stars in the bulge globular cluster NGC 6528 were obtained at the 8m VLT UT2-Kueyen telescope with the UVES spectrograph. Out of the five stars, two of them showed evidence of binarity. The target stars belong to the horizontal and red giant branch stages, at 4000 elemental ratios for this template bulge cluster, as a basis for the fundamental calibration of metal-rich populations. The present analysis provides a metallicity [Fe/H] = -0.1±0.2 and the α-elements O, Mg and Si, show [α/Fe] ≈ +0.1, whereas Ca and Ti are around the solar value or below, resulting in an overall metallicity Z ≈ Z⊙. Observations collected both at the European Southern Observatory, Paranal and La Silla, Chile (ESO programme 65.L-0340) and with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, operated by AURA Inc. under contract to NASA. Tables \\ref{targets}, \\ref{logobs}, \\ref{tablines} and Fig. \\ref{chart} are only available in electronic form at http://www.edpsciences.org

  3. Dynamics of the Galactic Bulge using Planetary Nebulae

    CERN Document Server

    Beaulieu, S F; Kálnay, A J; Saha, P; Zhao, H S; Beaulieu, Sylvie F.; Freeman, Kenneth C.; Kalnajs, Agris J.; Saha, Prasenjit; Zhao, HongSheng

    2000-01-01

    Evidence for a bar at the center of the Milky Way triggered a renewed enthusiasm for dynamical modelling of the Galactic bar-bulge. Our goal is to compare the kinematics of a sample of tracers, planetary nebulae, widely distributed over the bulge with the corresponding kinematics for a range of models of the inner Galaxy. Three of these models are N-body barred systems arising from the instabilities of a stellar disk (Sellwood, Fux and Kalnajs), and one is a Schwarzschild system constructed to represent the 3D distribution of the COBE/DIRBE near-IR light and then evolved as an N-body system for a few dynamical times (Zhao). For the comparison of our data with the models, we use a new technique developed by Saha (1998). The procedure finds the parameters of each model, i.e. the solar galactocentric distance R_o in model units, the orientation angle phi, the velocity scale (in km/s per model unit), and the solar tangential velocity which best fit the data.

  4. High-Redshift Clumpy Disks and Bulges in Cosmological Simulations

    CERN Document Server

    Ceverino, Daniel; Bournaud, Frederic

    2009-01-01

    We analyze the first cosmological simulations that recover the fragmentation of high-redshift galactic discs driven by cold streams. The fragmentation is recovered owing to an AMR resolution better than 70 pc with cooling below 10^4 K. We study three typical star-forming galaxies in haloes of approx. 5 10^11 Msun at z=2.3, when they were not undergoing a major merger. The steady gas supply by cold streams leads to gravitationally unstable, turbulent discs, which fragment into giant clumps and transient features on a dynamical timescale. The disc clumps are not associated with dark-matter haloes. The clumpy discs are self-regulated by gravity in a marginaly unstable state. Clump migration and angular-momentum transfer on an orbital timescale help the growth of a central bulge with a mass comparable to the disc. The continuous gas input keeps the system of clumpy disc and bulge in a near "steady state", for several Gyr. The average star-formation rate, much of which occurs in the clumps, follows the gas accreti...

  5. Planetary Nebulae towards the Galactic bulge. I. [OIII] fluxes

    CERN Document Server

    Kovacevic, Anna V; Jacoby, George H; Sharp, Rob; Miszalski, Brent; Frew, David J

    2010-01-01

    We present [OIII]{\\lambda}5007 fluxes and angular diameters for 435 Planetary Nebulae (PN) in the central 10' x 10' region towards the Galactic bulge. Our sample is taken from the new discoveries of the MASH PN surveys as well as previously known PN. This sample accounts for 80% of known PN in this region. Fluxes and diameters are measured from narrow-band imaging with the MOSAIC-II camera on the 4-m Blanco telescope at the Cerro-Tololo Inter-American Observatory. This is the largest (~60 square degrees), uniform [OIII]{\\lambda}5007 survey of the inner Galactic bulge ever undertaken. 104 of the objects have measured [OIII]{\\lambda}5007, [OIII]{\\lambda}4959, H{\\alpha} or H{\\beta} fluxes from the literature, which we use to undertake a detailed comparison to demonstrate the integrity of our new fluxes. Our independent measurements are in excellent agreement with the very best literature sources over two orders of magnitude, while maintaining good consistency over five orders of magnitude. The excellent resoluti...

  6. Synthesis, crystal structure and thermodynamic properties of a new praseodymium Schiff-base complex

    Energy Technology Data Exchange (ETDEWEB)

    Li, Chuan-Hua, E-mail: lichuanhua0526@126.com [School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China); Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan (China); Song, Xiang-Zhi, E-mail: xzsong@csu.edu.cn [School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan (China); Jiang, Jian-Hong [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan (China); Gu, Hui-Wen [State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan (China); Tao, Li-Ming; Yang, Ping; Li, Xu; Xiao, Sheng-Xiong; Yao, Fei-Hong; Liu, Wen-Qi; Xie, Jin-Qi; Peng, Meng-Na; Pan, Lan; Wu, Xi-Bin; Jiang, Chao; Wang, Song; Xu, Man-Fen [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan (China); Li, Qiang-Guo, E-mail: liqiangguo@163.com [Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, Department of Chemistry and Life Science, Xiangnan University, Chenzhou 423000, Hunan (China)

    2014-04-01

    Highlights: • A new mononuclear Schiff base praseodymium complex was synthesized. • Based on Hess's law, thermochemical cycles of two reactions were designed. • The dissolution enthalpies were measured by a solution–reaction calorimeter. • The standard molar enthalpy of formation of the complex was calculated. - Abstract: The title complex [Pr(H{sub 2}vanen)(NO{sub 3}){sub 2}(H{sub 2}O){sub 2}·NO{sub 3}] was synthesized reacting of Valen Schiff-base ligand [H{sub 2}vanen = N,N′-ethylene-bis(3-methoxysalicylideneimine)] and Pr(NO{sub 3}){sub 3}·6H{sub 2}O in ethanol at 60 °C. The complex was crystallized in the monoclinic crystal system with space group P21/c. The coordination polyhedron of Pr(III) ion was consisted of two bidentate nitrate ions, two molecules of water and one ligand which coordinated through oxygen atoms of the two phenolic and methoxy groups. After designing two reasonable thermochemical cycles according to Hess's law, the calorimetric experiments were conducted using isoperibol solution–reaction calorimeter at a constant temperature of 298.15 K. The standard molar enthalpy changes of two reactions were determined to be Δ{sub r}H{sub m}{sup θ}(1a)=−(51.94±1.26) kJ mol{sup −1} and Δ{sub r}H{sub m}{sup θ}(1b)=−(8.62±1.34) kJ mol{sup −1}. Then the standard molar enthalpies of formation of the ligand and the title complex were calculated to be Δ{sub f}H{sub m}{sup θ} [H{sub 2}vanen(s), 298.15 K] = −(517.75 ± 2.36) kJ mol{sup −1} and Δ{sub f}H{sub m}{sup θ} [Pr(H{sub 2}vanen)(NO{sub 3}){sub 2}(H{sub 2}O){sub 2}·NO{sub 3} (s), 298.15 K] = −(2454.8 ± 2.7) kJ mol{sup −1}, respectively. The rationality of two thermochemical cycles was verified by UV spectra and refractive indexes.

  7. Spectral descriptors for bulk metallic glasses based on the thermodynamics of competing crystalline phases

    CERN Document Server

    Perim, Eric; Liu, Yanhui; Toher, Cormac; Gong, Pan; Li, Yanglin; Simmons, W Neal; Levy, Ohad; Vlassak, Joost J; Schroers, Jan; Curtarolo, Stefano

    2016-01-01

    Metallic glasses have attracted considerable interest in recent years due to their unique combination of superb properties and processability. Predicting bulk metallic glass formers from known parameters remains a challenge and the search for new systems is still performed by trial and error. It has been speculated that some sort of "confusion" during crystallization of the crystalline phases competing with glass formation could play a key role. Here, we propose a heuristic descriptor quantifying confusion and demonstrate its validity by detailed experiments on two well-known glass forming alloy systems. With the insight provided by these results, we develop a robust model for predicting glass formation ability based on the spectral decomposition of geometrical and energetic features of crystalline phases calculated ab-initio in the AFLOW high throughput framework. Our findings indicate that the formation of metallic glass phases could be a much more common phenomenon than currently estimated, with more than ...

  8. Thermodynamic optimization of solid oxide fuel cell based combined cycle cogeneration plant

    Energy Technology Data Exchange (ETDEWEB)

    Odukoya, A.; Reddy, B.V. [University of Ontario Inst. of Technology, Oshawa, ON (Canada). Dept. of Mechanical Engineering; Carretero, J.A. [New Brunswick Univ., Fredericton, NB (Canada). Dept. of Mechanical Engineering

    2010-07-01

    Although coal has the highest greenhouse gas emission of all fossil fuels it is the most abundant of all the fuels. Optimization of new and existing power plant designs will help increase the operational efficiency of power generation. In particular, there is a need to optimize the design and operating parameters of power plants using integrated gasification combined cycle cogeneration technology. This study investigated the optimal operating condition of a co-fired combined cycle cogeneration power plant with solid oxide fuel cell (SOFC) combination fuelled with coal and natural gas. It examined the macroscopic detail of the plant while optimizing the operating parameters of individual components such as the gasifier, the consumption of methane and carbon monoxide in the fuel cell and the consumption of fuel in the combustion chamber of the gas turbine. The optimization of the entire plant was used to determine the best mode of operating the plant for a set of conditions within suggested limits. The study also found efficient ways to perform iterative processes to find exit conditions from the gasifier, fuel cell, gas turbine combustion chamber and exit condition from the gas turbine. The maximum fuel cell net work output, combined cycle net work output, combined cycle thermal efficiency and cogeneration efficiency were determined. The optimal pressure ratio, temperature of operation of the SOFC and, gas turbine inlet temperature were determined using a sequential quadratic program solver based on the Quasi-Newton algorithm. 18 refs., 5 tabs., 2 figs.

  9. Modeling the structure and thermodynamics of ferrocenium-based ionic liquids.

    Science.gov (United States)

    Bernardes, Carlos E S; Mochida, Tomoyuki; Canongia Lopes, José N

    2015-04-21

    A new force-field for the description of ferrocenium-based ionic liquids is reported. The proposed model was validated by confronting Molecular Dynamics simulations results with available experimental data-enthalpy of fusion, crystalline structure and liquid density-for a series of 1-alkyl-2,3,4,5,6,7,8,9-octamethylferrocenium bis(trifluoromethylsulfonyl)imide ionic liquids, [CnFc][NTf2] (3 ≤ n ≤ 10). The model is able to reproduce the densities and enthalpies of fusion with deviations smaller than 2.6% and 4.8 kJ mol(-1), respectively. The MD simulation trajectories were also used to compute relevant structural information for the different [CnFc][NTf2] ionic liquids. The results show that, unlike other ILs, the alkyl side chains present in the cations are able to interact directly with the ferrocenium core of other ions. Even the ferrocenium charged cores (with relatively mild charge densities) are able to form small contact aggregates. This causes the partial rupture of the polar network and precludes the formation of extended nano-segregated polar-nonpolar domains normally observed in other ionic liquids. PMID:25797914

  10. Nonequilibrium thermodynamics of nucleation

    International Nuclear Information System (INIS)

    We present a novel approach to nucleation processes based on the GENERIC framework (general equation for the nonequilibrium reversible-irreversible coupling). Solely based on the GENERIC structure of time-evolution equations and thermodynamic consistency arguments of exchange processes between a metastable phase and a nucleating phase, we derive the fundamental dynamics for this phenomenon, based on continuous Fokker-Planck equations. We are readily able to treat non-isothermal nucleation even when the nucleating cores cannot be attributed intensive thermodynamic properties. In addition, we capture the dynamics of the time-dependent metastable phase being continuously expelled from the nucleating phase, and keep rigorous track of the volume corrections to the dynamics. Within our framework the definition of a thermodynamic nuclei temperature is manifest. For the special case of nucleation of a gas phase towards its vapor-liquid coexistence, we illustrate that our approach is capable of reproducing recent literature results obtained by more microscopic considerations for the suppression of the nucleation rate due to nonisothermal effects

  11. Nonequilibrium thermodynamics of nucleation.

    Science.gov (United States)

    Schweizer, M; Sagis, L M C

    2014-12-14

    We present a novel approach to nucleation processes based on the GENERIC framework (general equation for the nonequilibrium reversible-irreversible coupling). Solely based on the GENERIC structure of time-evolution equations and thermodynamic consistency arguments of exchange processes between a metastable phase and a nucleating phase, we derive the fundamental dynamics for this phenomenon, based on continuous Fokker-Planck equations. We are readily able to treat non-isothermal nucleation even when the nucleating cores cannot be attributed intensive thermodynamic properties. In addition, we capture the dynamics of the time-dependent metastable phase being continuously expelled from the nucleating phase, and keep rigorous track of the volume corrections to the dynamics. Within our framework the definition of a thermodynamic nuclei temperature is manifest. For the special case of nucleation of a gas phase towards its vapor-liquid coexistence, we illustrate that our approach is capable of reproducing recent literature results obtained by more microscopic considerations for the suppression of the nucleation rate due to nonisothermal effects. PMID:25494727

  12. Chemical abundances and dust in planetary nebulae in the Galactic bulge

    NARCIS (Netherlands)

    Gutenkunst, S.; Bernard-Salas, J.; Pottasch, S. R.; Sloan, G. C.; Houck, J. R.

    2008-01-01

    We present mid-infrared Spitzer spectra of 11 planetary nebulae in the Galactic bulge. We derive argon, neon, sulfur, and oxygen abundances for them using mainly infrared line fluxes combined with some optical line fluxes from the literature. Due to the high extinction toward the bulge, the infrared

  13. An Experimental Study of Bulge-Forming Polycarbonate (PC)Semisphere Shell Parts

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, a new bulge-forming technology is described to manufacture a polycarbonate semisphere shell. Some experiments have been done, and the experimental results show that this technique is feasible to form polycarbonate part. But the wall thickness distribution of the bulged specimen by this method is not so even.

  14. The maximum optical depth toward bulge stars from axisymmetric models of the Milky Way

    NARCIS (Netherlands)

    Kuijken, K

    1997-01-01

    It has been known that recent microlensing results toward the bulge imply mass densities that are surprisingly high, given dynamical constraints on the Milky Way mass distribution. We derive the maximum optical depth toward the bulge that may be generated by axisymmetric structures in the Milky Way,

  15. Breast tissue bulge and lesion visibility during stereotactic biopsy – A phantom study

    International Nuclear Information System (INIS)

    Background: During mammography guided stereotactic breast biopsy a bulge of tissue can form in the paddle needle biopsy aperture. This bulge has been estimated to have a height of up to 30% of the breast itself. During clinical biopsy we have noticed that lesions can appear to be less visible when tissue bulges are evident. This can make biopsy more difficult in some cases. Objectives: This experiment investigates how lesion visibility varies with breast bulge magnitude. Method: Using a phantom to represent breast and breast bulge, lesion visibility was assessed using a two alternative forced choice methodology. To mimic clinical conditions, imaging was performed on a full field digital mammography system with the biopsy paddle attached using an automatic exposure device. Organ dose (breast) was estimated. Results: As breast bulge increases lesion visibility decreases; organ dose increases as breast bulge magnitude increases. Conclusion: Consideration should be given to the impact of breast bulge magnitude and lesion visibility when performing image guided biopsy. Advances in knowledge: The authors found no similar studies and the results of this study demonstrate a potential clinical risk

  16. Lost in secular evolution: the case of a low mass classical bulge

    CERN Document Server

    Saha, Kanak

    2015-01-01

    The existence of a classical bulge in disk galaxies holds important clue to the assembly history of galaxies. Finding observational evidence of very low mass classical bulges particularly in barred galaxies including our Milky Way, is a challenging task as the bar driven secular evolution might bring significant dynamical change to these bulges alongside the stellar disk. Using high-resolution N-body simulation, we show that if a cool stellar disk is assembled around a non-rotating low-mass classical bulge, the disk rapidly grows a strong bar within a few rotation time scales. Later, the bar driven secular process transform the initial classical bulge into a flattened rotating stellar system whose central part also have grown a bar-like component rotating in sync with the disk bar. During this time, a boxy/peanut (hereafter, B/P) bulge is formed via the buckling instability of the disk bar and the vertical extent of this B/P bulge being slightly higher than that of the classical bulge, it encompasses the whol...

  17. Lightweight Mg-based composites with thermodynamically stable interfaces by in-situ combustion synthesis

    Science.gov (United States)

    Jo, Ilguk

    Lightweight Mg-based composites have been produced by in-situ combustion synthesis of the Al-Ti-C reaction system. The characteristics of the in-situ composites were investigated in terms of phase evolution and interfacial stability using various analysis techniques. The structural analysis results showed that full conversion of the Al-Ti-C reactants into spherical TiC reinforcements with sizes around 1mum was achieved by the combustion reaction. In-situ formed TiC had less oxygen and higher Al contents at the interface than ex-situ formed TiC; these clean interfaces with an Al layer on the reinforcements were shown to yield interfacial stability. For these reasons, the in-situ composites exhibited higher theoretical densities and also good mechanical properties compared with ex-situ produced composites. The interfacial characteristics of molten Mg with the Al-Ti-C reactants and the commercial TiC+Al substrates were evaluated using an infiltration technique under an argon atmosphere. Infiltration length increased with time at temperature, yielding activation energies (Ea) for each system. The value of Ea for the Al-Ti-C system (307.31kJ/mol) is lower than that for the other system (350.84kJ/mol); the high Ea value indicates that the infiltration is not a simple viscosity-controlled phenomenon but involves a chemical reaction. Formation of the Al3Ti phase was observed from the crystal structural analysis of the infiltrated area; thus, existence of reaction promoting the wetting of Mg. The phase evolution, reaction mechanism and kinetics of the Al-Ti-C reaction were studied using DSC and HT-XRD. It was confirmed that, along with the melting of Al, there was formation of Al3Ti by reaction between Al and Ti. A detailed structural analysis indicates that, the reaction mechanism involves melting of Al followed by formation and growth of Al 3Ti, which then contacts the graphite powder and initiates the combustion reaction. The effect of important process parameters, such

  18. Thermodynamic interpolation

    Energy Technology Data Exchange (ETDEWEB)

    Maiden, D E

    1998-10-01

    A method for constructing bicubic interpolation polynomials for the pressure P and internal energy E that are thermodynamically consistent at the mesh ponts and continuous across mesh boundaries is presented. The slope boundary conditions for the pressure and energy are derived from finite differences of the data and from Maxwell's consistency relation. Monotonicity of the sound speed and the specific heat is obtained by a bilinear interpolation of the slopes of the tabulated data. Monotonicity of the functions near steep gradients may be achieved by mesh refinement or by using a non-consistent bilinear to the data. Mesh refinement is very efficient for uniform-linear or uniform-logarithmic spaced data because a direct table lookup can be used. The direct method was compared to binary search and was 37 percent faster for logarithmic-spaced data and 106 percent faster for linear-spaced data. This improvement in speed is very important in the radiation-transport opacity-lookup part of the calculation. Interpolation in P-E space, with mesh refinement, can be made simple, robust, and conserve energy. In the final analysis the interpolation of the free energy and entropy (Maiden and Cook) remains a competitor.

  19. A density functional reactivity theory (DFRT) based approach to understand the effect of symmetry of fullerenes on the kinetic, thermodynamic and structural aspects of carbon NanoBuds

    Science.gov (United States)

    Sarmah, Amrit; Roy, Ram Kinkar

    2016-06-01

    In the present study, we have rationalized the effect of variation in the symmetry of relatively smaller fullerene (C32) on the mode of its interaction with semi-conducting Single-Walled Carbon Nanotubes (SWCNTs) in the process of formation of stable hybrid carbon NanoBuds. Thermodynamic and kinetic parameters, along with the charge transfer values associated with the interaction between fullerene and SWCNTs, have been evaluated using an un-conventional and computationally cost-effective method based on density functional reactivity theory (DFRT). In addition to this, conventional DFT based studies are also performed to substantiate the growth of NanoBud structures formed by the interaction between fullerene and SWCNTs. The findings of the present study suggest that the kinetic, thermodynamic and structural aspects of hybrid carbon NanoBuds are significantly influenced by both the symmetry of C32 fullerene and its site of covalent attachment to the SWCNT.

  20. The chemical evolution of the Galactic Bulge seen through micro-lensing events

    Directory of Open Access Journals (Sweden)

    Lucatello S.

    2012-02-01

    Full Text Available Galactic bulges are central to understanding galaxy formation and evolution. Here we report on recent studies using micro-lensing events to obtain spectra of high resolution and moderately high signal-to-noise ratios of dwarf stars in the Galactic bulge. Normally this is not feasible for the faint turn-off stars in the Galactic bulge, but micro-lensing offers this possibility. Elemental abundance trends in the Galactic bulge as traced by dwarf stars are very similar to those seen for dwarf stars in the solar neighbourhood. We discuss the implications of the ages and metallicity distribution function derived for the micro-lensed dwarf stars in the Galactic bulge.

  1. The impact of bulges on the radial distribution of supernovae in disc galaxies

    CERN Document Server

    Hakobyan, A A; Barkhudaryan, L V; Mamon, G A; Kunth, D; Petrosian, A R; Adibekyan, V; Aramyan, L S; Turatto, M

    2016-01-01

    We present an analysis of the impact of bulges on the radial distributions of the different types of supernovae (SNe) in the stellar discs of host galaxies with various morphologies. We find that in Sa-Sm galaxies, all core-collapse (CC) and vast majority of SNe Ia belong to the disc, rather than the bulge component. The radial distribution of SNe Ia in S0-S0/a galaxies is inconsistent with their distribution in Sa-Sm hosts, which is probably due to the contribution of the outer bulge SNe Ia in S0-S0/a galaxies. The radial distributions of both types of SNe are similar in all the subsamples of Sa-Sbc and Sc-Sm galaxies. These results confirm that the old bulges of Sa-Sm galaxies are not significant producers of Type Ia SNe, while the bulge populations are significant for SNe Ia only in S0-S0/a galaxies.

  2. A TWO-PHASE SCENARIO FOR BULGE ASSEMBLY IN {Lambda}CDM COSMOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Obreja, A.; Dominguez-Tenreiro, R.; Brook, C. [Departamento de Fisica Teorica, Universidad Autonoma de Madrid, E-28049 Cantoblanco Madrid (Spain); Martinez-Serrano, F. J.; Domenech-Moral, M.; Serna, A. [Departamento de Fisica y Arquitectura de Computadores, Universidad Miguel Hernandez, E-03202 Elche (Spain); Molla, M. [Departamento de Investigacion Basica, CIEMAT, E-28040 Madrid (Spain); Stinson, G., E-mail: aura.obreja@uam.es [Max-Planck-Institut fuer Astronomie, Koenigstuhl 17, D-69117, Heidelberg (Germany)

    2013-01-20

    We analyze and compare the bulges of a sample of L {sub *} spiral galaxies in hydrodynamical simulations in a cosmological context, using two different codes, P-DEVA and GASOLINE. The codes regulate star formation in very different ways, with P-DEVA simulations inputting low star formation efficiency under the assumption that feedback occurs on subgrid scales, while the GASOLINE simulations have feedback that drives large-scale outflows. In all cases, the marked knee shape in mass aggregation tracks, corresponding to the transition from an early phase of rapid mass assembly to a later slower one, separates the properties of two populations within the simulated bulges. The bulges analyzed show an important early starburst resulting from the collapse-like fast phase of mass assembly, followed by a second phase with lower star formation, driven by a variety of processes such as disk instabilities and/or mergers. Classifying bulge stellar particles identified at z = 0 into old and young according to these two phases, we found bulge stellar sub-populations with distinct kinematics, shapes, stellar ages, and metal contents. The young components are more oblate, generally smaller, more rotationally supported, with higher metallicity and less alpha-element enhanced than the old ones. These results are consistent with the current observational status of bulges, and provide an explanation for some apparently paradoxical observations, such as bulge rejuvenation and metal-content gradients observed. Our results suggest that bulges of L {sub *} galaxies will generically have two bulge populations that can be likened to classical and pseudo-bulges, with differences being in the relative proportions of the two, which may vary due to galaxy mass and specific mass accretion and merger histories.

  3. A TWO-PHASE SCENARIO FOR BULGE ASSEMBLY IN ΛCDM COSMOLOGIES

    International Nuclear Information System (INIS)

    We analyze and compare the bulges of a sample of L * spiral galaxies in hydrodynamical simulations in a cosmological context, using two different codes, P-DEVA and GASOLINE. The codes regulate star formation in very different ways, with P-DEVA simulations inputting low star formation efficiency under the assumption that feedback occurs on subgrid scales, while the GASOLINE simulations have feedback that drives large-scale outflows. In all cases, the marked knee shape in mass aggregation tracks, corresponding to the transition from an early phase of rapid mass assembly to a later slower one, separates the properties of two populations within the simulated bulges. The bulges analyzed show an important early starburst resulting from the collapse-like fast phase of mass assembly, followed by a second phase with lower star formation, driven by a variety of processes such as disk instabilities and/or mergers. Classifying bulge stellar particles identified at z = 0 into old and young according to these two phases, we found bulge stellar sub-populations with distinct kinematics, shapes, stellar ages, and metal contents. The young components are more oblate, generally smaller, more rotationally supported, with higher metallicity and less alpha-element enhanced than the old ones. These results are consistent with the current observational status of bulges, and provide an explanation for some apparently paradoxical observations, such as bulge rejuvenation and metal-content gradients observed. Our results suggest that bulges of L * galaxies will generically have two bulge populations that can be likened to classical and pseudo-bulges, with differences being in the relative proportions of the two, which may vary due to galaxy mass and specific mass accretion and merger histories.

  4. Thermodynamics of Radiation Modes

    Science.gov (United States)

    Pina, Eduardo; de la Selva, Sara Maria Teresa

    2010-01-01

    We study the equilibrium thermodynamics of the electromagnetic radiation in a cavity of a given volume and temperature. We found three levels of description, the thermodynamics of one mode, the thermodynamics of the distribution of frequencies in a band by summing over the frequencies in it and the global thermodynamics by summing over all the…

  5. Radio Wave Reflections from Magnetized Plasma Bulges in the Martian Ionosphere

    Science.gov (United States)

    Zhang, Z.; Nielsen, E.; Xiao, L.; Liang, Y.

    2011-12-01

    In this paper we propose a quantitative explanation of a special type of radio wave reflection phenomena observed by MARSIS (Mars Advanced Radar for Subsurface and Ionosphere Sounding), in light of the cold plasma theory. The phenomena in question appear as a type of traces in the AIS (Active Ionosphere Sounding) ionograms. The traces show the following characteristics: (1) They may appear only when the spacecraft is near to a magnetic cusp region (around 300km altitude) on dayside; (2) They are "C"-shaped curves, with their open ends pointing to the increasing frequency direction. Obviously, these traces represent 'reflection pairs' (two echoes corresponding to one transmission from the antenna). The two echoes of a 'pair' have approximately the same time delay at the lowest propagating frequency, and have increasing time delay separation with increasing wave frequency; (3) Their positions and sizes in ionograms (i.e., their frequency ranges and time delay ranges) change regularly with spacecraft motion; (4) They represent quite rare events, since they are clearly observed only in a few orbit segments among thousands of orbits of Mars Express. In order to investigate the origin of these features, we employ a 2D spatial configuration model of the magnetized plasma bulge to simulate the behavior of the AIS radio waves. In the model the magnetic field is assumed to be a deformed vertical cylinder (corresponding to the patched crustal field of Mars), with its transverse size expanding upward. Magnetic flux density decreases upward and sideward continuously into a low background field value (while the total flux is conserved). Electron density is positively related to the field flux density, meanwhile decreases upward in an exponential manner. Equilibrium between magnetic pressure and plasma pressure is assumed to hold the density bulge. A ray tracing method based on the cold plasma dispersion relation is used to produce artificial ionograms. We find that under some

  6. Thermodynamic approach to biomass gasification

    International Nuclear Information System (INIS)

    The document presents an approach of biomass transformation in presence of steam, hydrogen or oxygen. Calculation results based on thermodynamic equilibrium are discussed. The objective of gasification techniques is to increase the gas content in CO and H2. The maximum content in these gases is obtained when thermodynamic equilibrium is approached. Any optimisation action of a process. will, thus, tend to approach thermodynamic equilibrium conditions. On the other hand, such calculations can be used to determine the conditions which lead to an increase in the production of CO and H2. An objective is also to determine transformation enthalpies that are an important input for process calculations. Various existing processes are assessed, and associated thermodynamic limitations are evidenced. (author)

  7. Lensing of unresolved stars towards the Galactic Bulge

    CERN Document Server

    Alard, C

    1996-01-01

    Previous calculations of the rates and optical depths due to microlensing only considered resolved stars. However, if a faint unresolved star lens is close enough to a resolved star, the event will be seen by the microlensing experiments and attributed to the bighter star. The blending biases the duration, making the contribution of the unresolved stars very significant for short events. This contribution is confused with lensing by brown dwarfs. The exact rates of these blended events are extremly sensitive to the limiting magnitude achieved in the microlensing search. Appropriate calculations of the optical depth and rates are provided here, and illustrated in the case of the DUO and OGLE experiments. The additional contribution of unresolved stars is very significant and probably explains the high optical depth and rates observed towards the Galactic Bulge. The blended unresolved event can be identified using either the color shift or the light curve shape. However, neither of these two methods is apropria...

  8. Mathematical foundations of thermodynamics

    CERN Document Server

    Giles, R; Stark, M; Ulam, S

    2013-01-01

    Mathematical Foundations of Thermodynamics details the core concepts of the mathematical principles employed in thermodynamics. The book discusses the topics in a way that physical meanings are assigned to the theoretical terms. The coverage of the text includes the mechanical systems and adiabatic processes; topological considerations; and equilibrium states and potentials. The book also covers Galilean thermodynamics; symmetry in thermodynamics; and special relativistic thermodynamics. The book will be of great interest to practitioners and researchers of disciplines that deal with thermodyn

  9. Thermodynamic characteristics of the acid-base equilibria of taurine in aqueous solutions, according to calorimetry data

    Science.gov (United States)

    Gridchin, S. N.; Shekhanov, R. F.; Pyreu, D. F.

    2015-02-01

    Enthalpies of the neutralization and protonation of taurine (HL) are measured by direct calorimetry at 298.15 K and ionic strengths of 0.3, 0.5, and 1.0 (KNO3). The standard thermodynamic characteristics of HL protolytic equilibria are calculated.

  10. Thermodynamic Property Surfaces for Adsorption of R507A, R134a, and n -Butane on Pitch-Based Carbonaceous Porous Materials

    KAUST Repository

    Chakraborty, Anutosh

    2010-10-01

    The thermodynamic property surfaces of R507A, R134a, and n-butane on pitch-based carbonaceous porous material (Maxsorb III) are developed from rigorous classical thermodynamics and experimentally measured adsorption isotherm data. These property fields enable us to compute the entropy, enthalpy, internal energy, and heat of adsorption as a function of pressure, temperature, and the amount of adsorbate. The entropy and enthalpy maps are necessary for the analysis of adsorption cooling cycle and gas storage. We have shown here that it is possible to plot an adsorption cooling cycle on the temperature-entropy (T-s) and enthalpy-uptake (h-x) maps. Copyright © Taylor and Francis Group, LLC 2010.

  11. MbT-Tool: An open-access tool based on Thermodynamic Electron Equivalents Model to obtain microbial-metabolic reactions to be used in biotechnological process.

    Science.gov (United States)

    Araujo, Pablo Granda; Gras, Anna; Ginovart, Marta

    2016-01-01

    Modelling cellular metabolism is a strategic factor in investigating microbial behaviour and interactions, especially for bio-technological processes. A key factor for modelling microbial activity is the calculation of nutrient amounts and products generated as a result of the microbial metabolism. Representing metabolic pathways through balanced reactions is a complex and time-consuming task for biologists, ecologists, modellers and engineers. A new computational tool to represent microbial pathways through microbial metabolic reactions (MMRs) using the approach of the Thermodynamic Electron Equivalents Model has been designed and implemented in the open-access framework NetLogo. This computational tool, called MbT-Tool (Metabolism based on Thermodynamics) can write MMRs for different microbial functional groups, such as aerobic heterotrophs, nitrifiers, denitrifiers, methanogens, sulphate reducers, sulphide oxidizers and fermenters. The MbT-Tool's code contains eighteen organic and twenty inorganic reduction-half-reactions, four N-sources (NH4 (+), NO3 (-), NO2 (-), N2) to biomass synthesis and twenty-four microbial empirical formulas, one of which can be determined by the user (CnHaObNc). MbT-Tool is an open-source program capable of writing MMRs based on thermodynamic concepts, which are applicable in a wide range of academic research interested in designing, optimizing and modelling microbial activity without any extensive chemical, microbiological and programing experience.

  12. MbT-Tool: An open-access tool based on Thermodynamic Electron Equivalents Model to obtain microbial-metabolic reactions to be used in biotechnological process.

    Science.gov (United States)

    Araujo, Pablo Granda; Gras, Anna; Ginovart, Marta

    2016-01-01

    Modelling cellular metabolism is a strategic factor in investigating microbial behaviour and interactions, especially for bio-technological processes. A key factor for modelling microbial activity is the calculation of nutrient amounts and products generated as a result of the microbial metabolism. Representing metabolic pathways through balanced reactions is a complex and time-consuming task for biologists, ecologists, modellers and engineers. A new computational tool to represent microbial pathways through microbial metabolic reactions (MMRs) using the approach of the Thermodynamic Electron Equivalents Model has been designed and implemented in the open-access framework NetLogo. This computational tool, called MbT-Tool (Metabolism based on Thermodynamics) can write MMRs for different microbial functional groups, such as aerobic heterotrophs, nitrifiers, denitrifiers, methanogens, sulphate reducers, sulphide oxidizers and fermenters. The MbT-Tool's code contains eighteen organic and twenty inorganic reduction-half-reactions, four N-sources (NH4 (+), NO3 (-), NO2 (-), N2) to biomass synthesis and twenty-four microbial empirical formulas, one of which can be determined by the user (CnHaObNc). MbT-Tool is an open-source program capable of writing MMRs based on thermodynamic concepts, which are applicable in a wide range of academic research interested in designing, optimizing and modelling microbial activity without any extensive chemical, microbiological and programing experience. PMID:27635191

  13. Chemical Equilibrium as Balance of the Thermodynamic Forces

    OpenAIRE

    Zilbergleyt, B.

    2004-01-01

    The article sets forth comprehensive basics of thermodynamics of chemical equilibrium as balance of the thermodynamic forces. Based on the linear equations of irreversible thermodynamics, De Donder definition of the thermodynamic force, and Le Chatelier's principle, new thermodynamics of chemical equilibrium offers an explicit account for multiple chemical interactions within the system. Basic relations between energetic characteristics of chemical transformations and reaction extents are bas...

  14. The discovery of thermodynamics

    Science.gov (United States)

    Weinberger, Peter

    2013-07-01

    Based on the idea that a scientific journal is also an "agora" (Greek: market place) for the exchange of ideas and scientific concepts, the history of thermodynamics between 1800 and 1910 as documented in the Philosophical Magazine Archives is uncovered. Famous scientists such as Joule, Thomson (Lord Kelvin), Clausius, Maxwell or Boltzmann shared this forum. Not always in the most friendly manner. It is interesting to find out, how difficult it was to describe in a scientific (mathematical) language a phenomenon like "heat", to see, how long it took to arrive at one of the fundamental principles in physics: entropy. Scientific progress started from the simple rule of Boyle and Mariotte dating from the late eighteenth century and arrived in the twentieth century with the concept of probabilities. Thermodynamics was the driving intellectual force behind the industrial revolution, behind the enormous social changes caused by this revolution. The history of thermodynamics is a fascinating story, which also gives insights into the mechanism that seem to govern science.

  15. CHEMICAL ABUNDANCE ANALYSIS OF A NEUTRON-CAPTURE ENHANCED RED GIANT IN THE BULGE PLAUT FIELD

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Christian I.; Rich, R. Michael [Department of Physics and Astronomy, UCLA, 430 Portola Plaza, Box 951547, Los Angeles, CA 90095-1547 (United States); McWilliam, Andrew, E-mail: cijohnson@astro.ucla.edu, E-mail: rmr@astro.ucla.edu, E-mail: cjohnson@cfa.harvard.edu, E-mail: andy@obs.carnegiescience.edu [Observatories of the Carnegie Institution of Washington, Pasadena, CA 91101 (United States)

    2013-09-20

    We present chemical abundances for 27 elements ranging from oxygen to erbium in the metal-poor ([Fe/H] = –1.67) bulge red giant branch star 2MASS 18174532-3353235. The results are based on equivalent width and spectrum synthesis analyses of a high-resolution (R ∼ 30, 000) spectrum obtained with the Magellan-MIKE spectrograph. While the light (Z ∼< 30) element abundance patterns match those of similar metallicity bulge and halo stars, the strongly enhanced heavy element abundances are more similar to 'r-II' halo stars (e.g., CS 22892-052) typically found at [Fe/H] ∼< – 2.5. We find that the heaviest elements (Z ≥ 56) closely follow the scaled-solar r-process abundance pattern. We do not find evidence supporting significant s-process contributions; however, the intermediate mass elements (e.g., Y and Zr) appear to have been produced through a different process than the heaviest elements. The light and heavy element abundance patterns of 2MASS 18174532-3353235 are in good agreement with the more metal-poor r-process enhanced stars CS 22892-052 and BD +17{sup o}3248. 2MASS 18174532-3353235 also shares many chemical characteristics with the similar metallicity but comparatively α-poor Ursa Minor dwarf galaxy giant COS 82. Interestingly, the Mo and Ru abundances of 2MASS 18174532-3353235 are also strongly enhanced and follow a similar trend recently found to be common in moderately metal-poor main-sequence turn-off halo stars.

  16. Bulge and Clump Evolution in Hubble Ultra Deep Field Clump Clusters, Chains and Spiral Galaxies

    CERN Document Server

    Elmegreen, Bruce G; Fernandez, Maria Ximena; Lemonias, Jenna Jo

    2008-01-01

    Clump clusters and chain galaxies in the Hubble Ultra Deep Field are examined for bulges in the NICMOS images. Approximately 50% of the clump clusters and 30% of the chains have relatively red and massive clumps that could be young bulges. Magnitudes and colors are determined for these bulge-like objects and for the bulges in spiral galaxies, and for all of the prominent star-formation clumps in these three galaxy types. The colors are fitted to population evolution models to determine the bulge and clump masses, ages, star-formation rate decay times, and extinctions. The results indicate that bulge-like objects in clump cluster and chain galaxies have similar ages and 2 to 5 times larger masses compared to the star-formation clumps, while the bulges in spirals have ~6 times larger ages and 20 to 30 times larger masses than the clumps. All systems appear to have an underlying red disk population. The masses of star-forming clumps are typically in a range from 10^7 to 10^8 Msun; their ages have a wide range ar...

  17. The Molecular Gas Density in Galaxy Centers and How It Connects to Bulges

    CERN Document Server

    Fisher, David B; Drory, Niv; Combes, Francoise; Blitz, Leo; Wong, Tony

    2012-01-01

    In this paper we present gas density, star formation rate, stellar masses, and bulge disk decompositions for a sample of 60 galaxies. Our sample is the combined sample of BIMA SONG, CARMA STING, and PdBI NUGA surveys. We study the effect of using CO-to-H_2 conversion factors that depend on the CO surface brightness, and also that of correcting star formation rates for diffuse emission from old stellar populations. We estimate that star formation rates in bulges are typically lower by 20% when correcting for diffuse emission. We find that over half of the galaxies in our sample have molecular gas surface density >100 M_sun pc^-2. We find a trend between gas density of bulges and bulge Sersic index; bulges with lower Sersic index have higher gas density. Those bulges with low Sersic index (pseudobulges) have gas fractions that are similar to that of disks. We also find that there is a strong correlation between bulges with the highest gas surface density and the galaxy being barred. However, we also find that c...

  18. Heavy elements Ba, La, Ce, Nd, and Eu in 56 Galactic bulge red giants

    CERN Document Server

    Van der Swaelmen, M; Hill, V; Zoccali, M; Minniti, D; Ortolani, S; Gomez, A

    2016-01-01

    Aims. The aim of this work is the study of abundances of the heavy elements Ba, La, Ce, Nd, and Eu in 56 bulge giants (red giant branch and red clump) with metallicities ranging from -1.3 dex to 0.5 dex. Methods. We obtained high-resolution spectra of our giant stars using the FLAMES-UVES spectrograph on the Very Large Telescope. We inspected four bulge fields along the minor axis. Results. We measure the chemical evolution of heavy elements, as a function of metallicity, in the Galactic bulge. Conclusions. The [Ba, La, Ce, Nd/Fe] vs. [Fe/H] ratios decrease with increasing metallicity, in which aspect they differ from disc stars. In our metal-poor bulge stars, La and Ba are enhanced relative to their thick disc counterpart, while in our metal-rich bulge stars La and Ba are underabundant relative to their disc counterpart. Therefore, this contrast between bulge and discs trends indicates that bulge and (solar neighbourhood) thick disc stars could behave differently. An increase in [La, Nd/Eu] with increasing m...

  19. Classical and statistical thermodynamics

    CERN Document Server

    Rizk, Hanna A

    2016-01-01

    This is a text book of thermodynamics for the student who seeks thorough training in science or engineering. Systematic and thorough treatment of the fundamental principles rather than presenting the large mass of facts has been stressed. The book includes some of the historical and humanistic background of thermodynamics, but without affecting the continuity of the analytical treatment. For a clearer and more profound understanding of thermodynamics this book is highly recommended. In this respect, the author believes that a sound grounding in classical thermodynamics is an essential prerequisite for the understanding of statistical thermodynamics. Such a book comprising the two wide branches of thermodynamics is in fact unprecedented. Being a written work dealing systematically with the two main branches of thermodynamics, namely classical thermodynamics and statistical thermodynamics, together with some important indexes under only one cover, this treatise is so eminently useful.

  20. Structural and thermodynamic signatures that define pseudotriloop RNA hairpins

    NARCIS (Netherlands)

    R.M. van der Werf (Ramon); S.S. Wijmenga (Sybren); H.A. Heus (Hans); R.C.L. Olsthoorn (René)

    2013-01-01

    textabstractPseudotriloop (PTL) structures in RNAs have been recognized as essential elements in RNA folding and recognition of proteins. PTL structures are derived from hexaloops by formation of a cross-loop base pair leaving a triloop and 3′ bulged out residue. Despite their common presence and fu

  1. 基于热力学定律的绿色经济发展探究%To Explore the Green Economy Based on the Thermodynamics Laws

    Institute of Scientific and Technical Information of China (English)

    曹庭珠

    2011-01-01

    Green economy, whose nature is ecological economy, is a new economic development model which can promote harmonious development between the soeio - economy and the environment. As complying with environmental rules, it has the primary meaning to study the thermodynamics laws of the thermal phenomenon about the energy conversion and state changes law for the green economy. The revelations of the thermodynamics laws to green economy are explored in this paper, while the thermodynamic analyses on green economy are made. The green economic development measures are put forward based on the thermodynamics laws by building low -entropy model: following the natural law, developing green science and technology and setting low- entropy idea.%绿色经济是人类寻求的一种能够促进社会经济与环境和谐发展的新型经济发展模式,其本质是生态经济.绿色经济遵从生态规律,研究热现象中物态转变和能量转换规律的热力学定律对于绿色经济具有重要的意义.文章探究了热力学定律对绿色经济发展的启示,并对绿色经济进行了热力学分析,提出通过构建低熵发展模式、遵循自然生态规律、发展绿色科技、树立低熵观念等途径发展绿色经济.

  2. Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, S H [Ames Laboratory; Wang, Y [Pennsylvania State University; Chen, L -Q [Pennsylvania State University; Liu, Z -K [Pennsylvania State University; Napolitano, R E [Ames Laboratory

    2014-09-01

    A solution-based thermodynamic description of the ternary Ni–Al–Mo system is developed here, incorporating first-principles calculations and reported modeling of the binary Ni–Al, Ni–Mo and Al–Mo systems. To search for the configurations with the lowest energies of the N phase, the Alloy Theoretic Automated Toolkit (ATAT) was employed and combined with VASP. The liquid, bcc and γ-fcc phases are modeled as random atomic solutions, and the γ'-Ni3Al phase is modeled by describing the ordering within the fcc structure using two sublattices, summarized as (Al,Mo,Ni)0.75(Al,Mo,Ni)0.25. Thus, γ-fcc and γ'-Ni3Al are modeled with a single Gibbs free energy function with appropriate treatment of the chemical ordering contribution. In addition, notable improvements are the following: first, the ternary effects of Mo and Al in the B2-NiAl and D0a-Ni3Mo phases, respectively, are considered; second, the N-NiAl8Mo3 phase is described as a solid solution using a three-sublattice model; third, the X-Ni14Al75Mo11 phase is treated as a stoichiometric compound. Model parameters are evaluated using first-principles calculations of zero-Kelvin formation enthalpies and reported experimental data. In comparison with the enthalpies of formation for the compounds ψ-AlMo, θ-Al8Mo3 and B2-NiAl, the first-principles results indicate that the N-NiAl8Mo3 phase, which is stable at high temperatures, decomposes into other phases at low temperature. Resulting phase equilibria are summarized in the form of isothermal sections and liquidus projections. To clearly identify the relationship between the γ-fcc and γ'-Ni3Al phases in the ternary Ni–Al–Mo system, the specific γ-fcc and γ'-Ni3Al phase fields are plotted in x(Al)–x(Mo)–T space for a temperature range 1200–1800 K.

  3. Using 3D Spectroscopy to Probe the Orbital Structure of Composite Bulges

    CERN Document Server

    Erwin, Peter; Thomas, Jens; Fabricius, Maximilian; Bender, Ralf; Rusli, Stephanie; Nowak, Nina; Beckman, John E; Beltrán, Juan Carlos Vega

    2014-01-01

    Detailed imaging and spectroscopic analysis of the centers of nearby S0 and spiral galaxies shows the existence of "composite bulges", where both classical bulges and disky pseudobulges coexist in the same galaxy. As part of a search for supermassive black holes in nearby galaxy nuclei, we obtained VLT-SINFONI observations in adaptive-optics mode of several of these galaxies. Schwarzschild dynamical modeling enables us to disentangle the stellar orbital structure of the different central components, and to distinguish the differing contributions of kinematically hot (classical bulge) and kinematically cool (pseudobulge) components in the same galaxy.

  4. Retrieving Bulge and Disk Parameters and Asymptotic Magnitudes from the Growth Curves of Galaxies

    CERN Document Server

    Okamura, S; Shimasaku, K; Yagi, M; Weinberg, D H; Okamura, Sadanori; Yasuda, Naoki; Shimasaku, Kazuhiro; Yagi, Masafumi; Weinberg, David H.

    1998-01-01

    We show that the growth curves of galaxies can be used to determine their bulge and disk parameters and bulge-to-total luminosity ratios, in addition to their conventional asymptotic magnitudes, provided that the point spread function is accurately known and signal-to-noise ratio is modest (S/N$\\gtrsim30$). The growth curve is a fundamental quantity that most future large galaxy imaging surveys will measure. Bulge and disk parameters retrieved from the growth curve will enable us to perform statistical studies of luminosity structure for a large number of galaxies.

  5. An optics-based variable-temperature assay system for characterizing thermodynamics of biomolecular reactions on solid support

    Energy Technology Data Exchange (ETDEWEB)

    Fei, Yiyan; Landry, James P.; Zhu, X. D., E-mail: xdzhu@physics.ucdavis.edu [Department of Physics, University of California, One Shields Avenue, Davis, California 95616 (United States); Li, Yanhong; Yu, Hai; Lau, Kam; Huang, Shengshu; Chokhawala, Harshal A.; Chen, Xi [Department of Chemistry, University of California, One Shields Avenue, Davis, California 95616 (United States)

    2013-11-15

    A biological state is equilibrium of multiple concurrent biomolecular reactions. The relative importance of these reactions depends on physiological temperature typically between 10 °C and 50 °C. Experimentally the temperature dependence of binding reaction constants reveals thermodynamics and thus details of these biomolecular processes. We developed a variable-temperature opto-fluidic system for real-time measurement of multiple (400–10 000) biomolecular binding reactions on solid supports from 10 °C to 60 °C within ±0.1 °C. We illustrate the performance of this system with investigation of binding reactions of plant lectins (carbohydrate-binding proteins) with 24 synthetic glycans (i.e., carbohydrates). We found that the lectin-glycan reactions in general can be enthalpy-driven, entropy-driven, or both, and water molecules play critical roles in the thermodynamics of these reactions.

  6. An optics-based variable-temperature assay system for characterizing thermodynamics of biomolecular reactions on solid support.

    Science.gov (United States)

    Fei, Yiyan; Landry, James P; Li, Yanhong; Yu, Hai; Lau, Kam; Huang, Shengshu; Chokhawala, Harshal A; Chen, Xi; Zhu, X D

    2013-11-01

    A biological state is equilibrium of multiple concurrent biomolecular reactions. The relative importance of these reactions depends on physiological temperature typically between 10 °C and 50 °C. Experimentally the temperature dependence of binding reaction constants reveals thermodynamics and thus details of these biomolecular processes. We developed a variable-temperature opto-fluidic system for real-time measurement of multiple (400-10,000) biomolecular binding reactions on solid supports from 10 °C to 60 °C within ±0.1 °C. We illustrate the performance of this system with investigation of binding reactions of plant lectins (carbohydrate-binding proteins) with 24 synthetic glycans (i.e., carbohydrates). We found that the lectin-glycan reactions in general can be enthalpy-driven, entropy-driven, or both, and water molecules play critical roles in the thermodynamics of these reactions.

  7. Measuring Thermodynamic Length

    Energy Technology Data Exchange (ETDEWEB)

    Crooks, Gavin E

    2007-09-07

    Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It is also connected to the Jensen-Shannon divergence, Fisher information, and Rao's entropy differential metric. Therefore, thermodynamic length is of central interestin understanding matter out of equilibrium. In this Letter, we will consider how to denethermodynamic length for a small system described by equilibrium statistical mechanics and how to measure thermodynamic length within a computer simulation. Surprisingly, Bennett's classic acceptance ratio method for measuring free energy differences also measures thermodynamic length.

  8. Thermodynamic characteristics of acid-base equilibria of DL-α-alanyl-DL-norleucine in aqueous solutions at 298 K

    Science.gov (United States)

    Lytkin, A. I.; Chernikov, V. V.; Krutova, O. N.; Bychkova, S. A.; Skvortsov, I. A.

    2015-09-01

    Protolytic equilibria in aqueous solutions of DL-α-alanyl-DL-norleucine are studied via potentiometry and calorimetry. Measurements are made at 298.15 K and ionic strengths of 0.5, 1.0, and 1.5 (against a background of potassium nitrate). The thermodynamic characteristics (p K, Δ G, Δ H, Δ S) of the stepwise dissociation of the dipeptide both in aqueous-salt solutions and in standard solution are obtained for the first time.

  9. The Theta-z relation for HST bulges and disks out to z approximately equal 0.8

    Science.gov (United States)

    Mutz, Steven B.; Windhorst, Rogier A.; Schmidtke, Paul C.; Pascarelle, Sebastian M.; Griffiths, Richard E.; Ratnatunga, Kavan U.; Casertano, Stefano; Im, Myungshin; Ellis, Richard S.; Glazebrook, Karl

    1994-01-01

    We present Hubble Space Telescope (HST) scale lengths and ground-based redshifts for 63 faint field galaxies down to I less than or approximately 21.5 mag from the Medium-Deep Survey. These have measured redshifts z less than or approximately 0.8 and half-light radii 0.1 sec less than or approximately r(sub e), r(sub s) less than or approximately 5 sec. We present the Theta-z relation for r(exp 1/4)-bulges and exponential disks separately for world models with q(sub 0) = 0.0-1.0. We show that selection against low surface brightness galaxies in the HST images and ground-based spectra is comparable to that in local surveys. We compare our HST disk-dominated galaxies to a magnitude-limited subsample of the European Southern Observatory (ESO)-Uppsala local spirals. Extrapolating the best-fit local exponential disk scale length (r(sub s) = 3.5 kpc for H(sub 0) = 75) out to z = 0.8, we find a rather symmetrical distribution of HST disks around this value. This implies that galaxy disks have been stable since z is approximately equal to 0.8. We compare our HST bulge-dominated galaxies with r(exp 1/4)-profiles to a magnitude-limited subsample of local Seven Samurai ellipticals. The latter have a local best fit r(sub e) = 5.7 kpc. Our HST bulge sample shows a similar distribution for z less than or approximately 0.8. Elliptical galaxy scale lengths have thus also remained rather constant since z less than or approximately 0.8. We set limits to their possible evolution.

  10. Understanding thermodynamics

    CERN Document Server

    Ness, H C van

    1983-01-01

    Clearly written treament elucidates fundamental concepts and demonstrates their plausibility and usefulness. Language is informal, examples are vivid and lively, and the perspectivie is fresh. Based on lectures delivered to engineering students, this work will also be valued by scientists, engineers, technicians, businessmen, anyone facing energy challenges of the future.

  11. Heat and thermodynamics

    CERN Document Server

    Saxena, A K

    2014-01-01

    Heat and thermodynamics aims to serve as a textbook for Physics, Chemistry and Engineering students. The book covers basic ideas of Heat and Thermodynamics, Kinetic Theory and Transport Phenomena, Real Gases, Liquafaction and Production and Measurement of very Low Temperatures, The First Law of Thermodynamics, The Second and Third Laws of Thermodynamics and Heat Engines and Black Body Radiation. KEY FEATURES Emphasis on concepts Contains 145 illustrations (drawings), 9 Tables and 48 solved examples At the end of chapter exercises and objective questions

  12. APOGEE Kinematics I: Overview of the Kinematics of the Galactic Bulge as Mapped by APOGEE

    CERN Document Server

    Ness, M; Johnson, J A; Athanassoula, E; Majewski, S R; Perez, A E Garcia; Bird, J; Nidever, D; Schneider, Donald P; Sobeck, J; Frinchaboy, P; Pan, Kaike; Bizyaev, Dmitry; Oravetz, Daniel; Simmons, Audrey

    2015-01-01

    We present the stellar kinematics across the Galactic bulge and into the disk at positive longitudes from the SDSS-III APOGEE spectroscopic survey of the Milky Way. APOGEE includes extensive coverage of the stellar populations of the bulge along the mid-plane and near-plane regions. From these data, we have produced kinematic maps of 10,000 stars across longitudes 0 deg -0.5 have dispersion and rotation profiles that are similar to that of N-body models of boxy/peanut bulges. There is a smooth kinematic transition from the thin bar and boxy bulge (l,|b|) -1.0, and the chemodynamics across (l,b) suggests the stars in the inner Galaxy with [Fe/H] > -1.0 have an origin in the disk.

  13. Abundance Ratios in the Galactic Bulge and Super Metal-Rich Type II Nucle osynthesis

    CERN Document Server

    Fulbright, J P; McWilliam, A; Fulbright, Jon P.; William, Andrew Mc

    2004-01-01

    We present abundance results from our Keck/HIRES observations of giants in the Galactic Bulge. We confirm that the metallicity distribution of giants in the low-reddening bulge field Baade's Window can be well-fit by a closed-box enrichment model. We also confirm previous observations that find enhanced [Mg/Fe], [Si/Fe] and [Ca/Fe] for all bulge giants, including those at super-solar metallicities. However, we find that the [O/Fe] ratios of metal-rich bulge dwarfs decrease with increasing metallicity, contrary to what is expected if the enhancements of the other $\\alpha$-elements is due to Type II supernovae enrichment. We suggest that the decrease in oxygen production may be due to mass loss in the pre-supernova evolution of metal-rich progenitors.

  14. Before the Bar: Kinematic Detection of A Spheroidal Metal-Poor Bulge Component

    CERN Document Server

    Kunder, Andrea; Storm, J; Nataf, D M; De Propris, R; Walker, A R; Bono, G; Johnson, C I; Shen, J; Li, Z Y

    2016-01-01

    We present 947 radial velocities of RR Lyrae variable stars in four fields located toward the Galactic bulge, observed within the data from the ongoing Bulge RR Lyrae Radial Velocity Assay (BRAVA-RR). We show that these RR Lyrae stars exhibit hot kinematics and null or negligible rotation and are therefore members of a separate population from the bar/pseudobulge that currently dominates the mass and luminosity of the inner Galaxy. Our RR Lyrae stars predate these structures, and have metallicities, kinematics, and spatial distribution that are consistent with a "classical" bulge, although we cannot yet completely rule out the possibility that they are the metal-poor tail of a more metal rich ([Fe/H] ~ -1 dex) halo-bulge population. The complete catalog of radial velocities for the BRAVA-RR stars is also published electronically.

  15. Theoretical Modeling of Thermodynamic and Mechanical Properties of the Pure Components of Ti and Zr Based Alloys Using the Exact Muffin-Tin Orbitals Method

    OpenAIRE

    Abrikosov, Igor; Nikonov, A. Yu; Ponomareva, A. V.; Dmitriev, A. I.; Barannikova, S. A.

    2014-01-01

    The exact muffin-tin orbitals (EMTO) method belongs to the third and latest generation of first-principles methods of calculating the electronic structure of materials in the so-called approximation of muffin-tin (MT) orbitals within the framework of the density functional theory. A study has been performed of its applicability for modeling the thermodynamic and mechanical properties of the pure components of Ti and Zr based alloys. The total energies of Ti, Zr, Nb, V, Mo, and Al are calculat...

  16. DBCreate: A SUPCRT92-based program for producing EQ3/6, TOUGHREACT, and GWB thermodynamic databases at user-defined T and P

    Science.gov (United States)

    Kong, Xiang-Zhao; Tutolo, Benjamin M.; Saar, Martin O.

    2013-02-01

    SUPCRT92 is a widely used software package for calculating the standard thermodynamic properties of minerals, gases, aqueous species, and reactions. However, it is labor-intensive and error-prone to use it directly to produce databases for geochemical modeling programs such as EQ3/6, the Geochemist's Workbench, and TOUGHREACT. DBCreate is a SUPCRT92-based software program written in FORTRAN90/95 and was developed in order to produce the required databases for these programs in a rapid and convenient way. This paper describes the overall structure of the program and provides detailed usage instructions.

  17. Star Clusters in Pseudo-Bulges of Spiral Galaxies

    CERN Document Server

    Di Nino, Daiana; Stiavelli, Massimo; Carollo, C Marcella; Scarlata, Claudia; Wyse, Rosemary F G

    2009-01-01

    We present a study of the properties of the star-cluster systems around pseudo-bulges of late-type spiral galaxies using a sample of 11 galaxies with distances from 17 to 37 Mpc. Star clusters are identified from multiband HST ACS and WFPC2 imaging data by combining detections in 3 bands (F435W and F814W with ACS and F606W with WFPC2). The photometric data are then compared to population synthesis models to infer the masses and ages of the star clusters. Photometric errors and completeness are estimated by means of artificial source Monte Carlo simulations. Dust extinction is estimated by considering F160W NICMOS observations of the central regions of the galaxies, augmenting our wavelength coverage. In all galaxies we identify star clusters with a wide range of ages, from young (age 100-250 Myr), more massive, red clusters. Some of the latter might likely evolve into objects similar to the Milky Way's globular clusters. We compute the specific frequencies for the older clusters with respect to the galaxy an...

  18. Stellar populations in the bulges of isolated galaxies

    CERN Document Server

    Morelli, L; Corsini, E M; Costantin, L; Bontà, E Dalla; Mèndez-Abreu, J; Pizzella, A

    2016-01-01

    We present photometry and long-slit spectroscopy for 12 S0 and spiral galaxies selected from the Catalogue of Isolated Galaxies. The structural parameters of the sample galaxies are derived from the Sloan Digital Sky Survey i-band images by performing a two-dimensional photometric decomposition of the surface brightness distribution. This is assumed to be the sum of the contribution of a S\\`ersic bulge, an exponential disc, and a Ferrers bar characterized by elliptical and concentric isophotes with constant ellipticity and position angles. The rotation curves and velocity dispersion profiles of the stellar component are measured from the spectra obtained along the major axis of galaxies. The radial profiles of the H{\\beta}, Mg and Fe line-strength indices are derived too. Correlations between the central values of the Mg 2 and Fe line-strength indices and the velocity dispersion are found. The mean age, total metallicity and total {\\alpha}/Fe enhancement of the stellar population in the centre and at the radi...

  19. Elemental abundances in AGB stars and the formation of the Galactic bulge

    OpenAIRE

    Wood P.R.; Ryde N.; Lebzelter T.; Blommaert J.A.D.L.; Uttenthaler S.; Schultheis M.; Aringer B.

    2012-01-01

    We obtained high-resolution near-IR spectra of 45 AGB stars located in the Galactic bulge. The aim of the project is to determine key elemental abundances in these stars to help constrain the formation history of the bulge. A further aim is to link the photospheric abundances to the dust species found in the winds of the stars. Here we present a progress report of the analysis of the spectra.

  20. Mechanical Analysis of Dead Load Crown and Structure Parameter of Hydraulic Elastic Bulging Roll

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chang-cai; LI Wei-min; LIU Zhu-bai

    2003-01-01

    The dead load crown of hydraulic elastic bulging roll was discussed using the theory of elastically supported beam, and the dead load experiment was carried out. The theoretical calculation is consistent with the experimental result. The structure parameters for the thickness of roll sleeve, the length of the oil groove and the crown of roll were discussed. The fundamental principle of determining the parameters was put forward. The theoretical basis of the application of the hydraulic elastic bulging roll was established.

  1. Inverse Approach to Evaluate the Tubular Material Parameters Using the Bulging Test

    OpenAIRE

    Yulong Ge; Xiaoxing Li; Lihui Lang

    2015-01-01

    Tubular material parameters are required for both part manufactory process planning and finite element simulations. The bulging test is one of the most credible ways to detect the property parameters for tubular material. The inverse approach provides more effective access to the accurate material evaluation than with direct identifications. In this paper, a newly designed set of bulging test tools is introduced. An inverse procedure is adopted to determine the tubular material properties in ...

  2. A fluorescence approach to the unfolding thermodynamics of horseradish peroxidase based on heme degradation by hydrogen peroxide

    Science.gov (United States)

    Ke, Zhigang; Ma, Shanshan; Li, Lamei; Huang, Qing

    2016-07-01

    Horseradish peroxidase (HRP) is a classical heme-containing protein which has been applied in many fields. The prosthetic group heme in HRP, especially in unfolded state, can react with hydrogen peroxide (H2O2) to produce a fluorescent product with the maximum emission wavelength at 450 nm. Utilizing this emission band as a fluorescence probe, the unfolding process of HRP in urea can be assessed quantitatively, and the calculated thermodynamic parameters are consistent with those determined by circular dichroism (CD) at 222 nm and steady-state tryptophan (Trp) fluorescence methods.

  3. Modelling the steady state deformation stress under various deformation conditions using a single irreversible thermodynamics based formulation

    Energy Technology Data Exchange (ETDEWEB)

    Huang Mingxin, E-mail: mingxin.huang@arcelormittal.com [Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft (Netherlands); Rivera-Diaz-del-Castillo, Pedro E.J. [Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft (Netherlands); Bouaziz, Olivier [ArcelorMittal Research, Voie Romaine-BP30320, 57283 Maizieres-les-Metz Cedex (France); Zwaag, Sybrand van der [Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft (Netherlands)

    2009-07-15

    A new unified description for the steady state deformation stress in single and polycrystalline metals and for various deformation conditions is presented. The new formulation for dislocation controlled deformation stems from the field of irreversible thermodynamics. The model applies to conditions of dynamic recovery as well as dynamic recrystallization and has been validated for constant strain rate and creep loading conditions. Unlike existing approaches, the new model captures transitions between deformation mechanisms within a single formulation. For conditions of dynamic recrystallization, the average dislocation density is found to be a function of the shear strain rate and a term combining the dislocation climb velocity and the grain boundary velocity.

  4. The Chemical Composition of the Galactic Bulge and Implications for its Evolution

    CERN Document Server

    McWilliam, Andrew

    2016-01-01

    The average bulge [Fe/H] and [Mg/H] are +0.06 and +0.17 dex, respectively, in Baade's Window, roughly 0.2 dex higher than the thin disk and ~0.7 dex higher than the local thick disk metallicity. This suggests a higher effective yield in the bulge, perhaps due to more efficient retention of supernova ejecta. The bulge vertical [Fe/H] gradient, at ~0.5 dex/kpc, appears to be due to a changing mixture of sub-populations (near +0.3 dex and -0.3 dex and one possibly near -0.7 dex) with latitude. The bulge is enhanced in O, Mg, Si, Ca, Ti, and Al relative to the sun, with [alpha/Fe]=+0.15 dex at [Fe/H]=0.0 dex. Below [Fe/H]~-0.5 dex, the bulge and local thick disk compositions are very similar, but small [Mg/Fe] and possibly [/Fe] enhancements, low [La/Eu] ratios and large [Cu/Fe], relative to the thick disk suggest slightly higher SFR in the bulge. However, these composition differences could simply be due to measurement errors and non-LTE effects. Unfortunately, comparison with the thick disk near solar [Fe/H] su...

  5. THE NUMBER OF TIDAL DWARF SATELLITE GALAXIES IN DEPENDENCE OF BULGE INDEX

    Energy Technology Data Exchange (ETDEWEB)

    López-Corredoira, Martín [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain); Kroupa, Pavel, E-mail: martinlc@iac.es, E-mail: pavel@astro.uni-bonn.de [Helmholtz-Institut für Strahlen- und Kernphysik, Universität Bonn, Nussallee 14-16, D-53115 Bonn (Germany)

    2016-01-20

    We show that a significant correlation (up to 5σ) emerges between the bulge index, defined to be larger for a larger bulge/disk ratio, in spiral galaxies with similar luminosities in the Galaxy Zoo 2 of the Sloan Digital Sky Survey and the number of tidal-dwarf galaxies in the catalog by Kaviraj et al. In the standard cold or warm dark matter cosmological models, the number of satellite galaxies correlates with the circular velocity of the dark matter host halo. In generalized gravity models without cold or warm dark matter, such a correlation does not exist, because host galaxies cannot capture infalling dwarf galaxies due to the absence of dark-matter-induced dynamical friction. However, in such models, a correlation is expected to exist between the bulge mass and the number of satellite galaxies because bulges and tidal-dwarf satellite galaxies form in encounters between host galaxies. This is not predicted by dark matter models in which bulge mass and the number of satellites are a priori uncorrelated because higher bulge/disk ratios do not imply higher dark/luminous ratios. Hence, our correlation reproduces the prediction of scenarios without dark matter, whereas an explanation is not found readily from the a priori predictions of the standard scenario with dark matter. Further research is needed to explore whether some application of the standard theory may explain this correlation.

  6. A new look at the kinematics of the bulge from an N-body model

    CERN Document Server

    Gomez, A; Stefanovitch, N; Haywood, M; Combes, F; Katz, D; Babusiaux, C

    2016-01-01

    (Abridged) By using an N-body simulation of a bulge that was formed via a bar instability mechanism, we analyse the imprints of the initial (i.e. before bar formation) location of stars on the bulge kinematics, in particular on the heliocentric radial velocity distribution of bulge stars. Four different latitudes were considered: $b=-4^\\circ$, $-6^\\circ$, $-8^\\circ$, and $-10^\\circ$, along the bulge minor axis as well as outside it, at $l=\\pm5^\\circ$ and $l=\\pm10^\\circ$. The bulge X-shaped structure comprises stars that formed in the disk at different locations. Stars formed in the outer disk, beyond the end of the bar, which are part of the boxy peanut-bulge structure may show peaks in the velocity distributions at positive and negative heliocentric radial velocities with high absolute values that can be larger than 100 $\\rm km$ $\\rm s^{-1}$, depending on the observed direction. In some cases the structure of the velocity field is more complex and several peaks are observed. Stars formed in the inner disk, t...

  7. Mergers and Bulge Formation in Lambda-CDM: Which Mergers Matter?

    CERN Document Server

    Hopkins, Philip F; Croton, Darren; Hernquist, Lars; Keres, Dusan; Khochfar, Sadegh; Stewart, Kyle; Wetzel, Andrew; Younger, Joshua D

    2009-01-01

    We use a suite of semi-empirical models to predict galaxy merger rates and contributions to bulge growth as functions of merger mass, redshift, and mass ratio. The models use empirical halo occupation constraints to identify mergers, together with high-resolution simulations to quantify how mergers with different properties contribute to the bulge population. We find good agreement with a variety of observational constraints, and provide fitting functions for merger rates and contributions to bulge growth. We identify several robust conclusions. (1) Major mergers dominate formation and assembly of L* bulges and the spheroid mass density, minor mergers contribute ~30%. (2) This is mass-dependent: bulge formation is dominated by more minor mergers in lower-mass systems. At higher masses, bulges form in major mergers near L*, but subsequently assemble in minor mergers. (3) The minor/major contribution is also morphology-dependent: higher B/T systems form in more major mergers, lower B/T systems form in situ from...

  8. The EMBLA Survey -- Metal-poor stars in the Galactic bulge

    CERN Document Server

    Howes, Louise M; Keller, Stefan C; Casey, Andrew R; Yong, David; Lind, Karin; Frebel, Anna; Hays, Austin; Alves-Brito, Alan; Bessell, Michael S; Casagrande, Luca; Marino, Anna F; Nataf, David M; Owen, Christopher I; Da Costa, Gary S; Schmidt, Brian P; Tisserand, Patrick

    2016-01-01

    Cosmological models predict the oldest stars in the Galaxy should be found closest to the centre of the potential well, in the bulge. The EMBLA Survey successfully searched for these old, metal-poor stars by making use of the distinctive SkyMapper photometric filters to discover candidate metal-poor stars in the bulge. Their metal-poor nature was then confirmed using the AAOmega spectrograph on the AAT. Here we present an abundance analysis of 10 bulge stars with -2.8<[Fe/H]<-1.7 from MIKE/Magellan observations, in total determining the abundances of 22 elements. Combining these results with our previous high-resolution data taken as part of the Gaia-ESO Survey, we have started to put together a picture of the chemical and kinematic nature of the most metal-poor stars in the bulge. The currently available kinematic data is consistent with the stars belonging to the bulge, although more accurate measurements are needed to constrain the stars' orbits. The chemistry of these bulge stars deviates from that ...

  9. The Number of Tidal Dwarf Satellite Galaxies in Dependence of Bulge Index

    Science.gov (United States)

    López-Corredoira, Martín; Kroupa, Pavel

    2016-01-01

    We show that a significant correlation (up to 5σ) emerges between the bulge index, defined to be larger for a larger bulge/disk ratio, in spiral galaxies with similar luminosities in the Galaxy Zoo 2 of the Sloan Digital Sky Survey and the number of tidal-dwarf galaxies in the catalog by Kaviraj et al. In the standard cold or warm dark matter cosmological models, the number of satellite galaxies correlates with the circular velocity of the dark matter host halo. In generalized gravity models without cold or warm dark matter, such a correlation does not exist, because host galaxies cannot capture infalling dwarf galaxies due to the absence of dark-matter-induced dynamical friction. However, in such models, a correlation is expected to exist between the bulge mass and the number of satellite galaxies because bulges and tidal-dwarf satellite galaxies form in encounters between host galaxies. This is not predicted by dark matter models in which bulge mass and the number of satellites are a priori uncorrelated because higher bulge/disk ratios do not imply higher dark/luminous ratios. Hence, our correlation reproduces the prediction of scenarios without dark matter, whereas an explanation is not found readily from the a priori predictions of the standard scenario with dark matter. Further research is needed to explore whether some application of the standard theory may explain this correlation.

  10. A high-velocity bulge RR Lyrae variable on a halo-like orbit

    CERN Document Server

    Kunder, Andrea; Hawkins, Keith; Poleski, Radek; Storm, Jesper; Johnson, Christian I; Shen, Juntai; Li, Zhao-Yu; Cordero, Maria Jose; Nataf, David M; Bono, Giuseppe; Walker, Alistair R; Koch, Andreas; De Propris, Roberto; Udalski, Andrzej; Szymanski, Michal K; Soszynski, Igor; Pietrzynski, Grzegorz; Ulaczyk, Krzysztof; Wyrzykowski, Lukasz; Pietrukowicz, Pawel; Skowron, Jan; Kozlowski, Szymon; Mroz, Przemyslaw

    2015-01-01

    We report on the RR Lyrae variable star, MACHO 176.18833.411, located toward the Galactic bulge and observed within the data from the ongoing Bulge RR Lyrae Radial Velocity Assay (BRAVA-RR), which has the unusual radial velocity of -372 +- 8 km/s and true space velocity of -482 +- 22 km/s relative to the Galactic rest frame. Located less than 1 kpc from the Galactic center and toward a field at (l,b)=(3,-2.5), this pulsating star has properties suggesting it belongs to the bulge RR Lyrae star population yet a velocity indicating it is abnormal, at least with respect to bulge giants and red clump stars. We show that this star is most likely a halo interloper and therefore suggest that halo contamination is not insignificant when studying metal-poor stars found within the bulge area, even for stars within 1 kpc of the Galactic center. We discuss the possibility that MACHO 176.18833.411 is on the extreme edge of the bulge RR Lyrae radial velocity distribution, and also consider a more exotic scenario in which it...

  11. The origin of the split red clump in the Galactic bulge of the Milky Way

    CERN Document Server

    Ness, M; Athanassoula, E; Wylie-de-Boer, E; Bland-Hawthorn, J; Lewis, G F; Yong, D; Asplund, M; Lane, R R; Kiss, L L; Ibata, R

    2012-01-01

    Near the minor axis of the Galactic bulge, at latitudes b -0.5 in the two higher-latitude fields, but not in the field at b = -5 degrees. Stars with [Fe/H] < -0.5 do not show the split. We compare the spatial distribution and kinematics of the clump stars with predictions from an evolutionary N-body model of a bulge that grew from a disk via bar-related instabilities. The density distribution of the peanut-shaped model is depressed near its minor axis. This produces a bimodal distribution of stars along the line of sight through the bulge near its minor axis, very much as seen in our observations. The observed and modelled kinematics of the two groups of stars are also similar. We conclude that the split red clump of the bulge is probably a generic feature of boxy/peanut bulges that grew from disks, and that the disk from which the bulge grew had relatively few stars with [Fe/H] < -0.5

  12. A HIGH-VELOCITY BULGE RR LYRAE VARIABLE ON A HALO-LIKE ORBIT

    Energy Technology Data Exchange (ETDEWEB)

    Kunder, Andrea; Storm, J. [Leibniz-Institut für Astrophysik Potsdam (AIP), An der Sternwarte 16, D-14482 Potsdam (Germany); Rich, R. M. [Department of Physics and Astronomy, University of California at Los Angeles, Los Angeles, CA 90095-1562 (United States); Hawkins, K. [Institute of Astronomy, Madingley Road, Cambridge CB3 0HA (United Kingdom); Poleski, R. [Department of Astronomy, Ohio State University, 140 W. 18th Avenue, Columbus, OH 43210 (United States); Johnson, C. I. [Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02138 (United States); Shen, J.; Li, Z.-Y. [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, 80 Nandan Road, Shanghai 200030 (China); Cordero, M. J. [Astronomisches Rechen-Institut: Zentrum für Astronomie, Mönchhofstr. 12-14, D-69120 Heidelberg (Germany); Nataf, D. M. [Research School of Astronomy and Astrophysics, The Australian National University, Canberra, ACT 2611 (Australia); Bono, G. [Dipartimento di Fisica, Universita di Roma Tor Vergata, Via della Ricerca Scientifica 1, I-00133 Roma (Italy); Walker, A. R. [Cerro Tololo Inter-American Observatory, National Optical Astronomy Observatory, Casilla 603, La Serena (Chile); Koch, A. [Landessternwarte, Zentrum für Astronomie der Universität Heidelberg, Königstuhl 12, D-69117 Heidelberg (Germany); De Propris, R. [Finnish Centre for Astronomy with ESO (FINCA), University of Turku, Turku (Finland); Udalski, A.; Szymanski, M. K.; Soszynski, I.; Pietrzynski, G.; Ulaczyk, K.; Wyrzykowski, Ł. [Warsaw University Observatory, Al. Ujazdowskie 4, 00-478 Warszawa (Poland); and others

    2015-07-20

    We report on the RR Lyrae variable star, MACHO 176.18833.411, located toward the Galactic bulge and observed within the data from the ongoing Bulge RR Lyrae Radial Velocity Assay, which has the unusual radial velocity of −372 ± 8 km s{sup −1} and true space velocity of −482 ± 22 km s{sup −1} relative to the Galactic rest frame. Located less than 1 kpc from the Galactic center and toward a field at (l, b) = (3, −2.5), this pulsating star has properties suggesting it belongs to the bulge RR Lyrae star population, yet a velocity indicating it is abnormal, at least with respect to bulge giants and red clump stars. We show that this star is most likely a halo interloper and therefore suggest that halo contamination is not insignificant when studying metal-poor stars found within the bulge area, even for stars within 1 kpc of the Galactic center. We discuss the possibility that MACHO 176.18833.411 is on the extreme edge of the bulge RR Lyrae radial velocity distribution, and also consider a more exotic scenario in which it is a runaway star moving through the Galaxy.

  13. Thermodynamics for dummies

    CERN Document Server

    Pauken, Mike

    2011-01-01

    Take some heat off the complexity of thermodynamics Does the mere thought of thermodynamics make you sweat? It doesn't have to! This hands-on guide helps you score your highest in a thermodynamics course by offering easily understood, plain-English explanations of how energy is used in things like automobiles, airplanes, air conditioners, and electric power plants. Thermodynamics 101 - take a look at some examples of both natural and man-made thermodynamic systems and get a handle on how energy can be used to perform work Turn up the heat - discover how to use the firs

  14. Introduction to applied thermodynamics

    CERN Document Server

    Helsdon, R M; Walker, G E

    1965-01-01

    Introduction to Applied Thermodynamics is an introductory text on applied thermodynamics and covers topics ranging from energy and temperature to reversibility and entropy, the first and second laws of thermodynamics, and the properties of ideal gases. Standard air cycles and the thermodynamic properties of pure substances are also discussed, together with gas compressors, combustion, and psychrometry. This volume is comprised of 16 chapters and begins with an overview of the concept of energy as well as the macroscopic and molecular approaches to thermodynamics. The following chapters focus o

  15. Twenty lectures on thermodynamics

    CERN Document Server

    Buchdahl, H A

    2013-01-01

    Twenty Lectures on Thermodynamics is a course of lectures, parts of which the author has given various times over the last few years. The book gives the readers a bird's eye view of phenomenological and statistical thermodynamics. The book covers many areas in thermodynamics such as states and transition; adiabatic isolation; irreversibility; the first, second, third and Zeroth laws of thermodynamics; entropy and entropy law; the idea of the application of thermodynamics; pseudo-states; the quantum-static al canonical and grand canonical ensembles; and semi-classical gaseous systems. The text

  16. Teaching Thermodynamics of Ideal Solutions: An Entropy-Based Approach to Help Students Better Understand and Appreciate the Subtleties of Solution Models

    Science.gov (United States)

    Tomba, J. Pablo

    2015-01-01

    The thermodynamic formalism of ideal solutions is developed in most of the textbooks postulating a form for the chemical potential of a generic component, which is adapted from the thermodynamics of ideal gas mixtures. From this basis, the rest of useful thermodynamic properties can be derived straightforwardly without further hypothesis. Although…

  17. Nonequilibrium thermodynamics in the strong coupling and non-Markovian regime based on a reaction coordinate mapping

    Science.gov (United States)

    Strasberg, Philipp; Schaller, Gernot; Lambert, Neill; Brandes, Tobias

    2016-07-01

    We propose a method to study the thermodynamic behaviour of small systems beyond the weak coupling and Markovian approximation, which is different in spirit from conventional approaches. The idea is to redefine the system and environment such that the effective, redefined system is again coupled weakly to Markovian residual baths and thus, allows to derive a consistent thermodynamic framework for this new system-environment partition. To achieve this goal we make use of the reaction coordinate (RC) mapping, which is a general method in the sense that it can be applied to an arbitrary (quantum or classical and even time-dependent) system coupled linearly to an arbitrary number of harmonic oscillator reservoirs. The core of the method relies on an appropriate identification of a part of the environment (the RC), which is subsequently included as a part of the system. We demonstrate the power of this concept by showing that non-Markovian effects can significantly enhance the steady state efficiency of a three-level-maser heat engine, even in the regime of weak system-bath coupling. Furthermore, we show for a single electron transistor coupled to vibrations that our method allows one to justify master equations derived in a polaron transformed reference frame.

  18. Rational extended thermodynamics

    CERN Document Server

    Müller, Ingo

    1998-01-01

    Ordinary thermodynamics provides reliable results when the thermodynamic fields are smooth, in the sense that there are no steep gradients and no rapid changes. In fluids and gases this is the domain of the equations of Navier-Stokes and Fourier. Extended thermodynamics becomes relevant for rapidly varying and strongly inhomogeneous processes. Thus the propagation of high­ frequency waves, and the shape of shock waves, and the regression of small-scale fluctuation are governed by extended thermodynamics. The field equations of ordinary thermodynamics are parabolic while extended thermodynamics is governed by hyperbolic systems. The main ingredients of extended thermodynamics are • field equations of balance type, • constitutive quantities depending on the present local state and • entropy as a concave function of the state variables. This set of assumptions leads to first order quasi-linear symmetric hyperbolic systems of field equations; it guarantees the well-posedness of initial value problems and f...

  19. Thermodynamics of the hot BIon

    DEFF Research Database (Denmark)

    Grignani, Gianluca; Harmark, Troels; Marini, Andrea;

    2011-01-01

    We investigate the thermodynamics of the recently obtained nite temperature BIon solution of arXiv:1012.1494, focusing on two aspects. The first concerns comparison of the free energy of the three available phases for the finite temperature brane-antibrane wormhole configuration. Based on this we...... is the possibility of constructing a finite temperature generalization of the infinite spike configuration of the extremal BIon. To this end we identify a correspondence point at the end of the throat where the thermodynamics of the D3-F1 blackfold configuration can be matched to that of k non-extremal black...

  20. A simple conductometric method for trace level determination of brilliant green in water based on β-cyclodextrin and silver nitrate and determination of their thermodynamic parameters

    Directory of Open Access Journals (Sweden)

    Roya Mohammad Zadeh Kakhki

    2014-12-01

    Full Text Available A gravimetric and complexometric titration method based on conductometric technique is presented for the quantitative determination of brilliant green (BG in water. The equilibrium constants and the thermodynamic parameters for the complex formation of β-cyclodextrin (β-CD with brilliant green (BG and precipitation of silver nitrate with BG have been determined by conductivity measurements in water. The results suggest that stable 1:1 complex is formed between BG and β-cyclodextrin and the thermodynamic parameters (ΔHc°,ΔSc° for this complexation reaction have been determined from temperature dependence of the stability constant using the van’t Hoff plots. Based on the obtained results, the conductometric method for the determination of BG in the presence of β-CD at 25 °C was developed in the range of 10−8–10−3 molL−1 and with AgNO3 is 10−3–10−5 molL−1.

  1. The age of the young bulge-like population in the stellar system Terzan5: linking the Galactic bulge to the high-z Universe

    CERN Document Server

    Ferraro, F R; Dalessandro, E; Lanzoni, B; Origlia, L; Rich, R M; Mucciarelli, A; -,

    2016-01-01

    The Galactic bulge is dominated by an old, metal rich stellar population. The possible presence and the amount of a young (a few Gyr old) minor component is one of the major issues debated in the literature. Recently, the bulge stellar system Terzan 5 was found to harbor three sub-populations with iron content varying by more than one order of magnitude (from 0.2 up to 2 times the solar value), with chemical abundance patterns strikingly similar to those observed in bulge field stars. Here we report on the detection of two distinct main sequence turn-off points in Terzan 5, providing the age of the two main stellar populations: 12 Gyr for the (dominant) sub-solar component and 4.5 Gyr for the component at super-solar metallicity. This discovery classifies Terzan 5 as a site in the Galactic bulge where multiple bursts of star formation occurred, thus suggesting a quite massive progenitor possibly resembling the giant clumps observed in star forming galaxies at high redshifts. This connection opens a new route ...

  2. Thermodynamics of Error Correction

    Science.gov (United States)

    Sartori, Pablo; Pigolotti, Simone

    2015-10-01

    Information processing at the molecular scale is limited by thermal fluctuations. This can cause undesired consequences in copying information since thermal noise can lead to errors that can compromise the functionality of the copy. For example, a high error rate during DNA duplication can lead to cell death. Given the importance of accurate copying at the molecular scale, it is fundamental to understand its thermodynamic features. In this paper, we derive a universal expression for the copy error as a function of entropy production and work dissipated by the system during wrong incorporations. Its derivation is based on the second law of thermodynamics; hence, its validity is independent of the details of the molecular machinery, be it any polymerase or artificial copying device. Using this expression, we find that information can be copied in three different regimes. In two of them, work is dissipated to either increase or decrease the error. In the third regime, the protocol extracts work while correcting errors, reminiscent of a Maxwell demon. As a case study, we apply our framework to study a copy protocol assisted by kinetic proofreading, and show that it can operate in any of these three regimes. We finally show that, for any effective proofreading scheme, error reduction is limited by the chemical driving of the proofreading reaction.

  3. Influence of roll misalignment on bulging of continuous casting slab%辊子错位对铸坯鼓肚变形的影响

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    Due to eccentricity of rolls,installation error of rolls,bending and wearing of rolls,the rolls deviate from the designed positions,causing roll misalignment,which exerts significant influences on the bulging of continuous casting slab. Based on the elasto-viscoplastic behavior of steel at an elevated temperature,a mathematical model of dynamic bulging with the movement of the slab between two roll pitches was developed. Then according to the model,the bulg-ing profiles of the slab on a pilot caster were computed. And in order to check the validity of this mathematical model, the calculated bulging profiles were compared with the measurements on a pilot caster. Then the bulging profiles of the slab combined with roll misalignments on the different segments of an industrial caster designed by VAI were computed according to the equipment and process parameters. The influences of roll pitches on the maximum strain at the solidify-ing front with specified roll alignment tolerances were discussed,and then an optimization method of roll pitches was presented.%由于加工、安装、变形与磨损等原因,连铸机辊列中的辊子会偏离设计位置而产生错位,这对铸坯鼓肚变形产生较大影响.基于高温铸坯黏弹塑性本构方程,建立两辊间距内的铸坯坯壳动态鼓肚数学模型,并利用模型计算试验铸机的铸坯坯壳鼓肚曲线,依照实测数据验证了模型的有效性.根据奥钢联工业连铸机的设备及工艺参数,计算铸机不同扇形段内铸坯坯壳在不同辊子错位量情况下的鼓肚变形,并讨论在辊子发生错位的情况下辊间距对铸坯坯壳固液交界面处最大应变的影响,并给出铸机辊间距的确定方法.

  4. Resonant Orbits and the High Velocity Peaks toward the Bulge

    Science.gov (United States)

    Molloy, Matthew; Smith, Martin C.; Evans, N. Wyn; Shen, Juntai

    2015-10-01

    We extract the resonant orbits from an N-body bar that is a good representation of the Milky Way, using the method recently introduced by Molloy et al. By decomposing the bar into its constituent orbit families, we show that they are intimately connected to the boxy-peanut shape of the density. We highlight the imprint due solely to resonant orbits on the kinematic landscape toward the Galactic center. The resonant orbits are shown to have distinct kinematic features and may be used to explain the cold velocity peak seen in the Apache Point Observatory Galactic Evolution Experiment commissioning data. We show that high velocity peaks are a natural consequence of the motions of stars in the 2:1 orbit family and that stars on other higher order resonances can contribute to the peaks. The locations of the peaks vary with bar angle and, with the tacit assumption that the observed peaks are due to the 2:1 family, we find that the locations of the high velocity peaks correspond to bar angles in the range {10}\\circ ≲ {θ }{bar}≲ 25^\\circ . However, some important questions about the nature of the peaks remain, such as their apparent absence in other surveys of the Bulge and the deviations from symmetry between equivalent fields in the north and south. We show that the absence of a peak in surveys at higher latitudes is likely due to the combination of a less prominent peak and a lower number density of bar supporting orbits at these latitudes.

  5. QSPR models based on molecular mechanics and quantum chemical calculations. 2. Thermodynamic properties of alkanes, alcohols, polyols, and ethers

    DEFF Research Database (Denmark)

    Dyekjær, Jane Dannow; Jonsdottir, Svava Osk

    2003-01-01

    Quantitative Structure-Property Relationship (QSPR) models for prediction of various thermodynamic properties of simple organic compounds have been developed. A number of new descriptors are proposed and used alongside with descriptors available within the Codessa program. An important feature...... in this work has been to include the most probable molecular conformers in the model development and thus account for the conformational flexibility of the molecules. The models cover the properties boiling points, melting points, enthalpies of vaporization, enthalpies of fusion, and liquid densities...... for alkanes, alcohols, diols, ethers, and oxyalcohols, including cyclic alkanes and alcohols. Several good models, having good predictability, have been developed. To enhance the applicability of the QSPR models, simpler expressions for each descriptor have also been developed. This allows for the prediction...

  6. Effects of Microalloying on Glass Forming Ability and Thermodynamic Fragility of Cu-Pr-Based Amorphous Alloys

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The effects of microalloying of Ti and B on the glass formation of Cu60Pr30Ni10Al10-2xTixBx(x=0, 0.05%(atom fraction)) amorphous alloys was investigated using differential scanning calorimetry (DSC) and X-ray diffraction (XRD). XRD analysis showed that microalloying with 0.05% Ti and 0.05% B improved the glass forming ability (GFA). The smaller difference in the Gibbs free energy between the liquid and crystalline states at the glass transition temperature (ΔGl-x (Tg)) and the smaller thermodynamic fragility index (ΔSf/Tm, where ΔSf is the entropy of fusion, and Tm is the melting temperature) after microalloying correlated with the higher GFA.

  7. Supermassive black holes and their host galaxies. I. Bulge luminosities from dedicated near-infrared data

    Energy Technology Data Exchange (ETDEWEB)

    Läsker, Ronald; Van de Ven, Glenn [Max-Planck Institut für Astronomie, Königstuhl 17, D-69117, Heidelberg (Germany); Ferrarese, Laura, E-mail: laesker@mpia.de [NRC Herzberg Institute of Astrophysics, 5071 West Saanich Road, Victoria, BC V9E2E7 (Canada)

    2014-01-01

    In an effort to secure, refine, and supplement the relation between central supermassive black hole masses, M {sub •}, and the bulge luminosities of their host galaxies, L {sub bul}, we obtained deep, high spatial resolution K-band images of 35 nearby galaxies with securely measured M {sub •}, using the wide-field WIRCam imager at the Canada-France-Hawaii-Telescope. A dedicated data reduction and sky subtraction strategy was adopted to estimate the brightness and structure of the sky, a critical step when tracing the light distribution of extended objects in the near-infrared. From the final image product, bulge and total magnitudes were extracted via two-dimensional profile fitting. As a first order approximation, all galaxies were modeled using a simple Sérsic-bulge+exponential-disk decomposition. However, we found that such models did not adequately describe the structure that we observed in a large fraction of our sample galaxies which often include cores, bars, nuclei, inner disks, spiral arms, rings, and envelopes. In such cases, we adopted profile modifications and/or more complex models with additional components. The derived bulge magnitudes are very sensitive to the details and number of components used in the models, although total magnitudes remain almost unaffected. Usually, but not always, the luminosities and sizes of the bulges are overestimated when a simple bulge+disk decomposition is adopted in lieu of a more complex model. Furthermore, we found that some spheroids are not well fit when the ellipticity of the Sérsic model is held fixed. This paper presents the details of the image processing and analysis, while we discuss how model-induced biases and systematics in bulge magnitudes impact the M {sub •}-L {sub bul} relation in a companion paper.

  8. Thermodynamic and Kinetic Aspects Involved in the Development of Nanocarriers and Drug Delivery Systems Based on Cationic Biopolymers.

    Science.gov (United States)

    Bianco, Ismael D; Alasino, Roxana V; Leonhard, Victoria; Beltramo, Dante M

    2016-01-01

    During the last years we have seen an increasing number of reports describing new properties and potential applications of cationic polymers and derived nanostructures. This review gives a summary of their applications in drug delivery, the preparation methods for nano and microstructures and will attempt to give a glimpse on how their structure, chemical composition and properties may be affected or modulated as to make them suitable for an intended application as drug delivery nanocarriers. The compositional complexity with the existence of several reacting groups makes cationic nanostructures critically sensitive to the contribution of thermodynamic and kinetic parameters in the determination of the type and stability of a particular structure and its ability to respond to changes in environmental conditions in the right time frame. Curiously, and contrarily to what could be expected, despite the fact that cationic polymers can form strong electrostatic interactions the contribution of the entropic component has been often found to be very important for their association with negatively charged supramolecular structures. Some general considerations indicate that when considering a complex multimolecular system like a nanocarrier containing an active ingredient it is frequently possible to find conditions under which enthalpic and entropic contributions are compensated leading to stable structures with a marginal thermodynamic stability (free energy change close to zero) which make them able to respond relatively fast to changes in the environmental conditions and therefore suitable for the design of smart drug delivery systems. Like with other nanocarriers, it should always be kept in mind that the properties of cationic nanocarriers will depend not only on their chemical composition but also on the properties of the structures formed by them.

  9. Study of the adsorption of Cd (II from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies

    Directory of Open Access Journals (Sweden)

    Hamedreza Javadian

    2015-11-01

    Full Text Available A specific type of zeolite, synthesized from coal fly ash, was used in our batch adsorption experiments in order to adsorb Cd (II ions from aqueous solution. Solid-state conversion of fly ash to an amorphous aluminosilicate adsorbent (geopolymer was investigated under specific conditions. The adsorbent ZFA was characterized using XRD, XRF, FT-IR, FE-SEM, LPS and BET surface area. The optimum conditions of sorption were found to be: a ZFA dose of 0.08 g in 25 mL of Cd (II with contact time of 7 h and pH 5. Four equations, namely Morris–Weber, Lagergren, Pseudo-second order and Elovich have been used in order to determine the kinetics of removal process. The collected kinetic data showed that pseudo-second order equations controlled the adsorption process. According to adsorption isotherm studies, the Langmuir isotherm was proved to be the best fit for our experimental data, in comparison to Freundlich, D–R and Tempkin models. The thermodynamic parameters ΔH, ΔS and ΔG are evaluated. Thermodynamic parameters showed that the adsorption of Cd (II onto ZFA was feasible, spontaneous and endothermic under studied conditions. To conduct desorption experiments, several solvents (including alkaline, bases and water have been employed. 84% of desorption efficiency was achieved using NaOH.

  10. Development of the high-temperature, solid-state, electromotive force technique to study the thermodynamics of Lewis-acid-base transition metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Bullard, G.L.

    1978-05-01

    The basic principles of the Engel-Brewer theory of metals are summarized and illustrated. Definitions of words used to describe its fundamentals are clarified. The theory predicts the extreme stability of the Lewis-acid-base alloys. The thermodynamics of such alloys may be obtained through the use of oxide-electrolyte, electrochemical cells. Experimental techniques associated with the use of these cells are explained in detail. Much attention is given to the preparation and processing of the materials required. A selective review of the cell literature demonstrates frequent difficulty in obtaining accurate thermodynamic data. In an attempt to correct this situation, as well as to correct problems discovered in this work, the physical processes which create the cell emf are clearly identified. The fundamental understanding afforded by the resulting cell model implies the procedures used to both discover and eliminate errors. Those due to concentration overpotentials, reactive impurities in the gas phase, and interfacial reactions are carefully analyzed. The procedures used to test for and attain equilibrium in an alloy-oxide, powder compact are supported through identification of the transport processes that mediate equilibration.

  11. Thermodynamic Analysis of Air Separation System Based on Exergy Balance%基于平衡的空分系统热力学分析

    Institute of Scientific and Technical Information of China (English)

    陈毕杨

    2015-01-01

    Based on the thermodynamics description and analysis methods of air separation ,the exergy balance of air sepa-ration system has established .While the evaluation of raw material and the products exergy obtained form , exergy change and exergy transfer , an unified benchmark was used in the balance relation to make thermodynamic analysis of the system , which provides a theoretical basis for the amortization of the cost of energy in actual production .%通过对空分系统的热力学描述和分析方法的比较,建立空分系统的平衡关系,通过统一基准,对系统进行热力学分析,得到系统原料及各产品的构成、变化和转移情况。为实际生产过程中能源成本的摊销提供了理论依据。

  12. An introduction to equilibrium thermodynamics

    CERN Document Server

    Morrill, Bernard; Hartnett, James P; Hughes, William F

    1973-01-01

    An Introduction to Equilibrium Thermodynamics discusses classical thermodynamics and irreversible thermodynamics. It introduces the laws of thermodynamics and the connection between statistical concepts and observable macroscopic properties of a thermodynamic system. Chapter 1 discusses the first law of thermodynamics while Chapters 2 through 4 deal with statistical concepts. The succeeding chapters describe the link between entropy and the reversible heat process concept of entropy; the second law of thermodynamics; Legendre transformations and Jacobian algebra. Finally, Chapter 10 provides a

  13. Drag with external and pressure drop with internal flows: a new and unifying look at losses in the flow field based on the second law of thermodynamics

    Science.gov (United States)

    Herwig, Heinz; Schmandt, Bastian

    2013-10-01

    Internal and external flows are characterized by friction factors and drag coefficients, respectively. Their definitions are based on pressure drop and drag force and thus are very different in character. From a thermodynamics point of view in both cases dissipation occurs which can uniformly be related to the entropy generation in the flow field. Therefore we suggest to account for losses in the flow field by friction factors and drag coefficients that are based on the overall entropy generation due to the dissipation in the internal and external flow fields. This second law analysis (SLA) has been applied to internal flows in many studies already. Examples of this flow category are given together with new cases of external flows, also treated by the general SLA-approach.

  14. Thermodynamics of radiation modes

    Energy Technology Data Exchange (ETDEWEB)

    Pina, Eduardo; De la Selva, Sara Maria Teresa [Departamento de Fisica, Universidad Autonoma Metropolitana - Iztapalapa, PO Box 55 534, Mexico, D F, 09340 (Mexico)], E-mail: pge@xanum.uam.mx, E-mail: tere@xanum.uam.mx

    2010-03-15

    We study the equilibrium thermodynamics of the electromagnetic radiation in a cavity of a given volume and temperature. We found three levels of description, the thermodynamics of one mode, the thermodynamics of the distribution of frequencies in a band by summing over the frequencies in it and the global thermodynamics by summing over all the frequencies. One equation relating frequency and volume is used to define the thermodynamics of one mode, and to explain the mystery of the frequency-dependent quantities having a similar behaviour to the non-frequency-dependent quantities for some thermodynamic equations and different behaviour for others. Besides, this frequency-volume relation is used to count the number of modes in a band of frequency.

  15. The third law of thermodynamics and the fractional entropies

    Science.gov (United States)

    Baris Bagci, G.

    2016-08-01

    We consider the fractal calculus based Ubriaco and Machado entropies and investigate whether they conform to the third law of thermodynamics. The Ubriaco entropy satisfies the third law of thermodynamics in the interval 0 thermodynamically stable. The Machado entropy, on the other hand, yields diverging inverse temperature in the region 0 law of thermodynamics. We also show that the aforementioned results are also supported by the one-dimensional Ising model with no external field.

  16. Thermodynamic Stability of Wormholes

    CERN Document Server

    Sajadi, S N

    2016-01-01

    In the context of GR, we study the thermodynamic stability of evolving Lorentzian wormholes at the apparent horizon. The average pressure of the anisotrropic components is considered as the pressure of the wormhole. According to the requirements of stable equilibrium in conventional thermodynamics, we calculate the heat capacity at constant pressure and Gibbs free energy and analyze the local and global thermodynamic stability of the wormhole.

  17. 多加强肋胀形可行性补充条件及有限元数值模拟%Feasibility supplementary criterion and finite element numerical simulation of bulging for multiple reinforcement ribs

    Institute of Scientific and Technical Information of China (English)

    管爱枝; 施于庆

    2013-01-01

    Multiple reinforcement ribs of metal shell parts should be made by one bulging procedure,while the current bulging feasibility criterion used for single reinforcement rib can not be directly used to determine whether multiple reinforcement ribs can be successfully bulged for the first time.After the regions between the positive reinforcement ribs were regarded as reverse reinforcement ribs,a feasibility supplementary criterion of bulging for multiple reinforcement ribs was proposed based on the supposition that the maximum bulging increment of reverse ribs should be smaller than that of positive ribs.Three kinds of metal shell parts were modeled,with single reinforcement rib,multiple ribs with small center distance and multiple ribs with large center distance,respectively.And the numerical simulation of the bulging process for those parts was carried out through ANSYS/LS-DYNA module based on finite element method.The validity of the feasibility supplementary criterion of bulging for multiple reinforcement ribs was verified by the results of thickness thinning rate distribution and forming limit diagram.The center distance between adjacent ribs is the key factor for determining the feasibility of once bulging.%金属板壳件的多加强肋需一次成形,而现有单加强肋胀形可行性条件不能直接用来判断多加强肋能否一次成功胀形.将多加强肋间区域视为反向加强肋,在其许用变形程度比正向加强肋小的前提下,提出了多加强肋胀形可行性的补充条件.建立了单加强肋、近距分布及远距分布多加强肋的3种板壳件模型,运用ANSYS/LS-DYNA完成了其胀形成形的有限元数值模拟.厚度减薄率和成形极限图的模拟结果验证了多加强肋胀形可行性补充条件的有效性.多加强肋之间的距离是决定其能否一次胀形成形的关键因素.

  18. A new look at the kinematics of the bulge from an N-body model

    Science.gov (United States)

    Gómez, A.; Di Matteo, P.; Stefanovitch, N.; Haywood, M.; Combes, F.; Katz, D.; Babusiaux, C.

    2016-05-01

    By using an N-body simulation of a bulge that was formed via a bar instability mechanism, we analyse the imprints of the initial (i.e. before bar formation) location of stars on the bulge kinematics, in particular on the heliocentric radial velocity distribution of bulge stars. Four different latitudes were considered: b = -4°, -6°, -8°, and -10°, along the bulge minor axis as well as outside it, at l = ± 5° and l = ± 10°. The bulge X-shaped structure comprises stars that formed in the disk at different locations. Stars formed in the outer disk, beyond the end of the bar, which are part of the boxy peanut-bulge structure may show peaks in the velocity distributions at positive and negative heliocentric radial velocities with high absolute values that can be larger than 100 km s-1, depending on the observed direction. In some cases the structure of the velocity field is more complex and several peaks are observed. Stars formed in the inner disk, the most numerous, contribute predominantly to the X-shaped structure and present different kinematic characteristics. They display a rather symmetric velocity distribution and a smaller fraction of high-velocity stars. The stellar stream motion, which is induced by the bar changes with the star initial position, can reach more than 40 km s-1 for stars that originated in the external disk, depending on the observed direction. Otherwise it is smaller than approximately 20 km s-1. In all cases, it decreases from b = -4° to -10°. Our results may enable us to interpret the cold high-velocity peak observed in the APOGEE commissioning data, as well as the excess of high-velocity stars in the near and far arms of the X-shaped structure at l = 0° and b = -6°. When compared with real data, the kinematic picture becomes more complex due to the possible presence in the observed samples of classical bulge and/or thick disk stars. Overall, our results point to the existence of complex patterns and structures in the bulge

  19. Methods of thermodynamics

    CERN Document Server

    Reiss, Howard

    1997-01-01

    Since there is no shortage of excellent general books on elementary thermodynamics, this book takes a different approach, focusing attention on the problem areas of understanding of concept and especially on the overwhelming but usually hidden role of ""constraints"" in thermodynamics, as well as on the lucid exposition of the significance, construction, and use (in the case of arbitrary systems) of the thermodynamic potential. It will be especially useful as an auxiliary text to be used along with any standard treatment.Unlike some texts, Methods of Thermodynamics does not use statistical m

  20. The visibility of the Galactic bulge in optical surveys. Application to the Gaia mission

    CERN Document Server

    Robin, A C; Picaud, Sylvain; Schultheis, M

    2004-01-01

    The bulge is a region of the Galaxy which is of tremendous interest for understanding Galaxy formation. However, measuring photometry and kinematics in it raises several inherent issues, like high extinction in the visible and severe crowding. Here we attempt to estimate the problem of the visibility of the bulge at optical wavelengths, where large CCD mosaics allow to easily cover wide regions from the ground, and where future astrometric missions are planned. Assuming the Besancon Galaxy model and high resolution extinction maps, we estimate the stellar density as a function of longitude, latitude and apparent magnitude and we deduce the possibility of reaching and measuring bulge stars. The method is applied to three Gaia instruments, the BBP and MBP photometers, and the RVS spectrograph. We conclude that, while in the BBP most of the bulge will be accessible, in the MBP there will be a small but significant number of regions where bulge stars will be detected and accurately measured in crowded fields. Ass...

  1. The number of tidal dwarf satellite galaxies in dependence of bulge index

    CERN Document Server

    Lopez-Corredoira, Martin

    2015-01-01

    We show that a significant correlation (up to 5sigma) emerges between the bulge index, defined to be larger for larger bulge/disk ratio, in spiral galaxies with similar luminosities in the Galaxy Zoo 2 of SDSS and the number of tidal-dwarf galaxies in the catalogue by Kaviraj et al. (2012). In the standard cold or warm dark-matter cosmological models the number of satellite galaxies correlates with the circular velocity of the dark matter host halo. In generalized-gravity models without cold or warm dark matter such a correlation does not exist, because host galaxies cannot capture in-falling dwarf galaxies due to the absence of dark-matter-induced dynamical friction. However, in such models a correlation is expected to exist between the bulge mass and the number of satellite galaxies, because bulges and tidal-dwarf satellite galaxies form in encounters between host galaxies. This is not predicted by dark matter models in which bulge mass and the number of satellites are a priori uncorrelated because higher b...

  2. Composite Stellar Populations and Element by Element Abundances in the Milky Way Bulge and Elliptical Galaxies

    CERN Document Server

    Tang, Baitian; Davis, A Bianca

    2014-01-01

    This paper explores the integrated-light characteristics of the Milky Way (MW) bulge and to what extent they match those of elliptical galaxies in the local universe. We model composite stellar populations with realistic abundance distribution functions (ADFs), tracking the trends of individual elements as a function of overall heavy element abundance as actually observed in MW bulge stars. The resultant predictions for absorption feature strengths from the MW bulge mimic elliptical galaxies better than solar neighborhood stars do, but the MW bulge does not match elliptical galaxies, either. Comparing bulge versus elliptical galaxies, Fe, Ti, and Mg trend about the same for both but C, Na, and Ca seem irreconcilably different. Exploring the behavior of abundance compositeness leads to the concepts of "red lean" where a narrower ADF appears more metal rich than a wide one, and "red spread" where the spectral difference between wide and narrow ADFs increases as the ADF peak is moved to more metal-rich values. T...

  3. Unifying the planar bar and the boxy bulge of the Milky Way

    Directory of Open Access Journals (Sweden)

    Martinez-Valpuesta I.

    2012-02-01

    Full Text Available For some time the Milky Way has been understood as a barred disk galaxy. Star count observations have provided evidence for two bars at apparently different orientations, the boxy bulge and a long planar bar. We report recent work in which we argued for a scenario where these observations can be reproduced with a single boxy bulge/bar: an evolved bar from the stellar disk and the corresponding boxy bulge generated from it through secular evolution and buckling instability. We calculated the star count distributions along different lines-of-sight for a simulated barred galaxy and an observer at the Sun position, and compared them with observations of red clump magnitude distributions. We found a good agreement between the model and the observations, even though the simulation has a single boxy bulge/bar. In this model, the different apparent orientations of the boxy bulge and planar bar are partially due to the volume effect and partially to the leading ends of the bar.

  4. Extremely metal-poor stars from the cosmic dawn in the bulge of the Milky Way.

    Science.gov (United States)

    Howes, L M; Casey, A R; Asplund, M; Keller, S C; Yong, D; Nataf, D M; Poleski, R; Lind, K; Kobayashi, C; Owen, C I; Ness, M; Bessell, M S; Da Costa, G S; Schmidt, B P; Tisserand, P; Udalski, A; Szymański, M K; Soszyński, I; Pietrzyński, G; Ulaczyk, K; Wyrzykowski, Ł; Pietrukowicz, P; Skowron, J; Kozłowski, S; Mróz, P

    2015-11-26

    The first stars are predicted to have formed within 200 million years after the Big Bang, initiating the cosmic dawn. A true first star has not yet been discovered, although stars with tiny amounts of elements heavier than helium ('metals') have been found in the outer regions ('halo') of the Milky Way. The first stars and their immediate successors should, however, preferentially be found today in the central regions ('bulges') of galaxies, because they formed in the largest over-densities that grew gravitationally with time. The Milky Way bulge underwent a rapid chemical enrichment during the first 1-2 billion years, leading to a dearth of early, metal-poor stars. Here we report observations of extremely metal-poor stars in the Milky Way bulge, including one star with an iron abundance about 10,000 times lower than the solar value without noticeable carbon enhancement. We confirm that most of the metal-poor bulge stars are on tight orbits around the Galactic Centre, rather than being halo stars passing through the bulge, as expected for stars formed at redshifts greater than 15. Their chemical compositions are in general similar to typical halo stars of the same metallicity although intriguing differences exist, including lower abundances of carbon.

  5. Clues to the Formation of Lenticular Galaxies Using Spectroscopic Bulge-Disk Decomposition

    CERN Document Server

    Johnston, Evelyn J; Merrifield, Michael R; Bedregal, Alejandro G

    2013-01-01

    Lenticular galaxies have long been thought of as evolved spirals, but the processes involved to quench the star formation are still unclear. By studying the individual star formation histories of the bulges and disks of lenticulars, it is possible to look for clues to the processes that triggered their transformation from spirals. To accomplish this feat, we present a new method for spectroscopic bulge-disk decomposition, in which a long-slit spectrum is decomposed into two one-dimensional spectra representing purely the bulge and disk light. We present preliminary results from applying this method to lenticular galaxies in the Virgo and Fornax Clusters, in which we show that the most recent star formation activity in these galaxies occurred within the bulges. We also find that the star formation timescales of the bulges are longer than the disks, and that more massive galaxies take longer to lose their gas during the transformation. These results point towards slow processes, such as ram-pressure stripping o...

  6. A case against an X-shaped structure in the Milky Way young bulge

    CERN Document Server

    Lopez-Corredoira, Martin

    2016-01-01

    CONTEXT. A number of recent papers have claimed the discovery of an X-shape structure in the bulge of our Galaxy in the population of the red clumps. AIMS. We endeavor to analyze the stellar density of bulge stars in the same regions using a different stellar population that is characteristic of the young bulge ($\\lesssim 5$ Gyr). Particularly, we use F0-F5 main-sequence stars with distances derived through photometric parallax. METHODS. We extract these stars from extinction-corrected color-magnitude diagrams in the near-infrared of VISTA-VVV data in some bulge regions and calculate the densities along the line of sight. We take the uncertaintity in the photometric parallax and the contamination of other sources into account, and we see that these errors do not avoid the detection of a possible double peak along some lines of sight as expected for a X-shape bulge if it existed. RESULTS. Only a single peak in the density distribution along the line of sight is observed, so apparently there is no X-shape struc...

  7. Structural properties of disk galaxies I. The intrinsic ellipticity of bulges

    CERN Document Server

    Mendez-Abreu, J; Corsini, E M; Simonneau, E

    2007-01-01

    (Abridged) A variety of formation scenarios was proposed to explain the diversity of properties observed in bulges. Studying their intrinsic shape can help in constraining the dominant mechanism at the epochs of their assembly. The structural parameters of a magnitude-limited sample of 148 unbarred S0--Sb galaxies were derived in order to study the correlations between bulges and disks as well as the probability distribution function (PDF) of the intrinsic equatorial ellipticity of bulges. It is presented a new fitting algorithm (GASP2D) to perform the two-dimensional photometric decomposition of galaxy surface-brightness distribution. This was assumed to be the sum of the contribution of a bulge and disk component characterized by elliptical and concentric isophotes with constant (but possibly different) ellipticity and position angles. Bulge and disk parameters of the sample galaxies were derived from the J-band images which were available in the Two Micron All Sky Survey. The PDF of the equatorial elliptic...

  8. Bulges and disks in the local Universe. Linking the galaxy structure to star formation activity

    CERN Document Server

    Morselli, L; Erfanianfar, G; Concas, A

    2016-01-01

    Galaxy morphology and star formation activity are strictly linked, in the way that bulge-dominated galaxies are in general quiescent, while disk dominated galaxies are actively star-forming. In this paper, we study the properties of bulges and disks as a function of the position of galaxies in the star formation rate (SFR) - stellar mass ($M_{\\star}$) plane. Our sample is built on the SDSS DR7 catalogue, and the bulge-disk decomposition is the one of Simard et al. (2011). We find that at a given stellar mass the Main Sequence (MS) is populated by galaxies with the lowest B/T ratios. The B/T on the MS increases with increasing stellar mass, thus confirming previous results in literature. In the upper envelop of the MS, the average B/T is higher than that of MS counterparts at fixed stellar mass. This indicates that starburst galaxies have a significant bulge component. In addition, bulges above the MS are characterised by blue colours, whereas, if on the MS or below it, they are mostly red and dead. The disks ...

  9. The Acceleration of the Nebular Shells in Planetary Nebulae in the Milky Way Bulge

    CERN Document Server

    Richer, Michael G; Pereyra, Margarita; Riesgo, Hortensia; Diaz, Maria Teresa Garcia; Baez, Sol-Haret

    2008-01-01

    We present a systematic study of line widths in the [\\ion{O}{3}]$\\lambda$5007 and H$\\alpha$ lines for a sample of 86 planetary nebulae in the Milky Way bulge based upon spectroscopy obtained at the \\facility{Observatorio Astron\\'omico Nacional in the Sierra San Pedro M\\'artir (OAN-SPM)} using the Manchester Echelle Spectrograph. The planetary nebulae were selected with the intention of simulating samples of bright extragalactic planetary nebulae. We separate the planetary nebulae into two samples containing cooler and hotter central stars, defined by the absence or presence, respectively, of the \\ion{He}{2} $\\lambda$6560 line in the H$\\alpha$ spectra. This division separates samples of younger and more evolved planetary nebulae. The sample of planetary nebulae with hotter central stars has systematically larger line widths, larger radii, lower electron densities, and lower H$\\beta$ luminosities. The distributions of these parameters in the two samples all differ at significance levels exceeding 99%. These dif...

  10. Precise Black Hole Masses From Megamaser Disks: Black Hole-Bulge Relations at Low Mass

    CERN Document Server

    Greene, J E; Kim, M; Kuo, C Y; Braatz, J A; Impellizzeri, C M V; Condon, J J; Lo, K Y; Henkel, C; Reid, M J

    2010-01-01

    The black hole (BH)-bulge correlations have greatly influenced the last decade of effort to understand galaxy evolution. Current knowledge of these correlations is limited predominantly to high BH masses (M_BH> 10^8 M_sun) that can be measured using direct stellar, gas, and maser kinematics. These objects, however, do not represent the demographics of more typical L< L* galaxies. This study transcends prior limitations to probe BHs that are an order of magnitude lower in mass, using BH mass measurements derived from the dynamics of H_2O megamasers in circumnuclear disks. The masers trace the Keplerian rotation of circumnuclear molecular disks starting at radii of a few tenths of a pc from the central BH. Modeling of the rotation curves, presented by Kuo et al. (2010), yields BH masses with exquisite precision. We present stellar velocity dispersion measurements for a sample of nine megamaser disk galaxies based on long-slit observations using the B&C spectrograph on the Dupont telescope and the DIS spe...

  11. New insight on the origin of the double red clump in the Milky Way bulge

    CERN Document Server

    Joo, Seok-Joo; Chung, Chul

    2016-01-01

    The double red clump (RC) observed in the Milky Way bulge is widely interpreted as evidence for an X-shaped structure. We have recently suggested, however, an alternative interpretation based on the multiple population phenomenon, where the bright RC is from helium enhanced second-generation stars (G2), while the faint RC is representing first-generation stars (G1) with normal helium abundance. Here our RC models are constructed in a large parameter space to see the effects of metallicity, age, and helium abundance on the double RC feature. Our models show that the luminosity of RC stars is mainly affected by helium abundance, while the RC color is primarily affected by metallicity. The effect of age is relatively small, unless it is older than 12 Gyr or much younger than 6 Gyr. The observed double RC feature can therefore be reproduced in a relatively large parameter space, once {\\Delta}Y between G2 and G1 is assumed to be greater than $\\sim$0.10. We further show that the longitude dependence of the double R...

  12. High resolution spectroscopic analysis of seven giants in the bulge globular cluster NGC 6723

    CERN Document Server

    Rojas-Arriagada, A; Vásquez, S; Ripepi, V; Musella, I; Marconi, M; Grado, A; Limatola, L

    2016-01-01

    Globular clusters associated with the Galactic bulge are important tracers of stellar populations in the inner Galaxy. High resolution analysis of stars in these clusters allows us to characterize them in terms of kinematics, metallicity, and individual abundances, and to compare these fingerprints with those characterizing field populations. We present iron and element ratios for seven red giant stars in the globular cluster NGC~6723, based on high resolution spectroscopy. High resolution spectra ($R\\sim48~000$) of seven K giants belonging to NGC 6723 were obtained with the FEROS spectrograph at the MPG/ESO 2.2m telescope. Photospheric parameters were derived from $\\sim130$ FeI and FeII transitions. Abundance ratios were obtained from line-to-line spectrum synthesis calculations on clean selected features. An intermediate metallicity of [Fe/H]$=-0.98\\pm0.08$ dex and a heliocentric radial velocity of $v_{hel}=-96.6\\pm1.3~km s^{-1}$ were found for NGC 6723. Alpha-element abundances present enhancements of $[O/...

  13. Extension of Tycho catalog for low-extinction windows in the galactic bulge

    CERN Document Server

    Dominici, T P; Horváth, J E; Medina-Tanco, G A; Benevides-Soares, P

    1999-01-01

    We present in this work secondary catalogs up to $m_{Val} \\sim 13$ based on the Tycho reference frame (ESA, 1997) for 12 selected low-extinction fields towards the galactic bulge. The observations have been performed with the Askania-Zeiss Meridian Circle equiped with a CCD camera, located at the Abrahão de Moraes Observatory (Valinhos, Brazil) and operated by the Institute of Astronomy and Geophysics, São Paulo University. The presented catalog, though not complete, has been designed to help in intensive search programmes (e.g. microlensing and variable searches) and therefore the selected standards have a high astrometric and photometric ($V$ band, approximately) quality. The mean precisions obtained were $0.0018^{s}$ in $\\alpha$, 0.013'' in magnitude when weighted with the error bars in each night (in the mean, 42 stars for the catalog of each window). Tables B.1 to B.12 are also available in eletronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg....

  14. The Width of the 511 KeV Line from the Bulge of the Galaxy

    CERN Document Server

    Zhitnitsky, A

    2006-01-01

    This is a comment on a recent criticism by Cumberbatch, Silk and Starkman (CSS), astro-ph/0606429. CSS criticize our proposal suggesting that the 511 keV \\gamma rays from the galactic bulge can be naturally explained by the supermassive Compact Composite Objects (CCO) of dark matter. In this comment I present the detail estimations supporting the original claim that the width of the 511 KeV line produced by such a mechanism is very narrow and in a few KeV range for incoming non relativistic electron with typical velocity v_e\\sim 10^{-3}c. The dominant mechanism of the annihilation in this case is the positronium formation e^+e^-\\to ~ ^1S_0 \\to 2\\gamma rather than a direct e^+e^-\\to 2\\gamma annihilation. This is in contrast with analysis of astro-ph/0606429 where a broad MeV distribution is expected as a result of annihilation within CCO framework. I also discuss some general features of the $\\gamma$ rays spectrum (in few MeV region) resulting from the CCO based mechanism.

  15. Metal-poor stars towards the Galactic bulge - a population potpourri

    CERN Document Server

    Koch, Andreas; Preston, George W; Thompson, Ian B

    2015-01-01

    We present a comprehensive chemical abundance analysis of five red giants and two horizontal branch (HB) stars towards the southern Galactic bulge, at (l,b)$\\sim$(0$^{\\rm o}$,-11$^{\\rm o}$). Based on high-resolution spectroscopy obtained with the Magellan/MIKE spectrograph, we derived up to 23 chemical element abundances and identify a mixed bag of stars, representing various populations in the central regions of the Galaxy. Although cosmological simulations predict that the inner Galaxy was host to the first stars in the Universe, we see no chemical evidence of the ensuing massive supernova explosions: all of our targets exhibit halo-like, solar [Sc/Fe] ratios, which is in contrast to the low values predicted from Population III nucleosynthesis. One of the targets is a CEMP-s star at [Fe/H]=-2.52 dex, and another one is a moderately metal-poor ([Fe/H]=-1.53 dex) CH star with strong enrichment in s-process elements (e.g., [Ba/Fe]=1.35). These individuals provide the first contenders of these classes of stars ...

  16. The Distance to the Galactic Center Derived From Infrared Photometry of Bulge Red Clump Stars

    CERN Document Server

    Nishiyama, S; Sato, S; Kato, D; Nagayama, T; Kusakabe, N; Matsunaga, N; Naoi, T; Sugitani, K; Tamura, M; Nishiyama, Shogo; Nagata, Tetsuya; Sato, Shuji; Kato, Daisuke; Nagayama, Takahiro; Kusakabe, Nobuhiko; Matsunaga, Noriyuki; Naoi, Takahiro; Sugitani, Koji; Tamura, Motohide

    2006-01-01

    On the basis of the near infrared observations of bulge red clump stars near the Galactic center, we have determined the galactocentric distance to be R_0 = 7.52 +- 0.10 (stat) +- 0.35 (sys) kpc. We observed the red clump stars at |l| < 1.0 deg and 0.7 deg < |b| < 1.0 deg with the IRSF 1.4 m telescope and the SIRIUS camera in the H and Ks bands. After extinction and population corrections, we obtained (m - M)_0 = 14.38 +- 0.03 (stat) +- 0.10 (sys). The statistical error is dominated by the uncertainty of the intrinsic local red clump stars' luminosity. The systematic error is estimated to be +- 0.10 including uncertainties in extinction and population correction, zero-point of photometry, and the fitting of the luminosity function of the red clump stars. Our result, R_0 = 7.52 kpc, is in excellent agreement with the distance determined geometrically with the star orbiting the massive black hole in the Galactic center. The recent result based on the spatial distribution of globular clusters is also co...

  17. The Distance to the Galactic Center Derived from Infrared Photometry of Bulge Red Clump Stars

    Science.gov (United States)

    Nishiyama, Shogo; Nagata, Tetsuya; Sato, Shuji; Kato, Daisuke; Nagayama, Takahiro; Kusakabe, Nobuhiko; Matsunaga, Noriyuki; Naoi, Takahiro; Sugitani, Koji; Tamura, Motohide

    2006-08-01

    On the basis of the near-infrared observations of bulge red clump stars near the Galactic center, we have determined the galactocentric distance to be R0=7.52+/-0.10 (stat) +/-0.35 (sys) kpc. We observed the red clump stars at |l|SIRIUS camera in the H and KS bands. After extinction and population corrections, we obtained (m-M)0=14.38+/-0.03 (stat) +/- 0.10 (sys). The statistical error is dominated by the uncertainty of the intrinsic local red clump stars' luminosity. The systematic error is estimated to be +/-0.10, including uncertainties in extinction and population correction, zero point of photometry, and the fitting of the luminosity function of the red clump stars. Our result, R0=7.52 kpc, is in excellent agreement with the distance determined geometrically with the star orbiting the massive black hole in the Galactic center. The recent result based on the spatial distribution of globular clusters is also consistent with our result. In addition, our study exhibits that the distance determination to the Galactic center with the red clump stars, even if the error of the population correction is taken into account, can achieve an uncertainty of about 5%, which is almost the same level as that in recent geometrical determinations.

  18. Identification of twenty-three accreting binaries in the Galactic Bulge Survey

    CERN Document Server

    Torres, M A P; Britt, C T; Johnson, C B; Hynes, R I; Greiss, S; Steeghs, D; Maccarone, T J; Ozel, F; Bassa, C; Nelemans, G

    2013-01-01

    (Abridged:) We present the identification of optical counterparts to 23 Galactic Bulge Survey X-ray sources. We report their accurate coordinates and optical spectra acquired at the VLT and Magellan. All sources are classified as accreting binaries according to their emission line characteristics. To distinguish accreting binaries from chromospherically active objects we develop and explain criteria based on Halpha and HeI 5786,6678 emission line properties available in the literature. The spectroscopic properties and photometric variability of all the objects are discussed and a classification of the source is given where possible. Among the 23 systems, at least 9 of them show an accretion-dominated optical spectrum (CX28, CX63, CX70, CX128, CX142, CX207, CX522, CX794, CX1011) and another 6 show photospheric lines from a late-type donor star in addition to accretion disc emission (CX44, CX93, CX137, CX154, CX377 and CX1004) indicating that they are probably accreting binaries in quiescence or in a low accret...

  19. On the age of Galactic bulge microlensed dwarf and subgiant stars

    CERN Document Server

    Valle, G; Moroni, P G Prada; Degl'Innocenti, S

    2015-01-01

    Recent results by Bensby and collaborators on the ages of microlensed stars in the Galactic bulge have challenged the picture of an exclusively old stellar population. However, these age estimates have not been independently confirmed. In this paper we verify these results by means of a grid-based method and quantify the systematic biases that might be induced by some assumptions adopted to compute stellar models. We explore the impact of increasing the initial helium abundance, neglecting the element microscopic diffusion, and changing the mixing-length calibration in theoretical stellar track computations. We adopt the SCEPtER pipeline with a novel stellar model grid for metallicities [Fe/H] from -2.00 to 0.55 dex, and masses in the range [0.60; 1.60] Msun from the ZAMS to the helium flash at the red giant branch tip. We show for the considered evolutionary phases that our technique provides unbiased age estimates. Our age results are in good agreement with Bensby and collaborators findings and show 16 star...

  20. A Catalog of Bulge+Disk Decompositions and Updated Photometry for 1.12 Million Galaxies in the Sloan Digital Sky Survey

    CERN Document Server

    Simard, Luc; Patton, David R; Ellison, Sara L; McConnachie, Alan W

    2011-01-01

    We perform two-dimensional, Point-Spread-Function-convolved, bulge+disk decompositions in the $g$ and $r$ bandpasses on a sample of 1,123,718 galaxies from the Legacy area of the Sloan Digital Sky Survey Data Release Seven. Four different decomposition procedures are investigated which make improvements to sky background determinations and object deblending over the standard SDSS procedures that lead to more robust structural parameters and integrated galaxy magnitudes and colors, especially in crowded environments. We use a set of science-based quality assurance metrics namely the disk luminosity-size relation, the galaxy color-magnitude diagram and the galaxy central (fiber) colors to show the robustness of our structural parameters. The best procedure utilizes simultaneous, two-bandpass decompositions. Bulge and disk photometric errors remain below 0.1 mag down to bulge and disk magnitudes of $g \\simeq 19$ and $r \\simeq 18.5$. We also use and compare three different galaxy fitting models: a pure Sersic mod...

  1. Understanding of surface pit formation mechanism of GaN grown in MOCVD based on local thermodynamic equilibrium assumption

    Science.gov (United States)

    Zhi-Yuan, Gao; Xiao-Wei, Xue; Jiang-Jiang, Li; Xun, Wang; Yan-Hui, Xing; Bi-Feng, Cui; De-Shu, Zou

    2016-06-01

    Frank’s theory describes that a screw dislocation will produce a pit on the surface, and has been evidenced in many material systems including GaN. However, the size of the pit calculated from the theory deviates significantly from experimental result. Through a careful observation of the variations of surface pits and local surface morphology with growing temperature and V/III ratio for c-plane GaN, we believe that Frank’s model is valid only in a small local surface area where thermodynamic equilibrium state can be assumed to stay the same. If the kinetic process is too vigorous or too slow to reach a balance, the local equilibrium range will be too small for the center and edge of the screw dislocation spiral to be kept in the same equilibrium state. When the curvature at the center of the dislocation core reaches the critical value 1/r 0, at the edge of the spiral, the accelerating rate of the curvature may not fall to zero, so the pit cannot reach a stationary shape and will keep enlarging under the control of minimization of surface energy to result in a large-sized surface pit. Project supported by the National Natural Science Foundation of China (Grant Nos. 11204009 and 61204011) and the Beijing Municipal Natural Science Foundation, China (Grant No. 4142005).

  2. A novel pressure sensing mechanism in a microchannel based on the surface tension and thermodynamic p–v–T relation

    International Nuclear Information System (INIS)

    A simple and cost-effective pressure sensing mechanism which can readily be used to increase measurement resolutions has been introduced. The proposed method measures the local static water pressure in a microchannel using the surface tension and thermodynamic p–v–T relation of air. The idea was tested using a microchannel along which a series of closed-end taps were perpendicularly placed. The prototype device was fabricated with SU-8, a negative photoresist. The dimension of the microchannel was 50 µm × 7 µm × 2.4 mm (W × H × L). The closed-end taps were located every 100 µm along the microchannel with various dimensions of 5–20 µm × 7 µm × 500–1500 µm (W × H × L). The surface tension was calculated through contact angle measurement on the water–air–SU-8 interface. Experiments were performed by imaging the meniscus location and were compared with analytical calculations. The proposed pressure sensing method showed good agreement with the analytical predictions and feasibilities as a valid pressure sensing mechanism in a microscale flow

  3. Potentiometric and Thermodynamic Studies of Some Schiff-Base Derivatives of 4-Aminoantipyrine and Their Metal Complexes

    Directory of Open Access Journals (Sweden)

    A. A. El-Bindary

    2013-01-01

    Full Text Available The proton-ligand dissociation constant of 4-(4-amino-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-ylideneamino-phenol ( and 4-(4-amino-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol-3-ylideneamino-benzoic acid ( and metal-ligand stability constants of their complexes with metal ions (Mn2+, Co2+, Ni2+, and Cu2+ have been determined potentiometrically in 0.1 mol·dm−3 KCl and 10% (by volume ethanol-water mixture and at 298, 308, and 318 K. The stability constants of the formed complexes increase in the order Mn2+, Co2+, Ni2+, and Cu2+. The effect of temperature was studied, and the corresponding thermodynamic parameters (, , and were derived and discussed. The dissociation process is nonspontaneous, endothermic, and entropically unfavourable. The formation of the metal complexes has been found to be spontaneous, endothermic, and entropically favourable.

  4. Complexation of Cu(II) by original tartaric acid-based ligands in nonionic micellar media: thermodynamic study and applications.

    Science.gov (United States)

    Dupont-Leclercq, Laurence; Giroux, Sébastien; Parant, Stéphane; Khoudour, Leïla; Henry, Bernard; Rubini, Patrice

    2009-04-01

    The complexation of Cu(II) with original alkylamidotartaric acids (C(x)T) is investigated in homogeneous aqueous medium and in the presence of nonionic micelles of Brij 58 (C16EO20), thanks to various analytical techniques such as NMR self-diffusion experiments, CD and UV-vis spectroscopy, ESI mass spectrometry, pHmetry and micellar-enhanced ultrafiltration (MEUF). First, a complete speciation study proves the formation of dimeric complexes in water and provides their formation constants. Second, a similar study is led in the presence of nonionic micelles. It underlines a modification of the apparent equilibrium constants in micellar medium and demonstrates that the structure of the complexes is slightly modified in the presence of micelles. This thermodynamic and structural study is applied to modelize the evolution of the extraction yields of Cu(II) by the micelles as a function of pH and to identify the complexes extracted in the micelles. The effects of the chain length of the ligand (C3T vs C8T) on the solubilization properties are put into relief and discussed. Anionic species are proved to be more incorporated in the nonionic micelles than the cationic species. The extracting system constituted of octylamidotartaric acid (CsT) solubilized in nonionic micelles of Brij 58 is demonstrated to be very efficient for the extraction of Cu(II) by MEUF, this technique being an interesting green alternative to traditional solvent extraction. PMID:19708239

  5. Detached Red Giant Eclipsing Binary Twins: Rosetta Stones to the Galactic Bulge

    CERN Document Server

    Nataf, David M; Pinsonneault, Marc H

    2012-01-01

    We identify 34 highly-probable detached, red giant eclipsing binary pairs among 315 candidates in Devor's catalog of $\\sim$10,000 OGLE-II eclipsing binaries. We estimate that there should be at least 200 such systems in OGLE-III. We show that spectroscopic measurements of the metallicities and radial-velocity-derived masses of these systems would independently constrain both the age-metallicity and helium-metallicity relations of the Galactic Bulge, potentially breaking the age-helium degeneracy that currently limits our ability to characterize the Bulge stellar population. Mass and metallicity measurements alone would be sufficient to immediately validate or falsify recent claims about the age and helium abundance of the Bulge. A spectroscopic survey of these systems would constrain models of Milky Way assembly, as well as provide significant auxiliary science on research questions such as mass loss on the red giant branch. We discuss the theoretical uncertainties in stellar evolution models that would need ...

  6. Chandra Studies of Unidentified X-ray Sources in the Galactic Bulge

    Science.gov (United States)

    Mori, Hideyuki

    2013-09-01

    We propose to study a complete X-ray sample in the luminosity range of > 10^34 erg s^-1 in the Galactic bulge, including 5 unidentified sources detected in the ROSAT All Sky Survey. Our goal is to obtain a clear picture about X-ray populations in the bulge, by utilizing the excellent Chandra position accuracy leading to unique optical identification together with the X-ray spectral properties. This is a new step toward understanding the formation history of the bulge. Furthermore, because the luminosity range we observe corresponds to a ``missing link'' region ever studied for a neutron star or blackhole X-ray binary, our results are also unique to test accretion disk theories at intermediate mass accretion rates.

  7. Long-Lived Spiral Structure for Galaxies with Intermediate Size Bulges

    CERN Document Server

    Saha, Kanak

    2016-01-01

    Spiral structure in disk galaxies is modeled with nine collisionless N-body simulations including live disks, halos, and bulges with a range of masses. Two of these simulations make long-lasting and strong two-arm spiral wave modes that last for $\\sim5$ Gyr with constant pattern speed. These two had a light stellar disk and the largest values of the Toomre $Q$ parameter in the inner region at the time the spirals formed, suggesting the presence of a Q-barrier to wave propagation resulting from the bulge. The relative bulge mass in these cases is about 10\\%. Models with weak two-arm spirals had pattern speeds that followed the radial dependence of the Inner Lindblad Resonance.

  8. The Controversial Star-Formation History and Helium Enrichment of the Milky Way Bulge

    CERN Document Server

    Nataf, David M

    2015-01-01

    The stellar population of the Milky Way bulge is thoroughly studied, with a plethora of measurements from virtually the full suite of instruments available to astronomers. It is thus perhaps surprising that alongside well-established results lies some substantial uncertainty in its star-formation history. Cosmological models predict the bulge to host the Galaxy's oldest stars for [Fe/H]$\\lesssim -1$, and this is demonstrated by RR Lyrae stars and globular cluster observations. There is consensus that bulge stars with [Fe/H]$\\lesssim0$ are older than $t \\approx10$ Gyr. However, at super-solar metallicity, there is a substantial unresolved discrepancy. Data from spectroscopic measurements of the main-sequence turnoff and subgiant branch, the abundances of asymptotic giant branch stars, the period distribution of Mira variables, the chemistry and central-star masses of planetary nebulae, all suggest a substantial intermediate-age population ($t \\approx 3$ Gyr). This is in conflict with predictions from cosmologi...

  9. Stellar Population Gradients in Bulges along the Hubble Sequence: I. The Data

    CERN Document Server

    Gorgas, J; Goudfrooij, P

    2007-01-01

    This is the first paper presenting our long-term project aimed at studying the nature of bulges through the analysis of their stellar population gradients. We present deep spectroscopic observations along the minor axis and the data reduction for a sample of 32 bulges of edge-on spiral galaxies. We explain in detail our procedures to measure their dynamical parameters (rotation curves and velocity dispersion profiles) and line-strength indices, including the conversion to the Lick/IDS system. Tables giving the values of the dynamical parameters and line-strength indices at each galactocentric radius are presented (in electronic form) for each galaxy of the sample. The derived line-strength gradients from this dataset will be analyzed in a forthcoming paper to set constraints on the different scenarios for the formation of the bulges.

  10. Red Variables in Globular Clusters: Comparison with the Bulge and the LMC

    CERN Document Server

    Matsunaga, N; Tanabé, T; Fukushi, H; Ita, Y

    2005-01-01

    We are conducting a project aimed at surveys and repeated observations of red variables (or long-period variables) in globular clusters. Using the IRSF/SIRIUS near-infrared facility located at South Africa, we are observing 145 globular clusters that are accessible from the site. In this contribution, we present our observations and preliminary results. We have discovered many red variables, especially in the Bulge region, whose memberships to the clusters remain to be confirmed. Using a sample of all red variables (both already known and newly discovered ones) in globular clusters except those projected to the Bulge region, we produce a log P-K diagram and compare it with those for the Bulge and the Large Magellanic Cloud. A prominent feature is that the bright part of overtone-pulsators' sequence (B+ and C') is absent.

  11. Red variables in globular clusters . Comparison with the Bulge and the LMC

    Science.gov (United States)

    Matsunaga, N.; Nakada, Y.; Tanabé, T.; Fukushi, H.; Ita, Y.

    We are conducting a project aimed at surveys and repeated observations of red variables (or long-period variables) in globular clusters. Using the IRSF/SIRIUS near-infrared facility located at South Africa, we are observing 145 globular clusters that are accessible from the site. In this contribution, we present our observations and preliminary results. We have discovered many red variables, especially in the Bulge region, whose memberships to the clusters remain to be confirmed. Using a sample of all red variables (both already known and newly discovered ones) in globular clusters except those projected to the Bulge region, we produce a log P-K diagram and compare it with those for the Bulge and the Large Magellanic Cloud. A prominent feature is that the bright part of overtone-pulsators' sequence (B+ and C\\prime) is absent. We discuss its implication on the evolution of red variables.

  12. Heat and thermodynamics

    CERN Document Server

    Brewster, Hilary D

    2009-01-01

    Thermodynamics is an exciting and fascinating subject that deals with energy, which is essential for sustenance of life, and Thermodynamics has long been an essential part of Engineering Curricula all over the world. It has a broad application area ranging from Microscopic Organisms to common Household Appliances, Transportation Vehicles, and Power Generation Systems.

  13. A case against an X-shaped structure in the Milky Way young bulge

    Science.gov (United States)

    López-Corredoira, Martín

    2016-09-01

    Context. A number of recent papers have claimed the discovery of an X-shape structure in the bulge of our Galaxy in the population of the red clumps. Aims: We endeavor to analyze the stellar density of bulge stars in the same regions using a different stellar population that is characteristic of the young bulge (≲ 5 Gyr). Particularly, we use F0-F5 main-sequence stars with distances derived through photometric parallax. Methods: We extract these stars from extinction-corrected color-magnitude diagrams in the near-infrared of VISTA-VVV data in some bulge regions and calculate the densities along the line of sight. We take the uncertaintity in the photometric parallax and the contamination of other sources into account, and we see that these errors do not avoid the detection of a possible double peak along some lines of sight as expected for a X-shape bulge if it existed. Results: Only a single peak in the density distribution along the line of sight is observed, so apparently there is no X-shape structure for this population of stars. Nonetheless, the effects of the dispersion of absolute magnitudes in the selected population might be an alternative explanation, although in principle these effects are insufficient to explain this lack of double peak according to our calculations. Conclusions: The results of the present paper do not demonstrate that previous claims of X-shaped bulge using only red clump stars are incorrect, but there are apparently some puzzling questions if we want to maintain the validity of both the red-clump results and the results of this paper.

  14. Applied chemical engineering thermodynamics

    CERN Document Server

    Tassios, Dimitrios P

    1993-01-01

    Applied Chemical Engineering Thermodynamics provides the undergraduate and graduate student of chemical engineering with the basic knowledge, the methodology and the references he needs to apply it in industrial practice. Thus, in addition to the classical topics of the laws of thermodynamics,pure component and mixture thermodynamic properties as well as phase and chemical equilibria the reader will find: - history of thermodynamics - energy conservation - internmolecular forces and molecular thermodynamics - cubic equations of state - statistical mechanics. A great number of calculated problems with solutions and an appendix with numerous tables of numbers of practical importance are extremely helpful for applied calculations. The computer programs on the included disk help the student to become familiar with the typical methods used in industry for volumetric and vapor-liquid equilibria calculations.

  15. Thermodynamics an engineering approach

    CERN Document Server

    Cengel, Yunus A

    2014-01-01

    Thermodynamics, An Engineering Approach, eighth edition, covers the basic principles of thermodynamics while presenting a wealth of real-world engineering examples so students get a feel for how thermodynamics is applied in engineering practice. This text helps students develop an intuitive understanding by emphasizing the physics and physical arguments. Cengel and Boles explore the various facets of thermodynamics through careful explanations of concepts and use of numerous practical examples and figures, having students develop necessary skills to bridge the gap between knowledge and the confidence to properly apply their knowledge. McGraw-Hill is proud to offer Connect with the eighth edition of Cengel/Boles, Thermodynamics, An Engineering Approach. This innovative and powerful new system helps your students learn more efficiently and gives you the ability to assign homework problems simply and easily. Problems are graded automatically, and the results are recorded immediately. Track individual stude...

  16. Mechanical problems of superplastic fill-forming bulge solved by one-dimensional tensile and two-dimensional free bulging constitutive equations

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Because of the strong structural sensitivity of superplasticity, the deformation rule must be affected by stress-state. It is necessary to prove whether one-dimensional tensile constitutive equation can be directly generalized to deal with the two-dimensional mechanical problems or not. In this paper, theoretical results of fill-forming bulge have been derived from both one-dimensional tensile and two-dimensional bulging constitutive equation with variable m value. By comparing theoretical analysis and experimental results made on typical superplastic alloy Zn-wt22%Al, it is shown that one-dimensional tensile constitutive equation cannot be directly generalized to deal with two-dimensional mechanical questions. A method to correct deviation between theoretical and experimental results is also proposed.

  17. Self-assembly thermodynamics of pH-responsive amino-acid-based polymers with a nonionic surfactant.

    Science.gov (United States)

    Bogomolova, Anna; Keller, Sandro; Klingler, Johannes; Sedlak, Marian; Rak, Dmytro; Sturcova, Adriana; Hruby, Martin; Stepanek, Petr; Filippov, Sergey K

    2014-09-30

    The behavior of pH-responsive polymers poly(N-methacryloyl-l-valine) (P1), poly(N-methacryloyl-l-phenylalanine) (P2), and poly(N-methacryloylglycyne-l-leucine) (P3) has been studied in the presence of the nonionic surfactant Brij98. The pure polymers phase-separate in an acidic medium with critical pHtr values of 3.7, 5.5, and 3.4, respectively. The addition of the surfactant prevents phase separation and promotes reorganization of polymer molecules. The nature of the interaction between polymer and surfactant depends on the amino acid structure in the side chain of the polymer. This effect was investigated by dynamic light scattering, isothermal titration calorimetry, electrophoretic measurements, small-angle neutron scattering, and infrared spectroscopy. Thermodynamic analysis revealed an endothermic association reaction in P1/Brij98 mixture, whereas a strong exothermic effect was observed for P2/Brij98 and P3/Brij98. Application of regular solution theory for the analysis of experimental enthalpograms indicated dominant hydrophobic interactions between P1 and Brij98 and specific interactions for the P2/Brij98 system. Electrophoretic and dynamic light scattering measurements support the applicability of the theory to these cases. The specific interactions can be ascribed to hydrogen bonds formed between the carboxylic groups of the polymer and the oligo(ethylene oxide) head groups of the surfactant. Thus, differences in polymer-surfactant interactions between P1 and P2 polymers result in different structures of polymer-surfactant complexes. Specifically, small-angle neutron scattering revealed pearl-necklace complexes and "core-shell" structures for P1/Brij98 and P2/Brij98 systems, respectively. These results may help in the design of new pH-responsive site-specific micellar drug delivery systems or pH-responsive membrane-disrupting agents.

  18. Identification of a novel HIV-1 TAR RNA bulge binding protein.

    OpenAIRE

    B. Baker; Muckenthaler, M; Vives, E.; Blanchard, A.; Braddock, M; Nacken, W.; Kingsman, A J; Kingsman, S M

    1994-01-01

    The Tat protein binds to TAR RNA to stimulate the expression of the human immunodeficiency virus type 1 (HIV-1) genome. Tat is an 86 amino acid protein that contains a short region of basic residues (aa49-aa57) that are required for RNA binding and TAR is a 59 nucleotide stem-loop with a tripyrimidine bulge in the upper stem. TAR is located at the 5' end of all viral RNAs. In vitro, Tat specifically interacts with TAR by recognising the sequence of the bulge and upper stem, with no requiremen...

  19. Bulge mass is king: The dominant role of the bulge in determining the fraction of passive galaxies in the Sloan Digital Sky Survey

    CERN Document Server

    Bluck, Asa F L; Ellison, Sara L; Moreno, Jorge; Simard, Luc; Patton, David R; Starkenburg, Else

    2014-01-01

    We investigate the origin of galaxy bimodality by quantifying the relative role of intrinsic and environmental drivers to the cessation (or `quenching') of star formation in over half a million local Sloan Digital Sky Survey (SDSS) galaxies. Our sample contains a wide variety of galaxies at z=0.02-0.2, with stellar masses of 8 < log(M*/M_sun) < 12, spanning the entire morphological range from pure disks to spheroids, and over four orders of magnitude in local galaxy density and halo mass. We utilise published star formation rates and add to this recent GIM2D photometric and stellar mass bulge + disk decompositions from our group. We find that the passive fraction of galaxies increases steeply with stellar mass, halo mass, and bulge mass, with a less steep dependence on local galaxy density and bulge-to-total stellar mass ratio (B/T). At fixed internal properties, we find that central and satellite galaxies have different passive fraction relationships. For centrals, we conclude that there is less variat...

  20. Comparing the properties of the X-shaped bulges of NGC 4710 and the Milky Way with MUSE

    CERN Document Server

    Gonzalez, O A; Debattista, V P; Rejkuba, M; Valenti, E; Zoccali, M; Coccato, L; Minniti, D; Ness, M

    2016-01-01

    We used the new ESO VLT instrument MUSE to obtain spectral and imaging coverage of NGC 4710. The wide area and excellent sampling of the MUSE integral field spectrograph allows us to investigate the dynamical properties of the X-shaped bulge of NGC 4710 and compare it with the properties of the Milky Way's own X-shaped bulge. We measured the radial velocities, velocity dispersion, and stellar populations using a penalized pixel full spectral fitting technique adopting simple stellar populations models, on a 1' x 1' area centred on the bulge of NGC 4710. We have constructed the velocity maps of the bulge of NGC 4710 and we investigated the presence of vertical metallicity gradients. These properties were compared to those of the Milky Way bulge and as well as to a simulated galaxy with boxy/peanut bulge. We find the line-of-sight velocity maps and 1D rotation curves of the bulge of NGC 4710 to be remarkably similar to those of the Milky Way bulge. Some specific differences that were identified are in good agre...

  1. Thermodynamics of firms' growth

    CERN Document Server

    Zambrano, Eduardo; Fernandez-Bariviera, Aurelio; Hernando, Ricardo; Plastino, Angelo

    2015-01-01

    The distribution of firms' growth and firms' sizes is a topic under intense scrutiny. In this paper we show that a thermodynamic model based on the Maximum Entropy Principle, with dynamical prior information, can be constructed that adequately describes the dynamics and distribution of firms' growth. Our theoretical framework is tested against a comprehensive data-base of Spanish firms, which covers to a very large extent Spain's economic activity with a total of 1,155,142 firms evolving along a full decade. We show that the empirical exponent of Pareto's law, a rule often observed in the rank distribution of large-size firms, is explained by the capacity of the economic system for creating/destroying firms, and can be used to measure the health of a capitalist-based economy. Indeed, our model predicts that when the exponent is larger that 1, creation of firms is favored; when it is smaller that 1, destruction of firms is favored instead; and when it equals 1 (matching Zipf's law), the system is in a full mac...

  2. Considerations on non equilibrium thermodynamics of interactions

    Science.gov (United States)

    Lucia, Umberto

    2016-04-01

    Nature can be considered the "first" engineer! For scientists and engineers, dynamics and evolution of complex systems are not easy to predict. A fundamental approach to study complex system is thermodynamics. But, the result is the origin of too many schools of thermodynamics with a consequent difficulty in communication between thermodynamicists and other scientists and, also, among themselves. The solution is to obtain a unified approach based on the fundamentals of physics. Here we suggest a possible unification of the schools of thermodynamics starting from two fundamental concepts of physics, interaction and flows.

  3. Renewable feedstocks in green solvents: thermodynamic study on phase diagrams of D-sorbitol and xylitol with dicyanamide based ionic liquids.

    Science.gov (United States)

    Paduszyński, Kamil; Okuniewski, Marcin; Domańska, Urszula

    2013-06-13

    Experimental and theoretical studies on thermodynamic properties of three ionic liquids based on dicyanamide anion (namely, 1-butyl-3-methylimidazolium dicyanamide, 1-butyl-1-methylpyrrolidinium dicyanamide, and 1-butyl-1-methylpiperidinium dicyanamide) and their binary mixtures with sugar alcohols (D-sorbitol and xylitol) were conducted in order to assess the applicability of the salts ionic liquids for dissolution of those biomass-related materials. Density and dynamic viscosity (at ambient pressure) of pure ionic liquids are reported in the temperature range from T = 293.15 to 363.15 K. Solid-liquid equilibrium phase diagrams in binary systems {sugar alcohol + ionic liquid} were measured with dynamic method up to the fusion temperature of sugar alcohol. The impact of the chemical structure of both the ionic liquid and sugar alcohol were established and discussed. For the very first time, the experimental solubility data were reproduced and analyzed in terms of equation of state rooted in statistical mechanics. For this purpose, perturbed-chain statistical associating fluid theory (PC-SAFT) was employed. In particular, new molecular schemes for the ionic liquids, D-sorbitol, and xylitol were proposed, and then the pure chemicals were parametrized by using available density and vapor pressure data. The model allowed accurate correlation of pure fluid properties for both ionic liquids and sugar alcohols, when the association term is taken into account. The results of solid-liquid equilibria modeling were also satisfactory. However, one or two adjustable binary corrections to the adopted combining rules were required to be adjusted in order to accurately capture the phase behavior. It was shown that a consistent thermodynamic description of extremely complex systems can be achieved by using relatively simple (but physically grounded) theoretical tools and molecular schemes.

  4. Chemical model for cement-based materials: Temperature dependence of thermodynamic functions for nanocrystalline and crystalline C-S-H phases

    International Nuclear Information System (INIS)

    In the context of waste confinement and, more specifically, waste from the nuclear industry, concrete is used both as a confinement and as a building material. Its exposure to high temperatures makes its geochemical behavior difficult to predict over large periods of time. The present work aims to elucidate the solubility constants, as a function of temperature, for the phases of the system CaO-SiO2-H2O. For the nanocrystalline phases, the present work investigates the existence of compounds of fixed composition, possibly in a metastable state. The question of whether the nanocrystalline C-S-H phases correspond to a series of phases of discrete composition or a solid solution is discussed and compared to the possible influence of impurities in the solid phases. For the crystalline phases, having established that the currently available values of thermodynamic properties were not consistent, we show that their refinement leads to a better agreement with the literature data. From the refined thermodynamic properties of crystalline C-S-H, a polyhedral decomposition model is developed. It enables to estimate the enthalpy of formation and the heat capacity of nanocrystalline C-S-H phases. Finally, verification shows that such phases remain unstable compared to the crystalline phases, at room or higher temperatures. A comparison, based on reaction enthalpies derived from experimental data indicates that predicted values for nanocrystalline C-S-H are in close agreement with experimental data. By estimating the properties of okenite and truscottite with the model developed in this study, we have been able to complete the CaO-SiO2-H2O phase diagram with a reasonable agreement with the literature. The case of jaffeite remains open to discussion. Finally, for the hydrate C2SH,α, the model predicts a transition with hillebrandite at 159 deg. C, in contradiction with the hypothesis of C2SH,α metastability.

  5. Cost reduction possibilities of vanadium-based solid solutions – Microstructural, thermodynamic, cyclic and environmental effects of ferrovanadium substitution

    Energy Technology Data Exchange (ETDEWEB)

    Ulmer, Ulrich, E-mail: Ulrich.Ulmer@kit.edu [Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, P.O. Box 3640, D-76021 Karlsruhe (Germany); Asano, Kohta [National Institute of Advanced Industrial Science and Technology (AIST), AIST Central-5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565 (Japan); Patyk, Andreas [Karlsruhe Institute of Technology (KIT), Institute of Technology Assessment and Systems Analysis, P.O. Box 3640, D-76021 Karlsruhe (Germany); Enoki, Hirotoshi; Nakamura, Yumiko [National Institute of Advanced Industrial Science and Technology (AIST), AIST Central-5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565 (Japan); Pohl, Alexander [Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, P.O. Box 3640, D-76021 Karlsruhe (Germany); Dittmeyer, Roland [Karlsruhe Institute of Technology (KIT), Institute for Micro Process Engineering, P.O. Box 3640, D-76021 Karlsruhe (Germany); Fichtner, Maximilian [Karlsruhe Institute of Technology (KIT), Institute of Nanotechnology, P.O. Box 3640, D-76021 Karlsruhe (Germany); Helmholtz-Institute Ulm for Electrochemical Energy Storage, Helmholtzstr. 11, 89081 Ulm (Germany)

    2015-11-05

    Microstructural changes, thermodynamic and cyclic properties, total material cost and the cumulative energy demand of V{sub (40−40·x)}Fe{sub (8−8·x)}Ti{sub 26}Cr{sub 26}(FeV){sub (48·x)} with 0 ≤ x ≤ 0.9 using commercial ferrovanadium (FeV) are investigated. The substitution of V + Fe by FeV (x = 0.9) raises the equilibrium hydrogen pressure at 298 K from p{sub a} = 1 MPa to p{sub a} = 6 MPa during absorption of H{sub 2} and p{sub d} = 0.2 MPa and p{sub d} = 1 MPa during desorption. The reversible hydrogen storage capacity is determined after 50 pressure-swing cycles and is reduced from 2.2 mass% to 1.7 mass% for the unsubstituted alloy (x = 0) compared to 1.7 mass% to 1.3 mass% for the FeV substituted alloy (x = 0.9). This corresponds to a loss of capacity of approx. 23% for both samples. After taking into account the capacity loss caused by FeV substitution, the raw material cost per 100 kg of stored H is reduced to 1/3 of the original price of the unsubstituted alloy. The cumulative energy demand of pure V depends on the number of purification steps. Ferrovanadium shows a cumulative energy demand which is reduced at least by a factor of 1.4 as compared to high-purity vanadium. - Highlights: • Effect of FeV on microstructure and H storage properties of V–Fe–Ti–Cr alloys. • Increasing FeV content increases the equilibrium pressure from 1 to 6 MPa. • Cyclic effects: degradation by 23% for both pristine and FeV-substituted alloys. • FeV substitution reduces the overall material cost to 1/3 of the original cost. • High-purity V production requires 1.4 times more energy than FeV production.

  6. Thermodynamics of cosmological matter creation

    OpenAIRE

    Prigogine, I.; Geheniau, J.; Gunzig, E.; Nardone, P.

    1988-01-01

    A type of cosmological history that includes large-scale entropy production is proposed. These cosmologies are based on reinterpretation of the matter-energy stress tensor in Einstein's equations. This modifies the usual adiabatic energy conservation laws, thereby including irreversible matter creation. This creation corresponds to an irreversible energy flow from the gravitational field to the created matter constituents. This point of view results from consideration of the thermodynamics of...

  7. Hadron melting and QCD thermodynamics

    OpenAIRE

    Jakovac, A.

    2013-01-01

    We study in this paper mechanisms of hadron melting based on the spectral representation of hadronic quantum channels, and examine the hadron width dependence of the pressure. The findings are applied to a statistical hadron model of QCD thermodynamics, where hadron masses are distributed by the Hagedorn model and a uniform mechanism for producing hadron widths is assumed. According to this model the hadron - quark gluon plasma transition occurs at $T\\approx 200$-250 MeV, the numerically obse...

  8. Stochastic approach to equilibrium and nonequilibrium thermodynamics.

    Science.gov (United States)

    Tomé, Tânia; de Oliveira, Mário J

    2015-04-01

    We develop the stochastic approach to thermodynamics based on stochastic dynamics, which can be discrete (master equation) and continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of entropy itself and the second the definition of entropy production rate, which is non-negative and vanishes in thermodynamic equilibrium. Based on these assumptions, we study interacting systems with many degrees of freedom in equilibrium or out of thermodynamic equilibrium and how the macroscopic laws are derived from the stochastic dynamics. These studies include the quasiequilibrium processes; the convexity of the equilibrium surface; the monotonic time behavior of thermodynamic potentials, including entropy; the bilinear form of the entropy production rate; the Onsager coefficients and reciprocal relations; and the nonequilibrium steady states of chemical reactions. PMID:25974471

  9. Non-equilibrium thermodynamics

    CERN Document Server

    Groot, S R De

    2011-01-01

    The study of thermodynamics is especially timely today, as its concepts are being applied to problems in biology, biochemistry, electrochemistry, and engineering. This book treats irreversible processes and phenomena - non-equilibrium thermodynamics.S. R. de Groot and P. Mazur, Professors of Theoretical Physics, present a comprehensive and insightful survey of the foundations of the field, providing the only complete discussion of the fluctuating linear theory of irreversible thermodynamics. The application covers a wide range of topics: the theory of diffusion and heat conduction, fluid dyn

  10. Thermodynamics of quantum strings

    CERN Document Server

    Morgan, M J

    1994-01-01

    A statistical mechanical analysis of an ideal gas of non-relativistic quantum strings is presented, in which the thermodynamic properties of the string gas are calculated from a canonical partition function. This toy model enables students to gain insight into the thermodynamics of a simple 'quantum field' theory, and provides a useful pedagogical introduction to the more complicated relativistic string theories. A review is also given of the thermodynamics of the open bosonic string gas and the type I (open) superstring gas. (author)

  11. Thermodynamics I essentials

    CERN Document Server

    REA, The Editors of

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Thermodynamics I includes review of properties and states of a pure substance, work and heat, energy and the first law of thermodynamics, entropy and the second law of thermodynamics

  12. Modern engineering thermodynamics

    CERN Document Server

    Balmer, Robert T

    2010-01-01

    Designed for use in a standard two-semester engineering thermodynamics course sequence. The first half of the text contains material suitable for a basic Thermodynamics course taken by engineers from all majors. The second half of the text is suitable for an Applied Thermodynamics course in mechanical engineering programs. The text has numerous features that are unique among engineering textbooks, including historical vignettes, critical thinking boxes, and case studies. All are designed to bring real engineering applications into a subject that can be somewhat abstract and mathematica

  13. The application of computational thermodynamics and a numerical model for the determination of surface tension and Gibbs-Thomson coefficient of aluminum based alloys

    International Nuclear Information System (INIS)

    Highlights: → Surface tension and the Gibbs-Thomson coefficient are computed for Al-based alloys. → Butler's scheme and ThermoCalc are used to compute the thermophysical properties. → Predictive cell/dendrite growth models depend on accurate thermophysical properties. → Mechanical properties can be related to the microstructural cell/dendrite spacing. - Abstract: In this paper, a solution for Butler's formulation is presented permitting the surface tension and the Gibbs-Thomson coefficient of Al-based binary alloys to be determined. The importance of Gibbs-Thomson coefficient for binary alloys is related to the reliability of predictions furnished by predictive cellular and dendritic growth models and of numerical computations of solidification thermal variables, which will be strongly dependent on the thermophysical properties assumed for the calculations. A numerical model based on Powell hybrid algorithm and a finite difference Jacobian approximation was coupled to a specific interface of a computational thermodynamics software in order to assess the excess Gibbs energy of the liquid phase, permitting the surface tension and Gibbs-Thomson coefficient for Al-Fe, Al-Ni, Al-Cu and Al-Si hypoeutectic alloys to be calculated. The computed results are presented as a function of the alloy composition.

  14. Capture of field stars by globular clusters in dense bulge regions

    CERN Document Server

    Bica, E; Ortolan, S; Barbuy, B; Bica, Eduardo; Dottori, Horacio; Ortolan, Sergio; Barbuy, Beatriz

    1997-01-01

    The recent detection of a double Red Giant Branch in the optical color-magnitude diagram (CMD) of the bulge globular cluster HP1 (Ortolani et al. 1997), a more populated metal-poor steep one corresponding to the cluster itself, and another metal-rich curved, led us to explore in the present Letter the possibility of capture of field stars by a globular cluster orbiting in dense bulge regions over several gigayears. Analytical arguments, as well as N-body calculations for a cluster model of 10^5 solar masses in a bulge-like environment, suggest that a significant fraction of cluster stars may consist of captures. Metal-poor globular clusters in the inner bulge, like HP1, contrasting at least in Delta [Fe/H] = 1.0 dex with respect to the surrounding metal-rich stars, are ideal probes to further test the capture scenario. In turn, if this scenario is confirmed, the double RGB of HP1 could provide direct estimates of blanketing amounts, which is fundamental for the photometric calibration of metal-rich stellar po...

  15. Extremely metal-poor stars from the cosmic dawn in the bulge of the Milky Way

    CERN Document Server

    Howes, L M; Asplund, M; Keller, S C; Yong, D; Nataf, D M; Poleski, R; Lind, K; Kobayashi, C; Owen, C I; Ness, M; Bessell, M S; Da Costa, G S; Schmidt, B P; Tisserand, P; Udalski, A; Szymański, M K; Soszyński, I; Pietrzyński, G; Ulaczyk, K; Wyrzykowski, Ł; Pietrukowicz, P; Skowron, J; Kozłowski, S; Mróz, P

    2015-01-01

    The first stars are predicted to have formed within 200 million years after the Big Bang, initiating the cosmic dawn. A true first star has not yet been discovered, although stars with tiny amounts of elements heavier than helium ('metals') have been found in the outer regions ('halo') of the Milky Way. The first stars and their immediate successors should, however, preferentially be found today in the central regions ('bulges') of galaxies, because they formed in the largest over-densities that grew gravitationally with time. The Milky Way bulge underwent a rapid chemical enrichment during the first 1-2 billion years, leading to a dearth of early, metal-poor stars. Here we report observations of extremely metal-poor stars in the Milky Way bulge, including one star with an iron abundance about 10,000 times lower than the solar value without noticeable carbon enhancement. We confirm that the most metal-poor bulge stars are on tight orbits around the Galactic Centre, rather than being halo stars passing through...

  16. Peanuts, brezels and bananas: food for thought on the orbital structure of the Galactic bulge

    Science.gov (United States)

    Portail, Matthieu; Wegg, Christopher; Gerhard, Ortwin

    2015-06-01

    Recent observations have discovered the presence of a box/peanut or X-shape structure in the Galactic bulge. Such box/peanut structures are common in external disc galaxies, and are well known in N-body simulations where they form following the buckling instability of a bar. From studies of analytical potentials and N-body models, it has been claimed in the past that box/peanut bulges are supported by `bananas', or x1v1 orbits. We present here a set of N-body models where instead the peanut bulge is mainly supported by brezel-like orbits, allowing strong peanuts to form with short extent relative to the bar length. This shows that stars in the X-shape do not necessarily stream along banana orbits which follow the arms of the X-shape. The brezel orbits are also found to be the main orbital component supporting the peanut shape in our recent made-to-measure dynamical models of the Galactic bulge. We also show that in these models the fraction of stellar orbits that contribute to the X-structure account for 40-45 per cent of the stellar mass.

  17. The Gaia-ESO Survey: Metal-rich Bananas in the Bulge

    Science.gov (United States)

    Williams, Angus A.; Evans, N. W.; Molloy, Matthew; Kordopatis, Georges; Smith, M. C.; Shen, J.; Gilmore, G.; Randich, S.; Bensby, T.; Francois, P.; Koposov, S. E.; Recio-Blanco, A.; Bayo, A.; Carraro, G.; Casey, A.; Costado, T.; Franciosini, E.; Hourihane, A.; de Laverny, P.; Lewis, J.; Lind, K.; Magrini, L.; Monaco, L.; Morbidelli, L.; Sacco, G. G.; Worley, C.; Zaggia, S.; Mikolaitis, Š.

    2016-06-01

    We analyze the kinematics of ˜2000 giant stars in the direction of the Galactic bulge, extracted from the Gaia-ESO survey in the region -10^\\circ ≲ {\\ell }≲ 10^\\circ and -11^\\circ ≲ b≲ -3^\\circ . We find distinct kinematic trends in the metal-rich ([{{M}}/{{H}}]\\gt 0) and metal-poor ([{{M}}/{{H}}]\\lt 0) stars in the data. The velocity dispersion of the metal-rich stars drops steeply with latitude, compared to a flat profile in the metal-poor stars, as has been seen previously. We argue that the metal-rich stars in this region are mostly on orbits that support the boxy-peanut shape of the bulge, which naturally explains the drop in their velocity dispersion profile with latitude. The metal-rich stars also exhibit peaky features in their line of sight velocity histograms, particularly along the minor axis of the bulge. We propose that these features are due to stars on resonant orbits supporting the boxy-peanut bulge. This conjecture is strengthened through the comparison of the minor axis data with the velocity histograms of resonant orbits generated in simulations of buckled bars. The “banana” or 2:1:2 orbits provide strongly bimodal histograms with narrow velocity peaks that resemble the Gaia-ESO metal-rich data.

  18. What planetary nebulae tell us about helium and the CNO elements in Galactic bulge stars

    CERN Document Server

    Buell, James F

    2012-01-01

    Thermally pulsing asymptotic giant branch (TP-AGB) models of bulge stars are calculated using a synthetic model. The goal is to infer typical progenitor masses and compositions by reproducing the typical chemical composition and central star masses of planetary nebulae (PNe) in the Galactic bulge. The AGB tip luminosity and the observation that the observed lack of bright carbon stars in the bulge are matched by the models. Five sets of galactic bulge PNe were analyzed to find typical abundances and central star of planetary nebulae (CSPN) masses. These global parameters were matched by the AGB models. These sets are shown to be consistent with the most massive CSPN having the largest abundances of helium and heavy elements. The CSPN masses of the most helium rich (He/H$\\ga$0.130 or $Y\\ga0.34$) PNe are estimated to be between 0.58 and 0.62$ {\\rm M}_{\\sun}$. The oxygen abundance in form $\\log{\\rm (O/H)}+12$ of these highest mass CSPN is estimated to be $\\approx$8.85. TP-AGB models with ZAMS masses between 1.2 ...

  19. The growth of galactic bulges through mergers in LCDM haloes revisited. II. Morphological mix evolution

    CERN Document Server

    Avila-Reese, Vladimir; Lacerna, Ivan

    2013-01-01

    The mass aggregation and merger histories of present-day distinct haloes selected from the cosmological Millennium Simulations I and II are mapped into stellar mass aggregation and galaxy merger histories of central galaxies by using empirical stellar-to-halo and stellar-to-gas mass relations. The growth of bulges driven by the galaxy mergers/interactions is calculated using analytical recipes. The predicted bulge demographics at redshift z~0 is consistent with observations (Zavala+2012). Here we present the evolution of the morphological mix (traced by the bulge-to-total mass ratio, B/T) as a function of mass up to z=3. This mix remains qualitatively the same up to z~1: B/T0.45 at large masses. At z>1, the fractions of disc-dominated and bulgeless galaxies increase strongly, and by z~2 the era of pure disc galaxies is reached. Bulge-dominated galaxies acquire such a morphology, and most of their mass, following a downsizing trend. Since our results are consistent with several recent observational studies of ...

  20. Peanuts, brezels and bananas: food for thought on the orbital structure of the Galactic bulge

    CERN Document Server

    Portail, M; Gerhard, O

    2015-01-01

    Recent observations have discovered the presence of a Box/Peanut or X-shape structure in the Galactic bulge. Such Box/Peanut structures are common in external disc galaxies, and are well-known in N-body simulations where they form following the buckling instability of a bar. From studies of analytical potentials and N-body models it has been claimed in the past that Box/Peanut bulges are supported by "bananas", or x1v1 orbits. We present here a set of N-body models where instead the peanut bulge is mainly supported by brezel-like orbits, allowing strong peanuts to form with short extent relative to the bar length. This shows that stars in the X-shape do not necessarily stream along banana orbits which follow the arms of the X-shape. The brezel orbits are also found to be the main orbital component supporting the peanut shape in our recent Made-to-Measure dynamical models of the Galactic bulge. We also show that in these models the fraction of stellar orbits that contribute to the X-structure account for 40-45...