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Sample records for barrier discharge reactor

  1. Conduction heat transfer in a cylindrical dielectric barrier discharge reactor

    Energy Technology Data Exchange (ETDEWEB)

    Sadat, H. [Laboratoire d' Etudes Thermiques, Universite de Poitiers, 40 Avenue du Recteur Pineau, 86022 Poitiers (France)], E-mail: hamou.sadat@univ-poitiers.fr; Dubus, N. [Laboratoire d' Etudes Thermiques, Universite de Poitiers, 40 Avenue du Recteur Pineau, 86022 Poitiers (France); Pinard, L.; Tatibouet, J.M.; Barrault, J. [Laboratoire en catalyse et chimie organique, Universite de Poitiers, 40 Avenue du Recteur Pineau, 86022 Poitiers (France)

    2009-04-15

    The thermal behaviour of a dielectric barrier discharge reactor is studied. The experimental tests are performed on a laboratory reactor with two working fluids: helium and air. A simple heat conduction model for calculating the heat loss is developed. By using temperature measurements in the internal and external electrodes, a thermal resistance of the reactor is defined. Finally, the percentage of the input power that is dissipated to the environment is given.

  2. Equation of Energy Injection to a Dielectric Barrier Discharge Reactor

    Science.gov (United States)

    Yao, Shuiliang; Weng, Shan; Jin, Qi; Han, Jingyi; Jiang, Boqiong; Wu, Zuliang

    2016-08-01

    The electric energy injection from a pulsed power supply to a planar type of dielectric barrier discharge (DBD) reactor at atmospheric pressure was studied. Relations of the energy injection with barrier materials, barrier thickness, peak voltage, gap distance, electrode area, and operation temperature were experimentally investigated. The energy injection is a function of relative permittivity, barrier thickness, peak voltage, gap distance, and electrode area. The influence of operation temperature on energy injection is slight in the range of 27-300 °C but becomes obvious in the range of 300-500 °C. A model was established using which the energy injection can be easily predicted. supported by National Natural Science Foundation of China (No. 11575159), Zhejiang Provincial Natural Science Foundation of China (No. LY13B070004), Program for Zhejiang Leading Team of S&T Innovation (No. 2013TD07), and National Natural Science Foundation of China (No. 51206146)

  3. Methane conversion into higher hydrocarbons with dielectric barrier discharge micro-plasma reactor

    Institute of Scientific and Technical Information of China (English)

    Baowei; Wang; Wenjuan; Yan; Wenjie; Ge; Xiaofei; Duan

    2013-01-01

    We reported a coaxial,micro-dielectric barrier discharge(micro-DBD)reactor and a conventional DBD reactor for the direct conversion of methane into higher hydrocarbons at atmospheric pressure.The effects of input power,residence time,discharge gap and external electrode length were investigated for methane conversion and product selectivity.We found the conversion of methane in a micro-DBD reactor was higher than that in a conventional DBD reactor.And at an input power of 25.0 W,the conversion of methane and the total C2+C3 selectivity reached 25.10% and 80.27%,respectively,with a micro-DBD reactor of 0.4 mm discharge gap.Finally,a nonlinear multiple regression model was used to study the correlations between both methane conversion and product selectivity and various system variables.The calculated data were obtained using SPSS 12.0 software.The regression analysis illustrated the correlations between system variables and both methane conversion and product selectivity.

  4. Experimental study on temperature characteristics and energy conversion in packed bed reactor with dielectric barrier discharge

    Science.gov (United States)

    Li, Sen; Tang, Zuchen; Gu, Fan

    2010-10-01

    The temperature characteristics and energy conversion in packed bed reactor combined with a dielectric barrier discharge (DBD) plasma was investigated experimentally. The pellet temperatures of two types packed bed reactor, cylindrical reactor and parallel-plate reactor, was measured in conditions of various inlet voltage of DBD plasma. The relationship between pellet temperature of the packed bed and applied voltage of DBD plasma was discovered. The experimental result indicates a tendency that the pellet temperature of packed bed increases as the applied voltage of inlet plasma increases. When the voltage of inlet plasma is high enough, the pellet temperature increment decreases. Simultaneously,the packed bed temperature is sensitive to the inlet plasma energy and there is a potential application to heat exchanger. Moreover the proportion of energy consumption of plasma inputting into packed bed reactor was analyzed and calculated. The mechanisms that electrical energy of inlet plasma is transformed into heat energy in the two phases, gaseous and pellets of the packed bed reactor are different. The energy consumption in pellet phase is dielectric polarization loss and depends on packed bed geometry and DBD plasma etc. The energy consumption in gaseous phase is plasma sheath procedure. The important factors effecting on gas discharge are gaseous component and voltage, frequency of power.

  5. Catalytic-Dielectric Barrier Discharge Plasma Reactor For Methane and Carbon Dioxide Conversion

    Directory of Open Access Journals (Sweden)

    Istadi Istadi

    2007-10-01

    Full Text Available A catalytic - DBD plasma reactor was designed and developed for co-generation of synthesis gas and C2+ hydrocarbons from methane. A hybrid Artificial Neural Network - Genetic Algorithm (ANN-GA was developed to model, simulate and optimize the reactor. Effects of CH4/CO2 feed ratio, total feed flow rate, discharge voltage and reactor wall temperature on the performance of catalytic DBD plasma reactor was explored. The Pareto optimal solutions and corresponding optimal operating parameters ranges based on multi-objectives can be suggested for catalytic DBD plasma reactor owing to two cases, i.e. simultaneous maximization of CH4 conversion and C2+ selectivity, and H2 selectivity and H2/CO ratio. It can be concluded that the hybrid catalytic DBD plasma reactor is potential for co-generation of synthesis gas and higher hydrocarbons from methane and carbon dioxide and showed better than the conventional fixed bed reactor with respect to CH4 conversion, C2+ yield and H2 selectivity for CO2 OCM process. © 2007 BCREC UNDIP. All rights reserved.[Presented at Symposium and Congress of MKICS 2007, 18-19 April 2007, Semarang, Indonesia][How to Cite: I. Istadi, N.A.S. Amin. (2007. Catalytic-Dielectric Barrier Discharge Plasma Reactor For Methane and Carbon Dioxide Conversion. Bulletin of Chemical Reaction Engineering and Catalysis, 2 (2-3: 37-44.  doi:10.9767/bcrec.2.2-3.8.37-44][How to Link/DOI: http://dx.doi.org/10.9767/bcrec.2.2-3.8.37-44 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/8][Cited by: Scopus 1 |

  6. A novel two-level dielectric barrier discharge reactor for methyl orange degradation.

    Science.gov (United States)

    Tao, Xumei; Wang, Guowei; Huang, Liang; Ye, Qingguo; Xu, Dongyan

    2016-12-15

    A novel pilot two-level dielectric barrier discharge (DBD) reactor has been proposed and applied for degradation of continuous model wastewater. The two-level DBD reactor was skillfully realized with high space utilization efficiency and large contact area between plasma and wastewater. Various conditions such as applied voltage, initial concentration and initial pH value on methyl orange (MO) model wastewater degradation were investigated. The results showed that the appropriate applied voltage was 13.4 kV; low initial concentration and low initial pH value were conducive for MO degradation. The percentage removal of 4 L MO with concentration of 80 mg/L reached 94.1% after plasma treatment for 80min. Based on ultraviolet spectrum (UV), Infrared spectrum (IR), liquid chromatography-mass spectrometry (LC-MS) analysis of degradation intermediates and products, insights in the degradation pathway of MO were proposed.

  7. Improvement of Dielectric Barrier Discharge Plasma Reactor for Ozone Generation by Electrode Shape

    Science.gov (United States)

    Shimizu, Masaki; Sato, Tohru; Kato, Shoji; Mukaigawa, Seiji; Takaki, Koichi; Fujiwara, Tamiya

    An effect of electrode shape on ozone generation in dielectric barrier discharge reactor is described in this article. Three different shape electrodes were employed as ground electrodes. A plane electrode is 6 cm in width, and 20 cm in length. A trench electrode has large number of knife-edge rails. A multipoint electrode has large number of four-sided pyramid projections on the plane. A high voltage plane electrode is covered with 0.5 mm thickness alumina layer worked as dielectric barrier. The experimental results show that the breakdown for the multipoint electrode occurs at 7.0 kVpp. This value is lower than 8.4 kVpp that is the breakdown voltage of the plane electrode. The ozone yield increases from 80 g/kWh to 130 g/kWh by changing the electrode shape from the plane to the multipoint. The ozone generation efficiency decreased with increase of the ozone concentration.

  8. Degradation of organic compounds and production of activated species in Dielectric Barrier Discharges and Glidarc reactors

    CERN Document Server

    Cormier, Jean Marie; Khacef, Ahmed

    2008-01-01

    Major sterilization mechanisms are related to atoms and radicals, charged parti-cles, excited molecules, ozone, and UV radiation. The ROS (Reactive Oxygen Species) are well known as evildoers. These species are easily created in ambient air and water and they live long enough to reach the cell and attack the organic matter. Test molecules conversion in dry and wet air is studied using Dielectric Barrier Discharge (DBD) and Gliding Arc Reactors (GAR). The effects of tem-perature and energy deposition into the media on the active species production and then on the organic compounds degradation are presented for two non thermal plasma reactors: DBD and GAR. Main production species investigated are OH, O3, NOx, CO and CxHyOz by-products. It is shown from experiment analysis that the reactive species production is quite different from one reactor to another. GAR and pulsed DBD are two chemical processing ways in which the temperature of heavy species in ionized gas is determinant. By reviewing the species producti...

  9. Partial oxidation of methane in a temperature-controlled dielectric barrier discharge reactor

    KAUST Repository

    Zhang, Xuming

    2015-01-01

    We studied the relative importance of the reduced field intensity and the background reaction temperature in the partial oxidation of methane in a temperature-controlled dielectric barrier discharge reactor. We obtained important mechanistic insight from studying high-temperature and low-pressure conditions with similar reduced field intensities. In the tested range of background temperatures (297 < T < 773 K), we found that the conversion of methane and oxygen depended on both the electron-induced chemistry and the thermo-chemistry, whereas the chemical pathways to the products were overall controlled by the thermo-chemistry at a given temperature. We also found that the thermo-chemistry enhanced the plasma-assisted partial oxidation process. Our findings expand our understanding of the plasma-assisted partial oxidation process and may be helpful in the design of cost-effective plasma reformers. © 2014 The Combustion Institute.

  10. Large-scale surface dielectric barrier discharge type reactor : effect of the electric wind on the conversion effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Jolibois, J. [Univ. de Poitiers, Poitiers (France). Centre national de la recherche scientifique, Laboratoire de Catalyse en Chimie Organique; Poitiers Univ., Futuroscope Chasseneuil Cedex (France). Centre national de la recherche scientifique, Inst. Pprime; Zouzou, N.; Moreau, E. [Poitiers Univ., Futuroscope Chasseneuil Cedex (France). Centre national de la recherche scientifique, Inst. Pprime; Tatibouet, J.M. [Univ. de Poitiers, Poitiers (France). Centre national de la recherche scientifique, Laboratoire de Catalyse en Chimie Organique

    2010-07-01

    Non-thermal plasma (NTP) techniques offer an innovative approach for air pollution reduction. Most studies in NTP techniques use volumetric discharge reactors with small dimensions and low flow rates at laboratory scale. The objective of this study was to develop an air pollution control plasma reactor at industrial scale with surface discharge. Propene (C{sub 3}H{sub 6}) was oxidized at high flow rates in a large-scale plasma reactor based on surface dielectric barrier discharge (DBD). Three different configurations of surface discharges were tested with 15 ppm of C{sub 3}H{sub 6} in air at ambient temperature for a flow rate of 50 m{sup 3} per hour. The properties of these different surface discharges were analyzed using chemical measurements and 3 component particle image velocimetry (PIV) measurements. PIV measurements were used characterize the effect of the electric wind on the polluted gas airflow inside the reactor and to explain the differences of effectiveness of the three tested plasma generators. For the three plasma generators, a propene oxidation of up to 45 percent was obtained at one J per liter. The electric wind produced by the surface discharge resulted in the formation of vortices inside the plasma reactor. This electric wind can increase gas mixing inside the plasma reactor and therefore plays a key role in conversion efficiency. It was concluded that the electric wind produced by surface discharges enables the use of this type of discharge for VOC elimination at high flow rate, with the same effectiveness of volumetric discharges. 5 refs., 10 figs.

  11. Methane conversion using a dielectric barrier discharge reactor at atmospheric pressure for hydrogen production

    Science.gov (United States)

    Khadir, N.; Khodja, K.; Belasri, A.

    2017-09-01

    In the present paper, we carried out a theoretical study of dielectric barrier discharge (DBD) filled with pure methane gas. The homogeneous discharge model used in this work includes a plasma chemistry unit, an electrical circuit, and the Boltzmann equation. The model was applied to the case of a sinusoidal voltage at a period frequency of 50 kHz and under a gas pressure of 600 Torr. We investigated the temporal variation of electrical and kinetic discharge parameters such as plasma and dielectric voltages, the discharge current density, electric field, deposited power density, and the species concentration. We also checked the physical model validity by comparing its results with experimental work. According to the results discussed herein, the dielectric capacitance is the parameter that has the greatest effect on the methane conversion and H2/CH4 ratio. This work enriches the knowledge for the improvement of DBD for CH4 conversion and hydrogen production.

  12. Influences of Excess Oscillation of Voltage Pulse and Discharge Mode on NO Removal Using Barrier-Type Plasma Reactor

    Science.gov (United States)

    Kadowaki, Kazunori; Suzuki, Yoshiaki; Ihori, Haruo; Kitani, Isamu

    This paper presents experimental results of NO removal from a simulated exhausted-gas using a barrier type reactor with screw electrodes subjected to polarity-reversed voltage pulses. The polarity-reversed pulse was produced by direct grounding of a charged coaxial cable because a traveling wave voltage was negatively reflected at the grounding end with a change in its polarity and then it propagated to the plasma reactor at the opposite end. Influence of cable length on NO removal was studied for two kinds of cable connection, single-connected cable and parallel-connected cables. NO removal ratio for a 50m-long cable was lower than that for much shorter cables in both single and parallel connections when the applied voltage became high. Energy efficiency for NO removal also increased with decreasing the cable length. This was because excess discharges during the voltage oscillation caused by the large stored energy in the long cable resulted in reproduction of NO molecules. Energy efficiency was further improved by changing the discharge mode from dielectric barrier discharge (DBD) to surface discharge (SD). Energy efficiency was up to 110g/kWh with 55% NO removal ratio and 34g/kWh with 100% NO removal ratio by using a single 10m-long cable in SD mode.

  13. The component content of active particles in a plasma-chemical reactor based on volume barrier discharge

    Science.gov (United States)

    Soloshenko, I. A.; Tsiolko, V. V.; Pogulay, S. S.; Terent'yeva, A. G.; Bazhenov, V. Yu; Shchedrin, A. I.; Ryabtsev, A. V.; Kuzmichev, A. I.

    2007-02-01

    In this paper the results of theoretical and experimental studies of the component content of active particles formed in a plasma-chemical reactor composed of a multiple-cell generator of active particles, based on volume barrier discharge, and a working chamber are presented. For calculation of the content of uncharged plasma components an approach is proposed which is based on averaging of the power introduced over the entire volume. Advantages of such an approach lie in an absence of fitting parameters, such as the dimensions of microdischarges, their surface density and rate of breakdown. The calculation and the experiment were accomplished with the use of dry air (20% relative humidity) as the plasma generating medium. Concentrations of O3, HNO3, HNO2, N2 O5 and NO3 were measured experimentally in the discharge volume and working chamber for the residence time of particles on a discharge of 0.3 s and more and discharge specific power of 1.5 W cm-3. It has been determined that the best agreement between the calculation and the experiment occurs at calculated gas medium temperatures in the discharge plasma of about 400-425 K, which correspond to the experimentally measured rotational temperature of nitrogen. In most cases the calculated concentrations of O3, HNO3, HNO2, N2O5 and NO3 for the barrier discharge and the working chamber are in fairly good agreement with the respective measured values.

  14. Fluid model for a partially packed dielectric barrier discharge plasma reactor

    Science.gov (United States)

    Gadkari, Siddharth; Tu, Xin; Gu, Sai

    2017-09-01

    In this work, a two-dimensional numerical fluid model is developed for a partially packed dielectric barrier discharge (DBD) in pure helium. Influence of packing on the discharge characteristics is studied by comparing the results of DBD with partial packing with those obtained for DBD with no packing. In the axial partial packing configuration studied in this work, the electric field strength was shown to be enhanced at the top surface of the spherical packing material and at the contact points between the packing and the dielectric layer. For each value of applied potential, DBD with partial packing showed an increase in the number of pulses in the current profile in the positive half cycle of the applied voltage, as compared to DBD with no packing. Addition of partial packing to the plasma-alone DBD also led to an increase in the electron and ion number densities at the moment of breakdown. The time averaged electron energy profiles showed that a much higher range of electron energy can be achieved with the use of partial packing as compared to no packing in a DBD, at the same applied power. The spatially and time averaged values over one voltage cycle also showed an increase in power density and electron energy on inclusion of partial packing in the DBD. For the applied voltage parameters studied in this work, the discharge was found to be consistently homogeneous and showed the characteristics of atmospheric pressure glow discharge.

  15. Pulsed power supply and coaxial reactor applied to E. coli elimination in water by pulsed dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Quiroz V, V. E.; Lopez C, R.; Rodriguez M, B. G.; Pena E, R.; Mercado C, A.; Valencia A, R.; Hernandez A, A. N.; Barocio, S. R.; Munoz C, A. E. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); De la Piedad B, A., E-mail: regulo.lopez@inin.gob.mx [Instituto Tecnologico de Toluca, Av. Tecnologico s/n, Ex-Rancho La Virgen, 52140 Metepec, Estado de Mexico (Mexico)

    2013-07-01

    The design and instrumentation intended for ATTC8739 Escherichia coli (E. coli) bacteria elimination in water, based on non thermal plasma generation at room pressure have been carried out by means of dielectric pulsed discharges. The latter have been produced by a power supply capable of providing voltages up to the order of 45 kV, 1-500 {mu}s pulse widths and variable frequencies between 100 Hz to 2000 Hz. This supply feeds a coaxial discharge reactor of the simple dielectric barrier type. The adequate operation of the system has been tested with the elimination of E. coli at 10{sup 4} and 10{sup 6} bacteria/ml concentrations, leading to reductions up to 85.3% and 95.1%, respectively, during the first 30 min of treatment. (Author)

  16. Electron-induced dry reforming of methane in a temperature-controlled dielectric barrier discharge reactor

    KAUST Repository

    Zhang, Xuming

    2013-09-23

    Dry reforming of methane has the potential to reduce the greenhouse gases methane and carbon dioxide and to generate hydrogen-rich syngas. In reforming methane, plasma-assisted reforming processes may have advantages over catalytic processes because they are free from coking and their response time for mobile applications is quick. Although plasma-assisted reforming techniques have seen recent developments, systematic studies that clarify the roles that electron-induced chemistry and thermo-chemistry play are needed for a full understanding of the mechanisms of plasma-assisted reformation. Here, we developed a temperature-controlled coaxial dielectric barrier discharge (DBD) apparatus to investigate the relative importance of electron-induced chemistry and thermo-chemistry in dry reforming of methane. In the tested background temperature range 297-773 K, electron-induced chemistry, as characterized by the physical properties of micro-discharges, was found to govern the conversions of CH4 and CO2, while thermo-chemistry influenced the product selectivities because they were found to depend on the background temperature. Comparisons with results from arc-jet reformation indicated that thermo-chemistry is an efficient conversion method. Our findings may improve designs of plasma-assisted reformers by using relatively hotter plasma sources. However, detailed chemical kinetic studies are needed. © 2013 IOP Publishing Ltd.

  17. Influence of the gap size and dielectric constant of the packing on the plasma discharge in a packed bed dielectric barrier discharge reactor: a fluid modeling study

    Science.gov (United States)

    van Laer, Koen; Bogaerts, Annemie

    2016-09-01

    Packed bed dielectric barrier discharge (DBD) reactors have proven to be very useful sources of non-thermal plasma for a wide range of applications, of which the environmental applications have received most attention in recent years. Compared to an empty DBD reactor, a packing was introduced to either enhance the energy efficiency of the process, or, if the packing is catalytically active, steer the process towards a preferred end product. A wide range of geometries, bead sizes and bead materials have been tested experimentally in the past. However, since experimental diagnostics become more difficult with a packing present, a computational study is proposed to gain more insight. Using COMSOL's built in plasma module, a 2D axisymmetric fluid model is developed to study the influence of the gap size and the dielectric constant (ɛ) of the packing. Helium is used as discharge gas, at atmospheric pressure and room temperature. By decreasing the gas gap, the electric field strength is enhanced, resulting in a higher number of current peaks per half cycle of applied rf potential. Increasing ɛ also enhances the electric field strength. However, after a certain ɛ, its influence saturates. The electric field strength will no longer increase, leaving the discharge behavior unchanged.

  18. Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor

    Directory of Open Access Journals (Sweden)

    Istadi Istadi

    2014-07-01

    Full Text Available Biodiesel synthesis reaction routes from palm oil using plasma electro-catalysis process over Dielectric-Barrier Discharge (DBD plasma reactor were studied. The study was focused on finding possible reaction mechanism route during plasma electro-catalysis process. The prediction was performed based on the changes of Gas Chromatography Mass Spectrometer (GC-MS and Fourier Transform Infra Red (FT-IR analyses to the biodiesel products with respect to time length of plasma treatment. It was found that main reaction mechanism occurred in the plasma electro-catalysis system was non-thermal pyrolysis rather than transesterification. The main reactions within the plasma treatment were due to collision between high energetic electrons (supplied from high voltage power supply through high voltage electrode and the reaction mixtures. The high energetic electrons affected the electrons pair of covalent bonding to be excited or dissociated even ionized at higher energy. Therefore, this plasma electro-catalysis system was promising for biodiesel synthesis from vegetable oils due to only very short time reaction was needed, even no need a catalyst, no soap formation, and no glycerol by-product. This system could produce fatty acid methyl ester yield of 75.65% at 120 seconds and other possible chemicals, such as alkynes, alkanes, esters, carboxylic acid, and aldehydes. However, during the plasma process, the reaction mechanisms were still difficult to be controlled due the action of available high energetic electrons. The advanced studies on how to control the reaction mechanism selectively in the plasma electro-catalysis will be published elsewhere. © 2014 BCREC UNDIP. All rights reservedReceived: 23rd January 2014; Revised: 20th March 2014; Accepted: 23rd March 2014[How to Cite: Istadi, I., Yudhistira, A.D., Anggoro, D.D., Buchori, L. (2014. Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor

  19. Kinetics of decolorization of azo dye by bipolar pulsed barrier discharge in a three-phase discharge plasma reactor

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Ruobing [Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China)]. E-mail: zrbingdut@163.com; Zhang Chi [Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Cheng Xingxin [Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Wang Liming [Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Wu Yan [Institute of Electrostatics and Special Power, Dalian University of Technology, Dalian 116024 (China); Guan Zhicheng [Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China)

    2007-04-02

    Removal of amaranth, a commercial synthetic azo dye widely used in the dye and food industry, was examined as a possible remediation technology for treating dye-contaminated water. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetition frequency, etc., on decolorization kinetics were investigated. Experimental results show that an aqueous solution of 24 mg/l dye is 81.24% decolorized following 30 min plasma treatment for a 50 kV voltage and 0.75 m{sup 3}/h gas flow rate. Decolorization reaction of amaranth in the plasma reactor is a pseudo first order reaction. Rate constant (k) of decolorization increases quickly with increasing the applied voltage, pulse repetition frequency and the gas flow rate. However, when the applied voltage is beyond 50 kV and increases further, increase rate of k decreases. In addition, k decreases quickly when the solution conductivity increases from 200 to 1481 {mu}S/cm. The decolorization reaction has a high rate constant (k = 0.0269 min{sup -1}) when the solution pH is beyond 10. Rate constant k decreases with the decrease of pH and reaches minimum at a pH of about 5 (k {sub min} = 0.01603 min{sup -1}), then increases to 0.02105 min{sup -1} when pH decreases to 3.07. About 15% of the initial TOC can be degraded only in about 120 min non-thermal plasma treatment.

  20. Theoretical study on the degradation reaction of octachlorinated dibenzo-p-dioxin with atomic oxygen O((3)P) in dielectric barrier discharge reactor.

    Science.gov (United States)

    Gong, Chen; Sun, Xiaomin; Zhang, Chenxi; Hu, Jingtian; Qi, Chuansong

    2014-11-01

    Dielectric barrier discharges (DBD) have been used in the degradation of dioxins due to the large number of excimers and free radicals produced in discharge process. In this article, the density functional theory (DFT) is used to study the degradation mechanism of octachlorinated dibenzo-p-dioxin (OCDD) with the atomic oxygen O((3)P) in DBD reactor. The reactants, intermediates, transition states and products are optimized at the MPWB1K/6-31+G(d,p) level. The vibrational frequencies have been calculated at the same level. The reaction pathways and mechanisms are analyzed in detail. The effect of removing the chlorine atom on environment also has been discussed.

  1. Interaction of atomized colloid with an ac electric field in a dielectric barrier discharge reactor used for deposition of nanocomposite coatings

    Science.gov (United States)

    Profili, Jacopo; Dap, Simon; Levasseur, Olivier; Naude, Nicolas; Belinger, Antoine; Stafford, Luc; Gherardi, Nicolas

    2017-02-01

    Nanocomposite thin films can be obtained by polymerization of a colloidal solution in a dielectric barrier discharge (DBD) at atmospheric pressure. In such a process, the dispersion of nanoparticles into the matrix is driven by the charging, transport, and deposition dynamics of the atomized colloid. This work examines the interaction of atomized TiO2 nanoparticles with ac electric fields in a plane-to-plane dielectric barrier discharge reactor. Experiments are performed with the discharge off to examine transport and deposition phenomena over a wide range of experimental conditions with a fixed particle charge distribution. Scanning electron microscopy reveals that the size distribution of TiO2 nanoparticles collected at different locations along the substrate surface placed on the bottom electrode of the DBD reactor can judiciously be controlled by varying the amplitude and frequency of the ac electric field. These results are also compared to the predictions of a simple particle motion model accounting for the electrostatic force, the gravitational force, and the neutral drag force in the laminar flow. It is found that while the initial charge distribution of atomized particles strongly influences the total deposition yield, its maximal position on the substrate, and the width of the deposited area, the initial size distribution of the particles at the entrance of the reactor mostly changes the size distribution at each position along the substrate surface.

  2. Dynamics of the atmospheric pressure diffuse dielectric barrier discharge between cylindrical electrodes in roll-to-roll PECVD reactor

    Science.gov (United States)

    Starostin, Sergey A.; Welzel, Stefan; Liu, Yaoge; van der Velden-Schuermans, Bernadette; Bouwstra, Jan B.; van de Sanden, Mauritius C. M.; de Vries, Hindrik W.

    2015-07-01

    The high current diffuse dielectric barrier discharge (DBD) was operated in a bi-axial cylindrical electrode configuration using nitrogen, oxygen and argon gas flow with the addition of tetraethyl orthosilicate as precursor for silica-like film deposition. The behaviour of the transient plasma was visualized by means of fast imaging from two orthogonal directions. The formation and propagation (~3 × 104 m s-1) of lateral ionization waves with the transverse light emission structure similar to the low pressure glow discharge was observed at time scales below 1 µs. Despite plasma non-uniformity at nanosecond time scale the deposition process on the web-rolled polymer results in smooth well adherent films with good film uniformity and excellent gas diffusion barrier properties. Contribution to the topical issue "The 14th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XIV)", edited by Nicolas Gherardi, Ronny Brandenburg and Lars Stollenwark

  3. Plasma-catalytic hydrogenation of CO2 for the cogeneration of CO and CH4 in a dielectric barrier discharge reactor: effect of argon addition

    Science.gov (United States)

    Zeng, Yuxuan; Tu, Xin

    2017-05-01

    Plasma-catalytic CO2 hydrogenation over a Ni/Al2O3 catalyst for the cogeneration of CO and CH4 has been carried out in a dielectric barrier discharge (DBD) reactor at 150 °C. The presence of the Ni catalyst in the DBD reactor has clearly demonstrated a plasma-catalytic synergistic effect at low temperatures, as the reaction performance of the plasma-catalytic CO2 hydrogenation is significantly higher than that of the sum of the individual processes (plasma process and thermal catalytic process) at the same temperature. The addition of argon (up to 60%) in the reaction enhances the conversion of CO2, the yield of CO and CH4 and the energy efficiency of the plasma process. The formation of metastable argon (Ar*) in the plasma could create new reaction routes which make a significant contribution to the enhanced CO2 conversion and production of CO and CH4. The introduction of Ar decreases the breakdown voltage of the feed gas and promotes charge transfer through the reactor. In addition, we find that the selectivity of CO is almost independent of the Ar content in the feed gas, while increasing the Ar content from 0 to 60% enhances the CH4 selectivity by 85%. This phenomenon suggests that the presence of Ar* might promote the methanation of CO and CO2 with hydrogen at low temperatures. Moreover, the molar ratio of CO/CH4 in the plasma-catalytic hydrogenation of CO2 can also be controlled by changing the Ar content in the feed gas.

  4. Studying barrier-discharge-stimulated plasmachemical reactions

    Science.gov (United States)

    Malanichev, V. E.; Malashin, M. V.; Moshkunov, S. I.; Nebogatkin, S. V.; Khomich, V. Yu.; Shmelev, V. M.

    2017-05-01

    Barrier-discharge stimulation of chemical reactions has been studied in the case of methane oxidation by atmospheric oxygen with the formation of carbon monoxide and hydrogen. Experiments in a plasmachemical reactor demonstrated the possibility of increasing the yield of synthesis gas (syngas) by means of plasma pretreatment of the initial mixture of air and methane in a 7: 1 ratio at atmospheric pressure. The output-gas composition was determined by gas chromatography. It is established that the plasma-discharge treatment of the initial gas mixture leads to a 15% increase in the amount of syngas at the reactor output and increases the reaction selectivity with respect to hydrogen and carbon monoxide by 3.2 and 6.5%, respectively.

  5. Dielectric barrier discharges in analytical chemistry.

    Science.gov (United States)

    Meyer, C; Müller, S; Gurevich, E L; Franzke, J

    2011-06-21

    The present review reflects the importance of dielectric barrier discharges in analytical chemistry. Special about this discharge is-and in contrast to usual discharges with direct current-that the plasma is separated from one or two electrodes by a dielectric barrier. This gives rise to two main features of the dielectric barrier discharges; it can serve as dissociation and excitation device and as ionization mechanism, respectively. The article portrays the various application fields for dielectric barrier discharges in analytical chemistry, for example the use for elemental detection with optical spectrometry or as ionization source for mass spectrometry. Besides the introduction of different kinds of dielectric barrier discharges used for analytical chemistry from the literature, a clear and concise classification of dielectric barrier discharges into capacitively coupled discharges is provided followed by an overview about the characteristics of a dielectric barrier discharge concerning discharge properties and the ignition mechanism.

  6. Roles of individual radicals generated by a submerged dielectric barrier discharge plasma reactor during Escherichia coli O157:H7 inactivation

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Muhammad Saiful Islam [Department of Food Biotechnology, University of Science and Technology, Daejeon, 305-350 (Korea, Republic of); Lee, Eun-Jung [Food Safety Research Group, Korea Food Research Institute, Seongnam-si, Gyeonggi-Do (Korea, Republic of); Kim, Yun-Ji, E-mail: yunji@kfri.re.kr [Department of Food Biotechnology, University of Science and Technology, Daejeon, 305-350 (Korea, Republic of); Food Safety Research Group, Korea Food Research Institute, Seongnam-si, Gyeonggi-Do (Korea, Republic of)

    2015-10-15

    A submerged dielectric barrier discharge plasma reactor (underwater DBD) has been used on Escherichia coli O157:H7 (ATCC 35150). Plasma treatment was carried out using clean dry air gas to investigate the individual effects of the radicals produced by underwater DBD on an E. coli O157:H7 suspension (8.0 log CFU/ml). E. coli O157:H7 was reduced by 6.0 log CFU/ml for 2 min of underwater DBD plasma treatment. Optical Emission Spectra (OES) shows that OH and NO (α, β) radicals, generated by underwater DBD along with ozone gas. E. coli O157:H7 were reduced by 2.3 log CFU/ml for 10 min of underwater DBD plasma treatment with the terephthalic acid (TA) OH radical scavenger solution, which is significantly lower (3.7 log CFU/ml) than the result obtained without using the OH radical scavenger. A maximum of 1.5 ppm of ozone gas was produced during the discharge of underwater DBD, and the obtained reduction difference in E.coli O157:H7 in presence and in absence of ozone gas was 1.68 log CFU/ml. The remainder of the 0.62 log CFU/ml reduction might be due to the effect of the NO (α, β) radicals or due to the combined effect of all the radicals produced by underwater DBD. A small amount of hydrogen peroxide was also generated but does not play any role in E. coli O157:H7 inactivation.

  7. Roles of individual radicals generated by a submerged dielectric barrier discharge plasma reactor during Escherichia coli O157:H7 inactivation

    Directory of Open Access Journals (Sweden)

    Muhammad Saiful Islam Khan

    2015-10-01

    Full Text Available A submerged dielectric barrier discharge plasma reactor (underwater DBD has been used on Escherichia coli O157:H7 (ATCC 35150. Plasma treatment was carried out using clean dry air gas to investigate the individual effects of the radicals produced by underwater DBD on an E. coli O157:H7 suspension (8.0 log CFU/ml. E. coli O157:H7 was reduced by 6.0 log CFU/ml for 2 min of underwater DBD plasma treatment. Optical Emission Spectra (OES shows that OH and NO (α, β radicals, generated by underwater DBD along with ozone gas. E. coli O157:H7 were reduced by 2.3 log CFU/ml for 10 min of underwater DBD plasma treatment with the terephthalic acid (TA OH radical scavenger solution, which is significantly lower (3.7 log CFU/ml than the result obtained without using the OH radical scavenger. A maximum of 1.5 ppm of ozone gas was produced during the discharge of underwater DBD, and the obtained reduction difference in E.coli O157:H7 in presence and in absence of ozone gas was 1.68 log CFU/ml. The remainder of the 0.62 log CFU/ml reduction might be due to the effect of the NO (α, β radicals or due to the combined effect of all the radicals produced by underwater DBD. A small amount of hydrogen peroxide was also generated but does not play any role in E. coli O157:H7 inactivation.

  8. Plasma spark discharge reactor and durable electrode

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Young I.; Cho, Daniel J.; Fridman, Alexander; Kim, Hyoungsup

    2017-01-10

    A plasma spark discharge reactor for treating water. The plasma spark discharge reactor comprises a HV electrode with a head and ground electrode that surrounds at least a portion of the HV electrode. A passage for gas may pass through the reactor to a location proximate to the head to provide controlled formation of gas bubbles in order to facilitate the plasma spark discharge in a liquid environment.

  9. Dielectric barrier discharges applied for optical spectrometry

    Science.gov (United States)

    Brandt, S.; Schütz, A.; Klute, F. D.; Kratzer, J.; Franzke, J.

    2016-09-01

    The present review reflects the importance of dielectric barrier discharges for optical spectrometric detection in analytical chemistry. In contrast to usual discharges with a direct current the electrodes are separated by at least one dielectric barrier. There are two main features of the dielectric barrier discharges: they can serve as dissociation and excitation devices as well as ionization sources, respectively. This article portrays various application fields of dielectric barrier discharges in analytical chemistry used for elemental and molecular detection with optical spectrometry.

  10. The electrical characteristics of the dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Yehia, Ashraf, E-mail: yehia30161@yahoo.com [Department of Physics, College of Science and Humanitarian Studies at Alkharj, Prince Sattam bin Abdulaziz University, P.O. Box 83, Alkharj 11942 (Saudi Arabia); Department of Physics, Faculty of Science, Assiut University, Assiut 71516 (Egypt)

    2016-06-15

    The electrical characteristics of the dielectric barrier discharges have been studied in this paper under different operating conditions. The dielectric barrier discharges were formed inside two reactors composed of electrodes in the shape of two parallel plates. The dielectric layers inside these reactors were pasted on the surface of one electrode only in the first reactor and on the surfaces of the two electrodes in the second reactor. The reactor under study has been fed by atmospheric air that flowed inside it with a constant rate at the normal temperature and pressure, in parallel with applying a sinusoidal ac voltage between the electrodes of the reactor. The amount of the electric charge that flows from the reactors to the external circuit has been studied experimentally versus the ac peak voltage applied to them. An analytical model has been obtained for calculating the electrical characteristics of the dielectric barrier discharges that were formed inside the reactors during a complete cycle of the ac voltage. The results that were calculated by using this model have agreed well with the experimental results under the different operating conditions.

  11. Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S., E-mail: cswong@um.edu.my [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-04-15

    The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50 Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

  12. Pathway Study on Dielectric Barrier Discharge Plasma Conversion of Hexane

    NARCIS (Netherlands)

    Agiral, Anil; Boyadjian, Cassia; Seshan, K.; Lefferts, Leon; Gardeniers, J.G.E. (Han)

    2010-01-01

    A plasma reactor based on dielectric barrier discharge has been developed for oxidative cracking of hexane to yield olefins at atmospheric pressure. Dissociation of hexane in the presence of oxygen with nonequilibrium plasma state represents complex chemistry, and both conversion and product selecti

  13. Filament Discharge Phenomena in Fingerprint Acquisition by Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    WENG Ming; XU Weijun; LIU Qiang

    2007-01-01

    In this paper, the dielectric barrier discharge fingerprint acquisition technique is introduced. The filament discharge phenomena were observed in the process of fingerprint acquisition. The filament discharge reduced the quality of fingerprint images. Obviously, it was necessary to eliminate streamer discharges in order to get good fingerprint images. The streamer discharge was considered to be the cause of the filament discharge in the experiment. The relationship between the critical electric field and the discharge gap was calculated with the Raether's model of streamer discharge. The calculated results and our experiment proved that it would be difficult for the streamer discharge to occur when the discharge gap was narrow. With a narrow discharge gap, the discharge was homogeneous, and the fingerprint images were clear and large in area. The images obtained in the experiment are very suitable for fingerprint identification as they contain more information.

  14. Numerical investigation of dielectric barrier discharges

    Science.gov (United States)

    Li, Jing

    1997-12-01

    A dielectric barrier discharge (DBD) is a transient discharge occurring between two electrodes in coaxial or planar arrangements separated by one or two layers of dielectric material. The charge accumulated on the dielectric barrier generates a field in a direction opposite to the applied field. The discharge is quenched before an arc is formed. It is one of the few non-thermal discharges that operates at atmospheric pressure and has the potential for use in pollution control. In this work, a numerical model of the dielectric barrier discharge is developed, along with the numerical approach. Adaptive grids based on the charge distribution is used. A self-consistent method is used to solve for the electric field and charge densities. The Successive Overrelaxation (SOR) method in a non-uniform grid spacing is used to solve the Poisson's equation in the cylindrically-symmetric coordinate. The Flux Corrected Transport (FCT) method is modified to solve the continuity equations in the non-uniform grid spacing. Parametric studies of dielectric barrier discharges are conducted. General characteristics of dielectric barrier discharges in both anode-directed and cathode-directed streamer are studied. Effects of the dielectric capacitance, the applied field, the resistance in external circuit and the type of gases (O2, air, N2) are investigated. We conclude that the SOR method in an adaptive grid spacing for the solution of the Poisson's equation in the cylindrically-symmetric coordinate is convergent and effective. The dielectric capacitance has little effect on the g-factor of radical production, but it determines the strength of the dielectric barrier discharge. The applied field and the type of gases used have a significant role on the current peak, current pulse duration and radical generation efficiency, discharge strength, and microstreamer radius, whereas the external series resistance has very little effect on the streamer properties. The results are helpful in

  15. Mechanism of Striation in Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    FENG Shuo; HE Feng; OUYANG Ji-Ting

    2007-01-01

    @@ The mechanism of striations in dielectric barrier discharge in pure neon is studied by a two-dimensional particlein-cell/Monte Carlo collision (PIC-MCC) model. It is shown that the striations appear in the plasma background,and non-uniform electrical field resulting from ionization and the negative wall charge appear on the dielectric layer above the anode. The sustainment of striations is a non-local kinetic effect of electrons in a stratified field controlled by non-elastic impact with neutral gases. The striations in the transient dielectric barrier discharge are similar to those in dc positive column discharge.

  16. Application of dielectric surface barrier discharge for food storage

    Directory of Open Access Journals (Sweden)

    Yassine BELLEBNA

    2015-12-01

    Full Text Available Ozone (O3 is a powerful oxidizer and has much higher disinfection potential than chlorine and other disinfectants. Ozone finds its application mainly in water treatment and air purification Dielectric barrier discharge (DBD method has proved to be the best method to produce ozone. Dried air or oxygen is forced to pass through a 1-2 mm gap. The aim of this study was to show that disinfection system using ozone generated by dielectric barrier discharge (DBD is an effective alternative to be used in food industry and ensures a safe quality of air for optimum preservation of fruits and vegetables. The DBDs are specific kind of discharges because one (or sometimes both electrodes is covered by a dielectric material, thereby preventing the discharge to move towards electrical breakdown. A succession of microdischarges occurs rapidly; their "lifetime" is in the range of a few nanoseconds. One of their most important applications is the production of ozone for air treatment, used mainly in the area of food industry, for extending the storage life of foods. After the achievement of a surface DBD reactor of cylindrical shape and its electrical characterization, it was then used as an ozone generator for air disinfection. Obtained results have shown that this reactor used as an ozone generator is effective for disinfection of air by removing viruses, bacteria and pathogens, causing the slowdown of the ripening process of fruits and vegetables.

  17. Dielectric barrier discharge source for supersonic beams

    Energy Technology Data Exchange (ETDEWEB)

    Luria, K.; Lavie, N.; Even, U. [Sackler School of Chemistry, Tel Aviv University, Tel Aviv 69978 (Israel)

    2009-10-15

    We present a new excitation source for pulsed supersonic beams. The excitation is based on dielectric barrier discharge in the beam. It produces cold beams of metastable atoms, dissociated neutral atoms from molecular precursors, and both positive and negative ions with high efficiency and reliability.

  18. Performance of a large-scale barrier discharge plume improved by an upstream auxiliary barrier discharge

    Science.gov (United States)

    Li, Xuechen; Chu, Jingdi; Zhang, Qi; Zhang, Panpan; Jia, Pengying; Geng, Jinling

    2016-11-01

    Enhanced by an upstream auxiliary dielectric barrier discharge (ADBD), a transverse barrier discharge plume with a fairly large scale is generated downstream of a narrow slit. Electrical and optical characteristics are compared for the two discharges with and without the ADBD. Results indicate that the plume with the ADBD is longer, more uniform, and dissipates a higher power. Moreover, its inception voltage is much lower. High-speed imaging presents that the uniform plasma plume with the ADBD comprises a series of moving micro-discharge filaments in a glow regime, which are much smoother than those without the ADBD.

  19. Properties Influencing Plasma Discharges in Packed Bed Reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Kushner, Mark J.

    2016-09-01

    Atmospheric pressure dielectric barrier discharges (DBDs) sustained in packed bed reactors (PBRs) are being investigated for CO2 removal and conversion of waste gases into higher value compounds. We report on results of a computational investigation of PBR-DBD properties using the plasma hydrodynamics simulator nonPDPSIM with a comparison to experiments. Dielectric beads (rods in 2D) were inserted between two coplanar electrodes, 1 cm apart filled by humid air. A step-pulse of -30 kV was applied to the top electrode. Material properties of the beads (dielectric constant, secondary emission coefficient) and gas properties (photoionization and photo-absorption cross-sections, temperature) were varied. We found that photoionization plays a critical role in the propagation of the discharge through the PBR, as it serves to seed charges in regions of high electric field. Increasing rates of photo-ionization enable increases in the discharge propagation velocity, ionization rates and production of radicals. A transition between DBD-like and arc-like discharges occurs as the radiation mean free path decreases. Increasing the dielectric constant of the beads increased electric fields in the gas, which translated to increased discharge propagation velocity and charge density until ɛ/ɛ0 100. Secondary electron emission coefficient and gas temperature have minimal impacts on the discharge propagation though the latter did affect the production of reactive species. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  20. Dielectric barrier discharge processing of aerospace materials

    Science.gov (United States)

    Scott, S. J.; Figgures, C. C.; Dixon, D. G.

    2004-08-01

    We report the use of atmospheric pressure, air based, dielectric barrier discharges (DBD) to treat materials commonly used in the aerospace industries. The material samples were processed using a test-bed of a conventional DBD configuration in which the sample formed one of the electrodes and was placed in close proximity to a ceramic electrode. The discharges generated a powerful, cold oxidizing environment which was able to remove organic contaminants, etch primer and paint layers, oxidize aluminium and roughen carbon fibre composites by the selective removal of resin.

  1. Electrical model of dielectric barrier discharge homogenous and filamentary modes

    Science.gov (United States)

    López-Fernandez, J. A.; Peña-Eguiluz, R.; López-Callejas, R.; Mercado-Cabrera, A.; Valencia-Alvarado, R.; Muñoz-Castro, A.; Rodríguez-Méndez, B. G.

    2017-01-01

    This work proposes an electrical model that combines homogeneous and filamentary modes of an atmospheric pressure dielectric barrier discharge cell. A voltage controlled electric current source has been utilized to implement the power law equation that represents the homogeneous discharge mode, which starts when the gas breakdown voltage is reached. The filamentary mode implies the emergence of electric current conducting channels (microdischarges), to add this phenomenon an RC circuit commutated by an ideal switch has been proposed. The switch activation occurs at a higher voltage level than the gas breakdown voltage because it is necessary to impose a huge electric field that contributes to the appearance of streamers. The model allows the estimation of several electric parameters inside the reactor that cannot be measured. Also, it is possible to appreciate the modes of the DBD depending on the applied voltage magnitude. Finally, it has been recognized a good agreement between simulation outcomes and experimental results.

  2. Modes of Homogeneous Barrier Discharge at Atmospheric Pressure in Helium

    Institute of Scientific and Technical Information of China (English)

    WANG Yan-Hui; WANG De-Zhen

    2004-01-01

    @@ The discharge modes of a homogeneous barrier discharge at atmospheric pressure in helium are investigated with a one-dimensional fluid model It is found that, either in single peak discharge or in multipeak discharge, there are two discharge modes: glow and Townsend modes. The structure and features of the two modes are compared.The conditions forming the two modes are discussed.

  3. Spent nuclear fuel discharges from U.S. reactors 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    Spent Nuclear Fuel Discharges from US Reactors 1994 provides current statistical data on fuel assemblies irradiated at commercial nuclear reactors operating in the US. This year`s report provides data on the current inventories and storage capacities at these reactors. Detailed statistics on the data are presented in four chapters that highlight 1994 spent fuel discharges, storage capacities and inventories, canister and nonfuel component data, and assembly characteristics. Five appendices, a glossary, and bibliography are also included. 10 figs., 34 tabs.

  4. Conversion of methane through dielectric-barrier discharge plasma

    Institute of Scientific and Technical Information of China (English)

    Baowei WANG; Xiaolei CAO; Kuanhui YANG; Genhui XU

    2008-01-01

    Methane coupling to produce C2 hydrocar-bons through a dielectric-barrier discharge (DBD) plasma reaction was studied in four DBD reactors. The effects of high voltage electrode position, different discharge gap, types of inner electrode, volume ratio of hydrogen to methane and air cooling method on the conversion of methane and distribution of products were investigated. Conversion of methane is obviously lower when a high voltage electrode acts as an outer electrode than when it acts as an inner electrode. The lifting of reaction temper-ature becomes slow due to cooling of outer electrode and the temperature can be controlled in the expected range of 60℃-150℃ for ensuring better methane conversion and safe operation. The parameters of reactors have obvious effects on methane conversion, but it only slightly affects distribution of the products. The main products are ethyl-ene, ethane and propane. The selectivity of C2 hydrocar-bons can reach 74.50% when volume ratio of hydrogen to methane is 1.50.

  5. Dielectric Barrier Discharge Characteristics of Multineedle-to-Cylinder Configuration

    Directory of Open Access Journals (Sweden)

    Caixin Sun

    2011-12-01

    Full Text Available A dielectric barrier discharge (DBD produces a homogenous discharge with low energy consumption, offering broad developmental prospects, and this discharge process is also the mechanism through which charges are transported. Higher reaction efficiency is achieved when more charges are transported. Focusing on the electrode configuration of the multineedle-to-cylinder (MC system, i.e., the structure of needles arrayed on the inner coaxial rod, the effect of needle arrangement, including needle length (NL, inter axial needle distance (ID, and inter axial needle rotation angle (INRA, on the transported charge per cycle and discharge power in DBDs is investigated. The finite-element method (FEM and quasi-static field simulation are adopted to study the active region (AR where the electric field strength exceeds the breakdown electric field strength between MC electrodes because this region plays a dominant role in DBD. The improvement of its volume ratio in the reactor allows an increase in discharge power. The simulation results are in accordance with the experimental results, which illustrate that quasi-static field simulation is effective and reliable. Simulation results show that mutual effects of nearby needles and between needles and the inner rod exist. As a result, shorter ID (1.5 mm, needles with similar lengths (3.5 mm are arranged, and an INRA of 0° is proven to be the optimal structure because it produces the highest AR volume ratio. The result is experimentally validated by transported charges per cycle and discharge power obtained through Lissajous figures.

  6. Dielectric barrier discharge plasma induced degradation of aqueous atrazine.

    Science.gov (United States)

    Feng, Jingwei; Jiang, Lin; Zhu, Dan; Su, Kuizu; Zhao, Dayong; Zhang, Jibiao; Zheng, Zheng

    2016-05-01

    Degradation of herbicide atrazine in aqueous solution was investigated using a plate type dielectric barrier discharge (DBD) plasma reactor. DBD plasma was generated at the gas-liquid interface of the formed water film. At discharge time of 14 min, atrazine was degradated effectively with a degradation rate of 99 % at the discharge power of 200 W. The experimental data fitted well with first-order kinetics and the energy efficiency for 90 % degradation of atrazine (G value) was calculated, obtaining a rate constant of 0.35 min(-1) and a G value of 1.27 × 10(-10) mol J(-1) (98.76 mg kW(-1) h(-1)) at a discharge power of 200 W, respectively. The addition of Fe(2+) increased the rate constant and G value dramatically, and a significant decrease of the rate constant and G value was observed with the addition of radical scavengers (tert-butyl alcohol, isopropyl alcohol, or Na2CO3). The generated aqueous O3 and H2O2 were determined, which promoted the degradation of herbicide atrazine. Dechlorination was observed and the experimentally detected Cl(-) was 1.52 mg L(-1) at a discharge time of 14 min. The degradation intermediates of atrazine were detected by means of liquid chromatography-mass spectrometry; dechlorination, hydroxylation, dealkylation, and alkyl oxidation processes were involved in the degradation pathways of atrazine.

  7. Reactor-specific spent fuel discharge projections, 1987-2020

    Energy Technology Data Exchange (ETDEWEB)

    Walling, R.C.; Heeb, C.M.; Purcell, W.L.

    1988-03-01

    The creation of five reactor-specific spent fuel data bases that contain information on the projected amounts of spent fuel to be discharged from U.S. commercial nuclear reactors through the year 2020 is described. The data bases contain detailed spent fuel information from existing, planned, and projected pressurized water reactors (PWR) and boiling water eactors (BWR), and one existing high temperature gas reactor (HTGR). The projections are based on individual reactor information supplied by the U.S. reactor owners. The basic information is adjusted to conform to Energy Information Administration (EIA) forecasts for nuclear installed capacity, generation, and spent fuel discharged. The EIA cases considered are: No New Orders (assumes increasing burnup), No New Orders with No Increased Burnup, Upper Reference (assumes increasing burnup), Upper Reference with No Increased Burnup, and Lower Reference (assumes increasing burnup). Detailed, by-reactor tables are provided for annual discharged amounts of spent fuel, for storage requirements assuming maximum at-reactor storage, and for storage requirements assuming maximum at-reactor storage plus intra-utility transshipment of spent fuel. 8 refs., 8 figs., 10 tabs.

  8. Reactor-specific spent fuel discharge projections: 1986 to 2020

    Energy Technology Data Exchange (ETDEWEB)

    Heeb, C.M.; Walling, R.C.; Purcell, W.L.

    1987-03-01

    The creation of five reactor-specific spent fuel data bases that contain information on the projected amounts of spent fuel to be discharged from US commercial nuclear reactors through the year 2020 is described. The data bases contain detailed spent-fuel information from existing, planned, and projected pressurized water reactors (PWR) and boiling water reactors (BWR). The projections are based on individual reactor information supplied by the US reactor owners. The basic information is adjusted to conform to Energy Information Agency (EIA) forecasts for nuclear installed capacity, generation, and spent fuel discharged. The EIA cases considered are: (1) No new orders with extended burnup, (2) No new orders with constant burnup, (3) Upper reference (which assumes extended burnup), (4) Upper reference with constant burnup, and (5) Lower reference (which assumes extended burnup). Detailed, by-reactor tables are provided for annual discharged amounts of spent fuel, for storage requirements assuming maximum-at-reactor storage, and for storage requirements assuming maximum-at-reactor plus intra-utility transshipment of spent fuel. 6 refs., 8 figs., 8 tabs.

  9. Reactor-specific spent fuel discharge projections, 1987-2020

    Energy Technology Data Exchange (ETDEWEB)

    Walling, R.C.; Heeb, C.M.; Purcell, W.L.

    1988-03-01

    The creation of five reactor-specific spent fuel data bases that contain information on the projected amounts of spent fuel to be discharged from U.S. commercial nuclear reactors through the year 2020 is described. The data bases contain detailed spent fuel information from existing, planned, and projected pressurized water reactors (PWR) and boiling water eactors (BWR), and one existing high temperature gas reactor (HTGR). The projections are based on individual reactor information supplied by the U.S. reactor owners. The basic information is adjusted to conform to Energy Information Administration (EIA) forecasts for nuclear installed capacity, generation, and spent fuel discharged. The EIA cases considered are: No New Orders (assumes increasing burnup), No New Orders with No Increased Burnup, Upper Reference (assumes increasing burnup), Upper Reference with No Increased Burnup, and Lower Reference (assumes increasing burnup). Detailed, by-reactor tables are provided for annual discharged amounts of spent fuel, for storage requirements assuming maximum at-reactor storage, and for storage requirements assuming maximum at-reactor storage plus intra-utility transshipment of spent fuel. 8 refs., 8 figs., 10 tabs.

  10. Statistical modelling of discharge behavior of atmospheric pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Tay, W. H.; Kausik, S. S.; Wong, C. S., E-mail: cswong@um.edu.my; Yap, S. L.; Muniandy, S. V. [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-11-15

    In this work, stochastic behavior of atmospheric pressure dielectric barrier discharge (DBD) has been investigated. The experiment is performed in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes powered by a 50 Hz ac high voltage source. Current pulse amplitude distributions for different space gaps and the time separation between consecutive current pulses are studied. A probability distribution function is proposed to predict the experimental distribution function for the current pulse amplitudes and the occurrence of the transition regime of the pulse distribution. Breakdown voltage at different positions on the dielectric surface is suggested to be stochastic in nature. The simulated results based on the proposed distribution function agreed well with the experimental results and able to predict the regime of transition voltage. This model would be useful for the understanding of stochastic behaviors of DBD and the design of DBD device for effective operation and applications.

  11. Abatement of malodorants from pesticide factory in dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Chen Jie; Yang Jiantao; Pan Hua; Su Qingfa; Liu Yamin [Institute of Industrial Ecology and Environment, Zhejiang University (Yuquan Campus) Hangzhou 310027 (China); Shi Yao, E-mail: shiyao@zju.edu.cn [Institute of Industrial Ecology and Environment, Zhejiang University (Yuquan Campus) Hangzhou 310027 (China)

    2010-05-15

    Traditional odor control methods are limitative technically and economically for the abatement of odor from pesticide factory due to its toxicity and complicated composition. Non-thermal plasma (NTP) methods, typically characterized by high removal efficiency, energy yields and good economy, offer possible alternative solutions. This paper provides laboratory scale experimental data on the removal of simulated odors from pesticide factory with various humidity (0-0.8 vol%) and oxygen contents (0-21%) by a dielectric barrier discharge (DBD) reactor. Peak voltage and initial dimethylamine (DML) concentration are important factors that influence the DML removal efficiency and energy yield. The conversion of DML of 761 mg/m{sup 3} reaches 100% at a peak voltage of 41.25 kV. Under the experiment conditions, the conversion of DML increases with an increase of oxygen contents. And the highest DML conversion was achieved with the gas stream containing 0.3% water. Simultaneously, the concentration of O{sub 3} and OH radical in reactor was measured. Higher conversion, higher energy yield and fewer byproducts were found in mixed odor (DML + dimethyl sulfide (DMS)) treatment than that in single odor treatment. The energy yield is promoted from 2.13 to 5.20 mg/kJ.

  12. Effects of pulse-to-pulse residual species on discharges in repetitively pulsed discharges through packed bed reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Kushner, Mark J.

    2016-09-01

    Atmospheric pressure dielectric barrier discharges (DBDs) sustained in packed bed reactors (PBRs) are being investigated for conversion of toxic and waste gases, and CO2 removal. These discharges are repetitively pulsed having varying flow rates and internal geometries, which results in species from the prior pulse still being in the discharge zone at the time the following discharge pulse occurs. A non-negligible residual plasma density remains, which effectively acts as preionization. This residual charge changes the discharge properties of subsequent pulses, and may impact important PBR properties such as chemical selectivity. Similarly, the residual neutral reactive species produced during earlier pulses will impact the reaction rates on subsequent pulses. We report on results of a computational investigation of a 2D PBR using the plasma hydrodynamics simulator nonPDPSIM. Results will be discussed for air flowing though an array of dielectric rods at atmospheric pressure. The effects of inter-pulse residual species on PBR discharges will be quantified. Means of controlling the presence of residual species in the reactor through gas flow rate, pulse repetition, pulse width and geometry will be described. Comparisons will be made to experiments. Work supported by US DOE Office of Fusion Energy Science and the National Science Foundation.

  13. The Effect of Dielectric Barrier Discharge Plasma Treatment on the Microorganisms Found in Raw Cow’s Milk

    OpenAIRE

    Aslan, Yakup

    2016-01-01

    Milk is an essential source of nutrition especially for the breastfed infants. Sterilization of milk is necessary because it can be contaminated by microorganisms due to unhygienic collection and storage conditions. In this study, the sterilization of raw cow milk was performed by using dielectric barrier discharge (DBD) plasma method. Raw milk was transferred to the plasma reactor and dielectric barrier discharge cold plasma was performed by changing various parameters including voltage, exp...

  14. Formaldehyde removal from gas streams by means of NaNO2 dielectric barrier discharge plasma.

    Science.gov (United States)

    Liang, Wen-Jun; Li, Jian; Li, Jing-Xin; Zhu, Tao; Jin, Yu-Quan

    2010-03-15

    Destruction of formaldehyde by means of NaNO2 ferro-electric packed bed dielectric barrier discharge plasma in a coaxial cylindrical reactor was carried out at atmospheric pressure and room temperature. The difference among four kinds of NaNO2 ferro-electric reactors was compared in terms of specific energy density (SED), energy yield (EY), and HCHO decomposition. In addition, by-products during the decomposition of HCHO and destruction mechanism were also investigated. The removal efficiency of HCHO increased by means of NaNO2 DBD plasma significantly and enhanced with increasing SED distinctly. More amount of NaNO2 contributed to higher HCHO removal efficiency in the reactors. Reactor C had the highest HCHO removal efficiency among the reactors. As an important by-product, ozone concentration increased with higher SED. The possible main products in the outlet effluent were CO, CO(2) and H(2)O.

  15. Reactor-specific spent fuel discharge projections, 1984 to 2020

    Energy Technology Data Exchange (ETDEWEB)

    Heeb, C.M.; Libby, R.A.; Holter, G.M.

    1985-04-01

    The original spent fuel utility data base (SFDB) has been adjusted to produce agreement with the EIA nuclear energy generation forecast. The procedure developed allows the detail of the utility data base to remain intact, while the overall nuclear generation is changed to match any uniform nuclear generation forecast. This procedure adjusts the weight of the reactor discharges as reported on the SFDB and makes a minimal (less than 10%) change in the original discharge exposures in order to preserve discharges of an integral number of fuel assemblies. The procedure used in developing the reactor-specific spent fuel discharge projections, as well as the resulting data bases themselves, are described in detail in this report. Discussions of the procedure cover the following topics: a description of the data base; data base adjustment procedures; addition of generic power reactors; and accuracy of the data base adjustments. Reactor-specific discharge and storage requirements are presented. Annual and cumulative discharge projections are provided. Annual and cumulative requirements for additional storage are shown for the maximum at-reactor (AR) storage assumption, and for the maximum AR with transshipment assumption. These compare directly to the storage requirements from the utility-supplied data, as reported in the Spent Fuel Storage Requirements Report. The results presented in this report include: the disaggregated spent fuel discharge projections; and disaggregated projections of requirements for additional spent fuel storage capacity prior to 1998. Descriptions of the methodology and the results are included in this report. Details supporting the discussions in the main body of the report, including descriptions of the capacity and fuel discharge projections, are included. 3 refs., 6 figs., 12 tabs.

  16. Decomposing Nitrous Oxide Thruster using Dielectric Barrier Discharge Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The University of Maryland is proposing to use a dielectric barrier discharge (DBD) as a means to dissociate N2O. DBD uses alternating high voltage differences...

  17. Study on the transition from filamentary discharge to diffuse discharge by using a dielectric barrier surface discharge device

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Discharge characteristics have been investigated in different gases under different pressures using a dielectric barrier surface discharge device. Electrical measurements and optical emission spectroscopy are used to study the discharge,and the results obtained show that the discharges in atmospheric pressure helium and in low-pressure air are diffuse,while that in high-pressure air is filamentary. With decreasing pressure, the discharge in air can transit from filamentary to diffuse one. The results also indicate that corona discharge around the stripe electrode is important for the diffuse discharge. The spectral intensity of N2+ (391.4 nm) relative to N2 (337.1 nm) is measured during the transition from diffuse to filamentary discharge. It is shown that relative spectral intensity increases during the discharge transition. This phenomenon implies that the averaged electron energy in diffuse discharge is higher than that in the filamentary discharge.

  18. Visible and VUV images of dielectric barrier discharges in Xe

    Energy Technology Data Exchange (ETDEWEB)

    Mildren, R.P. [Centre for Lasers and Applications, Macquarie University, Sydney, NSW (Australia); Carman, R.J. [Department of Physics, Macquarie University, Sydney, NSW (Australia); Falconer, I.S. [School of Physics A28, University of Sydney, Sydney, NSW (Australia)

    2001-12-07

    We have recorded short exposure images of visible and vacuum ultraviolet (VUV) emission from a Xe dielectric barrier discharge lamp, and investigated the effects of excitation by fast rising pulse and sinusoidal voltage waveforms on the discharge structure. The images from the pulsed discharge are essentially uniform over the active electrode area unlike the sinusoidal discharge which is filamentary. By investigating a single filament discharge, it is also found that a large fraction ((>)90%) of the total visible and VUV emission for sinusoidal excitation is generated from regions outside the filament. The images suggest that the VUV is generated from surface discharges, or 'feelers', which branch out laterally from the filaments. Model calculations suggest that surface or volume discharges, in which the current density is much lower than for filamentary discharges, generate VUV emission more efficiently due to the reduced rate for multi-step electron excitation of Xe* species. (author)

  19. Effects of background gas on sulfur hexafluoride removal by atmospheric dielectric barrier discharge plasma

    Science.gov (United States)

    Zhang, Xiaoxing; Xiao, Hanyan; Hu, Xiongxiong; Gui, Yingang

    2016-11-01

    The effects of background gases (He, Ar, N2 and air) on SF6 removal in a dielectric barrier reactor were investigated at atmospheric pressure. A comparison among these background gases was performed in terms of discharge voltage, discharge power, mean electron energy, electron density, removal efficiency and energy yield for the destruction of SF6. Results showed that the discharge voltage of He and Ar was lower than that of N2 and air, but the difference of their discharge power was small. Compared with three other background gases, Ar had a relatively superior destruction and removal rate and energy yield since the mean electron energy and electron density in SF6/H2O/Ar plasma were both maintained at a high level. Complete removal of 2% SF6 could be achieved at a discharge power of 48.86 W with Ar and the corresponding energy yield can reach 4.8 g/kWh.

  20. Effects of background gas on sulfur hexafluoride removal by atmospheric dielectric barrier discharge plasma

    Directory of Open Access Journals (Sweden)

    Xiaoxing Zhang

    2016-11-01

    Full Text Available The effects of background gases (He, Ar, N2 and air on SF6 removal in a dielectric barrier reactor were investigated at atmospheric pressure. A comparison among these background gases was performed in terms of discharge voltage, discharge power, mean electron energy, electron density, removal efficiency and energy yield for the destruction of SF6. Results showed that the discharge voltage of He and Ar was lower than that of N2 and air, but the difference of their discharge power was small. Compared with three other background gases, Ar had a relatively superior destruction and removal rate and energy yield since the mean electron energy and electron density in SF6/H2O/Ar plasma were both maintained at a high level. Complete removal of 2% SF6 could be achieved at a discharge power of 48.86 W with Ar and the corresponding energy yield can reach 4.8 g/kWh.

  1. MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    V.K. Mathur

    2003-02-01

    In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

  2. A model based on equations of kinetics to study nitrogen dioxide behavior within a plasma discharge reactor.

    Science.gov (United States)

    Abedi-Varaki, Mehdi; Ganjovi, Alireza; Shojaei, Fahimeh; Hassani, Zahra

    2015-01-01

    In this work, a zero-dimensional kinetics model is used to study the temporal behavior of different species such as charged particles, radicals and excited states inside a Dielectric Barrier Discharge plasma reactor. It is shown that, the reactor significantly reduces the concentration of nitrogen monoxide as an environmental pollutant. After a drastic increase, a decrease in the concentration of the NO2 molecules inside the reactor is seen. Nitrogen monoxide molecules with a very low concentration are produced inside the reactor and its quick conversion to other products is proved. The obtained results are compared with the existing experimental and simulation findings, whenever possible.

  3. Collective phenomena in volume and surface barrier discharges

    Science.gov (United States)

    Kogelschatz, U.

    2010-11-01

    Barrier discharges are increasingly used as a cost-effective configuration to produce non-equilibrium plasmas at atmospheric pressure. This way, copious amounts of electrons, ions, free radicals and excited species can be generated without significant heating of the background gas. In most applications the barrier is made of dielectric material. Major applications utilizing mainly dielectric barriers include ozone generation, surface cleaning and modification, polymer and textile treatment, sterilization, pollution control, CO2 lasers, excimer lamps, plasma display panels (flat TV screens). More recent research efforts are devoted to biomedical applications and to plasma actuators for flow control. Sinusoidal feeding voltages at various frequencies as well as pulsed excitation schemes are used. Volume as well as surface barrier discharges can exist in the form of filamentary, regularly patterned or diffuse, laterally homogeneous discharges. The physical effects leading to collective phenomena in volume and surface barrier discharges are discussed in detail. Special attention is paid to self-organization of current filaments and pattern formation. Major similarities of the two types of barrier discharges are elaborated.

  4. Spent nuclear fuel discharges from US reactors 1993

    Energy Technology Data Exchange (ETDEWEB)

    1995-02-01

    The Energy Information Administration (EIA) of the U.S. Department of Energy (DOE) administers the Nuclear Fuel Data Survey, Form RW-859. This form is used to collect data on fuel assemblies irradiated at commercial nuclear reactors operating in the United States, and the current inventories and storage capacities of those reactors. These data are important to the design and operation of the equipment and facilities that DOE will use for the future acceptance, transportation, and disposal of spent fuels. The data collected and presented identifies trends in burnup, enrichment, and spent nuclear fuel discharged form commercial light-water reactor as of December 31, 1993. The document covers not only spent nuclear fuel discharges; but also site capacities and inventories; canisters and nonfuel components; and assembly type characteristics.

  5. Discharge analysis and electrical modeling for the development of efficient dielectric barrier discharge

    Science.gov (United States)

    Pal, U. N.; Kumar, M.; Tyagi, M. S.; Meena, B. L.; Khatun, H.; Sharma, A. K.

    2010-02-01

    Dielectric-barrier discharges (DBDs) are characterized by the presence of at least one insulating layer in contact with the discharge between two planar or cylindrical electrodes connected to an AC/pulse power supply. The dielectric layers covering the electrodes act as current limiters and prevent the transition to an arc discharge. DBDs exist usually in filamentary mode, based on the streamer nature of the discharges. The main advantage of this type of electrical discharges is that nonequilibrium and non-thermal plasma conditions can be established at atmospheric pressure. VUV/UV sources based on DBDs are considered as promising alternatives of conventional mercury-based discharge plasmas, producing highly efficient VUV/UV radiation. The experiments have been performed using two coaxial quartz double barrier DBD tubes, which are filled with Xe/Ar at different pressures. A sinusoidal voltage up to 2.4 kV peak with frequencies from 20 to 100 kHz has been applied to the discharge electrodes for the generation of microdischarges. A stable and uniform discharge is produced in the gas gap between the dielectric barrier electrodes. By comparisons of visual images and electrical waveforms, the filamentary discharges for Ar tube while homogeneous discharge for Xe tube at the same conditions have been confirmed. The electrical modeling has been carried out to understand DBD phenomenon in variation of applied voltage waveforms. The simulated discharge characteristics have been validated by the experimental results.

  6. Synthesis gas regeneration electrotechnology using volume high-voltage pulsed discharges: corona and barrier ones

    Directory of Open Access Journals (Sweden)

    M.I. Boyko

    2014-09-01

    Full Text Available Factory testing of a created high-voltage complex (plant has been conducted. The complex consists of two pulse generators with the repetition rate of up to 50,000 pulses per second and load reactors with pulsed discharges - corona and barrier ones. Transistor (IGBT keys are used as energy switches. The efficient mode of coke gas methane conversion (steam reforming to syngas has been obtained with application of the complex created. A unidirectional action of the pulsed discharges, the gas mixture temperature, and a nickel catalyst has reduced the specific energy consumption for synthesis gas regeneration during the conversion. A feasible mechanism of this conversion is described.

  7. Double discharges in unipolar-pulsed dielectric barrier discharge xenon excimer lamps

    Science.gov (United States)

    Liu, Shuhai; Neiger, Manfred

    2003-07-01

    Excitation of dielectric barrier discharge xenon excimer lamps by unipolar short square pulses is studied in this paper. Two discharges with different polarity are excited by each voltage pulse (double discharge phenomenon). The primary discharge occurs at the top or at the rising flank of the applied unipolar square pulse, which is directly energized by the external circuit. The secondary discharge with the reversed polarity occurs at the falling flank or shortly after the falling flank end (zero external voltage) depending on the pulse width, which is energized by the energy stored by memory charges deposited by the primary discharge. Fast-speed ICCD imaging shows the primary discharge has a conic discharge appearance with a channel broadening on the anode side. This channel broadening increases with increasing the pulse top level. Only the anode-side surface discharge is observed in the primary discharge. The surface discharge on the cathode side which is present in bipolar sine voltage excitation is not observed. On the contrary, the secondary discharge has only the cathode-side surface discharge. The surface discharge on the anode side is not observed. The secondary discharge is much more diffuse than the primary discharge. Time-resolved emission measurement of double discharges show the secondary discharge emits more VUV xenon excimer radiation but less infrared (IR) xenon atomic emission than the primary discharge. It was found that the IR xenon atomic emission from the secondary discharge can be reduced by shortening the pulse width. The energy efficiency of unipolar-pulsed xenon excimer lamps (the overall energy efficiency of double discharges) is much higher than that obtained under bipolar sine wave excitation. The output VUV spectrum under unipolar pulse excitation is found to be identical to that under sine wave excitation and independent of injected electric power.

  8. Characterization of surface dielectric barrier discharge influenced by intermediate frequency for ozone production

    Science.gov (United States)

    Abdelaziz, Ayman A.; Ishijima, Tatsuo; Seto, Takafumi; Osawa, Naoki; Wedaa, Hassan; Otani, Yoshio

    2016-06-01

    The aim of this study is to investigate the effect of the intermediate frequency (1-10 kHz) of the sinusoidal driving voltage on the characteristics of a developed surface dielectric barrier discharge (SDBD)-based reactor having spikes on its discharge electrode. Moreover, its influence on the production of ozone and nitrogen oxide byproducts is evaluated. The results show that SDBD is operated in the filamentary mode at all the frequencies. Nevertheless, the pulses of the discharge current at high frequencies are much denser and have higher amplitudes than those at low frequencies. The analysis of the power consumed in the reactor shows that a small portion of the input power is dissipated in the dielectric material of SDBD source, whereas the major part of the power is consumed in the plasma discharge. The results of the ozone production show that higher frequencies have a slightly adverse effect on the ozone production at relatively high energy density values, where the ozone concentration is slightly decreased when the frequency is increased at the same energy density. The temperature of the discharge channels and gas is not a crucial factor for the decomposition of ozone in this reactor, while the results of the measurements of nitrogen oxides characteristics indicate that the formation of NO and NO2 has a significant adverse effect on the production efficiency of ozone due to their oxidation to another nitrogen oxides and their catalytic effect.

  9. The Experimental Investigations of Dielectric Barrier Discharge and Pulse Corona Discharge in Air Cleaning

    Institute of Scientific and Technical Information of China (English)

    左莉; 侯立安; 杨林松

    2003-01-01

    The dielectric barrier discharge (DBD) and pulse corona discharge(PCD) plasmagenerator was used to remove NH3, H2S, C7Hs etc. from atmosphere. The principle and charac-teristic of the two ways was discussed in the article. The test shows the result of PCD is betterthan that of DBD.

  10. Flow Reactor Studies with Nanosecond Pulsed Discharges at Atmospheric Pressure and Higher

    Science.gov (United States)

    2013-10-01

    Image of Discharge Reactor with Viewport Inlet Cap • Modular plasma discharge reactor can be interchanged with redesigned pressure shell to perform...Flow Reactor Studies with Nanosecond Pulsed Discharges at Atmospheric Pressure and Higher Nicholas Tsolas, Kuni Togai and Richard Yetter...Department of Mechanical and Nuclear Engineering The Pennsylvania State University University Park, PA, 16801 Fourth Annual Review Meeting of the

  11. Behavior of ZnO-coated alumina dielectric barrier discharge in atmospheric pressure air

    CERN Document Server

    Li, Meng; Tao, Xiaoping

    2011-01-01

    A complete investigation of the discharge behavior of dielectric barrier discharge device using ZnO-coated dielectric layer in atmospheric pressure is made. Highly conductive ZnO film was deposited on the dielectric surface. Discharge characteristic of the dielectric barrier discharge are examined in different aspects. Experimental result shows that discharge uniformity is improved definitely in the case of ZnO-coated dielectric barrier discharge. And relevant theoretical models and explanation are presented to describing its discharge physics.

  12. Ozone production in a dielectric barrier discharge with ultrasonic irradiation

    DEFF Research Database (Denmark)

    Drews, Joanna Maria; Kusano, Yukihiro; Leipold, Frank

    2011-01-01

    Ozone production has been investigated using an atmospheric pressure dielectric barrier discharge in pure O2 at room temperature with and without ultrasonic irradiation. It was driven at a frequency of either 15 kHz or 40 kHz. The ozone production was highly dependent on the O2 flow rate...... and the discharge power. Furthermore, powerful ultrasonic irradiation at a fundamental frequency of 30 kHz with the sound pressure level of 150 dB into the discharge can improve the ozone production efficiency, particularly when operated at the frequency of 15 kHz at the flow rate of 15 L/min....

  13. Removal of atrazine in water by combination of activated carbon and dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Vanraes, Patrick, E-mail: patrick.vanraes@ugent.be [Department of Applied Physics, Ghent University, Sint-Pietersnieuwstraat 41 B4, 9000 Gent (Belgium); Willems, Gert; Nikiforov, Anton [Department of Applied Physics, Ghent University, Sint-Pietersnieuwstraat 41 B4, 9000 Gent (Belgium); Surmont, Pieter; Lynen, Frederic [Separation Science Group, Department of Organic Chemistry, Ghent University, Krijgslaan 281 S4-bis, 9000 Gent (Belgium); Vandamme, Jeroen; Van Durme, Jim [Research Group Molecular Odor Chemistry, Department of Microbial and Molecular Systems (M2S), KU Leuven, Technology Campus, Gebroeders De Smetstraat 1, 9000 Gent (Belgium); Verheust, Yannick P.; Van Hulle, Stijn W.H.; Dumoulin, Ann [Department of Industrial Biological Sciences, Ghent University, Graaf Karel de Goedelaan 5, 8500 Kortrijk (Belgium); Leys, Christophe [Department of Applied Physics, Ghent University, Sint-Pietersnieuwstraat 41 B4, 9000 Gent (Belgium)

    2015-12-15

    Highlights: • Increasing input power with a factor 3.5 leads to deeper atrazine oxidation without significantly changing energy yield of atrazine removal. • Chlorine containing oxidation by-products of first and later generations are detected with HPLC–MS analysis, in agreement with literature. • Desorption analysis shows lower atrazine concentration and higher by-product concentration on activated carbon textile after plasma treatment. • Comparison with plasma reactors described in literature for atrazine decomposition confirms relatively high energy efficiency of our reactor. - Abstract: Efficiency of modern wastewater treatment plants to remove or decompose persistent contaminants in low concentration is often insufficient to meet the demands imposed by governmental laws. Novel, efficient and cheap methods are required to address this global issue. We developed a new type of plasma reactor, in which atrazine decomposition by atmospheric dielectric barrier discharge (DBD) in dry air is combined with micropollutant adsorption on activated carbon textile and with extra bubbling of generated ozone. Investigation of reaction kinetics and by-product analysis shows that increasing input power with a factor 3.5 leads to deeper atrazine oxidation without significantly changing energy yield of atrazine removal. By-products of first and later generations are detected with HPLC–MS analysis in water and adsorbed on the activated carbon textile. Our reactor is compared in energy efficiency with reactors described in literature, showing that combination of plasma discharge with pollutant adsorption and ozone recycling is attractive for future applications of water treatment.

  14. Hydrogen production by reforming of hydrocarbons and alcohols in a dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Sarmiento, Belen; Brey, J. Javier; Viera, Inmaculada G. [Hynergreen Technologies, S.A. Avda. de la Buhaira, 2. 41018 Sevilla (Spain); Gonzalez-Elipe, Agustin R.; Cotrino, Jose; Rico, Victor J. [Instituto de Ciencia de los Materiales de Sevilla (CSIC-University Sevilla), Avda. Americo Vespucio, 49, 41092 Sevilla (Spain)

    2007-06-10

    This work reports about the use of plasmas to obtain hydrogen by reforming of hydrocarbons or alcohols in mixtures with CO{sub 2} or H{sub 2}O. The plasma is activated in a dielectric barrier discharge (DBD) reactor working at atmospheric pressure and low temperatures (i.e., about 100 C). The reactor presents a great versatility in operation and a low manufacturing cost. Results are presented for the reforming of methane, methanol and ethanol. Methane transforms up to a 70% into CO and H{sub 2} without formation of any kind of superior hydrocarbon. For the two alcohols 100% conversion into the same products is found for flows much higher than in the case of methane. The work reports a description of the reactor and the operational conditions of the power supply enabling the ignition of the plasma and its steady state operation. (author)

  15. Dielectric barrier Discharge Plasma Actuator Characterization and Application

    NARCIS (Netherlands)

    Correale, G.

    2016-01-01

    An experimental investigation about nanosecond Dielectric Barrier Discharge (ns-DBD) plasma actuator is presented in this thesis. This work aimed to answer fundamental questions on the actuation mechanism of this device. In order to do so, parametric studies in a quiescent air as well as laminar

  16. Dielectric barrier Discharge Plasma Actuator Characterization and Application

    NARCIS (Netherlands)

    Correale, G.

    2016-01-01

    An experimental investigation about nanosecond Dielectric Barrier Discharge (ns-DBD) plasma actuator is presented in this thesis. This work aimed to answer fundamental questions on the actuation mechanism of this device. In order to do so, parametric studies in a quiescent air as well as laminar bou

  17. Experimental Study on Spiral Patterns in Dielectric Barrier Discharge System

    Institute of Scientific and Technical Information of China (English)

    LIU Shu-Hua; DONG Li-Fang; LIU Fu-Cheng; LI Shu-Feng; LI Xue-Chen; WANG Hong-Fang

    2006-01-01

    Spiral patterns are obtained in a dielectric barrier discharge system with water electrodes. The dynamics of spiral formation and transition is investigated. Wavelength characteristic of spiral patterns is also studied. Correlation measurements indicate that the wavelength of spiral pattern increases with the increasing gas gap width and oscillates with the increasing drive frequency.

  18. The reformation of liquid hydrocarbons in an aqueous discharge reactor

    KAUST Repository

    Zhang, Xuming

    2015-04-21

    We present an aqueous discharge reactor for the reformation of liquid hydrocarbons. To increase a dielectric constant of a liquid medium, we added distilled water to iso-octane and n-dodecane. As expected, we found decreased discharge onset voltage and increased discharge power with increased water content. Results using optical emission spectroscopy identified OH radicals and O atoms as the predominant oxidative reactive species with the addition of water. Enriched CH radicals were also visualized, evidencing the existence of cascade carbon-carbon cleavage and dehydrogenation processes in the aqueous discharge. The gaseous product consisted primarily of hydrogen, carbon monoxide, and unsaturated hydrocarbons. The composition of the product was readily adjustable by varying the volume of water added, which demonstrated a significant difference in composition with respect to the tested liquid hydrocarbon. In this study, we found no presence of CO2 emissions or the contamination of the reactor by solid carbon deposition. These findings offer a new approach to the reforming processes of liquid hydrocarbons and provide a novel concept for the design of a practical and compact plasma reformer. © 2015 IOP Publishing Ltd.

  19. Measurement of Restricted Atmospheric Barrier Discharge in Nonwoven Fiber Pores

    Science.gov (United States)

    Kawabe, Masaaki

    The restricted dielectric barrier discharge in nonwoven pores has been investigated by observation of the current pulse, the Lissajous figure and light emissions. The current pulse measurement revealed that homogeneity of the discharge was relatively high and the amount of individual pulse was quite small on the order of 0.01nC. Such a small current pulse demonstrates that nonwoven fiber is effective as a dielectric barrier. Analysis of the Lissajous figure, indicates the calculated value of the gap voltage for the discharge starting point of nonwoven fiber layers is close to what was predicted using the Paschen curve. On the other hand, the measured value of the gap voltage in the Lissajous figure is larger than its calculated value, so the surface charge on the dielectrics dissipated relatively fast. The observations of light emissions also showed a high homogeneity.

  20. Barriers to discharge from inpatient rehabilitation: a teamwork approach.

    Science.gov (United States)

    Cruz, Lisanne Catherine; Fine, Jeffrey S; Nori, Subhadra

    2017-03-13

    Purpose In order to prevent adverse events during the discharge process, coordinating appropriate community resources, medication reconciliation, and patient education needs to be implemented before the patient leaves the hospital. This coordination requires communication and effective teamwork amongst staff members. In order to address these concerns, the purpose of this paper is to incorporate the TeamSTEPPS principles to develop a discharge plan that would best meet the needs of the patients as they return to the community. Design/methodology/approach Through a gap analysis, barriers to discharge were identified from the following disciplines: nursing, social work, physical and occupational therapy, psychology, and rehabilitation physician. To improve communication, weekly meetings and twice-weekly huddles were implemented so that concerns regarding discharge obstacles could be identified and resolved. Visibility of discharge dates were improved by use of graduation certificates in patient rooms and green ribbons on patient wheelchairs. Findings After implementation of this discharge intervention, length of stay was reduced providing cost savings to the hospital, patient satisfaction on HCAHP surveys improved and demonstrated patient satisfaction with the discharge process, and readmission rates improved. Originality/value This study demonstrated that effective teamwork and communication can improve patient safety and satisfaction during the discharge period.

  1. ANALISA PENGARUH PERIODIK CHARGING DAN DISCHARGING PADA WAKTU CHARGING DAN DISCHARGING DARI METAL HYDRIDE REACTOR (MHR

    Directory of Open Access Journals (Sweden)

    Taurista Perdana Syawitri

    2015-01-01

    Full Text Available Perpindahan panas merupakan faktor penting yang mempengaruhi kinerja tangki penyimpanan hydrogen dalam bentuk metal hydride. Penelitian sebelumnya menyimpulkan bahwa penambahan sejumlah kecil metal foam pada interior metal hydride reactor (MHR merupakan cara yang efektif untuk meningkatkan perpindahan panas pada reaktor, sehingga mengurangi waktu charging. Namun, proses charging dan discharging MHR dilakukan secara terpisah dalam studi ini. Oleh karena itu, penelitian ini menyimulasikan model 2-D axisymmetric menggunakan software COMSOL untuk menginvestigasi pengaruh dari periodik charging dan discharging dari MHR yang mengandung metal foam dengan fraksi volume tertentu. Hasil simulasi menunjukkan bahwa model saat ini mempunyai hasil yang sesuai dengan hasil yang ditunjukkan di dalam literatur. Selain itu, ditemukan bahwa terdapat nilai optimum dari fraksi volume metal foam di setiap proses charging dan proses discharging yang memberikan waktu charging dan discharging lebih pendek.

  2. Influence of gas discharge parameters on emissions from a dielectric barrier discharge excited argon excimer lamp

    OpenAIRE

    2011-01-01

    A dielectric barrier discharge excited neutral argon (Ar I) excimer lamp has been developed and characterised. The aim of this study was to develop an excimer lamp operating at atmospheric pressure that can replace mercury lamps and vacuum equipment used in the sterilisation of medical equipment and in the food industry. The effects of discharge gas pressure, flow rate, excitation frequency and pulse width on the intensity of the Ar I vacuum ultraviolet (VUV) emission at 126 nm and near infra...

  3. Electric field in an AC dielectric barrier discharge overlapped with a nanosecond pulse discharge

    Science.gov (United States)

    Goldberg, Benjamin M.; Shkurenkov, Ivan; Adamovich, Igor V.; Lempert, Walter R.

    2016-08-01

    The effect of ns discharge pulses on the AC barrier discharge in hydrogen in plane-to-plane geometry is studied using time-resolved measurements of the electric field in the plasma. The AC discharge was operated at a pressure of 300 Torr at frequencies of 500 and 1750 Hz, with ns pulses generated when the AC voltage was near zero. The electric field vector is measured by ps four-wave mixing technique, which generates coherent IR signal proportional to the square of electric field. Absolute calibration was done using an electrostatic (sub-breakdown) field applied to the discharge electrodes, when no plasma was generated. The results are compared with one-dimensional kinetic modeling of the AC discharge and the nanosecond pulse discharge, predicting behavior of both individual micro-discharges and their cumulative effect on the electric field distribution in the electrode gap, using stochastic averaging based on the experimental micro-discharge temporal probability distribution during the AC period. Time evolution of the electric field in the AC discharge without ns pulses, controlled by a superposition of random micro-discharges, exhibits a nearly ‘flat top’ distribution with the maximum near breakdown threshold, reproduced quite well by kinetic modeling. Adding ns pulse discharges on top of the AC voltage waveform changes the AC discharge behavior in a dramatic way, inducing transition from random micro-discharges to a more regular, near-1D discharge. In this case, reproducible volumetric AC breakdown is produced at a well-defined moment after each ns pulse discharge. During the reproducible AC breakdown, the electric field in the plasma exhibits a sudden drop, which coincides in time with a well-defined current pulse. This trend is also predicted by the kinetic model. Analysis of kinetic modeling predictions shows that this effect is caused by large-volume ionization and neutralization of surface charges on the dielectrics by ns discharge pulses. The present

  4. Effects of airflow on the distribution of filaments in atmospheric AC dielectric barrier discharge

    Science.gov (United States)

    Fan, Zhihui; Qi, Haicheng; Liu, Yidi; Yan, Huijie; Ren, Chunsheng

    2016-12-01

    Atmospheric-pressure dielectric barrier discharge (DBD) accompanied by airflow has attracted a significant attention for its extensive applications. In this paper, the effects of airflow on the characteristics of the atmospheric air DBD plasma are experimentally investigated using the DBD reactor excited by a 15 kHz AC power source. In order to study the discharge filaments distribution at different flow rates, transparent conductive indium tin oxide film is used as the upper electrode, and quartz glasses are used as insulated dielectrics. Experiment results prove that the breakdown voltage is decreased and more current pulses with declined amplitudes are produced when the airflow is introduced into the discharge gap. It is confirmed that although the discharge seems to be diffuse in the presence of airflow to the naked eyes, the discharge mode remains filamentary in the intensified charge-coupled device images within a single AC cycle. By acquiring the images with a different exposure time, it can be recognized that the discharge filaments move along the flow field direction with a velocity less than the corresponding flow rate. The movement of discharge filaments is attributed to the motion of the charge induced by the airflow.

  5. Combustion Enhancement Using a Silent Discharge Plasma Reactor

    Science.gov (United States)

    Rosocha, Louis; Platts, David; Coates, Don; Stange, Sy

    2003-10-01

    Electric fields affect flame propagation speed, stability, and combustion chemistry. External electrodes, arc discharges, and plasma jets have been used to combust gas mixtures outside their flammability limits. Experiments with silent electrical discharges (SEDs) and propagating flames have shown that flame propagation velocity is actually decreased (combustion retarded) when an SED is applied directly to the flame region, but velocity is increased (combustion promoted) when applied to the unburned gas mixture upstream of a flame. More recent work has proposed electric arc/microwave-driven plasma-generating fuel nozzles to produce dissociated fuel or ionized fuel for aircraft gas turbine engine combustor mixers. In contrast to prior works, we have used a silent discharge plasma (SDP) reactor to break up large fuel molecules into smaller molecules and create free radicals/active species in a gas stream before the fuel is mixed with an oxidizer and combusted. A cylindrical SDP reactor was used to 'activate' propane before mixing it with air and igniting the combustible gas mixture. With the plasma, the physical appearance of the flame changes and substantial changes in mass spectrometer fragmentation peaks for fuel and combustion products are observed (i.e., combustion is enhanced). Results of changes in the degree of combustion will be discussed in terms of variations in the plasma specific energy.

  6. Particle simulation of filamentary formation in dielectric barrier discharge.

    Science.gov (United States)

    Fan, Weili; Dong, Lifang

    2015-11-01

    Dielectric barrier discharge (DBD) is well known for its extensive industrial applications. Recently, new attention has been paid to DBD as a system of rich nonlinear dynamics to study the self-organized filamentary patterns. Though a number of experimental studies have been implemented, the involved physics is still not completely clear, partially due to the limitation of the available space and time-resolved diagnostics. Computer simulation has proven to be an effective tool to give insights into the discharge mechanism. So far, most simulations presented are based on fluid models. However, since the plasma is non-equilibrium in DBD where the particle velocities may deviate from the Maxwellian distribution, self-consistent kinetic simulations are required. In this paper, two successive filamentary discharges in DBD have been studied by use of two-dimensional particle-in-cell simulation with Monte Carlo collisions included (PIC-MCC). The formation of multiple filaments and the involved electric fields, electric potentials, plasma densities, and particle temperatures are presented. Results show that both of the surface charges and space charges play significant roles in the discharges. The total electric field in the gas gap has been completely reversed before the ac voltage hit zero, due to the accumulation of the surface charges, which triggers the next discharge. The space charges always exist between two successive discharges, which provides the `seed charges' for reignition of the filaments. This modeling has revealed significant details of the discharge behaviors, which greatly improved our understanding of DBD mechanisms.

  7. Temporal modulation of plasma species in atmospheric dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Aijun; Wang, Xiaohua, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn; Liu, Dingxin; Rong, Mingzhe, E-mail: xhw@mail.xjtu.edu.cn, E-mail: mzrong@mail.xjtu.edu.cn [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Kong, Michael G. [Centre for Plasma Biomedicine, State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Frank Reidy Research Center for Bioelectrics, Department of Electrical and Computer Engineering, Old Dominion University, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2014-07-15

    The atmospheric pressure dielectric barrier discharge in helium is a pulsed discharge in nature and the moment of maximum species densities is almost consistent with peak discharge current density. In this paper, a one-dimensional fluid model is used to investigate the temporal structure of plasma species in an atmospheric He-N{sub 2} dielectric barrier discharge (DBD). It is demonstrated that there exist microsecond delays of the moments of the maximum electron and ion densities from the peak of discharge current density. These time delays are caused by a competition between the electron impact and Penning ionizations, modulated by the N{sub 2} level in the plasma-forming gas. Besides, significant electron wall losses lead to the DBD being more positively charged and, with a distinct temporal separation in the peak electron and cation densities, the plasma is characterized with repetitive bursts of net positive charges. The temporal details of ionic and reactive plasma species may provide a new idea for some biological processes.

  8. Discharge and radiation characteristics of Xe one-barrier excilamps

    Science.gov (United States)

    Arnold, Erich; Lomaev, Mikhail I.; Shitz, Dmitrii V.; Skakun, Victor S.; Tarasenko, Victor F.

    2002-03-01

    The paper is devoted to experimental study of discharge and radiation characteristics taking place in Xe one-barrier excilamps at broad variations of excitation pulse parameters and gas fill-pressures. The B-X band of the molecule Xe2* dominates the lamp spectrum and has high efficiency. Radiation of monatomic lines and luminescence of the lamp bulb can be observed too. The molecule Xe2* band B-X radiation of luminescence time dependence and luminescence of the lamp bulb quartz are similar, at the same time the radiation of Xe monatomic line (lambda) equals 467 nm has obviously some other form. Depending on excitation conditions, i.e. power, duration and excitation impulse form, a gas discharge Xe excilamp, different by homogeneity level and radiation efficiency types of discharge can be realized. Formation of discharge homogeneity is the necessary condition to obtain high efficiencies of excimer radiation in this type of lamp. In one-barrier xenon excilamps with internal small curvature of an electrode, a homogeneous discharge forms at pressures up to 300 Torr.

  9. Study of carbon dioxide gas treatment based on equations of kinetics in plasma discharge reactor

    Science.gov (United States)

    Abedi-Varaki, Mehdi

    2017-08-01

    Carbon dioxide (CO2) as the primary greenhouse gas, is the main pollutant that is warming earth. CO2 is widely emitted through the cars, planes, power plants and other human activities that involve the burning of fossil fuels (coal, natural gas and oil). Thus, there is a need to develop some method to reduce CO2 emission. To this end, this study investigates the behavior of CO2 in dielectric barrier discharge (DBD) plasma reactor. The behavior of different species and their reaction rates are studied using a zero-dimensional model based on equations of kinetics inside plasma reactor. The results show that the plasma reactor has an effective reduction on the CO2 density inside the reactor. As a result of reduction in the temporal variations of reaction rate, the speed of chemical reactions for CO2 decreases and very low concentration of CO2 molecules inside the plasma reactor is generated. The obtained results are compared with the existing experimental and simulation findings in the literature.

  10. Direct current dielectric barrier assistant discharge to get homogeneous plasma in capacitive coupled discharge

    Energy Technology Data Exchange (ETDEWEB)

    Du, Yinchang, E-mail: ycdu@mail.ustc.edu.cn [Modern Physics Department, University of Science and Technology of China, Hefei, Anhui 230026 (China); Max-Planck Institute for Extraterrestrial Physics, D-85748 Garching (Germany); Li, Yangfang [Max-Planck Institute for Extraterrestrial Physics, D-85748 Garching (Germany); Cao, Jinxiang; Liu, Yu; Wang, Jian; Zheng, Zhe [Modern Physics Department, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-06-15

    In this paper, we propose a method to get more homogeneous plasma in the geometrically asymmetric capacitive coupled plasma (CCP) discharge. The dielectric barrier discharge (DBD) is used for the auxiliary discharge system to improve the homogeneity of the geometrically asymmetric CCP discharge. The single Langmuir probe measurement shows that the DBD can increase the electron density in the low density volume, where the DBD electrodes are mounted, when the pressure is higher than 5 Pa. By this manner, we are able to improve the homogeneity of the plasma production and increase the overall density in the target volume. At last, the finite element simulation results show that the DC bias, applied to the DBD electrodes, can increase the homogeneity of the electron density in the CCP discharge. The simulation results show a good agreement with the experiment results.

  11. Investigation of NOx Reduction by Low Temperature Oxidation Using Ozone Produced by Dielectric Barrier Discharge

    DEFF Research Database (Denmark)

    Stamate, Eugen; Irimiea, Cornelia; Salewski, Mirko

    2013-01-01

    NOx reduction by low temperature oxidation using ozone produced by a dielectric barrier discharge generator is investigated for different process parameters in a 6m long reactor in serpentine arrangement using synthetic dry flue gas with NOx levels below 500 ppm, flows up to 50 slm and temperatures...... up to 80 C. The role of different mixing schemes and the impact of a steep temperature gradient are also taken into consideration. The process chemistry is monitored by Fourier transform infrared spectroscopy, chemiluminescence and absorption spectroscopy. The kinetic mechanism during the mixing...

  12. Experimental Observation of Travelling Hexagon Patterns in Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    董丽芳; 贺亚峰; 尹增谦; 柴志方

    2003-01-01

    Travelling hexagon patterns have been observed in dielectric barrier discharge in an air-argon mixture. The phase diagram of hexagon pattern appearance as functions of applied voltage and air concentration is given. The spatial frequency of hexagon pattern increases with increasing applied voltage and air concentration. The current waveforms of hexagon pattern also vary with the air concentration. The drift velocity of travelling hexagon pattern changes from 4mm/s to 18mm/s.

  13. Study a compound orthorhombic lattice pattern in dielectric barrier discharge

    Science.gov (United States)

    Wang, Hao; Dong, Lifang; Gao, Xing; Liu, Weibo; Wei, Lingyan; Pan, Yuyang

    2016-12-01

    The compound orthorhombic lattice pattern which is composed of the bright spot and the dim spot is observed for the first time in a dielectric barrier discharge system. It is found that the dim spot is located at the gravity center of the surrounding three bright spots. The discharge bifurcates from a square lattice, hexagon pattern to compound orthorhombic lattice pattern and finally changes to an irregular pattern. The phase diagram of the pattern types as a function of the applied voltage and the argon concentration is given. The spatio-temporal dynamics of the pattern is studied by the time correlation measurement and the high speed video camera images. Results show that the dim spot is formed by both volume discharge and surface discharge induced by the bright spot. The differences of plasma parameters between the bright spots and the dim spots obtained by optical emission spectroscopy verify that the dim spot is formed by both volume discharge and surface discharge. To better understand the mechanism of firing of the dim spots for the same conditions as in the first phase diagram, the phase diagram of the mechanism of firing of the dim spots as a function of the gas pressure and the argon concentration is given. The simulation of the electric fields of wall charges accumulated by bright spots further verifies that the bright spot has an effect on the formation of dim spot.

  14. Characterization of a dielectric barrier discharge in controlled atmosphere

    Science.gov (United States)

    Kogelheide, Friederike; Offerhaus, Björn; Bibinov, Nikita; Bracht, Vera; Smith, Ryan; Lackmann, Jan-Wilm; Awakowicz, Peter; Stapelmann, Katharina; Bimap Team; Aept Team

    2016-09-01

    Non-thermal atmospheric-pressure plasmas are advantageous for various biomedical applications as they make a contact- and painless therapy possible. Due to the potential medical relevance of such plasma sources further understanding of the chemical and physical impact on biological tissue regarding the efficacy and health-promoting effect is necessary. The knowledge of properties and effects offers the possibility to configure plasmas free of risk for humans. Therefore, tailoring the discharge chemistry in regard to resulting oxidative and nitrosative effects on biological tissue by adjusting different parameters is of growing interest. In order to ensure stable conditions for the characterization of the discharge, the used dielectric barrier discharge was mounted in a vessel. Absolutely calibrated optical emission spectroscopy was carried out to analyze the electron density and the reduced electric field. The rather oxygen-based discharge was tuned towards a more nitrogen-based discharge by adjusting several parameters as reactive nitrogen species are known to promote wound healing. Furthermore, the impact of an ozone-free discharge has to be studied. This work was funded by the German Research Foundation (DFG) with the packet grant PAK 816 `Plasma Cell Interaction in Dermatology'.

  15. Electrohydrodynamic force in dielectric barrier discharge plasma actuators

    Energy Technology Data Exchange (ETDEWEB)

    Boeuf, J P; Lagmich, Y; Unfer, Th; Callegari, Th; Pitchford, L C [CPAT-CNRS, Universite Paul Sabatier, 118 Route de Narbonne, Toulouse 31062 (France)

    2007-02-07

    Surface dielectric barrier discharges (DBDs) have been proposed as actuators for flow control. In this paper we discuss the basic mechanisms responsible for the electrohydrodynamic (EHD) force exerted by the discharge on the gas molecules. A two-dimensional fluid model of the DBD is used to describe the plasma dynamics, to understand the basic physics associated with the EHD force and to give some quantitative estimation of the force under simplified conditions. The results show that for ramp or sinusoidal voltage waveforms, the discharge consists of large amplitude short current pulses during which a filamentary plasma spreads along the surface, separated in time by long duration, low current discharge phases of a Townsend or corona type. The contribution of the low current phases to the total force exerted by the discharge on the gas is dominant because their duration is much longer than that of the current pulses and because the force takes place in a much larger volume. A description of the different discharge regimes and a parametric study of the EHD force as a function of voltage rise time and dielectric thickness is presented.

  16. Dielectric layer equivalent capacitance and loading p erformance of a coaxial dielectric barrier discharge reactor%同轴介质阻挡放电发生器介质层等效电容和负载特性研究

    Institute of Scientific and Technical Information of China (English)

    赵凯; 牟宗信; 张家良

    2014-01-01

    大气压介质阻挡放电(DBD)可以在常压下产生非平衡等离子体,已经成为热点研究领域。通过脉冲或交变电源激发放电,研究电源输出特性、电源与放电发生器负载间的匹配和外界条件对放电的影响对于理解放电现象和提高放电效率具有重要意义。本文采用Lissajous图形法,分别研究了驱动电压、气流速率等因素影响同轴DBD发生器介质层等效电容及负载幅频特性的规律。结果表明,气流速率和驱动电压等外界条件影响DBD发生器的负载特性:介质层等效电容随气流速率增大而减小,随驱动电压增大而增大;幅频特性曲线均表现出RLC回路谐振现象,谐振频率随气流速率增大而增大,随驱动电压增大而减小。通过对比发现,介质层等效电容随频率的变化曲线与幅频特性曲线具有一致的特征,介质层等效电容是影响电路谐振频率动态变化的主要因素。提出了一种有关介质层等效电容的形成机制。%Dielectric barrier discharge (DBD) can produce non-equilibrium plasma at atmospheric pressure, and it has become a hot point in recent years. For the DBD excited by pulsed or alternated currents, the effects of the loading performance of power supply, the matching between supply and discharge reactor and the discharge phenomena on its discharge are interesting issues. The studies of these issues are of great importance for understanding the DBD processes and improving the power supply efficiency. In this paper, the Lissajous figures of a DBD reactor with coaxial electrode configuration are measured. The loading performance of the DBD reactor and the dependences of excitation voltage and air flow rate on the dielectric layer equivalent capacitance are studied in atmospheric air. According to the experimental data and circuit modeling analysis, it is proved that the dielectric layer capacitance decreases with the increase of air flow rate

  17. Conversion of natural gas to C2 hydrocarbons through dielectric-barrier discharge plasma catalysis

    Institute of Scientific and Technical Information of China (English)

    王保伟; 许根慧

    2002-01-01

    The experiments are carried out in the system of continuous flow reactors with dielectric-barrier discharge (DBD) for studies on the conversion of natural gas to C2 hydrocarbons through plasma catalysis under the atmosphere pressure and room temperature. The influence of discharge frequency, structure of electrode, discharge voltage, number of electrode, ratio of H2/CH4, flow rate and catalyst on conversion of methane and selectivity of C2 hydrocarbons are investigated. At the same time, the reaction process is investigated. Higher conversion of methane and selectivity of C2 hydrocarbons are achieved and deposited carbons are eliminated by proper choice of parameters. The appropriate operation parameters in dielectric-barrier discharge plasma field are that the supply voltage is 20-40 kV (8.4-40 W), the frequency of power supply is 20 kHz, the structure of (b) electrode is suitable, and the flow of methane is 20-60 ml · min-1. The conversion of methane can reach 45%, the selectivity of C2 hydrocarbons i

  18. Dielectric Barrier Discharge Plasma-Induced Photocatalysis and Ozonation for the Treatment of Wastewater

    Science.gov (United States)

    Mok, Young Sun; Jo, Jin-Oh; Lee, Heon-Ju

    2008-02-01

    The physicochemical processes of dielectric barrier discharge (DBD) such as in-situ formation of chemically active species and emission of ultraviolet (UV)/visible light were utilized for the treatment of a simulated wastewater formed with Acid Red 4 as the model organic contaminant. The chemically active species (mostly ozone) produced in the DBD reactor were well distributed in the wastewater using a porous gas diffuser, thereby increasing the gas-liquid contact area. For the purpose of making the best use of the light emission, a titanium oxide-based photocatalyst was incorporated in the wastewater treating system. The experimental parameters chosen were the voltage applied to the DBD reactor, the initial pH of the wastewater, and the concentration of hydrogen peroxide added to the wastewater. The results have clearly shown that the present system capable of degrading organic contaminants in two ways (photocatalysis and ozonation) may be a promising wastewater treatment technology.

  19. Dielectric Barrier Discharge Plasma-Induced Photocatalysis and Ozonation for the Treatment of Wastewater

    Institute of Scientific and Technical Information of China (English)

    MOK Young Sun; JO Jin-Oh; LEE Heon-Ju

    2008-01-01

    The physicochemical processes of dielectric barrier discharge (DBD) such as in-situ formation of chemically active species and emission of ultraviolet (UV)/visible light were utilized for the treatment of a simulated wastewater formed with Acid Red 4 as the model organic contaminant. The chemically active species (mostly ozone) produced in the DBD reactor were well distributed in the wastewater using a porous gas diffuser, thereby increasing the gas-liquid contact area. For the purpose of making the best use of the light emission, a titanium oxide-based photocatalyst was incorporated in the wastewater treating system. The experimental parameters chosen were the voltage applied to the DBD reactor, the initial pH of the wastewater, and the concentration of hydrogen peroxide added to the wastewater. The results have clearly shown that the present system capable of degrading organic contaminants in two ways (photocatalysis and ozonation) may be a promising wastewater treatment technology.

  20. Effects of electrode geometry on the performance of dielectric barrier/packed-bed discharge plasmas in benzene degradation

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Nan [Institute of Electrostatics and Special Power, Dalian University of Technology, Dalian 116024 (China); Lu, Na; Shang, Kefeng [Institute of Electrostatics and Special Power, Dalian University of Technology, Dalian 116024 (China); Key Laboratory of Industrial Ecology and Environmental Engineering, Ministry of Education of the People' s Republic of China, Dalian 116024 (China); Li, Jie, E-mail: lijie@dlut.edu.cn [Institute of Electrostatics and Special Power, Dalian University of Technology, Dalian 116024 (China); Key Laboratory of Industrial Ecology and Environmental Engineering, Ministry of Education of the People' s Republic of China, Dalian 116024 (China); Wu, Yan [Institute of Electrostatics and Special Power, Dalian University of Technology, Dalian 116024 (China); Key Laboratory of Industrial Ecology and Environmental Engineering, Ministry of Education of the People' s Republic of China, Dalian 116024 (China)

    2013-11-15

    Highlights: • Benzene was successfully degraded by dielectric barrier/packed-bed discharge plasmas. • Different electrode geometry has distinct effect on plasmas oxidation performance. • Benzene degradation and energy performance were enhanced when using the coil electrode. • The reaction products were well determined by online FTIR analysis. -- Abstract: In this study, the effects of electrode geometry on benzene degradation in a dielectric barrier/packed-bed discharge plasma reactor with different electrodes were systematically investigated. Three electrodes were employed in the experiments, these were coil, bolt, and rod geometries. The reactor using the coil electrode showed better performance in reducing the dielectric loss in the barrier compared to that using the bolt or rod electrodes. In the case of the coil electrode, both the benzene degradation efficiency and energy yield were higher than those for the other electrodes, which can be attributed to the increased role of surface mediated reactions. Irrespective of the electrode geometry, the packed-bed discharge plasma was superior to the dielectric barrier discharge plasma in benzene degradation at any specific applied voltage. The main gaseous products of benzene degradation were CO, CO{sub 2}, H{sub 2}O, and formic acid. Discharge products such as O{sub 3}, N{sub 2}O, N{sub 2}O{sub 5}, and HNO{sub 3} were also detected in the outlet gas. Moreover, the presence of benzene inhibited the formation of ozone because of the competing reaction of oxygen atoms with benzene. This study is expected to offer an optimized approach combining dielectric barrier discharge and packed-bed discharge to improve the degradation of gaseous pollutants.

  1. Dielectric-barrier discharges in two-dimensional lattice potentials

    CERN Document Server

    Sinclair, Josiah

    2011-01-01

    We use a pin-grid electrode to introduce a corrugated electrical potential into a planar dielectric-barrier discharge (DBD) system, so that the amplitude of the applied electric field has the profile of a two-dimensional square lattice. The lattice potential provides a template for the spatial distribution of plasma filaments in the system and has pronounced effects on the patterns that can form. The positions at which filaments become localized within the lattice unit cell vary with the width of the discharge gap. The patterns that appear when filaments either overfill or under-fill the lattice are reminiscent of those observed in other physical systems involving 2d lattices. We suggest that the connection between lattice-driven DBDs and other areas of physics may benefit from the further development of models that treat plasma filaments as interacting particles.

  2. Atmospheric pressure dielectric barrier discharges for sterilization and surface treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chin, O. H.; Lai, C. K.; Choo, C. Y.; Wong, C. S.; Nor, R. M. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Thong, K. L. [Microbiology Division, Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-04-24

    Atmospheric pressure non-thermal dielectric barrier discharges can be generated in different configurations for different applications. For sterilization, a parallel-plate electrode configuration with glass dielectric that discharges in air was used. Gram-negative bacteria (Escherichia coli and Salmonella enteritidis) and Gram-positive bacteria (Bacillus cereus) were successfully inactivated using sinusoidal high voltage of ∼15 kVp-p at 8.5 kHz. In the surface treatment, a hemisphere and disc electrode arrangement that allowed a plasma jet to be extruded under controlled nitrogen gas flow (at 9.2 kHz, 20 kVp-p) was applied to enhance the wettability of PET (Mylar) film.

  3. Optical emission spectrum of filamentary nanosecond surface dielectric barrier discharge

    Science.gov (United States)

    Shcherbanev, S. A.; Khomenko, A. Yu; Stepanyan, S. A.; Popov, N. A.; Starikovskaia, S. M.

    2017-02-01

    Streamer-to-filament transition is a general feature of high pressure high voltage (HV) nanosecond surface dielectric barrier discharges. The transition was studied experimentally using time- and space-resolved optical emission in UV and visible parts of spectra. The discharge was initiated by HV pulses 20 ns in duration and 2 ns rise time, positive or negative polarity, 20-60 kV in amplitude on the HV electrode. The experiments were carried out in a single-shot regime at initial pressures P  >  3 bar and ambient initial temperature in air, N2, H2:N2 and O2:Ar mixtures. It was shown that the transition to filamentary mode is accompanied by the appearance of intense continuous radiation and broad atomic lines. Electron density calculated from line broadening is characterized by high absolute values and long decay in the afterglow. The possible reasons for the continuous spectra were analyzed.

  4. Language barriers and understanding of hospital discharge instructions.

    Science.gov (United States)

    Karliner, Leah S; Auerbach, Andrew; Nápoles, Anna; Schillinger, Dean; Nickleach, Dana; Pérez-Stable, Eliseo J

    2012-04-01

    Effective communication at hospital discharge is necessary for an optimal transition and to avoid adverse events. We investigated the association of a language barrier with patient understanding of discharge instructions. Spanish-speaking, Chinese-speaking, and English-speaking patients admitted to 2 urban hospitals between 2005 and 2008, comparing patient understanding of follow-up appointment type, and medication category and purpose between limited English-proficient (LEP) and English-proficient patients. Of the 308 patients, 203 were LEP. Rates of understanding were low overall for follow-up appointment type (56%) and the 3 medication outcomes (category 48%, purpose 55%, both 41%). In unadjusted analysis, LEP patients were less likely than English-proficient patients to know appointment type (50% vs. 66%; P=0.01), medication category (45% vs. 54%; P=0.05), and medication category and purpose combined (38% vs. 47%; P=0.04), but equally likely to know medication purpose alone. These results persisted in the adjusted models for medication outcomes: LEP patients had lower odds of understanding medication category (odds ratio 0.63; 95% confidence interval, 0.42-0.95); and category/purpose (odds ratio 0.59; 95% confidence interval, 0.39-0.89). Understanding of appointment type and medications after discharge was low, with LEP patients demonstrating worse understanding of medications. System interventions to improve communication at hospital discharge for all patients, and especially those with LEP, are needed.

  5. Simulation of transition from Townsend mode to glow discharge mode in a helium dielectric barrier discharge at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    Li Xue-Chen; Niu Dong-Ying; Xu Long-Fei; Jia Peng-Ying; Chang Yuan-Yuan

    2012-01-01

    The dielectric barrier discharge characteristics in helium at atmospheric pressure are simulated based on a one-dimensional fluid model.Under some discharge conditions,the results show that one discharge pulse per half voltage cycle usually appears when the amplitude of external voltage is low,while a glow-like discharge occurs at high voltage.For the one discharge pulse per half voltage cycle,the maximum of electron density appears near the anode at the beginning of the discharge,which corresponds to a Townsend discharge mode.The maxima of the electron density and the intensity of electric field appear in the vicinity of the cathode when the discharge current increases to some extent,which indicates the formation of a cathode-fall region.Therefore,the discharge has a transition from the Townsend mode to the glow discharge mode during one discharge pulse,which is consistent with previous experimental results.

  6. Average OH density in alternating current dielectric barrier discharge by laser-induced fluorescence technique

    Science.gov (United States)

    Yang, Hongliang; Feng, Chunlei; Gao, Liang; Ding, Hongbin

    2015-10-01

    The average OH density in atmospheric He-H2O(0.4%) needle-plate dielectric barrier discharge (DBD) was measured by the asynchronous laser-induced fluorescence (LIF) technique and the fluctuation of OH radical density was measured simultaneously to prove that the average OH density can be obtained by the asynchronous LIF technique. The evolution of the average OH density in four different discharge patterns, namely, negative barrier corona discharge, glow discharge, multi glow discharge, and streamer discharge, was studied, and it was found that the average OH density has an observable increase from corona discharge to streamer discharge. The main mechanism of OH production in the four different discharge patterns was analyzed. It was shown that the main mechanism of OH production in negative barrier corona discharge is electron direct collision dissociation, whereas in the other three discharge patterns the He metastable Penning ionization is the main process.

  7. The inactivation of Chlorella spp. with dielectric barrier discharge in gas-liquid mixture

    Science.gov (United States)

    Song, Dan; Sun, Bing; Zhu, Xiaomei; Yan, Zhiyu; Liu, Hui; Liu, Yongjun

    2013-03-01

    The inactivation of Chlorella spp. with high voltage and frequency pulsed dielectric barrier discharge in hybrid gas-liquid reactor with a suspension electrode was studied experimentally. In the hybrid gas-liquid reactor, a steel plate was used as high voltage electrode while a quartz plate as a dielectric layer, another steel plate placing in the aqueous solution worked as a whole ground electrode. A suspension electrode is installed near the surface of solution between high voltage and ground electrode to make the dielectric barrier discharge uniform and stable, the discharge gap was between the quartz plate and the surface of the water. The effect of peak voltage, treatment time, the initial concentration of Chlorella spp. and conductivity of solution on the inactivation rate of Chlorella spp. was investigated, and the inactivation mechanism of Chlorella spp. preliminarily was studied. Utilizing this system inactivation of Chlorella spp., the inactivation rate increased with increasing of peak voltage, treatment time and electric conductivity. It was found that the inactivation rate of Chlorella spp. arrived at 100% when the initial concentration was 4 × 106 cells mL-1, and the optimum operation condition required a peak voltage of 20 kV, a treatment time of 10 min and a frequency of 7 kHz. Though the increasing of initial concentration of the Chlorella spp. contributed to the addition of interaction probability between the Chlorella spp. and O3, H2O2, high-energy electrons, UV radiation and other active substances, the total inactivation number raise, but the inactivation rate of the Chlorella spp. decreased.

  8. Wire-cylinder dielectric barrier discharge induced degradation of aqueous atrazine.

    Science.gov (United States)

    Zhu, Dan; Jiang, Lin; Liu, Run-Long; Chen, Pei; Lang, Lin; Feng, Jing-Wei; Yuan, Shou-Jun; Zhao, Da-Yong

    2014-12-01

    The wire-cylinder dielectric barrier discharge reactor was adopted for removal of aqueous atrazine. The effect of different parameters on the degradation efficiency of atrazine was investigated, and the degradation mechanism of atrazine was studied. The experimental results showed that when the discharge power was 50 W and the air flow rate was 140 L h(-1), 93.7% of atrazine was degraded after 18 min of discharge time. The concentrations of generated O3 and H2O2 increased with increasing discharge time. The pH decreased from 6.80 to 2.50, 12.7% of TOC was removed after 18 min. The concentrations of generated Cl(-) and NO3(-) increased significantly during the degradation process of atrazine, and the decreasing toxicity trend was observed for the treated atrazine solution. The degradation byproducts of atrazine were identified using liquid chromatography-time-of-flight mass spectrometry (LC-TOF-MS), which might be formed mainly in dechlorination hydroxylation, alkyl oxidation, dechlorination hydroxylation combined with alkyl oxidation and demethylation oxidation reactions.

  9. Treatment of Wastewater by Ozone Produced in Dielectric Barrier Discharge

    Directory of Open Access Journals (Sweden)

    Rita Bhatta

    2015-01-01

    Full Text Available There is rapid diminishing of water resources in many countries due to, for example, population growth and constant reduction in fresh water supply. The sewage wastewater, industrial effluents, and municipal wastewater are directly and indiscriminately discharged into rivers and lakes and thus primarily cause water pollution in Nepal. This has increased the water crisis and also causes environmental deterioration. Therefore, the need for the development of an effective, cheap, and environmentally friendly process for the treatment of wastewater before discharging into aquatic environment has emerged. Treatment by ozone produced from dielectric barrier discharge is one of the emerging technologies for such application. The ozonation process is more effective for disinfection and degradation of organic pollutants from water. The current study describes the treatment of wastewater of selected site within Kathmandu. Results on various physicochemical and microbial parameters of the inlet and outlet samples are discussed. Our results showed slight increase in pH, decrease in chemical oxygen demand, and significant increase in dissolved oxygen after ozonation. Importantly, ozonation caused total reduction of fecal coliform.

  10. Evaluation of Dielectric-Barrier-Discharge Actuator Substrate Materials

    Science.gov (United States)

    Wilkinson, Stephen P.; Siochi, Emilie J.; Sauti, Godfrey; Xu, Tian-Bing; Meador, Mary Ann; Guo, Haiquan

    2014-01-01

    A key, enabling element of a dielectric barrier discharge (DBD) actuator is the dielectric substrate material. While various investigators have studied the performance of different homogeneous materials, most often in the context of related DBD experiments, fundamental studies focused solely on the dielectric materials have received less attention. The purpose of this study was to conduct an experimental assessment of the body-force-generating performance of a wide range of dielectric materials in search of opportunities to improve DBD actuator performance. Materials studied included commonly available plastics and glasses as well as a custom-fabricated polyimide aerogel. Diagnostics included static induced thrust, electrical circuit parameters for 2D surface discharges and 1D volume discharges, and dielectric material properties. Lumped-parameter circuit simulations for the 1D case were conducted showing good correspondence to experimental data provided that stray capacitances are included. The effect of atmospheric humidity on DBD performance was studied showing a large influence on thrust. The main conclusion is that for homogeneous, dielectric materials at forcing voltages less than that required for streamer formation, the material chemical composition appears to have no effect on body force generation when actuator impedance is properly accounted for.

  11. Influence of gas discharge parameters on emissions from a dielectric barrier discharge excited argon excimer lamp

    Directory of Open Access Journals (Sweden)

    Mike Collier

    2011-11-01

    Full Text Available A dielectric barrier discharge excited neutral argon (Ar I excimer lamp has been developed and characterised. The aim of this study was to develop an excimer lamp operating at atmospheric pressure that can replace mercury lamps and vacuum equipment used in the sterilisation of medical equipment and in the food industry. The effects of discharge gas pressure, flow rate, excitation frequency and pulse width on the intensity of the Ar I vacuum ultraviolet (VUV emission at 126 nm and near infrared (NIR lines at 750.4 nm and 811.5 nm have been investigated. These three lines were chosen as they represent emissions resulting from de-excitation of excimer states that emit energetic photons with an energy of 9.8 eV. We observed that the intensity of the VUV Ar2* excimer emission at 126 nm increased with increasing gas pressure, but decreased with increasing excitation pulse frequency and pulse width. In contrast, the intensities of the NIR lines decreased with increasing gas pressure and increased with increasing pulse frequency and pulse width. We have demonstrated that energetic VUV photons of 9.8 eV can be efficiently generated in a dielectric barrier discharge in Ar.

  12. Discharge and optical characterizations of nanosecond pulse sliding dielectric barrier discharge plasma for volatile organic compound degradation

    Science.gov (United States)

    Jiang, Nan; Guo, Lianjie; Shang, Kefeng; Lu, Na; Li, Jie; Wu, Yan

    2017-04-01

    In this work, a nanosecond bipolar pulsed voltage coupled with a negative DC component is employed to generate sliding dielectric barrier discharge (DBD) plasma in a three-electrode geometry reactor and improve volatile organic compound (VOC) degradation at room temperature. The effects of the bipolar pulsed voltage (U ±pulse) and negative DC voltage (U ‑DC) on the discharge characteristic, optical characteristic, plasma gas temperature (T gas), and vibrational temperature (T vib) are discussed. The horizontal distribution characteristics of the N2(C3Πu  →  B3Πg) emission intensity, T gas, and T vib are also investigated to understand the propagation mechanism of sliding DBD along the dielectric surface. The experimental results reveal that a negative DC component applied to a third electrode can extend the plasma extension region, indicating that the gas ionization is ignited by the nanosecond high-voltage pulse, while charge drift is forced by the surface potential difference caused by the negative high-voltage DC. The T gas is measured by optical emission spectroscopy related to the rotational bands of N2(C3 Πu  →  B3Πg), and is approximately 375  ±  5 K under the condition of U ±pulse  =  20 kV and U ‑DC  =  ‑20 kV. Compared with typical surface DBD plasma, sliding DBD plasma is quasi-diffusive and distributed more uniformly within the whole discharge gap. Furthermore, both surface DBD and sliding DBD are used for removing toluene from flowing air. It is found that sliding DBD has higher toluene degradation efficiency and energy yield than surface DBD when they are excited by the positive pulsed voltage (U +pulse).

  13. FUNCTIONAL PERFORMANCE, PARTICIPATION AND AUTONOMY AFTER DISCHARGE FROM PROSTHETIC REHABILITATION : BARRIERS, FACILITATORS AND OUTCOMES

    NARCIS (Netherlands)

    van Twillert, Sacha; Stuive, Ilse; Geertzen, Jan H. B.; Postema, Klaas; Lettinga, Ant T.

    2014-01-01

    Objective: To examine functional performance, participation and autonomy after discharge from prosthetic rehabilitation and to identify the barriers and facilitators affecting these outcomes. Design: Concurrent mixed-methods design. Quantitative and qualitative data were collected at discharge from

  14. Conversion of natural gas to C2 hydrocarbons through dielectric-barrier discharge plasma catalysis

    Institute of Scientific and Technical Information of China (English)

    王保伟; 许根慧

    2002-01-01

    The experiments are carried out in the system of continuous flow reactors with dielectric-barrier discharge (DBD) for studies on the conversion of natural gas to C2 hydrocarbons through plasma catalysis under the atmosphere pressure and room temperature. The influence of discharge frequency, structure of electrode, discharge voltage, number of electrode, ratio of H2/CH4, flow rate and catalyst on conversion of methane and selectivity of C2 hydrocarbons are investigated. At the same time, the reaction process is investigated. Higher conversion of methane and selectivity of C2 hydrocarbons are achieved and deposited carbons are eliminated by proper choice of parameters. The appropriate operation parameters in dielectric-barrier discharge plasma field are that the supply voltage is 20-40 kV (8.4-40 W), the frequency of power supply is 20 kHz, the structure of (b) electrode is suitable, and the flow of methane is 20-60 mL@min?1. The conversion of methane can reach 45%, the selectivity of C2 hydrocarbons is 76%, and the total selectivity of C2 hydrocarbons and C3 hydrocarbons is nearly 100%. The conversion of methane increases with the increase of voltage and decreases with the flow of methane increase; the selectivity of C2 hydrocarbons decreases with the increase of voltage and increases with the flow of methane increase. The selectivity of C2 hydrocarbons is improved with catalyst for conversion of natural gas to C2 hydrocarbons in plasma field. Methane molecule collision with radicals is mainly responsible for product formation.

  15. Sterilization of Turmeric by Atmospheric Pressure Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Setareh, Salarieh; Davoud, Dorranian

    2013-11-01

    In this study atmospheric pressure dielectric barrier discharge (DBD) plasma has been employed for sterilizing dry turmeric powders. A 6 kV, 6 kHz frequency generator was used to generate plasma with Ar, Ar/O2, He, and He/O2 gases between the 5 mm gap of two quartz covered electrodes. The complete sterilization time of samples due to plasma treatment was measured. The most important contaminant of turmeric is bacillus subtilis. The results show that the shortest sterilization time of 15 min is achieved by exposing the samples to Ar/O2 plasma. Survival curves of samples are exponential functions of time and the addition of oxygen to plasma leads to a significant increase of the absolute value of time constant of the curves. Magnitudes of protein and DNA in treated samples were increased to a similar value for all samples. Taste, color, and solubility of samples were not changed after the plasma treatment.

  16. Dielectric barrier discharge plasma pretreatment on hydrolysis of microcrystalline cellulose

    Science.gov (United States)

    Fangmin, HUANG; Zhouyang, LONG; Sa, LIU; Zhenglong, Qin

    2017-04-01

    Dielectric barrier discharge (DBD) plasma was used as a pretreatment method for downstream hydrolysis of microcrystalline cellulose (MCC). The degree of polymerization (DP) of MCC decreased after it was pretreated by DBD plasma under a carrier gas of air/argon. The effectiveness of depolymerization was found to be influenced by the crystallinity of MCC when under the pretreatment of DBD plasma. With the addition of tert-butyl alcohol in the treated MCC water suspension solution, depolymerization effectiveness of MCC was inhibited. When MCC was pretreated by DBD plasma for 30 min, the total reducing sugar concentration (TRSC) and liquefaction yield (LY) of pretreated-MCC (PMCC) increased by 82.98% and 34.18% respectively compared with those for raw MCC.

  17. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators

    Science.gov (United States)

    Likhanskii, Alexander

    2014-01-01

    Traditional approaches for active flow separation control using dielectric barrier discharge (DBD) plasma actuators are limited to relatively low speed flows and atmospheric conditions. This results in low feasibility of the DBDs for aerospace applications. For active flow control at turbine blades, fixed wings, and rotary wings and on hypersonic vehicles, DBD plasma actuators must perform at a wide range of conditions, including rarified flows and combustion mixtures. An efficient, comprehensive, physically based DBD simulation tool can optimize DBD plasma actuators for different operation conditions. Researchers are developing a DBD plasma actuator simulation tool for a wide range of ambient gas pressures. The tool will treat DBD using either kinetic, fluid, or hybrid models, depending on the DBD operational condition.

  18. Dielectric barrier discharge plasma pretreatment on hydrolysis of microcrystalline cellulose

    Science.gov (United States)

    Huang, Fangmin; Long, Zhouyang; Liu, Sa; Qin, Zhenglong

    2017-04-01

    Dielectric barrier discharge (DBD) plasma was used as a pretreatment method for downstream hydrolysis of microcrystalline cellulose (MCC). The degree of polymerization (DP) of MCC decreased after it was pretreated by DBD plasma under a carrier gas of air/argon. The effectiveness of depolymerization was found to be influenced by the crystallinity of MCC when under the pretreatment of DBD plasma. With the addition of tert-butyl alcohol in the treated MCC water suspension solution, depolymerization effectiveness of MCC was inhibited. When MCC was pretreated by DBD plasma for 30 min, the total reducing sugar concentration (TRSC) and liquefaction yield (LY) of pretreated-MCC (PMCC) increased by 82.98% and 34.18% respectively compared with those for raw MCC.

  19. Dielectric barrier discharge plasma treatment of cellulose nanofibre surfaces

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Madsen, Bo; Berglund, Linn

    2017-01-01

    on the nanofibre surface. Ultrasonic irradiation further enhanced the wetting and oxidation of the nanofibre coating. Scanning electron microscopic observations showed skeleton-like features on the plasma-treated surface, indicating preferential etching of weaker domains, such as low-molecular weight domains......Dielectric barrier discharge plasma treatment was applied to modify cellulose nanofibre (CNF) surfaces with and without ultrasonic irradiation. The plasma treatment improved the wetting by deionised water and glycerol, and increased the contents of oxygen, carbonyl group, and carboxyl group...... and amorphous phases. Ultrasonic irradiation also improved the uniformity of the treatment. Altogether, it is demonstrated that atmospheric pressure plasma treatment is a promising technique to modify the CNF surface before composite processing....

  20. Coal Liquefaction by Using Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Wang, Qiuying; Wu, Peng; Gu, Fan

    2013-07-01

    An innovative method for coal liquefaction by using dielectric barrier discharge (DBD) plasma in a short reaction time was developed. Using tetralin as the reaction medium, DBD plasma as the energy source, and a reaction time of 10 min at 140°C, up to 10% of coal was converted to liquid material. The results showed the feasibility of coal's liquefaction by DBD plasma under relatively moderate conditions. Simultaneously, it was clarified that the effect of DBD plasma treatment was opposed to the thermal effect of heating. An acid plasma sheath could be formed on the coal powder surface in DBD conditions, liquefied reactions could be carried out in the absence of inorganic acid, and the products were nearly neutral and with low causticity.

  1. Manufacturing of Dielectric Barrier Discharge Plasma Actuator for Degradation Resistance

    Science.gov (United States)

    Houser, Nicole M.

    The performance and broader application of dielectric barrier discharge (DBD) plasma actuators are restricted by the manufacturing methods currently employed. In the current work, two methodologies are proposed to build robust plasma actuators for active flow control; a protective silicone oil (PDMS) treatment for hand-cut and laid tape-based actuators and a microfabrication technique for glass-based devices. The microfabrication process, through which thin film electrodes are precisely deposited onto plasma-resistant glass substrates, is presented in detail. The resulting glass-based devices are characterized with respect to electrical properties and output for various operating conditions. The longevity of microfabricated devices is compared against silicone-treated and untreated hand-made devices of comparable geometries over 60 hours of continuous operation. Both tungsten and copper electrodes are considered for microfabricated devices. Human health effects are also considered in an electromagnetic field study of the area surrounding a live plasma actuator for various operating conditions.

  2. Initiation of extended arc discharge in ICF reactor dense atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Kislev, H.

    1986-01-01

    Reduced density plasma channels are essential for LIB transport from external diodes to an ICF pellet centered in the 2-4 MPa superheated steamfilled cavity of the Heavy Water ICF Reactor. Forming such channels by ohmic heating requires the initiation of straight arc discharges along each beamline. The goal of this thesis is to evaluate the threshold beamline preionization and applied electric field for arc initiation. The capability of several preionizers to produce a straight preionized trail is evaluated through a ten-group Boltzmann equation solver. Electron densities around 10/sup 17/ m/sup -3/ could be maintained in the trail by monojoule output external preionizers. Trail preionization through the co-application of UV and CO/sub 2/ lasers appears to be the most promising technique. UV laser preionization of NO(a/sup 4/..pi..) formed in the fireball shows also good prospective. The large divergence of soft x-ray sources reduces their attractivity. The E/N dependent electron transport properties are used to construct the first streamer model capable of evaluating the steady state streamer wave shape. The streamers-induced highly ionized filament transition into a multi-kA carrying plasma channel is simulated by a modified radiation-MHD one-dimensional code.

  3. Ambient-temperature trap/release of arsenic by dielectric barrier discharge and its application to ultratrace arsenic determination in surface water followed by atomic fluorescence spectrometry

    Science.gov (United States)

    A novel dielectric barrier discharge reactor (DBDR) was utilized to trap/release arsenic coupled to hydride generation atomic fluorescence spectrometry (HGAFS). On the DBD principle, the precise and accurate control of trap/release procedures was fulfilled at ambient temperature, and an analytical m...

  4. Improved performance of parallel surface/packed-bed discharge reactor for indoor VOCs decomposition: optimization of the reactor structure

    Science.gov (United States)

    Jiang, Nan; Hui, Chun-Xue; Li, Jie; Lu, Na; Shang, Ke-Feng; Wu, Yan; Mizuno, Akira

    2015-10-01

    The purpose of this paper is to develop a high-efficiency air-cleaning system for volatile organic compounds (VOCs) existing in the workshop of a chemical factory. A novel parallel surface/packed-bed discharge (PSPBD) reactor, which utilized a combination of surface discharge (SD) plasma with packed-bed discharge (PBD) plasma, was designed and employed for VOCs removal in a closed vessel. In order to optimize the structure of the PSPBD reactor, the discharge characteristic, benzene removal efficiency, and energy yield were compared for different discharge lengths, quartz tube diameters, shapes of external high-voltage electrode, packed-bed discharge gaps, and packing pellet sizes, respectively. In the circulation test, 52.8% of benzene was removed and the energy yield achieved 0.79 mg kJ-1 after a 210 min discharge treatment in the PSPBD reactor, which was 10.3% and 0.18 mg kJ-1 higher, respectively, than in the SD reactor, 21.8% and 0.34 mg kJ-1 higher, respectively, than in the PBD reactor at 53 J l-1. The improved performance in benzene removal and energy yield can be attributed to the plasma chemistry effect of the sequential processing in the PSPBD reactor. The VOCs mineralization and organic intermediates generated during discharge treatment were followed by CO x selectivity and FT-IR analyses. The experimental results indicate that the PSPBD plasma process is an effective and energy-efficient approach for VOCs removal in an indoor environment.

  5. Atmospheric-pressure dielectric barrier discharge generation by a full-bridge flying capacitor multilevel inverter

    Science.gov (United States)

    Peña-Eguiluz, Rosendo; López-Fernández, José, A.; Mercado-Cabrera, Antonio; Jaramillo-Sierra, Bethsabet; López-Callejas, Régulo; Rodríguez-Méndez, Benjamín; Valencia-Alvarado, Raúl; Flores-Fuentes, Allan, A.; Muñoz-Castro, Arturo E.

    2017-07-01

    A new configuration of a resonant full-bridge flying capacitor multicell inverter has been designed and constructed with the aim of achieving an extended output voltage frequency range with low harmonic distortion and reduced semiconductor commutation losses. This configuration was tested as a power supply for two different coaxial dielectric barrier discharge reactors, one of them employed for electric characterization and the other one for inorganic compound elimination in an aqueous solution. Two different gas mixtures, 90% Ar-10% O2 and 80% Ar-20% O2, were individually supplied during the experiments; the results showed a high-efficiency removal of meta-cresol (m-cresol) to the order of 98%, which was obtained by adding more oxygen to the plasma gas mixture.

  6. Cylindrical dielectric barrier discharge plasma catalytic effect on chemical methods of silver nano-particle production

    Science.gov (United States)

    Bahrami, Zahra; Khani, Mohammad Reza; Shokri, Babak

    2016-11-01

    In this study, cylindrical dielectric barrier discharge plasma was used to study the catalytic effect on chemical methods of silver nano-particles for the first time. In this method, the processing time is short and the temperature of reaction is low. Also, the reactor is very simple, inexpensive, and accessible. In this work, pure AgNO3 as the precursor agent and poly vinyl pyrrolidone as the macromolecular surfactant were dissolved in ethanol as the solvent. UV-Vis and XRD were used to identify the colloidal and powder nano-particles, respectively. Optical emission spectroscopy was also used to identify the active species in plasma. Effects of gas flow rate, voltage, volume of solution, and processing time were also studied. Moreover, TEM and SEM images presented the mean diameter of nano-particle size around 10 to 20 nm. The results have been very promising.

  7. Stabilization of premixed lean methane-air combustion using dielectric barrier discharge with low pollutant emissions

    Science.gov (United States)

    Ono, Ryo; Ogura, Kazuaki; Mogi, Toshio

    2017-09-01

    Catalytic combustion is a promising technology to stabilize lean combustion with low pollutant emissions. Catalytic combustion has been applied to gas turbine combustors; however, some drawbacks of this technology remain to be addressed. In this work, a new concept is demonstrated to overcome the problems of catalytic combustion by using dielectric barrier discharge (DBD) instead of a catalyst. A premixed lean methane-air mixture preheated to 400 °C with an equivalence ratio of 0.45 is flowed through the DBD reactor under atmospheric pressure. Almost complete combustion is achieved with a DBD power of 0.7% of the net calorific value of the mixture. The exhaust emissions are NO = 20 ppm, NO2 = 2 ppm, CO = 2 ppm, and HC \\cong 0 ppm. This work demonstrates that DBD-assisted combustion is a potential alternative to catalytic combustion.

  8. Conversion of carbon dioxide to carbon monoxide by pulse dielectric barrier discharge plasma

    Science.gov (United States)

    Wang, Taobo; Liu, Hongxia; Xiong, Xiang; Feng, Xinxin

    2017-01-01

    The conversion of carbon dioxide (CO2) to carbon monoxide (CO) was investigated in a non-thermal plasma dielectric barrier discharge (DBD) reactor, and the effects of different process conditions on the CO2 conversion were investigated. The results showed that the increase of input power could optimize the conversion of CO2 to CO. The CO2 conversion and CO yield were negatively correlated with the gas flow rate, but there was an optimum gas flow rate, that made the CO selectivity best. The carrier gas (N2, Ar) was conducive to the conversion of CO2, and the effect of N2 as carrier gas was better than Ar. The conversion of CO2 to CO was enhanced by addition of the catalyst (5A molecular sieve).

  9. Production of Ar metastables in a dielectric barrier discharge

    Science.gov (United States)

    Mikheyev, Pavel A.; Han, Jiande; Clark, Amanda; Sanderson, Carl; Heaven, Michael C.

    2017-01-01

    The results of experiments with a dielectric barrier discharge (DBD) are presented, where the production of metastable argon atoms was studied. The recently proposed optically pumped all-rare-gas laser (OPRGL) utilizes metastable atoms of heavier rare gases as lasing species. The required number density of metastables for efficient laser operation is 1012÷1013 cm-3 in an atmospheric pressure of He buffer gas. Recent experiments had shown that such densities are easily produced in a nanosecond pulsed discharge, even at pressures larger than atmospheric, but problems appear when one is trying to produce them in a CW regime. The reason for difficulties in the CW production of metastables at an atmospheric pressure seems to be the low value of the E/N parameter (DBD in 2-5% Ar mixture with He at an atmospheric pressure was studied. [Ar(1s5)] number density of the order of 1012 cm-3 was readily achieved. Temporal behavior of [Ar(1s5)] throughout the DBD cycle was obtained. The results demonstrate the feasibility of DBDs for OPRGL development.

  10. Simulation of pulsed dielectric barrier discharge xenon excimer lamp

    Science.gov (United States)

    Bogdanov, E. A.; Kudryavtsev, A. A.; Arslanbekov, R. R.; Kolobov, V. I.

    2004-11-01

    Recently, it has been shown that the efficiency of excimer lamps can be drastically increased in a pulsed regime. A one-dimensional simulation of pulsed excimer lamps has been performed by Carman and Mildren (2003 J. Phys. D: Appl. Phys. 36 19) (C&M). However, some computational results of the work of C&M are questionable and need to be revisited. In this paper, a dielectric barrier discharge (DBD) in xenon has been simulated for operating conditions similar to those of C&M to better understand plasma dynamics in a pulsed regime. Our simulation results differ considerably from the computational results of C&M. Although these differences do not affect profoundly the plasma macro parameters measured in the C&M experiments, they offer a better understanding of plasma dynamics in pulsed DBDs and form a solid foundation for computational optimization of excimer lamps. It was found that the dynamics of breakdown and the current pulse depend significantly on the initial densities of species after a previous pulse, and so it is important to accurately simulate the plasma evolution in both the afterglow and active stages. It seems possible to modify the power deposition in the plasma by varying external discharge parameters such as the amplitude and the rise time of the applied voltage, and to modify the plasma composition by changing the pulse repetition rate and plasma decay in the afterglow stage.

  11. Simulation of pulsed dielectric barrier discharge xenon excimer lamp

    Energy Technology Data Exchange (ETDEWEB)

    Bogdanov, E A [St Petersburg State University, St Petersburg (Russian Federation); Kudryavtsev, A A [St Petersburg State University, St Petersburg (Russian Federation); Arslanbekov, R R [CFD Research Corporation, Huntsville (United States); Kolobov, V I [CFD Research Corporation, Huntsville (United States)

    2004-11-07

    Recently, it has been shown that the efficiency of excimer lamps can be drastically increased in a pulsed regime. A one-dimensional simulation of pulsed excimer lamps has been performed by Carman and Mildren (2003 J. Phys. D: Appl. Phys. 36 19) (C and M). However, some computational results of the work of C and M are questionable and need to be revisited. In this paper, a dielectric barrier discharge (DBD) in xenon has been simulated for operating conditions similar to those of C and M to better understand plasma dynamics in a pulsed regime. Our simulation results differ considerably from the computational results of C and M. Although these differences do not affect profoundly the plasma macro parameters measured in the C and M experiments, they offer a better understanding of plasma dynamics in pulsed DBDs and form a solid foundation for computational optimization of excimer lamps. It was found that the dynamics of breakdown and the current pulse depend significantly on the initial densities of species after a previous pulse, and so it is important to accurately simulate the plasma evolution in both the afterglow and active stages. It seems possible to modify the power deposition in the plasma by varying external discharge parameters such as the amplitude and the rise time of the applied voltage, and to modify the plasma composition by changing the pulse repetition rate and plasma decay in the afterglow stage.

  12. Dielectric barrier discharge plasma actuator for flow control

    Science.gov (United States)

    Opaits, Dmitry Florievich

    Electrohydrodynamic (EHD) and magnetohydrodynamic phenomena are being widely studied for aerodynamic applications. The major effects of these phenomena are heating of the gas, body force generation, and enthalpy addition or extraction, [1, 2, 3]. In particular, asymmetric dielectric barrier discharge (DBD) plasma actuators are known to be effective EHD device in aerodynamic control, [4, 5]. Experiments have demonstrated their effectiveness in separation control, acoustic noise reduction, and other aeronautic applications. In contrast to conventional DBD actuators driven by sinusoidal voltages, we proposed and used a voltage profile consisting of nanosecond pulses superimposed on dc bias voltage. This produces what is essentially a non-self-sustained discharge: the plasma is generated by repetitive short pulses, and the pushing of the gas occurs primarily due to the bias voltage. The advantage of this non-self-sustained discharge is that the parameters of ionizing pulses and the driving bias voltage can be varied independently, which adds flexibility to control and optimization of the actuators performance. Experimental studies were conducted of a flow induced in a quiescent room air by a single DBD actuator. A new approach for non-intrusive diagnostics of plasma actuator induced flows in quiescent gas was proposed, consisting of three elements coupled together: the Schlieren technique, burst mode of plasma actuator operation, and 2-D numerical fluid modeling. During the experiments, it was found that DBD performance is severely limited by surface charge accumulation on the dielectric. Several ways to mitigate the surface charge were found: using a reversing DC bias potential, three-electrode configuration, slightly conductive dielectrics, and semi conductive coatings. Force balance measurements proved the effectiveness of the suggested configurations and advantages of the new voltage profile (pulses+bias) over the traditional sinusoidal one at relatively low

  13. Plutonium Discharge Rates and Spent Nuclear Fuel Inventory Estimates for Nuclear Reactors Worldwide

    Energy Technology Data Exchange (ETDEWEB)

    Brian K. Castle; Shauna A. Hoiland; Richard A. Rankin; James W. Sterbentz

    2012-09-01

    This report presents a preliminary survey and analysis of the five primary types of commercial nuclear power reactors currently in use around the world. Plutonium mass discharge rates from the reactors’ spent fuel at reload are estimated based on a simple methodology that is able to use limited reactor burnup and operational characteristics collected from a variety of public domain sources. Selected commercial reactor operating and nuclear core characteristics are also given for each reactor type. In addition to the worldwide commercial reactors survey, a materials test reactor survey was conducted to identify reactors of this type with a significant core power rating. Over 100 material or research reactors with a core power rating >1 MW fall into this category. Fuel characteristics and spent fuel inventories for these material test reactors are also provided herein.

  14. Study on hexagonal super-lattice pattern with surface discharges in dielectric barrier discharge

    Science.gov (United States)

    Liu, Ying; Dong, Lifang; Niu, Xuejiao; Gao, Yenan; Zhang, Chao

    2015-10-01

    The hexagonal super-lattice pattern with surface discharges (SDs) in dielectric barrier discharge is investigated by intensified charge-coupled device. The pattern is composed of the bright spot and the dim spot which is located at the centroid of surrounding other three bright spots. The phase diagram of the pattern as a function of the gas pressure and the argon concentration is given. The instantaneous images indicate that the bright spot emerging at the front of the current pulse is formed by the volume discharge (VD), and dim spot occurring at the tail of the current pulse is formed by the SD. The above result shows that the SD is induced by the VD. The simulation of the electric fields of wall charges accumulated by VDs confirms that the dim spot is formed by the confluences of the SDs of surrounding other three bright spots. By using optical emission spectrum method, both the molecule vibration temperature and electron density of the SD are larger than that of the VD.

  15. Dielectric barrier discharges: progress on plasma sources and on the understanding of regimes and single filaments

    Science.gov (United States)

    Brandenburg, Ronny

    2017-05-01

    Dielectric barrier discharges (DBDs) are plasmas generated in configurations with an insulating (dielectric) material between the electrodes which is responsible for a self-pulsing operation. DBDs are a typical example of nonthermal atmospheric or normal pressure gas discharges. Initially used for the generation of ozone, they have opened up many other fields of application. Therefore DBDs are a relevant tool in current plasma technology as well as an object for fundamental studies. Another motivation for further research is the fact that so-called partial discharges in insulated high voltage systems are special types of DBDs. The breakdown processes, the formation of structures, and the role of surface processes are currently under investigation. This review is intended to give an update to the already existing literature on DBDs considering the research and development within the last two decades. The main principles and different modes of discharge generation are summarized. A collection of known as well as special electrode configurations and reactor designs will be presented. This shall demonstrate the different and broad possibilities, but also the similarities and common aspects of devices for different fields of applications explored within the last years. The main part is devoted to the progress on the investigation of different aspects of breakdown and plasma formation with the focus on single filaments or microdischarges. This includes a summary of the current knowledge on the electrical characterization of filamentary DBDs. In particular, the recent new insights on the elementary volume and surface memory mechanisms in these discharges will be discussed. An outlook for the forthcoming challenges on research and development will be given.

  16. The Chlorella killed by pulsed electrical discharge in liquid with two different reactors

    Science.gov (United States)

    Gao, Z. Y.; Sun, B.; Yan, Z. Y.; Zhu, X. M.; Liu, H.; Song, Y. J.; Sato, M.

    2013-03-01

    The application of pulsed high-voltage discharge in liquid has attracted wide attention as an effective water treatment. In this paper, two different liquid high-voltage discharge systems were constructed with plate-hole-plate and needle-plate electrode structures, and the inactivation behaviors of Chlorella were studied in the two reactors. The results show that the killing rates of algae in both reactors all increased significantly with increasing discharge voltage and the killing rates were intensely related to discharge power, instantaneous power and single pulse input energy. Furthermore, the inactivation effect in needle-plate reactor was superior to that in plate-hole-plate reactor under the same experimental conditions.

  17. Degradation of Acid Orange 7 Dye in Two Hybrid Plasma Discharge Reactors

    Institute of Scientific and Technical Information of China (English)

    SHEN Yongjun; LEI Lecheng; ZHANG Xingwang; DING Jiandong

    2014-01-01

    To get an optimized pulsed electrical plasma discharge reactor and to increase the energy utilization efficiency in the removal of pollutants,two hybrid plasma discharge reactors were designed and optimized.The reactors were compared via the discharge characteristics,energy transfer efficiency,the yields of the active species and the energy utilization in dye wastewater degradation.The results showed that under the same AC input power,the characteristics of the discharge waveform of the point-to-plate reactor were better.Under the same AC input power,the two reactors both had almost the same peak voltage of 22 kV.The peak current of the point-to-plate reactor was 146 A,while that of the wire-to-cylinder reactor was only 48.8 A.The peak powers of the point-to-plate reactor and the wire-to-cylinder reactor were 1.38 MW and 1.01 MW,respectively.The energy per pulse of the point-to-plate reactor was 0.2221 J,which was about 29.4% higher than that of the wire-to-cylinder reactor (0.1716 J).To remove 50% Acid Orange 7 (AO7),the energy utilizations of the point-to-plate reactor and the wireto-cylinder reactor were 1.02×10-9 mol/L and 0.61×10-9 mol/L,respectively.In the point-to-plate reactor,the concentration of hydrogen peroxide in pure water was 3.6 mmol/L after 40 min of discharge,which was higher than that of the wire-to-cylinder reactor (2.5 mmol/L).The concentration of liquid phase ozone in the point-to-plate reactor (5.7×10-2 mmol/L) was about 26.7% higher than that in the wire-to-cylinder reactor (4.5× 10-2 mmol/L).The analysis results of the variance showed that the type of reactor and reaction time had significant impacts on the yields of the hydrogen peroxide and ozone.The main degradation intermediates of AO7 identified by gas chromatography and mass spectrometry (GCMS) were acetic acid,maleic anhydride,pbenzoquinone,phenol,benzoic acid,phthalic anhydride,coumarin and 2-naphthol.Proposed degradation pathways were elucidated in light of the analyzed

  18. Characterization of a dielectric barrier discharge in contact with liquid and producing a plasma activated water

    Science.gov (United States)

    Neretti, G.; Taglioli, M.; Colonna, G.; Borghi, C. A.

    2017-01-01

    In this work a low-temperature plasma source for the generation of plasma activated water (PAW) is developed and characterized. The plasma reactor was operated by means of an atmospheric-pressure air dielectric barrier discharge (DBD). The plasma generated is in contact with the water surface and is able to chemically activate the liquid medium. Electrodes were supplied by both sinusoidal and nanosecond-pulsed voltage waveforms. Treatment times were varied from 2 to 12 min to increase the energy dose released to the water by the DBD plasma. The physics of the discharge was studied by means of electrical, spectroscopic and imaging diagnostics. The interaction between the plasma and the liquid was investigated as well. Temperature and composition of the treated water were detected. Images of the discharges showed a filamentary behaviour in the sinusoidal case and a more homogeneous behaviour in the nanosecond-pulsed one. The images and the electrical measurements allowed to evaluate an average electron number density of about 4  ×  1019 and 6  ×  1017 m-3 for the sinusoidal and nanosecond-pulsed discharges respectively. Electron temperatures in the range of 2.1÷2.6 eV were measured by using spectroscopic diagnostics. Rotational temperatures in the range of 318-475 K were estimated by fitting synthetic spectra with the measured ones. Water temperature and pH level did not change significantly after the exposure to the DBD plasma. The production of ozone and hydrogen peroxide within the water was enhanced by increasing the plasma treatment time and the energy dose. Numerical simulations of the nanosecond-pulsed discharge were performed by using a self-consistent coupling of state-to-state kinetics of the air mixture with the Boltzmann equation of free electron kinetics. Temporal evolution of the electron energy distribution function shows departure from the Maxwellian distribution especially during the afterglow phase of the discharge. When

  19. Dielectric Barrier Discharge Plasma Actuator for Flow Control

    Science.gov (United States)

    Opaits, Dmitry, F.

    2012-01-01

    This report is Part II of the final report of NASA Cooperative Agreement contract no. NNX07AC02A. It includes a Ph.D. dissertation. The period of performance was January 1, 2007 to December 31, 2010. Part I of the final report is the overview published as NASA/CR-2012- 217654. Asymmetric dielectric barrier discharge (DBD) plasma actuators driven by nanosecond pulses superimposed on dc bias voltage are studied experimentally. This produces non-self-sustained discharge: the plasma is generated by repetitive short pulses, and the pushing of the gas occurs primarily due to the bias voltage. The parameters of ionizing pulses and the driving bias voltage can be varied independently, which adds flexibility to control and optimization of the actuators performance. The approach consisted of three elements coupled together: the Schlieren technique, burst mode of plasma actuator operation, and 2-D numerical fluid modeling. During the experiments, it was found that DBD performance is severely limited by surface charge accumulation on the dielectric. Several ways to mitigate the surface charge were found: using a reversing DC bias potential, three-electrode configuration, slightly conductive dielectrics, and semi conductive coatings. Force balance measurements proved the effectiveness of the suggested configurations and advantages of the new voltage profile (pulses+bias) over the traditional sinusoidal one at relatively low voltages. In view of practical applications certain questions have been also addressed, such as electrodynamic effects which accompany scaling of the actuators to real size models, and environmental effects of ozone production by the plasma actuators.

  20. STUDY OF DESTRUCTION PROCESSES OF SYNTHETIC SURFACE-ACTIVE SUBSTENCES (SURFFACTANTS IN BARRIER DISCHARGE

    Directory of Open Access Journals (Sweden)

    V.I. Grinevich

    2012-06-01

    Full Text Available Kinetic data of degradation on aqueous solutions of surfactants in the plasma of barrier discharge are presented. The possible mechanism of proceeding processes is offered and considered. It is shown that the treatment in a barrier discharge results in decomposition efficiency of 95%. It is established that the main product of degradation are carboxylic acids.

  1. Volume Diffuse Dielectric Barrier Discharge Plasma Produced by Nanosecond High Voltage Pulse in Airflow

    Institute of Scientific and Technical Information of China (English)

    QI Haicheng; GAO Wei; FAN Zhihui; LIU Yidi; REN Chunsheng

    2016-01-01

    Volume diffuse dielectric barrier discharge (DBD) plasma is produced in subsonic airflow by nanosecond high-voltage pulse power supply with a plate-to-plate discharge cell at 6 mm air gap length.The discharge images,optical emission spectra (OES),the applied voltage and current waveforms of the discharge at the changed airflow rates are obtained.When airflow rate is increased,the transition of the discharge mode and the variations of discharge intensity,breakdown characteristics and the temperature of the discharge plasma are investigated.The results show that the discharge becomes more diffuse,discharge intensity is decreased accompanied by the increased breakdown voltage and time lag,and the temperature of the discharge plasma reduces when airflow of small vclocity is introduced into the discharge gap.These phenomena are because that the airflow changes the spatial distribution of the heat and the space charge in the discharge gap.

  2. Volume Diffuse Dielectric Barrier Discharge Plasma Produced by Nanosecond High Voltage Pulse in Airflow

    Science.gov (United States)

    Qi, Haicheng; Gao, Wei; Fan, Zhihui; Liu, Yidi; Ren, Chunsheng

    2016-05-01

    Volume diffuse dielectric barrier discharge (DBD) plasma is produced in subsonic airflow by nanosecond high-voltage pulse power supply with a plate-to-plate discharge cell at 6 mm air gap length. The discharge images, optical emission spectra (OES), the applied voltage and current waveforms of the discharge at the changed airflow rates are obtained. When airflow rate is increased, the transition of the discharge mode and the variations of discharge intensity, breakdown characteristics and the temperature of the discharge plasma are investigated. The results show that the discharge becomes more diffuse, discharge intensity is decreased accompanied by the increased breakdown voltage and time lag, and the temperature of the discharge plasma reduces when airflow of small velocity is introduced into the discharge gap. These phenomena are because that the airflow changes the spatial distribution of the heat and the space charge in the discharge gap. supported by National Natural Science Foundation of China (No. 51437002)

  3. The Fast-Flow Discharge Reactor as an Undergraduate Instructional Tool.

    Science.gov (United States)

    Provencher, G. M.

    1981-01-01

    A fast-flow discharge reactor has been used in an analytical chemistry demonstration of gas phase titration, in inorganic preparative chemistry, and in physical chemistry as a "practice" vacuum line, kinetic reactor, and spectroscopic source as well as an undergraduate research tool. (SK)

  4. Carbon dioxide conversion by means of coplanar dielectric barrier discharges

    Science.gov (United States)

    Schiorlin, Milko; Klink, Rouven; Brandenburg, Ronny

    2016-08-01

    To face the worldwide problem of anthropogenic carbon dioxide (CO2) emission new techniques have to be developed. One approach for carbon capture utilization (CCU) is the conversion of CO2 to more valuable chemicals, e.g., carbon monoxide (CO) by means of non-thermal plasma generated at ambient conditions and supplied by excess energy from renewable sources. This paper reports about the effect of the admixture of inert gases, namely nitrogen or argon to CO2 in a coplanar dielectric barrier discharge (DBD). Systematic experiments were conducted to investigate the effects of applied voltage, frequency, flowrate and CO2 concentration in the influent. The composition of products, energy efficiency and yield were determined. Within the investigated parameter ranges, the maximum conversion of CO2 to CO efficiency of 1% was achieved when the specific input energy was 190 J L-1, whereas the maximum CO yield of 0.7% was achieved when the specific input energy was 210 J L-1. In conclusion, the energy efficiency can be significantly increased by operating the plasma in a diluted CO2 gas. Contribution to the topical issue "6th Central European Symposium on Plasma Chemistry (CESPC-6)", edited by Nicolas Gherardi, Ester Marotta and Cristina Paradisi

  5. Improvement of water quality using dielectric barrier discharge plasma

    Science.gov (United States)

    Quyen, N. T.; Traikool, T.; Nitisoravut, R.; Onjun, T.

    2017-06-01

    The improvement of water quality using by atmospheric plasma produced from a dielectric barrier discharge (DBD) was studied. An experiment was set-up with a 4 mm diameter pipe, which contains 2 electrodes and has an air flow with the rate of 15 liters per minute. Surface water, domestic wastewater and DI water were treated with the DBD plasma for some period of time. Electricity was supplied at 3.5 kV with the frequency of 5.5 kHz. Some key parameters of water quality includes the level of chemical oxygen demand (COD), total suspended solid (TSS), color, and odor are measured before and after. The result showed that strong acid with pH below 2 was observed after 60 minutes plasma treatment for the DI water, while the surface water and wastewater needs about 120 minutes to pH below 2 even though the pH value are about the same at the beginning. Moreover, It was formed that the COD, TSS microorganism was noticeably decreased, therefore the increasing of transparency level. This result confirms that atmospheric DBD plasma generated acidity in water as reduce amount of organic and suspended solid in water.

  6. Decolorization of reactive textile dyes using water falling film dielectric barrier discharge.

    Science.gov (United States)

    Dojčinović, Biljana P; Roglić, Goran M; Obradović, Bratislav M; Kuraica, Milorad M; Kostić, Mirjana M; Nešić, Jelena; Manojlović, Dragan D

    2011-08-30

    Decolorization of reactive textile dyes Reactive Black 5, Reactive Blue 52, Reactive Yellow 125 and Reactive Green 15 was studied using advanced oxidation processes (AOPs) in a non-thermal plasma reactor, based on coaxial water falling film dielectric barrier discharge (DBD). Used initial dye concentrations in the solution were 40.0 and 80.0mg/L. The effects of different initial pH of dye solutions, and addition of homogeneous catalysts (H(2)O(2), Fe(2+) and Cu(2+)) on the decolorization during subsequent recirculation of dye solution through the DBD reactor, i.e. applied energy density (45-315kJ/L) were studied. Influence of residence time was investigated over a period of 24h. Change of pH values and effect of pH adjustments of dye solution after each recirculation on the decolorization was also tested. It was found that the initial pH of dye solutions and pH adjustments of dye solution after each recirculation did not influence the decolorization. The most effective decolorization of 97% was obtained with addition of 10mM H(2)O(2) in a system of 80.0mg/L Reactive Black 5 with applied energy density of 45kJ/L, after residence time of 24h from plasma treatment. Toxicity was evaluated using the brine shrimp Artemia salina as a test organism.

  7. Decolorization of reactive black 5 using dielectric barrier discharge in the presence of inorganic salts

    Directory of Open Access Journals (Sweden)

    Dojčinović Biljana P.

    2012-01-01

    Full Text Available Inorganic salts improve the coloration of textiles, which increase pollution load on dyehouse effluent in general. Decolorization of reactive textile dye C.I. Reactive Black 5 was studied using Advanced Oxidation Processes (AOPs in a non-thermal plasma reactor, based on coaxial water falling film Dielectric Barrier Discharge (DBD. Initial dye concentration in the solution was 40.0 mg L-1. The effects of addition of inorganic salt different high concentrations (NaCl, Na2SO4 and Na2CO3 on the degree of decolorization were studied. Recirculation of dye solution through the DBD reactor with applied energy density 45-315 kJ L-1 was used. The influence of residence time was investigated after 5 minutes and 24 hours of plasma treatment. Decolorization of the dyes was monitored by spectrophotometric measurement. Changes of pH values and the conductivity of dye solution after each recirculation were tested. The most effective decolorization of over 90% was obtained with the addition of NaCl (50 g L-1, applied energy density of 135 kJ L-1 and after residence time of 24 hours of plasma treatment. Decolorization of solutions containing inorganic salts Na2SO4 and Na2CO3 were lower than for the solution without salt.

  8. Particle-in-cell modeling of gas-confined barrier discharge

    Science.gov (United States)

    Levko, Dmitry; Raja, Laxminarayan L.

    2016-04-01

    Gas-confined barrier discharge is studied using the one-dimensional Particle-in-Cell Monte Carlo Collisions model for the conditions reported by Guerra-Garcia and Martinez-Sanchez [Appl. Phys. Lett. 106, 041601 (2015)]. Depending on the applied voltage, two modes of discharge are observed. In the first mode, the discharge develops in the entire interelectrode gap. In the second mode, the discharge is ignited and develops only in the gas layer having smaller breakdown voltage. The one-dimensional model shows that for the conditions considered, there is no streamer stage of breakdown as is typical for a traditional dielectric barrier discharge.

  9. Particle-in-cell modeling of gas-confined barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Levko, Dmitry; Raja, Laxminarayan L. [Department of Aerospace Engineering and Engineering Mechanics, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2016-04-15

    Gas-confined barrier discharge is studied using the one-dimensional Particle-in-Cell Monte Carlo Collisions model for the conditions reported by Guerra-Garcia and Martinez-Sanchez [Appl. Phys. Lett. 106, 041601 (2015)]. Depending on the applied voltage, two modes of discharge are observed. In the first mode, the discharge develops in the entire interelectrode gap. In the second mode, the discharge is ignited and develops only in the gas layer having smaller breakdown voltage. The one-dimensional model shows that for the conditions considered, there is no streamer stage of breakdown as is typical for a traditional dielectric barrier discharge.

  10. Treatment of polycarbonate by dielectric barrier discharge (DBD) at atmospheric pressure

    Science.gov (United States)

    Kostov, K. G.; Hamia, Y. A. A.; Mota, R. P.; dos Santos, A. L. R.; Nascente, P. A. P.

    2014-05-01

    Generally most plastic materials are intrinsically hydrophobic, low surface energy materials, and thus do not adhere well to other substances. Surface treatment of polymers by discharge plasmas is of great and increasing industrial application because it can uniformly modify the surface of sample without changing the material bulk properties and is environmentally friendly. The plasma processes that can be conducted under ambient pressure and temperature conditions have attracted special attention because of their easy implementation in industrial processing. Present work deals with surface modification of polycarbonate (PC) by a dielectric barrier discharge (DBD) at atmospheric pressure. The treatment was performed in a parallel plate reactor driven by a 60Hz power supply. The DBD plasmas at atmospheric pressure were generated in air and nitrogen. Material characterization was carried out by contact angle measurements, and X-ray photoelectron spectroscopy (XPS). The surface energy of the polymer surface was calculated from contact angle data by Owens-Wendt method using distilled water and diiodomethane as test liquids. The plasma-induced chemical modifications are associated with incorporation of polar oxygen and nitrogen containing groups on the polymer surface. Due to these surface modifications the DBD-treated polymers become more hydrophilic. Aging behavior of the treated samples revealed that the polymer surfaces were prone to hydrophobic recovery although they did not completely recover their original wetting properties.

  11. Discoloration of Congo Red by Rod-Plate Dielectric Barrier Discharge Processes at Atmospheric Pressure

    Science.gov (United States)

    Wu, Haixia; Fang, Zhi; Zhou, Tong; Lu, Chen; Xu, Yanhua

    2016-05-01

    A dielectric barrier discharge (DBD) reactor with a rod-plate electrode configuration was used for the oxidative decomposition of Congo red dye in an aqueous solution. Plasma was generated in the gas space above the water interface under atmospheric pressure. Discharge characteristics were analyzed by voltage-current waveforms. Effects of applied voltage, initial conductivity, and initial concentration were also analyzed. Congo red discoloration increased with increased applied voltage and decreased conductivity. The initial conductivity significantly influenced the Congo red discoloration. Under the same conditions, the highest discoloration rate was obtained at 25 mg/L. The presence of ferrous ions in the solutions had a substantial positive effect on Fenton dye degradation and flocculation. At an applied voltage of 20 kV, about 100% of dye was degraded after 4 min of Fe2+/DBD treatment. Results showed that adding a certain dosage of hydrogen peroxide to the wastewater could enhance the discoloration rate. Possible pathways of Congo red discoloration by DBD plasma were proposed based on GC/MS, FTIR, and UV-vis spectroscopy analyses. supported by National Natural Science Foundation of China (No. 51377075), the Natural Science Foundation of Jiangsu Province of China (Nos. BK20131412, BK20150951)

  12. Discoloration of Congo Red by Rod-Plate Dielectric Barrier Discharge Processes at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    WU Haixia; FANG Zhi; ZHOU Tong; LU Chen; XU Yanhua

    2016-01-01

    A dielectric barrier discharge (DBD) reactor with a rod-plate electrode configuration was used for the oxidative decomposition of Congo red dye in an aqueous solution.Plasma was generated in the gas space above the water interface under atmospheric pressure.Discharge characteristics were analyzed by voltage-current waveforms.Effects of applied voltage,initial conductivity,and initial concentration were also analyzed.Congo red discoloration increased with increased applied voltage and decreased conductivity.The initial conductivity significantly influenced the Congo red discoloration.Under the same conditions,the highest discoloration rate was obtained at 25 mg/L.The presence of ferrous ions in the solutions had a substantial positive effect on Fenton dye degradation and flocculation.At an applied voltage of 20 kV,about 100%of dye was degraded after 4 min of Fe2+/DBD treatment.Results showed that adding a certain dosage of hydrogen peroxide to the wastewater could enhance the discoloration rate.Possible pathways of Congo red discoloration by DBD plasma were proposed based on GC/MS,FTIR,and UV-vis spectroscopy analyses.

  13. Decolorization of reactive textile dyes using water falling film dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Dojcinovic, Biljana P. [Institute of Chemistry, Technology and Metallurgy, Center of Chemistry, Studentski trg 12-16, 11000 Belgrade (Serbia); Roglic, Goran M. [Faculty of Chemistry, University of Belgrade, P.O. Box 158, 11000 Belgrade (Serbia); Obradovic, Bratislav M., E-mail: obrat@ff.bg.ac.rs [Faculty of Physics, University of Belgrade, P.O. Box 368, 11000 Belgrade (Serbia); Kuraica, Milorad M. [Faculty of Physics, University of Belgrade, P.O. Box 368, 11000 Belgrade (Serbia); Kostic, Mirjana M. [Faculty of Technology and Metallurgy, Department of Textile Engineering, Karnegijeva 4, 11000 Belgrade (Serbia); Nesic, Jelena; Manojlovic, Dragan D. [Faculty of Chemistry, University of Belgrade, P.O. Box 158, 11000 Belgrade (Serbia)

    2011-08-30

    Highlights: {yields} Decolorization of four reactive textile dyes using non-thermal plasma reactor. {yields} Influence of applied energy on decolorization. {yields} Effects of initial pH and addition of homogeneous catalysts. {yields} Toxicity evaluation using the brine shrimp as a test organism. - Abstract: Decolorization of reactive textile dyes Reactive Black 5, Reactive Blue 52, Reactive Yellow 125 and Reactive Green 15 was studied using advanced oxidation processes (AOPs) in a non-thermal plasma reactor, based on coaxial water falling film dielectric barrier discharge (DBD). Used initial dye concentrations in the solution were 40.0 and 80.0 mg/L. The effects of different initial pH of dye solutions, and addition of homogeneous catalysts (H{sub 2}O{sub 2}, Fe{sup 2+} and Cu{sup 2+}) on the decolorization during subsequent recirculation of dye solution through the DBD reactor, i.e. applied energy density (45-315 kJ/L) were studied. Influence of residence time was investigated over a period of 24 h. Change of pH values and effect of pH adjustments of dye solution after each recirculation on the decolorization was also tested. It was found that the initial pH of dye solutions and pH adjustments of dye solution after each recirculation did not influence the decolorization. The most effective decolorization of 97% was obtained with addition of 10 mM H{sub 2}O{sub 2} in a system of 80.0 mg/L Reactive Black 5 with applied energy density of 45 kJ/L, after residence time of 24 h from plasma treatment. Toxicity was evaluated using the brine shrimp Artemia salina as a test organism.

  14. Effect of air flow on the micro-discharge dynamics in an array of integrated coaxial microhollow dielectric barrier discharges

    Science.gov (United States)

    Nayak, Gaurav; Du, Yanjun; Brandenburg, Ronny; Bruggeman, Peter J.

    2017-03-01

    The micro-discharge properties and evolution in a 2D array of integrated coaxial microhollow dielectric barrier discharges are studied by using highly time-resolved electrical and optical diagnostics. The study is focused on the effect of the gas flow rate and gas residence time on discharge properties. The investigated integrated coaxial microhollow discharge geometry allows operating the discharge at exceptionally small residence times, which can be equal to or even smaller than the discharge period, at reasonable gas flow rates. The gas flow has an impact on gas heating, residual humidity, pre-ionization density and the densities of excited and reactive species produced by previous discharges. A unique voltage–charge plot is obtained with elongated periods without discharge activity. A very significant effect of flow on NO emission is observed that relates to the impact of flow on the NO production in these micro-discharges. Using the emission intensities of molecular bands of the second positive system of nitrogen and the first negative system of the nitrogen ion, effective reduced electric field strengths are obtained with a maximum equal to 870 Td. The reduced electric field decreases with increasing gas flow rate. This behavior is consistent with the reduction of the overall discharge intensity due to a reduced amount of charges present in the discharge gap. Both the flow rate and a reduction in water impurity changing the ion mobility can be responsible for the different effective electric field distributions at the highest and no flow conditions.

  15. Decomposition of dimethylamine gas with dielectric barrier discharge.

    Science.gov (United States)

    Ye, Zhaolian; Zhao, Jie; Huang, Hong ying; Ma, Fei; Zhang, Renxi

    2013-09-15

    The decomposition of dimethylamine (DMA) with gas under high flow rate was investigated with dielectric barrier discharge (DBD) technology. Different parameters including removal efficiency, energy yield, carbon balance and CO2 selectivity, secondary products, as well as pathways and mechanisms of DMA degradation were studied. The experimental results showed that removal efficiency of DMA depended on applied voltage and gas flow rate, but had no obvious correlation with initial concentration. Excellent energy performance was obtained using present DBD technology for DMA abatement. When experiment conditions were controlled at: gas flow rate of 14.9 m(3)/h, initial concentration of 2104 mg/m(3), applied voltage of 4.8 kV, removal efficiency of DMA and energy yield can reach 85.2% and 953.9 g/kWh, respectively. However, carbon balance (around 40%) was not ideal due to shorter residence time (about 0.1s), implying that some additional conditions should be considered to improve the total oxidation of DMA. Moreover, secondary products in outlet gas stream were detected via gas chromatogram-mass spectrum and the amounts of NO3(-) and NO2(-) were analyzed by ion chromatogram. The obtained data demonstrated that NOx might be suppressed due to reductive NH radical form DMA dissociation. The likely reaction pathways and mechanisms for the removal of DMA were suggested based on products analysis. Experimental results demonstrated the application potential of DBD as a clean technology for organic nitrogen-containing gas elimination from gas streams. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Treatment of industrial exhaust gases by a dielectric barrier discharge

    Science.gov (United States)

    Schmidt, Michael; Hołub, Marcin; Jõgi, Indrek; Sikk, Martin

    2016-08-01

    Volatile organic compounds (VOCs) in industrial exhaust gases were treated by a dielectric barrier discharge (DBD) operated with two different mobile power supplies. Together with the plasma source various gas diagnostics were used, namely fourier transform infrared (FTIR) spectroscopy, flame ionization detector (FID) and GC-MS. The analysis revealed that some exhaust gases consist of a rather complex mixture of hydrocarbons and inorganic compounds and also vary in pollutants concentration and flow rate. Thus, analysis of removal efficiencies and byproduct concentrations is more demanding than under laboratory conditions. This contribution presents the experimental apparatus used under the harsh conditions of industrial exhaust systems as well as the mobile power source used. Selected results obtained in a shale oil processing plant, a polymer concrete production facility and a yacht hull factory are discussed. In the case of total volatile organic compounds in oil processing units, up to 60% were removed at input energy of 21-37 J/L when the concentrations were below 500 mg/m3. In the yacht hull factory up to 74% of styrene and methanol were removed at specific input energies around 300 J/L. In the polymer concrete production site 195 ppm of styrene were decomposed with the consumption of 1.8 kJ/L. These results demonstrate the feasibility of plasma assisted methods for treatment of VOCs in the investigated production processes but additional analysis is needed to improve the energy efficiency. Contribution to the topical issue "6th Central European Symposium on Plasma Chemistry (CESPC-6)", edited by Nicolas Gherardi, Ester Marotta and Cristina Paradisi

  17. Simulation of Thermal and Chemical Relaxation in a Post-Discharge Air Corona Reactor

    CERN Document Server

    Meziane, M; Ducasse, O; Yousfi, M

    2016-01-01

    In a DC point-to-plane corona discharge reactor, the mono filamentary streamers cross the inter electrode gap with a natural repetition frequency of some tens of kHz. The discharge phase (including the primary and the secondary streamers development) lasts only some hundred of nanoseconds while the post-discharge phases occurring between two successive discharge phases last some tens of microseconds. From the point of view of chemical activation, the discharge phases create radical and excited species located inside the very thin discharge filaments while during the post-discharge phases these radical and excited species induce a chemical kinetics that diffuse in a part of the reactor volume. From the point of view of hydrodynamics activation, the discharge phases induce thermal shock waves and the storage of vibrational energy which relaxes into thermal form only during the post-discharge phase. Furthermore, the glow corona discharges that persist during the post-discharge phases induce the so called electri...

  18. Removal of priority pollutants from water by means of dielectric barrier discharge atmospheric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Hijosa-Valsero, María, E-mail: mhijv@unileon.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Molina, Ricardo, E-mail: ricardo.molina@cid.csic.es [Instituto de Química Avanzada de Cataluña (IQAC), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain); Schikora, Hendrik, E-mail: hendrik.schikora@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Müller, Michael, E-mail: michael.mueller@igb.fraunhofer.de [Fraunhofer IGB, Nobelstraße 12, 70569 Stuttgart (Germany); Bayona, Josep M., E-mail: josep.bayona@cid.csic.es [Instituto de Diagnóstico Ambiental y Estudios del Agua (IDAEA), CID, CSIC, C/Jordi Girona 18-26, E-08034 Barcelona (Spain)

    2013-11-15

    Highlights: • DBD plasma reactors were used to remove pollutants from aqueous solutions. • Atrazine, chlorfenvinfos, 2,4-dibromophenol and lindane were studied. • First-order degradation kinetics were observed for all the compounds. • Degradation by-products were identified by GC–MS. • Treatment efficiencies were lower in industrial wastewater than in pure water. -- Abstract: Two different nonthermal plasma reactors at atmospheric pressure were assessed for the removal of organic micropollutants (atrazine, chlorfenvinfos, 2,4-dibromophenol, and lindane) from aqueous solutions (1–5 mg L{sup −1}) at laboratory scale. Both devices were dielectric barrier discharge (DBD) reactors; one was a conventional batch reactor (R1) and the other a coaxial thin-falling-water-film reactor (R2). A first-order degradation kinetics was proposed for both experiments. The kinetic constants (k) were slightly faster in R1 (0.534 min{sup −1} for atrazine; 0.567 min{sup −1} for chlorfenvinfos; 0.802 min{sup −1} for 2,4-dibromophenol; 0.389 min{sup −1} for lindane) than in R2 (0.104 min{sup −1} for atrazine; 0.523 min{sup −1} for chlorfenvinfos; 0.273 min{sup −1} for 2,4-dibromophenol; 0.294 min{sup −1} for lindane). However, energy efficiencies were about one order of magnitude higher in R2 (89 mg kW{sup −1} h{sup −1} for atrazine; 447 mg kW{sup −1} h{sup −1} for chlorfenvinfos; 47 mg kW{sup −1} h{sup −1} for 2,4-dibromophenol; 50 mg kW{sup −1} h{sup −1} for lindane) than in R1. Degradation by-products of all four compounds were identified in R1. As expected, when the plasma treatment (R1) was applied to industrial wastewater spiked with atrazine or lindane, micropollutant removal was also achieved, although at a lower rate than with aqueous solutions (k = 0.117 min{sup −1} for atrazine; k = 0.061 min{sup −1} for lindane)

  19. Research progress in the study of atmospheric pressure glow barrier discharge

    Institute of Scientific and Technical Information of China (English)

    LI Xuechen; DONG Lifang; JIA Pengying

    2007-01-01

    Atmospheric pressure glow barrier discharge (APGBD) can operate at high pressure, and so vacuum device is not necessary. Furthermore, the produced plasma by APGBD has moderate electron temperature and density besides good uniformity. Therefore,APGBD has extensive potential applications in industry and has been becoming a hot issue in the research of low temperature plasma. In this paper, the main problems in the study of atmospheric pressure glow discharge generated by dielectric barrier discharge, including the experimental setup, judging criterion, discharging conditions, physical mechanisms, and parameter diagnoses, are discussed, and further research prospects of APGBD are proposed.

  20. Spent nuclear fuel discharges from US reactors 1992

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-05

    This report provides current statistical data on every fuel assembly irradiated in commercial nuclear reactors operating in the United States. It also provides data on the current inventories and storage capacities of those reactors to a wide audience, including Congress, Federal and State agencies, the nuclear and electric industries and the general public. It uses data from the mandatory, ``Nuclear Fuel Data`` survey, Form RW-859 for 1992 and historical data collected by the Energy Information Administration (EIA) on previous Form RW-859 surveys. The report was prepared by the EIA under a Memorandum of Understanding with the Office of Civilian Radioactive Waste Management.

  1. Evaluation of Novel Integrated Dielectric Barrier Discharge Plasma as Ozone Generator

    Directory of Open Access Journals (Sweden)

    Muhammad Nur

    2017-04-01

    Full Text Available This paper presents a characterization of an integrated ozone generator constructed by seven of reactors of Dielectric Barrier Discharge Plasma (DBDP. DBDP a has spiral-cylindrical configuration. Silence plasma produced ozone inside the DBDP reactor was generated by AC-HV with voltage up to 25 kV and maximum frequency of 23 kHz. As a source of ozone, dry air was pumped into the generator and controlled by valves system and a flowmeter. We found ozone concentration increased with the applied voltage, but in contrary, the concentration decreased with the flow rate of dry air. It was also found that a maximum concentration was 20 mg/L and ozone capacity of 48 g/h with an input power of 1.4 kW. Moreover, in this generator, IP efficiency of 8.13 g/kWh was obtained at input power 0.45 kW and air flow rate of 9 L/min. Therefore, be the higher ozone capacity can be produced with higher input power; however, it provided lower IP efficiency. The effect of dry air flow rate and applied voltage on ozone concentrations have been studied. At last, spiral wire copper was very corrosive done to the interaction with ozone, and it is necessary to do a research for finding the best metals as an active electrode inside of the quartz dielectric. Copyright © 2017 BCREC GROUP. All rights reserved Received: 18th July 2016; Revised: 25th September 2016; Accepted: 5th October 2016 How to Cite: Nur, M., Susan, A.I., Muhlisin, Z., Arianto, F., Kinandana, A.W., Nurhasanah, I., Sumariyah, S., Wibawa, P.J., Gunawan, G., Usman, A. (2017. Evaluation of Novel Integrated Dielectric Barrier Discharge Plasma as Ozone Generator. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (1: 24-31 (doi:10.9767/bcrec.12.1.605.24-31 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.1.605.24-31

  2. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Traditional approaches for active flow separation control using dielectric barrier discharge (DBD) plasma actuators are limited to relatively low-speed flows and...

  3. Conversion of Methane by Dielectric-barrier Discharge Plasma Method-Comparison with Microwave Plasma Method

    National Research Council Canada - National Science Library

    Konno, Katsuya; Kobayashi, Motoki; Onoe, Kaoru; Yamaguchi, Tatsuaki

    2010-01-01

      Methane conversion by the dielectric-barrier discharge plasma method (DBD) was compared with our previous findings for the microwave plasma method (MW). The power (Pw), initial pressure (P0) and flow rate (F0...

  4. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Traditional approaches for active flow separation control using dielectric barrier discharge (DBD) plasma actuators are limited to relatively low-speed flows and...

  5. Routes to increase the conversion and the energy efficiency in the splitting of CO2 by a dielectric barrier discharge

    Science.gov (United States)

    Ozkan, A.; Bogaerts, A.; Reniers, F.

    2017-03-01

    Here, we present routes to increase CO2 conversion into CO using an atmospheric pressure dielectric-barrier discharge. The change in conversion as a function of simple plasma parameters, such as power, flow rate, but also frequency, on-and-off power pulse, thickness and the chemical nature of the dielectric, wall and gas temperature, are described. By means of an in-depth electrical characterization of the discharge (effective plasma voltage, dielectric voltage, plasma current, number and lifetime of the microdischarges), combined with infrared analysis of the walls of the reactor, optical emission spectroscopy for the gas temperature, and mass spectrometry for the CO2 conversion, we propose a global interpretation of the effect of all the experimental parameters on the conversion and efficiency of the reaction.

  6. A gapless micro-dielectric-barrier-discharge ion source for analytical applications

    CERN Document Server

    Coy, Stephen L; Eiceman, Gary A; Kanik, Isik

    2016-01-01

    Use of dielectric barrier discharge (DBD) as an ion source for sensitive chemical analysis is uncommon because barrier discharges generate excess noise due to spatial and temporal instability. This design uses contacted, crossed glass-coated micro-wires to focus the field into a gradually vanishing gap, suppressing spatial and temporal variability, reducing pressure, temperature, and humidity effects, stabilizing discharge initiation and limiting chemical fragmentation. Positive-ion-mode proton transfer, chemical fragmentation from a micro-discharge, and NO+ adducts combine to allow broad chemical sensitivity. We analyze noise properties of the ion source and report chemical responsivity for a wide range of volatile organic compounds. Source noise spectral density is compared for three systems: the contacted coated wires source, a gapped dielectric barrier discharge source, and a 5 mCi Ni-63 radioactive source. The crossed-wires source shows noise properties approaching those of the white-noise Ni-63 source, ...

  7. Experimental Determination of Spatial and Temporal Discharge Parameters for an Ambient Pressure Dielectric Barrier Discharge in Helium

    Science.gov (United States)

    Bures, Brian; Bourham, Mohamed

    2004-11-01

    Ambient pressure Dielectric Barrier Discharges (DBD's) are studied for a number of applications. Barrier discharges composed primarily of inert gases are potentially useful for the production of intense excimer light, sterilization of thermally sensitive materials and control of insects for quarantine. The neutral bremsstrahlung technique is used to determine spatial variations of electron density and electron temperature in a parallel plate, helium (99.9% by vol) dielectric barrier discharge operated at an average power density between 50 and 75 mW/cm^3. The applied frequency is varied between 2 kHz and 6 kHz. The time average electron density suggests a more intense discharge near the surface of the electrodes than the bulk of the discharge for all frequencies and power densities. When moving parallel to the electrodes, the electron temperature remains constant, while the electron density is constant within 20% of the average value. A monochromator tuned to a nitrogen ion line (391.4 nm) and a helium line (706.5 nm) has a more intense emission when the electrode is negatively biased.

  8. Electrical and mechanical characteristics of nanosecond pulsed sliding dielectric barrier discharges with different electrode gaps

    Science.gov (United States)

    Bayoda, K. D.; Benard, N.; Moreau, E.

    2015-10-01

    This study proposes the characterization of a surface sliding discharge that extends over a length of 80 mm. The gas ionization is caused by series of high voltage pulses with nanosecond rising and decaying times while ion drift is forced by a negative DC component. Different plasma diagnostics such as electrical measurements, iCCD visualizations and strioscopy have been performed. They highlight that a threshold mean electric field between both air-exposed electrodes is required to fully establish a sliding discharge. Compared to a single nanosecond pulsed dielectric barrier discharge, the sliding discharge results in an energy consumption increase. Moreover, the pressure wave induced by the discharge is strongly impacted.

  9. Investigation of Ozone Yield of Air Fed Ozonizer by High Pressure Homogeneous Dielectric Barrier Discharge

    Science.gov (United States)

    2013-07-01

    field strength in the discharge. In order to clarify this phenomenon, further study on the gas analysis within the ozone gas by an FTIR spectrometer...31st ICPIG, July 14-19, 2013, Granada, Spain Investigation of ozone yield of air fed ozonizer by high pressure homogeneous dielectric barrier... ozonizer and found that the ozone yield is higher by the homogeneous discharge mode than by the conventional filamentary discharge mode in larger

  10. Modeling of asymmetric pulsed phenomena in dielectric-barrier atmospheric-pressure glow discharges

    Energy Technology Data Exchange (ETDEWEB)

    Ha Yan [College of Mathematics and Computer Science, Hebei University, Baoding 071002 (China); Wang Huijuan [School of Mathematics and Physics, North China Electric Power University, Baoding 071003 (China); Wang Xiaofei [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2012-01-15

    Asymmetric current pulses in dielectric-barrier atmospheric-pressure glow discharges are investigated by a self-consistent, one-dimensional fluid model. It is found that the glow mode and Townsend mode can coexist in the asymmetric discharge even though the gas gap is rather large. The reason for this phenomenon is that the residual space charge plays the role of anode and reduces the gap width, resulting in the formation of a Townsend discharge.

  11. Characterization of a Dielectric Barrier Plasma Gun Discharging at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    ZHANG Guang-Qiu; GE Yuan-Jing; ZHANG Yue-Fei; CHEN Guang-Liang

    2004-01-01

    @@ We develop a plasma gun based on dielectric barrier discharge and working at atmospheric pressure. A theoretical model to predict the gun discharge voltage is built, which is in agreement with the experimental results. After investigating the characterization of discharging gun and utilizing it for polymerization, we find that the gun can be used as a source to generate a stable uniform plasma for different plasma-processing technologies.

  12. Energy deposition characteristics of nanosecond dielectric barrier discharge plasma actuators: Influence of dielectric material

    NARCIS (Netherlands)

    Correale, G.; Winkel, R.; Kotsonis, M.

    2015-01-01

    An experimental study aimed at the characterization of energy deposition of nanosecond Dielectric Barrier Discharge (ns-DBD) plasma actuators was carried out. Special attention was given on the effect of the thickness and material used for dielectric barrier. The selected materials for this study we

  13. Removal of caffeine from water by combining dielectric barrier discharge (DBD plasma with goethite

    Directory of Open Access Journals (Sweden)

    Jian Wang

    2017-07-01

    Full Text Available In this research, dielectric barrier discharge plasma was developed to cooperate with goethite for removing caffeine in aqueous solution. Goethite was characterized by X-ray diffraction and scanning electron microscopy. The effects of input power, initial concentration and catalysts concentration on the removal efficiency of caffeine were evaluated. Furthermore, the degradation pathways of caffeine were also discussed preliminarily. In the case of caffeine concentration at 50 mg L−1, the degradation efficiency of caffeine was improved from 41% to 94% after 24 min on the conditions of input power of 75 W by combining goethite catalysts (2.5 g L−1, while the energy efficiency could be enhanced 1.6–2.3 times compared to the single DBD reactor. The reaction mechanism experiments demonstrated that attack by hydroxyl radical and ozone was the main degradation process of caffeine in aqueous solution. These studies also provided a theoretical and practical basis for the application of DBD-goethite in treatment of caffeine from water.

  14. CO and byproduct formation during CO₂ reduction in dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Brehmer, F. [Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); AFS GmbH, Von-Holzapfel-Straße 10, 86497 Horgau (Germany); Welzel, S.; Sanden, M. C. M. van de [Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Dutch Institute for Fundamental Energy Research, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Engeln, R. [Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2014-09-28

    The dissociation of CO₂ and the formation of CO, O₃, and O² were studied in a dielectric barrier discharge (DBD) at atmospheric pressure by means of ex-situ infrared absorption spectroscopy. CO mixing ratios of 0.1%–4.4% were determined for specific injected energies between 0.1 and 20 eV per molecule (0.3–70 kJ/l). A lower limit of the gas temperature of 320–480 K was estimated from the wall temperature of the quartz reactor as measured with an infrared camera. The formation of CO in the DBD could be described as function of the total number of transferred charges during the residence time of the gas in the active plasma zone. An almost stoichiometric CO:O₂ ratio of 2:1 was observed along with a strongly temperature dependent O₃ production up to 0.075%. Although the ideal range for an efficient CO₂ dissociation in plasmas of 1 eV per molecule for the specific injected energy was covered, the energy efficiency remained below 5% for all conditions. The present results indicate a reaction mechanism which is initiated by electron impact processes followed by charge transfer reactions and non-negligible surface enhanced O and CO recombination. While electron-driven CO₂ dissociation is relatively energy inefficient by itself, fast O recombination and the low gas temperatures inhibit the synergistic reuse of atomic oxygen in a secondary CO₂ + O dissociation step.

  15. Degradation of triclosan in aqueous solution by dielectric barrier discharge plasma combined with activated carbon fibers.

    Science.gov (United States)

    Xin, Lu; Sun, Yabing; Feng, Jingwei; Wang, Jian; He, Dong

    2016-02-01

    The degradation of triclosan (TCS) in aqueous solution by dielectric barrier discharge (DBD) plasma with activated carbon fibers (ACFs) was investigated. In this study, ACFs and DBD plasma coexisted in a planar DBD plasma reactor, which could synchronously achieve degradation of TCS, modification and in situ regeneration of ACFs, enhancing the effect of recycling of ACFs. The properties of ACFs before and after modification by DBD plasma were characterized by BET and XPS. Various processing parameters affecting the synergetic degradation of TCS were also investigated. The results exhibited excellent synergetic effects in DBD plasma-ACFs system on TCS degradation. The degradation efficiency of 120 mL TCS with initial concentration of 10 mg L(-1) could reach 93% with 1 mm thick ACFs in 18 min at input power of 80 W, compared with 85% by single DBD plasma. Meanwhile, the removal rate of total organic carbon increased from 12% at pH 6.26-24% at pH 3.50. ACFs could ameliorate the degradation efficiency for planar DBD plasma when treating TCS solution at high flow rates or at low initial concentrations. A possible degradation pathway of TCS was investigated according to the detected intermediates, which were identified by liquid chromatography-hybrid quadrupole time-of-flight mass spectrometry (LC-QTOF-MS) combined with theoretical calculation of Gaussian 09 program.

  16. Simulation of polyatomic discharges for thin film deposition processes in low-pressure plasma reactors

    Science.gov (United States)

    Bera, Kallol

    Comprehensive multi-dimensional self-consistent numerical fluid models for radio-frequency capacitively and inductively coupled methane discharges were developed to predict diamond-like-carbon thin film deposition/etching rate on the wafer. A numerical model of glow discharge provides insight on the physical phenomena in the discharge leading to better understanding and design of the reactor. The developed discharge models included detailed discharge physics, gas-phase chemistry and surface chemistry modeling. To understand the basic discharge phenomena, one- dimensional radio frequency capacitively coupled Ar plasma was simulated using a fluid model. The model was modified for methane plasma to predict the profiles of the plasma variables. The model was then extended to two- dimensional cylindrical coordinates to capture the effects of asymmetry of the reactor on the plasma variables. The necessary dc bias for the discharge was predicted such that the cycle-averaged current to the powered electrode was zero. A discharge chemistry model was also developed to predict various radical and neutral densities in the plasma, and their fluxes to the cathode. The species fluxes are used to predict film deposition rate and the properties of the deposited film. The model predictions of plasma density, self-generated de bias, cathode current and plasma potential compared well with the experimental results. A high density plasma with inductive coupling at low pressure was also considered. Separate rf bias and dc bias are applied to the substrate holder to modulate the ion energy. The present model simulates electron, ion and neutral transport, including detailed discharge and surface chemistry. The model has been implemented for methane discharge to obtain deposition/etching of thin carbon film on the wafer. To the author's knowledge, this is the first attempt to simulate capacitively and inductively coupled plasmas self-consistently for a depositing gas under the operating

  17. Investigation of planar barrier discharges for coherent nonlinear structures

    Science.gov (United States)

    Uzun-Kaymak, I. U.

    2017-02-01

    Nonlinear pattern formations are ubiquitous in nature. One of the analogous configurations in laboratory experiments to such nonlinear systems is the current filament formations observed in glow plasmas. These filaments can generate oscillatory fluctuations in glow, which are also observed in voltage and current measurements. Specifically, semiconductor-gas discharges are known to breed these types of current filaments naturally. The plasma discharge is initiated by applying a DC high voltage to electrodes while they are immersed in nitrogen gas at partial atmospheric pressure. Observed discharge behaves oscillatory in time. Harmonic frequency generation and coherency levels among these modes are investigated. Parametric scans are performed to study the transition to chaotic behavior. Observed results are discussed in detail.

  18. Dielectric barrier discharges with steep voltage rise: mapping of atomic nitrogen in single filaments measured by laser-induced fluorescence spectroscopy

    Science.gov (United States)

    Lukas, C.; Spaan, M.; Schulz-von der Gathen, V.; Thomson, M.; Wegst, R.; Döbele, H. F.; Neiger, M.

    2001-08-01

    Space and time resolved relative atomic density distributions of nitrogen have been measured for the first time at a single filament within a dielectric barrier discharge (DBD) reactor with submillimetre radial dimensions. Two-photon-Absorption Laser-Induced Fluorescence (TALIF) spectroscopy of atomic nitrogen using radiation at λ = 206.7 nm is applied to a DBD with fast rising voltage amplitudes. The decay time of the atomic nitrogen density depends strongly on the position within the discharge and the distance from the dielectric where the lifetime is maximum. Admixed oxygen leads to an increase of the N density decay by an order of magnitude even at small fractions.

  19. Plasma-chemical reactor based on a low-pressure pulsed arc discharge for synthesis of nanopowders

    Science.gov (United States)

    Karpov, I. V.; Ushakov, A. V.; Lepeshev, A. A.; Fedorov, L. Yu.

    2017-01-01

    A reactor for producing nanopowders in the plasma of a low-pressure arc discharge has been developed. As a plasma source, a pulsed cold-cathode arc evaporator has been applied. The design and operating principle of the reactor have been described. Experimental data on how the movement of a gaseous mixture in the reactor influences the properties of nanopowders have been presented.

  20. Formation of white-eye pattern with microdischarge in an air dielectric barrier discharge system

    CERN Document Server

    He, Yafeng; Liu, Weili; Wang, Hongfang; Zhao, Zengchao; Fan, Weili

    2011-01-01

    We report on the first observation of white-eye pattern in an air dielectric barrier discharge. The patterned discharges undergo a development as following: random spots - quasihexagonal pattern - hexagonal pattern (type I) - hexagonal pattern (type II) - white-eye pattern - chaos as the voltage is increased. The spatiotemporal characteristics of patterned discharges are investigated by using an optical method. Results show that the two discharge modes, uniform mode and filamentary mode, are actually two different spatial presentations of the same origin: the microdischarge. From the viewpoint of pattern dynamics, the white-eye pattern results from a 3-wave resonance interaction.

  1. DeNOx Study in Diesel Engine Exhaust Using Barrier Discharge Corona Assisted by V2O5/TiO2 Catalyst

    Institute of Scientific and Technical Information of China (English)

    B. S. Rajanikanth; V. Ravi

    2004-01-01

    A plasma-assisted catalytic reactor was used to remove nitrogen oxides (Nox) from diesel engine exhaust operated under different load conditions. Initial studies were focused on plasma reactor (a dielectric barrier discharge reactor) treatment of diesel exhaust at various temperatures. The nitric oxide (NO) removal efficiency was lowered when high temperature exhaust was treated using plasma reactor. Also, NO removal efficiency decreased when 45% load exhaust was treated. Studies were then made with plasma reactor combined with a catalytic reactor consisting of a selective catalytic reduction (SCR) catalyst, V2O5/TiO2. Ammonia was used as a reducing agent for SCR process in a ratio of 1:1 to Nox. The studies were focused on temperatures of the SCR catalytic reactor below 200 ℃. The plasma-assisted catalytic reactor was operated well to remove Nox under no-load and load conditions. For an energy input of 96 J/l, the Nox removal efficiencies obtained under no-load and load conditions were 90% and 72% respectively at an exhaust temperature of 100 ℃.

  2. A Fixed Bed Barrier Reactor with Separate Feed of Reactants

    NARCIS (Netherlands)

    Neomagus, H.W.J.P.; Saracco, G.; Versteeg, G.F.

    2001-01-01

    A new type of gas-solid reactor was developed and characterised in the series of reactor configurations with separate feed of reactants studied by our group. The novelty in the proposed design lies in the use of a fixed bed of small catalytic particles instead of a porous catalytic membrane. The maj

  3. A Fixed Bed Barrier Reactor with Separate Feed of Reactants

    NARCIS (Netherlands)

    Neomagus, H.W.J.P.; Saracco, G.; Versteeg, G.F.

    2001-01-01

    A new type of gas-solid reactor was developed and characterised in the series of reactor configurations with separate feed of reactants studied by our group. The novelty in the proposed design lies in the use of a fixed bed of small catalytic particles instead of a porous catalytic membrane. The maj

  4. Energy deposition characteristics of nanosecond dielectric barrier discharge plasma actuators: Influence of dielectric material

    Science.gov (United States)

    Correale, G.; Winkel, R.; Kotsonis, M.

    2015-08-01

    An experimental study aimed at the characterization of energy deposition of nanosecond Dielectric Barrier Discharge (ns-DBD) plasma actuators was carried out. Special attention was given on the effect of the thickness and material used for dielectric barrier. The selected materials for this study were polyimide film (Kapton), polyamide based nylon (PA2200), and silicone rubber. Schlieren measurements were carried out in quiescent air conditions in order to observe density gradients induced by energy deposited. Size of heated area was used to qualify the energy deposition coupled with electrical power measurements performed using the back-current shunt technique. Additionally, light intensity measurements showed a different nature of discharge based upon the material used for barrier, for a fixed thickness and frequency of discharge. Finally, a characterisation study was performed for the three tested materials. Dielectric constant, volume resistivity, and thermal conductivity were measured. Strong trends between the control parameters and the energy deposited into the fluid during the discharge were observed. Results indicate that efficiency of energy deposition mechanism relative to the thickness of the barrier strongly depends upon the material used for the dielectric barrier itself. In general, a high dielectric strength and a low volumetric resistivity are preferred for a barrier, together with a high heat capacitance and a low thermal conductivity coefficient in order to maximize the efficiency of the thermal energy deposition induced by an ns-DBD plasma actuator.

  5. Preliminary Investigation of a Dielectric Barrier Discharge Lamp in Open Air at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    LIU Feng; WANG Wei-Wei; CHANG Xi-Jiang; LIANG Rong-Qing

    2011-01-01

    @@ A dielectric barrier discharge (DBD) lamp is investigated by using sinusoidal power with a 10 kHz frequency in open air at atmospheric pressure.With increasing applied voltages, the different discharge phenomena appear.At relatively low voltages, the discharge states are general stochastic filamentary discharges with weak light.However, at relatively high voltages, the walls of quartz tubes are heated sharply by plasma, and then the dazzling light is emitted very quickly to form the DBD Lamp, corresponding to the low maintaining voltage that is lower than the ignited voltage.The discharge state or mode of the DBD lamp that corresponds to the glow discharge is deduced according to the wave form of the circuit current, which is evidently different from the filamentary discharges.Under these conditions, the spectrum of the DBD lamp is continuous in the range 400-932nm, which is scanned in the range 300-932nm.It is also shown that there is another discharge state or mode that is different from the traditional filamentary discharges.Therefore, it is concluded that the discharge state or mode of the DBD lamp is a glow discharge.

  6. Concentric-ring structures in an atmospheric pressure helium dielectric barrier discharge

    Institute of Scientific and Technical Information of China (English)

    Shang Wan-Li; Zhang Yuan-Tao; Wang De-Zhen; Sang Chao-Feng; Jiang shao-En; Yang Jia-Min; Liu shen-Ye; M.G.Kong

    2011-01-01

    This paper performs a numerical simulation of concentric-ring discharge structures within the scope of a two-dimensional diffusion-drift model at atmospheric pressure between two parallel circular electrodes covered with thin dielectric layers. With a relative high frequency the discharge structures present different appearances of ring structures within different radii in time due to the evolvement of the filaments. The spontaneous electron density distributions help understanding the formation and development of seff-organized discharge structures. During a cycle the electron avalanches are triggered by the electric field strengthened by the feeding voltage and the residual charged particles on the barrier surface deposited in the previous discharges. The accumulation of charges is shown to play a dominant role in the generation and annihilation of the discharge structures. Besides, the rings split and unify to bring and annihilate rings which form a new discharge structure.

  7. Treatment surfaces with atomic oxygen excited in dielectric barrier discharge plasma of O2 admixed to N2

    Directory of Open Access Journals (Sweden)

    E. V. Shun'ko

    2012-06-01

    Full Text Available This paper describes the increase in surface energy of substrates by their treatment with gas composition generated in plasmas of DBD (Dielectric Barrier Discharge in O2 admixed with N2. Operating gas dissociation and excitation was occurred in plasmas developed in two types of reactors of capacitively-coupled dielectric barrier configurations: coaxial cylindrical, and flat rectangular. The coaxial cylindrical type comprised an inner cylindrical electrode encapsulated in a ceramic sheath installed coaxially inside a cylindrical ceramic (quartz tube passing through an annular outer electrode. Components of the flat rectangular type were a flat ceramic tube of a narrow rectangular cross section supplied with two flat electrodes mounted against one another outside of the long parallel walls of this tube. The operating gas, mixture of N2 and O2, was flowing in a completely insulated discharge gap formed between insulated electrodes of the devices with an average velocity of gas inlet of about 7 to 9 m/s. Dielectric barrier discharge plasma was excited in the operating gaps with a bipolar pulse voltage of about 6 kV for 2 ms at 50 kHz repetition rate applied to the electrodes of the coaxial device, and of about 14 kV for 7 ms at 30 kHz repetition rate for the flat linear device. A lifetime of excited to the 2s22p4(1S0 state in DBD plasma and streaming to the surfaces with a gas flow atomic oxygen, responsible presumably for treating surfaces, exceeded 10 ms in certain cases, that simplified its separation from DBD plasma and delivery to substrates. As it was found in particular, surfaces of glass and some of polymers revealed significant enhancement in wettability after treatment.

  8. Calculation of Onset Voltage of Sliding Discharge over a Dielectric Barrier

    Directory of Open Access Journals (Sweden)

    Abdel-Salam Mazen

    2016-01-01

    Full Text Available This paper is aimed at calculating the onset voltage of a sliding discharge established between two electrodes at the upper and bottom surfaces of a dielectric barrier plate; named sliding dielectric barrier discharge (SDBD driven by AC voltage during negative half cycle. The onset voltage is based on the condition of self-sustenance of avalanche growth in the vicinity of the stressed electrode. This calls at first for calculation of the electric field in the vicinity of stressed electrode. The dependency of onset voltage on the thickness and permittivity of the dielectric barrier as well as the thickness of the stressed electrode and the inter-electrode spacing between the stressed and ground electrodes is investigated. The obtained results are discussed in the light of gas discharge physics.

  9. Decomposition of toluene in a gliding arc discharge plasma reactor

    Energy Technology Data Exchange (ETDEWEB)

    Du Changming [School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510275 (China); Yan Jianhua [Institute for Thermal Power Engineering, Zhejiang University, Hangzhou 310027 (China); Cheron, Bruno [UMR 6614 (CORIA), University of Rouen, 76821 Mont Saint Aignan (France)

    2007-11-15

    The decomposition of toluene in a gliding arc discharge (glidarc) was performed and studied. Experimental results indicate that the glidarc technology can effectively decompose toluene molecules and has bright prospects of being applied as an alternative tool to decompose volatile organic compounds. It is found that a change in the electrode material had an insignificant effect on the toluene removal efficiency. The toluene removal efficiency increases with increasing inlet gas temperature. The water vapor present in the gas mixture has a favorable effect on the toluene decomposition in the plasma. The energy efficiency is 29.46 g (kWh{sup -1}) at a relative humidity of 50% and a specific energy input of 0.26 kWh m{sup -3}, which is higher than other types of non-thermal plasmas. Too much or too little oxygen content does not favor toluene decomposition. The major gas phase products detected by FT-IR from the decomposition of toluene with air participation were CO, CO{sub 2}, H{sub 2}O and NO{sub 2}. Some brown depositions were found on the surface of the electrodes, which were polar oxygenous and nitrogenous compounds determined by the GC-MS analysis, such as benzaldehyde, benzoic acid, quinine and nitrophenol from the reaction of toluene with radicals. A possible mechanism for toluene destruction via glidarc technology is proposed and summarized.

  10. Study on the Microsecond Pulse Homogeneous Dielectric Barrier Discharges in Atmospheric Air and Its Influencing Factors%Study on the Microsecond Pulse Homogeneous Dielectric Barrier Discharges in Atmospheric Air and Its Influencing Factors

    Institute of Scientific and Technical Information of China (English)

    方志; 雷枭; 蔡玲玲; 邱毓昌; Edmund KUFFEL

    2011-01-01

    The homogeneous dielectric barrier discharge (DBD) in atmospheric air between two symmetric-columnar copper electrodes with epoxy plates as the dielectric barriers is generated using a us pulse high voltage power supply. The discharge characteristics are studied by measurement of its electrical discharge parameters and observation of its light emission phenom- ena, and the main discharge parameters of the homogenous DBD, such as discharge current and average discharge power, are calculated. Results show that the discharge generated is a homogeneous one with one larger single current pulse of about 2 #s duration appearing in each voltage pulse, and its light emission is radially homogeneous and covers the entire surface of the two elec- trodes. The influences of applied voltage amplitude, air gap distance and barrier thickness on the transition of discharge modes are studied. With the increase of air gap distance, the discharge will transit from homogeneous mode to filamentary mode. The higher the thickness of dielectric barriers, the larger the air gap distance for generating the homogeneous discharge mode. The average discharge power increases non-linearly with increasing applied voltage amplitude, and decreases non-linearly with the increase of air gap distance and barrier thickness. In order to generate stable and homogeneous DBD with high discharge power, thin barriers distance should be used, and higher applied voltage amplitude should be applied to small air gap.

  11. Generation of uniform atmospheric pressure argon glow plasma by dielectric barrier discharge

    Indian Academy of Sciences (India)

    Raju Bhai Tyata; Deepak Prasad Subedi; Rajendra Shrestha; Chiow San Wong

    2013-03-01

    In this paper, atmospheric pressure glow discharges (APGD) in argon generated in parallel plate dielectric barrier discharge system is investigated by means of electrical and optical measurements. Using a high voltage (0–20 kV) power supply operating at 10–30 kHz, homogeneous and steady APGD has been observed between the electrodes with gap spacing from 0.5 mm to 2 mm and with a dielectric barrier of thickness 2 mm while argon gas is fed at a controlled flow rate of 11/min. The electron temperature and electron density of the plasma are determined by means of optical emission spectroscopy. Our results show that the electron density of the discharge obtained is of the order of 1016 cm-3 while the electron temperature is estimated to be 0.65 eV. The important result is that electron density determined from the line intensity ratio method and stark broadening method are in very good agreement. The Lissajous figure is used to estimate the energy deposited to the glow discharge. It is found that the energy deposited to the discharge is in the range of 20 to 25 $\\$J with a discharge voltage of 1.85 kV. The energy deposited to the discharge is observed to be higher at smaller gas spacing. The glow discharge plasma is tested to be effective in reducing the hydrophobicity of polyethylene film significantly.

  12. Computational Modeling of the Dielectric Barrier Discharge (DBD) Device for Aeronautical Applications

    Science.gov (United States)

    2006-06-01

    Dielectric Barrier Discharge The Dielectric Barrier Discharge (DBD) device has been put to use since 1857 when Werner von Siemens used to produce...x y s t s t x y x ys t s t s t s t x y x y x yn S L t nx + − − Γ − Γ = − − Δ + Δ (18) and 1 1 2 2 , , , , ,, , , , , 1 , 1...driven flux and the thermal flux were oppositely directed. ( ), , , , 1s t s t s t s tadjacent Scharfetter Gummel thermal adjacenttn S L nx − − Δ = Γ

  13. Micronucleus formation induced by dielectric barrier discharge plasma exposure in brain cancer cells

    Science.gov (United States)

    Kaushik, Nagendra K.; Uhm, Hansup; Ha Choi, Eun

    2012-02-01

    Induction of micronucleus formation (cytogenetic damage) in brain cancer cells upon exposure of dielectric barrier discharge plasma has been investigated. We have investigated the influence of exposure and incubation times on T98G brain cancer cells by using growth kinetic, clonogenic, and micronucleus formation assay. We found that micronucleus formation rate directly depends on the plasma exposure time. It is also shown that colony formation capacity of cells has been inhibited by the treatment of plasma at all doses. Cell death and micronucleus formation are shown to be significantly elevated by 120 and 240 s exposure of dielectric barrier discharge plasma.

  14. Optical characteristics of the filamentary and diffuse modes in surface dielectric barrier discharge

    Science.gov (United States)

    Zhang, Ying; Li, Jie; Jiang, Nan; Shang, Ke-Feng; Lu, Na; Wu, Yan

    2016-11-01

    Surface dielectric barrier discharge (DBD) plasmas generally exhibits filamentary and diffuse discharges at atmospheric air. The focus of this investigation is on the different optical characteristics and quantitative research about morphological features of two discharge modes. The temporally and spatially resolved characteristics of discharge phenomenon together with the gas temperature are presented with microsecond time scale. Discharge area is estimated by the sum of pixels that equal to "1" in MATLAB software. The formation of diffuse plasma mainly depends on an increase of the ionization coefficient and a creation of sufficient seed electrons by the Penning effect at low electric fields. Accordingly, experimental measurements show that diffuse discharge during the negative half cycle has good uniformity and stability compared with filamentary discharge during the positive half cycle. The rotational temperatures of plasma are determined by comparing the experimental spectra with the simulated spectra that have been investigated. The plasma gas temperature keeps almost constant in the filamentary discharge phase and subsequently increased by about 115 K during the diffuse discharge. In addition, it is shown to be nearly identical in the axial direction. Non-uniform temperature distribution can be observed in the radial direction with large fluctuations. The plasma length is demonstrated almost the same between two discharge modes.

  15. Dielectric barrier discharges used for the conversion of greenhouse gases: modeling the plasma chemistry by fluid simulations

    Energy Technology Data Exchange (ETDEWEB)

    De Bie, Christophe; Martens, Tom; Bogaerts, Annemie [Research Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Wilrijk (Belgium); Van Dijk, Jan [Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven (Netherlands); Paulussen, Sabine; Verheyde, Bert [Flemish Institute for Technological Research (VITO), Boeretang 200, 2400 Mol (Belgium); Corthals, Steven, E-mail: annemie.bogaerts@ua.ac.b [Centre for Surface Chemistry and Catalysis, K. U. Leuven, Kasteelpark Arenberg 23, 3001 Heverlee (Belgium)

    2011-04-15

    The conversion of methane to value-added chemicals and fuels is considered to be one of the challenges of the 21st century. In this paper we study, by means of fluid modeling, the conversion of methane to higher hydrocarbons or oxygenates by partial oxidation with CO{sub 2} or O{sub 2} in a dielectric barrier discharge. Sixty-nine different plasma species (electrons, ions, molecules, radicals) are included in the model, as well as a comprehensive set of chemical reactions. The calculation results presented in this paper include the conversion of the reactants and the yields of the reaction products as a function of residence time in the reactor, for different gas mixing ratios. Syngas (i.e. H{sub 2} + CO) and higher hydrocarbons (C{sub 2}H{sub x}) are typically found to be important reaction products.

  16. Computational Model of One-Dimensional Dielectric Barrier Discharges

    Science.gov (United States)

    2005-06-01

    Siemens proposed a special electrical discharge to produce ozone (6:309). In 1955, Tanaka discovered that the DBD could be used for excimer...un t x t n nx t x tnn unn nu t n n n un u t nx t nx t x t n nx t x tunneNE ν δδϕ ϕ δ ν δ ν δϕ ϕϕ δδϕ ϕ ϕ . (91) This process is repeated for the...or blocks, consisting of the coefficients of the δ terms, nx is a four-term sub-vector of the unknown δ ’s and nb is a four-term sub- vector

  17. Dynamic Characteristics of Positive Pulsed Dielectric Barrier Discharge for Ozone Generation in Air

    Science.gov (United States)

    Wei, Linsheng; Peng, Bangfa; Li, Ming; Zhang, Yafang; Hu, Zhaoji

    2016-02-01

    A comprehensive dynamic model consisting of 66 reactions and 24 species is developed to investigate the dynamic characteristics of ozone generation by positive pulsed dielectric barrier discharge (DBD) using parallel-plate reactor in air. The electron energy conservation equation is coupled to the electron continuity equation, the heavy species continuity equation, and Poisson's equation for a better description. The reliability of the model is experimentally confirmed. The model can be used to predict the temporal and spatial evolution of species, as well as streamer propagation. The simulation results show that electron density increases nearly exponentially in the direction to the anode at the electron avalanche. Streamer propagation velocity is about 5.26 × 104 m/s from anode to cathode in the simulated condition. The primary positive ion, negative ion, and excited species are O2+, O3- and O2(1Δg) in pulsed DBD in air, respectively. N2O has the largest density among nitrogen oxides. e and N2+ densities in the streamer head increase gradually to maximum values with the development of the streamer. Meanwhile, the O2+, O, O3, N2(A3Σ) and N2O densities reach maximum values in the vicinity of the anode. supported by National Natural Science Foundation of China (Nos. 51366012 and 11105067), Jiangxi Province Young Scientists (Jinggang Star) Cultivation Plan of China (No. 20133BCB23008), Natural Science Foundation of Jiangxi, China (No. 20151BAB206047) and Jiangxi Province Higher School Science and Technology Landing Plan of China (No. KJLD-14015)

  18. UNJUK KERJA REAKTOR PLASMA DIELECTRIC BARRIER DISCHARGE UNTUK PRODUKSI BIODIESEL DARI MINYAK KELAPA SAWIT

    Directory of Open Access Journals (Sweden)

    Ardian Dwi Yudhistira

    2013-10-01

    Full Text Available Biodiesel is one of alternative renewable energy source to substitute diesel fuel. Various biodiesel productionprocesses through transesterification reaction with a variety of catalysts have been developed by previousresearcher. This process still has the disadvantage of a long reaction time, and high energy need. DielectricBarrier Discharge (DBD plasma electro-catalysis may become a solution to overcome the drawbacks in theconventional transesterification process. This process only needs a short time reaction and low energy process.The purpose of this study was to assess the performance of DBD plasma rector in making biodiesel such as: theeffect of high voltage electric value, electrodes gap, mole ratio of methanol / oil, and reaction time. TheResearch method was using GC-MS (Gas Cromatography-Mass Spectrofotometry and FTIR (FourierTransform Infrared Spectrofotometry and then it will be analysed the change of chemical bond betweenreactant and product. So, the reaction mechanism can be predicted. Biodiesel is produced using methanol andpalm oil as reactants and DBD plasma used as reactor in batch system. Then, reactants contacted by highvoltage electric. From the results of this research can be concluded that the reaction mechanism occurs in theprocess is the reaction mechanism of cracking, the higher of electric voltage and the longer of reaction time leadto increasing of product yield. The more of mole ratio of methanol / oil and widening the gap between theelectrodes lead to decreased product yield. From this research, product yield maksimum is 89,8% in the variableof rasio mol metanol/palm oil 3:1, voltage 10 kV, electrode gap 1,5 cm, and reaction time 30 seconds.

  19. Decomposition of Potent Greenhouse Gases SF6, CF4 and SF5CF3 by Dielectric Barrier Discharge

    Science.gov (United States)

    Zhang, Renxi; Wang, Jingting; Cao, Xu; Hou, Huiqi

    2016-04-01

    For their distinguished global warming potential (GWP100) and long atmosphere lifespan, CF4, SF6 and SF5CF3 were significant in the field of greenhouse gas research. The details of discharging character and the optimal parameter were discussed by using a Dielectric Barrier Discharge (DBD) reactor to decompose these potent greenhouse gases in this work. The results showed that SF6 could be decomposed by 92% under the conditions of 5 min resident time and 3000 V applied voltage with the partial pressure of 2.0 kPa, 28.2 kPa, and 1.8 kPa for SF6, air and water vapor, respectively. 0.4 kPa CF4 could be decomposed by 98.2% for 4 min resident time with 30 kPa Ar added. The decomposition of SF5CF3 was much more effective than that of SF6 and CF4 and moreover, 1.3 kPa SF5CF3, discharged with 30 kPa O2, Ar and air, could not be detected when the resident time was 80 s, 40 s, and 120 s, respectively. All the results indicated that DBD was a feasible technique for the abatement of potent greenhouse gases. supported by National Natural Science Foundation of China (Nos. 20507004, 21577023)

  20. Gas-dynamic disturbances created by surface dielectric barrier discharge in the constricted mode

    Science.gov (United States)

    Moralev, I.; Boytsov, S.; Kazansky, P.; Bityurin, V.

    2014-05-01

    Three-dimensional structure of the gas-dynamic disturbances, created by surface dielectric barrier discharge in a constricted (saturated) mode, was analyzed simultaneously with the discharge morphology. Discharge was created in the still air under normal conditions. Flow visualization was performed by shadowgraphy and stereo-PIV technique. The wall-normal jets with the origins located in between the positions of the constricted filaments are found. Velocity magnitude in the wall-normal direction is comparable with the tangential component. Flow structure is similar to the one created by the serpentine actuator.

  1. Characteristics of radio-frequency atmospheric pressure dielectric-barrier discharge with dielectric electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Hussain, S., E-mail: shussain@uos.edu.pk, E-mail: shussainuos@yahoo.com; Qazi, H. I. A.; Badar, M. A. [Department of Physics, University of Sargodha, 40100 Sargodha (Pakistan)

    2014-03-15

    An experimental investigation to characterize the properties and highlight the benefits of atmospheric pressure radio-frequency dielectric-barrier discharge (rf DBD) with dielectric electrodes fabricated by anodizing aluminium substrate is presented. The current-voltage characteristics and millisecond images are used to distinguish the α and γ modes. This atmospheric rf DBD is observed to retain the discharge volume without constriction in γ mode. Optical emission spectroscopy demonstrates that the large discharge current leads to more abundant reactive species in this plasma source.

  2. Three-dimensional patterns in dielectric barrier discharge with "H" shaped gas gap

    Science.gov (United States)

    Gao, Xing; Dong, Lifang; Wang, Hao; Zhang, Hao; Liu, Ying; Liu, Weibo; Fan, Weili; Pan, Yuyang

    2016-08-01

    Three-dimensional (3D) patterns are obtained for the first time in dielectric barrier discharge by a special designed device with "H" shaped gas gap which consists of a single gas layer gap and two double gas layer gaps. Three dimensional spatiotemporal characteristics of discharge are investigated by photomultiplier and intensified charge-coupled device camera. Results show that the discharge first generates in the single gas layer gap and the coupled filaments in the double gas layer gap present the simultaneity characteristics. The formation of 3D patterns is determined by the distribution of the effective field of the applied field and the wall charge field.

  3. Transient Behaviour of Superconducting Magnet Systems of Fusion Reactor ITER during Safety Discharge

    Directory of Open Access Journals (Sweden)

    A. M. Miri

    2008-01-01

    Full Text Available To investigate the transient behaviour of the toroidal and poloidal field coils magnet systems of the International Thermonuclear Experimental Reactor during safety discharge, network models with lumped elements are established. Frequency-dependant values of the network elements, that is, inductances and resistances are calculated with the finite element method. That way, overvoltages can be determined. According to these overvoltages, the insulation coordination of coils has to be selected.

  4. Degradation of Benzene by Using a Silent-Packed Bed Hybrid Discharge Plasma Reactor

    Science.gov (United States)

    Jiang, Nan; Lu, Na; Li, Jie; Wu, Yan

    2012-02-01

    In this work, a novel gas phase silent-packed bed hybrid discharge plasma reactor has been proposed, and its ability to control a simulative gas stream containing 240 ppm benzene is experimentally investigated. In order to optimize the geometry of the reactor, the benzene conversion rate and energy yield (EY) were compared for various inner electrode diameters and quartz tube shapes and sizes. In addition, benzene removal efficiency in different discharge regions was qualitatively analyzed and the gas parameter (space velocity) was systematically studied. It has been found that silent-packed bed hybrid discharge plasma reactor can effectively decompose benzene. Benzene removal proved to achieve an optimum value of 60% with a characteristic energy density of 255 J/L in this paper with a 6 mm bolt high-voltage electrode and a 13 mm quartz tube. The optimal space velocity was 188.1 h-1, which resulted in moderate energy yield and removal efficiency. Reaction by-products such as hydroquinone, heptanoic acid, 4-nitrocatechol, phenol and 4-phenoxy-phenol were identified by mean of GC-MS. In addition, based on these organic by-products, a benzene destruction pathway was proposed.

  5. Experimental study on dielectric barrier discharge actuators operating in pulse mode

    NARCIS (Netherlands)

    Kotsonis, M.; Veldhuis, L.

    2010-01-01

    An experimental investigation is performed on the operation of dielectric barrier discharge plasma actuators used as manipulators of secondary and unsteady flow structures such as boundary layer instabilities or shedding vortices. The actuators are tested mainly in pulse mode. High sample rate hot-w

  6. Influence of ultrasonic irradiation on ozone generation in a dielectric barrier discharge

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Drews, J.; Leipold, Frank

    2012-01-01

    An atmospheric pressure dielectric barrier discharge (DBD) was generated in an N2/O2 gas mixture at room temperature with and without ultrasonic irradiation to investigate ozone production. Powerful ultrasonic irradiation with the sound pressure level of approximately 150 dB into the DBD can...... enhance ozone production especially when the DBD was driven at a frequency of 15 kHz....

  7. Measurement of Plasma Density Produced in Dielectric Barrier Discharge for Active Aerodynamic Control with Interferometer

    Institute of Scientific and Technical Information of China (English)

    LI Gang; ZHANG Yi; XU Yan-Ji; LIN Bin; LI Yu-Tong; ZHU Jun-Qiang

    2009-01-01

    We utilize an interferometer to investigate the changes of the refractive index caused by dielectric barrier discharge plasma.The electronic density of the plasma produced is measured and analyzed tentatively.The results show that density of the plasma increases linearly with exciting voltages.

  8. Vortex flow formation during dielectric barrier discharge initiation in quiescent air

    NARCIS (Netherlands)

    Golub, V. V.; Saveliev, A. S.

    2010-01-01

    The structure of vortex flows generated by dielectric barrier discharge initiated in quiescent air at atmospheric pressure has been studied by the methods of particle image velocimetry and schlieren photography. The flow parameters have been measured as functions of the time past the electric discha

  9. Experimental Study on the Body Force Field of Dielectric Barrier Discharge Actuators

    NARCIS (Netherlands)

    Kotsonis, M.; Ghaemi, S.; Giepman, R.H.M.; Veldhuis, L.L.M.

    2010-01-01

    An experimental investigation on thrust and body force of Dielectric Barrier Discharge (DBD) /plasma actuators aimed at low power flow control applications is presented. A parametric study on thrust is conducted for a wide range of geometrical configurations as well as several electrical operational

  10. Effect of Dielectric Barrier Discharge on Wing-Tip Vortex Formation

    NARCIS (Netherlands)

    Agibalova, S. A.; Golub, V. V.; Moralev, I. A.; Saveliev, A. S.

    2011-01-01

    The formation of vortex trace behind a finite-span model airfoil has been studied by the method of stereoscopic particle image velocimetry. It is established that a dielectric barrier discharge initiated at the airfoil tip surface influences the wing-tip vortex formation.

  11. Effects of surface dielectric barrier discharge on aerodynamic characteristic of train

    Science.gov (United States)

    Dong, Lei; Gao, Guoqiang; Peng, Kaisheng; Wei, Wenfu; Li, Chunmao; Wu, Guangning

    2017-07-01

    High-speed railway today has become an indispensable means of transportation due to its remarkable advantages, including comfortability, convenience and less pollution. The increase in velocity makes the air drag become the main source of energy consumption, leading to receiving more and more concerns. The surface dielectric barrier discharge has shown some unique characteristics in terms of active airflow control. In this paper, the influences of surface dielectric barrier discharge on the aerodynamic characteristics of a scaled train model have been studied. Aspects of the discharge power consumption, the temperature distribution, the velocity of induced flow and the airflow field around the train model were considered. The applied AC voltage was set in the range of 20 kV to 28 kV, with a fixed frequency of 9 kHz. Results indicated that the discharge power consumption, the maximum temperature and the induced flow velocity increased with increasing applied voltage. Mechanisms of applied voltage influencing these key parameters were discussed from the point of the equivalent circuit. The airflow field around the train model with different applied voltages was observed by the smoke visualization experiment. Finally, the effects of surface dielectric barrier discharge on the train drag reduction with different applied voltages were analyzed.

  12. Discharge transitions between glow-like and filamentary in a xenon/chlorine-filled barrier discharge lamp

    Science.gov (United States)

    Xu, Jinzhou; Guo, Ying; Xia, Lei; Zhang, Jing

    2007-08-01

    An asymmetric electric voltage pulse source (2-20 kHz, Vp-p: 0-20 kV) was applied to stimulate excimer radiation by a dielectric barrier discharge in a binary gas mixture of chlorine (10.8 Torr)/xenon at high pressure (~460 Torr). When the source frequency increases continuously from 2.0 to 12.0 kHz or in reverse under a fixed output voltage of Vp-p (13.8 kV), it is observed that the discharge modes excited by this pulse source transmit between glow-like and filamentary, and we observe a mixed mode with filaments randomly distributed in the diffuse-like background in the narrow frequency range 7.0-8.0 kHz. It is argued that the reasons for the discharge transition could be the frequency and the time derivative of the voltage waveform of the power source. It is also observed that there is an obvious difference in the emission spectral profiles and the energy efficiency of excimer emission for the two discharge modes.

  13. Dielectric barrier discharge plasma atomizer for hydride generation atomic absorption spectrometry—Performance evaluation for selenium

    Energy Technology Data Exchange (ETDEWEB)

    Duben, Ondřej [Institute of Analytical Chemistry of the CAS, v.v.i., Veveří 97, CZ-602 00 Brno (Czech Republic); Faculty of Science, Department of Analytical Chemistry, Charles University in Prague, Hlavova 8, Prague, CZ 128 43 Czech Republic (Czech Republic); Boušek, Jaroslav [Faculty of Electrical Engineering and Communications, Brno University of Technology, Technická 1058/10, 61600 Brno (Czech Republic); Dědina, Jiří [Institute of Analytical Chemistry of the CAS, v.v.i., Veveří 97, CZ-602 00 Brno (Czech Republic); Kratzer, Jan, E-mail: jkratzer@biomed.cas.cz [Institute of Analytical Chemistry of the CAS, v.v.i., Veveří 97, CZ-602 00 Brno (Czech Republic)

    2015-09-01

    Atomization of selenium hydride in a quartz dielectric barrier discharge (DBD) atomizer was optimized and its performance was compared to that of the externally heated quartz multiatomizer. Argon was found as the best DBD discharge gas employing a flow rate of 75 ml min{sup −1} Ar while the DBD power was optimized at 14 W. The detection limits reached 0.24 ng ml{sup −1} Se in the DBD and 0.15 ng ml{sup −1} Se in the multiatomizer. The tolerance of DBD to interferences is even better than with the multiatomizer. - Highlights: • SeH{sub 2} atomization in a dielectric barrier discharge (DBD) was optimized for AAS. • Atomizer performance was compared for DBD and externally heated quartz atomizer. • Detection limits were quantified and interferences were studied in both atomizers. • Atomization efficiency in the DBD was estimated.

  14. Novel Gas-liquid Hybrid Discharge Reactor for 4-CP Containing Wastewater Treatment

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In order to improve 4-CP degradation efficiency, a novel gas-liquid hybrid discharge (HD) reactor was developed. Removal of 4-CP with spark-spark discharge (SSD) was higher than that with spark-corona discharge (SCD). Amount of H2O2 and O3 produced with SSD were larger than that with SCD. ·OH formation was increased by the combination of H2O2 and O3.The contribution of ·OH (38 % formed by O3 conversion) oxidation on removal of 4-CP accounted for nearly 60 %. The other effects of ultraviolet radiation, intense shock waves and pyrolysis,played partial roles in about 40 % of removal rate.

  15. Nanosecond pulsed sliding dielectric barrier discharge plasma actuator for airflow control: Electrical, optical, and mechanical characteristics

    Science.gov (United States)

    Bayoda, K. D.; Benard, N.; Moreau, E.

    2015-08-01

    Plasma actuators used for active flow control are widely studied because they could replace mechanical actuators. Industrial applications of these plasma actuators sometimes require a large surface plasma sheet in view of increasing the interaction region between the discharge and the incoming flow. Instead of using a typical two-electrode nanosecond pulsed dielectric barrier discharge for which the interaction region is limited to about 20 mm, this study proposes to characterize a nanosecond sliding discharge based on a three-electrode geometry in order to increase the extension length up to the electrode gap. This sliding discharge is compared to the typical nanosecond dielectric barrier discharge by means of electrical, optical, and mechanical diagnostics. Electrical characterization reveals that the deposited energy can be widely increased. Time-resolved Intensified Charge Coupled Device (iCCD) images of the discharge development over the dielectric surface highlight that the intensity and the propagation velocity of streamers are strongly affected by the DC voltage applied at the third electrode. Finally, qualitative and quantitative characterizations of the pressure wave due to the surrounding gas heating are proposed by means of Schlieren visualizations and high frequency pressure measurements, respectively.

  16. The influence of negative ions in helium-oxygen barrier discharges: I. Laser photodetachment experiment

    Science.gov (United States)

    Tschiersch, R.; Nemschokmichal, S.; Meichsner, J.

    2016-04-01

    This work is the experimental part of a comprehensive study that aims to understand the influence of negative ions on the development of atmospheric pressure barrier discharges in electronegative systems. The investigations will be complemented by a 1D numerical fluid simulation. Laser photodetachment experiments were performed in a glow-like barrier discharge operated in helium with admixtures of oxygen up to 1 vol.% at a gas pressure of 500 mbar. The discharge gap between the glass-coated electrodes was 3 mm. The discharge properties were characterized by electrical measurements and optical emission spectroscopy. Laser photodetachment of {{\\text{O}}-} , {\\text{O}}2- , and {\\text{O}}3- was studied using the fundamental and second harmonic wavelength of a Nd-YAG laser. The laser photodetachment of negative ions influences the breakdown characteristics when the laser is fired during the prephase of the discharge only. The breakdown voltage is reduced, which indicates an enhanced pre-ionization initiated by the detached electrons. Systematic variations in the laser pulse in time, the axial laser beam position, the laser pulse energy, and the laser wavelength provided detailed knowledge on this process. The investigation underlines the importance of the discharge prephase in general and aims to differentiate between the negative ion species {{\\text{O}}-} , {\\text{O}}2- , and {\\text{O}}3- .

  17. An experimental study of atmospheric pressure dielectric barrier discharge (DBD) in argon

    Energy Technology Data Exchange (ETDEWEB)

    Subedi, D. P. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel (Nepal); Tyata, R. B. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel, Nepal and Department of Electrical, Khwopa College of Engineering, Libali-2, Bhaktapur (Nepal); Shrestha, R. [Department of Natural Sciences, School of Science, Kathmandu University, Dhulikhel, Nepal and Department of Physics, Basu College, Kalighat, Byasi, Bhaktapur (Nepal); Wong, C. S. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2014-03-05

    In this paper, experimental results on atmospheric pressure argon dielectric barrier discharge (DBD) have been presented. The discharge was generated using a high voltage (0 to 20 kV) power supply operating at frequency of 10 to 30 kHz and was studied by means of electrical and optical measurements. A homogeneous and steady discharge was observed between the electrodes with gap spacing from 1 mm to 3 mm and with a dielectric barrier of thickness 1.5 mm while argon gas is fed at a controlled flow rate of 2liter per min. The electron temperature (T{sub e}) and electron density (n{sub e}) of the plasma have been determined by means of optical emission spectroscopy. Our results show that the electron density is of the order of 10{sup 16} cm{sup −3} while the electron temperature is estimated to be ∼ 1 eV. The homogeneity and non-thermal nature of the discharge were utilized in the investigation of the change in wettabilty of a polymer sample subjected to the treatment by the discharge. Contact angle analysis showed that the discharge was effective in improving the wettability of low density Polyethylene (LDPE) polymer sample after the treatment.

  18. Investigation of a single barrier discharge in submillimeter air gaps. Nonuniform field

    Science.gov (United States)

    Bondarenko, P. N.; Emel'yanov, O. A.; Shemet, M. V.

    2014-08-01

    Pulse characteristics of single barrier discharges as well as parameters of charges accumulated on the surface of a dielectric under the atmospheric pressure in the "needle-(0.1-2.0)-mm air gap-polymer barrier-plane" system are investigated. It is found experimentally that for the positive polarity of the needle, the voltage for the discharge initiation is higher than in the case of the negative polarity by ˜25-35%. The reversal of the needle polarity from negative to positive increases the amplitude of the discharge current and the accumulated surface charge by ˜1.5-3 times. For the positive polarity of the needle, the discharge is governed by a streamer mechanism, while for the negative polarity, the discharge is initiated by the formation of a single Trichel pulse. The single pulse regime is observed for the discharge current up to a certain electrode gap d CR. For the positive needle and for air gap width d air > d CR ≈ 1.5 mm, a multipulse burst corona is formed, while for the negative needle and d air > d CR ≈ 0.9 mm, a damped sequence of Trichel pulses evolves in the system.

  19. Catalytic and Noncatalytic Conversion of Methane to Olefins and Synthesis Gas in an AC Parallel Plate Discharge Reactor

    Directory of Open Access Journals (Sweden)

    Mohammad Ali Khodagholi

    2013-01-01

    Full Text Available Direct conversion of methane to ethylene, acetylene, and synthesis gas at ambient pressure and temperature in a parallel plate discharge reactor was investigated. The experiments were carried out using a quartz reactor of outer diameter of 9 millimeter and a driving force of ac current of 50 Hz. The input power to the reactor to establish a stable gas discharge varied from 9.6 to maximum 15.3 watts (w. The effects of ZSM5, Fe–ZSM5, and Ni–ZSM5 catalysts combined with corona discharge for conversion of methane to more valued products have been addressed. It was found that in presence or absence of a catalyst in gas discharge reactor, the rate of methane and oxygen conversion increased upon higher input power supplied to the reactor. The effect of Fe–ZSM5 catalyst combined with gas discharge plasma yields C2 hydrocarbons up to 21.9%, which is the highest productions of C2 hydrocarbons in this work. The effect of combined Ni–ZSM5 and gas discharge plasma was mainly production of synthesis gas. The advantage of introducing ZSM5 to the plasma zone was increase in synthesis gas and acetylene production. The highest energy efficiency was 0.22 mmol/kJ, which belongs to lower rate of energy injection to the reactor.

  20. RAPID COMMUNICATION: Enhanced performance of a dielectric barrier discharge lamp using short-pulsed excitation

    Science.gov (United States)

    Mildren, R. P.; Carman, R. J.

    2001-01-01

    We observe marked increases in the time-averaged intensity, peak intensity, efficiency and spectral purity of the VUV output from an Xe excimer barrier discharge lamp when using short-pulse (~150 ns FWHM (full width half maximum)) excitation. Intensity increases with Xe pressure up to 600 Torr with a maximum output 2.6 times higher and an efficiency 3.2 times higher than the same lamp excited by conventional ac excitation (i.e. sinusoidal voltage waveform). The output occurs in regular short pulses (pulsed discharge appears diffuse (i.e. glow-like), even at the higher pressures at which the ac discharge is filamentary. It is concluded that the enhanced performance results largely from the ability for pulsed excitation to generate a discharge at near atmospheric pressures with a much lower electron density than that possible using ac.

  1. Impact of gas flow rate on breakdown of filamentary dielectric barrier discharges

    Science.gov (United States)

    Höft, H.; Becker, M. M.; Kettlitz, M.

    2016-03-01

    The influence of gas flow rate on breakdown properties and stability of pulsed dielectric barrier discharges (DBDs) in a single filament arrangement using a gas mixture of 0.1 vol. % O2 in N2 at atmospheric pressure was investigated by means of electrical and optical diagnostics, accompanied by fluid dynamics and electrostatics simulations. A higher flow rate perpendicular to the electrode symmetry axis resulted in an increased breakdown voltage and DBD current maximum, a higher discharge inception jitter, and a larger emission diameter of the discharge channel. In addition, a shift of the filament position for low gas flow rates with respect to the electrode symmetry axis was observed. These effects can be explained by the change of the residence time of charge carriers in the discharge region—i.e., the volume pre-ionization—for changed flow conditions due to the convective transport of particles out of the center of the gap.

  2. Investigation of nanosecond-pulsed dielectric barrier discharge actuators with powered electrodes of different exposures

    Science.gov (United States)

    Xu, Shuangyan; Cai, Jinsheng; Lian, Yongsheng

    2017-09-01

    Nanosecond-pulsed dielectric barrier discharge actuators with powered electrodes of different exposures were investigated numerically by using a newly proposed plasma kinetic model. The governing equations include the coupled continuity plasma discharge equation, drift-diffusion equation, electron energy equation, Poisson’s equation, and the Navier-Stokes equations. Powered electrodes of three different exposures were simulated to understand the effect of surface exposure on plasma discharge and surrounding flow field. Our study showed that the fully exposed powered electrode resulted in earlier reduced electric field breakdown and more intensive discharge characteristics than partially exposed and rounded-exposed ones. Our study also showed that the reduced electric field and heat release concentrated near the right upper tip of the powered electrode. The fully exposed electrode also led to stronger shock wave, higher heating temperature, and larger heated area.

  3. Effect of duty-cycles on the air plasma gas-phase of dielectric barrier discharges

    Science.gov (United States)

    Barni, R.; Biganzoli, I.; Dell'Orto, E. C.; Riccardi, C.

    2015-10-01

    An experimental investigation concerning the effects of a duty-cycle in the supply of a dielectric barrier discharge in atmospheric pressure air has been performed. Electrical characteristics of the discharge have been measured, focusing mainly on the statistical properties of the current filaments and on dielectric surface charging, both affected by the frequent repetition of breakdown imposed by the duty-cycle. Information on the gas-phase composition was gathered too. In particular, a strong enhancement in the ozone formation rate is observed when suitable long pauses separate the active discharge phases. A simulation of the chemical kinetics in the gas-phase, based on a simplified discharge modeling, is briefly described in order to shed light on the observed increase in ozone production. The effect of a duty-cycle on surface modification of polymeric films in order to increase their wettability has been investigated too.

  4. Experimental investigation of Lissajous figure shapes in planar and surface dielectric barrier discharges

    Science.gov (United States)

    Biganzoli, I.; Barni, R.; Gurioli, A.; Pertile, R.; Riccardi, C.

    2014-11-01

    Dielectric Barrier Discharges (DBDs) operating in air at atmospheric pressure are widely employed as cold plasma sources for plasma processing and applications, in both volume and surface configurations. Surface dielectric barrier discharges, however, are mainly known for the manipulation of the boundary layer of an airflow surrounding a body, and thus for aeronautical applications. Lissajous figures, obtained by means of a high-voltage and a capacitive probes, are usually adopted for both these types of DBDs as a method for measuring the power consumption by the discharge. In this work, we propose to integrate this diagnostic tool with the measurement of current pulses, which are associated to microdischarges that usually develop in these plasmas because of the presence of the dielectric barrier. We have studied both planar and surface DBDs in presence of a continuous sinusoidal voltage feeding, and we have demonstrated that this method is promising in order to gain additional information about the discharge characteristics from the shape of the Lissajous figures.

  5. Liposomal membrane disruption by means of miniaturized dielectric-barrier discharge in air: liposome characterization

    Science.gov (United States)

    Svarnas, P.; Asimakoulas, L.; Katsafadou, M.; Pachis, K.; Kostazos, N.; Antimisiaris, S. G.

    2017-08-01

    The increasing interest of the plasma community in the application of atmospheric-pressure cold plasmas to bio-specimen treatment has led to the creation of the emerging field of plasma biomedicine. Accordingly, plasma setups based on dielectric-barrier discharges have already been widely tested for the inactivation of various cells. Most of these systems refer to the plasma jet concept where noble gases penetrate atmospheric air and are subjected to the influence of high electric fields, thus forming guided streamers. Following the original works of our group where liposomal membranes were proposed as models for studying the interaction between plasma jets and cells, we present herein a study on liposomal membrane disruption by means of miniaturized dielectric-barrier discharge running in atmospheric air. Liposomal membranes of various lipid compositions, lamellarities, and sizes are treated at different times. It is shown that the dielectric-barrier discharge of low mean power leads to efficient liposomal membrane disruption. The latter is achieved in a controllable manner and depends on liposome properties. Additionally, it is clearly demonstrated that liposomal membrane disruption takes place even after plasma extinction, i.e. during post-treatment, resembling thus an ‘apoptosis’ effect, which is well known today mainly for cell membranes. Thus, the adoption of the present concept would be beneficial for tailoring studies on plasma-treated cell-mimics. Finally, the liposome treatment is discussed with respect to possible physicochemical mechanisms and potential discharge modification due to the various compositions of the liquid electrode.

  6. Numerical investigation of the spatiotemporal distribution of chemical species in an atmospheric surface barrier-discharge

    Science.gov (United States)

    Hasan, M. I.; Walsh, J. L.

    2016-05-01

    Using a one dimensional time dependent convection-reaction-diffusion model, the temporal and spatial distributions of species propagating downstream of an atmospheric pressure air surface barrier discharge was studied. It was found that the distribution of negatively charged species is more spatially spread compared to positive ions species, which is attributed to the diffusion of electrons that cool down and attach to background gas molecules, creating different negative ions downstream of the discharge region. Given the widespread use of such discharges in applications involving the remote microbial decontamination of surfaces and liquids, the transport of plasma generated reactive species away from the discharge region was studied by implementing mechanical convection through the discharge region. It was shown that increased convection causes the spatial distribution of species density to become uniform. It was also found that many species have a lower density close to the surface of the discharge as convection prevents their accumulation. While for some species, such as NO2, convection causes a general increase in the density due to a reduced residence time close to the discharge region, where it is rapidly lost through reactions with OH. The impact of the applied power was also investigated, and it was found that the densities of most species, whether charged or neutral, are directly proportional to the applied power.

  7. Efficiency of pulse-mode dielectric barrier discharge excimer lamp in constant duty cycle

    Science.gov (United States)

    Akashi, Haruaki; Oda, Akinori; Sakai, Yosuke

    2008-10-01

    Efficiency of pulse-mode dielectric barrier discharge (DBD) excimer lamp under constant duty cycle with increasing applied voltage has been simulated using two dimensional fluid model[1]. Xe gas with 300Torr pressure is assumed. And the simulated region considered in this model is 1cm(gap length)x3cm(radial length). Periodical boundary conditions are assumed for the radial direction boundaries. The both electrodes are covered with dielectrics and their thickness is 0.2cm. 5˜8kV trapezoid shape voltage is applied with the same voltage rising ratio and 50% duty ratio waveform with 200x10^3pps repetition rate. The discharge occurs at the rising edge and tailing edge of applied voltage. 172nm VUV intensity obtained from first discharge is higher than second one in lower applied voltage (<6kV) case. And in higher voltage case, the intensity from second discharge becomes higher. This is explained by shortening of interval time between the discharges. The short interval time makes higher initial electron density for second discharge. As a results, the input and 172nm VUV output power increases with increasing applied voltage, but the efficiency decreases. Because of inefficient surface discharge [1]H. Akashi et al, IEEE Trans. Plasma Science, Vol.33,No.2(2005,4)pp.308-309

  8. Propagation of negative electrical discharges through 2-dimensional packed bed reactors

    Science.gov (United States)

    Kruszelnicki, Juliusz; Engeling, Kenneth W.; Foster, John E.; Xiong, Zhongmin; Kushner, Mark J.

    2017-01-01

    Plasma-based pollutant remediation and value-added gas production have recently gained increased attention as possible alternatives to the currently-deployed chemical reactor systems. Electrical discharges in packed bed reactors (PBRs) are of interest, due to their ability to synergistically combine catalytic and plasma chemical processes. In principle, these systems could be tuned to produce specific products, based on their application by combinations of power formats, materials, geometries and working gases. Negative voltage, atmospheric-pressure plasma discharges sustained in humid air in a PBR-like geometry were experimentally characterized using ICCD imaging and simulated in 2-dimensions (2D) to provide insights into possible routes to this tunability. Surface ionization waves (SIWs) and positive restrikes through the lattice of dielectric rods were shown to be the principal means of producing reactive species. The number and intensity of SIWs and restrikes are sensitive functions of the alignment of the lattice of dielectric beads (or rods in 2D) with respect to the applied electric field. Decreased spacing between the dielectric elements leads to an increased electric field enhancement in the gas, and therefore locally higher plasma densities, but does not necessarily impact the types of discharges that occur through the lattice.

  9. Ozone production in parallel multichannel dielectric barrier discharge from oxygen and air: the influence of gas pressure

    Science.gov (United States)

    Yuan, Dingkun; Wang, Zhihua; Ding, Can; He, Yong; Whiddon, Ronald; Cen, Kefa

    2016-11-01

    This research aims to investigate the influence of gas pressure (0.1 Mpa-0.2 Mpa) on ozone generation in a parallel multichannel dielectric barrier discharge (DBD) reactor with a narrow gap (0.2 mm). In addition to determining ozone concentration and ozone yield characteristics with gas pressure variation, this paper examines the possible reasons leading to the inconsistency with previous reported results. All the experimental results are plotted on the basis of specific input energy (SIE) in order to conduct the comparison within identical power density. By reviewing the experimental results, the possible cause leading to the inconsistency concerning gas pressure dependences of ozone generation was found using different comparison bases. Results show that ozone generation is slightly suppressed with an increase of gas pressure with an initial increase in SIE. The results of the ozone yield show that an increase of gas pressure would have a favorable effect on ozone production efficiency with an SIE larger than 400 J l-1 in oxygen while ozone yield reaches the maximum at 0.14 Mpa with an SIE larger than 150 J l-1 in air. Increasing gas pressure would lead to a higher critical SIE value at which ozone yield firstly decreases with an increase of SIE both in oxygen and air. The results of nitrogen oxide byproducts show that both NO x byproducts emission and the discharge poisoning effect are suppressed by increasing gas pressure in air plasmas.

  10. Effect of Frequency on Emission of XeIast Excimer in a Pulsed Dielectric Barrier Discharge

    Science.gov (United States)

    Ou, Qiong-Rong; Meng, Yue-Dong; Xu, Xu; Shu, Xing-Sheng; Ren, Zhao-Xing

    2004-07-01

    Emission spectra of XeIast excimers and ultraviolet intensity at 253 nm from a dielectric barrier discharge (DBD) lamp excited by a pulsed voltage were measured as functions of pressure, electrical power, and frequency. In the DBD lamp driven by a higher frequency voltage, a more intense emission of XeIast excimers with high efficiency at 253 nm was found. A diffuse discharge mode was observed at high xenon pressure (>1 atm) with an excessive iodine concentration in the DBD driven by a high frequency (60 kHz) voltage.

  11. Effect of Frequency on Emission of XeI* Excimer in a Pulsed Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    OU Qiong-Rong; MENG Yue-Dong; XU Xu; SHU Xing-Sheng; REN Zhao-Xing

    2004-01-01

    Emission spectra of XeI* excimers and ultraviolet intensity at 253 nm from a dielectric barrier discharge (DBD)lamp excited by a pulsed voltage were measured as functions of pressure, electrical power, and frequency. In the DBD lamp driven by a higher frequency voltage, a more intense emission of XeI* excimers with high efficiency at 253 nm was found. A diffuse discharge mode was observed at high xenon pressure (> 1 atm) with an excessive iodine concentration in the DBD driven by a high frequency (60 kHz) voltage.

  12. Optical Emission Spectroscopy Investigation of a Surface Dielectric Barrier Discharge Plasma Aerodynamic Actuator

    Institute of Scientific and Technical Information of China (English)

    LI Ying-Hong; WU Yun; JIA Min; ZHOU Zhang-Wen; GUO Zhi-Gang; PU Yi-Kang

    2008-01-01

    The optical emission spectroscopy of a surface dielectric barrier discharge plasma aerodynamic actuator is investigated with different electrode configurations, applied voltages and driving frequencies. The rotational temperature of N2 (C3IIu) molecule is calculated according to its rotational emission band near 380.5 nm. The average electron energy of the discharge is evaluated by emission intensity ratio of first negative system to second positive system of N2. The rotational temperature is sensitive to the inner space of an electrode pair. The average electron energy shows insensitivity to the applied voltage, the driving frequency and the electrode configuration.

  13. Generation of nanosecond pulses in a barrier-discharge XeBr excimer lamp

    Science.gov (United States)

    Avdeev, S. M.; Kostyrya, I. D.; Sosnin, É. A.; Tarasenko, V. F.

    2006-07-01

    The subject of investigation is the coaxial two-barrier short-pulse excimer lamp based on XeBr* molecules (λ = 282 nm). When the working mixture (Xe: Br2 = 70: 1) is excited by a high-voltage pulsed nanosecond discharge at a pressure of 1 atm, the peak power of the generated radiation is on the order of 100 kW at an FWHM of 4.5 ns. If the gap between the barriers is small, a train of pulses with an FWHM of 20 ns and a repetition rate of 200 kHz may be obtained.

  14. Evaluation of the potential for fish passage through the N Reactor and the Hanford generating project discharges

    Energy Technology Data Exchange (ETDEWEB)

    Dauble, D.D.; Vail, L.W.; Neitzel, D.A.

    1987-09-01

    The potential for juvenile downstream-migrating salmonids to encounter both the Hanford Generating Project (HGP) and N Reactor discharges was evaluated. Three general scenarios were assessed for fish exposure: (1) HGP plume centerline passage followed by N Reator plum centerline passage, (2) HGP plume centerline passage including intersection with the N Reactor plume, and (3) noncenterline plume passage through the edge of first the HGP and then the N Reactor plume. It is highly unlikely that a fish would pass through both plume centerlines because of the location of the two discharges and because of river-mixing characteristics near the discharges. For the set of conditions that we evaluated, exposure to elevated temperatures would be of insufficient duration to result in mortalities to fish that might encounter both the HGP and N Reactor plumes.

  15. Parallel 3-D numerical simulation of dielectric barrier discharge plasma actuators

    Science.gov (United States)

    Houba, Tomas

    Dielectric barrier discharge plasma actuators have shown promise in a range of applications including flow control, sterilization and ozone generation. Developing numerical models of plasma actuators is of great importance, because a high-fidelity parallel numerical model allows new design configurations to be tested rapidly. Additionally, it provides a better understanding of the plasma actuator physics which is useful for further innovation. The physics of plasma actuators is studied numerically. A loosely coupled approach is utilized for the coupling of the plasma to the neutral fluid. The state of the art in numerical plasma modeling is advanced by the development of a parallel, three-dimensional, first-principles model with detailed air chemistry. The model incorporates 7 charged species and 18 reactions, along with a solution of the electron energy equation. To the author's knowledge, a parallel three-dimensional model of a gas discharge with a detailed air chemistry model and the solution of electron energy is unique. Three representative geometries are studied using the gas discharge model. The discharge of gas between two parallel electrodes is used to validate the air chemistry model developed for the gas discharge code. The gas discharge model is then applied to the discharge produced by placing a dc powered wire and grounded plate electrodes in a channel. Finally, a three-dimensional simulation of gas discharge produced by electrodes placed inside a riblet is carried out. The body force calculated with the gas discharge model is loosely coupled with a fluid model to predict the induced flow inside the riblet.

  16. Three-dimensional discharge simulation of inductively coupled plasma (ICP) etching reactor

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    More and more importance has been attached to inductively coupled plasma (ICP) in semiconductor manufacture. For a deep understanding of the plasma discharge process in the etching reactor, this study made a three-dimensional simulation on the Ar plasma discharge process with the commercial software CFD-ACE, which is according to the real experiment conditions and data supplied by North Microelec-tronic Corporation. The error of the simulation results is in the range of ±20% with credibility. The numerical results show that the three-dimentional spatial distribu-tion of electron density is reduced from the chamber center to the wall. The distri-bution of electron density, electron temperature and power deposition is related to the shape and placement of the coil.

  17. Removal of NO and SO2 in Corona Discharge Plasma Reactor with Water Film

    Institute of Scientific and Technical Information of China (English)

    贺元吉; 董丽敏; 杨嘉祥

    2004-01-01

    In this paper, a novel type of a corona discharge plasma reactor was designed, which consists of needle-plate-combined electrodes, in which a series of needle electrodes are placed in a glass container filled with flue gas, and a plate electrode is immersed in the water. Based on this model, the removal of NO and SO2 was tested experimentally. In addition, the effect of streamer polarity on the reduction of SO2 and NO was investigated in detail. The experimental results show that the corona wind formed between the high-voltage needle electrode and the water by corona discharge enhances the cleaning efficiency of the flue gas because of the presence of water,and the cleaning efficiency will increase with the increase of applied dc voltage within a definite range. The removal efficiency of SO2 up to 98%, and about 85% of NOx removal under suitable conditions is obtained in our experiments.

  18. A Study of Removing Chlorobenzene by the Synergistic Effect of Catalysts and Dielectric-Barrier Discharge Driven by Bipolar Pulse-Power

    Institute of Scientific and Technical Information of China (English)

    LI Duan; ZHANG Di; WU Yan; LI Jie; LI Guofeng

    2008-01-01

    In this study, the improvement in the removal of chlorobenzene (C6H5Cl) in the air was investigated by combining dielectric barrier discharge (DBD) driven by bipolar pulse-power with catalysts. Molecular sieve 4A (MS-4A) and MnO2/γ-Al2O3 (MnO2/ALP) as two kinds of catalysts were tested at different positions in a DBD reactor. Catalysts were located either in the discharging area between two electrodes, or just behind the discharging area (in the afterglow area) closed to the outlet. The results indicated that DBD reactor with a bipolar pulse power-supply produced strong instant discharge and energetic particles, which can effectively activate catalysts of MS-4A and MnO2/ALP located in the afterglow area to achieve the synergistic effects on effective fission of chemical bonds of chlorobenzene. It was considered that the gas-chlorobenzene and the chlorobenzene adsorbed on the catalysts were decomposed simultaneously.

  19. Synthesized High-Frequency Thyristor for Dielectric Barrier Discharge Excimer Lamps

    OpenAIRE

    2012-01-01

    International audience; Dielectric barrier discharge (DBD) lamps, being capacitive loads, must be associated with bidirectional current sources for an appropriate control of the transferred power. Pulsed current source supplies, which are known to offer very interesting performances, require specific power switches that are able to manage bidirectional voltage and unidirectional current at much higher frequencies (several hundreds of kilohertz) than commercial thyristors. This paper proposes t...

  20. OPTIMISATION OF DIELECTRIC BARRIER DISCHARGE PLASMA ACTUATORS AND THEIR APPLICATION TO FLUID DYNAMICS

    OpenAIRE

    Erfani, Rasool

    2012-01-01

    The standard dielectric barrier discharge (DBD) plasma actuator, in which an asymmetric arrangement of electrodes leads to momentum coupling into the surrounding air, has already demonstrated its capability for flow control. The effect of some parameters such as dielectric thickness, dielectric temperature, voltage amplitude, driving frequency, different configurations and arrangements on actuator performance are examined. The new configuration of DBD which uses multiple encapsulated electrod...

  1. Self-Organized Filaments in Dielectric Barrier Discharge in Air at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    DONG Li-Fang; LI Xue-Chen; YINZeng-Qian; QIAN Sheng-Fa; OUYANG Ji-Ting; WANG Long

    2001-01-01

    The self-organized filament pattern created by dielectric barrier discharges in air at atmospheric pressure is investigated experimentally. The density and dimension of filament are analysed quantitatively. The experimental results show that the distance between neighbouring filaments decreases with the increased applied voltage or with the decreased width of the gas gap. Also, the diameter of the filament decreases with the increased applied voltages or with the decreased width of the gas gap.

  2. Contraction of Surface Barrier Discharge at Positive and Negative Polarities in Atmospheric Air

    Science.gov (United States)

    Leonov, Sergey; Houpt, Alec

    2016-10-01

    This experimental study of surface dielectric barrier discharge examines the morphology and charge transfer dynamics depending on the supplied voltage pattern: single polarity vs alternating polarity. Diagnostics included electrical measurements, camera imaging, optical emission spectroscopy, and a set of original charge sensors. Two basic modes were analyzed: diffusive and filamentary. The key factor of the discharge dynamics is the development of ionization instability causing the contraction of the discharge current and formation of the filamentary, highly conductive plasma during both positive and negative polarities. A main criterion of the discharge contraction is the generation of a zone with a high level of longitudinal electric field, not less than 15 kV/cm, realized during the alternating of the sign of surface charge. It is shown that the alternating polarity of the supplied voltage accompanied with the process of discharge contraction gives a significant benefit in the surface area covered by the discharge and in the power deposition, increasing it 2-4 times. FlowPAC Institute, University of Notre Dame.

  3. Formation mechanism of dot-line square superlattice pattern in dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Weibo; Dong, Lifang, E-mail: donglfhbu@163.com, E-mail: pyy1616@163.com; Wang, Yongjie; Zhang, Xinpu [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); College of Quality and Technical Supervision, Hebei University, Baoding 071002 (China); Pan, Yuyang, E-mail: donglfhbu@163.com, E-mail: pyy1616@163.com [College of Quality and Technical Supervision, Hebei University, Baoding 071002 (China)

    2014-11-15

    We investigate the formation mechanism of the dot-line square superlattice pattern (DLSSP) in dielectric barrier discharge. The spatio-temporal structure studied by using the intensified-charge coupled device camera shows that the DLSSP is an interleaving of three different subpatterns in one half voltage cycle. The dot square lattice discharges first and, then, the two kinds of line square lattices, which form square grid structures discharge twice. When the gas pressure is varied, DLSSP can transform from square superlattice pattern (SSP). The spectral line profile method is used to compare the electron densities, which represent the amounts of surface charges qualitatively. It is found that the amount of surface charges accumulated by the first discharge of DLSSP is less than that of SSP, leading to a bigger discharge area of the following discharge (lines of DLSSP instead of halos of SSP). The spatial distribution of the electric field of the surface charges is simulated to explain the formation of DLSSP. This paper may provide a deeper understanding for the formation mechanism of complex superlattice patterns in DBD.

  4. Modeling of dielectric barrier discharge excimer lamp excited by mono polar voltage pulses

    Science.gov (United States)

    Akashi, Haruaki; Oda, Akinori; Sakai, Yosuke

    2007-10-01

    Filametal discharges in Dielectric Barrier Discharge (DBD) excimer lamp excited by mono polar voltage pulses has been simulated using two dimensional fluid model. And the differences of the filament discharges formations between mono polar case and bipolar case [1] have been examined. Xe gas was used and its pressure is 300Torr. Simulated region is 1cm (gap length) x 3cm (radial length). Periodical boundary conditions are assumed for the radial direction boundaries. The both electrodes are covered with dielectrics and their thickness is 0.2cm. Applied voltage is 5kV trapezoid shape with 50% duty ratio waveform and its repetition rate is 200kpps. First a small amount of electron-ion pair is provided in the middle of the gap for initial condition. Then the voltage starts to apply. In the case of bipolar excitation, the discharge starts from one filament (streamer discharge), and finally, 5 filaments are obtained self-consistently. In the case of mono polar case, as first, similar to bipolar case, the discharge starts from one filament, however, only 3 filaments have been obtained. This result is similar to that of 100kHz bipolar voltage case. [1] H. Akashi et al, IEEE Trans. Plasma Science, Vol.33, No.2 (2005) pp.308-309

  5. Tailored reforming of n-dodecane in an aqueous discharge reactor

    KAUST Repository

    Zhang, Xuming

    2016-03-24

    Here, we present an original technical approach to simultaneously produce a tailored synthetic liquid fuel and a syngas. In an aqueous discharge reactor with gaseous bubbles, we reformed an emulsified n-dodecane/water mixture. The higher dielectric permittivity of the mixture facilitates electrical discharges that cause the electron impact dissociation of n-dodecane into alkyl and hydrogen radicals, while the addition of water also provides a steam-reforming environment inside the discharged bubbles. We added methane and carbon dioxide to the system because they dissociate into methyl and oxygen radicals, respectively, which prevent the alkyl-alkyl recombinations that result in the formation of long-chain hydrocarbons (HCs). Thus, we were able to control product selectivity by adding methane to increase the production of short-chain HCs and hydrogen gas or by adding carbon dioxide to increase the production of oxygenated fuels, such as 1-dodecanol. Using gas chromatography and gas chromatography-mass spectrometry we detail the compositions of both the synthetic liquid and the syngas, and we provide conceptual chemical mechanisms to selectively increase the production of oxygenates and that of HCs that are shorter or longer than the base fuel. The basis of this in-liquid discharge for the purpose of fuel reforming has potential applications to advanced engines to control ignition delay time, a continuing focus of study in our lab. © 2016 IOP Publishing Ltd.

  6. EOIL power scaling in a 1-5 kW supersonic discharge-flow reactor

    Science.gov (United States)

    Davis, Steven J.; Lee, Seonkyung; Oakes, David B.; Haney, Julie; Magill, John C.; Paulsen, Dwane A.; Cataldi, Paul; Galbally-Kinney, Kristin L.; Vu, Danthu; Polex, Jan; Kessler, William J.; Rawlins, Wilson T.

    2008-02-01

    Scaling of EOIL systems to higher powers requires extension of electric discharge powers into the kW range and beyond with high efficiency and singlet oxygen yield. We have previously demonstrated a high-power microwave discharge approach capable of generating singlet oxygen yields of ~25% at ~50 torr pressure and 1 kW power. This paper describes the implementation of this method in a supersonic flow reactor designed for systematic investigations of the scaling of gain and lasing with power and flow conditions. The 2450 MHz microwave discharge, 1 to 5 kW, is confined near the flow axis by a swirl flow. The discharge effluent, containing active species including O II(a1Δ g, b1Σ g +), O( 3P), and O 3, passes through a 2-D flow duct equipped with a supersonic nozzle and cavity. I2 is injected upstream of the supersonic nozzle. The apparatus is water-cooled, and is modular to permit a variety of inlet, nozzle, and optical configurations. A comprehensive suite of optical emission and absorption diagnostics is used to monitor the absolute concentrations of O II(a), O II(b), O( 3P), O 3, I II, I(2P 3/2), I(2P 1/2), small-signal gain, and temperature in both the subsonic and supersonic flow streams. We discuss initial measurements of singlet oxygen and I* excitation kinetics at 1 kW power.

  7. Recirculation pump discharge line break tests at ROSA-III for a boiling water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, M.; Anoda, Y.; Kumamaru, H.; Nakamura, H.; Shiba, M.; Tasaka, K.

    1985-08-01

    Three loss-of-coolant accident (LOCA) tests were conducted at the Rig of Safety Assessment (ROSA)-III test facility, which simulates boiling water reactor (BWR)/6-251 with a volumetric scaling factor of 1/424. The fundamental features of the recirculation pump discharge line break LOCA and the effects of break areas on the features are investigated. It has been confirmed experimentally that the LOCA phenomena in the discharge line break are analogous to those in the suction line break with the same effective choking flow area, which is a sum of the least choking flow areas along the break flow paths and controls the system pressure responses. In general, the maximum effective choking flow area is (A /SUB j/ + A /SUB p/ ) for discharge line breaks and (A /SUB j/ + A /SUB o/ ) for suction line breaks, where A /SUB j/ , A /SUB p/ , and A /SUB o/ are the flow areas of the jet pump drive nozzles, the main recirculation pump discharge nozzle, and the break, respectively. The similarity between the ROSA-III test and a BWR LOCA has been confirmed in the key phenomena by the analyses using the RELAP5/MOD1 code. An atypical behavior is observed in the fuel rod surface temperature transient in the early phase of blowdown due to the limitation of the ROSA-III initial core power.

  8. Tailored reforming of n-dodecane in an aqueous discharge reactor

    Science.gov (United States)

    Zhang, Xuming; Cha, Min Suk

    2016-05-01

    Here, we present an original technical approach to simultaneously produce a tailored synthetic liquid fuel and a syngas. In an aqueous discharge reactor with gaseous bubbles, we reformed an emulsified n-dodecane/water mixture. The higher dielectric permittivity of the mixture facilitates electrical discharges that cause the electron impact dissociation of n-dodecane into alkyl and hydrogen radicals, while the addition of water also provides a steam-reforming environment inside the discharged bubbles. We added methane and carbon dioxide to the system because they dissociate into methyl and oxygen radicals, respectively, which prevent the alkyl-alkyl recombinations that result in the formation of long-chain hydrocarbons (HCs). Thus, we were able to control product selectivity by adding methane to increase the production of short-chain HCs and hydrogen gas or by adding carbon dioxide to increase the production of oxygenated fuels, such as 1-dodecanol. Using gas chromatography and gas chromatography-mass spectrometry we detail the compositions of both the synthetic liquid and the syngas, and we provide conceptual chemical mechanisms to selectively increase the production of oxygenates and that of HCs that are shorter or longer than the base fuel. The basis of this in-liquid discharge for the purpose of fuel reforming has potential applications to advanced engines to control ignition delay time, a continuing focus of study in our lab.

  9. Plasma chemistry in an atmospheric pressure Ar/NH3 dielectric barrier discharge

    DEFF Research Database (Denmark)

    Fateev, A.; Leipold, F.; Kusano, Y.

    2005-01-01

    An atmospheric pressure dielectric barrier discharge (DBD) in Ar/NH3 (0.1 - 10%) mixtures with a parallel plate electrode geometry was studied. The plasma was investigated by emission and absorption spectroscopy in the UV spectral range. Discharge current and voltage were measured as well. UV...... absorption spectroscopy was also employed for the detection of stable products in the exhaust gas. To clarify the different processes for ammonia decomposition, N-2(2 - 10%) was added to the plasma. Modeling of the chemical kinetics in an Ar/NH3 plasma was performed as well. The dominant stable products...... of an atmospheric pressure Ar/NH3 DBD are H-2, N-2 and N2H4. The hydrazine (N2H4) concentration in the plasma and in the exhaust gases at various ammonia concentrations and different discharge powers was measured. Thermal N2H4 decomposition into NH2 radicals may be used for NOx reduction processes....

  10. The impacts of magnetic field on repetitive nanosecond pulsed dielectric barrier discharge in air

    Science.gov (United States)

    Liu, Yidi; Qi, Haicheng; Fan, Zhihui; Yan, Huijie; Ren, ChunSheng

    2016-11-01

    In this paper, the impacts of the parallel magnetic field on the repetitive nanosecond pulsed dielectric barrier discharge (DBD) are experimentally investigated by optical and electrical measurements. The DBD is generated between two parallel-plate electrodes in the ambient air with the stationary magnetic field on the order of 1 T. The experimental results show that additional microdischarge channels are generated and the photocurrent intensity of the plasma is increased by the magnetic field. The microdischarge channels develop along the magnetic field lines and the diffuse background emission of the discharge is stronger in the DBD with the magnetic field. As the pulse repetition frequency decreases from 1200 Hz to 100 Hz, only the photocurrent intensity of the third discharge that occurred at about 500 ns is noticeably increased by the additional magnetic field. It is believed that the enhancement of the memory effect and the confinement of the magnetic field on electrons are the main reasons.

  11. Formation of positive ions in hydrocarbon containing dielectric barrier discharge plasmas

    Science.gov (United States)

    Mihaila, Ilarion; Pohoata, Valentin; Jijie, Roxana; Nastuta, Andrei Vasile; Rusu, Ioana Alexandra; Topala, Ionut

    2016-12-01

    Low temperature atmospheric pressure plasma devices are suitable experimental solutions to generate transitory molecular environments with various applications. In this study we present experimental results regarding the plasma chemistry of dielectric barrier discharges (DBD) in helium - hydrogen (0.1%) - hydrocarbons (1.2%) mixtures. Four types of hydrocarbon gases were studied: methane (CH4), ethane (C2H6), propane (C3H8), and butane (C4H10). Discharge diagnosis and monitoring was assured by electrical measurements and optical emission spectroscopy. Molecular beam mass spectrometry is engaged to sample positive ions populations from two different plasma sources. Dissociation and generation of higher-chain and cyclic (aromatic) hydrocarbons were discussed as a function of feed gas and discharge geometry. We found a strong influence of these parameters on both molecular mass distribution and recombination processes in the plasma volume.

  12. Single dielectric barrier discharge characteristics in needle-to-plane configuration

    Science.gov (United States)

    Emelyanov, O. A.; Shemet, M. V.

    2014-08-01

    Single dielectric barrier discharges (DBDs) in the ‘needle—submillimetric air gap—polymer barrier—plane’ configuration were investigated. The measurements of breakdown voltages, discharge current pulses, transferred charges and surface charge distributions for both needle polarities were conducted by the developed experimental setup. For the same gaps the breakdown voltage and the accumulated surface charge for the positive needle polarity are larger than the ones for the negative polarity. It is shown that the main contribution to the DBD current pulse and accumulated charge is determined by the surface phase of discharge process. Additionally the subsequent DBD development during one period of the applied voltage of triangular waveform was observed. The results indicate a ‘memory effect’ of the DBD development.

  13. Temperature characterization of dielectric barrier discharge actuators: influence of electrical and geometric parameters

    Science.gov (United States)

    Tirumala, Rakshit; Benard, Nicolas; Moreau, Eric; Fenot, Matthieu; Lalizel, Gildas; Dorignac, Eva

    2014-06-01

    Dielectric barrier discharge (DBD) based surface plasma actuators have been well studied as flow manipulation devices. However, there is a dearth of research on their application for convective heat transfer enhancement. The adoption of DBD actuators to such areas requires a detailed study on the thermal characteristics of the plasma discharge. The present study conducts infrared thermography measurements on the surface of a thick dielectric (2-4 mm) based DBD actuator and characterizes it against various electrical and geometrical parameters. The temperature distribution is also studied in relation to the regimes of the discharge cycle through comparison with intensified charge-coupled device (iCCD) imaging. Measurements are also conducted with thin cylindrical electrode (wire) based configurations to study the influence of streamer inhibition. Based on the observed experimental results, a hypothesis is proposed on the mechanism of dielectric heating and the relationship between dielectric surface temperature and gas temperature.

  14. Diffuse coplanar surface barrier discharge -- basic properties and its application in surface treatment of nonwovens

    Science.gov (United States)

    Kovacik, Dusan; Rahel, Jozef; Kubincova, Jana; Zahoranova, Anna; Cernak, Mirko

    2009-10-01

    In recent years, low temperature atmospheric pressure plasma surface treatments have become a hot topic because of the potential of fast and efficient in-line processing fabrication without expensive vacuum equipment. A major problem of atmospheric pressure treatment in air is insufficient treatment uniformity because, particularly at the higher plasma power densities, the air plasma has the tendency of filamentation and transition into an arc discharge. Diffuse coplanar surface barrier discharge (DCSBD) plasma source has been developed to overcome these problems. This type of discharge enables to generate macroscopically homogeneous thin (˜ 0.3 mm) plasma layer with power density of some 100 W/cm^3 practically in any gas without admixture of He. It was found that the ambient air plasma of DCSBD is capable to make lightweight polypropylene nonwoven fabrics permanently hydrophilic, without any pinholing and with low power consumption of some 1 kWh/kg.

  15. Simulated and experimental studies on the array dielectric barrier discharge of water electrodes

    Science.gov (United States)

    Lele, WANG; Xiutao, HUANG; Junfeng, CHEN; Shengming, WANG; Zhaoyang, HU; Minghai, LIU

    2017-03-01

    A kind of dielectric barrier discharge (DBD) device composed of water electrodes with 3 × 3 forms can produce large-area low-temperature plasmas at atmospheric pressure. To reflect the discharge characteristics of DBD better, a dynamic simulation model, which is based on the voltage controlled current source (CCS), is established, then the established model in Matlab/Simulink is used to simulate the DBD in air. The voltage–current waves and Lissajous at a voltage of 10 kV, 11 kV and 12 kV peak value with a frequency of 15 kHz are studied. The change of the discharge power of DBD with a different amplitude and frequency of applied voltage is also analyzed. The result shows the voltage–current waves, Lissajous and discharge power of DBD under different conditions from the simulation agree well with those of the experiment. In addition, we propose a method to calculate the dielectric barrier capacitance {{C}}{{d}} and the gap capacitance {{C}}{{g}}, which is valid through analyzing the variation of capacitance at different voltage amplitudes.

  16. Simulated and experimental studies on the array dielectric barrier discharge of water electrodes

    Science.gov (United States)

    Wang, Lele; Huang, Xiutao; Chen, Junfeng; Wang, Shengming; Hu, Zhaoyang; Liu, Minghai

    2017-03-01

    A kind of dielectric barrier discharge (DBD) device composed of water electrodes with 3 × 3 forms can produce large-area low-temperature plasmas at atmospheric pressure. To reflect the discharge characteristics of DBD better, a dynamic simulation model, which is based on the voltage controlled current source (CCS), is established, then the established model in Matlab/Simulink is used to simulate the DBD in air. The voltage-current waves and Lissajous at a voltage of 10 kV, 11 kV and 12 kV peak value with a frequency of 15 kHz are studied. The change of the discharge power of DBD with a different amplitude and frequency of applied voltage is also analyzed. The result shows the voltage-current waves, Lissajous and discharge power of DBD under different conditions from the simulation agree well with those of the experiment. In addition, we propose a method to calculate the dielectric barrier capacitance {{C}}{{d}} and the gap capacitance {{C}}{{g}}, which is valid through analyzing the variation of capacitance at different voltage amplitudes.

  17. Barriers to discharge in an acute care medical teaching unit: a qualitative analysis of health providers' perceptions.

    Science.gov (United States)

    Okoniewska, Barbara; Santana, Maria Jose; Groshaus, Horacio; Stajkovic, Svetlana; Cowles, Jennifer; Chakrovorty, David; Ghali, William A

    2015-01-01

    The complex process of discharging patients from acute care to community care requires a multifaceted interaction between all health care providers and patients. Poor communication in a patient's discharge can result in post hospital adverse events, readmission, and mortality. Because of the gravity of these problems, discharge planning has been emphasized as a potential solution. The purpose of this paper is to identify communication barriers to effective discharge planning in an acute care unit of a tertiary care center and to suggest solutions to these barriers. Health care providers provided comments to a single open-ended question: "What are the communication barriers between the different health care providers that limit an effective discharge of patients from Unit 36?" We conducted qualitative thematic analysis by identifying themes related to communication barriers affecting a successful discharge process. Three broad themes related to barriers to the discharge process were identified: communication, lack of role clarity and lack of resources. We also identified two themes for opportunities for improvement, ie, structure and function of the medical team and need for leadership. While it was evident that poor communication was an overarching barrier identified by health care providers, other themes emerged. In an effort to increase inter-team communication, "bullet rounds", a condensed form of discharge rounds, were introduced to the medical teaching unit and occurred on a daily basis between the multidisciplinary team. To help facilitate provider-patient communication, electronic transfer of care summaries were suggested as a potential solution. To help role clarity, a discharge coordinator and/or liaison was suggested. Communication can be enhanced through use of electronic discharge summaries, bullet rounds, and implementation of a discharge coordinator(s). The findings from this study can be used to aid future researchers in devising appropriate

  18. Characteristics of gas-liquid pulsed discharge plasma reactor and dye decoloration efficiency

    Institute of Scientific and Technical Information of China (English)

    Bing Sun; Nyein Nyein Aye; Zhiying Gao; Dan Lv; Xiaomei Zhu; Masayuki Sato

    2012-01-01

    The pulsed high-voltage discharge is a new advanced oxidation technology for water treatment.Methyl Orange (MO) dye wastewater was chosen as the target object.Some investigations were conducted on MO decoloration including the discharge characteristics of the multi-needle reactor,parameter optimization,and the degradation mechanism.The following results were obtained.The color group of the azo dye MO was effectively decomposed by water surface plasma.The decoloration rate was promoted with the increase of treatment time,peak voltage,and pulse frequency.When the initial conductivity was 1700 tS/cm,the decoloration rate was the highest.The optimum distahce between the needle electrodes and the water surface was 1 mm,the distance between the grounding electrode and the water surface was 28 mm,and the number of needle electrodes and spacing between needles were 24 and 7.5 mm,respectively.The decoloration rate of MO was affected by the gas in the reactor and varied in the order oxygen > air> argon > nitrogen,and the energy yield obtained in this investigation was 0.45 g/kWh.

  19. Physics parameter calculations for a Tandem Mirror Reactor with thermal barriers

    Energy Technology Data Exchange (ETDEWEB)

    Boghosian, B.M.; Lappa, D.A.; Logan, B.G.

    1979-11-06

    Thermal barriers are localized reductions in potential between the plugs and the central cell, which effectively insulate trapped plug electrons from the central cell electrons. By then applying electron heating in the plug, it is possible to obtain trapped electron temperatures that are much greater than those of the central cell electrons. This, in turn, effects an increase in the plug potential and central cell confinement with a concomitant decrease in plug density and injection power. Ions trapped in the barrier by collisions are removed by the injection of neutral beams directed inside the barrier cell loss cone; these beam neutrals convert trapped barrier ions to neutrals by charge exchange permitting their escape. We describe a zero-dimensional physics model for this type of reactor, and present some preliminary results for Q.

  20. Formation and characteristics of patterns in atmospheric-pressure radio-frequency dielectric barrier discharge plasma

    Science.gov (United States)

    Yang, Lizhen; Liu, Zhongwei; Mao, Zhiguo; Li, Sen; Chen, Qiang

    2017-01-01

    The patterns in radio-frequency dielectric barrier discharge (RF DBD) are studied at atmospheric pressure of argon (Ar) or helium (He) mixed with nitrogen (N2) gas. When a small amount of N2 is mixed with He or Ar gas, discharge patterns are formed. In a N2/He gas mixture, besides the filament discharge that forms patterns, a glow background discharge is also observed, whereas only the filament discharge forms patterns in a N2/Ar gas mixture. The resolution of the hexagonal pattern as a function of applied power and gas flow rate is then explored. On the basis of spatial-temporal images taken using an intensified charge-coupled device (ICCD), we find that there is no interleaving of two transient hexagon sublattices in N2/Ar or N2/He plasma in RF DBD patterns, which are totally different from those in which surface charges dominated in the mid-frequency DBD plasma. This supports our hypothesis that the bulk charges dominate the pattern formation in RF DBD.

  1. Silicon Carbide Semiconductor Surface Dielectric Barrier Discharge (SSDBD) Device for Turbulent Skin Friction Drag Reduction and Flow Control Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed research effort explores the use of a nanosecond pulse driven offset semiconducting surface dielectric barrier discharge (SSDBD) device for the control...

  2. 1D fluid model of the dielectric barrier discharge in chlorine

    Science.gov (United States)

    Avtaeva, Svetlana

    2016-09-01

    The 1D fluid model of the dielectric barrier discharge (DBD) in pure chlorine is developed. The discharge is excited in 8 mm gas gap between quartz dielectric layers of 2 mm thickness covered metallic electrodes. The source voltage US =U0 sin ωt with a frequency 100 kHz and amplitude 8 kV is applied to the electrodes. Chlorine pressure is varied from 15 to 100 Torr. At pressure of 15 Torr a breakdown appears with voltage drop across the discharge gap about 1 kV whereas at 100 Torr it appears with voltage drop about 2 kV. After the first current spike some lower current spikes are observes with chlorine pressure of 100 Torr and large in number current spikes of about identical magnitude are observed with the pressure of 15 Torr. The maximal current density at all pressures reaches about 4 mA/cm.2Total density of surface charge deposited on the electrodes during a half-cycle decreases with chlorine pressure because duration of the current spike discharge phase reduces with chlorine pressure. The average power density inputted in the discharge is 2.5-5.8 W/cm3 per a cycle. The Cl2 plasma is electronegative, the most abundant ions are Cl2+and Cl-. It is shown, that ions get about 95% of the discharge power as electrons get about 5% of the discharge power. 67-97% of the electron power is spending for dissociation and ionization of Cl2 molecules. Emission of Cl* atoms and Cl2*molecules is weak.

  3. Reactors

    CERN Document Server

    International Electrotechnical Commission. Geneva

    1988-01-01

    This standard applies to the following types of reactors: shunt reactors, current-limiting reactors including neutral-earthing reactors, damping reactors, tuning (filter) reactors, earthing transformers (neutral couplers), arc-suppression reactors, smoothing reactors, with the exception of the following reactors: small reactors with a rating generally less than 2 kvar single-phase and 10 kvar three-phase, reactors for special purposes such as high-frequency line traps or reactors mounted on rolling stock.

  4. Thermoluminescence study of the trapped charge at an alumina surface electrode in different dielectric barrier discharge regimes

    Energy Technology Data Exchange (ETDEWEB)

    Ambrico, P F; Ambrico, M; Dilecce, G; De Benedictis, S [Consiglio Nazionale delle Ricerche, Istituto di Metodologie Inorganiche e dei Plasmi UOS Bari-c/o Dipartimento di Chimica, Universita degli Studi di Bari ' Aldo Moro' , via Orabona, 4, 70126 Bari (Italy); Colaianni, A [Dipartimento di Geologia e Geofisica, Universita degli Studi di Bari ' Aldo Moro' , via Orabona, 4, 70126 Bari (Italy); Schiavulli, L, E-mail: paolofrancesco.ambrico@cnr.i [Dipartimento Interateneo di Fisica, Universita degli Studi di Bari ' Aldo Moro' , via Orabona, 4, 70126 Bari (Italy)

    2010-08-18

    In this study, the charge trapping effect in alumina dielectric surfaces has been deeply investigated by means of a dedicated dielectric barrier discharge apparatus in different discharge regimes and gas mixtures. This work further validates our previous findings in the case of air discharges in a filamentary regime. Long lasting charge trapping has been evidenced by ex situ thermoluminescence characterizations of alumina dielectric barrier plates exposed to a plasma. The density of trapped surface charges was found to be higher in the glow discharge with respect to pseudo-glow and filamentary regimes, and for all regimes the minimum trap activation temperature was 390 K and the trap energy was less than or around 1 eV. This implies that in the case of glow discharges a higher reservoir of electrons is present. Also, the effect was found to persist for several days after running the discharge.

  5. Carbon dioxide splitting in a dielectric barrier discharge plasma: a combined experimental and computational study.

    Science.gov (United States)

    Aerts, Robby; Somers, Wesley; Bogaerts, Annemie

    2015-02-01

    Plasma technology is gaining increasing interest for the splitting of CO2 into CO and O2 . We have performed experiments to study this process in a dielectric barrier discharge (DBD) plasma with a wide range of parameters. The frequency and dielectric material did not affect the CO2 conversion and energy efficiency, but the discharge gap can have a considerable effect. The specific energy input has the most important effect on the CO2 conversion and energy efficiency. We have also presented a plasma chemistry model for CO2 splitting, which shows reasonable agreement with the experimental conversion and energy efficiency. This model is used to elucidate the critical reactions that are mostly responsible for the CO2 conversion. Finally, we have compared our results with other CO2 splitting techniques and we identified the limitations as well as the benefits and future possibilities in terms of modifications of DBD plasmas for greenhouse gas conversion in general.

  6. Mechanism of Phase Transition from Liquid to Gas Under Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Wang, Qiuying; Li, Sen; Gu, Fan

    2010-10-01

    Liquid gasification phenomenon was observable in liquid-solid dielectric barrier discharge (DBD) experiments. Starting from classical thermodynamics, this study aimed at finding the reason of liquid gasification in the DBD experiments. Fluid statics and electrohydrodynamics were adopted to analyze the mechanism of phase transition from liquid to gas. The Sumoto effect was also employed to visually explain the change in the pressure of fluid due to the electric field. It was concluded from both theoretical analysis and experiment that the change in liquid pressure was a key factor causing liquid to gasify in DBD conditions. Furthermore, it was stressed that the liquid pressure was affected by many parameters including liquid permittivity, voltage, electric intensity, size of the discharge space and uniformity of the electric field distribution, etc. All of them affected DBD liquid gasification. The related results would provide useful theoretical evidence for multi-phase DBD applications.

  7. High frequency excitation waveform for efficient operation of a xenon excimer dielectric barrier discharge lamp

    Energy Technology Data Exchange (ETDEWEB)

    Beleznai, Sz; Mihajlik, G; Richter, P [Department of Atomic Physics, Budapest University of Technology and Economics, 3-9.Muegyetem rkp., Budapest H-1111 (Hungary); Maros, I; Balazs, L, E-mail: beleznai@dept.phy.bme.h [GE Consumer and Industrial-Lighting, 77 Vaci ut, Budapest H-1344 (Hungary)

    2010-01-13

    The application of a high frequency ({approx}2.5 MHz) burst (amplitude-modulated sinusoidal) excitation voltage waveform is investigated for driving a fluorescent dielectric barrier discharge (DBD) light source. The excitation waveform presents a novel method for generating spatially stable homogeneous Xe DBD possessing a high conversion efficiency from electrical energy to VUV Xe{sub 2}{sup *} excimer radiation ({approx}172 nm), even at a significantly higher electrical energy deposition than realized by pulsed excitation. Simulation and experimental results predict discharge efficiencies around 60%. Lamp efficacy above 74 lm W{sup -1} has been achieved. VUV emission and loss mechanisms are investigated extensively and the performance of burst and pulsed waveforms is compared both theoretically and experimentally.

  8. High frequency excitation waveform for efficient operation of a xenon excimer dielectric barrier discharge lamp

    Science.gov (United States)

    Beleznai, Sz; Mihajlik, G.; Maros, I.; Balázs, L.; Richter, P.

    2010-01-01

    The application of a high frequency (~2.5 MHz) burst (amplitude-modulated sinusoidal) excitation voltage waveform is investigated for driving a fluorescent dielectric barrier discharge (DBD) light source. The excitation waveform presents a novel method for generating spatially stable homogeneous Xe DBD possessing a high conversion efficiency from electrical energy to VUV Xe_{2}^{\\ast} excimer radiation (~172 nm), even at a significantly higher electrical energy deposition than realized by pulsed excitation. Simulation and experimental results predict discharge efficiencies around 60%. Lamp efficacy above 74 lm W-1 has been achieved. VUV emission and loss mechanisms are investigated extensively and the performance of burst and pulsed waveforms is compared both theoretically and experimentally.

  9. 2D simulations of short-pulsed dielectric barrier discharge xenon excimer lamp

    Energy Technology Data Exchange (ETDEWEB)

    Bogdanov, E.A.; Kudryavtsev, A.A. [St. Petersburg State University, St. Petersburg (Russian Federation); Arslanbekov, R.R. [CFD Research Corporation, Huntsville (United States)

    2006-07-01

    Self-consistent two-dimensional (2D) simulations of short-pulsed dielectric barrier discharge (DBD) in pure xenon have been performed. It is shown that during short current pulse the traversal inhomogeneity of the plasma parameters can be important only at the end of the current pulse as an edge effect close to the side walls. During the current pulse, the gap voltage drops until the ionization wave reaches the cathode so the current in the cathode sheath is the displacement current. This means that almost all of the absorbed power is deposited into excitation of xenon atoms and not to the ion heating in the cathode sheath as in the traditional glow discharges. This fact is one of the reasons of high efficiency of short-pulsed DBD. The developed model allows one to estimate the temporal position of the plasma-sheath boundary. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  10. Study on ozone treatment of soil for agricultural application of surface dielectric barrier discharge

    Science.gov (United States)

    Nagatomo, Takuya; Abiru, Tomoya; Mitsugi, Fumiaki; Ebihara, Kenji; Nagahama, Kazuhiro

    2016-01-01

    Recently, application of plasma technologies to the agricultural field has attracted much interest because residual pesticides and excessive nitrogen oxides contained in plants, soil, and groundwater have become a serious issue worldwide. Since almost all of the atmospheric discharge plasma generates ozone, the effects of ozone are among the key factors for their agricultural applications. We have proposed the use of ozone generated using surface barrier discharge plasma for soil disinfection or sterilization. In this work, the ozone consumption coefficient and diffusion coefficient in soil were measured by the ultraviolet absorption method. The pH(H2O) and amount of nitrogen nutrient in soil after ozone diffusion treatment were studied and plant growth was observed simultaneously. The effect of ozone treatment on the amount of DNA in soil was also investigated and compared with that determined from the obtained ozone consumption coefficient.

  11. Electron dynamics and plasma jet formation in a helium atmospheric pressure dielectric barrier discharge jet

    Energy Technology Data Exchange (ETDEWEB)

    Algwari, Q. Th. [Centre for Plasma Physics, School of Maths and Physics, Queen' s University Belfast, University Road, Belfast, Northern Ireland BT7 1NN (United Kingdom); Electronic Department, College of Electronics Engineering, Mosul University, Mosul 41002 (Iraq); O' Connell, D. [Centre for Plasma Physics, School of Maths and Physics, Queen' s University Belfast, University Road, Belfast, Northern Ireland BT7 1NN (United Kingdom); York Plasma Institute, Department of Physics, University of York, York YO10 5DD (United Kingdom)

    2011-09-19

    The excitation dynamics within the main plasma production region and the plasma jets of a kHz atmospheric pressure dielectric barrier discharge (DBD) jet operated in helium was investigated. Within the dielectric tube, the plasma ignites as a streamer-type discharge. Plasma jets are emitted from both the powered and grounded electrode end; their dynamics are compared and contrasted. Ignition of these jets are quite different; the jet emitted from the powered electrode is ignited with a slight time delay to plasma ignition inside the dielectric tube, while breakdown of the jet at the grounded electrode end is from charging of the dielectric and is therefore dependent on plasma production and transport within the dielectric tube. Present streamer theories can explain these dynamics.

  12. Growth of Fluorocarbon Films by Low-Pressure Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    LI Wei; TAN Xiaodong; LIU Dongping; LIU Yanhong; FENG Zhiqing; CHEN Baoxiang

    2008-01-01

    Plasma polymerized fluorocarbon (FC) films have been deposited on silicon sub-strates from dielectric barrier discharge (DBD) plasma of C4Fs at room temperature under a pressure of 25~125 Pa. The effects of the discharge pressure and frequency of power supply on the films have been systematically investigated. FC films with a less cross linked structure may be formed at a relatively high pressure. Increase in the frequency of power supply leads to a signifi-cant increase in the deposition rate. Static contact angle measurements show that deposited FC films have a stable, hydrophobic surface property. All deposited films show smooth surfaces with an atomic surface roughness. The relationship between plasma parameters and the properties of the deposited FC films are discussed.

  13. Reel-to-Reel Atmospheric Pressure Dielectric Barrier Discharge (DBD Plasma Treatment of Polypropylene Films

    Directory of Open Access Journals (Sweden)

    Lukas JW Seidelmann

    2017-03-01

    Full Text Available Atmospheric pressure plasma treatment of the surface of a polypropylene film can significantly increase its surface energy and, thereby improve the printability of the film. A laboratory-scale dielectric barrier discharge (DBD system has therefore been developed, which simulates the electrode configuration and reel-to-reel web transport mechanism used in a typical industrial-scale system. By treating the polypropylene in a nitrogen discharge, we have shown that the water contact angle could be reduced by as much as 40° compared to the untreated film, corresponding to an increase in surface energy of 14 mNm−1. Ink pull-off tests showed that the DBD plasma treatment resulted in excellent adhesion of solvent-based inks to the polypropylene film.

  14. Degradation of Organic Compounds by Active Species Sprayed in a Dielectric Barrier Corona Discharge System

    Institute of Scientific and Technical Information of China (English)

    LI Jie; SONG Ling; LIU Qiang; QU Guangzhou; LI Guofeng; WU Yan

    2009-01-01

    Investigation was made into the degradation of organic compounds by a dielectric barrier corona discharge (DBCD) system. The DBCD, consisting of a quartz tube, a concentric high voltage electrode and a net wrapped to the external wall (used as ground electrode), was introduced to generate active species which were sprayed into the organic solution through an aerator fixed on the bottom of the tube. The effect of four factors-the discharge voltage, gas flow rate, solution conductivity, and pH of wastewater, on the degradation efficiency of phenol was assessed. The obtained results demonstrated that this process was an effective method for phenol degradation. The degradation rate was enhanced with the increase in power supplied. The degradation efficiency in alkaline conditions was higher than those in acid and neutral conditions.The optimal gas flow rate for phenol degradation in the system was 1.6 L/min, while the solution conductivity had little effect on the degradation.

  15. A sensitive gas chromatography detector based on atmospheric pressure chemical ionization by a dielectric barrier discharge.

    Science.gov (United States)

    Kirk, Ansgar T; Last, Torben; Zimmermann, Stefan

    2017-02-03

    In this work, we present a novel concept for a gas chromatography detector utilizing an atmospheric pressure chemical ionization which is initialized by a dielectric barrier discharge. In general, such a detector can be simple and low-cost, while achieving extremely good limits of detection. However, it is non-selective apart from the use of chemical dopants. Here, a demonstrator manufactured entirely from fused silica capillaries and printed circuit boards is shown. It has a size of 75×60×25mm(3) and utilizes only 2W of power in total. Unlike other known discharge detectors, which require high-purity helium, this detector can theoretically be operated using any gas able to form stable ion species. Here, purified air is used. With this setup, limits of detection in the low parts-per-billion range have been obtained for acetone.

  16. Roughness modification of surfaces treated by a pulsed dielectric barrier discharge

    CERN Document Server

    Dumitrascu, N; Apetroaei, N; Popa, G

    2002-01-01

    Local modifications of surface roughness are very important in many applications, as this surface property is able to generate new mechano-physical characteristics of a large category of materials. Roughness is one of the most important parameters used to characterize and control the surface morphology, and techniques that allow modifying and controlling the surface roughness present increasing interest. In this respect we propose the dielectric barrier discharge (DBD) as a simple and low cost method that can be used to induce controlled roughness on various surfaces in the nanoscale range. DBD is produced in helium, at atmospheric pressure, by a pulsed high voltage, 28 kV peak to peak, 13.5 kHz frequency and 40 W power. This type of discharge is a source of energy capable of modifying the physico-chemical properties of the surfaces without affecting their bulk properties. The discharge is characterized by means of electrical probes and, in order to analyse the heat transfer rate from the discharge to the tre...

  17. Formation of microdischarges inside a mesoporous catalyst in dielectric barrier discharge plasmas

    Science.gov (United States)

    Zhang, Ya; Wang, Hong-yu; Zhang, Yu-ru; Bogaerts, Annemie

    2017-05-01

    The formation process of a microdischarge (MD) in both μm- and nm-sized catalyst pores is simulated by a two-dimensional particle-in-cell/Monte Carlo collision model. A parallel-plate dielectric barrier discharge configuration in filamentary mode is considered in ambient air. The discharge is powered by a high voltage pulse. Our calculations reveal that a streamer can penetrate into the surface features of a porous catalyst and MDs can be formed inside both μm- and nm-sized pores, yielding ionization inside the pore. For the μm-sized pores, the ionization mainly occurs inside the pore, while for the nm-sized pores the ionization is strongest near and inside the pore. Thus, enhanced discharges near and inside the mesoporous catalyst are observed. Indeed, the maximum values of the electric field, ionization rate and electron density occur near and inside the pore. The maximum electric field and electron density inside the pore first increase when the pore size rises from 4 nm to 10 nm, and then they decrease for the 100 nm pore, due to a more pronounced surface discharge for the smaller pores. However, the ionization rate is highest for the 100 nm pore due to the largest effective ionization region.

  18. Effects of oxygen concentration on atmospheric pressure dielectric barrier discharge in Argon-Oxygen Mixture

    Science.gov (United States)

    Li, Xuechun; Li, Dian; Wang, Younian

    2016-09-01

    A dielectric barrier discharge (DBD) can generate a low-temperature plasma easily at atmospheric pressure and has been investigated for applications in trials in cancer therapy, sterilization, air pollution control, etc. It has been confirmed that reactive oxygen species (ROS) play a key role in the processes. In this work, we use a fluid model to simulate the plasma characteristics for DBD in argon-oxygen mixture. The effects of oxygen concentration on the plasma characteristics have been discussed. The evolution mechanism of ROS has been systematically analyzed. It was found that the ground state oxygen atoms and oxygen molecular ions are the dominated oxygen species under the considered oxygen concentrations. With the oxygen concentration increasing, the densities of electrons, argon atomic ions, resonance state argon atoms, metastable state argon atoms and excited state argon atoms all show a trend of decline. The oxygen molecular ions density is high and little influenced by the oxygen concentration. Ground state oxygen atoms density tends to increase before falling. The ozone density increases significantly. Increasing the oxygen concentration, the discharge mode begins to change gradually from the glow discharge mode to Townsend discharge mode. Project supported by the National Natural Science Foundation of China (Grant No. 11175034).

  19. Formation of striations in large-gap coplanar dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Xiaofei [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); He, Feng, E-mail: hefeng@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Ouyang, Jiting [School of Physics, Beijing Institute of Technology, Beijing 100081 (China)

    2012-06-04

    Striations in a large-gap coplanar dielectric barrier discharge (DBD) have been investigated by experiment and numerical simulation. The discharge current was measured and the images of infra-red (IR) radiation striation were obtained by an intensified charge-coupled device (ICCD) camera with nanosecond exposure time. The discharge processes are simulated by particle-in-cell/Monte Carlo collision (PIC/MCC) code. The calculated current and the distribution of Xe{sup ⁎} during a single pulse were compared with the experiment. The results show that there are two series of striations corresponding to two stages of discharge. The striations of the second stage are generated as the potential changed remarkably, while the distribution of surface charge almost keeps unchanged. The electric field induced by the space charges plays a key role in the formation of the striations. The stratified wall charge is only a consequence of the stratified spatial field and the striations. -- Highlights: ► IR radiation images of striations were compared with PIC/MCC simulation results. ► Space charge plays a key role in striation formation. ► Stratified wall charge is considered as a consequence of the striations.

  20. Evolution of nanosecond surface dielectric barrier discharge for negative polarity of a voltage pulse

    Science.gov (United States)

    Soloviev, V. R.; Krivtsov, V. M.; Shcherbanev, S. A.; Starikovskaia, S. M.

    2017-01-01

    Surface dielectric barrier discharge, initiated by a high-voltage pulse of negative polarity in atmospheric pressure air, is studied numerically and experimentally. At a pulse duration of a few tens of nanoseconds, two waves of optical emission propagate from the high-voltage electrode corresponding to the leading and trailing edges of the high-voltage pulse. It is shown by means of numerical modeling that a glow-like discharge slides along the surface of the dielectric at the leading edge of the pulse, slowing down on the plateau of the pulse. When the trailing edge of the pulse arrives to the high-voltage electrode, a second discharge starts and propagates in the same direction. The difference is that the discharge corresponding to the trailing edge is not diffuse and demonstrates a well-pronounced streamer-like shape. The 2D (in numerical modeling) streamer propagates above the dielectric surface, leaving a gap of about 0.05 mm between the streamer and the surface. The calculated and experimentally measured emission picture, waveform of the electrical current, and deposited energy, qualitatively coincide. The sensitivity of the numerical solution to unknown physical parameters of the model is discussed.

  1. Methane Conversion Using Dielectric Barrier Discharge: Comparison with Thermal Process and Catalyst Effects

    Institute of Scientific and Technical Information of China (English)

    Antonius Indarto; Jae-Wook Choi; Hwaung Lee; Hyung Keun Song

    2006-01-01

    The direct conversion of methane using a dielectric barrier discharge has been experimentally studied. Experiments with different values of flow rates and discharge voltages have been performed to investigate the effects on the conversion and reaction products both qualitatively and quantitatively.Experimental results indicate that the maximum conversion of methane has been 80% at an input flow rate of 5 ml/min and a discharge voltage of 4 kV. Experimental results also show that the optimum condition has occurred at a high discharge voltage and higher input flow rate. In terms of product distribution, a higher flow rate or shorter residence time can increase the selectivity for higher hydrocarbons. No hydrocarbon product was detected using the thermal method, except hydrogen and carbon. Increasing selectivity for ethane was found when Pt and Ru catalysts presented in the plasma reaction. Hydrogenation of acetylene in the catalyst surface could have been the reason for this phenomenon as the selectivity for acetylene in the products was decreasing.

  2. High-Pressure Plasma Deposition of a-C:H Films by Dielectric-Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    刘昌俊; 李阳; 杜海燕; 艾宝都

    2003-01-01

    The fabrication of a-C:H films from methane has been performed using dielectric-barrier discharges at atmospheric pressure. The effect of combined-feed gas, such as carbon dioxide,carbon monoxide or acetylene on the formation of a-C:H films has been investigated. It hasbeen demonstrated that the addition of carbon monoxide or acetylene into methane leads to aremarkable improvement in the fabrication of a-C:H films. The characterization of carbon filmobtained has been conducted using FT-IR, Raman and SEM.

  3. In situ encapsulation of copper nanoparticles by the dielectric barrier discharge

    Science.gov (United States)

    Lei, Haile; Tang, Yongjian; Li, Jun; Luo, Jiangshan; Zhang, Jingmin

    2007-09-01

    An experimental investigation is reported on in situ encapsulating copper nanoparticles with a nanolayer of hydrocarbon coating. Copper nanoparticles produced by the flow-levitation method are in situ encapsulated by the dielectric barrier discharge, which generates carbon and hydrogen plasmas for forming a polymerized nanolayer of hydrocarbon at the surface of Cu nanoparticles. The structural, chemical components and optical properties of the encapsulated Cu nanoparticles are characterized by transmission electron microscopy, energy dispersive x-ray spectra, x-ray diffraction, x-ray photoelectron spectra, and UV-visible absorption.

  4. Direct plasma NOx reduction using single surface dielectric barrier discharge

    DEFF Research Database (Denmark)

    Kroushawi, Feisal; Stamate, Eugen

    2014-01-01

    NOx reduction using direct atmospheric barrier discharge in air-NO mixture at different voltages and flow rates is inversigated. Reduction rate of 80% is achieved at 3.18 W/cm2 power density and gas mixture of 20 slm air and 0.006 slm NO. The ozone for NO reduction is produced by a honeycomb...... structured DBD with a total surface of 12.56 cm2. The reduction process is investigated by FTIR spectroscopy, chemiluminsecence, mass spectrometry and optical emission spectroscopy....

  5. Low-temperature sterilization of wrapped materials using flexible sheet-type dielectric barrier discharge

    Science.gov (United States)

    Eto, Hiroyuki; Ono, Yoshihito; Ogino, Akihisa; Nagatsu, Masaaki

    2008-12-01

    A flexible sheet-type dielectric barrier discharge (DBD) was studied for the low-temperature sterilization of medical instruments wrapped with Tyvek packaging. Sterilization experiments using Geobacillus stearothermophilus spores with a population of 106 were carried out with various mixtures of nitrogen and oxygen. We confirmed the inactivation of spores after 4.5 min of DBD irradiation at a temperature of 28.4 °C and relative humidity of 64.4%. The main sterilizing factors of this method are the ozone and UV emissions generated by DBD in dry air and synergistic OH radicals generated by DBD in moist air.

  6. Dielectric barrier discharge ionization in characterization of organic compounds separated on thin-layer chromatography plates.

    Science.gov (United States)

    Cegłowski, Michał; Smoluch, Marek; Babij, Michał; Gotszalk, Teodor; Silberring, Jerzy; Schroeder, Grzegorz

    2014-01-01

    A new method for on-spot detection and characterization of organic compounds resolved on thin layer chromatography (TLC) plates has been proposed. This method combines TLC with dielectric barrier discharge ionization (DBDI), which produces stable low-temperature plasma. At first, the compounds were separated on TLC plates and then their mass spectra were directly obtained with no additional sample preparation. To obtain good quality spectra the center of a particular TLC spot was heated from the bottom to increase volatility of the compound. MS/MS analyses were also performed to additionally characterize all analytes. The detection limit of proposed method was estimated to be 100 ng/spot of compound.

  7. Phase resolved analysis of the homogeneity of a diffuse dielectric barrier discharge

    Science.gov (United States)

    Baldus, Sabrina; Kogelheide, Friederike; Bibinov, Nikita; Stapelmann, Katharina; Awakowicz, Peter

    2015-09-01

    Cold atmospheric pressure plasmas have already proven their ability of supporting the healing process of chronic wounds. Especially simple configurations like a dielectric barrier discharge (DBD), comprising of one driven electrode which is coated with a dielectric layer, are of interest, because they are cost-effective and easy to handle. The homogeneity of such plasmas during treatment is necessary since the whole wound should be treated evenly. In this investigation phase resolved optical emission spectroscopy is used to investigate the homogeneity of a DBD. Electron densities and reduced electric field distributions are determined with temporal and spatial resolution and the differences for applied positive and negative voltage pulses are studied.

  8. Conversion from Dimethyl Ether to Dimethoxymethane and Dimethoxyethane Using Dielectric-Barrier Discharge Plasma

    Institute of Scientific and Technical Information of China (English)

    Wang Yu; Liu Changjun; Zhang Yueping

    2005-01-01

    Experimental investigation was conducted to convert dimethyl ether (DME) in thepresence of steam using dielectric barrier discharge (DBD) at atmospheric pressure and 373 K.The flow rate of DME was 20 ml/min. The introduction of steam resulted in an increase in theDME conversion and the selectivity of oxygenates. Plasma steam-enhanced dimethyl ether (DME)conversion led to a direct synthesis of DMMT and DMET, with a high selectivity of 5.78% and17.99%, respectively. The addition of steam promoted the formation of "plasma aerosol" that wasfavored for the formation of liquid oxygenates. The reaction pathway of plasma DME conversionwas proposed.

  9. Thermal behavior of bovine serum albumin after exposure to barrier discharge helium plasma jet

    Science.gov (United States)

    Jijie, R.; Pohoata, V.; Topala, I.

    2012-10-01

    Non-thermal plasma jets at atmospheric pressure are useful tools nowadays in plasma medicine. Various applications are tested such as cauterization, coagulation, wound healing, natural and artificial surfaces decontamination, and sterilization. In order to know more about the effects of gas plasma on biological supramolecules, we exposed protein powders to a barrier discharge helium plasma jet. Then, spectroscopic investigations were carried out in order to obtain information on protein secondary, tertiary, and quaternary structures. We obtained a reduction of the protein alpha-helix content after the plasma exposure and a different behavior, for both thermal denaturation/renaturation kinetics and thermal aggregation process.

  10. [Study of a wire-to-plate positive pulsed corona discharge reactor by emission spectroscopy].

    Science.gov (United States)

    Wang, Shen-Bing; Luo, Zhong-Yang; Zhao, Lei; Xuan, Jian-Yong; Jiang, Jian-Ping; Cen, Ke-Fa

    2011-11-01

    In order to get extensive knowledge of wire-to-plate pulsed corona discharge reactor, the influences of different diameters of wire electrode, different wire-to-plate and wire-to-wire spacing on OH radical generation were experimentally investigated under atmospheric pressure based on emission spectrum, and the spatial distribution of OH radicals in the electric field was also discussed in detail The results showed that OH radicals decrease along the X-axis, and the activation radius is approximately 20 mm; showing a trend of first increase and then decrease along the Y-axis, with the activation radius being more than 30 mm. OH radical has small change as the diameter of wire electrode changes below 2 mm, with a sharp decline as the diameter continues to increase. OH radical emission intensity increases as wire-to-wire spacing increases and decrease as wire-to-plate spacing increases.

  11. Barriers to discharge in an acute care medical teaching unit: a qualitative analysis of health providers’ perceptions

    Directory of Open Access Journals (Sweden)

    Okoniewska B

    2015-02-01

    Full Text Available Barbara Okoniewska,1 Maria Jose Santana,1 Horacio Groshaus,2 Svetlana Stajkovic,3 Jennifer Cowles,4 David Chakrovorty,5 William A Ghali1 1Department of Community Health Sciences, W21C Research and Innovation Centre, Institute of Public Health, 2Department of Internal Medicine, University of Calgary, 3Community Based Practice, 4Foothills Medical Centre, 5Department of Quality and Healthcare Improvement, Alberta Health Services, Calgary, AB, Canada Background: The complex process of discharging patients from acute care to community care requires a multifaceted interaction between all health care providers and patients. Poor communication in a patient’s discharge can result in post hospital adverse events, readmission, and mortality. Because of the gravity of these problems, discharge planning has been emphasized as a potential solution. The purpose of this paper is to identify communication barriers to effective discharge planning in an acute care unit of a tertiary care center and to suggest solutions to these barriers. Methods: Health care providers provided comments to a single open-ended question: “What are the communication barriers between the different health care providers that limit an effective discharge of patients from Unit 36?” We conducted qualitative thematic analysis by identifying themes related to communication barriers affecting a successful discharge process. Results: Three broad themes related to barriers to the discharge process were identified: communication, lack of role clarity and lack of resources. We also identified two themes for opportunities for improvement, ie, structure and function of the medical team and need for leadership. Conclusion: While it was evident that poor communication was an overarching barrier identified by health care providers, other themes emerged. In an effort to increase inter-team communication, “bullet rounds”, a condensed form of discharge rounds, were introduced to the medical

  12. Experimental Study on Inactivation of Bacterial Endotoxin by Using Dielectric Barrier Discharge%Experimental Study on Inactivation of Bacterial Endotoxin by Using Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    石兴民; 李娅西; 张冠军; 马跃; 邵先军

    2011-01-01

    The low-temperature plasma (LTP) generated by dielectric barrier discharge (DBD) was used to sterilize the E.coli endotoxin, which is usually difficult to kill by traditional methods. Three different concentrations of bacterial endotoxin (1 EU/mL, 0.5 EU/mL and 0.25 EU/mL) were treated by LTP for different time (20 s, 40 s and 60 s). Tachypleus amebocyte lysate (TAL) method was employed to detect the concentration variation of bacterial endotoxin before and af- ter the plasma treatment, and endotoxic shock mice model was used to evaluate the inactivation effects of LTP on endotoxin for further study. Experimental results demonstrated that, DBD plasma can inactivate the bacterial endotoxin quickly and effectively, and when the LTP treatment time was increased, the concentrations of bacterial endotoxin decreased gradually (after 60 s plasma treatment, its inactivation effect was beyond the Chinese pharmacopoeia standard), and the average survival time of mice gradually extended. The possible inactivation mechanisms are proposed to be related to reactive oxygen species (ROSs).

  13. Particle Densities of the Atmospheric-Pressure Argon Plasmas Generated by the Pulsed Dielectric Barrier Discharges

    Science.gov (United States)

    Pan, Jie; Li, Li; Wang, Yunuan; Xiu, Xianwu; Wang, Chao; Song, Yuzhi

    2016-11-01

    Atmospheric-pressure argon plasmas have received increasing attention due to their high potential in many industrial and biomedical applications. In this paper, a 1-D fluid model is used for studying the particle density characteristics of the argon plasmas generated by the pulsed dielectric barrier discharges. The temporal evolutions of the axial particle density distributions are illustrated, and the influences of changing the main discharge conditions on the averaged particle densities are researched by independently varying the various discharge conditions. The calculation results show that the electron density and the ion density reach two peaks near the momentary cathodes during the rising and the falling edges of the pulsed voltage. Compared with the charged particle densities, the densities of the resonance state atom Arr and the metastable state atom Arm have more uniform axial distributions, reach higher maximums and decay more slowly. During the platform of the pulsed voltage and the time interval between the pulses, the densities of the excited state atom Ar* are far lower than those of the Arr or the Arm. The averaged particle densities of the different considered particles increase with the increases of the amplitude and the frequency of the pulsed voltage. Narrowing the discharge gap and increasing the relative dielectric constant of the dielectric also contribute to the increase of the averaged particle densities. The effects of reducing the discharge gap distance on the neutral particle densities are more significant than the influences on the charged particle densities. supported by Natural Science Foundation of Shandong Province, China (No. ZR2015AQ008), and Project of Shandong Province Higher Educational Science and Technology Program of China (No. J15LJ04)

  14. Non-thermal dielectric-barrier discharge plasma damages human keratinocytes by inducing oxidative stress

    Science.gov (United States)

    KIM, KI CHEON; PIAO, MEI JING; HEWAGE, SUSARA RUWAN KUMARA MADDUMA; HAN, XIA; KANG, KYOUNG AH; JO, JIN OH; MOK, YOUNG SUN; SHIN, JENNIFER H.; PARK, YEUNSOO; YOO, SUK JAE; HYUN, JIN WON

    2016-01-01

    The aim of this study was to identify the mechanisms through which dielectric-barrier discharge plasma damages human keratinocytes (HaCaT cells) through the induction of oxidative stress. For this purpose, the cells were exposed to surface dielectric-barrier discharge plasma in 70% oxygen and 30% argon. We noted that cell viability was decreased following exposure of the cells to plasma in a time-dependent manner, as shown by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay. The levels of intracellular reactive oxygen species (ROS) were determined using 2′,7′-dichlorodihydro-fluorescein diacetate and dihydroethidium was used to monitor superoxide anion production. Plasma induced the generation of ROS, including superoxide anions, hydrogen peroxide and hydroxyl radicals. N-acetyl cysteine, which is an antioxidant, prevented the decrease in cell viability caused by exposure to plasma. ROS generated by exposure to plasma resulted in damage to various cellular components, including lipid membrane peroxidation, DNA breaks and protein carbonylation, which was detected by measuring the levels of 8-isoprostane and diphenyl-1-pyrenylphosphine assay, comet assay and protein carbonyl formation. These results suggest that plasma exerts cytotoxic effects by causing oxidative stress-induced damage to cellular components. PMID:26573561

  15. Nanosecond pulsed dielectric barrier discharge plasma-catalytic removal of HCHO in humid air

    Science.gov (United States)

    Zhang, Shuai; Wang, Wenchun; Zhang, Li; Zhao, Zilu; Yang, Dezheng

    2017-05-01

    Non-thermal plasma (NTP) has been regarded as a promising method for the removal of a wide range of low concentration volatile organic compounds (VOCs). In this paper, nanosecond pulsed and alternating current dielectric barrier discharge plasmas synergistic catalyst are utilized for removal of formaldehyde (HCHO) in humid air. Working gas is 1% H2O/21% O2/78% N2 with 154 ppm HCHO over total flow rate of 50 mL/min. Specific energy density (SED) are 32.5 JL-1, 35.8 JL-1 and 1069.2 JL-1 at power consumption of 0.325 W, 0.3 W, 8.9 W for removal of 67%, 63.8% and 73.8% HCHO when using bipolar nanosecond pulsed, unipolar nanosecond pulsed and AC dielectric barrier discharge (DBD) plasma, respectively. The removal efficiencies of HCHO using nanosecond pulsed DBD plasma increase approximately 10 20% when the packed-bed Al2O3 pellets exist and can reach up to almost 100% when TiO2 nanoparticles are used while the effect of CeO2 nanoparticles is a bit poor. Analysis indicate that OH radical and O atom play main role for removal HCHO and the gas temperature is a significant factor for its influence on rate constants of HCHO with active particles.

  16. ANTIMICROBIAL TEXTILE PREPARED BY SILVER DEPOSITION ON DIELECTRIC BARRIER DISCHARGE TREATED COTTON/POLYESTER FABRIC

    Directory of Open Access Journals (Sweden)

    Mirjana Kostić

    2008-11-01

    Full Text Available The objective of this research was to impart the additional value on cotton//polyester (Co/PES fabrics (i.e. antimicrobial properties to improve the quality of life and thus to tap new markets with the product. In this paper, silver ions were incorporated in Co/PES fabrics by chemisorptions into the fabric previously treated in a dielectric barrier discharge (DBD. A series of the DBD fabric treatments were done in order to determine the most suitable experimental conditions for the DBD activation of the fabric surface, while the optimal conditions for silver ions sorption by Co/PES fabrics were determined by changing sorption conditions. The antimicrobial Co/PES fabrics prepared by dielectric barrier discharge mediated silver deposition show an antimicrobial activity against tested pathogens: S. aureus, E. coli, and C. albicans under in vitro conditions. The obtained results confirm the practicability of the plasma modification process and furthermore show that with some delays in the next step, i.e. silver ion sorption, we can get the increase in the amount of the sorbed silver ions; the maximum sorption capacity of modified Co/PES fabrics was 0.135 mmol of Ag+ ions per gram of a fabric.

  17. Ozone Production With Dielectric Barrier Discharge: Effects of Power Source and Humidity

    KAUST Repository

    Zhang, Xuming

    2016-08-24

    Ozone synthesis in air dielectric barrier discharge (DBD) was studied with an emphasis on the effects of power sources and humidity. Discharge characteristics were investigated to understand the physical properties of plasma and corresponding system performance. It was found that 10-ns pulsed DBD produced a homogeneous discharge mode, while ac DBD yielded an inhomogeneous pattern with many microdischarge channels. At a similar level of the energy density (ED), decreasing the flowrate is more effective in the production of ozone for the cases of the ac DBD, while increased voltage is more effective for the pulsed DBD. Note that the maximum ozone production efficiency (110 g/kWh) was achieved with the pulsed DBD. At the ED of ∼ 85 J/L, the ozone concentrations with dry air were over three times higher than those with the relative humidity of 100% for both the ac DBD and pulsed DBD cases. A numerical simulation was conducted using a global model to understand a detailed chemical role of water vapor to ozone production. It was found HO and OH radicals from water vapor significantly consumed O atoms, resulting in a reduction in ozone production. The global model qualitatively captured the experimental trends, providing further evidence that the primary effect of humidity on ozone production is chemical in nature.

  18. Research on the degradation mechanism of pyridine in drinking water by dielectric barrier discharge.

    Science.gov (United States)

    Li, Yang; Yi, Rongjie; Yi, Chengwu; Zhou, Biyun; Wang, Huijuan

    2017-03-01

    Pyridine, an important chemical raw material, is widely used in industry, for example in textiles, leather, printing, dyeing, etc. In this research, a dielectric barrier discharge (DBD) system was developed to remove pyridine, as a representative type of nitrogen heterocyclic compound in drinking water. First, the influence of the active species inhibitors tertiary butanol alcohol (TBA), HCO3(-), and CO3(2-) on the degradation rate of pyridine was investigated to verify the existence of active species produced by the strong ionization discharge in the system. The intermediate and final products generated in the degradation process of pyridine were confirmed and analyzed through a series of analytical techniques, including liquid chromatography-mass spectrometry (LC-MS), high performance liquid chromatography (HPLC), ion chromatography (IC), total organic carbon (TOC) analysis, ultraviolet (UV) spectroscopy, etc. The results showed that the degradation of pyridine was mainly due to the strong oxidizing power of ozone and hydroxyl radical produced by the DBD system. Several intermediate products including 3-hydroxyl pyridine, fumaric acid, 2, 3-dihydroxypyridine, and oxalic acid were detected. Nitrogen was removed from the pyridine molecule to form nitrate. Through analysis of the degradation mechanism of pyridine, the oxidation pathway was deduced. The study provided a theoretical and experimental basis for the application of DBD strong ionization discharge in treatment of nitrogen heterocyclic compounds in drinking water. Copyright © 2016. Published by Elsevier B.V.

  19. Electrical and kinetical aspects of homogeneous dielectric-barrier discharge in xenon for excimer lamps

    Science.gov (United States)

    Belasri, A.; Harrache, Z.

    2010-12-01

    A pulsed dielectric-barrier discharge in xenon has been simulated for operating conditions typical to excimer lamps, in which the discharge is considered spatially homogeneous. The computer model developed is based on the xenon plasma chemistry, the circuit, and the Boltzmann equations. First, the validity of the physical model was checked and compared to experimental and theoretical works, and then the model is applied in the case of a sinusoidal voltage at period frequencies in the range of 50 kHz-2 MHz. The results obtained with the present description are in good agreement with experimental measurements and one-dimensional fluid prediction in terms of electrical characteristics and vacuum ultraviolet (vuv) emission. The effect of operation voltage, power source frequency, dielectric capacitance, as well as gas pressure on the discharge efficiency and the 172, 150, and 147 nm photon generation, under the typical experimental operating conditions and for the case of a sinusoidal applied voltage, have been investigated and discussed. Calculations suggest that the overall conversion efficiency from electrical energy to vuv emission in the lamp is greater than 38%, and it will be very affected at high power source frequency and high gas pressure with a significant dependence on the dielectric capacitance.

  20. A Comparison of AC and Short-Pulse Excitation for Xe Excimer Barrier Discharge Lamps

    Science.gov (United States)

    Mildren, R. P.; Morrow, R.; Carman, R. J.

    1999-10-01

    Dielectric barrier discharge excitation of rare-gas and rare-gas halide excimers provides an efficient scheme for generating intense VUV radiation for applications including lighting, ozonisation, and photochemical surface treatment. Typically, lamps employ AC (sinusoidal) voltage excitation in which case VUV emission is produced from short-livid micro discharges (streamers) distributed stochastically over the dielectric. However, it has been recently demonstrated that significantly increased efficiency (by factor 2-3) can be obtained from Xe lamps when using short excitation pulses separated by idle periods[1]. In this paper, we report an investigation into the mechanisms which bring about improved efficiency by comparing the electrical, spectral and spatial emission characteristics of a small-scale Xe lamp excited by short pulses ( 100ns) with that of conventional AC excitation. The results reveal that pulsed excitation produces a homogenous glow-like discharge in which the electron density and temperature are more favourable for efficient excimer production. [1] RP Mildren et al, IVth Int. Conf. Atom. and Molec. Pulsed Lasers, Tomsk, Siberia Sept. (1999); F Vollkommer and L Hitzschke, Proc. 8th Int. Symp. Sci. Tech. Light Sources, Greifswald, Germany, '98, IL-07, pp51-59 (1998)

  1. Study of a Filamentary Dielectric Barrier Discharge in Air at Atmospheric Pressure

    Science.gov (United States)

    Celestin, Sebastien; Zeghondy, Barbar; Guaitella, Olivier; Bourdon, Anne; Rousseau, Antoine

    2006-10-01

    Dielectric Barrier Discharges (DBD) at atmospheric pressure have many applications, for instance ozone production, surface treatment, and waste gas treatment. Generally, such a discharge is filamentary but it can be diffuse under particular conditions. Understanding the formation of the filament, which is an ionization wave or so-called ``streamer'', is very hard theoretically, numerically, and experimentally. This is due, first, to the non-linearity of the equations concerned, and second, because of the scaling in space and time of this phenomenon: a streamer has a radius on the order of a few microns, and propagates through distances of several centimeters in a few nanoseconds. In this study we will present the results obtained in experiments and in simulations for a plane-to-plane DBD. We electrically characterized this device and have observed collective effects that are still poorly understood. A point-to-plane DBD has also been studied for producing a much more localized discharge. In parallel with the experimental study we have developed a numerical model based on the Immersed Boundary Method (IBM) to introduce an electrode having a complex geometry into a structured Cartesian mesh. The first results of the code will be discussed.

  2. Self-organized plasmas formed by accumulated charge in dielectric barrier discharge

    Science.gov (United States)

    Akashi, Haruaki; Yoshinaga, Tomokazu

    2016-09-01

    Atmospheric pressure dielectric barrier discharges (DBDs) have been widely applied to various research fields, such as bio-medical treatment, toxic decomposition and so on. However, the details of DBD have not been understood yet. Because the phenomena occur in nanosecond time scale under atmospheric pressure. It is known that DBDs are significantly affected by accumulated charges on dielectrics, but the distributions and development of accumulated charges are not known for years. To clarify the distributions and the developments of accumulated charges on dielectrics and electron behavior in the vicinity of dielectrics, DBDs in atmospheric pressure oxygen have been simulated using a two dimensional fluid model with relatively high electron emission coefficient. In this condition, DBD simulation results are obtained in so called self-organized form. As a result, the locations of highly accumulated charges are at where the primary streamers reached in a half cycle. And the charges on the dielectrics become almost zero by the electrons after the change of discharge voltage polarity. The electron distribution in the vicinity of the dielectric forms similar to that of accumulated charges to compensate the charges. Excess electrons in front of dielectric become the seed electrons for next half cycle. This continuation makes discharge in self-organized form.

  3. Applicability of the dielectric barrier discharge for helium ash measurements in the divertor region

    Directory of Open Access Journals (Sweden)

    Książek Ireneusz

    2016-06-01

    Full Text Available Controlled fusion based on the magnetic confinement of the plasma is one of the main aims of the Euro-fusion programme. In the fusion device, the hydrogen isotopes, in nuclear reactions, will produce helium nuclei. The products, as the ash, will be removed from the plasma in the region of the so-called divertor. Controlling the helium to hydrogen ratio in this ‘exhaust gas’ will provide information about the efficiency of the fusion process as well as of the efficiency of the helium removal system. One of the methods to perform this task is to study the properties of the discharge conducted in such exhaust gas. In this paper, the applicability of the dielectric barrier discharge (DBD is studied. This preliminary experiment shows a great potential in applicability of this kind of discharge. The optical as well as pulse-height spectra were studied, both revealing very promising properties. In the optical spectrum, one can observe well separated hydrogen and helium spectral lines, with intensities of the same order of magnitude. Moreover, in the registered spectral region, the molecular spectra are negligible. The pulse-height spectra reveal very distinct shape in helium and hydrogen. Checking of this spectrum could provide parallel (redundant information about the partial pressure of helium in the magnetic confinement fusion (MCF device exhaust gas.

  4. Defining barriers to discharge from inpatient rehabilitation, classifying their causes, and proposed performance indicators for rehabilitation patient flow.

    Science.gov (United States)

    New, Peter W; Cameron, Peter A; Olver, John H; Stoelwinder, Johannes U

    2013-01-01

    There is little research literature on patient flow in rehabilitation. Accepted definitions of barriers to discharge and agreed performance measures are needed to support research and understanding of this topic. The potential of improved patient flow in rehabilitation to assist relieving demand pressures in acute hospitals underscores its importance. This study develops a definition of barriers to discharge from postacute care and classifies their causes using a multiphased iterative consultation and feedback process involving physiatrists, aged-care physicians, and senior nursing and allied health clinicians. Key performance indicators (KPIs) for postacute patient flow are then proposed, the development of which were informed by the available literature and a survey (n=101) of physiatrists, aged-care physicians, and hospital managers with responsibility for patient flow who were questioned about the use of relevant KPIs in this setting. Most (>70%) respondents believed that using KPIs (eg, waiting time from acceptance by postacute care and ready for transfer until admission, percentage of postacute bed days occupied by inpatients with a discharge barrier) to measure aspects of patient flow could improve processes, but few reported collecting this information (45% admission KPIs, 19% discharge KPIs). By using the definition and classification of discharge barriers prospectively to document and address barriers, in conjunction with appropriate KPIs, postacute patient flow and the efficiency of hospital resource utilization can potentially be improved. Our commentary aims to stimulate interest among others to develop a more robust evidence base for improved flow through postacute care.

  5. Failures of the thermal barriers of 900 MWe reactor coolant pumps

    Energy Technology Data Exchange (ETDEWEB)

    Peyrouty, P.

    1996-12-01

    This report describes the anomalies encountered in the thermal barriers of the reactor coolant pumps in French 900 MWe PWR power stations. In addition to this specific problem, it demonstrates how the fortuitous discovery of a fault during a sampling test enabled faults of a generic nature to be revealed in components which were not subject to periodic inspection, the failure of which could seriously affect safety. This example demonstrates the risk which can be associated with the deterioration in areas which are not examined periodically and for which there are no preceding signs which would make early detection of deterioration possible.

  6. Monitoring the removal of phosphate from ground water discharging through a pond-bottom permeable reactive barrier

    Science.gov (United States)

    McCobb, T.D.; LeBlanc, D.R.; Massey, A.J.

    2009-01-01

    Installation of a permeable reactive barrier to intercept a phosphate (PO4) plume where it discharges to a pond provided an opportunity to develop and test methods for monitoring the barrier's performance in the shallow pond-bottom sediments. The barrier is composed of zero-valent-iron mixed with the native sediments to a 0.6-m depth over a 1100-m2 area. Permanent suction, diffusion, and seepage samplers were installed to monitor PO 4 and other chemical species along vertical transects through the barrier and horizontal transects below and near the top of the barrier. Analysis of pore water sampled at about 3-cm vertical intervals by using multilevel diffusion and suction samplers indicated steep decreases in PO4 concentrations in ground water flowing upward through the barrier. Samples from vertically aligned pairs of horizontal multiport suction samplers also indicated substantial decreases in PO4 concentrations and lateral shifts in the plume's discharge area as a result of varying pond stage. Measurements from Lee-style seepage meters indicated substantially decreased PO4 concentrations in discharging ground water in the treated area; temporal trends in water flux were related to pond stage. The advantages and limitations of each sampling device are described. Preliminary analysis of the first 2 years of data indicates that the barrier reduced PO4 flux by as much as 95%. ?? 2009 National Ground Water Association.

  7. Dissipated power and induced velocity fields data of a micro single dielectric barrier discharge plasma actuator for active flow control☆

    Science.gov (United States)

    Pescini, E.; Martínez, D.S.; De Giorgi, M.G.; Francioso, L.; Ficarella, A.

    2015-01-01

    In recent years, single dielectric barrier discharge (SDBD) plasma actuators have gained great interest among all the active flow control devices typically employed in aerospace and turbomachinery applications [1,2]. Compared with the macro SDBDs, the micro single dielectric barrier discharge (MSDBD) actuators showed a higher efficiency in conversion of input electrical power to delivered mechanical power [3,4]. This article provides data regarding the performances of a MSDBD plasma actuator [5,6]. The power dissipation values [5] and the experimental and numerical induced velocity fields [6] are provided. The present data support and enrich the research article entitled “Optimization of micro single dielectric barrier discharge plasma actuator models based on experimental velocity and body force fields” by Pescini et al. [6]. PMID:26425667

  8. Demonstration of organic volatile decomposition and bacterial sterilization by miniature dielectric barrier discharges on low-temperature cofired ceramic electrodes

    Science.gov (United States)

    Kim, Duk-jae; Shim, Yeun-keun; Park, Jeongwon; Kim, Hyung-jun; Han, Jeon-geon

    2016-04-01

    Nonthermal atmospheric-pressure plasma discharge is designed with low-temperature cofired ceramic (LTCC) electrodes to achieve dielectric barrier surface discharge (DBSD). The environmental requirement (below 0.05 ppm) of the amount of byproducts (ozone and NO x ) produced during the process was met by optimizing the electrode design to produce a high dielectric barrier discharge for low-voltage (∼700 V) operation and minimizing the distance between electrodes to improve the plasma discharging efficiency. The concentrations of volatile organic compounds (VOCs) within interior cabins of commercial vehicles were significantly reduced after 1-h treatment to improve air quality cost-effectively. This atmospheric-pressure plasma process was demonstrated for the sterilization of Escherichia coli to prevent food poisoning during the preservation of food in refrigerators.

  9. Numerical modelling of the effect of dry air traces in a helium parallel plate dielectric barrier discharge

    Science.gov (United States)

    Lazarou, C.; Belmonte, T.; Chiper, A. S.; Georghiou, G. E.

    2016-10-01

    A validated numerical model developed for the study of helium barrier discharges in the presence of dry air impurities is presented in this paper. The model was used to numerically investigate the influence of air traces on the evolution of the helium dielectric barrier discharge (DBD). The level of dry air used as impurity was in the range from 0 to 1500 ppm, which corresponds to the most commonly encountered range in atmospheric pressure discharge experiments. The results presented in this study clearly show that the plasma chemistry and consequently the discharge evolution is highly affected by the concentration level of impurities in the mixture. In particular, it was observed that air traces assist the discharge ignition at low concentration levels (~55 ppm), while on the other hand, they increase the burning voltage at higher concentration levels (~1000 ppm). Furthermore, it was found that the discharge symmetry during the voltage cycle highly depends on the concentration of air. For the interpretation of the results, a detailed analysis of the processes that occur in the discharge gap is performed and the main reaction pathways of ion production are described. Thanks to this approach, useful insight into the physics behind the evolution of the discharge is obtained.

  10. Characterization of dielectric barrier discharge in air applying current measurement, numerical simulation and emission spectroscopy

    CERN Document Server

    Rajasekaran, Priyadarshini; Awakowicz, Peter

    2012-01-01

    Dielectric barrier discharge (DBD) in air is characterized applying current measurement, numerical simulation and optical emission spectroscopy (OES). For OES, a non-calibrated spectrometer is used. This diagnostic method is applicable when cross-sectional area of the active plasma volume and current density can be determined. The nitrogen emission in the spectral range of 380 nm- 406 nm is used for OES diagnostics. Electric field in the active plasma volume is determined applying the measured spectrum, well-known Frank-Condon factors for nitrogen transitions and numerically- simulated electron distribution functions. The measured electric current density is used for determination of electron density in plasma. Using the determined plasma parameters, the dissociation rate of nitrogen and oxygen in active plasma volume are calculated, which can be used by simulation of the chemical kinetics.

  11. Transferred plasma jet from a dielectric barrier discharge for processing of poly(dimethylsiloxane) surfaces

    CERN Document Server

    Nascimento, Fellype do; Canesqui, Mara A; Moshkalev, Stanislav

    2016-01-01

    In this work we studied processing of poly(dimethylsiloxane) (PDMS) surfaces using dielectric barrier discharge (DBD) plasma in two different assemblies, one using the primary plasma jet obtained from a conventional DBD and the other using a DBD plasma jet transfer. The evolution of water contact angle (WCA) in function of plasma processing time and in function of aging time as well as the changes in the surface roughness of PDMS samples for both plasma treatments have been studied. We also compared vibrational and rotational temperatures for both plasmas and for the first time the vibrational temperature (T_vib) for the transferred plasma jet has been shown to be higher as compared with the primary jet. The increment in the T_vib value seems to be the main reason for the improvements in adhesion properties and surface wettability for the transferred plasma jet. Possible explanations for the increase in the vibrational temperature are presented.

  12. Design of experiment analysis of CO2 dielectric barrier discharge conditions on CO production

    Science.gov (United States)

    Becker, Markus; Ponduri, Srinath; Engeln, Richard; van de Sanden, Richard; Loffhagen, Detlef

    2016-09-01

    Dielectric barrier discharges (DBD) are frequently used for the generation of CO from CO2 which is of particular interest for syngas production. It has been found by means of fluid modelling in that the CO2 conversion frequency in a CO2 DBD depends linearly on the specific energy input (SEI) while the energy efficiency of CO production is only weakly dependent on the SEI. Here, the same numerical model as in is applied to study systematically the influence of gas pressure, applied voltage amplitude and frequency on the CO2 conversion frequency and the energy efficiency of CO production based on a 2-level 3-factor full factorial experimental design. It is found that the operating conditions of the CO2 DBD for CO production can be chosen to either have an optimal throughput or a better energy efficiency. This work was partly supported by the German Research Foundation within the Collaborative Research Centre Transregio 24.

  13. Surface Modification of Polyimide Film by Dielectric Barrier Discharge at Atmospheric Pressure

    Science.gov (United States)

    Peng, Shi; Li, Lingjun; Li, Wei; Wang, Chaoliang; Guo, Ying; Shi, Jianjun; Zhang, Jing

    2016-04-01

    In this paper, polyimide (PI) films are modified using an atmospheric pressure plasma generated by a dielectric barrier discharge (DBD) in argon. Surface performance of PI film and its dependence on exposure time from 0 s to 300 s are investigated by dynamic water contact angle (WCA), field emission scanning electron microscopy (FESEM), and Fourier transform infrared spectroscopy in attenuated total multiple reflection mode (FTIR-ATR). The study demonstrates that dynamic WCA exhibits a minimum with 40 s plasma treatment, and evenly distributed nano-dots and shadow concaves appeared for 40 s and 12 s Ar plasma treatment individually. A short period of plasma modification can contribute to the scission of the imide ring and the introduction of C-O and C=O (-COOH) by detailed analysis of FTIR-ATR.

  14. Decomposition of L-valine under nonthermal dielectric barrier discharge plasma.

    Science.gov (United States)

    Li, Yingying; Kojtari, Arben; Friedman, Gary; Brooks, Ari D; Fridman, Alex; Ji, Hai-Feng

    2014-02-13

    L-Valine solutions in water and phosphate buffer were treated with nonthermal plasma generated by using a dielectric barrier discharge (DBD) device and the products generated after plasma treatments were characterized by (1)H NMR and GC-MS. Our results demonstrate that L-valine is decomposed to acetone, formic acid, acetic acid, threo-methylaspartic acid, erythro-methlyaspartic acid, and pyruvic acid after direct exposure to DBD plasma. The concentrations of these compounds are time-dependent with plasma treatment. The mechanisms of L-valine under the DBD plasma are also proposed in this study. Acetone, pyruvic acid, and organic radicals (•)CHO, CH3COCH2OO(•) (acetonylperoxy), and CH3COC(OH)2OO(•) (1,1-dihydroxypropan-2-one peroxy) may be the determining chemicals in DNA damage.

  15. Mesoporous TiO2 films fabricated using atmospheric pressure dielectric barrier discharge jet.

    Science.gov (United States)

    Seo, Hyung-Kee; Elliott, C Michael; Shin, Hyung-Shik

    2010-12-01

    TiO2 nanoparticles were synthesized by a facile method of dielectric barrier discharge jet (DBD jet) for the dye-sensitized solar cell (DSSC) and other potential applications. DBD jet is utilized as a method for deposition of TiO2 nanoparticles with a 9 μm/min growth rate which is more than ×25 faster than reported previously. Their performance was compared with cells fabricated using commercial TiO2 nanoparticles (P25). The crystallinity and chemical bonding states of samples were characterized by XRD and XPS. Photoanodes fabricated by the DBD jet method resulted in approximately 50% higher photoconversion efficiency than ones prepared from P25 nanoparticles.

  16. Surface Modification of Polyethylene (PE) Films Using Dielectric Barrier Discharge Plasma at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    WANG Kun; LI Jian; REN Chunsheng; WANG Dezhen; WANG Younian

    2008-01-01

    Modification of the surface properties of polyethylene (PE) films is studied using air dielectric barrier discharge at atmospheric pressure. The treated samples are examined by water contact angle measurements, Fourier transform infrared attenuated total reflection spectroscopy (FTIR-ATR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). With the increase in treating time, the water contact angle changes from 93.2° before treatment to a minimum of 53.3° after a treatment for 50 s. Both ATR and XPS results show some oxidized" species are introduced into the sample surface by the plasma treatment and the tendency of the water contact angle with the treating time is the same as that of oxygen concentration on the treated sample surface. SEM result shows the surface roughness of PE samples increases with the treatment time increasing.

  17. Facile Carbon Fixation to Performic Acids by Water-Sealed Dielectric Barrier Discharge

    Science.gov (United States)

    Kawasaki, Mitsuo; Morita, Tatsuo; Tachibana, Kunihide

    2015-10-01

    Carbon fixation refers to the conversion of carbon dioxide (CO2) to organic materials, as commonly performed in nature through photosynthesis by plants and other autotrophic organisms. The creation of artificial carbon fixation processes is one of the greatest challenges for chemistry to solve the critical environmental issue concerning the reduction of CO2 emissions. We have developed an electricity-driven facile CO2 fixation process that yields performic acid, HCO2OH, from CO2 and water at neutral pH by dielectric barrier discharge with an input electric power conversion efficiency of currently 0.2-0.4%. This method offers a promising future technology for artificial carbon fixation on its own, and may also be scaled up in combination with e.g., the post-combustion CO2 capture and storage technology.

  18. Characteristics of Ozone Production by Using Atmospheric Surface Glow Barrier Discharge

    Directory of Open Access Journals (Sweden)

    Mudtorlep NISOA

    2009-06-01

    Full Text Available Ozone is a strong oxidizer that can kill bacteria and other micro-organisms very effectively. In the recent years, ozone has become very important for sterilization of water used in shrimp farming and treatment of wastewater from food industry. However, ozonisers available in the markets are very expensive and have low energy-efficiency. In this work, a highly-efficient and low-cost system that can produce high-concentrations of ozone gas and dissolved ozone in water has been developed. The system consists of a dried air unit, high-voltage rf power supply, ozoniser tubes and venturi injector. The tubes are designed and configured to convert oxygen gas to ozone gas by atmospheric surface glow barrier discharge.

  19. Investigation of Plasma Polymerized Maleic Anhydride Film in a Middle Frequency Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    TANG Wenjie; CHEN Qiang; ZHANG Yuefei; GE Yuanjing

    2008-01-01

    Plasma polymerized maleic anhydride (MA) was carried out by using maleic anhydride supersaturated ethanol solution as a precursor in a dielectric barrier discharge (DBD). The film properties were characterized by water contact angle (WCA), Fourier transfer infrared (FTIR), X-ray photoelectron spectroscopy (XPS), atomic force microscope (AFM) analysis, and a thickness profilometer. The influence of the processing parameters on the film properties such as the power frequency, and polymerization zone was investigated. The results show that anhydride group incorporated into the growing films is favorable at the frequency of 80 kHz and working pressure of 50 Pa. The poly (maleic anhydride) film is uniform and compact at an average deposition rate of 8 nm/min.

  20. Harmonic hexagonal superlattice pattern in a dielectric barrier discharge at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    DONG LiFang; XIE WeiXia; ZHAO HaiTao; FAN WeiLi

    2009-01-01

    We report a harmonic hexagonal superlattice pattern in a dielectric barrier discharge in air/argon mixture at atmospheric pressure.The bifurcation scenario of harmonic hexagonal superlattice pattern with the applied voltage increasing is given.The phase diagram of the pattern types as a function of the applied voltage and the air-concentration is obtained.The hysteresis of pattern transitions at the upward and downward stage of the applied voltage is observed.The correlation measurements indicate that harmonic hexagonal superlattice pattern is an interleaving of two different transient sublattices.The spatial power spectrum demonstrates that harmonic hexagonal superlattice pattern has two separate wave vectors.Both small wave vector qh and big wave vector Kh,belong to the harmonic mode,and they obey a triad resonant interaction q1h + q2h,=Kh.

  1. Hydrogen generation from steam reforming of ethanol in dielectric barrier discharge

    Institute of Scientific and Technical Information of China (English)

    Baowei Wang; Yijun Lü; Xu Zhang; Shuanghui Hu

    2011-01-01

    Dielectric barrier discharge(DBD)was used for the generation of hydrogen from ethanol reforming.Effects of reaction conditions,such as vaporization temperature,ethanol flow rate,water/ethanol ratio,and addition of oxygen,on the ethanol conversion and hydrogen yield,were studied.The results showed that the increase of ethanol flow rate decreased ethanol conversion and hydrogen yield,and high water/ethanol ratio and addition of oxygen were advantageous.Ethanol conversion and hydrogen yield increased with the vaporization room temperature up to the maximum at first,and then decreased slightly.The maximum hydrogen yield of 31.8% was obtained at an ethanol conversion of 88.4% under the optimum operation conditions of vaporization room temperature of 120℃,ethanol flux of 0.18 mL/min,water/ethanol ratio of 7.7 and oxygen volume concentration of 13.3%.

  2. Theoretical analysis of ozone generation by pulsed dielectric barrier discharge in oxygen

    Science.gov (United States)

    Wei, L. S.; Zhou, J. H.; Wang, Z. H.; Cen, K. F.

    2007-08-01

    The use of very short high-voltage pulses combined with a dielectric layer results in high-energy electrons that dissociate oxygen molecules into atoms, which are a prerequisite for the subsequent production of ozone by collisions with oxygen molecules and third particles. The production of ozone depends on both the electrical and the physical parameters. For ozone generation by pulsed dielectric barrier discharge in oxygen, a mathematical model, which describes the relation between ozone concentration and these parameters that are of importance in its design, is developed according to dimensional analysis theory. A formula considering the ozone destruction factor is derived for predicting the characteristics of the ozone generation, within the range of the corona inception voltage to the gap breakdown voltage. The trend showing the dependence of the concentration of ozone in oxygen on these parameters generally agrees with the experimental results, thus confirming the validity of the mathematical model.

  3. Improved performance of a barrier-discharge plasma jet biased by a direct-current voltage

    Science.gov (United States)

    Li, Xuechen; Li, Yaru; Zhang, Panpan; Jia, Pengying; Dong, Lifang

    2016-01-01

    One of the challenges that plasma research encounters is how to generate a large-scale plasma plume at atmospheric pressure. Through utilizing a third electrode biased by a direct-current voltage, a longer plasma plume is generated by a plasma jet in dielectric barrier discharge configurations. Results indicate that the plume length increases until it reaches the third electrode with increasing the bias voltage. By fast photography, it is found that the plume consists of two types of streamers under the influence of the bias voltage, which develops from a guided streamer to a branching one with leaving the tube opening. The transition from the guided streamer to the branching one can be attributed to the electric field and the air/argon fraction. PMID:27759080

  4. Electron energy distribution functions for modelling the plasma kinetics in dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Carman, R.J. [Department of Physics, Division of Information and Communications Sciences, Macquarie University, Sydney, NSW (Australia)). E-mail: rcarman@physics.mq.edu.au; Mildren, R.P. [Centre for Lasers and Applications, Division of Information and Communications Sciences, Macquarie University, Sydney, NSW (Australia)

    2000-10-07

    In modelling the plasma kinetics in dielectric barrier discharges (DBDs), the electron energy conservation equation is often included in the rate equation analysis (rather than utilizing the local-field approximation) with the assumption that the electron energy distribution function (EEDF) has a Maxwellian profile. We show that adopting a Maxwellian EEDF leads to a serious overestimate of the calculated ionization/excitation rate coefficients and the electron mobility for typical plasma conditions in a xenon DBD. Alternative EEDF profiles are trialed (Druyvesteyn, bi-Maxwellian and bi-Druyvesteyn) and benchmarked against EEDFs obtained from solving the steady-state Boltzmann equation. A bi-Druyvesteyn EEDF is shown to be more inherently accurate for modelling simulations of xenon DBDs. (author)

  5. Improved performance of a barrier-discharge plasma jet biased by a direct-current voltage

    Science.gov (United States)

    Li, Xuechen; Li, Yaru; Zhang, Panpan; Jia, Pengying; Dong, Lifang

    2016-10-01

    One of the challenges that plasma research encounters is how to generate a large-scale plasma plume at atmospheric pressure. Through utilizing a third electrode biased by a direct-current voltage, a longer plasma plume is generated by a plasma jet in dielectric barrier discharge configurations. Results indicate that the plume length increases until it reaches the third electrode with increasing the bias voltage. By fast photography, it is found that the plume consists of two types of streamers under the influence of the bias voltage, which develops from a guided streamer to a branching one with leaving the tube opening. The transition from the guided streamer to the branching one can be attributed to the electric field and the air/argon fraction.

  6. Dynamic Properties of Helium Atmospheric Dielectric-Barrier-Discharge Plasma Jet.

    Science.gov (United States)

    Uchida, Giichiro; Takenaka, Kosuke; Miyazaki, Atsushi; Kawabata, Kazufumi; Setsuhara, Yuichi

    2015-03-01

    We present here experiments on helium atmospheric dielectric-barrier discharge jet in open air. A long stable plasma plume is realized at high applied voltage and high gas flow rate. Optical emission measurements show that the plasma plume consists of two part: a plume head with high energy electrons and a tail part with low energy electrons. The plasma plume propagates away from the quartz-tube outlet with about 30-80 km/sec along the helium gas flow channel. The propagation velocity of plasma plume is in the time scale of electron drift velocity, and the electric field plays an important role as a driving force of the plasma plume propagation.

  7. Inactivation of Escherichia coli on PTFE surfaces by diffuse coplanar surface barrier discharge

    Science.gov (United States)

    Tučeková, Zlata; Koval'ová, Zuzana; Zahoranová, Anna; Machala, Zdenko; Černák, Mirko

    2016-08-01

    The non-equilibrium plasma of diffuse coplanar surface barrier discharge (DCSBD) was tested for decontamination of bacteria Escherichia coli on polymer surfaces. We investigated the optical parameters of DCSBD plasma generated in synthetic air with different relative humidity. Our study was provided to estimate the main plasma components active during the DCSBD plasma degradation of E. coli contamination prepared on polytetrafluoroethylene (PTFE, Teflon) surface, in ambient air at atmospheric pressure. The DCSBD plasma was characterized by means of electrical measurements and optical emission spectroscopy. The inactivation of E. coli bacteria was evaluated by standard microbiological cultivation (CFU plate counting). The experimental results of the germicidal efficiency obtained for short plasma exposure times proved the effectiveness of DCSBD plasma for the polymer surface decontamination. Contribution to the topical issue "6th Central European Symposium on Plasma Chemistry (CESPC-6)", edited by Nicolas Gherardi, Ester Marotta and Cristina Paradisi

  8. Analysis of Ar plasma jets induced by single and double dielectric barrier discharges at atmospheric pressure

    Science.gov (United States)

    Judée, F.; Merbahi, N.; Wattieaux, G.; Yousfi, M.

    2016-09-01

    The aim is the comparison of different plasma parameters of single and double dielectric barrier discharge plasma jet configurations (S-DBD and D-DBD) which are potentially usable in biomedical applications. Both configurations are studied in terms of electric field distribution, electrical discharge characteristics, plasma parameters (estimated by optical emission spectroscopy analysis), and hydrodynamics of the plasma jet for electrical parameters of power supplies corresponding to an applied voltage of 10 kV, pulse duration of 1 μs, frequency of 9.69 kHz, and Ar flow of 2 l/min. We observed that the D-DBD configuration requires half the electrical power one needs to provide in the S-DBD case to generate a plasma jet with similar characteristics: excitation temperature around 4700 K, electron density around 2.5 × 1014 cm-3, gas temperature of about 320 K, a relatively high atomic oxygen concentration reaching up to 1000 ppm, the presence of reactive oxygen and nitrogen species (nitric oxide, hydroxyl radical, and atomic oxygen), and an irradiance in the UV-C range of about 20 μW cm-2. Moreover, it has been observed that D-DBD plasma jet is more sensitive to short pulse durations, probably due to the charge accumulation over the dielectric barrier around the internal electrode. This results in a significantly longer plasma length in the D-DBD configuration than in the S-DBD one up to a critical flow rate (2.25 l/min) before the occurrence of turbulence in the D-DBD case. Conversely, ionization wave velocities are significantly higher in the S-DBD setup (3.35 × 105 m/s against 1.02 × 105 m/s for D-DBD), probably due to the higher electrostatic field close to the high voltage electrode in the S-DBD plasma jet.

  9. The Key Factor for Uniform and Patterned Glow Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    OUYANG Ji-Ting; DUAN Xiao-Xi; XU Shao-Wei; HE Feng

    2012-01-01

    We present the results from 2D fluid modeling of the key roles controlling the glow dielectric barrier discharge (DBD) structure. A uniform DBD can be sustained at lower frequency when the space charge reaches uniformity due to plasma decay, while the patterned structure appears above a critical frequency when the space charge is nonuniform. The patterns start from the electrode edge where the electric field is significantly distorted, characterized by the patterned seed electrons that always form ahead of the surface charges. The formation of the patterned DBD structure is associated with the lateral inhibition of the local increase of space charges. The distribution of the volume seed electrons plays a key role in the DBD structure while the distribution of surface charge is a result of the formed structure.%We present the results from 2D fluid modeling of the key roles controlling the glow dielectric barrier discharge (DBD) structure.A uniform DBD can be sustained at lower frequency when the space charge reaches uniformity due to plasma decay,while the patterned structure appears above a critical frequency when the space charge is nonuniform.The patterns start from the electrode edge where the electric field is significantly distorted,characterized by the patterned seed electrons that always form ahead of the surface charges.The formation of the patterned DBD structure is associated with the lateral inhibition of the local increase of space charges.The distribution of the volume seed electrons plays a key role in the DBD structure while the distribution of surface charge is a result of the formed structure.

  10. A broadband excimer source of visible radiation with barrier discharge pumping

    Science.gov (United States)

    Malinin, A. N.; Polyak, A. V.

    2003-12-01

    We investigate the characteristics of a broadband cylindrical excimer source of visible radiation with a surface area of 230 cm2 excited by a pulse-periodic barrier discharge based on multicomponent mixtures (mercury diiodide and dibromide with helium and admixtures of molecular nitrogen and xenon). The working mixture components were excited by a pulse-periodic (pulse repetition rate 500 5000 Hz, pulse duration ˜150 ns) barrier discharge. We detected radiation from excimer HgI* and HgBr* molecules, the second positive system of molecular nitrogen, and mercury and xenon atoms. The amplitude, duration, and trailing edge of the radiation pulses in the HgI2:HgBr2:Xe:He and HgI2: HgBr2:N2:He mixtures with admixtures of xenon and molecular nitrogen were found to change compared to the HgI2:HgBr2:He mixture. The optimal partial pressure of helium lies within the range 162 195 kPa. The most intense radiation from HgI* and HgBr* molecules (in a ratio of more than 3: 1) is observed in the HgI2:HgBr2: Xe:He mixture. The mean and pulse radiation powers are 45 W and 93 kW, respectively, at a pumping pulse repetition rate of 5000 Hz and an efficiency of 30%. We discuss the spectral and temporal characteristics of the radiation source and the dependence of the radiation intensity of excimer molecules of mercury monoiodide and monobromide on the partial pressures of xenon and nitrogen. We point out that the radiation source is of considerable interest for applications in biotechnology and medicine.

  11. Spatial-Temporal Patterns in a Dielectric Barrier Discharge under Narrow Boundary Conditions in Argon at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    LI Xue-Chen; JIA Peng-Ying; ZHAO Na

    2011-01-01

    @@ Pattern formation phenomena are investigated in a dielectric barrier discharge under narrow boundary conditions in argon at atmospheric pressure.The discharge shows various scenarios with the increasing applied voltage.This is the first observation of alternating single spot and pair spots pattern and of a moving striation pattern in a dielectric barrier discharge system.The spatial-temporal correlations between discharge filaments in these patterns are measured by an optical method.The results show that the zigzag pattern is an interleaving of two sub-structure patterns, which ignites once for each sub-pattern per half cycle of the applied voltage.There is a temporal sequence inversion in consecutive half-cycles for the two sub-patterns.The pattern of alternating single spot and pair spots is also an interleaving of two sub-structure patterns.However, the pair spots sub-pattern ignites twice and the single spot sub-pattern ignites once per half cycle of the applied voltage.%Pattern formation phenomena are investigated in a dielectric barrier discharge under narrow boundary conditions in argon at atmospheric pressure. The discharge shows various scenarios with the increasing applied voltage.This is the first observation of alternating single spot and pair spots pattern and of a moving striation pattern in a dielectric barrier discharge system. The spatial-temporal correlations between discharge filaments in these patterns are measured by an optical method. The results show that the zigzag pattern is an interleaving of two sub-structure patterns, which ignites once for each sub-pattern per half cycle of the applied voltage. There is a temporal sequence inversion in consecutive half-cycles for the two sub-patterns. The pattern of alternating single spot and pair spots is also an interleaving of two sub-structure patterns. However, the pair spots sub-pattern ignites twice and the single spot sub-pattern ignites once per half cycle of the applied voltage.

  12. Simulation study of one-dimensional self-organized pattern in an atmospheric-pressure dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jiao; Wang, Yanhui, E-mail: wangyh@dlut.edu.cn; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2015-04-15

    A two-dimensional fluid model is developed to simulate the one-dimensional self-organized patterns in an atmospheric-pressure dielectric barrier discharge (DBD) driven by sinusoidal voltage in argon. Under certain conditions, by changing applied voltage amplitude, the transversely uniform discharge can evolve into the patterned discharge and the varied self-organized patterned discharges with different numbers and arrangements of discharge channels can be observed. Similar to the uniform atmospheric-pressure DBD, the patterned discharge mode is found to undergo a transition from Townsend regime, sub-glow regime to glow regime with increasing applied voltage amplitude. In the different regimes, charged particles and electric field display different dynamical behaviors. If the voltage amplitude is increased over a certain value, the discharge enters an asymmetric patterned discharge mode, and then transforms into the spatially chaotic state with out-of-order discharge channels. The reason for forming the one-dimensional self-organized pattern is mainly due to the so-called activation-inhibition effect resulting from the local high electron density region appearing in discharge space. Electrode arrangement is the reason that induces local high electron density.

  13. Removal of formaldehyde by a pulsed dielectric barrier discharge in dry air in the 20 °C to 300 °C temperature range

    Science.gov (United States)

    Blin-Simiand, N.; Pasquiers, S.; Magne, L.

    2016-05-01

    The influence of the gas mixture temperature, from 20 °C up to 300 °C, on the removal of formaldehyde, diluted at low concentration (less than 800 ppm) in dry air at atmospheric pressure, by a pulsed dielectric barrier discharge (DBD) is studied by means of Fourier transform infrared spectroscopy and micro gas chromatography. Efficient removal of CH2O is obtained and it is found that the characteristic energy, less than 200 J l-1, is a decreasing function of the temperature over the whole range of concentration values under consideration. Byproducts issued from the removal are identified and quantified (CO, CO2, HCOOH, HNO3). Experimental results are analysed using a zero-dimensional simplified DBD-reactor model in order to gain insights on the chemical processes involved. It is shown that the dissociation of the molecule competes with oxidation reactions at low temperature, whereas at high temperature oxidation processes dominate.

  14. A new approach to the non-oxidative conversion of gaseous alkanes in a barrier discharge and features of the reaction mechanism

    Science.gov (United States)

    Kudryashov, S.; Ryabov, A.; Shchyogoleva, G.

    2016-01-01

    A new approach to the non-oxidative conversion of C1-C4 alkanes into gaseous and liquid products in a barrier discharge is proposed. It consists in inhibiting the formation of deposits on the reactor electrode surfaces due to the addition of distilled water into the flow of hydrocarbon gases. The energy consumption on hydrocarbon conversion decreases from methane to n-butane from ~46 to 35 eV molecule-1. The main gaseous products of the conversion of light alkanes are hydrogen and C2-C4 hydrocarbons. The liquid reaction products contain C5+ alkanes with a predominantly isomeric structure. The results of modeling the kinetics of chemical reactions show that an increase in the molecular weight of the reaction products is mainly due to processes involving CH2 radical and the recombination of alkyl radicals.

  15. Packed-bed reactor/silent-discharge plasma design data report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    In 1992, Congress passed the Federal Facility Compliance Act requiring the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). The DOE Albuquerque Operations Office (AL) currently does not have adequate systems to treat the mixed wastes generated and stored at the nine DOE-AL sites. In response to the need for mixed-waste treatment capacity, DOE-AL organized a Treatment Selection Team under the Mixed-Waste Treatment Program (MWTP) to match mixed wastes with treatment options and develop a strategy for treatment of its mixed waste. The strategy developed by the Treatment Selection Team, as described in the AL Mixed-Waste Treatment Plan (DOE 1994), is to use available off-site commercial treatment facilities for all wastes that can be successfully and cost-effectively treated by such facilities. Where no appropriate commercial treatment facilities exist, mobile treatment units (MTUs) would be developed to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste must not only address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. The packed-bed reactor/silent discharge plasma was chosen as a potential candidate for the treatment of the mixed wastes. The process is described.

  16. Schlieren imaging in a dielectric barrier discharge actuator for airflow control

    Science.gov (United States)

    Cristofolini, A.; Neretti, G.; Roveda, F.; Borghi, C. A.

    2012-02-01

    The operation of a surface dielectric barrier discharge actuator for airflow control has been experimentally investigated. The actuator is constituted by an electrode pair separated by a dielectric Teflon sheet. Several ac supply conditions have been utilized. An electrohydrodynamics interaction was induced in still air, and several fluid-dynamic regimes were obtained. Visualization of the plasma boundary layer during the discharge ignition phase and during the steady state regime was obtained by utilizing a Schlieren diagnostic technique. The vortex morphology and propagation velocities at all supply conditions utilized have been evaluated. Velocity profiles perpendicular to the actuator surface, obtained from Pitot tube measurements, and line intensity profiles, determined by means of Schlieren imaging, have been determined for the steady regime operation. The integral along a line perpendicular to the actuator surface of the light intensity of the Schlieren image has been calculated. The profile obtained is in good agreement with the Pitot velocity profile in all the supply conditions investigated. Numerical simulations were also performed. The calculations confirm the relation between the flow velocity distribution in the boundary layer and the gas density distribution, which is the cause of the Schlieren image.

  17. Improvement of wettability and absorbancy of textile using atmospheric pressure dielectric barrier discharge

    Science.gov (United States)

    Ghimire, Bhagirath; Subedi, Deepak Prasad; Khanal, Raju

    2017-08-01

    In this study, cotton textile samples, commonly used in making quilt covers were subjected to atmospheric pressure dielectric barrier discharge treatment to study their surface wettability and absorbancy. Samples were treated in the discharge using a rotatory mechanism and the effects of plasma treatment were examined by contact angle measurement and weight measurement. Air plasma treatment was successful in incorporating hydrophilic functional groups on the textile surface due to which wettability as well as absorbancy immediately after the treatment were highly improved. Effects of plasma treatment started to appear only after 20 cycles (9 mins) and got saturated after 24 cycles (10.8 mins) of treatment. The contact angle reduced from 137 ° (untreated sample) to a value less than 30 ° while absorbancy increased by more than two times as compared to untreated sample. Also, the aging behavior of the plasma treated samples were studied for about a week after plasma treatment. It was observed that the induced oxygen containing groups re-oriented into the bulk of the material during their storage in the environment due to which initial properties of the samples recovered gradually. Our results indicate that low temperature plasma can be successfully applied to modify the properties of textiles and textile industries could utilize this by standardization.

  18. On spatial stabilization of dielectric barrier discharge microfilaments by residual heat build-up in air

    Science.gov (United States)

    Ráhel, Jozef; Szalay, Zsolt; Čech, Jan; Morávek, Tomás

    2016-04-01

    Microfilaments of dielectric barrier discharge are known for their multiple re-appearance at the same spot on dielectrics. This effect of localized re-appearance is driven by residual excited species and ions, surface charge deposited on the dielectric and the local temperature build-up resulting in the local increase of reduced electric field E/ΔN. To assess the magnitude of the latter, the breakdown voltage vs. temperature up to 180 °C was carefully measured at coplanar DBD and used as an input into the numerical simulation of heat build-up by the train of discharge pulses. An average reduction of breakdown voltage was found to be 20 V/K. The model predicted a quasi-stable microfilament temperature into which the thermal build-up rapidly converges. Its magnitude agreed well with the reported rotational temperature of similar electrode configuration. The impact of quasi-stable temperature on microfilament formation dynamics is further discussed. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  19. Reactive fluxes delivered by dielectric barrier discharge filaments to slightly wounded skin

    Science.gov (United States)

    Babaeva, Natalia Yu; Kushner, Mark J.

    2013-01-01

    The application of atmospheric-pressure plasmas to human tissue has been shown to have therapeutic effects for wound healing and in treatment of skin diseases. In this paper, we report on a computational study of the intersection of plasma filaments in a dielectric barrier discharge (DBD) with a small wound in human skin in the context of plasma medicine. The wound is represented as a small cut in the epidermal layer of cells. Intracellular structures and their electrical properties were incorporated into the two-dimensional computational mesh in order to self-consistently couple gas phase plasma transport with the charging of the surface of the wound. We quantify the fluxes of reactive oxygen and nitrogen species, ions and photons produced in or diffusing into the wound as might occur during the first few discharge pulses of treatment. Comparison is made to fluxes predicted by global modelling. We show that the relative location of the plasma filament with respect to the wound is important on plasma time scales (ns) for ions and photons, and for radicals directly produced by electron impact processes. On the longer-term diffusion time scales (ms) the position of the plasma filament relative to the wound is not so critical. For typical DBD conditions, the magnitude of these fluxes to the cellular surfaces corresponds to fluences of radicals nearly equal to the surface site density. These results imply that the biological reactivity is limited by reaction probabilities and not the availability of radical fluxes.

  20. Study of internal transport barriers in the initial phase of Ohmic discharges in TUMAN-3M

    Energy Technology Data Exchange (ETDEWEB)

    Askinazi, L G [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Bulanin, V V [St Petersburg State Polytechnical University, 195251 (Russian Federation); Vildjunas, M I [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Golant, V E [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Gorokhov, M V [St Petersburg State Polytechnical University, 195251 (Russian Federation); Kornev, V A [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Krikunov, S V [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Lebedev, S V [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Petrov, A V [St Petersburg State Polytechnical University, 195251 (Russian Federation); Rozhdestvensky, V V [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Tukachinsky, A S [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation); Zhubr, N A [Ioffe Physico-Technical Institute, RAS, 194021, St Petersburg (Russian Federation)

    2004-05-01

    A regime with electron heat confinement improvement was recently found in the initial phase of discharges in the TUMAN-3M tokamak. An internal transport barrier (ITB) formation in this regime was confirmed by Thomson scattering measurements and by transport modelling. Two possible reasons for the ITB formation are discussed in the paper: by reduction of turbulent transport in the presence of low magnetic shear or by plasma sheared rotation. It is demonstrated that low magnetic shear formation is possible in the current ramp-up phase of the Ohmic discharge. The low magnetic shear does not seem to be the only reason for the transport reduction. Results of Doppler reflectometry measurements of poloidal rotation of density fluctuations are presented. It is found that core confinement improvement correlates with the appearance of sheared rotation of the density fluctuations and with a burst of the MHD activity. The ITB formation in the regime seems to be a result of a combined action of reduced magnetic shear and plasma sheared rotation.

  1. Glyphosate contaminated soil remediation by atmospheric pressure dielectric barrier discharge plasma and its residual toxicity evaluation.

    Science.gov (United States)

    Wang, Tiecheng; Ren, Jingyu; Qu, Guangzhou; Liang, Dongli; Hu, Shibin

    2016-12-15

    Glyphosate was one of the most widely used herbicides in the world. Remediation of glyphosate-contaminated soil was conducted using atmospheric pressure dielectric barrier discharge (DBD) plasma. The feasibility of glyphosate degradation in soil was explored, and the soil leachate toxicity after remediation was assessed via a seed germination test. The experimental results showed that approximately 93.9% of glyphosate was degraded within 45min of DBD plasma treatment with an energy yield of 0.47gkWh(-1), and the degradation process fitted the first-order kinetic model. Increasing the discharge voltage and decreasing the organic matter content of the soil were both found to facilitate glyphosate degradation. There existed appropriate soil moisture to realize high glyphosate degradation efficiency. Glyphosate mineralization was confirmed by changes of total organic carbon (TOC), chemical oxygen demand (COD), PO4(3-) and NO3(-). The degradation intermediates including glycine, aminomethylphosphonic acid, acetic acid, formic acid, PO4(3-) and NO3(-), CO2 and CO were observed. A possible pathway for glyphosate degradation in the soil using this system was proposed. Based on the soil leachate toxicity test using wheat seed germination, the soil did not exhibit any hazardous effects following high-efficiency glyphosate degradation.

  2. Room Temperature Growth of Hydrogenated Amorphous Silicon Films by Dielectric Barrier Discharge Enhanced CVD

    Institute of Scientific and Technical Information of China (English)

    GUO Yu; ZHANG Xiwen; HAN Gaorong

    2007-01-01

    Hydrogenated amorphous silicon (a-Si:H) films were deposited on Si (100) and glass substrates by dielectric barrier discharge enhanced chemical vapour deposition (DBD-CVD)in (SiH4+H2) atmosphere at room temperature.Results of the thickness measurement,SEM (scanning electron microscope),Raman,and FTIR (Fourier transform infrared spectroscopy) show that with the increase in the applied peak voltage,the deposition rate and network order of the films increase,and the hydrogen bonding configurations mainly in di-hydrogen (Si-H2) and poly hydrogen (SiH2)n are introduced into the films.The UV-visible transmission spectra show that with the decrease in Sill4/ (SiH4+H2) the thin films'band gap shifts from 1.92 eV to 2.17 eV.These experimental results are in agreement with the theoretic analysis of the DBD discharge.The deposition of a-Si:H films by the DBD-CVD method as reported here for the first time is attractive because it allows fast deposition of a-Si:H films on large-area low-melting-point substrates and requires only a low cost of production without additional heating or pumping equipment.

  3. Plasma polymers deposited in atmospheric pressure dielectric barrier discharges: Influence of process parameters on film properties

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, Katja, E-mail: k.fricke@inp-greifswald.de [Leibniz Institute for Plasma Science and Technology e.V. (INP Greifswald), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Girard-Lauriault, Pierre-Luc [Plasma Processing Laboratory, Department of Chemical Engineering, McGill University, 3610 rue University, Montreal, QC H3A 0C5 (Canada); Weltmann, Klaus-Dieter [Leibniz Institute for Plasma Science and Technology e.V. (INP Greifswald), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Wertheimer, Michael R. [Department of Engineering Physics, École Polytechnique de Montréal, Box 6079, Station Centre-Ville, Montreal, QC H3C 3A7 (Canada)

    2016-03-31

    We present results on the deposition of plasma polymer (PP) films in a dielectric barrier discharge system fed with mixtures of argon or nitrogen carrier gas plus different hydrocarbon precursors, where the latter possess different carbon-to-hydrogen ratios: CH{sub 4} < C{sub 2}H{sub 6} < C{sub 2}H{sub 4} = C{sub 3}H{sub 6} < C{sub 2}H{sub 2}. The influence of precursor gas mixture and flow rate, excitation frequency, and absorbed power on PP film compositions and properties has been investigated. The discharge was characterized by electrical measurements, while the chemical compositions and structures of coatings were analysed by X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, total combustion, and elastic recoil detection analyses, the latter two for determining carbon-to-hydrogen ratios. Scanning electron microscopy was used to study the coatings' morphology, and profilometry for evaluating deposition rates. - Highlights: • Atmospheric pressure DBD is used to deposit organic hydrocarbon films. • High deposition rates can be achieved by varying the power and/or gas mixture ratio. • Process parameters affect the films' surface chemical composition and morphology. • Deposited films are not soluble in aqueous environment. • No delamination of coatings produced from argon plasma.

  4. A low power miniaturized dielectric barrier discharge based atmospheric pressure plasma jet

    Science.gov (United States)

    Divya Deepak, G.; Joshi, N. K.; Pal, Dharmendra Kumar; Prakash, Ram

    2017-01-01

    In this paper, a dielectric barrier discharge plasma based atmospheric pressure plasma jet has been generated in a floating helix and floating end ring electrode configuration using argon and helium gases. This configuration is subjected to a range of supply frequencies (10-25 kHz) and supply voltages (2-6 kV) at a fixed rate of gas flow rate (i.e., 1 l/min). The electrical characterization of the plasma jet has been carried out using a high voltage probe and current transformer. The current-voltage characteristics have been analyzed, and the consumed power has been estimated at different applied combinations for optimum power consumption at maximum jet length. The obtained optimum power and jet length for argon and helium gases are 12 mW and 32 mm, and 7.7 mW and 42 mm, respectively. It is inferred that besides the electrode configurations, the discharge gas is also playing a significant role in the low power operation of the cold plasma jet at maximum jet length. The obtained results are interpreted on the basis of penning processes.

  5. The influence of ethene on the conversion of ? in a dielectric barrier discharge

    Science.gov (United States)

    Niessen, Wolfgang; Wolf, Oliver; Schruft, Reiner; Neiger, Manfred

    1998-03-01

    The possibility of removing toxic impurities from gaseous streams by electrical gas discharges has been investigated for almost a decade. Cold discharges, i.e. plasmas in which the electrons are not in thermal equilibrium with ions and molecules, seem to be a potential method for the conversion of 0022-3727/31/5/011/img2 (0022-3727/31/5/011/img3, 0022-3727/31/5/011/img4) in exhaust gases of cars or in flue gases of incineration plants. In this work we present a model for the temporal evolution of the plasma chemical processes in a dielectric barrier discharge in a mixture containing 0022-3727/31/5/011/img5, 0022-3727/31/5/011/img6, 0022-3727/31/5/011/img7O and small amounts of NO, 0022-3727/31/5/011/img4 and optionally 0022-3727/31/5/011/img9H0022-3727/31/5/011/img10 (ethene). The results of the calculations are compared with our experimental data. Quantitative analysis of the reaction turnovers allows the identification of the main chemical pathways. Most of the conversion of 0022-3727/31/5/011/img2 is due to oxidation and only a small fraction is caused by chemical reduction. The complete removal of NO can be achieved at an energy expense of 5 to 10 eV per NO molecule if 2000 ppmv 0022-3727/31/5/011/img9H0022-3727/31/5/011/img10 are present in the gas stream. If 0022-3727/31/5/011/img9H0022-3727/31/5/011/img10 is not present 60 eV/NO are needed.

  6. Ozone correlates with antibacterial effects from indirect air dielectric barrier discharge treatment of water

    Science.gov (United States)

    Pavlovich, Matthew J.; Chang, Hung-Wen; Sakiyama, Yukinori; Clark, Douglas S.; Graves, David B.

    2013-04-01

    Ambient-condition air plasma produced by indirect dielectric barrier discharges can rapidly disinfect aqueous solutions contaminated with bacteria and other microorganisms. In this study, we measured key chemical species in plasma-treated aqueous solutions and the associated antimicrobial effect for varying discharge power densities, exposure times, and buffer components in the aqueous medium. The aqueous chemistry corresponded to air plasma chemistry, and we observed a transition in composition from ozone mode to nitrogen oxides mode as the discharge power density increased. The inactivation of E. coli correlates well with the aqueous-phase ozone concentration, suggesting that ozone is the dominant species for bacterial inactivation under these conditions. Published values of ozone-water antibacterial inactivation kinetics as a function of the product of ozone concentration and contact time are consistent with our results. In contrast to earlier studies of plasma-treated water disinfection, ozone-dependent bacterial inactivation does not require acidification of the aqueous medium and the bacterial inactivation rates are far higher. Furthermore, we show that the antimicrobial effect depends strongly on gas-liquid mixing following plasma treatment, apparently because of the low solubility of ozone and the slow rate of mass transfer from the gas phase to the liquid. Without thorough mixing of the ozone-containing gas and bacteria-laden water, the antimicrobial effect will not be observed. However, it should be recognized that the complexity of atmospheric pressure plasma devices, and their sensitivity to subtle differences in design and operation, can lead to different results with different mechanisms.

  7. Electron current extraction from radio frequency excited micro-dielectric barrier discharges

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jun-Chieh; Kushner, Mark J. [Electrical Engineering and Computer Science Department, University of Michigan, 1301 Beal Ave., Ann Arbor, Michigan 48109 (United States); Leoni, Napoleon; Birecki, Henryk; Gila, Omer [Hewlett Packard Research Labs, Palo Alto, California 94304 (United States)

    2013-01-21

    Micro dielectric barrier discharges (mDBDs) consist of micro-plasma devices (10-100 {mu}m diameter) in which the electrodes are fully or partially covered by dielectrics, and often operate at atmospheric pressure driven with radio frequency (rf) waveforms. In certain applications, it may be desirable to extract electron current out of the mDBD plasma, which necessitates a third electrode. As a result, the physical structure of the m-DBD and the electron emitting properties of its materials are important to its operation. In this paper, results from a two-dimensional computer simulation of current extraction from mDBDs sustained in atmospheric pressure N{sub 2} will be discussed. The mDBDs are sandwich structures with an opening of tens-of-microns excited with rf voltage waveforms of up to 25 MHz. Following avalanche by electron impact ionization in the mDBD cavity, the plasma can be expelled from the cavity towards the extraction electrode during the part of the rf cycle when the extraction electrode appears anodic. The electron current extraction can be enhanced by biasing this electrode. The charge collection can be controlled by choice of rf frequency, rf driving voltage, and permittivity of the dielectric barrier.

  8. Fluorescence (TALIF) measurement of atomic hydrogen concentration in a coplanar surface dielectric barrier discharge

    Science.gov (United States)

    Mrkvičková, M.; Ráheľ, J.; Dvořák, P.; Trunec, D.; Morávek, T.

    2016-10-01

    Spatially and temporally resolved measurements of atomic hydrogen concentration above the dielectric of coplanar barrier discharge are presented for atmospheric pressure in 2.2% H2/Ar. The measurements were carried out in the afterglow phase by means of two-photon absorption laser-induced fluorescence (TALIF). The difficulties of employing the TALIF technique in close proximity to the dielectric surface wall were successfully addressed by taking measurements on a suitable convexly curved dielectric barrier, and by proper mathematical treatment of parasitic signals from laser-surface interactions. It was found that the maximum atomic hydrogen concentration is situated closest to the dielectric wall from which it gradually decays. The maximum absolute concentration was more than 1022 m-3. In the afterglow phase, the concentration of atomic hydrogen above the dielectric surface stays constant for a considerable time (10 μs-1 ms), with longer times for areas situated farther from the dielectric surface. The existence of such a temporal plateau was explained by the presented 1D model: the recombination losses of atomic hydrogen farther from the dielectric surface are compensated by the diffusion of atomic hydrogen from regions close to the dielectric surface. The fact that a temporal plateau exists even closest to the dielectric surface suggests that the dielectric surface acts as a source of atomic hydrogen in the afterglow phase.

  9. Experimental and computational study of dielectric barrier discharges for environmental applications

    Science.gov (United States)

    Aerts, Robby

    Air pollution has become a major global concern which affects all inhabitants of our precious earth. Nowadays it is fact that our climate is changing and the sea level is rising. Moreover, we are facing an energy crisis because all our fossil fuel resources will sooner or later be running empty. It is clear that drastic measures are needed to keep our planet as it is today for generations to come. One of these measures is the 20-20-20 targets imposed by the European Commission, which stimulates the research for environmental energy applications. In this PhD dissertation two environmental applications of plasma technology are investigated. The first one is the abatement of flue gases, and more specifically the destruction of volatile organic compounds (VOCs). The second one is the conversion of CO2 into valuable chemicals. Both of these applications suffer from a large energy cost under classical (thermodynamic) conditions, due to the chemical stability of these molecules. Plasma technology is quite promising to overcome these thermodynamic barriers. Plasmas allow reactions at different time-scales with different species, such as electrons, ions, radicals, molecules and excited species, creating new chemical pathways. Indeed, in a plasma the applied electrical energy is directly transferred to the electrons, which activate the gas by ionization, excitation and dissociation, hence creating reactive species (ions, excited species, radicals), that can further easily undergo other chemical reactions. Especially gas discharges, which are low temperature plasmas, show promising results in the destruction of pollutants at mild conditions. A common type of gas discharge is the dielectric barrier discharge (DBD) which has been successfully scaled up for industrial ozone generation and is widely investigated in the field of environmental applications. The complexity of DBDs creates difficulties for experimental diagnostics and therefore numerical studies can help to improve

  10. Effect of Duty Cycle on the Characteristics of Pulse-Modulhted Radio-Frequency Atmospheric Pressure Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    LI Xuechun; WANG Huan; DING Zhenfeng; WANG Younian

    2012-01-01

    Using a one-dimensional fluid model, the pulse-modulated radio-frequency dielectric barrier discharge in atmospheric helium is described. The influences of the pulse duty cycle on the discharge characteristics are studied. The numerical results show that the dependence of discharge characteristics on the duty cycle is sensitive in the region of around 40% duty cycle under the given simulation parameters. In the case of a larger duty cycle, the plasma density is higher, the discharge becomes more intense, but the power consumption is higher. When the duty cycle is lower, one can get a weaker discharge, lower plasma density and higher electron temperature in the bulk plasma. In practical applications, in order to get a higher plasma density and a lower power consumption, it is more important to choose a suitable duty cycle to modulate the RF power supply.

  11. [Plasma temperature of white-eye hexagonal pattern in dielectric barrier discharge].

    Science.gov (United States)

    Zhao, Yang; Dong, Li-fang; Fu, Hong-yan

    2015-01-01

    By using the water-electrode discharge experimental setup, the white-eye hexagonal pattern is firstly observed and investigated in the dielectric barrier discharge with the mixture of argon and air whose content can be varied whenever necessary, and the study shows that the white-eye cell is an interleaving of three different hexagonal sub-structures: the spot, the ring, and the halo. The white-eye hexagonal pattern has the excellent discharge stability and sustainability during the experiment. Pictures recorded by ordinary camera with long exposure time in the same argon content condition show that the spot, the ring, and the halo of the white-eye hexagonal pattern have different brightness, which may prove that their plasma states are different. And, it is worth noting that there are obvious differences not only on the brightness but also on the color of the white-eye cell in conditions of different argon content, which shows that its plasma state also changed with the variation of the argon content. The white-eye hexagonal pattern is observed at a lower applied voltage so that the temperature of the water electrodes almost keeps unchanged during the whole experiment, which is advantageous for the long term stable measurement. The plasma state will not be affected by the temperature of the electrodes during the continuous discharge. Based on the above phenomena, plasma temperatures of the spot, the ring, and the halo in white-eye hexagonal pattern including molecule vibrational temperature and variations of electron density at different argon content are investigated by means of optical emission spectroscopy (OES). The emission spectra of the N2 second positive band(C3Πu-->B3Πg)are measured, and the molecule vibrational temperature of the spot, the ring, and the halo of the white-eye hexagonal pattern are calculated by the emission intensities. Furthermore, emission spectra of Ar I (2P2-->1S5)is collected and the changes of its width with different argon

  12. Noise control of a flow around a cylinder using high-frequency dielectric barrier discharge plasma actuators

    Science.gov (United States)

    Kopiev, V. F.; Belyaev, I. V.; Zaytsev, M. Yu.; Kazansky, P. N.; Kopiev, V. A.; Moralev, I. A.

    2015-03-01

    The effect of high-frequency dielectric barrier discharge plasma actuators on the noise of a flow around a circular cylinder is experimentally studied. It is shown that the plasma actuators are able to reduce the vortex noise of a cylinder within the range of velocities typical for aeroacoustic applications.

  13. Effect of Cooling Methods on Methane Conversion via Dielectric-Barrier Discharges

    Institute of Scientific and Technical Information of China (English)

    WANG Baowei; YANG Kuanhui; XU Genhui

    2008-01-01

    Effects of cooling methods on stability and methane conversion rate using dielectricbarrier discharges (DBD) were systematically investigated in this article.The results showed that the methane conversion rate was as high as 44.43% in a pure methane system at a flow rate of 100 mL.min-1 and an input power of 234.2 W with air cooling.A dark greenish and soft film-like carbon was deposited on the outer surface of quartz tube when the outer electrode was watercooled,which decreased the methane conversion.With air cooling of inner electrode the selectivity of C2 hydrocarbons was higher than that with other cooling methods,while the C3 hydrocarbons had higher selectivity with flowing water cooling.Cooling the inner electrode could restrain the carbon deposition,but would decrease the methane conversion rate.The stability of both reaction and plasma operation can be improved through cooling the reactor.From thermodynamic analysis,it was found that the effective collisions frequency among the reactant molecules and free electrons (e-) increased with temperature,which in turn led to a higher methane conversion rate and a change in the distribution of products.

  14. Deactivation of Streptococcus mutans Biofilms on a Tooth Surface Using He Dielectric Barrier Discharge at Atmospheric Pressure

    Science.gov (United States)

    Imola, Molnar; Judit, Papp; Alpar, Simon; Sorin, Dan Anghel

    2013-06-01

    This paper presents a study of the effect of the low temperature atmospheric helium dielectric barrier discharge (DBD) on the Streptococcus mutans biofilms formed on tooth surface. Pig jaws were also treated by plasma to detect if there is any harmful effect on the gingiva. The plasma was characterized by using optical emission spectroscopy. Experimental data indicated that the discharge is very effective in deactivating Streptococcus mutans biofilms. It can destroy them with an average decimal reduction time (D-time) of 19 s and about 98% of them were killed after a treatment time of 30 s. According to the survival curve kinetic an overall 32 s treatment time would be necessary to perform a complete sterilization. The experimental results presented in this study indicated that the helium dielectric barrier discharge, in plan-parallel electrode configuration, could be a very effective tool for deactivation of oral bacteria and might be a promising technique in various dental clinical applications.

  15. Transmutation of minor actinides discharged from LMFBR spent fuel in a high power density fusion reactor

    Energy Technology Data Exchange (ETDEWEB)

    Uebeyli, Mustafa E-mail: mubeyli@gazi.edu.tr

    2004-12-01

    Significant amounts of nuclear wastes consisting of plutonium, minor actinides and long lived fission products are produced during the operation of commercial nuclear power plants. Therefore, the destruction of these wastes is very important with respect to public health, environment and also the future of nuclear energy. In this study, transmutation of minor actinides (MAs) discharged from LMFBR spent fuel in a high power density fusion reactor has been investigated under a neutron wall load of 10 MW/m{sup 2} for an operation period of 10 years. Also, the effect of MA percentage on the transmutation has been examined. The fuel zone, containing MAs as spheres cladded with W-5Re, has been located behind the first wall to utilize the high neutron flux for transmutation effectively. Helium at 40 atm has been used as an energy carrier. At the end of the operation period, the total burning and transmutation are greater than the total buildups in all investigated cases, and very high burnups (420-470 GWd/tHM) are reached, depending on the MA content. The total transmutation rate values are 906 and 979 kg/GW{sub th} year at startup and decrease to 140 and 178 kg/GW{sub th} year at the end of the operation for fuel with 10% and 20% MA, respectively. Over an operation period of 10 years, the effective half lives decrease from 2.38, 2.21 and 3.08 years to 1.95, 1.80 and 2.59 years for {sup 237}Np, {sup 241}Am and {sup 243}Am, respectively. Total atomic densities decrease exponentially during the operation period. The reductions in the total atomic densities with respect to the initial ones are 79%, 81%, 82%, 83%, 85% and 86% for 10%, 12%, 14%, 16%, 18% and 20% MAs, respectively.

  16. Dielectric Barrier Discharge (DBD) Plasma Actuators Thrust-Measurement Methodology Incorporating New Anti-Thrust Hypothesis

    Science.gov (United States)

    Ashpis, David E.; Laun, Matthew C.

    2014-01-01

    We discuss thrust measurements of Dielectric Barrier Discharge (DBD) plasma actuators devices used for aerodynamic active flow control. After a review of our experience with conventional thrust measurement and significant non-repeatability of the results, we devised a suspended actuator test setup, and now present a methodology of thrust measurements with decreased uncertainty. The methodology consists of frequency scans at constant voltages. The procedure consists of increasing the frequency in a step-wise fashion from several Hz to the maximum frequency of several kHz, followed by frequency decrease back down to the start frequency of several Hz. This sequence is performed first at the highest voltage of interest, then repeated at lower voltages. The data in the descending frequency direction is more consistent and selected for reporting. Sample results show strong dependence of thrust on humidity which also affects the consistency and fluctuations of the measurements. We also observed negative values of thrust or "anti-thrust", at low frequencies between 4 Hz and up to 64 Hz. The anti-thrust is proportional to the mean-squared voltage and is frequency independent. Departures from the parabolic anti-thrust curve are correlated with appearance of visible plasma discharges. We propose the anti-thrust hypothesis. It states that the measured thrust is a sum of plasma thrust and anti-thrust, and assumes that the anti-thrust exists at all frequencies and voltages. The anti-thrust depends on actuator geometry and materials and on the test installation. It enables the separation of the plasma thrust from the measured total thrust. This approach enables more meaningful comparisons between actuators at different installations and laboratories. The dependence on test installation was validated by surrounding the actuator with a large diameter, grounded, metal sleeve.

  17. Surface modification of acrylate intraocular lenses with dielectric barrier discharge plasma at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    WANG Yao; LIU ZhenMei; XU ZhiKang; YAO Ke

    2009-01-01

    Surface modification with dielectric barrier discharge (DBD) plasma was carried out at atmospheric pressure (argon as the discharge gas) to improve the biocompatibility of hydrophobic acrylate intraocular lens (IOL). Changes of the plasma-treated IOL surface in chemical composition,morphology and hydrophilicity were comprehensively evaluated by X-ray photoelectron spectroscopy (XPS),field emission scanning electron microscopy (FESEM),atomic force microscopy (AFM) and water contact angle (WCA) measurements. The surface biocompatibility of the untreated and plasma-treated IOLs was compared with the adhesion behavior of platelets,macrophages and lens epithelial cells (LECs) in vitro. After DBD plasma treatment,the hydrophilicity of the IOL surface was obviously improved. The changes in WCA with treatment extension may be attributed to both the introduction of oxygen or/and nitrogen-containing polar groups and the increase of surface roughness induced by plasma etching effect. The existence of low molecular weight oxidized material (LMWOM) was proved on the plasma treated IOL which was caused by the chain scission effect of the plasma treatment. The plasma-treated lOLs resisted the adhesion of platelets and macrophages significantly. The LECs spreading and proliferation were postponed on the lOLs plasma-treated for more than 180 s,with a well maintained epithelial phenotype of LECs. The IOL biocompatibility was improved after the DBD plasma treatment. We speculate that slighter foreign-body reaction and later incidence of anterior capsule opacification (ACO) may be expected after implantation of the argon DBD plasma-treated IOL.

  18. Surface modification of acrylate intraocular lenses with dielectric barrier discharge plasma at atmospheric pressure

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Surface modification with dielectric barrier discharge(DBD) plasma was carried out at atmospheric pressure(argon as the discharge gas) to improve the biocompatibility of hydrophobic acrylate intraocular lens(IOL).Changes of the plasma-treated IOL surface in chemical composition,morphology and hydrophilicity were comprehensively evaluated by X-ray photoelectron spectroscopy(XPS),field emission scanning electron microscopy(FESEM),atomic force microscopy(AFM) and water contact angle(WCA) measurements.The surface biocompatibility of the untreated and plasma-treated IOLs was compared with the adhesion behavior of platelets,macrophages and lens epithelial cells(LECs) in vitro.After DBD plasma treatment,the hydrophilicity of the IOL surface was obviously improved.The changes in WCA with treatment extension may be attributed to both the introduction of oxygen or/and nitrogen-containing polar groups and the increase of surface roughness induced by plasma etching effect.The existence of low molecular weight oxidized material(LMWOM) was proved on the plasma-treated IOL which was caused by the chain scission effect of the plasma treatment.The plasma-treated IOLs resisted the adhesion of platelets and macrophages significantly.The LECs spreading and proliferation were postponed on the IOLs plasma-treated for more than 180 s,with a well maintained epithelial phenotype of LECs.The IOL biocompatibility was improved after the DBD plasma treatment.We speculate that slighter foreign-body reaction and later incidence of anterior capsule opacification(ACO) may be expected after implantation of the argon DBD plasma-treated IOL.

  19. One-equation modeling and validation of dielectric barrier discharge plasma actuator thrust

    Science.gov (United States)

    Yoon, Jae-San; Han, Jae-Hung

    2014-10-01

    Dielectric barrier discharge (DBD) plasma actuators with an asymmetric electrode configuration can generate a wall-bounded jet without mechanical moving parts, which require considerable modifications of existing aeronautical objects and which incur high maintenance costs. Despite this potential, one factor preventing the wider application of such actuators is the lack of a reliable actuator model. It is difficult to develop such a model because calculating the ion-electric field and fluid interaction consume a high amount calculation effort during the numerical analysis. Thus, the authors proposed a semi-empirical model which predicted the thrust of plasma actuators with a simple equation. It gave a numeric thrust value, and we implemented the value on a computational fluid dynamics (CFD) solver to describe the two-dimensional flow field induced by the actuator. However, the model had a narrow validation range, depending on the empirical formula, and it did not fully consider environment variables. This study presents an improved model by replacing the empirical formulae in the previous model with physical equations that take into account physical phenomena and environmental variables. During this process, additional operation parameters, such as pressure, temperature and ac waveforms, are newly taken to predict the thrust performance of the actuators with a wider range of existing parameters, the thickness of the dielectric barrier, the exposed electrode, the dielectric constant, the ac frequency and the voltage amplitude. Thrust prediction curves from the model are compared to those of earlier experimental results, showing that the average error is less than 5% for more than one hundred instances of data. As in the earlier work, the predicted thrust value is implemented on a CFD solver, and two-dimensional wall-jet velocity profiles induced by the actuator are compared to the previous experimental results.

  20. CO2 Dissociation using the Versatile Atmospheric Dielectric Barrier Discharge Experiment (VADER

    Directory of Open Access Journals (Sweden)

    Michael Allen Lindon

    2014-09-01

    Full Text Available Dissociation of CO2 is investigated in an atmospheric pressure dielectric barrier discharge (DBD with a simple, zero dimensional (0-D chemical model and through experiment. The model predicts that the primary CO2 dissociation pathway within a DBD is electron impact dissociation and electron-vibrational excitation. The relaxation kinetics following dissociation are dominated by atomic oxygen chemistry. The experiments included investigating the energy efficiencies and dissociation rates of CO2 within a planar DBD, while the gas flow rate, voltage, gas composition, driving frequency, catalyst, and pulse modes were varied. Some of the VADER results include a maximum CO2 dissociation energy efficiency of 2.5 +/- 0.5%, a maximum CO$_2$ dissociation rate of 4 +/- 0.4*10^-6 mol CO2/s (5 +/- 0.5% percent dissociation, discovering that a resonant driving frequency of ~30 kHz, dependent on both applied voltage and breakdown voltage, is best for efficient CO2 dissociation and that TiO2, a photocatalyst, improved dissociation efficiencies by an average of 18% at driving frequencies above 5 kHz.

  1. Control of endwall secondary flow in a compressor cascade with dielectric barrier discharge plasma actuation

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Three dielectric barrier discharge plasma actuators were mounted at the positions of 20%,40%and 60%of chord length on the endwall in a compressor cascade.The downstream flow field of the cascade has been measured with a mini five-hole pressure probe with and without the plasma actuation.The measured results show that the plasma actuation most effectively reduces total pressure loss and flow blockage when the actuators are operated simultaneously.As each of the actuators is operated independently,the actuator at the position of 20%of chord length most effectively reduces flow blockage, and the actuator at the position of 60%of chord length fairly reduces total pressure loss.However, negative pressure loss reduction occurs with the plasma actuator at the position of 40%of chord length.In brief,the plasma actuation placed on the endwall in the cascade apparently influences the endwall secondary flow,and the optimal locations and strength of actuation are critical for the control of endwall secondary flow in a compressor cascade with the plasma actuators.

  2. Saffman-Taylor-like instability in a narrow gap induced by dielectric barrier discharge

    Science.gov (United States)

    Hou, Shang-Yan; Chu, Hong-Yu

    2015-07-01

    This work is inspired by the expansion of the plasma bubble in a narrow gap reported by Chu and Lee [Phys. Rev. Lett. 107, 225001 (2011)], 10.1103/PhysRevLett.107.225001. We report the unstable phenomena of the plasma-liquid interface with different curvature in a Hele-Shaw cell. Dielectric barrier discharge is produced in the cell at atmospheric pressure which is partially filled with silicone oil. We show that the Saffman-Taylor-like instability is observed on the bubble-type, channel-type, and drop-type interfaces. The Schlieren observation of the plasma-drop interaction reveals that there is a vapor layer around the drop and the particle image velocimetry shows the liquid flow inside the drop. We propose that the thermal Marangoni effect induced by the plasma heating is responsible for the unstable phenomena of the plasma-liquid interaction. The fluctuation of the interface is shown consistently with the Saffman-Taylor instability modified by the temperature-dependent velocity and surface tension.

  3. Electrical and optical characterization of an atmospheric pressure, uniform, large-area processing, dielectric barrier discharge

    Science.gov (United States)

    Zeniou, A.; Puač, N.; Škoro, N.; Selaković, N.; Dimitrakellis, P.; Gogolides, E.; Petrović, Z. Lj

    2017-04-01

    A printed-circuit-board (PCB) based atmospheric pressure dielectric barrier discharge (DBD) capable of uniform processing over a large area was constructed consisting of two parallel plates. The first perforated plate is comprised of four layers: a RF powered metal layer, a polymeric dielectric layer, a floating metal grid and another dielectric layer. The second, grounded, plate was fluorine doped tin oxide (FTO) glass plate with surface of 100  ×  100 mm2 and thickness of 2 mm. The PCB based atmospheric pressure DBD was characterized by (a) measuring electrical characteristics of the device using derivative I-V probes, (b) ICCD imaging and (c) optical emission spectroscopy (OES). Optical and electrical characteristics, as well as plasma uniformity were measured by changing He flow rate and input power, while keeping the gap between the PCB and the FTO glass plate ground electrode constant at 2 mm. The plasma uniformity strongly depends on the applied power and on the flow rate of the buffer gas. When increasing the flow rate, the intensity of the nitrogen-dominated emission drops, while emission of helium and oxygen lines increases. The source allows low temperature, uniform plasma operation over a wide area of 100  ×  100 mm2, which could be essential for numerous applications. Examples of etching rate and hydrophilization are demonstrated.

  4. Plasma activated dissociation of CO2 studied in a dielectric barrier discharge

    Science.gov (United States)

    Engeln, Richard; Brehmer, Florian; Welzel, Stefan; Klarenaar, Bart; van de Sanden, Richard; Tu/E Collaboration; Afs Gmbh Collaboration; Differ Collaboration

    2014-10-01

    The ever-increasing emission of carbon dioxide into the atmosphere as well as the intermittency problem of electricity produced by renewable energy sources are challenges that urgently need to be addressed. An approach addressing both issues at the same time is converting CO2 to a fuel using plasma driven by electricity from renewable sources. We will present in this contribution the results of a study on the conversion of CO2 to CO in a dielectric barrier discharge in pure CO2 at pressures up to 1000 mbar: FTIR absorption and Raman spectroscopy were applied to measure CO number densities and gas temperatures as function of the specific injected energy. CO densities with a maximum at 1018 cm-3 (mixing ratio of 4.4%) at 46 kJ/sl, energy efficiencies in the range of a few percent and gas temperatures up to 550 K were detected. The CO production is directly linked with the total number of transferred charges q during the residence time tres of CO2 molecules. Also ozone has been detected with a maximum mixing ratio of 0.075%.

  5. Atomic oxygen characteristics in a dielectric barrier discharge developed for wound treatment

    Science.gov (United States)

    Baldus, Sabrina; Schroeder, Daniel; Schulz-von der Gathen, Volker; Bibinov, Nikita; Awakowicz, Peter

    2014-10-01

    Nowadays, infected chronic wounds are a major problem of society. Atmospheric pressure plasmas like dielectric barrier discharges (DBDs) have already shown their ability of improving the wound healing process of chronic wounds in clinical trials. Yet, the mechanism of action is poorly understood. A DBD comprising a single driven electrode is a beneficial configuration for wound treatment. The patient itself functions as the counter electrode. Hence, reactive oxygen species (ROS) like ozone or atomic oxygen produced in the plasma reach the wound directly. Some ROS, including superoxide or nitric oxide, are produced by skin cells to repulse invading bacteria. Nevertheless, a very high amount of ROS leads to oxidative stress and can cause cell damage or even cell death. Therefore it is crucial to have a well characterized plasma for effective wound treatment. Plasma parameters are determined using absolutely calibrated optical emission spectroscopy. Density of atomic oxygen is measured applying xenon-calibrated two photon absorption laser induced fluorescence spectroscopy. A simulation of the afterglow chemistry, developed to gain insight in the characteristics of the atomic oxygen and its flux towards the treated surface, is cross-checked with measurement results. Work supported by the German Research Foundation within PAK816.

  6. Miniature Dielectric Barrier Discharge Nonthermal Plasma Induces Apoptosis in Lung Cancer Cells and Inhibits Cell Migration

    Science.gov (United States)

    Eisenmann, Kathryn M.

    2017-01-01

    Traditional cancer treatments like radiotherapy and chemotherapy have drawbacks and are not selective for killing only cancer cells. Nonthermal atmospheric pressure plasmas with dielectric barrier discharge (DBD) can be applied to living cells and tissues and have emerged as novel tools for localized cancer therapy. The purpose of this study was to investigate the different effects caused by miniature DBD (mDBD) plasma to A549 lung cancer cells. In this study, A549 lung cancer cells cultured in 12 well plates were treated with mDBD plasma for specified treatment times to assess the changes in the size of the area of cell detachment, the viability of attached or detached cells, and cell migration. Furthermore, we investigated an innovative mDBD plasma-based therapy for localized treatment of lung cancer cells through apoptotic induction. Our results indicate that plasma treatment for 120 sec causes apoptotic cell death in 35.8% of cells, while mDBD plasma treatment for 60 sec, 30 sec, or 15 sec causes apoptotic cell death in 20.5%, 14.1%, and 6.3% of the cell population, respectively. Additionally, we observed reduced A549 cell migration in response to mDBD plasma treatment. Thus, mDBD plasma system can be a viable platform for localized lung cancer therapy. PMID:28243603

  7. Low-Power Miniaturized Helium Dielectric Barrier Discharge Photoionization Detectors for Highly Sensitive Vapor Detection.

    Science.gov (United States)

    Zhu, Hongbo; Zhou, Menglian; Lee, Jiwon; Nidetz, Robert; Kurabayashi, Katsuo; Fan, Xudong

    2016-09-06

    This paper presents the design, fabrication, and characterization of a microhelium dielectric barrier discharge photoionization detector (μHDBD-PID) on chip with dimensions of only ∼15 mm × ∼10 mm × ∼0.7 mm and weight of only ∼0.25 g. It offers low power consumption (4 orders of magnitude), and maintenance-free operation. Furthermore, the μHDBD-PID can be driven with a miniaturized (∼5 cm × ∼2.5 cm × ∼2.5 cm), light (22 g), and low cost (∼$2) power supply with only 1.5 VDC input. The dependence of the μHDBD-PID performance on bias voltage, auxiliary helium flow rate, carrier gas flow rate, and temperature was also systematically investigated. Finally, the μHDBD-PID was employed to detect permanent gases and a sublist of the EPA 8260 standard reagents that include 51 analytes. The μHDBD-PID developed here can have a broad range of applications in portable and microgas chromatography systems for in situ, real-time, and sensitive gas analysis.

  8. Inactivation of soybean trypsin inhibitor by dielectric-barrier discharge (DBD) plasma.

    Science.gov (United States)

    Li, Junguang; Xiang, Qisen; Liu, Xiufang; Ding, Tian; Zhang, Xiangsheng; Zhai, Yafei; Bai, Yanhong

    2017-10-01

    Soybean trypsin inhibitor (STI) is considered as one of the most important anti-nutritional factors in soybeans. The objective of this study was to investigate the impacts and underling mechanisms of dielectric-barrier discharge (DBD) plasma on STI activities. The results shown that DBD plasma treatment significantly induced the inactivation of STI in soymilk and Kunitz-type trypsin inhibitor from soybean (SKTI) in a model system. After exposure to DBD plasma at 51.4W for 21min, the STI activities of soymilk were reduced by 86.1%. Affter being treated by DBD plasma, the intrinsic fluorescence and surface hydrophobicity of SKTI were significantly decreased, while the sulfhydryl contents were increased. It is assumed that DBD plasma-induced conformational changes and oxidative modification might contribute to the inactivation of SKTI. In summary, DBD plasma technology is a potential alternative to heat treatment for the inactivation of anti-nutritional substances in food legumes. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Atomic oxygen dynamics in an air dielectric barrier discharge: a combined diagnostic and modeling approach

    Science.gov (United States)

    Baldus, Sabrina; Schröder, Daniel; Bibinov, Nikita; Schulz-von der Gathen, Volker; Awakowicz, Peter

    2015-06-01

    Cold atmospheric pressure plasmas are a promising alternative therapy for treatment of chronic wounds, as they have already shown in clinical trials. In this study an air dielectric barrier discharge (DBD) developed for therapeutic use in dermatology is characterized with respect to the plasma produced reactive oxygen species, namely atomic oxygen and ozone, which are known to be of great importance to wound healing. To understand the plasma chemistry of the applied DBD, xenon-calibrated two-photon laser-induced fluorescence spectroscopy and optical absorption spectroscopy are applied. The measured spatial distributions are shown and compared to each other. A model of the afterglow chemistry based on optical emission spectroscopy is developed to cross-check the measurement results and obtain insight into the dynamics of the considered reactive oxygen species. The atomic oxygen density is found to be located mostly between the electrodes with a maximum density of {{n}\\text{O}}=6× {{10}16} cm-3 . Time resolved measurements reveal a constant atomic oxygen density between two high voltage pulses. The ozone is measured up to 3 mm outside the active plasma volume, reaching a maximum value of {{n}{{\\text{O}3}}}=3× {{10}16} cm-3 between the electrodes.

  10. Intracellular electric fields produced by dielectric barrier discharge treatment of skin

    Energy Technology Data Exchange (ETDEWEB)

    Babaeva, Natalia Yu; Kushner, Mark J, E-mail: nbabaeva@umich.ed, E-mail: mjkush@umich.ed [University of Michigan, Department of Electrical Engineering and Computer Science, 1301 Beal Ave., Ann Arbor, MI 48109 (United States)

    2010-05-12

    The application of atmospheric pressure plasmas to human tissue has been shown to have therapeutic effects for wound healing and in treatment of skin diseases. These effects are attributed to both production of beneficial radicals which intersect with biological reaction chains and to the surface and intracellular generation of electric fields. In this paper, we report on computational studies of the intersection of plasma streamers in atmospheric pressure dielectric barrier discharges (DBDs) sustained in air with human skin tissue, with emphasis on the intracellular generation of electric fields. Intracellular structures and their electrical properties were incorporated into the computational mesh in order to self-consistently couple gas phase plasma transport with the charging of the surface of the skin and the intracellular production of electrical currents. The short duration of a single plasma filament in DBDs and its intersection with skin enables the intracellular penetration of electric fields. The magnitude of these electric fields can reach 100 kV cm{sup -1} which may exceed the threshold for electroporation.

  11. Spectroscopic Study of Plasma Polymerized a-C:H Films Deposited by a Dielectric Barrier Discharge

    Directory of Open Access Journals (Sweden)

    Thejaswini Halethimmanahally Chandrashekaraiah

    2016-07-01

    Full Text Available Plasma polymerized a-C:H thin films have been deposited on Si (100 and aluminum coated glass substrates by a dielectric barrier discharge (DBD operated at medium pressure using C2Hm/Ar (m = 2, 4, 6 gas mixtures. The deposited films were characterized by Fourier transform infrared reflection absorption spectroscopy (FT-IRRAS, Raman spectroscopy, and ellipsometry. FT-IRRAS revealed the presence of sp3 and sp2 C–H stretching and C–H bending vibrations of bonds in the films. The presence of D and G bands was confirmed by Raman spectroscopy. Thin films obtained from C2H4/Ar and C2H6/Ar gas mixtures have ID/IG ratios of 0.45 and 0.3, respectively. The refractive indices were 2.8 and 3.1 for C2H4/Ar and C2H6/Ar films, respectively, at a photon energy of 2 eV.

  12. EHD-driven mass transport enhancement in surface dielectric barrier discharges

    Science.gov (United States)

    Taglioli, M.; Shaw, A.; Wright, A.; FitzPatrick, B.; Neretti, G.; Seri, P.; Borghi, C. A.; Iza, F.

    2016-12-01

    Surface dielectric barrier discharges (S-DBDs) have received renewed attention in recent years for their potential application in emerging biomedical, environmental and agricultural applications. In most of these applications, the plasma is not in direct contact with the substrate being treated and the transport of reactive species from the plasma to the substrate is typically assumed to be controlled by diffusion. Here, we demonstrate that generally this is not the case and that electrohydrodynamic (EHD) forces can produce jets that enhance the delivery of these species, thereby influencing the efficacy of the S-DBD device. In particular, we have studied the degradation of potassium indigotrisulfonate solutions exposed to S-DBDs generated in devices with annular electrodes of diameters varying between 10 mm and 50 mm. All the devices were driven at constant linear power density (watts per cm of plasma length) and although local plasma properties remained the same in all the devices, a three-fold efficacy enhancement was observed for devices of diameter ~30 mm due to EHD effects.

  13. Effect of Inert Gases on Ozone Generation Using Dielectric Barrier Discharge in Oxygen

    Institute of Scientific and Technical Information of China (English)

    WEI Linsheng; TAN Zhihong

    2012-01-01

    This paper reports the results of an experimental study of the effect of inert gases He, Ar and Kr on ozone generation in a Dielectric Barrier Discharge (DBD) fed by pure oxygen. The chemical reaction mechanisms related to the process of ozone generation are discussed. The experimental results show that ozone concentration decrease with decreasing oxygen content in all He+ 02, Ar+02 and Kr + O2 mixtures mainly owing to the decrease of oxygen content. The conversion ratio of oxygen into ozone increases with increasing oxygen content in He+O2 mixtures, but the addition of Ar and Kr can improve the conversion ratio due to the increase of free electrons density and excited oxygen molecules required for ozone formation through ionization and Penning effect. The effect of Kr is more significant for the lower first ionization energy of metastable state compared with other gases. It is probable that the ozone concentration, and ozone production efficiency increase with Kr addition when the reduced electric field and mean electron energy are high enough.

  14. Gene Transfection Method Using Atmospheric Pressure Dielectric-Barrier Discharge Plasmas

    Science.gov (United States)

    Sasaki, Shota; Kanzaki, Makoto; Kaneko, Toshiro

    2013-09-01

    Gene transfection which is the process of deliberately introducing nucleic acids into cells is expected to play an important role in medical treatment because the process is necessary for gene therapy and creation of induced pluripotent stem (iPS) cells. However, the conventional transfection methods have some problems, so we focus attention on promising transfection methods by atmospheric pressure dielectric-barrier discharge (AP-DBD) plasmas. AP-DBD He plasmas are irradiated to the living cell covered with genes. Preliminarily, we use fluorescent dye YOYO-1 instead of the genes and use LIVE/DEAD Stain for cell viability test, and we analyze the transfection efficiency and cell viability under the various conditions. It is clarified that the transfection efficiency is strongly dependence on the plasma irradiation time and cell viability rates is high rates (>90%) regardless of long plasma irradiation time. These results suggest that ROS (Reactive Oxygen Species) and electric field generated by the plasma affect the gene transfection. In addition to this (the plasma irradiation time) dependency, we now investigate the effect of the plasma irradiation under the various conditions.

  15. Intracellular electric fields produced by dielectric barrier discharge treatment of skin

    Science.gov (United States)

    Babaeva, Natalia Yu; Kushner, Mark J.

    2010-05-01

    The application of atmospheric pressure plasmas to human tissue has been shown to have therapeutic effects for wound healing and in treatment of skin diseases. These effects are attributed to both production of beneficial radicals which intersect with biological reaction chains and to the surface and intracellular generation of electric fields. In this paper, we report on computational studies of the intersection of plasma streamers in atmospheric pressure dielectric barrier discharges (DBDs) sustained in air with human skin tissue, with emphasis on the intracellular generation of electric fields. Intracellular structures and their electrical properties were incorporated into the computational mesh in order to self-consistently couple gas phase plasma transport with the charging of the surface of the skin and the intracellular production of electrical currents. The short duration of a single plasma filament in DBDs and its intersection with skin enables the intracellular penetration of electric fields. The magnitude of these electric fields can reach 100 kV cm-1 which may exceed the threshold for electroporation.

  16. Removal of cyanobacteria from synthetic and real water by dielectric barrier discharge process.

    Science.gov (United States)

    Zhang, Yi; Chew, Stephanie Ting Yu; Te, Shu Harn; Lim, Tuti Mariana

    2015-12-01

    The feasibility of cyanobacteria removal from freshwater by a dielectric barrier discharge (DBD) process is investigated. Seven commercial and environmental cyanobacteria strains, as well as real algae-laden water, were tested. The removal of the cyanobacteria was evaluated by analyzing the changes in chlorophyll a content, total organic carbon (TOC) concentration, and cell morphology. Nearly total removal of chlorophyll a was achieved within 20 min, while the TOC analysis exhibited an increase-decrease-increase trend in 60 min of treatment, likely due to the oxidation of intracellular and intercellular materials. Observation under light microscopy revealed the disruption of intracellular and intercellular structures within 5 min of DBD treatment and thus supported the TOC analysis. Increasing the salinity of the medium from 0 to 5 parts per thousand (ppt) improved treatment efficiency, where similar level of chlorophyll a removal (around 93%) was achieved in only half the treatment time. Application of DBD on real algae-laden water from a fish farm yielded higher treatment efficiency than in synthetic medium, indicating the promising application of DBD as a means to control cyanobacteria bloom in fresh and estuary water bodies.

  17. Active species delivered by dielectric barrier discharge filaments to bacteria biofilms on the surface of apple

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, He; Liu, Xin; Lu, Xinpei [State Key Lab of Advanced Electromagnetic Engineering and Technology, Huazhong University of Science and Technology, WuHan, HuBei (China); IFSA Collaborative Innovation Center, Shanghai Jiao Tong University, Shanghai 200240 (China); Liu, Dawei, E-mail: ldw636@msn.com [State Key Lab of Advanced Electromagnetic Engineering and Technology, Huazhong University of Science and Technology, WuHan, HuBei (China); IFSA Collaborative Innovation Center, Shanghai Jiao Tong University, Shanghai 200240 (China); State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an (China)

    2016-07-15

    The atmospheric pressure non-equilibrium plasma has shown a significant potential as a novel food decontamination technology. In this paper, we report a computational study of the intersection of negative streamer produced by air dielectric barrier discharge with bacteria biofilm on an apple surface. The structure, conductivities, and permittivities of bacteria biofilm have been considered in the Poisson's equations and transportation equations of charge and neutral species to realize self-consistent transportation of plasma between electrode and charging surfaces of apple. We find that the ionization near the biofilm facilitates the propagation of negative streamer when the streamer head is 1 mm from the biofilm. The structure of the biofilm results in the non-uniform distribution of ROS and RNS captured by flux and time fluence of these reactive species. The mean free path of charged species in μm scale permitted the plasma penetrate into the cavity of the biofilm, therefore, although the density of ROS and RNS decrease by 6–7 order of magnitude, the diffusion results in the uniform distribution of ROS and RNS inside the cavity during the pulse off period.

  18. Surface Modification of Fluororubber Using Atmospheric Pressure Dielectric Barrier Discharge (DBD)

    Institute of Scientific and Technical Information of China (English)

    TONG Wei; LU Canhui; CAI Yongkun; HUANG Yigang

    2007-01-01

    Fluoride rubber F2311 film, an alternating copolymer of CF2-CFC1 (CTFE) and CH2-CF2 (VF2) components, was treated by atmospheric pressure dielectric barrier discharge (DBD) in air. The surface structure, topography and surface chemistry of the treated F2311 films were characterized by contact angle measurement, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS), respectively. The experimental results showed that a short time air plasma treatment led to morphological, wettability and chemical changes in the F2311 films. The surface hydrophilicity increased greatly after the plasma treatment, the static water contact angle decreased from 98.6° to 32°, and oxygen containing groups (C=O, O-C=O, etc. ) were introduced. Atomic force microscopy revealed that plasma produced by DBD etched F2311 films obviously. The roughness of the samples increased remarkably with the formation of peaks and valleys on the treated surfaces. The increased surface wettability may be correlated with both the introduction of hydrophilic groups due to air plasma oxidation of the surface and the change in surface morphology etched by DBD.

  19. Comparison Between Dielectric Barrier Discharge Plasma and Ozone Regenerations of Activated Carbon Exhausted with Pentachlorophenol

    Science.gov (United States)

    Qu, Guangzhou; Liang, Dongli; Qu, Dong; Huang, Yimei; Li, Jie

    2014-06-01

    In this study, two regeneration methods (dielectric barrier discharge (DBD) plasma and ozone (O3) regeneration) of saturated granular activated carbon (GAC) with pentachlorophenol (PCP) were compared. The results show that the two regeneration methods can eliminate contaminants from GAC and recover its adsorption properties to some extent. Comparing the DBD plasma with O3 regeneration, the adsorption rate and the capacity of the GAC samples after DBD plasma regeneration are greater than those after O3 regeneration. O3 regeneration decreases the specific surface area of GAC and increases the acidic surface oxygen groups on the surface of GAC, which causes a decrease in PCP on GAC uptake. With increasing regeneration cycles, the regeneration efficiencies of the two methods decrease, but the decrease in the regeneration efficiencies of GAC after O3 regeneration is very obvious compared with that after DBD plasma regeneration. Furthermore, the equilibrium data were fitted by the Freundlich and Langmuir models using the non-linear regression technique, and all the adsorption equilibrium isotherms fit the Langmuir model fairly well, which demonstrates that the DBD plasma and ozone regeneration processes do not appear to modify the adsorption process, but to shift the equilibrium towards lower adsorption concentrations. Analyses of the weight loss of GAC show that O3 regeneration has a lower weight loss than DBD plasma regeneration.

  20. Effects of hydrocarbon contamination on ozone generation with dielectric barrier discharges

    Science.gov (United States)

    Lopez, Jose L.; Vezzu, Guido; Freilich, Alfred; Paolini, Bernhard

    2013-08-01

    The increasing usage of the feed gases of lower grade liquid oxygen (LOX) containing higher levels of trace hydrocarbon impurities in dielectric barrier discharge (DBD) for ozone generation requires a better understanding of the kinetics of the by-product formation resulting from reactions involving these hydrocarbon impurities. As a case study of hydrocarbon impurities, the kinetics of CH4 conversion in DBDs and the subsequent HNO3 formation were investigated by means of gas-phase plasma diagnostics, supported by detailed process modeling, and extensive in-situ and ex-situ by-product analysis. The by-products formation in the plasma with the presence of CH4, were found to differ significantly in oxygen-fed generators as compared to generators fed with oxygen/nitrogen mixtures. The amount of HNO3 formed depends on the concentration of NOx formed in the plasma and the amount of CH4 that is converted, but not on the O3 concentration. In the present work we have investigated CH4 concentrations of up to 1.95 wt% of the feed gas. The rate of deterioration of the overall ozone generator performance was found to be affected by the concentration of nitrogen in the oxygen/nitrogen mixture.

  1. On the pulsating electric wind of a Single Dielectric Barrier Discharge (SDBD) plasma actuator

    Science.gov (United States)

    Vernet, Julie; Örlü, Ramis; Alfredsson, P. Henrik

    2014-11-01

    An experimental study is conducted on the electric wind produced by a Single Dielectric Barrier Discharge (SDBD) plasma actuator placed at the top of a half cylinder. Laser Doppler Velocimetry (LDV) measurements were performed and results show that increasing the driving voltage (6-16 kV peak-to-peak) and frequency (0.5-2 kHz) of the actuator increases the induced jet velocity (up to 4 m/s) and thus the momentum added by the actuator. The focus of the present study is on the phase-resolved behavior of the electric wind, in particular, its two strokes. Phase-averaged LDV data reveals that while the velocity during both strokes remains positive, there is nearly a factor of two in amplitude. The difference of behavior between the two strokes and its downstream and wall-normal evolution are mapped for various driving voltages. Results indicate that this difference is restricted to the vicinity of the actuator, thereby justifying the assumption of a steady force in simulations to model the induced force. The study is part of a larger investigation aiming at separation control on the A-pillar of a truck cabin. The support of the Swedish Energy Agency and SCANIA CV of the project Flow Research on Active and Novel Control Efficiency (FRANCE) is greatly acknowledged.

  2. Active species delivered by dielectric barrier discharge filaments to bacteria biofilms on the surface of apple

    Science.gov (United States)

    Cheng, He; Liu, Xin; Lu, Xinpei; Liu, Dawei

    2016-07-01

    The atmospheric pressure non-equilibrium plasma has shown a significant potential as a novel food decontamination technology. In this paper, we report a computational study of the intersection of negative streamer produced by air dielectric barrier discharge with bacteria biofilm on an apple surface. The structure, conductivities, and permittivities of bacteria biofilm have been considered in the Poisson's equations and transportation equations of charge and neutral species to realize self-consistent transportation of plasma between electrode and charging surfaces of apple. We find that the ionization near the biofilm facilitates the propagation of negative streamer when the streamer head is 1 mm from the biofilm. The structure of the biofilm results in the non-uniform distribution of ROS and RNS captured by flux and time fluence of these reactive species. The mean free path of charged species in μm scale permitted the plasma penetrate into the cavity of the biofilm, therefore, although the density of ROS and RNS decrease by 6-7 order of magnitude, the diffusion results in the uniform distribution of ROS and RNS inside the cavity during the pulse off period.

  3. Experimental Study on Inactivation of Bacterial Endotoxin by Using Dielectric Barrier Discharge

    Science.gov (United States)

    Shi, Xingmin; Li, Yaxi; Zhang, Guanjun; Ma, Yue; Shao, Xianjun

    2011-12-01

    The low-temperature plasma (LTP) generated by dielectric barrier discharge (DBD) was used to sterilize the E.coli endotoxin, which is usually difficult to kill by traditional methods. Three different concentrations of bacterial endotoxin (1 EU/mL, 0.5 EU/mL and 0.25 EU/mL) were treated by LTP for different time (20 s, 40 s and 60 s). Tachypleus amebocyte lysate (TAL) method was employed to detect the concentration variation of bacterial endotoxin before and after the plasma treatment, and endotoxic shock mice model was used to evaluate the inactivation effects of LTP on endotoxin for further study. Experimental results demonstrated that, DBD plasma can inactivate the bacterial endotoxin quickly and effectively, and when the LTP treatment time was increased, the concentrations of bacterial endotoxin decreased gradually (after 60 s plasma treatment, its inactivation effect was beyond the Chinese pharmacopoeia standard), and the average survival time of mice gradually extended. The possible inactivation mechanisms are proposed to be related to reactive oxygen species (ROSs).

  4. Improving Hydrophobicity of Glass Surface Using Dielectric Barrier Discharge Treatment in Atmospheric Air

    Institute of Scientific and Technical Information of China (English)

    FANG Zhi; QIU Yuchang; WANG Hui; E. KUFFEL

    2007-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in industrial applications, especially in material surface treatment. In this paper, the treatment of a glass surface for improving hydrophobicity using the non-thermal plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure in ambient air is conducted, and the surface properties of the glass before and after the DBD treatment are studied by using contact angle measurement, surface resistance measurement and wet flashover voltage tests. The effects of the applied voltage and time duration of DBD on the surface modification are studied, and the optimal conditions for the treatment are obtained. It is found that a layer of hydrophobic coating is formed on the glass surface after spraying a thin layer of silicone oil and undergoing the DBD treatment, and the improvement of hydrophobicity depends on DBD voltage and treating time. It seems that there exists an optimum treating time for a certain applied voltage of DBD during the surface treatment. The test results of thermal aging and chemical aging show that the hydrophobic layer has quite stable characteristics. The interaction mechanism between the DBD plasma and the glass surface is discussed. It is concluded that CH3 and large molecule radicals can react with the radicals in the glass surface to replace OH, and the hydrophobicity of the glass surface is improved accordingly.

  5. Beneficial and detrimental fatigue effects of dielectric barrier discharges on the piezoelectricity of polypropylene ferroelectrets

    Science.gov (United States)

    Qiu, Xunlin; Wirges, Werner; Gerhard, Reimund

    2011-07-01

    Cellular polypropylene (PP) ferroelectrets combine a large piezoelectricity with mechanical flexibility and elastic compliance. Their charging process represents a series of dielectric barrier discharges (DBDs) that generate a cold plasma with numerous active species and thus modify the inner polymer surfaces of the foam cells. Both the threshold for the onset of DBDs and the piezoelectricity of ferroelectrets are sensitive to repeated DBDs in the voids. It is found that the threshold voltage is approximately halved and the charging efficiency is clearly improved after only 103 DBD cycles. However, plasma modification of the inner surfaces from repeated DBDs deteriorates the chargeability of the voids, leading to a significant reduction of the piezoelectricity in ferroelectrets. After a significant waiting period, the chargeability of previously fatigued voids shows a partial recovery. The plasma modification is, however, detrimental to the stability of the deposited charges and thus also of the macroscopic dipoles and of the piezoelectricity. Fatigue from only 103 DBD cycles already results in significantly less stable piezoelectricity in cellular PP ferroelectrets. The fatigue rate as a function of the number of voltage cycles follows a stretched exponential. Fatigue from repeated DBDs can be avoided if most of the gas molecules inside the voids are removed via a suitable evacuation process.

  6. A Radical-Mediated Pathway for the Formation of [M + H]+ in Dielectric Barrier Discharge Ionization

    Science.gov (United States)

    Wolf, Jan-Christoph; Gyr, Luzia; Mirabelli, Mario F.; Schaer, Martin; Siegenthaler, Peter; Zenobi, Renato

    2016-09-01

    Active capillary plasma ionization is a highly efficient ambient ionization method. Its general principle of ion formation is closely related to atmospheric pressure chemical ionization (APCI). The method is based on dielectric barrier discharge ionization (DBDI), and can be constructed in the form of a direct flow-through interface to a mass spectrometer. Protonated species ([M + H]+) are predominantly formed, although in some cases radical cations are also observed. We investigated the underlying ionization mechanisms and reaction pathways for the formation of protonated analyte ([M + H]+). We found that ionization occurs in the presence and in the absence of water vapor. Therefore, the mechanism cannot exclusively rely on hydronium clusters, as generally accepted for APCI. Based on isotope labeling experiments, protons were shown to originate from various solvents (other than water) and, to a minor extent, from gaseous impurities and/or self-protonation. By using CO2 instead of air or N2 as plasma gas, additional species like [M + OH]+ and [M - H]+ were observed. These gas-phase reaction products of CO2 with the analyte (tertiary amines) indicate the presence of a radical-mediated ionization pathway, which proceeds by direct reaction of the ionized plasma gas with the analyte. The proposed reaction pathway is supported with density functional theory (DFT) calculations. These findings add a new ionization pathway leading to the protonated species to those currently known for APCI.

  7. Study of an Atmospheric Pressure Plasma Jet of Argon Generated by Column Dielectric Barrier Discharge

    Science.gov (United States)

    Nur, M.; Kinandana, A. W.; Winarto, P.; Muhlisin, Z.; Nasrudin

    2016-11-01

    An atmospheric of argon plasma jet was generated by using column dielectric barrier discharge has been investigated. In this study, argon gas was passed through the capillary column by regulating the flow rate of gas. This atmospheric pressure plasma jet (APPJ) was generated by a sinusoidal AC high voltage in the range of 0.4 kV to 10 kV and at frequencies of 15 kHz and 26 kHz. APPJ has been produced with flow rate of argon gas from 1 litter/min - 10 litters/min. The electric current has been taken with variation of voltage and each interval argon gas flow rate of 1 litter/min. The results show that electric current increase linearly and then it trends to saturation condition by the increasing of applied voltage. We found also that the length of the plasma jet increase by augmenting of applied voltage both for frequencies of 15 kHz and 26 kHz. Furthermore, our results show that length of plasma jet optimum for flow rate of argon gas of 2 litters/minute. In addition, we obtained that the larger applied voltage, the greater the temperature of the plasma jet.

  8. Design and testing of 45 kV, 50 kHz pulse power supply for dielectric barrier discharges.

    Science.gov (United States)

    Sharma, Surender Kumar; Shyam, Anurag

    2016-10-01

    The design, construction, and testing of high frequency, high voltage pulse power supply are reported. The purpose of the power supply is to generate dielectric barrier discharges for industrial applications. The power supply is compact and has the advantage of low cost, over current protection, and convenient control for voltage and frequency selection. The power supply can generate high voltage pulses of up to 45 kV at the repetitive frequency range of 1 kHz-50 kHz with 1.2 kW input power. The output current of the power supply is limited to 500 mA. The pulse rise time and fall time are less than 2 μs and the pulse width is 2 μs. The power supply is short circuit proof and can withstand variable plasma load conditions. The power supply mainly consists of a half bridge series resonant converter to charge an intermediate capacitor, which discharges through a step-up transformer at high frequency to generate high voltage pulses. Semiconductor switches and amorphous cores are used for power modulation at higher frequencies. The power supply is tested with quartz tube dielectric barrier discharge load and worked stably. The design details and the performance of the power supply on no load and dielectric barrier discharge load are presented.

  9. Physical and plasmachemical aspects of diffuse coplanar barrier discharge as a novel atmospheric-pressure plasma source

    Science.gov (United States)

    Cernak, M.; Kovacik, D.; Zahoranova, A.; Rahel, J.

    2008-07-01

    Collaborating Czech and Slovakian university teams have recently developed an innovative plasma source, the so-called Diffuse Coplanar Surface Barrier Discharge (DCSBD), which has the potential to move a step closer to the industry requirement for in-line treatment of low-added-value materials using a highly-nonequlibrium ambient air plasma (Simor et al. 2002, The idea is to generate a thin (on the order of 0.1 mm) layer of highly-nonequlibrium plasma with a high power density (up to 100 W/cm^3) in the immediate vicinity of the treated surface and bring it into a close contact with the treated surface. Comparing to atmospheric-pressure glow discharge, volume dielectric barrier discharge, and plasma jet plasmas, such a diffuse plasma layer is believed to provide substantial advantages in energy consumption, exposure time, and technical simplicity. A brief outline of physical mechanism and basic properties of DCSBD will given using the results of emission spectroscopy, high-speed camera, and spatially resolved cross-correlation spectroscopy studies. The presentation will review also a current state of the art in in-line plasma treatment of low-cost materials and opportunities for the use of the so-called Diffuse Coplanar Surface Dielectric Barrier Discharge (DCSBD). The results obtained on the ambient air plasma treatments of textile, paper, wood, and glass illustrate that DCSBD offers outstanding performance with extremely low energy consumption for large area, uniform surface modifications of materials under continuous process conditions.

  10. Characteristics of a micro-gap argon barrier discharge excited by a saw-tooth voltage at atmospheric pressure

    Science.gov (United States)

    Li, Xuechen; Zhang, Qi; Jia, Pengying; Chu, Jingdi; Zhang, Panpan; Dong, Lifang

    2017-03-01

    Using two water electrodes, a micro-gap dielectric barrier discharge excited by a saw-tooth voltage is investigated in atmospheric pressure argon. Through electrical and optical measurements, it is found that, at a lower driving frequency, a stepped discharge mode is obtained per half voltage cycle. Moreover, the duration and amplitude of the current plateau increase with the increase in the applied peak voltage. With the increase in the driving frequency, the stepped discharge mode transits into a pulsed one after a multi-peak mode. During this process, a diffuse discharge at a lower frequency transits into a filamentary one at a higher frequency. Temporal evolutions of the discharges are investigated axially based on fast photography. It is found that the stepped mode is in atmospheric pressure Townsend discharge (APTD) regime. However, there is a transition from APTD to atmospheric pressure glow discharge for the pulsed mode. Spectral intensity ratio of 391.4 nm to 337.1 nm is used to determine the averaged electron energy, which decreases with increasing peak voltage or driving frequency.

  11. Positioning of the Precursor Gas Inlet in an Atmospheric Dielectric Barrier Reactor, and its Effect on the Quality of Deposited TiOx Thin Film Surface

    Directory of Open Access Journals (Sweden)

    Jan Píchal

    2013-01-01

    Full Text Available Thin film technology has become pervasive in many applications in recent years, but it remains difficult to select the best deposition technique. A further consideration is that, due to ecological demands, we are forced to search for environmentally benign methods. One such method might be the application of cold plasmas, and there has already been a rapid growth in studies of cold plasma techniques. Plasma technologies operating at atmospheric pressure have been attracting increasing attention. The easiest way to obtain low temperature plasma at atmospheric pressure seems to be through atmospheric dielectric barrier discharge (ADBD. We used the plasma enhanced chemical vapour deposition (PECVD method applying atmospheric dielectric barrier discharge (ADBD plasmafor TiOx thin films deposition, employing titanium isopropoxide (TTIP and oxygen as reactants, and argon as a working gas. ADBD was operated in filamentary mode. The films were deposited on glass. We studied the quality of the deposited TiOx thin film surface for various precursor gas inlet positions in the ADBD reactor. The best thin films quality was achieved when the precursor gases were brought close to the substrate surface directly through the inlet placed in one of the electrodes.High hydrophilicity of the samples was proved by contact angle tests (CA. The film morphology was tested by atomic force microscopy (AFM. The thickness of the thin films varied in the range of (80 ÷ 210 nm in dependence on the composition of the reactor atmosphere. XPS analyses indicate that composition of the films is more like the composition of TiOxCy.

  12. Comparative study of NO removal in surface-plasma and volume-plasma reactors based on pulsed corona discharges.

    Science.gov (United States)

    Malik, Muhammad Arif; Kolb, Juergen F; Sun, Yaohong; Schoenbach, Karl H

    2011-12-15

    Nitric oxide (NO) conversion has been studied for two different types of atmospheric-pressure pulsed-corona discharges, one generates a surface-plasma and the other provides a volume-plasma. For both types of discharges the energy cost for NO removal increases with decreasing oxygen concentration and initial concentration of NO. However, the energy cost for volume plasmas for 50% NO removal, EC(50), from air was found to be 120 eV/molecule, whereas for the surface plasma, it was only 70 eV/molecule. A smaller difference in energy cost, but a higher efficiency for removal of NO was obtained in a pure nitrogen atmosphere, where NO formation is restricted due to the lack of oxygen. For the volume plasma, EC(50) in this case was measured at 50 eV/molecule, and for the surface plasma it was 40 eV/molecule. Besides the higher NO removal efficiency of surface plasmas compared to volume plasmas, the energy efficiency of surface-plasmas was found to be almost independent of the amount of electrical energy deposited in the discharge, whereas the efficiency for volume plasmas decreases considerably with increasing energy. This indicates the possibility of operating surface plasma discharges at high energy densities and in more compact reactors than conventional volume discharges.

  13. Comparative study of NO removal in surface-plasma and volume-plasma reactors based on pulsed corona discharges

    Energy Technology Data Exchange (ETDEWEB)

    Malik, Muhammad Arif, E-mail: MArifMalik@gmail.com [Frank Reidy Research Center for Bioelectrics, Old Dominion University, 4211 Monarch Way, Suite 300, Norfolk, VA 23508 (United States); Kolb, Juergen F.; Sun, Yaohong; Schoenbach, Karl H. [Frank Reidy Research Center for Bioelectrics, Old Dominion University, 4211 Monarch Way, Suite 300, Norfolk, VA 23508 (United States)

    2011-12-15

    Nitric oxide (NO) conversion has been studied for two different types of atmospheric-pressure pulsed-corona discharges, one generates a surface-plasma and the other provides a volume-plasma. For both types of discharges the energy cost for NO removal increases with decreasing oxygen concentration and initial concentration of NO. However, the energy cost for volume plasmas for 50% NO removal, EC{sub 50}, from air was found to be 120 eV/molecule, whereas for the surface plasma, it was only 70 eV/molecule. A smaller difference in energy cost, but a higher efficiency for removal of NO was obtained in a pure nitrogen atmosphere, where NO formation is restricted due to the lack of oxygen. For the volume plasma, EC{sub 50} in this case was measured at 50 eV/molecule, and for the surface plasma it was 40 eV/molecule. Besides the higher NO removal efficiency of surface plasmas compared to volume plasmas, the energy efficiency of surface-plasmas was found to be almost independent of the amount of electrical energy deposited in the discharge, whereas the efficiency for volume plasmas decreases considerably with increasing energy. This indicates the possibility of operating surface plasma discharges at high energy densities and in more compact reactors than conventional volume discharges.

  14. Effect Of Gas Mixture Composition On Tar Removal Process In A Pulsed Corona Discharge Reactor

    Science.gov (United States)

    Filimonova E.; Naidis, G.

    2010-07-01

    The simulation of naphthalene (C10H8) removal from several gas mixtures (pure nitrogen, mixtures containing N2 with CO2, CO, H2, H2O, and biogas - the product of biomass gasification), has been investigated. The modeling is based on the experimental data obtained in the reactor with a pulsed positive corona discharge. The problem of simulation of the cleaning process includes description of two stages. The first, fast stage is generation of primary active species during streamer propagation. The second, slow stage is the chain of chemical transformations triggered by these species. The input parameters for the modeling of the second stage are G-values for generation of primary active species, obtained under consideration of streamer dynamics. Simulation of the second stage of the removal process takes into account the processes of chemical kinetics and diffusion outside and inside of streamer traces during multi-pulsed treatment. Besides neutral active species, streamer discharges produce electrons and ions. Primary positive ions (N2+, CO+, CO2+, H2+, H2O+) in a chain of fast ion-molecule reactions transform into more stable positive ions. The ions recombine with electrons. Both ion-molecule reactions and electron-ion recombination process are additional (to dissociation of gas molecules by electron impact in the streamer head) sources of neutral active species. The relative contribution of these sources to the G-values for H, OH and O is rather large. In our modeling two approaches have been used. At the first approach the contribution of ion-molecule reactions is estimated approximately assuming that the dominating stable ion is N4+ (in pure N2 and its mixtures with H2) or CO2+ (in mixtures including CO2). Other way is the calculations with kinetic scheme including the molecular ions, aquated ions such as H3O(H2O)m+, NO2(H2O)-, NO2(H2O)+ and other. The comparison of results of two approaches is presented. Only full kinetic scheme allowed describing the

  15. High-pressure (>1-bar) dielectric barrier discharge lamps generating short pulses of high-peak power vacuum ultraviolet radiation

    Energy Technology Data Exchange (ETDEWEB)

    Carman, R J; Mildren, R P; Ward, B K; Kane, D M [Short Wavelength Interactions with Materials (SWIM), Physics Department, Macquarie University, North Ryde, Sydney, NSW 2109 (Australia)

    2004-09-07

    We have investigated the scaling of peak vacuum ultraviolet output power from homogeneous Xe dielectric barrier discharges excited by short voltage pulses. Increasing the Xe fill pressure above 1-bar provides an increased output pulse energy, a shortened pulse duration and increases in the peak output power of two to three orders of magnitude. High peak power pulses of up to 6 W cm{sup -2} are generated with a high efficiency for pulse rates up to 50 kHz. We show that the temporal pulse characteristics are in good agreement with results from detailed computer modelling of the discharge kinetics.

  16. Compressibility effects on the non-linear receptivity of boundary layers to dielectric barrier discharges

    Science.gov (United States)

    Denison, Marie F. C.

    The reduction of drag and aerodynamic heating caused by boundary layer transition is of central interest for the development of hypersonic vehicles. Receptivity to flow perturbation in the form of Tollmien-Schlichting (TS) wave growth often determines the first stage of the transition process, which can be delayed by depositing specific excitations into the boundary layer. Weakly ionized Dielectric Barrier Discharge (DBD) actuators are being investigated as possible sources of such excitations, but little is known today about their interaction with high-speed flows. In this framework, the first part of the thesis is dedicated to a receptivity study of laminar compressible boundary layers over a flat plate by linear stability analysis following an adjoint operator formulation, under DBD representative excitations assumed independent of flow conditions. The second part of the work concentrates on the development of a coupled plasma-Navier and Stokes solver targeted at the study of supersonic flow and compressibility effects on DBD forcing and non-parallel receptivity. The linear receptivity study of quasi-parallel compressible flows reveals several interesting features such as a significant shift of the region of maximum receptivity deeper into the flow at high Mach number and strong wave amplitude reduction compared to incompressible flows. The response to DBD relevant excitation distributions and to variations of the base flow conditions and system length scales follows these trends. Observed absolute amplitude changes and relative sensitivity modifications between source types are related to the evolution of the offset between forcing peak profile and relevant adjoint mode maximum. The analysis highlights the crucial importance of designing and placing the actuator in a way that matches its force field to the position of maximum boundary layer receptivity for the specific flow conditions of interest. In order to address the broad time and length scale spectrum

  17. Skeletal cell differentiation is enhanced by atmospheric dielectric barrier discharge plasma treatment.

    Directory of Open Access Journals (Sweden)

    Marla J Steinbeck

    Full Text Available Enhancing chondrogenic and osteogenic differentiation is of paramount importance in providing effective regenerative therapies and improving the rate of fracture healing. This study investigated the potential of non-thermal atmospheric dielectric barrier discharge plasma (NT-plasma to enhance chondrocyte and osteoblast proliferation and differentiation. Although the exact mechanism by which NT-plasma interacts with cells is undefined, it is known that during treatment the atmosphere is ionized generating extracellular reactive oxygen and nitrogen species (ROS and RNS and an electric field. Appropriate NT-plasma conditions were determined using lactate-dehydrogenase release, flow cytometric live/dead assay, flow cytometric cell cycle analysis, and Western blots to evaluate DNA damage and mitochondrial integrity. We observed that specific NT-plasma conditions were required to prevent cell death, and that loss of pre-osteoblastic cell viability was dependent on intracellular ROS and RNS production. To further investigate the involvement of intracellular ROS, fluorescent intracellular dyes Mitosox (superoxide and dihydrorhodamine (peroxide were used to assess onset and duration after NT-plasma treatment. Both intracellular superoxide and peroxide were found to increase immediately post NT-plasma treatment. These increases were sustained for one hour but returned to control levels by 24 hr. Using the same treatment conditions, osteogenic differentiation by NT-plasma was assessed and compared to peroxide or osteogenic media containing β-glycerolphosphate. Although both NT-plasma and peroxide induced differentiation-specific gene expression, neither was as effective as the osteogenic media. However, treatment of cells with NT-plasma after 24 hr in osteogenic or chondrogenic media significantly enhanced differentiation as compared to differentiation media alone. The results of this study show that NT-plasma can selectively initiate and amplify ROS

  18. Skeletal cell differentiation is enhanced by atmospheric dielectric barrier discharge plasma treatment.

    Science.gov (United States)

    Steinbeck, Marla J; Chernets, Natalie; Zhang, Jun; Kurpad, Deepa S; Fridman, Gregory; Fridman, Alexander; Freeman, Theresa A

    2013-01-01

    Enhancing chondrogenic and osteogenic differentiation is of paramount importance in providing effective regenerative therapies and improving the rate of fracture healing. This study investigated the potential of non-thermal atmospheric dielectric barrier discharge plasma (NT-plasma) to enhance chondrocyte and osteoblast proliferation and differentiation. Although the exact mechanism by which NT-plasma interacts with cells is undefined, it is known that during treatment the atmosphere is ionized generating extracellular reactive oxygen and nitrogen species (ROS and RNS) and an electric field. Appropriate NT-plasma conditions were determined using lactate-dehydrogenase release, flow cytometric live/dead assay, flow cytometric cell cycle analysis, and Western blots to evaluate DNA damage and mitochondrial integrity. We observed that specific NT-plasma conditions were required to prevent cell death, and that loss of pre-osteoblastic cell viability was dependent on intracellular ROS and RNS production. To further investigate the involvement of intracellular ROS, fluorescent intracellular dyes Mitosox (superoxide) and dihydrorhodamine (peroxide) were used to assess onset and duration after NT-plasma treatment. Both intracellular superoxide and peroxide were found to increase immediately post NT-plasma treatment. These increases were sustained for one hour but returned to control levels by 24 hr. Using the same treatment conditions, osteogenic differentiation by NT-plasma was assessed and compared to peroxide or osteogenic media containing β-glycerolphosphate. Although both NT-plasma and peroxide induced differentiation-specific gene expression, neither was as effective as the osteogenic media. However, treatment of cells with NT-plasma after 24 hr in osteogenic or chondrogenic media significantly enhanced differentiation as compared to differentiation media alone. The results of this study show that NT-plasma can selectively initiate and amplify ROS signaling to enhance

  19. Surface modification of chitosan/PEO nanofibers by air dielectric barrier discharge plasma for acetylcholinesterase immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Dorraki, Naghme, E-mail: n.dorraki@web.sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Safa, Nasrin Navab [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Jahanfar, Mehdi [Protein Research Center, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Ghomi, Hamid [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Ranaei-Siadat, Seyed-Omid [Protein Research Center, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of)

    2015-09-15

    Highlights: • We used an economical and effective method for surface modification. • Chitosan/PEO nanofibrous membranes were modified by air-DBD plasma. • The most NH{sub 3}{sup +} group was generated on the 6 min plasma modified membrane. • We immobilized acetylcholinesterase on the plasma modified and unmodified membranes. • More enzyme activity was detected on the modified membrane by plasma. - Abstract: There are different methods to modify polymer surfaces for biological applications. In this work we have introduced air-dielectric barrier discharge (DBD) plasma at atmospheric pressure as an economical and safe method for modifying the surface of electrospun chitosan/PEO (90/10) nanofibers for acetylcholinesterase (AChE) immobilization. According to the contact angle measurement results, the nanofibers become highly hydrophilic when they are exposed to the DBD plasma for 6 min in compared to unmodified membrane. Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) results reveal hydroxyl, C=O and NH{sub 3}{sup +} polar groups increment after 6 min plasma treatment. Contact angle measurements and ATR-FTIR results are confirmed by X-ray photoelectron spectroscopy (XPS). AChE at pH 7.4 carries a negative charge and after immobilization on the surface of plasma-treated nanofibrous membrane attracts the NH{sub 3}{sup +} group and more enzyme activity is detected on the plasma-modified nanofibers for 6 min in compared to unmodified nanofibers. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) are used for the surface topography and morphology characterization. The results have proved that air-DBD plasma is a suitable method for chitosan/PEO nanofibrous membrane modification as a biodegradable and functionalized substrate for enzyme immobilization.

  20. Dielectric barrier discharge molecular emission spectrometer as multichannel GC detector for halohydrocarbons.

    Science.gov (United States)

    Li, Wei; Zheng, Chengbin; Fan, Guangyu; Tang, Li; Xu, Kailai; Lv, Yi; Hou, Xiandeng

    2011-07-01

    A novel microplasma molecular emission spectrometer based on an atmospheric pressure dielectric barrier discharge (DBD) is described and further used as a promising multichannel GC detector for halohydrocarbons. The plasma is generated in a DBD device consisting of an outer electrode (1.2 mm in diameter) and an inner electrode (1.7 mm in diameter) within a small quartz tube (3.0 mm i.d. × 5.0 mm o.d. × 50 mm), wherein analyte molecules are excited by the microplasma to generate molecular emission. Therefore, the analytes are selectively and simultaneously detected with a portable charge-coupled device (CCD) via multichannel detection of their specific emission lines. The performance of this method was evaluated by separation and detection of a model mixture of chlorinated hydrocarbons (CHCl(3) and CCl(4)), brominated hydrocarbons (CH(2)Br(2) and CH(2)BrCH(2)Br), and iodinated hydrocarbons (CH(3)I and (CH(3))(2)CHI) undergoing GC with the new detector. The completely resolved identification of the tested compounds was achieved by taking advantages of both chromatographic and spectral resolution. Under the optimized conditions with the CCD spectrometer set at 258, 292, and 342 nm channels for determination of chlorinated hydrocarbons, brominated hydrocarbons, and iodinated hydrocarbons, respectively, this detector with direct injection provided detection limits of 0.07, 0.06, 0.3, 0.04, 0.05, and 0.02 μg mL(-1) for CCl(4), CHCl(3), CH(2)Cl(2), CH(3)I, CH(3)CH(2)I, and (CH(3))(2)CHI, respectively.

  1. Effect of dielectric and liquid on plasma sterilization using dielectric barrier discharge plasma.

    Directory of Open Access Journals (Sweden)

    Navya Mastanaiah

    Full Text Available Plasma sterilization offers a faster, less toxic and versatile alternative to conventional sterilization methods. Using a relatively small, low temperature, atmospheric, dielectric barrier discharge surface plasma generator, we achieved ≥ 6 log reduction in concentration of vegetative bacterial and yeast cells within 4 minutes and ≥ 6 log reduction of Geobacillus stearothermophilus spores within 20 minutes. Plasma sterilization is influenced by a wide variety of factors. Two factors studied in this particular paper are the effect of using different dielectric substrates and the significance of the amount of liquid on the dielectric surface. Of the two dielectric substrates tested (FR4 and semi-ceramic (SC, it is noted that the FR4 is more efficient in terms of time taken for complete inactivation. FR4 is more efficient at generating plasma as shown by the intensity of spectral peaks, amount of ozone generated, the power used and the speed of killing vegetative cells. The surface temperature during plasma generation is also higher in the case of FR4. An inoculated FR4 or SC device produces less ozone than the respective clean devices. Temperature studies show that the surface temperatures reached during plasma generation are in the range of 30°C-66 °C (for FR4 and 20 °C-49 °C (for SC. Surface temperatures during plasma generation of inoculated devices are lower than the corresponding temperatures of clean devices. pH studies indicate a slight reduction in pH value due to plasma generation, which implies that while temperature and acidification may play a minor role in DBD plasma sterilization, the presence of the liquid on the dielectric surface hampers sterilization and as the liquid evaporates, sterilization improves.

  2. Oxygen functionalization of MWCNTs in RF-dielectric barrier discharge Ar/O2 plasma

    Science.gov (United States)

    Abdel-Fattah, E.; Ogawa, D.; Nakamura, K.

    2017-07-01

    The oxygenation of multi-wall carbon nanotubes (MWCNTs) was performed via a radio frequency dielectric barrier discharge (RF-DBD) in an Ar/{{\\text{H}}2}\\text{O} plasma mixture. The relative intensity of the Ar/{{\\text{O}}2} plasma species was characterized by optical emission spectroscopy (OES). The effects of treatment time, RF power and oxygen gas percentage on the chemical composition and surface morphology of MWCNTs were investigated by means of x-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and field emission scanning electron microscopy (FE-SEM). The results of FTIR and XPS revealed the presence of oxygen-containing functional groups on the MWCNTs treated in an Ar/{{\\text{O}}2} plasma at an RF power of 50 W and pressure of 400 Pa. The amount of oxygen functional groups (C=O, C-O, and O-COO) also increased by increasing treatment time up to 6 min, but slightly decreased when treatment time was increased by 10 min. The increase of oxygen gas percentage in the plasma mixture does not affect the oxygen content in the treated MWCNTs. Meanwhile, MWCNTs treated at high power (80 W) showed a reduction in oxygen functional groups in comparison with low RF power conditions. The Raman analysis was consistent with the XPS and FTIR results. The integrity of the nanotube patterns also remained damaged as observed by FE-SEM images. The MWCNTs treated in RF-DBD using the Ar/{{\\text{O}}2} plasma mixture showed improved dispersibility in deionized water. A correlation between the OES data and the observed surface characterization for an improved understanding of the functionalization of MWCNTs in Ar/{{\\text{O}}2} plasma was presented.

  3. Plasma inactivation of microorganisms on sprout seeds in a dielectric barrier discharge.

    Science.gov (United States)

    Butscher, Denis; Van Loon, Hanne; Waskow, Alexandra; Rudolf von Rohr, Philipp; Schuppler, Markus

    2016-12-05

    Fresh produce is frequently contaminated by microorganisms, which may lead to spoilage or even pose a threat to human health. In particular sprouts are considered to be among the most risky foods sold at retail since they are grown in an environment practically ideal for growth of bacteria and usually consumed raw. Because heat treatment has a detrimental effect on the germination abilities of sprout seeds, alternative treatment technologies need to be developed for microbial inactivation purposes. In this study, non-thermal plasma decontamination of sprout seeds is evaluated as a promising option to enhance food safety while maintaining the seed germination capabilities. In detail, investigations focus on understanding the efficiency of non-thermal plasma inactivation of microorganisms as influenced by the type of microbial contamination, substrate surface properties and moisture content, as well as variations in the power input to the plasma device. To evaluate the impact of these parameters, we studied the reduction of native microbiota or artificially applied E. coli on alfalfa, onion, radish and cress seeds exposed to non-thermal plasma in an atmospheric pressure pulsed dielectric barrier discharge streamed with argon. Plasma treatment resulted in a maximum reduction of 3.4 logarithmic units for E. coli on cress seeds. A major challenge in plasma decontamination of granular food products turned out to be the complex surface topology, where the rough surface with cracks and crevices can shield microorganisms from plasma-generated reactive species, thus reducing the treatment efficiency. However, improvement of the inactivation efficiency was possible by optimizing substrate characteristics such as the moisture level and by tuning the power supply settings (voltage, frequency) to increase the production of reactive species. While the germination ability of alfalfa seeds was considerably decreased by harsh plasma treatment, enhanced germination was observed under

  4. A Kinetic Study of Ozone and Nitric Oxides in Dielectric Barrier Discharges for O2/NOx Mixtures

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A simple model is described to simulate kinetic processes in dielectric barrier discharges for O2/NOx mixtures. A threshold of ozone production found experimentally is confirmed by the calculations of this modeling, and the underlying chemical reaction mechanisms are discussed. It is also found that the effects of diffusion processes in the period of the lifetime of O atoms are not important to microdischarge channels with a large radius, i.e. larger than 150μm.

  5. Theoretical analysis of ion kinetic energies and DLC film deposition by CH4+Ar (He) dielectric barrier discharge plasmas

    Institute of Scientific and Technical Information of China (English)

    Liu Yan-Hong; Zhang Jia-Liang; Ma Teng-Cai; Li Jian; Liu Dong-Ping

    2007-01-01

    The kinetic energy of ions in dielectric barrier discharge plasmas are analysed theoretically using the model of binary collisions between ions and gas molecules. Langevin equation for ions in other gases, Blanc law for ions in mixed gases, and the two-temperature model for ions at higher reduced field are used to determine the ion mobility. The kinetic energies of ions in CH4 + Ar(He) dielectric barrier discharge plasma at a fixed total gas pressure and various Ar (He)concentrations are calculated. It is found that with increasing Ar (He) concentration in CH4 + Ar (He) from 20% to 83%,the CH4+ kinetic energy increases from 69.6 (43.9) to 92.1 (128.5)eV, while the Ar+ (He+) kinetic energy decreases from 97 (145.2) to 78.8 (75.5)eV. The increase of CH4+ kinetic energy is responsible for the increase of hardness of diamond-like carbon films deposited by CH4 + Ar (He) dielectric barrier discharge without bias voltage over substrates.

  6. Treatment of gaseous effluents by using surface discharge plasma in continuous reactors: Process modelling and simulation

    OpenAIRE

    Assadi, Aymen,; Bouzaza, Abdelkrim; Wolbert, Dominique

    2015-01-01

    International audience; In the present work, the oxidation of isovaleraldehyde, a typical pollutant of indoor air, is investigated by using two different plasma DBD reactors: cylindrical and planar reactor. The study of the influence of the specific energy shows that its increment is accompanied by an increase of the removal efficiency. In fact, when specific energy extends three times, the removal efficiency is increased from 5 to 40%. Moreover an increase of the specific energy induces a hi...

  7. Treatment of gaseous effluents by using surface discharge plasma in continuous reactors: Process modelling and simulation

    OpenAIRE

    Assadi, Aymen; Bouzaza, Abdelkrim; Wolbert, Dominique

    2015-01-01

    International audience; In the present work, the oxidation of isovaleraldehyde, a typical pollutant of indoor air, is investigated by using two different plasma DBD reactors: cylindrical and planar reactor. The study of the influence of the specific energy shows that its increment is accompanied by an increase of the removal efficiency. In fact, when specific energy extends three times, the removal efficiency is increased from 5 to 40%. Moreover an increase of the specific energy induces a hi...

  8. Uniform and non-uniform modes of nanosecond-pulsed dielectric barrier discharge in atmospheric air: fast imaging and spectroscopic measurements of electric field.

    Science.gov (United States)

    Liu, Chong; Dobrynin, Danil; Fridman, Alexander

    2014-06-25

    In this study, we report experimental results on fast ICCD imaging of development of nanosecond-pulsed dielectric barrier discharge (DBD) in atmospheric air and spectroscopic measurements of electric field in the discharge. Uniformity of the discharge images obtained with nanosecond exposure times were analyzed using chi-square test. The results indicate that DBD uniformity strongly depends on applied (global) electric field in the discharge gap, and is a threshold phenomenon. We show that in the case of strong overvoltage on the discharge gap (provided by fast rise times), there is transition from filamentary to uniform DBD mode which correlates to the corresponding decrease of maximum local electric field in the discharge.

  9. Fundamental Research on Mercuryless Fluorescent Lamps II — External Electrode Operation with Pulsed Dielectric Barrier Discharge

    Science.gov (United States)

    Jinno, Masafumi; Aono, Hisayoshi

    1999-07-01

    The characteristics of electrodeless xenon discharge fluorescent lampsusing dielectric barrier discharge are described in this paper. All lamps were operated with pulsed discharge.The luminance of phosphor increases as the pressure of xenon increases.As the pressure of xenon increases, the second peak of phosphoremission increases.These increases seem to be caused by the VUV light of xenon excimers. Therefore, in order to obtain high luminance, xenon should be filled athigh pressure. In the case of the lamp operated by inner electrodes, if only xenon iscontained in the lamp, the cathode is bombarded and is damaged by thelarge mass of a xenon ion.On the other hand, the external electrode type is never damaged by theions or electrons.Moreover, the efficacy of the external electrode type is as great as the inner electrode type, and it can be improved by increasing the distance between electrodes.

  10. Nonintrusive microwave diagnostics of collisional plasmas in Hall thrusters and dielectric barrier discharges

    Science.gov (United States)

    Stults, Joshua

    This research presents a numerical framework for diagnosing electron properties in collisional plasmas. Microwave diagnostics achieved a significant level of development during the middle part of the last century due to work in nuclear weapons and fusion plasma research. With the growing use of plasma-based devices in fields as diverse as space propulsion, materials processing and fluid flow control, there is a need for improved, flexible diagnostic techniques suitable for use under the practical constraints imposed by plasma fields generated in a wide variety of aerospace devices. Much of the current diagnostic methodology in the engineering literature is based on analytical diagnostic, or forward, models. The Appleton-Hartree formula is an oft-used analytical relation for the refractive index of a cold, collisional plasma. Most of the assumptions underlying the model are applicable to diagnostics for plasma fields such as those found in Hall Thrusters and dielectric barrier discharge (DBD) plasma actuators. Among the assumptions is uniform material properties, this assumption is relaxed in the present research by introducing a flexible, numerical model of diagnostic wave propagation that can capture the effects of spatial gradients in the plasma state. The numerical approach is chosen for its flexibility in handling future extensions such as multiple spatial dimensions to account for scattering effects when the spatial extent of the plasma is small relative to the probing beam's width, and velocity dependent collision frequency for situations where the constant collision frequency assumption is not justified. The numerical wave propagation model (forward model) is incorporated into a general tomographic reconstruction framework that enables the combination of multiple interferometry measurements. The combined measurements provide a quantitative picture of the spatial variation in the plasma properties. The benefit of combining multiple measurements in a coherent

  11. Numerical Study of Pulsed Dielectric Barrier Discharge at Atmospheric Pressure Under the Needle-Plate Electrode Configuration

    Institute of Scientific and Technical Information of China (English)

    WANG Yanhui; YE Huanhuan; ZHANG Jiao; WANG Qi; ZHANG Jie; WANG Dezhen

    2016-01-01

    In this paper,we study the characteristics of atmospheric-pressure pulsed dielectric barrier discharge (DBD) under the needle-plate electrode configuration using a one-dimensional self-consistent fluid model.The results show that,the DBDs driven by positive pulse,negative pulse and bipolar pulse possess different behaviors.Moreover,the two discharges appearing at the rising and the falling phases of per voltage pulse also have different discharge regimes.For the case of the positive pulse,the breakdown field is much lower than that of the negative pulse,and its propagation characteristic is different from the negative pulse DBD.When the DBD is driven by a bipolar pulse voltage,there exists the interaction between the positive and negative pulses,resulting in the decrease of the breakdown field of the negative pulse DBD and causing the change of the discharge behaviors.In addition,the effects of the discharge parameters on the behaviors of pulsed DBD in the needle-plate electrode configuration are also studied.

  12. Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres

    Science.gov (United States)

    Kovačević, Vesna V.; Dojčinović, Biljana P.; Jović, Milica; Roglić, Goran M.; Obradović, Bratislav M.; Kuraica, Milorad M.

    2017-04-01

    The formation of hydroxyl radical and long-living chemical species (H2O2, O3, \\text{NO}3- and \\text{NO}2- ) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of ˙OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma–liquid interaction. The highest ˙OH production rate of 1.19  ×  10‑5 mol l‑1 s‑1 was found when water was treated in oxygen, with a yield of 2.75  ×  10‑2 molecules of ˙OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh‑1 when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.

  13. Effect of a direct current bias on the electrohydrodynamic performance of a surface dielectric barrier discharge actuator for airflow control

    Science.gov (United States)

    Yan, Huijie; Yang, Liang; Qi, Xiaohua; Ren, Chunsheng

    2015-02-01

    The effect of a DC bias on the electrohydrodynamics (EHD) force induced by a surface dielectric barrier AC discharge actuator for airflow control at the atmospheric pressure is investigated. The measurement of the surface potential due to charge deposition at different DC biases is carried out by using a special designed corona like discharge potential probe. From the surface potential data, the plasma electromotive force is shown not affected much by the DC biases except for some reduction of the DC bias near the exposed electrode edge for the sheath-like configuration. The total thrust is measured by an analytical balance, and an almost linear relationship to the potential voltage at the exposed electrode edge is found for the direct thrust force. The temporally averaged ionic wind characteristics are investigated by Pitot tube sensor and schlieren visualization system. It is found that the ionic wind velocity profiles with different DC biases are almost the same in the AC discharge plasma area but gradually diversified in the further downstream area as well as the upper space away from the discharge plasma area. Also, the DC bias can significantly modify the topology of the ionic wind produced by the AC discharge actuator. These results can provide an insight into how the DC biases to affect the force generation.

  14. Investigation of the coplanar barrier discharge in synthetic air at atmospheric pressure by cross-correlation spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hoder, T [Department of Physical Electronics, Masaryk University, Kotlarska 2, Brno 611 37 (Czech Republic); SIra, M [Department of Physical Electronics, Masaryk University, Kotlarska 2, Brno 611 37 (Czech Republic); Kozlov, K V [Institute of Physics, Ernst-Moritz-Arndt University, Felix-Hausdorff-Str. 6, D-17489 Greifswald (Germany); Wagner, H-E [Institute of Physics, Ernst-Moritz-Arndt University, Felix-Hausdorff-Str. 6, D-17489 Greifswald (Germany)

    2008-02-07

    The barrier discharge in the coplanar arrangement operating in a single-filament mode was studied spectroscopically. The evolution of the discharge luminosity was measured by the technique of cross-correlation spectroscopy. The 1D-spatially and temporally resolved luminosities of the first negative (at 391.5 nm) and the second positive (at 337.1 nm) system of molecular nitrogen were recorded using the above-mentioned technique. A cathode-directed ionizing wave (IW) was clearly seen on the plot for radiation intensity at 337.1 nm. In addition to this, also observed was a wave of the enhanced electric field propagating over the anode. In this paper, the propagation of these waves is described and their velocities are determined. The discharge evolution is divided into three phases-the Townsend phase, the phase of the IWs propagation and the extinction phase. Since the above-mentioned luminosity distributions could be interpreted approximately as the electric field (for 391.5 nm) and the electron density (for 337.1 nm) distribution, the qualitative description of the discharge is made accordingly. All these parameters are compared with similar measurements of the volume discharge. Apart from this, an attempt to determine the reduced electric field is made according to the kinetic model.

  15. Simultaneous removal of aerosol particles, NO{sub x} and SO{sub 2}, from incense smokes by a DC electrostatic precipitator with dielectric barrier discharge prechargers

    Energy Technology Data Exchange (ETDEWEB)

    Kawada, Yoshihiro; Chang Jenshih [Department of Engineering Physics, McMaster University, Hamilton, ON (Canada); Department of Electrical and Electronics Engineering, Musashi Institute of Technology, Tamazutsumi, Setagaya-ku, Tokyo (Japan); Kaneko, Tadamitsu [Department of Engineering Physics, McMaster University, Hamilton, ON (Canada); Faculty of Humanities, Miyazaki Municipal University, Funatsuka 1-chome, Miyazaki (Japan); Ito, Tairo [Department of Electrical and Electronics Engineering, Musashi Institute of Technology, Tamazutsumi, Setagaya-ku, Tokyo (Japan)

    2002-08-21

    In this paper, electrostatic precipitators (ESPs) under positive corona discharge operation with and without wire-rod and wire-quadrupole type barrier discharge prechargers were tested for simultaneous removal of submicron particles, NO{sub x} and SO{sub 2}. High dielectric constant ferro-electric materials and hard glass were used as the barrier for barrier discharge type precharger. The results show that aerosol particles, NO{sub x} and SO{sub 2}, were simultaneously removed by DC positively biased wire-plate ESPs, and that the particle collection efficiency was improved by an addition of wire-quadrupole type barrier discharge precharger in front of the wire-plate ESP. The addition of the prechargers, however, had little effect on the overall removal efficiencies of NO{sub x} and SO{sub 2}. (author)

  16. Ozone generation in a kHz-pulsed He-O2 capillary dielectric barrier discharge operated in ambient air

    Science.gov (United States)

    Sands, Brian L.; Ganguly, Biswa N.

    2013-12-01

    The generation of reactive oxygen species using nonequilibrium atmospheric pressure plasma jet devices has been a subject of recent interest due to their ability to generate localized concentrations from a compact source. To date, such studies with plasma jet devices have primarily utilized radio-frequency excitation. In this work, we characterize ozone generation in a kHz-pulsed capillary dielectric barrier discharge configuration comprised of an active discharge plasma jet operating in ambient air that is externally grounded. The plasma jet flow gas was composed of helium with an admixture of up to 5% oxygen. A unipolar voltage pulse train with a 20 ns pulse risetime was used to drive the discharge at repetition rates between 2-25 kHz. Using UVLED absorption spectroscopy centered at 255 nm near the Hartley-band absorption peak, ozone was detected over 1 cm from the capillary axis. We observed roughly linear scaling of ozone production with increasing pulse repetition rate up to a "turnover frequency," beyond which ozone production steadily dropped and discharge current and 777 nm O(5P→5S°) emission sharply increased. The turnover in ozone production occurred at higher pulse frequencies with increasing flow rate and decreasing applied voltage with a common energy density of 55 mJ/cm3 supplied to the discharge. The limiting energy density and peak ozone production both increased with increasing O2 admixture. The power dissipated in the discharge was obtained from circuit current and voltage measurements using a modified parallel plate dielectric barrier discharge circuit model and the volume-averaged ozone concentration was derived from a 2D ozone absorption measurement. From these measurements, the volume-averaged efficiency of ozone production was calculated to be 23 g/kWh at conditions for peak ozone production of 41 mg/h at 11 kV applied voltage, 3% O2, 2 l/min flow rate, and 13 kHz pulse repetition rate, with 1.79 W dissipated in the discharge.

  17. Microinstability properties of negative magnetic shear discharges in the Tokamak Fusion Test Reactor and DIII-D

    Energy Technology Data Exchange (ETDEWEB)

    Rewoldt, G.; Tang, W.M. [Princeton Univ., NJ (United States). Princeton Plasma Physics Lab.; Lao, L.L. [General Atomics, San Diego, CA (United States)

    1997-03-01

    The microinstability properties of discharges with negative (reversed) magnetic shear in the Tokamak Fusion Test Reactor (TFTR) and DIII-D experiments with and without confinement transitions are investigated. A comprehensive kinetic linear eigenmode calculation employing the ballooning representation is employed with experimentally measured profile data, and using the corresponding numerically computed magnetohydrodynamic (MHD) equilibria. The instability considered is the toroidal drift mode (trapped-electron-{eta}{sub i} mode). A variety of physical effects associated with differing q-profiles are explained. In addition, different negative magnetic shear discharges at different times in the discharge for TFTR and DIII-D are analyzed. The effects of sheared toroidal rotation, using data from direct spectroscopic measurements for carbon, are analyzed using comparisons with results from a two-dimensional calculation. Comparisons are also made for nonlinear stabilization associated with shear in E{sub r}/RB{sub {theta}}. The relative importance of changes in different profiles (density, temperature, q, rotation, etc.) on the linear growth rates is considered.

  18. Enhanced efficiency from a Xe excimer barrier discharge lamp employing short-pulsed excitation

    Science.gov (United States)

    Mildren, Richard P.; Morrow, R.; Carman, Robert J.

    2000-04-01

    We have measured the efficiency and spatial characteristics of output radiation as a function of fill pressure for a Xe excimer lamp employing a short voltage pulse (approximately 100 ns) excitation circuit, and compared the results with those obtained using conventional AC (ie. sinusoidal voltage waveform). When using pulsed excitation, VUV output is obtained from a homogeneous discharge at efficiencies which increase linearly with Xe pressure in the range 50 - 750 torr up to 3.2X the maximum efficiency obtained when using AC. When using AC excitation, the efficiency saturates with increasing pressure > 350 torr for which pressures the discharge appearance is altered from a diffuse discharge to one which is comprised of stochastic or stationary filaments. We have also recorded discharge spectra which highlight the different character of the homogeneous and filamented types of discharges. It is deduced that the enhanced efficiency arises due to the capability of pulsed excitation to produce a homogeneous (glow-like) discharge at higher pressure, which brings about more optimal electron density and temperature conditions for exclusively exciting Xe metastables than possible using AC. We attribute the homogenizing effect of short-pulsed excitation to the rapid rate at which the applied E-field increases to the necessary value for homogeneous discharge breakdown to proceed at a faster rate than the formation of filaments.

  19. Effect of Dielectric Barrier Discharge Plasma Actuators on Non-equilibrium Hypersonic Flows

    Science.gov (United States)

    2014-10-28

    goes into the kinetic energy of the electrons rather than heating of the surrounding gas.24 The examples of these include corona discharge and micro...and S. P. Wilkinson, “Boundary layer flow control with a one atmosphere uniform glow discharge surface plasma,” AIAA Paper 98 0328, 1998. 4L. Leger, E...Moreau, G. Artana, and G. Touchard, “Influence of a DC corona discharge on the airflow along an inclined flat plate,” J. Electrostat. 51–52, 300 306

  20. Modeling of discharges in a capacitively coupled dual frequency plasma reactor

    Directory of Open Access Journals (Sweden)

    Bojarov Aleksandar

    2009-01-01

    Full Text Available In this paper we have modeled a dual frequency coupled plasma reactor (DF-CCP by using a 1d3v PIC/MCC code. The obtained results apart from their theoretical relevance have practical applications especially for development of plasma reactors and for nanoelectronics. Dual frequency plasmas are used for etching of dielectric interconnect layers with high aspect ratios (contact holes. In the DF-CCP, the density of the plasma is controlled by the high frequency, while the ion energy depends mainly on the potential drop in the sheath, which is controlled by the low frequency. The results of our simulations show the dependence of the energy of the ions arriving at the inner electrode on the voltage of the low frequency generator and how the voltage of the high frequency generator affects the ion flux on the electrode.

  1. Amine-containing film deposited in pulsed dielectric barrier discharge at a high pressure and its cell adsorption behaviours

    Institute of Scientific and Technical Information of China (English)

    Hu Wen-Juan; Xie Fen-Yan; Chen Qiang; Weng Jing

    2009-01-01

    With monomer allylamine, amine-containing functional films were prepared in alternative current pulsed dielectric barrier discharge (DBD) at a high pressure. This paper analyses in detail the film properties and structures, such as hydrophilicity, compounds and microstructures as well as amine density by the water contact angle, Fourier transform infrared spectroscopy, atomic force microscopy, and ultraviolet-visible measurement. The influence of discharge param-eters, in particular applied power, on amine density was investigated. As an application the cell adsorption behaviours on plasma polymerization films was performed in-vitro. The results show that at a high pressure pulsed DBD plasma can polymerize films with sufficient amine group on surface, through which the very efficient cell adsorption behaviours was demonstrated, and the high rate of cell proliferation was visualized.

  2. Improving thrust by pulse-induced breakdown enhancement in AC surface dielectric barrier discharge actuators for airflow control

    Science.gov (United States)

    Yan, Huijie; Yang, Liang; Qi, Xiaohua; Ren, Chunsheng

    2016-07-01

    The characteristics of a plate-to-plate AC surface dielectric barrier discharge (SDBD) actuator using the pulse-induced breakdown enhancing method are experimentally investigated. The encapsulated electrode is supplied with a sine high AC voltage, while the exposed electrode is feed by a synchronized pulse voltage. Based on the thrust force and power consumption measurements, a parametric study was performed using a positive pulse applied at the trough phase of the AC cycles in which the thrust force was observed to increase by about 100% to 300% and the efficiency up to about 100% compared with the AC-only supply conditions for different AC voltages within the tested range. The pulse-induced breakdown effect was analyzed from the electrical and light emission waveforms to reveal the underlying mechanism. The surface potential due to the charge deposition effect was also measured using a specially designed corona-like discharge potential probe. It is shown that the pulse-induced breakdown was able to cause a temporarily intensified local electric field to enhance the glow-like discharge and meanwhile increase the time-average surface potential in the region further downstream. The improvement in the force by the enhancement in the pulse-induced breakdown was mainly due to enhancements in the glow-like discharge and the surface potential increment, with the latter being more important when the AC voltage is higher.

  3. Computer modelling of a short-pulse excited dielectric barrier discharge xenon excimer lamp (lambda approx 172 nm)

    CERN Document Server

    Carman, R J

    2003-01-01

    A detailed rate-equation analysis has been used to simulate the plasma kinetics in a pulsed-excited dielectric barrier discharge in xenon, under operating conditions where the discharge structure is spatially homogeneous. The one-dimensional model, incorporating 14 species and 70 reaction processes, predicts results that are in good agreement with experimental measurements of the electrical characteristics, and optical (vacuum-ultraviolet (VUV) and visible) pulse shapes. The model reveals that electrical breakdown of the discharge gap occurs via a fast-moving ionization/excitation wavefront that starts close to the anode dielectric and propagates towards the cathode at approx 3x10 sup 5 m s sup - sup 1. The wavefront appears as a result of successive avalanches of electrons that propagate across the discharge gap after release from the cathode dielectric. During breakdown, the mean electron energy in the bulk plasma is close to optimum for preferential excitation of the Xe* 1s sub 4 sub , sub 5 states that fe...

  4. Partial oxidation of methane to methanol with nitrogen dioxide in dielectric barrier discharge plasma: experimental and molecular modeling

    Science.gov (United States)

    Indarto, Antonius

    2016-04-01

    Non-catalytic conversion of methane (CH4) and nitrogen dioxide (NO2) into methanol (CH3OH) has been conducted and presented in this paper. Experiments were carried out using dielectric barrier discharge as the reaction medium in atmospheric pressure and temperature conditions. High yield production of methanol was achieved (18-20% mol) by single-stage plasma reaction with maximum selectivity of 32% mol. Compared to other oxidants, such as O2, the presence of NO2 in the plasma reaction resulted in higher methanol selectivity. For better understanding of the reactions, density functional theory calculations were also performed and discussed.

  5. Application of nanosecond-pulsed dielectric barrier discharge for biomedical treatment of topographically non-uniform surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Ayan, H; Staack, D; Mukhin, Y; Starikovskii, A; Fridman, A [Department of Mechanical Engineering and Mechanics, College of Engineering, Drexel University, Philadelphia, PA 19104 (United States); Fridman, G [School of Biomedical Engineering, Science, and Health Systems, Drexel University, Philadelphia, PA 19104 (United States); Gutsol, A [Chevron Energy Technology Company, Richmond, CA 94802 (United States); Friedman, G [Department of Electrical and Computer Engineering, College of Engineering, Drexel University, Philadelphia, PA 19104 (United States)

    2009-06-21

    Antimicrobial effectiveness of a nanosecond-pulsed dielectric barrier discharge (DBD) was investigated and compared with that of a microsecond-pulsed DBD. Experiments were conducted on the Escherichia coli bacteria covering a topographically non-uniform agar surface acting as one of the DBD electrodes. They reveal that the nanosecond-pulsed DBD can inactivate bacteria in recessed areas whereas the microsecond-pulsed and conventional DBDs fail to do so. Charged species (electrons and ions) appear to play the major role in the bacteria inactivation with the nanosecond-pulsed DBD. Moreover, the nanosecond-pulsed DBD kills bacteria significantly faster than its microsecond-pulsed counterpart.

  6. Comparison of dielectric barrier discharge, atmospheric pressure radiofrequency-driven glow discharge and direct analysis in real time sources for ambient mass spectrometry of acetaminophen

    Energy Technology Data Exchange (ETDEWEB)

    Kratzer, Jan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Institute of Analytical Chemistry of the ASCR, v.v.i., Veveri 97, CZ-602 00 Brno (Czech Republic); Mester, Zoltan [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada); Sturgeon, Ralph E., E-mail: Ralph.Sturgeon@nrc-cnrc.gc.ca [Institute for National Measurement Standards, National Research Council of Canada, 1200 Montreal Road, Ottawa, Ontario, K1A 0R6 (Canada)

    2011-08-15

    Three plasma-based ambient pressure ion sources were investigated; laboratory constructed dielectric barrier and rf glow discharges, as well as a commercial corona discharge (DART source). All were used to desorb and ionize a model analyte, providing sampling techniques for ambient mass spectrometry (MS). Experimental parameters were optimized to achive highest signal for acetaminophen as the analyte. Insight into the mechanisms of analyte desorption and ionization was obtained by means of emission spectrometry and ion current measurements. Desorption and ionization mechanisms for this analyte appear to be identical for all three plasma sources. Emission spectra differ only in the intensities of various lines and bands. Desorption of solid analyte requires transfer of thermal energy from the plasma source to sample surface, in the absence of which complete loss of MS response occurs. For acetaminophen, helium was the best plasma gas, providing 100- to 1000-fold higher analyte response than with argon or nitrogen. The same trend was also evident with background ions (protonated water clusters). MS analyte signal intensity correlates with the ion density (expressed as ion current) in the plasma plume and with emission intensity from excited state species in the plasma. These observations support an ionization process which occurs via proton transfer from protonated water clusters to analyte molecules.

  7. Emission characteristics of a barrier discharge in an argon-freon-water vapor mixture in the UV-VUV spectral range

    Science.gov (United States)

    Shuaibov, A. K.; Minya, A. I.; Gomoki, Z. T.; Gritsak, R. V.

    2013-05-01

    Optical characteristics of an ArCl*-OH* lamp excited by a nanosecond barrier discharge are studied. This discharge is a source of the ArCl ( B → X), ( D' → A'), and OH( A → X) molecular band emission with peaks at 175, 258, and 309 nm, respectively. The intensity of the barrier discharge plasma radiation is optimized as a function of the CCl4 vapor partial pressure at p(Ar) = 24 kPa and p(H2O) = 10-20 Pa.

  8. The application of electrorefining for recovery and purification of fuel discharged from the Integral Fast Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Burris, L.; Steunenberg, R.K.; Miller, W.E.

    1986-01-01

    An electrorefining process employing a molten salt electrolyte and a molten cadmium anode is proposed for the separation of uranium and plutonium from fission products and cladding material in discharged IFR driver fuel. The use of a liquid cadmium anode, which is the unique feature of the process, permits selective dissolution of the fuel from the cladding and prevents electrolytic corrosion of the steel container and contamination of the product by noble metal fission products.

  9. Radial Evolution of the Atmospheric Pressure Glow Discharge in Helium Controlled by Dielectric Barrier

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yuan-Tao; WANG De-Zhen; WANG Yan-Hui; LIU Cheng-Sen

    2005-01-01

    @@ The radial evolution of atmospheric pressure glow discharge in helium is presented by numerical simulation. The calculations reveal the mechanism of two current peaks per half cycle. The first breakdown occurs firstly in the central region of the electrode, and then spreads to the edge, while the second breakdown ignites at the periphery firstly, and then propagates toward the discharge central region. The simulations indicate that radial electric fields and radial sheath play an important role in the evolution of the second peak. These results agree fundamentally with the experimental observations.

  10. Experimental method to quantify the efficiency of the first two operational stages of nanosecond dielectric barrier discharge plasma actuators

    Science.gov (United States)

    Correale, G.; Avallone, F.; Starikovskiy, A. Yu

    2016-12-01

    A method to quantify the efficiency of the first two operational stages of a nanosecond dielectric barrier discharge (ns-DBD) plasma actuator is proposed. The method is based on the independent measurements of the energy of electrical pulses and the useful part of the energy which heats up the gas in the discharge region. Energy input is calculated via a back current shunt technique as the difference between the energy given and the energy reflected back. The ratio of the difference of the latter two quantities and the energy input gives the electrical efficiency (η E) of a ns-DBD. The extent of the energy deposited is estimated via Schlieren visualizations and infrared thermography measurements. Then, the ideal power flux obtained if all the inputted energy was converted into heat is calculated. Transient surface temperature was measured via infrared thermography and used to solve a 1D inverse heat transfer problem in a direction normal to the surface. It gives as output the actual power flux. The estimated ratio between the two power fluxes represents a quantification of the mechanical fluid efficiency (η FM) of a ns-DBD plasma actuator. Results show an inverse proportionality between η E, and η FM, and the thickness of the barrier. The efficiency of the first two operational stages of a ns-DBD is further defined as η  =  η E · η FM.

  11. Surface modification of polyvinyl alcohol/malonic acid nanofibers by gaseous dielectric barrier discharge plasma for glucose oxidase immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Afshari, Esmail, E-mail: e.afshari@mail.sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Mazinani, Saeedeh [Amirkabir Nanotechnology Research Institute (ANTRI), Amirkabir University of Technology, 15875-4413, Tehran (Iran, Islamic Republic of); Ranaei-Siadat, Seyed-Omid [Protein Research Center, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Ghomi, Hamid [Laser and Plasma Research Institute, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of)

    2016-11-01

    Highlights: • We fabricated polyvinyl alcohol/malonic acid nanofibers using electrospinning. • The surface nanofibers were modified by gaseous (air, nitrogen, CO{sub 2} and argon) dielectric barrier discharge. • Among them, air plasma had the most significant effect on glucose oxidase immobilization. • Chemical analysis showed that after modification of nanofibers by air plasma, the carboxyl group increased. • After air plasma treatment, reusability and storage stability of glucose oxidase immobilized on nanofibers improved. - Abstract: Polymeric nanofiber prepares a suitable situation for enzyme immobilization for variety of applications. In this research, we have fabricated polyvinyl alcohol (PVA)/malonic acid nanofibers using electrospinning. After fabrication of nanofibers, the effect of air, nitrogen, CO{sub 2}, and argon DBD (dielectric barrier discharge) plasmas on PVA/malonic acid nanofibers were analysed. Among them, air plasma had the most significant effect on glucose oxidase (GOx) immobilization. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrum analysis and X-ray photoelectron spectroscopy (XPS) results revealed that in case of air plasma modified nanofibers, the carboxyl groups on the surface are increased. The scanning electron microscopy (SEM) images showed that, after GOx immobilization, the modified nanofibers with plasma has retained its nanofiber structure. Finally, we analysed reusability and storage stability of GOx immobilized on plasma modified and unmodified nanofibers. The results were more satisfactory for modified nanofibers with respect to unmodified ones.

  12. Diagnosis of the ion density in two discharge modes generated in atmospheric pressure argon with pin-to-plate dielectric barrier geometry

    Energy Technology Data Exchange (ETDEWEB)

    Qi Bing; Huang Jianjun; Qiu Yunming; Liu Ying; Liu Lijun [Applied Low Temperature Plasma Laboratory, College of Physics Science and Technology, Shenzhen University, Shenzhen 518060 (China)

    2011-08-15

    In this study, the ion densities of an ac dielectric barrier discharge (DBD) (that is, a pin-to-plate DBD) as a function of the applied frequency in argon have been studied by means of the plasma radiation. The pin-to-plate DBD shows the characteristic of radiation oscillations with a low-frequency wave hidden in a high-frequency wave to form a mosaic structure, which reveals the coexistence of two discharge modes in the ac barrier discharge, i.e., the streamer mode and the corona mode. According to the oscillation frequencies, the ion densities are calculated. The results show that the ion density in streamer discharge is higher than that in corona discharge for about 1-2 magnitude orders.

  13. Study on the Generation Characteristics of Dielectric Barrier Discharge Plasmas on Water Surface

    Science.gov (United States)

    Liu, Wenzheng; Li, Chuanhui

    2014-01-01

    A new contact glow discharge electrode on the surface of water was designed and employed in this study. Because of the strong field strength in the small air gap formed by the electrode and the water surface, glow discharge plasmas were generated and used to treat waste water. The electric field distribution of the designed electrode model was simulated by MAXWELL 3D® simulation software, and the discharge parameters were measured. Through a series of experiments, we investigated the impact of optimal designs, such as the dielectric of the electrode, immersion depths, and curvature radii of the electrode on the generation characteristics of plasmas. In addition, we designed an equipotential multi-electrode configuration to treat a Methyl Violet solution and observe the discoloration effect. The experimental and simulation results indicate that the designed electrodes can realize glow discharge with a relative low voltage, and the generated plasmas covered a large area and were in stable state. The efficiency of water treatment is improved and optimized with the designed electrodes.

  14. Estimation of the light output power and efficiency of Xe barrier discharge excimer lamps using a one-dimensional fluid model for various voltage waveforms

    Science.gov (United States)

    Oda, Akinori; Sugawara, Hirotake; Sakai, Yosuke; Akashi, Haruaki

    2000-06-01

    Xe dielectric barrier discharges at different gap lengths under applied pulse voltages with trapezoidal and sinusoidal waveforms were simulated using a self-consistent one-dimensional fluid model. In both waveforms, the light output power depended not only on the amplitude of voltage waveforms but also on the discharge gap length. At the narrower discharge gap, the light output efficiency was improved by increasing the time gradient of the applied voltage when the trapezoidal pulse is applied, and by decreasing the duty ratio in the sinusoidal case. In the present simulation, we adopted a fast numerical method for calculation of electric field introducing an exact expression of the discharge current.

  15. Effect of nitrogen addition to ozone generation characteristics by diffuse and filamentary dielectric barrier discharges at atmospheric pressure

    Science.gov (United States)

    Osawa, Naoki; Tsuji, Takafumi; Ogiso, Ryota; Yoshioka, Yoshio

    2017-05-01

    Ozone is widely used for gas treatment, advanced oxidation processes, microorganisms inactivation, etc. In this research, we investigated the effect of nitrogen addition to ozone generation characteristics by atmospheric pressure Townsend discharge (APTD) type and filamentary dielectric barrier discharge (DBD) type ozone generators. The result showed that the ozone generated by the filamentary DBD increases rapidly with the increase of O2 content, and is higher than that by the APTD. On the other hand, it is interesting that the ozone generated by the APTD gradually decreases with the increase of O2 content. In order to clarify why the characteristics of ozone generation by the two kinds of discharge modes showed different dependency to the N2 content, we analyzed the exhaust gas composition using FTIR spectroscopy and calculated the rate coefficients using BOLSIG+ code. As a result, we found that although O2 content decreased with increasing N2 content, additional O atoms produced by excited N2 molecules contribute to ozone generation in case of APTD. Contribution to the topical issue "The 15th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XV)", edited by Nicolas Gherardi and Tomáš Hoder

  16. Dependence of Ozone Generation on Gas Temperature Distribution in AC Atmospheric Pressure Dielectric Barrier Discharge in Oxygen

    Science.gov (United States)

    Takahashi, Go; Akashi, Haruaki

    AC atmospheric pressure multi-filament dielectric barrier discharge in oxygen has been simulated using two dimensional fluid model. In the discharge, three kinds of streamers have been obtained. They are primary streamers, small scale streamers and secondary streamers. The primary streamers are main streamers in the discharge and the small scale streamers are formed after the ceasing of the primary streamers. And the secondary streamers are formed on the trace of the primary streamers. In these streamers, the primary and the small scale streamers are very effective to generate O(3P) oxygen atoms which are precursor of ozone. And the ozone is generated mainly in the vicinity of the dielectrics. In high gas temperature region, ozone generation decreases in general. However, increase of the O(3P) oxygen atom density in high gas temperature region compensates decrease of ozone generation rate coefficient. As a result, amount of ozone generation has not changed. But if the effect of gas temperature was neglected, amount of ozone generation increases 10%.

  17. Production of ammonia-derived radicals in a dielectric barrier discharge and their injection for denitrification

    DEFF Research Database (Denmark)

    Kusano, Y.; Leipold, F.; Fateev, A.

    2005-01-01

    and laser diode absorption spectroscopy was employed for detection of NH and NE, in the discharge respectively, while ultraviolet absorption and Fourier transform infrared spectroscopy was used for detection of nitrogen oxides, ammonia, ammonia-derived radicals, and other products after mixing the plasma...... efficiency and no generation of corrosive acids. In the present work ammonia-derived radicals were generated using an atmospheric pressure Ar/NH3 DBD and subsequently injected into an exhaust chamber where a synthetic flue gas of an NO/N-2 mixture was fed for demonstration of NO reduction. Optical emission...... activated gas with the synthetic flue gas. Although NE and NH2 radicals were observed in the discharge, due to their short lifetimes it is unlikely that they would be simply transported, mixed with the flue gas and react with NO to form N-2. On the other hand, hydrazine (N2H4), which is a stable ammonia...

  18. Concentric-Ring Patterns in a Helium Dielectric Barrier Discharge at Atmospheric Pressure

    Institute of Scientific and Technical Information of China (English)

    SHANG Wan-Li; WANG De-Zhen

    2007-01-01

    We perform the theoretical simulation of the concentric-ring patterns between two parallel electrodes covered with thin dielectric layers within the scope of a two-dimensional diffusion-drift model at atmospheric pressure. The time evolution of the discharge patterns is studied and the concentric-ring patterns with different radii shift alternately. The spatial-temporal evolution of electron density in a cycle at different time scales is performed.

  19. Risk of medication errors at hospital discharge and barriers to problem resolution.

    Science.gov (United States)

    Enguidanos, Susan M; Brumley, Richard D

    2005-01-01

    Medication errors are common among older adults, particularly among those who are at heightened risk due to transfer between care settings. Determining accurate medications for hospitalized patients is a complicated process. This paper presents findings from a small pilot study conducted to identify medication documentation problems at the point of hospital discharge among older adults and the problems encountered in developing new technological systems to address these problems. A prospective study was conducted within a managed care medical center that included patient and physician surveys and chart reviews. A review of 104 medical records revealed several problems in the documentation of patient medication including legibility, use of medical abbreviations and incomplete and missing entries. While patients overall were satisfied with medications communication efforts at discharge, physicians surveyed reported that these methods were inadequate in transmitting medication lists to primary care physicians, patients and other care providers. Patients reported taking more drugs than what were listed in the medical record. These findings led to the development, testing, and implementation of an electronic medication sheet. Despite the success in developing this new system, few physicians engaged in its use, with most preferring to continue with their standard discharge practices of written communication.

  20. Modeling and simulation of plasma gas flow driven by a single nanosecond-pulsed dielectric barrier discharge

    Science.gov (United States)

    Xu, S. Y.; Cai, J. S.; Li, J.

    2016-10-01

    A simplified (7 species and 9 processes) plasma kinetic model is proposed to investigate the mechanism of the plasma aerodynamic actuation driven by nanosecond-pulsed dielectric barrier discharge (NS-DBD). The governing equations include conservation equations for each species, the Poisson equation for the electric potential, and Navier-Stokes equations for the gas dynamic flow. Numerical simulations of plasma discharge and flow actuation on NS-DBD plasma actuators have been carried out. Key discharge characteristics and the responses of the quiescent air were reproduced and compared to those obtained in experiments and numerical simulations. Results demonstrate that the reduced plasma kinetic model is able to capture the dominant species and reactions to predict the actuation in complicated hydrodynamics. For the one-dimensional planar and two-dimensional symmetric NS-DBD, the forming of the sheath collapse is mainly due to the charge accumulation and secondary emission from the grounded electrode. Rapid species number density rise and electric field drop occur at the edge of the plasma sheath, where the space charge density gradient peaks. For the aerodynamic actuation with typical asymmetry electrodes, discharge characteristics have a core area on the right edge of the upper electrode, where the value can be much higher. The formation and propagation of the compression waves generated through rapid heating have also been performed and compared to those measured in a recent experiment. Energy release leads to gas expansion and forms a cylindrical shock wave, centering at the upper electrode tip with low gas acceleration. For the present single pulsed 12 kV case, the mean temperature of gas heating reaches about 575 K at 1 μs and decreases to about 460 K at 10 μs.

  1. Computer modelling of a short-pulse excited dielectric barrier discharge xenon excimer lamp (lambda~172 nm)

    Science.gov (United States)

    Carman, R. J.; Mildren, R. P.

    2003-01-01

    A detailed rate-equation analysis has been used to simulate the plasma kinetics in a pulsed-excited dielectric barrier discharge in xenon, under operating conditions where the discharge structure is spatially homogeneous. The one-dimensional model, incorporating 14 species and 70 reaction processes, predicts results that are in good agreement with experimental measurements of the electrical characteristics, and optical (vaccum-ultraviolet (VUV) and visible) pulse shapes. The model reveals that electrical breakdown of the discharge gap occurs via a fast-moving ionization/excitation wavefront that starts close to the anode dielectric and propagates towards the cathode at ~3×105 m s-1. The wavefront appears as a result of successive avalanches of electrons that propagate across the discharge gap after release from the cathode dielectric. During breakdown, the mean electron energy in the bulk plasma is close to optimum for preferential excitation of the Xeast 1s4,5 states that feed the VUV emitting Xe2ast excimer states. Calculations suggest that the overall conversion efficiency from electrical energy to VUV output in the plasma is greater than 60%, with >99% of the light output emitted in the VUV. Parasitic processes that act to reduce the key Xeast 1s4,5 and Xe2ast populations are found to be essentially negligible. For pulsed excitation, the longer-term spatio-temporal behaviour of the electron/ions during the afterglow or inter-pulse period is important, resulting in a remnant `pre-pulse' ion density of ~1015 m-3 close to the cathode dielectric. These ions bombard the cathode during the subsequent excitation period to release the secondary (seed) electrons required to achieve electrical breakdown.

  2. Computer modelling of a short-pulse excited dielectric barrier discharge xenon excimer lamp ({lambda} {approx} 172 nm)

    Energy Technology Data Exchange (ETDEWEB)

    Carman, R J; Mildren, R P [Department of Physics, Macquarie University, North Ryde, Sydney NSW (Australia)

    2003-01-07

    A detailed rate-equation analysis has been used to simulate the plasma kinetics in a pulsed-excited dielectric barrier discharge in xenon, under operating conditions where the discharge structure is spatially homogeneous. The one-dimensional model, incorporating 14 species and 70 reaction processes, predicts results that are in good agreement with experimental measurements of the electrical characteristics, and optical (vacuum-ultraviolet (VUV) and visible) pulse shapes. The model reveals that electrical breakdown of the discharge gap occurs via a fast-moving ionization/excitation wavefront that starts close to the anode dielectric and propagates towards the cathode at {approx} 3x10{sup 5} m s{sup -1}. The wavefront appears as a result of successive avalanches of electrons that propagate across the discharge gap after release from the cathode dielectric. During breakdown, the mean electron energy in the bulk plasma is close to optimum for preferential excitation of the Xe* 1s{sub 4,5} states that feed the VUV emitting Xe{sub 2}* excimer states. Calculations suggest that the overall conversion efficiency from electrical energy to VUV output in the plasma is greater than 60%, with >99% of the light output emitted in the VUV. Parasitic processes that act to reduce the key Xe* 1s{sub 4,5} and Xe{sub 2}* populations are found to be essentially negligible. For pulsed excitation, the longer-term spatio-temporal behaviour of the electron/ions during the afterglow or inter-pulse period is important, resulting in a remnant 'pre-pulse' ion density of {approx} 10{sup 15} m{sup -3} close to the cathode dielectric. These ions bombard the cathode during the subsequent excitation period to release the secondary (seed) electrons required to achieve electrical breakdown.

  3. Removal of dimethylamine and dimethyl sulfide from gas streams with dielectric barrier discharge plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Chen, J.; Jiang, J.; Pan, H.; Shi, Y. [Zhejiang Univ., Hangzhou (China). Inst. of Industrial Ecology and Environment, Dept. of Chemical and Biological Engineering

    2010-07-01

    This paper presented the experimental results from a study involving the removal of dimethylamine (DML) and dimethyl sulfide (DMS) from gas streams using a wire-cylinder pulse corona reactor. Peak voltage and initial DML concentration were shown to be important factors that influence the DML removal efficiency and energy yield. The conversion of DML of 761 mg/m{sup 3} reached 100 percent at a peak voltage of 41.25 kV. The conversion of DML increased as oxygen (O{sub 2}) concentration increased. The highest DML conversion was achieved with the gas stream containing 0.3 percent water. The removal of mixed odour (DML + DMS) in dry air was also investigated. Higher conversion, higher energy yield and fewer byproducts were found in mixed odour treatment than that in single odour treatment. The main byproducts in single DML removal were nitrogen oxides (NOx), ammonia (NH{sub 3}), sulphur dioxide (SO{sub 2}) and ozone (O{sub 3}). Some sulphur and white crystal ammonium nitrates were found adhering to the corona wire and reactor wall in the case of DML and DMS removal.

  4. Vortex shedding noise reduction by single dielectric barrier discharge plasma actuators

    OpenAIRE

    Al-Sadawi, L; Chong, TP

    2016-01-01

    An experimental study of active control of vortex shedding narrow band tonal noise from both blunt and rounded trailing edge of a profiled body at zero incidences was performed using Single Dielectric Barrier plasma actuators (DBD). Acoustics and flow measurements were carried out in an open jet, aerocoustic wind tunnel at Reynolds numbers ranging from 7x104 to 4x105. The noise results were obtained using single microphone, while both PIV and hot-wire were used for flow measurement in order t...

  5. Consequences of unburned hydrocarbons on microstreamer dynamics and chemistry during plasma remediation of NO sub x using dielectric barrier discharges

    CERN Document Server

    Dorai, R

    2003-01-01

    Atmospheric pressure plasmas, and dielectric barrier discharges (DBDs) in particular, are being investigated for their use in the remediation of nitrogen oxides (NO sub x) from automotive exhausts. In their normal mode of operation, DBDs consist of a large density of short-lived filamentary microdischarges. Localized energy deposition results in spatially nonuniform gas temperatures and species densities which initiate advective and diffusive transport. Diesel exhausts, one of the major sources of NO sub x , typically contain unburned hydrocarbons (UHCs) which significantly influence the NO sub x chemistry during plasma remediation. In this paper, we discuss results from a computational investigation of the consequences of UHC chemistry on radial transport dynamics and remediation of NO sub x. In the presence of UHCs, radicals such as O and OH are dominantly consumed in the microstreamer region and their transport to larger radii is reduced. As a result, the conversion of NO to NO sub 2 is mainly restricted t...

  6. Thin film deposition at atmospheric pressure using dielectric barrier discharges: Advances on three-dimensional porous substrates and functional coatings

    Science.gov (United States)

    Fanelli, Fiorenza; Bosso, Piera; Mastrangelo, Anna Maria; Fracassi, Francesco

    2016-07-01

    Surface processing of materials by atmospheric pressure dielectric barrier discharges (DBDs) has experienced significant growth in recent years. Considerable research efforts have been directed for instance to develop a large variety of processes which exploit different DBD electrode geometries for the direct and remote deposition of thin films from precursors in gas, vapor and aerosol form. This article briefly reviews our recent progress in thin film deposition by DBDs with particular focus on process optimization. The following examples are provided: (i) the plasma-enhanced chemical vapor deposition of thin films on an open-cell foam accomplished by igniting the DBD throughout the entire three-dimensional (3D) porous structure of the substrate, (ii) the preparation of hybrid organic/inorganic nanocomposite coatings using an aerosol-assisted process, (iii) the DBD jet deposition of coatings containing carboxylic acid groups and the improvement of their chemical and morphological stability upon immersion in water.

  7. Dielectric Barrier Discharge (DBD) Plasma Assisted Synthesis of Ag₂O Nanomaterials and Ag₂O/RuO₂ Nanocomposites.

    Science.gov (United States)

    Ananth, Antony; Mok, Young Sun

    2016-02-26

    Silver oxide, ruthenium oxide nanomaterials and its composites are widely used in a variety of applications. Plasma-mediated synthesis is one of the emerging technologies to prepare nanomaterials with desired physicochemical properties. In this study, dielectric barrier discharge (DBD) plasma was used to synthesize Ag₂O and Ag₂O/RuO₂ nanocomposite materials. The prepared materials showed good crystallinity. The surface morphology of the Ag₂O exhibited "garland-like" features, and it changed to "flower-like" and "leaf-like" at different NaOH concentrations. The Ag₂O/RuO₂ composite showed mixed structures of aggregated Ag₂O and sheet-like RuO₂. Mechanisms governing the material's growth under atmospheric pressure plasma were proposed. Chemical analysis was performed using Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS). Thermogravimetric analysis (TGA) showed the thermal decomposition behavior and the oxygen release pattern.

  8. Efficient new process for the desulfurization of mixtures of air and hydrogen sulfide via a dielectric barrier discharge plasma

    Directory of Open Access Journals (Sweden)

    S. Dahle

    2015-10-01

    Full Text Available The efficient removal of hydrogen sulfide, H2S, from streams of H2S in air via a dielectric barrier discharge (DBD plasma has been investigated using a quadrupole mass spectrometer. A suitable plasma device with a reservoir for storing sorbent powder of various kinds within the plasma region was constructed. Plasma treatments of gas streams with high concentrations of hydrogen sulfide in air yielded a removal of more than 98% of the initial hydrogen sulfide and a deposition of sulfur at the surface of the dielectric, while small amounts of sulfur dioxide were generated. The presence of calcium carbonate within the plasma region of the DBD device resulted in the removal of over 99% of the initial hydrogen sulfide content and the removal of 98% of the initial sulfur dioxide impurities from the gas mixture.

  9. Surface modification of polyvinyl alcohol/malonic acid nanofibers by gaseous dielectric barrier discharge plasma for glucose oxidase immobilization

    Science.gov (United States)

    Afshari, Esmail; Mazinani, Saeedeh; Ranaei-Siadat, Seyed-Omid; Ghomi, Hamid

    2016-11-01

    Polymeric nanofiber prepares a suitable situation for enzyme immobilization for variety of applications. In this research, we have fabricated polyvinyl alcohol (PVA)/malonic acid nanofibers using electrospinning. After fabrication of nanofibers, the effect of air, nitrogen, CO2, and argon DBD (dielectric barrier discharge) plasmas on PVA/malonic acid nanofibers were analysed. Among them, air plasma had the most significant effect on glucose oxidase (GOx) immobilization. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrum analysis and X-ray photoelectron spectroscopy (XPS) results revealed that in case of air plasma modified nanofibers, the carboxyl groups on the surface are increased. The scanning electron microscopy (SEM) images showed that, after GOx immobilization, the modified nanofibers with plasma has retained its nanofiber structure. Finally, we analysed reusability and storage stability of GOx immobilized on plasma modified and unmodified nanofibers. The results were more satisfactory for modified nanofibers with respect to unmodified ones.

  10. Impact of wet season river flood discharge on phytoplankton absorption properties in the southern Great Barrier Reef region coastal waters

    Science.gov (United States)

    Cherukuru, Nagur; Brando, Vittorio E.; Blondeau-Patissier, David; Ford, Phillip W.; Clementson, Lesley A.; Robson, Barbara J.

    2017-09-01

    Light absorption due to particulate and dissolved material plays an important role in controlling the underwater light environment and the above water reflectance signature. Thorough understanding of absorption properties and their variability is important to estimate light propagation in the water column. However, knowledge of light absorption properties in flood impacted coastal waters is limited. To address this knowledge gap we investigated a bio-optical dataset collected during a flood (2008) in the southern Great Barrier Reef (GBR) region coastal waters. Results presented here show strong impact of river flood discharges on water column stratification, distribution of suspended substances and light absorption properties in the study area. Bio-optical analysis showed phytoplankton absorption efficiency to reduce in response to increased coloured dissolved organic matter presence in flood impacted coastal waters. Biogeophysical property ranges, relationships and parametrisation presented here will help model realistic underwater light environment and optical signature in flood impacted coastal waters.

  11. Microsecond-pulsed dielectric barrier discharge plasma stimulation of tissue macrophages for treatment of peripheral vascular disease

    Science.gov (United States)

    Miller, V.; Lin, A.; Kako, F.; Gabunia, K.; Kelemen, S.; Brettschneider, J.; Fridman, G.; Fridman, A.; Autieri, M.

    2015-12-01

    Angiogenesis is the formation of new blood vessels from pre-existing vessels and normally occurs during the process of inflammatory reactions, wound healing, tissue repair, and restoration of blood flow after injury or insult. Stimulation of angiogenesis is a promising and an important step in the treatment of peripheral artery disease. Reactive oxygen species have been shown to be involved in stimulation of this process. For this reason, we have developed and validated a non-equilibrium atmospheric temperature and pressure short-pulsed dielectric barrier discharge plasma system, which can non-destructively generate reactive oxygen species and other active species at the surface of the tissue being treated. We show that this plasma treatment stimulates the production of vascular endothelial growth factor, matrix metalloproteinase-9, and CXCL 1 that in turn induces angiogenesis in mouse aortic rings in vitro. This effect may be mediated by the direct effect of plasma generated reactive oxygen species on tissue.

  12. Microsecond-pulsed dielectric barrier discharge plasma stimulation of tissue macrophages for treatment of peripheral vascular disease

    Energy Technology Data Exchange (ETDEWEB)

    Miller, V., E-mail: vmiller@coe.drexel.edu; Lin, A.; Brettschneider, J.; Fridman, G.; Fridman, A. [AJ Drexel Plasma Institute, Drexel University, Camden, New Jersey 08103 (United States); Kako, F.; Gabunia, K.; Kelemen, S.; Autieri, M. [Department of Physiology, Independence Blue Cross Cardiovascular Research Center, Temple University School of Medicine, Philadelphia, Pennsylvania 19140 (United States)

    2015-12-15

    Angiogenesis is the formation of new blood vessels from pre-existing vessels and normally occurs during the process of inflammatory reactions, wound healing, tissue repair, and restoration of blood flow after injury or insult. Stimulation of angiogenesis is a promising and an important step in the treatment of peripheral artery disease. Reactive oxygen species have been shown to be involved in stimulation of this process. For this reason, we have developed and validated a non-equilibrium atmospheric temperature and pressure short-pulsed dielectric barrier discharge plasma system, which can non-destructively generate reactive oxygen species and other active species at the surface of the tissue being treated. We show that this plasma treatment stimulates the production of vascular endothelial growth factor, matrix metalloproteinase-9, and CXCL 1 that in turn induces angiogenesis in mouse aortic rings in vitro. This effect may be mediated by the direct effect of plasma generated reactive oxygen species on tissue.

  13. Electrical and chemical properties of XeCl*(308 nm) exciplex lamp created by a dielectric barrier discharge

    Energy Technology Data Exchange (ETDEWEB)

    Baadj, S.; Harrache, Z., E-mail: zharrache@yahoo.com; Belasri, A. [Université des Sciences et de la Technologie d’Oran, USTO-MB, Laboratoire de Physique des Plasmas, Matériaux Conducteurs et leurs Application (LPPMCA) (Algeria)

    2013-12-15

    The aim of this work is to highlight, through numerical modeling, the chemical and the electrical characteristics of xenon chloride mixture in XeCl* (308 nm) excimer lamp created by a dielectric barrier discharge. A temporal model, based on the Xe/Cl{sub 2} mixture chemistry, the circuit and the Boltzmann equations, is constructed. The effects of operating voltage, Cl{sub 2} percentage in the Xe/Cl{sub 2} gas mixture, dielectric capacitance, as well as gas pressure on the 308-nm photon generation, under typical experimental operating conditions, have been investigated and discussed. The importance of charged and excited species, including the major electronic and ionic processes, is also demonstrated. The present calculations show clearly that the model predicts the optimal operating conditions and describes the electrical and chemical properties of the XeCl* exciplex lamp.

  14. Experimental Study on Surface Dielectric Barrier Discharge Plasma Actuator with Different Encapsulated Electrode Widths for Airflow Control at Atmospheric Pressure

    Science.gov (United States)

    Qi, Xiaohua; Yang, Liang; Yan, Huijie; Jin, Ying; Hua, Yue; Ren, Chunsheng

    2016-10-01

    The surface dielectric barrier discharge (SDBD) plasma actuator has shown great promise as an aerodynamic flow control device. In this paper, the encapsulated electrode width of a SDBD actuator is changed to study the airflow acceleration behavior. The effects of encapsulated electrode width on the actuator performance are experimentally investigated by measuring the dielectric layer surface potential, time-averaged ionic wind velocity and thrust force. Experimental results show that the airflow velocity and thrust force increase with the encapsulated electrode width. The results can be attributed to the distinct plasma distribution at different encapsulated electrode widths. supported by National Natural Science Foundation of China (No. 11175037), National Natural Science Foundation for Young Scientists of China (No. 11305017) and Special Fund for Theoretical Physics (No. 11247239)

  15. Consequences of unburned hydrocarbons on microstreamer dynamics and chemistry during plasma remediation of NOx using dielectric barrier discharges

    Science.gov (United States)

    Dorai, Rajesh; Kushner, Mark J.

    2003-05-01

    Atmospheric pressure plasmas, and dielectric barrier discharges (DBDs) in particular, are being investigated for their use in the remediation of nitrogen oxides (NOx) from automotive exhausts. In their normal mode of operation, DBDs consist of a large density of short-lived filamentary microdischarges. Localized energy deposition results in spatially nonuniform gas temperatures and species densities which initiate advective and diffusive transport. Diesel exhausts, one of the major sources of NOx, typically contain unburned hydrocarbons (UHCs) which significantly influence the NOx chemistry during plasma remediation. In this paper, we discuss results from a computational investigation of the consequences of UHC chemistry on radial transport dynamics and remediation of NOx. In the presence of UHCs, radicals such as O and OH are dominantly consumed in the microstreamer region and their transport to larger radii is reduced. As a result, the conversion of NO to NO2 is mainly restricted to the core of the microstreamer.

  16. Towards In-Flight Applications? - Requirements on the Dielectric Barrier Discharge (DBD) Plasma Actuator (PA)

    Science.gov (United States)

    Kriegseis, Jochen; Simon, Bernhard; Grundmann, Sven

    2016-11-01

    Most of today's flow control (FC) efforts with DBD show a rather one-sided picture. Typically, either the discharge properties are discussed extensively or FC achievements are reported. The former group of contributions only pays limited attention to implications and consequences of most characteristics with respect to subsequent control steps for successful DBD-based FC - the latter group mostly ignores changing discharge properties, thus varying control authority for the respective applications when changes of environment, PA health state or simply a varied angle-of-attack are to be considered. In addition, there still remains a fair bit of uncertainty regarding a universal PA-evaluation metric, such that some of the most promising quantities/characteristics for successful controller operation remain largely untouched from the community. The purpose of the present work is to outline the requirement profile of PAs in one coherent story starting from electrical issues all the way down the road to in-flight FC success, where particular emphasis is placed on the interplay of the involved subtopics. It is hypothesized that such a clear guideline is the only way to advance beyond the present level of lab studies, where there still is an obvious lack of real flight applications.

  17. Atmospheric pressure plasma produced inside a closed package by a dielectric barrier discharge in Ar/CO2 for bacterial inactivation of biological samples

    DEFF Research Database (Denmark)

    Chiper, Alina Silvia; Chen, Weifeng; Mejlholm, Ole

    2011-01-01

    The generation and evaluation of a dielectric barrier discharge produced inside a closed package made of a commercially available packaging film and filled with gas mixtures of Ar/CO2 at atmospheric pressure is reported. The discharge parameters were analysed by electrical measurements and optical...... times higher in the Ar/CO2 plasma compared with an Ar plasma. The efficiency of the produced plasma for the inactivation of bacteria on food inside the closed package was investigated....

  18. Infrared gas phase study on plasma-polymer interactions in high-current diffuse dielectric barrier discharge

    Science.gov (United States)

    Liu, Y.; Welzel, S.; Starostin, S. A.; van de Sanden, M. C. M.; Engeln, R.; de Vries, H. W.

    2017-06-01

    A roll-to-roll high-current diffuse dielectric barrier discharge at atmospheric pressure was operated in air and Ar/N2/O2 gas mixtures. The exhaust gas from the discharge was studied using a high-resolution Fourier-transform infrared spectrometer in the range from 3000 to 750 cm-1 to unravel the plasma-polymer interactions. The absorption features of HxNyOz, COx, and HCOOH (formic acid) were identified, and the relative densities were deduced by fitting the absorption bands of the detected molecules. Strong interactions between plasma and polymer (Polyethylene-2,6-naphthalate, or PEN) in precursor-free oxygen-containing gas mixtures were observed as evidenced by a high COx production. The presence of HCOOH in the gas effluent, formed through plasma-chemical synthesis of COx, turns out to be a sensitive indicator for etching. By adding tetraethylorthosilicate precursor in the plasma, dramatic changes in the COx production were measured, and two distinct deposition regimes were identified. At high precursor flows, a good agreement with the precursor combustion and the COx production was observed, whereas at low precursor flows an etching-deposition regime transpires, and the COx production is dominated by polymer etching.

  19. A comparative study for the inactivation of multidrug resistance bacteria using dielectric barrier discharge and nano-second pulsed plasma.

    Science.gov (United States)

    Park, Ji Hoon; Kumar, Naresh; Park, Dae Hoon; Yusupov, Maksudbek; Neyts, Erik C; Verlackt, Christof C W; Bogaerts, Annemie; Kang, Min Ho; Uhm, Han Sup; Choi, Eun Ha; Attri, Pankaj

    2015-09-09

    Bacteria can be inactivated through various physical and chemical means, and these have always been the focus of extensive research. To further improve the methodology for these ends, two types of plasma systems were investigated: nano-second pulsed plasma (NPP) as liquid discharge plasma and an Argon gas-feeding dielectric barrier discharge (Ar-DBD) as a form of surface plasma. To understand the sterilizing action of these two different plasma sources, we performed experiments with Staphylococcus aureus (S. aureus) bacteria (wild type) and multidrug resistant bacteria (Penicillum-resistant, Methicillin-resistant and Gentamicin-resistant). We observed that both plasma sources can inactivate both the wild type and multidrug-resistant bacteria to a good extent. Moreover, we observed a change in the surface morphology, gene expression and β-lactamase activity. Furthermore, we used X-ray photoelectron spectroscopy to investigate the variation in functional groups (C-H/C-C, C-OH and C=O) of the peptidoglycan (PG) resulting from exposure to plasma species. To obtain atomic scale insight in the plasma-cell interactions and support our experimental observations, we have performed molecular dynamics simulations to study the effects of plasma species, such as OH, H2O2, O, O3, as well as O2 and H2O, on the dissociation/formation of above mentioned functional groups in PG.

  20. On the influence of high voltage slope steepness on breakdown and development of pulsed dielectric barrier discharges

    Science.gov (United States)

    Höft, H.; Becker, M. M.; Loffhagen, D.; Kettlitz, M.

    2016-12-01

    The influence of the steepness of the applied high voltage (HV) waveform on the characteristics of pulsed dielectric barrier discharges (DBDs) is investigated using a single-filament arrangement with 1 mm gap in 0.1 vol% O2 in N2 at atmospheric pressure. The slope steepness was varied between 75 V ns-1 and 200 V ns-1. The discharge development was recorded with a combined iCCD and streak camera system accompanied by electrical measurements. The analysis was supported by time-dependent, spatially one-dimensional fluid model calculations. A steeper HV slope leads to a higher transferred charge and electrical energy per cycle. The DBD emission structure in the gap features a shorter ‘dark space’ in front of the cathode for steeper HV pulses. The starting velocity of the positive streamer-like propagation at the rising slope of the HV pulses increases with increasing slope steepness, but without influencing the maximal velocity in front of the cathode. At the falling slope, however, smaller propagation velocities for steeper pulses were measured. The modelling results and the measurements of the emission during the pre-phase suggest that the elevated pre-ionisation and higher electrical energy for steeper HV slopes is responsible for most of the observed effects.

  1. Study of the first pulse of Ne-Xe-HCl dielectric barrier discharge for the excimer lamp

    Science.gov (United States)

    Belasri, A.; Bendella, S.; Baba-Hamed, T.

    2008-05-01

    A global one-dimensional model of a dielectric barrier discharge which includes the sheath region and the positive column was developed. The model was used to study the electrical properties under operating conditions of the vacuum ultraviolet excimer lamp and to understand the basic processes of plasma kinetics. A 0.5cm interelectrode gap distance is filled with a Ne-Xe-HCl mixture. Time variations of the charged particles and excited species in the positive column were described. Then the one-dimensional model was used in the cathode region to illustrate (i) the spatio-temporal behavior of electronic and ionic densities and the electric field, and (ii) the time variation of the voltage, the current, and secondary currents due to ion and photon (λ =172nm) impact on the cathode. It shows a good resolution inside the sheath at high pressure and it correctly predicts the waveform of the discharge behavior. The obtained results have been discussed and analyzed.

  2. Particle-in-Cell Simulation for the Control of Electron Energy Distribution of Dielectric Barrier Discharges at Atmospheric Pressure

    Science.gov (United States)

    Bae, Hyo Won; Yel Lee, Jung; Lee, Ho-Jun; Lee, Hae June

    2011-10-01

    Recently, atmospheric pressure plasmas attract lots of interests for the useful applications such as surface modification and bio-medical treatment. In this study, a particle-in-cell Monte Carlo collision (PIC-MCC) simulation was adopted to investigate the discharge characteristics of a planar micro dielectric barrier discharge (DBD) with a driving frequency from 1 MHz to 50 MHz and with a gap distance from 60 to 500 micrometers. The variation of control parameters such as the gap distance, the driving wave form, and the applied voltage results in the change in the electron energy distribution function (EEDF). Through the relation between the ionization mean free path and the gap size, a significant change of EEDFs is achievable with the decrease of gap distance. Therefore, it is possible to categorize the operation range of DBDs for its applications by controlling the interactions between plasmas and neutral gas for the generation of preferable radicals. This work was supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant funded by the Korea government Ministry of Knowledge Economy (No. 20104010100670).

  3. Modeling of recovery mechanism of ozone zero phenomenaby adding small amount of nitrogen in atmospheric pressure oxygen dielectric barrier discharges

    Science.gov (United States)

    Akashi, Haruaki; Yoshinaga, Tomokazu

    2013-09-01

    Ozone zero phenomena in an atmospheric pressure oxygen dielectric barrier discharges have been one of the major problems during a long time operation of ozone generators. But it is also known that the adding a small amount of nitrogen makes the recover from the ozone zero phenomena. To make clear the mechanism of recovery, authors have been simulated the discharges with using the results of Ref. 3. As a result, the recovery process can be seen and ozone density increased. It is found that the most important species would be nitrogen atoms. The reaction of nitrogen atoms and oxygen molecules makes oxygen atoms which is main precursor species of ozone. This generation of oxygen atoms is effective to increase ozone. The dependence of oxygen atom density (nO) and nitrogen atom density (nN) ratio was examined in this paper. In the condition of low nN/nO ratio case, generation of nitrogen oxide is low, and the quenching of ozone by the nitrogen oxide would be low. But in the high ratio condition, the quenching of ozone by nitrogen oxide would significant. This work was supported by KAKENHI(23560352).

  4. Changes in water clarity in response to river discharges on the Great Barrier Reef continental shelf: 2002-2013

    Science.gov (United States)

    Fabricius, K. E.; Logan, M.; Weeks, S. J.; Lewis, S. E.; Brodie, J.

    2016-05-01

    Water clarity is a key factor for the health of marine ecosystems. The Australian Great Barrier Reef (GBR) is located on a continental shelf, with >35 major seasonal rivers discharging into this 344,000 km2 tropical to subtropical ecosystem. This work investigates how river discharges affect water clarity in different zones along and across the GBR. For each day over 11 years (2002-2013) we calculated 'photic depth' as a proxy measure of water clarity (calibrated to be equivalent to Secchi depth), for each 1 km2 pixel from MODIS-Aqua remote sensing data. Long-term and seasonal changes in photic depth were related to the daily discharge volumes of the nearest rivers, after statistically removing the effects of waves and tides on photic depth. The relationships between photic depths and rivers differed across and along the GBR. They typically declined from the coastal to offshore zones, and were strongest in proximity to rivers in agriculturally modified catchments. In most southern inner zones, photic depth declined consistently throughout the 11-year observation period; such long-term trend was not observed offshore nor in the northern regions. Averaged across the GBR, photic depths declined to 47% of local maximum values soon after the onset of river floods, and recovery to 95% of maximum values took on average 6 months (range: 150-260 days). The river effects were strongest at latitude 14.5°-19.0°S, where river loads are high and the continental shelf is narrow. Here, even offshore zones showed a >40% seasonal decline in photic depth, and 17-24% reductions in annual mean photic depth in years with large river nutrients and sediment loads. Our methodology is based on freely available data and tools and may be applied to other shelf systems, providing valuable insights in support of ecosystem management.

  5. Influences of oxygen content on characteristics of atmospheric pressure dielectric barrier discharge in argon/oxygen mixtures

    Science.gov (United States)

    Fang, Zhi; Shao, Tao; Wang, Ruixue; Yang, Jing; Zhang, Cheng

    2016-04-01

    The dielectric barrier discharge generated in argon/oxygen mixtures at atmospheric pressure is investigated, and the effect of oxygen content on discharge characteristics at applied voltage of 4.5 kV is studied by means of electrical measurements and optical diagnostics. The results show that the filaments in the discharge regime become more densely packed with the increasing in the oxygen content, and the distribution of the filaments is more uniform in the gap. An increase in the oxygen content results in a decrease in the average power consumed and transported charges, while there exists an optimal value of oxygen content for the production of oxygen radicals. The maximal yield of oxygen radicals is obtained in mixtures of argon with 0.3% oxygen addition, and the oxygen radicals then decrease with the further increase in the oxygen content. The oxygen/argon plasma is employed to modify surface hydrophilicity of the PET films to estimate the influence of oxygen content on the surface treatment, and the static contact angles before and after the treatments are measured. The lowest contact angle is obtained at a 0.3% addition of oxygen to argon, which is in accordance with the optimum oxygen content for oxygen radicals generation. The electron density and electron temperature are estimated from the measured current and optical emission spectroscopy, respectively. The electron density is found to reduce significantly at a higher oxygen content due to the increased electron attachment, while the estimated electron temperature do not change apparently with the oxygen content. Contribution to the Topical Issue "Recent Breakthroughs in Microplasma Science and Technology", edited by Kurt Becker, Jose Lopez, David Staack, Klaus-Dieter Weltmann and Wei Dong Zhu.

  6. Reduction of microbial contamination and improvement of germination of sweet basil (Ocimum basilicum L.) seeds via surface dielectric barrier discharge

    Science.gov (United States)

    Ambrico, Paolo F.; Šimek, Milan; Morano, Massimo; De Miccolis Angelini, Rita M.; Minafra, Angelantonio; Trotti, Pasquale; Ambrico, Marianna; Prukner, Václav; Faretra, Francesco

    2017-08-01

    Naturally contaminated basil seeds were treated by a surface dielectric barrier discharge driven in the humid air by an amplitude modulated AC high voltage to avoid heat shock. In order to avoid direct contact of seeds with microdischarge filaments, the seeds to be treated were placed at sufficient distance from the surface discharge. After treatment, the seeds were analyzed in comparison with control samples for their microbial contamination as well as for the capability of germination and seedling growth. Moreover, chemical modification of seed surface was observed through the elemental energy dispersive x-ray analysis and wettability tests. We found that treatment applied at 20% duty cycle (effective discharge duration up to 20 s) significantly decreases microbial load without reducing the viability of the seeds. On the other side, seedling growth was considerably accelerated after the treatment, and biometric growth parameters of seedlings (total length, weight, leaf extension) considerably increased compared to the controls. Interestingly, scanning electron microscopy images taken for the different duration of treatment revealed that seed radicle micropylar regions underwent significant morphological changes while the coat was substantially undamaged. Inside the seed, the embryo seemed to be well preserved while the endosperm body was detached from the epithelial tegument. A total of 9 different genera of fungi were recovered from the analyzed seeds. Scanning electron microscopy images revealed that conidia were localized especially in the micropylar region, and after plasma treatment, most of them showed substantial damages. Therefore, the overall effect of the treatment of naturally contaminated seeds by reactive oxygen and nitrogen species produced by plasma and the consequent changes in surface chemistry and microbial load can significantly improve seed vigor.

  7. Almost twenty years' search of transuranium isotopes in effluents discharged to air from nuclear power plants with VVER reactors.

    Science.gov (United States)

    Hölgye, Z; Filgas, R

    2006-04-01

    Airborne effluents of 5 stacks (stacks 1-5) of three nuclear power plants, with 9 pressurized water reactors VVER of 4,520 MWe total power, were searched for transuranium isotopes in different time periods. The search started in 1985. The subject of this work is a presentation of discharge data for the period of 1998-2003 and a final evaluation. It was found that 238Pu, 239,240Pu, 241Am, 242Cm, and 244Cm can be present in airborne effluents. Transuranium isotope contents in most of the quarterly effluent samples from stacks 2, 4 and 5 were not measurable. Transuranium isotopes were present in the effluents from stack l during all 9 years of the study and from stack 3 since the 3rd quarter of 1996 as a result of a defect in the fuel cladding. A relatively high increase of transuranium isotopes in effluents from stack 3 occurred in the 3rd quarter of 1999, and a smaller increase occurred in the 3rd quarter of 2003. In each instance 242Cm prevailed in the transuranium isotope mixtures. 238Pu/239,240Pu, 241Am/239,240Pu, 242Cm/239,240Pu, and 244Cm/239,240Pu ratios in fuel for different burn-up were calculated, and comparison of these ratios in fuel and effluents was performed.

  8. 针-板介质阻挡放电3种放电模式特性%Characteristics of Three Types of Discharge Modes in A Needle-plate Dielectric Barrier Discharge

    Institute of Scientific and Technical Information of China (English)

    任国强; 杨丽

    2011-01-01

    A needle-plate dielectric barrier discharge device with a transparent plate electrode is designed and used to study on characteristics of different types of discharge modes in atmospheric discharge in argon/air mixture. Three types of discharge modes, which are corona discharge, monofilament discharge,and spark discharge, are realized by changing the applied voltage. The discharge currents in positive halfcycle of the applied voltage are different from that in negative half-cycle. The optical emission spectra are collected in three types of discharges and the molecular vibrational temperatures are calculated. It shows that the vibrational temperature in corona discharge is the highest and that in monofilament discharge is larger than that in spark discharge.%设计了一种具有透明平板电极的针-板介质阻挡放电装置,研究了大气压氩气/空气混合气体放电中不同放电模式的特性.实验通过改变电压,实现了3种模式的放电:电晕放电、单丝放电和火花放电.在3种模式中,电流脉冲在外加电压的正、负半周表现出不同性质.采集了3种放电模式下的发射光谱,计算了分子振动温度,结果表明:电晕放电时分子振动温度最高,单丝放电次之,火花放电最低.

  9. Influence of the Gas Mixture Ratio on the Correlations Between the Excimer XeCl* Emission and the Sealed Gas Temperature in Dielectric Barrier Discharge Lamps

    Institute of Scientific and Technical Information of China (English)

    徐金洲; 梁荣庆; 任兆杏

    2002-01-01

    For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.

  10. Submarine groundwater discharge and solute transport under a transgressive barrier island

    Science.gov (United States)

    Evans, Tyler B.; Wilson, Alicia M.

    2017-04-01

    Many recent investigations of groundwater dynamics in beaches employed groundwater models that assumed isotropic, numerically-convenient hydrogeological conditions. Real beaches exhibit local variability with respect to stratigraphy, sediment grain size and associated topographic profile, so that groundwater flow may diverge significantly from idealized models. We used a combination of hydrogeologic field methods and a variable-density, saturated-unsaturated, transient groundwater flow model to investigate SGD and solute transport under Cabretta Beach, a small transgressive barrier island seaward of Sapelo Island, Georgia. We found that the inclusion of real beach heterogeneity drove important deviations from predictions based on theoretical beaches. Cabretta Beach sustained a stronger upper saline plume than predicted due to the presence of a buried silty mud layer beneath the surface. Infiltration of seawater was greater for neap tides than for spring tides due to variations in beach slope. The strength of the upper saline plume was greatest during spring tides, contrary to recent model predictions. The position and width of the upper saline plume was highly dynamic through the lunar cycle. Our results suggest that field measurements of salinity gradients may be useful for estimating rates of tidally and density driven recirculation through the beach. Finally, our results indicate that several important biogeochemical cycles recently studied at Cabretta Beach were heavily influenced by groundwater flow and associated solute transport.

  11. A combined study for turning CO$_2$ and H$_2$O into value-added products in a dielectric barrier discharge

    CERN Document Server

    Snoeckx, Ramses; Aerts, Robby; Dufour, Thierry; Reniers, François; Bogaerts, Annemie

    2016-01-01

    A combination of experiments and extensive modelling, including a chemical kinetics analysis, was performed for a CO$_2$/H$_2$O plasma in a dielectric barrier discharge. This provides a better understanding of the mechanisms related to the reactivity of the plasma and of the conversions into value-added products, such as methanol.

  12. Dielectric barrier discharge atmospheric cold plasma inhibits Escherichia coli 0157:H7, Salmonella, Listeria monocytogenes, and Tulane virus in Romaine lettuce

    Science.gov (United States)

    The present study investigated the effects of dielectric barrier discharge atmospheric cold plasma (DACP) treatment on the inactivation of Escherichia coli O157:H7, Salmonella, Listeria monocytogenes, and Tulane virus (TV) on Romaine lettuce, assessing the influences of moisture vaporization, modifi...

  13. Analysis of Influence Factors on Coal Desulfurization with Dielectric Barrier Discharge%煤介质阻挡放电脱硫的影响因素分析

    Institute of Scientific and Technical Information of China (English)

    许允之; 李国欣; 曹海洋

    2011-01-01

    依据介质阻挡放电理论,对原煤进行煤介质阻挡放电脱硫实验.实验结果表明,煤介质阻挡放电脱硫的影响因素与电极结构、介质成分和气隙距离等因素有关,如将介质放到放电间隙中间时脱硫的效果没有将介质直接放在放电极板上的脱硫效果好,加煤的情况下微放电的强度明显大于不加煤的微放电过程强度;脱硫效果呈"U"字型变化,由此推论,在一定的外界条件下,煤介质阻挡放电除硫有一个最佳的施加电压;随着电压的增加,放电脉冲的相位范围逐渐扩展.%According to the theory of dielectric barrier discharge, coal desulfurization experiment of dielectric barrier discharge was done.The experiment result showed that influence factors of coal desulfurization with dielectric barrier discharge are electrode structure, medium composition and air-gap distance, for example, desulfurization effect of putting medium on discharge board is better than the one of putting medium in air-gap, the intensity of microdischarge of adding coal is stronger than that the one of unadding coal; the desulfurization effect changes in "U" type, so it can be deduced that desulfurization has a best applied voltage in certain external conditions with dielectric barrier discharge; the phase scope of discharge pulse expands gradually with increase of the voltage.

  14. Experimental study on surface modification of PET films under bipolar nanosecond-pulse dielectric barrier discharge in atmospheric air

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Yunfei [State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049 (China); Su, Chunqiang [Xi’an High Voltage Apparatus Research Institute, Xi’an 710077 (China); Ren, Xiang; Fan, Chuan; Zhou, Wenwu [State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049 (China); Wang, Feng [School of Electrical and Information Engineering, Hunan University, Changsha 410082 (China); Ding, Weidong, E-mail: wdding@mail.xjtu.edu.cn [State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049 (China)

    2014-09-15

    Highlights: • Homogeneous DBD is generated under bipolar nanosecond pulse in atmospheric air. • Effects of surface modification under homogeneous DBD are discussed. • Dielectric properties of the PET films are fully studied from relative dielectric constant ε{sub r}, dielectric loss tangent tan δ and breakdown voltages V{sub b}. • Oxygen-containing polar groups are considered to be the most essential reason for dielectric property changes. - Abstract: Dielectric barrier discharge (DBD) is widely used for surface modification of polymer films. In this paper, DBD characteristics under bipolar repetitive frequency nanosecond pulse in atmospheric air are studied and surface properties of polyethylene terephthalate films under homogeneous DBD and filamentary DBD modification are compared through scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and dielectric test equipment. It is found that the discharge is homogeneous when gap spacing d is less than 1.2 mm and filamentary when d is within the range of 3.0 mm to 5.8 mm. SEM pictures reveal that films under homogeneous DBD present a smooth surface while intensive “gully-like” etches appear on the surface of the films under filamentary DBD, which can result in local insulation defects and is disadvantageous to surface modification. It is found from the XPS analysis that a number of oxygen-containing polar groups are introduced onto the surface of the film modified by homogeneous DBD compared with the untreated one. Experimental results for dielectric properties indicate that the three parameters: relative dielectric constant ε{sub r}, dielectric loss tangent tan δ and breakdown voltages V{sub b} are all changed in different degree after surface modification. And possible reason for the phenomenon is discussed.

  15. The consequences of air flow on the distribution of aqueous species during dielectric barrier discharge treatment of thin water layers

    Science.gov (United States)

    Tian, Wei; Lietz, Amanda M.; Kushner, Mark J.

    2016-10-01

    The desired outcomes of wet tissue treatment by dielectric barrier discharges (DBDs) strongly depend on the integrated fluences of reactive species incident onto the tissue, which are determined by power, frequency and treatment time. The reactivity produced by such plasmas is often expected to be proportional to treatment time due to the accumulation of radicals in the liquid over the tissue. However, one of the typically uncontrolled parameters in DBD treatment of liquids and tissue is gas flow, which could affect the delivery of plasma produced radicals to the tissue. Gas flow can redistribute long-lived, plasma produced gas phase species prior to solvating in the liquid, while not greatly affecting the solvation of short-lived species. Gas flow can therefore potentially be a control mechanism for tailoring the fluences of reactive species to the tissue. In this paper, we report on a computational investigation of the consequences of gas flow on treatment of liquid layers covering tissue by atmospheric DBDs by up to 100 pulses. We found that gas flow (through residence time of the gas) can control the production of gas phase species requiring many collisions to form, such as reactive nitrogen species (RNS). The resulting solvation of the RNS in turn controls the production of aqueous species such as \\text{NO}\\text{3aq}- and \\text{ONOO}\\text{aq}- (aq denotes an aqueous species). With the exception of O3 and O3aq, reactive oxygen species (ROS) are less sensitive to gas flow, and so OHaq and H2O2aq, are determined primarily by discharge properties.

  16. Barriers and facilitators to preparing families with premature infants for discharge home from the neonatal unit. Perceptions of health care providers.

    Science.gov (United States)

    Raffray, Marie; Semenic, Sonia; Osorio Galeano, Sandra; Ochoa Marín, Sandra Catalina

    2014-01-01

    To explore Colombian health care provider perceptions of barriers and facilitators to preparing families with premature infants for discharge home from the neonatal intensive care unit (NICU). Using a qualitative descriptive design, in-depth semi-structured interviews were conducted with fifteen neonatal health care providers (HCPs) in Colombia. Data were analyzed using qualitative content analysis. Participant responses centered on three main themes: 1) establishment of the parent-infant bond, 2) acquisition of parenting skills, and 3) getting ready for the transition from hospital to home. Barreirs to preparing parents for NICU discharge included obstacles to parental visiting in the NICU, communication barriers, difficulties related to the establishment of successful breastfeeding, insufficient human resources and poor links between hospital and community-based resources. Facilitators included the availability of social aids for vulnerable families, 24-hour telephone access to the neonatal units, tailored educational materials and group sessions, continuing education for staff and the community-based Kangaroo Program available to parents post-discharge. Adolescent mothers, indigenous parent and working fathers were identified as particularly challenging to reach and engage in discharge preparation. Neonatal HCPs identified numerous challenges as well as helpful strategies for preparing families for hospital discharge. Additional studies are needed on the experience of neonatal discharge from the perspective of parents of premature infants in Colombia, to help inform optimal interventions for supporting families during the transition from hospital to home.

  17. Barriers and facilitators to preparing families with premature infants for discharge home from the neonatal unit. Perceptions of health care providers

    Directory of Open Access Journals (Sweden)

    Marie Raffray

    2014-12-01

    Full Text Available Objective. To explore Colombian health care provider perceptions of barriers and facilitators to preparing families with premature infants for discharge home from the neonatal intensive care unit (NICU. Methodology. Using a qualitative descriptive design, in-depth semi-structured interviews were conducted with fifteen neonatal health care providers (HCPs in Colombia. Data were analyzed using qualitative content analysis. Results. Participant responses centered on three main themes: 1 establishment of the parent-infant bond, 2 acquisition of parenting skills, and 3 getting ready for the transition from hospital to home. Barreirs to preparing parents for NICU discharge included obstacles to parental visiting in the NICU, communication barriers, difficulties related to the establishment of successful breastfeeding, insufficient human resources and poor links between hospital and community-based resources. Facilitators included the availability of social aids for vulnerable families, 24-hour telephone access to the neonatal units, tailored educational materials and group sessions, continuing education for staff and the community-based Kangaroo Program available to parents post-discharge. Adolescent mothers, indigenous parent and working fathers were identified as particularly challenging to reach and engage in discharge preparation. Conclusion. Neonatal HCPs identified numerous challenges as well as helpful strategies for preparing families for hospital discharge. Additional studies are needed on the experience of neonatal discharge from the perspective of parents of premature infants in Colombia, to help inform optimal interventions for supporting families during the transition from hospital to home.

  18. Reactor

    Science.gov (United States)

    Evans, Robert M.

    1976-10-05

    1. A neutronic reactor having a moderator, coolant tubes traversing the moderator from an inlet end to an outlet end, bodies of material fissionable by neutrons of thermal energy disposed within the coolant tubes, and means for circulating water through said coolant tubes characterized by the improved construction wherein the coolant tubes are constructed of aluminum having an outer diameter of 1.729 inches and a wall thickness of 0.059 inch, and the means for circulating a liquid coolant through the tubes includes a source of water at a pressure of approximately 350 pounds per square inch connected to the inlet end of the tubes, and said construction including a pressure reducing orifice disposed at the inlet ends of the tubes reducing the pressure of the water by approximately 150 pounds per square inch.

  19. Towards a better understanding of dielectric barrier discharges in ferroelectrets: Paschen breakdown fields in micrometer sized voids

    Science.gov (United States)

    Harris, Scott; Mellinger, Axel

    2014-04-01

    Charged cellular polypropylene foams (i.e., ferro- or piezoelectrets) demonstrate high piezoelectric activity upon being electrically charged. When an external electric field is applied, dielectric barrier discharges (DBDs) occur, resulting in a separation of charges which are subsequently deposited on dielectric surfaces of internal micrometer sized voids. This deposited space charge is responsible for the piezoelectric activity of the material. Previous studies have indicated charging fields larger than predicted by Townsend's model of Paschen breakdown applied to a multilayered electromechanical model; a discrepancy which prompted the present study. The actual breakdown fields for micrometer sized voids were determined by constructing single cell voids using polypropylene spacers with heights ranging from 8 to 75 μm, "sandwiched" between two polypropylene dielectric barriers and glass slides with semi-transparent electrodes. Subsequently, a bipolar triangular charging waveform with a peak voltage of 6 kV was applied to the samples. The breakdown fields were determined by monitoring the emission of light due to the onset of DBDs using an electron multiplying CCD camera. The breakdown fields at absolute pressures from 101 to 251 kPa were found to be in good agreement with the standard Paschen curves. Additionally, the magnitude of the light emission was found to scale linearly with the amount of gas, i.e., the height of the voids. Emissions were homogeneous over the observed regions of the voids for voids with heights of 25 μm or less and increasingly inhomogeneous for void heights greater than 40 μm at high electric fields.

  20. Treatment of poly(ethylene terephthalate) foils by atmospheric pressure air dielectric barrier discharge and its influence on cell growth

    Energy Technology Data Exchange (ETDEWEB)

    Kuzminova, Anna [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Vandrovcová, Marta [Institute of Physiology, Academy of Sciences of the Czech Republic, Vídeňská 1083, 142 20 Prague 4 (Czech Republic); Shelemin, Artem [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Kylián, Ondřej, E-mail: ondrej.kylian@gmail.com [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Choukourov, Andrei; Hanuš, Jan [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic); Bačáková, Lucie [Institute of Physiology, Academy of Sciences of the Czech Republic, Vídeňská 1083, 142 20 Prague 4 (Czech Republic); Slavínská, Danka; Biederman, Hynek [Department of Macromolecular Physics, Faculty of Mathematics and Physics, Charles University, V Holešovickách 2, 180 00 Praha 8 (Czech Republic)

    2015-12-01

    Highlights: • Effect of atmospheric pressure DBD plasma on PET foils was investigated. • DBD treatment causes increase in surface density of O-containing functional groups. • DBD plasma causes increase of wettability, roughness and complex modulus of PET. • DBD treatment positively influences cells growth on PET. • Enhancement of cell growth on treated PET depends on the cell type. - Abstract: In this contribution an effect of dielectric barrier discharge (DBD) sustained in air at atmospheric pressure on surface properties of poly(ethylene terephthalate) (PET) foils is studied. It is found that exposure of PET to DBD plasma leads to rapid changes of surface chemical composition, wettability, surface morphology as well as mechanical properties of PET surface. In addition, based on biological tests that were performed using two cell types (Saos-2 human osteoblast-like cells and HUVEC human umbilical vein endothelial cells), it may be concluded that DBD plasma treatment positively influences cell growth on PET. This effect was found to be connected predominantly with increased surface energy and oxygen content of the surface of treated PET foils.

  1. Aerodynamic flow-control with dielectric barrier discharge plasma actuators; Aerodynamische Stroemungssteuerung mittels dielektrischer Barriereentladungs-Plasmaaktuatoren

    Energy Technology Data Exchange (ETDEWEB)

    Wilke, Joern Bastian

    2009-07-01

    In this work, measurements of the spatial-temporal evolution of velocity vector fields, induced by a dielectric barrier discharge plasma actuator, are presented for the first time in order to enhance the understanding of these actuators. A procedure for calculating the body forces-induced by these actuators-from the measured velocity vector fields is also described. A number of parametric studies with plasma actuators, were performed in order to identify the relevant parameter dependencies concerning the effectiveness and the efficiency for an optimization of these actuators. A new phenomenological model for the simulation of the aerodynamic effect of plasma actuators was developed, which can be used to produce more accurate numerical results than existing models. The suitability of plasma actuators in aerodynamic applications was investigated for two different cases. In the first case, a circulation control of a rotorcraft airfoil by plasma actuators, the actuators were arranged such that the gurney flap active principle was achieved and observed for the first time. In the second case, a plasma actuator was mounted on the leading edge of a delta wing to successfully demonstrate flow control up to Re=10{sup 6}. The three velocity components in the plane normal to the flow velocity were measured, enabling the analysis of the change of the leading edge vortices due to plasma actuation. (orig.)

  2. Influence of ionic liquid and ionic salt on protein against the reactive species generated using dielectric barrier discharge plasma.

    Science.gov (United States)

    Attri, Pankaj; Sarinont, Thapanut; Kim, Minsup; Amano, Takaaki; Koga, Kazunori; Cho, Art E; Choi, Eun Ha; Shiratani, Masaharu

    2015-12-10

    The presence of salts in biological solution can affect the activity of the reactive species (RS) generated by plasma, and so they can also have an influence on the plasma-induced sterilization. In this work, we assess the influence that diethylammonium dihydrogen phosphate (DEAP), an ionic liquid (IL), and sodium chloride (NaCl), an ionic salt (IS), have on the structural changes in hemoglobin (Hb) in the presence of RS generated using dielectric barrier discharge (DBD) plasma in the presence of various gases [O2, N2, Ar, He, NO (10%) + N2 and Air]. We carry out fluorescence spectroscopy to verify the generation of (•)OH with or without the presence of DEAP IL and IS, and we use electron spin resonance (ESR) to check the generation of H(•) and (•)OH. In addition, we verified the structural changes in the Hb structure after treatment with DBD in presence and absence of IL and IS. We then assessed the structural stability of the Hb in the presence of IL and IS by using molecular dynamic (MD) simulations. Our results indicate that the IL has a strong effect on the conservation of the Hb structure relative to that of IS against RS generated by plasma.

  3. The Changes in Electrical and Interfacial Properties of Polyimide Exposed to Dielectric Barrier Discharge in SF6 Medium

    Directory of Open Access Journals (Sweden)

    Hafiz Z. Alisoy

    2013-01-01

    Full Text Available The formation mechanism of space charges in polyimide (PI which was exposed to dielectric barrier discharge (DBD in SF6 medium and the effects of the space charges on interfacial and electrical properties of PI were investigated. The variation of normalized surface charge density on PI sample was calculated and illustrated for different DBD exposure times. The surface potential was measured to determine the effect of the space charges on the sample. Then, the contact angle values were measured to obtain the relation between the surface energy and the surface charge density. The expressions for the total charge and the concentration of trapped electrons were derived by using Poisson and continuity equations at stationary state. The space charges were determined experimentally by using thermally stimulated depolarization current (TSDC method. Also, SEM image and FTIR spectrum of virgin and treated samples were presented to observe the structural variations. It was seen that the approach for the formation mechanism of the space charges agreed with the experimental data. However, it was concluded particularly for the short-time DBD treatments that the space charges accumulated in the sample should be considered besides the effects of surface functionalization in the determination of the surface energy.

  4. Changes in Properties of Dielectric Barrier Discharge Plasma Jets for Different Gases and for Insulating and Conducting Transfer Plates

    Science.gov (United States)

    do Nascimento, Fellype; Moshkalev, Stanislav; Machida, Munemasa

    2017-03-01

    Dielectric barrier discharge (DBD) plasma jets have been studied extensively in recent years because of its wide range of applications. DBD plasmas can be produced using many different gases and can be applied to a broad variety of surfaces and substrates. This work provides comparisons of DBD plasmas generated using argon (Ar), helium (He), and nitrogen (N2), as well as their mixtures with water vapor in order to know how some plasma properties are affected by the use of different gases. All plasmas were studied in two different conditions: using a transfer plate made of a conductive material and using a transfer plate made of an insulating one. It was observed that the process of Penning ionization of nitrogen molecules by direct collisions with metastable atoms and molecules is evident and significant only in plasmas that use He as the working gas, which means that He atoms in metastable states have greater ability to transfer energy to molecules of nitrogen in the plasma. The collisions of metastable He with N2 molecules determine the vibrational temperature (T vib) values in He plasmas, while in Ar and N2 plasmas, the T vib values are determined mainly by collisions of electrons with N2 molecules. It was noticed that the use of an insulating or a conducting transfer plate as the sample holder affects the results of adhesion between poly(dimethylsiloxane) samples, and it is mainly due to the differences in the plasma power, with a higher plasma power leading to better adhesion.

  5. The topical use of non-thermal dielectric barrier discharge (DBD): nitric oxide related effects on human skin.

    Science.gov (United States)

    Heuer, Kiara; Hoffmanns, Martin A; Demir, Erhan; Baldus, Sabrina; Volkmar, Christine M; Röhle, Mirco; Fuchs, Paul C; Awakowicz, Peter; Suschek, Christoph V; Opländer, Christian

    2015-01-30

    Dielectric barrier discharge (DBD) devices generate air plasma above the skin containing active and reactive species including nitric oxide (NO). Since NO plays an essential role in skin physiology, a topical application of NO by plasma may be useful in the treatment of skin infections, impaired microcirculation and wound healing. Thus, after safety assessments of plasma treatment using human skin specimen and substitutes, NO-penetration through the epidermis, the loading of skin tissue with NO-derivates in vitro and the effects on human skin in vivo were determined. After the plasma treatment (0-60 min) of skin specimen or reconstructed epidermis no damaging effects were found (TUNEL/MTT). By Franz diffusion cell experiments plasma-induced NO penetration through epidermis and dermal enrichment with NO related species (nitrite 6-fold, nitrate 7-fold, nitrosothiols 30-fold) were observed. Furthermore, skin surface was acidified (~pH 2.7) by plasma treatment (90 s). Plasma application on the forearms of volunteers increased microcirculation fourfold in 1-2 mm and twofold in 6-8 mm depth in the treated skin areas. Regarding the NO-loading effects, skin acidification and increase in dermal microcirculation, plasma devices represent promising tools against chronic/infected wounds. However, efficacy of plasma treatment needs to be quantified in further studies and clinical trials.

  6. Application of Dielectric-Barrier Discharge to the Stabilization of Lifted Non-Premixed Methane/Air Jet Flames

    Science.gov (United States)

    Liao, Ying-Hao; Zhao, Xiang-Hong

    2016-11-01

    Recent studies have shown that the application of non-thermal plasma is a promising way to enhance the flame stabilization and combustion efficiency. The present study experimentally investigates the effect of a dielectric-barrier discharge (DBD) on the stabilization of lifted non-premixed methane/air jet flames. The jet flame with co-annular DBD is produced by a co-flow burner and has a Reynolds number of Re = 2500, 5000, 7000, and 9000. The application of DBD is seen to have an impact on the flame lift-off height, and the degree of impact is subject to flow conditions (such as Reynolds number and co-flow velocity) and plasma power. In general, the enhancement of flame stabilization, indicated by the decrease in lift-off height, is most evident at low Reynolds number and co-flow velocity. For flames with a Reynolds number less than Re = 5000, flames are attached to the nozzle regardless of the co-flow velocity and plasma power; at Re = 5000, flames are often intermittently attached. The enhancement is not that significant at high Reynolds number and co-flow velocity at least for the plasma power employed in the current study. A slight increase in plasma power leads to enhanced flame stabilization.

  7. Pesticide analysis at ppt concentration levels: coupling nano-liquid chromatography with dielectric barrier discharge ionization-mass spectrometry.

    Science.gov (United States)

    Mirabelli, Mario F; Wolf, Jan-Christoph; Zenobi, Renato

    2016-05-01

    We report the coupling of nano-liquid chromatography (nano-LC) with an ambient dielectric barrier discharge ionization (DBDI)-based source. Detection and quantification were carried out by high-resolution mass spectrometry (MS), using an LTQ-Orbitrap in full scan mode. Despite the fact that nano-LC systems are rarely used in food analysis, this coupling was demonstrated to deliver extremely high sensitivity in pesticide analysis, with limits of detection (LODs) as low as 10 pg/mL. In all cases, the limits of quantification (LOQs) were compliant with the current EU regulation. An excellent signal linearity over up to four orders of magnitude was also observed. Therefore, this method can easily compete with conventional GC-(EI)-MS or LC-ESI-MS/MS methods and in some cases outperform them. The method was successfully tested for food sample analysis, with apples and baby food, extracted using the QuEChERS approach. Our results demonstrate an outstanding sensitivity (at femtogram level) and reproducibility of the nano-LC-DBDI coupling, capable of improving routine pesticide analysis. To the best of our knowledge, this is the most sensitive and reproducible plasma-MS-based method for pesticide analysis reported to date.

  8. The Changes in Electrical and Interfacial Properties of Polyimide Exposed to Dielectric Barrier Discharge in SF6 Medium

    Science.gov (United States)

    Alisoy, Hafiz Z.; Koseoglu, Murat

    2013-01-01

    The formation mechanism of space charges in polyimide (PI) which was exposed to dielectric barrier discharge (DBD) in SF6 medium and the effects of the space charges on interfacial and electrical properties of PI were investigated. The variation of normalized surface charge density on PI sample was calculated and illustrated for different DBD exposure times. The surface potential was measured to determine the effect of the space charges on the sample. Then, the contact angle values were measured to obtain the relation between the surface energy and the surface charge density. The expressions for the total charge and the concentration of trapped electrons were derived by using Poisson and continuity equations at stationary state. The space charges were determined experimentally by using thermally stimulated depolarization current (TSDC) method. Also, SEM image and FTIR spectrum of virgin and treated samples were presented to observe the structural variations. It was seen that the approach for the formation mechanism of the space charges agreed with the experimental data. However, it was concluded particularly for the short-time DBD treatments that the space charges accumulated in the sample should be considered besides the effects of surface functionalization in the determination of the surface energy. PMID:23844414

  9. Functionalization of Hydrogen-free Diamond-like Carbon Films using Open-air Dielectric Barrier Discharge Atmospheric Plasma Treatments

    Energy Technology Data Exchange (ETDEWEB)

    Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA; Instituto de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid, Spain; Instituto de Quimica-Fisica" Rocasolano" C.S.I.C., 28006 Madrid, Spain; Mahasarakham University, Mahasarakham 44150, Thailand; CASTI, CNR-INFM Regional Laboratory, L' Aquila 67100, Italy; SUNY Upstate Medical University, Syracuse, NY 13210, USA; Endrino, Jose; Endrino, J. L.; Marco, J. F.; Poolcharuansin, P.; Phani, A.R.; Allen, M.; Albella, J. M.; Anders, A.

    2007-12-28

    A dielectric barrier discharge (DBD) technique has been employed to produce uniform atmospheric plasmas of He and N2 gas mixtures in open air in order to functionalize the surface of filtered-arc deposited hydrogen-free diamond-like carbon (DLC) films. XPS measurements were carried out on both untreated and He/N2 DBD plasma treated DLC surfaces. Chemical states of the C 1s and N 1s peaks were collected and used to characterize the surface bonds. Contact angle measurements were also used to record the short- and long-term variations in wettability of treated and untreated DLC. In addition, cell viability tests were performed to determine the influence of various He/N2 atmospheric plasma treatments on the attachment of osteoblast MC3T3 cells. Current evidence shows the feasibility of atmospheric plasmas in producing long-lasting variations in the surface bonding and surface energy of hydrogen-free DLC and consequently the potential for this technique in the functionalization of DLC coated devices.

  10. Optical visualization and electrical characterization of fast-rising pulsed dielectric barrier discharge for airflow control applications

    Science.gov (United States)

    Benard, Nicolas; Zouzou, Nourredine; Claverie, Alain; Sotton, Julien; Moreau, Eric

    2012-02-01

    Flow control consists of manipulating flows in an effective and robust manner to improve the global performances of transport systems or industrial processes. Plasma technologies, and particularly surface dielectric barrier discharge (DBD), can be a good candidate for such purpose. The present experimental study focuses on optical and electrical characterization of plasma sheet formed by applying a pulse of voltage with rising and falling periods of 50 ns for a typical surface DBD geometry. Positive and negative polarities are compared in terms of current behavior, deposited energy, fast-imaging of the plasma propagation, and resulting modifications of the surrounding medium by using shadowgraphy acquisitions. Positive and negative pulses of voltage produce streamers and corona type plasma, respectively. Both of them result in the production of a localized pressure wave propagating in the air with a speed maintained at 343 m/s (measurements at room temperature of 20 °C). This suggests that the produced pressure wave can be considered as a propagating sound wave. The intensity of the pressure wave is directly connected to the dissipated energy at the dielectric wall with a linear increase with the applied voltage amplitude and a strong dependence toward the rising time. At constant voltage amplitude, the pressure wave is reinforced by using a positive pulse. The present investigation also reveals that rising and decaying periods of a single pulse of voltage result in two distinct pressure waves. As a result, superposition or successive pressure wave can be produced by adjusting the width of the pulse.

  11. Determination of gaseous semi-and low-volatile organic halogen compounds by barrier-discharge atomic emission spectrometry

    Institute of Scientific and Technical Information of China (English)

    Yifei Sun; Nobuhisa Watanabe; Wei Wang; Tianle Zhu

    2013-01-01

    A group parameter approach using "total organic halogen" is effective for monitoring gaseous organic halogen compounds,including fluorine,chlorine,and bromine compounds,generated from combustion.We described the use of barrier-discharge radiofrequencyhelium-plasma/atomic emission spectrometry,for the detection of semi-and low-volatile organic halogen compounds (SLVOXs),which can be collected by CarbotrapTM adsorbents and analyzed using thermal desorption.The optimal carrier gas flow rates at the injection and desorption lines were established to be 100 mL/min.The detection range for SLVOXs in the gaseous samples was from 10 ng to tens of micrograms.Measuring F was more diflicult than measuring Cl or Br,because the wavelength ofF is dose to that of air.The barrierdischarge radiofrequency-helium-plasma/atomic emission spectrometry measured from 85% to 103% of the SLVOXs in the gas sample.It has been found that Carbotrap B is appropriate for high-boiling-point compounds,and Carbotrap C is suitable for the determination of organic halogen compounds with lower boiling points,in the range 200-230℃.Under optimal analysis conditions,a chlorinecontaining plastic was destroyed using different oxygen concentrations.Lower oxygen concentrations resulted in the production of lower amounts of organic halogen compounds.

  12. Treatment of Candida albicans biofilms with low-temperature plasma induced by dielectric barrier discharge and atmospheric pressure plasma jet

    Energy Technology Data Exchange (ETDEWEB)

    Koban, Ina; Welk, Alexander; Meisel, Peter; Holtfreter, Birte; Kocher, Thomas [Unit of Periodontology, Dental School, University of Greifswald, Rotgerberstr. 8, 17475 Greifswald (Germany); Matthes, Rutger; Huebner, Nils-Olaf; Kramer, Axel [Institute for Hygiene and Environmental Medicine, University of Greifswald, Walther-Rathenau-Str. 49 a, 17487 Greifswald (Germany); Sietmann, Rabea [Institute of Microbiology, University of Greifswald, Friedrich-Ludwig-Jahn-Str. 15, 17487 Greifswald (Germany); Kindel, Eckhard; Weltmann, Klaus-Dieter, E-mail: ina.koban@uni-greifswald.d [Leibniz Institute for Plasma Science and Technology (INP), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany)

    2010-07-15

    Because of some disadvantages of chemical disinfection in dental practice (especially denture cleaning), we investigated the effects of physical methods on Candida albicans biofilms. For this purpose, the antifungal efficacy of three different low-temperature plasma devices (an atmospheric pressure plasma jet and two different dielectric barrier discharges (DBDs)) on Candida albicans biofilms grown on titanium discs in vitro was investigated. As positive treatment controls, we used 0.1% chlorhexidine digluconate (CHX) and 0.6% sodium hypochlorite (NaOCl). The corresponding gas streams without plasma ignition served as negative treatment controls. The efficacy of the plasma treatment was determined evaluating the number of colony-forming units (CFU) recovered from titanium discs. The plasma treatment reduced the CFU significantly compared to chemical disinfectants. While 10 min CHX or NaOCl exposure led to a CFU log{sub 10} reduction factor of 1.5, the log{sub 10} reduction factor of DBD plasma was up to 5. In conclusion, the use of low-temperature plasma is a promising physical alternative to chemical antiseptics for dental practice.

  13. Novel design of high voltage pulse source for efficient dielectric barrier discharge generation by using silicon diodes for alternating current

    Science.gov (United States)

    Truong, Hoa Thi; Hayashi, Misaki; Uesugi, Yoshihiko; Tanaka, Yasunori; Ishijima, Tatsuo

    2017-06-01

    This work focuses on design, construction, and optimization of configuration of a novel high voltage pulse power source for large-scale dielectric barrier discharge (DBD) generation. The pulses were generated by using the high-speed switching characteristic of an inexpensive device called silicon diodes for alternating current and the self-terminated characteristic of DBD. The operation started to be powered by a primary DC low voltage power supply flexibly equipped with a commercial DC power supply, or a battery, or DC output of an independent photovoltaic system without transformer employment. This flexible connection to different types of primary power supply could provide a promising solution for the application of DBD, especially in the area without power grid connection. The simple modular structure, non-control requirement, transformer elimination, and a minimum number of levels in voltage conversion could lead to a reduction in size, weight, simple maintenance, low cost of installation, and high scalability of a DBD generator. The performance of this pulse source has been validated by a load of resistor. A good agreement between theoretically estimated and experimentally measured responses has been achieved. The pulse source has also been successfully applied for an efficient DBD plasma generation.

  14. Statistical Analysis of Reducing Biochemical Oxygen Demand (BOD) on Industrial Rubber Wastewater using Dielectric Barrier Discharge Plasma

    Science.gov (United States)

    Syakur, Abdul; Zaman, Badrus; Yunita Nurmaliakasih, Dias

    2017-04-01

    Dielectric Barrier Discharge plasma (DBD) is one of type non-thermal plasma (non-equilibrium plasma) or can be referred to as cold plasma. In this research, DBD plasma be utilized to reduce organic compounds like Biochemichal oxygen demand in the wastewater rubber processing. In the environment field DBD plasma has been used as a treatment for reducing air pollutants such as gas COx, NOx and HC. In addition DBD plasma have been developed to processed wastewater as an alternative technology in wastewater treatment. DBD plasma appears when the electrode is given a high voltage so that, it will form electric field in the area of the electrodes which allows the ionization and the presence of high-energy electrons in the area. The presence of these electrons will ionize molecules of H2O into active species such as OH•, H• and H2O2. The active species that can oxidize into CO2 and H2O so, BOD that can be degraded. In this research for wastewater treatment used high voltage are 10kV, 11kV, 12kV and 13kV and variations of processing time for 5, 10, 15, 20, and 25 (minutes). By increasing the voltage and extend the contact time then the speed variation of electrons to ionize the greater and more active species to be formed to degrade the pollutants to the maximum. This research used quantitative analysis with statistical analysis using SPSS software.

  15. Synthesis of flat sticky hydrophobic carbon diamond-like films using atmospheric pressure Ar/CH4 dielectric barrier discharge

    Science.gov (United States)

    Rincón, R.; Hendaoui, A.; de Matos, J.; Chaker, M.

    2016-06-01

    An Ar/CH4 atmospheric pressure dielectric barrier discharge (AP-DBD) was used to synthesize sticky hydrophobic diamond-like carbon (DLC) films on glass surface. The film is formed with plasma treatment duration shorter than 30 s, and water contact angles larger than 90° together with contact angle hysteresis larger than 10° can be achieved. According to Fourier transform infrared spectroscopy and atomic force microscopy analysis, hydrocarbon functional groups are created on the glass substrate, producing coatings with low surface energy (˜35 mJ m-2) with no modification of the surface roughness. To infer the plasma processes leading to the formation of low energy DLC surfaces, optical emission spectroscopy was used. From the results, a direct relationship between the CH species present in the plasma and the carbon concentration in the hydrophobic layer was found, which suggests that the CH species are the precursors of DLC film growth. Additionally, the plasma gas temperature was measured to be below 350 K which highlights the suitability of using AP-DBD to treat thermo-sensitive surfaces.

  16. Rapid removal of bacterial endotoxin and natural organic matter in water by dielectric barrier discharge plasma: Efficiency and toxicity assessment.

    Science.gov (United States)

    Zhang, Can; Fang, Zhendong; Liu, Wenjun; Tian, Fang; Bai, Miao

    2016-11-15

    Low-temperature plasma was used to control bacteria, endotoxins and natural organic matter (NOM) in water by a dielectric barrier discharge (DBD) device. Results indicate that DBD plasma has an obvious inactivation effect on various bacteria in water. The degree of inactivation from difficult to easy is as follows: Bacillus subtilis>Escherichia coli>Staphylococcus aureus. Activated ultrapure water treated using DBD plasma exhibited a sustained sterilization effect, but this sterilization effect decreased gradually after 1h. The total-endotoxin (free-endotoxin and bound-endotoxin) released by Escherichia coli during inactivation, as well as artificially simulated endotoxin in a control solution, was significantly controlled by DBD plasma. Both the metabolites that appeared after inactivation of microorganisms by plasma treatment, and the NOM in filtration effluent of a water treatment plant were well removed by DBD plasma if the treatment duration was sufficiently long. However, the acute toxicity increased significantly, and persisted for at least 2h, indicating that some long-life active substances were generated during the DBD process. Therefore, the removal of bacteria, endotoxins or NOM does not mean a safe water is produced. It is also important to eliminate the toxicity and byproducts produced during water treatment for the continuous promotion and industrial application of DBD plasma.

  17. Effects of surface modification by atmospheric oxygen dielectric barrier discharge plasma on PBO fibers and its composites

    Science.gov (United States)

    Liu, Zhe; Chen, Ping; Zhang, Xiaoliang; Yu, Qi; Ma, Keming; Ding, Zhenfeng

    2013-10-01

    In this paper, oxygen dielectric barrier discharge (oxy-DBD) plasma was employed to modify PBO fibers and enhance the interfacial adhesion of PBO fiber/bismaleimide composites. The interlaminar shear strength (ILSS) of the composites was improved greatly to 62.0 MPa with an increment of 41.2% at 30 W/cm3, 24 s. The SEM images of fracture morphology indicated that the failure place shifted from the interface to the matrix, and the water absorption decreased from 1.96 to 1.53%, the two results demonstrated the improved adhesive strength in other ways. In addition, the ILSS retention ratio of PBO/BMI composites after boiling in water were about 90%, confirming good humid resistance of the composites. The results obtained from XPS and AFM revealed that some polar groups were introduced onto PBO fibers and the surface morphology of PBO fibers was roughened. As a result, the wettability, reactivity and roughness of PBO fibers were all improved, they contributed to the improvement of the ILSS of the composites. The comparisons with air-DBD plasma showed that the chemical changes of PBO fibers were not alike because of different plasma gases.

  18. Effects and Mechanism of Atmospheric-Pressure Dielectric Barrier Discharge Cold Plasma on Lactate Dehydrogenase (LDH) Enzyme.

    Science.gov (United States)

    Zhang, Hao; Xu, Zimu; Shen, Jie; Li, Xu; Ding, Lili; Ma, Jie; Lan, Yan; Xia, Weidong; Cheng, Cheng; Sun, Qiang; Zhang, Zelong; Chu, Paul K

    2015-01-01

    Proteins are carriers of biological functions and the effects of atmospheric-pressure non-thermal plasmas on proteins are important to applications such as sterilization and plasma-induced apoptosis of cancer cells. Herein, we report our detailed investigation of the effects of helium-oxygen non-thermal dielectric barrier discharge (DBD) plasmas on the inactivation of lactate dehydrogenase (LDH) enzyme solutions. Circular dichroism (CD) and dynamic light scattering (DLS) indicate that the loss of activity stems from plasma-induced modification of the secondary molecular structure as well as polymerization of the peptide chains. Raising the treatment intensity leads to a reduced alpha-helix content, increase in the percentage of the beta-sheet regions and random sequence, as well as gradually decreasing LDH activity. However, the structure of the LDH plasma-treated for 300 seconds exhibits a recovery trend after storage for 24 h and its activity also increases slightly. By comparing direct and indirect plasma treatments, plasma-induced LDH inactivation can be attributed to reactive species (RS) in the plasma, especially ones with a long lifetime including hydrogen peroxide, ozone, and nitrate ion which play the major role in the alteration of the macromolecular structure and molecular diameter in lieu of heat, UV radiation, and charged particles.

  19. Ecologically based targets for bioavailable (reactive) nitrogen discharge from the drainage basins of the Wet Tropics region, Great Barrier Reef.

    Science.gov (United States)

    Wooldridge, Scott A; Brodie, Jon E; Kroon, Frederieke J; Turner, Ryan D R

    2015-08-15

    A modelling framework is developed for the Wet Tropics region of the Great Barrier Reef that links a quantitative river discharge parameter (viz. dissolved inorganic nitrogen concentration, DIN) with an eutrophication indicator within the marine environment (viz. chlorophyll-a concentration, chl-a). The model predicts catchment-specific levels of reduction (%) in end-of-river DIN concentrations (as a proxy for total potentially reactive nitrogen, PRN) needed to ensure compliance with chl-a 'trigger' guidelines for the ecologically distinct, but PRN-related issues of crown-of-thorns starfish (COTS) outbreaks, reef biodiversity loss, and thermal bleaching sensitivity. The results indicate that even for river basins dominated by agricultural land uses, quite modest reductions in end-of-river PRN concentrations (∼20-40%) may assist in mitigating the risk of primary COTS outbreaks from the mid-shelf reefs of the Wet Tropics. However, more significant reductions (∼60-80%) are required to halt and reverse declines in reef biodiversity, and loss of thermal bleaching resistance.

  20. Simulation Tool for Dielectric Barrier Discharge Plasma Actuators at Atmospheric and Sub-Atmospheric Pressures: SBIR Phase I Final Report

    Science.gov (United States)

    Likhanskii, Alexandre

    2012-01-01

    This report is the final report of a SBIR Phase I project. It is identical to the final report submitted, after some proprietary information of administrative nature has been removed. The development of a numerical simulation tool for dielectric barrier discharge (DBD) plasma actuator is reported. The objectives of the project were to analyze and predict DBD operation at wide range of ambient gas pressures. It overcomes the limitations of traditional DBD codes which are limited to low-speed applications and have weak prediction capabilities. The software tool allows DBD actuator analysis and prediction for subsonic to hypersonic flow regime. The simulation tool is based on the VORPAL code developed by Tech-X Corporation. VORPAL's capability of modeling DBD plasma actuator at low pressures (0.1 to 10 torr) using kinetic plasma modeling approach, and at moderate to atmospheric pressures (1 to 10 atm) using hydrodynamic plasma modeling approach, were demonstrated. In addition, results of experiments with pulsed+bias DBD configuration that were performed for validation purposes are reported.